Sample records for tektites

  1. Tektite origin by hypervelocity asteroidal or cometary impact: The quest for the source craters

    NASA Technical Reports Server (NTRS)

    Koeberl, Christian

    1992-01-01

    Tektites are natural glasses that are chemically homogeneous, often spherically symmetrical objects several centimeters in size, and occur in four known strewn fields on the surface of the Earth: the North American, moldavite (or Central European), Ivory Coast, and Australasian strewn fields. Tektites found within such strewn fields are related to each other with respect to their petrological, physical, and chemical properties as well as their age. A theory of tektite origin needs to explain the similarity of tektites in respect to age and certain aspects of isotopic and chemical composition within one strewn field, as well as the variety of tektite materials present in each strewn field. In addition to tektites on land, microtektites (which are generally less than 1 mm in diameter) have been found in deep-sea cores. Tektites are classified into three groups: (1) normal or splash-form tektites, (2) aerodynamically shaped tektites, and (3) Muong Nong-type tektites (sometimes also called layered tektites). The aerodynamic ablation results from partial remelting of glass during atmospheric passage after it was ejected outside the terrestrial atmosphere and quenched from a hot liquid. Aerodynamically shaped tektites are known mainly from the Australasian strewn field where they occur as flanged-button australites. The shapes of splash-form tektites (spheres, droplets, teardrops, dumbbells, etc., or fragments thereof) are the result of the solidification of rotating liquids in the air or vacuum. Mainly due to chemical studies, it is now commonly accepted that tektites are the product of melting and quenching of terrestrial rocks during hypervelocity impact on the Earth. The chemistry of tektites is in many respects identical to the composition of upper crustal material.

  2. A Cuban tektite

    USGS Publications Warehouse

    Garlick, G.D.; Naeser, C.W.; O'Neil, J.R.

    1971-01-01

    A large tektite from Cuba is classified with other North American tektites on the basis of its age. The major-element chemistry, oxygen isotopic composition, refractive index and density of the Cuban tektite are within the ranges exhibited by bediasites. ?? 1971.

  3. Study of the ablative effects on tektites: Atmosphere entry of a swarm of tektites. [shielding by hypersonic wake

    NASA Technical Reports Server (NTRS)

    Sepri, P.; Chen, K. K.

    1977-01-01

    The large variety of ablation markings observed on recovered tektites lead to the previously proposed swarm wake model which states that the lead peripheral tektites bore the blunt of aerodynamic heating upon entry, and that the bulk of tektites in the wake enjoyed partial shielding at the expense of the leaders. Further considerations are presented in support of this model. Quantitative assessments indicate that wake shielding might indeed have provided for substantially less heating than would have been experienced by a tektite entering an undisturbed atmosphere along a similar trajectory. For the case of strong wake shielding it is even possible that the surface temperature of a falling tektite had barely reached its melting point. In the distribution of tektites, there is a size band (near R = 0.5 cm) which is least susceptible to melting.

  4. Mechanism of Muong Nong-type tektite formation and speculation on the source of Australasian tektites

    NASA Technical Reports Server (NTRS)

    Schnetzler, C. C.

    1992-01-01

    The source crater of the youngest and largest of the tektite strewnfields, the Australasian strewnfield, has not been located. A number of lines of evidence indicate that the Muong Nong-type tektites, primarily found in Indochina, are more primitive than the much more abundant and widespread splash-form tektites, and are proximal to the source. In this study the spatial distribution of Muong Nong-type tektite sites and chemical character have been used to indicate the approximate location of the source. The variation of Muong Nong-type tektite chemical composition appears to be caused by mixing of two silicate rock end-members and a small amount of limestone, and not by vapor fractionation. The variation in composition is not random, and does not support in situ melting or multiple impact theories. The distribution of both Muong Nong and splash-form tektite sites suggest the source is in a limited area near the southern part of the Thailand-Laos border.

  5. Constraints on the formation of layered tektites from the excavation and analysis of layered tektites from northeast Thailand

    NASA Astrophysics Data System (ADS)

    Fiske, Peter S.

    1996-01-01

    The size, shape, composition, and vesicle content of 6 kg of layered tektite fragments, excavated near the town of Huai Sai, Thailand, place some constraints on the formation of layered tektites. The mass, shape, and distribution of the fragments are not consistent with an origin as a "puddle" of impact melt but suggest that they were derived from a single equant block. The presence of vesicles up to 7 mm in mean diameter within the tektite fragments suggests that the material was too viscous to allow for significant gravity-driven flow. These results suggest that layered tektites may be analogous to lava bombs, which may have been stretched and deformed in flight but underwent little flow after landing. Rather than being a product of "unusual circumstances," such as multiple impacts, layered tektites may differ from splash-form tektites only in initial temperature of formation, speed of ejection, and small differences in initial composition.

  6. New data on selected Ivory Coast tektites

    USGS Publications Warehouse

    Cuttitta, F.; Carron, M.K.; Annell, C.S.

    1972-01-01

    Fourteen Ivory Coast tektites exhibit a range of bulk indices of refraction of 1.5156 to 1.5217 ?? 0.0004 and of bulk specific gravities of 2.428 to 2.502 ??0.005. Seven of these Ivory Coast (IVC) tektites were analyzed for major and minor element content. Compared to tektites from other strewn fields, their SiO2 content is low (67.2-69.1 %), A12O3 relatively high (15.8-16.8 %), and total iron relatively high but with a more restricted range (6.3-6.8 % as FeO). Their lime content is low (0.71-1.35%) compared to Australasian tektites but their MgO CaO ratio (about 3.1) is unusually high. All other tektite groups have Na2O K2O ratios less than unity, but the Na2O K2O ratio of the IVC tektites is slightly greater than unity. Their K Rb ratios range from 200 to 256 and average 227, which is higher than those determined for Australasian tektites, but similar to some obtained for moldavites. The Li content (41-48 ppm) is about the same as that of the Australasian tektites, but the Cs and Rb are lower, being 1.9 to 2.9 and 57 to 86 ppm, respectively. The IVC tektites are high in Cr (260-375 ppm), Co (19-25 ppm) and Ni (101-167 ppm), and particularly in Pb (<10-18 ppm), Cu (13-21 ppm) and Ga (14-23 ppm). The high Cr Ni ratios of the IVC tektites (range 2-3.6) are similar to those found for australites, philippinites and thailandites, but not the javanites and indochinites. Evaluation of these and other reported data show that compositional similarities between the IVC tektites and green or black Bosumtwi Crater glasses strongly support the hypothesis of a common impact origin-i.e. the Bosumtwi Crater site. Comparison of the IVC tektite composition with those of returned lunar materials (gabbros, basalts, breccia and soils) do not support a lunar origin for the Ivory Coast tektites. ?? 1972.

  7. Tektites and their origin. [properties and distribution

    NASA Technical Reports Server (NTRS)

    Okeefe, J. A.

    1975-01-01

    A study was conducted of the literature pertaining to the origin and characteristics of tektites. Topics discussed include tektite distribution in geographical locations, shapes of tektites, internal structure of tektites, physical properties, mechanical properties, optical properties, chemical composition, and comparisons with compositions of impact materials. Various arguments are presented on the terrestrial origin of tektites. It was found that some lunar craters of considerable size must be the products of volcanism which occurred during the past few million years, and that the moon must have within it a reservoir of rock which is considerably more like the mantle of the earth than like the rocks from which the basalts of the lunar crust are derived.

  8. The problem of the origin of tektites from Zhamanshin astrobleme

    NASA Astrophysics Data System (ADS)

    Takhauov, Artur; Anoshin, Dmitriy; Plotnikova, Irina

    2013-04-01

    Tektites (from Greek. Tektós - molten, melted) - are natural glassy formations of yellow, green, but mostly black color, completely fused, that may have different shape and size. According to their composition tektites are high-silicon (acidic) glasses. The content of SiO may reach 88,5%, AlO - 20,5%, FeO - 11,5%, and CaO - 8,5%. The presence of Ni and relatively low content of water in comparison with other glasses (only 0.02%, which is 10 times less than in the volcanic glass) is of particular importance. The name to tektites was given by Austrian geologist E. Suess (1900). Tektites are often denominated according to their location: irgizites and zhamanshinites (river Irgiz and Zhamanshin hole in Kazakhstan), moldavites [river Moldava (modern Vltava, Czech Republic)] filippinites (Philippines), idoshinites (Indo-china), avstralites (Australia), etc. There is still no generally accepted hypothesis about the origin of tektites: some consider them to be a part of meteorites, others suggest that tektites are the result of the explosion and melting of terrestrial matter that happens when meteorites, asteroids or comets fall down on Earth. The aim of the present work is to conduct analytic studies of tektites from Zhamanshin crater. We examined 50 samples that are part of the collection from the Zhamanshin crater gathered in 1979 by I.N. Plotnikova during her student field expedition led by P.V. Florenskiy. For the convenience of the research of tektites during its early stages the authors compiled a morphological classification of the given samples. On the basis of the visual inspection by the help of a magnifying glass we distinguished the following groups of tektites, which are characterized by certain morphological features: 1. Porous (cavernous), black, isometric shape 2. Porous (cavernous), yellowish-brown, isometric shape 3. Elongated, torose 4. Elongated, with glassy luster 5. Elongated, twisted 6. worm-shaped 7. Vitreous, glassy 8. Deformated The vast majority of researchers believe that the surface of tektites reflects the dynamic resistance of the medium (air) that they were experiencing in their movement. Visual examination of the samples confirms that, and looking at the most tektites, it is difficult not to agree with this idea. Consequently, we can make an assumption that the morphology of tektites depends on the conditions of the genesis (in particular, on the distance and the expansion velocity of tektites). Aubrey Whymark, a famous contemporary specialist in tektites, also believes that the morphology is associated with the range of expansion of tektites from an impact crater, which, according to his theory, are formed as a result of impact metamorphism. This opinion is shared by many scientists involved in the research of tektites. In the next phase of the research the samples of all the morphological groups were examined using electron microscopy. During this analysis, we have found non-melted areas of the rock in 3 out of 50 samples (these were the rocks of the 2nd and the 7th groups from our classification). We also detected the features of the surface patterns that testify the impact formation of tektites.

  9. Origin of tektites

    NASA Technical Reports Server (NTRS)

    O'Keefe, John A.

    1994-01-01

    The origin of tektites has been obscure because of the following dilemma. The application of physical principles to the data available on tektites points strongly to origin from one or more lunar volcanoes; but few glasses of tektite composition have hitherto been reported from the lunar samples. Instead, the lunar silicic glasses consist chiefly of a material very rich in K2O and poor in MgO. The ratio of K2O/MgO is higher in these glasses than in any tektites reported. The solution of the dilemma seems to come from the study of some recently discovered terrestrial deposits of tektite glass with high values of K2O/MgO at the Cretaceous Tertiary boundary. These glasses are found to be very vulnerable to crystallization into sandine or to alteration to smectite. These end products are known and are more abundant than any terrestrial deposits of tektite glass. It seems possible that, in fact, the moon produces tektite glass, mostly of the high K2O-low MgO type; but on Earth these deposits are destroyed. The much less abundant deposits with lower K and higher Mg are observed because they survive. Other objections to the lunar origin hypothesis appear to be answerable.

  10. The tektite problem

    NASA Technical Reports Server (NTRS)

    Okeefe, J. A.

    1978-01-01

    Small glassy pebbles, called tektites, are found in widely scattered locations around the world. These tektites appear much like volcanic glass obsidian, but their chemical composition is different from that of any terrestrial lava and they contain far less water and none of obsidian's characteristic microcrystals. No one has ever found the mother lode of a field of tektites. They cannot, therefore, be the product of terrestrial volcanism. Recently acquired knowledge about the moon's surface confirms earlier indications that tektites cannot be bits of lunar soil propelled to the earth by the impact of meteorites on the moon. According to one of two remaining possibilities tektites are bits of terrestrial sedimentary rock excavated by meteorites striking the earth's surface, melted by the heat of impact, and congealed into glass as they travel above the atmosphere to the scattered sites where they are found. The other possibility is that tektites are the remains of gobs of lava fired at the earth by volcanic activity on the moon.

  11. Fe-57 Moessbauer study of tektites

    NASA Technical Reports Server (NTRS)

    Evans, B. J.; Leung, L. K.

    1976-01-01

    Moessbauer measurements were made on selected moldavite, australite, philippinite, and Georgia tektites. The spectra consist of two apparent lines, but at least two quadrupole doublets can be fitted to these spectra. The Moessbauer parameters for these doublets indicate that they arise from Fe2+ ions with local environments, which are relatively rich and relatively poor in calcium, respectively, similar to those in clinopyroxenes. No evidence for Fe3+/Fe2+ ratios above 0.01 (estimated detection limit) have been found in any tektite. Tektites are considerably more reduced than previously believed, and the extent of the reduction shows little or no variation among different types of tektites. These results limit the source materials of tektites to minerals in which the iron is uniformly highly reduced and in which the iron is contained clinopyroxene-like phases.

  12. The Shapes of Splash-Form Tektites: Their Geometrical Analysis, Classification and Mechanics of Formation

    NASA Astrophysics Data System (ADS)

    Stauffer, Mel R.; Butler, Samuel L.

    2010-12-01

    Splash-form tektites are found with a wide range of sizes and in an intriguing array of shapes ranging from spheres to flat discs to dumbbells. Despite the considerable interest that exists in tektites, there has been relatively little effort to develop rational shape descriptors and to understand the origin of their shapes based on basic physics. Tektites represent a natural laboratory experiment that can be analyzed to better understand the physics of rotating fluid drops. In this paper, we propose a classification scheme based on the axial ratios of ellipsoids, and we analyze the frequency of tektite shapes using a database of over 1,000 measured tektites. We show that the shape distribution for tektites from Thailand and Vietnam are very similar and that the most common tektites are moderately deformed discs but there exist also a significant number of moderately deformed dumbbells, and we argue that this distribution comes about because fluid drops first deform as oblate forms and then undergo a non-axisymmetric instability to become prolate. We also find that the largest tektites are most likely to be weakly deformed oblate objects while the most strongly deformed and most highly prolate forms are considerably smaller. A numerical model for the evolution of an axisymmetric fluid drop, such as a tektite in its molten early stage, is presented which demonstrates that drops that deform relatively slowly over a longer period of time are likely to develop central thinning while those that deform more rapidly are more likely to retain the shape of an ellipsoid. For the numerical parameters used the characteristic time scale for deformation was less than 1 s.

  13. Field recovery of layered tektites in northeast Thailand

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Wasson, J.T.; Pitakpaivan, K.; Putthapiban, P.

    The authors recovered Australasian tektites in place throughout a 40 X 130 km region in northeast Thailand extending from the Laotian border westward to a line connecting Na Pho Klang in the northeast through Det Udom to Nam Yun in the south. With two exceptions, in sites near the western edge of this region, all fragments are layered (muong-Nong-type) tektites. It appears that large layered tektites are mainly found by rice farmers in fields that were forested until the recent past. The presence of layered tektites in this 40 X 130 km area implies that impact melt that fell inmore » these areas was hot enough to flow if it was deposited on a sloping surface. The absence of splash-form tektites from the region indicates that the layer was still molten when masses having shapes (teardrops, dumbbells, etc.) produced by spinning reached the ground. To account for this and to allow time for the melt to flow a few tens of centimeters requires that the atmosphere remained hot (>2300 K) for a few minutes. Tektites that are in place are almost always associated with a widespread 10-cm to meter-thick layer of laterite. In two cases (one involving layered, one involving splash-form tektites), where accurate stratigraphic control demonstrated that the tektites were still in section, they were sited on top of the laterite layer just below a layer of aeolian sand. 27 refs., 1 fig., 1 tab.« less

  14. A review of volatile compounds in tektites, and carbon content and isotopic composition of moldavite glass

    NASA Astrophysics Data System (ADS)

    Žák, Karel; SkáLA, Roman; Šanda, Zdeněk.; Mizera, Jiří.

    2012-06-01

    Tektites, natural silica-rich glasses produced during impact events, commonly contain bubbles. The paper reviews published data on pressure and composition of a gas phase contained in the tektite bubbles and data on other volatile compounds which can be released from tektites by either high-temperature melting or by crushing or milling under vacuum. Gas extraction from tektites using high-temperature melting generally produced higher gas yield and different gas composition than the low-temperature extraction using crushing or milling under vacuum. The high-temperature extraction obviously releases volatiles not only from the bubbles, but also volatile compounds contained directly in the glass. Moreover, the gas composition can be modified by reactions between the released gases and the glass melt. Published data indicate that besides CO2 and/or CO in the bubbles, another carbon reservoir is present directly in the tektite glass. To clarify the problem of carbon content and carbon isotopic composition of the tektite glass, three samples from the Central European tektite strewn field—moldavites—were analyzed. The samples contained only 35-41 ppm C with δ13C values in the range from -28.5 to -29.9‰ VPDB. This indicates that terrestrial organic matter was a dominant carbon source during moldavite formation.

  15. Vector diagram of the chemical compositions of tektites and earth lavas

    NASA Technical Reports Server (NTRS)

    Kvasha, L. G.; Gorshkov, G. S.

    1978-01-01

    The chemical compositions of tektites and various volcanic glasses, similar in composition to tektites are compared by a petrochemical method. The advantage of the method is that a large number of chemical analyses of igneous rocks can be graphically compared with the help of vectors, plotted in relation to six parameters. These parameters, calculated from ratios of the main oxides given by silicate analysis, reflect the chief characteristics of igneous rock. Material for the study was suppled by data from chemical analysis characterizing tektites of all known locations and data from chemical analyses of obsidians similar in chemical composition to tektites of various petrographical provinces.

  16. On the nature of the Ni-rich component in splash-form Australasian tektites

    NASA Astrophysics Data System (ADS)

    Goderis, Steven; Tagle, Roald; Fritz, Jörg; Bartoschewitz, Rainer; Artemieva, Natalia

    2017-11-01

    The Australasian tektite strewn field is exceptional, not only as the largest and most recent, but also as the only strewn field without an identified source impact crater. Therefore, scenarios without the formation of an impact crater, such as a low altitude cometary airburst, have proven hard to discard. Here, new geochemical evidence is presented for mixing of projectile and target material, which implies the formation of an Australasian tektite-related impact crater. First, ninety-two Australasian tektites were grouped according to their Cr, Co and Ni concentrations. Based on this data, Australasian tektites with the highest Ni contents (>200 μg/g) occur more than 1500 km south-southeast (SSE) of the northern Indochina region, with the highest concentration of Ni-rich tektites in South Vietnam, the islands of Borneo, Belitung, and Java, and reports in literature for Ni-rich tektites in central Australia. The tektites with the highest Cr and Ni abundances often also show highly siderophile element (HSE) enrichments of up to 4 ng/g Ir. The most Ni-rich samples exhibit broadly chondrite-relative HSE proportions. However, a chondritic impactor contribution appears to be inconsistent with the observed Ni/Cr, Ni/Co, and Cr/Co ratios. A previously suggested significant terrestrial mantle contribution can also not explain the siderophile element enrichments in combination with relatively low FeOtot (<7 wt.%) and MgO (<4 wt.%) contents. Elemental fractionation during impact cratering or tektite formation by an impactor with a chondritic signature may explain these observations. Alternatively, a projectile component from a primitive achondrite may be advocated, with contribution from a mafic to ultramafic extraterrestrial lithology with a relatively unfractionated HSE signature and Ni/Cr ratio distinctly higher than those of Earth's mantle. Element distribution maps obtained from individual Australasian tektites document complex mingling processes of chemically distinct melt batches, each exhibiting variable contributions from distinct endmember compositions. These texturally recorded mingling processes are consistent with high-resolution numerical models of impact cratering processes that resolve the growth of Kelvin-Helmholtz instabilities at the projectile/target interface during impact, when both materials co-occur at high pressure. These numerical models indicate that Ni-rich tektite populations across the central part of the Australasian tektite strewn field could represent projectile-enriched material preferentially ejected downrange. Continued tracing of this Ni-rich component across the strewn field may help to constrain the location of the yet to be identified source crater of the Australasian (micro)tektites.

  17. Aerodynamic Evidence Pertaining to the Entry of Tektites into the Earth's Atmosphere

    NASA Technical Reports Server (NTRS)

    Chapman, Dean R.; Larson, Howard K.; Anderson, Lewis A.

    1962-01-01

    Evidence is presented which shows that the Australian and Java tektites entered the earth's atmosphere and experienced ablation by severe aerodynamic heating in hypervelocity flight. The laboratory experiments on hypervelocity ablation have reproduced ring-wave flow ridges and coiled circumferential flanges like those found on certain of these tektites. Systematic striae distortions exhibited in a thin layer beneath the front surface of australites also are reproduced in the laboratory ablation experiments, and are shown to correspond to the calculated distortions for aerodynamic ablation of a glass. About 98 percent of Australian tektites represent aerodynamically stable configurations during the ablative portion of an entry trajectory. Certain meteorites exhibit surface features similar to those on tektites.

  18. Geographic Size Variation and Intra-Tektite Geochemical Heterogeneity of Muong Nong Tektites: Insights for Cratering Process and Fall Location.

    NASA Astrophysics Data System (ADS)

    Schonwalder, D. A.; Sieh, K.; Herrin, J. S.; Wiwegwin, W.; Charusiri, P.; Singsomboun, K.; Sihavong, V.

    2017-12-01

    Australasian tektites cover 10% of Earth's surface and are the result of a 790 ka meteorite impact [1]. We have suggested that the search of the impact crater has long been mysterious because it lies buried beneath the volcanic field of the Bolaven Plateau (BP), southern Laos. [2]. Here we report our initial textural and geochemical work on 700 Muong Nong (MN) tektites collected in Laos and Thailand, including physical inspections and geochemical point-analyses of selected samples using a Field Emission Electron Probe Microanalyzer. We integrated our results with published data to identify any geographic patterns related to proposed crater site on the BP. Mung Nong tektite masses display a clear pattern in relation to BP. Within 50 km of the BP source, they do not exceed 10 gr. Mass then increases with radius to peak of 1 to 10 kg between 100 and 600 km, beyond which mass decreases steadily. We also see large geochemical heterogeneities within single tektites (e.g. 72.80±4.38 wt. % SiO2), and intra-sample compositions consisting with mixing of three principal source rocks on the BP, basalt-sourced laterites, basalt and sandstone. We infer that the geographical pattern in mass distribution of the MN tektites result from fragmentation of brittle, partially molten material during crater excavation and by debris interactions occurring in the ejecta blanket. The smaller and closest-to-crater tektites experienced greater interactions with crater walls and other ejecta during crater excavation, whereas the larger tektites that fell farther from the impact site, experienced lesser fragmentation because they had higher ejection trajectories that had less involvement in crater excavation. Intra-tektite compositional trends suggest the involvement of three protoliths, all of them found at the BP. 1. Schwarz et al. (2016) Geochem. Cosmo. Acta 178 2. Sieh et al. (2015) AGU Fall Mtg. T54A-04

  19. Age of the Australasian Tektite Strewn Field

    NASA Astrophysics Data System (ADS)

    Izokh, E. P.

    1993-07-01

    As Fig. 1 shows, the widespread belief that the age of the Australasian tektite strewn field (AATSF) is ~0.7 m.y. appeared to be conventional. Tektites of different fission-track ages were found within the AATSF: 0.83 m.y. [1], 3.54-4.25 m.y. [2], and ~11 m.y. [3]. The first systematic investigation of the tektites, which were collected from a single stratigraphic layer in Vietnam, revealed three statistically discrete tektite age groups: 0.4, 0.6, and 0.8 m.y. [4]. Similar tektites 0.75 m.y. and 1.1 m.y. in age are typical of the Zhamanshin impact crater, which represents an eminent part of the AATSF [5]. Fig. 1, which appears here in the hard copy, shows radiogenic dating: 1-2: AATSF; 3-4: Zhamanshin; 1,3: data with known annealing correction. Compiled after Zahringer, 1963; Fleischer and Price, 1964; Gentner et al., 1969; McDougal and Lovering, 1969; Fleischer et al., 1969; Storzer and Wagner, 1979, 1980; Watanabe et al., 1985; Virk, 1985; Shukolukov et al., 1986; Kashkarov et al, 1986, 1987; Kolesnikov et al., 1987; Storzer and Muller-Sonhius, 1986; Arakelyants et al., 1988; etc. The very young geological age of the AATSF was established in Australia, and was confirmed by the author in Vietnam and in the Zhamanshin impact crater. This well-known tektite age paradox strongly supports an extraterrestrial origin of tektites. The paradox is fatal to the currently dominating Earth- impact theory of tektite origin, and we are not surprised that there are no continued attempts to either silence or disavow its significance. As a matter of fact, the formation of the gigantic AATSF can be considered as the main reason for the abrupt catastrophic climatic global changes and mass extinction of species on the Pleistocene/Holocene boundary 10,000 years ago [5,6]. The age-paradox scope dictates that tektites have been periodically formed and accumulated somewhere on an as-yet-unknown planetary body and then delivered to the Earth. The extraterrestrial volcanic eruptions seem to be the most appropriate process of the tektite formation and launching [7]. The frequent shift of the K-Ar ages relative to the fission-track ages of tektites can be explained by the presence of an extra argon inherited from some older crystalline inclusions foreign to the tektite glass. These inclusions are most common to the Muong Nong-type layered tektites and to flanges of the button-shape australites, and can be considered as an extraterrestrial environmental dust peppering. References: [1] Storzer and Wagner (1980) Meteoritics, 15, 372. [2] Fleischer et al. (1969) EPSL, 7, 51-52. [3] Storzer and Muller-Sonhius (1986) Meteoritics, 21, 518-519. [4] Kashkarov et al. (1986) Meteoritika, 45, 105-170. [5] Izokh (1991) Soviet Geol. and Geophys., 32, 1-10. [6] Tollman and Tollmann (1992) Mitt. Osterr. Geol. Ges., 84. [7] Izokh and Le duc An (1983) Meteoritika, 42, 158-169.

  20. Diminished tektite ablation in the wake of a swarm

    NASA Technical Reports Server (NTRS)

    Sepri, P.; Chen, K. K.; Okeefe, J. A.

    1981-01-01

    Observations of ablation markings on tektite surfaces reveal that a large variation in aerodynamic heating must have occurred among the members of a swarm during atmospheric entry. In a few cases, the existence of jagged features indicates that these tektite surfaces may have barely reached the melting temperature. Such an observation seems to be incompatible with the necessarily large heating rates suffered by other tektites which exhibit the ring wave melt flow. A reconciliation is proposed in the form of a wake shielding model which is a natural consequence of swarm entry. Calculations indicate that the observed ablation variations are actually possible for swarm entry at greater than escape velocity. This aerodynamic conclusion provides support for the arguments favoring extraterrestrial origin of tektites.

  1. Zhamanshin and Aouelloul - Craters produced by impact of tektite-like glasses?

    NASA Technical Reports Server (NTRS)

    O'Keefe, John A.

    1987-01-01

    It is shown that the enhanced abundance of siderophile elements and chromium in tektite-like glasses from the two impact craters of Zhamanshin and Aouelloul cannot be explained as a result of contamination of the country rock by meteorites nor, probably, comets. The pattern is, however, like that found in certain Australasian tektites, and in Ivory Coast tektites. It is concluded, in agreement with earlier suggestions by Campbell-Smith and Hey, that these craters were formed by the impact of large masses of tektite-like glass, of which the glasses which were studied are fragments. It follows that it is necessary, in considering an impact crater, to bear in mind that the projectile may have been a glass.

  2. Zhamanshin and Aouelloul - Craters produced by impact of tektite-like glasses?

    NASA Astrophysics Data System (ADS)

    O'Keefe, John A.

    1987-09-01

    It is shown that the enhanced abundance of siderophile elements and chromium in tektite-like glasses from the two impact craters of Zhamanshin and Aouelloul cannot be explained as a result of contamination of the country rock by meteorites nor, probably, comets. The pattern is, however, like that found in certain Australasian tektites, and in Ivory Coast tektites. It is concluded, in agreement with earlier suggestions by Campbell-Smith and Hey, that these craters were formed by the impact of large masses of tektite-like glass, of which the glasses which were studied are fragments. It follows that it is necessary, in considering an impact crater, to bear in mind that the projectile may have been a glass.

  3. Tektite-like bodies at Lonar Crater, India - Implications for the origin of tektites

    NASA Technical Reports Server (NTRS)

    Murali, A. V.; Zolensky, M. E.; Blanchard, D. P.

    1987-01-01

    Homogeneous dense glass bodies (both irregular and splash form) with high silica contents (about 67 pct SiO2) occur in the vicinity of Lonar Crater, India. Their lack of microlites and mineral remnants and their uniform chemical composition virtually preclude a volcanic origin. They are similar to tektites reported in the literature. While such a close association of tektite-like bodies with impact craters is already known (Aouelloul Crater, Mauritania; Zhamanshin Crater, U.S.S.R.), the tektite-like bodies at Lonar Crater are unique in that they occur in an essentially basaltic terrain. Present geochemical data are consistent with these high silica glass bodies being impact melt products of two-thirds basalt and one-third local intertrappean sediment (chert). The tektite-like bodies of the impact craters Lonar, Zhamanshin, and Aouelloul are generally similar. Strong terrestrial geochemical signatures reflect the target rock REE patterns and abundance ratios and demonstrate their terrestrial origin resulting from meteorite impact, as has been suggested by earlier workers.

  4. Late Eocene rings around the earth

    NASA Technical Reports Server (NTRS)

    King, E. A.

    1980-01-01

    The suggestion of O'Keefe (1980) that the terminal Eocene event was caused by rings of tektite material encircling the earth is discussed. It is argued that the assumption that the tektites are of lunar volcanic origin is unwarranted and contrary to existing data, including the lack of lunar rocks of suitable composition, the lack of lunar rocks of the correct age, the lack of evidence that the North American tektites fell throughout a sedimentary rock column of a few million years, and the nondetection of a tektite with a measurable cosmic ray exposure age. Alternatively, it is suggested that the terminal Eocene event may be associated with volcanic ash, air-fall tuff and bentonite in the late Eocene. O'Keefe replies that the hypothesis of the terrestrial origin of the tektites conflicts with the laws of physics, for example in the glass structure and shaping of the tektites. Furthermore, evidence is cited for lunar rocks of the proper major-element composition and ages, and it is noted that the proposed solar Poynting-Robertson effect would account for the particle fall distributions and cosmic ray ages.

  5. The water, deuterium, gas and uranium content of tektites

    USGS Publications Warehouse

    Friedman, I.

    1958-01-01

    The water content, deuterium concentration of the water, total gas and uranium contents were determined on tektite samples and other glass samples from Texas, Australia, Philippine Islands, Java, French Indo-China, Czechoslovakia, Libyan Desert, Billiton Island, Thailand, French West Africa, Peru, and New Mexico. The water content ranges from 0.24 per cent for the Peru tektite, to 0.0002 per cent for a moldavite. The majority of the tektites have less than 0.05 per cent water, and average 0.005 per cent H2O by weight. No other gases were detected, the lower detection limit being about 1 p.p.m. by weight. The deuterium content of the water in tektites is in the same range as that in terrestrial waters, and varies from 0.010 mole per cent to 0.0166 mole per cent deuterium. The uranium content is about from 1 to 3 p.p.m. The possible origin of tektites is discussed. The experimental data presented favour their being originally terrestrial, but produced by some catastrophic event. An extra-terrestrial source is not ruled out. ?? 1958.

  6. Magnetic susceptibility of tektites and some other glasses

    USGS Publications Warehouse

    Senftle, F.E.; Thorpe, A.

    1959-01-01

    The magnetic susceptibility at several magnetic field strengths of about thirty tektites from various localities have been measured. The susceptibility ranges from 2 ?? 10-6 to about 7.9 ?? 10-6 e.m.u./g. Tektites from a given locality have similar susceptibilities. The intensity of magnetization of all the tektites measured is zero or very small. For comparison, the same measurements have been made on about thirty obsidians. The magnetic susceptibilities cover approximately the same range, but the intensity of magnetization of the impurity was found to be much higher. By heating the obsidians to 1450??C the intensity of magnetization was reduced to zero. From the above data, it is shown that the tektites must have been heated well above 1400??C, and that essentially all the iron is in solution. On the other hand, the evidence shows that obsidians have not been heated much above this temperature, and that there is a significant amount of undissolved iron in the glass, probably as magnetite. Further, if tektites are extraterrestrial, they probably entered the earth's atmosphere as a glass. ?? 1959.

  7. Study of the ablative effects on tektites. [wake shielding during atmospheric entry

    NASA Technical Reports Server (NTRS)

    Sepri, P.; Chen, K. K.

    1976-01-01

    Equations are presented which provide approximate parameters describing surface heating and tektite deceleration during atmosphere passage. Numerical estimates of these parameters using typical initial and ambient conditions support the conclusion that the commonly assumed trajectories would not have produced some of the observed surface markings. It is suggested that tektites did not enter the atmosphere singly but rather in a swarm dense enough to afford wake shielding according to a shock envelope model which is proposed. A further aerodynamic mechanism is described which is compatible with hemispherical pits occurring on tektite surfaces.

  8. The behavior of osmium and other siderophile elements during impacts: Insights from the Ries impact structure and central European tektites

    NASA Astrophysics Data System (ADS)

    Ackerman, Lukáš; Magna, Tomáš; Žák, Karel; Skála, Roman; Jonášová, Šárka; Mizera, Jiří; Řanda, Zdeněk

    2017-08-01

    Impact processes are natural phenomena that contribute to a variety of physico-chemical mechanisms over an extreme range of shock pressures and temperatures, otherwise seldomly achieved in the Earth's crust through other processes. Under these extreme conditions with transient temperatures and pressures ≥3000 K and ≥100 GPa, followed by their rapid decrease, the behavior of elements has remained poorly understood. Distal glassy ejecta (tektites) were produced in early phases of contact between the Earth's surface and an impacting body. Here we provide evidence for a complex behavior of Os and other highly siderophile elements (HSE; Ir, Ru, Pt, Pd, and Re) during tektite production related to a hyper-velocity impact that formed the Ries structure in Germany. Instead of simple mixing between the surface materials, which are thought to form the major source of central European tektites (moldavites), and impactor matter, the patterns of HSE contents and 187Re/188Os - 187Os/188Os ratios in moldavites, target sediments and impact-related breccias (suevites) can be explained by several sequential and/or contemporary processes. These involve (i) evaporative loss of partially oxidized HSE from the overheated tektite melt, (ii) mixing of target-derived and impactor-derived HSE vapor (plasma) phases, and (iii) early (high-temperature) condensation of a part of the mixed vapor phase back to silicate melt droplets. An almost complete loss of terrestrial Os from the tektite melt and its replacement with extra-terrestrial Os are indicated by low 187Os/188Os ratios in tektites (<0.163) relative to precursor materials (>0.69). This is paralleled by a co-variation between Os and Ni contents in tektites but not in suevites formed later in the impact process.

  9. Search for the 700,000-year-old source crater of the Australasian tektite strewn field

    NASA Technical Reports Server (NTRS)

    Schnetzler, C. C.; Garvin, J. B.

    1992-01-01

    Many tektite investigations have hypothesized that the impact crater that was the source of the extensive Australasian strewn field lies somewhere in or near Indochina. This is due to variations in abundance and size of tektites across the strewn field, variation of thickness of microtektite layers in ocean cores, nature and ablation characteristics across the field, and, above all, the occurrence of the large, blocky, layered Muong Nong-type tektites in Indochina. A recent study of the location and chemistry of Muong Nong-type and splash-form tektites suggests that the source region can be further narrowed to a limited area in eastern Thailand and southern Loas. Satellite multispectral imagery, a digital elevation dataset, and maps showing drainage patterns were used to search within this area for possible anomalous features that may be large degraded impact craters. Four interesting structures were identified from these datasets, and they are presented.

  10. Lithium in tektites and impact glasses: Implications for sources, histories and large impacts

    NASA Astrophysics Data System (ADS)

    Magna, T.; Deutsch, A.; Mezger, K.; Skála, R.; Seitz, H.-M.; Mizera, J.; Řanda, Z.; Adolph, L.

    2011-04-01

    Lithium (Li) abundances and isotope compositions were determined in a representative suite of tektites (moldavites, Muong Nong-type tektites and an australite, Ivory Coast tektites and bediasites), impact-related glasses (Libyan Desert Glass, zhamanshinites and irghizites), a glass fragment embedded in the suevite from the Ries impact crater and sedimentary materials in order to test a possible susceptibility of Li to fractionation during hypervelocity impact events and to de-convolve links to their potential parental sources. The overall data show a large spread in Li abundance (4.7-58 ppm Li) and δ 7Li values (-3.2‰ to 26.0‰) but individual groups of tektites and impact glasses have distinctive Li compositions. Most importantly, any significant high-temperature Li isotope fractionation can be excluded by comparing sedimentary lithologies from central Europe with moldavites. Instead, we suggest that Li isotope compositions in tektites and impact-related glasses are probably diagnostic of the precursor materials and their pre-impact geological histories. The Muong Nong-type tektites and australite specimen are identical in terms of Li concentrations and δ 7Li and we tentatively endorse their common origin in a single impact event. Evidence for low-temperature Rayleigh fractionation, which must have operated prior to impact-induced melting and solidification, is provided for a subset of Muong Nong-type tektites. Although Li isotope variations in most tektites are broadly similar to those of the upper continental crust, Libyan Desert Glass carries high δ 7Li ⩾24.7‰, which appears to mirror the previous fluvial history of parental material that was perhaps deposited in lacustrine environment or coastal seawater. Lithium isotopes in impact-related glasses from the Zhamanshin crater define a group distinct from all other samples and point to melting of chemically less evolved mafic lithologies, which is also consistent with their major and trace element patterns. Extreme shock pressures and the related extreme post-shock temperatures alone appear not to have any effect on the Li isotope systematics; therefore, useful information on parental lithologies and magmatic processes may be retrieved from analyses of Martian and lunar meteorites. Moreover, lack of significant Li depletion in tektites provides further constraints on the loss of moderately volatile elements during the Moon-forming impact.

  11. An Ordinary Chondrite Impactor Composition for the Bosumtwi Impact Structure, Ghana, West Africa: Discussion of Siderophile Element Contents and Os and Cr Isotope Data

    NASA Technical Reports Server (NTRS)

    Koeberl, Christian; Shukolyukov, Alex; Lugmair, Guenter

    2004-01-01

    Osmium isotope data had shown that Ivory Coast tektites contain an extraterrestrial component, but do not allow distinction between chondritic and iron meteorite contamination. PGE abundances of Ivory Coast tektites and impactites and target rocks from the Bosumtwi crater, the source crater of the Ivory Coast tektites, were all relatively high and did not allow to resolve the presence, or identify the nature, of the meteoritic component. However, Cr isotope analyses of an Ivory Coast tektite yielded a distinct 53Cr excess of 0.30+/-0.06, which indicates that the Bosumtwi impactor was an ordinary chondrite.

  12. Nickel-iron spherules in tektites - Non-meteoritic in origin

    NASA Technical Reports Server (NTRS)

    Ganapathy, R.; Larimer, J. W.

    1983-01-01

    The concentrations of several diagnostic trace elements were determined in two comparatively large NiFe spherules extracted from tektites. The purpose of the study was to obtain some clues about the chemistry of the projectile that is presumed responsible for the formation of these tektites. However, the trace element pattern is distinctly terrestrial implying that the spherules are the result of in-situ reduction of the host rock and are not meteoritic in origin.

  13. Osmium isotopes in Ivory Coast tektites: Confirmation of a meteoritic component and rhenium depletion

    NASA Technical Reports Server (NTRS)

    Koeberl, Christian; Shirey, Steven B.

    1993-01-01

    The sensitive negative thermal ionization mass spectrometry method was used for the measurement of concentrations and isotopic ratios of osmium and rhenium in four Ivory Coast tektites. These tektites have crustal major and trace element composition, as well as large negative epsilon(sub Nd)(-20) and positive epsilon(sub Sr)(+260 to +300) which are characteristic for old continental crust. Os concentrations ranging from 0.09 to 0.30 ppb were found, clearly much higher than average crustal values, Os-187/Os-186 ratios of about 1.2-1.7, and low Re-187/Os-186 ratios. These results show unambiguously the existence of a meteoritic component (on the order of 0.06%) in the Ivory Coast tektites. Low Re abundances are the result of fractionation of Re during the impact.

  14. Evaporation Induced Oxygen Isotope Fractionation in Impact Ejecta

    NASA Astrophysics Data System (ADS)

    Macris, C. A.; Young, E. D.; Kohl, I. E.; zur Loye, T. E.

    2017-12-01

    Tektites are natural glasses formed as quenched impact melt ejecta. Because they experienced extreme heating while entrained in a hot impact vapor plume, tektites allow insight into the nature of these ephemeral events, which play a critical role in planetary accretion and evolution. During tektite formation, the chemical and isotopic composition of parent materials may be modified by (1) vapor/liquid fractionation at high T in the plume, (2) incorporation of meteoric water at the target site, (3) isotope exchange with atmospheric oxygen (if present), or some combination of the three. Trends from O isotope studies reveal a dichotomy: some tektite δ18O values are 4.0-4.5‰ lower than their protoliths (Luft et al. 1987; Taylor & Epstein 1962), opposite in direction to a vaporization induced fractionation; increases in δ18O with decreasing SiO2 in tektites (Taylor & Epstein 1969) is consistent with vapor fractionation. Using an aerodynamic levitation laser furnace (e.g. Macris et al. 2016), we can experimentally determine the contributions of processes (1), (2) and (3) above to tektite compositions. We conducted a series of evaporation experiments to test process (1) using powdered tektite fused into 2 mm spheres and heated to 2423-2473 K for 50-90 s while levitated in Ar in the furnace. Mass losses were from 23 to 26%, reflecting evaporation of Si and O from the melt. The starting tektite had a δ18O value of 10.06‰ (±0.01 2se) and the residues ranged from 13.136‰ (±0.006) for the least evaporated residue to 14.30‰ (±0.02) for the most evaporated (measured by laser fluorination). The increase in δ18O with increasing mass loss is consistent with Rayleigh fractionation during evaporation, supporting the idea that O isotopes are fractionated due to vaporization at high T in an impact plume. Because atmospheric O2 and water each have distinctive Δ17O values, we should be able to use departures from our measured three-isotope fractionation law to evaluate the relative contributions of these sources. Future experiments will investigate the contribution of meteoric water in starting material (2) and exchange with an O2 rich atmosphere (3) to the O isotope values of tektites. Luft et al., Geochim Cosmochim Acta 51 (1987) Macris et al., AGU Fall Meet Abstr (2016) Taylor & Epstein, J Geophys Res 67 (1962) Taylor & Epstein, J Geophys Res 74 (1969)

  15. Development of near-zero water consumption cement materials via the geopolymerization of tektites and its implication for lunar construction

    PubMed Central

    Wang, Kai-tuo; Tang, Qing; Cui, Xue-min; He, Yan; Liu, Le-ping

    2016-01-01

    The environment on the lunar surface poses some difficult challenges to building long-term lunar bases; therefore, scientists and engineers have proposed the creation of habitats using lunar building materials. These materials must meet the following conditions: be resistant to severe lunar temperature cycles, be stable in a vacuum environment, have minimal water requirements, and be sourced from local Moon materials. Therefore, the preparation of lunar building materials that use lunar resources is preferred. Here, we present a potential lunar cement material that was fabricated using tektite powder and a sodium hydroxide activator and is based on geopolymer technology. Geopolymer materials have the following properties: approximately zero water consumption, resistance to high- and low-temperature cycling, vacuum stability and good mechanical properties. Although the tektite powder is not equivalent to lunar soil, we speculate that the alkali activated activity of lunar soil will be higher than that of tektite because of its low Si/Al composition ratio. This assumption is based on the tektite geopolymerization research and associated references. In summary, this study provides a feasible approach for developing lunar cement materials using a possible water recycling system based on geopolymer technology. PMID:27406467

  16. Development of near-zero water consumption cement materials via the geopolymerization of tektites and its implication for lunar construction.

    PubMed

    Wang, Kai-Tuo; Tang, Qing; Cui, Xue-Min; He, Yan; Liu, Le-Ping

    2016-07-13

    The environment on the lunar surface poses some difficult challenges to building long-term lunar bases; therefore, scientists and engineers have proposed the creation of habitats using lunar building materials. These materials must meet the following conditions: be resistant to severe lunar temperature cycles, be stable in a vacuum environment, have minimal water requirements, and be sourced from local Moon materials. Therefore, the preparation of lunar building materials that use lunar resources is preferred. Here, we present a potential lunar cement material that was fabricated using tektite powder and a sodium hydroxide activator and is based on geopolymer technology. Geopolymer materials have the following properties: approximately zero water consumption, resistance to high- and low-temperature cycling, vacuum stability and good mechanical properties. Although the tektite powder is not equivalent to lunar soil, we speculate that the alkali activated activity of lunar soil will be higher than that of tektite because of its low Si/Al composition ratio. This assumption is based on the tektite geopolymerization research and associated references. In summary, this study provides a feasible approach for developing lunar cement materials using a possible water recycling system based on geopolymer technology.

  17. Artificial tektites: an experimental technique for capturing the shapes of spinning drops

    NASA Astrophysics Data System (ADS)

    Baldwin, Kyle A.; Butler, Samuel L.; Hill, Richard J. A.

    2015-01-01

    Determining the shapes of a rotating liquid droplet bound by surface tension is an archetypal problem in the study of the equilibrium shapes of a spinning and charged droplet, a problem that unites models of the stability of the atomic nucleus with the shapes of astronomical-scale, gravitationally-bound masses. The shapes of highly deformed droplets and their stability must be calculated numerically. Although the accuracy of such models has increased with the use of progressively more sophisticated computational techniques and increases in computing power, direct experimental verification is still lacking. Here we present an experimental technique for making wax models of these shapes using diamagnetic levitation. The wax models resemble splash-form tektites, glassy stones formed from molten rock ejected from asteroid impacts. Many tektites have elongated or `dumb-bell' shapes due to their rotation mid-flight before solidification, just as we observe here. Measurements of the dimensions of our wax `artificial tektites' show good agreement with equilibrium shapes calculated by our numerical model, and with previous models. These wax models provide the first direct experimental validation for numerical models of the equilibrium shapes of spinning droplets, of importance to fundamental physics and also to studies of tektite formation.

  18. Tektite ablation - Some confirming calculations.

    NASA Technical Reports Server (NTRS)

    O'Keefe, J. A., III; Silver, A. D.; Cameron, W. S.; Adams , E. W.; Warmbrod, J. D.

    1973-01-01

    The calculation of tektite ablation has been redone, taking into account transient effects, internal radiation, melting and nonequilibrium vaporization of the glass, and the drag effect of the flanges. It is found that the results confirm the earlier calculations of Chapman and his group and of Adams and his co-workers. The general trend of the results is not sensitive to reasonable changes of the physical parameters. The ablation is predominantly by melting rather than by vaporization at all velocities up to 11 km/sec; this is surprising in view of the lack of detectable melt flow in most tektites. Chemical effects have not been considered.

  19. Tektites: Origin as melts produced by the impact of small projectiles onto dry targets

    NASA Technical Reports Server (NTRS)

    Wasson, John T.

    1988-01-01

    The formation of tektites in general and layered tektites in particular seems to require a very special kind of cratering event. Evidence for the formation of pools of melt free of unmelted clasts has not been reported for the well-studied terrestrial craters such as Manicouagan or Ries. It is suggested that large amounts of relict-free melt were produced only when a sizeable fraction of the cratered target consisted of dry, high-porosity materials such as aeolian sediments. Since dry, high-porosity target materials are always confined to the outer 100 to 200 m of the Earth, the fraction of melt produced melt is probably higher in small (radius 50 to 500 m) craters than in large (r greater than 1 km) craters. Another reason to infer that the Southeast Asian tektites were produced in a multitude of small craters is the wide distribution of layered tektites. The file spans at least 1200 km, which would require ballistic ejection at velocities greater than 2 km s(-1) if all melt was generated in a single crater. It seems impossible to devise a scenario that would lead to the deposition of primary melt as a crystal-free pool at a distance of 600 km from the crater.

  20. Ti K-edge EXAFS and XANES study on tektites from different strewnfields

    NASA Astrophysics Data System (ADS)

    Wang, L.; Furuta, T.; Okube, M.; Yoshiasa, A.

    2011-12-01

    The concentration and local structure of each element may have various kinds of information about the asteroid impact and mass extinction. Farges and Brown have discussed about the Ti local structure by XANES, and concluded that Ti in tektite occupies 4-coordinated site. EXAFS can be analyzed to give precise information about the distance from Ti to near neighbors. The XAFS measurement of Ti local structure was preformed at the beamline 9C of the Photon Factory in KEK, Tsukuba, Japan. The specimens of tektites are from different strewnfields, they are: indochinite, bediasite, hainanite, philippinite, australite and moldavite. Sample for comparison are Libya desert glass and suevite. The k3χ(k) function was transformed into the radial structure function (RSF) for Ti K-edge of six tektites. The RSF for the Ti atom in indochinite and bediasite are similar; hainanite, australite and philippinite are similar; and moldavite is discriminated from others. It indicates that they have the same local atomic environmental around the Ti atoms and extended structure respectively. Coordination numbers and radial structure function are determined by EXAFS analyses (Table 1). We classified the tektites in three types: in indochinite and bediasite, Ti occupies 4-coordinated tetrahedral site and Ti-O distances are 1.84-1.81 Å; in hainanite, australite and philippinite, Ti occupies 5-coordinated trigonal bi-pyramidal or tetragonal pyramidal site and Ti-O distances are 1.92-1.87 Å; in moldavite, Ti occupies the 6-coordinated octahedral site and Ti-O distance is 2.00-1.96 Å. Formation of tektites is related to the impact process. It is generally recognized that tektites were formed under higher temperature and high pressure. But through this study, local structures of Ti are differing in three strewnfields and even different locations of the same strewnfield. What caused the various local structures will be another topic of tektite studies. Local structure of Ti may be changed in the impact event and the following stage. Tektites splashed to the space and travel in several kinds of processes and routes, which lead to different temperature and pressure history. Local structure of Ti should be related with the temperature, pressure, quenching rate, sizes of impact meteorite and size of falling melts. [1] Koeberl. Ann.Rev.Earth Planet.Sci. 14, 323-350 (1986) [2] François Farges & Gordon E. Brown Jr Geochim. Cosmo. Acta.61, 1863-1870 (1997). [3]Paris, E., Dingwell, D., Seifert, F., Mottana, A. & Romano, C. (1994). Phys. Chem. Miner. 21, 520-525.
    Table 1 Structure parameters determined by EXAFS

  1. Artificial tektites: an experimental technique for capturing the shapes of spinning drops

    NASA Astrophysics Data System (ADS)

    Baldwin, K. A.

    2014-12-01

    Tektites are small stones formed from rapidly cooling drops of molten rock ejected from high velocity asteroid impacts with the Earth, that freeze into a myriad of shapes during flight. Many splash-form tektites have an elongated or dumb-bell shape owing to their rotation prior to solidification[1]. Here we present a novel method for creating 'artificial tektites' from spinning drops of molten wax, using diamagnetic levitation to suspend the drops[2]. We find that the solid wax models produced this way are the stable equilibrium shapes of a spinning liquid droplet held together by surface tension. In addition to the geophysical interest in tektite formation, the stable equilibrium shapes of liquid drops have implications for many physical phenomena, covering a wide range of length scales, from nuclear physics (e.g. in studies of rapidly rotating atomic nuclei), to astrophysics (e.g. in studies of the shapes of astronomical bodies such as asteroids, rapidly rotating stars and event horizons of rotating black holes). For liquid drops bound by surface tension, analytical and numerical methods predict a series of stable equilibrium shapes with increasing angular momentum. Slowly spinning drops have an oblate-like shape. With increasing angular momentum these shapes become secularly unstable to a series of triaxial pseudo-ellipsoids that then evolve into a family of two-lobed 'dumb-bell' shapes as the angular momentum is increased still further. Our experimental method allows accurate measurements of the drops to be taken, which are useful to validate numerical models. This method has provided a means for observing tektite formation, and has additionally confirmed experimentally the stable equilibrium shapes of liquid drops, distinct from the equivalent shapes of rotating astronomical bodies. Potentially, this technique could be applied to observe the non-equilibrium dynamic processes that are also important in real tektite formation, involving, e.g. viscoelastic effects, non-uniform solidification, surface wrinkling (Schlieren), and rapid separation/fission of dumb-bells via the Rayleigh-Plateau instability. [1] M. R. Stauffer and S. L. Butler, Earth Moon Planets, 107, 169 (2009). [2] R. J. A. Hill and L. Eaves, Phys. Rev. Lett. 101, 234501 (2008).

  2. Fragmentation and hydration of tektites and microtektites

    USGS Publications Warehouse

    Glass, B.P.; Muenow, D.W.; Bohor, B.F.; Meeker, G.P.

    1997-01-01

    An examination of data collected over the last 30 years indicates that the percent of glass fragments vs. whole splash forms in the Cenozoic microtektite strewn fields increases towards the source crater (or source region). We propose that this is due to thermal stress produced when tektites and larger microtektites fall into water near the source crater while still relatively hot (>1150 ??C). We also find evidence (low major oxide totals, frothing when melted) for hydration of most of the North American tektite fragments and microtektites found in marine sediments. High-temperature mass spectrometry indicates that these tektite fragments and microtektites contain up to 3.8 wt% H2O. The H2O-release behavior during the high-temperature mass-spectrometric analysis, plus high Cl abundances (???0.05 wt%), indicate that the North. American tektite fragments and microtektites were hydrated in the marine environment (i.e., the H2O was not trapped solely on quenching from a melt). The younger Ivory Coast and Australasian microtektites do not exhibit much evidence of hydration (at least not in excess of 0.5 wt% H2O); this suggests that the degree of hydration increases with age. In addition, we find that some glass spherules (with 65 wt% SiO2 can undergo simple hydration in the marine environment, while impact glasses (with <65 wt% SiO2) can also undergo palagonitization.

  3. Metallic spherules in tektites from Isabela, Philippine Islands

    USGS Publications Warehouse

    Chao, E.C.T.; Adler, I.; Dwornik, E.J.; Littler, J.

    1962-01-01

    Iron-nickel spherules, as much as 0.5 mm in diameter, have been found completely embedded in some philippinites. The spherules consist mainly of kamacite with unidentified pink inclusions. The meteoritic origin of these spherules seems reasonable, suggesting that the tektites containing them were formed by asteroidal or meteoritic impact.

  4. Tektites and climate

    NASA Astrophysics Data System (ADS)

    Wasson, J. T.; Heins, W. A.

    1993-02-01

    Only four tektite fields have been produced during the past 40 m.y., even though at least 60 impact craters have been produced during the same period in continental lithologies having tektite-like compositions. The apparent reason for this discrepancy is that the ejecta from most crater-forming impacts was not completely melted. The key factor affecting melt production seems to be the nature of the target, particularly its porosity. The fraction of projectile kinetic energy converted to heat may be an order of magnitude higher in a highly porous target than in a void-free target. The grain size and water content of the target are also important. The ideal target is a porous, fine-grained sediment such as loess, particularly if it is also dry. It is suggested that the rate of impact production of fully molten crater ejecta is proportional to the fraction of the continental surface having thick (greater than 10 m) blankets of dry loess and that tektites are mainly produced during cold, dry periods when such deposits are an order of magnitude more common than at present.

  5. Preliminary discussion on the origin of Lei-gong-mo (tektites)

    NASA Technical Reports Server (NTRS)

    Baoyin, Y.

    1983-01-01

    The specimens of lei-gong-mo (tektites) were collected from Hainan Island and Leizhow Peninsula during the period from 1963 to 1975. The distribution, forms, sculpture, abration surface (bald spot), internal structure and chemical composition of lei-gong-mo are discussed. Studies of these materials lead to the following conclusions: (1) the specimens of lei-gong-mo can be morphologically divided into eight types; (2) the sculptures on the surface of lei-gong-mo are probably due to the corrosion effect of volcanic gas, and the abration surface due to the aerodynamic corrosion; (3) the folded structures in the layered lei-gong-mo (Muong Nong-type tektite) seem hardly to be formed by an impact of meteorites, but they might be produced in the magma flow process when the lei-gong-mo was melting within the crater vent; and (4) the comparison of its chemical composition with that of basalt from Hainan Island does not show that lei-gong-mo came from the local volcano. The hypothesis of the lunar volcanic origin of tektites is examined.

  6. Ages of Zhamanshin Crater Impactites and Projectile Tektites

    NASA Astrophysics Data System (ADS)

    Izokh, E. P.; Kashkarov, L. L.; Korotkova, N. N.

    1993-07-01

    The Zhamanshin impact crater is the only one in which impactites have been found together with layered Muong Nong-type glasses and tektites-irghizites associated with microtektites. The K-Ar ages of these tektites vary from 0.69 to 5.2 m.y, while fission-track ages vary from 0.75 to 1.08 m.y. All geological data demonstrate a 10,000-year age of the impact event; this age coincides with the age of the Pleistocene/Holocene boundary [1]. A very young fission-track age of the Zhamanshin basic impactites was obtained [2]; however, these results were contested [3]. To eliminate the suggested high differences in thermal stability between basic and acidic Zhamanshin glasses, glass heating experiments were performed. The ~0.01-m.y. age (Table 1) of the basic impact glass collected from the deep bore holes shows that secondary heating and fission-track annealing by Sun-heating, fires, etc., must be excluded. The same age differences (1-2 orders of magnitude) were confirmed by thermoluminescence. Furthermore, in the Muong Nong-type Zhamanshinite, which is full of target rock inclusions, two different fission-track groups were recognized (Table 2). Therefore the Muong Nong-type Zhamanshinites are not local impactites, but instead represent a part of the projectile, as first suggested by J. O'Keefe [4]. In the Zhamanshin case, few tektites that fell opposite to impact explosion were partially remelted, while tektites that landed just after explosion are practically intact, like all other Australasian tektites [1,5]. Tables 1 and 2 appear here in the hard copy. References: [1] Izokh E. (1991) Soviet Geol. and Geophys., 32, 1-10. [2] Kashkarov L. et al. (1987) 2nd Intl. Conf. on Nat. Glasses, Prague, 199-202. [3] Koeberl C. and Storzer D., ibid., 207-213. [4] O'Keefe J. (1987) Meteoritics, 22, 219-228. [5] Izokh E. and Le duc An (1983) Meteoritika, 42, 158-169.

  7. Potassium isotope abundances in Australasian tektites and microtektites.

    NASA Astrophysics Data System (ADS)

    Herzog, G. F.; O'D. Alexander, C. M.; Berger, E. L.; Delaney, J. S.; Glass, B. P.

    2008-10-01

    We report electron microprobe determinations of the elemental compositions of 11 Australasian layered tektites and 28 Australasian microtektites; and ion microprobe determinations of the 41K/39K ratios of all 11 tektites and 13 of the microtektites. The elemental compositions agree well with literature values, although the average potassium concentrations measured here for microtektites, 1.1 1.6 wt%, are lower than published average values, 1.9 2.9 wt%. The potassium isotope abundances of the Australasian layered tektites vary little. The average value of δ41K, 0.02 ± 0.12‰ (1σ mean), is indistinguishable from the terrestrial value (= 0 by definition) as represented by our standard, thereby confirming four earlier tektite analyses of Humayun and Koeberl (2004). In agreement with those authors, we conclude that evaporation has significantly altered neither the isotopic nor the elemental composition of Australasian layered tektites for elements less volatile than potassium. Although the average 41K/39K ratio of the microtektites, 1.1 ± 1.7‰ (1σ mean), is also statistically indistinguishable from the value for the standard, the individual ratios vary over a very large range, from -10.6 ± 1.4‰ to +13.8 ± 1.5‰ and at least three of them are significantly different from zero. We interpret these larger variations in terms of the evaporation of isotopically light potassium; condensation of potassium in the vapor plume; partial or complete stirring and quenching of the melts; and the possible uptake of potassium from seawater. That the average 41K/39K ratio of the microtektites equals the terrestrial value suggests that the microtektite-forming system was compositionally closed with respect to potassium and less volatile elements. The possibility remains open that 41K/39K ratios of microtektites vary systematically with location in the strewn field.

  8. Effect of a Quaternary Meteoroid Impact in Indo-China on the Surface Sedimentary Record

    NASA Astrophysics Data System (ADS)

    Carling, Paul; Songtham, Wickanet; Tada, Riuji; Tada, Toshihiro; Duangkrayon, Jaa

    2017-04-01

    Effects of meteoroid impacts on terrestrial geology primarily have been considered with respect of proximal effects near the impact location; such as cratering, fracturing and melt. However, other than the use of rare elements (iridium) as event markers and tektite chemistry for dating control, distal effects of impacts are less-well documented. Distal effects might include: fireball, air blast, heat, water vaporization, catastrophic flooding, earthquakes, ejecta fallout (tektites & dust), large quantities of N2O from shock heating of the atmosphere, release of CO2 and sulphur aerosols causing heating or cooling of atmosphere, IR radiation causing vegetation fires, smoke and pyrotoxins, and altered native rock geochemistry. Such processes may affect the distal surface geology, degrade vegetation cover and cause extirpation of flora and fauna. Quaternary sedimentary sections have been examined in northern and central Cambodia, in southern China and in north-east Thailand. These locality lie within the Australian strewn tektite field ̶ reliably dated to 0.77-0.78Ma BP ̶ just before the 0.80Ma BP Brunhes/Matayama reversal. The location of the primary impact crater (if any) is uncertain but a local major crater probably lies within central Laos or just offshore to the east. The described sections are considered distal from the main impact. Stratigraphic evidence indicates a temporal sequence of catastrophic stripping of alluvial-gravel surfaces followed by catastrophic redistribution of gravel (incorporating tektites), followed by deposition of atmospheric dust. Grain-size and grain-density trends, XRD, spherule distributions, luminescence profiles, tektite, and microtektite and shock quartz assay, are used to with the stratigraphic evidence to examine an hypothesis that the sections represent the distal effects of a meteorite. Additional insight is gained with respect to prior claims that large accumulations of woody debris in Thai Quaternary river terraces were due to blast and are burnt. Fossil evidence for the local extirpations of Quaternary mammals within the region might also be related to the impact event. Tektites occur at the same level as occupation horizons of Palaeolithic people such that the impact would have had direct effects on hominins. The stratigraphy includes: erosional antidunes, blast-induced debris flow incorporating tektites, catastrophically-broken laterite pavements and mud layers with reversed magnetism. Sedimentological evidence in favour of impact includes: the presence of delicate thin translucent-tektites that must be in situ from initial fallout as reworking would destroy them, graded spherule distributions, highly-stressed quartz grains and microtektites. Grain size data, including X-ray and CT-scanning analysis, can be used to support the impact hypothesis but alone these data are not conclusive. XRD data is inconclusive. On balance the stratigraphy and sedimentology support the notion that the sediments represent the distal effects of a meteorite in the region.

  9. Laser-fusion 40Ar/39Ar Ages of Darwin Impact Glass

    NASA Astrophysics Data System (ADS)

    Lo, Ching-Hua; Howard, Kieren T.; Chung, Sun-Lin; Meffre, Sebastien

    2002-11-01

    Three samples of Darwin Glass, an impact glass found in Tasmania, Australia at the edge of the Australasian tektite strewn field were dated using the 40Ar/39Ar single-grain laser fusion technique, yielding isochron ages of 796-815 ka with an overall weighted mean of 816 ± 7 ka. These data are statistically indistinguishable from those recently reported for the Australasian tektites from Southeast Asia and Australia (761-816 ka; with a mean weighted age of 803 ± 3 ka). However, considering the compositional and textural differences and the disparity from the presumed impact crater area for Australasian tektites, Darwin Glass is more likely to have resulted from a distinct impact during the same period of time.

  10. Vapor pressure and vapor fractionation of silicate melts of tektite composition

    USGS Publications Warehouse

    Walter, Louis S.; Carron, M.K.

    1964-01-01

    The total vapor pressure of Philippine tektite melts of approximately 70 per cent silica has been determined at temperatures ranging from 1500 to 2100??C. This pressure is 190 ?? 40 mm Hg at 1500??C, 450 ?? 50 mm at 1800??C and 850 ?? 70 mm at 2100?? C. Determinations were made by visually observing the temperature at which bubbles began to form at a constant low ambient pressure. By varying the ambient pressure, a boiling point curve was constructed. This curve differs from the equilibrium vapor pressure curve due to surface tension effects. This difference was evaluated by determining the equilibrium bubble size in the melt and calculating the pressure due to surface tension, assuming the latter to be 380 dyn/cm. The relative volatility from tektite melts of the oxides of Na, K, Fe, Al and Si has been determined as a function of temperature, total pressure arid roughly, of oxygen fugacity. The volatility of SiO2 is decreased and that of Na2O and K2O is increased in an oxygen-poor environment. Preliminary results indicate that volatilization at 2100??C under atmospheric pressure caused little or no change in the percentage Na2O and K2O. The ratio Fe3 Fe2 of the tektite is increased in ambient air at a pressure of 9 ?? 10-4 mm Hg (= 106.5 atm O2, partial pressure) at 2000??C. This suggests that tektites were formed either at lower oxygen pressures or that they are a product of incomplete oxidation of parent material with a still lower ferricferrous ratio. ?? 1964.

  11. The chemical durability of tektites - A laboratory study and correlation with long-term corrosion behavior

    NASA Technical Reports Server (NTRS)

    Barkatt, A.; Boulos, M. S.; Barkatt, A.; Sousanpour, W.; Boroomand, M. A.; Macedo, P. B.; Okeefe, J. A.

    1984-01-01

    Leach tests carried out on tektite specimens (indochinites and australites) under high-dilution conditions show a common behavior characterized by low leach rates (0.00018 g/sq m per d, or 7.2 x 10 to the -12th m/d at 23 C) and an activation energy of (79,600 + or - 700 J/mol). The extent of selective leaching is very small, of the order of 10 to the -8th m. Extrapolation of test results over the lifetime of the tektites gives an excellent agreement with field observations on the extent of corrosion, and this is an important step in establishing the validity of laboratory tests as a basis for the development of models and predictions concerning long-term durabilities at least in the limiting case of high dilution or rapid flow. The results are also shown to be in agreement with various previous observations on the corrosion resistance of tektites. The chemical durability of tektites is observed to be consistent with their composition, highlighting requirements of high corrosion resistance in glasses; these requirements include a silica content in excess of 67 mol percent, an extremely low water content, and an alkali content which is low both absolutely and relative to the di- and poly-valent metal oxide levels. It is shown that artificial glasses which fulfil these criteria are no less corrosion-resistant than the corresponding natural glasses. These conclusions have bearing on the development, as well as on the evaluation, of glasses intended for very long service, such as radioactive waste vitrification media.

  12. Characterization of Particles Created By Laser-Driven Hydrothermal Processing

    DTIC Science & Technology

    2016-06-01

    created by laser-driven hydrothermal processing, an innovative technique used for the ablation of submerged materials. Two naturally occurring...processing, characterization, obsidian, tektite, natural glass 15. NUMBER OF PAGES 89 16. PRICE CODE 17. SECURITY CLASSIFICATION OF REPORT...technique used for the ablation of submerged materials. Two naturally occurring materials, obsidian and tektite, were used as targets for this technique

  13. Healdsburgite - a New Tektite and Associated Tektite Strewnfield in North Central California

    NASA Astrophysics Data System (ADS)

    Erickson, R. C.; Deino, A. L.; Norwick, S. A.; Byrd, C.

    2012-12-01

    Erickson, Rolfe; Norwick, Steven; and Byrd, Caitlin, Sonoma State University; Deino, Alan, Berkeley Geochronology Center. I A Distinctive Glass Clast Population In numerous locations in Sonoma and Solano Counties in north central California, over an area of ~ 200 km2, distinctive ~ 1-5 cm dominantly ovoid glass clasts are found as part of the pebble population in young sediments. They are composed of black massive aphyric nonvesicular glass whose surfaces are totally covered with a texture of adjoining small deep pits and grooves. The pits are hemispherical, 1-10 mm across, and join at sharp edges composed of straight segments. The grooves, where present, are the width and depth of the pits and may be up to several cm long and vermicular. Some clasts have internal layering resembling flow textures. These glass objects were brought to our attention by a local resident, Ms. Diane Moore, about 20 years ago. Four of these glass clasts from widely separated locations in the exposure area have been dated by the laser incremental-heating Ar39/Ar40 method at the Berkeley Geochronology Center, with an age of ~ 2.81 Ma (upper Pliocene). The four samples have mutually overlapping ages at one sigma. Chemical analyses of the 10 major and 50 minor elements, of four widely separated clasts, were obtained at commercial laboratories. The clasts are all rhyolites and cluster tightly on the TAS diagram of Le Maitre et al (2002). All available data show that all these pitted and grooved clasts are part of a single population. II. The Clasts are Tektites We believe these distinctive glass clasts to be tektites for the following reasons: 1. Pits are always present and wholly cover the clast surface. Perhaps half the clasts also have distinctive irregular vermicular grooves superimposed on the pitted surface. This surface pattern is like those on other long-recognized 'classic' tektites, like indochinites. The clasts look like tektites; compare McCall (2001, Figure 2.30) for example. 2. The clasts show no significant weathering. Once cleaned of adhering sediment, they are solid and vitreous. There are also no cases of partial development of the distinctive surface texture, as might be expected if it were a consequence of in situ weathering. 3. The clasts do not have a detrital origin; they are not obsidian pebbles. The pit and groove pattern, which is uniformly well developed on clasts throughout the distribution area, is fragile and could not have survived much transport. 4. The clasts are not volcanic in origin (i.e., 'apache tears'). The pit and groove pattern contrasts with the relatively smooth surface of apache tears, and the clasts bear no resemblance to lapilli. Their distinctive appearance and uniform age and chemistry suggests that these objects are tektites in a strewnfield, only a small part of which has been identified to date. No related impact site has been identified, but clast composition suggests a continental target. We suggest these clasts, heretofore informally called Healdsburg glass, be recognized as tektites and called healdsburgites, in the manner of other tektites. A public domain PDF format copy of this poster will be available for download in the digital archive in the Sonoma State University library.

  14. Local crystal/chemical structures at iron sites in amorphous, magnetic, and nanocrystalline materials

    NASA Astrophysics Data System (ADS)

    Clark, Ted Michael

    Order-disorder phenomena have been examined by means of Mossbauer spectroscopy in a variety of materials, including (a) tektites and other silicate glasses, (b) magnetic materials such as natural and synthetic magnetoplumbite, M-type hexagonal ferrites and magnetite, and (c) nanocrystalline zinc ferrite. A methodology has been established for the analysis of the local crystal/chemical structures of iron in tektites and its application has reconfirmed a low ferric/ferrous ratio of approximately 0.10 for tektites. Additionally, a greater degree of submirocscopic heterogeneity has been established for Muong Nong tektites in comparison with splash form tektites. The dynamics of the 2b site in hexagonal ferrites has been studied above and below the Curie temperature for magnetoplumbite and its synthetic analogs, and also for polycrystalline and oriented single-crystals of MeFesb{12}Osb{19} (Me=Ba, Sr, Pb). Cation ordering on this site is shown to be dependent on the thermal history of the material, while the dynamic disorder of the 2b site for the end-member hexagonal ferrites is shown to be influenced by the divalent heavy metal species, Me. The influence of chemical composition on the morphology of magnetite has been shown to depend on the site preference of impurity cations: Substitutional impurities with tetrahedral site preferences are postulated to result in the seldom-observed cubic habit. Based on the cation distributions of bulk and nanocrystalline material it is held that the enhanced magnetic moments and susceptibilities of nanocrystalline zinc ferrite are shown to be consistent with surface phenomena, independent of synthesis methodology, and contrary to claims of special effects resulting from a particular synthesis methodology.

  15. The Origin of Tektites

    NASA Technical Reports Server (NTRS)

    OKeefe, J. A.

    1960-01-01

    Tektites are probably extraterrestrial, rather than the result of heating some terrestrial materials, because they are a chemically homogeneous group with definite peculiarities (high silica, excess of alkaline earths over alkalis, excess of potash over soda, absence of water), and because some of them (the australites) appear to have undergone ablation in flight through the atmosphere. Since comparatively slow heating is required to explain the liquefaction of the tektite material, it is suggested that the tektites arrived along orbits which were nearly parallel to the surface of the earth, and which resulted from the decay of the orbit of a natural satellite. The great meteor procession of February 9, 1913, is an example of such an object. Comparison with the reentry phenomena of the artificial satellite 1957 Beta suggests that the 1913 shower consisted of a single large stone weighing about 400 kilograms, and a few dozen smaller bodies weighing about 40 grams each, formed by ablation from the larger body. It is shown that under the observed conditions considerable liquid flow would be expected in the stone, which would be heated to about 2100 K. Objects falling from such a shower near the perigee point of the orbit would have a considerable distribution along the orbit as a result of slight variations in height or drag coefficient. The distribution in longitude would be made wider by the turning of the earth under the orbit during the time of fall. The ultimate source of the body which produces a tektite shower is probably the moon, which appears, by virtue of its polarization and the phase distribution of the returned light, to contain high-silica materials. It is suggested that the Igast object alleged to have fallen in 1855 is in fact genuine and represents an unmelted portion of the lunar crust.

  16. Zhamanshin meteor crater

    NASA Technical Reports Server (NTRS)

    Florenskiy, P. V.; Dabizha, A. I.

    1987-01-01

    A historical survey and geographic, geologic and geophysical characteristics, the results of many years of study of the Zhamanshin meteor crater in the Northern Aral region, are reported. From this data the likely initial configuration and cause of formation of the crater are reconstructed. Petrographic and mineralogical analyses are given of the brecciated and remelted rocks, of the zhamanshinites and irgizite tektites in particular. The impact melting, dispersion and quenching processes resulting in tektite formation are discussed.

  17. Some effects of gas adsorption on the high temperature volatile release behavior of a terrestrial basalt, tektite and lunar soil

    NASA Technical Reports Server (NTRS)

    Graham, D. G.; Muenow, D. W.; Gibson, E. K., Jr.

    1979-01-01

    Mass pyrograms obtained from high-temperature, mass psectrometric pyrolysis of a glassy theoleiitic submarine basalt and a tektite, ground in air to less than 64 microns, have shown N2 and SO release patterns very similar to those from the pyrolysis of mature lunar soil fines. The N2 and CO release behavior from the terrestrial samples reproduces the biomodal, high-temperature (approximately 700 and 1050 C) features from the lunar samples. Unground portions of the basalt and tektite show no release of N2 and CO during pyrolysis. Grinding also alters the release behavior and absolute amounts of H2O and CO2. It is suggested that adsorption of atmospheric gases in addition to solar wind implantation of ions may account for the wide range of values in previously reported concentrations of carbon and nitrogen from lunar fines.

  18. A Philippinite with an Unusually Large Bubble: Gas Pressure and Noble Gas Composition

    NASA Astrophysics Data System (ADS)

    Matsuda, J.; Maruoka, T.; Pinti, D. L.; Koeberl, C.

    1995-09-01

    Bubbles are common in tektites, but usually their sizes range up to only a few mm. They are most abundant in Muong Nong-type tektites. The gases contained in these bubbles are of terrestrial atmospheric composition, with pressures below 1 atm (e.g., [1]). The abundances of light noble gases (He, Ne) are controlled by diffusion from the atmosphere [2], and noble gases dissolved in tektite glass indicate that the glass solidified at atmospheric pressures equivalent to about 40 km altitude [3]. Large bubbles in splash-form tektites are rather rare. Thus, the finding that a philippinite (size: 6.0 x 4.5 cm; weight: 199.6 g) contains an unusually large bubble justified a detailed study. The volume of the bubble, which was confirmed by X-ray photography, was estimated at 5.4 cm^3, by comparing the density of this tektite (2.288 g/cm^3) to that of normal philippinites (2.438 g/cm^3). A device was specifically constructed for crushing the present sample under vacuum. The 10x10 cm cylindrical device has a piston that allows to gently crush the sample by turning a handle. Various disk spacers can be used to adjust the inner height to that of the sample. The device is made of stainless steel, yielding a low noble gas blank. The crushing device is connected to a purification line and a noble gas sector-type mass spectrometer (VG 5400) [4]. Before crushing, the complete tektite was wrapped in aluminum foil. A first crushing attempt, using stainless steel disk spacers, failed and resulted in damage to the steel spacers, indicating a high strength of the tektite. Using iron disk spacers resulted in an ambient pressure increase (probably due to hydrogen from the Fe) in the sample chamber. However, the noble gas blanks were negligible. The background pressure, at 2 x 10-4 Torr, increased to 3 x 10-4 Torr when the sample was crushed. From the volume of the crushing device and that of the bubble in the tektite, the total gas pressure in the bubble was estimated at about 1 x 10-4 atm. Part of the extracted gas was kept for total gas analysis, while the remainder has been purified for the noble gas measurements. Total amounts and isotopic ratios of all noble gases were measured. The amounts of Ar, Kr, and Xe close to the blank level, while those of He and Ne were about 3 to 4 orders of magnitude larger than the blank. The ^20Ne/^36Ar ratio in the bubble gas is more than 4 orders of magnitude higher than the atmospheric value, which is similar to the pattern previously observed in tektites [2,3,5]. The isotopic ratios of Ar, Kr and Xe were, within uncertainties, similar to those of the terrestrial atmosphere. However, the Ne isotopic ratios were significantly different from atmospheric values, and differ from the results reported in previous studies [2,5]. The Ne isotope data seem to lie on the mass fractionation line from the atmosphere in a ^20Ne/^22Ne vs. ^21Ne/^22Ne three isotope plot, suggesting that the Ne in the bubble has diffused in from the atmosphere. However, it is generally believed that the isotopic fractionation during a steady state is very small, and the observed Ne values are higher than those calculated from simple mass fractionation [6]. The high isotopic fractionation is likely to be associated with the non-equilibrium conditions prevailing during tektite formation. Acknowledgments: We are grateful to D. Heinlein for bringing the precious sample to our attention and for allowing its analysis. References: [1] Jessberger E. K. and Gentner W. (1972) EPSL, 14, 221-225. [2] Matsubara K. and Matsuda J. (1991) Meteoritics, 26, 217-220. [3] Matsuda J. et al. (1993) Meteoritics, 28, 586-599. [4] Maruoka T. and Matsuda J. (1995) J. Mass Spectrom. Soc. Jpn., 43, 1-8. [5] Hennecke et al. (1975) JGR, 80, 2931-2934. [6] Kaneoka I., EPSL, 48, 284-292.

  19. Project Tektite 1: A multiagency 60-day saturated dive

    NASA Technical Reports Server (NTRS)

    Pauli, D. C. (Editor); Cole, H. A. (Editor)

    1970-01-01

    The history, organization, and accomplishments of Project Tektite are presented. The project demonstrated that it is possible for men to live and work successfully at underwater depths of 49 feet. The biomedical responses of the aquanauts to the 60 day dive are described. The behavioral and psychological responses to each other, the work, and the isolated environment are reported. The experiments conducted in the fields of marine science, psychological sciences, and biomedical sciences are discussed.

  20. Neodymium and strontium isotopic study of Australasian tektites - New constraints on the provenance and age of target materials

    NASA Technical Reports Server (NTRS)

    Blum, Joel D.; Papanastassiou, D. A.; Wasserburg, G. J.; Koeberl, C.

    1992-01-01

    The Nd and Sr isotopic compositions of Australasian tectites (including two flanged Australian tectites, two low-SiO2 Muong Nong-type tectites, and three high-SiO2 Muong Nong-type tectites) and the Nd, Sm, Sr, and Rb concentrations were investigated by isotope-dilution thermal ionization mass spectrometry, and the Sm-Nd and Rb-Sr isotope systematics were used to study the characteristics of the parental material. It is shown that the Nd and Sr isotopic data provide evidence that all Australasian tektites were derived from a single sedimentary formation with a narrow range of stratigraphic ages close to 170 Ma. It is suggested that all of the Australasian tektites were derived from a single impact event and that the australites represent the upper part of a melt sheet ejected at high velocity, whereas the indochinites represent melts formed at a lower level in the target material distributed closer to the area of the impact.

  1. Petrographic and petrological studies of lunar rocks. [Apollo 15 breccias and Russian tektites

    NASA Technical Reports Server (NTRS)

    Winzer, S. R.

    1978-01-01

    Clasts, rind glass, matrix glass, and matrix minerals from five Apollo 15 glass-coated breccias (15255, 15286, 15465, 15466, and 15505) were studied optically and with the SEM/microprobe. Rind glass compositions differ from sample to sample, but are identical, or nearly so, to the local soil, suggesting their origin by fusion of that soil. Most breccia samples contain green or colorless glass spheres identical to the Apollo 15 green glasses. These glasses, along with other glass shards and fragments, indicate a large soil component is present in the breccias. Clast populations include basalts and gabbros containing phases highly enriched in iron, indicative of extreme differentiation or fractional crystallization. Impact melts, anorthosites, and minor amounts of ANT suite material are also present among the clasts. Tektite glasses, impact melts, and breccias from the Zhamanshin structure, USSR, were also studied. Basic tektite glasses were found to be identical in composition to impact melts from the structure, but no satisfactory parent material has been identified in the limited suite of samples available.

  2. Theory of Tumbling Bodies Entering Planetary Atmospheres with Application to Probe Vehicles and the Australian Tektites

    NASA Technical Reports Server (NTRS)

    Tobak, Murray; Peterson, Victor L.

    1964-01-01

    The tumbling motion of aerodynamically stable bodies entering planetary atmospheres is analyzed considering that the tumbling, its arrest, and the subsequent oscillatory motion are governed by the equation for the fifth Painleve' transcendent. Results based on the asymptotic behavior of the transcendent are applied to study (1) the oscillatory behavior of planetary probe vehicles in relation to aerodynamic heating and loads and (2) the dynamic behavior of the Australian tektites on entering the Earth's atmosphere, under the hypothesis that their origin was the Moon.

  3. Source of Australasian Tektites: Investigating Possible Impact Sites in Laos

    NASA Astrophysics Data System (ADS)

    Schnetzler, C. C.; McHone, J. F.

    1995-09-01

    Approximately 770,000 years ago an asteroid or comet crashed with the Earth somewhere in southeast Asia, in what was arguably the largest terrestrial impact in the past several 10's of millions of years. Evidence for this impact is not a crater but ejecta from a crater - tektites, microtektites and impact debris - which are found over more than one-tenth of the Earth's surface. Despite its relative youth and the large size of the ejecta field, the structure produced by this impact has not yet been discovered. In the past few years searches have focused on eastern Indochina, specifically in northeast Thailand [1], Cambodia [2] and Laos [3]. In February, 1995 we spent ten days in southern Laos looking for the source crater. The trip was an outgrowth of an investigation using satellite imagery and a digital topographic database, which suggested the impact site might be one of several structures in southern Laos. The primary purpose of the trip was to investigate these structures; a secondary objective was to document tektite localities and to collect samples of known provenance. One crater-like structure identified from digital topographic and multispectral images seemed to be especially interesting due to its quasi-circular shape and relatively youthful appearance. Three additional suspicious structures were identified near this primary target, but these appeared much more subdued and highly eroded. All of these features lie in southern Laos within the broad region of Mesozoic marine sedimentary rocks, primarily sandstones interbedded with shales and limestones, which covers much of central Indochina. The top-priority structure, centered at 16.35 degrees N/106.15 degrees E, is a ring of steep-sided hills 35 to 40 km in diameter, rising 70 to several hundred meters above the surrounding flat plain. It also has a central elevated area rising about 100 meters above the floor, suggesting an eroded central uplift. Despite difficult field conditions we successfully reconnoitered all four potential impact structures. None showed obvious evidence of formation by extraterrestrial impact. A small domal feature near the city of Savannakhet is probably a salt diapir, and a nearby larger eviscerated domal form to the southeast is similarly related to broadscale evaporite tectonics. The 90 km diameter Savannakhet Basin shows no evidence of impact damage and has been a stable sedimentary trap since Mesozoic times. Our prime target, the 35 to 40 km diameter craterlike depression south of Muong Phin, is an erosional feature etched into upper layers of a sedimentary section. Its "central peak" is a fortuitous resistant erosional remnant. Not a great deal of time was available for the secondary objective, i.e., to look for tektites which occur in Indochina in two forms: layered form (Muong Nong-type) which appear to have flowed over the ground and splash form which solidified during atmospheric flight. We identified ten new sites and collected samples from some of these sites. Nine sites were in southern Laos, and all contained only layered tektites. Three of these sites were found by us in road-material quarries south of the village of Xeno. Here the yellow loessial soil overburden had been scraped off to expose a laterite layer rich in quartz pebbles, where small tektites were found after only a short search. This same technique, looking for road-material quarries beside the highway, was used to find layered tektites by Wasson's 1994 field expedition in Thailand [1] about 200 km to the southwest of our areas in Laos. Our new sites support a working theory [3, 4] that this area is rich in layered tektites but there are no splash-form tektites over a broad area of southern NE Thailand and neighboring Laos. The approximate dimensions of this area appears to be at least 200 by 350 km. Acknowledgments: Work was supported in part by NASA and the Barringer Crater Company. References: [1] Wasson J. T. et al. (1995) JGR, in press. [2] Hartung J. and Koeberl C. (1994) Meteoritics, 29, 411-416. [3] Schnetzler C. C. (1992) Meteoritics, 27, 154-165. [4] Wasson J. T. (1993) Eos Trans. AGU, 74, 390.

  4. The terminal Eocene event - Formation of a ring system around the earth

    NASA Technical Reports Server (NTRS)

    Okeefe, J. A.

    1980-01-01

    It is suggested that the formation of a ring system about the earth by particles and debris related to the North American strewn tektite field is responsible for the terminal Eocene event of 34 million years ago, in which severe climatic changes accompanied by widespread biological extinctions occurred. Botanical data is cited which implies a 20-C decrease in winter temperature with no change in summer temperature, and evidence of the correlation of the North American tektite fall, which is estimated to have a total mass of 10 to the 9th to 10 to the 10th tons, with the disappearance of five of the most abundant species of radiolaria is presented. The possible connection between the tektites and climatic change is argued to result from the screening of sunlight by an equatorial ring of trapped particles of extraterrestrial origin in geocentric orbit which would cut off sunlight only in the winter months. Such a ring, located at a distance of between 1.5 and 2.5 earth radii (the Roche limit) is estimated to have a lifetime of a few million years.

  5. Coeval Ar-40/Ar-39 ages of 65.0 million years ago from Chicxulub crater melt rock and Cretaceous-Tertiary boundary tektites

    NASA Technical Reports Server (NTRS)

    Swisher, Carl C., III; Grajales-Nishimura, Jose M.; Montanari, Alessandro; Margolis, Stanley V.; Claeys, Philippe; Alvarez, Walter; Renne, Paul; Cedillo-Pardo, Esteban; Maurrasse, Florentin J.-M. R.; Curtis, Garniss H.

    1992-01-01

    Ar-40/Ar-39 dating of drill-core samples of a glassy melt rock recovered from beneath a massive impact breccia contained with the 180-kilometer subsurface Chicxulub crater yields well-behaved incremental heating spectra with a mean plateau age of 64.98 +/- 0.05 million years ago (Ma). The glassy melt rock of andesitic composition was obtained from core 9 (1390 to 1393 meters) in the Chicxulub 1 well. The age of the melt rock is virtually indistinguishable from Ar-40/Ar-39 ages obtained on tektite glass from Beloc, Haiti, and Arroyo el Mimbral, northeastern Mexico, of 65.01 +/- 0.08 Ma (mean plateau age for Beloc) and 65.07 +/- 0.10 Ma (mean total fusion age for both sites). The Ar-40/Ar-39 ages, in conjunction with geochemical and petrological similarities, strengthen the suggestion that the Chicxulub structure is the source for the Haitian and Mexican tektites and is a viable candidate for the Cretaceous-Tertiary boundary impact site.

  6. Tektites in cretaceous-tertiary boundary rocks on Haiti and their bearing on the Alvarez impact extinction hypothesis

    NASA Astrophysics Data System (ADS)

    Izett, G. A.

    1991-11-01

    Observational and geochemical data for glass objects recently discovered, by Izett et al. (1990), in K-T boundary rocks on the island of Haiti are presented. The presence of tektites, which are of terrestrial impact origin, in the same bed with a Pt-metal abundance anomaly and shocked mineral grains enormously strengthens the impact component of the Alvarez K-T impact extinction hypothesis. Shocked quartz grains in samples of the Haitian K-T boundary marker bed are about the same size as those at the K-T boundary sites in western North America. Petrographic observations indicate that the K-T marker bed on Haiti is not a primary air fall unit composed entirely of impact ejecta. It contains a small volcanogenic component of locally derived material admixed with the impact ejecta during deposition on the seafloor. The major and trace element composition of the Haitian tektites, in particular, the high Rb and REE content, suggests that the target material melted during the K-T impact was sedimentary with an average composition of andesite, not mafic or ultramafic oceanic crust.

  7. Meteoroid mayhem in Ole Virginny: Source of the North American tektite strewn field

    USGS Publications Warehouse

    Poag, C. Wylie; Powars, David S.; Poppe, Lawrence J.; Mixon, Robert B.

    1994-01-01

    New seismic reflection data from Chesapeake Bay reveal a buried, 85-km-wide, 1.5-2.0-km-deep, peak-ring impact crater, carved through upper Eocene to Lower Cretaceous sedimentary strata and into underlying pre-Mesozoic crystalline basement rocks. A polymictic, late Eocene impact breccia, composed mainly of locally derived sedimentary debris (determined from four continuous cores), surrounds and partly fills the crater. Structural and sedimentary characteristics of the Chesapeake Bay crater closely resemble those of the Miocene Ries peakring crater in southern Germany. We speculate that the Chesapeake Bay crater is the source of the North American tektite strewn field.

  8. Meteoroid mayhem in Ole Virginny: source of the North American tektite strewn field

    USGS Publications Warehouse

    Poag, C.W.; Powars, D.S.; Poppe, L.J.; Mixon, R.B.

    1994-01-01

    New seismic reflection data from Chesapeake Bay reveal a buried, 85-km-wide, 1.5-2.0-km-deep, peak-ring impact crater, carved through upper Eocene to Lower Cretaceous sedimentary strata and into underlying pre-Mesozoic crystalline basement rocks. A polymictic, late Eocene impact breccia, composed mainly of locally derived sedimentary debris (determined from four continuous cores), surrounds and partly fills the crater. Structural and sedimentary characteristics of the Chesapeake Bay crater closely resemble those of the Miocene Ries peak-ring crater in southern Germany. It is speculated that the Chesapeake Bay crater is the source of the North American tektite strewn field. -Authors

  9. Tektite 2 habitability research program: Day-to-day life in the habitat

    NASA Technical Reports Server (NTRS)

    Nowlis, D. P.

    1972-01-01

    Because it is widely agreed that the field of environmental psychology is quite young, it was determined that a sample of recorded observations from a representative mission should be included in the report on Tektite to give the professional reader a better feeling of normal day-to-day life in the isolated habitat. Names of the crew members have been replaced with numbers and some off-color words have been replaced by more acceptable slang; some remarks have been omitted that might lead to easy identification of the subjects. Otherwise, the following pages are exactly as transcribed during the late afternoons and the evenings of the mission.

  10. Spalled, aerodynamically modified moldavite from Slavice, Moravia, Czechoslovakia

    USGS Publications Warehouse

    Chao, E.C.T.

    1964-01-01

    A Czechoslovakian tektite or moldavite shows clear, indirect evidence of aerodynamic ablation. This large tektite has the shape of a teardrop, with a strongly convex, deeply corroded, but clearly identifiable front and a planoconvex, relatively smooth, posterior surface. In spite of much erosion and corrosion, demarcation of the posterior and the anterior part of the specimen (the keel) is clearly preserved locally. This specimen provides the first tangible evidence that moldavites entered the atmosphere cold, probably at a velocity exceeding 5 kilometers per second; the result was selective heating of the anterior face and perhaps ablation during the second melting. This provides evidence of the extraterrestial origin of moldavites.

  11. Trace-element composition of Chicxulub crater melt rock, K/T tektites and Yucatan basement

    NASA Technical Reports Server (NTRS)

    Hildebrand, A. R.; Gregoire, D. C.; Attrep, M., Jr.; Claeys, P.; Thompson, C. M.; Boynton, W. V.

    1993-01-01

    The Cretaceous/Tertiary (K/T) boundary Chicxulub impact is the best preserved large impact in the geologic record. The Chicxulub crater has been buried with no apparent erosion of its intracrater deposits, and its ejecta blanket is known and is well preserved at hundreds of localities globally. Although most of the molten material ejected from the crater has been largely altered, a few localities still preserve tektite glass. Availability of intra- and extracrater impact products as well as plausible matches to the targeted rocks allows the comparison of compositions of the different classes of impact products to those of the impacted lithologies. Determination of trace-element compositions of the K/T tektites, Chicxulub melt rock, and the targeted Yucatan silicate basement and carbonate/evaporite lithologies have been made using instrumental neutron activation analysis (INAA) and inductively coupled plasma mass spectrometry (ICP-MS). Some sample splits were studied with both techniques to ensure that inter-laboratory variation was not significant or could be corrected. The concentration of a few major and minor elements was also checked against microprobe results. Radiochemical neutron activation analysis (RNAA) was used to determine Ir abundances in some samples.

  12. Laboratory synthesis of silicate glass spherules: Application to impact ejecta

    NASA Astrophysics Data System (ADS)

    Stoddard, P. S.; Pahlevan, K.; Tumber, S.; Weber, R.; Lee, K. K.

    2012-12-01

    To investigate the process by which molten droplets of impact ejecta solidify into glassy spherule tektites, we employed laser levitation experiments to recreate the hot temperatures of falling molten rock. Following models for Earth composition based on enstatite chondrites, we levitated mixtures of oxide powders in a stream of gas and melted them with a laser, producing silicate glass beads. After quenching, we polished the ~1 mm diameter samples in cross-section and analyzed with electron probe microanalysis (EPMA). Fine and coarsely-spaced EPMA transects across each bead displayed diffusion profiles at their edges, particularly in their SiO2 and MgO content. Heating altered the beads' bulk composition as well; all of the glassy spherules were compositionally different from the initial combination of powders. By comparing these changes to the environmental factors acting on the bead (e.g., temperature, type of levitation gas, duration of heating and amount of rotation), we produced a model for how molten ejecta change chemically and physically as they solidify into a glass. We find that high temperatures likely generated on impact have a strong effect on the composition of tektites; therefore, attempts to correlate tektites to their parent rocks should correct for this effect.

  13. Shock induced reaction in Chicxulub target materials (CaSO4 and SiO2) and their relation to extinctions

    NASA Technical Reports Server (NTRS)

    Chen, Guangqing; Ahrens, Thomas J.

    1993-01-01

    The global platinum element rich layer, the presence of shocked quartz grains (in some cases with stishovite), and the observation of a tektite-rich layer, precisely at the K-T boundary, are the three major arguments for the extinction bolide impact hypothesis of Alvarez et al. Tektites (spherules) from Beloc in Haiti and Mimbral in Mexico received particular interest because of their geological proximity to the Chicxulub impact structure, which is a leading candidate for at least one of the K-T impact craters. Although in most localities the original glass has weathered to clay minerals, some shock-induced glass is found in outcrops and drill cores which is used for Ar-38/Ar-39 dating. The glassy tektites were found to be chemically similar and coeval at 65.0 Ma with Chicxulub melt rock. Two kinds of K-T spherules were discovered: (1) a silic black glass; and (2) a yellow glass, enriched in Ca, Mg, and S. The high sulfur content of the glass and the abundance of anhydrite (CaSO4) in the carbonate-evaporite sequence observed in Drill Holes Y-1 and Y-2 at Chicxulub prompted studies of calcium sulfate devolatization. Further discussion of our experiments is presented.

  14. Shock induced reaction in Chicxulub target materials (CaSO4 and SiO2) and their relation to extinctions

    NASA Astrophysics Data System (ADS)

    Chen, Guangqing; Ahrens, Thomas J.

    1993-03-01

    The global platinum element rich layer, the presence of shocked quartz grains (in some cases with stishovite), and the observation of a tektite-rich layer, precisely at the K-T boundary, are the three major arguments for the extinction bolide impact hypothesis of Alvarez et al. Tektites (spherules) from Beloc in Haiti and Mimbral in Mexico received particular interest because of their geological proximity to the Chicxulub impact structure, which is a leading candidate for at least one of the K-T impact craters. Although in most localities the original glass has weathered to clay minerals, some shock-induced glass is found in outcrops and drill cores which is used for Ar-38/Ar-39 dating. The glassy tektites were found to be chemically similar and coeval at 65.0 Ma with Chicxulub melt rock. Two kinds of K-T spherules were discovered: (1) a silic black glass; and (2) a yellow glass, enriched in Ca, Mg, and S. The high sulfur content of the glass and the abundance of anhydrite (CaSO4) in the carbonate-evaporite sequence observed in Drill Holes Y-1 and Y-2 at Chicxulub prompted studies of calcium sulfate devolatization. Further discussion of our experiments is presented.

  15. Mid-infrared bi-directional reflectance spectroscopy of impact melt glasses and tektites

    NASA Astrophysics Data System (ADS)

    Morlok, Andreas; Stojic, Aleksandra; Weber, Iris; Hiesinger, Harald; Zanetti, Michael; Helbert, Joern

    2016-11-01

    We have analyzed 14 impact melt glass samples, covering the compositional range from highly felsic to mafic/basaltic, as part of our effort to provide mid-infrared spectra (7-14 μm) for MERTIS (Mercury Radiometer and Thermal Infrared Spectrometer), an instrument onboard of the ESA/JAXA BepiColombo mission. Since Mercury was exposed to many impacts in its history, and impact glasses are also common on other bodies, powders of tektites (Irghizite, Libyan Desert Glass, Moldavite, Muong Nong, Thailandite) and impact glasses (from the Dellen, El'gygytgyn, Lonar, Mien, Mistastin, and Popigai impact structures) were analyzed in four size fractions of (0-25, 25-63, 93-125 and 125-250 μm) from 2.5 to 19 μm in bi-directional reflectance. The characteristic Christiansen Feature (CF) is identified between 7.3 μm (Libyan Desert Glass) and 8.2 μm (Dellen). Most samples show mid-infrared spectra typical of highly amorphous material, dominated by a strong Reststrahlen Band (RB) between 8.9 μm (Libyan Desert Glass) and 10.3 μm (Dellen). Even substantial amounts of mineral fragments hardly affect this general band shape. Comparisons of the SiO2 content representing the felsic/mafic composition of the samples with the CF shows felsic/intermediate glass and tektites forming a big group, and comparatively mafic samples a second one. An additional sign of a highly amorphous state is the lack of features at wavelengths longer than ∼15 μm. The tektites and two impact glasses, Irghizite and El'gygytgyn respectively, have much weaker water features than most of the other impact glasses. For the application in remote sensing, spectral features have to be correlated with compositional characteristics of the materials. The dominating RB in the 7-14 μm range correlates well with the SiO2 content, the Christiansen Feature shows similar dependencies. To distinguish between glass and crystalline phases of the same chemical composition, a comparison between CF the SCFM index (SiO2/(SiO2 + CaO + FeO + MgO)) (Walter and Salisbury [1989] J. Geophys. Res., 94, 9203-9213) is useful, if chemical compositional data are also available.

  16. Tektite 1, man-in-the-sea project: Marine Science Program

    USGS Publications Warehouse

    Clifton, H.E.; Mahnken, C.V.W.; Van Derwalker, J. C.; Waller, R.A.

    1970-01-01

    The Tektite experiment was designed to provide data for a number of behavioral, biomedical, and engineering studies in addition to the marine sciences program. Conditions for some of these studies were not altogether compatible with the program for the marine sciences. For example, isolation imposed by human behavioral studies precluded physical contact with the surface team, even though such contact was physically possible and desirable for the conduct of the marine sciences program. Isolation also imposed on the scientific team the duty of all in-habitat maintenance, both scheduled and unscheduled, thereby taking substantial time from scientific research. In addition, between 10 and 20 percent of the waking time was devoted to performance of psychological tests required for the biomedical studies. Most of the experiments were directed toward detecting potentially adverse changes and thus were accepted as necessary and desirable. The only health problem to affect the scientific program during the dive was a minor external ear infection contracted by all the divers. Nonetheless, the experiment demon. strated, at least to our satisfaction, the advantages of underwater habitation and saturation diving for biological and geological research. A major advantage is the opportunity for continuous monitoring of organisms or processes. In addition, underwater habitation provides for considerably more research time in the water than surface diving or intermittent bottom dwelling, and this advantage increases greatly as the depth of habitation increases. Even in the relatively shallow depths at which Tektite 1 was conducted, the undersea team could spend appreciably more time at work in the water than their colleagues on the surface. Finally, Tektite 1 demonstrated that the scientist who lives in the sea need not have the extensive qualifications of a professional diver. Of the four scientists of the in-habitat team, only Crew Chief Waller was so qualified; the other three had used scuba as a research tool, but on a relatively limited basis. Any healthy, well-conditioned marine scientist with a basic diving background is capable of extending his research into the shallow sea on a full-time basis. It is hoped that many such scientists will in the future be able to utilize the undersea laboratory.

  17. The formation of the moon

    NASA Technical Reports Server (NTRS)

    O'Keefe, J. A., III

    1974-01-01

    Supporting evidence for the fission hypothesis for the origin of the moon is offered. The maximum allowable amount of free iron now present in the moon would not suffice to extract the siderophiles from the lunar silicates with the observed efficiency. Hence extraction must have been done with a larger amount of iron, as in the mantle of the earth, of which the moon was once a part, according to the fission hypothesis. The fission hypothesis gives a good resolution of the tektite paradox. Tektites are chemically much like products of the mantle of the earth; but no physically possible way has been found to explain their production from the earth itself. Perhaps they are a product of late, deep-seated lunar volcanism. If so, the moon must have inside it some material with a strong resemblance to the earth's mantle.

  18. Stratigraphy and sedimentology of the K/T boundary deposit in Haiti

    NASA Technical Reports Server (NTRS)

    Carey, S.; Sigurdsson, H.; Dhondt, S.; Espindola, J. M.

    1993-01-01

    The K/T boundary sequence is exposed in uplifted carbonate sediments of the southwest peninsula of Haiti. It is found at 15 localities within the Beloc formation, a sequence of limestone and marls interpreted as a monoclinal nappe structure thrust to the north. This tectonic deformation has affected the K/T boundary deposit to varying degrees. In some cases the less competent K/T deposit has acted as a slip plane leading to extensive shearing of the boundary layer, as well as duplication of the section. The presence of glassy tektites, shocked quartz, and an Ir anomaly directly link the deposit to a bolide impact. Stratigraphic and sedimentological features of the tripartite sequence indicate that it was formed by deposition from ballistic fallout of coarse tektites, emplacement of particle gravity flows and fine grained fallout of widely dispersed impact ejecta.

  19. Radiometric Dating Does Work!

    ERIC Educational Resources Information Center

    Dalrymple, G. Brent

    2000-01-01

    Discusses the accuracy of dating methods and creationist arguments that radiometric dating does not work. Explains the Manson meteorite impact and the Pierre shale, the ages of meteorites, the K-T tektites, and dating the Mount Vesuvius eruption. (Author/YDS)

  20. Aerodynamic Analysis of Tektites and Their Parent Bodies

    NASA Technical Reports Server (NTRS)

    Adams, E. W.; Huffaker, R. M.

    1962-01-01

    Experiment and analysis indicate that the button-type australites were derived from glassy spheres which entered or re-entered the atmosphere as cold solid bodies; in case of average-size specimens, the entry direction was nearly horizontal and the entry speed between 6.5 and 11.2 km/sec. Terrestrial origin of such spheres is impossible because of extremely high deceleration rates at low altitudes. The limited extension of the strewn fields rules out extraterrestrial origin of clusters of such spheres because of stability considerations for clusters in space. However, tektites may have been released as liquid droplets from glassy parent bodies ablating in the atmosphere of the earth. The australites then have skipped together with the parent body in order to re-enter as cold spheres. Terrestrial origin of a parent body would require an extremely violent natural event. Ablation analysis shows that fusion of opaque siliceous stone into glass by aerodynamic heating is impossible.

  1. Iridium Anomaly Approximately Synchronous with Terminal Eocene Extinctions

    NASA Astrophysics Data System (ADS)

    Alvarez, Walter; Asaro, Frank; Michel, Helen V.; Alvarez, Luis W.

    1982-05-01

    An iridium anomaly has been found in coincidence with the known microtektite level in cores from Deep Sea Drilling Project site 149 in the Caribbean Sea. The iridium was probably not in the microtektites but deposited simultaneously with them; this could occur if the iridium was deposited from a dust cloud resulting from a bolide impact, as suggested for the anomaly associated with the Cretaceous-Tertiary boundary. Other workers have deduced that the microtektites are part of the North American strewn tektite field, which is dated at about 34 million years before present, and that the microtektite horizon in deep-sea cores is synchronous with the extinction of five radiolarian species. Mass extinctions also occur in terrestrial mammals within 4 million years of this time. The iridium anomaly and the tektites and microtektites are supportive of a major bolide impact about 34 million years ago.

  2. Correlating Distal, Medial and Proximal Ejecta Transport/Emplacement From Oblique Cosmic Impact On North American Continental Ice Sheet At MIS20 ( 786 ka) Via Suborbital Analysis (SA).

    NASA Astrophysics Data System (ADS)

    Harris, T. H. S.; Davais, M. E.

    2017-12-01

    Several elements of the 786 ka Australasian (AA) tektite imprint bear close scrutinyin order to locate the parent impact site or structure. The unique Carolina bays unit geologic formation is indicated as a large "medial" ejecta blanket from a large cosmic impact during a period containing 786 ka. Coincidence? Kg-scale sub-spherical hollow splash form AA tektites implies prolonged atmospheric blow out-scale momentum current with a core of sub-parallel or divergent flow volume having essentially zero turbulence. This would allow for plasma entrainment and heating of target mass at prolonged low dynamic pressure during outflow, where adiabatic expansion could deliver both semi-solid Muong Nong-type and inviscid melts above the atmosphere for gentle release upon rarefaction in vacuum. Within a large atmospheric blow-out scale momentum current, target mass becomes entrained at the speed of adiabatic outflow. 10+ km/s ejecta entrainment yields inter-hemispheric emplacement from launch per governing suborbital mechanics, without question. Oblique impact into a thick ice sheet explains reduced excavation volume and shearing disruption in the form of hypersonic steam plasma scouring. Adiabatic expansion would be immediately available to accelerate and further heat proto-tektite target mass. With shock no longer the sole transport engine, kg-scale splash forms and tektite speeds above the post-shock vaporization velocity of quartz are explained by expansion of shocked ice, in agreement with the observed imprint. The 6 Carolina bay shapes or "Davias Archetypes" are reproducible using conic perturbation in Suborbital Analysis, conforming to a formative mechanism of suborbital transport and ballistic emplacement: "Suborbital Obstruction Shadowing" needs only 3 parts in 10,000 of VEL variation around a circular EL-AZ-VEL launch cone, before considering re-entry effects. Transport energy of the Carolina bay sand, calculated using the 3.5 to 4 km/s launch VEL required for its indicated transport, must account for inefficiency of entrained transport. Roughly 1600 cubic kilometers of Carolina bays sand must have taken 10 to 1000 times more energy to transport than the entire Chixulub event yield. Imagery by M. E. Davias of Cintos.org, S.E. Nebraska (top) and Bennettsville, South Carolina (bottom).

  3. Planning and Implementation of Remote Sensing Experiments.

    DTIC Science & Technology

    Contents: TEKTITE II experiment-upwelling detection (NASA Mx 138); Design of oceanographic experiments (Gulf of Mexico, Mx 159); Design of oceanographic experiments (Gulf of Mexico, Mx 165); Experiments on thermal pollution; Remote sensing newsletter; Symposium on remote sensing in marine biology and fishery resources.

  4. Monitoring the coral disease, plague type II, on coral reefs in St. John, U.S. Virgin Islands

    USGS Publications Warehouse

    Miller, J.; Rogers, C.; Waara, R.

    2003-01-01

    In July 1997, conspicuous white patches of necrotic tissue and bare skeleton began to appear on scleractinian corals in several bays around St. John, US Virgin Islands. Analysis of diseased coral tissue from five different species confirmed the presence of a Sphingomonas-like bacterium, the pathogen for plague type II. To date, 14 species of hard corals have been affected by plague type II around St. John. This disease was monitored at Haulover and Tektite Reefs at depths of 7-12 meters. The study site at Tektite Reef has >50% cover by scleractinian corals with 90% of hard corals being composed of Montastraea annular is. Monthly surveys at Tektite Reef from December 1997 to May 2001 documented new incidence of disease (bare white patches of skeleton) every month with associated loss of living coral and 90.5% of all disease patches occurred on M. annularis. The frequency of disease within transects ranged from 3 to 58%, and the area of disease patches ranged from 0.25 to 9000 cm2. The average percent cover by the disease within 1 m2 ranged from 0.01% (?? 0.04 SD) to 1.74% (?? 9.08 SD). Photo-monitoring of 28 diseased corals of 9 species begun in September 1997 at Haulover Reef revealed no recovery of diseased portions with all necrotic tissue being overgrown rapidly by turf algae, usually within less than one month. Most coral colonies suffered partial mortality. Very limited recruitment (e.g., of Agaricia spp., Favia spp. and sponges) has been noted on the diseased areas. This coral disease has the potential to cause more loss of live coral on St. John reefs than any other stress to date because it targets the dominant reef building species, M. annularis.

  5. Tektites, Apollo, the Crust, and Planets: A Life with Trace Elements

    NASA Astrophysics Data System (ADS)

    Taylor, Stuart Ross

    2016-06-01

    Stuart Ross Taylor, MSc (University of New Zealand), PhD (Indiana University), ScD (University of Oxford), FAA, AC, always called Ross, grew up on a farm near Ashburton, New Zealand. Ross has worked on a wide variety of topics in trace element geochemistry, including the composition and evolution of the Moon, the continental crust, tektites, impact glasses, and island arc rocks. In 1969 he carried out the first chemical analysis of the first returned lunar sample at NASA in Houston. He has published 10 books and 240 papers in scientific journals. He was awarded the V.M. Goldschmidt Award of the Geochemical Society in 1993. In 1994 he was elected a Foreign Associate of the National Academy of Sciences. In 1998, he was awarded the Leonard Medal of the Meteoritical Society, in 2002 the Bucher Medal of the American Geophysical Union, and in 2012 the Shoemaker Distinguished Lunar Scientist Medal of the NASA Lunar Science Institute. Asteroid 5670 is named Rosstaylor.

  6. Tektite 2 habitability research program

    NASA Technical Reports Server (NTRS)

    Nowlis, D. P.; Wortz, E. C.; Watters, H.

    1972-01-01

    Multi-level parameters relating to perceived life quality in an isolated research and residence quarters were measured using a variety of tests. The habitat under study, emplaced beneath the sea off the coast of St. John's Island as a part of the Tektite II program, was being used for marine research. The crew for each of the 10 missions consisted of one engineer and 4 scientists. One mission had an all-female crew. Mission length was either 14 or 20 days, and 4 engineers, in covering 6 missions, stayed in the habitat for periods of 30 days each. A personality test was taken before confinement in the habitat. Two attitude tests were filled out by the aquanauts while they were still in the habitat. Daily moods were monitored during all missions. Special observations were made of leisure time use. Standardized private debriefings were administered at the end of each mission to each aquanaut. Other behavioral observations made by another research team were intercorrelated with the other measures described above.

  7. The Twenty-Fifth Lunar and Planetary Science Conference. Part 3: P-Z

    NASA Technical Reports Server (NTRS)

    1994-01-01

    Various papers on lunar and planetary science are presented, covering such topics as: impact craters, tektites, lunar geology, lava flow, geodynamics, chondrites, planetary geology, planetary surfaces, volcanology, tectonics, topography, regolith, metamorphic rock, geomorphology, lunar soil, geochemistry, petrology, cometary collisions, geochronology, weathering, and meteoritic composition.

  8. Trace Element Data help Understanding the Origin of Lake Bosumtwi Crater Related Glass (Ivory Coast Tektites, Microtektites, Fall-Back Particles, Suevite Glass)

    NASA Astrophysics Data System (ADS)

    Deutsch, A.; Langenhorst, F.; Berndt, J.

    2015-09-01

    We report for the four internally rather homogeneous groups of glass (IVC, IVC-MT, BOT 12 [suevite], FBG) concentrations of major and 42 minor elements (in-situ data with LA-ICP-MS) as well as Sr-Nd, and DEGAS data.

  9. Modelling the gravity and magnetic field anomalies of the Chicxulub crater

    NASA Technical Reports Server (NTRS)

    Aleman, C. Ortiz; Pilkington, M.; Hildebrand, A. R.; Roest, W. R.; Grieve, R. A. F.; Keating, P.

    1993-01-01

    The approximately 180-km-diameter Chicxulub crater lies buried by approximately 1 km of sediment on the northwestern corner of the Yucatan Peninsula, Mexico. Geophysical, stratigraphic and petrologic evidence support an impact origin for the structure and biostratigraphy suggests that a K/T age is possible for the impact. The crater's location is in agreement with constraints derived from proximal K/T impact-wave and ejecta deposits and its melt-rock is similar in composition to the K/T tektites. Radiometric dating of the melt rock reveals an age identical to that of the K/T tektites. The impact which produced the Chicxulub crater probably produced the K/T extinctions and understanding the now-buried crater will provide constraints on the impact's lethal effects. The outstanding preservation of the crater, the availability of detailed gravity and magnetic data sets, and the two-component target of carbonate/evaporites overlying silicate basement allow application of geophysical modeling techniques to explore the crater under most favorable circumstances. We have found that the main features of the gravity and magnetic field anomalies may be produced by the crater lithologies.

  10. Accretionary lapilli, tektites, or concretions: the ubiquitous spherules of Meridiani Planum

    NASA Astrophysics Data System (ADS)

    DiGregorio, Barry E.

    2004-11-01

    One of the most enigmatic discoveries made by the NASA Mars Exploration Rover Opportunity (MER-B) at the Meridiani Planum landing site are the ubiquitous spherules referred to as "blueberries" by the science team. They cover the entire landing area and can be seen in every direction within view of the rover cameras. Subsequent analysis of a small grouping of the spherules laying on top of a rock outcrop by Mossbauer spectroscopy showed an intense hematite signature not found on the rock or in the surrounding basaltic soils. Spherules were also found attached to and embedded within sedimentary sulfate rock outcrops found at the landing area that have been determined by the MER science team as having been formed in an acidic liquid water environment. The appearance of most of the Meridiani spherules is strikingly similar to the morphology and size of terrestrial accretionary lapilli and show similarities to terrestrial tektites. Accretionary lapilli are spherical balls and fragments with a concentric layered structure that are formed by a variety of mechanisms including hydrovolcanic eruptions, geysers and large meteorite impacts in water. Tektites are glassy impact spherules that form as a result of large meteorite impacts and also seem apparent in some of the rover images. Tektites can be perfectly spherical or have teardrop and dumbbell shapes. A lack of a visible volcanic source capable of producing high volumes of accretionary lapilli as seen in the MER-B images, in combination with the strong spectral signature of hematite, that some of the spherules display, led the MER science team to favor a concretion hypothesis thus far. All of these types of spherules involve interaction of with surface water or ice to form. Problems exist in explaining how the Martian "concretions", if that is indeed what they are, are of such uniform size and have such a wide distribution. Evidence from Martian orbit and on the surface indicate that the Meridiani Planum landing ellipse is located within an ancient 800 km diameter impact structure with another 140 km crater under the site. Estimated hydrothermal output from this size of an impact would be equivalent to 38 times Yellowstone over a 15,000 year time period. Life as we understand it is dependent on a source of liquid water, energy, and nutrients. Hydrothermal energy can originate from either internal volcanic sources or through the action of large bolide impact. A 25 km diameter fluidized ejecta (rampart) crater named Victoria is located 50 km to the southwest of the Opportunity rover landing site and might explain how the Meridiani Planum region is covered with such an enormous abundance of spherules.

  11. Search for and analysis of radioactive halos in lunar material

    NASA Technical Reports Server (NTRS)

    Gentry, R. V.

    1976-01-01

    The lunar halo search was conducted because halos in terrestrial minerals serve as pointers to localized radioactivity, and make possible analytical studies on the problems of isotopic dating and mode of crystallization of the host mineral. Ancillary studies were conducted on terrestrial halos and on certain samples of special origin such as tektites and meteorites.

  12. Implications for behavior of volatile elements during impacts—Zinc and copper systematics in sediments from the Ries impact structure and central European tektites

    NASA Astrophysics Data System (ADS)

    Rodovská, Zuzana; Magna, TomáÅ.¡; Žák, Karel; Kato, Chizu; Savage, Paul S.; Moynier, Frédéric; Skála, Roman; Ježek, Josef

    2017-10-01

    Moldavites are tektites genetically related to the Ries impact structure, located in Central Europe, but the source materials and the processes related to the chemical fractionation of moldavites are not fully constrained. To further understand moldavite genesis, the Cu and Zn abundances and isotope compositions were measured in a suite of tektites from four different substrewn fields (South Bohemia, Moravia, Cheb Basin, Lusatia) and chemically diverse sediments from the surroundings of the Ries impact structure. Moldavites are slightly depleted in Zn ( 10-20%) and distinctly depleted in Cu (>90%) relative to supposed sedimentary precursors. Moreover, the moldavites show a wide range in δ66Zn values between 1.7 and 3.7‰ (relative to JMC 3-0749 Lyon) and δ65Cu values between 1.6 and 12.5‰ (relative to NIST SRM 976) and are thus enriched in heavy isotopes relative to their possible parent sedimentary sources (δ66Zn = -0.07 to +0.64‰; δ65Cu = -0.4 to +0.7‰). In particular, the Cheb Basin moldavites show some of the highest δ65Cu values (up to 12.5‰) ever observed in natural samples. The relative magnitude of isotope fractionation for Cu and Zn seen here is opposite to oxygen-poor environments such as the Moon where Zn is significantly more isotopically fractionated than Cu. One possibility is that monovalent Cu diffuses faster than divalent Zn in the reduced melt and diffusion will not affect the extent of Zn isotope fractionation. These observations imply that the capability of forming a redox environment may aid in volatilizing some elements, accompanied by isotope fractionation, during the impact process. The greater extent of elemental depletion, coupled with isotope fractionation of more refractory Cu relative to Zn, may also hinge on the presence of carbonyl species of transition metals and electromagnetic charge, which could exist in the impact-induced high-velocity jet of vapor and melts.

  13. Intrinsic oxygen fugacity measurements on seven chondrites, a pallasite, and a tektite and the redox state of meteorite parent bodies

    USGS Publications Warehouse

    Brett, R.; Sato, M.

    1984-01-01

    Intrinsic oxygen-fugacity (fO2) measurements were made on five ordinary chondrites, a carbonaceous chondrite, an enstatite chondrite, a pallasite, and a tektite. Results are of the form of linear log fO2 - 1 T plots. Except for the enstatite chondrite, measured results agree well with calculated estimates by others. The tektite produced fO2 values well below the range measured for terrestrial and lunar rocks. The lowpressure atmospheric regime that is reported to follow large terrestrial explosions, coupled with a very high temperature, could produce glass with fO2 in the range measured. The meteorite Salta (pallasite) has low fO2 and lies close to Hvittis (E6). Unlike the other samples, results for Salta do not parallel the iron-wu??stite buffer, but are close to the fayalite-quartz-iron buffer in slope. Minor reduction by graphite appears to have taken place during metamorphism of ordinary chondrites. fO2 values of unequilibrated chondrites show large scatter during early heating suggesting that the constituent phases were exposed to a range of fO2 conditions. The samples equilibrated with respect to fO2 in relatively short time on heating. Equilibration with respect to fO2 in ordinary chondrites takes place between grades 3 and 4 of metamorphism. Application of P - T - fO2 relations in the system C-CO-CO2 indicates that the ordinary chondrites were metamorphosed at pressures of 3-20 bars, as it appears that they lay on the graphite surface. A steep positive thermal gradient in a meteorite parent body lying at the graphite surface will produce thin reduced exterior, an oxidized near-surface layer, and an interior that is increasingly reduced with depth; a shallow thermal gradient will produce the reverse. A body heated by accretion on the outside will have a reduced exterior and oxidized interior. Meteorites from the same parent body clearly are not required to have similar redox states. ?? 1984.

  14. Australasian microtektites and associated impact ejecta in the South China Sea and the Middle Pleistocene supereruption of Toba

    NASA Astrophysics Data System (ADS)

    Glass, Billy P.; Koeberl, Christian

    2006-02-01

    Australasian microtektites were discovered in Ocean Drilling Program (ODP) Hole 1143A in the central part of the South China Sea. Unmelted ejecta were found associated with the microtektites at this site and with Australasian microtektites in Core SO95-17957-2 and ODP Hole 1144A from the central and northern part of the South China Sea, respectively. A few opaque, irregular, rounded, partly melted particles containing highly fractured mineral inclusions (generally quartz and some K feldspar) and some partially melted mineral grains, in a glassy matrix were also found in the microtektite layer. The unmelted ejecta at all three sites include abundant white, opaque grains consisting of mixtures of quartz, coesite, and stishovite, and abundant rock fragments which also contain coesite and, rarely, stishovite. This is the first time that shock-metamorphosed rock fragments have been found in the Australasian microtektite layer. The rock fragments have major and trace element contents similar to the Australasian microtektites and tektites, except for higher volatile element contents. Assuming that the Australasian tektites and microtektites were formed from the same target material as the rock fragments, the parent material for the Australasian tektites and microtektites appears to have been a fine-grained sedimentary deposit. Hole 1144A has the highest abundance of microtektites (number/cm2) of any known Australasian microtektite-bearing site and may be closer to the source crater than any previously identified Australasian microtektite-bearing site. A source crater in the vicinity of 22° N and 104° E seems to explain geographic variations in abundance of both the microtektites and the unmelted ejecta the best; however, a region extending NW into southern China and SE into the Gulf of Tonkin explains the geographic variation in abundance of microtektites and unmelted ejecta almost as well. The size of the source crater is estimated to be 43 ± 9 km based on estimated thickness of the ejecta layer at each site and distance from the proposed source. A volcanic ash layer occurs just above the Australasian microtektite layer, which some authors suggest is from a supereruption of the Toba caldera complex. We estimate that deposition of the ash occurred ˜800 ka ago and that it is spread over an area of at least 3.7 × 107 km2.

  15. Chemistry of Tertiary sediments in the surroundings of the Ries impact structure and moldavite formation revisited

    NASA Astrophysics Data System (ADS)

    Žák, Karel; Skála, Roman; Řanda, Zdeněk; Mizera, Jiří; Heissig, Kurt; Ackerman, Lukáš; Ďurišová, Jana; Jonášová, Šárka; Kameník, Jan; Magna, Tomáš

    2016-04-01

    Moldavites, tektites of the Central European strewn field, have been traditionally linked with the Ries impact structure in Germany. They are supposed to be derived mainly from the near-surface sediments of the Upper Freshwater Molasse of Miocene age that probably covered the target area before the impact. Comparison of the chemical composition of moldavites with that of inferred source materials requires recalculation of the composition of sediments to their water-, organic carbon- and carbon dioxide-free residuum. This recalculation reflects the fact that these compounds were lost almost completely from the target materials during their transformation to moldavites. Strong depletions in concentrations of many elements in moldavites relative to the source sediments (e.g., Mo, Cu, Ag, Sb, As, Fe) contrast with enrichments of several elements in moldavites (e.g., Cs, Ba, K, Rb). These discrepancies can be generally solved using two different approaches, either by involvement of a component of specific chemical composition, or by considering elemental fractionation during tektite formation. The proposed conceptual model of moldavite formation combines both approaches and is based on several steps: (i) the parent mixture (Upper Freshwater Molasse sediments as the dominant source) contained also a minor admixture of organic matter and soils; (ii) the most energetic part of the ejected matter was converted to vapor (plasma) and another part produced melt directly upon decompression; (iii) following further adiabatic decompression, the expanding vapor phase disintegrated the melt into small melt droplets and some elements were partially lost from the melt because of their volatility, or because of the volatility of their compounds, such as carbonyls of Fe and other transition metals (e.g., Ni, Co, Mo, Cr, and Cu); (iv) large positively charged ions such as Cs+, Ba2+, K+, Rb+ from the plasma portion were enriched in the late-stage condensation spherules or condensed directly onto negatively charged melt droplets; (v) simultaneously, the melt droplets coalesced into larger tektite bodies. Steps (iii)-(v) may have overlapped in time. The still melted moldavite bodies reaching their final size were reshaped by further melt flow. This melt flow was related to moldavite rotation and escape (bubbling off) of the last portion of gaseous volatiles during their flight in a low-pressure region above the dense layer of the atmosphere.

  16. Scanning probe microscopy in mineralogical studies: about origin of the observed roughness of natural silica-rich glasses

    NASA Astrophysics Data System (ADS)

    Golubev, Ye A.; Isaenko, S. I.

    2017-10-01

    We have studied different mineralogical objects: natural glasses of impact (tektites, impactites) and volcanic (obsidians) origin, using atomic force microscopy, X-ray microanalysis, infrared and Raman spectroscopy. The spectroscopy showed the difference in the structure and chemical composition of the glasses of different origin. The analysis of the dependence of nanoscale heterogeneity of the glasses, revealed by the atomic force microscopy, on their structural and chemical features was carried out.

  17. Abstracts for the 54th Annual Meeting of the Meteoritical Society

    NASA Technical Reports Server (NTRS)

    1991-01-01

    Abstracts of the papers presented at 54th Annual Meeting of the Meteoritic Society are compiled. The following subject areas are covered: Antarctic meteorites; nebula and parent body processing; primary and secondary SNC parent planet processes; enstatite chondrites and aubrites; achondrite stew; refractory inclusions; meteorite exposure ages and sizes; interstellar/meteorite connections; lunar origins, processes and meteorites; craters, cratering and tektites; cretaceous-tertiary impact(s); IDPs (LDEF, stratosphere, Greenland and Antarctica); chondrules; and chondrites.

  18. High-resolution record of the Matuyama–Brunhes transition constrains the age of Javanese Homo erectus in the Sangiran dome, Indonesia

    PubMed Central

    Hyodo, Masayuki; Matsu'ura, Shuji; Kamishima, Yuko; Kondo, Megumi; Takeshita, Yoshihiro; Kitaba, Ikuko; Danhara, Tohru; Aziz, Fachroel; Kurniawan, Iwan; Kumai, Hisao

    2011-01-01

    A detailed paleomagnetic study conducted in the Sangiran area, Java, has provided a reliable age constraint on hominid fossil-bearing formations. A reverse-to-normal polarity transition marks a 7-m thick section across the Upper Tuff in the Bapang Formation. The transition has three short reversal episodes and is overlain by a thick normal polarity magnetozone that was fission-track dated to the Brunhes chron. This pattern closely resembles another high-resolution Matuyama–Brunhes (MB) transition record in an Osaka Bay marine core. In the Sangiran sediments, four successive transitional polarity fields lie just below the presumed main MB boundary. Their virtual geomagnetic poles cluster in the western South Pacific, partly overlapping the transitional virtual geomagnetic poles from Hawaiian and Canary Islands’ lavas, which have a mean 40Ar/39Ar age of 776 ± 2 ka. Thus, the polarity transition is unambiguously the MB boundary. A revised correlation of tuff layers in the Bapang Formation reveals that the hominid last occurrence and the tektite level in the Sangiran area are nearly coincident, just below the Upper Middle Tuff, which underlies the MB transition. The stratigraphic relationship of the tektite level to the MB transition in the Sangiran area is consistent with deep-sea core data that show that the meteorite impact preceded the MB reversal by about 12 ka. The MB boundary currently defines the uppermost horizon yielding Homo erectus fossils in the Sangiran area. PMID:22106291

  19. High-resolution record of the Matuyama-Brunhes transition constrains the age of Javanese Homo erectus in the Sangiran dome, Indonesia.

    PubMed

    Hyodo, Masayuki; Matsu'ura, Shuji; Kamishima, Yuko; Kondo, Megumi; Takeshita, Yoshihiro; Kitaba, Ikuko; Danhara, Tohru; Aziz, Fachroel; Kurniawan, Iwan; Kumai, Hisao

    2011-12-06

    A detailed paleomagnetic study conducted in the Sangiran area, Java, has provided a reliable age constraint on hominid fossil-bearing formations. A reverse-to-normal polarity transition marks a 7-m thick section across the Upper Tuff in the Bapang Formation. The transition has three short reversal episodes and is overlain by a thick normal polarity magnetozone that was fission-track dated to the Brunhes chron. This pattern closely resembles another high-resolution Matuyama-Brunhes (MB) transition record in an Osaka Bay marine core. In the Sangiran sediments, four successive transitional polarity fields lie just below the presumed main MB boundary. Their virtual geomagnetic poles cluster in the western South Pacific, partly overlapping the transitional virtual geomagnetic poles from Hawaiian and Canary Islands' lavas, which have a mean (40)Ar/(39)Ar age of 776 ± 2 ka. Thus, the polarity transition is unambiguously the MB boundary. A revised correlation of tuff layers in the Bapang Formation reveals that the hominid last occurrence and the tektite level in the Sangiran area are nearly coincident, just below the Upper Middle Tuff, which underlies the MB transition. The stratigraphic relationship of the tektite level to the MB transition in the Sangiran area is consistent with deep-sea core data that show that the meteorite impact preceded the MB reversal by about 12 ka. The MB boundary currently defines the uppermost horizon yielding Homo erectus fossils in the Sangiran area.

  20. Evidence for a second impactor at the K-Pg Boundary in Baja California, Mexico

    NASA Astrophysics Data System (ADS)

    Santa Catharina, Amanda; Kneller, Benjamin Charles; Charao Marques, Juliana; McArthur, Adam Daniel; Kane, Ian Antony; Silvestre Cevallos Ferriz, Sergio Rafael

    2017-04-01

    Controversies remain regarding the trigger, or triggers, of the Cretaceous/Paleogene Mass Extinction. The Chicxulub Impact and the Deccan Volcanism are the main candidates, but discussions about the timing of these events and the magnitude of their effects on the biota are ongoing. Data collected around the globe suggests that profound alterations in the biosphere occurred at this interval, and locations in the Northeastern Atlantic margin and the Gulf of Mexico show evidences of tsunamis and mass waste deposits directly associated with the Chicxulub Impact. Close to El Rosario, Baja California, an enigmatic stratigraphic succession spanning this interval occurs. The succession is distinct from the normal submarine slope deposits in this region and consists of (1) 30 m thick muddy debrites, rich in terrestrial material including fossilized tree trunks up to 2m long and with evidence of exposure to fires, glassy tektites and a horizon rich in gastropods, bivalves, and fragments of corals; (2) an up to 20 m thick coarse grained tuffaceous interval, andesitic in composition, within a channel-like geometry cutting into the debrites, with lapilli (ranging from 1 to 15 cm in size) in discrete sets, fossilized tree trunks close to the base, tektites and shocked quartz; and (3) muddy debrites interbedded with tuffaceous lenses that become less frequent up section. This succession sits between hemipelagic slope deposits, with an abrupt basal contact onto Upper Maastrichtian mudstones and a gradational top, which represents a stabilisation and return to the typical sedimentation environment, with Danian fauna and flora. We believe unit 1 represents material transported onto the slope by the seismic activity caused by the impact of a bolide, which destabilised the coastal region. The tuffaceous channelized unit has been dated (SHRIMP U-Pb in zircons), and its age is indistinguishable from the proposed ages for the K-Pg Boundary. No volcanic activity of this age has been reported in the surrounding areas, either in the Peninsular Ranges or the Sonora Desert, and the presence of shocked quartz and tektites in this unit compels us to believe that its origin is related to ejecta material from an impact. The distance of these thick and coarse grained deposits from the Chicxulub Impact site (c.2000 km) suggests that these deposits are not related to the Chicxulub Impactor, and therefore may have been generated by a different impact of a geologically similar age, but more proximal to this area. The occurrence of multiple impactors is not uncommon, and should be considered a possibility for the K-Pg Boundary.

  1. Coordination chemistry of titanium (IV) in silicate glasses and melts: IV. XANES studies of synthetic and natural volcanic glasses and tektites at ambient temperature and pressure

    NASA Astrophysics Data System (ADS)

    Farges, François; Brown, Gordon E.

    1997-05-01

    The coordination environment of Ti(IV) in seven natural and synthetic glasses of basaltic, trachytic, rhyolitic composition as well as four tektites has been studied using high-resolution Ti K-edge x-ray absorption near edge structure (XANES) spectroscopy at ambient temperature and pressure. Pre-edge features of Ti K-edge XANES spectra for these glasses suggest that [5]Ti is the dominant Ti coordination in all volcanic glasses. However, in the less polymerized glasses studied (basaltic and trachytic), [6]Ti is also important (30-50% of the total Ti) but [4]Ti was not detected. In contrast, [4]Ti is important in the most polymerized glasses (rhyolites and tektites) (from 30 to 60% of the total Ti depending on NBO/T) with [6]Ti below the detection level (≈10 at%). The local structure around Ti in the natural volcanic glasses is similar to that observed in compositionally similar synthetic silicate glasses and also in Ti-bearing silicate glass and melts with simpler compositions. The presence of F, Cl, and H 2O does not appear to affect the coordination of Ti, based on Ti K-edge XANES measurements of natural glasses bearing these volatile components. In contrast, the presence of nonbridging oxygens (produced by network modifiers) favors [5]Ti in these glass/melts. In parallel, [4]Ti is important when nonbridging oxygens are at small concentrations (NBO/T < 0.1). [6]Ti is detected (i.e., when present >10% of the total Ti) when alkaline-earths are dominant over alkalis, in agreement with bond-valence predictions for Ti-bearing silicate glass/melts below TiO 2 saturation. The abundance of [5]Ti in these silicate glasses (and presumably their melts) is in sharp contrast with the rarity of this Ti coordination state in common rock-forming minerals. Titanium cannot readily enter the structure of most rock-forming minerals, because it is present dominantly as titanyl-bearing ( [5]TiO) units in most natural magmas. In contrast, [6]Ti and [4]Ti (present, respectively, in basic and acidic magmas) are better able to enter inosilicates, but these coordination states represent only a fraction of the Ti in basalts, explaining the usually moderate level of incompatibility of Ti during magmatic differentiation. Finally, [5]Ti transforms to [6]Ti during crystallization of Ti-rich minerals (ilmenite, rutile, pyrochlore).

  2. Proceedings of Naval Facilities Engineering Command Ocean Engineering Conference Held at Washington DC on 23-25 September 1969

    DTIC Science & Technology

    1969-09-01

    use a "plucking" process rather than a pruning " process with our established projects. In this way, the im- portant projects will be accomplished in...Enger, CEC, USN, Commander, NAVFAC 1000-1015 "Ocean Engineering Capt. W.A. Walls Policies" 1015-1030 Coffee Break 1030-1045 Conference Objectives Dr...of Structures a. SEALAB b. TEKTITE Dr. J.D. Stachiw, NCEL c. Concrete Structures D. Potter, NAVFAC d. Penetrations 0945-1000 Coffee Break 1000-1100 e

  3. Tektite-bearing, deep-water clastic unit at the Cretaceous-Tertiary boundary in northeastern Mexico

    NASA Technical Reports Server (NTRS)

    Smit, J.; Montanari, A.; Swinburne, N. H.; Alvarez, W.; Hildebrand, A. R.; Margolis, S. V.; Claeys, P.; Lowrie, W.; Asaro, F.

    1992-01-01

    The hypothesis of Cretaceous-Tertiary (K-T) boundary impact on Yucatan, Mexico, predicts that nearby sites should show evidence of proximal impact ejecta and disturbance by giant waves. An outcrop along the Arroyo el Mimbral in northeastern Mexico contains a layered clastic unit up to 3 m thick that interrupts a biostratigraphically complete pelagic-marl sequence deposited at more than 400 m water depth. The marls were found to be unsuitable for determining magnetostratigraphy, but foraminiferal biostratigraphy places the clastic unit precisely at the K-T boundary. We interpret this clastic unit as the deposit of a megawave or tsunami produced by an extraterrestrial impact. The clastic unit comprises three main subunits. (1) The basal "spherule bed" contains glass in the form of tektites and microtektites, glass spherules replaced by chlorite-smectite and calcite, and quartz grains showing probable shock features. This bed is interpreted as a channelized deposit of proximal ejecta. (2) A set of lenticular, massive, graded "laminated beds" contains intraclasts and abundant plant debris, and may be the result of megawave backwash that carried coarse debris from shallow parts of the continental margin into deeper water. (3) At the top, several thin "ripple beds" composed of fine sand are separated by clay drapes; they are interpreted as deposits of oscillating currents, perhaps a seiche. An iridium anomaly (921 +/- 23 pg/g) is observed at the top of the ripple beds. Our observations at the Mimbral locality support the hypothesis of a K-T impact on nearby Yucatan.

  4. High energy nuclear interactions with matter and nuclear processes in nature. Final report. [Summaries of research activities at New York State University

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Schaeffer, O.A.

    1976-09-01

    The research conducted during the period 1965 to 1975 was concerned with two areas: (1) high energy proton interactions, and (2) nuclear reactions in nature. The systematics of high energy proton produced rare gas nuclides from Cu, Ag, Au, and U targets were investigated. It was found that the lower mass nuclides up to A approximately 30 were produced mainly by fragment emission, while the higher mass nuclides were produced mainly by spallation except for U targets for which fission dominates. The existence of ..beta beta.. decay was firmly established for the first time on experimental grounds. The half-life ofmore » the ..beta beta.. decay /sup 130/Te--/sup 130/Xe was measured to be 2.2 x 10/sup 21/ years. The meteorites St. Severin, Lost City, and Suchy Dul were investigated for cosmic ray proton produced rare gases. Cosmic ray exposure ages of 11, 8, and 23 million years respectively were determined. At the same time, the K--Ar ages were found to be 4.4, 4.1, and 1.9 billion years respectively. A model was proposed which allows a tektite strewn field to be at least 100 km from the impact crater. The model removes one of the major constraints on the terrestrial origins of tektites. It was found that /sup 228/Ra diffuses from sea sediments and as such is a good tracer for studying bottom currents and diffusion processes in the sea. A list of publications is included.« less

  5. Tectites of Vietnam. Tectites delivered by a comet: A hypothesis

    NASA Technical Reports Server (NTRS)

    Izokh, E. P.; An, Le Dyk

    1987-01-01

    Tectites (tektites) are mysterious natural acid glasses that differ dramatically from terrestrial volcanic or impact glasses. There are many arguments that speak in favor of their non-terrestrial origin, and that is why the problem of their origin has an important scientific and historical significance. It is no accident that hundreds of publications written by specialists of various fields from all over the world are devoted to this issue. It is discussed at length in a collection of articles entitled 'Tectites' (1963,1973), as well as in the excellent monograph by O'Keefe (1976).

  6. Microanalytical study of some cosmic dust discovered in sea-floor sediments in China

    NASA Technical Reports Server (NTRS)

    Shijie, Z.; Hanchang, P.; Zhong, Y.

    1984-01-01

    The study of cosmic dust can provide useful data in the investigation of the origin of the Earth and the evolution of celestial bodies. Three types of cosmic dust (ferriginous, siliceous, and glassy) were discovered in the seafloor sediments near China. Their chemical composition and microstructure were examined by X-ray diffraction, fractography, and electron microscopy. The major mineral in an iron-containing cosmic dust is magnetite. The silicate spheres contain sundry metals and metal oxides. Glassy microtektites are similar in composition to tektites, and are found in all the major meteorite areas worldwide.

  7. Laser Raman Spectroscopic Characterization of Shocked Plagioclase from the Lonar Impact Crater, India.

    NASA Astrophysics Data System (ADS)

    Chakrabarti, R.; Basu, A. R.; Peterson, J.; Misra, S.

    2004-12-01

    We report Raman spectra of shocked plagioclase grains from the Lonar impact Crater of India. The Lonar Crater, located in the Buldana district of Maharashtra, India (19° 58'N, 76° 31'E), is an almost circular depression in the 65Ma old basalt flows of the Deccan Traps. Age estimates of this impact crater range from 10-50ka. Tektite and basalt samples were collected for this study from the rim of the crater, which is raised about 20 meters above the surrounding plains. For comparison, a Manicouagan maskelynite and an unaltered mid-oceanic ridge basalt with plagioclase laths were also analyzed. Polished thin sections of all these samples were first petrographically studied. The MORB plagioglase as well as the plagioclase from Lonar host-basalts show first order interference colors and distinct multiple lamellar twinning. The Manicouagan maskelynite is isotropic under crossed-polars. The Lonar tektite samples characteristically demonstrate spherules which are identified by their perfectly circular cross-section and isotropic nature. The spherules also contain fragments of the host basalt with plagioclase laths showing lamellar twinning. The groundmass within the spherules shows lath shaped plagioclase grains, most of which show varying degrees of isotropism due to maskelynitization. Raman scattering measurements were performed using the 514.5 nm line of an argon ion laser at an intensity of 40 kW/cm2. An inverted microscope (Nikon TE3000) with 50x objective (NA 0.55) was used for confocal imaging. A holographic notch filter removed residual laser scatter and the Raman scattering was detected by a silicon CCD at -90° C (Princeton Instruments Spec10-400R). Raman spectra were collected from ~250 cm-1 through 2000 cm-1. Raman spectra of crystalline unshocked plagioclase feldspars from the MORB and the Lonar host basalt show strongest peaks at 265 cm-1, 410 cm-1, 510 cm-1 and 1110 cm-1. The results remain the same for different points in a single grain but vary slightly from one grain to another, perhaps due to difference in composition. This observation is consistent with previously reported analyses of unshocked plagioclase feldspars. The Raman spectra of the maskelynites from the tektite samples show more flattened-out patterns. Earlier studies have reported the "disappearance" of peaks due to an increased luminescent background in experimentally shocked single plagioclase grains (Heymann and Herz, 1990, Cont. Min. Petr. 17, 38-44, 1990). Our study in multiple variably shocked plagioclase grains of the Lonar basalt impact breccia further corroborates these previous observations and reinstates the importance of Raman Spectroscopy in identifying shocked plagioclase grains.

  8. DARWIN Glass and DARWIN Crater Revisited. Multiple Impacts in the Australasian Strewn Field?

    NASA Astrophysics Data System (ADS)

    Meisel, T.; Biino, G. G.; Villa, I. M.; Chambers, J. E.; McHone, J. F.

    1995-09-01

    Darwin glass, an impact glass occurring in South West Tasmania, has been found at least since human beings reached Tasmania ca. 40 k.y. ago. Darwin glass, although in the proximity of the Australasian tektites strewn field, has never been counted as part of it. Darwin Crater was recognized about 30 years ago. Still, the existence of an impact structure in Tasmania has been neglected and does not show up in most compilations of known impact craters. Age determinations on Darwin Glass from the early 70's revealed a combined K-Ar and fission track age of 0.73 +/- 0.04 m.y. [1]. The most recent and most precise estimate for Australites and Indochinites yields 0.784 +/- 0.012 m.y. [2]. The two ages are indistinguishable from each other. This contemporaneity lead to the hypothesis that impact on Earth producing australites also formed Darwin Crater as a primary and/or secondary crater (Gentner et al., 1973). If one believes that all tektites of the Australian strewn field were produced by one impact in or near Indochina, then a special case is required to also form Darwin Crater, which is at least 5000 km away. Atmospheric breakup of a planetary body is a very unlikely possibility, because the distance travelled after breakup is too small to account for the dispersion. Double craters on Earth are always close to each other (e.g., Kara and Kara Ust). A more likely scenario could be an impact of an asteroidal body with an accompanying small moon (e.g., Ida and Gaspra). If one believes in multiple impacts for the formation of Muong Nong-type or layered tektites in the Australasian strewn field, then a collision of an asteroidal body with another body shortly before impact on Earth is required. In this case, an impact on Earth a large distance away (i.e., Tasmania) is realistic. To address the problem of crater recognition and possible simultaneous impact events, a new multidisciplinary investigation is currently underway. We intend to determine the age of three Darwin Glasses with the 40Ar-39Ar technique at the University of Bern. We thus hope to obtain a precise age which will permit or deny verification of multiple impacts large distances apart. New samples, taken from the country rock of the proposed Darwin Crater site, are currently being studied for microscopic impact features. Mathematical calculations will be performed to test possible impact scenarios for the likelihood of contemporaneity of multiple impact events in the Australasian strewn field area. References: [1] Gentner W. et al. (1973) EPSL, 20, 204-210. [2] Kunz J. et al. (1995) LPS XXVI, 809.

  9. Impact Chemistry and the Origin of Life

    NASA Astrophysics Data System (ADS)

    Melosh, H. J.; Pasek, M.

    2012-12-01

    Most discussions of global environmental effects of large impacts focus on changes deleterious to extant life. However, impacts may also produce changes that enhance or even create conditions beneficial to the origin of life. Many other authors have discussed impact delivery of organic molecules, and some have shown the shock synthesis of prebiotic molecules such as amino acids during impact. Our past work on the chemistry of impacts demonstrated that strong chemical reduction occurs in impact melt ejecta (spherules and melt droplets; tektites). Here we focus on the element phosphorus (P), whose role is crucial in biology as the backbone of DNA and RNA, and in metabolic biochemical energy transfer. Pasek previously showed that reduced P readily enters into interesting biological compounds with organic molecules in aqueous solution, and that these reduced P compounds may generate structures similar to sugar phosphates, which are critical to life as we know it. In this talk we argue that impact reduction of P transforms terrestrial and meteoritic phosphates bearing an oxidation state of +5 to the lower redox states of +3 (phosphites) and 0 as an alloy with metal (phosphides). We base this argument on studies of fulgurites—glasses formed by cloud-to-ground lightning—that bear phosphides and phosphites as major carriers of P. Fulgurite chemistry frequently parallels that of impact glasses. Additionally, thermodynamic calculations show that separation of an O-rich vapor from a melt readily results in the transformation of phosphate to phosphites and metal phosphides. These results are confirmed by the presence of metal phosphides within tektites. The impact reduction of phosphates followed by global dispersal of reduced P in the form of glassy droplets likely played a major role in the origin of life on Earth and perhaps on other young planets.

  10. Modelling of dispersal and deposition of impact glass spherules from the Cretaceous-Tertiary boundary deposit

    NASA Technical Reports Server (NTRS)

    Espindola, J. M.; Carey, S.; Sigurdsson, H.

    1993-01-01

    The dispersal of glass spherules or tektites from a bolide impact with the Earth is modelled as ballistic trajectories in standard atmosphere. Ballistic dispersal of Cretaceous-Tertiary boundary impact glass spherules found in Haiti and Mimbral, Mexico requires a fireball radius in excess of 50 km but less than 100 km to account for the observed distribution. Glass spherules from 1 and up to 8 mm in diameter have been found at the KT boundary at Beloc in Haiti, at Mimbral, Mexico, and at DSDP Sites 536 and 540 in the Gulf of Mexico corresponding to paleodistances of 600 to 1000 km from the Chicxulub crater. In Haiti the basal and major glass-bearing unit at the KT boundary is attributed to fallout on basis of sedimentologic features. When compared with theoretical and observed dispersal of volcanic ejecta, the grain size versus distance relationship of the KT boundary tektite fallout is extreme, and rules out a volcanic fallout origin. At a comparable distance from source, the KT impact glass spherules are more than an order of mangitude coarser than ejecta of the largest known volcanic events. We model the dispersal of KT boundary impact glass spherules as ballistic ejecta from a fireball generated by the impact of a 10 km diameter bolide. Mass of ejecta in the fireball is taken as twice the bolide mass. Melt droplets are accelerated by gas flow in the fireball cloud, and leave the fireball on ballistic trajectories within the atmosphere, subject to drag, depending on angle of ejection and altitude. The model for ballistic dispersal is based on equations of motion, drag and ablation for silicate spheres in standard atmosphere.

  11. Natural analogues of nuclear waste glass corrosion.

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Abrajano, T.A. Jr.; Ebert, W.L.; Luo, J.S.

    1999-01-06

    This report reviews and summarizes studies performed to characterize the products and processes involved in the corrosion of natural glasses. Studies are also reviewed and evaluated on how well the corrosion of natural glasses in natural environments serves as an analogue for the corrosion of high-level radioactive waste glasses in an engineered geologic disposal system. A wide range of natural and experimental corrosion studies has been performed on three major groups of natural glasses: tektite, obsidian, and basalt. Studies of the corrosion of natural glass attempt to characterize both the nature of alteration products and the reaction kinetics. Information availablemore » on natural glass was then compared to corresponding information on the corrosion of nuclear waste glasses, specifically to resolve two key questions: (1) whether one or more natural glasses behave similarly to nuclear waste glasses in laboratory tests, and (2) how these similarities can be used to support projections of the long-term corrosion of nuclear waste glasses. The corrosion behavior of basaltic glasses was most similar to that of nuclear waste glasses, but the corrosion of tektite and obsidian glasses involves certain processes that also occur during the corrosion of nuclear waste glasses. The reactions and processes that control basalt glass dissolution are similar to those that are important in nuclear waste glass dissolution. The key reaction of the overall corrosion mechanism is network hydrolysis, which eventually breaks down the glass network structure that remains after the initial ion-exchange and diffusion processes. This review also highlights some unresolved issues related to the application of an analogue approach to predicting long-term behavior of nuclear waste glass corrosion, such as discrepancies between experimental and field-based estimates of kinetic parameters for basaltic glasses.« less

  12. Geochemistry of K/T-boundary Chicxulub ejecta of NE-Mexico

    NASA Astrophysics Data System (ADS)

    Harting, M.; Deutsch, A.; Rickers, K.

    2003-12-01

    Many K/T sections all over the world contain impact spherules supposed related to the Chicxulub event. This study focus on ejecta layers in NE-Mexican profiles. We carried out systematic XRF and synchrotron radiation measurements on such spherules at the HASYLAB and ANKA facilities as well as microprobe analyses (CAMECA SX50). Area scans on tektite-like material of the Bochil section reveal a pronounced zonation in the inner part, dominated by Ba and Sr whereas secondary CaCO3 dominates in the altered margin. The composition of the spherules from the Mesa-Juan Perez section differ significantly from the Beloc (Haiti) and Bochil tektite glasses. At Mesa-Juan Perez, spherules are either extremely rich in Fe and Ca or consist of smectite, some of those carry carbonate inclusions. Yttrium, La and Ce are zoned within the smectite with concentrations below the detection limit and up to 20 æg/g The Ca-rich inclusions are enriched in Y (up to 35 æg/g) and La (18 æg/g) and, compared to the surrounding smectite, also in Ce (up to 34 æg/g). The Ce enrichment in spherules from the Mesa-Juan Perez section indicates impact-melted carbonates of the Yucatan carbonate platform as possible precursor rocks. Recent investigations focus on the chemistry of melt rock samples from the PEMEX wells Yucatan-6 and Chicxulub-1: Their average composition (mean of 250 data points in wt-percent ) is 61.6 for SiO2, 0.16 for TiO2, 18.07 for Al2O3, 0.01 for Cr2O3, 1.98 for Na2O, 1.5 for FeO, 0.05 for MnO, 0.01 for NiO, 0.31 for MgO, 9.14 for K2O, 3.44 for CaO, and 0.01 for SO2. These results are in some cases comparable to the geochemistry of ejecta glasses, e.g. from Beloc (Haiti).

  13. Cretaceous-tertiary boundary spherules and Cenozoic microtektites: Similarities and differences

    NASA Technical Reports Server (NTRS)

    Glass, B. P.; Bohor, Bruce F.; Betterton, William J.

    1993-01-01

    Bohor and Betterton pointed out that the K-T spherules can be divided into three groups. Their Type 1 spherules appear to be found in or adjacent to North America, particularly the Western Interior and in Haiti and Mexico. The Type 1 spherules occur in the lower part of the K-T boundary clay below an Ir anomaly. It is the Type 1 spherules which are most similar to microtektites. The discovery of K-T boundary spherules in Beloc, Haiti, and Mimbral, Mexico, with residual tektite-like glass cores supports the hypothesis that the Type 1 spherules are diagenetically altered microtektites. The similarities and differences of the Type 1 K-T boundary spherules to previously described Cenozoic microtektites are discussed.

  14. Monsters in the sky. I mostri del cielo

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Maffei, P.

    1980-01-01

    The book treats astronomical objects and phenomena which remain unexplained or unproven by current investigators. Specific objects discussed include comets, satellite clouds surrounding the earth, tektites, the planet Vulcan (within the orbit of Mercury), Planet X (beyond Pluto), the Gum Nebula, planetary nebulae, supernovae, supernova remnants, transient X-ray sources, the possible extinction of the dinosaurs by an X-ray explosion and super-supernovae. Attention is also given to the star Eta Carinae, black holes, BL Lacertae objects, active galaxies, Markarian galaxies, N and compact galaxies, Seyfert galaxies, quasars, redshift anomalies, Stephan's quintet of galaxies, and intergalactic black holes or black dwarfs whichmore » may account for the mass necessary to bind together clusters of galaxies.« less

  15. Report on an international workshop on Cryptoexplosions and Catastrophes in the Geological Record, with a Special Focus on the Vredefort Structure

    NASA Technical Reports Server (NTRS)

    Reimold, W. U.

    1988-01-01

    Eighty-five geoscientists gathered in the heart of the Vredefort Cryptoexplosion structure to discuss and evaluate the current knowledge about mass extinctions, impact and volcanic cratering and to obtain first-hand information on the Vredefort structure and its origin. Presentations were made within 8 topical sessions: (1) the regional setting of the Vredefort structure; (2) the Vredefort structure itself; (3) deformations and microdeformations; (4) large cryptoexplosion structures; (5) the Ries Crater; (6) tektites; (7) the K-T boundary, and (8) tectonophysics of cratering. The program was rounded up by working group and plenum discussions culminating in a Workshop report emphasizing problem areas, gaps in the data base and recommendations for future research.

  16. Space Station Habitability Recommendations Based on a Systematic Comparative Analysis of Analogous Conditions

    NASA Technical Reports Server (NTRS)

    Stuster, Jack W.

    1986-01-01

    Conditions analogous to the proposed NASA Space Station are systematically analyzed in order to extrapolate design guidelines and recommendations concerning habitability and crew productivity. Analogous environments studied included Skylab, Sealab, Tektite, submarines, Antarctic stations and oil drilling platforms, among others. These analogues were compared and rated for size and composition of group, social organization, preparedness for mission, duration of tour, types of tasks, physical and psychological isolation, personal motivation, perceived risk, and quality of habitat and life support conditions. One-hundred design recommendations concerning, sleep, clothing, exercise, medical support, personal hygiene, food preparation, group interaction, habitat aesthetics, outside communications, recreational opportunities, privacy and personal space, waste disposal, onboard training, simulation and task preparation, and behavioral and physiological requirements associated with a microgravity environment, are provided.

  17. NUCLEAR CHEMISTRY RESEARCH AT CARNEGIE INSTITUTE OF TECHNOLOGY 1962-1963. Progress Report

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    None

    1963-06-01

    Progress is reported on: nuclear reaction studies of cross sections of iron and stone meteoritic elements for 130- to 400-Mev protons, simulated cosmic- ray irradiations of thick iron and stone targets with 100-Mev to 3-Bev protons, and induced alpha-activity in short half-life ranges; nuclear geochemistry and cosmochemistry studies of nuclide dating of sediments, pseudo-diffusion in ocean and Maria sediments, cosmogenic radionuclides in iron and stone meteorites, cosmogenic radionuclides in Bondoc Achondrite and Bogou iron, half life of Mn/sup 53/, cosmogenic radioactivity in fragments of Sputnik N, Be/sup 10/ occurrence in tektites, and conversion of sealed anticoincidence shield counters to flow,more » counters; and the search for natural radioactivity in Ca/sup 48/. (B.O.G.)« less

  18. Uppermost impact fallback layer in the Bosumtwi crater (Ghana): Mineralogy, geochemistry, and comparison with Ivory Coast tektites

    NASA Astrophysics Data System (ADS)

    Koeberl, Christian; Brandstätter, Franz; Glass, Billy P.; Hecht, Lutz; Mader, Dieter; Reimold, Wolf Uwe

    In 2004, an International Continental Scientific Drilling Program (ICDP) drilling project at the Bosumtwi impact crater, Ghana (10.5 km in diameter, 1.07 Myr old), was performed to study the sediments that fill the lake as well as the underlying impactites. In one (LB-05) of 16 cores drilled into the lake sediments, the zone between the impact breccias and the post-impact sediments was penetrated, preserving the final, fine-grained impact fallback layer. This ~30 cm thick layer contains in the top 10 cm “accretionary” lapilli, microtektite-like glass spherules, and shocked quartz grains. Glass particles -- mostly of splash form less than 1 mm size -- make up the bulk of the grains (~70-78% by number) in the coarser size fraction (>125 μm) of the top of the fallback layer. About one-third of all quartz grains in the uppermost part of the layer are shocked, with planar deformation features (PDFs); almost half of these grains are highly shocked, with 3 or more sets of PDFs. K-feldspar grains also occur and some show shock deformation. The abundance of shocked quartz grains and the average shock level as indicated by the number of sets of PDFs, for both quartz and K-feldspar, decrease with depth into the layer. The well-preserved glass spherules and fragments are chemically rather homogeneous within each particle, and also show relatively small variations between the various particles. On average, the composition of the fallback spherules from core LB-5B is very similar to the composition of Ivory Coast tektites and microtektites, with the exception of CaO contents, which are about 1.5 to 2 times higher in the fallback spherules. This is a rare case in which the uppermost fallback layer and the transition to the post-impact sediments has been preserved in an impact structure; its presence indicates that the impactite sequence at Bosumtwi is complete and that Bosumtwi is a very well-preserved impact crater.

  19. Measuring the specific surface area of natural and manmade glasses: effects of formation process, morphology, and particle size

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Papelis, Charalambos; Um, Wooyong; Russel, Charles E.

    2003-03-28

    The specific surface area of natural and manmade solid materials is a key parameter controlling important interfacial processes in natural environments and engineered systems, including dissolution reactions and sorption processes at solid-fluid interfaces. To improve our ability to quantify the release of trace elements trapped in natural glasses, the release of hazardous compounds trapped in manmade glasses, or the release of radionuclides from nuclear melt glass, we measured the specific surface area of natural and manmade glasses as a function of particle size, morphology, and composition. Volcanic ash, volcanic tuff, tektites, obsidian glass, and in situ vitrified rock were analyzed.more » Specific surface area estimates were obtained using krypton as gas adsorbent and the BET model. The range of surface areas measured exceeded three orders of magnitude. A tektite sample had the highest surface area (1.65 m2/g), while one of the samples of in situ vitrified rock had the lowest surf ace area (0.0016 m2/g). The specific surface area of the samples was a function of particle size, decreasing with increasing particle size. Different types of materials, however, showed variable dependence on particle size, and could be assigned to one of three distinct groups: (1) samples with low surface area dependence on particle size and surface areas approximately two orders of magnitude higher than the surface area of smooth spheres of equivalent size. The specific surface area of these materials was attributed mostly to internal porosity and surface roughness. (2) samples that showed a trend of decreasing surface area dependence on particle size as the particle size increased. The minimum specific surface area of these materials was between 0.1 and 0.01 m2/g and was also attributed to internal porosity and surface roughness. (3) samples whose surface area showed a monotonic decrease with increasing particle size, never reaching an ultimate surface area limit within the particle size range examined. The surface area results were consistent with particle morphology, examined by scanning electron microscopy, and have significant implications for the release of radionuclides and toxic metals in the environment.« less

  20. Using the Planetary Science Institute’s Meteorite Mini-Kits to Address the Nature of Science

    NASA Astrophysics Data System (ADS)

    Lebofsky, Larry A.; Cañizo, Thea L.; Buxner, Sanlyn

    2014-11-01

    Hands-on learning allows students to understand science concepts by directly observing and experiencing the topics they are studying. The Planetary Science Institute (PSI) has created instructional rock kits that have been introduced to elementary and middle school teachers in Tucson, in our professional development workshops. PSI provides teachers with supporting material and training so that they can use the kits as tools for students’ hands-on learning. Use of these kits provides an important experience with natural materials that is essential to instruction in Earth and Space Science. With a stronger knowledge of science content and of how science is actually conducted, the workshops and kits have instilled greater confidence in teachers’ ability to teach science content. The Next Generation Science Standards (NGSS) Performance Expectations includes: “What makes up our solar system?” NGSS emphasizes the Crosscutting Concepts—Patterns Scale, Portion, and Quantity; and Systems and System Models. NGSS also states that the Nature of Science (NOS) should be an “essential part” of science education. NOS topics include understanding that scientific investigations use a variety of methods, that scientific knowledge is based on empirical evidence, that scientific explanations are open to revision in light of new evidence, and an understanding of the nature of scientific models.Addressing a need expressed by teachers for borrowing kits less expensive than our $2000 option, we created a Meteorite Mini-Kit. Each Mini-Kit contains eight rocks: an iron-bearing chondrite, a sliced chondrite (showing iron and chondrules), a tektite, a common Tucson rock, a river-polished rock, pumice, a small iron, and a rounded obsidian rock (false tektite). Also included in the Mini-Kits are magnets and a magnifier. The kits cost $40 to $50, depending on the sizes of the chondrites. A teacher can check out a classroom set of these which contains either 10 or 20 Mini-Kits. Each kit includes a description of the rocks as well as suggestions for using them in the classroom. Our presentation will highlight their use in various venues.

  1. The coming revolution in planetology

    NASA Technical Reports Server (NTRS)

    Okeefe, J. A.

    1985-01-01

    Current ideas about the moon appear to be mistaken on two fundamental points. First, at least within certain large classes of lunar craters, internal origin (i.e., some form of volcanism) predominates over impact; this result raises questions about the reality of the 'era of violent bombardment'. Second, the origin of tektites by meteoritic impact on the earth cannot be reconciled with physical principles and is to be abandoned. The only viable alternative is origin by lunar volcanism, which implies the following: continuance of (rare) explosive lunar volcanism to the present time; existence of silicic lunar volcanism and of small patches of silicic rock at the lunar surface; a body of rock in the lunar interior, probably at great depth, which is closely similar to the earth's mantle and which contains billions of tons of volatiles, probably including hydrogen; and origin of the moon from the earth after the formation of the earth's core.

  2. Ne-20/Ne-22 in the Martian Atmosphere: New Evidence from Martian Meteorites

    NASA Technical Reports Server (NTRS)

    Park, J.; Nyquist, L. E.; Herzog, G. F.; Nagao, K.; Mikouchi, T.; Kusakabe, M.

    2017-01-01

    Analyses of Ne trapped in "pods" of impact melt in the Elephant Moraine 79001 (EET 79001) Martian meteorite led to suggest (Ne-20/Ne-22) approx.10 in the Martian atmosphere (MA). In contrast, obtained trapped (Ne-20/Ne-22)Tr approx.7 from an impact melt vein in Yamato 793605 (Y-793605) and concluded that the isotopic composition of Martian Ne remained poorly defined. A "pyroxene-rich" separate from Dhofar 378 (Dho 378) analyzed gave a comparatively high trapped Ne concentration and (Ne-20/Ne-22) = 7.3+/-0.2 in agreement with the Y-793605 value. We explore the hypothesis that Martian Ne was trapped in the Dho 378 meteorite in a manner similar to entrapment of terrestrial Ne in tektites strengthening the "Martian atmosphere" interpretation. We also report new data for Northwest Africa 7034 (NWA 7034) that are consistent with the Ne data for Dho 378.

  3. Stanley V. Margolis (1943-1992)

    NASA Astrophysics Data System (ADS)

    Alvarez, Walter; Kennett, James P.; Kroopnick, Peter; Mount, Jeffrey F.

    Stanley V. Margolis, geologist, oceanographer, administrator, and teacher, died in Davis, Calif., on November 7, 1992, after a brief illness. His enthusiasm, vitality, and legendary generosity influenced innumerable colleagues and students during his productive career in marine and Earth sciences. He is best known as a leader and often a pioneer in the analysis of surfaces of materials that make up the geologic record of both the Earth and the Moon. He had a well-known knack for applying new analytical tools toward exciting and diverse questions. How old is the polar cryosphere? What is the character of lunar dust? What is the origin of tektites? How do deep-sea manganese nodules form? What caused the extinctions that mark the end of the Cretaceous? Is the Kouros an authentic Greek artifact or simply a modern fake? Stan's approaches to these and a host of other diverse questions were creative and innovative.

  4. High Temperature, Controlled-Atmosphere Aerodynamic Levitation Experiments with Applications in Planetary Science

    NASA Astrophysics Data System (ADS)

    Macris, C. A.; Badro, J.; Eiler, J. M.; Stolper, E. M.

    2016-12-01

    The aerodynamic levitation laser apparatus is an instrument in which spherical samples are freely floated on top of a stream of gas while being heated with a CO2laser to temperatures up to about 3500 °C. Laser heated samples, ranging in size from 0.5 to 3.5 mm diameter, can be levitated in a variety of chemically active or inert atmospheres in a gas-mixing chamber (e.g., Hennet et al. 2006; Pack et al. 2010). This allows for containerless, controlled-atmosphere, high temperature experiments with potential for applications in earth and planetary science. A relatively new technique, aerodynamic levitation has been used mostly for studies of the physical properties of liquids at high temperatures (Kohara et al. 2011), crystallization behavior of silicates and oxides (Arai et al. 2004), and to prepare glasses from compositions known to crystallize upon quenching (Tangeman et al. 2001). More recently, however, aerodynamic levitation with laser heating has been used as an experimental technique to simulate planetary processes. Pack et al. (2010) used levitation and melting experiments to simulate chondrule formation by using Ar-H2 as the flow gas, thus imposing a reducing atmosphere, resulting in reduction of FeO, Fe2O3, and NiO to metal alloys. Macris et al. (2015) used laser heating with aerodynamic levitation to reproduce the textures and diffusion profiles of major and minor elements observed in impact ejecta from the Australasian strewn field, by melting a powdered natural tektite mixed with 60-100 μm quartz grains on a flow of pure Ar gas. These experiments resulted in quantitative modeling of Si and Al diffusion, which allowed for interpretations regarding the thermal histories of natural tektites and their interactions with the surrounding impact vapor plume. Future experiments will employ gas mixing (CO, CO2, H2, O, Ar) in a controlled atmosphere levitation chamber to explore the range of fO2applicable to melt-forming impacts on other rocky planetary bodies, including the Moon and Mars. Arai et al., Rev. Sci. Instrum. 75, 2262-2265 (2004) Hennet et al., Rev. Sci. Instrum. 73, 124-129 (2001) Kohara et al., P. Natl. Acad. Sci.USA 108, 14780-14785 (2011) Macris et al., GSA Abstracts with Programs 47, 437 (2015) Pack et al., Geochem. T. 11, 1-16 (2010) Tangeman et al., Geophys. Res. Lett. 28, 2517-2520 (2001)

  5. Australasian microtektites: Impactor identification using Cr, Co and Ni ratios

    NASA Astrophysics Data System (ADS)

    Folco, L.; Glass, B. P.; D'Orazio, M.; Rochette, P.

    2018-02-01

    Impactor identification is one of the challenges of large-scale impact cratering studies due to the dilution of meteoritic material in impactites (typically < 1 wt%). The nature of the impactor that generated the Australasian tektite/microtektite strewn field, i.e., the largest Cenozoic strewn field (∼15% of the Earth's surface), the youngest (∼0.78 Myr old) on Earth, and the only one without an associated impact crater so far, is an outstanding issue. We identify a chondritic impactor signature in 77 Australasian microtektites (size range: ∼200-700 μm) from within 3000 km from the hypothetical impact location in Indochina (∼17°N, 107°E) based on variations of Cr, Co and Ni interelement ratios in a Co/Ni vs Cr/Ni space (46 microtektites analyzed in this work by Laser Ablation-Inductively Coupled Plasma -Mass Spectrometry and 31 from literature by means of Neutron Activation Analyses with Cr, Co and Ni concentrations up to ∼370, 50 and 680 μg/g, respectively). Despite substantial overlap in Cr/Ni versus Co/Ni composition for several meteorite types with chondritic composition (chondrites and primitive achondrites), regression calculation based on ∼85% of the studied microtektites best fit a mixing line between crustal compositions and an LL chondrite. However, due to some scatter mainly in the Cr versus Ni ratios in the considered dataset, an LL chondrite may not be the best fit to the data amongst impactors of primitive compositions. Eight high Ni/Cr and five low Ni/Cr outlier microtektites (∼15% in total) deviate from the above mixing trend, perhaps resulting from incomplete homogenization of heterogeneous impactor and target precursor materials at the microtektite scale, respectively. Together with previous evidence from the ∼35 Myr old Popigai impact spherules and the ∼1 Myr old Ivory Coast microtektites, our finding suggests that at least three of the five known Cenozoic distal impact ejecta were generated by the impacts of large stony asteroids of chondritic composition, and possibly of ordinary chondritic composition. The impactor signature found in Australasian microtektites documents mixing of target and impactor melts upon impact cratering. This requires target-impactor mixing in both the two competing models in literature for the formation of the Australasian tektites/microtektites: the impact cratering and low-altitude airburst plume models.

  6. Paleo-Environment and C-14 Dating: The Key to the Depositional Age of the Tha Chang and Related Sand Pits, Northeastern Thailand

    NASA Technical Reports Server (NTRS)

    Putthapiban, P.; Zolensky, M.; Jull, T.; Demartino, M.; Salyapongse, S.

    2012-01-01

    Tha Chang sand pits, Nakhon Ratchasima Province and many other sand pits in the area adjacent to the Mun River are characterized by their fluviatile environment in association with mass wasting deposits, along the paleo-river channel and the flood plain of the Mun River. Sediments of these deposits are characterized by clasts of various rock types especially the resistant ones with frequent big tree trunks, logs and wood fragments in different sizes and various stages of transformation from moldering stage to lignification and petrification. Widespread pyritization of the lower horizon suggests strongly reducing environment during burial. The Tha Chang deposits have been received much attention from geoscientists especially paleontologist communities, as they contain fragments of some distinct vertebrate species such as Stegadon sp., hominoid primate, rhinoceros Aceratherium and others. Based on the associated mammal fauna and hominoid fossils, the late Miocene ( 9 - 6 Ma) was given for the time of deposition of this sand and gravel unit. Some other reports believed that sediments and materials of these sand and gravel quarries (pits) were deposited by high-energy flood pulses contemporaneous with the tektites forming event during mid-Pleistocene at c. 0.8 Ma. Interpretation from Palynostratigraphical study suggested that the lower horizon of Tha Chang sand pit was deposited during Pliocene/Pleistocene period and the upper horizons are Pleistoncene/Holocene. It is crystal clear that all the fluviatile sediments including tektites and almost all fossil fragments being deposited in these sand pits were, likely a multiple times reworked materials. Only some old bamboo trees, some old crowling trees and fossils grasses observed on the old river bank are considered in situ. C-14 dating of 5 old wood specimens from Tha Chang Sand Pits, 15 old wood specimens from Chumpuang Sand Pits and one sample of old pottery from a Chumpuang Sand Pit were carried out in the NSF- Arizona AMS Laboratory. Although, there is no sharp boundary between the unconsolidated sedimentary horizons in the pits, C-14 ages obtained from the Tha Chang vary from 34,340 BP at the middle horizon (approx 10 m below ground zero) to >49,900 BP at the lower horizon with unknown basal formation (highly pyritized zone approx 20 - 25 m below ground zero). The ages for the Chumpuang vary from 41,700 BP, >45,900 BP and >49,900 BP from the upper most to the lower most of a broad horizon (approx 8 m to approx 12 m below ground zero). The C-14 age of the pottery collected from layer approximately 5 m below ground zero is 2,514 BP. The nature of fluviatile together with occasional mass wasting characteristics of all sand pits studies suggest the relatively faster depositional rate of the lower horizon which involved more flooding and mass wasting deposits than those of the upper horizons. The apparent of some mixing of the wood ages may indicate reworking and lag deposits nature of the area. The depositional rate of the upper most sand and soil horizon (5 m thick) is approximately 1 m per 500 years which mean both erosion and deposition had played a significant role during that time period. In term of the true age of the formation, we argue that since most of the materials deposited are reworked materials, all ages obtained from fossil fragments could not be the age of sand and gravel formation. Furthermore, the maximum age of all the tektite bearing horizons cannot be older than 0.8 Ma. The oldest C-14 age of 49,900 BP is interpreted as the minimum age of the Tha Chang and related sand pits formation when geomorphology of the area was a lot more hilly and much higher gradient than that of the present day.

  7. Projectile-target mixing in melted ejecta formed during a hypervelocity impact cratering event

    NASA Technical Reports Server (NTRS)

    Evans, Noreen Joyce; Ahrens, Thomas J.; Shahinpoor, M.; Anderson, W. W.

    1993-01-01

    Tektites contain little to no projectile contamination while, in contrast, some distal ejecta deposits can be relatively projectile-rich (e.g. the Cretaceous-Tertiary (K-T) boundary clay). This compositional difference motivated an experimental study of hypervelocity target-projectile mixing processes. We hope to scale up the results from these experiments and apply them to terrestrial impact structures like the Chicxulub Crater, Yucutan, Mexico, the leading contender as the site for the impact that caused the mass extinction that marks the K-T boundary. Shock decomposition of the approximately 500m thickness of anhydrite, or greater thickness of limestone, in the target rocks at Chicxulub may have been a critical mechanism for either global cooling via SO3, and subsequently H2SO4, formation, or possibly, global warming via increased CO2 formation. Understanding target-projectile mixing processes during hypervelocity impact may permit more accurate estimates of the amount of potentially toxic, target-derived material reaching stratospheric heights.

  8. Discovery of coesite and shocked quartz associated with the upper Eocene cpx spherule layer

    NASA Technical Reports Server (NTRS)

    Liu, S.; Kyte, T.; Glass, B. P.

    2002-01-01

    At least two major impact ejecta layers have been discovered in upper Eocene strata. The upper layer is the North American microtektite layer. lt consists tektite fragments, microtektites, and shocked mineral grains (e.g., quartz and feldspar with multiple sets of PDFs, coesite and reidite (a high-pressure polymorph of zircon)). The slightly older layer contains clinopyroxene-bearing (cpx) spherules and microtektites associated with an Ir anomaly. The North American tektite layer may be derived from the Chesapeake Bay impact structure, and the cpx spherule layer may from the Popigai impact crater. A cpx spherule layer associated with a positive Ir anomaly was recently found at ODP Site 709, western Indian Ocean. A large sample (Hole 709C, core 31, section 4, 145-150 cm), originally used for a study of interstitial water by shipboard scientists, was acquired for the purpose of recovering a large number of spherules for various petrographic and geochemical studies. A split of the sample (50.35 g) was disaggregated and wet-sieved. More than 17,000 cpx spherules and several hundred microtektites (larger than 125 microns) were recovered from the sample. Rare white opaque grains were observed in the 125-250 micron size fraction after removal of the carbonate component using dilute HCI. Seven of the white opaque grains were X-rayed using a Gandolfi camera and six were found to be coesite (probably mixed with lechatelierite). Eighty translucent colorless grains from the 63-125 micron size fraction were studied with a petrographic microscope. Four of the grains exhibit one to two sets of planar deformation features (PDFs). The only other possible known occurrence of shocked minerals associated with the cpx spherule layer is at Massignano, Italy, where pancake-shaped clay spherules (thought to be diagenetically altered cpx spherules are associated with a positive Ir anomaly and Ni- rich spinel crystals. Shocked quartz grains with multiple sets of PDFs also occur at this site. Until now, unmelted impact ejecta have not been found associated with the cpx spherules at any of the other 20 sites around the world and this is the first time that coesite has been found associated with the cpx spherule layer. The discovery of coesite and shocked quartz associated with the cpx spherules at Site 709 in Indian Ocean is further evidence for the impact origin of the cpx spherule layer. We hope that future discovery of other unmelted minerals from this sample may provide materials to establish constraints on the provenance of this late Eocene ejecta.

  9. Magnetic Characterization of Proposed Tektite-like Objects (Urengoites, South-Ural Glass) from Siberia, Russia

    NASA Astrophysics Data System (ADS)

    Bezaeva, N. S.; Rochette, P.; Masaitis, V. L.; Badyukov, D. D.; Kosterov, A.

    2017-12-01

    Urengoites and South-Ural glass are proposed `tektite-like' objects from Western Siberia (Russia), previously described in [1-3]. Urengoites (U-1, U-2, U-3; 24 Ma [1]) were discovered near the West-Siberian town of Novy Urengoi [1-2]. Total recovered mass: 21.65 g. The only recovered South-Ural glass A-1 was found near Magnitogorsk ( 90 g) [3]. In spite of previous works [1-3], the magnetic properties of urengoites and South-Ural glass remain unknown. Here we present a comprehensive magnetic characterization for all three currently known urengoite specimens and the only discovered South-Ural glass. Rock magnetic investigations revealed the presence of ferrimagnetic minerals in all samples. Low-temperature magnetometry (ZFC-FC dataset) points out to magnetite, which was detected in the most magnetic urengoite sample (U-3) via its characteristic Verwey transition at 120K (<1 ppm). Contrary to previous investigations [2], we could measure NRM for all samples and acquire alternating field demagnetization spectra for the biggest samples (U-1 and A-1). The following SIRM values were recorded: 4.33 μAm2/kg (U-1). 13.20 μAm2/kg (U-2), 62.40 μAm2/kg (U-3) and 9.36 μAm2/kg (A-1). The obtained χ0 values for all four samples (U-1 to U-3: from 9.98 to 19.90·10-9 m3/kg; A-1: 4.66·10-9 m3/kg) are close to those for Libyan glassed (see Table 1 in [4]). Anisotropy of magnetic susceptibility (AMS) measurements for A-1 sample revealed 28% of anisotropy. SIRM values and non-isotropic susceptibility demonstrate a composite ferrimagnetic and paramagnetic origin of susceptibility. U-1 and A-1 do not demonstrate any field nor frequency dependence of χ0, which likely indicates the absence of superparamagnetic grains of nanometric size. Acknowledgements: The work is supported by Act 211 Government of the Russian Federation, agreement № 02.A03.21.0006 and is performed according to the Russian Government Program of Competitive Growth of Kazan Federal University. This research has been conducted using the facilities of St. Petersburg University Scientific Park, RCs Geomodel, DFM, and ITCN. Refs: [1] Deutsch A. et al. (1997) MAPS 32:679-686. [2] Masaitis V.L. et al. (1988) LPS XIX:728-729. [3] Koroteev V.A. et al. (1994) Zapisky Vseross. Mineral. Obsh. 123:44-48 (in Russian). [4] Rochette et al. (2015) EPSL 432:381-390.

  10. Living in contained environments: Research implications from undersea habitats. [undersea habitats

    NASA Technical Reports Server (NTRS)

    Helmreich, Robert L.

    1986-01-01

    A cost-reward model is used to frame a discussion of differences in observed behavior of individuals and groups in confined environments. It has been observed that the high cost of functioning in a stressful environment is likely to produce poor performance when anticipated rewards are low but that participants can manage the stress and achieve high performance if they anticipate high rewards. The high-reward environment is exemplified by early undersea habitats such as Sealab and Tektite and by early space missions. Other aspects of behavior occur in all confined environments and point to an important area for future research. Of particular interest are intergroup conflicts arising between the confined group and its external control. Also, individual differences in personality seem always to have an impact in confined environments. Recent research has focused on: (1) predicting performance and adjustment based on instrumental and expressive aspects of the self; (2) the differential predictive power of achievement striving and irritation/irritability in Type A personalities; and (3) the nature and role of leadership in small, isolated groups.

  11. Relaxation dynamics of nanosecond laser superheated material in dielectrics

    DOE PAGES

    Demos, Stavros G.; Negres, Raluca A.; Raman, Rajesh N.; ...

    2015-08-20

    Intense laser pulses can cause superheating of the near-surface volume of materials. This mechanism is widely used in applications such as laser micromachining, laser ablation, or laser assisted thin film deposition. The relaxation of the near solid density superheated material is not well understood, however. In this work, we investigate the relaxation dynamics of the superheated material formed in several dielectrics with widely differing physical properties. The results suggest that the relaxation process involves a number of distinct phases, which include the delayed explosive ejection of microscale particles starting after the pressure of the superheated material is reduced to aboutmore » 4 GPa and for a time duration on the order of 1 μs. The appearance of a subset of collected ejected particles in fused silica is similar to that of micro-tektites and provides information about the state of the superheated material at the time of ejection. Lastly, these results advance our understanding of a key aspect of the laser–material interaction pathway and can lead to optimization of associated applications ranging from material processing to laser surgery.« less

  12. Lunar and Planetary Science XXXV: Effects of Impacts: Shock and Awe

    NASA Technical Reports Server (NTRS)

    Kyte, F. T.; Koeberl, C.

    2004-01-01

    This document discusses the following topics: Zircon as a Shock Indicator in Impactites of Drill Core Yaxcopoil-1, Chicxulub Impact Structure, Mexico; Experimental Investigation of Shock Effects in a Metapelitic Granulite; Experimental Reproduction of Shock Veins in Single-Crystal Minerals; Post-Shock Crystal-Plastic Processes in Quartz from Crystalline Target Rocks of the Charlevoix Impact Structure; Shock Reequilibration of Fluid Inclusions; How Does Tektite Glass Lose Its Water?; Assessing the Role of Anhydrite in the KT Mass Extinction: Hints from Shock-loading Experiments; A Mineralogical and Geochemical Study of the Nonmarine Permian/Triassic Boundary in the Southern Karoo Basin, South Africa; Extraterrestrial Chromium in the Permian-Triassic Boundary at Graphite Peak, Antarctica; Magnetic Fe,Si,Al-rich Impact Spherules from the P-T Boundary Layer at Graphite Peak, Antarctica; A Newly Recognized Late Archean Impact Spherule Layer in the Reivilo Formation, Griqualand West Basin, South Africa; Initial Cr-Isotopic and Iridium Measurements of Concentrates from Late Eocene Cpx-Spherule Deposits; An Ordinary Chondrite Impactor Composition for the Bosumtwi Impact Structure, Ghana, West Africa: Discussion of Siderophile Element Contents and Os and Cr Isotope Data.

  13. Scientific Tools and Techniques: An Innovative Introduction to Planetary Science / Astronomy for 9th Grade Students

    NASA Astrophysics Data System (ADS)

    Albin, Edward F.

    2014-11-01

    Fernbank Science Center in Atlanta, GA (USA) offers instruction in planetary science and astronomy to gifted 9th grade students within a program called "Scientific Tools and Techniques" (STT). Although STT provides a semester long overview of all sciences, the planetary science / astronomy section is innovative since students have access to instruction in the Center's Zeiss planetarium and observatory, which includes a 0.9 m cassegrain telescope. The curriculum includes charting the positions of planets in planetarium the sky; telescopic observations of the Moon and planets; hands-on access to meteorites and tektites; and an introduction to planetary spectroscopy utilizing LPI furnished ALTA reflectance spectrometers. In addition, students have the opportunity to watch several full dome planetary themed planetarium presentations, including "Back to the Moon for Good" and "Ring World: Cassini at Saturn." An overview of NASA's planetary exploration efforts is also considered, with special emphasis on the new Orion / Space Launch System for human exploration of the solar system. A primary goal of our STT program is to not only engage but encourage students to pursue careers in the field of science, with the hope of inspiring future scientists / leaders in the field of planetary science.

  14. Inducement of heterochronic variation in a species of planktic foraminifera by a Late Eocene impact event

    NASA Technical Reports Server (NTRS)

    Macleod, N.; Kitchell, J. A.

    1988-01-01

    While it is well known that the cosmic impact event at or near the Cretaceous-Tertiary boundary coincides with an interval of mass extinction, a similar impact (or series of impacts) near the Eocene-Oligocene boundary presents a more complex picture, in terms of associated fluctuations in marine biotic diversity. Tektites, microtektites, and mineral grains exhibiting features of shock metamorphism found in Eocene sediments of the western N. Atlantic, Caribbean, and Gulf of Mexico (comprising the North American microtektite strewn field) offer compelling evidence for a catastrophic impact event. Despite the magnitude of this event, however, few extinctions in the planktic marine fauna are known to have occurred coincident with this event. Instead, changes in relative abundance, morphology, and development occurred. Cosmic impacts generally have been interpreted as influencing the course of evolution through the wholesale elimination of significant portions of standing biotic diversity. Indeed, extinction traditionally has been viewed as the negative side of evolution. In some instances, it is suggested such impact events can serve instead to increase, rather than decrease, morphological and ecological diversity, by altering the developmental programs within species at the level of the local population.

  15. Earth: A Ringed Planet?

    NASA Astrophysics Data System (ADS)

    Hancock, L. O.; Povenmire, H.

    2010-12-01

    Among the most beautiful findings of the Space Age have been the discoveries of planetary rings. Not only Saturn but also Jupiter, Uranus and Neptune have rings; Saturn’s ring system has structures newly discovered; even Saturn's moon Rhea itself has a ring. All these are apparently supplied by material from the planetary moons (Rhea's ring by Rhea itself). The question naturally arises, why should the Earth not have a ring, and on the other hand, if it does, why has it not been observed? No rings have yet been observed in the inner solar system, but after all, rings in the inner solar system might simply tend to be fainter and more transient than those of the outer solar system: the inner solar system is more affected by the solar wind, and the Sun’s perturbing gravitational influence is greater. J.A. O’Keefe first suggested (1980) that Earth might have a ring system of its own. An Earth ring could account for some climate events. O’Keefe remarked that formation or thickening of a ring system in Earth’s equatorial plane could drive glaciation by deepening the chill of the winter hemisphere. (It is very well established that volcanic dust is an effective agent for the extinction of sunlight; this factor can be overwhelmingly apparent in eclipse observations.) O’Keefe died in 2000 and the speculation was not pursued, but the idea of an Earth ring has a prima facie reasonableness that calls for its renewed consideration. The program of this note is to hypothesize that, as O’Keefe proposed: (a) an Earth ring system exists; (b) it affects Earth's weather and climate; (c) the tektite strewn fields comprise filaments of the ring fallen to Earth's surface on various occasions of disturbance by comets or asteroids. On this basis, and drawing on the world's weather records, together with the Twentieth Century Reanalysis by NCEP/CIRES covering the period 1870-2010 and the geology of the tektite strewn fields, we herein propose the hypothesized Earth ring system’s orbital elements and structure. Our work concludes that rings may exist in Earth’s equatorial plane and in the plane of the lunar orbit, that such rings are filamentary structures comprising segments of geologically homogeneous material flung into earth’s orbit at distinct periods of lunar volcanism, and that earth’s weather may indeed be very strongly affected by the rings. In closing, until the time of the lunar landing in 1969, the moon was considered geologically dead. But today, we have multiple lines of evidence that the Moon is still volcanically active. According to our study, this volcanism may affect weather and climate considerably. If lunar volcanism and weather on Earth are linked, then a satisfactory understanding of lunar volcanism is called for by considerations of human welfare. The subsistence farmer has an immediate need to know what is true about our Moon; food security depends on it.

  16. Recalibration of the Palaeocene-Eocene boundary (P-E) using high precision U-Pb and Ar-Ar isotopic dating

    NASA Astrophysics Data System (ADS)

    Chambers, L.; Pringle, M.; Fitton, G.; Larsen, L. M.; Pedersen, A. K.; Parrish, R.

    2003-04-01

    In the current time scales (Cande and Kent, 95; Berggren et al, 95) the P-E Boundary is positioned at 55 Ma based primarily on the age of the -17 ash layer in Denmark. In the absence of a global stratigraphic section and point the boundary is an interval of 1 m.y. from 55.5 to 54.5 Ma that includes all of the different means of calibrating the boundary tie point, including the NP9/NP10 calcareous nannofossil zonal boundary, the planktonic foraminiferal P5/P6a zonal boundary, preliminary ages for the -17 and +19 ash layers (unpub.), the base of the London Clay Formation, and the δ13C spike. Here we present new Ar-Ar ages for the -17 and +19 ash layers in Denmark and combine this study with a calibration of the Ar-Ar with the U-Pb method. As Ar-Ar ages are relative to the known age of a standard or monitor, U-Pb ages on zircons from the same rocks from the British Tertiary Igneous Province provide an absolute age calibration for all of our Ar-Ar ages (including the monitors). An additional complication arises because the time scale is currently being revised (J. Ogg, Pers. Comm.). In the new time scale the P-E boundary will stay at 55 Ma and the K-T boundary will move by 0.5 m.y. to 65.5 Ma. Our results have a direct impact on the positioning of the P-E Boundary relative to the K-T boundary as definitive K-T tektite is used as one of our Ar-Ar standards. Ar-Ar ages and U-Pb ages for the same sample from the BTIP are indistinguishable when the ages used for the Ar-Ar monitor minerals are those recommended in Renne et al (98). This means that the K-T tektite is 65.78 ± 0.03 Ma, the -17 ash is 54.52 ± 0.05Ma, and the +19 ash is 54.04 ± 0.14 Ma. If the P-E boundary is taken to be between the -17 and +19 ash layers, as in DSDP Hole 550 (the ashes bracket the planktonic foraminiferal P5/P6a zonal boundary) then the current position at 55 Ma is too old. We therefore suggest that if the K-T boundary moves to 65.5 Ma, then the P-E boundary should not stay at 55 Ma, but move to 54.5 Ma (extending the Palaeocene by 1 m.y.). If the K-T boundary does not move by 0.5 m.y. then the P-E boundary would still have to move from its current position at 55 Ma and the ages used for the argon monitor minerals revised.

  17. Zhamanshin astrobleme provides evidence for carbonaceous chondrite and post-impact exchange between ejecta and Earth's atmosphere.

    PubMed

    Magna, Tomáš; Žák, Karel; Pack, Andreas; Moynier, Frédéric; Mougel, Bérengère; Peters, Stefan; Skála, Roman; Jonášová, Šárka; Mizera, Jiří; Řanda, Zdeněk

    2017-08-09

    Chemical fingerprints of impacts are usually compromised by extreme conditions in the impact plume, and the contribution of projectile matter to impactites does not often exceed a fraction of per cent. Here we use chromium and oxygen isotopes to identify the impactor and impact-plume processes for Zhamanshin astrobleme, Kazakhstan. ε 54 Cr values up to 1.54 in irghizites, part of the fallback ejecta, represent the 54 Cr-rich extremity of the Solar System range and suggest a CI-like chondrite impactor. Δ 17 O values as low as -0.22‰ in irghizites, however, are incompatible with a CI-like impactor. We suggest that the observed 17 O depletion in irghizites relative to the terrestrial range is caused by partial isotope exchange with atmospheric oxygen (Δ 17 O = -0.47‰) following material ejection. In contrast, combined Δ 17 O-ε 54 Cr data for central European tektites (distal ejecta) fall into the terrestrial range and neither impactor fingerprint nor oxygen isotope exchange with the atmosphere are indicated.Identifying the original impactor from craters remains challenging. Here, the authors use chromium and oxygen isotopes to indicate that the Zhamanshin astrobleme impactor was a carbonaceous chrondrite by demonstrating that depleted 17O values are due to exchange with atmospheric oxygen.

  18. Role of reef fauna in sediment transport and distribution - Studies from Tektite I and II

    USGS Publications Warehouse

    Clifton, H.E.

    1973-01-01

    1. Reef organisms may play a major role in the transport and distribution of sediment on the sea floor adjacent to coral reefs. 2. Some fish such as Malacanthus plumieri (Bloch) selectively transport and collect certain types of sediment (such as larger coral and shell fragments). 3. The random movement of crawling or burrowing organisms may cause a large amount of sediment to be shifted laterally on the sea floor. On slopes, a net downhill displacement may result. 4. The surface configuration and internal structure of the sediment is rapidly changed by faunal mixing. Ripple marks formed by waves or currents are obliterated by the activity of organisms in only a few weeks in the environment studied. Internal structure (bedding) near the sediment-water interface is similarly destroyed in a short period of time. 5. Larger clasts (including empty shells) on the sea floor tend to be buried by faunal undermining. The rate of burial depends primarily on the grain size of the substrate. 6. The random movement of fauna on the sea floor may produce a predominantly concave-up orientation of pelecypod shells and shell fragments on the sea floor - the opposite of that produced by the activity of waves or currents. ?? 1973 Biologischen Anstalt Helgoland.

  19. Proximal impact deposits at the Cretaceous-Tertiary boundary in the Gulf of Mexico: a restudy of DSDP Leg 77 Sites 536 and 540

    NASA Technical Reports Server (NTRS)

    Alvarez, W.; Smit, J.; Lowrie, W.; Asaro, F.; Margolis, S. V.; Claeys, P.; Kastner, M.; Hildebrand, A. R.

    1992-01-01

    Restudy of Deep Sea Drilling Project Sites 536 and 540 in the southeast Gulf of Mexico gives evidence for a giant wave at Cretaceous-Tertiary boundary time. Five units are recognized: (1) Cenomanian limestone underlies a hiatus in which the five highest Cretaceous stages are missing, possibly because of catastrophic K-T erosion. (2) Pebbly mudstone, 45 m thick, represents a submarine landslide possibly of K-T age. (3) Current-bedded sandstone, more than 2.5 m thick, contains anomalous iridium, tektite glass, and shocked quartz; it is interpreted as ejecta from a nearby impact crater, reworked on the deep-sea floor by the resulting tsunami. (4) A 50-cm interval of calcareous mudstone containing small Cretaceous planktic foraminifera and the Ir peak is interpreted as the silt-size fraction of the Cretaceous material suspended by the impact-generated wave. (5) Calcareous mudstone with basal Tertiary forams and the uppermost tail of the Ir anomaly overlies the disturbed interval, dating the impact and wave event as K-T boundary age. Like Beloc in Haiti and Mimbral in Mexico, Sites 536 and 540 are consistent with a large K-T age impact at the nearby Chicxulub crater.

  20. Synchroneity of the K-T oceanic mass extinction and meteorite impact: Blake Nose, western North Atlantic

    USGS Publications Warehouse

    Norris, R.D.; Huber, B.T.; Self-Trail, J.

    1999-01-01

    A 10-cm-thick layer of green spherules occurs precisely at the biostratigraphic boundary between the Cretaceous and Paleogene (K-T boundary) at Ocean Drilling Program Site 1049 (lat 30??08???N, long 76??06???W). The spherulitic layer contains abundant rock fragments (chalk, limestone, dolomite, chert, mica books, and schist) as well as shocked quartz, abundant large Cretaceous planktic foraminifera, and rounded clasts of clay as long as 4 mm interpreted as altered tektite glass probably derived from the Chicxulub impact structure. Most of the Cretaceous foraminifera present above the spherule layer are not survivors since small specimens are conspicuously rare compared to large individuals. Instead, the Cretaceous taxa in Paleocene sediments are thought to be reworked. The first Paleocene planktic foraminifera and calcareous nannofossil species are recorded immediately above the spherule bed, the upper part of which contains an iridium anomaly. Hence, deposition of the impact ejecta exactly coincided with the biostratigraphic K-T boundary and demonstrates that the impact event was synchronous with the evolutionary turnover in the oceans. These results are consistent with a reanalysis of the biostratigraphy of the K-T boundary stratotype, which argues that shallow-marine K-T boundary sections are not biostratigraphically more complete than deep-sea K-T boundary sites.

  1. The debate over the Cretaceous-Tertiary boundary

    NASA Technical Reports Server (NTRS)

    Alvarez, W.; Asaro, F.; Alvarez, L. W.; Michel, H. V.

    1988-01-01

    Large-body impact on the Earth is a rare but indisputable geologic process. The impact rate is approximately known from objects discovered in Earth-crossing orbits and from the statistics of craters on the Earth's surface. Tektite and microtektite strewn fields constitute unmistakable ejecta deposits that can be due only to large-body impacts. The Cretaceous-Tertiary (K-T) boundary coincides with an unusually severe biological trauma, and this stratigraphic horizon is marked on a worldwide basis by anomalous concentrations of noble metals in chondritic proportions, mineral spherules with relict quench-crystallization textures, and mineral and rock grains showing shock deformation. These features are precisely compatible with an impact origin. Although only impact explains all the types of K-T boundary evidence, the story may not be as simple as once thought. The original hypothesis envisioned one large impact, triggering one great extinction. Newer evidence hints at various complications. Different challenges are faced by the occupants of each apex of a three-cornered argument over the K-T event. Proponents of a non-impact explanation must show that the evidence fits their preferred model better than it fits the impact scenario. Proponents of the single impact-single extinction view must explain away the complications. Proponents of a more complex impact crisis must develop a reasonable scenario which honors the new evidence.

  2. Copper Diffusion in Silicate Melts and Melt Inclusion Study on Volatiles in The Lunar Interior

    NASA Astrophysics Data System (ADS)

    Ni, Peng

    This thesis focuses on the application of diffusion kinetics to both terrestrial and lunar geochemistry. In Chapters II and III, diffusivities of Cu in silicate melts were experimentally determined and used to discuss the role of Cu diffusion in formation of Cu ore deposits and also Cu isotope fractionation in tektites. In Chapters IV and V, lunar olivine-hosted melt inclusions are studied to understand their volatile loss during homogenization in lab, to estimate cooling rate for lunar Apollo sample 74220, and to estimate volatile abundance in the lunar mantle. Magmatic sulfide deposits and porphyry-type Cu deposits are two major types of Cu deposits that supply the world's Cu. In particular, porphyry-type Cu deposits provide ˜57% of the world's total discovered Cu. Recent studies suggest a potential role of diffusive transport of metals (e.g. Cu, Au, PGE, Mo) in the formation of magmatic sulfide deposits and porphyry-type deposits. Diffusivities of Cu in silicate melts, however, are poorly determined. In Chapters II and III of this thesis, Cu diffusion in basaltic melt and rhyolitic melts are studied by diffusion couple and chalcocite "dissolution" methods. Our results indicate high diffusivities of Cu and a general equation for Cu diffusion in silicate melts is obtained. The high diffusivity of Cu indicate that partition of Cu between the silicate phase and the sulfide or fluid phase can be assumed to be in equilibrium during the formation of magmatic sulfide deposits or porphyry-type deposits. In addition, our Cu diffusion data helps explain why Cu isotopes are more fractionated than Zn isotopes in tektites. Volatile abundances in the lunar mantle have profound implications for the origin of the Moon, which was thought to be bone-dry till about a decade ago, when trace amounts of H2O were detected in various types of lunar samples. In particular, high H2O concentrations comparable to mid-ocean ridge basalts were reported in lunar melt inclusions. There are still uncertainties, however, for lunar melt inclusion studies in at least two aspects. One is whether the low H2O/Ce ratios measured in homogenized crystalline inclusions are affected by the homogenization process. The other is that current estimation of volatile abundances in lunar mantle relies heavily on 74220, which is argued to be a local anomaly by some authors. In order to reach a conclusive answer on volatile abundances in lunar mantle, the above two questions have to be answered. To improve our understanding about these questions, in Chapter IV of this thesis, a series of experiments are carried out to understand possible volatile loss from lunar melt inclusions during homogenization. Our results indicate significant H2O loss from inclusions during homogenization in minutes, whereas loss of F, Cl or S is unlikely a concern under our experimental conditions. The most applicable way to preserve H2O during homogenization is to use large inclusions. In Chapter V of this thesis, volatile, trace and major element data for melt inclusions from 10020, 12040, 15016, 15647 and 74235 are reported. Our new data indicate large variation in H2O/Ce ratios from ˜77 to ˜1 across different lunar samples, which is at least partially due to H2O loss on lunar surface during cooling. In addition, evidences were found in F/Nd and S/Dy ratios that might suggest lunar mantle heterogeneity in terms of its volatile abundances.

  3. DOE Office of Scientific and Technical Information (OSTI.GOV)

    Bonamici, Chloë E.; Kinman, William S.; Fournelle, John H.

    Reprocessed earth material is a glassy nuclear fallout debris from near-surface nuclear tests. A geochemical approach to analysis of glassy fallout is uniquely suited to determine the means of reprocessing and shed light on the mechanisms of fallout formation. An improved understanding of fallout formation is of interest both for its potential to guide post-detonation nuclear forensic investigations and in the context of possible affinities between glassy debris and other glasses generated by high-energy natural events, such as meteorite impacts and lightning strikes. Our study presents a large major-element compositional dataset for glasses within aerodynamic fallout from the Trinity nuclearmore » test (“trinitite”) and a geochemically based analysis of the glass compositional trends. Silica-rich and alkali-rich trinitite glasses show compositions and textures consistent with formation through melting of individual mineral grains—quartz and alkali feldspar, respectively—from the test-site sediment. Furthermore, the volumetrically dominant glass phase—called the CaMgFe glass—shows extreme major-element compositional variability. Compositional trends in the CaMgFe glass are most consistent with formation through volatility-controlled condensation from compositionally heterogeneous plasma. Radioactivity occurs only in CaMgFe glass, indicating that co-condensation of evaporated bulk ground material and trace device material was the main mechanism of radioisotope incorporation into trinitite. CaMgFe trinitite glasses overlap compositionally with basalts, rhyolites, fulgurites, tektites, and microtektites but display greater compositional diversity than all of these naturally formed glasses. Indeed, the most refractory CaMgFe glasses compositionally resemble early solar system condensates—specifically, CAIs.« less

  4. How many upper Eocene microspherule layers: More than we thought

    NASA Technical Reports Server (NTRS)

    Hazel, Joseph E.

    1988-01-01

    The scientific controversy over the origin of upper Eocene tektites, microtektites and other microspherules cannot be logically resolved until it is determined just how many events are involved. The microspherule-bearing beds in marine sediments have been dated using standard biozonal techniques. Although a powerful stratigraphic tool, zonal biostratigraph has its limitations. One is that if an event, such as a microspherule occurrence, is observed to occur in a zone at one locality and then a similar event observed in the same zone at another locality, it still may be unwarranted to conclude that these events exactly correlate. To be in a zone a sample only need be between the fossil events that define the zone boundaries. It is often very difficult to accurately determine where within a zone one might be. Further, the zone defining events do not everywhere occur at the same points in time. That is, the ranges of the defining taxa are not always filled. Thus, the length of time represented by a zone (but not, of course, its chronozone) can vary from place to place. These problems can be offset by use of chronostratigraphic modelling techniques such as Graphic Correlation. This technique was used to build a Cretaceous and Cenozoic model containing fossil, magnetopolarity, and other events. The scale of the model can be demonstrated to be linear with time. This model was used to determine the chronostratigraphic position of upper Eocene microspherule layers.

  5. Impact origin of the Sudbury structure: Evolution of a theory

    NASA Technical Reports Server (NTRS)

    Lowman, Paul D., Jr.

    1992-01-01

    This paper reviews the origin, development, and present status of the widely accepted theory, proposed by Robert S. Dietz in 1962, that the Sudbury structure was formed by meteoritic or asteroidal impact. The impact theory for the origin of the Sudbury structure seems supported by a nearly conclusive body of evidence. However, even assuming an impact origin to be correct, at least three major questions require further study: (1) the original size and shape of the crater, before tectonic deformation and erosion; (2) the source of the melt now forming the Sudbury Igneous Complex; and (3) the degree, if any, to which the Ni-Cu-platinum group elements are meteoritic. The history of the impact theory illustrates several under-appreciated aspects of scientific research: (1) the importance of cross-fertilization between space research and terrestrial geology; (2) the role of the outsider in stimulating thinking by insiders; (3) the value of small science, at least in the initial stages of an investigation, Dietz's first field work having been at his own expense; and (4) the value of analogies (here, between the Sudbury Igneous Complex and the maria), which although incorrect in major aspects, may trigger research on totally new lines. Finally, the Sudbury story illustrates the totally unpredictable and, by implication, unplannable nature of basic research, in that insight to the origin of the world's then-greatest Ni deposit came from the study of tektites and the Moon.

  6. The next decade in geochemistry

    USGS Publications Warehouse

    Ingerson, E.

    1958-01-01

    The purpose, associations, functions; and activities of the Geochmical Society are reviewed briefly. Work on the Colorado Plateau uranium deposits is described as an example of what geochemical research, in conjunction with detailed field work, mineralogical studies, and related techniques can contribute to the understanding of a type of deposit. It is pointed out that not only have these studies given a great deal of information about the origin of the ores, but they have brought about directly a manifold increase in production and reserves of uranium in the United States. Indirectly, they aided the discovery of the tremendous deposits of the Blind River area in Ontario. It is suggested that similar broad cooperative attacks could not only yield comparable results with other types of mineral deposits, such as laterites and Mississippi Valley type lead-zinc deposits, but could also advance our knowledge and understanding of such diverse problems of geology and cosmology as the origin of granites, origin and geologic implications of meteorites (including tektites), origin and search for petroleum, and geochemical relations and interpretations of natural waters. For each of these problems methods of approach are outlined and for some of them, specific projects and correlative problems are mentioned. It is further suggested that the broad cooperative attack needed for most of these problems might be fostered most effectively by a programme comparable to that of the I.G.Y., even though for most types of geochemical research synoptic sampling and observations are not as important as they are for many projects in geophysics. ?? 1958.

  7. Multiple microtektite horizons in upper Eocene marine sediments: No evidence for mass extinctions

    USGS Publications Warehouse

    Keller, G.; D'Hondt, Steven L.; Vallier, T.L.

    1983-01-01

    Microtektites have been recovered from three horizons in eight middle Eocene to middle Oligocene marine sediment sequences. Five of these occurrences are coeval and of latest Eocene age (37.5 to 38.0 million years ago); three are coeval and of early late Eocene age (38.5 to 39.5 million years ago); and three are of middle Oligocene age (31 to 32 million years ago). In addition, rare probable microtektites have been found in sediments with ages of about 36.0 to 36.5 million years. The microtektite horizon at 37.5 to 38.0 million years can be correlated with the North American tektite-strewn field, which has a fission track age (minimum) of 34 to 35 million years and a paleomagnetic age of 37.5 to 38.0 million years. There is no evidence for mass faunal extinctions at any of the microtektite horizons. Many of the distinct faunal changes that occurred in the middle Eocene to middle Oligocene can be related to the formation of the Antarctic ice sheet and the associated cooling phenomena and intensification of bottom currents that led to large-scale dissolution of calcium carbonate and erosion, which created areally extensive hiatuses in the deep-sea sediment records. The occurrence of microtektite horizons of several ages and the lack of evidence for faunal extinctions suggest that the effects of extraterrestrial bolide impacts may be unimportant in the biologic realm during middle Eocene to middle Oligocene time.

  8. A geochemical approach to constraining the formation of glassy fallout debris from nuclear tests

    DOE PAGES

    Bonamici, Chloë E.; Kinman, William S.; Fournelle, John H.; ...

    2016-12-15

    Reprocessed earth material is a glassy nuclear fallout debris from near-surface nuclear tests. A geochemical approach to analysis of glassy fallout is uniquely suited to determine the means of reprocessing and shed light on the mechanisms of fallout formation. An improved understanding of fallout formation is of interest both for its potential to guide post-detonation nuclear forensic investigations and in the context of possible affinities between glassy debris and other glasses generated by high-energy natural events, such as meteorite impacts and lightning strikes. Our study presents a large major-element compositional dataset for glasses within aerodynamic fallout from the Trinity nuclearmore » test (“trinitite”) and a geochemically based analysis of the glass compositional trends. Silica-rich and alkali-rich trinitite glasses show compositions and textures consistent with formation through melting of individual mineral grains—quartz and alkali feldspar, respectively—from the test-site sediment. Furthermore, the volumetrically dominant glass phase—called the CaMgFe glass—shows extreme major-element compositional variability. Compositional trends in the CaMgFe glass are most consistent with formation through volatility-controlled condensation from compositionally heterogeneous plasma. Radioactivity occurs only in CaMgFe glass, indicating that co-condensation of evaporated bulk ground material and trace device material was the main mechanism of radioisotope incorporation into trinitite. CaMgFe trinitite glasses overlap compositionally with basalts, rhyolites, fulgurites, tektites, and microtektites but display greater compositional diversity than all of these naturally formed glasses. Indeed, the most refractory CaMgFe glasses compositionally resemble early solar system condensates—specifically, CAIs.« less

  9. Lunar and Planetary Science XXXV: Impact-Related Deposits

    NASA Technical Reports Server (NTRS)

    2004-01-01

    The session "Impact-Related Deposits" included:Evidence for a Lightning-Strike Origin of the Edeowie Glass; 57Fe M ssbauer Spectroscopy of Fulgurites: Implications for Chemical Reduction; Ca-Metasomatism in Crystalline Target Rocks from the Charlevoix Structure, Quebec, Canada: Evidence for Impact-related Hydrothermal Activity; Magnetic Investigations of Breccia Veins and Basement Rocks from Roter Kamm Crater and Surrounding Region, Namibia; Petrologic Complexities of the Manicouagan Melt Sheet: Implications for 40Ar-39Ar Geochronology; Laser Argon Dating of Melt Breccias from the Siljan Impact Structure, Sweden: Implications for Possible Relationship to Late Devonian Extinction Events; Lunar Impact Crater, India: Occurrence of a Basaltic Suevite?; Age of the Lunar Impact Crater, India: First Results from Fission Track Dating; The Fluidized Chicxulub Ejecta Blanket, Mexico: Implications for Mars; Low Velocity Ejection of Boulders from Small Lunar Craters: Ground Truth for Asteroid Surfaces; Ejecta and Secondary Crater Distributions of Tycho Crater: Effects of an Oblique Impact; Potassium Isotope Systematics of Crystalline Lunar Spherules from Apollo 16; Late Paleocene Spherules from the North Sea: Probable Sea Floor Precipitates: A Silverpit Provenance Unproven; A Lithological Investigation of Marine Strata from the Triassic-Jurassic Boundary Interval, Queen Charlotte Islands, British Columbia, Including a Search for Shocked Quartz; Triassic Cratered Cobbles: Shock Effects or Tectonic Pressure?; Regional Variations of Trace Element Composition Within the Australasian Tektite Strewn Field; Cretaceous-Tertiary Boundary Microtektite-bearing Sands and Tsunami Beds, Alabama Gulf Coastal Plain; Sand Lobes on Stewart Island as Probable Impact-Tsunami Deposits; Distal Impact Ejecta, Uppermost Eocene, Texas Coastal Plain; and Continental Impact Debris in the Eltanin Impact Layer.

  10. A geochemical approach to constraining the formation of glassy fallout debris from nuclear tests

    NASA Astrophysics Data System (ADS)

    Bonamici, Chloë E.; Kinman, William S.; Fournelle, John H.; Zimmer, Mindy M.; Pollington, Anthony D.; Rector, Kirk D.

    2017-01-01

    Glassy nuclear fallout debris from near-surface nuclear tests is fundamentally reprocessed earth material. A geochemical approach to analysis of glassy fallout is uniquely suited to determine the means of reprocessing and shed light on the mechanisms of fallout formation. An improved understanding of fallout formation is of interest both for its potential to guide post-detonation nuclear forensic investigations and in the context of possible affinities between glassy debris and other glasses generated by high-energy natural events, such as meteorite impacts and lightning strikes. This study presents a large major-element compositional dataset for glasses within aerodynamic fallout from the Trinity nuclear test ("trinitite") and a geochemically based analysis of the glass compositional trends. Silica-rich and alkali-rich trinitite glasses show compositions and textures consistent with formation through melting of individual mineral grains—quartz and alkali feldspar, respectively—from the test-site sediment. The volumetrically dominant glass phase—called the CaMgFe glass—shows extreme major-element compositional variability. Compositional trends in the CaMgFe glass are most consistent with formation through volatility-controlled condensation from compositionally heterogeneous plasma. Radioactivity occurs only in CaMgFe glass, indicating that co-condensation of evaporated bulk ground material and trace device material was the main mechanism of radioisotope incorporation into trinitite. CaMgFe trinitite glasses overlap compositionally with basalts, rhyolites, fulgurites, tektites, and microtektites but display greater compositional diversity than all of these naturally formed glasses. Indeed, the most refractory CaMgFe glasses compositionally resemble early solar system condensates—specifically, CAIs.

  11. A high-precision 40Ar/39Ar age for the Nördlinger Ries impact crater, Germany, and implications for the accurate dating of terrestrial impact events

    NASA Astrophysics Data System (ADS)

    Schmieder, Martin; Kennedy, Trudi; Jourdan, Fred; Buchner, Elmar; Reimold, Wolf Uwe

    2018-01-01

    40Ar/39Ar dating of specimens of moldavite, the formation of which is linked to the Ries impact in southern Germany, with a latest-generation ARGUS VI multi-collector mass spectrometer yielded three fully concordant plateau ages with a weighted mean age of 14.808 ± 0.021 Ma (± 0.038 Ma including all external uncertainties; 2σ; MSWD = 0.40, P = 0.67). This new best-estimate age for the Nördlinger Ries is in general agreement with previous 40Ar/39Ar results for moldavites, but constitutes a significantly improved precision with respect to the formation age of the distal Ries-produced tektites. Separates of impact glass from proximal Ries ejecta (suevite glass from three different surface outcrops) and partially melted feldspar particles from impact melt rock of the SUBO 18 Enkingen drill core failed to produce meaningful ages. These glasses show evidence for excess 40Ar introduction, which may have been incurred during interaction with hydrothermal fluids. Only partially reset 40Ar/39Ar ages could be determined for the feldspathic melt separates from the Enkingen core. The new 40Ar/39Ar results for the Ries impact structure constrain the duration of crater cooling, during the prevailing hydrothermal activity, to locally at least ∼60 kyr. With respect to the dating of terrestrial impact events, this paper briefly discusses a number of potential issues and effects that may be the cause for seemingly precise, but on a kyr-scale inaccurate, impact ages.

  12. Centimeter to decimeter hollow concretions and voids in Gale Crater sediments, Mars

    NASA Astrophysics Data System (ADS)

    Wiens, Roger C.; Rubin, David M.; Goetz, Walter; Fairén, Alberto G.; Schwenzer, Susanne P.; Johnson, Jeffrey R.; Milliken, Ralph; Clark, Ben; Mangold, Nicolas; Stack, Kathryn M.; Oehler, Dorothy; Rowland, Scott; Chan, Marjorie; Vaniman, David; Maurice, Sylvestre; Gasnault, Olivier; Rapin, William; Schroeder, Susanne; Clegg, Sam; Forni, Olivier; Blaney, Diana; Cousin, Agnes; Payré, Valerie; Fabre, Cecile; Nachon, Marion; Le Mouelic, Stephane; Sautter, Violaine; Johnstone, Stephen; Calef, Fred; Vasavada, Ashwin R.; Grotzinger, John P.

    2017-06-01

    Voids and hollow spheroids between ∼1 and 23 cm in diameter occur at several locations along the traverse of the Curiosity rover in Gale crater, Mars. These hollow spherical features are significantly different from anything observed in previous landed missions. The voids appear in dark-toned, rough-textured outcrops, most notably at Point Lake (sols 302-305) and Twin Cairns Island (sol 343). Point Lake displays both voids and cemented spheroids in close proximity; other locations show one or the other form. The spheroids have 1-4 mm thick walls and appear relatively dark-toned in all cases, some with a reddish hue. Only one hollow spheroid (Winnipesaukee, sol 653) was analyzed for composition, appearing mafic (Fe-rich), in contrast to the relatively felsic host rock. The interior surface of the spheroid appears to have a similar composition to the exterior with the possible exceptions of being more hydrated and slightly depleted in Fe and K. Origins of the spheroids as Martian tektites or volcanic bombs appear unlikely due to their hollow and relatively fragile nature and the absence of in-place clearly igneous rocks. A more likely explanation to both the voids and the hollow spheroids is reaction of reduced iron with oxidizing groundwater followed by some re-precipitation as cemented rind concretions at a chemical reaction front. Although some terrestrial concretion analogs are produced from a precursor siderite or pyrite, diagenetic minerals could also be direct precipitates for other terrestrial concretions. The Gale sediments differ from terrestrial sandstones in their high initial iron content, perhaps facilitating a higher occurrence of such diagenetic reactions.

  13. 10Be Content in Suevite Breccia from the Bosumtwi Impact Crater

    NASA Astrophysics Data System (ADS)

    Losiak, Anna; Wild, Eva Maria; Michlmayr, Leonard; Koeberl, Christian

    2013-04-01

    Introduction: According to the current understanding of meteorite impact processes, surface target material is transported from a crater in the form of ejecta or is vaporized/melted (e.g., [1]). The formation model of tektites from the surface of the target rocks has been established using the 10Be content of tektites (e.g., [2]), and chemical comparison with the possible target surface material (e.g., [3]); it was also reproduced by computer modeling (e.g., [4]). On the other hand, some observations ([5, 6]) suggest that part of the surface material may be incorporated into the crater-fill. The aim of this study is to check if surface-derived material is present in suevitic breccias to better understand formation mechanisms of fallback breccias. Also, 10Be can be used to trace contamination of rocks in the top layer of the suevitic layer by meteoric (lake) water. This abstract is an update (based on more data now available) of the previous report presented during the Metsoc75 conference. Samples: The Bosumtwi crater was chosen as study site because of its relatively large size (10.5 km in diameter), young age of 1.07 Ma [7], good state of preservation, and availability of core samples. Clasts from suevitic breccia selected for this study come from the LB-07A and LB-08A cores that are located within the crater and represent fallback breccia (e.g., [7]). Of 41 analyzed samples (22 single clasts and 21 matrix samples - 11 of those being monomictic breccia), 36 came from core LB-07A (in the zone outside the central uplift) and represent depths of 333.7 - 407.9 m and 5 are from core LB-08A (on the flank of the central uplift) from depths 239.5 - 264.9 m. Methods: For each sample, 0.8 g of finely grounded material from clasts containing in situ produced and meteoric 10Be was dissolved in a mixture of HF and HNO3 by microwave digestion. A 9Be carrier (1 mg or 0.6 mg, 10Be/9Be ratio: 2.82±0.31*10-15 [2? uncertainty]) was added to the sample, and then Be was chemically separated from the sample solution. 10Be/9Be ratios were measured at the Vienna Environmental Research Accelerator Facility (VERA) at the University of Vienna. Results: Most samples have 10Be/9Be ratios indistinguishable from the blank value within 2? uncertainty. Samples located just below the boundary between impactites and lake deposits have slightly elevated (1 ? significant) 10Be/9Be ratios. Discussion: The data suggest that none of the analyzed samples present in the suevitic breccia of the Bosumtwi crater come from the surficial layer (0-20 m) of the target. A very small amount of the 10Be present in the layer directly underneath the lake sediments suggests that those two deposits were very efficiently separated from each other. Possibly, this separation was caused by the uppermost impact fallback layer described by Koeberl et al. (2007). Acknowledgment: Supported by University of Vienna doctoral school IK-1045 (Planetology). References: [1] Melosh H.J. 1988. Impact Cratering, Oxford University Press, 256 pp.. [2] Serefiddin F. et al. 2007. Geochimica et Cosmochimica Acta 71: 1574-1582. [3] Son T.H. and Koeberl C. 2007. GFF 29: 161-176. [4] Artemieva N.A. 2000. In: Impacts in Precambrian Shields, Springer, pp. 257-276. [5] Puura V. et al. 2004. Meteoritics & Planetary Science 39: 425-451. [6] Reimold W.U., et al. 1992. Geology 20:1079-1082. [7] Koeberl C. et al. 2007. Meteoritics & Planetary Science 42: 483-511. [8] Koeberl C. et al. 2007. Meteoritics & Planetary Science 42: 709-729.

  14. Centimeter to decimeter hollow concretions and voids in Gale Crater sediments, Mars

    DOE PAGES

    Wiens, Roger C.; Rubin, David M.; Goetz, Walter; ...

    2017-02-21

    Voids and hollow spheroids between ~1 and 23 cm in diameter occur at several locations along the traverse of the Curiosity rover in Gale crater, Mars. These hollow spherical features are significantly different from anything observed in previous landed missions. The voids appear in dark-toned, rough-textured outcrops, most notably at Point Lake (sols 302–305) and Twin Cairns Island (sol 343). Point Lake displays both voids and cemented spheroids in close proximity; other locations show one or the other form. The spheroids have 1–4 mm thick walls and appear relatively dark-toned in all cases, some with a reddish hue. Only onemore » hollow spheroid (Winnipesaukee, sol 653) was analyzed for composition, appearing mafic (Fe-rich), in contrast to the relatively felsic host rock. The interior surface of the spheroid appears to have a similar composition to the exterior with the possible exceptions of being more hydrated and slightly depleted in Fe and K. The origins of the spheroids as Martian tektites or volcanic bombs appear unlikely due to their hollow and relatively fragile nature and the absence of in-place clearly igneous rocks. A more likely explanation to both the voids and the hollow spheroids is reaction of reduced iron with oxidizing groundwater followed by some re-precipitation as cemented rind concretions at a chemical reaction front. Though some terrestrial concretion analogs are produced from a precursor siderite or pyrite, diagenetic minerals could also be direct precipitates for other terrestrial concretions. The Gale sediments differ from terrestrial sandstones in their high initial iron content, perhaps facilitating a higher occurrence of such diagenetic reactions.« less

  15. Hydrocode modeling of the spallation process during hypervelocity impacts: Implications for the ejection of Martian meteorites

    NASA Astrophysics Data System (ADS)

    Kurosawa, Kosuke; Okamoto, Takaya; Genda, Hidenori

    2018-02-01

    Hypervelocity ejection of material by impact spallation is considered a plausible mechanism for material exchange between two planetary bodies. We have modeled the spallation process during vertical impacts over a range of impact velocities from 6 to 21 km/s using both grid- and particle-based hydrocode models. The Tillotson equations of state, which are able to treat the nonlinear dependence of density on pressure and thermal pressure in strongly shocked matter, were used to study the hydrodynamic-thermodynamic response after impacts. The effects of material strength and gravitational acceleration were not considered. A two-dimensional time-dependent pressure field within a 1.5-fold projectile radius from the impact point was investigated in cylindrical coordinates to address the generation of spalled material. A resolution test was also performed to reject ejected materials with peak pressures that were too low due to artificial viscosity. The relationship between ejection velocity veject and peak pressure Ppeak was also derived. Our approach shows that "late-stage acceleration" in an ejecta curtain occurs due to the compressible nature of the ejecta, resulting in an ejection velocity that can be higher than the ideal maximum of the resultant particle velocity after passage of a shock wave. We also calculate the ejecta mass that can escape from a planet like Mars (i.e., veject > 5 km/s) that matches the petrographic constraints from Martian meteorites, and which occurs when Ppeak = 30-50 GPa. Although the mass of such ejecta is limited to 0.1-1 wt% of the projectile mass in vertical impacts, this is sufficient for spallation to have been a plausible mechanism for the ejection of Martian meteorites. Finally, we propose that impact spallation is a plausible mechanism for the generation of tektites.

  16. Magnetic microspherules associated with the K/T and upper Eocene extinction events

    NASA Technical Reports Server (NTRS)

    Cisowski, Stanley M.

    1988-01-01

    Magnetic microspherules were identified in over 20 K/T boundary sites, and in numerous Deep Sea Drilling Project (DSDP) cores from the Caribbean and Pacific, synchronous with the extinction of several radiolarian species near the end of the Eocene. The K/T magnetic spherules are of particular interest as carriers of Ir and other siderophiles generally found in abundance in K/T boundary clay. Furthermore the textures and unusual chemistry of their component magnetic phases indicate an origin at high temperature, possibly related to (an) unusual event(s) marking the end of the Cretaceous and Eocene periods. Their origin, along with the non-magnetic (sanidine) spheules, is generally ascribed directly to megaimpact events hypothesized to have periodically disrupted life on Earth. A survey of microspherical forms associated with known meteorite and impact derived materials reveals fundamental differences from the extinction related spherules. Low temperature magnetic experiments on the K/T and Upper Eocene spheroids indicate that, unlike tektites, extremely small superparamagnetic carriers are not present in abundance. The extensive subaerial exposure of Cretaceous combustible black shale during sea level regression in the latest Cretaceous represents a potential source for the magnetic spheroids found in certain K/T boundary clays. The recent discovery of high Ir abundances distributed above and below the K/T boundary within shallow water sediments in Israel, which also contain the most extensive known zones of combustion metamorphism, the so called Mottled Zone, adds a further dramatic footnote to the proposed association between the magnetic spheroids and combustion of organic shales. Interestingly, the Mottled Zone also contains the rare mineral magnesioferrite, which was identified both within the K/T magnetic spheroids and as discrete crystals in boundary clay from marine and continental sites.

  17. New links between the Chicxulub impact structure and the Cretaceous/Tertiary boundary

    USGS Publications Warehouse

    Sharpton, V.L.; Dalrymple, G.B.; Marin, L.E.; Ryder, G.; Schuraytz, B.C.; Urrutia-Fucugauchi, J.

    1992-01-01

    THE 200-km-diameter Chicxulub structure1-3 in northern Yucatan, Mexico has emerged as the prime candidate for the Cretaceous/Tertiary (K/T) boundary impact crater3-6. Concentric geophysical anomalies associated with enigmatic occurrences of Upper Cretaceous breccias and andesitic rocks led Penfield and Camargo1 to suspect that this structure was a buried impact basin. More recently, the discovery of shocked quartz grains in a Chicxulub breccia3, and chemical similarities between Chicxulub rocks and K/T tektite-like glasses3-6 have been advanced as evidence that the Chicxulub structure is a K/T impact site. Here we present evidence from core samples that Chicxulub is indeed a K/T source crater, and can apparently account for all the evidence of impact distributed globally at the K/T boundary without the need for simultaneous multiple impacts or comet showers. Shocked breccia clasts found in the cores are similar to shocked lithic fragments found worldwide in the K/T boundary ejecta layer7,8. The Chicxulub melt rocks that we studied contain anomalously high levels of iridium (up to 13.5 parts per 109), also consistent with the indium-enriched K/T boundary layer9. Our best estimate of the crystallization age of these melt rocks, as determined by 40Ar/39Ar analyses, is 65.2??0.4 (1??) Myr, in good agreement with the mean plateau age of 64.98 ?? 0.05 Myr recently reported10. Furthermore, these melt rocks acquired a remanent magnetization indicating that they cooled during an episode of reversed geomagnetic polarity. The only such episode consistent with 40Ar/39Ar constraints is chron 29R, which includes the K/T boundary.

  18. Centimeter to decimeter hollow concretions and voids in Gale Crater sediments, Mars

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Wiens, Roger C.; Rubin, David M.; Goetz, Walter

    Voids and hollow spheroids between ~1 and 23 cm in diameter occur at several locations along the traverse of the Curiosity rover in Gale crater, Mars. These hollow spherical features are significantly different from anything observed in previous landed missions. The voids appear in dark-toned, rough-textured outcrops, most notably at Point Lake (sols 302–305) and Twin Cairns Island (sol 343). Point Lake displays both voids and cemented spheroids in close proximity; other locations show one or the other form. The spheroids have 1–4 mm thick walls and appear relatively dark-toned in all cases, some with a reddish hue. Only onemore » hollow spheroid (Winnipesaukee, sol 653) was analyzed for composition, appearing mafic (Fe-rich), in contrast to the relatively felsic host rock. The interior surface of the spheroid appears to have a similar composition to the exterior with the possible exceptions of being more hydrated and slightly depleted in Fe and K. The origins of the spheroids as Martian tektites or volcanic bombs appear unlikely due to their hollow and relatively fragile nature and the absence of in-place clearly igneous rocks. A more likely explanation to both the voids and the hollow spheroids is reaction of reduced iron with oxidizing groundwater followed by some re-precipitation as cemented rind concretions at a chemical reaction front. Though some terrestrial concretion analogs are produced from a precursor siderite or pyrite, diagenetic minerals could also be direct precipitates for other terrestrial concretions. The Gale sediments differ from terrestrial sandstones in their high initial iron content, perhaps facilitating a higher occurrence of such diagenetic reactions.« less

  19. Evidences of melting of terrestrial sediments and paleoenvironment changes during the Younger Dryas in tectonic lacustrine basins of Transmexican Volcanic Belt, Mexico.

    NASA Astrophysics Data System (ADS)

    Israde-Alcantara, I.

    2017-12-01

    It is well known in the sedimentary record of several parts of the world that during the Younger Dryas interval (YD) ocurred an abrupt environmental change between 12,900 and 11,700 cal yr BP (10,900 to 10,000 14C BP). In the lacustrine basins this changes are often preserved and in some Mexican lakes this is a distinctive stratigraphic marker for the YD. We analized the proxies of this event in cores of two lakes (Chapala, Cuitzeo) and three trenches of ex-lakes (Acambay,Texcoco and El Cedral). Deposits consist of fine detrital material with often Pleistocene fossil vertebrate assemblages. At the Chapala, Cuitzeo, Acambay, and Tocuila lacustrine environments are found in association with a distinctive dark organic layer showing sharp changes in the diatom, pollen, mineralogical and geochemical record. Includes also microscopic magnetic, Fe-rich spherules, silica melted droplets with aerodynamic shapes (tektites), followed by large amounts of charcoal, and sometimes nanodiamonds (Cuitzeo), that were deposited at the onset of the YD or in the limit Pleistocene-Holocene. These unusual materials are buried more than 2.50 meters and were not observed above or below the Younger Dryas sediments at these sites. The geochemistry of the microspherules indicates that they are not volcanic, anthropogenic or authigenic origin. A very distinctive feature is the shape of the spherules, ovoid, polygonal, filigreed or dendritic indicating melting and quenching infering that are product of an impact event. Their morphologies includes hollow shells caused by de-gassing of elements at very high temperatures causing a flattened side with a "skirt" structure by a high-velocity collision.Our results are consistent with the Firestone hypothesis.

  20. Disturbing the solar system. Impacts, close encounters, and coming attractions

    NASA Astrophysics Data System (ADS)

    Rubin, Alan E.

    The solar system is not akin to a well-oiled machine whose parts move smartly along prescribed paths. It has always been - and continues to be - a messy place in which gravity wreaks havoc. Moons form, asteroids and comets crash into planets, ice ages commence, and dinosaurs disappear. By describing the dramatic consequences of such disturbances, this fascinating book reveals the fundamental interconnectedness of the solar system - and what it means for life on its most interesting planet. After relating a brief history of the solar system, Alan Rubin describes how astronomers determined our location in the Milky Way. He provides succinct and up-to-date accounts of the energetic interactions among planetary bodies, the generation of the Earth's magnetic field, the effects of other solar-system objects on our climate, the moon's genesis, the heating of asteroids, and the origin of the mysterious tektites. Along the way, Rubin introduces us to the individual scientists - including the famous, the now obscure, and the newest generation of researchers - who have enhanced our understanding of the galactic neighborhood. He shows how scientific discoveries are made; he discusses the uncertainty that presides over the boundaries of knowledge as well as the occasional reluctance of scientists to change their minds even when confronted by compelling evidence. This fresh historical perspective reveals science as it is: an imperfect but self-correcting enterprise. Journeying to the frontiers of knowledge, Rubin concludes with the exciting realm of astrobiology. He chronicles the history of the search for life on Mars and describes cutting-edge lines of astrobiological inquiry, including panspermia (the possible transfer of life from planet to planet), the likelihood of technologically advanced alien civilizations in our galaxy, and our probable responses to alien contact.

  1. 1992 WAMET/EUROMET Joint Expedition to Search for Meteorites in the Nullarbor Region, Western Australia

    NASA Astrophysics Data System (ADS)

    Bevan, A.

    1992-07-01

    The Nullarbor Region is a limestone desert in the south of Australia. It forms part of the larger Eucla Basin, which straddles the border between South Australia and Western Australia. The portion of the Eucla Basin lying in Westem Australia covers an area of about 104,000 km^2 (Bevan and Binns, 1989) and meteorites have been recovered from this region since 1971, new material being deposited at the Western Australia Museum. Between 21/3/92 and 6/4/92 a joint expedition between the Western Australia Museum and EUROMET recovered approximately 440 specimens of meteorites (total mass 13206 g) and 297 tektites. The expedition, whose members were Claude Perron (Paris), Christian Koeberl (Vienna), Georg Delisle (BGR Hannover), Gian- Paolo Sighinolfi (Modena), and Andrew Morse (OU) for Euromet, together with Wayne Smith (Australian Army) and Tom Smith (Perth Astronomical Observatory), was led by Dr Alex Bevan of the Western Australia Museum. Searching was carried out on foot with the participants spread out in a line with a 10-m spacing, walking along a compass bearing for approximately 10 km and back each day. Eight collecting regions were used, with a stop of about 2 days at each camp. Half of the searching was done near known strewn fields in order that the team become practised. Thus the expedition collected material at the following known sites. Camel Donga, Eucrite: The initial recovery was made in 1984 (Cleverly et al., 1986). The strewn field is about 8 km by 2-3 km at coordinates 30 degrees 19'S, 126 degrees 37'E. This expedition recovered 65 stones weighing a total of 2456 g, plus one stone of 4.8 g that was clearly chondritic in hand specimen. Mulga (north), H6: The initial recovery was made in 1964 (McCall, 1968). The strewn field is 8 km by 2 km at coordinates 30 degrees 11'S, 126 degrees 22'E and on this expedition 5 stones were recovered with a weight of 548 g. Also 110 stones (total mass 1535 g) that are certainly not H6 were found within a 100-m radius of coordinates 30 degrees 10'S, 126 degrees 24'E but could be paired with Billygoat Donga, an L6 ordinary chondrite (McCall and Cleverly, 1968). Three other specimens may possibly be part of the Mulga (west) or Mulga (south) strewn fields, or may be new meteorites. Mundrabilla, Anomalous Iron (de Laeter, 1972): 171 fragments were found, weighing a total of 7450 g in the vicinity of coordinates 30 degrees 46'S, 127 degrees 50'E. Eighty five other meteorite specimens were recovered from previously unsearched locations with a total weight of 1217 g. As no concentration/movement mechanism is involved, pairing is much easier than for the Antarctic and from a total of 89 new stones various estimates suggest between 20-40 new meteorites. The Nullarbor Region has proved to be a prolific collecting region and with the specimens collected in this expedition, is second only to Antarctica in terms of productivity for the recovery of meteorites. At present, all the specimens recovered, excluding tektites, are on loan from the Western Australian Museum to EUROMET and are held at the curatorial facility at The Open University for purposes of classification. Forty of the most promising stones are being prepared as PTSs, hopefully in time for identification to be announced at the conference. Acknowledgment: EUROMET is supported by the EC through its SCIENCE (Twinning and operations) programme; contract no.: SCI* - CT91- 0618(SSMA). References: Bevan A. W. R. and Binns R. A. (1989) Meteoritics 24, 127-133. Cleverly W. H., Jarosewich E. and Mason B. (1986) Meteoritics 21, 263-269. de Laeter J. R. (1972) Meteoritics 7, 285-294. McCall G. J. H. (1968) First Suppl. West. Austr. Mus. Spec. Publ. 3, 12. McCall G. J. H. and Cleverly W. H. (1968) Mineralog. Mag. 36, 691-716.

  2. Glass corrosion in natural environments

    NASA Technical Reports Server (NTRS)

    Thorpe, Arthur N.; Barkatt, Aaron

    1992-01-01

    Experiments carried out during the progress period are summarized. Experiments carried out involving glass samples exposed to solutions of Tris have shown the appearance of 'spikes' upon monitoring glass dissolution as a function of time. The periodic 'spikes' observed in Tris-based media were interpreted in terms of cracking due to excessive stress in the surface region of the glass. Studies of the interactions of silicate glasses with metal ions in buffered media were extended to systems containing Al. Caps buffer was used to establish the pH. The procedures used are described and the results are given. Preliminary studies were initiated as to the feasibility of adding a slowly dissolving solid compound of the additive to the glass-water system to maintain a supply of dissolved additive. It appears that several magnesium compounds have a suitable combination of solubility and affinity towards silicate glass surfaces to have a pronounced retarding effect on the extraction of uranium from the glass. These preliminary findings raise the possibility that introducing a magnesium source into geologic repositories for nuclear waste glass in the form of a sparingly soluble Mg-based backfill material may cause a substantial reduction in the extent of long-term glass corrosion. The studies described also provide mechanistic understanding of the roles of various metal solutes in the leachant. Such understanding forms the basis for developing long-term predictions of nuclear waste glass durability under repository conditions. From what is known about natural highly reduced glasses such as tektites, it is clear that iron is dissolved as ferrous iron with little or no ferric iron. The reducing conditions were high enough to cause metallic iron to exsolve out of the glass in the form of submicroscopic spherules. As the nuclear waste glass is much less reduced, a study was initiated on other natural glasses in addition to the nuclear waste glass. Extensive measurements were carried out on these glasses in order to characterize their magnetic properties. Results of these studies are described.

  3. Petrified lightning: the role of bubbles in the physical and chemical processes leading to formation of rock fulgurites

    NASA Astrophysics Data System (ADS)

    Chen, J.; Elmi, C.; Goldsby, D. L.; Giere, R.

    2016-12-01

    Fulgurite is a vitrified soil, sand or rock resulting from lightning strikes. The thunderbolt, which can have an energy density of 3.3 ×106 J/m, is associated with air temperatures of up to 30,000 K and a current of up to 10 kA, which can heat the rock to >2000 K within tens of ms. The rapid fusing and subsequent quenching of the surface of the rock leaves a distinctive thin garbled coating comprised of glassy to fine-grained porous material. Similar materials and structures result from atomic bomb tests (trinitite) and from meteorite impacts (tektite). Chemical analysis of rock fulgurite samples on granites collected near Baveno, Italy reveals a glass composition of mainly SiO2 and Al2O3. A porosity of about 10% in the analyzed fulgurite was determined. The presence of newly-formed cristobalite and relict quartz in a relatively chemically homogenous glass matrix indicates induced temperatures >1700 ºC. The residual organic matter in the glass suggests that rapid cooling of the melt trapped NOx and COx gases vaporized during the lightning event. Tiny spheres mainly made of Fe and rich in Si point to reducing conditions. To better understand the formation of the porous glass matrix during intense Joule heating and subsequent rapid cooling, idealized physical models were developed to simulate bubble nucleation and redox reactions inside the bubbles. Preliminary results suggest that a weathered surface layer of higher electrical conductivity than the bulk rock results in strong Joule heating near the surface, facilitating the formation of a dense population of bubbles in the 10 mm-thick glass layer. Experiments to generate fulgurites in the laboratory, with well controlled energy input and sample properties, will aid our understanding of the physics of fulgurite formation and corroborate theoretical models. The results of such experiments, which are underway, will be presented.

  4. Deconvolution of Thermal Emissivity Spectra of Mercury to their Endmember Counterparts measured in Simulated Mercury Surface Conditions

    NASA Astrophysics Data System (ADS)

    Varatharajan, I.; D'Amore, M.; Maturilli, A.; Helbert, J.; Hiesinger, H.

    2017-12-01

    The Mercury Radiometer and Thermal Imaging Spectrometer (MERTIS) payload of ESA/JAXA Bepicolombo mission to Mercury will map the thermal emissivity at wavelength range of 7-14 μm and spatial resolution of 500 m/pixel [1]. Mercury was also imaged at the same wavelength range using the Boston University's Mid-Infrared Spectrometer and Imager (MIRSI) mounted on the NASA Infrared Telescope Facility (IRTF) on Mauna Kea, Hawaii with the minimum spatial coverage of 400-600km/spectra which blends all rocks, minerals, and soil types [2]. Therefore, the study [2] used quantitative deconvolution algorithm developed by [3] for spectral unmixing of this composite thermal emissivity spectrum from telescope to their respective areal fractions of endmember spectra; however, the thermal emissivity of endmembers used in [2] is the inverted reflectance measurements (Kirchhoff's law) of various samples measured at room temperature and pressure. Over a decade, the Planetary Spectroscopy Laboratory (PSL) at the Institute of Planetary Research (PF) at the German Aerospace Center (DLR) facilitates the thermal emissivity measurements under controlled and simulated surface conditions of Mercury by taking emissivity measurements at varying temperatures from 100-500°C under vacuum conditions supporting MERTIS payload. The measured thermal emissivity endmember spectral library therefore includes major silicates such as bytownite, anorthoclase, synthetic glass, olivine, enstatite, nepheline basanite, rocks like komatiite, tektite, Johnson Space Center lunar simulant (1A), and synthetic powdered sulfides which includes MgS, FeS, CaS, CrS, TiS, NaS, and MnS. Using such specialized endmember spectral library created under Mercury's conditions significantly increases the accuracy of the deconvolution model results. In this study, we revisited the available telescope spectra and redeveloped the algorithm by [3] by only choosing the endmember spectral library created at PSL for unbiased model accuracy with the RMS value of 0.03-0.04. Currently, the telescope spectra are investigated for its calibrations and the results will be presented at AGU. References: [1] Hiesinger, H. and J. Helbert (2010) PSS, 58(1-2): 144-165. [2] Sprague, A.L. et al (2009) PSS, 57, 364-383. [3] Ramsey and Christiansen (1998) JGR, 103, 577-596

  5. Monturaqui meteorite impact crater, Chile: A field test of the utility of satellite-based mapping of ejecta at small craters

    NASA Astrophysics Data System (ADS)

    Rathbun, K.; Ukstins, I.; Drop, S.

    2017-12-01

    Monturaqui Crater is a small ( 350 m diameter), simple meteorite impact crater located in the Atacama Desert of northern Chile that was emplaced in Ordovician granite overlain by discontinuous Pliocene ignimbrite. Ejecta deposits are granite and ignimbrite, with lesser amounts of dark impact melt and rare tektites and iron shale. The impact restructured existing drainage systems in the area that have subsequently eroded through the ejecta. Satellite-based mapping and modeling, including a synthesis of photographic satellite imagery and ASTER thermal infrared imagery in ArcGIS, were used to construct a basic geological interpretation of the site with special emphasis on understanding ejecta distribution patterns. This was combined with field-based mapping to construct a high-resolution geologic map of the crater and its ejecta blanket and field check the satellite-based geologic interpretation. The satellite- and modeling-based interpretation suggests a well-preserved crater with an intact, heterogeneous ejecta blanket that has been subjected to moderate erosion. In contrast, field mapping shows that the crater has a heavily-eroded rim and ejecta blanket, and the ejecta is more heterogeneous than previously thought. In addition, the erosion rate at Monturaqui is much higher than erosion rates reported elsewhere in the Atacama Desert. The bulk compositions of the target rocks at Monturaqui are similar and the ejecta deposits are highly heterogeneous, so distinguishing between them with remote sensing is less effective than with direct field observations. In particular, the resolution of available imagery for the site is too low to resolve critical details that are readily apparent in the field on the scale of 10s of cm, and which significantly alter the geologic interpretation. The limiting factors for effective remote interpretation at Monturaqui are its target composition and crater size relative to the resolution of the remote sensing methods employed. This suggests that satellite-based mapping of ejecta may have limited utility at small craters due to limitations in source resolution compared to the geology of the site in question.

  6. The origin of volatile element depletion in early solar system material: Clues from Zn isotopes in chondrules

    NASA Astrophysics Data System (ADS)

    Pringle, Emily A.; Moynier, Frédéric; Beck, Pierre; Paniello, Randal; Hezel, Dominik C.

    2017-06-01

    Volatile lithophile elements are depleted in the different planetary materials to various degrees, but the origin of these depletions is still debated. Stable isotopes of moderately volatile elements such as Zn can be used to understand the origin of volatile element depletions. Samples with significant volatile element depletions, including the Moon and terrestrial tektites, display heavy Zn isotope compositions (i.e. enrichment of 66Zn vs. 64Zn), consistent with kinetic Zn isotope fractionation during evaporation. However, Luck et al. (2005) found a negative correlation between δ66Zn and 1/[Zn] between CI, CM, CO, and CV chondrites, opposite to what would be expected if evaporation caused the Zn abundance variations among chondrite groups. We have analyzed the Zn isotope composition of multiple samples of the major carbonaceous chondrite classes: CI (1), CM (4), CV (2), CO (4), CB (2), CH (2), CK (4), and CK/CR (1). The bulk chondrites define a negative correlation in a plot of δ66Zn vs 1/[Zn], confirming earlier results that Zn abundance variations among carbonaceous chondrites cannot be explained by evaporation. Exceptions are CB and CH chondrites, which display Zn systematics consistent with a collisional formation mechanism that created enrichment in heavy Zn isotopes relative to the trend defined by CI-CK. We further report Zn isotope analyses of chondrite components, including chondrules from Allende (CV3) and Mokoia (CV3), as well as an aliquot of Allende matrix. All chondrules are enriched in light Zn isotopes (∼500 ppm on 66Zn/64Zn) relative to the bulk, contrary to what would be expected if Zn were depleted during evaporation, on the other hand the matrix has a complementary heavy isotope composition. We report sequential leaching experiments in un-equilibrated ordinary chondrites, which show sulfides are isotopically heavy compared to silicates and the bulk meteorite by ca. +0.65 per mil on 66Zn/64Zn. We suggest isotopically heavy sulfides were removed from either chondrules or their precursors, thereby producing the light Zn isotope enrichments in chondrules.

  7. Imaging 50,000 Oriented Ovoid Depressions Using LiDAR Elevation Data Elucidates the Enigmatic Character of The Carolina Bays: Wind & Wave, Or Cosmic Impact Detritus?

    NASA Astrophysics Data System (ADS)

    Davias, M. E.; Harris, T. H. S.

    2017-12-01

    80 years after aerial photography revealed thousands of aligned oval depressions on the USA's Atlantic Coastal Plain, the geomorphology of the "Carolina bays" remains enigmatic. Geologists and astronomers alike hold that invoking a cosmic impact for their genesis is indefensible. Rather, the bays are commonly attributed to gradualistic fluvial, marine and/or aeolian processes operating during the Pleistocene era. The major axis orientations of Carolina bays are noted for varying statistically by latitude, suggesting that, should there be any merit to a cosmic hypothesis, a highly accurate triangulation network and suborbital analysis would yield a locus and allow for identification of a putative impact site. Digital elevation maps using LiDAR technology offer the precision necessary to measure their exquisitely-carved circumferential rims and orientations reliably. To support a comprehensive geospatial survey of Carolina bay landforms (Survey) we generated about a million km2 of false-color hsv-shaded bare-earth topographic maps as KML-JPEG tile sets for visualization on virtual globes. Considering the evidence contained in the Survey, we maintain that interdisciplinary research into a possible cosmic origin should be encouraged. Consensus opinion does hold a cosmic impact accountable for an enigmatic Pleistocene event - the Australasian tektite strewn field - despite the failure of a 60-year search to locate the causal astroblem. Ironically, a cosmic link to the Carolina bays is considered soundly falsified by the identical lack of a causal impact structure. Our conjecture suggests both these events are coeval with a cosmic impact into the Great Lakes area during the Mid-Pleistocene Transition, at 786 ka ± 5 k. All Survey data and imagery produced for the Survey are available on the Internet to support independent research. A table of metrics for 50,000 bays examined for the Survey is available from an on-line Google Fusion Table: https://goo.gl/XTHKC4 . Each bay is also geospatially referenceable through a map containing clickable placemarks that provide information windows displaying that bay's measurements as well as further links which allows visualization of the associated LiDAR imagery and the bay's planform measurement overlay within the Google Earth virtual globe: https://goo.gl/EHR4Lf .

  8. Impact structures in Africa: A review

    PubMed Central

    Reimold, Wolf Uwe; Koeberl, Christian

    2014-01-01

    More than 50 years of space and planetary exploration and concomitant studies of terrestrial impact structures have demonstrated that impact cratering has been a fundamental process – an essential part of planetary evolution – ever since the beginning of accretion and has played a major role in planetary evolution throughout the solar system and beyond. This not only pertains to the development of the planets but to evolution of life as well. The terrestrial impact record represents only a small fraction of the bombardment history that Earth experienced throughout its evolution. While remote sensing investigations of planetary surfaces provide essential information about surface evolution and surface processes, they do not provide the information required for understanding the ultra-high strain rate, high-pressure, and high-temperature impact process. Thus, hands-on investigations of rocks from terrestrial impact craters, shock experimentation for pressure and temperature calibration of impact-related deformation of rocks and minerals, as well as parameter studies pertaining to the physics and chemistry of cratering and ejecta formation and emplacement, and laboratory studies of impact-generated lithologies are mandatory tools. These, together with numerical modeling analysis of impact physics, form the backbone of impact cratering studies. Here, we review the current status of knowledge about impact cratering – and provide a detailed account of the African impact record, which has been expanded vastly since a first overview was published in 1994. No less than 19 confirmed impact structures, and one shatter cone occurrence without related impact crater are now known from Africa. In addition, a number of impact glass, tektite and spherule layer occurrences are known. The 49 sites with proposed, but not yet confirmed, possible impact structures contain at least a considerable number of structures that, from available information, hold the promise to be able to expand the African impact record drastically – provided the political conditions for safe ground-truthing will become available. The fact that 28 structures have also been shown to date NOT to be of impact origin further underpins the strong interest in impact in Africa. We hope that this review stimulates the education of students about impact cratering and the fundamental importance of this process for Earth – both for its biological and geological evolution. This work may provide a reference volume for those workers who would like to search for impact craters and their ejecta in Africa. PMID:27065753

  9. Physical Properties of the Icy Soil at the Phoenix Landing Site

    NASA Astrophysics Data System (ADS)

    Keller, H.; Markiewicz, W. J.; Hviid, S. F.; Goetz, W.; Mellon, M. T.; El Maarry, M.; Madsen, M. B.; Smith, P.; Pike, W.; Zent, A.; Hecht, M. H.; Ming, D.; Staufer, U.

    2008-12-01

    The geomorphological setting of the subpolar terrain at the landing site is characterized by polygonal structures. These structures are generated by long term and periodic cycles of contraction and expansion of the subsurface icy soil. The physical properties of the covering soil layer effectively control the details of this process that has its counterpart on earth in (sub) polar regions including the Siberian tundra and in Antartica. One of the prime science goals of the Phoenix mission is to investigate the physical properties of the icy soil, how these processes are influenced by water vapour diffusion in the regolith and exchange of the water vapour with the atmosphere. It is important to understand these processes on diurnal, seasonal, and climatic time scales. Phoenix landed in the middle of one of the polygons. Its retro rockets cleared the ice table of the polygon underneath the jet assemblies from ca. 5 to 10 cm of loose cloddy regolith. Soil was piled up in the centre. The fact that the soil looked still cloddy similar to that in undisturbed areas suggests strong cohesiveness of the matrix material. The clumps were not destroyed by the blast. Excavated regolith material imaged in the scoop was made up of agglomerates of grains smaller than the best resolution of the Robotic Arm Camera (20 micron). Higher resolution images (4 micron) of the microscope corroborate that the soil is predominantly composed of agglomerates of very small particles with a mean size comparable to those observed in the Martian atmosphere. The Atomic Force Microscope reveals micron sized particles and smaller, partly of plate-like shape, indicating clay like particles. The matrix material of the soil is of reddish colour probably due to iron oxideadmixture. Only about 10% by volume of the soil are most often rounded grains between 40 to 100 micrometers of diameter. Some are glassy resembling micro tektites, and most of these are magnetic. The cohesiveness of the clumps and clods of matrix material is most likely caused by interfacial water, but electrostatic and van der Waals forces could also play a part. The soil also sticks readily to the scoop. Once desiccated in the scoop clumps fall apart further indicating that water was a major agent responsible for the cohesiveness of the soil.

  10. Ties of Heat and Mass Transport Properties in Glasses and Melts, with Emphasis on Natural Lava Compositions

    NASA Astrophysics Data System (ADS)

    Hofmeister, A. M.; Whittington, A. G.; Robert, G.; Sehlke, A.

    2016-12-01

    We have discovered strong ties of mass and heat transport properties in glasses and melts via coordinated measurements of thermal diffusivity (D) and viscosity (η). Over the course of several studies we have compared over 50 remelted natural lavas, tektites, and synthetic glasses and melts, with substantially different chemical compositions, e.g., from 50 to 100% silica, and with slight variations in H and Fe cations and the presence/absence of Al. We use laser flash analysis to obtain D, which avoids contact and radiative errors and constrain η over a wide range of temperature (T). We use a combination of parallel-plate and concentric-cylinder viscometry to obtain η from the glass transition to above the liquidus. Our most recent studies include differential scanning calorimetric measurements of heat capacity (CP) to calculate their thermal conductivity (k), and we are now measuring thermal expansivity using dilatometry. The combined datasets show consistent macroscopic behavior, providing an improved understanding of microscopic behavior, particularly of heat transport properties, which have been misunderstood. Both viscosity and the glass transition temperature decrease with decreasing melt polymerization. Clear correlations exist between D of glass or melt with Si content, density, NBO/T, and, most strongly, with fragility (obtained from η). Glass thermal diffusivity is represented by D = FT-G +HT, where F, G and H are fitting parameters. For melts, D drops upon melting but we could only resolve D/T for a small number of samples. The results show that high-T behavior is controlled by Fe oxidation state and polymerization and involves radiative transfer (HT) but at infrared frequencies. In disordered materials, acoustic scattering is less important to heat transfer than is IR absorption/re-emissions. We find that k for glasses is described by a Maier-Kelly formula, consistent with the T response being dominated by CP. Trends in k are irregular due to k being the convolution of three physical properties. Nonetheless, basaltic melts are constrained to k 1.4±0.1 Wm-1k-1. Low values for thermal diffusivity and viscosity for basaltic melts suggests that basalts transfer heat much more efficiently by advection than by conduction alone, which pertains to upper mantle processes.

  11. YORP: Its origin

    NASA Astrophysics Data System (ADS)

    Paddack, Stephen; Rubincam, David P.

    2015-11-01

    It’s all about photons and their behavior. Yarkovsky (1844-1902) did not have the knowledge we have today about photons and radiation pressure. Nevertheless, he published a pamphlet in 1901 that small rotating celestial bodies could absorb sunlight and reradiate it as heat after a delay, resulting in possible orbital changes, setting the stage for radiation effects in celestial mechanics. Yarkovsly’s work remained obscure until Öpik recalled having read Yarkovsky’s pamphlet. Öpik brought Yarkovsky’s idea to the attention of John A. O’Keefe in the late 1960s. O’Keefe, the mentor for two aspiring PhD students, Paddack and Rubincam, told them about Yarkovsky. In 1968 Paddack postulated that the reflection of sunlight off of small, irregularly shaped celestial bodies could have a significant effect on their spin rates. He referred to this as a windmill effect. Paddack and O’Keefe tested the idea of windmill shapes causing spin by dropping crushed stones with irregular shapes into a swimming pool and watching them twirl. Paddack then mimicked the space environment by placing windmill-shaped artificial objects and tektites in a vacuum chamber on an almost frictionless bearing and spinning them up with a strong source of light, conclusively showing the relation of shape to spin. Earlier in 1954 Radzievskii wrote about the effects radiation pressure on variations in the albedo of small celestial bodies as a means of changing their spin rates. The uniform color of Paddack’s test bodies ruled out Radzievskii’s effect as the cause for the observed spin-up. The Yarkovsky effect was minimized because the test object had a coating of vapor-deposited aluminum with a very high albedo and consequently did not heat up. In 2000 Rubincam applied Paddack’s idea to small asteroids and called it the YORP effect (YORP = Yarkovsky-O’Keefe-Radzievskii-Paddack), to give it a catchy name and sell the idea. In 2007 results were published in Science about the observed behavior of asteroid (54509) 2000 PH5 stating that its spin rate changes because of the YORP effect (Lowery et al and Taylor et al). Since 2000 there have been more than 400 papers and talks with “YORP” in the title or the abstract.

  12. 10Be and relative paleointensity signals across the last geomagnetic reversal

    NASA Astrophysics Data System (ADS)

    Savranskaia, T.; Valet, J. P.; Bassinot, F. C.; Meynadier, L.; Simon, Q.; Bourles, D. L.; Thouveny, N.; Thevarasan, A.; Villedieu, A.; Choy, S.; Gacem, L.

    2017-12-01

    Two techniques can be used to determine the evolution of the geomagnetic field intensity in the past. The first one relies on records of relative paleointensity (RPI) in sediments. Although they remain relatively sparse detailed records of 10Be production (expressed in terms of 10Be/9Be) provide an alternative approach. However integration of 10Be within the sediment is not better understood than the magnetization process, and therefore paleofield studies should greatly benefit from the integration of both datasets. In order to achieve this goal, it is crucial to compare and analyze the signals over a common time period. We selected five sedimentary cores from the Indian, Pacific and Atlantic Oceans and focused on the last reversal which is characterized by the largest intensity changes. Since 10Be is homogenized in the atmosphere, the same amount of 10Be should be recorded everywhere. We found different amounts of 10Be at each site during the last reversal which appear roughly correlated with accumulation rate. In contrast the 10Be amplitude is similar at all locations while higher amplitude signals are expected for low deposition rates. Taking advantage of the distribution of tektites layers, the beryllium signals have been deconvolved, but this procedure did not strikingly change the results. Despite atmospheric mixing we wonder whether 10Be production was slightly different at each location in presence of a multipolar transitional field. The comparison between the 10Be and RPI signals reveals large similarities but also puzzling differences. In particular, the relationship between the two signals is not the same during periods of stable polarity as during the transitional interval. A precursor with low intensity is present in several RPI records but not clearly marked on the beryllium records. We also addressed the question of a possible offset between the two signals that would be indicative of a delayed magnetization acquisition. After correlating and rescaling all records at the same common depth, the unique offset between RPI and 10Be was found in one core from the equatorial Pacific. Summarizing we wonder whether it is justified to match RPI and 10Be records over periods of higher 10Be production and lowest RPI. This is not without consequences when stacking records.

  13. Geochemistry of impact glasses and target rocks from the Zhamanshin impact structure, Kazakhstan: Implications for mixing of target and impactor matter

    NASA Astrophysics Data System (ADS)

    Jonášová, Šárka; Ackerman, Lukáš; Žák, Karel; Skála, Roman; Ďurišová, Jana; Deutsch, Alexander; Magna, Tomáš

    2016-10-01

    Internal structure and element chemistry including contents of highly siderophile elements (HSE) and Os isotope ratios have been studied in target rocks and several groups of impact glasses of the Zhamanshin impact structure, Kazakhstan. These include larger irregularly-shaped fragments and blocks of impact glass (zhamanshinites), and three types of tektite-like splash-form glasses, part of fallback ejecta. These glassy objects typically are up to 30 mm large and are shaped as teardrops, irregularly bent and curved glass rods and fibers. They can be subdivided into acidic types (irghizites; typically 69-76 wt.% SiO2), basic splash-forms (typically 53-56 wt.% SiO2), and rarely occurring highly inhomogeneous composites with abundant mineral inclusions. A comparison with the target rocks shows that zhamanshinites and basic splash-forms usually have no detectable admixture of the projectile matter, indicated by major and trace elements as well as highly siderophile element contents, with the exception of one sample containing Fe-, Cr-, Ni- and Ti-enriched particles and elevated HSE contents. In contrast, irghizites exhibit clear admixture of the projectile matter, which was incorporated by complex processes accompanied by strong element fractionations. Microscopic investigations confirm that irghizites were formed mainly by coalescence of smaller molten glass droplets sized typically below 1 mm. Irghizites exhibit significant enrichments in Ni, Co and Cr, whose concentrations are locally elevated in the rims of the original small droplets. A portion of these elements and also part of Fe and Mn and other elements were derived from the impactor, most likely a Ni-rich carbonaceous chondrite. The contents of HSE are low and strongly fractionated, with moderate depletions of Pt and Pd and strong depletions of other HSE with respect to chondritic element ratios. Osmium shows the strongest depletion, likely related to the presence of oxygen in the post-impact atmosphere causing strong Os loss through volatilization. One composite splash-form contains Fe-Ni-S inclusions and exhibits a less fractionated HSE pattern suggesting the lowest degree of melting, volatilization and condensation. The observed structural and microchemical features of irghizites are interpreted to reflect variable proportions of the uppermost target sediments and the projectile matter, with HSE element ratios influenced by evaporation and condensation processes, and differences in volatility of individual HSE elements and/or their compounds. Two possible pathways of incorporation of the projectile matter into the irghizites include either re-condensation of evaporated projectile matter on the surface of glass droplets, or incorporation of less chemically fractionated microparticles dispersed by the explosion.

  14. Deep drilling in the Chesapeake Bay impact structure - An overview

    USGS Publications Warehouse

    Gohn, G.S.; Koeberl, C.; Miller, K.G.; Reimold, W.U.

    2009-01-01

    The late Eocene Chesapeake Bay impact structure lies buried at moderate depths below Chesapeake Bay and surrounding landmasses in southeastern Virginia, USA. Numerous characteristics made this impact structure an inviting target for scientific drilling, including the location of the impact on the Eocene continental shelf, its threelayer target structure, its large size (??85 km diameter), its status as the source of the North American tektite strewn field, its temporal association with other late Eocene terrestrial impacts, its documented effects on the regional groundwater system, and its previously unstudied effects on the deep microbial biosphere. The Chesapeake Bay Impact Structure Deep Drilling Project was designed to drill a deep, continuously cored test hole into the central part of the structure. A project workshop, funding proposals, and the acceptance of those proposals occurred during 2003-2005. Initial drilling funds were provided by the International Continental Scientific Drilling Program (ICDP) and the U.S. Geological Survey (USGS). Supplementary funds were provided by the National Aeronautics and Space Administration (NASA) Science Mission Directorate, ICDP, and USGS. Field operations were conducted at Eyreville Farm, Northampton County, Virginia, by Drilling, Observation, and Sampling of the Earth's Continental Crust (DOSECC) and the project staff during September-December 2005, resulting in two continuously cored, deep holes. The USGS and Rutgers University cored a shallow hole to 140 m in April-May 2006 to complete the recovered section from land surface to 1766 m depth. The recovered section consists of 1322 m of crater materials and 444 m of overlying postimpact Eocene to Pleistocene sediments. The crater section consists of, from base to top: basement-derived blocks of crystalline rocks (215 m); a section of suevite, impact melt rock, lithic impact breccia, and cataclasites (154 m); a thin interval of quartz sand and lithic blocks (26 m); a granite megablock (275 m); and sediment blocks and boulders, polymict, sediment-clast-dominated sedimentary breccias, and a thin upper section of stratified sediments (652 m). The cored postimpact sediments provide insight into the effects of a large continental-margin impact on subsequent coastal-plain sedimentation. This volume contains the first results of multidisciplinary studies of the Eyreville cores and related topics. The volume is divided into these sections: geologic column; borehole geophysical studies; regional geophysical studies; crystalline rocks, impactites, and impact models; sedimentary breccias; postimpact sediments; hydrologic and geothermal studies; and microbiologic studies. ?? 2009 The Geological Society of America.

  15. The Ewing Impact Structure: Progress Report

    NASA Astrophysics Data System (ADS)

    Abbott, D. H.; Nunes, A. A.; Leung, I. S.; Burckle, L.; Hagstrum, J. T.

    2003-12-01

    We have previously reported on the discovery of the Ewing impact structure. It is 150 km in diameter and is located in the equatorial Pacific between the Clarion and Clipperton fracture zones. We have now mapped the distribution of microtektites and other types of impact spherules. The microtektite bearing cores form a half circle to the south with a straight edge that passes through the center of the crater. This pattern of tektite distribution matches the pattern that has been modeled for deep-water impacts. The impact melt bodies that are the source of the magnetic anomalies associated with the crater also lie in the southern half of the crater. Thus, the overall pattern of microtektite and impact melt distribution is consistent with an impactor on an inclined trajectory that arrived from the north and sprayed ejecta to the south. We have found an impact melt bomb that is part of the distal ejecta blanket. The impact melt bomb is about 10 cm by 6 cm in size. It contains unmelted marine sediment in the center that is surrounded by impact melt glass. So far, attempts to date glassy spherules and impact melt glass have been unsuccessful. Thus, our best estimate of the age of the impact is derived from diatom biostratigraphy, which gives an age of 7 to 11 Ma. In this time period, there are three major climatic excursions that might be related to the Ewing impact event. In most of the region, the 5000-meter water depth precludes using the more numerous foraminiferal zones and oxygen isotope stratigraphy to more precisely date the ejecta layer. Detailed studies of the mineralogy of the ejecta layer in core PLDS-111P have failed to find any quartz at all, shocked or unshocked. However, this core received its ejecta from the southern half of the crater, where the pre-impact basement was composed of normal oceanic crust. To the north, a minor fracture zone cuts the crater. This fracture zone is a potential location of plagiogranites, which are quartz normative. The fracture zone also contains local topographic highs that are shallow enough to retain foraminifera. By concentrating our efforts on carbonate rich cores that sample the ejecta from the northern half of the crater on or near the fracture zone, we hope to determine a more accurate biostratigraphic age for the Ewing impact event. We will also examine the mineralogy of these samples to see if quartz or opaque minerals are present. Both quartz and some opaques can show characteristic shock deformation features.

  16. Ancient impact structures on modern continental shelves: The Chesapeake Bay, Montagnais, and Toms Canyon craters, Atlantic margin of North America

    USGS Publications Warehouse

    Poag, C. Wylie; Plescia, J.B.; Molzer, P.C.

    2002-01-01

    Three ancient impact craters (Chesapeake Bay - 35.7 Ma; Toms Canyon - 35.7 Ma; Montagnais - 51 Ma) and one multiring impact basin (Chicxulub - 65 Ma) are currently known to be buried beneath modern continental shelves. All occur on the passive Atlantic margin of North America in regions extensively explored by seismic reflection surveys in the search for oil and gas reserves. We limit our discussion herein to the three youngest structures. These craters were created by submarine impacts, which produced many structural and morphological features similar in construction, composition, and variability to those documented in well-preserved subaerial and planetary impact craters. The subcircular Chesapeake Bay (diameter 85 km) and ovate Montagnais (diameter 45-50 km) structures display outer-rim scarps, annular troughs, peak rings, inner basins, and central peaks similar to those incorporated in the widely cited conceptual model of complex impact craters. These craters differ in several respects from the model, however. For example, the Montagnais crater lacks a raised lip on the outer rim, the Chesapeake Bay crater displays only small remnants of a raised lip, and both craters contain an unusually thick body of impact breccia. The subtriangular Toms Canyon crater (diameter 20-22 km), on the other hand, contains none of the internal features of a complex crater, nor is it typical of a simple crater. It displays a prominent raised lip on the outer rim, but the lip is present only on the western side of the crater. In addition, each of these craters contains some distinct features, which are not present in one or both of the others. For example, the central peak at Montagnais rises well above the elevation of the outer rim, whereas at Chesapeake Bay, the outer rim is higher than the central peak. The floor of the Toms Canyon crater is marked by parallel deep troughs and linear ridges formed of sedimentary rocks, whereas at Chesapeake Bay, the crater floor contains concentric faults and compression ridges formed in rocks of the crystalline basement. The Chesapeake Bay crater is distinguished further by its cluster of at least 23 adjacent secondary craters. The North American tektite strewn field, a widespread deposit of distal ejecta, is thought to be derived from the Chesapeake Bay impact, perhaps with a small contribution from the Toms Canyon impact. No ejecta field is known to be associated with the Montagnais impact. No immediate major extinction event is directly linked to any of these three impacts. There is evidence, however, that the Chesapeake Bay and Toms Canyon impacts helped initiate a long-term pulse of warm global climate, whose eventual dissipation coincided with an early Oligocene mass extinction event, 2 Ma after the impacts.

  17. Advanced SEM/EDS Analysis using Stage Control and an annular Silicon Drift Detector: Applications in Impact Studies from Centimetre below Micrometre Scale

    NASA Astrophysics Data System (ADS)

    Salge, Tobias; Berlin, Jana; Terborg, Ralf; Howard, Kieren; Newsom, Horton; Wozniakiewicz, Penny; Price, Mark; Burchell, Mark; Cole, Mike; Kearsley, Anton

    2013-04-01

    Introduction: Imaging of ever smaller structures, in situ within large samples, requires low electron beam energy (HV<6 kV) to enhance spatial resolution, and therefore also the use of low energy X-ray lines for element analysis. To separate significantly overlapping peaks e.g. N-K (392 eV) and Ti-Ll (395 eV), the incorporation of line deconvolution algorithms in energy dispersive X-ray software is of crucial importance. Methods: Without adequate X-ray count statistics, deconvolution is unlikely to be effective. We therefore used an annular Silicon Drift Detector (SDD), the Bruker XFlash® 5060F which is placed between the pole piece and sample. High take-off angle and collection of X-rays from four different directions allow data collection across samples with substantial surface topography. Automated stage control and spectrum imaging allow large data sets to be acquired within a short time. Applications: (A) Large area, high resolution images (with tiling or stitching of neighbouring areas) is useful for understanding processes in the formation of tektites [1], revealing flow textures and layering, without destructive section preparation. Coalescence textures formed during the transition from melt to solid, surface pitting produced by micro-impact collisions in the impact plume, and surface etching by chemical attack in the impact plume, or later weathering, can all be revealed. (B) Spectrum imaging of the matrix in the impact melt breccia of the Chicxulub impact crater (Yaxcopoil-1 borehole, Unit 5 861.72 m) reveals secondary mineral formation, such as NaCl (<500 nm) and Fe-Ti-oxides (<150 nm) associated with garnet resorption. It documents the role of multiple episodes of precipitation of Mg-rich phyllosilicates as well as the formation and dissolution of accessory minerals in a relatively high temperature (>300°C) hydrothermal event [2]. (C) In experimental hypervelocity impact craters, spectrum images readily find locations of projectile residue throughout all the complex topography. The very high count rate at even low beam energy and current reveals inhomogeneous compositions and textures below micrometre scale [3]. These results help us understand preservation and modification of structure and composition in the fine-grained cometary dust aggregates which made aluminium foil craters on the Stardust spacecraft during its encounter with comet Wild 2. Acknowledgements: International Continental Scientific Drilling Program and the Museum of Natural History Berlin for providing samples. References: [1] K.T. Howard 2011. Geological Society of London: 573-591. [2] M. Nelson et al. 2012. GCA 86: 1-20. [3] A. T. Kearsley et al. 2013. Submitted to LPSC #1910.

  18. Lost Impacts (Invited)

    NASA Astrophysics Data System (ADS)

    Schultz, P. H.; Stickle, A. M.

    2009-12-01

    The absence of a clearly identified crater (or craters) for the proposed YDB impact has raised questions concerning the reality of such an event. Geologic studies have identified impact deposits well before recognizing a causative crater (e.g., Chicxulub and Chesapeake Bay); some have yet to be discovered (e.g., Australasian tektite strewnfields). The absence of a crater, therefore, cannot be used as an argument against the reality of the YDB impact (and its possible consequences). The study here addresses how a large on-land impact during the late Pleistocene or early Holocene could avoid easy detection today. It does not argue the case for a YDB impact, since such evidence must come from the rock record. During the late Pleistocene, the receding Laurentide ice sheet still covered a significant portion of Canada. While a large (1km) body impacting vertically (90°) would penetrate such a low-impedance ice layer and excavate the substrate, an oblique impact couples more of its energy into the surface layer, thereby partially shielding the substrate. Three approaches address the effectiveness of this flak-jacket effect. First, hypervelocity impact experiments at the NASA Ames Vertical Gun Range investigated the effectiveness of low-impedance layers of different thicknesses for mitigating substrate damage. Second, selected experiments were compared with hydrocode models (see Stickle and Schultz, this volume) and extended to large scales. Third, comparisons were made with relict craters found in eroding sediment and ice covers on Mars. Oblique impacts (30 degrees) into soft particulates (no. 24 sand) covering a solid substrate (aluminum) have no effect on the final crater diameter for layer thicknesses exceeding a projectile diameter and result in only plastic deformation in the substrate. In contrast, a vertical impact requires a surface layer at least 3 times the projectile diameter to achieve the same diameter (with significant substrate damage). Oblique impacts into ice and plasticene layers over clear acrylic blocks allow assessing internal damage. These experiments reveal that low-impedance surface layers approaching 1 to 2 projectile diameters effectively shield the substrate from shock damage for impact angles less than 30 degrees. Missing craters (and relict crater roots) within ice-rich deposits on Mars illustrate the rapid erasure the impact record. Numerous small pedestal craters (crater diameter < 5km) occur at high latitudes and reflect the cyclic expansion and disappearance of polar ice/dust deposits up to 0.5 km thick. Much larger examples (> 50km), however, occur at low latitudes but are localized in certain regions where even thicker deposits (locally >2km) have been removed, uncovering a preserved Noachian landscape. Crater statistics further document this missing cratering record. Thick Pleistocene ice sheets on Earth would have played a similar role for the removal of terrestrial cratering record. We calculate that a crater as large as 15km in diameter formed by an oblique impact could have been effectively erased, except for dispersed ejecta containing shocked impactor relicts and a disturbed substrate. While plausible, evidence for specific missing events (e.g., the proposed YB impact) must be found in still-preserved ice layers and sediments.

  19. Missing in Action? Evaluating the Putative Absence of Impacts by Large Asteroids and Comets during the Quaternary Period

    NASA Astrophysics Data System (ADS)

    Masse, W.; Weaver, R.; Abbott, D.; Gusiakov, V.; Bryant, E.

    The Quaternary period represents the interval of oscillating climatic extremes (glacial and interglacial periods) beginning about 2.6 million years ago to the present. Based on modeling by the Near Earth Object (NEO) community of planetary scientists, the known and validated record of Quaternary impact on Earth by comets and asteroids is seemingly depauperate in terms of larger impactors of 10,000+ Mt (roughly equal to or larger than about 500 m in diameter). Modeling suggests that an average of between 2-3 and perhaps as many as 5 globally catastrophic (ca. 1,000,000+ Mt) impacts by asteroids and comets could have occurred on Earth during this period of time, each having catastrophic regional environmental effects and moderate to severe continental and global effects. A slightly larger number of substantive but somewhat less than globally catastrophic impacts in the 10,000-100,000 Mt range would also be predicted to have occurred during the Quaternary. However, databases of validated impact structures on Earth, contain only two examples of Quaternary period impacts in the 10,000-100,000 Mt range (Zhamanshin, Bosumtwi), dating to around a million years ago, while no examples of Quaternary period globally catastrophic impact structures have been yet identified. In addition, all of the 27 validated Quaternary period impact structures are terrestrial--no Quaternary period oceanic impacts have been yet validated. Two likely globally catastrophic probable oceanic impacts events, Eltanin (ca. 1,000,000 Mt at around 2.5 mya), and that associated with the Australasian tektite strewn field (> 1,000,000 Mt at around 0.8 mya), are known due to their debris fields for which craters have not yet been identified and validated. These and the 8-km diameter Bolivian Iturralde candidate impact structure (ca. 10,000 Mt at around 20 kya) round out our list of likely large Quaternary impact structures. This suggests that one or more Quaternary period globally catastrophic impacts and several events in the 10,000-100,000 Mt range occurred in oceanic settings and have not yet been identified. At issue here is the default position of the NEO community that no large impacts have occurred during the past 15,000 years and that there is little evidence for human death by impacts during the past 5000 years of recorded history. This bias, deriving largely from reliance on stochastic models and by selectively ignoring physical, anthropological, and archaeological evidence in support of such impacts, is apparent in the messages being given to the media and general public, and in the general lack of grant support and other assistance to scientists and scholars wishing to conduct fieldwork on impacts that may date to the past 15,000 years. Such a position has a chilling effect on what should otherwise be an important arena of inquiry into the risks and effects of cosmic impact on human society. It potentially limits advancement in our understanding of the recent record and flux of cosmic impact, and diverts attention away from significant research questions such as the possible role of impact in Quaternary period climate change and biological and cultural evolution and process. LA-UR-07-2526.

  20. Equations of State: Gateway to Planetary Origin and Evolution (Invited)

    NASA Astrophysics Data System (ADS)

    Melosh, J.

    2013-12-01

    Research over the past decades has shown that collisions between solid bodies govern many crucial phases of planetary origin and evolution. The accretion of the terrestrial planets was punctuated by planetary-scale impacts that generated deep magma oceans, ejected primary atmospheres and probably created the moons of Earth and Pluto. Several extrasolar planetary systems are filled with silicate vapor and condensed 'tektites', probably attesting to recent giant collisions. Even now, long after the solar system settled down from its violent birth, a large asteroid impact wiped out the dinosaurs, while other impacts may have played a role in the origin of life on Earth and perhaps Mars, while maintaining a steady exchange of small meteorites between the terrestrial planets and our moon. Most of these events are beyond the scale at which experiments are possible, so that our main research tool is computer simulation, constrained by the laws of physics and the behavior of materials during high-speed impact. Typical solar system impact velocities range from a few km/s in the outer solar system to 10s of km/s in the inner system. Extrasolar planetary systems expand that range to 100s of km/sec typical of the tightly clustered planetary systems now observed. Although computer codes themselves are currently reaching a high degree of sophistication, we still rely on experimental studies to determine the Equations of State (EoS) of materials critical for the correct simulation of impact processes. The recent expansion of the range of pressures available for study, from a few 100 GPa accessible with light gas guns up to a few TPa from current high energy accelerators now opens experimental access to the full velocity range of interest in our solar system. The results are a surprise: several groups in both the USA and Japan have found that silicates and even iron melt and vaporize much more easily in an impact than previously anticipated. The importance of these findings is illustrated by the impact origin of our Moon. Computer simulations that do not take account of the liquid/vapor phase change are unable to retain any material in orbit around the Earth after a planetary impact. A purely gaseous disk around the Earth is wracked by gravitational instabilities and soon collapses back onto the Earth. Only if the silicate EoS also includes a liquid phase can a disk remain stable long enough to condense into a moon. The implications of this new-found ease of vaporization have yet to be fully explored, but it seems clear that current ideas must undergo extensive revision. More melt and vapor production in impacts implies much larger volume changes of the impacted materials and hence more energetic post-impact expansion. EoSs are thus of vital importance to our understanding of the evolution of planetary systems. Computer simulations can (and must!) substitute for experiments for many aspects of large planetary collisions, but so far experiments are leading theory in accurate determination of equations of state. Yet, the fidelity of the computer simulations to Nature can be only as good as the accuracy of the inputs, making further experimental study of EoS a central task in the exploration and elucidation of our solar system and of planetary systems in general.

  1. Upper Eocene Spherules at ODP Site 1090B

    NASA Technical Reports Server (NTRS)

    Liu, S.; Kyte, F. T.; Glass, B. P.; Gersonde, R.

    2000-01-01

    Our two labs independently discovered upper Eocene microtektites and microkrystites at ODP Site 1090, a new South Atlantic locality near the Agulhus Ridge. This is a significant new data point for the strewn fields of these spherules, which were recently extended into the Atlantic sector of the Southern Ocean when they were reported at ODP Site 689 on the Maude Rise. The microtektites have been regarded as related to North American tektites and the microkrystites as belonging to the clinopyroxene-bearing (cpx) spherule strewn field. Initial reports indicate that Site 1090 contains a complete sequence of upper Eocene sediments composed of diatom and nannofossil oozes. The magneto- and bio-stratigraphy indicate that impact-age sediments should occur in core 30X of Hole 1090B. One of us (FTK) took 2 cc samples at 10 cm intervals over 600 cm of core for Ir analyses and the senior author (SL) took 3 cc samples at 20 cm intervals to search for spherules. Both studies proved successful and additional samples were obtained to confirm initial results and better define the Ir anomaly and spherule abundances. Peak Ir concentrations of 0.97 ng/g were found at 1090B-30X-5, 105-106cm and 0.78 ng/g at 115-116 cm. Anomalous Ir concentrations (greater than 0.1 ng/g) extend over about 100 cm of core. Preliminary results indicate that the excess Ir at this site is about 25 ng per sq cm. About 380 microtektites (>63 pm) and 2492 microkrystites (>63 pm) were recovered over a 1.8 m interval with a peak abundance of microtektites (106/gram) and microkrystites (562/gram) at 1090B-30X- 5, 114-115 cm. The largest microtektite is approximately 960 x 1140 micron in size. About 55 % are spherical, and the rest are disc, cylinder, dumbbell, teardrop, or fragments. Most of the microtektites are transparent colorless, but a few are transparent pale brown or green. Preliminary data indicate that the microtektites at Site 1090 have similar major oxide compositions to those at Site 689. About 50% of the cpx spherules are spherical, the rest are fragments. They range from yellowish translucent to dark opaque. Based on stratigraphic data, occurrence of a positive Ir anomaly, and similar appearance and major oxide compositions of the Site 1090 spherules to those at Site 689, we believe that the spherule layer(s) are the same at both sites. However, there are significant differences between these two sites. At Site 689 the peak abundance of the cpx spherules is slightly below that of the microtektites. We can distinguish no such separation at Site 1090, despite a somewhat higher sediment accumulation rates. Peak Ir concentrations are about four times higher at Site 1090, resulting in a similarly higher total flux of Ir for this site compared to Site 689 on the Maude Rise. This is generally consistent with the flux of cpx spherules (greater than 63 pm) which is estimated to be approximately -2100 per sq cm, about twice that of Site 689D (1040 sq cm) and with the cpx-spherule component being a principal carrier of the Ir signal. The number of microtektites per sq cm (greater than 63 micron) is nearly the same at both sites, approximately 300 in 1090B and 280 in 689B. A decrease in the greater than 63 micron size fraction (consisting primarily of diatoms and radiolaria) is coincident with the spherule layer at both sites suggesting that the impact(s) that produced the spherule layer(s) may have had an adverse affect on the marine plankton.

  2. BARRINGER AWARD ADDRESS: Shock Metamorphism of Quartz in Nature and Experiment: A Review

    NASA Astrophysics Data System (ADS)

    Stoffler, D.

    1993-07-01

    Quartz as a widespread rock-forming mineral of the Earth's crust represents the most sensitive indicator of impact-induced shock waves and therefore provides an outstanding tool for the recognition of terrestrial impact formations and for the pressure calibration of shock metamorphosed rocks. This paper attempts to summarize the current knowledge in this field. Shocked quartz has been observed in quite variable spatial relations to impact craters: (1) in the crater basement, (2) in rock and mineral clasts of polymict breccias, and (3) in distal ejecta such as tektites and global air- fall beds (e.g., K/T boundary). Quartz displays a wide variety of shock- induced mechanical deformations and transformations [1,2]. Microscopically observable effects are multiple sets of planar fractures (PF) and planar deformation features (PDF) parallel to low indices crystallographic planes; mosaickism; reduced refractivity and birefringence; partial transformation to stishovite; increased optic axial angle; amorphization (diaplectic glass), partial transformation to coesite; and melting (lechatelierite). Additional effects at the atomic scale are well documented by TEM, X-ray diffraction and spectroscopy [3-7]. All types of shock effects observed so far in natural quartz have been reproduced by experimental shock waves in the laboratory and in large scale TNT and nuclear explosions. By means of sophisticated techniques the pressure dependence of shock effects has been calibrated with high precision. Threshold pressures at room temperature (given in GPa) for the onset of certain effects in single crystals and in nonporous quartzofeldpathic rocks are: 7.5 +- 2, 10 +- 2, 20 +- 2 (various PFs and PDFs), 12 +- 1 (stishovite), 25 +- 1 (reduced refractive index and density), ~30 (coesite), 34 +- 1 (total transformation to diaplectic glass), 50 +- 2 (melting and formation of lechatelierite) [8-12]. The type of shock effects, their paragenetic combination, and their formation pressure are strongly dependent on the physical and textural properties of the impacted quartz-bearing target. Porosity [13] and preshock temperature [9,12,14] are most effective. Both properties are lowering the threshold pressure for certain shock effects and they affect the orientation and type of planar deformation structures (PFs and PDFs). Upon thermometamorphism shocked quartz displays characteristic annealing effects useful for (limited) geothermometry. PDFs transform to "decorated planar features" due to recrystallization. These features persist up to the conditions of recrystallization of the primary quartz. Annealing of diaplectic glass leads to densification of the glass between 700 and 1200 degrees C and to complete recrystallization to alpha-quartz + alpha-cristobalite above 1200 degrees C [10]. In impact craters this transformation produces the characteristic "ballen" texture as observed in clasts of melt rocks. Stishovite and coesite decompose near 350 degrees C and above about 1150 degrees C, respectively. These annealing features provide important boundary conditions for interpreting the temperature-time history of impact formations. There is unequivocal evidence, strongly supported by TEM studies [3,4,8], that most of the shock effects discussed above and, certainly, the complete set cannot be produced by endogenic processes in near-surface environments of the Earth's crust where the strain rates are several orders of magnitude lower than those in impact processes, and the peak pressures exceed 5 GPa only in very special tectonic settings at great depth. References: [1] Stoffler D. (1972) Fortschr. Mineral., 49, 50-113, and references therein. [2] Stoffler D. (1974) Fortschr. Mineral., 51, 256-289. [3] Gratz A. J. et al. (1988) Phys. Chem. Mineral., 16, 221-233. [4] Goltrant O. et al. (1991) EPSL 106, 103-115. [5] Cygan R. T. et al. (1990) LPSC XX, 451-457. [6] Jakubith M. and Lehmann G. (1981) Phys. Chem. Mineral., 7, 165- 168. [7] Ashworth J. R. and Schneider H. (1985) Phys. Chem. Mineral., 11, 241- 249. [8] Stoffler D. (1984) J. Non-Cryst. Solids, 67, 465-502, and references therein. [9] Gratz A. J. (1992) Phys. Chem. Mineral., 19, 267-288, [10] Rehfeldt-Oskierski A. (1986) Ph.D. thesis, Univ. of Munster. [11] Grothues J. (1988) Diploma thesis, Univ. of Muenster [12] Langenhorst F. (1993), Ph.D. thesis, Univ. of Munster. [13] Kieffer S. W. et al. (1976) Contr. Mineral. Petrol., 59, 41-93, [14] Langenhorst F. (1992) Nature, 356, 507-509.

  3. New Evidence from Silica Debris Exo-Systems for Planet Building Hypervelocity Impacts

    NASA Astrophysics Data System (ADS)

    Lisse, Carey

    2010-05-01

    There is abundant inferential evidence for massive collisions in the early solar system [1]: Mercury's high density; Venus' retrograde spin; Earth's Moon; Mars' North/South hemispherical cratering anisotropy; Vesta's igneous origin [2]; brecciation in meteorites [3]; and Uranus' spin axis located near the plane of the ecliptic. Recent work [4] analyzing Spitzer mid-IR spectra has demonstrated the presence of large amounts of amorphous silica and SiO gas produced by a recent (within 103 - 104 yrs) large (MExcess > MPluto) hypervelocity impact collision around the young (~12 Myr old) nearby star HD172555, at the right age to form rocky planets. Many questions still remain concerning the location, lifetime, and source of the detected silica/SiO gas, which should not be stable in orbit at the estimated 5.8 AU from the HD172555 A5V primary for more than a few decades, yet it is also highly unlikely that we are fortuitously observing these systems immediately after silica formation A tabulation of the amount counts in the fine silica dust is decidedly Fe and Mg-atom poor compared to solar [4]. Three possible origins for the observed silica/SiO gas seem currently plausible : (1) A single hyperevelocity impact (>10km/s in order to produce silica and vaporize SiO at impact) creating an optically thick circumplanetary debris ring which is overflowing or releasing silica-rich material from its Hill sphere. Like terrestrial tektites, the Fe/Mg poor amorphous silica rubble is formed from quick-quenched molten/vaporized rock created during the impact. The amount of dust detected in the HD172555 system is easily enough to fill and overflow the Hill sphere radius of 0.03 AU for a Pluto-sized body at 5.8 AU from an A5 star, unless it is optically thick (> 1 cm in physical depth). Such a disk would provide a substantial fraction of the observed IR flux, and will be dense enough to self-shield its SiO gas, greatly extending its photolytic lifetime. The lifetime for such a system versus re-condensation into a solid body like the Moon is short, though, ~ 103 to 104 yrs [5]. Credence is lent to this scenario by observations of the Jovian impact in July 2009 [6], where absorption features due to silica have been found superimposed on those of hot ammonia at the > 60 km/s impact site (Fig. 1). (2) Ongoing multiple small hypervelocity impacts continuously grinding down a distribution of large circumstellar particles above the blowout size limit (the 'rubble' identified in [4]) and releasing silica rich material and SiO gas. This model would require a massive (>1 MMoon) belt of 10 μm - 1 cm particles with inclinations spread out over at least ±45o [4] or dust on highly eccentric orbits [7]. The amount of material implied by the relative amplitude of the rubble spectral feature is consistent with the amount needed to collisionally produce the fine silica dust [4, 8]. A body rapidly re-accreting in a debris ring after collisional disruption (like the Moon) would have similar behavior (lots of impacts for some time, producing gas and little melt droplets). (3) A single impact onto a silica-rich object with already highly differentiated surface layers. For a very young system at 10 - 20 Myr when we expect planets to be rapidly accreting, a Mercury or larger-sized rocky body covered in an SiO rich magma ocean is very likely by the Jeans energy criterion [9], even without considering additional heating input by 26Al and other radioactives. For the lowest expected impact velocities,v MercuryEscape = 4 km/s, a pre-existing magma ocean in equilibrium with a surrounding SiO atmosphere would be required; at higher velocities the impacting body could be the formative mechanism for the magma ocean [10]. Further evidence for excess circumstellar emission due to silica dust have now been found. The youngest of these, HD154263, at ~20 Myr age shows evidence for SiO gas and amorphous + crystalline silica. The 2 older systems, HD23514 at ~100 Myr age, and HD15407 at ~2 Gyr, conspicuously do not show any evidence for SiO gas while exhibiting strong features mainly due to crystalline silica. HD23514 also shows evidence for large amounts of amorphous carbon, PAHs, and nanodiamonds, due to a strongly enhanced C-atom abundance in impactor or impactee. HD15407, the oldest system, also does not show any conclusive evidence for the presence of large dark particles ('rubble').

  4. Ejecta emplacement: from distal to proximal

    NASA Astrophysics Data System (ADS)

    Artemieva, N.

    2008-09-01

    Introduction Most part of impact ejecta is deposited ballistically at some distance from a crater, defined by ejection velocity V and ejection angle α: d=v2sinα/g. In case of giant impacts, planetary curvature should be taken into account [1]. Combined with ejecta scaling [2], these relations allow to define ejecta thickness as a function of distance. Ejecta from large craters are deposited at velocity high enough to mobilize substrate material and to thicken ejecta deposits [3]. Ballistic approximation is valid for airless bodies (if impact vaporization is not vast) or for proximal ejecta of large impact craters, where ejecta mass per unit area is substantially greater than the mass of involved vapor/atmosphere (M-ratio). Deposition of distal ejecta, in which ejecta mass is negligible compared to the atmosphere, may be also treated in a simplified manner, i.e. as 1) passive motion of ejected particles within an impact plume and 2) later, as sedimentation of particles in undisturbed atmosphere (equilibrium between gravity and drag). In all intermediate M-ratio values, impact ejecta move like a surge, i.e. dilute suspension current in which particles are carried in turbulent flows under the influence of gravity. Surges are well-known for near-surface explosive tests, described in detail for volcanic explosions (Plinian column collapse, phreato-magmatic eruption, lateral blast), and found in ejecta from the Chicxulub [4] and the Ries [5]. Important aspects of surge transport include its ability to deposit ejecta over a larger area than that typical of continuous ballistic ejecta and to create multiple ejecta layers. Numerical model Two-phase hydrodynamics. Surges should be modeled in the frame of two-phase hydrodynamics, i.e. interaction between solid/molten particles and atmospheric gas/impact vapor should be taken into account. There are two techniques of solving equations for dust particle motion in a gas flow. The first one describes solid/molten particles as a liquid with specific properties, i.e. finite-difference equations are the same as in standard hydrodynamics [6-8]. Another approach is based on solving equations of motion for representative particles [9]. Each of these markers describes the motion of a large number of real particles with similar sizes, velocities, and trajectories. Equation of motion (gravity, viscosity, and drag) is solved for every marker and then exchange of momentum, heat and energy with surrounding vaporair mixture is taken into account. This approach is used in the SOVA code [10] and allows to vary particle sizes within a broad range (from a few m to a few microns). Implicit procedure of velocity update allows a larger time step. The substantial advantage of the model is its three-dimensional geometry, allowing modeling of asymmetric deposits of oblique impact ejecta. Turbulent diffusion is taken into account in a simplified manner [6]. Fragments size-frequency distribution (SFD) may be of crucial importance: while large fragments move ballistically, the smallest ones are passively involved in gas motion. Ejected material is usually transformed into particles under tension. The initial particle velocity is given by the hydrodynamic velocity, but the object's initial position within the cell is randomly defined. The SFD of solid fragments in high velocity impacts has been studied experimentally [2,11], numerically [12,13], and has been derived from the lunar and terrestrial crater observations [14,15]. Various approaches may be used to implement fragment size in a dynamic model: in Grady-Kipp model the average fragment size is defined by strain rate [12]; alternatively, average ejection velocity [16] or maximum shock compression [17] may be used. All methods may be verified through comparison with known data. Volcanic direct blast. Numerical modeling of pyroclastic flows, checked against recent observations and young deposits, may be then a useful instrument for reconstruction of terrestrial craters' ejecta, which are mostly eroded or buried; and for impact ejecta study on other planets (first of all - on Mars), where remote sensing data are still the only source of our knowledge. In volcanology typical velocities are usually below 300 m/s, temperatures may be as low as 300 K (wet surge) and not higher than 1000 K (dry surge), solid/gas mass ratio ranges between 5-50, particle size rarely exceeds several cm, while the mass fraction of fine micronsized particles is usually poorly defined. Modeling results (thickness and spatial distribution of pyroclastics) are in reasonable agreement with observations of direct blast at Bezymianny volcano (Kamchatka, Russia) in 1956. Crater ejecta - the Ries crater in Germany. Impact ejecta parameters vary in a substantially wider range: distal ejecta velocities reach several km/s, km-sized fragments are typical for large craters, gas content may be high enough for cratering in volatile rich (or water-covered) target or in the presence of a dense atmosphere. Moldavites.. The Ries impact site is characterized by a thick sedimentary layer, from which a large amount of vapor (e.g., CO2) is shock-released. This vapor contributes to the ejected particles acceleration, or at least, to the sustainment of their motion. The initial ejection velocities of material are rather high, up to 10 km/s, which are close to the velocity of the expanding gas. As a result, the particles are not subject to high dynamic pressures that otherwise would disrupt them into fine mist immediately after ejection. The temperature of the entraining gas is rather high, so the particles do not cool quickly during the flight, allowing enough time to have them aerodynamically shaped (typical for tektites), and to lose volatiles [18,19]. Tektites are distributed up to 400-500 km away from the impact, in a fan of ˜75° symmetrically distributed with respect to the downrange direction. Bunte Breccia and fallout Suevite in Otting (Ries crater). The total amount of ejected material is about 160 km3 (with an average sediment/basement proportion of 3:1). The maximum ejection velocity for crystalline rocks does not exceed 1 km/s. There are no basement ejecta in the uprange direction. Ejecta deposited within a ring of 16-18 km radius (similar to the position of the Otting site) have a deposition velocity of ~350 m/s. This velocity allows substantial reworking of ejecta and mixing with target rocks. Otting ejecta consist of a sediment /basement rock mixture. The average shock compression of basement rocks is at least 4 times higher than in sediments for any azimuthal angle (16 GPa versus 4 GPa). Ejecta thickness (tens of m) is in a reasonable agreement with observations. However, our modeling results relevant to ballistic deposition do not allow to reproduce the observed ejecta in the suevite layer of Otting: 1) there is just very little melt in the modeled ejecta and 2) separation of sedimentary rocks from basement rocks (i.e. Bunte Breccia and fallout suevite) does not occur. Separation and gradation of ejected particles by atmosphere (fallout) seems improbable as the total ejecta mass per unit area at these distances is substantially higher than the mass of the involved atmosphere. Deposition of a suevitic layer as a viscous flow [20] seems also improbable, as viscosity of the flow with solid fragments (i.e. with temperature below the solidus) increases dramatically and prevents spreading to a few km from the transient cavity. We need another mechanism of the ejecta flow "fluidization". One possibility is a gas release (mainly water vapor from sediments) which allows dispersal of the smallest particles and suevite deposition above the ballistically deposited Bunte Breccia (similar to pyroclastic surges). Applications for planets Mars. Several attempts have been made to quantitatively describe the process of ejecta emplacement in formation of ramparts [21-25]. They dealt mainly with propagation of fluidized ejecta initially deposited ballistically and included rheologic models for Newtonian or Bingham materials based on observations (runout distance, height of the distal ridge). Our model establishes better initial conditions for ejecta flow formation and provide estimates for the properties of fluidized ejecta directly on the basis of the particles/gas ratio, particle size, and temperaturedensity conditions in the ejecta. Venus. Ejecta deposition on Venus is substantially non-ballistic due to thick Venusian atmosphere. Some of impact craters are surrounded by "dark halos" [26- 28], others have unique dark parabolas, representing surficial deposits of loose material lifted during crater formation [29-30]. Methods of two-phase hydrodynamics may be useful to describe mechanism of their formation. References [1] Dobrovolskis A. (1981) Icarus 47, 203-219. [2] Cintala M.J., et al. (1999) M&PS. 34, 605-623. [3] Oberbeck V.R. (1975) Rev. Geophys. Space Phys. 13, 337-362. [4] Dressler et al. (2004) M&PS 39, 857- 878. [5] Hörz F. et al. (1983) Rev Geophys.Space Phys. 21, 1667-1725. [6] Valentine G.A. and Wohletz K.H. (1989) JGR 94, 1867-1887. [7] Dobran F. and Neri A. (1993) JGR 98, 4231-4259. [8] Neri A. et al. (2003) JGR 108, doi:10.1029/ 2001JB000508. [9] Boothroyd R.G. (1971) Flowing gas-solids suspension, Chapman and Hall Ltd, London. [10] Shuvalov V.V. (1999) Shock waves 9, 381-390. [11] Nakamura A. and Fujiwara A. (1991) Icarus 92, 132- 146. [12] Grady D.E. and Kipp M.E. (1980) Int. J. Rock Mech. Min. Sci. Geomech. Abstr. 17, 147-157. [13] Melosh H.J. et al. (1992) JGR 97, 14735-14759. [14] Gault, D.E. et al. (1963) NASA TND-1767. [15] Vickery A.M. (1986) Icarus 67, 224-236. [16] Melosh H.J. (1984) Icarus 59, 234-260. [17] Shuvalov V.V. (2002) LPSC-33, abstr.#1259. [18] Stöffler et al. (2002) M&PS 37, 1893-1908. [19] Melosh H.J. and Artemieva N.A. (2004) LPSC-35, abstr. #1723. [20] Osinski et al. (2004) Meteoritics Planet. Sci. 39, 1655-1683. [21] Ivanov B.A. et al. (1997) LPSC 28, 637-638. [22] Garvin J.B., Baloga S.M. (1999) LPSC 30, Abst. #1735. [23] Fagents S.A. et al. (2005) LPSC 36, Abst. #2127. [24] Baratoux D. et al. (2002) GRL 29(8), 1210, 10.1029/ 2001GL012779. [25] Barnouin-Jha O.S. and Schultz P.H. (1998) JGR 103(E11), 25,739-25,756. [26] Phillips R,J, et al. (1991) Science 252, 288-297. [27] Ivanov B. et al. (1992) JGR 97, 16,167-181. [28] Takata T. et al. (1995) JGR 100, 23,329-348. [29] Campbell D. et al. (1992) JGR 97, 16,249-277. [30] Bondarenko N.V. and Head J.W. (2004) JGR 109, doi 10.1029/2004JE002256.

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