Science.gov

Sample records for symmetric top molecules

  1. Vibration-rotation double resonance effects in symmetrical top molecules.

    NASA Technical Reports Server (NTRS)

    Marantz, H.; Frenkel, L.; Sullivan, T.

    1971-01-01

    Rotational transitions in symmetrical top molecules in the wavelength regions of 1-3 mm are sufficiently strong to be observed directly on an oscilloscope. Changes in the vibrational level populations induced by laser radiations affect the intensity of the rotational transitions. Observation of the microwave lines under the influence of chopped laser radiation shows a variety of interesting and potentially informative effects. At pressures above a few tenths of a torr the effect of laser radiation is to reduce the microwave response. This is true for all microwave lines at all those laser frequencies which are absorbed by the gas, and this effect is roughly proportional to the absorption coefficient. The rise and decay times of this effect increase with pressure and the the linear dimensions of the absorption cell. At low pressures the microwave response may increase, decrease, or remain unaffected depending on the observed microwave transitions and the specific laser line applied to the gas.

  2. Critical binding and electron scattering by symmetric-top polar molecules.

    PubMed

    Garrett, W R

    2014-10-28

    Quantum treatments of electron interactions with polar symmetric-top rotor molecules show features not present in the treatment of the linear-polar-rotor model. For symmetric tops possessing non-zero angular momentum about the symmetry axis, a new critical dipole can be defined that guarantees an infinite set of dipole-bound states independent of the values of the components of the inertial tensor. Additionally, for this same class, the scattering cross section diverges for all nonzero values of dipole moments and inertial moments, similar to solutions for the fixed linear dipole. Additional predictions are presented for electron affinities and rotational resonances of these systems.

  3. Critical binding and electron scattering by symmetric-top polar molecules

    SciTech Connect

    Garrett, W. R.

    2014-10-28

    Quantum treatments of electron interactions with polar symmetric-top rotor molecules show features not present in the treatment of the linear-polar-rotor model. For symmetric tops possessing non-zero angular momentum about the symmetry axis, a new critical dipole can be defined that guarantees an infinite set of dipole-bound states independent of the values of the components of the inertial tensor. Additionally, for this same class, the scattering cross section diverges for all nonzero values of dipole moments and inertial moments, similar to solutions for the fixed linear dipole. Additional predictions are presented for electron affinities and rotational resonances of these systems.

  4. Quantum effects in the capture of charged particles by dipolar polarizable symmetric top molecules. II. Interplay between electrostatic and gyroscopic interactions.

    PubMed

    Auzinsh, M; Dashevskaya, E I; Litvin, I; Nikitin, E E; Troe, J

    2013-10-14

    Within the general axially nonadiabatic channel approach described in Paper I of this series [M. Auzinsh, E. I. Dashevskaya, I. Litvin, E. E. Nikitin, and J. Troe, J. Chem. Phys. 139, 084311 (2013)], the present article analyzes the simultaneous manifestation of electrostatic and gyroscopic interactions in the quantum capture of dipolar polarizable symmetric top molecules by ions. As a demonstration, the rate coefficients for capture of CH3D and CD3H by H(+), D(+), and H3(+) are calculated.

  5. A new extended diffusion model for rotational motion of symmetric-top molecules in the liquid phase

    NASA Astrophysics Data System (ADS)

    Lascombe, J.; Besnard, M.; Maraval, P.

    1982-11-01

    In this paper, we present first a model called partially relaxed rotation model (PRR), to treat the reorientation motion of a symmetric top which rotates freely around its molecular axis with a tumbling motion relaxed according to a characteristic time τ 1. We show that this model can easily be extended to develop a 2τ model where both tumbling and spinning motion around the molecular axis are relaxed with a second characteristic time τ 2. As limiting cases one can obtain from the 2τ model, the Gordon-McClung and PRR models. Next, we illustrate the PPR and 2τ models by calculating Raman and infrared rotational spectral densities of liquid cyclopropane at room temperature. We also discuss in the PRR model the influence of the characteristic relaxation time τ 1, on the Raman rotational profile Î21( overlineν) Finally, we emphasize on the example of room-temperature liquid cyclopropane, the advantage of the PRR model to treat a E″ degenerated Raman profile with negligible Coriolis vibrational-rotational interaction. bl

  6. Rotational Spectra of Symmetric Top Molecules in Ground and Different Vibrational Excited States, and Phenomenon of Resonance – Applying in CF3CCH

    PubMed Central

    Motamedi, Masoud

    2007-01-01

    This paper deals with review of exploration of resonance in symmetric top molecules in different vibrational excited states, vt = n (n =1, 2, 3, 4). Calculations for CF3CCH shows that resonance take place at k=xℓℓ+(A-B)-2AζAζ-(A-B) and k=xℓℓ+(A-B)-2AζAζ-(A-B) for v10 = 2 and v10 = 3 respectively. In order to account for splitting about 3 MHz for the − 2 series in v10 = 4 is necessary to introduce the element 〈 J,k, ℓ|f24| J,k + 2, ℓ − 4〉 in fitting program.

  7. Is the Aliev and Watson method a suitable tool to relate DK0 of symmetric top molecules to excited state rovibrational parameters?

    NASA Astrophysics Data System (ADS)

    Graner, Georges; Bürger, Hans

    1986-02-01

    The M. R. Aliev and J. K. G. Watson sum rule [ J. Mol. Spectrosc.75, 150-160 (1979)] has been tentatively applied to the following symmetric top molecules: H 3SiCl, H 3GeCl, H 3GeBr, H 3SiF, H 3CCl, D 3CCl, H 3CBr, D 3CBr, H 3CI, D 3CI, H 3CF, D 3CF, NH 3, PH 3, PD 3, AsH 3, H 3CD, H 3SiD, H 3GeD, HCF 3, H 2CCCH 2, and D 2CCCD 2. This sum rule relates ηtJ and ηtK to the quartic centrifugal distortions and should allow the determination of DK0. Therefore we have collected the best available values of the experimental quantities ηtJ and u t = D K0 - {1}/{4} η tK for each perpendicular band. We find that the sum role or its simplified version usually provides estimates which are at least as good as force field predictions of DK0 for which a direct determination is frequently precluded. Since this method is based on the rovibrational analysis of all perpendicular bands, it is also useful to detect perturbations not accounted for in the rovibrational analysis of these fundamentals. In such cases, DK0 values from different sources turn out to be inconsistent. A critical evaluation of the signs and magnitudes of the ηtJ and ηtK values may be helpful to find the origin for such inconsistencies. Because of the greater difficulties met and correlation of parameters usually found in the rovibrational analysis of the light ( XY3) and/or nearly spherical top molecules, the Aliev and Watson sum rule appears at the moment to be of greater value for molecules with a large {A 0}/{B 0} ratio.

  8. Collision dynamics of symmetric top molecules: A comparison of the rotationally inelastic scattering of CD{sub 3} and ND{sub 3} with He

    SciTech Connect

    Tkáč, Ondřej; Orr-Ewing, Andrew J.; Dagdigian, Paul J.; Alexander, Millard H.; Onvlee, Jolijn; Avoird, Ad van der

    2014-04-07

    We compare rotationally inelastic scattering of deuterated methyl radicals (CD{sub 3}) and ammonia (ND{sub 3}) in collisions with helium using close-coupling quantum-mechanical scattering calculations performed with ab initio potential energy surfaces (PESs). The theoretical methods have been rigorously tested against angle-resolved experimental measurements obtained using crossed molecular beam apparatuses in combination with velocity map imaging [O. Tkáč, A. G. Sage, S. J. Greaves, A. J. Orr-Ewing, P. J. Dagdigian, Q. Ma, and M. H. Alexander, Chem. Sci. 4, 4199 (2013); O. Tkáč, A. K. Saha, J. Onvlee, C.-H. Yang, G. Sarma, C. K. Bishwakarma, S. Y. T. van de Meerakker, A. van der Avoird, D. H. Parker, and A. J. Orr-Ewing, Phys. Chem. Chem. Phys. 16, 477 (2014)]. Common features of the scattering dynamics of these two symmetric top molecules, one closed-shell and the other an open-shell radical, are identified and discussed. Two types of anisotropies in the PES influence the interaction of an atom with a nonlinear polyatomic molecule. The effects of these anisotropies can be clearly seen in the state-to-state integral cross sections out of the lowest CD{sub 3} rotational levels of each nuclear spin symmetry at a collision energy of 440 cm{sup −1}. Similarities and differences in the differential cross sections for the ND{sub 3}–He and CD{sub 3}–He systems can be linked to the coupling terms derived from the PESs which govern particular initial to final rotational level transitions.

  9. Coriolis coupling as a source of non-RRKM effects in triatomic near-symmetric top molecules: Diffusive intramolecular energy exchange between rotational and vibrational degrees of freedom.

    PubMed

    Kryvohuz, M; Marcus, R A

    2010-06-14

    A classical theory is proposed to describe the non-RRKM effects in activated asymmetric top triatomic molecules observed numerically in classical molecular dynamics simulations of ozone. The Coriolis coupling is shown to result in an effective diffusive energy exchange between the rotational and vibrational degrees of freedom. A stochastic differential equation is obtained for the K-component of the rotational angular momentum that governs the diffusion.

  10. Rotational excitation of symmetric top molecules by collisions with atoms: Close coupling, coupled states, and effective potential calculations for NH3-He

    NASA Technical Reports Server (NTRS)

    Green, S.

    1976-01-01

    The formalism for describing rotational excitation in collisions between symmetric top rigid rotors and spherical atoms is presented both within the accurate quantum close coupling framework and also the coupled states approximation of McGuire and Kouri and the effective potential approximation of Rabitz. Calculations are reported for thermal energy NH3-He collisions, treating NH3 as a rigid rotor and employing a uniform electron gas (Gordon-Kim) approximation for the intermolecular potential. Coupled states are found to be in nearly quantitative agreement with close coupling results while the effective potential method is found to be at least qualitatively correct. Modifications necessary to treat the inversion motion in NH3 are discussed.

  11. Ab initio ro-vibrational Hamiltonian in irreducible tensor formalism: a method for computing energy levels from potential energy surfaces for symmetric-top molecules

    NASA Astrophysics Data System (ADS)

    Rey, M.; Nikitin, A. V.; Tyuterev, Vl. G.

    2010-08-01

    A theoretical approach to study ro-vibrational molecular states from a full nuclear Hamiltonian expressed in terms of normal-mode irreducible tensor operators is presented for the first time. Each term of the Hamiltonian expansion can thus be cast in the tensor form in a systematic way using the formalism of ladder operators. Pyramidal XY3 molecules appear to be good candidates to validate this approach which allows taking advantage of the symmetry properties when doubly degenerate vibrational modes are considered. Examples of applications will be given for PH3 where variational calculations have been carried out from our recent potential energy surface [Nikitin et al., J. Chem. Phys. 130, 244312 (2009)].

  12. The microwave spectrum of methyl isoselenocyanate: CH 3NCSe as a quasi-symmetric top

    NASA Astrophysics Data System (ADS)

    Koput, J.; Stroh, F.; Winnewisser, M.

    1990-03-01

    The microwave spectrum of methyl isoselenocyanate, CH 3NCSe, has been measured in the region 18-40 GHz. The a-type J + 1 ← J rotational transitions ( J = 5 to 10) in the ground vibrational state of the molecule have been assigned for the three isotopic species with 82Se, 80Se, and 78Se. For the most abundant isotopic species, with 80Se, the rotational transitions in the excited states of the CNC bending mode v10 = 1 and 2 have also been assigned. Contrary to the previous investigation [T. Sakaizumi et al., Bull. Chem. Soc. Japan59, 1614-1616 (1986)], it has been shown that the observed spectrum is consistent with that of a quasi-symmetric top molecule. The rotation-vibration constants have been determined, showing an unusual variation with excitation of the CNC bending mode. The CNC bending potential function has been determined in preliminary calculations using a quasi-symmetric top model. The potential function is calculated to be very anharmonic, with an equilibrium CNC angle of about 162° and a barrier to linearity of the CNCSe skeleton of about 25 cm -1. From accidental resonances observed for the ground state transitions the barrier to internal rotation of the methyl group was estimated to be about 3 cm -1.

  13. On the symmetrization of rotational spectra for freely rotating linear molecules

    NASA Astrophysics Data System (ADS)

    Borysow, Aleksandra; Moraldi, Massimo

    It is demonstrated that the symmetrization of a quantum mechanical rotational spectrum of freely rotating linear molecules by means of the Egelstaff transformation produces a symmetric spectrum whose first two even moments coincide with the corresponding classical moments.

  14. Collisional Transitions in Interstellar Asymmetric Top Molecules

    NASA Astrophysics Data System (ADS)

    Chandra, Suresh

    2012-07-01

    For the study of a molecule in interstellar space or in circumstellar envelopes of an evolved star, one has to deal with a multi-level system in the molecule. These levels are connected through radiative as well as collisional transitions. The NLTE effects in a molecule come in the picture only when collisional transitions are present. Computation of collisional rates is quite cumbersome task. Besides emission and absorption, two anomalous phenomena: (i) MASER action and (ii) Anomalous absorption (Absorption against the CMB) are shown by some molecules in interstellar space. Both of these phenomena are good examples of NLTE prevailing in the interstellar space and circumstellar envelopes of evolved stars. In the present talk, we shall discuss about the collisional transitions between rotational levels in a molecule. The collisional rate coefficients for the rotational transition J τ → J' τ' at the kinetic temperature T, averaged over the Maxwellian distribution are C(J τ → J' τ'|T) = \\Big(\\frac{8 k T}{π μ}\\Big)^{1/2} \\Big(\\frac{1}{k T}\\Big)^2 \\int_0^\\infty σ (J τ → J' τ'|E) E {e}^{-E/kT} {d} E where μ is the reduced mass of the system and the cross section σ(J τ → J' τ'|E) for the transition is \\begin{eqnarray} σ (J τ → J' τ'|E) = \\sum_{L M M'} S(J, τ, J', τ'|L, M, M') q(L, M, M'|E) The q(L, M, M'|E) are the parameters which can be obtained from the software MOLSCAT. The spectroscopic coefficients, S ( J, τ, J', τ'|L, M, M'), depend on the wave-functions of the molecules and on the angular momentum coupling factors: S(J, τ, J', τ'|L, M, M') = \\sum_{p, p', q, q'} g^p_{J τ} g^q_{J τ} g^{p'}_{J' τ'} g^{q'}_{J' τ'} \\big \\big Here, \\big represents the Clebsch-Gorden coefficient. The g-coefficients can be obtained from laboratory analysis of the molecule and the parameters q(L, M, M'|E) can be obtained with the help of the software MOLSCAT for a

  15. Second virial coefficients of asymmetric top molecules.

    PubMed

    Wormer, Paul E S

    2005-05-08

    A short self-contained derivation is given for the second virial coefficient B2(T) of a gas consisting of identical interacting asymmetric rigid rotors. The resulting expression is correct through variant Planck's over h2. First, the canonical partition function is derived by means of an variant Planck's over h expansion of exp[-H/(k(B)T)] due to Friedmann [Adv. Chem. Phys. 4, 225 (1962)]. The present work applies angular momentum operators and known facts from angular momentum theory. It is considerably more accessible than Friedmann's exposition, which is not based on angular momentum operators, but instead on explicit derivatives with respect to Euler angles. The partition function obtained from the variant Planck's over h expansion is applied to the derivation of an expression for B2(T) that is identical in appearance to the expression for symmetric rotors of T Pack [J. Chem. Phys. 78, 7217 (1983)]. The final equation in this work is valid for rigid rotors of any symmetry.

  16. Molecular collisions. 11: Semiclassical approximation to atom-symmetric top rotational excitation

    NASA Technical Reports Server (NTRS)

    Russell, D.; Curtiss, C. F.

    1973-01-01

    In a paper of this series a distorted wave approximation to the T matrix for atom-symmetric top scattering was developed which is correct to first order in the part of the interaction potential responsible for transitions in the component of rotational angular momentum along the symmetry axis of the top. A semiclassical expression for this T matrix is derived by assuming large values of orbital and rotational angular momentum quantum numbers.

  17. Alignment of asymetric-top molecules using multiple-pulse trains.

    SciTech Connect

    Pabst, S.; Santra, R.; X-Ray Science Division; Univ. Erlangen-Nuremberg; Univ. of Chicago

    2010-06-07

    We theoretically analyze the effectiveness of multiple-pulse laser alignment methods for asymmetric-top molecules. As an example, we choose SO2 and investigate the alignment dynamics induced by two different sequences, each consisting of four identical laser pulses. Each sequence differs only in the time delay between the pulses. Equally spaced pulses matching the alignment revival of the symmetrized SO2 rotor model are exploited in the first sequence. The pulse separations in the second sequence are short compared to the rotation dynamics of the molecule and monotonically increase the degree of alignment until the maximum alignment is reached. We point out the significant differences between the alignment dynamics of SO2 treated as an asymmetric-top and a symmetric-top rotor, respectively. We also explain why the fast sequence of laser pulses creates considerably stronger one-dimensional molecular alignment for asymmetric-top molecules. In addition, we show that multiple-pulse trains with elliptically polarized pulses do not enhance one-dimensional alignment or create three-dimensional alignment.

  18. Rare top quark decays in Alternative Left-Right Symmetric Models

    SciTech Connect

    Gaitan, R.; Miranda, O. G.; Cabral-Rosetti, L. G.

    2007-06-19

    We evaluate the flavor changing neutral currents (FCNC) decay t {yields} H0 + c in the context of Alternative Left-Right symmetric Models (ALRM) with extra isosinglet heavy fermions; the FCNC decays may place at tree level and are only supressed by the mixing between ordinary top and charm quarks. We also comment on the decay process t {yields} c + {gamma}, which involves radiative corrections.

  19. The Asymmetric Top Molecule In An Electric Field

    NASA Astrophysics Data System (ADS)

    Pittman, Suzanne; Almaguer, Jose; Heller, Eric; Heller Group Team

    2014-03-01

    The quantum and classical behavior of the asymmetric top has been studied in a variety of different contexts, and is known for its dynamical complexity due to have greater than 2 DOF. In this presentation the focus will be on the classical dynamics of an asymmetric top molecule with a dipole moment in an electric field (a non-integrable system), and how the underlying classical phase space structures, such as resonances, can impact the behavior of its quantum analog. Specifically, we will be presenting results from a classical simulation, which highlights both chaotic and regular regions for small electric fields depending on initial conditions. Department of Physics and Harvard, I7 Oxford St., Harvard University, Cambridge, Massachusetts 02138.

  20. The Relaxation Matrix for Symmetric Tops with Inversion Symmetry. I. Effects of Line Coupling on Self-Broadened v (sub 1) and Pure Rotational Bands of NH3

    NASA Technical Reports Server (NTRS)

    Ma, Q.; Boulet, C.

    2016-01-01

    The Robert-Bonamy formalism has been commonly used to calculate half-widths and shifts of spectral lines for decades. This formalism is based on several approximations. Among them, two have not been fully addressed: the isolated line approximation and the neglect of coupling between the translational and internal motions. Recently, we have shown that the isolated line approximation is not necessary in developing semi-classical line shape theories. Based on this progress, we have been able to develop a new formalism that enables not only to reduce uncertainties on calculated half-widths and shifts, but also to model line mixing effects on spectra starting from the knowledge of the intermolecular potential. In our previous studies, the new formalism had been applied to linear and asymmetric-top molecules. In the present study, the method has been extended to symmetric-top molecules with inversion symmetry. As expected, the inversion splitting induces a complete failure of the isolated line approximation. We have calculated the complex relaxation matrices of selfbroadened NH3. The half-widths and shifts in the ?1 and the pure rotational bands are reported in the present paper. When compared with measurements, the calculated half-widths match the experimental data very well, since the inapplicable isolated line approximation has been removed. With respect to the shifts, only qualitative results are obtained and discussed. Calculated off-diagonal elements of the relaxation matrix and a comparison with the observed line mixing effects are reported in the companion paper (Paper II).

  1. The role played by self-orientational properties in nematics of colloids with molecules axially symmetric.

    PubMed

    Alarcón-Waess, O

    2010-04-14

    The self-orientational structure factor as well as the short-time self-orientational diffusion coefficient is computed for colloids composed by nonspherical molecules. To compute the short-time dynamics the hydrodynamic interactions are not taken into account. The hard molecules with at least one symmetry axis considered are: rods, spherocylinders, and tetragonal parallelepipeds. Because both orientational properties in study are written in terms of the second and fourth order parameters, these automatically hold the features of the order parameters. That is, they present a discontinuity for first order transitions, determining in this way the spinodal line. In order to analyze the nematic phase only, we choose the appropriate values for the representative quantities that characterize the molecules. Different formalisms are used to compute the structural properties: de Gennes-Landau approach, Smoluchowski equation and computer simulations. Some of the necessary inputs are taken from literature. Our results show that the self-orientational properties play an important role in the characterization and the localization of axially symmetric phases. While the self-structure decreases throughout the nematics, the short-time self-diffusion does not decrease but rather increases. We study the evolution of the second and fourth order parameters; we find different responses for axial and biaxial nematics, predicting the possibility of a biaxial nematics in tetragonal parallelepiped molecules. By considering the second order in the axial-biaxial phase transition, with the support of the self-orientational structure factor, we are able to propose the density at which this occurs. The short-time dynamics is able to predict a different value in the axial and the biaxial phases. Because the different behavior of the fourth order parameter, the diffusion coefficient is lower for a biaxial phase than for an axial one. Therefore the self-structure factor is able to localize

  2. The relaxation matrix for symmetric tops with inversion symmetry. I. Effects of line coupling on self-broadened ν1 and pure rotational bands of NH3

    NASA Astrophysics Data System (ADS)

    Ma, Q.; Boulet, C.

    2016-06-01

    The Robert-Bonamy formalism has been commonly used to calculate half-widths and shifts of spectral lines for decades. This formalism is based on several approximations. Among them, two have not been fully addressed: the isolated line approximation and the neglect of coupling between the translational and internal motions. Recently, we have shown that the isolated line approximation is not necessary in developing semi-classical line shape theories. Based on this progress, we have been able to develop a new formalism that enables not only to reduce uncertainties on calculated half-widths and shifts, but also to model line mixing effects on spectra starting from the knowledge of the intermolecular potential. In our previous studies, the new formalism had been applied to linear and asymmetric-top molecules. In the present study, the method has been extended to symmetric-top molecules with inversion symmetry. As expected, the inversion splitting induces a complete failure of the isolated line approximation. We have calculated the complex relaxation matrices of self-broadened NH3. The half-widths and shifts in the ν1 and the pure rotational bands are reported in the present paper. When compared with measurements, the calculated half-widths match the experimental data very well, since the inapplicable isolated line approximation has been removed. With respect to the shifts, only qualitative results are obtained and discussed. Calculated off-diagonal elements of the relaxation matrix and a comparison with the observed line mixing effects are reported in the companion paper (Paper II).

  3. The relaxation matrix for symmetric tops with inversion symmetry. I. Effects of line coupling on self-broadened ν1 and pure rotational bands of NH3.

    PubMed

    Ma, Q; Boulet, C

    2016-06-14

    The Robert-Bonamy formalism has been commonly used to calculate half-widths and shifts of spectral lines for decades. This formalism is based on several approximations. Among them, two have not been fully addressed: the isolated line approximation and the neglect of coupling between the translational and internal motions. Recently, we have shown that the isolated line approximation is not necessary in developing semi-classical line shape theories. Based on this progress, we have been able to develop a new formalism that enables not only to reduce uncertainties on calculated half-widths and shifts, but also to model line mixing effects on spectra starting from the knowledge of the intermolecular potential. In our previous studies, the new formalism had been applied to linear and asymmetric-top molecules. In the present study, the method has been extended to symmetric-top molecules with inversion symmetry. As expected, the inversion splitting induces a complete failure of the isolated line approximation. We have calculated the complex relaxation matrices of self-broadened NH3. The half-widths and shifts in the ν1 and the pure rotational bands are reported in the present paper. When compared with measurements, the calculated half-widths match the experimental data very well, since the inapplicable isolated line approximation has been removed. With respect to the shifts, only qualitative results are obtained and discussed. Calculated off-diagonal elements of the relaxation matrix and a comparison with the observed line mixing effects are reported in the companion paper (Paper II).

  4. Collision-induced absorption in mixtures of symmetrical linear and tetrahedral molecules - Methane-nitrogen

    NASA Technical Reports Server (NTRS)

    Birnbaum, G.; Borysow, A.; Buechele, A.

    1993-01-01

    The far infrared absorption of a CH4-N2 mixture was measured at 297, 195, and 162 K from 30 to 650/cm. The spectral invariants gamma1 and alpha1, proportional, respectively, to the zeroth and first spectral moments, due to bimolecular collisions between CH4 and N2 were obtained from these data and compared with theoretical values. The theory for collision-induced dipoles between a tetrahedral and a diatomic or symmetrical linear molecule includes contributions not previously considered. Whereas the theoretical values of gamma1 are only somewhat greater than experiment at all temperatures, the theoretical values of alpha1 are significantly lower than the experimental values. From the theoretical spectral moments for the various induced dipole components, the parameters of the BC shape were computed, and theoretical spectra were constructed. Good agreement was obtained at the lower frequencies, but with increasing frequencies the theoretical spectra were increasingly less intense than the experimental spectra. Although the accuracy of the theoretical results may suffer from the lack of a reliable potential function, it does not appear that this high frequency discrepancy can be removed by any conceivable modification in the potential.

  5. The dark side of crystal engineering: creating glasses from small symmetric molecules that form multiple hydrogen bonds.

    PubMed

    Lebel, Olivier; Maris, Thierry; Perron, Marie-Eve; Demers, Eric; Wuest, James D

    2006-08-16

    Glasses made from compounds of low molecular weight are useful materials with many attractive features, including well-defined compositions. At present, there are no reliable ways to identify molecules that will form long-lived glasses, and efforts to design them have tended to rely on crude principles, such as avoiding small, symmetric, and relatively inflexible molecules that engage in strong intermolecular association. We have found that it is possible to make glasses from such molecules by turning to the dark side of crystal engineering and by making small but carefully selected structural modifications specifically designed to thwart established patterns of crystallization.

  6. Rotational state dependence of rate constants for the reaction of ions with asymmetric top molecules at very low temperatures: application to the N+/H2O system

    NASA Astrophysics Data System (ADS)

    Dubernet, M. L.; McCarroll, R.

    1990-12-01

    The adiabatic rotational state method is applied to the study of reactions between ions and polar asymmetric top molecules at very low temperatures. Detailed results of the calculated rate coefficients for the reaction of N+ with H2O are presented. A strong dependence of the rate coefficients on the initial rotational state is observed at low temperatures. In the case of a thermal distribution of rotational states, where the rate constants are summed over a Boltzman distribution, the replacement of the asymmetric top by an average symmetric top, which leads to a considerable simplification of the calculations, appears to be satisfactory. On the other hand, for a non thermal distribution, no such simplifying assumption can be made. In particular, the rate coefficient for a specific initial rotational state is quite sensitive to the orientation of the dipole moment.

  7. The relaxation matrix for symmetric tops with inversion symmetry. II. Line mixing effects in the ν1 band of NH3.

    PubMed

    Boulet, C; Ma, Q

    2016-06-14

    Line mixing effects have been calculated in the ν1 parallel band of self-broadened NH3. The theoretical approach is an extension of a semi-classical model to symmetric-top molecules with inversion symmetry developed in the companion paper [Q. Ma and C. Boulet, J. Chem. Phys. 144, 224303 (2016)]. This model takes into account line coupling effects and hence enables the calculation of the entire relaxation matrix. A detailed analysis of the various coupling mechanisms is carried out for Q and R inversion doublets. The model has been applied to the calculation of the shape of the Q branch and of some R manifolds for which an obvious signature of line mixing effects has been experimentally demonstrated. Comparisons with measurements show that the present formalism leads to an accurate prediction of the available experimental line shapes. Discrepancies between the experimental and theoretical sets of first order mixing parameters are discussed as well as some extensions of both theory and experiment.

  8. The Relaxation Matrix for Symmetric Tops with Inversion Symmetry. II; Line Mixing Effects in the V1 Band of NH3

    NASA Technical Reports Server (NTRS)

    Boulet, C.; Ma, Q.

    2016-01-01

    Line mixing effects have been calculated in the ?1 parallel band of self-broadened NH3. The theoretical approach is an extension of a semi-classical model to symmetric-top molecules with inversion symmetry developed in the companion paper [Q. Ma and C. Boulet, J. Chem. Phys. 144, 224303 (2016)]. This model takes into account line coupling effects and hence enables the calculation of the entire relaxation matrix. A detailed analysis of the various coupling mechanisms is carried out for Q and R inversion doublets. The model has been applied to the calculation of the shape of the Q branch and of some R manifolds for which an obvious signature of line mixing effects has been experimentally demonstrated. Comparisons with measurements show that the present formalism leads to an accurate prediction of the available experimental line shapes. Discrepancies between the experimental and theoretical sets of first order mixing parameters are discussed as well as some extensions of both theory and experiment.

  9. Anomalous absorption in a-type asymmetric top molecules in cosmic objects

    NASA Astrophysics Data System (ADS)

    Chandra, Suresh

    Since the detection of the first molecule OH in cosmic objects in 1963, scientists got interested in identification of molecules in the cosmic objects. By now more than 170 molecules have been identified. In order to know about the physical conditions prevailing in the cool cosmic objects and about the chemical reactions going on there, scientists are interested in identification of as many molecules as possible. In some molecular clouds, the kinetic temperature is very low, 10 - 20 K. For such objects, anomalous absorption, i.e., the absorption against the cosmic microwave background, may play an important role for identification of molecules. The transition 111 - 110 at 4.829 GHz of H_2CO was the first one showing the anomalous absorption in the cosmic objects. The molecule H_2CS also has been identified in the cosmic objects. We have discussed about the anomalous absorption of 111 - 110 transition in a-type asymmetric top molecules. For the investigation, the required parameters are the radiative and collisional transition probabilities. We can calculate radiative transition probabilities between the rotational levels. Calculation of collisional rates is a tedious job. In absence of accurate collisional rates, we can investigated the anomalous absorption in a qualitative manner by using the scaled values for collisional rates. We find that anomalous absorption of 111 - 110 transition is possible, provided collisional rates satisfy the required condition.

  10. Response functions for dimers and square-symmetric molecules in four-wave-mixing experiments with polarized light.

    PubMed

    Smith, Eric Ryan; Farrow, Darcie A; Jonas, David M

    2005-07-22

    Four-wave-mixing nonlinear-response functions are given for intermolecular and intramolecular vibrations of a perpendicular dimer and intramolecular vibrations of a square-symmetric molecule containing a doubly degenerate state. A two-dimensional particle-in-a-box model is used to approximate the electronic wave functions and obtain harmonic potentials for nuclear motion. Vibronic interactions due to symmetry-lowering distortions along Jahn-Teller active normal modes are discussed. Electronic dephasing due to nuclear motion along both symmetric and asymmetric normal modes is included in these response functions, but population transfer between states is not. As an illustration, these response functions are used to predict the pump-probe polarization anisotropy in the limit of impulsive excitation.

  11. Temperature dependence of collisional rate coefficients for rotational transitions: a-type asymmetric top molecules

    NASA Astrophysics Data System (ADS)

    Sharma, M. K.; Sharma, M.; Chandra, S.

    2017-04-01

    On realizing that the rate coefficients for rotational transitions in the H2CS, H2CO, H2CC, H2CSi, due to collisions with He atom, under the IOS approximation, increase with the increase of kinetic temperature, we have looked analytically for 9 transitions in a-type asymmetric top molecules, because the results of Green et al. (1978) for H2CO do not increase for all the transitions, though they also are calculated under the IOS approximation. We tried to understand the source of discrepancy, but could not succeed, as the details of the work of Green et al. (1978) are not available. Data for other three molecules (H2CS, H2CC, H2CSi) are not available in the literature. Since our investigation is analytical, there is no reason not to believe our results.

  12. Design of tailored microwave pulses to create rotational coherent states for an asymmetric-top molecule

    NASA Astrophysics Data System (ADS)

    Ortigoso, Juan

    1998-06-01

    Tailored microwave pulses, to guide asymmetric-top molecules from selected rotational states belonging to the vibronic ground state to generalized angular-momentum coherent states, are designed by using optimal control theory. Characteristics that the molecules have to fulfill in order to achieve the goal with feasible pulses are discussed. Properties of the pulses are discussed as well. The further dephasing among the components of the wave packet which, for the simplest coherent state, is a form of dynamical tunneling, can be locked by exploiting the changes that energy levels and eigenfunctions undergo in the presence of an external static electric field with appropriate intensity. For the special case with M=0, periodic fields are more flexible in avoiding dephasing. This is shown by examining properties of quasienergies and dressed states resulting from the diagonalization of a truncated Floquet matrix.

  13. Rotational state selection and orientation of diatomic and asymmetric top molecules via the electric hexapole technique

    NASA Astrophysics Data System (ADS)

    Hain, Toby Douglas

    2000-11-01

    The hexapole rotational state selection of 2∏ Ω diatomic and asymmetric top molecules is investigated. Classical molecular trajectory simulations are shown to reproduce experimental focusing spectra in these large classes of molecules. Deviations from linear Stark effects introduce significant effects in the focusing behavior of both the 2∏ and asymmetric rotor species. The laboratory frame distributions of orientations of the state-selected molecules are quantified by quantum mechanical orientational probability distribution functions (opdf's). Chapter 1 introduces preliminary data for the hexapole focusing of hydroxyl radicals and shows the deviation of the structured focusing curves from the first-order Stark effect. In Chapter 2, the focusing theory is developed for 2∏ diatomics, and the focusing spectra presented in Chapter 1 are analyzed using the theory. The Λ-doublet splitting is found to be the important parameter for simulating the measured focusing spectra. The high field limit opdf's are calculated, and highly anisotropic orientational distributions for the selected states are shown. Chapter 3 shows the laboratory orientation of 2∏ molecules is tunable via the electric field strength of an orienting field for post- hexapole selected rotational states. A laser induced fluorescence experiment is detailed allowing experimental validation of the theoretical opdf's. Chapter 4 explores the scattering of hexapole selected OD rotational states with various target gases. Elastic scattering cross sections are reported for OD + M (M = He, Ar, H2O, CO2, NH3, and CH3F). Hexapole focusing and the subsequent orientation of asymmetric rotors are the subjects of Chapter 5. Matrix treatments are used to calculate the field-free and Stark energies exactly. Perturbation and intermediate Stark effect approximations are compared to the exact matrix method, yielding several general rules useful in analyzing and predicting experimental focusing spectra. The theory

  14. Computational studies of x-ray scattering from three-dimensionally-aligned asymmetric-top molecules.

    SciTech Connect

    Pabst, S.; Ho, P.; Santra, R.

    2010-01-01

    We theoretically and numerically analyze x-ray scattering from asymmetric-top molecules three-dimensionally aligned using elliptically polarized laser light. A rigid-rotor model is assumed. The principal axes of the polarizability tensor are assumed to coincide with the principal axes of the moment of inertia tensor. Several symmetries in the Hamiltonian are identified and exploited to enhance the efficiency of solving the time-dependent Schroedinger equation for each rotational state initially populated in a thermal ensemble. Using a phase-retrieval algorithm, the feasibility of structure reconstruction from a quasiadiabatically aligned sample is illustrated for the organic molecule naphthalene. The spatial resolution achievable strongly depends on the laser parameters, the initial rotational temperature, and the x-ray pulse duration. We demonstrate that for a laser peak intensity of 5 TW/cm{sup 2}, a laser pulse duration of 100 ps, a rotational temperature of 10 mK, and an x-ray pulse duration of 1 ps, the molecular structure may be probed at a resolution of 1 {angstrom}.

  15. Computational studies of x-ray scattering from three-dimensionally-aligned asymmetric-top molecules

    SciTech Connect

    Pabst, Stefan; Ho, Phay J.; Santra, Robin

    2010-04-15

    We theoretically and numerically analyze x-ray scattering from asymmetric-top molecules three-dimensionally aligned using elliptically polarized laser light. A rigid-rotor model is assumed. The principal axes of the polarizability tensor are assumed to coincide with the principal axes of the moment of inertia tensor. Several symmetries in the Hamiltonian are identified and exploited to enhance the efficiency of solving the time-dependent Schroedinger equation for each rotational state initially populated in a thermal ensemble. Using a phase-retrieval algorithm, the feasibility of structure reconstruction from a quasiadiabatically aligned sample is illustrated for the organic molecule naphthalene. The spatial resolution achievable strongly depends on the laser parameters, the initial rotational temperature, and the x-ray pulse duration. We demonstrate that for a laser peak intensity of 5 TW/cm{sup 2}, a laser pulse duration of 100 ps, a rotational temperature of 10 mK, and an x-ray pulse duration of 1 ps, the molecular structure may be probed at a resolution of 1 A ring .

  16. Computational studies of x-ray scattering from three-dimensionally-aligned asymmetric-top molecules

    NASA Astrophysics Data System (ADS)

    Pabst, Stefan; Ho, Phay; Santra, Robin

    2009-11-01

    We theoretically and numerically analyze x-ray scattering from asymmetric-top molecules three-dimensionally aligned using elliptically polarized laser light. A rigid-rotor model is assumed. The principal axes of the polarizability tensor are assumed to coincide with the principal axes of the moment of inertia tensor. Several symmetries in the Hamiltonian are identified and employed to enhance the efficiency of solving the time-dependent Schr"odinger equation for each rotational state initially populated in a thermal ensemble. Using a phase-retrieval algorithm, the feasibility of structure reconstruction from a quasi-adiabatically-aligned sample is illustrated for the organic molecule naphthalene. The spatial resolution achievable strongly depends on the laser parameters, the initial rotational temperature, and the x-ray pulse duration. We demonstrate that for a laser peak intensity of 5 TW/cm^2, a laser pulse duration of 100 ps, a rotational temperature of 10 mK, and an x-ray pulse duration of 1 ps, the molecular structure may be probed at a resolution of 1 å.

  17. Homochiral D4-symmetric metal–organic cages from stereogenic Ru(II) metalloligands for effective enantioseparation of atropisomeric molecules

    PubMed Central

    Wu, Kai; Li, Kang; Hou, Ya-Jun; Pan, Mei; Zhang, Lu-Yin; Chen, Ling; Su, Cheng-Yong

    2016-01-01

    Absolute chiral environments are rare in regular polyhedral and prismatic architectures, but are achievable from self-assembly of metal–organic cages/containers (MOCs), which endow us with a promising ability to imitate natural organization systems to accomplish stereochemical recognition, catalysis and separation. Here we report a general assembly approach to homochiral MOCs with robust chemical viability suitable for various practical applications. A stepwise process for assembly of enantiopure ΔΔΔΔΔΔΔΔ- and ΛΛΛΛΛΛΛΛ-Pd6(RuL3)8 MOCs is accomplished by pre-resolution of the Δ/Λ-Ru-metalloligand precursors. The obtained Pd–Ru bimetallic MOCs feature in large D4-symmetric chiral space imposed by the predetermined Ru(II)-octahedral stereoconfigurations, which are substitutionally inert, stable, water-soluble and are capable of encapsulating a dozen guests per cage. Chiral resolution tests reveal diverse host–guest stereoselectivity towards different chiral molecules, which demonstrate enantioseparation ability for atropisomeric compounds with C2 symmetry. NMR studies indicate a distinctive resolution process depending on guest exchange dynamics, which is differentiable between host–guest diastereomers. PMID:26839048

  18. Extension of the measurement, assignment, and fit of the rotational spectrum of the two-top molecule methyl acetate

    NASA Astrophysics Data System (ADS)

    Nguyen, Ha Vinh Lam; Kleiner, Isabelle; Shipman, Steven T.; Mae, Yoshiaki; Hirose, Kazue; Hatanaka, Shota; Kobayashi, Kaori

    2014-05-01

    New and previous spectroscopic data were recorded for the two-top molecule methyl acetate using five spectrometers in four different labs: a room temperature chirped-pulse Fourier transform microwave (FTMW) spectrometer in the frequency range from 8.7 to 26.5 GHz, two molecular beam FTMW spectrometers (2-40 GHz), a free jet absorption Stark-modulated spectrometer (60-78 GHz), and a room temperature millimeter-wave spectrometer (44-68 GHz). Approximately 800 new lines with J up to 40 and K up to 16 were assigned. In total, 1603 lines were fitted with 34 parameters using an internal rotation Hamiltonian in the Rho Axis Method (RAM) and the program BELGI-Cs-2tops to standard deviations close to the experimental uncertainties. More precise determinations of the top-top interaction and the J, K dependent parameters were carried out.

  19. Ionization of one- and three-dimensionally-oriented asymmetric-top molecules by intense circularly polarized femtosecond laser pulses

    SciTech Connect

    Hansen, Jonas L.; Holmegaard, Lotte; Kalhoej, Line; Kragh, Sofie Louise; Stapelfeldt, Henrik; Filsinger, Frank; Meijer, Gerard; Kuepper, Jochen; Dimitrovski, Darko; Abu-samha, Mahmoud; Martiny, Christian Per Juul; Madsen, Lars Bojer

    2011-02-15

    We present a combined experimental and theoretical study on strong-field ionization of a three-dimensionally-oriented asymmetric top molecule, benzonitrile (C{sub 7}H{sub 5}N), by circularly polarized, nonresonant femtosecond laser pulses. Prior to the interaction with the strong field, the molecules are quantum-state selected using a deflector and three-dimensionally (3D) aligned and oriented adiabatically using an elliptically polarized laser pulse in combination with a static electric field. A characteristic splitting in the molecular frame photoelectron momentum distribution reveals the position of the nodal planes of the molecular orbitals from which ionization occurs. The experimental results are supported by a theoretical tunneling model that includes and quantifies the splitting in the momentum distribution. The focus of the present article is to understand strong-field ionization from 3D-oriented asymmetric top molecules, in particular the suppression of electron emission in nodal planes of molecular orbitals. In the preceding article [Dimitrovski et al., Phys. Rev. A 83, 023405 (2011)] the focus is to understand the strong-field ionization of one-dimensionally-oriented polar molecules, in particular asymmetries in the emission direction of the photoelectrons.

  20. Generalized Vibrational Perturbation Theory for Rotovibrational Energies of Linear, Symmetric and Asymmetric Tops: Theory, Approximations, and Automated Approaches to Deal with Medium-to-Large Molecular Systems

    PubMed Central

    Piccardo, Matteo; Bloino, Julien; Barone, Vincenzo

    2015-01-01

    Models going beyond the rigid-rotor and the harmonic oscillator levels are mandatory for providing accurate theoretical predictions for several spectroscopic properties. Different strategies have been devised for this purpose. Among them, the treatment by perturbation theory of the molecular Hamiltonian after its expansion in power series of products of vibrational and rotational operators, also referred to as vibrational perturbation theory (VPT), is particularly appealing for its computational efficiency to treat medium-to-large systems. Moreover, generalized (GVPT) strategies combining the use of perturbative and variational formalisms can be adopted to further improve the accuracy of the results, with the first approach used for weakly coupled terms, and the second one to handle tightly coupled ones. In this context, the GVPT formulation for asymmetric, symmetric, and linear tops is revisited and fully generalized to both minima and first-order saddle points of the molecular potential energy surface. The computational strategies and approximations that can be adopted in dealing with GVPT computations are pointed out, with a particular attention devoted to the treatment of symmetry and degeneracies. A number of tests and applications are discussed, to show the possibilities of the developments, as regards both the variety of treatable systems and eligible methods. © 2015 Wiley Periodicals, Inc. PMID:26345131

  1. Generalized Vibrational Perturbation Theory for Rotovibrational Energies of Linear, Symmetric and Asymmetric Tops: Theory, Approximations, and Automated Approaches to Deal with Medium-to-Large Molecular Systems.

    PubMed

    Piccardo, Matteo; Bloino, Julien; Barone, Vincenzo

    2015-08-05

    Models going beyond the rigid-rotor and the harmonic oscillator levels are mandatory for providing accurate theoretical predictions for several spectroscopic properties. Different strategies have been devised for this purpose. Among them, the treatment by perturbation theory of the molecular Hamiltonian after its expansion in power series of products of vibrational and rotational operators, also referred to as vibrational perturbation theory (VPT), is particularly appealing for its computational efficiency to treat medium-to-large systems. Moreover, generalized (GVPT) strategies combining the use of perturbative and variational formalisms can be adopted to further improve the accuracy of the results, with the first approach used for weakly coupled terms, and the second one to handle tightly coupled ones. In this context, the GVPT formulation for asymmetric, symmetric, and linear tops is revisited and fully generalized to both minima and first-order saddle points of the molecular potential energy surface. The computational strategies and approximations that can be adopted in dealing with GVPT computations are pointed out, with a particular attention devoted to the treatment of symmetry and degeneracies. A number of tests and applications are discussed, to show the possibilities of the developments, as regards both the variety of treatable systems and eligible methods.

  2. Abnormal difference between the mobilities of left- and right-twisted conformations of C6H12N2 roto-symmetrical molecules at very low temperatures.

    PubMed

    Gabuda, S P; Kozlova, S G

    2015-06-21

    We report an abnormal difference of low-temperature mobility of left-twisted and right-twisted conformations of roto symmetric molecules C6H12N2 (dabco) located in the same positions in crystal Zn2(C8H4O4)2⋅C6H12N2. The difference between (1)H NMR (Nuclear Magnetic Resonance) spin-relaxation data for left-twisted and right-twisted molecules reaches ∼3 × 10(3) times at 8 K and tends to grow at lower temperatures. We argue that taking into account four-component relativistic Dirac wave functions in the vicinity of the nodal plane of dabco molecules and vacuum fluctuations due to virtual particle-antiparticle pairs can explain the changes which C6H12N2 conformations undergo at low temperatures.

  3. Analysis of electron diffraction data for several symmetric coordinates of large-amplitude motions in the case of the 1,3,5-trinitrobenzene molecule

    NASA Astrophysics Data System (ADS)

    Khaikin, L. S.; Kochikov, I. V.; Tikhonov, D. S.; Grikina, O. E.

    2015-06-01

    A brief description of a solution of the problem on electron diffraction analysis using the potential procedure for nonrigid molecules with large-amplitude motions along several symmetric internal coordinates was given. The efficiency of the approach was demonstrated for determination of the equilibrium geometry of the 1,3,5-trinitrobenzene molecule with three equivalent internal rotation coordinates of NO2 groups. The results of the electron diffraction experiment and quantum-chemical calculation at the MP2( full)/ cc-pVTZ level were considered along with the vibrational spectra of 1,3,5-trinitrobenzene and a planar equilibrium D 3 h symmetry conformation for the molecule was found reliably for the first time. The geometrical parameters of the molecule were determined ( r e , the bond lengths are given in Å, the angles in deg): CC 1.387(2), CN 1.474(4), NO 1.220(1), CH 1.072(31), ONO 125.8(2), CC(H)C 116.6(3), HCC* 121.7(1), CC(N)C* 123.4(3), NCC* 118.3(1), and CNO* 117.1(1); the asterisk marks the dependent parameters.

  4. Theoretical description of the mixed-field orientation of asymmetric-top molecules: A time-dependent study

    NASA Astrophysics Data System (ADS)

    Omiste, Juan J.; González-Férez, Rosario

    2016-12-01

    We present a theoretical study of the mixed-field-orientation of asymmetric-top molecules in tilted static electric field and nonresonant linearly polarized laser pulse by solving the time-dependent Schrödinger equation. Within this framework, we compute the mixed-field orientation of a state-selected molecular beam of benzonitrile (C7H5N ) and compare with the experimental observations [J. L. Hansen et al., Phys. Rev. A 83, 023406 (2011), 10.1103/PhysRevA.83.023406] and with our previous time-independent descriptions [J. J. Omiste et al., Phys. Chem. Chem. Phys. 13, 18815 (2011), 10.1039/c1cp21195a]. For an excited rotational state, we investigate the field-dressed dynamics for several field configurations as those used in the mixed-field experiments. The nonadiabatic phenomena and their consequences on the rotational dynamics are analyzed in detail.

  5. A semi-classical approach to the calculation of highly excited rotational energies for asymmetric-top molecules.

    PubMed

    Schmiedt, Hanno; Schlemmer, Stephan; Yurchenko, Sergey N; Yachmenev, Andrey; Jensen, Per

    2017-01-18

    We report a new semi-classical method to compute highly excited rotational energy levels of an asymmetric-top molecule. The method forgoes the idea of a full quantum mechanical treatment of the ro-vibrational motion of the molecule. Instead, it employs a semi-classical Green's function approach to describe the rotational motion, while retaining a quantum mechanical description of the vibrations. Similar approaches have existed for some time, but the method proposed here has two novel features. First, inspired by the path integral method, periodic orbits in the phase space and tunneling paths are naturally obtained by means of molecular symmetry analysis. Second, the rigorous variational method is employed for the first time to describe the molecular vibrations. In addition, we present a new robust approach to generating rotational energy surfaces for vibrationally excited states; this is done in a fully quantum-mechanical, variational manner. The semi-classical approach of the present work is applied to calculating the energies of very highly excited rotational states and it reduces dramatically the computing time as well as the storage and memory requirements when compared to the fullly quantum-mechanical variational approach. Test calculations for excited states of SO2 yield semi-classical energies in very good agreement with the available experimental data and the results of fully quantum-mechanical calculations.

  6. A semi-classical approach to the calculation of highly excited rotational energies for asymmetric-top molecules

    PubMed Central

    Schmiedt, Hanno; Schlemmer, Stephan; Yurchenko, Sergey N.; Yachmenev, Andrey

    2017-01-01

    We report a new semi-classical method to compute highly excited rotational energy levels of an asymmetric-top molecule. The method forgoes the idea of a full quantum mechanical treatment of the ro-vibrational motion of the molecule. Instead, it employs a semi-classical Green's function approach to describe the rotational motion, while retaining a quantum mechanical description of the vibrations. Similar approaches have existed for some time, but the method proposed here has two novel features. First, inspired by the path integral method, periodic orbits in the phase space and tunneling paths are naturally obtained by means of molecular symmetry analysis. Second, the rigorous variational method is employed for the first time to describe the molecular vibrations. In addition, we present a new robust approach to generating rotational energy surfaces for vibrationally excited states; this is done in a fully quantum-mechanical, variational manner. The semi-classical approach of the present work is applied to calculating the energies of very highly excited rotational states and it reduces dramatically the computing time as well as the storage and memory requirements when compared to the fullly quantum-mechanical variational approach. Test calculations for excited states of SO2 yield semi-classical energies in very good agreement with the available experimental data and the results of fully quantum-mechanical calculations. PMID:28000807

  7. Effects on Calculated Half-Widths and Shifts from the Line Coupling for Asymmetric-Top Molecules

    NASA Technical Reports Server (NTRS)

    Ma, Q.; Boulet, C.; Tipping, R. H.

    2014-01-01

    The refinement of the Robert-Bonamy formalism by considering the line coupling for linear molecules developed in our previous studies [Q. Ma, C. Boulet, and R. H. Tipping, J. Chem. Phys. 139, 034305 (2013); 140, 104304 (2014)] have been extended to asymmetric-top molecules. For H2O immersed in N2 bath, the line coupling selection rules applicable for the pure rotational band to determine whether two specified lines are coupled or not are established. Meanwhile, because the coupling strengths are determined by relative importance of off-diagonal matrix elements versus diagonal elements of the operator -iS1 -S2, quantitative tools are developed with which one is able to remove weakly coupled lines from consideration. By applying these tools, we have found that within reasonable tolerances, most of the H2O lines in the pure rotational band are not coupled. This reflects the fact that differences of energy levels of the H2O states are pretty large. But, there are several dozen strongly coupled lines and they can be categorized into different groups such that the line couplings occur only within the same groups. In practice, to identify those strongly coupled lines and to confine them into sub-linespaces are crucial steps in considering the line coupling. We have calculated half-widths and shifts for some groups, including the line coupling. Based on these calculations, one can conclude that for most of the H2O lines, it is unnecessary to consider the line coupling. However, for several dozens of lines, effects on the calculated half-widths from the line coupling are small, but remain noticeable and reductions of calculated half-widths due to including the line coupling could reach to 5%. Meanwhile, effects on the calculated shifts are very significant and variations of calculated shifts could be as large as 25%.

  8. Quasi-Classical Trajectory Study of Atom-Diatomic Molecule Collisions in Symmetric Hyperspherical Coordinates: The F + HCl Reaction as a Test Case.

    PubMed

    Freixas-Lemus, Victor Manuel; Martínez-Mesa, Aliezer; Uranga-Piña, Llinersy

    2016-04-07

    We investigate the reactive dynamics of the triatomic system F + HCl → HF + Cl for total angular momentum equal zero and for different low-lying rovibrational states of the diatomic molecule. For each of the initial vibrational quantum numbers, the time evolution of the atom-diatom collision process is investigated for a wide range of impact angles and collision energies. To this purpose, the Quasi-Classical Trajectories (QCT) method was implemented in a hyperspherical configuration space. The Hamilton equations of motion are solved numerically in an intermediate effective Cartesian space to exploit the relative simplicity of this intermediate representation. Interatomic interactions are described by a London-Eyring-Polanyi-Sato potential energy surface, specifically developed for the title reaction, and the results of the QCT simulations are discussed in terms of the time-evolution of the hyperangles. The analysis of the collision dynamics using symmetric hyperspherical coordinates provides, in addition to the description in terms of a natural reaction coordinate (the hyperradius), a more striking representation of the exchange dynamics, in terms of the time-dependent probability distribution along the kinematic rotation hyperangle, and a precise distinction between direct and indirect mechanisms of the reaction.

  9. Organometallic complexes of bulky, optically active, C3-symmetric tris(4S-isopropyl-5,5-dimethyl-2-oxazolinyl)phenylborate (ToP*)

    DOE PAGES

    Xu, Songchen; Magoon, Yitzhak; Reinig, Regina R.; ...

    2015-07-16

    A bulky, optically active monoanionic scorpionate ligand, tris(4S-isopropyl-5,5-dimethyl-2-oxazolinyl)phenylborate (ToP*), is synthesized from the naturally occurring amino acid l-valine as its lithium salt, Li[ToP*] (1). That compound is readily converted to the thallium complex Tl[ToP*] (2) and to the acid derivative H[ToP*] (3). Group 7 tricarbonyl complexes ToP*M(CO)3 (M = Mn (4), Re (5)) are synthesized by the reaction of MBr(CO)5 and Li[ToP*] and are crystallographically characterized. The νCO bands in their infrared spectra indicate that π back-donation in the rhenium compounds is greater with ToP* than with non-methylated tris(4S-isopropyl-2-oxazolinyl)phenylborate (ToP). The reaction of H[ToP*] and ZnEt2 gives ToP*ZnEt (6), whilemore » ToP*ZnCl (7) is synthesized from Li[ToP*] and ZnCl2. The reaction of ToP*ZnCl and KOtBu followed by addition of PhSiH3 provides the zinc hydride complex ToP*ZnH (8). In this study, compound 8 is the first example of a crystallographically characterized optically active zinc hydride. We tested its catalytic reactivity in the cross-dehydrocoupling of silanes and alcohols, which provided Si-chiral silanes with moderate enantioselectivity.« less

  10. Symmetrical Diphosphatetraazacyclooctatetraenes.

    DTIC Science & Technology

    1980-06-26

    aryl, alkyl, perfluoroalkyl and perfluoroalkylether radcalsl Rf is selected from perfluoroalkyl and perfluoroalkylether radicals 20 as represented by...process for synthesizing symmetrical diphosphatetraazacyclooctatetraenes by reacting perfluoroalkyl or perfluoroalkylether amidine with a...symmetrical diphosphatetraazacyclooctatetraene. The substituent Rf can he selected from perfluoroalkyl and pertluoroalkylether groups as represented hy the

  11. Theoretical studies of pressure broadened halfwidths of symmetric tops: CH3CN-CH3CN and CH3Cl-CO2

    NASA Astrophysics Data System (ADS)

    Lavrentieva, Nina N.; Dudaryonok, Anna S.; Buldyreva, Jeanna V.

    2014-11-01

    The semi-empirical method has been used to determine of room temperature self-broadened halfwidths of methyl cyanide and CO2-broadened halfwidths of methyl chloride. We obtained data approximately for 1500 rotation-vibration transitions. J-dependences of these colliding systems are different due to various absorber-perturber resonance effects. Results of calculations clearly demonstrate a very good agreement between observed and computed parameters for both absorbing molecules.

  12. Fingerprinting seamless single-walled carbon nanotube junctions via the migration of encapsulated N2 molecules from bottom to top: are arrays of VA-SWNTs continuous?

    PubMed

    Thurakitseree, Theerapol; Kramberger, Christian; Singjai, Pisith; Maruyama, Shigeo

    2017-03-17

    Structure control such as diameter changes along single-walled carbon nanotubes (SWNTs) can be achieved in arrays of vertically aligned (VA-) SWNTs by switching the feedstock during growth. The local nature of the macroscopic transition from one diameter to another is then questioned as one can either envisage seamless transitions or discontinuous individual SWNTs. Here, we demonstrate that encapsulated molecules can serve as markers to doubtlessly identify seamless interconnections in macroscopic samples. A migration of nitrogen molecules inside the continuous SWNTs is observed using bulk scale measurements on double-layered SWNT arrays synthesized from different carbon/nitrogen feedstocks. The existence of N2 molecules at the top of the SWNT arrays proves that there are continuous SWNTs throughout the double layered arrays with different diameters.

  13. C2v top data system (C2v TDS) software for infrared spectrum simulation of XY2Z2 asymmetric molecules: some improvements to the TDS packages

    NASA Astrophysics Data System (ADS)

    Wenger, Ch.; Rotger, M.; Boudon, V.

    2005-07-01

    The spherical top data system (STDS) program suite developed in Dijon has been extended with the aim of studying any rovibrational band or polyad of XY2Z2(C2v) asymmetric top molecules. We work in the O(3)⊃Td⊃C2v chain because these species result from the substitution of two ligands of a corresponding “parent” spherical top and thus are relatively close to tetrahedral symmetry. The choice of this group chain has consequences on the method used to specify the input parameters of the programs for Hamiltonian and transition moment model calculations. One example concerning the ground state of the SO2F2 quasi-spherical molecule is presented. As before, this suite consists in a series of FORTRAN programs called by a script. The whole package is freely accessible through ftp (user anonymous) at jupiter.u-bourgogne.fr/dist or through the World Wide Web at http://www.u-bourgogne.fr/LPUB/c2vTDS.html. Further general improvements have been brought about for all the TDS packages (STDS, HTDS, C4vTDS) developed in our group and are briefly discussed in the present paper.

  14. Symmetric textures

    SciTech Connect

    Ramond, P. . Dept. of Physics)

    1993-01-01

    The Wolfenstein parametrization is extended to the quark masses in the deep ultraviolet, and an algorithm to derive symmetric textures which are compatible with existing data is developed. It is found that there are only five such textures.

  15. Symmetric textures

    SciTech Connect

    Ramond, P.

    1993-04-01

    The Wolfenstein parametrization is extended to the quark masses in the deep ultraviolet, and an algorithm to derive symmetric textures which are compatible with existing data is developed. It is found that there are only five such textures.

  16. Polymer-facilitated low temperature fusing of spray-coated silver nanowire networks as transparent top and bottom electrodes in small molecule organic photovoltaics (Presentation Recording)

    NASA Astrophysics Data System (ADS)

    Selzer, Franz; Weiß, Nelli; Kneppe, David; Bormann, Ludwig; Sachse, Christoph; Gaponik, Nikolai; Eychmüller, Alexander; Leo, Karl; Müller-Meskamp, Lars

    2015-10-01

    Networks of silver nanowires (AgNWs) are promising candidates for transparent conducting electrodes in organic photovoltaics (OPV), as they achieve similar performance as the commonly used indium tin oxide (ITO) at lower cost and increased flexibility. The initial sheet resistance (Rs) of AgNW electrodes typically needs to be reduced by a post-annealing step (90 min@200 °C), being detrimental for processing on polymeric substrates. We present novel low temperature-based methods to integrate AgNWs in organic small molecule-based photovoltaics, either as transparent and highly conductive bottom-electrode or, for the first time, as spray-coated AgNW top-electrode. The bottom-electrodes are prepared by organic matrix assisted low-temperature fusing. Here, selected polymers are coated below the AgNWs to increase the interaction between NWs and substrate. In comparison to networks without these polymeric sublayers, the Rs is reduced by two orders of magnitude. AgNW top-electrodes are realized by dispersing modified high-quality AgNWs in inert solvents, which do not damage small molecule layers. Accordingly, our AgNW dispersion can be spray-coated onto all kind of OPV devices. Both bottom- and top-electrodes show a Rs of <11 Ω/ at >87 % transparency directly after spray-coating at very low substrate temperatures of <80 °C. We also demonstrate the implementation of our AgNW electrodes in organic solar cells. The corresponding devices show almost identical performance compared to organic solar cells exploiting ITO as bottom or thermally evaporated thin-metal as top-electrode.

  17. Analytical Morse/long-range model potential and predicted infrared and microwave spectra for a symmetric top-atom dimer: a case study of CH₃F-He.

    PubMed

    Ma, Yong-Tao; Zeng, Tao; Li, Hui

    2014-06-07

    Four-dimensional ab initio intermolecular potential energy surfaces (PESs) for CH3F-He that explicitly incorporates dependence on the Q3 stretching normal mode of the CH3F molecule and are parametrically dependent on the other averaged intramolecular coordinates have been calculated. Analytical three-dimensional PESs for v3(CH3F) = 0 and 1 are obtained by least-squares fitting the vibrationally averaged potentials to the Morse/Long-Range potential function form. With the 3D PESs, we employ Lanczos algorithm to calculate rovibrational levels of the dimer system. Following some re-assignments, the predicted transition frequencies are in good agreement with experimental microwave data for ortho-CH3F, with the root-mean-square deviation of 0.042 cm(-1). We then provide the first prediction of the infrared and microwave spectra for the para-CH3F-He dimer. The calculated infrared band origin shifts associated with the ν3 fundamental of CH3F are 0.039 and 0.069 cm(-1) for para-CH3F-He and ortho-CH3F-He, respectively.

  18. Rotational Spectroscopy as a Tool to Investigate Interactions Between Vibrational Polyads in Symmetric Top Molecules: Low-Lying States v_8 ≤ 2 OF Methyl Cyanide

    NASA Astrophysics Data System (ADS)

    Müller, Holger S. P.; Ordu, Matthias H.; Lewen, Frank; Brown, Linda; Drouin, Brian; Pearson, John; Sung, Keeyoon; Kleiner, Isabelle; Sams, Robert

    2015-06-01

    Rotational and rovibrational spectra of methyl cyanide were recorded to analyze interactions in low-lying vibrational states and to construct line lists for radio astronomical observations as well as for infrared spectroscopic investigations of planetary atmospheres. The rotational spectra cover large portions of the 36-1627~GHz region. In the infrared (IR), a spectrum was recorded for this study in the region of 2ν_8 around 717~cm-1 with assignments covering 684-765~cm-1. Additional spectra in the ν _8 region were used to validate the analysis. Using ν _8 data as well as spectroscopic parameters for v_4 = 1, v_7 = 1, and v_8 = 3 from previous studies, we analyzed rotational data involving v = 0, v_8 = 1, and v_8 = 2 up to high J and K quantum numbers. We analyzed a strong Δ v_8 = ± 1, Δ K = 0, Δ l = ±3 Fermi resonance between v_8 = 1-1 and v_8 = 2+2 at K = 14 and obtained preliminary results for two further Fermi resonances between v_8 = 2 and 3. We also found resonant Δ v_8 = ± 1, Δ K = ∓ 2, Δ l = ± 1 interactions between v_8 = 1 and 2 and present the first detailed analysis of such a resonance between v_8 = 0 and 1. We discuss the impact of this analysis on the v_8 = 1 and 2 as well as on the axial v = 0 parameters and compare selected CH_3CN parameters with those of CH_3CCH and CH_3NC. We evaluated transition dipole moments of ν _8, 2ν _8 - ν _8, and 2ν _8 for remote sensing in the IR. Part of this work was carried out at the Jet Propulsion Laboratory under contract with the National Aeronautics and Space Administration. M. Koivusaari et al., J. Mol. Spectrosc. 152 (1992) 377-388. A.-M. Tolonen et al., J. Mol. Spectrosc. 160 (1993) 554-565.

  19. Rotational spectroscopy as a tool to investigate interactions between vibrational polyads in symmetric top molecules: Low-lying states v(8) <= 2 of methyl cyanide, CH3CN

    SciTech Connect

    Muller, H. S.; Brown, Linda R.; Drouin, B. J.; Pearson, J. C.; Kleiner, Isabelle; Sams, Robert L.; Sung, Keeyoon; Ordu, Matthias H.; Lewen, Frank

    2015-06-01

    Rotational and rovibrational spectra of methyl cyanide were recorded to analyze interactions in low-lying vibrational states and to construct line lists for radio astronomical observations as well as for infrared spectroscopic investigations of planetary atmospheres. The rotational spectra cover large portions of the 36-1627 GHz region. In the infrared (IR), a spectrum was recorded for this study in the region of 2v(8) around 717 cm(-1) with assignments covering 684-765 cm-1. Additional spectra in the vs region were used to validate the analysis.

  20. A spray-coating process for highly conductive silver nanowire networks as the transparent top-electrode for small molecule organic photovoltaics

    NASA Astrophysics Data System (ADS)

    Selzer, Franz; Weiß, Nelli; Kneppe, David; Bormann, Ludwig; Sachse, Christoph; Gaponik, Nikolai; Eychmüller, Alexander; Leo, Karl; Müller-Meskamp, Lars

    2015-01-01

    We present a novel top-electrode spray-coating process for the solution-based deposition of silver nanowires (AgNWs) onto vacuum-processed small molecule organic electronic solar cells. The process is compatible with organic light emitting diodes (OLEDs) and organic light emitting thin film transistors (OLETs) as well. By modifying commonly synthesized AgNWs with a perfluorinated methacrylate, we are able to disperse these wires in a highly fluorinated solvent. This solvent does not dissolve most organic materials, enabling a top spray-coating process for sensitive small molecule and polymer-based devices. The optimized preparation of the novel AgNW dispersion and spray-coating at only 30 °C leads to high performance electrodes directly after the deposition, exhibiting a sheet resistance of 10.0 Ω □-1 at 87.4% transparency (80.0% with substrate). By spraying our novel AgNW dispersion in air onto the vacuum-processed organic p-i-n type solar cells, we obtain working solar cells with a power conversion efficiency (PCE) of 1.23%, compared to the air exposed reference devices employing thermally evaporated thin metal layers as the top-electrode.We present a novel top-electrode spray-coating process for the solution-based deposition of silver nanowires (AgNWs) onto vacuum-processed small molecule organic electronic solar cells. The process is compatible with organic light emitting diodes (OLEDs) and organic light emitting thin film transistors (OLETs) as well. By modifying commonly synthesized AgNWs with a perfluorinated methacrylate, we are able to disperse these wires in a highly fluorinated solvent. This solvent does not dissolve most organic materials, enabling a top spray-coating process for sensitive small molecule and polymer-based devices. The optimized preparation of the novel AgNW dispersion and spray-coating at only 30 °C leads to high performance electrodes directly after the deposition, exhibiting a sheet resistance of 10.0 Ω □-1 at 87

  1. Abnormal difference between the mobilities of left- and right-twisted conformations of C{sub 6}H{sub 12}N{sub 2} roto-symmetrical molecules at very low temperatures

    SciTech Connect

    Gabuda, S. P.; Kozlova, S. G.

    2015-06-21

    We report an abnormal difference of low-temperature mobility of left-twisted and right-twisted conformations of roto symmetric molecules C{sub 6}H{sub 12}N{sub 2} (dabco) located in the same positions in crystal Zn{sub 2}(C{sub 8}H{sub 4}O{sub 4}){sub 2}⋅C{sub 6}H{sub 12}N{sub 2}. The difference between {sup 1}H NMR (Nuclear Magnetic Resonance) spin-relaxation data for left-twisted and right-twisted molecules reaches ∼3 × 10{sup 3} times at 8 K and tends to grow at lower temperatures. We argue that taking into account four-component relativistic Dirac wave functions in the vicinity of the nodal plane of dabco molecules and vacuum fluctuations due to virtual particle-antiparticle pairs can explain the changes which C{sub 6}H{sub 12}N{sub 2} conformations undergo at low temperatures.

  2. Binding of electrons, holes, and excitons in symmetric strained InP/ In0.49 Ga0.51 P triple quantum-dot molecules

    NASA Astrophysics Data System (ADS)

    Tadić, M.; Peeters, F. M.

    2004-11-01

    The electron, hole, and exciton spectra in the strained quantum-dot molecule consisting of three vertically arranged type-II InP/ In0.49 Ga0.51 P self-assembled quantum dots are modeled by the k•p theory. For the sake of simplicity, we consider dots of cylindrical shape, but take into account the anisotropy of the strain through the continuum mechanical model. For thick spacers, the strain leads to an upward shift of the lowest energies in all explored electron shells, but for spacers thinner than, say, the coupling length, the quantum mechanical coupling prevails, and downward shifts are observed. The magnitudes of both the energy shift and the coupling length vary with the quantum-dot height. For the holes, the interplay of strain and mixing enables binding at larger distances than for the electrons. The overlap of the hole clouds is basically established by means of the light holes, which are confined by the strain in the spacer between the dots and may efficiently couple the heavy-hole states, which are localized inside the quantum dots. Similar to electrons, the exciton lowest-energy states of different angular momenta, as computed by an exact-diagonalization approach, exhibit overshoots on the single-quantum-dot levels. Good agreement is found with experiment on the spatial location of electrons and holes in the triple-quantum-dot molecules.

  3. Two Dimensional Symmetric Correlation Functions of the S Operator and Two Dimensional Fourier Transforms: Considering the Line Coupling for P and R Lines of Linear Molecules

    NASA Technical Reports Server (NTRS)

    Ma, Q.; Boulet, C.; Tipping, R. H.

    2014-01-01

    The refinement of the Robert-Bonamy (RB) formalism by considering the line coupling for isotropic Raman Q lines of linear molecules developed in our previous study [Q. Ma, C. Boulet, and R. H. Tipping, J. Chem. Phys. 139, 034305 (2013)] has been extended to infrared P and R lines. In these calculations, the main task is to derive diagonal and off-diagonal matrix elements of the Liouville operator iS1 - S2 introduced in the formalism. When one considers the line coupling for isotropic Raman Q lines where their initial and final rotational quantum numbers are identical, the derivations of off-diagonal elements do not require extra correlation functions of the ^S operator and their Fourier transforms except for those used in deriving diagonal elements. In contrast, the derivations for infrared P and R lines become more difficult because they require a lot of new correlation functions and their Fourier transforms. By introducing two dimensional correlation functions labeled by two tensor ranks and making variable changes to become even functions, the derivations only require the latters' two dimensional Fourier transforms evaluated at two modulation frequencies characterizing the averaged energy gap and the frequency detuning between the two coupled transitions. With the coordinate representation, it is easy to accurately derive these two dimensional correlation functions. Meanwhile, by using the sampling theory one is able to effectively evaluate their two dimensional Fourier transforms. Thus, the obstacles in considering the line coupling for P and R lines have been overcome. Numerical calculations have been carried out for the half-widths of both the isotropic Raman Q lines and the infrared P and R lines of C2H2 broadened by N2. In comparison with values derived from the RB formalism, new calculated values are significantly reduced and become closer to measurements.

  4. Two dimensional symmetric correlation functions of the S-circumflex operator and two dimensional Fourier transforms: Considering the line coupling for P and R lines of linear molecules

    SciTech Connect

    Ma, Q.; Tipping, R. H.

    2014-03-14

    The refinement of the Robert-Bonamy (RB) formalism by considering the line coupling for isotropic Raman Q lines of linear molecules developed in our previous study [Q. Ma, C. Boulet, and R. H. Tipping, J. Chem. Phys. 139, 034305 (2013)] has been extended to infrared P and R lines. In these calculations, the main task is to derive diagonal and off-diagonal matrix elements of the Liouville operator iS{sub 1} − S{sub 2} introduced in the formalism. When one considers the line coupling for isotropic Raman Q lines where their initial and final rotational quantum numbers are identical, the derivations of off-diagonal elements do not require extra correlation functions of the S-circumflex operator and their Fourier transforms except for those used in deriving diagonal elements. In contrast, the derivations for infrared P and R lines become more difficult because they require a lot of new correlation functions and their Fourier transforms. By introducing two dimensional correlation functions labeled by two tensor ranks and making variable changes to become even functions, the derivations only require the latters’ two dimensional Fourier transforms evaluated at two modulation frequencies characterizing the averaged energy gap and the frequency detuning between the two coupled transitions. With the coordinate representation, it is easy to accurately derive these two dimensional correlation functions. Meanwhile, by using the sampling theory one is able to effectively evaluate their two dimensional Fourier transforms. Thus, the obstacles in considering the line coupling for P and R lines have been overcome. Numerical calculations have been carried out for the half-widths of both the isotropic Raman Q lines and the infrared P and R lines of C{sub 2}H{sub 2} broadened by N{sub 2}. In comparison with values derived from the RB formalism, new calculated values are significantly reduced and become closer to measurements.

  5. Rigid rotators. [deriving the time-independent energy states associated with rotational motions of the molecule

    NASA Technical Reports Server (NTRS)

    1976-01-01

    The two-particle, steady-state Schroedinger equation is transformed to center of mass and internuclear distance vector coordinates, leading to the free particle wave equation for the kinetic energy motion of the molecule and a decoupled wave equation for a single particle of reduced mass moving in a spherical potential field. The latter describes the vibrational and rotational energy modes of the diatomic molecule. For fixed internuclear distance, this becomes the equation of rigid rotator motion. The classical partition function for the rotator is derived and compared with the quantum expression. Molecular symmetry effects are developed from the generalized Pauli principle that the steady-state wave function of any system of fundamental particles must be antisymmetric. Nuclear spin and spin quantum functions are introduced and ortho- and para-states of rotators, along with their degeneracies, are defined. Effects of nuclear spin on entropy are deduced. Next, rigid polyatomic rotators are considered and the partition function for this case is derived. The patterns of rotational energy levels for nonlinear molecules are discussed for the spherical symmetric top, for the prolate symmetric top, for the oblate symmetric top, and for the asymmetric top. Finally, the equilibrium energy and specific heat of rigid rotators are derived.

  6. Recent Top Properties Measurements at CDF

    SciTech Connect

    Chiarelli, Giorgio

    2014-11-26

    We present the most recent CDF results on the measurements of the decay and production vertex of the top-quark. New results on forward-backward asymmetry in top-antitop events are presented. Also, recent measurements of the branching fractions of top-quark are discussed. Finally, measurements in single top events, where top-quark is produced through electroweak processes, are presented. Despite the much larger number of top events collected at the LHC, due to the symmetric initial state and the better signal-to-background ratio in specific channels, some results will be lasting heritage of the Tevatron.

  7. Rotational spectroscopy as a tool to investigate interactions between vibrational polyads in symmetric top molecules: Low-lying states v8 ⩽ 2 of methyl cyanide, CH3CN

    NASA Astrophysics Data System (ADS)

    Müller, Holger S. P.; Brown, Linda R.; Drouin, Brian J.; Pearson, John C.; Kleiner, Isabelle; Sams, Robert L.; Sung, Keeyoon; Ordu, Matthias H.; Lewen, Frank

    2015-06-01

    Rotational and rovibrational spectra of methyl cyanide were recorded to analyze interactions in low-lying vibrational states and to construct line lists for radio astronomical observations as well as for infrared spectroscopic investigations of planetary atmospheres. The rotational spectra cover large portions of the 36-1627 GHz region. In the infrared (IR), a spectrum was recorded for this study in the region of 2ν8 around 717 cm-1 with assignments covering 684-765 cm-1. Additional spectra in the ν8 region were used to validate the analysis. Information on the K level structure of CH3CN is almost exclusively obtained from IR spectra, as are basics of the J level structure. The large amount and the high accuracy of the rotational data improves knowledge of the J level structure considerably. Moreover, since these data extend to much higher J and K quantum numbers, they allowed us to investigate for the first time in depth local interactions between these states which occur at high K values. In particular, we have detected several interactions between v8 = 1 and 2. Notably, there is a strong Δv8 = ± 1 , ΔK = 0 , Δl = ± 3 Fermi resonance between v8 =1-1 and v8 =2+2 at K = 14 . Pronounced effects in the spectrum are also caused by resonant Δv8 = ± 1 , ΔK = ∓ 2 , Δl = ± 1 interactions between v8 = 1 and 2 at K = 13 , l = - 1 / K = 11 , l = 0 and at K = 15 , l = + 1 / K = 13 , l = + 2 . An equivalent resonant interaction occurs between K = 14 of the ground vibrational state and K = 12 , l = + 1 of v8 = 1 for which we present the first detailed account. A preliminary account was given in an earlier study on the ground vibrational state. Similar resonances were found for CH3CCH and, more recently, for CH3NC, warranting comparison of the results. From data pertaining to v8 = 2 , we also investigated rotational interactions with v4 = 1 as well as Δv8 = ± 1 , ΔK = 0 , Δl = ± 3 Fermi interactions between v8 = 2 and 3. We have derived N2- and self-broadening coefficients for the ν8 , 2ν8 -ν8 , and 2ν8 bands from previously determined ν4 values. Subsequently, we determined transition moments and intensities for the three IR bands.

  8. Symmetrical gait descriptions

    NASA Astrophysics Data System (ADS)

    Dunajewski, Adam; Dusza, Jacek J.; Rosado Muñoz, Alfredo

    2014-11-01

    The article presents a proposal for the description of human gait as a periodic and symmetric process. Firstly, the data for researches was obtained in the Laboratory of Group SATI in the School of Engineering of University of Valencia. Then, the periodical model - Mean Double Step (MDS) was made. Finally, on the basis of MDS, the symmetrical models - Left Mean Double Step and Right Mean Double Step (LMDS and RMDS) could be created. The method of various functional extensions was used. Symmetrical gait models can be used to calculate the coefficients of asymmetry at any time or phase of the gait. In this way it is possible to create asymmetry, function which better describes human gait dysfunction. The paper also describes an algorithm for calculating symmetric models, and shows exemplary results based on the experimental data.

  9. Symmetric continued fractions

    SciTech Connect

    Panprasitwech, Oranit; Laohakosol, Vichian; Chaichana, Tuangrat

    2010-11-11

    Explicit formulae for continued fractions with symmetric patterns in their partial quotients are constructed in the field of formal power series. Similar to the work of Cohn in 1996, which generalized the so-called folding lemma to {kappa}-fold symmetry, the notion of {kappa}-duplicating symmetric continued fractions is investigated using a modification of the 1995 technique due to Clemens, Merrill and Roeder.

  10. Braids, shuffles and symmetrizers

    NASA Astrophysics Data System (ADS)

    Isaev, A. P.; Ogievetsky, O. V.

    2009-07-01

    Multiplicative analogues of the shuffle elements of the braid group rings are introduced; in local representations they give rise to certain graded associative algebras (b-shuffle algebras). For the Hecke and BMW algebras, the (anti)-symmetrizers have simple expressions in terms of the multiplicative shuffles. The (anti)-symmetrizers can be expressed in terms of the highest multiplicative 1-shuffles (for the Hecke and BMW algebras) and in terms of the highest additive 1-shuffles (for the Hecke algebras). The spectra and multiplicities of eigenvalues of the operators of the multiplication by the multiplicative and additive 1-shuffles are examined. Dedicated to the memory of Aleosha Zamolodchikov.

  11. Architectural Tops

    ERIC Educational Resources Information Center

    Mahoney, Ellen

    2010-01-01

    The development of the skyscraper is an American story that combines architectural history, economic power, and technological achievement. Each city in the United States can be identified by the profile of its buildings. The design of the tops of skyscrapers was the inspiration for the students in the author's high-school ceramic class to develop…

  12. PT-symmetric kinks

    SciTech Connect

    Souza Dutra, A. de; Santos, V. G. C. S. dos; Amaro de Faria, A. C. Jr.

    2007-06-15

    Some kinks for non-Hermitian quantum field theories in 1+1 dimensions are constructed. A class of models where the soliton energies are stable and real are found. Although these kinks are not Hermitian, they are symmetric under PT transformations.

  13. PT-symmetric strings

    SciTech Connect

    Amore, Paolo; Fernández, Francisco M.; Garcia, Javier; Gutierrez, German

    2014-04-15

    We study both analytically and numerically the spectrum of inhomogeneous strings with PT-symmetric density. We discuss an exactly solvable model of PT-symmetric string which is isospectral to the uniform string; for more general strings, we calculate exactly the sum rules Z(p)≡∑{sub n=1}{sup ∞}1/E{sub n}{sup p}, with p=1,2,… and find explicit expressions which can be used to obtain bounds on the lowest eigenvalue. A detailed numerical calculation is carried out for two non-solvable models depending on a parameter, obtaining precise estimates of the critical values where pair of real eigenvalues become complex. -- Highlights: •PT-symmetric Hamiltonians exhibit real eigenvalues when PT symmetry is unbroken. •We study PT-symmetric strings with complex density. •They exhibit regions of unbroken PT symmetry. •We calculate the critical parameters at the boundaries of those regions. •There are exact real sum rules for some particular complex densities.

  14. A fitting program for molecules with two equivalent methyl tops and C2v point-group symmetry at equilibrium: Application to existing microwave, millimeter, and sub-millimeter wave measurements of acetone

    NASA Astrophysics Data System (ADS)

    Ilyushin, Vadim V.; Hougen, Jon. T.

    2013-07-01

    A program, called PAM_C2v_2tops, for fitting the high-resolution torsion-rotation spectra of molecules with two equivalent methyl rotors and C2v symmetry at equilibrium is described and applied to the spectrum of acetone [(CH3)2CO]. The G36 permutation-inversion group-theoretical considerations used in the design of the program are presented followed by a description of the structure of the program, which uses the principal axis method and a two-step diagonalization procedure. The program was used to carry out a weighted least-squares fit of 1720 microwave, millimeter-wave, and sub-millimeter-wave line frequencies of acetone that are available in the literature. The weighted standard deviation of 0.94 obtained here for a joint fit of rotational lines belonging to the ground, the lower torsional fundamental, and the higher torsional fundamental states of acetone represents significant progress in comparison with previous fitting attempts, especially for the excited torsional states.

  15. a Fitting Program for Molecules with Two Equivalent Tops and C_{2V} Point-Group Symmetry at Equilibrium: Application to Existing Microwave, Millimeter, and Sub-Millimeter Wave Measurements of Acetone

    NASA Astrophysics Data System (ADS)

    Ilyushin, Vadim V.; Hougen, Jon T.

    2013-06-01

    We will present a new theoretical tool, a program called PAM-C2v-2tops, for analysis of the high-resolution torsion-rotation spectra of molecules with two equivalent methyl rotors and C_{2V} symmetry at equilibrium. The new tool belongs to the broad class of effective Hamiltonians, is based on Longuet-Higgins' group theoretical ideas and uses G_{36} permutation-inversion group-theoretical considerations, the principal axis method and a two-step diagonalization procedure. The program was used to carry out a weighted least-squares fit of 1720 microwave, millimeter-wave, and sub-millimeter-wave line frequencies of acetone [(CH_3)_2CO] that are available in the literature. The weighted root-mean-square deviation of 0.93 obtained for a joint fit of the microwave lines belonging to the ground, the lower torsional fundamental, and the higher torsional fundamental states of acetone represents significant progress in comparison with previous fitting attempts, especially for the excited torsional states.

  16. Symmetric modular torsatron

    DOEpatents

    Rome, J.A.; Harris, J.H.

    1984-01-01

    A fusion reactor device is provided in which the magnetic fields for plasma confinement in a toroidal configuration is produced by a plurality of symmetrical modular coils arranged to form a symmetric modular torsatron referred to as a symmotron. Each of the identical modular coils is helically deformed and comprise one field period of the torsatron. Helical segments of each coil are connected by means of toroidally directed windbacks which may also provide part of the vertical field required for positioning the plasma. The stray fields of the windback segments may be compensated by toroidal coils. A variety of magnetic confinement flux surface configurations may be produced by proper modulation of the winding pitch of the helical segments of the coils, as in a conventional torsatron, winding the helix on a noncircular cross section and varying the poloidal and radial location of the windbacks and the compensating toroidal ring coils.

  17. Symmetric waterbomb origami.

    PubMed

    Chen, Yan; Feng, Huijuan; Ma, Jiayao; Peng, Rui; You, Zhong

    2016-06-01

    The traditional waterbomb origami, produced from a pattern consisting of a series of vertices where six creases meet, is one of the most widely used origami patterns. From a rigid origami viewpoint, it generally has multiple degrees of freedom, but when the pattern is folded symmetrically, the mobility reduces to one. This paper presents a thorough kinematic investigation on symmetric folding of the waterbomb pattern. It has been found that the pattern can have two folding paths under certain circumstance. Moreover, the pattern can be used to fold thick panels. Not only do the additional constraints imposed to fold the thick panels lead to single degree of freedom folding, but the folding process is also kinematically equivalent to the origami of zero-thickness sheets. The findings pave the way for the pattern being readily used to fold deployable structures ranging from flat roofs to large solar panels.

  18. Symmetric waterbomb origami

    NASA Astrophysics Data System (ADS)

    Chen, Yan; Feng, Huijuan; Ma, Jiayao; Peng, Rui; You, Zhong

    2016-06-01

    The traditional waterbomb origami, produced from a pattern consisting of a series of vertices where six creases meet, is one of the most widely used origami patterns. From a rigid origami viewpoint, it generally has multiple degrees of freedom, but when the pattern is folded symmetrically, the mobility reduces to one. This paper presents a thorough kinematic investigation on symmetric folding of the waterbomb pattern. It has been found that the pattern can have two folding paths under certain circumstance. Moreover, the pattern can be used to fold thick panels. Not only do the additional constraints imposed to fold the thick panels lead to single degree of freedom folding, but the folding process is also kinematically equivalent to the origami of zero-thickness sheets. The findings pave the way for the pattern being readily used to fold deployable structures ranging from flat roofs to large solar panels.

  19. Static cylindrically symmetric spacetimes

    NASA Astrophysics Data System (ADS)

    Fjällborg, Mikael

    2007-05-01

    We prove the existence of static solutions to the cylindrically symmetric Einstein Vlasov system, and we show that the matter cylinder has finite extension in two of the three spatial dimensions. The same results are also proved for a quite general class of equations of state for perfect fluids coupled to the Einstein equations, extending the class of equations of state considered by Bicak et al (2004 Class. Quantum Grav.21 1583). We also obtain this result for the Vlasov Poisson system.

  20. N≥ 𝟐 symmetric superpolynomials

    NASA Astrophysics Data System (ADS)

    Alarie-Vézina, L.; Lapointe, L.; Mathieu, P.

    2017-03-01

    The theory of symmetric functions has been extended to the case where each variable is paired with an anticommuting one. The resulting expressions, dubbed superpolynomials, provide the natural N =1 supersymmetric version of the classical bases of symmetric functions. Here we consider the case where more than one independent anticommuting variable is attached to each ordinary variable. First, the N =2 super-version of the monomial, elementary, homogeneous symmetric functions, as well as the power sums, is constructed systematically (using an exterior-differential formalism for the multiplicative bases), these functions being now indexed by a novel type of superpartitions. Moreover, the scalar product of power sums turns out to have a natural N =2 generalization which preserves the duality between the monomial and homogeneous bases. All these results are then generalized to an arbitrary value of N . Finally, for N =2 , the scalar product and the homogeneous functions are shown to have a one-parameter deformation, a result that prepares the ground for the yet-to-be-defined N =2 Jack superpolynomials.

  1. Wave Engine Topping Cycle Assessment

    NASA Technical Reports Server (NTRS)

    Welch, Gerard E.

    1996-01-01

    The performance benefits derived by topping a gas turbine engine with a wave engine are assessed. The wave engine is a wave rotor that produces shaft power by exploiting gas dynamic energy exchange and flow turning. The wave engine is added to the baseline turboshaft engine while keeping high-pressure-turbine inlet conditions, compressor pressure ratio, engine mass flow rate, and cooling flow fractions fixed. Related work has focused on topping with pressure-exchangers (i.e., wave rotors that provide pressure gain with zero net shaft power output); however, more energy can be added to a wave-engine-topped cycle leading to greater engine specific-power-enhancement The energy addition occurs at a lower pressure in the wave-engine-topped cycle; thus the specific-fuel-consumption-enhancement effected by ideal wave engine topping is slightly lower than that effected by ideal pressure-exchanger topping. At a component level, however, flow turning affords the wave engine a degree-of-freedom relative to the pressure-exchanger that enables a more efficient match with the baseline engine. In some cases, therefore, the SFC-enhancement by wave engine topping is greater than that by pressure-exchanger topping. An ideal wave-rotor-characteristic is used to identify key wave engine design parameters and to contrast the wave engine and pressure-exchanger topping approaches. An aerodynamic design procedure is described in which wave engine design-point performance levels are computed using a one-dimensional wave rotor model. Wave engines using various wave cycles are considered including two-port cycles with on-rotor combustion (valved-combustors) and reverse-flow and through-flow four-port cycles with heat addition in conventional burners. A through-flow wave cycle design with symmetric blading is used to assess engine performance benefits. The wave-engine-topped turboshaft engine produces 16% more power than does a pressure-exchanger-topped engine under the specified topping

  2. Top decays in extended models

    SciTech Connect

    Gaitan, R.; Miranda, O. G.; Cabral-Rosetti, L. G.

    2009-04-20

    Top quark decays are interesting as a mean to test the Standard Model (SM) predictions. The Cabbibo-Kobayashi-Maskawa (CKM)-suppressed process t{yields}cWW, and the rare decays t{yields}cZ, t{yields}H{sup 0}+c, and t{yields}c{gamma} an excellent window to probe the predictions of theories beyond the SM. We evaluate the flavor changing neutral currents (FCNC) decay t{yields}H{sup 0}+c in the context of Alternative Left-Right symmetric Models (ALRM) with extra isosinglet heavy fermions; the FCNC decays may place at tree level and are only supressed by the mixing between ordinary top and charm quarks. We also comment on the decay process t{yields}c+{gamma}, which involves radiative corrections.

  3. Optimal symmetric flight studies

    NASA Technical Reports Server (NTRS)

    Weston, A. R.; Menon, P. K. A.; Bilimoria, K. D.; Cliff, E. M.; Kelley, H. J.

    1985-01-01

    Several topics in optimal symmetric flight of airbreathing vehicles are examined. In one study, an approximation scheme designed for onboard real-time energy management of climb-dash is developed and calculations for a high-performance aircraft presented. In another, a vehicle model intermediate in complexity between energy and point-mass models is explored and some quirks in optimal flight characteristics peculiar to the model uncovered. In yet another study, energy-modelling procedures are re-examined with a view to stretching the range of validity of zeroth-order approximation by special choice of state variables. In a final study, time-fuel tradeoffs in cruise-dash are examined for the consequences of nonconvexities appearing in the classical steady cruise-dash model. Two appendices provide retrospective looks at two early publications on energy modelling and related optimal control theory.

  4. Modifications to Axially Symmetric Simulations Using New DSMC (2007) Algorithms

    NASA Technical Reports Server (NTRS)

    Liechty, Derek S.

    2008-01-01

    Several modifications aimed at improving physical accuracy are proposed for solving axially symmetric problems building on the DSMC (2007) algorithms introduced by Bird. Originally developed to solve nonequilibrium, rarefied flows, the DSMC method is now regularly used to solve complex problems over a wide range of Knudsen numbers. These new algorithms include features such as nearest neighbor collisions excluding the previous collision partners, separate collision and sampling cells, automatically adaptive variable time steps, a modified no-time counter procedure for collisions, and discontinuous and event-driven physical processes. Axially symmetric solutions require radial weighting for the simulated molecules since the molecules near the axis represent fewer real molecules than those farther away from the axis due to the difference in volume of the cells. In the present methodology, these radial weighting factors are continuous, linear functions that vary with the radial position of each simulated molecule. It is shown that how one defines the number of tentative collisions greatly influences the mean collision time near the axis. The method by which the grid is treated for axially symmetric problems also plays an important role near the axis, especially for scalar pressure. A new method to treat how the molecules are traced through the grid is proposed to alleviate the decrease in scalar pressure at the axis near the surface. Also, a modification to the duplication buffer is proposed to vary the duplicated molecular velocities while retaining the molecular kinetic energy and axially symmetric nature of the problem.

  5. {PT}-symmetric optical superlattices

    NASA Astrophysics Data System (ADS)

    Longhi, Stefano

    2014-04-01

    The spectral and localization properties of {PT}-symmetric optical superlattices, either infinitely extended or truncated at one side, are theoretically investigated, and the criteria that ensure a real energy spectrum are derived. The analysis is applied to the case of superlattices describing a complex ( {PT}-symmetric) extension of the Harper Hamiltonian in the rational case.

  6. Representation of Fuzzy Symmetric Relations

    DTIC Science & Technology

    1986-03-19

    Std Z39-18 REPRESENTATION OF FUZZY SYMMETRIC RELATIONS L. Valverde Dept. de Matematiques i Estadistica Universitat Politecnica de Catalunya Avda...REPRESENTATION OF FUZZY SYMMETRIC RELATIONS L. "Valverde* Dept. de Matematiques i Estadistica Universitat Politecnica de Catalunya Avda. Diagonal, 649

  7. Tensor species and symmetric functions.

    PubMed Central

    Méndez, M

    1991-01-01

    An equivariant representation of the symmetric group Sn (equivariant representation from here on) is defined as a particular type of tensor species. For any tensor species R the characteristic generating function of R is defined in a way that generalizes the Frobenius characters of representations of the symmetric groups. If R is an equivariant representation, then the characteristic is a homogeneous symmetric function. The combinatorial operations on equivariant representations correspond to formal operations on the respective characteristic functions. In particular, substitution of equivariant representations corresponds to plethysm of symmetric functions. Equivariant representations are constructed that have as characteristic the elementary, complete, and Schur functions. Bijective proofs are given for the formulas that connect them with the monomial symmetric functions. PMID:11607233

  8. Conformally symmetric traversable wormholes

    SciTech Connect

    Boehmer, Christian G.; Harko, Tiberiu; Lobo, Francisco S. N.

    2007-10-15

    Exact solutions of traversable wormholes are found under the assumption of spherical symmetry and the existence of a nonstatic conformal symmetry, which presents a more systematic approach in searching for exact wormhole solutions. In this work, a wide variety of solutions are deduced by considering choices for the form function, a specific linear equation of state relating the energy density and the pressure anisotropy, and various phantom wormhole geometries are explored. A large class of solutions impose that the spatial distribution of the exotic matter is restricted to the throat neighborhood, with a cutoff of the stress-energy tensor at a finite junction interface, although asymptotically flat exact solutions are also found. Using the 'volume integral quantifier', it is found that the conformally symmetric phantom wormhole geometries may, in principle, be constructed by infinitesimally small amounts of averaged null energy condition violating matter. Considering the tidal acceleration traversability conditions for the phantom wormhole geometry, specific wormhole dimensions and the traversal velocity are also deduced.

  9. Rare top quark decays in extended models

    SciTech Connect

    Gaitan, R.; Miranda, O. G.; Cabral-Rosetti, L. G.

    2006-09-25

    Flavor changing neutral currents (FCNC) decays t {yields} H0 + c, t {yields} Z + c, and H0 {yields} t + c-bar are discussed in the context of Alternative Left-Right symmetric Models (ALRM) with extra isosinglet heavy fermions where FCNC decays may take place at tree-level and are only suppressed by the mixing between ordinary top and charm quarks, which is poorly constraint by current experimental values. The non-manifest case is also briefly discussed.

  10. Topological Analyses of Symmetric Eruptive Prominences

    NASA Astrophysics Data System (ADS)

    Panasenco, O.; Martin, S. F.

    Erupting prominences (filaments) that we have analyzed from Hα Doppler data at Helio Research and from SOHO/EIT 304 Å, show strong coherency between their chirality, the direction of the vertical and lateral motions of the top of the prominences, and the directions of twisting of their legs. These coherent properties in erupting prominences occur in two patterns of opposite helicity; they constitute a form of dynamic chirality called the ``roll effect." Viewed from the positive network side as they erupt, many symmetrically-erupting dextral prominences develop rolling motion toward the observer along with right-hand helicity in the left leg and left-hand helicity in the right leg. Many symmetricaly-erupting sinistral prominences, also viewed from the positive network field side, have the opposite pattern: rolling motion at the top away from the observer, left-hand helical twist in the left leg, and right-hand twist in the right leg. We have analysed the motions seen in the famous movie of the ``Grand Daddy" erupting prominence and found that it has all the motions that define the roll effect. From our analyses of this and other symmetric erupting prominences, we show that the roll effect is an alternative to the popular hypothetical configuration of an eruptive prominence as a twisted flux rope or flux tube. Instead we find that a simple flat ribbon can be bent such that it reproduces nearly all of the observed forms. The flat ribbon is the most logical beginning topology because observed prominence spines already have this topology prior to eruption and an initial long magnetic ribbon with parallel, non-twisted threads, as a basic form, can be bent into many more and different geometrical forms than a flux rope.

  11. Top physics at CDF

    SciTech Connect

    Julia Thom

    2004-06-24

    Precision studies of top quark properties are a primary goal of the Run II physics program at the Fermilab Tevatron. Marking the first stages of this program, the CDF collaboration presents recent results on top pair production cross section, single top physics and top mass, using between 109 and 200 pb{sup -1} of Run II data.

  12. Ultracold Molecules in Crystals of Light: A Highly Tunable System for Exploring Novel Materials, Quantum Dynamics, and Quantum Complexity

    NASA Astrophysics Data System (ADS)

    Carr, Lincoln; Maeda, Kenji; Wall, Michael L.

    2015-03-01

    Ultracold molecules trapped in optical lattices present a new regime of physical chemistry and a new state of matter: complex dipolar matter. Such systems open up the prospect of tunable quantum complexity. We present models for the quantum many-body statics and dynamics of present experiments on polar bi-alkali dimer molecules. We are developing Hamiltonians and simulations for upcoming experiments on dimers beyond the alkali metals, including biologically and chemically important naturally occurring free radicals like the hydroxyl free radical (OH), as well as symmetric top polyatomic molecules like methyl fluoride (CH3F). These systems offer surprising opportunities in modeling and design of new materials. For example, symmetric top polyatomics can be used to study quantum molecular magnets and quantum liquid crystals. We use matrix-product-state (MPS) algorithms, supplemented by exact diagonalization, variational, perturbative, and other approaches. MPS algorithms not only produce experimentally measurable quantum phase diagrams but also explore the dynamical interplay between internal and external degrees of freedom inherent in complex dipolar matter. We maintain open source code (openTEBD and openMPS) available freely and used widely. Funded by NSF and AFOSR.

  13. Experimental Support for the Evolution of Symmetric Protein Architecture from a Simple Peptide Motif

    SciTech Connect

    J Lee; M Blaber

    2011-12-31

    The majority of protein architectures exhibit elements of structural symmetry, and 'gene duplication and fusion' is the evolutionary mechanism generally hypothesized to be responsible for their emergence from simple peptide motifs. Despite the central importance of the gene duplication and fusion hypothesis, experimental support for a plausible evolutionary pathway for a specific protein architecture has yet to be effectively demonstrated. To address this question, a unique 'top-down symmetric deconstruction' strategy was utilized to successfully identify a simple peptide motif capable of recapitulating, via gene duplication and fusion processes, a symmetric protein architecture (the threefold symmetric {beta}-trefoil fold). The folding properties of intermediary forms in this deconstruction agree precisely with a previously proposed 'conserved architecture' model for symmetric protein evolution. Furthermore, a route through foldable sequence-space between the simple peptide motif and extant protein fold is demonstrated. These results provide compelling experimental support for a plausible evolutionary pathway of symmetric protein architecture via gene duplication and fusion processes.

  14. Top quark physics

    SciTech Connect

    Ahmadov, A.; Azuelos, G.; Bauer, U.; Belyaev, A.; Berger, E. L.; Sullivan, Z.; Tait, T. M. P.

    2000-03-24

    The top quark, when it was finally discovered at Fermilab in 1995 completed the three-generation structure of the Standard Model (SM) and opened up the new field of top quark physics. Viewed as just another SM quark, the top quark appears to be a rather uninteresting species. Produced predominantly, in hadron-hadron collisions, through strong interactions, it decays rapidly without forming hadrons, and almost exclusively through the single mode t {r_arrow} Wb. The relevant CKM coupling V{sub tb} is already determined by the (three-generation) unitarity of the CKM matrix. Rare decays and CP violation are unmeasurable small in the SM. Yet the top quark is distinguished by its large mass, about 35 times larger than the mass of the next heavy quark, and intriguingly close to the scale of electroweak (EW) symmetry breaking. This unique property raises a number of interesting questions. Is the top quark mass generated by the Higgs mechanism as the SM predicts and is its mass related to the top-Higgs-Yukawa coupling? Or does it play an even more fundamental role in the EW symmetry breaking mechanism? If there are new particles lighter than the top quark, does the top quark decay into them? Could non-SM physics first manifest itself in non-standard couplings of the top quark which show up as anomalies in top quark production and decays? Top quark physics tries to answer these questions. Several properties of the top quark have already been examined at the Tevatron. These include studies of the kinematical properties of top production, the measurements of the top mass, of the top production cross-section, the reconstruction of t{bar t}pairs in the fully hadronic final states, the study of {tau} decays of the top quark, the reconstruction of hadronic decays of the W boson from top decays, the search for flavor changing neutral current decays, the measurement of the W helicity in top decays, and bounds on t{bar t} spin correlations. Most of these measurements are limited by

  15. Synthesis of a symmetrical dithiirane

    SciTech Connect

    Allakverdiev, M.A.; Farzaliev, V.M.; Mamedov, C.I.

    1986-04-01

    The reaction of p-xylene with epichlorohydrin in the presence of aluminum chloride gave 1,4-dimethyl-2,5-bis(1-chloro-2-hydroxypropyl) benzene, which serves as the starting compound for the synthesis of the corresponding symmetrical dithiirane.

  16. Prior Distributions on Symmetric Groups

    ERIC Educational Resources Information Center

    Gupta, Jayanti; Damien, Paul

    2005-01-01

    Fully and partially ranked data arise in a variety of contexts. From a Bayesian perspective, attention has focused on distance-based models; in particular, the Mallows model and extensions thereof. In this paper, a class of prior distributions, the "Binary Tree," is developed on the symmetric group. The attractive features of the class are: it…

  17. Supercritical Flow Past Symmetrical Airfoils.

    DTIC Science & Technology

    1980-12-01

    about quasi-elliptic airfoil sections. The method was later extended by Boerstoel [1967] to present a catalog of solutions for certain body shapes. Bauer...Lecture Notes in Economics and Mathematical Systems, Springer- Verlag, New York, 1972. Boerstoel , J. W., "A Survey of Symmetrical Transonic Potential

  18. Particle-vortex symmetric liquid

    NASA Astrophysics Data System (ADS)

    Mulligan, Michael

    2017-01-01

    We introduce an effective theory with manifest particle-vortex symmetry for disordered thin films undergoing a magnetic field-tuned superconductor-insulator transition. The theory may enable one to access both the critical properties of the strong-disorder limit, which has recently been confirmed by Breznay et al. [Proc. Natl. Acad. Sci. USA 113, 280 (2016), 10.1073/pnas.1522435113] to exhibit particle-vortex symmetric electrical response, and the nearby metallic phase discovered earlier by Mason and Kapitulnik [Phys. Rev. Lett. 82, 5341 (1999), 10.1103/PhysRevLett.82.5341] in less disordered samples. Within the effective theory, the Cooper-pair and field-induced vortex degrees of freedom are simultaneously incorporated into an electrically neutral Dirac fermion minimally coupled to a (emergent) Chern-Simons gauge field. A derivation of the theory follows upon mapping the superconductor-insulator transition to the integer quantum Hall plateau transition and the subsequent use of Son's particle-hole symmetric composite Fermi liquid. Remarkably, particle-vortex symmetric response does not require the introduction of disorder; rather, it results when the Dirac fermions exhibit vanishing Hall effect. The theory predicts approximately equal (diagonal) thermopower and Nernst signal with a deviation parameterized by the measured electrical Hall response at the symmetric point.

  19. Thermophoresis of Axially Symmetric Bodies

    DTIC Science & Technology

    2007-11-02

    Sweden Abstract. Thermophoresis of axially symmetric bodies is investigated to first order in the Knudsen-mimber, Kn. The study is made in the limit...derived. Asymptotic solutions are studied. INTRODUCTION Thermophoresis as a phenomenon has been known for a long time, and several authors have approached

  20. Spherical Tippe Tops

    ERIC Educational Resources Information Center

    Cross, Rod

    2013-01-01

    A tippe top (see Fig. 1) is usually constructed as a truncated sphere with a cylindrical peg on top, as indicated in Fig. 2(a). When spun rapidly on a horizontal surface, a tippe top spins about a vertical axis while rotating slowly about a horizontal axis until the peg touches the surface. At that point, weight is transferred to the peg, the…

  1. Dare We Teach Tops?

    ERIC Educational Resources Information Center

    Featonby, David

    2010-01-01

    "Tops" are mentioned in classical literature and references are even found in the ancient world. For many children a top is one of the first mechanical toys that they play with by themselves, yet a full appreciation of their motion is rare. My hope is that this article will stimulate the reader's interest in tops, will help with the first stages…

  2. CDF Top Physics

    DOE R&D Accomplishments Database

    Tartarelli, G. F.; CDF Collaboration

    1996-05-01

    The authors present the latest results about top physics obtained by the CDF experiment at the Fermilab Tevatron collider. The data sample used for these analysis (about 110 pb{sup{minus}1}) represents almost the entire statistics collected by CDF during four years (1992--95) of data taking. This large data size has allowed detailed studies of top production and decay properties. The results discussed here include the determination of the top quark mass, the measurement of the production cross section, the study of the kinematics of the top events and a look at top decays.

  3. CDF top physics

    SciTech Connect

    Tartarelli, G.F.; CDF Collaboration

    1996-05-01

    The authors present the latest results about top physics obtained by the CDF experiment at the Fermilab Tevatron collider. The data sample used for these analysis (about 110 pb{sup {minus}1}) represents almost the entire statistics collected by CDF during four years (1992--95) of data taking. This large data size has allowed detailed studies of top production and decay properties. The results discussed here include the determination of the top quark mass, the measurement of the production cross section, the study of the kinematics of the top events and a look at top decays.

  4. Structuring by multi-beam interference using symmetric pyramids.

    PubMed

    Lei, Ming; Yao, Baoli; Rupp, Romano A

    2006-06-12

    A method for producing optical structures using rotationally symmetric pyramids is proposed. Two-dimensional structures can be achieved using acute prisms. They form by multi-beam interference of plane waves that impinge from directions distributed symmetrically around the axis of rotational symmetry. Flat-topped pyramids provide an additional beam along the axis thus generating three-dimensional structures. Experimental results are consistent with the results of numerical simulations. The advantages of the method are simplicity of operation, low cost, ease of integration, good stability, and high transmittance. Possible applications are the fabrication of photonic micro-structures such as photonic crystals or array waveguides as well as multi-beam optical tweezers.

  5. Symmetric States Requiring System Asymmetry

    NASA Astrophysics Data System (ADS)

    Nishikawa, Takashi; Motter, Adilson E.

    2016-09-01

    Spontaneous synchronization has long served as a paradigm for behavioral uniformity that can emerge from interactions in complex systems. When the interacting entities are identical and their coupling patterns are also identical, the complete synchronization of the entire network is the state inheriting the system symmetry. As in other systems subject to symmetry breaking, such symmetric states are not always stable. Here, we report on the discovery of the converse of symmetry breaking—the scenario in which complete synchronization is not stable for identically coupled identical oscillators but becomes stable when, and only when, the oscillator parameters are judiciously tuned to nonidentical values, thereby breaking the system symmetry to preserve the state symmetry. Aside from demonstrating that diversity can facilitate and even be required for uniformity and consensus, this suggests a mechanism for convergent forms of pattern formation in which initially asymmetric patterns evolve into symmetric ones.

  6. Molecule nanoweaver

    DOEpatents

    Gerald, II; Rex E.; Klingler, Robert J.; Rathke, Jerome W.; Diaz, Rocio; Vukovic, Lela

    2009-03-10

    A method, apparatus, and system for constructing uniform macroscopic films with tailored geometric assemblies of molecules on the nanometer scale. The method, apparatus, and system include providing starting molecules of selected character, applying one or more force fields to the molecules to cause them to order and condense with NMR spectra and images being used to monitor progress in creating the desired geometrical assembly and functionality of molecules that comprise the films.

  7. HUBBLE'S TOP TEN GRAVITATIONAL LENSES

    NASA Technical Reports Server (NTRS)

    2002-01-01

    The NASA Hubble Space Telescope serendipitous survey of the sky has uncovered exotic patterns, rings, arcs and crosses that are all optical mirages produced by a gravitational lens, nature's equivalent of having giant magnifying glass in space. Shown are the top 10 lens candidates uncovered in the deepest 100 Hubble fields. Hubble's sensitivity and high resolution allow it to see faint and distant lenses that cannot be detected with ground-based telescopes whose images are blurred by Earth's atmosphere. [Top Left] - HST 01248+0351 is a lensed pair on either side of the edge-on disk lensing galaxy. [Top Center] - HST 01247+0352 is another pair of bluer lensed source images around the red spherical elliptical lensing galaxy. Two much fainter images can be seen near the detection limit which might make this a quadruple system. [Top Right] - HST 15433+5352 is a very good lens candidate with a bluer lensed source in the form of an extended arc about the redder elliptical lensing galaxy. [Middle Far Left] - HST 16302+8230 could be an 'Einstein ring' and the most intriguing lens candidate. It has been nicknamed the 'the London Underground' since it resembles that logo. [Middle Near Left] - HST 14176+5226 is the first, and brightest lens system discovered in 1995 with the Hubble telescope. This lens candidate has now been confirmed spectroscopically using large ground-based telescopes. The elliptical lensing galaxy is located 7 billion light-years away, and the lensed quasar is about 11 billion light-years distant. [Middle Near Right] - HST 12531-2914 is the second quadruple lens candidate discovered with Hubble. It is similar to the first, but appears smaller and fainter. [Middle Far Right] - HST 14164+5215 is a pair of bluish lensed images symmetrically placed around a brighter, redder galaxy. [Bottom Left] - HST 16309+8230 is an edge-on disk-like galaxy (blue arc) which has been significantly distorted by the redder lensing elliptical galaxy. [Bottom Center] - HST 12368

  8. The Top Triangle Moose

    NASA Astrophysics Data System (ADS)

    Chivukula, R. S.; Christensen, N. D.; Coleppa, B.; Simmons, E. H.

    2011-01-01

    We introduce a deconstructed model that incorporates both Higgsless and top-color mechanisms. The model alleviates the typical tension in Higgsless models between obtaining the correct top quark mass and keeping Δρ small. It does so by singling out the top quark mass generation as arising from a Yukawa coupling to an effective top-Higgs which develops a small vacuum expectation value, while electroweak symmetry breaking results largely from a Higgsless mechanism. As a result, the heavy partners of the SM fermions can be light enough to be seen at the LHC.

  9. Top Physics at CDF

    SciTech Connect

    Moon, Chang-Seong

    2011-06-01

    We present the recent results of top-quark physics using up to 6 fb{sup -1} of p{bar p} collisions at a center of mass energy of {radical}s = 1.96 TeV analyzed by the CDF collaboration. Thanks to this large data sample, precision top quark measurements are now a reality at the Tevatron. Further, several new physics signals could appear in this large dataset. We will present the latest measurements of top quark intrinsic properties as well as direct searches for new physics in the top sector.

  10. Modeling Symmetric Macromolecular Structures in Rosetta3

    PubMed Central

    DiMaio, Frank; Leaver-Fay, Andrew; Bradley, Phil; Baker, David; André, Ingemar

    2011-01-01

    Symmetric protein assemblies play important roles in many biochemical processes. However, the large size of such systems is challenging for traditional structure modeling methods. This paper describes the implementation of a general framework for modeling arbitrary symmetric systems in Rosetta3. We describe the various types of symmetries relevant to the study of protein structure that may be modeled using Rosetta's symmetric framework. We then describe how this symmetric framework is efficiently implemented within Rosetta, which restricts the conformational search space by sampling only symmetric degrees of freedom, and explicitly simulates only a subset of the interacting monomers. Finally, we describe structure prediction and design applications that utilize the Rosetta3 symmetric modeling capabilities, and provide a guide to running simulations on symmetric systems. PMID:21731614

  11. Training Top 125

    ERIC Educational Resources Information Center

    Training, 2011

    2011-01-01

    Top companies realize how vital training is to their success and continue to invest in it, even in trying times. This article presents "Training" magazine's 11th annual ranking of the top companies with employee-sponsored workforce training and development. First-time No. 1 winner Farmers Insurance puts such a premium on learning that its new…

  12. The Driven Spinning Top

    ERIC Educational Resources Information Center

    Grosu, Ioan; Featonby, David

    2016-01-01

    This driven top is quite a novelty and can, with some trials, be made using the principles outlined here. This new top has many applications in developing both understanding and skills and these are detailed in the article. Depending on reader's available time and motivation they may feel an urge to make one themselves, or simply invest a few…

  13. Training Top 125

    ERIC Educational Resources Information Center

    Training, 2012

    2012-01-01

    The best learning and development organizations support business initiatives tactically "and" help drive strategic change. Verizon did just that, earning it the No. 1 spot for the first time on the Training Top 125. Verizon and the other 2012 Top 125 winners continued to invest in training, collectively dedicating a mean of 4.52 percent of their…

  14. Top search at CDF

    SciTech Connect

    Contreras, M.; The CDF Collaboration

    1991-10-01

    We review top quark searches carried out at CDF with data collected during the 1988--1989 Collider Run. The latest analyses give a lower limit on the top quark mass of 91 GeV/c{sup 2} at the 95% confidence level, assuming Standard Model decays. 8 refs., 6 figs., 1 tab.

  15. Top physics at CDF

    SciTech Connect

    Hughes, R.E.

    1997-01-01

    We report on top physics results using a 100 pb{sup -1} data sample of p{bar p} collisions at {radical}s = 1.8 TeV collected with the Collider Detector at Fermilab (CDF). We have identified top signals in a variety of decay channels, and used these channels to extract a measurement of the top mass and production cross section. A subset of the data (67 pb{sup -1}) is used to determine M{sub top} = 176 {+-} 8(stat) {+-} 10(syst) and {sigma}(tt) = 7.6 {sub -2.0}{sup +2.4} pb. We present studies of the kinematics of t{bar t} events and extract the first direct measurement of V{sub tb}. Finally, we indicate prospects for future study of top physics at the Tevatron.

  16. Special symmetric quark mass matrices

    NASA Astrophysics Data System (ADS)

    Silva-Marcos, J. I.

    1998-12-01

    We give a procedure to construct a special class of symmetric quark mass matrices near the democratic limit of equal Yukawa couplings for each sector. It is shown that within appropriate weak-bases, the requirements of symmetry and arg[det(M)]=0 are very strong conditions, that necessarily lead to a Cabibbo angle given by Vus=sqrt(md/ms), and to Vcb~ms/mb, in first order. In addition, we prove that the recently classified ansätze, which also reproduce these mixing matrix relations, and which were based on the hypothesis of the Universal Strength for Yukawa couplings, where all Yukawa couplings have equal moduli while the flavour dependence is only in their phases, are, in fact, particular cases of the generalized symmetric quark mass matrix ansätze we construct here. In an excellent numerical example, the experimental values on all quark mixings and masses are accommodated, and the CP violation phase parameter is shown to be crucially dependent on the values of mu and Vus.

  17. PELDOR in rotationally symmetric homo-oligomers

    NASA Astrophysics Data System (ADS)

    Giannoulis, Angeliki; Ward, Richard; Branigan, Emma; Naismith, James H.; Bode, Bela E.

    2013-10-01

    Nanometre distance measurements by pulsed electron-electron double resonance (PELDOR) spectroscopy have become an increasingly important tool in structural biology. The theoretical underpinning of the experiment is well defined for systems containing two nitroxide spin-labels (spin pairs); however, recently experiments have been reported on homo-oligomeric membrane proteins consisting of up to eight spin-labelled monomers. We have explored the theory behind these systems by examining model systems based on multiple spins arranged in rotationally symmetric polygons. The results demonstrate that with a rising number of spins within the test molecule, increasingly strong distortions appear in distance distributions obtained from an analysis based on the simple spin pair approach. These distortions are significant over a range of system sizes and remain so even when random errors are introduced into the symmetry of the model. We present an alternative approach to the extraction of distances on such systems based on a minimisation that properly treats multi-spin correlations. We demonstrate the utility of this approach on a spin-labelled mutant of the heptameric Mechanosensitive Channel of Small Conductance of E. coli.

  18. Top quark mass measurement

    SciTech Connect

    Maki, Tuula

    2008-03-18

    The top quark is the heaviest elementary particle. Its mass is one of the fundamental parameters of the standard model of particle physics, and an important input to precision electroweak tests. This thesis describes three measurements of the top-quark mass in the dilepton decay channel. The dilepton events have two neutrinos in the final state; neutrinos are weakly interacting particles that cannot be detected with a multipurpose experiment. Therefore, the signal of dilepton events consists of a large amount of missing energy and momentum carried off by the neutrinos. The top-quark mass is reconstructed for each event by assuming an additional constraint from a top mass independent distribution. Template distributions are constructed from simulated samples of signal and background events, and parametrized to form continuous probability density functions. The final top-quark mass is derived using a likelihood fit to compare the reconstructed top mass distribution from data to the parametrized templates. One of the analyses uses a novel technique to add top mass information from the observed number of events by including a cross-section-constraint in the likelihood function. All measurements use data samples collected by the CDF II detector.

  19. Top physics at CDF

    SciTech Connect

    Palencia, Enrique; /Cantabria Inst. of Phys.

    2006-06-01

    The top quark is the most massive fundamental particle observed so far, and the study of its properties is interesting for several reasons ranging from its possible special role in electroweak symmetry breaking to its sensitivity to physics beyond the Standard Model (SM). This article focuses on the latest top physics results from CDF based on 320-750 pb{sup -1} of p{bar p} collision data at {radical}s = 1.96 TeV. The t{bar t} cross section and the top mass have been measured in different decay channels and using different methods. They have also searched for massive t{bar t} resonances.

  20. Probabilistic cloning of three symmetric states

    SciTech Connect

    Jimenez, O.; Bergou, J.; Delgado, A.

    2010-12-15

    We study the probabilistic cloning of three symmetric states. These states are defined by a single complex quantity, the inner product among them. We show that three different probabilistic cloning machines are necessary to optimally clone all possible families of three symmetric states. We also show that the optimal cloning probability of generating M copies out of one original can be cast as the quotient between the success probability of unambiguously discriminating one and M copies of symmetric states.

  1. Walking dynamics are symmetric (enough)

    PubMed Central

    Ankaralı, M. Mert; Sefati, Shahin; Madhav, Manu S.; Long, Andrew; Bastian, Amy J.; Cowan, Noah J.

    2015-01-01

    Many biological phenomena such as locomotion, circadian cycles and breathing are rhythmic in nature and can be modelled as rhythmic dynamical systems. Dynamical systems modelling often involves neglecting certain characteristics of a physical system as a modelling convenience. For example, human locomotion is frequently treated as symmetric about the sagittal plane. In this work, we test this assumption by examining human walking dynamics around the steady state (limit-cycle). Here, we adapt statistical cross-validation in order to examine whether there are statistically significant asymmetries and, even if so, test the consequences of assuming bilateral symmetry anyway. Indeed, we identify significant asymmetries in the dynamics of human walking, but nevertheless show that ignoring these asymmetries results in a more consistent and predictive model. In general, neglecting evident characteristics of a system can be more than a modelling convenience—it can produce a better model. PMID:26236826

  2. Top quark mass measurements

    SciTech Connect

    Hill, Christopher S.; /UC, Santa Barbara

    2004-12-01

    The top quark, with its extraordinarily large mass (nearly that of a gold atom), plays a significant role in the phenomenology of EWSB in the Standard Model. In particular, the top quark mass when combined with the W mass constrains the mass of the as yet unobserved Higgs boson. Thus, a precise determination of the mass of the top quark is a principal goal of the CDF and D0 experiments. With the data collected thus far in Runs 1 and 2 of the Tevatron, CDF and D0 have measured the top quark mass in both the lepton+jets and dilepton decay channels using a variety of complementary experimental techniques. The author presents an overview of the most recent of the measurements.

  3. Top physics: CDF results

    SciTech Connect

    K. Bloom

    2004-06-23

    The top quark plays an important role in the grand scheme of particle physics, and is also interesting on its own merits. We present recent results from CDF on top-quark physics based on 100-200 pb{sup -1} of p{bar p} collision data. We have measured the t{bar t} cross section in different decay modes using several different techniques, and are beginning our studies of top-quark properties. New analyses for this conference include a measurement of {sigma}{sub t{bar t}} in the lepton-plus-jets channel using a neural net to distinguish signal and background events, and measurements of top-quark branching fractions.

  4. PT -symmetric slowing down of decoherence

    NASA Astrophysics Data System (ADS)

    Gardas, Bartłomiej; Deffner, Sebastian; Saxena, Avadh

    2016-10-01

    We investigate P T -symmetric quantum systems ultraweakly coupled to an environment. We find that such open systems evolve under P T -symmetric, purely dephasing and unital dynamics. The dynamical map describing the evolution is then determined explicitly using a quantum canonical transformation. Furthermore, we provide an explanation of why P T -symmetric dephasing-type interactions lead to a critical slowing down of decoherence. This effect is further exemplified with an experimentally relevant system, a P T -symmetric qubit easily realizable, e.g., in optical or microcavity experiments.

  5. PT-symmetric slowing down of decoherence

    DOE PAGES

    Gardas, Bartlomiej; Deffner, Sebastian; Saxena, Avadh Behari

    2016-10-27

    Here, we invesmore » tigate PT-symmetric quantum systems ultraweakly coupled to an environment. We find that such open systems evolve under PT-symmetric, purely dephasing and unital dynamics. The dynamical map describing the evolution is then determined explicitly using a quantum canonical transformation. Furthermore, we provide an explanation of why PT-symmetric dephasing-type interactions lead to a critical slowing down of decoherence. This effect is further exemplified with an experimentally relevant system, a PT-symmetric qubit easily realizable, e.g., in optical or microcavity experiments.« less

  6. Computing symmetric colorings of the dihedral group

    NASA Astrophysics Data System (ADS)

    Zelenyuk, Yuliya

    2016-06-01

    A symmetry on a group G is a mapping G ∋ x ↦ gx-1 g ∈ G, where g ∈ G. A subset A ⊆ G is symmetric if it is invariant under some symmetry, that is, A = gA-1g. The notion of symmetry has interesting relations to enumerative combinatorics. A coloring is symmetric if χ(gx-1g) = χ(x) for some g ∈ G. We discuss an approach how to compute the number of symmetric r-colorings for any finite group. Using this approach we derive the formula for the number of symmetric r-colorings of the dihedral group D3.

  7. Top quark properties

    SciTech Connect

    Hong, Ziqing

    2014-10-31

    The top quark physics has entered the precision era. The CDF and D0 collaborations are finalizing their legacy results of the properties of the top quark after the shutdown of the Fermilab Tevatron three years ago. The ATLAS and CMS collaborations have been publishing results from the LHC Run I with 7 TeV and 8 TeV proton-proton collisions, with many more forthcoming. We present a selection of recent results produced by the Tevatron and LHC experiments.

  8. Lineage tracing quantification reveals symmetric stem cell division in Drosophila male germline stem cells.

    PubMed

    Salzmann, Viktoria; Inaba, Mayu; Cheng, Jun; Yamashita, Yukiko M

    2013-12-01

    In the homeostatic state, adult stem cells divide either symmetrically to increase the stem cell number to compensate stem cell loss, or asymmetrically to maintain the population while producing differentiated cells. We have investigated the mode of stem cell division in the testes of Drosophila melanogaster by lineage tracing and confirm the presence of symmetric stem cell division in this system. We found that the rate of symmetric division is limited to 1-2% of total germline stem cell (GSC) divisions, but it increases with expression of a cell adhesion molecule, E-cadherin, or a regulator of the actin cytoskeleton, Moesin, which may modulate adhesiveness of germ cells to the stem cell niche. Our results indicate that the decision regarding asymmetric vs. symmetric division is a dynamically regulated process that contributes to tissue homeostasis, responding to the needs of the tissue.

  9. Interstellar Molecules

    ERIC Educational Resources Information Center

    Solomon, Philip M.

    1973-01-01

    Radioastronomy reveals that clouds between the stars, once believed to consist of simple atoms, contain molecules as complex as seven atoms and may be the most massive objects in our Galaxy. (Author/DF)

  10. Modeling Molecules

    NASA Technical Reports Server (NTRS)

    2000-01-01

    The molecule modeling method known as Multibody Order (N) Dynamics, or MBO(N)D, was developed by Moldyn, Inc. at Goddard Space Flight Center through funding provided by the SBIR program. The software can model the dynamics of molecules through technology which stimulates low-frequency molecular motions and properties, such as movements among a molecule's constituent parts. With MBO(N)D, a molecule is substructured into a set of interconnected rigid and flexible bodies. These bodies replace the computation burden of mapping individual atoms. Moldyn's technology cuts computation time while increasing accuracy. The MBO(N)D technology is available as Insight II 97.0 from Molecular Simulations, Inc. Currently the technology is used to account for forces on spacecraft parts and to perform molecular analyses for pharmaceutical purposes. It permits the solution of molecular dynamics problems on a moderate workstation, as opposed to on a supercomputer.

  11. Mobius Molecules

    ERIC Educational Resources Information Center

    Eckert, J. M.

    1973-01-01

    Discusses formation of chemical molecules via Mobius strip intermediates, and concludes that many special physics-chemical properties of the fully closed circular form (1) of polyoma DNA are explainable by this topological feature. (CC)

  12. Enumerating molecules.

    SciTech Connect

    Visco, Donald Patrick, Jr.; Faulon, Jean-Loup Michel; Roe, Diana C.

    2004-04-01

    This report is a comprehensive review of the field of molecular enumeration from early isomer counting theories to evolutionary algorithms that design molecules in silico. The core of the review is a detail account on how molecules are counted, enumerated, and sampled. The practical applications of molecular enumeration are also reviewed for chemical information, structure elucidation, molecular design, and combinatorial library design purposes. This review is to appear as a chapter in Reviews in Computational Chemistry volume 21 edited by Kenny B. Lipkowitz.

  13. Continuity and Separation in Symmetric Topologies

    ERIC Educational Resources Information Center

    Harris, J.; Lynch, M.

    2007-01-01

    In this note, it is shown that in a symmetric topological space, the pairs of sets separated by the topology determine the topology itself. It is then shown that when the codomain is symmetric, functions which separate only those pairs of sets that are already separated are continuous, generalizing a result found by M. Lynch.

  14. Inversion-symmetric topological insulators

    NASA Astrophysics Data System (ADS)

    Hughes, Taylor L.; Prodan, Emil; Bernevig, B. Andrei

    2011-06-01

    We analyze translationally invariant insulators with inversion symmetry that fall outside the current established classification of topological insulators. These insulators exhibit no edge or surface modes in the energy spectrum and hence they are not edge metals when the Fermi level is in the bulk gap. However, they do exhibit protected modes in the entanglement spectrum localized on the cut between two entangled regions. Their entanglement entropy cannot be made to vanish adiabatically, and hence the insulators can be called topological. There is a direct connection between the inversion eigenvalues of the Hamiltonian band structure and the midgap states in the entanglement spectrum. The classification of protected entanglement levels is given by an integer N, which is the difference between the negative inversion eigenvalues at inversion symmetric points in the Brillouin zone, taken in sets of 2. When the Hamiltonian describes a Chern insulator or a nontrivial time-reversal invariant topological insulator, the entirety of the entanglement spectrum exhibits spectral flow. If the Chern number is zero for the former, or time reversal is broken in the latter, the entanglement spectrum does not have spectral flow, but, depending on the inversion eigenvalues, can still exhibit protected midgap bands similar to impurity bands in normal semiconductors. Although spectral flow is broken (implying the absence of real edge or surface modes in the original Hamiltonian), the midgap entanglement bands cannot be adiabatically removed, and the insulator is “topological.” We analyze the linear response of these insulators and provide proofs and examples of when the inversion eigenvalues determine a nontrivial charge polarization, a quantum Hall effect, an anisotropic three-dimensional (3D) quantum Hall effect, or a magnetoelectric polarization. In one dimension, we establish a link between the product of the inversion eigenvalues of all occupied bands at all inversion

  15. Baryon symmetric big bang cosmology

    NASA Technical Reports Server (NTRS)

    Stecker, F. W.

    1978-01-01

    Both the quantum theory and Einsteins theory of special relativity lead to the supposition that matter and antimatter were produced in equal quantities during the big bang. It is noted that local matter/antimatter asymmetries may be reconciled with universal symmetry by assuming (1) a slight imbalance of matter over antimatter in the early universe, annihilation, and a subsequent remainder of matter; (2) localized regions of excess for one or the other type of matter as an initial condition; and (3) an extremely dense, high temperature state with zero net baryon number; i.e., matter/antimatter symmetry. Attention is given to the third assumption, which is the simplest and the most in keeping with current knowledge of the cosmos, especially as pertains the universality of 3 K background radiation. Mechanisms of galaxy formation are discussed, whereby matter and antimatter might have collided and annihilated each other, or have coexisted (and continue to coexist) at vast distances. It is pointed out that baryon symmetric big bang cosmology could probably be proved if an antinucleus could be detected in cosmic radiation.

  16. Kernel mucking in top

    SciTech Connect

    LeFebvre, W.

    1994-08-01

    For many years, the popular program top has aided system administrations in examination of process resource usage on their machines. Yet few are familiar with the techniques involved in obtaining this information. Most of what is displayed by top is available only in the dark recesses of kernel memory. Extracting this information requires familiarity not only with how bytes are read from the kernel, but also what data needs to be read. The wide variety of systems and variants of the Unix operating system in today`s marketplace makes writing such a program very challenging. This paper explores the tremendous diversity in kernel information across the many platforms and the solutions employed by top to achieve and maintain ease of portability in the presence of such divergent systems.

  17. Top-ophilia

    SciTech Connect

    Quigg, Chris; /Fermilab

    2008-01-01

    Almost from the moment in June 1977 when the discovery of the Upsilon resonance revealed the existence of what we now call the bottom quark, physicists began searching for its partner. Through the years, as we established the electric charge and weak isospin of the b-quark, and detected the virtual influence of its mate, it became clear that the top quark must exist. Exactly at what mass, we couldn't say, but we knew just how top events would look. We also knew that top events would be rare--if the Tevatron could make them at all--and that picking out the events would pose a real challenge for the experimenters and their detectors.

  18. TOPS optical correlation program

    NASA Astrophysics Data System (ADS)

    Lindell, Scott D.

    1993-09-01

    Martin Marietta is conducting a TOPS optical correlation program in which several algorithms and four optical correlators involving two spatial light modulator technologies will be developed and tested. The program will culminate in 1994 with an automatic target recognition flight demonstration using a UH-1 helicopter flying a Fiber Optic Guide Missile (FOG-M) mission profile. The flight demonstration will be conducted by US Army Missile Command (MICOM) and Martin Marietta and will involve detecting, locating and tracking a M60A2 tank positioned among an array of five vehicle types. Current status of the TOPS program will be given.

  19. TOPping off meiosis.

    PubMed

    Haber, James E

    2015-02-19

    Double-strand breaks (DSBs) threaten chromosome integrity. The most accurate repair of DSBs is by homologous recombination (HR), catalyzed by recombination proteins such as Rad51. Three papers in this issue of Molecular Cell (Fasching et al., 2015; Kaur et al., 2015; Tang et al., 2015) now reveal the role of three of these proteins in budding yeast: Sgs1 (BLM homolog), Top3 (TOPIIIα homolog), and Rmi1. They demonstrate several steps where all three proteins act together, and find additional functions of the Top3-Rmi1 subcomplex that are critical for the completion of meiosis.

  20. Oriented molecule beams: Focusing and orientation of t-butyl iodide with analysis by polarized laser photofragmentation

    NASA Astrophysics Data System (ADS)

    Xu, Qi-Xun; Jung, Kyung-Hoon; Bernstein, Richard B.

    1988-08-01

    The tert-butyl iodide molecule is readily focused with the electrostatic hexapole, via its first-order Stark effect as a pseudo-symmetric top. The pulsed, seeded supersonic focused beam, characterized by =Vth/ V0 (where θ is the angle between the molecular dipole axis μ and the electric field E; ±V0 the hexapole ``rod voltage,'' and Vth the so-called threshold voltage), passes into a small homogeneous electric field in which it is oriented. The degree of laboratory orientation achieved is measured using the method of linearly polarized laser-induced photofragmentation [S. R. Gandhi, T. J. Curtiss, and R. B. Bernstein, Phys. Rev. Lett. 59, 2951 (1987)], operating (at three laser wavelengths) on the I(2P3/2) and I(2P1/2) as well as the t-C4H9 radical photofragments. The results show that the oriented beam molecules of t-butyl iodide (at a rotational temperature near 15 K) have a higher degree of orientation than the prototype CH3I molecules (JKM state-selected and focused similarly), explainable by the greater importance of the so-called hyperfine disorientation effect for the prolate symmetric top (CH3I) than for the t-C4H9I. For the latter, orientations with photofragment up-down asymmetry ratios as large as a factor of 10 can be achieved, suggesting that t-C4H9I is an excellent candidate reagent for reactive asymmetry studies.

  1. Top quark physics: Future measurements

    SciTech Connect

    Frey, R.; Vejcik, S.; Berger, E.L.

    1997-04-04

    The authors discuss the study of the top quark at future experiments and machines. Top`s large mass makes it a unique probe of physics at the natural electroweak scale. They emphasize measurements of the top quark`s mass, width, and couplings, as well as searches for rare or nonstandard decays, and discuss the complementary roles played by hadron and lepton colliders.

  2. Ten Top Tech Trends

    ERIC Educational Resources Information Center

    McLester, Susan

    2008-01-01

    In this article, the author discusses the major technical issues, products, and practices of the day. The top ten tech trends are listed and discussed. These include: (1) data mining; (2) cyberbullying; (3) 21st century skills; (4) digital content; (5) learning at leisure; (6) personal responders; (7) mobile tools; (8) bandwidth; (9) open-source…

  3. Choosing a Top Ten.

    ERIC Educational Resources Information Center

    IUCN Bulletin, 1984

    1984-01-01

    Presents an annotated list of 34 animals and 32 plants which are candidates for a list of the top 10 endangered species. Also presents the criteria used to formulate these lists. They include the conservation value (urgency prominance, biological value) and operational considerations (such as cost factors) for each species. (JN)

  4. Demonstration of a cylindrically symmetric second-order nonlinear fiber with self-assembled organic surface layers.

    PubMed

    Daengngam, Chalongrat; Hofmann, Matthias; Liu, Zhiwen; Wang, Anbo; Heflin, James R; Xu, Yong

    2011-05-23

    We report the fabrication and characterization of a cylindrically symmetric fiber structure that possesses significant and thermodynamically stable second-order nonlinearity. Such fiber structure is produced through nanoscale self-assembly of nonlinear molecules on a silica fiber taper and possesses full rotational symmetry. Despite its highly symmetric configuration, we observed significant second harmonic generation (SHG) and obtained good agreement between experimental results and theoretical predictions.

  5. Martingale Rosenthal inequalities in symmetric spaces

    SciTech Connect

    Astashkin, S V

    2014-12-31

    We establish inequalities similar to the classical Rosenthal inequalities for sequences of martingale differences in general symmetric spaces; a central role is played here by the predictable quadratic characteristic of a martingale. Bibliography: 26 titles.

  6. Reversibility of a Symmetric Linear Cellular Automata

    NASA Astrophysics Data System (ADS)

    Del Rey, A. Martín; Sánchez, G. Rodríguez

    The characterization of the size of the cellular space of a particular type of reversible symmetric linear cellular automata is introduced in this paper. Specifically, it is shown that those symmetric linear cellular with 2k + 1 cells, and whose transition matrix is a k-diagonal square band matrix with nonzero entries equal to 1 are reversible. Furthermore, in this case the inverse cellular automata are explicitly computed. Moreover, the reversibility condition is also studied for a general number of cells.

  7. Block Lanczos tridiagonalization of complex symmetric matrices

    NASA Astrophysics Data System (ADS)

    Qiao, Sanzheng; Liu, Guohong; Xu, Wei

    2005-08-01

    The classic Lanczos method is an effective method for tridiagonalizing real symmetric matrices. Its block algorithm can significantly improve performance by exploiting memory hierarchies. In this paper, we present a block Lanczos method for tridiagonalizing complex symmetric matrices. Also, we propose a novel componentwise technique for detecting the loss of orthogonality to stablize the block Lanczos algorithm. Our experiments have shown our componentwise technique can reduce the number of orthogonalizations.

  8. Lax Operator for Macdonald Symmetric Functions

    NASA Astrophysics Data System (ADS)

    Nazarov, Maxim; Sklyanin, Evgeny

    2015-07-01

    Using the Lax operator formalism, we construct a family of pairwise commuting operators such that the Macdonald symmetric functions of infinitely many variables and of two parameters q, t are their eigenfunctions. We express our operators in terms of the Hall-Littlewood symmetric functions of the variables and of the parameter t corresponding to the partitions with one part only. Our expression is based on the notion of Baker-Akhiezer function.

  9. Four tops for LHC

    NASA Astrophysics Data System (ADS)

    Alvarez, Ezequiel; Faroughy, Darius A.; Kamenik, Jernej F.; Morales, Roberto; Szynkman, Alejandro

    2017-02-01

    We design a search strategy for the Standard Model t t bar t t bar production at the LHC in the same-sign dilepton and trilepton channels. We study different signal features and, given the small expected number of signal events, we scrutinize in detail all reducible and irreducible backgrounds. Our analysis shows that by imposing a basic set of jet and lepton selection criteria, the SM pp → t t bar t t bar process could be evidenced in the near future, within Run-II, when combining both multi-lepton search channels. We argue that this search strategy should also be used as a guideline to test New Physics coupling predominantly to top-quarks. In particular, we show that a non-resonant New Physics enhancement in the four-top final state would be detectable through this search strategy. We study two top-philic simplified models of this kind, a neutral scalar boson and a Z‧, and present current and future exclusion limits on their mass and couplings.

  10. The Design and Synthesis of Highly Branched and Spherically Symmetric Fluorinated Oils and Amphiles

    PubMed Central

    Jiang, Zhong-Xing; Yu, Y. Bruce

    2007-01-01

    A new emulsifier design principle, based on concepts borrowed from protein science, is proposed. Using this principle, a class of highly branched and spherically symmetric fluorinated oils and amphiles has been designed and synthesized, for potential applications in the construction of fluorocarbon nanoparticles. The Mitsunobu reaction was employed as the key step for introducing three perfluoro-tert-butoxyl groups into pentaerythritol derivatives with excellent yields and extremely simple isolation procedures. Due to the symmetric arrangement of the fluorine atoms, each fluorinated oil or amphile molecule gives one sharp singlet 19F NMR signal. PMID:18461118

  11. Experimental support for the evolution of symmetric protein architecture from a simple peptide motif

    PubMed Central

    Lee, Jihun; Blaber, Michael

    2011-01-01

    The majority of protein architectures exhibit elements of structural symmetry, and “gene duplication and fusion” is the evolutionary mechanism generally hypothesized to be responsible for their emergence from simple peptide motifs. Despite the central importance of the gene duplication and fusion hypothesis, experimental support for a plausible evolutionary pathway for a specific protein architecture has yet to be effectively demonstrated. To address this question, a unique “top-down symmetric deconstruction” strategy was utilized to successfully identify a simple peptide motif capable of recapitulating, via gene duplication and fusion processes, a symmetric protein architecture (the threefold symmetric β-trefoil fold). The folding properties of intermediary forms in this deconstruction agree precisely with a previously proposed “conserved architecture” model for symmetric protein evolution. Furthermore, a route through foldable sequence-space between the simple peptide motif and extant protein fold is demonstrated. These results provide compelling experimental support for a plausible evolutionary pathway of symmetric protein architecture via gene duplication and fusion processes. PMID:21173271

  12. 22. Top Lateral Bracing & Top Chord, Vertical Tension Member ...

    Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

    22. Top Lateral Bracing & Top Chord, Vertical Tension Member 6, end Vertical Compression Members 5 & 4; South Swing Span; looking N. - Pacific Shortline Bridge, U.S. Route 20,spanning Missouri River, Sioux City, Woodbury County, IA

  13. Cloud top entrainment instability and cloud top distributions

    NASA Technical Reports Server (NTRS)

    Boers, Reinout; Spinhirne, James D.

    1990-01-01

    Classical cloud-top entrainment instability condition formulation is discussed. A saturation point diagram is used to investigate the details of mixing in cases where the cloud-top entrainment instability criterion is satisfied.

  14. 7. DETAIL VIEW OF TOP CHORD AND TOP CHORD CONNECTION ...

    Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

    7. DETAIL VIEW OF TOP CHORD AND TOP CHORD CONNECTION - Springfield-Des Arc Bridge, Spanning North Branch of Cadron Creek at Old Springfield-Des Arc Road (County Road 222), Springfield, Conway County, AR

  15. Top quark physics at CDF

    SciTech Connect

    Nielsen, Jason

    2004-04-30

    The existence of the top quark, discovered by CDF and D0 in 1995, has been re-established in the burgeoning dataset being collected in Run 2 of the Tevatron at Fermilab. Results from CDF on the top quark production cross section and top quark mass are consistent with the Standard Model expectations. The well-characterized top data samples will make it possible in the future to probe further for new physics in the top quark sector. This report summarizes recent CDF top quark physics results.

  16. Symmetry-Based Techniques for Qualitative Understanding of Rovibrational Effects in Spherical-Top Molecular Spectra and Dynamics

    NASA Astrophysics Data System (ADS)

    Mitchell, Justin Chadwick

    2011-12-01

    Using light to probe the structure of matter is as natural as opening our eyes. Modern physics and chemistry have turned this art into a rich science, measuring the delicate interactions possible at the molecular level. Perhaps the most commonly used tool in computational spectroscopy is that of matrix diagonalization. While this is invaluable for calculating everything from molecular structure and energy levels to dipole moments and dynamics, the process of numerical diagonalization is an opaque one. This work applies symmetry and semi-classical techniques to elucidate numerical spectral analysis for high-symmetry molecules. Semi-classical techniques, such as the Potential Energy Surfaces, have long been used to help understand molecular vibronic and rovibronic spectra and dynamics. This investigation focuses on newer semi-classical techniques that apply Rotational Energy Surfaces (RES) to rotational energy level clustering effects in high-symmetry molecules. Such clusters exist in rigid rotor molecules as well as deformable spherical tops. This study begins by using the simplicity of rigid symmetric top molecules to clarify the classical-quantum correspondence of RES semi-classical analysis and then extends it to a more precise and complete theory of modern high-resolution spectra. RES analysis is extended to molecules having more complex and higher rank tensorial rotational and rovibrational Hamiltonians than were possible to understand before. Such molecules are shown to produce an extraordinary range of rotational level clusters, corresponding to a panoply of symmetries ranging from C4v to C2 and C1 (no symmetry) with a corresponding range of new angular momentum localization and J-tunneling effects. Using RES topography analysis and the commutation duality relations between symmetry group operators in the lab-frame to those in the body-frame, it is shown how to better describe and catalog complex splittings found in rotational level clusters. Symmetry

  17. Top quark physics: Future Measurements

    SciTech Connect

    Frey, Raymond; Gerdes, David; Jaros, John; Vejcik, Steve; Berger, Edmond L.; Chivukula, R. Sekhar; Cuypers, Frank; Drell, Persis S.; Fero, Michael; Hadley, Nicholas; Han, Tao; Heinson, Ann P.; Knuteson, Bruce; Larios, Francisco; Miettinen, Hannu; Orr, Lynne H.; Peskin, Michael E.; Rizzo, Thomas; Sarid, Uri; Schmidt, Carl; Stelzer, Tim; Sullivan, Zack

    1996-12-31

    We discuss the study of the top quark at future experiments and machines. Top's large mass makes it a unique probe of physics at the natural electroweak scale. We emphasize measurements of the top quark's mass, width, and couplings, as well as searches for rare or nonstandard decays, and discuss the complementary roles played by hadron and lepton colliders.

  18. Top physics results at CDF

    SciTech Connect

    Vickey, Trevor; /Illinois U., Urbana

    2005-05-01

    The most recent results on top quark physics at CDF are reported. Measurements of cross-section and mass are presented, and the status of single top quark production searches are discussed. The results obtained from probing various top quark properties are also presented.

  19. Curly Top Disease of Tomato

    Technology Transfer Automated Retrieval System (TEKTRAN)

    Curly top disease, caused by viruses in the genus, Curtovirus, has impacted western US agriculture for over a century; and is a significant threat to tomato production. The two most abundant curtovirus species today are Beet severe curly top virus (BSCTV) and Beet mild curly top virus (BMCTV) but ot...

  20. CDF results on top

    SciTech Connect

    Beretvas, A.; CDF Collaboration

    1995-08-01

    CDF has established the existence of the top quark. Results from p{anti p} collisions at {radical}s = 1.8 TeV are presented. In the dilepton final state the authors found seven events with a background of 1.3 {+-} 0.3. In the e, {mu} + {nu} + jets channel with a b identified via a secondary vertex detector (SVX), they found twenty one events with a background of 5.5 {+-} 1.8. They measure the top quark mass to be 176 {+-} 8 (stat) {+-} 10 (syst) GeV/c{sup 2}, and the t{anti t} production cross section to be 7.6{sub {minus}2.0}{sup +2.4} pb. The integrated luminosity for the results presented in this talk is 67 pb{sup {minus}1}. The CDF detector needs to be upgraded for the next run. The integrated luminosity for the next run is expected to be more than 1,000 pb{sup {minus}1}.

  1. Top quark mass measurements

    SciTech Connect

    L. Cerrito

    2004-07-16

    Preliminary results on the measurement of the top quark mass at the Tevatron Collider are presented. In the dilepton decay channel, the CDF Collaboration measures m{sub t} = 175.0{sub -16.9}{sup +17.4}(stat.){+-}8.4(syst.) GeV/c{sup 2}, using a sample of {approx} 126 pb{sup -1} of proton-antiproton collision data at {radical}s = 1.96 TeV (Run II). In the lepton plus jets channel, the CDF Collaboration measures 177.5{sub -9.4}{sup +12.7}(stat.) {+-} 7.1(syst.) GeV/c{sup 2}, using a sample of {approx} 102 pb{sup -1} at {radical}s = 1.96 TeV. The D0 Collaboration has newly applied a likelihood technique to improve the analysis of {approx} 125 pb{sup -1} of proton-antiproton collisions at {radical}s = 1.8 TeV (Run I), with the result: m{sub t} = 180.1 {+-} 3.6(stat.) {+-}3.9(syst.) GeV/c{sup 2}. The latter is combined with all the measurements based on the data collected in Run I to yield the most recent and comprehensive experimental determination of the top quark mass: m{sub t} = 178.0 {+-} 2.7(stat.) {+-} 3.3(syst.) GeV/c{sup 2}.

  2. Top properties at the Tevatron

    SciTech Connect

    Chiarelli, G.; The CDF Collaboration

    1997-05-01

    We present the latest results associated with top properties at the Tevatron. The large data set collected in four years of running has allowed, after top discovery, the study of various top properties. The results presented here include the measurement of the CKM matrix element {vert_bar}V{sub if}{vert_bar}, the search for top FCNC, the study of properties of W in t decays and the search for heavy states decaying to tt pairs. Future measurements in top physics at the Tevatron are briefly discussed.

  3. Resolving metal-molecule interfaces at single-molecule junctions

    PubMed Central

    Komoto, Yuki; Fujii, Shintaro; Nakamura, Hisao; Tada, Tomofumi; Nishino, Tomoaki; Kiguchi, Manabu

    2016-01-01

    Electronic and structural detail at the electrode-molecule interface have a significant influence on charge transport across molecular junctions. Despite the decisive role of the metal-molecule interface, a complete electronic and structural characterization of the interface remains a challenge. This is in no small part due to current experimental limitations. Here, we present a comprehensive approach to obtain a detailed description of the metal-molecule interface in single-molecule junctions, based on current-voltage (I-V) measurements. Contrary to conventional conductance studies, this I-V approach provides a correlated statistical description of both, the degree of electronic coupling across the metal-molecule interface, and the energy alignment between the conduction orbital and the Fermi level of the electrode. This exhaustive statistical approach was employed to study single-molecule junctions of 1,4-benzenediamine (BDA), 1,4-butanediamine (C4DA), and 1,4-benzenedithiol (BDT). A single interfacial configuration was observed for both BDA and C4DA junctions, while three different interfacial arrangements were resolved for BDT. This multiplicity is due to different molecular adsorption sites on the Au surface namely on-top, hollow, and bridge. Furthermore, C4DA junctions present a fluctuating I-V curve arising from the greater conformational freedom of the saturated alkyl chain, in sharp contrast with the rigid aromatic backbone of both BDA and BDT. PMID:27221947

  4. CAST: Contraction Algorithm for Symmetric Tensors

    SciTech Connect

    Rajbhandari, Samyam; NIkam, Akshay; Lai, Pai-Wei; Stock, Kevin; Krishnamoorthy, Sriram; Sadayappan, Ponnuswamy

    2014-09-22

    Tensor contractions represent the most compute-intensive core kernels in ab initio computational quantum chemistry and nuclear physics. Symmetries in these tensor contractions makes them difficult to load balance and scale to large distributed systems. In this paper, we develop an efficient and scalable algorithm to contract symmetric tensors. We introduce a novel approach that avoids data redistribution in contracting symmetric tensors while also avoiding redundant storage and maintaining load balance. We present experimental results on two parallel supercomputers for several symmetric contractions that appear in the CCSD quantum chemistry method. We also present a novel approach to tensor redistribution that can take advantage of parallel hyperplanes when the initial distribution has replicated dimensions, and use collective broadcast when the final distribution has replicated dimensions, making the algorithm very efficient.

  5. Communication-avoiding symmetric-indefinite factorization

    SciTech Connect

    Ballard, Grey Malone; Becker, Dulcenia; Demmel, James; Dongarra, Jack; Druinsky, Alex; Peled, Inon; Schwartz, Oded; Toledo, Sivan; Yamazaki, Ichitaro

    2014-11-13

    We describe and analyze a novel symmetric triangular factorization algorithm. The algorithm is essentially a block version of Aasen's triangular tridiagonalization. It factors a dense symmetric matrix A as the product A=PLTLTPT where P is a permutation matrix, L is lower triangular, and T is block tridiagonal and banded. The algorithm is the first symmetric-indefinite communication-avoiding factorization: it performs an asymptotically optimal amount of communication in a two-level memory hierarchy for almost any cache-line size. Adaptations of the algorithm to parallel computers are likely to be communication efficient as well; one such adaptation has been recently published. As a result, the current paper describes the algorithm, proves that it is numerically stable, and proves that it is communication optimal.

  6. Communication-avoiding symmetric-indefinite factorization

    DOE PAGES

    Ballard, Grey Malone; Becker, Dulcenia; Demmel, James; ...

    2014-11-13

    We describe and analyze a novel symmetric triangular factorization algorithm. The algorithm is essentially a block version of Aasen's triangular tridiagonalization. It factors a dense symmetric matrix A as the product A=PLTLTPT where P is a permutation matrix, L is lower triangular, and T is block tridiagonal and banded. The algorithm is the first symmetric-indefinite communication-avoiding factorization: it performs an asymptotically optimal amount of communication in a two-level memory hierarchy for almost any cache-line size. Adaptations of the algorithm to parallel computers are likely to be communication efficient as well; one such adaptation has been recently published. As a result,more » the current paper describes the algorithm, proves that it is numerically stable, and proves that it is communication optimal.« less

  7. Symmetric States on the Octonionic Bloch Ball

    NASA Astrophysics Data System (ADS)

    Graydon, Matthew

    2012-02-01

    Finite-dimensional homogeneous self-dual cones arise as natural candidates for convex sets of states and effects in a variety of approaches towards understanding the foundations of quantum theory in terms of information-theoretic concepts. The positive cone of the ten-dimensional Jordan-algebraic spin factor is one particular instantiation of such a convex set in generalized frameworks for quantum theory. We consider a projection of the regular 9-simplex onto the octonionic projective line to form a highly symmetric structure of ten octonionic quantum states on the surface of the octonionic Bloch ball. A uniform subnormalization of these ten symmetric states yields a symmetric informationally complete octonionic quantum measurement. We discuss a Quantum Bayesian reformulation of octonionic quantum formalism for the description of two-dimensional physical systems. We also describe a canonical embedding of the octonionic Bloch ball into an ambient space for states in usual complex quantum theory.

  8. On symmetric and upwind TVD schemes

    NASA Technical Reports Server (NTRS)

    Yee, H. C.

    1985-01-01

    A class of explicit and implicit total variation diminishing (TVD) schemes for the compressible Euler and Navier-Stokes equations was developed. They do not generate spurious oscillations across shocks and contact discontinuities. In general, shocks can be captured within 1 to 2 grid points. For the inviscid case, these schemes are divided into upwind TVD schemes and symmetric (nonupwind) TVD schemes. The upwind TVD scheme is based on the second-order TVD scheme. The symmetric TVD scheme is a generalization of Roe's and Davis' TVD Lax-Wendroff scheme. The performance of these schemes on some viscous and inviscid airfoil steady-state calculations is investigated. The symmetric and upwind TVD schemes are compared.

  9. The Robust Assembly of Small Symmetric Nanoshells

    PubMed Central

    Wagner, Jef; Zandi, Roya

    2015-01-01

    Highly symmetric nanoshells are found in many biological systems, such as clathrin cages and viral shells. Many studies have shown that symmetric shells appear in nature as a result of the free-energy minimization of a generic interaction between their constituent subunits. We examine the physical basis for the formation of symmetric shells, and by using a minimal model, demonstrate that these structures can readily grow from the irreversible addition of identical subunits. Our model of nanoshell assembly shows that the spontaneous curvature regulates the size of the shell while the mechanical properties of the subunit determine the symmetry of the assembled structure. Understanding the minimum requirements for the formation of closed nanoshells is a necessary step toward engineering of nanocontainers, which will have far-reaching impact in both material science and medicine. PMID:26331253

  10. The Robust Assembly of Small Symmetric Nanoshells.

    PubMed

    Wagner, Jef; Zandi, Roya

    2015-09-01

    Highly symmetric nanoshells are found in many biological systems, such as clathrin cages and viral shells. Many studies have shown that symmetric shells appear in nature as a result of the free-energy minimization of a generic interaction between their constituent subunits. We examine the physical basis for the formation of symmetric shells, and by using a minimal model, demonstrate that these structures can readily grow from the irreversible addition of identical subunits. Our model of nanoshell assembly shows that the spontaneous curvature regulates the size of the shell while the mechanical properties of the subunit determine the symmetry of the assembled structure. Understanding the minimum requirements for the formation of closed nanoshells is a necessary step toward engineering of nanocontainers, which will have far-reaching impact in both material science and medicine.

  11. Top quark pair production and top quark properties at CDF

    SciTech Connect

    Moon, Chang-Seong

    2016-06-02

    We present the most recent measurements of top quark pairs production and top quark properties in proton-antiproton collisions with center-of-mass energy of 1.96 TeV using CDF II detector at the Tevatron. The combination of top pair production cross section measurements and the direct measurement of top quark width are reported. The test of Standard Model predictions for top quark decaying into $b$-quarks, performed by measuring the ratio $R$ between the top quark branching fraction to $b$-quark and the branching fraction to any type of down quark is shown. The extraction of the CKM matrix element $|V_{tb}|$ from the ratio $R$ is discussed. We also present the latest measurements on the forward-backward asymmetry ($A_{FB}$) in top anti-top quark production. With the full CDF Run II data set, the measurements are performed in top anti-top decaying to final states that contain one or two charged leptons (electrons or muons). In addition, we combine the results of the leptonic forward-backward asymmetry in $t\\bar t$ system between the two final states. All the results show deviations from the next-to-leading order (NLO) standard model (SM) calculation.

  12. Self-bending symmetric cusp beams

    SciTech Connect

    Gong, Lei; Liu, Wei-Wei; Lu, Yao; Li, Yin-Mei; Ren, Yu-Xuan

    2015-12-07

    A type of self-bending symmetric cusp beams with four accelerating intensity maxima is theoretically and experimentally presented. Distinguished from the reported regular polygon beams, the symmetric cusp beams simultaneously exhibit peculiar features of natural autofocusing and self-acceleration during propagation. Further, such beams take the shape of a fine longitudinal needle-like structure at the focal region and possess the strong ability of self-healing over obstacles. All these intriguing properties were verified experimentally. Particularly, the spatial profile of the reconstructed beam exhibits spatially sculpted optical structure with four siamesed curved arms. Thus, we anticipate that the structured beam will benefit optical guiding and optofluidics in surprising ways.

  13. All-optical symmetric ternary logic gate

    NASA Astrophysics Data System (ADS)

    Chattopadhyay, Tanay

    2010-09-01

    Symmetric ternary number (radix=3) has three logical states (1¯, 0, 1). It is very much useful in carry free arithmetical operation. Beside this, the logical operation using this type of number system is also effective in high speed computation and communication in multi-valued logic. In this literature all-optical circuits for three basic symmetrical ternary logical operations (inversion, MIN and MAX) are proposed and described. Numerical simulation verifies the theoretical model. In this present scheme the different ternary logical states are represented by different polarized state of light. Terahertz optical asymmetric demultiplexer (TOAD) based interferometric switch has been used categorically in this manuscript.

  14. Properties of a symmetric RHIC insertion

    SciTech Connect

    Lee, S.Y.

    1991-07-01

    This report evaluates the lattice functions of the symmetric insertion proposed by A.G. Ruggiero for the RHIC insertion. The crossing geometry, Inner and Outer matching sections, and chromatic properties are studied in detail. Some properties of the missing dipole dispersion correction scheme are also discussed. We found that the chromatic properties of the symmetric insertion is not better than the antisymmetric insertion. The problem is that the four family sextupole correction scheme seems not able to improve the chromatic distortion. Analytic understanding of the failure of the four family sextupole correction scheme will be very useful. 9 figs., 1 tab.

  15. Quantum fidelity of symmetric multipartite states

    NASA Astrophysics Data System (ADS)

    Neven, A.; Mathonet, P.; Gühne, O.; Bastin, T.

    2016-11-01

    For two symmetric quantum states one may be interested in maximizing the overlap under local operations applied to one of them. The question arises whether the maximal overlap can be obtained by applying the same local operation to each party. We show that for two symmetric multiqubit states and local unitary transformations this is the case; the maximal overlap can be reached by applying the same unitary matrix everywhere. For local invertible operations (stochastic local operations assisted by classical communication equivalence), however, we present counterexamples, demonstrating that considering the same operation everywhere is not enough.

  16. Observational tests of Baryon symmetric cosmology

    NASA Technical Reports Server (NTRS)

    Stecker, F. W.

    1982-01-01

    Observational evidence for Baryon symmetric (matter/antimatter) cosmology and future observational tests are reviewed. The most significant consequences of Baryon symmetric cosmology lie in the prediction of an observable cosmic background of gamma radiation from the decay of pi(0)-mesons produced in nucleon-antinucleon annihilations. Equations for the prediction of the amma ray background spectrum for the case of high redshifts are presented. The theoretical and observational plots of the background spectrum are shown to be in good agreement. Measurement of cosmic ray antiprotons and the use of high energy neutrino astronomy to look for antimatter elsewhere in the universe are also addressed.

  17. Top quark physics

    SciTech Connect

    Menzione, A.

    1995-10-01

    Most of the material presented in this report, comes from contributions to the parallel session PL20 of this conference. We summarise the experimental results of direct production of Top quarks, coming from the CDF and C0 Collaborations at Fermilab, and compare these results to what one expects within current theoretical understanding. Particular attention is given to new results such as all hadronic modes of t{bar t} decay. As far as the mass is concerned, a comparison is made with precision measurements of related quantities, coming from LEP and other experiments. An attempt is made to look at the medium-term future and understand which variables and with what accuracy one can measure them with increased integrated luminosity.

  18. Top-Higgs and top-pion phenomenology in the top triangle moose model

    NASA Astrophysics Data System (ADS)

    Chivukula, R. Sekhar; Simmons, Elizabeth H.; Coleppa, Baradhwaj; Logan, Heather E.; Martin, Adam

    2011-03-01

    We discuss the deconstructed version of a topcolor-assisted technicolor model wherein the mechanism of top quark mass generation is separated from the rest of electroweak symmetry breaking. The minimal deconstructed version of this scenario is a “triangle moose” model, where the top quark gets its mass from coupling to a top-Higgs field, while the gauge boson masses are generated from a Higgsless sector. The spectrum of the model includes scalar (top-Higgs) and pseudoscalar (top-pion) states. In this paper, we study the properties of these particles, discuss their production mechanisms and decay modes, and suggest how best to search for them at the LHC.

  19. Top-Higgs and top-pion phenomenology in the top triangle moose model

    SciTech Connect

    Chivukula, R. Sekhar; Simmons, Elizabeth H.; Coleppa, Baradhwaj; Logan, Heather E.; Martin, Adam

    2011-03-01

    We discuss the deconstructed version of a topcolor-assisted technicolor model wherein the mechanism of top quark mass generation is separated from the rest of electroweak symmetry breaking. The minimal deconstructed version of this scenario is a ''triangle moose'' model, where the top quark gets its mass from coupling to a top-Higgs field, while the gauge boson masses are generated from a Higgsless sector. The spectrum of the model includes scalar (top-Higgs) and pseudoscalar (top-pion) states. In this paper, we study the properties of these particles, discuss their production mechanisms and decay modes, and suggest how best to search for them at the LHC.

  20. Super-symmetric informationally complete measurements

    SciTech Connect

    Zhu, Huangjun

    2015-11-15

    Symmetric informationally complete measurements (SICs in short) are highly symmetric structures in the Hilbert space. They possess many nice properties which render them an ideal candidate for fiducial measurements. The symmetry of SICs is intimately connected with the geometry of the quantum state space and also has profound implications for foundational studies. Here we explore those SICs that are most symmetric according to a natural criterion and show that all of them are covariant with respect to the Heisenberg–Weyl groups, which are characterized by the discrete analog of the canonical commutation relation. Moreover, their symmetry groups are subgroups of the Clifford groups. In particular, we prove that the SIC in dimension 2, the Hesse SIC in dimension 3, and the set of Hoggar lines in dimension 8 are the only three SICs up to unitary equivalence whose symmetry groups act transitively on pairs of SIC projectors. Our work not only provides valuable insight about SICs, Heisenberg–Weyl groups, and Clifford groups, but also offers a new approach and perspective for studying many other discrete symmetric structures behind finite state quantum mechanics, such as mutually unbiased bases and discrete Wigner functions.

  1. Onthe static and spherically symmetric gravitational field

    NASA Astrophysics Data System (ADS)

    Gottlieb, Ioan; Maftei, Gheorghe; Mociutchi, Cleopatra

    Starting from a generalization of Einstein 's theory of gravitation, proposed by one of the authors (Cleopatra Mociutchi), the authors study a particular spherical symmetric case. Among other one obtain the compatibility conditions for the existence of the static and spherically symmetruic gravitational filed in the case of extended Einstein equation.

  2. Convexity and symmetrization in relativistic theories

    NASA Astrophysics Data System (ADS)

    Ruggeri, T.

    1990-09-01

    There is a strong motivation for the desire to have symmetric hyperbolic field equations in thermodynamics, because they guarantee well-posedness of Cauchy problems. A generic quasi-linear first order system of balance laws — in the non-relativistic case — can be shown to be symmetric hyperbolic, if the entropy density is concave with respect to the variables. In relativistic thermodynamics this is not so. This paper shows that there exists a scalar quantity in relativistic thermodynamics whose concavity guarantees a symmetric hyperbolic system. But that quantity — we call it —bar h — is not the entropy, although it is closely related to it. It is formed by contracting the entropy flux vector — ha with a privileged time-like congruencebar ξ _α . It is also shown that the convexity of h plus the requirement that all speeds be smaller than the speed of light c provide symmetric hyperbolic field equations for all choices of the direction of time. At this level of generality the physical meaning of —h is unknown. However, in many circumstances it is equal to the entropy. This is so, of course, in the non-relativistic limit but also in the non-dissipative relativistic fluid and even in relativistic extended thermodynamics for a non-degenerate gas.

  3. Small diameter symmetric networks from linear groups

    NASA Technical Reports Server (NTRS)

    Campbell, Lowell; Carlsson, Gunnar E.; Dinneen, Michael J.; Faber, Vance; Fellows, Michael R.; Langston, Michael A.; Moore, James W.; Multihaupt, Andrew P.; Sexton, Harlan B.

    1992-01-01

    In this note is reported a collection of constructions of symmetric networks that provide the largest known values for the number of nodes that can be placed in a network of a given degree and diameter. Some of the constructions are in the range of current potential engineering significance. The constructions are Cayley graphs of linear groups obtained by experimental computation.

  4. The deuterium puzzle in the symmetric universe

    NASA Technical Reports Server (NTRS)

    Leroy, B.; Nicolle, J. P.; Schatzman, E.

    1973-01-01

    An attempt was made to use deuterium abundance in the symmetric universe to prove that no nucleosynthesis takes place during annihilation and therefore neutrons were loss before nucleosynthesis. Data cover nucleosynthesis during the radiative era, cross section estimates, maximum abundance of He-4 at the end of nucleosynthesis area, and loss rate.

  5. PT -symmetric model of immune response

    NASA Astrophysics Data System (ADS)

    Bender, Carl M.; Ghatak, Ananya; Gianfreda, Mariagiovanna

    2017-01-01

    The study of PT -symmetric physical systems began in 1998 as a complex generalization of conventional quantum mechanics, but beginning in 2007 experiments began to be published in which the predicted PT phase transition was clearly observed in classical rather than in quantum-mechanical systems. This paper examines the classical PT phase transition in dynamical-system models that are moderately accurate representations of antigen-antibody systems. A surprising conclusion that can be drawn from these models is that it might be possible treat a serious disease in which the antigen concentration grows out of bounds (and the host dies) by injecting a small dose of a second (different) antigen. In this case a PT -symmetric analysis shows there are two possible favorable outcomes. In the unbroken-PT -symmetric phase the disease becomes chronic and is no longer lethal, while in the appropriate broken-PT -symmetric phase the concentration of lethal antigen goes to zero and the disease is completely cured.

  6. Dissociative recombination of highly symmetric polyatomic ions.

    PubMed

    Douguet, Nicolas; Orel, Ann E; Greene, Chris H; Kokoouline, Viatcheslav

    2012-01-13

    A general first-principles theory of dissociative recombination is developed for highly symmetric molecular ions and applied to H(3)O(+) and CH(3)(+), which play an important role in astrophysical, combustion, and laboratory plasma environments. The theoretical cross sections obtained for the dissociative recombination of the two ions are in good agreement with existing experimental data from storage ring experiments.

  7. Resonances for Symmetric Two-Barrier Potentials

    ERIC Educational Resources Information Center

    Fernandez, Francisco M.

    2011-01-01

    We describe a method for the accurate calculation of bound-state and resonance energies for one-dimensional potentials. We calculate the shape resonances for symmetric two-barrier potentials and compare them with those coming from the Siegert approximation, the complex scaling method and the box-stabilization method. A comparison of the…

  8. Super-symmetric informationally complete measurements

    NASA Astrophysics Data System (ADS)

    Zhu, Huangjun

    2015-11-01

    Symmetric informationally complete measurements (SICs in short) are highly symmetric structures in the Hilbert space. They possess many nice properties which render them an ideal candidate for fiducial measurements. The symmetry of SICs is intimately connected with the geometry of the quantum state space and also has profound implications for foundational studies. Here we explore those SICs that are most symmetric according to a natural criterion and show that all of them are covariant with respect to the Heisenberg-Weyl groups, which are characterized by the discrete analog of the canonical commutation relation. Moreover, their symmetry groups are subgroups of the Clifford groups. In particular, we prove that the SIC in dimension 2, the Hesse SIC in dimension 3, and the set of Hoggar lines in dimension 8 are the only three SICs up to unitary equivalence whose symmetry groups act transitively on pairs of SIC projectors. Our work not only provides valuable insight about SICs, Heisenberg-Weyl groups, and Clifford groups, but also offers a new approach and perspective for studying many other discrete symmetric structures behind finite state quantum mechanics, such as mutually unbiased bases and discrete Wigner functions.

  9. Mind Molecules

    PubMed Central

    Snyder, Solomon H.

    2011-01-01

    Scientific styles vary tremendously. For me, research is largely about the unfettered pursuit of novel ideas and experiments that can test multiple ideas in a day, not a year, an approach that I learned from my mentor Julius “Julie” Axelrod. This focus on creative conceptualizations has been my métier since working in the summers during medical school at the National Institutes of Health, during my two years in the Axelrod laboratory, and throughout my forty-five years at Johns Hopkins University School of Medicine. Equally important has been the “high” that emerges from brainstorming with my students. Nothing can compare with the eureka moments when, together, we sense new insights and, better yet, when high-risk, high-payoff experiments succeed. Although I have studied many different questions over the years, a common theme emerges: simple biochemical approaches to understanding molecular messengers, usually small molecules. Equally important has been identifying, purifying, and cloning the messengers' relevant biosynthetic, degradative, or target proteins, at all times seeking potential therapeutic relevance in the form of drugs. In the interests of brevity, this Reflections article is highly selective, and, with a few exceptions, literature citations are only of findings of our laboratory that illustrate notable themes. PMID:21543333

  10. On the Complex Symmetric and Skew-Symmetric Operators with a Simple Spectrum

    NASA Astrophysics Data System (ADS)

    Zagorodnyuk, Sergey M.

    2011-02-01

    In this paper we obtain necessary and sufficient conditions for a linear bounded operator in a Hilbert space H to have a three-diagonal complex symmetric matrix with non-zero elements on the first sub-diagonal in an orthonormal basis in H. It is shown that a set of all such operators is a proper subset of a set of all complex symmetric operators with a simple spectrum. Similar necessary and sufficient conditions are obtained for a linear bounded operator in H to have a three-diagonal complex skew-symmetric matrix with non-zero elements on the first sub-diagonal in an orthonormal basis in H.

  11. Top physics results from CDF

    SciTech Connect

    Gomez, Gervasio; /Cantabria Inst. of Phys.

    2005-05-01

    The top quark is by far the most massive fundamental particle observed so far, and the study of its properties is interesting for several reasons ranging from its possible special role in electroweak symmetry breaking to its sensitivity to physics beyond the Standard Model. They present recent top physics results from CDF based on 160-320 pb{sup -1} of p{bar p} collision data at {radical}s = 1.96 TeV. The t{bar t} cross section and the top mass have been measured in different decay channels and using different methods. they have searched for evidence of single top production, setting upper limits on its production rate. Other results shown in this conference include studies of the polarization of W bosons from top decays, a search for charged Higgs decaying from top, and a search for additional heavy t' quarks.

  12. Buckling Analysis of Anti-Symmetric Cross-Ply Laminated Composite Plates Under Different Boundary Conditions

    NASA Astrophysics Data System (ADS)

    Adim, B.; Daouadji, T. Hassaine; Abbes, B.

    2016-11-01

    The buckling analysis of anti-symmetric cross-ply laminated composite plates under different boundary conditions is examined by using a refined higher order exponential shear deformation theory. The theory, which has strong similarity with classical plate theory in many aspects, accounts for a quadratic variation of the transverse shear strains across the thickness and satisfies the zero traction boundary conditions on the top and bottom surfaces of the plate without using shear correction factors. The number of independent unknowns in the present theory is four, as against five in other shear deformation theories. In this investigation, the equations of motion for simply supported thick laminated rectangular plates are derived and obtained through the use of Hamilton's principle. The closed-form solutions of anti-symmetric cross-ply and angle-ply laminates are obtained using Navier solution. Numerical results for critical buckling loads anti-symmetric cross-ply laminated composite plates are presented. The validity of the present study is demonstrated by comparison with other higher-order solutions reported in the literature. It can be concluded that the proposed theory is accurate and simple in solving the buckling behaviors of anti-symmetric cross-ply laminated composite plates under different boundary conditions

  13. Are vacuum-filtrated reduced graphene oxide membranes symmetric?

    NASA Astrophysics Data System (ADS)

    Tang, Bo; Zhang, Lianbin; Li, Renyuan; Wu, Jinbo; Hedhili, Mohamed Neijib; Wang, Peng

    2015-12-01

    Graphene or reduced graphene oxide (rGO) membrane-based materials are promising for many advanced applications due to their exceptional properties. One of the most widely used synthesis methods for rGO membranes is vacuum filtration of graphene oxide (GO) on a filter membrane, followed by reduction, which shows great advantages such as operational convenience and good controllability. Despite vacuum-filtrated rGO membranes being widely used in many applications, a fundamental question is overlooked: are the top and bottom surfaces of the membranes formed at the interfaces with air and with the filter membrane respectively symmetric or asymmetric? This work, for the first time, reports the asymmetry of the vacuum-filtrated rGO membranes and discloses the filter membranes' physical imprint on the bottom surface of the rGO membrane, which takes place when the filter membrane surface pores have similar dimension to GO sheets. This result points out that the asymmetric surface properties should be cautiously taken into consideration while designing the surface-related applications for GO and rGO membranes.Graphene or reduced graphene oxide (rGO) membrane-based materials are promising for many advanced applications due to their exceptional properties. One of the most widely used synthesis methods for rGO membranes is vacuum filtration of graphene oxide (GO) on a filter membrane, followed by reduction, which shows great advantages such as operational convenience and good controllability. Despite vacuum-filtrated rGO membranes being widely used in many applications, a fundamental question is overlooked: are the top and bottom surfaces of the membranes formed at the interfaces with air and with the filter membrane respectively symmetric or asymmetric? This work, for the first time, reports the asymmetry of the vacuum-filtrated rGO membranes and discloses the filter membranes' physical imprint on the bottom surface of the rGO membrane, which takes place when the filter

  14. Dark matter on top

    SciTech Connect

    Gómez, M.A.; Jackson, C.B.; Shaughnessy, G. E-mail: chris@uta.edu

    2014-12-01

    We consider a simplified model of fermionic dark matter which couples exclusively to the right-handed top quark via a renormalizable interaction with a color-charged scalar. We first compute the relic abundance of this type of dark matter and investigate constraints placed on the model parameter space by the latest direct detection data. We also perform a detailed analysis for the production of dark matter at the LHC for this model. We find several kinematic variables that allow for a clean signal extraction and we show that the parameter space of this model will be well probed during LHC Run-II. Finally, we investigate the possibility of detecting this type of dark matter via its annihilations into gamma rays. We compute the continuum and the line emission (which includes a possible ''Higgs in Space!'' line) and its possible discovery by future gamma-ray telescopes. We find that the annihilation spectrum has distinctive features which may distinguish it from other models.

  15. Top Down Chemistry Versus Bottom up Chemistry

    NASA Astrophysics Data System (ADS)

    Oka, Takeshi; Witt, Adolf N.

    2016-06-01

    The idea of interstellar top down chemistry (TDC), in which molecules are produced from decomposition of larger molecules and dust in contrast to ordinary bottom up chemistry (BUC) in which molecules are produced synthetically from smaller molecules and atoms in the ISM, has been proposed in the chemistry of PAH and carbon chain molecules both for diffusea,c and dense cloudsb,d. A simple and natural idea, it must have occurred to many people and has been in the air for sometime. The validity of this hypothesis is apparent for diffuse clouds in view of the observed low abundance of small molecules and its rapid decrease with molecular size on the one hand and the high column densities of large carbon molecules demonstrated by the many intense diffuse interstellar bands (DIBs) on the other. Recent identification of C60^+ as the carrier of 5 near infrared DIBs with a high column density of 2×1013 cm-2 by Maier and others confirms the TDC. This means that the large molecules and dust produced in the high density high temperature environment of circumstellar envelopes are sufficiently stable to survive decompositions due to stellar UV radiaiton, cosmic rays, C-shocks etc. for a long time (≥ 10^7 year) of their migration to diffuse clouds and seems to disagree with the consensus in the field of interstellar grains. The stability of molecules and aggregates in the diffuse interstellar medium will be discussed. Duley, W. W. 2006, Faraday Discuss. 133, 415 Zhen,J., Castellanos, P., Paardekooper, D. M., Linnartz, H., Tielens, A. G. G. M. 2014, ApJL, 797, L30 Huang, J., Oka, T. 2015, Mol. Phys. 113, 2159 Guzmán, V. V., Pety, J., Goicoechea, J. R., Gerin, M., Roueff, E., Gratier, P., Öberg, K. I. 2015, ApJL, 800, L33 L. Ziurys has sent us many papers beginning Ziurys, L. M. 2006, PNAS 103, 12274 indicating she had long been a proponent of the idea. Campbell, E. K., Holz, M., Maier, J. P., Gerlich, D., Walker, G. A. H., Bohlender, D, 2016, ApJ, in press Draine, B. T. 2003

  16. 4. DETAIL VIEW OF TOP CHORD AND TOP CHORD CONNECTIONS ...

    Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

    4. DETAIL VIEW OF TOP CHORD AND TOP CHORD CONNECTIONS NEAR NORTH CORNER OF BRIDGE, LOOKING WEST - Springfield-Des Arc Bridge, Spanning North Branch of Cadron Creek at Old Springfield-Des Arc Road (County Road 222), Springfield, Conway County, AR

  17. Symmetric Absorber-Coupled Far-Infrared Microwave Kinetic Inductance Detector

    NASA Technical Reports Server (NTRS)

    U-yen, Kongpop (Inventor); Wollack, Edward J. (Inventor); Brown, Ari D. (Inventor); Stevenson, Thomas R. (Inventor); Patel, Amil A. (Inventor)

    2016-01-01

    The present invention relates to a symmetric absorber-coupled far-infrared microwave kinetic inductance detector including: a membrane having an absorber disposed thereon in a symmetric cross bar pattern; and a microstrip including a plurality of conductor microstrip lines disposed along all edges of the membrane, and separated from a ground plane by the membrane. The conducting microstrip lines are made from niobium, and the pattern is made from a superconducting material with a transition temperature below niobium, including one of aluminum, titanium nitride, or molybdenum nitride. The pattern is disposed on both a top and a bottom of the membrane, and creates a parallel-plate coupled transmission line on the membrane that acts as a half-wavelength resonator at readout frequencies. The parallel-plate coupled transmission line and the conductor microstrip lines form a stepped impedance resonator. The pattern provides identical power absorption for both horizontal and vertical polarization signals.

  18. Symmetric curvature descriptors for label-free analysis of DNA

    PubMed Central

    Buzio, Renato; Repetto, Luca; Giacopelli, Francesca; Ravazzolo, Roberto; Valbusa, Ugo

    2014-01-01

    High-resolution microscopy techniques such as electron microscopy, scanning tunnelling microscopy and atomic force microscopy represent well-established, powerful tools for the structural characterization of adsorbed DNA molecules at the nanoscale. Notably, the analysis of DNA contours allows mapping intrinsic curvature and flexibility along the molecular backbone. This is particularly suited to address the impact of the base-pairs sequence on the local conformation of the strands and plays a pivotal role for investigations relating the inherent DNA shape and flexibility to other functional properties. Here, we introduce novel chain descriptors aimed to characterize the local intrinsic curvature and flexibility of adsorbed DNA molecules with unknown orientation. They consist of stochastic functions that couple the curvatures of two nanosized segments, symmetrically placed on the DNA contour. We show that the fine mapping of the ensemble-averaged functions along the molecular backbone generates characteristic patterns of variation that highlight all pairs of tracts with large intrinsic curvature or enhanced flexibility. We demonstrate the practical applicability of the method for DNA chains imaged by atomic force microscopy. Our approach paves the way for the label-free comparative analysis of duplexes, aimed to detect nanoscale conformational changes of physical or biological relevance in large sample numbers. PMID:25248631

  19. An exact variational method to calculate rovibrational spectra of polyatomic molecules with large amplitude motion.

    PubMed

    Yu, Hua-Gen

    2016-08-28

    We report a new full-dimensional variational algorithm to calculate rovibrational spectra of polyatomic molecules using an exact quantum mechanical Hamiltonian. The rovibrational Hamiltonian of system is derived in a set of orthogonal polyspherical coordinates in the body-fixed frame. It is expressed in an explicitly Hermitian form. The Hamiltonian has a universal formulation regardless of the choice of orthogonal polyspherical coordinates and the number of atoms in molecule, which is suitable for developing a general program to study the spectra of many polyatomic systems. An efficient coupled-state approach is also proposed to solve the eigenvalue problem of the Hamiltonian using a multi-layer Lanczos iterative diagonalization approach via a set of direct product basis set in three coordinate groups: radial coordinates, angular variables, and overall rotational angles. A simple set of symmetric top rotational functions is used for the overall rotation whereas a potential-optimized discrete variable representation method is employed in radial coordinates. A set of contracted vibrationally diabatic basis functions is adopted in internal angular variables. Those diabatic functions are first computed using a neural network iterative diagonalization method based on a reduced-dimension Hamiltonian but only once. The final rovibrational energies are computed using a modified Lanczos method for a given total angular momentum J, which is usually fast. Two numerical applications to CH4 and H2CO are given, together with a comparison with previous results.

  20. An exact variational method to calculate rovibrational spectra of polyatomic molecules with large amplitude motion

    NASA Astrophysics Data System (ADS)

    Yu, Hua-Gen

    2016-08-01

    We report a new full-dimensional variational algorithm to calculate rovibrational spectra of polyatomic molecules using an exact quantum mechanical Hamiltonian. The rovibrational Hamiltonian of system is derived in a set of orthogonal polyspherical coordinates in the body-fixed frame. It is expressed in an explicitly Hermitian form. The Hamiltonian has a universal formulation regardless of the choice of orthogonal polyspherical coordinates and the number of atoms in molecule, which is suitable for developing a general program to study the spectra of many polyatomic systems. An efficient coupled-state approach is also proposed to solve the eigenvalue problem of the Hamiltonian using a multi-layer Lanczos iterative diagonalization approach via a set of direct product basis set in three coordinate groups: radial coordinates, angular variables, and overall rotational angles. A simple set of symmetric top rotational functions is used for the overall rotation whereas a potential-optimized discrete variable representation method is employed in radial coordinates. A set of contracted vibrationally diabatic basis functions is adopted in internal angular variables. Those diabatic functions are first computed using a neural network iterative diagonalization method based on a reduced-dimension Hamiltonian but only once. The final rovibrational energies are computed using a modified Lanczos method for a given total angular momentum J, which is usually fast. Two numerical applications to CH4 and H2CO are given, together with a comparison with previous results.

  1. A single-molecule diode

    PubMed Central

    Elbing, Mark; Ochs, Rolf; Koentopp, Max; Fischer, Matthias; von Hänisch, Carsten; Weigend, Florian; Evers, Ferdinand; Weber, Heiko B.; Mayor, Marcel

    2005-01-01

    We have designed and synthesized a molecular rod that consists of two weakly coupled electronic π -systems with mutually shifted energy levels. The asymmetry thus implied manifests itself in a current–voltage characteristic with pronounced dependence on the sign of the bias voltage, which makes the molecule a prototype for a molecular diode. The individual molecules were immobilized by sulfur–gold bonds between both electrodes of a mechanically controlled break junction, and their electronic transport properties have been investigated. The results indeed show diode-like current–voltage characteristics. In contrast to that, control experiments with symmetric molecular rods consisting of two identical π -systems did not show significant asymmetries in the transport properties. To investigate the underlying transport mechanism, phenomenological arguments are combined with calculations based on density functional theory. The theoretical analysis suggests that the bias dependence of the polarizability of the molecule feeds back into the current leading to an asymmetric shape of the current–voltage characteristics, similar to the phenomena in a semiconductor diode. PMID:15956208

  2. A single-molecule diode.

    PubMed

    Elbing, Mark; Ochs, Rolf; Koentopp, Max; Fischer, Matthias; von Hänisch, Carsten; Weigend, Florian; Evers, Ferdinand; Weber, Heiko B; Mayor, Marcel

    2005-06-21

    We have designed and synthesized a molecular rod that consists of two weakly coupled electronic pi -systems with mutually shifted energy levels. The asymmetry thus implied manifests itself in a current-voltage characteristic with pronounced dependence on the sign of the bias voltage, which makes the molecule a prototype for a molecular diode. The individual molecules were immobilized by sulfur-gold bonds between both electrodes of a mechanically controlled break junction, and their electronic transport properties have been investigated. The results indeed show diode-like current-voltage characteristics. In contrast to that, control experiments with symmetric molecular rods consisting of two identical pi-systems did not show significant asymmetries in the transport properties. To investigate the underlying transport mechanism, phenomenological arguments are combined with calculations based on density functional theory. The theoretical analysis suggests that the bias dependence of the polarizability of the molecule feeds back into the current leading to an asymmetric shape of the current-voltage characteristics, similar to the phenomena in a semiconductor diode.

  3. Properties of the Top Quark

    SciTech Connect

    Déliot, Frédéric; Hadley, Nicholas; Parke, Stephen; Schwarz, Tom

    2014-10-01

    The top quark is the heaviest known elementary particle, and it is often seen as a window to search for new physics processes in particle physics. A large program to study the top-quark properties has been performed both at the Tevatron and LHC colliders by the D0, CDF, ATLAS and CMS experiments. The most recent results are discussed in this article.

  4. Broadening and shifting of the methanol 119 {mu}m gain line of linear and circular polarization by collision with chiral molecules

    SciTech Connect

    J.S. Bakos; G. Djotyan; Zsuzsa Soerlei; J. Szigeti; D. K. Mansfield; J. Sarkozi

    2000-06-21

    Evidence of circular dichroism has been observed in the spectral properties of a gas of left-right symmetric molecules. This dichroism comes about as the result of collisions of the symmetric molecules with left-right asymmetric molecules introduced as a buffer gas. In this sense, the dichroism can be said to have been transferred from the chiral buffer molecules to the symmetric, non-chiral molecules of the background vapor. This transferred dichroism appears as broadening in the gain line of the symmetric molecule which is asymmetric with respect to the right or left handedness of a circularly polarized probe. The broadening of the 119 {mu}m line of the methanol molecule was observed using infrared-far infrared double resonance spectroscopy.

  5. Axially symmetric static sources of gravitational field

    NASA Astrophysics Data System (ADS)

    Hernandez-Pastora, J. L.; Herrera, L.; Martin, J.

    2016-12-01

    A general procedure to find static and axially symmetric, interior solutions to the Einstein equations is presented. All the so obtained solutions, verify the energy conditions for a wide range of values of the parameters, and match smoothly to some exterior solution of the Weyl family, thereby representing globally regular models describing non-spherical sources of gravitational field. In the spherically symmetric limit, all our models converge to the well known incompressible perfect fluid solution. The key stone of our approach is based on an ansatz allowing to define the interior metric in terms of the exterior metric functions evaluated at the boundary source. Some particular sources are obtained, and the physical variables of the energy-momentum tensor are calculated explicitly, as well as the geometry of the source in terms of the relativistic multipole moments. The total mass of different configurations is also calculated, it is shown to be equal to the monopole of the exterior solution.

  6. Multipartite maximally entangled states in symmetric scenarios

    NASA Astrophysics Data System (ADS)

    González-Guillén, Carlos E.

    2012-08-01

    We consider the class of (N+1)-partite states suitable for protocols where there is a powerful party, the authority, and the other N parties play the same role, namely, the state of their system lies in the symmetric Hilbert space. We show that, within this scenario, there is a “maximally entangled state” that can be transform by a local operations and classical communication protocol into any other state. In addition, we show how to use the protocol efficiently, including the construction of the state, and discuss security issues for possible applications to cryptographic protocols. As an immediate consequence we recover a sequential protocol that implements the 1-to-N symmetric cloning.

  7. Integrability of PT-symmetric dimers

    NASA Astrophysics Data System (ADS)

    Pickton, J.; Susanto, H.

    2013-12-01

    The coupled discrete linear and Kerr nonlinear Schrödinger equations with gain and loss describing transport on dimers with parity-time (PT)-symmetric potentials are considered. The model is relevant among others to experiments in optical couplers and proposals on Bose-Einstein condensates in PT-symmetric double-well potentials. It is known that the models are integrable. Here, the integrability is exploited further to construct the phase portraits of the system. A pendulum equation with a linear potential and a constant force for the phase difference between the fields is obtained, which explains the presence of unbounded solutions above a critical threshold parameter. The behavior of all solutions of the system, including changes in the topological structure of the phase plane, is then discussed.

  8. Theory of connectivity for formally symmetric operators

    PubMed Central

    Herrera, Ismael

    1977-01-01

    A previous paper introduced the notion of complete connectivity conditions and developed variational principles for diffraction problems subjected to such restrictions. Here, an abstract definition of formally symmetric operators is given and it is shown that the problem of connecting solutions of equations associated with this kind of operators leads to complete connectivity conditions. The variational principles previously developed as well as a present more general one are thus applicable. The problem of connecting solutions defined in different regions is basic for finite element formulations. Formally symmetric operators occur in many branches of science and engineering. Applications are given here to potential theory, wave propagation, elasticity, and a general class of boundary integral equations. PMID:16592459

  9. Static spherically symmetric wormholes with isotropic pressure

    NASA Astrophysics Data System (ADS)

    Cataldo, Mauricio; Liempi, Luis; Rodríguez, Pablo

    2016-06-01

    In this paper we study static spherically symmetric wormhole solutions sustained by matter sources with isotropic pressure. We show that such spherical wormholes do not exist in the framework of zero-tidal-force wormholes. On the other hand, it is shown that for the often used power-law shape function there are no spherically symmetric traversable wormholes sustained by sources with a linear equation of state p = ωρ for the isotropic pressure, independently of the form of the redshift function ϕ (r). We consider a solution obtained by Tolman at 1939 for describing static spheres of isotropic fluids, and show that it also may describe wormhole spacetimes with a power-law redshift function, which leads to a polynomial shape function, generalizing a power-law shape function, and inducing a solid angle deficit.

  10. Naturalness from a composite top?

    NASA Astrophysics Data System (ADS)

    Pierce, Aaron; Zhao, Yue

    2017-01-01

    We consider a theory with composite top quarks but an elementary Higgs boson. The hierarchy problem can be solved by supplementing TeV scale top compositeness with either supersymmetry or Higgs compositeness appearing at the multi-TeV scale. The Higgs boson couples to uncolored partons within the top quark. We study how this approach can give rise to a novel screening effect that suppresses production of the colored top partners at the LHC. Strong constraints arise from Z to overline{b}b , as well potentially from flavor physics. Independent of flavor considerations, current constraints imply a compositeness scale ≳ TeV; this implies that the model is likely tuned at the percent level. Four top quark production at the LHC is a smoking-gun probe of this scenario. New CP violation in D meson mixing is also possible.

  11. On the global behaviour of symmetric Skyrmions

    NASA Astrophysics Data System (ADS)

    Yang, Yisong

    1990-01-01

    It is shown that the chiral angle, θ( r), of the hedgehog (symmetric) Skyrmions with an arbitrary baryon number, is a strictly decreasing or increasing function. For large values of r>0, θ( r) is strictly convex or concave. As r→∞, θ( r) and θ'( r) approach their limit values at the rate O r -α for any α∈(0,2).

  12. PT symmetric Aubry-Andre model

    NASA Astrophysics Data System (ADS)

    Yuce, C.

    2014-06-01

    PT symmetric Aubry-Andre model describes an array of N coupled optical waveguides with position-dependent gain and loss. We show that the reality of the spectrum depends sensitively on the degree of quasi-periodicity for small number of lattice sites. We obtain the Hofstadter butterfly spectrum and discuss the existence of the phase transition from extended to localized states. We show that rapidly changing periodical gain/loss materials almost conserve the total intensity.

  13. Solitons in PT-symmetric nonlinear lattices

    SciTech Connect

    Abdullaev, Fatkhulla Kh.; Konotop, Vladimir V.; Zezyulin, Dmitry A.; Kartashov, Yaroslav V.

    2011-04-15

    The existence of localized modes supported by the PT-symmetric nonlinear lattices is reported. The system considered reveals unusual properties: unlike other typical dissipative systems, it possesses families (branches) of solutions, which can be parametrized by the propagation constant; relatively narrow localized modes appear to be stable, even when the conservative nonlinear lattice potential is absent; and finally, the system supports stable multipole solutions.

  14. Diagnostic and Therapeutic Advances: Distal Symmetric Polyneuropathy

    PubMed Central

    Callaghan, Brian C.; Price, Raymond S.; Feldman, Eva L.

    2016-01-01

    Importance Peripheral neuropathy is a highly prevalent and morbid condition affecting 2–7% of the population. Patients frequently suffer from pain and are at risk of falls, ulcerations, and amputations. We aimed to review recent diagnostic and therapeutic advances in peripheral neuropathy in distal symmetric polyneuropathy, the most common subtype of peripheral neuropathy. Observations and Advances Current evidence supports limited routine laboratory testing in patients with distal symmetric polyneuropathy. Patients without a known cause should have a complete blood count, comprehensive metabolic panel, B12, serum protein electrophoresis with immunofixation, fasting glucose, and a glucose tolerance test. The presence of atypical features such as asymmetry, non-length-dependence, motor predominance, acute or subacute onset, and/or prominent autonomic involvement should prompt a consultation with a neurologist or neuromuscular specialist. Electrodiagnostic tests and magnetic resonance imaging of the neuroaxis are the main drivers of the cost of the diagnostic evaluation, but evidence supporting their use is lacking. Strong evidence supports the use of tricyclic antidepressants, serotonin and norepinephrine reuptake inhibitors, and voltage-gated calcium channel ligands in the treatment of neuropathic pain. More intensive glucose control substantially reduces the incidence of distal symmetric polyneuropathy in patients with type 1 diabetes, but does not in type 2 diabetes. Conclusions and Relevance The opportunity exists to improve guideline concordant testing in distal symmetric polyneuropathy patients. Moreover, the role of electrodiagnostic tests needs to be further defined, and interventions to reduce magnetic resonance imaging use in this population are needed. Even though several efficacious medications exist for neuropathic pain treatment, pain is still under-recognized and undertreated. New disease modifying medications are needed to prevent and treat

  15. Wave equation on spherically symmetric Lorentzian metrics

    SciTech Connect

    Bokhari, Ashfaque H.; Al-Dweik, Ahmad Y.; Zaman, F. D.; Kara, A. H.; Karim, M.

    2011-06-15

    Wave equation on a general spherically symmetric spacetime metric is constructed. Noether symmetries of the equation in terms of explicit functions of {theta} and {phi} are derived subject to certain differential constraints. By restricting the metric to flat Friedman case the Noether symmetries of the wave equation are presented. Invertible transformations are constructed from a specific subalgebra of these Noether symmetries to convert the wave equation with variable coefficients to the one with constant coefficients.

  16. Scattering from a PT symmetric standing wave

    NASA Astrophysics Data System (ADS)

    Yuce, C.

    2012-09-01

    We study the Kapitza-Dirac diffraction of a free beam particle in the presence of a PT symmetric standing wave. We discuss that the momentum and total probability are not conserved in the non-Hermitian scattering process. We show that the average momentum gain/loss does not vanish over a period even if the non-Hermitian optical potential changes periodically in time. We give the resonance conditions at which large momentum transfer is produced.

  17. Time-symmetric electrodynamics and quantum measurement

    NASA Astrophysics Data System (ADS)

    Pegg, D. T.

    The application of the Wheeler-Feynman theory of time-symmetric electrodynamics to obtain definite answers to questions concerning the objective existence of quantum states in an optical EPR type of experiment is discussed. This theory allows the influence of the detector on the system being studied to be taken into account. The result is an entirely fresh understanding of experiments of the Kocher-Commins type.

  18. Compensator configurations for load currents' symmetrization

    NASA Astrophysics Data System (ADS)

    Rusinaru, D.; Manescu, L. G.; Dinu, R. C.

    2016-02-01

    This paper approaches aspects regarding the mitigation effects of asymmetries in 3-phase 3-wire networks. The measure consisting in connecting of load current symmetrization devices at the load coupling point is presented. A time-variation of compensators parameters is determined as a function of the time-recorded electrical values. The general sizing principle of the load current symmetrization reactive components is based on a simple equivalent model of the unbalanced 3-phase loads. By using these compensators a certain control of the power components transits is ensured in the network. The control is based on the variations laws of the compensators parameters as functions of the recorded electrical values: [B] = [T]·[M]. The link between compensator parameters and measured values is ensured by a transformation matrix [T] for each operation conditions of the supply network. Additional conditions for improving of energy and efficiency performance of the compensator are considered: i.e. reactive power compensation. The compensator sizing algorithm was implemented into a MATLAB environment software, which generate the time-evolution of the parameters of load current symmetrization device. The input data of application takes into account time-recording of the electrical values. By using the compensator sizing software, some results were achieved for the case of a consumer connected at 20 kV busbar of a distribution substation, during 24 hours measurement session. Even the sizing of the compensators aimed some additional network operation aspects (power factor correction) correlated with the total or major load symmetrizations, the harmonics aspects of the network values were neglected.

  19. Symmetrical peripheral gangrene associated with peripartum cardiomyopathy

    PubMed Central

    Jaryal, Ajay; Raina, Sujeet; Thakur, Surender; Sontakke, Tushar

    2013-01-01

    Symmetrical peripheral gangrene (SPG) is a rare clinical entity. It was first described in late 19th century and since then has been reported with array of medical conditions mainly those complicated with shock, sepsis, and disseminated intravascular coagulation (DIC). Here in, we describe a parturient with peripartum cardiomyopathy (PPCM) and SPG. Clinicians should be aware of this entity as early recognition can help in reducing morbidity and mortality. PMID:23984243

  20. PT-Symmetric Quantum Liouvillean Dynamics

    NASA Astrophysics Data System (ADS)

    Prosen, Tomaž

    2012-08-01

    We discuss a combination of unitary and antiunitary symmetry of quantum Liouvillean dynamics, in the context of open quantum systems, which implies a D2 symmetry of the complex Liouvillean spectrum. For sufficiently weak system-bath coupling, it implies a uniform decay rate for all coherences, i.e., off-diagonal elements of the system’s density matrix taken in the eigenbasis of the Hamiltonian. As an example, we discuss symmetrically boundary driven open XXZ spin 1/2 chains.

  1. Symmetric multilayer megampere X-pinch

    SciTech Connect

    Shelkovenko, T. A.; Pikuz, S. A.; McBride, R. D.; Knapp, P. F.; Wilhelm, G.; Sinars, D. B.; Hammer, D. A.; Orlov, N. Yu.

    2010-01-15

    Raising the power of X-ray emission from an X-pinch by increasing the pinch current to the megampere level requires the corresponding increase in the initial linear mass of the load. This can be achieved by increasing either the number of wires or their diameter. In both cases, special measures should be undertaken to prevent the formation of a complicated configuration with an uncontrolled spatial structure in the region of wire crossing, because such a structure breaks the symmetry of the neck formed in the crossing region, destabilizes plasma formation, and degrades X-ray generation. To improve the symmetry of the wire crossing region, X-pinch configurations with a regular multilayer arrangement of wires in this region were proposed and implemented. The results of experiments with various symmetric X-pinch configurations on the COBRA facility at currents of {approx}1MA are presented. It is shown that an X-pinch with a symmetric crossing region consisting of several layers of wires made of different materials can be successfully used in megampere facilities. The most efficient combinations of wires in symmetric multilayer X-pinches are found in which only one hot spot forms and that are characterized by a high and stable soft X-ray yield.

  2. Spherically symmetric thick branes cosmological evolution

    NASA Astrophysics Data System (ADS)

    Bernardini, A. E.; Cavalcanti, R. T.; da Rocha, Roldão

    2015-01-01

    Spherically symmetric time-dependent solutions for the 5D system of a scalar field canonically coupled to gravity are obtained and identified as an extension of recent results obtained by Ahmed et al. (JHEP 1404:061. arXiv:1312.3576 [hep-th], 2014). The corresponding cosmology of models with regularized branes generated by such a 5D scalar field scenario is also investigated. It has been shown that the anisotropic evolution of the warp factor and consequently the Hubble like parameter are both driven by the radial coordinate on the brane, which leads to an emergent thick brane-world scenario with spherically symmetric time dependent warp factor. Meanwhile, the separability of variables depending on fifth dimension, , which is exhibited by the equations of motion, allows one to recover the extra dimensional profiles obtained in Ahmed et al. (2014), namely the extra dimensional part of the scale (warp) factor and the scalar field dependence on . Therefore, our results are mainly concerned with the time dependence of a spherically symmetric warp factor. Besides evincing possibilities for obtaining asymmetric stable brane-world scenarios, the extra dimensional profiles here obtained can also be reduced to those ones investigated in Ahmed et al. (2014).

  3. Nonlinear waves in PT -symmetric systems

    NASA Astrophysics Data System (ADS)

    Konotop, Vladimir V.; Yang, Jianke; Zezyulin, Dmitry A.

    2016-07-01

    Recent progress on nonlinear properties of parity-time (PT )-symmetric systems is comprehensively reviewed in this article. PT symmetry started out in non-Hermitian quantum mechanics, where complex potentials obeying PT symmetry could exhibit all-real spectra. This concept later spread out to optics, Bose-Einstein condensates, electronic circuits, and many other physical fields, where a judicious balancing of gain and loss constitutes a PT -symmetric system. The natural inclusion of nonlinearity into these PT systems then gave rise to a wide array of new phenomena which have no counterparts in traditional dissipative systems. Examples include the existence of continuous families of nonlinear modes and integrals of motion, stabilization of nonlinear modes above PT -symmetry phase transition, symmetry breaking of nonlinear modes, distinctive soliton dynamics, and many others. In this article, nonlinear PT -symmetric systems arising from various physical disciplines are presented, nonlinear properties of these systems are thoroughly elucidated, and relevant experimental results are described. In addition, emerging applications of PT symmetry are pointed out.

  4. Distal symmetrical polyneuropathy: definition for clinical research.

    PubMed

    England, J D; Gronseth, G S; Franklin, G; Miller, R G; Asbury, A K; Carter, G T; Cohen, J A; Fisher, M A; Howard, J F; Kinsella, L J; Latov, N; Lewis, R A; Low, P A; Sumner, A J

    2005-01-01

    The objective of this report was to develop a case definition of "distal symmetrical polyneuropathy" to standardize and facilitate clinical research and epidemiological studies. A formalized consensus process was employed to reach agreement after a systematic review and classification of evidence from the literature. The literature indicates that symptoms alone have relatively poor diagnostic accuracy in predicting the presence of polyneuropathy; signs are better predictors of polyneuropathy than symptoms; and single abnormalities on examination are less sensitive than multiple abnormalities in predicting the presence of polyneuropathy. The combination of neuropathic symptoms, signs, and electrodiagnostic findings provides the most accurate diagnosis of distal symmetrical polyneuropathy. A set of case definitions was rank ordered by likelihood of disease. The highest likelihood of polyneuropathy (useful for clinical trials) occurs with a combination of multiple symptoms, multiple signs, and abnormal electrodiagnostic studies. A modest likelihood of polyneuropathy (useful for field or epidemiological studies) occurs with a combination of multiple symptoms and multiple signs when the results of electrodiagnostic studies are not available. A lower likelihood of polyneuropathy occurs when electrodiagnostic studies and signs are discordant. For research purposes, the best approach for defining distal symmetrical polyneuropathy is a set of case definitions rank ordered by estimated likelihood of disease. The inclusion of this formalized case definition in clinical and epidemiological research studies will ensure greater consistency of case selection.

  5. Symmetric smoothing filters from global consistency constraints.

    PubMed

    Haque, Sheikh Mohammadul; Pai, Gautam P; Govindu, Venu Madhav

    2015-05-01

    Many patch-based image denoising methods can be viewed as data-dependent smoothing filters that carry out a weighted averaging of similar pixels. It has recently been argued that these averaging filters can be improved using their doubly stochastic approximation, which are symmetric and stable smoothing operators. In this paper, we introduce a simple principle of consistency that argues that the relative similarities between pixels as imputed by the averaging matrix should be preserved in the filtered output. The resultant consistency filter has the theoretically desirable properties of being symmetric and stable, and is a generalized doubly stochastic matrix. In addition, we can also interpret our consistency filter as a specific form of Laplacian regularization. Thus, our approach unifies two strands of image denoising methods, i.e., symmetric smoothing filters and spectral graph theory. Our consistency filter provides high-quality image denoising and significantly outperforms the doubly stochastic version. We present a thorough analysis of the properties of our proposed consistency filter and compare its performance with that of other significant methods for image denoising in the literature.

  6. Are vacuum-filtrated reduced graphene oxide membranes symmetric?

    PubMed

    Tang, Bo; Zhang, Lianbin; Li, Renyuan; Wu, Jinbo; Hedhili, Mohamed Neijib; Wang, Peng

    2016-01-14

    Graphene or reduced graphene oxide (rGO) membrane-based materials are promising for many advanced applications due to their exceptional properties. One of the most widely used synthesis methods for rGO membranes is vacuum filtration of graphene oxide (GO) on a filter membrane, followed by reduction, which shows great advantages such as operational convenience and good controllability. Despite vacuum-filtrated rGO membranes being widely used in many applications, a fundamental question is overlooked: are the top and bottom surfaces of the membranes formed at the interfaces with air and with the filter membrane respectively symmetric or asymmetric? This work, for the first time, reports the asymmetry of the vacuum-filtrated rGO membranes and discloses the filter membranes' physical imprint on the bottom surface of the rGO membrane, which takes place when the filter membrane surface pores have similar dimension to GO sheets. This result points out that the asymmetric surface properties should be cautiously taken into consideration while designing the surface-related applications for GO and rGO membranes.

  7. Role of 2-D periodic symmetrical nanostructures in improving efficiency of thin film solar cells

    NASA Astrophysics Data System (ADS)

    Zhang, Wei; Jiang, Liyong; Li, Xiangyin

    2016-01-01

    We systematically investigated several different nanostructures in crystalline silicon (c-Si) thin film solar cells and then proposed a brand-new structure with two dimensional (2-D) periodic dielectric cylinders on the top and annular metal columns on bottom surface to enhance the optical harvesting. The periodic symmetrical nanostructures affect the solar cell efficiency due to the grating diffraction effect of dielectric columns and surface plasmon polaritons (SPPs) effect induced by metal nanostructures at the dielectric-metal interface. About 52.1% more optical absorption and 33.3% more power conversion efficiency are obtained, and the maximum short current reaches to 33.24 mA/cm2.

  8. Status of the top quark: Top production cross section and top properties

    SciTech Connect

    Boisvert, V.; /Rochester U.

    2006-08-01

    This report describes the latest cross section and property measurements associated with the top quark at the Tevatron Run II. The largest data sample used is 760 pb{sup -1} of integrated luminosity. Due to its large mass, the top quark might be involved in the process of electroweak symmetry breaking, making it a useful probe for signs of new physics.

  9. Nonthermal and geometric effects on the symmetric and anti-symmetric surface waves in a Lorentzian dusty plasma slab

    SciTech Connect

    Lee, Myoung-Jae; Jung, Young-Dae

    2015-02-15

    The nonthermal and geometric effects on the propagation of the surface dust acoustic waves are investigated in a Lorentzian dusty plasma slab. The symmetric and anti-symmetric dispersion modes of the dust acoustic waves are obtained by the plasma dielectric function with the spectral reflection conditions the slab geometry. The variation of the nonthermal and geometric effects on the symmetric and the anti-symmetric modes of the surface plasma waves is also discussed.

  10. Properties of the top quark

    SciTech Connect

    Jung, A. W.

    2014-09-24

    Recent measurements of top-quark properties at the LHC and the Tevatron are presented. Most recent measurements of the top quark mass have been carried out by CMS using $19.7/$fb of $\\sqrt{s} = 8$ TeV data including the study of the dependence on event kinematics. ATLAS uses the full Run I data at $\\sqrt{s} = 7$ TeV for a "3D" measurement that significantly reduces systematic uncertainties. D0 employs the full Run II data using the matrix element method to measure the top quark mass with significantly reduced systematic uncertainties. Many different measurements of the top quark exist to date and the most precise ones per decay channel per experiment have been combined into the first world combination with a relative precision of 0.44%. Latest updates of measurements of production asymmetries include the measurement of the \\ttbar production asymmetry by D0 employing the full Run II data set, by CMS and ATLAS (including the polarization of the top quark) employing both the full data set at $\\sqrt{s} = 7$ TeV. CMS uses the full $\\sqrt{s} = 8$ TeV data to measure the top quark polarization in single top production, the ratio ${\\cal R}$ of the branching fractions ${\\cal B}(t \\rightarrow Wb) / {\\cal B}(t \\rightarrow Wq)$ and to search for flavor changing neutral currents. The results from all these measurements agree well with their respective Standard Model expectation.

  11. Symmetry calculation for molecules and transition states.

    PubMed

    Vandewiele, Nick M; Van de Vijver, Ruben; Van Geem, Kevin M; Reyniers, Marie-Françoise; Marin, Guy B

    2015-01-30

    The symmetry of molecules and transition states of elementary reactions is an essential property with important implications for computational chemistry. The automated identification of symmetry by computers is a very useful tool for many applications, but often relies on the availability of three-dimensional coordinates of the atoms in the molecule and hence becomes less useful when these coordinates are a priori unavailable. This article presents a new algorithm that identifies symmetry of molecules and transition states based on an augmented graph representation of the corresponding structures, in which both topology and the presence of stereocenters are accounted for. The automorphism group order of the graph associated with the molecule or transition state is used as a starting point. A novel concept of label-stereoisomers, that is, stereoisomers that arise after labeling homomorph substituents in the original molecule so that they become distinguishable, is introduced and used to obtain the symmetry number. The algorithm is characterized by its generic nature and avoids the use of heuristic rules that would limit the applicability. The calculated symmetry numbers are in agreement with expected values for a large and diverse set of structures, ranging from asymmetric, small molecules such as fluorochlorobromomethane to highly symmetric structures found in drug discovery assays. The new algorithm opens up new possibilities for the fast screening of the degree of symmetry of large sets of molecules.

  12. Controlling polar molecules in optical lattices

    SciTech Connect

    Kotochigova, S.; Tiesinga, E.

    2006-04-15

    We theoretically investigate the interaction of polar molecules with optical lattices and microwave fields. We demonstrate the existence of frequency windows in the optical domain where the complex internal structure of the molecule does not influence the trapping potential of the lattice. In such frequency windows the Franck-Condon factors are so small that near-resonant interaction of vibrational levels of the molecule with the lattice fields have a negligible contribution to the polarizability, and light-induced decoherences are kept to a minimum. In addition, we show that microwave fields can induce a tunable dipole-dipole interaction between ground-state rotationally symmetric (J=0) molecules. A combination of a carefully chosen lattice frequency and microwave-controlled interaction between molecules will enable trapping of polar molecules in a lattice and possibly realize molecular quantum logic gates. Our results are based on ab initio relativistic electronic structure calculations of the polar KRb and RbCs molecules combined with calculations of their rovibrational motion.

  13. Australia's Next Top Fraction Model

    ERIC Educational Resources Information Center

    Gould, Peter

    2013-01-01

    Peter Gould suggests Australia's next top fraction model should be a linear model rather than an area model. He provides a convincing argument and gives examples of ways to introduce a linear model in primary classrooms.

  14. Trajectory correction propulsion for TOPS

    NASA Technical Reports Server (NTRS)

    Long, H. R.; Bjorklund, R. A.

    1972-01-01

    A blowdown-pressurized hydrazine propulsion system was selected to provide trajectory correction impulse for outer planet flyby spacecraft as the result of cost/mass/reliability tradeoff analyses. Present hydrazine component and system technology and component designs were evaluated for application to the Thermoelectric Outer Planet Spacecraft (TOPS); while general hydrazine technology was adequate, component design changes were deemed necessary for TOPS-type missions. A prototype hydrazine propulsion system was fabricated and fired nine times for a total of 1600 s to demonstrate the operation and performance of the TOPS propulsion configuration. A flight-weight trajectory correction propulsion subsystem (TCPS) was designed for the TOPS based on actual and estimated advanced components.

  15. Forum outlines top emerging technologies

    NASA Astrophysics Data System (ADS)

    Extance, Andy

    2015-04-01

    Additive manufacturing, next-generation robotics, "sense and avoid" drones that fly themselves, artificial intelligence and "neuromorphic" computing have all made it into the World Economic Forum's top 10 emerging technologies for 2015.

  16. Top 10 Products of 2011

    ERIC Educational Resources Information Center

    American School & University, 2011

    2011-01-01

    In 2011, American School & University (AS&U) showcased some of the hottest products in the industry. This article presents the top ten most requested products as determined by readers. The top one on the list is the Bulb crusher which can cut recycling costs by 50%, can hold 1,350 4-foot lamps in a single 55-gallon drum, can crush a 4-foot lamp in…

  17. Symmetrical and anti-symmetrical coherent perfect absorption for acoustic waves

    SciTech Connect

    Wei, Pengjiang; Croënne, Charles; Tak Chu, Sai; Li, Jensen

    2014-03-24

    We investigate tunable acoustic absorption enabled by the coherent control of input waves. It relies on coherent perfect absorption originally proposed in optics. By designing appropriate acoustic metamaterial structures with resonating effective bulk modulus or density, we show that complete absorption of incident waves impinging on the metamaterial can be achieved for either symmetrical or anti-symmetrical inputs in the forward and backward directions. By adjusting the relative phase between the two incident beams, absorption can be tuned effectively from unity to zero, making coherent control useful in applications like acoustic modulators, noise controllers, transducers, and switches.

  18. A synthetic method to access symmetric and non-symmetric 2-(N,N'-disubstituted)guanidinebenzothiazoles.

    PubMed

    Cruz, Alejandro; Padilla-Martínez, Itzia I; García-Báez, Efrén V

    2012-08-24

    Symmetric and non-symmetric 2-(N-H, N-methyl, N-ethylenyl and N-aryl)guanidinebenzothiazoles were synthesized from the reaction of ammonia, methylamine, pyrrolidine and aniline with dimethyl benzo[d]thiazol-2-yl-carbonodithioimidate as intermediate. The products were characterized by ¹H-, ¹³C-NMR spectroscopy and three of them by X-ray diffraction analysis. HN-phenyl protons formed intramolecular hydrogen bonds that assist the stereochemistry of the second substituent, whereas the HN-alkyl protons were involved in intermolecular hydrogen bonding.

  19. Symmetrical band-pass loudspeaker systems

    NASA Astrophysics Data System (ADS)

    Matusiak, Grzegorz Piotr

    2001-12-01

    Loudspeaker systems are analyzed in a doctoral dissertation. The dissertation concerns loudspeaker systems, which are known as subwoofers or band-pass loudspeaker systems. Their advantages include: high- quality sound reproduction in the low-frequency range, small dimensions, small nonlinear distortions and the fact that they can be placed anywhere in a room or car. Band-pass loudspeaker systems are used widely in the so- called Home Theatre as well as to provide sound in cinema, theatre, concert, discotheque, opera, operetta, philharmonic and amphitheater halls, at open-air concerts, and so on. Various designs are mass-produced by a large number of manufacturers. The study covers an analysis of band-pass loudspeaker systems to which the frequency transformation, i.e. the reactance transformation, has been applied. Since this is a symmetrical transformation, amplitude frequency responses of the studied band-pass systems are also symmetrical (logarithmic scale of a frequency). As a result, the high-pass loudspeaker system design method, known as the Thiele-Small, Benson analysis, can be employed. The investigations include the formulation of band-pass system equations (fourth, sixth and eighth-order polynomials) and the subsequent derivation of relations for the calculation of system parameters. The obtained results enable the calculation of optimum designs for prescribed alignments, e.g. (Chebyshev) equal-ripple, (Butterworth) maximally flat, or quasi-maximally flat (QB). The analysis covers fourth, sixth and eighth-order symmetrical systems. Eighth-order systems have been divided into three kinds according to three ways of physical realization. The doctoral dissertation includes band-pass loudspeaker systems, which can be designed with active or passive filters or without the filter. Designed systems consist of a loudspeaker whose front of a diaphragm is loaded with a Helmholtz resonator, i.e. an enclosure with a vent, which radiates sound outwards. The back is

  20. Uncovering the single top: observation of electroweak top quark production

    SciTech Connect

    Benitez, Jorge Armando

    2009-01-01

    The top quark is generally produced in quark and anti-quark pairs. However, the Standard Model also predicts the production of only one top quark which is mediated by the electroweak interaction, known as 'Single Top'. Single Top quark production is important because it provides a unique and direct way to measure the CKM matrix element Vtb, and can be used to explore physics possibilities beyond the Standard Model predictions. This dissertation presents the results of the observation of Single Top using 2.3 fb-1 of Data collected with the D0 detector at the Fermilab Tevatron collider. The analysis includes the Single Top muon+jets and electron+jets final states and employs Boosted Decision Tress as a method to separate the signal from the background. The resulting Single Top cross section measurement is: (1) σ(p$\\bar{p}$→ tb + X, tqb + X) = 3.74-0.74+0.95 pb, where the errors include both statistical and systematic uncertainties. The probability to measure a cross section at this value or higher in the absence of signal is p = 1.9 x 10-6. This corresponds to a standard deviation Gaussian equivalence of 4.6. When combining this result with two other analysis methods, the resulting cross section measurement is: (2) σ(p$\\bar{p}$ → tb + X, tqb + X) = 3.94 ± 0.88 pb, and the corresponding measurement significance is 5.0 standard deviations.

  1. Symmetric missile dynamic instabilities: A review

    NASA Astrophysics Data System (ADS)

    Murphy, C. H.

    1980-03-01

    Dynamic instabilities observed for symmetric missiles and projectiles arise from a large variety of causes. These include unstable linear damping moments, and different nonlinear in-plane and out-of-plane damping moments for nonspinning re-entry vehicles, nonlinear Magnus moments for spinning missiles, and internal resonance with moving payload components. If aerodynamic trim is present, linear spin-yaw resonance can occur as well as nonlinear subharmonic motions and a number of other limit motions. This report gives a complete survey of these possibilities with a number of actual case histories.

  2. Symmetric Toeplitz-Structured Compressed Sensing Matrices

    NASA Astrophysics Data System (ADS)

    Huang, Tao; Fan, Yi-Zheng; Zhu, Ming

    2015-11-01

    How to construct a suitable measurement matrix is an important topic in compressed sensing. A significant part of the recent work is that the measurement matrices are not completely random on the entries but exhibit some considerable structures. In this paper, we proved that a symmetric Toeplitz matrix and its variant can be used as measurement matrices and recovery signal with high probability. Compared with random matrices (e.g. Gaussian and Bernoulli matrices) and some structured matrices (e.g. Toeplitz and circulant matrices), we need to generate fewer independent entries to obtain the measurement matrix while the effectiveness of the recovery keeps good.

  3. Scalar resonances in axially symmetric spacetimes

    NASA Astrophysics Data System (ADS)

    Ranea-Sandoval, Ignacio F.; Vucetich, Héctor

    2015-03-01

    We study properties of resonant solutions to the scalar wave equation in several axially symmetric spacetimes. We prove that nonaxial resonant modes do not exist neither in the Lanczos dust cylinder, the extreme (2 + 1) dimensional Bañados-Taitelboim-Zanelli (BTZ) spacetime nor in a class of simple rotating wormhole solutions. Moreover, we find unstable solutions to the wave equation in the Lanczos dust cylinder and in the r2 < 0 region of the extreme (2 + 1) dimensional BTZ spacetime, two solutions that possess closed timelike curves. Similarities with previous results obtained for the Kerr spacetime are explored.

  4. Quantum asymmetric cryptography with symmetric keys

    NASA Astrophysics Data System (ADS)

    Gao, Fei; Wen, Qiaoyan; Qin, Sujuan; Zhu, Fuchen

    2009-12-01

    Based on quantum encryption, we present a new idea for quantum public-key cryptography (QPKC) and construct a whole theoretical framework of a QPKC system. We show that the quantum-mechanical nature renders it feasible and reasonable to use symmetric keys in such a scheme, which is quite different from that in conventional public-key cryptography. The security of our scheme is analyzed and some features are discussed. Furthermore, the state-estimation attack to a prior QPKC scheme is demonstrated.

  5. Synthesis of controllers for symmetric systems

    NASA Astrophysics Data System (ADS)

    Ameur Abid, Chiheb; Zouari, Belhassen

    2010-11-01

    This article deals with supervisory control problem for coloured Petri (CP) nets. Considering a CP-net, we build a condensed version of the ordinary state-space, namely the symbolic reachability graph (SRG). This latter graph allows to cope with state-space explosion problem for symmetric systems. The control specification can be expressed in terms of either forbidden states or forbidden sequences of transitions. According to these specifications, we derive the controller by applying the theory of regions on the basis of the SRG. Thanks to expressiveness power of CP-nets, the obtained controller to be connected to the plant model is reduced to one single place.

  6. Type-dependent stochastic Ising model describing the dynamics of a non-symmetric feedback module.

    PubMed

    Gonzalez-Navarrete, Manuel

    2016-10-01

    We study an alternative approach to model the dynamical behaviors of biological feedback loop, that is, a type-dependent spin system, this class of stochastic models was introduced by Fernández et. al [13], and are useful since take account to inherent variability of gene expression. We analyze a non-symmetric feedback module being an extension for the repressilator, the first synthetic biological oscillator, invented by Elowitz and Leibler [7]. We consider a mean-field dynamics for a type-dependent Ising model, and then study the empirical-magnetization vector representing concentration of molecules. We apply a convergence result from stochastic jump processes to deterministic trajectories and present a bifurcation analysis for the associated dynamical system. We show that non-symmetric module under study can exhibit very rich behaviours, including the empirical oscillations described by repressilator.

  7. Breaking of symmetrical charge distribution in xanthylocyanine chromophores detecting by their absorption spectra

    NASA Astrophysics Data System (ADS)

    Vasyluk, S. V.; Viniychuk, O. O.; Poronik, Ye. M.; Kovtun, Yu. P.; Shandura, M. P.; Yashchuk, V. M.; Kachkovsky, O. D.

    2011-03-01

    A detailed experimental investigation and quantum-chemical analysis of symmetrical cyanines with xanthylium and its substituted derivatives and with different polymethine chain (containing 1 and 2 vinylene groups) have been performed with the goal of understanding the nature of the electronic transitions in molecules. It is established electronic transitions in carbocyanines are similar to that in the typical Brooker's cyanines. In contrast, the absorption spectra of dicarbocyanines demonstrate a strong solvent dependence and substantial band broadening represented by the growth of the short wavelength shoulder. Basing on the results of the quantum-chemical calculation and conception of the mobile solitonic-like charge waves, we have concluded that the dicarbocyanines exist in two charged forms in the ground state with symmetrical and unsymmetrical distributions of the charge density. These are the examples of the cationic cyanines with the shortest chain when the symmetry breaking occurs.

  8. SW New Mexico Oil Well Formation Tops

    SciTech Connect

    Shari Kelley

    2015-10-21

    Rock formation top picks from oil wells from southwestern New Mexico from scout cards and other sources. There are differing formation tops interpretations for some wells, so for those wells duplicate formation top data are presented in this file.

  9. Electroweak Baryogenesis in R-symmetric Supersymmetry

    SciTech Connect

    Fok, R.; Kribs, Graham D.; Martin, Adam; Tsai, Yuhsin

    2013-03-01

    We demonstrate that electroweak baryogenesis can occur in a supersymmetric model with an exact R-symmetry. The minimal R-symmetric supersymmetric model contains chiral superfields in the adjoint representation, giving Dirac gaugino masses, and an additional set of "R-partner" Higgs superfields, giving R-symmetric \\mu-terms. New superpotential couplings between the adjoints and the Higgs fields can simultaneously increase the strength of the electroweak phase transition and provide additional tree-level contributions to the lightest Higgs mass. Notably, no light stop is present in this framework, and in fact, we require both stops to be above a few TeV to provide sufficient radiative corrections to the lightest Higgs mass to bring it up to 125 GeV. Large CP-violating phases in the gaugino/higgsino sector allow us to match the baryon asymmetry of the Universe with no constraints from electric dipole moments due to R-symmetry. We briefly discuss some of the more interesting phenomenology, particularly of the of the lightest CP-odd scalar.

  10. Fast numerical determination of symmetric sparsity patterns

    SciTech Connect

    Carter, R.G.

    1994-08-01

    The author considers a function g: {Re}{sup n} {yields} {Re}{sup n} for which the Jacobian is symmetric and sparse. Such functions often arise, for instance, in numerical optimization, where g is the gradient of some objective function f so that the Jacobian of g is the Hessian of f. In many such applications one can generate extremely efficient algorithms by taking advantage of the sparsity structure of the problem if this pattern is known a priori. Unfortunately, determining such sparsity structures by hand is often difficult and prone to error. If one suspects a mistake has been made, or if g is a {open_quotes}black box{close_quotes} so that the true structure is completely unknown, one often has no alternative but to compute the entire matrix by finite differences - a prohibitively expensive task for large problems. The author shows that it is possible to numerically determine symmetric sparsity patterns using a relatively small number of g evaluations. Numerical results are shown for n up to 100,000 in which all nonzeros in the Jacobian are correctly identified in about one-hundredth of the time required to estimate the sparsity structure by a full finite difference calculation. When a good initial guess for the sparsity structure is available, numerical results are presented for n up to 500,000, in which all missing nonzeros are correctly located almost five-thousand times faster than would be possible with a full finite difference calculation.

  11. The modelling of symmetric airfoil vortex generators

    NASA Technical Reports Server (NTRS)

    Reichert, B. A.; Wendt, B. J.

    1996-01-01

    An experimental study is conducted to determine the dependence of vortex generator geometry and impinging flow conditions on shed vortex circulation and crossplane peak vorticity for one type of vortex generator. The vortex generator is a symmetric airfoil having a NACA 0012 cross-sectional profile. The geometry and flow parameters varied include angle-of-attack alfa, chordlength c, span h, and Mach number M. The vortex generators are mounted either in isolation or in a symmetric counter-rotating array configuration on the inside surface of a straight pipe. The turbulent boundary layer thickness to pipe radius ratio is delta/R = 0. 17. Circulation and peak vorticity data are derived from crossplane velocity measurements conducted at or about 1 chord downstream of the vortex generator trailing edge. Shed vortex circulation is observed to be proportional to M, alfa, and h/delta. With these parameters held constant, circulation is observed to fall off in monotonic fashion with increasing airfoil aspect ratio AR. Shed vortex peak vorticity is also observed to be proportional to M, alfa, and h/delta. Unlike circulation, however, peak vorticity is observed to increase with increasing aspect ratio, reaching a peak value at AR approx. 2.0 before falling off.

  12. Spherically Symmetric Solutions of Light Galileon

    NASA Astrophysics Data System (ADS)

    Momeni, D.; Houndjo, M. J. S.; Güdekli, E.; Rodrigues, M. E.; Alvarenga, F. G.; Myrzakulov, R.

    2016-02-01

    We have been studied the model of light Galileon with translational shift symmetry ϕ → ϕ + c. The matter Lagrangian is presented in the form {L}_{φ }= -η (partial φ )2+β G^{μ ν }partial _{μ }φ partial _{ν }φ . We have been addressed two issues: the first is that, we have been proven that, this type of Galileons belong to the modified matter-curvature models of gravity in type of f(R,R^{μ ν }T_{μ ν }m). Secondly, we have been investigated exact solution for spherically symmetric geometries in this model. We have been found an exact solution with singularity at r = 0 in null coordinates. We have been proven that the solution has also a non-divergence current vector norm. This solution can be considered as an special solution which has been investigated in literature before, in which the Galileon's field is non-static (time dependence). Our scalar-shift symmetrized Galileon has the simple form of ϕ = t, which it is remembered by us dilaton field.

  13. Compressible flow about symmetrical Joukowski profiles

    NASA Technical Reports Server (NTRS)

    Kaplan, Carl

    1938-01-01

    The method of Poggi is employed for the determination of the effects of compressibility upon the flow past an obstacle. A general expression for the velocity increment due to compressibility is obtained. The general result holds whatever the shape of the obstacle; but, in order to obtain the complete solution, it is necessary to know a certain Fourier expansion of the square of the velocity of flow past the obstacle. An application is made to the case flow of a symmetrical Joukowski profile with a sharp trailing edge, fixed in a stream of an arbitrary angle of attack and with the circulation determined by the Kutta condition. The results are obtained in a closed form and are exact insofar as the second approximation to the compressible flow is concerned, the first approximation being the result for the corresponding incompressible flow. Formulas for lift and moment analogous to the Blasius formulas in incompressible flow are developed and are applied to thin symmetrical Joukowski profiles for small angles of attack.

  14. Decay Structure for Symmetric Hyperbolic Systems with Non-Symmetric Relaxation and its Application

    NASA Astrophysics Data System (ADS)

    Ueda, Yoshihiro; Duan, Renjun; Kawashima, Shuichi

    2012-07-01

    This paper is concerned with the decay structure for linear symmetric hyperbolic systems with relaxation. When the relaxation matrix is symmetric, the dissipative structure of the systems is completely characterized by the Kawashima-Shizuta stability condition formulated in Umeda et al. (Jpn J Appl Math 1:435-457, 1984) and Shizuta and Kawashima (Hokkaido Math J 14:249-275, 1985) and we obtain the asymptotic stability result together with the explicit time-decay rate under that stability condition. However, some physical models which satisfy the stability condition have non-symmetric relaxation term (for example, the Timoshenko system and the Euler-Maxwell system). Moreover, it had been already known that the dissipative structure of such systems is weaker than the standard type and is of the regularity-loss type (see Duan in J Hyperbolic Differ Equ 8:375-413, 2011; Ide et al. in Math Models Meth Appl Sci 18:647-667, 2008; Ide and Kawashima in Math Models Meth Appl Sci 18:1001-1025, 2008; Ueda et al. in SIAM J Math Anal 2012; Ueda and Kawashima in Methods Appl Anal 2012). Therefore our purpose in this paper is to formulate a new structural condition which includes the Kawashima-Shizuta condition, and to analyze the weak dissipative structure for general systems with non-symmetric relaxation.

  15. Matrix isolation ESR spectroscopy and magnetic anisotropy of D{sub 3h} symmetric septet trinitrenes

    SciTech Connect

    Misochko, Eugenii Ya.; Akimov, Alexander V.; Masitov, Artem A.; Korchagin, Denis V.; Aldoshin, Sergei M.; Chapyshev, Sergei V.

    2013-05-28

    The fine-structure (FS) parameters D of a series of D{sub 3h} symmetric septet trinitrenes were analyzed theoretically using density functional theory (DFT) calculations and compared with the experimental D values derived from ESR spectra. ESR studies show that D{sub 3h} symmetric septet 1,3,5-trichloro-2,4,6-trinitrenobenzene with D=-0.0957 cm{sup -1} and E= 0 cm{sup -1} is the major paramagnetic product of the photolysis of 1,3,5-triazido-2,4,6-trichlorobenzene in solid argon matrices at 15 K. Trinitrenes of this type display in the powder X-band ESR spectra intense Z{sub 1}-transition at very low magnetic fields, the position of which allows one to precisely calculate the parameter D of such molecules. Thus, our revision of the FS parameters of well-known 1,3,5-tricyano-2,4,6-trinitrenobenzene [E. Wasserman, K. Schueller, and W. A. Yager, Chem. Phys. Lett. 2, 259 (1968)] shows that this trinitrene has Double-Vertical-Line D Double-Vertical-Line = 0.092 cm{sup -1} and E= 0 cm{sup -1}. DFT calculations reveal that, unlike C{sub 2v} symmetric septet trinitrenes, D{sub 3h} symmetric trinitrenes have the same orientations of the spin-spin coupling tensor D-caret{sub SS} and the spin-orbit coupling tensor D-caret{sub SOC} and, as a result, have negative signs for both the D{sub SS} and D{sub SOC} values. The negative magnetic anisotropy of septet 2,4,6-trinitrenobenzenes is considerably strengthened on introduction of heavy atoms in the molecules, owing to an increase in contributions of various excitation states to the D{sub SOC} term.

  16. Electrodynamical forbiddance of strong quadrupole light-molecule interaction and peculiarities of the SEHR spectra in the methane molecule

    NASA Astrophysics Data System (ADS)

    Chelibanov, V. P.; Polubotko, A. M.

    2014-07-01

    It is demonstrated that the strong quadrupole light-molecule interaction, which is responsible for the most enhancement of Surface Enhanced Hyper Raman Scattering (SEHRS), experiences so-called electrodynamical forbiddance in the methane molecule and molecules with cubic symmetry groups and does not influence on formation of the SEHRS spectra. This forbiddance results in the fact that the lines, caused by the totally symmetric vibrations, which are observed in pyrazine and phenazine, must be slight, or absent at all. In this case, in methane, the most enhanced lines are those, caused by vibrations, transforming after the irreducible representations T1 , or T2 .

  17. Decelerating and Trapping Large Polar Molecules.

    PubMed

    Patterson, David

    2016-11-18

    Manipulating the motion of large polyatomic molecules, such as benzonitrile (C6 H5 CN), presents significant difficulties compared to the manipulation of diatomic molecules. Although recent impressive results have demonstrated manipulation, trapping, and cooling of molecules as large as CH3 F, no general technique for trapping such molecules has been demonstrated, and cold neutral molecules larger than 5 atoms have not been trapped (M. Zeppenfeld, B. G. U. Englert, R. Glöckner, A. Prehn, M. Mielenz, C. Sommer, L. D. van Buuren, M. Motsch, G. Rempe, Nature 2012, 491, 570-573). In particular, extending Stark deceleration and electrostatic trapping to such species remains challenging. Here, we propose to combine a novel "asymmetric doublet state" Stark decelerator with recently demonstrated slow, cold, buffer-gas-cooled beams of closed-shell volatile molecules to realize a general system for decelerating and trapping samples of a broad range of volatile neutral polar prolate asymmetric top molecules. The technique is applicable to most stable volatile molecules in the 100-500 AMU range, and would be capable of producing trapped samples in a single rotational state and at a motional temperature of hundreds of mK. Such samples would immediately allow for spectroscopy of unprecedented resolution, and extensions would allow for further cooling and direct observation of slow intramolecular processes such as vibrational relaxation and Hertz-level tunneling dynamics.

  18. Physics of Molecules

    NASA Astrophysics Data System (ADS)

    Williams, D.; Murdin, P.

    2000-11-01

    Many varieties of molecule have been detected in the Milky Way and in other galaxies. The processes by which these molecules are formed and destroyed are now broadly understood (see INTERSTELLAR CHEMISTRY). These molecules are important components of galaxies in two ways. Firstly, radiation emitted by molecules enables us to trace the presence of diffuse gas, to infer its physical properties and ...

  19. Theoretical spectra of floppy molecules

    NASA Astrophysics Data System (ADS)

    Chen, Hua

    2000-09-01

    Detailed studies of the vibrational dynamics of floppy molecules are presented. Six-D bound-state calculations of the vibrations of rigid water dimer based on several anisotropic site potentials (ASP) are presented. A new sequential diagonalization truncation approach was used to diagonalize the angular part of the Hamiltonian. Symmetrized angular basis and a potential optimized discrete variable representation for intermonomer distance coordinate were used in the calculations. The converged results differ significantly from the results presented by Leforestier et al. [J. Chem. Phys. 106 , 8527 (1997)]. It was demonstrated that ASP-S potential yields more accurate tunneling splittings than other ASP potentials used. Fully coupled 4D quantum mechanical calculations were performed for carbon dioxide dimer using the potential energy surface given by Bukowski et al [J. Chem. Phys., 110, 3785 (1999)]. The intermolecular vibrational frequencies and symmetry adapted force constants were estimated and compared with experiments. The inter-conversion tunneling dynamics was studied using the calculated virtual tunneling splittings. Symmetrized Radau coordinates and the sequential diagonalization truncation approach were formulated for acetylene. A 6D calculation was performed with 5 DVR points for each stretch coordinate, and an angular basis that is capable of converging the angular part of the Hamiltonian to 30 cm-1 for internal energies up to 14000 cm-1. The probability at vinylidene configuration were evaluated. It was found that the eigenstates begin to extend to vinylidene configuration from about 10000 cm-1, and the ra, coordinate is closely related to the vibrational dynamics at high energy. Finally, a direct product DVR was defined for coupled angular momentum operators, and the SDT approach were formulated. They were applied in solving the angular part of the Hamiltonian for carbon dioxide dimer problem. The results show the method is capable of giving very accurate

  20. Optimum top and bottom oxide thicknesses and flat-band voltages for improving subthreshold characteristics of 5 nm DGMOSFET

    NASA Astrophysics Data System (ADS)

    Jung, Hakkee; Dimitrijev, Sima

    2017-01-01

    This paper has proposed the optimum design rules as investigating subthreshold characteristics of 5 nm DG (Double Gate) MOSFET for top/bottom gate flat-band voltages and oxide thicknesses. The difference of top gate voltages between on-current (10-7 A) and off-current (10-12 A) is specified as ΔVon - off , and the top-gate voltage for the on-current is defined as the threshold voltage. ΔVon - off and the threshold voltage are derived from equations for the drain current and gate voltage for various top/bottom gate flat-band voltages and oxide thicknesses, and compared with those for symmetric structure having equal top/bottom gate flat-band voltages and oxide thicknesses. As a result, the potential distributions for top/bottom gate flat-band voltages and oxide thicknesses influence on directly the tunneling current, which greatly changes ΔVon - off and the threshold voltage in subthreshold region. It is established that the top flat-band voltage and oxide thickness have to be larger than the bottom flat-band voltage and oxide thickness to reduce ΔVon - off and threshold voltage, compared with those of symmetric structure.

  1. Minimal Left-Right Symmetric Dark Matter.

    PubMed

    Heeck, Julian; Patra, Sudhanwa

    2015-09-18

    We show that left-right symmetric models can easily accommodate stable TeV-scale dark matter particles without the need for an ad hoc stabilizing symmetry. The stability of a newly introduced multiplet either arises accidentally as in the minimal dark matter framework or comes courtesy of the remaining unbroken Z_{2} subgroup of B-L. Only one new parameter is introduced: the mass of the new multiplet. As minimal examples, we study left-right fermion triplets and quintuplets and show that they can form viable two-component dark matter. This approach is, in particular, valid for SU(2)×SU(2)×U(1) models that explain the recent diboson excess at ATLAS in terms of a new charged gauge boson of mass 2 TeV.

  2. Cracked shells under skew-symmetric loading

    NASA Technical Reports Server (NTRS)

    Lelale, F.

    1982-01-01

    A shell containing a through crack in one of the principal planes of curvature and under general skew-symmetric loading is considered. By employing a Reissner type shell theory which takes into account the effect of transverse shear strains, all boundary conditions on the crack surfaces are satisfied separately. Consequently, unlike those obtained from the classical shell theory, the angular distributions of the stress components around the crack tips are shown to be identical to the distributions obtained from the plane and antiplane elasticity solutions. Extensive results are given for axially and circumferentially cracked cylindrical shells, spherical shells, and toroidal shells under uniform inplane shearing, out of plane shearing, and torsion. The effect of orthotropy on the results is also studied.

  3. A symmetric bipolar nebula around MWC 922.

    PubMed

    Tuthill, P G; Lloyd, J P

    2007-04-13

    We report regular and symmetric structure around dust-enshrouded Be star MWC 922 obtained with infrared imaging. Biconical lobes that appear nearly square in aspect, forming this "Red Square" nebula, are crossed by a series of rungs that terminate in bright knots or "vortices," and an equatorial dark band crossing the core delimits twin hyperbolic arcs. The intricate yet cleanly constructed forms that comprise the skeleton of the object argue for minimal perturbation from global turbulent or chaotic effects. We also report the presence of a linear comb structure, which may arise from optically projected shadows of a periodic feature in the inner regions, such as corrugations in the rim of a circumstellar disk. The sequence of nested polar rings draws comparison with the triple-ring system seen around the only naked-eye supernova in recent history: SN1987A.

  4. Highly symmetric POVMs and their informational power

    NASA Astrophysics Data System (ADS)

    Słomczyński, Wojciech; Szymusiak, Anna

    2016-01-01

    We discuss the dependence of the Shannon entropy of normalized finite rank-1 POVMs on the choice of the input state, looking for the states that minimize this quantity. To distinguish the class of measurements where the problem can be solved analytically, we introduce the notion of highly symmetric POVMs and classify them in dimension 2 (for qubits). In this case, we prove that the entropy is minimal, and hence, the relative entropy (informational power) is maximal, if and only if the input state is orthogonal to one of the states constituting a POVM. The method used in the proof, employing the Michel theory of critical points for group action, the Hermite interpolation, and the structure of invariant polynomials for unitary-antiunitary groups, can also be applied in higher dimensions and for other entropy-like functions. The links between entropy minimization and entropic uncertainty relations, the Wehrl entropy, and the quantum dynamical entropy are described.

  5. Symmetric Satellite Swarms and Choreographic Crystals.

    PubMed

    Boyle, Latham; Khoo, Jun Yong; Smith, Kendrick

    2016-01-08

    In this Letter, we introduce a natural dynamical analogue of crystalline order, which we call choreographic order. In an ordinary (static) crystal, a high degree of symmetry may be achieved through a careful arrangement of the fundamental repeated elements. In the dynamical analogue, a high degree of symmetry may be achieved by having the fundamental elements perform a carefully choreographed dance. For starters, we show how to construct and classify all symmetric satellite constellations. Then we explain how to generalize these ideas to construct and classify choreographic crystals more broadly. We introduce a quantity, called the "choreography" of a given configuration. We discuss the possibility that some (naturally occurring or artificial) many-body or condensed-matter systems may exhibit choreographic order, and suggest natural experimental signatures that could be used to identify and characterize such systems.

  6. Diamond Turning of Nonrotationally Symmetric Surfaces.

    NASA Astrophysics Data System (ADS)

    Falter, Peter John

    Conventional techniques for ultraprecision turning have been successfully applied to the generation of optical quality surfaces. These resulting geometries however have been limited to surfaces of revolution. To investigate the machining of more general geometries, equipment has been developed to allow the production of accurate non -rotationally symmetric optical surfaces. This apparatus utilizes high speed digital control and a piezoelectric tool servo in conjunction with a workpiece-based metrology frame to synchronize tool position with spindle rotation. Machining experiments have been conducted to investigate the limits of producibility and the mechanics of this type of turning. The influences of tool forces, machine dynamics and metrology/control equipment on the accuracy of the finished part have also been determined.

  7. Partial transpose criteria for symmetric states

    NASA Astrophysics Data System (ADS)

    Bohnet-Waldraff, F.; Braun, D.; Giraud, O.

    2016-10-01

    We express the positive-partial-transpose (PPT) separability criterion for symmetric states of multiqubit systems in terms of matrix inequalities based on the recently introduced tensor representation for spin states. We construct a matrix from the tensor representation of the state and show that it is similar to the partial transpose of the density matrix written in the computational basis. Furthermore, the positivity of this matrix is equivalent to the positivity of a correlation matrix constructed from tensor products of Pauli operators. This allows for a more transparent experimental interpretation of the PPT criteria for an arbitrary spin-j state. The unitary matrices connecting our matrix to the partial transpose of the state generalize the so-called magic basis that plays a central role in Wootters' explicit formula for the concurrence of a two-qubit system and the Bell bases used for the teleportation of a one- or two-qubit state.

  8. Pseudo-Z symmetric space-times

    NASA Astrophysics Data System (ADS)

    Mantica, Carlo Alberto; Suh, Young Jin

    2014-04-01

    In this paper, we investigate Pseudo-Z symmetric space-time manifolds. First, we deal with elementary properties showing that the associated form Ak is closed: in the case the Ricci tensor results to be Weyl compatible. This notion was recently introduced by one of the present authors. The consequences of the Weyl compatibility on the magnetic part of the Weyl tensor are pointed out. This determines the Petrov types of such space times. Finally, we investigate some interesting properties of (PZS)4 space-time; in particular, we take into consideration perfect fluid and scalar field space-time, and interesting properties are pointed out, including the Petrov classification. In the case of scalar field space-time, it is shown that the scalar field satisfies a generalized eikonal equation. Further, it is shown that the integral curves of the gradient field are geodesics. A classical method to find a general integral is presented.

  9. Tensor eigenvalues and entanglement of symmetric states

    NASA Astrophysics Data System (ADS)

    Bohnet-Waldraff, F.; Braun, D.; Giraud, O.

    2016-10-01

    Tensor eigenvalues and eigenvectors have been introduced in the recent mathematical literature as a generalization of the usual matrix eigenvalues and eigenvectors. We apply this formalism to a tensor that describes a multipartite symmetric state or a spin state, and we investigate to what extent the corresponding tensor eigenvalues contain information about the multipartite entanglement (or, equivalently, the quantumness) of the state. This extends previous results connecting entanglement to spectral properties related to the state. We show that if the smallest tensor eigenvalue is negative, the state is detected as entangled. While for spin-1 states the positivity of the smallest tensor eigenvalue is equivalent to separability, we show that for higher values of the angular momentum there is a correlation between entanglement and the value of the smallest tensor eigenvalue.

  10. Symmetric Satellite Swarms and Choreographic Crystals

    NASA Astrophysics Data System (ADS)

    Boyle, Latham; Khoo, Jun Yong; Smith, Kendrick

    2016-01-01

    In this Letter, we introduce a natural dynamical analogue of crystalline order, which we call choreographic order. In an ordinary (static) crystal, a high degree of symmetry may be achieved through a careful arrangement of the fundamental repeated elements. In the dynamical analogue, a high degree of symmetry may be achieved by having the fundamental elements perform a carefully choreographed dance. For starters, we show how to construct and classify all symmetric satellite constellations. Then we explain how to generalize these ideas to construct and classify choreographic crystals more broadly. We introduce a quantity, called the "choreography" of a given configuration. We discuss the possibility that some (naturally occurring or artificial) many-body or condensed-matter systems may exhibit choreographic order, and suggest natural experimental signatures that could be used to identify and characterize such systems.

  11. Focal symmetrical encephalomalacia in a goat.

    PubMed

    Oliveira, Diego M; Pimentel, Luciano A; Pessoa, André F; Dantas, Antônio F M; Uzal, Francisco; Riet-Correa, Franklin

    2010-09-01

    Focal symmetrical encephalomalacia (FSE) is the most prominent lesion seen in the chronic form of enterotoxemia caused by Clostridium perfringens type D in sheep. However, this lesion has not been reported in goats. The current paper reports a case of FSE in a goat from the state of Paraíba in the Brazilian semiarid region. As reported by the farmer, 30, 4-48-month-old animals from a flock of 150 goats died after showing nervous signs, including blindness and recumbence, for periods varying between 1 and 14 days. The flock was grazing native pasture supplemented with wheat and corn bran. Additionally, lactating goats were supplemented with soybeans. A 4-month-old goat with nervous signs was examined clinically and then necropsied 3 days after the onset of clinical signs. Bilateral, focal, and symmetrical areas of brown discoloration were observed in the internal capsule and thalamus. Histologic lesions in these areas consisted of multifocal, bilateral malacia with a few neutrophils; endothelial cell swelling; perivascular edema; and hemorrhages. The etiology of these lesions was not determined. However, FSE is considered pathognomonic for C. perfringens type D enterotoxemia in sheep, and it is speculated that this microorganism was the etiologic agent in the present case. The flock had been vaccinated against type D enterotoxemia only once, approximately 3 months before the beginning of the outbreak. Insufficient immunity due to the incorrect vaccination protocol, low efficacy of the vaccine used, and a diet including large amounts of highly fermentable carbohydrates were suspected to be predisposing factors for this outbreak.

  12. Static, cylindrically symmetric strings in general relativity with cosmological constant

    SciTech Connect

    Linet, B.

    1986-07-01

    The static, cylindrically symmetric solutions to Einstein's equations with a cosmological term describing cosmic strings are determined. The discussion depends on the sign of the cosmological constant.

  13. Symmetrization of grey-scale images based on dilation

    NASA Astrophysics Data System (ADS)

    Tuzikov, Alexander V.; Krivonos, O. V.

    1996-03-01

    We generalize set symmetrization transformations based on Minkowski addition to symmetrization transformations for numerical functions. For this purpose two types of function representation are used. The first one is umbra representation, when symmetrization transformations are performed to the set of points under the graph of a function. This corresponds to introducing of transformations using gray-scale dilation. The second representation of a function is based on a family of threshold sets. Flat function symmetrization transformations are generated by corresponding set transformations operating on threshold sets.

  14. Entanglement equivalence of N-qubit symmetric states

    SciTech Connect

    Mathonet, P.; Krins, S.; Bastin, T.; Godefroid, M.; Solano, E.

    2010-05-15

    We study the interconversion of multipartite symmetric N-qubit states under stochastic local operations and classical communication (SLOCC). We demonstrate that if two symmetric states can be connected with a nonsymmetric invertible local operation (ILO), then they belong necessarily to the separable, W, or Greenberger-Horne-Zeilinger (GHZ) entanglement class, establishing a practical method of discriminating subsets of entanglement classes. Furthermore, we prove that there always exists a symmetric ILO connecting any pair of symmetric N-qubit states equivalent under SLOCC, simplifying the requirements for experimental implementations of local interconversion of those states.

  15. Spin-orbit coupling and strong electronic correlations in cyclic molecules

    NASA Astrophysics Data System (ADS)

    Khosla, A. L.; Jacko, A. C.; Merino, J.; Powell, B. J.

    2017-03-01

    In atoms spin-orbit coupling (SOC) cannot raise the angular momentum above a maximum value or lower it below a minimum. Here we show that this need not be the case in materials built from nanoscale structures including multinuclear coordination complexes, materials with decorated lattices, or atoms on surfaces. In such cyclic molecules the electronic spin couples to currents running around the molecule. For odd-fold symmetric molecules (e.g., odd-membered rings) the SOC is highly analogous to the atomic case; but for even-fold symmetric molecules every angular momentum state can be both raised and lowered. These differences arise because for odd-fold symmetric molecules the maximum and minimum molecular orbital angular momentum states are time-reversal conjugates, whereas for even-fold symmetric molecules they are aliases of the same single state. We show, from first-principles calculations, that in suitable molecules this molecular SOC is large, compared to the energy differences between frontier molecular orbitals. Finally, we show that, when electronic correlations are strong, molecular SOC can cause highly anisotropic exchange interactions and discuss how this can lead to effective spin models with compass Hamiltonians.

  16. Symmetric Resonance Charge Exchange Cross Section Based on Impact Parameter Treatment

    NASA Technical Reports Server (NTRS)

    Omidvar, Kazem; Murphy, Kendrah; Atlas, Robert (Technical Monitor)

    2002-01-01

    Using a two-state impact parameter approximation, a calculation has been carried out to obtain symmetric resonance charge transfer cross sections between nine ions and their parent atoms or molecules. Calculation is based on a two-dimensional numerical integration. The method is mostly suited for hydrogenic and some closed shell atoms. Good agreement has been obtained with the results of laboratory measurements for the ion-atom pairs H+-H, He+-He, and Ar+-Ar. Several approximations in a similar published calculation have been eliminated.

  17. Training Top 10 Hall of Fame

    ERIC Educational Resources Information Center

    Training, 2012

    2012-01-01

    Microsoft Corporation and SCC Soft Computer are the newest inductees into the Training Top 10 Hall of Fame, joining the ranks of the 11 companies named to the hall since its inception in 2008 (Wyeth Pharmaceuticals subsequently was acquired by Pfizer Inc. in 2009). These 11 companies held Top 10 spots in the Training Top 50, Top 100, and now Top…

  18. Top Mass Measurements at the Tevatron

    SciTech Connect

    Wang, M.H.L.S.; /Fermilab

    2009-04-01

    We present the latest measurements of the top quark mass from the Tevatron. The different top decay channels and measurement techniques used for these results are also described. The world average of the top quark mass based on some of these new results combined with previous results is m{sub top} = 172.6 {+-} 1.4 GeV.

  19. Kowalevski top in quantum mechanics

    SciTech Connect

    Matsuyama, A.

    2013-09-15

    The quantum mechanical Kowalevski top is studied by the direct diagonalization of the Hamiltonian. The spectra show different behaviors depending on the region divided by the bifurcation sets of the classical invariant tori. Some of these spectra are nearly degenerate due to the multiplicity of the invariant tori. The Kowalevski top has several symmetries and symmetry quantum numbers can be assigned to the eigenstates. We have also carried out the semiclassical quantization of the Kowalevski top by the EBK formulation. It is found that the semiclassical spectra are close to the exact values, thus the eigenstates can be also labeled by the integer quantum numbers. The symmetries of the system are shown to have close relations with the semiclassical quantum numbers and the near-degeneracy of the spectra. -- Highlights: •Quantum spectra of the Kowalevski top are calculated. •Semiclassical quantization is carried out by the EBK formulation. •Quantum states are labeled by the semiclassical integer quantum numbers. •Multiplicity of the classical torus makes the spectra nearly degenerate. •Symmetries, quantum numbers and near-degenerate spectra are closely related.

  20. The Top Theological Degree Producers

    ERIC Educational Resources Information Center

    Diverse: Issues in Higher Education, 2012

    2012-01-01

    Each year, "Diverse: Issues in Higher Education" publishes a list of the Top 100 producers of associate, bachelor's and graduate degrees awarded to minority students based on research conducted by Dr. Victor M. H. Borden, professor of educational leadership and policy studies at Indiana University Bloomington. This year, for the first…

  1. "Top School Problems" Are Myths.

    ERIC Educational Resources Information Center

    Males, Mike

    1992-01-01

    A well-known "study" comparing the top school problems of 1940 (talking and gum chewing) with those of 1987 (drug abuse, pregnancy, and violence) is nonexistent. In 1940, 49 percent of all youth did not finish high school, 37,000 teenagers died from violence or disease, and 335,000 teens gave birth. Educators should discount pastoral…

  2. China offshore has top priority

    SciTech Connect

    Cornitius, T.A.

    1983-11-01

    Joint venture development of offshore petroleum reserves has top priority in the mammoth effort to modernize the People's Republic of China. While the country works to overcome a critical shortage of skilled personnel, export of oil, coal, consumer goods, and metals will finance technological imports.

  3. Observation of the Top Quark

    DOE R&D Accomplishments Database

    Kim, S. B.

    1995-08-01

    Top quark production is observed in{bar p}p collisions at{radical}s= 1.8 TeV at the Fermilab Tevatron. The Collider Detector at Fermilab (CDF) and D{O} observe signals consistent with t{bar t} to WWb{bar b}, but inconsistent with the background prediction by 4.8{sigma} (CDF), 4.6a (D{O}). Additional evidence for the top quark Is provided by a peak in the reconstructed mass distribution. The kinematic properties of the excess events are consistent with the top quark decay. They measure the top quark mass to be 176{plus_minus}8(stat.){plus_minus}10(sys.) GeV/c{sup 2} (CDF), 199{sub -21}{sup+19}(stat.){plus_minus}22(sys.) GeV/c{sup 2} (D{O}), and the t{bar t} production cross section to be 6.8{sub -2.4}{sup+3.6}pb (CDF), 6.4{plus_minus}2.2 pb (D{O}).

  4. Kinematic top analyses at CDF

    SciTech Connect

    Cobal-Grassman, M.; CDF Collaboration

    1996-01-01

    We present an update of the top quark analysis using kinematic techniques in {rho}{ovr string {rho}} collisions at {radical}s = 1.8 TeV with the Collider Detector at Fermilab (CDF). We reported before on a study which used 19.3 pb{sup -1} of data from the 1992-93 collider run, but now we use a larger data sample of 67 pb{sup -1}. First, we analyze the total transverse energy of the hard collision in W+{ge}3 jet events, showing the likely presence of a t{ovr string t} component in the event sample. Next, we compare in more detail the kinematic structure of W+{ge}3 jet events with expectations for top pair production and with background processes, predominantly direct W+ jet production. We again find W+{ge}3 jet events which cannot be explained in terms of background, but show kinematic features as expected from top. These events also show evidence for beauty quarks. The findings confirm the observation of top events made earlier in the data of the 1992-93 collider run.

  5. The Top STEM Degree Producers

    ERIC Educational Resources Information Center

    Diverse: Issues in Higher Education, 2012

    2012-01-01

    This article presents a list of the top Science, Technology, Engineering, and Mathematics (STEM) degree producers in the U.S. This list is broken down into seven categories: (1) Total Minority Research/Scholarship and Other Doctoral: Mathematics and Statistics; (2) Total Minority Bachelors: Biological and Biomedical Sciences; (3) Total Minority…

  6. High-Resolution Infrared Spectroscopy Slit-Jet Cooled Hydroxymethyl Radical (CH_2OH): CH Symmetric Stretching Mode

    NASA Astrophysics Data System (ADS)

    Wang, Fang; Chang, Chih-Hsuan; Nesbitt, David

    2014-06-01

    Hydroxymethyl radical (CH_2OH) plays an important role in combustion and environmental chemistry as a reactive intermediate. Reisler's group published the first rotationally resolved spectroscopy of CH_2OH with determined band origins for fundamental CH symmetric stretch state, CH asymmetric stretch state and OH stretch state, respectively. Here CH_2OH was first studied via sub-Doppler infrared spectroscopy in a slit-jet supersonic discharge expansion source. Rotationally resolved direct absorption spectra in the CH symmetric stretching mode were recorded. As a result of the low rotational temperature and sub-Doppler linewidths, the tunneling splittings due to the large amplitude of COH torsion slightly complicate the spectra. Each of the ground vibration state and the CH symmetric stretch state includes two levels. One level, with a 3:1 nuclear spin statistic ratio for Ka=0+/Ka=1+, is labeled as ``+". The other tunneling level, labeled as ``-", has Ka=0-/Ka=1- states with 1:3 nuclear spin statistics. Except for the Ka=0+ ← 0+ band published before, more bands (Ka=1+ ← 1+, Ka=0- ← 0- and Ka=1- ← 1-) were identified. The assigned transitions were fit to a Watson A-reduced symmetric top Hamiltonian to improve the accuracy of the band origin of CH symmetric state. The rotational parameters for both ground and CH symmetric stretch state were well determined. L. Feng, J. Wei and H. Reisler, J. Phys. Chem. A, Vol. 108. M. A. Roberts, E. N. Sharp-Williams and D. J. Nesbitt, J. Phys. Chem. A 2013, 117, 7042-7049

  7. Top Jets at the LHC

    SciTech Connect

    Almeida, L.G.; Lee, S.J.; Perez, G.; Sung, I.; Virzi, J.

    2008-10-06

    We investigatethe reconstruction of high pT hadronically-decaying top quarksat the Large Hadron Collider. One of the main challenges in identifying energetictop quarks is that the decay products become increasingly collimated. This reducesthe efficacy of conventional reconstruction methods that exploit the topology of thetop quark decay chain. We focus on the cases where the decay products of the topquark are reconstructed as a single jet, a"top-jet." The most basic"top-tag" methodbased on jet mass measurement is considered in detail. To analyze the feasibility ofthe top-tagging method, both theoretical and experimental aspects of the large QCDjet background contribution are examined. Based on a factorization approach, wederive a simple analytic approximation for the shape of the QCD jet mass spectrum.We observe very good agreement with the Monte Carlo simulation. We consider high pT tt bar production in the Standard Model as an example, and show that our theoretical QCD jet mass distributions can efficiently characterize the background via sideband analyses. We show that with 25 fb-1 of data, our approach allows us to resolve top-jets with pT _> 1 TeV, from the QCD background, and about 1.5 TeV top-jets with 100 fb-1, without relying on b-tagging. To further improve the significancewe consider jet shapes (recently analyzed in 0807.0234 [hep-ph]), which resolve thesubstructure of energy flow inside cone jets. A method of measuring the top quarkpolarization by using the transverse momentum of the bottom quark is also presented.The main advantages of our approach are: (i) the mass distributions are driven byfirst principle calculations, instead of relying solely on Monte Carlo simulation; (ii) for high pT jets (pT _> 1 TeV), IR-safe jet shape variables are robust against detectorresolution effects. Our analysis can be applied to other boosted massive particlessuch as the electroweak gauge bosons and the Higgs.

  8. Properties of the Top Quark

    SciTech Connect

    Wicke, Daniel; /Wuppertal U., Dept. Math.

    2009-08-01

    The aim of particle physics is the understanding of elementary particles and their interactions. The current theory of elementary particle physics, the Standard Model, contains twelve different types of fermions which (neglecting gravity) interact through the gauge bosons of three forces. In addition a scalar particle, the Higgs boson, is needed for theoretical consistency. These few building blocks explain all experimental results found in the context of particle physics, so far. Nevertheless, it is believed that the Standard Model is only an approximation to a more complete theory. First of all the fourth known force, gravity, has withstood all attempts to be included until now. Furthermore, the Standard Model describes several features of the elementary particles like the existence of three families of fermions or the quantisation of charges, but does not explain these properties from underlying principles. Finally, the lightness of the Higgs boson needed to explain the symmetry breaking is difficult to maintain in the presence of expected corrections from gravity at high scales. This is the so called hierarchy problem. In addition astrophysical results indicate that the universe consists only to a very small fraction of matter described by the Standard Model. Large fractions of dark energy and dark matter are needed to describe the observations. Both do not have any correspondence in the Standard Model. Also the very small asymmetry between matter and anti-matter that results in the observed universe built of matter (and not of anti-matter) cannot be explained until now. It is thus an important task of experimental particle physics to test the predictions of the Standard Model to the best possible accuracy and to search for deviations pointing to necessary extensions or modifications of our current theoretical understanding. The top quark was predicted to exist by the Standard Model as the partner of the bottom quark. It was first observed in 1995 by the

  9. Structural tailoring effects on the magnetic behavior of symmetric and asymmetric cubane-type Ni complexes.

    PubMed

    Ponomaryov, Alexey N; Kim, Namseok; Hwang, Jaewon; Nojiri, Hiroyuki; van Tol, Johan; Ozarowski, Andrew; Park, Jena; Jang, Zeehoon; Suh, Byoungjin; Yoon, Sungho; Choi, Kwang-Yong

    2013-06-01

    Using two kinds of carboxylate ligands with small but significant differences in steric size, symmetric and asymmetric Fe(II) and Ni(II) cubanes have been synthesized in a controlled fashion. Fast sweeping pulsed field measurements showed magnetization hysteresis loops for two cubane-type molecular complexes, [Ni4(μ-OMe)4(O2CAr(4F-Ph))4(HOMe)8] and [Ni4(μ-OMe)4(O2CAr(Tol))4(HOMe)6], thus suggesting single-molecule magnet behavior. To differentiate the magnetic properties between the symmetric and asymmetric cubanes, detailed electron paramagnetic resonance (EPR) measurements were performed. From the EPR data, taken at various frequencies and temperatures, zero-field splitting parameters D, E, and other higher-order parameters for both cubane samples were extracted. Compared to the symmetric Ni-cubane, the asymmetric one shows an increase in the D and E values by about 20%, thereby suggesting structural engineering effects on the magnetic properties. By using the magnetic parameters determined by EPR, a static magnetization curve at 2 K and a temperature dependence of the magnetic susceptibility were simulated. A good agreement between theoretical and experimental data confirms the validity of the values obtained from EPR measurements.

  10. Solid-Phase Synthesis of Triostin A Using a Symmetrical Bis(diphenylmethyl) Linker System.

    PubMed

    Sable, Ganesh A; Lim, Dongyeol

    2015-08-07

    Triostin A is a symmetric bicyclic depsipeptide with very potent antitumoral activity because of its bisintercalation into DNA. In this study, we report a new synthetic strategy that exploits a structural symmetry of triostin A. First, we prepared a novel symmetric linker molecule that is labile under mildly acidic conditions and suitable for a solid-phase synthesis procedure. Two Cys units were attached to a linker-resin conjugate via their free thiol groups, and double deprotection and double coupling reactions were then applied to synthesize linear tetradepsipeptides. Subsequently, the key biscyclization of the tetradepsipeptides was performed on the resin, and the resulting cyclic octapeptide was detached from the linker-resin conjugate to give a peptide with two free thiols. Finally, triostin A was obtained by oxidizing the free thiols in solution to produce a disulfide. The yield was improved through exploration of two different solid-phase synthetic approaches under similar strategy. Mainly, this strategy was developed to enable the ease and rapid preparation of libraries of symmetric bicyclic depsipeptides. It also addresses several synthetic problems with our synthesis, including diketopiperazine (DKP) formation, poor cyclization yields and preparation of noncommercial N-methyl amino acids in good yields.

  11. Simultaneous Evaluation of Multiple Rotationally Excited States of Floppy Molecules Using Diffusion Monte Carlo

    NASA Astrophysics Data System (ADS)

    McCoy, Anne B.; Ford, Jason E.; Marlett, Melanie L.; Petit, Andrew S.

    2014-06-01

    In this work, an extension to diffusion Monte Carlo (DMC) is proposed, allowing for the simultaneous calculation of the energy and wave function of multiple rotationally excited states of floppy molecules. The total wave function is expanded into a set of Dirac δ-functions called walkers, while the rotational portion of the wave function is expanded in a symmetric top basis set. Each walker is given a rotational state vector containing coefficients for all states of interest. The positions of the atoms and the coefficients in the state vector evolve according to the split operator approximation of the quantum propagator. The method was benchmarked by comparing calculated rotation-vibration energies for H_3^+, H_2D^+, and H_3O^+ to experimental values. For low to moderate values of J, the resulting energies are within the statistical uncertainty of the calculation. Rotation-vibration coupling is captured through flexibility introduced in the form of the vibrational wave function. This coupling is found to increase with increasing J-values. Based on the success achieved through these systems, the method was applied to CH_5^+ and its deuterated isotopologues for v = 0, J ≥ 10. Based on these calculations, the energy level structure of CH_5^+ is found to resemble that for a of a spherical top, and excitations up to J = 10 displayed insignificant rotation-vibration coupling. Extensions of this approach that explicitly account for vibrations will also be discussed. ` A. S. Petit, J. E. Ford and A. B. McCoy, J. Phys. Chem. A, in press, K. D. Jordan Festschrift, DOI: 10.1021/jp408821a

  12. No-scalar-hair theorem for spherically symmetric reflecting stars

    NASA Astrophysics Data System (ADS)

    Hod, Shahar

    2016-11-01

    It is proved that spherically symmetric compact reflecting objects cannot support static bound-state configurations made of scalar fields whose self-interaction potential V (ψ2) is a monotonically increasing function of its argument. Our theorem rules out, in particular, the existence of massive scalar hair outside the surface of a spherically symmetric compact reflecting star.

  13. 47 CFR 51.711 - Symmetrical reciprocal compensation.

    Code of Federal Regulations, 2011 CFR

    2011-10-01

    ... 47 Telecommunication 3 2011-10-01 2011-10-01 false Symmetrical reciprocal compensation. 51.711... (CONTINUED) INTERCONNECTION Reciprocal Compensation for Transport and Termination of Telecommunications Traffic § 51.711 Symmetrical reciprocal compensation. (a) Rates for transport and termination...

  14. 47 CFR 51.711 - Symmetrical reciprocal compensation.

    Code of Federal Regulations, 2010 CFR

    2010-10-01

    ... 47 Telecommunication 3 2010-10-01 2010-10-01 false Symmetrical reciprocal compensation. 51.711... (CONTINUED) INTERCONNECTION Reciprocal Compensation for Transport and Termination of Telecommunications Traffic § 51.711 Symmetrical reciprocal compensation. (a) Rates for transport and termination...

  15. Do capuchin monkeys (Sapajus apella) prefer symmetrical face shapes?

    PubMed Central

    Paukner, Annika; Wooddell, Lauren J.; Lefevre, Carmen; Lonsdorf, Eric; Lonsdorf, Elizabeth

    2016-01-01

    In humans, facial symmetry has been linked to an individual's genetic quality, and facial symmetry has a small yet significant effect on ratings of facial attractiveness. The same evolutionary processes underlying these phenomena may also convey a selective advantage to symmetrical individuals of other primate species, yet to date, few studies have examined sensitivity to facial symmetry in non-human primates. Here we presented images of symmetrical and asymmetrical human and monkey faces to tufted capuchin monkeys (Sapajus apella), and hypothesized that capuchins would visually prefer symmetrical faces of opposite sex conspecifics. Instead, we found that male capuchins preferentially attended to symmetrical male conspecific faces whereas female capuchins did not appear to discriminate between symmetrical and asymmetrical faces. These results suggest that male capuchin monkeys may use facial symmetry to judge male quality in intra-male competition. PMID:28182489

  16. Attitude propulsion technology for TOPS

    NASA Technical Reports Server (NTRS)

    Moynihan, P. I.

    1972-01-01

    The thermoelectric outer planet spacecraft (TOPS) attitude propulsion subsystem (APS) effort is discussed. It includes the tradeoff rationale that went into the selection of an anhydrous hydrazine baseline system, followed by a discussion of the 0.22 N thruster and its integration into a portable, self-contained propulsion module that was designed, developed, and man rated to support the TOPS single-axis attitude control tests. The results of a cold-start feasibility demonstration with a modified thruster are presented. A description of three types of 0.44 thrusters that were procured for in-house evaluation is included along with the results of the test program. This is followed by a description of the APS feed system components, their evaluations, and a discussion of an evaluation of elastomeric material for valve seat seals. A list of new technology items which will be of value for application to future systems of this type is included.

  17. Thermoelectric Outer Planets Spacecraft (TOPS)

    NASA Technical Reports Server (NTRS)

    1973-01-01

    The research and advanced development work is reported on a ballistic-mode, outer planet spacecraft using radioisotope thermoelectric generator (RTG) power. The Thermoelectric Outer Planet Spacecraft (TOPS) project was established to provide the advanced systems technology that would allow the realistic estimates of performance, cost, reliability, and scheduling that are required for an actual flight mission. A system design of the complete RTG-powered outer planet spacecraft was made; major technical innovations of certain hardware elements were designed, developed, and tested; and reliability and quality assurance concepts were developed for long-life requirements. At the conclusion of its active phase, the TOPS Project reached its principal objectives: a development and experience base was established for project definition, and for estimating cost, performance, and reliability; an understanding of system and subsystem capabilities for successful outer planets missions was achieved. The system design answered long-life requirements with massive redundancy, controlled by on-board analysis of spacecraft performance data.

  18. Symmetric weak ternary quantum homomorphic encryption schemes

    NASA Astrophysics Data System (ADS)

    Wang, Yuqi; She, Kun; Luo, Qingbin; Yang, Fan; Zhao, Chao

    2016-03-01

    Based on a ternary quantum logic circuit, four symmetric weak ternary quantum homomorphic encryption (QHE) schemes were proposed. First, for a one-qutrit rotation gate, a QHE scheme was constructed. Second, in view of the synthesis of a general 3 × 3 unitary transformation, another one-qutrit QHE scheme was proposed. Third, according to the one-qutrit scheme, the two-qutrit QHE scheme about generalized controlled X (GCX(m,n)) gate was constructed and further generalized to the n-qutrit unitary matrix case. Finally, the security of these schemes was analyzed in two respects. It can be concluded that the attacker can correctly guess the encryption key with a maximum probability pk = 1/33n, thus it can better protect the privacy of users’ data. Moreover, these schemes can be well integrated into the future quantum remote server architecture, and thus the computational security of the users’ private quantum information can be well protected in a distributed computing environment.

  19. Drift waves in helically symmetric stellarators

    SciTech Connect

    Rafiq, T.; Hegna, C.

    2005-11-15

    The local linear stability of electron drift waves and ion temperature gradient modes (ITG) is investigated in a quasihelically symmetric (QHS) stellarator and a conventional asymmetric (Mirror) stellarator. The geometric details of the different equilibria are emphasized. Eigenvalue equations for the models are derived using the ballooning mode formalism and solved numerically using a standard shooting technique in a fully three-dimensional stellarator configuration. While the eigenfunctions have a similar shape in both magnetic geometries, they are slightly more localized along the field line in the QHS case. The most unstable electron drift modes are strongly localized at the symmetry points (where stellarator symmetry is present) and in the regions where normal curvature is unfavorable and magnitude of the local magnetic shear and magnetic field is minimum. The presence of a large positive local magnetic shear in the bad curvature region is found to be destabilizing. Electron drift modes are found to be more affected by the normal curvature than by the geodesic curvature. The threshold of stability of the ITG modes in terms of {eta}{sub i} is found to be 2/3 in this fluid model consistent with the smallest threshold for toroidal geometry with adiabatic electrons. Optimization to favorable drift wave stability has small field line curvature, short connection lengths, the proper combination of geodesic curvature and local magnetic shear, large values of local magnetic shear, and the compression of flux surfaces in the unfavorable curvature region.

  20. Spherically symmetric conformal gravity and ''gravitational bubbles''

    SciTech Connect

    Berezin, V.A.; Dokuchaev, V.I.; Eroshenko, Yu.N. E-mail: dokuchaev@inr.ac.ru

    2016-01-01

    The general structure of the spherically symmetric solutions in the Weyl conformal gravity is described. The corresponding Bach equations are derived for the special type of metrics, which can be considered as the representative of the general class. The complete set of the pure vacuum solutions is found. It consists of two classes. The first one contains the solutions with constant two-dimensional curvature scalar of our specific metrics, and the representatives are the famous Robertson-Walker metrics. One of them we called the ''gravitational bubbles'', which is compact and with zero Weyl tensor. Thus, we obtained the pure vacuum curved space-times (without any material sources, including the cosmological constant) what is absolutely impossible in General Relativity. Such a phenomenon makes it easier to create the universe from ''nothing''. The second class consists of the solutions with varying curvature scalar. We found its representative as the one-parameter family. It appears that it can be conformally covered by the thee-parameter Mannheim-Kazanas solution. We also investigated the general structure of the energy-momentum tensor in the spherical conformal gravity and constructed the vectorial equation that reveals clearly some features of non-vacuum solutions. Two of them are explicitly written, namely, the metrics à la Vaidya, and the electrovacuum space-time metrics.

  1. Coscheduling Technique for Symmetric Multiprocessor Clusters

    SciTech Connect

    Yoo, A B; Jette, M A

    2000-09-18

    Coscheduling is essential for obtaining good performance in a time-shared symmetric multiprocessor (SMP) cluster environment. However, the most common technique, gang scheduling, has limitations such as poor scalability and vulnerability to faults mainly due to explicit synchronization between its components. A decentralized approach called dynamic coscheduling (DCS) has been shown to be effective for network of workstations (NOW), but this technique is not suitable for the workloads on a very large SMP-cluster with thousands of processors. Furthermore, its implementation can be prohibitively expensive for such a large-scale machine. IN this paper, they propose a novel coscheduling technique based on the DCS approach which can achieve coscheduling on very large SMP-clusters in a scalable, efficient, and cost-effective way. In the proposed technique, each local scheduler achieves coscheduling based upon message traffic between the components of parallel jobs. Message trapping is carried out at the user-level, eliminating the need for unsupported hardware or device-level programming. A sending process attaches its status to outgoing messages so local schedulers on remote nodes can make more intelligent scheduling decisions. Once scheduled, processes are guaranteed some minimum period of time to execute. This provides an opportunity to synchronize the parallel job's components across all nodes and achieve good program performance. The results from a performance study reveal that the proposed technique is a promising approach that can reduce response time significantly over uncoordinated time-sharing and batch scheduling.

  2. Spherically symmetric conformal gravity and ``gravitational bubbles''

    NASA Astrophysics Data System (ADS)

    Berezin, V. A.; Dokuchaev, V. I.; Eroshenko, Yu. N.

    2016-01-01

    The general structure of the spherically symmetric solutions in the Weyl conformal gravity is described. The corresponding Bach equations are derived for the special type of metrics, which can be considered as the representative of the general class. The complete set of the pure vacuum solutions is found. It consists of two classes. The first one contains the solutions with constant two-dimensional curvature scalar of our specific metrics, and the representatives are the famous Robertson-Walker metrics. One of them we called the ``gravitational bubbles'', which is compact and with zero Weyl tensor. Thus, we obtained the pure vacuum curved space-times (without any material sources, including the cosmological constant) what is absolutely impossible in General Relativity. Such a phenomenon makes it easier to create the universe from ``nothing''. The second class consists of the solutions with varying curvature scalar. We found its representative as the one-parameter family. It appears that it can be conformally covered by the thee-parameter Mannheim-Kazanas solution. We also investigated the general structure of the energy-momentum tensor in the spherical conformal gravity and constructed the vectorial equation that reveals clearly some features of non-vacuum solutions. Two of them are explicitly written, namely, the metrics à la Vaidya, and the electrovacuum space-time metrics.

  3. Plasma Control in Symmetric Mirror Machines

    NASA Astrophysics Data System (ADS)

    Horton, W.; Rowan, W. L.; Alvarado, Igor; Fu, X. R.; Beklemishev, A. D.

    2014-10-01

    Plasma confinement in the symmetric rotating mirror plasma at the Budker Institute shows enhanced confinement with high electron temperatures with end plates biasing. Improved confinement is achieved by biasing end plate cells in the expansion tanks so as to achieve an inward pointing radial electric field. The negative potential well produces vortex plasma rotation similar to that in the negative potential well of Ohmic heated tokamaks. This plasma state has similarity with the lower turbulence level regimes documented in the Helimak where negative biasing of the end plates produces an inward radial electric field. To understand this vortex confinement we carry out 3D simulations with nonlinear partial differential equations for the electric potential and density in plasmas with an axially localized region of unfavorable and favorable magnetic curvature. The simulations show that the plasma density rapidly adjusts to be higher in the region of favorable curvature regions and remains relatively well confined while rapidly rotating. The results support the concept of using plasma-biasing electrodes in large expander tanks to achieve enhanced mirror plasma confinement. Supported by US-DoE grant to UT, LANL and the Budker Institute for Nuclear Physics.

  4. Top quark results at CDF

    SciTech Connect

    Leone, S.; CDF Collaboration

    1996-08-01

    We present the latest results on the top quark obtained by the CDF experiment using a data sample of about 110 {ital pb}{sup -1} collected at the Fermilab Tevatron collider. We briefly describe the candidate events selection and then discuss the production cross section determination and the mass measurement. The study of two new decay channels (all hadronic and ``tau dilepton``) is also reported.

  5. Observation of the Top Quark

    SciTech Connect

    Abachi, S.; Abbott, B.; Abolins, M.; Acharya, B.S.; Adam, I.; Adams, D.L.; Adams, M.; Ahn, S.; Aihara, H.; Aihara, H.; Alitti, J.; Alvarez, G.; Alves, G.A.; Amidi, E.; Amos, N.; Anderson, E.W.; Aronson, S.H.; Astur, R.; Avery, R.E.; Balamurali, V.; Balderston, J.; Baldin, B.; Bantly, J.; Bartlett, J.F.; Bazizi, K.; Bendich, J.; Beri, S.B.; Bertram, I.; Bezzubov, V.A.; Bhat, P.C.; Bhatnagar, V.; Bhattacharjee, M.; Bischoff, A.; Biswas, N.; Blazey, G.; Blessing, S.; Boehnlein, A.; Bojko, N.I.; Borcherding, F.; Borders, J.; Boswell, C.; Brandt, A.; Brock, R.; Bross, A.; Buchholz, D.; Burtovoi, V.S.; Butler, J.M.; Casey, D.; Castilla-Valdez, H.; Chakraborty, D.; Chang, S.; Chekulaev, S.V.; Chen, L.; Chen, W.; Chevalier, L.; Chopra, S.; Choudhary, B.C.; Christenson, J.H.; Chung, M.; Claes, D.; Clark, A.R.; Cobau, W.G.; Cochran, J.; Cooper, W.E.; Cretsinger, C.; Cullen-Vidal, D.; Cummings, M.; Cutts, D.; Dahl, O.I.; De, K.; Demarteau, M.; Demina, R.; Denisenko, K.; Denisenko, N.; Denisov, D.; Denisov, S.P.; Dharmaratna, W.; Diehl, H.T.; Diesburg, M.; Di Loreto, G.; Dixon, R.; Draper, P.; Drinkard, J.; Ducros, Y.; Dugad, S.R.; Durston-Johnson, S.; Edmunds, D.; Efimov, A.O.; Ellison, J.; Elvira, V.D.; Engelmann, R.; Eno, S.; Eppley, G.; Ermolov, P.; Eroshin, O.V.; Evdokimov, V.N.; Fahey, S.; Fahland, T.; Fatyga, M.; Fatyga, M.K.; Featherly, J.; Feher, S.; Fein, D.; Ferbel, T.; Finocchiaro, G.; Fisk, H.E.; Fisyak, Y.; Flattum, E.; Forden, G.E.; Fortner, M.; Frame, K.C.; Franzini, P.; Fredriksen, S.; Fuess, S.; Galjaev, A.N.; Gallas, E.; Gao, C.S.; Gao, S.; Geld, T.L.; Genik, R.J. II; Genser, K.; Gerber, C.E.; Gibbard, B.; Glaubman, M.; Glebov, V.; Glenn, S.; Glicenstein, J.F.; Gobbi, B.; Goforth, M.; Goldschmidt, A.; Gomez, B.; Goncharov, P.I.; Gordon, H.; Goss, L.T.; Graf, N.; Grannis, P.D.; Green, D.R.; Green, J.; Greenlee, H.; Griffin, G.; Grossman, N.; Grudberg, P.; Gruenendahl, S.; Guida, J.A.; Guida, J.M.; Guryn, W.; Gurzhiev, S.N.; Gutnikov, Y.E.

    1995-04-03

    The D0 Collaboration reports on a search for the standard model top quark in {ital p{bar p}} collisions at {radical}{ital s}=1.8TeV at the Fermilab Tevatron with an integrated luminosity of approximately 50pb{sup {minus}1}. We have searched for {ital t{bar t}} production in the dilepton and single-lepton decay channels with and without tagging of {ital b}-quark jets. We observed 17 events with an expected background of 3.8{plus_minus}0.6 events. The probability for an upward fluctuation of the background to produce the observed signal is 2{times}10{sup {minus}6} (equivalent to 4.6 standard deviations). The kinematic properties of the excess events are consistent with top quark decay. We conclude that we have observed the top quark and measured its mass to be 199{sub {minus}21}{sup +19} (stat) {plus_minus}22 (syst) GeV/{ital c}{sup 2} and its production cross section to be 6.4{plus_minus}2.2pb.

  6. Top quark studies at hadron colliders

    SciTech Connect

    Sinervo, P.K.

    1997-01-01

    The techniques used to study top quarks at hadron colliders are presented. The analyses that discovered the top quark are described, with emphasis on the techniques used to tag b quark jets in candidate events. The most recent measurements of top quark properties by the CDF and DO Collaborations are reviewed, including the top quark cross section, mass, branching fractions, and production properties. Future top quark studies at hadron colliders are discussed, and predictions for event yields and uncertainties in the measurements of top quark properties are presented.

  7. Nakedness and curvature strength of a shell-focusing singularity in spherically symmetric spacetime with vanishing radial pressure

    NASA Astrophysics Data System (ADS)

    Harada, Tomohiro; Nakao, Ken-ichi; Iguchi, Hideo

    1999-08-01

    It was shown recently that the metric functions which describe a spherically symmetric spacetime with vanishing radial pressure can be explicitly integrated. We investigate the nakedness and curvature strength of the shell-focusing singularity in that spacetime. If the singularity is naked, the relation between the circumferential radius and the Misner-Sharp mass is given by Ricons/Journals/Common/approx" ALT="approx" ALIGN="TOP"/>2y0micons/Journals/Common/beta" ALT="beta" ALIGN="TOP"/> with (1/3)TOP"/>icons/Journals/Common/le" ALT="le" ALIGN="TOP"/>1 along the first radial null geodesic from the singularity. The icons/Journals/Common/beta" ALT="beta" ALIGN="TOP"/> is closely related to the curvature strength of the naked singularity. For example, for the outgoing or ingoing null geodesic, if the strong curvature condition (SCC) of Tipler holds, then icons/Journals/Common/beta" ALT="beta" ALIGN="TOP"/> must be equal to 1. We define the `gravity-dominance condition' (GDC) for a geodesic. If GDC is satisfied for the null geodesic, both SCC and the limiting focusing condition (LFC) of Królak holds for icons/Journals/Common/beta" ALT="beta" ALIGN="TOP"/> = 1 and y0icons/Journals/Common/ne" ALT="ne" ALIGN="TOP"/>1, not SCC but only LFC holds for 1/2 icons/Journals/Common/le" ALT="le" ALIGN="TOP"/>icons/Journals/Common/beta" ALT="beta" ALIGN="TOP"/><1, and neither holds for (1/3)TOP"/>< 1/2 , for the null geodesic. On the other hand, if GDC is satisfied for the timelike geodesic r = 0, both SCC and LFC are satisfied for the timelike geodesic, irrespective of the value of icons/Journals/Common/beta" ALT="beta" ALIGN="TOP"/>. Several examples are also discussed.

  8. Gas-phase infrared and ab initio study of the unstable CF3CNO molecule and its stable furoxan ring dimer.

    PubMed

    Havasi, Balázs; Pasinszki, Tibor; Westwood, Nicholas P C

    2005-05-05

    The unstable trifluoroacetonitrile N-oxide molecule, CF3CNO, has been generated in high yield in the gas phase from CF3BrC=NOH and studied for the first time by gas-phase mid-infrared spectroscopy. Cold trapping of this molecule followed by slow warming forms the stable ring dimer, bis(trifluoromethyl)furoxan, also investigated by gas-phase infrared spectroscopy. The spectroscopy provides an investigation into the vibrational character of the two molecules, the assignments supported by calculations of the harmonic vibrational frequencies using in the case of CF3CNO both ab initio (CCSD(T)) and density functional theory (B3LYP) and B3LYP for the ring dimer. The ground-state structures of both molecules were investigated at the B3LYP level of theory, with CF3CNO further investigated using coupled-cluster. The CCSD(T) method suggests a slightly bent (C(s)) structure for CF3CNO, while the B3LYP method (with basis sets ranging from 6-311G(d) to cc-pVTZ) suggests a close-to-linear or linear CCNO chain. The CCN bending potential in CF3CNO was explored at the CCSD(T)(fc)/cc-pVTZ level, with the results suggesting that CF3CNO exhibits strong quasi-symmetric top behavior with a barrier to linearity of 174 cm(-1). Since both isomerization and dimerization are feasible loss processes for this unstable molecule, the relative stability of CF3CNO with respect to the known cyanate (CF3OCN), isocyanate (CF3NCO), and fulminate (CF3ONC) isomers and the mechanism of the dimerization process to the ring furoxan and other isomers were studied with density functional theory.

  9. Trapping polar molecules in an ac trap

    SciTech Connect

    Bethlem, Hendrick L.; Veldhoven, Jacqueline van; Schnell, Melanie; Meijer, Gerard

    2006-12-15

    Polar molecules in high-field seeking states cannot be trapped in static traps as Maxwell's equations do not allow a maximum of the electric field in free space. It is possible to generate an electric field that has a saddle point by superposing an inhomogeneous electric field to an homogeneous electric field. In such a field, molecules are focused along one direction, while being defocused along the other. By reversing the direction of the inhomogeneous electric field the focusing and defocusing directions are reversed. When the fields are being switched back and forth at the appropriate rate, this leads to a net focusing force in all directions. We describe possible electrode geometries for creating the desired fields and discuss their merits. Trapping of {sup 15}ND{sub 3} ammonia molecules in a cylindrically symmetric ac trap is demonstrated. We present measurements of the spatial distribution of the trapped cloud as a function of the settings of the trap and compare these to both a simple model assuming a linear force and to full three-dimensional simulations of the experiment. With the optimal settings, molecules within a phase-space volume of 270 mm{sup 3} (m/s){sup 3} remain trapped. This corresponds to a trap depth of about 5 mK and a trap volume of about 20 mm{sup 3}.

  10. Microwave spectroscopic detection of a transient phosphorus-bearing molecule, H3PO

    NASA Astrophysics Data System (ADS)

    Ahmad, Imtiaz K.; Ozeki, Hiroyuki; Saito, Shuji

    1999-01-01

    The microwave spectrum of the transient phosphine oxide, H3PO, was detected in the gas phase for the first time using a source-modulated spectrometer. The H3PO molecule was generated in a free space cell by a dc glow discharge of a mixture of PH3, CO2, and H2 gases and the corresponding spectral lines for each rotational transition of H3PO formed a pattern clearly indicative of a symmetric top molecule. Isotopomers of H3PO, i.e., H3P18O and D3PO were also produced; H3P18O in the same fashion as for H3PO, and D3PO, in a mixture of D2 and CO2 gases passing over red phosphorus grains. In total, 54 spectral lines of H3PO, 55 lines of H3P18O, and 61 lines of D3PO were measured for the fine structure of rotational transitions, J=2-1 to 12-11. The rotational constant, B0, and centrifugal constants, DJ, DJK, and HKJ were ascertained by a least squares analysis of the measured frequencies for each of the species. Using the rotational constants of the three isotopic species, the following r0 structure was determined: r0 (PO)=1.4763 Å, r0(PH)=1.4406 Å, and ∠HPO=114.26°. The value of each structural parameter deviates significantly from the most recent results predicted by ab initio calculations.

  11. The lack of large compact symmetric objects

    NASA Astrophysics Data System (ADS)

    Augusto, P.

    2009-02-01

    In recent years, `baby' (< 103 yr) and `young' (103-105 yr) radio galaxies have been found and classified, although their numbers are still small (tens). Also, they have many different names, depending on the type of survey and scientific context in which they were found: compact steep spectrum sources (CSS), giga-Hertz peaked spectrum sources (GPS) and compact-medium symmetric objects (C-MSO). The latter have the radio galaxy structure more obvious and correspond to the `babies' (CSOs; < 1 kpc) and `young' (MSOs; 1-15 kpc) radio galaxies. The log-size distribution of CSOs shows a sharp drop at 0.3 kpc. This trend continues through flat-spectrum MSOs (over the full 1-15 kpc size range). In order to find out if this lack of large CSOs and flat-spectrum MSOs is due to poor sampling (lack of surveys that probe efficiently the 0.3-15 kpc size range) and/or has physical meaning (e.g. if the lobes of CSOs expand as they grow and age, they might become CSSs, `disappearing' from the flat-spectrum MSO statistics), we have built a sample of 157 flat-spectrum radio sources with structure on ˜0.3-15 kpc scales. We are using new, archived and published data to produce and inspect hundreds of multi-frequency multi-instrument maps and models. We have already found 13 new secure CSO/MSOs. We expect to uncover ˜30-40 new CSOs and MSOs, most on the 0.3-15 kpc size range, when our project is complete.

  12. Recent advances in symmetric and network dynamics

    NASA Astrophysics Data System (ADS)

    Golubitsky, Martin; Stewart, Ian

    2015-09-01

    We summarize some of the main results discovered over the past three decades concerning symmetric dynamical systems and networks of dynamical systems, with a focus on pattern formation. In both of these contexts, extra constraints on the dynamical system are imposed, and the generic phenomena can change. The main areas discussed are time-periodic states, mode interactions, and non-compact symmetry groups such as the Euclidean group. We consider both dynamics and bifurcations. We summarize applications of these ideas to pattern formation in a variety of physical and biological systems, and explain how the methods were motivated by transferring to new contexts René Thom's general viewpoint, one version of which became known as "catastrophe theory." We emphasize the role of symmetry-breaking in the creation of patterns. Topics include equivariant Hopf bifurcation, which gives conditions for a periodic state to bifurcate from an equilibrium, and the H/K theorem, which classifies the pairs of setwise and pointwise symmetries of periodic states in equivariant dynamics. We discuss mode interactions, which organize multiple bifurcations into a single degenerate bifurcation, and systems with non-compact symmetry groups, where new technical issues arise. We transfer many of the ideas to the context of networks of coupled dynamical systems, and interpret synchrony and phase relations in network dynamics as a type of pattern, in which space is discretized into finitely many nodes, while time remains continuous. We also describe a variety of applications including animal locomotion, Couette-Taylor flow, flames, the Belousov-Zhabotinskii reaction, binocular rivalry, and a nonlinear filter based on anomalous growth rates for the amplitude of periodic oscillations in a feed-forward network.

  13. Generalized symmetric extension for size-limited multirate filter banks.

    PubMed

    Bamberger, R H; Eddins, S L; Nuri, V

    1994-01-01

    A multirate (MR) filter bank is called size-limited if the total number of output samples equals the number of input samples. A method called symmetric extension improved performance in subband image compression systems compared to the earlier method of circular convolution. However, the symmetric extension method was developed only for two-band uniform filter banks, and required even-length linear phase analysis filters. The authors generalize the symmetric extension method to the M-band, possibly nonuniform filter banks, where M=/>2. The length restriction on the analysis filters is relaxed.

  14. The classification of quantum symmetric-key encryption protocols

    NASA Astrophysics Data System (ADS)

    Xiang, Chong; Yang, Li; Peng, Yong; Chen, Dongqing

    2014-11-01

    The classification of quantum symmetric-key encryption protocol is presented. According to five elements of a quantum symmetric-key encryption protocol: plaintext, ciphertext, key, encryption algorithm and decryption algorithm, there are 32 different kinds of them. Among them, 5 kinds of protocols have already been constructed and studied, and 21 kinds of them are proved to be impossible to construct, the last 6 kinds of them are not yet presented effectively. That means the research on quantum symmetric-key encryption protocol only needs to consider with 5 kinds of them nowadays.

  15. Experimental scheme for unambiguous discrimination of linearly independent symmetric states

    SciTech Connect

    Jimenez, O.; Burgos-Inostroza, E.; Delgado, A.; Saavedra, C.; Sanchez-Lozano, X.

    2007-12-15

    We propose an experimental setup for discriminating four linearly independent nonorthogonal symmetric quantum states. The setup is based on linear optics only and can be configured to implement both optimal unambiguous state discrimination [Chefles and Barnett, Phys. Lett. A 250, 223 (1998)] and minimum error discrimination. In both cases, the setup is characterized by an optimal success probability. The experimental setup can be generalized to the case of discrimination among N linearly nonorthogonal symmetric quantum states. We also study the discrimination between two incoherent superpositions of symmetric states. In this case, the setup also achieves an optimal success probability in the case of unambiguous discrimination as well as minimum error discrimination.

  16. (M-theory-)Killing spinors on symmetric spaces

    SciTech Connect

    Hustler, Noel; Lischewski, Andree

    2015-08-15

    We show how the theory of invariant principal bundle connections for reductive homogeneous spaces can be applied to determine the holonomy of generalised Killing spinor covariant derivatives of the form D = ∇ + Ω in a purely algebraic and algorithmic way, where Ω : TM → Λ{sup ∗}(TM) is a left-invariant homomorphism. Specialising this to the case of symmetric M-theory backgrounds (i.e., (M, g, F) with (M, g) an eleven-dimensional Lorentzian (locally) symmetric space and F an invariant closed 4-form), we derive several criteria for such a background to preserve some supersymmetry and consequently find all supersymmetric symmetric M-theory backgrounds.

  17. Formation of Ultracold Molecules

    SciTech Connect

    Cote, Robin

    2016-01-28

    Advances in our ability to slow down and cool atoms and molecules to ultracold temperatures have paved the way to a revolution in basic research on molecules. Ultracold molecules are sensitive of very weak interactions, even when separated by large distances, which allow studies of the effect of those interactions on the behavior of molecules. In this program, we have explored ways to form ultracold molecules starting from pairs of atoms that have already reached the ultracold regime. We devised methods that enhance the efficiency of ultracold molecule production, for example by tuning external magnetic fields and using appropriate laser excitations. We also investigates the properties of those ultracold molecules, especially their de-excitation into stable molecules. We studied the possibility of creating new classes of ultra-long range molecules, named macrodimers, thousand times more extended than regular molecules. Again, such objects are possible because ultra low temperatures prevent their breakup by collision. Finally, we carried out calculations on how chemical reactions are affected and modified at ultracold temperatures. Normally, reactions become less effective as the temperature decreases, but at ultracold temperatures, they can become very effective. We studied this counter-intuitive behavior for benchmark chemical reactions involving molecular hydrogen.

  18. Scanning Tunneling Microscopic Characterization of an Engineered Organic Molecule

    DTIC Science & Technology

    2011-08-01

    attachment and wide -band MCT detector, was used. Figure 3 shows the spectra obtained for SAM of PMNBT (top), which was compared to raw crystal PMNBT...Graphite Covered with Phthalocyanine Molecules. Science , 1992, 255, 1115– 1118. 10. Stabel, A.; Herwig, P.; Mullen, K.; Rabe, J. P. Diode Like...J. J.; Dunbar, T. D.; Allara, D. L.; Weiss, P. S. Electron Transfer through Organic Molecules. J. Phys. Chem. B 1999, 103, 8122–8127. 16. Wold , D

  19. Multiple optical trapping based on high-order axially symmetric polarized beams

    NASA Astrophysics Data System (ADS)

    Zhou, Zhe-Hai; Zhu, Lian-Qing

    2015-02-01

    Multiple optical trapping with high-order axially symmetric polarized beams (ASPBs) is studied theoretically, and a scheme based on far-field optical trapping with ASPBs is first proposed. The focused fields and the corresponding gradient forces on Rayleigh dielectric particles are calculated for the scheme. The calculated results indicate that multiple ultra-small focused spots can be achieved, and multiple nanometer-sized particles with refractive index higher than the ambient can be trapped simultaneously near these focused spots, which are expected to enhance the capabilities of traditional optical trapping systems and provide a solution for massive multiple optical trapping of nanometer-sized particles. Project supported by the National Natural Science Foundation of China (Grant Nos. 61108047 and 61475021), the Program for New Century Excellent Talents in University, China (Grant No. NCET-13-0667), and the Beijing Top Young Talents Support Program, China (Grant No. CIT&TCD201404113).

  20. SelInv - An Algorithm for Selected Inversion of a Sparse Symmetric Matrix

    SciTech Connect

    Lin, Lin; Yang, Chao; Meza, Juan C.; Lu, Jianfeng; Ying, Lexing; E, Weinan

    2009-10-16

    We describe an efficient implementation of an algorithm for computing selected elements of a general sparse symmetric matrix A that can be decomposed as A = LDL^T, where L is lower triangular and D is diagonal. Our implementation, which is called SelInv, is built on top of an efficient supernodal left-looking LDL^T factorization of A. We discuss how computational efficiency can be gained by making use of a relative index array to handle indirect addressing. We report the performance of SelInv on a collection of sparse matrices of various sizes and nonzero structures. We also demonstrate how SelInv can be used in electronic structure calculations.

  1. Transient behavior of granular materials with symmetric conditions for tumbler shapes and fill fractions

    NASA Astrophysics Data System (ADS)

    Pohlman, Nicholas; Si, Yun

    2014-11-01

    The typical granular motion in circular tumblers is considered steady-state since there are no features to disrupt the top surface layer dimension. In polygon tumblers, however, the flowing layer is perpetually changing length, which creates unsteady conditions with corresponding change in the flow behavior. Prior work showed the minimization of free surface energy is independent of tumbler dimension, particle size, and rotation rate. This subsequent research reports on experiments where dimensional symmetry of the free surface in triangular and square tumblers with varying fill fractions do not necessarily produce the symmetric flow behaviors. Results of the quasi-2D tumbler experiment show that other dimensions aligned with gravity and the instantaneous free surface influence the phase when extrema for angle of repose and other flow features occur. The conclusion is that 50% fill fraction may produce geometric symmetry of dimensions, but the symmetry point of flow likely occurs at a lower fill fraction.

  2. Separation of variables in anisotropic models and non-skew-symmetric elliptic r-matrix

    NASA Astrophysics Data System (ADS)

    Skrypnyk, Taras

    2016-11-01

    We solve a problem of separation of variables for the classical integrable hamiltonian systems possessing Lax matrices satisfying linear Poisson brackets with the non-skew-symmetric, non-dynamical elliptic so(3)⊗ so(3) -valued classical r-matrix. Using the corresponding Lax matrices, we present a general form of the "separating functions" B(u) and A(u) that generate the coordinates and the momenta of separation for the associated models. We consider several examples and perform the separation of variables for the classical anisotropic Euler's top, Steklov-Lyapunov model of the motion of anisotropic rigid body in the liquid, two-spin generalized Gaudin model and "spin" generalization of Steklov-Lyapunov model.

  3. Heavy flavour physics from top to bottom

    SciTech Connect

    Paulini, M.; CDF and D0 Collaboration

    1998-02-01

    We review the status of heavy flavour physics at the Fermilab Tevatron collider by summarizing recent top quark and B physics results from CDF and D0. In particular we discuss the measurement of the top quark mass and top production cross section as well as B meson lifetimes and time dependent B{anti B} mixing results. An outlook of perspectives for top and B physics in Run II starting in 1999 is also given.

  4. Cloud-top parameters - A hail indicator

    NASA Technical Reports Server (NTRS)

    Pearl, E. W.; Shenk, W. E.; Skillman, W.

    1975-01-01

    Airborne photographic observations of four hail-producing storms are discussed. With the exception of one storm producing a tornadic event, the overshooting tops were nearly steady-state. The tops were consistently high and wide, reaching maximum heights within about 5 minutes of the initiation of hail. Measured updraft velocities in the turrets composing the overshooting top were 25 m/sec. The dimensions of the overshooting tops were sufficiently large to permit satellite observation.

  5. MHD Integrated Topping Cycle Project

    SciTech Connect

    Not Available

    1992-07-01

    This eighteenth quarterly technical progress report of the MHD Integrated Topping cycle Project presents the accomplishments during the period November 1, 1991 to January 31, 1992. The precombustor is fully assembled. Manufacturing of all slagging stage components has been completed. All cooling panels were welded in place and the panel/shell gap was filled with RTV. Final combustor assembly is in progress. The low pressure cooling subsystem (LPCS) was delivered to the CDIF. Second stage brazing issues were resolved. The construction of the two anode power cabinets was completed.

  6. Table-top job analysis

    SciTech Connect

    Not Available

    1994-12-01

    The purpose of this Handbook is to establish general training program guidelines for training personnel in developing training for operation, maintenance, and technical support personnel at Department of Energy (DOE) nuclear facilities. TTJA is not the only method of job analysis; however, when conducted properly TTJA can be cost effective, efficient, and self-validating, and represents an effective method of defining job requirements. The table-top job analysis is suggested in the DOE Training Accreditation Program manuals as an acceptable alternative to traditional methods of analyzing job requirements. DOE 5480-20A strongly endorses and recommends it as the preferred method for analyzing jobs for positions addressed by the Order.

  7. A single-molecule diode

    NASA Astrophysics Data System (ADS)

    Elbing, Mark; Ochs, Rolf; Koentopp, Max; Fischer, Matthias; von Hänisch, Carsten; Weigend, Florian; Evers, Ferdinand; Weber, Heiko B.; Mayor, Marcel

    2005-06-01

    We have designed and synthesized a molecular rod that consists of two weakly coupled electronic π -systems with mutually shifted energy levels. The asymmetry thus implied manifests itself in a current-voltage characteristic with pronounced dependence on the sign of the bias voltage, which makes the molecule a prototype for a molecular diode. The individual molecules were immobilized by sulfur-gold bonds between both electrodes of a mechanically controlled break junction, and their electronic transport properties have been investigated. The results indeed show diode-like current-voltage characteristics. In contrast to that, control experiments with symmetric molecular rods consisting of two identical π -systems did not show significant asymmetries in the transport properties. To investigate the underlying transport mechanism, phenomenological arguments are combined with calculations based on density functional theory. The theoretical analysis suggests that the bias dependence of the polarizability of the molecule feeds back into the current leading to an asymmetric shape of the current-voltage characteristics, similar to the phenomena in a semiconductor diode. Author contributions: F.E., H.B.W., and M.M. designed research; M.E., R.O., M.K., M.F., F.E., H.B.W., and M.M. performed research; M.E., R.O., M.K., M.F., C.v.H., F.W., F.E., H.B.W., and M.M. contributed new reagents/analytic tools; M.E., R.O., M.K., C.v.H., F.E., H.B.W., and M.M. analyzed data; and F.E., H.B.W., and M.M. wrote the paper.This paper was submitted directly (Track II) to the PNAS office.Abbreviations: A, acceptor; D, donor; MCB, mechanically controlled break junction.Data deposition: The atomic coordinates have been deposited in the Cambridge Structural Database, Cambridge Crystallographic Data Centre, Cambridge CB2 1EZ, United Kingdom (CSD reference no. 241632).

  8. Water: a responsive small molecule.

    PubMed

    Shultz, Mary Jane; Vu, Tuan Hoang; Meyer, Bryce; Bisson, Patrick

    2012-01-17

    Unique among small molecules, water forms a nearly tetrahedral yet flexible hydrogen-bond network. In addition to its flexibility, this network is dynamic: bonds are formed or broken on a picosecond time scale. These unique features make probing the local structure of water challenging. Despite the challenges, there is intense interest in developing a picture of the local water structure due to water's fundamental importance in many fields of chemistry. Understanding changes in the local network structure of water near solutes likely holds the key to unlock problems from analyzing parameters that determine the three dimensional structure of proteins to modeling the fate of volatile materials released into the atmosphere. Pictures of the local structure of water are heavily influenced by what is known about the structure of ice. In hexagonal I(h) ice, the most stable form of solid water under ordinary conditions, water has an equal number of donor and acceptor bonds; a kind of symmetry. This symmetric tetrahedral coordination is only approximately preserved in the liquid. The most obvious manifestation of this altered tetrahedral bonding is the greater density in the liquid compared with the solid. Formation of an interface or addition of solutes further modifies the local bonding in water. Because the O-H stretching frequency is sensitive to the environment, vibrational spectroscopy provides an excellent probe for the hydrogen-bond structure in water. In this Account, we examine both local interactions between water and small solutes and longer range interactions at the aqueous surface. Locally, the results suggest that water is not a symmetric donor or acceptor, but rather has a propensity to act as an acceptor. In interactions with hydrocarbons, action is centered at the water oxygen. For soluble inorganic salts, interaction is greater with the cation than the anion. The vibrational spectrum of the surface of salt solutions is altered compared with that of neat

  9. Top quark physics expectations at the LHC

    SciTech Connect

    ATLAS Collaboration; CMS Collaboration; Gaponenko, Andrei

    2008-09-30

    The top quark will be produced copiously at the LHC. This will make possible detailed physics studies, and also the use of top quark decays for detector calibration. This talk reviews plans and prospects for top physics activities in ATLAS and CMS experiments.

  10. A novel sandwich differential capacitive accelerometer with symmetrical double-sided serpentine beam-mass structure

    NASA Astrophysics Data System (ADS)

    Xiao, D. B.; Li, Q. S.; Hou, Z. Q.; Wang, X. H.; Chen, Z. H.; Xia, D. W.; Wu, X. Z.

    2016-02-01

    This paper presents a novel differential capacitive silicon micro-accelerometer with symmetrical double-sided serpentine beam-mass sensing structure and glass-silicon-glass sandwich structure. The symmetrical double-sided serpentine beam-mass sensing structure is fabricated with a novel pre-buried mask fabrication technology, which is convenient for manufacturing multi-layer sensors. The glass-silicon-glass sandwich structure is realized by a double anodic bonding process. To solve the problem of the difficulty of leading out signals from the top and bottom layer simultaneously in the sandwich sensors, a silicon pillar structure is designed that is inherently simple and low-cost. The prototype is fabricated and tested. It has low noise performance (the peak to peak value is 40 μg) and μg-level Allan deviation of bias (2.2 μg in 1 h), experimentally demonstrating the effectiveness of the design and the novel fabrication technology.

  11. Quantum Behavior of Water Molecules Confined to Nanocavities in Gemstones.

    PubMed

    Gorshunov, Boris P; Zhukova, Elena S; Torgashev, Victor I; Lebedev, Vladimir V; Shakurov, Gil'man S; Kremer, Reinhard K; Pestrjakov, Efim V; Thomas, Victor G; Fursenko, Dimitry A; Dressel, Martin

    2013-06-20

    When water is confined to nanocavities, its quantum mechanical behavior can be revealed by terahertz spectroscopy. We place H2O molecules in the nanopores of a beryl crystal lattice and observe a rich and highly anisotropic set of absorption lines in the terahertz spectral range. Two bands can be identified, which originate from translational and librational motions of the water molecule isolated within the cage; they correspond to the analogous broad bands in liquid water and ice. In the present case of well-defined and highly symmetric nanocavities, the observed fine structure can be explained by macroscopic tunneling of the H2O molecules within a six-fold potential caused by the interaction of the molecule with the cavity walls.

  12. Flow-separation patterns on symmetric forebodies

    NASA Technical Reports Server (NTRS)

    Keener, Earl R.

    1986-01-01

    Flow-visualization studies of ogival, parabolic, and conical forebodies were made in a comprehensive investigation of the various types of flow patterns. Schlieren, vapor-screen, oil-flow, and sublimation flow-visualization tests were conducted over an angle-of-attack range from 0 deg. to 88 deg., over a Reynolds-number range from 0.3X10(6) to 2.0X10(6) (based on base diameter), and over a Mach number range from 0.1 to 2. The principal effects of angle of attack, Reynolds number, and Mach number on the occurrence of vortices, the position of vortex shedding, the principal surface-flow-separation patterns, the magnitude of surface-flow angles, and the extent of laminar and turbulent flow for symmetric, asymmetric, and wake-like flow-separation regimes are presented. It was found that the two-dimensional cylinder analogy was helpful in a qualitative sense in analyzing both the surface-flow patterns and the external flow field. The oil-flow studies showed three types of primary separation patterns at the higher Reynolds numbers owing to the influence of boundary-layer transition. The effect of angle of attack and Reynolds number is to change the axial location of the onset and extent of the primary transitional and turbulent separation regions. Crossflow inflectional-instability vortices were observed on the windward surface at angles of attack from 5 deg. to 55 deg. Their effect is to promote early transition. At low angles of attack, near 10 deg., an unexpected laminar-separation bubble occurs over the forward half of the forebody. At high angles of attack, at which vortex asymmetry occurs, the results support the proposition that the principal cause of vortex asymmetry is the hydrodynamic instability of the inviscid flow field. On the other hand, boundary-layer asymmetries also occur, especially at transitional Reynolds numbers. The position of asymmetric vortex shedding moves forward with increasing angle of attack and with increasing Reynolds number, and moves

  13. MHD Integrated Topping Cycle Project

    SciTech Connect

    Not Available

    1992-01-01

    The overall objective of the project is to design and construct prototypical hardware for an integrated MHD topping cycle, and conduct long duration proof-of-concept tests of integrated system at the US DOE Component Development and Integration Facility in Butte, Montana. The results of the long duration tests will augment the existing engineering design data base on MHD power train reliability, availability, maintainability, and performance, and will serve as a basis for scaling up the topping cycle design to the next level of development, an early commercial scale power plant retrofit. The components of the MHD power train to be designed, fabricated, and tested include: A slagging coal combustor with a rated capacity of 50 MW thermal input, capable of operation with an Eastern (Illinois {number sign}6) or Western (Montana Rosebud) coal, a segmented supersonic nozzle, a supersonic MHD channel capable of generating at least 1.5 MW of electrical power, a segmented supersonic diffuser section to interface the channel with existing facility quench and exhaust systems, a complete set of current control circuits for local diagonal current control along the channel, and a set of current consolidation circuits to interface the channel with the existing facility inverter.

  14. MHD Integrated Topping Cycle Project

    SciTech Connect

    Not Available

    1992-03-01

    The Magnetohydrodynamics (MHD) Integrated Topping Cycle (ITC) Project represents the culmination of the proof-of-concept (POC) development stage in the US Department of Energy (DOE) program to advance MHD technology to early commercial development stage utility power applications. The project is a joint effort, combining the skills of three topping cycle component developers: TRW, Avco/TDS, and Westinghouse. TRW, the prime contractor and system integrator, is responsible for the 50 thermal megawatt (50 MW{sub t}) slagging coal combustion subsystem. Avco/TDS is responsible for the MHD channel subsystem (nozzle, channel, diffuser, and power conditioning circuits), and Westinghouse is responsible for the current consolidation subsystem. The ITC Project will advance the state-of-the-art in MHD power systems with the design, construction, and integrated testing of 50 MW{sub t} power train components which are prototypical of the equipment that will be used in an early commercial scale MHD utility retrofit. Long duration testing of the integrated power train at the Component Development and Integration Facility (CDIF) in Butte, Montana will be performed, so that by the early 1990's, an engineering data base on the reliability, availability, maintainability and performance of the system will be available to allow scaleup of the prototypical designs to the next development level. This Sixteenth Quarterly Technical Progress Report covers the period May 1, 1991 to July 31, 1991.

  15. Top quark physics at CDF

    SciTech Connect

    Caner, A.; CDF Collaboration

    1996-08-01

    We present preliminary results on top quark physics recently obtained by the CDF collaboration. The data sample consists of 110 {ital pb}{sup -1} of {ital p{anti p}} collisions at {radical}{ital s} = 1.8 TeV, collected with the Collider Detector at Fermilab during the period 1992 - 1995. We report on the {ital t{anti t}} production cross section and on the top quark mass. The measurements are made in three topologies, corresponding to the decay modes of the {ital Wb} pairs in the final state: lepton + multi-jets, dilepton and all hadronic final state. The analysis performed on the single lepton sample yields the most accurate measurements, due to the good acceptance and the favorable signal to noise ratio obtained after applying some b-tagging techniques. In this channel we measure: {sigma}{sub {ital t{anti t}}} = 6.8{sup +2.3}{sub -1.8} pb M{sub {ital t}} = 175.6 {+-} 5.7 ({ital stat}) {+-} 7.1 ({ital syst.}) {ital GeV/c{sup 2}} Combining the cross sections measured with the lepton + multi-jet and dilepton data we obtain: {sigma}{sub {ital t{anti t}}} = 7.5{sup +1.9}{sub -1.6} {ital pb} A preliminary investigation of the production mechanism of the {ital t{anti t}} system is shown and compared to Standard Model expectations.

  16. Ricci solitons on low-dimensional generalized symmetric spaces

    NASA Astrophysics Data System (ADS)

    Calvaruso, Giovanni; Rosado, Eugenia

    2017-02-01

    We consider three- and four-dimensional pseudo-Riemannian generalized symmetric spaces, whose invariant metrics were explicitly described in Černý and Kowalski (1982). While four-dimensional pseudo-Riemannian generalized symmetric spaces of types A, C and D are algebraic Ricci solitons, the ones of type B are not so. The Ricci soliton equation for their metrics yields a system of partial differential equations. Solving such system, we prove that almost all the four-dimensional pseudo-Riemannian generalized symmetric spaces of type B are Ricci solitons. These examples show some deep differences arising for the Ricci soliton equation between the Riemannian and the pseudo-Riemannian cases, as any homogeneous Riemannian Ricci soliton is algebraic Jablonski (2015). We also investigate three-dimensional generalized symmetric spaces of any signature and prove that they are Ricci solitons.

  17. Systems of Differential Equations with Skew-Symmetric, Orthogonal Matrices

    ERIC Educational Resources Information Center

    Glaister, P.

    2008-01-01

    The solution of a system of linear, inhomogeneous differential equations is discussed. The particular class considered is where the coefficient matrix is skew-symmetric and orthogonal, and where the forcing terms are sinusoidal. More general matrices are also considered.

  18. TRMM Satellite Sees an Non-symmetric Hurricane Cristobal

    NASA Video Gallery

    TRMM satellite passed over Cristobal on Aug. 27 at 8:16 a.m. EDT. Cristobal didn't appear round and symmetric in either clouds or rainfall which suggests that the hurricane is being battered by sou...

  19. A parallel algorithm for the non-symmetric eigenvalue problem

    SciTech Connect

    Dongarra, J.; Sidani, M. |

    1991-12-01

    This paper describes a parallel algorithm for computing the eigenvalues and eigenvectors of a non-symmetric matrix. The algorithm is based on a divide-and-conquer procedure and uses an iterative refinement technique.

  20. Symmetric polynomials in information theory: Entropy and subentropy

    SciTech Connect

    Jozsa, Richard; Mitchison, Graeme

    2015-06-15

    Entropy and other fundamental quantities of information theory are customarily expressed and manipulated as functions of probabilities. Here we study the entropy H and subentropy Q as functions of the elementary symmetric polynomials in the probabilities and reveal a series of remarkable properties. Derivatives of all orders are shown to satisfy a complete monotonicity property. H and Q themselves become multivariate Bernstein functions and we derive the density functions of their Levy-Khintchine representations. We also show that H and Q are Pick functions in each symmetric polynomial variable separately. Furthermore, we see that H and the intrinsically quantum informational quantity Q become surprisingly closely related in functional form, suggesting a special significance for the symmetric polynomials in quantum information theory. Using the symmetric polynomials, we also derive a series of further properties of H and Q.

  1. [Endothelial cell adhesion molecules].

    PubMed

    Ivanov, A N; Norkin, I A; Puchin'ian, D M; Shirokov, V Iu; Zhdanova, O Iu

    2014-01-01

    The review presents current data concerning the functional role of endothelial cell adhesion molecules belonging to different structural families: integrins, selectins, cadherins, and the immunoglobulin super-family. In this manuscript the regulatory mechanisms and factors of adhesion molecules expression and distribution on the surface of endothelial cells are discussed. The data presented reveal the importance of adhesion molecules in the regulation of structural and functional state of endothelial cells in normal conditions and in pathology. Particular attention is paid to the importance of these molecules in the processes of physiological and pathological angiogenesis, regulation of permeability of the endothelial barrier and cell transmigration.

  2. Malachite green mediates homodimerization of antibody VL domains to form a fluorescent ternary complex with singular symmetric interfaces

    PubMed Central

    Szent-Gyorgyi, Chris; Stanfield, Robyn L.; Andreko, Susan; Dempsey, Alison; Ahmed, Mushtaq; Capek, Sara; Waggoner, Alan; Wilson, Ian A.; Bruchez, Marcel P.

    2013-01-01

    We report that a symmetric small molecule ligand mediates the assembly of antibody light chain variable domains (VLs) into a correspondent symmetric ternary complex with novel interfaces. The L5* Fluorogen Activating Protein (FAP) is a VL domain that binds malachite green dye (MG) to activate intense fluorescence. Crystallography of liganded L5* reveals a 2:1 protein:ligand complex with inclusive C2 symmetry, where MG is almost entirely encapsulated between an antiparallel arrangement of the two VL domains. Unliganded L5* VL domains crystallize as a similar antiparallel VL/VL homodimer. The complementarity determining regions (CDRs) are spatially oriented to form novel VL/VL and VL/ligand interfaces that tightly constrain a propeller conformer of MG. Binding equilibrium analysis suggests highly cooperative assembly to form a very stable VL/MG/VL complex, such that MG behaves as a strong chemical inducer of dimerization. Fusion of two VL domains into a single protein tightens MG binding over 1,000-fold to low picomolar affinity without altering the large binding enthalpy, suggesting that bonding interactions with ligand and restriction of domain movements make independent contributions to binding. Fluorescence activation of a symmetrical fluorogen provides a selection mechanism for the isolation and directed evolution of ternary complexes where unnatural symmetric binding interfaces are favored over canonical antibody interfaces. As exemplified by L5*, these self-reporting complexes may be useful as modulators of protein association or as high affinity protein tags and capture reagents. PMID:23978698

  3. Malachite green mediates homodimerization of antibody VL domains to form a fluorescent ternary complex with singular symmetric interfaces.

    PubMed

    Szent-Gyorgyi, Chris; Stanfield, Robyn L; Andreko, Susan; Dempsey, Alison; Ahmed, Mushtaq; Capek, Sarah; Waggoner, Alan S; Wilson, Ian A; Bruchez, Marcel P

    2013-11-15

    We report that a symmetric small-molecule ligand mediates the assembly of antibody light chain variable domains (VLs) into a correspondent symmetric ternary complex with novel interfaces. The L5* fluorogen activating protein is a VL domain that binds malachite green (MG) dye to activate intense fluorescence. Crystallography of liganded L5* reveals a 2:1 protein:ligand complex with inclusive C2 symmetry, where MG is almost entirely encapsulated between an antiparallel arrangement of the two VL domains. Unliganded L5* VL domains crystallize as a similar antiparallel VL/VL homodimer. The complementarity-determining regions are spatially oriented to form novel VL/VL and VL/ligand interfaces that tightly constrain a propeller conformer of MG. Binding equilibrium analysis suggests highly cooperative assembly to form a very stable VL/MG/VL complex, such that MG behaves as a strong chemical inducer of dimerization. Fusion of two VL domains into a single protein tightens MG binding over 1000-fold to low picomolar affinity without altering the large binding enthalpy, suggesting that bonding interactions with ligand and restriction of domain movements make independent contributions to binding. Fluorescence activation of a symmetrical fluorogen provides a selection mechanism for the isolation and directed evolution of ternary complexes where unnatural symmetric binding interfaces are favored over canonical antibody interfaces. As exemplified by L5*, these self-reporting complexes may be useful as modulators of protein association or as high-affinity protein tags and capture reagents.

  4. Noncommutative deformations of locally symmetric Kähler manifolds

    NASA Astrophysics Data System (ADS)

    Hara, Kentaro; Sako, Akifumi

    2017-04-01

    We derive algebraic recurrence relations to obtain a deformation quantization with separation of variables for a locally symmetric Kähler manifold. This quantization method is one of the ways to perform a deformation quantization of Kähler manifolds, which is introduced by Karabegov. From the recurrence relations, concrete expressions of star products for one-dimensional local symmetric Kähler manifolds and CPN are constructed. The recurrence relations for a Grassmann manifold G2,2 are closely studied too.

  5. Self-Similar Subsets of Symmetric Cantor Sets

    NASA Astrophysics Data System (ADS)

    Zeng, Ying

    This paper concerns the affine embeddings of general symmetric Cantor sets. Under certain condition, we show that if a self-similar set F can be affinely embedded into a symmetric Cantor set E, then their contractions are rationally commensurable. Our result supports Conjecture 1.2 in [D. J. Feng, W. Huang and H. Rao, Affine embeddings and intersections of Cantor sets, J. Math. Pures Appl. 102 (2014) 1062-1079].

  6. Uniqueness of symmetric basis in quasi-Banach spaces

    NASA Astrophysics Data System (ADS)

    Albiac, F.; Leránoz, C.

    2008-12-01

    We show that if X is a nonlocally convex natural quasi-Banach space with symmetric basis whose Banach envelope is isomorphic to l1, then all symmetric bases of X are equivalent. The scope of this result is quite ample since the Banach envelopes of natural quasi-Banach spaces with basis always exhibit an l1-like behavior, in the sense that they contain copies of 's uniformly complemented.

  7. Stochastic thermodynamics for Ising chain and symmetric exclusion process

    NASA Astrophysics Data System (ADS)

    Toral, R.; Van den Broeck, C.; Escaff, D.; Lindenberg, Katja

    2017-03-01

    We verify the finite-time fluctuation theorem for a linear Ising chain in contact with heat reservoirs at its ends. Analytic results are derived for a chain consisting of two spins. The system can be mapped onto a model for particle transport, namely, the symmetric exclusion process in contact with thermal and particle reservoirs. We modify the symmetric exclusion process to represent a thermal engine and reproduce universal features of the efficiency at maximum power.

  8. CP Violation in Single Top Quark Production

    SciTech Connect

    Geng, Weigang

    2012-01-01

    We present a search for CP violation in single top quark production with the DØ experiment at the Tevatron proton-antiproton collider. CP violation in the top electroweak interaction results in different single top quark production cross sections for top and antitop quarks. We perform the search in the single top quark final state using 5.4 fb-1 of data, in the s-channel, t-channel, and for both combined. At this time, we do not see an observable CP asymmetry.

  9. Top Quark Studies at D0

    SciTech Connect

    Peters, Reinhild Yvonne

    2014-11-26

    Years after its discovery in 1995 by CDF and D0, the top quark still undergoes intense investigations at the Tevatron. Using up to the full Run II data sample, new measurements of top quark production and properties by the D0 Collaboration are presented. In particular, the first observation of single top quark s-channel production, the measurement of differential tbar t distributions, forward-backward tbar t asymmetry, a new measurement of the top quark mass, and a measurement of the top quark charge are discussed.

  10. Measurements of top quark properties at CDF

    SciTech Connect

    Kraan, Aafke C.; /Pennsylvania U.

    2006-11-01

    The top quark with its mass of about 172 GeV/c{sup 2} is the most massive fundamental particle observed by experiment. In this talk they highlight the most recent measurements of several top quark properties performed with the CDF detector based on data samples corresponding to integrated luminosities up to 1 fb{sup -1}. These results include a search for top quark pair production via new massive resonances, measurements of the helicity of the W boson from top-quark decay, and a direct limit on the lifetime of the top quark.

  11. Growth of heat trace coefficients for locally symmetric spaces

    NASA Astrophysics Data System (ADS)

    Gilkey, P.; Miatello, R. J.

    2012-10-01

    We study the asymptotic behavior of the heat trace coefficients an as n → ∞ for the scalar Laplacian in the context of locally symmetric spaces. We show that if a locally symmetric space is modeled on a noncompact type symmetric space X = G/K such that G has one conjugacy class of Cartan subgroups then these coefficients are O(C^n/n!) for some C > 0. In contrast, we prove that for even dimensional locally rank 1-symmetric spaces, one has |an| ≈ C'n . n! for some C' > 0. We conjecture this is the growth for general noncompact type symmetric spaces unless all Cartan subgroups in G are conjugate. These spaces also have the distinguishing property that the Huygens principle for the shifted wave equation holds (n odd). These examples show that growth estimates conjectured by Berry and Howls ["High orders of the Weyl expansion for quantum billiards: Resurgence of periodic orbits and the Stokes phenomenon," Proc. R. Soc. London A 447, 527-555 (1994), 10.1098/rspa.1994.0154] are sharp. We also construct examples of locally symmetric spaces which are not irreducible, which are not flat, and so that only a finite number of the an is non-zero.

  12. Symmetric and antisymmetric forms of the Pauli master equation

    PubMed Central

    Klimenko, A. Y.

    2016-01-01

    When applied to matter and antimatter states, the Pauli master equation (PME) may have two forms: time-symmetric, which is conventional, and time-antisymmetric, which is suggested in the present work. The symmetric and antisymmetric forms correspond to symmetric and antisymmetric extensions of thermodynamics from matter to antimatter — this is demonstrated by proving the corresponding H-theorem. The two forms are based on the thermodynamic similarity of matter and antimatter and differ only in the directions of thermodynamic time for matter and antimatter (the same in the time-symmetric case and the opposite in the time-antisymmetric case). We demonstrate that, while the symmetric form of PME predicts an equibalance between matter and antimatter, the antisymmetric form of PME favours full conversion of antimatter into matter. At this stage, it is impossible to make an experimentally justified choice in favour of the symmetric or antisymmetric versions of thermodynamics since we have no experience of thermodynamic properties of macroscopic objects made of antimatter, but experiments of this kind may become possible in the future. PMID:27440454

  13. Symmetric and antisymmetric forms of the Pauli master equation

    NASA Astrophysics Data System (ADS)

    Klimenko, A. Y.

    2016-07-01

    When applied to matter and antimatter states, the Pauli master equation (PME) may have two forms: time-symmetric, which is conventional, and time-antisymmetric, which is suggested in the present work. The symmetric and antisymmetric forms correspond to symmetric and antisymmetric extensions of thermodynamics from matter to antimatter — this is demonstrated by proving the corresponding H-theorem. The two forms are based on the thermodynamic similarity of matter and antimatter and differ only in the directions of thermodynamic time for matter and antimatter (the same in the time-symmetric case and the opposite in the time-antisymmetric case). We demonstrate that, while the symmetric form of PME predicts an equibalance between matter and antimatter, the antisymmetric form of PME favours full conversion of antimatter into matter. At this stage, it is impossible to make an experimentally justified choice in favour of the symmetric or antisymmetric versions of thermodynamics since we have no experience of thermodynamic properties of macroscopic objects made of antimatter, but experiments of this kind may become possible in the future.

  14. Liquid-liquid interfacial properties of a symmetrical Lennard-Jones binary mixture.

    PubMed

    Martínez-Ruiz, F J; Moreno-Ventas Bravo, A I; Blas, F J

    2015-09-14

    We determine the interfacial properties of a symmetrical binary mixture of equal-sized spherical Lennard-Jones molecules, σ11 = σ22, with the same dispersive energy between like species, ϵ11 = ϵ22, but different dispersive energies between unlike species low enough to induce phase separation. We use the extensions of the improved version of the inhomogeneous long-range corrections of Janec̆ek [J. Phys. Chem. B 110, 6264 (2006)], presented recently by MacDowell and Blas [J. Chem. Phys. 131, 074705 (2009)] and Martínez-Ruiz et al. [J. Chem. Phys. 141, 184701 (2014)], to deal with the interaction energy and microscopic components of the pressure tensor. We perform Monte Carlo simulations in the canonical ensemble to obtain the interfacial properties of the symmetrical mixture with different cut-off distances rc and in combination with the inhomogeneous long-range corrections. The pressure tensor is obtained using the mechanical (virial) and thermodynamic route. The liquid-liquid interfacial tension is also evaluated using three different procedures, the Irving-Kirkwood method, the difference between the macroscopic components of the pressure tensor, and the test-area methodology. This allows to check the validity of the recent extensions presented to deal with the contributions due to long-range corrections for intermolecular energy and pressure tensor in the case of binary mixtures that exhibit liquid-liquid immiscibility. In addition to the pressure tensor and the surface tension, we also obtain density profiles and coexistence densities and compositions as functions of pressure, at a given temperature. According to our results, the main effect of increasing the cut-off distance rc is to sharpen the liquid-liquid interface and to increase the width of the biphasic coexistence region. Particularly interesting is the presence of a relative minimum in the total density profiles of the symmetrical mixture. This minimum is related with a desorption of the molecules

  15. Liquid-liquid interfacial properties of a symmetrical Lennard-Jones binary mixture

    SciTech Connect

    Martínez-Ruiz, F. J.; Blas, F. J.; Moreno-Ventas Bravo, A. I.

    2015-09-14

    We determine the interfacial properties of a symmetrical binary mixture of equal-sized spherical Lennard-Jones molecules, σ{sub 11} = σ{sub 22}, with the same dispersive energy between like species, ϵ{sub 11} = ϵ{sub 22}, but different dispersive energies between unlike species low enough to induce phase separation. We use the extensions of the improved version of the inhomogeneous long-range corrections of Janecek [J. Phys. Chem. B 110, 6264 (2006)], presented recently by MacDowell and Blas [J. Chem. Phys. 131, 074705 (2009)] and Martínez-Ruiz et al. [J. Chem. Phys. 141, 184701 (2014)], to deal with the interaction energy and microscopic components of the pressure tensor. We perform Monte Carlo simulations in the canonical ensemble to obtain the interfacial properties of the symmetrical mixture with different cut-off distances r{sub c} and in combination with the inhomogeneous long-range corrections. The pressure tensor is obtained using the mechanical (virial) and thermodynamic route. The liquid-liquid interfacial tension is also evaluated using three different procedures, the Irving-Kirkwood method, the difference between the macroscopic components of the pressure tensor, and the test-area methodology. This allows to check the validity of the recent extensions presented to deal with the contributions due to long-range corrections for intermolecular energy and pressure tensor in the case of binary mixtures that exhibit liquid-liquid immiscibility. In addition to the pressure tensor and the surface tension, we also obtain density profiles and coexistence densities and compositions as functions of pressure, at a given temperature. According to our results, the main effect of increasing the cut-off distance r{sub c} is to sharpen the liquid-liquid interface and to increase the width of the biphasic coexistence region. Particularly interesting is the presence of a relative minimum in the total density profiles of the symmetrical mixture. This minimum is related

  16. Liquid-liquid interfacial properties of a symmetrical Lennard-Jones binary mixture

    NASA Astrophysics Data System (ADS)

    Martínez-Ruiz, F. J.; Moreno-Ventas Bravo, A. I.; Blas, F. J.

    2015-09-01

    We determine the interfacial properties of a symmetrical binary mixture of equal-sized spherical Lennard-Jones molecules, σ11 = σ22, with the same dispersive energy between like species, ɛ11 = ɛ22, but different dispersive energies between unlike species low enough to induce phase separation. We use the extensions of the improved version of the inhomogeneous long-range corrections of Janec̆ek [J. Phys. Chem. B 110, 6264 (2006)], presented recently by MacDowell and Blas [J. Chem. Phys. 131, 074705 (2009)] and Martínez-Ruiz et al. [J. Chem. Phys. 141, 184701 (2014)], to deal with the interaction energy and microscopic components of the pressure tensor. We perform Monte Carlo simulations in the canonical ensemble to obtain the interfacial properties of the symmetrical mixture with different cut-off distances rc and in combination with the inhomogeneous long-range corrections. The pressure tensor is obtained using the mechanical (virial) and thermodynamic route. The liquid-liquid interfacial tension is also evaluated using three different procedures, the Irving-Kirkwood method, the difference between the macroscopic components of the pressure tensor, and the test-area methodology. This allows to check the validity of the recent extensions presented to deal with the contributions due to long-range corrections for intermolecular energy and pressure tensor in the case of binary mixtures that exhibit liquid-liquid immiscibility. In addition to the pressure tensor and the surface tension, we also obtain density profiles and coexistence densities and compositions as functions of pressure, at a given temperature. According to our results, the main effect of increasing the cut-off distance rc is to sharpen the liquid-liquid interface and to increase the width of the biphasic coexistence region. Particularly interesting is the presence of a relative minimum in the total density profiles of the symmetrical mixture. This minimum is related with a desorption of the molecules

  17. How far the postorogenic extensional tectonics in the Aegean domain is symmetric?

    NASA Astrophysics Data System (ADS)

    Augier, Romain; Jolivet, Laurent; Gadenne, Leslie; Driussi, Olivier

    2013-04-01

    Current models to explain the finite geometry of the Aegean domain and the exhumation of the eclogite-bearing HP rocks in the Aegean domain rely on the recognition of a synorogenic exhumation regime followed by a postorogenic back-arc extension. A first generation of low-angle normal faults (LANF) developed during the subduction and the formation of the Hellenic Eocene orogenic wedge contemporaneously with the overthrusting of the Cycladic Blueschists over basement units. Other LANF were formed subsequently and accompanied the development of Metamorphic Core Complexes (MCC) during the collapse of the internal zones in the back-arc domain. Most of the stretching during postorogenic extension was accommodated by N-dipping LANF with N- to NE-sense of shear pertaining to the North Cycladic Detachment System (NCDS). More recently, the description of the top-to-the-south West Cycladic Detachment System (WCDS) resulted in a more symmetrical character of the postorogenic extension. However, the transition in time and space between these major structures, particularly the NCDS and the WCDS, which is a key question to understand the dynamics of the back-arc extension, remains widely unclear. The Folegandros-Sikinos area, whose tectonometamorphic evolution appears poorly constrained, is however quite exemplary of this discussion. Located to the south of the Cycladic Archipelago, at short distance from the WCDS last outcrop in Serifos Island, this area offers the opportunity to study both the synorogenic deformation preserved at the vicinity of the Cycladic basement and the structural transition between areas characterised by top-to-the-North and top-to-the-South kinematics during the postorogenic history. Based on an extensive field survey making the link between kinematics of the noncoaxial deformation and changing metamorphic conditions, we show that (1) a E-W syn-blueschists facies deformation is preserved within the HP lenses; (2) a penetrative, post-blueschists facies

  18. Finite plasticity in \\varvec{P}^top \\varvec{P}. Part I: constitutive model

    NASA Astrophysics Data System (ADS)

    Grandi, Diego; Stefanelli, Ulisse

    2017-01-01

    We address a finite-plasticity model based on the symmetric tensor \\varvec{P}^top \\varvec{P} instead of the classical plastic strain \\varvec{P}. Such a structure arises by assuming that the material behavior is invariant with respect to frame transformations of the intermediate configuration. The resulting variational model is lower dimensional, symmetric and based solely on the reference configuration. We discuss the existence of energetic solutions at the material-point level as well as the convergence of time discretizations. The linearization of the model for small deformations is ascertained via a rigorous evolution-Γ -convergence argument. The constitutive model is combined with the equilibrium system in Part II where we prove the existence of quasistatic evolutions and ascertain the linearization limit (Grandi and Stefanelli in 2016).

  19. Molecular docking guided structure based design of symmetrical N,N'-disubstituted urea/thiourea as HIV-1 gp120-CD4 binding inhibitors.

    PubMed

    Sivan, Sree Kanth; Vangala, Radhika; Manga, Vijjulatha

    2013-08-01

    Induced fit molecular docking studies were performed on BMS-806 derivatives reported as small molecule inhibitors of HIV-1 gp120-CD4 binding. Comprehensive study of protein-ligand interactions guided in identification and design of novel symmetrical N,N'-disubstituted urea and thiourea as HIV-1 gp120-CD4 binding inhibitors. These molecules were synthesized in aqueous medium using microwave irradiation. Synthesized molecules were screened for their inhibitory ability by HIV-1 gp120-CD4 capture enzyme-linked immunosorbent assay (ELISA). Designed compounds were found to inhibit HIV-1 gp120-CD4 binding in micromolar (0.013-0.247 μM) concentrations.

  20. Locally parity-time-symmetric and globally parity-symmetric systems

    NASA Astrophysics Data System (ADS)

    Ahmed, W. W.; Herrero, R.; Botey, M.; Staliunas, K.

    2016-11-01

    We introduce a class of systems holding parity-time (PT ) symmetry locally, whereas being globally P symmetric. The potential, U =U (|r |) , fulfills PT symmetry with respect to periodically distributed points r0:U (| r0+r |) =U*(| r0-r |) being r0≠0 . We show that such systems hold unusual properties arising from the merging of the two different symmetries, leading to a strong field localization and enhancement at the double-symmetry center, r =0 , when the coupling of outward to inward propagating waves is favored. We explore such general potentials in one and two dimensions, which could have actual realizations combining gain-loss and index modulations in nanophotonic structures. In particular, we show how to render a broad aperture vertical-cavity surface-emitting laser into a bright and narrow beam source, as a direct application.

  1. Enzymatic DNA molecules

    NASA Technical Reports Server (NTRS)

    Joyce, Gerald F. (Inventor); Breaker, Ronald R. (Inventor)

    1998-01-01

    The present invention discloses deoxyribonucleic acid enzymes--catalytic or enzymatic DNA molecules--capable of cleaving nucleic acid sequences or molecules, particularly RNA, in a site-specific manner, as well as compositions including same. Methods of making and using the disclosed enzymes and compositions are also disclosed.

  2. Molecules between the Stars.

    ERIC Educational Resources Information Center

    Verschuur, Gerrit L.

    1987-01-01

    Provides a listing of molecules discovered to date in the vast interstellar clouds of dust and gas. Emphasizes the recent discoveries of organic molecules. Discusses molecular spectral lines, MASERs (microwave amplification by stimulated emission of radiation), molecular clouds, and star birth. (TW)

  3. MHD Integrated Topping Cycle Project

    SciTech Connect

    Not Available

    1992-07-01

    This seventeenth quarterly technical progress report of the MHD Integrated Topping Cycle Project presents the accomplishments during the period August 1, 1991 to October 31, 1991. Manufacturing of the prototypical combustor pressure shell has been completed including leak, proof, and assembly fit checking. Manufacturing of forty-five cooling panels was also completed including leak, proof, and flow testing. All precombustor internal components (combustion can baffle and swirl box) were received and checked, and integration of the components was initiated. A decision was made regarding the primary and backup designs for the 1A4 channel. The assembly of the channel related prototypical hardware continued. The cathode wall electrical wiring is now complete. The mechanical design of the diffuser has been completed.

  4. Porous organic molecules

    NASA Astrophysics Data System (ADS)

    Holst, James R.; Trewin, Abbie; Cooper, Andrew I.

    2010-11-01

    Most synthetic materials that show molecular-scale porosity consist of one-, two- or three-dimensional networks. Porous metal-organic frameworks in particular have attracted a lot of recent attention. By contrast, discrete molecules tend to pack efficiently in the solid state, leaving as little empty space as possible, which leads to non-porous materials. This Perspective discusses recent developments with discrete organic molecules that are porous in the solid state. Such molecules, which may be either crystalline or amorphous, can be categorized as either intrinsically porous (containing permanent covalent cavities) or extrinsically porous (inefficiently packed). We focus on the possible advantages of organic molecules over inorganic or hybrid systems in terms of molecular solubility, choice of components and functionalities, and structural mobility and responsiveness in non-covalent extended solids. We also highlight the potential for 'undiscovered' porous systems among the large number of cage-like organic molecules that are already known.

  5. Designing a small molecule erythropoietin mimetic.

    PubMed

    Guarnieri, Frank

    2015-01-01

    Erythropoietin (EPO) is a protein made by the kidneys in response to low red blood cell count that is secreted into the bloodstream and binds to a receptor on hematopoietic stem cells in the bone marrow inducing them to become new red blood cells. EPO made with recombinant DNA technology was brought to market in the 1980s to treat anemia caused by kidney disease and cancer chemotherapy. Because EPO infusion was able to replace blood transfusions in many cases, it rapidly became a multibillion dollar per year drug and as the first biologic created with recombinant technology it launched the biotech industry. For many years intense research was focused on creating a small molecule orally available EPO mimetic. The Robert Wood Johnson (RWJ) group seemed to definitively establish that only large peptides with a minimum of 60 residues could replace EPO, as anything less was not a full agonist. An intense study of the published work led me to hypothesize that the size of the mimetic is not the real issue, but the symmetry making and breaking of the EPO receptor induced by the ligand is the key to activating the stem cells. This analysis meant that residues in the binding site of the receptor deemed absolutely essential for ligand binding and activation from mutagenesis experiments, were probably not really that important. My fundamental hypotheses were: (a) the symmetric state of the homodimeric receptor is the most stable state and thus must be the off-state, (b) a highly localized binding site exists at a pivot point where the two halves of the receptor meet, (c) small molecules can be created that have high potency for this site that will be competitive with EPO and thus can displace the protein-protein interaction, (d) small symmetric molecules will stabilize the symmetric off-state of the receptor, and (e) a key asymmetry in the small molecule will stabilize a mirror image asymmetry in the receptor resulting in the stabilization of the on-state and proliferation of

  6. Graphene-Enhanced Raman Scattering from the Adenine Molecules

    NASA Astrophysics Data System (ADS)

    Dolgov, Leonid; Pidhirnyi, Denys; Dovbeshko, Galyna; Lebedieva, Tetiana; Kiisk, Valter; Heinsalu, Siim; Lange, Sven; Jaaniso, Raivo; Sildos, Ilmo

    2016-04-01

    An enhanced Raman scattering from a thin layer of adenine molecules deposited on graphene substrate was detected. The value of enhancement depends on the photon energy of the exciting light. The benzene ring in the structure of adenine molecule suggests π-stacking of adenine molecule on top of graphene. So, it is proposed that the enhancement in the adenine Raman signal is explained by the resonance electron transfer from the Fermi level of graphene to the lowest unoccupied molecular orbital (LUMO) level of adenine.

  7. The rise and fall of spinning tops

    NASA Astrophysics Data System (ADS)

    Cross, Rod

    2013-04-01

    The motion of four different spinning tops was filmed with a high-speed video camera. Unlike pointed tops, tops with a rounded peg precess initially about a vertical axis that lies well outside the top, and then spiral inward until the precession axis passes through a point close to the center-of-mass. The center-of-mass of a top with a rounded peg can rise as a result of rolling rather than sliding friction, contrary to the explanation normally given for the rise of spinning tops. A tippe top was also filmed and was observed to jump vertically off a horizontal surface several times while the center-of-mass was rising, contrary to the usual assumption that the normal reaction force on a tippe top remains approximately equal to its weight. It was found that the center-of-mass of a tippe top rises as a result of rolling friction at low spin frequencies and as a result of sliding friction at high spin frequencies. It was also found that, at low spin frequencies, a tippe top can precess at two different frequencies simultaneously.

  8. Discrete energy transport in collagen molecules

    NASA Astrophysics Data System (ADS)

    Alain, Mvogo; Germain, H. Ben-Bolie; Timoléon, C. Kofané

    2014-09-01

    The modulational instability in the three coupled α-polypeptide chains of a collagen molecule is investigated. Choosing symmetric and asymmetric solutions, and applying the so-called rotating-wave approximation, we describe the dynamics of the system by the discrete nonlinear Schrödinger (DNLS) equation. The linear stability analysis of the continuous wave solution is performed. The numerical simulations show the generation of trains of solitonic structures in the lattice with increasing amplitude as time progresses. The effect of damping and noise forces of the physiological temperature (T = 300 K) introduces an erratic behavior to the formed patterns, reinforcing the idea that the energy used in metabolic processes is confined to specific regions for efficiency.

  9. Dynamics of Activated Molecules

    SciTech Connect

    Mullin, Amy S.

    2016-11-16

    Experimental studies have been performed to investigate the collisional energy transfer processes of gas-phase molecules that contain large amounts of internal energy. Such molecules are prototypes for molecules under high temperature conditions relevant in combustion and information about their energy transfer mechanisms is needed for a detailed understanding and modeling of the chemistry. We use high resolution transient IR absorption spectroscopy to measure the full, nascent product distributions for collisions of small bath molecules that relax highly vibrationally excited pyrazine molecules with E=38000 cm-1 of vibrational energy. To perform these studies, we developed new instrumentation based on modern IR light sources to expand our experimental capabilities to investigate new molecules as collision partners. This final report describes our research in four areas: the characterization of a new transient absorption spectrometer and the results of state-resolved collision studies of pyrazine(E) with HCl, methane and ammonia. Through this research we have gained fundamental new insights into the microscopic details of relatively large complex molecules at high energy as they undergo quenching collisions and redistribute their energy.

  10. View-Tolerant Face Recognition and Hebbian Learning Imply Mirror-Symmetric Neural Tuning to Head Orientation.

    PubMed

    Leibo, Joel Z; Liao, Qianli; Anselmi, Fabio; Freiwald, Winrich A; Poggio, Tomaso

    2017-01-09

    The primate brain contains a hierarchy of visual areas, dubbed the ventral stream, which rapidly computes object representations that are both specific for object identity and robust against identity-preserving transformations, like depth rotations [1, 2]. Current computational models of object recognition, including recent deep-learning networks, generate these properties through a hierarchy of alternating selectivity-increasing filtering and tolerance-increasing pooling operations, similar to simple-complex cells operations [3-6]. Here, we prove that a class of hierarchical architectures and a broad set of biologically plausible learning rules generate approximate invariance to identity-preserving transformations at the top level of the processing hierarchy. However, all past models tested failed to reproduce the most salient property of an intermediate representation of a three-level face-processing hierarchy in the brain: mirror-symmetric tuning to head orientation [7]. Here, we demonstrate that one specific biologically plausible Hebb-type learning rule generates mirror-symmetric tuning to bilaterally symmetric stimuli, like faces, at intermediate levels of the architecture and show why it does so. Thus, the tuning properties of individual cells inside the visual stream appear to result from group properties of the stimuli they encode and to reflect the learning rules that sculpted the information-processing system within which they reside.

  11. Ultrafast optical switching using photonic molecules in photonic crystal waveguides.

    PubMed

    Zhao, Yanhui; Qian, Chenjiang; Qiu, Kangsheng; Gao, Yunan; Xu, Xiulai

    2015-04-06

    We study the coupling between photonic molecules and waveguides in photonic crystal slab structures using finite-difference time-domain method and coupled mode theory. In a photonic molecule with two cavities, the coupling of cavity modes results in two super-modes with symmetric and anti-symmetric field distributions. When two super-modes are excited simultaneously, the energy of electric field oscillates between the two cavities. To excite and probe the energy oscillation, we integrate photonic molecule with two photonic crystal waveguides. In coupled structure, we find that the quality factors of two super-modes might be different because of different field distributions of super-modes. After optimizing the radii of air holes between two cavities of photonic molecule, nearly equal quality factors of two super-modes are achieved, and coupling strengths between the waveguide modes and two super-modes are almost the same. In this case, complete energy oscillations between two cavities can be obtained with a pumping source in one waveguide, which can be read out by another waveguide. Finally, we demonstrate that the designed structure can be used for ultrafast optical switching with a time scale of a few picoseconds.

  12. C 3-symmetric opioid scaffolds are pH-responsive DNA condensation agents

    PubMed Central

    McStay, Natasha; Molphy, Zara; Coughlan, Alan; Cafolla, Attilio; McKee, Vickie; Gathergood, Nicholas; Kellett, Andrew

    2017-01-01

    Herein we report the synthesis of tripodal C3-symmetric opioid scaffolds as high-affinity condensation agents of duplex DNA. Condensation was achieved on both supercoiled and canonical B-DNA structures and identified by agarose electrophoresis, viscosity, turbidity and atomic force microscopy (AFM) measurements. Structurally, the requirement of a tris-opioid scaffold for condensation is demonstrated as both di- (C2-symmetric) and mono-substituted (C1-symmetric) mesitylene-linked opioid derivatives poorly coordinate dsDNA. Condensation, observed by toroidal and globule AFM aggregation, arises from surface-binding ionic interactions between protonated, cationic, tertiary amine groups on the opioid skeleton and the phosphate nucleic acid backbone. Indeed, by converting the 6-hydroxyl group of C3-morphine (MC3) to methoxy substituents in C3-heterocodeine (HC3) and C3-oripavine (OC3) molecules, dsDNA compaction is retained thus negating the possibility of phosphate—hydroxyl surface-binding. Tripodal opioid condensation was identified as pH dependent and strongly influenced by ionic strength with further evidence of cationic amine-phosphate backbone coordination arising from thermal melting analysis and circular dichroism spectroscopy, with compaction also witnessed on synthetic dsDNA co-polymers poly[d(A-T)2] and poly[d(G-C)2]. On-chip microfluidic analysis of DNA condensed by C3-agents provided concentration-dependent protection (inhibition) to site-selective excision by type II restriction enzymes: BamHI, HindIII, SalI and EcoRI, but not to the endonuclease DNase I. PMID:27899572

  13. C 3-symmetric opioid scaffolds are pH-responsive DNA condensation agents.

    PubMed

    McStay, Natasha; Molphy, Zara; Coughlan, Alan; Cafolla, Attilio; McKee, Vickie; Gathergood, Nicholas; Kellett, Andrew

    2017-01-25

    Herein we report the synthesis of tripodal C3-symmetric opioid scaffolds as high-affinity condensation agents of duplex DNA. Condensation was achieved on both supercoiled and canonical B-DNA structures and identified by agarose electrophoresis, viscosity, turbidity and atomic force microscopy (AFM) measurements. Structurally, the requirement of a tris-opioid scaffold for condensation is demonstrated as both di- (C2-symmetric) and mono-substituted (C1-symmetric) mesitylene-linked opioid derivatives poorly coordinate dsDNA. Condensation, observed by toroidal and globule AFM aggregation, arises from surface-binding ionic interactions between protonated, cationic, tertiary amine groups on the opioid skeleton and the phosphate nucleic acid backbone. Indeed, by converting the 6-hydroxyl group of C3-morphine ( MC3: ) to methoxy substituents in C3-heterocodeine ( HC3: ) and C3-oripavine ( OC3: ) molecules, dsDNA compaction is retained thus negating the possibility of phosphate-hydroxyl surface-binding. Tripodal opioid condensation was identified as pH dependent and strongly influenced by ionic strength with further evidence of cationic amine-phosphate backbone coordination arising from thermal melting analysis and circular dichroism spectroscopy, with compaction also witnessed on synthetic dsDNA co-polymers poly[d(A-T)2] and poly[d(G-C)2]. On-chip microfluidic analysis of DNA condensed by C3-agents provided concentration-dependent protection (inhibition) to site-selective excision by type II restriction enzymes: BamHI, HindIII, SalI and EcoRI, but not to the endonuclease DNase I.

  14. Mechanical, physical, and physiological analysis of symmetrical and asymmetrical combat.

    PubMed

    Clemente-Suárez, Vicente J; Robles-Pérez, José J

    2013-09-01

    In current theaters of operation, soldiers had to face a different situation as symmetrical (defined battlefield) and asymmetrical combat (non-defined battlefield), especially in urban areas. The mechanical and organic responses of soldiers in these combats are poorly studied in specific literature. This research aimed to analyze physical, mechanical, and physiological parameters during symmetrical and asymmetrical combat simulations. We analyzed 20 soldiers from the Spanish Army and Spanish Forces and Security Corps (34.5 ± 4.2 years; 176.4 ± 8.4 cm; 74.6 ± 8.7 kg; 63.3 ± 8.0 kg muscular mass; 7.6 ± 3.2 kg fat mass) during a symmetric combat (traditional combat simulation) and during an asymmetrical combat (urban combat simulation). Heart rate (HR), speed, sprints, distances, impact, and body load parameters were measured by a GPS system and a HR belt. Results showed many differences between symmetrical and asymmetrical combat. Asymmetrical combat presented higher maximum velocity movement, number of sprints, sprint distance, and average HR. By contrary, symmetric combat presented higher number of impact and body load. This information could be used to improve specific training programs for each type of combat.

  15. Top quark mass: past, present and future

    SciTech Connect

    Gutierrez, Gaston; /Fermilab

    2007-07-01

    The top quark is the most massive elementary particle discovered thus far. Its large mass may help explain the mechanism by which fundamental particles gain mass - the Standard Model's greatest standing mystery. Today the top quark mass, together with the W boson mass, plays an important role in constraining the Higgs boson mass. The current status of the top quark mass measurement and a brief outline of the expectation at the Large Hadron Collider and the International Linear Collider will be covered.

  16. TOP500 Supercomputers for June 2005

    SciTech Connect

    Strohmaier, Erich; Meuer, Hans W.; Dongarra, Jack; Simon, Horst D.

    2005-06-22

    25th Edition of TOP500 List of World's Fastest Supercomputers Released: DOE/L LNL BlueGene/L and IBM gain Top Positions MANNHEIM, Germany; KNOXVILLE, Tenn.; BERKELEY, Calif. In what has become a closely watched event in the world of high-performance computing, the 25th edition of the TOP500 list of the world's fastest supercomputers was released today (June 22, 2005) at the 20th International Supercomputing Conference (ISC2005) in Heidelberg Germany.

  17. TOP500 Supercomputers for November 2004

    SciTech Connect

    Strohmaier, Erich; Meuer, Hans W.; Dongarra, Jack; Simon, Horst D.

    2004-11-08

    24th Edition of TOP500 List of World's Fastest Supercomputers Released: DOE/IBM BlueGene/L and NASA/SGI's Columbia gain Top Positions MANNHEIM, Germany; KNOXVILLE, Tenn.; BERKELEY, Calif. In what has become a closely watched event in the world of high-performance computing, the 24th edition of the TOP500 list of the worlds fastest supercomputers was released today (November 8, 2004) at the SC2004 Conference in Pittsburgh, Pa.

  18. Top quark mass measurements at CDF

    SciTech Connect

    Maki, Tuula; /Helsinki U. /Helsinki Inst. of Phys.

    2007-10-01

    The top quark mass is interesting both as a fundamental parameter of the standard model as well as an important input to precision electroweak tests. The CDF Collaboration has measured the top quark mass with high precision in all decay channels with complementary methods. A combination of the results from CDF gives a top quark mass of 170.5{+-}1.3(stat.){+-}1.8(syst.) GeV/c{sup 2}.

  19. TOP500 Supercomputers for June 2004

    SciTech Connect

    Strohmaier, Erich; Meuer, Hans W.; Dongarra, Jack; Simon, Horst D.

    2004-06-23

    23rd Edition of TOP500 List of World's Fastest Supercomputers Released: Japan's Earth Simulator Enters Third Year in Top Position MANNHEIM, Germany; KNOXVILLE, Tenn.;&BERKELEY, Calif. In what has become a closely watched event in the world of high-performance computing, the 23rd edition of the TOP500 list of the world's fastest supercomputers was released today (June 23, 2004) at the International Supercomputer Conference in Heidelberg, Germany.

  20. Top quark physics at the Tevatron

    SciTech Connect

    D. Gerdes

    2004-01-28

    Precision studies of the top quark are a prime goal of the Run II physics program at the Fermilab Tevatron. Since the start of Run II in early 2002, the CDF and D0 experiments have analyzed approximately 100 pb{sup -1} of data and have re-established the top quark signal. In this article the author summarizes recent measurements of the top production cross section and mass.

  1. Of Molecules and Models.

    ERIC Educational Resources Information Center

    Brinner, Bonnie

    1992-01-01

    Presents an activity in which models help students visualize both the DNA process and transcription. After constructing DNA, RNA messenger, and RNA transfer molecules; students model cells, protein synthesis, codons, and RNA movement. (MDH)

  2. Boat Deck, Cabin Deck, Bridge Deck, Flat House Top, Stage ...

    Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

    Boat Deck, Cabin Deck, Bridge Deck, Flat House Top, Stage Top, Mast House Top, Upper Deck, Flat House Tops, Forecastle Deck, Main Deck - American Racer, Suisun Bay Reserve Fleet, Benicia, Solano County, CA

  3. Top Quark Mass Measurements at the Tevatron

    SciTech Connect

    Peters, Reinhild Yvonne

    2014-01-01

    Since the discovery of the top quark in 1995 by the CDF and D0 collaborations at the Fermilab Tevatron proton antiproton collider, precise measurements of its mass are ongoing. Using data recorded by the D0 and CDF experiment, corresponding to up to the full Tevatron data sample, top quark mass measurements performed in different final states using various extraction techniques are presented in this article. The recent Tevatron top quark mass combination yields m_t=173.20 +-0.87 GeV. Furthermore, measurements of the top antitop quark mass difference from the Tevatron are discussed.

  4. Top Quark Production Asymmetries AFBt and AFBl

    DOE PAGES

    Berger, Edmond L.; Cao, Qing-Hong; Chen, Chuan-Ren; ...

    2012-02-14

    A large forward-backward asymmetry is seen in both the top quark rapidity distribution AFBt and in the rapidity distribution of charged leptons AFBl from top quarks produced at the Tevatron. We study the kinematic and dynamic aspects of the relationship of the two observables arising from the spin correlation between the charged lepton and the top quark with different polarization states. We emphasize the value of both measurements, and we conclude that a new physics model which produces more right-handed than left-handed top quarks is favored by the present data.

  5. A Symmetrical Tetramer for S. aureus Pyruvate Carboxylase in Complex with Coenzyme A

    SciTech Connect

    Yu, L.; Xiang, S; Lasso, G; Gil, D; Valle, M; Tong, L

    2009-01-01

    Pyruvate carboxylase (PC) is a conserved metabolic enzyme with important cellular functions. We report crystallographic and cryo-electron microscopy (EM) studies of Staphylococcus aureus PC (SaPC) in complex with acetyl-CoA, an allosteric activator, and mutagenesis, biochemical, and structural studies of the biotin binding site of its carboxyltransferase (CT) domain. The disease-causing A610T mutation abolishes catalytic activity by blocking biotin binding to the CT active site, and Thr908 might play a catalytic role in the CT reaction. The crystal structure of SaPC in complex with CoA reveals a symmetrical tetramer, with one CoA molecule bound to each monomer, and cryo-EM studies confirm the symmetrical nature of the tetramer. These observations are in sharp contrast to the highly asymmetrical tetramer of Rhizobium etli PC in complex with ethyl-CoA. Our structural information suggests that acetyl-CoA promotes a conformation for the dimer of the biotin carboxylase domain of PC that might be catalytically more competent.

  6. MHD Integrated Topping Cycle Project

    SciTech Connect

    Not Available

    1992-02-01

    This fourteenth quarterly technical progress report of the MHD Integrated Topping Cycle Project presents the accomplishments during the period November 1, 1990 to January 31, 1991. Testing of the High Pressure Cooling Subsystem electrical isolator was completed. The PEEK material successfully passed the high temperature, high pressure duration tests (50 hours). The Combustion Subsystem drawings were CADAM released. The procurement process is in progress. An equipment specification and RFP were prepared for the new Low Pressure Cooling System (LPCS) and released for quotation. Work has been conducted on confirmation tests leading to final gas-side designs and studies to assist in channel fabrication.The final cathode gas-side design and the proposed gas-side designs of the anode and sidewall are presented. Anode confirmation tests and related analyses of anode wear mechanisms used in the selection of the proposed anode design are presented. Sidewall confirmation tests, which were used to select the proposed gas-side design, were conducted. The design for the full scale CDIF system was completed. A test program was initiated to investigate the practicality of using Avco current controls for current consolidation in the power takeoff (PTO) regions and to determine the cause of past current consolidation failures. Another important activity was the installation of 1A4-style coupons in the 1A1 channel. A description of the coupons and their location with 1A1 channel is presented herein.

  7. Top-of-Rail lubricant

    SciTech Connect

    Alzoubi, M. F.; Fenske, G. R.; Erck, R. A.; Boparai, A. S.

    2000-07-14

    Analysis of the volatile and semivolatile fractions collected after use of the TOR lubricant indicated that other than contaminants in the collection laboratory, no compounds on the EPA's Target Compound Lists (Tables 2 and 5) were detected in these fractions. The data of these qualitative analyses, given in the various tables in the text, indicate only the relative amounts of the tentatively identified compounds. The authors recommend that quantitative analysis be performed on the volatile and semivolatile fractions to allow confirmation of the tentatively identified compounds and to obtain absolute amounts of the detected compounds. Additionally, the semivolatile fraction should be analyzed by liquid chromatography/mass spectrometry to identify compounds that are not chromatographable under the temperature program used for determination of semivolatile compounds. Introducing the top-of-rail (TOR) lubricant into the wheel/rail interface results in a reduction of almost 60% of lateral friction force over the forces encountered under dry conditions. This reveals good potential for energy savings, as well as wear reduction, for railroad companies. In TOR lubrication, an increase in the angle of attack and axle load results in increased lateral friction and rate of lubricant consumption. The most efficient TOR lubricant quantity to be used in the wheel/rail interface must be calculated precisely according to the number of cars, axle loads, train speed, and angle of attack.

  8. Canonical distributions on Riemannian homogeneous k-symmetric spaces

    NASA Astrophysics Data System (ADS)

    Balashchenko, Vitaly V.

    2015-01-01

    It is known that distributions generated by almost product structures are applicable, in particular, to some problems in the theory of Monge-Ampère equations. In this paper, we characterize canonical distributions defined by canonical almost product structures on Riemannian homogeneous k-symmetric spaces in the sense of types AF (anti-foliation), F (foliation), TGF (totally geodesic foliation). Algebraic criteria for all these types on k-symmetric spaces of orders k = 4, 5, 6 were obtained. Note that canonical distributions on homogeneous k-symmetric spaces are closely related to special canonical almost complex structures and f-structures, which were recently applied by I. Khemar to studying elliptic integrable systems.

  9. Accessing the exceptional points of parity-time symmetric acoustics

    PubMed Central

    Shi, Chengzhi; Dubois, Marc; Chen, Yun; Cheng, Lei; Ramezani, Hamidreza; Wang, Yuan; Zhang, Xiang

    2016-01-01

    Parity-time (PT) symmetric systems experience phase transition between PT exact and broken phases at exceptional point. These PT phase transitions contribute significantly to the design of single mode lasers, coherent perfect absorbers, isolators, and diodes. However, such exceptional points are extremely difficult to access in practice because of the dispersive behaviour of most loss and gain materials required in PT symmetric systems. Here we introduce a method to systematically tame these exceptional points and control PT phases. Our experimental demonstration hinges on an active acoustic element that realizes a complex-valued potential and simultaneously controls the multiple interference in the structure. The manipulation of exceptional points offers new routes to broaden applications for PT symmetric physics in acoustics, optics, microwaves and electronics, which are essential for sensing, communication and imaging. PMID:27025443

  10. Harmonic gyrotrons operating in high-order symmetric modes

    SciTech Connect

    Nusinovich, Gregory S.; Kashyn, Dmytro G.; Antonsen, T. M.

    2015-01-05

    It is shown that gyrotrons operating at cyclotron harmonics can be designed for operation in symmetric TE{sub 0,p}-modes. Such operation in fundamental harmonic gyrotrons is possible only at small radial indices (p≤3) because of the severe mode competition with TE{sub 2,p}-modes, which are equally coupled to annular beams as the symmetric modes. At cyclotron harmonics, however, this “degeneracy” of coupling is absent, and there is a region in the parameter space where harmonic gyrotrons can steadily operate in symmetric modes. This fact is especially important for sub-THz and THz-range gyrotrons where ohmic losses limit the power achievable in continuous-wave and high duty cycle regimes.

  11. Taming the Exceptional Points of Parity-Time Symmetric Acoustics

    NASA Astrophysics Data System (ADS)

    Dubois, Marc; Shi, Chengzhi; Chen, Yun; Cheng, Lei; Ramezani, Hamidreza; Wang, Yuan; Zhang, Xiang

    Parity-time (PT) symmetric concept and development lead to a wide range of applications including coherent perfect absorbers, single mode lasers, unidirectional cloaking and sensing, and optical isolators. These new applications and devices emerge from the existence of a phase transition in PT symmetric complex-valued potential obtained by balancing gain and loss materials. However, the systematic extension of such devices is adjourned by the key challenge in the management of the complex scattering process within the structure in order to engineer PT phase and exceptional points. Here, based on active acoustic elements, we experimentally demonstrate the simultaneous control of complex-valued potentials and multiple interference inside the structure at any given frequency. This method broadens the scope of applications for PT symmetric devices in many fields including optics, microwaves, electronics, which are crucial for sensing, imaging, cloaking, lasing, absorbing, etc.

  12. Phase-coupled optical diode based on PT symmetric system

    NASA Astrophysics Data System (ADS)

    Gao, Yong-Pan; Cao, Cong; Zhang, Yong; Wang, Tie-Jun; Wang, Chuan

    2017-01-01

    Here we investigate a phase-coupled parity-time symmetric plasmonic system, and theoretically achieved the all optical on-chip plasmonic diode using the coupled mode theory. The proposed symmetrical system consists of one loss cavity and one gain cavity each coupled with the waveguide, and we find that the controllable amplification of the input field can be achieved by changing the power coupling fraction between the resonators and the waveguide. Moreover, this loss-gain symmetric system could work as a frequency comb filter, and the operation on the device could be controlled by tuning the coupling strength between the two plasmonic cavities by tuning the coupling distance between the cavities and the waveguide.

  13. A new integrated symmetrical table for genetic codes.

    PubMed

    Shu, Jian-Jun

    2017-01-01

    Degeneracy is a salient feature of genetic codes, because there are more codons than amino acids. The conventional table for genetic codes suffers from an inability of illustrating a symmetrical nature among genetic base codes. In fact, because the conventional wisdom avoids the question, there is little agreement as to whether the symmetrical nature actually even exists. A better understanding of symmetry and an appreciation for its essential role in the genetic code formation can improve our understanding of nature's coding processes. Thus, it is worth formulating a new integrated symmetrical table for genetic codes, which is presented in this paper. It could be very useful to understand the Nobel laureate Crick's wobble hypothesis - how one transfer ribonucleic acid can recognize two or more synonymous codons, which is an unsolved fundamental question in biological science.

  14. Solution of generalized shifted linear systems with complex symmetric matrices

    NASA Astrophysics Data System (ADS)

    Sogabe, Tomohiro; Hoshi, Takeo; Zhang, Shao-Liang; Fujiwara, Takeo

    2012-07-01

    We develop the shifted COCG method [R. Takayama, T. Hoshi, T. Sogabe, S.-L. Zhang, T. Fujiwara, Linear algebraic calculation of Green's function for large-scale electronic structure theory, Phys. Rev. B 73 (165108) (2006) 1-9] and the shifted WQMR method [T. Sogabe, T. Hoshi, S.-L. Zhang, T. Fujiwara, On a weighted quasi-residual minimization strategy of the QMR method for solving complex symmetric shifted linear systems, Electron. Trans. Numer. Anal. 31 (2008) 126-140] for solving generalized shifted linear systems with complex symmetric matrices that arise from the electronic structure theory. The complex symmetric Lanczos process with a suitable bilinear form plays an important role in the development of the methods. The numerical examples indicate that the methods are highly attractive when the inner linear systems can efficiently be solved.

  15. Lift generation by a two-dimensional symmetric flapping wing

    NASA Astrophysics Data System (ADS)

    Inamuro, Takaji; Ota, Keigo; Suzuki, Kosuke

    2010-11-01

    Two-dimensional symmetric flapping flight is investigated by an immersed boundary-lattice Boltzmann method. In the method we can treat the moving boundary problem efficiently on the Cartesian grid. First, we investigate the effect of the Reynolds number on flows around symmetric flapping wings under no-gravity field and find that at high Reynolds numbers asymmetric vortices are appeared and the time-averaged lift force is induced on the wings, while at low Reynolds numbers only symmetric vortices are appeared around the wings and no lift force is induced. Also, the effect of the initial position of the wings on the lift force is investigated. Secondly, we carry out free flight simulations under gravity field for various Reynolds and Froude numbers and find the region where upward flights are possible.

  16. Plane symmetric thin-shell wormholes: Solutions and stability

    SciTech Connect

    Lemos, Jose P. S.; Lobo, Francisco S. N.

    2008-08-15

    Using the cut-and-paste procedure, we construct static and dynamic, plane symmetric wormholes by surgically grafting together two spacetimes of plane symmetric vacuum solutions with a negative cosmological constant. These plane symmetric wormholes can be interpreted as domain walls connecting different universes, having planar topology, and upon compactification of one or two coordinates, cylindrical topology or toroidal topology, respectively. A stability analysis is carried out for the dynamic case by taking into account specific equations of state, and a linearized stability analysis around static solutions is also explored. It is found that thin-shell wormholes made of a dark energy fluid or of a cosmological constant fluid are stable, while thin-shell wormholes made of phantom energy are unstable.

  17. Symmetric quadratic Hamiltonians with pseudo-Hermitian matrix representation

    SciTech Connect

    Fernández, Francisco M.

    2016-06-15

    We prove that any symmetric Hamiltonian that is a quadratic function of the coordinates and momenta has a pseudo-Hermitian adjoint or regular matrix representation. The eigenvalues of the latter matrix are the natural frequencies of the Hamiltonian operator. When all the eigenvalues of the matrix are real, then the spectrum of the symmetric Hamiltonian is real and the operator is Hermitian. As illustrative examples we choose the quadratic Hamiltonians that model a pair of coupled resonators with balanced gain and loss, the electromagnetic self-force on an oscillating charged particle and an active LRC circuit. -- Highlights: •Symmetric quadratic operators are useful models for many physical applications. •Any such operator exhibits a pseudo-Hermitian matrix representation. •Its eigenvalues are the natural frequencies of the Hamiltonian operator. •The eigenvalues may be real or complex and describe a phase transition.

  18. Reciprocal and unidirectional scattering of parity-time symmetric structures

    PubMed Central

    Jin, L.; Zhang, X. Z.; Zhang, G.; Song, Z.

    2016-01-01

    Parity-time symmetry is of great interest. The reciprocal and unidirectional features are intriguing besides the symmetry phase transition. Recently, the reciprocal transmission, unidirectional reflectionless and invisibility are intensively studied. Here, we show the reciprocal reflection/transmission in -symmetric system is closely related to the type of symmetry, that is, the axial (reflection) symmetry leads to reciprocal reflection (transmission). The results are further elucidated by studying the scattering of rhombic ring form coupled resonators with enclosed synthetic magnetic flux. The nonreciprocal phase shift induced by the magnetic flux and gain/loss break the parity and time-reversal symmetry but keep the parity-time symmetry. The reciprocal reflection (transmission) and unidirectional transmission (reflection) are found in the axial (reflection) -symmetric ring centre. The explorations of symmetry and asymmetry from symmetry may shed light on novel one-way optical devices and application of -symmetric metamaterials. PMID:26876806

  19. On Einstein warped products with a quarter-symmetric connection

    NASA Astrophysics Data System (ADS)

    Pahan, Sampa; Pal, Buddhadev; Bhattacharyya, Arindam

    This paper characterizes the warping functions for a multiply generalized Robertson-Walker space-time to get an Einstein space M with a quarter-symmetric connection for different dimensions of M (i.e. (1). dim M = 2, (2). dim M ≥ 3) when all the fibers are Ricci flat. Then we have also computed the warping functions for a Ricci flat Einstein multiply warped product spaces M with a quarter-symmetric connection for different dimensions of M (i.e. (1). dim M = 2, (2). dim M = 3, (3). dim M ≥ 4) and all the fibers are Ricci flat. In the last section, we have given two examples of multiply generalized Robertson-Walker space-time with respect to quarter-symmetric connection.

  20. SYMTRAN - A Time-dependent Symmetric Tandem Mirror Transport Code

    SciTech Connect

    Hua, D; Fowler, T

    2004-06-15

    A time-dependent version of the steady-state radial transport model in symmetric tandem mirrors in Ref. [1] has been coded up and first tests performed. Our code, named SYMTRAN, is an adaptation of the earlier SPHERE code for spheromaks, now modified for tandem mirror physics. Motivated by Post's new concept of kinetic stabilization of symmetric mirrors, it is an extension of the earlier TAMRAC rate-equation code omitting radial transport [2], which successfully accounted for experimental results in TMX. The SYMTRAN code differs from the earlier tandem mirror radial transport code TMT in that our code is focused on axisymmetric tandem mirrors and classical diffusion, whereas TMT emphasized non-ambipolar transport in TMX and MFTF-B due to yin-yang plugs and non-symmetric transitions between the plugs and axisymmetric center cell. Both codes exhibit interesting but different non-linear behavior.

  1. Chiral optical response of planar and symmetric nanotrimers enabled by heteromaterial selection

    NASA Astrophysics Data System (ADS)

    Banzer, Peter; Woźniak, Paweł; Mick, Uwe; de Leon, Israel; Boyd, Robert W.

    2016-10-01

    Chirality is an intriguing property of certain molecules, materials or artificial nanostructures, which allows them to interact with the spin angular momentum of the impinging light field. Due to their chiral geometry, they can distinguish between left- and right-hand circular polarization states or convert them into each other. Here we introduce an approach towards optical chirality, which is observed in individual two-dimensional and geometrically mirror-symmetric nanostructures. In this scheme, the chiral optical response is induced by the chosen heterogeneous material composition of a particle assembly and the corresponding resonance behaviour of the constituents it is built from, which breaks the symmetry of the system. As a proof of principle, we investigate such a structure composed of individual silicon and gold nanoparticles both experimentally, as well as numerically. Our proposed concept constitutes an approach for designing two-dimensional chiral media tailored at the nanoscale, allowing for high tunability of their optical response.

  2. Chiral optical response of planar and symmetric nanotrimers enabled by heteromaterial selection

    PubMed Central

    Banzer, Peter; Woźniak, Paweł; Mick, Uwe; De Leon, Israel; Boyd, Robert W.

    2016-01-01

    Chirality is an intriguing property of certain molecules, materials or artificial nanostructures, which allows them to interact with the spin angular momentum of the impinging light field. Due to their chiral geometry, they can distinguish between left- and right-hand circular polarization states or convert them into each other. Here we introduce an approach towards optical chirality, which is observed in individual two-dimensional and geometrically mirror-symmetric nanostructures. In this scheme, the chiral optical response is induced by the chosen heterogeneous material composition of a particle assembly and the corresponding resonance behaviour of the constituents it is built from, which breaks the symmetry of the system. As a proof of principle, we investigate such a structure composed of individual silicon and gold nanoparticles both experimentally, as well as numerically. Our proposed concept constitutes an approach for designing two-dimensional chiral media tailored at the nanoscale, allowing for high tunability of their optical response. PMID:27734960

  3. On the stability of the cyclic O8 molecule

    NASA Astrophysics Data System (ADS)

    Ochoa-Calle, A. J.; Ramírez-Solís, A.

    2014-01-01

    We present a refined study of some isomers of the covalently bound O8 molecule at the MP2 and CCSD levels with sequences of correlation-consistent basis sets. The previously known symmetric D4d crown structure is 28 kcal/mol more stable than the structure by Forte et al. (Phys. Lett. A 377 (2013) 801), which is a second order transition state leading to 4O2 (3∑g-) and to another lower-lying unstable cyclic structure. The O8 symmetric crown lies 104 kcal/mol above the 4O2 (3∑g-) fragments and has 1.40 Å O-O bonds, which are shorter than those of the O4 and O6 cyclic species at the MP2/CBS level.

  4. Conformally symmetric traversable wormholes in f( G) gravity

    NASA Astrophysics Data System (ADS)

    Sharif, M.; Fatima, H. Ismat

    2016-11-01

    We discuss non-static conformally symmetric traversable wormholes for spherically symmetric spacetime using the model f(G)=α Gn, where n>0 and α is an arbitrary constant. We investigate wormhole solutions by taking two types of shape function and found that physically realistic wormholes exist only for even values of n. We also check the validity of flare-out condition, required for wormhole construction, for the shape functions deduced from two types of equation of state. It is found that this condition is satisfied by these functions in all cases except phantom case with non-static conformal symmetry.

  5. Characterization of Generalized Young Measures Generated by Symmetric Gradients

    NASA Astrophysics Data System (ADS)

    De Philippis, Guido; Rindler, Filip

    2017-02-01

    This work establishes a characterization theorem for (generalized) Young measures generated by symmetric derivatives of functions of bounded deformation (BD) in the spirit of the classical Kinderlehrer-Pedregal theorem. Our result places such Young measures in duality with symmetric-quasiconvex functions with linear growth. The "local" proof strategy combines blow-up arguments with the singular structure theorem in BD (the analogue of Alberti's rank-one theorem in BV), which was recently proved by the authors. As an application of our characterization theorem we show how an atomic part in a BD-Young measure can be split off in generating sequences.

  6. Geometry and Symmetric Coherent States of Three Qubits Systems

    NASA Astrophysics Data System (ADS)

    Guo, Xiao-Kan

    2016-06-01

    In this paper, we first generalize the previous results that relate 1- and 2-qubit geometries to complex and quaternionic Möbius transformations respectively, to the case of 3-qubit states under octonionic Möbius transformations. This completes the correspondence between the qubit geometries and the four normed division algebras. Thereby, new systems of symmetric coherent states with 2 and 3 qubits can be constructed by mapping the spin coherent states to their antipodal symmetric ponits on the generalized Bloch spheres via Möbius transformations in corresponding dimensions. Finally, potential applications of the normed division algebras in physics are discussed.

  7. Rotating Symmetrical Piezoelectric Microactuators for Magnetic Head Drives

    NASA Astrophysics Data System (ADS)

    Kurihara, Kazuaki; Hida, Masaharu; Umemiya, Shigeyoshi; Kondo, Masao; Koganezawa, Shinji

    2006-09-01

    A unique piezoelectric microactuator for the head-slider drive dual-stage actuator systems in magnetic disk drives has been developed. This microactuator is based on a rotating symmetrical structure and a symmetrical operation. The piezoelectric actuator elements used in the system have a simple rectangular multilayered structure. A prototype model with pico slider and head suspension has been tested to demonstrate 0.86 μm displacement at a dc applied voltage of 30 V and observed main resonant frequency of over 20 kHz. No fluctuation in flying height was observed.

  8. Numerical analysis of the symmetric hybrid transducer ultrasonic motor.

    PubMed

    Satonobu, J; Friend, J R; Nakamura, K; Ueha, S

    2001-11-01

    In this paper, operation of a symmetric hybrid transducer ultrasonic motor with output produced by two rotors connected together via a driveshaft is numerically analyzed and compared with the traditional asymmetric hybrid transducer motor design that produces its output from only one rotor. A one-dimensional finite element model for torsional vibration in the stator and a Coulomb friction model for rotor/stator contact associated with the longitudinal vibration of the motor are introduced. The calculation results demonstrate that the symmetric design is capable of performance comparable with the traditional asymmetric design when an optimum static spring force in the rotor/stator contact interface is applied during operation.

  9. Bunch-Kaufman factorization for real symmetric indefinite banded matrices

    NASA Technical Reports Server (NTRS)

    Jones, Mark T.; Patrick, Merrell L.

    1989-01-01

    The Bunch-Kaufman algorithm for factoring symmetric indefinite matrices was rejected for banded matrices because it destroys the banded structure of the matrix. Herein, it is shown that for a subclass of real symmetric matrices which arise in solving the generalized eigenvalue problem using Lanczos's method, the Bunch-Kaufman algorithm does not result in major destruction of the bandwidth. Space time complexities of the algorithm are given and used to show that the Bunch-Kaufman algorithm is a significant improvement over LU factorization.

  10. A parallel Lanczos method for symmetric generalized eigenvalue problems

    SciTech Connect

    Wu, K.; Simon, H.D.

    1997-12-01

    Lanczos algorithm is a very effective method for finding extreme eigenvalues of symmetric matrices. It requires less arithmetic operations than similar algorithms, such as, the Arnoldi method. In this paper, the authors present their parallel version of the Lanczos method for symmetric generalized eigenvalue problem, PLANSO. PLANSO is based on a sequential package called LANSO which implements the Lanczos algorithm with partial re-orthogonalization. It is portable to all parallel machines that support MPI and easy to interface with most parallel computing packages. Through numerical experiments, they demonstrate that it achieves similar parallel efficiency as PARPACK, but uses considerably less time.

  11. Spherically symmetric black-hole entropy without brick walls

    NASA Astrophysics Data System (ADS)

    Ren, Zhao; Yue-Qin, Wu; Li-Chun, Zhang

    2003-11-01

    Properties of the thermal radiation of black holes are discussed using a new equation of state density motivated by the generalized uncertainty relation in quantum gravity. There is no burst at the last stage of emission from a spherically symmetric black hole. When the new equation of state density is used to investigate the entropy of a bosonic field and fermionic field outside the horizon of a static spherically symmetric black hole, the divergence that appears in the brick-wall model is removed without any cutoff. The entropy proportional to the horizon area is derived from the contribution from the vicinity of the horizon.

  12. Bound states of PT-symmetric separable potentials

    SciTech Connect

    Bender, Carl M.; Jones, Hugh F.

    2011-09-15

    All of the PT-symmetric potentials that have been studied so far have been local. In this paper, nonlocal PT-symmetric separable potentials of the form V(x,y)=i{epsilon}[U(x)U(y)-U(-x)U(-y)], where U(x) is real, are examined. Two specific models are examined. In each case, it is shown that there is a parametric region of the coupling strength {epsilon} for which the PT symmetry of the Hamiltonian is unbroken and the bound-state energies are real. The critical values of {epsilon} that bound this region are calculated.

  13. Possible origin of transition from symmetric to asymmetric fission

    NASA Astrophysics Data System (ADS)

    Paşca, H.; Andreev, A. V.; Adamian, G. G.; Antonenko, N. V.

    2016-09-01

    The charged distributions of fragments produced in the electromagnetic-induced fission of the even-even isotopes of Rn, Ra, Th, and U are described within an improved scission-point model and compared with the available experimental data. The three-equal-peaked charge distributions are predicted for several fissioning nuclei with neutron number N = 136. The possible explanation of the transition from a symmetric fission mode to an asymmetric one around N ∼ 136 is presented. The excitation energy dependencies of the asymmetric and symmetric fission modes are anticipated.

  14. Cosmological and spherically symmetric solutions with intersecting p-branes

    NASA Astrophysics Data System (ADS)

    Ivashchuk, V. D.; Melnikov, V. N.

    1999-12-01

    Multidimensional model describing the cosmological evolution and/or spherically symmetric configuration with n+1 Einstein spaces in the theory with several scalar fields and forms is considered. When electro-magnetic composite p-brane ansatz is adopted, n ``internal'' spaces are Ricci-flat, one space M0 has a nonzero curvature, and all p-branes do not ``live'' in M0, a class of exact solutions is obtained if certain block-orthogonality relations on p-brane vectors are imposed. A subclass of spherically symmetric solutions (containing nonextremal p-brane black holes) is considered. Post-Newtonian parameters are calculated.

  15. Bimodal symmetric fission observed in the heaviest elements

    SciTech Connect

    Hulet, E.K.; Wild, J.F.; Dougan, R.J.; Lougheed, R.W.; Landrum, J.H.; Dougan, A.D.; Schadel, M.; Hahn, R.L.; Baisden, P.A.; Henderson, C.M.

    1986-01-27

    We measured the mass and kinetic-energy partitioning in the spontaneous fission of /sup 258/Fm, /sup 259/Md, /sup 260/Md, /sup 258/No, and /sup 260/(104). All fissioned with mass distributions that were symmetric. Total-kinetic-energy distributions peaked near either 200 or 235 MeV. Surprisingly, these energy distributions were skewed upward or downward from the peak in each case, except for /sup 260/(104), indicating a composite of two energy distributions. We interpret this as a mixture of liquid-drop-like and fragment-shell directed symmetric fission, although theory had not anticipated this phenomenon.

  16. Detection of Multiparticle Entanglement: Quantifying the Search for Symmetric Extensions

    NASA Astrophysics Data System (ADS)

    Brandão, Fernando G. S. L.; Christandl, Matthias

    2012-10-01

    We provide quantitative bounds on the characterization of multiparticle separable states by states that have locally symmetric extensions. The bounds are derived from two-particle bounds and relate to recent studies on quantum versions of de Finetti’s theorem. We discuss algorithmic applications of our results, in particular a quasipolynomial-time algorithm to decide whether a multiparticle quantum state is separable or entangled (for constant number of particles and constant error in the norm induced by one-way local operations and classical communication, or in the Frobenius norm). Our results provide a theoretical justification for the use of the search for symmetric extensions as a test for multiparticle entanglement.

  17. Measuring top-quark polarization in top-pair + missing-energy events.

    PubMed

    Berger, Edmond L; Cao, Qing-Hong; Yu, Jiang-Hao; Zhang, Hao

    2012-10-12

    The polarization of a top quark can be sensitive to new physics beyond the standard model. Since the charged lepton from top-quark decay is maximally correlated with the top-quark spin, it is common to measure the polarization from the distribution in the angle between the charged lepton and the top-quark directions. We propose a novel method based on the charged lepton energy fraction and illustrate the method with a detailed simulation of top-quark pairs produced in supersymmetric top squark pair production. We show that the lepton energy ratio distribution that we define is very sensitive to the top-quark polarization but insensitive to the precise measurement of the top-quark energy.

  18. Review of Top Quark Physics Results

    SciTech Connect

    Kehoe, R.; Narain, M.; Kumar, A.

    2007-12-01

    As the heaviest known fundamental particle, the top quark has taken a central role in the study of fundamental interactions. Production of top quarks in pairs provides an important probe of strong interactions. The top quark mass is a key fundamental parameter which places a valuable constraint on the Higgs boson mass and electroweak symmetry breaking. Observations of the relative rates and kinematics of top quark final states constrain potential new physics. In many cases, the tests available with study of the top quark are both critical and unique. Large increases in data samples from the Fermilab Tevatron have been coupled with major improvements in experimental techniques to produce many new precision measurements of the top quark. The first direct evidence for electroweak production of top quarks has been obtained, with a resulting direct determination of V{sub tb}. Several of the properties of the top quark have been measured. Progress has also been made in obtaining improved limits on potential anomalous production and decay mechanisms. This review presents an overview of recent theoretical and experimental developments in this field. We also provide a brief discussion of the implications for further efforts.

  19. The Sakai Spinner: A Paperclip Top

    ERIC Educational Resources Information Center

    Corrao, Christian T.

    2014-01-01

    A challenge: Can you create a stable top from a single paper clip? Several interesting solutions to this problem were provided by Takao Sakai from Japan, the requirement of each being that the center of gravity be located on the vertical y-axis at the center of the top. In the simplest configuration, we see that there exists a single angle ?…

  20. Top-Ten IT Issues, 2008

    ERIC Educational Resources Information Center

    Allison, Debra H.; DeBlois, Peter B.

    2008-01-01

    EDUCAUSE presents the top-ten IT-related issues in terms of strategic importance to the higher education institution, as revealed by the ninth annual EDUCAUSE Current Issues Survey. This year, "Security" moves back to the top of the list. (Contains 20 notes.)

  1. 49 CFR 236.779 - Plate, top.

    Code of Federal Regulations, 2010 CFR

    2010-10-01

    ... 49 Transportation 4 2010-10-01 2010-10-01 false Plate, top. 236.779 Section 236.779 Transportation Other Regulations Relating to Transportation (Continued) FEDERAL RAILROAD ADMINISTRATION, DEPARTMENT OF... OF SIGNAL AND TRAIN CONTROL SYSTEMS, DEVICES, AND APPLIANCES Definitions § 236.779 Plate, top....

  2. 49 CFR 236.779 - Plate, top.

    Code of Federal Regulations, 2011 CFR

    2011-10-01

    ... 49 Transportation 4 2011-10-01 2011-10-01 false Plate, top. 236.779 Section 236.779 Transportation Other Regulations Relating to Transportation (Continued) FEDERAL RAILROAD ADMINISTRATION, DEPARTMENT OF... OF SIGNAL AND TRAIN CONTROL SYSTEMS, DEVICES, AND APPLIANCES Definitions § 236.779 Plate, top....

  3. Race to Top Draws out New Suitors

    ERIC Educational Resources Information Center

    McNeil, Michele

    2012-01-01

    The list of 61 finalists for the latest Race to the Top competition shows that the U.S. Department of Education was successful in enticing high-scoring applications from districts in rural America and in states that had not shared in the Race to the Top bounty before. But whether the ultimate winners, which will be announced this month, will be…

  4. Top 12 Web Resources for 2012

    ERIC Educational Resources Information Center

    Gonzales, Lisa; Vodicka, Devin

    2012-01-01

    In this article, the authors describe some of the top websites recommended by colleagues for the Association of California School Administrators. The Top 12 for 2012 are: (1) Facebook (facebook.com); (2) Twitter (twitter.com); (3) Tungle (tungle.me); (4) FCMAT (fcmat.org); (5) YouSendIt (yousendit.com); (6) Slideshare (slideshare.net); (7) QR…

  5. Controlling Severe Curly Top in Sugarbeets

    Technology Transfer Automated Retrieval System (TEKTRAN)

    Controlling curly top in sugarbeet has been industry priority in the western United States since the 1920s. Curly top is a virus disease that is vectored by the beet leafhopper. If the beet leafhopper moves into commercial fields early in the season, virus is more likely to be transmitted to sugar...

  6. Pinch Experiments in a Table Top Generator

    SciTech Connect

    Pavez, Cristian; Moreno, Jose; Soto, Leopoldo; Tarifeno, Ariel

    2009-01-21

    The design and construction of a table top multipurpose capacitor bank of hundred of Joules and hundred of kiloAmperes conceived to be used in small scale Z-pinch experiments is reported. A recent result on a Z-pinch gas embedded discharge using hollow conical electrodes done in a similar table top generator is also presented.

  7. Search for top quark at Fermilab Collider

    SciTech Connect

    Sliwa, K.; The CDF Collaboration

    1991-10-01

    The status of a search for the top quark with Collider Detector at Fermilab (CDF), based on a data sample recorded during the 1988--1989 run is presented. The plans for the next Fermilab Collider run in 1992--1993 and the prospects of discovering the top quark are discussed. 19 refs., 4 figs., 2 tabs.

  8. World average top-quark mass

    SciTech Connect

    Glenzinski, D.; /Fermilab

    2008-01-01

    This paper summarizes a talk given at the Top2008 Workshop at La Biodola, Isola d Elba, Italy. The status of the world average top-quark mass is discussed. Some comments about the challanges facing the experiments in order to further improve the precision are offered.

  9. Physics of the top quark at CDF

    SciTech Connect

    Vejcik, S.; CDF Collaboration

    1997-07-01

    Measurements of Top quark properties with the CDF detector are reported. The production cross section and mass provide a consistent picture of the Top quark as described by the Standard Model. Initial studies of other properties such as estimates of branching ratios are also reported.

  10. Tools for top physics at D0

    SciTech Connect

    Harel, Amnon

    2008-07-01

    Top quark measurements rely on the jet energy calibration and often on b-quark identification. We discuss these and other tools and how they apply to top quark analyses at D0. In particular some of the nuances that result from D0's data driven approach to these issues are presented.

  11. Top Quark Pair Production at the Tevatron

    SciTech Connect

    Nielsen, Jason

    2005-05-17

    The measurement of the top quark pair production crosssection inproton-antiproton collisions at 1.96 TeV is a test ofquantumchromodynamics and could potentially be sensitive to newphysics beyondthe standard model. I report on the latest t-tbarcross section resultsfrom the CDF and DZero experiments in various finalstate topologies whicharise from decays of top quark pairs.

  12. TOP500 Supercomputers for June 2002

    SciTech Connect

    Strohmaier, Erich; Meuer, Hans W.; Dongarra, Jack; Simon, Horst D.

    2002-06-20

    19th Edition of TOP500 List of World's Fastest Supercomputers Released MANNHEIM, Germany; KNOXVILLE, Tenn.;&BERKELEY, Calif. In what has become a much-anticipated event in the world of high-performance computing, the 19th edition of the TOP500 list of the worlds fastest supercomputers was released today (June 20, 2002). The recently installed Earth Simulator supercomputer at the Earth Simulator Center in Yokohama, Japan, is as expected the clear new number 1. Its performance of 35.86 Tflop/s (trillions of calculations per second) running the Linpack benchmark is almost five times higher than the performance of the now No.2 IBM ASCI White system at Lawrence Livermore National Laboratory (7.2 Tflop/s). This powerful leap frogging to the top by a system so much faster than the previous top system is unparalleled in the history of the TOP500.

  13. Thermionic topping of electric power plants

    NASA Technical Reports Server (NTRS)

    Britt, E. J.; Fitzpatrick, G. O.; Rasor, N. S.

    1975-01-01

    The most likely use of thermionic conversion is in the form of a topping cycle combined with a steam-turbogenerator plant. A specific reference system is chosen in which the thermionic topping cycle occurs in thermionic heat exchangers referred to as large, modular thermionic units to which heat is transferred from a separate heat source and which reject their heat to a conventional steam turboelectric system. Results of analysis show that the performance and cost criteria for practical thermionic topping of large electric power plants are well within the reach of demonstrated and foreseeable converter capabilities. Thermionic topping has many significant advantages over unconventional cycles proposed for topping applications, including level of demonstrated and projected performance and lifetime, development time, and design simplicity.

  14. Protein Identification Using Top-Down

    SciTech Connect

    Liu, Xiaowen; Sirotkin, Yakov; Shen, Yufeng; Anderson, Gordon A.; Tsai, Yi-Hsuan S.; Ting, Ying S.; Goodlett, David R.; Smith, Richard D.; Bafna, Vineet; Pevzner, Pavel A.

    2012-06-01

    In the last two years, due to advances in protein separation and mass spectrometry, top-down mass spectrometry moved from analyzing single proteins to analyzing complex samples and identifying hundreds and even thousands of proteins. However, computational tools for database search of top-down spectra against protein databases are still in infancy. We describe MS-Align+, a fast algorithm for top-down protein identification based on spectral alignment that enables searches for unexpected post-translational modifications (PTMs). We also propose a method for evaluating statistical significance of top-down protein identifications and further benchmark MS-Align+ along with PIITA, ProSightPTM and SEQUEST, which were previously used for top-down MS/MS database searches. We demonstrate that MS-Align+ and PIITA significantly increase the number of identified proteins as compared to ProSightPTM and SEQUEST.

  15. Positronium ions and molecules

    NASA Technical Reports Server (NTRS)

    Ho, Y. K.

    1990-01-01

    Recent theoretical studies on positronium ions and molecules are discussed. A positronium ion is a three particle system consisting of two electrons in singlet spin state, and a positron. Recent studies include calculations of its binding energy, positron annihilation rate, and investigations of its doubly excited resonant states. A positronium molecule is a four body system consisting of two positrons and two electrons in an overall singlet spin state. The recent calculations of its binding energy against the dissociation into two positronium atoms, and studies of auto-detaching states in positronium molecules are discussed. These auto-dissociating states, which are believed to be part of the Rydberg series as a result of a positron attaching to a negatively charged positronium ion, Ps-, would appear as resonances in Ps-Ps scattering.

  16. Single-Molecule Bioelectronics

    PubMed Central

    Rosenstein, Jacob K.; Lemay, Serge G.; Shepard, Kenneth L.

    2014-01-01

    Experimental techniques which interface single biomolecules directly with microelectronic systems are increasingly being used in a wide range of powerful applications, from fundamental studies of biomolecules to ultra-sensitive assays. Here we review several technologies which can perform electronic measurements of single molecules in solution: ion channels, nanopore sensors, carbon nanotube field-effect transistors, electron tunneling gaps, and redox cycling. We discuss the shared features among these techniques that enable them to resolve individual molecules, and discuss their limitations. Recordings from each of these methods all rely on similar electronic instrumentation, and we discuss the relevant circuit implementations and potential for scaling these single-molecule bioelectronic interfaces to high-throughput arrayed sensing platforms. PMID:25529538

  17. MOLECULES IN {eta} CARINAE

    SciTech Connect

    Loinard, Laurent; Menten, Karl M.; Guesten, Rolf; Zapata, Luis A.; Rodriguez, Luis F.

    2012-04-10

    We report the detection toward {eta} Carinae of six new molecules, CO, CN, HCO{sup +}, HCN, HNC, and N{sub 2}H{sup +}, and of two of their less abundant isotopic counterparts, {sup 13}CO and H{sup 13}CN. The line profiles are moderately broad ({approx}100 km s{sup -1}), indicating that the emission originates in the dense, possibly clumpy, central arcsecond of the Homunculus Nebula. Contrary to previous claims, CO and HCO{sup +} do not appear to be underabundant in {eta} Carinae. On the other hand, molecules containing nitrogen or the {sup 13}C isotope of carbon are overabundant by about one order of magnitude. This demonstrates that, together with the dust responsible for the dimming of {eta} Carinae following the Great Eruption, the molecules detected here must have formed in situ out of CNO-processed stellar material.

  18. Polarization of deuterium molecules

    SciTech Connect

    J. F. J. van den Brand; H. J. Bulten; M. Ferro-Luzzi; Z.-L. Zhou; Ricardo Alarcon; T. Botto; M. Bouwhuis; Rolf Ent; Peter Heimberg; Douglas W. Higinbotham; Kees de Jager; J. Lang; D. J. de Lange; I. Passchier; H. R. Poolman; J. J. M. Steijger; O. Unal; H. de Vries

    1997-08-01

    For molecular systems, spin relaxation is expected to be suppressed compared to the case of atoms, since the paired electrons in a hydrogen or deuterium molecule are chemically stable, and only weakly interact with the spin of the nucleus. Such systems would be largely insensitive to polarization losses due to spin-exchange collisions, to the interaction of the electron spins with external fields (e.g. the RF-field of a bunched charged-particle beam), and/or to the presence of container walls. Here, we discuss the results of a recent experiment where we obtained evidence that nuclear polarization is maintained, when polarized atoms recombine to molecules on a copper surface (in a magnetic field of 23 mT and at a density of about 10{sup 12} molecules {center_dot} cm{sup -3}).

  19. Measurements and searches with top quarks

    SciTech Connect

    Peters, Reinhild Yvonne

    2008-08-01

    In 1995 the last missing member of the known families of quarks, the top quark, was discovered by the CDF and D0 experiments at the Tevatron, a proton-antiproton collider at Fermilab near Chicago. Until today, the Tevatron is the only place where top quarks can be produced. The determination of top quark production and properties is crucial to understand the Standard Model of particle physics and beyond. The most striking property of the top quark is its mass--of the order of the mass of a gold atom and close to the electroweak scale--making the top quark not only interesting in itself but also as a window to new physics. Due to the high mass, much higher than of any other known fermion, it is expected that the top quark plays an important role in electroweak symmetry breaking, which is the most prominent candidate to explain the mass of particles. In the Standard Model, electroweak symmetry breaking is induced by one Higgs field, producing one additional physical particle, the Higgs boson. Although various searches have been performed, for example at the Large Electron Positron Collider (LEP), no evidence for the Higgs boson could yet be found in any experiment. At the Tevatron, multiple searches for the last missing particle of the Standard Model are ongoing with ever higher statistics and improved analysis techniques. The exclusion or verification of the Higgs boson can only be achieved by combining many techniques and many final states and production mechanisms. As part of this thesis, the search for Higgs bosons produced in association with a top quark pair (t$\\bar{t}$H) has been performed. This channel is especially interesting for the understanding of the coupling between Higgs and the top quark. Even though the Standard Model Higgs boson is an attractive candidate, there is no reason to believe that the electroweak symmetry breaking is induced by only one Higgs field. In many models more than one Higgs boson are expected to exist, opening even more

  20. Electromagnetic fields in axial symmetric waveguides with variable cross section

    SciTech Connect

    Kheifets, S.

    1980-02-15

    A new class of separable variables is found which allows one to find an approximate analytical solution of the Maxwell equations for axial symmetric waveguides with slow (but not necessarily small) varying boundary surfaces. An example of the solution is given. Possible applications and limitations of this approach are discussed. 6 refs., 10 figs.

  1. 32. Symmetrical view of castiron columns and arches, looking W, ...

    Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

    32. Symmetrical view of cast-iron columns and arches, looking W, in interior of N room of mill. - Hacienda Azurarera Santa Elena, Sugar Mill Ruins, 1.44 miles North of PR Route 2 Bridge Over Rio De La Plata, Toa Baja, Toa Baja Municipio, PR

  2. Constructing I[subscript h] Symmetrical Fullerenes from Pentagons

    ERIC Educational Resources Information Center

    Gan, Li-Hua

    2008-01-01

    Twelve pentagons are sufficient and necessary to form a fullerene cage. According to this structural feature of fullerenes, we propose a simple and efficient method for the construction of I[subscript h] symmetrical fullerenes from pentagons. This method does not require complicated mathematical knowledge; yet it provides an excellent paradigm for…

  3. New algorithms for the symmetric tridiagonal eigenvalue computation

    SciTech Connect

    Pan, V. |

    1994-12-31

    The author presents new algorithms that accelerate the bisection method for the symmetric eigenvalue problem. The algorithms rely on some new techniques, which include acceleration of Newton`s iteration and can also be further applied to acceleration of some other iterative processes, in particular, of iterative algorithms for approximating polynomial zeros.

  4. General description of circularly symmetric Bessel beams of arbitrary order

    NASA Astrophysics Data System (ADS)

    Wang, Jia Jie; Wriedt, Thomas; Lock, James A.; Mädler, Lutz

    2016-11-01

    A general description of circularly symmetric Bessel beams of arbitrary order is derived in this paper. This is achieved by analyzing the relationship between different descriptions of polarized Bessel beams obtained using different approaches. It is shown that a class of circularly symmetric Davis Bessel beams derived using the Hertz vector potentials possesses the same general functional dependence as the aplanatic Bessel beams generated using the angular spectrum representation (ASR). This result bridges the gap between different descriptions of Bessel beams and leads to a general description of circularly symmetric Bessel beams, such that the Davis Bessel beams and the aplanatic Bessel beams are merely the two simplest cases of an infinite number of possible circularly symmetric Bessel beams. Additionally, magnitude profiles of the electric and magnetic fields, the energy density and the Poynting vector are displayed for Bessel beams in both paraxial and nonparaxial cases. The results presented in this paper provide a fresh perspective on the description of Bessel beams and cast some insights into the light scattering and light-matter interactions problems in practice.

  5. Symmetric and antisymmetric structure constants for SU(6)

    SciTech Connect

    Sarid, U.

    1985-08-01

    The 124 completely antisymmetric f/sub i/jk and 221 completely symmetric d/sub i/jk (nonzero) structure constants for a simple representation of SU(6) are tabulated. The basis matrices lambda/sub i/ used to generate the structure constants are also given.

  6. Topological phase in a non-Hermitian PT symmetric system

    NASA Astrophysics Data System (ADS)

    Yuce, C.

    2015-06-01

    In this work, we consider a tight binding lattice with two non-Hermitian impurities. The system is described by a non-Hermitian generalization of the Aubry-Andre model. We show that there exists topologically nontrivial edge states for the system in the PT symmetric region.

  7. Symmetric Electrodes for Electrochemical Energy-Storage Devices.

    PubMed

    Zhang, Lei; Dou, Shi Xue; Liu, Hua Kun; Huang, Yunhui; Hu, Xianluo

    2016-12-01

    Increasing environmental problems and energy challenges have so far attracted urgent demand for developing green and efficient energy-storage systems. Among various energy-storage technologies, sodium-ion batteries (SIBs), electrochemical capacitors (ECs) and especially the already commercialized lithium-ion batteries (LIBs) are playing very important roles in the portable electronic devices or the next-generation electric vehicles. Therefore, the research for finding new electrode materials with reduced cost, improved safety, and high-energy density in these energy storage systems has been an important way to satisfy the ever-growing demands. Symmetric electrodes have recently become a research focus because they employ the same active materials as both the cathode and anode in the same energy-storage system, leading to the reduced manufacturing cost and simplified fabrication process. Most importantly, this feature also endows the symmetric energy-storage system with improved safety, longer lifetime, and ability of charging in both directions. In this Progress Report, we provide the comprehensive summary and comment on different symmetric electrodes and focus on the research about the applications of symmetric electrodes in different energy-storage systems, such as the above mentioned SIBs, ECs and LIBs. Further considerations on the possibility of mass production have also been presented.

  8. Left-right-symmetric model parameters: Updated bounds

    SciTech Connect

    Polak, J.; Zralek, M. )

    1992-11-01

    Using the available updated experimental data, including the last results from the CERN {ital e}{sup +}{ital e{minus}} collider LEP and improved parity-violation results, we find new constraints on the parameters in the left-right-symmetric model in the case of light right-handed neutrinos.

  9. Fault-tolerant symmetrically-private information retrieval

    NASA Astrophysics Data System (ADS)

    Wang, Tian-Yin; Cai, Xiao-Qiu; Zhang, Rui-Ling

    2016-08-01

    We propose two symmetrically-private information retrieval protocols based on quantum key distribution, which provide a good degree of database and user privacy while being flexible, loss-resistant and easily generalized to a large database similar to the precedent works. Furthermore, one protocol is robust to a collective-dephasing noise, and the other is robust to a collective-rotation noise.

  10. Separator-Integrated, Reversely Connectable Symmetric Lithium-Ion Battery.

    PubMed

    Wang, Yuhang; Zeng, Jiren; Cui, Xiaoqi; Zhang, Lijuan; Zheng, Gengfeng

    2016-02-24

    A separator-integrated, reversely connectable, symmetric lithium-ion battery is developed based on carbon-coated Li3V2(PO4)3 nanoparticles and polyvinylidene fluoride-treated separators. The Li3V2(PO4)3 nanoparticles are synthesized via a facile solution route followed by calcination in Ar/H2 atmosphere. Sucrose solution is used as the carbon source for uniform carbon coating on the Li3V2(PO4)3 nanoparticles. Both the carbon and the polyvinylidene fluoride treatments substantially improve the cycling life of the symmetric battery by preventing the dissolution and shuttle of the electroactive Li3V2(PO4)3. The obtained symmetric full cell exhibits a reversible capacity of ≈ 87 mA h g(-1), good cycling stability, and capacity retention of ≈ 70% after 70 cycles. In addition, this type of symmetric full cell can be operated in both forward and reverse connection modes, without any influence on the cycling of the battery. Furthermore, a new separator integration approach is demonstrated, which enables the direct deposition of electroactive materials for the battery assembly and does not affect the electrochemical performance. A 10-tandem-cell battery assembled without differentiating the electrode polarity exhibits a low thickness of ≈ 4.8 mm and a high output voltage of 20.8 V.

  11. Symmetric Nonlinear Regression. Research Report. ETS RR-07-13

    ERIC Educational Resources Information Center

    Antal, Tamás

    2007-01-01

    An estimation tool for symmetric univariate nonlinear regression is presented. The method is based on introducing a nontrivial set of affine coordinates for diffeomorphisms of the real line. The main ingredient making the computations possible is the Connes-Moscovici Hopf algebra of these affine coordinates.

  12. Non-Real Eigenvalues for PT-Symmetric Double Wells

    NASA Astrophysics Data System (ADS)

    Benbernou, Amina; Boussekkine, Naima; Mecherout, Nawal; Ramond, Thierry; Sjöstrand, Johannes

    2016-12-01

    We study small, PT-symmetric perturbations of self-adjoint double-well Schrödinger operators in dimension {n≥ 1}. We prove that the eigenvalues stay real for a very small perturbation, then bifurcate to the complex plane as the perturbation gets stronger.

  13. Radiative seesaw in left-right symmetric model

    SciTech Connect

    Gu Peihong; Sarkar, Utpal

    2008-10-01

    There are some radiative origins for the neutrino masses in the conventional left-right symmetric models with the usual bidoublet and triplet Higgs scalars. These radiative contributions could dominate over the tree-level seesaw and could explain the observed neutrino masses.

  14. Perturbation approximation for orbits in axially symmetric funnels

    NASA Astrophysics Data System (ADS)

    Nauenberg, Michael

    2014-11-01

    A perturbation method that can be traced back to Isaac Newton is applied to obtain approximate analytic solutions for objects sliding in axially symmetric funnels in near circular orbits. Some experimental observations are presented for balls rolling in inverted cones with different opening angles, and in a funnel with a hyperbolic surface that approximately simulates the gravitational force.

  15. Symmetrical Womanhood: The Educational Ideology of Activism at Wellesley.

    ERIC Educational Resources Information Center

    Palmieri, Patricia Ann

    1995-01-01

    The ideology of higher education for women at Wellesley College in the late 19th and early 20th centuries is discussed in the context of feminism and the women's suffrage movement. "Symmetrical womanhood," a concept emphasizing balance of traditional roles and intellectual and community involvement, was a goal of Wellesley faculty of…

  16. Duality, phase structures, and dilemmas in symmetric quantum games

    SciTech Connect

    Ichikawa, Tsubasa . E-mail: tsubasa@post.kek.jp; Tsutsui, Izumi

    2007-03-15

    Symmetric quantum games for 2-player, 2-qubit strategies are analyzed in detail by using a scheme in which all pure states in the 2-qubit Hilbert space are utilized for strategies. We consider two different types of symmetric games exemplified by the familiar games, the Battle of the Sexes (BoS) and the Prisoners' Dilemma (PD). These two types of symmetric games are shown to be related by a duality map, which ensures that they share common phase structures with respect to the equilibria of the strategies. We find eight distinct phase structures possible for the symmetric games, which are determined by the classical payoff matrices from which the quantum games are defined. We also discuss the possibility of resolving the dilemmas in the classical BoS, PD, and the Stag Hunt (SH) game based on the phase structures obtained in the quantum games. It is observed that quantization cannot resolve the dilemma fully for the BoS, while it generically can for the PD and SH if appropriate correlations for the strategies of the players are provided.

  17. Symmetric Electrodes for Electrochemical Energy‐Storage Devices

    PubMed Central

    Zhang, Lei; Dou, Shi Xue; Huang, Yunhui

    2016-01-01

    Increasing environmental problems and energy challenges have so far attracted urgent demand for developing green and efficient energy‐storage systems. Among various energy‐storage technologies, sodium‐ion batteries (SIBs), electrochemical capacitors (ECs) and especially the already commercialized lithium‐ion batteries (LIBs) are playing very important roles in the portable electronic devices or the next‐generation electric vehicles. Therefore, the research for finding new electrode materials with reduced cost, improved safety, and high‐energy density in these energy storage systems has been an important way to satisfy the ever‐growing demands. Symmetric electrodes have recently become a research focus because they employ the same active materials as both the cathode and anode in the same energy‐storage system, leading to the reduced manufacturing cost and simplified fabrication process. Most importantly, this feature also endows the symmetric energy‐storage system with improved safety, longer lifetime, and ability of charging in both directions. In this Progress Report, we provide the comprehensive summary and comment on different symmetric electrodes and focus on the research about the applications of symmetric electrodes in different energy‐storage systems, such as the above mentioned SIBs, ECs and LIBs. Further considerations on the possibility of mass production have also been presented. PMID:27981003

  18. All static spherically symmetric anisotropic solutions of Einstein's equations

    SciTech Connect

    Herrera, L.; Di Prisco, A.; Ospino, J.

    2008-01-15

    An algorithm recently presented by Lake to obtain all static spherically symmetric perfect fluid solutions is extended to the case of locally anisotropic fluids (principal stresses unequal). As expected, the new formalism requires the knowledge of two functions (instead of one) to generate all possible solutions. To illustrate the method some known cases are recovered.

  19. Symmetric Peripheral Gangrene Associated with H1N1 Infection

    PubMed Central

    Kaulgud, Ram S.; Kamath, Vasantha; Patil, Vijayalaxmi; Desai, Sagar

    2013-01-01

    More and more cases of H1N1 influenza are being detected in India and so also the variety of complications this virus can cause. Here, we report a case of symmetric peripheral gangrene following H1N1 infection. PMID:24319562

  20. LANZ: Software solving the large sparse symmetric generalized eigenproblem

    NASA Technical Reports Server (NTRS)

    Jones, Mark T.; Patrick, Merrell L.

    1990-01-01

    A package, LANZ, for solving the large symmetric generalized eigenproblem is described. The package was tested on four different architectures: Convex 200, CRAY Y-MP, Sun-3, and Sun-4. The package uses a Lanczos' method and is based on recent research into solving the generalized eigenproblem.

  1. Lipometer subcutaneous adipose tissue topography (SAT-Top) reflects serum leptin levels varying in circadian rhythms

    NASA Astrophysics Data System (ADS)

    Moeller, Reinhard; Tafeit, Erwin; Sudi, Karl; Vrecko, Karoline; Horejsi, Renate; Hinghofer-Szalkay, Helmut G.; Reibnegger, Gilbert

    1998-05-01

    Recent advances in obesity research have shown that the product of the ob-gene named leptin is related to total body fast mass in humans. There is, however, a debate if leptin levels are pulsatile and linked to body fat distribution. In this study we therefore investigated the subcutaneous adipose tissue topography (SAT-Top) measured by means of the newly developed device Lipometer and leptin levels during a 24 hours beginning at 0715am ending the same time in the next day. Blood samples for measurement of leptin were taken every 3 hours in a male subject. Measurements of SAT-Top were performed at 15 body sites from neck to calf at the left and right body site at the same time interval. We observed an almost symmetrically reaction of the left and right body site with a maximum of the mean value of all body sites in the evening at 0715pm. There was a negative correlation between serum leptin levels and SAT-Top using the set of certain body sites (R2 equals 0.80, p equals 0.01). If these combination of body sites is inversed and set against serum leptin levels, both curves show almost identical shape and time dependence. We conclude that SAT-Top by means of Lipometer is changed in a short time and related to leptin levels in the investigated male subject.

  2. Single molecule diffraction.

    PubMed

    Spence, J C H; Doak, R B

    2004-05-14

    For solving the atomic structure of organic molecules such as small proteins which are difficult to crystallize, the use of a jet of doped liquid helium droplets traversing a continuous high energy electron beam is proposed as a means of obtaining electron diffraction patterns (serial crystallography). Organic molecules (such as small proteins) within the droplet (and within a vitreous ice jacket) may be aligned by use of a polarized laser beam. Iterative methods for solving the phase problem are indicated. Comparisons with a related plan for pulsed x-ray diffraction from single proteins in a molecular beam are provided.

  3. Enzyme molecules as nanomotors.

    PubMed

    Sengupta, Samudra; Dey, Krishna K; Muddana, Hari S; Tabouillot, Tristan; Ibele, Michael E; Butler, Peter J; Sen, Ayusman

    2013-01-30

    Using fluorescence correlation spectroscopy, we show that the diffusive movements of catalase enzyme molecules increase in the presence of the substrate, hydrogen peroxide, in a concentration-dependent manner. Employing a microfluidic device to generate a substrate concentration gradient, we show that both catalase and urease enzyme molecules spread toward areas of higher substrate concentration, a form of chemotaxis at the molecular scale. Using glucose oxidase and glucose to generate a hydrogen peroxide gradient, we induce the migration of catalase toward glucose oxidase, thereby showing that chemically interconnected enzymes can be drawn together.

  4. Floppy Molecules with Internal Rotation and Inversion

    NASA Astrophysics Data System (ADS)

    Kreglewski, Marek

    2016-06-01

    There are different ways to analyze rovibrational structure of molecules having several large amplitude motions of different type, like internal rotation and inversion or ring-puckering. In my research group we have developed and used methods starting from potential surfaces for large amplitude motions but also applied purely effective Hamiltonians, where tunneling splittings were key parameters. Whatever is the method the following problems must be solved when addressing a rovibrational problem with large amplitude vibrations: 1) a definition of the permutation-inversion molecular symmetry group, 2) a choice of the internal coordinates and their transformation in the symmetry group, 3) derivation of the Hamiltonian in chosen coordinates, 4) calculation of the Hamiltonian matrix elements in a symmetrized basis set. These points will be discussed. The advantage of methods which start from the geometry and potential surface for large amplitude vibrations give much clearer picture of internal dynamics of molecules but generally the fit to experimental data is much poorer. The fitting procedure is strongly non-linear and the iteration procedure much longer. The effective Hamiltonians the fit is generally much better since almost all optimized parameters are linear but the parameters have no clear physical meaning. This method is very useful in the assignment of experimental spectra. Results of the application of both method to methylamine and hydrazine will be presented.

  5. Various photonic crystal structures fabricated by using a top-cut hexagonal prism

    NASA Astrophysics Data System (ADS)

    Sun, X. H.; Tao, X. M.; Wang, Y. Y.

    2010-02-01

    We demonstrate a holographic approach for the fabrication of large-area photonic crystal (PhC) microstructures by applying a single top-cut hexagonal prism (TCHP). The interference patterns of the beams from the TCHP are calculated. Various two-dimensional PhC structures are fabricated in photo-resist films. They include symmetrical hexagonal structures, the honey-comb structure and the hexagonal structure with skewed elliptical rods. The first structures come from six-beam and symmetrical three-beam interfering. The second structure appears when the beam is incident on the TCHP obliquely. The third structure is obtained when adjacent three beams or four beams are interfered. The period can be decreased to 285 nm. SPM observations of the PhCs provide the basis for measurement of their structural parameters. A good agreement is obtained for the measured structural parameters and calculated results for the PhCs. The photonic band gaps of the hexagonal symmetrical and honeycomb structures are derived by using the plane wave method. These results reveal that, by varying the number of split beams and the incident angle, using the single TCHP PhCs, different band gaps can be achieved.

  6. Complex PT-symmetric nonlinear Schrödinger equation and Burgers equation.

    PubMed

    Yan, Zhenya

    2013-04-28

    The complex -symmetric nonlinear wave models have drawn much attention in recent years since the complex -symmetric extensions of the Korteweg-de Vries (KdV) equation were presented in 2007. In this review, we focus on the study of the complex -symmetric nonlinear Schrödinger equation and Burgers equation. First of all, we briefly introduce the basic property of complex symmetry. We then report on exact solutions of one- and two-dimensional nonlinear Schrödinger equations (known as the Gross-Pitaevskii equation in Bose-Einstein condensates) with several complex -symmetric potentials. Finally, some complex -symmetric extension principles are used to generate some complex -symmetric nonlinear wave equations starting from both -symmetric (e.g. the KdV equation) and non- -symmetric (e.g. the Burgers equation) nonlinear wave equations. In particular, we discuss exact solutions of some representative ones of the complex -symmetric Burgers equation in detail.

  7. Discovery of single top quark production

    SciTech Connect

    Gillberg, Dag

    2009-04-01

    The top quark is by far the heaviest known fundamental particle with a mass nearing that of a gold atom. Because of this strikingly high mass, the top quark has several unique properties and might play an important role in electroweak symmetry breaking - the mechanism that gives all elementary particles mass. Creating top quarks requires access to very high energy collisions, and at present only the Tevatron collider at Fermilab is capable of reaching these energies. Until now, top quarks have only been observed produced in pairs via the strong interaction. At hadron colliders, it should also be possible to produce single top quarks via the electroweak interaction. Studies of single top quark production provide opportunities to measure the top quark spin, how top quarks mix with other quarks, and to look for new physics beyond the standard model. Because of these interesting properties, scientists have been looking for single top quarks for more than 15 years. This thesis presents the first discovery of single top quark production. An analysis is performed using 2.3 fb-1 of data recorded by the D0 detector at the Fermilab Tevatron Collider at centre-of-mass energy √s = 1.96 TeV. Boosted decision trees are used to isolate the single top signal from background, and the single top cross section is measured to be σ(p$\\bar{p}$ → tb + X, tqb + X) = 3.74-0.74+0.95 pb. Using the same analysis, a measurement of the amplitude of the CKM matrix element Vtb, governing how top and b quarks mix, is also performed. The measurement yields: |V{sub tb}|f1L| = 1.05 -0.12+0.13, where f1L is the left-handed Wtb coupling. The separation of signal from background is improved by combining the boosted decision trees with two other multivariate techniques. A new cross section measurement is performed, and the significance for the excess over the predicted background exceeds 5

  8. Imaging of photoinduced tautomerism in single porphyrin molecules

    NASA Astrophysics Data System (ADS)

    Jäger, Regina; Chizhik, Anna M.; Chizhik, Alexey I.; Mack, Hans-Georg; Lyubimtsev, Alexey; Hanack, Michael; Meixner, Alfred J.

    2011-10-01

    In this work we present our new experimental and theoretical results upon investigations of the photoinduced tautomerism processes of single metal-free porphyrin-type molecules. During tautomerization a molecule changes its structure, therefore the excitation transition dipole moment (TDM) of the molecule changes its orientation. Using confocal microscopy in combination with azimuthally and radially polarized laser beams we are able to determine the orientation of the TDM as well as the orientation of a single molecule itself. In the case of tautomerism we are able to visualize this process and even the involved isomers separately. The study first focuses on two symmetrical compounds: a phthalocyanine and a porphyrin. Additionally, differences of the single molecules embedded in a polymer matrix or just spin-coated on a glass cover slide and under nitrogen flow are investigated. In the latter case we observe a higher frequency of the change of the TDM orientation. The experimental studies are supplemented by quantum chemical calculations. Variations of the molecular substituents, the environment and excitation wavelength can give new insights into the excited-state tautomerism process of a single molecule. We also introduce some suggestions for future experiments to support the understanding of the photoinduced tautomerism.

  9. A symmetrical Waxholm canonical mouse brain for NeuroMaps

    PubMed Central

    Bowden, Douglas M.; Johnson, G. Allan; Zaborsky, Laszlo; Green, William D.K.; Moore, Eider; Badea, Alexandra; Dubach, Mark F.; Bookstein, Fred L.

    2011-01-01

    NeuroMaps (2009) is a web-based application that enables investigators to map data from macaque studies to a canonical atlas of the macaque brain. It includes an image processor enabling one to create figures suitable for publication. Eventually it will enable investigators studying several species to analyze overlap between their data and multimodality data mapped by others. The purpose of this project was to incorporate the Waxholm canonical mouse brain (Hawrylycz, 2009) into NeuroMaps. An enhanced gradient echo (T2*) magnetic resonance image (MRI) of the Waxholm brain (Johnson et al., 2010) was warped to bring the irregular biological midplane of the MRI into line with the mathematically flat midsagittal plane of Waxholm space. The left hemisphere was deleted and the right reflected to produce a symmetrical 3D MRI. The symmetrical T2* image was imported into NeuroMaps. The map executing the warp was applied to four other voxellated volumes based on the same specimen and maintained at the Center for In-Vitro Microscopy (CIVM): a T2-weighted MRI, a T1 weighted MRI, a segmented image and an image reconstructed from Nissl-stained histological sections. Symmetric versions of those images were submitted to the CIVM repository where they are available to other laboratories. Utility of the symmetric atlas was demonstrated by mapping and comparing a cortical areas illustrated in three conventional mouse brain atlases. The symmetric Waxholm mouse brain atlas is now accessible in NeuroMaps. Investigators can map image data to standard templates over the Web and process them for publication, presentation and archival purposes: http://braininfo.rprc.washington.edu/MapViewData.aspx. PMID:21163300

  10. Hydrogen bond symmetrization and superconducting phase of HBr and HCl under high pressure: An ab initio study.

    PubMed

    Duan, Defang; Tian, Fubo; He, Zhi; Meng, Xing; Wang, Liancheng; Chen, Changbo; Zhao, Xiusong; Liu, Bingbing; Cui, Tian

    2010-08-21

    Ab initio calculations are performed to probe the hydrogen bonding, structural, and superconducting behaviors of HBr and HCl under high pressure. The calculated results show that the hydrogen bond symmetrization (Cmc2(1)-->Cmcm transition) of HBr and HCl occurs at 25 and 40 GPa, respectively, which can be attributed to the symmetry stretching A(1) mode softening. After hydrogen bond symmetrization, a pressure-induced soft transverse acoustic phonon mode of Cmcm phase is identified and a unique metallic phase with monoclinic structure of P2(1)/m (4 molecules/cell) for both compounds is revealed by ab initio phonon calculations. This phase preserves the symmetric hydrogen bond and is stable in the pressure range from 134 to 196 GPa for HBr and above 233 GPa for HCl, while HBr is predicted to decompose into Br(2)+H(2) above 196 GPa. Perturbative linear-response calculations predict that the phase P2(1)/m is a superconductor with T(c) of 27-34 K for HBr at 160 GPa and 9-14 K for HCl at 280 GPa.

  11. Metal-metal multiple bonding in C3-symmetric bimetallic complexes of the first row transition metals.

    PubMed

    Krogman, Jeremy P; Thomas, Christine M

    2014-05-25

    Metal-metal multiple bonds have been an intense area of focus in inorganic chemistry for many decades as a result of their fundamentally interesting bonding properties, as well as their potential applications in multielectron transfer and small molecule activation processes. Much of what is known in this field revolves around 2nd and 3rd row transition metals, with fundamental knowledge lacking in the area of bonds between elements of the first transition series. The smaller size and tendency of first row ions to adopt high-spin electron configurations weaken metal-metal interactions and serve to complicate the interpretation of the electronic structure and bonding in bimetallic species containing first row transition metals. Furthermore, traditional tetragonal "paddlewheel" complexes dominate the metal-metal multiple bond literature, and only recently have researchers begun to take advantage of the weaker ligand field in three-fold symmetric bimetallic complexes to encourage more favourable metal-metal bonding interactions. In the past 5 years, several research groups have exploited three-fold symmetric frameworks to investigate new trends in metal-metal bonding involving the first row transition metals. This feature article serves to highlight recent achievements in this area and to use C3-symmetric systems as a model to better understand the fundamental aspects of multiple bonds featuring first row transition metals.

  12. Measurement of the top quark mass

    SciTech Connect

    Blusk, Steven R.

    1998-05-01

    The first evidence and subsequent discovery of the top quark was reported nearly 4 years ago. Since then, CDF and D0 have analyzed their full Run 1 data samples, and analysis techniques have been refined to make optimal use of the information. In this paper, we report on the most recent measurements of the top quark mass, performed by the CDF and D0 collaborations at the Fermilab Tevatron. The CDF collaboration has performed measurements of the top quark mass in three decay channels from which the top quark mass is measured to be 175.5 {+-} 6.9 GeV=c{sup 2}. The D0 collaboration combines measurements from two decay channels to obtain a top quark mass of 172.1 {+-} 7.1 GeV/c{sup 2}. Combining the measurements from the two experiments, assuming a 2 GeV GeV/c{sup 2} correlated systematic uncertainty, the measurement of the top quark mass at the Tevatron is 173.9 {+-} 5.2 GeV/c{sup 2}. This report presents the measurements of the top quark mass from each of the decay channels which contribute to this measurement.

  13. The Top Quark, QCD, And New Physics.

    DOE R&D Accomplishments Database

    Dawson, S.

    2002-06-01

    The role of the top quark in completing the Standard Model quark sector is reviewed, along with a discussion of production, decay, and theoretical restrictions on the top quark properties. Particular attention is paid to the top quark as a laboratory for perturbative QCD. As examples of the relevance of QCD corrections in the top quark sector, the calculation of e{sup+}e{sup -}+ t{bar t} at next-to-leading-order QCD using the phase space slicing algorithm and the implications of a precision measurement of the top quark mass are discussed in detail. The associated production of a t{bar t} pair and a Higgs boson in either e{sup+}e{sup -} or hadronic collisions is presented at next-to-leading-order QCD and its importance for a measurement of the top quark Yulrawa coupling emphasized. Implications of the heavy top quark mass for model builders are briefly examined, with the minimal supersymmetric Standard Model and topcolor discussed as specific examples.

  14. Sweeping molecules with light

    NASA Astrophysics Data System (ADS)

    Hutzler, Nicholas R.

    2017-03-01

    Many areas of physics—precision measurements, quantum information, and physical chemistry, to name a few—are starting to benefit from the enormous advantages offered by cold and ultracold polar molecules. Molecules have more states, more interactions, and more chemical properties compared to atoms, which make them exciting to study but difficult to tame. In particular, the powerful techniques of atomic laser cooling cannot be naïvely applied to molecules due to their complicated structure. Developments over the past few years have made directly laser cooled and trapped molecules a reality, and now much effort is focused on making these samples larger, denser, and colder—an important step to realizing many of their exciting applications. A careful experimental and numerical study by Truppe et al (2017 New J. Phys. 19 022001) demonstrates a significant improvement and advance in understanding of one of the most limiting steps in laser cooling and trapping of molecules—slowing them from a molecular beam to a near-standstill, with small enough kinetic energy that they can be loaded into a trap.

  15. Disentangling DNA molecules.

    PubMed

    Vologodskii, Alexander

    2016-09-01

    The widespread circular form of DNA molecules inside cells creates very serious topological problems during replication. Due to the helical structure of the double helix the parental strands of circular DNA form a link of very high order, and yet they have to be unlinked before the cell division. DNA topoisomerases, the enzymes that catalyze passing of one DNA segment through another, solve this problem in principle. However, it is very difficult to remove all entanglements between the replicated DNA molecules due to huge length of DNA comparing to the cell size. One strategy that nature uses to overcome this problem is to create the topoisomerases that can dramatically reduce the fraction of linked circular DNA molecules relative to the corresponding fraction at thermodynamic equilibrium. This striking property of the enzymes means that the enzymes that interact with DNA only locally can access their topology, a global property of circular DNA molecules. This review considers the experimental studies of the phenomenon and analyzes the theoretical models that have been suggested in attempts to explain it. We describe here how various models of enzyme action can be investigated computationally. There is no doubt at the moment that we understand basic principles governing enzyme action. Still, there are essential quantitative discrepancies between the experimental data and the theoretical predictions. We consider how these discrepancies can be overcome.

  16. Diversity in Biological Molecules

    ERIC Educational Resources Information Center

    Newbury, H. John

    2010-01-01

    One of the striking characteristics of fundamental biological processes, such as genetic inheritance, development and primary metabolism, is the limited amount of variation in the molecules involved. Natural selective pressures act strongly on these core processes and individuals carrying mutations and producing slightly sub-optimal versions of…

  17. Mighty Molecule Models

    ERIC Educational Resources Information Center

    Brown, Tom; Rushton, Greg; Bencomo, Marie

    2008-01-01

    As part of the SMATHematics Project: The Wonder of Science, The Power of Mathematics--a collaborative partnership between Kennesaw State University and two local school districts, fifth graders had the opportunity to puzzle out chemical formulas of propane, methanol, and other important molecules. In addition, they explored properties that…

  18. Algebraic theory of molecules

    NASA Technical Reports Server (NTRS)

    Iachello, Franco

    1995-01-01

    An algebraic formulation of quantum mechanics is presented. In this formulation, operators of interest are expanded onto elements of an algebra, G. For bound state problems in nu dimensions the algebra G is taken to be U(nu + 1). Applications to the structure of molecules are presented.

  19. Single molecules: Thermodynamic limits

    NASA Astrophysics Data System (ADS)

    Liphardt, Jan

    2012-09-01

    Technologies aimed at single-molecule resolution of non-equilibrium systems increasingly require sophisticated new ways of thinking about thermodynamics. An elegant extension to standard fluctuation theory grants access to the kinetic intermediate states of these systems -- as DNA-pulling experiments now demonstrate.

  20. Disentangling DNA molecules

    NASA Astrophysics Data System (ADS)

    Vologodskii, Alexander

    2016-09-01

    The widespread circular form of DNA molecules inside cells creates very serious topological problems during replication. Due to the helical structure of the double helix the parental strands of circular DNA form a link of very high order, and yet they have to be unlinked before the cell division. DNA topoisomerases, the enzymes that catalyze passing of one DNA segment through another, solve this problem in principle. However, it is very difficult to remove all entanglements between the replicated DNA molecules due to huge length of DNA comparing to the cell size. One strategy that nature uses to overcome this problem is to create the topoisomerases that can dramatically reduce the fraction of linked circular DNA molecules relative to the corresponding fraction at thermodynamic equilibrium. This striking property of the enzymes means that the enzymes that interact with DNA only locally can access their topology, a global property of circular DNA molecules. This review considers the experimental studies of the phenomenon and analyzes the theoretical models that have been suggested in attempts to explain it. We describe here how various models of enzyme action can be investigated computationally. There is no doubt at the moment that we understand basic principles governing enzyme action. Still, there are essential quantitative discrepancies between the experimental data and the theoretical predictions. We consider how these discrepancies can be overcome.

  1. Three new 'nonterrestrial' molecules

    NASA Astrophysics Data System (ADS)

    Thaddeus, P.; Guelin, M.; Linke, R. A.

    1981-05-01

    Eight new interstellar lines have been detected from three molecules not previously observed spectroscopically in space or in the laboratory. One is a linear or nearly linear molecule with microwave constants B0 equals 21,337.15 plus or minus 0.06 MHz, D0 equals 21.4 plus or minus 1.5 kHz. This is the thioformyl ion HCS(plus), first identified because B0 and D0 are close to those calculated, and now confirmed by laboratory detection of one of the present lines (Gudeman et al.). The second molecule, also linear or nearly so, has microwave constants B0 equals 10,691,406 plus or minus 0.043 MHz, D0 equals 1.84 plus or minus 0.91 kHz close to those expected for the isoelectronic systems HOCO(plus) and HOCN; a choice between the two cannot be made on the basis of the available astronomical data. The existence of a third molecule is deduced from an unidentified line at 85,338 MHz that has been found in many sources, is fairly intense in several, and may be self-absorbed in Sgr B2.

  2. Tevatron Top-Quark Combinations and World Top-Quark Mass Combination

    SciTech Connect

    Peters, Reinhild Yvonne

    2014-11-04

    Almost 20 years after its discovery, the top quark is still an interesting particle, undergoing precise investigation of its properties. For many years, the Tevatron proton antiproton collider at Fermilab was the only place to study top quarks in detail, while with the recent start of the LHC proton proton collider a top quark factory has opened. An important ingredient for the full understanding of the top quark is the combination of measurements from the individual experiments. In particular, the Tevaton combinations of single top-quark cross sections, the ttbar production cross section, the W helicity in top-quark decays as well as the Tevatron and the world combination of the top-quark mass are discussed.

  3. Precision Determination of the Top Quark Mass

    SciTech Connect

    Movilla Fernandez, Pedro A.; /LBL, Berkeley

    2007-05-01

    The CDF and D0 collaborations have updated their measurements of the mass of the top quark using proton-antiproton collisions at {radical}s = 1.96 TeV produced at the Tevatron. The uncertainties in each of the top-antitop decay channels have been reduced. The new Tevatron average for the mass of the top quark based on about 1 fb{sup -1} of data per experiment is 170.9 {+-} 1.8 GeV/c{sup 2}.

  4. Single Top Quark Measurements at the Tevatron

    SciTech Connect

    Ronzani, Manfredi

    2014-12-01

    This paper reports the most recent measurements of single top quark production performed by CDF and D0 collaborations in proton-antiproton collisions at Tevatron. Events are selected in the lepton+jets final state by CDF and D0 and in the missing transverse energy plus jets final state by CDF. The small single top signal in s-channel, t-channel and inclusive s+t channel is separated from the large background by using different multivariate techniques. We also present the most recent results on extraction of the CKM matrix element $|V_{tb}|$ from the single top quark cross section.

  5. Top quark mass measurement at the Tevatron

    SciTech Connect

    Guimaraes da Costa, Joao; /Harvard U.

    2004-12-01

    The authors report on the latest experimental measurements of the top quark mass by the CDF and D0 Collaborations at the Fermilab Tevatron. They present a new top mass measurement using the t{bar t} events collected by the D0 Collaboration in Run I between 1994 and 1996. This result is combined with previous measurements to yield a new world top mass average. They also describe several preliminary results using up to 193 pb{sup -1} of t{bar t} events produced in {bar p}p collisions at {radical}s = 1.96 TeV during the Run II of the Tevatron.

  6. Top quark properties from the Tevatron

    SciTech Connect

    Klute, Markus; /MIT, LNS

    2006-05-01

    This report describes latest measurements and studies of top quark properties from the Tevatron in Run II with an integrated luminosity of up to 750 pb{sup -1}. Due to its large mass of about 172 GeV/c{sup 2}, the top quark provides a unique environment for tests of the Standard Model and is believed to yield sensitivity to new physics beyond the Standard Model. With data samples of close to 1 fb{sup -1} the CDF and D0 collaborations at the Tevatron enter a new area of precision top quark measurements.

  7. A New Approach to Materials Discovery for Electronic and Thermoelectric Properties of Single-Molecule Junctions.

    PubMed

    Manrique, David Zsolt; Al-Galiby, Qusiy; Hong, Wenjing; Lambert, Colin J

    2016-02-10

    We have investigated a large set of symmetric and asymmetric molecules to demonstrate a general rule for molecular-scale quantum transport, which provides a new route to materials design and discovery. The rule states "the conductance GXBY of an asymmetric molecule is the geometric mean of the conductance of the two symmetric molecules derived from it and the thermopower SXBY of the asymmetric molecule is the algebraic mean of their thermopowers". The studied molecules have a structure X-B-Y, where B is the backbone of the molecule, while X and Y are anchor groups, which bind the molecule to metallic electrodes. When applied to experimentally measured histograms of conductance and thermopower, the rules apply to the statistically most probable values. We investigated molecules with anchors chosen from the following family: cyano, pyridl, dihydrobenzothiol, amine and thiol. For the backbones B, we tested 14 different structures. We found that the formulas (GXBY)(2) = GXBX*GYBY and SXBY = (SXBX + SYBY)/2 were satisfied in the large majority of the cases, provided the Fermi energy is located within the HOMO-LUMO gap of the molecules. The circuit rules imply that if measurements are performed on molecules with nA different anchors and nB different backbones, then properties of nA(nA + 1)nB/2 molecules can be predicted. So for example, in the case of 20 backbones and 10 anchors, 30 measurements (or reliable calculations) can provide a near quantitative estimate for 1070 measurements of other molecules, at no extra cost.

  8. OMG: Open Molecule Generator.

    PubMed

    Peironcely, Julio E; Rojas-Chertó, Miguel; Fichera, Davide; Reijmers, Theo; Coulier, Leon; Faulon, Jean-Loup; Hankemeier, Thomas

    2012-09-17

    Computer Assisted Structure Elucidation has been used for decades to discover the chemical structure of unknown compounds. In this work we introduce the first open source structure generator, Open Molecule Generator (OMG), which for a given elemental composition produces all non-isomorphic chemical structures that match that elemental composition. Furthermore, this structure generator can accept as additional input one or multiple non-overlapping prescribed substructures to drastically reduce the number of possible chemical structures. Being open source allows for customization and future extension of its functionality. OMG relies on a modified version of the Canonical Augmentation Path, which grows intermediate chemical structures by adding bonds and checks that at each step only unique molecules are produced. In order to benchmark the tool, we generated chemical structures for the elemental formulas and substructures of different metabolites and compared the results with a commercially available structure generator. The results obtained, i.e. the number of molecules generated, were identical for elemental compositions having only C, O and H. For elemental compositions containing C, O, H, N, P and S, OMG produces all the chemically valid molecules while the other generator produces more, yet chemically impossible, molecules. The chemical completeness of the OMG results comes at the expense of being slower than the commercial generator. In addition to being open source, OMG clearly showed the added value of constraining the solution space by using multiple prescribed substructures as input. We expect this structure generator to be useful in many fields, but to be especially of great importance for metabolomics, where identifying unknown metabolites is still a major bottleneck.

  9. Creation of Functional Micro/Nano Systems through Top-down and Bottom-up Approaches

    PubMed Central

    Wong, Tak-Sing; Brough, Branden; Ho, Chih-Ming

    2009-01-01

    Mimicking nature’s approach in creating devices with similar functional complexity is one of the ultimate goals of scientists and engineers. The remarkable elegance of these naturally evolved structures originates from bottom-up self-assembly processes. The seamless integration of top-down fabrication and bottom-up synthesis is the challenge for achieving intricate artificial systems. In this paper, technologies necessary for guided bottom-up assembly such as molecular manipulation, molecular binding, and the self assembling of molecules will be reviewed. In addition, the current progress of synthesizing mechanical devices through top-down and bottom-up approaches will be discussed. PMID:19382535

  10. Bacterial invasion reconstructed molecule by molecule

    SciTech Connect

    Werner, James H

    2009-01-01

    We propose to visualize the initial stages of bacterial infection of a human host cell with unmatched spatial and temporal resolution. This work will develop a new capability for the laboratory (super-resolution optical imaging), will test unresolved scientific hypotheses regarding host-pathogen interaction dynamics, and leverages state of the art 3D molecular tracking instrumentation developed recently by our group. There is much to be gained by applying new single molecule tools to the important and familiar problem of pathogen entry into a host cell. For example, conventional fluorescence microscopy has identified key host receptors, such as CD44 and {alpha}5{beta}1 integrin, that aggregate near the site of Salmonella typhimurium infection of human cells. However, due to the small size of the bacteria ({approx} 2 {micro}m) and the diffraction of the emitted light, one just sees a fluorescent 'blob' of host receptors that aggregate at the site of attachment, making it difficult to determine the exact number of receptors present or whether there is any particular spatial arrangement of the receptors that facilitates bacterial adhesion/entry. Using newly developed single molecule based super-resolution imaging methods, we will visualize how host receptors are directed to the site of pathogen adhesion and whether host receptors adopt a specific spatial arrangement for successful infection. Furthermore, we will employ our 3D molecular tracking methods to follow the injection of virulence proteins, or effectors, into the host cell by the pathogen Type III secretion system (TTSS). We expect these studies to provide mechanistic insights into the early events of pathogen infection that have here-to-fore been technically beyond our reach. Our Research Goals are: Goal 1--Construct a super-resolution fluorescence microscope and use this new capability to image the spatial distribution of different host receptors (e.g. CD44, as {alpha}5{beta}1 integrin) at the point of

  11. Water vapor near Venus cloud tops from VIRTIS-H/Venus express observations 2006-2011

    NASA Astrophysics Data System (ADS)

    Cottini, V.; Ignatiev, N. I.; Piccioni, G.; Drossart, P.

    2015-08-01

    This work aims to give a summary of the water vapor at the cloud top of Venus atmosphere using the complete set of observations made using high spectral resolution channel (-H) of Visible and Infrared Thermal Imaging Spectrometer (VIRTIS), on board the ESA Venus Express orbiter, to measure the cloud top altitude and the water vapor abundance near this level. An initial analysis of these measurements by Cottini et al. (2012) was limited to data in 140 orbits in the period 2007-2008. These observations were limited to the Northern hemisphere due to observational geometry in this early part of the mission. In the present paper, the analysis is extended to a larger dataset covering the years 2006-2011, significantly improving the latitudinal coverage. Altitude of the cloud tops, corresponding to unit optical depth at a wavelength of 2.5 μm, is equal to 69±1 km at low latitudes, and decreases toward the pole to 62-64 km. The water vapor abundance is equal to 3±1 ppm in low latitudes and it increases reaching a maximum of 5±2 ppm at 70-80° of latitude in both hemispheres, with a sharp drop in the polar regions. This can be explained by the specific dynamics of the atmosphere of Venus affecting the distribution of water vapor such as the transfer of water vapor in the Hadley cell and the dynamic in the polar vortex. The average height of the cloud tops and the H2O near this level are symmetric with respect to the equator. As a function of local solar time, the water vapor shows no particular dependence, and the cloud tops exhibit just a weak maximum around noon. Over 5 years of observations the average values of the cloud top altitude and the water vapor were quite stable in low and middle latitudes, while in high latitudes both quantities in 2009-2011 years are systematically higher than in 2006-2008. Short period variations increasing with latitude are observed, from approximately less than ±1 km for cloud tops and ±1 ppm for water vapor in low latitudes to

  12. Depolarized light scattering studies of the collision induced polarizability anisotropy of atoms and spherical top molecules

    NASA Astrophysics Data System (ADS)

    Dunmur, D. A.; Manterfield, M. R.; Robinson, D. J.

    New measurements are reported of the density dependent depolarization ratio for argon, krypton, xenon, methane and sulphur hexafluoride, and the results are analysed to provide values for the second and third depolarization virial coefficients. The relationships between the second depolarization virial coefficient, the zeroth moment of the two-body Rayleigh spectrum and the second Kerr virial coefficient are considered, and it is shown that they now provide consistent results for the collision-induced pair polarizability anisotropy. Former inconsistencies are attributed to insufficient allowance for the effects of three-body interactions. Calculations of the second and third depolarization virial coefficients based on the DID model and using the Maitland-Smith potential are in excellent agreement with the experimental results for argon, krypton and xenon.

  13. Top Five Lifestyle Changes to Reduce Cholesterol

    MedlinePlus

    Top 5 lifestyle changes to improve your cholesterol Lifestyle changes can help reduce cholesterol, keep you off cholesterol-lowering medications or enhance the effect of your medications. Here are five lifestyle ...

  14. Higgs Effects in Top Quark Pair Production

    SciTech Connect

    Kuhn, J.H.

    2003-06-13

    Top quark production in p{bar p} and e{sup +}e{sup -} collisions is enhanced by the exchange of a Higgs boson. The enhancement factors are calculated in the threshold region using the Greens function method.

  15. Top Quark Physics at the Tevatron

    SciTech Connect

    Jung, Andreas W.

    2015-05-21

    An overview of recent top quark measurements using the full Run II data set of CDF or D0 at the Tevatron is presented. Results are complementary to the ones at the LHC. Recent measurements of the production cross section of top quarks in strong and electroweak production and of top quark production asymmetries are presented. The latter includes the measurement of the tt-bar production asymmetry by D0 in the dilepton decay channel. Within their uncertainties the results from all these measurements agree with their respective Standard Model expectation. Finally latest updates on measurements of the top quark mass are discussed, which at the time of the conference are the most precise determinations.

  16. Wind Energy Program: Top 10 Program Accomplishments

    SciTech Connect

    2009-01-18

    Brochure on the top accomplishments of the Wind Energy Program, including the development of large wind machines, small machines for the residential market, wind tunnel testing, computer codes for modeling wind systems, high definition wind maps, and successful collaborations.

  17. Dark decay of the top quark

    SciTech Connect

    Kong, Kyoungchul; Lee, Hye -Sung; Park, Myeonghun

    2014-04-01

    We suggest top quark decays as a venue to search for light dark force carriers. Top quark is the heaviest particle in the standard model whose decays are relatively poorly measured, allowing sufficient room for exotic decay modes from new physics. A very light (GeV scale) dark gauge boson (Z') is a recently highlighted hypothetical particle that can address some astrophysical anomalies as well as the 3.6 σ deviation in the muon g-2 measurement. We present and study a possible scenario that top quark decays as t → b W + Z's. This is the same as the dominant top quark decay (t → b W) accompanied by one or multiple dark force carriers. The Z' can be easily boosted, and it can decay into highly collimated leptons (lepton-jet) with large branching ratio. In addition, we discuss the implications for the Large Hadron Collider experiments including the analysis based on the lepton-jets.

  18. Top partner probes of extended Higgs sectors

    NASA Astrophysics Data System (ADS)

    Kearney, John; Pierce, Aaron; Thaler, Jesse

    2013-08-01

    Natural theories of the weak scale often include fermionic partners of the top quark. If the electroweak symmetry breaking sector contains scalars beyond a single Higgs doublet, then top partners can have sizable branching ratios to these extended Higgs sector states. In fact, top partner decays may provide the most promising discovery mode for such scalars, especially given the large backgrounds to direct and associated production. In this paper, we present a search strategy for top partner decays to a charged Higgs boson and a bottom quark, focusing on the case where the charged Higgs dominantly decays to third-generation quarks to yield a multi- b final state. We also discuss ways to extend this search to exotic neutral scalars decaying to bottom quark pairs.

  19. Top decays and mass with CDF

    SciTech Connect

    Barbaro-Galtieri, A.; CDF Collaboration

    1996-06-01

    The authors report preliminary results on top quark decays and measurements of the top mass recently obtained by the CDF collaboration, using a data sample of about 110 pb{sup {minus}1} collected at the Tevatron collider. Upper limits for non Standard model top decays into W + q (non b quark), Z + q and {gamma} + q are given. Top mass measurements are obtained in three topologies for t{anti t} production and decay into W b: lepton + {ge} 4 jets, di-lepton and all hadronic final states. The most precise measurement is obtained in the lepton + {ge} 4 jets topology using 34 events which have at least one jet tagged by the SVX or SLT b-tagging algorithms and a good constrained kinematics fit.

  20. Giving top quark effective operators a boost

    NASA Astrophysics Data System (ADS)

    Englert, Christoph; Moore, Liam; Nordström, Karl; Russell, Michael

    2016-12-01

    We investigate the prospects to systematically improve generic effective field theory-based searches for new physics in the top sector during LHC run 2 as well as the high luminosity phase. In particular, we assess the benefits of high momentum transfer final states on top EFT-fit as a function of systematic uncertainties in comparison with sensitivity expected from fully-resolved analyses focusing on t t bar production. We find that constraints are typically driven by fully-resolved selections, while boosted top quarks can serve to break degeneracies in the global fit. This demystifies and clarifies the importance of high momentum transfer final states for global fits to new interactions in the top sector from direct measurements.