Antimicrobial properties of Cocos nucifera (coconut) husk: An extrapolation to oral health.

PubMed

Jose, Maji; Cyriac, Maria B; Pai, Vidya; Varghese, Ipe; Shantaram, Manjula

2014-07-01

Brushing the teeth with fibrous husk of Cocos nucifera (coconut) is a common oral hygiene practice among people of rural areas of South India. However, the probable antimicrobial properties of this plant material against common oral pathogens have not been proved scientifically. Therefore, the present study was designed. Alcoholic extract of the husk of Cocos nucifera was prepared and the antimicrobial properties against common oral pathogens like cariogenic bacteria, periodontal pathogens, and candidal organisms were performed by the Agar Well Diffusion Method. The results obtained were then subjected to statistical analysis using One-Way Analysis of Variance (ANOVA) and the Tukey's Honestly Significant Difference (HSD). The alcoholic extract of Cocos nucifera showed a significant concentration-dependent antimicrobial activity, expressed as a zone of inhibition with respect to all tested organisms except Actinomyces species. The inhibitory effect was more significant, with a majority of cariogenic organisms and Candida, with a zone of inhibition ranging from 4.6 mm to 16.3 mm. However, the effect was lesser with Cocos nucifera compared to chlorhexidine. Minimum inhibitory concentration (MIC) ranged from 50 mg/ml to 75 mg/ml. Cocos nucifera has a significant inhibitory action against common oral pathogens, indicating the presence of highly effective antimicrobial compounds. Therefore, it is proved that its use can contribute to oral health to a great extent. Identification of these active compounds provides the scope for incorporating it into a modern oral care system, so as to control oral diseases.

Development and preliminary verification of the 3D core neutronic code: COCO

DOE Office of Scientific and Technical Information (OSTI.GOV)

Lu, H.; Mo, K.; Li, W.

As the recent blooming economic growth and following environmental concerns (China)) is proactively pushing forward nuclear power development and encouraging the tapping of clean energy. Under this situation, CGNPC, as one of the largest energy enterprises in China, is planning to develop its own nuclear related technology in order to support more and more nuclear plants either under construction or being operation. This paper introduces the recent progress in software development for CGNPC. The focus is placed on the physical models and preliminary verification results during the recent development of the 3D Core Neutronic Code: COCO. In the COCO code,more » the non-linear Green's function method is employed to calculate the neutron flux. In order to use the discontinuity factor, the Neumann (second kind) boundary condition is utilized in the Green's function nodal method. Additionally, the COCO code also includes the necessary physical models, e.g. single-channel thermal-hydraulic module, burnup module, pin power reconstruction module and cross-section interpolation module. The preliminary verification result shows that the COCO code is sufficient for reactor core design and analysis for pressurized water reactor (PWR). (authors)« less

Antimicrobial properties of Cocos nucifera (coconut) husk: An extrapolation to oral health

PubMed Central

Jose, Maji; Cyriac, Maria B; Pai, Vidya; Varghese, Ipe; Shantaram, Manjula

2014-01-01

Background and Objectives: Brushing the teeth with fibrous husk of Cocos nucifera (coconut) is a common oral hygiene practice among people of rural areas of South India. However, the probable antimicrobial properties of this plant material against common oral pathogens have not been proved scientifically. Therefore, the present study was designed. Materials and Methods: Alcoholic extract of the husk of Cocos nucifera was prepared and the antimicrobial properties against common oral pathogens like cariogenic bacteria, periodontal pathogens, and candidal organisms were performed by the Agar Well Diffusion Method. The results obtained were then subjected to statistical analysis using One-Way Analysis of Variance (ANOVA) and the Tukey's Honestly Significant Difference (HSD). Results: The alcoholic extract of Cocos nucifera showed a significant concentration-dependent antimicrobial activity, expressed as a zone of inhibition with respect to all tested organisms except Actinomyces species. The inhibitory effect was more significant, with a majority of cariogenic organisms and Candida, with a zone of inhibition ranging from 4.6 mm to 16.3 mm. However, the effect was lesser with Cocos nucifera compared to chlorhexidine. Minimum inhibitory concentration (MIC) ranged from 50 mg/ml to 75 mg/ml. Conclusion: Cocos nucifera has a significant inhibitory action against common oral pathogens, indicating the presence of highly effective antimicrobial compounds. Therefore, it is proved that its use can contribute to oral health to a great extent. Identification of these active compounds provides the scope for incorporating it into a modern oral care system, so as to control oral diseases. PMID:25097415

An Integrated Age Model for the Cocos Plate using IODP CRISP Drilling Data

NASA Astrophysics Data System (ADS)

Baxter, A. T.; Kutterolf, S.; Schindlbeck, J. C.; Sandoval, M. I.; Barckhausen, U.; Li, Y. X.; Petronotis, K. E.

2017-12-01

We present an integrated age model for the incoming Cocos Plate sediments offshore Costa Rica. The data, collected over two IODP Expeditions (334 and 344), provides a medium- to high-resolution record from the initial formation of the ocean crust in the Miocene to the present day. This study provides >50 age control points for the CRISP sediments from Sites U1381 and U1414. Although the two sites are just 10 km apart, there are distinct differences in the sediment and tephra record. Most notable is the presence of a hiatus at Site U1381. The hiatus, which is seen at other sites on the Cocos Plate, but not at Site U1414, may be related to erosion due to bottom water currents, mass wasting from Cocos Ridge subduction or may be related to the closure of the Central American Seaway (CAS). Sediment accumulation rates in the Miocene are comparable to modern abyssal plain rates. However, an increase is observed in the Pleistocene, when detritus from the forearc basin appears at Site U1414 2 Ma, shortly after the initiation of Cocos Ridge subduction. A tectonic model is presented that reconstructs the Cocos Plate, from its formation at 23 Ma to the present day. Eastern Equatorial Pacific (EEP) paleoceanographic events, such as the Miocene `carbonate crash' and the Late Miocene-Early Pliocene `biogenic bloom' observed at Site U1414, are also discussed.

Molecular mechanism of Poria cocos combined with oxaliplatin on the inhibition of epithelial-mesenchymal transition in gastric cancer cells.

PubMed

Wang, Na; Liu, Dengxiang; Guo, Jun; Sun, Yawei; Guo, Ting; Zhu, Xiaoyan

2018-06-01

Natural product Poria cocos possesses antitumor effect. This study will explore the molecular mechanism of Poria cocos combined with chemotherapy in the inhibition of gastric cancer cell EMT process. The experiment was divided into blank control group, Poria cocos group, oxaliplatin group and Poria cocos combined with oxaliplatin group. Scratch and Transwell assay were used to detect cell migration and invasion respectively. RT-qPCR and Western Blot analyses were used to detect mRNA and protein expression of the epithelial-mesenchymal transition (EMT) related factors including Snail, Twist, Vimentin, E-cadherin and N-cadherin respectively. Morphologic assessment was performed with HPIAS-1000 automated image analysis system. The migration and invasion abilities of gastric cancer cells in the Poria cocos combined with oxaliplatin group were significantly decreased (P < 0.01). The mRNA and protein expression of Snail, Twist, Vimentin and N-cadherin were significantly decreased while the mRNA and protein expression of E-cadherin were significantly increased (P < 0.01) compared with blank control group. Nude mice model of gastric cancer was successfully established. Poria cocos combined with oxaliplatin could significantly inhibit gastric tumor progression. The expression of EMT related factors were consistent with in vitro study. Morphologic assessment showed that the nucleus area, perimeter, mean diameter, volume, long diameter and shape factor in the Poria cocos combined with oxaliplatin group were significantly different compared with the blank control group (P < 0.01) but not significantly different compared with the normal control. Poria cocos combined with oxaliplatin could significantly inhibit the migration and invasion of gastric cancer cells. Through both in vitro and in vivo studies, it is confirmed that Poria cocos combined with oxaliplatin could significantly inhibit the EMT process of gastric cancer. Poria cocos combined with oxaliplatin could

[Study on UPLC-UV-MS fingerprints of different medicinal parts of Poria cocos].

PubMed

Li, Ke; Zhang, Li-Qun; Nie, Jing

2013-03-01

To establish an analytical method for the fingerprint of triterpenoid constituents of Poria cocos by UPLC-UV-MS and compare the fingerprints of different medicinal parts of Poria cocos. With dehydropachymic acid as reference substance, the separation was performed on Shim-pack XR-ODS II (75 mm x 2.0 mm, 2.2 microm) analytical column. The mobile phase was consisted of acetonitrile and 0.1% formic acid as gradient eluent. The UV detection wavelength was 242 nm. The flow rate was 0.5 mL/min. The column temperature was 30 degrees C. The cluster analysis was carried on by SPSS 16. 0. The UPLC-UV-MS fingerprints of triterpenoid constituents of Poria cocos were set up. The result showed that 22 peaks were found in different medicinal parts and 12 peaks of them were common. The results of method validation met technical requirement of fingerprints; Triterpenoid constituents in pared skin of Poria and peeled and sliced Poria were different, and the effect of habitat on the quality of peeled and sliced Poria was more obvious than that of pared skin of Poria. The method is stable and reliable with a good reproducibility and provides a reference standard for the quality control of Poria cocos.

40 CFR 721.10193 - 1-Butanaminium, N-(3-aminopropyl)-N-butyl-N-(2-carboxyethyl)-, N-coco acyl derivs., inner salts.

Code of Federal Regulations, 2011 CFR

2011-07-01

...-butyl-N-(2-carboxyethyl)-, N-coco acyl derivs., inner salts. 721.10193 Section 721.10193 Protection of...-aminopropyl)-N-butyl-N-(2-carboxyethyl)-, N-coco acyl derivs., inner salts. (a) Chemical substance and...-aminopropyl)-N-butyl-N-(2-carboxyethyl)-, N-coco acyl derivs., inner salts (PMN P-06-263, Chemical B; CAS No...

Biological activities and potential health benefits of polysaccharides from Poria cocos and their derivatives.

PubMed

Sun, Yichun

2014-07-01

Poria cocos has a long history of medicinal use in Asian countries such as China, Japan, Korea and Thailand. It is a kind of edible and pharmaceutical mushroom. The chemical compositions of Poria cocos mainly include triterpenes, polysaccharides, steroids, amino acids, choline, histidine, etc. Great advances have been made in chemical and bioactive studies on Poria cocos polysaccharides (PCP) and their derivatives in recent decades. These PCP and their derivatives exhibit many beneficial biological activities including anticancer, anti-inflammatory, antioxidant and antiviral activities. Therefore, PCP and their derivatives have great potential for further development as therapy or adjuvant therapy for cancer, immune-modulatory and antiviral drugs. This paper presents an overview of biological activities and potential health benefits of PCP and their derivatives. Copyright © 2014 Elsevier B.V. All rights reserved.

Geometry of the Cocos Plate Under North American Plate

NASA Astrophysics Data System (ADS)

Perez-Campos, X.

2015-12-01

The Cocos plate subducts under the North American plate with a complex geometry, and previous seismicity studies revealed some of this complexity. However, details of the geometry and the depth that the plate penetrates werelargely unknown. Since 2004, temporary experiments and the expansion of the permanent network of the Servicio Sismológico Nacional (SSN, Mexican National Seismological Service) have improved resolution of the plate geometry and have helped to map its descent into the upper mantle. Going from northwest to southeast, the Cocos plate appears to be fragmenting into north and south segments. The north segment subducts with an angle of ~30º and the south with an angle of ~10-15º. The transition is smooth near the trench and progresses to a tear at depth; this coincides with the projection of the Orozco Fracture Zone to depth. Also, this transition marks the limit of the presence to the south of an ultra slow velocity layer (USL) on top of the slab.South of this transition, the Cocos plate subducts horizontally , underplating the North American plate for a distance of ~140 to ~300 km from the trench. Along this horizontal region, silent slow events (SSE) and tectonic tremor (TT) have been observed. At a distance of 300 km from the trench (beneath central Mexico), the plate dives into the mantle with an angle of 76º to a depth of 500 km. This geometry changes abruptly to the south, marking the eastern limit of the USL. This change seems to be also characterized by a tear on the slab. Finally to the south, the Cocos plate subducts with a constant angle of 26º. This presentation summarizes the work of many contributors including A. Arciniega-Ceballos, M. Brudzinski, E. Cabral-Cano, T. Chen, R. Clayton,F. Cordoba-Montiel,P. Davis,S. Dougherty,F. Green, M. Gurnis, D. V. Helmberger, A. Husker,A. Iglesias, Y. Kim, V. Manea, D. Melgar, M. Rodríguez-Domínguez,S. K. Singh, T.-R. A. Song, C. M. Valdés-González, D. Valencia-Cabrera

Heterogeneous epoxide carbonylation by cooperative ion-pair catalysis in Co(CO) 4 –-incorporated Cr-MIL-101

DOE Office of Scientific and Technical Information (OSTI.GOV)

Park, Hoyoung D.; Dinca, Mircea; Roman-Leshkov, Yuriy

Here, despite the commercial desirability of epoxide carbonylation to β-lactones, the reliance of this process on homogeneous catalysts makes its industrial application challenging. Here we report the preparation and use of a Co(CO) 4 –-incorporated Cr-MIL-101 (Co(CO) 4cCr-MIL-101, Cr-MIL-101 = Cr 3O(BDC) 3F, H2BDC = 1,4-benzenedicarboxylic acid) heterogeneous catalyst for the ring-expansion carbonylation of epoxides, whose activity, selectivity, and substrate scope are on par with those of the reported homogeneous catalysts. We ascribe the observed performance to the unique cooperativity between the postsynthetically introduced Co(CO) 4 – and the site-isolated Lewis acidic Cr(III) centers in the metal–organic framework (MOF). Themore » heterogeneous nature of Co(CO) 4cCr-MIL-101 allows the first demonstration of gas-phase continuous-flow production of β-lactones from epoxides, attesting to the potential applicability of the heterogeneous epoxide carbonylation strategy.« less

Heterogeneous epoxide carbonylation by cooperative ion-pair catalysis in Co(CO) 4 –-incorporated Cr-MIL-101

DOE PAGES

Park, Hoyoung D.; Dinca, Mircea; Roman-Leshkov, Yuriy

2017-03-21

Here, despite the commercial desirability of epoxide carbonylation to β-lactones, the reliance of this process on homogeneous catalysts makes its industrial application challenging. Here we report the preparation and use of a Co(CO) 4 –-incorporated Cr-MIL-101 (Co(CO) 4cCr-MIL-101, Cr-MIL-101 = Cr 3O(BDC) 3F, H2BDC = 1,4-benzenedicarboxylic acid) heterogeneous catalyst for the ring-expansion carbonylation of epoxides, whose activity, selectivity, and substrate scope are on par with those of the reported homogeneous catalysts. We ascribe the observed performance to the unique cooperativity between the postsynthetically introduced Co(CO) 4 – and the site-isolated Lewis acidic Cr(III) centers in the metal–organic framework (MOF). Themore » heterogeneous nature of Co(CO) 4cCr-MIL-101 allows the first demonstration of gas-phase continuous-flow production of β-lactones from epoxides, attesting to the potential applicability of the heterogeneous epoxide carbonylation strategy.« less

Three-dimensional Numerical Models of the Cocos-northern Nazca Slab Gap

NASA Astrophysics Data System (ADS)

Jadamec, M.; Fischer, K. M.

2012-12-01

In contrast to anisotropy beneath the middle of oceanic plates, seismic observations in subduction zones often indicate mantle flow patterns that are not easily explained by simple coupling of the subducting and overriding plates to the mantle. For example, in the Costa Rica-Nicaragua subduction zone local S shear wave splitting measurements combined with geochemical data indicate trench parallel flow in the mantle wedge with flow rates of 6.3-19 cm/yr, which is on order of or may be up to twice the subducting plate velocity. We construct geographically referenced high-resolution three-dimensional (3D) geodynamic models of the Cocos-northern Nazca subduction system to investigate what is driving the northwest directed, and apparently rapid, trench-parallel flow in the mantle wedge beneath Costa Rica-Nicaragua. We use the SlabGenerator code to construct a 3D plate configuration that is used as input to the community mantle convection code, CitcomCU. Models are run on over 400 CPUs on XSEDE, with a mesh resolution of up to 3 km at the plate boundary. Seismicity and seismic tomography delineate the shape and depth of the Cocos and northern Nazca slabs. The subducting plate thermal structure is based on a plate cooling model and ages from the seafloor age grid. Overriding plate thickness is constrained by the ages from the sea floor age grid where available and the depth to the lithosphere-asthenosphere boundary from the greatest negative gradient in absolute shear wave velocity. The geodynamic models test the relative controls of the change in the dip of the Cocos plate and the slab gap between the Cocos and northern Nazca plates in driving the mantle flow beneath Central America. The models also investigate the effect of a non-Newtonian rheology in dynamically generating a low viscosity mantle wedge and how this controls mantle flow rates. To what extent the Cocos-northern Nazca slab gap channelizes mantle flow between Central and South America has direct application

RNA-Seq Analysis of Cocos nucifera: Transcriptome Sequencing and De Novo Assembly for Subsequent Functional Genomics Approaches

PubMed Central

Xia, Wei; Mason, Annaliese S.; Xia, Zhihui; Qiao, Fei; Zhao, Songlin; Tang, Haoru

2013-01-01

Background Cocos nucifera (coconut), a member of the Arecaceae family, is an economically important woody palm grown in tropical regions. Despite its agronomic importance, previous germplasm assessment studies have relied solely on morphological and agronomical traits. Molecular biology techniques have been scarcely used in assessment of genetic resources and for improvement of important agronomic and quality traits in Cocos nucifera, mostly due to the absence of available sequence information. Methodology/Principal Findings To provide basic information for molecular breeding and further molecular biological analysis in Cocos nucifera, we applied RNA-seq technology and de novo assembly to gain a global overview of the Cocos nucifera transcriptome from mixed tissue samples. Using Illumina sequencing, we obtained 54.9 million short reads and conducted de novo assembly to obtain 57,304 unigenes with an average length of 752 base pairs. Sequence comparison between assembled unigenes and released cDNA sequences of Cocos nucifera and Elaeis guineensis indicated that the assembled sequences were of high quality. Approximately 99.9% of unigenes were novel compared to the released coconut EST sequences. Using BLASTX, 68.2% of unigenes were successfully annotated based on the Genbank non-redundant (Nr) protein database. The annotated unigenes were then further classified using the Gene Ontology (GO), Clusters of Orthologous Groups (COG) and Kyoto Encyclopedia of Genes and Genomes (KEGG) databases. Conclusions/Significance Our study provides a large quantity of novel genetic information for Cocos nucifera. This information will act as a valuable resource for further molecular genetic studies and breeding in coconut, as well as for isolation and characterization of functional genes involved in different biochemical pathways in this important tropical crop species. PMID:23555859

RNA-Seq analysis of Cocos nucifera: transcriptome sequencing and de novo assembly for subsequent functional genomics approaches.

PubMed

Fan, Haikuo; Xiao, Yong; Yang, Yaodong; Xia, Wei; Mason, Annaliese S; Xia, Zhihui; Qiao, Fei; Zhao, Songlin; Tang, Haoru

2013-01-01

Cocos nucifera (coconut), a member of the Arecaceae family, is an economically important woody palm grown in tropical regions. Despite its agronomic importance, previous germplasm assessment studies have relied solely on morphological and agronomical traits. Molecular biology techniques have been scarcely used in assessment of genetic resources and for improvement of important agronomic and quality traits in Cocos nucifera, mostly due to the absence of available sequence information. To provide basic information for molecular breeding and further molecular biological analysis in Cocos nucifera, we applied RNA-seq technology and de novo assembly to gain a global overview of the Cocos nucifera transcriptome from mixed tissue samples. Using Illumina sequencing, we obtained 54.9 million short reads and conducted de novo assembly to obtain 57,304 unigenes with an average length of 752 base pairs. Sequence comparison between assembled unigenes and released cDNA sequences of Cocos nucifera and Elaeis guineensis indicated that the assembled sequences were of high quality. Approximately 99.9% of unigenes were novel compared to the released coconut EST sequences. Using BLASTX, 68.2% of unigenes were successfully annotated based on the Genbank non-redundant (Nr) protein database. The annotated unigenes were then further classified using the Gene Ontology (GO), Clusters of Orthologous Groups (COG) and Kyoto Encyclopedia of Genes and Genomes (KEGG) databases. Our study provides a large quantity of novel genetic information for Cocos nucifera. This information will act as a valuable resource for further molecular genetic studies and breeding in coconut, as well as for isolation and characterization of functional genes involved in different biochemical pathways in this important tropical crop species.

GPS measurement of relative motion of the Cocos and Caribbean Plates and strain accumulation across the Middle America Trench

NASA Astrophysics Data System (ADS)

Dixon, Timothy H.

1993-10-01

Global Positioning System (GPS) measurements in 1988 and 1991 on Cocos Island (Cocos plate), San Andres Island (Caribbean plate), and Liberia (Caribbean plate, mainland Costa Rica) provide an estimate of relative motion between the Cocos and Caribbean plates. The data for Cocos and San Andres Islands, both located more than 400 km from the Middle America Trench, define a velocity that is equivalent within two standard errors (7 mm/yr rate, 5 degrees azimuth) to the NUVEL-1 plate motion model. The data for Liberia, 120 km from the trench, define a velocity that is similar in azimuth but substantially different in rate from NUVEL-1. The discrepancy can be explained with a simple model of elastic strain accumulation with a subduction zone that is locked to a relatively shallow (20±5 km) depth.

The crustal structure of the Cocos ridge off Costa Rica

NASA Astrophysics Data System (ADS)

Walther, Christian H. E.

2003-03-01

The submarine Cocos ridge in the northwestern Panamá basin, a bathymetric feature more than 1000-km long and 250-500 km broad, is about 2 km shallower than the adjacent basin. It is generally interpreted as the trace of the Galápagos hot spot. Two 127- and 260-km long seismic wide-angle sections were recorded along and across this ridge, offshore the Osa peninsula, Costa Rica. Crustal thickening is seen everywhere along the sections. On the northwestern outer ridge flank, increased thickness is exclusively attributed to the upper crust and expressed by 2-km thick flow basalts. The Quepos plateau caps the upper crust in this area. Toward the center of the Cocos ridge, the Moho deepens from 11-12 to 21 km depth and crustal thickening is almost entirely attributed to the lower crust which makes up 80% of the crust and is three times the thickness of normal oceanic lower crust. It is homogeneously structured and the velocities which range from 6.5 km/s at the top to 7.35 km/s at the base are comparable to normal lower crust under these depth conditions and suggest no differences to a gabbroic rock composition. Similarities to the crustal velocity structure of Iceland, central Kerguelen plateau, and Broken ridge are consistent with a formation of this 13-15 Ma old Cocos ridge segment by excessive magmatism in a near-plate boundary setting.

Electron-Induced Chemistry of Cobalt Tricarbonyl Nitrosyl (Co(CO)3NO) in Liquid Helium Nanodroplets

PubMed Central

2015-01-01

Electron addition to cobalt tricarbonyl nitrosyl (Co(CO3NO) and its clusters has been explored in helium nanodroplets. Anions were formed by adding electrons with controlled energies, and reaction products were identified by mass spectrometry. Dissociative electron attachment (DEA) to the Co(CO)3NO monomer gave reaction products similar to those reported in earlier gas phase experiments. However, loss of NO was more prevalent than loss of CO, in marked contrast to the gas phase. Since the Co–N bond is significantly stronger than the Co–C bond, this preference for NO loss must be driven by selective reaction dynamics at low temperature. For [Co(CO)3NO]N clusters, the DEA chemistry is similar to that of the monomer, but the anion yields as a function of electron energy show large differences, with the relatively sharp resonances of the monomer being replaced by broad profiles peaking at much higher electron energies. A third experiment involved DEA of Co(CO)3NO on a C60 molecule in an attempt to simulate the effect of a surface. Once again, broad ion yield curves are seen, but CO loss now becomes the most probable reaction channel. The implication of these findings for understanding focused electron beam induced deposition of cobalt is described. PMID:26401190

Poria cocos Wolf extracts represses pigmentation in vitro and in vivo.

PubMed

Lee, HyunKyung; Cha, Hwa Jun

2018-04-30

In skin, melanocytes determine skin color using melanogenesis, which induces protective mechanism to oxidative stress and UV damage. However, when melanin is excessive produced by the various stimulus, the accumulated melanin induces hyperpigmentation disease such as melasma, freckles, Melanism ware induced. Therefore, it is implicated to finding potential agents for whitening to be used in cosmetic products. In our present study, we show that Poria cocos Wolf extracts decreased melanin synthesis in B16F10. And then this inhibition of melanogenesis was provoked by regulation of tyrosinase activity and tyrosinase and MITF expression. Moreover, Poria cocos Wolf extracts contained cream improved skin tone using increase of bright value. Overall, these results provide evidence to potential agent for whitening to be used in cosmetic products.

Fluid inclusion petrology and microthermometry of the Cocos Ridge hydrothermal system, IODP Expedition 344 (CRISP 2), Site U1414.

PubMed

Brandstätter, Jennifer; Kurz, Walter; Krenn, Kurt; Micheuz, Peter

2016-04-01

In this study, we present new data from microthermometry of fluid inclusions entrapped in hydrothermal veins along the Cocos Ridge from the IODP Expedition 344 Site U1414. The results of our study concern a primary task of IODP Expedition 344 to evaluate fluid/rock interaction linked with the tectonic evolution of the incoming Cocos Plate from the Early Miocene up to recent times. Aqueous, low saline fluids are concentrated within veins from both the Cocos Ridge basalt and the overlying lithified sediments of Unit III. Mineralization and crosscutting relationships give constraints for different vein generations. Isochores from primary, reequilibrated, and secondary fluid inclusions crossed with litho/hydrostatic pressures indicate an anticlockwise PT evolution during vein precipitation and modification by isobaric heating and subsequent cooling at pressures between ∼210 and 350 bar. Internal over and underpressures in the inclusions enabled decrepitation and reequilibration of early inclusions but also modification of vein generations in the Cocos Ridge basalt and in the lithified sediments. We propose that lithification of the sediments was accompanied with a first stage of vein development (VU1 and VC1) that resulted from Galapagos hotspot activity in the Middle Miocene. Heat advection, either related to the Cocos-Nazca spreading center or to hotspot activity closer to the Middle America Trench, led to subsequent vein modification (VC2, VU2/3) related to isobaric heating. The latest mineralization (VC3, VU3) within aragonite and calcite veins and some vesicles of the Cocos Ridge basalt occurred during crustal cooling up to recent times. Fluid inclusion analyses and published isotope data show evidence for communication with deeper sourced, high-temperature hydrothermal fluids within the Cocos Plate. The fluid source of the hydrothermal veins reflects aqueous low saline pore water mixed with invaded seawater.

Coco Nut Meets the Gadget Maker. Volume 1.

ERIC Educational Resources Information Center

Thomson, P.

The adventures of Coco Nut, a coconut which has fallen from a palm tree in Florida, are illustrated in this booklet for elementary school students. His fall into a canal and ensuing encounters with dead and alive fish and a gadget maker (industry) are used to portray the effects of water pollution. What man can do to stop such pollution and…

Antinociceptive and free radical scavenging activities of Cocos nucifera L. (Palmae) husk fiber aqueous extract.

PubMed

Alviano, Daniela S; Rodrigues, Karen F; Leitão, Suzana G; Rodrigues, Marcio L; Matheus, Maria Eline; Fernandes, Patrícia D; Antoniolli, Angelo R; Alviano, Celuta S

2004-06-01

In the current study, the analgesic and free radical scavenging properties of an aqueous extract from the husk fiber of Cocos nucifera L. (Palmae) were demonstrated by the use of in vivo and in vitro models. The orally administered Cocos nucifera aqueous extract (200 or 400 mg/kg) inhibited the acetic acid-induced writhing response in mice. Tail flick and hot plate assays demonstrated that treatment of animals with this plant extract at 200 mg/kg induced attenuation in the response to a heat stimulus. A LD(50) of 2.30 g/kg was obtained in acute toxicity tests. Topic treatment of rabbits with the Cocos nucifera extract indicated that it does not induce any significant dermic or ocular irritation. In vitro experiments using the 2,2-diphenyl-1-picryl-hydrazyl-hydrate (DPPH) photometric assay demonstrated that this plant extract also possesses free radical scavenging properties.

Co@Co3O4 nanoparticle embedded nitrogen-doped carbon architectures as efficient bicatalysts for oxygen reduction and evolution reactions

NASA Astrophysics Data System (ADS)

Qi, Chunling; Zhang, Li; Xu, Guancheng; Sun, Zhipeng; Zhao, Aihua; Jia, Dianzeng

2018-01-01

The oxygen reduction reaction (ORR) and oxygen evolution reaction (OER) play crucial roles in efficient energy conversion and storage solutions. Here, Co@Co3O4 nanoparticle embedded nitrogen-doped carbon architectures (denoted as Co@Co3O4/NCs) are prepared via a simple two-step and in situ approach by carbonization and subsequent oxidation of Co-MOF containing high contents of carbon and nitrogen. When evaluated as electrocatalyst towards both ORR and OER in a KOH electrolyte solution, the as-fabricated Co@Co3O4/NC-2 exhibits similar ORR catalytic activity to the commercial Pt/C catalyst, but superior stability and good methanol tolerance. Furthermore, the as-fabricated catalysts also show promising catalytic activity for OER. The effective catalytic activities originate from the synergistic effects between well wrapped Co@Co3O4 nanoparticles and nitrogen doped carbon structures.

A new estimate for present-day Cocos-Caribbean Plate motion: Implications for slip along the Central American Volcanic Arc

NASA Astrophysics Data System (ADS)

DeMets, Charles

Velocities from 153 continuously-operating GPS sites on the Caribbean, North American, and Pacific plates are combined with 61 newly estimated Pacific-Cocos seafloor spreading rates and additional marine geophysical data to derive a new estimate of present-day Cocos-Caribbean plate motion. A comparison of the predicted Cocos-Caribbean direction to slip directions of numerous shallow-thrust subduction earthquakes from the Middle America trench between Costa Rica and Guatemala shows the slip directions to be deflected 10° clockwise from the plate convergence direction, supporting the hypothesis that frequent dextral strike-slip earthquakes along the Central American volcanic arc result from partitioning of oblique Cocos-Caribbean plate convergence. Linear velocity analysis for forearc locations in Nicaragua and Guatemala predicts 14±2 mm yr-1 of northwestward trench-parallel slip of the forearc relative to the Caribbean plate, possibly decreasing in magnitude in El Salvador and Guatemala, where extension east of the volcanic arc complicates the tectonic setting.

Indoor cultivation and cultural characteristics of Wolfiporia cocos sclerotia using mushroom culture bottles.

PubMed

Kubo, Toshiyuki; Terabayashi, Susumu; Takeda, Shuichi; Sasaki, Hiroshi; Aburada, Masaki; Miyamoto, Ken-ichi

2006-06-01

We newly developed an indoor cultivation technique for Wolfiporia cocos (Wolf) Ryvarden et Gilbertson (Syn. Poria cocos Wolf), not with soil, but using mushroom culture bottles with pine logs, and clarified some cultural characteristics of sclerotia in the laboratory. To determine the optimum conditions for sclerotia growth, the weight of sclerotia and concentration of CO2 in three different air filters; cloth, paper and urethane resin, and closed bottles were tested. When the cloth air filter was used, the growth rate was the fastest and the yield was maximal. These results suggested that the aeration was an important environmental factor for cultivation. To clarify the characteristics of culture in the cloth air filtered and closed bottles, the weight of sclerotia, the compositions of pine logs and the contents of pachymic acid and dehydropachymic acid were examined during 24 weeks. The growth of scleroia and the wood decaying efficiency in the cloth air filtered bottles were better than those in the closed bottles. Also, it was found that W. cocos was a brown rot fungus due to the alkaline solubility of pine logs in the wood decay process. In addition, the contents of pachymic acid and dehydropachymic acid and the TLC pattern between the cultivated and commercial sclerotia did not differ remarkably.

Fluid inclusion petrology and microthermometry of the Cocos Ridge hydrothermal system, IODP Expedition 344 (CRISP 2), Site U1414

PubMed Central

Brandstätter, Jennifer; Krenn, Kurt; Micheuz, Peter

2016-01-01

Abstract In this study, we present new data from microthermometry of fluid inclusions entrapped in hydrothermal veins along the Cocos Ridge from the IODP Expedition 344 Site U1414. The results of our study concern a primary task of IODP Expedition 344 to evaluate fluid/rock interaction linked with the tectonic evolution of the incoming Cocos Plate from the Early Miocene up to recent times. Aqueous, low saline fluids are concentrated within veins from both the Cocos Ridge basalt and the overlying lithified sediments of Unit III. Mineralization and crosscutting relationships give constraints for different vein generations. Isochores from primary, reequilibrated, and secondary fluid inclusions crossed with litho/hydrostatic pressures indicate an anticlockwise PT evolution during vein precipitation and modification by isobaric heating and subsequent cooling at pressures between ∼210 and 350 bar. Internal over and underpressures in the inclusions enabled decrepitation and reequilibration of early inclusions but also modification of vein generations in the Cocos Ridge basalt and in the lithified sediments. We propose that lithification of the sediments was accompanied with a first stage of vein development (VU1 and VC1) that resulted from Galapagos hotspot activity in the Middle Miocene. Heat advection, either related to the Cocos‐Nazca spreading center or to hotspot activity closer to the Middle America Trench, led to subsequent vein modification (VC2, VU2/3) related to isobaric heating. The latest mineralization (VC3, VU3) within aragonite and calcite veins and some vesicles of the Cocos Ridge basalt occurred during crustal cooling up to recent times. Fluid inclusion analyses and published isotope data show evidence for communication with deeper sourced, high‐temperature hydrothermal fluids within the Cocos Plate. The fluid source of the hydrothermal veins reflects aqueous low saline pore water mixed with invaded seawater. PMID:27570496

Cytoprotective, antihyperglycemic and phytochemical properties of Cocos nucifera (L.) inflorescence.

PubMed

Renjith, R S; Chikku, A M; Rajamohan, T

2013-10-01

To analyze the cytoprotective and antidiabetic activities as well as phytochemical composition of the immature inflorescence of Cocos nucifera belonging to the Arecaceae Family. The phytochemical screening of inflorescence was done to determine the major constituents present in Cocos nucifera inflorescence. The free radical scavenging potential of inflorescence extracts were evaluated using in vitro radical scavenging assay models. The phytochemical analyses on inflorescence showed the presence of phenolic compounds, flavonoids, resins and alkaloids. The macronutrient analyses, on the other hand, showed the presence of carbohydrate, proteins and fibers. Administration of the methanol extract of coconut inflorescence to the diabetic rats showed dose dependent reduction in hyperglycemia. The cytoprotective property of coconut inflorescence was evidenced from the acute toxicological evaluation. The levels of serum aspartate aminotransferase, alanine aminotransferase, and alkaline phosphatase were significantly decreased in the diabetic rats treated with inflorescence when compared with the diabetic control rats. The results obtained from the present study apparently proved the non-toxic nature and the cytoprotective and antihyperglycemic properties of coconut inflorescence. Copyright © 2013 Hainan Medical College. Published by Elsevier B.V. All rights reserved.

Evaluation of the antiplasmodial and cytotoxicity potentials of husk fiber extracts from Cocos nucifera, a medicinal plant used in Nigeria to treat human malaria.

PubMed

Adebayo, J O; Santana, A E G; Krettli, A U

2012-03-01

Nigeria is an African country where transmission of malaria occurs all year round and where most inhabitants use plants as remedies against parasitic diseases, including malaria. Some of such medicinal plants have their antimalarial efficacies already demonstrated experimentally, active compounds isolated and the mechanism of drug action suggested. Decoction of Cocos nucifera husk is used in the middle belt region of Nigeria as an antimalarial remedy. In our current studies, we tested extracts from husks of four varieties of C. nucifera, all collected in Brazil, where the plant fruit is popularly named 'coco'. The husks of coco mestiço, amarelo, anão and gigante collected in the Northeast of Brazil were used to prepare extracts at the Chemistry Department, Federal University of Alagoas (UFAL), which were then tested for their antiplasmodial activities, cytotoxicities and hemolytic activities in vitro. Only the hexane extract of coco mestiço was active against the blood forms of Plasmodium falciparum human malaria parasite maintained in continuous culture. Most extracts presented selectivity indices of <10, while hexane extract of coco mestiço had a selectivity index of 35, meaning that the extract is not toxic. The isolation of the active compounds from coco mestiço husks has not yet been done.

Co@Co3 O4 @PPD Core@bishell Nanoparticle-Based Composite as an Efficient Electrocatalyst for Oxygen Reduction Reaction.

PubMed

Wang, Zhijuan; Li, Bing; Ge, Xiaoming; Goh, F W Thomas; Zhang, Xiao; Du, Guojun; Wuu, Delvin; Liu, Zhaolin; Andy Hor, T S; Zhang, Hua; Zong, Yun

2016-05-01

Durable electrocatalysts with high catalytic activity toward oxygen reduction reaction (ORR) are crucial to high-performance primary zinc-air batteries (ZnABs) and direct methanol fuel cells (DMFCs). An efficient composite electrocatalyst, Co@Co3 O4 core@shell nanoparticles (NPs) embedded in pyrolyzed polydopamine (PPD) is reported, i.e., in Co@Co3 O4 @PPD core@bishell structure, obtained via a three-step sequential process involving hydrothermal synthesis, high temperature calcination under nitrogen atmosphere, and gentle heating in air. With Co@Co3 O4 NPs encapsulated by ultrathin highly graphitized N-doped carbon, the catalyst exhibits excellent stability in aqueous alkaline solution over extended period and good tolerance to methanol crossover effect. The integration of N-doped graphitic carbon outer shell and ultrathin nanocrystalline Co3 O4 inner shell enable high ORR activity of the core@bishell NPs, as evidenced by ZnABs using catalyst of Co@Co3 O4 @PPD in air-cathode which delivers a stable voltage profile over 40 h at a discharge current density of as high as 20 mA cm(-2) . © 2016 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

40 CFR 721.2086 - Coco acid triamine condensate, polycarboxylic acid salts.

Code of Federal Regulations, 2010 CFR

2010-07-01

... 40 Protection of Environment 30 2010-07-01 2010-07-01 false Coco acid triamine condensate, polycarboxylic acid salts. 721.2086 Section 721.2086 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) TOXIC SUBSTANCES CONTROL ACT SIGNIFICANT NEW USES OF CHEMICAL SUBSTANCES Significant New Uses for Specific Chemical Substances §...

Fluid inclusion petrography and microthermometry of the Cocos Ridge hydrothermal system, IODP Expedition 344 (CRISP 2), Site U1414

NASA Astrophysics Data System (ADS)

Brandstätter, J.; Kurz, W.; Krenn, K.; Micheuz, P.

2015-12-01

We present new data from microthermometric analyses of fluid inclusions entrapped in hydrothermal veins within lithified sediments and Cocos Ridge (CCR) basalt from IODP Expedition 344 site U1414 (Costa Rica) and concern on a primary task of Expedition 344, i.e. to evaluate fluid/rock interaction, the hydrologic system, and the geochemical processes (indicated by composition and volume of fluids) active within the incoming Cocos Plate. Mineralization of the veins and crosscutting relationships gives constraints for the different generation of veins. Calcium carbonate, commonly aragonite in the upper part and calcite in the lower part of the igneous basement, is usually present in veins as a late phase following the quartz precipitation and the clay minerals formation. The sequence of vein generations in the lithified sediments close to the contact within the CCR basalt is characterized by smaller veins filled by quartz, followed by massive intersecting calcite veins. A high fluid pressure can be concluded, due to wall rock fragments embedded within the filling and fractured mineral grains in the ground mass, which are close to the veins. This requires that the magmatic basement and the lithified sediments were covered by sequences of low permeability sediments forming a barrier that enabled build up elevated fluid pressure. The investigation of fluid inclusions in the lowest units of borehole 344-U1414, give clues about the source of the fluids and about the vein evolution within the incoming Cocos Plate close to Middle American Trench. The microthermometric analyses of the primary, almost aqueous, inclusions indicate a temperature range during entrapment between 200 and 420°C. The data indicate that seawater within the Cocos Ridge aquifer communicated with high-temperature fluids and/or were modified by heat advection. We consider the Galapagos hotspot and/ or the Cocos-Nazca spreading center as heat source. Fluids originated from mobilized sediment pore water

The Malpelo Plate Hypothesis and implications for nonclosure of the Cocos-Nazca-Pacific plate motion circuit

NASA Astrophysics Data System (ADS)

Zhang, Tuo; Gordon, Richard G.; Mishra, Jay K.; Wang, Chengzu

2017-08-01

Using global multiresolution topography, we estimate new transform-fault azimuths along the Cocos-Nazca plate boundary and show that the direction of relative plate motion is 3.3° ± 1.8° (95% confidence limits) clockwise of prior estimates. The new direction of Cocos-Nazca plate motion is, moreover, 4.9° ± 2.7° (95% confidence limits) clockwise of the azimuth of the Panama transform fault. We infer that the plate east of the Panama transform fault is not the Nazca plate but instead is a microplate that we term the Malpelo plate. With the improved transform-fault data, the nonclosure of the Nazca-Cocos-Pacific plate motion circuit is reduced from 15.0 mm a-1 ± 3.8 mm a-1 to 11.6 mm a-1 ± 3.8 mm a-1 (95% confidence limits). The nonclosure seems too large to be due entirely to horizontal thermal contraction of oceanic lithosphere and suggests that one or more additional plate boundaries remain to be discovered.

The Effects of Aseismic Ridge Collision on Upper Plate Deformation: Cocos Ridge Collision and Deformation of the Western Caribbean

NASA Astrophysics Data System (ADS)

La Femina, P. C.; Govers, R. M. A.; Ruiz, G.; Geirsson, H.; Camacho, E.; Mora-Paez, H.

2015-12-01

The collision of the Panamanian isthmus with northwestern South America is thought to have initiated as early as Oligocene - Miocene time (23-25 Ma) based on geologic and geophysical data and paleogeographic reconstructions. This collision was driven by eastward-directed subduction beneath northwestern South America. Cocos - Caribbean convergence along the Middle America Trench, and Nazca - Caribbean oblique convergence along the South Panama Deformed Belt have resulted in complex deformation of the southwestern Caribbean since Miocene - Pliocene time. Subduction and collision of the aseismic Cocos Ridge is thought to have initiated <3.5 Ma and has been linked to: 1) late Miocene-Pliocene cessation of volcanism and uplift of the Cordillera de Talamanca, Costa Rica; 2) Quaternary migration of the volcanic arc toward the back-arc in Costa Rica; 3) Quaternary to present deformation within the Central Costa Rica Deformed Belt; 4) Quaternary to present shortening across the fore-arc Fila Costeña fold and thrust belt and back-arc North Panama Deformed Belt (NPDB); 5) Quaternary to present outer fore-arc uplift of Nicoya Peninsula above the seamount domain, and the Osa and Burica peninsulas above the ridge; and 6) Pleistocene to present northwestward motion of the Central American Fore Arc (CAFA) and northeastward motion of the Panama Region. We investigate the geodynamic effects of Cocos Ridge collision on motion of the Panama Region with a new geodynamic model. The model is compared to a new 1993-2015 GPS-derived three-dimensional velocity field for the western Caribbean and northwestern South America. Specifically, we test the hypotheses that the Cocos Ridge is the main driver for upper plate deformation in the western Caribbean. Our models indicate that Cocos Ridge collision drives northwest-directed motion of the CAFA and the northeast-directed motion of the Panama Region. The Panama Region is driven into the Caribbean across the NPDB and into northwestern South

Eco-Efficient Synthesis of Highly Porous CoCO3 Anodes from Supercritical CO2 for Li+ and Na+ Storage.

PubMed

Li, Hui-Ying; Tseng, Chuan-Ming; Yang, Cheng-Hsien; Lee, Tai-Chou; Su, Ching-Yuan; Hsieh, Chien-Te; Chang, Jeng-Kuei

2017-06-09

An eco-efficient synthetic route for the preparation of high-performance carbonate anodes for Li + and Na + batteries is developed. With supercritical CO 2 (scCO 2 ) as the precursor, which has gas-like diffusivity, extremely low viscosity, and near-zero surface tension, CoCO 3 particles are uniformly formed and tightly connected on graphene nanosheets (GNSs). This synthesis can be conducted at 50 °C, which is considerably lower than the temperature required for conventional preparation methods, minimizing energy consumption. The obtained CoCO 3 particles (ca. 20 nm in diameter), which have a unique interpenetrating porous structure, can increase the number of electroactive sites, promote electrolyte accessibility, shorten ion diffusion length, and readily accommodate the strain generated upon charging/discharging. With a reversible capacity of 1105 mAh g -1 , the proposed CoCO 3 /GNS anode shows an excellent rate capability, as it can deliver 745 mAh g -1 in 7.5 min. More than 98 % of the initial capacity is retained after 200 cycles. These properties are clearly superior to those of previously reported CoCO 3 -based electrodes for Li + storage, indicating the merit of our scCO 2 -based synthesis, which is facile, green, and can be easily scaled up for mass production. © 2017 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.

The Malpelo Plate Hypothesis and Implications for Non-closure of the Cocos-Nazca-Pacific Plate Motion Circuit

NASA Astrophysics Data System (ADS)

Zhang, T.; Gordon, R. G.; Mishra, J. K.; Wang, C.

2017-12-01

The non-closure of the Cocos-Nazca-Pacific plate motion circuit by 15.0 mm a-1± 3.8 mm a-1 (95% confidence limits throughout this abstract) [DeMets et al. 2010] represents a daunting challenge to the central tenet of plate tectonics—that the plates are rigid. This misfit is difficult to explain from known processes of intraplate deformation, such as horizontal thermal contraction [Collette, 1974; Kumar and Gordon, 2009; Kreemer and Gordon, 2014; Mishra and Gordon, 2016] or movement of plates over a non-spherical Earth [McKenzie, 1972; Turcotte and Oxburgh, 1973]. Possibly there are one or more unrecognized plate boundaries in the circuit, but no such boundary has been found to date. To make progress on this problem, we present three new Cocos-Nazca transform fault azimuths from multibeam data now available through Geomapapp's global multi-resolution topography [Ryan et al., 2009]. We determine a new Cocos-Nazca best-fitting angular velocity from the three new transform-fault azimuths combined with the spreading rates of DeMets et al. [2010]. The new direction of relative plate motion is 3.3° ±1.8° clockwise of prior estimates and is 4.9° ±2.7° clockwise of the azimuth of the Panama transform fault, demonstrating that the Panama transform fault does not parallel Nazca-Cocos plate motion. We infer that the plate east of the Panama transform fault is not the Nazca plate, but instead is a microplate that we term the Malpelo plate. We hypothesize that a diffuse plate boundary separates the Malpelo plate from the much larger Nazca plate. The Malpelo plate extends only as far north as ≈6°N where seismicity marks another boundary with a previously recognized microplate, the Coiba plate [Pennington, 1981, Adamek et al., 1988]. The Malpelo plate moves 5.9 mm a-1 relative to the Nazca plate along the Panama transform fault. When we sum the Cocos-Pacific and Pacific-Nazca best-fitting angular velocities of DeMets et al. [2010] with our new Nazca-Cocos best

CO-CO coupling on Cu facets: Coverage, strain and field effects

DOE PAGES

Sandberg, Robert B.; Montoya, Joseph H.; Chan, Karen; ...

2016-08-21

We present a DFT study on the effect of coverage, strain, and electric field on CO-CO coupling energetics on Cu (100), (111), and (211). Our calculations indicate that CO-CO coupling is facile on all three facets in the presence of a cation-induced electric field in the Helmholtz plane, with the lowest barrier on Cu(100). The CO dimerization pathway is therefore expected to play a role in C 2 formation at potentials negative of the Cu potential of zero charge, corresponding to CO 2/CO reduction conditions at high pH. Both increased *CO coverage and tensile strain further improve C-C coupling energeticsmore » on Cu (111) and (211). Since CO dimerization is facile on all 3 Cu facets, subsequent surface hydrogenation steps may also play an important role in determining the overall activity towards C 2 products. Adsorption of *CO, *H, and *OH on the 3 facets were investigated with a Pourbaix analysis. Here, the (211) facet has the largest propensity to co-adsorb *CO and *H, which would favor surface hydrogenation following CO dimerization.« less

Transient cracks and triple junctions induced by Cocos-Nazca propagating rift

NASA Astrophysics Data System (ADS)

Schouten, H.; Smith, D. K.; Zhu, W.; Montesi, L. G.; Mitchell, G. A.; Cann, J. R.

2009-12-01

The Galapagos triple junction is a ridge-ridge-ridge triple junction where the Cocos, Nazca, and Pacific plates meet around the Galapagos microplate (GMP). On the Cocos plate, north of the large gore that marks the propagating Cocos-Nazca (C-N) Rift, a 250-km-long and 50-km-wide band of NW-SE-trending cracks crosscuts the N-S-trending abyssal hills of the East Pacific Rise (EPR). These appear as a succession of minor rifts, accommodating some NE-SW extension of EPR-generated seafloor. The rifts successively intersected the EPR in triple junctions at distances of 50-100 km north of the tip of the C-N Rift. We proposed a simple crack interaction model to explain the location of the transient rifts and their junction with the EPR. The model predicts that crack locations are controlled by the stress perturbation along the EPR, induced by the dominant C-N Rift, and scaled by the distance of its tip to the EPR (Schouten et al., 2008). The model also predicts that tensile stresses are symmetric about the C-N Rift and thus, similar cracks should have occurred south of the C-N Rift prior to formation of the GMP about 1 Ma. There were no data at the time to test this prediction. In early 2009 (AT 15-41), we mapped an area on the Nazca plate south of the C-N rift out to 4 Ma. The new bathymetric data confirm the existence of a distinctive pattern of cracks south of the southern C-N gore that mirrors the pattern on the Cocos plate until about 1 Ma, and lends support to the crack interaction model. The envelope of the symmetric cracking pattern indicates that the distance between the C-N Rift tip and the EPR varied between 40 and 65 km during this time (1-4 Ma). The breakdown of the symmetry at 1 Ma accurately dates the onset of a southern plate boundary of the GMP, now Dietz Deep Rift. At present, the southern rift boundary of the GMP joins the EPR with a steep-sided, 80 km long ridge. This ridge releases the stress perturbation otherwise induced along the EPR by elastic

Cocos nucifera coir-mediated green synthesis of Pd NPs and its investigation against larvae and agricultural pest.

PubMed

Elango, Ganesh; Mohana Roopan, Selvaraj; Abdullah Al-Dhabi, Naif; Arasu, Mariadhas Valan; Irukatla Damodharan, Kasinathan; Elumalai, Kuppuswamy

2017-12-01

In recent decades, several scientists focused their process towards nanoparticles synthesis by using various sustainable approaches. Cocos nucifera (C. nucifera) was one of the versatile trees in tropical regions which also can act as a thrust quencher in all over the world. Cocos nucifera coir was one of the waste by-products in all coconut-refining industries and with the help C. nucifera coir, Palladium nanoparticles (Pd NPs) were synthesized. Green-synthesized spherical-shape Pd NPs were over layered by secondary metabolites from C. nucifera coir extract and with an average particle size of 62 ± 2 nm, which were confirmed by morphological analysis. Eco-friendly mediated Pd NPs were further subjected to several biological applications like larvicidal against Aedes aegypti (A. aegypti) and anti-feedent, ovicidal, and oviposition deterrent against agricultural pest Callasobruchus maculates (C. maculates) and compared with C. nuciferacoir methanolic extract, which results in LC 50 value of 288.88 ppm and LC 90 value of 483.06 ppm using LSD-Tukey's test against dengue vector (A. aegypti). Cocos nucifera coir methanolic extract shows significant output while compared with Pd NPs towards anti-feedent assays; ovicidal activity and oviposition deterrent were discussed here.

Synthesis and characterization of polymer matrix composite material with combination of ZnO filler and nata de coco fiber as a candidate of semiconductor material

NASA Astrophysics Data System (ADS)

Saputra, Asep Handaya; Anindita, Hana Nabila

2015-12-01

Synthesis of semiconductor composite using acrylic matrix filled with ZnO and nata de coco fiber has been conducted in this research. The purpose of this research is to obtain semiconductor composite material that has a good mechanical strength and thermal resistance. In situ polymerization method is used in this research and the composites are ready to be characterized after 12 hours. The main parameter that is characterized is the electric conductivity of the composite. Additional parameters are also characterized such as composite's elastic modulus and glass transition temperature. The composites that has been made in this research can be classified as semiconductor material because the conductivity is in the range of 10-8-103 S/cm. In general the addition of ZnO and nata de coco filler can increase the conductivity of the composite. The highest semiconductor characteristic in acrylic/ZnO composite is obtained from 30% volume filler that reach 3.4 x 10-7 S/cm. Similar with acrylic/ZnO composite, in acrylic/nata de coco fiber composite the highest semiconductor characteristic is also obtained from 30% volume filler that reach 1.15 x 10-7 S/cm. Combination of 20% volume of ZnO, 10% volume of nata de coco, and 70% volume of acrylic resulting in composite with electric conductivity of 1.92 x 10-7 S/cm. In addition, combination of ZnO and nata de coco fiber as filler in composite can also improve the characteristic of composite where composite with 20% volume of ZnO filler and 10% volume of nata de coco fiber resulting in composite with elastic modulus of 1.79 GPa and glass transition temperature of 175.73°C which is higher than those in acrylic/ZnO composite.

The high-pressure behavior of spherocobaltite (CoCO3): a single crystal Raman spectroscopy and XRD study

NASA Astrophysics Data System (ADS)

Chariton, Stella; Cerantola, Valerio; Ismailova, Leyla; Bykova, Elena; Bykov, Maxim; Kupenko, Ilya; McCammon, Catherine; Dubrovinsky, Leonid

2018-01-01

Magnesite (MgCO3), calcite (CaCO3), dolomite [(Ca, Mg)CO3], and siderite (FeCO3) are among the best-studied carbonate minerals at high pressures and temperatures. Although they all exhibit the calcite-type structure ({R}\\bar{3}{c}) at ambient conditions, they display very different behavior at mantle pressures. To broaden the knowledge of the high-pressure crystal chemistry of carbonates, we studied spherocobaltite (CoCO3), which contains Co2+ with cation radius in between those of Ca2+ and Mg2+ in calcite and magnesite, respectively. We synthesized single crystals of pure spherocobaltite and studied them using Raman spectroscopy and X-ray diffraction in diamond anvil cells at pressures to over 55 GPa. Based on single crystal diffraction data, we found that the bulk modulus of spherocobaltite is 128 (2) GPa and K' = 4.28 (17). CoCO3 is stable in the calcite-type structure up to at least 56 GPa and 1200 K. At 57 GPa and after laser heating above 2000 K, CoCO3 partially decomposes and forms CoO. In comparison to previously studied carbonates, our results suggest that at lower mantle conditions carbonates can be stable in the calcite-type structure if the radius of the incorporated cation(s) is equal or smaller than that of Co2+ (i.e., 0.745 Å).

Plume-Ridge Interaction on the Cocos Plate (ODP Leg 205, Costa Rica): Implication for Fluid Circulation

NASA Astrophysics Data System (ADS)

Dreyer, B.; Chavagnac, V.; Font, L.; Morris, J.; Schramm, B.; Chavagnac, V.; Font, L.; Schramm, B.; Dreyer, B.; Morris, J. D.

2004-12-01

At subduction zone, the permeability and hydrology of the down-going igneous section play a key role on the behaviour of the seismogenic zone, which produces earthquake and tsunamis. We present, here, evidence of fluid circulation pathways in the igneous section being subducted at the Central American convergent margin (Site 1253 ODP Leg 205, Costa Rica). The geological evolution of the Cocos plate over the last 25 Ma is complicated as a result of plate boundaries re-arrangement (Silver et al., 1998). The Cocos-Nazca spreading centre (CNS) interacted with the Galapagos hotspot, which simultaneously deposited volcanic material on both side of the CNS, on the Cocos and Nazca plates. The oceanic crust of the Cocos and Nazca plates was formed along four spreading centres (Meschede et al., 1998) and the East Pacific Rise (EPR). The EPR oceanic crust has the featureless morphology and low-amplitude magnetic anomalies common to fast spreading ridge (Wilson & Hey, 1995) while the CNS oceanic crust presents a rough topography and high-amplitude magnetic anomalies (Wilson & Hey, 1995). We wish to focus on the ODP 1253 Site drilled in the Cocos plate because it samples the igneous input (rock, heat and fluid) to the Central American subduction zone. Coring at Site 1253 penetrated two separate igneous Units of which the upper one is a sill (Unit 4A) separated from the lower Unit (Unit 4B) by sediment. Both Unit 4A and 4B present similar texture, structure and mineralogy apart from the thin basaltic interval at 513 mbsf, below which Unit 4B becomes more glass-rich and altered. Unit 4B is either a sill complex with multiple intrusions related to the Galapagos volcanic activity or a series of thick slowly cooled lava flows formed at the EPR. Some of these characteristics of Unit 4B are similar to those seen in horizons recovered at Site 1256, which intersected thick-ponded lava flows. Analyses of marine magnetic anomalies indicate that the crust at Site 1253 was formed at EPR 25

Kinetics of CO/CO2 and H2/H2O reactions at Ni-based and ceria-based solid-oxide-cell electrodes.

PubMed

Graves, Christopher; Chatzichristodoulou, Christodoulos; Mogensen, Mogens B

2015-01-01

The solid oxide electrochemical cell (SOC) is an energy conversion technology that can be operated reversibly, to efficiently convert chemical fuels to electricity (fuel cell mode) as well as to store electricity as chemical fuels (electrolysis mode). The SOC fuel-electrode carries out the electrochemical reactions CO2 + 2e(-) ↔ CO + O(2-) and H2O + 2e(-) ↔ H2 + O(2-), for which the electrocatalytic activities of different electrodes differ considerably. The relative activities in CO/CO2 and H2/H2O and the nature of the differences are not well studied, even for the most common fuel-electrode material, a composite of nickel and yttria/scandia stabilized zirconia (Ni-SZ). Ni-SZ is known to be more active for H2/H2O than for CO/CO2 reactions, but the reported relative activity varies widely. Here we compare AC impedance and DC current-overpotential data measured in the two gas environments for several different electrodes comprised of Ni-SZ, Gd-doped CeO2 (CGO), and CGO nanoparticles coating Nb-doped SrTiO3 backbones (CGOn/STN). 2D model and 3D porous electrode geometries are employed to investigate the influence of microstructure, gas diffusion and impurities.Comparing model and porous Ni-SZ electrodes, the ratio of electrode polarization resistance in CO/CO2vs. H2/H2O decreases from 33 to 2. Experiments and modelling suggest that the ratio decreases due to a lower concentration of impurities blocking the three phase boundary and due to the nature of the reaction zone extension into the porous electrode thickness. Besides showing higher activity for H2/H2O reactions than CO/CO2 reactions, the Ni/SZ interface is more active for oxidation than reduction. On the other hand, we find the opposite behaviour in both cases for CGOn/STN model electrodes, reporting for the first time a higher electrocatalytic activity of CGO nanoparticles for CO/CO2 than for H2/H2O reactions in the absence of gas diffusion limitations. We propose that enhanced surface reduction at the

The Cocos Ridge hydrothermal system revealed by microthermometry of fluid and melt inclusions

NASA Astrophysics Data System (ADS)

Brandstätter, J.; Kurz, W.; Krenn, K.

2017-12-01

Microthermometric analyses of fluid and melt inclusions in hydrothermal veins and in the Cocos Ridge (CCR) basalt were used to reveal the CCR thermal history at IODP Site 344-U1414 and to constrain fluid source and flow. Hydrothermal veins are hosted by lithified sediments and CCR basalt . Site 344-U1414, located 1 km seaward of the Middle American Trench offshore Costa Rica, serves to evaluate fluid/rock interaction, the hydrologic system and geochemical processes linked with the tectonic evolution of the incoming Cocos Plate from the Early Miocene up to recent times. The veins in the sedimentary rocks are mainly filled by blocky calcite, containing numerous fluid inclusions, and sometimes crosscut fibrous quartz/chalcedony veins. The veins in the basalt can be differentiated into three types: antitaxial fibrous calcite veins, composite veins with fibrous calcite and clay minerals at the vein margins and spherulitic quartz in the center, and syntaxial blocky aragonite veins surrounded by a clay selvage in the uppermost CCR basalt sections. Secondary minerals, clay minerals, fibrous calcite, quartz/chalcedony and pyrite also filled vesicles in the basalt. Fluid inclusions were mainly found in the aragonite veins and rarely in quartz in the composite veins and vesicles. Blocky veins with embedded wall rock fragments appear in the sediments and in the basalt indicate hydraulic fracturing. The occurrence of decrepitated fluid inclusions show high homogenization temperatures up to 400 °C. Decrepitated fluid inclusions are formed by increased internal overpressure, related to isobaric heating. Elongated fluid inclusion planes, arc-like fluid inclusions and low homogenization temperatures indicate subsequent isobaric cooling. The results obtained so far from Raman spectroscopy and microthermometry indicate CO2 inclusions and petrographic observations suggest the presence of silicate melt inclusions in phenocrysts in the basalt (mainly in clinopyroxene and plagioclase

The shallow-water fish assemblage of Isla del Coco National Park, Costa Rica: Structure and patterns in an isolated, predator-dominated ecosystem

USGS Publications Warehouse

Friedlander, Alan M.; Zgliczynski, Brian J.; Ballesteros, Enric; Aburto-Oropeza, Octavio; Bolaños, Allan; Sala, Enric

2012-01-01

Fishes at Isla del Coco National Park, Costa Rica, were surveyed as part of a larger scientific expedition to the area in September 2009. The average total biomass of nearshore fishes was 7.8 tonnes per ha, among the largest observed in the tropics, with apex predators such as sharks, jacks, and groupers accounting for nearly 40% of the total biomass. The abundance of reef and pelagic sharks, particularly large aggregations of threatened species such as the scalloped hammerhead shark (up to 42 hammerheads ha-1) and large schools of jacks and snappers show the capacity for high biomass in unfished ecosystems in the Eastern Tropical Pacific. However, the abundance of hammerhead and reef whitetip sharks appears to have been declining since the late 1990s, and likely causes may include increasing fishing pressure on sharks in the region and illegal fishing inside the Park. One Galapagos shark tagged on September 20, 2009 in the Isla del Coco National Park moved 255km southeast towards Malpelo Island in Colombia, when it stopped transmitting. These results contribute to the evidence that sharks conduct large-scale movements between marine protected areas (Isla del Coco, Malpelo, Galápagos) in the Eastern tropical Pacific and emphasize the need for regional-scale management. More than half of the species and 90% of the individuals observed were endemic to the tropical eastern Pacific. These high biomass and endemicity values highlight the uniqueness of the fish assemblage at Isla del Coco and its importance as a global biodiversity hotspot.

Technical Update: Johnson Space Center system using a solid electrolytic cell in a remote location to measure oxygen fugacities in CO/CO2 controlled-atmosphere furnaces

NASA Technical Reports Server (NTRS)

Jurewicz, A. J. G.; Williams, R. J.; Le, L.; Wagstaff, J.; Lofgren, G.; Lanier, A.; Carter, W.; Roshko, A.

1993-01-01

Details are given for the design and application of a (one atmosphere) redox-control system. This system differs from that given in NASA Technical Memorandum 58234 in that it uses a single solid-electrolytic cell in a remote location to measure the oxygen fugacities of multiple CO/CO2 controlled-atmosphere furnaces. This remote measurement extends the range of sample-furnace conditions that can be measured using a solid-electrolytic cell, and cuts costs by extending the life of the sensors and by minimizing the number of sensors in use. The system consists of a reference furnace and an exhaust-gas manifold. The reference furnace is designed according to the redox control system of NASA Technical Memorandum 58234, and any number of CO/CO2 controlled-atmosphere furnaces can be attached to the exhaust-gas manifold. Using the manifold, the exhaust gas from individual CO/CO2 controlled atmosphere furnaces can be diverted through the reference furnace, where a solid-electrolyte cell is used to read the ambient oxygen fugacity. The oxygen fugacity measured in the reference furnace can then be used to calculate the oxygen fugacity in the individual CO/CO2 controlled-atmosphere furnace. A BASIC computer program was developed to expedite this calculation.

New species of Nuuanu (Amphipoda: Nuuanuidae) from Norfolk Island, Torres Strait and the Cocos (Keeling) Islands.

PubMed

Hughes, L E; Bopiah, A

2013-01-01

Three new species of Nuuanu, N. quintalana sp. nov., N. stuckeyorun sp. nov. and N. titaseyi sp. nov. are described from Norfolk Island, Tasman Sea; Cocos (Keeling) Islands, Indian Ocean and the Torres Strait, Australia, respectively. There are currently 17 described species of Nuuanu with the genus distributed world-wide.

Cloning and functional expression of a cDNA encoding stearoyl-ACP Δ9-desaturase from the endosperm of coconut (Cocos nucifera L.).

PubMed

Gao, Lingchao; Sun, Ruhao; Liang, Yuanxue; Zhang, Mengdan; Zheng, Yusheng; Li, Dongdong

2014-10-01

Coconut (Cocos nucifera L.) is an economically tropical fruit tree with special fatty acid compositions. The stearoyl-acyl carrier protein (ACP) desaturase (SAD) plays a key role in the properties of the majority of cellular glycerolipids. In this paper, a full-length cDNA of a stearoyl-acyl carrier protein desaturase, designated CocoFAD, was isolated from cDNA library prepared from the endosperm of coconut (C. nucifera L.). An 1176 bp cDNA from overlapped PCR products containing ORF encoding a 391-amino acid (aa) protein was obtained. The coded protein was virtually identical and shared the homology to other Δ9-desaturase plant sequences (greater than 80% as similarity to that of Elaeis guineensis Jacq). The real-time fluorescent quantitative PCR result indicated that the yield of CocoFAD was the highest in the endosperm of 8-month-old coconut and leaf, and the yield was reduced to 50% of the highest level in the endosperm of 15-month-old coconut. The coding region showed heterologous expression in strain INVSc1 of yeast (Saccharomyces cerevisiae). GC-MS analysis showed that the levels of palmitoleic acid (16:1) and oleic acid (18:1) were improved significantly; meanwhile stearic acid (18:0) was reduced. These results indicated that the plastidial Δ9 desaturase from the endosperm of coconut was involved in the biosynthesis of hexadecenoic acid and octadecenoic acid, which was similar with other plants. These results may be valuable for understanding the mechanism of fatty acid metabolism and the genetic improvement of CocoFAD gene in palm plants in the future. Copyright © 2014 Elsevier B.V. All rights reserved.

Widespread Mega-Pockmarks Imaged Along the Western Edge of the Cocos Ridge

NASA Astrophysics Data System (ADS)

Gibson, J. C.; Kluesner, J. W.; Silver, E. A.; Bangs, N. L.; McIntosh, K. D.

2012-12-01

A large field (245km2) of 31 seabed mega-pockmarks was imaged between the Cocos ridge and the Quepos plateau on ~16.5 Ma oceanic crust generated at the Cocos-Nazca spreading center. The imaged pockmarks represent only a fraction of the much larger pockmark field evident in 100 m grid cell bathymetry data secured from MGDS. The pockmarks are clustered around 1800-2100 mbsl and were mapped using EM122 multibeam sonar, a 3.5 kHz sub-bottom profiler, and 3D Multi-Channel Seismic (MCS) aboard R/V Marcus G. Langseth during the CRISP seismic survey (2011). Using a constrained swath width of 1.4 km, the increased sounding density facilitated bathymetry/backscatter to be gridded at 10m and 8m respectively. The diameter of the pockmarks varies from ~1 km to ~2 km with a relief range of ~30-80 m, and average slopes of 15°. The MCS data also reveal older buried pockmarks in trench adjacent sediments. Small high-backscatter mounds occur within a subset of the pockmarks, which may indicate bioherms or carbonate banks above focused fluid flow conduits. Based on drilling results of DSDP Site 158 and ODP Site 1381, the pockmarks appear to be the result of paleo-differential advancement of a silica diagenetic front (opal-A to opal-CT). Although, the pockmarks may be erosional features sourced at depth from dewatering of sediments inter-bedded with igneous layers.

From transpressional to transtensional tectonics in Northern Central America controlled by Cocos - Caribbean subduction coupling change

NASA Astrophysics Data System (ADS)

Alonso-Henar, Jorge; Alvarez-Gomez, José Antonio; Jesús Martinez-Diaz, José

2017-04-01

The Central American Volcanic Arc (CAVA) is located at the western margin of the Caribbean plate, over the Chortís Block, spanning from Guatemala to Costa Rica. The CAVA is associated to the subduction of the Cocos plate under the Caribbean plate at the Middle America Trench. Our study is focused in the Salvadorian CAVA segment, which is tectonically characterized by the presence of the El Salvador Fault Zone (ESFZ), part of the western boundary of a major block forming the Caribbean plate (the Chortis Block). The structural evolution of the western boundary of the Chortis Block, particularly in the CAVA crossing El Salvador remains unknown. We have done a kinematic analysis from seismic and fault slip data and combined our results with a review of regional previous studies. This approach allowed us to constrain the tectonic evolution and the forces that control the deformation in northern Central America. Along the active volcanic arc we identified active transtensional deformation. On the other hand, we have identified two deformation phases in the back arc region: A first one of transpressional wrenching close to simple shearing (Miocene); and a second one characterized by almost E-W extension. Our results reveal a change from transpressional to transtensional shearing coeval with a migration of the volcanism towards the trench in Late Miocene times. This strain change could be related with a coupled to decoupled transition on the Cocos - Caribbean subduction interface, which could be related to a slab roll-back of the Cocos Plate beneath the Chortis Block. The combination of different degrees of coupling on the subduction interface, together with a constant relative eastward drift of the Caribbean Plate, control the deformation style along the western boundary of the Chortis Block.

Absolute Plate Motion Control Since the Triassic from the Cocos Slab and its Associated Subduction Record in Mexico

NASA Astrophysics Data System (ADS)

Boschman, L.; Van Hinsbergen, D. J. J.; Langereis, C. G.; Molina-Garza, R. S.; Kimbrough, D. L.; Spakman, W.

2017-12-01

A positive wave speed anomaly interpreted as the Cocos slab stretches from the uppermost mantle at the Middle America trench in the west, to the lowermost mantle below the Atlantic in the east. The length and continuity of this slab indicates long-lived, uninterrupted eastward subduction of the attached Cocos Plate and its predecessor, the Farallon Plate. The geological record of Mexico contains Triassic to present day evidence of subduction, of which the post-Late Cretaceous phase is of continental margin-style. Interpretations of the pre-Upper Cretaceous subduction-related rock assemblages are under debate, and vary from far-travelled exotic intra-oceanic island arc character to in-situ extended continental margin origin. We present new paleomagnetic data that show that Triassic, Jurassic and Cretaceous subduction-related rocks from the Vizcaíno Peninsula and the Guerrero terrane have a paleolatitudinal plate motion history that is equal to that of the North American continent. This suggests that these rock assemblages were part of the overriding plate and were perhaps only separated from the North American continent by temporal fore- or back-arc spreading. The entire Triassic-present day subduction record, and hence, reconstructed trench location, can therefore be linked to the Cocos slab, which provides control on longitudinal plate motion of North America since the time of Pangea. Compared to the latest state of the art mantle frames, in which longitudes are essentially unconstrained for pre-Cretaceous times, our reconstructed absolute position of North America requires a significant westward longitudinal shift for Mesozoic times.

A new species of Callispa Baly (Coleoptera, Chrysomelidae, Cassidinae, Callispini) infesting coconut palm ( Cocos nucifera L.) in India

PubMed Central

Shameem, K. M.; Prathapan, K. D.

2013-01-01

Abstract Callispa keram sp. n. infesting coconut palm (Cocos nucifera L.) in Kerala, India is described and illustrated. Livistona chinensis R.Br. and Syagrus romanzoffiana (Cham.) Glassman are reported as additional host plants. PMID:23653522

Shifting elasmobranch community assemblage at Cocos Island--an isolated marine protected area.

PubMed

White, Easton R; Myers, Mark C; Flemming, Joanna Mills; Baum, Julia K

2015-08-01

Fishing pressure has increased the extinction risk of many elasmobranch (shark and ray) species. Although many countries have established no-take marine reserves, a paucity of monitoring data means it is still unclear if reserves are effectively protecting these species. We examined data collected by a small group of divers over the past 21 years at one of the world's oldest marine protected areas (MPAs), Cocos Island National Park, Costa Rica. We used mixed effects models to determine trends in relative abundance, or probability of occurrence, of 12 monitored elasmobranch species while accounting for variation among observers and from abiotic factors. Eight of 12 species declined significantly over the past 2 decades. We documented decreases in relative abundance for 6 species, including the iconic scalloped hammerhead shark (Sphyrna lewini) (-45%), whitetip reef shark (Triaenodon obesus) (-77%), mobula ray (Mobula spp.) (-78%), and manta ray (Manta birostris) (-89%), and decreases in the probability of occurrence for 2 other species. Several of these species have small home ranges and should be better protected by an MPA, which underscores the notion that declines of marine megafauna will continue unabated in MPAs unless there is adequate enforcement effort to control fishing. In addition, probability of occurrence at Cocos Island of tiger (Galeocerdo cuvier), Galapagos (Carcharhinus galapagensis), blacktip (Carcharhinus limbatus), and whale (Rhincodon typus) sharks increased significantly. The effectiveness of MPAs cannot be evaluated by examining single species because population responses can vary depending on life history traits and vulnerability to fishing pressure. © 2015 Society for Conservation Biology.

New records of Lasiodiplodia theobromae in seeds of Tetrapleura tetraptera from Nigeria and fruit of Cocos nucifera from Mexico

USDA-ARS?s Scientific Manuscript database

The cosmopolitan warm-climate plant pathogen Lasiodiplodia theobromae was isolated from two sources: Seeds of Tetrapleura tetraptera from Nigeria and fruits of Cocos nucifera from Mexico; the former instance is novel for host, the latter a novel geographic record for infection of coconut fruits. Per...

An Overview of Phytoconstituents, Biotechnological Applications, and Nutritive Aspects of Coconut (Cocos nucifera).

PubMed

Roopan, Selvaraj Mohana

2016-08-01

Cocos nucifera is one of the highest nutritional and medicinal value plants with various fractions of proteins which play a major role in several biological applications such as anti-microbial, anti-inflammatory, anti-diabetic, anti-neoplastic, anti-parasitic, insecticidal, and leishmanicidal activities. This review is focused on several biotechnological, biomedical aspects of various solvent extracts collected from different parts of coconut and the phytochemical constituents which are present in it. The results obtained from this source will facilitate most of the researchers to focus their work toward the process of diagnosing diseases in future.

Geochemistry of basement rocks of incoming plate (Cocos Ridge) from Sites U1381 and 1414, IODP Expeditions 334 and 344

NASA Astrophysics Data System (ADS)

Yan, Q.; Shi, X.

2015-12-01

The drilling sites of IODP 334 and 344 lie in the being subducted part of Cocos Ridge, offshore Costa Rica. Some seamount clusters distributed in the northwest side of the sites. Most scientists accepted that the Cocos ridge is intimately related to the activity of Galapagos plume (e.g., Hoernle et al., 2000, 2004, 2008). In this study we have selected some basaltic samples from U1381A, U1381C and U1414A (IODP 334 and 344) (Harris et al., 2015a, b) to carry out petrogenetic study. Major element compositions show that these basaltic rocks belong to sub-alkaline rocks, which is consistent with previous study on basalts from northern side of Cocos ridge. The characteristics of trace element composition are similar to that of EMORB, and the compositional differences in trace elements among samples reflect the influence of fractional crystallization. Sr-Nd-Pb isotopic compositions of these basaltic rocks show that there exist mantle heterogeneity beneath the Cocos ridge, and they may be the product of mixing between DMM/GSC and EMII. The new data show more enriched source feature than those from Galapagos hotspot (and its tracks) in previous study (Hoernle et al., 2000,2004), and slightly more enriched than those Miocene to Pliocene arc volcanics from Central America (Gazel et al., 2009). Partial melting model show that the parental basalts for these basaltic rocks may be produced by 13 to 28% partial melting of garnet pyroxenite. ReferencesGazel et al., 2009. G-cubed.10, Q02S11, doi:10.1029/2008GC002246.//Harris, R.N., Sakaguchi, A., Petronotis, K., and the Expedition 344 Scientists. 2015a. Input Site U1381. Proceedings of the Integrated Ocean Drilling Program, Volume 344//Harris, R.N., Sakaguchi, A., Petronotis, K., and the Expedition 344 Scientists. 2015b. Input Site U1414.Proceedings of the Integrated Ocean Drilling Program, Volume 344//Hoernle et al., 2000. Geology, 28(5),435-438//Hoernle et al., 2004. Geology, 32,697-700//Hoernle et al., 2008. Nature, 451

In vitro antioxidant, anti-inflammatory and anticancer activities of ethyl acetate soluble proanthocyanidins of the inflorescence of Cocos nucifera L.

PubMed

Padumadasa, Chayanika; Dharmadana, Durga; Abeysekera, Ajit; Thammitiyagodage, Mayuri

2016-09-05

Proanthocyanidins belong to a class of polyphenolic compounds called flavonoids and have been reported to exhibit important biological activities. The immature inflorescence of Cocos nucifera L. is used by Ayurvedic and traditional medical practitioners for the treatment of menorrhagia in Sri Lanka. Our studies have shown that the inflorescence of Cocos nucifera L. predominantly contains proanthocyanidins. To determine the antioxidant, anti-inflammatory and anticancer activities of ethyl acetate soluble proanthocyanidins (EASPA) of immature inflorescence of Cocos nucifera L. EASPA fraction of an acetone/water (7:3) extract of Cocos nucifera L. inflorescence was purified on Sephadex LH-20 and was used for the study. Antioxidant activity of EASPA was determined using DPPH and SOR scavenging assays. Anti-inflammatory activity of EASPA was determined by oxidative burst assay using chemiluminescence technique. MTT colorimetric assay was used to evaluate the cytotoxicity of EASPA to both PC3 and HeLa cells. EASPA showed radical scavenging activity against both DPPH and superoxide radicals with IC50 values of 11.02 ± 0.60 μg/mL and 26.11 ± 0.72 μg/mL. In both assays, EASPA showed less antioxidant activity than the standards used. It exhibited similar anti-inflammatory activity (IC50 = 10.31 ± 1.11 μg/mL) to ibuprofen (IC50 = 11.20 ± 1.90 μg/mL) (P ≥ 0.05). EASPA also showed stronger cytotoxic activity towards Hela cells (IC50 = 18.78 ± 0.90 μg/mL) than tamoxifen (IC50 = 28.80 ± 1.94 μg/mL) (P ≤ 0.05), while low cytotoxicity was observed against PC3 cells (IC50 = 44.21 ± 0.73 μg/mL) compared to doxorubicin (IC50 = 1.38 ± 0.16 μg/mL). EASPA showed antioxidant, anti-inflammatory and anticancer activities.

Elementary reaction modeling of reversible CO/CO2 electrochemical conversion on patterned nickel electrodes

NASA Astrophysics Data System (ADS)

Luo, Yu; Shi, Yixiang; Li, Wenying; Cai, Ningsheng

2018-03-01

CO/CO2 are the major gas reactant/product in the fuel electrode of reversible solid oxide cells (RSOC). This study proposes a two-charge-transfer-step mechanism to describe the reaction and transfer processes of CO-CO2 electrochemical conversion on a patterned Ni electrode of RSOC. An elementary reaction model is developed to couple two charge transfer reactions, C(Ni)+O2-(YSZ) ↔ CO(Ni)+(YSZ) +2e- and CO(Ni)+O2-(YSZ) ↔ CO2(Ni)+(YSZ)+2e-, with adsorption/desorption, surface chemical reactions and surface diffusion. This model well validates in both solid oxide electrolysis cell (SOEC) and solid oxide fuel cell (SOFC) modes by the experimental data from a patterned Ni electrode with 10 μm stripe width at different pCO (0-0.25 atm), pCO2 (0-0.35 atm) and operating temperature (600-700 °C). This model indicates SOEC mode is dominated by charge transfer step C(Ni)+O2-(YSZ)↔CO(Ni)+(YSZ) +2e-, while SOFC mode by CO(Ni)+ O2-(YSZ)↔CO2(Ni)+(YSZ)+2e- on the patterned Ni electrode. The sensitivity analysis shows charge transfer step is the major rate-determining step for RSOC, besides, surface diffusion of CO and CO2 as well as CO2 adsorption also plays a significant role in the electrochemical reaction of SOEC while surface diffusion of CO and CO2 desorption could be co-limiting in SOFC.

40 CFR 721.10193 - 1-Butanaminium, N-(3-aminopropyl)-N-butyl-N-(2-carboxyethyl)-, N-coco acyl derivs., inner salts.

Code of Federal Regulations, 2010 CFR

2010-07-01

... 40 Protection of Environment 30 2010-07-01 2010-07-01 false 1-Butanaminium, N-(3-aminopropyl)-N-butyl-N-(2-carboxyethyl)-, N-coco acyl derivs., inner salts. 721.10193 Section 721.10193 Protection of... CHEMICAL SUBSTANCES Significant New Uses for Specific Chemical Substances § 721.10193 1-Butanaminium, N-(3...

Antimicrobial and antiviral activities of polyphenolics from Cocos nucifera Linn. (Palmae) husk fiber extract.

PubMed

Esquenazi, Daniele; Wigg, Marcia D; Miranda, Mônica M F S; Rodrigues, Hugo M; Tostes, João B F; Rozental, Sonia; da Silva, Antonio J R; Alviano, Celuta S

2002-12-01

The decoction of Cocos nucifera L. husk fiber has been used in northeastern Brazil traditional medicine for treatment of diarrhea and arthritis. Water extract obtained from coconut husk fiber and fractions from adsorption chromatography revealed antimicrobial activity against Staphylococcus aureus. The crude extract and one of the fractions rich in catechin also showed inhibitory activity against acyclovir-resistant herpes simplex virus type 1 (HSV-1-ACVr). All fractions were inactive against the fungi Candida albicans, Fonsecaea pedrosoi and Cryptococcus neoformans. Catechin and epicatechin together with condensed tannins (B-type procyanidins) were demonstrated to be the components of the water extract.

Antiepileptic activity of total triterpenes isolated from Poria cocos is mediated by suppression of aspartic and glutamic acids in the brain.

PubMed

Gao, Yanqiong; Yan, Hua; Jin, Ruirui; Lei, Peng

2016-11-01

Triterpenes from Poria cocos Wolf (Polyporaceae) have been used to treat various diseases in traditional Chinese medicine. However, the antiepileptic effects and mechanism are not fully understood. The objective of this study is to investigate the antiepileptic properties of total triterpenes (TTP) from the whole P. cocos. The ethanol extract TTP was identified by HPLC fingerprint analysis. Male ICR mice were gavaged (i.g.) with TTP (5, 20, 80 or 160 mg/kg) or reference drugs twice a day for 7 d. Antiepileptic activities of TTP were evaluated by maximal electroshock (MES)- and pentylenetetrazole (PTZ)-induced seizures in mice for 30 and 60 min, respectively. Locomotor activity and Rota-rod tests were performed for 60 min and 5 min, respectively. The levels of glutamic acid (Glu), aspartic acid (Asp), γ-aminobutyric acid (GABA) and glycine (Gly) in convulsive mice were estimated. The chronic epileptic model of Wistar rats was built to measure expressions of glutamate decarboxylase 65 (GAD65) and GABA A in rat brain after TTP treatment. The LC 50 of TTP (i.g.) was above 6 g/kg. TTP (5-160 mg/kg) protected mice against MES- and PTZ-induced convulsions at 65.0% and 62.5%, respectively, but have no effect on rota-rod treadmill; TTP (20-160 mg/kg) significantly reduced the locomotor activities, shortened the onset of pentobarbital sodium-induced sleep; TTP decreased Glu and Asp levels in convulsive mice, but increased the GAD65 and GABA A expressions in chronic epileptic rats at doses usage. TTP extracted from P. cocos possessed potential antiepileptic properties and is a candidate for further antiepileptic drug development.

Crystal Structure of Cocosin, A Potential Food Allergen from Coconut (Cocos nucifera).

PubMed

Jin, Tengchuan; Wang, Cheng; Zhang, Caiying; Wang, Yang; Chen, Yu-Wei; Guo, Feng; Howard, Andrew; Cao, Min-Jie; Fu, Tong-Jen; McHugh, Tara H; Zhang, Yuzhu

2017-08-30

Coconut (Cocos nucifera) is an important palm tree. Coconut fruit is widely consumed. The most abundant storage protein in coconut fruit is cocosin (a likely food allergen), which belongs to the 11S globulin family. Cocosin was crystallized near a century ago, but its structure remains unknown. By optimizing crystallization conditions and cryoprotectant solutions, we were able to obtain cocosin crystals that diffracted to 1.85 Å. The cocosin gene was cloned from genomic DNA isolated from dry coconut tissue. The protein sequence deduced from the predicted cocosin coding sequence was used to guide model building and structure refinement. The structure of cocosin was determined for the first time, and it revealed a typical 11S globulin feature of a double layer doughnut-shaped hexamer.

‘Candidatus Phytoplasma palmicola’, a novel taxon associated with a lethal yellowing-type disease (LYD) of coconut (Cocos nucifera L.) in Mozambique

USDA-ARS?s Scientific Manuscript database

In this study, the taxonomic position and group classification of the phytoplasma associated with a lethal yellowing-type disease (LYD) of coconut (Cocos nucifera L.) in Mozambique were addressed. Pairwise sequence similarity values based on alignment of near full-length 16SrRNA genes (1530 bp) reve...

Evaluation of antihyperglycemic activity of Cocos nucifera Linn. on streptozotocin induced type 2 diabetic rats.

PubMed

Naskar, Sagar; Mazumder, Upal K; Pramanik, Goutam; Gupta, Malaya; Kumar, R B Suresh; Bala, Asis; Islam, Aminul

2011-12-08

The plant Cocos nucifera Linn. (Arecaceae) is commonly known as coconut. Traditionally the juice of the young spadix when fresh is used in diarrhea and diabetes. The objective of the present study was to investigate the effect of antidiabetic activity and effect on lipid profile as well as cardioprotective effect of hydro-methanol extract of Cocos nucifera (HECN) on streptozotocin (STZ)-induced diabetic rats. After 72 h of STZ (50 mg/kg, b.w. i.p.) administration, animals showing plasma sugar level more than 250 mg/dl were considered as diabetic rat. Fasting blood glucose (FBG) levels were measured on 0th (after 72 h of STZ), 5th, 10th, and 15th day. On the 15th day all the animals were sacrificed and the serum biochemical parameters and antioxidant enzyme status were measured. HECN treated animals showed a significant reduction in FBG level as compared with diabetic control group. Serum enzyme level (SGOT, SGPT, SALP), lipid peroxidation and antioxidant enzyme level such as CAT, GSH, SOD and cholesterol and triglycerides in the HECN treated groups were restored towards normal level as compared to diabetic control groups and the values were comparable with the standard groups (glibenclamide). Improvement in the FBG and the restoration of all other biomarker as well as enzymes indicates that HECN has very good antidiabetic activity with very low side effects and provides a scientific rationale for the use as an antidiabetic agent. Copyright © 2011 Elsevier Ireland Ltd. All rights reserved.

Assessment of Reactive Catch Basin Larvicide Treatments Toward Improved Water Quality Using FourStar(®) Briquets and CocoBear™ Larvicide Oil.

PubMed

Harbison, Justin E; Zazra, Dave; Henry, Marlon; Xamplas, Christopher; Kafensztok, Ruth

2015-09-01

Because it is often logistically impossible to monitor all catch basins within an operational area, local mosquito control programs will preemptively treat catch basins with larvicides each season. However, these larvicides can, ostensibly, be considered water quality pollutants. To experimentally reduce the use of larvicides toward improving water quality, 30 basins within a small 0.7-km(2) residential area were monitored weekly for the presence of larvae and pupae for 14 wk in the summer of 2013. Once a basin was found to reach a threshold of 12 mosquitoes per dip sample, it received a FourStar® Briquet (a 180-day briquet formulation of 6% Bacillus sphaericus and 1% B. thuringiensis israelensis). Each week a FourStar-treated basin surpassed this threshold, it was treated with an application of CocoBear™ oil (10% mineral oil). By the end of trials, all but one basin received a briquet and 13 required at least 4 treatments of CocoBear, suggesting that preemptive treatment is appropriate for the study area.

High temperature chemical kinetic study of the H2-CO-CO2-NO reaction system

NASA Technical Reports Server (NTRS)

Jachimowski, C. J.

1975-01-01

An experimental study of the kinetics of the H2-CO-CO2-NO reaction system was made behind incident shock waves at temperatures of 2460 and 2950 K. The overall rate of the reaction was measured by monitoring radiation from the CO + O yields CO2 + h upoilon reaction. Correlation of these data with a detailed reaction mechanism showed that the high-temperature rate of the reaction N + OH yields NO + H can be described by the low-temperature (320 K) rate coefficient. Catalytic dissociation of molecular hydrogen was an important reaction under the tests conditions.

Tomography of the subducting Cocos plate in central Mexico using data from the installation of a prototype wireless seismic network: Images of a truncated slab

NASA Astrophysics Data System (ADS)

Husker, Allen Leroy, Jr.

WiLSoN during the MASE experiment. The MASE data is used to perform a 2D P-wave tomography of the subducting Cocos plate. A seismicity study by Pardo and Suarez (1995) mapped a flat Cocos slab under the North America plate to 190 km inland. Our tomography shows the slab subduction continues from 250 km inland at a much steeper angle of 75°. The slab stops somewhere between 450 km and 550 km depth under the northern Trans-Mexican Volcanic Belt. The Farallon plate, from which the Cocos plate presumably broke, is not seen. P-wave travel times are also inverted for a 2D temperature model of the Cocos slab under Mexico. The temperature model from Davies and Stevenson (1992) is found to have unrealistic values in the case of a thin slab, so the diffusion equation is solved with their initial conditions to correct their solution to remove this limitation. The dipping portion of the slab begins 230 km inland, dip at an angle of 74 degrees from the surface, extend to 500 km depth, and have a thickness of 40 km. The model is extended to 21/2D by assuming the slab is infinite along its width. The strike of the slab is then solved for with the full 3D rays found from ray tracing through the iasp91 model. The strike of the dipping slab is found to be 108° clockwise from north, very similar to the strike of the TMVB. A model of the tectonic history is presented that combines those proposed by Ferrari (2004) and Gorbatov and Fukao (2005). At 25 Ma the volcanic arc moved inland marking the beginning of flat-slab subduction. At the same time a tear between the Cocos and Farallon initiated. The torsion from the tear squeezed the Cocos plate causing a flat-slab geometry. At 12.5 Ma another tear propagated along the flat Cocos slab removing the torsion causing uplift. The removal of the uplift caused the upper portion of the Cocos slab to sink and start rolling back until it reached the position where it is imaged in this study. The lack of a Wadati-Benioff zone is due to no deeper

Cocos nucifera (L.) (Arecaceae): A phytochemical and pharmacological review

PubMed Central

Lima, E.B.C.; Sousa, C.N.S.; Meneses, L.N.; Ximenes, N.C.; Santos, M.A.; Vasconcelos, G.S.; Lima, N.B.C.; Patrocínio, M.C.A.; Macedo, D.; Vasconcelos, S.M.M.

2015-01-01

Cocos nucifera (L.) (Arecaceae) is commonly called the “coconut tree” and is the most naturally widespread fruit plant on Earth. Throughout history, humans have used medicinal plants therapeutically, and minerals, plants, and animals have traditionally been the main sources of drugs. The constituents of C. nucifera have some biological effects, such as antihelminthic, anti-inflammatory, antinociceptive, antioxidant, antifungal, antimicrobial, and antitumor activities. Our objective in the present study was to review the phytochemical profile, pharmacological activities, and toxicology of C. nucifera to guide future preclinical and clinical studies using this plant. This systematic review consisted of searches performed using scientific databases such as Scopus, Science Direct, PubMed, SciVerse, and Scientific Electronic Library Online. Some uses of the plant were partially confirmed by previous studies demonstrating analgesic, antiarthritic, antibacterial, antipyretic, antihelminthic, antidiarrheal, and hypoglycemic activities. In addition, other properties such as antihypertensive, anti-inflammatory, antimicrobial, antioxidant, cardioprotective, antiseizure, cytotoxicity, hepatoprotective, vasodilation, nephroprotective, and anti-osteoporosis effects were also reported. Because each part of C. nucifera has different constituents, the pharmacological effects of the plant vary according to the part of the plant evaluated. PMID:26292222

Final report on the safety assessment of Cocos nucifera (coconut) oil and related ingredients.

PubMed

Burnett, Christina L; Bergfeld, Wilma F; Belsito, Donald V; Klaassen, Curtis D; Marks, James G; Shank, Ronald C; Slaga, Thomas J; Snyder, Paul W; Andersen, F Alan

2011-05-01

Cocos nucifera (coconut) oil, oil from the dried coconut fruit, is composed of 90% saturated triglycerides. It may function as a fragrance ingredient, hair conditioning agent, or skin-conditioning agent and is reported in 626 cosmetics at concentrations from 0.0001% to 70%. The related ingredients covered in this assessment are fatty acids, and their hydrogenated forms, corresponding fatty alcohols, simple esters, and inorganic and sulfated salts of coconut oil. The salts and esters are expected to have similar toxicological profiles as the oil, its hydrogenated forms, and its constituent fatty acids. Coconut oil and related ingredients are safe as cosmetic ingredients in the practices of use and concentration described in this safety assessment.

Behavioral Characteristics and CO+CO2 Production Rates of Halley-Type Comets Observed by NEOWISE

NASA Astrophysics Data System (ADS)

Rosser, Joshua David; Bauer, James M.; Mainzer, Amy K.; Kramer, Emily A.; Masiero, Joseph R.; Nugent, Carrie; Sonnett, Sarah M.; Fernandez, Yanga R.; Wright, Edward L.; WISE, NEOWISE

2017-10-01

From the NEOWISE dataset of comet images, 11 different Halley-Type Comets (HTCs) were identified and analyzed for dust production rates (Afρ), CO+CO2 production rates (QCO2), and nucleus size. The objects considered ranged in heliocentric distance from 1.21 AU to 2.66 AU and were only considered when showing signs of reasonable activity. When multiple epochs were included and when combined with data from previous WISE and NEOWISE studies, our dataset totaled to 21 observations; 13 of which included active comets, and 7 for which we calculated upper limits of production. Comet P/2010 JC81 was removed from consideration due to clear inactivity. For this study, active comets are defined as those which exhibit excess signal of at least 3σ in the 4.6 μm detection band, while comets for which upper limits were calculated demonstrated excess signal of 1σ in the 4.6 μm detection band. Furthermore, we confirmed the nucleus size of 27P, P/2006 HR30, C/2010 L5, P/2012 NJ, C/2016 S1. We found that given the range in heliocentric distance for this sample of HTCs, Afρ ranged from 0.790 ± 0.036 to 2.64 ± 0.14, and QCO2 ranged from 25.08 ± 0.08 to 26.71 ± 0.12. No significant correlation between dust production and heliocentric distance, nor CO+CO2 production with heliocentric distance was found for this population. This poster will display production rates and other physical properties of these HTCs, as well as place the ensemble of HTC production rate properties into context.

Etude de l'influence de la temperature et de l'humidite sur les proprietes mecaniques en traction des fibres de chanvre et de coco

NASA Astrophysics Data System (ADS)

Ho Thi, Thu Nga

L'objectif de cette etude fut d'etablir l'effet de l'humidite et de la temperature sur la resistance en traction et le module elastique des fibres de chanvre et de coco. Deux etudes ont ete realisees afin d'atteindre cet objectif. La premiere vise l'absorption de l'humidite dans ces fibres en exposition dans l'air (de 0%RH a 80%RH) ainsi que l'absorption de l'eau dans ces fibres immergees dans l'eau aux differentes temperatures. La deuxieme consiste a mesurer la resistance en traction et le module elastique de ces fibres sous differentes conditions d'humidite et de temperature. En basant sur les resultats experimentaux obtenus, les methodes semi empiriques et de reseaux de neurones ont ete utilisees pour but de predire les proprietes en traction (resistance et module d'elasticite) des fibres de chanvre et de coco sous l'influence de l'humidite et de la temperature.

Deep-Water Octocorals (Cnidaria, Anthozoa) from the Galápagos and Cocos Islands. Part 1: Suborder Calcaxonia

PubMed Central

Cairns, Stephen D.

2018-01-01

Abstract Thirteen species of deep-water calcaxonian octocorals belonging to the families Primnoidae, Chrysogorgiidae, and Isididae collected from off the Galápagos and Cocos Islands are described and figured. Seven of these species are described as new; nine of the 13 are not known outside the Galápagos region. Of the four species occurring elsewhere, two also occur in the eastern Pacific, one off Hawaii, and one from off Antarctica. A key to the 22 Indo-Pacific species of Callogorgia is provided to help distinguish those species. PMID:29416390

Toroidal, Counter-Toroidal, and Upwelling Flow in the Mantle Wedge of the Rivera and Cocos Plates: Implications for IOB Geochemistry in the Trans-Mexican Volcanic Belt

NASA Astrophysics Data System (ADS)

Neumann, Florian; Vásquez-Serrano, Alberto; Tolson, Gustavo; Negrete-Aranda, Raquel; Contreras, Juan

2016-10-01

We carried out analog laboratory modeling at a scale 1:4,000,000 and computer rendering of the flow patterns in a simulated western Middle American subduction zone. The scaled model consists of a transparent tank filled with corn syrup and housing two conveyor belts made of polyethylene strips. One of the strips dips 60° and moves at a velocity of 30 mm/min simulating the Rivera plate. The other one dips 45°, moves at 90 mm/min simulating the subduction of the Cocos plate. Our scaled subduction zone also includes a gap between the simulated slabs analogous to a tear recently observed in shear wave tomography studies. An acrylic plate 3 mm thick floats on the syrup in grazing contact with the polyethylene strips and simulates the overriding North America plate. Our experiments reveal a deep toroidal flow of asthenospheric mantle through the Cocos-Rivera separation. The flow is driven by a pressure gradient associated with the down-dip differential-motion of the slabs. Similarly, low pressure generated by the fast-moving Cocos plate creates a shallow counter-toroidal flow in the uppermost 100 km of the mantle wedge. The flow draws mantle beneath the western Trans-Mexican Volcanic Belt to the Jalisco block, then plunges into the deep mantle by the descending poloidal cell of the Cocos slab. Moreover, our model suggests a hydraulic jump causes an ~250 km asthenosphere upwelling around the area where intra-arc extensional systems converge in western Mexico. The upwelling eventually merges with the shallow counter-toroidal flow describing a motion in 3D space similar to an Archimedes' screw. Our results indicate the differential motion between subducting slabs drives mixing in the mantle wedge of the Rivera plate and allows the slab to steepen and retreat. Model results are in good agreement with seismic anisotropy studies and the geochemistry of lavas erupted in the Jalisco block. The model can explain the eruption of OIB lavas in the vicinity of the City of

Antidepressant, antioxidant and neurotrophic properties of the standardized extract of Cocos nucifera husk fiber in mice.

PubMed

Lima, Eliane Brito Cortez; de Sousa, Caren Nádia Soares; Vasconcelos, Germana Silva; Meneses, Lucas Nascimento; E Silva Pereira, Yuri Freitas; Ximenes, Naiara Coelho; Santos Júnior, Manuel Alves; Matos, Natália Castelo Branco; Brito, Rayanne; Miron, Diogo; Leal, Luzia Kalyne Almeida Moreira; Macêdo, Danielle; Vasconcelos, Silvânia Maria Mendes

2016-07-01

The plant Cocos nucifera and its derivatives have shown antidepressant-like effects, although its hydroalcoholic extract has not been studied with this end in mind. Therefore, we decided to determine the antidepressant-like effects of the standardized hydroalcoholic extract of Cocos nucifera husk fiber (HECN) as well as oxidative alterations in the prefrontal cortex (PFC), hippocampus (HC) and striatum (ST), and the levels of brain-derived neurotrophic factor (BDNF) in the HC of mice. The extract was characterized based on the content of total polyphenols as well as two phenol compounds-catechin and chlorogenic acid-by HPLC-PDA. Male animals were treated per os (p.o.) for 7 days with distilled water or HECN (50, 100 or 200 mg/kg), or intraperitoneally with vitamin E (Vit E 400 mg/kg). One hour after the last drug administration, the animals were submitted to the open field test, forced swimming test (FST), tail suspension test (TST) and, immediately after the behavioral tests, had their brain removed for neurochemical determinations. The results showed that HECN100 decreased the immobility time in the FST and TST presenting, thus demonstrating an antidepressant-like effect. The administration of HECN decreased malondialdehyde levels in all doses and brain areas studied with the exception of HECN50 in the HC. The administration of HECN also decreased nitrite levels in all doses and brain regions studied. HECN100 also increased the levels of BDNF in HC of mice. In conclusion, we demonstrated that HECN has antidepressant-like properties, probably based on its antioxidant and neurotrophic effects, and is thus relevant for the treatment of depression.

Antimalarial Activity of Cocos nucifera Husk Fibre: Further Studies.

PubMed

Adebayo, J O; Balogun, E A; Malomo, S O; Soladoye, A O; Olatunji, L A; Kolawole, O M; Oguntoye, O S; Babatunde, A S; Akinola, O B; Aguiar, A C C; Andrade, I M; Souza, N B; Krettli, A U

2013-01-01

In this study, the antimalarial and toxicity potentials of husk fibre extracts of five Nigerian varieties of Cocos nucifera were evaluated in vitro. The only active extract fraction, West African Tall (WAT) ethyl acetate extract fraction, was then evaluated for its phytochemical constituents, antimalarial and toxicity potentials at varying doses (31.25-500 mg/kg body weight) using various organ function indices. The results revealed that WAT ethyl acetate extract fraction (WATEAEF) contained alkaloids, tannins, and flavonoids and was active against Plasmodium falciparum W2 strain maintained in continuous culture, with a selectivity index of 30.3. The same extract fraction was active in vivo against Plasmodium berghei NK65, causing more than 50% reduction in parasitaemia on days 4 and 6 after inoculation at various doses administered. WATEAEF did not significantly alter (P > 0.05) function indices of the liver and cardiovascular system at all doses administered but significantly increased (P < 0.05) plasma creatinine concentration at 250 and 500 mg/Kg body weight compared to controls. The results of this study suggest that WATEAEF possesses antimalarial activity and may not adversely affect normal liver function nor predispose subjects to cardiovascular diseases but may impair normal kidney function at higher doses. Further studies are underway to isolate the active principles.

First report on the whitefly, Aleurodicus pseudugesii on the coconut palm, Cocos nucifera in Brazil.

PubMed

de Omena, Rose Paula Mendonça; Guzzo, Elio Cesar; Ferreira, Joana Maria Santos; de Mendonça, Fernando Antônio Cavalcante; de Lima, Aurino Florencio; Racca-Filho, Francisco; Santana, Antônio Euzébio Goulart

2012-01-01

The coconut palm, Cocos nucifera L. (Arecales: Arecaceae), is currently grown extensively throughout the intertropical zones of the world, including Brazil, where it constitutes an important source of income for growers. Although whiteflies are not normally considered coconut pests, these insects can damage crops directly by sucking the sap, which weakens the plant; indirect damage may be caused by sooty mold formation over the excreted honeydew and by the transmission of pathogens. Whiteflies have infested coconut plants in the northeastern, northern, and southeastern regions of Brazil. Infested materials were collected and the causative insect was identified as Aleurodicus pseudugesii Martin (Hemiptera: Aleyrodidae). This is the first report of A. pseudugesii in Brazil as a pest of the coconut palm.

Adsorption of Ni(II) onto Chemically Modified Spent Grated Coconut (Cocos Nucifera)

NASA Astrophysics Data System (ADS)

Hamzah, F. I.; Khalid, K.; Hanafiah, M. A. K. M.

2017-06-01

A new adsorbent of plant waste origin from coconut processing food factory was explored for removing Ni(II) from aqueous solutions. Several parameters such as pH, dosage, concentration and contact time were studied to obtain optimum conditions for treatment of Ni(II) contaminated wastewater. Spent grated coconut (Cocos nucifera) treated with sulfuric acid (SSGC) showed good adsorption capacity for Ni(II) ion. The amount adsorbed was affected by solution pH with the highest value achieved at pH 5. Other optimum conditions found were; dosage of 0.02 g, and 60 min of equilibrium time. Ni(II) adsorption obeyed the pseudo-second order kinetic model which suggested that chemisorption mechanism occurred in the adsorption process. The equilibrium data presented a better fitting to the Langmuir isotherm model, an indication that monolayer adsorption occurred onto a homogeneous surface. The maximum adsorption capacity, qmax was 97.09 mg g-1, thus SSGC can be classified as good and comparable with other plant waste adsorbents.

Renal metabolic profiling of early renal injury and renoprotective effects of Poria cocos epidermis using UPLC Q-TOF/HSMS/MSE.

PubMed

Zhao, Ying-Yong; Lei, Ping; Chen, Dan-Qian; Feng, Ya-Long; Bai, Xu

2013-01-01

Poria cocos epidermis is one of ancient traditional Chinese medicines (TCMs), which is usually used for the treatment of chronic kidney disease (CKD) for thousands of years in China. A metabonomic approach based on ultra performance liquid chromatography coupled with quadrupole time-of-flight high-sensitivity mass spectrometry (UPLC Q-TOF/HSMS) and a mass spectrometry(Elevated Energy) (MS(E)) data collection technique was developed to obtained a systematic view of the development and progression of CKD and biochemistry mechanism of therapeutic effects of P. cocos epidermis (Fu-Ling-Pi, FLP). By partial least squares-discriminate analysis, 19 metabolites were identified as potential biomarkers of CKD. Among the 19 biomarkers, 10 biomarkers including eicosapentaenoic acid, docosahexaenoic acid, lysoPC(20:4), lysoPC(18:2), lysoPC(15:0), lysoPE(20:0/0:0), indoxyl sulfate, hippuric acid, p-cresol sulfate and allantoin were reversed to the control level in FLP-treated groups. The study indicates that FLP treatment can ameliorate CKD by intervening in some dominating metabolic pathways, such as fatty acid metabolism, phospholipid metabolism, purine metabolism and tryptophan metabolism. This work was for the first time to investigate the FLP therapeutic effect based on metabonomics technology, which is a potentially powerful tool to study the TCMs. Copyright © 2013 Elsevier B.V. All rights reserved.

First Report on the Whitefly, Aleurodicus pseudugesii on the Coconut Palm, Cocos nucifera in Brazil

PubMed Central

de Omena, Rose Paula Mendonça; Guzzo, Elio Cesar; Ferreira, Joana Maria Santos; de Mendonça, Fernando Antônio Cavalcante; de Lima, Aurino Florencio; Racca-Filho, Francisco; Santana, Antônio Euzébio Goulart

2012-01-01

The coconut palm, Cocos nucifera L. (Arecales: Arecaceae), is currently grown extensively throughout the intertropical zones of the world, including Brazil, where it constitutes an important source of income for growers. Although whiteflies are not normally considered coconut pests, these insects can damage crops directly by sucking the sap, which weakens the plant; indirect damage may be caused by sooty mold formation over the excreted honeydew and by the transmission of pathogens. Whiteflies have infested coconut plants in the northeastern, northern, and southeastern regions of Brazil. Infested materials were collected and the causative insect was identified as Aleurodicus pseudugesii Martin (Hemiptera: Aleyrodidae). This is the first report of A. pseudugesii in Brazil as a pest of the coconut palm. PMID:22958126

Antimalarial Activity of Cocos nucifera Husk Fibre: Further Studies

PubMed Central

Adebayo, J. O.; Balogun, E. A.; Malomo, S. O.; Soladoye, A. O.; Olatunji, L. A.; Kolawole, O. M.; Oguntoye, O. S.; Babatunde, A. S.; Akinola, O. B.; Aguiar, A. C. C.; Andrade, I. M.; Souza, N. B.; Krettli, A. U.

2013-01-01

In this study, the antimalarial and toxicity potentials of husk fibre extracts of five Nigerian varieties of Cocos nucifera were evaluated in vitro. The only active extract fraction, West African Tall (WAT) ethyl acetate extract fraction, was then evaluated for its phytochemical constituents, antimalarial and toxicity potentials at varying doses (31.25–500 mg/kg body weight) using various organ function indices. The results revealed that WAT ethyl acetate extract fraction (WATEAEF) contained alkaloids, tannins, and flavonoids and was active against Plasmodium falciparum W2 strain maintained in continuous culture, with a selectivity index of 30.3. The same extract fraction was active in vivo against Plasmodium berghei NK65, causing more than 50% reduction in parasitaemia on days 4 and 6 after inoculation at various doses administered. WATEAEF did not significantly alter (P > 0.05) function indices of the liver and cardiovascular system at all doses administered but significantly increased (P < 0.05) plasma creatinine concentration at 250 and 500 mg/Kg body weight compared to controls. The results of this study suggest that WATEAEF possesses antimalarial activity and may not adversely affect normal liver function nor predispose subjects to cardiovascular diseases but may impair normal kidney function at higher doses. Further studies are underway to isolate the active principles. PMID:23983800

Complete Sequence and Comparative Analysis of the Chloroplast Genome of Coconut Palm (Cocos nucifera)

PubMed Central

Huang, Ya-Yi; Matzke, Antonius J. M.; Matzke, Marjori

2013-01-01

Coconut, a member of the palm family (Arecaceae), is one of the most economically important trees used by mankind. Despite its diverse morphology, coconut is recognized taxonomically as only a single species (Cocos nucifera L.). There are two major coconut varieties, tall and dwarf, the latter of which displays traits resulting from selection by humans. We report here the complete chloroplast (cp) genome of a dwarf coconut plant, and describe the gene content and organization, inverted repeat fluctuations, repeated sequence structure, and occurrence of RNA editing. Phylogenetic relationships of monocots were inferred based on 47 chloroplast protein-coding genes. Potential nodes for events of gene duplication and pseudogenization related to inverted repeat fluctuation were mapped onto the tree using parsimony criteria. We compare our findings with those from other palm species for which complete cp genome sequences are available. PMID:24023703

Complete sequence and comparative analysis of the chloroplast genome of coconut palm (Cocos nucifera).

PubMed

Huang, Ya-Yi; Matzke, Antonius J M; Matzke, Marjori

2013-01-01

Coconut, a member of the palm family (Arecaceae), is one of the most economically important trees used by mankind. Despite its diverse morphology, coconut is recognized taxonomically as only a single species (Cocos nucifera L.). There are two major coconut varieties, tall and dwarf, the latter of which displays traits resulting from selection by humans. We report here the complete chloroplast (cp) genome of a dwarf coconut plant, and describe the gene content and organization, inverted repeat fluctuations, repeated sequence structure, and occurrence of RNA editing. Phylogenetic relationships of monocots were inferred based on 47 chloroplast protein-coding genes. Potential nodes for events of gene duplication and pseudogenization related to inverted repeat fluctuation were mapped onto the tree using parsimony criteria. We compare our findings with those from other palm species for which complete cp genome sequences are available.

Protective and curative effects of Cocos nucifera inflorescence on alloxan-induced pancreatic cytotoxicity in rats

PubMed Central

Renjith, Raveendran S.; Rajamohan, Thankappan

2012-01-01

Objectives: This study was planned to investigate the effects of pre and post-treatment of young inflorescence of Cocos nucifera (CnI) on alloxan-induced diabetic rats. Materials and Methods: Male albino Sprague Dawely rats were divided into five groups of six animals each. Group I was normal control, Group II was diabetic control, Cocos nucifera Inflorescence (CnI) was fed along with diet [20% (w/w)] orally (Group III) for a period of 11 days prior to alloxan injection (150 mg/kg i.p.). The curative effect of CnI was evaluated at the same feeding levels in alloxan-induced diabetic rats (Group IV) for a period of 30 days. The effects of both pretreatment and post-treatment (Group V) were also evaluated. Biochemical parameters such serum glucose, hepatic glycogen, and enzymes involving carbohydrate metabolism (hexokinase, phosphoglucomutase, pyruvate kinase, glucose-6-phosphatase, fructose 1, 6-diphosphatase, glucose-6 phosphate dehydrogenase, and glycogen phosphorylase) were assayed along with pancreatic histopathology. Data were analyzed using one-way analysis of variance followed by Duncan's post hoc multiple variance test. P < 0.05 was considered statistical significant. Results: Diabetic control rats showed significant increase in serum glucose (P < 0.05) and decrease in hepatic glycogen levels (P < 0.05) compared to normal rats, which was reversed to near normal in both CnI pretreated and post-treated rats. Treatment with CnI resulted in significant decrease (P < 0.05) in activities of gluconeogenic enzymes in Group III and IV on compared to the diabetic control group, while glycolytic enzyme activities were improved in these groups. The cytotoxicity of pancreatic islets also ameliorated by treatment with CnI on histopathological examination. Conclusion: The results obtained in the study indicate the protective and curative effects of CnI on alloxan-induced pancreatic cytotoxicity, which is mediated through the regulation of carbohydrate metabolic enzyme

Conservation of coconut (Cocos nucifera L.) germplasm at sub-zero temperature.

PubMed

Sisunandar; Sopade, Peter A; Samosir, Yohannes M S; Rival, Alain; Adkins, Steve W

2012-01-01

Protocols are proposed for the low (-20 degree C) and ultra-low (-80 degree C) temperature storage of coconut (Cocos nucifera L.) embryos. A tissue dehydration step prior to storage, and a rapid warming step upon recovery optimized the protocol. The thermal properties of water located within embryos were monitored using differential scanning calorimetry (DSC). In the most efficient version of the protocol, embryos were dehydrated under a sterile air flow in a dehydration solution containing glucose (3.33 M) and glycerol (15 percent) for 16 hours. This protocol decreased the embryo water content from 77 to 29 percent FW and at the same time reduced the amount of freezable water down to 0.03 percent. The dehydrated embryos could be stored for up to 3 weeks at -20 degree C (12 percent producing normal plants upon recovery) or 26 weeks at -80 degree C (28 percent producing normal plants upon recovery). These results indicate that it is possible to store coconut germplasm on a medium term basis using an ultra-deep freezer unit. However for more efficient, long term storage, cryopreservation remains the preferred option.

Investigation of Structure and Property of Indian Cocos nucifera L. Fibre

NASA Astrophysics Data System (ADS)

Basu, Gautam; Mishra, Leena; Samanta, Ashis Kumar

2017-12-01

Structure and physico-mechanical properties of Cocos nucifera L. fibre from a specific agro-climatic region of India, was thoroughly studied. Fine structure of the fibre was examined by Fourier Transform Infra-Red (FTIR) spectroscopy, Thermo-Gravimetric Analysis (TGA), X-Ray Diffraction (XRD), component analysis, Scanning Electron Microscope (SEM) and optical microscope. SEM shows prominent longitudinal cracks and micro-pores on the surface. XRD shows a low degree of crystallinity (45%), bigger crystallite size, and even the presence of appreciable amount of non-cellulose matter. FTIR reveals presence of large quantities of hydroxyl, phenolic and aldehyde groups. Component and thermal analyses indicates presence of cellulose and lignin as major components. Physical parameters reveal that, fibres are highly variable in length (range 44-305 mm), and diameter (range 100-795 µm). Mechanical properties of the fibre viz. breaking tenacity, breaking extensibility, specific work of rupture, and coefficient of friction were measured. Microbial decomposition test under soil reveals excellent durability of coconut fibre which makes it appropriate for the application in geotextiles. Mass specific electrical resistance of 4 Ω-kg/m2 indicates its enhanced insulation as compared to the jute.

Pattern of morphological variation and diversity of Cocos nucifera (Arecaceae) in Mexico.

PubMed

Zizumbo-Villarreal, D; Piñero, D

1998-06-01

The pattern of morphological variation of Cocos nucifera in Mexico was statistically and numerically evaluated. Forty-one populations were analyzed, using 17 morphological fruit characters. Principal components and cluster analyses indicated four main groups of coconut populations that showed high similarity with four different genotypes recently imported into Mexico from areas that could be the origin of Mexican coconut populations. These four genotypes were evaluated with regard to the lethal yellowing disease in Jamaica and showed a differential susceptibility. Therefore it is possible to speculate upon a difference in susceptibility of the Mexican genotypes. The analysis of correlation between morphological and geographical distances showed a high positive correlation that supports: (1) historical evidence that indicates early introductions of coconut from different regions of the world, (2) that on both coasts of Mexico two different patterns of dispersal were involved: continuous and in jumps. Collectively these results suggest that the impact of the lethal yellowing disease on coconut populations will vary depending on the specific area and the origin of its coconuts.

Lipidomics Biomarkers of Diet-Induced Hyperlipidemia and Its Treatment with Poria cocos.

PubMed

Miao, Hua; Zhao, Yu-Hui; Vaziri, Nosratola D; Tang, Dan-Dan; Chen, Hua; Chen, Han; Khazaeli, Mahyar; Tarbiat-Boldaji, Mehrdokht; Hatami, Leili; Zhao, Ying-Yong

2016-02-03

Hyperlipidemia is a major cause of atherosclerotic cardiovascular disease. Poria cocos (PC) is a medicinal product widely used in Asia. This study was undertaken to define the alterations of lipid metabolites in rats fed a high-fat diet to induce hyperlipidemia and to explore efficacy and mechanism of action of PC in the treatment of diet-induced hyperlipidemia. Plasma samples were then analyzed using UPLC-HDMS. The untreated rats fed a high-fat diet exhibited significant elevation of plasma triglyceride and total and low-density lipoprotein (LDL) cholesterol concentrations. This was associated with marked changes in plasma concentrations of seven fatty acids (palmitic acid, hexadecenoic acid, hexanoylcarnitine, tetracosahexaenoic acid, cervonoyl ethanolamide, 3-hydroxytetradecanoic acid, and 5,6-DHET) and five sterols [cholesterol ester (18:2), cholesterol, hydroxytestosterone, 19-hydroxydeoxycorticosterone, and cholic acid]. These changes represented disorders of biosynthesis and metabolism of the primary bile acids, steroids, and fatty acids and mitochondrial fatty acid elongation pathways in diet-induced hyperlipidemia. Treatment with PC resulted in significant improvements of hyperlipidemia and the associated abnormalities of the lipid metabolites.

Unfertilized ovary: a novel explant for coconut (Cocos nucifera L.) somatic embryogenesis.

PubMed

Perera, Prasanthi I P; Hocher, Valerie; Verdeil, Jean Luc; Doulbeau, Sylvie; Yakandawala, Deepthi M D; Weerakoon, L Kaushalya

2007-01-01

Unfertilized ovaries isolated from immature female flowers of coconut (Cocos nucifera L.) were tested as a source of explants for callogenesis and somatic embryogenesis. The correct developmental stage of ovary explants and suitable in vitro culture conditions for consistent callus production were identified. The concentration of 2,4-dichlorophenoxyacetic acid (2,4-D) and activated charcoal was found to be critical for callogenesis. When cultured in a medium containing 100 microM 2,4-D and 0.1% activated charcoal, ovary explants gave rise to 41% callusing. Embryogenic calli were sub-cultured into somatic embryogenesis induction medium containing 5 microM abscisic acid, followed by plant regeneration medium (with 5 microM 6-benzylaminopurine). Many of the somatic embryos formed were complete with shoot and root poles and upon germination they gave rise to normal shoots. However, some abnormal developments were also observed. Flow cytometric analysis revealed that all the calli tested were diploid. Through histological studies, it was possible to study the sequence of the events that take place during somatic embryogenesis including orientation, polarization and elongation of the embryos.

A 2006 earthquakes series at the Colima rift and its relationship to the Rivera-Cocos plate boundary

NASA Astrophysics Data System (ADS)

Yamamoto, J.; Jimenez, Z.

2013-12-01

From July 31 through 13 August 2006 a series of fourteen earthquakes (M 3.9 to 6.1) occurred in the western end of the Central Mexican Volcanic Belt (CMVB) in twenty five days period. The most prominent earthquake (Mw 6.1) occurred on 11 August 2006 at 14:30 UTC (9:30 local time) approximately at 18.37° N, 101.25° W and 81 km depth. The epicenter was less than 40 km from Huetamo, Michoacan a 41,250-inhabitant city and 60 km from the El Infiernillo dam embayment the third largest hydroelectric plant in Mexico. This earthquake was widely felt through out the region with minor to moderate reported damage. In Mexico City 250 km away from the epicenter the earthquake, produced alarm among the population and several buildings evacuated. The earthquake series developed into two activity clusters one centered in the coast and separated about 300 km from a second inland cluster. The initial coastal cluster consisted of a nearly linear activity distribution which includes two shallow-depth earthquakes and reverse faulting mechanism with a slight left lateral strike-slip component and a possible fault planes trending roughly east-west. Two normal faulting earthquakes located at the extremes of the graben system, and fault planes oriented in a nearly north-south direction followed. The earthquakes are located approximately between the trench and the coast along the El Gordo-Colima graben system, which has been proposed as the continuation of the diffuse boundary between the Rivera and Cocos plates. The reverse faulting earthquakes are congruent either, with the expected subduction of the Rivera or Cocos plate under the North America plate and the normal faulting earthquake that can be associated to motions in the graben.

[Freshwater macroinvertebrates from Cocos Island, Costa Rica: species and comparison with other islands of the Eastern Tropical Pacific].

PubMed

Gutiérrez-Fonseca, Pablo E; Ramírez, Alonso; Umaña, Gerardo; Springer, Monika

2013-06-01

Freshwater macroinvertebrates from Cocos Island, Costa Rica: species and comparison with other islands of the Eastern Tropical Pacific. Cocos Island is an oceanic island in the Eastern Pacific, at 496km from Cabo Blanco, Costa Rica. This 24 km2 island is surrounded by a protected marine area of 9640 km2. it was declared National Park in 1978 and a World Heritage by UNESCO in 1997. Freshwater macroinvertebrate fauna was collected in 20 sites covering three rivers (Genio, Chatam and Sucio) and two creeks (Minuto and an unnamed creek behind the park rangers' house). Tank bromeliads or phytotelmata were also examined for aquatic macroinvertebrates. Physicochemical parameters were determined in 13 study sites. Additionally, a comparison with other islands in the Eastern Tropical Pacific was conducted to determine the most important factors controlling the diversity in Tropical Pacific islands. A total of 455 individuals were collected belonging to 20 taxa (mostly identified to genus level) from 15 families of aquatic insects. Other macroinvertebrates such as Palaemonid shrimps, Hidrachnida and Oligochaeta were also collected. The family Staphylinidae (Coleoptera) was the most abundant, followed by Chironomidae (Diptera). Diptera was the order of insects with the highest taxonomic richness. A relationship between distance and the number of families was observed supporting the premises of the Theory of island Biogeography. This relationship was improved by correcting area by island elevation, indicating that mountainous islands had the richest faunas, potentially due to high cloud interception that feeds freshwater environments favoring the establishment of aquatic fauna. Physicochemical variables were similar in all sites, possibly due to the geology and the absence of significant sources of pollution on the island.

Development of a heavy metal sorption system through the P=S functionalization of coconut (Cocos nucifera) fibers.

PubMed

de Sousa, Dayane Almeida; de Oliveira, Elisabeth; da Costa Nogueira, Márcio; Espósito, Breno Pannia

2010-01-01

Lignocellulosic residues are interesting materials for the production of heavy metal adsorbents for aquatic systems. Whole fibers taken from coconut (Cocos nucifera) husks were functionalized with the thiophosphoryl (P=S) group by means of the direct reaction with Cl(3)PS, (CH(3)O)(2)ClP=S or (CH(3)CH(2)O)(2)ClP=S in order to obtain an adsorptive system for 'soft' metal ions, particularly Cd(2+). These functionalized fibers (FFs) were characterized by means of elemental analysis, infrared spectroscopy, thermal analysis and acid-base titration. Adsorption isotherms for Cd(2+) fitted the Langmuir model, with binding capacities of 0.2-5 m mol g(-1) of FF at 25 degrees C.

Behavioral Characteristics and CO+CO2 Production Rates of Halley-type Comets Observed by NEOWISE

NASA Astrophysics Data System (ADS)

Rosser, J. D.; Bauer, J. M.; Mainzer, A. K.; Kramer, E.; Masiero, J. R.; Nugent, C. R.; Sonnett, S.; Fernández, Y. R.; Ruecker, K.; Krings, P.; Wright, E. L.; WISE, The; NEOWISE Teams

2018-04-01

From the entire data set of comets observed by NEOWISE, we have analyzed 11 different Halley-type Comets (HTCs) for dust production rates, CO+CO2 production rates, and nucleus sizes. Incorporating HTCs from previous studies and multiple comet visits, we have a total of 21 stacked visits, 13 of which are active and 8 for which we calculated upper limits of production. We determined the nucleus sizes of 27P, P/2006 HR30, P/2012 NJ, and C/2016 S1. Furthermore, we analyzed the relationships between dust production and heliocentric distance, and gas production and heliocentric distance. We concluded that for this population of HTCs, ranging in heliocentric distance from 1.21 to 2.66 au, there was no significant correlation between dust production and heliocentric distance, nor between gas production and heliocentric distance.

Nata de coco (NDC) hydrogel as nanoreactors for preparation iron nanoparticles (FeNps) from ferrocenium reduction

DOE Office of Scientific and Technical Information (OSTI.GOV)

Andarini, Mellissa; Lazim, Azwan

This study focuses on hydrogel as nano template to produce iron nanoparticles (FeNps). Radical polymerization was used to synthesize the hydrogel from nata de coco (NDC-g-PAA). Ferrocenium (FcCL) with 1 × 10{sup −4} g/ml has successfully incorporated with NDC-g-PAA hydrogel system and reduce using sodium hydroxide (NaOH) at different concentrations. Transmission electron microscopy (TEM) result demonstrates that the size of FeNps produced was about 5 – 20 nm. Morphological analysis of hydrogel is carried out by scanning electron microscopy (SEM), SEM-EDEX is used to determine percentage of iron (Fe) in hydrogel. The results offer a wide range of application inmore » various areas, especially the use of hydrogel system as a responsive template.« less

Paleomagnetic results from IODP Expedition 344 Site U1381 and implications for the initial subduction of the Cocos Ridge

NASA Astrophysics Data System (ADS)

Li, Yong-Xiang; Zhao, Xixi; Jovane, Luigi; Petronotis, Katerina; Gong, Zheng; Xie, Siyi

2016-04-01

Understanding the processes that govern the strength, nature, and distribution of slip along subduction zones is a fundamental and societally relevant goal of modern earth science. The Costa Rica Seismogenesis Project (CRISP) is specially designed to understand the processes that control nucleation and seismic rupture of large earthquakes at erosional subduction zones. Drilling directly on the Cocos Ridge (CR) during International Ocean Drilling Program (IODP) Expedition 344 discovered a sedimentary hiatus in Site U1381 cores. In this study, we conducted a magnetostratigraphic and rock magnetic study on the Cenozoic sedimentary sequences of site U1381. Anisotropy of magnetic susceptibility data from sediments above and below the hiatus show oblate fabrcis, but the Kmin axes of the AMS data from sediments below the hiatus are more dispersed than those from sediments above the hiatus, implying that formation of hiatus may have affected AMS. Paleomagnetic results of the U1381 core, together with available Ar-Ar dates of ash layers from sediments below the hiatus, allow us to establish a geomagnetic polarity timescale that brackets the hiatus between ca. 9.61 and 1.52 Ma. Analyses of sedimentary records from ODP/IODP cores in the vicinity reveal that the hiatus appears to be regional, spanning the northeastern end of the CR. Also, the hiatus appears to occur only at certain locations. Its regional occurrence at unique locations implies a link to the initial shallow subduction of the Cocos Ridge. The hiatus was probably produced by either bottom current erosion or the CR buckling upon its initial collision with the Middle American trench (MAT). Thus, the initial subduction of the CR must have taken place on or before 1.52 Ma.

Complete Sequence and Analysis of Coconut Palm (Cocos nucifera) Mitochondrial Genome

PubMed Central

Zhao, Yuhui; Zeng, Jingyao; Alamer, Ali; Alanazi, Ibrahim O.; Alawad, Abdullah O.; Al-Sadi, Abdullah M.; Hu, Songnian; Yu, Jun

2016-01-01

Coconut (Cocos nucifera L.), a member of the palm family (Arecaceae), is one of the most economically important crops in tropics, serving as an important source of food, drink, fuel, medicine, and construction material. Here we report an assembly of the coconut (C. nucifera, Oman local Tall cultivar) mitochondrial (mt) genome based on next-generation sequencing data. This genome, 678,653bp in length and 45.5% in GC content, encodes 72 proteins, 9 pseudogenes, 23 tRNAs, and 3 ribosomal RNAs. Within the assembly, we find that the chloroplast (cp) derived regions account for 5.07% of the total assembly length, including 13 proteins, 2 pseudogenes, and 11 tRNAs. The mt genome has a relatively large fraction of repeat content (17.26%), including both forward (tandem) and inverted (palindromic) repeats. Sequence variation analysis shows that the Ti/Tv ratio of the mt genome is lower as compared to that of the nuclear genome and neutral expectation. By combining public RNA-Seq data for coconut, we identify 734 RNA editing sites supported by at least two datasets. In summary, our data provides the second complete mt genome sequence in the family Arecaceae, essential for further investigations on mitochondrial biology of seed plants. PMID:27736909

Complete Sequence and Analysis of Coconut Palm (Cocos nucifera) Mitochondrial Genome.

PubMed

Aljohi, Hasan Awad; Liu, Wanfei; Lin, Qiang; Zhao, Yuhui; Zeng, Jingyao; Alamer, Ali; Alanazi, Ibrahim O; Alawad, Abdullah O; Al-Sadi, Abdullah M; Hu, Songnian; Yu, Jun

2016-01-01

Coconut (Cocos nucifera L.), a member of the palm family (Arecaceae), is one of the most economically important crops in tropics, serving as an important source of food, drink, fuel, medicine, and construction material. Here we report an assembly of the coconut (C. nucifera, Oman local Tall cultivar) mitochondrial (mt) genome based on next-generation sequencing data. This genome, 678,653bp in length and 45.5% in GC content, encodes 72 proteins, 9 pseudogenes, 23 tRNAs, and 3 ribosomal RNAs. Within the assembly, we find that the chloroplast (cp) derived regions account for 5.07% of the total assembly length, including 13 proteins, 2 pseudogenes, and 11 tRNAs. The mt genome has a relatively large fraction of repeat content (17.26%), including both forward (tandem) and inverted (palindromic) repeats. Sequence variation analysis shows that the Ti/Tv ratio of the mt genome is lower as compared to that of the nuclear genome and neutral expectation. By combining public RNA-Seq data for coconut, we identify 734 RNA editing sites supported by at least two datasets. In summary, our data provides the second complete mt genome sequence in the family Arecaceae, essential for further investigations on mitochondrial biology of seed plants.

Coconut (Cocos nucifera L.: Arecaceae): in health promotion and disease prevention.

PubMed

DebMandal, Manisha; Mandal, Shyamapada

2011-03-01

Coconut, Cocos nucifera L., is a tree that is cultivated for its multiple utilities, mainly for its nutritional and medicinal values. The various products of coconut include tender coconut water, copra, coconut oil, raw kernel, coconut cake, coconut toddy, coconut shell and wood based products, coconut leaves, coir pith etc. Its all parts are used in someway or another in the daily life of the people in the traditional coconut growing areas. It is the unique source of various natural products for the development of medicines against various diseases and also for the development of industrial products. The parts of its fruit like coconut kernel and tender coconut water have numerous medicinal properties such as antibacterial, antifungal, antiviral, antiparasitic, antidermatophytic, antioxidant, hypoglycemic, hepatoprotective, immunostimulant. Coconut water and coconut kernel contain microminerals and nutrients, which are essential to human health, and hence coconut is used as food by the peoples in the globe, mainly in the tropical countries. The coconut palm is, therefore, eulogised as 'Kalpavriksha' (the all giving tree) in Indian classics, and thus the current review describes the facts and phenomena related to its use in health and disease prevention. Copyright © 2011 Hainan Medical College. Published by Elsevier B.V. All rights reserved.

Effect of a polysaccharide from Poria cocos on humoral response in mice immunized by H1N1 influenza and HBsAg vaccines.

PubMed

Wu, Yajun; Li, Shuai; Li, Haixia; Zhao, Chunzhi; Ma, Hao; Zhao, Xiunan; Wu, Junhua; Liu, Kunlu; Shan, Junjie; Wang, Yuxia

2016-10-01

Poria cocos has a long history of medicinal use in China. Polysaccharides and their derivatives in the medicine exhibit many beneficial biological activities including anticancer, anti-inflammatory, antioxidant and antiviral activities. In this study, a new polysaccharide (PCP-II) was isolated from sclerotium of Poria cocos. Its physico-chemical characters were identified and its adjuvant activity was investigated in mice co-immunized with H1N1 influenza vaccine and hepatitis B surface antigen (HBsAg). The results revealed that PCP-II has a molecular weight of 29.0kDa. It was composed of fucose, mannose, glucose and galactose in molar ration of 1.00:1.63:0.16:6.29 respectively. Pharmacological data demonstrated that PCP-II increased antigen-specific antibody levels in mice immunized with influenza vaccine. PCP-II also elicited anti-HBsAg antibodies at significantly higher titers and generated robust and durable immunity compared to mice immunized with HBsAg-alum following two administrations. PCP-II improved proliferation of splenocytes, stimulated IL-12p70 and TNF-α productions in dendritic cells and macrophages respectively. These results suggested that PCP-II-adjuvanted vaccines enhanced humoral and cellular immunity. PCP-II could be developed as an efficacious adjuvant in human and animal vaccines. Copyright © 2016 Elsevier B.V. All rights reserved.

Kinetics of Reduction of CaO-FeO x -MgO-PbO-SiO2 Slags by CO-CO2 Gas Mixtures

NASA Astrophysics Data System (ADS)

Jahanshahi, Sharif; Wright, Steven

2017-08-01

Kinetics of the reaction of lead slags (PbO-CaO-SiO2-FeO x -MgO) with CO-CO2 gas mixtures was studied by monitoring the changes in the slag composition when a stream of CO-CO2 gas mixture was blown on the surface of thin layers of slags (3 to 10 mm) at temperatures in the range of 1453 K to 1593 K (1180 °C to 1320 °C). These measurements were carried out under conditions where mass transfer in the gas phase was not the rate-limiting step and the reduction rates were insensitive to factors affecting mass transfer in the slag phase. The results show simultaneous reduction of PbO and Fe2O3 in the slag. The measured specific rate of oxygen removal from the melts varied from about 1 × 10-6 to 4 × 10-5 mol O cm-2 s-1 and was strongly dependent on the slag chemistry and its oxidation state, partial pressure of CO in the reaction gas mixture, and temperature. The deduced apparent first-order rate constant increased with increasing iron oxide content, oxidation state of the slag, and temperature. The results indicate that under the employed experimental conditions, the rate of formation of CO2 at the gas-slag interface is likely to be the rate-limiting step.

The Mouse-colored Tyrannulet (Phaeomyias murina) is a species complex that includes the Cocos Flycatcher (Nesotriccus ridgwayi), an island form that underwent a population bottleneck.

PubMed

Zucker, Marc R; Harvey, Michael G; Oswald, Jessica A; Cuervo, Andrés; Derryberry, Elizabeth; Brumfield, Robb T

2016-08-01

Simultaneous examination of evolutionary history in island forms and closely related mainland relatives can provide reciprocal insight into the evolution of island and mainland faunas. The Cocos Flycatcher (Nesotriccus ridgwayi) is a small tyrant flycatcher (Tyrannidae) endemic to Cocos Island, an oceanic island in the eastern Pacific Ocean. We first established its close relationship to the mainland species Mouse-colored Tyrannulet (Phaeomyias murina) using a phylogeny from genome-wide ultraconserved elements and exons. We then used mitochondrial DNA to explore the relationships between Nesotriccus and Phaeomyias populations from across its distribution in Central and South America. We found that Nesotriccus is nested within the Phaeomyias evolutionary tree, and that Phaeomyias represents a complex of at least four evolutionarily distinct species that differ in plumage, voice, and habitat association. Nesotriccus underwent a population bottleneck subsequent to its divergence from Central American and northern South American Phaeomyias populations in the middle Pleistocene. The 46 UCE loci containing alleles that are fixed between the two species are widely distributed across the genome, which suggests that selective or neutral processes responsible for divergence have occurred genome-wide. Overall, our simultaneous examination of Phaeomyias and Nesotriccus revealed divergent levels of genetic diversity and evolutionary histories between island and mainland forms. Copyright © 2016 Elsevier Inc. All rights reserved.

NEOWISE Reactivated Mission Cometary CO+CO2: Preliminary Results from Years 1 through 3

NASA Astrophysics Data System (ADS)

Bauer, James M.; Grav, Tommy; Mainzer, Amy K.; Kramer, Emily A.; Masiero, Joseph R.; Kelley, Michael S.; Nugent, Carrie R.; Sonnett, Sarah M.; Fernandez, Yanga R.; Lisse, Casey M.; Meech, Karen Jean; Rosser, Joshua David; Walker, Russell G.; Wright, Edward L.; NEOWISE Team

2017-10-01

NEOWISE has utilized the WISE spacecraft data to provided an unpresidented number of radiometrically determined diameters and mid-infrared photometric observations of small bodies. During the WISE prime mission (January 2010 - January 2011) over 158000 solar system objects were detected by the spacecraft[1] before it was placed in hibernation in February of 2011. Of these, 164 comets were detected and characterized with respect to their dust production and particle size[2,3], CO+CO2 production[4], and diameters[5].The WISE spacecraft was reactived in 2013 and survey operations were restarted with the express purpose of searching for and characterizing solar system objects[6]. Re-named NEOWISE, the spacecraft continues to image the sky for Near-Earth objects and other small bodies at wavelengths of 3.4 and 4.6 μm, and is now into year 4 of its reactivated survey. The first 3 years of the NEOWISE reactivated mission produced detections of 11,800 objects[7,8], with a larger fraction of comets than during the cryogenic mission. Over 110 comets have been detected in the first 3 years of the reactivated survey. With NEOWISE's wavelength coverage, the survey is sensative to CO2 emission lines that are obscured by Earth's atmosphere and faint CO emission that is not easily detected from groundbased observations. We will present a preliminary analysis of this 3-year data set of comets regarding CO and CO2 production rates, tracing the behavior of these emissions at different heliocentric distances for several comets and for the ensemble of comets that show excess emission relative to dust that is indicative of CO+CO2 emission, approximately two thirds of the entire sample. We will also place these in the context of the Spitzer mission data set of targeted comet observations[9].[1] Mainzer, A. et al. 2011a, ApJ, 731, 53.[2] Kramer, E. 2014, PhD Dissertation, Univ. Central Florida.[3] Kramer, E. et al. 2017, ApJ, 838, 58.[4] Bauer, J. M. et al. 2015, ApJ, 814, 85.[5] Bauer

Biochemical and nutritional characterization of coconut (Cocos nucifera L.) haustorium.

PubMed

Manivannan, Arivalagan; Bhardwaj, Rakesh; Padmanabhan, Sugatha; Suneja, Poonam; Hebbar, K B; Kanade, Santosh R

2018-01-01

Study was conducted to determine the biochemical constituents in coconut (Cocos nucifera L.) haustorium, a spongy tissue formed during coconut germination. Results indicated that 100g of dried coconut haustorium contained 1.05±0.2% ash, 44.2±4.6% soluble sugar, 24.5±3.2% starch, 5.50±0.3% protein, 1.99±0.9% fat, 5.72±0.4% soluble dietary fibre, 20.3±1.9% insoluble dietary fibre, and 146±14.3mg phenolics. Mineral profiling showed that it contained 145±8.6, 104±9.6, 33.9±8.2, 30.9±1.9, 9.45±2.1, 0.292±0.1, 2.53±0.2 and 1.20±0.1mg of K, Mg, Ca, P, Mn, Cu, Fe and Zn, respectively. Antioxidant activity assay indicated that 100g haustorium was equivalent to 1918±173, 170±20.4, 72.8±14.7 and 860±116mg of Trolox as measured by CUPRAC, FRAP, DPPH and ABTS, respectively. Amino acid score indicated that methionine+cysteine (57.6%), phenylalanine+tyrosine (32.6%), leucine (45.7%) and isoleucine (68%) are found less in haustorium. Further studies needed in developing nutritionally balanced formulations using coconut haustorium, which will be useful for lactose intolerant children. Copyright © 2016 Elsevier Ltd. All rights reserved.

Anthelmintic activity of Cocos nucifera L. against sheep gastrointestinal nematodes.

PubMed

Oliveira, L M B; Bevilaqua, C M L; Costa, C T C; Macedo, I T F; Barros, R S; Rodrigues, A C M; Camurça-Vasconcelos, A L F; Morais, S M; Lima, Y C; Vieira, L S; Navarro, A M C

2009-01-22

The development of anthelmintic resistance has made the search for alternatives to control gastrointestinal nematodes of small ruminants imperative. Among these alternatives are several medicinal plants traditionally used as anthelmintics. This work evaluated the efficacy of Cocos nucifera fruit on sheep gastrointestinal parasites. The ethyl acetate extract obtained from the liquid of green coconut husk fiber (LGCHF) was submitted to in vitro and in vivo tests. The in vitro assay was based on egg hatching (EHT) and larval development tests (LDT) with Haemonchus contortus. The concentrations tested in the EHT were 0.31, 0.62, 1.25, 2.5 and 5 mg ml(-1), while in the LDT they were 5, 10, 20, 40 and 80 mg ml(-1). The in vivo assay was a controlled test. In this experiment, 18 sheep infected with gastrointestinal nematodes were divided into three groups (n=6), with the following doses administered: G1-400 mg kg(-1) LGCHF ethyl acetate extract, G2-0.2 mg kg(-1) moxidectin (Cydectin) and G3-3% DMSO. The worm burden was analyzed. The results of the in vitro and in vivo tests were submitted to ANOVA and analyzed by the Tukey and Kruskal-Wallis tests, respectively. The extract efficacy in the EHT and LDT, at the highest concentrations tested, was 100% on egg hatching and 99.77% on larval development. The parameters evaluated in the controlled test were not statistically different, showing that despite the significant results of the in vitro tests, the LGCHF ethyl acetate extract showed no activity against sheep gastrointestinal nematodes.

Cocos nucifera L. water improves reproductive indices in Wistar Rats.

PubMed

Kunle-Alabi, O T; Akindele, O O; Oyovwi, M O; Duro-Ladipo, M A; Raji, Y

2014-12-01

This study explored the effects of Cocos nucifera L. water (CW) on the hypothalamo-pituitary-gonadal axis (HPG) and fertility in Wistar rats. Adult male and female Wistar rats were treated orally as follows; Study 1: Group 1: control (distilled water), group 2: 20 ml/kg corn oil (danazol vehicle), group 3: 20 ml/kg CW, group 4: 40 ml/kg CW, group 5: danazol, group 6: danazol + 20 ml/kg CW and group 7: danazol + 40 ml/kg CW. 200 mg/ kg danazol was administered. Serum levels of LH, FSH, estradiol and testosterone; gonadal weights and sperm indices were assessed. Study 2: Group 1: control (distilled water), group 2: 20 ml/kg CW, group 3: 40 ml/kg CW for 6 and 2 weeks prior to mating in male and female rats respectively. Significant (p < 0.05) increases in estradiol concentration were observed in groups 3, 4, 6 and 7. Significant reductions in LH, FSH, estradiol and testosterone levels were observed in group 5 which were ameliorated in groups 6 and 7. Males showed significant increases in sperm count and motility in groups 3, 4, 6 and 7, and reductions in these variables along with viability in group 5. CW pre-treatment increased fecundity index and proportion of female pups from dams, while the pups from sires showed higher birth weights. CW acts on the HPG to positively influence reproductive function in both males and females and may aid in maternal preconception sex selection of female offspring.

Stomach nematodes (Mastophorus muris) in rats (Rattus rattus) are associated with coconut (Cocos nucifera) habitat at Palmyra Atoll.

PubMed

Lafferty, Kevin D; Hathaway, Stacie A; Wegmann, Alex S; Shipley, Frank S; Backlin, Adam R; Helm, Joel; Fisher, Robert N

2010-02-01

Black rats ( Rattus rattus ) and their stomach nematodes (Mastophorus muris) were historically introduced to islets at Palmyra Atoll in the central Pacific Line Islands. To investigate patterns of parasitism, we trapped rats and quantified nematodes on 13 islets of various sizes and habitat types. Most rats were parasitized (59%) with an average of 12 worms per infected rat. Islet size did not greatly influence parasite population biology. Nematodes also did not appear to affect rat condition (weight to skull length). The only strong and consistent factor associated with the mean abundance of nematodes in rats was habitat (dominant cover and locally dominant plant species). Thus, nematodes were much more abundant in rats from sites dominated by coconut trees (Cocos nucifera). Coconut trees may also be an introduced species at Palmyra Atoll.

Microstructural analysis and calcite piezometry on hydrothermal veins: Insights into the deformation history of the Cocos Plate at Site U1414 (IODP Expedition 344)

NASA Astrophysics Data System (ADS)

Brandstätter, Jennifer; Kurz, Walter; Rogowitz, Anna

2017-08-01

In this study we present microstructural data from hydrothermal veins in the sedimentary cover and the igneous basement recovered from Hole U1414A, Integrated Ocean Drilling Program (IODP) Expedition 344 (Costa Rica Seismogenesis Project), to constrain deformation mechanism operating in the subducting Cocos Plate. Cathodoluminescence studies, mechanical e-twin piezometry and electron backscatter diffraction (EBSD) analyses of carbonate veins were used to give insights into the deformation conditions and to help to understand the tectonic deformation history of the Cocos Plate offshore Costa Rica. Analyses of microstructures in the sedimentary rocks and in the basalt of the igneous basement reveal brittle deformation, as well as crystal-plastic deformation of the host rock and the vein material. Cathodoluminescence images showed that in the basalt fluid flow and related precipitation occurred over several episodes. The differential stresses, obtained from two different piezometers using the same parameter (twin density), indicate various mean differential stresses of 49 ± 11 and 69 ± 30 MPa and EBSD mapping of calcite veins reveals low-angle subgrain boundaries. Deformation temperatures are restricted to the range from 170°C to 220°C, due to the characteristics of the existing twins and the lack of high-temperature intracrystalline deformation mechanisms (>220°C). The obtained results suggest that deformation occurred over a period associated with changes of ambient temperatures, occurrence of fluids and hydrofracturing, induced differential stresses due to the bending of the plate at the trench, and related seismic activity.

Local and Indigenous Knowledge Regarding the Land Use and Use of Other Natural Resources in the Aspiring Rio Coco Geopark

NASA Astrophysics Data System (ADS)

Pásková, Martina

2017-12-01

There is a limited number of studies describing the situation and importance of current or potential usage of the local and indigenous traditional environmental knowledge in the region of Northern Nicaragua. To fill this gap, the author supported by a local team conducted the participative research in this rather neglected Central American region, concretely in the northern area of the aspiring Rio Coco Geopark. The purpose of this research was to identify the local and indigenous knowledge regarding the present and traditional use of natural resources including land use and to analyse the contribution and potential of the usage of this knowledge for the local development sustainability. The practical long-term impact of this research is expected mainly in the form of enhancement of the local geotourism sustainability. The research process itself was of the same importance as its results, especially the involvement of the local and indigenous people. In this participative research, young local and indigenous people obtained training and served as co-investigators who later interviewed representatives of the local households. The other field methods included life history of elders, discussions in the focal groups involving common people from local communities as well as the mapping and photo-documentation of the identified local and indigenous traditional environmental knowledge. The participative character of the research process not only facilitated the data collection and validation but also supported the revival of the community memory and revitalization of its cultural and natural identity. The research findings point out that the more distant and more dispersed are the local settlements the better conserved local and indigenous knowledge regarding the traditional land use and other use of natural resources is. Among the best-conserved local and indigenous traditional environmental knowledge in the northern area of the aspiring Rio Coco Geopark was the usage of

Stomach nematodes (Mastophorus Muris) in rats (Rattus rattus) are associated with coconut (Cocos nucifera) Habitat at palmyra atoll

USGS Publications Warehouse

Lafferty, K.D.; Hathaway, S.A.; Wegmann, A.S.; Shipley, F.S.; Backlin, A.R.; Helm, J.; Fisher, R.N.

2010-01-01

Black rats (Rattus rattus) and their stomach nematodes (Mastophorus muris) were historically introduced to islets at Palmyra Atoll in the central Pacific Line Islands. To investigate patterns of parasitism, we trapped rats and quantified nematodes on 13 islets of various sizes and habitat types. Most rats were parasitized (59) with an average of 12 worms per infected rat. Islet size did not greatly influence parasite population biology. Nematodes also did not appear to affect rat condition (weight to skull length). The only strong and consistent factor associated with the mean abundance of nematodes in rats was habitat (dominant cover and locally dominant plant species). Thus, nematodes were much more abundant in rats from sites dominated by coconut trees (Cocos nucifera). Coconut trees may also be an introduced species at Palmyra Atoll. ?? American Society of Parasitologists 2010.

Leishmanicidal activity of polyphenolic-rich extract from husk fiber of Cocos nucifera Linn. (Palmae).

PubMed

Mendonça-Filho, Ricardo R; Rodrigues, Igor A; Alviano, Daniela S; Santos, André L S; Soares, Rosangela M A; Alviano, Celuta S; Lopes, Angela H C S; Rosa, Maria do Socorro S

2004-04-01

The available therapy for leishmaniasis, which affects 2 million people per annum, still causes serious side effects. The polyphenolic-rich extract from the husk fiber of Cocos nucifera Linn. (Palmae) presents antibacterial and antiviral activities, also inhibiting lymphocyte proliferation, as shown by our group in previous works. In the present study, the in vitro leishmanicidal effects of C. nucifera on Leishmania amazonensis were evaluated. The minimal inhibitory concentration of the polyphenolic-rich extract from C. nucifera to completely abrogate parasite growth was 10 microg/ml. Pretreatment of peritoneal mouse macrophages with 10 microg/ml of C. nucifera polyphenolic-rich extract reduced approximately 44% the association index between these macrophages and L. amazonensis promastigotes, with a concomitant increase of 182% in nitric oxide production by the infected macrophage in comparison to nontreated macrophages. These results provide new perspectives on drug development against leishmaniasis, since the extract of C. nucifera at 10 microg/ml is a strikingly potent leishmanicidal substance which inhibited the growth of both promastigote and amastigote developmental stages of L. amazonensis after 60 min, presenting no in vivo allergenic reactions or in vitro cytotoxic effects in mammalian systems.

Modelling the growth of Listeria monocytogenes in fresh green coconut (Cocos nucifera L.) water.

PubMed

Walter, Eduardo H M; Kabuki, Dirce Y; Esper, Luciana M R; Sant'Ana, Anderson S; Kuaye, Arnaldo Y

2009-09-01

The behaviour of Listeria monocytogenes in the fresh coconut water stored at 4 degrees C, 10 degrees C and 35 degrees C was studied. The coconut water was aseptically extracted from green coconuts (Cocos nucifera L.) and samples were inoculated in triplicate with a mixture of 5 strains of L. monocytogenes with a mean population of approximately 3 log(10) CFU/mL. The kinetic parameters of the bacteria were estimated from the Baranyi model, and compared with predictions of the Pathogen Modelling Program so as to predict its behaviour in the beverage. The results demonstrated that fresh green coconut water was a beverage propitious for the survival and growth of L. monocytogenes and that refrigeration at 10 degrees C or 4 degrees C retarded, but did not inhibit, growth of this bacterium. Temperature abuse at 35 degrees C considerably reduced the lagtimes. The study shows that L. monocytogenes growth in fresh green coconut water is controlled for several days by storage at low temperature, mainly at 4 degrees C. Thus, for risk population this product should only be drunk directly from the coconut or despite the sensorial alterations should be consumed pasteurized.

Effects of copra (Cocos nucifera) meal on the growth performance of Cyprinus carpio

NASA Astrophysics Data System (ADS)

Yusup, Cep Hikmat Maulana; Nugroho, Rudy A.

2017-02-01

This research aimed to evaluate the optimum concentration of copra meal as a fish meal replacement on the growth performance of Cyprinus carpio. Various concentrations of copra (Cocos nucifera) meal, viz 3, 6, 9, and 12 % were used to determine the final weight, body weight gain (BWG), average weekly gain (AWG), daily weight gain (DWG), specific growth rate (SGR), protein efficiency ratio (PER), feed conversion ratio (FCR) of the C. carpio (Initial body weight 25-25.2 g/fish) and compare with control group (Basal diet) without copra meal replacement and commercial diet (CD). Six groups of C. carpio with three replicates were used and fed with different concentration of copra meal at satiation level five times per day for 12 weeks. At the end of feeding trial, the C. carpio fed 9% copra meal in the diet had higher final weight, BWG, AWG, DWG, SGR than any other groups, except commercial diet (CD). Meanwhile, the highest PER was found on the fish fed CD, followed by fish fed 3 % of copra meal in the diet. However, FCR was not affected by any types of diets. These finding suggested that the 9% replacement of wheat in the diet with copra meal is beneficial to improve growth performance.

Determination of specific activity of cobalt (60Co/Co) in steel samples exposed to the atomic bomb in Hiroshima.

PubMed

Kimura, T; Takano, N; Iba, T; Fujita, S; Watanabe, T; Maruyama, T; Hamada, T

1990-06-01

Specific activity 60Co/Co in two steel samples taken at 687m S and 1295m NNW from the hypocenter was measured by gamma-ray spectrometry and neutron activation analysis. The results were, respectively, (2.64 +/- 0.38) x 10(1) and (3.09 +/- 0.48) x 10(-1) dpm/mg Co at the time of bombing, which are consistent with previous data by Hashizume et al. for steel rings on the surface of roofs of buildings. The present data are expected to serve as verification of the bomb neutron transport calculations. Content of nickel and copper in the samples, determined by colorimetric and neutron activation methods, respectively, was too small to account for any significant 60Co production by the (n,p) and (n, alpha) reactions.

Microstructural analysis and calcite piezometry on hydrothermal veins: Insights into the deformation history of the Cocos Plate at Site U1414 (IODP Expedition 344).

PubMed

Brandstätter, Jennifer; Kurz, Walter; Rogowitz, Anna

2017-08-01

In this study we present microstructural data from hydrothermal veins in the sedimentary cover and the igneous basement recovered from Hole U1414A, Integrated Ocean Drilling Program (IODP) Expedition 344 (Costa Rica Seismogenesis Project), to constrain deformation mechanism operating in the subducting Cocos Plate. Cathodoluminescence studies, mechanical e-twin piezometry and electron backscatter diffraction (EBSD) analyses of carbonate veins were used to give insights into the deformation conditions and to help to understand the tectonic deformation history of the Cocos Plate offshore Costa Rica. Analyses of microstructures in the sedimentary rocks and in the basalt of the igneous basement reveal brittle deformation, as well as crystal-plastic deformation of the host rock and the vein material. Cathodoluminescence images showed that in the basalt fluid flow and related precipitation occurred over several episodes. The differential stresses, obtained from two different piezometers using the same parameter (twin density), indicate various mean differential stresses of 49 ± 11 and 69 ± 30 MPa and EBSD mapping of calcite veins reveals low-angle subgrain boundaries. Deformation temperatures are restricted to the range from 170°C to 220°C, due to the characteristics of the existing twins and the lack of high-temperature intracrystalline deformation mechanisms (>220°C). The obtained results suggest that deformation occurred over a period associated with changes of ambient temperatures, occurrence of fluids and hydrofracturing, induced differential stresses due to the bending of the plate at the trench, and related seismic activity.

Microstructural analysis and calcite piezometry on hydrothermal veins: Insights into the deformation history of the Cocos Plate at Site U1414 (IODP Expedition 344)

PubMed Central

Kurz, Walter; Rogowitz, Anna

2017-01-01

Abstract In this study we present microstructural data from hydrothermal veins in the sedimentary cover and the igneous basement recovered from Hole U1414A, Integrated Ocean Drilling Program (IODP) Expedition 344 (Costa Rica Seismogenesis Project), to constrain deformation mechanism operating in the subducting Cocos Plate. Cathodoluminescence studies, mechanical e‐twin piezometry and electron backscatter diffraction (EBSD) analyses of carbonate veins were used to give insights into the deformation conditions and to help to understand the tectonic deformation history of the Cocos Plate offshore Costa Rica. Analyses of microstructures in the sedimentary rocks and in the basalt of the igneous basement reveal brittle deformation, as well as crystal‐plastic deformation of the host rock and the vein material. Cathodoluminescence images showed that in the basalt fluid flow and related precipitation occurred over several episodes. The differential stresses, obtained from two different piezometers using the same parameter (twin density), indicate various mean differential stresses of 49 ± 11 and 69 ± 30 MPa and EBSD mapping of calcite veins reveals low‐angle subgrain boundaries. Deformation temperatures are restricted to the range from 170°C to 220°C, due to the characteristics of the existing twins and the lack of high‐temperature intracrystalline deformation mechanisms (>220°C). The obtained results suggest that deformation occurred over a period associated with changes of ambient temperatures, occurrence of fluids and hydrofracturing, induced differential stresses due to the bending of the plate at the trench, and related seismic activity. PMID:29081570

Control of concerted two bond versus single bond dissociation in CH(3)Co(CO)(4) via an intermediate state using pump-dump laser pulses.

PubMed

Ambrosek, David; González, Leticia

2007-10-07

Wavepacket propagations on ab initio multiconfigurational two-dimensional potential energy surfaces for CH(3)Co(CO)(4) indicate that after irradiation to the lowest first and second electronic excited states, concerted dissociation of CH(3) and the axial CO ligand takes place. We employ a pump-dump sequence of pulses with appropriate frequencies and time delays to achieve the selective breakage of a single bond by controlling the dissociation angle. The pump and dump pulse sequence exploits the unbound surface where dissociation occurs in a counterintuitive fashion; stretching of one bond in an intermediate state enhances the single dissociation of the other bond.

Molecular cloning of a Poria cocos protein that activates Th1 immune response and allays Th2 cytokine and IgE production in a murine atopic dermatitis model.

PubMed

Lu, Ya-Ting; Kuan, Yen-Chou; Chang, Hui-Hsin; Sheu, Fuu

2014-04-02

Edible fungus Poria cocos (Schw.) Wolf is a cooking material that has myriad health benefits. However, its active constituents have not been well-defined. We previously purified an immunomodulatory protein, PCP, from P. cocos and described its biochemical features and its ability to activate primary macrophage via TLR4. In this study, we cloned the gene of PCP and demonstrated its ability to activate Th1 response in cell cultures and in mice. The complete cDNA sequence of PCP consisted of 807 bp, which included a 579 bp coding sequence that encoded 194 amino acids. With the addition of co-stimulatory CD3/CD28 signals, PCP significantly increased the surface expression of CD44 and CD69 on effector T cells. PCP could also up-regulate T-bet and STAT4 expressions and IFN-γ and IL-2 secretions. Oral administration of PCP suppressed the production of both total and OVA-specific IgG1 in serum and enhanced the amounts of serum and OVA-specific IgG2a and Th1-related cytokine production in BALB/c splenocytes. In addition, oral administration of PCP significantly reduced IL-4 and IgE expressions in a murine model of atopic dermatitis. In conclusion, these results provide evidence that PCP could regulate mammalian immune cells and reveal their pharmaceutical potential in developing therapeutic strategies against Th2-mediated immune disorders.

Assessing the influence of regional transport from Mainland China over the Korean Peninsula during the 2016 KORUS-AQ Field Campaign with CO/CO2 ratios

NASA Astrophysics Data System (ADS)

Halliday, H. S.; DiGangi, J. P.; Diskin, G. S.; Choi, Y.; Pusede, S.; Rana, M.; Nowak, J. B.

2017-12-01

The industrial growth in East Asia has resulted in widespread growth and prosperity, but has been accompanied by degraded air quality. These poor air quality events have both local and regional effects, and long range transportation of pollution can greatly increase the affected populations. South Korea has a technologically oriented economy with vibrant urban regions, but suffers from poor air quality arising from both local emissions on the Korean peninsula and from the transport of pollution from Mainland China. The KORUS-AQ field campaign was an international collaboration to characterize and understand the air quality over the Korean peninsula in the spring of 2016. We use the aircraft in situ data from the DC-8 aircraft to examine trace gas ratios over three major analysis regions: the Seoul Metropolitan region, the South Korean peninsula, and the West Sea (Yellow Sea). We look specifically at the correlations between CO and CO2 as an indicator of emissions type, with low ratios generally indicative of more efficient combustion and high emission ratios indicating low efficiency combustion. At low altitudes, higher incidences of low CO/CO2 ratios were observed in the Seoul and Peninsula regions, compared to higher ratios of CO/CO2 over the West Sea. We examine the meteorological dependence of these carbon species ratios, their relationships to VOC tracers, and their vertical behavior to evaluate the air mass contributions from Mainland China and assess the percentage contributions of these regional emissions to the measurements over the Korean Peninsula.

Addition of a combination of onion (Allium cepa) and coconut (Cocos nucifera) to food of sheep stops gastrointestinal helminthic infections.

PubMed

Mehlhorn, Heinz; Al-Quraishy, Saleh; Al-Rasheid, Khaled A S; Jatzlau, Antje; Abdel-Ghaffar, Fathy

2011-04-01

Sheep with gastrointestinal nematodes and cestodes were fed on three farms with a combination of specially prepared extracts of onion (Allium cepa) and coconut (Cocos nucifera) for 8 days containing each 60 g coconut and onion extract, combined with milk powder and/or polyethylene glycol (PEG) propylencarbonate (PC). In all cases, the worm stages disappeared from the feces and were also not found 9 and 20 days after the end of the feeding with this plant combination. Since all treated animals increased their body weight considerably (when compared to untreated animals), worm reduction was apparently as effective as it was shown in previous laboratory trials with rats and mice (Klimpel et al., Parasitol Res, in press, 2010; Abdel-Ghaffar et al., Parasitol Res, in press, 2010; in this volume).

Pb-isotopic Features of Primitive Rocks from Hess Deep: Distinguishing between EPR and Cocos-Nazca Mantle Source(s)

NASA Astrophysics Data System (ADS)

Jean, M. M.; Falloon, T.; Gillis, K. M.

2014-12-01

We have acquired high-precision Pb-isotopic signatures of primitive lithologies (basalts/gabbros) recovered from IODP Expedition 345.The Hess Deep Rift, located in the vicinity of the Galapagos triple junction (Cocos, Nazca, and Pacific), is viewed as one the best-studied tectonic windows into fast-spreading crust because a relatively young (<1.5 Ma) cross section of oceanic crust. This allows for (1) characterization of the mantle source(s) at Hess Deep, (2) insight into the extent of isotopic homogeneity or heterogeneity in the area, and (3) constrain the relative contributions from the intruding Cocos-Nazca spreading center. The observed Pb-isotopic variation at Hess Deep covers almost the entire range of EPR MORB (10°N to -5°S). Hess Deep samples range from 208Pb (37.3-38.25), 207Pb (15.47-15.58), 206Pb (17.69-18.91). These compositions suggest that this part of Hess Deep mantle is no more isotopically homogeneous than EPR mantle. Two distinct arrays are also observed: 208Pb-enriched (r2=0.985; n=30) and 208Pb-depleted (r2=0.988; n=6). The 208Pb/204Pb isotopes indicates that the Pb-source for some of the samples at Hess Deep had very low Th/U ratios, whereas other areas around the Galapagos microplate seem to have more "normal" ratios. These trends are less apparent when viewed with 207Pb-isotopes. Instead, the majority of basalts and gabbros follow the NHRL, however, at the depleted-end of this array a negative excursion to more enriched compositions is observed. This negative but linear trend could signify an alteration trend or mixing with an EMI-type mantle source, yet this mixing is not observed with 208Pb. This trend is also observed at Pito Deep, which has similar origins to Hess Deep (Barker et al., 2008; Pollack et al., 2009). The Galapagos region has been considered a testing ground for mixing of HIMU, Enriched Mantle, and Depleted Mantle reservoirs (e.g., Schilling et al., 2002). According to our data, however, an EPR-component must also be

Independent Origins of Cultivated Coconut (Cocos nucifera L.) in the Old World Tropics

PubMed Central

Gunn, Bee F.; Baudouin, Luc; Olsen, Kenneth M.

2011-01-01

As a portable source of food, water, fuel, and construction materials, the coconut (Cocos nucifera L.) played a fundamental role in human migrations and the development of civilization across the humid tropics. Here we investigated the coconut's domestication history and its population genetic structure as it relates to human dispersal patterns. A sample of 1,322 coconut accessions, representing the geographical and phenotypic diversity of the species, was examined using ten microsatellite loci. Bayesian analyses reveal two highly genetically differentiated subpopulations that correspond to the Pacific and Indo-Atlantic oceanic basins. This pattern suggests independent origins of coconut cultivation in these two world regions, with persistent population structure on a global scale despite long-term human cultivation and dispersal. Pacific coconuts show additional genetic substructure corresponding to phenotypic and geographical subgroups; moreover, the traits that are most clearly associated with selection under human cultivation (dwarf habit, self-pollination, and “niu vai” fruit morphology) arose only in the Pacific. Coconuts that show evidence of genetic admixture between the Pacific and Indo-Atlantic groups occur primarily in the southwestern Indian Ocean. This pattern is consistent with human introductions of Pacific coconuts along the ancient Austronesian trade route connecting Madagascar to Southeast Asia. Admixture in coastal east Africa may also reflect later historic Arab trading along the Indian Ocean coastline. We propose two geographical origins of coconut cultivation: island Southeast Asia and southern margins of the Indian subcontinent. PMID:21731660

Independent origins of cultivated coconut (Cocos nucifera L.) in the old world tropics.

PubMed

Gunn, Bee F; Baudouin, Luc; Olsen, Kenneth M

2011-01-01

As a portable source of food, water, fuel, and construction materials, the coconut (Cocos nucifera L.) played a fundamental role in human migrations and the development of civilization across the humid tropics. Here we investigated the coconut's domestication history and its population genetic structure as it relates to human dispersal patterns. A sample of 1,322 coconut accessions, representing the geographical and phenotypic diversity of the species, was examined using ten microsatellite loci. Bayesian analyses reveal two highly genetically differentiated subpopulations that correspond to the Pacific and Indo-Atlantic oceanic basins. This pattern suggests independent origins of coconut cultivation in these two world regions, with persistent population structure on a global scale despite long-term human cultivation and dispersal. Pacific coconuts show additional genetic substructure corresponding to phenotypic and geographical subgroups; moreover, the traits that are most clearly associated with selection under human cultivation (dwarf habit, self-pollination, and "niu vai" fruit morphology) arose only in the Pacific. Coconuts that show evidence of genetic admixture between the Pacific and Indo-Atlantic groups occur primarily in the southwestern Indian Ocean. This pattern is consistent with human introductions of Pacific coconuts along the ancient Austronesian trade route connecting Madagascar to Southeast Asia. Admixture in coastal east Africa may also reflect later historic Arab trading along the Indian Ocean coastline. We propose two geographical origins of coconut cultivation: island Southeast Asia and southern margins of the Indian subcontinent.

Reduction of Hematite to Magnetite in CO/CO2 Gas Mixtures Under Carbon Looping Combustion Conditions

NASA Astrophysics Data System (ADS)

Simmonds, Tegan; Hayes, Peter C.

2017-12-01

Iron oxides have been identified as promising materials for use as oxygen carriers in chemical looping combustion technologies as there are abundant resources available in the form of ore and in industrial wastes. The isothermal reduction of hematite (Fe2O3) in the fuel reactor and the subsequent oxidation of magnetite (Fe3O4) in air are the principal reactions of interest for these applications. Experimental investigations have been carried out to characterize the microstructural changes taking place as a result of the reduction reactions for a range of CO/CO2 gas compositions at temperatures between 1073 K and 1373 K (800 °C and 1100 °C). It has been shown that magnetite spinel is formed directly from hematite under these conditions and that porous magnetite or dense platelet or "lath" type morphologies can be formed depending on gas composition and reaction temperature. The conditions for the lath/pore transition are established. Dendritic gas pores are formed during the creation of the porous magnetite. This morphology allows continuous contact between the gas reactant and reaction interface and results in high reduction reaction rates.

Poria cocos polysaccharide attenuates RANKL-induced osteoclastogenesis by suppressing NFATc1 activity and phosphorylation of ERK and STAT3.

PubMed

Song, Dezhi; Cao, Zhen; Tickner, Jennifer; Qiu, Heng; Wang, Chao; Chen, Kai; Wang, Ziyi; Guo, Chunyu; Dong, Shiwu; Xu, Jiake

2018-06-01

Pathological fractures caused by osteolytic lesions seriously threaten the health of patients. Osteoclasts play important roles in bone resorption whose hyperfunction are closely related to osteolytic lesions. Studies on osteoclast differentiation and function assist in the prevention of excessive bone loss associated diseases. We screened a variety of natural compounds with anti-inflammatory effect and found that poria cocos polysaccharide (PCP) inhibited RANKL-induced osteoclast formation and bone resorption via TRAcP staining, immunofluorescence, RT-PCR and western blot. PCP down-regulated phosphorylation of STAT3, P38, ERK and JNK, and thus repressed the expression of NFAcT1 and c-Fos during RANKL-induced osteoclastogenesis. Besides, the expression of bone resorption related genes such as TRAcP and CTSK was suppressed by PCP. The results suggest that PCP can be invoked as a candidate for the treatment of osteolytic diseases by inhibiting osteoclastogenesis. Copyright © 2018 Elsevier Inc. All rights reserved.

Co@Co3O4 Encapsulated in Carbon Nanotube-Grafted Nitrogen-Doped Carbon Polyhedra as an Advanced Bifunctional Oxygen Electrode.

PubMed

Aijaz, Arshad; Masa, Justus; Rösler, Christoph; Xia, Wei; Weide, Philipp; Botz, Alexander J R; Fischer, Roland A; Schuhmann, Wolfgang; Muhler, Martin

2016-03-14

Efficient reversible oxygen electrodes for both the oxygen reduction reaction (ORR) and the oxygen evolution reaction (OER) are vitally important for various energy conversion devices, such as regenerative fuel cells and metal-air batteries. However, realization of such electrodes is impeded by insufficient activity and instability of electrocatalysts for both water splitting and oxygen reduction. We report highly active bifunctional electrocatalysts for oxygen electrodes comprising core-shell Co@Co3O4 nanoparticles embedded in CNT-grafted N-doped carbon-polyhedra obtained by the pyrolysis of cobalt metal-organic framework (ZIF-67) in a reductive H2 atmosphere and subsequent controlled oxidative calcination. The catalysts afford 0.85 V reversible overvoltage in 0.1 m KOH, surpassing Pt/C, IrO2 , and RuO2 and thus ranking them among one of the best non-precious-metal electrocatalysts for reversible oxygen electrodes. © 2016 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

Anti-inflammatory, antioxidant, and antimicrobial activities of Cocos nucifera var. typica

PubMed Central

2013-01-01

Background Teas from the husk fiber of Cocos nucifera are used in the folk medicine to treat arthritis and other inflammatory processes. Some works show that some varieties have biological activities. However, one of the main variety of the species, C. nucifera var. typica, known in Brazil as “gigante”, was not studied yet. Thus, this study evaluates if this variety has the anti-inflammatory and antimicrobial activities already reported in other varieties. Methods C. nucifera aqueous crude extract (10, 50, and 100 mg/kg) and the reference drugs morphine (1 mg/kg) and acetylsalicylic acid (100 mg/kg) were evaluated in models of inflammation (formalin-induced licking and subcutaneous air pouch). The antioxidant activity was evaluated by 2,2-diphenyl-1-picryl-hydrazyl-hydrate (DPPH) photometric assay and compared with those of the standards (quercetin, rutin, and ascorbic acid). The extract was also screened against Candida albicans, Escherichia coli, Staphylococcus aureus, and methicillin-resistant Staphylococcus aureus (MRSA), in the agar diffusion method. The minimal inhibitory concentration (MIC) and minimal bactericidal concentration (MBC) were determined by the broth micro-dilution assay. Activities of combinations of the extract and antibiotics (methicillin or vancomycin) against MRSA were evaluated using checkerboard assays. Results The extract significantly inhibited the time that the animals spent licking the formalin-injected paws (second phase). The extract also inhibited the inflammatory process induced by subcutaneous carrageenan injection by reducing cell migration, protein extravasation, and TNF-α production. Additionally, the extract showed an antioxidant potential in vitro as good as standards in their antioxidant activity. The extract was active only against S. aureus and MRSA. MIC and the bactericidal concentrations were identical (1,024 μg/ml). The extract and methicillin acted synergistically against the clinical MRSA isolate, whereas an

Anti-inflammatory, antioxidant, and antimicrobial activities of Cocos nucifera var. typica.

PubMed

Silva, Rafaela Ribeiro; Oliveira e Silva, Davi; Fontes, Humberto Rollemberg; Alviano, Celuta Sales; Fernandes, Patricia Dias; Alviano, Daniela Sales

2013-05-16

Teas from the husk fiber of Cocos nucifera are used in the folk medicine to treat arthritis and other inflammatory processes. Some works show that some varieties have biological activities. However, one of the main variety of the species, C. nucifera var. typica, known in Brazil as "gigante", was not studied yet. Thus, this study evaluates if this variety has the anti-inflammatory and antimicrobial activities already reported in other varieties. C. nucifera aqueous crude extract (10, 50, and 100 mg/kg) and the reference drugs morphine (1 mg/kg) and acetylsalicylic acid (100 mg/kg) were evaluated in models of inflammation (formalin-induced licking and subcutaneous air pouch). The antioxidant activity was evaluated by 2,2-diphenyl-1-picryl-hydrazyl-hydrate (DPPH) photometric assay and compared with those of the standards (quercetin, rutin, and ascorbic acid). The extract was also screened against Candida albicans, Escherichia coli, Staphylococcus aureus, and methicillin-resistant Staphylococcus aureus (MRSA), in the agar diffusion method. The minimal inhibitory concentration (MIC) and minimal bactericidal concentration (MBC) were determined by the broth micro-dilution assay. Activities of combinations of the extract and antibiotics (methicillin or vancomycin) against MRSA were evaluated using checkerboard assays. The extract significantly inhibited the time that the animals spent licking the formalin-injected paws (second phase). The extract also inhibited the inflammatory process induced by subcutaneous carrageenan injection by reducing cell migration, protein extravasation, and TNF-α production. Additionally, the extract showed an antioxidant potential in vitro as good as standards in their antioxidant activity. The extract was active only against S. aureus and MRSA. MIC and the bactericidal concentrations were identical (1,024 μg/ml). The extract and methicillin acted synergistically against the clinical MRSA isolate, whereas an indifferent effect was detected

Distributed deformation ahead of the Cocos-Nazca Rift at the Galapagos triple junction

NASA Astrophysics Data System (ADS)

Smith, Deborah K.; Schouten, Hans; Zhu, Wen-lu; Montési, Laurent G. J.; Cann, Johnson R.

2011-11-01

The Galapagos triple junction is not a simple ridge-ridge-ridge (RRR) triple junction. The Cocos-Nazca Rift (C-N Rift) tip does not meet the East Pacific Rise (EPR). Instead, two secondary rifts form the link: Incipient Rift at 2°40‧N and Dietz Deep volcanic ridge, the southern boundary of the Galapagos microplate (GMP), at 1°10‧N. Recently collected bathymetry data are used to investigate the regional tectonics prior to the establishment of the GMP (∼1.5 Ma). South of C-N Rift a band of northeast-trending cracks cuts EPR-generated abyssal hills. It is a mirror image of a band of cracks previously identified north of C-N Rift on the same age crust. In both areas, the western ends of the cracks terminate against intact abyssal hills suggesting that each crack initiated at the EPR spreading center and cut eastward into pre-existing topography. Each crack formed a short-lived triple junction until it was abandoned and a new crack and triple junction initiated nearby. Between 2.5 and 1.5 Ma, the pattern of cracking is remarkably symmetric about C-N Rift providing support for a crack interaction model in which crack initiation at the EPR axis is controlled by stresses associated with the tip of the westward-propagating C-N Rift. The model also shows that offsets of the EPR axis may explain times when cracking is not symmetric. South of C-N Rift, cracks are observed on seafloor as old as 10.5 Ma suggesting that this triple junction has not been a simple RRR triple junction during that time.

Whole-plant adjustments in coconut (Cocos nucifera) in response to sink-source imbalance.

PubMed

Mialet-Serra, I; Clement-Vidal, A; Roupsard, O; Jourdan, C; Dingkuhn, M

2008-08-01

Coconut (Cocos nucifera L.) is a perennial tropical monocotyledon that produces fruit continuously. The physiological function of the large amounts of sucrose stored in coconut stems is unknown. To test the hypothesis that reserve storage and mobilization enable the crop to adjust to variable sink-source relationships at the scale of the whole plant, we investigated the dynamics of dry matter production, yield and yield components, and concentrations of nonstructural carbohydrate reserves in a coconut plantation on Vanuatu Island in the South Pacific. Two treatments were implemented continuously over 29 months (April 2002 to August 2004): 50% leaf pruning (to reduce the source) and 100% fruit and inflorescence pruning (to reduce the sink). The pruning treatments had little effect on carbohydrate reserves because they affected only petioles, not the main reserve pool in the stem. Both pruning treatments greatly reduced dry matter production of the reproductive compartment, but vegetative growth and development were negligibly affected by treatment and season. Leaf pruning increased radiation-use efficiency (RUE) initially, and fruit pruning greatly reduced RUE throughout the experiment. Changes in RUE were negatively correlated with leaflet soluble sugar concentration, indicating feedback inhibition of photosynthesis. We conclude that vegetative development and growth of coconut show little phenotypic plasticity, assimilate demand for growth being largely independent of a fluctuating assimilate supply. The resulting sink-source imbalances were partly compensated for by transitory reserves and, more importantly, by variable RUE in the short term, and by adjustment of fruit load in the long term. Possible physiological mechanisms are discussed, as well as modeling concepts that may be applied to coconut and similar tree crops.

Effect of drying on the porosity of the hydroxyapatite and cellulose nata de coco compositeas bone graft candidate

NASA Astrophysics Data System (ADS)

Anitasari, S.; Mu’ti, A.; Hutahaean, YO

2018-04-01

Bone graft is used to replace bone parts damaged by illness and accident. As a bone replacement material, the bone graft should be able to stimulate the process of the osteogenesis. The process of osteogenesis is influenced by the osteoconductive properties of a biomaterial, that porosity affects this process. The shells of blood scallop (Anadaragranosa) are producing hydroxyapatite (HAp),having high compressive strength, biocompatibility and osteoconductive properties, but low porosity while cellulose nata de coco (Cnc) have low compressive strength but high porosity. Therefore, the combination of two biomaterials are expected to produce composite that have high osteoconductive properties. The purpose of this research wasknowing the porosity of HAp/Cnc composite which wasbeingprecipitated for 5 hours, 15 hours, 25 hours and wasdried for 24 hours, 48 hours and 72 hours. This research usedwise drop technique to synthesis HAp powder and cellulose immersion technique for synthesis of HAp/Cnc. Results of this research, there was difference in porosity between HAp/Cnc that was precipitated for 5 hours, 15 hours and 25 hours, as well as was dried for 1 day, 2 days and 3 days. The conclusion, the synthesis of HAp/Cncwasuseful as bone graft candidate.

Abundance and Distribution Patterns of Thunnus albacares in Isla del Coco National Park through Predictive Habitat Suitability Models.

PubMed

Gonzáles-Andrés, Cristina; F M Lopes, Priscila; Cortés, Jorge; Sánchez-Lizaso, José Luis; Pennino, Maria Grazia

2016-01-01

Information on the distribution and habitat preferences of ecologically and commercially important species is essential for their management and protection. This is especially important as climate change, pollution, and overfishing change the structure and functioning of pelagic ecosystems. In this study, we used Bayesian hierarchical spatial-temporal models to map the Essential Fish Habitats of the Yellowfin tuna (Thunnus albacares) in the waters around Isla del Coco National Park, Pacific Costa Rica, based on independent underwater observations from 1993 to 2013. We assessed if observed changes in the distribution and abundance of this species are related with habitat characteristics, fishing intensity or more extreme climatic events, including the El Niño Southern Oscillation, and changes on the average sea surface temperature. Yellowfin tuna showed a decreasing abundance trend in the sampled period, whereas higher abundances were found in shallow and warmer waters, with high concentration of chlorophyll-a, and in surrounding seamounts. In addition, El Niño Southern Oscillation events did not seem to affect Yellowfin tuna distribution and abundance. Understanding the habitat preferences of this species, using approaches as the one developed here, may help design integrated programs for more efficient management of vulnerable species.

Abundance and Distribution Patterns of Thunnus albacares in Isla del Coco National Park through Predictive Habitat Suitability Models

PubMed Central

Gonzáles-Andrés, Cristina; F. M. Lopes, Priscila; Cortés, Jorge; Sánchez-Lizaso, José Luis; Pennino, Maria Grazia

2016-01-01

Information on the distribution and habitat preferences of ecologically and commercially important species is essential for their management and protection. This is especially important as climate change, pollution, and overfishing change the structure and functioning of pelagic ecosystems. In this study, we used Bayesian hierarchical spatial-temporal models to map the Essential Fish Habitats of the Yellowfin tuna (Thunnus albacares) in the waters around Isla del Coco National Park, Pacific Costa Rica, based on independent underwater observations from 1993 to 2013. We assessed if observed changes in the distribution and abundance of this species are related with habitat characteristics, fishing intensity or more extreme climatic events, including the El Niño Southern Oscillation, and changes on the average sea surface temperature. Yellowfin tuna showed a decreasing abundance trend in the sampled period, whereas higher abundances were found in shallow and warmer waters, with high concentration of chlorophyll-a, and in surrounding seamounts. In addition, El Niño Southern Oscillation events did not seem to affect Yellowfin tuna distribution and abundance. Understanding the habitat preferences of this species, using approaches as the one developed here, may help design integrated programs for more efficient management of vulnerable species. PMID:27973538

Genetic relationship and diversity among coconut (Cocos nucifera L.) accessions revealed through SCoT analysis.

PubMed

Rajesh, M K; Sabana, A A; Rachana, K E; Rahman, Shafeeq; Jerard, B A; Karun, Anitha

2015-12-01

Coconut (Cocos nucifera L.) is one of the important palms grown both as a homestead and plantation crop in countries and most island territories of tropical regions. Different DNA-based marker systems have been utilized to assess the extent of genetic diversity in coconut. Advances in genomics research have resulted in the development of novel gene-targeted markers. In the present study, we have used a simple and novel marker system, start codon targeted polymorphism (SCoT), for its evaluation as a potential marker system in coconut. SCoT markers were utilized for assessment of genetic diversity in 23 coconut accessions (10 talls and 13 dwarfs), representing different geographical regions. Out of 25 SCoT primers screened, 15 primers were selected for this study based on their consistent amplification patterns. A total of 102 scorable bands were produced by the 15 primers, 88 % of which were polymorphic. The scored data were used to construct a similarity matrix. The similarity coefficient values ranged between 0.37 and 0.91. These coefficients were utilized to construct a dendrogram using the unweighted pair group of arithmetic means (UPGMA). The extent of genetic diversity observed based on SCoT analysis of coconut accessions was comparable to earlier findings using other marker systems. Tall and dwarf coconut accessions were clearly demarcated, and in general, coconut accessions from the same geographical region clustered together. The results indicate the potential of SCoT markers to be utilized as molecular markers to detect DNA polymorphism in coconut accessions.

Ameliorative Effects of Chloroform Fraction of Cocos nucifera L. Husk Fiber Against Cisplatin-induced Toxicity in Rats.

PubMed

Adaramoye, Oluwatosin Adekunle; Azeez, Adesola Fausat; Ola-Davies, Olufunke Elizabeth

2016-01-01

Cisplatin (Cis) is used in the treatment of solid tumors and is known to elicit serious side effects. The present study investigated the protective effects of chloroform fraction of Cocos nucifera husk fiber (CFCN) against Cis-induced organs' damage and chromosomal defect in rats. Quercetin (QUE), standard antioxidant, served as positive control. Thirty male Wistar rats were assigned into six groups and treated with corn oil (control), Cis alone, Cis + CFCN, CFCN alone, Cis + QUE, and QUE alone. QUE and CFCN were given at 50 and 200 mg/kg/day, respectively, by oral gavage for 7 days before the rats were exposed to a single dose of Cis (10 mg/kg, intraperitoneal) at the last 36 h of study. Administration of Cis alone caused a significant (P < 0.05) increase in the levels of serum creatinine and urea by 72% and 70%, respectively, when compared with the control. The activity of serum aspartate aminotransferase was significantly (P < 0.05) increased while alanine aminotransferase and alkaline phosphatase were insignificantly (P > 0.05) affected in Cis-treated rats. Furthermore, the activities of hepatic and renal catalase, superoxide dismutase, glutathione S-transferase, glutathione peroxidase, and levels of reduced glutathione were significantly (P < 0.05) decreased in Cis-treated rats with concomitant elevation of malondialdehyde. Cis exposure increased the frequency of micro nucleated polychromatic erythrocytes (mPCE) by 92%. Pretreatment with CFCN inhibited lipid peroxidation, enhanced the activities of some antioxidative enzymes and reduced the frequency of mPCE. Chloroform fraction of CFCN may protect against organs damage by Cis. Further studies are required to determine the component of the plant responsible for this activity. Cisplatin (Cis) is used in the treatment of solid tumors and is known to elicit serious side effects. This study investigated the protective effects of chloroform fraction of Cocos nucifera husk fiber (CFCN) against Cis-induced organs

The 2017 Mw8.2 Tres Picos, Mexico Earthquake, an intraslab rupture crossing the Tehuantepec Fracture Zone stopped by a tear in the Cocos Plate

NASA Astrophysics Data System (ADS)

Wei, S.; Zeng, H.; WANG, X.; Qiu, Q.; Wang, T.; Li, L.; Chen, M.; Hermawan, I.; Wang, Y.; Tapponnier, P.; Barbot, S.

2017-12-01

On September 7th 2017, an Mw 8.2 intraslab earthquake ruptured beneath the Tehuantepec seismic gap in the Mexico subduction zone. We conducted a comprehensive investigation to characterize the earthquake rupture, including high-resolution back-projection, mainshock and large aftershocks relocation, aftershock moment tensor inversion, finite rupture model inversion jointly inverted from seismic waveform, static/high-rate GPS and InSAR images, and tsunami modeling. The back-projection results delineate a unilateral northwestward rupture about 150 km in length and 60s in duration, with a stable average rupture speed of 2.8 km/s. To reconcile multiple datasets, we used a two-segment fault geometry with near vertical dip angle (78°), and the second segment strikes slightly northward oriented, to mimic the rupture across the Tehuantepec Fracture Zone (FTZ) that separates the rupture into two segments. The joint inversion shows that the slip southeastern of TFZ dominates the moment release in the depth range of 30-50km during the first 40s. The second rupture segment released about 15% of the total moment, but with relatively larger contribution to the high-rate GPS, static geodetic and tide gauges data. Most of the large aftershocks occurred in the shallower part of the slab, with dominant thrust focal mechanism in agreement with slab bending. In contrast, the mainshock initiated at greater depth inside the slab, on a fault that may have formed near the trench and was reactivated by slab unbending, and was perhaps facilitated by dehydration. The comparison between the rupture model and the free air gravity anomaly suggests that the rupture was blocked westward by a low gravity anomaly zone. We interpret the difference in subducting speed and slab age across the TFZ and the Cocos plate gravity anomaly to be responsible for the abrupt stopping of the rupture at a tear zone inside the diving Cocos plate. Whether this earthquake will enhance future rupture on the plate

Isolation of beta-mannanase from Cocos nucifera Linn haustorium and its application in the depolymerization of beta-(1,4)-linked D-mannans.

PubMed

Soumya, Rema S; Abraham, Emilia T

2010-05-01

Beta-mannanase was extracted from coconut (Cocos nucifera Linn) haustorium and purified through ammonium sulfate precipitation and sepharose 6B-lectin affinity chromatography. Coconut beta-mannanase is an acidic protein with a pI of 3.75. The molecular mass of coconut beta-mannanase (sodium dodecyl sulfate-polyacrylamide gel electrophoresis) was found to be 44 kDa and was confirmed by matrix-assisted laser desorption ionization time-of-flight mass spectrometry. The optimum temperature and pH for enzyme activity was 70 degrees C and 5.2. The enzyme was used for the preparation of neutraceutical dietary supplement from galactomannans of guar gum and tender coconut kernel having a beta-(1,4)-linked D-mannose backbone. Depolymerized guar gum has 92% of oligosaccharides with a degree of polymerization of 3 and 7. Tender coconut kernel has a degree of polymerization of 9-39 oligosaccharides along with disaccharides and trisaccharides. Hence this mannanase will be useful to depolymerize beta-(1,4)-linked D-mannose polysaccharides from most plant sources to produce prebiotics in a cost-effective technique.

Antifungal Potential and Antioxidant Efficacy in the Shell Extract of Cocos nucifera (L.) (Arecaceae) against Pathogenic Dermal Mycosis

PubMed Central

Khalid Thebo, Nasreen; Ahmed Simair, Altaf; Sughra Mangrio, Ghulam; Ansari, Khalil Ahmed; Ali Bhutto, Aijaz; Lu, Changrui; Ali Sheikh, Wazir

2016-01-01

Background: Coconut is a tropical fruit well known for its essential oils that have been recognized for their biological activities since ancient times. There have been no previous investigations on the essential oils from coconut shells. Method: The shell extract of Cocos nucifera (L.) was prepared by the Soxhlet method and total phenolic content (TPC) in the extract was determined by Folin-Ciocalteu (FC) assay. The antioxidant potential of the coconut shell extract was evaluated by using the 2,2-diphenyl-1-picrylhydrazyl (DPPH) radical scavenging assay. Minimum inhibitory concentration (MIC) of the extract was determined by the strip method against clinically isolated dermal mycosis of 20 infected patients. Result: Total antioxidant activity varied from 92.32% to 94.20% and total phenolic content was found at 5.33 ± 0.02 mg/g in the coconut shell extract. The extract was found to be most effective as an antifungal against human pathogenic fungi, including A. niger, A. flavus, T. rubrum, M. canis, M. gypseum, A. fumigates, T. mentagrophyte and T. vercossum. The crude shell extract was highly effective against all dermal mycosis tested with the MIC ranging from 62 mm to 90 mm, whereas all fungal samples showed good inhibitory effect. Conclusion: The results of the present study provide a potential cure for microbial infections. PMID:28930122

Cocos nucifera Linn. (Palmae) husk fiber ethanolic extract: antioxidant capacity and electrochemical investigation.

PubMed

Oliveira, Monika Bezerra dos Santos; Valentim, Iara Barros; de Vasconcelos, Camila Calado; Omena, Cristhiane Maria Bazílio; Bechara, Etelvino José Henriques; da Costa, João Gomes; Freitas, Mikael de Lima; Sant'Ana, Antônio Euzébio Goulart; Goulart, Marília Oliveira Fonseca

2013-02-01

The present study aims to determine the antioxidant capacity of the ethanolic extracts of husk fiber of four coconut (Cocos nucifera L.) varieties (yellow dwarf, green dwarf, giant and hybrid) and to evaluate the electrochemical behavior of these extracts on a glassy carbon electrode and on a modified glassy carbon electrode. The highest values of total phenolic content were obtained for the hybrid (531 ± 24 mg GAE g(-1) dry extract) and yellow dwarf (501 ± 29 mg GAE g(-1) dry extract) varieties and the lowest was for the green dwarf variety with 58 ± 9 mg GAE g(-1) dry extract. The ability of the extracts to scavenge DPPH˙ radicals was in the order of giant > yellow dwarf > hybrid > green dwarf and the IC50 values varied from 8.6 to 55.9 μg mL(-1). All varieties showed reducing potential by the use of FRAP and CUPRAC methods, with the lowest performance obtained for the green dwarf variety. Additionally, through the use of mimetic biomembranes, ethanolic extracts of coconut husk were shown to protect lipids against oxidative damage independent of the variety. The main antioxidants identified in the extract of yellow dwarf variety by UPLC-MS were quercetin and catechin. Cyclic voltammetric studies of the ethanolic extracts on glassy carbon electrode confirmed the presence of easily oxidized compounds, and the high antioxidant capacity of the varieties. This capacity was expressed as mg quercetin equivalents g(-1) dry extract and ranged from 25.9 up to 53.5 mg QE g(-1). A poly-xanthurenic acid (poly-Xa)/multi-walled carbon nanotube (MWCNT) / glassy carbon modified electrode (poly-Xa/MWCNT/GCE) was used for this purpose. Our findings suggest that these extracts are potentially important antioxidant supplements for the everyday human diet, pharmaceutical and cosmetic industries, thereby aggregating value to the enormous amount of waste from the coconut industry, mostly used for burning purposes.

Ameliorative Effects of Chloroform Fraction of Cocos nucifera L. Husk Fiber Against Cisplatin-induced Toxicity in Rats

PubMed Central

Adaramoye, Oluwatosin Adekunle; Azeez, Adesola Fausat; Ola-Davies, Olufunke Elizabeth

2016-01-01

Background: Cisplatin (Cis) is used in the treatment of solid tumors and is known to elicit serious side effects. Objective: The present study investigated the protective effects of chloroform fraction of Cocos nucifera husk fiber (CFCN) against Cis-induced organs’ damage and chromosomal defect in rats. Quercetin (QUE), standard antioxidant, served as positive control. Materials and Methods: Thirty male Wistar rats were assigned into six groups and treated with corn oil (control), Cis alone, Cis + CFCN, CFCN alone, Cis + QUE, and QUE alone. QUE and CFCN were given at 50 and 200 mg/kg/day, respectively, by oral gavage for 7 days before the rats were exposed to a single dose of Cis (10 mg/kg, intraperitoneal) at the last 36 h of study. Results: Administration of Cis alone caused a significant (P < 0.05) increase in the levels of serum creatinine and urea by 72% and 70%, respectively, when compared with the control. The activity of serum aspartate aminotransferase was significantly (P < 0.05) increased while alanine aminotransferase and alkaline phosphatase were insignificantly (P > 0.05) affected in Cis-treated rats. Furthermore, the activities of hepatic and renal catalase, superoxide dismutase, glutathione S-transferase, glutathione peroxidase, and levels of reduced glutathione were significantly (P < 0.05) decreased in Cis-treated rats with concomitant elevation of malondialdehyde. Cis exposure increased the frequency of micro nucleated polychromatic erythrocytes (mPCE) by 92%. Pretreatment with CFCN inhibited lipid peroxidation, enhanced the activities of some antioxidative enzymes and reduced the frequency of mPCE. Conclusions: Chloroform fraction of CFCN may protect against organs damage by Cis. Further studies are required to determine the component of the plant responsible for this activity. SUMMARY Cisplatin (Cis) is used in the treatment of solid tumors and is known to elicit serious side effects. This study investigated the protective effects of

The husk fiber of Cocos nucifera L. (Palmae) is a source of anti-neoplastic activity.

PubMed

Koschek, P R; Alviano, D S; Alviano, C S; Gattass, C R

2007-10-01

In the present study, we investigated the in vitro anti-tumoral activities of fractions from aqueous extracts of the husk fiber of the typical A and common varieties of Cocos nucifera (Palmae). Cytotoxicity against leukemia cells was determined by the 3-[4,5-dimethylthiazol-2-yl]-2,5-diphenyltetrazolium bromide (MTT) assay. Cells (2 x 10(4)/well) were incubated with 0, 5, 50 or 500 microg/mL high- or low-molecular weight fractions for 48 h, treated with MTT and absorbance was measured with an ELISA reader. The results showed that both varieties have almost similar antitumoral activity against the leukemia cell line K562 (60.1 +/- 8.5 and 47.5 +/- 11.9% for the typical A and common varieties, respectively). Separation of the crude extracts with Amicon membranes yielded fractions with molecular weights ranging in size from 1-3 kDa (fraction A) to 3-10 kDa (fraction B) and to more than 10 kDa (fraction C). Cells were treated with 500 microg/mL of these fractions and cytotoxicity was evaluated by MTT. Fractions ranging in molecular weight from 1-10 kDa had higher cytotoxicity. Interestingly, C. nucifera extracts were also active against Lucena 1, a multidrug-resistant leukemia cell line. Their cytotoxicity against this cell line was about 50% (51.9 +/- 3.2 and 56.3 +/- 2.9 for varieties typical A and common, respectively). Since the common C. nucifera variety is extensively cultured in Brazil and the husk fiber is its industrial by-product, the results obtained in the present study suggest that it might be a very inexpensive source of new antineoplastic and anti-multidrug resistant drugs that warrants further investigation.

Batrachedra nuciferae, an Inflorescence-Feeding Moth Associated with Coconut, Cocos nucifera, and Palmiste, Roystonea oleracea, in Trinidad, West Indies

PubMed Central

Cock, Matthew J. W.

2013-01-01

In 2006, Batrachedra nuciferae Hodges (Lepidoptera: Batrachedridae) was the first phytophagous insect to be reported from inflorescences of coconut, Cocos nucifera L. (Arecales: Arecaceae), in Trinidad, West Indies. At that time, it was suggested to be an introduced species contributing to decreasing coconut yields on the island and potentially a threat to other palms. In this preliminary study, inflorescences of coconut, seven indigenous palms, and six exotic ornamental palms were surveyed in several areas of Trinidad. Caterpillars of more than 10 species of Lepidoptera were found and reared through to the adult stage. Batrachedra nuciferae was positively identified. It was concluded that the caterpillars of B. nuciferae feed on pollen in the male flowers of coconut and palmiste or royal palm, Roystonea oleracea (Jacquin) O.F. Cook. There was no evidence that B. nuciferae bred on any of the other palms surveyed, but it is not conclusive that they do not do so. A parasitoid, Apanteles (sensu lato) sp. (Hymenoptera: Braconidae), of B. nuciferae was reared. On available information, B. nuciferae is more likely to be an indigenous species that has hitherto been overlooked than an introduced species. In view of what is known about damage-yield relationships and biological control agents, B. nuciferae is unlikely to cause yield losses to coconut, so control measures are not justified. PMID:24786569

Batrachedra nuciferae, an inflorescence-feeding moth associated with coconut, Cocos nucifera, and palmiste, Roystonea oleracea, in Trinidad, West Indies.

PubMed

Cock, Matthew J W

2013-01-01

In 2006, Batrachedra nuciferae Hodges (Lepidoptera: Batrachedridae) was the first phytophagous insect to be reported from inflorescences of coconut, Cocos nucifera L. (Arecales: Arecaceae), in Trinidad, West Indies. At that time, it was suggested to be an introduced species contributing to decreasing coconut yields on the island and potentially a threat to other palms. In this preliminary study, inflorescences of coconut, seven indigenous palms, and six exotic ornamental palms were surveyed in several areas of Trinidad. Caterpillars of more than 10 species of Lepidoptera were found and reared through to the adult stage. Batrachedra nuciferae was positively identified. It was concluded that the caterpillars of B. nuciferae feed on pollen in the male flowers of coconut and palmiste or royal palm, Roystonea oleracea (Jacquin) O.F. Cook. There was no evidence that B. nuciferae bred on any of the other palms surveyed, but it is not conclusive that they do not do so. A parasitoid, Apanteles (sensu lato) sp. (Hymenoptera: Braconidae), of B. nuciferae was reared. On available information, B. nuciferae is more likely to be an indigenous species that has hitherto been overlooked than an introduced species. In view of what is known about damage-yield relationships and biological control agents, B. nuciferae is unlikely to cause yield losses to coconut, so control measures are not justified.

De novo transcriptome assembly and identification of the gene conferring a "pandan-like" aroma in coconut (Cocos nucifera L.).

PubMed

Saensuk, Chatree; Wanchana, Samart; Choowongkomon, Kiattawee; Wongpornchai, Sugunya; Kraithong, Tippaya; Imsabai, Wachiraya; Chaichoompu, Ekawat; Ruanjaichon, Vinitchan; Toojinda, Theerayut; Vanavichit, Apichart; Arikit, Siwaret

2016-11-01

Thailand's aromatic coconut (Cocos nucifera L.) is a special type of green dwarf coconut, the liquid endosperm of which is characterized by a pleasant "pandan-like" aroma due to the presence of 2-acetyl-1-pyrroline (2AP). The aim of this study was to perform a de novo assembly of transriptome from C. nucifera endosperm and to identify the gene responsible for 2AP biosynthesis. CnAMADH2 was identified as an ortholog of the rice aromatic gene and a G-to-C substitution found in exon 14 was associated with 2AP content in the aromatic green dwarf coconut accessions. The base substitution caused an amino-acid change, alanine-to-proline, at position 442 (P442A). The presence of P at this position might alter the steric conformation at the loop region and subsequently result in an unstabilized dimer conformation that could lower AMADH enzyme activity. Among AMADH/BADH protein sequences in different plant species, the P442A mutation was found exclusively in aromatic coconut. The PCR marker developed based on this sequence variation can perfectly detect the aromatic and non-aromatic alleles of the gene. This study confirms the hypothesis that plants may share a mechanism of 2AP biosynthesis. This is the first identification of the gene associated with 2AP biosynthesis in a tree plant. Copyright © 2016 Elsevier Ireland Ltd. All rights reserved.

Alkalic marine tephra layers at ODP Site 1241 - Major explosive eruptions from an oceanic volcano in a pre-shield stage?

NASA Astrophysics Data System (ADS)

Schindlbeck, J. C.; Kutterolf, S.; Freundt, A.; Andrews, G. D. M.; Wang, K.-L.; Völker, D.; Werner, R.; Frische, M.; Hoernle, K.

2016-12-01

We report a series of fourteen marine tephra layers that are the products of large explosive eruptions of Subplinian to Plinian intensities and magnitudes (VEI > 4) from Cocos Island, Costa Rica. Cocos Island is a volcanic island in the eastern Central Pacific Ocean 500 km offshore Costa Rica, and is situated on the northwestern flank of the aseismic Cocos Ridge. Geochemical fingerprinting of Pleistocene ( 2.4-1.4 Ma) marine tephra layers from Ocean Drilling Project (ODP) Leg 202 Site 1241 using major and trace element compositions of volcanic glass shards demonstrates unequivocally their origin from Cocos Island rather than the Galápagos Archipelago or the Central American Volcanic Arc (CAVA). Cocos Island and the adjacent seamounts of the Cocos Island Province have alkalic compositions and formed on young (≤ 3 Ma) oceanic crust from an extinct spreading ridge bounded by a transform fault against the older and thicker crust of the aseismic Cocos Ridge. Cocos Island has six times the average volume of the adjacent seamounts although all appear to have formed during the 3-1.4 Ma time period. Cocos Island lies closest to the transform fault and we explain its excessive growth by melts rising from garnet-bearing mantle being deflected from the thick Cocos Ridge lithosphere toward the thinner lithosphere on the other side of the transform, thus enlarging the melt catchment area for Cocos Island compared to the seamounts farther away from the transform. This special setting favored growth above sea level and subaerial explosive eruptions even though the absence of appropriate compositions suggests that the entirely alkalic Cocos Island (and seamounts) never evolved through the productive tholeiitic shield stage typical of other Pacific Ocean islands, possibly because melt production rates remained too small. Conditions of magma generation and ascent resembled Hawaiian pre-shield volcanoes but persisted for much longer (< 1 m.y.) and formed evolved, trachytic magmas

Glycaemic index of different coconut (Cocos nucifera)-flour products in normal and diabetic subjects.

PubMed

Trinidad, Trinidad P; Valdez, Divinagracia H; Loyola, Anacleta S; Mallillin, Aida C; Askali, Faridah C; Castillo, Joan C; Masa, Dina B

2003-09-01

The glycaemic index (GI) of commonly consumed bakery products supplemented with increasing levels of coconut (Cocos nucifera) flour was determined in ten normal and ten diabetic subjects. Using a randomized crossover design, the control and test foods were fed in random order on separate occasions after an overnight fast. Blood samples were collected through finger prick before and after feeding and were analysed for glucose levels using a clinical chemistry analyser. The significantly low-GI (<60) foods investigated were: macaroons (GI 45.7 (sem 3.0)) and carrot cake (GI 51.8 (sem 3.3)), with 200-250 g coconut flour/kg (P<0.05). The test foods with 150 g coconut flour/kg had GI ranging from 61.3 to 71.4. Among the test foods, pan de sal (GI 87.2 (sem 5.5)) and multigrain loaf (GI 85.2 (sem 6.8)) gave significantly higher GI with 50 and 100 g coconut flour/kg respectively (P<0.05). On the other hand, granola bar and cinnamon bread with 50 and 100 g coconut flour/kg respectively gave a GI ranging from 62.7 to 71.6 and did not differ significantly from the test foods with 150 g coconut flour/kg (P<0.05). A very strong negative correlation (r -0.85, n 11, P<0.005) was observed between the GI and dietary fibre content of the test foods supplemented with coconut flour. In conclusion, the GI of coconut flour-supplemented foods decreased with increasing levels of coconut flour and this may be due to its high dietary fibre content. The results of the present study may form a scientific basis for the development of coconut flour as a functional food. However, the fat content of coconut flour-supplemented food should always be considered to optimize the functionality of coconut fibre in the proper control and management of diabetes mellitus.

Effect of Euterpe oleracea Mart. (Açaí) Oil on Dyslipidemia Caused by Cocos nucifera L. Saturated Fat in Wistar Rats.

PubMed

Faria E Souza, Belmira S; Carvalho, Helison O; Taglialegna, Talisson; Barros, Albenise Santana A; da Cunha, Edilson Leal; Ferreira, Irlon Maciel; Keita, Hady; Navarrete, Andres; Carvalho, José Carlos Tavares

2017-09-01

Dyslipidemia is caused by disturbances in lipid metabolism that lead to chronic elevations of serum lipids, especially low-density lipoprotein (LDL)-cholesterol and triglycerides, increasing the risk of metabolic syndrome, obesity, diabetes, atherogenic processes, and cardiovascular diseases. The oil from the fruits of Euterpe oleracea (OFEO) is rich in unsaturated fatty acids with potential for treating alterations in lipid metabolism. In this study, we aimed to investigate the effect of OFEO on hyperlipidemia induced by Cocos nucifera L. saturated fat (GSC) in Wistar rats. Chromatographic profile showed that unsaturated fatty acids account for 66.08% in OFEO, predominately oleic acid (54.30%), and saturated fatty acids (palmitic acid 31.6%) account for 33.92%. GSC-induced dyslipidemia resulted in an increase in total cholesterol, LDL-cholesterol, triglycerides, glucose, and liver and abdominal fat, as well as atherogenic processes in the thoracic aorta. OFEO treatment did not reduce hypertriglyceridemia, but did reduce total cholesterol and LDL-cholesterol, thus contributing to the antiatherogenic action of OFEO. OFEO treatment inhibited the formation of atheromatous plaques in the vascular endothelium of the treated rats, as well as those who were treated with simvastatin. The results obtained suggest that OFEO has an antiatherogenic effect in a rat model of dyslipidemia.

Resistencia a antibióticos de última línea en cocos Gram positivos: la era posterior a la vancomicina

PubMed Central

Rincón, Sandra; Panesso, Diana; Díaz, Lorena; Carvajal, Lina P.; Reyes, Jinnethe; Munita, José M.; Arias, César A.

2015-01-01

En los últimos años se han desarrollado nuevas alternativas para el tratamiento de infecciones por patógenos Gram positivos multirresistentes, entre los cuales Staphylococcus aureus resistente a la meticilina (SARM) y los enterococos resistentes a la vancomicina (ERV) se consideran un verdadero reto terapéutico, y aunque el uso de la vancomicina en infecciones graves causadas por SARM ha generado serias dudas en los últimos años, continúa siendo escasa la información clínica de respaldo al uso de agentes terapéuticos que la superen en eficacia. El linezolid, la daptomicina y la tigeciclina son agentes que tienen actividad contra los cocos Gram positivos y que fueron aprobados e introducidos en la terapia clínica en la década pasada. Además, se han probado o están en las fases finales de desarrollo otros agentes como las cefalosporinas de última generación (ceftarolina y ceftobiprol). El propósito de esta revisión fue describir las nuevas alternativas terapéuticas, particularmente en la era posterior a la vancomicina, y repasar las características químicas más relevantes de los compuestos y su espectro de actividad, haciendo énfasis en sus mecanismos de acción y resistencia. PMID:24968051

Tissue culture and associated biotechnological interventions for the improvement of coconut (Cocos nucifera L.): a review.

PubMed

Nguyen, Quang Thien; Bandupriya, H D Dharshani; López-Villalobos, Arturo; Sisunandar, S; Foale, Mike; Adkins, Steve W

2015-11-01

The present review discusses not only advances in coconut tissue culture and associated biotechnological interventions but also future research directions toward the resilience of this important palm crop. Coconut (Cocos nucifera L.) is commonly known as the 'tree of life'. Every component of the palm can be used to produce items of value and many can be converted into industrial products. Coconut cultivation faces a number of acute problems that reduce its productivity and competitiveness. These problems include various biotic and abiotic challenges as well as an unstable market for its traditional oil-based products. Around 10 million small-holder farmers cultivate coconut palms worldwide on c. 12 million hectares of land, and many more people own a few coconut palms that contribute to their livelihoods. Inefficiency in the production of seedlings for replanting remains an issue; however, tissue culture and other biotechnological interventions are expected to provide pragmatic solutions. Over the past 60 years, much research has been directed towards developing and improving protocols for (i) embryo culture; (ii) clonal propagation via somatic embryogenesis; (iii) homozygote production via anther culture; (iv) germplasm conservation via cryopreservation; and (v) genetic transformation. Recently other advances have revealed possible new ways to improve these protocols. Although effective embryo culture and cryopreservation are now possible, the limited frequency of conversion of somatic embryos to ex vitro seedlings still prevents the large-scale clonal propagation of coconut. This review illustrates how our knowledge of tissue culture and associated biotechnological interventions in coconut has so far developed. Further improvement of protocols and their application to a wider range of germplasm will continue to open up new horizons for the collection, conservation, breeding and productivity of coconut.

Involvement of monoaminergic systems in anxiolytic and antidepressive activities of the standardized extract of Cocos nucifera L.

PubMed

Lima, Eliane Brito Cortez; de Sousa, Caren Nádia Soares; Meneses, Lucas Nascimento; E Silva Pereira, Yuri Freitas; Matos, Natália Castelo Branco; de Freitas, Rayanne Brito; Lima, Nycole Brito Cortez; Patrocínio, Manoel Cláudio Azevedo; Leal, Luzia Kalyne Almeida Moreira; Viana, Glauce Socorro Barros; Vasconcelos, Silvânia Maria Mendes

2017-01-01

Extracts from the husk fiber of Cocos nucifera are used in folk medicine, but their actions on the central nervous system have not been studied. Here, the anxiolytic and antidepressant effects of the standardized hydroalcoholic extract of C. nucifera husk fiber (HECN) were evaluated. Male Swiss mice were treated with HECN (50, 100, or 200 mg/kg) 60 min before experiments involving the plus maze test, hole-board test, tail suspension test, and forced swimming test (FST). HECN was administered orally (p.o.) in acute and repeated-dose treatments. The forced swimming test was performed with dopaminergic and noradrenergic antagonists, as well as a serotonin release inhibitor. Administration of HECN in the FST after intraperitoneal (i.p.) pretreatment of mice with sulpiride (50 mg/kg), prazosin (1 mg/kg), or p-chlorophenylalanine (PCPA, 100 mg/kg) caused the actions of these three agents to be reversed. However, this effect was not observed after pretreating the animals with SCH23390 (15 µg/kg, i.p.) or yohimbine (1 mg/kg, i.p.) The dose chosen for HECN was 100 mg/kg, p.o., which increased the number of entries as well as the permanence in the open arms of the maze after acute and repeated doses. In both the forced swimming and the tail suspension tests, the same dose decreased the time spent immobile but did not disturb locomotor activity in an open-field test. The anxiolytic effect of HECN appears to be related to the GABAergic system, while its antidepressant effect depends upon its interaction with the serotoninergic, noradrenergic (α1 receptors), and dopaminergic (D2 dopamine receptors) systems.

In-vitro antibacterial properties of crude aqueous and n-hexane extracts of the husk of Cocos nucifera.

PubMed

Akinyele, Taiwo Adesola; Okoh, Omobola Oluranti; Akinpelu, David Ayinde; Okoh, Anthony Ifeanyi

2011-03-03

The increasing numbers of cases of antibiotic resistance among pathogenic bacteria such as Vibrio species poses a major problem to the food and aquaculture industries, as most antibiotics are no longer effective in controlling pathogenic bacteria affecting these industries. Therefore, this study was carried out to assess the antibacterial potentials of crude aqueous and n-hexane extracts of the husk of Cocos nucifera against some selected Vibrio species and other bacterial pathogens including those normally implicated in food and wound infections. The crude extracts were screened against forty-five strains of Vibrio pathogens and twenty-five other bacteria isolates made up of ten Gram positive and fifteen Gram negative bacteria. The aqueous extract was active against 17 of the tested bacterial and 37 of the Vibrio isolates; while the n-hexane extract showed antimicrobial activity against 21 of the test bacteria and 38 of the test Vibrio species. The minimum inhibitory concentrations (MICs) of the aqueous and n-hexane extracts against the susceptible bacteria ranged between 0.6-5.0 mg/mL and 0.3-5.0 mg/mL respectively, while the time kill study result for the aqueous extract ranged between 0.12 Log₁₀ and 4.2 Log₁₀ cfu/mL after 8 hours interaction in 1 x MIC and 2 x MIC. For the n-hexane extract, the log reduction ranged between 0.56 Log₁₀ and 6.4 Log₁₀ cfu/mL after 8 hours interaction in 1 x MIC and 2 x MIC. This study revealed the huge potential of C. nucifera extracts as alternative therapies against microbial infections.

'Candidatus Phytoplasma palmicola', associated with a lethal yellowing-type disease of coconut (Cocos nucifera L.) in Mozambique.

PubMed

Harrison, Nigel A; Davis, Robert E; Oropeza, Carlos; Helmick, Ericka E; Narváez, María; Eden-Green, Simon; Dollet, Michel; Dickinson, Matthew

2014-06-01

In this study, the taxonomic position and group classification of the phytoplasma associated with a lethal yellowing-type disease (LYD) of coconut (Cocos nucifera L.) in Mozambique were addressed. Pairwise similarity values based on alignment of nearly full-length 16S rRNA gene sequences (1530 bp) revealed that the Mozambique coconut phytoplasma (LYDM) shared 100% identity with a comparable sequence derived from a phytoplasma strain (LDN) responsible for Awka wilt disease of coconut in Nigeria, and shared 99.0-99.6% identity with 16S rRNA gene sequences from strains associated with Cape St Paul wilt (CSPW) disease of coconut in Ghana and Côte d'Ivoire. Similarity scores further determined that the 16S rRNA gene of the LYDM phytoplasma shared <97.5% sequence identity with all previously described members of 'Candidatus Phytoplasma'. The presence of unique regions in the 16S rRNA gene sequence distinguished the LYDM phytoplasma from all currently described members of 'Candidatus Phytoplasma', justifying its recognition as the reference strain of a novel taxon, 'Candidatus Phytoplasma palmicola'. Virtual RFLP profiles of the F2n/R2 portion (1251 bp) of the 16S rRNA gene and pattern similarity coefficients delineated coconut LYDM phytoplasma strains from Mozambique as novel members of established group 16SrXXII, subgroup A (16SrXXII-A). Similarity coefficients of 0.97 were obtained for comparisons between subgroup 16SrXXII-A strains and CSPW phytoplasmas from Ghana and Côte d'Ivoire. On this basis, the CSPW phytoplasma strains were designated members of a novel subgroup, 16SrXXII-B.

Localized double-array stacking analysis of PcP: D″ and ULVZ structure beneath the Cocos plate, Mexico, central Pacific, and north Pacific

USGS Publications Warehouse

Hutko, Alexander R.; Lay, Thorne; Revenaugh, Justin

2009-01-01

A large, high quality P-wave data set comprising short-period and broadband signals sampling four separate regions in the lowermost mantle beneath the Cocos plate, Mexico, the central Pacific, and the north Pacific is analyzed using regional one-dimensional double-array stacking and modelling with reflectivity synthetics. A data-screening criterion retains only events with stable PcP energy in the final data stacks used for modelling and interpretation. This significantly improves the signal stacks relative to including unscreened observations, allows confident alignment on the PcP arrival and allows tight bounds to be placed on P-wave velocity structure above the core–mantle boundary (CMB). The PcP reflections under the Cocos plate are well modelled without any ultra-low velocity zone from 5 to 20°N. At latitudes from 15 to 20°N, we find evidence for two P-wave velocity discontinuities in the D″ region. The first is ∼182 km above the CMB with a δln Vp of +1.5%, near the same depth as a weaker discontinuity (<+0.5%) observed from 5 to 15°N in prior work. The other reflector is ∼454 km above the CMB, with a δln Vp of +0.4%; this appears to be a shallower continuation of the joint P- and S-wave discontinuity previously detected south of 15° N, which is presumed to be the perovskite to post-perovskite phase transition. The data stacks for paths bottoming below Mexico have PcP images that are well matched with the simple IASP91 structure, contradicting previous inferences of ULVZ presence in this region. These particular data are not very sensitive to any D″ discontinuities, and simply bound them to be <∼2%, if present. Data sampling the lowermost mantle beneath the central Pacific confirm the presence of a ∼15-km thick ultra-low velocity zone (ULVZ) just above the CMB, with δln Vp and δln Vs of around −3 to −4% and −4 to −8%, respectively. The ULVZ models predict previous S-wave data stacks well. The data for this region

Cryopreservation of coconut (Cocos nucifera L.) zygotic embryos does not induce morphological, cytological or molecular changes in recovered seedlings.

PubMed

Sisunandar; Rival, Alain; Turquay, Patricia; Samosir, Yohannes; Adkins, Steve W

2010-07-01

The present study aimed at exploring the fidelity of coconut (Cocos nucifera L.) plants recovered from cryopreservation. Zygotic embryos from various different cultivars were cryopreserved following four successive steps, namely: rapid dehydration, rapid freezing, rapid thawing and in vitro recovery followed by acclimatization. At the end of the acclimatization period, the seedlings were compared to counterparts of the same age, which were produced from non-cryopreserved embryos. Both series were submitted to morphological, cytological and molecular comparisons. No significant differences in terms of growth rates could be measured. In addition, no morphological variation could be detected through the measurement of shoot elongation rates, production of opened leaves, and the number and total length of primary roots. Karyotype analysis revealed the same chromosome number (2n = 32) in all studied cultivars independently of cryopreservation. No significant differences could be observed between control and cryopreserved material concerning the type of chromosomes, the length of the long and short arms, the arm length ratio and the centromeric index. However, idiogram analysis did show a greater number of black banding on chromosomes isolated from cryopreserved material. Genetic and epigenetic fidelity was assessed through microsatellite (SSR) analysis and global DNA methylation rates; no significant differences would be observed between genomic DNAs isolated from seedlings originating from cryopreserved embryos and respective controls. In conclusion, our results suggest that the method of cryopreservation under study did not induce gross morphological, genetic or epigenetic changes, thus suggesting that it is an appropriate method to efficiently preserve coconut germplasm.

Biochemical and microstructural Ccharacteristics of insoluble and soluble dietary fiber prepared from mushroom sclerotia of Pleurotus tuber-regium, Polyporus rhinocerus, and Wolfiporia cocos.

PubMed

Wong, Ka-Hing; Cheung, Peter C K; Wu, Jin-Zhong

2003-11-19

The proximate composition of sclerotia of Pleurotus tuber-regium, Polyporus rhinoceros, and Wolfiporia cocos, together with the yield, purity, monosaccharide profile, and microstructure of their insoluble dietary fiber (IDF) and soluble dietary fiber (SDF) fractions prepared from AOAC enzymatic-gravimetric methods were investigated and compared. All three sclerotia were typical carbohydrate rich sclerotia [ranging from 90.5 to 98.1% dry matter (DM)] with an exceptionally low amount of crude lipid content (ranging from 0.02 to 0.14% DM). Besides, all three sclerotia possessed substantial amounts of IDF (ranging from 77.4 to 94.6% DM) with notably high levels of nonstarch polysaccharides (NSP) (89.9-92.2% DM) in which glucose was the predominant sugar residue (90.6-97.2% of NSP DM). On the contrary, both the yield (only ranging from 1.45 to 2.50% DM) and the amount of NSP (ranging from 22.4 to 29.6% DM) of the three sclerotial SDF fractions were very low. Scanning electron micrographs showed fragments of interwoven hyphae and insoluble materials in the three sclerotial IDF fractions, but only an amorphous structure of soluble materials was observed in the SDF fractions. The potential use of these fiber preparations was discussed.

Protective Effect of Mangifera indica Linn., Cocos nucifera Linn., and Averrhoa carambola Linn. Extracts against Ultraviolet B-Induced Damage in Human Keratinocytes

PubMed Central

Ronpirin, Chalinee; Pattarachotanant, Nattaporn

2016-01-01

This study was aimed at investigating the antioxidant activity of Mangifera indica Linn., Cocos nucifera Linn., and Averrhoa carambola Linn. and their biological effect on human keratinocytes affected by the ultraviolet B (UVB), a major cause of cell damage and skin cancer through induction of DNA damage, production of reactive oxygen species (ROS), and apoptosis. The richest antioxidant activity was found in ethanol fraction of M. indica (21.32 ± 0.66 mg QE/g dry weight), while the lowest one was found in aqueous fractions of M. indica and C. nucifera (1.76 ± 2.10 and 1.65 ± 0.38 mg QE/g dry weight, respectively). Ethanol and aqueous fractions of A. carambola (250 µg/mL) significantly reduced the number of apoptotic cells. The expression of cleaved caspase 3 in UVB-treated group was significantly greater than that in untreated group. Both fractions of A. carambola (50, 100, and 250 µg/mL) significantly decreased the expression of cleaved caspase 3. Regarding the induction of DNA repair, ethanol (100 and 250 µg/mL) and aqueous (50, 100 and 250 µg/mL) fractions of A. carambola significantly decreased the percentage of cyclobutane pyrimidine dimers (CPD). Taken together, our results suggest that both fractions of A. carambola may be potentially developed for dermal applications. PMID:27057195

Protective Effect of Mangifera indica Linn., Cocos nucifera Linn., and Averrhoa carambola Linn. Extracts against Ultraviolet B-Induced Damage in Human Keratinocytes.

PubMed

Ronpirin, Chalinee; Pattarachotanant, Nattaporn; Tencomnao, Tewin

2016-01-01

This study was aimed at investigating the antioxidant activity of Mangifera indica Linn., Cocos nucifera Linn., and Averrhoa carambola Linn. and their biological effect on human keratinocytes affected by the ultraviolet B (UVB), a major cause of cell damage and skin cancer through induction of DNA damage, production of reactive oxygen species (ROS), and apoptosis. The richest antioxidant activity was found in ethanol fraction of M. indica (21.32 ± 0.66 mg QE/g dry weight), while the lowest one was found in aqueous fractions of M. indica and C. nucifera (1.76 ± 2.10 and 1.65 ± 0.38 mg QE/g dry weight, respectively). Ethanol and aqueous fractions of A. carambola (250 µg/mL) significantly reduced the number of apoptotic cells. The expression of cleaved caspase 3 in UVB-treated group was significantly greater than that in untreated group. Both fractions of A. carambola (50, 100, and 250 µg/mL) significantly decreased the expression of cleaved caspase 3. Regarding the induction of DNA repair, ethanol (100 and 250 µg/mL) and aqueous (50, 100 and 250 µg/mL) fractions of A. carambola significantly decreased the percentage of cyclobutane pyrimidine dimers (CPD). Taken together, our results suggest that both fractions of A. carambola may be potentially developed for dermal applications.

Imaging b-value depth variations within the Cocos and Rivera plates at the Mexican subduction zone

NASA Astrophysics Data System (ADS)

Rodríguez-Pérez, Quetzalcoatl; Zuñiga, F. Ramón

2018-06-01

By a systematic mapping of the b-value along profiles perpendicular to the Mexican Wadati-Benioff zone, we obtained important characteristics pertaining the stress state and faulting style related to the subduction process. To this purpose, we used data from the earthquake catalog reported by the Servicio Sismologico Nacional (1988-2016). We investigate depth variations of the b-value for the Cocos and Rivera under North American plates interface, by a detailed analysis of 15 cross-sections. The obtained b-value profiles vary from 0.50 to 2.50, which nevertheless appear related to the faulting style and stress state. By comparing the locations and focal mechanism of the largest events with the b-values of the surrounding regions, our analysis corroborates the dependence of the b-value on the faulting style. Thrust events occur in regions of low and high b-value at depths <50 km. Normal-faulting events occur mainly in high b-value regions at all shallow (Z < 30 km) and intermediate depths (Z > 30 km), in agreement with global studies. These results support the hypothesis that differential stress processes may be behind the occurrence of the different faulting style. On the contrary, by analyzing the mean b-values for both types of faulting mechanism at each of the cross-sections, we found a significantly lower mean b-value related to normal faulting for those regions where the 8 (Mw 8.2) and 19 (Mw 7.1) September 2017 earthquakes occur. These results lead us to conclude that those regions experienced an increased stress state prone to the occurrence of normal-intraplate events. We also compare the b-value distribution with Vp and Q tomography studies obtaining a good correlation between them. We found evidence to relate b-value variations with subduction processes such as stress state due to tectonic and flexural conditions, and to a lesser extent to material heterogeneity and fluid dehydration.

Holocene environmental change of the northern Caribbean inferred from the sediments of a flooded sinkhole, Cayo Coco, Cuba

NASA Astrophysics Data System (ADS)

Peros, M. C.; Agosta G'meiner, A. M.; Collins, S.

2016-12-01

We present new data on the Holocene environments of the northern Caribbean inferred from the sediments of a flooded sinkhole (Cenote Jennifer) on the island of Cayo Coco in north-central Cuba. Cenote Jennifer is located several meters above sea level and has an average depth of 13 meters. Water chemistry measurements indicate that the water in the sinkhole is highly stratified with a halocline at about 8 meters depth and an anoxic base. A series of sediment cores collected at the center of the sinkhole were analyzed for fossil pollen, microcharcoal, dinoflagellate cysts, elemental geochemistry (by high-resolution XRF core-scanning), and grain size and were dated by Pb-210 and AMS radiocarbon techniques (using well-preserved macrofossils of leaves, bark, and twigs). The results show that sediments first began to accumulate in Cenote Jennifer approximately 9000 years ago and continued until the present. The elemental geochemistry results record increases in elements such as Br, Cl, Ni, and Cu during the 8.2 kyr event which may reflect enhanced deep-ocean upwelling at this time. The fossil pollen data record a succession in vegetation that included cattail marsh, thorny coastal scrubland, dry evergreen forest, and secondary forest communities over the course of the Holocene. Changes in vegetation were driven mostly by relative sea level rise in the early Holocene but climate change was more important by the middle to late Holocene. Hundreds of mm- to cm-scale laminations are also present in the core, many of which represent past hurricane strikes. The microcharcoal and pollen evidence also suggests that prehistoric humans may have settled the area and practiced agriculture as early as 2800 cal yr BP. The findings from Cenote Jennifer highlight the utility of flooded sinkholes as paleoenvironmental archives in tropical kart regions and provide important new data on the hydroclimatology of the northern Caribbean.

Single base substitution causing the fragrant phenotype and development of a type-specific marker in aromatic coconut (Cocos nucifera).

PubMed

Vongvanrungruang, A; Mongkolsiriwatana, C; Boonkaew, T; Sawatdichaikul, O; Srikulnath, K; Peyachoknagul, S

2016-09-19

The fragrance gene, betaine aldehyde dehydrogenase 2 (Badh2), has been well studied in many plant species. The objectives of this study were to clone Badh2 and compare the sequences between aromatic and non-aromatic coconuts. The complete coding region was cloned from cDNA of both aromatic and non-aromatic coconuts. The nucleotide sequences were highly homologous to Badh2 genes of other plants. Badh2 consisted of a 1512-bp open reading frame encoding 503 amino acids. A single nucleotide difference between aromatic and non-aromatic coconuts resulted in the conversion of alanine (non-aromatic) to proline (aromatic) at position 442, which was the substrate binding site of BADH2. The ring side chain of proline could destabilize the structure leading to a non-functional enzyme. Badh2 genomic DNA was cloned from exon 1 to 4, and from exon 5 to 15 from the two coconut types, except for intron 4 that was very long. The intron sequences of the two coconut groups were highly homologous. No differences in Badh2 expression were found among the tissues of aromatic coconut or between aromatic and non-aromatic coconuts. The amino acid sequences of BADH2 from coconut and other plants were compared and the genetic relationship was analyzed using MEGA 7.0. The phylogenetic tree reconstructed by the Bayesian information criterion consisted of two distinct groups of monocots and dicots. Among the monocots, coconut (Cocos nucifera) and oil palm (Elaeis guineensis) were the most closely related species. A marker for coconut differentiation was developed from one-base substitution site and could be successfully used.

Transcriptomics-based analysis using RNA-Seq of the coconut (Cocos nucifera) leaf in response to yellow decline phytoplasma infection.

PubMed

Nejat, Naghmeh; Cahill, David M; Vadamalai, Ganesan; Ziemann, Mark; Rookes, James; Naderali, Neda

2015-10-01

Invasive phytoplasmas wreak havoc on coconut palms worldwide, leading to high loss of income, food insecurity and extreme poverty of farmers in producing countries. Phytoplasmas as strictly biotrophic insect-transmitted bacterial pathogens instigate distinct changes in developmental processes and defence responses of the infected plants and manipulate plants to their own advantage; however, little is known about the cellular and molecular mechanisms underlying host-phytoplasma interactions. Further, phytoplasma-mediated transcriptional alterations in coconut palm genes have not yet been identified. This study evaluated the whole transcriptome profiles of naturally infected leaves of Cocos nucifera ecotype Malayan Red Dwarf in response to yellow decline phytoplasma from group 16SrXIV, using RNA-Seq technique. Transcriptomics-based analysis reported here identified genes involved in coconut innate immunity. The number of down-regulated genes in response to phytoplasma infection exceeded the number of genes up-regulated. Of the 39,873 differentially expressed unigenes, 21,860 unigenes were suppressed and 18,013 were induced following infection. Comparative analysis revealed that genes associated with defence signalling against biotic stimuli were significantly overexpressed in phytoplasma-infected leaves versus healthy coconut leaves. Genes involving cell rescue and defence, cellular transport, oxidative stress, hormone stimulus and metabolism, photosynthesis reduction, transcription and biosynthesis of secondary metabolites were differentially represented. Our transcriptome analysis unveiled a core set of genes associated with defence of coconut in response to phytoplasma attack, although several novel defence response candidate genes with unknown function have also been identified. This study constitutes valuable sequence resource for uncovering the resistance genes and/or susceptibility genes which can be used as genetic tools in disease resistance breeding.

Exploring the influence of sterilisation and storage on some physicochemical properties of coconut (Cocos nucifera L.) water

PubMed Central

2011-01-01

Background Fresh coconut (Cocos nucifera L) water is a clear, sterile, colourless, slightly acidic and naturally flavoured drink, mostly consumed in tropical areas. It is a rich source of nutrients and has been used for medical purposes. This study was designed to investigate changes in selected characteristics of coconut water after autoclaving, gamma irradiation and storage. Also, the study was designed for assessing the possibility of measuring the growth of bacterial in fresh, stored or sterilised coconut water using turbidity measurements (at wavelengths between 600 nm and 800 nm) or by dry biomass determinations. Results Portions of coconut water aseptically extracted from the matured fruit, (average pH of 6.33 ± 0.17) were either stored at 4°C, autoclaved at 121°C for 20 min., or irradiated with gamma rays at 5 kGy. Subsequent changes in selected characteristics were determined. Autoclaving, gamma irradiation and long term storage of coconut water at 4°C resulted both in the development of a pale to intense yellow colour and changes in turbidity. After storage, the dry matter content of fresh, autoclaved and irradiated coconut water by 52.0%, 23.5% and 5.0% respectively. There were also significant differences in the UV spectra before and after sterilisation and during the storage of the coconut water. Although changes in total carbohydrates were observed, they were not significant (p > 0.05). Conclusions The enormous differences in the characteristics before and after storage suggests that the use of turbidity and dry biomass measurements for measuring the growth of bacteria in fresh, autoclaved and gamma irradiated coconut water before storage is practicable without any possibility of interference by the innate turbidity, colour and dry matter of the coconut water. However, this is not practicable after storing the coconut waters at 4°C, since there were increases in the turbidity and dry matter of the coconut water to levels that will mask the

Exploring the influence of sterilisation and storage on some physicochemical properties of coconut (Cocos nucifera L.) water.

PubMed

Awua, Adolf K; Doe, Edna D; Agyare, Rebecca

2011-10-27

Fresh coconut (Cocos nucifera L) water is a clear, sterile, colourless, slightly acidic and naturally flavoured drink, mostly consumed in tropical areas. It is a rich source of nutrients and has been used for medical purposes. This study was designed to investigate changes in selected characteristics of coconut water after autoclaving, gamma irradiation and storage. Also, the study was designed for assessing the possibility of measuring the growth of bacterial in fresh, stored or sterilised coconut water using turbidity measurements (at wavelengths between 600 nm and 800 nm) or by dry biomass determinations. Portions of coconut water aseptically extracted from the matured fruit, (average pH of 6.33 ± 0.17) were either stored at 4°C, autoclaved at 121°C for 20 min., or irradiated with gamma rays at 5 kGy. Subsequent changes in selected characteristics were determined. Autoclaving, gamma irradiation and long term storage of coconut water at 4°C resulted both in the development of a pale to intense yellow colour and changes in turbidity. After storage, the dry matter content of fresh, autoclaved and irradiated coconut water by 52.0%, 23.5% and 5.0% respectively. There were also significant differences in the UV spectra before and after sterilisation and during the storage of the coconut water. Although changes in total carbohydrates were observed, they were not significant (p > 0.05). The enormous differences in the characteristics before and after storage suggests that the use of turbidity and dry biomass measurements for measuring the growth of bacteria in fresh, autoclaved and gamma irradiated coconut water before storage is practicable without any possibility of interference by the innate turbidity, colour and dry matter of the coconut water. However, this is not practicable after storing the coconut waters at 4°C, since there were increases in the turbidity and dry matter of the coconut water to levels that will mask the turbidity of a growing bacteria

Effect of microwave drying and oven drying on the water activity, color, phenolic compounds content and antioxidant activity of coconut husk (Cocos nucifera L.).

PubMed

Valadez-Carmona, Lourdes; Cortez-García, Rosa María; Plazola-Jacinto, Carla Patricia; Necoechea-Mondragón, Hugo; Ortiz-Moreno, Alicia

2016-09-01

The coconut ( Cocos nucifera L.) husk is basically composed by fiber and pith material and remained under-utilized. This is an important source of phenolic compounds that could be used as functional ingredients. The aim of this study was to determine the effect of: oven-drying (OD) and microwave drying (MD), on the water activity, color, phenolic compound content and antioxidant activity of coconut husk. The OD was performed at 60 °C for 12 h and MD was performed at 900 W for 10 min. The total phenolic content (TPC) in fresh coconut husk was 64.2 mg GAE/g dry wt and significant higher than observed after OD and MD of 35.8 and 45.5 mg GAE/g dry wt, respectively. Ten phenols were identified in fresh and dehydrated coconut husks. The husk MD showed an increase in the content of gallic, 4-hydroxybenzoic, ferulic and syringic acids and epicatechin compared with the fresh; while coconut husk OD and MD, showed a decrease in the content of vanillic acid, vanillin, catequin and kaempferol. The antioxidant activity decreased after both OD and MD. However, MD resulted in a better antioxidant activity in husk than OD. MD of husk resulted into better retention of preserved color, TPC and TFC than OD.

Final report on the safety assessment of sodium cetearyl sulfate and related alkyl sulfates as used in cosmetics.

PubMed

Fiume, Monice; Bergfeld, Wilma F; Belsito, Donald V; Klaassen, Curtis D; Marks, James G; Shank, Ronald C; Slaga, Thomas J; Snyder, Paul W; Alan Andersen, F

2010-05-01

Sodium cetearyl sulfate is the sodium salt of a mixture of cetyl and stearyl sulfate. The other ingredients in this safety assessment are also alkyl salts, including ammonium coco-sulfate, ammonium myristyl sulfate, magnesium coco-sulfate, sodium cetyl sulfate, sodium coco/hydrogenated tallow sulfate, sodium coco-sulfate, sodium decyl sulfate, sodium ethylhexyl sulfate, sodium myristyl sulfate, sodium oleyl sulfate, sodium stearyl sulfate, sodium tallow sulfate, sodium tridecyl sulfate, and zinc coco-sulfate. These ingredients are surfactants used at concentrations from 0.1% to 29%, primarily in soaps and shampoos. Many of these ingredients are not in current use. The Cosmetic Ingredient Review (CIR) Expert Panel previously completed a safety assessment of sodium and ammonium lauryl sulfate. The data available for sodium lauryl sulfate and ammonium lauryl sulfate provide sufficient basis for concluding that sodium cetearyl sulfate and related alkyl sulfates are safe in the practices of use and concentration described in the safety assessment.

Simultaneous analysis of different classes of phytohormones in coconut (Cocos nucifera L.) water using high-performance liquid chromatography and liquid chromatography-tandem mass spectrometry after solid-phase extraction.

PubMed

Ma, Zhen; Ge, Liya; Lee, Anna S Y; Yong, Jean Wan Hong; Tan, Swee Ngin; Ong, Eng Shi

2008-03-10

Coconut (Cocos nucifera L.) water, which contains many uncharacterized phytohormones is extensively used as a growth promoting supplement in plant tissue culture. In this paper, a high-performance liquid chromatography (HPLC) method was developed for the simultaneous determination of various classes phytohormones, including indole-3-acetic acid (IAA), indole-3-butyric acid (IBA), abscisic acid (ABA), gibberellic acid (GA), zeatin (Z), N(6)-benzyladenine (BA), alpha-naphthaleneacetic acid (NAA) and 2,4-dichlorophenoxyacetic acid (2,4-D) in young coconut water (CW). The analysis was carried out using a reverse-phase HPLC gradient elution, with an aqueous mobile phase (containing 0.1% formic acid, pH adjusted to 3.2 with triethylamine (TEA)) modified by methanol, and solute detection made at 265 nm wavelength. The method was validated for specificity, quantification, accuracy and precision. After preconcentration of putative endogenous phytohormones in CW using C(18) solid-phase extraction (SPE) cartridges, the HPLC method was able to screen for putative endogenous phytohormones present in CW. Finally, the identities of the putative phytohormones present in CW were further confirmed using independent liquid chromatography-tandem mass spectrometry (LC-MS/MS) equipped with an electrospray ionization (ESI) interface.

In vivo antimalarial activity and toxicological effects of methanolic extract of Cocos nucifera (Dwarf red variety) husk fibre.

PubMed

Balogun, Elizabeth Abidemi; Malomo, Sylvia Orume; Adebayo, Joseph Oluwatope; Ishola, Ahmed Adebayo; Soladoye, Ayodele Olufemi; Olatunji, Lawrence Aderemi; Kolawole, Olatunji Matthew; Oguntoye, Stephen Olubunmi; Babatunde, Abiola Samuel; Akinola, Oluwole Busayo

2014-11-01

Phytochemical constituents as well as antimalarial and toxicity potentials of the methanolic extract of the husk fibre of Dwarf Red variety of Cocos nucifera were evaluated in this study. The dried powdered husk fibre was exhaustively extracted with hexane, ethyl acetate and methanol successively and the methanolic extract was screened for flavonoids, phenolics, tannins, alkaloids, steroids, triterpenes, phlobatannins, anthraquinones and glycosides. A 4-day suppressive antimalarial test was carried out using Plasmodium berghei NK65-infected mice, to which the extract was administered at doses of 31.25, 62.5, 125, 250 and 500 mg/kg body weight (BW). Toxicity of the extract was evaluated in rats using selected hematological parameters and organ function indices after orally administering doses of 25, 50 and 100 mg/kg BW for 14 d. Phytochemical analysis revealed the presence of alkaloids, tannins, phenolics, saponins, glycosides, steroids and anthraquinones in the extract. Moreover, the extract reduced parasitemia by 39.2% and 45.8% at doses of 250 and 500 mg/kg BW respectively on day 8 post-inoculation. Various hematological parameters evaluated were not significantly altered (P>0.05) at all doses of the extract, except red blood cell count which was significantly elevated (P<0.05) at 100 mg/kg BW. The extract significantly increased (P<0.05) urea, creatinine, cholesterol, high-density lipoprotein-cholesterol and bilirubin concentrations in the serum as well as atherogenic index, while it reduced albumin concentration significantly (P<0.05) at higher doses compared to the controls. Alanine aminotransferase activity was reduced in the liver and heart significantly (P<0.05) but was increased in the serum significantly (P<0.05) at higher doses of the extract compared to the controls. The results suggest that methanolic extract of the Dwarf red variety has partial antimalarial activity at higher doses, but is capable of impairing normal kidney and liver function as well

Exceptionally High Efficient Co-Co2P@N, P-Codoped Carbon Hybrid Catalyst for Visible Light-Driven CO2-to-CO Conversion.

PubMed

Fu, Wen Gan

2018-05-02

Artificial photosynthesis has attracted wide attention, particularly the development of efficient solar light-driven methods to reduce CO2 to form energy-rich carbon-based products. Because CO2 reduction is an uphill process with a large energy barrier, suitable catalysts are necessary to achieve this transformation. In addition, CO2 adsorption on a catalyst and proton transfer to CO2 are two important factors for the conversion reaction，and catalysts with high surface area and more active sites are required to improve the efficiency of CO2 reduction. Here, we report a visible light-driven system for CO2-to-CO conversion that consists of a heterogeneous hybrid catalyst of Co and Co2P nanoparticles embedded in carbon nanolayers codoped with N and P (Co-Co2P@NPC) and a homogeneous Ru(II)-based complex photosensitizer. The average generation rate of CO of the system was up to 35,000 μmol h-1 g-1 with selectivity of 79.1% in 3 h. Linear CO production at an exceptionally high rate of 63,000 μmol h-1 g-1 was observed in the first hour of reaction. Inspired by this highly active catalyst, we also synthesized Co@NC and Co2P@NPC materials and explored their structure, morphology, and catalytic properties for CO2 photoreduction. The results showed that the nanoparticle size, partially adsorbed H2O molecules on the catalyst surface, and the hybrid nature of the systems influenced their photocatalytic CO2 reduction performance. © 2018 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

Small-scale Forearc Structure from Residual Bathymetry and Vertical Gravity Gradients at the Cocos-North America Subduction Zone offshore Mexico

NASA Astrophysics Data System (ADS)

Garcia, E. S. M.; Ito, Y.

2017-12-01

The subduction of topographic relief on the incoming plate at subduction zones causes deformation of the plate interface as well as the overriding plate. Whether the resulting geometric irregularities play any role in inhibiting or inducing seismic rupture is a topic of relevance for megathrust earthquake source studies. A method to discern the small-scale structure at subduction zone forearcs was recently developed by Bassett and Watts (2015). Their technique constructs an ensemble average of the trench-perpendicular topography, and the removal of this regional tectonic signal reveals the short-wavelength residual bathymetric anomalies. Using examples from selected areas at the Tonga, Mariana, and Japan subduction zones, they were able to link residual bathymetric anomalies to the subduction of seamount chains, given the similarities in wavelength and amplitude to the morphology of seamounts that have yet to subduct. We focus here on an analysis of forearc structures found in the Mexico segment of the Middle America subduction zone, and their potential mechanical interaction with areas on the plate interface that have been previously identified as source regions for earthquake ruptures and aseismic events. We identified several prominent residual bathymetric anomalies off the Guerrero and Oaxaca coastlines, mainly in the shallow portion of the plate interface and between 15 and 50 kilometers away from the trench axis. The residual amplitude of these bathymetric anomalies is typically in the hundreds of meters. Some of the residual bathymetric anomalies offshore Oaxaca are found landward of seamount chains on the incoming Cocos Plate, suggesting that these anomalies are associated with the prior subduction of seamounts at the margin. We also separated the residual and regional components of satellite-based vertical gravity gradient data using a directional median filter to isolate the possible gravity signals from the seamount edifices.

3D hierarchical porous cobalt monoxide nanoplates with a book-like structure derived from Co(CO3)0.5(OH)·0.11H2O: two-steps oriented attachment and high-performance asymmetric supercapacitors

NASA Astrophysics Data System (ADS)

Xiao, Yuanhua; Zhao, Xiaobing; Jin, Qingxian; Su, Dangcheng; Wang, Xuezhao; Wu, Shide; Zhou, Liming; Fang, Shaoming

2017-10-01

3D Hierarchical porous cobalt monoxide (CoO) nanoplates with a book-like structure derive from Co(CO3)0.5(OH)·0.11H2O by a two-steps oriented attachment mechanism in the solvothermal process. Firstly, nanoplates are formed by oriented attachment of nanorods. Secondly, new nanoplates could be generated on the old nanoplates by a sloped oriented attachment of nanorods with the based nanoplates shape into a 3D hierarchical book-like structure. The CoO nanoplates show superior specific capacitance about 1221.7 F g-1 at 1 A g-1 to most of the Co-based supercapacitor materials up to date. An asymmetric supercapacitor (ASC) based on positive electrode CoO and negative electrode active carbon (AC) exhibits an excellent energy density of 50.1 Wh kg-1 at a power density of 589 W kg-1 and gets a satisfactory cycling stability (86.3% of its initial capacitance retention at 10 A g-1 over 10 000 cycles).

Analyses of gibberellins in coconut (Cocos nucifera L.) water by partial filling-micellar electrokinetic chromatography-mass spectrometry with reversal of electroosmotic flow.

PubMed

Ge, Liya; Yong, Jean Wan Hong; Tan, Swee Ngin; Hua, Lin; Ong, Eng Shi

2008-05-01

In this paper, we present the results of simultaneous screening of eight gibberellins (GAs) in coconut (Cocos nucifera L.) water by MEKC directly coupled to ESI-MS detection. During the development of MEKC-MS, partial filling (PF) was used to prevent the micelles from reaching the mass spectrometer as this is detrimental to the MS signal, and a cationic surfactant, cetyltrimethylammonium hydroxide, was added to the electrolyte to reverse the EOF. On the basis of the resolution of the neighboring peaks, different parameters (i.e., the pH and concentration of buffer, surfactant concentrations, length of the injected micellar plug, organic modifier, and applied separation voltage) were optimized to achieve a satisfactory PF-MEKC separation of eight GA standards. Under optimum conditions, a baseline separation of GA standards, including GA1, GA3, GA5, GA6, GA7, GA9, GA12, and GA13, was accomplished within 25 min. Satisfactory results were obtained in terms of precision (RSD of migration time below 0.9%), sensitivity (LODs in the range of 0.8-1.9 microM) and linearity (R2 between 0.981 and 0.997). MS/MS with multiple reaction monitoring (MRM) detection was carried out to obtain sufficient selectivity. PF-MEKC-MS/MS allowed the direct identification and confirmation of the GAs presented in coconut water (CW) sample after SPE, while, the quantitative analysis of GAs was performed by PF-MEKC-MS approach. GA1 and GA3 were successfully detected and quantified in CW. It is anticipated that the current PF-MEKC-MS method can be applicable to analyze GAs in a wide range of biological samples.

Isolation of the endosperm-specific LPAAT gene promoter from coconut (Cocos nucifera L.) and its functional analysis in transgenic rice plants.

PubMed

Xu, Li; Ye, Rongjian; Zheng, Yusheng; Wang, Zhekui; Zhou, Peng; Lin, Yongjun; Li, Dongdong

2010-09-01

As one of the key tropical crops, coconut (Cocos nucifera L.) is a member of the monocotyledonous family Aracaceae (Palmaceae). In this study, we amplified the upstream region of an endosperm-specific expression gene, Lysophosphatidyl acyltransferase (LPAAT), from the coconut genomic DNA by chromosome walking. In this sequence, we found several types of promoter-related elements including TATA-box, CAAT-box and Skn1-motif. In order to further examine its function, three different 5'-deletion fragments were inserted into pBI101.3, a plant expression vector harboring the LPAAT upstream sequence, leading to pBI101.3-L1, pBI101.3-L2 and pBI101.3-L3, respectively. We obtained transgenic plants of rice by Agrobacterium-mediated callus transformation and plant regeneration and detected the expression of gus gene by histochemical staining and fluorometric determination. We found that gus gene driven by the three deletion fragments was specifically expressed in the endosperm of rice seeds, but not in the empty vector of pBI101.3 and other tissues. The highest expression level of GUS was at 15 DAF in pBI101.3-L3 and pBI101.3-L2 transgenic lines, while the same level was detected at 10 DAF in pBI101.3-L1. The expression driven by the whole fragment was up to 1.76- and 2.8-fold higher than those driven by the -817 bp and -453 bp upstream fragments, and 10.7-fold higher than that driven by the vector without the promoter. Taken together, our results strongly suggest that these promoter fragments from coconut have a significant potential in genetically improving endosperm in main crops.

Correlation between the distribution of lignin and pectin and distribution of sorbed metal ions (lead and zinc) on coir (Cocos nucifera L.).

PubMed

Conrad, Kathrine

2008-11-01

Plant fibres are capacious for sorption of metal ions, and can be used in water cleaning. Knowledge about the sorption will help in selection of the fibre and optimisation of its chemical modification, if any. The aim of this paper is to investigate the connection, if any, between the distribution of lignin and pectin and the loading of Pb and Zn on coir (mesocarp fibres from Cocos nucifera L.). The coir consisted mainly of xylem and a fibre sheath. The lignin was evenly distributed in the cell walls of the fibre sheath, but in the xylem, there was no detectable content in the compound middle lamella, and a smaller content of lignin in the secondary walls than in the walls of the fibre sheath. The only detectable content of pectin in the fibre sheath walls was in the middle lamella, cell corners and extracellular matrix, while in the xylem, the pectin was almost evenly distributed in the wall, with a higher concentration in the middle lamella and cell corners. All cell walls facing the lacuna had a high content of pectin. The metal ions were mainly loaded on the xylem and cell walls facing the lacuna, maybe with an additional trend to be loaded on the large fibres. Lead was distributed on and across the whole secondary wall. Zinc was loaded on the secondary walls, but there was no information about the distribution across the wall. If there is a simple correlation between the loading of metal ions and the distribution of lignin or pectin, these investigations point at no correlation with lignin and a positive correlation with pectin. It has to be stressed that these conclusions are made on limited material and are therefore preliminary in nature.

Intermediate-depth earthquakes within young Cocos plate beneath Central Mexico: A hypothesis test for dehydration embrittlement and shear instability

NASA Astrophysics Data System (ADS)

Song, T.

2010-12-01

Subducting slab undergoes a series of dehydration reactions on their ways into the mantle and these processes are responsible for transporting water, recycling volatiles and chemical elements in arc magmas. It is generally accepted that the SOC is hydrated. However, it is not clear if subducting oceanic mantle (SOM) is hydrated and how deep the hydration is. Seismic refraction studies found that normal-fault type faulting can extend 12-20 km deep into the interior of the slab off Nicaragua, suggesting deep hydration of the SOM. Seismic refraction studies also found that the uppermost SOM is seismically slow and is partially serpentinized. The fluids released from dehydration inside the SOM can reduce the normal stress locally and facilitate the occurrences of intra-slab events through dehydration embrittlement and hydraulic fracture. It has been suggested that the dehydration of antigorite at about 600C is particularly important in facilitating the lower plane of the double seismic zone. To link the dehydration process to the occurrences of intra-slab events, it is critical to clarify where these events are located, either located at the dehydration boundary or in the neighborhood rocks. However, if the SOM is anhydrous, other mechanism, such as shear instabilities, has to be invoked to explain the occurrences of intermediate-depth intraslab earthquakes. Here I discuss locations of intermediate-depth intraslab earthquakes in Central Mexico subduction zone, where young Cocos plate subducts beneath North America plate. Recent studies involving local converted wave modeling and receiver function analysis indicate the presence of an ultra-slow velocity layer (USL) of about 3 km thick, likely an over-pressured upper oceanic crust. Most events display anomalously large converted SP waves that are 2-2.5 secs after direct P waves and finite difference modeling converge the location of these events about 9 km below the lower boundary USL. With a lower oceanic crust of about

Identification and computational annotation of genes differentially expressed in pulp development of Cocos nucifera L. by suppression subtractive hybridization

PubMed Central

2014-01-01

Background Coconut (Cocos nucifera L.) is one of the world’s most versatile, economically important tropical crops. Little is known about the physiological and molecular basis of coconut pulp (endosperm) development and only a few coconut genes and gene product sequences are available in public databases. This study identified genes that were differentially expressed during development of coconut pulp and functionally annotated these identified genes using bioinformatics analysis. Results Pulp from three different coconut developmental stages was collected. Four suppression subtractive hybridization (SSH) libraries were constructed (forward and reverse libraries A and B between stages 1 and 2, and C and D between stages 2 and 3), and identified sequences were computationally annotated using Blast2GO software. A total of 1272 clones were obtained for analysis from four SSH libraries with 63% showing similarity to known proteins. Pairwise comparing of stage-specific gene ontology ids from libraries B-D, A-C, B-C and A-D showed that 32 genes were continuously upregulated and seven downregulated; 28 were transiently upregulated and 23 downregulated. KEGG (Kyoto Encyclopedia of Genes and Genomes) analysis showed that 1-acyl-sn-glycerol-3-phosphate acyltransferase (LPAAT), phospholipase D, acetyl-CoA carboxylase carboxyltransferase beta subunit, 3-hydroxyisobutyryl-CoA hydrolase-like and pyruvate dehydrogenase E1 β subunit were associated with fatty acid biosynthesis or metabolism. Triose phosphate isomerase, cellulose synthase and glucan 1,3-β-glucosidase were related to carbohydrate metabolism, and phosphoenolpyruvate carboxylase was related to both fatty acid and carbohydrate metabolism. Of 737 unigenes, 103 encoded enzymes were involved in fatty acid and carbohydrate biosynthesis and metabolism, and a number of transcription factors and other interesting genes with stage-specific expression were confirmed by real-time PCR, with validation of the SSH results as

Identification and computational annotation of genes differentially expressed in pulp development of Cocos nucifera L. by suppression subtractive hybridization.

PubMed

Liang, Yuanxue; Yuan, Yijun; Liu, Tao; Mao, Wei; Zheng, Yusheng; Li, Dongdong

2014-08-02

Coconut (Cocos nucifera L.) is one of the world's most versatile, economically important tropical crops. Little is known about the physiological and molecular basis of coconut pulp (endosperm) development and only a few coconut genes and gene product sequences are available in public databases. This study identified genes that were differentially expressed during development of coconut pulp and functionally annotated these identified genes using bioinformatics analysis. Pulp from three different coconut developmental stages was collected. Four suppression subtractive hybridization (SSH) libraries were constructed (forward and reverse libraries A and B between stages 1 and 2, and C and D between stages 2 and 3), and identified sequences were computationally annotated using Blast2GO software. A total of 1272 clones were obtained for analysis from four SSH libraries with 63% showing similarity to known proteins. Pairwise comparing of stage-specific gene ontology ids from libraries B-D, A-C, B-C and A-D showed that 32 genes were continuously upregulated and seven downregulated; 28 were transiently upregulated and 23 downregulated. KEGG (Kyoto Encyclopedia of Genes and Genomes) analysis showed that 1-acyl-sn-glycerol-3-phosphate acyltransferase (LPAAT), phospholipase D, acetyl-CoA carboxylase carboxyltransferase beta subunit, 3-hydroxyisobutyryl-CoA hydrolase-like and pyruvate dehydrogenase E1 β subunit were associated with fatty acid biosynthesis or metabolism. Triose phosphate isomerase, cellulose synthase and glucan 1,3-β-glucosidase were related to carbohydrate metabolism, and phosphoenolpyruvate carboxylase was related to both fatty acid and carbohydrate metabolism. Of 737 unigenes, 103 encoded enzymes were involved in fatty acid and carbohydrate biosynthesis and metabolism, and a number of transcription factors and other interesting genes with stage-specific expression were confirmed by real-time PCR, with validation of the SSH results as high as 66.6%. Based on

Microstructural observations on hydrothermal veins of Site U1414, IODP Expedition 344 (CRISP 2)

NASA Astrophysics Data System (ADS)

Brandstätter, Jennifer; Kurz, Walter; Rogowitz, Anna

2017-04-01

The erosive active margin offshore Osa Peninsula (Costa Rica) is characterized by the subducting Cocos Plate with its topographic height, the aseismic Cocos Ridge, which has lifted the seismogenic zone in the reach of scientific drilling. To understand the processes occurring in the subducting Cocos Plate in the vicinity to the Middle America Trench, we investigated microstructures in hydrothermal veins, transecting the lithified sediments and the igneous basement of IODP Hole U-1414A. Mechanical e-twinning occurred mainly in the blocky calcite veins in the lithified sediments, rather than in the fibrous calcite veins within the Cocos Ridge basalt. The differential stress, obtained from two different piezometers, indicate mean differential stresses of approximately 53 and 82 MPa. The majority of the twins show a significant thickness (up to 120 µm), straight twin boundaries and are indicative for deformation temperatures between 150 to 300°C. The presence of additional deformation structures, such as undulose extinction and subgrain boundaries, indicates intracrystalline-plastic deformation by dislocation creep. The comparison of the EBSD data from two samples within the lithified sedimentary unit indicates diverse deformation temperatures. Variation in subgrain size observed for the different samples can be related to local variations in differential stress. The results of different microstructural observations showed, that the deformational history of Site 344-U1414 is characterized by distinct tectonic phases, occurring during the movement of the Cocos Ridge from its location of origin (the Galapagos hotspot) to the convergent margin offshore Costa Rica. The causes for these changes in deformation mechanisms in the studied rocks are ascribed to magmatic advection resulting in an increase of temperature and decrease of critical resolved shear stresses, as well as the bending of the Cocos plate adjacent to the Middle American trench.

Proximate composition, extraction, characterization and comparative assessment of coconut (Cocos nucifera) and melon (Colocynthis citrullus) seeds and seed oils.

PubMed

Obasi, N A; Ukadilonu, Joy; Eze, Eberechukwu; Akubugwo, E I; Okorie, U C

2012-01-01

Proximate composition, extraction, characterization and comparative assessment of Cocos nucifera and Colocynthis citrullus seeds and seed oils were evaluated in this work using standard analytical techniques. The results showed the percentage (%) moisture, crude fibre, ash, crude protein, lipids and total carbohydrate contents of the seeds as 7.51 and 4.27, 7.70 and 5.51, 1.02 and 2.94, 10.57 and 11.67, 47.80 and 50.42 and 32.84 and 29.47 while the calorific values were 553.99 and 567.32 Kcal/100 g for C. nucifera and C. citrullus, respectively. The two seed oils were odourless and at room temperature (30 degrees C) liquids, with a pale yellow to yellowish colouration. Lipid indices of the seed oils indicated the Acid Values (AV) as 2.06-6.36 mg NaOH g(-1) and 2.99-6.17 mg NaOH g(-1), Free Fatty Acids (FFA) as 1.03-3.18 and 1.49-3.09%, Saponification Values (SV) as 252.44-257.59 and 196.82-201.03 mg KOH g(-1), Iodine Values (IV) as 9.73-10.99 and 110.93-111.46 mg of I2 g(-1) of oil and Peroxide Values (PV) as 0.21-0.21 and 1.53-2.72 mg O2 kg(-1) for soxhlet-mechanical extracted C. nucifera and C. citrullus seed oils, respectively. The studied characteristics of the oil extracts in most cases compared favourably with most conventional vegetable oils sold in the Nigeria markets; however, there were some observed levels of significant differences in the values at p < or = 0.05. These results suggest that the seeds examined may be nutritionally potent and also viable sources of seed oils judging by their oil yield. The data also showed that the seed oils were edible inferring from their low AV and their corresponding low FFA contents. Industrially, the results revealed the seed oils to have great potentials in soap manufacturing industries because of their high SV. They were also shown to be non-drying due to their low IV which also suggested that the oils contain few unsaturated bonds and therefore have low susceptibility to oxidative rancidity and deterioration as

The solubility of carbon monoxide in silicate melts at high pressures and its effect on silicate phase relations. [in terrestrial and other planetary interiors

NASA Technical Reports Server (NTRS)

Eggler, D. H.; Mysen, B. O.; Hoering, T. C.; Holloway, J. R.

1979-01-01

Autoradiographic analysis and gas chromatography were used to measure the solubility in silicate melts of CO-CO2 vapors (30 to 40% CO by thermodynamic calculation) in equilibrium with graphite at temperatures up to 1700 deg C and pressures to 30 kbar. At near-liquidus temperatures CO-CO2 vapors were found to be slightly more soluble than CO2 alone. As a result of the apparently negative temperature dependence of CO solubility, the solubility of CO-CO2 at superliquidus temperatures is less than that of CO2. Melting points of two silicates were depressed more by CO than by CO2. Phase boundary orientations suggest that CO/CO + CO2 is greater in the liquid than in the vapor. The effect of the presence of CO on periodotite phase relations was investigated, and it was found that melts containing both CO and CO2 are nearly as polymerized as those containing only CO2. These results suggest that crystallization processes in planetary interiors can be expected to be about the same, whether the melts contain CO2 alone or CO2 and CO.

Species of Concern (SOC) on Department of Defense Installations

DTIC Science & Technology

2002-07-15

HODI, RUUR, SYAL , OEMLERIA CERASIFORMIS/DISPORUM HOOKERI, POLYSTICHUM, SMILACINA RACEMOSA, HYDROPHYLLUM TENUIPES, ADENOCAULON BICOLOR, TELLIMA...SPECIES: ACCI, SYAL ,RHAI,COCO. HERBS:POMU,POMU,DRAR,TROV,SMST,DIHO,VAHE,ACRU,RUUR,ADBI,LICO ,GATR,DSCH,TEGR.* SOC on DOD Installations FINAL – July...SITE. ORGANIC LAYER OVERSOIL. ASSOC. W/GASH, POMU, COCO, RHDI, ACTAEA RUBRA, SYAL .* OLD GROWTH PSME. UNDERSTORY OF CORYLUS CORNUTA, ACMA, ACCI. GROUND

Biodiversity and density of subtidal benthos of an oceanic tropical island (a comparison within the Pacific Ocean)

NASA Astrophysics Data System (ADS)

Sibaja-Cordero, Jeffrey A.; Troncoso, Jesús S.; Cortés, Jorge; Moreira, Juan; Vargas, José A.; Benavides-Varela, Catalina

2016-09-01

The marine macrofauna of the shallow sandy bottom of Isla del Coco, Costa Rica (5°32‧N-87°04‧W) was assessed in April 2010. Comparisons of richness, density and diversity between levels of exposure to ocean influence were carried out. During this study 15,407 specimens with a mean density of 1826 ind m- 2 were found between 3-75 m depth. The specimens were distributed in 267 taxa (29% new additions) with a mean of 55 ± 14 expected taxa m- 2. The values of density, richness and diversity were higher at the exposed coast, whereas they decreased at inner bays due to the influence of freshwater input. These estimates were compared with 40 studies in the Tropical Pacific Ocean (TPO). Taxa and density previously reported from the TPO were dependent on the area and depth range studied. Additionally, these parameters varied according to the sampling gear used. For example, higher densities were reported by using corers or boxcorers. The Shannon-Wiener index was most effective in identifying sediment and geographical patterns of variation along the TPO. Differences in these diversity parameters were also found between islands and mainland studies. Moreover, richness and density values from Isla del Coco were higher than the same parameters reported in studies using grabs in the TPO. At Isla del Coco annelids were dominant in terms of relative abundance (49.6%), followed by crustaceans (10.1%), mollusks (2.8%), and others faunal groups (37.5%). The faunistic composition at Isla del Coco differed when compared to the rest of localities of TPO due to the higher contribution of miscellaneous groups. In conclusion, the comparison with previous studies in the TPO indicate that islands like Isla del Coco have high numbers of taxa and diversity than those of the mainland, but lower density. However, this value is influenced by the sampling methodology. The taxa accumulation curve at Isla del Coco did not reach the asymptote, suggesting that an intensive sampling, especially

On the merging rates of envelope-deprived components of binary systems which can give rise to supernova events

NASA Astrophysics Data System (ADS)

Tornambe, Amedeo

1989-08-01

Theoretical rates of mergings of envelope-deprived components of binary systems, which can give rise to supernova events are described. The effects of the various assumptions on the physical properties of the progenitor system and of its evolutionary behavior through common envelope phases are discussed. Four cases have been analyzed: CO-CO, He-CO, He-He double degenerate mergings and He star-CO dwarf merging. It is found that, above a critical efficiency of the common envelope action in system shrinkage, the rate of CO-CO mergings is not strongly sensitive to the efficiency. Below this critical value, no CO-CO systems will survive for times larger than a few Gyr. In contrast, He-CO dwarf systems will continue to merge at a reasonable rate up to 20 Gyr, and more, also under extreme conditions.

Autophagy and TGF-Beta Antagonist Signaling in Breast Cancer Dormancy at Premetastatic Sites

DTIC Science & Technology

2015-06-01

blocking Coco and other players involved in reactivation of dormant legions. These inhibitors will be the drug leads for further medicinal chemistry and...blocking Coco and other players involved in reactivation of dormant legions. These inhibitors will be the drug leads for further medicinal chemistry and... protocol . Below we report our progress, starting with the SOW check list below followed by detailed description. Statement of Work (SOW): Task-1

Bolide impacts and the oxidation state of carbon in the Earth's early atmosphere

NASA Technical Reports Server (NTRS)

Kasting, J. F.

1992-01-01

A one-dimensional photochemical model was used to examine the effect of bolide impacts on the oxidation state of Earth's primitive atmosphere. The impact rate should have been high prior to 3.8 Ga before present, based on evidence derived from the Moon. Impacts of comets or carbonaceous asteroids should have enhanced the atmospheric CO/CO2 ratio by bringing in CO ice and/or organic carbon that can be oxidized to CO in the impact plume. Ordinary chondritic impactors would contain elemental iron that could have reacted with ambient CO2 to give CO. Nitric oxide (NO) should also have been produced by reaction between ambient CO2 and N2 in the hot impact plumes. High NO concentrations increase the atmospheric CO/CO2 ratio by increasing the rainout rate of oxidized gases. According to the model, atmospheric CO/CO2 ratios of unity or greater are possible during the first several hundred million years of Earth's history, provided that dissolved CO was not rapidly oxidized to bicarbonate in the ocean. Specifically, high atmospheric CO/CO2 ratios are possible if either: (1) the climate was cool (like today's climate), so that hydration of dissolved CO to formate was slow, or (2) the formate formed from CO was efficiently converted into volatile, reduced carbon compounds, such as methane. A high atmospheric CO/CO2 ratio may have helped to facilitate prebiotic synthesis by enhancing the production rates of hydrogen cyanide and formaldehyde. Formaldehyde may have been produced even more efficiently by photochemical reduction of bicarbonate and formate in Fe(++)-rich surface waters.

Frictional properties of silicic to calcareous ooze on the Cocos Plate entering the Costa Rica Subduction Zone

NASA Astrophysics Data System (ADS)

Tsutsumi, A.; Kameda, J.; Ujiie, K.

2012-12-01

Here we report experimental results on the frictional properties of the cover sediments on the Cocos plate incoming into the erosive Costa Rica subduction zone. Mechanical properties of the incoming sediments to subduction plate boundaries are essential to constrain subduction-related faulting processes. However, knowledge of the frictional properties of sediments composed of abundant biogenic component, such as spicules, diatoms, and radiolarians are limited. Experimental samples were silicic to calcareous ooze collected at a reference site (Site U1381) off shore Osa Peninsula during IODP Expedition 334 (Vannucchi et al., 2012). To be used in the experiments, the discrete samples was disaggregated, oven dried at 60 degrees centigrade for 24 hours. The experimental fault is composed of a 24.9 mm diameter cylinder of gabbro cut perpendicularly to the cylinder axis in two halves that are ground to obtain rough wall surfaces, and re-assembled with an intervening thin layer (~1.0 mm) disaggregated sample. Frictional experiments have been performed using a rotary-shear friction testing machine, at normal stresses up to 5 MPa, over a range of slip velocities from 0.0026 mm/s to 1.3 m/s, with more than ~150 mm of displacements for water saturated condition. Experimental results reveal that friction values at slow slip velocities (v < ~30 mm/s) are about ~0.7, of which level is comparable to the typically reported friction values for rocks. The experimental faults exhibited velocity-weakening at v < 0.3 mm/s and neutral to velocity-strengthening at 0.3 < v < ~3 mm/s. At higher velocities (v > ~30 mm/s), steady state friction decreases dramatically. For example, at a velocity of 260 mm/s, the friction coefficient for samples U1381A-9R and -10R show a gradual decrease with a large weakening displacement toward the establishment of a nearly constant level of friction at ~0.1. The velocity weakening behavior at slow velocities could provide a condition to initiate unstable

Structure of the Malpelo Ridge (Colombia) from seismic and gravity modelling

NASA Astrophysics Data System (ADS)

Marcaillou, Boris; Charvis, Philippe; Collot, Jean-Yves

2006-12-01

Wide-angle and multichannel seismic data collected on the Malpelo Ridge provide an image of the deep structure of the ridge and new insights on its emplacement and tectonic history. The crustal structure of the Malpelo Ridge shows a 14 km thick asymmetric crustal root with a smooth transition to the oceanic basin southeastward, whereas the transition is abrupt beneath its northwestern flank. Crustal thickening is mainly related to the thickening of the lower crust, which exhibits velocities from 6.5 to 7.4 km/s. The deep structure is consistent with emplacement at an active spreading axis under a hotspot like the present-day Galapagos Hotspot on the Cocos-Nazca Spreading Centre. Our results favour the hypothesis that the Malpelo Ridge was formerly a continuation of the Cocos Ridge, emplaced simultaneously with the Carnegie Ridge at the Cocos-Nazca Spreading Centre, from which it was separated and subsequently drifted southward relative to the Cocos Ridge due to differential motion along the dextral strike-slip Panama Fracture Zone. The steep faulted northern flank of the Malpelo Ridge and the counterpart steep and faulted southern flank of Regina Ridge are possibly related to a rifting phase that resulted in the Coiba Microplate’s separation from the Nazca Plate along the Sandra Rift.

Middle to Late Miocene Contractional Deformation in Costa Rica Triggered by Plate Geodynamics

NASA Astrophysics Data System (ADS)

Mescua, José Francisco; Porras, Hernán.; Durán, Patrick; Giambiagi, Laura; de Moor, Maarten; Cascante, Monserrat; Salazar, Esteban; Protti, Marino; Poblete, Fernando

2017-12-01

Contractional deformation in Costa Rica is usually attributed to the subduction of the aseismic Cocos Ridge. In this work, we review the evidences for contraction in the middle to late Miocene, prior to the arrival of the Cocos Ridge at the Middle America Trench. We find that the Miocene phase of contractional deformation is found in all of Costa Rica, probably extending to Nicaragua as well. The widespread distribution of this event requires a regional or plate geodynamic trigger. We analyze the possible mechanisms that could produce the onset of contractional deformation, using the better known case of subduction orogeny, the Andes, as an analog. We propose that a change in the direction of the Cocos plate since ˜19 Ma led to a change from oblique to orthogonal convergence, producing contractional deformation of the upper plate.

Lower plate deformation structures along the Costa Rica erosive plate boundary - results from IODP Expedition 344 (CRISP 2)

NASA Astrophysics Data System (ADS)

Brandstätter, Jennifer; Kurz, Walter; Micheuz, Peter; Krenn, Kurt

2015-04-01

The primary objective of Integrated Ocean Drilling Program (IODP) Expedition 344 offshore the Osa Peninsula in Costa Rica was to sample and quantify the material entering the seismogenic zone of the Costa Rican erosive subduction margin. Fundamental to this objective is an understanding of the nature of both the subducting Cocos plate crust and of the overriding Caribbean plate. The subducting Cocos plate is investigated trying to define its hydrologic system and thermal state. The forearc structures recorded by the sediment deposited on the forearc, instead, document periods of uplift and subsidence and provide important information about the process of tectonic erosion that characterizes the Costa Rica margin. Offshore the western margin of Costa Rica, the oceanic Cocos plate subducts under the Caribbean plate, forming the southern end of the Middle America Trench. Subduction parameters including the age, convergence rate, azimuth, obliquity, morphology, and slab dip all vary along strike. The age of the Cocos plate at the Middle America Trench decreases from 24 Ma offshore the Nicoya Peninsula to 15 Ma offshore the Osa Peninsula. Subduction rates vary from 70 mm/y offshore Guatemala to 90 mm/y offshore southern Costa Rica. Convergence obliquity across the trench varies from offshore Nicaragua, where it is as much as 25° oblique, to nearly orthogonal southeast of the Nicoya Peninsula. Passage of the Cocos plate over the Galapagos hotspot created the aseismic Cocos Ridge, an overthickened welt of oceanic crust. This ridge is ~25 km thick, greater than three times normal oceanic crustal thickness. During IODP Expedition 344, the incoming Cocos plate was drilled at sites U1381 and U1414. Site U1381 is located ~4.5 km seaward of the deformation front offshore the Osa Peninsula and Caño Island. It is located on a local basement high. Basement relief often focuses fluid flow, so data from this site are likely to document the vigor of fluid flow in this area. Site U

Linked hydro-thermo-chemo-microbiological processes within a cool hydrothermal circulation system in 18-24 M.y. old seafloor of the Cocos Plate

NASA Astrophysics Data System (ADS)

Fisher, A. T.; Wheat, C. G.; Lauer, R. M.; Villinger, H. W.; McManus, J.; Orcutt, B.

2017-12-01

We present results from surveys and studies of ridge-flank hydrothermal circulation in part of the Cocos Plate. Fluids flowing into and out of the crust in an area >104 km2 extract most of the lithospheric heat. Water moves in and out of the crust through a few mid-plate seamounts, which penetrate low-permeability sediments, and water flows laterally across tens of kilometers between seamounts. This kind of fluid circulation is common globally, extracting 20-25% of Earth's geothermal heat, but focused fluid discharge from these systems has not previously been found or sampled. Sites of discharge from this cool hydrothermal system (CHS) were found and sampled on Dorado Outcrop, a small volcanic edifice on 23 M.y. old seafloor, using deep-submergence vehicles. Seafloor measurements show that Dorado Outcrop is a local site of elevated geothermal heat flux, and temperatures recorded during outcrop surveys show a pattern of small bottom-water temperature anomalies (≤0.04°C, mainly above the central and southern part of the outcrop). Direct measurements of shimmering fluids discharging from patches of bare rock on Dorado Outcrop indicate temperatures up to 10.5°C warmer than bottom water, whereas heat flux and reflection seismic data show regional reaction temperatures in basement of 15-20 °C. Heat budget calculations and coupled fluid-heat simulations of regional circulation indicate that the net discharge from Dorado Outcrop is on the order of 1,000-5,000 L/s, and direct observations show that spring discharge rates vary with time, likely being modulated by ocean tides. Samples of Dorado Outcrop fluids have concentrations that are indistinguishable from bottom seawater for many major ions, but concentrations of minor and trace elements differ significantly, especially Mo, V, Rb, U, phosphate, Li, and silicate. In addition, CHS fluids discharging from Dorado Outcrop have about 50% of the dissolved oxygen (DO) found in bottom seawater, showing that DO is consumed as

Small-Scale Trials Suggest Increasing Applications of Natular™ XRT and Natular™ T30 Larvicide Tablets May Not Improve Mosquito Reduction in Some Catch Basins

PubMed Central

Harbison, Justin E.; Henry, Marlon; Corcoran, Peter C.; Zazra, Dave; Xamplas, Christopher

2016-01-01

Stormwater catch basins are commonly treated with larvicides by mosquito control agencies to reduce local populations of mosquito species capable of transmitting West Nile virus. Recent evidence suggests that extended-release larvicides formulated to last up to 180 days in catch basins may not be effective in some basins due to chronic flushing, rapid dissolution, or burying of treatment in sump debris. To investigate if increasing the number of applications could improve effectiveness, a small study was performed over 13 weeks in 2015 to evaluate two extended-release larvicides (Natular™ XRT 180-day tablets and Natular™ T30 30-day tablets) and a larvicide oil (CocoBear™). Over the course of 13 weeks, three groups of eight basins were monitored for mosquitoes, each group receiving Natular™ XRT, Natular™ T30, or CocoBear™ larvicides. All basins received a single application at the beginning of the study period. Once mosquitoes in a basin surpassed the treatment threshold during weekly monitoring, an additional application of the associated larvicide was given to that basin. The number of applications during the study period ranged from 1 to 10 for CocoBear™ basins, 1 to 7 for T30 basins, and 2 to 8 for XRT basins. Overall, the average number of applications and the cost of larvicide per basin were 4.4 applications at $0.66 per Coco-Bear™ basin, 4.4 applications at $6.26 per T30 basin, and 4 applications at $16.56 per XRT basin. Basins treated with XRT and T30 needed reapplications more often than expected, yet were no more effective than CocoBear™, suggesting that increasing the frequency of application of these larvicide formulations may not provide increased mosquito reduction in some basins. PMID:26792998

High-Efficiency Co/CoxSy@S,N-Codoped Porous Carbon Electrocatalysts Fabricated from Controllably Grown Sulfur- and Nitrogen-Including Cobalt-Based MOFs for Rechargeable Zinc-Air Batteries.

PubMed

Liu, Shengwen; Zhang, Xian; Wang, Guozhong; Zhang, Yunxia; Zhang, Haimin

2017-10-04

Developing bifunctional oxygen electrocatalysts with superior catalytic activities of oxygen reduction reaction (ORR) and oxygen revolution reaction (OER) is crucial to their practical energy storage and conversion applications. In this work, we report the fabrication of Co/Co x S y @S,N-codoped porous carbon structures with various morphologies, specific surface areas, and pore structures, derived from controllably grown Co-based metal-organic frameworks with S- and N-containing organic ligands (thiophene-2,5-dicarboxylate, Tdc; and 4,4'-bipyridine, bpy) utilizing solvent effect (e.g., water and methanol) under room temperature and hydrothermal conditions. The results demonstrate that Co/Co x S y @S,N-codoped carbon fibers fabricated at a pyrolytic temperature of 800 °C (Co/Co x S y @SNCF-800) from Co-MOFs fibers fabricated in methanol under hydrothermal conditions as electrocatalysts exhibit superior bifunctional ORR and OER activities in alkaline media, endowing them as air cathodic catalysts in rechargeable zinc-air batteries with high power density and good durability.

Deformation of the Western Caribbean: Insights from Block and Geodynamic Models of Geodetic, Seismic and Geologic Data

NASA Astrophysics Data System (ADS)

La Femina, P. C.; Geirsson, H.; Kobayashi, D.

2012-12-01

Cocos - Caribbean convergence along the Middle America Trench, including subduction of the Cocos Ridge and seamount domain, and Nazca - Caribbean oblique convergence along the South Panama Deformed Belt have resulted in complex plate boundary zone deformation since Miocene - Pliocene time. Plate boundary evolution and upper plate deformation in the western Caribbean is well studied and indicates, 1) Quaternary migration of the volcanic arc toward the back-arc northwest of the Cocos Ridge; 2) Pleistocene to present northwestward motion of the Central American Fore Arc (CAFA); 3) Quaternary to present deformation within the Central Costa Rica Deformed Belt; 4) Miocene-Pliocene cessation of volcanism and uplift of the Cordillera de Talamanca inboard the ridge; 5) Quaternary to present shortening across the fore-arc Fila Costeña fold and thrust belt and back-arc North Panama Deformed Belt (NPDB); 6) Quaternary to present outer fore-arc uplift above the seamount domain (Nicoya Peninsula), and above (Osa Peninsula) and flanking (Burica Peninsula) the ridge; and 7) Quaternary to present faulting along the Sona-Azuero and Canal Discontinuity fault systems. We investigate the dynamic effects of Cocos and Nazca convergence along the entire Central American margin, and the implications on western Caribbean plate boundary evolution with a new GPS derived three-dimensional (horizontal and vertical) velocity field and kinematic block and geodynamic models. Specifically, we test the hypotheses that the Cocos Ridge is the main driver for upper plate deformation and that there is an independent Panama block. Our model results provide new Euler vectors for the CAFA and Panama block, rates of relative plate and block motions in the region, and constraints on interseismic coupling along the Middle America Trench and other major block bounding fault systems. These results are compared to existing geophysical and geologic data for the region and add insights into the rates of

Dietary fibers from mushroom sclerotia: 3. In vitro fermentability using human fecal microflora.

PubMed

Wong, Ka-Hing; Wong, King-Yee; Kwan, Hoi-Shan; Cheung, Peter C K

2005-11-30

The in vitro fermentability of three novel dietary fibers (DFs) prepared from mushroom sclerotia, namely, Pleurotus tuber-regium, Polyporous rhinocerus, and Wolfiporia cocos, was investigated and compared with that of the cellulose control. All DF samples (0.5 g each) were fermented in vitro with a human fecal homogenate (10 mL) in a batch system (total volume, 50 mL) under strictly anaerobic conditions (using oxygen reducing enzyme and under argon atmosphere) at 37 degrees C for 24 h. All three novel sclerotial DFs exhibited notably higher dry matter disappearance (P. tuber-regium, 8.56%; P. rhinocerus, 13.5%; and W. cocos, 53.4%) and organic matter disappearance (P. tuber-regium, 9.82%; P. rhinocerus, 14.6%; and W. cocos, 57.4%) when compared with those of the cellulose control. Nevertheless, only the W. cocos DF was remarkably degraded to produce considerable amounts of total short chain fatty acids (SCFAs) (5.23 mmol/g DF on organic matter basis, with a relatively higher molar ratio of propionate) that lowered the pH of its nonfermented residue to a slightly acidic level (5.89). Variations on the in vitro fermentability among the three sclerotial DFs might mainly be attributed to their different amounts of interwoven hyphae present (different amounts of enzyme inaccessible cell wall components) as well as the possible different structural arrangement (linkage and degree of branching) of their beta-glucans.

Dietary fibers from mushroom sclerotia. 4. In vivo mineral absorption using ovariectomized rat model.

PubMed

Wong, Ka-Hing; Katsumata, Shin-Ichi; Masuyama, Ritsuko; Uehara, Mariko; Suzuki, Kazuharu; Cheung, Peter C K

2006-03-08

The effect of three novel dietary fibers (DFs) prepared from mushroom sclerotia, namely, Pleurotus tuber-regium, Polyporus rhinocerus, and Wolfiporia cocos, on calcium and magnesium absorption was evaluated in ovariectomized (OVX) rats fed with sclerotial DF based and low Ca (0.3%) diets for 14 days. The animals in the W. cocos DF diet group possessed significantly (p < 0.05) higher levels of cecal total short-chain fatty acids (204 mumol/g of cecal content) and had an acidic pH (5.88) in their cecum when compared with those of the cellulose control group. Such an acidic environment was found to promote the ionization of the unabsorbed Ca and Mg in their cecum, which in turn significantly (p < 0.05) increased the concentrations of cecal soluble Ca (2.56-fold) and Mg (1.22-fold). Besides, the apparent Ca and Mg absorptions of the W. cocos DF group were also significantly (p < 0.05) enhanced (Ca, 16.5%; Mg, 15.3%) together with significantly (p < 0.05) higher serum Ca (3.61 mmol/L) and Mg (1.07 mmol/L) levels when compared with those of the cellulose control group. These data suggest that ingestion of W. cocos DF could improve the overall Ca and Mg absorptions of the OVX rats fed a low Ca diet. The potential use of sclerotial DFs as a functional food ingredient for enhancing mineral absorption is also discussed.

Comparison of the effect of two excipients (karite nut butter and vaseline) on the efficacy of Cocos nucifera, Elaeis guineensis and Carapa procera oil-based repellents formulations against mosquitoes biting in Ivory Coast.

PubMed

Konan, Y L; Sylla, M S; Doannio, J M; Traoré, S

2003-06-01

Repellents in the form of dermal pomades are recommended as a protection against awakening and bedtime mosquito bites. If synthesis repellents are available, they are nevertheless not common and the prices remain out of reach for the communities concerned. The people therefore have to resort more and more to traditional concoctions, some of which have been shown to be effective. After demonstrating that oil-based formulations (lotions, creams, pomades) of Cocos nucifera (coconut), Elaeis guineensis (oil palm) and Carapa procera (gobi) were effective against mosquitoes, it became necessary to study the impact of the two excipients used in their manufacture, on the effectiveness of the repellents. Experiments were carried with Anopheles gambiae and Aedes aegypti under lobaratory conditions and any other mosquitoes collected under field conditions in Ivory Coast. The laboratory results indicate that the average protection times obtained with formulations with karite nut butter as excipient (54.8 +/- 37.0 mn and 74.6 +/- 26.4 mn respectively on An. gambiae and Ae. aegypti) are higher than those recorded with vaseline as excipient (respectively 42.7 +/- 30.0 mn and 60.8 +/- 33.9 mn). On the other hand, under field conditions, the biting rate percentage reduction obtained with the products with karite nut butter and vaseline excipient were similar (respectively 29.8% and 35.9% for all mosquitoes collected and 45.7% and 47.4% against An. gambiae). Nevertheless, the use of karite nut butter on repellent products should be encouraged because its sale price is very lower (10 time less) than the vaseline's.

Atmospheric Observations of Carbon Dioxide and Quantification of Fossil Fuel Carbon Dioxide and Emission Inventories using Radiocarbon in the Korean Peninsula during the KORUS-AQ Field Campaign

NASA Astrophysics Data System (ADS)

Choi, Y.; DiGangi, J. P.; Diskin, G. S.; Nowak, J. B.; Halliday, H.; Pusede, S.; Arellano, A. F., Jr.; Tang, W.; Knote, C. J.; Woo, J. H.; Lee, Y.; Kim, Y.; Bu, C.; Blake, D. R.; Simpson, I. J.; Blake, N. J.; Xu, X.

2017-12-01

This presentation discusses a unique data set of airborne in situ carbon dioxide (CO2) and carbon monoxide (CO) soundings and radiocarbon measurements to accurately quantify anthropogenic CO2 emissions from the total measured CO2 signal. Precise assessment of fossil fuel (FF) CO2 gives a better understanding of source contributions to emission inventories in the study region. Fast response (1Hz) and high precision (<0.1 ppm) in situ measurements of atmospheric CO2 and other trace gases, including 60 CO2 radiocarbon measurements from flask samples, onboard the NASA DC-8 aircraft during KORUS-AQ (May-June, 2016), were used in combination with an updated emissions inventory named NIER/KU_CREATE (Comprehensive Regional Emissions inventory for Atmospheric Transport Experiment) to gain a better understanding of pollution characteristics in the study region. Fractional FF CO2 contributions were calculated using radiocarbon and in-situ CO2 concentrations. These quantified FF CO/CO2 ratios from the in situ measurements were compared to the updated emissions inventory. Distinctly higher ratios were found in Chinese outflow, relative to those from the Korean Peninsula, and the emission inventory shows higher CO/CO2 ratios than measurements both in the Korea and China regions. This quantified FF CO/CO2 ratio was applied to continuous measurements of in-situ CO and CO2 and used to identify the portion of biogenic CO2 observed during the field campaign (the biospheric contribution to the total CO2 is typically 20-30 % in this regions). This continuous partitioning of biogenic and anthropogenic sources will give a better understanding of diurnal variations of local sources and will be helpful for the evaluation of emission inventories, where mega-city fossil fuel combustion sources mix with biospheric sources. Also discussed is the comparison of quantified FF CO/CO2 ratios with the CAMS (Copernicus Atmosphere Monitoring Service) simulated products ratios and local source

Bolide impacts and the oxidation state of carbon in the earth's early atmosphere

NASA Technical Reports Server (NTRS)

Kasting, James F.

1990-01-01

A one-dimensional photochemical model was used to examine the effect of bolide impacts on the oxidation state of earth's primitive atmosphere. The impact rate should have been high prior to 3.8 Ga before present, based on evidence derived from the moon. Impacts of comets or carbonaceous asteroids should have enhanced the atmospheric CO/CO2 ratio by bringing in CO ice and/or organic carbon that can be oxidized to CO in the impact plume. Ordinary chondritic impactors would contain elemental iron that could have reacted with ambient CO2 to give CO. Nitric oxide (NO) should also have been produced by reaction between ambient CO2 and N2 in the hot impact plumes. High NO concentrations increase the atmospheric CO/CO2 ratio by increasing the rainout rate of oxidized gases. According to the model, atmospheric CO/CO2 ratios of unity or greater are possible during the first several hundred million years of earth's history, provided that dissolved CO was not rapidly oxidized to bicarbonate in the ocean.

Characterization of fungal sulfated polysaccharides and their synergistic anticancer effects with doxorubicin.

PubMed

Cheng, Jing-Jy; Chang, Chia-Chuan; Chao, Chi-Hsein; Lu, Mei-Kuang

2012-09-01

Sulfated polysaccharides (SPSs) from two edible fungal species, including two strains of Antrodia cinnamomea and Poria cocos, were isolated. Fucose, glucosamine, galactose, glucose, and mannose were the major sugars in the SPSs, and these SPSs had a high sulfate content. The area percentage of low-molecular-weight SPSs (1-100 kDa) covered almost half of the SPS mixture of the A. cinnamomea strains. In contrast, high-molecular-weight SPSs (>1000 kDa) of P. cocos covered a large proportion of the area at 30.06%. SPSs from A. cinnamomea B86 showed stronger inhibition of endothelial cell (EC) tube formation in an in vitro assay of angiogenesis, than did A. cinnamomea 35396 or P. cocos. The degree of sulfation paralleled their antiangiogenic activity. When tumor cells were concurrently exposed to doxorubicin (DOX) and fungal SPSs, SPSs synergistically increased the cytotoxicity of DOX to different degree up to 50-fold. Fungal SPSs may offer new applications for combinational-therapy drugs. Copyright © 2012 Elsevier Ltd. All rights reserved.

A web-based simulation of a longitudinal clinic used in a 4-week ambulatory rotation: a cohort study

PubMed Central

Wong, Rene WG; Lochnan, Heather A

2009-01-01

Background Residency training takes place primarily on inpatient wards. In the absence of a resident continuity clinic, internal medicine residents rely on block rotations to learn about continuity of care. Alternate methods to introduce continuity of care are needed. Methods A web-based tool, Continuity of Care Online Simulations (COCOS), was designed for use in a one-month, postgraduate clinical rotation in endocrinology. It is an interactive tool that simulates the continuing care of any patient with a chronic endocrine disease. Twenty-three residents in internal medicine participated in a study to investigate the effects of using COCOS during a clinical rotation in endocrinology on pre-post knowledge test scores and self-assessment of confidence. Results Compared to residents who did the rotation alone, residents who used COCOS during the rotation had significantly higher improvements in test scores (% increase in pre-post test scores +21.6 [standard deviation, SD, 8.0] vs. +5.9 [SD 6.8]; p < .001). Test score improvements were most pronounced for less commonly seen conditions. There were no significant differences in changes in confidence. Residents rated COCOS very highly, recommending its use as a standard part of the rotation and throughout residency. Conclusion A stand-alone web-based tool can be incorporated into an existing clinical rotation to help residents learn about continuity of care. It has the most potential to teach residents about topics that are less commonly seen during a clinical rotation. The adaptable, web-based format allows the creation of cases for most chronic medical conditions. PMID:19187554

The Copernicus Complexio: a high-resolution view of the small-scale Universe

NASA Astrophysics Data System (ADS)

Hellwing, Wojciech A.; Frenk, Carlos S.; Cautun, Marius; Bose, Sownak; Helly, John; Jenkins, Adrian; Sawala, Till; Cytowski, Maciej

2016-04-01

We introduce Copernicus Complexio (COCO), a high-resolution cosmological N-body simulation of structure formation in the ΛCDM model. COCO follows an approximately spherical region of radius ˜17.4 h-1 Mpc embedded in a much larger periodic cube that is followed at lower resolution. The high-resolution volume has a particle mass of 1.135 × 105 h-1 M⊙ (60 times higher than the Millennium-II simulation). COCO gives the dark matter halo mass function over eight orders of magnitude in halo mass; it forms ˜60 haloes of galactic size, each resolved with about 10 million particles. We confirm the power-law character of the subhalo mass function, overline{N}(>μ )∝ μ ^{-s}, down to a reduced subhalo mass Msub/M200 ≡ μ = 10-6, with a best-fitting power-law index, s = 0.94, for hosts of mass = 1012 h-1 M⊙. The concentration-mass relation of COCO haloes deviates from a single power law for masses M200 < afew × 108 h-1 M⊙, where it flattens, in agreement with results by Sanchez-Conde et al. The host mass invariance of the reduced maximum circular velocity function of subhaloes, ν ≡ Vmax/V200, hinted at in previous simulations, is clearly demonstrated over five orders of magnitude in host mass. Similarly, we find that the average, normalized radial distribution of subhaloes is approximately universal (I.e. independent of subhalo mass), as previously suggested by the Aquarius simulations of individual haloes. Finally, we find that at fixed physical subhalo size, subhaloes in lower mass hosts typically have lower central densities than those in higher mass hosts.

The effect of an East Pacific Rise offset on the formation of secondary cracks ahead of the Cocos-Nazca Rift at the Galapagos Triple Junction

NASA Astrophysics Data System (ADS)

Smith, D. K.; Montesi, L. G.; Schouten, H.; Zhu, W.

2011-12-01

A succession of short-lived, E-W trending cracks at the Galapagos Triple Junction north and south of the Cocos-Nazca (C-N) Rift, has been explained by a simple crack interaction model. The locations of where the cracks initiate are controlled by tensile stresses generated at the East Pacific Rise (EPR) by two interacting cracks: One representing the north-south trending EPR, and the other the large, westward propagating C-N Rift, whose tip is separated from the EPR by a distance D. The model predicts symmetric cracking at the EPR north and south of the C-N Rift tip. Symmetry in the distribution of cracks north and south of the C-N Rift is observed and especially remarkable between 2.5 and 1.5 Ma when the rapid jumping of cracks toward the C-N Rift appears synchronous. The rapid jumping can be explained by decreasing D, which means that the tip of the C-N Rift was moving closer to the EPR. Symmetry of cracking breaks down at 1.5 Ma, however, with the establishment of the Dietz Deep Rift, the southern boundary of the Galapagos microplate. Symmetry of cracking also breaks down on older crust to the east between about 100 35'W and 100 45'W (about 2.6 Ma) where a rapid jumping of cracks toward the C-N Rift is observed in the south cracking region. There is no evidence of similar rapid jumping in the north cracking region. It could be simply that the response to changing the value of D is not always as predicted. It could also be that the shape of the EPR has not always been symmetric about the C-N Rift, as assumed in the model. Currently, an overlapping spreading center with a 15 km east-west offset between the limbs of the EPR has formed at 1 50'N. We assess the importance of the geometry of the EPR on the crack interaction model. The model has been modified to include a ridge offset similar to what is observed today. We find that the region of stress enhancement at the EPR (where cracks initiate) is subdued south of the C-N Rift tip because of the EPR offset. It is

Effect of Fluoride on the Morphology and Electrochemical Property of Co3O4 Nanostructures for Hydrazine Detection

PubMed Central

Gao, Wanlin; Wang, Qiang; Umar, Ahmad

2018-01-01

In this paper, we systematically investigated the influence of fluoride on the morphology and electrochemical property of Co3O4 nanostructures for hydrazine detection. The results showed that with the introduction of NH4F during the synthesis process of Co3O4, both Co(CO3)0.5(OH)·0.11H2O and Co(OH)F precursors would be generated. To understand the influence of F on the morphology and electrochemical property of Co3O4, three Co3O4 nanostructures that were respectively obtained from bare Co(CO3)0.5(OH)·0.11H2O, Co(OH)F and Co(CO3)0.5(OH)·0.11H2O mixtures and bare Co(OH)F were successfully synthesized. The electrochemical tests revealed the sensing performance of prepared Co3O4 nanostructures decreased with the increase in the fluoride contents of precursors. The more that dosages of NH4F were used, the higher crystallinity and smaller specific surface area of Co3O4 was gained. Among these three Co3O4 nanostructures, the Co3O4 that was obtained from bare Co(CO3)0.5(OH)·0.11H2O-based hydrazine sensor displayed the best performances, which exhibited a great sensitivity (32.42 μA·mM−1), a low detection limit (9.7 μΜ), and a wide linear range (0.010–2.380 mM), together with good selectivity, great reproducibility and longtime stability. To the best of our knowledge, it was revealed for the first time that the sensing performance of prepared Co3O4 nanostructures decreased with the increase in fluoride contents of precursors. PMID:29382161

Annealing-Based Electrical Tuning of Cobalt-Carbon Deposits Grown by Focused-Electron-Beam-Induced Deposition.

PubMed

Puydinger Dos Santos, Marcos V; Velo, Murilo F; Domingos, Renan D; Zhang, Yucheng; Maeder, Xavier; Guerra-Nuñez, Carlos; Best, James P; Béron, Fanny; Pirota, Kleber R; Moshkalev, Stanislav; Diniz, José A; Utke, Ivo

2016-11-30

An effective postgrowth electrical tuning, via an oxygen releasing method, to enhance the content of non-noble metals in deposits directly written with gas-assisted focused-electron-beam-induced deposition (FEBID) is presented. It represents a novel and reproducible method for improving the electrical transport properties of Co-C deposits. The metal content and electrical properties of Co-C-O nanodeposits obtained by electron-induced dissociation of volatile Co 2 (CO) 8 precursor adsorbate molecules were reproducibly tuned by applying postgrowth annealing processes at 100 °C, 200 °C, and 300 °C under high-vacuum for 10 min. Advanced thin film EDX analysis showed that during the annealing process predominantly oxygen is released from the Co-C-O deposits, yielding an atomic ratio of Co:C:O = 100:16:1 (85:14:1) with respect to the atomic composition of as-written Co:C:O = 100:21:28 (67:14:19). In-depth Raman analysis suggests that the amorphous carbon contained in the as-written deposit turns into graphite nanocrystals with size of about 22.4 nm with annealing temperature. Remarkably, these microstructural changes allow for tuning of the electrical resistivity of the deposits over 3 orders of magnitude from 26 mΩ cm down to 26 μΩ cm, achieving a residual resistivity of ρ 2K /ρ 300 K = 0.56, close to the value of 0.53 for pure Co films with similar dimensions, making it especially interesting and advantageous over the numerous works already published for applications such as advanced scanning-probe systems, magnetic memory, storage, and ferroelectric tunnel junction memristors, as the graphitic matrix protects the cobalt from being oxidized under an ambient atmosphere.

Electron-temperature dependence of dissociative recombination of electrons with CO/+/./CO/n-series ions

NASA Technical Reports Server (NTRS)

Whitaker, M.; Biondi, M. A.; Johnsen, R.

1981-01-01

The dependence on electron temperature of the coefficients for electron recombination with molecular cluster ions of the carbon monoxide series, CO(+).(CO)n, is determined. A microwave discharge lasting approximately 0.1 msec was applied in 5-20 Torr neon containing a few tenths percent CO in an afterglow mass spectrometer apparatus, and the time histories of the various afterglow ions were measured. Expressions for the dependence of the recombination coefficients of the dimer and trimer ions CO(+).CO and CO(+).(CO)2 are obtained which are found to be significantly different from those previously obtained for hydronium and ammonium series polar cluster ions, but similar to those of simple diatomic ions.

Green synthesis, spectroscopic investigation and photocatalytic activity of lead nanoparticles

NASA Astrophysics Data System (ADS)

Elango, Ganesh; Roopan, Selvaraj Mohana

2015-03-01

Most of researcher focused their research towards synthesize of nanoparticles by the method of applied chemical method which was one of the costliest method. We have focused cheapest and simplest method for the synthesizing of lead nanoparticles (Pb-NPs) using cocos nucifera L extract. The methanolic extract of cocos nucifera L was efficiently used as a reducing agent for synthesizing Pb-NPs. On treatment of lead acetate with cocos nucifera coir extracts, stable Pb-NPs were formed. The synthesized Pb-NPs were further confirmed by UV-visible spectroscopy, X-ray diffraction (XRD), Transmission electron microscope (TEM) and Energy Dispersive (EDAX) analysis. The secondary metabolites present in methanolic extract which can mainly act as a reducing and capping agents for the formation of Pb-NPs were identified by GC-MS. Anti-microbial activity for Pb-NPs against four pathogenic strain's such as Staphylococcus aureus, Escheria coli, Staphylococcus epidermis and Bacillus subtilis. Result states that Pb-NPs size was 47 nm and also shows good activity against S. aureus. Further we report on photocatalytic absorption of malachite green dye processed in short UV wavelength at 254 nm. UV spectral analysis showed peak absorbance at 613 nm with special reference to the excitation of surfaces plasmon vibration by Pb-NPs.

P-Wave Velocity Tomography from Local Earthquakes in Western Mexico

NASA Astrophysics Data System (ADS)

Ochoa-Chávez, Juan A.; Escudero, Christian R.; Núñez-Cornú, Francisco J.; Bandy, William L.

2016-10-01

In western Mexico, the subduction of the Rivera and Cocos plates beneath the North America plate has deformed and fragmented the overriding plate, forming several structural rifts and crustal blocks. To obtain a reliable subsurface image of the continental crust and uppermost mantle in this complex area, we used P-wave arrivals of local earthquakes along with the Fast Marching Method tomography technique. We followed an inversion scheme consisting of (1) the use of a high-quality earthquake catalog and corrected phase picks, (2) the selection of earthquakes using a maximum location error threshold, (3) the estimation of an improved 1-D reference velocity model, and (4) the use of checkerboard testing to determine the optimum configuration of the velocity nodes and inversion parameters. Surprisingly, the tomography results show a very simple δVp distribution that can be described as being controlled by geologic structures formed during two stages of the separation of the Rivera and Cocos plates. The earlier period represents the initial stages of the separation of the Rivera and Cocos plates beneath western Mexico; the later period represents the more advanced stage of rifting where the Rivera and Cocos plates had separated sufficiently to allow melt to accumulate below the Colima Volcanic complex. During the earlier period (14 or 10-1.6 Ma), NE-SW-oriented structures/lineaments (such as the Southern Colima Rift) were formed as the two plates separated. During the second period (1.6 Ma to the present), the deformation is attributed to magma, generated within and above the tear zone between the Rivera and Cocos plates, rising beneath the region of the Colima Volcanic Complex. The rising magma fractured the overlying crust, forming a classic triple-rift junction geometry. This triple-rift system is confined to the mid- to lower crust perhaps indicating that this rifting process is still in an early stage. This fracturing, along with fluid circulation and associated

Characterization and Ectopic Expression of CoWRI1, an AP2/EREBP Domain-Containing Transcription Factor from Coconut (Cocos nucifera L.) Endosperm, Changes the Seeds Oil Content in Transgenic Arabidopsis thaliana and Rice (Oryza sativa L.)

PubMed Central

Sun, RuHao; Ye, Rongjian; Gao, Lingchao; Zhang, Lin; Wang, Rui; Mao, Ting; Zheng, Yusheng; Li, Dongdong; Lin, Yongjun

2017-01-01

Coconut (Cocos nucifera L.) is a key tropical crop and a member of the monocotyledonous family Arecaceae (Palmaceae). Few genes and related metabolic processes involved in coconut endosperm development have been investigated. In this study, a new member of the WRI1 gene family was isolated from coconut endosperm and was named CoWRI1. Its transcriptional activities and interactions with the acetyl-CoA carboxylase (BCCP2) promoter of CoWRI1 were confirmed by the yeast two-hybrid and yeast one-hybrid approaches, respectively. Functional characterization was carried out through seed-specific expression in Arabidopsis and endosperm-specific expression in rice. In transgenic Arabidopsis, high over-expressions of CoWRI1 in seven independent T2 lines were detected by quantitative real-time PCR. The relative mRNA accumulation of genes encoding enzymes involved in either fatty acid biosynthesis or triacylglycerols assembly (BCCP2, KASI, MAT, ENR, FATA, and GPDH) were also assayed in mature seeds. Furthermore, lipid and fatty acids C16:0 and C18:0 significantly increased. In two homozygous T2 transgenic rice lines (G5 and G2), different CoWRI1 expression levels were detected, but no CoWRI1 transcripts were detected in the wild type. Analyses of the seed oil content, starch content, and total protein content indicated that the two T2 transgenic lines showed a significant increase (P < 0.05) in seed oil content. The transgenic lines also showed a significant increase in starch content, whereas total protein content decreased significantly. Further analysis of the fatty acid composition revealed that palmitic acid (C16:0) and linolenic acid (C18:3) increased significantly in the seeds of the transgenic rice lines, but oleic acid (C18:1) levels significantly declined. PMID:28179911

Characterization and Ectopic Expression of CoWRI1, an AP2/EREBP Domain-Containing Transcription Factor from Coconut (Cocos nucifera L.) Endosperm, Changes the Seeds Oil Content in Transgenic Arabidopsis thaliana and Rice (Oryza sativa L.).

PubMed

Sun, RuHao; Ye, Rongjian; Gao, Lingchao; Zhang, Lin; Wang, Rui; Mao, Ting; Zheng, Yusheng; Li, Dongdong; Lin, Yongjun

2017-01-01

Coconut ( Cocos nucifera L.) is a key tropical crop and a member of the monocotyledonous family Arecaceae ( Palmaceae ). Few genes and related metabolic processes involved in coconut endosperm development have been investigated. In this study, a new member of the WRI1 gene family was isolated from coconut endosperm and was named CoWRI1 . Its transcriptional activities and interactions with the acetyl-CoA carboxylase ( BCCP2 ) promoter of CoWRI1 were confirmed by the yeast two-hybrid and yeast one-hybrid approaches, respectively. Functional characterization was carried out through seed-specific expression in Arabidopsis and endosperm-specific expression in rice. In transgenic Arabidopsis , high over-expressions of CoWRI1 in seven independent T2 lines were detected by quantitative real-time PCR. The relative mRNA accumulation of genes encoding enzymes involved in either fatty acid biosynthesis or triacylglycerols assembly (BCCP2, KASI, MAT, ENR, FATA, and GPDH) were also assayed in mature seeds. Furthermore, lipid and fatty acids C16:0 and C18:0 significantly increased. In two homozygous T2 transgenic rice lines (G5 and G2), different CoWRI1 expression levels were detected, but no CoWRI1 transcripts were detected in the wild type. Analyses of the seed oil content, starch content, and total protein content indicated that the two T2 transgenic lines showed a significant increase ( P < 0.05) in seed oil content. The transgenic lines also showed a significant increase in starch content, whereas total protein content decreased significantly. Further analysis of the fatty acid composition revealed that palmitic acid (C16:0) and linolenic acid (C18:3) increased significantly in the seeds of the transgenic rice lines, but oleic acid (C18:1) levels significantly declined.

Airblast Attenuation in Entranceways and other Typical Components of Structures. Small-Scale Tests Data Report 1

DTIC Science & Technology

1984-12-01

CD <^P CO CD CO CO *^D CO CO *S) ^0 ^0 CO CO ^0 ^D r». cocococn^^-cvicncororo OJCO CMtocM«-« M> i —~«CD rococo co<~ coco...I ro rowtoto r».»* coco CM co ro CM rococo GO r^ voco co i a»v coCM<**•co<r>-« i * -•-« i...J 1 1 1 1 1 1 ! 1 1 t • • • rococo CVI**« •* iv.rw^ojrs.oMoooro-«<»eo CVJ CM «-• *-**■<«■* <M v* «■*«*«* CM I I • ••••«••••••I I

7 CFR 319.37-3 - Permits.

Code of Federal Regulations, 2013 CFR

2013-01-01

.... (gladiolus), and Watsonia spp. (bugle lily) from New Zealand; (4) Articles of Cocos nucifera (coconut); and... Massachusetts, New York, West Virginia, or Wisconsin; (11) Articles (except seeds) of Planera spp. (water elm...

7 CFR 319.37-3 - Permits.

Code of Federal Regulations, 2012 CFR

2012-01-01

.... (gladiolus), and Watsonia spp. (bugle lily) from New Zealand; (4) Articles of Cocos nucifera (coconut); and... Massachusetts, New York, West Virginia, or Wisconsin; (11) Articles (except seeds) of Planera spp. (water elm...

The interaction between stratospheric monthly mean regional winds and sporadic-E

NASA Astrophysics Data System (ADS)

Çetin, Kenan; Özcan, Osman; Korlaelçi, Serhat

2017-03-01

In the present study, a statistical investigation is carried out to explore whether there is a relationship between the critical frequency (foEs) of the sporadic-E layer that is occasionally seen on the E region of the ionosphere and the quasi-biennial oscillation (QBO) that flows in the east-west direction in the equatorial stratosphere. Multiple regression model as a statistical tool was used to determine the relationship between variables. In this model, the stationarity of the variables (foEs and QBO) was firstly analyzed for each station (Cocos Island, Gibilmanna, Niue Island, and Tahiti). Then, a co-integration test was made to determine the existence of a long-term relationship between QBO and foEs. After verifying the presence of a long-term relationship between the variables, the magnitude of the relationship between variables was further determined using the multiple regression model. As a result, it is concluded that the variations in foEs were explainable with QBO measured at 10 hPa altitude at the rate of 69%, 94%, 79%, and 58% for Cocos Island, Gibilmanna, Niue Island, and Tahiti stations, respectively. It is observed that the variations in foEs were explainable with QBO measured at 70 hPa altitude at the rate of 66%, 69%, 53%, and 47% for Cocos Island, Gibilmanna, Niue Island, and Tahiti stations, respectively.

Classical Optimal Control for Energy Minimization Based On Diffeomorphic Modulation under Observable-Response-Preserving Homotopy.

PubMed

Soley, Micheline B; Markmann, Andreas; Batista, Victor S

2018-06-12

We introduce the so-called "Classical Optimal Control Optimization" (COCO) method for global energy minimization based on the implementation of the diffeomorphic modulation under observable-response-preserving homotopy (DMORPH) gradient algorithm. A probe particle with time-dependent mass m( t;β) and dipole μ( r, t;β) is evolved classically on the potential energy surface V( r) coupled to an electric field E( t;β), as described by the time-dependent density of states represented on a grid, or otherwise as a linear combination of Gaussians generated by the k-means clustering algorithm. Control parameters β defining m( t;β), μ( r, t;β), and E( t;β) are optimized by following the gradients of the energy with respect to β, adapting them to steer the particle toward the global minimum energy configuration. We find that the resulting COCO algorithm is capable of resolving near-degenerate states separated by large energy barriers and successfully locates the global minima of golf potentials on flat and rugged surfaces, previously explored for testing quantum annealing methodologies and the quantum optimal control optimization (QuOCO) method. Preliminary results show successful energy minimization of multidimensional Lennard-Jones clusters. Beyond the analysis of energy minimization in the specific model systems investigated, we anticipate COCO should be valuable for solving minimization problems in general, including optimization of parameters in applications to machine learning and molecular structure determination.

Green synthesis, spectroscopic investigation and photocatalytic activity of lead nanoparticles.

PubMed

Elango, Ganesh; Roopan, Selvaraj Mohana

2015-03-15

Most of researcher focused their research towards synthesize of nanoparticles by the method of applied chemical method which was one of the costliest method. We have focused cheapest and simplest method for the synthesizing of lead nanoparticles (Pb-NPs) using cocos nucifera L extract. The methanolic extract of cocos nucifera L was efficiently used as a reducing agent for synthesizing Pb-NPs. On treatment of lead acetate with cocos nucifera coir extracts, stable Pb-NPs were formed. The synthesized Pb-NPs were further confirmed by UV-visible spectroscopy, X-ray diffraction (XRD), Transmission electron microscope (TEM) and Energy Dispersive (EDAX) analysis. The secondary metabolites present in methanolic extract which can mainly act as a reducing and capping agents for the formation of Pb-NPs were identified by GC-MS. Anti-microbial activity for Pb-NPs against four pathogenic strain's such as Staphylococcus aureus, Escheria coli, Staphylococcus epidermis and Bacillus subtilis. Result states that Pb-NPs size was 47 nm and also shows good activity against S. aureus. Further we report on photocatalytic absorption of malachite green dye processed in short UV wavelength at 254 nm. UV spectral analysis showed peak absorbance at 613 nm with special reference to the excitation of surfaces plasmon vibration by Pb-NPs. Copyright © 2014 Elsevier B.V. All rights reserved.

Coconut (Cocos nucifera l.) pollen cryopreservation.

PubMed

Karun, A; Sjini, K K; Niral, V; Amarnth, C H; Remya, P; Rajesh, M K; Samsudeen, K; Jerard, B A; Engelmann, F

2014-01-01

Coconut genetic resources are threatened by pests and pathogens, natural hazards and human activities. Cryopreservation is the only method allowing the safe and cost-effective long-term conservation of recalcitrant seed species such as coconut. The objective of this work was to test the effect of cryopreservation and of cryostorage duration on coconut pollen germination and fertility. Pollen of two coconut varieties (West Coast Tall WWCTW and Chowghat Orange Dwarf CODC) was collected in March-May over three successive years, desiccated to 7.5 % moisture content (FW) and cryopreserved by direct immersion in liquid nitrogen. Germination and pollen tube length (PTL) of desiccated and cryopreserved pollen were not significantly different for both WCT and COD over the three harvest months of the three consecutive years of study. Pollen germination ranged from 24 to 32 % in desiccated pollen whereas it was between 26 and 29 % in cryopreserved COD pollen. In the case of WCT, germination ranged from 30 to 31 % in desiccated pollen, while it was between 28 and 32 % in cryopreserved pollen. PTL of cryopreserved pollen ranged between 224-390 nm and 226-396 mm for COD and WCT, respectively. Germination of COD pollen varied between 29.0 and 44.1 % after 4 years and 1.0/1.5 years cryostorage, respectively. Germination of WCT pollen did not change significantly between 0 and 6 years cryostorage, being comprised between 32 (24 h) and 40 % (1.5 years). Germination and vigour of cryopreserved pollen were generally higher compared to that of pollen dried in oven and non-cryopreserved. Normal seed set was observed in COD and WCT palms using pollen cryostored for 6 months and 4 years. Cryopreserved pollen of five Tall and five Dwarf accessions displayed 24-31 % and 25-49 % germination, respectively. These results show that it is now possible to establish pollen cryobanks to contribute to coconut germplasm long-term conservation.

Phylogenetic Analysis of Seven WRKY Genes across the Palm Subtribe Attaleinae (Arecaceae) Identifies Syagrus as Sister Group of the Coconut

PubMed Central

Meerow, Alan W.; Noblick, Larry; Borrone, James W.; Couvreur, Thomas L. P.; Mauro-Herrera, Margarita; Hahn, William J.; Kuhn, David N.; Nakamura, Kyoko; Oleas, Nora H.; Schnell, Raymond J.

2009-01-01

Background The Cocoseae is one of 13 tribes of Arecaceae subfam. Arecoideae, and contains a number of palms with significant economic importance, including the monotypic and pantropical Cocos nucifera L., the coconut, the origins of which have been one of the “abominable mysteries” of palm systematics for decades. Previous studies with predominantly plastid genes weakly supported American ancestry for the coconut but ambiguous sister relationships. In this paper, we use multiple single copy nuclear loci to address the phylogeny of the Cocoseae subtribe Attaleinae, and resolve the closest extant relative of the coconut. Methodology/Principal Findings We present the results of combined analysis of DNA sequences of seven WRKY transcription factor loci across 72 samples of Arecaceae tribe Cocoseae subtribe Attaleinae, representing all genera classified within the subtribe, and three outgroup taxa with maximum parsimony, maximum likelihood, and Bayesian approaches, producing highly congruent and well-resolved trees that robustly identify the genus Syagrus as sister to Cocos and resolve novel and well-supported relationships among the other genera of the Attaleinae. We also address incongruence among the gene trees with gene tree reconciliation analysis, and assign estimated ages to the nodes of our tree. Conclusions/Significance This study represents the as yet most extensive phylogenetic analyses of Cocoseae subtribe Attaleinae. We present a well-resolved and supported phylogeny of the subtribe that robustly indicates a sister relationship between Cocos and Syagrus. This is not only of biogeographic interest, but will also open fruitful avenues of inquiry regarding evolution of functional genes useful for crop improvement. Establishment of two major clades of American Attaleinae occurred in the Oligocene (ca. 37 MYBP) in Eastern Brazil. The divergence of Cocos from Syagrus is estimated at 35 MYBP. The biogeographic and morphological congruence that we see for

Clostridium scatologenes strain SL1 isolated as an acetogenic bacterium from acidic sediments.

PubMed

Küsel, K; Dorsch, T; Acker, G; Stackebrandt, E; Drake, H L

2000-03-01

A strictly anaerobic, H2-utilizing bacterium, strain SL1, was isolated from the sediment of an acidic coal mine pond. Cells of strain SL1 were sporulating, motile, long rods with a multilayer cell wall. Growth was observed at 5-35 degrees C and pH 3.9-7.0. Acetate was the sole end product of H2 utilization and was produced in stoichiometries indicative of an acetyl-CoA-pathway-dependent metabolism. Growth and substrate utilization also occurred with CO/CO2, vanillate, syringate, ferulate, ethanol, propanol, 1-butanol, glycerine, cellobiose, glucose, fructose, mannose, xylose, formate, lactate, pyruvate and gluconate. With most substrates, acetate was the main or sole product formed. Growth in the presence of H2/CO2 or CO/CO2 was difficult to maintain in laboratory cultures. Methoxyl, carboxyl and acrylate groups of various aromatic compounds were O-demethylated, decarboxylated and reduced, respectively. Small amounts of butyrate were produced during the fermentation of sugars. The acrylate group of ferulate was reduced. Nitrate, sulfate, thiosulfate, dimethylsulfoxide and Fe(III) were not utilized as electron acceptors. Analysis of the 16S rRNA gene sequence of strain SL1 demonstrated that it is closely related to Clostridium scatologenes (99.6% sequence similarity), an organism characterized as a fermentative anaerobe but not previously shown to be capable of acetogenic growth. Comparative experiments with C. scatologenes DSM 757T demonstrated that it utilized H2/CO2 (negligible growth), CO/CO2 (negligible growth), formate, ethanol and aromatic compounds according to stoichiometries indicative of the acetyl-CoA pathway. CO dehydrogenase, formate dehydrogenase and hydrogenase activities were present in both strain SL1 and C. scatologenes DSM 757T. These results indicate that (i) sediments of acidic coal mine ponds harbour acetogens and (ii) C. scatologenes is an acetogen that tends to lose its capacity to grow acetogenically under H2/CO2 or CO/CO2 after prolonged

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Seismicity of the Earth 1900-2010 Mexico and vicinity

USGS Publications Warehouse

Rhea, Susan; Dart, Richard L.; Villaseñor, Antonio; Hayes, Gavin P.; Tarr, Arthur C.; Furlong, Kevin P.; Benz, Harley M.

2011-01-01

Mexico, located in one of the world's most seismically active regions, lies on three large tectonic plates: the North American plate, Pacific plate, and Cocos plate. The relative motion of these tectonic plates causes frequent earthquakes and active volcanism and mountain building. Mexico's most seismically active region is in southern Mexico where the Cocos plate is subducting northwestward beneath Mexico creating the deep Middle America trench. The Gulf of California, which extends from approximately the northern terminus of the Middle America trench to the U.S.-Mexico border, overlies the plate boundary between the Pacific and North American plates where the Pacific plate is moving northwestward relative to the North American plate. This region of transform faulting is the southern extension of the well-known San Andreas Fault system.

Interpenetrating Triphase Cobalt-Based Nanocomposites as Efficient Bifunctional Oxygen Electrocatalysts for Long-Lasting Rechargeable Zn–Air Batteries

DOE Office of Scientific and Technical Information (OSTI.GOV)

Jiang, Yi; Deng, Ya-Ping; Fu, Jing

Rational construction of atomic-scale interfaces in multiphase nanocomposites is an intriguing and challenging approach to developing advanced catalysts for both oxygen reduction (ORR) and evolution reactions (OER). In this paper, a hybrid of interpenetrating metallic Co and spinel Co 3O 4 “Janus” nanoparticles stitched in porous graphitized shells (Co/Co 3O 4@PGS) is synthesized via ionic exchange and redox between Co 2+ and 2D metal–organic-framework nanosheets. This strategy is proven to effectively establish highways for the transfer of electrons and reactants within the hybrid through interfacial engineering. Specifically, the phase interpenetration of mixed Co species and encapsulating porous graphitized shells providesmore » an optimal charge/mass transport environment. Furthermore, the defect-rich interfaces act as atomic-traps to achieve exceptional adsorption capability for oxygen reactants. Finally, robust coupling between Co and N through intimate covalent bonds prohibits the detachment of nanoparticles. As a result, Co/Co 3O 4@PGS outperforms state-of-the-art noble-metal catalysts with a positive half-wave potential of 0.89 V for ORR and a low potential of 1.58 V at 10 mA cm -2 for OER. Finally, in a practical demonstration, ultrastable cyclability with a record lifetime of over 800 h at 10 mA cm -2 is achieved by Zn–air batteries with Co/Co 3O 4@PGS within the rechargeable air electrode.« less

Indo-Pacific echinoids in the tropical eastern Pacific

NASA Astrophysics Data System (ADS)

Lessios, H. A.; Kessing, B. D.; Wellington, G. M.; Graybeal, A.

1996-06-01

The existing literature reports that only one species of Indo-Pacific echinoid ( Echinometra oblonga), occurs in the eastern Pacific. In this study we confirm the presence of this species at Islas Revillagigedo and also report the presence of two species of Echinothrix (a genus hitherto unknown outside the Indo-Pacific) at Isla del Coco and at Clipperton Island. We also present evidence from isozymes and from mitochondrial DNA sequences indicating that at least one individual of Diadema at Clipperton may belong to a maternal lineage characteristic of the west Pacific species D. savignyi. These data are consistent with the hypothesis that the observed populations of Indo-Pacific echinoid species are recent arrivals to the eastern Pacific, as opposed to the view that they are relicts of Tethyan pan-tropical distributions. Echinothrix diadema, in particular, may have arrived at Isla del Coco during the 1982-1983 El Nifio. In addition to Indo-Pacific species, Clipperton, Isla del Coco and the Revillagigedos contain a complement of eastern Pacific echinoids. The echinoid faunas of these islands should, therefore, be regarded as mixtures of two biogeographic provinces. Though none of the Indo-Pacific species are known to have reached the coast of the American mainland, their presence at the offshore islands of the eastern Pacific suggests that, for some echinoids, the East Pacific Barrier is not as formidable an obstacle to migration as was previously thought.

Interpenetrating Triphase Cobalt-Based Nanocomposites as Efficient Bifunctional Oxygen Electrocatalysts for Long-Lasting Rechargeable Zn–Air Batteries

DOE PAGES

Jiang, Yi; Deng, Ya-Ping; Fu, Jing; ...

2018-01-31

Rational construction of atomic-scale interfaces in multiphase nanocomposites is an intriguing and challenging approach to developing advanced catalysts for both oxygen reduction (ORR) and evolution reactions (OER). In this paper, a hybrid of interpenetrating metallic Co and spinel Co 3O 4 “Janus” nanoparticles stitched in porous graphitized shells (Co/Co 3O 4@PGS) is synthesized via ionic exchange and redox between Co 2+ and 2D metal–organic-framework nanosheets. This strategy is proven to effectively establish highways for the transfer of electrons and reactants within the hybrid through interfacial engineering. Specifically, the phase interpenetration of mixed Co species and encapsulating porous graphitized shells providesmore » an optimal charge/mass transport environment. Furthermore, the defect-rich interfaces act as atomic-traps to achieve exceptional adsorption capability for oxygen reactants. Finally, robust coupling between Co and N through intimate covalent bonds prohibits the detachment of nanoparticles. As a result, Co/Co 3O 4@PGS outperforms state-of-the-art noble-metal catalysts with a positive half-wave potential of 0.89 V for ORR and a low potential of 1.58 V at 10 mA cm -2 for OER. Finally, in a practical demonstration, ultrastable cyclability with a record lifetime of over 800 h at 10 mA cm -2 is achieved by Zn–air batteries with Co/Co 3O 4@PGS within the rechargeable air electrode.« less

Formation of hydrothermal pits and the role of seamounts in the Guatemala Basin (Equatorial East Pacific) from heat flow, seismic, and core studies

NASA Astrophysics Data System (ADS)

Villinger, H. W.; Pichler, T.; Kaul, N.; Stephan, S.; Pälike, H.; Stephan, F.

2017-01-01

We acquired seismic and heat flow data and collected sediment cores in three areas in the Guatemala Basin (Cocos Plate, Eastern Pacific) to investigate the process by which depressions (pits) in the sedimentary cover on young oceanic crust were formed. Median heat flow of 55 mW/m2 for the three areas is about half of the expected conductive cooling value. The heat deficit is caused by massive recharge of cold seawater into the upper crust through seamounts which is inferred from depressed heat flow in the vicinity of seamounts. Heat flow inside of pits is always elevated, in some cases up to three times (max. 300 mW/m2) relative to background. None of the geochemical pore water profiles from cores inside and outside of the pits show any evidence of active fluid flow inside the pits. All three areas originated within the high productivity equatorial zone and moved northwest over the past 15 to 18 Ma. Pits found in the working areas are likely relict dissolution structures formed by diffuse hydrothermal venting in a zone of high biogenic carbonate production which were sealed when they moved north. It is likely that these pits were discharge sites of "hydrothermal siphons" where recharging seamounts could feed cold seawater via the upper crust to several discharging pits. Probably pit density on the whole Cocos Plate is similar to the three working areas and which may explain the huge heat deficit of the Cocos Plate.

Biochemical and immunological studies on eight pollen types from South Assam, India.

PubMed

Sharma, Dhruba; Dutta, B K; Singh, A B

2009-12-01

A total of 65 pollen types were identified from two years atmospheric pollen survey in the environmental conditions of South Assam. Out of them, eight pollen types viz., Acacia auriculiformis, Amaranthus spinosus, Cassia alata, Cleome gynandra, Cocos nucifera, Imperata cylindrica, Ricinus communis and Trewia nudiflora, were selected for biochemical studies on the basis of their dominance in the study sites. Among the sample extract tested, Ricinus communis was found to contain the highest amount of soluble protein, free amino acid and total carbohydrate, per gram of dry weight followed by Imperata cylindrica and Cassia alata. Maximum numbers of protein polypeptide bands were detected in the sample extract of Cassia alata by polyacrylamide gel electrophoresis method followed by Acacia auriculiformis, Imperata cylindrica and Cocos nucifera. IgE binding protein fractions were maximum in Cassia alata and minimum in Trewia nudiflora.

Coconut, date and oil palm genomics

USDA-ARS?s Scientific Manuscript database

A review of genomics research is presented for the three most economically important palm crops, coconut (Cocos nucifera), date palm (Phoenix dactylifera) and oil palm (Elaeis guineensis), encompassing molecular markers studies of genetic diversity, genetic mapping, quantitative trait loci discovery...

A Cultural Resources Reconnaissance of the Susupe-Chalan-Kanoa Flood Control Study Area, Saipan, Mariana Islands,

DTIC Science & Technology

1980-03-01

of coconut palms (Cocos nuciferza), breadfruit (Artocarpue incisus ), papaya (Carica papaya ) , banana (Msa sp.) * ( .. . . . .. *’ I. . l r l[. . . . i...interconnecting ones are generally composed of limestone gravel. Flametrees ( DeZonix regia ) are common along thorough-fares and bananas, papayas

Galapagos Tectonics and Evolution (Invited)

NASA Astrophysics Data System (ADS)

Hey, R. N.

2010-12-01

Galapagos is now considered one of the type-examples of hotspot-ridge interaction, although in the early years of plate tectonics it was generally thought that this interpretation was demonstrably wrong, with two influential groups insisting that non-hotspot models were required for this area. The key to understanding Galapagos tectonic evolution was the recognition that small ridge axis jumps toward the hotspot had occurred, producing complicated magnetic anomalies and asymmetric lithospheric accretion. My dissertation work, guided by Jason Morgan, showed that this simple modification to plate tectonic theory could resolve the seemingly compelling geometric arguments against the Cocos and Carnegie aseismic ridges being Galapagos hotspot tracks, and further that if Galapagos were a hotspot near Fernandina, fixed with respect to the Hawaii hotspot, there should be aseismic ridges on the Cocos and Nazca plates with the observed Cocos and Carnegie ridge geometry, both aseismic ridges forming when the hotspot was ridge-centered, but only the Carnegie ridge since the plate boundary migrated north of the hotspot. A great deal of subsequent research has shown that some areas are considerably more complicated than originally thought, but the following basic model still appears to hold. The Farallon plate split apart along the Grijalva scarp, possibly a preexisting Pacific-Farallon FZ that intersected the hotspot at this time (although alternative interpretations exist), probably in response to tensional stress caused by slab pull in different directions at the Mid-America and Peru-Chile trenches. This break-up allowed more orthogonal subduction of independent Cocos and Nazca plates beginning shortly after 25 Ma. The original Cocos-Nazca ridge trended E-NE, but soon reorganized into N-S spreading segments. The subsequent evolution involved substantial northward ridge migration and ridge jumps, mostly toward the Galapagos hotspot. Recent ridge jumps have occurred in

Is the Central America forearc sliver part of the North America plate?

NASA Astrophysics Data System (ADS)

Guzman-Speziale, M.

2012-04-01

The Central America Forearc sliver is located between the Central America volcanic arc and the Middle America trench. Several authors have suggested that the forearc is being displaced to the northwest with respect to the Caribbean plate; they point to right-lateral, normal-faulting earthquakes along the Central America volcanic arc as prime evidence of this displacement. Apparently, the forearc continues to the northwest into southeastern Mexico, although this portion of the forearc is not being displaced. I present evidence that suggests that the forearc indeed continues into southeastern Mexico and that it belongs to the North America plate. Physiographically, there is a continuity of the forearc into the Coastal plains of southeastern (Chiapas) Mexico, across the Motagua and Polochic faults. Offshore, cross-sections of the Middle America trench are similar along the mexican (Chiapas) segment, and the Central American segment. Furthermore, at the northwestern end of the coastal plain there are no compressive structures, which suggests that the coastal plain is not being displaced to the northwest. As a matter of fact, fault-plane solutions for shallow earthquakes show extension rather than compression. Shallow, interplate earthquakes along the trench show similar parameters along both segments. P-axes and earthquake slip vectors have consistent azimuths, which relate better with Cocos-North America convergence than with Cocos-Caribbean. Azimuth of T-axes for normal-faulting earthquakes also agree well with Cocos-North America convergence. Similarity in several parameters is thus found across both segments, the Chiapas coastal plain and the Central America forearc sliver proper. This suggests that both segments are continuous and probably one and the same, and belonging to the North America plate. Perhaps more properly, the forearc sliver extends into southeastern Mexico and is part of the zone of deformation associated to the Cocos-North America-Caribbean plates

Effect of coconut palm proximities and Musa spp. germplasm resistance to colonization by Raoiella indica (Acari: Tenuipalpidae)

USDA-ARS?s Scientific Manuscript database

Although coconut (Cocos nucifera L.) is the predominant host for Raoiella indica Hirst (Acari: Tenuipalpidae), false spider mite infestations do occur on bananas and plantains (Musa spp. Colla). Since its introduction, the banana and plantain industries have been negatively impacted to different deg...

Comparison of eastern tropical Pacific TEX86 and Globigerinoides ruber Mg/Ca derived sea surface temperatures: Insights from the Holocene and Last Glacial Maximum

NASA Astrophysics Data System (ADS)

Hertzberg, Jennifer E.; Schmidt, Matthew W.; Bianchi, Thomas S.; Smith, Richard W.; Shields, Michael R.; Marcantonio, Franco

2016-01-01

The use of the TEX86 temperature proxy has thus far come to differing results as to whether TEX86 temperatures are representative of surface or subsurface conditions. In addition, although TEX86 temperatures might reflect sea surface temperatures based on core-top (Holocene) values, this relationship might not hold further back in time. Here, we investigate the TEX86 temperature proxy by comparing TEX86 temperatures to Mg/Ca temperatures of multiple species of planktonic foraminifera for two sites in the eastern tropical Pacific (on the Cocos and Carnegie Ridges) across the Holocene and Last Glacial Maximum. Core-top and Holocene TEX86H temperatures at both study regions agree well, within error, with the Mg/Ca temperatures of Globigerinoides ruber, a surface dwelling planktonic foraminifera. However, during the Last Glacial Maximum, TEX86H temperatures are more representative of upper thermocline temperatures, and are offset from G. ruber Mg/Ca temperatures by 5.8 °C and 2.9 °C on the Cocos Ridge and Carnegie Ridge, respectively. This offset between proxies cannot be reconciled by using different TEX86 temperature calibrations, and instead, we suggest that the offset is due to a deeper export depth of GDGTs at the LGM. We also compare the degree of glacial cooling at both sites based on both temperature proxies, and find that TEX86H temperatures greatly overestimate glacial cooling, especially on the Cocos Ridge. This study has important implications for applying the TEX86 paleothermometer in the eastern tropical Pacific.

Photoelectron spectra of carbonyls. Propellenes and propellanones

DOE Office of Scientific and Technical Information (OSTI.GOV)

Dougherty, D.; Bloomfield, J.J.; Newkome, G.R.

1976-09-23

The HeI photoelectron spectra (UPS) of a number of unsaturated (4.4.2)propellanes and (4.4.2)propellane-dione derivatives are presented. The interpretation of the UPS data is based on through-space and through-bond interaction models and on CNDO/s computations. An analysis of the photoelectron spectra of (4.4.2)propella-3,8-diene-11,12-dione (1), (4.4.2)propell-3-ene-11,12-dione (2), (4.4.2)propellane-11,12-dione (3), (4.4.2)propella-3,8-dien-11-one (4), and (4.4.2) propella-3,8-diene (5) involves the assignment of n/sub +/, n/sub -/, ..pi../sub +/, ..pi../sub -/, and sigma/sub square/ (i.e., cyclobutane sigma) ionization events. The analysis of the data for 5, (4.4.2)propella-3,8,11-triene (6), (4.4.2)propella-3,11-diene (7), and (4.4.2)propell-11-ene (8) leads to the conclusion that the photoelectron spectrum of 6 should be reassigned.more » The /sup 1/GAMMA/sub n..pi..*/ reverse arrow /sup 1/GAMMA/sub 1/ absorption spectra of 1,2, and 3 have been investigated as a function of temperature. The low energy of this transition in 1 is attributed to a high degree of CO/CO coplanarity, the high energy of this transition in 3 is attributed to CO/CO noncoplanarity, and the isomerism evident in 2 is attributed to multiple minima of the potential energy along the CO/CO dihedral angle coordinate of the ground state.« less

Bacterial cellulose based hydrogel (BC-g-AA) and preliminary result of swelling behavior

DOE Office of Scientific and Technical Information (OSTI.GOV)

Hakam, Adil; Lazim, Azwan Mat; Abdul Rahman, I. Irman

2013-11-27

In this study, hydrogel based on Bacterial cellulose (BC) or local known as Nata de Coco, which grafted with monomer: Acrylic acid (AA) is synthesis by using gamma radiation technique. These hydrogel (BC-g-AA) has unique characteristic whereby responsive to pH buffer solution.

Phylogenetic analysis of six WRKY transcription factor loci across the spiny cocosoid palm subtribes Bactridinae and Elaeidinae (Areceaceae, Cocoseae),and comparison of several gene tree/species tree reconciliation approaches

USDA-ARS?s Scientific Manuscript database

The Cocoseae is one of 13 tribes of Arecaceae subfamily Arecoideae, and contains a number of palms with significant economic importance, including the monotypic and pantropical Cocos nucifera, the coconut, and African oil palm (Elaeis guineensis). Using seven single copy WRKY transcription factor g...

Phylogenetic analysis of seven WRKY genes across the palm subtribe Attaleinae (Areceaceae) identifies Syagrus as sister to the coconut

USDA-ARS?s Scientific Manuscript database

The origins of the coconut (Cocos nucifera) have been one of the "abominable mysteries" of palm systematics for decades. Previous studies with predominantly plastid genes have indicated an American ancestry for the coconut but with weak support and ambiguous sister relationships. We used primers d...

Evolutionary history of Arecaccea tribe Cocoseae inferred from seven WRKY transcription factors

USDA-ARS?s Scientific Manuscript database

The Cocoseae is one of 13 tribes of Arecaceae subfam. Arecoideae, and contains a number of palms with significant economic importance, including the monotypic and pantropical Cocos nucifera, the coconut, and African oil palm (Elaeis guineensis). Using seven single copy WRKY transcription factor gen...

Coconut leaf bioactivity toward generalist maize insect pests

USDA-ARS?s Scientific Manuscript database

Tropical plants are often more resistant to insects than temperate plants due to evolution of robust defenses to cope with a more constant insect threat. Coconut (Cocos nucifera L.) has very few chewing leaf feeding insect pests and was tested against two omnivorous leaf feeding caterpillar species,...

Biodiversity, bioaccumulation and physiological changes in lichens growing in the vicinity of coal-based thermal power plant of Raebareli district, north India.

PubMed

Bajpai, Rajesh; Upreti, Dalip K; Nayaka, S; Kumari, B

2010-02-15

The lichen diversity assessment carried out around a coal-based thermal power plant indicated the increase in lichen abundance with the increase in distance from power plant in general. The photosynthetic pigments, protein and heavy metals were estimated in Pyxine cocoes (Sw.) Nyl., a common lichen growing around thermal power plant for further inference. Distributions of heavy metals from power plant showed positive correlation with distance for all directions, however western direction has received better dispersion as indicated by the concentration coefficient-R(2). Least significant difference analysis showed that speed of wind and its direction plays a major role in dispersion of heavy metals. Accumulation of Al, Cr, Fe, Pb and Zn in the thallus suppressed the concentrations of pigments like chlorophyll a, chlorophyll b and total chlorophyll, however, enhanced the level of protein. Further, the concentrations of chlorophyll contents in P. cocoes increased with the decreasing the distance from the power plant, while protein, carotenoid and phaeophytisation exhibited significant decrease.

Monte Carlo Study of the Diffusion of CO Molecules inside Anthraquinone Hexagons on Cu(111)

NASA Astrophysics Data System (ADS)

Kim, Kwangmoo; Einstein, T. L.; Wyrick, Jon; Bartels, Ludwig

2010-03-01

Using Monte Carlo calculations of the two-di-men-sion-al (2D) lattice gas model, we study the diffusion of CO molecules inside anthraquinone (AQ) hexagons on a Cu(111) plane. We use experimentally-derived CO-CO interactionsfootnotetextK.L. Wong, , L. Bartels, J. Chem.Phys.123, 201102 (2005) and the analytic expression for the long-range surface-state- mediated interactionsfootnotetextK. Berland, TLE, and P. Hyldgaard, Phys.Rev. B 80, 155431 (2009) to describe the CO-AQ interactions. We assume that the CO-CO interactions are not affected by the presence of AQ's and that the CO-AQ interactions can be controlled by varying the intra-surface-state (ISS) reflectance r and the ISS phase shift δ of the indirect-electronic adsorbate-pair interactions. Comparing our results with experimental observations, we find that not only pair but also surface-state-mediated trio interactionsfootnotetextP. Hyldgaard and T.L. Einstein, EPL 59, 265 (2002) are needed to understand the data.

Waffle production: influence of batter ingredients on sticking of waffles at baking plates-Part II: effect of fat, leavening agent, and water.

PubMed

Huber, Regina; Schoenlechner, Regine

2017-05-01

Fresh egg waffles are continuously baked in tunnel baking ovens in industrial scale. Waffles that partly or fully stick to the baking plates cause significant product loss and increased costs. The aim of this study was, therefore, to investigate the effect of different recipe ingredients on the sticking behavior of waffles. In this second part, ingredients investigated were different leavening agents (sodium acid pyrophosphate, ammonium bicarbonate, magnesium hydroxide carbonate, or monocalcium phosphate), different fat sources (rapeseed oil, cocos fat, butter, or margarine), and different water sources (tap water 12°dH and distilled water). Within the different types of fats, solid fats with high amount of short-chain fatty acids (cocos fat or butter) decreased the number of sticking waffles compared to liquid oils (rapeseed oil). Regarding leavening agents, magnesium hydroxide carbonate and ammonium bicarbonate were superior to sodium acid pyrophosphate or monocalcium phosphate. Between the two water sources, effects were small.

The young sun, the early earth and the photochemistry of oxygen, ozone and formaldehyde in the early atmosphere

NASA Technical Reports Server (NTRS)

Canuto, V. M.; Levine, J. S.; Augustsson, T. R.; Imhoff, C. L.; Goldman, I.; Hubickyj, O.

1986-01-01

Recent work on the evolution of the solar nebula and the subsequent formation of planets is reviewed, and the stages of star formation thought to lead to a protosun and an accompanying solar nebula are considered. Photochemical results suggest that concentrations of O2, O3, and H2CO, and the ratio of CO/CO2 in the prebiological paleoatmosphere are very sensitive to atmospheric levels of H2O and CO2 and to the flux of incident solar ultraviolet. For enhanced levels of CO2 and solar UV, surface levels of O2 may have approached the parts per billion level in the prebiological paleoatmosphere. It is suggested that 10 percent or more of the enhanced H2CO production could have been rained out of the atmosphere into the early oceans where synthesis into more complex organic molecules could have taken place. CO/CO2 values of greater than unity could have been possible for enhanced levels of solar UV flux.

Integrating the Global War on Terrorism with the War on Drugs

DTIC Science & Technology

2007-03-01

illegal use of drugs is the slow destruction of the moral fiber of civilized society There is a clear and direct correlation between illicit drug...Their activities were largely funded by the taxes they levied on coco production, and today, they still use drug profits to finance their operations

76 FR 28967 - Columbia Gas Transmission, LLC; Notice of Application

Federal Register 2010, 2011, 2012, 2013, 2014

2011-05-19

... authority to continue to test and evaluate its Coco C storage field located in Kanawha County, West Virginia... field to develop further storage services, all as more fully set forth in the application which is on file with the Commission and open to public inspection. Any questions regarding this application should...

Physiological and ionic changes in dwarf coconut seedlings irrigated with saline water

USDA-ARS?s Scientific Manuscript database

The use of salt-tolerant plants is an important alternative to cope with the problem of salinity in semi-arid regions. The dwarf coconut palm (Cocos nucifera L.) has emerged as a salt-tolerant crop once established. However, little is known about the physiological mechanisms that may contribute to t...

REFERENCE AID: Glossary of Spanish and Portuguese Narcotics Terms

DTIC Science & Technology

1977-05-09

abrir la boca aceite aceituna aceitunas acelerado acelerador acido achiclar (acicalar) adepto adormidera aguantadero aguaje aguarras...andar volando anfeta ansioliticos antidepresivo apanar aparelio arboles de navidad armamento arpon arponeado arponero aspiradora aspirar...maceracion cocacola cocacolo cocazo cocinero coco coctel marihuana, hemp (IA) marihuana plant (IA) vein (Ar) capsules (IA) persons who carry

76 FR 40822 - Endangered and Threatened Wildlife and Plants; Endangered Status for the Largetooth Sawfish

Federal Register 2010, 2011, 2012, 2013, 2014

2011-07-12

... system (Manacapuru, Brazil), as well as in Lake Nicaragua and the San Juan River; the Rio Coco, on the... system. The San Juan River originates at Lake Nicaragua and runs along the Nicaragua-Costa Rica border... Colorado system (Burgess et al., 2009). Bussing (2002) indicated that this species was known to inhabit the...

Deletion of Smad4 attenuates the hepatic inflammation and fibrogenesis during nonalcoholic steatohepatitis progression.

PubMed

Qin, Geng; Wang, Guo Zhen; Guo, Dan Dan; Bai, Ru-Xue; Wang, Miao; Du, Shi Yu

2018-04-25

To explore the effects of Smad4 deletion on inflammation and fibrogenesis during nonalcoholic steatohepatitis (NASH) progression. We collected 56 liver tissues from NASH patients (NASH group) and 60 normal liver tissues from patients received liver resection for trauma (control group). Smad4 Co/Co mice and wild-type (WT) mice were used to construct NASH model by high-fat diet (HFD) or methionine- and choline-deficient (MCD) diet. Hematoxylin and eosin (HE) staining and Tunnel assay were performed to observe pathological changes and apoptosis of liver tissues, respectively, quantitative real-time polymerase chain reaction (qRT-PCR) to detect expressions of inflammatory, fibrogenesis and apoptosis-related genes, and immunohistochemistry to determine proteins expressions of Smad4, MCP-1 and α-SMA. Smad4 protein expression was significantly increased in NASH patients as compared with Control group. Besides, in terms of HFD- and MCD- fed mice, those in Smad4 Co/Co group showed reduction of hepatic steatosis, inflammatory, liver apoptosis and NAS scores, and presented a decrease in glucose, TG, FFAs, AST and ALT, a great up-regulation in adiponectin. Besides, as compared with the WT mice fed with HFD and MCD, Smad4 Co/Co decreased the expressions of inflammatory markers (TNF-α, MCP-1, IFN-γ), fibrogenesis markers (COL1A1, α-SMA and TGF-β1), lipogenic genes (SREBP1c, FAS and ACC) and proapoptotic genes (Bax and caspase 3) in liver tissues, but increased the expressions of β-oxidation genes (PPARα, CPT1 and ACO) and antiapoptotic gene Bcl-2. Smad4 deletion may inhibit lipogenesis, stimulateβ-oxidation, ameliorate lipid metabolism and liver function, alleviate inflammation, fibrosis, and reduce liver apoptosis during NASH. This article is protected by copyright. All rights reserved.

Consumption of high ω-3 fatty acid diet suppressed prostate tumorigenesis in C3(1) Tag mice.

PubMed

Akinsete, Juliana A; Ion, Gabriela; Witte, Theodore R; Hardman, W Elaine

2012-01-01

Prostate cancer incidence and mortality are high in the Western world and high ω-6/ω-3 PUFA in the Western diet may be a contributing factor. We investigated whether changing from a diet that approximates ω-6 fat content of the Western diet to a high ω-3 fat diet at adulthood might reduce prostate cancer risk. Female SV 129 mice that had consumed a high ω-6 diet containing corn oil for 2 weeks were bred with homozygous C3(1)Tag transgenic male mice. All male offspring were weaned to the corn oil diet (CO) until postpuberty when half of the male offspring were transferred to a high ω-3 diet containing canola oil and fish oil concentrate (FS). High ω-3 diet increased ω-3 and decreased ω-6 fat content of mice tissues. Average weights of prostate and genitourinary bloc were significantly lower in mice consuming high ω-3 diet at adulthood (CO-FS) than mice fed a lifetime high ω-6 diet (CO-CO). There was slower progression of tumorigenesis in dorsalateral prostate of CO-FS than in CO-CO mice. CO-FS mice had slightly lower plasma testosterone level at 24 and 40 weeks, significantly lower estradiol level at 40 weeks and significantly less expressed androgen receptor (AR) in the dorsalateral prostate at 40 weeks than CO-CO mice. Consumption of high ω-3 diet lowered the expression of genes expected to increase proliferation and decrease apoptosis in dorsalateral prostate. Our results suggest that consumption of high ω-3 diet slows down prostate tumorigenesis by lowering estradiol, testosterone and AR levels, promoting apoptosis and suppressing cell proliferation in C3(1)Tag mice.

Decay not serious in northern red oak

Treesearch

Frederick H. Berry; John A. Beaton

1971-01-01

A study of 114 northern red oak, Quercus rubra, indicated that decay is not serious during the time necessary to produce high-quality saw logs and veneer logs. Two heart-rot fungi, Poria oleraceae and P. cocos, accounted for almost 25 percent of the total decay volume in the study trees. Basal fire wounds, dead...

78 FR 20315 - Columbia Gas Transmission, LLC; Notice of Request under Blanket Authorization

Federal Register 2010, 2011, 2012, 2013, 2014

2013-04-04

... Coco C Storage Fields in West Virginia. Columbia states that, as a result of storage field tests, the overall capacity of these fields can be increased. Columbia does not propose to expand the boundaries... fields, all as more fully set forth in the application, which is on file with the Commission and open to...

The mechanism of epoxide carbonylation by [Lewis Acid]+[Co(CO)4]- catalysts.

PubMed

Church, Tamara L; Getzler, Yutan D Y L; Coates, Geoffrey W

2006-08-09

A detailed mechanistic investigation of epoxide carbonylation by the catalyst [(salph)Al(THF)2]+ [Co(CO)4]- (1, salph = N,N'-o-phenylenebis(3,5-di-tert-butylsalicylideneimine), THF = tetrahydrofuran) is reported. When the carbonylation of 1,2-epoxybutane (EB) to beta-valerolactone is performed in 1,2-dimethoxyethane solution, the reaction rate is independent of the epoxide concentration and the carbon monoxide pressure but first order in 1. The rate of lactone formation varies considerably in different solvents and depends primarily on the coordinating ability of the solvent. In mixtures of THF and cis/trans-2,5-dimethyltetrahydrofuran, the reaction is first order in THF. From spectroscopic and kinetic data, the catalyst resting state was assigned to be the neutral (beta-aluminoxy)acylcobalt species (salph)AlOCH(Et)CH2COCo(CO)4 (3a), which was successfully trapped with isocyanates. As the formation of 3a from EB, CO, and 1 is rapid, lactone ring closing is rate-determining. The favorable impact of donating solvents was attributed to the necessity of stabilizing the aluminum cation formed upon generation of the lactone.

Dynamics of tungsten hexacarbonyl, dicobalt octacarbonyl, and their fragments adsorbed on silica surfaces.

PubMed

Muthukumar, Kaliappan; Valentí, Roser; Jeschke, Harald O

2014-05-14

Tungsten and cobalt carbonyls adsorbed on a substrate are typical starting points for the electron beam induced deposition of tungsten or cobalt based metallic nanostructures. We employ first principles molecular dynamics simulations to investigate the dynamics and vibrational spectra of W(CO)6 and W(CO)5 as well as Co2(CO)8 and Co(CO)4 precursor molecules on fully and partially hydroxylated silica surfaces. Such surfaces resemble the initial conditions of electron beam induced growth processes. We find that both W(CO)6 and Co2(CO)8 are stable at room temperature and mobile on a silica surface saturated with hydroxyl groups (OH), moving up to half an Angström per picosecond. In contrast, chemisorbed W(CO)5 or Co(CO)4 ions at room temperature do not change their binding site. These results contribute to gaining fundamental insight into how the molecules behave in the simulated time window of 20 ps and our determined vibrational spectra of all species provide signatures for experimentally distinguishing the form in which precursors cover a substrate.

Tetra-ammine-(carbonato-κ(2) O,O')cobalt(III) nitrate: a powder X-ray diffraction study.

PubMed

Le Bail, Armel

2013-01-01

Practical chemistry courses at universities very frequently propose the synthesis and characterization of [Co(CO3)(NH3)4]NO3, but this goal is never achieved since students only obtain the hemihydrated form. The anhydrous form can be prepared, however, and its structure is presented here. Similar to the hemihydrate form, the anhydrous phase contains the Co(III) ion in an octahedral O2N4 coordination by a chelating carbonate group and four ammine ligands. The structure reveals an intricate array of N-H⋯O hydrogen bonds involving both the chelating and the non-chelating O atoms of the carbonate ligand as hydrogen-bond acceptors of the amine H atoms, which are also involved in hydrogen-bonding inter-actions with the nitrate O atoms. The structure of the anhydrous form is close to that of the hemihydrate phase, suggesting a probable topotactic reaction with relatively small rotations and translations of the [Co(CO3)(NH3)4](+) and NO3 (-) groups during the dehydration process, which produces an unusual volume increase of 4.3%.

Tetra­ammine­(carbonato-κ2 O,O′)cobalt(III) nitrate: a powder X-ray diffraction study

PubMed Central

Le Bail, Armel

2013-01-01

Practical chemistry courses at universities very frequently propose the synthesis and characterization of [Co(CO3)(NH3)4]NO3, but this goal is never achieved since students only obtain the hemihydrated form. The anhydrous form can be prepared, however, and its structure is presented here. Similar to the hemihydrate form, the anhydrous phase contains the CoIII ion in an octahedral O2N4 coordination by a chelating carbonate group and four ammine ligands. The structure reveals an intricate array of N—H⋯O hydrogen bonds involving both the chelating and the non-chelating O atoms of the carbonate ligand as hydrogen-bond acceptors of the amine H atoms, which are also involved in hydrogen-bonding inter­actions with the nitrate O atoms. The structure of the anhydrous form is close to that of the hemihydrate phase, suggesting a probable topotactic reaction with relatively small rotations and translations of the [Co(CO3)(NH3)4]+ and NO3 − groups during the dehydration process, which produces an unusual volume increase of 4.3%. PMID:24046543

Dehydration improves cryopreservation of coconut (Cocos nucifera L.).

PubMed

Sisunandar; Sopade, Peter A; Samosir, Yohannes M S; Rival, Alain; Adkins, Steve W

2010-12-01

Cryopreservation of coconut can be used as a strategy to back up the establishment of living collections which are expensive to maintain and are under constant threat from biotic and abiotic factors. Unfortunately, cryopreservation protocols still need to be developed that are capable of producing a sizeable number of field-grown plants. Therefore, we report on the development of an improved cryopreservation protocol which can be used on a wide range of coconut cultivars. The cryopreservation of zygotic embryos and their recovery to soil-growing plants was achieved through the application of four optimised steps viz.: (i) rapid dehydration; (ii) rapid cooling; (iii) rapid warming and recovery in vitro and (iv) acclimatization and soil-supported growth. The thermal properties of water within the embryos were monitored using differential scanning calorimetry (DSC) in order to ensure that the freezable component was kept to a minimum. The feasibility of the protocol was assessed using the Malayan Yellow Dwarf (MYD) cultivar in Australia and then tested on a range of cultivars which were freshly harvested and studied in Indonesia. The most efficient protocol was one based on an 8-h rapid dehydration step followed by rapid cooling step. Best recovery percentages were obtained when a rapid warming step and an optimised in vitro culture step were used. Following this protocol, 20% (when cryopreserved 12 days after harvesting) and 40% (when cryopreserved at the time of harvest) of all MYD embryos cryopreserved could be returned to normal seedlings growing in soil. DSC showed that this protocol induced a drop in embryo fresh weight to 19% and significantly reduced the amount of water remaining that could produce ice crystals (0.1%). Of the 20 cultivars tested, 16 were found to produce between 10% and 40% normal seedlings while four cultivars generated between 0% and 10% normal seedlings after cryopreservation. This new protocol is applicable to a wide range of coconut cultivars and is useful for the routine cryopreservation of coconut genetic resources. Copyright © 2010 Elsevier Inc. All rights reserved.

How Does the Political Nature of the Defense Acquisition Process Affect Cost Growth

DTIC Science & Technology

2006-09-01

using the following equations. 100*% k k k BCWP COCO = (5) Where: k = the kth year of DAES reporting and, kKk BCWPACWPCO −= (6) The...F-16 270 F-35 Joint Strike Fighter (JSF) 6 FAAD C2I 64 FAAD NLOS Fiber Optic Guided-Missile 7 FBCB2 19 FDS 60 FFG-7 271 Future Aircraft Carrier

Chemical compositions, infrared spectroscopy, and X-ray diffractometry study on brown-rotted woods

Treesearch

Gai-Yun Li; Luo-Hua Huang; Chung Hse; Te-Fu Qin

2011-01-01

The effect of brown-rot decay on the chemical composition and crystallinity of Masson pine was studied by exposing it to Wolfiporia cocos (Schwein.) Ryvarden and Gilbn. for durations of up to 15 weeks in the field. The holocellulose content, α-cellulose content, and wood crystallinity decreased slowly in the initial stage, followed by a significant reduction...

Toddler on the Road

ERIC Educational Resources Information Center

Balick, Marshall; Jepson, Megan

2014-01-01

This article describes the experiences of frequently-traveling parents Balick and Jepson, and their 2-year daughter Coco. As owners of two businesses (an event-planning business and a Montessori aterials company) the travel between 7 days and 3 months at a time--for trade shows, conferences, school visits, and working events. How does one manage…

High resolution sedimentary record from the Cocos Ridge: evidence of land-ocean linkages in the Eastern Equatorial Pacific over the last 70 ka

NASA Astrophysics Data System (ADS)

Murdmaa, I.; Ivanova, E.; Leduc, G.; Beaufort, L.; Peresypkin, V.; Vidal, L.; Ovsepyan, E.; Alekhina, G.; Kravtsov, V.; Vasileva, V.

2009-04-01

We analyzed n-alkanes spectra, TOC content, and C/N ratio in the upper 12 m of the giant IMAGES Core MD02-2529 from the Cocos Ridge (08°12.33'N; 84°07.32'W; 1619 m w.d.) to estimate terrestrial organic matter (TOM) and marine organic matter (MOM) contribution to the total organic matter budget in sediments. Multi-proxy studies of nannofossils, benthic and planktic foraminifers reveal productivity variations during the time interval of the last ~ 70 ka recovered by the upper part of the core according to the age model based on AMS-14C dates and benthic oxygen isotope record. According to the shipboard core description, the slightly calcareous hemipelagic mud recovered by Core MD02-2529 contains a considerable admixture of terrestrial plant remains. This is confirmed by optical microscopic and SEM studies which reveal a strong pyritization of the particular terrestrial organic matter. As estimated by the proportion of the mainly terrestrial long-molecular alkanes (C23 - C38) relative to mainly planktic short-molecular ones (C10 - C22), the TOM input largely controls variations in the TOC content throughout the studied core interval, possibly except for the Upper Holocene, where higher TOC values correspond to relatively increased MOM content. TOM strongly dominates over the MOM content in sediments of the beginning of Termination 1, most enriched in total organic matter (up to 3.4% TOC). High content of the TOM is also fixed by n-alkane data over the Younger Dryas and H-events. Mass accumulation rates (MAR) of TOC, as well as terrestrial and marine organic matter, generally support the data on percentages, but show that the MOM flux was considerable even during the maximum TOM input at the beginning of Termination I. We suggest that this abundant TOM flux was related to the glacioeustatic sea level lowstand at the LGM, during which the emerged shelf became a vegetated coastal plain affected by seasonally humid tropical monsoon climate. The terrestrial organic

Do Periodic Plate Reorganisations Control Late-stage Volcanism across a Broad Galápagos Hotspot?

NASA Astrophysics Data System (ADS)

O'Connor, J. M.; Hoernle, K.; Wijbrans, J. R.; Werner, R.; Hauff, S. F.; Stoffers, P.

2010-12-01

Much of the Galápagos Volcanic Province (GVP), consisting of the Cocos, Carnegie, Coiba and Malpelo aseismic ridges and related seamount provinces, remains poorly understood due to a lack of direct age and geochemical data. In recent years reconnaissance dredge/grab sampling of these submerged regions of the GVP provides some new insights that can be re-evaluated in the context of the three new cruises to the region in 2010. The distribution of 40Ar/39Ar basement ages [1-3] suggest that volcanism migrated time-progressively across GVP in broad regions of long-lived, possible concurrent, hotspot volcanism. Development of the GVP via such broad zones of overlapping volcanism leads to multiple phases of volcanism post-dating the onset of hotspot volcanism, similar to rejuvenescent volcanism that occurs million years after the main shield-building phase of mid-plate oceanic volcano, most notably along the Hawaiian-Emperor Seamount Chain. Evidence for rejuvenescent volcanism across the GVP provides an opportunity to evaluate this poorly understood process in a very different physical setting compared to the Hawaiian-Emperor Chain (mid-plate versus on/near spreading axis). Widespread episodes of coeval GVP volcanism show that the Galápagos hotspot influences broad regions of the lithosphere implying relative motion between the Cocos and Nazca plates and a broad Galápagos hotspot. The complex spreading history of the Cocos-Nazca spreading centre likely controlled the relative distribution of GVP volcanism between the Cocos and Nazca plates while creating lithosphere of variable age/thickness across the region [3]. But recent age and geochemical studies of other hotspot systems show that lithosphere influenced in the past by hotspot activity is more likely to generate late-stage volcanism in response to changing patterns of stress in the lithosphere. Late stage volcanism across a broad Galápagos hotspot might therefore reflect periodic reorganisations of the Gal

GPS Monitoring of Subduction Zone Deformation in Costa Rica

NASA Technical Reports Server (NTRS)

Lundgren, Paul

1997-01-01

The subduction of the Cocos plate beneath Costa Rica is among the highest convergence rates in the world. The high subduction rate and nearness of the Nicoya Peninsula, Costa Rica to the Middle America Trench (MAT) provide a unique opportunity to map variations in interseismic strain of the crust above the seismogenic zone in response to variations in seismic coupling.

Area Handbook Series: Thailand. A Country Study

DTIC Science & Technology

1987-09-01

cashew nuts , soybeans, bananas, sesame, coco- nuts , cotton, kapok, and castor beans. Rice Rice, the nation’s major crop, was grown by about three...Sugarcane ......... 5,382.0 6,585.9 19,910.0 30,260.0 24,000.0 24,410.0 Mung beans ........ 60.3 150.5 120.6 283.7 323.4 325.0 Ground nuts ....... 152.0

Defense Energy Support Center Fact Book, Fiscal Year 1999, Twenty-Second Edition

DTIC Science & Technology

1999-01-01

numbers SOURCE: FACILITIES AND DISTRIBUTION MANAGEMENT COMMODITY BUSINESS UNIT 11 OCONUS COCO 10 8,717,850...GOCO 7 1,518,905 SOURCE: FACILITIES AND DISTRIBUTION MANAGEMENT COMMODITY BUSINESS UNIT DLA MANAGED STORAGE...FY 95 FY 96 FY 97 FY 98 FY 99 SOURCE: FACILITIES AND DISTRIBUTION MANAGEMENT COMMODITY BUSINESS UNIT 13 0 20 40 60 80 100 120 140 160 180 200 220

Seismic anisotropy of western Mexico and northeastern Tibet

NASA Astrophysics Data System (ADS)

Leon-Soto, Gerardo

In this dissertation, characteristics of upper mantle anisotropy, using shear wave splitting techniques, for two distinct tectonic provinces are presented. In the first part, in western Mexico, the Rivera and Cocos plates subduct beneath the North America plate constituting a young subduction setting where plate fragmentation and capture is occurring today. We characterize the upper mantle anisotropy from SKS and local S phases from the data collected by the MARS experiment (MApping the Rivera Subduction zone) and by two stations of the Mexican Servicio Sismologico National. SKS shear-wave splitting parameters indicate that the fast directions of the split SKS waves for the stations that lie on the central and southern Jalisco block are approximately trench normal. Fast polarizations of these phases also follow the convergence direction between the Rivera Plate and Jalisco block with respect to the North America plate. S-wave splitting from slab events show a small averaged delay time of about 0.2 sec for the upper 60 km of the crust and mantle. Therefore, the main source of anisotropy must reside on the entrained mantle below the young and thin Rivera Plate. Trench-oblique fast SKS split directions are observed in the western edge of the Rivera Plate and western parts of the Cocos slab. The curved pattern of fast SKS split directions in the western Jalisco block and the Rivera-Cocos gap indicate 3-D toroidal mantle flow, around the northwestern edge of the Rivera slab and Rivera- Cocos gap. This behavior profoundly affects finite strain field in the northwestern edge of the Rivera slab and the mantle wedge. The shear wave splitting results support the idea that the Rivera and Cocos plates not only moved in a down-dip direction but also have recently rolled back towards the trench and the Colima rift is intimately related to the tearing between the Rivera and Cocos plates. In the second study, the tectonic enviroment of the northeastern Tibetan plateau is

Differential identification of mushrooms sclerotia by IR macro-fingerprint method

NASA Astrophysics Data System (ADS)

Choong, Yew Keong; Lan, Jin; Lee, Han Lim; Chen, Xiang-dong; Wang, Xiao-guang; Yang, Yu-ping

2016-01-01

Many macrofungus sclerotia are well-known medicinal herbs, health food and nutritional supplements. However, the prevalent adulterant commercial products are major hindrances to their incorporation into mainstream medical use in many countries. The mushroom sclerotia of Lignosus rhinocerotis, Poria cocos, Polyporus umbellatus, Pleurotus tuber-regium and Omphalia lapidescens are commonly used in traditional Chinese medicine. In this study, IR macro-fingerprint method was used in the identification of these sclerotia. The results showed that the spectrum of L. rhinocerotis (LR) was comparable with P. cocos with 94.4% correlation, except that the peak at 1543 cm-1 of LR appeared in lower intensity. The spectrum of P. umbellatus and P. tuber-regium was also correlated (91.5%), as both spectra could be clearly discriminated in that P. umbellatus spectrum has small base peaks located at the range of 1680-1500 cm-1. O. lapidescens was not comparable with all the other sclerotia as its spectrum was totally different. Its base peak was broad and derivated equally along the range. The first IR has revealed the dissimilarity among five mushrooms sclerotia. The second derivative and 2DIR further enhanced the identification in detail.

Evaluation of the hormonal state of columnar apple trees (Malus x domestica) based on high throughput gene expression studies.

PubMed

Krost, Clemens; Petersen, Romina; Lokan, Stefanie; Brauksiepe, Bastienne; Braun, Peter; Schmidt, Erwin R

2013-02-01

The columnar phenotype of apple trees (Malus x domestica) is characterized by a compact growth habit with fruit spurs instead of lateral branches. These properties provide significant economic advantages by enabling high density plantings. The columnar growth results from the presence of a dominant allele of the gene Columnar (Co) located on chromosome 10 which can appear in a heterozygous (Co/co) or homozygous (Co/Co) state. Although two deep sequencing approaches could shed some light on the transcriptome of columnar shoot apical meristems (SAMs), the molecular mechanisms of columnar growth are not yet elaborated. Since the influence of phytohormones is believed to have a pivotal role in the establishment of the phenotype, we performed RNA-Seq experiments to study genes associated with hormone homeostasis and clearly affected by the presence of Co. Our results provide a molecular explanation for earlier findings on the hormonal state of columnar apple trees. Additionally, they allow hypotheses on how the columnar phenotype might develop. Furthermore, we show a statistically approved enrichment of differentially regulated genes on chromosome 10 in the course of validating RNA-Seq results using additional gene expression studies.

Investigation of Water Quality and Fisheries of the Black River Lake-Cocodrie Lake Area, Louisiana.

DTIC Science & Technology

1986-08-01

fish (Mike Ewing, District Fisheries Biologist, Louisiana Department of Wildlife and Fisheries - personal communication ). Of this amount, about 5 to...Ewing, District Fisheries Biologist, Louisiana Department of Wildlife and Fisheries - personal communication ). Cobb, et al., (1984) reported that young...f-A072 169 INVESTIGATION OF WATER QUALITY AND FISHERIES OF THE 1/1 BLACK RIVER LAKE-COCO..CU) ARMY ENGINEER WATERWAYS EXPERIMENT STATION VICKSBURG MS

Performance of Charcoal Cookstoves for Haiti, Part 2: Results from the Controlled Cooking Test

DOE Office of Scientific and Technical Information (OSTI.GOV)

Lask, Kathleen; Jones, Jennifer; Booker, Kayje

2011-11-30

Five charcoal cookstoves were tested using a Controlled Cooking Test (CCT) developed from cooking practices in Haiti. Cookstoves were tested for total burn time, specific fuel consumption, and emissions of carbon monoxide (CO), carbon dioxide (CO 2), and the ratio of carbon monoxide to carbon dioxide (CO/CO 2). These results are presented in this report along with LBNL testers’ observations regarding the usability of the stoves.

Defense Acquisition Research Journal. Volume 20, Number 3, Issue 67, October 2013

DTIC Science & Technology

2013-10-01

Contracting Operations (PZCO) FIGURE 4. CONTRACTING PHASE ZERO: PLAN, EXERCISE, REHEARSE, AND SYNCHRONIZE Note. BPA = Blanket Purchase Agreement; COCO...Construction Supplies; Oce Equipment; Quality of Life; and Morale, Welfare, and Recreation PO/TO/DO/ BPA Small Purchase Standard Vehicles PO/TO/DO/ BPA Small...Purchase Standard Vehicles PO/TO/DO/ BPA Small Purchase Standard Vehicles PO/TO/DO/ BPA Small Purchase Food, Water, Billeting, Hygiene; Transportation

Impact of certain flavonoids on lipid profiles--potential action of Garcinia cambogia flavonoids.

PubMed

Koshy, A S; Vijayalakshmi, N R

2001-08-01

Flavonoids from Cocos nucifera, Myristica fragrance, Saraka asoka and Garcinia cambogia exerted hypolipidaemic activity in rats. Lipid lowering activity was maximum in rats administered flavonoids (10 mg/kg BW/day) from Garcinia cambogia. A dose response study revealed biphasic activity. Higher doses were less effective in reducing lipid levels in serum and tissues, although devoid of toxic effects. Copyright 2001 John Wiley & Sons, Ltd.

Antioxidant Activity of Coconut (Cocos nucifera L.) Protein Fractions.

PubMed

Li, Yan; Zheng, Yajun; Zhang, Yufeng; Xu, Jianguo; Gao, Gang

2018-03-20

Coconut cake is an abundant and good potential edible protein source. However, until now it has not been extensively used in the food industry. To promote its usage, the characterization, nutrition value and antioxidant activity of coconut cake protein fractions (albumin, globulin, prolamine, glutelin-1 and glutelin-2) were studied. Results revealed that all the albumin, globulin, glutelin-1 and glutelin-2 fractions showed a high nutrition value. The prolamine, glutelin-1 and glutelin-2 all exhibited good radical scavenging activity and reducing power, and the globulin and prolamine showed high ion chelating ability (89.14-80.38%). Moreover, all the fractions except glutelin-2 could effectively protect DNA against oxidative damage. Several peptides containing five to eight amino acids with antioxidant activity were also identified by LC-MS/MS from the globulin and glutelin-2 fractions. The results demonstrated that the coconut cake protein fractions have potential usages in functional foods.

Antiulcerogenic effects of coconut (Cocos nucifera) extract in rats.

PubMed

Nneli, R O; Woyike, O A

2008-07-01

A warm water crude extract of coconut milk and a coconut water dispersion were investigated for their antiulcerogenic effects in male Wistar albino rats. Ulcers were induced in the male rats by subcutaneous administration of indomethacin (40 mg/kg) using standard procedures. The ulcer inhibition rate (UIR) was taken as a measure of the cytoprotection offered by test substances. Coconut milk (2 mL daily oral feeding) produced a stronger percentage (54%) reduction in the mean ulcer area than coconut water (39%). The effect of coconut milk was similar to the effect of sucralfate that reduced the mean ulcer area by 56% in this study. Sucralfate is a conventional cytoprotective agent. The results showed that coconut milk and water via macroscopic observation had protective effects on the ulcerated gastric mucosa. It is concluded that coconut milk offered stronger protection on indomethacin-induced ulceration than coconut water in rats.

Mid and Late Devonian arenites deposited by sheet-flood, braided streams and rivers in the northern Barrier Ranges, far western New South Wales, Australia

NASA Astrophysics Data System (ADS)

Neef, G.; Bottrill, R. S.; Cohen, D. R.

1996-05-01

Extensive and well exposed, fine-grained fluvial sandstone and less common pebbly coarse-grained fluvial sandstone of Devonian age, crop out in the northern Barrier Ranges of far west New South Wales, Australia. These strata were deposited largely on low-gradient alluvial fans in a basin and range landscape and contain common sedimentary structures (especially streaming lineations and tabular cross-beds). Around 400 of these sedimentary structures were measured to determine the palaeoflow trends of the sheet floods, streams or rivers which deposited the sandstone. The strata are mapped as the Mid Devonian Coco Range Sandstone and the Late Devonian Nundooka Sandstone, which together are around 2.7 km thick. They were deposited at the western margin of the large Emsian to Early Carboniferous Darling Basin. The Coco Range Sandstone is Emsian to Eifelian in age (based on fragments) of fossil fish) and it is separated from the Frasnian-Famennian (Late Devonian) Nundooka Sandstone by the north-trending Nundooka Creek Fault. The eastern boundary of the Nundooka Sandstone is formed by the Western Boundary Fault. Eastward of this fault is the north-trending and 40 km wide Bancannia Trough, which contains gently folded Late Silurian to Early Carboniferous strata up to 7.5 km thick. Most of the Coco Range Sandstone and all of the Nundooka Sandstone are non-graded, fine and very fine-grained, light brown sub-litharenites which are considered to have been deposited mainly on low-gradient alluvial fans. Sedimentary successions of 1.75 to 5.25 m thickness in the fine-grained arenite usually commence with Sm (massive or slumped) → Sh (laminated arenite) or St (trough cross-beds) → Sp (tabular cross-bedded sandstone). An erosional surface commonly underlies the sedimentary successions and they are interpreted to be the result of deposition from decelerating sheet floods. Units composed of tabular cross-bedded strata several metres thick are rarely channelised and are

Bis(2,2'-bipyridyl-κN,N')(carbonato-κO,O')cobalt(III) bromide trihydrate.

PubMed

Ma, Peng-Tao; Wang, Yu-Xia; Zhang, Guo-Qian; Li, Ming-Xue

2007-12-06

The title complex, [Co(CO(3))(C(10)H(8)N(2))(2)]Br·3H(2)O, is isostructural with the chloride analogue. The six-coordinated octahedral [Co(2,2'-bipy)(2)CO(3)](+) cation (2,2'-bipy is 2,2'-bipyrid-yl), bromide ion and water mol-ecules are linked together via O-H⋯Br and O-H⋯O hydrogen bonds, generating a one-dimensional chain.

Phylogeny of Darwin's finches as revealed by mtDNA sequences.

PubMed

Sato, A; O'hUigin, C; Figueroa, F; Grant, P R; Grant, B R; Tichy, H; Klein, J

1999-04-27

Darwin's finches comprise a group of passerine birds first collected by Charles Darwin during his visit to the Galápagos Archipelago. The group, a textbook example of adaptive radiation (the diversification of a founding population into an array of species differentially adapted to diverse environmental niches), encompasses 14 currently recognized species, of which 13 live on the Galápagos Islands and one on the Cocos Island in the Pacific Ocean. Although Darwin's finches have been studied extensively by morphologists, ecologists, and ethologists, their phylogenetic relationships remain uncertain. Here, sequences of two mtDNA segments, the cytochrome b and the control region, have been used to infer the evolutionary history of the group. The data reveal the Darwin's finches to be a monophyletic group with the warbler finch being the species closest to the founding stock, followed by the vegetarian finch, and then by two sister groups, the ground and the tree finches. The Cocos finch is related to the tree finches of the Galápagos Islands. The traditional classification of ground finches into six species and tree finches into five species is not reflected in the molecular data. In these two groups, ancestral polymorphisms have not, as yet, been sorted out among the cross-hybridizing species.

Water inhibits CO oxidation on gold cations in the gas phase. Structures and binding energies of the sequential addition of CO, H2O, O2, and N2 onto Au.

PubMed

Reveles, J Ulises; Saoud, Khaled M; El-Shall, M Samy

2016-10-19

We report a detailed experimental and theoretical study of the gas phase reactivity of Au + with CO, O 2 , N 2 and their mixtures in the presence of a trace amount of water impurity. The gold cation is found to strongly interact with CO and H 2 O molecules via successive addition reactions until reaching saturation. The stoichiometry of the formed complex is determined by the strength of the binding energy of the neutral molecule to the gold cation. CO binds the strongest to Au + , followed by H 2 O, N 2 and then O 2 . We found that the gold cation (Au + ) can activate the O 2 molecule within the Au + (CO) 2 (O 2 ) complex which could react with another CO molecule to form Au + (CO)(CO 2 ) + CO 2 . The product Au + (CO)(CO 2 ) is observed experimentally with a small intensity at room temperature. However, the presence of water leads to the formation of Au + (CO)(H 2 O)(O 2 ) instead of Au + (CO) 2 (O 2 ) due to the strong interaction between Au + and water. The current experiments and calculations might lead to a molecular level understanding of the interactions between the active sites, reactants and impurities which could pave the way for the design of efficient nanocatalysts.

High Aspect Ratio Perforated Co₃O₄ Nanowires Derived from Cobalt-Carbonate-Hydroxide Nanowires with Enhanced Sensing Performance.

PubMed

Zhou, Tuantuan; Gao, Wanlin; Wang, Qiang; Umar, Ahmad

2018-05-01

Herein, we report the facile synthesis of high-aspect ratio perforated Co3O4 nanowires derived from cobalt-carbonate-hydroxide (Co(CO3)0.5(OH) 0.11H2O) nanowires. The Co(CO3)0.5(OH) 0.11H2O nanowires were synthesized by simple hydrothermal process at 120 °C while annealing of such nanowires at 400 °C leads the formation of perforated Co3O4 nanowires. The prepared nanowires were characterized by several techniques which confirmed the high aspect ratio and well-crystallinity for the synthesized nanowires. For application point of view, the prepared perforated Co3O4 nanowires were used as efficient electrode material to fabricate highly sensitive and selective hydrazine chemical sensor. The electrochemical impedance spectroscopy (EIS) technique was employed to confirm the successful modification of the electrode. The key parameters of chemical sensor, such as detection limit, sensitivity, and linear range, have been systematically explored. The fabricated hydrazine sensor displayed a rather low detection limit of 4.52 μM (S/N = 3), a good sensitivity of 25.70 μA · mM-1, and a wide linear range of 16.97-358.34 μM.

Differential identification of mushrooms sclerotia by IR macro-fingerprint method.

PubMed

Choong, Yew Keong; Lan, Jin; Lee, Han Lim; Chen, Xiang-Dong; Wang, Xiao-Guang; Yang, Yu-Ping

2016-01-05

Many macrofungus sclerotia are well-known medicinal herbs, health food and nutritional supplements. However, the prevalent adulterant commercial products are major hindrances to their incorporation into mainstream medical use in many countries. The mushroom sclerotia of Lignosus rhinocerotis, Poria cocos, Polyporus umbellatus, Pleurotus tuber-regium and Omphalia lapidescens are commonly used in traditional Chinese medicine. In this study, IR macro-fingerprint method was used in the identification of these sclerotia. The results showed that the spectrum of L. rhinocerotis (LR) was comparable with P. cocos with 94.4% correlation, except that the peak at 1543cm(-1) of LR appeared in lower intensity. The spectrum of P. umbellatus and P. tuber-regium was also correlated (91.5%), as both spectra could be clearly discriminated in that P. umbellatus spectrum has small base peaks located at the range of 1680-1500cm(-1). O. lapidescens was not comparable with all the other sclerotia as its spectrum was totally different. Its base peak was broad and derivated equally along the range. The first IR has revealed the dissimilarity among five mushrooms sclerotia. The second derivative and 2DIR further enhanced the identification in detail. Copyright © 2015 Elsevier B.V. All rights reserved.

Tectonic analysis and paleo-stress determination of the upper lava section at ODP/IODP site 1256 (East Pacific Ocean)

NASA Astrophysics Data System (ADS)

Fontana, Emanuele

2015-09-01

Research on the deep sea is of great importance for a better understanding of the mechanism of magma emplacement and the tectonic evolution of oceanic crust. However, details of the internal structure in the upper levels of the oceanic crust are much less complete than that of the more fully studied sub-aerial areas. For the first time, this study proposes a dynamic analysis using the inversion method on core data derived from the drilled basement of the present-day intact oceanic crust at ODP/IODP Site 1256 in the Cocos plate. The research is based on an innovative core reorientation process and combines different stress hypothesis approaches for the analysis of heterogeneous failure-slip data via exploitation of two distinct techniques. From the analysis of the failure-slip data, both techniques produce 5 distinct subsystem datasets. All calculated subsystems are mechanically and geometrically admissible. Interpretation of the results allows the researchers to note a complex local and regional tectonic evolution deriving from the interplay of (1) the ridge push and rotation of both the East Pacific Rise and the Cocos-Nazca Spreading Center, (2) the effect of the slab pull of the Middle America Trench, (3) the influence of lava emplacement mechanisms, and (4) intra-plate deformation.

Bis[bis­(2,2′-bi­pyridine-κ2 N,N′)(carbon­ato-κ2 O,O′)cobalt(III)] 2-{4-[(carboxyl­atometh­yl)carbamo­yl]benz­amido}­acetate hexa­hydrate

PubMed Central

Pook, Niels-Patrick; Gjikaj, Mimoza; Adam, Arnold

2014-01-01

The complex cation of the title compound, [Co(CO3)(C10H8N2)2]2(C12H10N2O6)·6H2O, contains a CoIII atom with a distorted octa­hedral coordination environment formed by four N atoms from two bidentate 2,2′-bi­pyridine ligands and one bidentate carbonate anion. The asymmetric unit is completed by one-half of the 2-({4-[(carboxyl­atometh­yl)carbamo­yl]phen­yl}formamido)­acetate dianion, which is located on a centre of inversion, and by three water mol­ecules. Two [Co(CO3)(C10H8N2)2]+ cations are connected through C—H⋯O contacts by the uncoordinating anions. The aromatic rings of the 2,2′-bi­pyridine ligands and di­acetate anions are involved in π–π stacking and C—H⋯π inter­actions. The centroid–centroid distances are in the range 3.4898 (4)–3.6384 (5) Å. The crystal structure is stabilized by further O—H⋯O and N—H⋯O hydrogen bonds, which give rise to a three-dimensional supra­molecular network. PMID:24860299

JPRS Report, Soviet Union, Kommunist, No. 10, July 1989.

DTIC Science & Technology

1989-09-21

the verbal husks from the ornaments, allegedly had very little to do with class antagonism. The requirement of class nature here is most often...tea. All such goods, including coconuts and bananas, are almost always available in the stores. Coco- nuts, for example, may not enjoy particular... coconuts than not to purchase them. In recent years the country has begun to import substan- tial volumes of grain as well, about half a million tons

Autophagy and TGF-Beta Antagonist Signaling in Breast Cancer at Premetastatic Sites

DTIC Science & Technology

2015-06-01

dormant legions. These inhibitors will be the drug leads for further medicinal chemistry and preclinical/clinical studies. 4 Body Overview Over the...autophagy, largely due to unexpected half-year delay of the official approval of our ACURO animal protocol . Below we report our progress, starting with...sections taken at various times after tail vein injection will enable us to verify that the anti-Coco MAb does not affect extravasation or homing but

Mariana Islands-Hyperspectral Airborne Remote Environmental Sensing Experiment 2010

DTIC Science & Technology

2012-04-09

In some places along the strand, coconut palms (Cocos nucifera) were the dominant plant and the litter which has fallen year after year, posed a...in San Jose, Tinian’s largest village, in order to survey several beaches, the limestone cliffs, and a variety of plant species. The Tinian coastline...thrives on sandy soils and is highly tolerant of salinity. Cordia subcordata niyoron Strand Small (1-7m) tree found along the beach and on

A Cultural Resources Inventory of the Proposed Dry Impoundment Area North of Ross Barnett Reservoir and Field Reconnaissance of the Pearl River, between River Miles 278 and 301, in the Vicinity of Jackson, Mississippi.

DTIC Science & Technology

1982-08-01

are about twice as many herbs as shrubs and vines. These subordinate species support a rich fauna of insectp and spiders. The understory trees include...coco, three-cornered grass, yellow cut grass, bull tongue, pickerel weed and wild mullet charac- terize the vegetation in the brackish marshes. The...that frog legs are generally known as a good source of food, and in aboriginal times, salamanders were also eaten. Edible and larger frogs that would

Preferential Redistribution of Fine-Grained Particles in the Panama Basin and Potential Errors in 230Th-Derived Focusing Factors

NASA Astrophysics Data System (ADS)

Marcantonio, F.; Lyle, M. W.; Ibrahim, R.

2013-12-01

The 230Th constant-flux proxy technique, commonly used in paleoceanography to estimate sediment fluxes, is thought to differentiate lateral from vertical fluxes of sediment at sites that have undergone sediment redistribution. However, redistribution processes (focusing or winnowing) are expected to fractionate fine particles from those that are coarse. Since fine particles with greater surface area are known to contain greater concentrations of 230Th, one might expect that sediment redistribution would bias 230Th-derived sediment mass accumulation rates (MARs). We investigate this possibility in two regions of the Panama Basin where significant sediment focusing has been hypothesized to occur. We examine multicore sediments from paired sites at two locations, one close to the equator at the southern limit of the Panama Basin (Carnegie Ridge) where upwelling and primary productivity are high, and one at 6°N at the northern boundary of the Panama Basin (Cocos Ridge), where primary productivity is lower. The multicores, which are constrained by radiocarbon ages that span the latest Holocene at each paired site, represent regions that have undergone potential winnowing and focusing (thin vs thick sediment drapes identified using seismic reflection) at each Panama Basin location. Since the distance separating the paired sites at each location is no more than about 50 km, one would expect the 230Th-derived MARs to be similar, i.e., the rain rate should not be significantly different at each of the paired sites. The radiocarbon-derived sand fraction (>63-μm) MARs, which likely represent the vertical rain of particles not transported by bottom currents, are identical at each of the paired sites, with fluxes at the Carnegie Ridge about 3.5 times greater than those at the Cocos Ridge over the past several thousand years. Over the same time period, the 230Th-normalized MARs are relatively similar at both the Carnegie and Cocos sites, but are different by about 60% at each

Emissions of mercury in Southern Africa derived from long-term observations at Cape Point, South Africa

NASA Astrophysics Data System (ADS)

Brunke, E.-G.; Ebinghaus, R.; Kock, H. H.; Labuschagne, C.; Slemr, F.

2012-05-01

Mercury emissions in South Africa have so far been estimated only by a bottom-up approach from activities and emission factors for different processes. In this paper we derive GEM/CO (GEM being gaseous elemental mercury, Hg0), GEM/CO2, GEM/CH4, CO/CO2, CH4/CO2, and CH4/CO emission ratios from plumes observed during long-term monitoring of these species at Cape Point between March 2007 and December 2009. The average observed GEM/CO, GEM/CO2, GEM/CH4, CO/CO2, CH4/CO2, and CH4/CO emission ratios were 2.40 ± 2.65 pg m-3 ppb-1 (n = 47), 62.7 ± 80.2 pg m-3 ppb-1 (n = 44), 3.61 ± 4.66 pg m-3 ppb-1 (n = 46), 35.6 ± 25.4 ppb ppm-1 (n = 52), 20.2 ± 15.5 ppb ppm-1 (n=48), and 0.876 ± 1.106 ppb ppm-1 (n=42), respectively. The observed CO/CO2, CH4/CO2, and CH4/CO emission ratios agree within the combined uncertainties of the observations and emissions with the ratios calculated from EDGAR (version 4.2) CO2, CO, and CH4 inventories for South Africa and Southern Africa (South Africa, Lesotho, Swaziland, Namibia, Botswana, Zimbabwe, and Mozambique) in 2007 and 2008 (inventories for 2009 are not available yet). Total elemental mercury emission of 13.1, 15.2, and 16.1 t Hg yr-1 are estimated independently using the GEM/CO, GEM/CO2, and GEM/CH4 emission ratios and the annual mean CO, CO2, and CH4 emissions, respectively, of South Africa in 2007 and 2008. The average of these independent estimates of 14.8 ± 1.5 t GEM yr-1 is much less than the total emission of 257 t Hg yr-1 from older inventories. Considering that emission of GEM represents only 50-78% of all mercury emissions, our estimates come close to the total mercury emission estimates ranging between 40-50 t Hg yr-1 from more recent inventories.

Influence Of The Redox State On The Electrical Conductivity Of Basaltic Melts

NASA Astrophysics Data System (ADS)

Pommier, A.; Gaillard, F.; Pichavant, M.

2007-12-01

The electrical conductivity is an efficient probe of mass transfer processes within silicate melts and magmas. Previous studies have established that the electrical conductivity is sensitive to parameters such as temperature, melt composition and pressure. In contrast to what is known for Fe-bearing minerals, little attention has been given to the influence of redox state on the electrical conductivity of melts. Experiments were performed on tephritic and basaltic compositions respectively from Mt. Vesuvius and Pu'u 'O'o. Measurements were carried out on cylindrical glass samples (OD: 6 mm, ID: 1 mm, L: 8 mm) drilled from glass obtained by fusing each rock sample at 1400°C in air. A two-electrode configuration was adopted, with the electrical impedance being radially measured. A Pt wire was used as the internal electrode whereas a Pt tube served as the external electrode. Experiments were conducted at 1 atm in a vertical furnace between 1200°C and 1300°C, both in air and in a CO-CO2 atmosphere at a fO2 corresponding to NNO+1. Both reduction and oxidation experiments were performed. In reduction experiments (pure CO2 then CO-CO2 gas mixture), electrical conductivities progressively increase with time. The reverse is observed in oxidation experiments (CO-CO2 gas mixture then pure CO2). These variations of electrical conductivities are correlated with modifications of the Fe2+/Fe3+ ratio in the melt, and are consistent with the respective structural roles of Fe2+ and Fe3+. In both types of experiments, a minimum of about 400 mn is necessary before a plateau is reached, interpreted to reflect the kinetics of attainment of the equilibrium Fe2+/Fe3+ ratio in the melt. Differences between plateau and initial values are typically of a few ohms, much higher than the sensitivity of our measurements (better than 0.1 ohm). When increasing temperature, the time required for reaching plateau values decreases. At NNO+1, the electrical activation energy (Ea) was determined for

An Approach to the Quantitative Study of Sea Floor Topography.

DTIC Science & Technology

1980-01-01

Basement in the Pacific Ocean MAGNETIC TOTAL RMS ANOMALY SPREADING RELIEF MEAN RMS RIDGE WINDOW RATE (cm/yr) (meters) RELIEF (meters) Nazca-Cocos 0-2’ 6 104...investigation. V. CONCLUSIONS The sea floor and the lithologic boundaries below it can generally be thought of as interfaces of acoustic impedance mismatch... Magnetic Anomalies , and Plate Tectonic History of the Mouth of the Gulf of California. Geol. Soc. Am. Bull., v. 83, p. 3345-3360. Luyendyk, B. P

Modulus, Strength and Thermal Exposure Studies of FP-Al2O3/Aluminum and FP-Al2O3/Magnesium Composites.

DTIC Science & Technology

1981-01-01

for the ~AUG18IS~ 1W Symposium on Comites and Advanced Materials*M sponsored by the American Ceramic Society Coco Beach, Florida, January 18424, 1981E...properties of cFP-A203 fiber reinforced composites prepared by liquid metal infiltration f a techniques. The first approach was the incorporation of a...coated FP-A1203 fibers in the composites. This coating is readily wet by molten aluminum and permitted the use of more conventional aluminum alloys

Identification (ID) Cards for Members of the Uniformed Services, Their Dependents, and Other Eligible Individuals

DTIC Science & Technology

1992-12-30

Encl 5) Cayman Islands CJ Central African Republic CT Chad CD Chile CI China CH Christmas Island KT Clipperton Islands IP Cocos (Keeling) Islands CK...PA Puerto Rico PR Rhode Island RI South Carolina SC South Dakota SD Tennessee TN Federated States of Marshall Islands , Palau TT Texas TX Utah UT...Vermont VT Virginia VA Virgin Islands VI Washington WA West Virginia WV Wisconsin WI Wyoming WY Block 17. ZIP Code. Enter the correct nine-digit ZIP Code

Advanced Concepts for Composite Structure Joints and Attachment Fittings. Volume 2. Design Guide

DTIC Science & Technology

1981-11-01

500 3CC000 .loo 310- GRID 11040 100 M250 30.0000 .0 3311- GRID 11041 100 .2OO 15.COCO .5000 332- GRID 13042 ILO .2500 15.0000 .4000 313- GRID 11043...b~ l ( 115K -. 1 2 It e l t 1 1 A N A I 1 1 CARO 1 L~uNI 4 ... * ’ * 9.. 6 . p. . . 0 h0t- 91’ S 193 1001% 109 1016 402- SPl 9 123 10004 10006

Interactive Programming and Analysis Aids (IPAA)

DTIC Science & Technology

1978-06-01

PAGE 2. GOVT ACCESSION NO.J I JBBIITWj ’"" —— ■ "- INTERACTIVE PROGRAMMING AND ANALYSIS AIDS (IPÄA). 7^ 9. PERFORMING ORGANIZATION ...H fll u u u j o^ o f-« w « » m ^ r>» • ff> o fH CM w * «n >II N ec o^ o »^ ew « isik.f.^iiki>.i«.i^coco<s(Oflos>cocoa> coff >0^ovo«oko^3^a

Bis(2,2′-bipyridyl-κ2 N,N′)(carbonato-κ2 O,O′)cobalt(III) bromide trihydrate

PubMed Central

Ma, Peng-Tao; Wang, Yu-Xia; Zhang, Guo-Qian; Li, Ming-Xue

2008-01-01

The title complex, [Co(CO3)(C10H8N2)2]Br·3H2O, is isostructural with the chloride analogue. The six-coordinated octahedral [Co(2,2′-bipy)2CO3]+ cation (2,2′-bipy is 2,2′-bipyrid­yl), bromide ion and water mol­ecules are linked together via O—H⋯Br and O—H⋯O hydrogen bonds, generating a one-dimensional chain. PMID:21200495

Tetraammine(carbonato-κ(2) O,O')cobalt(III) perchlorate.

PubMed

Mohan, Singaravelu Chandra; Jenniefer, Samson Jegan; Muthiah, Packianathan Thomas; Jothivenkatachalam, Kandasamy

2013-01-01

In the title complex, [Co(CO3)(NH3)4]ClO4, both the cation and anion lie on a mirror plane. The Co(III) ion is coordinated by two NH3 ligands and a chelating carbonato ligand in the equatorial sites and by two NH3 groups in the axial sites, forming a distorted octa-hedral geometry. In the crystal, N-H⋯O hydrogen bonds connect the anions and cations, forming a three-dimensional network.

Antibiofilm activity of coconut (Cocos nucifera Linn.) husk fibre extract.

PubMed

Viju, N; Satheesh, S; Vincent, S G P

2013-01-01

In this study, antibiofilm activity of coconut husk extract (CHE) was tested by various assays in the laboratory. The effects of CHE on extracellular polymeric substance (EPS) production, hydrophobicity and adhesion ability of Pseudomonas sp., Alteromonas sp. and Gallionella sp. and the antimicrobial activity of the extract against these bacteria were assessed. CHE was found to possess antibacterial activity against all the bacterial strains and affected the EPS production. The CHE affected the growth of the biofilm-forming bacteria in a culture medium. The hydrophobicity of the bacterial cells was also changed due to the CHE treatment. The active compound of the CHE was characterised by thin-layer chromatography (TLC), high performance liquid chromatography (HPLC) and fourier transform infrared (FT-IR) analysis. HPLC spectrum showed a single peak and the FT-IR spectrum indicated the presence of an OH-group-containing compound in the extract. In conclusion the CHE could be used as a source for the isolation of antifouling compounds.

Antibiofilm activity of coconut (Cocos nucifera Linn.) husk fibre extract

PubMed Central

Viju, N.; Satheesh, S.; Vincent, S.G.P.

2012-01-01

In this study, antibiofilm activity of coconut husk extract (CHE) was tested by various assays in the laboratory. The effects of CHE on extracellular polymeric substance (EPS) production, hydrophobicity and adhesion ability of Pseudomonas sp., Alteromonas sp. and Gallionella sp. and the antimicrobial activity of the extract against these bacteria were assessed. CHE was found to possess antibacterial activity against all the bacterial strains and affected the EPS production. The CHE affected the growth of the biofilm-forming bacteria in a culture medium. The hydrophobicity of the bacterial cells was also changed due to the CHE treatment. The active compound of the CHE was characterised by thin-layer chromatography (TLC), high performance liquid chromatography (HPLC) and fourier transform infrared (FT-IR) analysis. HPLC spectrum showed a single peak and the FT-IR spectrum indicated the presence of an OH-group-containing compound in the extract. In conclusion the CHE could be used as a source for the isolation of antifouling compounds. PMID:23961225

Cryopreservation of coconut (Cocos nucifera L.) zygotic embryos by vitrification.

PubMed

Sajini, K K; Karun, A; Amamath, C H; Engelmann, F

2011-01-01

The present study investigates the effect of preculture conditions, vitrification and unloading solutions on survival and regeneration of coconut zygotic embryos after cryopreservation. Among the seven plant vitrification solutions tested, PVS3 was found to be the most effective for regeneration of cryopreserved embryos. The optimal protocol involved preculture of embryos for 3 days on medium with 0.6 M sucrose, PVS3 treatment for 16 h, rapid cooling and rewarming and unloading in 1.2 M sucrose liquid medium for 1.5 h. Under these conditions, 70-80 survival (corresponding to size enlargement and weight gain) was observed with cryopreserved embryos and 20-25 percent of the plants regenerated (showing normal shoot and root growth) from cryopreserved embryos were established in pots.

In vitro culture of coconut (Cocos nucifera L.) zygotic embryos.

PubMed

Engelmann, Florent; Malaurie, Bernard; N'Nan, Oulo

2011-01-01

Coconut is a very important crop for millions of people in tropical countries. With coconut, in vitro culture protocols have been developed with two main objectives, viz. the large scale production of particular types of coconuts and the international exchange and conservation of coconut germplasm. The methods described in this chapter have been developed in the framework of collaborative activities between research institutes in Côte d'Ivoire and France. Two coconut embryo in vitro collecting protocols have been established, one consisting of storing the disinfected embryos in a KCl solution until they are brought back to the laboratory, where they are re-disinfected and inoculated in vitro under sterile conditions, and the other including in vitro inoculation of the embryos in the field. For international germplasm exchange, zygotic embryos inoculated in vitro in plastic test tubes or endosperm cylinders containing embryos in plastic bags are used. For in vitro culture, embryos are inoculated on semi-solid medium supplemented with sucrose and activated charcoal and placed in the dark, and then transferred to light conditions with the same (solid or liquid) medium once the first true leaf is visible and the root system has started developing.

Microwave-assisted pyrolysis of Mississippi coal: A comparative study with conventional pyrolysis

DOE Office of Scientific and Technical Information (OSTI.GOV)

Abdelsayed, Victor; Shekhawat, Dushyant; Smith, Mark W.

Pyrolysis conditions greatly affect the structure-reactivity relationship of char during coal gasification. Here, this work investigated the effect of temperature and microwave heating on the structural properties of the chars generated during pyrolysis, as well as gaseous and tar products. Results showed that microwave pyrolysis of Mississippi coal produced more gaseous products and less tars compared to conventional pyrolysis. Higher CO/CO 2 ratio (>1) was observed under microwave pyrolysis compared to conventional pyrolysis (CO/CO2 < 1), which may be explained by a greater extent of gasification between solid carbon and the CO 2 formed during microwave pyrolysis. Additionally, in microwavemore » pyrolysis, the oil tars generated exhibited lower concentrations of polar oxygenates, while the wax tars showed higher concentrations of non-polar alkanes, as observed from the intensity of CH vibrations in FTIR. The product compositions and FTIR analysis of the tars (oils and waxes) suggest that the microwave interacted preferentially with these polar species, which have relatively higher dielectric properties compared to alkanes. The structure–reactivity relationship of the chars produced was also investigated using a variety of characterization tools such as XRD, BET, SEM, EDS, and FTIR. Finally, the char reactivity towards combustion suggested that microwave-produced chars have a higher thermal stability, likely due to lower O/C ratios, and could be utilized in the metallurgical industry.« less

Microwave-assisted pyrolysis of Mississippi coal: A comparative study with conventional pyrolysis

DOE PAGES

Abdelsayed, Victor; Shekhawat, Dushyant; Smith, Mark W.; ...

2018-01-13

Pyrolysis conditions greatly affect the structure-reactivity relationship of char during coal gasification. Here, this work investigated the effect of temperature and microwave heating on the structural properties of the chars generated during pyrolysis, as well as gaseous and tar products. Results showed that microwave pyrolysis of Mississippi coal produced more gaseous products and less tars compared to conventional pyrolysis. Higher CO/CO 2 ratio (>1) was observed under microwave pyrolysis compared to conventional pyrolysis (CO/CO2 < 1), which may be explained by a greater extent of gasification between solid carbon and the CO 2 formed during microwave pyrolysis. Additionally, in microwavemore » pyrolysis, the oil tars generated exhibited lower concentrations of polar oxygenates, while the wax tars showed higher concentrations of non-polar alkanes, as observed from the intensity of CH vibrations in FTIR. The product compositions and FTIR analysis of the tars (oils and waxes) suggest that the microwave interacted preferentially with these polar species, which have relatively higher dielectric properties compared to alkanes. The structure–reactivity relationship of the chars produced was also investigated using a variety of characterization tools such as XRD, BET, SEM, EDS, and FTIR. Finally, the char reactivity towards combustion suggested that microwave-produced chars have a higher thermal stability, likely due to lower O/C ratios, and could be utilized in the metallurgical industry.« less

Faster R-CNN: Towards Real-Time Object Detection with Region Proposal Networks.

PubMed

Ren, Shaoqing; He, Kaiming; Girshick, Ross; Sun, Jian

2017-06-01

State-of-the-art object detection networks depend on region proposal algorithms to hypothesize object locations. Advances like SPPnet [1] and Fast R-CNN [2] have reduced the running time of these detection networks, exposing region proposal computation as a bottleneck. In this work, we introduce a Region Proposal Network (RPN) that shares full-image convolutional features with the detection network, thus enabling nearly cost-free region proposals. An RPN is a fully convolutional network that simultaneously predicts object bounds and objectness scores at each position. The RPN is trained end-to-end to generate high-quality region proposals, which are used by Fast R-CNN for detection. We further merge RPN and Fast R-CNN into a single network by sharing their convolutional features-using the recently popular terminology of neural networks with 'attention' mechanisms, the RPN component tells the unified network where to look. For the very deep VGG-16 model [3] , our detection system has a frame rate of 5 fps (including all steps) on a GPU, while achieving state-of-the-art object detection accuracy on PASCAL VOC 2007, 2012, and MS COCO datasets with only 300 proposals per image. In ILSVRC and COCO 2015 competitions, Faster R-CNN and RPN are the foundations of the 1st-place winning entries in several tracks. Code has been made publicly available.

Imaging the Eastern Trans-Mexican Volcanic Belt and the Veracruz Basin with Ambient Seismic noise and Earthquake Body Waves

NASA Astrophysics Data System (ADS)

Castillo, J.; Clayton, R. W.

2017-12-01

The Trans-Mexican Volcanic Belt (TMVB) is a prominent and enigmatic feature of the subduction system in Mexico. Its volcanic style diversity and oblique orientation to the trench are explained by the large along-strike variations in the subduction parameters of the Rivera and Cocos plates. However, the abrupt termination of the TMVB on its eastern end with the Pico de Orizaba volcano is puzzling as the current slab model suggests that the transition of the Cocos flat-slab geometry to normal subduction is smooth through this region. There is evidence that suggests that a tear in the slab might be developing, but it is unclear how this feature can support the unusually large topographic gradient that connects the volcanic high peaks with the Veracruz basin just south of the volcanic front. To provide further insight into the transition anatomy of this portion of the slab, and its relation with surface topography, we present a detailed and unified model of the structure of the crust and uppermost mantle built from fundamental-mode Rayleigh and Love surface waves, and high-quality arrival-time data of regional and teleseismic earthquakes. The anisotropic behavior of the subsurface of this region and its relation with present and past flow of material is also quantified and integrated into the model to explain the tectonic evolution of this area.

Tetraammine(carbonato-κ2 O,O′)cobalt(III) perchlorate

PubMed Central

Mohan, Singaravelu Chandra; Jenniefer, Samson Jegan; Muthiah, Packianathan Thomas; Jothivenkatachalam, Kandasamy

2013-01-01

In the title complex, [Co(CO3)(NH3)4]ClO4, both the cation and anion lie on a mirror plane. The CoIII ion is coordinated by two NH3 ligands and a chelating carbonato ligand in the equatorial sites and by two NH3 groups in the axial sites, forming a distorted octa­hedral geometry. In the crystal, N—H⋯O hydrogen bonds connect the anions and cations, forming a three-dimensional network. PMID:24109252

Retinoic acid plus arsenic trioxide, the ultimate panacea for acute promyelocytic leukemia?

PubMed

Lallemand-Breitenbach, Valérie; de Thé, Hugues

2013-09-19

Rarely in the field of cancer treatment did we experience as many surprises as with acute promyelocytic leukemia (APL). Yet, the latest clinical trial reported by Lo-Coco et al in the New England Journal of Medicine is a practice-changing study, as it reports a very favorable outcome of virtually all enrolled low-intermediate risk patients with APL without any DNA-damaging chemotherapy. Although predicted from previous small pilot studies, these elegant and stringently controlled results open a new era in leukemia therapy.

Summary of IODP Expedition 344, CRISP-A2, offshore the Osa Peninsula, Costa Rica

NASA Astrophysics Data System (ADS)

Harris, R. N.; Sakaguchi, A.; Petronotis, K. E.

2013-12-01

The Costa Rica Seismogenesis Project (CRISP) is designed to elucidate the processes that control nucleation and seismic rupture of large earthquakes at erosional subduction zones. The CRISP study area is located offshore the Osa Peninsula where the incoming Cocos Ridge has lifted the seismogenic zone to within reach of scientific drilling. The incoming plate is characterized by low sediment supply, a fast convergence rate, abundant plate interface seismicity, and a change in subducting plate relief along strike. In addition to elucidating processes at erosional convergent margins, this project is complementary to other IODP deep fault drilling projects (e.g., NanTroSEIZE and J-FAST). Expedition 344 (23 October - 11 December, 2012) is the second expedition of CRISP Program A (Integrated Ocean Drilling Program Proposal 537A-Full5) that focused on the shallow lithologic, hydrologic, stress, and thermal conditions that lead to unstable slip in the seismogenic zone. With the exception of not reaching the décollement and the underthrust sediment at the toe site (U1412), Expedition 344 exceeded expectations. Material was recovered from the incoming Cocos plate (Sites U1381 and U1414), the toe of the margin (Site U1412), the mid-slope region (Site U1380), and the upper-slope region (Site U1413). Input sites U1381 and U1414 are characterized by anomalously high heat flow and the flow of fluids. These sites contained abundant ash that will be used to assess the impact of Cocos Ridge subduction on the evolution of the Central American volcanic arc. Although toe Site U1412 did not cross the décollement we did penetrate terrigenous sediments interrupted by a Miocene ooze that may reflect accretion of a frontal prism sliver. Mid-slope Site U1380 yielded a major result in that the upper plate material is not a mélange of oceanic material or the offshore extension of the Caribbean large igneous complex, but forearc basin material consisting of lithic sedimentary units. Upper

Analysis physical properties of composites polymer from cocofiber and polypropylene plastic waste with maleic anhydrate as crosslinking agent

NASA Astrophysics Data System (ADS)

Pelita, E.; Hidayani, T. R.; Akbar, A.

2017-07-01

This research was conducted with the aim to produce composites polymer with polypropylene plastic waste materials and cocofiber which aims to produce wood replacement material in the home furnishings industry. This research was conducted with several stages. The first stage is the process of soaking coco fiber with detergent to remove oil and 2% NaOH. The second stage is to combine the polypropylene plastic waste with cocofiber is a chemical bond, modification by adding maleic anhydride as a crosslinking agent and benzoyl peroxide as an initiator each as much as 1%. Mixing materials done by reflux method using xylene solvent. In this study, carried out a wide range of weight variation of coco fiber are added to the 10, 20, 30, 40 and 50%. The third stage is a polymer composite molding process using hot press at a temperature of 158°C. The results of polymer composites Showed optimum condition on the addition of 40% cocofiber with supple tensile strength value of 90.800 kgf /cm2 and value of elongation break at 3.6726 x 104 (kgf/cm2), melting point at 160.02°C, burning point 463.43°C, residue of TGA is 19%, the density of 0.84 g/mL. From these data, conclude that the resulting polymer composites meet the SNI 03-2105-2006 about ordinary composite polymer and polymer composite structural type 8 regular types from 17.5 to 10.5.

Formation mechanisms of Fe3−xSnxO4 by a chemical vapor transport (CVT) process

PubMed Central

Su, Zijian; Zhang, Yuanbo; Liu, Bingbing; Chen, Yingming; Li, Guanghui; Jiang, Tao

2017-01-01

Our former study reported that Fe-Sn spinel (Fe3−xSnxO4) was easily formed when SnO2 and Fe3O4 were roasted under CO-CO2 atmosphere at 900–1100 °C. However, the formation procedure is still unclear and there is a lack of theoretical research on the formation mechanism of the Fe-Sn spinel. In this work, the reaction mechanisms between SnO2 and Fe3O4 under CO-CO2 atmosphere were determined using XRD, VSM, SEM-EDS, XPS, etc. The results indicated that the formation of Fe3−xSnxO4 could be divided into four steps: reduction of SnO2 to solid phase SnO, volatilization of gaseous SnO, adsorption of gaseous SnO on the surface of Fe3O4, and redox reaction between SnO and Fe3O4. During the roasting process, part of Fe3+ in Fe3O4 was reduced to Fe2+ by gaseous SnO, and meanwhile Sn2+ was oxidized to Sn4+ and entered into Fe3−xSnxO4. The reaction between SnO2 and Fe3O4 could be summarized as Fe3O4 + xSnO(g) → Fe3−xSnxO4 (x = 0–1.0). PMID:28262673

Water-rich bending faults at the Middle America Trench

NASA Astrophysics Data System (ADS)

Naif, Samer; Key, Kerry; Constable, Steven; Evans, Rob L.

2015-09-01

The portion of the Central American margin that encompasses Nicaragua is considered to represent an end-member system where multiple lines of evidence point to a substantial flux of subducted fluids. The seafloor spreading fabric of the incoming Cocos plate is oriented parallel to the trench such that flexural bending at the outer rise optimally reactivates a dense network of normal faults that extend several kilometers into the upper mantle. Bending faults are thought to provide fluid pathways that lead to serpentinization of the upper mantle. While geophysical anomalies detected beneath the outer rise have been interpreted as broad crustal and upper mantle hydration, no observational evidence exists to confirm that bending faults behave as fluid pathways. Here we use seafloor electromagnetic data collected across the Middle America Trench (MAT) offshore of Nicaragua to create a comprehensive electrical resistivity image that illuminates the infiltration of seawater along bending faults. We quantify porosity from the resistivity with Archie's law and find that our estimates for the abyssal plain oceanic crust are in good agreement with independent observations. As the Cocos crust traverses the outer rise, the porosity of the dikes and gabbros progressively increase from 2.7% and 0.7% to 4.8% and 1.7%, peaking within 20 km of the trench axis. We conclude that the intrusive crust subducts twice as much pore water as previously thought, significantly raising the flux of fluid to the seismogenic zone and the mantle wedge.

Internal tectonic structure of the Central American Wadati-Benioff zone based on analysis of aftershock sequences

NASA Astrophysics Data System (ADS)

Å PičáK, Aleš; Hanuš, VáClav; VaněK, JiřÃ.­; BěHounková, Marie

2007-09-01

Relocated Engdahl et al. (1998) global seismological data for 10 aftershock sequences were used to analyze the internal tectonic structure of the Central American subduction zone; the main shocks of several of these were the most destructive and often referenced earthquakes in the region (e.g., the 1970 Chiapas, 1983 Osa, 1992 Nicaragua, 1999 Quepos, 2001 El Salvador earthquakes). The spatial analysis of aftershock foci distribution was performed in a rotated Cartesian coordinate system (x, y, z) related to the Wadati-Benioff zone, and not in a standard coordinate system (ϕ, λ, h are latitude, longitude, focal depth, respectively). Available fault plane solutions were also transformed into the plane approximating the Wadati-Benioff zone. The spatial distribution of earthquakes in each aftershock sequence was modeled as either a plane fit using a least squares approximation or a volume fit with a minimum thickness rectangular box. The analysis points to a quasi-planar distribution of earthquake foci in all aftershock sequences, manifesting the appurtenance of aftershocks to fracture zones. Geometrical parameters of fracture zones (strike, dip, and dimensions) hosting individual sequences were calculated and compared with the seafloor morphology of the Cocos Plate. The smooth character of the seafloor correlates with the aftershock fracture zones oriented parallel to the trench and commonly subparallel to the subducting slab, whereas subduction of the Cocos Ridge and seamounts around the Quepos Plateau coincides with steeply dipping fracture zones. Transformed focal mechanisms are almost exclusively (>90%) of normal character.

Internal tectonic structure of the Central American Wadati-Benioff zone based on analysis of aftershock sequences

NASA Astrophysics Data System (ADS)

Špičák, Aleš; Hanuš, Václav; Vaněk, Jiří; Běhounková, Marie

2007-09-01

Relocated Engdahl et al. (1998) global seismological data for 10 aftershock sequences were used to analyze the internal tectonic structure of the Central American subduction zone; the main shocks of several of these were the most destructive and often referenced earthquakes in the region (e.g., the 1970 Chiapas, 1983 Osa, 1992 Nicaragua, 1999 Quepos, 2001 El Salvador earthquakes). The spatial analysis of aftershock foci distribution was performed in a rotated Cartesian coordinate system (x, y, z) related to the Wadati-Benioff zone, and not in a standard coordinate system ($\\varphi$, λ, h are latitude, longitude, focal depth, respectively). Available fault plane solutions were also transformed into the plane approximating the Wadati-Benioff zone. The spatial distribution of earthquakes in each aftershock sequence was modeled as either a plane fit using a least squares approximation or a volume fit with a minimum thickness rectangular box. The analysis points to a quasi-planar distribution of earthquake foci in all aftershock sequences, manifesting the appurtenance of aftershocks to fracture zones. Geometrical parameters of fracture zones (strike, dip, and dimensions) hosting individual sequences were calculated and compared with the seafloor morphology of the Cocos Plate. The smooth character of the seafloor correlates with the aftershock fracture zones oriented parallel to the trench and commonly subparallel to the subducting slab, whereas subduction of the Cocos Ridge and seamounts around the Quepos Plateau coincides with steeply dipping fracture zones. Transformed focal mechanisms are almost exclusively (>90%) of normal character.

[Research on early fire detection with CO-CO2 FTIR-spectroscopy].

PubMed

Du, Jian-hua; Zhang, Ren-cheng; Huang, Xiang-ying; Gong, Xue; Zhang, Xiao-hua

2007-05-01

A new fire detection method is put forward based on the theory of FTIR spectroscopy through analyzing all kinds of detection methods, in which CO and CO2 are chosen as early fire detection objects, and an early fire experiment system has been set up. The concentration characters of CO and CO2 were obtained through early fire experiments including real alarm sources and nuisance alarm sources. In real alarm sources there are abundant CO and CO2 which change regularly. In nuisance alarm sources there is almost no CO. So it's feasible to reduce the false alarms and increase the sensitivity of early fire detectors through analyzing the concentration characters of CO and CO2.

Cryopreservation by encapsulation-dehydration of plumules of coconut (Cocos nucifera L.).

PubMed

N'Nan, Oulo; Hocher, Valérie; Verdeil, Jean-Luc; Konan, Jean-Louis; Ballo, Koffi; Mondeil, Fanja; Malaurie, Bernard

2008-01-01

This study describes the use of an encapsulation-dehydration cryopreservation technique on coconut plumules (apical dome with three or four leaf primordia) excised from embryos. In order to establish a reliable cryopreservation process for plumules, several different key factors were tested: pretreatment duration, sugar concentration, dehydration period and freezing. In parallel, histological studies were performed to describe the structural changes of tissues and plumule cells subjected to dehydration and freezing. A good survival level of around 60% was obtained. However, after 8 months culture regrowth, this level decreased to a maximum of 20 % which was achieved using sucrose treatment. In this paper we report for the first time the regeneration of leafy shoots from coconut plumules after cryopreservation.

Structural characterization of lignin isolated from coconut (Cocos nucifera) coir fibers.

PubMed

Rencoret, Jorge; Ralph, John; Marques, Gisela; Gutiérrez, Ana; Martínez, Ángel T; del Río, José C

2013-03-13

The structure of the isolated milled "wood" lignin from coconut coir has been characterized using different analytical methods, including Py-GC/MS, 2D NMR, DFRC, and thioacidolysis. The analyses demonstrated that it is a p-hydroxyphenyl-guaiacyl-syringyl (H-G-S) lignin, with a predominance of G units (S/G ratio 0.23) and considerable amounts of associated p-hydroxybenzoates. Two-dimensional NMR indicated that the main substructures present in this lignin include β-O-4' alkyl aryl ethers followed by phenylcoumarans and resinols. Two-dimensional NMR spectra also indicated that coir lignin is partially acylated at the γ-carbon of the side chain with p-hydroxybenzoates and acetates. DFRC analysis showed that acetates preferentially acylate the γ-OH in S rather than in G units. Despite coir lignin's being highly enriched in G-units, thioacidolysis indicated that β-β' resinol structures are mostly derived from sinapyl alcohol. Finally, we find evidence that the flavone tricin is incorporated into the coconut coir lignin, as has been recently noted for various grasses.

Correlation between oxalic acid production and copper tolerance in Wolfiporia cocos

Treesearch

C. A. Clausen; Frederick Green; B. M. Woodward; J. W. Evans; R. C. DeGroot

2000-01-01

The increased interest in copper-based wood preservatives has hastened the need for understanding why some fungi are able to attack copper-treated wood. Due in part to accumulation of oxalic acid by brown-rot fungi and visualization of copper oxalate crystals in wood decayed by known copper-tolerant decay fungi, oxalic acid has been implicated in copper tolerance by...

National Defense Budget Estimates for FY

DTIC Science & Technology

1993-05-01

funding" policy . Under full funding, Congress approves, in the year of the request, sufficient funds to complete a given quantity of items, even though...the proposed level of general transfer authority, and a technical outlay adjustment to properly reflect the Administration’s pay policies . 16 SCO...rg O) oo OO *-< coco •r-» CD cncD CD CM CO CD CD *4 in *•* o o f-t CM O r- CM CM O CM ao CM ^ in CO CM CD CM r-. co CM r- co

Prime Contract Awards Alphabetically by Contractor, by State or Country, and Place, Fiscal Year 1987. Part 6. Donnegan Systems, Incorporated-Fairfield Machine Company, Incorporated.

DTIC Science & Technology

1987-01-01

go- 0 00 0C0 C 00 000 00 0 10 CC I M .COCO Z- - - r-F P- -- rI , zt zt ,r - z - z - - I-- Zol I MOOC I,4-~- CON-00N <C 0-4 00- 4 00 <o C4-4-- 00040-4...InI 1 - In I- P. - --f- 1( ar - -r 1 P rf- -QvQv0vf- - - 0L I W I (AO MOOC Ll 70 CAC co V)00 0 n 0 0120000CO0 (10000 V) 00 0 (.12 00 0 0000

Oxidation-Reduction Resistance of Advanced Copper Alloys

NASA Technical Reports Server (NTRS)

Greenbauer-Seng, L. (Technical Monitor); Thomas-Ogbuji, L.; Humphrey, D. L.; Setlock, J. A.

2003-01-01

Resistance to oxidation and blanching is a key issue for advanced copper alloys under development for NASA's next generation of reusable launch vehicles. Candidate alloys, including dispersion-strengthened Cu-Cr-Nb, solution-strengthened Cu-Ag-Zr, and ODS Cu-Al2O3, are being evaluated for oxidation resistance by static TGA exposures in low-p(O2) and cyclic oxidation in air, and by cyclic oxidation-reduction exposures (using air for oxidation and CO/CO2 or H2/Ar for reduction) to simulate expected service environments. The test protocol and results are presented.

A Palladium Iodide-Catalyzed Cyclocarbonylation Approach to Thiadiazafluorenones.

PubMed

Veltri, Lucia; Paladino, Veronica; Plastina, Pierluigi; Gabriele, Bartolo

2016-07-15

The first example of an additive cyclocarbonylation process leading to 1-thia-4a,9-diazafluoren-4-ones is reported. This process is based on the reaction of readily available 2-(propynylthio)benzimidazoles with carbon monoxide carried out in EtOH at 100 °C under a 5/2 mixture of CO-CO2 at 70 atm in the presence of the PdI2/KI catalytic system. Experimental evidence suggests a mechanistic pathway involving N-palladation of the substrate followed by CO insertion, triple bond insertion, protonolysis, and isomerization.

Optimizing Hemodynamic Support of Acute Spinal Cord Injury Based on Injury Mechanism

DTIC Science & Technology

2016-10-01

lnJury Specifics Force Weig Tre.tment Notes ht (k&) 8178 Andrew the Giant Yucatan 1-Apr-16 2585.52 25.0 CNTR PILOTTING: unst1ble MAP 8177 Brett...Hart Yucatan 6-Apr-16 3210.77 26.0 CNTR MAP inf11sion: 8202 Coco B. Ware Yucatan 24-Apr-16 2967.00 26.5 NEQJmp(30 min) 60-min Norepinephrine 20...mmHg above BSL 8192 Diamond D. Page Yucatan 27-Apr-16 3609.00 25.0 CNTR 8179 Edge Yucatan 3-May-16 Contusion: 3423.00 26.0 CNTR Groups: - CNTR: no

The Impact of the Demonstration Project on Managers at the Naval Weapons Center, China Lake.

DTIC Science & Technology

1983-06-01

MO» OCi too» (NW H 10 s o m H 10 M ~J «8 M O w cu to z «S H o (-I z s o w H ZU JCi « SH MO OH U 04 10 z O t...SO OiZ IT’-" CO-4 COCO uu cro TM rr .3- m ^o r» CO O"* o"~ (V <* 131 uuu OSMCO ItiQH as>«a a: co a, ^s Wrtce "-ITHZ «63 .1 CM

(Carbonato-κO,O')bis-(1,10-phenan-throline-κN,N')cobalt(III) nitrate monohydrate.

PubMed

Andaç, Omer; Yolcu, Zuhal; Büyükgüngör, Orhan

2009-12-12

The crystal structure of the title compound, [Co(CO(3))(C(12)H(8)N(2))(2)]NO(3)·H(2)O, consists of Co(III) complex cations, nitrate anions and uncoordinated water mol-ecules. The Co(III) cation is chelated by a carbonate anion and two phenanthroline ligands in a distorted octa-hedral coordination geometry. A three-dimensional supra-molecular structure is formed by O-H⋯O and C-H⋯O hydrogen bonding, C-H⋯π and aromatic π-π stacking [centroid-centroid distance = 3.995 (1)Å] inter-actions.

In vitro efficacy of five essential oils against Pediculus humanus capitis.

PubMed

Candy, Kerdalidec; Nicolas, Patrick; Andriantsoanirina, Valérie; Izri, Arezki; Durand, Rémy

2018-02-01

Treatment of head lice has relied mainly on the use of topical insecticides. Today, conventional topical pediculicides have suffered considerable loss of activity worldwide. There is increasing interest in the use of natural products such as essential oils for head louse control, and many of them are now incorporated into various over-the-counter products presented as pediculicides, often without proper evaluation. The aim of the present study was to assess the in vitro efficacy of five essential oils against adults of Pediculus humanus capitis using a contact filter paper toxicity bioassay. The chemical composition of the essential oils from wild bergamot, clove, lavender, tea tree, and Yunnan verbena was analyzed by gas chromatography-mass spectrometry. All treatments and controls were replicated three times on separate occasions over a period of 11 months. In all, 1239 living lice were collected from the scalp of 51 subjects, aged from 1 to 69 years. Clove oil, diluted either in coco oil or sunflower oil, demonstrated the best adulticidal activity, reaching > 90% mortality within 2 h in lice submitted to a 30-min contact. Yunnan verbena oil diluted in coco oil showed also a significant efficacy. Other essential oils showed a lower efficacy. The oil's major component(s) differed according to the tested oils and appeared chemically diverse. In the case of clove oil, the eugenol appeared as the main component. This study confirmed the potential interest of some of the essential oils tested, but not all, as products to include possibly in a pediculicidal formulation.

The Origin of Widespread Long-lived Volcanism Across the Galapagos Volcanic Province

NASA Astrophysics Data System (ADS)

O'Connor, J. M.; Stoffers, P.; Wijbrans, J. R.; Worthington, T. J.

2005-12-01

40Ar/39Ar ages for rocks dredged (SO144 PAGANINI expedition) and drilled (DSDP) from the Galapagos Volcanic Province (Cocos, Carnegie, Coiba and Malpelo aseismic ridges and associated seamounts) show evidence of 1) increasing age with distance from the Galapagos Archipelago, 2) long-lived episodic volcanism at many locations, and 3) broad overlapping regions of coeval volcanism. The widespread nature of synchronous volcanism across the Galapagos Volcanic Province (GVP) suggests a correspondingly large Galapagos hotspot melting anomaly (O'Connor et al., 2004). Development of the GVP via Cocos and Nazca plate migration and divergence over this broad melting anomaly would explain continued multiple phases of volcanism over millions of years following the initial onset of hotspot volcanism. The question arising from these observations is whether long-lived GVP episodic volcanism is equivalent to `rejuvenescent' or a `post-erosional' phase of volcanism that occurs hundreds of thousands or million years after the main shield-building phase documented on many mid-plate seamount chains, most notably along the Hawaiian-Emperor Seamount Chain? Thus, investigating the process responsible for long-lived episodic GVP volcanism provides the opportunity to evaluate this little understood process of rejuvenation in a physical setting very different to the Hawaiian-Emperor Chain (i.e. on/near spreading axis versus mid-plate). We consider here timing and geochemical information to test the various geodynamic models proposed to explain the origin of GVP hotspot volcanism, especially the possibility of rejuvenated phases that erupt long after initial shield-building.

DOE Office of Scientific and Technical Information (OSTI.GOV)

McNally, K.C.; Minster, J.B.

Revised estimates of seismic slip rates along the Middle America Trench are lower on the average than plate convergence rates but match them locally (for example, Oaxaca). Along the Cocos-North American plate boundary this can be explained by nonuniformities in slip at points of aseismic ridge or fracture zone subduction. For at least 81 yr (and possibly several hundred years), no major (M/sub s/> or =7.5) shallow earthquake is known to have occurred near the Orozco Fracture Zone and Tehuantepec Ridge areas. Compared with the average recurrence periods for large earthquakes (33 +- 8 yr since 1898 and 35 +-more » 24 yr between 1542 and 1979), this suggests that either a large (M> or =8.4) event may be anticipated at such locations, or that these are points of aseismic subduction. Large coastal terraces and evidence suggesting tectonic uplift are found onshore near the Orozco Fracture zone. The larger discrepancy between plate convergence and seismic slip rates along the Cocos-Carribbean plate boundary is more likely due to decoupling and downbending of the subducted plate. We used the limited statistical evidence available to characterize both spatial and temporal deficiencies in recent seismic slip. The observations appear consistent with a possible forthcoming episode of more intense seismic activity. Based on a series of comparisons with carefully delineated aftershock zones, we conclude that the zones of anomalous seismic activity can be indentified by a systematic, automated analysis of the worldwide earthquake catalog (m/sub b/> or =4).« less

A role for PPARα in the regulation of arginine metabolism and nitric oxide synthesis.

PubMed

Guelzim, Najoua; Mariotti, François; Martin, Pascal G P; Lasserre, Frédéric; Pineau, Thierry; Hermier, Dominique

2011-10-01

The pleiotropic effects of PPARα may include the regulation of amino acid metabolism. Nitric oxide (NO) is a key player in vascular homeostasis. NO synthesis may be jeopardized by a differential channeling of arginine toward urea (via arginase) versus NO (via NO synthase, NOS). This was studied in wild-type (WT) and PPARα-null (KO) mice fed diets containing either saturated fatty acids (COCO diet) or 18:3 n-3 (LIN diet). Metabolic markers of arginine metabolism were assayed in urine and plasma. mRNA levels of arginases and NOS were determined in liver. Whole-body NO synthesis and the conversion of systemic arginine into urea were assessed by using (15)N(2)-guanido-arginine and measuring urinary (15)NO(3) and [(15)N]-urea. PPARα deficiency resulted in a markedly lower whole-body NO synthesis, whereas the conversion of systemic arginine into urea remained unaffected. PPARα deficiency also increased plasma arginine and decreased citrulline concentration in plasma. These changes could not be ascribed to a direct effect on hepatic target genes, since NOS mRNA levels were unaffected, and arginase mRNA levels decreased in KO mice. Despite the low level in the diet, the nature of the fatty acids modulated some effects of PPARα deficiency, including plasma arginine and urea, which increased more in KO mice fed the LIN diet than in those fed the COCO diet. In conclusion, PPARα is largely involved in normal whole-body NO synthesis. This warrants further study on the potential of PPARα activation to maintain NO synthesis in the initiation of the metabolic syndrome.

Active strike-slip faulting in El Salvador, Central America

NASA Astrophysics Data System (ADS)

Corti, Giacomo; Carminati, Eugenio; Mazzarini, Francesco; Oziel Garcia, Marvyn

2005-12-01

Several major earthquakes have affected El Salvador, Central America, during the Past 100 yr as a consequence of oblique subduction of the Cocos plate under the Caribbean plate, which is partitioned between trench-orthogonal compression and strike-slip deformation parallel to the volcanic arc. Focal mechanisms and the distribution of the most destructive earthquakes, together with geomorphologic evidence, suggest that this transcurrent component of motion may be accommodated by a major strike-slip fault (El Salvador fault zone). We present field geological, structural, and geomorphological data collected in central El Salvador that allow the constraint of the kinematics and the Quaternary activity of this major seismogenic strike-slip fault system. Data suggest that the El Salvador fault zone consists of at least two main ˜E-W fault segments (San Vicente and Berlin segments), with associated secondary synthetic (WNW-ESE) and antithetic (NNW-SSE) Riedel shears and NW-SE tensional structures. The two main fault segments overlap in a dextral en echelon style with the formation of an intervening pull-apart basin. Our original geological and geomorphologic data suggest a late Pleistocene Holocene slip rate of ˜11 mm/yr along the Berlin segment, in contrast with low historical seismicity. The kinematics and rates of deformation suggested by our new data are consistent with models involving slip partitioning during oblique subduction, and support the notion that a trench-parallel component of motion between the Caribbean and Cocos plates is concentrated along E-W dextral strike-slip faults parallel to the volcanic arc.

A fuzzy goal programming model for biodiesel production

NASA Astrophysics Data System (ADS)

Lutero, D. S.; Pangue, EMU; Tubay, J. M.; Lubag, S. P.

2016-02-01

A fuzzy goal programming (FGP) model for biodiesel production in the Philippines was formulated with Coconut (Cocos nucifera) and Jatropha (Jatropha curcas) as sources of biodiesel. Objectives were maximization of feedstock production and overall revenue and, minimization of energy used in production and working capital for farming subject to biodiesel and non-biodiesel requirements, and availability of land, labor, water and machine time. All these objectives and constraints were assumed to be fuzzy. Model was tested for different sets of weights. Results for all sets of weights showed the same optimal allocation. Coconut alone can satisfy the biodiesel requirement of 2% per volume.

Effects of different levels of coconut fiber on blood glucose, serum insulin and minerals in rats.

PubMed

Sindurani, J A; Rajamohan, T

2000-01-01

The effect of neutral detergent fiber (NDF) from coconut kernel (Cocos nucifera L) in rats fed 5%, 15% and 30% level on the concentration of blood glucose, serum insulin and excretion of minerals was studied. Increase in the intake of fiber resulted in significant decrease in the level of blood glucose and serum insulin. Faecal excretion of Cu, Cr, Mn, Mg, Zn and Ca was found to increase in rats fed different levels of coconut fiber when compared to fiber free group. The result of the present investigation suggest that inclusion of coconut fiber in the diet results in significant hypoglycemic action.

The kinetics of ulvoespinel reduction - Synthetic study and applications to lunar rocks.

NASA Technical Reports Server (NTRS)

Mccallister, R. H.; Taylor, L. A.

1973-01-01

The kinetics of Fe2TiO4 reduction to FeTiO3 + Fe were studied using CO-CO2 gas mixtures with fO2 measured by a solid ceramic (calcia-zirconia) oxygen electrolyte cell. Isothermal rate studies at 900 C suggest that the mechanism of Fe2TiO4 reduction is one of nucleation and growth, where the growth stage may be controlled by the diffusion of the reactant through the product layer or volume diffusion. The activation energy for the growth stage of the process was determined to be 46 plus or minus 4 kcal/mole.

Index to Watervliet Arsenal Technical Reports, 1973

DTIC Science & Technology

1973-09-01

T-2-46-73 RS4---07 SU8JECT I~p steel cont. Temeratuzre M-WV-T-1-25-73 R-W-T-l8-73 R-VT64-3 R-W-T-1-53-73 R-IP-T-6-3-73 Tensile Propertiss H-WVT-6-9...unlimited. U. S. Army Weapons Command Corrosion of" high strength steel in gaseous environment is largely divided in IrcLa, high temperature oxidation...and stress corrosion cracking at lower t ,, ;i - tru,. Ili 1 h temperature oxidation of the 4330 steel was conducted in CO-CO, ml res ii: to 1300.%. The

(Carbonato-κ2 O,O′)bis­(1,10-phenan­throline-κ2 N,N′)cobalt(III) nitrate monohydrate

PubMed Central

Andaç, Ömer; Yolcu, Zuhal; Büyükgüngör, Orhan

2010-01-01

The crystal structure of the title compound, [Co(CO3)(C12H8N2)2]NO3·H2O, consists of CoIII complex cations, nitrate anions and uncoordinated water mol­ecules. The CoIII cation is chelated by a carbonate anion and two phenanthroline ligands in a distorted octa­hedral coordination geometry. A three-dimensional supra­molecular structure is formed by O—H⋯O and C—H⋯O hydrogen bonding, C—H⋯π and aromatic π–π stacking [centroid–centroid distance = 3.995 (1)Å] inter­actions. PMID:21579944

Grain Size Biasing of 230Th-derived Focusing Factors in the Panama Basin

NASA Astrophysics Data System (ADS)

Loveley, M. R.; Marcantonio, F.; Lyle, M. W.; Ibrahim, R.; Wang, J. K.; Hertzberg, J. E.

2014-12-01

In this study, we attempt to understand how differing grain size classes in Panama Basin sediments may create biasing of 230Th as a constant-flux proxy. Greater amounts of 230Th are contained in fine grained particles, which, if fractionated from coarser grained counterparts may lead to biasing of 230Th-derived mass accumulation rates (MARs) and sediment focusing factors. We examined sediments that span the past 25 kyr from four new sediment cores retrieved from two different localities close to the ridges that bound the Panama Basin. Each locality contained paired sites that were seismically interpreted to have undergone sediment redistribution, i.e., thick focused sites versus thin winnowed sites. Two sediment cores were retrieved from the northern part of the Panama basin, Cocos Ridge, (MV1014-01-"4JC", 5° 44.7'N 85° 45.5' W, 1730 m depth; MV1014-01-"8JC", 6° 14.0'N 86° 2.6' W, 1993 m depth), and two were retrieved from the southern part of the basin, Carnegie Ridge, (MV1014-02-"11JC", 0° 41.6'S 85° 20.0' W, 2452 m depth; MV1014-02-"17JC" 0° 10.8'S 85° 52.0' W, 2846 m depth). Cores 4JC and 11JC lie closer to the ridge tops of the Cocos and Carnegie Ridges, respectively, and have thin sediment drapes, while deeper cores, 8JC (Cocos) and 17JC (Carnegie), have thicker sediment drapes and lie downslope from the ridge top cores. Age-model-derived sand MARs, which likely represent the vertical rain of particles that cannot be transported by bottom currents, are similar at each of the paired sites in Holocene and glacial time slices. However, 230Th-normalized MARs are about 50% lower, on average at each of the paired sites during the same time slices. Both Holocene and glacial samples from "thin" cores (4,11JC) contain, surprisingly, significant amounts (up to 50%) of the 230Th within the coarse grained (>63 μm) fraction which makes up 40-70% of the bulk samples analyzed. On the contrary, Holocene and glacial samples from "thick" cores, (8,17JC), contain the

Emissions of mercury in southern Africa derived from long-term observations at Cape Point, South Africa

NASA Astrophysics Data System (ADS)

Brunke, E.-G.; Ebinghaus, R.; Kock, H. H.; Labuschagne, C.; Slemr, F.

2012-08-01

Mercury emissions in South Africa have so far been estimated only by a bottom-up approach from activities and emission factors for different processes. In this paper we derive GEM/CO (GEM being gaseous elemental mercury, Hg0), GEM/CO2, GEM/CH4, CO/CO2, CH4/CO2, and CH4/CO emission ratios from plumes observed during long-term monitoring of these species at Cape Point between March 2007 and December 2009. The average observed GEM/CO, GEM/CO2, GEM/CH4, CO/CO2, CH4/CO2, and CH4/CO emission ratios were 2.40 ± 2.65 pg m-3 ppb-1 (n = 47), 62.7 ± 80.2 pg m-3 ppm-1 (n = 44), 3.61 ± 4.66 pg m-3 ppb-1 (n = 46), 35.6 ± 25.4 ppb ppm-1 (n = 52), 20.2 ± 15.5 ppb ppm-1 (n = 48), and 0.876 ± 1.106 ppb ppb-1 (n = 42), respectively. The observed CO/CO2, CH4/CO2, and CH4/CO emission ratios agree within the combined uncertainties of the observations and emissions with the ratios calculated from EDGAR (version 4.2) CO2, CO, and CH4 inventories for South Africa and southern Africa (South Africa, Lesotho, Swaziland, Namibia, Botswana, Zimbabwe, and Mozambique) in 2007 and 2008 (inventories for 2009 are not available yet). Total elemental mercury emission of 13.1, 15.2, and 16.1 t Hg yr-1 are estimated independently using the GEM/CO, GEM/CO2, and GEM/CH4 emission ratios and the annual mean CO, CO2, and CH4 emissions, respectively, of South Africa in 2007 and 2008. The average of these independent estimates of 14.8 t GEM yr-1 is much less than the total emission of 257 t Hg yr-1 shown by older inventories which are now considered to be wrong. Considering the uncertainties of our emission estimate, of the emission inventories, and the fact that emission of GEM represents 50-78 % of all mercury emissions, our estimate is comparable to the currently cited GEM emissions in 2004 and somewhat smaller than emissions in 2006. A further increase of mercury emissions due to increasing electricity consumption will lead to a more pronounced difference. A quantitative assessment of the difference

Method comparisons of vehicle emissions measurements in the fort mchenry and Tuscarora mountain tunnels

NASA Astrophysics Data System (ADS)

Bishop, Gary A.; McLaren, Scott E.; Stedman, Donald H.; Pierson, William R.; Zweidinger, Roy B.; Ray, William D.

Experiments were conducted in the Fort McHenry Tunnel in Baltimore, MD, and in the Tuscarora Mountain Tunnel in Pennsylvania, during the summer of 1992 to evaluate real-world automotive emissions. Included in these experiments were the first reported measurements of individual vehicle exhaust in tunnels by a remote sensing device (RSD). Results are compared to integrated emission measurements carried out by analysis of concurrent collections of tunnel air into bags, canisters, and adsorbent traps and by conventional Fourier transform infrared (FTIR) spectroscopy. The vehicles using these highway tunnels proved to be lower emitting than vehicles usually measured by remote sensing in urban areas. At Fort McHenry the RSD-measured CO/CO2 ratios were, on average, high compared to either the bag or FTIR measurements (by a factor of 1.4 ± 0.2) for the four runs monitored. RSD hydrocarbon data were obtained only at the uphill location ( + 3.76% grade). RSD HC/CO2 ratios were lower on average, but statistically indistinguishable when compared with either the FTIR or the integrated uphill measurements. At Tuscarora, the RSD-measured CO/CO2 ratios were in agreement with the CO/CO2 ratios in the tunnel bag measurements and FTIR measurements (within a factor of 1.00 ± 0.16 by one method and 0.82 ± 0.32 by a second, when traffic was dominated by light-duty spark-ignition vehicles). The RSD HC/CO2 ratios were, however, higher than the light-duty vehicle estimates from the integrated (bag/canister/Tenax) tunnel measurements by a factor of 3, and higher than the FTIR Δ HC/Δ CO2 ratios by an even higher factor, mostly owing to water vapor interferences in the low average RSD measurements. For the first time RSD measurements were collected from a small sample of heavy-duty diesels; comparisons to the heavy-duty emissions contributions for CO and HC were favorable. Analysis of emissions data for vehicle variability at Fort McHenry revealed that low CO emitting vehicles tended to

Authigenic Uranium in Eastern Equatorial Pacific Sediments

NASA Astrophysics Data System (ADS)

Marcantonio, F.; Lyle, M. W.; Loveley, M. R.; Ibrahim, R.

2014-12-01

Authigenic U concentrations have been used as an indicator of redox state in marine sediments. Soluble U(VI) in porewaters is reduced to insoluble U(IV) under suboxic conditions setting up a diffusion gradient through which U in bottom waters is supplied to reducing sediments. Researchers have used sedimentary redox enrichment of U as a tool to identify past redox changes, which may be caused by changes in organic carbon rain rates and/or bottom water oxygen levels. Differentiating between these two explanations is important, as the former is tied to the use of authigenic U as a paleoproductivity proxy. We examined sediments from 4 sediment cores retrieved from two different localities in the Panama Basin in the eastern equatorial Pacific. Two cores were retrieved from the northern Panama basin at the Cocos Ridge, (4JC at 5° 44.7'N 85° 45.5' W, 1730 m depth; 8JC at 6° 14.0'N 86° 2.6' W, 1993 m depth), and two were retrieved from the south at the Carnegie Ridge, (11JC at 0° 41.6'S 85° 20.0' W, 2452 m depth; 17JC at 0° 10.8'S 85° 52.0' W, 2846 m depth). Using 230Th systematics and seismic profiling at each of the sites, we've identified significant sediment winnowing (4JC and 11JC) and focusing (8JC and 17JC). At all sites, we believe that changes in age-model-derived sand (i.e., >63µm) mass accumulation rates (MAR) best represent changes in rain rates. Glacial rain rates are higher than those in the Holocene by a factor of 2-3 at both sites. Peak Mn levels (>1%), the brown-to-green color transition (which likely represents the oxic/post-oxic boundary), and peak U concentrations all appear in the same order with increasing depth down core. At the Carnegie sites, where MARs are greater than those at the Cocos sites, increases in authigenic U (up to 4 ppm) occur during the mid- to late Holocene at depths of 10-15 cm. At the Cocos sites, increases in authigenic U (up to 12 ppm) occur lower in the sediment column (25-30 cm) during the late glacial. The decrease

Population structures of Brazilian tall coconut (Cocos nucifera L.) by microsatellite markers

PubMed Central

2010-01-01

Coconut palms of the Tall group were introduced to Brazil from the Cape Verde Islands in 1553. The present study sought to evaluate the genetic diversity among and within Brazilian Tall coconut populations. Samples were collected of 195 trees from 10 populations. Genetic diversity was accessed by investigating 13 simple sequence repeats (SSR) loci. This provided a total of 68 alleles, ranging from 2 to 13 alleles per locus, with an average of 5.23. The mean values of gene diversity (He ) and observed heterozygosity (Ho ) were 0.459 and 0.443, respectively. The genetic differentiation among populations was estimated at θ^P=0.1600and the estimated apparent outcrossing rate was ta = 0.92. Estimates of genetic distances between the populations varied from 0.034 to 0.390. Genetic distance and the corresponding clustering analysis indicate the formation of two groups. The first consists of the Baía Formosa, Georgino Avelino, and São José do Mipibu populations and the second consists of the Japoatã, Pacatuba, and Praia do Forte populations. The correlation matrix between genetic and geographic distances was positive and significant at a 1% probability. Taken together, our results suggest a spatial structuring of the genetic variability among the populations. Geographically closer populations exhibited greater similarities. PMID:21637579

The chemical composition and biological properties of coconut (Cocos nucifera L.) water.

PubMed

Yong, Jean W H; Ge, Liya; Ng, Yan Fei; Tan, Swee Ngin

2009-12-09

Coconut water (coconut liquid endosperm), with its many applications, is one of the world's most versatile natural product. This refreshing beverage is consumed worldwide as it is nutritious and beneficial for health. There is increasing scientific evidence that supports the role of coconut water in health and medicinal applications. Coconut water is traditionally used as a growth supplement in plant tissue culture/micropropagation. The wide applications of coconut water can be justified by its unique chemical composition of sugars, vitamins, minerals, amino acids and phytohormones. This review attempts to summarise and evaluate the chemical composition and biological properties of coconut water.

Density structure and geometry of the Costa Rican subduction zone from 3-D gravity modeling and local earthquake data

NASA Astrophysics Data System (ADS)

Lücke, O. H.; Arroyo, I. G.

2015-07-01

The eastern part of the oceanic Cocos Plate presents a heterogeneous crustal structure due to diverse origins and ages as well as plate-hot spot interactions which originated the Cocos Ridge, a structure that converges with the Caribbean Plate in southeastern Costa Rica. The complex structure of the oceanic plate directly influences the dynamics and geometry of the subduction zone along the Middle American Trench. In this paper an integrated interpretation of the slab geometry is presented based on three-dimensional density modeling of combined satellite and surface gravity data, constrained by available geophysical and geological data and seismological information obtained from local networks. The results show the continuation of steep subduction geometry from the Nicaraguan margin into Northwestern Costa Rica, followed by a moderate dipping slab under the Central Cordillera toward the end of the Central American Volcanic Arc. To the southeast end of the volcanic arc, our preferred model shows a steep, coherent slab that extends up to the landward projection of the Panama Fracture Zone. Overall, a gradual change in the depth of the intraplate seismicity is observed, reaching 220 km in the northwestern part, and becoming progressively shallower toward the southeast, where it reaches a terminal depth of 75 km. The changes in the terminal depth of the observed seismicity correlate with the increased density in the modeled slab. The absence of intermediate depth intraplate seismicity in the southeastern section and the higher densities for the subducted slab in this area, support a model in which dehydration reactions in the subducted slab cease at a shallower depth, originating an anhydrous and thus aseismic slab.

Density structure and geometry of the Costa Rican subduction zone from 3-D gravity modeling and local earthquake data

NASA Astrophysics Data System (ADS)

Lücke, O. H.; Arroyo, I. G.

2015-10-01

The eastern part of the oceanic Cocos Plate presents a heterogeneous crustal structure due to diverse origins and ages as well as plate-hot spot interactions which originated the Cocos Ridge, a structure that converges with the Caribbean Plate in southeastern Costa Rica. The complex structure of the oceanic plate directly influences the dynamics and geometry of the subduction zone along the Middle American Trench. In this paper an integrated interpretation of the slab geometry in Costa Rica is presented based on 3-D density modeling of combined satellite and surface gravity data, constrained by available geophysical and geological data and seismological information obtained from local networks. The results show the continuation of steep subduction geometry from the Nicaraguan margin into northwestern Costa Rica, followed by a moderate dipping slab under the Central Cordillera toward the end of the Central American Volcanic Arc. Contrary to commonly assumed, to the southeast end of the volcanic arc, our preferred model shows a steep, coherent slab that extends up to the landward projection of the Panama Fracture Zone. Overall, a gradual change in the depth of the intraplate seismicity is observed, reaching 220 km in the northwestern part, and becoming progressively shallower toward the southeast, where it reaches a maximum depth of 75 km. The changes in the terminal depth of the observed seismicity correlate with the increased density in the modeled slab. The absence of intermediate depth (> 75 km) intraplate seismicity in the southeastern section and the higher densities for the subducted slab in this area, support a model in which dehydration reactions in the subducted slab cease at a shallower depth, originating an anhydrous and thus aseismic slab.

Rapid detection of aflatoxin B1 in medicinal materials of radix and rhizome by gold immunochromatographic assay.

PubMed

Hu, Shurong; Dou, Xiaowen; Zhang, Lei; Xie, Yanjun; Yang, Shihai; Yang, Meihua

2018-05-22

A rapid screening of the most toxic aflatoxin B 1 (AFB 1 ) in medicinal materials of radix and rhizome was performed by an immune chromatography method for the first time. The colloidal gold immunochromatographic strip was prepared after optimization of the conjugation of gold particles with monoclonal antibody, the test line and the control line. Under optimized conditions, the detection limit of the constructed test strip was as low as 0.1 ng mL -1 and the total analysis was conducted within 15 min by naked eyes. Four kinds of medicinal materials (Gastrodia elata, Poria cocos, Bletilla striata and Radix Angelicae Dahuricae) were investigated by the strip. Various complex matrixes pay a significant influence on the feasibility and effectiveness of the strip screening in medicinal materials. Aiming to the characteristics of selected medicinal materials, the screening was successfully proceeded with extraction by 70% methanol-water as well as three-fold dilution in Gastrodia elata and Radix Angelicae Dahuricae, 70% methanol-PBS as well as four-fold dilution in Poria cocos., and 60% methanol-water as well as four-fold dilution in Bletilla striata. Among the collected 40 samples, one was found to be positive of AFB 1 with level above 5 μg kg -1 . The result was in a good agreement with those obtained from LC-MS/MS determination (6.12 μg kg -1 ). The gold immunochromatographic strip was demonstrated as a rapid, cost-effective, reliable and on-site screening technique for mycotoxins in starch and polysaccharides-rich herbal medicines. Copyright © 2018 Elsevier Ltd. All rights reserved.

Mechanism of phosphorus passivation of near-interface oxide traps in 4H–SiC MOS devices investigated by CCDLTS and DFT calculation

NASA Astrophysics Data System (ADS)

Jayawardena, Asanka; Shen, X.; Mooney, P. M.; Dhar, Sarit

2018-06-01

Interfacial charge trapping in 4H–SiC MOS capacitors with P doped SiO2 or phospho-silicate glass (PSG) as a gate dielectric has been investigated with temperature dependent capacitance–voltage measurements and constant capacitance deep level transient spectroscopy (CCDLTS) measurements. The measurements indicate that P doping in the dielectric results in significant reduction of near-interface electron traps that have energy levels within 0.5 eV of the 4H–SiC conduction band edge. Extracted trap densities confirm that the phosphorus induced near-interface trap reduction is significantly more effective than interfacial nitridation, which is typically used for 4H–SiC MOSFET processing. The CCDLTS measurements reveal that the two broad near-interface trap peaks, named ‘O1’ and ‘O2’, with activation energies around 0.15 eV and 0.4 eV below the 4H–SiC conduction band that are typically observed in thermal oxides on 4H–SiC, are also present in PSG devices. Previous atomic scale ab initio calculations suggested these O1 and O2 traps to be carbon dimers substituted for oxygen dimers (CO=CO) and interstitial Si (Sii) in SiO2, respectively. Theoretical considerations in this work suggest that the presence of P in the near-interfacial region reduces the stability of the CO=CO defects and reduces the density of Sii defects through the network restructuring. Qualitative comparison of results in this work and reported work suggest that the O1 and O2 traps in SiO2/4H–SiC MOS system negatively impact channel mobility in 4H–SiC MOSFETs.

Caribbean basin framework, 3: Southern Central America and Colombian basin

DOE Office of Scientific and Technical Information (OSTI.GOV)

Kolarsky, R.A.; Mann, P.

1991-03-01

The authors recognize three basin-forming periods in southern Central America (Panama, Costa Rica, southern Nicaragua) that they attempt to correlate with events in the Colombian basin (Bowland, 1984): (1) Early-Late Cretaceous island arc formation and growth of the Central American island arc and Late Cretaceous formation of the Colombian basin oceanic plateau. During latest Cretaceous time, pelagic carbonate sediments blanketed the Central American island arc in Panama and Costa Rica and elevated blocks on the Colombian basin oceanic plateau; (2) middle Eocene-middle Miocene island arc uplift and erosion. During this interval, influx of distal terrigenous turbidites in most areas ofmore » Panama, Costa Rica, and the Colombian basin marks the uplift and erosion of the Central American island arc. In the Colombian basin, turbidites fill in basement relief and accumulate to thicknesses up to 2 km in the deepest part of the basin. In Costa Rica, sedimentation was concentrated in fore-arc (Terraba) and back-arc (El Limon) basins; (3) late Miocene-Recent accelerated uplift and erosion of segments of the Central American arc. Influx of proximal terrigenous turbidites and alluvial fans in most areas of Panama, Costa Rica, and the Colombian basin marks collision of the Panama arc with the South American continent (late Miocene early Pliocene) and collision of the Cocos Ridge with the Costa Rican arc (late Pleistocene). The Cocos Ridge collision inverted the Terraba and El Limon basins. The Panama arc collision produced northeast-striking left-lateral strike-slip faults and fault-related basins throughout Panama as Panama moved northwest over the Colombian basin.« less

Development of a Mathematical Model that Simulates the Longitudinal, and Lateral-Directional Response of the F/A-18 for the Study of Flight Control Reconfiguration

DTIC Science & Technology

1986-09-01

rococo CO CO COooo...iHrHrH OOO<<< [l|[i4[x4 OOO OrHCM rococoOOO rHr-Hf— I OOO [i4[ii[i4 OOO co<*lo cocoooOOO (Hi—IrH OOO<<< [14 [14 [14 OOO loc^co rococo OOO iHr-irH OOO...kO— O COH I Eh + CNi—11—11—iQ •2WSO ’^J-* 1— 1 0-i 1—1 . II Q II JHH || CN II II Eh<EhCQO rococo coco cf> cr> cji cr> <y> fafafafafa fa O o + Q O

Effect of dietary fiber on the activity of intestinal and fecal beta-glucuronidase activity during 1,2-dimethylhydrazine induced colon carcinogenesis.

PubMed

Manoj, G; Thampi, B S; Leelamma, S; Menon, P V

2001-01-01

The effects of fiber isolated from black gram (Phaseolus mungo) and coconut (Cocos nucifera) kernel on the metabolic activity of intestinal and fecal beta glucuronidase activity during 1,2-dimethylhydrazine induced colon carcinogenesis were studied. The results indicated that the inclusion of fiber from black gram and coconut kernel generally supported lower specific activities and less fecal output of beta-glucuronidase than did the fiber free diet. This study suggests that the fibers isolated from coconut or black gram may potentially play a role in preventing the formation of colon tumors induced by the carcinogen 1,2-dimethylhydrazine by reducing the activity of the intestinal as well as fecal beta-glucuronidase.

All Prime Contract Awards by State or Country, Place, and Contractor. Part 4 (San Diego, California-Victorville, California)

DTIC Science & Technology

1990-01-01

4 N 41, <- ɘ) 41 - <-40 MI C-4 04 N NNNNN04N N\\CN 0 40 40 -4 ’-4 0) 0 00C Oi MC-4 Ilr-4--44l"I4.4- -1.44 -f-4 1- 0 Coco c)0 41 W C oc NOWO H1-1 W...zoo4 Cn-44.-44-4- 0)0000o00000000 =1310- it I CI t 347 ) 00 NC- o 7 f40 -100 00(0) 2 1((( (0(0 a)0 _ NO) 0 OOOOOOOOO))C)0)0)C M 14 04 1-0 1- < 0 CA: 0Z

Prime Contract Awards Alphabetically by Contractor, State or Country, and Place. Part 10 (International Bus MCHS Corp, New Orleans, Louisiana - Lemmen Pontiac and Farm Equipment Co Inc, Coopersville, Michigan), FY1991

DTIC Science & Technology

1991-01-01

40400 ENNC -IN0 " I COCO< a 0D000 0 0D 00 0v C 00 ou n 00100. otnn ivan 0. a %- I M(04 s 0D000 C. 0 1 -0 0 00 = t-I%. 000 fA N -4.C400 WE a I 02...4NN Can 0 CO wU a 0 a 004o a o 00 Canan geCY) 0 3:CN( 00C I %anan oan 04t 00 f) U O- 0 00 0 V0 00000oo* 00 Cwt 00000 -an 000 CL C LNC -.40c a 0I in0o4

Electron-temperature dependence of dissociative recombination of electrons with N2/+/.N2 dimer ions

NASA Technical Reports Server (NTRS)

Whitaker, M.; Biondi, M. A.; Johnsen, R.

1981-01-01

The variation with electron temperature of the dissociative recombination of electrons with N2(+).N2 dimer ions is investigated in light of the importance of such ions in the lower ionosphere and in laser plasmas. Dissociative recombination coefficients were determined by means of a microwave afterglow mass spectrometer technique for electron temperatures from 300-5600 K and an ion and neutral temperature of 300 K. The recombination coefficient is found to be proportional to the -0.41 power of the electron temperature in this range, similar to that observed for the CO(+).CO dimer ion and consistent with the expected energy dependence for a fast dissociative process.

Leg 67: the Deep Sea Drilling Project Mid-America Trench transect off Guatemala.

USGS Publications Warehouse

von Huene, Roland E.

1980-01-01

Drilling on the Cocos plate recovered a basal chalk sequence deposited during early and mid-Miocene time, a short interval of abyssal red clay, and an upper sequence of late Miocene and younger sediment deposited within an area influenced by a terrigenous source. In the trench, a mud and sand fill less than 400,000 yr old overlies the oceanic sequence. The entire section shows no evidence of compressive deformation. In contrast, the section cored on the trench's landward slope 3 km from the trench axis is affected by tectonism. The section contains a Cretaceous to Pliocene claystone sequence capped by Pliocene to Quaternary hemipelagic slope deposits.- from Authors

A Top-Down Performance Analysis of a Pegasus-Based Space Strike System

DTIC Science & Technology

1991-12-01

284): AP 1 O. coCO 4., cos 2 =~ +I Q ( QbO - 2) cos2 Cbo 28 This equation is useful for determining free-flight range for any set of burnout con...it may therefore be expressed in the manner given by Eq (26): cot1 - Qbo cos 2 Obo2 Qbo cos ¢ bo1 - cos2 kbo (27) Since \\/f1-cos7 Obo = sin Obo and...in general, cos a sin a = 1/2 x sin 2a, then Eq (27) can be further simplified to ’’ 2 cot - = 2csc20b, - cot Obo (28) 2 Qbo Rearranging tcrms results

Determination of Activities of Niobium in Cu-Nb Melts Containing Dilute Nb

NASA Astrophysics Data System (ADS)

Wang, Daya; Yan, Baijun; Sichen, Du

2015-04-01

The activity coefficients of niobium in Cu-Nb melts were measured by equilibrating solid NbO2 with liquid copper under controlled oxygen potentials in the temperature range of 1773 K to 1898 K (1500 °C to 1625 °C). Either CO-CO2 gas mixture or H2-CO2 gas mixture was employed to obtain the desired oxygen partial pressures. Cu-Nb system was found to follow Henry's law in the composition range studied. The temperature dependence of Henry's constant in the Cu-Nb melts could be expressed as follows: The partial molar excess Gibbs energy change of niobium in Cu-Nb melts can be expressed as follows:

All Prime Contract Awards by State or Country, Place, and Contractor. Part 23 (Iceland-TRW INC Classified Location)

DTIC Science & Technology

1990-01-01

0 U anoonno Q0000mnh00 C21 000 cc 00m0h00h9 103M CIO U U -4N0I H * o~ O444444N~C200 0 00 cc -4 CocoU -4000 * iaU-iNMU<: WW -4-4-4-4-4-i C404Nqf 4 -4...0 8 rH Ia. 4 0 P4 PI. 00& soG or r ,4 - . .#.- ,I.t-f .4 W-404 0 0 4 4. 4 co4 0 40a 0000000 -1- 9( 0 3co000 * In 6 344 0 40 0 a0 c 0 00>>>WA>>>>> * 0

Sacha Inchi Oil (Plukenetia volubilis L.), effect on adherence of Staphylococus aureus to human skin explant and keratinocytes in vitro.

PubMed

Gonzalez-Aspajo, German; Belkhelfa, Haouaria; Haddioui-Hbabi, Laïla; Bourdy, Geneviève; Deharo, Eric

2015-08-02

Plukenetia volubilis L. (Euphorbiaceae) is a domesticated vine distributed from the high-altitude Andean rain forest to the lowlands of the Peruvian Amazon. Oil from the cold-pressed seeds, sold under the commercial name of Sacha Inchi Oil (SIO) is actually much in favour because it contains a high percentage of omega 3 and omega 6, and is hence used as a dietary supplement. SIO is also used traditionally for skin care, in order to maintain skin softness, and for the treatment of wounds, insect bites and skin infections, in a tropical context where the skin is frequently damaged. This study was designed in order to verify whether the traditional use of SIO for skin care would have any impact on Staphylococcus aureus growth and skin adherence, as S. aureus is involved in many skin pathologies (impetigo, folliculitis, furuncles and subcutaneous abscesses) being one if the main pathogens that can be found on the skin. Therefore, our objective was to assess SIO bactericidal activity and interference with adherence to human skin explants and the keratinocyte cell line. Cytotoxicity on that cells was also determined. The activity of SIO was compared to coconut oil (CocO), which is widely used for skin care but has different unsaturated fatty acids contents. Laboratory testing with certified oil, determined antibacterial activity against radio labelled S. aureus. Cytotoxic effects were measured with XTT on keratinocyte cells and with neutral red on human skin explants; phenol was used as cytotoxic control. Adherence assays were carried out by mixing H3-labelled S. aureus bacteria with keratinocyte cells and human skin explants, incubated with oils 2h before (to determine the inhibition of adherence, assimilated to a preventive effect) or 2h after the contact of the biological material with S. aureus (to assess the detachment of the bacteria, assimilated to a curative effect). Residual radioactivity measured after washings made it possible to determine the adherence

The isotopic composition of CO in vehicle exhaust

NASA Astrophysics Data System (ADS)

Naus, S.; Röckmann, T.; Popa, M. E.

2018-03-01

We investigated the isotopic composition of CO in the exhaust of individual vehicles. Additionally, the CO2 isotopes, and the CO:CO2, CH4:CO2 and H2:CO gas ratios were measured. This was done under idling and revving conditions, and for three vehicles in a full driving cycle on a testbench. The spread in the results, even for a single vehicle, was large: for δ13 C in CO ∼ -60 to 0‰, for δ18 O in CO ∼ +10 to +35‰, and for all gas ratios several orders of magnitude. The results show an increase in the spread of isotopic values for CO compared to previous studies, suggesting that increasing complexity of emission control in vehicles might be reflected in the isotopic composition. When including all samples, we find a weighted mean for the δ13 C and δ18 O in CO of -28.7 ± 0.5‰ and +24.8 ± 0.3‰ respectively. This result is dominated by cold petrol vehicles. Diesel vehicles behaved as a distinct group, with CO enriched in 13C and depleted in 18O, compared to petrol vehicles. For the H2:CO ratio of all vehicles, we found a value of 0.71 ± 0.31 ppb:ppb. The CO:CO2 ratio, with a mean of 19.4 ± 6.8 ppb:ppm, and the CH4:CO2 ratio, with a mean of 0.26 ± 0.05 ppb:ppm, are both higher than recent literature indicates. This is likely because our sampling distribution was biased towards cold vehicles, and therefore towards higher emission situations. The CH4:CO2 ratio was found to behave similarly to the CO:CO2 ratio, suggesting that the processes affecting CO and CH4 are similar. The δ13 C values in CO2 were close to the expected δ13 C in fuel, with no significant difference between petrol and diesel vehicles. The δ18 O values in CO2 for petrol vehicles covered a range of 20-35‰, similar to the δ18 O of CO. The δ18 O values in CO2 for diesel vehicles were close to the δ18 O in atmospheric oxygen. A set of polluted atmospheric samples, taken near a highway and inside parking garages, showed an isotopic signature of CO and a H2:CO ratio that were

Crystal structure of cocosin, a potential food allergen from coconut (Cocos nucifera) (abstract)

USDA-ARS?s Scientific Manuscript database

RATIONALE: Coconut allergy cases have been reported, but only one coconut allergen has been identified. The 11S seed storage proteins belong to one of a few protein families that contain known food allergens in many food of plant sources. Cocosin, the 11S protein from cocosin remains to be character...

Identification of molecular markers associated with mite resistance in coconut (Cocos nucifera L.).

PubMed

Shalini, K V; Manjunatha, S; Lebrun, P; Berger, A; Baudouin, L; Pirany, N; Ranganath, R M; Prasad, D Theertha

2007-01-01

Coconut mite (Aceria guerreronis 'Keifer') has become a major threat to Indian coconut (Coçcos nucifera L.) cultivators and the processing industry. Chemical and biological control measures have proved to be costly, ineffective, and ecologically undesirable. Planting mite-resistant coconut cultivars is the most effective method of preventing yield loss and should form a major component of any integrated pest management stratagem. Coconut genotypes, and mite-resistant and -susceptible accessions were collected from different parts of South India. Thirty-two simple sequence repeat (SSR) and 7 RAPD primers were used for molecular analyses. In single-marker analysis, 9 SSR and 4 RAPD markers associated with mite resistance were identified. In stepwise multiple regression analysis of SSRs, a combination of 6 markers showed 100% association with mite infestation. Stepwise multiple regression analysis for RAPD data revealed that a combination of 3 markers accounted for 83.86% of mite resistance in the selected materials. Combined stepwise multiple regression analysis of RAPD and SSR data showed that a combination of 5 markers explained 100% of the association with mite resistance in coconut. Markers associated with mite resistance are important in coconut breeding programs and will facilitate the selection of mite-resistant plants at an early stage as well as mother plants for breeding programs.

Local earthquake tomography of the Jalisco, Mexico region

NASA Astrophysics Data System (ADS)

Watkins, W. David; Thurber, Clifford H.; Abbott, Elizabeth R.; Brudzinski, Michael R.

2018-01-01

The states of Jalisco, Colima, and Michoacán in western Mexico overlie the boundary of the subducting Rivera and Cocos plates, presenting an ideal target for seismological inquiry to better understand the resulting mantle flow and regional volcanism. The different dips between the two subducting plates are thought to provide a mantle conduit that has contributed to the Colima Volcanic Complex (CVC), but there is considerable debate on the depth of the Rivera plate and width of the resulting conduit. With data from the Mapping the Rivera Subduction Zone (MARS) and Colima Deep Seismic Experiment (CODEX) networks, two temporary broadband arrays deployed in the region between 2006 and 2008, we inverted for three-dimensional P- and S-wave velocity as well as Vp/Vs structure of the upper 70 km of the crust and mantle in the Jalisco region. Using a newly-developed automatic P- and S-wave picker, we increased P picks by 74% and S picks by more than a factor of four compared to a database of manual picks for the 803 earthquakes used in the inversion. Additional relocated earthquakes extending to the trench are consistent with previous interpretations of the Rivera and Cocos plate interfaces. Areas of high Vp/Vs above both subducting slabs suggest the presence of fluids resulting from dehydration of subducted material. Extensive crustal seismicity occurs near these anomalies. A zone of high Vp/Vs is also present under the CVC. We also compare the results of different methods for obtaining Vp/Vs: a direct inversion for Vp/Vs from S minus P times versus simply dividing the Vp model by the Vs model. We find direct inversions of S minus P times to be more reliable.

Shallow seismicity patterns in the northwestern section of the Mexico Subduction Zone

NASA Astrophysics Data System (ADS)

Abbott, Elizabeth R.; Brudzinski, Michael R.

2015-11-01

This study characterizes subduction related seismicity with local deployments along the northwestern section of the Mexico Subduction Zone where 4 portions of the plate interface have ruptured in 1973, 1985, 1995, and 2003. It has been proposed that the subducted boundary between the Cocos and Rivera plates occurs beneath this region, as indicated by inland volcanic activity, a gap in tectonic tremor, and the Manzanillo Trough and Colima Graben, which are depressions thought to be associated with the splitting of the two plates after subduction. Data from 50 broadband stations that comprised the MARS seismic array, deployed from January 2006 to June 2007, were processed with the software program Antelope and its generalized source location algorithm, genloc, to detect and locate earthquakes within the network. Slab surface depth contours from the resulting catalog indicate a change in subduction trajectory between the Rivera and Cocos plates. The earthquake locations are spatially anti-correlated with tectonic tremor, supporting the idea that they represent different types of fault slip. Hypocentral patterns also reveal areas of more intense seismic activity (clusters) that appear to be associated with the 2003 and 1973 megathrust rupture regions. Seismicity concentrated inland of the 2003 rupture is consistent with slip on a shallowly dipping trajectory for the Rivera plate interface as opposed to crustal faulting in the overriding North American plate. A prominent cluster of seismicity within the suspected 1973 rupture zone appears to be a commonly active portion of the megathrust as it has been active during three previous deployments. We support these interpretations by determining focal mechanisms and detailed relocations of the largest events within the 1973 and inland 2003 clusters, which indicate primarily thrust mechanisms near the plate interface.

Long-term and Short-term Vertical Deformation Rates across the Forearc in the Central Mexican Subduction Zone

NASA Astrophysics Data System (ADS)

Ramirez-Herrera, M. T.; Gaidzik, K.; Forman, S. L.; Kostoglodov, V.; Burgmann, R.

2015-12-01

Spatial scales of the earthquake cycle, from rapid deformation associated with earthquake rupture to slow deformation associated with interseismic and transient slow-slip behavior, span from fractions of a meter to thousands of kilometers (plate boundaries). Similarly, temporal scales range from seconds during an earthquake rupture to thousands of years of strain accumulation between earthquakes. The complexity of the multiple physical processes operating over this vast range of scales and the limited coverage of observations leads most scientists to focus on a narrow space-time window to isolate just one or a few process. We discuss here preliminary results on the vertical crustal deformation associated with both slow and rapid crustal deformation along a profile across the forearc region of the central Mexican subduction zone on the Guerrero sector, where the Cocos plate underthrusts the North American plate. This sector of the subduction zone is characterized by a particular slab geometry (with zones of rapid bending-unbending of the slab), irregular distributed seismicity, exceptionally large slow slip events (SSE) and non-volcanic tremors (NVT). We used the river network and geomorphic features of the Papagayo River to assess Quaternary crustal deformation. The Papagayo drainage network is strongly controlled by Late Cenozoic tectonic, Holocene and recent earthquake cycle processes. This is particularly true for the southern section of the drainage basin; from the dam in La Venta to the river mouth, where W-E structures commonly offset the course of the main river. River terraces occur along the course of the river at different elevations. We measured the height of a series of terraces and obtained OSL ages on quartz extracts to determine long-term rates of deformation. Finally, we discuss associations of the topography and river characteristics with the Cocos slab geometry, slow earthquakes, crustal deformation, and interseismic deformation.

The Occurrence of the Recent Deadly Mexico Earthquakes was not that Unexpected

NASA Astrophysics Data System (ADS)

Flores-Marquez, L.; Sarlis, N. V.; Skordas, E. S.; Varotsos, P.; Ramírez-Rojas, A.

2017-12-01

Most big Mexican earthquakes occur right along the interface between the colliding Cocos and North American plates, but the two recent deadly Mexico earthquakes, i.e., the magnitude 8.2 earthquake that struck the Mexico's Chiapas state on 7 September 2017 and the magnitude 7.1 earthquake that struck central Mexico, almost 12 days later, killing more than 400 people and reducing buildings to rubble in several States happened at two different spots in the flat-slab in the middle of the Cocos tectonic plate which is considered a geologically surprising area [1]. Here, upon considering a new type of analysis termed natural time, we show that their occurrence should not in principle puzzle scientists. Earthquakes may be considered as critical phenomena, see Ref. [2] and references therein and natural time analysis [3] uncovers an order parameter for seismicity. It has been shown [2] that the fluctuations of this order parameter exhibit a universal behavior with a probability density function (pdf), which is non-Gaussian having a left exponential tail [3]. Natural time analysis of seismicity in various tectonic regions of the Mexican Pacific Coast has been made in Ref.[4]. The study of the order parameter pdf for the Chiapas area as well as for the Guerrero area shows that the occurrence of large earthquakes in these two areas was not unexpected. References A. Witze, Deadly Mexico quakes not linked, Nature 549, 442 (2017). Varotsos PA, Sarlis NV, Skordas ES, Natural Time Analysis: The new view of time. Precursory Seismic Electric Signals, Earthquakes and other Complex Time-Series (Springer-Verlag, Berlin Heidelberg 2011) P. Varotsos et al., Similarity of fluctuations in correlated systems: the case of seismicity. Phys. Rev. E 72, 041103 (2005) A. Ramírez-Rojas and E.L. Flores-Márquez, Order parameter analysis of seismicity of the Mexican Pacific coast. Physica A, 392 2507 (2013)

MULCHES AND OTHER COVER MATERIALS TO REDUCE WEED GROWTH IN CONTAINER-GROWN NURSERY STOCK.

PubMed

Rys, F; Van Wesemael, D; Van Haecke, D; Mechant, E; Gobin, B

2014-01-01

Due to the recent EU-wide implementation of Integrated Pest Management (IPM), alternative methods to reduce weed growth in container-grown nursery stock are needed to cut back the use of herbicides. Covering the upper layer of the substrate is known as a potential method to prevent or reduce weed growth in plant containers. As a high variety of mulches and other cover materials are on the market, however, it is no longer clear for growers which cover material is most efficient for use in containers. Therefore, we examined the effect on weed growth of different mulches and other cover materials, including Pinus maritima, P. sylvestris, Bio-Top Basic, Bio-Top Excellent, coco chips fine, hemp fibres, straw pellets, coco disk 180LD and jute disk. Cover materials were applied immediately after repotting of Ligustrum ovalifolium or planting of Fagus sylvatica. At regular times, both weed growth and side effects (e.g., plant growth, water status of the substrate, occurrence of mushrooms, foraging of birds, complete cover of the substrate and fixation) were assessed. All examined mulches or other cover materials were able to reduce weed growth on the containers during the whole growing season. Weed suppression was even better than that of a chemical treated control. Although all materials showed some side effects, the impact on plant growth is most important to the grower and depends not only on material characteristics (e.g., biodegradation, nutrient leaching and N-immobilisation) but also on container size and climatic conditions. In conclusion, mulches and other cover materials can be a valuable tool within IPM to lower herbicide use. To enable a deliberate choice of which cover material is best used in a specific situation more research is needed on lifespan and stability as well as on economic characteristics of the materials.

Long-distance dispersal of the coconut palm by migration within the coral atoll ecosystem

PubMed Central

Harries, Hugh C.; Clement, Charles R.

2014-01-01

Background The location of the original home of the coconut palm, Cocos nucifera, and the extent of its natural dispersal are not known. Proponents of a South American origin must explain why it is not indigenous there and why it shows greatest diversity in southern Asia. Conversely, proponents of an Asian origin must explain why there are no Asian Cocoseae and why the closest botanical relative to Cocos is in South America. Both hypotheses share the common problems of how, when, where and in what directions long-distance dispersal occurred. Hypothesis These difficulties are resolved by accepting that C. nucifera originated and dispersed by populating emerging islands of the coral atoll ecosystem, where establishment conditions impose high selection pressures for survival. When lifted by wave action onto virtually sterile, soilless coralline rocks just above sea level and exposed to the full impact of the sun, seednuts must germinate, root and establish vigorous populations. The cavity within the nut augments the buoyancy provided by the thick husk, which in turn protects the embryo and, by delaying germination, simultaneously extends viability while floating and provides a moisture-retentive rooting medium for the young seedling. These adaptations allow coconuts to disperse widely through the coral atoll ecosystem. Conclusions The monthly production of fruit and the long floating duration ensure that viable seednuts are always available in the lagoon to replace those destroyed by hurricanes and tsunamis, or to populate newly emerged coral atolls elsewhere. Long-distance dispersal is secondary, because it was the spontaneous, independent migration of coral polyps on a prolonged geological time scale that generated new coral atolls in new areas where the coconuts would be amongst the earliest inhabitants. The coconut palm became an intermittent, itinerant, pioneer endemic there, and also on suitable beaches on volcanic or large islands and continental coastlines

Removing traffic emissions from CO2 time series measured at a tall tower using mobile measurements and transport modeling

NASA Astrophysics Data System (ADS)

Schmidt, Andres; Rella, Chris W.; Göckede, Mathias; Hanson, Chad; Yang, Zhenlin; Law, Beverly E.

2014-11-01

In recent years, measurements of atmospheric carbon dioxide with high precision and accuracy have become increasingly important for climate change research, in particular to inform terrestrial biosphere models. Anthropogenic carbon dioxide emissions from fossil fuel burning have long been recognized to contribute a significant portion of the carbon dioxide in the atmosphere. Here, we present an approach to remove the traffic related carbon dioxide emissions from mole fractions measured at a tall tower by using the corresponding carbon monoxide measurements in combination with footprint analyses and transport modeling. This technique improves the suitability of the CO2 data to be used in inverse modeling approaches of atmosphere-biosphere exchange that do not account for non-biotic portions of CO2. In our study region in Oregon, road traffic emissions are the biggest source of anthropogenic carbon dioxide and carbon monoxide. A three-day mobile campaign covering 1700 km of roads in northwestern Oregon was performed during summer of 2012 using a laser-based Cavity Ring-Down Spectrometer. The mobile measurements incorporated different roads including main highways, urban streets, and back-roads, largely within the typical footprint of a tall CO/CO2 observation tower in Oregon's Willamette Valley. For the first time, traffic related CO:CO2 emission ratios were measured directly at the sources during an on-road campaign under a variety of different driving conditions. An average emission ratio of 7.43 (±1.80) ppb CO per ppm CO2 was obtained for the study region and applied to separate the traffic related portion of CO2 from the mole fraction time series. The road traffic related portion of the CO2 mole fractions measured at the tower site reached maximum values ranging from 9.8 to 12 ppm, depending on the height above the surface, during summer 2012.

Long-distance dispersal of the coconut palm by migration within the coral atoll ecosystem.

PubMed

Harries, Hugh C; Clement, Charles R

2014-03-01

The location of the original home of the coconut palm, Cocos nucifera, and the extent of its natural dispersal are not known. Proponents of a South American origin must explain why it is not indigenous there and why it shows greatest diversity in southern Asia. Conversely, proponents of an Asian origin must explain why there are no Asian Cocoseae and why the closest botanical relative to Cocos is in South America. Both hypotheses share the common problems of how, when, where and in what directions long-distance dispersal occurred. These difficulties are resolved by accepting that C. nucifera originated and dispersed by populating emerging islands of the coral atoll ecosystem, where establishment conditions impose high selection pressures for survival. When lifted by wave action onto virtually sterile, soilless coralline rocks just above sea level and exposed to the full impact of the sun, seednuts must germinate, root and establish vigorous populations. The cavity within the nut augments the buoyancy provided by the thick husk, which in turn protects the embryo and, by delaying germination, simultaneously extends viability while floating and provides a moisture-retentive rooting medium for the young seedling. These adaptations allow coconuts to disperse widely through the coral atoll ecosystem. The monthly production of fruit and the long floating duration ensure that viable seednuts are always available in the lagoon to replace those destroyed by hurricanes and tsunamis, or to populate newly emerged coral atolls elsewhere. Long-distance dispersal is secondary, because it was the spontaneous, independent migration of coral polyps on a prolonged geological time scale that generated new coral atolls in new areas where the coconuts would be amongst the earliest inhabitants. The coconut palm became an intermittent, itinerant, pioneer endemic there, and also on suitable beaches on volcanic or large islands and continental coastlines.

Synthesis of thin film containing 4-amino-1,2,4-triazole iron(II) complexes

DOE Office of Scientific and Technical Information (OSTI.GOV)

Onggo, Djulia, E-mail: djulia@Chem.itb.ac.id

The Iron(II) complex with 4-amino-1,2,4 triazole (NH{sub 2}-trz) ligand has potential applications as smart material since the compounds show a distinct color change from lilac at low temperature to colorless at high temperature. The lilac color of the complex represent the diamagnetic low spin state while the colorless correspond to the paramagnetic high spin state of iron(II). The transition between the two states could be tuned by changing the anionic group. Generally, the complex was synthesized directly from aqueous solution of iron(II) salt with considerable amounts of NH{sub 2}-trz solution produced solid powder compound. For application as an electronic molecularmore » device, the complex should be obtained as a thin film. The transparent [Fe(NH{sub 2}trz){sub 3}]-Nafion film has been successfully obtained, however, no anion variation can be produced since the nafion is an anionic resin. In this work, the [Fe(NH{sub 2}trz){sub 3}]-complexes with several anions have been synthesized inside nata de coco membrane that commonly used as a medium for deposition metal nano-particles. After drying the membrane containing the complex became a thin film. At room temperature, the film containing iron(II) complexes of sulphate and nitrate salts show lilac color, similar to that of the original complexes in the powder form. On heating, the color of the complex film changed to colorless and this color change was observed reversibly. In contrast, the films containing perchlorate and tetrafluoroborate iron(II) complexes are colorless at room temperature and changed to lilac on cooling. The significant color changing of the iron(II)complexes in the nata de coco film can be used for demonstration thermo chromic effect of smart materials with relatively small amount of the compounds.« less

Active crustal deformation of the El Salvador Fault Zone by integrating geodetic, seismological and geological data: application in seismic hazard assessment

NASA Astrophysics Data System (ADS)

Staller, A.; Benito, B.; Martínez-Díaz, J.; Hernández, D.; Hernández-Rey, R.

2013-05-01

El Salvador, Central America, is part of the Chortis block in the northwestern boundary of the Caribbean plate. This block is interacting with a diffuse triple junction point with the Cocos and North American plates. Among the structures that cut the Miocene to Pleistocene volcanic deposits stands out the El Salvador Fault Zone (ESFZ): It is oriented in N90-100E direction, and it is composed of several structural segments that deform Quaternary deposits with right-lateral and oblique slip motions. The ESFZ is seismically active and capable of producing earthquakes such as the February 13, 2001 with Mw 6.6 (Martínez-Díaz et al., 2004), that seriously affected the population, leaving many casualties. This structure plays an important role in the tectonics of the Chortis block, since its motion is directly related to the drift of the Caribbean plate to the east and not with the partitioning of the deformation of the Cocos subduction (here not coupled) (Álvarez-Gómez et al., 2008). Together with the volcanic arc of El Salvador, this zone constitutes a weakness area that allows the motion of forearc block toward the NW. The geometry and the degree of activity of the ESFZ are not studied enough. However their knowledge is essential to understand the seismic hazard associated to this important seismogenic structure. For this reason, since 2007 a GPS dense network was established along the ESFZ (ZFESNet) in order to obtain GPS velocity measurements which are later used to explain the nature of strain accumulation on major faults along the ESFZ. The current work aims at understanding active crustal deformation of the ESFZ through kinematic model. The results provide significant information to be included in a new estimation of seismic hazard taking into account the major structures in ESFZ.

Active crustal deformation of the El Salvador Fault Zone (ESFZ) using GPS data: Implications in seismic hazard assessment

NASA Astrophysics Data System (ADS)

Staller, Alejandra; Benito, Belen; Jesús Martínez-Díaz, José; Hernández, Douglas; Hernández-Rey, Román; Alonso-Henar, Jorge

2014-05-01

El Salvador, Central America, is part of the Chortis block in the northwestern boundary of the Caribbean plate. This block is interacting with a diffuse triple junction point with the Cocos and North American plates. Among the structures that cut the Miocene to Pleistocene volcanic deposits stands out the El Salvador Fault Zone (ESFZ): It is oriented in N90º-100ºE direction, and it is composed of several structural segments that deform Quaternary deposits with right-lateral and oblique slip motions. The ESFZ is seismically active and capable of producing earthquakes such as the February 13, 2001 with Mw 6.6 (Martínez-Díaz et al., 2004), that seriously affected the population, leaving many casualties. This structure plays an important role in the tectonics of the Chortis block, since its motion is directly related to the drift of the Caribbean plate to the east and not with the partitioning of the deformation of the Cocos subduction (here not coupled) (Álvarez-Gómez et al., 2008). Together with the volcanic arc of El Salvador, this zone constitutes a weakness area that allows the motion of forearc block toward the NW. The geometry and the degree of activity of the ESFZ are not studied enough. However their knowledge is essential to understand the seismic hazard associated to this important seismogenic structure. For this reason, since 2007 a GPS dense network was established along the ESFZ (ZFESNet) in order to obtain GPS velocity measurements which are later used to explain the nature of strain accumulation on major faults along the ESFZ. The current work aims at understanding active crustal deformation of the ESFZ through kinematic model. The results provide significant information to be included in a new estimation of seismic hazard taking into account the major structures in ESFZ.

High performance MIIM diode based on cobalt oxide/titanium oxide

NASA Astrophysics Data System (ADS)

Herner, S. B.; Weerakkody, A. D.; Belkadi, A.; Moddel, G.

2017-05-01

Optical rectennas for infrared energy harvesting commonly incorporate metal/double-insulator/metal diodes. Required diode characteristics include high responsivity and low resistance near zero bias with a sub-micron area, which have not been obtainable simultaneously. Diodes based on a new material set, Co/Co3O4/TiO2/Ti and an area of 0.071 μm2, provide a median maximum responsivity of 4.1 A/W, a median zero-bias responsivity of 1.2 A/W, and a median resistance of 14 kΩ. The highest performing diode has a maximum responsivity of 4.4 A/W, a zero-bias responsivity of 2.2 A/W, and a resistance of 18 kΩ.

ROPE: Recoverable Order-Preserving Embedding of Natural Language

DOE Office of Scientific and Technical Information (OSTI.GOV)

Widemann, David P.; Wang, Eric X.; Thiagarajan, Jayaraman J.

We present a novel Recoverable Order-Preserving Embedding (ROPE) of natural language. ROPE maps natural language passages from sparse concatenated one-hot representations to distributed vector representations of predetermined fixed length. We use Euclidean distance to return search results that are both grammatically and semantically similar. ROPE is based on a series of random projections of distributed word embeddings. We show that our technique typically forms a dictionary with sufficient incoherence such that sparse recovery of the original text is possible. We then show how our embedding allows for efficient and meaningful natural search and retrieval on Microsoft’s COCO dataset and themore » IMDB Movie Review dataset.« less

Electron-temperature dependence of dissociative recombination of electrons with CO(+)-(CO)n-series ions

NASA Technical Reports Server (NTRS)

Whitaker, M.; Biondi, M. A.; Johnsen, R.

1980-01-01

A microwave afterglow mass spectrometer apparatus is used to determine the dependence on electron temperature T sub e of the recombination coefficients alpha sub n of the dimer and trimer ions of the series CO+.(CO) sub n. It is found that alpha sub 1 = (1.3 + or - 0.3)x 0.000001 (T sub e(K)/300) to the -0.34; and alpha sub 2 = (1.9 + or - 0.4)x 0.000001 (T sub e(K)/300) to the -0.33 cu cm/sec. These dependences on T sub e are quite different from those obtained previously for polar-cluster ions of the hydronium and ammonium series but are similar to that for simple diatomic ions.

Study of the structure changes caused by volcanic activity in Mexico applying the lineament analysis to the Aster (Terra) satellite data.

NASA Astrophysics Data System (ADS)

Arellano-Baeza, A. A.; Garcia, R. V.; Trejo-Soto, M.; Molina-Sauceda, E.

Mexico is one of the most volcanically active regions in North America Volcanic activity in central Mexico is associated with the subduction of the Cocos and Rivera plates beneath the North American plate Periods of enhanced microseismic activity associated with the volcanic activity of the Colima and Popocapetl volcanoes are compared to some periods of low microseismic activity We detected changes in the number and orientation of lineaments associated with the microseismic activity due to lineament analysis of a temporal sequence of high resolution satellite images of both volcanoes 15 m resolution multispectral images provided by the ASTER VNIR instrument were used The Lineament Extraction and Stripes Statistic Analysis LESSA software package was employed for the lineament extraction

Effect of oxide films on hydrogen permeability of candidate Stirling engine heater head tube alloys

NASA Technical Reports Server (NTRS)

Schuon, S. R.; Misencik, J. A.

1981-01-01

The effect of oxide films developed in situ from CO/CO2 doped hydrogen on high pressure hydrogen permeability at 820 C was studied on N-155, A-286, IN 800, 19-9DL, Nitronic 40, HS-188, and IN 718 tubing in a Stirling materials simulator. The hydrogen permeability decreased with increasing dopant levels of CO or CO2 and corresponding decreases in oxide porosity. Minor reactive alloying elements strongly influenced permeability. At high levels of CO or CO2, a liquid oxide formed on alloys with greater than 50 percent Fe. This caused increased permeability. The oxides formed on the inside tube walls were analyzed and their effective permeabilities were calculated.

Analysis and control of the dynamical response of a higher order drifting oscillator

NASA Astrophysics Data System (ADS)

Liu, Yang; Páez Chávez, Joseph; Pavlovskaia, Ekaterina; Wiercigroch, Marian

2018-02-01

This paper studies a position feedback control strategy for controlling a higher order drifting oscillator which could be used in modelling vibro-impact drilling. Special attention is given to two control issues, eliminating bistability and suppressing chaos, which may cause inefficient and unstable drilling. Numerical continuation methods implemented via the continuation platform COCO are adopted to investigate the dynamical response of the system. Our analyses show that the proposed controller is capable of eliminating coexisting attractors and mitigating chaotic behaviour of the system, providing that its feedback control gain is chosen properly. Our investigations also reveal that, when the slider's property modelling the drilled formation changes, the rate of penetration for the controlled drilling can be significantly improved.

A two-dimensional hydrogen-bonded water layer in the structure of a cobalt(III) cubane complex.

PubMed

Qi, Ji; Zhai, Xiang-Sheng; Zhu, Hong-Lin; Lin, Jian-Li

2014-02-01

A tetranuclear Co(III) oxide complex with cubane topology, tetrakis(2,2'-bipyridine-κ(2)N,N')di-μ2-carbonato-κ(4)O:O'-tetra-μ3-oxido-tetracobalt(III) pentadecahydrate, [Co4(CO3)2O4(C10H8N2)4]·15H2O, with an unbounded hydrogen-bonded water layer, has been synthesized by reaction of CoCO3 and 2,2'-bipyridine. The solvent water molecules form a hydrogen-bonded net with tetrameric and pentameric water clusters as subunits. The Co4O4 cubane-like cores are sandwiched between the water layers, which are further stacked into a three-dimensional metallo-supramolecular network.

The quiet and disturbed time performance of the IRI 2012 within 90°-130°E longitude sector during solar cycle 24

NASA Astrophysics Data System (ADS)

Bhuyan, Pradip; Yokoyama, Tatsuhiro; Supnithi, Pornchai; Kalita, Bitap Raj; Wang, Kehe; Komolmis, Tharadol; Yatini, Clara

2016-07-01

The performance of the IRI 2012 model is examined for the double peaked solar cycle 24 in the low latitude region of 90-130oE longitude in the context of the global longitudinal wave number four structure (WN4). The monthly mean values of the foF2 and the hmF2(if available) measurements at low and low mid-latitude stations Dibrugarh (27.5°N, 95°E), Hainan (19.2°N,109.7°E),Okinawa (26.5°N,128°E) and Cocos Island (12.2°S,96.8°E) during quiet times and Dibrugarh (27.5°N, 95°E), Chiang Mai (18.76°N,98.93°E), Chumphon (10.72°N,99.37°E), Kototabang (0.2°S,100.32°E) and Cocos Island (12.2°S,96.8°E ) during the disturbed days of a severe geomagnetic storm are investigated. These stations are located under the strongest peak of the longitudinal WN4 structure in NmF2 along 90-130°E longitudes. The IRI is quite successful in predicting the seasonal averages of NmF2 over this region except in the equinox afternoon period where IRI underestimates the NmF2 in low latitudes. When the monthly mean measured data is compared with IRI, the difference between the IRI model predictions and the measurements are found to follow a systematic pattern. The IRI-2012 with CCIR options slightly underestimates foF2 over Dibrugarh in day time and overestimates in the night time. The amount of underestimation varies from month to month and also depends on the solar activity levels. The IRI also underestimated the day time hmF2 and overestimated the night time hmF2 over Dibrugarh. In case of Hainan, the IRI overestimates the NmF2 in the equinox months and generally in the afternoon to post sunset period. The model values are closer in the solstice than in the equinox. In Okinawa, the trend reverses and the IRI overestimates the NmF2 in the day time and underestimates in the night time. The IRI overestimated the day time hmF2 and underestimated the night time hmF2 over Okinawa. In case of Cocos Island which lies almost on the EIA anomaly region of the southern hemisphere, IRI

The medical officer's journal: HMAS Sydney 1913-1922. An Australian Naval record of surgery and anaesthesia at the time of the outbreak of World War I.

PubMed

McDonald, J M; Todd, E M

2014-07-01

The Medical Officer's Journal of HMAS Sydney was a record kept by the ship's Surgeon, Leonard Darby, of the conditions on the ship and the health, diseases, injuries and treatment of the sailor's under his care. Records of anaesthesia and surgery indicate chloroform was mostly administered as was ether occasionally. There was some use of intravenous and subcutaneous fluids for resuscitation. The journal also provides an eyewitness account of the Sydney-Emden battle on 9 November 1914 which occurred off the Cocos Keeling Islands and was a famous first victory for the young Australian Navy, making headlines around the world. The treatment of the many injured, mostly Germans, is described; with the two Australian surgeons and the surviving German surgeon working together.

Official Guard and Reserve Manpower Strengths and Statistics. FY 2000 Summary

DTIC Science & Technology

2000-01-01

t- 0- at UJ UJ 1/1 oo X LULO > < o Z r- u. or O O Z O. < a: oe S»5 < r- O corvi mo -q-m HHfnSin^ Is-. r** rococo m...1- r^ •=!•-ŗ-•<!• rH rHCTirH to »T O rsi Tfrgr^rH ino rH *j- I— iH m m rsirHinm ro rsi rH rsi COCO Lnoo -1 <r m LnoOf\\IC7l rococo r-^ 1- TJ...i a. t i 1 cn > lOolOIN^ioooooolcoHHrrnj-ttiALOLDiflfnOcoOHHONNO rococo in inmioi£)CT1n-i^-inco CTCOOOCOCOOOCOOOCOCOC71CTlCTlCTlC71C71CT

Central and South America GPS geodesy - CASA Uno

NASA Technical Reports Server (NTRS)

Kellogg, James N.; Dixon, Timothy H.

1990-01-01

In January 1988, scientists from over 25 organizations in 13 countries and territories cooperated in the largest GPS campaign in the world to date. A total of 43 GPS receivers collected approximately 590 station-days of data in American Samoa, Australia, Canada, Colombia, Costa Rica, Ecuador, New Zealand, Norway, Panama, Sweden, United States, West Germany, and Venezuela. The experiment was entitled CASA Uno. Scientific goals of the project include measurements of strain in the northern Andes, subduction rates for the Cocos and Nazca plates beneath Central and South America, and relative motion between the Caribbean plate and South America. A second set of measurements are planned in 1991 and should provide preliminary estimates of crustal deformation and plate motion rates in the region.

Carbon in oxides and silicates - Dissolution versus exsolution

NASA Technical Reports Server (NTRS)

Freund, F.

1986-01-01

A theory of CO2 dissolution in the solid state is developed, using the idea proposed by Freund (1983) concerning dissolution of CO/CO2 in MgO on the basis of their experimental results obtained with an MgO-containing carbon impurity. It is shown that the dissolution mechanism may be linked to an internal redox reaction by which a certain number of lattice oxygens change their formal oxidation state from -2 to -1, while the carbon becomes reduced. The similarities between the mechanisms of CO and/or CO2 dissolution and that of H2O dissolution are pointed out. A hypothesis is proposed concerning the exsolution of reduced carbon from supersaturated solid solutions under conditions which permit C-C bond formation.

Anti-inflammatory, analgesic, and antipyretic activities of virgin coconut oil.

PubMed

Intahphuak, S; Khonsung, P; Panthong, A

2010-02-01

This study investigated some pharmacological properties of virgin coconut oil (VCO), the natural pure oil from coconut [Cocos nucifera Linn (Palmae)] milk, which was prepared without using chemical or high-heat treatment. The anti-inflammatory, analgesic, and antipyretic effects of VCO were assessed. In acute inflammatory models, VCO showed moderate anti-inflammatory effects on ethyl phenylpropiolate-induced ear edema in rats, and carrageenin- and arachidonic acid-induced paw edema. VCO exhibited an inhibitory effect on chronic inflammation by reducing the transudative weight, granuloma formation, and serum alkaline phosphatase activity. VCO also showed a moderate analgesic effect on the acetic acid-induced writhing response as well as an antipyretic effect in yeast-induced hyperthermia. The results obtained suggest anti-inflammatory, analgesic, and antipyretic properties of VCO.

Analysis and control of the dynamical response of a higher order drifting oscillator

PubMed Central

Páez Chávez, Joseph; Pavlovskaia, Ekaterina; Wiercigroch, Marian

2018-01-01

This paper studies a position feedback control strategy for controlling a higher order drifting oscillator which could be used in modelling vibro-impact drilling. Special attention is given to two control issues, eliminating bistability and suppressing chaos, which may cause inefficient and unstable drilling. Numerical continuation methods implemented via the continuation platform COCO are adopted to investigate the dynamical response of the system. Our analyses show that the proposed controller is capable of eliminating coexisting attractors and mitigating chaotic behaviour of the system, providing that its feedback control gain is chosen properly. Our investigations also reveal that, when the slider’s property modelling the drilled formation changes, the rate of penetration for the controlled drilling can be significantly improved. PMID:29507508

Effect of bend faulting on the hydration state of oceanic crust: Electromagnetic constraints from the Middle America Trench

NASA Astrophysics Data System (ADS)

Naif, S.; Key, K.; Constable, S.; Evans, R. L.

2017-12-01

In Northern Central America, the portion of the incoming Cocos oceanic plate formed at the East Pacific Rise has a seafloor spreading fabric that is oriented nearly parallel to the trench axis, whereby flexural bending at the outer rise reactivates a dense network of dormant abyssal hill faults. If bending-induced normal faults behave as fluid pathways they may promote extensive mantle hydration and significantly raise the flux of fluids into the subduction system. Multi-channel seismic reflection data imaged bend faults that extend several kilometers beneath the Moho offshore Nicaragua, coincident with seismic refraction data showing significant P-wave velocity reductions in both the crust and uppermost mantle. Ignoring the effect of fracture porosity, the observed mantle velocity reduction is equivalent to an upper bound of 15-20% serpentinization (or 2.0-2.5 wt% H2O). Yet the impact of bend faulting on porosity structure and crustal hydration are not well known. Here, we present results on the electrical resistivity structure of the incoming Cocos plate offshore Nicaragua, the first controlled-source electromagnetic (CSEM) experiment at a subduction zone. The CSEM data imaged several sub-vertical conductive channels extending beneath fault scarps to 5.5 km below seafloor, providing independent evidence for fluid infiltration into the oceanic crust via bending faults. We applied Archie's Law to estimate porosity from the resistivity observations: the dike and gabbro layers increase from 2.7% and 0.7% porosity at 100 km to 4.8% and 1.7% within 20 km of the trench, respectively. In contrast the resistivity, and hence porosity, remain relatively unchanged at sub-Moho depths. Therefore, either the faults do not provide an additional flux of free water to the mantle or, in light of the reduced seismic velocities, the volumetric expansion resulting from mantle serpentinization rapidly consumes any fault-generated porosity. Since our crustal porosity estimates seaward

[Sedimentological Implications of the change in the coverage of mangrove forest in Boca Zacate, Térraba-Sierpa National Wetlands, Costa Rica].

PubMed

Silva Benavides, Ana Margarita; Picado Barboza, Jorge; Mora Rodríguez, Fernando; González Gairaud, Carmen

2015-09-01

In the last sixty years many geomorphological changes have occurred in Costa Rica's Térraba-Sierpe National Wetlands. Changes in coastal geomorphology are generally associated with erosion or accretion of sediment, which has led to the removal of sections of mangrove forests or sediment banks colonized by mangroves. The aim of this study was to analyze sedimentation as a leading process in the dynamics of coastal morphology and its implications for mangrove forest cover in the Boca Zacate area of Térraba-Sierpe wetlands. The study was conducted in the sectors of Bocón, Brujo and Coco Island in Boca Zacate, from 2008 to 2013. The research was based on a multi-temporal analysis of coastal morphology using aerial photographs from the years 1948, 1960, 1974, 1978, 1984, 1992 and 2011. The following measurements were also performed: monthly sedimentation rate (g/cm2/day), and granulometric composition and content of chemical elements in the sediments of the study area. These last two measurements were performed once each in the dry and rainy seasons during the years of study. The results indicated that over the past 60 years, Boca Zacate has witnessed a process of sustained erosion; from 1948 through 2001, losing 10.6 % of its land and approximately 8.9 % of its forest cover. It has also experienced accretion in the area of Coco Island. The Brujo sector showed the highest sedimentation rate and the Camibar estuary, the lowest. The dominant type of sediment in all study sites was sand, followed by clay and silt. The most widespread chemical elements (mg/L) included magnesium, calcium and potassium; others, such as manganese, iron, aluminum, phosphorus, zinc and copper, were measured in smaller amounts. Transport, composition and quantity of sediment in Boca Zacate are crucial to the changes that have occurred on the coastal area of La Boca, where the presence of dead trees was evident. This geomorphological analysis holds great importance for future guidelines and

Deformation of Forearcs during Aseismic Ridge Subduction

NASA Astrophysics Data System (ADS)

Zeumann, S.; Hampel, A.

2014-12-01

Subduction of aseismic oceanic ridges causes considerable deformation of the forearc region. To identify the crucial parameters for forearc deformation we created 3D finite-element models representing both erosive and accretive forearcs as well as migrating and non-migrating ridges. As natural examples we choose the Cocos ridge subducting stationary beneath the erosive margin of Costa Rica and the Nazca and Gagua Ridges that migrate along the erosive Peruvian margin and the accretive accretive Ryukyu margin, respectively. A series of models show that the deformation of the forearc depends on the ridge shape (height, width), on the frictional coupling along the plate interface and the mechanical strength of the forearc. The forearc is uplifted and moved sideward during ridge subduction. Strain components show domains of both, shortening and extension. Along the ridge axis, extension occurs except at the ridge tip, where shortening prevails. The strain component normal to the ridge axis reveals extension at the ridge tip and contraction above the ridge flanks. Shortening and extension increase with increasing ridge height. Higher friction coefficients lead to less extension and more shortening. Accretive wedges show larger indentation at the model trench. For stationary ridges (Cocos Ridge) the deformation pattern of the forearc is symmetric with respect to the ridge axis whereas for migrating ridges (Nazca Ridge, Gagua Ridge) the oblique convergence direction leads to asymmetric deformation of the forearc. In case of ridge migration, uplift occurs at the leading flank of the ridge and subsidence at the trailing flank, in agreement with field observations and analogue models. For a model with a 200-km-wide and 1500-m-high ridge (i.e. similar to the dimensions of the Nazca Ridge), the modelled uplift rate at the southern ridge flank of the ridge is ~1 mm/a, which agrees well with uplift rates of ~0.7 mm/a derived from the elevation of marine terraces in southern Peru.

Medicinal plants used to treat TB in Ghana.

PubMed

Nguta, Joseph Mwanzia; Appiah-Opong, Regina; Nyarko, Alexander K; Yeboah-Manu, Dorothy; Addo, Phyllis G A

2015-06-01

The current study was designed to document medicinal plant species that are traditionally used to treat tuberculosis (TB) by Ghanaian communities. The medicinal plants used against TB or its signs and symptoms were selected using library and online published data searches. A guided questionnaire interview was also conducted with a botanist involved in plant collection at the Centre for Scientific Research into Plant Medicine (CSRPM) at Mampong. Data obtained were entered in Excel and summarized into means and frequencies using SPSS 12.0.1 for windows, and expressed as tables and bar graphs. A total of 15 medicinal plant species distributed between 13 genera and 13 families were documented. The following medicinal plant species were found to be used against TB in Greater Accra and Eastern parts of Ghana: Azadirachta indica A. Juss. Stem bark (Meliaceae), Hygrophila auriculata Heine, whole plant (Acanthaceae), Chenopodium ambrosioides L. leaves (Amaranthaceae), Coix lacryma-jobi L. glumes (Poaceae), Solanum torvum Sw. unripe fruits (Solanaceae), Solanum torvum Sw. leaves (Solanaceae), Bidens pilosa L. whole plant (Asteraceae), Phyllanthus fraternus G.L. Webster leaves (Phyllanthaceae), Dissotis rotundifolia (Sm.) Triana, leaves (Melastomataceae), Cymbopogon giganteus Chiov. Leaves (Poaceae), Cyperus articulatus L. roots (Cyperaceae), Allium sativum L. bulb (Amaryllidaceae), Zingiber officinale Roscoe, rhizomes (Zingiberaceae), Allium cepa L. bulbs (Amaryllidaceae), Allium cepa L. leaves (Amaryllidaceae), Aloe vera var. barbadensis aqueous extract from leaves (Xanthorrhoeaceae), Aloe vera var. barbadensis organic extract from leaves (Xanthorrhoeaceae), Cocos nucifera Linn, water (Arecaceae) and Cocos nucifera Linn. Husk (Arecaceae). The collected plant species could be a source of a new class of drugs against TB. Bioactivity guided fractionation is recommended to identify lead compounds for antimycobacterial activity. The current paper documents for the first time

Adakitic-like volcanism in Southern Mexico and subduction of the Tehuantepec Ridge

NASA Astrophysics Data System (ADS)

Manea, M.; Manea, V. C.

2007-05-01

The origin of El Chichón volcano is poorly understood, and our attempt in this study is to demonstrate that Tehuantepec Ridge, a major tectonic discontinuity on the Cocos plate, plays a key role in the slab dehydration budget and therefore in partial melting of the mantle beneath El Chichón. Using marine magnetic anomalies we show that the upper mantle beneath TR undergo partial serpentinization, a 5-7 km thick serpentinized root extending along TR and below the oceanic crust. Another key aspect of the magnetic anomaly over southern México is a long-wavelength (~150 km) high amplitude (~500 nT) magnetic anomaly located between the trench and the coast. Using a 2D joint magnetic-gravity forward model, constrained by the subduction P-T structure, slab geometry and seismicity, we find a highly magnetic and low-density source located at 40-130 km depth. We interpret this result as a serpentinized mantle wedge by fluids expelled from the subducting Cocos plate beneath southern Mexico. Such a deep hydrated mantle requires a low temperature wedge (T<600° C) because serpentine is stable below this temperature and also the magnetic properties are preserved for temperature less than the Currie point for magnetite (~580° C). This result explains the lack of volcanism in southern México where the slab depth is ~ 100 km. Using phase diagrams for sediments, basalt and peridotite, and the subduction P-T structure beneath El Chichón we find that sediments and basalt dehydrate ~ 50% at depths corresponding with the location of serpentinized mantle wedge, whereas the serpentinized root beneath TR strongly dehydrates (60-80%) at higher depths (170-180 km) comparable with the slab depth beneath El Chichón. We conclude that this strong deserpentinization pulse of mantle lithosphere beneath TR at great depths triggers arc melting, explaining the unusual location and probably the adakitic signature of El Chichón.

Geometry and velocity structure of the northern Costa Rica seismogenic zone from 3D local earthquake tomography

NASA Astrophysics Data System (ADS)

Deshon, H. R.; Schwartz, S. Y.; Newman, A. V.; Dorman, L. M.; Protti, M.; Gonzalez, V.

2003-12-01

We present results of a 3D local earthquake tomography study of the Middle America Trench seismogenic zone in northern Costa Rica. Local earthquake tomography can provide constraints on the updip, downdip, and lateral variability of seismicity and P- and S-wave velocities; these constraints may in turn provide information on compositional and/or mechanical variability along the seismogenic zone. We use arrival time data recorded by the Nicoya Peninsula seismic array, part of the Costa Rica seismogenic zone experiment (CRSEIZE), a collaborative effort undertaken to better understand seismogenic behavior at the Costa Rica subduction zone using data from land and ocean bottom seismic arrays, oceanic fluid flux meters, and GPS receivers. We invert ˜10,000 P-wave and S-wave arrival times from 475 well-recorded local earthquakes (GAP < 180° , >8 P-wave arrivals) to solve for the best-fitting 1D P- and S-wave velocity models, station corrections, and hypocenters using the algorithm VELEST. These 1D velocity models are used as a starting models for 3D simultaneous inversion using the algorithm SIMULPS14. Preliminary P-wave inversions contain a positive velocity anomaly dipping beneath the Nicoya Peninsula, interpreted as the subducting Cocos Plate. Earthquakes occur in a narrow band along the slab-continent interface and are consistent with the results of Newman et al. (2002). The updip limit of seismicity occurs ˜5 km deeper and 5-10 km landward in the northern vs. the southern Nicoya Peninsula, and this shift spatially correlates to the change from Cocos-Nazca to East Pacific Rise derived oceanic plate. P-wave velocities in the upper 5-10 km of the model are consistent with the geology of the Nicoya Peninsula. We will correlate relocated microseismicity to previously noted variability in oceanic plate morphology, heat flow, fluid flow, and thermal structure and compare the resulting P- and S-wave velocity models to wide-angle refraction models and hypothesized mantle

Cancer Mortality Following Polychlorinated Biphenyl (PCB) Contamination of a Guam Village

PubMed Central

Badowski, Grazyna; Bordallo, Renata

2011-01-01

Beginning more than 10 years after the release of polychlorinated biphenyl (PCB) contamination in the favored fishing grounds of Merizo village, an increase in the proportional cancer mortality rate was observed among residents of the village. This increased rate continued for approximately 20 years after which it returned to near island-wide Guam levels. Although the temporal association between PCB contamination of the environment of this village and an increase in cancer mortality is intriguing, it does not necessarily demonstrate a cause and effect relationship. Objective To investigate a possible temporal relationship between PCB contamination of the Cocos Lagoon and cancer deaths in the adjoining village of Merizo. Methods Data utilized in the study included deaths recorded by the Guam Cancer Registry (years 2000 to 2007) and data collected from original death certificates (years 1968–1999). To check whether there was a significant difference in the proportion of deaths due to cancer in Merizo compared with the rest of Guam, deaths were grouped in four 10-year periods, 1968–1977, 1978–1987, 1988–1997, and 1998–2007, and the Pearson Chi-Square test was calculated for each period separately Results While the number of new cancer cases recorded in the village of Merizo were insufficient in number to draw a statistically significant conclusion when single year incidence rates were compared to the rest of the island, a proportional mortality study showed a distinct increase for the village of Merizo compared to other villages for the period 1978–1997. Conclusion While it is not possible to conclude with certainty that PCB contamination of the Cocos Lagoon was responsible for the observed increase in the proportion of cancer deaths in Merizo village beginning during the 10-year period 1978–1987, that increase and the subsequent decrease as PCB levels also decreased presents the possibility that these trends may be related. PMID:22235158

The 2001 January 13th M {W}7.7 and February 13th M {W}6.6 El Salvador Earthquakes: Deformation and Stress Triggering

NASA Astrophysics Data System (ADS)

Hreinsdóttir, S.; Freymueller, J. T.

2001-12-01

On the 13th of January 2001, an M {W} 7.7 normal fault earthquake occurred offshore El Salvador. The earthquake occurred in the subducting Cocos plate and was followed by high seismic activity and several earthquakes exceeding magnitude 5. On the 13th of February, an M {W} 6.6 strike slip earthquake occurred in the overriding Caribbean plate, about 75 km NNW from the epicenter of the large January earthquake. Deformation due to these earthquakes was observed at six continuous CORS GPS stations in Central America. In the M {W} 7.7 earthquake about 10 mm displacement was measured at GPS stations in El Salvador and Honduras. A smaller but significant dispacement was also observed at GPS stations in Nicaragua, more then 200 km from the earthquake's epicenter. In the M {W} 6.6 earthquake 41+/- 1 mm displacement in direction N111oE was measured at the GPS station in San Salvador, El Salvador. Other CORS GPS stations were not affected by that earthquake. A postsesmic signal is detectable at the San Salvador GPS station, strongest right after the earthquake and then decays. On average we see 0.3 +/- 0.1 mm/day of SSW motion of the station in the first twenty days following the earthquake. Using seismic and geodetic data, we calculated Coulomb stress changes following the January 13th, M {W} 7.7 earthquake. Of special interest were six 5.4 <= {M} {W}<=5.8 thrust events that presumably occurred on the interface between the Caribean and Cocos plate, and the M {W} 6.6 strike slip earthquake that occurred in the overriding Caribean plate. The location and focal mechanism of these earthquakes correlate with areas of calculated increase in static stress thus indicating stress triggering. The thrust events occurred 2 to 20 days after the M {W} 7.7 earthquake, in increasing distance from the M {W} 7.7 event with time.

Stepwise Splitting Growth and Pseudocapacitive Properties of Hierarchical Three-Dimensional Co3O4 Nanobooks

PubMed Central

Chen, Huilong; Lu, Shuang; Gong, Feilong; Liu, Huanzhen; Li, Feng

2017-01-01

Three-dimensional hierarchical Co3O4 nanobooks have been synthesized successfully on a large scale by calcining orthorhombic Co(CO3)0.5(OH)·0.11H2O precursors with identical morphologies. Based on the influence of reaction time and urea concentration on the nanostructures of the precursors, a stepwise splitting growth mechanism can be proposed to understand the formation of the 3D nanobooks. The 3D Co3O4 nanobooks exhibit excellent pseudocapacitive performances with specific capacitances of 590, 539, 476, 453, and 421 F/g at current densities of 0.5, 1, 2, 4, and 8 A/g, respectively. The devices can retain ca. 97.4% of the original specific capacitances after undergoing charge–discharge cycle tests 1000 times continuously at 4 A/g. PMID:28394297

Bond angles in transition-metal tricarbonyl compounds: A test of the theory of hybrid bond orbitals*

PubMed Central

Pauling, Linus

1978-01-01

The theory of hybrid bond orbitals is used to calculate equations giving the value of the bond angle OC—M—CO in relation to the bond number of the metal—carbonyl bond for tricarbonyl groups in which the transition-metal atom is enneacovalent or octacovalent and the group has approximate trigonal symmetry. For cobalt and iron and their congeners the average experimental values lie within about 1° of the theoretical values for enneacovalence, which are 101.9° for Co(CO)3 and 94.5° for Fe(CO)3. This agreement provides strong support for the theory. For Mn(CO)3 and Cr(CO)3 the experimental values indicate the average covalence to be about 8.4 and 7.7, respectively, in agreement with considerations based on the electroneutrality principle. PMID:16592477

Social Image Captioning: Exploring Visual Attention and User Attention

PubMed Central

Chu, Xiaoliang; Zhang, Weishan; Wei, Yiwei; Sun, Weichen; Wu, Chunlei

2018-01-01

Image captioning with a natural language has been an emerging trend. However, the social image, associated with a set of user-contributed tags, has been rarely investigated for a similar task. The user-contributed tags, which could reflect the user attention, have been neglected in conventional image captioning. Most existing image captioning models cannot be applied directly to social image captioning. In this work, a dual attention model is proposed for social image captioning by combining the visual attention and user attention simultaneously.Visual attention is used to compress a large mount of salient visual information, while user attention is applied to adjust the description of the social images with user-contributed tags. Experiments conducted on the Microsoft (MS) COCO dataset demonstrate the superiority of the proposed method of dual attention. PMID:29470409

Social Image Captioning: Exploring Visual Attention and User Attention.

PubMed

Wang, Leiquan; Chu, Xiaoliang; Zhang, Weishan; Wei, Yiwei; Sun, Weichen; Wu, Chunlei

2018-02-22

Image captioning with a natural language has been an emerging trend. However, the social image, associated with a set of user-contributed tags, has been rarely investigated for a similar task. The user-contributed tags, which could reflect the user attention, have been neglected in conventional image captioning. Most existing image captioning models cannot be applied directly to social image captioning. In this work, a dual attention model is proposed for social image captioning by combining the visual attention and user attention simultaneously.Visual attention is used to compress a large mount of salient visual information, while user attention is applied to adjust the description of the social images with user-contributed tags. Experiments conducted on the Microsoft (MS) COCO dataset demonstrate the superiority of the proposed method of dual attention.

Recent volcano monitoring in Costa Rica

USGS Publications Warehouse

Thorpe, R.; Brown, G.; Rymer, H.; Barritt, S.; Randal, M.

1985-01-01

The Costa Rican volacno Rincon de la Vieja is loosely but mysteriously translated as the "Old Lady's Corner." It consists of six volcanic centers that form a remote elongated ridge standing some 1300m above the surrounding terraine. Geologically speaking, the Guanacaste province of northern Costa Rica consists of a series of composite volcanic cones built on a shield of ignimbrites (welded and unwelded ash flows) of Pliocene-Pleistocene age (up to 2 million years old), that themselves lie on basement crust of Cretaceious-Tertiary age (up to 90 million years old). the active volcanoes are aligned on a northwest-southeast axis parallel to the Middle American oceanic trench in the Pacific Ocean that is the site of subduction of hte Cocos oceanic plate underneath Central America.  

Observations of CO on Mars with OMEGA/Mars Express: A Study of Local Variations over the Volcanoes

NASA Astrophysics Data System (ADS)

Encrenaz, T.; Drossart, P.; Fouchet, T.; Melchiorri, R.; Lellouch, E.; Combes, M.; Bibring, J.-P.; Moroz, V.; Ignatiev, N.; Forget, F.; OMEGA Team

Spectra of Mars recorded with the OMEGA/Mars Express experiment have been used to retrieve information on the CO mixing ratio over the planet. By using simultaneously the CO (1-0) band at 4.7 microns and a weak CO2 band at 4.85 microns, we have inferred the CO mixing ratio in all regions where the thermal emission is dominent, i.e. where the surface temperature is maximum. These observations, in particular, indicate a significant depletion of the CO/CO2 ratio over Olympus Mons. This preliminary result seems to confirm the analysis performed by the ISM imaging spectrometer aboard the Phobos mission, which suggested a possible depletion of CO over the volcanoes (Rosenqvist et al., Icarus 98, 254, 1992). Implications of this result will be discussed.

Formation of Hierarchical Cu-Doped CoSe2 Microboxes via Sequential Ion Exchange for High-Performance Sodium-Ion Batteries.

PubMed

Fang, Yongjin; Yu, Xin-Yao; Lou, Xiong Wen David

2018-04-06

Electrode materials based on electrochemical conversion reactions have received considerable interest for high capacity anodes of sodium-ion batteries. However, their practical application is greatly hindered by the poor rate capability and rapid capacity fading. Tuning the structure at nanoscale and increasing the conductivity of these anode materials are two effective strategies to address these issues. Herein, a two-step ion-exchange method is developed to synthesize hierarchical Cu-doped CoSe 2 microboxes assembled by ultrathin nanosheets using Co-Co Prussian blue analogue microcubes as the starting material. Benefitting from the structural and compositional advantages, these Cu-doped CoSe 2 microboxes with improved conductivity exhibit enhanced sodium storage properties in terms of good rate capability and excellent cycling performance. © 2018 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

Structural investigation of Bi doped InSe chalcogenide thin films using Raman spectroscopy

NASA Astrophysics Data System (ADS)

Sharma, Shaveta; Sharma, Rita; Kumar, Praveen; Chander, Ravi; Thangaraj, R.; Mian, M.

2015-05-01

The infrared transparency of the chalcogenide glasses have been investigated presently for the CO/CO2 laser power in various medical diagnostic applications. The addition of Bi improves the chemical durability and broadens the IR transparency region of various chalcogenide glassy systems. In the present work, we have studied the effect of Bi addition on the structural properties of In-Se thin films by using the RAMAN spectroscopy. The melt quenched bulk ingot of BixIn25-xSe75 (1≤ x≤ 7) alloys were used for the vacuum thermal evaporation of films in a vacuum better than 10-5 mbar. RAMAN bands at 1575, 1354 and 525 cm-1 has been observed, while with the increase in the Bi concentration vibrational band disappear at 525 cm-1 in sample x=7.

Detection of aflatoxigenic aspergillus flavus contamination of coconut (cocos nucifera) nutmeat (copra) using ammonia treatment

USDA-ARS?s Scientific Manuscript database

For many crops government regulations define mycotoxin contamination levels that represent the primary determinants of quality, value and possible uses of crops. Quality can be raised in some crops by lowering the mycotoxin level through removal of infected products. In the case of copra, the drie...

Visualization of aflatoxigenic Aspergillus flavus contamination of coconut (Cocos nucifera) nutmeat (Copra) using ammonia treatment

USDA-ARS?s Scientific Manuscript database

For many crops government regulations define mycotoxin contamination levels that reflect the primary determinants of quality, value and possible uses of crops. Quality can be raised by lowering the mycotoxin level through a remediation process. In the case of copra, the dried nutmeat of the coconu...

Variability in coconut (Cocos nucifera L.) germplasm and hybrids for fatty acid profile of oil.

PubMed

Kumar, S Naresh

2011-12-28

Coconut oil, the main product of coconut fruit, is the richest source of glycerol and lauric acid and hence is called lauric oil. This paper reports the fatty acid profile of oil from 60 Talls, 14 Dwarfs, and 34 hybrids. These include collections from 13 countries covering a large coconut-growing area of the world, apart from the indigenous ones. Capillary gas chromatography analysis of oil indicated a wider variation for the fatty acid profile than earlier reported. Apart from this, for the first time other fatty acids such as behenic and lignoceric acids were detected. Oil from cultivars and hybrids of coconut has significantly differed, particularly for commercially important fatty acids such as lauric acid and unsaturated fatty acids. However, coconut oil seems to have a conserved fatty acid profile, mainly because of low unsaturated fatty acids, indicating the possibility of grouping cultivars on the basis of their fatty acid profiles. The cluster analysis based on fatty acid profile indicated grouping together of geographically and typically closely related cultivars. Cultivars with high concentrations of specific fatty acids can be of potential use for industrial exploitation, whereas those with high concentrations of short- and medium-chain fatty acids and unsaturated fatty acids are more suitable for human consumption. Cultivars and hybrids with high and low values for each of the fatty acids are also identified.

Village agroforestry systems and tree-use practices: A case study in Sri Lanka. Multipurpose tree species network research series

DOE Office of Scientific and Technical Information (OSTI.GOV)

Wickramasinghe, A.

1992-01-01

Village agroforestry systems in Sri Lanka have evolved through farmers' efforts to meet their survival needs. The paper examines farmers' land-use systems and their perceptions of the role of trees in the villages of Bambarabedda and Madugalla in central Sri Lanka. The benefits of village agroforestry are diverse food, fuelwood, fodder, timber, and mulch, but food products are of outstanding importance. The ability of Artocarpus heterophyllus (the jackfruit tree) and Cocos nucifera (coconut) to ensure food security during the dry season and provide traditional foods throughout the year, as well as to grow in limited space, make them popular cropsmore » in the two study villages. The study recommends that further research precede the formulation of agricultural interventions and that efforts to promote improved tree varieties recognize farmers' practices and expressed needs.« less

Present-day kinematics of the Rivera plate and implications for tectonics in southwestern Mexico

NASA Technical Reports Server (NTRS)

Demets, Charles; Stein, Seth

1990-01-01

A model for the present-day motion of the Rivera plate relative to the North America, Cocos, and Pacific plates is derived using new data from the Pacific-Rivera rise and Rivera transform fault, together with new estimates of Pacific-Rivera motions. The results are combined with the closure-consistent NUVEL-1 global plate motion model of DeMets et al. (1990) to examine present-day deformation in southwestern Mexico. The analysis addresses several questions raised in previous studies of the Rivera plate. Namely, do plate motion data from the northern East Pacific rise require a distinct Rivera plate? Do plate kinematic data require the subduction of the Rivera plate along the seismically quiescent Acapulco trench? If so, what does the predicted subduction rate imply about the earthquake recurrence interval in the Jalisco region of southwestern Mexico?

Forest bird and fruit bat populations on Sarigan, Mariana Islands

USGS Publications Warehouse

Fancy, Steven G.; Craig, Robert J.; Kessler, Curt T.

1999-01-01

We conducted the first quantitative surveys of forest bird and bat populations on the uninhabited island of Sarigan, Commonwealth of the Northern Mariana Islands. Severe habitat degradation has occurred on Sarigan because of overgrazing by introduced goats and pigs. Planting of coconut palms (Cocos nucifera) for copra production has also eliminated much of the island’s native forest. We recorded five species of forest birds on Sarigan: Micronesian Honeyeater (Myzomela rubratra), Micronesian Megapode (Megapodius laperouse laperouse), Micronesian Starling (Aplonis opaca), Collared Kingfisher (Halcyon chloris), and White-throated Ground Dove (Gallicolumba xanthonura). Estimated population sizes (95% confidence interval) in 1997 were 1,821 (1,617–2,026) for Micronesian Honeyeater, 677 (545–810) for Micronesian Megapode, 497 (319–675) for Micronesian Starling, 107 (82–131) for Collared Kingfisher, and 170 (101–238) for Mariana Fruit Bat (Pteropus mariannus).

Hierarchical cobalt-based hydroxide microspheres for water oxidation.

PubMed

Zhang, Ye; Cui, Bai; Derr, Olivia; Yao, Zhibo; Qin, Zhaotong; Deng, Xiangyun; Li, Jianbao; Lin, Hong

2014-03-21

3D hierarchical cobalt hydroxide carbonate hydrate (Co(CO3)0.5(OH)·0.11H2O) has been synthesized featuring a hollow urchin-like structure by a one-step hydrothermal method at modest temperature on FTO glass substrates. The functionalities of precursor surfactants were isolated and analyzed. A plausible formation mechanism of the spherical urchin-like microclusters has been furnished through time-dependent investigations. Introduction of other transitional metal doping (Cu, Ni) would give rise to a substantial morphological change associated with a surface area drop. The directly grown cobalt-based hydroxide composite electrodes were found to be capable of catalyzing oxygen evolution reaction (OER) under both neutral pH and alkaline conditions. The favorable 3D dendritic morphology and porous structure provide large surface areas and possible defect sites that are likely responsible for their robust electrochemical activity.

Synthesis and Structural Characterization of a Novel Indium Mercapto Derivative [clln(sch2(co)o)2]2-[(4-mepyh)2]2+

NASA Technical Reports Server (NTRS)

Banger, Kulbinder K.; Duraj, Stan A.; Fanwick, Philip E.; Hepp, Aloysius F.; Martock, Robert A.

2004-01-01

The synthesis and structural characterization of a novel In(III) complex is described. The reaction between InCl3 with sodium mercapto-acetic acid, (NaSCH2(CO)OH) in 4-methylpyridine, (CH3(C5H5N), (4-Mepy)) at 25 C affords [ClIn(SCH2(CO)O)2]2- [(4-MepyH)2]2+. X-ray diffraction studies show it to have a distorted square pyramidal geometry, with the [(-SCH2(CO)CO-)] ligands in a trans conformation. The compound crystallizes in the P(raised dash) 1 (No. 2) space group with a = 7.8624 Angstrom, b = 9.950 Angstrom, c = 13.793 Angstrom, alpha = 107.60 degrees, beta= 90.336 degrees, gamma = 98.983 degrees, V = 1014.3 Angstroms (sup 3), R(F(raised circle)) = 0.037, and R(sub w) = 0.048.

(Carbonato-κO,O')bis-(di-2-pyridyl-amine-κN,N')cobalt(III) bromide.

PubMed

Czapik, Agnieszka; Papadopoulos, Christos; Lalia-Kantouri, Maria; Gdaniec, Maria

2011-04-01

In the title compound, [Co(CO(3))(C(10)H(9)N(3))(2)]Br, a distorted octa-hedral coordination of the Co(III) atom is completed by four N atoms of the two chelating di-2-pyridyl-amine ligands and two O atoms of the chelating carbonate anion. The di-2-pyridyl-amine ligands are nonplanar and the dihedral angles between the 2-pyridyl groups are 29.11 (9) and 37.15 (12)°. The coordination cation, which has approximate C(2) symmetry, is connected to the bromide ion via an N-H⋯Br(-) hydrogen bond. The ionic pair thus formed is further assembled into a dimer via N-H⋯O inter-actions about an inversion centre. A set of weaker C-H⋯O and C-H⋯Br(-) inter-actions connect the dimers into a three-dimensional network.

Real-world automotive emissions—Summary of studies in the Fort McHenry and Tuscarora mountain tunnels

NASA Astrophysics Data System (ADS)

Pierson, William R.; Gertler, Alan W.; Robinson, Norman F.; Sagebiel, John C.; Zielinska, Barbara; Bishop, Gary A.; Stedman, Donald H.; Zweidinger, Roy B.; Ray, William D.

Motor vehicle emission rates of CO, NO, NO x, and gas-phase speciated nonmethane hydrocarbons (NMHC) and carbonyl compounds were measured in 1992 in the Fort McHenry Tunnel under Baltimore Harbor and in the Tuscarora Mountain Tunnel of the Pennsylvania Turnpike, for comparison with emission-model predictions and for calculation of the reactivity of vehicle emissions with respect to O 3 formation. Both tunnels represent a high-speed setting at relatively steady speed. The cars at both sites tended to be newer than elsewhere (median age was < 4 yr), and much better maintained as judged by low CO/CO2 ratios and other emissions characteristics. The Tuscarora Mountain Tunnel is flat, making it advantageous for testing automotive emission models, while in the underwater Fort McHenry Tunnel the impact of roadway grade can be evaluated. MOBILE4.1 and MOBILES gave predictions within ± 50% of observation most of the time. There was a tendency to overpredict, especially with MOBILES and especially at Tuscarora. However, light-duty-vehicle CO, NMHC, and NO x, all were underpredicted by MOBILE4.1 at Fort McHenry. Light-duty-vehicle CO/NOx ratios and NMHC/NO x, ratios were generally a little higher than predicted. The comparability of the predictions to the observations contrasts with a 1987 experiment in an urban tunnel (Van Nuys) where CO and HC, as well as CO/NOx, and NMHC/NO x, ratios, were grossly underpredicted. The effect of roadway grade on gram per mile (g mi -1) emissions was substantial. Fuel-specific emissions (g gal -1), however, were almost independent of roadway grade, which suggests a potential virtue in emissions models based on fuel-specific emissions rather than g mi -1) emissions. Some 200 NMHC and carbonyl emissions species were quantified as to their light- and heavy-duty-vehicle emission rates. The heavy-duty-vehicle NMHC emissions were calculated to possess more reactivity, per vehicle-mile, with respect to O 3 formation (g O 3 per vehicle-mile) than did

Antibacterial Efficacy of Tender Coconut Water (Cocos nucifera L) on Streptococcus mutans: An In-Vitro Study

PubMed Central

Rukmini, J. N.; Manasa, Sunkari; Rohini, Chenna; Sireesha, Lavanya Putchla; Ritu, Sachan; Umashankar, G. K.

2017-01-01

Objective: The antibacterial property of coconut, the presence of lauric acid, and the ability to extract antimicrobial peptides Cn-AMP (1, 2, and 3) from tender coconut water has drawn attention on its effectiveness in normal consumption. An in-vitro experimental study was conducted to evaluate the antimicrobial efficacy of tender coconut water in its natural state on Streptococcus mutans. Materials and Methods: Fresh tender coconut water and pasteurized tender coconut water were taken as test samples, dimethyl formamide was used as the negative control, and 0.2% chlorhexidine was used as the positive control. Pure strain of S. mutans (MTCC 890) was used for determining the antibacterial effects. The test samples along with the controls were subjected to antimicrobial sensitivity test procedure and the zone of inhibition was examined. Kruskal–Wallis test was used to check for any significant differences in the antibacterial efficacy between the samples. Result: There was no zone of inhibition with the tender coconut water, fresh and pasteurised, and negative control (dimethyl formamide). Zone of inhibition was seen in positive control (0.2% Chlorhexidine). Conclusion: No antimicrobial activity was demonstrated with tender coconut water in its normal state (in vitro). PMID:28462183

Determination of cytokinins in coconut (Cocos nucifera L.) water using capillary zone electrophoresis-tandem mass spectrometry.

PubMed

Ge, Liya; Yong, Jean Wan Hong; Tan, Swee Ngin; Ong, Eng Shi

2006-06-01

The applicability of CZE in combination with MS and MS/MS methods for the simultaneous separation and determination of 12 cytokinins was investigated for the first time. Cytokinins were first completely separated by CZE within less than 20 min using a volatile buffer and then detected directly by MS or MS/MS. Satisfactory separation of the 12 cytokinin standards was achieved using a 25 mM ammonium formate/formic acid buffer (pH 3.4) and 3% ACN v/v with a separation voltage of 25 kV. On the basis of the resolution of the neighboring peaks, the various parameters for CZE-MS optimization, such as buffer pH value, concentration of buffer and organic modifier, applied voltage and sheath liquid, were evaluated systematically. MS/MS with multiple reaction monitoring detection was carried out to obtain sufficient selectivity and sensitivity. The combination of on-line sample stacking and CZE-MS/MS achieved a detection limit in the range of 0.05-0.18 microM for the 12 cytokinins at an S/N of 3. The optimized CZE-MS/MS method was simple, rapid, low cost, robust and highly selective. Furthermore, the developed method was successfully applied to screen for endogenous cytokinins in purified coconut water extract sample. Nine cytokinins were detected and quantified in coconut water after SPE.

Physicochemical and Phytochemical Analyses of Copra and Oil of Cocos nucifera L. (West Coast Tall Variety)

PubMed Central

Ghosh, Probir Kumar; Bhattacharjee, Paramita; Mitra, Souvik; Poddar-Sarkar, Mousumi

2014-01-01

Coconut copra from West coast tall variety, cultivated in Kerala, India, was subjected to aqueous and solvent extractions (using n-hexane). Additionally, oil was extracted from the copra in Soxhlet assembly using petroleum ether (b.p. 60–80°C). Physicochemical and phytochemical analyses were conducted for the extracts and the oil, with commercial coconut oil as the experimental control. The physicochemical analyses showed that the aqueous extract of copra was milky-white in color with a sweet odor, while the solvent extract was pale yellow and odorless. The commercial oil had 0.08 ± 0.02% oleic acid and a TOTOX value of 7.73 ± 0.78, lower than the Soxhlet extracted oil. Among all the extracts and oils, best phytochemical properties, antioxidant activity (DPPH activity, IC50 value 0.04 ± 0.01 mg/mL), total phenol (0.96 ± 0.04 mg gallic acid eq./g dry copra), reducing power (40.49 ± 1.84 mg BHT eq./g dry copra), and anti-inflammatory activity (NO activity, IC50  value 0.77 ± 0.06 mg/mL) were obtained in the commercial coconut oil, followed by the Soxhlet extracted oil, aqueous extract, and solvent extract. Fatty acid composition analyses showed mainly medium chain fatty acids in the copra oil with lauric acid as the predominant fatty acid (51.88% and 44.84% in Soxhlet extracted and commercial oils, resp.). PMID:26904626

Physicochemical and Phytochemical Analyses of Copra and Oil of Cocos nucifera L. (West Coast Tall Variety).

PubMed

Ghosh, Probir Kumar; Bhattacharjee, Paramita; Mitra, Souvik; Poddar-Sarkar, Mousumi

2014-01-01

Coconut copra from West coast tall variety, cultivated in Kerala, India, was subjected to aqueous and solvent extractions (using n-hexane). Additionally, oil was extracted from the copra in Soxhlet assembly using petroleum ether (b.p. 60-80°C). Physicochemical and phytochemical analyses were conducted for the extracts and the oil, with commercial coconut oil as the experimental control. The physicochemical analyses showed that the aqueous extract of copra was milky-white in color with a sweet odor, while the solvent extract was pale yellow and odorless. The commercial oil had 0.08 ± 0.02% oleic acid and a TOTOX value of 7.73 ± 0.78, lower than the Soxhlet extracted oil. Among all the extracts and oils, best phytochemical properties, antioxidant activity (DPPH activity, IC50 value 0.04 ± 0.01 mg/mL), total phenol (0.96 ± 0.04 mg gallic acid eq./g dry copra), reducing power (40.49 ± 1.84 mg BHT eq./g dry copra), and anti-inflammatory activity (NO activity, IC50  value 0.77 ± 0.06 mg/mL) were obtained in the commercial coconut oil, followed by the Soxhlet extracted oil, aqueous extract, and solvent extract. Fatty acid composition analyses showed mainly medium chain fatty acids in the copra oil with lauric acid as the predominant fatty acid (51.88% and 44.84% in Soxhlet extracted and commercial oils, resp.).

Antibacterial Efficacy of Tender Coconut Water (Cocos nucifera L) on Streptococcus mutans: An In-Vitro Study.

PubMed

Rukmini, J N; Manasa, Sunkari; Rohini, Chenna; Sireesha, Lavanya Putchla; Ritu, Sachan; Umashankar, G K

2017-01-01

The antibacterial property of coconut, the presence of lauric acid, and the ability to extract antimicrobial peptides Cn-AMP (1, 2, and 3) from tender coconut water has drawn attention on its effectiveness in normal consumption. An in-vitro experimental study was conducted to evaluate the antimicrobial efficacy of tender coconut water in its natural state on Streptococcus mutans . Fresh tender coconut water and pasteurized tender coconut water were taken as test samples, dimethyl formamide was used as the negative control, and 0.2% chlorhexidine was used as the positive control. Pure strain of S. mutans (MTCC 890) was used for determining the antibacterial effects. The test samples along with the controls were subjected to antimicrobial sensitivity test procedure and the zone of inhibition was examined. Kruskal-Wallis test was used to check for any significant differences in the antibacterial efficacy between the samples. There was no zone of inhibition with the tender coconut water, fresh and pasteurised, and negative control (dimethyl formamide). Zone of inhibition was seen in positive control (0.2% Chlorhexidine). No antimicrobial activity was demonstrated with tender coconut water in its normal state ( in vitro ).

Synthesis of Composite Adsorbent from Calcium Carbonate and Cocos Nucifera Carbon Powder Crosslinked with Biopolymer Matrix

NASA Astrophysics Data System (ADS)

Kamaruddin, M. A.; Bakri, M. M. A.; Norashiddin, F. A.; Zawawi, M. H.; Zainol, M. R. R. A.

2018-03-01

The use of coconut shell based adsorbent for removing various pollutants from wastewater offers attractive advantages such as exceptional adsorption capacity with larger surface area, low-cost and biocompatibility for a wide range of pollutants. The same goes for calcium carbonate based adsorbent, which provides better removal for metals ions through precipitation method. In fact, recycling of waste material is considered environmentally preferable and is supported by public opinion and government policy. However, because of unit operations mechanisms and effectiveness are different to one another in downstream process, it is quite difficult to provide good adsorbent that exhibits dual attributes of hydrophobic and hydrophilic characters. This paper provides brief process for sintering of composite adsorbent for separation and purification of industrial wastewater application. Characterization was performed by physical and chemical approach. Results prove that the inclusion of biopolymer as composite binder improved mechanical properties of the composite adsorbent.

Earthquake cycle deformation in Mexico and Central America constrained by GPS: Implications for coseismic, postseismic, and slow slip

NASA Astrophysics Data System (ADS)

Graham, Shannon E.

Using surface deformation measured by GPS stations within Mexico and Central America, I model coseismic slip, Coulomb stress changes, postseismic afterslip, and slow slip events in order to increase our knowledge of the earthquake deformation cycle in seismically hazardous regions. In Chapter 1, I use GPS data to estimate coseismic slip due to the May 28, 2009 Swan Islands fault earthquake off the coast of Honduras and then use the slip distribution to calculate Coulomb stress changes for the earthquake. Coulomb stress change calculations resolve stress transfer to the seismically hazardous Motagua fault and further show an unclamping of normal faults in northern Honduras. In Chapter 2, the focus shifts to southern Mexico, where continuous GPS measurements since the mid-1990s are revolutionizing our understanding of the flatly subducting Cocos plate. I perform a time-dependent inversion of continuous GPS observations of the 2011-2012 slow slip event (SSE) to estimate the location and magnitude of slow slip preceding the March 20, 2012 Ometepec earthquake. Coulomb stress changes as a result of slip during the SSE are consistent with the hypothesis that the SSE triggered the Ometepec earthquake. Chapter 3 describes inversions for slip both during and after the Ometepec earthquake. Time-dependent modeling of the first six months of postseismic deformation reveals that fault afterslip extended ˜250 km inland to depths of ˜50 km along the Cocos plate subduction. The postseismic afterslip and previous SSEs in southern Mexico occur at similar depths down-dip from the seismogenic zone, indicating that transitional areas of the subduction interface underlie much of southern Mexico. Finally, I perform the first time-dependent modeling of SSEs below Mexico and the first to exploit all available continuous GPS stations in southern and central Mexico. The results provide a more complete and consistent catalog of modeled SSE for the Mexico subduction zone (MSZ) than is

Relationship Between Subduction Erosion, Seamount Subduction, Fluid Venting and Mound Formation on the Slope of the Costa Rican Continental Margin

NASA Astrophysics Data System (ADS)

Petersen, C.; Klaucke, I.; Weinrebe, W.

2006-12-01

The oceanic crust off central Costa Rica northwest of the Cocos Ridge is dominated by chains of seamounts rising 1-2 km above the seafloor with diameters of up to 20 km. The subduction of these seamounts leads to strong indentations, scars and slides on the continental margin. A smoother segment of about 80 km width is located offshore Nicoya peninsula. The segment ends at a fracture zone which marks the transition of oceanic crust created at the Cocos-Nazca spreading center (CNS) and at the East Pacific Rise (EPR). Offshore Nicaragua the incoming EPR crust is dominated by bending related faults. To investigate the relationship between subduction erosion, fluid venting and mound formation, multibeam bathymetry and high-resolution deep-tow sidescan sonar and sediment echosounder data were acquired during R/V Sonne cruises SO163 and SO173 (2002/2003). The deep-tow system consisted of a dual-frequency 75/410 kHz sidescan sonar and a 2-12 kHz chirp sub-bottom profiler. The connection of the observed seafloor features to deeper subduction related processes is obtained by analysis of multi-channel streamer (MCS) data acquired during cruises SO81 (1992) and BGR99 (1999). Data examples and interpretations for different settings along the margin are presented. Near the Fisher seamount the large Nicoya slump failed over the flank of a huge subducted seamount. The sidescan and echosounder data permit a detailed characterization of fault patterns and fluid escape structures around the headwall of the slump. Where the fracture zone separating CNS and EPR crust subducts, the Hongo mound field was mapped in detail. Several mounds of up to 100 m height are located in line with a scar possibly created by a subducting ridge of the fracture zone. MCS data image a topographic high on the subducting oceanic crust beneath the mound field which lead to uplift and possibly enabled ascent of fluids from the subducting plate. The combined analysis of geoacoustic and seismic MCS data

Mega-pockmarks surrounding IODP Site U1414: Insights from the CRISP 3D seismic survey

NASA Astrophysics Data System (ADS)

Nale, S. M.; Kluesner, J. W.; Silver, E. A.; Bangs, N. L.; McIntosh, K. D.; Ranero, C. R.

2013-12-01

Visualization of neural network meta-attribute analyses reveals fluid migration pathways associated with mega-pockmarks within the CRISP 3D seismic volume offshore southern Costa Rica, near site U1414 of IODP Expedition 344. A 245km2 field of mega-pockmarks was imaged on the Cocos Ridge using EM122 multibeam bathymetry, backscatter and 3D seismic reflection aboard R/V Marcus G. Langseth during the 2011 CRISP seismic survey. We utilize the OpendTect software package to calculate supervised neural network meta-attributes within the 3D seismic volume, in order to detect and visualize probable faults and fluid-migration pathways within the sedimentary section of the incoming Cocos plate [see Kluesner et al., this meeting]. Pockmarks imaged within the 3D volume near the trench commonly show a two-tier structure with upper pockmarks located above the steep walls of deeper, older pockmarks. The latter appear to truncate surrounding strata, including widespread high-amplitude reverse polarity reflectors (RPRs), interpreted as trapping horizons. In addition, RPRs are also truncated by positive polarity crosscutting reflections (CCRs), most of which form the base and sides of lens-like structures below the RPRs that are frequently located next to imaged pockmarks. Site U1414 intersects one of these lens-like structures and this appears to correlate to a sharp density and porosity swing observed at ~255 mbsf. In addition, preliminary geochemical analyses from site U1414 show evidence of lateral fluid flow through sediments below the RPR [Expedition 344 Scientists, 2013]. Thus, we interpret the 3D lens-like structures to be pockets of trapped gas and/or over-pressured fluid. Based on 3D imaging we propose a 3-stage pockmark evolution: (1) Overpressure and blowout along RPRs, resulting in pockmark formation, (2) sustained seepage along pockmark walls, resulting in preferential deposition near the center of the pockmark, and (3) rapid burial as pockmarks near the trench axis. On

DOE Office of Scientific and Technical Information (OSTI.GOV)

Carpenter, Alex E.; Chan, Chinglin; Rheingold, Arnold L.

The m-terphenyl isocyanide complex, HCo(CNAr Mes2) 4 (Ar Mes2 = 2,6-(2,4,6-Me 3C 6H 2) 2C 6H 3), serves as a unique example of a well-defined isocyano analogue to HCo(CO) 4. Given the well documented Brønsted acidity of HCo(CO) 4 in both protic and nonprotic media, the Brønsted acidity of HCo(CNAr Mes2) 4 was assessed for a quantitative comparison. Acid bracketing experiments in THF solution revealed that HCo(CNAr Mes2) 4 has a Morris relative pK α THF value of 38.5-40.7, which is considerably higher than that of HCo(CO) 4 (pK α THF (calc) = 11.4) and thereby indicates insignificant Brønsted acidity.more » Furthermore, the relative acidity of HCo(CNAr Mes2) 4 rivals that of tetra-phosphine cobalt hydrides (i.e., HCo(PR 3) 4; pK α THF (calc) ≥ 48), despite the good π-acidity properties of the isocyano unit. To systematically determine the effect of substituting an isocyanide for a CO ligand on the acidity of the Co-H unit in HCoL 4 complexes, the full series of HCo(CO) n(CNAr Mes2) 4-n monohydrides and [Co(CO) n(CNAr Mes2) 4-n] - (n = 1-4) metalates were prepared and characterized. Acid bracketing studies on the [Co(CO) n(CNAr Mes2) 4-n] - metalates in THF solution revealed a regular progression of increasing pK α THF values as isocyanides are added to the Co center. However, the monoisocyanide tricarbonyl hydride, HCo(CO) 3(CNAr Mes2), possesses a pK α THF value of 28.6-32.5, which is also significantly higher than that of HCo(CO) 4 and the monophosphine complex HCo(CO) 3(PPh 3). Accordingly, the unconventional ability of isocyanide ligands to function as stronger σ-donors than organophosphines is discussed within the context of both the Brønsted acidity and spectroscopic features of the HCo(CO) n(CNAr Mes2) 4-n monohydrides.« less

222 Aerobiological and Immunological Studies on Coconut Pollen Allergy

PubMed Central

Saha, Bodhisattwa; Bhattacharya, Swati Gupta

2012-01-01

Background Pollen grains constitute a significant portion of the aerobiological flora. The plant Coccos nucifera (commonly known as coconut) is found in huge quantities in the tropical coastal areas of the world and is very common in Kolkata, India. A 2 years aerobiological survey was carried out using Burkard Volumetric Sampler to know the seasonal variation of Cocos nucifera pollen. The plant flower through out the year but maximum concentration was found in the month of August. Allergenicity of Cocos nucifera pollen has been reported from the Skin Prick Test, Lung function test, ELISA from a 400 susceptible patients in and around West Bengal in India. An immunobiological study was conducted to identify major allergens from Coccos nucifera pollen causing hay fever, skin allergy and allergic asthma in Kolkata population. Methods Proteins from pollen grains were obtained by initially defatting and then extracted with sodium phosphate buffer with 10 mM PMSF. Total protein was divided into 4 fractions by ammonium sulfate at 25%, 50 %, 75% and 100% respectively. SDS PAGE was done with the 25% fraction (result obtained from dot blotting) and subsequently western blotting was performed. Two dimensional gel electrophoresis and immunoblotting was also done from the crude protein. Results The total protein was separated on a SDS PAGE gel showed 21 prominent bands by Coomassie Blue staining. Dot -blotting the different fractions from ammonium sulfate cut, showed a positive result in the 25% fraction. Western blot with patient specific sera gave 3 bands out of which a major band was obtained at 60Kd. This result was obtained in more than 65% of the patients from whom Sera was isolated. 2D gel electrophoresis of the crude protein sample was performed which showed 120 protein spots in the PI range of 3 to 10 and molecular weight 14Kd to 97Kd. Immunoblotting the 2D gel with pooled patient specific sera showed 20 spots thus implying IgE reactivity. Conclusions It can thus be

CO2 Emissions from the Los Angeles Basin During Spring of 2010 - Measurements vs. Model

NASA Astrophysics Data System (ADS)

Newman, S.; Jeong, S.; Fischer, M. L.; Xu, X.; Gurney, K. R.; Alvarez, S. L.; Rappenglueck, B.; Haman, C. L.; Lefer, B. L.; Miller, C. E.; Yung, Y. L.

2011-12-01

More than half of the world's population now lives in urban areas, contributing large fluxes of greenhouse gas to the atmosphere. Quantifying the spatiotemporal distribution of these emissions is critical for providing independent verification of future mitigation activities. We have used high precision measurements of CO2 and CO to determine the contribution of fossil fuel combustion (ffCO2 mixing ratio) to the total CO2 emissions in the Los Angeles basin during the CalNex-LA ground campaign of May-June 2010 in Pasadena. The ratio of COxs/CO2xs (the excess of each species above free tropospheric levels) varies significantly by time of day, giving a proxy for the fraction of ffCO2/CO2xs. Using an emission ratio for CO/CO2 for fossil fuel combustion of 0.011±0.002 (Wunch et al., 2009, Geophys Res Lett 36, L15810), we determined that burning of fossil fuels contributed ~50% overnight - 100% during midday of the total local contribution, resulting in ffCO2 of 13 - 23 ppm, respectively. These values compare very well with those calculated from Δ14C for measurements of two samples aggregated from 7-8 flask samples collected at 14:00 PST on alternate days during the first and second half of the CalNex-LA campaign: 17 and 24 ppm ffCO2, respectively. We then compared the measured values of ffCO2 with predictions combining a diurnally averaged version of the Vulcan 2.0 ffCO2 emission inventory (http://www.purdue.edu/eas/carbon/vulcan/index.php) and mesoscale transport computed with the Weather Research and Forecast (WRF) and Stochastic Time-Inverted Lagrangian Transport (STILT) models. To evaluate transport model uncertainty, we compared predicted and measured planetary boundary layer height (PBLH) and found WRF predictions compared favorably with ceilometer measurements made during the day at the Pasadena site. Initial comparison of the diurnal cycle of ffCO2 determined by the CO/CO2 ratios to that predicted with a temporally constant map of diurnal mean emissions shows

The Seismic Strong Motion Array Project (SSMAP) and the September 5, 2012 Mw=7.6 Nicoya, Costa Rica Earthquake

NASA Astrophysics Data System (ADS)

Simila, Gerald; Mohammadebrahim, Ehsan; McNally, Karen; Quintero, Ronnie; Segura, Juan

2014-05-01

Seismic gaps along the subduction zones are locations where large earthquakes have not occurred in a long time. The Cocos plate is subducting beneath the Caribbean plate in Costa Rica, and the Nicoya Peninsula, located in northwestern Costa Rica, has been identified as a seismic gap. The previous major earthquakes in Nicoya occurred on 1853, 1900 and 1950, which indicates about a 50-year recurrence interval for the characteristic earthquake cycle. Since 2006, the seismic strong motion array project (SSMAP) for the Nicoya Peninsula in northwestern Costa Rica has been composed of 10 sites with Geotech A900/A800 accelerographs (three-component) and GPS timing. Our digital accelerographs array has been deployed as part of our ongoing research on large earthquakes, including the potential Nicoya event, in conjunction with the Earthquake and Volcano Observatory (OVSICORI) at the Universidad Nacional in Costa Rica. From 2006 to 2012, 28 events were relocated using the SSMAP and OVSICORI data with moderate magnitudes (4 < Mw< 6.5), and were mainly located in Nicoya Peninsula region. On September 5, 2012, a Mw=7.6 earthquake occurred in the seismic gap and appears to be the expected event based on the 50 years recurrence interval, but was instead 62 years later. The main shock focal mechanism was thrust faulting, propagating downdip, of the Cocos plate in the Middle America trench with strike N54W and dip 20 degrees NE. The mainshock and 15 early aftershocks were relocated by using SSMAP, OVSICORI, and UCSC networks. The final location of the mainshock is 9.671 N and 85.878 W with a depth of 18 km. The maximum accelerations from two A900 stations perpendicular to the trench, Fortuna (distance 112km) and Pedernal (distance 128 km) are: 13.8% and 8.9 % g, respectively. In addition, the October 10 (MW 5.3) and 24(Mw 6.6) aftershocks recorded at Tamarindo (distances 40 km and 70 km, respectively) showed accelerations of 2.4% and 8.2% g; respectively. The mainshock acceleration

A Well-Defined Isocyano Analogue of HCo(CO) 4. 2: Relative Brønsted Acidity as a Function of Isocyanide Ligation

DOE PAGES

Carpenter, Alex E.; Chan, Chinglin; Rheingold, Arnold L.; ...

2016-07-07

The m-terphenyl isocyanide complex, HCo(CNAr Mes2) 4 (Ar Mes2 = 2,6-(2,4,6-Me 3C 6H 2) 2C 6H 3), serves as a unique example of a well-defined isocyano analogue to HCo(CO) 4. Given the well documented Brønsted acidity of HCo(CO) 4 in both protic and nonprotic media, the Brønsted acidity of HCo(CNAr Mes2) 4 was assessed for a quantitative comparison. Acid bracketing experiments in THF solution revealed that HCo(CNAr Mes2) 4 has a Morris relative pK α THF value of 38.5-40.7, which is considerably higher than that of HCo(CO) 4 (pK α THF (calc) = 11.4) and thereby indicates insignificant Brønsted acidity.more » Furthermore, the relative acidity of HCo(CNAr Mes2) 4 rivals that of tetra-phosphine cobalt hydrides (i.e., HCo(PR 3) 4; pK α THF (calc) ≥ 48), despite the good π-acidity properties of the isocyano unit. To systematically determine the effect of substituting an isocyanide for a CO ligand on the acidity of the Co-H unit in HCoL 4 complexes, the full series of HCo(CO) n(CNAr Mes2) 4-n monohydrides and [Co(CO) n(CNAr Mes2) 4-n] - (n = 1-4) metalates were prepared and characterized. Acid bracketing studies on the [Co(CO) n(CNAr Mes2) 4-n] - metalates in THF solution revealed a regular progression of increasing pK α THF values as isocyanides are added to the Co center. However, the monoisocyanide tricarbonyl hydride, HCo(CO) 3(CNAr Mes2), possesses a pK α THF value of 28.6-32.5, which is also significantly higher than that of HCo(CO) 4 and the monophosphine complex HCo(CO) 3(PPh 3). Accordingly, the unconventional ability of isocyanide ligands to function as stronger σ-donors than organophosphines is discussed within the context of both the Brønsted acidity and spectroscopic features of the HCo(CO) n(CNAr Mes2) 4-n monohydrides.« less

A possible connection between post-subduction arc magmatism and adakite-NEB rock association in Baja California, Mexico

NASA Astrophysics Data System (ADS)

Castillo, P. R.

2007-05-01

Late Miocene to Recent arc-related magmatism occurs in Baja California, Mexico despite the cessation of plate subduction along its western margin at ~12.5 Ma. It includes calcalkaline and K-rich andesites, tholeiitic basalts and basaltic andesites, alkalic basalts similar to many ocean island basalts (OIB), magnesian and basaltic andesites with adakitic affinity (bajaiites), adakites, and Nb-enriched basalts (NEB). A popular model for the close spatial and temporal association of adakite (plus bajaiite) and NEB in Baja California is these are due to melting of the subducted Farallon/Cocos plate, which in turn is caused by the influx of hot asthenospheric mantle through a window created in the subducted slab directly beneath the Baja California peninsula [e.g., Benoit, M. et. al. (2002) J. Geol. 110, 627-648; Calmus, T. et al. (2003) Lithos 66, 77-105]. Here I propose an alternative model for the cause of post-subduction magmatism in Baja California in particular and origin of adakite-NEB rock association in general. The complicated tectonic configuration of the subducting Farallon/Cocos plate and westward motion of the North American continent caused western Mexico to override the hot, upwelling Pacific mantle that was decoupled from the spreading centers abandoned west of Baja California. The upwelling asthenosphere is best manifested east of the peninsula, beneath the Gulf of California, and is most probably due to a tear or window in the subducted slab there. The upwelling asthenosphere is compositionally heterogeneous and sends materials westward into the mantle wedge beneath the peninsula. These materials provide sources for post-subduction tholeiitic and alkalic magmas. Portions of tholeiitic magmas directly erupted at the surface produce tholeiitic lavas, but some get ponded beneath the crust. Re-melting and/or high-pressure fractional crystallization of the ponded tholeiitic magmas generate adakitic rocks. Alkalic magmas directly erupted at the surface

A revision of the Australian species of Trimma (Actinopterygii, Gobiidae), with descriptions of six new species and redescriptions of twenty-three valid species.

PubMed

Winterbottom, Richard; Hoese, Douglass F

2015-03-17

The gobiid genus Trimma currently contains 75 valid species, with another 20-30 known but undescribed species. There are 29 species in Australian waters (six undescribed). This paper describes the six new species, and provides redescriptions of most of the 23 previously described species known from the region, as well as a key for all the species. The six new species are: T. insularum (endemic to Cocos (Keeling) Islands), T. kitrinum (Fiji to Great Barrier Reef), T. meristum (Cape York to the Bismark Archipelago and Fiji), T. pentherum (Great Barrier Reef to Fiji and the South-West Islands of Palau), T. readerae (Australia to Japan), and T. xanthum (Palau to Fiji, Great Barrier Reef to Christmas Island). The following 23 species have been recorded from Australian waters, and most are redescribed here: T. anaima (Comores to Fiji), T. annosum (Maldives to the Phoenix Islands, Taiwan to the southern Great Barrier Reef), T. benjamini (southern Vietnam to the Marshall Islands, Samoa and southern Barrier Reef), T. caesiura (Ryukyus through the Marshall Islands to Samoa and Elizabeth Reef on the Lord Howe Rise), T. capostriatum (New Caledonia to eastern Australia and Papua New Guinea), T. maiandros (Java to the Ryukyus, Marshalls to Great Barrier Reef), T. emeryi (Comores to Ryukyus and Samoa), T. fangi (western South China Sea through to the Solomons), T. flavatrum (Ryukyu Islands to Western Australia and Samoa), T. hoesei (Chagos Archipelago, central Indian Ocean to Palau and Solomons), T. lantana (Australia, Solomons, northern New Guinea, South-West Islands of Palau), T. macrophthalmus (Ryukyu Islands to Cocos (Keeling) Islands and Samoa), T. milta (Taiwan to Western Australia, Society Islands and Hawaii), T. nasa (Sumbawa, Indonesia to Fiji), T. necopinum (northern tip of Cape York to Sydney), T. nomurai (Japan to northern Australia and New Caledonia), T. okinawae (western Thailand to Japan and the Phoenix Islands, north-west Australia to the Great Barrier Reef), T

Scaling laws of the size-distribution of monogenetic volcanoes within the Michoacán-Guanajuato Volcanic Field (Mexico)

NASA Astrophysics Data System (ADS)

Pérez-López, R.; Legrand, D.; Garduño-Monroy, V. H.; Rodríguez-Pascua, M. A.; Giner-Robles, J. L.

2011-04-01

The Michoacán-Guanajuato Volcanic Field displays about 1040 monogenetic volcanoes mainly composed of basaltic cinder cones. This monogenetic volcanic field is the consequence of a dextral transtensive tectonic regime within the Transmexican Volcanic Belt (TMVB), the largest intra continental volcanic arc around the world, related to the subduction of the Rivera and Cocos plates underneath the North American Plate. We performed a statistical analysis for the size-distribution of the basal diameter (Wco) for cinder cones. Dataset used here was compiled by Hasenaka and Carmichael (1985). Monogenetic volcanoes obey a power-law very similar to the Gutenberg-Richter law for earthquakes, with respect to their size-distribution: log 10 ( N >= Wco ) = α - β log10( Wco), with β = 5.01 and α = 2.98. Therefore, the monogenetic volcanoes exhibit a (Wco) size-distribution empirical power-law, suggesting a self-organized criticality phenomenon.

Geometrical separation method for lipoproteins using bioformulated-fiber matrix electrophoresis: size of high-density lipoprotein does not reflect its density.

PubMed

Tabuchi, Mari; Seo, Makoto; Inoue, Takayuki; Ikeda, Takeshi; Kogure, Akinori; Inoue, Ikuo; Katayama, Shigehiro; Matsunaga, Toshiyuki; Hara, Akira; Komoda, Tsugikazu

2011-02-01

The increasing number of patients with metabolic syndrome is a critical global problem. In this study, we describe a novel geometrical electrophoretic separation method using a bioformulated-fiber matrix to analyze high-density lipoprotein (HDL) particles. HDL particles are generally considered to be a beneficial component of the cholesterol fraction. Conventional electrophoresis is widely used but is not necessarily suitable for analyzing HDL particles. Furthermore, a higher HDL density is generally believed to correlate with a smaller particle size. Here, we use a novel geometrical separation technique incorporating recently developed nanotechnology (Nata de Coco) to contradict this belief. A dyslipidemia patient given a 1-month treatment of fenofibrate showed an inverse relationship between HDL density and size. Direct microscopic observation and morphological observation of fractionated HDL particles confirmed a lack of relationship between particle density and size. This new technique may improve diagnostic accuracy and medical treatment for lipid related diseases.

Electronic structure of the alkyne-bridged dicobalt hexacarbonyl complex Co(2) micro-C(2)H(2) (CO)(6): evidence for singlet diradical character and implications for metal-metal bonding.

PubMed

Platts, James A; Evans, Gareth J S; Coogan, Michael P; Overgaard, Jacob

2007-08-06

A series of ab initio calculations are presented on the alkyne-bridged dicobalt hexacarbonyl cluster Co2 micro-C2H2 (CO)6, indicating that this compound has substantial multireference character, which we interpret as evidence of singlet diradical behavior. As a result, standard theoretical methods such as restricted Hartree-Fock (RHF) or Kohn-Sham (RKS) density functional theory cannot properly describe this compound. We have therefore used complete active space (CAS) methods to explore the bonding in and spectroscopic properties of Co2 micro-C2H2 (CO)6. CAS methods identify significant population of a Co-Co antibonding orbital, along with Co-pi* back-bonding, and a relatively large singlet-triplet energy splitting. Analysis of the electron density and related quantities, such as energy densities and atomic overlaps, indicates a small but significant amount of covalent bonding between cobalt centers.

Experimental investigation of various vegetable fibers as sorbent materials for oil spills.

PubMed

Annunciado, T R; Sydenstricker, T H D; Amico, S C

2005-11-01

Oil spills are a global concern due to their environmental and economical impact. Various commercial systems have been developed to control these spills, including the use of fibers as sorbents. This research investigates the use of various vegetable fibers, namely mixed leaves residues, mixed sawdust, sisal (Agave sisalana), coir fiber (Cocos nucifera), sponge-gourd (Luffa cylindrica) and silk-floss as sorbent materials of crude oil. Sorption tests with crude oil were conducted in deionized and marine water media, with and without agitation. Water uptake by the fibers was investigated by tests in dry conditions and distillation of the impregnated sorbent. The silk-floss fiber showed a very high degree of hydrophobicity and oil sorption capacity of approximately 85goil/g sorbent (in 24hours). Specific gravity measurements and buoyancy tests were also used to evaluate the suitability of these fibers for the intended application.

A Biomimetic Nickel Complex with a Reduced CO2 Ligand Generated by Formate Deprotonation and Its Behaviour towards CO2.

PubMed

Zimmermann, Philipp; Hoof, Santina; Braun-Cula, Beatrice; Herwig, Christian; Limberg, Christian

2018-04-10

Reduced CO 2 species are key intermediates in a variety of natural and synthetic processes. In the majority of systems, however, they elude isolation or characterisation owing to high reactivity or limited accessibility (heterogeneous systems), and their formulations thus often remain uncertain or are based on calculations only. We herein report on a Ni-CO 2 2- complex that is unique in many ways. While its structural and electronic features help understand the CO 2 -bound state in Ni,Fe carbon monoxide dehydrogenases, its reactivity sheds light on how CO 2 can be converted into CO/CO 3 2- by nickel complexes. In addition, the complex was generated by a rare example of formate β-deprotonation, a mechanistic step relevant to the nickel-catalysed conversion of H x CO y z- at electrodes and formate oxidation in formate dehydrogenases. © 2018 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.

Rhizopalmoxylon nypoides - a new palm root from the Deccan Intertrappean beds of Sagar, Madhya Pradesh, India

NASA Astrophysics Data System (ADS)

Kathal, P. K.; Srivastava, Rashmi; Mehrotra, R. C.; Alexander, P. O.

2017-04-01

A new species of fossil palm rhizome having root-mat under the organ genus Rhizopalamoxylon ( Rhizopalmoxylon nypoides sp. nov.) is reported. The specimen shows the closest resemblance with the modern monotypic genus Nypa Wurmb of the Arecaceae. The specimen was collected from the late Maastrichtian-early Danian sediments of Deccan Intertrappean beds, Mothi, Sagar district, Madhya Pradesh, India. Nypa is a mangrove palm naturally found in estuaries and swamps of the tropical region and represents one of the oldest records of the genus from the Deccan Intertrappean beds of central India. The abundance of palms, including Nypa and previously recorded coastal and mangrove elements such as Acrostichum, Barringtonia, Cocos, Sonneratia and marine algae ( Distichoplax and Peyssonellia) from the Deccan Intertrappean beds indicate marine influence and existence of tropical rainforest ecosystem in the vicinity of fossil locality in contrast to the deciduous forests occurring there at present.

TRISO-Coated Fuel Durability Under Extreme Conditions

DOE Office of Scientific and Technical Information (OSTI.GOV)

Reimanis, Ivar; Gorman, Brian; Butt, Darryl

2014-03-30

The PIs propose to examine TRISO-coated particles (SiC and ZrC coatings) in an integrated two-part study. In the first part, experiments will be performed to assess the reaction kinetics of the carbides under CO-CO2 environments at temperatures up to 1800 degree C. Kinetic model will be applied to describe the degradation. Scanning and transmission electron microscopy will be employed to establish the chemical and microstructure evolution under the imposed environmental conditions. The second part of the proposed work focuses on establishing the role of the high temperature, environmental exposure described above on the mechanical behavior of TRISO-coated particles. Electron microscopymore » and other advanced techniques will be subsequently performed to evaluate failure mechanisms. The work is expected to reveal relationships between corrosion reactions, starting material characteristics (polytype of SiC, impurity concentration, flaw distribution), flaw healing behavior, and crack growth.« less

Dispersions of attractive semiflexible fiberlike colloidal particles from bacterial cellulose microfibrils.

PubMed

Kuijk, Anke; Koppert, Remco; Versluis, Peter; van Dalen, Gerard; Remijn, Caroline; Hazekamp, Johan; Nijsse, Jaap; Velikov, Krassimir P

2013-11-26

We prepared dispersions from bacterial cellulose microfibrils (CMF) of a commercial Nata de Coco source. We used an ultra-high-energy mechanical deagglomeration process that is able to disperse the CMFs from the pellicle in which they are organized in an irregular network. Because of the strong attractions between the CMFs, the dispersion remained highly heterogeneous, consisting of fiber bundles, flocs, and voids spanning tens to hundreds of micrometers depending on concentration. The size of these flocs increased with CMF concentration, the size of the bundles stayed constant, and the size of the voids decreased. The observed percolation threshold in MFC dispersions is lower than the theoretical prediction, which is accounted for by the attractive interactions in the system. Because bacterial cellulose is chemically very pure, it can be used to study the interaction of attractive and highly shape-anisotropic, semiflexible fiberlike colloidal particles.

Experimental methods for quenching structures in lunar-analog silicate melts: Variations as a function of quench media and composition

NASA Technical Reports Server (NTRS)

Dyar, M. D.

1985-01-01

Compositions analogous to lunar green, organge, and brown glasses were synthesized under consistent conditions, then quenched into a variety of different media when the samples were removed from the furnace. Iron valence and coordination are a direct function of quench media used, spanning the range from brine/ice (most effective quench), water, butyl phthalate, silicone oil, liquid nitrogen, highly reducing CO-CO2 gas, to air (least efficient quench). In the green and brown glasses, Fe(3+) in four-fold and six-fold coordination is observed in the slowest-quenched samples; Fe(2+) coordination varies directly with quench efficiency. Less pronounced changes were observed in the Ti-rich orange glass. Therefore the remote-sensed spectrum of a glass-bearing regolith on the Moon may be influenced by the process by which the glass cooled, and extreme caution must be used when comparing spectra of synthetic glass analogs with real lunar glasses.

Experimental methods for quenching structures in lunar-analog silicate melts - Variations as a function of quench media and composition

NASA Technical Reports Server (NTRS)

Dyar, M. D.

1984-01-01

Compositions analogous to lunar green, orange, and brown glasses were synthesized under consistent conditions, then quenched into a variety of different media when the samples were removed from the furnace. Iron valence and coordination are a direct function of quench media used, spanning the range from brine/ice (most effective quench), water, butyl phthalate, silicone oil, liquid nitrogen, highly reducing CO-CO2 gas, to air (least efficient quench). In the green and brown glasses, Fe(3+) in four-fold and six-fold coordination is observed in the slowest-quenched samples; Fe(2+) coordination varies directly with quench efficiency. Less pronounced changes were observed in the Ti-rich orange glass. Therefore the remote-sensed spectrum of a glass-bearing regolith on the moon may be influenced by the process by which the glass cooled, and extreme caution must be used when comparing spectra of synthetic glass analogs with real lunar glasses.

Synthesis,and structural characterization of [(CH3(C5H4N))Ga(SCH2(CO)O)]-[(4-MepyH)]+, a novel Ga(III) five coordinate complex.

NASA Technical Reports Server (NTRS)

Banger, Kulbinder K.; Duraj, Stan A.; Fanwic, Phillp E.; Hepp, Aloysius F.; Martuch, Robert A.

2003-01-01

The synthesis and structural characterization of a novel ionic Ga(III) five coordinate complex [{CH3(C5H4N)}Ga(SCH2(CO)O)2]-[(4-MepyH)]+, (4-Mepy = CH3(C5H5N)) from the reaction between Ga2Cl4 with sodium mercapto-acetic acid in 4-methylpyridine is described. Under basic reaction conditions the mercapto ligand is found to behave as a 2e- bidentate ligand. Single crystal X-ray diffraction studies show the complex to have a distorted square pyramidal geometry with the [(-SCH2(CO)CO-)] ligands in a trans conformation. The compound crystallizes in the P2(sub 1)/c (No. 14) space group with a = 7.7413(6) A, b = 16.744(2) A, c = 14.459(2) A, V = 1987.1(6) A(sup 3), R(F) = 0.032 and R(sub w) = 0.038.

Boosting photocatalytic overall water splitting by Co doping into Mn3O4 nanoparticles as oxygen evolution cocatalysts.

PubMed

Yoshinaga, Taizo; Saruyama, Masaki; Xiong, Anke; Ham, Yeilin; Kuang, Yongbo; Niishiro, Ryo; Akiyama, Seiji; Sakamoto, Masanori; Hisatomi, Takashi; Domen, Kazunari; Teranishi, Toshiharu

2018-06-14

The effect of cobalt doping into a manganese oxide (tetragonal spinel Mn 3 O 4 ) nanoparticle cocatalyst up to Co/(Co + Mn) = 0.4 (mol/mol) on the activity of photocatalytic water oxidation was studied. Monodisperse ∼10 nm Co y Mn 1-y O (0 ≤y≤ 0.4) nanoparticles were uniformly loaded onto photocatalysts and converted to Co x Mn 3-x O 4 nanoparticles through calcination. 40 mol% cobalt-doped Mn 3 O 4 nanoparticle-loaded Rh@Cr 2 O 3 /SrTiO 3 photocatalyst exhibited 1.8 times-higher overall water splitting activity than that with pure Mn 3 O 4 nanoparticles. Investigation on the band structure and electrocatalytic water oxidation activity of Co x Mn 3-x O 4 nanoparticles revealed that the Co doping mainly contributes to the improvement of water oxidation kinetics on the surface of the cocatalyst nanoparticles.

Anticorrelated seismic velocity anomalies from post-perovskite in the lowermost mantle

USGS Publications Warehouse

Hutko, Alexander R.; Lay, T.; Revenaugh, Justin; Garnero, E.J.

2008-01-01

Earth's lowermost mantle has thermal, chemical, and mineralogical complexities that require precise seismological characterization. Stacking, migration, and modeling of over 10,000 P and S waves that traverse the deep mantle under the Cocos plate resolve structures above the core-mantle boundary. A small -0.07 ?? 0.15% decrease of P wave velocity (Vp) is accompanied by a 1.5 ?? 0.5% increase in S wave velocity (Vs) near a depth of 2570 km. Bulk-sound velocity [Vb = (V p2 - 4/3Vs2)1/2] decreases by -1.0 ?? 0.5% at this depth. Transition of the primary lower-mantle mineral, (Mg1-x-y FexAly)(Si,Al) O3 perovskite, to denser post-perovskite is expected to have a negligible effect on the bulk modulus while increasing the shear modulus by ???6%, resulting in local anticorrelation of Vb and Vs anomalies; this behavior explains the data well.

(Carbonato-κ2 O,O′)bis­(di-2-pyridyl­amine-κ2 N,N′)cobalt(III) bromide

PubMed Central

Czapik, Agnieszka; Papadopoulos, Christos; Lalia-Kantouri, Maria; Gdaniec, Maria

2011-01-01

In the title compound, [Co(CO3)(C10H9N3)2]Br, a distorted octa­hedral coordination of the CoIII atom is completed by four N atoms of the two chelating di-2-pyridyl­amine ligands and two O atoms of the chelating carbonate anion. The di-2-pyridyl­amine ligands are nonplanar and the dihedral angles between the 2-pyridyl groups are 29.11 (9) and 37.15 (12)°. The coordination cation, which has approximate C 2 symmetry, is connected to the bromide ion via an N—H⋯Br− hydrogen bond. The ionic pair thus formed is further assembled into a dimer via N—H⋯O inter­actions about an inversion centre. A set of weaker C—H⋯O and C—H⋯Br− inter­actions connect the dimers into a three-dimensional network. PMID:21753946

(Carbonato-κ(2)O,O')bis-(5,5'-dimethyl-2,2'-bipyridyl-κ(2)N,N')cobalt(III) bromide trihydrate.

PubMed

Arun Kumar, Kannan; Meera, Parthsarathi; Amutha Selvi, Madhavan; Dayalan, Arunachalam

2012-04-01

In the title complex, [Co(CO(3))(C(12)H(12)N(2))(2)]Br·3H(2)O, the Co(III) cation has a distorted octa-hedral coordination environment. It is chelated by four N atoms of two different 5,5'-dimethyl-2,2'-bipyridyl (dmbpy) ligands in axial and equatorial positions, and by two O atoms of a carbonate anion completing the equatorial positions. Although the water mol-ecules are disordered and their H atoms were not located, there are typical O⋯O distances between 2.8 and 3.0 Å, indicating O-H⋯O hydrogen bonding. The crystal packing is consolidated by C-H⋯O and C-H⋯Br hydrogen bonds, as well as π-π stacking inter-actions between adjacent pyridine rings of the dmbpy ligands, with centroid-centroid distances of 3.694 (3) and 3.7053 (3) Å.

Experimental Investigation of Gas/Slag/Matte/Tridymite Equilibria in the Cu-Fe-O-S-Si System in Controlled Gas Atmospheres: Experimental Results at 1473 K (1200 °C) and P(SO2) = 0.25 atm

NASA Astrophysics Data System (ADS)

Fallah-Mehrjardi, Ata; Hidayat, Taufiq; Hayes, Peter C.; Jak, Evgueni

2017-12-01

Experimental studies were undertaken to determine the gas/slag/matte/tridymite equilibria in the Cu-Fe-O-S-Si system at 1473 K (1200 °C), P(SO2) = 0.25 atm, and a range of P(O2)'s. The experimental methodology involved high-temperature equilibration using a substrate support technique in controlled gas atmospheres (CO/CO2/SO2/Ar), rapid quenching of equilibrium phases, followed by direct measurement of the chemical compositions of the phases with Electron Probe X-ray Microanalysis (EPMA). The experimental data for slag and matte were presented as a function of copper concentration in matte (matte grade). The data provided are essential for the evaluation of the effect of oxygen potential under controlled atmosphere on the matte grade, liquidus composition of slag and chemically dissolved copper in slag. The new data provide important accurate and reliable quantitative foundation for improvement of the thermodynamic databases for copper-containing systems.

Particle sorting during sediment redistribution processes and the effect on 230Th-normalized mass accumulation rates

NASA Astrophysics Data System (ADS)

Marcantonio, Franco; Lyle, Mitchell; Ibrahim, Rami

2014-08-01

The 230Th method of determining mass accumulation rates (MARs) assumes that little to no fractionation occurs during sediment redistribution processes at the seafloor. We examine 230Th inventories in radiocarbon-dated multicore sediments from paired winnowed and focused sites at Cocos and Carnegie Ridges, Panama Basin. Radiocarbon-derived sand MARs, which likely represent the vertical rain of particles poorly transported by bottom currents, are similar at each of the paired sites but are different using 230Th normalization. 230Th-normalized MARs are about 60% lower at focused sites and likely underestimate vertical MARs, while the reverse is true for winnowed sites. We hypothesize that size fractionation occurs most frequently at lower current velocities, resulting in the coarse fraction being left behind and primarily the fine 230Th-rich grains being transported downslope. 230Th-normalization works well for recording fine-grained (detrital and opal), but not coarse-grained (carbonate), fluxes in regions that have undergone sediment redistribution.

Late Cenozoic alkaline volcanism in the northwestern Caribbean - Tectonic setting and Sr isotopic characteristics

NASA Technical Reports Server (NTRS)

Wadge, G.; Wooden, J. L.

1982-01-01

The northwestern corner of the Caribbean plate has at least sixteen centers of alkalic volcanism, most of which is Quaternary in age. Sr-87/Sr-86 ratios of the rocks in these centers are used to distinguish three geographical groups: a low-ratio group (0.7026-0.7031) at the Nicaraguan Rise, an intermediate-ratio group (0.7036-0.7038) in northeastern Costa Rica, and a high-ratio group (0.7047-0.7063) in Hispaniola. It is suggested that the increased radiogenic strontium in both Costa Rica and Hispaniola may have come from volatile-rich fluids escaping from adjacent subducting slabs of oceanic crust. The isotopic differences between the two areas is explained by the relative longevity and high rate of subduction in Costa Rica compared to that in Hispaniola. The Costa Rican alkaline rocks cover a segment of the Cocos plate which is being subducted at a smaller angle (about 35 deg) than at the rest of the Central American arc.

Testing Earthquake Links in Mexico From 1978 to the 2017 M = 8.1 Chiapas and M = 7.1 Puebla Shocks

NASA Astrophysics Data System (ADS)

Segou, Margarita; Parsons, Tom

2018-01-01

The M = 8.1 Chiapas and the M = 7.1 Puebla earthquakes occurred in the bending part of the subducting Cocos plate 11 days and 600 km apart, a range that puts them well outside the typical aftershock zone. We find this to be a relatively common occurrence in Mexico, with 14% of M > 7.0 earthquakes since 1900 striking more than 300 km apart and within a 2 week interval, not different from a randomized catalog. We calculate the triggering potential caused by crustal stress redistribution from large subduction earthquakes over the last 40 years. There is no evidence that static stress transfer or dynamic triggering from the 8 September Chiapas earthquake promoted the 19 September earthquake. Both recent earthquakes were promoted by past thrust events instead, including delayed afterslip from the 2012 M = 7.5 Oaxaca earthquake. A repeated pattern of shallow thrust events promoting deep intraslab earthquakes is observed over the past 40 years.

From an Easily Accessible Pentacarbonylcobalt(I) Salt to Piano-Stool Cations [(arene)Co(CO)2 ].

PubMed

Meier, Stefan C; Holz, Albina; Schmidt, Alexei; Kratzert, Daniel; Himmel, Daniel; Krossing, Ingo

2017-10-17

The facile synthesis of a pentacarbonyl cobalt(I) salt without the need for a superacid as solvent is presented. This salt, [Co(CO) 5 ] + [Al(OR F ) 4 ] - {R F =C(CF 3 ) 3 }, readily accessible on a multigram scale, undergoes substitution reactions with arenes yielding the hitherto unknown class of two-legged cobalt piano-stool complexes [(arene)Co(CO) 2 ] + with four different arene ligands. Such a substitution chemistry would have been impossible in superacid solution, as the arenes used would have been oxidized and/or protonated. Thus, the general approach described herein may have a wide synthetic use. Additionally, the thermochemistry of the piano-stool complexes is shown to be not easy to describe computationally and most of the established DFT methods overestimate the reaction energies. Only CCSD(T) calculations close to the basis set limit gave energies fully agreeing with the experiment. © 2017 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.

Free-standing and porous hierarchical nanoarchitectures constructed with cobalt cobaltite nanowalls for supercapacitors with high specific capacitances

NASA Astrophysics Data System (ADS)

Xiao, Yuanhua; Zhang, Aiqin; Liu, Shaojun; Zhao, Jihong; Fang, Shaoming; Jia, Dianzeng; Li, Feng

2012-12-01

Free-standing and porous hierarchical nanoarchitectures constructed with cobalt cobaltite (Co3O4) nanowalls have been successfully synthesized in large scale by calcining three dimensional (3D) hierarchical nanostructures consisting of single crystalline cobalt carbonate hydroxide hydrate - Co(CO3)0.5(OH)·0.11H2O nanowalls prepared with a solvothermal method. The step-by-step decomposition of the precursor can generate porous Co3O4 nanowalls with BET surface area of 88.34 m2 g-1. The as-prepared Co3O4 nanoarchitectures show superior specific capacitance to the most Co3O4 supercapacitor electrode materials to date. After continuously cycled for 1000 times of charge-discharge at 4 A g-1, the supercapacitors can retain ca 92.3% of their original specific capacitances. The excellent performances of the devices can be attributed to the porous and hierarchical 3D nanostructure of the materials.

Source characteristics of the Nicaraguan tsunami earthquake of September 2, 1992

NASA Astrophysics Data System (ADS)

Ide, Satoshi; Imamura, Fumihiko; Yoshida, Yasuhiro; Abe, Katsuyuki

1993-05-01

The source mechanisms of the Nicaraguan tsunami earthquake of September 2, 1992 is studied via waveforms of body waves and surface waves recorded on global broadband seismographs. The possibility of a single force is ruled out from radiation patterns and the amplitude ratio of Rayleigh and Love waves. The main shock is interpreted as low-angle thrust fault with strike of 302 deg, dip of 16 deg, and slip of 87 deg, the Cocos plate underthrusting beneath the Caribbean plate. The seismic moment from surface wave analysis is 3.0 x 10 exp 20 Nm. The source dimension is estimated to be 200 x 100 km from the aftershock area. The inversion results of body waves suggest bilateral rupture with rupture velocity as low as 1.5 km/s and duration time of about 100 s. The source process time is unusually long, from which it is inferred that the associated crustal deformation has a long time constant.

Isothermal Oxidation of Magnetite to Hematite in Air and Cyclic Reduction/Oxidation Under Carbon Looping Combustion Conditions

NASA Astrophysics Data System (ADS)

Simmonds, Tegan; Hayes, Peter C.

2017-12-01

In the carbon looping combustion process the oxygen carrier is regenerated through oxidation in air; this process has been simulated by the oxidation of dense synthetic magnetite for selected temperatures and times. The oxidation of magnetite in air is shown to occur through the formation of dense hematite layers on the particle surface. This dense hematite forms through lath type shear transformations or solid-state diffusion through the product layer. Cyclic reduction in CO-CO2/oxidation in air of hematite single crystals has been carried out under controlled laboratory conditions at 1173 K (900 °C). It has been shown that the initial reduction step is critical to determining the product microstructure, which consists of gas pore dendrites in the magnetite matrix with blocky hematite formed on the pore surfaces. The progressive growth of the magnetite layer with the application of subsequent cycles appears to continue until no original hematite remains, after which physical disintegration of the particles takes place.

Rough versus smooth topography along oceanic hotspot tracks: Observations and scaling analysis

NASA Astrophysics Data System (ADS)

Orellana-Rovirosa, Felipe; Richards, Mark

2017-05-01

Some hotspot tracks are topographically smooth and broad (Nazca, Carnegie/Cocos/Galápagos, Walvis, Iceland), while others are rough and discontinuous (Easter/Sala y Gomez, Tristan-Gough, Louisville, St. Helena, Hawaiian-Emperor). Smooth topography occurs when the lithospheric age at emplacement is young, favoring intrusive magmatism, whereas rough topography is due to isolated volcanic edifices constructed on older/thicker lithosphere. The main controls on the balance of intrusive versus extrusive magmatism are expected to be the hotspot swell volume flux Qs, plate hotspot relative speed v, and lithospheric elastic thickness Te, which can be combined as a dimensionless parameter R = (Qs/v)1/2/Te, which represents the ratio of plume heat to the lithospheric heat capacity. Observational constraints show that, except for the Ninetyeast Ridge, R is a good predictor of topographic character: for R < 1.5 hotspot tracks are topographically rough and dominated by volcanic edifices, whereas for R > 3 they are smooth and dominated by intrusion.

Alpha List of Prime Contract Awards. Oct 92-Sep 93. FY93. (Oank8 Elbelco Inc. - Food Service Decor & Design). Part 7

DTIC Science & Technology

1994-03-01

In = 4j 1 wow 11 (A com L) w U U) 04 ý4 0 u Ce ý4 0 0 Cie 0 Ix rý 00 .4 L) cc W 0 N C I cc" If x Q-J(Doý- x q1t (D 0 xooooý-- 0 L) 0 0 ý- CL. 0 m Ln...oCGoCOCO CON CN w 4 < 0 44 < O44 M -cvMN U (COO0-40(11 .-40 -40 OCOCCID(O 040 00W 04 NU) COM -i -444 0 N 0-4 if U.. a: a Ezz Z z 0 In0 000 a CV (0() 3n U4... coM 4)(4W-4 sN UN u m 4 - W gn N I 004- If > tcI Ny.4 -4 of0 X.4 cc (a 000000000001111111111Q0 N a I 004o- N1 as 4- -40-4 .4 -4 0 No tl 00 0

Enhanced performance of CO oxidation over Pt/CuCrOx catalyst in the presence of CO2 and H2O

NASA Astrophysics Data System (ADS)

Deng, Yun; Wang, Ting; Zhu, Li; Jia, Ai-Pin; Lu, Ji-Qing; Luo, Meng-Fei

2018-06-01

A Pt catalyst supported on CuO-CrOx composite oxide (Pt/CuCrOx) was prepared and tested for CO oxidation in the presence of CO2 and H2O. It was found that the catalyst was stable in the realistic reaction conditions and the catalytic activity was improved in the presence of CO2 and H2O compared to that in dry condition. Kinetic investigation and temperature - programmed desorption of CO results revealed that the addition of CO2 in the feed resulted in the competitive adsorption of CO/CO2 and the formation of surface carbonate species, which consequently deactivated the catalyst. In contrast, although the presence of H2O also inhibited the adsorption of CO, the possible formation of surface hydroxyl groups may trigger a new and more facile reaction route for CO oxidation, which could explain the promoting effect of H2O. Therefore, the current findings makes the catalyst promising in CO oxidation under realistic reaction conditions.

Antibacterial properties of some plants used in Mexican traditional medicine for the treatment of gastrointestinal disorders.

PubMed

Alanís, A D; Calzada, F; Cervantes, J A; Torres, J; Ceballos, G M

2005-08-22

Antibacterial properties of aqueous and methanolic extracts of 26 medicinal plants used in Mexico to treat gastrointestinal disorders were tested against eight different species of enteropathogens: two Escherichia coli species; two Shigella sonnei species; two Shigella flexneri species; and two Salmonella sp. species. The results showed that all crude extracts exhibited antibacterial activity, at least against one of the microorganisms tested, at concentrations of 8 mg/mL or lower. The extracts from Caesalpinia pulcherria, Chiranthodendron pentadactylon, Cocos nucifera, Geranium mexicanum (aerial parts and roots), Hippocratea excelsa, and Punica granatum possessed strong antibacterial activity against most of the pathogens tested. In general, methanolic extracts were more active than aqueous extracts. Their activity was higher than chloramphenicol but did not exceed that of trimethoprim. Shigella sonnei species showed the highest susceptibility to both extracts. This is the first evaluation of these plants against bacterial pathogen isolates, which cause diarrhea and dysentery in Mexican population.

Fast quantitative detection of cocaine in beverages using nanoextractive electrospray ionization tandem mass spectrometry.

PubMed

Hu, Bin; Peng, Xuejiao; Yang, Shuiping; Gu, Haiwei; Chen, Huanwen; Huan, Yanfu; Zhang, Tingting; Qiao, Xiaolin

2010-02-01

Without any sample pretreatment, effervescent beverage fluids were manually sprayed into the primary ion plume created by using a nanoelectrospray ionization source for direct ionization, and the analyte ions of interest were guided into an ion trap mass spectrometer for tandem mass analysis. Functional ingredients (e.g., vitamins, taurine, and caffeine, etc.) and spiked impurity (e.g., cocaine) in various beverages, such as Red Bull energy drink, Coco-cola, and Pepsi samples were rapidly identified within 1.5 s. The limit of detection was found to be 7-15 fg (S/N = 3) for cocaine in different samples using the characteristic fragment (m/z 150) observed in the MS(3) experiments. Typical relative standard deviation and recovery of this method were 6.9%-8.6% and 104%-108% for direct analysis of three actual samples, showing that nanoextractive electrospray ionization tandem mass spectrometry is a useful technique for fast screening cocaine presence in beverages. 2010. Published by Elsevier Inc.

Integrated bioconversion of syngas into bioethanol and biopolymers.

PubMed

Lagoa-Costa, Borja; Abubackar, Haris Nalakath; Fernández-Romasanta, María; Kennes, Christian; Veiga, María C

2017-09-01

Syngas bioconversion is a promising method for bioethanol production, but some VFA remains at the end of fermentation. A two-stage process was set-up, including syngas fermentation as first stage under strict anaerobic conditions using C. autoethanogenum as inoculum, with syngas (CO/CO 2 /H 2 /N 2 , 30/10/20/40) as gaseous substrate. The second stage consisted in various fed-batch assays using a highly enriched PHA accumulating biomass as inoculum, where the potential for biopolymer production from the remaining acetic acid at the end of the syngas fermentation was evaluated. All of the acetic acid was consumed and accumulated as biopolymer, while ethanol and 2,3-butanediol remained basically unused. It can be concluded that a high C/N ratio in the effluent from the syngas fermentation stage was responsible for non-consumption of alcohols. A maximum PHA content of 24% was reached at the end of the assay. Copyright © 2017 Elsevier Ltd. All rights reserved.

Room temperature stable COx-free H2 production from methanol with magnesium oxide nanophotocatalysts

PubMed Central

Liu, Zhengqing; Yin, Zongyou; Cox, Casandra; Bosman, Michel; Qian, Xiaofeng; Li, Na; Zhao, Hongyang; Du, Yaping; Li, Ju; Nocera, Daniel G.

2016-01-01

Methanol, which contains 12.6 weight percent hydrogen, is a good hydrogen storage medium because it is a liquid at room temperature. However, by releasing the hydrogen, undesirable CO and/or CO2 byproducts are formed during catalytic fuel reforming. We show that alkaline earth metal oxides, in our case MgO nanocrystals, exhibit stable photocatalytic activity for CO/CO2-free H2 production from liquid methanol at room temperature. The performance of MgO nanocrystals toward methanol dehydrogenation increases with time and approaches ~320 μmol g−1 hour−1 after a 2-day photocatalytic reaction. The COx-free H2 production is attributed to methanol photodecomposition to formaldehyde, photocatalyzed by surface electronic states of unique monodispersed, porous MgO nanocrystals, which were synthesized with a novel facile colloidal chemical strategy. An oxygen plasma treatment allows for the removal of organic surfactants, producing MgO nanocrystals that are well dispersible in methanol. PMID:28508036

Can green roof act as a sink for contaminants? A methodological study to evaluate runoff quality from green roofs.

PubMed

Vijayaraghavan, K; Joshi, Umid Man

2014-11-01

The present study examines whether green roofs act as a sink or source of contaminants based on various physico-chemical parameters (pH, conductivity and total dissolved solids) and metals (Na, K, Ca, Mg, Al, Fe, Cr, Cu, Ni, Zn, Cd and Pb). The performance of green roof substrate prepared using perlite, vermiculite, sand, crushed brick, and coco-peat, was compared with local garden soil based on improvement of runoff quality. Portulaca grandiflora was used as green roof vegetation. Four different green roof configurations, with vegetated and non-vegetated systems, were examined for several artificial rain events (un-spiked and metal-spiked). In general, the vegetated green roof assemblies generated better-quality runoff with less conductivity and total metal ion concentration compared to un-vegetated assemblies. Of the different green roof configurations examined, P. grandiflora planted on green roof substrate acted as sink for various metals and showed the potential to generate better runoff. Copyright © 2014 Elsevier Ltd. All rights reserved.

Application of dietary fiber method AOAC 2011.25 in fruit and comparison with AOAC 991.43 method.

PubMed

Tobaruela, Eric de C; Santos, Aline de O; Almeida-Muradian, Ligia B de; Araujo, Elias da S; Lajolo, Franco M; Menezes, Elizabete W

2018-01-01

AOAC 2011.25 method enables the quantification of most of the dietary fiber (DF) components according to the definition proposed by Codex Alimentarius. This study aimed to compare the DF content in fruits analyzed by the AOAC 2011.25 and AOAC 991.43 methods. Plums (Prunus salicina), atemoyas (Annona x atemoya), jackfruits (Artocarpus heterophyllus), and mature coconuts (Cocos nucifera) from different Brazilian regions (3 lots/fruit) were analyzed for DF, resistant starch, and fructans contents. The AOAC 2011.25 method was evaluated for precision, accuracy, and linearity in different food matrices and carbohydrate standards. The DF contents of plums, atemoyas, and jackfruits obtained by AOAC 2011.25 was higher than those obtained by AOAC 991.43 due to the presence of fructans. The DF content of mature coconuts obtained by the same methods did not present a significant difference. The AOAC 2011.25 method is recommended for fruits with considerable fructans content because it achieves more accurate values. Copyright © 2016 Elsevier Ltd. All rights reserved.

Lysophosphatidic Acid Acyltransferase from Coconut Endosperm Mediates the Insertion of Laurate at the sn-2 Position of Triacylglycerols in Lauric Rapeseed Oil and Can Increase Total Laurate Levels

PubMed Central

Knutzon, Deborah S.; Hayes, Thomas R.; Wyrick, Annette; Xiong, Hui; Maelor Davies, H.; Voelker, Toni A.

1999-01-01

Expression of a California bay laurel (Umbellularia californica) 12:0-acyl-carrier protein thioesterase, bay thioesterase (BTE), in developing seeds of oilseed rape (Brassica napus) led to the production of oils containing up to 50% laurate. In these BTE oils, laurate is found almost exclusively at the sn-1 and sn-3 positions of the triacylglycerols (T.A. Voelker, T.R. Hayes, A.C. Cranmer, H.M. Davies [1996] Plant J 9: 229–241). Coexpression of a coconut (Cocos nucifera) 12:0-coenzyme A-preferring lysophosphatitic acid acyltransferase (D.S. Knutzon, K.D. Lardizabal, J.S. Nelsen, J.L. Bleibaum, H.M. Davies, J.G. Metz [1995] Plant Physiol 109: 999–1006) in BTE oilseed rape seeds facilitates efficient laurate deposition at the sn-2 position, resulting in the acccumulation of trilaurin. The introduction of the coconut protein into BTE oilseed rape lines with laurate above 50 mol % further increases total laurate levels. PMID:10398708

The Effect of CaO on Gas/Slag/Matte/Tridymite Equilibria in Fayalite-Based Copper Smelting Slags at 1473 K (1200 °C) and P(SO2) = 0.25 Atm

NASA Astrophysics Data System (ADS)

Fallah-Mehrjardi, Ata; Hayes, Peter C.; Jak, Evgueni

2018-04-01

Fundamental experimental studies have been undertaken to determine the effect of CaO on the equilibria between the gas phase (CO/CO2/SO2/Ar) and slag/matte/tridymite phases in the Cu-Fe-O-S-Si-Ca system at 1473 K (1200 °C) and P(SO2) = 0.25 atm. The experimental methodology developed in the Pyrometallurgy Innovation Centre was used. New experimental data have been obtained for the four-phase equilibria system for fixed concentrations of CaO (up to 4 wt pct) in the slag phase as a function of copper concentration in matte, including the concentrations of dissolved sulfur and copper in slag, and Fe/SiO2 ratios in slag at tridymite saturation. The new data provided in the present study are of direct relevance to the pyrometallurgical processing of copper and will be used as an input to optimize the thermodynamic database for the copper-containing multi-component multi-phase system.

Evidence for reentrant spin glass behavior in transition metal substituted Co-Ga alloys near critical concentration

NASA Astrophysics Data System (ADS)

Yasin, Sk. Mohammad; Srinivas, V.; Kasiviswanathan, S.; Vagadia, Megha; Nigam, A. K.

2018-04-01

In the present study magnetic and electrical transport properties of transition metal substituted Co-Ga alloys (near critical cobalt concentration) have been investigated. Analysis of temperature and field dependence of dc magnetization and ac susceptibility (ACS) data suggests an evidence of reentrant spin glass (RSG) phase in Co55.5TM3Ga41.5 (TM = Co, Cr, Fe, Cu). The magnetic transition temperatures (TC and Tf) are found to depend on the nature of TM element substitution with the exchange coupling strength Co-Fe > Co-Co > Co-Cu > Co-Cr. From magnetization dynamics precise transition temperatures for the glassy phases are estimated. It is found that characteristic relaxation times are higher than that of spin glasses with minimal spin-cluster formation. The RSG behavior has been further supported by the temperature dependence of magnetotransport studies. From the magnetic field and substitution effects it has been established that the magnetic and electrical transport properties are correlated in this system.

Ketogenic Diet Based on Extra Virgin Coconut Oil Has No Effects in Young Wistar Rats With Pilocarpine-Induced Epilepsy.

PubMed

Melo, Isabelle T; M Rêgo, Elisabete; Bueno, Nassib B; Gomes, Tâmara C; Oliveira, Suzana L; Trindade-Filho, Euclides M; Cabral, Cyro R; Machado, Tacy S; Galvão, Jaqueline A; R Ataide, Terezinha

2018-02-01

This study evaluated the effects of a ketogenic diet (KD) based on extra virgin coconut oil (Cocos nucifera L., VCO), on the treatment of epileptic rats. Two sets of experiments were conducted. First, male Wistar rats underwent induction of status epilepticus (SE) with the administration of pilocarpine intraperitoneally 21 animals reached spontaneous recurrent seizures (SRS) and were randomly allocated to the dietary regimens and video-monitored for 19 days. In the second experiment, 24 animals were randomized immediately after the induction of SE and followed for 67 days. Diets were as follows: Control (AIN-93G; 7% lipid), KetoTAGsoya (KD based on soybean oil; 69.79% lipid), and KetoTAGcoco (KD based on VCO; 69.79% lipid). There were no differences in the latency to the first crisis, total frequency, and duration of the SRS between groups in 2 experiments. The data suggest no effects of KD, with or without VCO, in rats with pilocarpine-induced epilepsy. © 2018 AOCS.

Virgin coconut oil supplementation ameliorates cyclophosphamide-induced systemic toxicity in mice.

PubMed

Nair, S S; Manalil, J J; Ramavarma, S K; Suseela, I M; Thekkepatt, A; Raghavamenon, A C

2016-02-01

Virgin coconut oil (VCO) is an unrefined kernal oil, prepared from Cocos nucifera L., having substantial nutritional and medicinal value. Experimental studies have suggested its antioxidant, anti-inflammatory, immunostimulatory and hypolipidemic effects. The present study assesses its effect on formalin-induced chronic inflammation and cyclophosphamide (CTX)-induced systemic toxicity in murine models. Oral administration of VCO effectively reduced formalin-induced paw oedema in mice with more or less similar efficacy as that of diclofenac. The CTX-induced hike in blood urea, creatinine, thiobarbituric acid reactive substances (TBARS) and liver marker enzymes in mice was marginally decreased by VCO (8 g/kg body weight) ingestion orally. The liver and kidney catalase, superoxide dismutase and glutathione peroxidase activities, together with cellular glutathione and TBARS levels, were found to be improved in these animals. Overall the study reveals the protective efficacy of VCO against secondary toxicity induced by CTX possibly through its antioxidant and anti-inflammatory properties. © The Author(s) 2015.

Fever detection from free-text clinical records for biosurveillance.

PubMed

Chapman, Wendy W; Dowling, John N; Wagner, Michael M

2004-04-01

Automatic detection of cases of febrile illness may have potential for early detection of outbreaks of infectious disease either by identification of anomalous numbers of febrile illness or in concert with other information in diagnosing specific syndromes, such as febrile respiratory syndrome. At most institutions, febrile information is contained only in free-text clinical records. We compared the sensitivity and specificity of three fever detection algorithms for detecting fever from free-text. Keyword CC and CoCo classified patients based on triage chief complaints; Keyword HP classified patients based on dictated emergency department reports. Keyword HP was the most sensitive (sensitivity 0.98, specificity 0.89), and Keyword CC was the most specific (sensitivity 0.61, specificity 1.0). Because chief complaints are available sooner than emergency department reports, we suggest a combined application that classifies patients based on their chief complaint followed by classification based on their emergency department report, once the report becomes available.

Synthesis of Ternary Borocarbonitrides by High Temperature Pyrolysis of Ethane 1,2-Diamineborane

PubMed Central

Leardini, Fabrice; Massimi, Lorenzo; Flores-Cuevas, Eduardo; Fernández, Jose Francisco; Ares, Jose Ramon; Betti, Maria Grazia; Mariani, Carlo

2015-01-01

Ethane 1,2-diamineborane (EDAB) is an alkyl-containing amine-borane adduct with improved hydrogen desorption properties as compared to ammonia borane. In this work, it is reported the high temperature thermolytic decomposition of EDAB. Thermolysis of EDAB has been investigated by concomitant thermogravimetry-differential thermal analysis-mass spectrometry experiments. EDAB shows up to four H2 desorption events below 1000 °C. Small fractions of CH4, C2H4 and CO/CO2 are also observed at moderate-high temperatures. The solid-state thermolysis product has been characterized by means of different structural and chemical methods, such as X-ray diffraction, Raman spectroscopy, Scanning electron microscopy, Elemental analysis, and X-ray photoelectron spectroscopy (XPS). The obtained results indicate the formation of a ternary borocarbonitride compound with a poorly-crystalline graphitic-like structure. By contrast, XPS measurements show that the surface is rich in carbon and nitrogen oxides, which is quite different to the bulk of the material. PMID:28793545

Room temperature stable CO x -free H2 production from methanol with magnesium oxide nanophotocatalysts.

PubMed

Liu, Zhengqing; Yin, Zongyou; Cox, Casandra; Bosman, Michel; Qian, Xiaofeng; Li, Na; Zhao, Hongyang; Du, Yaping; Li, Ju; Nocera, Daniel G

2016-09-01

Methanol, which contains 12.6 weight percent hydrogen, is a good hydrogen storage medium because it is a liquid at room temperature. However, by releasing the hydrogen, undesirable CO and/or CO 2 byproducts are formed during catalytic fuel reforming. We show that alkaline earth metal oxides, in our case MgO nanocrystals, exhibit stable photocatalytic activity for CO/CO 2 -free H 2 production from liquid methanol at room temperature. The performance of MgO nanocrystals toward methanol dehydrogenation increases with time and approaches ~320 μmol g -1 hour -1 after a 2-day photocatalytic reaction. The CO x -free H 2 production is attributed to methanol photodecomposition to formaldehyde, photocatalyzed by surface electronic states of unique monodispersed, porous MgO nanocrystals, which were synthesized with a novel facile colloidal chemical strategy. An oxygen plasma treatment allows for the removal of organic surfactants, producing MgO nanocrystals that are well dispersible in methanol.

Evolutionary fuzzy modeling human diagnostic decisions.

PubMed

Peña-Reyes, Carlos Andrés

2004-05-01

Fuzzy CoCo is a methodology, combining fuzzy logic and evolutionary computation, for constructing systems able to accurately predict the outcome of a human decision-making process, while providing an understandable explanation of the underlying reasoning. Fuzzy logic provides a formal framework for constructing systems exhibiting both good numeric performance (accuracy) and linguistic representation (interpretability). However, fuzzy modeling--meaning the construction of fuzzy systems--is an arduous task, demanding the identification of many parameters. To solve it, we use evolutionary computation techniques (specifically cooperative coevolution), which are widely used to search for adequate solutions in complex spaces. We have successfully applied the algorithm to model the decision processes involved in two breast cancer diagnostic problems, the WBCD problem and the Catalonia mammography interpretation problem, obtaining systems both of high performance and high interpretability. For the Catalonia problem, an evolved system was embedded within a Web-based tool-called COBRA-for aiding radiologists in mammography interpretation.

Green coconut mesocarp pretreated by an alkaline process as raw material for bioethanol production.

PubMed

Soares, Jimmy; Demeke, Mekonnen M; Foulquié-Moreno, Maria R; Van de Velde, Miet; Verplaetse, Alex; Fernandes, Antonio Alberto Ribeiro; Thevelein, Johan M; Fernandes, Patricia Machado Bueno

2016-09-01

Cocos nucifera L., coconut, is a palm of high importance in the food industry, but a considerable part of the biomass is inedible. In this study, the pretreatment and saccharification parameters NaOH solution, pretreatment duration and enzyme load were evaluated for the production of hydrolysates from green coconut mesocarp using 18% (w/v) total solids (TS). Hydrolysates were not detoxified in order to preserve sugars solubilized during the pretreatment. Reduction of enzyme load from 15 to 7.5 filter paper cellulase unit (FPU)/g of biomass has little effect on the final ethanol titer. With optimized pretreatment and saccharification, hydrolysates with more than 7% (w/v) sugars were produced in 48h. Fermentation of the hydrolysate using industrial Saccharomyces cerevisiae strains produced 3.73% (v/v) ethanol. Our results showed a simple pretreatment condition with a high-solid load of biomass followed by saccharification and fermentation of undetoxified coconut mesocarp hydrolysates to produce ethanol with high titer. Copyright © 2016 Elsevier Ltd. All rights reserved.

Crew Earth Observations (CEO) taken during Expedition Six

NASA Image and Video Library

2003-01-01

ISS006-E-51456 (2003) --- Marias Islands, Mexico is featured in this image photographed by an Expedition Six crewmember on the International Space Station. The view shows the land-sea interactions along a section of Mexico's west coast just south of Mazatlan and the Isla Marias archipelago. The islands are a manifestation of intersecting plate boundaries -- the East Pacific Rise spreading center that traces south from the Gulf of California, and the subduction zone that consumes the Cocos plate beneath southern Mexico. These islands are biologically important: they comprise the Islas Marias Biosphere Reserve and contain endemic species of raccoons and rabbits, and important habitat for birds and marine life. Between the islands and the mainland, swirling surface currents are highlighted by the sun glint reflecting off the ocean surface. Along the Mexican coast, water flows out from a coastal lagoon, and near shore currents carry sediment (light colored water) along the beach front.

GoAmazon2014/15. Oxidation Flow Reactor Final Campaign Report

DOE Office of Scientific and Technical Information (OSTI.GOV)

Jimenez, J. L.; Day, D. A.; Hu, W.

The primary goal of the Green Ocean Amazon (GoAmazon2014/5) field campaign was to measure and mechanistically understand the formation of particle number and mass in a region affected by large tropical rainforest biogenic emissions and sometimes anthropogenic influence from a large urban center. As part of the two intensive operational periods (IOPs) and in collaboration with Pacific Northwest National Laboratory (PNNL) and Harvard, the Jimenez Group proposed to deploy a High-Resolution Time-of-Flight Aerosol Mass Spectrometer (HR-ToF-AMS), Thermal Denuder (TD), Scanning Mobility Particle Size (SMPS), two oxidation flow reactors (OFR; including supporting O 3, CO/CO 2/CH 4, RH analyzers), and amore » high volume filter sampler (MCV) for the measurement of gas and aerosol chemical, physicochemical, and volatility properties. The two IOPs were conducted during the wet season (February to March, 2014) and dry season (August to October, 2014). This proposal was part of a collaborative proposal involving other university and government laboratories.« less

Isabela Island, Galapagos Islands

NASA Image and Video Library

1996-01-20

STS072-732-072 (11-20 Jan. 1996) --- Three of the nineteen Galapagos Islands are visible in this image, photographed from the Earth-orbiting Space Shuttle Endeavour. The Galapagos Islands are located 600 miles (1,000 kilometers) to the west of Ecuador. The largest of the islands, Isabela, is at center (north is toward the upper right corner). The numerous circular features on the island, highlighted by clouds, are volcanoes. The Galapagos Islands owe their existence to a hot spot, or persistent heat source in the mantle, which also is located over a rift, or place where plates are separating and new crust is being created. The rift is located between the Cocos and Nazca Plates. The dark linear features on the islands are lava flows from past eruptions. The island to the left of Isabela is Fernandina, while the island to the right is San Salvador. The Galapagos Islands were visited by the English naturalist Charles Darwin in 1835.

(Carbonato-κ2 O,O′)bis­(5,5′-dimethyl-2,2′-bipyridyl-κ2 N,N′)cobalt(III) bromide trihydrate

PubMed Central

Arun Kumar, Kannan; Meera, Parthsarathi; Amutha Selvi, Madhavan; Dayalan, Arunachalam

2012-01-01

In the title complex, [Co(CO3)(C12H12N2)2]Br·3H2O, the CoIII cation has a distorted octa­hedral coordination environment. It is chelated by four N atoms of two different 5,5′-dimethyl-2,2′-bipyridyl (dmbpy) ligands in axial and equatorial positions, and by two O atoms of a carbonate anion completing the equatorial positions. Although the water mol­ecules are disordered and their H atoms were not located, there are typical O⋯O distances between 2.8 and 3.0 Å, indicating O—H⋯O hydrogen bonding. The crystal packing is consolidated by C—H⋯O and C—H⋯Br hydrogen bonds, as well as π–π stacking inter­actions between adjacent pyridine rings of the dmbpy ligands, with centroid–centroid distances of 3.694 (3) and 3.7053 (3) Å. PMID:22589773

Tectonic Structure of the Middle America Pacific Margin and Incoming Cocos Plate From Costa Rica to Guatemala

NASA Astrophysics Data System (ADS)

Ranero, C. R.; Weinrebe, W.; Grevemeyer, I.; Phipps Morgan, J.; Vannucchi, P.; von Huene, R.

2003-12-01

A new multibeam bathymetry and magnetic survey with R/V SONNE in summer 2003 has mapped the continental margin and incoming plate of NW Nicaragua, El Salvador and Guatemala, extending existing coverage from offshore Costa Rica and part of Nicaragua to a full coverage map of about 1200 km long by 100 km wide area along the plate boundary. The incoming plate along Nicaragua, El Salvador and Guatemala is of similar age and was formed at superfast spreading rates; however, its morphology changes drastically along strike. The seafloor-spreading inherited morphology is very smooth along Nicaragua, but with ridges up to 800 m high in Guatemala, with a transition across El Salvador. The development and dimensions of the dominant inherited fabric seems to be related to discontinuities at the paleospreading center. A series of troughs oblique to the main fabric may indicate the location of pseudofaults and correspond to areas where the seafloor fabric is most prominent. Bending of the oceanic plate into the trench reactivates the inherited fabric forming a well pervasive faulting system along the oceanic trench slope. The continental slope displays three morphotectonic units that roughly correspond to the upper, middle and lower slope, although the across slope width of each unit is fairly variable. Small canyons and gullies that form at the sudden dip change across the shelf break carve the upper slope. The canyons coalesce and become shallower as the dip decreases downslope. Locally some large canyons continue into the slope toe. The middle slope is a rough terrain variable in width and dip sculptured by pervasive normal faulting and locally by mass wasting processes. The lower slope is formed by en echelon terraces striking similar to the rough terrain of the incoming plate and mimicking the half graben morphology of the underthusting plate. The three morphotectonic slope domains represent differences in tectonic activity, with more stable upper slope, a middle slope dominated by tectonic extension and the thin, highly fractured upper plate of the lower slope riffling over the incoming plate topography. The trench axis is largely empty, with local turbidite ponds at the mouth of a few large canyons transecting the entire slope.

Transcriptome and secretome analyses of the wood decay fungus Wolfiporia cocos support alternative mechanisms of lignocellulose conversion

Treesearch

Jill Gaskell; Robert A. Blanchette; Philip E. Stewart; Sandra Splinter BonDurant; Marie Adams; Grzegorz Sabat; Philip Kersten; Daniel Cullen

2016-01-01

Certain wood decay basidiomycetes, collectively referred to as brown rot fungi, rapidly depolymerize cellulose while leaving behind the bulk of cell wall lignin as a modified residue. The mechanism(s) employed is unclear, but considerable evidence implicates the involvement of diffusible oxidants generated via Fenton-like chemistry. Toward a better understanding of...

Wolfiporia cocos : a potential agent for composting of bioprocessing Douglas-fir wood treated with copper-based preservatives

Treesearch

Rodney. De Groot; Bessie. Woodward

1998-01-01

In laboratory experiments, Douglas-fir wood blocks that were treated with copper- based wood preservatives were challenged with two wood decay fungi known to be tolerant of copper. Factors influencing the amount of decay, as determined by loss of weight in the test blocks, were preservative, then fungus. Within those combinations, the relative importance of...

Prophylactic effect of coconut water (Cocos nucifera L.) on ethylene glycol induced nephrocalcinosis in male wistar rat.

PubMed

Gandhi, M; Aggarwal, M; Puri, S; Singla, S K

2013-01-01

Many medicinal plants have been employed during ages to treat urinary stones though the rationale behind their use is not well established. Thus, the present study was proposed to evaluate the effect of coconut water as a prophylactic agent in experimentally induced nephrolithiasis in a rat model. The male Wistar rats were divided randomly into three groups. Animals of group I (control) were fed standard rat diet. In group II, the animals were administrated 0.75% ethylene glycol in drinking water for the induction of nephrolithiasis. Group III animals were administrated coconut water in addition to ethylene glycol. All the treatments were continued for a total duration of seven weeks. Treatment with coconut water inhibited crystal deposition in renal tissue as well as reduced the number of crystals in urine. Furthermore, coconut water also protected against impaired renal function and development of oxidative stress in the kidneys. The results indicate that coconut water could be a potential candidate for phytotherapy against urolithiasis.

Optimization of ultrasound extraction of phenolic compounds from coconut (Cocos nucifera) shell powder by response surface methodology.

PubMed

Rodrigues, Sueli; Pinto, Gustavo A S; Fernandes, Fabiano A N

2008-01-01

Coconut is a tropical fruit largely consumed in many countries. In some areas of the Brazilian coast, coconut shell represents more than 60% of the domestic waste volume. The coconut shell is composed mainly of lignin and cellulose, having a chemical composition very similar to wood and suitable for phenolic extraction. In this work, the use of ultrasound to extract phenolic compounds from coconut shell was evaluated. The effect of temperature, solution to solid ratio, pH and extraction time were evaluated through a 2(4) experimental planning. The extraction process was also optimized using surface response methodology. At the optimum operating condition (30 degrees C, solution to solid ratio of 50, 15 min of extraction and pH 6.5) the process yielded 22.44 mg of phenolic compounds per gram of coconut shell.

Biodiversity Measurement Using Indices Based on Hyperspectral Reflectance on the Coast of Lagos

NASA Astrophysics Data System (ADS)

Omodanisi, E. O.; Salami, A. T.

2013-12-01

Hyperspectral measurements provide explicit measurements which can be used in the analysis of biodiversity change. This study was carried out in the coastal area of Lagos State, Nigeria. The objective of this study was to determine if gasoline seepage affects vegetation species distribution and reflectance; with the view to analyzing the vegetation condition. To evaluate the potential of different reflectance spectroscopy of species, the ASD Handheld2 Spectrometer was used. Three identified impacted plots of 30m by 30m were selected randomly and a control plot established in relatively undisturbed vegetated areas away from but perpendicular to the source of seepage. Each identified plot and the control consisted of five transects and measurement were taken at every 2m with about four reflectance measurement per sample point, to average out differences in reflectance as a result of different leaf angles. The radiance output of the spectrometer was converted into reflectance using the reflectance of a white reference over a standardized white spectralon panel. Indices such as Normalized Differential Vegetation Index, RedEdge Normalized Difference Vegetation Index, Soil Adjusted Vegetation Index, Ratio Vegetation Index and Volgelmann RedEdge Index 1 were calculated to accurately estimate the chlorophyll content in the vegetation within optimal band wavelength. Shannon-Weiner's index, Spearman's rank correlation and Analysis of Variance were used to analyze the data. Cocos nucifera was observed to be the most dominant species with a relative abundance of 47.27% while Ananas comosus recorded the lowest relative abundance of 21.8%. In the control plot, Cocos nucifera had the highest relative abundance of 42.3% and Mangifera indica with the least relative abundance of 16.7%. The relationship between the indices and chlorophyll content of the vegetation were significantly higher at (p>0.01) for all the indices in all the plots; however, RedEdgeNDVI and VOG1 indices had the

Coseismic and postseismic stress changes in a subducting plate: Possible stress interactions between large interplate thrust and intraplate normal-faulting earthquakes

NASA Astrophysics Data System (ADS)

Mikumo, Takeshi; Yagi, Yuji; Singh, Shri Krishna; Santoyo, Miguel A.

2002-01-01

A large intraplate, normal-faulting earthquake (Mw = 7.5) occurred in 1999 in the subducting Cocos plate below the downdip edge of the ruptured thrust fault of the 1978 Oaxaca, Mexico, earthquake (Mw = 7.8). This situation is similar to the previous case of the 1997 normal-faulting event (Mw = 7.1) that occurred beneath the rupture area of the 1985 Michoacan, Mexico, earthquake (Mw = 8.1). We investigate the possibility of any stress interactions between the preceding 1978 thrust and the following 1999 normal-faulting earthquakes. For this purpose, we estimate the temporal change of the stress state in the subducting Cocos plate by calculating the slip distribution during the 1978 earthquake through teleseismic waveform inversion, the dynamic rupture process, and the resultant coseismic stress change, together with the postseismic stress variations due to plate convergence and the viscoelastic relaxation process. To do this, we calculate the coseismic and postseismic changes of all stress components in a three-dimensional space, incorporating the subducting slab, the overlying crust and uppermost mantle, and the asthenosphere. For the coseismic stress change we solve elastodynamic equations, incorporating the kinematic fault slip as an observational constraint under appropriate boundary conditions. To estimate postseismic stress accumulations due to plate convergence, a virtual backward slip is imposed to lock the main thrust zone. The effects of viscoelastic stress relaxations of the coseismic change and the back slip are also included. The maximum coseismic increase in the shear stress and the Coulomb failure stress below the downdip edge of the 1978 thrust fault is estimated to be in the range between 0.5 and 1.5 MPa, and the 1999 normal-faulting earthquake was found to take place in this zone of stress increase. The postseismic variations during the 21 years after the 1978 event modify the magnitude and patterns of the coseismic stress change to some extent but

Kinematics of the Southwestern Caribbean from New Geodetic Observations

NASA Astrophysics Data System (ADS)

Ruiz, G.; La Femina, P. C.; Tapia, A.; Camacho, E.; Chichaco, E.; Mora-Paez, H.; Geirsson, H.

2014-12-01

The interaction of the Caribbean, Cocos, Nazca, and South American plates has resulted in a complex plate boundary zone and the formation of second order tectonic blocks (e.g., the North Andean, Choco and Central America Fore Arc blocks). The Panama Region [PR], which is bounded by these plates and blocks, has been interpreted and modeled as a single tectonic block or deformed plate boundary. Previous research has defined the main boundaries: 1) The Caribbean plate subducts beneath the isthmus along the North Panama Deformed Belt, 2) The Nazca plate converges at very high obliquity with the PR and motion is assumed along a left lateral transform fault and the South Panama Deformed Belt, 3) The collision of PR with NW South America (i.e., the N. Andean and Choco blocks) has resulted in the Eastern Panama Deformed Belt, and 4) collision of the Cocos Ridge in the west is accommodated by crustal shortening, Central American Fore Arc translation and deformation across the Central Costa Rican Deformed Belt. In addition, there are several models that suggest internal deformation of this region by cross-isthmus strike-slip faults. Recent GPS observations for the PR indicates movement to the northeast relative to a stable Caribbean plate at rates of 6.9±4.0 - 7.8±4.8 mm a-1 from southern Costa Rica to eastern Panama, respectively (Kobayashi et al., 2014 and references therein). However, the GPS network did not have enough spatial density to estimate elastic strain accumulation across these faults. Recent installation and expansion of geodetic networks in southwestern Caribbean (i.e., Costa Rica, Panama, and Colombia) combined with geological and geophysical observations provide a new input to investigate crustal deformation processes in this complex tectonic setting, specifically related to the PR. We use new and existing GPS data to calculate a new velocity field for the region and to investigate the kinematics of the PR, including elastic strain accumulation on the

Impact fracture experiments simulating interstellar grain-grain collisions

NASA Technical Reports Server (NTRS)

Freund, Friedemann; Chang, Sherwood; Dickinson, J. Thomas

1990-01-01

Oxide and silicate grains condensing during the early phases of the formation of the solar system or in the outflow of stars are exposed to high partial pressures of the low-z elements H, C, N and O and their simple gaseous compounds. Though refractory minerals are nominally anhydrous and non-carbonate, if they crystallize in the presence of H2O, N2 and CO or CO2 gases, they dissolve traces of the gaseous components. The question arises: How does the presence of dissolved gases or gas components manifest itself when grain-grain collisions occur. What are the gases emitted when grains are shattered during a collision event. Researchers report on fracture experiments in ultrahigh vacuum (UHV, approximately less than 10 to the -8th power mbar) designed to measure (by means of a quadrupole mass spectrometer, QMS, with microns to ms time resolution) the emission of gases and vapors during and after impact (up to 1.5 sec). Two terrestrial materials were chosen which represent structural and compositional extremes: olivine (San Carlos, AZ), a densely packed Mg-Fe(2+) silicate from the upper mantle, available as 6 to 12 mm single crystals, and obsidian (Oregon), a structurally open, alkaline-SiO2-rich volcanic glass. In the olivine crystals OH- groups have been identified spectroscopically, as well as H2 molecules. Obsidian is a water-rich glass containing OH- besides H2O molecules. Olivine from the mantle often contains CO2, either as CO2-rich fluid in fluid inclusions or structurally dissolved or both. By analogy to synthetic glasses CO2 in the obsidian may be present in form of CO2 molecules in voids of molecular dimensions, or as carbonate anions, CO3(2-). No organic molecules have been detected spectroscopically in either material. Results indicate that refractory oxide/silicates which contain dissolved traces of the H2O and CO/CO2 components but no spectroscopically detectable traces of organics may release complex H-C-O (possibly H-C-N-O) molecules upon fracture

Atmospheric processes in reaction of Northern Sumatra Earthquake sequence Dec 2004-Apr 2005

NASA Astrophysics Data System (ADS)

Ouzounov, D.; Pulinets, S.; Cervone, G.; Singh, R.; Taylor, P.

2005-05-01

This work describes our first results in analyzing data from different and independent sources ûemitted long-wavelength radiation (OLR), surface latent heat flux (SHLF) and GPS Total Electron Content (TEC) collected from ground based (GPS) and satellite TIR (thermal infra-red) data sources (NOAA/AVHRR, MODIS). We found atmosphere and ionosphere anomalies one week prior to both the Sumatra-Andaman Islands earthquake (Dec 26, 2004) and M 8.7 - Northern Sumatra, March 28, 2005. We analyzed 118 days of data from December 1, 2004 through April 1, 2005 for the area (0°-10°,north latitude and 90°-100° east longitude) which included 125 earthquakes with M>5.5. Recent analysis of the continuous OLR from the Earth surface indicates anomalous variations (on top of the atmosphere) prior to a number of medium to large earthquakes. In the case of M 9.0 - Sumatra-Andaman Islands event, compared to the reference fields for the months of December between 2001 and 2004, we found strongly OLR anomalous +80 W/m2 signals (two sigma) along the epicentral area on Dec 21, 2004 five days before the event. In the case of M8.7 March 28, 2005 anomalues signatures over the epicenter appears on March 26 is much weaker (only +20W/m2) and have a different topology. Anomalous values of SHLF associated with M9.0 - Sumatra-Andaman Islands were found on Dec 22, 2005 (SLHF +280Wm2) and less intensity on Mar 23, 2005 (SLHF +180Wm2). Ionospheric variations (GPS/TEC) associated with the Northern Sumatra events were determine by five Regional GPS network stations (COCO, BAKO, NTUS, HYDE and BAST2). For every station time series of the vertical TEC (VTEC) were computed together with correlation with the Dst index. On December 22, four days prior to the M9.0 quake GPS/TEC data reach the monthly maximum for COCO with minor DST activity. For the M 8.7-March 28 event, the increased values of GPS/TEC were observed during four days (March 22-25) in quiet geomagnetic background. Our results need additional

Normal block faulting in the Airport Graben, Managua pull-apart rift, Nicaragua: gravity and magnetic constraints

NASA Astrophysics Data System (ADS)

Campos-Enriquez, J. O.; Zambrana Arias, X.; Keppie, D.; Ramón Márquez, V.

2012-12-01

Regional scale models have been proposed for the Nicaraguan depression: 1) parallel rifting of the depression (and volcanic front) due to roll back of the underlying subducted Cocos plate; 2) right-lateral strike-slip faulting parallel to the depression and locally offset by pull-apart basins; 3) right-lateral strike-slip faulting parallel to the depression and offset by left-lateral transverse or bookshelf faults. At an intermediate scale, Funk et al. (2011) interpret the depression as half graben type structures. The E-W Airport graben lies in the southeastern part of the Managua graben (Nicaragua), across which the active Central American volcanic arc is dextrally offset, possibly the result of a subducted transform fault where the subduction angle changes. The Managua graben lies within the late Quaternary Nicaragua depression produced by backarc rifting during roll back of the Middle American Trench. The Managua graben formed as a pull-apart rift associated with dextral bookshelf faulting during dextral shear between the forearc and arc and is the locus of two historical, large earthquakes that destroyed the city of Managua. In order to asses future earthquake risk, four E-W gravity and magnetic profiles were undertaken to determine its structure across the Airport graben, which is bounded by the Cofradia and Airport fault zones, to the east and west, respectively. These data indicated the presence of a series of normal faults bounding down-thrown and up-thrown fault blocks and a listric normal fault, Sabana Grande Fault. The models imply that this area has been subjected to tectonic extension. These faults appear to be part of the bookshelf suite and will probably be the locus of future earthquakes, which could destroy the airport and surrounding part of Managua. Three regional SW-NE gravity profiles running from the Pacific Ocean up to the Caribbean See indicate a change in crustal structure: from north to south the crust thins. According to these regional

Thermal evolution of Site U1414 by stable isotopes δ13C and δ18O, 87Sr/86Sr and fluid inclusion analyses, IODP Expedition 344

NASA Astrophysics Data System (ADS)

Brandstätter, Jennifer; Kurz, Walter; Krenn, Kurt; Richoz, Sylvain

2017-04-01

IODP Expedition 344 is the second expedition in course of the Costa Rica Seismogenesis Project (Program A), that was designed to reveal processes that effect nucleation and seismic rupture of large earthquakes at erosional subduction zones. Site 344-U1414, located 1 km seaward of the deformation front offshore Costa Rica, serves to evaluate fluid-rock interaction and geochemical processes linked with the tectonic evolution of the incoming Cocos Plate from the Early Miocene up to recent times. Combined isotope analyses and microthermometric analyses of fluid inclusions of hydrothermal veins within lithified sediments and the igneous basement (Cocos Ridge basalt), was used to reveal the thermal history of Site 344-U1414. Veins in the sedimentary rocks are mainly filled by coarse-grained calcite and subordinately by quartz. Veins within the basalt show polymineralic filling of clay minerals, calcite, aragonite and quartz. Blocky veins with embedded wall rock fragments, appearing in the sediments and in the basalt, indicate hydraulic fracturing. The carbon isotopic composition of the vein calcite suggest the influence of a CO2 -rich fluid mixed with seawater (-3.0 to -0.4‰ V-PDB) and the δ18O values can be differentiated in two groups, depending on the formation temperature (-13.6 to -9.3‰ and -10.8 to -4.7‰ V-PDB). 87Sr/86Sr ratios from the veins confirm the results of the stable isotope analyses, with a higher 87Sr/86Sr ratio close to seawater composition and lower ratios indicating the influence of basalt alteration. The hydrothermal veins contain different types of fluid inclusions with high and low entrapment temperatures and low saline fluids. The occurrence of decrepitated fluid inclusions, formed by increased internal overpressure, is related to isobaric heating. Elongated fluid inclusion planes, arc-like fluid inclusions and low homogenization temperatures suggest subsequent isobaric cooling. The stable isotopic content, strontium isotopic composition

Ionospheric response to the 17-18 March 2015 geomagnetic storm as seen from multiple TEC and NmF2 measurements along 100°E

NASA Astrophysics Data System (ADS)

Bhuyan, Pradip; Yokoyama, Tatsuhiro; Kalita, Bitap Raj; Seemala, G. K.; Hazarika, Rumajyoti; Komolmis, Tharadol; Yatini, Clara; Chakrabarty, Dibyendu; Supnithi, Pornchai

2016-07-01

The response of the ionosphere along 100°E to the strong geomagnetic storm of 17-18 March 2015 has been investigated combining TEC and NmF2 data from multiple stations spanning low latitudes in the northern and southern hemispheres to the equator. The GPS TEC data measured over Dibrugarh (27.4°N, 95°E), Kohima (25.6°N, 94.1°E) and Ahmedabad (23.0°N, 72.5°E) and NmF2 measured along a chain of ionosonde stations Dibrugarh (27.5°N, 95°E), Chiang Mai (18.76ºN, 98.93ºE), Chumphon (10.72ºN,99.37ºE), Kototabang (0.2ºS,100.32ºE) and Cocos Island (12.2ºS,96.8ºE ) were used to examine the signature of the storm around the low-mid latitude ionosphere in this sector. Nearly similar TEC variation has been observed over Dibrugarh and Kohima located at the northern edge of the EIA. The maximum TEC on 18 March over Dibrugarh and Kohima was reduced by more than ~80 TECU compared to that on the geomagnetically quiet day of 16 March 2015. In contrast to the substantial reduction in TEC over ~100°E TEC from the ~75°E longitude station Ahmedabad showed insignificant variations on the same day. Strong reduction in NmF2 at the crest of the anomaly in both northern and southern hemisphere (Dibrugarh, Ching Mai and Cocos Island) and enhancement near the equator (Cumphon and Kototbang) has been observed. The O/N2 ratio as obtained from the TIMED/GUVI reduced substantially along 100°E on 18 March compared to other longitude sectors. Equatorward meridional winds depleted the ionization at the crest region and enhanced the same near the equator. No L band scintillation was observed in the evening of 17 March at Dibrugarh and Kohima indicating absence of F region irregularity along this longitude while strong scintillations were observed at 75°E. The reversal of the IMF Bz from southward to northward direction in the dusk to evening sector inhibited the growth of the irregularity due to reversal of the PPEF at 100°E while the PPEF favoured generation and growth of Spread F

Probabilistic Seismic Hazard Assessment of the Chiapas State (SE Mexico)

NASA Astrophysics Data System (ADS)

Rodríguez-Lomelí, Anabel Georgina; García-Mayordomo, Julián

2015-04-01

The Chiapas State, in southeastern Mexico, is a very active seismic region due to the interaction of three tectonic plates: Northamerica, Cocos and Caribe. We present a probabilistic seismic hazard assessment (PSHA) specifically performed to evaluate seismic hazard in the Chiapas state. The PSHA was based on a composited seismic catalogue homogenized to Mw and was used a logic tree procedure for the consideration of different seismogenic source models and ground motion prediction equations (GMPEs). The results were obtained in terms of peak ground acceleration as well as spectral accelerations. The earthquake catalogue was compiled from the International Seismological Center and the Servicio Sismológico Nacional de México sources. Two different seismogenic source zones (SSZ) models were devised based on a revision of the tectonics of the region and the available geomorphological and geological maps. The SSZ were finally defined by the analysis of geophysical data, resulting two main different SSZ models. The Gutenberg-Richter parameters for each SSZ were calculated from the declustered and homogenized catalogue, while the maximum expected earthquake was assessed from both the catalogue and geological criteria. Several worldwide and regional GMPEs for subduction and crustal zones were revised. For each SSZ model we considered four possible combinations of GMPEs. Finally, hazard was calculated in terms of PGA and SA for 500-, 1000-, and 2500-years return periods for each branch of the logic tree using the CRISIS2007 software. The final hazard maps represent the mean values obtained from the two seismogenic and four attenuation models considered in the logic tree. For the three return periods analyzed, the maps locate the most hazardous areas in the Chiapas Central Pacific Zone, the Pacific Coastal Plain and in the Motagua and Polochic Fault Zone; intermediate hazard values in the Chiapas Batholith Zone and in the Strike-Slip Faults Province. The hazard decreases

Rapid Seismic Deployment for Capturing Aftershocks of the September 2017 Tehuantepec, Mexico (M=8.1) and Morelos-Puebla (M=7.1), Mexico Earthquakes

NASA Astrophysics Data System (ADS)

Velasco, A. A.; Karplus, M. S.; Dena, O.; Gonzalez-Huizar, H.; Husker, A. L.; Perez-Campos, X.; Calo, M.; Valdes, C. M.

2017-12-01

The September 7 Tehuantepec, Mexico (M=8.1) and the September 19 Morelos-Puebla, Mexico (M=7.1) earthquakes ruptured with extensional faulting within the Cocos Plate at 70-km and 50-km depth, as it subducts beneath the continental North American Plate. Both earthquakes caused significant damage and loss of life. These events were followed by a M=6.1 extensional earthquake at only 10-km depth in Oaxaca on September 23, 2017. While the Morelos-Puebla earthquake was likely too far away to be statically triggered by the Tehuantepec earthquake, initial Coulomb stress analyses show that the M=6.1 event may have been an aftershock of the Tehuantepec earthquake. Many questions remain about these earthquakes, including: Did the Cocos Plate earthquakes load the upper plate, and could they possibly trigger an equal or larger earthquake on the plate interface? Are these the result of plate bending? Do the aftershocks migrate to the locked zone in the subduction zone? Why did the intermediate depth earthquakes create so much damage? Are these earthquakes linked by dynamic stresses? Is it possible that a potential slow-slip event triggered both events? To address some of these questions, we deployed 10 broadband seismometers near the epicenter of the Tehuantepec, Mexico earthquake and 51 UTEP-owned nodes (5-Hz, 3-component geophones) to record aftershocks and augment networks deployed by the Universidad Nacional Autónoma de México (UNAM). The 10 broadband instruments will be deployed for 6 months, while the nodes were deployed 25 days. The relative ease-of-deployment and larger numbers of the nodes allowed us to deploy them quickly in the area near the M=6.1 Oaxaca earthquake, just a few days after that earthquake struck. We deployed them near the heavily-damaged cities of Juchitan, Ixtaltepec, and Ixtepec as well as in Tehuantepec and Salina Cruz, Oaxaca in order to test their capabilities for site characterization and aftershock studies. This is the first test of these

Recent Intermediate Depth Earthquakes in El Salvador, Central Mexico, Cascadia and South-West Japan

NASA Astrophysics Data System (ADS)

Lemoine, A.; Gardi, A.; Gutscher, M.; Madariaga, R.

2001-12-01

We studied occurence and source parameters of several recent intermediate depth earthquakes. We concentrated on the Mw=7.7 salvadorian earthquake which took place on January 13, 2001. It was a good example of the high seismic risk associated to such kind of events which occur closer to the coast than the interplate thrust events. The Salvadorian earthquake was an intermediate depth downdip extensional event which occured inside the downgoing Cocos plate, next to the downdip flexure where the dip increases sharply before the slab sinks more steeply. This location corresponds closely to the position of the Mw=5.7 1996 and Mw=7.3 1982 downdip extensional events. Several recent intermediate depth earthquakes occured in subduction zones exhibiting a ``flat slab'' geometry with three distinct flexural bends where flexural stress may be enhanced. The Mw=6.7 Geiyo event showed a downdip extensional mechanism with N-S striking nodal planes. This trend was highly oblique to the trench (Nankai Trough), yet consistent with westward steepening at the SW lateral termination of the SW Japan flat slab. The Mw=6.8 Olympia earthquake in the Cascadia subduction zone occured at the downdip termination of the Juan de Fuca slab, where plate dip increases from about 5o to over 30o. The N-S orientation of the focal planes, parallel to the trench indicated downdip extension. The location at the downdip flexure corresponds closely to the estimated positions of the 1949 M7.1 Olympia and 1965 M6.5 Seattle-Tacoma events. Between 1994 and 1999, in Central Mexico, an unusually high intermediate depth seismicity occured where several authors proposed a flat geometry for the Cocos plate. Seven events of magnitude between Mw=5.9 and Mw=7.1 occured. Three of them were downdip compressional and four where down-dip extensional. We can explain these earthquakes by flexural stresses at down-dip and lateral terminations of the supposed flat segment. Even if intermediate depth earthquakes occurence could

Surface thermodynamic stability, electronic and magnetic properties in various (001) surfaces of Zr2CoSn Heusler alloy

NASA Astrophysics Data System (ADS)

Yang, Yan; Feng, Zhong-Ying; Zhang, Jian-Min

2018-05-01

The spin-polarized first-principles are used to study the surface thermodynamic stability, electronic and magnetic properties in various (001) surfaces of Zr2CoSn Heusler alloy, and the bulk Zr2CoSn Heusler alloy are also discussed to make comparison. The conduction band minimum (CBM) of half-metallic (HM) bulk Zr2CoSn alloy is contributed by ZrA, ZrB and Co atoms, while the valence band maximum (VBM) is contributed by ZrB and Co atoms. The SnSn termination is the most stable surface with the highest spin polarizations P = 77.1% among the CoCo, ZrCo, ZrZr, ZrSn and SnSn terminations of the Zr2CoSn (001) surface. In the SnSn termination of the Zr2CoSn (001) surface, the atomic partial density of states (APDOS) of atoms in the surface, subsurface and third layers are much influenced by the surface effect and the total magnetic moment (TMM) is mainly contributed by the atomic magnetic moments of atoms in fourth to ninth layers.