Temperature and pressure dependences of kimberlite melts viscosity (experimental-theoretical study)

NASA Astrophysics Data System (ADS)

Persikov, Eduard; Bykhtiyarov, Pavel; Cokol, Alexsander

2016-04-01

Experimental data on temperature and pressure dependences of viscosity of model kimberlite melts (silicate 82 + carbonate 18, wt. %, 100NBO/T = 313) have been obtained for the first time at 100 MPa of CO2 pressure and at the lithostatic pressures up to 7.5 GPa in the temperature range 1350 oC - 1950 oC using radiation high gas pressure apparatus and press free split-sphere multi - anvil apparatus (BARS). Experimental data obtained on temperature and pressure dependences of viscosity of model kimberlite melts at moderate and high pressures is compared with predicted data on these dependences of viscosity of basaltic melts (100NBO/T = 58) in the same T, P - range. Dependences of the viscosity of model kimberlite and basaltic melts on temperature are consistent to the exponential Arrenian equation in the T, P - range of experimental study. The correct values of activation energies of viscous flow of kimberlite melts have been obtained for the first time. The activation energies of viscous flow of model kimberlite melts exponentially increase with increasing pressure and are equal: E = 130 ± 1.3 kJ/mole at moderate pressure (P = 100 MPa) and E = 160 ± 1.6 kJ/mole at high pressure (P = 5.5 GPa). It has been established too that the viscosity of model kimberlite melts exponentially increases on about half order of magnitude with increasing pressures from 100 MPa to 7.5 GPa at the isothermal condition (1800 oC). It has been established that viscosity of model kimberlite melts at the moderate pressure (100 MPa) is lover on about one order of magnitude to compare with the viscosity of basaltic melts, but at high pressure range (5.5 - 7.5 GPa), on the contrary, is higher on about half order of magnitude at the same values of the temperatures. Here we use both a new experimental data on viscosity of kimberlite melts and our structural chemical model for calculation and prediction the viscosity of magmatic melts [1] to determine the fundamental features of viscosity of kimberlite and basaltic magmas at the T, P - parameters of the Earth's crust and upper mantle. The Russian Foundation for Basic Research (project 15-05-01318) and the Russian Science Foundation (project 14-27-00054) are acknowledged for the financial support. [1] Persikov, E.S. & Bukhtiyarov, P.G. (2009) Russian Geology & Geophysics, 50, No 12, 1079-1090.

Viscosity of alumina nanoparticles dispersed in car engine coolant

DOE Office of Scientific and Technical Information (OSTI.GOV)

Kole, Madhusree; Dey, T.K.

The present paper, describes our experimental results on the viscosity of the nanofluid prepared by dispersing alumina nanoparticles (<50 nm) in commercial car coolant. The nanofluid prepared with calculated amount of oleic acid (surfactant) was tested to be stable for more than 80 days. The viscosity of the nanofluids is measured both as a function of alumina volume fraction and temperature between 10 and 50 C. While the pure base fluid display Newtonian behavior over the measured temperature, it transforms to a non-Newtonian fluid with addition of a small amount of alumina nanoparticles. Our results show that viscosity of themore » nanofluid increases with increasing nanoparticle concentration and decreases with increase in temperature. Most of the frequently used classical models severely under predict the measured viscosity. Volume fraction dependence of the nanofluid viscosity, however, is predicted fairly well on the basis of a recently reported theoretical model for nanofluids that takes into account the effect of Brownian motion of nanoparticles in the nanofluid. The temperature dependence of the viscosity of engine coolant based alumina nanofluids obeys the empirical correlation of the type: log ({mu}{sub nf}) = A exp(BT), proposed earlier by Namburu et al. (author)« less

Quantitative characterization of the viscosity of a microemulsion

NASA Technical Reports Server (NTRS)

Berg, Robert F.; Moldover, Michael R.; Huang, John S.

1987-01-01

The viscosity of the three-component microemulsion water/decane/AOT has been measured as a function of temperature and droplet volume fraction. At temperatures well below the phase-separation temperature the viscosity is described by treating the droplets as hard spheres suspended in decane. Upon approaching the two-phase region from low temperature, there is a large (as much as a factor of four) smooth increase of the viscosity which may be related to the percolation-like transition observed in the electrical conductivity. This increase in viscosity is not completely consistent with either a naive electroviscous model or a simple clustering model. The divergence of the viscosity near the critical point (39 C) is superimposed upon the smooth increase. The magnitude and temperature dependence of the critical divergence are similar to that seen near the critical points of binary liquid mixtures.

Peristalsis of nonconstant viscosity Jeffrey fluid with nanoparticles

NASA Astrophysics Data System (ADS)

Alvi, N.; Latif, T.; Hussain, Q.; Asghar, S.

Mixed convective peristaltic activity of variable viscosity nanofluids is addressed. Unlike the conventional consideration of constant viscosity; the viscosity is taken as temperature dependent. Constitutive relations for linear viscoelastic Jeffrey fluid are employed and uniform magnetic field is applied in the transverse direction. For nanofluids, the formulation is completed in presence of Brownian motion, thermophoresis, viscous dissipation and Joule heating. Consideration of temperature dependence of viscosity is not a choice but the realistic requirement of the wall temperature and the heat generated due to the viscous dissipation. Well established large wavelength and small Reynolds number approximations are invoked. Non-linear coupled system is analytically solved for the convergent series solutions identifying the interval of convergence explicitly. A comparative study between analytical and numerical solution is made for certainty. Influence of the parameters undertaken for the description of the problem is pointed out and its physics explained.

Study on the temperature-dependent coupling among viscosity, conductivity and structural relaxation of ionic liquids.

PubMed

Yamaguchi, Tsuyoshi; Yonezawa, Takuya; Koda, Shinobu

2015-07-15

The frequency-dependent viscosity and conductivity of three imidazolium-based ionic liquids were measured at several temperatures in the MHz region, and the results are compared with the intermediate scattering functions determined by neutron spin echo spectroscopy. The relaxations of both the conductivity and the viscosity agree with that of the intermediate scattering function at the ionic correlation when the relaxation time is short. As the relaxation time increases, the relaxations of the two transport properties deviate to lower frequencies than that of the ionic structure. The deviation begins at a shorter relaxation time for viscosity than for conductivity, which explains the fractional Walden rule between the zero-frequency values of the shear viscosity and the molar conductivity.

Sensitivity of viscosity Arrhenius parameters to polarity of liquids

NASA Astrophysics Data System (ADS)

Kacem, R. B. H.; Alzamel, N. O.; Ouerfelli, N.

2017-09-01

Several empirical and semi-empirical equations have been proposed in the literature to estimate the liquid viscosity upon temperature. In this context, this paper aims to study the effect of polarity of liquids on the modeling of the viscosity-temperature dependence, considering particularly the Arrhenius type equations. To achieve this purpose, the solvents are classified into three groups: nonpolar, borderline polar and polar solvents. Based on adequate statistical tests, we found that there is strong evidence that the polarity of solvents affects significantly the distribution of the Arrhenius-type equation parameters and consequently the modeling of the viscosity-temperature dependence. Thus, specific estimated values of parameters for each group of liquids are proposed in this paper. In addition, the comparison of the accuracy of approximation with and without classification of liquids, using the Wilcoxon signed-rank test, shows a significant discrepancy of the borderline polar solvents. For that, we suggested in this paper new specific coefficient values of the simplified Arrhenius-type equation for better estimation accuracy. This result is important given that the accuracy in the estimation of the viscosity-temperature dependence may affect considerably the design and the optimization of several industrial processes.

The onset of convection in a binary fluid mixture with temperature dependent viscosity and Coriolis force with Soret presence

NASA Astrophysics Data System (ADS)

Abidin, Nurul Hafizah Zainal; Mokhtar, Nor Fadzillah Mohd; Majid, Zanariah Abdul; Ghani, Siti Salwa Abd

2017-11-01

Temperature dependent viscosity and Coriolis force were applied to the steady Benard-Marangoni convection where the lower boundary of a horizontal layer of the binary mixture is heated from below and cooled from above. The purpose of this paper is to study in detail the onset of convection with these effects. Few cases of boundary conditions are studied which are rigid-rigid, rigid-free and free-free representing the lower-upper boundaries. A detailed numerical calculation of the marginal stability curves was performed by using the Galerkin method and it is showed that temperature dependent viscosity and Soret number destabilize the binary fluid layer system and Taylor number act oppositely.

Role of rheology in reconstructing slab morphology in global mantle models

NASA Astrophysics Data System (ADS)

Bello, Léa; Coltice, Nicolas; Tackley, Paul; Müller, Dietmar

2015-04-01

Reconstructing the 3D structure of the Earth's mantle has been a challenge for geodynamicists for about 40 years. Although numerical models and computational capabilities have incredibly progressed, parameterizations used for modeling convection forced by plate motions are far from being Earth-like. Among the set of parameters, rheology is fundamental because it defines in a non-linear way the dynamics of slabs and plumes, and the organization of the lithosphere. Previous studies have employed diverse viscosity laws, most of them being temperature and depth dependent with relatively small viscosity contrasts. In this study, we evaluate the role of the temperature dependence of viscosity (variations up to 6 orders of magnitude) on reconstructing slab evolution in 3D spherical models of convection driven by plate history models. We also investigate the importance of pseudo-plasticity in such models. We show that strong temperature dependence of viscosity combined with pseudo-plasticity produce laterally and vertically continuous slabs, and flat subduction where trench retreat is fast (North, Central and South America). Moreover, pseudo-plasticity allows a consistent coupling between imposed plate motions and global convection, which is not possible with temperature-dependent viscosity only. However, even our most sophisticated model is not able to reproduce unambiguously stagnant slabs probably because of the simplicity of material properties we use here. The differences between models employing different viscosity laws are very large, larger than the differences between two models with the same rheology but using two different plate reconstructions or initial conditions.

Intrinsic and Extrinsic Temperature-Dependency of Viscosity-Sensitive Fluorescent Molecular Rotors

PubMed Central

Howell, Sarah; Dakanali, Marianna; Theodorakis, Emmanuel A.; Haidekker, Mark A.

2011-01-01

Molecular rotors are a group of environment-sensitive fluorescent probes whose quantum yield depends on the ability to form twisted intramolecular chargetransfer (TICT) states. TICT formation is dominantly governed by the solvent's microviscosity, but polarity and the ability of the solvent to form hydrogen bonds play an additional role. The relationship between quantum yield ϕF and viscosity η is widely accepted as a power-law, ϕF = C · ηx. In this study, we isolated the direct influence of the temperature on the TICT formation rate by examining several molecular rotors in protic and aprotic solvents over a range of temperatures. Each solvent's viscosity was determined as a function of temperature and used in the above power-law to determine how the proportionality constant C varies with temperature. We found that the power-law relationship fully explains the variations of the measured steady-state intensity by temperature-induced variations of the solvent viscosity, and C can be assumed to be temperature-independent. The exponent x, however, was found to be significantly higher in aprotic solvents than in protic solvents. We conclude that the ability of the solvent to form hydrogen bonds has a major influence on the relationship between viscosity and quantum yield. To use molecular rotors for the quantitative determination of viscosity or microviscosity, the exponent x needs to be determined for each dye-solvent combination. PMID:21947609

Impact of viscosity variation and micro rotation on oblique transport of Cu-water fluid.

PubMed

Tabassum, Rabil; Mehmood, R; Nadeem, S

2017-09-01

This study inspects the influence of temperature dependent viscosity on Oblique flow of micropolar nanofluid. Fluid viscosity is considered as an exponential function of temperature. Governing equations are converted into dimensionless forms with aid of suitable transformations. Outcomes of the study are shown in graphical form and discussed in detail. Results revealed that viscosity parameter has pronounced effects on velocity profiles, temperature distribution, micro-rotation, streamlines, shear stress and heat flux. It is found that viscosity parameter enhances the temperature distribution, tangential velocity profile, normal component of micro-rotation and shear stress at the wall while it has decreasing effect on tangential component of micro-rotation and local heat flux. Copyright © 2017 Elsevier Inc. All rights reserved.

Characterization of the temperature and humidity-dependent phase diagram of amorphous nanoscale organic aerosols.

PubMed

Rothfuss, Nicholas E; Petters, Markus D

2017-03-01

Atmospheric aerosols can exist in amorphous semi-solid or glassy phase states. These states are determined by the temperature (T) and relative humidity (RH). New measurements of viscosity for amorphous semi-solid nanometer size sucrose particles as a function of T and RH are reported. Viscosity is measured by inducing coagulation between two particles and probing the thermodynamic states that induce the particle to relax into a sphere. It is shown that the glass transition temperature can be obtained by extrapolation to 10 12 Pa s from the measured temperature-dependent viscosity in the 10 6 to 10 7 Pa s range. The experimental methodology was refined to allow isothermal probing of RH dependence and to increase the range of temperatures over which the dry temperature dependence can be studied. Several experiments where one monomer was sodium dodecyl sulfate (SDS), which remains solid at high RH, are also reported. These sucrose-SDS dimers were observed to relax into a sphere at T and RH similar to those observed in sucrose-sucrose dimers, suggesting that amorphous sucrose will flow over an insoluble particle at a viscosity similar to that characteristic of coalescence between two sucrose particles. Possible physical and analytical implications of this observation are considered. The data reported here suggest that semi-solid viscosity between 10 4 and 10 12 Pa s can be modelled over a wide range of T and RH using an adapted Vogel-Fulcher-Tammann equation and the Gordon-Taylor mixing rule. Sensitivity of modelled viscosity to variations in dry glass transition temperature, Gordon-Taylor constant, and aerosol hygroscopicity are explored, along with implications for atmospheric processes such as ice nucleation of glassy organic aerosols in the upper free troposphere. The reported measurement and modelling framework provides a template for characterizing the phase diagram of other amorphous aerosol systems, including secondary organic aerosols.

Can a grain size-dependent viscosity help yielding realistic seismic velocities of LLSVPs?

NASA Astrophysics Data System (ADS)

Schierjott, J.; Cheng, K. W.; Rozel, A.; Tackley, P. J.

2017-12-01

Seismic studies show two antipodal regions of low shear velocity at the core-mantle boundary (CMB), one beneath the Pacific and one beneath Africa. These regions, called Large Low Shear Velocity Provinces (LLSVPs), are thought to be thermally and chemically distinct and thus have a different density and viscosity. Whereas there is some general consensus about the density of the LLSVPs the viscosity is still a very debated topic. So far, in numerical studies the viscosity is treated as either depth- and/or temperature- dependent but the potential grain size- dependence of the viscosity is neglected most of the time. In this study we use a self-consistent convection model which includes a grain size- dependent rheology based on the approach by Rozel et al. (2011) and Rozel (2012). Further, we consider a primordial layer and a time-dependent basalt production at the surface to dynamically form the present-day chemical heterogeneities, similar to earlier studies, e.g by Nakagawa & Tackley (2014). With this model we perform a parameter study which includes different densities and viscosities of the imposed primordial layer. We detect possible thermochemical piles based on different criterions, compute their average effective viscosity, density, rheology and grain size and investigate which detecting criterion yields the most realistic results. Our preliminary results show that a higher density and/or viscosity of the piles is needed to keep them at the core-mantle boundary (CMB). Relatively to the ambient mantle grain size is high in the piles but due to the temperature at the CMB the viscosity is not remarkably different than the one of ordinary plumes. We observe that grain size is lower if the density of the LLSVP is lower than the one of our MORB material. In that case the average temperature of the LLSVP is also reduced. Interestingly, changing the reference viscosity is responsible for a change in the average viscosity of the LLSVP but not for a different average grain size. Finally, we compare the numerical results with seismological observations by computing 1D seismic velocity profiles (p-wave, shear-wave and bulk velocities) inside and outside our detected piles using thermodynamic data calculated from Perple_X .

Understanding the importance of the temperature dependence of viscosity on the crystallization dynamics in the Ge2Sb2Te5 phase-change material

NASA Astrophysics Data System (ADS)

Aladool, A.; Aziz, M. M.; Wright, C. D.

2017-06-01

The crystallization dynamics in the phase-change material Ge2Sb2Te5 is modelled using the more detailed Master equation method over a wide range of heating rates commensurate with published ultrafast calorimetry experiments. Through the attachment and detachment of monomers, the Master rate equation naturally traces nucleation and growth of crystallites with temperature history to calculate the transient distribution of cluster sizes in the material. Both the attachment and detachment rates in this theory are strong functions of viscosity, and thus, the value of viscosity and its dependence on temperature significantly affect the crystallization process. In this paper, we use the physically realistic Mauro-Yue-Ellison-Gupta-Allan viscosity model in the Master equation approach to study the role of the viscosity model parameters on the crystallization dynamics in Ge2Sb2Te5 under ramped annealing conditions with heating rates up to 4 × 104 K/s. Furthermore, due to the relatively low computational cost of the Master equation method compared to atomistic level computations, an iterative numerical approach was developed to fit theoretical Kissinger plots simulated with the Master equation system to experimental Kissinger plots from ultrafast calorimetry measurements at increasing heating rates. This provided a more rigorous method (incorporating both nucleation and growth processes) to extract the viscosity model parameters from the analysis of experimental data. The simulations and analysis revealed the strong coupling between the glass transition temperature and fragility index in the viscosity and crystallization models and highlighted the role of the dependence of the glass transition temperature on the heating rate for the accurate estimation of the fragility index of phase-change materials from the analysis of experimental measurements.

Temperature Dependence of Density, Viscosity and Electrical Conductivity for Hg-Based II-VI Semiconductor Melts

NASA Technical Reports Server (NTRS)

Li, C.; Ban, H.; Lin, B.; Scripa, R. N.; Su, C.-H.; Lehoczky, S. L.

2004-01-01

The relaxation phenomenon of semiconductor melts, or the change of melt structure with time, impacts the crystal growth process and the eventual quality of the crystal. The thermophysical properties of the melt are good indicators of such changes in melt structure. Also, thermophysical properties are essential to the accurate predication of the crystal growth process by computational modeling. Currently, the temperature dependent thermophysical property data for the Hg-based II-VI semiconductor melts are scarce. This paper reports the results on the temperature dependence of melt density, viscosity and electrical conductivity of Hg-based II-VI compounds. The melt density was measured using a pycnometric method, and the viscosity and electrical conductivity were measured by a transient torque method. Results were compared with available published data and showed good agreement. The implication of the structural changes at different temperature ranges was also studied and discussed.

Temperature Dependence of the Viscosity of Isotropic Liquids

NASA Astrophysics Data System (ADS)

Jadzyn, J.; Czechowski, G.; Lech, T.

1999-04-01

Temperature dependence of the shear viscosity measured for isotropic liquids belonging to the three homologous series: 4-(trans-4'-n-alkylcyclohexyl) isothiocyanatobenzenes (Cn H2n+1 CyHx Ph NCS; nCHBT, n=0-12), n-alkylcyanobiphenyls (CnH2n+1 Ph Ph CN; nCB, n=2-12) and 1,n-alkanediols (HO(CH2)nOH; 1,nAD, n=2-10) were analysed with the use of Arrhenius equation and its two modifications: Vogel--Fulcher and proposed in this paper. The extrapolation of the isothermal viscosity of 1,n-alkanediols (n=2-10) to n=1 leads to an interesting conclusion concerning the expected viscosity of methanediol, HOCH2OH, the compound strongly unstable in a pure state.

Density, Viscosity and Surface Tension of Binary Mixtures of 1-Butyl-1-Methylpyrrolidinium Tricyanomethanide with Benzothiophene.

PubMed

Domańska, Urszula; Królikowska, Marta; Walczak, Klaudia

2014-01-01

The effects of temperature and composition on the density and viscosity of pure benzothiophene and ionic liquid (IL), and those of the binary mixtures containing the IL 1-butyl-1-methylpyrrolidynium tricyanomethanide ([BMPYR][TCM] + benzothiophene), are reported at six temperatures (308.15, 318.15, 328.15, 338.15, 348.15 and 358.15) K and ambient pressure. The temperature dependences of the density and viscosity were represented by an empirical second-order polynomial and by the Vogel-Fucher-Tammann equation, respectively. The density and viscosity variations with compositions were described by polynomials. Excess molar volumes and viscosity deviations were calculated and correlated by Redlich-Kister polynomial expansions. The surface tensions of benzothiophene, pure IL and binary mixtures of ([BMPYR][TCM] + benzothiophene) were measured at atmospheric pressure at four temperatures (308.15, 318.15, 328.15 and 338.15) K. The surface tension deviations were calculated and correlated by a Redlich-Kister polynomial expansion. The temperature dependence of the interfacial tension was used to evaluate the surface entropy, the surface enthalpy, the critical temperature, the surface energy and the parachor for pure IL. These measurements have been provided to complete information of the influence of temperature and composition on physicochemical properties for the selected IL, which was chosen as a possible new entrainer in the separation of sulfur compounds from fuels. A qualitative analysis on these quantities in terms of molecular interactions is reported. The obtained results indicate that IL interactions with benzothiophene are strongly dependent on packing effects and hydrogen bonding of this IL with the polar solvent.

Toward unraveling a secret of the lower mantle: Detecting and characterizing piles using a grain size-dependent, composite rheology

NASA Astrophysics Data System (ADS)

Schierjott, Jana; Rozel, Antoine; Tackley, Paul

2017-04-01

Seismic studies show two antipodal regions of low shear velocity at the core-mantle boundary (CMB), one beneath the Pacific and one beneath Africa. These regions, called Large Low Shear Velocity Provinces (LLSVPs), are thought to be thermally and chemically distinct and thus have a different density and viscosity. Whereas there is some general consensus about the density of the LLSVPs, their viscosity is still debated. So far, in numerical studies the viscosity is treated as either depth- and/or temperature- dependent but the potential grain size-dependence of the viscosity is neglected most of the time. In this study we use a self-consistent convection model which includes a grain size- dependent rheology based on the approach by Rozel et al. (2011). Further, we consider a basal primordial layer and a time-dependent basalt production to dynamically form the present-day chemical heterogeneities, similar to earlier studies, e.g by Nakagawa & Tackley (2014). Our study comprises three main parts: 1) We perform a parameter study which includes different densities and viscosities of the imposed primordial layer. 2) We detect possible piles and compute their average effective viscosity, density, rheology and grain size. 3) We test the influence of grain size evolution on the development and morphology of piles and compare it to non-grain size models. Our preliminary results show that a higher density and/or viscosity of the piles is needed to keep them at the core-mantle boundary (CMB). Relatively to the ambient mantle grain size is high in the piles but due to the temperature at the CMB the viscosity is not remarkably different than the one of ordinary plumes. We observe that grain size is lower if the density of the imposed primordial material is lower than basalt. In that case the average temperature of the pile is also reduced. Interestingly, changing the reference viscosity is responsible for a change in the average viscosity of the pile but not for a different average grain size.

Temperature-Dependent Conformations of Model Viscosity Index Improvers

DOE Office of Scientific and Technical Information (OSTI.GOV)

Ramasamy, Uma Shantini; Cosimbescu, Lelia; Martini, Ashlie

2015-05-01

Lubricants are comprised of base oils and additives where additives are chemicals that are deliberately added to the oil to enhance properties and inhibit degradation of the base oils. Viscosity index (VI) improvers are an important class of additives that reduce the decline of fluid viscosity with temperature [1], enabling optimum lubricant performance over a wider range of operating temperatures. These additives are typically high molecular weight polymers, such as, but not limited to, polyisobutylenes, olefin copolymer, and polyalkylmethacrylates, that are added in concentrations of 2-5% (w/w). Appropriate polymers, when dissolved in base oil, expand from a coiled to anmore » uncoiled state with increasing temperature [2]. The ability of VI additives to increase their molar volume and improve the temperature-viscosity dependence of lubricants suggests there is a strong relationship between molecular structure and additive functionality [3]. In this work, we aim to quantify the changes in polymer size with temperature for four polyisobutylene (PIB) based molecular structures at the nano-scale using molecular simulation tools. As expected, the results show that the polymers adopt more conformations at higher temperatures, and there is a clear indication that the expandability of a polymer is strongly influenced by molecular structure.« less

Investigation of instability of displacement front in non-isothermal flow problems

NASA Astrophysics Data System (ADS)

Syulyukina, Natalia; Pergament, Anna

2012-11-01

In this paper, we investigate the issues of front instability arising in non-isothermal flow displacement processes. The problem of two-phase flow of immiscible fluids, oil and water, is considered, including sources and dependence of viscosity on temperature. Three-dimensional problem with perturbation close to the injection well was considered to find the characteristic scale of the instability. As a result of numerical calculations, theoretical studies on the development of the instability due to the fact that the viscosity of the displacing fluid is less than the viscosity of the displaced have been confirmed. The influence of temperature on the evolution of the instability was considered. For this purpose, the dependence of oil viscosity on temperature has been added to the problem. Numerical calculations were carried out for different values of temperature and it was shown that with increasing of production rate. Thus, it has been demonstrated that the selection of the optimal temperature for injected fluids a possible way for stimulation of oil production also delaying the field water-flooding. This work was supporting by the RFBR grant 12-01-00793-a.

Plate-like convection in fluids with temperature-dependent viscosity

NASA Astrophysics Data System (ADS)

Curbelo, J.; Mancho, A. M.

2015-12-01

The study of instabilities in fluids in which viscosity experiences a transition at a certain temperature range is of great interest for the understanding of planetary interiors, since this phenomena is suitable for representing a very viscous lithosphere (and thus rather rigid) over a convecting mantle. To this end, we study a 2D convection problem in which viscosity depends on temperature by abruptly changing its value within a narrow temperature gap. Notable solutions are found for a sharp transition viscosity law which are fundamentally related to the presence of a symmetry in the problem. For instance, cyclic series are found consisting of spontaneous plate-like behaviors emerging sporadically through abrupt bursts, and rapidly evolving towards a stagnant lid regime. The plate-like evolution alternates motions towards either right or left, introducing temporary asymmetries on the convecting styles. Further time-dependent regimes with stagnant and plate-like lids are described, which are also greatly influenced by the presence of the symmetry. These results provide convection examples of moving plates, that coexist with subsurface upwards and downwards meandering jets, but without a proper subduction, and can be particularly illustrative for understanding convective styles of the Earth prior to subduction, or that of other planetary bodies.

Fractional time-dependent apparent viscosity model for semisolid foodstuffs

NASA Astrophysics Data System (ADS)

Yang, Xu; Chen, Wen; Sun, HongGuang

2017-10-01

The difficulty in the description of thixotropic behaviors in semisolid foodstuffs is the time dependent nature of apparent viscosity under constant shear rate. In this study, we propose a novel theoretical model via fractional derivative to address the high demand by industries. The present model adopts the critical parameter of fractional derivative order α to describe the corresponding time-dependent thixotropic behavior. More interestingly, the parameter α provides a quantitative insight into discriminating foodstuffs. With the re-exploration of three groups of experimental data (tehineh, balangu, and natillas), the proposed methodology is validated in good applicability and efficiency. The results show that the present fractional apparent viscosity model performs successfully for tested foodstuffs in the shear rate range of 50-150 s^{ - 1}. The fractional order α decreases with the increase of temperature at low temperature, below 50 °C, but increases with growing shear rate. While the ideal initial viscosity k decreases with the increase of temperature, shear rate, and ingredient content. It is observed that the magnitude of α is capable of characterizing the thixotropy of semisolid foodstuffs.

Computing the Viscosity of Supercooled Liquids: Markov Network Model

PubMed Central

Li, Ju; Kushima, Akihiro; Eapen, Jacob; Lin, Xi; Qian, Xiaofeng; Mauro, John C.; Diep, Phong; Yip, Sidney

2011-01-01

The microscopic origin of glass transition, when liquid viscosity changes continuously by more than ten orders of magnitude, is challenging to explain from first principles. Here we describe the detailed derivation and implementation of a Markovian Network model to calculate the shear viscosity of deeply supercooled liquids based on numerical sampling of an atomistic energy landscape, which sheds some light on this transition. Shear stress relaxation is calculated from a master-equation description in which the system follows a transition-state pathway trajectory of hopping among local energy minima separated by activation barriers, which is in turn sampled by a metadynamics-based algorithm. Quantitative connection is established between the temperature variation of the calculated viscosity and the underlying potential energy and inherent stress landscape, showing a different landscape topography or “terrain” is needed for low-temperature viscosity (of order 107 Pa·s) from that associated with high-temperature viscosity (10−5 Pa·s). Within this range our results clearly indicate the crossover from an essentially Arrhenius scaling behavior at high temperatures to a low-temperature behavior that is clearly super-Arrhenius (fragile) for a Kob-Andersen model of binary liquid. Experimentally the manifestation of this crossover in atomic dynamics continues to raise questions concerning its fundamental origin. In this context this work explicitly demonstrates that a temperature-dependent “terrain” characterizing different parts of the same potential energy surface is sufficient to explain the signature behavior of vitrification, at the same time the notion of a temperature-dependent effective activation barrier is quantified. PMID:21464988

Temperature dependence of internal friction in enzyme reactions.

PubMed

Rauscher, Anna Á; Simon, Zoltán; Szöllosi, Gergely J; Gráf, László; Derényi, Imre; Malnasi-Csizmadia, Andras

2011-08-01

Our aim was to elucidate the physical background of internal friction of enzyme reactions by investigating the temperature dependence of internal viscosity. By rapid transient kinetic methods, we directly measured the rate constant of trypsin 4 activation, which is an interdomain conformational rearrangement, as a function of temperature and solvent viscosity. We found that the apparent internal viscosity shows an Arrhenius-like temperature dependence, which can be characterized by the activation energy of internal friction. Glycine and alanine mutations were introduced at a single position of the hinge of the interdomain region to evaluate how the flexibility of the hinge affects internal friction. We found that the apparent activation energies of the conformational change and the internal friction are interconvertible parameters depending on the protein flexibility. The more flexible a protein was, the greater proportion of the total activation energy of the reaction was observed as the apparent activation energy of internal friction. Based on the coupling of the internal and external movements of the protein during its conformational change, we constructed a model that quantitatively relates activation energy, internal friction, and protein flexibility.

Application of SEAWAT to select variable-density and viscosity problems

USGS Publications Warehouse

Dausman, Alyssa M.; Langevin, Christian D.; Thorne, Danny T.; Sukop, Michael C.

2010-01-01

SEAWAT is a combined version of MODFLOW and MT3DMS, designed to simulate three-dimensional, variable-density, saturated groundwater flow. The most recent version of the SEAWAT program, SEAWAT Version 4 (or SEAWAT_V4), supports equations of state for fluid density and viscosity. In SEAWAT_V4, fluid density can be calculated as a function of one or more MT3DMS species, and optionally, fluid pressure. Fluid viscosity is calculated as a function of one or more MT3DMS species, and the program also includes additional functions for representing the dependence of fluid viscosity on temperature. This report documents testing of and experimentation with SEAWAT_V4 with six previously published problems that include various combinations of density-dependent flow due to temperature variations and/or concentration variations of one or more species. Some of the problems also include variations in viscosity that result from temperature differences in water and oil. Comparisons between the results of SEAWAT_V4 and other published results are generally consistent with one another, with minor differences considered acceptable.

Variable Viscosity Effects on Time Dependent Magnetic Nanofluid Flow past a Stretchable Rotating Plate

NASA Astrophysics Data System (ADS)

Ram, Paras; Joshi, Vimal Kumar; Sharma, Kushal; Walia, Mittu; Yadav, Nisha

2016-01-01

An attempt has been made to describe the effects of geothermal viscosity with viscous dissipation on the three dimensional time dependent boundary layer flow of magnetic nanofluids due to a stretchable rotating plate in the presence of a porous medium. The modelled governing time dependent equations are transformed a from boundary value problem to an initial value problem, and thereafter solved by a fourth order Runge-Kutta method in MATLAB with a shooting technique for the initial guess. The influences of mixed temperature, depth dependent viscosity, and the rotation strength parameter on the flow field and temperature field generated on the plate surface are investigated. The derived results show direct impact in the problems of heat transfer in high speed computer disks (Herrero et al. [1]) and turbine rotor systems (Owen and Rogers [2]).

Viscosity of Industrially Important Zn-Al Alloys Part II: Alloys with Higher Contents of Al and Si

NASA Astrophysics Data System (ADS)

Nunes, V. M. B.; Queirós, C. S. G. P.; Lourenço, M. J. V.; Santos, F. J. V.; Nieto de Castro, C. A.

2018-05-01

The viscosity of Zn-Al alloys melts, with industrial interest, was measured for temperatures between 693 K and 915 K, with an oscillating cup viscometer, and estimated expanded uncertainties between 3 and 5 %, depending on the alloy. The influence of minor components, such as Si, Mg and Ce + La, on the viscosity of the alloys is discussed. An increase in the amount of Mg triggers complex melt/solidification processes while the addition of Ce and La renders alloys viscosity almost temperature independent. Furthermore, increases in Al and Si contents decrease melts viscosity and lead to an Arrhenius type behavior. This paper complements a previous study describing the viscosity of Zn-Al alloys with quasi-eutectic compositions.

Temperature dependent viscosity of cobalt ferrite / ethylene glycol ferrofluids

NASA Astrophysics Data System (ADS)

Kharat, Prashant B.; Somvanshi, Sandeep B.; Kounsalye, Jitendra S.; Deshmukh, Suraj S.; Khirade, Pankaj P.; Jadhav, K. M.

2018-04-01

In the present work, cobalt ferrite / ethylene glycol ferrofluid is prepared in 0 to 1 (in the step of 0.2) volume fraction of cobalt ferrite nanoparticles synthesized by co-precipitation method. The XRD results confirmed the formation of single phase spinel structure. The Raman spectra have been deconvoluted into individual Lorentzian peaks. Cobalt ferrite has cubic spinel structure with Fd3m space group. FT-IR spectra consist of two major absorption bands, first at about 586 cm-1 (υ1) and second at about 392 cm-1 (υ2). These absorption bands confirm the formation of spinel-structured cobalt ferrite. Brookfield DV-III viscometer and programmable temperature-controlled bath was used to study the relationship between viscosity and temperature. Viscosity behavior with respect to temperature has been studied and it is revealed that the viscosity of cobalt ferrite / ethylene glycol ferrofluids increases with an increase in volume fraction of cobalt ferrite. The viscosity of the present ferrofluid was found to decrease with increase in temperature.

Analytical studies into radiation-induced starch damage in black and white peppers

NASA Astrophysics Data System (ADS)

Sharif, M. M.; Farkas, J.

1993-07-01

Temperature dependency of the apparent viscosity of heat-gelatinized suspensions of untreated and irradiated pepper samples has been investigated. There was a close linear correlation between the logaritm of "fluidity" /reciprocal of the apparent viscosity) and the reciprocal absolute temperature of the measurement. The slope of the regression line(the temperature dependence of fluidity) increased with the radiation dose. Gelatinization thermograms of aqueous suspensions of ground pepper samples were obtained by differential scanning calorimetry. Temperature characteristics of heat-gelatinization endotherms showed no significant differences between untreated and irradiated samples. A colorimetric method for damaged starch, the estimation of reducing power, and the alcohol-induced turbidity of aqueous extracts showed statistically significant increases of starch damage at doses higher than 4 kGy. These indices of starch-depolymerization have been changed less dramatically by irradiation than the apparent viscosity of the heat-gelatinized suspensions.

Moving Forward to Constrain the Shear Viscosity of QCD Matter

DOE PAGES

Denicol, Gabriel; Monnai, Akihiko; Schenke, Björn

2016-05-26

In this work, we demonstrate that measurements of rapidity differential anisotropic flow in heavy-ion collisions can constrain the temperature dependence of the shear viscosity to entropy density ratio η/s of QCD matter. Comparing results from hydrodynamic calculations with experimental data from the RHIC, we find evidence for a small η/s ≈ 0.04 in the QCD crossover region and a strong temperature dependence in the hadronic phase. A temperature independent η/s is disfavored by the data. We further show that measurements of the event-by-event flow as a function of rapidity can be used to independently constrain the initial state fluctuations inmore » three dimensions and the temperature dependent transport properties of QCD matter.« less

Density, Electrical Conductivity and Viscosity of Hg(0.8)Cd(0.2)Te Melt

NASA Technical Reports Server (NTRS)

Li, C.; Scripa, R. N.; Ban, H.; Su, C.-H.; Lehoczky, S. L.

2004-01-01

The density, viscosity, and electrical conductivity of Hg(0.8)Cd(0.2)Te melt were measured as a function of temperature. A pycnometric method was used to measure the melt density in the temperature range of 1072 to 1122 K. The viscosity and electrical conductivity were determined using a transient torque method from 1068 to 1132 K. The density result from this study is within 0.3% of the published data. However, the current viscosity result is approximately 30% lower than the existing data. The electrical conductivity of Hg(0.8)Cd(0.2)Te melt as a function of temperature, which is not available in the literature, is also determined. The analysis of the temperature dependent electrical conductivity and the relationship between the kinematic viscosity and density indicated that the structure of the melt appeared to be homogeneous when the temperature was above 1090 K. A structural transition occurred in the Hg(0.8)Cd(0.2)Te melt as the temperature was decreased to below 1090 K

Density, Electrical Conductivity and Viscosity of Hg(sub 0.8)Cd(sub 0.2)Te Melt

NASA Technical Reports Server (NTRS)

Li, C.; Scripa, R. N.; Ban, H.; Lin, B.; Su, C.-H.; Lehoczky, S. L.

2004-01-01

The density, viscosity, and electrical conductivity of Hg(sub 0.8)Cd(sub 0.2)Te melt were measures as a function of temperature. A pycnometric method was used to measure the melt density in the temperature range of 1072 to 1122 K. The viscosity and electrical conductivity were determined using a transient torque method from 1068 to 1132 K. The density result from this study is within 0.3% of the published data. However, the current viscosity result is approximately 30% lower than the existing data. The electrical conductivity of Hg(sub 0.8)Cd(sub 0.2)Te melt as a function of temperature, which is not available in the literature, is also determined. The analysis of the temperature dependent electrical conductivity and the relationship between the kinematic viscosity and density indicated that the structure of the melt appeared to be homogeneous when the temperature was above 1090 K. A structural transition occurred in the Hg(sub 0.8)Cd(sub 0.2)Te melt as the temperature was decreased to below 1090 K.

Density, refractive index, interfacial tension, and viscosity of ionic liquids [EMIM][EtSO4], [EMIM][NTf2], [EMIM][N(CN)2], and [OMA][NTf2] in dependence on temperature at atmospheric pressure.

PubMed

Fröba, Andreas P; Kremer, Heiko; Leipertz, Alfred

2008-10-02

The density, refractive index, interfacial tension, and viscosity of ionic liquids (ILs) [EMIM][EtSO 4] (1-ethyl-3-methylimidazolium ethylsulfate), [EMIM][NTf 2] (1-ethyl-3-methylimidazolium bis(trifluoromethylsulfonyl)imide), [EMIM][N(CN) 2] (1-ethyl-3-methylimidazolium dicyanimide), and [OMA][NTf 2] (trioctylmethylammonium bis(trifluoromethylsulfonyl)imide) were studied in dependence on temperature at atmospheric pressure both by conventional techniques and by surface light scattering (SLS). A vibrating tube densimeter was used for the measurement of density at temperatures from (273.15 to 363.15) K and the results have an expanded uncertainty ( k = 2) of +/-0.02%. Using an Abbe refractometer, the refractive index was measured for temperatures between (283.15 and 313.15) K with an expanded uncertainty ( k = 2) of about +/-0.0005. The interfacial tension was obtained from the pendant drop technique at a temperature of 293.15 K with an expanded uncertainty ( k = 2) of +/-1%. For higher and lower temperatures, the interfacial tension was estimated by an adequate prediction scheme based on the datum at 293.15 K and the temperature dependence of density. For the ILs studied within this work, at a first order approximation, the quantity directly accessible by the SLS technique was the ratio of surface tension to dynamic viscosity. By combining the experimental results of the SLS technique with density and interfacial tension from conventional techniques, the dynamic viscosity could be obtained for temperatures between (273.15 and 333.15) K with an estimated expanded uncertainty ( k = 2) of less than +/-3%. The measured density, refractive index, and viscosity are represented by interpolating expressions with differences between the experimental and calculated values that are comparable with but always smaller than the expanded uncertainties ( k = 2). Besides a comparison with the literature, the influence of structural variations on the thermophysical properties of the ILs is discussed in detail. The viscosities mostly agree with values reported in the literature within the combined estimated expanded uncertainties ( k = 2) of the measurements while our density and interfacial tension data differ by more than +/-1% and +/-5%.

Assessing the role of slab rheology in coupled plate-mantle convection models

NASA Astrophysics Data System (ADS)

Bello, Léa; Coltice, Nicolas; Tackley, Paul J.; Dietmar Müller, R.; Cannon, John

2015-11-01

Reconstructing the 3D structure of the Earth's mantle has been a challenge for geodynamicists for about 40 yr. Although numerical models and computational capabilities have substantially progressed, parameterizations used for modeling convection forced by plate motions are far from being Earth-like. Among the set of parameters, rheology is fundamental because it defines in a non-linear way the dynamics of slabs and plumes, and the organization of lithosphere deformation. In this study, we evaluate the role of the temperature dependence of viscosity (variations up to 6 orders of magnitude) and the importance of pseudo-plasticity on reconstructing slab evolution in 3D spherical models of convection driven by plate history models. Pseudo-plasticity, which produces plate-like behavior in convection models, allows a consistent coupling between imposed plate motions and global convection, which is not possible with temperature-dependent viscosity alone. Using test case models, we show that increasing temperature dependence of viscosity enhances vertical and lateral coherence of slabs, but leads to unrealistic slab morphologies for large viscosity contrasts. Introducing pseudo-plasticity partially solves this issue, producing thin laterally and vertically more continuous slabs, and flat subduction where trench retreat is fast. We evaluate the differences between convection reconstructions employing different viscosity laws to be very large, and similar to the differences between two models with the same rheology but using two different plate histories or initial conditions.

Reference Correlation for the Viscosity of Carbon Dioxide

NASA Astrophysics Data System (ADS)

Laesecke, Arno; Muzny, Chris D.

2017-03-01

A comprehensive database of experimental and computed data for the viscosity of carbon dioxide (CO2) was compiled and a new reference correlation was developed. Literature results based on an ab initio potential energy surface were the foundation of the correlation of the viscosity in the limit of zero density in the temperature range from 100 to 2000 K. Guided symbolic regression was employed to obtain a new functional form that extrapolates correctly to 0 and to 10 000 K. Coordinated measurements at low density made it possible to implement the temperature dependence of the Rainwater-Friend theory in the linear-in-density viscosity term. The residual viscosity could be formulated with a scaling term ργ/T, the significance of which was confirmed by symbolic regression. The final viscosity correlation covers temperatures from 100 to 2000 K for gaseous CO2 and from 220 to 700 K with pressures along the melting line up to 8000 MPa for compressed and supercritical liquid states. The data representation is more accurate than with the previous correlations, and the covered pressure and temperature range is significantly extended. The critical enhancement of the viscosity of CO2 is included in the new correlation.

Oxidation-state dependence of rheology in peralkaline glasses of phonolitic composition

NASA Astrophysics Data System (ADS)

Scherrer, M. C.; Hess, K.-U.; Fehr, K. T.; Dingwell, D. B.

2012-04-01

The precise description of magmatic melts rheology at the glass transition is crucial in understanding dynamic processes in volcanology. The glass transition has been described to scale with the viscosity of the material according to Maxwell's relaxation theory for viscoelastic liquids (Dingwell and Webb, 1989). The temperature dependence of the viscosity of multi-component systems can adequately be calculated using empirical models such as Hess et al. (1996), Giordano et al. (2008) and Hui and Zhang (2008); yet, within these calculations, the influence of oxidation state has been so far considered minor and was consequently neglected. The rheological behavior of some iron-rich silicate melts has shown noteworthy oxidation state-dependent variations (Cukierman and Uhlmann 1974, Dingwell and Virgo 1987). The focus of our study is to improve the viscosity models by investigating the necessity of an additional redox-parameter. Thirteen re-melted glass samples of natural phonolitic composition (peralkaline lavas with 8.5 wt. % FeOtot) were produced under different oxygen fugacity (fO2) conditions in a CO/CO2 gas-mixing furnace. Their oxidation-state (Fe3+/Fetot) ranges from 0.44 to 0.93 (±0.05). The viscosity above the liquidus was recorded via the concentric cylinder technique at a constant temperature of 1186 ° C. Additionally, viscosities were measured in the interval of 107to 1011Pa swith temperatures up to 900 ° C at ambient pressure via a BAEHR micro-penetration viscometer. Glass transition temperatures (Tg) have been determined with a constant heating/cooling rate of 10K/min on a SETARAM Sensys evo DSC using the peak of the specific heat capacity curve. Under a constant temperature in the super-liquidus state, the viscosity increases strongly with increasing fO2. In the sub-liquidus state, the measured calorimetric Tgis shifted to lower temperatures as the ratio of ferrous/total iron decreases from 638 ° C to 610 ° C. However, there is no equivalent measurable effect of the oxidation-state on super-cooled melt viscosity at Tg, within the precision of the micro-penetration experiment (all values are scattered around 10.10 ± 0.2 Pa s). Our results show a large discrepancy of 0.5 log units compared to the predicted viscosity at Tg using the kinetic model of Gottsmann et al. (2002). We further investigate additional relatively iron-rich compositions aiming for the development of an improved model for the viscosity prediction at the glass transition.

Properties of sugar-based low-melting mixtures

NASA Astrophysics Data System (ADS)

Fischer, Veronika; Kunz, Werner

2014-05-01

Physico-chemical properties of ternary sugar-based low-melting mixtures were determined. Choline chloride, urea and glucose or sorbitol, serving as sugars, were blended in various compositions. The refractive index, density, viscosity, decomposition temperatures and glass transition temperatures were measured. Further, the influence of temperature and water content was investigated. The results show that the mixtures are liquid below room temperature and the viscosity and density are dependent on the temperature and composition. Moreover, the viscosity decreases with increasing water content. These mixtures are biodegradable, low toxic, non-volatile, non-reactive with water and can be accomplished with low-cost materials. In consideration of these advantages and a melting point below room temperature, these low-melting mixtures can be a good alternative to ionic liquids as well as environmentally unfriendly and toxic solvents.

Steady and dynamic shear rheological behavior of semi dilute Alyssum homolocarpum seed gum solutions: influence of concentration, temperature and heating-cooling rate.

PubMed

Alaeddini, Behzad; Koocheki, Arash; Mohammadzadeh Milani, Jafar; Razavi, Seyed Mohammad Ali; Ghanbarzadeh, Babak

2018-05-01

Alyssum homolocarpum seed gum (AHSG) solution exhibits high viscosity at low shear rates and has anionic features. However there is no information regarding the flow and dynamic properties of this gum in semi-dilute solutions. The present study aimed to investigate the dynamic and steady shear behavior of AHSG in the semi-dilute region. The viscosity profile demonestrated a shear thinning behavior at all temperatures and concentrations. An increase in the AHSG concentration was acompanied by an increase in the pseudoplasticity degree, whereas, by increasing the temperature, the pseudoplasticity of AHSG decreased. At low gum concentration, solutions had more viscosity dependence on temperature. The mechanical spectra obtained from the frequency sweep experiment demonstrated viscoelastic properties for gum solutions. AHSG solutions showed typical weak gel-like behavior, revealing G' greater than G' within the experimental range of frequency (Hz), with slight frequency dependency. The influence of temperature on viscoelastic properties of AHSG solutions was studied during both heating (5-85 °C) and cooling (85-5 °C) processes. The complex viscosity of AHSG was greater compared to the apparent viscosity, indicating the disruption of AHSG network structure under continuous shear rates and deviation from the Cox-Merz rule. During the initial heating, the storage modulus showed a decreasing trend and, with a further increase in temperature, the magnitude of storage modulus increased. The influence of temperature on the storage modulus was considerable when a higher heating rate was applied. AHSG can be applied as a thickening and stabilizing agents in food products that require good stability against temperature. © 2017 Society of Chemical Industry. © 2017 Society of Chemical Industry.

Oceanic lithosphere and asthenosphere - Thermal and mechanical structure

NASA Technical Reports Server (NTRS)

Schubert, G.; Yuen, D. A.; Froidevaux, C.

1976-01-01

A coupled thermomechanical subsolidus model of the oceanic lithosphere and asthenosphere is developed which includes vertical heat conduction, a temperature-dependent thermal conductivity, heat advection by a horizontal and vertical mass flow that depends on depth and age, contributions of viscous dissipation or shear heating, a linear or nonlinear deformation law relating shear stress and strain rate, as well as a temperature- and pressure-dependent viscosity. The model requires a constant horizontal velocity and temperature at the surface, but zero horizontal velocity and constant temperature at great depths. The depth- and age-dependent temperature, horizontal and vertical velocities, and viscosity structure of the lithosphere and asthenosphere are determined along with the age-dependent shear stress in those two zones. The ocean-floor topography, oceanic heat flow, and lithosphere thickness are deduced as functions of ocean-floor age; seismic velocity profiles which exhibit a marked low-velocity zone are constructed from the age-dependent geotherms and assumed values of the elastic parameters. It is found that simple boundary-layer cooling determines the thermal structure at young ages, while effects of viscous dissipation become more important at older ages.

Viscous properties of isotropic fluids composed of linear molecules: departure from the classical Navier-Stokes theory in nano-confined geometries.

PubMed

Hansen, J S; Daivis, Peter J; Todd, B D

2009-10-01

In this paper we present equilibrium molecular-dynamics results for the shear, rotational, and spin viscosities for fluids composed of linear molecules. The density dependence of the shear viscosity follows a stretched exponential function, whereas the rotational viscosity and the spin viscosities show approximately power-law dependencies. The frequency-dependent shear and spin viscosities are also studied. It is found that viscoelastic behavior is first manifested in the shear viscosity and that the real part of the spin viscosities features a maximum for nonzero frequency. The calculated transport coefficients are used together with the extended Navier-Stokes equations to investigate the effect of the coupling between the intrinsic angular momentum and linear momentum for highly confined fluids. Both steady and oscillatory flows are studied. It is shown, for example, that the fluid flow rate for Poiseuille flow is reduced by up to 10% in a 2 nm channel for a buta-triene fluid at density 236 kg m(-3) and temperature 306 K. The coupling effect may, therefore, become very important for nanofluidic applications.

Reference Correlation for the Viscosity of Carbon Dioxide1

PubMed Central

Laesecke, Arno; Muzny, Chris D.

2017-01-01

A comprehensive database of experimental and computed data for the viscosity of carbon dioxide (CO2) was compiled and a new reference correlation was developed. Literature results based on an ab initio potential energy surface were the foundation of the correlation of the viscosity in the limit of zero density in the temperature range from 100 K to 2000 K. Guided symbolic regression was employed to obtain a new functional form that extrapolates correctly to T → 0 K and to 10 000 K. Coordinated measurements at low density made it possible to implement the temperature dependence of the Rainwater-Friend theory in the linear-in-density viscosity term. The residual viscosity could be formulated with a scaling term ργ/T the significance of which was confirmed by symbolic regression. The final viscosity correlation covers temperatures from 100 K to 2000 K for gaseous CO2, and from 220 K to 700 K with pressures along the melting line up to 8000 MPa for compressed and supercritical liquid states. The data representation is more accurate than with the previous correlations, and the covered pressure and temperature range is significantly extended. The critical enhancement of the viscosity of CO2 is included in the new correlation. PMID:28736460

Comparison of High-Speed Operating Characteristics of Size 215 Cylindrical-Roller Bearings as Determined in Turbojet Engine and in Laboratory Test Rig

NASA Technical Reports Server (NTRS)

Macks, E Fred; Nemeth, Zolton N

1951-01-01

A comparison of the operating characteristics of 75-millimeter-bore (size 215) cylindrical-roller one-piece inner-race-riding cage-type bearings was made using a laboratory test rig and a turbojet engine. Cooling correlation parameters were determined by means of dimensional analysis, and the generalized results for both the inner- and outer-race bearing operating temperatures are compared for the laboratory test rig and the turbojet engine. Inner- and outer-race cooling-correlation curves were obtained for the turbojet-engine turbine-roller bearing with the same inner- and outer-race correlation parameters and exponents as those determined for the laboratory test-rig bearing. The inner- and outer-race turbine roller-bearing temperatures may be predicted from a single curve, regardless of variations in speed, load, oil flow, oil inlet temperature, oil inlet viscosity, oil-jet diameter or any combination of these parameters. The turbojet-engine turbine-roller-bearing inner-race temperatures were 30 to 60 F greater than the outer-race-maximum temperatures, the exact values depending on the operating condition and oil viscosity; these results are in contrast to the laboratory test-rig results where the inner-race temperatures were less than the outer-race-maximum temperatures. The turbojet-engine turbine-roller bearing, maximum outer-race circumferential temperature variation was approximately 30 F for each of the oils used. The effect of oil viscosity on inner- and outer-race turbojet-engine turbine-roller-bearing temperatures was found to be significant. With the lower viscosity oil (6x10(exp -7) reyns (4.9 centistokes) at 100 F; viscosity index, 83), the inner-race temperature was approximately 30 to 35 F less than with the higher viscosity oil (53x10(exp -7) reyns (42.8 centistokes) at 100 F; viscosity index, 150); whereas the outer-race-maximum temperatures were 12 to 28 F lower with the lower viscosity oil over the DN range investigated.

Effect of atmosphere on the surface tension and viscosity of molten LiNbO 3 measured using the surface laser-light scattering method

NASA Astrophysics Data System (ADS)

Nagasaka, Yuji; Kobayashi, Yusuke

2007-09-01

The surface tension and the viscosity of molten LiNbO 3 (LN) having the congruent composition have been measured simultaneously in a temperature range from 1537 to 1756 K under argon gas and dry-air atmospheres. The present measurement technique involves surface laser-light scattering (SLLS) that detects nanometer-order-amplitude surface waves usually regarded as ripplons excited by thermal fluctuations. This technique's non-invasive nature allows it to avoid the experimental difficulties of conventional techniques resulting from the insertion of an actuator in the melt. The results of surface tension measurement obtained under a dry-air atmosphere are about 5% smaller than those obtained under an argon atmosphere near the melting temperature, and the temperature dependence of the surface tension under a dry-air atmosphere is twice that under an argon atmosphere. The uncertainty of surface tension measurement is estimated to be ±2.6% under argon and ±1.9% under dry air. The temperature dependence of viscosity can be well correlated with the results of Arrhenius-type equations without any anomalous behavior near the melting point. The viscosities obtained under a dry-air atmosphere were slightly smaller than those obtained under an argon atmosphere. The uncertainty of viscosity measurement is estimated to be ±11.1% for argon and ±14.3% for dry air. Moreover, we observed the real-time dynamic behavior of the surface tension and the viscosity of molten LN in response to argon and dry-air atmospheres.

Thermal Evolution of Charon and the Major Satellites of Uranus: Constraints on Early Differentiation

NASA Astrophysics Data System (ADS)

Spohn, T.; Multhaup, K.

2007-12-01

A thermal history model developed for medium-sized icy satellites containing silicate rock at low volume fractions is applied to Charon and the satellites of Uranus Ariel, Umbriel, Titania, Oberon and Miranda. The model assumes homogeneously accreted satellites. To calculate the initial temperature profile we assume that infalling planetesimals deposit a fraction h of their kinetic energy as heat at the instantaneous surface of the growing satellites. The parameter h is varied between models. The model continuously checks for convectively unstable shells in the interior by updating the temperature profile and calculating the Rayleigh number and the temperature-dependent viscosity. The viscosity parameter values are taken as those of ice I although the satellites under consideration likely contain admixtures of lighter constituents. Their effects and those of rock on the viscosity are discussed. Convective heat transport is calculated assuming the stagnant lid model for strongly temperature dependent viscosity. In convectively stable regions heat transfer is by conduction with a temperature dependent thermal conductivity. Thermal evolution calculations considering radiogenic heating by the long-lived radiogenic isotopes of U, Th, and K suggest that Ariel, Umbriel, Titania, Oberon and Charon may have started to differentiate after a few hundred million years of evolution. With short-lived isotopes -- if present in sizeable concentrations -- this time will move earlier. Results for Miranda -- the smallest satellite of Uranus -- indicate that it never convected or differentiated if heated by the said long-lived isotopes only. Miranda's interior temperature was found to be not even close to the melting temperatures of reasonable mixtures of water and ammonia. This finding is in contrast to its heavily modified surface and supports theories that propose alternative heating mechanisms such as the decay of short-lived isotopes or early tidal heating.

Thermophysical Properties and Structural Transition of Hg(0.8)Cd(0.2)Te Melt

NASA Technical Reports Server (NTRS)

Li, C.; Scripa, R. N.; Ban, H.; Lin, B.; Su, C.; Lehoczky, S. L.

2004-01-01

Thermophysical properties, namely, density, viscosity, and electrical conductivity of Hg(sub o.8)Cd(sub 0.2)Te melt were measured as a function of temperature. A pycnometric method was used to measure the melt density in the temperature range of 1072 to 1122 K. The viscosity and electrical conductivity were simultaneously determined using a transient torque method from 1068 to 1132 K. The density result from this study is within 0.3% of the published data. However, the current viscosity result is approximately 30% lower than the existing data. The electrical conductivity of Hg(sub o.8)Cd(sub 0.2)Te melt as a function of temperature, which is not available in the literature, is also determined. The analysis of the temperature dependent electrical conductivity and the relationship between the kinematic viscosity and density indicated that the structure of the melt appeared to be homogeneous when the temperature was above 1090 K. A structural transition occurred in the Hg(sub 0.8)Cd(0.2)Te melt as the temperature was decreased from 1090 K to the liquidus temperature.

Nonequilibrium viscosity of glass

NASA Astrophysics Data System (ADS)

Mauro, John C.; Allan, Douglas C.; Potuzak, Marcel

2009-09-01

Since glass is a nonequilibrium material, its properties depend on both composition and thermal history. While most prior studies have focused on equilibrium liquid viscosity, an accurate description of nonequilibrium viscosity is essential for understanding the low temperature dynamics of glass. Departure from equilibrium occurs as a glass-forming system is cooled through the glass transition range. The glass transition involves a continuous breakdown of ergodicity as the system gradually becomes trapped in a subset of the available configurational phase space. At very low temperatures a glass is perfectly nonergodic (or “isostructural”), and the viscosity is described well by an Arrhenius form. However, the behavior of viscosity during the glass transition range itself is not yet understood. In this paper, we address the problem of glass viscosity using the enthalpy landscape model of Mauro and Loucks [Phys. Rev. B 76, 174202 (2007)] for selenium, an elemental glass former. To study a wide range of thermal histories, we compute nonequilibrium viscosity with cooling rates from 10-12 to 1012K/s . Based on these detailed landscape calculations, we propose a simplified phenomenological model capturing the essential physics of glass viscosity. The phenomenological model incorporates an ergodicity parameter that accounts for the continuous breakdown of ergodicity at the glass transition. We show a direct relationship between the nonequilibrium viscosity parameters and the fragility of the supercooled liquid. The nonequilibrium viscosity model is validated against experimental measurements of Corning EAGLE XG™ glass. The measurements are performed using a specially designed beam-bending apparatus capable of accurate nonequilibrium viscosity measurements up to 1016Pas . Using a common set of parameters, the phenomenological model provides an accurate description of EAGLE XG™ viscosity over the full range of measured temperatures and fictive temperatures.

Addition of simultaneous heat and solute transport and variable fluid viscosity to SEAWAT

USGS Publications Warehouse

Thorne, D.; Langevin, C.D.; Sukop, M.C.

2006-01-01

SEAWAT is a finite-difference computer code designed to simulate coupled variable-density ground water flow and solute transport. This paper describes a new version of SEAWAT that adds the ability to simultaneously model energy and solute transport. This is necessary for simulating the transport of heat and salinity in coastal aquifers for example. This work extends the equation of state for fluid density to vary as a function of temperature and/or solute concentration. The program has also been modified to represent the effects of variable fluid viscosity as a function of temperature and/or concentration. The viscosity mechanism is verified against an analytical solution, and a test of temperature-dependent viscosity is provided. Finally, the classic Henry-Hilleke problem is solved with the new code. ?? 2006 Elsevier Ltd. All rights reserved.

On The Stability Of Model Flows For Chemical Vapour Deposition

NASA Astrophysics Data System (ADS)

Miller, Robert

2016-11-01

The flow in a chemical vapour deposition (CVD) reactor is assessed. The reactor is modelled as a flow over an infinite-radius rotating disk, where the mean flow and convective instability of the disk boundary layer are measured. Temperature-dependent viscosity and enforced axial flow are used to model the steep temperature gradients present in CVD reactors and the pumping of the gas towards the disk, respectively. Increasing the temperature-dependence parameter of the fluid viscosity (ɛ) results in an overall narrowing of the fluid boundary layer. Increasing the axial flow strength parameter (Ts) accelerates the fluid both radially and axially, while also narrowing the thermal boundary layer. It is seen that when both effects are imposed, the effects of axial flow generally dominate those of the viscosity temperature dependence. A local stability analysis is performed and the linearized stability equations are solved using a Galerkin projection in terms of Chebyshev polynomials. The neutral stability curves are then plotted for a range of ɛ and Ts values. Preliminary results suggest that increasing Ts has a stabilising effect on both type I and type II stationary instabilities, while small increases in ɛ results in a significant reduction to the critical Reynolds number.

THE INFLUENCE OF PRESSURE-DEPENDENT VISCOSITY ON THE THERMAL EVOLUTION OF SUPER-EARTHS

DOE Office of Scientific and Technical Information (OSTI.GOV)

Stamenkovic, Vlada; Noack, Lena; Spohn, Tilman

2012-03-20

We study the thermal evolution of super-Earths with a one-dimensional (1D) parameterized convection model that has been adopted to account for a strong pressure dependence of the viscosity. A comparison with a 2D spherical convection model shows that the derived parameterization satisfactorily represents the main characteristics of the thermal evolution of massive rocky planets. We find that the pressure dependence of the viscosity strongly influences the thermal evolution of super-Earths-resulting in a highly sluggish convection regime in the lower mantles of those planets. Depending on the effective activation volume and for cooler initial conditions, we observe with growing planetary massmore » even the formation of a conductive lid above the core-mantle boundary (CMB), a so-called CMB-lid. For initially molten planets our results suggest no CMB-lids but instead a hot lower mantle and core as well as sluggish lower mantle convection. This implies that the initial interior temperatures, especially in the lower mantle, become crucial for the thermal evolution-the thermostat effect suggested to regulate the interior temperatures in terrestrial planets does not work for massive planets if the viscosity is strongly pressure dependent. The sluggish convection and the potential formation of the CMB-lid reduce the convective vigor throughout the mantle, thereby affecting convective stresses, lithospheric thicknesses, and heat fluxes. The pressure dependence of the viscosity may therefore also strongly affect the propensity of plate tectonics, volcanic activity, and the generation of a magnetic field of super-Earths.« less

Modified free volume theory of self-diffusion and molecular theory of shear viscosity of liquid carbon dioxide.

PubMed

Nasrabad, Afshin Eskandari; Laghaei, Rozita; Eu, Byung Chan

2005-04-28

In previous work on the density fluctuation theory of transport coefficients of liquids, it was necessary to use empirical self-diffusion coefficients to calculate the transport coefficients (e.g., shear viscosity of carbon dioxide). In this work, the necessity of empirical input of the self-diffusion coefficients in the calculation of shear viscosity is removed, and the theory is thus made a self-contained molecular theory of transport coefficients of liquids, albeit it contains an empirical parameter in the subcritical regime. The required self-diffusion coefficients of liquid carbon dioxide are calculated by using the modified free volume theory for which the generic van der Waals equation of state and Monte Carlo simulations are combined to accurately compute the mean free volume by means of statistical mechanics. They have been computed as a function of density along four different isotherms and isobars. A Lennard-Jones site-site interaction potential was used to model the molecular carbon dioxide interaction. The density and temperature dependence of the theoretical self-diffusion coefficients are shown to be in excellent agreement with experimental data when the minimum critical free volume is identified with the molecular volume. The self-diffusion coefficients thus computed are then used to compute the density and temperature dependence of the shear viscosity of liquid carbon dioxide by employing the density fluctuation theory formula for shear viscosity as reported in an earlier paper (J. Chem. Phys. 2000, 112, 7118). The theoretical shear viscosity is shown to be robust and yields excellent density and temperature dependence for carbon dioxide. The pair correlation function appearing in the theory has been computed by Monte Carlo simulations.

Bulk viscosity of strongly interacting matter in the relaxation time approximation

DOE PAGES

Czajka, Alina; Hauksson, Sigtryggur; Shen, Chun; ...

2018-04-24

Here, we show how thermal mean field effects can be incorporated consistently in the hydrodynamical modeling of heavy-ion collisions. The nonequilibrium correction to the distribution function resulting from a temperature-dependent mass is obtained in a procedure which automatically satisfies the Landau matching condition and is thermodynamically consistent. The physics of the bulk viscosity is studied here for Boltzmann and Bose-Einstein gases within the Chapman-Enskog and 14-moment approaches in the relaxation time approximation. Constant and temperature-dependent masses are considered in turn. It is shown that, in the small mass limit, both methods lead to the same value of the ratio ofmore » the bulk viscosity to its relaxation time. The inclusion of a temperature-dependent mass leads to the emergence of the β λ function in that ratio, and it is of the expected parametric form for the Boltzmann gas, while for the Bose-Einstein case it is affected by the infrared cutoff. This suggests that the relaxation time approximation may be too crude to obtain a reliable form of ς/τ R for gases obeying Bose-Einstein statistics.« less

Bulk viscosity of strongly interacting matter in the relaxation time approximation

DOE Office of Scientific and Technical Information (OSTI.GOV)

Czajka, Alina; Hauksson, Sigtryggur; Shen, Chun

Here, we show how thermal mean field effects can be incorporated consistently in the hydrodynamical modeling of heavy-ion collisions. The nonequilibrium correction to the distribution function resulting from a temperature-dependent mass is obtained in a procedure which automatically satisfies the Landau matching condition and is thermodynamically consistent. The physics of the bulk viscosity is studied here for Boltzmann and Bose-Einstein gases within the Chapman-Enskog and 14-moment approaches in the relaxation time approximation. Constant and temperature-dependent masses are considered in turn. It is shown that, in the small mass limit, both methods lead to the same value of the ratio ofmore » the bulk viscosity to its relaxation time. The inclusion of a temperature-dependent mass leads to the emergence of the β λ function in that ratio, and it is of the expected parametric form for the Boltzmann gas, while for the Bose-Einstein case it is affected by the infrared cutoff. This suggests that the relaxation time approximation may be too crude to obtain a reliable form of ς/τ R for gases obeying Bose-Einstein statistics.« less

Bulk viscosity of strongly interacting matter in the relaxation time approximation

NASA Astrophysics Data System (ADS)

Czajka, Alina; Hauksson, Sigtryggur; Shen, Chun; Jeon, Sangyong; Gale, Charles

2018-04-01

We show how thermal mean field effects can be incorporated consistently in the hydrodynamical modeling of heavy-ion collisions. The nonequilibrium correction to the distribution function resulting from a temperature-dependent mass is obtained in a procedure which automatically satisfies the Landau matching condition and is thermodynamically consistent. The physics of the bulk viscosity is studied here for Boltzmann and Bose-Einstein gases within the Chapman-Enskog and 14-moment approaches in the relaxation time approximation. Constant and temperature-dependent masses are considered in turn. It is shown that, in the small mass limit, both methods lead to the same value of the ratio of the bulk viscosity to its relaxation time. The inclusion of a temperature-dependent mass leads to the emergence of the βλ function in that ratio, and it is of the expected parametric form for the Boltzmann gas, while for the Bose-Einstein case it is affected by the infrared cutoff. This suggests that the relaxation time approximation may be too crude to obtain a reliable form of ζ /τR for gases obeying Bose-Einstein statistics.

A macroscopic model that connects the molar excess entropy of a supercooled liquid near its glass transition temperature to its viscosity.

PubMed

Matsuoka, Hiroshi

2012-11-28

For a deeply supercooled liquid near its glass transition temperature, we suggest a possible way to connect the temperature dependence of its molar excess entropy to that of its viscosity by constructing a macroscopic model, where the deeply supercooled liquid is assumed to be a mixture of solid-like and liquid-like micro regions. In this model, we assume that the mole fraction x of the liquid-like micro regions tends to zero as the temperature T of the liquid is decreased and extrapolated to a temperature T(g)(*), which we assume to be below but close to the lowest glass transition temperature T(g) attainable with the slowest possible cooling rate for the liquid. Without referring to any specific microscopic nature of the solid-like and liquid-like micro regions, we also assume that near T(g), the molar enthalpy of the solid-like micro regions is lower than that of the liquid-like micro regions. We then show that the temperature dependence of x is directly related to that of the molar excess entropy. Close to T(g), we assume that an activated motion of the solid-like micro regions controls the viscosity and that this activated motion is a collective motion involving practically all of the solid-like micro-regions so that the molar activation free energy Δg(a) for the activated motion is proportional to the mole fraction, 1 - x, of the solid-like micro regions. The temperature dependence of the viscosity is thus connected to that of the molar excess entropy s(e) through the temperature dependence of the mole fraction x. As an example, we apply our model to a class of glass formers for which s(e) at temperatures near T(g) is well approximated by s(e) ∝ 1 - T(K)∕T with T(K) < T(g) ≅ T(g)(*) and find their viscosities to be well approximated by the Vogel-Fulcher-Tamman equation for temperatures very close to T(g). We also find that a parameter a appearing in the temperature dependence of x for a glass former in this class is a measure for its fragility. As this class includes both fragile and strong glass formers, our model applies to both fragile and strong glass formers. We estimate the values of three parameters in our model for three glass formers in this class, o-terphenyl, 3-bromopentane, and Pd(40)Ni(40)P(20), which is the least fragile among these three. Finally, we also suggest a way to test our assumption about the solid-like and liquid-like micro regions by means of molecular dynamics simulations of model liquids.

Phenomenological and statistical analyses of turbulence in forced convection with temperature-dependent viscosity under non-Boussinesq condition.

PubMed

Yahya, S M; Anwer, S F; Sanghi, S

2013-10-01

In this work, Thermal Large Eddy Simulation (TLES) is performed to study the behavior of weakly compressible Newtonian fluids with anisotropic temperature-dependent viscosity in forced convection turbulent flow. A systematic analysis of variable-viscosity effects, isolated from gravity, with relevance to industrial cooling/heating applications is being carried out. A LES of a planar channel flow with significant heat transfer at a low Mach number was performed to study effects of fluid property variation on the near-wall turbulence structure. In this flow configuration the top wall is maintained at a higher temperature (T hot ) than the bottom wall (T cold ). The temperature ratio (R θ = T hot /T cold ) is fixed at 1.01, 2 and 3 to study the effects of property variations at low Mach number. Results indicate that average and turbulent fields undergo significant changes. Compared with isothermal flow with constant viscosity, we observe that turbulence is enhanced in the cold side of the channel, characterized by locally lower viscosity whereas a decrease of turbulent kinetic energy is found at the hot wall. The turbulent structures near the cold wall are very short and densely populated vortices but near the hot wall there seems to be a long streaky structure or large elongated vortices. Spectral study reveals that turbulence is completely suppressed at the hot side of the channel at a large temperature ratio because no inertial zone is obtained (i.e. index of Kolmogorov scaling law is zero) from the spectra in these region.

RETRACTION: Unsteady flow and heat transfer of viscous incompressible fluid with temperature-dependent viscosity due to a rotating disc in a porous medium

NASA Astrophysics Data System (ADS)

Attia, H. A.

2007-04-01

It has come to the attention of the Institute of Physics that this article should not have been submitted for publication owing to its plagiarism of an earlier paper (Hossain A, Hossain M A and Wilson M 2001 Unsteady flow of viscous incompressible fluid with temperature-dependent viscosity due to a rotating disc in presence of transverse magnetic field and heat transfer Int. J. Therm. Sci. 40 11-20). Therefore this article has been retracted by the Institute of Physics and by the author, Hazem Ali Attia.

Acoustic Experiment to Measure the Bulk Viscosity of Near-Critical Xenon in Microgravity

NASA Technical Reports Server (NTRS)

Gillis, K. A.; Shinder, I.; Moldover, M. R.; Zimmerli, G. A.

2002-01-01

We plan a rigorous test of the theory of dynamic scaling by accurately measuring the bulk viscosity of xenon in microgravity 50 times closer to the critical temperature T(sub c) than previous experiments. The bulk viscosity zeta (or "second viscosity" or "dilational viscosity") will be determined by measuring the attenuation length of sound alpha lambda and also measuring the frequency-dependence of the speed of sound. For these measurements, we developed a unique Helmholtz resonator and specialized electro-acoustic transducers. We describe the resonator, the transducers, their performance on Earth, and their expected performance in microgravity.

Correlation between the critical viscosity and ash fusion temperatures of coal gasifier ashes

DOE PAGES

Hsieh, Peter Y.; Kwong, Kyei-Sing; Bennett, James

2015-09-27

Coal gasification yields synthesis gas, an important intermediate in chemical manufacturing. It is also vital to the production of liquid fuels through the Fischer-Tropsch process and electricity in Integrated Gasification Combined Cycle power generation. Minerals naturally present in coal become molten in entrained-flow slagging gasifiers. Molten coal ash slag penetrates and dissolves refractory bricks, leading to costly plant shutdowns. The extent of coal ash slag penetration and refractory brick dissolution depends on the slag viscosity, the gasification temperature, and the composition of slag and bricks. We measured the viscosity of several synthetic coal ash slags with a high-temperature rotary viscometermore » and their ash fusion temperatures through optical image analysis. All measurements were made in a carbon monoxide-carbon dioxide reducing atmosphere that approximates coal gasification conditions. Empirical correlation models based on ash fusion temperatures were used to calculate critical viscosity temperatures based on the coal ash compositions. These values were then compared with those obtained from thermodynamic phase-transition models. An understanding of slag viscosity as a function of ash composition is important to reducing refractory wear in slagging coal gasifiers, which would help to reduce the cost and environmental impact of coal for chemical and electricity production.« less

Correlation between the critical viscosity and ash fusion temperatures of coal gasifier ashes

DOE Office of Scientific and Technical Information (OSTI.GOV)

Hsieh, Peter Y.; Kwong, Kyei-Sing; Bennett, James

Coal gasification yields synthesis gas, an important intermediate in chemical manufacturing. It is also vital to the production of liquid fuels through the Fischer-Tropsch process and electricity in Integrated Gasification Combined Cycle power generation. Minerals naturally present in coal become molten in entrained-flow slagging gasifiers. Molten coal ash slag penetrates and dissolves refractory bricks, leading to costly plant shutdowns. The extent of coal ash slag penetration and refractory brick dissolution depends on the slag viscosity, the gasification temperature, and the composition of slag and bricks. We measured the viscosity of several synthetic coal ash slags with a high-temperature rotary viscometermore » and their ash fusion temperatures through optical image analysis. All measurements were made in a carbon monoxide-carbon dioxide reducing atmosphere that approximates coal gasification conditions. Empirical correlation models based on ash fusion temperatures were used to calculate critical viscosity temperatures based on the coal ash compositions. These values were then compared with those obtained from thermodynamic phase-transition models. An understanding of slag viscosity as a function of ash composition is important to reducing refractory wear in slagging coal gasifiers, which would help to reduce the cost and environmental impact of coal for chemical and electricity production.« less

Determination of the glass-transition temperature of proteins from a viscometric approach.

PubMed

Monkos, Karol

2015-03-01

All fully hydrated proteins undergo a distinct change in their dynamical properties at glass-transition temperature Tg. To determine indirectly this temperature for dry albumins, the viscosity measurements of aqueous solutions of human, equine, ovine, porcine and rabbit serum albumin have been conducted at a wide range of concentrations and at temperatures ranging from 278 K to 318 K. Viscosity-temperature dependence of the solutions is discussed on the basis of the three parameters equation resulting from Avramov's model. One of the parameter in the Avramov's equation is the glass-transition temperature. For all studied albumins, Tg of a solution monotonically increases with increasing concentration. The glass-transition temperature of a solution depends both on Tg for a dissolved dry protein Tg,p and water Tg,w. To obtain Tg,p for each studied albumin the modified Gordon-Taylor equation was applied. This equation describes the dependence of Tg of a solution on concentration, and Tg,p and a parameter depending on the strength of the protein-solvent interaction are the fitting parameters. Thus determined the glass-transition temperature for the studied dry albumins is in the range (215.4-245.5)K. Copyright © 2014 Elsevier B.V. All rights reserved.

The Effect of Temperature on Kinetics and Diffusion Coefficients of Metallocene Derivatives in Polyol-Based Deep Eutectic Solvents

PubMed Central

Bahadori, Laleh; Chakrabarti, Mohammed Harun; Manan, Ninie Suhana Abdul; Hashim, Mohd Ali; Mjalli, Farouq Sabri; AlNashef, Inas Muen; Brandon, Nigel

2015-01-01

The temperature dependence of the density, dynamic viscosity and ionic conductivity of several deep eutectic solvents (DESs) containing ammonium-based salts and hydrogen bond donvnors (polyol type) are investigated. The temperature-dependent electrolyte viscosity as a function of molar conductivity is correlated by means of Walden’s rule. The oxidation of ferrocene (Fc/Fc+) and reduction of cobaltocenium (Cc+/Cc) at different temperatures are studied by cyclic voltammetry and potential-step chronoamperometry in DESs. For most DESs, chronoamperometric transients are demonstrated to fit an Arrhenius-type relation to give activation energies for the diffusion of redox couples at different temperatures. The temperature dependence of the measured conductivities of DES1 and DES2 are better correlated with the Vogel-Tamman-Fulcher equation. The kinetics of the Fc/Fc+ and Cc+/Cc electrochemical systems have been investigated over a temperature range from 298 to 338 K. The heterogeneous electron transfer rate constant is then calculated at different temperatures by means of a logarithmic analysis. The glycerol-based DES (DES5) appears suitable for further testing in electrochemical energy storage devices. PMID:26642045

Transport properties of nonelectrolyte liquid mixtures—I. Viscosity coefficients for n-alkane mixtures at saturation pressure from 283 to 378 K

NASA Astrophysics Data System (ADS)

Dymond, J. H.; Young, K. J.

1980-12-01

Viscosity coefficient measurements at saturation pressure are reported for n-hexane + n-hexadecane, n-hexane + n-octane + n-hexadecane, and n-hexane + n-octane + n-dodecane + n-hexadecane at temperatures from 283 to 378 K. The results show that the Congruence Principle applies to the molar excess Gibbs free energy of activation for flow, δ* G E, at temperatures other than 298 K. However, curves of δ* G E versus index number of the mixture are temperature dependent, and this must be taken into account for accurate prediction of mixture viscosity coefficients by this approach. The purely empirical equation of Grunberg and Nissan; 1 10765_2004_Article_BF00516562_TeX2GIFE1.gif ln η = x_1 ln η _1 + x_2 ln η _2 + x_1 x_2 G which has the advantage of not involving molar volumes, satisfactorily reproduces the experimental results for the binary mixture, but G is definitely composition dependent.

Compensatory escape mechanism at low Reynolds number

PubMed Central

Gemmell, Brad J.; Sheng, Jian; Buskey, Edward J.

2013-01-01

Despite high predation pressure, planktonic copepods remain one of the most abundant groups on the planet. Their escape response provides one of most effective mechanisms to maximize evolutionary fitness. Owing to their small size (100 µm) compared with their predators (>1 mm), increasing viscosity is believed to have detrimental effects on copepods’ fitness at lower temperature. Using high-speed digital holography we acquire 3D kinematics of the nauplius escape including both location and detailed appendage motion. By independently varying temperature and viscosity we demonstrate that at natural thermal extremes, contrary to conventional views, nauplii achieve equivalent escape distance while maintaining optimal velocity. Using experimental results and kinematic simulations from a resistive force theory propulsion model, we demonstrate that a shift in appendage timing creates an increase in power stroke duration relative to recovery stroke duration. This change allows the nauplius to limit losses in velocity and maintain distance during escapes at the lower bound of its natural thermal range. The shift in power stroke duration relative to recovery stroke duration is found to be regulated by the temperature dependence of swimming appendage muscle groups, not a dynamic response to viscosity change. These results show that copepod nauplii have natural adaptive mechanisms to compensate for viscosity variations with temperature but not in situations in which viscosity varies independent of temperature, such as in some phytoplankton blooms. Understanding the robustness of escapes in the wake of environmental changes such as temperature and viscosity has implications in assessing the future health of performance compensation. PMID:23487740

Predicting the glass transition temperature and viscosity of secondary organic material using molecular composition

NASA Astrophysics Data System (ADS)

Wong DeRieux, Wing-Sy; Li, Ying; Lin, Peng; Laskin, Julia; Laskin, Alexander; Bertram, Allan K.; Nizkorodov, Sergey A.; Shiraiwa, Manabu

2018-05-01

Secondary organic aerosol (SOA) accounts for a large fraction of submicron particles in the atmosphere. SOA can occur in amorphous solid or semi-solid phase states depending on chemical composition, relative humidity (RH), and temperature. The phase transition between amorphous solid and semi-solid states occurs at the glass transition temperature (Tg). We have recently developed a method to estimate Tg of pure compounds containing carbon, hydrogen, and oxygen atoms (CHO compounds) with molar mass less than 450 g mol-1 based on their molar mass and atomic O : C ratio. In this study, we refine and extend this method for CH and CHO compounds with molar mass up to ˜ 1100 g mol-1 using the number of carbon, hydrogen, and oxygen atoms. We predict viscosity from the Tg-scaled Arrhenius plot of fragility (viscosity vs. Tg/T) as a function of the fragility parameter D. We compiled D values of organic compounds from the literature and found that D approaches a lower limit of ˜ 10 (±1.7) as the molar mass increases. We estimated the viscosity of α-pinene and isoprene SOA as a function of RH by accounting for the hygroscopic growth of SOA and applying the Gordon-Taylor mixing rule, reproducing previously published experimental measurements very well. Sensitivity studies were conducted to evaluate impacts of Tg, D, the hygroscopicity parameter (κ), and the Gordon-Taylor constant on viscosity predictions. The viscosity of toluene SOA was predicted using the elemental composition obtained by high-resolution mass spectrometry (HRMS), resulting in a good agreement with the measured viscosity. We also estimated the viscosity of biomass burning particles using the chemical composition measured by HRMS with two different ionization techniques: electrospray ionization (ESI) and atmospheric pressure photoionization (APPI). Due to differences in detected organic compounds and signal intensity, predicted viscosities at low RH based on ESI and APPI measurements differ by 2-5 orders of magnitude. Complementary measurements of viscosity and chemical composition are desired to further constrain RH-dependent viscosity in future studies.

Pressure Dependence of Komatiite Liquid Viscosity and Implications for Magma Ocean Rheology

NASA Astrophysics Data System (ADS)

O'Dwyer Brown, L.; Lesher, C. E.; Terasaki, H. G.; Yamada, A.; Sakamaki, T.; Shibazaki, Y.; Ohtani, E.

2009-12-01

The viscosities of komatiite liquids at high pressures and temperatures were investigated using the in-situ falling sphere technique at BL04B1, SPring-8. Komatiites are naturally occurring magmas, rich in network modifying cations. Despite the refractory and fluid nature of komatiite, we successfully measured the viscosity of molten komatiites from Gorgona Island, Colombia (MgO = 17.8 wt.%; NBO/T = 1.5) between 11 and 13 GPa at 2000 C, and from Belingwe, Zimbabwe (MgO = 28.14 wt.%; NBO/T = 2.1) from 12 to 14 GPa at 2000 C. Under isothermal conditions, the viscosity of Gorgona Island komatiite melt increased with pressure, consistent with our previous measurements at lower pressures for this composition. We interpreted this positive pressure dependence as the result of reductions in interatomic space diminishing the free volume of the liquid when compressed. The viscosity of molten komatiite from Belingwe also increased up to 12 GPa, however between 12 and 14 GPa the viscosity is nearly constant. In previous studies of depolymerized silicate liquids, the pressure dependence of viscosity has been shown to reverse from positive to negative between 8 and 10 GPa with corresponding changes in activation volume [1] [2]. In contrast, the activation volume for Belingwe liquid decreases to near zero, but does not become negative above 11 GPa. Similarly, the activation volume for Gorgona Island komatiite remains positive throughout the pressure range investigated. Molecular dynamics simulations of simple MgO-SiO2 liquids with NBO/T > 2 also show a positive pressure dependence, reflecting the dominant control of free-volume reduction on the viscosity of depolymerized melts. However, the more rapid reduction in activation volume with pressure in komatiite liquids may be related to the presence of Al, Ti and other cations that interact and undergo coordination changes unavailable in simple silicate liquids. Along Hadean and post-Hadean mantle adiabats the net effect of temperature and pressure on ultramafic liquids suggests that changes in viscosity are likely modest and viscosity will decrease with depth. Stiffening and isolation of the lower regions of a magma ocean due to increasing melt viscosity seem unlikely. [1] PEPI (2003) 139, 45 [2] EPSL (2005) 240, 589

Unsteady Convection Flow and Heat Transfer over a Vertical Stretching Surface

PubMed Central

Cai, Wenli; Su, Ning; Liu, Xiangdong

2014-01-01

This paper investigates the effect of thermal radiation on unsteady convection flow and heat transfer over a vertical permeable stretching surface in porous medium, where the effects of temperature dependent viscosity and thermal conductivity are also considered. By using a similarity transformation, the governing time-dependent boundary layer equations for momentum and thermal energy are first transformed into coupled, non-linear ordinary differential equations with variable coefficients. Numerical solutions to these equations subject to appropriate boundary conditions are obtained by the numerical shooting technique with fourth-fifth order Runge-Kutta scheme. Numerical results show that as viscosity variation parameter increases both the absolute value of the surface friction coefficient and the absolute value of the surface temperature gradient increase whereas the temperature decreases slightly. With the increase of viscosity variation parameter, the velocity decreases near the sheet surface but increases far away from the surface of the sheet in the boundary layer. The increase in permeability parameter leads to the decrease in both the temperature and the absolute value of the surface friction coefficient, and the increase in both the velocity and the absolute value of the surface temperature gradient. PMID:25264737

Unsteady convection flow and heat transfer over a vertical stretching surface.

PubMed

Cai, Wenli; Su, Ning; Liu, Xiangdong

2014-01-01

This paper investigates the effect of thermal radiation on unsteady convection flow and heat transfer over a vertical permeable stretching surface in porous medium, where the effects of temperature dependent viscosity and thermal conductivity are also considered. By using a similarity transformation, the governing time-dependent boundary layer equations for momentum and thermal energy are first transformed into coupled, non-linear ordinary differential equations with variable coefficients. Numerical solutions to these equations subject to appropriate boundary conditions are obtained by the numerical shooting technique with fourth-fifth order Runge-Kutta scheme. Numerical results show that as viscosity variation parameter increases both the absolute value of the surface friction coefficient and the absolute value of the surface temperature gradient increase whereas the temperature decreases slightly. With the increase of viscosity variation parameter, the velocity decreases near the sheet surface but increases far away from the surface of the sheet in the boundary layer. The increase in permeability parameter leads to the decrease in both the temperature and the absolute value of the surface friction coefficient, and the increase in both the velocity and the absolute value of the surface temperature gradient.

Effect of Temperature on the Physico-Chemical Properties of a Room Temperature Ionic Liquid (1-Methyl-3-pentylimidazolium Hexafluorophosphate) with Polyethylene Glycol Oligomer

PubMed Central

Wu, Tzi-Yi; Chen, Bor-Kuan; Hao, Lin; Peng, Yu-Chun; Sun, I-Wen

2011-01-01

A systematic study of the effect of composition on the thermo-physical properties of the binary mixtures of 1-methyl-3-pentyl imidazolium hexafluorophosphate [MPI][PF6] with poly(ethylene glycol) (PEG) [Mw = 400] is presented. The excess molar volume, refractive index deviation, viscosity deviation, and surface tension deviation values were calculated from these experimental density, ρ, refractive index, n, viscosity, η, and surface tension, γ, over the whole concentration range, respectively. The excess molar volumes are negative and continue to become increasingly negative with increasing temperature; whereas the viscosity and surface tension deviation are negative and become less negative with increasing temperature. The surface thermodynamic functions, such as surface entropy, enthalpy, as well as standard molar entropy, Parachor, and molar enthalpy of vaporization for pure ionic liquid, have been derived from the temperature dependence of the surface tension values. PMID:21731460

A method for matching the refractive index and kinematic viscosity of a blood analog for flow visualization in hydraulic cardiovascular models.

PubMed

Nguyen, T T; Biadillah, Y; Mongrain, R; Brunette, J; Tardif, J C; Bertrand, O F

2004-08-01

In this work, we propose a simple method to simultaneously match the refractive index and kinematic viscosity of a circulating blood analog in hydraulic models for optical flow measurement techniques (PIV, PMFV, LDA, and LIF). The method is based on the determination of the volumetric proportions and temperature at which two transparent miscible liquids should be mixed to reproduce the targeted fluid characteristics. The temperature dependence models are a linear relation for the refractive index and an Arrhenius relation for the dynamic viscosity of each liquid. Then the dynamic viscosity of the mixture is represented with a Grunberg-Nissan model of type 1. Experimental tests for acrylic and blood viscosity were found to be in very good agreement with the targeted values (measured refractive index of 1.486 and kinematic viscosity of 3.454 milli-m2/s with targeted values of 1.47 and 3.300 milli-m2/s).

Hemorheology and oxygen transport in vertebrates. A role in thermoregulation?

PubMed

Viscor, G; Torrella, J R; Fouces, V; Pagés, T

2003-12-01

We studied the effect of temperature on blood rheology in three vertebrate species with different thermoregulation and erythrocyte characteristics. Higher fibrinogen proportion to total plasma protein was found in turtles (20%) than in pigeons (5.6%) and rats (4.2%). Higher plasma viscosity at room temperature than at homeotherm body temperature was observed in rats (1.69 mPa x s at 20 degrees C vs. 1.33 mPa x s at 37 degrees C), pigeons (3.40 mPa x s at 20 degrees C vs. 1.75 mPa x s at 40 degrees C), and turtles (1.74 mPa x s at 20 degrees C vs. 1.32 mPa x s at 37 degrees C). This fact allow us to hypothesize that thermal changes in protein structure may account for an adjustment of the plasma viscosity. Blood viscosity was dependent on shear rate, temperature and hematocrit in the three species. A different behaviour in apparent and relative viscosities between rat and pigeon at environmental temperature was found. Moreover, the blood oxygen transport capacity seems more affected by a reduction of temperature in rats than in pigeons. Both findings indicate a greater influence of temperature on mammalian erythrocyte than on nucleated red cells, possibly as a consequence of differences in thermal sensitivity and mechanical stability between them. A comparison between the three species revealed that apparent blood viscosity measured at homeotherm physiological temperature was linearly related to the hematocrit level of each species. However, when measured at environmental temperature, rat blood showed a higher apparent viscosity than those found in species with non-nucleated red cells, thus indicating a higher impact of temperature decrease on blood viscosity in mammals. This suggest that regional hypothermia caused by cold exposure may affect mammalian blood rheological behaviour in a higher extent than in other vertebrate species having nucleated red cells and, consequently, influencing circulatory function and oxygen transport.

Internal Waves in CVX

NASA Technical Reports Server (NTRS)

Berg, Robert F.

1996-01-01

Near the liquid-vapor critical point, density stratification supports internal gravity waves which affect 1-g viscosity measurements in the CVX (Critical Viscosity of Xenon) experiment. Two internal-wave modes were seen in the horizontal viscometer. The frequencies of the two modes had different temperature dependences: with decreasing temperature, the higher frequency increased monotonically from 0.7 to 2.8 Hz, but the lower frequency varied non-monotonically, with a maximum of 1.0 Hz at 20 mK above the critical temperature. The measured frequencies agree with independently calculated frequencies to within 15%.

Microgravity Studies of Liquid-Liquid Phase Transitions in Alumina-Yttria Melts

NASA Technical Reports Server (NTRS)

Guynes, Buddy (Technical Monitor); Weber, Richard; Nordine, Paul

2004-01-01

The scientific objective of this research is to increase the fundamental knowledge base for liquid- phase processing of technologically important oxide materials. The experimental objective is to define conditions and hardware requirements for microgravity flight experiments to test and expand the experimental hypotheses that: 1. Liquid phase transitions can occur in undercooled melts by a diffusionless process. 2. Onset of the liquid phase transition is accompanied by a large change in the temperature dependence of melt viscosity. Experiments on undercooled YAG (Y3A15012)- and rare earth oxide aluminate composition liquids demonstrated a large departure from an Arrhenian temperature dependence of viscosity. Liquid YAG is nearly inviscid at its 2240 K melting point. Glass fibers were pulled from melts undercooled by ca. 600 K indicating that the viscosity is on the order of 100 Pans (1000 Poise) at 1600 K. This value of viscosity is 500 times greater than that obtained by extrapolation of data for temperatures above the melting point of YAG. These results show that the liquids are extremely fragile and that the onset of the highly non-Arrhenian viscosity-temperature relationship occurs at a temperature considerably below the equilibrium melting point of the solid phases. Further results on undercooled alumina-yttria melts containing 23-42 mole % yttrium oxide indicate that a congruent liquid-liquid phase transition occurs in the undercooled liquids. The rates of transition are inconsistent with a diffusion-limited process. This research is directed to investigation of the scientifically interesting phenomena of polyamorphism and fragility in undercooled rare earth oxide aluminum oxide liquids. The results bear on the technologically important problem of producing high value rare earth-based optical materials.

Rheological profile of boron nitride–ethylene glycol nanofluids

DOE Office of Scientific and Technical Information (OSTI.GOV)

Żyła, Gaweł, E-mail: gzyla@prz.edu.pl; Witek, Adam; Gizowska, Magdalena

2015-01-07

The paper presents the complete rheological profile of boron nitride (BN)–ethylene glycol (EG) nanofluids. Nanofluids have been produced by two-step method on the basis of commercially available powder of plate-like grains of nanometrical thickness. Viscoelastic structure has been determined in oscillatory measurements at a constant frequency and temperature. Viscosity and flow curves for these materials have been measured. Studies have shown that the Carreau model can be used for the modeling of dynamic viscosity curves of the material. The samples were tested for the presence of thixotropy. The dependence of viscosity on temperature was also examined. The effect of temperaturemore » on the dynamic viscosity of BN-EG nanofluids can be modelled with the use of Vogel-Fulcher-Tammann expression.« less

Temperature dependent of viscoelasticity measurement on fat emulsion phantom using acoustic radiation force elasticity imaging method

PubMed Central

Xie, Peng; Wang, Mengke; Guo, Yanrong; Wen, Huiying; Chen, Xin; Chen, Siping; Lin, Haoming

2018-01-01

During the past two decades, tissue elasticity has been extensively studied and has been used in clinical disease diagnosis. But biological soft tissues are viscoelastic in nature. Therefore, they should be simultaneously characterized in terms of elasticity and viscosity. In addition, the mechanical properties of soft tissues are temperature dependent. However, how the temperature influences the shear wave dispersion and the viscoelasticity of soft tissue are still unclear. The aim of this study is to compare viscoelasticity of fat emulsion phantom with different temperature using acoustic radiation force elasticity imaging method. In our experiment, we produced four proportions of ultrasonic phantom by adding fat emulsion gelatin. Through adjusting the component of the fat emulsion, we change the viscoelasticity of the ultrasonic phantom. We used verasonics system to gather data and voigt model to fit the elasticity and viscosity value of the ultrasonic phantom we made. The influence of temperature to the ultrasonic phantom also measured in our study. The results show that the addition of fat emulsion to the phantom can increase the viscosity of the phantom, and the shear wave phase velocity decreases gradually at each frequency with the temperature increases, which provides a new material for the production of viscoelastic phantom. PMID:29758968

Temperature dependent of viscoelasticity measurement on fat emulsion phantom using acoustic radiation force elasticity imaging method.

PubMed

Xie, Peng; Wang, Mengke; Guo, Yanrong; Wen, Huiying; Chen, Xin; Chen, Siping; Lin, Haoming

2018-04-27

During the past two decades, tissue elasticity has been extensively studied and has been used in clinical disease diagnosis. But biological soft tissues are viscoelastic in nature. Therefore, they should be simultaneously characterized in terms of elasticity and viscosity. In addition, the mechanical properties of soft tissues are temperature dependent. However, how the temperature influences the shear wave dispersion and the viscoelasticity of soft tissue are still unclear. The aim of this study is to compare viscoelasticity of fat emulsion phantom with different temperature using acoustic radiation force elasticity imaging method. In our experiment, we produced four proportions of ultrasonic phantom by adding fat emulsion gelatin. Through adjusting the component of the fat emulsion, we change the viscoelasticity of the ultrasonic phantom. We used verasonics system to gather data and voigt model to fit the elasticity and viscosity value of the ultrasonic phantom we made. The influence of temperature to the ultrasonic phantom also measured in our study. The results show that the addition of fat emulsion to the phantom can increase the viscosity of the phantom, and the shear wave phase velocity decreases gradually at each frequency with the temperature increases, which provides a new material for the production of viscoelastic phantom.

Shear viscosity to entropy density ratios and implications for (im)perfect fluidity in Fermionic and Bosonic superfluids

NASA Astrophysics Data System (ADS)

Boyack, Rufus; Guo, Hao; Levin, K.

2015-03-01

Recent experiments on both unitary Fermi gases and high temperature superconductors (arxiv:1410.4835 [cond-mat.quant-gas], arxiv:1409.5820 [cond-mat.str-el].) have led to renewed interest in near perfect fluidity in condensed matter systems. This is quantified by studying the ratio of shear viscosity to entropy density. In this talk we present calculations of this ratio in homogeneous bosonic and fermionic superfluids, with the latter ranging from BCS to BEC. While the shear viscosity exhibits a power law (for bosons) or exponential suppression (for fermions), a similar dependence is found for the respective entropy densities. As a result, strict BCS and (true) bosonic superfluids have an analogous viscosity to entropy density ratio, behaving linearly with temperature times the (T-dependent) dissipation rate; this is characteristic of imperfect fluidity in weakly coupled fluids. This is contrasted with the behavior of fermions at unitarity which we argue is a consequence of additional terms in the entropy density thereby leading to more perfect fluidity. (arXiv:1407.7572v1 [cond-mat.quant-gas])

Modeling turbulent energy behavior and sudden viscous dissipation in compressing plasma turbulence

DOE PAGES

Davidovits, Seth; Fisch, Nathaniel J.

2017-12-21

Here, we present a simple model for the turbulent kinetic energy behavior of subsonic plasma turbulence undergoing isotropic three-dimensional compression, which may exist in various inertial confinement fusion experiments or astrophysical settings. The plasma viscosity depends on both the temperature and the ionization state, for which many possible scalings with compression are possible. For example, in an adiabatic compression the temperature scales as 1/L 2, with L the linear compression ratio, but if thermal energy loss mechanisms are accounted for, the temperature scaling may be weaker. As such, the viscosity has a wide range of net dependencies on the compression.more » The model presented here, with no parameter changes, agrees well with numerical simulations for a range of these dependencies. This model permits the prediction of the partition of injected energy between thermal and turbulent energy in a compressing plasma.« less

Modeling turbulent energy behavior and sudden viscous dissipation in compressing plasma turbulence

DOE Office of Scientific and Technical Information (OSTI.GOV)

Davidovits, Seth; Fisch, Nathaniel J.

Here, we present a simple model for the turbulent kinetic energy behavior of subsonic plasma turbulence undergoing isotropic three-dimensional compression, which may exist in various inertial confinement fusion experiments or astrophysical settings. The plasma viscosity depends on both the temperature and the ionization state, for which many possible scalings with compression are possible. For example, in an adiabatic compression the temperature scales as 1/L 2, with L the linear compression ratio, but if thermal energy loss mechanisms are accounted for, the temperature scaling may be weaker. As such, the viscosity has a wide range of net dependencies on the compression.more » The model presented here, with no parameter changes, agrees well with numerical simulations for a range of these dependencies. This model permits the prediction of the partition of injected energy between thermal and turbulent energy in a compressing plasma.« less

Polythermal investigation of viscosity of solution of metal carboxylates in VIK-grade mixed carboxylic acids: Yttrium and gadolinium carboxylates

DOE Office of Scientific and Technical Information (OSTI.GOV)

Mezhov, E.A.; Samatov, A.V.; Troyanovskii, L.V.

Kinematic viscosities have been measured for solutions of yttrium and gadolinium carboxylates in grade VIK mixed carboxylic acids (MCA). It has been established that the optimal fluidity of these metal carboxylate solutions for application to articles is reached at 333 K. A regression model has been developed to describe the concentration and temperature dependences of the viscosity of yttrium- and gadolinium-containing MCA solutions. 2 refs., 3 tabs.

Experiment and Artificial Neural Network Prediction of Thermal Conductivity and Viscosity for Alumina-Water Nanofluids

PubMed Central

Zhao, Ningbo; Li, Zhiming

2017-01-01

To effectively predict the thermal conductivity and viscosity of alumina (Al2O3)-water nanofluids, an artificial neural network (ANN) approach was investigated in the present study. Firstly, using a two-step method, four Al2O3-water nanofluids were prepared respectively by dispersing different volume fractions (1.31%, 2.72%, 4.25%, and 5.92%) of nanoparticles with the average diameter of 30 nm. On this basis, the thermal conductivity and viscosity of the above nanofluids were analyzed experimentally under various temperatures ranging from 296 to 313 K. Then a radial basis function (RBF) neural network was constructed to predict the thermal conductivity and viscosity of Al2O3-water nanofluids as a function of nanoparticle volume fraction and temperature. The experimental results showed that both nanoparticle volume fraction and temperature could enhance the thermal conductivity of Al2O3-water nanofluids. However, the viscosity only depended strongly on Al2O3 nanoparticle volume fraction and was increased slightly by changing temperature. In addition, the comparative analysis revealed that the RBF neural network had an excellent ability to predict the thermal conductivity and viscosity of Al2O3-water nanofluids with the mean absolute percent errors of 0.5177% and 0.5618%, respectively. This demonstrated that the ANN provided an effective way to predict the thermophysical properties of nanofluids with limited experimental data. PMID:28772913

Experiment and Artificial Neural Network Prediction of Thermal Conductivity and Viscosity for Alumina-Water Nanofluids.

PubMed

Zhao, Ningbo; Li, Zhiming

2017-05-19

To effectively predict the thermal conductivity and viscosity of alumina (Al₂O₃)-water nanofluids, an artificial neural network (ANN) approach was investigated in the present study. Firstly, using a two-step method, four Al₂O₃-water nanofluids were prepared respectively by dispersing different volume fractions (1.31%, 2.72%, 4.25%, and 5.92%) of nanoparticles with the average diameter of 30 nm. On this basis, the thermal conductivity and viscosity of the above nanofluids were analyzed experimentally under various temperatures ranging from 296 to 313 K. Then a radial basis function (RBF) neural network was constructed to predict the thermal conductivity and viscosity of Al₂O₃-water nanofluids as a function of nanoparticle volume fraction and temperature. The experimental results showed that both nanoparticle volume fraction and temperature could enhance the thermal conductivity of Al₂O₃-water nanofluids. However, the viscosity only depended strongly on Al₂O₃ nanoparticle volume fraction and was increased slightly by changing temperature. In addition, the comparative analysis revealed that the RBF neural network had an excellent ability to predict the thermal conductivity and viscosity of Al₂O₃-water nanofluids with the mean absolute percent errors of 0.5177% and 0.5618%, respectively. This demonstrated that the ANN provided an effective way to predict the thermophysical properties of nanofluids with limited experimental data.

Linearly exact parallel closures for slab geometry

NASA Astrophysics Data System (ADS)

Ji, Jeong-Young; Held, Eric D.; Jhang, Hogun

2013-08-01

Parallel closures are obtained by solving a linearized kinetic equation with a model collision operator using the Fourier transform method. The closures expressed in wave number space are exact for time-dependent linear problems to within the limits of the model collision operator. In the adiabatic, collisionless limit, an inverse Fourier transform is performed to obtain integral (nonlocal) parallel closures in real space; parallel heat flow and viscosity closures for density, temperature, and flow velocity equations replace Braginskii's parallel closure relations, and parallel flow velocity and heat flow closures for density and temperature equations replace Spitzer's parallel transport relations. It is verified that the closures reproduce the exact linear response function of Hammett and Perkins [Phys. Rev. Lett. 64, 3019 (1990)] for Landau damping given a temperature gradient. In contrast to their approximate closures where the vanishing viscosity coefficient numerically gives an exact response, our closures relate the heat flow and nonvanishing viscosity to temperature and flow velocity (gradients).

Intrinsic viscosity and rheological properties of natural and substituted guar gums in seawater.

PubMed

Wang, Shibin; He, Le; Guo, Jianchun; Zhao, Jinzhou; Tang, Hongbiao

2015-05-01

The intrinsic viscosity and rheological properties of guar gum (GG), hydroxypropyl guar (HPG) and carboxymethyl guar (CMG) in seawater and the effects of shear rate, concentration, temperature and pH on these properties were investigated. An intrinsic viscosity-increasing effect was observed with GG and HPG in seawater (SW) compared to deionized water (DW), whereas the intrinsic viscosity of CMG in seawater was much lower than that in DW due to a screening effect that reduced the repulsion between the polymer chains. Regardless of the functional groups, all sample solutions was well characterized by a modified Cross model that exhibited the transition from Newtonian to pseudoplastic in the low shear rate range at the concentrations of interest to industries, and their viscosity increased with the increase in their concentration but decreased with the increase in temperature. In contrast to nonionic GG or HPG, anionic CMG had a slightly decreased viscosity property in SW, exhibiting polyelectrolyte viscosity behavior. The α value in the zero-shear rate viscosity vs. concentration power-law equation for the samples gave the order of CMG>HPG>GG while the SW solution of CMG had the lowest viscous flow activation energy and exhibited a strong pH-dependent viscosity by a different shear rate. Copyright © 2015 Elsevier B.V. All rights reserved.

Periodic MHD flow with temperature dependent viscosity and thermal conductivity past an isothermal oscillating cylinder

NASA Astrophysics Data System (ADS)

Ahmed, Rubel; Rana, B. M. Jewel; Ahmmed, S. F.

2017-06-01

Temperature dependent viscosity and thermal conducting heat and mass transfer flow with chemical reaction and periodic magnetic field past an isothermal oscillating cylinder have been considered. The partial dimensionless equations governing the flow have been solved numerically by applying explicit finite difference method with the help Compaq visual 6.6a. The obtained outcome of this inquisition has been discussed for different values of well-known flow parameters with different time steps and oscillation angle. The effect of chemical reaction and periodic MHD parameters on the velocity field, temperature field and concentration field, skin-friction, Nusselt number and Sherwood number have been studied and results are presented by graphically. The novelty of the present problem is to study the streamlines by taking into account periodic magnetic field.

Fundamental investigation of stress corrosion cracking

NASA Technical Reports Server (NTRS)

Beck, T. R.; Blackburn, M. J.; Smyrl, W. H.

1972-01-01

Two principle areas studied were stress corrosion crack growth rates of a titanium alloy in liquid environments containing halide ions and pitting corrosion of titanium in bromide solutions. Two initial assumptions were made, that the rate of propagation was controlled by a macroscopic solution parameter and that this parameter was viscosity. A series of solutions were prepared using lithium chloride as the solute and water, methanol, glycerin, formic acid, acetone, dimethyl sulphoxide, etc. As solvents, these solutions were prepared with a 5:1 solvent-solute ratio. Viscosity was varied by changing the temperature and it was found: (1) In all solvents the velocity of cracking was proportional to the reciprocal of the viscosity. (2) Each solvent gave a separate relationship, (3) The temperature dependence and numerical values for the apparent activation energy of cracking and viscosity were the same.

Using Mason number to predict MR damper performance from limited test data

NASA Astrophysics Data System (ADS)

Becnel, Andrew C.; Wereley, Norman M.

2017-05-01

The Mason number can be used to produce a single master curve which relates MR fluid stress versus strain rate behavior across a wide range of shear rates, temperatures, and applied magnetic fields. As applications of MR fluid energy absorbers expand to a variety of industries and operating environments, Mason number analysis offers a path to designing devices with desired performance from a minimal set of preliminary test data. Temperature strongly affects the off-state viscosity of the fluid, as the passive viscous force drops considerably at higher temperatures. Yield stress is not similarly affected, and stays relatively constant with changing temperature. In this study, a small model-scale MR fluid rotary energy absorber is used to measure the temperature correction factor of a commercially-available MR fluid from LORD Corporation. This temperature correction factor is identified from shear stress vs. shear rate data collected at four different temperatures. Measurements of the MR fluid yield stress are also obtained and related to a standard empirical formula. From these two MR fluid properties - temperature-dependent viscosity and yield stress - the temperature-corrected Mason number is shown to predict the force vs. velocity performance of a full-scale rotary MR fluid energy absorber. This analysis technique expands the design space of MR devices to high shear rates and allows for comprehensive predictions of overall performance across a wide range of operating conditions from knowledge only of the yield stress vs. applied magnetic field and a temperature-dependent viscosity correction factor.

On the instability of a liquid sheet moving in vacuum

NASA Astrophysics Data System (ADS)

Sisoev, G. M.; Osiptsov, A. N.; Koroteev, A. A.

2018-03-01

A linear stability analysis of a non-isothermal liquid sheet moving in vacuum is studied taking into account the temperature dependencies of the liquid viscosity, thermal conductivity, and surface tension coefficients. It is found that there are two mechanisms of instability. The short-wave instability is caused by viscosity stratification across the sheet due to nonuniform temperature profiles developed downstream in the cooling sheet. The long-wave thermocapillary instability is caused by the temperature gradient along the sheet surfaces. Computed examples of steady flows and their instabilities demonstrated that the unstable short waves have much larger amplification factors.

Low-temperature heat capacity of diopside glass (CaMgSi2O6): A calorimetric test of the configurational-entropy theory applied to the viscosity of liquid silicates

USGS Publications Warehouse

Richet, P.; Robie, R.A.; Hemingway, B.S.

1986-01-01

Heat-capacity measurements have been made between 8 and 370 K on an annealed and a rapidly quenched diopside glass. Between 15 and 200 K, Cp does not depend significantly on the thermal history of the glass. Below 15 K Cp is larger for the quenched than for the annealed specimen. The opposite is true above 200 K as a result of what is interpreted as a secondary relaxation around room temperature. The magnitude of these effects, however, is small enough that the relative entropies S(298)-S(0) of the glasses differ by only 0.5 J/mol K, i.e., a figure within the combined experimental uncertainties. The insensitivity of relative entropies to thermal history supports the assumption that the configurational heat capacity of the liquid may be taken as the heat capacity difference between the liquid and the glass (??Cp). Furthermore, this insensitivity allows calculation of the residual entropies at 0 K of diopside glasses as a function of the fictive temperature from the entropy of fusion of diopside and the heat capacities of the crystalline, glassy and liquid phases. For a glass with a fictive temperature of 1005 K, for example, this calorimetric residual entropy is 24.3 ?? 3 J/mol K, in agreement with the prediction made by RICHET (1984) from an analysis of the viscosity data with the configurational-entropy theory of relaxation processes of Adam and Gibbs (1965). In turn, all the viscosity measurements for liquid diopside, which span the range 0.5-4?? 1013 poise, can be quantitatively reproduced through this theory with the calorimetrically determined entropies and ??Cp data. Finally, the unclear significance of "activation energies" for structural interpretations of viscosity data is emphasized, and the importance of ??Cp and glass-transition temperature systematics for determining the composition and temperature dependences of the viscosity is pointed out. ?? 1986.

Temperature Variations in Lubricating Films Induced by Viscous Dissipation

NASA Astrophysics Data System (ADS)

Mozaffari, Farshad; Metcalfe, Ralph

2015-11-01

We have studied temperature distributions of lubricating films. The study has applications in tribology where temperature-reduced viscosity decreases load carrying capacity of bearings, or degrades elastomeric seals. The viscosity- temperature dependency is modeled according to ASTM D341-09. We have modeled the film temperature distribution by our finite element program. The program is made up of three modules: the first one solves the general form of Reynolds equation for the film pressure and velocity gradients. The other two solve the energy equation for the film and its solid boundary temperature distributions. The modules are numerically coupled and iteratively converged to the solutions. We have shown that the temperature distribution in the film is strongly coupled with the thermal response at the boundary. In addition, only thermal diffusion across film thickness is dominant. Moreover, thermal diffusion in the lateral directions, as well as all the convection terms, are negligible. The approximation reduces the energy equation to an ordinary differential equation, which significantly simplifies the modeling of temperature -viscosity effects in thin films. Supported by Kalsi Engineering, Inc.

The viscosity to entropy ratio: From string theory motivated bounds to warm dense matter

DOE PAGES

Faussurier, G.; Libby, S. B.; Silvestrelli, P. L.

2014-07-04

Here, we study the ratio of viscosity to entropy density in Yukawa one-component plasmas as a function of coupling parameter at fixed screening, and in realistic warm dense matter models as a function of temperature at fixed density. In these two situations, the ratio is minimized for values of the coupling parameters that depend on screening, and for temperatures that in turn depend on density and material. In this context, we also examine Rosenfeld arguments relating transport coefficients to excess reduced entropy for Yukawa one-component plasmas. For these cases we show that this ratio is always above the lower-bound conjecturemore » derived from string theory ideas.« less

Time-Dependent Effect of Refrigeration on Viscosity and Conversion Kinetics of Dental Adhesive Resins

PubMed Central

Faria-e-Silva, André L; Piva, Evandro; Moraes, Rafael R

2010-01-01

Objectives: This study evaluated the effect of refrigeration at 4°C and post-refrigeration times (immediate, 5, 10, 15, or 20 min) on the viscosity and conversion kinetics of adhesive bonding resins. Methods: Scotchbond Dual-Cure (3M ESPE) and Clearfil SE Bond (Kuraray) were tested. Control samples were kept at 25°C for 24 h. At each post-refrigeration time, the temperature was checked with a K-type thermocouple. Viscosity measurements as a function of temperature were performed using a cone-plate viscometer. Real-time polymerization was monitored by infrared spectroscopy. Degree of conversion (DC) was calculated for each second during polymerization, and the rate of polymerization analyzed. Data were separately submitted to two-way ANOVA and Tukey’s test (P<.05). Results: Clearfil presented faster increase in temperature after exposure to room temperature than Scotchbond. A continuous decrease in viscosity (Pa.s) was observed for both Scotchbond (0.49, 0.34, 0.30, 0.26, 0.23, 0.23) and Clearfil (0.38, 0.37, 0.34, 0.25, 0.24, 0.22). For Scotchbond, higher final DC was detected for the control (62.7%) compared with the immediate (53.3%) and 5 min (54.7%) groups. For Clearfil, the control sample (81.4%) showed higher DC than all refrigerated groups (68.8–69.5%). Clearfil always showed significantly higher DC than Scotchbond. Conclusions: Refrigeration presented a significant time- and material-dependent effect on the viscosity and polymerization kinetics of the bonding resins. Under clinical conditions, adhesive agents should be removed from the refrigerator at least 20 min before being used. PMID:20396445

Differences in Viscosity of Superior and Inferior Spikelets of Japonica Rice with Various Percentages of Apparent Amylose Content.

PubMed

Ma, Zhao-Hui; Cheng, Hai-Tao; Nitta, Y; Aoki, Naohiro; Chen, Yun; Chen, Heng-Xue; Ohsugi, Ryu; Lyu, Wen-Yan

2017-05-31

Viscosity, a crucial characteristic for rice palatability, is affected by endosperm characters. We compared correlations between differences in viscosity of japonica rice with various palatability and endosperm characters. Changes in apparent amylose and protein contents (AAC% and PC%, respectively) and amylopectin side-chain distribution and the relationship of these traits with palatability were investigated in superior and inferior spikelets of good cultivars with low amylose content from Hokkaido and common cultivars from northeastern Japan, using rapid visco analyzer characteristics and rice-grain microstructures. Significant differences occurred in PC%, AAC%, breakdown, setback, peak time, and pasting temperature of different cultivars and grain positions. Amylopectin components showed remarkable differences in grain surfaces, surface layers, and section structure between the grain varieties. Hokkaido cultivars showed better viscosity than northeastern cultivars, particularly initial stage grains. Correlation analysis indicated viscosity was mainly AAC%-dependent, whereas differences in endosperm characteristics between spikelet positions were mainly due to grain-filling temperature.

Polymer deformation and filling modes during microembossing

NASA Astrophysics Data System (ADS)

Rowland, Harry D.; King, William P.

2004-12-01

This work investigates the initial stages of polymer deformation during hot embossing micro-manufacturing at processing temperatures near the glass transition temperature (Tg) of polymer films having sufficient thickness such that polymer flow is not supply limited. Several stages of polymer flow can be observed by employing stamp geometries of various widths and varying imprint conditions of time and temperature to modulate polymer viscosity. Experiments investigate conditions affecting cavity filling phenomena, including apparent polymer viscosity. Stamps with periodic ridges of height and width 4 µm and periodicity 30, 50 and 100 µm emboss trenches into polymethyl methacrylate films at Tg - 10 °C < Temboss < Tg + 20 °C. Imprint parameters of time, temperature and load are correlated with replicated polymer shape, height and imprinted area. Polymer replicates are measured by atomic force microscopy and inspected by scanning electron microscopy. Cavity size and the temperature dependence of polymer viscosity significantly influence the nature of polymer deformation in hot embossing micro-manufacturing and must be accounted for in rational process design.

Microscopic relaxations in a protein sustained down to 160K in a non-glass forming organic solvent.

PubMed

Mamontov, E; O'Neill, H

2017-01-01

We have studied microscopic dynamics of a protein in carbon disulfide, a non-glass forming solvent, down to its freezing temperature of ca. 160K. We have utilized quasielastic neutron scattering. A comparison of lysozyme hydrated with water and dissolved in carbon disulfide reveals a stark difference in the temperature dependence of the protein's microscopic relaxation dynamics induced by the solvent. In the case of hydration water, the common protein glass-forming solvent, the protein relaxation slows down in response to a large increase in the water viscosity on cooling down, exhibiting a well-known protein dynamical transition. The dynamical transition disappears in non-glass forming carbon disulfide, whose viscosity remains a weak function of temperature all the way down to freezing at just below 160K. The microscopic relaxation dynamics of lysozyme dissolved in carbon disulfide is sustained down to the freezing temperature of its solvent at a rate similar to that measured at ambient temperature. Our results demonstrate that protein dynamical transition is not merely solvent-assisted, but rather solvent-induced, or, more precisely, is a reflection of the temperature dependence of the solvent's glass-forming dynamics. We hypothesize that, if the long debated idea regarding the direct link between the microscopic relaxations and the biological activity in proteins is correct, then not only the microscopic relaxations, but also the activity, could be sustained in proteins all the way down to the freezing temperature of a non-glass forming solvent with a weak temperature dependence of its viscosity. This article is part of a Special Issue entitled "Science for Life" Guest Editor: Dr. Austen Angell, Dr. Salvatore Magazù and Dr. Federica Migliardo. Copyright © 2016 Elsevier B.V. All rights reserved.

Transient rheology of crystallizing andesitic magmas

NASA Astrophysics Data System (ADS)

de Biasi, L. J.; Chevrel, M. O.; Hanson, J. B.; Cimarelli, C.; Lavallée, Y.; Dingwell, D. B.

2012-04-01

The viscosity of magma strongly influences its rheological behaviour, which is a key determinant of magma transport processes and volcanic eruptions. Understanding the factors controlling the viscosity of magma is important to our assessment of hazards posed by active volcanoes. In nature, magmas span a very wide range in viscosity (10-1 to 1014 Pa s), depending on chemical composition (including volatile content), temperature, and importantly, crystal fraction, which further induces a complex strain rate dependence (i.e. non-Newtonian rheology). Here, we present results of transient viscosities of a crystallizing andesitic melt (57 wt.% SiO2) from Tungurahua volcano (Ecuador). We followed the experimental method developed by Vona et al. (2011) for the concentric cylinder apparatus, but optimized its implementation by leaving the spindle in situ before quenching the experimental products, to preserve the complete developed texture of the sample. The viscosity is investigated under super-liquidus (1400 ° C) and sub-liquidus temperatures (1162 and 1167 ° C). For each temperature increment, thermal equilibrium is achieved over a period of days while the spindle constantly stirs the magma. Simultaneous monitoring of the torque is used to calculate the apparent viscosity of the transient suspension. To get a better understanding of the nucleation and crystal growth processes that are involved at sub-liquidus conditions, further time-step experiments were carried out, where the samples were quenched at various equilibration stages. The mineralogical assemblage, as well as the crystal fraction, distribution and preferential alignment were then quantitatively analyzed. At temperatures below the liquidus, the suspension shows a progressive, but irregular increase of the relative shear viscosity. First, the viscosity slightly increases, possibly due to the crystallization of small, equant oxides and the formation of plagioclase nuclei. After some time (1.5-2.5 days), crystallization of large, tabular plagioclase begins, inducing a significantly stronger increase in apparent viscosity until thermo-chemical equilibration is achieved. After continued stirring the apparent viscosity slightly decreases, likely due to increasing crystal alignment. The analysis of pre-equilibrium quenched samples indicates that crystals nucleate and grow preferentially in proximity to both the spindle and the crucible wall. Furthermore, decreasing the stirring rate (aka strain rate) results in an increase in the apparent viscosity, which evidences the non-Newtonian characteristics of the magmatic suspension. In conclusion, these experiments indicate that natural andesitic magmas undergo significant rheological changes at the onset of crystallization. The observed thermo-chemical variations elucidate a transient viscosity, which deserves consideration into all problems of magma transport. Reference: Vona, A., Romano, C., Dingwell, D.B., Giordano, D. 2011. The rheology of crystal-bearing basaltic magmas from Stromboli and Etna. Geochim. Cosmochim. Acta, 75, 3214-3236.

Calculation of shear viscosity using Green-Kubo relations within a parton cascade

NASA Astrophysics Data System (ADS)

Wesp, C.; El, A.; Reining, F.; Xu, Z.; Bouras, I.; Greiner, C.

2011-11-01

The shear viscosity of a gluon gas is calculated using the Green-Kubo relation. Time correlations of the energy-momentum tensor in thermal equilibrium are extracted from microscopic simulations using a parton cascade solving various Boltzmann collision processes. We find that the perturbation-QCD- (pQCD-) based gluon bremsstrahlung described by Gunion-Bertsch processes significantly lowers the shear viscosity by a factor of 3 to 8 compared to elastic scatterings. The shear viscosity scales with the coupling as η˜1/[αs2log(1/αs)]. For constant αs the shear viscosity to entropy density ratio η/s has no dependence on temperature. Replacing the pQCD-based collision angle distribution of binary scatterings by an isotropic form decreases the shear viscosity by a factor of 3.

Characteristics of Chemical and Functional Properties of Modified Cassava Flour (Manihot esculenta) by Autoclaving-Cooling Cycles Method

NASA Astrophysics Data System (ADS)

Cecep Erwan Andriansyah, Raden; Rahman, Taufik; Herminiati, Ainia; Rahman, Nurhaidar; Luthfiyanti, Rohmah

2017-12-01

The modified cassava flour can be made using the method of the autoclaving cooling cycle (AAC). The stability of the warming can be seen from the decreasing value of breakdown viscosity, while the stability of the stirring process can be seen by the decreasing value of setback viscosity. The stages of research include: (1) the making of cassava flour, (2) the making of modified cassava flour by the method of treatment of ACC with a variety of flour concentration and autoclaving time, (3) chemical analysis of the moisture, ash, fat, protein, carbohydrate; The functional properties of the pasting characteristics to the initial temperature of the pasting, peak viscosity, hot paste viscosity, breakdown viscosity, cold paste viscosity and setback viscosity. The result shows that cassava flour modified by treatment of flour concentration 16% and autoclaving time 41 minutes having pasting code and pasting viscosity which is resistant to high temperature. Flour with this character is flour that is expected to maintain the texture of processed products with a paste form that remains stable. Utilization of modified cassava flour by the ACC method can be applied to the pasting product such as noodle and spaghetti, hoping to support for food diversification program to reduce dependence on wheat flour in Indonesia.

Two-state protein model with water interactions: Influence of temperature on the intrinsic viscosity of myoglobin

DOE Office of Scientific and Technical Information (OSTI.GOV)

Bakk, Audun

2001-06-01

We describe a single-domain protein as a two-state system with water interactions. Around the unfolded apolar parts of the protein we incorporate the hydration effect by introducing hydrogen bonds between the water molecules in order to mimic the {open_quotes}icelike{close_quotes} shell structure. Intrinsic viscosity, proportional to the effective hydrodynamic volume, for sperm whale metmyoglobin is assigned from experimental data in the folded and in the denaturated state. By weighing statistically the two states against the degree of folding, we express the total intrinsic viscosity. The temperature dependence of the intrinsic viscosity, for different chemical potentials, is in good correspondence with experimentalmore » data [P. L. Privalov , J. Mol. Biol. >190, 487 (1986)]. Cold and warm unfolding, common to small globular proteins, is also a result of the model.« less

Rheology and tribology of lubricants with polymeric viscosity modifiers

NASA Astrophysics Data System (ADS)

Babak, LotfizadehDehkordi

Elastohydrodynamic lubrication (EHL) theory has been used to model the lubrication state of antifriction machine elements, where initial viscosity and pressure viscosity coefficients are essential parameters in film thickness modeling. Since the pressures of lubricants in the contact zone can be very high, it is important to know the rheological properties of lubricants in these pressure and temperature regimes. The characteristics of viscosity behavior as a function of pressure are also essential for a universal definition of the pressure viscosity coefficient in order to estimate film thickness in an EHL regime. In this study, viscosities and pressure-viscosity coefficients of ten commercial engine and gear oils and seventeen laboratory-produced oil/polymer viscosity modifiers (VM) additives are measured up to 1.3 GPa at 40, 75 and 100 °C. For the first time, a sharp increase in the viscosity and piezoviscous factor is observed in both mineral-based and synthetic-based oils with different VMs. Analysis of the experimental results indicates that sharp increase in viscosity observed in these experiments are believed to arise from physical changes in the VMs, that is liquid-solid phase transition. Evidence is offered that polymer properties such as molecular weight, concentration and structure influence the onset of the phase transitions. A modified Yasutomi model, which normally describes the pressure dependence of the viscosity of lubricants very well, fails to predict the viscosity of the specimens above the onset of sharp increase in viscosity. A design of experiment (DOE) analysis using Design-Expert software indicates that pressure and temperature are the most critical parameters in the viscosity variation. Tribological tests demonstrate that wear in the contact, zone occurs at temperatures and stresses that coincides with the VM phase transitions in both commercial and laboratory synthesized oil/VMs. Tribological results also indicate that the onset of the sharp increase in viscosity can have significant and unanticipated consequences on the elastohydrodynamic contact and can adversely affect EHL theory. The onset of the steep rise in viscosity may also affect the torque and power losses in a mechanical system. Hence, this previously unknown behavior of the lubricant with VMs should be seriously considered in the application of lubricant in mechanical system.

THE DEPENDENCE OF ION AND ELECTRON MOBILITY UPON MOLECULAR STRUCTURE IN DIELECTRIC LIQUIDS (in German)

DOE Office of Scientific and Technical Information (OSTI.GOV)

Adamczewski, I.

1961-09-01

The viscosity coefficient of dielectric liquids was found to be dependent upon molecular structure and temperature. From this a general formula for ion and electron mobility was derived. This formula includes the dependence of mobility upon molecular structure and temperature, thus making it possible to give a theoretical explanation of other published experimental results. In addition, the formula can be used to calculate ion mobility for a number of other liquids at various temperatures. (auth)

Transport properties of nonelectrolyte liquid mixtures. VIII. Viscosity coefficients for toluene and for three mixtures of toluene + hexane from 25 to 100°C at pressures up to 500 MPa

NASA Astrophysics Data System (ADS)

Dymond, J. H.; Awan, M. A.; Glen, N. F.; Isdale, J. D.

1991-03-01

Viscosity coefficients measured using a two-coil self-centering falling-body viscometer are reported for toluene and three binary mixtures of toluene + n-hexane at 25, 50, 75, and 100°C at pressures up to 500 MPa. The data for a given composition at different temperatures and pressures are correlated very satisfactorily by a plot of reduced viscosity η * versus log V', where V'= V· V 0(TR)/V0(T) and V 0 represents a characteristic volume. The binary mixture data are well represented by the Grunberg and Nissan equation with a mixing parameter which is pressure dependent but composition and temperature independent.

Solution of magnetohydrodynamic flow and heat transfer of radiative viscoelastic fluid with temperature dependent viscosity in wire coating analysis

PubMed Central

Khan, Muhammad Altaf; Siddiqui, Nasir; Ullah, Murad; Shah, Qayyum

2018-01-01

Wire coating process is a continuous extrusion process for primary insulation of conducting wires with molten polymers for mechanical strength and protection in aggressive environments. In the present study, radiative melt polymer satisfying third grade fluid model is used for wire coating process. The effect of magnetic parameter, thermal radiation parameter and temperature dependent viscosity on wire coating analysis has been investigated. Reynolds model and Vogel’s models have been incorporated for variable viscosity. The governing equations characterizing the flow and heat transfer phenomena are solved analytically by utilizing homotopy analysis method (HAM). The computed results are also verified by ND-Solve method (Numerical technique) and Adomian Decomposition Method (ADM). The effect of pertinent parameters is shown graphically. In addition, the instability of the flow in the flows of the wall of the extrusion die is well marked in the case of the Vogel model as pointed by Nhan-Phan-Thien. PMID:29596448

Viscosity of the liquid Al-6Mg-1Mn-0.2Sc-0.1Zr alloy

NASA Astrophysics Data System (ADS)

Reznik, P. L.; Chikova, O. A.; Tsepelev, V. S.

2017-07-01

The microstructure and the phase composition of as-cast Al-Mg-Mn-Sc-Zr alloy samples are studied by electron microscopy and electron-probe microanalysis. The processes of solidification and melting of this alloy are described. The temperature dependence of the kinematic viscosity of the Al-Mg-Mn-Sc-Zr melts is studied during heating and subsequent cooling of the samples. The measurement results are used to determine the temperature at which inherited microheterogeneities in the melts are destroyed irreversibly.

Transport and thermodynamic properties of hydrous melts in the system An-Di.

NASA Astrophysics Data System (ADS)

Giordano, D.; Potuzak, M.; Romano, C.; Russell, J. K.; Nowak, M.; Dingwell, D. B.

2006-12-01

The thermodynamic and transport properties hydrous silicate melts are of fundamental importance for characterization of the dynamics and energetics associated with silicate melts in the Earth. The literature concerning the transport and calorimetric properties of hydrous silicate melts remains scarce. With few exceptions little has been effectively done in order to provide chemical models that bridge the gap between the description of both complex and simple systems. The An-Di system is of general interest to geochemists as well as petrologists because it serves as a simple analogue for basaltic compositions. It was chosen here due to the combination of its simple chemical description and the presence of an extensive database of published experimental data on both its transport and thermodynamic properties. We have measured the viscosity (η)), the glass transition temperatures (Tg) and the heat capacity (Cp) of silicate melts in the An-Di system containing up to 3 wt.% of dissolved H2O. Viscosity data were obtained by using the dilatometric method of micropenetration, whereas a differential scanning calorimeter (DSC) was employed to determine the glass transition temperatures and the heat capacities. In order to characterize the well-known cooling/heating rate dependence of the glass transition temperatures the calorimetric measurements were performed at heating/cooling rate of 5, 10, 15 and 20 K/min. These results together with those of previous experimental studies have been used to provide a compositional model capable of calculating the Newtonian viscosity of melts as well as the Tg and Cp values for the An- Di+H2O system. The non-Arrhenian T-dependence of viscosity is accounted for by the Vogel-Fulcher- Tammann (VFT) and the Adam Gibbs (AG) equations. Our optimizations assume a common, high-T limit (A) for silicate melt viscosity, consistent with values provided by both theoretical and experimental studies. In particular, we also show that glass transition temperatures taken at each single heating/cooling rate are associated to single viscosity values. The equivalence of the activation energy associated to viscous and enthalpic relaxation process at specific temperatures also allow us to calibrate a tool to predict the viscosity of silicate melts by using specific heat curves. The effect of water on the heat capacity of the glass (Cpglass), from dry to nearly 3 wt% H2O, ranges from almost absent up to 20% of the measured Cp,glass values.

Compositional dependence of lower crustal viscosity

NASA Astrophysics Data System (ADS)

Shinevar, William J.; Behn, Mark D.; Hirth, Greg

2015-10-01

We calculate the viscosity structure of the lower continental crust as a function of its bulk composition using multiphase mixing theory. We use the Gibbs free-energy minimization routine Perple_X to calculate mineral assemblages for different crustal compositions under pressure and temperature conditions appropriate for the lower continental crust. The effective aggregate viscosities are then calculated using a rheologic mixing model and flow laws for the major crust-forming minerals. We investigate the viscosity of two lower crustal compositions: (i) basaltic (53 wt % SiO2) and (ii) andesitic (64 wt % SiO2). The andesitic model predicts aggregate viscosities similar to feldspar and approximately 1 order of magnitude greater than that of wet quartz. The viscosity range calculated for the andesitic crustal composition (particularly when hydrous phases are stable) is most similar to independent estimates of lower crust viscosity in actively deforming regions based on postglacial isostatic rebound, postseismic relaxation, and paleolake shoreline deflection.

Standard High Solids Vessel Design De-inventory Simulant Qualification

DOE Office of Scientific and Technical Information (OSTI.GOV)

Fiskum, Sandra K.; Burns, Carolyn A.M.; Gauglitz, Phillip A.

The Hanford Tank Waste Treatment and Immobilization Plant (WTP) is working to develop a Standard High Solids Vessel Design (SHSVD) process vessel. To support testing of this new design, WTP engineering staff requested that a Newtonian simulant be developed that would represent the de-inventory (residual high-density tank solids cleanout) process. Its basis and target characteristics are defined in 24590-WTP-ES-ENG-16-021 and implemented through PNNL Test Plan TP-WTPSP-132 Rev. 1.0. This document describes the de-inventory Newtonian carrier fluid (DNCF) simulant composition that will satisfy the basis requirement to mimic the density (1.18 g/mL ± 0.1 g/mL) and viscosity (2.8 cP ± 0.5more » cP) of 5 M NaOH at 25 °C.1 The simulant viscosity changes significantly with temperature. Therefore, various solution compositions may be required, dependent on the test stand process temperature range, to meet these requirements. Table ES.1 provides DNCF compositions at selected temperatures that will meet the density and viscosity specifications as well as the temperature range at which the solution will meet the acceptable viscosity tolerance.« less

Discontinuous Galerkin (DG) Method for solving time dependent convection-diffusion type temperature equation : Demonstration and Comparison with Other Methods in the Mantle Convection Code ASPECT

NASA Astrophysics Data System (ADS)

He, Y.; Puckett, E. G.; Billen, M. I.; Kellogg, L. H.

2016-12-01

For a convection-dominated system, like convection in the Earth's mantle, accurate modeling of the temperature field in terms of the interaction between convective and diffusive processes is one of the most common numerical challenges. In the geodynamics community using Finite Element Method (FEM) with artificial entropy viscosity is a popular approach to resolve this difficulty, but introduce numerical diffusion. The extra artificial viscosity added into the temperature system will not only oversmooth the temperature field where the convective process dominates, but also change the physical properties by increasing the local material conductivity, which will eventually change the local conservation of energy. Accurate modeling of temperature is especially important in the mantle, where material properties are strongly dependent on temperature. In subduction zones, for example, the rheology of the cold sinking slab depends nonlinearly on the temperature, and physical processes such as slab detachment, rollback, and melting all are sensitively dependent on temperature and rheology. Therefore methods that overly smooth the temperature may inaccurately represent the physical processes governing subduction, lithospheric instabilities, plume generation and other aspects of mantle convection. Here we present a method for modeling the temperature field in mantle dynamics simulations using a new solver implemented in the ASPECT software. The new solver for the temperature equation uses a Discontinuous Galerkin (DG) approach, which combines features of both finite element and finite volume methods, and is particularly suitable for problems satisfying the conservation law, and the solution has a large variation locally. Furthermore, we have applied a post-processing technique to insure that the solution satisfies a local discrete maximum principle in order to eliminate the overshoots and undershoots in the temperature locally. To demonstrate the capabilities of this new method we present benchmark results (e.g., falling sphere), and a simple subduction models with kinematic surface boundary condition. To evaluate the trade-offs in computational speed and solution accuracy we present results for the same benchmarks using the Finite Element entropy viscosity method available in ASPECT.

The Effect of Temperature Dependent Rheology on a Kinematic Model of Continental Breakup and Rifted Continental Margin Formation

NASA Astrophysics Data System (ADS)

Tymms, V. J.; Kusznir, N. J.

2004-12-01

The effect of temperature dependent rheology has been examined for a model of continental lithosphere thinning by an upwelling divergent flow field within continental lithosphere and asthenosphere leading to continental breakup and rifted continental margin formation. The model uses a coupled FE fluid flow and thermal solution and is kinematically driven using a half divergence rate Vx and upwelling velocity Vz. Viscosity structure is modified by the evolving temperature field of the model through the temperature dependent Newtonian rheology. Continental lithosphere and asthenosphere material are advected by the fluid-flow field in order to predict crustal and mantle lithosphere thinning leading to rifted continental margin formation. The results of the temperature dependent rheology model are compared with those of a simple isoviscous model. The temperature dependent rheology model predicts continental lithosphere thinning and depth dependent stretching, similar to that predicted by the uniform viscosity model. However compared with the uniform viscosity model the temperature dependent rheology predicts greater amounts of thinning of the continental crust and lithospheric mantle than the isoviscous solutions. An important parameter within the kinematic model of continental lithosphere breakup and rifted continental margin development is the velocity ratio Vz/Vx. For non-volcanic margins, Vz/Vx is thought to be around unity. Applying a velocity ratio Vz/Vx of unity gives a diffuse ocean-continent transition and exhumation of continental lithospheric mantle. For volcanic margins, Vz/Vx is of order 10, falling to unity with a half-life of order 10 Ma, leading to a more sharply defined ocean-continent transition. While Vx during continental breakup may be estimated, Vz can only be inferred. FE fluid flow solutions, in which Vz is not imposed and without an initial buoyancy driven flow component, predict a velocity ratio Vz/Vx of around unity for both temperature dependent rheology and isovisous fluid-flow solutions. The effect of incorporating a lithology dependent continental lithosphere rheology (quartz-feldspar crust, olivine mantle) with temperature dependence is also being investigated. The work forms part of the Integrated Seismic Imaging and Modelling of Margins (iSIMM*) project. This work forms part of the NERC Margins iSIMM project. iSIMM investigators are from Liverpool and Cambridge Universities, Schlumberger Cambridge Research & Badley Geoscience, supported by the NERC, the DTI, Agip UK, BP, Amerada Hess Ltd, Anadarko, Conoco-Phillips, Shell, Statoil and WesternGeco. The iSIMM team comprises NJ Kusznir, RS White, AM Roberts, PAF Christie, R Spitzer, N Hurst, ZC Lunnon, CJ Parkin, AW Roberts, LK Smith, V Tymms & D. Healy.

Negative Magnetoresistance in Viscous Flow of Two-Dimensional Electrons.

PubMed

Alekseev, P S

2016-10-14

At low temperatures, in very clean two-dimensional (2D) samples, the electron mean free path for collisions with static defects and phonons becomes greater than the sample width. Under this condition, the electron transport occurs by formation of a viscous flow of an electron fluid. We study the viscous flow of 2D electrons in a magnetic field perpendicular to the 2D layer. We calculate the viscosity coefficients as the functions of magnetic field and temperature. The off-diagonal viscosity coefficient determines the dispersion of the 2D hydrodynamic waves. The decrease of the diagonal viscosity in magnetic field leads to negative magnetoresistance which is temperature and size dependent. Our analysis demonstrates that this viscous mechanism is responsible for the giant negative magnetoresistance recently observed in the ultrahigh-mobility GaAs quantum wells. We conclude that 2D electrons in those structures in moderate magnetic fields should be treated as a viscous fluid.

Negative Magnetoresistance in Viscous Flow of Two-Dimensional Electrons

NASA Astrophysics Data System (ADS)

Alekseev, P. S.

2016-10-01

At low temperatures, in very clean two-dimensional (2D) samples, the electron mean free path for collisions with static defects and phonons becomes greater than the sample width. Under this condition, the electron transport occurs by formation of a viscous flow of an electron fluid. We study the viscous flow of 2D electrons in a magnetic field perpendicular to the 2D layer. We calculate the viscosity coefficients as the functions of magnetic field and temperature. The off-diagonal viscosity coefficient determines the dispersion of the 2D hydrodynamic waves. The decrease of the diagonal viscosity in magnetic field leads to negative magnetoresistance which is temperature and size dependent. Our analysis demonstrates that this viscous mechanism is responsible for the giant negative magnetoresistance recently observed in the ultrahigh-mobility GaAs quantum wells. We conclude that 2D electrons in those structures in moderate magnetic fields should be treated as a viscous fluid.

Compressing turbulence and sudden viscous dissipation with compression-dependent ionization state

DOE Office of Scientific and Technical Information (OSTI.GOV)

Davidovits, Seth; Fisch, Nathaniel J.

Turbulent plasma flow, amplified by rapid three-dimensional compression, can be suddenly dissipated under continuing compression. Furthermore, this effect relies on the sensitivity of the plasma viscosity to the temperature, μ ~ T 5 / 2 . The plasma viscosity is also sensitive to the plasma ionization state. Here, we show that the sudden dissipation phenomenon may be prevented when the plasma ionization state increases during compression, and we demonstrate the regime of net viscosity dependence on compression where sudden dissipation is guaranteed. In addition, it is shown that, compared to cases with no ionization, ionization during compression is associated withmore » larger increases in turbulent energy and can make the difference between growing and decreasing turbulent energy.« less

Compressing turbulence and sudden viscous dissipation with compression-dependent ionization state

DOE PAGES

Davidovits, Seth; Fisch, Nathaniel J.

2016-11-14

Turbulent plasma flow, amplified by rapid three-dimensional compression, can be suddenly dissipated under continuing compression. Furthermore, this effect relies on the sensitivity of the plasma viscosity to the temperature, μ ~ T 5 / 2 . The plasma viscosity is also sensitive to the plasma ionization state. Here, we show that the sudden dissipation phenomenon may be prevented when the plasma ionization state increases during compression, and we demonstrate the regime of net viscosity dependence on compression where sudden dissipation is guaranteed. In addition, it is shown that, compared to cases with no ionization, ionization during compression is associated withmore » larger increases in turbulent energy and can make the difference between growing and decreasing turbulent energy.« less

A numerical study of magnetohydrodynamic transport of nanofluids over a vertical stretching sheet with exponential temperature-dependent viscosity and buoyancy effects

NASA Astrophysics Data System (ADS)

Akbar, Noreen Sher; Tripathi, Dharmendra; Khan, Zafar Hayat; Bég, O. Anwar

2016-09-01

In this paper, a mathematical study is conducted of steady incompressible flow of a temperature-dependent viscous nanofluid from a vertical stretching sheet under applied external magnetic field and gravitational body force effects. The Reynolds exponential viscosity model is deployed. Electrically-conducting nanofluids are considered which comprise a suspension of uniform dimension nanoparticles suspended in viscous base fluid. The nanofluid sheet is extended with a linear velocity in the axial direction. The Buonjiornio model is utilized which features Brownian motion and thermophoresis effects. The partial differential equations for mass, momentum, energy and species (nano-particle concentration) are formulated with magnetic body force term. Viscous and Joule dissipation effects are neglected. The emerging nonlinear, coupled, boundary value problem is solved numerically using the Runge-Kutta fourth order method along with a shooting technique. Graphical solutions for velocity, temperature, concentration field, skin friction and Nusselt number are presented. Furthermore stream function plots are also included. Validation with Nakamura's finite difference algorithm is included. Increasing nanofluid viscosity is observed to enhance temperatures and concentrations but to reduce velocity magnitudes. Nusselt number is enhanced with both thermal and species Grashof numbers whereas it is reduced with increasing thermophoresis parameter and Schmidt number. The model is applicable in nano-material manufacturing processes involving extruding sheets.

Numerical investigation of magnetohydrodynamic slip flow of power-law nanofluid with temperature dependent viscosity and thermal conductivity over a permeable surface

NASA Astrophysics Data System (ADS)

Hussain, Sajid; Aziz, Asim; Khalique, Chaudhry Masood; Aziz, Taha

2017-12-01

In this paper, a numerical investigation is carried out to study the effect of temperature dependent viscosity and thermal conductivity on heat transfer and slip flow of electrically conducting non-Newtonian nanofluids. The power-law model is considered for water based nanofluids and a magnetic field is applied in the transverse direction to the flow. The governing partial differential equations(PDEs) along with the slip boundary conditions are transformed into ordinary differential equations(ODEs) using a similarity technique. The resulting ODEs are numerically solved by using fourth order Runge-Kutta and shooting methods. Numerical computations for the velocity and temperature profiles, the skin friction coefficient and the Nusselt number are presented in the form of graphs and tables. The velocity gradient at the boundary is highest for pseudoplastic fluids followed by Newtonian and then dilatant fluids. Increasing the viscosity of the nanofluid and the volume of nanoparticles reduces the rate of heat transfer and enhances the thickness of the momentum boundary layer. The increase in strength of the applied transverse magnetic field and suction velocity increases fluid motion and decreases the temperature distribution within the boundary layer. Increase in the slip velocity enhances the rate of heat transfer whereas thermal slip reduces the rate of heat transfer.

Calibration of the Oscillating Screen Viscometer

NASA Technical Reports Server (NTRS)

Berg, Robert F.; Moldover, Michael R.

1993-01-01

We have devised a calibration procedure for the oscillating screen viscometer which can provide the accuracy needed for the flight measurement of viscosity near the liquid-vapor critical point of xenon. The procedure, which makes use of the viscometer's wide bandwidth and hydrodynamic similarity, allows the viscometer to be self-calibrating. To demonstrate the validity of this procedure we measured the oscillator's transfer function under a wide variety of conditions. We obtained data using CO2 at temperatures spanning a temperature range of 35 K and densities varying by a factor of 165, thereby encountering viscosity variations as great as 50%. In contrast the flight experiment will be performed over a temperature range of 29 K and at only a single density, and the viscosity is expected to change by less than 40%. The measurements show that, after excluding data above 10 Hz (where frequency-dependent corrections are poorly modeled) and making a plausible adjustment to the viscosity value used at high density, the viscometer's behavior is fully consistent with the use of hydrodynamic similarity for calibration. Achieving this agreement required understanding a 1% anelastic effect present in the oscillator's torsion fiber.

Transport in thin polarized Fermi-liquid films

NASA Astrophysics Data System (ADS)

Li, David Z.; Anderson, R. H.; Miller, M. D.

2015-10-01

We calculate expressions for the state-dependent quasiparticle lifetime τσ, the thermal conductivity κ , the shear viscosity η , and discuss the spin diffusion coefficient D for Fermi-liquid films in two dimensions. The expressions are valid for low temperatures and arbitrary polarization. In two dimensions, as in three dimensions, the integrals over the transition rates factor into energy and angular parts. However, the angular integrations contain a weak divergence. This problem is addressed using the method of K. Miyake and W. J. Mullin [Phys. Rev. Lett. 50, 197 (1983), 10.1103/PhysRevLett.50.197; J. Low Temp. Phys. 56, 499 (1984), 10.1007/BF00681808]. The low-temperature expressions for the transport coefficients are essentially exact. We find that κ-1˜T lnT , and η-1˜T2 for arbitrary polarizations 0 ≤P ≤1 . These results are in agreement with earlier zero-polarization results of H. H. Fu and C. Ebner [Phys. Rev. A 10, 338 (1974)., 10.1103/PhysRevA.10.338], but differ from the temperature dependence of the shear viscosity found by D. S. Novikov (arXiv:cond-mat/0603184). They also differ from the discontinuous change of temperature dependence in D from zero to nonzero polarization that was discovered by Miyake and Mullin. We note that in two dimensions the shear viscosity requires a unique analysis. We obtain predictions for the density, temperature, and polarization dependence of κ ,η , and D for second-layer 3He films on graphite, and thin 3He-4He superfluid mixtures. For 3He on graphite, we find roughly an order of magnitude increase in magnitude for κ and η as the polarization is increased from 0 to 1. For D a similar large increase is predicted from zero polarization to the polarization where D is a maximum (˜0.74 ). We discuss the applicability of 3He thin films to the question of the existence of a universal lower bound for the ratio of the shear viscosity to the entropy density.

Viscosity of komatiite liquid at high pressure and temperature

NASA Astrophysics Data System (ADS)

O Dwyer, L.; Lesher, C. E.; Wang, Y.

2006-12-01

The viscosities of komatiite liquids at high pressures and temperatures are being investigated by the in-situ falling sphere technique, using the T-25 multianvil apparatus at the GSECARS 13 ID-D beamline at the Advanced Photon Source, ANL. The refractory and fluid nature of komatiite and other ultramafic liquids relevant to the Earth's deep interior, presents unique challenges for this approach. To reach superliquidus temperatures we use a double reservoir configuration, where marker spheres are placed at the top of both a main melt reservoir and an overlying reservoir containing a more refractory composition. Using this approach, we have successfully measured the viscosity of a komatiite from Gorgona Island (GOR-94-29; MgO - 17.8 wt.%; NBO/T = 1.6) up to 6 GPa and 1900 K. Under isothermal conditions, viscosity increases with pressure, consistent with the depolymerized nature of the komatiite. At 1900 K, viscosity increases from 1.5 (+- 0.3) Pa s at 3.5 GPa to 3.4 (+- 0.3) Pa s at 6 GPa, corresponding to an activation volume of 2.2 cm3/mol. At high pressures, the viscosities of Gorgona Island komatiite melt are an order of magnitude higher than those measured by Liebske et al. (2005, EPSL, v. 240) for peridotite melt (MgO 37.1 wt.%; NBO/T = 2.5), and similar in magnitude to molten diopside (NBO/T = 2) (Reid et al. 2003, PEPI, v. 139). The positive pressure dependence is consistent with the reduction in interatomic space diminishing the free volume of the liquid as it is compressed. Above 6 GPa the free volume reduction may become less important with the production of high-coordinated network formers, as attributed to the reversal of the pressure dependence of viscosity for peridotite melt at ~8.5 GPa and diopside melt at ~10 GPa. Experiments at higher pressures are underway to determine if a similar viscosity maximum occurs for komatiite melt and whether its pressure is greater than 10 GPa, as suggested by the data for peridotite and diopside melts.

Inference of viscosity jump at 670 km depth and lower mantle viscosity structure from GIA observations

NASA Astrophysics Data System (ADS)

Nakada, Masao; Okuno, Jun'ichi; Irie, Yoshiya

2018-03-01

A viscosity model with an exponential profile described by temperature (T) and pressure (P) distributions and constant activation energy (E_{{{um}}}^{{*}} for the upper mantle and E_{{{lm}}}^* for the lower mantle) and volume (V_{{{um}}}^{{*}} and V_{{{lm}}}^*) is employed in inferring the viscosity structure of the Earth's mantle from observations of glacial isostatic adjustment (GIA). We first construct standard viscosity models with an average upper-mantle viscosity ({\\bar{η }_{{{um}}}}) of 2 × 1020 Pa s, a typical value for the oceanic upper-mantle viscosity, satisfying the observationally derived three GIA-related observables, GIA-induced rate of change of the degree-two zonal harmonic of the geopotential, {\\dot{J}_2}, and differential relative sea level (RSL) changes for the Last Glacial Maximum sea levels at Barbados and Bonaparte Gulf in Australia and for RSL changes at 6 kyr BP for Karumba and Halifax Bay in Australia. Standard viscosity models inferred from three GIA-related observables are characterized by a viscosity of ˜1023 Pa s in the deep mantle for an assumed viscosity at 670 km depth, ηlm(670), of (1 - 50) × 1021 Pa s. Postglacial RSL changes at Southport, Bermuda and Everglades in the intermediate region of the North American ice sheet, largely dependent on its gross melting history, have a crucial potential for inference of a viscosity jump at 670 km depth. The analyses of these RSL changes based on the viscosity models with {\\bar{η }_{{{um}}}} ≥ 2 × 1020 Pa s and lower-mantle viscosity structures for the standard models yield permissible {\\bar{η }_{{{um}}}} and ηlm (670) values, although there is a trade-off between the viscosity and ice history models. Our preferred {\\bar{η }_{{{um}}}} and ηlm (670) values are ˜(7 - 9) × 1020 and ˜1022 Pa s, respectively, and the {\\bar{η }_{{{um}}}} is higher than that for the typical value of oceanic upper mantle, which may reflect a moderate laterally heterogeneous upper-mantle viscosity. The mantle viscosity structure adopted in this study depends on temperature distribution and activation energy and volume, and it is difficult to discuss the impact of each quantity on the inferred lower-mantle viscosity model. We conclude that models of smooth depth variation in the lower-mantle viscosity following η ( z ) ∝ {{ exp}}[ {( {E_{{{lm}}}^* + P( z )V_{{{lm}}}^*} )/{{R}}T( z )} ] with constant E_{{{lm}}}^* and V_{{{lm}}}^* are consistent with the GIA observations.

The effects of temperature, organic matter and time-dependency on rheological properties of dry anaerobic digested swine manure.

PubMed

Liu, Gang-Jin; Liu, Yi; Wang, Zhi-Yong; Lei, Yun-Hui; Chen, Zi-Ai; Deng, Liang-Wei

2015-04-01

An efficient way to avoid the pollution of swine wastewater is the application of dry anaerobic digestion, which needs rheological parameter for stirring and pipe designing. The rheological properties of this kind of sludge have been studied for many decades, yet their effects only solid concentration has been investigated widely. In this paper, the influences of temperature, organic and time-dependency on the efficiency of anaerobic digested swine manure were studied. The viscosity decreased with temperature arranged from 10 to 60 °C which caused increase in protein from 7.18 to 8.49 g/kg. 60 °C can make the digested swine manure with TS from 16.6% to 21.5% reach to the same rheology state. The added peptone decreased the viscosity because of its function of water-reducing admixture and air entraining mixture. Time-dependent experiment showed the decrease of shear stress over time. The first and the second yield stress of dry anaerobic digested swine manure were evaluated through time-dependent model. Copyright © 2015 Elsevier Ltd. All rights reserved.

Thermodynamic properties and transport coefficients of two-temperature helium thermal plasmas

NASA Astrophysics Data System (ADS)

Guo, Xiaoxue; Murphy, Anthony B.; Li, Xingwen

2017-03-01

Helium thermal plasmas are in widespread use in arc welding and many other industrial applications. Simulation of these processes relies on accurate plasma property data, such as plasma composition, thermodynamic properties and transport coefficients. Departures from LTE (local thermodynamic equilibrium) generally occur in some regions of helium plasmas. In this paper, properties are calculated allowing for different values of the electron temperature, T e, and heavy-species temperature, T h, at atmospheric pressure from 300 K to 30 000 K. The plasma composition is first calculated using the mass action law, and the two-temperature thermodynamic properties are then derived. The viscosity, diffusion coefficients, electrical conductivity and thermal conductivity of the two-temperature helium thermal plasma are obtained using a recently-developed method that retains coupling between electrons and heavy species by including the electron-heavy-species collision term in the heavy-species Boltzmann equation. It is shown that the viscosity and the diffusion coefficients strongly depend on non-equilibrium ratio θ (θ ={{T}\\text{e}}/{{T}\\text{h}} ), through the plasma composition and the collision integrals. The electrical conductivity, which depends on the electron number density and ordinary diffusion coefficients, and the thermal conductivity have similar dependencies. The choice of definition of the Debye length is shown to affect the electrical conductivity significantly for θ  >  1. By comparing with literature data, it is shown that the coupling between electrons and heavy species has a significant influence on the electrical conductivity, but not on the viscosity. Plasma properties are tabulated in the supplementary data.

Structure and phase transitions of asphaltenes in solutions

DOE Office of Scientific and Technical Information (OSTI.GOV)

Tar, M.M. de; Sheu, E.Y.; Storm, D.A.

The authors investigated the rheological properties of two vacuum resid fractions in a series of solvents. The authors measured the viscosity as a function of concentration and temperature respectively. In this study, two aspects were focused: (1) the concentration dependence of viscosity for the pentane soluble fractions in a series of n-alkane solvents for study of the particle structure, and (2) the temperature dependence of viscosity of the heptane insoluble fraction in toluene at various concentrations for the study of the phase transitions. From their results it was found that all the systems studied are Newtonian. The results for (1)more » show that the particles are approximately spherical and as the carbon number of the n-alkane solvent increases, the quality of the solvent increases, thereby increasing the particle solvation. This result is consistent with that reported in a recent paper by Ali and Saleem. Also, the particles were found to behave similarly to colloidal particles. As for (2), a glass-like transition was observed at 50% concentration (0.31 volume fraction) with glass transition temperature at about 254 K, while no structural or phase transitions were observed for concentrations below 50%.« less

Temperature transition of human hemoglobin at body temperature: effects of calcium.

PubMed Central

Kelemen, C; Chien, S; Artmann, G M

2001-01-01

We studied the effects of calcium ion concentration on the temperature dependence of rheological behavior of human red blood cells (RBCs) and concentrated hemoglobin solutions. Our previous study (G. M. Artmann, C. Kelemen, D. Porst, G. Büldt, and S. Chien, 1998, Biophys. J., 75:3179-3183) showed a critical temperature (Tc) of 36.4 +/- 0.3 degrees C at which the RBCs underwent a transition from non-passage to passage through 1.3 microm micropipettes in response to an aspiration pressure of -2.3 kPa. An increase in intracellular Ca2+ concentration by using the ionophore A23187 reduced the passability of intact RBCs through small micropipettes above T(c); the micropipette diameter needed for >90% passage increased to 1.7 microm. Viscometry of concentrated hemoglobin solutions (45 and 50 g/dl) showed a sudden viscosity transition at 36 +/- 1 degrees C (Tc(eta)) at all calcium concentrations investigated. Below Tc(eta), the viscosity value of the concentrated hemoglobin solution at 1.8 mM Ca(2+) was higher than that at other concentrations (0.2 microM, 9 mM, and 18 mM). Above Tc(eta), the viscosity was almost Ca2+ independent. At 1.8 mM Ca2+ and 36 +/- 1 degrees C, the activation energy calculated from the viscometry data showed a strong dependence on the hemoglobin concentration. We propose that the transition of rheological behavior is attributable to a high-to-low viscosity transition mediated by a partial release of the hemoglobin-bound water. PMID:11371439

Transport properties of nonelectrolyte liquid mixtures—II. Viscosity coefficients for the n-hexane + n-hexadecane system at temperatures from 25 to 100‡C at pressures up to the freezing pressure or 500 MPa

NASA Astrophysics Data System (ADS)

Dymond, J. H.; Young, K. J.; Isdale, J. D.

1980-12-01

Viscosity coefficients measured with an estimated accuracy of 2% using a self-centering falling body viscometer are reported for n-hexane, n-hexadecane, and four binary mixtures at 25, 50, 75, and 100‡C at pressures up to the freezing pressure or 500 MPa. The data for a given composition at different temperatures and pressures are very satisfactorily correlated by a plot of Ή, defined as 104 ηV 2/3/( MT)1/2 in the cgs system of units, or generally, 9.118×107 η V 2/3/( MRT)1/2, versus log V', as suggested by the hard-sphere theories, where V' = V · V 0( T R)/ V 0( T) and V 0 represents the close-packed volume at temperature T and reference temperature T R . The experimental results for all compositions are fitted, generally well within the estimated uncertainty, by the equation 1 10765_2004_Article_BF00516563_TeX2GIFE1.gif ln η ' = {text{ - 1}}{text{.0 + }}{BV_0 }/{V - V_0 } where B and V 0 are temperature and composition dependent. Values of B and V 0 for the mixtures are simply related to values for the pure liquids, and viscosity coefficients calculated on the basis of this equation have an estimated accuracy of 3%. The effectiveness of the recently recommended empirical Grunberg and Nissan equation is investigated. It is found that the parameter G is pressure dependent, as well as composition dependent, but is practically temperature independent.

Effect of Oils on Kinematic Viscosity of R134a

NASA Astrophysics Data System (ADS)

Sato, Tomoaki; Takaishi, Yoshinori; Oguchi, Kosei

The kinematic viscosity defined as a ratio of viscosity to density is one of the key properties in producing technically important dimensionless numbers such as Prandtl and Reynolds numbers. We measured both viscosity and density of R134a/POE and R134a/PAG mixtures at saturation in the range of relatively low oilconcentrations. The density measurements for oil-concentrations up to 50 mass% were conducted with a densimeter making use of glass buoys within overall uncertainty of ±1.0%, and the viscosity measurements for oil-concentrations up to 16 mass% were carried out with an oscillating-cup viscometer making use of polarizer with overall uncertainty less than ±3.5%. The kinematic viscosities obtained from the experimental viscosity and density data are presented for both R134a/POE and R134a/PAG mixtures in the range of temperatures from 278 K to 288 K for oil-concentrations up to 15 mass%. The oil-concentration dependence of the kinematic viscosity for both mixtures is also reported.

DOE Office of Scientific and Technical Information (OSTI.GOV)

Mamontov, Eugene; O'Neil, Hugh

In this paper, we have studied microscopic dynamics of a protein in carbon disulfide, a non-glass forming solvent, down to its freezing temperature of ca. 160 K. We have utilized quasielastic neutron scattering. A comparison of lysozyme hydrated with water and dissolved in carbon disulfide reveals a stark difference in the temperature dependence of the protein's microscopic relaxation dynamics induced by the solvent. In the case of hydration water, the common protein glass-forming solvent, the protein relaxation slows down in response to a large increase in the water viscosity on cooling down, exhibiting a well-known protein dynamical transition. The dynamicalmore » transition disappears in non-glass forming carbon disulfide, whose viscosity remains a weak function of temperature all the way down to freezing at just below 160 K. The microscopic relaxation dynamics of lysozyme dissolved in carbon disulfide is sustained down to the freezing temperature of its solvent at a rate similar to that measured at ambient temperature. Finally, our results demonstrate that protein dynamical transition is not merely solvent-assisted, but rather solvent-induced, or, more precisely, is a reflection of the temperature dependence of the solvent's glass-forming dynamics.« less

The Relation between Vaporization Enthalpies and Viscosities: Eyring's Theory Applied to Selected Ionic Liquids.

PubMed

Bonsa, Anne-Marie; Paschek, Dietmar; Zaitsau, Dzmitry H; Emel'yanenko, Vladimir N; Verevkin, Sergey P; Ludwig, Ralf

2017-05-19

Key properties for the use of ionic liquids as electrolytes in batteries are low viscosities, low vapor pressure and high vaporization enthalpies. Whereas the measurement of transport properties is well established, the determination of vaporization enthalpies of these extremely low volatile compounds is still a challenge. At a first glance both properties seem to describe different thermophysical phenomena. However, eighty years ago Eyring suggested a theory which related viscosities and vaporization enthalpies to each other. The model is based on Eyring's theory of absolute reaction rates. Recent attempts to apply Eyring's theory to ionic liquids failed. The motivation of our study is to show that Eyring's theory works, if the assumptions specific for ionic liquids are fulfilled. For that purpose we measured the viscosities of three well selected protic ionic liquids (PILs) at different temperatures. The temperature dependences of viscosities were approximated by the Vogel-Fulcher-Tamann (VFT) relation and extrapolated to the high-temperature regime up to 600 K. Then the VFT-data could be fitted to the Eyring-model. The values of vaporization enthalpies for the three selected PILs predicted by the Eyring model have been very close to the experimental values measured by well-established techniques. We conclude that the Eyring theory can be successfully applied to the chosen set of PILs, if the assumption that ionic pairs of the viscous flow in the liquid and the ionic pairs in the gas phase are similar is fulfilled. It was also noticed that proper transfer of energies can be only derived if the viscosities and the vaporization energies are known for temperatures close to the liquid-gas transition temperature. The idea to correlate easy measurable viscosities of ionic liquids with their vaporization enthalpies opens a new way for a reliable assessment of these thermodynamic properties for a broad range of ionic liquids. © 2017 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.

Numerical studies on convective stability and flow pattern in three-dimensional spherical mantle of terrestrial planets

NASA Astrophysics Data System (ADS)

Yanagisawa, Takatoshi; Kameyama, Masanori; Ogawa, Masaki

2016-09-01

We explore thermal convection of a fluid with a temperature-dependent viscosity in a basally heated 3-D spherical shell using linear stability analyses and numerical experiments, while considering the application of our results to terrestrial planets. The inner to outer radius ratio of the shell f assumed in the linear stability analyses is in the range of 0.11-0.88. The critical Rayleigh number Rc for the onset of thermal convection decreases by two orders of magnitude as f increases from 0.11 to 0.88, when the viscosity depends sensitively on the temperature, as is the case for real mantle materials. Numerical simulations carried out in the range of f = 0.11-0.55 show that a thermal boundary layer (TBL) develops both along the surface and bottom boundaries to induce cold and hot plumes, respectively, when f is 0.33 or larger. However, for smaller f values, a TBL develops only on the bottom boundary. Convection occurs in the stagnant-lid regime where the root mean square velocity on the surface boundary is less than 1 per cent of its maximum at depth, when the ratio of the viscosity at the surface boundary to that at the bottom boundary exceeds a threshold that depends on f. The threshold decreases from 106.5 at f = 0.11 to 104 at f = 0.55. If the viscosity at the base of the convecting mantle is 1020-1021 Pa s, the Rayleigh number exceeds Rc for Mars, Venus and the Earth, but does not for the Moon and Mercury; convection is unlikely to occur in the latter planets unless the mantle viscosity is much lower than 1020 Pa s and/or the mantle contains a strong internal heat source.

Frequency-Dependent Viscosity of Xenon Near the Critical Point

NASA Technical Reports Server (NTRS)

Berg, Robert F.; Moldover, Michael R.; Zimmerli, Gregory A.

1999-01-01

We used a novel, overdamped oscillator aboard the Space Shuttle to measure the viscosity eta of xenon near its critical density rho(sub c), and temperature T(sub c). In microgravity, useful data were obtained within 0.1 mK of T(sub c), corresponding to a reduced temperature t = (T -T(sub c))/T(sub c) = 3 x 10(exp -7). The data extend two decades closer to T(sub c) than the best ground measurements, and they directly reveal the expected power-law behavior eta proportional to t(sup -(nu)z(sub eta)). Here nu is the correlation length exponent, and our result for the small viscosity exponent is z(sub eta) = 0.0690 +/- 0.0006. (All uncertainties are one standard uncertainty.) Our value for z(sub eta) depends only weakly on the form of the viscosity crossover function, and it agrees with the value 0.067 +/- 0.002 obtained from a recent two-loop perturbation expansion. The measurements spanned the frequency range 2 Hz less than or equal to f less than or equal to 12 Hz and revealed viscoelasticity when t less than or equal to 10(exp -1), further from T(sub c) than predicted. The viscoelasticity scales as Af(tau), where tau is the fluctuation-decay time. The fitted value of the viscoelastic time-scale parameter A is 2.0 +/- 0.3 times the result of a one-loop perturbation calculation. Near T(sub c), the xenon's calculated time constant for thermal diffusion exceeded days. Nevertheless, the viscosity results were independent of the xenon's temperature history, indicating that the density was kept near rho(sub c), by judicious choices of the temperature vs. time program. Deliberately bad choices led to large density inhomogeneities. At t greater than 10(exp -5), the xenon approached equilibrium much faster than expected, suggesting that convection driven by microgravity and by electric fields slowly stirred the sample.

Composition and Temperature Dependence of Shear Viscosity of Hydrocarbon Mixtures

DTIC Science & Technology

1980-07-01

HNN- XTHDCPD Binary System IX. VTF Eq. Parameters for Shear Viscosities Using Constant B Parameter X. Results of Fits to Master Viscosity Eqs. (43...T(K) for 5 C10 Hydrocarbons I Fig. 2a. log n versus 103/T(K) for HNNi I Fig. 2b. log n versus 103/T(K) for XTHDCPD Fig. 3. Isothem of log n versus X...CD for CO-MO Binary System Fig. 4. Isotherm of log n versus XNBC for NBC-DMO Binary System ( ~Fig. 5. Isotherm of log n versus XfINN for HNN- XTHDCPD

The temperature dependence of ponded infiltration under isothermal conditions

USGS Publications Warehouse

Constantz, J.; Murphy, F.

1991-01-01

A simple temperature-sensitive modification to the Green and Ampt infiltration equation is described; this assumes that the temperature dependence of the hydraulic conductivity is reciprocally equal to the temperature dependence of the viscosity of liquid water, and that both the transmission zone saturation and the wetting front matric potential gradient are independent of temperature. This modified Green and Ampt equation is compared with ponded, isothermal infiltration experiments run on repacked columns of Olympic Sand and Aiken Loam at 5, 25, and 60??C. Experimental results showed increases in infiltration rates of at least 300% between 5 and 60??C for both soil materials, with subsequent increases in cumulative infiltration of even greater magnitudes for the loam. There is good agreement between measured and predicted initial infiltration rates at 25??C for both soil materials, yet at 60??C, the predicted results overestimate initial infiltration rates for the sand and underestimate initial rates for the loam. Measurements of the wetting depth vs. cumulative infiltration indicate that the transmission zone saturation increased with increasing temperature for both soil materials. In spite of this increased saturation with temperature, the final infiltration rates at both 25 and 60??C were predicted accurately using the modified Green and Ampt equation. This suggests that increased saturation occurred primarily in dead-end pore spaces, so that transmission zone hydraulic conductivities were unaffected by these temperature-induced changes in saturation. In conclusion, except for initial infiltration rates at 60??C, the measured influence of temperature on infiltration rates was fully accounted for by the temperature dependence of the viscosity of liquid water. ?? 1991.

Non-Newtonian behavior of plagioclase-bearing basaltic magma: Subliquidus viscosity measurement of the 1707 basalt of Fuji volcano, Japan

NASA Astrophysics Data System (ADS)

Ishibashi, Hidemi

2009-03-01

Laboratory measurements of viscosity were done for basalt erupted in 1707 AD from Fuji volcano, Japan, using a concentric cylinder rotational viscometer at temperatures of 1297-1157 °C, 1 atm pressure, and fO 2 near the Ni-NiO buffer. On cooling, elongated plagioclase crystals with a mean length/width ratio of ca. 8.5 appeared at 1237 °C, followed by olivine at 1157 °C. At progressively lower temperatures, the total crystal volume fraction increased monotonously to ca. 0.25; viscosity increased from 38.9 to 765 Pa s at a shear strain rate of 1 s - 1 . This basalt magma behaves as a Newtonian fluid at temperatures greater than 1217 °C, but shear-thinning behavior occurs at temperatures less than 1197 °C because of the suspended plagioclase crystals. This behavior is well approximated as a power law fluid. At the onset of shear thinning, the crystal volume fraction was between 0.06 and 0.13, which is attributed to the pronounced lath-shape of plagioclase crystals. The relative viscosity increases monotonously with increase of crystal volume fraction at a constant shear strain rate, and with decrease of shear strain rate at a constant crystal volume fraction. A modified form of the Krieger-Dougherty equation is introduced herein. It enables us to describe the dependencies of relative viscosity on both the crystal volume fraction and shear strain rate, and consequently the onset of shear-thinning behavior.

Silicate melts: The “anomalous” pressure dependence of the viscosity

NASA Astrophysics Data System (ADS)

Bottinga, Y.; Richet, P.

1995-07-01

The decrease of the specific volume, when the extent of polymerization diminishes, is a cause of the pressure sensitivity of the viscosity of silicate melts. This effect can be explained by means of the Adam and Gibbs (1965) theory, taking into account the pressure dependence of the degree of polymerization of the melt and its influence on the configurational entropy. At temperatures close to their glass transitions, liquid silica and SiO2sbnd Na2O melts have configurational entropies that are probably due to the mixing of their bridging and nonbridging oxygen atoms.

Study of the viscosity behaviour of glasses obtained from urban wastewater treatment sludges from Egypt using hot stage microscopy

NASA Astrophysics Data System (ADS)

Garcia-Valles, M.

2012-04-01

The volume of sludge produced in wastewater treatment plants in Egypt is becoming more important; this paper studied the chemical composition of sludge from four treatment plants located around Nile delta and valley: El-Sadat City (E-01), Alexandria (E-02), Abo-Rawash (E-03) and Minufiya (E-04), and is suggested as a possible solution, the vitrification of these sludges. Another important objective for obtaining correct this glass is to know the viscosity temperature curve, including developing a prototype of hot stage microscopy (HSM) and development of software suitable for the analysis of images. Each image has different morphology related to different viscosity, can that way determine the viscosity at the temperature of heating. The chemical composition of these sludges is close to a basalt rock except that the phosphorus content is higher, and sometimes with a certain proportion of heavy metals. Cr, Zn and Pb exceeds the limit allowed to be used in agriculture, this is one of the solutions actually used. In general, major oxides to sludges ranging from: SiO2 (36-48 wt %), Al2O3 (9-16 wt %), CaO (5-25 wt %), P2O5 (1.5-11 wt %) and Fe2O3 (~ 9 wt %), this composition. Since of them are formulated and prepared by four different glasses, in some cases being necessary to incorporate a quantity of raw materials. The sludge combustion heat, the thermal evolution, vitreous transition temperature (Tg) and crystal growth temperature of the glasses were obtained by carrying out a differential thermal analysis. Tg of the four glasses vary between 650 and 725 °C and the growth occurs between 938 and 1033 °C. The vitreous transition temperature was also determined with a dilatometer. Each original glass has been characterized mineralogically by X-ray diffraction: quartz, plagioclase, K-feldspar and calcite. Two samples contained gypsum and some clay mineral traces. We also obtained the viscosity - temperature curves with the aid of the hot stage microscopy that has allowed us to determine the working temperatures of the four glasses, ranging from 926 and to 1419 °C, depending on the type of forming process used. In all glass samples the viscosity-temperature curves have similar characteristics, but for higher viscosities a separation among the different viscosity-temperature curves occurs. This different behaviour is associated to chemical composition: Ca-rich silica aluminum melt, present low viscosity at low temperatures, > P2O5 content, the nucleation of a more refractory phosphate phase occurs. In order to obtain the original glasses working conditions (necessary for possible industrial applications) are used the Vogel-Fulcher-Tammann equation: a) upper and lower annealing temperatures of the samples are similar for the different glasses and ranging between 595-641 °C and 671-701 °C respectively; b) working temperature range from 917-1307 °C for the sample E-02, and 925-1503 °C for the sample E-04, depending on the conformation system used. Finally, the forming and melting temperatures of the samples vary between 1307-1403 °C (E-02) and 1503-1550 °C (E-04). The results confirm that HSM is a good technique for studying the sludge vitrification process, and could provide important information for the possible industrial application. Acknowledgements This study is a contribution of the bilateral project A/030032/10 and CICYT TIN2008-02903. The analytical work was conducted at Research Consolidated Groups 2009SGR-0044 (Mineral Resources). Wastewater treatment plants at El-Sadat City, Alexandria, Abo-Rawash and Minufiya are acknowledged for sampling authorization and facilities. We express our acknowledgement to the technical support of the Scientific-Technical Service Unit of the University of Barcelona and the additional support of the Institute for Bioengineering of Catalonia (IBEC).

Measurement and correlation of jet fuel viscosities at low temperatures

NASA Technical Reports Server (NTRS)

Schruben, D. L.

1985-01-01

Apparatus and procedures were developed to measure jet fuel viscosity for eight current and future jet fuels at temperatures from ambient to near -60 C by shear viscometry. Viscosity data showed good reproducibility even at temperatures a few degrees below the measured freezing point. The viscosity-temperature relationship could be correlated by two linear segments when plotted as a standard log-log type representation (ASTM D 341). At high temperatures, the viscosity-temperature slope is low. At low temperatures, where wax precipitation is significant, the slope is higher. The breakpoint between temperature regions is the filter flow temperature, a fuel characteristic approximated by the freezing point. A generalization of the representation for the eight experimental fuels provided a predictive correlation for low-temperature viscosity, considered sufficiently accurate for many design or performance calculations.

Anatomy of a laminar starting thermal plume at high Prandtl number

NASA Astrophysics Data System (ADS)

Davaille, Anne; Limare, Angela; Touitou, Floriane; Kumagai, Ichiro; Vatteville, Judith

2011-02-01

We present an experimental study of the dynamics of a plume generated from a small heat source in a high Prandtl number fluid with a strongly temperature-dependent viscosity. The velocity field was determined with particle image velocimetry, while the temperature field was measured using differential interferometry and thermochromic liquid crystals. The combination of these different techniques run simultaneously allows us to identify the different stages of plume development, and to compare the positions of key-features of the velocity field (centers of rotation, maximum vorticity locations, stagnation points) respective to the plume thermal anomaly, for Prandtl numbers greater than 103. We further show that the thermal structure of the plume stem is well predicted by the constant viscosity model of Batchelor (Q J R Met Soc 80: 339-358, 1954) for viscosity ratios up to 50.

Radiant energy receiver having improved coolant flow control means

DOEpatents

Hinterberger, H.

1980-10-29

An improved coolant flow control for use in radiant energy receivers of the type having parallel flow paths is disclosed. A coolant performs as a temperature dependent valve means, increasing flow in the warmer flow paths of the receiver, and impeding flow in the cooler paths of the receiver. The coolant has a negative temperature coefficient of viscosity which is high enough such that only an insignificant flow through the receiver is experienced at the minimum operating temperature of the receiver, and such that a maximum flow is experienced at the maximum operating temperature of the receiver. The valving is accomplished by changes in viscosity of the coolant in response to the coolant being heated and cooled. No remotely operated valves, comparators or the like are needed.

Description and comparative study of physico-chemical parameters of the teleost fish skin mucus.

PubMed

Guardiola, Francisco A; Cuartero, María; Del Mar Collado-González, María; Arizcún, Marta; Díaz Baños, F Guillermo; Meseguer, José; Cuesta, Alberto; Esteban, María A

2015-01-01

The study of mucosal surfaces, and in particular the fish skin and its secreted mucus, has been of great interest recently among immunologists. Measurement of the viscosity and other physico-chemical parameters (protein concentration, pH, conductivity, redox potential, osmolality and density) of the skin mucus can help to understand its biological functions. We have used five marine species of teleost: gilthead seabream (Sparus aurata L.), European sea bass (Dicentrarchus labrax L.), shi drum (Umbrina cirrosa L.), common dentex (Dentex dentex L.) and dusky grouper (Epinephelus marginatus L.), all of them with commercial interest in the aquaculture of the Mediterranean area. Mucus showed a direct shear- and temperature-dependent viscosity, with a non-Newtonian behavior, which differed however between two groups: one with higher viscosity (D. labrax, U. cirrosa, D. dentex) and the other with lower viscosity (S. aurata, E. marginatus). In addition, there was a clear interrelation between density and osmolality, as well as between density and temperature. Taking into account that high values of viscosity should improve the barrier effect against pathogens but low values of viscosity are needed for good locomotion characteristics, our results may help elucidate the relationship between physico-chemical and biological parameters of skin mucus, and disease susceptibility.

A similarity solution of time dependent MHD liquid film flow over stretching sheet with variable physical properties

NASA Astrophysics Data System (ADS)

Idrees, M.; Rehman, Sajid; Shah, Rehan Ali; Ullah, M.; Abbas, Tariq

2018-03-01

An analysis is performed for the fluid dynamics incorporating the variation of viscosity and thermal conductivity on an unsteady two-dimensional free surface flow of a viscous incompressible conducting fluid taking into account the effect of a magnetic field. Surface tension quadratically vary with temperature while fluid viscosity and thermal conductivity are assumed to vary as a linear function of temperature. The boundary layer partial differential equations in cartesian coordinates are transformed into a system of nonlinear ordinary differential equations (ODEs) by similarity transformation. The developed nonlinear equations are solved analytically by Homotopy Analysis Method (HAM) while numerically by using the shooting method. The Effects of natural parameters such as the variable viscosity parameter A, variable thermal conductivity parameter N, Hartmann number Ma, film Thickness, unsteadiness parameter S, Thermocapillary number M and Prandtl number Pr on the velocity and temperature profiles are investigated. The results for the surface skin friction coefficient f″ (0) , Nusselt number (heat flux) -θ‧ (0) and free surface temperature θ (1) are presented graphically and in tabular form.

The Role of Viscosity in Causing the Plasma Poloidal Motion in Magnetic Clouds

DOE Office of Scientific and Technical Information (OSTI.GOV)

Zhao, Ake; Wang, Yuming; Liu, Jiajia

An interesting phenomenon, plasma poloidal motion, has been found in many magnetic clouds (MCs), and viscosity has been proposed as a possible mechanism. However, it is not clear how significant the role of viscosity is in generating such motion. In this paper, we conduct a statistical study of the MCs detected by the Wind spacecraft during 1995–2012. It is found that, for 19% of all the studied MCs (186), the poloidal velocities of the MC plasma near the MC boundaries are well correlated with those of the corresponding ambient solar wind plasma. A non-monotonic increase from inner to outer MCsmore » suggests that the viscosity does play a role, albeit weak, on the poloidal motion in the MC statistically. The possible dependence on the solar wind parameters is then studied in detail for the nine selected crossings, which represent the viscosity characteristic. There is an evident negative correlation between the viscosity and the density, a weak negative correlation between the viscosity and the turbulence strength, and no clear correlation between the viscosity and the temperature.« less

Mantle dynamics in super-Earths: Post-perovskite rheology and self-regulation of viscosity

NASA Astrophysics Data System (ADS)

Tackley, P. J.; Ammann, M.; Brodholt, J. P.; Dobson, D. P.; Valencia, D.

2013-07-01

The discovery of extra-solar "super-Earth" planets with sizes up to twice that of Earth has prompted interest in their possible lithosphere and mantle dynamics and evolution. Simple scalings suggest that super-Earths are more likely than an equivalent Earth-sized planet to be undergoing plate tectonics. Generally, viscosity and thermal conductivity increase with pressure while thermal expansivity decreases, resulting in lower convective vigour in the deep mantle, which, if extralopated to the largest super-Earths might, according to conventional thinking, result in no convection in their deep mantles due to the very low effective Rayleigh number. Here we evaluate this. First, as the mantle of a super-Earth is made mostly of post-perovskite we here extend the density functional theory (DFT) calculations of post-perovskite activation enthalpy of to a pressure of 1 TPa, for both slowest diffusion (upper-bound rheology) and fastest diffusion (lower-bound rheology) directions. Along a 1600 K adiabat the upper-bound rheology would lead to a post-perovskite layer of a very high (˜1030 Pa s) but relatively uniform viscosity, whereas the lower-bound rheology leads to a post-perovskite viscosity increase of ˜7 orders of magnitude with depth; in both cases the deep mantle viscosity would be too high for convection. Second, we use these DFT-calculated values in statistically steady-state numerical simulations of mantle convection and lithosphere dynamics of planets with up to ten Earth masses. The models assume a compressible mantle including depth-dependence of material properties and plastic yielding induced plate-like lithospheric behaviour. Results confirm the likelihood of plate tectonics for planets with Earth-like surface conditions (temperature and water) and show a self-regulation of deep mantle temperature. The deep mantle is not adiabatic; instead feedback between internal heating, temperature and viscosity regulates the temperature such that the viscosity has the value needed to facilitate convective loss of the radiogenic heat, which results in a very hot perovskite layer for the upper-bound rheology, a super-adiabatic perovskite layer for the lower-bound rheology, and an azimuthally-averaged viscosity of no more than 1026 Pa s. Convection in large super-Earths is characterised by large upwellings (even with zero basal heating) and small, time-dependent downwellings, which for large super-Earths merge into broad downwellings. In the context of planetary evolution, if, as is likely, a super-Earth was extremely hot/molten after its formation, it is thus likely that even after billions of years its deep interior is still extremely hot and possibly substantially molten with a "super basal magma ocean" - a larger version of the proposal of Labrosse et al. (Labrosse, S., Hernlund, J.W., Coltice, N. [2007]. Nature 450, 866-869), although this depends on presently unknown melt-solid density contrast and solidus.

Estimation of the viscosities of liquid binary alloys

NASA Astrophysics Data System (ADS)

Wu, Min; Su, Xiang-Yu

2018-01-01

As one of the most important physical and chemical properties, viscosity plays a critical role in physics and materials as a key parameter to quantitatively understanding the fluid transport process and reaction kinetics in metallurgical process design. Experimental and theoretical studies on liquid metals are problematic. Today, there are many empirical and semi-empirical models available with which to evaluate the viscosity of liquid metals and alloys. However, the parameter of mixed energy in these models is not easily determined, and most predictive models have been poorly applied. In the present study, a new thermodynamic parameter Δ G is proposed to predict liquid alloy viscosity. The prediction equation depends on basic physical and thermodynamic parameters, namely density, melting temperature, absolute atomic mass, electro-negativity, electron density, molar volume, Pauling radius, and mixing enthalpy. Our results show that the liquid alloy viscosity predicted using the proposed model is closely in line with the experimental values. In addition, if the component radius difference is greater than 0.03 nm at a certain temperature, the atomic size factor has a significant effect on the interaction of the binary liquid metal atoms. The proposed thermodynamic parameter Δ G also facilitates the study of other physical properties of liquid metals.

Microscopic relaxations in a protein sustained down to 160 K in a non-glass forming organic solvent

DOE PAGES

Mamontov, Eugene; O'Neil, Hugh

2016-05-03

In this paper, we have studied microscopic dynamics of a protein in carbon disulfide, a non-glass forming solvent, down to its freezing temperature of ca. 160 K. We have utilized quasielastic neutron scattering. A comparison of lysozyme hydrated with water and dissolved in carbon disulfide reveals a stark difference in the temperature dependence of the protein's microscopic relaxation dynamics induced by the solvent. In the case of hydration water, the common protein glass-forming solvent, the protein relaxation slows down in response to a large increase in the water viscosity on cooling down, exhibiting a well-known protein dynamical transition. The dynamicalmore » transition disappears in non-glass forming carbon disulfide, whose viscosity remains a weak function of temperature all the way down to freezing at just below 160 K. The microscopic relaxation dynamics of lysozyme dissolved in carbon disulfide is sustained down to the freezing temperature of its solvent at a rate similar to that measured at ambient temperature. Finally, our results demonstrate that protein dynamical transition is not merely solvent-assisted, but rather solvent-induced, or, more precisely, is a reflection of the temperature dependence of the solvent's glass-forming dynamics.« less

A comparative study of texture and rheology of Argentinian honeys from two regions.

PubMed

Maldonado, Ezequiel; Navarro, Alba S; Yamul, Diego K

2018-06-23

The rheological and textural properties of 26 eastern Argentinian honeys from two different regions (North and Central) were investigated. The viscosity curves of the samples were obtained using a rotational rheometer over a temperature range of 10 to 50°C. The viscosity decreased with temperature and all honeys showed a Newtonian behaviour. The temperature dependence of viscosity was described using the Arrhenius, Williams- Landel-Ferry, Vogel-Taumman-Fulcher and Power Law models. The glass transition temperatures of honeys were measured with differential scanning calorimetry and values ranged from -42.63 to -47.71°C. The glass transition temperature was also predicted with the Williams- Landel-Ferry model and no significant differences were observed with the experimental results. Rheological parameters were obtained by small amplitude oscillation experiments. Results indicated that the viscous modulus was higher than the storage modulus within all the frequency ranges assayed and honeys from the North region were more viscous. Results of the back extrusion test showed that honeys from the Central region are harder and both groups of honeys (North and Central) exhibited the same consistency and adhesivity. This article is protected by copyright. All rights reserved. This article is protected by copyright. All rights reserved.

Transport properties of nonelectrolyte liquid mixtures—VI. Viscosimetric study of binary mixtures of hexafluorobenzene with aromatic hydrocarbons

NASA Astrophysics Data System (ADS)

Dymond, J. H.; Robertson, J.

1985-01-01

Viscosity coefficients for binary mixtures of hexafluorobenzene with benzene, toluene, para-xylene, and mesitylene have been measured along the saturation line at temperatures from 15 to 120°C using specially designed capillary viscometers. Densities were measured using a pyknometer and volume-change apparatus. Deviations of the viscosities from a rectilinear dependence on mole fraction are consistent with enhanced interactions between unlike species, which increase with increasing number of methyl groups on the aromatic hydrocarbon and decrease with increasing temperature. The application of the Grunberg and Nissan equation, the Hildebrand equation, and energy of activation theories to these results is examined.

Topological Ordering and Viscosity in the Glassy Ge-Se System: The Search for a Structural or Dynamical Signature of the Intermediate Phase

NASA Astrophysics Data System (ADS)

Zeidler, Anita; Salmon, Philip S.; Whittaker, Dean A. J.; Pizzey, Keiron J.; Hannon, Alex C.

2017-11-01

The topological ordering of the network structure in vitreous Ge_xSe_{1-x} was investigated across most of the glass-forming region (0 ≤ x ≤ 0.4) by using high-resolution neutron diffraction to measure the Bhatia-Thornton number-number partial structure factor. This approach gives access to the composition dependence of the mean coordination number \\bar{n} and correlation lengths associated with the network ordering. The thermal properties of the samples were also measured by using temperature-modulated differential scanning calorimetry. The results do not point to a structural origin of the so-called intermediate phase, which in our work is indicated for the composition range 0.175(8) ≤ x ≤ 0.235(8) by a vanishingly-small non-reversing enthalpy near the glass transition. The midpoint of this range coincides with the mean-field expectation of a floppy-to-rigid transition at x = 0.20. The composition dependence of the liquid viscosity, as taken from the literature, was also investigated to look for a dynamical origin of the intermediate phase, using the Mauro-Yue-Ellison-Gupta-Allan (MYEGA) model to estimate the viscosity at the liquidus temperature. The evidence points to a maximum in the viscosity at the liquidus temperature, and a minimum in the fragility index, for the range 0.20 ≤ x ≤ 0.22. The utility of the intermediate phase as a predictor of the material properties in network glass-forming systems is discussed.

Benchmarking FEniCS for mantle convection simulations

NASA Astrophysics Data System (ADS)

Vynnytska, L.; Rognes, M. E.; Clark, S. R.

2013-01-01

This paper evaluates the usability of the FEniCS Project for mantle convection simulations by numerical comparison to three established benchmarks. The benchmark problems all concern convection processes in an incompressible fluid induced by temperature or composition variations, and cover three cases: (i) steady-state convection with depth- and temperature-dependent viscosity, (ii) time-dependent convection with constant viscosity and internal heating, and (iii) a Rayleigh-Taylor instability. These problems are modeled by the Stokes equations for the fluid and advection-diffusion equations for the temperature and composition. The FEniCS Project provides a novel platform for the automated solution of differential equations by finite element methods. In particular, it offers a significant flexibility with regard to modeling and numerical discretization choices; we have here used a discontinuous Galerkin method for the numerical solution of the advection-diffusion equations. Our numerical results are in agreement with the benchmarks, and demonstrate the applicability of both the discontinuous Galerkin method and FEniCS for such applications.

Role of hydrodynamic viscosity on phonon transport in suspended graphene

NASA Astrophysics Data System (ADS)

Li, Xun; Lee, Sangyeop

2018-03-01

When phonon transport is in the hydrodynamic regime, the thermal conductivity exhibits peculiar dependences on temperatures (T ) and sample widths (W ). These features were used in the past to experimentally confirm the hydrodynamic phonon transport in three-dimensional bulk materials. Suspended graphene was recently predicted to exhibit strong hydrodynamic features in thermal transport at much higher temperature than the three-dimensional bulk materials, but its experimental confirmation requires quantitative guidance by theory and simulation. Here we quantitatively predict those peculiar dependences using the Monte Carlo solution of the Peierls-Boltzmann equation with an ab initio full three-phonon scattering matrix. Thermal conductivity is found to increase as Tα where α ranges from 1.89 to 2.49 depending on a sample width at low temperatures, much larger than 1.68 of the ballistic case. The thermal conductivity has a width dependence of W1.17 at 100 K, clearly distinguished from the sublinear dependence of the ballistic-diffusive regime. These peculiar features are explained with a phonon viscous damping effect of the hydrodynamic regime. We derive an expression for the phonon hydrodynamic viscosity from the Peierls-Boltzmann equation, and discuss the fact that the phonon viscous damping explains well those peculiar dependences of thermal conductivity at 100 K. The phonon viscous damping still causes significant thermal resistance when a temperature is 300 K and a sample width is around 1 µm, even though the hydrodynamic regime is not dominant over other regimes at this condition.

Viscous flow behavior of tholeiitic and alkaline Fe-rich martian basalts

NASA Astrophysics Data System (ADS)

Chevrel, Magdalena Oryaëlle; Baratoux, David; Hess, Kai-Uwe; Dingwell, Donald B.

2014-01-01

The chemical compositions of martian basalts are enriched in iron with respect to terrestrial basalts. Their rheology is poorly known and liquids of this chemical composition have not been experimentally investigated. Here, we determine the viscosity of five synthetic silicate liquids having compositions representative of the diversity of martian volcanic rocks including primary martian mantle melts and alkali basalts. The concentric cylinder method has been employed between 1500 °C and the respective liquidus temperatures of these liquids. The viscosity near the glass transition has been derived from calorimetric measurements of the glass transition. Although some glass heterogeneity limits the accuracy of the data near the glass transition, it was nevertheless possible to determine the parameters of the non-Arrhenian temperature-dependence of viscosity over a wide temperature range (1500 °C to the glass transition temperature). At superliquidus conditions, the martian basalt viscosities are as low as those of the Fe-Ti-rich lunar basalts, similar to the lowest viscosities recorded for terrestrial ferrobasalts, and 0.5 to 1 order of magnitude lower than terrestrial tholeiitic basalts. Comparison with empirical models reveals that Giordano et al. (2008) offers the best approximation, whereas the model proposed by Hui and Zhang (2007) is inappropriate for the compositions considered. The slightly lower viscosities exhibited by the melts produced by low degree of mantle partial melting versus melts produced at high degree of mantle partial melting (likely corresponding to the early history of Mars), is not deemed sufficient to lead to viscosity variations large enough to produce an overall shift of martian lava flow morphologies over time. Rather, the details of the crystallization sequence (and in particular the ability of some of these magmas to form spinifex texture) is proposed to be a dominant effect on the viscosity during martian lava flow emplacement and may explain the lower range of viscosities (102-104 Pa s) inferred from lava flow morphology. Further, the differences between the rheological behaviors of tholeiitic vs. trachy-basalts are significant enough to affect their emplacement as intrusive bodies or as effusive lava flows. The upper range of viscosities (106-108 Pa s) suggested from lava flow morphology is found consistent with the occurrence of alkali basalt documented from in situ analyses and does not necessarily imply the occurrence of basaltic-andesite or andesitic rocks.

Nanostructures study of CNT nanofluids transport with temperature-dependent variable viscosity in a muscular tube

NASA Astrophysics Data System (ADS)

Akbar, Noreen Sher; Abid, Syed Ali; Tripathi, Dharmendra; Mir, Nazir Ahmed

2017-03-01

The transport of single-wall carbon nanotube (CNT) nanofluids with temperature-dependent variable viscosity is analyzed by peristaltically driven flow. The main flow problem has been modeled using cylindrical coordinates and flow equations are simplified to ordinary differential equations using long wavelength and low Reynolds' number approximation. Analytical solutions have been obtained for axial velocity, pressure gradient and temperature. Results acquired are discussed graphically for better understanding. It is observed that with an increment in the Grashof number the velocity of the governing fluids starts to decrease significantly and the pressure gradient is higher for pure water as compared to single-walled carbon nanotubes due to low density. As the specific heat is very high for pure water as compared to the multi-wall carbon nanotubes, it raises temperature of the muscles, in the case of pure water, as compared to the multi-walled carbon nanotubes. Furthermore, it is noticed that the trapped bolus starts decreasing in size as the buoyancy forces are dominant as compared to viscous forces. This model may be applicable in biomedical engineering and nanotechnology to design the biomedical devices.

Refractive index and solubility control of para-cymene solutions for index-matched fluid-structure interaction studies

NASA Astrophysics Data System (ADS)

Fort, Charles; Fu, Christopher D.; Weichselbaum, Noah A.; Bardet, Philippe M.

2015-12-01

To deploy optical diagnostics such as particle image velocimetry or planar laser-induced fluorescence (PLIF) in complex geometries, it is beneficial to use index-matched facilities. A binary mixture of para-cymene and cinnamaldehyde provides a viable option for matching the refractive index of acrylic, a common material for scaled models and test sections. This fluid is particularly appropriate for large-scale facilities and when a low-density and low-viscosity fluid is sought, such as in fluid-structure interaction studies. This binary solution has relatively low kinematic viscosity and density; its use enables the experimentalist to select operating temperature and to increase fluorescence signal in PLIF experiments. Measurements of spectral and temperature dependence of refractive index, density, and kinematic viscosity are reported. The effect of the binary mixture on solubility control of Rhodamine 6G is also characterized.

DWPF STARTUP FRIT VISCOSITY MEASUREMENT ROUND ROBIN RESULTS

DOE Office of Scientific and Technical Information (OSTI.GOV)

Crum, Jarrod V.; Edwards, Tommy B.; Russell, Renee L.

2012-07-31

A viscosity standard is needed to replace the National Institute of Standards and Technology (NIST) glasses currently being used to calibrate viscosity measurement equipment. The current NIST glasses are either unavailable or less than ideal for calibrating equipment to measure the viscosity of high-level waste glasses. This report documents the results of a viscosity round robin study conducted on the Defense Waste Processing Facility (DWPF) startup frit. DWPF startup frit was selected because its viscosity-temperature relationship is similar to most DWPF and Hanford high-level waste glass compositions. The glass underwent grinding and blending to homogenize the large (100 lb) batch.more » Portions of the batch were supplied to the laboratories (named A through H) for viscosity measurements following a specified temperature schedule with a temperature range of 1150 C to 950 C and with an option to measure viscosity at lower temperatures if their equipment was capable of measuring at the higher viscosities. Results were used to fit the Vogel-Tamman-Fulcher and Arrhenius equations to viscosity as a function of temperature for the entire temperature range of 460 C through 1250 C as well as the limited temperature interval of approximately 950 C through 1250 C. The standard errors for confidence and prediction were determined for the fitted models.« less

Thermophysical properties of liquid Ni around the melting temperature from molecular dynamics simulation

DOE Office of Scientific and Technical Information (OSTI.GOV)

Rozas, R. E.; Department of Physics, University of Bío-Bío, Av. Collao 1202, P.O. Box 5C, Concepción; Demiraǧ, A. D.

Thermophysical properties of liquid nickel (Ni) around the melting temperature are investigated by means of classical molecular dynamics (MD) simulation, using three different embedded atom method potentials to model the interactions between the Ni atoms. Melting temperature, enthalpy, static structure factor, self-diffusion coefficient, shear viscosity, and thermal diffusivity are compared to recent experimental results. Using ab initio MD simulation, we also determine the static structure factor and the mean-squared displacement at the experimental melting point. For most of the properties, excellent agreement is found between experiment and simulation, provided the comparison relative to the corresponding melting temperature. We discuss themore » validity of the Hansen-Verlet criterion for the static structure factor as well as the Stokes-Einstein relation between self-diffusion coefficient and shear viscosity. The thermal diffusivity is extracted from the autocorrelation function of a wavenumber-dependent temperature fluctuation variable.« less

Nonlinear radiative peristaltic flow of hydromagnetic fluid through porous medium

NASA Astrophysics Data System (ADS)

Hussain, Q.; Latif, T.; Alvi, N.; Asghar, S.

2018-06-01

The radiative heat and mass transfer in wall induced flow of hydromagnetic fluid through porous medium in an asymmetric channel is analyzed. The fluid viscosity is considered temperature dependent. In the theory of peristalsis, the radiation effects are either ignored or taken as linear approximation of radiative heat flux. Such approximation is only possible when there is sufficiently small temperature differences in the flow field; however, nonlinear radiation effects are valid for large temperature differences as well (the new feature added in the present study). Mathematical modeling of the problems include the complicated system of highly nonlinear differential equations. Semi-analytical solutions are established in the wave reference frame. Results are displayed graphically and discussed in detail for the variation of various physical parameters with the special attention to viscosity, radiation, and temperature ratio parameters.

REVIEWS OF TOPICAL PROBLEMS: Universal viscosity growth in metallic melts at megabar pressures: the vitreous state of the Earth's inner core

NASA Astrophysics Data System (ADS)

Brazhkin, Vadim V.; Lyapin, A. G.

2000-05-01

Experimental data on and theoretical models for the viscosity of various types of liquids and melts under pressure are reviewed. Experimentally, the least studied melts are those of metals, whose viscosity is considered to be virtually constant along the melting curve. The authors' new approach to the viscosity of melts involves the measurement of the grain size in solidified samples. Measurements on liquid metals at pressures up to 10 GPa using this method show, contrary to the empirical approach, that the melt viscosity grows considerably along the melting curves. Based on the experimental data and on the critical analysis of current theories, a hypothesis of a universal viscosity behavior is introduced for liquids under pressure. Extrapolating the liquid iron results to the pressures and temperatures at the Earth's core reveals that the Earth's outer core is a very viscous melt with viscosity values ranging from 102 Pa s to 1011 Pa s depending on the depth. The Earth's inner core is presumably an ultraviscous (>1011 Pa s) glass-like liquid — in disagreement with the current idea of a crystalline inner core. The notion of the highly viscous interior of celestial bodies sheds light on many mysteries of planetary geophysics and astronomy. From the analysis of the pressure variation of the melting and glass-transition temperatures, an entirely new concept of a stable metallic vitreous state arises, calling for further experimental and theoretical study.

Monitoring processing properties of high performance thermoplastics using frequency dependent electromagnetic sensing

NASA Technical Reports Server (NTRS)

Kranbuehl, D. E.; Delos, S. E.; Hoff, M. S.; Weller, L. W.; Haverty, P. D.

1987-01-01

An in situ NDE dielectric impedance measurement method has been developed for ascertaining the cure processing properties of high temperature advanced thermoplastic and thermosetting resins, using continuous frequency-dependent measurements and analyses of complex permittivity over 9 orders of magnitude and 6 decades of frequency at temperatures up to 400 C. Both ionic and Debye-like dipolar relaxation processes are monitored. Attention is given to LARC-TPI, PEEK, and poly(arylene ether) resins' viscosity, glass transition temperature, recrystallization, and residual solvent content and evolution properties.

Optical and Transport Properties of Energetic Materials

NASA Astrophysics Data System (ADS)

Choi, Chang Sun

1990-01-01

The densities of Hydroxyl ammonium nitrate (HAN) based fast reacting liquids were measured as a function of pressure (up to 4.83 kbars) at several temperatures and the results of density measurements were fit to the Tait equation. Also the shear viscosities of this liquid were measured as a function of both pressure and temperature. The free volume model was applied to explain behavior of the shear viscosity with the assumption that only the reference temperature (T_0) in the Fulcher (1925), WLF (Williams, Landel, and Ferry) and Angell equations depends on pressure. The general relation to predict viscosity of this liquid at any temperature and pressure was derived and the difference between expected and measured values are about 5%. The phase diagrams of the HAN solution, Triethanol ammonium nitrate (TEAN) solution and LP-1845 were obtained through Differential Scanning Calorimetry (DSC) measurements. The TEAN solution has a eutectic temperature in the vicinity of 260^circK. The measured phase diagrams are in good agreement with the calculated phase diagrams. The TEAN solutions show a large supercooling effect. Some phase separation was observed in the TEAN solutions and this separation was believed to be due to eutectic composition of the TEAN solution. The expected freezing temperature of LP-1845 was almost the same with the calculated T_0 from the viscosity data. Raman spectra from the HAN solution, TEAN solution and LP-1845 were measured. Every peak in the spectra was assigned. These solutions show various interactions, such as ion-ion pairing and ion-water interaction. The strongest peak was a NO_3^- symmetric stretch mode at 1050 cm^{-1}. The time correlation functions were calculated from the Raman spectra of the 1050 cm^{-1} peak. The correlation time, which can be calculated from the linewidth, become shorter with decreasing temperatures and with increasing concentrations. The Kubo's stochastic theory explains the correlation functions very well if the solution is relatively dilute. The pressure dependence of the reaction rate was estimated by using the density data and Raman peak shift data.

Shock wave structure in rarefied polyatomic gases with large relaxation time for the dynamic pressure

NASA Astrophysics Data System (ADS)

Taniguchi, Shigeru; Arima, Takashi; Ruggeri, Tommaso; Sugiyama, Masaru

2018-05-01

The shock wave structure in rarefied polyatomic gases is analyzed based on extended thermodynamics (ET). In particular, the case with large relaxation time for the dynamic pressure, which corresponds to large bulk viscosity, is considered by adopting the simplest version of extended thermodynamics with only 6 independent fields (ET6); the mass density, the velocity, the temperature and the dynamic pressure. Recently, the validity of the theoretical predictions by ET was confirmed by the numerical analysis based on the kinetic theory in [S Kosuge and K Aoki: Phys. Rev. Fluids, Vol. 3, 023401 (2018)]. It was shown that numerical results using the polyatomic version of ellipsoidal statistical model agree with the theoretical predictions by ET for small or moderately large Mach numbers. In the present paper, first, we compare the theoretical predictions by ET6 with the ones by kinetic theory for large Mach number under the same assumptions, that is, the gas is polytropic and the bulk viscosity is proportional to the temperature. Second, the shock wave structure for large Mach number in a non-polytropic gas is analyzed with the particular interest in the effect of the temperature dependence of specific heat and the bulk viscosity on the shock wave structure. Through the analysis of the case of a rarefied carbon dioxide (CO2) gas, it is shown that these temperature dependences play important roles in the precise analysis of the structure for strong shock waves.

Temperature-viscosity relationships of selected asphalt cements.

DOT National Transportation Integrated Search

1970-06-01

To gain information on the appropriate temperature to obtain a given desirable viscosity for the various asphalt cements commonly used in Oregon, viscosities were determined at three or more temperatures near the mixing temperature. From the values d...

Sheet-like and plume-like thermal flow in a spherical convection experiment performed under microgravity

NASA Astrophysics Data System (ADS)

Breuer, D.; Futterer, B.; Plesa, A.; Krebs, A.; Zaussinger, F.; Egbers, C.

2013-12-01

In mantle dynamics research, experiments, usually performed in rectangular geometries in Earth-based laboratories, have the character of ';exploring new physics and testing theories' [1]. In this work, we introduce our spherical geometry experiments on electro-hydrodynamical driven Rayleigh-Benard convection that have been performed for both temperature-independent (`GeoFlow I'), and temperature-dependent fluid viscosity properties (`GeoFlow II') with a measured viscosity contrast up to 1.5. To set up a self-gravitating force field, we use a high voltage potential between the inner and outer boundaries and a dielectric insulating liquid and perform the experiment under microgravity conditions at the ISS [2, 3]. Further, numerical simulations in 3D spherical geometry have been used to reproduce the results obtained in the `GeoFlow' experiments. For flow visualisation, we use Wollaston prism shearing interferometry which is an optical method producing fringe pattern images. Flow pattern differ between our two experiments (Fig. 1). In `GeoFlow I', we see a sheet-like thermal flow. In this case convection patterns have been successfully reproduced by 3D numerical simulations using two different and independently developed codes. In contrast, in `GeoFlow II' we obtain plume-like structures. Interestingly, numerical simulations do not yield this type of solution for the low viscosity contrast realised in the experiment. However, using a viscosity contrast of two orders of magnitude or higher, we can reproduce the patterns obtained in the `GeoFlow II' experiment, from which we conclude that non-linear effects shift the effective viscosity ratio [4]. References [1] A. Davaille and A. Limare (2009). In: Schubert, G., Bercovici, D. (Eds.), Treatise on Geophysics - Mantle Dynamics. [2] B. Futterer, C. Egbers, N. Dahley, S. Koch, L. Jehring (2010). Acta Astronautica 66, 193-100. [3] B. Futterer, N. Dahley, S. Koch, N. Scurtu, C. Egbers (2012). Acta Astronautica 71, 11-19. [4] B. Futterer, A. Krebs, A.-C. Plesa, F. Zaussinger, D.Breuer, C. Egbers (2013). submitted to Journal of Fluid Mechanics. Fig. 1: a) Sheet-like thermal flow in the GeoFlow I spherical experiment with silicone oil of temperature-stable properties (RaE=1.17e6); b) Plume-like dominated flow in the GeoFlow II experiment using a fluid with temperature dependent viscosity and volume expansion (RaE=1.87e6).

An Arrhenius-type viscosity function to model sintering using the Skorohod Olevsky viscous sintering model within a finite element code.

DOE Office of Scientific and Technical Information (OSTI.GOV)

Ewsuk, Kevin Gregory; Arguello, Jose Guadalupe, Jr.; Reiterer, Markus W.

2006-02-01

The ease and ability to predict sintering shrinkage and densification with the Skorohod-Olevsky viscous sintering (SOVS) model within a finite-element (FE) code have been improved with the use of an Arrhenius-type viscosity function. The need for a better viscosity function was identified by evaluating SOVS model predictions made using a previously published polynomial viscosity function. Predictions made using the original, polynomial viscosity function do not accurately reflect experimentally observed sintering behavior. To more easily and better predict sintering behavior using FE simulations, a thermally activated viscosity function based on creep theory was used with the SOVS model. In comparison withmore » the polynomial viscosity function, SOVS model predictions made using the Arrhenius-type viscosity function are more representative of experimentally observed viscosity and sintering behavior. Additionally, the effects of changes in heating rate on densification can easily be predicted with the Arrhenius-type viscosity function. Another attribute of the Arrhenius-type viscosity function is that it provides the potential to link different sintering models. For example, the apparent activation energy, Q, for densification used in the construction of the master sintering curve for a low-temperature cofire ceramic dielectric has been used as the apparent activation energy for material flow in the Arrhenius-type viscosity function to predict heating rate-dependent sintering behavior using the SOVS model.« less

Semiclassical law for the apparent viscosity of non-Newtonian fluids: An analogy between thixotropy of fluids and sintering of solids

NASA Astrophysics Data System (ADS)

Mezzasalma, Stefano A.

2000-08-01

A theory is presented to describe the apparent viscosity of thixotropic fluids as a function of the rate of shear. It represents the extension of a semiclassical approach that was previously formulated to deal with matter densification phenomena in solids starting from the state equation of the medium. In this context, the Debye expression for the Helmholtz free energy has been provided with a density of vibrational modes that accounts for atomic and microstructural changes occurring at the frequency scale of momentum transport (see diffusion). Working out the steady-state condition with respect to time gives an equation relating reduced apparent viscosity (η˜) and shear rate (γ˜) through the temperature value (θ*) that is energetically equivalent to the medium vibrations implied. Viscosity also turns out to depend on the Debye temperature θD (see φ˜θ*/θD) and an equivalent Gruneisen parameter (μ), defined with respect to viscosity variations. Increasing φ in pseudoplastic and dilatant media, respectively, increases and decreases η˜, which always increases with increasing μ. The analogy between dilatancy/sintering and pseudoplasticity/desintering is suggested, and a correspondence between matter and momentum transports is traced on the basis of the phononic spectrum properties. Application to experimental measurements are presented and discussed for aqueous monodispersions of polystyrene (PS) latex particles, aqueous glycerol solutions of partially hydrolyzed polyacrylamide (PHPAA) at different sodium chloride (NaCl) concentrations, polymethylmethacrylate (PMMA) suspensions in dioctylphthalate (DOP), and for a molecularly thin liquid film of octamethylciclotetrasiloxane (OMCTS). Best fit coefficients for φ and μ have been constrained to the Debye temperature and the effective low-shear viscosity (η0) according to their dependences upon the suspended volume fraction (φ), θD=θD(φ), and η0=η0(φ), and the agreement with experimental data is quite satisfactory in all cases here examined. It is then suggested that the viscous character of a liquid can be described in terms of a coupling between Brownian diffusion and phonon wave motion.

Activation energy and entropy for viscosity of wormlike micelle solutions.

PubMed

Chandler, H D

2013-11-01

The viscosities of two surfactant solutions which form wormlike micelles (WLMs) were studied over a range of temperatures and strain rates. WLM solutions appear to differ from many other shear thinning systems in that, as the shear rate increases, stress-shear rate curves tend to converge with temperature rather than diverge and this can sometimes lead to higher temperature curves crossing those at lower. Behaviour was analysed in terms of activation kinetics. It is suggested that two mechanisms are involved: Newtonian flow, following an Arrhenius law superimposed on a non-Newtonian flow described by a stress assisted kinetic law, this being a more general form of the Arrhenius law. Anomalous flow is introduced into the kinetic equation via a stress dependent activation entropy term. Copyright © 2013 Elsevier Inc. All rights reserved.

Numerical solution of problems concerning the thermal convection of a variable-viscosity liquid

NASA Astrophysics Data System (ADS)

Zherebiatev, I. F.; Lukianov, A. T.; Podkopaev, Iu. L.

A stabilizing-correction scheme is constructed for integrating the fourth-order equation describing the dynamics of a viscous incompressible liquid. As an example, a solution is obtained to the problem of the solidification of a liquid in a rectangular region with allowance for convective energy transfer in the liquid phase as well as temperature-dependent changes of viscosity. It is noted that the proposed method can be used to study steady-state problems of thermal convection in ingots obtained through continuous casting.

Effect of Structure on Transport Properties (Viscosity, Ionic Conductivity, and Self-Diffusion Coefficient) of Aprotic Heterocyclic Anion (AHA) Room-Temperature Ionic Liquids. 1. Variation of Anionic Species.

PubMed

Sun, Liyuan; Morales-Collazo, Oscar; Xia, Han; Brennecke, Joan F

2015-12-03

A series of room temperature ionic liquids (RTILs) based on 1-ethyl-3-methylimidazolium ([emim](+)) with different aprotic heterocyclic anions (AHAs) were synthesized and characterized as potential electrolyte candidates for lithium ion batteries. The density and transport properties of these ILs were measured over the temperature range between 283.15 and 343.15 K at ambient pressure. The temperature dependence of the transport properties (viscosity, ionic conductivity, self-diffusion coefficient, and molar conductivity) is fit well by the Vogel-Fulcher-Tamman (VFT) equation. The best-fit VFT parameters, as well as linear fits to the density, are reported. The ionicity of these ILs was quantified by the ratio of the molar conductivity obtained from the ionic conductivity and molar concentration to that calculated from the self-diffusion coefficients using the Nernst-Einstein equation. The results of this study, which is based on ILs composed of both a planar cation and planar anions, show that many of the [emim][AHA] ILs exhibit very good conductivity for their viscosities and provide insight into the design of ILs with enhanced dynamics that may be suitable for electrolyte applications.

Symmetric flows for compressible heat-conducting fluids with temperature dependent viscosity coefficients

NASA Astrophysics Data System (ADS)

Wan, Ling; Wang, Tao

2017-06-01

We consider the Navier-Stokes equations for compressible heat-conducting ideal polytropic gases in a bounded annular domain when the viscosity and thermal conductivity coefficients are general smooth functions of temperature. A global-in-time, spherically or cylindrically symmetric, classical solution to the initial boundary value problem is shown to exist uniquely and converge exponentially to the constant state as the time tends to infinity under certain assumptions on the initial data and the adiabatic exponent γ. The initial data can be large if γ is sufficiently close to 1. These results are of Nishida-Smoller type and extend the work (Liu et al. (2014) [16]) restricted to the one-dimensional flows.

Insitu measurement and control of processing properties of composite resins in a production tool

NASA Technical Reports Server (NTRS)

Kranbuehl, D.; Hoff, M.; Haverty, P.; Loos, A.; Freeman, T.

1988-01-01

An in situ measuring technique for use in automated composite processing and quality control is discussed. Frequency dependent electromagnetic sensors are used to measure processing parameters at four ply positions inside a thick section 192-ply graphite-epoxy composite during cure in an 8 x 4 in. autoclave. Viscosity measurements obtained using the sensors are compared with the viscosities calculated using the Loos-Springer cure process model. Good overall agreement is obtained. In a subsequent autoclave run, the output from the four sensors was used to control the autoclave temperature. Using the 'closed loop' sensor controlled autoclave temperature resulted in a more uniform and more rapid cure cycle.

Transport properties of nonelectrolyte liquid mixtures—V. Viscosity coefficients for binary mixtures of benzene plus alkanes at saturation pressure from 283 to 393 K

NASA Astrophysics Data System (ADS)

Dymond, J. H.; Young, K. J.

1981-09-01

Viscosity coefficient measurements at saturation pressure are reported for benzene + n-hexane, benzene + n-octane, benzene + n-decane, benzene + n-dodecane, benzene + n-hexadecane, and benzene + cyclohexane at temperatures from 283 to 393 K. The characteristic parameter G in the Grunberg and Nissan equation 10765_2004_Article_BF00504187_TeX2GIFE1.gif ell nη = x_1 ell nη _1 + x_2 ell nη _2 + x_1 x_2 G is found to be both composition and temperature dependent for benzene + n-alkane mixtures, but it is independent of composition for the system benzene + cyclohexane.

Solution properties and taste behavior of lactose monohydrate in aqueous ascorbic acid solutions at different temperatures: Volumetric and rheological approach.

PubMed

Sarkar, Abhijit; Sinha, Biswajit

2016-11-15

The densities and viscosities of lactose monohydrate in aqueous ascorbic acid solutions with several molal concentrations m=(0.00-0.08)molkg(-1) of ascorbic acid were determined at T=(298.15-318.15)K and pressure p=101kPa. Using experimental data apparent molar volume (ϕV), standard partial molar volume (ϕV(0)), the slope (SV(∗)), apparent specific volumes (ϕVsp), standard isobaric partial molar expansibility (ϕE(0)) and its temperature dependence [Formula: see text] the viscosity B-coefficient and solvation number (Sn) were determined. Viscosity B-coefficients were further employed to obtain the free energies of activation of viscous flow per mole of the solvents (Δμ1(0≠)) and of the solute (Δμ2(0≠)). Effects of molality, solute structure and temperature and taste behavior were analyzed in terms of solute-solute and solute-solvent interactions; results revealed that the solutions are characterized predominantly by solute-solvent interactions and lactose monohydrate behaves as a long-range structure maker. Copyright © 2016 Elsevier Ltd. All rights reserved.

Application of SH surface acoustic waves for measuring the viscosity of liquids in function of pressure and temperature.

PubMed

Kiełczyński, P; Szalewski, M; Balcerzak, A; Rostocki, A J; Tefelski, D B

2011-12-01

Viscosity measurements were carried out on triolein at pressures from atmospheric up to 650 MPa and in the temperature range from 10°C to 40°C using ultrasonic measuring setup. Bleustein-Gulyaev SH surface acoustic waves waveguides were used as viscosity sensors. Additionally, pressure changes occurring during phase transition have been measured over the same temperature range. Application of ultrasonic SH surface acoustic waves in the liquid viscosity measurements at high pressure has many advantages. It enables viscosity measurement during phase transitions and in the high-pressure range where the classical viscosity measurement methods cannot operate. Measurements of phase transition kinetics and viscosity of liquids at high pressures and various temperatures (isotherms) is a novelty. The knowledge of changes in viscosity in function of pressure and temperature can help to obtain a deeper insight into thermodynamic properties of liquids. Copyright © 2011 Elsevier B.V. All rights reserved.

Glass viscosity calculation based on a global statistical modelling approach

DOE Office of Scientific and Technical Information (OSTI.GOV)

Fluegel, Alex

2007-02-01

A global statistical glass viscosity model was developed for predicting the complete viscosity curve, based on more than 2200 composition-property data of silicate glasses from the scientific literature, including soda-lime-silica container and float glasses, TV panel glasses, borosilicate fiber wool and E type glasses, low expansion borosilicate glasses, glasses for nuclear waste vitrification, lead crystal glasses, binary alkali silicates, and various further compositions from over half a century. It is shown that within a measurement series from a specific laboratory the reported viscosity values are often over-estimated at higher temperatures due to alkali and boron oxide evaporation during the measurementmore » and glass preparation, including data by Lakatos et al. (1972) and the recently published High temperature glass melt property database for process modeling by Seward et al. (2005). Similarly, in the glass transition range many experimental data of borosilicate glasses are reported too high due to phase separation effects. The developed global model corrects those errors. The model standard error was 9-17°C, with R^2 = 0.985-0.989. The prediction 95% confidence interval for glass in mass production largely depends on the glass composition of interest, the composition uncertainty, and the viscosity level. New insights in the mixed-alkali effect are provided.« less

Temperature dependent droplet impact dynamics on flat and textured surfaces

DOE Office of Scientific and Technical Information (OSTI.GOV)

Azar Alizadeh; Vaibhav Bahadur; Sheng Zhong

Droplet impact dynamics determines the performance of surfaces used in many applications such as anti-icing, condensation, boiling and heat transfer. We study impact dynamics of water droplets on surfaces with chemistry/texture ranging from hydrophilic to superhydrophobic and across a temperature range spanning below freezing to near boiling conditions. Droplet retraction shows very strong temperature dependence especially for hydrophilic surfaces; it is seen that lower substrate temperatures lead to lesser retraction. Physics-based analyses show that the increased viscosity associated with lower temperatures can explain the decreased retraction. The present findings serve to guide further studies of dynamic fluid-structure interaction at variousmore » temperatures.« less

DOE Office of Scientific and Technical Information (OSTI.GOV)

Khvorostukhin, A. S.; Joint Institute for Nuclear Research, 141980 Dubna; Institute of Applied Physics, Moldova Academy of Science, MD-2028 Kishineu

Shear {eta} and bulk {zeta} viscosities are calculated in a quasiparticle model within a relaxation-time approximation for pure gluon matter. Below T{sub c}, the confined sector is described within a quasiparticle glueball model. The constructed equation of state reproduces the first-order phase transition for the glue matter. It is shown that with this equation of state, it is possible to describe the temperature dependence of the shear viscosity to entropy ratio {eta}/s and the bulk viscosity to entropy ratio {zeta}/s in reasonable agreement with available lattice data, but absolute values of the {zeta}/s ratio underestimate the upper limits of thismore » ratio in the lattice measurements typically by an order of magnitude.« less

Resolving Discrepancies Between Observed and Predicted Dynamic Topography on Earth

NASA Astrophysics Data System (ADS)

Richards, F. D.; Hoggard, M.; White, N. J.

2017-12-01

Compilations of well-resolved oceanic residual depth measurements suggest that present-day dynamic topography differs from that predicted by geodynamic simulations in two significant respects. At short wavelengths (λ ≤ 5,000 km), much larger amplitude variations are observed, whereas at long wavelengths (λ > 5,000 km), observed dynamic topography is substantially smaller. Explaining the cause of this discrepancy with a view to reconciling these different approaches is central to constraining the structure and dynamics of the deep Earth. Here, we first convert shear wave velocity to temperature using an experimentally-derived anelasticity model. This relationship is calibrated using a pressure and temperature-dependent plate model that satisfies age-depth subsidence, heat flow measurements, and seismological constraints on the depth to the lithosphere-asthenosphere boundary. In this way, we show that, at short-wavelengths, observed dynamic topography is consistent with ±150 ºC asthenospheric temperature anomalies. These inferred thermal buoyancy variations are independently verified by temperature measurements derived from geochemical analyses of mid-ocean ridge basalts. Viscosity profiles derived from the anelasticity model suggest that the asthenosphere has an average viscosity that is two orders of magnitude lower than that of the underlying upper mantle. The base of this low-viscosity layer coincides with a peak in azimuthal anisotropy observed in recent seismic experiments. This agreement implies that lateral asthenospheric flow is rapid with respect to the underlying upper mantle. We conclude that improved density and viscosity models of the uppermost mantle, which combine a more comprehensive physical description of the lithosphere-asthenosphere system with recent seismic tomographic models, can help to resolve spectral discrepancies between observed and predicted dynamic topography. Finally, we explore possible solutions to the long-wavelength discrepancy that exploit the velocity to density conversion described above combined with radial variation of mantle viscosity.

Constraints on the properties of Pluto's nitrogen-ice rich layer from convection simulations

NASA Astrophysics Data System (ADS)

Wong, T.; McKinnon, W. B.; Schenk, P.

2016-12-01

Pluto's Sputnik Planum basin (informally named) displays regular cellular patterns strongly suggesting that solid-state convection is occurring in a several-kilometers-deep nitrogen-ice rich layer (McKinnon et al., Convection in a volatile nitrogen-ice-rich layer drives Pluto's geological vigour, Nature 534, 82-85, 2016). We investigate the behavior of thermal convection in 2-D that covers a range of parameters applicable to the nitrogen ice layer to constrain its properties such that these long-wavelength surface features can be explained. We perform a suite of numerical simulations of convection with basal heating and temperature-dependent viscosity in either exponential form or Arrhenius form. For a plausible range of Rayleigh numbers and viscosity contrasts for solid nitrogen, convection can occur in all possible regimes: sluggish lid, transitional, or stagnant lid, or the layer could be purely conducting. We suggest the range of depth and temperature difference across the layer for convection to occur. We observe that the plume dynamics can be widely different in terms of the aspect ratio of convecting cells, or the width and spacing of plumes, and also in the lateral movement of plumes. These differences depend on the regime of convection determined by the Rayleigh number and the actual viscosity contrast across the layer, but is not sensitive to whether the viscosity is in Arrhenius or exponential form. The variations in plume dynamics result in different types of dynamic topography, which can be compared with the observed horizontal and vertical scales of the cells in Sputnik Planum. Based on these simulations we suggest several different possibilities for the formation and evolution of Sputnik Planum, which may be a consequence of the time-dependent behavior of thermal convection.

Thermal History and Mantle Dynamics of Venus

NASA Technical Reports Server (NTRS)

Hsui, Albert T.

1997-01-01

One objective of this research proposal is to develop a 3-D thermal history model for Venus. The basis of our study is a finite-element computer model to simulate thermal convection of fluids with highly temperature- and pressure-dependent viscosities in a three-dimensional spherical shell. A three-dimensional model for thermal history studies is necessary for the following reasons. To study planetary thermal evolution, one needs to consider global heat budgets of a planet throughout its evolution history. Hence, three-dimensional models are necessary. This is in contrasts to studies of some local phenomena or local structures where models of lower dimensions may be sufficient. There are different approaches to treat three-dimensional thermal convection problems. Each approach has its own advantages and disadvantages. Therefore, the choice of the various approaches is subjective and dependent on the problem addressed. In our case, we are interested in the effects of viscosities that are highly temperature dependent and that their magnitudes within the computing domain can vary over many orders of magnitude. In order to resolve the rapid change of viscosities, small grid spacings are often necessary. To optimize the amount of computing, variable grids become desirable. Thus, the finite-element numerical approach is chosen for its ability to place grid elements of different sizes over the complete computational domain. For this research proposal, we did not start from scratch and develop the finite element codes from the beginning. Instead, we adopted a finite-element model developed by Baumgardner, a collaborator of this research proposal, for three-dimensional thermal convection with constant viscosity. Over the duration supported by this research proposal, a significant amount of advancements have been accomplished.

Study of nanostructural organization of ionic liquids by electron paramagnetic resonance spectroscopy.

PubMed

Merunka, Dalibor; Peric, Mirna; Peric, Miroslav

2015-02-19

The X-band electron paramagnetic resonance spectroscopy (EPR) of a stable, spherical nitroxide spin probe, perdeuterated 2,2,6,6-tetramethyl-4-oxopiperidine-1-oxyl (pDTO) has been used to study the nanostructural organization of a series of 1-alkyl-3-methylimidazolium tetrafluoroborate ionic liquids (ILs) with alkyl chain lengths from two to eight carbons. By employing nonlinear least-squares fitting of the EPR spectra, we have obtained values of the rotational correlation time and hyperfine coupling splitting of pDTO to high precision. The rotational correlation time of pDTO in ILs and squalane, a viscous alkane, can be fit very well to a power law functionality with a singular temperature, which often describes a number of physical quantities measured in supercooled liquids. The viscosity of the ILs and squalane, taken from the literature, can also be fit to the same power law expression, which means that the rotational correlation times and the ionic liquid viscosities have similar functional dependence on temperature. The apparent activation energy of both the rotational correlation time of pDTO and the viscous flow of ILs and squalane increases with decreasing temperature; in other words, they exhibit strong non-Arrhenius behavior. The rotational correlation time of pDTO as a function of η/T, where η is the shear viscosity and T is the temperature, is well described by the Stokes-Einstein-Debye (SED) law, while the hydrodynamic probe radii are solvent dependent and are smaller than the geometric radius of the probe. The temperature dependence of hyperfine coupling splitting is the same in all four ionic liquids. The value of the hyperfine coupling splitting starts decreasing with increasing alkyl chain length in the ionic liquids in which the number of carbons in the alkyl chain is greater than four. This decrease together with the decrease in the hydrodynamic radius of the probe indicates a possible existence of nonpolar nanodomains.

User`s guide for UTCHEM-5.32m a three dimensional chemical flood simulator. Final report, September 30, 1992--December 31, 1995

DOE Office of Scientific and Technical Information (OSTI.GOV)

NONE

1996-07-01

UTCHEM is a three-dimensional chemical flooding simulator. The solution scheme is analogous to IMPES, where pressure is solved for implicitly, but concentrations rather than saturations are then solved for explicitly. Phase saturations and concentrations are then solved in a flash routine. An energy balance equation is solved explicitly for reservoir temperature. The energy balance equation includes heat flow between the reservoir and the over-and under-burden rocks. The major physical phenomena modeled in the simulator are: dispersion; dilution effects; adsorption; interfacial tension; relative permeability; capillary trapping; cation exchange; phase density; compositional phase viscosity; phase behavior (pseudoquaternary); aqueous reactions; partitioning of chemicalmore » species between oil and water; dissolution/precipitation; cation exchange reactions involving more than two cations; in-situ generation of surfactant from acidic crude oil; pH dependent adsorption; polymer properties: shear thinning viscosity; inaccessible pore volume; permeability reduction; adsorption; gel properties: viscosity; permeability reduction; adsorption; tracer properties: partitioning; adsorption; radioactive decay; reaction (ester hydrolization); temperature dependent properties: viscosity; tracer reaction; gel reactions The following options are available with UTCHEM: isothermal or non-isothermal conditions, a constant or variable time-step, constant pressure or constant rate well conditions, horizontal and vertical wells, and a radial or Cartesian geometry. Please refer to the dissertation {open_quotes}Field Scale Simulation of Chemical Flooding{close_quotes} by Naji Saad, August, 1989, for a more detailed discussion of the UTCHEM simulator and its formulation.« less

Shear viscosity of the quark-gluon plasma in a kinetic theory approach

DOE Office of Scientific and Technical Information (OSTI.GOV)

Puglisi, A.; Plumari, S.; Scardina, F.

2014-05-09

One of the main results of heavy ions collision (HIC) at relativistic energy experiments is the very small shear viscosity to entropy density ratio of the Quark-Gluon Plasma, close to the conjectured lower bound η/s=1/4π for systems in the infinite coupling limit. Transport coefficients like shear viscosity are responsible of non-equilibrium properties of a system: Green-Kubo relations give us an exact expression to compute these coefficients. We compute shear viscosity numerically using Green-Kubo relation in the framework of Kinetic Theory solving the relativistic transport Boltzmann equation in a finite box with periodic boundary conditions. We investigate a system of particlesmore » interacting via anisotropic and energy dependent cross-section in the range of temperature of interest for HIC. Green-Kubo results are in agreement with Chapman-Enskog approximation while Relaxation Time approximation can underestimates the viscosity of a factor 2. The correct analytic formula for shear viscosity can be used to develop a transport theory with a fixed η/s and have a comparison with physical observables like elliptic flow.« less

Thermodynamic Simulation of Viscosity of TiO2-Ti2O3-CaO Ternary Slag

NASA Astrophysics Data System (ADS)

Zhang, P.; Ma, W. H.; Zhang, S. J.; Lei, Y.; Wen, J. H.

2017-12-01

The viscosity of high titanium slag at high temperature is one of the key factors of slag-iron separation. Based on the Einstein-Roscoe equation, thermodynamic simulation of viscosity of TiO2-Ti2O3-CaO ternary slag is studied by using FactSage® software, and the effects of temperature, CaO content and solid-phase particles on the viscosity of slag were studied. The results show that the increase of CaO content has the effect of reducing melting temperature and viscosity of TiO2-Ti2O3-CaO ternary slag. After the TiO2-Ti2O3-CaO ternary slag is completely melted, the increase of temperature has little effect on viscosity of slag, and the viscosity is about 110~125mPa·s. When the temperature is lower than melting temperature, TiO2-Ti2O3-CaO ternary slag will precipitate solid-phase particles, and the precipitation process is carried out in stages, and with the decrease of temperature, the precipitation will increase and the viscosity will sharply increase. TiO2-Ti2O3-CaO ternary titanium slag has obvious characteristics of short slag.

Investigation of Ternary Mixtures Containing 1-Ethyl-3-methylimidazolium Bis(trifluoromethanesulfonyl)azanide, Ethylene Carbonate and Lithium Bis(trifluoromethanesulfonyl)azanide

PubMed Central

Hofmann, Andreas; Migeot, Matthias; Arens, Lukas; Hanemann, Thomas

2016-01-01

Temperature-dependent viscosity, conductivity and density data of ternary mixtures containing 1-ethyl-3-methylimidazolium bis(trifluoromethanesulfonyl)azanide (EMIM-TFSA), ethylene carbonate (EC), and lithium bis(trifluoromethanesulfonyl)azanide (Li-TFSA) were determined at atmospheric pressure in the temperature range of 20 to 80 °C. Differential scanning calorimetry (DSC) measurements were performed to characterize phase conditions of the mixtures in a temperature range of −120 to +100 °C. The viscosity data were fitted according to the Vogel-Fulcher-Tammann-Hesse (VFTH) equation and analyzed with the help of the fractional Walden rule. In this study, fundamental physicochemical data about the mixtures are provided and discussed as a basis for structure-property relationship calculations and for potential use of those mixtures as electrolytes for various applications. PMID:27153066

Effect of Viscosity on the Crystallization of Undercooled Liquids

NASA Technical Reports Server (NTRS)

2003-01-01

There have been numerous studies of glasses indicating that low-gravity processing enhances glass formation. NASA PI s are investigating the effect of low-g processing on the nucleation and crystal growth rates. Dr. Ethridge is investigating a potential mechanism for glass crystallization involving shear thinning of liquids in 1-g. For shear thinning liquids, low-g (low convection) processing will enhance glass formation. The study of the viscosity of glass forming substances at low shear rates is important to understand these new crystallization mechanisms. The temperature dependence of the viscosity of undercooled liquids is also very important for NASA s containerless processing studies. In general, the viscosity of undercooled liquids is not known, yet knowledge of viscosity is required for crystallization calculations. Many researchers have used the Turnbull equation in error. Subsequent nucleation and crystallization calculations can be in error by many orders of magnitude. This demonstrates the requirement for better methods for interpolating and extrapolating the viscosity of undercooled liquids. This is also true for undercooled water. Since amorphous water ice is the predominant form of water in the universe, astrophysicists have modeled the crystallization of amorphous water ice with viscosity relations that may be in error by five orders-of-magnitude.

Quantum close coupling calculation of transport and relaxation properties for Hg-H2 system

NASA Astrophysics Data System (ADS)

Nemati-Kande, Ebrahim; Maghari, Ali

2016-11-01

Quantum mechanical close coupling calculation of the state-to-state transport and relaxation cross sections have been done for Hg-H2 molecular system using a high-level ab initio potential energy surface. Rotationally averaged cross sections were also calculated to obtain the energy dependent Senftleben-Beenakker cross sections at the energy range of 0.005-25,000 cm-1. Boltzmann averaging of the energy dependent Senftleben-Beenakker cross sections showed the temperature dependency over a wide temperature range of 50-2500 K. Interaction viscosity and diffusion coefficients were also calculated using close coupling cross sections and full classical Mason-Monchick approximation. The results were compared with each other and with the available experimental data. It was found that Mason-Monchick approximation for viscosity is more reliable than diffusion coefficient. Furthermore, from the comparison of the experimental diffusion coefficients with the result of the close coupling and Mason-Monchick approximation, it was found that the Hg-H2 potential energy surface used in this work can reliably predict diffusion coefficient data.

Fluids by design using chaotic surface waves to create a metafluid that is Newtonian, thermal, and entirely tunable

PubMed Central

Welch, Kyle J.; Liebman-Peláez, Alexander; Corwin, Eric I.

2016-01-01

In conventional fluids, viscosity depends on temperature according to a strict relationship. To change this relationship, one must change the molecular nature of the fluid. Here, we create a metafluid whose properties are derived not from the properties of molecules but rather from chaotic waves excited on the surface of vertically agitated water. By making direct rheological measurements of the flow properties of our metafluid, we show that it has independently tunable viscosity and temperature, a quality that no conventional fluid possesses. We go on to show that the metafluid obeys the Einstein relation, which relates many-body response (viscosity) to single-particle dynamics (diffusion) and is a fundamental result in equilibrium thermal systems. Thus, our metafluid is wholly consistent with equilibrium thermal physics, despite being markedly nonequilibrium. Taken together, our results demonstrate a type of material that retains equilibrium physics while simultaneously allowing for direct programmatic control over material properties. PMID:27621467

Magnetohydrodynamic dissipative flow across the slendering stretching sheet with temperature dependent variable viscosity

NASA Astrophysics Data System (ADS)

Jayachandra Babu, M.; Sandeep, N.; Ali, M. E.; Nuhait, Abdullah O.

The boundary layer flow across a slendering stretching sheet has gotten awesome consideration due to its inexhaustible pragmatic applications in nuclear reactor technology, acoustical components, chemical and manufacturing procedures, for example, polymer extrusion, and machine design. By keeping this in view, we analyzed the two-dimensional MHD flow across a slendering stretching sheet within the sight of variable viscosity and viscous dissipation. The sheet is thought to be convectively warmed. Convective boundary conditions through heat and mass are employed. Similarity transformations used to change over the administering nonlinear partial differential equations as a group of nonlinear ordinary differential equations. Runge-Kutta based shooting technique is utilized to solve the converted equations. Numerical estimations of the physical parameters involved in the problem are calculated for the friction factor, local Nusselt and Sherwood numbers. Viscosity variation parameter and chemical reaction parameter shows the opposite impact to each other on the concentration profile. Heat and mass transfer Biot numbers are helpful to enhance the temperature and concentration respectively.

Activation energy associated with the electromigration of oligosaccharides through viscosity modifier and polymeric additive containing background electrolytes.

PubMed

Kerékgyártó, Márta; Járvás, Gábor; Novák, Levente; Guttman, András

2016-02-01

The activation energy related to the electromigration of oligosaccharides can be determined from their measured electrophoretic mobilities at different temperatures. The effects of a viscosity modifier (ethylene glycol) and a polymeric additive (linear polyacrylamide) on the electrophoretic mobility of linear sugar oligomers with α1-4 linked glucose units (maltooligosaccharides) were studied in CE using the activation energy concept. The electrophoretic separations of 8-aminopyrene-1,3,6-trisulfonate-labeled maltooligosaccharides were monitored by LIF detection in the temperature range of 20-50°C, using either 0-60% ethylene glycol (viscosity modifier) or 0-3% linear polyacrylamide (polymeric additive) containing BGEs. Activation energy curves were constructed based on the slopes of the Arrhenius plots. With the use of linear polyacrylamide additive, solute size-dependent activation energy variations were found for the maltooligosaccharides with polymerization degrees below and above maltoheptaose (DP 7), probably due to molecular conformation changes and possible matrix interaction effects. © 2015 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

Temperature-viscosity models reassessed.

PubMed

Peleg, Micha

2017-05-04

The temperature effect on viscosity of liquid and semi-liquid foods has been traditionally described by the Arrhenius equation, a few other mathematical models, and more recently by the WLF and VTF (or VFT) equations. The essence of the Arrhenius equation is that the viscosity is proportional to the absolute temperature's reciprocal and governed by a single parameter, namely, the energy of activation. However, if the absolute temperature in K in the Arrhenius equation is replaced by T + b where both T and the adjustable b are in °C, the result is a two-parameter model, which has superior fit to experimental viscosity-temperature data. This modified version of the Arrhenius equation is also mathematically equal to the WLF and VTF equations, which are known to be equal to each other. Thus, despite their dissimilar appearances all three equations are essentially the same model, and when used to fit experimental temperature-viscosity data render exactly the same very high regression coefficient. It is shown that three new hybrid two-parameter mathematical models, whose formulation bears little resemblance to any of the conventional models, can also have excellent fit with r 2 ∼ 1. This is demonstrated by comparing the various models' regression coefficients to published viscosity-temperature relationships of 40% sucrose solution, soybean oil, and 70°Bx pear juice concentrate at different temperature ranges. Also compared are reconstructed temperature-viscosity curves using parameters calculated directly from 2 or 3 data points and fitted curves obtained by nonlinear regression using a larger number of experimental viscosity measurements.

An accurate estimation method of kinematic viscosity for standard viscosity liquids

NASA Astrophysics Data System (ADS)

Kurano, Y.; Kobayashi, H.; Yoshida, K.; Imai, H.

1992-07-01

Deming's method of least squares is introduced to make an accurate kinematic viscosity estimation for a series of 13 standard-viscosity liquids at any desired temperature. The empirical ASTM kinematic viscosity-temperature equation is represented in the form loglog( v+c)=a-b log T, where v (in mm2. s-1) is the kinematic viscosity at temperature T (in K), a and b are the constants for a given liquid, and c has a variable value. In the present application, however, c is assumed to have a constant value for each standard-viscosity liquid, as do a and b in the ASTM equation. This assumption has since been verified experimentally for all standard-viscosity liquids. The kinematic viscosities for the 13 standard-viscosity liquids have been measured with a high accuracy in the temperature range of 20 40°C using a series of the NRLM capillary master viscometers with an automatic flow time detection system. The deviations between measured and estimated kinematic viscosities were less than ±0.04% for the 10 standard-viscosity liquids JS2.5 to JS2000 and ±0.11% for the 3 standard-viscosity liquids JS15H to JS200H, respectively. From the above investigation, it was revealed that the uncertainty in the present estimation method is less than one-third that in the usual ASTM method.

Exploring the Use of Ionic Liquid Mixtures to Enhance the Performance of Dicationic Ionic Liquids

DOE PAGES

Lall-Ramnarine, Sharon I.; Suarez, Sophia N.; Fernandez, Eddie D.; ...

2017-05-06

Dicationic ionic liquids (DILs) of diverse structural architectures (including symmetrical and asymmetrical ammonium, phosphonium and heterodications and the bis(trifluoromethylsulfonyl)amide (NTf 2 -) anion) have been prepared and used as additives to N-methyl-N-ethoxyethylpyrrolidinium (P 1EOE) NTf 2, a relatively high-performing IL in terms of its transport properties (viscosity 53 mPa s). The three-ion, binary IL mixtures were characterized for their thermal and transport properties using differential scanning calorimetry, temperature dependent viscosity, conductivity and Pulsed Gradient Spin Echo (PGSE) NMR. Variable temperature 1H, 19F and 31P self-diffusion coefficients were determined at 25, 60 and 75°C. The order of the diffusion coefficients wasmore » D(P 1EOE +) > D(anion) > D(dication), and the composition of the dication had a strong effect on the degree to which diffusion of all three species is more or less coupled. IL mixtures containing about 30 mol % of the dicationic NTf 2 and 70 mol % of P 1EOE NTf 2 resulted in a significant decrease in glass transition temperatures and viscosities compared to the pure DIL. The mixtures extended the liquid range and potential for practical applications significantly. Finally, the data obtained here provides insight into the future design of dicationic salts tailored to exhibit lower viscosity and higher conductivities.« less

Viscoplasticity of simulated high-level radioactive waste glass containing platinum group metal particles

NASA Astrophysics Data System (ADS)

Uruga, Kazuyoshi; Usami, Tsuyoshi; Tsukada, Takeshi; Komamine, Satoshi; Ochi, Eiji

2014-09-01

The shear rate dependency of the viscosity of three simulated high-level radioactive waste glasses containing 0, 1.2 and 4.5 wt% platinum group metals (PGMs) was examined at a temperature range of 1173-1473 K by a rotating viscometer. Shear stress when the shear rate equals zero, i.e. yield stress, was also measured by capillary method. The viscosity of the glass containing no PGM was shear rate-independent Newtonian fluid. On the other hand, the apparent viscosity of the glasses containing PGMs increased with decreasing shear rate, and nonzero amount of yield stresses were detected from both glasses. The viscosity and yield stress of the glass containing 4.5 wt% PGMs was roughly one to two orders of magnitude greater than the glass containing 1.2 wt% PGMs. These viscoplastic properties were numerically expressed by Casson equation.

A numerical study of three-dimensional diurnal variations within the thermosphere.

NASA Technical Reports Server (NTRS)

Volland, H.; Mayr, H. G.

1973-01-01

A thermosphere model with a realistic temperature profile is assumed. Heat conduction waves are introduced in addition to gravity waves. The temporal and spatial distribution of ion-neutral collisions is taken into account. However, the influence of viscosity waves is neglected. Viscosity-wave effects are simulated by an effective height-dependent collision number. Numerical calculations are conducted of the generation and propagation of two of the most important symmetric tidal waves at thermospheric heights. The influence of the solar EUV-heat upon the generation of the two tidal modes is investigated.

Viscoelastic behavior of basaltic ash from Stromboli volcano inferred from intermittent compression experiments

NASA Astrophysics Data System (ADS)

Kurokawa, A. K.; Miwa, T.; Okumura, S.; Uesugi, K.

2017-12-01

After ash-dominated Strombolian eruption, considerable amount of ash falls back to the volcanic conduit forming a dense near-surface region compacted by weights of its own and other fallback clasts (Patrick et al., 2007). Gas accumulation below this dense cap causes a substantial increase in pressure within the conduit, causing the volcanic activity to shift to the preliminary stages of a forthcoming eruption (Del Bello et al., 2015). Under such conditions, rheology of the fallback ash plays an important role because it controls whether the fallback ash can be the cap. However, little attention has been given to the point. We examined the rheology of ash collected at Stromboli volcano via intermittent compression experiments changing temperature and compression time/rate. The ash deformed at a constant rate during compression process, and then it was compressed without any deformation during rest process. The compression and rest processes repeated during each experiment to see rheological variations with progression of compaction. Viscoelastic changes during the experiment were estimated by Maxwell model. The results show that both elasticity and viscosity increases with decreasing porosity. On the other hand, the elasticity shows strong rate-dependence in the both compression and rest processes while the viscosity dominantly depends on the temperature, although the compression rate also affects the viscosity in the case of the compression process. Thus, the ash behaves either elastically or viscously depending on experimental process, temperature, and compression rate/time. The viscoelastic characteristics can be explained by magnitude relationships between the characteristic relaxation times and times for compression and rest processes. This indicates that the balance of the time scales is key to determining the rheological characteristics and whether the ash behaves elastically or viscously may control cyclic Strombolian eruptions.

Measuring internal friction of an ultrafast-folding protein.

PubMed

Cellmer, Troy; Henry, Eric R; Hofrichter, James; Eaton, William A

2008-11-25

Nanosecond laser T-jump was used to measure the viscosity dependence of the folding kinetics of the villin subdomain under conditions where the viscogen has no effect on its equilibrium properties. The dependence of the unfolding/refolding relaxation time on solvent viscosity indicates a major contribution to the dynamics from internal friction. The internal friction increases with increasing temperature, suggesting a shift in the transition state along the reaction coordinate toward the native state with more compact structures, and therefore, a smaller diffusion coefficient due to increased landscape roughness. Fitting the data with an Ising-like model yields a relatively small position dependence for the diffusion coefficient. This finding is consistent with the excellent correlation found between experimental and calculated folding rates based on free energy barrier heights using the same diffusion coefficient for every protein.

Measurement of the dynamic viscosity of hybrid engine oil -Cuo-MWCNT nanofluid, development of a practical viscosity correlation and utilizing the artificial neural network

NASA Astrophysics Data System (ADS)

Aghaei, Alireza; Khorasanizadeh, Hossein; Sheikhzadeh, Ghanbar Ali

2018-01-01

The main objectives of this study have been measurement of the dynamic viscosity of CuO-MWCNTs/SAE 5w-50 hybrid nanofluid, utilization of artificial neural networks (ANN) and development of a new viscosity model. The new nanofluid has been prepared by a two-stage procedure with volume fractions of 0.05, 0.1, 0.25, 0.5, 0.75 and 1%. Then, utilizing a Brookfield viscometer, its dynamic viscosity has been measured for temperatures of 5, 15, 25, 35, 45, 55 °C. The experimental results demonstrate that the viscosity increases by increasing the nanoparticles volume fraction and decreases by increasing temperature. Based on the experimental data the maximum and minimum nanofluid viscosity enhancements, when the volume fraction increases from 0.05 to 1, are 35.52% and 12.92% for constant temperatures of 55 and 15 °C, respectively. The higher viscosity of oil engine in higher temperatures is an advantage, thus this result is important. The measured nanofluid viscosity magnitudes in various shear rates show that this hybrid nanofluid is Newtonian. An ANN model has been employed to predict the viscosity of the CuO-MWCNTs/SAE 5w-50 hybrid nanofluid and the results showed that the ANN can estimate the viscosity efficiently and accurately. Eventually, for viscosity estimation a new temperature and volume fraction based third-degree polynomial empirical model has been developed. The comparison shows that this model is in good agreement with the experimental data.

ARRHENIUS MODEL FOR HIGH-TEMPERATURE GLASS VISCOSITY WITH A CONSTANT PRE-EXPONENTIAL FACTOR

DOE Office of Scientific and Technical Information (OSTI.GOV)

Hrma, Pavel R.

2008-04-15

A simplified form of the Arrhenius equation, ln η = A + B(x)/T, where η is the viscosity, T the temperature, x the composition vector, and A and B the Arrhenius coefficients, was fitted to glass-viscosity data for the processing temperature range (the range at which the viscosity is within 1 to 103 Pa.s) while setting A = constant and treating B(x) as a linear function of mass fractions of major components. Fitting the Arrhenius equation to over 550 viscosity data of commercial glasses and approximately 1000 viscosity data of glasses for nuclear-waste glasses resulted in the A values ofmore » -11.35 and -11.48, respectively. The R2 value ranged from 0.92 to 0.99 for commercial glasses and was 0.98 for waste glasses. The Arrhenius models estimate viscosities for melts of commercial glasses containing 42 to 84 mass% SiO2 within the temperature range of 1100 to 1550°C and viscosity range of 5 to 400 Pa.s and for waste glasses containing 32 to 60 mass% SiO2 within the temperature range of 850 to 1450°C and viscosity range of 0.4 to 250 Pa.s.« less

Structural and dynamical properties of liquid Al-Au alloys

NASA Astrophysics Data System (ADS)

Peng, H. L.; Voigtmann, Th.; Kolland, G.; Kobatake, H.; Brillo, J.

2015-11-01

We investigate temperature- and composition-dependent structural and dynamical properties of Al-Au melts. Experiments are performed to obtain accurate density and viscosity data. The system shows a strong negative excess volume, similar to other Al-based binary alloys. We develop a molecular-dynamics (MD) model of the melt based on the embedded-atom method (EAM), gauged against the available experimental liquid-state data. A rescaling of previous EAM potentials for solid-state Au and Al improves the quantitative agreement with experimental data in the melt. In the MD simulation, the admixture of Au to Al can be interpreted as causing a local compression of the less dense Al system, driven by less soft Au-Au interactions. This local compression provides a microscopic mechanism explaining the strong negative excess volume of the melt. We further discuss the concentration dependence of self- and interdiffusion and viscosity in the MD model. Al atoms are more mobile than Au, and their increased mobility is linked to a lower viscosity of the melt.

Trehalose Mediated Inhibition of Lactate Dehydrogenase from Rabbit Muscle. The Application of Kramers' Theory in Enzyme Catalysis.

PubMed

Hernández-Meza, Juan M; Sampedro, José G

2018-04-19

Lactate dehydrogenase (LDH) catalyzes the reduction of pyruvate to lactate by using NADH. LDH kinetics has been proposed to be dependent on the dynamics of a loop over the active site. Kramers' theory has been useful in the study of enzyme catalysis dependent on large structural dynamics. In this work, LDH kinetics was studied in the presence of trehalose and at different temperatures. In the absence of trehalose, temperature increase raised exponentially the LDH V max and revealed a sigmoid transition of K m toward a low-affinity state similar to protein unfolding. Notably, LDH V max diminished when in the presence of trehalose, while pyruvate affinity increased and the temperature-mediated binding site transition was hindered. The effect of trehalose on k cat was viscosity dependent as described by Kramers' theory since V max correlated inversely with the viscosity of the medium. As a result, activation energy ( E a ) for pyruvate reduction was dramatically increased by trehalose presence. This work provides experimental evidence that the dynamics of a structural component in LDH is essential for catalysis, i.e., the closing of the loop on the active site. While the trehalose mediated-increased of pyruvate affinity is proposed to be due to the compaction and/or increase of structural order at the binding site.

AIRCRAFT SHELTER-DICE THROW Data Report

DTIC Science & Technology

1977-03-01

damping fluid viscosity is temperature dependent, a number of thermistors were installed at velocity transducer locations. Accurate calibra- tion of these... thermistors enabled the temperatures at the velocity gage locations to be _etermi.ied through measurement of the thermistor resistances. These...stationary (reference) targets. As shown in Figures C-3 and C-5, targets were fabricated from steel pipe and welded to imbedded steel plates in the

Time-Dependent Reversible-Irreversible Deformation Threshold Determined Explicitly by Experimental Technique

NASA Technical Reports Server (NTRS)

Castelli, Michael G.; Arnold, Steven M.

2000-01-01

Structural materials for the design of advanced aeropropulsion components are usually subject to loading under elevated temperatures, where a material's viscosity (resistance to flow) is greatly reduced in comparison to its viscosity under low-temperature conditions. As a result, the propensity for the material to exhibit time-dependent deformation is significantly enhanced, even when loading is limited to a quasi-linear stress-strain regime as an effort to avoid permanent (irreversible) nonlinear deformation. An understanding and assessment of such time-dependent effects in the context of combined reversible and irreversible deformation is critical to the development of constitutive models that can accurately predict the general hereditary behavior of material deformation. To this end, researchers at the NASA Glenn Research Center at Lewis Field developed a unique experimental technique that identifies the existence of and explicitly determines a threshold stress k, below which the time-dependent material deformation is wholly reversible, and above which irreversible deformation is incurred. This technique is unique in the sense that it allows, for the first time, an objective, explicit, experimental measurement of k. The underlying concept for the experiment is based on the assumption that the material s time-dependent reversible response is invariable, even in the presence of irreversible deformation.

The influence of magma viscosity on convection within a magma chamber

NASA Astrophysics Data System (ADS)

Schubert, M.; Driesner, T.; Ulmer, P.

2012-12-01

Magmatic-hydrothermal ore deposits are the most important sources of metals like Cu, Mo, W and Sn and a major resource for Au. It is well accepted that they are formed by the release of magmatic fluids from a batholith-sized magma body. Traditionally, it has been assumed that crystallization-induced volatile saturation (called "second boiling") is the main mechanism for fluid release, typically operating over thousands to tens of thousands of years (Candela, 1991). From an analysis of alteration halo geometries caused by magmatic fluids, Cathles and Shannon (2007) suggested much shorter timescales in the order of hundreds of years. Such rapid release of fluids cannot be explained by second boiling as the rate of solidification scales with the slow conduction of heat away from the system. However, rapid fluid release is possible if convection is assumed within the magma chamber. The magma would degas in the upper part of the magma chamber and volatile poor magma would sink down again. Such, the rates of degassing can be much higher than due to cooling only. We developed a convection model using Navier-Stokes equations provided by the computational fluid dynamics platform OpenFOAM that gives the possibility to use externally derived meshes with complex (natural) geometries. We implemented a temperature, pressure, composition and crystal fraction dependent viscosity (Ardia et al., 2008; Giordano et al., 2008; Moore et al., 1998) and a temperature, pressure, composition dependent density (Lange1994). We found that the new viscosity and density models strongly affect convection within the magma chamber. The dependence of viscosity on crystal fraction has a particularly strong effect as the steep viscosity increase at the critical crystal fraction leads to steep decrease of convection velocity. As the magma chamber is cooling from outside to inside a purely conductive layer is developing along the edges of the magma chamber. Convection continues in the inner part of the magma chamber but the heat loss is limited by the conductive heat transport along the edges. The goal of the study is to consider magma degassing in terms of implementing solubility of water in dependence of temperature, pressure and composition and find a parameterization for the viscosity that considers the developing bubbles. References Ardia, P., Giordano, D., and Schmidt, M. W., 2008, A model for the viscosity of rhyolite as a function of H2O-content and pressure: A calibration based on centrifuge piston cylinder experiments: Geochimica Et Cosmochimica Acta, v. 72, no. 24, p. 6103-6123. Candela, P. A., 1991, Physics of Aqueous Phase Evolution in Plutonic Environments: American Mineralogist, v. 76, no. 7-8, p. 1081-1091. Cathles, L. M., and Shannon, R., 2007, How potassium silicate alteration suggests the formation of porphyry ore deposits begins with the nearly explosive but barren expulsion of large volumes of magmatic water: Earth and Planetary Science Letters, v. 262, no. 1-2, p. 92-108. Giordano, D., Russell, J. K., and Dingwell, D. B., 2008, Viscosity of magmatic liquids: A model: Earth and Planetary Science Letters, v. 271, no. 1-4, p. 123-134. Moore, G., Vennemann, T., and Carmichael, I. S. E., 1998, An empirical model for the solubility of H2O in magmas to 3 kilobars: American Mineralogist, v. 83, no. 1-2, p. 36-42.

Viscosity, relaxation time, and dynamics within a model asphalt of larger molecules

DOE Office of Scientific and Technical Information (OSTI.GOV)

Li, Derek D.; Greenfield, Michael L., E-mail: greenfield@egr.uri.edu

2014-01-21

The dynamics properties of a new “next generation” model asphalt system that represents SHRP AAA-1 asphalt using larger molecules than past models is studied using molecular simulation. The system contains 72 molecules distributed over 12 molecule types that range from nonpolar branched alkanes to polar resins and asphaltenes. Molecular weights range from 290 to 890 g/mol. All-atom molecular dynamics simulations conducted at six temperatures from 298.15 to 533.15 K provide a wealth of correlation data. The modified Kohlrausch-Williams-Watts equation was regressed to reorientation time correlation functions and extrapolated to calculate average rotational relaxation times for individual molecules. The rotational relaxationmore » rate of molecules decreased significantly with increasing size and decreasing temperature. Translational self-diffusion coefficients followed an Arrhenius dependence. Similar activation energies of ∼42 kJ/mol were found for all 12 molecules in the model system, while diffusion prefactors spanned an order of magnitude. Viscosities calculated directly at 533.15 K and estimated at lower temperatures using the Debye-Stokes-Einstein relationship were consistent with experimental data for asphalts. The product of diffusion coefficient and rotational relaxation time showed only small changes with temperature above 358.15 K, indicating rotation and translation that couple self-consistently with viscosity. At lower temperatures, rotation slowed more than diffusion.« less

Numerical Implementation of Ice Rheology for Europa's Shell

NASA Technical Reports Server (NTRS)

Barr, A. C.; Pappalardo, R. T.

2004-01-01

We present a discussion of approximations to the temperature dependent part of the rheology of ice. We have constructed deformation maps using the superplastic rheology of Goldsby & Kohlstedt and find that the rheologies that control convective flow in the Europa's are likely grain boundary sliding and basal slip for a range of grain sizes 0.1 mm < d < 1 cm. We compare the relative merits of two different approximations to the temperature dependence of viscosity and argue that for temperature ranges appropriate to Europa, implementing the non-Newtonian, lab-derived flow law directly is required to accurately judge the onset of convection in the ice shell and temperature gradient in the near-surface ice.

On the relationship between tectonic plates and thermal mantle plume morphology

NASA Technical Reports Server (NTRS)

Lenardic, A.; Kaula, W. M.

1993-01-01

Models incorporating plate-like behavior, i.e., near uniform surface velocity and deformation concentrated at plate boundaries, into a convective system, heated by a mix of internal and basal heating and allowing for temperature dependent viscosity, were constructed and compared to similar models not possessing plate-like behavior. The simplified numerical models are used to explore how plate-like behavior in a convective system can effect the lower boundary layer from which thermal plumes form. A principal conclusion is that plate-like behavior can significantly increase the temperature drop across the lower thermal boundary layer. This temperature drop affects the morphology of plumes by determining the viscosity drop across the boundary layer. Model results suggest that plumes on planets possessing plate-like behavior, e.g., the Earth, may differ in morphologic type from plumes on planets not possessing plate-like behavior, e.g., Venus and Mars.

Viscosity and density of methanol/water mixtures at low temperatures

NASA Technical Reports Server (NTRS)

Austin, J. G.; Kurata, F.; Swift, G. W.

1968-01-01

Viscosity and density are measured at low temperatures for three methanol/water mixtures. Viscosity is determined by a modified falling cylinder method or a calibrated viscometer. Density is determined by the volume of each mixture contained in a calibrated glass cell placed in a constant-temperature bath.

Viscosity of high-temperature iodine

NASA Technical Reports Server (NTRS)

Kang, Steve H.; Kunc, Joseph A.

1991-01-01

The viscosity coefficient of iodine in the temperature range 500 - 3000 K is calculated. Because of the low dissociation energy of the I2 molecules, the dissociation degree of the gas increases quickly with temperature, and I + I2 and I + I collisions must be taken into account in calculation of viscosity at temperatures greater than 1000 deg. Several possible channels for atom-atom interaction are considered, and the resulting collision integrals are averaged over all the important channels. It is also shown that the rigid-sphere model is inaccurate in predictions of the viscosity.

Geothermal Heat Flux and Upper Mantle Viscosity across West Antarctica: Insights from the UKANET and POLENET Seismic Networks

NASA Astrophysics Data System (ADS)

O'Donnell, J. P.; Dunham, C.; Stuart, G. W.; Brisbourne, A.; Nield, G. A.; Whitehouse, P. L.; Hooper, A. J.; Nyblade, A.; Wiens, D.; Aster, R. C.; Anandakrishnan, S.; Huerta, A. D.; Wilson, T. J.; Winberry, J. P.

2017-12-01

Quantifying the geothermal heat flux at the base of ice sheets is necessary to understand their dynamics and evolution. The heat flux is a composite function of concentration of upper crustal radiogenic elements and flow of heat from the mantle into the crust. Radiogenic element concentration varies with tectonothermal age, while heat flow across the crust-mantle boundary depends on crustal and lithospheric thicknesses. Meanwhile, accurately monitoring current ice mass loss via satellite gravimetry or altimetry hinges on knowing the upper mantle viscosity structure needed to account for the superimposed glacial isostatic adjustment (GIA) signal in the satellite data. In early 2016 the UK Antarctic Network (UKANET) of 10 broadband seismometers was deployed for two years across the southern Antarctic Peninsula and Ellsworth Land. Using UKANET data in conjunction with seismic records from our partner US Polar Earth Observing Network (POLENET) and the Antarctic Seismographic Argentinian Italian Network (ASAIN), we have developed a 3D shear wave velocity model of the West Antarctic crust and uppermost mantle based on Rayleigh and Love wave phase velocity dispersion curves extracted from ambient noise cross-correlograms. We combine seismic receiver functions with the shear wave model to help constrain the depth to the crust-mantle boundary across West Antarctica and delineate tectonic domains. The shear wave model is subsequently converted to temperature using a database of densities and elastic properties of minerals common in crustal and mantle rocks, while the various tectonic domains are assigned upper crustal radiogenic element concentrations based on their inferred tectonothermal ages. We combine this information to map the basal geothermal heat flux variation across West Antarctica. Mantle viscosity depends on factors including temperature, grain size, the hydrogen content of olivine and the presence of melt. Using published mantle xenolith and magnetotelluric data to constrain grain size and hydrogen content, respectively, we use the temperature model to estimate the regional upper mantle viscosity structure. The viscosity information will be incorporated in a 3D GIA model that will better constrain estimates of current ice loss from the West Antarctic Ice Sheet.

DOE Office of Scientific and Technical Information (OSTI.GOV)

Xiong, L. H.; Wang, X. D.; Yu, Q.

Temperature-dependent atomistic structure evolution of liquid gallium (Ga) has been investigated by using in situ high energy X-ray diffraction experiment and ab initio molecular dynamics simulation. Both experimental and theoretical results reveal the existence of a liquid structural change around 1000 K in liquid Ga. Below and above this temperature the liquid exhibits differences in activation energy for selfdiffusion, temperature-dependent heat capacity, coordination numbers, density, viscosity, electric resistivity and thermoelectric power, which are reflected from structural changes of the bond-orientational order parameter Q6, fraction of covalent dimers, averaged string length and local atomic packing. This finding will trigger more studiesmore » on the liquid-to-liquid crossover in metallic melts.« less

Fluorine and the viscosity of jadeite-leucite and nepheline-kalsilite melts at atmospheric pressure

NASA Astrophysics Data System (ADS)

Robert, G.; Bruno, M.; Carty, O.; Smith, R. A.; Whittington, A. G.

2017-12-01

While fluorine has a lower abundance than H2O and CO2 in most magmatic and volcanic systems, F is as effective as water at reducing the viscosity of silica-rich melts. Previous studies have also shown that, just like water, the effect of F in reducing melt viscosity is strongest in the most highly polymerized melts. We measured the viscosity of fluorine-free and fluorine-bearing melts along the jadeite-leucite (Jd-Lct) and nepheline-kalsilite (Ne-Kls) joins of the NaAlSiO4-KAlSiO4-SiO2 system. All compositions studied are metaluminous to slightly peraluminous, and nominally fully polymerized (noting that non-bridging oxygen sites exist in metaluminous and peraluminous glasses, their proportion being a function of Al/Si ratio and cation charge). We test whether the effects of fluorine on viscosity have a dependence on Na/K or Al/Si ratios in these melts. In fluorine-free melts, the K-rich melts have the highest viscosity and T12 (temperature of the 1012 Pas isokom). The mixed-alkali effect results in a viscosity minimum at compositions with intermediate Na/K ratios. At 1200K, for the Na- end-member melts, the lowest Al/Si ratio melts (nepheline-kalsilite melts) have the highest viscosity. Available literature data and extrapolation of trends from our measurements suggest there is little difference in viscosity between the K- end-member melts at 1200K. At high temperatures, the jadeite-leucite melts generally have higher viscosities than the nepheline-kalsilite melts. Fluorine reduces the viscosity of all of the melts we studied, and, although it has been suggested that fluorine preferentially bonds with potassium over sodium, its effects on viscosity appears to be approximately independent of Na/K ratio in metaluminous melts. With increasing Al/Si ratio, more order is required to satisfy the aluminum avoidance principle, but this also does not seem to affect the magnitude of viscosity reduction due to the addition of fluorine, at least for melts with intermediate Na/K ratio. Adding 8 mol% F to melts with Na/(Na+K) ratio of 0.5 results in a T12 reduction of 186°C relative to F-free melts.

Finite element modeling of melting and fluid flow in the laser-heated diamond-anvil cell

NASA Astrophysics Data System (ADS)

Gomez-Perez, N.; Rodriguez, J. F.; McWilliams, R. S.

2017-04-01

The laser-heated diamond anvil cell is widely used in the laboratory study of materials behavior at high-pressure and high-temperature, including melting curves and liquid properties at extreme conditions. Laser heating in the diamond cell has long been associated with fluid-like motion in samples, which is routinely used to determine melting points and is often described as convective in appearance. However, the flow behavior of this system is poorly understood. A quantitative treatment of melting and flow in the laser-heated diamond anvil cell is developed here to physically relate experimental motion to properties of interest, including melting points and viscosity. Numerical finite-element models are used to characterize the temperature distribution, melting, buoyancy, and resulting natural convection in samples. We find that continuous fluid motion in experiments can be explained most readily by natural convection. Fluid velocities, peaking near values of microns per second for plausible viscosities, are sufficiently fast to be detected experimentally, lending support to the use of convective motion as a criterion for melting. Convection depends on the physical properties of the melt and the sample geometry and is too sluggish to detect for viscosities significantly above that of water at ambient conditions, implying an upper bound on the melt viscosity of about 1 mPa s when convective motion is detected. A simple analytical relationship between melt viscosity and velocity suggests that direct viscosity measurements can be made from flow speeds, given the basic thermodynamic and geometric parameters of samples are known.

Wavelength dependence of the Brillouin spectral width of boron doped germanosilicate optical fibers.

PubMed

Law, Pi-Cheng; Dragic, Peter D

2010-08-30

Boron co-doped germanosilicate fibers are investigated via the Brillouin light scattering technique using two wavelengths, 1534 nm and 1064 nm. Several fibers are investigated, including four drawn from the same preform but at different draw temperatures. The Stokes' shifts and the Brillouin spectral widths are found to increase with increasing fiber draw temperature. A frequency-squared law has adequately described the wavelength dependence of the Brillouin spectral width of conventional Ge-doped fibers. However, it is found that unlike conventional Ge-doped fibers these fibers do not follow the frequency-squared law. This is explained through a frequency-dependent dynamic viscosity that modifies this law.

Unveiling the relationships among the viscosity equations of glass liquids and colloidal suspensions for obtaining universal equations with the generic free volume concept.

PubMed

Hao, Tian

2015-09-14

The underlying relationships among viscosity equations of glass liquids and colloidal suspensions are explored with the aid of free volume concept. Viscosity equations of glass liquids available in literature are focused and found to have a same physical basis but different mathematical expressions for the free volume. The glass transitions induced by temperatures in glass liquids and the percolation transition induced by particle volume fractions in colloidal suspensions essentially are a second order phase transition: both those two transitions could induce the free volume changes, which in turn determines how the viscosities are going to change with temperatures and/or particle volume fractions. Unified correlations of the free volume to both temperatures and particle volume fractions are thus proposed. The resulted viscosity equations are reducible to many popular viscosity equations currently widely used in literature; those equations should be able to cover many different types of materials over a wide temperature range. For demonstration purpose, one of the simplified versions of those newly developed equations is compared with popular viscosity equations and the experimental data: it can well fit the experimental data over a wide temperature range. The current work reveals common physical grounds among various viscosity equations, deepening our understanding on viscosity and unifying the free volume theory across many different systems.

Effects of temperature and particles concentration on the dynamic viscosity of MgO-MWCNT/ethylene glycol hybrid nanofluid: Experimental study

NASA Astrophysics Data System (ADS)

Soltani, Omid; Akbari, Mohammad

2016-10-01

In this paper, the effects of temperature and particles concentration on the dynamic viscosity of MgO-MWCNT/ethylene glycol hybrid nanofluid is examined. The experiments carried out in the solid volume fraction range of 0 to 1.0% under the temperature ranging from 30 °C to 60 °C. The results showed that the hybrid nanofluid behaves as a Newtonian fluid for all solid volume fractions and temperatures considered. The measurements also indicated that the dynamic viscosity increases with increasing the solid volume fraction and decreases with the temperature rising. The relative viscosity revealed that when the solid volume fraction enhances from 0.1 to 1%, the dynamic viscosity increases up to 168%. Finally, using experimental data, in order to predict the dynamic viscosity of MgO-MWCNT/ethylene glycol hybrid nanofluids, a new correlation has been suggested. The comparisons between the correlation outputs and experimental results showed that the suggested correlation has an acceptable accuracy.

Plasma viscosity with mass transport in spherical inertial confinement fusion implosion simulations

DOE Office of Scientific and Technical Information (OSTI.GOV)

Vold, E. L.; Molvig, K.; Joglekar, A. S.

2015-11-15

The effects of viscosity and small-scale atomic-level mixing on plasmas in inertial confinement fusion (ICF) currently represent challenges in ICF research. Many current ICF hydrodynamic codes ignore the effects of viscosity though recent research indicates viscosity and mixing by classical transport processes may have a substantial impact on implosion dynamics. We have implemented a Lagrangian hydrodynamic code in one-dimensional spherical geometry with plasma viscosity and mass transport and including a three temperature model for ions, electrons, and radiation treated in a gray radiation diffusion approximation. The code is used to study ICF implosion differences with and without plasma viscosity andmore » to determine the impacts of viscosity on temperature histories and neutron yield. It was found that plasma viscosity has substantial impacts on ICF shock dynamics characterized by shock burn timing, maximum burn temperatures, convergence ratio, and time history of neutron production rates. Plasma viscosity reduces the need for artificial viscosity to maintain numerical stability in the Lagrangian formulation and also modifies the flux-limiting needed for electron thermal conduction.« less

Contribution to modeling the viscosity Arrhenius-type equation for saturated pure fluids

NASA Astrophysics Data System (ADS)

Tian, Jianxiang; Zhang, Laibin

2016-09-01

Recently, Haj-Kacem et al. proposed an equation modeling the relationship between the two parameters of viscosity Arrhenius-type equations [Fluid Phase Equilibria 383, 11 (2014)]. The authors found that the two parameters are dependent upon each other in an exponential function form. In this paper, we reconsidered their ideas and calculated the two parameter values for 49 saturated pure fluids by using the experimental data in the NIST WebBook. Our conclusion is different with the ones of Haj-Kacem et al. We found that (the linearity shown by) the Arrhenius equation stands strongly only in low temperature range and that the two parameters of the Arrhenius equation are independent upon each other in the whole temperature range from the triple point to the critical point.

New Formulation for the Viscosity of n-Butane

NASA Astrophysics Data System (ADS)

Herrmann, Sebastian; Vogel, Eckhard

2018-03-01

A new viscosity formulation for n-butane, based on the residual quantity concept, uses the reference equation of state by Bücker and Wagner [J. Phys. Chem. Ref. Data 35, 929 (2006)] and is valid in the fluid region from the triple point to 650 K and to 100 MPa. The contributions for the zero-density viscosity and for the initial-density dependence were separately developed, whereas those for the critical enhancement and for the higher-density terms were pretreated. All contributions were given as a function of the reciprocal reduced temperature τ, while the last two contributions were correlated as a function of τ and of the reduced density δ. The different contributions were based on specific primary data sets, whose evaluation and choice were discussed in detail. The final formulation incorporates 13 coefficients derived employing a state-of-the-art linear optimization algorithm. The viscosity at low pressures p ≤ 0.2 MPa is described with an expanded uncertainty of 0.5% (coverage factor k = 2) for temperatures 293 ≤ T/K ≤ 626. The expanded uncertainty in the vapor phase at subcritical temperatures T ≥ 298 K as well as in the supercritical thermodynamic region T ≤ 448 K at pressures p ≤ 30 MPa is estimated to be 1.5%. It is raised to 4.0% in regions where only less reliable primary data sets are available and to 6.0% in ranges without any primary data, but in which the equation of state is valid. A weakness of the reference equation of state in the near-critical region prevents estimation of the expanded uncertainty in this region. Viscosity tables for the new formulation are presented in Appendix B for the single-phase region, for the vapor-liquid phase boundary, and for the near-critical region.

Reanalysis of the fragility of glycerol at very high pressures using new Tg data

NASA Astrophysics Data System (ADS)

Lyon, Kevin; Oliver, William

Direct measurements of the glass transition temperature of glycerol between 1 atm and 6.7 GPa from our lab allow reanalysis of high-pressure viscosity data, which were limited to approximately 107 poise. Previous attempts to determine Tg (P) and fragility by extrapolation of the viscosity data by many orders of magnitude led to inconclusive results. Tg (P) data constrain the value of viscosity at the glass transition providing for more accurate determinations of isobaric fragilities. Over most of the pressure range, a constant fragility is found in agreement with analysis of high-pressure dielectric data by Paluch et al.. Discrepancies in the pressure dependence of the fragility of glycerol at very low pressures exist in the literature and will also be discussed.

Magnetic fluid hyperthermia probed by both calorimetric and dynamic hysteresis measurements

NASA Astrophysics Data System (ADS)

Guibert, Clément; Fresnais, Jérôme; Peyre, Véronique; Dupuis, Vincent

2017-01-01

In this paper, we report an investigation of magnetic fluid hyperthermia (MFH) using combined calorimetric and newly implemented dynamic hysteresis measurements for two sets of well characterized size-sorted maghemite nanoparticles (with diameters of about 10 nm and 20 nm) dispersed in water and in glycerol. Our primary goal was to assess the influence of viscosity on the heating efficiency of magnetic nanoparticles described in terms of specific loss power (SLP or specific absorption rate, SAR) and dynamic hysteresis. In particular, we aimed to investigate how this SLP depends on the transition from Néelian to Brownian behavior of nanoparticles expected to occur between 10 nm and 20 nm (for maghemite) and dependent on the viscosity. While we observed a good agreement between calorimetric and dynamic hysteresis measurements, we found that the SLP measured for the different systems do not depend noticeably on the viscosity of solvent. Calculations performed according to Rosensweig's linear model [1] allow us to quantitatively reproduce our results at low field intensities, provided we use a value for the magnetic anisotropy constant much smaller than the one commonly used in the literature. This raises the question of the temperature dependance of the magnetic anisotropy constant and its relevance for a quantitative description of MFH.

46 CFR 153.908 - Cargo viscosity and melting point information; measuring cargo temperature during discharge...

Code of Federal Regulations, 2014 CFR

2014-10-01

... 46 Shipping 5 2014-10-01 2014-10-01 false Cargo viscosity and melting point information; measuring... Cargo viscosity and melting point information; measuring cargo temperature during discharge: Categories... lading, a written statement of the following: (1) For Category A or B NLS, the cargo's viscosity at 20 °C...

46 CFR 153.908 - Cargo viscosity and melting point information; measuring cargo temperature during discharge...

Code of Federal Regulations, 2013 CFR

2013-10-01

... 46 Shipping 5 2013-10-01 2013-10-01 false Cargo viscosity and melting point information; measuring... Cargo viscosity and melting point information; measuring cargo temperature during discharge: Categories... lading, a written statement of the following: (1) For Category A or B NLS, the cargo's viscosity at 20 °C...

46 CFR 153.908 - Cargo viscosity and melting point information; measuring cargo temperature during discharge...

Code of Federal Regulations, 2012 CFR

2012-10-01

... 46 Shipping 5 2012-10-01 2012-10-01 false Cargo viscosity and melting point information; measuring... Cargo viscosity and melting point information; measuring cargo temperature during discharge: Categories... lading, a written statement of the following: (1) For Category A or B NLS, the cargo's viscosity at 20 °C...

Flow properties of liquid crystal phases of the Gay-Berne fluid

NASA Astrophysics Data System (ADS)

Sarman, Sten

1998-05-01

We have calculated the viscosities of a variant of the Gay-Berne fluid as a function of the temperature by performing molecular dynamics simulations. We have evaluated the Green-Kubo relations for the various viscosity coefficients. The results have been cross-checked by performing shear flow simulations. At high temperatures there is a nematic phase that is transformed to a smectic A phase as the temperature is decreased. The nematic phase is found to be flow stable. Close to the nematic-smectic transition point the liquid crystal model system becomes flow unstable. This is in agreement with the theoretical predictions by Jähnig and Brochard [F. Jähnig and F. Brochard, J. Phys. 35, 301 (1974)]. In a planar Couette flow one can define the three Miesowicz viscosities or effective viscosities η1, η2, and η3. The coefficient η1 is the viscosity when the director is parallel to the streamlines, η2 is the viscosity when the director is perpendicular to the shear plane, and η3 is the viscosity when the director is perpendicular to the vorticity plane. In the smectic phase η1 is undefined because the strain rate field is incommensurate with the smectic layer structure when the director is parallel to the streamlines. The viscosity η3 is found to be fairly independent of the temperature. The coefficient η2 increases with the temperature. This is unusual because the viscosity of most isotropic liquids decreases with the temperature. This anomaly is due to the smectic layer structure that is present at low temperatures. This lowers the friction because the layers can slide past each other fairly easily.

Experimental investigation on thermal conductivity and viscosity of maghemite (γ –Fe2O3) water-based nanofluids

NASA Astrophysics Data System (ADS)

Nurdin, I.; Johan, M. R.; Ang, B. C.

2018-03-01

Thermal conductivity and kinematic viscosity of maghemite nanofluids were experimentally investigated at a small volume fraction of maghemite nanoparticles and temperatures. Maghemite nanofluids were prepared by suspending maghemite nanoparticles in water as base fluids. Results show that the thermal conductivity of maghemite nanofluids linearly increase with increasing particle volume fraction and temperature, while kinematic viscosity increase with increasing particle volume fraction and decrease with increasing temperature. The highest enhancement of thermal conductivity and kinematic viscosity are 18.84% and 13.66% respectively, at particle volume fraction 0.6% and temperature 35.

g-Jitter Mixed Convective Slip Flow of Nanofluid past a Permeable Stretching Sheet Embedded in a Darcian Porous Media with Variable Viscosity

PubMed Central

Uddin, Mohammed J.; Khan, Waqar A.; Amin, Norsarahaida S.

2014-01-01

The unsteady two-dimensional laminar g-Jitter mixed convective boundary layer flow of Cu-water and Al2O3-water nanofluids past a permeable stretching sheet in a Darcian porous is studied by using an implicit finite difference numerical method with quasi-linearization technique. It is assumed that the plate is subjected to velocity and thermal slip boundary conditions. We have considered temperature dependent viscosity. The governing boundary layer equations are converted into non-similar equations using suitable transformations, before being solved numerically. The transport equations have been shown to be controlled by a number of parameters including viscosity parameter, Darcy number, nanoparticle volume fraction, Prandtl number, velocity slip, thermal slip, suction/injection and mixed convection parameters. The dimensionless velocity and temperature profiles as well as friction factor and heat transfer rates are presented graphically and discussed. It is found that the velocity reduces with velocity slip parameter for both nanofluids for fluid with both constant and variable properties. It is further found that the skin friction decreases with both Darcy number and momentum slip parameter while it increases with viscosity variation parameter. The surface temperature increases as the dimensionless time increases for both nanofluids. Nusselt numbers increase with mixed convection parameter and Darcy numbers and decreases with the momentum slip. Excellent agreement is found between the numerical results of the present paper with published results. PMID:24927277

Electrorheology for energy production and conservation

NASA Astrophysics Data System (ADS)

Huang, Ke

Recently, based on the physics of viscosity, we developed a new technology, which utilizes electric or magnetic fields to change the rheology of complex fluids to reduce the viscosity, while keeping the temperature unchanged. The method is universal and applicable to all complex fluids with suspended particles of nano-meter, submicrometer, or micrometer size. Completely different from the traditional viscosity reduction method, raising the temperature, this technology is energy-efficient, as it only requires small amount of energy to aggregate the suspended particles. In this thesis, we will first discuss this new technology in detail, both in theory and practice. Then, we will report applications of our technology to energy science research. Presently, 80% of all energy sources are liquid fuels. The viscosity of liquid fuels plays an important role in energy production and energy conservation. With an electric field, we can reduce the viscosity of asphalt-based crude oil. This is important and useful for heavy crude oil and off-shore crude oil production and transportation. Especially, since there is no practical way to raise the temperature of crude oil inside the deepwater pipelines, our technology may play a key role in future off-shore crude oil production. Electrorehology can also be used to reduce the viscosity of refinery fuels, such as diesel fuel and gasoline. When we apply this technology to fuel injection, the fuel droplets in the fuel atomization become smaller, leading to faster combustion in the engine chambers. As the fuel efficiency of internal combustion engines depends on the combustion speed and timing, the fast combustion produces much higher fuel efficiency. Therefore, adding our technology on existing engines improves the engine efficiency significantly. A theoretical model for the engine combustion, which explains how fast combustion improves the engine efficiency, is also presented in the thesis. As energy is the key to our national security, we believe that our technology is important and will have a strong impact on energy production and conversation in the future.

Shear viscosity and imperfect fluidity in bosonic and fermionic superfluids

NASA Astrophysics Data System (ADS)

Boyack, Rufus; Guo, Hao; Levin, K.

2014-12-01

In this paper we address the ratio of the shear viscosity to entropy density η /s in bosonic and fermionic superfluids. A small η /s is associated with nearly perfect fluidity, and more general measures of the fluidity perfection/imperfection are of wide interest to a number of communities. We use a Kubo approach to concretely address this ratio via low-temperature transport associated with the quasiparticles. Our analysis for bosonic superfluids utilizes the framework of the one-loop Bogoliubov approximation, whereas for fermionic superfluids we apply BCS theory and its BCS-BEC extension. Interestingly, we find that the transport properties of strict BCS and Bogoliubov superfluids have very similar structures, albeit with different quasiparticle dispersion relations. While there is a dramatic contrast between the power law and exponential temperature dependence for η alone, the ratio η /s for both systems is more similar. Specifically, we find the same linear dependence (on the ratio of temperature T to inverse lifetime γ (T ) ) with η /s ∝T /γ (T ) , corresponding to imperfect fluidity. By contrast, near the unitary limit of BCS-BEC superfluids a very different behavior results, which is more consistent with near-perfect fluidity.

Reference Correlation for the Viscosity of Ammonia from the Triple Point to 725 K and up to 50 MPa

NASA Astrophysics Data System (ADS)

Monogenidou, S. A.; Assael, M. J.; Huber, M. L.

2018-06-01

This paper presents a new wide-ranging correlation for the viscosity of ammonia based on critically evaluated experimental data. The correlation is designed to be used with a recently developed equation of state, and it is valid from the triple point to 725 K at pressures up to 50 MPa. The estimated uncertainty varies depending on the temperature and pressure, from 0.6% to 5%. The correlation behaves in a physically reasonable manner when extrapolated to 100 MPa; however, care should be taken when using the correlation outside of the validated range.

DOE Office of Scientific and Technical Information (OSTI.GOV)

Matyas, Josef; Cooley, Scott K.; Sundaram, S. K.

Slags of low viscosity readily penetrate the refractory lining in slagging gasifiers, causing rapid and severe corrosion called spalling. In addition, a low-viscosity slag that flows down the gasifier wall forms a relatively thin layer of slag on the refractory surface, allowing the corrosive gases in the gasifier to participate in the chemical reactions between the refractory and the slag. In contrast, a slag viscosity of <25 Pa•s at 1400°C is necessary to minimize the possibility of plugging the slag tap. There is a need to predict and optimize slag viscosity so slagging gasifiers can operate continuously at temperatures rangingmore » from 1300 to 1650°C. The approach adopted in this work was to statistically design and prepare simulated slags, measure the viscosity as a function of temperature, and develop a model to predict slag viscosity based on slag composition and temperature. Statistical design software was used to select compositions from a candidate set of all possible vertices that will optimally represent the composition space for 10 main components. A total of 21 slag compositions were generated, including 5 actual coal slag compositions. The Arrhenius equation was applied to measured viscosity versus temperature data of tested slags, and the Arrhenius coefficients (A and B in ln(vis) = A + B/T) were expressed as linear functions of the slag composition. The viscosity model was validated using 1) data splitting approach, and 2) viscosity/temperature data of selected slag compositions from the literature that were formulated and melted at Pacific Northwest National Laboratory. The capability of the model to predict the viscosity of coal slags was compared with the model developed by Browning et al. because this model can predict the viscosity of slags from coal ash better than the most commonly used empirical models found in the literature.« less

Rheological study of synovial fluid obtained from dogs: healthy, pathological, and post-surgery, after spontaneous rupture of cranial cruciate ligament.

PubMed

Goudoulas, Thomas B; Kastrinakis, Eleftherios G; Nychas, Stavros G; Papazoglou, Lysimachos G; Kazakos, George M; Kosmas, Panagiotis V

2010-01-01

In the present study synovial fluid (SF) obtained from the stifle joint of healthy adult dogs and of dogs after cranial cruciate ligament rupture was analyzed regarding its rheological characteristics according to the condition of the joint. The viscoelastic and shear flow properties were measured at 25 and 38 degrees C. The results showed that the healthy SF exhibits practically temperature independent viscosity curve and satisfactory viscoelastic characteristics, i.e. G' > G'', over frequencies of 0.05-5 Hz, and characteristic relaxation time lambda of the order of magnitude of 100 s. Creep measurements demonstrate that the zero shear viscosity was in the range of 10-100 Pa s. In shear flow viscosity measurements, by increasing gamma from 10(-4) s(-1) up to 10(3) s(-1), non-Newtonian shear thinning behavior was observed and the viscosity values were decreased from 10(3) to 0.1 Pa s. On the contrary, in pathological conditions of cranial cruciate ligament rupture (CCLR), the measured viscosity was found drastically reduced, i.e. between 100 and 10 mPa s. The CCLR synovial fluid, similar to healthy SF, exhibits insignificant temperature dependence. The present study showed also that about one week after a surgery for CCLR repair the SF exhibits non-Newtonian behavior of dilute polymers. After two weeks from the operation, however, the rheological behavior converges to the one of healthy SF.

Effect of total solids content and temperature on the rheological behaviour of reconstituted whole milk concentrates.

PubMed

Trinh, Binh; Trinh, Khanh Tuoc; Haisman, Derek

2007-02-01

This work investigated the combined effect of solids content, heating and storage temperatures on the rheological behaviour of reconstituted whole milk concentrates. The powder was reconstituted at 35 degrees C in a custom built recombination rig to various total solids content (TS) from 10-48% TS. The concentrates were then heated to 45-85 degrees C and stored at the heating temperature. The rheological behaviour shifter from Newtonian behaviour (below 30% TS) to power law (below 40% TS), with the yield stress observed from 40% TS upwards and time-dependent behaviour was noticed above 44% TS. Higher heating temperatures tend to promote non-Newtonian behaviour at lower solids content. The viscosity-solid content curve showed an exponential relationship, while the viscosity-temperature curve exhibited a minimum at 65-75 degrees C above 46% TS. During age thickening, the yield stress and the consistency coefficient increased, while the flow behaviour index decreased with storage time. This indicated that the milk concentrates deviated away from Newtonian behaviour during age thickening.

Dependence of viscosity of suspensions of ceramic nanopowders in ethyl alcohol on concentration and temperature

PubMed Central

2012-01-01

This work presents results of measurements of viscosity of suspensions including yttrium oxide (Y2O3), yttrium aluminum garnet (Y3Al5O12) and magnesium aluminum spinel (MgAl2O4) nanopowders in ethanol. Nanoparticles used in our research were either commercially available (Baikowski) or nanopowders newly developed in the Institute of Ceramics and Building Materials in Warsaw, Poland. The study was conducted in a wide range of shear rates (0.01 to 2,000 s−1) and temperature interval from -15°C to 20°C. A Haake Mars 2 rheometer from Thermo Fisher, Germany, was used in the Biophysics Laboratory at Rzeszów University of Technology. Most of the samples show a non-Newtonian behaviour. It was confirmed with a Rheo-NMR system from Bruker that 10% by weight of Y2O3 suspension is a non-Newtonian fluid. In this work, we also report an unexpected behaviour of the viscosity of some samples (Y2O3 and Y3Al5O12) due to sedimentation effect. PMID:22824064

Bonding Strength Properties of Adhesively-Timber Joint with Thixotropic and Room Temperature Cured Epoxy Based Adhesive Reinforced with Nano- and Micro-particles

NASA Astrophysics Data System (ADS)

Ahmad, Z.; Ansell, M. P.; Smedley, D.

2011-02-01

This research work is concerned with in situ bonded-in timber connection using pultruded rod; where the manufacturing of such joint requires adhesive which can produce thick glue-lines and does not allow any use of pressure and heat. Four types of thixotropic (for ease application) and room temperature cured epoxy based were used namely CB10TSS (regarded as standards adhesive), Nanopox (modification of CB10TSS with addition of nanosilica), Albipox (modification of CB10TSS with addition of liquid rubber) and Timberset (an epoxy-based adhesive with addition of micro-size ceramic particles). The quality of the adhesive bonds was accessed using block shear test in accordance with ASTM D905. The bond strength depends on how good the adhesive wet the timber surface. Therefore the viscosity and contact angle was also measured. The nano- and microfiller additions increased the bond strength significantly. The viscosity correlates well with contact angle measurements where lower viscosities are associated with lower contact angles. However contact angle contradicts with measured strength and wettability.

A Simple Model for the Viscosity of Rhyolites as a Function of Temperature, Pressure and Water Content: Implications for Obsidian Flow Emplacement

NASA Astrophysics Data System (ADS)

Whittington, A. G.; Romine, W. L.

2014-12-01

Understanding the dynamics of rhyolitic conduits and lava flows, requires precise knowledge of how viscosity (η) varies with temperature (T), pressure (P) and volatile content (X). In order to address the paucity of viscosity data for high-silica rhyolite at low water contents, which represent water saturation at near-surface conditions, we made 245 viscosity measurements on Mono Craters (California) rhyolites containing between 0.01 and 1.1 wt.% H2O, at temperatures between 796 and 1774 K using parallel plate and concentric cylinder methods at atmospheric pressure. We then developed and calibrated a new empirical model for the log of the viscosity of rhyolitic melts, where non-linear variations due to temperature and water content are nested within a linear dependence of log η on P. The model was fitted to a total of 563 data points: our 245 new data, 255 published data from rhyolites across a wide P-T-X space, and 63 data on haplogranitic and granitic melts under high P-T conditions. Statistically insignificant parameters were eliminated from the model in an effort to increase parsimony and the final model is simple enough for use in numerical models of conduit or lava flow dynamics: log η = -5.142+(13080-2982log⁡(w+0.229))/(T-(98.9-175.9 log⁡(w+0.229)))- P(0.0007-0.76/T ) where η is in Pa s, w is water content in wt.%, P is in MPa and T is in K. The root mean square deviation (rmsd) between the model predictions and the 563 data points used in calibration is 0.39 log units. Experimental constraints have led previously to spurious correlations between P, T, X and η in viscosity data sets, so that predictive models may struggle to correctly resolve the individual effects of P, T and X, and especially their cross-correlations. The increasing water solubility with depth inside a simple isothermal sheet of obsidian suggests that viscosity should decrease by ~1 order of magnitude at ~20m depth and by ~2 orders of magnitude at ~100m depth. If equilibrium water contents are maintained, then deformation in spreading obsidian flows should be strongly partitioned into the deeper parts of the flow. Kinetically inhibited degassing, or recycling of degassed crust into a flow interior (e.g. by caterpillar-tread motion) could lead to strong lateral variations in viscosity within a flow, affecting flow evolution and morphology.

The effects of the variations in sea surface temperature and atmospheric stability in the estimation of average wind speed by SEASAT-SASS

NASA Technical Reports Server (NTRS)

Liu, W. T.

1984-01-01

The average wind speeds from the scatterometer (SASS) on the ocean observing satellite SEASAT are found to be generally higher than the average wind speeds from ship reports. In this study, two factors, sea surface temperature and atmospheric stability, are identified which affect microwave scatter and, therefore, wave development. The problem of relating satellite observations to a fictitious quantity, such as the neutral wind, that has to be derived from in situ observations with models is examined. The study also demonstrates the dependence of SASS winds on sea surface temperature at low wind speeds, possibly due to temperature-dependent factors, such as water viscosity, which affect wave development.

Dependence of the atomic level Green-Kubo stress correlation function on wavevector and frequency: molecular dynamics results from a model liquid.

PubMed

Levashov, V A

2014-09-28

We report on a further investigation of a new method that can be used to address vibrational dynamics and propagation of stress waves in liquids. The method is based on the decomposition of the macroscopic Green-Kubo stress correlation function into the atomic level stress correlation functions. This decomposition, as was demonstrated previously for a model liquid studied in molecular dynamics simulations, reveals the presence of stress waves propagating over large distances and a structure that resembles the pair density function. In this paper, by performing the Fourier transforms of the atomic level stress correlation functions, we elucidate how the lifetimes of the stress waves and the ranges of their propagation depend on their frequency, wavevector, and temperature. These results relate frequency and wavevector dependence of the generalized viscosity to the character of propagation of the shear stress waves. In particular, the results suggest that an increase in the value of the frequency dependent viscosity at low frequencies with decrease of temperature is related to the increase in the ranges of propagation of the stress waves of the corresponding low frequencies. We found that the ranges of propagation of the shear stress waves of frequencies less than half of the Einstein frequency extend well beyond the nearest neighbor shell even above the melting temperature. The results also show that the crossover from quasilocalized to propagating behavior occurs at frequencies usually associated with the Boson peak.

An experimental study on rheological behavior of a nanofluid containing oxide nanoparticle and proposing a new correlation

NASA Astrophysics Data System (ADS)

Saeedi, Amir Hussein; Akbari, Mohammad; Toghraie, Davood

2018-05-01

In this paper, the nanofluid dynamic viscosity composed of CeO2- Ethylene Glycol is examined within 25-50 °C with 5 °C intervals and at six volume fractions (0.05, 0.1, 0.2, 0.4, 0.8 and 1.2%) experimentally. The nanofluid was exposed to ultrasound waves for various durations to study the effect of this parameter on dynamic viscosity of the fluid. We found that at a constant temperature, nanofluid viscosity increases with increases in the volume fraction of the nanoparticles. Also, at a given volume fraction, nanofluid viscosity decreases when temperature is increased. Maximum increase in nanofluid viscosity compared to the base fluid viscosity occurs at 25 °C and volume fraction of 1.2%. It can be inferred that the obtained mathematical relationship is a suitable predicting model for estimating dynamic viscosity of CeO2- Ethylene Glycol (EG) at different volume fractions and temperatures and its results are consistent to laboratory results in the set volume fraction and temperature ranges.

Viscosity of meson matter

NASA Astrophysics Data System (ADS)

Dobado, Antonio; Llanes-Estrada, Felipe J.

2004-06-01

We report a calculation of the shear viscosity in a relativistic multicomponent meson gas as a function of temperature and chemical potentials. We approximately solve the Uehling-Uhlenbeck transport equation of kinetic theory, appropriate for a boson gas, with relativistic kinematics. Since at low temperatures the gas can be taken as mostly composed of pions, with a fraction of kaons and etas, we explore the region where binary elastic collisions with at least one pion are the dominant scattering processes. Our input meson scattering phase shifts are fits to the experimental data obtained from chiral perturbation theory and the inverse amplitude method. Our results take the correct nonrelativistic limit (viscosity proportional to the square root of the temperature), show a viscosity of the order of the cube of the pion mass up to temperatures somewhat below that mass, and then a large increase due to kaons and etas. Our approximation may break down at even higher temperatures, where the viscosity follows a temperature power law with an exponent near 3.

The sensitivity of conduit flow models to basic input parameters: there is no need for magma trolls!

NASA Astrophysics Data System (ADS)

Thomas, M. E.; Neuberg, J. W.

2012-04-01

Many conduit flow models now exist and some of these models are becoming extremely complicated, conducted in three dimensions and incorporating the physics of compressible three phase fluids (magmas), intricate conduit geometries and fragmentation processes, to name but a few examples. These highly specialised models are being used to explain observations of the natural system, and there is a danger that possible explanations may be getting needlessly complex. It is coherent, for instance, to propose the involvement of sub-surface dwelling magma trolls as an explanation for the change in a volcanoes eruptive style, but assuming the simplest explanation would prevent such additions, unless they were absolutely necessary. While the understanding of individual, often small scale conduit processes is increasing rapidly, is this level of detail necessary? How sensitive are these models to small changes in the most basic of governing parameters? Can these changes be used to explain observed behaviour? Here we will examine the sensitivity of conduit flow models to changes in the melt viscosity, one of the fundamental inputs to any such model. However, even addressing this elementary issue is not straight forward. There are several viscosity models in existence, how do they differ? Can models that use different viscosity models be realistically compared? Each of these viscosity models is also heavily dependent on the magma composition and/or temperature, and how well are these variables constrained? Magma temperatures and water contents are often assumed as "ball-park" figures, and are very rarely exactly known for the periods of observation the models are attempting to explain, yet they exhibit a strong controlling factor on the melt viscosity. The role of both these variables will be discussed. For example, using one of the available viscosity models a 20 K decrease in temperature of the melt results in a greater than 100% increase in the melt viscosity. With changes of this magnitude resulting from small alterations in the basic governing parameters does this render any changes in individual conduit processes of secondary importance? As important as the melt viscosity is to any conduit flow model, it is a meaningless parameter unless there is a conduit through which to flow. The shape and size of a volcanic conduit are even less well constrained than magma's temperature and water content, but have an equally important role to play. Rudimentary changes such as simply increasing or decreasing the radius of a perfectly cylindrical conduit can have large effects, and when coupled with the range of magma viscosities that may be flowing through them can completely change interpretations. Although we present results specifically concerning the variables of magma temperature and water content and the radius of a cylindrical conduit, this is just the start, by systematically identifying the effect each parameter has on the conduit flow models it will be possible to identify which areas are most requiring of future attention.

Viscous effects on the Rayleigh-Taylor instability with background temperature gradient

DOE Office of Scientific and Technical Information (OSTI.GOV)

Gerashchenko, Sergiy; Livescu, Daniel

Here we studied the growth rate of the compressible Rayleigh-Taylor instability in the presence of a background temperature gradient, Θ, using a normal mode analysis. The effect of Θ variation is examined for three interface types corresponding to the combinations of the viscous properties of the fluids (inviscid-inviscid, viscous-viscous, and viscous-inviscid) at different Atwood numbers, At, and when at least one of the fluids' viscosity is non-zero, as a function of the Grashof number. For the general case, the resulting ordinary differential equations are solved numerically; however, dispersion relations for the growth rate are presented for several limiting cases. Anmore » analytical solution is found for the inviscid-inviscid interface and the corresponding dispersion equation for the growth rate is obtained in the limit of large Θ. For the viscous-inviscid case, a dispersion relation is derived in the incompressible limit and Θ=0. Compared to Θ=0 case, the role of Θ<0 (hotter light fluid) is destabilizing and becomes stabilizing when Θ>0 (colder light fluid). The most pronounced effect of Θ ≠ 0 is found at low At and/or at large perturbation wavelengths relative to the domain size for all interface types. On the other hand, at small perturbation wavelengths relative to the domain size, the growth rate for the Θ<0 case exceeds the infinite domain incompressible constant density result. The results are applied to two practical examples, using sets of parameters relevant to Inertial Confinement Fusion coasting stage and solar corona plumes. The role of viscosity on the growth rate reduction is discussed together with highlighting the range of wavenumbers most affected by viscosity. The viscous effects further increase in the presence of background temperature gradient, when the viscosity is temperature dependent.« less

Viscous effects on the Rayleigh-Taylor instability with background temperature gradient

DOE PAGES

Gerashchenko, Sergiy; Livescu, Daniel

2016-07-28

Here we studied the growth rate of the compressible Rayleigh-Taylor instability in the presence of a background temperature gradient, Θ, using a normal mode analysis. The effect of Θ variation is examined for three interface types corresponding to the combinations of the viscous properties of the fluids (inviscid-inviscid, viscous-viscous, and viscous-inviscid) at different Atwood numbers, At, and when at least one of the fluids' viscosity is non-zero, as a function of the Grashof number. For the general case, the resulting ordinary differential equations are solved numerically; however, dispersion relations for the growth rate are presented for several limiting cases. Anmore » analytical solution is found for the inviscid-inviscid interface and the corresponding dispersion equation for the growth rate is obtained in the limit of large Θ. For the viscous-inviscid case, a dispersion relation is derived in the incompressible limit and Θ=0. Compared to Θ=0 case, the role of Θ<0 (hotter light fluid) is destabilizing and becomes stabilizing when Θ>0 (colder light fluid). The most pronounced effect of Θ ≠ 0 is found at low At and/or at large perturbation wavelengths relative to the domain size for all interface types. On the other hand, at small perturbation wavelengths relative to the domain size, the growth rate for the Θ<0 case exceeds the infinite domain incompressible constant density result. The results are applied to two practical examples, using sets of parameters relevant to Inertial Confinement Fusion coasting stage and solar corona plumes. The role of viscosity on the growth rate reduction is discussed together with highlighting the range of wavenumbers most affected by viscosity. The viscous effects further increase in the presence of background temperature gradient, when the viscosity is temperature dependent.« less

Thermophysical Properties of Undercooled Alloys: An Overview of the Molecular Simulation Approaches

PubMed Central

Lv, Yong J.; Chen, Min

2011-01-01

We review the studies on the thermophysical properties of undercooled metals and alloys by molecular simulations in recent years. The simulation methods of melting temperature, enthalpy, specific heat, surface tension, diffusion coefficient and viscosity are introduced and the simulated results are summarized. By comparing the experimental results and various theoretical models, the temperature and the composition dependences of the thermophysical properties in undercooled regime are discussed. PMID:21339987

Hall viscosity of a chiral two-orbital superconductor at finite temperatures

NASA Astrophysics Data System (ADS)

Yazdani-Hamid, Meghdad; Shahzamanian, Mohammad Ali

2018-06-01

The Hall viscosity known as the anti-symmetric part of the viscosity fourth-rank tensor. Such dissipationless response which appears for systems with broken time reversal symmetry. We calculate this non-dissipative quantity for a chiral two-orbital superconductor placed in a viscoelastic magnetic field using the linear response theory and apply our calculations to the putative multiband chiral superconductor Sr2RuO4. The chirality origin of a multiband superconductor arises from the interorbital coupling of the superconducting state. This feature leads to the robustness of the Hall viscosity against temperature and impurity effects. We study the temperature effect on the Hall viscosity at the one-loop approximation.

Effect of temperature, viscosity and surface tension on gelatine structures produced by modified 3D printer

NASA Astrophysics Data System (ADS)

Kalkandelen, C.; Ozbek, B.; Ergul, N. M.; Akyol, S.; Moukbil, Y.; Oktar, F. N.; Ekren, N.; Kılıc, O.; Kılıc, B.; Gunduz, O.

2017-12-01

In the present study, gelatine scaffolds were manufactured by using modified 3D (3 Dimensional) printing machine and the effect of different parameters on scaffold structure were investigated. Such as; temperature, viscosity and surface tension of the gelatine solutions. The varying of gelatine solutions (1, 3, 5, 10, 15 and 20 wt.%) were prepared and characterized. It has been detected that, viscosity of those solutions were highly influenced by temperature and gelatine concentration. Specific CAD (Computer Assistant Design) model which has 67% porosity and original design were created via computer software. However, at high temperatures gelatine solutions caused like liquid but at the lower temperatures were observed the opposite behaviour. In addition to that, viscosity of 1,3,5 wt.% solutions were not enough to build a structure and 20 wt.% gelatine solution too hard to handle, because of the sudden viscosity changes with temperature. Even though, scaffold of the 20 wt.% gelatine solution printed hardly but it was observed the best printed solutions, which were 10 and 15 wt.% gelatine solutions. As a result, 3D printing of gelatine were found the values of the best temperature, viscosity, surface tension and gelatine concentration such as 25-35 °C, 36-163 cP, 46-59 mN/m and 15 wt.% gelatine concentration respectively.

ZBLAN Microgravity Study

NASA Technical Reports Server (NTRS)

Workman, Gary L.; Smith, Guy A.; OBrien, Sue; Adcock, Leonard

1995-01-01

One of the greatest obstacles with the fluorozirconate ZBLAN (ZrF4-BaF2-LaF3-AIF3-NaF) is the problem of devitrification. Fluoride glasses have a narrow working range and the viscosity is a strong function of temperature. Rates of nucleation and growth of crystals in the glass depend on the viscosity, making these glasses unstable and prone to crystallization. The viscosity of ZBLAN at the drawing temperature is low, usually between two to five poise, so it is difficult to obtain fibers from their preform melts without crystallization. The preforms usually contain heterogeneous nuclei which grow into microcrystallites above the glass transition temperature, T(g). Since microcrystallites in an optical fiber cause extrinsic light scattering losses of the optical signal, fiber drawing must be completed in a short time to minimize the generation of light scattering centers. To keep these losses to a minimum and to fabricate low scattering loss fibers and other optical components, this research deals with the possibility of minimizing crystallite formation by removing the gravitational influence of solutal segregation of the ZBLAN elements. This report reviews the early work on the KC-135 aircraft, the development of the ZBLAN Rocket Experiment, preparations at the White Sands Missile Range, analysis of the flight and ground test results, lessons learned and future experimentation.

Sealed Gravitational Capillary Viscometry of Dimethyl Ether and Two Next-Generation Alternative Refrigerants

PubMed Central

Cousins, Dylan S.; Laesecke, Arno

2012-01-01

The viscosities of dimethyl ether (DME, C2H6O) and of the fluorinated propene isomers 2,3,3,3-tetrafluoroprop-1-ene (R1234yf, C3H2F4) and trans-1,3,3,3-tetrafluoropropene (R1234ze(E)) were measured in a combined temperature range from 242 K to 350 K at saturated liquid conditions. The instrument was a sealed gravitational capillary viscometer developed at NIST for volatile liquids. Calibration and adjustment of the instrument constant were conducted with n-pentane. The repeatability of the measurements was found to be approximately 1.5 %, leading to a temperature-dependent estimated combined standard uncertainty of the experimental data between 5.7 % at 242 K for dimethyl ether and 2.6 % at 340 K for R1234yf. The measurements were supplemented by ab initio calculations of the molecular size, shape, and charge distributions of the measured compounds. The viscosity results for dimethyl ether were compared with literature data. One other data set measured with a sealed capillary viscometer and exceeding the present results by up to 7 % could be reconciled by applying the vapor buoyancy correction. Then, all data agreed within the estimated uncertainty of the present results. Viscosities for the fluorinated propene isomers deviate up to 4 % from values predicted with the NIST extended corresponding-states model. The viscosities of the two isomers do not scale with their dipole moments. While the measured viscosity of R1234ze(E) with the lower dipole moment is close to that of R134a, the refrigerant to be replaced, that of R1234yf with the higher dipole moment is up to 25 % lower. The viscosity of dimethyl ether is compared with those of water and methanol. PMID:26900526

Thermophysical Properties Measurement of High-Temperature Liquids Under Microgravity Conditions in Controlled Atmospheric Conditions

NASA Technical Reports Server (NTRS)

Watanabe, Masahito; Ozawa, Shumpei; Mizuno, Akotoshi; Hibiya, Taketoshi; Kawauchi, Hiroya; Murai, Kentaro; Takahashi, Suguru

2012-01-01

Microgravity conditions have advantages of measurement of surface tension and viscosity of metallic liquids by the oscillating drop method with an electromagnetic levitation (EML) device. Thus, we are preparing the experiments of thermophysical properties measurements using the Materials-Science Laboratories ElectroMagnetic-Levitator (MSL-EML) facilities in the international Space station (ISS). Recently, it has been identified that dependence of surface tension on oxygen partial pressure (Po2) must be considered for industrial application of surface tension values. Effect of Po2 on surface tension would apparently change viscosity from the damping oscillation model. Therefore, surface tension and viscosity must be measured simultaneously in the same atmospheric conditions. Moreover, effect of the electromagnetic force (EMF) on the surface oscillations must be clarified to obtain the ideal surface oscillation because the EMF works as the external force on the oscillating liquid droplets, so extensive EMF makes apparently the viscosity values large. In our group, using the parabolic flight levitation experimental facilities (PFLEX) the effect of Po2 and external EMF on surface oscillation of levitated liquid droplets was systematically investigated for the precise measurements of surface tension and viscosity of high temperature liquids for future ISS experiments. We performed the observation of surface oscillations of levitated liquid alloys using PFLEX on board flight experiments by Gulfstream II (G-II) airplane operated by DAS. These observations were performed under the controlled Po2 and also under the suitable EMF conditions. In these experiments, we obtained the density, the viscosity and the surface tension values of liquid Cu. From these results, we discuss about as same as reported data, and also obtained the difference of surface oscillations with the change of the EMF conditions.

Effects of Temperature, Oxygen Partial Pressure, and Materials Selection on Slag Infiltration into Porous Refractories for Entrained-Flow Gasifiers

NASA Astrophysics Data System (ADS)

Kaneko, Tetsuya Kenneth

The penetration rate of molten mineral contents (slag) from spent carbonaceous feedstock into porous ceramic-oxide refractory linings is a critical parameter in determining the lifecycle of integrated gasification combined cycle energy production plants. Refractory linings that withstand longer operation without interruption are desirable because they can mitigate consumable and maintenance costs. Although refractory degradation has been extensively studied for many other high-temperature industrial processes, this work focuses on the mechanisms that are unique to entrained-flow gasification systems. The use of unique feedstock mixtures, temperatures from 1450 °C to 1600 °C, and oxygen partial pressures from 10-7 atm to 10-9 atm pose engineering challenges in designing an optimal refractory material. Experimentation, characterization, and modeling show that gasifier slag infiltration into porous refractory is determined by interactions between the slag and the refractory that either form a physical barrier that impedes fluid flow or induce an increased fluid viscosity that decelerates the velocity of the fluid body. The viscosity of the slag is modified by the thermal profile of the refractory along the penetration direction as well as reactions between the slag and refractory that alter the chemistry, and thereby the thermo-physical properties of the fluid. Infiltration experiments reveal that the temperature gradient inherently present along the refractory lining limits penetration. A refractory in near-isothermal conditions demonstrates deeper slag penetration as compared to one that experiences a steeper thermal profile. The decrease in the local temperatures of the slag as it travels deeper into the refractory increases the viscosity of the fluid, which in turn slows the infiltration velocity of fluid body into the pores of the refractory microstructure. With feedstock mixtures that exhibit high iron-oxide concentrations, a transition-metal-oxide, the oxygen partial pressure of the operating atmosphere regulates the penetration of slag into refractory. The viscosity of the slag, which dictates its penetration rate, is influenced by the oxidation state of the Fe cation. Slag penetrations are shallower in oxidizing conditions than they are in reducing conditions because the iron-oxide from the slag solutions into the corundum-structured refractory and the slag is depleted of iron-oxide, increasing the viscosity of slags. Equally, the chemistries of both the refractory and slag materials dictate the course of penetration. Cr2O3-Al2O3 refractory limits mixed feedstock slag penetration through formation of a chromium spinel layer that functions as a physical obstacle against fluid flow. Al2O 3-SiO2 refractory limits eastern coal feedstock slag penetration as a result of refractory dissolution of SiO2, which increases the viscosity of slags. A physical model, which considers unidirectional fluid flow of slag through each pore of the porous microstructure of the refractory, sufficiently approximates the penetration depth of the slag into the refractory. Agreement between experiments and the physical model demonstrates that the slag is driven into the refractory by capillary pressure. Since the viscosity of the slag continuously changes as the slag travels through the inherent temperature gradient of the refractory lining, the model incorporates dynamic viscosities that are dependent on both temperature and composition to project depths that are unique to the experimental parameters. The significantly different length scales of the radial and penetration directions of the pores allows for the application of a lubrication approximation onto the momentum equation. This process produces an analytical solution that effectively envelopes the variable viscosity into a single term.

Describing Temperature-Dependent Self-Diffusion Coefficients and Fluidity of 1- and 3-Alcohols with the Compensated Arrhenius Formalism.

PubMed

Fleshman, Allison M; Forsythe, Grant E; Petrowsky, Matt; Frech, Roger

2016-09-22

The location of the hydroxyl group in monohydroxy alcohols greatly affects the temperature dependence of the liquid structure due to hydrogen bonding. Temperature-dependent self-diffusion coefficients, fluidity (the inverse of viscosity), dielectric constant, and density have been measured for several 1-alcohols and 3-alcohols with varying alkyl chain lengths. The data are modeled using the compensated Arrhenius formalism (CAF). The CAF follows a modified transition state theory using an Arrhenius-like expression to describe the transport property, which consists of a Boltzmann factor containing an energy of activation, Ea, and an exponential prefactor containing the temperature-dependent solution dielectric constant, εs(T). Both 1- and 3-alcohols show the Ea of diffusion coefficients (approximately 43 kJ mol(-1)) is higher than the Ea of fluidity (approximately 35 kJ mol(-1)). The temperature dependence of the exponential prefactor in these associated liquids is explained using the dielectric constant and the Kirkwood-Frölich correlation factor, gk. It is argued that the dielectric constant must be used to account for the additional temperature dependence due to variations in the liquid structure (e.g., hydrogen bonding) for the CAF to accurately model the transport property.

Estimating the Kinematic Viscosity of Petroleum Fractions

NASA Astrophysics Data System (ADS)

AlMulla, Hessa A.; Albahri, Tareq A.

2017-04-01

Kinematic viscosity correlation has been developed for liquid petroleum fractions at 37.78°C and 98.89°C (100 and 210°F) standard temperatures using a large variety of experimental data. The only required inputs are the specific gravity and the average boiling point temperature. The accuracy of the correlation was compared with several other correlations available in the literature. The proposed correlations proved to be more accurate in predicting the viscosity at 37.78°C and 98.89°C with average absolute deviations of 0.39 and 0.72 mm2/s, respectively. Another objective was to develop a relation for the variation of viscosity with temperature to predict the viscosity of petroleum fraction at a certain temperature from the knowledge of the viscosity for the same liquid at two other temperatures. The newly developed correlation represents a wide array of temperatures from 20°C to 150°C and viscosities from 0.14 mm2/s to 343.64 mm2/s. The results have been validated with experimental data consisting of 9558 data points, yielding an overall deviation of 0.248 mm2/s and R2 of 0.998. In addition, new formulas were developed to interconvert the viscosity of petroleum fractions from one unit of measure to another based on finding the best fit for a set of experimental data from the literature with R2 as high as 1.0 for many cases. Detailed analysis showed good agreement between the predicted values and the experimental data.

Explicit expressions of self-diffusion coefficient, shear viscosity, and the Stokes-Einstein relation for binary mixtures of Lennard-Jones liquids

DOE Office of Scientific and Technical Information (OSTI.GOV)

Ohtori, Norikazu, E-mail: ohtori@chem.sc.niigata-u.ac.jp; Ishii, Yoshiki

Explicit expressions of the self-diffusion coefficient, D{sub i}, and shear viscosity, η{sub sv}, are presented for Lennard-Jones (LJ) binary mixtures in the liquid states along the saturated vapor line. The variables necessary for the expressions were derived from dimensional analysis of the properties: atomic mass, number density, packing fraction, temperature, and the size and energy parameters used in the LJ potential. The unknown dependence of the properties on each variable was determined by molecular dynamics (MD) calculations for an equimolar mixture of Ar and Kr at the temperature of 140 K and density of 1676 kg m{sup −3}. The scalingmore » equations obtained by multiplying all the single-variable dependences can well express D{sub i} and η{sub sv} evaluated by the MD simulation for a whole range of compositions and temperatures without any significant coupling between the variables. The equation for D{sub i} can also explain the dual atomic-mass dependence, i.e., the average-mass and the individual-mass dependence; the latter accounts for the “isotope effect” on D{sub i}. The Stokes-Einstein (SE) relation obtained from these equations is fully consistent with the SE relation for pure LJ liquids and that for infinitely dilute solutions. The main differences from the original SE relation are the presence of dependence on the individual mass and on the individual energy parameter. In addition, the packing-fraction dependence turned out to bridge another gap between the present and original SE relations as well as unifying the SE relation between pure liquids and infinitely dilute solutions.« less

Factors affecting the viscosity of sodium hypochlorite and their effect on irrigant flow.

PubMed

Bukiet, F; Soler, T; Guivarch, M; Camps, J; Tassery, H; Cuisinier, F; Candoni, N

2013-10-01

To assess the influence of concentration, temperature and surfactant addition to a sodium hypochlorite solution on its dynamic viscosity and to calculate the corresponding Reynolds number to determine the corresponding flow regimen. The dynamic viscosity of the irrigant was assessed using a rotational viscometer. Sodium hypochlorite with concentrations ranging from 0.6% to 9.6% was tested at 37 and 22 °C. A wide range of concentrations of three different surfactants was mixed in 2.4% sodium hypochlorite for viscosity measurements. The Reynolds number was calculated under each condition. Data were analysed using two-way anova. There was a significant influence of sodium hypochlorite concentration (P < 0.001) and temperature (P < 0.001) on dynamic viscosity: the latter significantly increased with sodium hypochlorite concentration and decreased with temperature. A significant influence of surfactant concentration on dynamic viscosity (P < 0.001) occurred, especially for high surfactant concentrations: 6.25% for benzalkonium chloride, 15% for Tween 80 and 6.25% for Triton X-100. Reynolds number values calculated for a given flow rate (0.14 mL s(-1)), and root canal diameter (sizes 45 and 70) clearly qualified the irrigant flow regimen as laminar. Dynamic viscosity increased with sodium hypochlorite and surfactant concentration but decreased with temperature. Under clinical conditions, all viscosities measured led to laminar flow. The transition between laminar and turbulent flow may be reached by modifying different parameters at the same time: increasing flow rate and temperature whilst decreasing irrigant viscosity by adding surfactants with a high value of critical micellar concentration. © 2013 International Endodontic Journal. Published by John Wiley & Sons Ltd.

Sequence and Temperature Dependence of the End-to-End Collision Dynamics of Single-Stranded DNA

PubMed Central

Uzawa, Takanori; Isoshima, Takashi; Ito, Yoshihiro; Ishimori, Koichiro; Makarov, Dmitrii E.; Plaxco, Kevin W.

2013-01-01

Intramolecular collision dynamics play an essential role in biomolecular folding and function and, increasingly, in the performance of biomimetic technologies. To date, however, the quantitative studies of dynamics of single-stranded nucleic acids have been limited. Thus motivated, here we investigate the sequence composition, chain-length, viscosity, and temperature dependencies of the end-to-end collision dynamics of single-stranded DNAs. We find that both the absolute collision rate and the temperature dependencies of these dynamics are base-composition dependent, suggesting that base stacking interactions are a significant contributor. For example, whereas the end-to-end collision dynamics of poly-thymine exhibit simple, linear Arrhenius behavior, the behavior of longer poly-adenine constructs is more complicated. Specifically, 20- and 25-adenine constructs exhibit biphasic temperature dependencies, with their temperature dependences becoming effectively indistinguishable from that of poly-thymine above 335 K for 20-adenines and 328 K for 25-adenines. The differing Arrhenius behaviors of poly-thymine and poly-adenine and the chain-length dependence of the temperature at which poly-adenine crosses over to behave like poly-thymine can be explained by a barrier friction mechanism in which, at low temperatures, the energy barrier for the local rearrangement of poly-adenine becomes the dominant contributor to its end-to-end collision dynamics. PMID:23746521

Internal friction controls the speed of protein folding from a compact configuration.

PubMed

Pabit, Suzette A; Roder, Heinrich; Hagen, Stephen J

2004-10-05

Several studies have found millisecond protein folding reactions to be controlled by the viscosity of the solvent: Reducing the viscosity allows folding to accelerate. In the limit of very low solvent viscosity, however, one expects a different behavior. Internal interactions, occurring within the solvent-excluded interior of a compact molecule, should impose a solvent-independent upper limit to folding speed once the bulk diffusional motions become sufficiently rapid. Why has this not been observed? We have studied the effect of solvent viscosity on the folding of cytochrome c from a highly compact, late-stage intermediate configuration. Although the folding rate accelerates as the viscosity declines, it tends toward a finite limiting value approximately 10(5) s(-1) as the viscosity tends toward zero. This limiting rate is independent of the cosolutes used to adjust solvent friction. Therefore, interactions within the interior of a compact denatured polypeptide can limit the folding rate, but the limiting time scale is very fast. It is only observable when the solvent-controlled stages of folding are exceedingly rapid or else absent. Interestingly, we find a very strong temperature dependence in these "internal friction"-controlled dynamics, indicating a large energy scale for the interactions that govern reconfiguration within compact, near-native states of a protein.

Effect of ethanol, dry extract and reducing sugars on density and viscosity of Brazilian red wines.

PubMed

Neto, Flávia S P P; de Castilhos, Maurício B M; Telis, Vânia R N; Telis-Romero, Javier

2015-05-01

Density and viscosity are properties that exert great influence on the body of wines. The present work aimed to evaluate the influence of the alcoholic content, dry extract, and reducing sugar content on density and viscosity of commercial dry red wines at different temperatures. The rheological assays were carried out on a controlled stress rheometer, using concentric cylinder geometry at seven temperatures (2, 8, 14, 16, 18, 20 and 26 °C). Wine viscosity decreased with increasing temperature and density was directly related to the wine alcohol content, whereas viscosity was closely linked to the dry extract. Reducing sugars did not influence viscosity or density. Wines produced from Italian grapes were presented as full-bodied with higher values for density and viscosity, which was linked to the higher alcohol content and dry extract, respectively. The results highlighted the major effects of certain physicochemical properties on the physical properties of wines, which in turn is important for guiding sensory assessments. © 2014 Society of Chemical Industry.

KELVIN-HELMHOLTZ INSTABILITIES AT THE SLOSHING COLD FRONTS IN THE VIRGO CLUSTER AS A MEASURE FOR THE EFFECTIVE INTRACLUSTER MEDIUM VISCOSITY

DOE Office of Scientific and Technical Information (OSTI.GOV)

Roediger, E.; Kraft, R. P.; Forman, W. R.

2013-02-10

Sloshing cold fronts (CFs) arise from minor merger triggered gas sloshing. Their detailed structure depends on the properties of the intracluster medium (ICM): hydrodynamical simulations predict the CFs to be distorted by Kelvin-Helmholtz instabilities (KHIs), but aligned magnetic fields, viscosity, or thermal conduction can suppress the KHIs. Thus, observing the detailed structure of sloshing CFs can be used to constrain these ICM properties. Both smooth and distorted sloshing CFs have been observed, indicating that the KHI is suppressed in some clusters, but not in all. Consequently, we need to address at least some sloshing clusters individually before drawing general conclusionsmore » about the ICM properties. We present the first detailed attempt to constrain the ICM properties in a specific cluster from the structure of its sloshing CF. Proximity and brightness make the Virgo Cluster an ideal target. We combine observations and Virgo-specific hydrodynamical sloshing simulations. Here, we focus on a Spitzer-like temperature-dependent viscosity as a mechanism to suppress the KHI, but discuss the alternative mechanisms in detail. We identify the CF at 90 kpc north and northeast of the Virgo center as the best location in the cluster to observe a possible KHI suppression. For viscosities {approx}> 10% of the Spitzer value KHIs at this CF are suppressed. We describe in detail the observable signatures at low and high viscosities, i.e., in the presence or the absence of KHIs. We find indications for a low ICM viscosity in archival XMM-Newton data and demonstrate the detectability of the predicted features in deep Chandra observations.« less

Diffusivity Measurements of Volatile Organics in Levitated Viscous Aerosol Particles

NASA Astrophysics Data System (ADS)

Bastelberger, Sandra; Krieger, Ulrich; Luo, Beiping; Peter, Thomas

2017-04-01

Field measurements indicating that atmospheric secondary aerosol (SOA) particles can be present in a highly viscous, glassy state have spurred numerous studies addressing low water diffusivities in glassy aerosols, focusing on kinetic limitations to hygroscopic growth and the plasticizing effect of water. Less is known about diffusion limitations of organic molecules and oxidants in viscous matrices and how these might affect atmospheric chemistry and gas-particle phase partitioning of complex mixtures with constituents of different volatility. Often viscosity data has been used to infer diffusivity via the Stokes- Einstein relationship even though strong deviations from this relationship have been observed for matrices of high viscosity. In this study, we provide a quantitative estimate for the diffusivity of a volatile organic in a viscous matrix. Evaporation of single particles generated from an aqueous solution of sucrose and a small quantity of volatile tetraethylene glycol (PEG-4) is investigated in an electrodynamic balance at controlled relative humidity (RH) and temperature conditions, thereby varying the viscosity of the sucrose matrix. The evaporative loss of tetraethylene glycol as determined by Mie resonance spectroscopy is used in conjunction with a diffusion model to retrieve translational diffusion coefficients of tetraethylene glycol. The evaporation of PEG-4 shows a pronounced RH and temperature dependence and is severely depressed for RH 30% corresponding to diffusivities < 10-14 cm2/s at temperatures as high as 15 °C, implying that atmospheric volatile organic compounds (VOC) can be subject to severe diffusion limitations in glassy SOA. Comparison of the experimentally derived diffusivities with viscosity estimates for the ternary system reveals a breakdown of the Stokes-Einstein relationship.

Surface acetylation of bamboo cellulose: preparation and rheological properties.

PubMed

Cai, Jie; Fei, Peng; Xiong, Zhouyi; Shi, Yongjun; Yan, Kai; Xiong, Hanguo

2013-01-30

In this study, purified bamboo cellulose was used to synthesize cellulose diacetate (B-CDA). The synthesis was controlled by determination of the degree of substitution and insoluble residue content. The product then was characterized by FTIR. The rheological properties of B-CDA solutions in acetone/N,N-dimethylacetamide (DMAc) solvent system were systematically investigated on an advanced rheometer, including the dependence of apparent viscosity η(α), non-Newtonian index n, and structural viscosity index Δη on the concentration and temperature of the solutions. B-CDA-acetone/DMAc solution is a shear-thinning fluid. With increasing solution concentration and decreasing temperature, Δη increased, whereas n decreased, which indicates a deteriorating spinnability. Moreover, the values of the viscous flow activation energy E(η) based on the Arrhenius equation increased when the shear rate γ was enhanced, which indicates that the η(α) of the solution is more sensitive to temperature in the higher γ values. The results are favorable for predicting the B-CDA solution spinnability. Copyright © 2012 Elsevier Ltd. All rights reserved.

Pulsating gliding transition in the dynamics of levitating liquid nitrogen droplets

NASA Astrophysics Data System (ADS)

Snezhko, Alexey; Ben Jacob, Eshel; Aranson, Igor S.

2008-04-01

Hot surfaces can cause levitation of small liquid droplets if the temperature is kept above the Leidenfrost point (220 °C for water) due to the pressure formed because of rapid evaporation. Here, we demonstrate a new class of pulsating-gliding dynamic transitions in a special setting of the Leidenfrost effect at room temperatures and above a viscous fluid for droplets of liquid nitrogen. A whole range of highly dynamic patterns unfolds when droplets of liquid nitrogen are poured on the surface of another, more viscous liquid at room temperature. We also discovered that the levitating droplets induce vortex motion in the supporting viscous liquid. Depending on the viscosity of the supporting liquid, the nitrogen droplets either adopt an oscillating (pulsating) star-like shape with different azimuthal symmetries (from 2-9 petals) or glide on the surface with random trajectories. Thus, by varying the viscosity of the supporting liquid, we achieve controlled morphology and dynamics of Leidenfrost droplets.

High-Temperature Viscosity Of Commercial Glasses

DOE Office of Scientific and Technical Information (OSTI.GOV)

Hrma, Pavel R; See, Clem A; Lam, Oanh P

2005-01-01

Viscosity was measured for six types of commercial glasses: low-expansion-borosilicate glasses, E glasses, fiberglass wool glasses, TV panel glasses, container glasses, and float glasses. Viscosity data were obtained with rotating spindle viscometers within the temperature range between 900°C and 1550°C; the viscosity varied from 1 Pa∙s to 750 Pa∙s. Arrhenius coefficients were calculated for individual glasses and linear models were applied to relate them to the mass fractions of 11 major components (SiO2, CaO, Na2O, Al2O3, B2O3, BaO, SrO, K2O, MgO, PbO, and ZrO2) and 12 minor components (Fe2O3, ZnO, Li2O, TiO2, CeO2, F, Sb2O3, Cr2O3, As2O3, MnO2, SO3, andmore » Co3O4). The models are recommended for glasses containing 42 to 84 mass% SiO2 to estimate viscosities or temperatures at a constant viscosity for melts within both the temperature range from 1100°C to 1550°C and viscosity range from 10 to 400 Pas.« less

Nanofluids Containing γ-Fe2O3 Nanoparticles and Their Heat Transfer Enhancements

NASA Astrophysics Data System (ADS)

Guo, Shou-Zhu; Li, Yang; Jiang, Ji-Sen; Xie, Hua-Qing

2010-07-01

Homogeneous and stable magnetic nanofluids containing γ-Fe2O3 nanoparticles were prepared using a two-step method, and their thermal transport properties were investigated. Thermal conductivities of the nanofluids were measured to be higher than that of base fluid, and the enhanced values increase with the volume fraction of the nanoparticles. Viscosity measurements showed that the nanofluids demonstrated Newtonian behavior and the viscosity of the nanofluids depended strongly on the tested temperatures and the nanoparticles loadings. Convective heat transfer coefficients tested in a laminar flow showed that the coefficients increased with the augment of Reynolds number and the volume fraction.

Effects of bulk viscosity and hadronic rescattering in heavy ion collisions at energies available at the BNL Relativistic Heavy Ion Collider and at the CERN Large Hadron Collider

NASA Astrophysics Data System (ADS)

Ryu, Sangwook; Paquet, Jean-François; Shen, Chun; Denicol, Gabriel; Schenke, Björn; Jeon, Sangyong; Gale, Charles

2018-03-01

We describe ultrarelativistic heavy ion collisions at the BNL Relativistic Heavy Ion Collider and the CERN Large Hadron Collider with a hybrid model using the IP-Glasma model for the earliest stage and viscous hydrodynamics and microscopic transport for the later stages of the collision. We demonstrate that within this framework the bulk viscosity of the plasma plays an important role in describing the experimentally observed radial flow and azimuthal anisotropy simultaneously. We further investigate the dependence of observables on the temperature below which we employ the microscopic transport description.

Transport properties of nonelectrolyte mixtures. IX. Viscosity coefficients for acetonitrile and for three mixtures of toluene+acetonitrile from 25 to 100°c at pressures up to 500 MPa

NASA Astrophysics Data System (ADS)

Dymond, J. H.; Awan, M. A.; Glen, N. F.; Isdale, J. D.

1991-05-01

A two-coil self-centering falling-body viscometer has been used to measure viscosity coefficients for acetonitrile and three binary mixtures of toluene+ acetonitrile at 25, 50, 75, and 100°C and pressures up to 500 MPa. The results for acetonitrile can be interpreted by an approach based on hard-sphere theory, with a roughness factor of 1.46. The binary-mixture data are well represented by the Grunberg and Nissan equation with a mixing parameter which is pressure and temperature dependent but composition independent.

Nearly Perfect Fluidity in a High Temperature Superconductor

DOE PAGES

Rameau, J. D.; Reber, T. J.; Yang, H. -B.; ...

2014-10-13

Perfect fluids are characterized as having the smallest ratio of shear viscosity to entropy density, η/s, consistent with quantum uncertainty and causality. So far, nearly perfect fluids have only been observed in the quark-gluon plasma and in unitary atomic Fermi gases, exotic systems that are amongst the hottest and coldest objects in the known universe, respectively. We use angle resolved photoemission spectroscopy to measure the temperature dependence of an electronic analog of η/s in an optimally doped cuprate high-temperature superconductor, finding it too is a nearly perfect fluid around, and above, its superconducting transition temperature T c.

Nearly perfect fluidity in a high-temperature superconductor

NASA Astrophysics Data System (ADS)

Rameau, J. D.; Reber, T. J.; Yang, H.-B.; Akhanjee, S.; Gu, G. D.; Johnson, P. D.; Campbell, S.

2014-10-01

Perfect fluids are characterized as having the smallest ratio of shear viscosity to entropy density, η /s, consistent with quantum uncertainty and causality. So far, nearly perfect fluids have only been observed in the quark-gluon plasma and in unitary atomic Fermi gases, exotic systems that are amongst the hottest and coldest objects in the known universe, respectively. We use angle resolved photoemission spectroscopy to measure the temperature dependence of an electronic analog of η /s in an optimally doped cuprate high-temperature superconductor, finding it too is a nearly perfect fluid around, and above, its superconducting transition temperature Tc.

How the dispersion of magnesium oxide nanoparticles effects on the viscosity of water-ethylene glycol mixture: Experimental evaluation and correlation development

NASA Astrophysics Data System (ADS)

Afrand, Masoud; Abedini, Ehsan; Teimouri, Hamid

2017-03-01

In this paper, the effect of dispersion of magnesium oxide nanoparticles on viscosity of a mixture of water and ethylene glycol (50-50% vol.) was examined experimentally. Experiments were performed for various nanofluid samples at different temperatures and shear rates. Measurements revealed that the nanofluid samples with volume fractions of less than 1.5% had Newtonian behavior, while the sample with volume fraction of 3% showed non-Newtonian behavior. Results showed that the viscosity of nanofluids enhanced with increasing nanoparticles volume fraction and decreasing temperature. Results of sensitivity analysis revealed that the viscosity sensitivity of nanofluid samples to temperature at higher volume fractions is more than that of at lower volume fractions. Finally, because of the inability of the existing model to predict the viscosity of MgO/EG-water nanofluid, an experimental correlation has been proposed for predicting the viscosity of the nanofluid.

Fiber-optic epoxy composite cure sensor. I. Dependence of refractive index of an autocatalytic reaction epoxy system at 850 nm on temperature and extent of cure

NASA Astrophysics Data System (ADS)

Lam, Kai-Yuen; Afromowitz, Martin A.

1995-09-01

We discuss the behavior of the refractive index of a typical epoxy-aromatic diamine system. Near 850 nm the index of refraction is found to be largely controlled by the density of the epoxy. Models are derived to describe its dependence on temperature and extent of cure. Within the range of temperatures studied, the refractive index decreases linearly with increasing temperature. In addition, as the epoxy is cured, the refractive index increases linearly with conversion to the gel point. >From then on, shrinkage in the volume of the epoxy is restricted by local viscosity. Therefore the linear relationship between the refractive index and the extent of cure does not hold beyond the gel point.

An investigation into the injection molding of PMR-15 polyimide

NASA Technical Reports Server (NTRS)

Colaluca, M. A.

1984-01-01

The chemorheological behavior of the PRM-15 molding compounds were characterized, the range of suitable processing parameters for injection molding in a reciprocating screw injection molding machine was determined, and the effects of the injection molding processing parameters on the mechanical properties of molded PMR-15 parts were studied. The apparatus and procedures for measuring viscosity and for determining the physical response of the material during heating are described. Results show that capillary rheometry can be effectively used with thermosets if the equipment is designed to overcome some of the inherent problems of these materials. A uniform temperature was provided in the barrel by using a circulating hot oil system. Standard capillary rheometry methods can provide the dependence of thermoset apparent viscosity on shear rate, temperature, and time. Process conditions resulting in complete imidization should be carefully defined. Specification of controlled oven temperature is inadequate and can result in incomplete imidization. For completely imidized PMR-15 heat at 15 C/min melt flow without gas evolution occurs in the temperature range of 325 C to 400 C.

Melting in super-earths.

PubMed

Stixrude, Lars

2014-04-28

We examine the possible extent of melting in rock-iron super-earths, focusing on those in the habitable zone. We consider the energetics of accretion and core formation, the timescale of cooling and its dependence on viscosity and partial melting, thermal regulation via the temperature dependence of viscosity, and the melting curves of rock and iron components at the ultra-high pressures characteristic of super-earths. We find that the efficiency of kinetic energy deposition during accretion increases with planetary mass; considering the likely role of giant impacts and core formation, we find that super-earths probably complete their accretionary phase in an entirely molten state. Considerations of thermal regulation lead us to propose model temperature profiles of super-earths that are controlled by silicate melting. We estimate melting curves of iron and rock components up to the extreme pressures characteristic of super-earth interiors based on existing experimental and ab initio results and scaling laws. We construct super-earth thermal models by solving the equations of mass conservation and hydrostatic equilibrium, together with equations of state of rock and iron components. We set the potential temperature at the core-mantle boundary and at the surface to the local silicate melting temperature. We find that ancient (∼4 Gyr) super-earths may be partially molten at the top and bottom of their mantles, and that mantle convection is sufficiently vigorous to sustain dynamo action over the whole range of super-earth masses.

Measurement of the temperature-dependent threshold shear-stress of red blood cell aggregation.

PubMed

Lim, Hyun-Jung; Nam, Jeong-Hun; Lee, Yong-Jin; Shin, Sehyun

2009-09-01

Red blood cell (RBC) aggregation is becoming an important hemorheological parameter, which typically exhibits temperature dependence. Quite recently, a critical shear-stress was proposed as a new dimensional index to represent the aggregative and disaggregative behaviors of RBCs. The present study investigated the effect of the temperature on the critical shear-stress that is required to keep RBC aggregates dispersed. The critical shear-stress was measured at various temperatures (4, 10, 20, 30, and 37 degrees C) through the use of a transient microfluidic aggregometry. The critical shear-stress significantly increased as the blood temperature lowered, which accorded with the increase in the low-shear blood viscosity with the lowering of the temperature. Furthermore, the critical shear-stress also showed good agreement with the threshold shear-stress, as measured in a rotational Couette flow. These findings assist in rheologically validating the critical shear-stress, as defined in the microfluidic aggregometry.

Temperature dependence of optically induced cell deformations

NASA Astrophysics Data System (ADS)

Fritsch, Anatol; Kiessling, Tobias R.; Stange, Roland; Kaes, Josef A.

2012-02-01

The mechanical properties of any material change with temperature, hence this must be true for cellular material. In biology many functions are known to undergo modulations with temperature, like myosin motor activity, mechanical properties of actin filament solutions, CO2 uptake of cultured cells or sex determination of several species. As mechanical properties of living cells are considered to play an important role in many cell functions it is surprising that only little is known on how the rheology of single cells is affected by temperature. We report the systematic temperature dependence of single cell deformations in Optical Stretcher (OS) measurements. The temperature is changed on a scale of about 20 minutes up to hours and compared to defined temperature shocks in the range of milliseconds. Thereby, a strong temperature dependence of the mechanics of single suspended cells is revealed. We conclude that the observable differences arise rather from viscosity changes of the cytosol than from structural changes of the cytoskeleton. These findings have implications for the interpretation of many rheological measurements, especially for laser based approaches in biological studies.

Temperature Effect on Rheological Behavior of Silicone Oils. A Model for the Viscous Heating.

PubMed

Romano, Mario R; Cuomo, Francesca; Massarotti, Nicola; Mauro, Alessandro; Salahudeen, Mohamed; Costagliola, Ciro; Ambrosone, Luigi

2017-07-27

The rheological behavior of silicone oils, (CH 3 ) 3 SiO-[Si(CH 3 ) 2 O] n -Si(CH 3 ) 3 , and their mixtures is studied. Shear-stress measurements, in the temperature range of 293-313 K, reveal that this polymer family is a group of shear-thinning liquids with a yield stress below which no flow occurs. Experimental diagrams, i.e., shear stress versus shear rate, are satisfactorily described by the Casson fluid model over a wide range of shear rates. In order to monitor the effect of temperature on fluid properties, Casson's rheological model is reformulated using the fictitious shear rate, γ̇ f , and the infinite-shear viscosity, η ∞ , as constitutive parameters. Due to low intermolecular forces and high chain flexibility, γ̇ f varies very little when the temperature increases. For this reason, the apparent material viscosity depends on temperature only through η ∞ , which exponentially decreases until high shear rates are reached, and there is more alignment possible. Interestingly, the temperature sensitivity of this pseudoplastic behavior is the same for all of the silicone oils investigated; therefore, they can be classified according to their tendency to emulsify. Experimental results are then used to model the flow of silicone oils in a cylindrical pipe and estimate the temperature increase due to viscous heating. Numerical results show that the normalized temperature, i.e., ratio of fluid temperature to wall temperature, increases approximately 23%, and the apparent viscosity decreases drastically, going toward the center of the tube. The non-Newtonian nature of fluid is reflected in the presence of a critical region. In this region, the velocity and temperature gradients vanish. Since silicon oil is a surgical tool, we hope that the acquired physicochemical information can provide help to facilitate the removal of this material during surgical procedures.

Influence of Surrounding Dielectrics on the Data Retention Time of Doped Sb2Te Phase Change Material

NASA Astrophysics Data System (ADS)

Jedema, Friso; in `t Zandt, Micha; Wolters, Rob; Gravesteijn, Dirk

2011-02-01

The crystallization properties of as-deposited and laser written amorphous marks of doped Sb2Te phase change material are found to be only dependent on the top dielectric layer. A ZnS:SiO2 top dielectric layer yields a higher crystallization temperature and a larger crystal growth activation energy as compared to a SiO2 top dielectric layer, leading to superior data retention times at ambient temperatures. The observed correlation between the larger crystallization temperatures and larger crystal growth activation energies indicates that the viscosity of the phase change material in the amorphous state is dependent on the interfacial energy between the phase change material and the top dielectric layer.

Application of the compensated Arrhenius formalism to fluidity data of polar organic liquids.

PubMed

Petrowsky, Matt; Fleshman, Allison M; Frech, Roger

2013-03-14

The temperature dependence of viscosity (the reciprocal of fluidity) in polar liquids has been studied for over a century, but the available theoretical models have serious limitations. Consequently, the viscosity is often described with empirical equations using adjustable fitting parameters that offer no insight into the molecular mechanism of transport. We have previously reported a novel approach called the compensated Arrhenius formalism (CAF) to describe ionic conductivity, self-diffusion, and dielectric relaxation in terms of molecular and system properties. Here the CAF is applied to fluidity data of pure n-acetates, 2-ketones, n-nitriles, and n-alcohols over the temperature range 5-85 °C. The fluidity is represented as an Arrhenius-like expression that includes a static dielectric constant dependence in the exponential prefactor. The dielectric constant dependence results from the dependence of mass and charge transport on the molecular dipole moment and the solvent dipole density. The CAF is the only self-consistent description of fluid transport in polar liquids written solely in terms of molecular and system parameters. A scaling procedure is used to calculate the activation energy for transport. We find that the activation energies for fluidity of the aprotic liquids are comparable in value, whereas a higher average E(a) value is observed for the n-alcohol data. Finally, we contrast the molecular description of transport presented here with the conventional hydrodynamic model.

Hydrodynamical Modeling of Large Circumstellar Disks

NASA Astrophysics Data System (ADS)

Kurfürst, P.; Krtǐcka, J.

2016-11-01

Direct centrifugal ejection from a critically or near-critically rotating surface forms a gaseous equatorial decretion disk. Anomalous viscosity provides the efficient mechanism for transporting the angular momentum outwards. The outer part of the disk can extend up to a very large distance from the parent star. We study the evolution of density, radial and azimuthal velocity, and angular momentum loss rate of equatorial decretion disks out to very distant regions. We investigate how the physical characteristics of the disk depend on the distribution of temperature and viscosity. We also study the magnetorotational instability, which is considered to be the origin of anomalous viscosity in outflowing disks. We use analytical calculations to study the stability of outflowing disks submerged to the magnetic field. At large radii the instability disappears in the region where the disk orbital velocity is roughly equal to the sound speed. Therefore, the disk sonic radius can be roughly considered as an outer disk radius.

Stokes-Einstein relation and excess entropy in Al-rich Al-Cu melts

NASA Astrophysics Data System (ADS)

Pasturel, A.; Jakse, N.

2016-07-01

We investigate the conditions for the validity of the Stokes-Einstein relation that connects diffusivity to viscosity in melts using entropy-scaling relationships developed by Rosenfeld. Employing ab initio molecular dynamics simulations to determine transport and structural properties of liquid Al1-xCux alloys (with composition x ≤ 0.4), we first show that reduced self-diffusion coefficients and viscosities, according to Rosenfeld's formulation, scale with the two-body approximation of the excess entropy except the reduced viscosity for x = 0.4. Then, we use our findings to evidence that the Stokes-Einstein relation using effective atomic radii is not valid in these alloys while its validity can be related to the temperature dependence of the partial pair-excess entropies of both components. Finally, we derive a relation between the ratio of the self-diffusivities of the components and the ratio of their pair excess entropies.

Kinematic dust viscosity effect on linear and nonlinear dust-acoustic waves in space dusty plasmas with nonthermal ions

DOE Office of Scientific and Technical Information (OSTI.GOV)

El-Hanbaly, A. M.; Sallah, M., E-mail: msallahd@mans.edu.eg; El-Shewy, E. K.

2015-10-15

Linear and nonlinear dust-acoustic (DA) waves are studied in a collisionless, unmagnetized and dissipative dusty plasma consisting of negatively charged dust grains, Boltzmann-distributed electrons, and nonthermal ions. The normal mode analysis is used to obtain a linear dispersion relation illustrating the dependence of the wave damping rate on the carrier wave number, the dust viscosity coefficient, the ratio of the ion temperature to the electron temperatures, and the nonthermal parameter. The plasma system is analyzed nonlinearly via the reductive perturbation method that gives the KdV-Burgers equation. Some interesting physical solutions are obtained to study the nonlinear waves. These solutions aremore » related to soliton, a combination between a shock and a soliton, and monotonic and oscillatory shock waves. Their behaviors are illustrated and shown graphically. The characteristics of the DA solitary and shock waves are significantly modified by the presence of nonthermal (fast) ions, the ratio of the ion temperature to the electron temperature, and the dust kinematic viscosity. The topology of the phase portrait and the potential diagram of the KdV-Burgers equation is illustrated, whose advantage is the ability to predict different classes of traveling wave solutions according to different phase orbits. The energy of the soliton wave and the electric field are calculated. The results in this paper can be generalized to analyze the nature of plasma waves in both space and laboratory plasma systems.« less

Oceanic lithosphere and asthenosphere: The thermal and mechanical structure

NASA Technical Reports Server (NTRS)

Schubert, G.; Froidevaux, C.; Yuen, D. A.

1976-01-01

A coupled thermal and mechanical solid state model of the oceanic lithosphere and asthenosphere is presented. The model includes vertical conduction of heat with a temperature dependent thermal conductivity, horizontal and vertical advection of heat, viscous dissipation or shear heating, and linear or nonlinear deformation mechanisms with temperature and pressure dependent constitutive relations between shear stress and strain rate. A constant horizontal velocity u sub 0 and temperature t sub 0 at the surface and zero horizontal velocity and constant temperature t sub infinity at great depth are required. In addition to numerical values of the thermal and mechanical properties of the medium, only the values of u sub 0, t sub 0 and t sub infinity are specified. The model determines the depth and age dependent temperature horizontal and vertical velocity, and viscosity structures of the lithosphere and asthenosphere. In particular, ocean floor topography, oceanic heat flow, and lithosphere thickness are deduced as functions of the age of the ocean floor.

Modelling of a Convecting, Crystallizing, and Replenished Diopside-Anorthite Axial Magma Chamber beneath Mid Ocean Ridges

NASA Astrophysics Data System (ADS)

Lowell, R. P.; Lata, C.

2016-12-01

The aim of this work is to model heat output from a cooling, convective, crystallizing, and replenished basaltic magma sill, representing an axial magma lens (AML) at mid oceanic ridges. As a simplified version of basaltic melt, we have assumed the melt to be a two-component eutectic system composed of diopside and anorthite. Convective vigor is expressed through the Rayleigh number and heat flux is scaled through a classical relationship between the Rayleigh number and Nusselt number, where the temperature difference driving the convective heat flux is derived from a "viscous" temperature scale reflecting the strong temperature dependent viscosity of the system. Viscosity is modeled as a function of melt composition and temperature using the Tammann-Vogel-Fulcher equation, with parameters fit to the values of observed viscosities along the diopside-anorthite liquidus. It was observed for the un-replenished case, in which crystals fall rapidly to the floor of the AML, model results show that the higher initial concentration of diopside, the more vigorous the convection and the faster the rate of crystallization and decay of heat output. Replenishment of the AML accompanied by modest thickening of the melt layer stabilizes the heat output at values similar to those observed at ridge-axis hydrothermal systems. This study is an important step forward in quantitative understanding of thermal evolution of the axial magma lens at a mid-ocean ridge and the corresponding effect on high-temperature hydrothermal systems. Future work could involve improved replenishment mechanisms, more complex melts, and direct coupling with hydrothermal circulation models.

Molecular basis of high viscosity in concentrated antibody solutions: Strategies for high concentration drug product development.

PubMed

Tomar, Dheeraj S; Kumar, Sandeep; Singh, Satish K; Goswami, Sumit; Li, Li

2016-01-01

Effective translation of breakthrough discoveries into innovative products in the clinic requires proactive mitigation or elimination of several drug development challenges. These challenges can vary depending upon the type of drug molecule. In the case of therapeutic antibody candidates, a commonly encountered challenge is high viscosity of the concentrated antibody solutions. Concentration-dependent viscosity behaviors of mAbs and other biologic entities may depend on pairwise and higher-order intermolecular interactions, non-native aggregation, and concentration-dependent fluctuations of various antibody regions. This article reviews our current understanding of molecular origins of viscosity behaviors of antibody solutions. We discuss general strategies and guidelines to select low viscosity candidates or optimize lead candidates for lower viscosity at early drug discovery stages. Moreover, strategies for formulation optimization and excipient design are also presented for candidates already in advanced product development stages. Potential future directions for research in this field are also explored.

Correlation range in a supercooled liquid via Green-Kubo expression for viscosity, local atomic stresses, and MD simulations

NASA Astrophysics Data System (ADS)

Levashov, Valentin A.; Egami, Takeshi; Morris, James R.

2009-03-01

We present a new approach to the issue of correlation range in supercooled liquids based on Green-Kubo expression for viscosity. The integrand of this expression is the average stress-stress autocorrelation function. This correlation function could be rewritten in terms of correlations among local atomic stresses at different times and distances. The features of the autocorrelation function decay with time depend on temperature and correlation range. Through this approach we can study the development of spatial correlation with time, thus directly addressing the question of dynamic heterogeneity. We performed MD simulations on a single component system of particles interacting through short range pair potential. Our results indicate that even above the crossover temperature correlations extend well beyond the nearest neighbors. Surprisingly we found that the system size effects exist even on relatively large systems. We also address the role of diffusion in decay of stress-stress correlation function.

DOE Office of Scientific and Technical Information (OSTI.GOV)

Kim, Sun Ung, E-mail: sunung@umich.edu; Monroe, Charles W., E-mail: cwmonroe@umich.edu

The inverse problem of parameterizing intermolecular potentials given macroscopic transport and thermodynamic data is addressed. Procedures are developed to create arbitrary-precision algorithms for transport collision integrals, using the Lennard-Jones (12–6) potential as an example. Interpolation formulas are produced that compute these collision integrals to four-digit accuracy over the reduced-temperature range 0.3≤T{sup ⁎}≤400, allowing very fast computation. Lennard-Jones parameters for neon, argon, and krypton are determined by simultaneously fitting the observed temperature dependences of their viscosities and second virial coefficients—one of the first times that a thermodynamic and a dynamic property have been used simultaneously for Lennard-Jones parameterization. In addition tomore » matching viscosities and second virial coefficients within the bounds of experimental error, the determined Lennard-Jones parameters are also found to predict the thermal conductivity and self-diffusion coefficient accurately, supporting the value of the Lennard-Jones (12–6) potential for noble-gas transport-property correlation.« less

Chemoviscosity modeling for thermosetting resins, 2

NASA Technical Reports Server (NTRS)

Hou, T. H.

1985-01-01

A new analytical model for simulating chemoviscosity of thermosetting resin was formulated. The model is developed by modifying the Williams-Landel-Ferry (WLF) theory in polymer rheology for thermoplastic materials. By assuming a linear relationship between the glass transition temperature and the degree of cure of the resin system under cure, the WLF theory can be modified to account for the factor of reaction time. Temperature dependent functions of the modified WLF theory constants were determined from the isothermal cure data of Lee, Loos, and Springer for the Hercules 3501-6 resin system. Theoretical predictions of the model for the resin under dynamic heating cure cycles were shown to compare favorably with the experimental data reported by Carpenter. A chemoviscosity model which is capable of not only describing viscosity profiles accurately under various cure cycles, but also correlating viscosity data to the changes of physical properties associated with the structural transformations of the thermosetting resin systems during cure was established.

Transient cage formation around hot gold colloids dispersed in polymer solutions.

PubMed

Schwaiger, F; Zimmermann, W; Köhler, W

2011-12-14

Gold colloids dispersed in dilute to concentrated polymer solutions can efficiently be heated by laser irradiation and act as almost pointlike heat sources. In systems with positive Soret coefficients S(T) of the polymer, such as solutions of polystyrene in toluene, the polymer can almost entirely be removed from the particle surface. The colloid attracts the solvent and a transient cage of low viscosity and dramatically enhanced mobility is formed, which follows the motion of the particle with a certain retardation. Based on a complete parameterization of S(T)(M, c, T), we analyze in detail the stationary temperature, concentration, and viscosity profiles. Depending on the polymer molar mass and concentration on the distance to the glass transition temperature, the negative or positive feedback-loops are established that lead to either attenuation or self-amplification of the polymer depletion. © 2011 American Institute of Physics

Coupled kinetic equations for fermions and bosons in the relaxation-time approximation

NASA Astrophysics Data System (ADS)

Florkowski, Wojciech; Maksymiuk, Ewa; Ryblewski, Radoslaw

2018-02-01

Kinetic equations for fermions and bosons are solved numerically in the relaxation-time approximation for the case of one-dimensional boost-invariant geometry. Fermions are massive and carry baryon number, while bosons are massless. The conservation laws for the baryon number, energy, and momentum lead to two Landau matching conditions, which specify the coupling between the fermionic and bosonic sectors and determine the proper-time dependence of the effective temperature and baryon chemical potential of the system. The numerical results illustrate how a nonequilibrium mixture of fermions and bosons approaches hydrodynamic regime described by the Navier-Stokes equations with appropriate forms of the kinetic coefficients. The shear viscosity of a mixture is the sum of the shear viscosities of fermion and boson components, while the bulk viscosity is given by the formula known for a gas of fermions, however, with the thermodynamic variables characterising the mixture. Thus, we find that massless bosons contribute in a nontrivial way to the bulk viscosity of a mixture, provided fermions are massive. We further observe the hydrodynamization effect, which takes place earlier in the shear sector than in the bulk one. The numerical studies of the ratio of the longitudinal and transverse pressures show, to a good approximation, that it depends on the ratio of the relaxation and proper times only. This behavior is connected with the existence of an attractor solution for conformal systems.

Solute-solvent interactions in 2,4-dihydroxyacetophenone isonicotinoylhydrazone solutions in N, N-dimethylformamide and dimethyl sulfoxide at 298-313 K on ultrasonic and viscometric data

NASA Astrophysics Data System (ADS)

Dikkar, A. B.; Pethe, G. B.; Aswar, A. S.

2016-02-01

The speed of sound ( u), density (ρ), and viscosity (η) of 2,4-dihydroxyacetophenone isonicotinoylhydrazone (DHAIH) have been measured in N, N-dimethyl formamide and dimethyl sulfoxide at equidistance temperatures 298.15, 303.15, 308.15, and 313.15 K. These data were used to calculate some important ultrasonic and thermodynamic parameters such as apparent molar volume ( V ϕ s st ), apparent molar compressibility ( K ϕ), partial molar volume ( V ϕ 0 ) and partial molar compressibility ( K ϕ 0 ), were estimated by using the values of ( V ϕ 0 ) and ( K ϕ), at infinite dilution. Partial molar expansion at infinite dilution, (ϕ E 0 ) has also been calculated from temperature dependence of partial molar volume V ϕ 0 . The viscosity data have been analyzed using the Jones-Dole equation, and the viscosity, B coefficients are calculated. The activation free energy has been calculated from B coefficients and partial molar volume data. The results have been discussed in the term of solute-solvent interaction occurring in solutions and it was found that DHAIH acts as a structure maker in present systems.

Human telomere sequence DNA in water-free and high-viscosity solvents: G-quadruplex folding governed by Kramers rate theory.

PubMed

Lannan, Ford M; Mamajanov, Irena; Hud, Nicholas V

2012-09-19

Structures formed by human telomere sequence (HTS) DNA are of interest due to the implication of telomeres in the aging process and cancer. We present studies of HTS DNA folding in an anhydrous, high viscosity deep eutectic solvent (DES) comprised of choline choride and urea. In this solvent, the HTS DNA forms a G-quadruplex with the parallel-stranded ("propeller") fold, consistent with observations that reduced water activity favors the parallel fold, whereas alternative folds are favored at high water activity. Surprisingly, adoption of the parallel structure by HTS DNA in the DES, after thermal denaturation and quick cooling to room temperature, requires several months, as opposed to less than 2 min in an aqueous solution. This extended folding time in the DES is, in part, due to HTS DNA becoming kinetically trapped in a folded state that is apparently not accessed in lower viscosity solvents. A comparison of times required for the G-quadruplex to convert from its aqueous-preferred folded state to its parallel fold also reveals a dependence on solvent viscosity that is consistent with Kramers rate theory, which predicts that diffusion-controlled transitions will slow proportionally with solvent friction. These results provide an enhanced view of a G-quadruplex folding funnel and highlight the necessity to consider solvent viscosity in studies of G-quadruplex formation in vitro and in vivo. Additionally, the solvents and analyses presented here should prove valuable for understanding the folding of many other nucleic acids and potentially have applications in DNA-based nanotechnology where time-dependent structures are desired.

Rheological changes of polyamide 12 under oscillatory shear

NASA Astrophysics Data System (ADS)

Mielicki, C.; Gronhoff, B.; Wortberg, J.

2014-05-01

Changes in material properties as well as process deviation prevent Laser Sintering (LS) technology from manufacturing of quality assured parts in a series production. In this context, the viscosity of Polyamide 12 (PA12) is assumed to possess the most significant influence, as it determines the sintering velocity, the resistance towards melt formation and the bonding strength of sintered layers. Moreover, the viscosity is directly related to the structure of the molten polymer. In particular, it has been recently reported that LS process conditions lead to structural changes of PA12 affecting viscosity and coalescence of adjacent polymer particles, i.e. melt formation significantly. Structural change of PA12 was understood as a post condensation. Its influence on viscosity was described by a time and temperature depending rheological model whereas time dependence was considered by a novel structural change shift factor which was derived from melt volume rate data. In combination with process data that was recorded using online thermal imaging, the model is suitable to control the viscosity (processability of the material) as result of material and process properties. However, as soon as laser energy is exposed to the powder bed PA12 undergoes a phase transition from solid to molten state. Above the melting point, structural change is expected to occur faster due to a higher kinetic energy and free volume of the molten polymer. Oscillatory shear results were used to study the influence of aging time and for validation of the novel structural change shift factor and its model parameters which were calibrated based on LS processing condition.

Rheology of arc dacite lavas: experimental determination at low strain rates

NASA Astrophysics Data System (ADS)

Avard, Geoffroy; Whittington, Alan G.

2012-07-01

Andesitic-dacitic volcanoes exhibit a large variety of eruption styles, including explosive eruptions, endogenous and exogenous dome growth, and kilometer-long lava flows. The rheology of these lavas can be investigated through field observations of flow and dome morphology, but this approach integrates the properties of lava over a wide range of temperatures. Another approach is through laboratory experiments; however, previous studies have used higher shear stresses and strain rates than are appropriate to lava flows. We measured the apparent viscosity of several lavas from Santiaguito and Bezymianny volcanoes by uniaxial compression, between 1,109 and 1,315 K, at low shear stress (0.085 to 0.42 MPa), low strain rate (between 1.1 × 10-8 and 1.9 × 10-5 s-1), and up to 43.7 % total deformation. The results show a strong variability of the apparent viscosity between different samples, which can be ascribed to differences in initial porosity and crystallinity. Deformation occurs primarily by compaction, with some cracking and/or vesicle coalescence. Our experiments yield apparent viscosities more than 1 order of magnitude lower than predicted by models based on experiments at higher strain rates. At lava flow conditions, no evidence of a yield strength is observed, and the apparent viscosity is best approached by a strain rate- and temperature-dependent power law equation. The best fit for Santiaguito lava, for temperatures between 1,164 and 1,226 K and strain rates lower than 1.8 × 10-4 s-1, is log {η_{{app}}} = - 0.738 + 9.24 × {10^3}{/}T(K) - 0.654 \\cdot log dot{\\varepsilon } where η app is apparent viscosity and dot{\\varepsilon } is strain rate. This equation also reproduced 45 data for a sample from Bezymianny with a root mean square deviation of 0.19 log unit Pa s. Applying the rheological model to lava flow conditions at Santiaguito yields calculated apparent viscosities that are in reasonable agreement with field observations and suggests that internal shear heating may be significant ongoing heat source within these flows, enabling highly viscous lava to travel long distances.

In-silico prediction of concentration-dependent viscosity curves for monoclonal antibody solutions

PubMed Central

Tomar, Dheeraj S.; Li, Li; Broulidakis, Matthew P.; Luksha, Nicholas G.; Burns, Christopher T.; Singh, Satish K.; Kumar, Sandeep

2017-01-01

ABSTRACT Early stage developability assessments of monoclonal antibody (mAb) candidates can help reduce risks and costs associated with their product development. Forecasting viscosity of highly concentrated mAb solutions is an important aspect of such developability assessments. Reliable predictions of concentration-dependent viscosity behaviors for mAb solutions in platform formulations can help screen or optimize drug candidates for flexible manufacturing and drug delivery options. Here, we present a computational method to predict concentration-dependent viscosity curves for mAbs solely from their sequence—structural attributes. This method was developed using experimental data on 16 different mAbs whose concentration-dependent viscosity curves were experimentally obtained under standardized conditions. Each concentration-dependent viscosity curve was fitted with a straight line, via logarithmic manipulations, and the values for intercept and slope were obtained. Intercept, which relates to antibody diffusivity, was found to be nearly constant. In contrast, slope, the rate of increase in solution viscosity with solute concentration, varied significantly across different mAbs, demonstrating the importance of intermolecular interactions toward viscosity. Next, several molecular descriptors for electrostatic and hydrophobic properties of the 16 mAbs derived using their full-length homology models were examined for potential correlations with the slope. An equation consisting of hydrophobic surface area of full-length antibody and charges on VH, VL, and hinge regions was found to be capable of predicting the concentration-dependent viscosity curves of the antibody solutions. Availability of this computational tool may facilitate material-free high-throughput screening of antibody candidates during early stages of drug discovery and development. PMID:28125318

In-silico prediction of concentration-dependent viscosity curves for monoclonal antibody solutions.

PubMed

Tomar, Dheeraj S; Li, Li; Broulidakis, Matthew P; Luksha, Nicholas G; Burns, Christopher T; Singh, Satish K; Kumar, Sandeep

2017-04-01

Early stage developability assessments of monoclonal antibody (mAb) candidates can help reduce risks and costs associated with their product development. Forecasting viscosity of highly concentrated mAb solutions is an important aspect of such developability assessments. Reliable predictions of concentration-dependent viscosity behaviors for mAb solutions in platform formulations can help screen or optimize drug candidates for flexible manufacturing and drug delivery options. Here, we present a computational method to predict concentration-dependent viscosity curves for mAbs solely from their sequence-structural attributes. This method was developed using experimental data on 16 different mAbs whose concentration-dependent viscosity curves were experimentally obtained under standardized conditions. Each concentration-dependent viscosity curve was fitted with a straight line, via logarithmic manipulations, and the values for intercept and slope were obtained. Intercept, which relates to antibody diffusivity, was found to be nearly constant. In contrast, slope, the rate of increase in solution viscosity with solute concentration, varied significantly across different mAbs, demonstrating the importance of intermolecular interactions toward viscosity. Next, several molecular descriptors for electrostatic and hydrophobic properties of the 16 mAbs derived using their full-length homology models were examined for potential correlations with the slope. An equation consisting of hydrophobic surface area of full-length antibody and charges on V H , V L , and hinge regions was found to be capable of predicting the concentration-dependent viscosity curves of the antibody solutions. Availability of this computational tool may facilitate material-free high-throughput screening of antibody candidates during early stages of drug discovery and development.

A study on the impact of hydroxypropyl methylcellulose on the viscosity of PEG melt suspensions using surface plots and principal component analysis.

PubMed

Oh, Ching Mien; Heng, Paul Wan Sia; Chan, Lai Wah

2015-04-01

An understanding of the rheological behaviour of polymer melt suspensions is crucial in pharmaceutical manufacturing, especially when processed by spray congealing or melt extruding. However, a detailed comparison of the viscosities at each and every temperature and concentration between the various grades of adjuvants in the formulation will be tedious and time-consuming. Therefore, the statistical method, principal component analysis (PCA), was explored in this study. The composite formulations comprising polyethylene glycol (PEG) 3350 and hydroxypropyl methylcellulose (HPMC) of ten different grades (K100 LV, K4M, K15M, K100M, E15 LV, E50 LV, E4M, F50 LV, F4M and Methocel VLV) at various concentrations were prepared and their viscosities at different temperatures determined. Surface plots showed that concentration of HPMC had a greater effect on the viscosity compared to temperature. Particle size and size distribution of HPMC played an important role in the viscosity of melt suspensions. Smaller particles led to a greater viscosity than larger particles. PCA was used to evaluate formulations of different viscosities. The complex viscosity profiles of the various formulations containing HPMC were successfully classified into three clusters of low, moderate and high viscosity. Formulations within each group showed similar viscosities despite differences in grade or concentration of HPMC. Formulations in the low viscosity cluster were found to be sprayable. PCA was able to differentiate the complex viscosity profiles of different formulations containing HPMC in an efficient and time-saving manner and provided an excellent visualisation of the data.

A Classical Phase Space Framework For the Description of Supercooled Liquids and an Apparent Universal Viscosity Collapse

NASA Astrophysics Data System (ADS)

Weingartner, Nicholas; Pueblo, Chris; Nogueira, Flavio; Kelton, Kenneth; Nussinov, Zohar

A fundamental understanding of the phenomenology of the metastable supercooled liquid state remains elusive. Two of the most pressing questions in this field are how to describe the temperature dependence of the viscosity, and determine whether or not the dynamical behaviors are universal. To address these questions, we have devised a simple first-principles classical phase space description of supercooled liquids that (along with a complementary quantum approach) predicts a unique functional form for the viscosity which relies on only a single parameter. We tested this form for 45 liquids of all types and fragilities, and have demonstrated that it provides a statistically significant fit to all liquids. Additionally, by scaling the viscosity of all studied liquids using the single parameter, we have observed a complete collapse of the data of all 45 liquids to a single scaling curve over 16 decades, suggesting an underlying universality in the dynamics of supercooled liquids. In this talk I will outline the basic approach of our model, as well as demonstrate the quality of the model performance and collapse of the data.

Relaxation Dynamics in Heme Proteins.

NASA Astrophysics Data System (ADS)

Scholl, Reinhard Wilhelm

A protein molecule possesses many conformational substates that are likely arranged in a hierarchy consisting of a number of tiers. A hierarchical organization of conformational substates is expected to give rise to a multitude of nonequilibrium relaxation phenomena. If the temperature is lowered, transitions between substates of higher tiers are frozen out, and relaxation processes characteristic of lower tiers will dominate the observational time scale. This thesis addresses the following questions: (i) What is the energy landscape of a protein? How does the landscape depend on the environment such as pH and viscosity, and how can it be connected to specific structural parts? (ii) What relaxation phenomena can be observed in a protein? Which are protein specific, and which occur in other proteins? How does the environment influence relaxations? (iii) What functional form best describes relaxation functions? (iv) Can we connect the motions to specific structural parts of the protein molecule, and are these motions important for the function of the protein?. To this purpose, relaxation processes after a pressure change are studied in carbonmonoxy (CO) heme proteins (myoglobin-CO, substrate-bound and substrate-free cytochrome P450cam-CO, chloroperoxidase-CO, horseradish peroxidase -CO) between 150 K and 250 K using FTIR spectroscopy to monitor the CO bound to the heme iron. Two types of p -relaxation experiments are performed: p-release (200 to ~eq40 MPa) and p-jump (~eq40 to 200 MPa) experiments. Most of the relaxations fall into one of three groups and are characterized by (i) nonexponential time dependence and non-Arrhenius temperature dependence (FIM1( nu), FIM1(Gamma)); (ii) exponential time dependence and non-Arrhenius temperature dependence (FIM0(A_{i}to A_{j})); exponential time dependence and Arrhenius temperature dependence (FIMX( nu)). The influence of pH is studied in myoglobin-CO and shown to have a strong influence on the substate population of the highest tier, tier 0, but not on the relaxation rates. Two different viscosities in myoglobin-CO are compared. The dependence of relaxations on the thermodynamic history of a sample is shown. For substrate-free P450cam-CO, relaxations after a p-jump are observed far above the glass transition of the protein-solvent system.

Study on viscosity of conventional and polymer modified asphalt binders in steady and dynamic shear domain

NASA Astrophysics Data System (ADS)

Saboo, Nikhil; Singh, Bhupendra; Kumar, Praveen; Vikram, Durgesh

2018-02-01

This study focuses on evaluating the flow behavior of conventional and polymer modified asphalt binders in steady- and dynamic-shear domain, for a temperature range of 20-70 °C, using a Dynamic Shear Rheometer (DSR). Steady-shear viscosity and frequency sweep tests were carried out on two conventional (VG 10 and VG 30) and two polymer (SBS and EVA) modified asphalt binders. Applicability of the Cox-Merz principle was evaluated and complex viscosity master curves were analyzed at five different reference temperatures. Cross model was used to simulate the complex viscosity master curves at different temperatures. It was found that asphalt binders exhibited shear-thinning behavior at all the test temperatures. The critical shear rate increased with increase in temperature and was found to be lowest for plastomeric modified asphalt binder. The Cox-Merz principle was found to be valid in the zero-shear viscosity (ZSV) domain and deviated at higher frequency/shear rate for all the binders. Results from the study indicated that the ratio of ZSV can be successfully used as shift factors for construction of master curves at different reference temperatures. Cross model was found to be suitable in simulating the complex viscosity master curves at all the test temperatures. Analysis of model parameters indicated that a strong relationship exists between ZSV and the critical shear rate. ZSV and critical shear rate varied exponentially with temperature. This relationship was used to propose a simple equation for assessing the shift factors for construction of master curves.

Thermal conductivity as influenced by the temperature and apparent viscosity of dairy products.

PubMed

Gonçalves, B J; Pereira, C G; Lago, A M T; Gonçalves, C S; Giarola, T M O; Abreu, L R; Resende, J V

2017-05-01

This study aimed to evaluate the rheological behavior and thermal conductivity of dairy products, composed of the same chemical components but with different formulations, as a function of temperature. Subsequently, thermal conductivity was related to the apparent viscosity of yogurt, fermented dairy beverage, and fermented milk. Thermal conductivity measures and rheological tests were performed at 5, 10, 15, 20, and 25°C using linear probe heating and an oscillatory rheometer with concentric cylinder geometry, respectively. The results were compared with those calculated using the parallel, series, and Maxwell-Eucken models as a function of temperature, and the discrepancies in the results are discussed. Linear equations were fitted to evaluate the influence of temperature on the thermal conductivity of the dairy products. The rheological behavior, specifically apparent viscosity versus shear rate, was influenced by temperature. Herschel-Bulkley, power law, and Newton's law models were used to fit the experimental data. The Herschel-Bulkley model best described the adjustments for yogurt, the power law model did so for fermented dairy beverages, and Newton's law model did so for fermented milk and was then used to determine the rheological parameters. Fermented milk showed a Newtonian trend, whereas yogurt and fermented dairy beverage were shear thinning. Apparent viscosity was correlated with temperature by the Arrhenius equation. The formulation influenced the effective thermal conductivity. The relationship between the 2 properties was established by fixing the temperature and expressing conductivity as a function of apparent viscosity. Thermal conductivity increased with viscosity and decreased with increasing temperature. Copyright © 2017 American Dairy Science Association. Published by Elsevier Inc. All rights reserved.

Melting properties of Pt and its transport coefficients in liquid states under high pressures

NASA Astrophysics Data System (ADS)

Wang, Pan-Pan; Shao, Ju-Xiang; Cao, Qi-Long

2016-11-01

Molecular dynamics (MD) simulations of the melting and transport properties in liquid states of platinum for the pressure range (50-200 GPa) are reported. The melting curve of platinum is consistent with previous ab initio MD simulation results and the first-principles melting curve. Calculated results for the pressure dependence of fusion entropy and fusion volume show that the fusion entropy and the fusion volume decrease with increasing pressure, and the ratio of the fusion volume to fusion entropy roughly reproduces the melting slope, which has a moderate decrease along the melting line. The Arrhenius law well describes the temperature dependence of self-diffusion coefficients and viscosity under high pressure, and the diffusion activation energy decreases with increasing pressure, while the viscosity activation energy increases with increasing pressure. In addition, the entropy-scaling law, proposed by Rosenfeld under ambient pressure, still holds well for liquid Pt under high pressure conditions.

Development of Viscosity Model for Petroleum Industry Applications

NASA Astrophysics Data System (ADS)

Motahhari, Hamed reza

Heavy oil and bitumen are challenging to produce and process due to their very high viscosity, but their viscosity can be reduced either by heating or dilution with a solvent. Given the key role of viscosity, an accurate viscosity model suitable for use with reservoir and process simulators is essential. While there are several viscosity models for natural gases and conventional oils, a compositional model applicable to heavy petroleum and diluents is lacking. The objective of this thesis is to develop a general compositional viscosity model that is applicable to natural gas mixtures, conventional crudes oils, heavy petroleum fluids, and their mixtures with solvents and other crudes. The recently developed Expanded Fluid (EF) viscosity correlation was selected as a suitable compositional viscosity model for petroleum applications. The correlation relates the viscosity of the fluid to its density over a broad range of pressures and temperatures. The other inputs are pressure and the dilute gas viscosity. Each fluid is characterized for the correlation by a set of fluid-specific parameters which are tuned to fit data. First, the applicability of the EF correlation was extended to asymmetric mixtures and liquid mixtures containing dissolved gas components. A new set of mass-fraction based mixing rules was developed to calculate the fluid-specific parameters for mixtures. The EF correlation with the new set of mixing rules predicted the viscosity of over 100 mixtures of hydrocarbon compounds and carbon dioxide with overall average absolute relative deviations (AARD) of less than 10% either with measured densities or densities estimated by Advanced Peng-Robinson equation of state (APR EoS). To improve the viscosity predictions with APR EoS-estimated densities, general correlations were developed for non-zero viscosity binary interaction parameters. The EF correlation was extended to non-hydrocarbon compounds typically encountered in natural gas industry. It was demonstrated that the framework of the correlation is valid for these compounds, except for compounds with strong hydrogen bonding such as water. A temperature dependency was introduced into the correlation for strongly hydrogen bonding compounds. The EF correlation fit the viscosity data of pure non-hydrocarbon compounds with AARDs below 6% and predicted the viscosity of sour and sweet natural gases and aqueous solutions of organic alcohols with overall AARDs less than 9%. An internally consistent estimation method was also developed to calculate the fluid-specific parameters for hydrocarbons when no experimental viscosity data are available. The method correlates the fluid-specific parameters to the molecular weight and specific gravity. The method was evaluated against viscosity data of over 250 pure hydrocarbon compounds and petroleum distillations cuts. The EF correlation predictions were found to be within the same order of magnitude of the measurements with an overall AARD of 31%. A methodology was then proposed to apply the EF viscosity correlation to crude oils characterized as mixtures of the defined components and pseudo-components. The above estimation methods are used to calculate the fluid-specific parameters for pseudo-components. Guidelines are provided for tuning of the correlation to available viscosity data, calculating the dilute gas viscosities, and improving the densities calculated with the Peng-Robinson EoS. The viscosities of over 10 dead and live crude oils and bitumen were predicted within a factor of 3 of the measured values using the measured density of the oils as the input. It was shown that single parameter tuning of the model improved the viscosity prediction to within 30% of the measured values. Finally, the performance of the EF correlation was evaluated for diluted heavy oils and bitumens. The required density and viscosity data were collected for over 20 diluted dead and live bitumen mixtures using an in-house capillary viscometer also equipped with an in-line density-meter at temperatures and pressures up to 175 °C and 10 MPa. The predictions of the correlation were found within the same order of magnitude of the measured values with overall AARDs less than 20%. It was shown that the predictions of the correlation with generalized non-zero interaction parameters for the solvent-oil pairs were improved to overall AARDs less than 10%.

Viscosity-dependent diffusion of fluorescent particles using fluorescence correlation spectroscopy.

PubMed

Jung, Chanbae; Lee, Jaeran; Kang, Manil; Kim, Sok Won

2014-11-01

Fluorescent particles show the variety characteristics by the interaction with other particles and solvent. In order to investigate the relationship between the dynamic properties of fluorescent particles and solvent viscosity, particle diffusion in various solvents was evaluated using a fluorescence correlation spectroscopy. Upon analyzing the correlation functions of AF-647, Q-dot, and beads with different viscosity values, the diffusion time of all particles was observed to increase with increasing solvent viscosity, and the ratio of diffusion time to solvent viscosity, τ D /η, showed a linear dependence on particle size. The particle diffusion coefficients calculated from the diffusion time decreased with increasing solvent viscosity. Further, the hydrodynamic radii of AF-647, Q-dot, and beads were 0.98 ± 0.1 nm, 64.8 ± 3.23 nm, and 89.8 ± 4.91 nm, respectively, revealing a linear dependence on τ D /η, which suggests that the hydrodynamic radius of a particle strongly depends on both the physical size of the particle and solvent viscosity.

Molecular Simulation Studies of Covalently and Ionically Grafted Nanoparticles

NASA Astrophysics Data System (ADS)

Hong, Bingbing

Solvent-free covalently- or ionically-grafted nanoparticles (CGNs and IGNs) are a new class of organic-inorganic hybrid composite materials exhibiting fluid-like behaviors around room temperature. With similar structures to prior systems, e.g. nanocomposites, neutral or charged colloids, ionic liquids, etc, CGNs and IGNs inherit the functionality of inorganic nanopariticles, the facile processibility of polymers, as well as conductivity and nonvolatility from their constituent materials. In spite of the extensive prior experimental research having covered synthesis and measurements of thermal and dynamic properties, little progress in understanding of these new materials at the molecular level has been achieved, because of the lack of simulation work in this new area. Atomistic and coarse-grained molecular dynamics simulations have been performed in this thesis to investigate the thermodynamics, structure, and dynamics of these systems and to seek predictive methods predictable for their properties. Starting from poly(ethylene oxide) oligomers (PEO) melts, we established atomistic models based on united-atom representations of methylene. The Green-Kubo and Einstein-Helfand formulas were used to calculate the transport properties. The simulations generate densities, viscosities, diffusivities, in good agreement with experimental data. The chain-length dependence of the transport properties suggests that neither Rouse nor reptation models are applicable in the short-chain regime investigated. Coupled with thermodynamic integration methods, the models give good predictions of pressure-composition-density relations for CO 2 + PEO oligomers. Water effects on the Henry's constant of CO 2 in PEO have also been investigated. The dependence of the calculated Henry's constants on the weight percentage of water falls on a temperature-dependent master curve, irrespective of PEO chain length. CGNs are modeled by the inclusion of solid-sphere nanoparticles into the atomistic oligomers. The calculated viscosities from Green-Kubo relationships and temperature extrapolation are of the same order of magnitude as experimental values, but show a smaller activation energy relative to real CGNs systems. Grafted systems have higher viscosities, smaller diffusion coefficients, and slower chain dynamics than the ungrafted counterparts - nanocomposites - at high temperatures. At lower temperatures, grafted systems exhibit faster dynamics for both nanoparticles and chains relative to ungrafted systems, because of lower aggregation of nanoparticles and enhanced correlations between nanoparticles and chains. This agrees with the experimental observation that the new materials have liquid-like behavior in the absence of a solvent. To lower the simulated temperatures into the experimental range, we established a coarse-grained CGNs model by matching structural distribution functions to atomistic simulation data. In contrast with linear polymer systems, for which coarse-graining always accelerate dynamics, coarse-graining of grafted nanoparticles can either accelerate or slowdown the core motions, depending on the length of the grafted chains. This can be qualitatively predicted by a simple transition-state theory. Similar atomistic models to CGNs were developed for IGNs, with ammonium counterions described by an explicit-hydrogen way; these were in turn compared with "generic" coarse-grained IGNs. The elimination of chemical details in the coarse-grained models does not bring in qualitative changes to the radial distribution functions and diffusion of atomistic IGNs, but saves considerable simulation resources and make simulations near room temperatures affordable. The chain counterions in both atomistic and coarse-grained models are mobile, moving from site to site and from nanoparticle to nanoparticle. At the same temperature and the same core volume fractions, the nanoparticle diffusivities in coarse-grained IGNs are slower by a factor ten than the cores of CGNs. The coarse-grained IGNs models are later used to investigate the system dynamics through analysis of the dependence on temperature and structural parameters of the transport properties (self-diffusion coefficients, viscosities and conductivities). Further, migration kinetics of oligomeric counterions is analyzed in a manner analogous to unimer exchange between micellar aggregates. The counterion migrations follow the "double-core" mechanism and are kinetically controlled by neighboring-core collisions. (Abstract shortened by UMI.)

A Slag Management Toolset for Determining Optimal Coal Gasification Temperatures

DOE Office of Scientific and Technical Information (OSTI.GOV)

Kwong, Kyei-Sing; Bennett, James P.

Abstract Gasifier operation is an intricate process because of the complex relationship between slag chemistry and temperature, limitations of feedstock materials, and operational preference. High gasification temperatures increase refractory degradation, while low gasification temperatures can lead to slag buildup on the gasifier sidewall or exit, either of which are problematic during operation. Maximizing refractory service life and gasifier performance require finding an optimized operating temperature range which is a function of the coal slag chemistry and viscosity. Gasifier operators typically use a slag’s viscosity-temperature relationship and/or ash-fusion fluid temperature to determine the gasification temperature range. NETL has built a slagmore » management toolset to determine the optimal temperature range for gasification of a carbon feedstock. This toolset is based on a viscosity database containing experimental data, and a number of models used to predict slag viscosity as a function of composition and temperature. Gasifier users typically have no scientific basis for selecting an operational temperature range for gasification, instead using experience to select operational conditions. The use of the toolset presented in this paper provides a basis for estimating or modifying carbon feedstock slags generated from ash impurities in carbon feedstock.« less

A Slag Management Toolset for Determining Optimal Coal Gasification Temperatures

DOE PAGES

Kwong, Kyei-Sing; Bennett, James P.

2016-11-25

Abstract Gasifier operation is an intricate process because of the complex relationship between slag chemistry and temperature, limitations of feedstock materials, and operational preference. High gasification temperatures increase refractory degradation, while low gasification temperatures can lead to slag buildup on the gasifier sidewall or exit, either of which are problematic during operation. Maximizing refractory service life and gasifier performance require finding an optimized operating temperature range which is a function of the coal slag chemistry and viscosity. Gasifier operators typically use a slag’s viscosity-temperature relationship and/or ash-fusion fluid temperature to determine the gasification temperature range. NETL has built a slagmore » management toolset to determine the optimal temperature range for gasification of a carbon feedstock. This toolset is based on a viscosity database containing experimental data, and a number of models used to predict slag viscosity as a function of composition and temperature. Gasifier users typically have no scientific basis for selecting an operational temperature range for gasification, instead using experience to select operational conditions. The use of the toolset presented in this paper provides a basis for estimating or modifying carbon feedstock slags generated from ash impurities in carbon feedstock.« less

Influence of hydroxyapatite nanoparticles on the viscosity of dimethyl sulfoxide-H2O-NaCl and glycerol-H2O-NaCl ternary systems at subzero temperatures.

PubMed

Yi, Jingru; Tang, Heyu; Zhao, Gang

2014-10-01

The viscosity, at subzero temperatures, of ternary solutions commonly used in cryopreservation is tremendously important for understanding ice formation and molecular diffusion in biopreservation. However, this information is scarce in the literature. In addition, to the best of our knowledge, the effect of nanoparticles on the viscosity of these solutions has not previously been reported. The objectives of this study were thus: (i) to systematically measure the subzero viscosity of two such systems, dimethyl sulfoxide (Me2SO)-H2O-NaCl and glycerol-H2O-NaCl; (ii) to explore the effect of hydroxyapatite (HA) nanoparticles on the viscosity; and (iii) to provide models that precisely predict viscosity at multiple concentrations of cryoprotective agent (CPA) in saline solutions at subzero temperatures. Our experiments were performed in two parts. We first measured the viscosity at multiple CPA concentrations [0.3-0.75 (w/w)] in saline solution with and without nanoparticles at subzero temperatures (0 to -30°C). The data exhibited a good fit to the Williams-Landel-Ferry (WLF) equation. We then measured the viscosity of residual unfrozen ternary solutions with and without nanoparticles during equilibrium freezing. HA nanoparticles made the solution more viscous, suggesting applications for these nanoparticles in preventing cell dehydration, ice nucleation, and ice growth during freezing and thawing in cryopreservation. Copyright © 2014 Elsevier Inc. All rights reserved.

Effects of bulk viscosity and hadronic rescattering in heavy ion collisions at energies available at the BNL Relativistic Heavy Ion Collider and at the CERN Large Hadron Collider

DOE Office of Scientific and Technical Information (OSTI.GOV)

Ryu, Sangwook; Paquet, Jean-Francois; Shen, Chun

Here, we describe ultrarelativistic heavy ion collisions at the BNL Relativistic Heavy Ion Collider and the CERN Large Hadron Collider with a hybrid model using the IP-Glasma model for the earliest stage and viscous hydrodynamics and microscopic transport for the later stages of the collision. We demonstrate that within this framework the bulk viscosity of the plasma plays an important role in describing the experimentally observed radial flow and azimuthal anisotropy simultaneously. Finally, we further investigate the dependence of observables on the temperature below which we employ the microscopic transport description.

Effects of bulk viscosity and hadronic rescattering in heavy ion collisions at energies available at the BNL Relativistic Heavy Ion Collider and at the CERN Large Hadron Collider

DOE PAGES

Ryu, Sangwook; Paquet, Jean-Francois; Shen, Chun; ...

2018-03-15

Here, we describe ultrarelativistic heavy ion collisions at the BNL Relativistic Heavy Ion Collider and the CERN Large Hadron Collider with a hybrid model using the IP-Glasma model for the earliest stage and viscous hydrodynamics and microscopic transport for the later stages of the collision. We demonstrate that within this framework the bulk viscosity of the plasma plays an important role in describing the experimentally observed radial flow and azimuthal anisotropy simultaneously. Finally, we further investigate the dependence of observables on the temperature below which we employ the microscopic transport description.

P2O5-doping in waste glasses: evolution of viscosity and crystallization processes

NASA Astrophysics Data System (ADS)

Tarrago, Mariona; Espuñes, Alex; Garcia-Valles, Maite; Martinez, Salvador

2015-04-01

Current concern for environmental preservation is the main motive for the study of new, more sustainable materials. Increasing amounts of sewage sludge are produced in wastewater treatment plants over the world every day. This fact represents a major problem for the municipalities and industries due to the volume of waste and also to the contaminant elements it may bear, which require expensive conditions for disposal in landfills. Vitrification is an established technique in the inertization of different types of toxic wastes (such as nuclear wastes and contaminated soils) that has been used successfully for sewage sludge. Glasses of basaltic composition (43.48SiO2-14.00Al2O3-12.86Fe2O3-10.00CaO-9.94MgO-3.27Na2O-1.96K2O-0.17MnO-0.55P2O5-2.48TiO2) are used as a laboratory analogous of wastes such as sewage sludge and galvanic sludge to study the properties of the inertization matrix. This basaltic matrix is doped by adding 1%, 2%, 3%, 4% and 20% of P5O5 in order to cover the compositional range of phosphate in sewage sludge encountered in the literature. In this study, the focus has been placed in the effect of the concentration of phosphate (P2O5) in glass stability, thermal properties and evolution of viscosity with temperature. The dependence of viscosity on temperature and the thermal behaviour of these glasses are critical parameters in the design of their production process. Regarding the compositional limits of the mixture, it has been observed that melt reactivity is much increased when P2O5 content is over 4%, hindering the glass conformation process. Moreover, stanfieldite (calcium and magnesium phosphate) crystallized during glass making when phosphate concentration approached 20%, hence establishing the upper limit for glass stability. Viscosity is also dramatically increased in this range, hence requiring production amends. Differential thermal analysis has provided nucleation and crystallization temperatures of the glasses around 915°C and 1050°C respectively at phosphate contents up to 4%. Subsequent analysis by X-Ray Diffraction has proved that newly formed phases are iron oxides, Ca - Mg silicates and feldspars. Glass transition temperature (Tg; approximately 635°C) obtained by dilatometry remains almost constant until very high phosphate contents; even then, the increase is not large (650°C at 20% P2O5). Hot-Stage microscopy (HSM) has shown the evolution of viscosity with temperature through the analysis of the morphological evolution of cylindrical probes of glass according to German standard DIN 51730. The annealing range (viscosity between 1013.5 and 1012 is reached at temperatures between 600 and 700°C. The temperatures of the lower limit of the working range (viscosity under 103 Pa-s) are between 1325 and 1375°C; decreasing slightly with the addition of P2O5.

Transport properties of N2 gas at cryogenic temperatures. [computation of viscosity and thermal conductivity

NASA Technical Reports Server (NTRS)

Pearson, W. E.

1974-01-01

The viscosity and thermal conductivity of nitrogen gas for the temperature range 5 K - 135 K have been computed from the second Chapman-Enskog approximation. Quantum effects, which become appreciable at the lower temperatures, are included by utilizing collision integrals based on quantum theory. A Lennard-Jones (12-6) potential was assumed. The computations yield viscosities about 20 percent lower than those predicted for the high end of this temperature range by the method of corresponding states, but the agreement is excellent when the computed values are compared with existing experimental data.

Validity of Eucken formula and Stokes’ viscosity relation in high-temperature electronically excited gases

DOE Office of Scientific and Technical Information (OSTI.GOV)

Istomin, V. A.; Kustova, E. V.; Mekhonoshina, M. A.

2014-12-09

In the present work we evaluate the accuracy of the Eucken formula and Stokes’ viscosity relation in high temperature non-equilibrium air species with electronic excitation. The thermal conductivity coefficient calculated using the exact kinetic theory methods is compared with that obtained applying approximate formulas in the temperature range 200–20000 K. A modification of the Eucken formula providing a good agreement with exact calculations is proposed. It is shown that the Stokes viscosity relation is not valid in electronically excited monoatomic gases at temperatures higher than 2000 K.

A technique for evaluating the oil/heavy-oil viscosity changes under ultrasound in a simulated porous medium.

PubMed

Hamidi, Hossein; Mohammadian, Erfan; Junin, Radzuan; Rafati, Roozbeh; Manan, Mohammad; Azdarpour, Amin; Junid, Mundzir

2014-02-01

Theoretically, Ultrasound method is an economical and environmentally friendly or "green" technology, which has been of interest for more than six decades for the purpose of enhancement of oil/heavy-oil production. However, in spite of many studies, questions about the effective mechanisms causing increase in oil recovery still existed. In addition, the majority of the mechanisms mentioned in the previous studies are theoretical or speculative. One of the changes that could be recognized in the fluid properties is viscosity reduction due to radiation of ultrasound waves. In this study, a technique was developed to investigate directly the effect of ultrasonic waves (different frequencies of 25, 40, 68 kHz and powers of 100, 250, 500 W) on viscosity changes of three types of oil (Paraffin oil, Synthetic oil, and Kerosene) and a Brine sample. The viscosity calculations in the smooth capillary tube were based on the mathematical models developed from the Poiseuille's equation. The experiments were carried out for uncontrolled and controlled temperature conditions. It was observed that the viscosity of all the liquids was decreased under ultrasound in all the experiments. This reduction was more significant for uncontrolled temperature condition cases. However, the reduction in viscosity under ultrasound was higher for lighter liquids compare to heavier ones. Pressure difference was diminished by decreasing in the fluid viscosity in all the cases which increases fluid flow ability, which in turn aids to higher oil recovery in enhanced oil recovery (EOR) operations. Higher ultrasound power showed higher liquid viscosity reduction in all the cases. Higher ultrasound frequency revealed higher and lower viscosity reduction for uncontrolled and controlled temperature condition experiments, respectively. In other words, the reduction in viscosity was inversely proportional to increasing the frequency in temperature controlled experiments. It was concluded that cavitation, heat generation, and viscosity reduction are three of the promising mechanisms causing increase in oil recovery under ultrasound. Copyright © 2013 Elsevier B.V. All rights reserved.

Dependence of Perpendicular Viscosity on Magnetic Fluctuations in a Stochastic Topology

NASA Astrophysics Data System (ADS)

Fridström, R.; Chapman, B. E.; Almagri, A. F.; Frassinetti, L.; Brunsell, P. R.; Nishizawa, T.; Sarff, J. S.

2018-06-01

In a magnetically confined plasma with a stochastic magnetic field, the dependence of the perpendicular viscosity on the magnetic fluctuation amplitude is measured for the first time. With a controlled, ˜ tenfold variation in the fluctuation amplitude, the viscosity increases ˜100 -fold, exhibiting the same fluctuation-amplitude-squared dependence as the predicted rate of stochastic field line diffusion. The absolute value of the viscosity is well predicted by a model based on momentum transport in a stochastic field, the first in-depth test of this model.

Clinical investigations of polymethylmethacrylate cement viscosity during vertebroplasty and related in vitro measurements

PubMed Central

Boger, A.; Schenk, B.; Heini, P. F.

2009-01-01

Percutaneous vertebroplasty, comprising an injection of polymethylmethacrylate (PMMA) into vertebral bodies, is a practical procedure for the stabilization of osteoporotic compression fractures as well as other weakening lesions. Cement leakage is considered to be one of the major and most severe complications during percutaneous vertebroplasty. The viscosity of the material plays a key role in this context. In order to enhance the safety for the patient, a rheometer system was developed to measure the cement viscosity intraoperatively. For this development, it is of great importance to know the proper viscosity to start the procedure determined by experienced surgeons and the relation between the time period when different injection devices are used and the cement viscosity. The purpose of the study was to investigate the viscosity ranges for different injection systems during conventional vertebroplasty. Clinically observed viscosity values and related time periods showed high scattering. In order to get a better understanding of the clinical observations, cement viscosity during hardening at different ambient temperatures and by simulation of the body temperature was investigated in vitro. It could be concluded, that the direct viscosity assessment with a rheometer during vertebroplasty can help clinicians to define a lower threshold viscosity and thereby decrease the risk of leakage and make adjustments to their injection technique in real time. Secondly, the acceleration in hardening of PMMA-based cements at body temperature can be useful in minimizing leakages by addressing them with a short injection break. PMID:19479285

Mechanisms for the Crystallization of ZBLAN

NASA Technical Reports Server (NTRS)

Ethridge, Edwin C.; Tucker, Dennis S.; Kaukler, William; Antar, Basil

2003-01-01

The objective of this ground based study is to test the hypothesis that shear thinning (the non-Newtonian response of viscosity to shear rate) is a viable mechanism to explain the observation of enhanced glass formation in numerous low-g experiments. In 1-g, fluid motion results from buoyancy forces and surface tension driven convection. This fluid flow will introduce shear in undercooled liquids in 1-g. In low-g it is known that fluid flows are greatly reduced so that the shear rate in fluids can be extremely low. It is believed that some fluids may have weak structure in the absence of flow. Very small shear rates could cause this structure to collapse in response to shear resulting in a lowering of the viscosity of the fluid. The hypothesis of this research is that: Shear thinning in undercooled liquids decreases the viscosity, increasing the rate of nucleation and crystallization of glass forming melts. Shear in the melt can be reduced in low-g, thus enhancing undercooling and glass formation. The viscosity of a model glass (lithium di-silicate, L2S) often used for crystallization studies has been measured at very low shear rates using a dynamic mechanical thermal analyzer. Our results are consistent with increasing viscosity with a lowering of shear rates. The viscosity of L2S may vary as much as an order of magnitude depending on the shear rate in the temperature region of maximum nucleation and crystal growth. Classical equations for nucleation and crystal growth rates, are inversely related to the viscosity and viscosity to the third power respectively. An order of magnitude variation in viscosity (with shear) at a given temperature would have dramatic effects on glass crystallization Crystallization studies with the heavy metal fluoride glass ZBLAN (ZrF2-BaF2-LaF3-AlF3-NaF) to examine the effect of shear on crystallization are being initiated. Samples are to be melted and quenched under quiescent conditions at different shear rates to determine the effect on crystallization. The results from this study are expected to advance the current scientific understanding of glass formation in low-g and glass crystallization under glass molding conditions and will improve the scientific understanding of technological processes such as fiber pulling, bulk amorphous alloys, and glass fabrication processes.

The Brittle-Ductile Transition in Crystal and Bubble-bearing Magmas

NASA Astrophysics Data System (ADS)

Caricchi, L.; Pistone, M.; Cordonnier, B.; Tripoli, B.; Ulmer, P.; Reusser, E.; Marone, F.; Burlini, L.

2011-12-01

The strain response of magma is critically dependent upon its viscosity, the magnitude of the applied stress and the experimental time-scale. The brittle-ductile transition in pure silicate melts is expected for an applied stress approaching 108±0.5 Pa (Dingwell, 1997). However, magmas are mostly mixture of crystal and bubble-bearing silicate melts. To date, there are no data to constrain the ductile-brittle transition for three-phase magmas. Thus, we conducted consistent torsion experiments at high temperature (673-973 K) and high pressure (200 MPa), in the strain rate range 1*10-5-4*10-3 s-1, using a HT-HP internally-heated Paterson-type rock deformation apparatus. The samples are composed of hydrous haplogranitic glass, quartz crystals (24-65 vol%) and CO2-rich gas-pressurized bubbles (9-12 vol%). The applied strain rate was increased until brittle failure occurred; micro-fracturing and healing processes commonly occurred before sample macroscopic fracturing. The experimental results highlight a clear relationship between the effective viscosity of the three-phase magmas, strain rate, temperature and the onset of brittle-ductile behavior. Crystal- and bubble-free melts at high viscosity (1011-1011.6 Pa*s at 673 K) show brittle behavior in the strain rate range between 1*10-4 and 5*10-4 s-1. For comparable viscosities crystal and bubble-bearing magmas show a transition to brittle behavior at lower strain rates. Synchrotron-based 3D imaging of fractured samples, show the presence of fractures with an antithetic trend with respect to shear strain directions. The law found in this study expresses the transition from ductile to brittle behavior for real magmas and could significantly improve our understanding of the control of brittle processes on extrusion of high-viscosity magmas and degassing at silicic volcanoes.

Glass transition and viscosity of P/sub 2/O/sub 5/

DOE Office of Scientific and Technical Information (OSTI.GOV)

Martin, S.W.; Angell, C.A.

1986-12-04

The calorimetric glass transition temperature T/sub g/ for pure anhydrous P/sub 2/O/sub 5/ melted in sealed SiO/sub 2/ ampules at 1000 /sup 0/C has been obtained directly for the first time with differential scanning calorimetry, and the increase in heat capacity at T/sub g/ has been determined. T/sub g/ measured in this way is 57 K higher than the value quoted in the literature, which is probably based on an Arrhenius law extrapolation of viscosity data to eta = 10/sup 13/ P. Combining the high-temperature viscosity data with the common observation that, for oxide glasses, eta = 10/sup 12/ Pmore » at the DSC T/sub g/, the authors find that the P/sub 2/O/sub 5/ viscosity obeys an Arrhenius law over at least 6 decades of eta. Furthermore, the intercept at 1/T = 0 coincides with the common point of T/sub g/ - reduced viscosity plots for a wide variety of liquids recently used in establishing the strong vs. fragile classification of glass-forming liquids. On this basis, P/sub 2/O/sub 5/ behaves as the archetypal strong liquid. However, the value of C/sub p/(liquid)/C/sub p/(glass) at T/sub g/, 1.27, is larger than expected on this basis since other strong liquids show smaller values, e.g., GeO/sub 2/ (1.09) and BeF/sub 2/ (no ..delta..C/sub p/ detected). The dependence of T/sub g/ on heating rate has been determined and shows that enthalpy relaxation in the transition region has, within error, the same activation energy (43.9 kcal/mol) as for viscous flow.« less

Effect of particle size on the glass transition.

PubMed

Larsen, Ryan J; Zukoski, Charles F

2011-05-01

The glass transition temperature of a broad class of molecules is shown to depend on molecular size. This dependency results from the size dependence of the pair potential. A generalized equation of state is used to estimate how the volume fraction at the glass transition depends on the size of the molecule, for rigid molecule glass-formers. The model shows that at a given pressure and temperature there is a size-induced glass transition: For molecules larger than a critical size, the volume fraction required to support the effective pressure due to particle attractions is above that which characterizes the glassy state. This observation establishes the boundary between nanoparticles, which exist in liquid form only as dispersions in low molecular weight solvents and large molecules which form liquids that have viscosities below those characterized by the glassy state.

Molecular basis of high viscosity in concentrated antibody solutions: Strategies for high concentration drug product development

PubMed Central

Tomar, Dheeraj S.; Kumar, Sandeep; Singh, Satish K.; Goswami, Sumit; Li, Li

2016-01-01

ABSTRACT Effective translation of breakthrough discoveries into innovative products in the clinic requires proactive mitigation or elimination of several drug development challenges. These challenges can vary depending upon the type of drug molecule. In the case of therapeutic antibody candidates, a commonly encountered challenge is high viscosity of the concentrated antibody solutions. Concentration-dependent viscosity behaviors of mAbs and other biologic entities may depend on pairwise and higher-order intermolecular interactions, non-native aggregation, and concentration-dependent fluctuations of various antibody regions. This article reviews our current understanding of molecular origins of viscosity behaviors of antibody solutions. We discuss general strategies and guidelines to select low viscosity candidates or optimize lead candidates for lower viscosity at early drug discovery stages. Moreover, strategies for formulation optimization and excipient design are also presented for candidates already in advanced product development stages. Potential future directions for research in this field are also explored. PMID:26736022

Driving forces: Slab subduction and mantle convection

NASA Technical Reports Server (NTRS)

Hager, Bradford H.

1988-01-01

Mantle convection is the mechanism ultimately responsible for most geological activity at Earth's surface. To zeroth order, the lithosphere is the cold outer thermal boundary layer of the convecting mantle. Subduction of cold dense lithosphere provides tha major source of negative buoyancy driving mantle convection and, hence, surface tectonics. There are, however, importnat differences between plate tectonics and the more familiar convecting systems observed in the laboratory. Most important, the temperature dependence of the effective viscosity of mantle rocks makes the thermal boundary layer mechanically strong, leading to nearly rigid plates. This strength stabilizes the cold boundary layer against small amplitude perturbations and allows it to store substantial gravitational potential energy. Paradoxically, through going faults at subduction zones make the lithosphere there locally weak, allowing rapid convergence, unlike what is observed in laboratory experiments using fluids with temperature dependent viscosities. This bimodal strength distribution of the lithosphere distinguishes plate tectonics from simple convection experiments. In addition, Earth has a buoyant, relatively weak layer (the crust) occupying the upper part of the thermal boundary layer. Phase changes lead to extra sources of heat and bouyancy. These phenomena lead to observed richness of behavior of the plate tectonic style of mantle convection.

Viscous effects on the Rayleigh-Taylor instability with background temperature gradient

DOE Office of Scientific and Technical Information (OSTI.GOV)

Gerashchenko, S.; Livescu, D., E-mail: livescu@lanl.gov

The growth rate of the compressible Rayleigh-Taylor instability is studied in the presence of a background temperature gradient, Θ, using a normal mode analysis. The effect of Θ variation is examined for three interface types corresponding to the combinations of the viscous properties of the fluids (inviscid-inviscid, viscous-viscous, and viscous-inviscid) at different Atwood numbers, At, and when at least one of the fluids' viscosity is non-zero, as a function of the Grashof number. For the general case, the resulting ordinary differential equations are solved numerically; however, dispersion relations for the growth rate are presented for several limiting cases. An analyticalmore » solution is found for the inviscid-inviscid interface and the corresponding dispersion equation for the growth rate is obtained in the limit of large Θ. For the viscous-inviscid case, a dispersion relation is derived in the incompressible limit and Θ = 0. Compared to Θ = 0 case, the role of Θ < 0 (hotter light fluid) is destabilizing and becomes stabilizing when Θ > 0 (colder light fluid). The most pronounced effect of Θ ≠ 0 is found at low At and/or at large perturbation wavelengths relative to the domain size for all interface types. On the other hand, at small perturbation wavelengths relative to the domain size, the growth rate for the Θ < 0 case exceeds the infinite domain incompressible constant density result. The results are applied to two practical examples, using sets of parameters relevant to Inertial Confinement Fusion coasting stage and solar corona plumes. The role of viscosity on the growth rate reduction is discussed together with highlighting the range of wavenumbers most affected by viscosity. The viscous effects further increase in the presence of background temperature gradient, when the viscosity is temperature dependent.« less

Study on viscosity of MDEA-MeOH aqueous solutions

NASA Astrophysics Data System (ADS)

Wang, F.; Wang, L. M.; Wang, S. Q.; Fu, D.

2017-03-01

The viscosities of the N-methyldiethanolamine (MDEA)-methanol (MeOH) aqueous solutions were measured at temperatures ranging from (303.2 to 323.2) K. The mass fraction of MDEA and MeOH respectively ranged from 0.2 to 0.4 and 0 to 0.15. On the basis of experimental measurement, the effects of temperature, mass fraction of MDEA and MeOH on viscosities were demonstrated.

Effects of wall temperature on skin-friction measurements by oil-film interferometry

NASA Astrophysics Data System (ADS)

Bottini, H.; Kurita, M.; Iijima, H.; Fukagata, K.

2015-10-01

Wind-tunnel skin-friction measurements with thin-oil-film interferometry have been taken on an aluminum sample to investigate the effects of wall temperature on the accuracy of the technique. The sample has been flush-mounted onto a flat plate with an electric heater at its bottom and mirror-smooth temperature-sensitive paint sprayed on its top. The heater has varied the sample temperature from ambient to 328 K, and the paint has permitted wall temperature measurements on the same area of the skin-friction measurements and during the same test. The measured wall temperatures have been used to calculate the correct oil viscosities, and these viscosities and the constant nominal viscosity at 298 K have been used to calculate two different sets of skin-friction coefficients. These sets have been compared to each other and with theoretical values. This comparison shows that the effects of wall temperature on the accuracy of skin-friction measurements are sensible, and more so as wall temperature differs from 298 K. Nonetheless, they are effectively neutralized by the use of wall temperature measurements in combination with the correct oil viscosity-temperature law. In this regard, the special temperature-sensitive paint developed for this study shows advantages with respect to more traditional wall temperature measurement techniques.

Stokes-Einstein relation in liquid iron-nickel alloy up to 300 GPa

NASA Astrophysics Data System (ADS)

Cao, Q.-L.; Wang, P.-P.

2017-05-01

Molecular dynamic simulations were applied to investigate the Stokes-Einstein relation (SER) and the Rosenfeld entropy scaling law (ESL) in liquid Fe0.9Ni0.1 over a sufficiently broad range of temperatures (0.70 < T/Tm < 1.85 Tm is melting temperature) and pressures (from 50 GPa to 300 GPa). Our results suggest that the SER and ESL hold well in the normal liquid region and break down in the supercooled region under high-pressure conditions, and the deviation becomes larger with decreasing temperature. In other words, the SER can be used to calculate the viscosity of liquid Earth's outer core from the self-diffusion coefficients of iron/nickel and the ESL can be used to predict the viscosity and diffusion coefficients of liquid Earth's outer core form its structural properties. In addition, the pressure dependence of effective diameters cannot be ignored in the course of using the SER. Moreover, ESL provides a useful, structure-based probe for the validity of SER, while the ratio of the self-diffusion coefficients of the components cannot be used as a probe for the validity of SER.

Physicochemical, morphological and rheological properties of canned bean pastes "negro Queretaro" variety (Phaseolus vulgaris L.).

PubMed

Martínez-Preciado, A H; Estrada-Girón, Y; González-Álvarez, A; Fernández, V V A; Macías, E R; Soltero, J F A

2014-09-01

Proximate, thermal, morphological and rheological properties of canned "negro Querétaro" bean pastes, as a function of fat content (0, 2 and 3 %) and temperature (60, 70 and 85 °C), were evaluated. Raw and precooked bean pastes were characterized by scanning electron microscopy (SEM) and differential scanning calorimetry (DSC). Well-defined starch granules in the raw bean pastes were observed, whereas a gelatinized starch paste was observed for the canned bean pastes. The DSC analysis showed that the raw bean pastes had lower onset peak temperatures (79 °C, 79.1 °C) and gelatinization enthalpy (1.940 J/g), compared to that precooked bean pastes (70.4 °C, 75.7 °C and 1.314 J/g, respectively) thermal characteristics. Moreover, the dynamic rheological results showed a gel-like behavior for the canned bean pastes, where the storage modulus (G') was frequency independent and was higher than the loss modulus (G″). The non-linear rheological results exhibited a shear-thinning flow behavior, where the steady shear-viscosity was temperature and fat content dependent. For canned bean pastes, the shear-viscosity data followed a power law equation, where the power law index (n) decreased when the temperature and the fat content increased. The temperature effect on the shear-viscosity was described by an Arrhenius equation, where the activation energy (Ea) was in the range from 19.04 to 36.81 KJ/mol. This rheological behavior was caused by gelatinization of the starch during the cooking and sterilization processes, where starch-lipids and starch-proteins complex were formed.

Linear response and Berry curvature in two-dimensional topological phases

NASA Astrophysics Data System (ADS)

Bradlyn, Barry J.

In this thesis we examine the viscous and thermal transport properties of chiral topological phases, and their relationship to topological invariants. We start by developing a Kubo formalism for calculating the frequency dependent viscosity tensor of a general quantum system, both with and without a uniform external magnetic field. The importance of contact terms is emphasized. We apply this formalism to the study of integer and fractional quantum Hall states, as well as p + ip paired superfluids, and verify the relationship between the Hall viscosity and the mean orbital spin density. We also elucidate the connection between our Kubo formulas and prior adiabatic transport calculations of the Hall viscosity. Additionally, we derive a general relationship between the frequency dependent viscosity and conductivity tensors for Galilean-invariant systems. We comment on the implications of this relationship towards the measurement of Hall viscosity in solid-state systems. To address the question of thermal transport, we first review the standard Kubo formalism of Luttinger for computing thermoelectric coefficients. We apply this to the specific case of non-interacting electrons in the integer quantum Hall regime, paying careful attention to the roles of bulk and edge effects. In order to generalize our discussion to interacting systems, we construct a low-energy effective action for a two-dimensional non-relativistic topological phase of matter in a continuum, which completely describes all of its bulk thermoelectric and visco-elastic properties in the limit of low frequencies, long distances, and zero temperature, without assuming either Lorentz or Galilean invariance, by coupling the microscopic degrees of freedom to the background spacetime geometry. We derive the most general form of a local bulk induced action to first order in derivatives of the background fields, from which thermodynamic and transport properties can be obtained. We show that the gapped bulk cannot contribute to low-temperature thermoelectric transport other than the ordinary Hall conductivity; the other thermoelectric effects (if they occur) are thus purely edge effects. The stress response to time-dependent strains is given by the Hall viscosity, which is robust against perturbations and related to the spin current. Finally, we address the issue of calculating the topological central charge from bulk wavefunctions for a topological phase. Using the form of the topological terms in the induced action, we show that we can calculate the various coefficients of these terms as Berry curvatures associated to certain metric and electromagnetic vector potential perturbations. We carry out this computation explicitly for quantum Hall trial wavefunctions that can be represented as conformal blocks in a chiral conformal field theory (CFT). These calculations make use of the gauge and gravitational anomalies in the underlying chiral CFT.

On the diffusion of ferrocenemethanol in room-temperature ionic liquids: an electrochemical study.

PubMed

Lovelock, Kevin R J; Ejigu, Andinet; Loh, Sook Fun; Men, Shuang; Licence, Peter; Walsh, Darren A

2011-06-07

The electrochemical behaviour of ferrocenemethanol (FcMeOH) has been studied in a range of room-temperature ionic liquids (RTILs) using cyclic voltammetry, chronoamperomery and scanning electrochemical microscopy (SECM). The diffusion coefficient of FcMeOH, measured using chronoamperometry, decreased with increasing RTIL viscosity. Analysis of the mass transport properties of the RTILs revealed that the Stokes-Einstein equation did not apply to our data. The "correlation length" was estimated from diffusion coefficient data and corresponded well to the average size of holes (voids) in the liquid, suggesting that a model in which the diffusing species jumps between holes in the liquid is appropriate in these liquids. Cyclic voltammetry at ultramicroelectrodes demonstrated that the ability to record steady-state voltammograms during ferrocenemethanol oxidation depended on the voltammetric scan rate, the electrode dimensions and the RTIL viscosity. Similarly, the ability to record steady-state SECM feedback approach curves depended on the RTIL viscosity, the SECM tip radius and the tip approach speed. Using 1.3 μm Pt SECM tips, steady-state SECM feedback approach curves were obtained in RTILs, provided that the tip approach speed was low enough to maintain steady-state diffusion at the SECM tip. In the case where tip-induced convection contributed significantly to the SECM tip current, this effect could be accounted for theoretically using mass transport equations that include diffusive and convective terms. Finally, the rate of heterogeneous electron transfer across the electrode/RTIL interface during ferrocenemethanol oxidation was estimated using SECM, and k(0) was at least 0.1 cm s(-1) in one of the least viscous RTILs studied.

Investigation of Damping Liquids for Aircraft Instruments : II

NASA Technical Reports Server (NTRS)

Houseman, M R; Keulegan, G H

1932-01-01

Data are presented on the kinematic viscosity, in the temperature range -50 degrees to +30 degrees C. of pure liquids and of solutions of animal oils, vegetable oils, mineral oils, glycerine, and ethylene glycol in various low freezing point solvents. It is shown that the thermal coefficient of kinematic viscosity as a function of the kinematic viscosity of the solutions of glycerine and ethylene glycol in alcohols is practically independent of the temperature and the chemical composition of the individual liquids. This is similarly true for the mineral oil group and, for a limited temperature interval, for the pure animal and vegetable oils. The efficiency of naphthol, hydroquinone, and diphenylamine to inhibit the change of viscosity of poppyseed and linseed oils was also investigated.

Comparison of liquid-state anomalies in Stillinger-Weber models of water, silicon, and germanium

NASA Astrophysics Data System (ADS)

Dhabal, Debdas; Chakravarty, Charusita; Molinero, Valeria; Kashyap, Hemant K.

2016-12-01

We use molecular dynamics simulations to compare and contrast the liquid-state anomalies in the Stillinger-Weber models of monatomic water (mW), silicon (Si), and germanium (Ge) over a fairly wide range of temperatures and densities. The relationships between structure, entropy, and mobility, as well as the extent of the regions of anomalous behavior, are discussed as a function of the degree of tetrahedrality. We map out the cascade of density, structural, pair entropy, excess entropy, viscosity, and diffusivity anomalies for these three liquids. Among the three liquids studied here, only mW displays anomalies in the thermal conductivity, and this anomaly is evident only at very low temperatures. Diffusivity and viscosity, on the other hand, show pronounced anomalous regions for the three liquids. The temperature of maximum density of the three liquids shows re-entrant behavior consistent with either singularity-free or liquid-liquid critical point scenarios proposed to explain thermodynamic anomalies. The order-map, which shows the evolution of translational versus tetrahedral order in liquids, is different for Ge than for Si and mW. We find that although the monatomic water reproduces several thermodynamic and dynamic properties of rigid-body water models (e.g., SPC/E, TIP4P/2005), its sequence of anomalies follows, the same as Si and Ge, the silica-like hierarchy: the region of dynamic (diffusivity and viscosity) anomalies encloses the region of structural anomalies, which in turn encloses the region of density anomaly. The hierarchy of the anomalies based on excess entropy and Rosenfeld scaling, on the other hand, reverses the order of the structural and dynamic anomalies, i.e., predicts that the three Stillinger-Weber liquids follow a water-like hierarchy of anomalies. We investigate the scaling of diffusivity, viscosity, and thermal conductivity with the excess entropy of the liquid and find that for dynamical properties that present anomalies there is no universal scaling of the reduced property with excess entropy for the whole range of temperatures and densities. Instead, Rosenfeld's scaling holds for all the three liquids at high densities and high temperatures, although deviations from simple exponential dependence are observed for diffusivity and viscosity at lower temperatures and intermediate densities. The slope of the scaling of transport properties obtained for Ge is comparable to that obtained for simple liquids, suggesting that this low tetrahedrality liquid, although it stabilizes a diamond crystal, is already close to simple liquid behavior for certain properties.

Comparison of liquid-state anomalies in Stillinger-Weber models of water, silicon, and germanium.

PubMed

Dhabal, Debdas; Chakravarty, Charusita; Molinero, Valeria; Kashyap, Hemant K

2016-12-07

We use molecular dynamics simulations to compare and contrast the liquid-state anomalies in the Stillinger-Weber models of monatomic water (mW), silicon (Si), and germanium (Ge) over a fairly wide range of temperatures and densities. The relationships between structure, entropy, and mobility, as well as the extent of the regions of anomalous behavior, are discussed as a function of the degree of tetrahedrality. We map out the cascade of density, structural, pair entropy, excess entropy, viscosity, and diffusivity anomalies for these three liquids. Among the three liquids studied here, only mW displays anomalies in the thermal conductivity, and this anomaly is evident only at very low temperatures. Diffusivity and viscosity, on the other hand, show pronounced anomalous regions for the three liquids. The temperature of maximum density of the three liquids shows re-entrant behavior consistent with either singularity-free or liquid-liquid critical point scenarios proposed to explain thermodynamic anomalies. The order-map, which shows the evolution of translational versus tetrahedral order in liquids, is different for Ge than for Si and mW. We find that although the monatomic water reproduces several thermodynamic and dynamic properties of rigid-body water models (e.g., SPC/E, TIP4P/2005), its sequence of anomalies follows, the same as Si and Ge, the silica-like hierarchy: the region of dynamic (diffusivity and viscosity) anomalies encloses the region of structural anomalies, which in turn encloses the region of density anomaly. The hierarchy of the anomalies based on excess entropy and Rosenfeld scaling, on the other hand, reverses the order of the structural and dynamic anomalies, i.e., predicts that the three Stillinger-Weber liquids follow a water-like hierarchy of anomalies. We investigate the scaling of diffusivity, viscosity, and thermal conductivity with the excess entropy of the liquid and find that for dynamical properties that present anomalies there is no universal scaling of the reduced property with excess entropy for the whole range of temperatures and densities. Instead, Rosenfeld's scaling holds for all the three liquids at high densities and high temperatures, although deviations from simple exponential dependence are observed for diffusivity and viscosity at lower temperatures and intermediate densities. The slope of the scaling of transport properties obtained for Ge is comparable to that obtained for simple liquids, suggesting that this low tetrahedrality liquid, although it stabilizes a diamond crystal, is already close to simple liquid behavior for certain properties.

Plasma viscosity with mass transport in spherical inertial confinement fusion implosion simulations

DOE PAGES

Vold, Erik Lehman; Joglekar, Archis S.; Ortega, Mario I.; ...

2015-11-20

The effects of viscosity and small-scale atomic-level mixing on plasmas in inertial confinement fusion(ICF) currently represent challenges in ICF research. Many current ICF hydrodynamic codes ignore the effects of viscosity though recent research indicates viscosity and mixing by classical transport processes may have a substantial impact on implosion dynamics. In this paper, we have implemented a Lagrangian hydrodynamic code in one-dimensional spherical geometry with plasmaviscosity and mass transport and including a three temperature model for ions, electrons, and radiation treated in a gray radiation diffusion approximation. The code is used to study ICF implosion differences with and without plasmaviscosity andmore » to determine the impacts of viscosity on temperature histories and neutron yield. It was found that plasmaviscosity has substantial impacts on ICF shock dynamics characterized by shock burn timing, maximum burn temperatures, convergence ratio, and time history of neutron production rates. Finally, plasmaviscosity reduces the need for artificial viscosity to maintain numerical stability in the Lagrangian formulation and also modifies the flux-limiting needed for electron thermal conduction.« less

Convection Models for Ice-Water System: Dynamical Investigation of Phase Transition

NASA Astrophysics Data System (ADS)

Allu Peddinti, D.; McNamara, A. K.

2012-12-01

Ever since planetary missions of Voyager and Galileo revealed a dynamically altered surface of the icy moon Europa, a possible subsurface ocean under an icy shell has been speculated and surface features have been interpreted from an interior dynamics perspective. The physics of convection in a two phase water-ice system is governed by a wide set of physical parameters that include melting viscosity of ice, the variation of viscosity due to pressure and temperature, temperature contrast across and tidal heating within the system, and the evolving thickness of each layer. Due to the extreme viscosity contrast between liquid water and solid ice, it is not feasible to model the entire system to study convection. However, using a low-viscosity proxy (higher viscosity than the liquid water but much lower than solid ice) for the liquid phase provides a convenient approximation of the system, and allows for a relatively realistic representation of convection within the ice layer while also providing a self-consistent ice layer thickness that is a function of the thermal state of the system. In order to apply this method appropriately, we carefully examine the upper bound of viscosity required for the low-viscosity proxy to adequately represent the liquid phase. We identify upper bounds on the viscosity of the proxy liquid such that convective dynamics of the ice are not affected by further reductions of viscosity. Furthermore, we investigate how the temperature contrast across the system and viscosity contrast between liquid and ice control ice layer thickness. We also investigate ice shell thickening as a function of cooling, particularly how viscosity affects the conduction-to-convection transition within the ice shell. Finally, we present initial results that investigate the effects that latent heat of fusion (due to the ice-water phase transition) has on ice convection.

INCREASES IN CORE TEMPERATURE COUNTERBALANCE EFFECTS OF HEMOCONCENTRATION ON BLOOD VISCOSITY DURING PROLONGED EXERCISE IN THE HEAT

PubMed Central

Buono, Michael J.; Krippes, Taylor; Kolkhorst, Fred W.; Williams, Alexander T.; Cabrales, Pedro

2015-01-01

Previous studies have reported that blood viscosity is significantly increased following exercise. However, these studies measured both pre- and post-exercise blood viscosity at 37 °C even though core and blood temperatures would be expected to have increased during the exercise. Consequently, the effect of exercise-induced hyperthermia on mitigating change in blood viscosity may have been missed. The purpose of this study was to isolate the effects of exercise-induced hemoconcentration and hyperthermia, as well as determine their combined effects, on blood viscosity. Nine subjects performed 2 h of moderate-intensity exercise in the heat (37 °C, 40% rH), which resulted in significant increases from pre-exercise values for rectal temperature (37.11 ± 0.35 °C to 38.76 ± 0.13 °C), hemoconcentration (hematocrit = 43.6 ± 3.6% to 45.6 ± 3.5%), and dehydration (Δbody weight = −3.6 ± 0.7%). Exercise-induced hemoconcentration significantly (P < 0.05) increased blood viscosity by 9% (3.97 to 4.30 cP at 300 s−1) while exercise-induced hyperthermia significantly decreased blood viscosity by 7% (3.97 to 3.70 cP at 300 s−1). However, when both factors were considered together, there was no overall change in blood viscosity (3.97 to 4.03 cP at 300 s−1). The effects of exercise-induced hemoconcentration, increased plasma viscosity, and increased red blood cell aggregation, all of which increased blood viscosity, were counterbalanced by increased RBC deformability (e.g., RBC membrane shear elastic modulus and elongation index) caused by the hyperthermia. Thus, blood viscosity remained unchanged following prolonged moderate-intensity exercise in the heat. PMID:26682653

Experimental Investigation of the Viscosity of Iron-rich Silicate Melts under Pressure

NASA Astrophysics Data System (ADS)

Edwards, P. M.; Lesher, C. E.; Pommier, A.; O'Dwyer Brown, L.

2017-12-01

The transport properties of silicate melts govern diffusive flow of momentum, heat, and mass in the interior of terrestrial planets. In particular, constraining melt viscosity is critical for dynamic modeling of igneous processes and is thus key to our understanding of magma convection and mixing, melt migration in the mantle, and crystal-liquid fractionation. Among the different constituents of silicate melts, iron is of significant importance as it highly influences some of their properties, such as surface tension, compressibility, and density. We present an experimental study of the viscosity of natural and synthetic iron-rich silicate melts under pressure. In situ falling-sphere measurements of viscosity have been conducted on hedenbergite (CaFeSi2O6) and iron-rich peridotite melts from 1 to 7 GPa and at temperatures between 1750 and 2100 K, using the multi-anvil apparatus at the GSECARS beamline at the Advanced Photon Source, Argonne National Lab. We used double reservoir capsules, with the bottom reservoir containing the sample, while a more refractory material is placed in the upper reservoir (e.g., diopside, enstatite, forsterite). This configuration allows the fall of two rhenium spheres across the sample at different temperatures. Melt viscosity is calculated using Stokes' law and the terminal velocity of the spheres. We observe that melt viscosity slightly decreases with increasing temperature and increasing pressure: for instance, the viscosity of the hedenbergite melt decreases from 1.26 Pa•s to 0.43 Pa•s over the 1 - 3.5 GPa pressure range and between 1820 and 1930 K. Our experimental data are used to develop a viscosity model of iron-rich silicate melts under pressure. Results will be compared with previous viscosity works on iron-free and iron-bearing silicate liquids in order to discuss the effect of iron on melt viscosity and structure at pressure and temperature conditions relevant to terrestrial mantles.

Effect of Bulk Viscosity on the Oscillating Screen Viscometer

NASA Technical Reports Server (NTRS)

Berg, Robert F.; Moldover, Michael R.

1993-01-01

Close to the critical temperature, the bulk viscosity of the xenon sample will exceed the shear viscosity by more than a factor of a billion. Nevertheless, the viscometer's low operating frequency ensures that the only significant force on the oscillating screen will be due to the shear viscosity.

Thermodynamic parameters of bonds in glassy materials from viscosity-temperature relationships.

PubMed

Ojovan, Michael I; Travis, Karl P; Hand, Russell J

2007-10-17

Doremus's model of viscosity assumes that viscous flow in amorphous materials is mediated by broken bonds (configurons). The resulting equation contains four coefficients, which are directly related to the entropies and enthalpies of formation and motion of the configurons. Thus by fitting this viscosity equation to experimental viscosity data these enthalpy and entropy terms can be obtained. The non-linear nature of the equation obtained means that the fitting process is non-trivial. A genetic algorithm based approach has been developed to fit the equation to experimental viscosity data for a number of glassy materials, including SiO 2 , GeO 2 , B 2 O 3 , anorthite, diopside, xNa 2 O-(1-x)SiO 2 , xPbO-(1-x)SiO 2 , soda-lime-silica glasses, salol, and α-phenyl-o-cresol. Excellent fits of the equation to the viscosity data were obtained over the entire temperature range. The fitting parameters were used to quantitatively determine the enthalpies and entropies of formation and motion of configurons in the analysed systems and the activation energies for flow at high and low temperatures as well as fragility ratios using the Doremus criterion for fragility. A direct anti-correlation between fragility ratio and configuron percolation threshold, which determines the glass transition temperature in the analysed materials, was found.

Temperature control and measurement with tunable femtosecond optical tweezers

NASA Astrophysics Data System (ADS)

Mondal, Dipankar; Goswami, Debabrata

2016-09-01

We present the effects of wavelength dependent temperature rise in a femtosecond optical tweezers. Our experiments involve the femtosecond trapping laser tunable from 740-820 nm at low power 25 mW to cause heating in the trapped volume within a homogeneous solution of sub micro-molar concentration of IR dye. The 780 nm high repetition rate laser acts as a resonant excitation source which helps to create the local heating effortlessly within the trapping volume. We have used both position autocorrelation and equipartion theorem to evaluate temperature at different wavelength having different absorption coefficient. Fixing the pulse width in the temporal domain gives constant bandwidth at spatial domain, which makes our system behave as a tunable temperature rise device with high precision. This observation leads us to calculate temperature as well as viscosity within the vicinity of the trapping zone. A mutual energy transfer occurs between the trapped bead and solvents that leads to transfer the thermal energy of solvents into the kinetic energy of the trap bead and vice-versa. Thus hot solvated molecules resulting from resonant and near resonant excitation of trapping wavelength can continuously dissipate heat to the trapped bead which will be reflected on frequency spectrum of Brownian noise exhibited by the bead. Temperature rise near the trapping zone can significantly change the viscosity of the medium. We observe temperature rise profile according to its Gaussian shaped absorption spectrum with different wavelength.

Dielectric spectroscopy for the determination of the glass transition temperature of pharmaceutical solid dispersions.

PubMed

O'Donnell, Kevin P; Woodward, W H Hunter

2015-06-01

The purpose of this study was to evaluate analytical techniques for the measurement of the glass transition temperature of HPMC and formulated solid dispersions thereof. Unmodified samples of various grades of HPMC and solid dispersions of HPMC and itraconazole produced by hot melt extrusion were analyzed by thermomechanical analysis, differential scanning calorimetry, thermally stimulated depolarization current and dielectric spectroscopy. It was found that dielectric spectroscopy offers the best accuracy and reproducibility for analysis of the base HPMC powders regardless of the substitution type or viscosity grade and that the obtained results were not frequency dependent. The results of dielectric measurements of solid dispersions prepared by hot melt extrusion were compared with predicted values of the Gordon-Taylor equation. It was found that time-temperature superposition effects and small molecule frequency dependence makes broadly applying determination of the glass transition temperature in drug dispersions by dielectric spectroscopy prohibitively difficult.

A Liquid-Liquid Transition in an Undercooled Ti-Zr-Ni Liquid

NASA Technical Reports Server (NTRS)

Lee, G. W.; Gangopadhyay, A. K.; Kelton, K. F.; Hyers, R. W.; Rathz, T. J.; Rogers, J. R.

2003-01-01

If crystallization can be avoided, liquids enter a metastable (undercooled) state below their equilibrium liquidus temperatures, TI, finally freezing into a glass below a characteristic temperature called the glass transition temperature, T,. In rare cases, the undercooled liquid may undergo a liquid-liquid phase transition (liquid polymorphism) before entering the glassy state. This has been suggested from experimental studies of HzO and Si4. Such phase transitions have been predicted in some stable liquids, i.e. above TI at atmospheric pressure, for Si02 and BeF;, but these have not been verified experimentally. They have been observed in liquids of P7, Sis and C9, but only under high pressure. All of these transitions are driven by an anomalous density change, i.e. change in local structure, with temperature or pressure. In this letter we present the first experimental evidence for a phase transition in a low viscosity liquid that is not driven by an anomalous density change, but by an approach to a constant configuration state. A maximum in the specific heat at constant pressure, similar to what is normally observed near T,, is reported here for undercooled low viscosity liquids of quasicrystal- forming Ti-Zr-Ni alloys. that includes cooperativity, by incorporating a temperature dependent excitation energy fits the data well, signaling a phase transition.

Two-dimensional modeling of density and thermal structure of dense circumstellar outflowing disks

NASA Astrophysics Data System (ADS)

Kurfürst, P.; Feldmeier, A.; Krtička, J.

2018-06-01

Context. Evolution of massive stars is affected by a significant loss of mass either via (nearly) spherically symmetric stellar winds or by aspherical mass-loss mechanisms, namely the outflowing equatorial disks. However, the scenario that leads to the formation of a disk or rings of gas and dust around massive stars is still under debate. It is also unclear how various forming physical mechanisms of the circumstellar environment affect its shape and density, as well as its kinematic and thermal structure. Aims: We study the hydrodynamic and thermal structure of optically thick, dense parts of outflowing circumstellar disks that may be formed around various types of critically rotating massive stars, for example, Be stars, B[e] supergiant (sgB[e]) stars or Pop III stars. We calculate self-consistent time-dependent models of temperature and density structure in the disk's inner dense region that is strongly affected by irradiation from a rotationally oblate central star and by viscous heating. Methods: Using the method of short characteristics, we specify the optical depth of the disk along the line-of-sight from stellar poles. Within the optically thick dense region with an optical depth of τ > 2/3 we calculate the vertical disk thermal structure using the diffusion approximation while for the optically thin outer layers we assume a local thermodynamic equilibrium with the impinging stellar irradiation. For time-dependent hydrodynamic modeling, we use two of our own types of hydrodynamic codes: two-dimensional operator-split numerical code based on an explicit Eulerian finite volume scheme on a staggered grid, and unsplit code based on the Roe's method, both including full second-order Navier-Stokes shear viscosity. Results: Our models show the geometric distribution and contribution of viscous heating that begins to dominate in the central part of the disk for mass-loss rates higher than Ṁ ≳ 10-10 M⊙ yr-1. In the models of dense viscous disks with Ṁ > 10-8 M⊙ yr-1, the viscosity increases the central temperature up to several tens of thousands of Kelvins, however the temperature rapidly drops with radius and with distance from the disk midplane. The high mass-loss rates and high viscosity lead to instabilities with significant waves or bumps in density and temperature in the very inner disk region. Conclusions: The two-dimensional radial-vertical models of dense outflowing disks including the full Navier-Stokes viscosity terms show very high temperatures that are however limited to only the central disk cores inside the optically thick area, while near the edge of the optically thick region the temperature may be low enough for the existence of neutral hydrogen, for example.

Viscous Dissipation in One-Dimensional Quantum Liquids

DOE Office of Scientific and Technical Information (OSTI.GOV)

Matveev, K. A.; Pustilnik, M.

We develop a theory of viscous dissipation in one-dimensional single-component quantum liquids at low temperatures. Such liquids are characterized by a single viscosity coefficient, the bulk viscosity. We show that for a generic interaction between the constituent particles this viscosity diverges in the zerotemperature limit. In the special case of integrable models, the viscosity is infinite at any temperature, which can be interpreted as a breakdown of the hydrodynamic description. In conclusion, our consideration is applicable to all single-component Galilean- invariant one-dimensional quantum liquids, regardless of the statistics of the constituent particles and the interaction strength.

Viscous Dissipation in One-Dimensional Quantum Liquids

DOE PAGES

Matveev, K. A.; Pustilnik, M.

2017-07-20

We develop a theory of viscous dissipation in one-dimensional single-component quantum liquids at low temperatures. Such liquids are characterized by a single viscosity coefficient, the bulk viscosity. We show that for a generic interaction between the constituent particles this viscosity diverges in the zerotemperature limit. In the special case of integrable models, the viscosity is infinite at any temperature, which can be interpreted as a breakdown of the hydrodynamic description. In conclusion, our consideration is applicable to all single-component Galilean- invariant one-dimensional quantum liquids, regardless of the statistics of the constituent particles and the interaction strength.

Measurement of Xenon Viscosity as a Function of Low Temperature and Pressure

NASA Technical Reports Server (NTRS)

Grisnik, Stanley P.

1998-01-01

The measurement of xenon gas viscosity at low temperatures (175-298 K) and low pressures (350 torr-760 torr) has been performed in support of Hall Thruster testing at NASA Lewis Research Center. The measurements were taken using the capillary flow technique. Viscosity measurements were repeatable to within 3%. The results in this paper are in agreement with data from Hanley and Childs and suggest that the data from Clarke and Smith is approximately 2% low. There are no noticeable pressure effects on xenon absolute viscosity for the pressure range from 350 torr to 760 torr.

Temperature-dependent physical properties of egg white for HIFU applications

NASA Astrophysics Data System (ADS)

Liu, Yunbo; Maruvada, Subha; Herman, Bruce A.; Harris, Gerald R.

2012-10-01

Because egg white denatures at elevated temperature due to its protein content, it has the potential for use as a blood coagulation surrogate in pre-clinical evaluations of thermal therapy procedures such as high intensity focused ultrasound (HIFU) surgery. We therefore have measured the relevant physical properties of egg white, including coagulation temperature, frequency-dependent attenuation, sound speed, viscosity, and thermal properties, as a function of temperature (20 - 95°C). Thermal coagulation and attenuation (5-12 MHz) of cow blood, pig blood, and human blood also were assessed and compared with egg white. For a 30 s thermal exposure, both egg white and blood samples started to denature at 65°C and coagulate into an elastic gel at 85°C. The temperature-dependent parameters were found to be similar to that of the blood samples. For example, the attenuation of egg white ranged from 0.23f1.09 to 2.7f0.5 dB/cm over the 20°C - 95°C range. These results suggest that egg white would make a useful blood mimic for bench testing of therapeutic ultrasound devices.

Thermophysical Properties of Nanoparticle-Enhanced Ionic Liquids (NEILs) Heat-Transfer Fluids

DOE Office of Scientific and Technical Information (OSTI.GOV)

Fox, Elise B.; Visser, Ann E.; Bridges, Nicholas J.

2013-06-20

An experimental investigation was completed on nanoparticle enhanced ionic liquid heat transfer fluids as an alternative to conventional organic based heat transfer fluids (HTFs). These nanoparticle-based HTFs have the potential to deliver higher thermal conductivity than the base fluid without a significant increase in viscosity at elevated temperatures. The effect of nanoparticle morphology and chemistry on thermophysical properties was examined. Whisker shaped nanomaterials were found to have the largest thermal conductivity temperature dependence and were also less likely to agglomerate in the base fluid than spherical shaped nanomaterials.

Galilean-invariant Nosé-Hoover-type thermostats.

PubMed

Pieprzyk, S; Heyes, D M; Maćkowiak, Sz; Brańka, A C

2015-03-01

A new pairwise Nosé-Hoover type thermostat for molecular dynamics (MD) simulations which is similar in construction to the pair-velocity thermostat of Allen and Schmid, [Mol. Simul. 33, 21 (2007)] (AS) but is based on the configurational thermostat is proposed and tested. Both thermostats generate the canonical velocity distribution, are Galilean invariant, and conserve linear and angular momentum. The unique feature of the pairwise thermostats is an unconditional conservation of the total angular momentum, which is important for thermalizing isolated systems and those nonequilibrium bulk systems manifesting local rotating currents. These thermostats were benchmarked against the corresponding Nosé-Hoover (NH) and Braga-Travis prescriptions, being based on the kinetic and configurational definitions of temperature, respectively. Some differences between the shear-rate-dependent shear viscosity from Sllod nonequilibrium MD are observed at high shear rates using the different thermostats. The thermostats based on the configurational temperature produced very similar monotically decaying shear viscosity (shear thinning) with increasing shear rate, while the NH method showed discontinuous shear thinning into a string phase, and the AS method produced a continuous increase of viscosity (shear thickening), after a shear thinning region at lower shear rates. Both pairwise additive thermostats are neither purely kinetic nor configurational in definition, and possible directions for further improvement in certain aspects are discussed.

Galilean-invariant Nosé-Hoover-type thermostats

NASA Astrophysics Data System (ADS)

Pieprzyk, S.; Heyes, D. M.; Maćkowiak, Sz.; Brańka, A. C.

2015-03-01

A new pairwise Nosé-Hoover type thermostat for molecular dynamics (MD) simulations which is similar in construction to the pair-velocity thermostat of Allen and Schmid, [Mol. Simul. 33, 21 (2007), 10.1080/08927020601052856] (AS) but is based on the configurational thermostat is proposed and tested. Both thermostats generate the canonical velocity distribution, are Galilean invariant, and conserve linear and angular momentum. The unique feature of the pairwise thermostats is an unconditional conservation of the total angular momentum, which is important for thermalizing isolated systems and those nonequilibrium bulk systems manifesting local rotating currents. These thermostats were benchmarked against the corresponding Nosé-Hoover (NH) and Braga-Travis prescriptions, being based on the kinetic and configurational definitions of temperature, respectively. Some differences between the shear-rate-dependent shear viscosity from Sllod nonequilibrium MD are observed at high shear rates using the different thermostats. The thermostats based on the configurational temperature produced very similar monotically decaying shear viscosity (shear thinning) with increasing shear rate, while the NH method showed discontinuous shear thinning into a string phase, and the AS method produced a continuous increase of viscosity (shear thickening), after a shear thinning region at lower shear rates. Both pairwise additive thermostats are neither purely kinetic nor configurational in definition, and possible directions for further improvement in certain aspects are discussed.

Transverse transport of Fe3O4-H2O with viscosity variation under pure internal heating

NASA Astrophysics Data System (ADS)

Mehmood, Rashid; Tabassum, R.

2018-05-01

Smart fluids are the fluids whose properties can be changed by applying an electric or a magnetic field. Such type of fluid finds tremendous applications in electronic devices, semi-active dampers, magnetic resonance imaging, in space craft propulsion and many more. This communication addresses water based magneto ferrofluid striking at a stretching surface in an oblique manner. In order to present physically realistic analysis, viscosity is assumed to be dependent upon temperature as well as volume fraction of magnetite nanoparticle. The flow governing problem is altered into nonlinear coupled system of ordinary differential equations via scaling transformation which is then solved numerically by means of Runge-kutta Fehlberg scheme. Impact of sundry parameters such as magnetic field parameter, nanoparticle volume fraction, heat generation parameter and variable viscosity parameter on velocity and temperature profile of magneto ferrofluid is presented graphically and discussed in a physical manner. Practical measures of interest namely skin friction and heat flux at the surface are computed. Streamline patterns are traced out to examine the flow pattern. It is found that skin friction and rate of heat transfer at the wall enhances by strengthening the applied magnetic field. Local heat flux can also be enhanced with increasing the volume fraction of magnetite nanoparticles.

Mechanisms and mechanics of shape loss during supersolidus liquid-phase sintering

NASA Astrophysics Data System (ADS)

Lal, Anand

Rapid sinter densification of relatively coarse prealloyed powders is possible by exceeding the solidus temperature in an approach termed supersolidus liquid phase sintering (SLPS). However, narrow processing windows for densification without distortion often limit this process. The liquid films at the grain boundaries that are responsible for densification also reduce the structural rigidity of components. Hence, components tend to slump under their own weight. Thus, the present study investigates shape loss during SLPS and rationalizes the processing and material factors with regard to separating densification from distortion. Experiments are performed on various prealloyed powders, including bronze, 316L stainless steel, and T15 tool steel. Differential thermal analysis, dilatometry, and in situ video imaging of sintering compacts are used to follow melting, densification, and distortion, respectively. Further, density and dimensional measurements are performed on sintered compacts. Results indicate a dependence of distortion on the sintering temperature and time, compact size, and melting behavior of the alloy. It is shown that the sintering temperature window, where high-density, precise components are obtained, can be widened for 316L stainless steel by boron addition. For the first time, a beam bending technique is used to measure the macroscopic apparent viscosity of semisolid bronze. The viscosity drops with temperature above the solidus and lies in the range of 108 to 106 Pa-s. Additionally, the in situ transverse rupture strength of bronze is measured to demonstrate the softening above the solidus temperature. Further, microstructural measurements are performed to enable correlation with the slumping behavior and viscosity. A model combining the deformation mechanisms, driving forces, and microstructural characteristics is developed to predict the conditions for densification and distortion onset. The microstructure is also correlated with the magnitude of shape loss and viscosity of a semisolid aggregate. A mechanistic model, based on the semisolid rheological characteristics, is developed to predict the magnitude and nature of shape loss. The model shows good correlation with experimental data for bronze. This study offers critical insight into SLPS and provides processing strategies for fabrication of high-density components without shape loss.

Selected Thermophysical Properties of 2,2 Dimethylcyclopentyl Methylphosphonofluoridate (GP) and 2,2 Dimethylcyclopentanol (DMCP)

DTIC Science & Technology

2016-09-01

Thermophysical properties, including vapor pressure, density, viscosity, surface tension, and flash point, are reported for 2,2-dimethylcyclopentyl...methylphosphonofluoridate (GP; Chemical Abstracts Service [CAS] no. 453574-97-5). Density data above the melting point, and vapor pressure of the liquid and solid...experimental vapor pressure data and were used to calculate the temperature-dependent enthalpy of vaporization , volatility, and entropy of

Diffusion in Zinc at High Pressure and Rheology of the Earth's Inner Core

NASA Astrophysics Data System (ADS)

Keshav, S.; van Orman, J. A.

2004-12-01

An attempt has been made here to estimate the viscosity of the Earth's inner core, and also to identify the primary mechanism by which the inner core deforms. Estimation of the viscosity and identification of the deformation mechanism(s) of the inner core require measurements of diffusion in the hcp (hexagonal close-packed, or epsilon) phase of iron, suggested to be stable at the Earth's inner-core pressure conditions. However, owing largely to experimental and analytical challenges, actual measurements on the diffusivity in this phase are non-existent. To overcome this problem, we have focused on the divalent transition metal, zinc (Zn), which has the hcp structure over a wide range of pressures. Hcp metals are known to have similar diffusivities at the same homologous temperature. A primary goal of this work was to explore the effect of increasing pressure on diffusion in zinc. Zinc has high compressibility, allowing diffusion measurements to be made on normalized pressures (P/K, pressure/bulk modulus) approaching those of Earth's core. We focused on diffusion of gold (Au), which has been extensively studied at atmospheric pressure. We find that with increasing pressure from 10 to 25 GPa, the diffusion coefficient of Au in Zn decreases, and the data at high pressures are in good agreement with that at 1 atm. However, in a plot of log D versus homologous temperature (Tm/T, where Tm is the melting point), the slope besides being slightly shallower, the high-pressure diffusivity values retrieved are higher than predicted from extrapolation of the 1 atm data. This trend is more prominent in plot of log D versus pressure, where instead of being linear, the diffusion coefficient shows a slight parabolic dependence, indicating that the activation volume decreases with pressure. High-pressure diffusivity values are higher than predicted either from homologous temperature scaling, or those retrieved assuming constant activation volume from one atmosphere data. To a good approximation, the inner core is in hydrostatic equilibrium with the surrounding fluid. The shear stress on the inner core is thought to be low, and grain sizes are larger than in the lower mantle. Temperature and pressure both influence the effective viscosity, and their role is often included in rheological models by referring the temperature to the melting temperature, Tm; the pressure dependence enters implicitly through its influence on Tm. Calculated values of viscosity of the Earth's inner core using the experimental philosophy outlined above are at least 8-9 orders of magnitude lower than estimated so far. These low viscosities have important consequences for the origin of seismic anisotropy and diffusion in the inner core. On the basis of these measurements, it appears that the inner core can quickly erase memory of deformation that occurred early in its history. Thus, search for alternative explanations of the anisotropy is required. Unraveling the clues left behind by the growth of the inner core offers the hope of new insights into the evolution of the Earth's deep interior.

GLASS VISCOSITY AS A FUNCTION OF TEMPERATURE AND COMPOSITION: A MODEL BASED ON ADAM-GIBBS EQUATION

DOE Office of Scientific and Technical Information (OSTI.GOV)

Hrma, Pavel R.

2008-07-01

Within the temperature range and composition region of processing and product forming, the viscosity of commercial and waste glasses spans over 12 orders of magnitude. This paper shows that a generalized Adam-Gibbs relationship reasonably approximates the real behavior of glasses with four temperature-independent parameters of which two are linear functions of the composition vector. The equation is subjected to two constraints, one requiring that the viscosity-temperature relationship approaches the Arrhenius function at high temperatures with a composition-independent pre-exponential factor and the other that the viscosity value is independent of composition at the glass-transition temperature. Several sets of constant coefficients weremore » obtained by fitting the generalized Adam-Gibbs equation to data of two glass families: float glass and Hanford waste glass. Other equations (the Vogel-Fulcher-Tammann equation, original and modified, the Avramov equation, and the Douglass-Doremus equation) were fitted to float glass data series and compared with the Adam-Gibbs equation, showing that Adam-Gibbs glass appears an excellent approximation of real glasses even as compared with other candidate constitutive relations.« less

Viscosity, conductivity, and electrochemical property of dicyanamide ionic liquids

NASA Astrophysics Data System (ADS)

Yuan, Wen-Li; Yang, Xiao; He, Ling; Xue, Ying; Qin, Song; Tao, Guo-Hong

2018-03-01

The instructive structure-property relationships of ionic liquids (ILs) can be put to task-specific design of new functionalized ILs. The dicyanamide (DCA) ILs are typical CHN type ILs which are halogen free, chemical stable, low-viscous and fuel-rich. The transport properties of DCA ionic liquids are significant for their applications as solvents, electrolytes and hypergolic propellants. This work systematically investigates several important transport properties of four DCA ILs ([C4mim][N(CN)2], [C4m2im][N(CN)2], N4442[N(CN)2], and N8444[N(CN)2]) including viscosity, conductivity, and electrochemical property at different temperatures. The melting points, temperature-dependent viscosities and conductivities reveal the structure-activity relationship of four DCA ILs. From the Walden plots, the imidazolium cations exhibit stronger cation–anion attraction than the ammonium cations. DCA ILs have relatively high values of electrochemical windows (EWs), which indicates that the DCA ILs are potential candidates for electrolytes in electrochemical applications. The cyclic voltammograms of Eu(III) in these DCA ILs at GC working electrode at various temperatures 303–333 K consists of quasi-reversible waves. The electrochemical properties of the DCA ILs are also dominated by the cationic structures. The current intensity (ip), the diffusion coefficients (Do), the charge transfer rate constants (ks) of Eu(III) in DCA ILs all increased with the molar conductivities increased. The cationic structure-transport property relationships of DCA ILs were constructed for designing novel functionalized ILs to fulfill specific demands.

Viscosity, Conductivity, and Electrochemical Property of Dicyanamide Ionic Liquids

PubMed Central

Yuan, Wen-Li; Yang, Xiao; He, Ling; Xue, Ying; Qin, Song; Tao, Guo-Hong

2018-01-01

The instructive structure-property relationships of ionic liquids (ILs) can be put to task-specific design of new functionalized ILs. The dicyanamide (DCA) ILs are typical CHN type ILs which are halogen free, chemical stable, low-viscous, and fuel-rich. The transport properties of DCA ionic liquids are significant for their applications as solvents, electrolytes, and hypergolic propellants. This work systematically investigates several important transport properties of four DCA ILs ([C4mim][N(CN)2], [C4m2im][N(CN)2], N4442[N(CN)2], and N8444[N(CN)2]) including viscosity, conductivity, and electrochemical property at different temperatures. The melting points, temperature-dependent viscosities and conductivities reveal the structure-activity relationship of four DCA ILs. From the Walden plots, the imidazolium cations exhibit stronger cation–anion attraction than the ammonium cations. DCA ILs have relatively high values of electrochemical windows (EWs), which indicates that the DCA ILs are potential candidates for electrolytes in electrochemical applications. The cyclic voltammograms of Eu(III) in these DCA ILs at GC working electrode at various temperatures 303–333 K consists of quasi-reversible waves. The electrochemical properties of the DCA ILs are also dominated by the cationic structures. The current intensity (ip), the diffusion coefficients (Do), the charge transfer rate constants (ks) of Eu(III) in DCA ILs all increased with the molar conductivities increased. The cationic structure-transport property relationships of DCA ILs were constructed for designing novel functionalized ILs to fulfill specific demands. PMID:29600245

Liquid Aluminum: Atomic diffusion and viscosity from ab initio molecular dynamics

PubMed Central

Jakse, Noel; Pasturel, Alain

2013-01-01

We present a study of dynamic properties of liquid aluminum using density-functional theory within the local-density (LDA) and generalized gradient (GGA) approximations. We determine the temperature dependence of the self-diffusion coefficient as well the viscosity using direct methods. Comparisons with experimental data favor the LDA approximation to compute dynamic properties of liquid aluminum. We show that the GGA approximation induce more important backscattering effects due to an enhancement of the icosahedral short range order (ISRO) that impact directly dynamic properties like the self-diffusion coefficient. All these results are then used to test the Stokes-Einstein relation and the universal scaling law relating the diffusion coefficient and the excess entropy of a liquid. PMID:24190311

Surface topography due to convection in a variable viscosity fluid - Application to short wavelength gravity anomalies in the central Pacific Ocean

NASA Technical Reports Server (NTRS)

Lin, J.; Parmentier, E. M.

1985-01-01

Finite difference calculations of thermal convection in a fluid layer with a viscosity exponentially decreasing with temperature are performed in the context of examining the topography and gravity anomalies due to mantle convection. The surface topography and gravity anomalies are shown to be positive over regions of ascending flow and negative over regions of descending flow; at large Rayleigh numbers the amplitude of surface topography is inferred to depend on Rayleigh number to the power of 7/9. Compositional stratifications of the mantle is proposed as a mechanism for confining small-scale convection to a thin layer. A comparative analysis of the results with other available models is included.

Production and Characterization of a Polymer from Arthrobacter sp.

PubMed

Bodie, E A; Schwartz, R D; Catena, A

1985-09-01

An Arthrobacter sp. isolated from a glucose-sucrose agar plate was found to produce a neutral, extremely viscous, opalescent extracellular polymer. Growth, polymer production, and rheological properties and chemical composition of the isolated polymer were examined. The polymer was found to be substantially different from other arthrobacter polymers. Some unusual properties included irreversible loss of viscosity with high temperature and degradation of the polymer during fermentation and upon storage at 4 degrees C. Other characteristics included dependence on sucrose for polymer production, relative pH stability, increased viscosity with increased salt concentration, and pseudoplasticity. The polymer was found to be composed primarily (if not entirely) of d-fructose. The fructose content and other characteristics suggested that the polymer was a levan.

Production and Characterization of a Polymer from Arthrobacter sp

PubMed Central

Bodie, Elizabeth A.; Schwartz, Robert D.; Catena, Anthony

1985-01-01

An Arthrobacter sp. isolated from a glucose-sucrose agar plate was found to produce a neutral, extremely viscous, opalescent extracellular polymer. Growth, polymer production, and rheological properties and chemical composition of the isolated polymer were examined. The polymer was found to be substantially different from other arthrobacter polymers. Some unusual properties included irreversible loss of viscosity with high temperature and degradation of the polymer during fermentation and upon storage at 4°C. Other characteristics included dependence on sucrose for polymer production, relative pH stability, increased viscosity with increased salt concentration, and pseudoplasticity. The polymer was found to be composed primarily (if not entirely) of d-fructose. The fructose content and other characteristics suggested that the polymer was a levan. PMID:16346883

Titin Based Viscosity in Ventricular Physiology: An Integrative Investigation of PEVK-Actin Interactions

PubMed Central

Chung, Charles S; Methawasin, Methajit; Nelson, O Lynne; Radke, Michael H; Hidalgo, Carlos G; Gotthardt, Michael; Granzier, Henk L

2011-01-01

Viscosity is proposed to modulate diastolic function, but only limited understanding of the source(s) of viscosity exists. In-vitro experiments have shown that the proline-glutamic acid-valine-lysine (PEVK) rich element of titin interacts with actin, causing a viscous force in the sarcomere. It is unknown whether this mechanism contributes to viscosity in-vivo. We tested the hypothesis that PEVK-actin interaction causes cardiac viscosity and is important in-vivo via an integrative physiological study on a unique PEVK-knockout (KO) model. Both skinned cardiomyocytes and papillary muscle fibers were isolated from wildtype (WT) and PEVK KO mice and passive viscosity was examined using stretch-hold-release and sinusoidal analysis. Viscosity was reduced by ~60% in KO myocytes and ~50% in muscle fibers at room temperature. The PEVK-actin interaction was not modulated by temperature or diastolic calcium, but was increased by lattice compression. Stretch-hold and sinusoidal frequency protocols on intact isolated mouse hearts showed a smaller, 30–40% reduction in viscosity, possibly due to actomyosin interactions, and showed that microtubules did not contribute to viscosity. Transmitral Doppler echocardiography similarly revealed a 40% decrease in LV chamber viscosity in the PEVK KO in-vivo. This integrative study is the first to quantify the influence of a specific molecular (PEVK-actin) viscosity in-vivo and shows that PEVK-actin interactions are an important physiological source of viscosity. PMID:21708170

Stokes–Einstein relation and excess entropy in Al-rich Al-Cu melts

DOE Office of Scientific and Technical Information (OSTI.GOV)

Pasturel, A.; Jakse, N.

We investigate the conditions for the validity of the Stokes-Einstein relation that connects diffusivity to viscosity in melts using entropy-scaling relationships developed by Rosenfeld. Employing ab initio molecular dynamics simulations to determine transport and structural properties of liquid Al{sub 1−x}Cu{sub x} alloys (with composition x ≤ 0.4), we first show that reduced self-diffusion coefficients and viscosities, according to Rosenfeld's formulation, scale with the two-body approximation of the excess entropy except the reduced viscosity for x = 0.4. Then, we use our findings to evidence that the Stokes-Einstein relation using effective atomic radii is not valid in these alloys while its validity can be relatedmore » to the temperature dependence of the partial pair-excess entropies of both components. Finally, we derive a relation between the ratio of the self-diffusivities of the components and the ratio of their pair excess entropies.« less

Analysis of rheological properties of bone cements.

PubMed

Nicholas, M K D; Waters, M G J; Holford, K M; Adusei, G

2007-07-01

The rheological properties of three commercially available bone cements, CMW 1, Palacos R and Cemex ISOPLASTIC, were investigated. Testing was undertaken at both 25 and 37 degrees C using an oscillating parallel plate rheometer. Results showed that the three high viscosity cements exhibited distinct differences in curing rate, with CMW 1 curing in 8.7 min, Palacos R and Cemex ISOPLASTIC in 13 min at 25 degrees C. Furthermore it was found that these curing rates were strongly temperature dependent, with curing rates being halved at 37 degrees C. By monitoring the change of viscosity with time over the entire curing process, the results showed that these cements had differing viscosity profiles and hence exhibit very different handling characteristics. However, all the cements reached the same maximum viscosity of 75 x 10(3) Pa s. Also, the change in elastic/viscous moduli and tan delta with time, show the cements changing from a viscous material to an elastic solid with a clear peak in the viscous modulus during the latter stages of curing. These results give valuable information about the changes in rheological properties for each commercial bone cement, especially during the final curing process.

Measuring the Viscosity of the Escherichia coli Plasma Membrane Using Molecular Rotors.

PubMed

Mika, Jacek T; Thompson, Alexander J; Dent, Michael R; Brooks, Nicholas J; Michiels, Jan; Hofkens, Johan; Kuimova, Marina K

2016-10-04

The viscosity is a highly important parameter within the cell membrane, affecting the diffusion of small molecules and, hence, controlling the rates of intracellular reactions. There is significant interest in the direct, quantitative assessment of membrane viscosity. Here we report the use of fluorescence lifetime imaging microscopy of the molecular rotor BODIPY C10 in the membranes of live Escherichia coli bacteria to permit direct quantification of the viscosity. Using this approach, we investigated the viscosity in live E. coli cells, spheroplasts, and liposomes made from E. coli membrane extracts. For live cells and spheroplasts, the viscosity was measured at both room temperature (23°C) and the E. coli growth temperature (37°C), while the membrane extract liposomes were studied over a range of measurement temperatures (5-40°C). At 37°C, we recorded a membrane viscosity in live E. coli cells of 950 cP, which is considerably higher than that previously observed in other live cell membranes (e.g., eukaryotic cells, membranes of Bacillus vegetative cells). Interestingly, this indicates that E. coli cells exhibit a high degree of lipid ordering within their liquid-phase plasma membranes. Copyright © 2016 Biophysical Society. Published by Elsevier Inc. All rights reserved.

Thermal conductivity and viscosity measurements of ethylene glycol-based Al2O3 nanofluids

NASA Astrophysics Data System (ADS)

Pastoriza-Gallego, María José; Lugo, Luis; Legido, José Luis; Piñeiro, Manuel M.

2011-12-01

The dispersion and stability of nanofluids obtained by dispersing Al2O3 nanoparticles in ethylene glycol have been analyzed at several concentrations up to 25% in mass fraction. The thermal conductivity and viscosity were experimentally determined at temperatures ranging from 283.15 K to 323.15 K using an apparatus based on the hot-wire method and a rotational viscometer, respectively. It has been found that both thermal conductivity and viscosity increase with the concentration of nanoparticles, whereas when the temperature increases the viscosity diminishes and the thermal conductivity rises. Measured enhancements on thermal conductivity (up to 19%) compare well with literature values when available. New viscosity experimental data yield values more than twice larger than the base fluid. The influence of particle size on viscosity has been also studied, finding large differences that must be taken into account for any practical application. These experimental results were compared with some theoretical models, as those of Maxwell-Hamilton and Crosser for thermal conductivity and Krieger and Dougherty for viscosity.

Correlation between electrical, mechanical and chemical properties of fresh and used aircraft engine oils

NASA Astrophysics Data System (ADS)

Gajewski, Juliusz B.; Głogowski, Marek J.; Paszkowski, Maciej; Czarnik-Matusewicz, Bogusława

2011-06-01

In this paper the results are presented of measurements of electrical, mechanical and chemical properties of fresh and used aircraft engine oils. Oils were used in a four-stroke aircraft engine and their samples were taken after the 50-hour work of the engine. The resistivity, permittivity and viscosity of oils were measured as a function of temperature. Additionally, some measurements of the absorbance spectra and size of particles contained in the oils were carried out. The significant reduction in the resistivity of the used Total oil was observed. The relative permittivity of both used oils was slightly increased. The oil's relative viscosity depends on temperature of oil and given time that elapsed from the very first moment when the shear force was applied in a rheometer. The results obtained allowed one to identify more precisely the chemical and physico-chemical interactions occurring in the tested samples, as compared with a typical infrared spectroscopy.

Studies on chemoviscosity modeling for thermosetting resins

NASA Technical Reports Server (NTRS)

Bai, J. M.; Hou, T. H.; Tiwari, S. N.

1987-01-01

A new analytical model for simulating chemoviscosity of thermosetting resins has been formulated. The model is developed by modifying the well-established Williams-Landel-Ferry (WLF) theory in polymer rheology for thermoplastic materials. By introducing a relationship between the glass transition temperature Tg(t) and the degree of cure alpha(t) of the resin system under cure, the WLF theory can be modified to account for the factor of reaction time. Temperature dependent functions of the modified WLF theory constants C sub 1 (t) and C sub 2 (t) were determined from the isothermal cure data. Theoretical predictions of the model for the resin under dynamic heating cure cycles were shown to compare favorably with the experimental data. This work represents progress toward establishing a chemoviscosity model which is capable of not only describing viscosity profiles accurately under various cure cycles, but also correlating viscosity data to the changes of physical properties associated with the structural transformation of the thermosetting resin systems during cure.

Chemoviscosity modeling for thermosetting resin systems, part 3

NASA Technical Reports Server (NTRS)

Hou, T. H.; Bai, J. M.

1988-01-01

A new analytical model for simulating chemoviscosity resin has been formulated. The model is developed by modifying the well established Williams-Landel-Ferry (WLF) theory in polymer rheology for thermoplastic materials. By introducing a relationship between the glass transition temperature (T sub g (t)) and the degree of cure alpha(t) of the resin system under cure, the WLF theory can be modified to account for the factor of reaction time. Temperature-dependent functions of the modified WLF theory parameters C sub 1 (T) and C sub 2 (T) were determined from the isothermal cure data. Theoretical predictions of the model for the resin under dynamic heating cure cycles were shown to compare favorably with the experimental data. This work represents a progress toward establishing a chemoviscosity model which is capable of not only describing viscosity profiles accurately under various cure cycles, but also correlating viscosity data to the changes of physical properties associated with the structural transformations of the thermosetting resin systems during cure.

Is the boundary layer of an ionic liquid equally lubricating at higher temperature?

PubMed

Hjalmarsson, Nicklas; Atkin, Rob; Rutland, Mark W

2016-04-07

Atomic force microscopy has been used to study the effect of temperature on normal forces and friction for the room temperature ionic liquid (IL) ethylammonium nitrate (EAN), confined between mica and a silica colloid probe at 25 °C, 50 °C, and 80 °C. Force curves revealed a strong fluid dynamic influence at room temperature, which was greatly reduced at elevated temperatures due to the reduced liquid viscosity. A fluid dynamic analysis reveals that bulk viscosity is manifested at large separation but that EAN displays a nonzero slip, indicating a region of different viscosity near the surface. At high temperatures, the reduction in fluid dynamic force reveals step-like force curves, similar to those found at room temperature using much lower scan rates. The ionic liquid boundary layer remains adsorbed to the solid surface even at high temperature, which provides a mechanism for lubrication when fluid dynamic lubrication is strongly reduced. The friction data reveals a decrease in absolute friction force with increasing temperature, which is associated with increased thermal motion and reduced viscosity of the near surface layers but, consistent with the normal force data, boundary layer lubrication was unaffected. The implications for ILs as lubricants are discussed in terms of the behaviour of this well characterised system.

Comparison of 2-3D convection models with parameterized thermal evolution models: Application to Mars

NASA Astrophysics Data System (ADS)

Thiriet, M.; Plesa, A. C.; Breuer, D.; Michaut, C.

2017-12-01

To model the thermal evolution of terrestrial planets, 1D parametrized models are often used as 2 or 3D mantle convection codes are very time-consuming. In these parameterized models, scaling laws that describe the convective heat transfer rate as a function of the convective parameters are derived from 2-3D steady state convection models. However, so far there has been no comprehensive comparison whether they can be applied to model the thermal evolution of a cooling planet. Here we compare 2D and 3D thermal evolution models in the stagnant lid regime with 1D parametrized models and use parameters representing the cooling of the Martian mantle. For the 1D parameterized models, we use the approach of Grasset and Parmentier (1998) and treat the stagnant lid and the convecting layer separately. In the convecting layer, the scaling law for a fluid with constant viscosity is valid with Nu (Ra/Rac) ?, with Rac the critical Rayleigh number at which the thermal boundary layers (TBL) - top or bottom - destabilize. ? varies between 1/3 and 1/4 depending on the heating mode and previous studies have proposed intermediate values of b 0.28-0.32 according to their model set-up. The base of the stagnant lid is defined by the temperature at which the mantle viscosity has increased by a factor of 10; it thus depends on the rate of viscosity change with temperature multiplied by a factor? , whose value appears to vary depending on the geometry and convection conditions. In applying Monte Carlo simulations, we search for the best fit to temperature profiles and heat flux using three free parameters, i.e. ? of the upper TBL, ? and the Rac of the lower TBL. We find that depending on the definition of the stagnant lid thickness in the 2-3D models several combinations of ? and ? for the upper TBL can retrieve suitable fits. E.g. combinations of ? = 0.329 and ? = 2.19 but also ? = 0.295 and ? = 2.97 are possible; Rac of the lower TBL is 10 for all best fits. The results show that although the heating conditions change from bottom to mainly internally heating as a function of time, the thermal evolution can be represented by one set of parameters.

High pressure study of viscosity and temperature effects on tetracyanobenzene EDA complexes

NASA Astrophysics Data System (ADS)

Thomas, Michele Moisio; Drickamer, H. G.

1981-12-01

High pressure fluorescence studies from 0-10 kbar have been performed on electron donor-acceptor (EDA) complexes of s-tetracyanobenzene (TCNB) with a series of aromatic hydrocarbons. Four solvents were used: 2,2,4,4,6,8,8-heptamethylnonane (HMN), methylcyclohexane (MCH), 2,6,10,14-tetramethylpentadecane (TMPD), and a mixture of MCH and HMN. A viscosity range from 0.006 to 10 000 P was covered at two temperatures: 0 and 25 °C. As pressure (viscosity) increased the fluorescence spectrum shifted from one dominated by emission from the equilibrium (EQ) excited singlet state to one dominated by Franck-Condon (FC) singlet emission. Lifetime measurements for the complexes of o-xylene and p-xylene with TCNB yielded the two radiative rates (kEQ and kFC) as well as the rate of relaxation from FC to the EQ excited state (kRE). kRE was found to correlate well with viscosity and to be independent of temperature at constant viscosity, indicating that the relaxation process is diffusion controlled.

Flow effects in a vertical CVD reactor

NASA Technical Reports Server (NTRS)

Young, G. W.; Hariharan, S. I.; Carnahan, R.

1992-01-01

A model is presented to simulate the non-Boussinesq flow in a vertical, two-dimensional, chemical vapor deposition reactor under atmospheric pressure. Temperature-dependent conductivity, mass diffusivity, viscosity models, and reactive species mass transfer to the substrate are incorporated. In the limits of small Mach number and small aspect ratio, asymptotic expressions for the flow, temperature, and species fields are developed. Soret diffusion effects are also investigated. Analytical solutions predict an inverse relationship between temperature field and concentration field due to Soret effects. This finding is consistent with numerical simulations, assisting in the understanding of the complex interactions amongst the flow, thermal, and species fields in a chemically reacting system.

Viscosity of two-dimensional strongly coupled dusty plasma modified by a perpendicular magnetic field

NASA Astrophysics Data System (ADS)

Feng, Yan; Lin, Wei; Murillo, M. S.

2017-11-01

Transport properties of two-dimensional (2D) strongly coupled dusty plasmas have been investigated in detail, but never for viscosity with a strong perpendicular magnetic field; here, we examine this scenario using Langevin dynamics simulations of 2D liquids with a binary Yukawa interparticle interaction. The shear viscosity η of 2D liquid dusty plasma is estimated from the simulation data using the Green-Kubo relation, which is the integration of the shear stress autocorrelation function. It is found that, when a perpendicular magnetic field is applied, the shear viscosity of 2D liquid dusty plasma is modified substantially. When the magnetic field is increased, its viscosity increases at low temperatures, while at high temperatures its viscosity diminishes. It is determined that these different variational trends of η arise from the different behaviors of the kinetic and potential parts of the shear stress under external magnetic fields.

Influence of Functional Groups on the Viscosity of Organic Aerosol.

PubMed

Rothfuss, Nicholas E; Petters, Markus D

2017-01-03

Organic aerosols can exist in highly viscous or glassy phase states. A viscosity database for organic compounds with atmospherically relevant functional groups is compiled and analyzed to quantify the influence of number and location of functional groups on viscosity. For weakly functionalized compounds the trend in viscosity sensitivity to functional group addition is carboxylic acid (COOH) ≈ hydroxyl (OH) > nitrate (ONO 2 ) > carbonyl (CO) ≈ ester (COO) > methylene (CH 2 ). Sensitivities to group addition increase with greater levels of prior functionalization and decreasing temperature. For carboxylic acids a sharp increase in sensitivity is likely present already at the second addition at room temperature. Ring structures increase viscosity relative to linear structures. Sensitivities are correlated with analogously derived sensitivities of vapor pressure reduction. This may be exploited in the future to predict viscosity in numerical models by piggybacking on schemes that track the evolution of organic aerosol volatility with age.

Measurement and modeling of density and viscosity of n-octanol-kerosene-phosphoric acid solutions in a temperature range 293.15-333.15 K

NASA Astrophysics Data System (ADS)

Ye, Changwen; Pei, Xiangjun; Liu, J. C.

2016-12-01

Densities and viscosities have been measured for the n-octanol + aviation kerosene (AK) + phosphoric acid (H3PO4) system with the mass fraction of H3PO4 in the range from w = 0 to 0.26 and in the temperature of 293.15-333.15 K. According to the experimental data, the measured viscosities were found well correlated with the temperature and mass fraction of H3PO4, which were fitted to regression equations. The result shows that the dilution effect of AK is obvious under the same temperature and mass fraction of H3PO4.

Monitoring cure of composite resins using frequency dependent electromagnetic sensing techniques

NASA Technical Reports Server (NTRS)

Kranbuehl, D. E.; Hoff, M. S.; Loos, A. C.; Freeman, W. T., Jr.; Eichinger, D. A.

1988-01-01

A nondestructive in situ measurement technique has been developed for monitoring and measuring the cure processing properties of composite resins. Frequency dependent electromagnetic sensors (FDEMS) were used to directly measure resin viscosity during cure. The effects of the cure cycle and resin aging on the viscosity during cure were investigated using the sensor. Viscosity measurements obtained using the sensor are compared with the viscosities calculated by the Loos-Springer cure process model. Good overall agreement was obtained except for the aged resin samples.

Fluid dynamics of the magnetic field dependent thermosolutal convection and viscosity between coaxial contracting discs

NASA Astrophysics Data System (ADS)

Khan, Aamir; Shah, Rehan Ali; Shuaib, Muhammad; Ali, Amjad

2018-06-01

The effects of magnetic field dependent (MFD) thermosolutal convection and MFD viscosity of the fluid dynamics are investigated between squeezing discs rotating with different velocities. The unsteady constitutive expressions of mass conservation, modified Navier-Stokes, Maxwell and MFD thermosolutal convection are coupled as a system of ordinary differential equations. The corresponding solutions for the transformed radial and azimuthal momentum as well as solutions for the azimuthal and axial induced magnetic field equations are determined, also the MHD pressure and torque which the fluid exerts on the upper disc is derived and discussed in details. In the case of smooth discs the self-similar equations are solved using Homotopy Analysis Method (HAM) with appropriate initial guesses and auxiliary parameters to produce an algorithm with an accelerated and assured convergence. The validity and accuracy of HAM results is proved by comparison of the HAM solutions with numerical solver package BVP4c. It has been shown that magnetic Reynolds number causes to decrease magnetic field distributions, fluid temperature, axial and tangential velocity. Also azimuthal and axial components of magnetic field have opposite behavior with increase in MFD viscosity. Applications of the study include automotive magneto-rheological shock absorbers, novel aircraft landing gear systems, heating up or cooling processes, biological sensor systems and biological prosthetic etc.

How can we constrain the amount of heat producing elements in the interior of Mars?

NASA Astrophysics Data System (ADS)

Grott, M.; Plesa, A.; Breuer, D.

2013-12-01

The InSight (Interior Exploration using Seismic Investigations, Geodesy and Heat Transport) mission to be launched in 2016 will study Mars' deep interior and help improving our knowledge about the interior structure and the thermal evolution of the planet - the latter is also directly linked to its volcanic history and atmospheric evolution. Measurements planned with the two main instruments, SEIS (Seismic Experiment for Interior Structure) and HP3 (Heat Flow and Physical Properties Package) aim to constrain the main structure of the planet, i.e. core, mantle and crust as well as the rate at which the planet loses the interior heat over its surface. Since the surface heat flow depends on the amount of radiogenic heat elements (HPE) present in the interior, it offers a measurable quantity which could constrain the heat budget. Being the principal agent regulating the heat budget which in turn influences partial melting in the interior, crustal and atmospheric evolution, the heat producing elements have a major impact on the entire the present temperature thermal history of the planet. To constrain the radiogenic heat elements of the planet from the surface heat flow is possible assuming that the urey number of the planet, which describes the contribution of internal heat production to the surface heat loss, is known. We have tested this assumption by calculating the thermal evolution of the planet with fully dynamical numerical simulations and by comparing the obtained present-day urey number for a set of different models/parameters (Fig. 1). For one-plate planets like Mars, numerical models show - in contrast to models for the Earth, where plate tectonics play a major role adding more complexity to the system - that the urey ratio is mainly sensitive to two effects: the efficiency of cooling due to the temperature-dependence of the viscosity and the mean half-life time of the long lived radiogenic isotopes. The temperature-dependence of the viscosity results in the so-called thermostat effect regulating the interior temperature such that the present-day temperatures are independent of the initial temperature distribution. If the thermostat effect is efficient as we show for the assumed Martian mantle rheology, and if the system is not dominated by radioactive isotopes like Thorium with a half-life much longer than the age of the planet as in the model of [3], all numerical simulations show similar today's values for the urey number (Fig. 1). Knowing the surface heat loss from the upcoming heat flow measurements planned for the InSight mission, one can distinguish then between different radiogenic heat source models [1, 2, 3, 4]. REFERENCES [1] Wänke et al., 94; [2] Lodders & Fegley, 97; [3] Morgan & Anders, 79; [4] Treiman et al., 86 Fig. 1: a) the influence of the reference viscosity and initial upper thermal boundary layer (TBL) on the urey ratio using HPE density from [1]; b) different models for HPE density; c) the urey ratio for different HPE models and 1e22 Pa s reference viscosity.

Temperature-Induced Transitions in the Structure and Interfacial Rheology of Human Meibum

PubMed Central

Leiske, Danielle L.; Leiske, Christopher I.; Leiske, Daniel R.; Toney, Michael F.; Senchyna, Michelle; Ketelson, Howard A.; Meadows, David L.; Fuller, Gerald G.

2012-01-01

Meibomian lipids are the primary component of the lipid layer of the tear film. Composed primarily of a mixture of lipids, meibum exhibits a range of melt temperatures. Compositional changes that occur with disease may alter the temperature at which meibum melts. Here we explore how the mechanical properties and structure of meibum from healthy subjects depend on temperature. Interfacial films of meibum were highly viscoelastic at 17°C, but as the films were heated to 30°C the surface moduli decreased by more than two orders of magnitude. Brewster angle microscopy revealed the presence of micron-scale inhomogeneities in meibum films at higher temperatures. Crystalline structure was probed by small angle x-ray scattering of bulk meibum, which showed evidence of a majority crystalline structure in all samples with lamellar spacing of 49 Å that melted at 34°C. A minority structure was observed in some samples with d-spacing at 110 Å that persisted up to 40°C. The melting of crystalline phases accompanied by a reduction in interfacial viscosity and elasticity has implications in meibum behavior in the tear film. If the melt temperature of meibum was altered significantly from disease-induced compositional changes, the resultant change in viscosity could alter secretion of lipids from meibomian glands, or tear-film stabilization properties of the lipid layer. PMID:22339874

Viscosity measurements of crystallizing andesite from Tungurahua volcano (Ecuador).

PubMed

Chevrel, Magdalena Oryaëlle; Cimarelli, Corrado; deBiasi, Lea; Hanson, Jonathan B; Lavallée, Yan; Arzilli, Fabio; Dingwell, Donald B

2015-03-01

Viscosity has been determined during isothermal crystallization of an andesite from Tungurahua volcano (Ecuador). Viscosity was continuously recorded using the concentric cylinder method and employing a Pt-sheathed alumina spindle at 1 bar and from 1400°C to subliquidus temperatures to track rheological changes during crystallization. The disposable spindle was not extracted from the sample but rather left in the sample during quenching thus preserving an undisturbed textural configuration of the crystals. The inspection of products quenched during the crystallization process reveals evidence for heterogeneous crystal nucleation at the spindle and near the crucible wall, as well as crystal alignment in the flow field. At the end of the crystallization, defined when viscosity is constant, plagioclase is homogeneously distributed throughout the crucible (with the single exception of experiment performed at the lowest temperature). In this experiments, the crystallization kinetics appear to be strongly affected by the stirring conditions of the viscosity determinations. A TTT (Time-Temperature-Transformation) diagram illustrating the crystallization "nose" for this andesite under stirring conditions and at ambient pressure has been constructed. We further note that at a given crystal content and distribution, the high aspect ratio of the acicular plagioclase yields a shear-thinning rheology at crystal contents as low as 13 vol %, and that the relative viscosity is higher than predicted from existing viscosity models. These viscosity experiments hold the potential for delivering insights into the relative influences of the cooling path, undercooling, and deformation on crystallization kinetics and resultant crystal morphologies, as well as their impact on magmatic viscosity.

Scaling and Thermal Evolution of Internally Heated Planets: Yield Stress and Thermal History.

NASA Astrophysics Data System (ADS)

Weller, M. B.; Lenardic, A.; Moore, W. B.

2014-12-01

Using coupled 3D mantle convection and planetary tectonics models of bi-stable systems, we show how system behaviors for mobile-lid and stagnant-lid states scale as functions of internal heating rates (Q) and basal Ra (Rab). With parameter ranges for temperature- and depth-dependant viscosities: 1e4 - 3e4, Rab: 1e5- 3e5, Q: 0 - 100, and yield stress: 1e4 - 2e5, it can be shown the internal temperatures, velocities, heat fluxes, and system behaviors for mobile-lid and stagnant-lid states diverge, for equivalent parameter values, as a function of increasing Q. For the mobile-lid regime, yielding behavior in the upper boundary layer strongly influences the dynamics of the system. Internal temperatures, and consequently temperature-dependant viscosities, vary strongly as a function of yield stress for a given Q. The temperature distribution across the upper and lower mantles are sub-adiabatic for low to moderate yield stress, and adiabatic to super-adiabatic for high yield stresses. Across the parameter range considered, and for fixed yield stress, the Nu across the basal boundary (Nub) is positive and only weakly dependant on Q (varies by ~ 9%). Nub varies strongly as a function of yield stress (maximum variation of ~84%). Both mobile-lid velocities and lid-thicknesses are yield stress dependant for a given Q and Ra. In contrast to mobile-lids, the stagnant-lid regime is governed by the relative inefficiency of heat transport through the surface boundary layer. Internal temperatures are yield stress independent, and are on average 30% greater. Nub has a strong dependence on heating rates and surface boundary layer thicknesses. Within the parameter space considered, the maximum stagnant-lid Nub corresponds to the minimum mobile-lid Nub (for high yield stress), and decreases with increasing Q. For high Q, super-heated stagnant-lids may develop, with Nub< 0, and changes in trends for system behaviors. Planets with high levels of internal heating and/or high yield stresses (e.g. Super-Earths), may favor super-heated stagnant-lids early in their evolution. These regimes indicate reduced heat transport efficiencies (from the nominal stagnant-lid), and as a result, increasing heat flux into the core with increasing Q. Implications for terrestrial and Super-Earth planetary evolution will be discussed.

On the resolution of shallow mantle viscosity structure using post-earthquake relaxation data: Application to the 1999 Hector Mine, California, earthquake

USGS Publications Warehouse

Pollitz, Fred F.; Thatcher, Wayne R.

2010-01-01

Most models of lower crust/mantle viscosity inferred from postearthquake relaxation assume one or two uniform-viscosity layers. A few existing models possess apparently significant radially variable viscosity structure in the shallow mantle (e.g., the upper 200 km), but the resolution of such variations is not clear. We use a geophysical inverse procedure to address the resolving power of inferred shallow mantle viscosity structure using postearthquake relaxation data. We apply this methodology to 9 years of GPS-constrained crustal motions after the 16 October 1999 M = 7.1 Hector Mine earthquake. After application of a differencing method to isolate the postearthquake signal from the “background” crustal velocity field, we find that surface velocities diminish from ∼20 mm/yr in the first few months to ≲2 mm/yr after 2 years. Viscoelastic relaxation of the mantle, with a time-dependent effective viscosity prescribed by a Burgers body, provides a good explanation for the postseismic crustal deformation, capturing both the spatial and temporal pattern. In the context of the Burgers body model (which involves a transient viscosity and steady state viscosity), a resolution analysis based on the singular value decomposition reveals that at most, two constraints on depth-dependent steady state mantle viscosity are provided by the present data set. Uppermost mantle viscosity (depth ≲ 60 km) is moderately resolved, but deeper viscosity structure is poorly resolved. The simplest model that explains the data better than that of uniform steady state mantle viscosity involves a linear gradient in logarithmic viscosity with depth, with a small increase from the Moho to 220 km depth. However, the viscosity increase is not statistically significant. This suggests that the depth-dependent steady state viscosity is not resolvably different from uniformity in the uppermost mantle.

The Effect of TiO2 on the Liquidus Zone and Apparent Viscosity of SiO2-CaO-8wt.%MgO-14wt.%Al2O3 System

NASA Astrophysics Data System (ADS)

Yan, Zhiming; Lv, Xuewei; Zhang, Jie; Xu, Jian

TiO2 has been approved as a viscosity-decreasing agent in blast furnace slag under inert atmosphere both by experimental and structure calculation. However, the validity of the above conclusion in a much bigger zone in CaO-SiO2-Al2O3-MgO phase diagram has not approved. The viscosity of slag dependent on the TiO2 content and basicity were measured in the present work. It was found that the viscosity and viscous activation energy decrease with increasing TiO2 content and basicity at a reasonable range, indicating TiO2 behaved as a viscosity-decreasing agent by depolymerizing the silicate network structure when its less than 50wt. %. The liquidity of the slag can be improved when TiO2 content less than 50wt. % and basicity from 0.5 to 1.1. The free running temperature increase at TiO2 content from 10wt.% to 30wt. %. The results of calculation does not agree well with the experimental values at a high basicity of 1.3 with TiO2 content from 20wt.% to 30wt.% and the lower basicity of 0.5 with TiO2 content more than 50wt.%.

Theory and Simulation of A Novel Viscosity Measurement Method for High Temperature Semiconductor

NASA Technical Reports Server (NTRS)

Lin, Bochuan; Li, Chao; Ban, Heng; Scripa, Rose; Zhu, Shen; Su, Ching-Hua; Lehoczky, S. L.; Curreri, Peter A. (Technical Monitor)

2002-01-01

The properties of molten semiconductors are good indicators for material structure transformation and hysteresis under temperature variations. Viscosity, as one of the most important properties, is difficult to measure because of high temperature, high pressure, and vapor toxicity of melts. Recently, a novel method was developed by applying a rotating magnetic field to the melt sealed in a suspended quartz ampoule, and measuring the transient torque exerted by rotating melt flow on the ampoule wall. The method was designed to measure viscosity in short time period, which is essential for evaluating temperature hysteresis. This paper compares the theoretical prediction of melt flow and ampoule oscillation with the experimental data. A theoretical model was established and the coupled fluid flow and ampoule torsional vibration equations were solved numerically. The simulation results showed a good agreement with experimental data. The results also showed that both electrical conductivity and viscosity could be calculated by fitting the theoretical results to the experimental data. The transient velocity of the melt caused by the rotating magnetic field was found reach equilibrium in about half a minute, and the viscosity of melt could be calculated from the altitude of oscillation. This would allow the measurement of viscosity in a minute or so, in contrast to the existing oscillation cup method, which requires about an hour for one measurement.

Viscosity minima in binary mixtures of ionic liquids + molecular solvents.

PubMed

Tariq, M; Shimizu, K; Esperança, J M S S; Canongia Lopes, J N; Rebelo, L P N

2015-05-28

The viscosity (η) of four binary mixtures (ionic liquids plus molecular solvents, ILs+MSs) was measured in the 283.15 < T/K < 363.15 temperature range. Different IL/MS combinations were selected in such a way that the corresponding η(T) functions exhibit crossover temperatures at which both pure components present identical viscosity values. Consequently, most of the obtained mixture isotherms, η(x), exhibit clear viscosity minima in the studied T-x range. The results are interpreted using auxiliary molecular dynamics (MD) simulation data in order to correlate the observed η(T,x) trends with the interactions in each mixture, including the balance between electrostatic forces and hydrogen bonding.

An exploration of viscosity models in the realm of kinetic theory of liquids originated fluids

NASA Astrophysics Data System (ADS)

Hussain, Azad; Ghafoor, Saadia; Malik, M. Y.; Jamal, Sarmad

The preeminent perspective of this article is to study flow of an Eyring Powell fluid model past a penetrable plate. To find the effects of variable viscosity on fluid model, continuity, momentum and energy equations are elaborated. Here, viscosity is taken as function of temperature. To understand the phenomenon, Reynold and Vogel models of variable viscosity are incorporated. The highly non-linear partial differential equations are transfigured into ordinary differential equations with the help of suitable similarity transformations. The numerical solution of the problem is presented. Graphs are plotted to visualize the behavior of pertinent parameters on the velocity and temperature profiles.

Gibbs Energy Additivity Approaches in Estimation of Dynamic Viscosities of n-Alkane-1-ol

NASA Astrophysics Data System (ADS)

Phankosol, S.; Krisnangkura, K.

2017-09-01

Alcohols are solvents for organic and inorganic substances. Dynamic viscosity of liquid is important transport properties. In this study models for estimating n-alkan-1-ol dynamic viscosities are correlated to the Martin’s rule of free energy additivity. Data available in literatures are used to validate and support the proposed equations. The dynamic viscosities of n-alkan-1-ol can be easily estimated from its carbon numbers (nc) and temperatures (T). The bias, average absolute deviation and coefficient of determination (R2) in estimating of n-alkan-1-ol are -0.17%, 1.73% and 0.999, respectively. The dynamic viscosities outside temperature between 288.15 and 363.15 K may be possibly estimated by this model but accuracy may be lower.

Solubility and diffusion of oxygen in phospholipid membranes.

PubMed

Möller, Matías N; Li, Qian; Chinnaraj, Mathivanan; Cheung, Herbert C; Lancaster, Jack R; Denicola, Ana

2016-11-01

The transport of oxygen and other nonelectrolytes across lipid membranes is known to depend on both diffusion and solubility in the bilayer, and to be affected by changes in the physical state and by the lipid composition, especially the content of cholesterol and unsaturated fatty acids. However, it is not known how these factors affect diffusion and solubility separately. Herein we measured the partition coefficient of oxygen in liposome membranes of dilauroyl-, dimiristoyl- and dipalmitoylphosphatidylcholine in buffer at different temperatures using the equilibrium-shift method with electrochemical detection. The apparent diffusion coefficient was measured following the fluorescence quenching of 1-pyrenedodecanoate inserted in the liposome bilayers under the same conditions. The partition coefficient varied with the temperature and the physical state of the membrane, from below 1 in the gel state to above 2.8 in the liquid-crystalline state in DMPC and DPPC membranes. The partition coefficient was directly proportional to the partial molar volume and was then associated to the increase in free-volume in the membrane as a function of temperature. The apparent diffusion coefficients were corrected by the partition coefficients and found to be nearly the same, with a null dependence on viscosity and physical state of the membrane, probably because the pyrene is disturbing the surrounding lipids and thus becoming insensitive to changes in membrane viscosity. Combining our results with those of others, it is apparent that both solubility and diffusion increase when increasing the temperature or when comparing a membrane in the gel to one in the fluid state. Copyright © 2016 Elsevier B.V. All rights reserved.

Variable viscosity on unsteady dissipative Carreau fluid over a truncated cone filled with titanium alloy nanoparticles

NASA Astrophysics Data System (ADS)

Raju, C. S. K.; Sekhar, K. R.; Ibrahim, S. M.; Lorenzini, G.; Viswanatha Reddy, G.; Lorenzini, E.

2017-05-01

In this study, we proposed a theoretical investigation on the temperature-dependent viscosity effect on magnetohydrodynamic dissipative nanofluid over a truncated cone with heat source/sink. The involving set of nonlinear partial differential equations is transforming to set of nonlinear ordinary differential equations by using self-similarity solutions. The transformed governing equations are solved numerically using Runge-Kutta-based Newton's technique. The effects of various dimensionless parameters on the skin friction coefficient and the local Nusselt number profiles are discussed and presented with the support of graphs. We also obtained the validation of the current solutions with existing solution under some special cases. The water-based titanium alloy has a lesser friction factor coefficient as compared with kerosene-based titanium alloy, whereas the rate of heat transfer is higher in water-based titanium alloy compared with kerosene-based titanium alloy. From this we can highlight that depending on the industrial needs cooling/heating chooses the water- or kerosene-based titanium alloys.

The thermo magnetic instability in hot viscose plasmas

NASA Astrophysics Data System (ADS)

Haghani, A.; Khosravi, A.; Khesali, A.

2017-10-01

Magnetic Rotational Instability (MRI) can not performed well in accretion disks with strong magnetic field. Studies have indicated a new type of instability called thermomagnetic instability (TMI) in systems where Nernst coefficient and gradient temperature were considered. Nernst coefficient would appear if Boltzman equation could be expanded through ω_{Be} (cyclotron frequency). However, the growth rate of this instability was two magnitude orders below MRI growth (Ωk), which could not act the same as MRI. Therefor, a higher growth rate of unstable modes was needed. In this paper, rotating viscid hot plasma with strong magnetic filed was studied. Firstly, a constant alpha viscosity was studied and then a temperature sensitive viscosity. The results showed that the temperature sensitive viscosity would be able to increase the growth rate of TMI modes significantly, hence capable of acting similar to MRI.

Elastohydrodynamic Lubrication with Polyolester Lubricants and HFC Refrigerants, Final Report, Volume 2

DOE Office of Scientific and Technical Information (OSTI.GOV)

Gunsel, Selda; Pozebanchuk, Michael

1999-04-01

Lubrication properties of refrigeration lubricants were investigated in high pressure nonconforming contacts under different conditions of temperature, rolling speed, and refrigerant concentration. The program was based upon the recognition that the lubrication regime in refrigeration compressors is generally elastohydrodynamic or hydrodynamic, as determined by the operating conditions of the compressor and the properties of the lubricant. Depending on the compressor design, elastohydrodynamic lubrication conditions exist in many rolling and sliding elements of refrigeration compressors such as roller element bearings, gears, and rotors. The formation of an elastohydrodynamic film separating rubbing surfaces is important in preventing the wear and failure ofmore » compressor elements. It is, therefore, important to predict the elastohydrodynamic (EHD) performance of lubricants under realistic tribocontact renditions. This is, however, difficult as the lubricant properties that control film formation are critically dependent upon pressure and shear, and cannot be evaluated using conventional laboratory instruments. In this study, the elastohydrodynamic behavior of refrigeration lubricants with and without the presence of refrigerants was investigated using the ultrathin film EHD interferometry technique. This technique enables very thin films, down to less than 5 nm, to be measured accurately within an EHD contact under realistic conditions of temperature, shear, and pressure. The technique was adapted to the study of lubricant refrigerant mixtures. Film thickness measurements were obtained on refrigeration lubricants as a function of speed, temperature, and refrigerant concentration. The effects of lubricant viscosity, temperature, rolling speed, and refrigerant concentration on EHD film formation were investigated. From the film thickness measurements, effective pressure-viscosity coefficients were calculated. The lubricants studied in this project included two naphthenic mineral oils (NMO), four polyolesters (POE), and two polyvinyl ether (PVE) fluids. These fluids represented viscosity grades of ISO 32 and ISO 68 and are shown in a table. Refrigerants studied included R-22, R-134a, and R-410A. Film thickness measurements were conducted at 23 C, 45 C, and 65 C with refrigerant concentrations ranging from zero to 60% by weight.« less

Two types of asthenospheric layers and their evolution

NASA Astrophysics Data System (ADS)

Czechowski, Leszek; Grad, Marek

2016-04-01

Basic assumptions The plate tectonics theory describes some basic global tectonic processes in terms of motion of lithospheric plates. The boundary between lithosphere and asthenosphere (LAB) is defined by a difference in response to stress. A few factors determine viscosity of the mantle. The generalized viscosity relation valid for both diffusion and dislocation creeps is: ( ) (-σ)1-n Ea-+-pVa η = C G exp RT , where η is the viscosity [Pa s], σ is the differential stress [Pa] (in fact: an invariant of the stress tensor), Ea is the energy activation [J], p is the pressure [Pa], and V a is the volume activation [m3]. C (G, h, fH2O,fmelts) is the function of rigidity G [Pa], the grain size h [m], fOHis the hydrogen and hydroxyl concentration,fmelts is the melt fraction. The expression Ea+pVa is proportional to the temperature of melting Tm. In a typical approach, the asthenosphere is believed to be determined by the ratio of Tmto the actual temperature T , i.e. by q. The Tmis a function of pressure p. Therefore, the basic differences of lithosphere and asthenosphere properties are often explained as a result of the T - p conditions. Note however that the above equation indicates that the effective viscosity depends also on other factors, e.g. chemical composition, size of grains, etc. In our consideration we choose to investigate the role of σ. Generally, viscosity is proportional to σ1-n. For n=1 the viscosity does not depend on the stress. For true mantle:n is probably in the range from 3 to 5. Observations Using results from deep seismic sounding and surface wave tomography we have found that below some regions there are structures in the mantle that could be a forming/vanishing low viscosity layers. Reflectors in the lower lithosphere are observed beneath Trans-European suture zone between Precambrian and Palaeozoic platforms. In a thick Baltic shield lithosphere (200 km or more) low velocity zones and seismic reflectors are observed in the depth range 60-100 km, which could be interpreted as mechanical low Vp velocity zones, in contrast to thermal velocity zone in deeper asthenosphere. Conclusions 1. In general, two kinds of asthenospheres could exist: mainly of mechanical origin (or shear stress origin) and mainly of thermal origin. In our calculations the role of shear stresses and thermal effects is of the same order. 2. The evolution of σ could be very fast, so the asthenosphere of shear stress origin could be a transient, time-dependent feature. 3. The evolution of the system of two asthenospheres leads usually to origin of a thick lithosphere with characteristic two low S-wave velocity layers. We suggest that at least some of the observed thick continental lithospheres are of this origin. Acknowledgments This work was partially supported by the National Science Centre (grant 2011/01/B/ST10/06653). Computer resources of Interdisciplinary Centre for Mathematical and Computational Modeling of University of Warsaw were also used in the research

In situ droplet surface tension and viscosity measurements in gas metal arc welding

NASA Astrophysics Data System (ADS)

Bachmann, B.; Siewert, E.; Schein, J.

2012-05-01

In this paper, we present an adaptation of a drop oscillation technique that enables in situ measurements of thermophysical properties of an industrial pulsed gas metal arc welding (GMAW) process. Surface tension, viscosity, density and temperature were derived expanding the portfolio of existing methods and previously published measurements of surface tension in pulsed GMAW. Natural oscillations of pure liquid iron droplets are recorded during the material transfer with a high-speed camera. Frame rates up to 30 000 fps were utilized to visualize iron droplet oscillations which were in the low kHz range. Image processing algorithms were employed for edge contour extraction of the droplets and to derive parameters such as oscillation frequencies and damping rates along different dimensions of the droplet. Accurate surface tension measurements were achieved incorporating the effect of temperature on density. These are compared with a second method that has been developed to accurately determine the mass of droplets produced during the GMAW process which enables precise surface tension measurements with accuracies up to 1% and permits the study of thermophysical properties also for metals whose density highly depends on temperature. Thermophysical properties of pure liquid iron droplets formed by a wire with 1.2 mm diameter were investigated in a pulsed GMAW process with a base current of 100 A and a pulse current of 600 A. Surface tension and viscosity of a sample droplet were 1.83 ± 0.02 N m-1 and 2.9 ± 0.3 mPa s, respectively. The corresponding droplet temperature and density are 2040 ± 50 K and 6830 ± 50 kg m-3, respectively.

Configurational Entropy Approach to the Kinetics of Glasses

PubMed Central

Di Marzio, Edmund A.; Yang, Arthur J. M.

1997-01-01

A kinetic theory of glasses is developed using equilibrium theory as a foundation. After establishing basic criteria for glass formation and the capability of the equilibrium entropy theory to describe the equilibrium aspects of glass formation, a minimal model for the glass kinetics is proposed. Our kinetic model is based on a trapping description of particle motion in which escapes from deep wells provide the rate-determining steps for motion. The formula derived for the zero frequency viscosity η (0,T) is log η (0,T) = B − AF(T)kT where F is the free energy and T the temperature. Contrast this to the Vogel-Fulcher law log η (0,T) = B + A/(T − Tc). A notable feature of our description is that even though the location of the equilibrium second-order transition in temperature-pressure space is given by the break in the entropy or volume curves the viscosity and its derivative are continuous through the transition. The new expression for η (0,T) has no singularity at a critical temperature Tc as in the Vogel-Fulcher law and the behavior reduces to the Arrhenius form in the glass region. Our formula for η (0,T) is discussed in the context of the concepts of strong and fragile glasses, and the experimentally observed connection of specific heat to relaxation response in a homologous series of polydimethylsiloxane is explained. The frequency and temperature dependencies of the complex viscosity η (ω< T), the diffusion coefficient D(ω< T), and the dielectric response ε (ω< T) are also obtained for our kinetic model and found to be consistent with stretched exponential behavior. PMID:27805133

Phase separation in thermal systems: A lattice Boltzmann study and morphological characterization

NASA Astrophysics Data System (ADS)

Gan, Yanbiao; Xu, Aiguo; Zhang, Guangcai; Li, Yingjun; Li, Hua

2011-10-01

We investigate thermal and isothermal symmetric liquid-vapor separations via a fast Fourier transform thermal lattice Boltzmann (FFT-TLB) model. Structure factor, domain size, and Minkowski functionals are employed to characterize the density and velocity fields, as well as to understand the configurations and the kinetic processes. Compared with the isothermal phase separation, the freedom in temperature prolongs the spinodal decomposition (SD) stage and induces different rheological and morphological behaviors in the thermal system. After the transient procedure, both the thermal and isothermal separations show power-law scalings in domain growth, while the exponent for thermal system is lower than that for isothermal system. With respect to the density field, the isothermal system presents more likely bicontinuous configurations with narrower interfaces, while the thermal system presents more likely configurations with scattered bubbles. Heat creation, conduction, and lower interfacial stresses are the main reasons for the differences in thermal system. Different from the isothermal case, the release of latent heat causes the changing of local temperature, which results in new local mechanical balance. When the Prandtl number becomes smaller, the system approaches thermodynamical equilibrium much more quickly. The increasing of mean temperature makes the interfacial stress lower in the following way: σ=σ0[(Tc-T)/(Tc-T0)]3/2, where Tc is the critical temperature and σ0 is the interfacial stress at a reference temperature T0, which is the main reason for the prolonged SD stage and the lower growth exponent in the thermal case. Besides thermodynamics, we probe how the local viscosities influence the morphology of the phase separating system. We find that, for both the isothermal and thermal cases, the growth exponents and local flow velocities are inversely proportional to the corresponding viscosities. Compared with the isothermal case, the local flow velocity depends not only on viscosity but also on temperature.

Viscosity Control Experiment Feasibility Study

DOE Office of Scientific and Technical Information (OSTI.GOV)

Morris, Heidi E.; Bradley, Paul Andrew

Turbulent mix has been invoked to explain many results in Inertial Confinement Fusion (ICF) and High Energy Density (HED) physics, such as reduced yield in capsule implosions. Many ICF capsule implosions exhibit interfacial instabilities seeded by the drive shock, but it is not clear that fully developed turbulence results from this. Many simulations use turbulent mix models to help match simulation results to data, but this is not appropriate if turbulence is not present. It would be useful to have an experiment where turbulent mixing could be turned on or off by design. The use of high-Z dopants to modifymore » viscosity and the resulting influence on turbulence is considered here. A complicating factor is that the plasma in some implosions can become strongly coupled, which makes the Spitzer expression for viscosity invalid. We first consider equations that cover a broad parameter space in temperature and density to address regimes for various experimental applications. Next, a previous shock-tube and other ICF experiments that investigate viscosity or use doping to examine the effects on yield are reviewed. How viscosity and dopants play a role in capsule yield depends on the region and process under consideration. Experiments and simulations have been performed to study the effects of viscosity on both the hot spot and the fuel/ablator mix. Increases in yield have been seen for some designs, but not all. We then discuss the effect of adding krypton dopant to the gas region of a typical OMEGA and a 2-shock NIF implosion to determine approximately the effect of adding dopant on the computed Reynolds number. Recommendations for a path forward for possible experiments using high-Z dopants to affect viscosity and turbulence are made.« less

Dynamic compensation in the central Pacific Ocean

NASA Technical Reports Server (NTRS)

Hinojosa, Juan Homero; Marsh, Bruce D.

1988-01-01

The intermediate-wavelength geoid (lambda similar to 2000 km) and sea-floor topography fields in the central Pacific Ocean were studied in terms of static and dynamic compensation models. Topographic features on the sea-floor with lambda less than 1000 km were found to be compensated both regionally, by the elastic strength of the lithosphere, and locally, by displacing mantle material to reach isostatic adjustment. The larger-scale sea-floor topography and the corresponding geoid anomalies with lambda similar to 2000 km cannot be explained by either local or regional compensation. The topography and the resulting geoid anomaly at this wavelength were modeled by considering the dynamic effects arising from viscous stresses in a layer of fluid with a highly temperature-dependent viscosity for the cases of: (1) surface cooling, and (2) basal heating. In this model, the mechanical properties of the elastic part of the lithosphere were taken into account by considering an activation energy of about 520 kJ/mol in the Arrhenius law for the viscosity. Numerical predictions of the topography, total geoid anomaly, and admittance were obtained, and the results show that the thermal perturbation in the layer, which accounts for the mass deficit, must be located close to the surface to compensate the gravitational effect of the surface deformation. For the case of basal heating, the temperature dependence of viscosity results in a separation of the upper, quasi-rigid lid from the lower mobile fluid, hence inhibiting the development of a compensating thermal perturbation at shallow depths. The results clearly rule out small-scale, upper-mantle convection as the source of these anomalies. Instead, the geophysical observables can be well explained by a shallow, transient thermal perturbation.

Rotational Diffusion Depends on Box Size in Molecular Dynamics Simulations.

PubMed

Linke, Max; Köfinger, Jürgen; Hummer, Gerhard

2018-06-07

We show that the rotational dynamics of proteins and nucleic acids determined from molecular dynamics simulations under periodic boundary conditions suffer from significant finite-size effects. We remove the box-size dependence of the rotational diffusion coefficients by adding a hydrodynamic correction k B T/6 ηV with k B Boltzmann's constant, T the absolute temperature, η the solvent shear viscosity, and V the box volume. We show that this correction accounts for the finite-size dependence of the rotational diffusion coefficients of horse-heart myoglobin and a B-DNA dodecamer in aqueous solution. The resulting hydrodynamic radii are in excellent agreement with experiment.

Low temperatures shear viscosity of a two-component dipolar Fermi gas with unequal population

NASA Astrophysics Data System (ADS)

Darsheshdar, E.; Yavari, H.; Zangeneh, Z.

2016-07-01

By using the Green's functions method and linear response theory we calculate the shear viscosity of a two-component dipolar Fermi gas with population imbalance (spin polarized) in the low temperatures limit. In the strong-coupling Bose-Einstein condensation (BEC) region where a Feshbach resonance gives rise to tightly bound dimer molecules, a spin-polarized Fermi superfluid reduces to a simple Bose-Fermi mixture of Bose-condensed dimers and the leftover unpaired fermions (atoms). The interactions between dimer-atom, dimer-dimer, and atom-atom take into account to the viscous relaxation time (τη) . By evaluating the self-energies in the ladder approximation we determine the relaxation times due to dimer-atom (τDA) , dimer-dimer (τcDD ,τdDD) , and atom-atom (τAA) interactions. We will show that relaxation rates due to these interactions τDA-1 ,τcDD-1, τdDD-1, and τAA-1 have T2, T4, e - E /kB T (E is the spectrum of the dimer atoms), and T 3 / 2 behavior respectively in the low temperature limit (T → 0) and consequently, the atom-atom interaction plays the dominant role in the shear viscosity in this rang of temperatures. For small polarization (τDA ,τAA ≫τcDD ,τdDD), the low temperatures shear viscosity is determined by contact interaction between dimers and the shear viscosity varies as T-5 which has the same behavior as the viscosity of other superfluid systems such as superfluid neutron stars, and liquid helium.

A pH-responsive wormlike micellar system of a noncovalent interaction-based surfactant with a tunable molecular structure.

PubMed

Kang, Wanli; Wang, Pengxiang; Fan, Haiming; Yang, Hongbin; Dai, Caili; Yin, Xia; Zhao, Yilu; Guo, Shujun

2017-02-08

Responsive wormlike micelles are very useful in a number of applications, whereas it is still challenging to create dramatic viscosity changes in wormlike micellar systems. Here we developed a pH-responsive wormlike micellar system based on a noncovalent constructed surfactant, which is formed by the complexation of N-erucamidopropyl-N,N-dimethylamine (UC 22 AMPM) and citric acid at the molar ratio of 3 : 1 (EACA). The phase behavior, aggregate microstructure and viscoelasticity of EACA solutions were investigated by macroscopic appearance observation, rheological and cryo-TEM measurements. It was found that the phase behavior of EACA solutions undergoes transition from transparent viscoelastic fluids to opalescent solutions and then phase separation with white floaters upon increasing the pH. Upon increasing the pH from 2.03 to 6.17, the viscosity of wormlike micelles in the transparent solutions continuously increased and reached ∼683 000 mPa s at pH 6.17. As the pH was adjusted to 7.31, the opalescent solution shows a water-like flowing behaviour and the η 0 rapidly declines to ∼1 mPa s. Thus, dramatic viscosity changes of about 6 magnitudes can be triggered by varying the pH values without any deterioration of the EACA system. This drastic variation in rheological behavior is attributed to the pH dependent interaction between UC 22 AMPM and citric acid. Furthermore, the dependence on concentration and temperature of the rheological behavior of EACA solutions was also studied to assist in obtaining the desired pH-responsive viscosity changes.

Communication: Simple liquids' high-density viscosity

NASA Astrophysics Data System (ADS)

Costigliola, Lorenzo; Pedersen, Ulf R.; Heyes, David M.; Schrøder, Thomas B.; Dyre, Jeppe C.

2018-02-01

This paper argues that the viscosity of simple fluids at densities above that of the triple point is a specific function of temperature relative to the freezing temperature at the density in question. The proposed viscosity expression, which is arrived at in part by reference to the isomorph theory of systems with hidden scale invariance, describes computer simulations of the Lennard-Jones system as well as argon and methane experimental data and simulation results for an effective-pair-potential model of liquid sodium.

Evaluation of Sealing Materials and Techniques for Installing Quoin and Miter Block Backing Grout

DTIC Science & Technology

2015-11-01

being used effectively in the field. The materials currently in use have low viscosities and are typically poured behind the quoin and miter blocks in...tively in the field. The materials now used have low viscosities . They are typ- ically poured behind the quoin and miter blocks in lifts. The perimeter of...colder temperatures. Low viscosity at warmer temperatures. Hilti HIT ICE Epoxy Acrylate It is primarily a cold weather product that had poor

Transparent, immiscible, surrogate liquids with matchable refractive indexes: Increased range of density and viscosity ratios

NASA Astrophysics Data System (ADS)

Cadillon, Jérémy; Saksena, Rajat; Pearlstein, Arne J.

2016-12-01

By replacing the "heavy" silicone oil used in the oil phase of Saksena, Christensen, and Pearlstein ["Surrogate immiscible liquid pairs with refractive indexes matchable over a wide range of density and viscosity ratios," Phys. Fluids 27, 087103 (2015)] by one with a twentyfold higher viscosity, and replacing the "light" silicone oil in that work by one with a viscosity fivefold lower and a density about 10% lower, we have greatly extended the range of viscosity ratio accessible by index-matching the adjustable-composition oil phase to an adjustable-composition 1,2-propanediol + CsBr + H2O aqueous phase and have also extended the range of accessible density ratios. The new system of index-matchable surrogate immiscible liquids is capable of achieving the density and viscosity ratios for liquid/liquid systems consisting of water with the entire range of light or medium crude oils over the temperature range from 40 °F (4.44 °C) to 200 °F (93.3 °C) and can access the density and viscosity ratios for water with some heavy crude oils over part of the same temperature range. It also provides a room-temperature, atmospheric-pressure surrogate for the liquid CO2 + H2O system at 0 °C over almost all of the pressure range of interest in sub-seabed CO2 sequestration.

Measurement of viscosity and elasticity of lubricants at high pressures

NASA Technical Reports Server (NTRS)

Rein, R. G., Jr.; Charng, T. T.; Sliepcevich, C. M.; Ewbank, W. J.

1975-01-01

The oscillating quartz crystal viscometer has been used to investigate possible viscoelastic behavior in synthetic lubricating fluids and to obtain viscosity-pressure-temperature data for these fluids at temperatures to 300 F and pressures to 40,000 psig. The effect of pressure and temperature on the density of the test fluids was measured concurrently with the viscosity measurements. Viscoelastic behavior of one fluid, di-(2-ethylhexyl) sebacate, was observed over a range of pressures. These data were used to compute the reduced shear elastic (storage) modulus and reduced loss modulus for this fluid at atmospheric pressure and 100 F as functions of reduced frequency.

Increases in core temperature counterbalance effects of haemoconcentration on blood viscosity during prolonged exercise in the heat.

PubMed

Buono, Michael J; Krippes, Taylor; Kolkhorst, Fred W; Williams, Alexander T; Cabrales, Pedro

2016-02-01

What is the central question of this study? The purpose of the present study was to determine the effects of exercise-induced haemoconcentration and hyperthermia on blood viscosity. What is the main finding and its importance? Exercise-induced haemoconcentration, increased plasma viscosity and increased blood aggregation, all of which increased blood viscosity, were counterbalanced by increased red blood cell (RBC) deformability (e.g. RBC membrane shear elastic modulus and elongation index) caused by the hyperthermia. Thus, blood viscosity remained unchanged following prolonged moderate-intensity exercise in the heat. Previous studies have reported that blood viscosity is significantly increased following exercise. However, these studies measured both pre- and postexercise blood viscosity at 37 °C even though core and blood temperatures would be expected to have increased during the exercise. Consequently, the effect of exercise-induced hyperthermia on mitigating change in blood viscosity may have been missed. The purpose of this study was to isolate the effects of exercise-induced haemoconcentration and hyperthermia and to determine their combined effects on blood viscosity. Nine subjects performed 2 h of moderate-intensity exercise in the heat (37 °C, 40% relative humidity), which resulted in significant increases from pre-exercise values for rectal temperature (from 37.11 ± 0.35 to 38.76 ± 0.13 °C), haemoconcentration (haematocrit increased from 43.6 ± 3.6 to 45.6 ± 3.5%) and dehydration (change in body weight = -3.6 ± 0.7%). Exercise-induced haemoconcentration significantly (P < 0.05) increased blood viscosity by 9% (from 3.97 to 4.33 cP at 300 s(-1)), whereas exercise-induced hyperthermia significantly decreased blood viscosity by 7% (from 3.97 to 3.69 cP at 300 s(-1)). When both factors were considered together, there was no overall change in blood viscosity (from 3.97 to 4.03 cP at 300 s(-1)). The effects of exercise-induced haemoconcentration, increased plasma viscosity and increased red blood cell aggregation, all of which increased blood viscosity, were counterbalanced by increased red blood cell deformability (e.g. red blood cell membrane shear elastic modulus and elongation index) caused by the hyperthermia. Thus, blood viscosity remained unchanged following prolonged moderate-intensity exercise in the heat. © 2015 The Authors. Experimental Physiology © 2015 The Physiological Society.

An experimental investigation into the effects of pores and crystals on magma rheology

NASA Astrophysics Data System (ADS)

Coats, Rebecca; Cai, Biao; Kendrick, Jackie; Wallace, Paul; Hornby, Adrian; Miwa, Taka; Ashworth, James; von Aulock, Felix; Godinho, José; Lee, Peter; Lavallée, Yan

2017-04-01

The rheology of magma has a key control on eruption style; transitions in flow dynamics can be linked to changes in porosity, crystallinity and melt chemistry. Physical interactions due to the presence of both crystals and bubbles in a volcanic melt can influence a system's rheology by causing variations in viscosity and strain dependent flow behaviour, making eruption style difficult to predict. Ergo it is essential to gain an insight into the manner in which crystalline, porous magmas flow and fail. By conducting uniaxial compressive strength (UCS) tests on both volcanic rocks and synthetic samples at room and high temperatures, a deeper understanding of how these materials behave at volcanic conditions can be attained. Here we have taken advantage of a suite of highly crystalline ( 50 vol.%) dacite from Mt Unzen, with varying porosity (9-32 vol.%), along with a sintered glass with a range of atmospheric air filled pores (<3, 20 and 30 vol.%) and TiO2 particles (0-50 vol.%). Mt Unzen experiments have revealed that the UCS systematically decreases with an increase in porosity, matching other volcanic rocks in the literature and UCS is strain rate dependent. The latter of which, along with the observation that UCS increases at higher temperatures, has not previously been observed in glass-bearing volcanic rocks and was seen in both samples from Mt Unzen and in the glass-particle mixtures. From the synthetic sample tests at room temperature we see that the UCS does not vary with crystal content (across the range measured), but at high temperature preliminary results suggest strength decreases with particle volume. Gent's parallel plate technique was applied to calculate the viscosity of samples that appeared to flow under the applied stresses. Both natural and synthetic samples demonstrated a non-Newtonian, shear thinning response to applied strain rates. For the natural Mt. Unzen samples it appears that viscosity does not scale with porosity; which, at 50 vol.% crystals, is supported by experimental and modelling data in the literature[1]. Although experiments are yet to take place on porous synthetic samples, tests on the dense samples reveal that viscosity is proportional to crystal content. Conclusions drawn from these experiments both confirm and contradict results published in the literature, which we interpret as a demonstration that multi-phase magmas are more complex than previously suggested. In order to help resolve these complexities we recently undertook a series of high-temperature compression experiments on the synthetic magma in-situ at the Diamond Light Source, the results of which will shed light on the way in which crystalline, porous materials flow and fracture. [1] Truby JM, Mueller SP, Llewellin EW and Mader HM. 2015 The rheology of three-phase suspensions at low bubble capillary number. Proc. R. Soc. A

Neoproterozoic sand wedges: crack formation in frozen soils under diurnal forcing during a snowball Earth

NASA Astrophysics Data System (ADS)

Maloof, Adam C.; Kellogg, James B.; Anders, Alison M.

2002-11-01

Thermal contraction cracking of permafrost produced sand-wedge polygons at sea level on the paleo-equator during late Neoproterozoic glacial episodes. These sand wedges have been used as evidence for high (≥54°) paleo-obliquity of the Earth's ecliptic, because cracks that form wedges are hypothesized to require deep seasonal cooling so the depth of the stressed layer in the ground reaches ≥1 m, similar to the measured depths of cracks that form wedges. To test the counter hypothesis that equatorial cracks opened under a climate characterized by a strong diurnal cycle and low mean annual temperature (snowball Earth conditions), we examine crack formation in frozen ground subject to periodic temperature variations. We derive analytical expressions relating the Newtonian viscosity to the potential crack depth, concluding that cracks will form only in frozen soils with viscosities greater than ˜10 14 Pa s. We also show numerical calculations of crack growth in frozen soils with stress- and temperature-dependent rheologies and find that fractures may propagate to depths 3-25 times the depth of the thermally stressed layer in equatorial permafrost during a snowball Earth because the mean annual temperature is low enough to keep the ground cold and brittle to relatively great depths.

Thermal conductivity and viscosity measurements of ethylene glycol-based Al2O3 nanofluids

PubMed Central

2011-01-01

The dispersion and stability of nanofluids obtained by dispersing Al2O3 nanoparticles in ethylene glycol have been analyzed at several concentrations up to 25% in mass fraction. The thermal conductivity and viscosity were experimentally determined at temperatures ranging from 283.15 K to 323.15 K using an apparatus based on the hot-wire method and a rotational viscometer, respectively. It has been found that both thermal conductivity and viscosity increase with the concentration of nanoparticles, whereas when the temperature increases the viscosity diminishes and the thermal conductivity rises. Measured enhancements on thermal conductivity (up to 19%) compare well with literature values when available. New viscosity experimental data yield values more than twice larger than the base fluid. The influence of particle size on viscosity has been also studied, finding large differences that must be taken into account for any practical application. These experimental results were compared with some theoretical models, as those of Maxwell-Hamilton and Crosser for thermal conductivity and Krieger and Dougherty for viscosity. PMID:21711737

Synthesis of high-temperature viscosity stabilizer used in drilling fluid

NASA Astrophysics Data System (ADS)

Zhang, Yanna; Luo, Huaidong; Shi, Libao; Huang, Hongjun

2018-02-01

Abstract For a well performance drilling fluid, when it operates in deep wells under high temperature, the most important property required is the thermal stability. The drilling fluid properties under high temperature can be controlled by proper selection of viscosity stabilizer, which can capture oxygen to protect polymer agent in the drilling fluid. In this paper a viscosity stabilizer PB-854 is described, which was synthesized by 4-phenoxybutyl bromide, paraformaldehyde, and phloroglucinol using etherification method and condensation reaction. We studied the effect of catalyst dosage, temperature, time, and stirring rate on the synthetic yield. Under this condition: molar ratio of 2-tert-Butylphenol, paraformaldehyde and phloroglucinol of 2:1:2.5, reacting temperature of 100 °C, stirring rate of 100 r min-1, and mass content of catalyst of 15 %, char yield of 5-bromine-3-tert-butyl salicylaldehyde reached 86 %. Under this condition: molar ratio of 5-bromine-3-tert-butyl salicylaldehyde and phloroglucinol of 4, reacting temperature of 60 °C, reacting time of 30 min, volume content of sulphuric acid of 80 %, char yield of the target product viscosity stabilizer PB-854 is 86%. Finally, in this paper, infrared spectroscopy is adopted to analyse the structure of the synthetic product PB-854.The improvement in the stability of drilling fluid was further shown after adding the viscosity stabilizer in the common polymer drilling fluid under high temperature conditions of 120 °C ˜ 180 °C. The results show significant change in terms of fluid stability in the presence of this new stabilizer as it provides better stability.

Dielectric analysis of depth dependent curing behavior of dental resin composites.

PubMed

Steinhaus, Johannes; Moeginger, Bernhard; Grossgarten, Mandy; Rosentritt, Martin; Hausnerova, Berenika

2014-06-01

The aim of this study is to investigate depth dependent changes of polymerization process and kinetics of visible light-curing (VLC) dental composites in real-time. The measured quantity - "ion viscosity" determined by dielectric analysis (DEA) - provides the depth dependent reaction rate which is correlated to the light intensity available in the corresponding depths derived from light transmission measurements. The ion viscosity curves of two composites (VOCO Arabesk Top and Grandio) were determined during irradiation of 40s with a light-curing unit (LCU) in specimen depths of 0.5/0.75/1.0/1.25/1.5/1.75 and 2.0mm using a dielectric cure analyzer (NETZSCH DEA 231 with Mini IDEX sensors). The thickness dependent light transmission was measured by irradiation composite specimens of various thicknesses on top of a radiometer setup. The shape of the ion viscosity curves depends strongly on the specimen thickness above the sensor. All curves exhibit a range of linear time dependency of the ion viscosity after a certain initiation time. The determined initiation times, the slopes of the linear part of the curves, and the ion viscosities at the end of the irradiation differ significantly with depth within the specimen. The slopes of the ion viscosity curves as well as the light intensity values decrease with depth and fit to the Lambert-Beer law. The corresponding attenuation coefficients are determined for Arabesk Top OA2 to 1.39mm(-1) and 1.48mm(-1), respectively, and for Grandio OA2 with 1.17 and 1.39mm(-1), respectively. For thicknesses exceeding 1.5mm a change in polymerization behavior is observed as the ion viscosity increases subsequent to the linear range indicating some kind of reaction acceleration. The two VLC composites and different specimen thicknesses discriminate significantly in their ion viscosity evolution allowing for a precise characterization of the curing process even with respect to the polymerization mechanism. Copyright © 2014. Published by Elsevier Ltd.

Sensor-model prediction, monitoring and in-situ control of liquid RTM advanced fiber architecture composite processing

NASA Technical Reports Server (NTRS)

Kranbuehl, D.; Kingsley, P.; Hart, S.; Loos, A.; Hasko, G.; Dexter, B.

1992-01-01

In-situ frequency dependent electromagnetic sensors (FDEMS) and the Loos resin transfer model have been used to select and control the processing properties of an epoxy resin during liquid pressure RTM impregnation and cure. Once correlated with viscosity and degree of cure the FDEMS sensor monitors and the RTM processing model predicts the reaction advancement of the resin, viscosity and the impregnation of the fabric. This provides a direct means for predicting, monitoring, and controlling the liquid RTM process in-situ in the mold throughout the fabrication process and the effects of time, temperature, vacuum and pressure. Most importantly, the FDEMS-sensor model system has been developed to make intelligent decisions, thereby automating the liquid RTM process and removing the need for operator direction.

Viscosity of Associated Mixtures Approximated by the Grunberg-Nissan Model

NASA Astrophysics Data System (ADS)

Marczak, W.; Adamczyk, N.; Łężniak, M.

2012-04-01

Previous experiments demonstrated that microheterogeneities occur in liquid systems (2-methylpyridine or 2,6-dimethylpyridine) + water. They are most probably due to the association of the hydrates through hydrogen bonds between water molecules. Substitution of methanol for water causes that the mixtures become homogenous. The results of viscometric studies reported in this study confirmed that the molecular clusters in aqueous solutions are much larger than the complexes occurring in the methanolic systems. Taking into consideration "kinetic entities" rather than monomeric molecules, the dependence of viscosity on concentration and temperature have been satisfactorily approximated by the Grunberg-Nissan relation with two adjustable coefficients. The kinetic entities were trimers of water, dimers of methanol, and monomeric amines. The same approach proved to be valid for the activation energy of viscous flow as well.

Properties of bioadhesive ketoprofen liquid suppositories: preparation, determination of gelation temperature, viscosity studies and evaluation of mechanical properties using texture analyzer by 4 × 4 factorial design.

PubMed

Ozgüney, Işık; Kardhiqi, Anita

2014-12-01

Development and evaluation of thermosensitive and bioadhesive liquid suppositories containing ketoprofen (KP). This study was conducted to develope thermosensitive and bioadhesive liquid suppositories containing KP using poloxamer and different bioadhesive polymers and to investigate their gelation temperature, viscosity and mechanical properties. Bioadhesive liquid suppositories were prepared by the cold method using poloxamer 407 (P 407), Poloxamer 188 (P 188) and various amounts of different bioadhesive polymers. Their gelation temperatures, viscosity values and mechanical properties were determined using texture analyzer by 4 × 4 factorial design. It was seen that in presence of KP, gelation temperature of formulation P 407/P 188 (4/20%) significantly decreased from 64 to 37.1 °C. It is to be noted that addition of increasing concentrations of bioadhesive polymers lowered gelation temperature and its decrease was highest with addition of Carbopol 934 P (C). Results of texture profile analysis (TPA) showed that formulations containing C have significantly higher hardness and adhesiveness values than other bioadhesive formulations. According to TPA, gel structure of liquid suppository formulation F5, containing P 407/P 188/KP/C (4/20/2.5/0.8%), exhibited the greatest hardness, compressibilty, adhesiveness and besides greatest viscosity. According to mechanical properties and viscosity values, it was concluded that F5 could be a promising formulation.

Pressure dependence of viscosity in supercooled water and a unified approach for thermodynamic and dynamic anomalies of water

PubMed Central

Singh, Lokendra P.; Issenmann, Bruno; Caupin, Frédéric

2017-01-01

The anomalous decrease of the viscosity of water with applied pressure has been known for over a century. It occurs concurrently with major structural changes: The second coordination shell around a molecule collapses onto the first shell. Viscosity is thus a macroscopic witness of the progressive breaking of the tetrahedral hydrogen bond network that makes water so peculiar. At low temperature, water at ambient pressure becomes more tetrahedral and the effect of pressure becomes stronger. However, surprisingly, no data are available for the viscosity of supercooled water under pressure, in which dramatic anomalies are expected based on interpolation between ambient pressure data for supercooled water and high pressure data for stable water. Here we report measurements with a time-of-flight viscometer down to 244K and up to 300MPa, revealing a reduction of viscosity by pressure by as much as 42%. Inspired by a previous attempt [Tanaka H (2000) J Chem Phys 112:799–809], we show that a remarkably simple extension of a two-state model [Holten V, Sengers JV, Anisimov MA (2014) J Phys Chem Ref Data 43:043101], initially developed to reproduce thermodynamic properties, is able to accurately describe dynamic properties (viscosity, self-diffusion coefficient, and rotational correlation time) as well. Our results support the idea that water is a mixture of a high density, “fragile” liquid, and a low density, “strong” liquid, the varying proportion of which explains the anomalies and fragile-to-strong crossover in water. PMID:28404733

Ab initio calculation of the shear viscosity of neon in the liquid and hypercritical state over a wide pressure and temperature range

NASA Astrophysics Data System (ADS)

Eggenberger, Rolf; Gerber, Stefan; Huber, Hanspeter; Searles, Debra; Welker, Marc

1992-08-01

The shear viscosity is calculated ab initio for the liquid and hypercritical state, i.e. a previously published potential for Ne 2, obtained from ab initio calculations including electron correlation, is used in classical equilibrium molecular dynamics simulations to obtain the shear viscosity from a Green-Kubo integral. The quality of the results is quite uniform over a large pressure range up to 1000 MPa and a wide temperature range from 26 to 600 K. In most cases the calculated shear viscosity deviates by less than 10% from the experimental value, in general the error being only a few percent.

Dielectric and electro-optic characterization of a partially fluorinated ferroelectric liquid crystal

NASA Astrophysics Data System (ADS)

Goswami, Debarghya; Sinha, Debashis; Mandal, Pradip Kumar

2018-05-01

One newly synthesized fluorinated ferroelectric liquid crystal, (S)-(+)-4_-[(3-undecafluorohexanoyloxy) prop-1-oxy]biphenyl-4-yl 4-(1-methylheptyloxy)-benzoate (code name 5F3R), has been characterized by dielectric and electro-optic investigations. The sample exhibits only SmC* phase for a considerable range of temperature. Only Gold stone mode of relaxation has been observed in dielectric study. Spontaneous polarization, response time, optical tilt angle, rotational viscosity have also been measured. The values of observed physical parameters and their temperature dependence have been compared with that of other samples of same homologues series.

Negative effect of nanoconfinement on water transport across nanotube membranes

NASA Astrophysics Data System (ADS)

Zhao, Kuiwen; Wu, Huiying; Han, Baosan

2017-10-01

Nanoconfinement environments are commonly considered advantageous for ultrafast water flow across nanotube membranes. This study illustrates that nanoconfinement has a negative effect on water transport across nanotube membranes based on molecular dynamics simulations. Although water viscosity and the friction coefficient evidently decrease because of nanoconfinement, water molecular flux and flow velocity across carbon nanotubes decrease sharply with the pore size of nanotubes. The enhancement of water flow across nanotubes induced by the decreased friction coefficient and water viscosity is markedly less prominent than the negative effect induced by the increased flow barrier as the nanotube size decreases. The decrease in water flow velocity with the pore size of nanotubes indicates that nanoconfinement is not essential for the ultrafast flow phenomenon. In addition, the relationship between flow velocity and water viscosity at different temperatures is investigated at different temperatures. The results indicate that flow velocity is inversely proportional to viscosity for nanotubes with a pore diameter above 1 nm, thereby indicating that viscosity is still an effective parameter for describing the effect of temperature on the fluid transport at the nanoscale.

Reactivity of liquid and semisolid secondary organic carbon with chloride and nitrate in atmospheric aerosols

DOE Office of Scientific and Technical Information (OSTI.GOV)

Wang, Bingbing; O'Brien, Rachel E.; Univ. of the Pacific, Stockton, CA

2015-05-14

Constituents of secondary organic carbon (SOC) in atmospheric aerosols are often mixed with inorganic components and compose a significant mass fraction of fine particulate matter in the atmosphere. Interactions between SOC and other condensed-phase species are not well understood. Here, we investigate the reactions of liquid-like and semi-solid SOC from ozonolysis of limonene (LSOC) and α-pinene (PSOC) with NaCl using a set of complementary micro-spectroscopic analyses. These reactions result in chloride depletion in the condensed phase, release of gaseous HCl, and formation of organic salts. The reactions attributed to acid displacement by SOC acidic components are driven by the highmore » volatility of HCl. Similar reactions can take place in SOC/NaNO₃ particles. The results show that an increase in SOC mass fraction in the internally mixed SOC/NaCl particles leads to higher chloride depletion. Glass transition temperatures and viscosity of PSOC were estimated for atmospherically relevant conditions. Data show that the reaction extent depends on SOC composition, particle phase state and viscosity, mixing state, temperature, relative humidity (RH), and reaction time. LSOC shows slightly higher potential to deplete chloride than PSOC. Higher particle viscosity at low temperatures and RH can hinder these acid displacement reactions. Formation of organic salts from these overlooked reactions can alter particle physiochemical properties and may affect their reactivity and ability to act as cloud condensation and ice nuclei. The release and potential recycling of HCl and HNO₃ from reacted aerosol particles may have important implications for atmospheric chemistry.« less

Reactivity of liquid and semisolid secondary organic carbon with chloride and nitrate in atmospheric aerosols.

PubMed

Wang, Bingbing; O'Brien, Rachel E; Kelly, Stephen T; Shilling, John E; Moffet, Ryan C; Gilles, Mary K; Laskin, Alexander

2015-05-14

Constituents of secondary organic carbon (SOC) in atmospheric aerosols are often mixed with inorganic components and compose a significant mass fraction of fine particulate matter in the atmosphere. Interactions between SOC and other condensed-phase species are not well understood. Here, we investigate the reactions of liquid-like and semisolid SOC from ozonolysis of limonene (LSOC) and α-pinene (PSOC) with NaCl using a set of complementary microspectroscopic analyses. These reactions result in chloride depletion in the condensed phase, release of gaseous HCl, and formation of organic salts. The reactions attributed to acid displacement by SOC acidic components are driven by the high volatility of HCl. Similar reactions can take place in SOC/NaNO3 particles. The results show that an increase in SOC mass fraction in the internally mixed SOC/NaCl particles leads to higher chloride depletion. Glass transition temperatures and viscosity of PSOC were estimated for atmospherically relevant conditions. Data show that the reaction extent depends on SOC composition, particle phase state and viscosity, mixing state, temperature, relative humidity (RH), and reaction time. LSOC shows slightly higher potential to deplete chloride than PSOC. Higher particle viscosity at low temperatures and RH can hinder these acid displacement reactions. Formation of organic salts from these overlooked reactions can alter particle physiochemical properties and may affect their reactivity and ability to act as cloud condensation and ice nuclei. The release and potential recycling of HCl and HNO3 from reacted aerosol particles may have important implications for atmospheric chemistry.

Dynamic melting of metals in the diamond cell: Clues for melt viscosity?

NASA Astrophysics Data System (ADS)

Boehler, R.; Karandikar, A.; Yang, L.

2011-12-01

From the observed decreasing mobility of liquid iron at high pressure in the laser-heated diamond cell and the gradual decrease in the shear modulus in shock experiments, one may derive high viscosity in the liquid outer core of the Earth. A possible explanation could be the presence of local structures in the liquid as has been observed for several transition metals. In order to bridge the large gap in the timescales between static and dynamic melting experiments, we have developed new experimental techniques to solve the large discrepancies in the melting curves of transition metals (Fe, W, Ta, Mo) measured statically in the laser-heated diamond cell and in shock experiments. The new methods employ "single-shot" laser heating in order to reduce problems associated with mechanical instabilities and chemical reactions of the samples subjected to several thousand degrees at megabar pressures. For melt detection, both synchrotron X-ray diffraction and Scanning Electron Microscopy (SEM) on recovered samples are used. A third approach is the measurement of latent heat effects associated with melting or freezing. This method employs simultaneous CW and pulse laser heating and monitoring the temperature-time history with fast photomultipliers. Using the SEM recovery method, we measured first melting temperatures of rhenium, which at high pressure may be one of the most refractory materials. From the melt textures of Re, we did not observe a significant pressure dependence of viscosity.

Combined Wave and Current Bottom Boundary Layers: A Review

DTIC Science & Technology

2016-03-01

18 3.2 Wave and currents at arbitrary angles ....................................................................... 19 3.3 Eddy viscosity ...closure ................................................................................................. 22 3.3.1 Eddy viscosity for stratified fluids...23 3.3.2 Time-dependent eddy viscosities

Temperature Dependence of Low-Frequency Spectra in Molten Bis(trifluoromethylsulfonyl)amide Salts of Imidazolium Cations Studied by Femtosecond Raman-Induced Kerr Effect Spectroscopy.

PubMed

Shirota, Hideaki; Kakinuma, Shohei

2015-07-30

In this study, the temperature dependence of the low-frequency spectra of liquid bis(trifluoromethylsulfonyl)amide salts of the monocations 1-methyl-3-propylimidazolium and 1-hexyl-3-methylimidazolium and the dications 1,6-bis(3-methylimidazolium-1-yl)hexane and 1,12-bis(3-methylimidazolium-1-yl)dodecane has been investigated by means of femtosecond optical heterodyne-detected Raman-induced Kerr effect spectroscopy. The intensity in the low-frequency region below 20 cm(-1) in the spectra of the four ionic liquids increases with rising temperature. From a line-shape analysis of the broadened low-frequency spectra of the ionic liquids, it is clear that the lowest-frequency component, which peaks at approximately 5 cm(-1), contributes to the temperature dependence of the spectra. This implies that the activity of the intermolecular translational vibrational motion is increasing with rising temperature. It is also possible that decoupling in the crossover process between intermolecular vibrational motion and structural relaxation occurs as a result of a deterioration of the non-Markovian feature or the loss of memory caused by the higher temperature. The peak of the highest-frequency component, which is due mainly to the imidazolium ring libration, shifts to lower frequency with increasing temperature. This is attributed to weaker interactions of the ionic liquids at higher temperatures. Temperature-dependent viscosities from 293 to 353 K of the four ionic liquids have also been characterized.

Viscosity of carbonate-rich melts under different oxygen fugacity conditions

NASA Astrophysics Data System (ADS)

Di Genova, Danilo; Hess, Kai-Uwe; Cimarelli, Corrado; Dingwell, Donald B.

2015-04-01

Viscosity is a fundamental property of many materials and its changes affects the fluid dynamics of natural system as well as industrial processes. The mobility of carbonatitic melts, which are carbonate-rich and very fluid melts, has attracted renewed interest in both earth science and industry. In fact, these melts are considered the main transport agent of carbon from the mantle to the crust and may be intimately linked to the generation of kimberlites. At the same time lithium, potassium and sodium carbonate are used as electrolytes in molten carbonate fuel cells which operate at high temperatures (~650° C) for the production of electricity without CO2 emissions. Accurate measurement of the transport property (i.e. viscosity) of carbonatitic melts is a priority in order to understand the carbonatite mobility and reaction rates. Additionally, obtaining accurate viscosity measurements of such low viscosity melts is however an experimental challenge due to volatility, very low torques and chemical melt instability in the viscometer. To overcome these limitations we have customized a Modular Compact Rheometer (MCR 502 from Anton Paar) ad hoc equipped with 2 narrow gap concentric-cylinder geometries of steel and Pt-Au. The rheometer is characterized by an air-bearing-supported synchronous motor with torque ranging between 0.01 μNm and 230 mNm (resolution of 0.1 nNm), achieving very low viscosity measurements in the order of mPa s, temperatures up to 1000° C and shear rates ranging between 1 and 100 sec-1. These experimental conditions well match the temperature-viscosity-shear rate window relevant for carbonate melts. Here we present the calibration of the rheometer and the results of a rheological characterization study on a series of very low viscous synthetic and natural carbonatitic melts at different oxygen fugacity (air and CO2 saturated atmosphere). Viscosity measurements on carbonate melts have been performed in the temperature range between ~650 and 1000° C. Measured values range between ~2 and 20 mPa sec. The results point out that the viscosity of synthetic samples is inversely related to the cations radius, being Li2CO3 melt the more viscous. Viscosity measurements on natural samples (carbonatitic lava from Lengai volcano, Tanzania), reveal a higher viscosity (~1000 mPa s) and a dramatic higher activation energy than the synthetic samples. Our results have been compared with literature data in order to determine the effect of chemical composition and oxygen fugacity conditions on the liquid viscosity of carbonatitic melts.

Magnetic stage with environmental control for optical microscopy and high-speed nano- and microrheology

NASA Astrophysics Data System (ADS)

Aprelev, Pavel; McKinney, Bonni; Walls, Chadwick; Kornev, Konstanin G.

2017-07-01

A novel design of a low-field magnetic stage for optical microscopy of droplets and films within a controlled environment is described. The stage consists of five magnetic coils with a 3D magnetic sensor in a feedback control loop, which allows one to manipulate magnetic nano- and microprobes with microtesla fields. A locally uniform time-dependent field within the focal plane of the microscope objective enables one to rotate the probes in a precisely set manner and observe their motion. The probe tracking protocol was developed to follow the probe rotation in real time and relate it with the viscosity of the host liquid. Using this magnetic stage, a method for measuring mPa s-level viscosity of nanoliter droplets and micron thick films in a 10-20 s timeframe is presented and validated. The viscosity of a rapidly changing liquid can be tracked by using only a few visible probes rotating simultaneously. Vapor pressure and temperature around the sample can be controlled to directly measure viscosity as a function of equilibrium vapor pressure; this addresses a significant challenge in characterization of volatile nanodroplets and thin films. Thin films of surfactant solutions undergoing phase transitions upon solvent evaporation were studied and their rheological properties were related to morphological changes in the material.

Transport and dielectric properties of water and the influence of coarse-graining: Comparing BMW, SPC/E, and TIP3P models

DOE Office of Scientific and Technical Information (OSTI.GOV)

Braun, Daniel; Boresch, Stefan; Steinhauser, Othmar

Long-term molecular dynamics simulations are used to compare the single particle dipole reorientation time, the diffusion constant, the viscosity, and the frequency-dependent dielectric constant of the coarse-grained big multipole water (BMW) model to two common atomistic three-point water models, SPC/E and TIP3P. In particular, the agreement between the calculated viscosity of BMW and the experimental viscosity of water is satisfactory. We also discuss contradictory values for the static dielectric properties reported in the literature. Employing molecular hydrodynamics, we show that the viscosity can be computed from single particle dynamics, circumventing the slow convergence of the standard approaches. Furthermore, our datamore » indicate that the Kivelson relation connecting single particle and collective reorientation time holds true for all systems investigated. Since simulations with coarse-grained force fields often employ extremely large time steps, we also investigate the influence of time step on dynamical properties. We observe a systematic acceleration of system dynamics when increasing the time step. Carefully monitoring energy/temperature conservation is found to be a sufficient criterion for the reliable calculation of dynamical properties. By contrast, recommended criteria based on the ratio of fluctuations of total vs. kinetic energy are not sensitive enough.« less

Online shear viscosity measurement of starchy melts enriched in wheat bran.

PubMed

Robin, Frédéric; Bovet, Nicolas; Pineau, Nicolas; Schuchmann, Heike P; Palzer, Stefan

2011-01-01

Addition of wheat bran to flours modifies their expansion properties after cooking extrusion. This can be attributed to changes in the melt shear viscosity at the die. The effect of wheat bran concentration added to achieve 2 levels of dietary fibers of 12. 6% and 24.4%, and process conditions on the shear viscosity of wheat flour was therefore assessed using an online twin-slit rheometer. The shear viscosity measured at 30 s⁻¹ ranged from 9.5 × 10³ to 53.4 × 10³ Pa s. Regardless of the process conditions and bran concentration, the extruded melts showed a pseudoplastic behavior with a power law index n ranging from 0.05 to 0.27. Increasing the barrel temperature of the extruder from 120 to 180 °C, the water content from 18% to 22% or the screw speed from 400 to 800 rpm significantly decreased the melt shear viscosity at the extruder exit. The addition of bran significantly increased the melt shear viscosity only at the highest bran concentration. The effect was process condition dependant. Mathematical interpretations, based upon observations, of the experimental data were carried out. They can be used to predict the effect of the process conditions on the melt shear viscosity at the die of extruded wheat flour with increasing bran concentration. The viscosity data will be applied in future works to study the expansion properties of extruded wheat flour supplemented with bran. Incorporation of wheat bran, a readily available and low cost by-product, in extruded puffed foods is constrained due to its negative effect on the product texture. Understanding the effect of wheat bran on rheological properties of extruded melts, driving the final product properties, is essential to provide solutions to the food industry and enhance its use. © 2011 Institute of Food Technologists®

Conditions for extreme sensitivity of protein diffusion in membranes to cell environments

PubMed Central

Tserkovnyak, Yaroslav; Nelson, David R.

2006-01-01

We study protein diffusion in multicomponent lipid membranes close to a rigid substrate separated by a layer of viscous fluid. The large-distance, long-time asymptotics for Brownian motion are calculated by using a nonlinear stochastic Navier–Stokes equation including the effect of friction with the substrate. The advective nonlinearity, neglected in previous treatments, gives only a small correction to the renormalized viscosity and diffusion coefficient at room temperature. We find, however, that in realistic multicomponent lipid mixtures, close to a critical point for phase separation, protein diffusion acquires a strong power-law dependence on temperature and the distance to the substrate H, making it much more sensitive to cell environment, unlike the logarithmic dependence on H and very small thermal correction away from the critical point. PMID:17008402

Experimental Investigation of the Thermophysical Properties of TiO2/Propylene Glycol-Water Nanofluids for Heat-Transfer Applications

NASA Astrophysics Data System (ADS)

Leena, M.; Srinivasan, S.

2018-05-01

Nanofluids have been prepared by dispersing TiO2 nanoparticles in 70:30% (by weight) water-propylene glycol mixture. The thermal conductivity and viscosity were found experimentally at various temperatures with the volume concentrations 0.1-0.8%. The results indicate that the thermal conductivity of the nanofluids increases with the volume concentration and temperature. Similarly, the viscosity of the nanofluids increases with the volume concentration but decreases with increase in the temperature. Correlations have been proposed for estimating the thermal conductivity and viscosity of the nanofluids. The potential heat transfer benefits of their use in laminar and turbulent flow conditions has been explained.

Adiabatic temperature changes of magma-gas mixtures during ascent and eruption

USGS Publications Warehouse

Mastin, L.G.; Ghiorso, M.S.

2001-01-01

Most quantitative studies of flow dynamics in eruptive conduits during volcanic eruptions use a simplified energy equation that ignores either temperature changes, or the thermal effects of gas exsolution. In this paper we assess the effects of those simplifications by analyzing the influence of equilibrium gas exsolution and expansion on final temperatures, velocities, and liquid viscosities of magma-gas mixtures during adiabatic decompression. For a given initial pressure (p1), temperature (T1) and melt composition, the final temperature (Tf) and velocity (Umax) will vary depending on the degree to which friction and other irreversible processes reduce mechanical energy within the conduit. The final conditions range between two thermodynamic end members: (1) Constant enthalpy (dh=0), in which Tf is maximal and no energy goes into lifting or acceleration; and (2) constant entropy (ds=0), in which Tf is minimal and maximum energy goes into lifting and acceleration. For ds=0, T1=900 ??C and p1=200 MPa, a water-saturated albitic melt cools by ???200 ??C during decompression, but only about 250 ??C of this temperature decrease can be attributed to the energy of gas exsolution per se: The remainder results from expansion of gas that has already exsolved. For the same T1 and p1, and dh=0, Tf is 10-15 ??C hotter than T1 but is about 10-25 ??C cooler than Tf in similar calculations that ignore the energy of gas exsolution. For ds=0, p1=200 MPa and T1= 9,000 ??C, assuming that all the enthalpy change of decompression goes into kinetic energy, a water-saturated albitic mixture can theoretically accelerate to ???800 m/s. Similar calculations that ignore gas exsolution (but take into account gas expansion) give velocities about 10-15% higher. For the same T1, p1 = 200 MPa, and ds = 0, the cooling associated with gas expansion and exsolution increases final melt viscosity more than 2.5 orders of magnitude. For dh = 0, isenthalpic heating decreases final melt viscosity by about 0.7 orders of magnitude. Thermal effects of gas exsolution are responsible for less than 10% of these viscosity changes. Isenthalpic heating could significantly reduce flow resistance in eruptive conduits if heat generation were concentrated along conduit walls, where shearing is greatest. Isentropic cooling could enhance clast fragmentation in near-surface vents in cases where extremely rapid pressure drops reduce gas temperatures and chill the margins of expanding pyroclasts.

Glass dynamics and anomalous aging in a family of ionic liquids above the glass transition temperature.

PubMed

Shamim, Nabila; McKenna, Gregory B

2010-12-09

The present paper reports the results of a systematic rheological study of the dynamic moduli of 1-butyl 3-methylimidazolium tetrafluoroborate ([Bmim][BF(4)]), 1-butyl 3-methylimidazolium hexafluorophosphate ([Bmim][PF(6)]), and 1-ethyl 3-methylimidazolium ethylsulfate ([Emim][EtSO(4)]) in the vicinity of their respective glass transition temperatures. The results show an anomalous aging in that the dynamic and the low shear rate viscosities decrease with time at temperatures near to, but above, the glass transition temperature, and this is described. The samples that are aged into equilibrium obey the time-temperature superposition principle, and the shift factors and the viscosities follow classic super-Arrhenius behaviors with intermediate fragility values as the glass transition is approached. Similar experiments using a high-purity [Bmim][BF(4)] show that using a higher purity of the ionic liquid, while changing absolute values of the properties, does not eliminate the anomalous aging response. The data are also analyzed in a fashion similar to that used for polymer melts, and we find that these ionic liquids do not follow, for example, the Cox-Merz relationship between the steady shear viscosity and the dynamic viscosity.

Viscosity, density, and thermal conductivity of aluminum oxide and zinc oxide nanolubricants

PubMed Central

Kedzierski, M.A.; Brignoli, R.; Quine, K.T.; Brown, J.S.

2017-01-01

This paper presents liquid kinematic viscosity, density, and thermal conductivity measurements of eleven different synthetic polyolester-based nanoparticle nanolubricants (dispersions) at atmospheric pressure over the temperature range 288 K to 318 K. Aluminum oxide (Al2O3) and zinc oxide (ZnO) nanoparticles with nominal diameters of 127 nm and 135 nm, respectively, were investigated. A good dispersion of the spherical and non-spherical nanoparticles in the lubricant was maintained with a surfactant. Viscosity, density, and thermal conductivity measurements were made for the neat lubricant along with eleven nanolubricants with differing nanoparticle and surfactant mass fractions. Existing models were used to predict kinematic viscosity (±20%), thermal conductivity (±1%), and specific volume (±6%) of the nanolubricant as a function of temperature, nanoparticle mass fraction, surfactant mass fraction, and nanoparticle diameter. The liquid viscosity, density and thermal conductivity were shown to increase with respect to increasing nanoparticle mass fraction. PMID:28736463

Early stages of transition in viscosity-stratified channel flow

NASA Astrophysics Data System (ADS)

Govindarajan, Rama; Jose, Sharath; Brandt, Luca

2013-11-01

In parallel shear flows, it is well known that transition to turbulence usually occurs through a subcritical process. In this work we consider a flow through a channel across which there is a linear temperature variation. The temperature gradient leads to a viscosity variation across the channel. A large body of work has been done in the linear regime for this problem, and it has been seen that viscosity stratification can lead to considerable changes in stability and transient growth characteristics. Moreover contradictory effects of introducing a non uniform viscosity in the system have been reported. We conduct a linear stability analysis and direct numerical simulations (DNS) for this system. We show that the optimal initial structures in the viscosity-stratified case, unlike in unstratified flow, do not span the width of the channel, but are focussed near one wall. The nonlinear consequences of the localisation of the structures will be discussed.

Progress on Acoustic Measurements of the Bulk Viscosity of Near-Critical Xenon (BVX)

NASA Technical Reports Server (NTRS)

Gillis, Keith A.; Shinder, Iosif I.; Moldover, Michael R.; Zimmerli, Gregory A.

2004-01-01

We plan to determine the bulk viscosity of xenon 10 times closer [in reduced temperature tau = (T-Tc)/Tc] to its liquid-vapor critical point than ever before. (Tc is the critical temperature.) To do so, we must measure the dispersion and attenuation of sound at frequencies 1/100 of those used previously. In general, sound attenuation has contributions from the bulk viscosity acting throughout the volume of the xenon as well as contributions from the thermal conductivity and the shear viscosity acting within thin thermoacoustic boundary layers at the interface between the xenon and the solid walls of the resonator. Thus, we can determine the bulk viscosity only when the boundary layer attenuation is small and well understood. We present a comparison of calculations and measurements of sound attenuation in the acoustic boundary layer of xenon near its liquid-vapor critical point.

Checking the statistical theory of liquids by ultraacoustic measurements

NASA Technical Reports Server (NTRS)

Dima, V. N.

1974-01-01

The manner of theoretically obtaining radial distribution functions 9(r) for n-hexane as a function of temperature is described. With the aid of function g(r) the coefficient of dynamic viscosity and the coefficient of volumetric viscosity for temperatures ranging from 213 K to 273 K were calculated. With the aid of the two coefficients of viscosity the coefficient of absorption of ultrasounds in n-hexane referred to the square of the frequency was determined. The same values were measured experimentally. Comparison of theory with experiments resulted in satisfactory agreement.

Superparamagnetic nanoparticle-based viscosity test

NASA Astrophysics Data System (ADS)

Wu, Kai; Liu, Jinming; Wang, Yi; Ye, Clark; Feng, Yinglong; Wang, Jian-Ping

2015-08-01

Hyperviscosity syndrome is triggered by high blood viscosity in the human body. This syndrome can result in retinopathy, vertigo, coma, and other unanticipated complications. Serum viscosity is one of the important factors affecting whole blood viscosity, which is regarded as an indicator of general health. In this letter, we propose and demonstrate a Brownian relaxation-based mixing frequency method to test human serum viscosity. This method uses excitatory and detection coils and Brownian relaxation-dominated superparamagnetic nanoparticles, which are sensitive to variables of the liquid environment such as viscosity and temperature. We collect the harmonic signals produced by magnetic nanoparticles and estimate the viscosity of unknown solutions by comparison to the calibration curves. An in vitro human serum viscosity test is performed in less than 1.5 min.

Apparatus and method for high temperature viscosity and temperature measurements

DOEpatents

Balasubramaniam, Krishnan; Shah, Vimal; Costley, R. Daniel; Singh, Jagdish P.

2001-01-01

A probe for measuring the viscosity and/or temperature of high temperature liquids, such as molten metals, glass and similar materials comprises a rod which is an acoustical waveguide through which a transducer emits an ultrasonic signal through one end of the probe, and which is reflected from (a) a notch or slit or an interface between two materials of the probe and (b) from the other end of the probe which is in contact with the hot liquid or hot melt, and is detected by the same transducer at the signal emission end. To avoid the harmful effects of introducing a thermally conductive heat sink into the melt, the probe is made of relatively thermally insulative (non-heat-conductive) refractory material. The time between signal emission and reflection, and the amplitude of reflections, are compared against calibration curves to obtain temperature and viscosity values.

Transport coefficients of Lennard-Jones fluids: A molecular-dynamics and effective-hard-sphere treatment

NASA Astrophysics Data System (ADS)

Heyes, David M.

1988-04-01

This study evaluates the shear viscosity, self-diffusion coefficient, and thermal conductivity of the Lennard-Jones (LJ) fluid over essentially the entire fluid range by molecular-dynamics (MD) computer simulation. The Green-Kubo (GK) method is mainly used. In addition, for shear viscosity, homogeneous shear nonequilibrium MD (NEMD) is also employed and compared with experimental data on argon along isotherms. Reasonable agreement between GK, NEMD, and experiment is found. Hard-sphere MD modified Chapman-Enskog expressions for these transport coefficients are tested with use of a temperature-dependent effective hard-sphere diameter. Excellent agreement is found for shear viscosity. The thermal conductivity and, more so, self-diffusion coefficient is less successful in this respect. This behavior is attributed to the attractive part to the LJ potential and its soft repulsive core. Expressions for the constant-volume and -pressure activation energies for these transport coefficients are derived solely in terms of the thermodynamic properties of the LJ fluid. Also similar expressions for the activation volumes are given, which should have a wider range of applications than just for the LJ system.

Studies of Nucleation and Growth, Specific Heat and Viscosity of Undercooled Melts of Quasicrystals and Polytetrehedral-Phase-Forming Alloys

NASA Technical Reports Server (NTRS)

2003-01-01

By investigating the properties of quasicrystals and quasicrystal-forming liquid alloys, we may determine the role of ordering of the liquid phase in the formation of quasicrystals, leading to a better fundamental understanding of both the quasicrystal and the liquid. A quasicrystal is solid characterized by a symmetric but non-periodic arrangement of atoms, usually in the form of an icosahedron (12 atoms, 20 triangular faces). It is theorized that the short-range order in liquids takes this same form. The degree of ordering depends on the temperature of the liquid, and affects many of the liquid s properties, including specific heat, viscosity, and electrical resistivity. The MSFC role in this project includes solidification studies, phase diagram determination, and thermophysical property measurements on the liquid quasicrystal-forming alloys, all by electrostatic levitation (ESL). The viscosity of liquid quasicrystal-forming alloys is measured by the oscillating drop method, both in the stable and undercooled liquid state. The specific heat of solid, undercooled liquid, and stable liquid are measured by the radiative cooling rate of the droplets.

Investigation of Tokamak Solid Divertor Target Options.

DTIC Science & Technology

1981-05-26

but materials are not known which could operate at the high resulting wall temperatures . Mist- steam flows would also demand a relatively high ...flux P = coolant density = bulk coolant viscosity w = coolant viscosity at average wall temperature = units conversion At high heat loads and moderate...therefore, the inner wall temperature will be over 300 OF, posing a high temp- erature materials challenge. E. Swirl and Mixed Flow Schemes Extensive work

Investigation of damping liquids for aircraft instruments

NASA Technical Reports Server (NTRS)

Keulegan, G H

1929-01-01

This report covers the results of an investigation carried on at the Bureau of Standards under a research authorization from, and with the financial assistance of, the National Advisory Committee for Aeronautics. The choice of a damping liquid for aircraft instruments is difficult owing to the range of temperature at which aircraft operate. Temperature changes affect the viscosity tremendously. The investigation was undertaken with the object of finding liquids of various viscosities otherwise suitable which had a minimum change in viscosity with temperature. The new data relate largely to solutions. The effect of temperature on the kinematic viscosity of the following liquids and solutions was determined in the temperature interval -18 degrees to +30 degrees C. (1) solutions of animal and vegetable oils in xylene. These were poppy-seed oil, two samples of neat's-foot oils, castor oil, and linseed oil. (2) solutions of mineral oil in xylene. These were Squibb's petrolatum of naphthene base and transformer oil. (3) glycerine solutions in ethyl alcohol and in mixture of 50-50 ethyl alcohol and water. (4) mixtures of normal butyl alcohol with methyl alcohol. (5) individual liquids, kerosene, mineral spirits, xylene, recoil oil. The apparatus consisted of four capillary-tube viscometers, which were immersed in a liquid bath in order to secure temperature control. The method of calibration and the related experimental data are presented.

The rheology of water-methanol slurries: Implications for cryovolcanism on Titan

NASA Astrophysics Data System (ADS)

Mitchell, K. L.; Zhong, F.; Hays, C. C.; Choukroun, M.; Barmatz, M. B.; Kargel, J. S.

2008-12-01

Cassini SAR imagery has revealed the presence of landforms on the surface of Titan that may be cryovolcanic flows and domes [1,2]. In order to relate the observed surface features to the geological processes and chemistries that produced them, it is necessary to construct rheological flow models at cryogenic temperatures. We report preliminary cryogenic rheological measurements on a binary 40 wt% methanol-water composition, used as a path finding analog for characterizing the rheological properties of candidate cryo-magmas and eruptant materials [3]. Work by Kargel et al. [4] used a cryogenic rotational viscometer and a viscous drop experiment to determine the viscosity of ammonia-water slurries, a likely composition of Titan cryomagma. This work revealed that the materials in question have viscosities that were controlled by the pure liquid viscosity and the solid fraction, the latter also resulting in shear-rate dependence. Our cryogenic rheological measurements were conducted between 90-300 K using a home- built LN2 cooled cryogenic rotational viscometer system, with data acquisition and control achieved using the National Instruments LabView program. We report the results of a series of measurements performed as a function of temperature and rotational strain rate. The methanol-water mixture exhibited a variety of rheological response behaviors under these experimental conditions; i.e., development of yield stress-like behaviors, shear-rate dependence, and thixotropic behavior, even at relatively low crystal fractions, which to our knowledge have not been previously observed or reported. At fixed shear rate our data are fit well by the Andrade equation, with the activation energy modified by the solid volume fraction. At fixed temperature, depending on shearing history, a Cross model describes our data well over a wide shear rate range. A Bingham plastic model appears to be a good constitutive model for the data measured at high shear rates when the shear was global, but at low shear stresses the approximation becomes inaccurate because the Bingham yield stress is only an approximation to what is actually a high viscosity creep behavior. This yield-stress-like creep behavior implies that initialization of levees in cryolava flows is more likely than would be inferred from previous cryo-rheological studies and may provide a partial explanation for features observed by the Cassini spacecraft on Titan, which are interpreted as steep-sided volcanic constructs [2]. This analysis will be critical in the development of future experiments designed to measure all the parameters controlling cryomagma rheologies for input into flow models. [1] Elachi et al. (2005) Science 308, 970-974. [2] Lopes et al. (2007) Icarus 186, 395-412. [3] Zhong et al. (in review) Icarus. [4] Kargel et al. (1991) Icarus 89, 93-11.

Study on Movable gel Profiling/Flooding System Optimization at Boundary Temperature

NASA Astrophysics Data System (ADS)

Gao, Shanshan; Xie, Gang; Zhang, Tiantian; Wang, Zhiqiang; Jiang, Peijun; Wei, Junjie; Gu, Yi; Lei, Xiaoyang; Guo, Suzhen; Lei, Shi

2017-12-01

65-75°C is the boundary temperature of phenol-formaldehyde resin and organic chrome crosslink with HPAM to generate movable gel. Generally speaking, when the reservoir temperature is below 65-75°C, the crosslinking agent is Organic chrome. Phenol-formaldehyde resin is used when the temperature is above 65-75°C. In this paper the gelation properties of phenol-formaldehyde resin and organic chrome were compared at 70°C. The experiment results showed that the crosslinking time of phenol-formaldehyde resin gel was longer and more conducive to field injection. In addition the phenol-formaldehyde resin gel had greater viscosity, adhesion and shearing resistance compared with the organic chrome gel. So the phenol-formaldehyde resin was chosen for further optimization. The crosslinking time was shortened and the gel viscosity increased with the increase of the polymer concentration. As the polymer crosslinker proportion increased The crosslinking time was shortened and the gel viscosity increased first and then decreased. Reinforcer NC and stabilizer WG were added to improve the temperature and salt tolerance of the gel. The gel formula suitable for the boundary temperature was obtained. The optimum polymer concentration is 1200mg/L, the polymer crosslinker proportion is 1:1.1, the best reinforcer concentration is 400mg/L and the concentration of the stabilizer is 150mg/L. The crosslinking time is 31h, the gel viscosity is above 2100mPa·s. The gel did not shrink and no water separation was observed at 70°C for 150 days. The viscosity retention rate was more than 70%.

Viscosity of ammonia at high temperature and pressure

DOE Office of Scientific and Technical Information (OSTI.GOV)

Sun, S.B.K.; Storvick, T.S.

1979-04-01

The viscosity of ammonia on five isotherms in the temperature range 448 to 598 K and pressures to 121 bar are reported. The measurements were made in a steady-state, capillary flow viscometer. The measurements are estimated to be accurate to better than 0.4% over the full range. 5 figures, 1 table.

The effect of medium viscosity on kinetics of ATP hydrolysis by the chloroplast coupling factor CF1.

PubMed

Malyan, Alexander N

2016-05-01

The coupling factor CF1 is a catalytic part of chloroplast ATP synthase which is exposed to stroma whose viscosity is many-fold higher than that of reaction mixtures commonly used to measure kinetics of CF1-catalyzed ATP hydrolysis. This study is focused on the effect of medium viscosity modulated by sucrose or bovine serum albumin (BSA) on kinetics of Ca(2+)- and Mg(2+)-dependent ATP hydrolysis by CF1. These agents were shown to reduce the maximal rate of Ca(2+)-dependent ATPase without changing the apparent Michaelis constant (К m), thus supporting the hypothesis on viscosity dependence of CF1 activity. For the sulfite- and ethanol-stimulated Mg(2+)-dependent reaction, the presence of sucrose increased К m without changing the maximal rate that is many-fold as high as that of Ca(2+)-dependent hydrolysis. The hydrolysis reaction was shown to be stimulated by low concentrations of BSA and inhibited by its higher concentrations, with the increasing maximal reaction rate estimated by extrapolation. Sucrose- or BSA-induced inhibition of the Mg(2+)-dependent ATPase reaction is believed to result from diffusion-caused deceleration, while its BSA-induced stimulation is probably caused by optimization of the enzyme structure. Molecular mechanisms of the inhibitory effect of viscosity are discussed. Taking into account high protein concentrations in the chloroplast stroma, it was suggested that kinetic parameters of ATP hydrolysis, and probably those of ATP synthesis in vivo as well, must be quite different from measurements taken at a viscosity level close to that of water.

High temperature breakdown of the Stokes-Einstein relation in a computer simulated Cu-Zr melt

DOE Office of Scientific and Technical Information (OSTI.GOV)

Han, X. J., E-mail: xjhan@sjtu.edu.cn; Li, J. G., E-mail: lijg@sjtu.edu.cn; Schober, H. R., E-mail: h.schober@fz-juelich.de

Transport properties and the Stokes-Einstein (SE) relation in liquid Cu{sub 8}Zr{sub 3} are studied by molecular dynamics simulation with a modified embedded atom potential. The critical temperature T{sub c} of mode coupling theory (MCT) is derived as 930 K from the self-diffusion coefficient D and viscosity η. The SE relation breaks down around T{sub SE} = 1900 K, which is far above T{sub c}. At temperatures below T{sub SE}, the product of D and η fluctuates around a constant value, similar to the prediction of MCT near T{sub c}. The influence of the microscopic atomic motion on macroscopic properties ismore » investigated by analyzing the time dependent liquid structure and the self-hole filling process. The self-holes for the two components are preferentially filled by atoms of the same component. The self-hole filling dynamics explains the different breakdown behaviors of the SE relation in Zr-rich liquid CuZr{sub 2} compared to Cu-rich Cu{sub 8}Zr{sub 3}. At T{sub SE}, a kink is found in the temperature dependence of both partial and total coordination numbers for the three atomic pair combinations and of the typical time of self-hole filling. This indicates a strong correlation between liquid structure, atomic dynamics, and the breakdown of SE relation. The previously suggested usefulness of the parameter d(D{sub 1}/D{sub 2})/dT to predict T{sub SE} is confirmed. Additionally we propose a viscosity criterion to predict T{sub SE} in the absence of diffusion data.« less

In situ measurement of gas composition changes in radio frequency plasmas using a quartz sensor

DOE Office of Scientific and Technical Information (OSTI.GOV)

Suzuki, Atsushi; Nonaka, Hidehiko

2009-09-15

A simple method using a quartz sensor (Q-sensor) was developed to observe gas composition changes in radio frequency (rf) plasmas. The output depends on the gases' absolute pressure, molecular weight, and viscosity. The pressure-normalized quartz sensor output depends only on the molecular weight and viscosity of the gas. Consequently, gas composition changes can be detected in the plasmas if a sensor can be used in the plasmas. Influences imparted by the plasmas on the sensor, such as those by reactive particles (e.g., radicals and ions), excited species, electrons, temperature, and electric potentials during measurements were investigated to test the applicabilitymore » of this quartz sensor measurement to plasma. The Q-sensor measurement results for rf plasmas with argon, hydrogen, and their mixtures are reproducible, demonstrating that the Q-sensor measurement is applicable for plasmas. In this work, pressure- and temperature-normalized Q-sensor output (NQO) were used to obtain the gas composition information of plasma. Temperature-normalization of the Q-sensor output enabled quartz sensor measurements near plasma electrodes, where the quartz sensor temperature increases. The changes in NQO agreed with results obtained by gas analysis using a quadrupole mass spectrometer. Results confirmed that the change in NQO is mainly attributable to changes in the densities and kinds of gas molecules in the plasma gas phase, not by other extrinsic influences of plasma. For argon, hydrogen, and argon-hydrogen plasmas, these changes correspond to reduction in nitrogen, production of carbon monoxide, and dissociation of hydrogen molecules, respectively. These changes in NQO qualitatively and somewhat quantitatively agreed with results obtained using gas analysis, indicting that the measurement has a potential application to obtain the gas composition in plasmas without disturbing industrial plasma processes.« less

Diffusivity measurements of volatile organics in levitated viscous aerosol particles

NASA Astrophysics Data System (ADS)

Bastelberger, Sandra; Krieger, Ulrich K.; Luo, Beiping; Peter, Thomas

2017-07-01

Field measurements indicating that atmospheric secondary organic aerosol (SOA) particles can be present in a highly viscous, glassy state have spurred numerous studies addressing low diffusivities of water in glassy aerosols. The focus of these studies is on kinetic limitations of hygroscopic growth and the plasticizing effect of water. In contrast, much less is known about diffusion limitations of organic molecules and oxidants in viscous matrices. These may affect atmospheric chemistry and gas-particle partitioning of complex mixtures with constituents of different volatility. In this study, we quantify the diffusivity of a volatile organic in a viscous matrix. Evaporation of single particles generated from an aqueous solution of sucrose and small amounts of volatile tetraethylene glycol (PEG-4) is investigated in an electrodynamic balance at controlled relative humidity (RH) and temperature. The evaporative loss of PEG-4 as determined by Mie resonance spectroscopy is used in conjunction with a radially resolved diffusion model to retrieve translational diffusion coefficients of PEG-4. Comparison of the experimentally derived diffusivities with viscosity estimates for the ternary system reveals a breakdown of the Stokes-Einstein relationship, which has often been invoked to infer diffusivity from viscosity. The evaporation of PEG-4 shows pronounced RH and temperature dependencies and is severely depressed for RH ≲ 30 %, corresponding to diffusivities < 10-14 cm2 s-1 at temperatures < 15 °C. The temperature dependence is strong, suggesting a diffusion activation energy of about 300 kJ mol-1. We conclude that atmospheric volatile organic compounds can be subject to severe diffusion limitations in viscous organic aerosol particles. This may enable an important long-range transport mechanism for organic material, including pollutant molecules such as polycyclic aromatic hydrocarbons (PAHs).

Effects of grain size evolution on mantle dynamics

NASA Astrophysics Data System (ADS)

Schulz, Falko; Tosi, Nicola; Plesa, Ana-Catalina; Breuer, Doris

2016-04-01

The rheology of planetary mantle materials is strongly dependent on temperature, pressure, strain-rate, and grain size. In particular, the rheology of olivine, the most abundant mineral of the Earth's upper mantle, has been extensively studied in the laboratory (e.g., Karato and Wu, 1993; Hirth and Kohlstedt, 2003). Two main mechanisms control olivine's deformation: dislocation and diffusion creep. While the former implies a power-law dependence of the viscosity on the strain-rate that leads to a non-Newtonian behaviour, the latter is sensitively dependent on the grain size. The dynamics of planetary interiors is locally controlled by the deformation mechanism that delivers the lowest viscosity. Models of the dynamics and evolution of planetary mantles should thus be capable to self-consistently distinguish which of the two mechanisms dominates at given conditions of temperature, pressure, strain-rate and grain size. As the grain size can affect the viscosity associated with diffusion creep by several orders of magnitude, it can strongly influence the dominant deformation mechanism. The vast majority of numerical, global-scale models of mantle convection, however, are based on the use of a linear diffusion-creep rheology with constant grain-size. Nevertheless, in recent studies, a new equation has been proposed to properly model the time-dependent evolution of the grain size (Austin and Evens, 2007; Rozel et al., 2010). We implemented this equation in our mantle convection code Gaia (Hüttig et al., 2013). In the framework of simple models of stagnant lid convection, we compared simulations based on the fully time-dependent equation of grain-size evolution with simulations based on its steady-state version. In addition, we tested a number of different parameters in order to identify those that affects the grain size to the first order and, in turn, control the conditions at which mantle deformation is dominated by diffusion or dislocation creep. References Austin, N. J. and Evans, B. (2007). Geology, 35(4):343. Hirth, G. and Kohlstedt, D. (2003). Geophysical Monograph Series, page 83105. Hüttig, C., Tosi, N., and Moore, W. B. (2013). Physics of the Earth and Planetary Interiors, 220:11-18. Karato, S.-i. and Wu, P. (1993). Science, 260(5109):771778. Rozel, A., Ricard, Y., and Bercovici, D. (2010). Geophysical Journal International, 184(2):719728.

Reference Correlation for the Viscosity of Ethane

DOE Office of Scientific and Technical Information (OSTI.GOV)

Vogel, Eckhard, E-mail: eckhard.vogel@uni-rostock.de; Span, Roland; Herrmann, Sebastian

2015-12-15

A new representation of the viscosity for the fluid phase of ethane includes a zero-density correlation and a contribution for the critical enhancement, initially both developed separately, but based on experimental data. The higher-density contributions are correlated as a function of the reduced density δ = ρ/ρ{sub c} and of the reciprocal reduced temperature τ = T{sub c}/T (ρ{sub c}—critical density and T{sub c}—critical temperature). The final formulation contains 14 coefficients obtained using a state-of-the-art linear optimization algorithm. The evaluation and choice of the selected primary data sets is reviewed, in particular with respect to the assessment used in earliermore » viscosity correlations. The new viscosity surface correlation makes use of the reference equation of state for the thermodynamic properties of ethane by Bücker and Wagner [J. Phys. Chem. Ref. Data 35, 205 (2006)] and is valid in the fluid region from the melting line to temperatures of 675 K and pressures of 100 MPa. The viscosity in the limit of zero density is described with an expanded uncertainty of 0.5% (coverage factor k = 2) for temperatures 290 < T/K < 625, increasing to 1.0% at temperatures down to 212 K. The uncertainty of the correlated values is 1.5% in the range 290 < T/K < 430 at pressures up to 30 MPa on the basis of recent measurements judged to be very reliable as well as 4.0% and 6.0% in further regions. The uncertainty in the near-critical region (1.001 < 1/τ < 1.010 and 0.8 < δ < 1.2) increases with decreasing temperature up to 3.0% considering the available reliable data. Tables of the viscosity calculated from the correlation are listed in an appendix for the single-phase region, for the vapor–liquid phase boundary, and for the near-critical region.« less

An environmentally friendly organosolv (ethanol-water) pulping of poplar wood.

PubMed

Akgul, Mehmet; Kirci, Huseyin

2009-09-01

In this study pulp production from the fast growing plant, poplar; was examined for organosolv pulping with or without catalysts. In order to find the optimum cooking conditions, 18 different cooking experiments were carried out. The effect of ethanol ratio, cooking time as well as catalyst was studied. It was observed that even at lower temperature (90 degrees C), cooking without catalyst was able to cause sufficient defiberization. It was seen that the increasing proportion of catalyst and cooking temperature resulted in an increased delignification. However in the case of using 0.02% acid catalyst pulp yield and viscosity were lowered to an unacceptable level. The most important cooking factors were found to be the proportion of acid catalyst. Furthermore, the delignification performance was found to be depending on the pH of the black liquor. In a result, the optimum pulp properties were obtained by cooking at 180 degrees C for 90 min with 50% ethanol mixture without catalyst. The pulp yield was noted as 44.49%, viscosity was 892 cm2 g(-1) and the kappa number was 67.

Temperature and chain length dependence of ultrafast vibrational dynamics of thiocyanate in alkylimidazolium ionic liquids: A random walk on a rugged energy landscape.

PubMed

Brinzer, Thomas; Garrett-Roe, Sean

2017-11-21

Ultrafast two-dimensional infrared spectroscopy of a thiocyanate vibrational probe (SCN - ) was used to investigate local dynamics in alkylimidazolium bis-[trifluoromethylsulfonyl]imide ionic liquids ([Im n,1 ][Tf 2 N], n = 2, 4, 6) at temperatures from 5 to 80 °C. The rate of frequency fluctuations reported by SCN - increases with increasing temperature and decreasing alkyl chain length. Temperature-dependent correlation times scale proportionally to temperature-dependent bulk viscosities of each ionic liquid studied. A multimode Brownian oscillator model demonstrates that very low frequency (<10 cm -1 ) modes primarily drive the observed spectral diffusion and that these modes broaden and blue shift on average with increasing temperature. An Arrhenius analysis shows activation barriers for local motions around the probe between 5.5 and 6.5 kcal/mol that are very similar to those for translational diffusion of ions. [Im 6,1 ][Tf 2 N] shows an unexpected decrease in activation energy compared to [Im 4,1 ][Tf 2 N] that may be related to mesoscopically ordered polar and nonpolar domains. A model of dynamics on a rugged potential energy landscape provides a unifying description of the observed Arrhenius behavior and the Brownian oscillator model of the low frequency modes.

The evolution of impact basins - Viscous relaxation of topographic relief. [for lunar surface modeling

NASA Technical Reports Server (NTRS)

Solomon, S. C.; Comer, R. P.; Head, J. W.

1982-01-01

A topographic profile of the young large lunar basin, Orientale, is presented in order to examine the effects of viscous relaxation on basin topography. Analytical models for viscous flow are considered, showing a wavelength-dependence of time constants for viscous decay on the decrease in viscosity with depth and on the extent of the isostatic compensation of the initial topography. Lunar rheological models which are developed include a half-space model for uniform Newtonian viscosity, density, and gravitational acceleration, a layer over inviscid half space model with material inviscid over geological time scales, and a layer with isostatic compensation where a uniformly viscous layer overlies an inviscid half space of higher density. Greater roughness is concluded, and has been observed, on the moon's dark side due to continued lower temperatures since the time of heavy bombardment.

Intraplate deformation, stress in the lithosphere and the driving mechanism for plate motions

NASA Technical Reports Server (NTRS)

Hager, Bradford H.

1988-01-01

During this period work was carried out on three fronts relevant to the understanding of intraplate deformation, stress in the lithosphere, and the driving mechanisms for plate motions: (1) observational constraints, using GPS geodesy on the deformation in the region of the boundry between the Pacific and North American plates in central and southern California; (2) numerical modeling of the effects of temperature dependent lithospheric viscosity on the stress and strain history of extensional regimes; and (3) improvement of estimates of mantle viscosity variation, the long-wave-length density variations in the mantle, and the topography of the core-mantel boundary from modeling of geoid anomalies, nutation, and changes in length of day. These projects are described in more detail, followed by a discussion of meetings attended and a list of abstracts and papers submitted and/or published.

Thermal shaft effects on load-carrying capacity of a fully coupled, variable-properties cryogenic journal bearing

NASA Technical Reports Server (NTRS)

Braun, M. J.; Wheeler, R. L., III; Hendricks, R. C.

1986-01-01

The purpose of this work was to perform a rather complete analysis for a cryogenic (oxygen) journal bearing. The Reynolds equation required coupling and simultaneous solution with the fluid energy equation. To correctly account for the changes in the fluid viscosity, the fluid energy equation was coupled with the shaft and bearing heat conduction energy equations. The effects of pressure and temperature on the density, viscosity, and load-carrying capacity were further discussed as analysis parameters, with respect to relative eccentricity and the angular velocity. The isothermal fluid case and the adiabatic fluid case represented the limiting boundaries. The discussion was further extrapolated to study the Sommerfeld number dependency on the fluid Nusselt number and its consequence on possible total loss of load-carrying capacity and/or seizure (catastrophic failure).

On steady two-dimensional Carreau fluid flow over a wedge in the presence of infinite shear rate viscosity

NASA Astrophysics Data System (ADS)

Khan, Masood; Sardar, Humara

2018-03-01

This paper investigates the steady two-dimensional flow over a moving/static wedge in a Carreau viscosity model with infinite shear rate viscosity. Additionally, heat transfer analysis is performed. Using suitable transformations, nonlinear partial differential equations are transformed into ordinary differential equations and solved numerically using the Runge-Kutta Fehlberg method coupled with the shooting technique. The effects of various physical parameters on the velocity and temperature distributions are displayed graphically and discussed qualitatively. A comparison with the earlier reported results has been made with an excellent agreement. It is important to note that the increasing values of the wedge angle parameter enhance the fluid velocity while the opposite trend is observed for the temperature field for both shear thinning and thickening fluids. Generally, our results reveal that the velocity and temperature distributions are marginally influenced by the viscosity ratio parameter. Further, it is noted that augmented values of viscosity ratio parameter thin the momentum and thermal boundary layer thickness in shear thickening fluid and reverse is true for shear thinning fluid. Moreover, it is noticed that the velocity in case of moving wedge is higher than static wedge.

Effect of pressure on viscosity of liquid Fe-alloys up to 16 GPa

NASA Astrophysics Data System (ADS)

Terasaki, H.; Ohtani, E.; Suzuki, A.; Nishida, K.; Sakamaki, T.; Shindo, S.; Funakoshi, K.

2005-12-01

Viscosity of liquid Fe-alloy is closely related to a convection behavior of the Earth's liquid outer core and also time scale of planetary core formation. In previous studies, viscosity of liquid Fe-S has been measured up to 7 GPa using X-ray radiography falling sphere method [Terasaki et al. 2001]. However, some technical problems, such as chemical reaction between the metal marker sphere and the Fe-alloy sample and insufficient image recording time for less viscous material, have been suggested. In this study, we have measured the viscosity of Fe-S and Fe-C liquids without those problems by using novel techniques combined with in situ X-ray radiography falling sphere method and extended the pressure range to 16 GPa. Falling sphere viscometry was carried out under high pressure and temperature using high speed CCD camera with 1500 ton Kawai-type multi-anvil device at BL04B1, SPring-8 in Japan. Starting compositions of Fe-alloy were Fe78S22 and Fe86C14 which correspond to near eutectic compositions at the experimental pressures. Viscosity marker sphere, which was made of Re or Pt, was coated by alumina in order to prevent the reaction between the sphere and the Fe-alloy sample. Falling sphere images were obtained with recording rate of 50 - 125 frame/second. Viscosity of liquid Fe-S was measured up to 16.1 GPa and 1763 K. Measured viscosity coefficients were in the range of 8.8 - 9.2 mPa-s which indicates that the activation volume of viscous flow is approximately a half of the previous estimations (1.5 cm3/mol). Viscosity of liquid Fe-C was measured up to 5 GPa and 1843 K. Viscosity coefficients are 4.7 - 4.9 mPa-s. Activation volume of Fe-C liquid is estimated to be 0.8 cm3/mol. This pressure dependence is consistent with the result of Lucas (1964) measured at ambient pressure. Consequently, viscosity of Fe-alloy liquids are likely to stay small in the Earth's interior and there is no large difference in viscosity coefficient and activation volume between Fe-S and Fe-C eutectic liquids in the range of measurements.

Drag reduction in homogeneous turbulence by scale-dependent effective viscosity.

PubMed

Benzi, Roberto; Ching, Emily S C; Procaccia, Itamar

2004-08-01

We demonstrate, by using suitable shell models, that drag reduction in homogeneous turbulence is usefully discussed in terms of a scale-dependent effective viscosity. The essence of the phenomenon of drag reduction found in models that couple the velocity field to the polymers can be recaptured by an "equivalent" equation of motion for the velocity field alone, with a judiciously chosen scale-dependent effective viscosity that succinctly summarizes the important aspects of the interaction between the velocity and the polymer fields. Finally, we clarify the differences between drag reduction in homogeneous and in wall bounded flows.

Internal friction in enzyme reactions.

PubMed

Rauscher, Anna; Derényi, Imre; Gráf, László; Málnási-Csizmadia, András

2013-01-01

The empirical concept of internal friction was introduced 20 years ago. This review summarizes the results of experimental and theoretical studies that help to uncover the nature of internal friction. After the history of the concept, we describe the experimental challenges in measuring and interpreting internal friction based on the viscosity dependence of enzyme reactions. We also present speculations about the structural background of this viscosity dependence. Finally, some models about the relationship between the energy landscape and internal friction are outlined. Alternative concepts regarding the viscosity dependence of enzyme reactions are also discussed. Copyright © 2012 International Union of Biochemistry and Molecular Biology, Inc.

Viscosity of the earth's core.

NASA Technical Reports Server (NTRS)

Gans, R. F.

1972-01-01

Calculation of the viscosity of the core at the boundary of the inner and outer core. It is assumed that this boundary is a melting transition and the viscosity limits of the Andrade (1934,1952) hypothesis (3.7 to 18.5 cp) are adopted. The corresponding kinematic viscosities are such that the precessional system explored by Malkus (1968) would be unstable. Whether it would be sufficiently unstable to overcome a severely subadiabatic temperature gradient cannot be determined.

Viscosities of Fe Ni, Fe Co and Ni Co binary melts

NASA Astrophysics Data System (ADS)

Sato, Yuzuru; Sugisawa, Koji; Aoki, Daisuke; Yamamura, Tsutomu

2005-02-01

Viscosities of three binary molten alloys consisting of the iron group elements, Fe, Ni and Co, have been measured by using an oscillating cup viscometer over the entire composition range from liquidus temperatures up to 1600 °C with high precision and excellent reproducibility. The viscosities measured showed good Arrhenius linearity for all the compositions. The viscosities of Fe, Ni and Co as a function of temperature are as follows: \\eqalign{ & \\log \\eta={-}0.6074 + 2493/T\\qquad for\\quad Fe\\\\ & \\log \\eta={-}0.5695 + 2157/T\\qquad for\\quad Ni \\\\ & \\log \\eta={-}0.6620 + 2430/T\\qquad for\\quad Co.} The isothermal viscosities of Fe-Ni and Fe-Co binary melts increase monotonically with increasing Fe content. On the other hand, in Ni-Co binary melt, the isothermal viscosity decreases slightly and then increases with increasing Co. The activation energy of Fe-Co binary melt increased slightly on mixing, and those of Fe-Ni and Ni-Co melts decreased monotonically with increasing Ni content. The above behaviour is discussed based on the thermodynamic properties of the alloys.

The dependence of efficiency of transmembrane molecular transfer using electroporation on medium viscosity.

PubMed

Sungailaitė, Sandra; Ruzgys, Paulius; Šatkauskienė, Ingrida; Čepurnienė, Karolina; Šatkauskas, Saulius

2015-01-01

In the present study, we aimed to evaluate the efficiency of drug and gene electrotransfer into cells in vitro depending on medium viscosity. Experiments were performed using Chinese hamster ovary cells. Efficiency of molecular electrotransfer depending of medium viscosity was evaluated using two different electroporation conditions: a high-voltage (HV) pulse and a combination of a high-voltage pulse and a low-voltage pulse (HV + LV). To evaluate the efficiency of molecular electrotransfer, anticancer drug bleomycin and two different plasmids coding for green fluorescent protein and luciferase were used. We found that a slight increase in medium viscosity from 1.3-1.4 mPa·s significantly decreased the transfection efficiency, both in terms of transfected cells and total protein production, which was abolished completely with an increase in medium viscosity to 6.1 mPa·s. Notably, at this medium viscosity, electrotransfer of the small anticancer drug was still efficient. Using HV and HV + LV pulse combinations, we showed that a decrease of DNA electrotransfer, especially at lower medium viscosities, can be compensated for by the LV pulse to some extent. On the other hand, the addition of the LV pulse after the HV pulse did not have any positive effect on the efficiency of bleomycin electrotransfer. These findings demonstrate that transfection is very susceptible to medium viscosity and highlights the importance of the electrophoretic component in experiments when a considerable transfection level is needed. Copyright © 2015 John Wiley & Sons, Ltd.

Femtosecond Raman-Induced Kerr Effect Study of Temperature-Dependent Intermolecular Dynamics in Molten Bis(trifluoromethylsulfonyl)amide Salts: Effects of Cation Species.

PubMed

Kakinuma, Shohei; Shirota, Hideaki

2018-05-25

In this study, we have investigated the effects of cation structures on the temperature dependence of the intermolecular vibrational dynamics of ionic liquids using femtosecond Raman-induced Kerr effect spectroscopy. The ionic liquids used in this study are bis(trifluoromethylsulfonyl)amide [NTf 2 ] - salts of the cations 1-butyl-3-methylimidazolium [C 4 MIm] + , 1-butyl-1-methylpyrrolidinium [Pyrr 14 ] + , 1-butylpyridinium [C 4 Py] + , butyldiethylmethylammonium [N 1224 ] + , triethyloctylammonium [N 2228 ] + , and triethyloctylphosphonium [P 2228 ] + . All of the ionic liquids show temperature-dependent low-frequency spectra. A difference in the temperature dependence between the spectra of the aromatic and nonaromatic cation based ionic liquids is especially significant. In the case of the aromatic cation based ionic liquids [C 4 MIm][NTf 2 ] and [C 4 Py][NTf 2 ], the spectral intensities in the low-frequency region below ca. 50 cm -1 increase and the high-frequency components at ca. 80 cm -1 shift to lower frequencies with rising temperature. In contrast, the ionic liquids based on nonaromatic cations only exhibit an increase in the low-frequency region below ca. 50 cm -1 with increasing temperature, while the high-frequency region of the spectra above ca. 50 cm -1 shows little change with variation of the temperature. These results suggest that the presence or absence of aromatic rings is the main factor in determining the temperature-dependent spectral features, particularly in the high-frequency region. We also found that the alkyl chain length and central atoms of the nonaromatic quaternary cations do not have much influence on the temperature-dependent spectral features. The first moments of the aromatic cation based ionic liquids are a little more sensitive to temperature than those of the nonaromatic cation based ionic liquids. The temperature-dependent viscosities and fragilities of the ionic liquids have also been examined.

A new study of the kinetics of curd production in the process of cheese manufacture.

PubMed

Muñoz, Susana Vargas; Torres, Maykel González; Guerrero, Francisco Quintanilla; Talavera, Rogelio Rodríguez

2017-11-01

We studied the role played by temperature and rennet concentration in the coagulation process for cheese manufacture and the evaluation of their kinetics. We concluded that temperature is the main factor that determines the kinetics. The rennet concentration was unimportant probably due to the fast action of the enzyme chymosin. The Dynamic light scattering technique allowed measuring the aggregate's size and their formation kinetics. The volume fraction of solids was determined from viscosity measurements, showing profiles that are in agreement with the size profiles. The results indicate that the formation of the aggregates for rennet cheese is strongly dependent on temperature and rennet concentration. The results revealed that at 35·5 °C the volume fraction of solids has the maximum slope, indicating that at this temperature the curd is formed rapidly. The optimal temperature throughout the process was established. Second-order kinetics were obtained for the process. We observed a quadratic dependence between the rennet volume and the volume fraction of solids (curd), thereby indicating that the kinetics of the curd production should be of order two.

Simultaneous viscosity and density measurement of small volumes of liquids using a vibrating microcantilever† †Electronic supplementary information (ESI) available. See DOI: 10.1039/c6an02674e Click here for additional data file.

PubMed Central

Payam, A. F.; Trewby, W.

2017-01-01

Many industrial and technological applications require precise determination of the viscosity and density of liquids. Such measurements can be time consuming and often require sampling substantial amounts of the liquid. These problems can partly be overcome with the use of microcantilevers but most existing methods depend on the specific geometry and properties of the cantilever, which renders simple, accurate measurement difficult. Here we present a new approach able to simultaneously quantify both the density and the viscosity of microliters of liquids. The method, based solely on the measurement of two characteristic frequencies of an immersed microcantilever, is completely independent of the choice of a cantilever. We derive analytical expressions for the liquid's density and viscosity and validate our approach with several simple liquids and different cantilevers. Application of our model to non-Newtonian fluids shows that the calculated viscosities are remarkably robust when compared to measurements obtained from a standard rheometer. However, the results become increasingly dependent on the cantilever geometry as the frequency-dependent nature of the liquid's viscosity becomes more significant. PMID:28352874

Initial-boundary value problem to 2D Boussinesq equations for MHD convection with stratification effects

NASA Astrophysics Data System (ADS)

Bian, Dongfen; Liu, Jitao

2017-12-01

This paper is concerned with the initial-boundary value problem to 2D magnetohydrodynamics-Boussinesq system with the temperature-dependent viscosity, thermal diffusivity and electrical conductivity. First, we establish the global weak solutions under the minimal initial assumption. Then by imposing higher regularity assumption on the initial data, we obtain the global strong solution with uniqueness. Moreover, the exponential decay rates of weak solutions and strong solution are obtained respectively.

Nitric Oxide Measurement Study. Volume II. Probe Methods,

DTIC Science & Technology

1980-05-01

case of the Task I study, it should be pointed out that at lower gas temperatures where much of the study was performed, the mass flow through the...third body as pointed out by Matthews, et al. (1977) but also dependent on the viscosity of the sampled gas for standard commercial units (Folsom and...substantially above the dew point (based on the maximum pressure in the sampling system and the initial water concentration) or (2) sample line and

Fuel system for diesel engine with multi-stage heated

NASA Astrophysics Data System (ADS)

Ryzhov, Yu N.; Kuznetsov, Yu A.; Kolomeichenko, A. V.; Kuznetsov, I. S.; Solovyev, R. Yu; Sharifullin, S. N.

2017-09-01

The article describes a fuel system of a diesel engine with a construction tractor multistage heating, allowing the use of pure rapeseed oil as a diesel engine fuel. The paper identified the kinematic viscosity depending on the temperature and composition of the mixed fuel, supplemented by the existing recommendations on the use of mixed fuels based on vegetable oils and developed the device allowing use as fuel for diesel engines of biofuels based on vegetable oils.

On relaxation nature of glass transition in amorphous materials

NASA Astrophysics Data System (ADS)

Sanditov, Damba S.; Ojovan, Michael I.

2017-10-01

A short review on relaxation theories of glass transition is presented. The main attention is paid to modern aspects of the glass transition equation qτg = C, suggested by Bartenev in 1951 (q - cooling rate of the melt, τg - structural relaxation time at the glass transition temperature Tg). This equation represents a criterion of structural relaxation at transition from liquid to glass at T = Tg (analogous to the condition of mechanical relaxation ωτ = 1, where the maximum of mechanical loss is observed). The empirical parameter С = δTg has the meaning of temperature range δTg that characterizes the liquid-glass transition. Different approaches of δTg calculation are reviewed. In the framework of the model of delocalized atoms a modified kinetic criterion of glass transition is proposed (q/Tg)τg = Cg, where Cg ≅ 7·10-3 is a practically universal dimensionless constant. It depends on fraction of fluctuation volume fg, which is frozen at the glass transition temperature Cg = fg/ln(1/fg). The value of fg is approximately constant fg ≅ 0.025. At Tg the process of atom delocalization, i.e. its displacement from the equilibrium position, is frozen. In silicate glasses atom delocalization is reduced to critical displacement of bridge oxygen atom in Si-O-Si bridge necessary to switch a valence bond according to Muller and Nemilov. An equation is derived for the temperature dependence of viscosity of glass-forming liquids in the wide temperature range, including the liquid-glass transition and the region of higher temperatures. Notion of (bridge) atom delocalization is developed, which is related to necessity of local low activation deformation of structural network for realization of elementary act of viscous flow - activated switch of a valence (bridge) bond. Without atom delocalization (;trigger mechanism;) a switch of the valence bond is impossible and, consequently, the viscous flow. Thus the freezing of atom delocalization process at low temperatures, around Tg, leads to the cease of the viscous flow and transition of a melt to a glassy state. This occurs when the energy of disordered lattice thermal vibrations averaged to one atom becomes equal or less than the energy of atom delocalization. The Bartenev equation for cooling rate dependence of glass transition temperature Tg = Tg(q) is discussed. The value of fg calculated from the data on the Tg(q) dependence coincides with result of the fg calculation using the data on viscosity near the glass transition. Derivation of the Bartenev equation with the account of temperature dependence of activation energy of glass transition process is considered. The obtained generalized relation describes the Tg(q) dependence in a wider interval of the cooling rate compared Bartenev equation. Experimental data related to standard cooling rate q = 3 K/min were used in this work.

Laboratory experiments on fragmentation of highly-viscous bubbly syrup

NASA Astrophysics Data System (ADS)

Kurihara, H.; Kameda, M.; Ichihara, M.

2006-12-01

Fragmentation of vesicular magma by rapid decompression is a key process in explosive eruptions. To determine the fragmentation criteria, we carried out laboratory experiments on magma fragmentation using analogous materials. We used commercial syrup as an analogous material of magma, because the viscosity was widely altered by adding or subtracting water contents in the syrup. We made the bubbly syrup by adding hydrogen peroxide with manganese oxide in the syrup. The amount of hydrogen peroxide is proportional to the gas volume fraction in the syrup. We measured the rheological properties of the syrup. Zero shear viscosity η was measured by a rotating viscometer and a fiber elongation technique. Glass transition temperature was measured by differential scanning calorimetry. The measured data indicated that the temperature dependence of viscosity was described well using Williams-Landel-Ferry (WLF) equation. The solid content of syrup alters the viscosity as well as the glass transition temperature, though it may hardly affect the rigidity μ, which was measured by ultrasonic test in our previous work. We used a pressurized vertical tube with a large vacuum vessel to apply the rapid decompression on the material. An acrylic container, filled with the bubbly syrup, was placed in the bottom of the pressurized tube. By rupturing the diaphragms inserted between the tube and the vacuum vessel, the bubbly syrup is rapidly decompressed due to expansion of the pressurized gas in the tube. A high-speed video camera was used to obtain sequential images of the materials. Pressure transducers were mounted on the sidewall of the tube and the bottom of the container. The initial pressure was varied from 1 MPa to 5 MPa. The gas-volume fraction of the syrup under pressure was fixed as 2 % to 20%. The viscosity varied from 105 Pa·s to 108 Pa·s. We successfully observed three principal behaviors using the present analogous material; brittle fragmentation, partial fracture and ductile expansion without crack initiation. From all the experimental data, in conclusion, the fragmentation is observed when the pressure drop Δ p reaches a critical value within the order of relaxation time of syrup, which is defined as η/μ. Simultaneously, the initial gas volume fraction should be larger than a critical value, which decreases as the initial high-pressure is larger.

Time-dependent calculations of molten pool formation and thermal plasma with metal vapour in gas tungsten arc welding

NASA Astrophysics Data System (ADS)

Tanaka, M.; Yamamoto, K.; Tashiro, S.; Nakata, K.; Yamamoto, E.; Yamazaki, K.; Suzuki, K.; Murphy, A. B.; Lowke, J. J.

2010-11-01

A gas tungsten arc (GTA) was modelled taking into account the contamination of the plasma by metal vapour from the molten anode. The whole region of GTA atmosphere including the tungsten cathode, the arc plasma and the anode was treated using a unified numerical model. A viscosity approximation was used to express the diffusion coefficient in terms of viscosity of the shielding gas and metal vapour. The transient two-dimensional distributions of temperature, velocity of plasma flow and iron vapour concentration were predicted, together with the molten pool as a function of time for a 150 A arc current at atmospheric pressure, both for helium and argon gases. It was shown that the thermal plasma in the GTA was influenced by iron vapour from the molten pool surface and that the concentration of iron vapour in the plasma was dependent on the temperature of the molten pool. GTA on high sulfur stainless steel was calculated to discuss the differences between a low sulfur and a high sulfur stainless steel anode. Helium was selected as the shielding gas because a helium GTA produces more metal vapour than an argon GTA. In the GTA on a high sulfur stainless steel anode, iron vapour and current path were constricted. Radiative emission density in the GTA on high sulfur stainless steel was also concentrated in the centre area of the arc plasma together with the iron vapour although the temperature distributions were almost the same as that in the case of a low sulfur stainless steel anode.

A thermodynamic model to predict electron mobility in superfluid helium.

PubMed

Aitken, Frédéric; Volino, Ferdinand; Mendoza-Luna, Luis Guillermo; Haeften, Klaus von; Eloranta, Jussi

2017-06-21

Electron mobility in superfluid helium is modeled between 0.1 and 2.2 K by a van der Waals-type thermodynamic equation of state, which relates the free volume of solvated electrons to temperature, density, and phase dependent internal pressure. The model is first calibrated against known electron mobility reference data along the saturated vapor pressure line and then validated to reproduce the existing mobility literature values as a function of pressure and temperature with at least 10% accuracy. Four different electron mobility regimes are identified: (1) Landau critical velocity limit (T ≈ 0), (2) mobility limited by thermal phonons (T < 0.6 K), (3) thermal phonon and discrete roton scattering ("roton gas") limited mobility (0.6 K < T < 1.2 K), and (4) the viscous liquid ("roton continuum") limit (T > 1.2 K) where the ion solvation structure directly determines the mobility. In the latter regime, the Stokes equation can be used to estimate the hydrodynamic radius of the solvated electron based on its mobility and fluid viscosity. To account for the non-continuum behavior appearing below 1.2 K, the temperature and density dependent Millikan-Cunningham factor is introduced. The hydrodynamic electron bubble radii predicted by the present model appear generally larger than the solvation cavity interface barycenter values obtained from density functional theory (DFT) calculations. Based on the classical Stokes law, this difference can arise from the variation of viscosity and flow characteristics around the electron. The calculated DFT liquid density profiles show distinct oscillations at the vacuum/liquid interface, which increase the interface rigidity.

[Effect of physical properties of respiratory gas on pneumotachographic measurement of ventilation in newborn infants].

PubMed

Foitzik, B; Schmalisch, G; Wauer, R R

1994-04-01

The measurement of ventilation in neonates has a number of specific characteristics; in contrast to lung function testing in adults, the inspiratory gas for neonates is often conditioned. In pneumotachographs (PNT) based on Hagen-Poiseuille's law, changes in physical characteristics of respiratory gas (temperature, humidity, pressure and oxygen fraction [FiO2]) produce a volume change as calculated with the ideal gas equation p*V/T = const; in addition, the viscosity of the gas is also changed, thus leading to measuring errors. In clinical practice, the effect of viscosity on volume measurement is often ignored. The accuracy of these empirical laws was investigated in a size 0 Fleisch-PNT using a flow-through technique and variously processed respiratory gas. Spontaneous breathing was simulated with the aid of a calibration syringe (20 ml) and a rate of 30 min-1. The largest change in viscosity (11.6% at 22 degrees C and dry gas) is found with an increase in FiO2 (21...100%). A rise in temperature from 24 to 35 degrees C (dry air) produced an increase in viscosity of 5.2%. An increase of humidity (0...90%, 35 degrees C) decreased the viscosity by 3%. A partial compensation of these viscosity errors is thus possible. Pressure change (0...50 mbar, under ambient conditions) caused no measurable viscosity error. With the exception of temperature, the measurements have shown good agreement between the measured volume measuring errors and those calculated from viscosity changes. If the respiratory gas differs from ambient air (e.g. elevated FiO2) or if the PNT is calibrated under BTPS conditions, changes in viscosity must not be neglected when performing accurate ventilation measurements. On the basis of the well-known physical laws of Dalton, Thiesen and Sutherland, a numerical correction of adequate accuracy is possible.

Systematic parameter study of hadron spectra and elliptic flow from viscous hydrodynamic simulations of Au+Au collisions at sNN=200 GeV

NASA Astrophysics Data System (ADS)

Shen, Chun; Heinz, Ulrich; Huovinen, Pasi; Song, Huichao

2010-11-01

Using the (2+1)-dimensional viscous hydrodynamic code vish2+1 [H. Song and U. Heinz, Phys. Lett. BPYLBAJ0370-269310.1016/j.physletb.2007.11.019 658, 279 (2008); H. Song and U. Heinz, Phys. Rev. CPRVCAN0556-281310.1103/PhysRevC.77.064901 77, 064901 (2008); H. Song, Ph. D. thesis, The Ohio State University, 2009], we present systematic studies of the dependence of pion and proton transverse-momentum spectra and their elliptic flow in 200A GeV Au+Au collisions on the parameters of the hydrodynamic model (thermalization time, initial entropy density distribution, decoupling temperature, equation of state, and specific shear viscosity η/s). We identify a tension between the slope of the proton spectra, which (within hydrodynamic simulations that assume a constant shear viscosity to entropy density ratio) prefer larger η/s values, and the slope of the pT dependence of charged hadron elliptic flow, which prefers smaller values of η/s. Changing other model parameters does not appear to permit dissolution of this tension.

Systematic parameter study of hadron spectra and elliptic flow from viscous hydrodynamic simulations of Au+Au collisions at {radical}(s{sub NN})=200 GeV

DOE Office of Scientific and Technical Information (OSTI.GOV)

Shen Chun; Heinz, Ulrich; Huovinen, Pasi

2010-11-15

Using the (2+1)-dimensional viscous hydrodynamic code vish2+1[H. Song and U. Heinz, Phys. Lett. B 658, 279 (2008); H. Song and U. Heinz, Phys. Rev. C 77, 064901 (2008); H. Song, Ph. D. thesis, The Ohio State University, 2009], we present systematic studies of the dependence of pion and proton transverse-momentum spectra and their elliptic flow in 200A GeV Au+Au collisions on the parameters of the hydrodynamic model (thermalization time, initial entropy density distribution, decoupling temperature, equation of state, and specific shear viscosity {eta}/s). We identify a tension between the slope of the proton spectra, which (within hydrodynamic simulations that assumemore » a constant shear viscosity to entropy density ratio) prefer larger {eta}/s values, and the slope of the p{sub T} dependence of charged hadron elliptic flow, which prefers smaller values of {eta}/s. Changing other model parameters does not appear to permit dissolution of this tension.« less

Effect of viscosity on rolling-element fatigue life at cryogenic temperature with fluorinated ether lubricants

NASA Technical Reports Server (NTRS)

Dietrich, M. W.; Zaretsky, E. V.

1975-01-01

Rolling-element fatigue tests were conducted with 12.7-mm-(1/2-in.-) diameter AISI 52100 steel balls in the NASA five-ball fatigue tester, with a maximum hertz stress of 5500 mN/m2 (800 000 psi), a shaft speed of 4750 rpm, lubricant temperature of 200 K (360 R), a contact angle of 20 deg, using four fluorinated ether lubricants of varying viscosities. No statistically significant differences in rolling-element fatigue life occurred using the four viscosity levels. Elastohydrodynamic calculations indicate that values of the lubricant film parameter were approximately 2 or greater.

Pressure-viscosity measurements for several lubricants to 5.5 x 10 to the 8th power Newtons per square meter (8 x 10 to the 4th psi) and 149 C (300 F)

NASA Technical Reports Server (NTRS)

Jones, W. R.; Johnson, R. L.; Winer, W. O.; Sanborn, D. M.

1974-01-01

A capillary viscometer was used to measure viscosity as a function of pressure, temperature, and shear stress for a number of lubricants. The conditions under which the measurements were made are specified. The results obtained for each material are analyzed. It was determined that all pressure-viscosity coefficients decreased with increasing temperature. Data from other techniques such as optical elastohydrodynamics, oscillating crystal, and low shear capillary viscometry were compared with the results obtained.

Effects of molecular size and structure on self-diffusion coefficient and viscosity for saturated hydrocarbons having six carbon atoms.

PubMed

Iwahashi, Makio; Kasahara, Yasutoshi

2007-01-01

Self-diffusion coefficients and viscosities for the saturated hydrocarbons having six carbon atoms such as hexane, 2-methylpentane (2MP), 3-methylpentane (3MP), 2,2-dimethylbutane (22DMB), 2,3-dimethylbutane (23DMB), methylcyclopentane (McP) and cyclohexane (cH) were measured at various constant temperatures; obtained results were discussed in connection with their molar volumes, molecular structures and thermodynamic properties. The values of self-diffusion coefficients as the microscopic property were inversely proportional to those of viscosities as the macroscopic property. The order of their viscosities was almost same to those of their melting temperatures and enthalpies of fusion, which reflect the attractive interactions among their molecules. On the other hand, the order of the self-diffusion coefficients inversely related to the order of the melting temperatures and the enthalpies of the fusion. Namely, the compound having the larger attractive interaction mostly shows the less mobility in its liquid state, e.g., cyclohexane (cH), having the largest attractive interaction and the smallest molar volume exhibits an extremely large viscosity and small self-diffusion coefficient comparing with other hydrocarbons. However, a significant exception was 22DMB, being most close to a sphere: In spite of the smallest attractive interaction and the largest molar volume of 22DMB in the all samples, it has the thirdly larger viscosity and the thirdly smaller self-diffusion coefficient. Consequently, the dynamical properties such as self-diffusion and viscosity for the saturated hydrocarbons are determined not only by their attractive interactions but also by their molecular structures.

Do Clustering Monoclonal Antibody Solutions Really Have a Concentration Dependence of Viscosity?

PubMed Central

Pathak, Jai A.; Sologuren, Rumi R.; Narwal, Rojaramani

2013-01-01

Protein solution rheology data in the biophysics literature have incompletely identified factors that govern hydrodynamics. Whereas spontaneous protein adsorption at the air/water (A/W) interface increases the apparent viscosity of surfactant-free globular protein solutions, it is demonstrated here that irreversible clusters also increase system viscosity in the zero shear limit. Solution rheology measured with double gap geometry in a stress-controlled rheometer on a surfactant-free Immunoglobulin solution demonstrated that both irreversible clusters and the A/W interface increased the apparent low shear rate viscosity. Interfacial shear rheology data showed that the A/W interface yields, i.e., shows solid-like behavior. The A/W interface contribution was smaller, yet nonnegligible, in double gap compared to cone-plate geometry. Apparent nonmonotonic composition dependence of viscosity at low shear rates due to irreversible (nonequilibrium) clusters was resolved by filtration to recover a monotonically increasing viscosity-concentration curve, as expected. Although smaller equilibrium clusters also existed, their size and effective volume fraction were unaffected by filtration, rendering their contribution to viscosity invariant. Surfactant-free antibody systems containing clusters have complex hydrodynamic response, reflecting distinct bulk and interface-adsorbed protein as well as irreversible cluster contributions. Literature models for solution viscosity lack the appropriate physics to describe the bulk shear viscosity of unstable surfactant-free antibody solutions. PMID:23442970

Thermal Evolution of the Earth from a Plate Tectonics Point of View

NASA Astrophysics Data System (ADS)

Grigne, C.; Combes, M.; Le Yaouanq, S.; Husson, L.; Conrad, C. P.; Tisseau, C.

2011-12-01

Earth's thermal history is classically studied using scaling laws that link the surface heat loss to the temperature and viscosity of the convecting mantle. When such a parameterization is used in the global heat budget of the Earth to integrate the mantle temperature backwards in time, a runaway increase of temperature is obtained, leading to the so-called "thermal catastrophe". We propose a new approach that does not rely on convective scaling laws but instead considers the dynamics of plate tectonics, including temperature-dependent surface processes. We use a multi-agent system to simulate time-dependent plate tectonics in a 2D cylindrical geometry with evolutive plate boundaries. Plate velocities are computed using local force balance and explicit parameterizations for plate boundary processes such as trench migration, subduction initiation, continental breakup and plate suturing. The number of plates is not imposed but emerges naturally. At a given time step, heat flux is integrated from the seafloor age distribution and a global heat budget is used to compute the evolution of mantle temperature. This approach has a very low computational cost and allows us to study the effect of a wide range of input parameters on the long-term thermal evolution of the system. For Earth-like parameters, an average cooling rate of 60-70K per billion years is obtained, which is consistent with petrological and rheological constraints. Two time scales arise in the evolution of the heat flux: a linear long-term decrease and high-amplitude short-term fluctuations due to tectonic rearrangements. We show that the viscosity of the mantle is not a key parameter in the thermal evolution of the system and that no thermal catastrophe occurs when considering tectonic processes. The cooling rate of the Earth depends mainly on its ability to replace old insulating seafloor by young thin oceanic lithosphere. Therefore, the main controlling factors are parameters such as the resistance of continental lithosphere to breakup or the critical age for subduction initiation. We infer that simple convective considerations alone cannot account for the complex nature of mantle heat loss and that tectonic processes dictate the thermal evolution of the Earth.

Femtosecond Raman-Induced Kerr Effect Study of Temperature-Dependent Intermolecular Dynamics in Imidazolium-Based Ionic Liquids: Effects of Anion Species and Cation Alkyl Groups.

PubMed

Kakinuma, Shohei; Ishida, Tateki; Shirota, Hideaki

2017-01-12

The temperature dependence of the intermolecular vibrational dynamics in imidazolium-based ionic liquids (ILs) with 10 different anions was studied by femtosecond Raman-induced Kerr effect spectroscopy. For all ILs investigated in this study, the intensity in the low-frequency region below 50 cm -1 increases, and the spectral density in the high-frequency region above 80 cm -1 decreases (and shows a redshift) with increasing temperature. The first phenomenon would be attributed to the activation of the translational vibrational motions, whereas the second one is ascribed to the slowing librational motion of the imidazolium ring with increasing temperature. Calculated spectra of the density of states for the intermolecular vibrations of 1-butyl-3-methylimidazolium hexafluorophosphate, which is one of the experiment samples studied here, obtained by molecular dynamics simulation agreed well with the experimental results and confirmed the spectral assignments. When we compared the difference spectra between spectra measured at various temperatures and the spectrum measured at 293 K, a clear difference was found in the ∼50 cm -1 region of the Kerr spectra of 1-butyl-3-methylimidazolium thiocyanate and 1-butyl-3-methylimidazolium dicyanamide from those of the other ILs. The difference might have originated from the librational motions of the corresponding anions. We also compared the temperature-dependent Kerr spectra of hexafluorophosphate salts of 1-butyl-3-methylimidazolium, 1-hexyl-3-methylimidazolium, and 1-heptyl-3-methylimidazolium cations. These ILs showed a similar temperature dependence, which was not affected by the alkyl group length. The temperature-dependent viscosities and glass transition temperatures of the ILs were also estimated to determine their fragilities.

Kinetics of phloretin binding to phosphatidylcholine vesicle membranes

PubMed Central

1980-01-01

The submillisecond kinetics for phloretin binding to unilamellar phosphatidylcholine (PC) vesicles was investigated using the temperature-jump technique. Spectrophotometric studies of the equilibrium binding performed at 328 nm demonstrated that phloretin binds to a single set of independent, equivalent sites on the vesicle with a dissociation constant of 8.0 microM and a lipid/site ratio of 4.0. The temperature of the phloretin-vesicle solution was jumped by 4 degrees C within 4 microseconds producing a monoexponential, concentration-dependent relaxation process with time constants in the 30--200-microseconds time range. An analysis of the concentration dependence of relaxation time constants at pH 7.30 and 24 degrees C yielded a binding rate constant of 2.7 X 10(8) M-1 s-1 and an unbinding constant of 2,900 s-1; approximately 66 percent of total binding sites are exposed at the outer vesicle surface. The value of the binding rate constant and three additional observations suggest that the binding kinetics are diffusion limited. The phloretin analogue, naringenin, which has a diffusion coefficient similar to phloretin yet a dissociation constant equal to 24 microM, bound to PC vesicle with the same rate constant as phloretin did. In addition, the phloretin-PC system was studied in buffers made one to six times more viscous than water by addition of sucrose or glycerol to the differ. The equilibrium affinity for phloretin binding to PC vesicles is independent of viscosity, yet the binding rate constant decreases with the expected dependence (kappa binding alpha 1/viscosity) for diffusion-limited processes. Thus, the binding rate constant is not altered by differences in binding affinity, yet depends upon the diffusion coefficient in buffer. Finally, studies of the pH dependence of the binding rate constant showed a dependence (kappa binding alpha [1 + 10pH-pK]) consistent with the diffusion-limited binding of a weak acid. PMID:7391812

Loss of FliL alters Proteus mirabilis surface sensing and temperature-dependent swarming.

PubMed

Lee, Yi-Ying; Belas, Robert

2015-01-01

Proteus mirabilis is a dimorphic motile bacterium well known for its flagellum-dependent swarming motility over surfaces. In liquid, P. mirabilis cells are 1.5- to 2.0-μm swimmer cells with 4 to 6 flagella. When P. mirabilis encounters a solid surface, where flagellar rotation is limited, swimmer cells differentiate into elongated (10- to 80-μm), highly flagellated swarmer cells. In order for P. mirabilis to swarm, it first needs to detect a surface. The ubiquitous but functionally enigmatic flagellar basal body protein FliL is involved in P. mirabilis surface sensing. Previous studies have suggested that FliL is essential for swarming through its involvement in viscosity-dependent monitoring of flagellar rotation. In this study, we constructed and characterized ΔfliL mutants of P. mirabilis and Escherichia coli. Unexpectedly and unlike other fliL mutants, both P. mirabilis and E. coli ΔfliL cells swarm (Swr(+)). Further analysis revealed that P. mirabilis ΔfliL cells also exhibit an alteration in their ability to sense a surface: e.g., ΔfliL P. mirabilis cells swarm precociously over surfaces with low viscosity that normally impede wild-type swarming. Precocious swarming is due to an increase in the number of elongated swarmer cells in the population. Loss of fliL also results in an inhibition of swarming at <30°C. E. coli ΔfliL cells also exhibit temperature-sensitive swarming. These results suggest an involvement of FliL in the energetics and function of the flagellar motor. Copyright © 2015, American Society for Microbiology. All Rights Reserved.

Dynamic-compliance and viscosity of PET and PEN

NASA Astrophysics Data System (ADS)

Weick, Brian L.

2016-05-01

Complex dynamic-compliance and in-phase dynamic-viscosity data are presented and analyzed for PET and PEN advanced polyester substrates used for magnetic tapes. Frequency-temperature superposition is used to predict long-term behavior. Temperature and frequency ranges for the primary glass transition and secondary transitions are discussed and compared for PET and PEN. Shift factors from frequency-temperature superposition are used to determine activation energies for the transitions, and WLF parameters are determined for the polyester substrates.

Dynamic-compliance and viscosity of PET and PEN

DOE Office of Scientific and Technical Information (OSTI.GOV)

Weick, Brian L.

Complex dynamic-compliance and in-phase dynamic-viscosity data are presented and analyzed for PET and PEN advanced polyester substrates used for magnetic tapes. Frequency-temperature superposition is used to predict long-term behavior. Temperature and frequency ranges for the primary glass transition and secondary transitions are discussed and compared for PET and PEN. Shift factors from frequency-temperature superposition are used to determine activation energies for the transitions, and WLF parameters are determined for the polyester substrates.

Convective Differentiation of the Earth's Mantle

NASA Astrophysics Data System (ADS)

Hansen, U.; Schmalzl, J.; Stemmer, K.

2007-05-01

The differentiation of the Earth is likely to be influenced by convective motions within the early mantle. Double- diffusive convection (d.d.c), driven by thermally and compositionally induced density differences is considered as a vital mechanism behind the dynamic differentiation of the early mantle.. We demonstrate that d.d.c can lead to layer formation on a planetary scale in the diffusive regime where composition stabilizes the system whil heat provides the destabilizing force. Choosing initial conditions in which a stable compositional gradient overlies a hot reservoir we mimic the situation of a planet in a phase after core formation. Differently from earlier studies we fixed the temperature rather than the heat flux at the lower boundary, resembling a more realistic condition for the core-mantle boundary. We have carried out extended series of numerical experiments, ranging from 2D calculations in constant viscosity fluids to fully 3D experiments in spherical geometry with strongly temperature dependent viscosity. The buoyancy ratio R and the Lewis number Le are the important dynamical parameters. In all scenarios we could identify a parameter regime where the non-layered initial structure developed into a state consisting of several, mostly two layers. Initially plumes from the bottom boundary homogenize a first layer which subsequently thickens. The bottom layer heats up and then convection is initiated in the top layer. This creates dynamically (i.e. without jump in the material behavior) a stack of separately convecting layers. The bottom layer is significantly thicker than the top layer. Strongly temperature dependent viscosity leads to a more complex evolution The formation of the bottom layer is followed by the generation of several layers on top. Finally the uppermost layer starts to convect. In general, the multilayer structure collapses into a two layer system. We employed a numerical technique, allowing for a diffusion free treatment of the compositional field. In each case a similar evolution has been observed. This indicates that a temporary formation of layered structures in planetary interiors is a typical phenomenon. Moreover, in this scenario, plate tectonics appears only in later stages of the evolution.

Study of rheological behaviour of wines

NASA Astrophysics Data System (ADS)

Trávníček, Petr; Burg, Patrik; Krakowiak-Bal, Anna; Junga, Petr; Vítěz, Tomáš; Ziemiańczyk, Urszula

2016-10-01

This study deals with rheological properties of various wine varieties. Samples of the following wines were used for this experiment: André, Cabernet Moravia, Laurot, Saint Laurent, Gruner Veltliner, Pinot Blanc, Müller Thurgau, and Riesling Italico. These samples were obtained from wine produced from the grapes collected in the Czech Republic (Morava region, subregion Velke Pavlovice). In the first phase, the chemical composition of the samples was determined. The following chemical parameters were determined: total acidity, pH, content of the alcohol, reduced sugars, free SO2, total SO2, and volatile acids. In the second phase of the study, the physical properties of the samples were determined and the samples of the wines were subjected to rheological tests. These tests consisted in determination of apparent viscosity in relation to temperature, hysteresis loop tests, and apparent viscosity related to time. The dependence of the shear rate on the shear stress was described with the Herschel-Bulkley mathematical model. The experiment yielded the following findings: seven out of the eight samples behaved as non-Newtonian fluids at low temperature (5°C); non-Newtonian behaviour was changed into Newtonian at the temperature higher than 10°C; non-Newtonian behaviour was characterised as thixotropic behaviour; the degree of thixotropy is relatively small and reaches 1.85 Pa s-1 ml-1.

Comparison of polynomial and neural fuzzy models as applied to the ethanolamine pulping of vine shoots.

PubMed

Jiménez, L; Angulo, V; Caparrós, S; Ariza, J

2007-12-01

The influence of operational variables in the pulping of vine shoots by use of ethanolamine [viz. temperature (155-185 degrees C), cooking time (30-90min) and ethanolamine concentration (50-70% v/v)] on the properties of the resulting pulp (viz. yield, kappa index, viscosity and drainability) was studied. A central composite factorial design was used in conjunction with the software BMDP and ANFIS Edit Matlab 6.5 to develop polynomial and fuzzy neural models that reproduced the experimental results of the dependent variables with errors less than 10%. Both types of models are therefore effective with a view to simulating the ethanolamine pulping process. Based on the proposed equations, the best choice is to use values of the operational valuables resulting in near-optimal pulp properties while saving energy and immobilized capital on industrial facilities by using lower temperatures and shorter processing times. One combination leading to near-optimal properties with reduced costs is using a temperature of 180 degrees C and an ethanolamine concentration of 60% for 60min, to obtain pulp with a viscosity of 6.13% lower than the maximum value (932.8ml/g) and a drainability of 5.49% lower than the maximum value (71 (o)SR).

Anisotropic stress correlations in two-dimensional liquids

DOE PAGES

Wu, Bin; Iwashita, Takuya; Egami, Takeshi

2015-03-01

In this paper we demonstrate the presence of anisotropic stress correlations in the simulated 2D liquids. Whereas the temporal correlation of macroscopic shear stress is known to contribute to viscosity via the Green-Kubo formula, the general question regarding angular dependence of the spatial correlation among atomic level stresses in liquids without external shear has not been explored. Besides the apparent anisotropicity with well-defined symmetry, we found that the characteristic length of shear stress correlation depends on temperature and follows the power law, suggesting divergence around the glass transition temperature. The anisotropy of the stress correlations can be explained in termsmore » of the inclusion model by Eshelby, based upon which we suggest that the mismatch between the atom and its nearest neighbor cage produces the atomic level stress as well as the long-range stress fields.« less

FOR STIMULI-RESPONSIVE POLYMERS WITH ENHANCED EFFICIENCY IN RESERVOIR RECOVERY PROCESSES

DOE Office of Scientific and Technical Information (OSTI.GOV)

Charles McCormick; Roger Hester

To date, our synthetic research efforts have been focused on the development of stimuli-responsive water-soluble polymers designed for use in enhanced oil recovery (EOR) applications. These model systems are structurally tailored for potential application as viscosifiers and/or mobility control agents for secondary and tertiary EOR methods. The following report discloses the progress of our ongoing research of polyzwitterions, polymers derived from monomers bearing both positive and negative charges, that show the ability to sustain or increase their hydrodynamic volume (and thus, solution viscosity) in the presence of electrolytes. Such polymers appear to be well-suited for use under conditions similar tomore » those encountered in EOR operations. Additionally, we disclose the synthesis and characterization of a well-defined set of polyacrylamide (PAM) homopolymers that vary by MW. The MW of the PAM samples is controlled by addition of sodium formate to the polymerization medium as a conventional chain transfer agent. Data derived from polymer characterization is used to determine the kinetic parameter C{sub CT}, the chain transfer constant to sodium formate under the given polymerization conditions. The PAM homopolymer series will be employed in future set of experiments designed to test a simplified intrinsic viscosity equation. The flow resistance of a polymer solution through a porous medium is controlled by the polymer's hydrodynamic volume, which is strongly related to it's intrinsic viscosity. However, the hydrodynamic volume of a polymer molecule in an aqueous solution varies with fluid temperature, solvent composition, and polymer structure. This report on the theory of polymer solubility accentuates the importance of developing polymer solutions that increase in intrinsic viscosity when fluid temperatures are elevated above room conditions. The intrinsic viscosity response to temperature and molecular weight variations of three polymer solutions verified the modeling capability of a simplified intrinsic viscosity equation. These results imply that the simplified intrinsic viscosity equation is adequate in modeling polymer coil size response to solvent composition, temperature and polymer molecular weight. The equation can be used to direct efforts to produce superior polymers for mobility control during flooding of reservoirs at elevated temperatures.« less