Sample records for temperature depth profiles

  1. Interpreting Repeated Temperature-Depth Profiles for Groundwater Flow

    NASA Astrophysics Data System (ADS)

    Bense, Victor F.; Kurylyk, Barret L.; van Daal, Jonathan; van der Ploeg, Martine J.; Carey, Sean K.

    2017-10-01

    Temperature can be used to trace groundwater flows due to thermal disturbances of subsurface advection. Prior hydrogeological studies that have used temperature-depth profiles to estimate vertical groundwater fluxes have either ignored the influence of climate change by employing steady-state analytical solutions or applied transient techniques to study temperature-depth profiles recorded at only a single point in time. Transient analyses of a single profile are predicated on the accurate determination of an unknown profile at some time in the past to form the initial condition. In this study, we use both analytical solutions and a numerical model to demonstrate that boreholes with temperature-depth profiles recorded at multiple times can be analyzed to either overcome the uncertainty associated with estimating unknown initial conditions or to form an additional check for the profile fitting. We further illustrate that the common approach of assuming a linear initial temperature-depth profile can result in significant errors for groundwater flux estimates. Profiles obtained from a borehole in the Veluwe area, Netherlands in both 1978 and 2016 are analyzed for an illustrative example. Since many temperature-depth profiles were collected in the late 1970s and 1980s, these previously profiled boreholes represent a significant and underexploited opportunity to obtain repeat measurements that can be used for similar analyses at other sites around the world.

  2. Maine Geological Survey Borehole Temperature Profiles

    DOE Data Explorer

    Marvinney, Robert

    2013-11-06

    This dataset includes temperature profiles from 30 boreholes throughout Maine that were selected for their depth, location, and lithologies encountered. Depths range from about 300 feet to 2,200 feet. Most of the boreholes selected for measurement were completed in granite because this lithology can be assumed to be nearly homogeneous over the depth of the borehole. Boreholes were also selected to address gaps in existing geothermal datasets. Temperature profiles were collected in October and November, 2012.

  3. An optical fiber expendable seawater temperature/depth profile sensor

    NASA Astrophysics Data System (ADS)

    Zhao, Qiang; Chen, Shizhe; Zhang, Keke; Yan, Xingkui; Yang, Xianglong; Bai, Xuejiao; Liu, Shixuan

    2017-10-01

    Marine expendable temperature/depth profiler (XBT) is a disposable measuring instrument which can obtain temperature/depth profile data quickly in large area waters and mainly used for marine surveys, scientific research, military application. The temperature measuring device is a thermistor in the conventional XBT probe (CXBT)and the depth data is only a calculated value by speed and time depth calculation formula which is not an accurate measurement result. Firstly, an optical fiber expendable temperature/depth sensor based on the FBG-LPG cascaded structure is proposed to solve the problems of the CXBT, namely the use of LPG and FBG were used to detect the water temperature and depth, respectively. Secondly, the fiber end reflective mirror is used to simplify optical cascade structure and optimize the system performance. Finally, the optical path is designed and optimized using the reflective optical fiber end mirror. The experimental results show that the sensitivity of temperature and depth sensing based on FBG-LPG cascade structure is about 0.0030C and 0.1%F.S. respectively, which can meet the requirements of the sea water temperature/depth observation. The reflectivity of reflection mirror is in the range from 48.8% to 72.5%, the resonant peak of FBG and LPG are reasonable and the whole spectrum are suitable for demodulation. Through research on the optical fiber XBT (FXBT), the direct measurement of deep-sea temperature/depth profile data can be obtained simultaneously, quickly and accurately. The FXBT is a new all-optical seawater temperature/depth sensor, which has important academic value and broad application prospect and is expected to replace the CXBT in the future.

  4. Estimating the Soil Temperature Profile from a Single Depth Observation: A Simple Empirical Heatflow Solution

    NASA Technical Reports Server (NTRS)

    Holmes, Thomas; Owe, Manfred; deJeu, Richard

    2007-01-01

    Two data sets of experimental field observations with a range of meteorological conditions are used to investigate the possibility of modeling near-surface soil temperature profiles in a bare soil. It is shown that commonly used heat flow methods that assume a constant ground heat flux can not be used to model the extreme variations in temperature that occur near the surface. This paper proposes a simple approach for modeling the surface soil temperature profiles from a single depth observation. This approach consists of two parts: 1) modeling an instantaneous ground flux profile based on net radiation and the ground heat flux at 5cm depth; 2) using this ground heat flux profile to extrapolate a single temperature observation to a continuous near surface temperature profile. The new model is validated with an independent data set from a different soil and under a range of meteorological conditions.

  5. GIS Well Temperature Data from the Roosevelt Hot Springs, Utah FORGE Site

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Gwynn, Mark; Hill, Jay; Allis, Rick

    This is a GIS point feature shapefile representing wells, and their temperatures, that are located in the general Utah FORGE area near Milford, Utah. There are also fields that represent interpolated temperature values at depths of 200 m, 1000 m, 2000 m, 3000 m, and 4000 m. in degrees Fahrenheit. The temperature values at specific depths as mentioned above were derived as follows. In cases where the well reached a given depth (200 m and 1, 2, 3, or 4 km), the temperature is the measured temperature. For the shallower wells (and at deeper depths in the wells reaching onemore » or more of the target depths), temperatures were extrapolated from the temperature-depth profiles that appeared to have stable (re-equilibrated after drilling) and linear profiles within the conductive regime (i.e. below the water table or other convective influences such as shallow hydrothermal outflow from the Roosevelt Hydrothermal System). Measured temperatures/gradients from deeper wells (when available and reasonably close to a given well) were used to help constrain the extrapolation to greater depths. Most of the field names in the attribute table are intuitive, however HF = heat flow, intercept = the temperature at the surface (x-axis of the temperature-depth plots) based on the linear segment of the plot that was used to extrapolate the temperature profiles to greater depths, and depth_m is the total well depth. This information is also present in the shapefile metadata.« less

  6. Boron depth profiles and residual damage following rapid thermal annealing of low-temperature BSi molecular ion implantation in silicon

    NASA Astrophysics Data System (ADS)

    Liang, J. H.; Wang, S. C.

    2007-08-01

    The influence of substrate temperature on both the implantation and post-annealing characteristics of molecular-ion-implanted 5 × 1014 cm-2 77 keV BSi in silicon was investigated in terms of boron depth profiles and damage microstructures. The substrate temperatures under investigation consisted of room temperature (RT) and liquid nitrogen temperature (LT). Post-annealing treatments were performed using rapid thermal annealing (RTA) at 1050 °C for 25 s. Boron depth profiles and damage microstructures in both the as-implanted and as-annealed specimens were determined using secondary ion mass spectrometry (SIMS) and transmission electron microscopy (TEM), respectively. The as-implanted results revealed that, compared to the RT specimen, the LT specimen yields a shallower boron depth profile with a reduced tail into the bulk. An amorphous layer containing a smooth amorphous-to-crystalline (a/c) interface is evident in the LT specimen while just the opposite is true in the as-implanted RT one. The as-annealed results illustrated that the extension of the boron depth profile into the bulk via transient-enhanced diffusion (TED) in the LT specimen is less than it is in the RT one. Only residual defects are visible in the LT specimen while two clear bands of dislocation loops appear in the RT one.

  7. Stream bed temperature profiles as indicators of percolation characteristics beneath arroyos in the middle Rio Grande Basin, USA

    USGS Publications Warehouse

    Constantz, J.; Thomas, C.L.

    1997-01-01

    Stream bed temperature profiles were monitored continuously during water year 1990 and 1991 (WY90 and 91) in two New Mexico arroyos, similar in their meteorological features and dissimilar in their hydrological features. Stream bed temperature profiles between depths of 30 and 300 cm were examined to determine whether temporal changes in temperature profiles represent accurate indicators of the timing, depth and duration of percolation in each stream bed. These results were compared with stream flow, air temperature, and precipitation records for WY90 and 91, to evaluate the effect of changing surface conditions on temperature profiles. Temperature profiles indicate a persistently high thermal gradient with depth beneath Grantline Arroyo, except during a semi-annual thermal reversal in spring and autumn. This typifies the thermal response of dry sediments with low thermal conductivities. High thermal gradients were disrupted only during infrequent stream flows, followed by rapid re-establishment of high gradients. The stream bed temperature at 300 cm was unresponsive to individual precipitation or stream flow during WY90 and 91. This thermal pattern provides strong evidence that most seepage into Grantline Arroyo failed to percolate at a sufficient rate to reach 300 cm before being returned to the atmosphere. A distinctly different thermal pattern was recorded beneath Tijeras Arroyo. Low thermal gradients between 30 and 300 cm and large diurnal variations in temperature, suggest that stream flow created continuous, advection-dominated heat transport for over 300 days, annually. Beneath Tijeras Arroyo, low thermal gradients were interrupted only briefly during periodic, dry summer conditions. Comparisons of stream flow records for WY90 and 91 with stream bed temperature profiles indicate that independent analysis of thermal patterns provides accurate estimates of the timing, depth and duration of percolation beneath both arroyos. Stream flow loss estimates indicate that seepage rates were 15 times greater for Tijeras Arroyo than for Grantline Arroyo, which supports qualitative conclusions derived from analysis of stream bed temperature responses to surface conditions. ?? 1997 John Wiley & Sons, Ltd.

  8. A search for thermal excursions from ancient extraterrestrial impacts using Hadean zircon Ti-U-Th-Pb depth profiles.

    PubMed

    Abbott, Sunshine S; Harrison, T Mark; Schmitt, Axel K; Mojzsis, Stephen J

    2012-08-21

    Few terrestrial localities preserve more than a trace lithic record prior to ca. 3.8 Ga greatly limiting our understanding of the first 700 Ma of Earth history, a period inferred to have included a spike in the bolide flux to the inner solar system at ca. 3.85-3.95 Ga (the Late Heavy Bombardment, LHB). An accessible record of this era may be found in Hadean detrital zircons from the Jack Hills, Western Australia, in the form of μm-scale epitaxial overgrowths. By comparing crystallization temperatures of pre-3.8 Ga zircon overgrowths to the archive of zircon temperature spectra, it should, in principle, be possible to identify a distinctive impact signature. We have developed Ti-U-Th-Pb ion microprobe depth profiling to obtain age and temperature information within these zircon overgrowths and undertaken a feasibility study of its possible use in identifying impact events. Of eight grains profiled in this fashion, four have overgrowths of LHB-era age. Age vs. temperature profiles reveal a period between ca. 3.85-3.95 Ga (i.e., LHB era) characterized by significantly higher temperatures (approximately 840-875 °C) than do older or younger zircons or zircon domains (approximately 630-750 °C). However, temperatures approaching 900 °C can result in Pb isotopic exchange rendering interpretation of these profiles nonunique. Coupled age-temperature depth profiling shows promise in this role, and the preliminary data we report could represent the first terrestrial evidence for impact-related heating during the LHB.

  9. Reconstruction of radial thermal conductivity depth profile in case hardened steel rods

    NASA Astrophysics Data System (ADS)

    Celorrio, Ricardo; Mendioroz, Arantza; Apiñaniz, Estibaliz; Salazar, Agustín; Wang, Chinhua; Mandelis, Andreas

    2009-04-01

    In this work the surface thermal-wave field (ac temperature) of a solid cylinder illuminated by a modulated light beam is calculated first in two cases: a multilayered cylinder and a cylinder the radial thermal conductivity of which varies continuously. It is demonstrated numerically that, using a few layers of different thicknesses, the surface thermal-wave field of a cylindrical sample with continuously varying radial thermal conductivity can be calculated with high accuracy. Next, an inverse procedure based on the multilayered model is used to reconstruct the radial thermal conductivity profile of hardened C1018 steel rods, the surface temperature of which was measured by photothermal radiometry. The reconstructed thermal conductivity depth profile has a similar shape to those found for flat samples of this material and shows a qualitative anticorrelation with the hardness depth profile.

  10. Analyzed DTS Data, Guelph, ON Canada

    DOE Data Explorer

    Coleman, Thomas

    2015-07-01

    Analyzed DTS datasets from active heat injection experiments in Guelph, ON Canada is included. A .pdf file of images including borehole temperature distributions, temperature difference distributions, temperature profiles, and flow interpretations is included as the primary analyzed dataset. Analyzed data used to create the .pdf images are included as a matlab data file that contains the following 5 types of data: 1) Borehole Temperature (matrix of temperature data collected in the borehole), 2) Borehole Temperature Difference (matrix of temperature difference above ambient for each test), 3) Borehole Time (time in both min and sec since the start of a DTS test), 4) Borehole Depth (channel depth locations for the DTS measurements), 5) Temperature Profiles (ambient, active, active off early time, active off late time, and injection).

  11. The electrical conductivity of the Earth's upper mantle as estimated from satellite measured magnetic field variations. Ph.D. Thesis

    NASA Technical Reports Server (NTRS)

    Didwall, E. M.

    1981-01-01

    Low latitude magnetic field variations (magnetic storms) caused by large fluctuations in the equatorial ring current were derived from magnetic field magnitude data obtained by OGO 2, 4, and 6 satellites over an almost 5 year period. Analysis procedures consisted of (1) separating the disturbance field into internal and external parts relative to the surface of the Earth; (2) estimating the response function which related to the internally generated magnetic field variations to the external variations due to the ring current; and (3) interpreting the estimated response function using theoretical response functions for known conductivity profiles. Special consideration is given to possible ocean effects. A temperature profile is proposed using conductivity temperature data for single crystal olivine. The resulting temperature profile is reasonable for depths below 150-200 km, but is too high for shallower depths. Apparently, conductivity is not controlled solely by olivine at shallow depths.

  12. Objective fitting of hemoglobin dynamics in traumatic bruises based on temperature depth profiling

    NASA Astrophysics Data System (ADS)

    Vidovič, Luka; Milanič, Matija; Majaron, Boris

    2014-02-01

    Pulsed photothermal radiometry (PPTR) allows noninvasive measurement of laser-induced temperature depth profiles. The obtained profiles provide information on depth distribution of absorbing chromophores, such as melanin and hemoglobin. We apply this technique to objectively characterize mass diffusion and decomposition rate of extravasated hemoglobin during the bruise healing process. In present study, we introduce objective fitting of PPTR data obtained over the course of the bruise healing process. By applying Monte Carlo simulation of laser energy deposition and simulation of the corresponding PPTR signal, quantitative analysis of underlying bruise healing processes is possible. Introduction of objective fitting enables an objective comparison between the simulated and experimental PPTR signals. In this manner, we avoid reconstruction of laser-induced depth profiles and thus inherent loss of information in the process. This approach enables us to determine the value of hemoglobin mass diffusivity, which is controversial in existing literature. Such information will be a valuable addition to existing bruise age determination techniques.

  13. Milford, Utah FORGE Temperature Contours at 200 m

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Joe Moore

    The individual shapefiles in this dataset delineate estimated temperature contours (20, 40, 60, and 80) at a depth of 200 m in the Milford, Utah FORGE area. Contours were derived from 86 geothermal, gradient, and other wells drilled in the area since the mid-1970s with depths greater than 50 m. Conductive temperature profiles for wells less than 200 m were extrapolated to determine the temperature at the desired depth. Because 11 wells in the eastern section of the study area (in and around the Mineral Mountains) are at higher elevations compared to those closer to the center of the basin,more » temperature profiles were extrapolated to a constant elevation of 200 m below the 1830 m (6000 ft) a.s.l. datum (approximate elevation of alluvial fans at the base of the Mineral Mountains) to smooth the contours across the ridges and valleys.« less

  14. A search for thermal excursions from ancient extraterrestrial impacts using Hadean zircon Ti-U-Th-Pb depth profiles

    PubMed Central

    Abbott, Sunshine S.; Harrison, T. Mark; Schmitt, Axel K.; Mojzsis, Stephen J.

    2012-01-01

    Few terrestrial localities preserve more than a trace lithic record prior to ca. 3.8 Ga greatly limiting our understanding of the first 700 Ma of Earth history, a period inferred to have included a spike in the bolide flux to the inner solar system at ca. 3.85–3.95 Ga (the Late Heavy Bombardment, LHB). An accessible record of this era may be found in Hadean detrital zircons from the Jack Hills, Western Australia, in the form of μm-scale epitaxial overgrowths. By comparing crystallization temperatures of pre-3.8 Ga zircon overgrowths to the archive of zircon temperature spectra, it should, in principle, be possible to identify a distinctive impact signature. We have developed Ti-U-Th-Pb ion microprobe depth profiling to obtain age and temperature information within these zircon overgrowths and undertaken a feasibility study of its possible use in identifying impact events. Of eight grains profiled in this fashion, four have overgrowths of LHB-era age. Age vs. temperature profiles reveal a period between ca. 3.85–3.95 Ga (i.e., LHB era) characterized by significantly higher temperatures (approximately 840–875 °C) than do older or younger zircons or zircon domains (approximately 630–750 °C). However, temperatures approaching 900 °C can result in Pb isotopic exchange rendering interpretation of these profiles nonunique. Coupled age-temperature depth profiling shows promise in this role, and the preliminary data we report could represent the first terrestrial evidence for impact-related heating during the LHB. PMID:22869711

  15. Dissolved oxygen stratification and response to thermal structure and long-term climate change in a large and deep subtropical reservoir (Lake Qiandaohu, China).

    PubMed

    Zhang, Yunlin; Wu, Zhixu; Liu, Mingliang; He, Jianbo; Shi, Kun; Zhou, Yongqiang; Wang, Mingzhu; Liu, Xiaohan

    2015-05-15

    From January 2010 to March 2014, detailed depth profiles of water temperature, dissolved oxygen (DO), and chromophoric dissolved organic matter (CDOM) were collected at three sites in Lake Qiandaohu, a large, deep subtropical reservoir in China. Additionally, we assessed the changes in DO stratification over the past 61 years (1953-2013) based on our empirical models and long-term air temperature and transparency data. The DO concentration never fell below 2 mg/L, the critical value for anoxia, and the DO depth profiles were closely linked to the water temperature depth profiles. In the stable stratification period in summer and autumn, the significant increase in CDOM in the metalimnion explained the decrease in DO due to the oxygen consumed by CDOM. Well-developed oxygen stratification was detected at the three sites in spring, summer and autumn and was associated with thermal stratification. Oxycline depth was significantly negatively correlated with daily air temperature and thermocline thickness but significantly positively correlated with thermocline depth during the stratification weakness period (July-February). However, there were no significant correlations among these parameters during the stratification formation period (March-June). The increase of 1.67 °C in yearly average daily air temperature between 1980 and 2013 and the decrease of 0.78 m in Secchi disk depth caused a decrease of 1.65 m and 2.78 m in oxycline depth, respectively, facilitating oxygen stratification and decreasing water quality. Therefore, climate warming has had a substantial effect on water quality through changing the DO regime in Lake Qiandaohu. Copyright © 2015 Elsevier Ltd. All rights reserved.

  16. Temperature and electrical conductivity of the lunar interior from magnetic transient measurements in the geomagnetic tail

    NASA Technical Reports Server (NTRS)

    Dyal, P.; Parkin, C. W.; Daily, W. D.

    1974-01-01

    Magnetometers were deployed at four Apollo sites on the moon to measure remanent and induced lunar magnetic fields. Measurements from this network of instruments were used to calculate the electrical conductivity, temperature, magnetic permeability, and iron abundance of the lunar interior. Global lunar fields due to eddy currents, induced in the lunar interior by magnetic transients in the geomagnetic tail field, were analyzed to calculate an electrical conductivity profile for the moon: the conductivity increases rapidly with depth from 10 to the minus 9 power mhos/meter at the lunar surface to .0001 mhos/meter at 200 km depth, then less rapidly to .02 mhos/meter at 1000 km depth. A temperature profile is calculated from conductivity: temperature rises rapidly with depth to 1100 K at 200 km depth, then less rapidly to 1800 K at 1000 km depth. Velocities and thicknesses of the earth's magnetopause and bow shock are estimated from simultaneous magnetometer measurements. Average speeds are determined to be about 50 km/sec for the magnetopause and 70 km/sec for the bow shock, although there are large variations in the measurements for any particular boundary crossing.

  17. Magnetic Nonuniformity and Thermal Hysteresis of Magnetism in a Manganite Thin Film [Depth profiling of magnetization and coupling of strain with magnetization in (La 0.4Pr 0.6) 0.67Ca 0.33MnO 3 films

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Singh, Surendra; Fitzsimmons, M. R.; Lookman, T.

    We measured the chemical and magnetic depth profiles of a single crystalline film grown on a NdGaO 3 substrate using x-ray reflectometry, electron microscopy, electron energy-loss spectroscopy and polarized neutron reflectometry. Our data indicate that the film exhibits coexistence of different magnetic phases as a function of depth. The magnetic depth profile is correlated with a variation of chemical composition with depth. The thermal hysteresis of ferromagnetic order in the film suggests a first order ferromagnetic transition at low temperatures

  18. On the temperature dependence of Na migration in thin SiO 2 films during ToF-SIMS O 2+ depth profiling

    NASA Astrophysics Data System (ADS)

    Krivec, Stefan; Detzel, Thomas; Buchmayr, Michael; Hutter, Herbert

    2010-10-01

    The detection of Na in insulating samples by means of time of flight-secondary ion mass spectrometry (ToF-SIMS) depth profiling has always been a challenge. In particular the use of O 2+ as sputter species causes a severe artifact in the Na depth distribution due to Na migration under the influence of an internal electrical filed. In this paper we address the influence of the sample temperature on this artifact. It is shown that the transport of Na is a dynamic process in concordance with the proceeding sputter front. Low temperatures mitigated the migration process by reducing the Na mobility in the target. In the course of this work two sample types have been investigated: (i) A Na doped PMMA layer, deposited on a thin SiO 2 film. Here, the incorporation behavior of Na into SiO 2 during depth profiling is demonstrated. (ii) Na implanted into a thin SiO 2 film. By this sample type the migration behavior could be examined when defects, originating from the implantation process, are present in the SiO 2 target. In addition, we propose an approach for the evaluation of an implanted Na profile, which is unaffected by the migration process.

  19. Fort Bliss Geothermal Area Data: Temperature profile, logs, schematic model and cross section

    DOE Data Explorer

    Adam Brandt

    2015-11-15

    This dataset contains a variety of data about the Fort Bliss geothermal area, part of the southern portion of the Tularosa Basin, New Mexico. The dataset contains schematic models for the McGregor Geothermal System, a shallow temperature survey of the Fort Bliss geothermal area. The dataset also contains Century OH logs, a full temperature profile, and complete logs from well RMI 56-5, including resistivity and porosity data, drill logs with drill rate, depth, lithology, mineralogy, fractures, temperature, pit total, gases, and descriptions among other measurements as well as CDL, CNL, DIL, GR Caliper and Temperature files. A shallow (2 meter depth) temperature survey of the Fort Bliss geothermal area with 63 data points is also included. Two cross sections through the Fort Bliss area, also included, show well position and depth. The surface map included shows faults and well spatial distribution. Inferred and observed fault distributions from gravity surveys around the Fort Bliss geothermal area.

  20. Pulsed photothermal depth profiling of tattoos undergoing laser removal treatment

    NASA Astrophysics Data System (ADS)

    Milanic, Matija; Majaron, Boris

    2012-02-01

    Pulsed photothermal radiometry (PPTR) allows noninvasive determination of temperature depth profiles induced by pulsed laser irradiation of strongly scattering biological tissues and organs, including human skin. In present study, we evaluate the potential of this technique for investigational characterization and possibly quantitative evaluation of laser tattoo removal. The study involved 5 healthy volunteers (3 males, 2 females), age 20-30 years, undergoing tattoo removal treatment using a Q-switched Nd:YAG laser. There were four measurement and treatment sessions in total, separated by 2-3 months. Prior to each treatment, PPTR measurements were performed on several tattoo sites and one nearby healthy site in each patient, using a 5 ms Nd:YAG laser at low radiant exposure values and a dedicated radiometric setup. The laser-induced temperature profiles were then reconstructed by applying a custom numerical code. In addition, each tatoo site was documented with a digital camera and measured with a custom colorimetric system (in tristimulus color space), providing an objective evaluation of the therapeutic efficacy to be correlated with our PPTR results. The results show that the laser-induced temperature profile in untreated tattoos is invariably located at a subsurface depth of 300 μm. In tattoo sites that responded well to laser therapy, a significant drop of the temperature peak was observed in the profiles obtained from PPTR record. In several sites that appeared less responsive, as evidenced by colorimetric data, a progressive shift of the temperature profile deeper into the dermis was observed over the course of consecutive laser treatments, indicating that the laser tattoo removal was efficient.

  1. Changes in dive profiles as an indicator of feeding success in king and Adélie penguins

    NASA Astrophysics Data System (ADS)

    Bost, C. A.; Handrich, Y.; Butler, P. J.; Fahlman, A.; Halsey, L. G.; Woakes, A. J.; Ropert-Coudert, Y.

    2007-02-01

    Determining when and how deep avian divers feed remains a challenge despite technical advances. Systems that record oesophageal temperature are able to determine rate of prey ingestion with a high level of accuracy but technical problems still remain to be solved. Here we examine the validity of using changes in depth profiles to infer feeding activity in free-ranging penguins, as more accessible proxies of their feeding success. We used oesophageal temperature loggers with fast temperature sensors, deployed in tandem with time-depth recorders, on king and Adélie penguins. In the king penguin, a high correspondence was found between the number of ingestions recorded per dive and the number of wiggles during the bottom and the ascent part of the dives. In the Adélie penguins, which feed on smaller prey, the number of large temperature drops was linearly related to the number of undulations per dive. The analysis of change in depth profiles from high-resolution time-depth recorders can provide key information to enhance the study of feeding rate and foraging success of these predators. Such potential is especially relevant in the context of using Southern marine top predators to study change in availability of marine resources.

  2. Influence of Annealing on the Depth Microstructure of the Shot Peened Duplex Stainless Steel at Elevated Temperature

    NASA Astrophysics Data System (ADS)

    Feng, Qiang; She, Jia; Xiang, Yong; Wu, Xianyun; Wang, Chengxi; Jiang, Chuanhai

    The depth profiles of residual stresses and lattice parameters in the surface layers of shot peened duplex stainless steel at elevated temperature were investigated utilizing X-ray diffraction analysis. At each deformation depth, residual stress distributions in both ferrite and austenite were studied by X-ray diffraction stress analysis which is performed on the basis of the sin2ψ method and the lattice parameters were explored by Rietveld method. The results reveal that difference changes of depth residual compressive stress profiles between ferrite and austenite under the same annealing condition are resulted from the diverse coefficient of thermal expansion, dislocation density, etc. for different phases in duplex stainless steel. The relaxations of depth residual stresses in austenite are more obvious than those in ferrite. The lattice parameters decrease in the surface layer with the extending of annealing time, however, they increase along the depth after annealing for 16min. The change of the depth lattice parameters can be ascribed to both thermal expansion and the relaxation of residual stress. The different changes of microstructure at elevated temperature between ferrite and austenite are discussed.

  3. Characterization of drug-eluting stent (DES) materials with cluster secondary ion mass spectrometry (SIMS)

    NASA Astrophysics Data System (ADS)

    Mahoney, Christine M.; Patwardhan, Dinesh V.; Ken McDermott, M.

    2006-07-01

    Secondary ion mass spectrometry (SIMS) employing an SF 5+ polyatomic primary ion source was utilized to analyze several materials commonly used in drug-eluting stents (DES). Poly(ethylene- co-vinyl acetate) (PEVA), poly(lactic- co-glycolic acid) (PLGA) and various poly(urethanes) were successfully depth profiled using SF 5+ bombardment. The resultant molecular depth profiles obtained from these polymeric films showed very little degradation in molecular signal as a function of increasing SF 5+ primary ion dose when experiments were performed at low temperatures (signal was maintained for doses up to ˜5 × 10 15 ions/cm 2). Temperature was determined to be an important parameter in both the success of the depth profiles and the mass spectral analysis of the polymers. In addition to the pristine polymer films, paclitaxel (drug released in Taxus™ stent) containing PLGA films were also characterized, where it was confirmed that both drug and polymer signals could be monitored as a function of depth at lower paclitaxel concentrations (10 wt%).

  4. Tracking the Subsurface Signal of Decadal Climate Warming to Quantify Vertical Groundwater Flow Rates

    NASA Astrophysics Data System (ADS)

    Bense, V. F.; Kurylyk, B. L.

    2017-12-01

    Sustained ground surface warming on a decadal time scale leads to an inversion of thermal gradients in the upper tens of meters. The magnitude and direction of vertical groundwater flow should influence the propagation of this warming signal, but direct field observations of this phenomenon are rare. Comparison of temperature-depth profiles in boreholes in the Veluwe area, Netherlands, collected in 1978-1982 and 2016 provided such direct measurement. We used these repeated profiles to track the downward propagation rate of the depth at which the thermal gradient is zero. Numerical modeling of the migration of this thermal gradient "inflection point" yielded estimates of downward groundwater flow rates (0-0.24 m a-1) that generally concurred with known hydrogeological conditions in the area. We conclude that analysis of inflection point depths in temperature-depth profiles impacted by surface warming provides a largely untapped opportunity to inform sustainable groundwater management plans that rely on accurate estimates of long-term vertical groundwater fluxes.

  5. Correlation of corneal thickness, endothelial cell density and anterior chamber depth with ocular surface temperature in normal subjects.

    PubMed

    Pattmöller, Johanna; Wang, Jiong; Zemova, Elena; Seitz, Berthold; Eppig, Timo; Langenbucher, Achim; Szentmáry, Nóra

    2015-09-01

    To analyze corneal surface temperature profile in a young and healthy study population and to determine the impact of corneal thickness (CT), anterior chamber depth (ACD), and endothelial cell density (ECD) on surface temperature. In this prospective, single-center study 61 healthy right eyes of 61 subjects without tear film pathologies (mean age 24.9 ± 6.7 years) were recruited. Ocular surface temperature (OST) was measured with the Ocular Surface Thermographer TG-1000. From Pentacam HR CT and ACD, and from specular microscopy ECD and central corneal thickness (CCT) were acquired. From the raw measurement data (OST, CT and ACD) we extracted a) local OST the corneal center and 3mm away from the center at the 3, 6, and 9 o'clock positions, and b) Zernike parameters Z1, Z2 and Z3 to evaluate the general temperature profile within a 6mm circular area around the center. Overall, there was no correlation between OST and CT, ACD or ECD. Local OST did not correlate with CT at any measurement position. On average local OST was highest at measurement positions where CT was lowest, but without reaching statistical significance. Baseline OST was highest at thin corneal regions and temperature decay over time was smallest in those regions. Z1, Z2 and Z3 correlated well with CT. In healthy subjects corneal thickness, endothelial cell density and anterior chamber depth have no effect on corneal surface temperature. The general temperature profile seems to be influenced by the corneal thickness profile effecting a higher temperature and lower decay at thinner corneal regions. Copyright © 2014. Published by Elsevier GmbH.

  6. Characterization of Hydrologic and Thermal Properties at Brady Geothermal Field, NV

    NASA Astrophysics Data System (ADS)

    Patterson, J.; Cardiff, M. A.; Lim, D.; Coleman, T.; Wang, H. F.; Feigl, K. L.

    2017-12-01

    Understanding and predicting the temperature evolution of geothermal reservoirs is a primary focus for geothermal power plant operators ensuring continued financial sustainability of the resource. Characterization of reservoir properties - such as thermal diffusivity and hydraulic conductivity - facilitates modeling efforts to develop a better understanding of temperature evolution. As part of the integrated "PoroTomo" experiment, borehole pressure measurements were collected in three monitoring wells of various depths under varying operational conditions at the Brady Geothermal Field near Reno, NV. During normal operational conditions, a vertical profile of borehole temperature to 330 m depth was collected using distributed temperature sensing (DTS) for a period of 5 days. Borehole pressure data indicates 2D flow and shows rapid responses to changes in pumping /injection rates, likely indicating fault-dominated flow. The temperature data show that borehole temperature recovery following cold water slug injection is variable with depth. Late time vertical temperature profiles show the borehole following a shallow geotherm to a depth of approximately 275 meters, below which the temperature declines until a depth of approximately 320 meters, with a stable zone of cold water forming below this, possibly indicating production-related thermal drawdown. A validated heat transfer model is used in conjunction with the temperature data to determine depth-dependent reservoir thermal properties. Hydraulic reservoir properties are determined through inversion of the collected pressure data using MODFLOW. These estimated thermal and hydraulic properties are synthesized with existing structural and stratigraphic datasets at Brady. The work presented herein was funded in part by the Office of Energy Efficiency and Renewable Energy (EERE), U.S. Department of Energy, under Award Number DE-EE0006760.

  7. Auger compositional depth profiling of the metal contact-TlBr interface

    NASA Astrophysics Data System (ADS)

    Nelson, A. J.; Swanberg, E. L.; Voss, L. F.; Graff, R. T.; Conway, A. M.; Nikolic, R. J.; Payne, S. A.; Kim, H.; Cirignano, L.; Shah, K.

    2015-08-01

    Degradation of room temperature operation of TlBr radiation detectors with time is thought to be due to electromigration of Tl and Br vacancies within the crystal as well as the metal contacts migrating into the TlBr crystal itself due to electrochemical reactions at the metal/TlBr interface. Scanning Auger electron spectroscopy (AES) in combination with sputter depth profiling was used to investigate the metal contact surface/interfacial structure on TlBr devices. Device-grade TlBr was polished and subjected to a 32% HCl etch to remove surface damage and create a TlBr1-xClx surface layer prior to metal contact deposition. Auger compositional depth profiling results reveal non-equilibrium interfacial diffusion after device operation in both air and N2 at ambient temperature. These results improve our understanding of contact/device degradation versus operating environment for further enhancing radiation detector performance.

  8. Temperature and oxygen in Missouri reservoirs

    USGS Publications Warehouse

    Jones, John R.; Knowlton, Matthew F.; Obrecht, Daniel V.; Graham, Jennifer L.

    2011-01-01

    Vertical profiles of water temperature (n = 7193) and dissolved oxygen (n = 6516) were collected from 235 Missouri reservoirs during 1989–2007; most data were collected during May–August and provide a regional summary of summer conditions. Collectively, surface water temperature ranged from a mean of ~22 C in May to 28 C in July, and individual summer maxima typically were 28–32 C. Most (~95%) reservoirs stably stratify by mid-May, but few are deep enough to have hypolimnia with near-uniform temperatures. Among stratified reservoirs, maximum effective length and maximum depth accounted for 75% of the variation in mixed depth and thermocline depth. Ephemeral, near-surface thermoclines occurred in 39% of summer profiles and were most frequent in small, turbid reservoirs. Isotherms below the mixed layer deepen during stratification, and the water column is >20 C by August in all but the deepest reservoirs. Most reservoirs showed incipient dissolved oxygen (DO) depletion by mid-May, and by August, 80% of profiles had DO minima of 50% of variation in DO below the mixed layer during summer. Warm summer temperatures and widespread low DO often limit available fish habitat in Missouri reservoirs and compress warm-water fish communities into subsurface layers that exceed their thermal preferences. This study provides a regional baseline of reservoir temperature and oxygen conditions useful for future evaluations of eutrophication and the effects of a warming climate.

  9. Evidence of strong ocean heating during glacial periods

    NASA Astrophysics Data System (ADS)

    Zimov, S. A.; Zimov, N.

    2013-12-01

    Numerous hypotheses have addressed glacial-interglacial climatic dynamics, but none of them explain the sharp 25C temperature increase in Greenland in the last deglaciation (Cuffey et al. 1995; Dahl-Jensen et al. 1998). These robust data were obtained through analyzing the temperature profile in the Greenland ice sheet where cold from the last glaciation is preserved in the depth of the glacial sheet. We suggest that during glaciations the ocean accumulated energy: interior ocean water heated up to ~20-30C and during deglaciation this energy is released. In the analogy with reconstructing the ice sheet temperature profiles, the most reliable proof of ocean interior warming during the last glaciation is the heat flux profiles in the bottom sediments. In the final reports based on temperature measurements conducted during the DSDP (Deep Sea Drilling Project) it is stated that heat flux in the bottom sediments doesn't vary with depth and consequently there were no substantial temperature changes in the ocean interior during the last glacial cycle, and heat flux on the surface of the ocean bottom is the geothermal heat flux (Erickson et al., 1975, Hyndman et al., 1987). However, we have critically investigated data in all initial reports of all deep sea drilling projects and have noticed that all temperature data show that heat flow decreases strongly with depth (a minimum of 40 mW/m2), i.e. most of the heat flux detected on the surface of the ocean floor is not the geothermal heat flux but remaining heat that bottom sediments release. Sharp shifts in heat flow are seen within boreholes at depths crossing gas hydrate bottom. All this means that during the last glacial period interior water temperature was on 25-30C degrees warmer. Conversely, in isolated seas heat flow in the sediments shows little change with depth.

  10. Climate reconstruction from borehole temperatures influenced by groundwater flow

    NASA Astrophysics Data System (ADS)

    Kurylyk, B.; Irvine, D. J.; Tang, W.; Carey, S. K.; Ferguson, G. A. G.; Beltrami, H.; Bense, V.; McKenzie, J. M.; Taniguchi, M.

    2017-12-01

    Borehole climatology offers advantages over other climate reconstruction methods because further calibration steps are not required and heat is a ubiquitous subsurface property that can be measured from terrestrial boreholes. The basic theory underlying borehole climatology is that past surface air temperature signals are reflected in the ground surface temperature history and archived in subsurface temperature-depth profiles. High frequency surface temperature signals are attenuated in the shallow subsurface, whereas low frequency signals can be propagated to great depths. A limitation of analytical techniques to reconstruct climate signals from temperature profiles is that they generally require that heat flow be limited to conduction. Advection due to groundwater flow can thermally `contaminate' boreholes and result in temperature profiles being rejected for regional climate reconstructions. Although groundwater flow and climate change can result in contrasting or superimposed thermal disturbances, groundwater flow will not typically remove climate change signals in a subsurface thermal profile. Thus, climate reconstruction is still possible in the presence of groundwater flow if heat advection is accommodated in the conceptual and mathematical models. In this study, we derive a new analytical solution for reconstructing surface temperature history from borehole thermal profiles influenced by vertical groundwater flow. The boundary condition for the solution is composed of any number of sequential `ramps', i.e. periods with linear warming or cooling rates, during the instrumented and pre-observational periods. The boundary condition generation and analytical temperature modeling is conducted in a simple computer program. The method is applied to reconstruct climate in Winnipeg, Canada and Tokyo, Japan using temperature profiles recorded in hydrogeologically active environments. The results demonstrate that thermal disturbances due to groundwater flow and climate change must be considered in a holistic manner as opposed to isolating either perturbation as was done in prior analytical studies.

  11. In Vivo Simulator for Microwave Treatment

    NASA Technical Reports Server (NTRS)

    Arndt, G. Dickey (Inventor); Carl, James R. (Inventor); Raffoul, George W. (Inventor); Karasack, Vincent G. (Inventor); Pacifico, Antonio (Inventor); Pieper, Carl F. (Inventor)

    2001-01-01

    Method and apparatus are provided for propagating microwave energy into heart tissues to produce a desired temperature profile therein at tissue depths sufficient for thermally ablating arrhythmogenic cardiac tissue to treat ventricular tachycardia and other arrhythmias while preventing excessive heating of surrounding tissues, organs, and blood. A wide bandwidth double-disk antenna is effective for this purpose over a bandwidth of about 6 GHz. A computer simulation provides initial screening capabilities for an antenna such as antenna. frequency, power level, and power application duration. The simulation also allows optimization of techniques for specific patients or conditions. In operation, microwave energy between about 1 GHz and 12 GHz is applied to monopole microwave radiator having a surface wave limiter. A test setup provides physical testing of microwave radiators to determine the temperature profile created in actual heart tissue or ersatz heart tissue. Saline solution pumped over the heart tissue with a peristaltic pump simulates blood flow. Optical temperature sensors disposed at various tissue depths within the heart tissue detect the temperature profile without creating any electromagnetic interference. The method may be used to produce a desired temperature profile in other body tissues reachable by catheter such as tumors and the like.

  12. Transcatheter Antenna For Microwave Treatment

    NASA Technical Reports Server (NTRS)

    Arndt, G. Dickey (Inventor); Carl, James R. (Inventor); Raffoul, George W. (Inventor); Karasack, Vincent G. (Inventor); Pacifico, Antonio (Inventor); Pieper, Carl F. (Inventor)

    2000-01-01

    Method and apparatus are provided for propagating microwave energy into heart tissues to produce a desired temperature profile therein at tissue depths sufficient for thermally ablating arrhythmogenic cardiac tissue to treat ventricular tachycardia and other arrhythmias while preventing excessive heating of surrounding tissues, organs, and blood. A wide bandwidth double-disk antenna is effective for this purpose over a bandwidth of about six gigahertz. A computer simulation provides initial screening capabilities for an antenna such as antenna, frequency, power level, and power application duration. The simulation also allows optimization of techniques for specific patients or conditions. In operation, microwave energy between about 1 Gigahertz and 12 Gigahertz is applied to monopole microwave radiation having a surface wave limiter. A test setup provides physical testing of microwave radiators to determine the temperature profile created in actual heart tissue or ersatz heart tissue. Saline solution pumped over the heart tissue with a peristaltic pump simulates blood flow. Optical temperature sensors disposed at various tissue depths within the heart tissue detect the temperature profile without creating any electromagnetic interference. The method may he used to produce a desired temperature profile in other body tissues reachable by catheter such as tumors and the like.

  13. Microwave Treatment for Cardiac Arrhythmias

    NASA Technical Reports Server (NTRS)

    Arndt, G. Dickey (Inventor); Carl, James R. (Inventor); Raffoul, George W. (Inventor); Pacifico, Antonio (Inventor)

    1999-01-01

    Method and apparatus are provided for propagating microwave energy into heart tissues to produce a desired temperature profile therein at tissue depths sufficient for thermally ablating arrhythmogenic cardiac tissue to treat ventricular tachycardia and other arrhythmias while preventing excessive heating of surrounding tissues, organs, and blood. A wide bandwidth double-disk antenna is effective for this purpose over a bandwidth of about six gigahertz. A computer simulation provides initial screening capabilities for an antenna such as antenna, frequency, power level, and power application duration. The simulation also allows optimization of techniques for specific patients or conditions. In operation, microwave energy between about 1 Gigahertz and 12 Gigahertz is applied to monopole microwave radiator having a surface wave limiter. A test setup provides physical testing of microwave radiators to determine the temperature profile created in actual heart tissue or ersatz heart tissue. Saline solution pumped over the heart tissue with a peristaltic pump simulates blood flow. Optical temperature sensors disposed at various tissue depths within the heart tissue detect the temperature profile without creating any electromagnetic interference. The method may be used to produce a desired temperature profile in other body tissues reachable by catheter such as tumors and the like.

  14. Chemical characteristics of hadal waters in the Izu-Ogasawara Trench of the western Pacific Ocean.

    PubMed

    Gamo, Toshitaka; Shitashima, Kiminori

    2018-01-01

    Vertical profiles of potential temperature, salinity, and some chemical components were obtained at a trench station (29°05'N, 142°51'E; depth = 9768 m) in the Izu-Ogasawara (Bonin) Trench in 1984 and 1994 to characterize the hadal waters below ∼6000 m depth. We compared portions of both the 1984 and 1994 profiles with nearby data obtained between 1976 and 2013. Results demonstrated that the hadal waters had slightly higher potential temperature and nitrate and lower dissolved oxygen than waters at sill depths (∼6000 m) outside the trench, probably due to the effective accumulation of geothermal heat and active biological processes inside the trench. The silicate, iron, and manganese profiles in 1984 showed slight but significant increases below ∼6000 m depth, suggesting that these components may have been intermittently supplied from the trench bottom. Significant amounts of 222 Rn in excess over 226 Ra were detected in the hadal waters up to 2675 m from the bottom, reflecting laterally supplied 222 Rn from the trench walls.

  15. Atmospheric and surface temperatures and airborne dust amounts during late southern summer from Mariner 9 IRIS data

    NASA Technical Reports Server (NTRS)

    Santee, M.; Crisp, D.

    1992-01-01

    The temperature structure and dust loading of the Martian atmosphere are investigated using thermal emission spectra recorded in 1972 by the Mariner 9 infrared interferometer spectrometer (IRIS). The analysis focuses on a subset of data consisting of approximately 2400 spectra obtained near the end of the southern summer season (L(sub s) equal to 343 deg to 348 deg), after the global dust storm had largely abated and airborne dust amounts were subsiding to background values. Simultaneous retrieval of the vertical distribution of both atmospheric temperature and dust optical depth is accomplished through an iterative procedure which is performed on each individual spectrum. The atmospheric transmittances are calculated using a Voigt quasi-random band model, which includes absorption by CO2 and dust, but neglects the effects of multiple scattering. Vertical profiles of temperature and dust optical depth are obtained using modified algorithms. These profiles are used to construct global maps of temperature and dust optical depth as functions of latitude (+/- 90 deg), altitude (approximately 0-50 km), and local time of day.

  16. The thermal regime in the resurgent dome of Long Valley Caldera, California: Inferences from precision temperature logs in deep wells

    USGS Publications Warehouse

    Hurwitz, S.; Farrar, C.D.; Williams, C.F.

    2010-01-01

    Long Valley Caldera in eastern California formed 0.76Ma ago in a cataclysmic eruption that resulted in the deposition of 600km3 of Bishop Tuff. The total current heat flow from the caldera floor is estimated to be ~290MW, and a geothermal power plant in Casa Diablo on the flanks of the resurgent dome (RD) generates ~40MWe. The RD in the center of the caldera was uplifted by ~80cm between 1980 and 1999 and was explained by most models as a response to magma intrusion into the shallow crust. This unrest has led to extensive research on geothermal resources and volcanic hazards in the caldera. Here we present results from precise, high-resolution, temperature-depth profiles in five deep boreholes (327-1,158m) on the RD to assess its thermal state, and more specifically 1) to provide bounds on the advective heat transport as a guide for future geothermal exploration, 2) to provide constraints on the occurrence of magma at shallow crustal depths, and 3) to provide a baseline for future transient thermal phenomena in response to large earthquakes, volcanic activity, or geothermal production. The temperature profiles display substantial non-linearity within each profile and variability between the different profiles. All profiles display significant temperature reversals with depth and temperature gradients <50??C/km at their bottom. The maximum temperature in the individual boreholes ranges between 124.7??C and 129.5??C and bottom hole temperatures range between 99.4??C and 129.5??C. The high-temperature units in the three Fumarole Valley boreholes are at the approximate same elevation as the high-temperature unit in borehole M-1 in Casa Diablo indicating lateral or sub-lateral hydrothermal flow through the resurgent dome. Small differences in temperature between measurements in consecutive years in three of the wells suggest slow cooling of the shallow hydrothermal flow system. By matching theoretical curves to segments of the measured temperature profiles, we calculate horizontal groundwater velocities in the hydrothermal flow unit under the RD that range from 1.9 to 2.8m/yr, which corresponds to a maximum power flowing through the RD of 3-4MW. The relatively low temperatures and large isothermal segments at the bottom of the temperature profiles are inconsistent with the presence of magma at shallow crustal levels. ?? 2010.

  17. The thermal regime in the resurgent dome of Long Valley Caldera, California: Inferences from precision temperature logs in deep wells

    NASA Astrophysics Data System (ADS)

    Hurwitz, Shaul; Farrar, Christopher D.; Williams, Colin F.

    2010-12-01

    Long Valley Caldera in eastern California formed 0.76 Ma ago in a cataclysmic eruption that resulted in the deposition of 600 km 3 of Bishop Tuff. The total current heat flow from the caldera floor is estimated to be ~ 290 MW, and a geothermal power plant in Casa Diablo on the flanks of the resurgent dome (RD) generates ~40 MWe. The RD in the center of the caldera was uplifted by ~ 80 cm between 1980 and 1999 and was explained by most models as a response to magma intrusion into the shallow crust. This unrest has led to extensive research on geothermal resources and volcanic hazards in the caldera. Here we present results from precise, high-resolution, temperature-depth profiles in five deep boreholes (327-1,158 m) on the RD to assess its thermal state, and more specifically 1) to provide bounds on the advective heat transport as a guide for future geothermal exploration, 2) to provide constraints on the occurrence of magma at shallow crustal depths, and 3) to provide a baseline for future transient thermal phenomena in response to large earthquakes, volcanic activity, or geothermal production. The temperature profiles display substantial non-linearity within each profile and variability between the different profiles. All profiles display significant temperature reversals with depth and temperature gradients <50 °C/km at their bottom. The maximum temperature in the individual boreholes ranges between 124.7 °C and 129.5 °C and bottom hole temperatures range between 99.4 °C and 129.5 °C. The high-temperature units in the three Fumarole Valley boreholes are at the approximate same elevation as the high-temperature unit in borehole M-1 in Casa Diablo indicating lateral or sub-lateral hydrothermal flow through the resurgent dome. Small differences in temperature between measurements in consecutive years in three of the wells suggest slow cooling of the shallow hydrothermal flow system. By matching theoretical curves to segments of the measured temperature profiles, we calculate horizontal groundwater velocities in the hydrothermal flow unit under the RD that range from 1.9 to 2.8 m/yr, which corresponds to a maximum power flowing through the RD of 3-4 MW. The relatively low temperatures and large isothermal segments at the bottom of the temperature profiles are inconsistent with the presence of magma at shallow crustal levels.

  18. HCMM energy budget data as a model input for assessing regions of high potential groundwater pollution

    NASA Technical Reports Server (NTRS)

    Moore, D. G. (Principal Investigator); Heilman, J.; Tunheim, J. A.; Baumberger, V.

    1978-01-01

    The author has identified the following significant results. To investigate the general relationship between surface temperature and soil moisture profiles, a series of model calculations were carried out. Soil temperature profiles were calculated during a complete diurnal cycle for a variety of moisture profiles. Preliminary results indicate the surface temperature difference between two sites measured at about 1400 hours is related to the difference in soil moisture within the diurnal damping depth (about 50 cm). The model shows this temperature difference to vary considerably throughout the diurnal cycle.

  19. Depth to Curie temperature across the central Red Sea from magnetic data using the de-fractal method

    NASA Astrophysics Data System (ADS)

    Salem, Ahmed; Green, Chris; Ravat, Dhananjay; Singh, Kumar Hemant; East, Paul; Fairhead, J. Derek; Mogren, Saad; Biegert, Ed

    2014-06-01

    The central Red Sea rift is considered to be an embryonic ocean. It is characterised by high heat flow, with more than 90% of the heat flow measurements exceeding the world mean and high values extending to the coasts - providing good prospects for geothermal energy resources. In this study, we aim to map the depth to the Curie isotherm (580 °C) in the central Red Sea based on magnetic data. A modified spectral analysis technique, the “de-fractal spectral depth method” is developed and used to estimate the top and bottom boundaries of the magnetised layer. We use a mathematical relationship between the observed power spectrum due to fractal magnetisation and an equivalent random magnetisation power spectrum. The de-fractal approach removes the effect of fractal magnetisation from the observed power spectrum and estimates the parameters of depth to top and depth to bottom of the magnetised layer using iterative forward modelling of the power spectrum. We applied the de-fractal approach to 12 windows of magnetic data along a profile across the central Red Sea from onshore Sudan to onshore Saudi Arabia. The results indicate variable magnetic bottom depths ranging from 8.4 km in the rift axis to about 18.9 km in the marginal areas. Comparison of these depths with published Moho depths, based on seismic refraction constrained 3D inversion of gravity data, showed that the magnetic bottom in the rift area corresponds closely to the Moho, whereas in the margins it is considerably shallower than the Moho. Forward modelling of heat flow data suggests that depth to the Curie isotherm in the centre of the rift is also close to the Moho depth. Thus Curie isotherm depths estimated from magnetic data may well be imaging the depth to the Curie temperature along the whole profile. Geotherms constrained by the interpreted Curie isotherm depths have subsequently been calculated at three points across the rift - indicating the variation in the likely temperature profile with depth.

  20. Experimental Verification of Modeled Thermal Distribution Produced by a Piston Source in Physiotherapy Ultrasound

    PubMed Central

    Lopez-Haro, S. A.; Leija, L.

    2016-01-01

    Objectives. To present a quantitative comparison of thermal patterns produced by the piston-in-a-baffle approach with those generated by a physiotherapy ultrasonic device and to show the dependency among thermal patterns and acoustic intensity distributions. Methods. The finite element (FE) method was used to model an ideal acoustic field and the produced thermal pattern to be compared with the experimental acoustic and temperature distributions produced by a real ultrasonic applicator. A thermal model using the measured acoustic profile as input is also presented for comparison. Temperature measurements were carried out with thermocouples inserted in muscle phantom. The insertion place of thermocouples was monitored with ultrasound imaging. Results. Modeled and measured thermal profiles were compared within the first 10 cm of depth. The ideal acoustic field did not adequately represent the measured field having different temperature profiles (errors 10% to 20%). Experimental field was concentrated near the transducer producing a region with higher temperatures, while the modeled ideal temperature was linearly distributed along the depth. The error was reduced to 7% when introducing the measured acoustic field as the input variable in the FE temperature modeling. Conclusions. Temperature distributions are strongly related to the acoustic field distributions. PMID:27999801

  1. Temperature measurements at IODP 337 Expedition, off Shimokita, NE Japan.

    NASA Astrophysics Data System (ADS)

    Yamada, Y.; Sanada, Y.; Moe, K.; Kubo, Y.; Inagaki, F.

    2014-12-01

    Precise estimation of underground temperature is a challenging issue, since direct measurements require drill holes that disturb the original underground environment. During IODP 337 expedition, we have obtained in-situ temperature datasets for several times by using geophysical logging tools. A common procedure to estimate the undisturbed maximum underground temperature is by approximating that the 'build-up' pattern of measured values in the borehole should reach to the equilibrium temperature. At the Shimokita site, this was 63.7 oC at a depth of 2466 m. We have much more measurement dataset and all of these were used to analyze detailed in-site temperatures at various depths. The result shows a non-linear temperature profile to the depth and this may be reflected by the thermal properties of the surrounding rocks.

  2. A Non-Steady-State Condition in Sediments at the Gashydrate Stability Boundary off West Spitsbergen: Evidence for Gashydrate Dissociation or Just Dynamic Methane Transport?

    NASA Astrophysics Data System (ADS)

    Treude, T.; Krause, S.; Bertics, V. J.; Steinle, L.; Niemann, H.; Liebetrau, V.; Feseker, T.; Burwicz, E.; Krastel, S.; Berndt, C.

    2014-12-01

    In 2008, a large area with several hundred methane plumes was discovered along the West Spitsbergen continental margin at water depths between 150 and 400 m (Westbrook et al. 2009, GRL 36, doi:10.1029/2009GL039191). Many of the observed plumes were located at the boundary of gas hydrate stability (~400 m water depth). It was speculated that the methane escape at this depth was correlated with gas hydrate destabilization caused by recent increases in water temperatures recorded in this region. In a later study, geochemical analyses of authigenic carbonates and modeling of heat flow data combined with seasonal changes in water temperature demonstrated that the methane seeps were active already prior to industrial warming but that the gas hydrate system nevertheless reacts very sensitive to even seasonal temperature changes (Berndt et al. 2014, Science 343: 284-287). Here, we report about a methane seep site at the gas hydrate stability boundary (394 m water depth) that features unusual geochemical profiles indicative for non-steady state conditions. Sediment was recovered with a gravity corer (core length 210 cm) and samples were analyzed to study porewater geochemistry, methane concentration, authigenic carbonates, and microbial activity. Porewater profiles revealed two zones of sulfate-methane transition at 50 and 200 cm sediment depth. The twin zones were confirmed by a double peaking in sulfide, total alkalinity, anaerobic oxidation of methane, and sulfate reduction. δ18O values sharply increased from around -2.8 ‰ between 0 and 126 cm to -1.2 ‰ below 126 cm sediment depth. While U/Th isotope measurements of authigenic seep carbonates that were collected from different depths of the core illustrated that methane seepage must be occurring at this site since at least 3000 years, the biogeochemical profiles suggest that methane flux must have been altered recently. By applying a multi-phase reaction-transport model using known initial parameters from the study site (e.g. water depth, temperature profile, salinity, and sediment surface concentrations of CH4, SO4, DIC, and POC) were able to show that the observed twin sulfate-methane transition zones are an ephemeral phenomenon occurring during increase of methane production in the sediment, which can be introduced by, e.g., gas hydrate dissociation.

  3. Where is the 1-million-year-old ice at Dome A?

    NASA Astrophysics Data System (ADS)

    Zhao, Liyun; Moore, John C.; Sun, Bo; Tang, Xueyuan; Guo, Xiaoran

    2018-05-01

    Ice fabric influences the rheology of ice, and hence the age-depth profile at ice core drilling sites. To investigate the age-depth profile to be expected of the ongoing deep ice coring at Kunlun station, Dome A, we use the depth-varying anisotropic fabric suggested by the recent polarimetric measurements around Dome A along with prescribed fabrics ranging from isotropic through girdle to single maximum in a three-dimensional, thermo-mechanically coupled full-Stokes model of a 70 × 70 km2 domain around Kunlun station. This model allows for the simulation of the near basal ice temperature and age, and ice flow around the location of the Chinese deep ice coring site. Ice fabrics and geothermal heat flux strongly affect the vertical advection and basal temperature which consequently control the age profile. Constraining modeled age-depth profiles with dated radar isochrones to 2/3 ice depth, the surface vertical velocity, and also the spatial variability of a radar isochrones dated to 153.3 ka BP, limits the age of the deep ice at Kunlun to between 649 and 831 ka, a much smaller range than previously inferred. The simple interpretation of the polarimetric radar fabric data that we use produces best fits with a geothermal heat flux of 55 mW m-2. A heat flux of 50 mW m-2 is too low to fit the deeper radar layers, and 60 mW m-2 leads to unrealistic surface velocities. The modeled basal temperature at Kunlun reaches the pressure melting point with a basal melting rate of 2.2-2.7 mm a-1. Using the spatial distribution of basal temperatures and the best fit fabric suggests that within 400 m of Kunlun station, 1-million-year-old ice may be found 200 m above the bed, and that there are large regions where even older ice is well above the bedrock within 5-6 km of the Kunlun station.

  4. Synthetic temperature profiles derived from Geosat altimetry: Comparison with air-dropped expendable bathythermograph profiles

    NASA Astrophysics Data System (ADS)

    Carnes, Michael R.; Mitchell, Jim L.; de Witt, P. Webb

    1990-10-01

    Synthetic temperature profiles are computed from altimeter-derived sea surface heights in the Gulf Stream region. The required relationships between surface height (dynamic height at the surface relative to 1000 dbar) and subsurface temperature are provided from regression relationships between dynamic height and amplitudes of empirical orthogonal functions (EOFs) of the vertical structure of temperature derived by de Witt (1987). Relationships were derived for each month of the year from historical temperature and salinity profiles from the region surrounding the Gulf Stream northeast of Cape Hatteras. Sea surface heights are derived using two different geoid estimates, the feature-modeled geoid and the air-dropped expendable bathythermograph (AXBT) geoid, both described by Carnes et al. (1990). The accuracy of the synthetic profiles is assessed by comparison to 21 AXBT profile sections which were taken during three surveys along 12 Geosat ERM ground tracks nearly contemporaneously with Geosat overflights. The primary error statistic considered is the root-mean-square (rms) difference between AXBT and synthetic isotherm depths. The two sources of error are the EOF relationship and the altimeter-derived surface heights. EOF-related and surface height-related errors in synthetic temperature isotherm depth are of comparable magnitude; each translates into about a 60-m rms isotherm depth error, or a combined 80 m to 90 m error for isotherms in the permanent thermocline. EOF-related errors are responsible for the absence of the near-surface warm core of the Gulf Stream and for the reduced volume of Eighteen Degree Water in the upper few hundred meters of (apparently older) cold-core rings in the synthetic profiles. The overall rms difference between surface heights derived from the altimeter and those computed from AXBT profiles is 0.15 dyn m when the feature-modeled geoid is used and 0.19 dyn m when the AXBT geoid is used; the portion attributable to altimeter-derived surface height errors alone is 0.03 dyn m less for each. In most cases, the deeper structure of the Gulf Stream and eddies is reproduced well by vertical sections of synthetic temperature, with largest errors typically in regions of high horizontal gradient such as across rings and the Gulf Stream front.

  5. What are the associated parameters and temporal coverage?

    Atmospheric Science Data Center

    2014-12-08

    ... Extinction Coefficient, Cloud Vertical Profile, Radar-only Liquid Water Content, Radar-only Liquid Ice Content, Vertical Flux Profile, ... ISCCP-D2like Cloud fraction, Effective Pressure, Temperature, optical depth, IWP/LWP, particle size, IR Emissivity in ...

  6. Laser depth profiling of diffusion and alpha ejection profiles in Durango apatite: testing the fundamental parameters of apatite (U-Th)/He dating

    NASA Astrophysics Data System (ADS)

    van Soest, M. C.; Monteleone, B. D.; Boyce, J. W.; Hodges, K.

    2009-12-01

    Since its development (e.g. Zeitler et al., 1987, Lippolt et al., 1994, Farley et al., 1996, Wolf et al., 1996) as a viable low temperature thermochronological method (U-Th)/He dating of apatite has become a popular and widely applied low temperature thermochronometer. The method has been applied with success to a great variety of geological problems, and the fundamental parameters of the method: the bulk diffusion parameters of helium in apatite, and the calculated theoretical helium stopping distance in apatite used to correct the ages for the effects of alpha ejection appear sound. However, the development of the UV laser microprobe technique for the (U-Th)/He method (Boyce et al., 2006) allows for in-situ testing of the helium bulk diffusion parameters (Farley, 2000) and can provide a direct measurement of the alpha ejection distance in apatite. So, with the ultimate goal of further developing the in-situ (U-Th)/He dating method and micro-analytical depth profiling techniques to constrain cooling histories in natural grains, we conducted a helium depth profiling study of induced diffusion and natural alpha ejection profiles in Durango apatite. For the diffusion depth profiling, a Durango crystal was cut in slabs oriented parallel and perpendicular to the crystal c-axis. The slabs were polished and heated using different temperature and time schedules to induce predictable diffusion profiles based on the bulk helium diffusion parameters in apatite. Depth profiling of the 4He diffusion profiles was done using an ArF excimer laser. The measured diffusion depth profiles at 350°, 400°, and 450° C coincide well with the predicted bulk diffusion curves, independent of slab orientation, but the 300° C profiles consistently deviate significantly. The possible cause for this deviation is currently being investigated. Alpha ejection profiling was carried out on crystal margins from two different Durango apatite crystals, several faces from each crystal were analyzed to evaluate the potential effects of crystallographic orientation on alpha ejection. The results from both crystals were very reproducible irrespective of crystal surface used and confirm the findings of Monteleone et al. (2008) that the measured alpha ejection profiles deviate significantly from and are shorter than the calculated theoretical average value. Efforts are currently underway to better constrain the measured alpha ejection distance and measure alpha ejection profiles in apatite crystals other than Durango apatite. References: Boyce, J. et al. (2006) GCA 70, pp. 3031-3039. Farley, K. et al. (1996) GCA 60, pp. 4223-4229. Farley, K. (2006) JGR SE 105, p. 2903-2914. Lippolt, H. et al. (1994) Chem Geol 112, pp. 179-191. Monteleone, B. et al. (2008) Eos Trans AGU, 89 Fall Meeting V53B-2162. Wolf, R. et al. (1996) GCA 60, pp. 4231-4240. Zeitler, P. et al. (1987) GCA 51, pp. 2865-2868.

  7. An objective algorithm for reconstructing the three-dimensional ocean temperature field based on Argo profiles and SST data

    NASA Astrophysics Data System (ADS)

    Zhou, Chaojie; Ding, Xiaohua; Zhang, Jie; Yang, Jungang; Ma, Qiang

    2017-12-01

    While global oceanic surface information with large-scale, real-time, high-resolution data is collected by satellite remote sensing instrumentation, three-dimensional (3D) observations are usually obtained from in situ measurements, but with minimal coverage and spatial resolution. To meet the needs of 3D ocean investigations, we have developed a new algorithm to reconstruct the 3D ocean temperature field based on the Array for Real-time Geostrophic Oceanography (Argo) profiles and sea surface temperature (SST) data. The Argo temperature profiles are first optimally fitted to generate a series of temperature functions of depth, with the vertical temperature structure represented continuously. By calculating the derivatives of the fitted functions, the calculation of the vertical temperature gradient of the Argo profiles at an arbitrary depth is accomplished. A gridded 3D temperature gradient field is then found by applying inverse distance weighting interpolation in the horizontal direction. Combined with the processed SST, the 3D temperature field reconstruction is realized below the surface using the gridded temperature gradient. Finally, to confirm the effectiveness of the algorithm, an experiment in the Pacific Ocean south of Japan is conducted, for which a 3D temperature field is generated. Compared with other similar gridded products, the reconstructed 3D temperature field derived by the proposed algorithm achieves satisfactory accuracy, with correlation coefficients of 0.99 obtained, including a higher spatial resolution (0.25° × 0.25°), resulting in the capture of smaller-scale characteristics. Finally, both the accuracy and the superiority of the algorithm are validated.

  8. Ground-Water Temperature Data, Nevada Test Site and Vicinity, Nye, Clark, and Lincoln Counties, Nevada, 2000-2006

    USGS Publications Warehouse

    Reiner, Steven R.

    2007-01-01

    Ground-water temperature data were collected by the U.S. Geological Survey in wells at and in the vicinity of the Nevada Test Site during the years 2000-2006. Periodic ground-water temperatures were collected in 166 wells. In general, periodic ground-water temperatures were measured annually in each well at 5 and 55 feet below the water surface. Ground-water temperature profiles were collected in 73 wells. Temperatures were measured at multiple depths below the water surface to produce these profiles. Databases were constructed to present the ground-water temperature data.

  9. Ground-Water Temperature Data, Nevada Test Site and Vicinity, Nye, Clark, and Lincoln Counties, Nevada, 2000-2006.

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Steven R. Reiner

    2007-08-07

    Ground-water temperature data were collected by the U.S. Geological Survey in wells at and in the vicinity of the Nevada Test Site during the years 2000–2006. Periodic ground-water temperatures were collected in 166 wells. In general, periodic ground-water temperatures were measured annually in each well at 5 and 55 feet below the water surface. Ground-water temperature profiles were collected in 73 wells. Temperatures were measured at multiple depths below the water surface to produce these profiles. Databases were constructed to present the ground-water temperature data.

  10. Nitric oxide assisted C60 secondary ion mass spectrometry for molecular depth profiling of polyelectrolyte multilayers.

    PubMed

    Zappalà, G; Motta, V; Tuccitto, N; Vitale, S; Torrisi, A; Licciardello, A

    2015-12-15

    Secondary ion mass spectrometry (SIMS) with polyatomic primary ions provides a successful tool for molecular depth profiling of polymer systems, relevant in many technological applications. Widespread C60 sources, however, cause in some polymers extensive damage with loss of molecular information along depth. We study a method, based on the use of a radical scavenger, for inhibiting ion-beam-induced reactions causing sample damage. Layered polystyrene sulfonate and polyacrylic acid based polyelectrolyte films, behaving differently towards C60 beam-induced damage, were selected and prepared as model systems. They were depth profiled by means of time-of-flight (TOF)-SIMS in dual beam mode, using fullerene ions for sputtering. Nitric oxide was introduced into the analysis chamber as a radical scavenger. The effect of sample cooling combined with NO-dosing on the quality of depth profiles was explored. NO-dosing during C60-SIMS depth profiling of >1 micrometer-thick multilayered polyelectrolytes allows detection, along depth, of characteristic fragments from systems otherwise damaged by C60 bombardment, and increases sputtering yield by more than one order of magnitude. By contrast, NO has little influence on those layers that are well profiled with C60 alone. Such leveling effect, more pronounced at low temperature, leads to a dramatic improvement of profile quality, with a clear definition of interfaces. NO-dosing provides a tool for extending the applicability, in SIMS depth profiling, of the widely spread fullerene ion sources. In view of the acceptable erosion rates on inorganics, obtainable with C60, the method could be of relevance also in connection with the 3D-imaging of hybrid polymer/inorganic systems. Copyright © 2015 John Wiley & Sons, Ltd.

  11. Seasonally frozen layer in natural and drained peatlands at the South of West Siberia, Russia

    NASA Astrophysics Data System (ADS)

    Dyukarev, Egor; Kiselev, Maxim; Voropay, Nadezhda; Preis, Yulia

    2017-04-01

    The temperature regime of soils in natural and drained peatlands at Bakchar bog located in the South Taiga zone of West Siberia is studied. Soil temperature for depths up to 320 cm was registered using autonomous temperature profile recorder during the period from August 2010 to September 2016. Maximal and minimal temperatures were registered at surface in July and February, consequently. Extreme soil temperatures at 320 cm depth shifts to December (maximum) and July (minimum) reducing absolute values. Annual peat soil temperature amplitude decrease with depth from 21,8 °C on surface to 1,1 °C at 320 cm. The analysis of daily, month and annual mean data of temperature in peat soil has shown that seasonally frozen layer was registered up to 20-60 cm depth. The duration of seasonally freeze layer existence varies from 130 to 180 days. Drained peatlands with the lowest water table have highest freeze depth. Soil at water-logged sedge-sphagnum fen in winter is warmer than soil in ryam ecosystem and mineral soil at upland. Maximal freezing depth in peatlands is up to 3 times lower than at drain areas.

  12. Two-dimensional temperature and carbon dioxide concentration profiles in atmospheric laminar diffusion flames measured by mid-infrared direct absorption spectroscopy at 4.2 μm

    NASA Astrophysics Data System (ADS)

    Liu, Xunchen; Zhang, Guoyong; Huang, Yan; Wang, Yizun; Qi, Fei

    2018-04-01

    We present a multi-line flame thermometry technique based on mid-infrared direct absorption spectroscopy of carbon dioxide at its v_3 fundamental around 4.2 μm that is particularly suitable for sooting flames. Temperature and concentration profiles of gas phase molecules in a flame are important characteristics to understand its flame structure and combustion chemistry. One of the standard laboratory flames to analyze polycyclic aromatic hydrocarbons (PAH) and soot formation is laminar non-premixed co-flow flame, but PAH and soot introduce artifact to most non-contact optical measurements. Here we report an accurate diagnostic method of the temperature and concentration profiles of CO2 in ethylene diffusion flames by measuring its v_3 vibrational fundamental. An interband cascade laser was used to probe the R-branch bandhead at 4.2 μm, which is highly sensitive to temperature change, free from soot interference and ambient background. Calibration measurement was carried out both in a low-pressure Herriott cell and an atmospheric pressure tube furnace up to 1550 K to obtain spectroscopic parameters for high-temperature spectra. In our co-flow flame measurement, two-dimensional line-of-sight optical depth of an ethylene/N2 laminar sooting flame was recorded by dual-beam absorption scheme. The axially symmetrical attenuation coefficient profile of CO2 in the co-flow flame was reconstructed from the optical depth by Abel inversion. Spatially resolved flame temperature and in situ CO2 volume fraction profiles were derived from the calibrated CO2 spectroscopic parameters and compared with temperature profiles measured by two-line atomic fluorescence.

  13. An Empirical Estimation of Underground Thermal Performance for Malaysian Climate

    NASA Astrophysics Data System (ADS)

    Mukhtar, Azfarizal; Zamri Yusoff, Mohd; Khai Ching, Ng

    2017-12-01

    In this study, the soil temperature profile was computed based on the harmonic heat transfer equations at various depths. The meteorological data ranging from January, 1st 2016 to December, 31st 2016 measured by local weather stations were employed. The findings indicted that as the soil depth increases, the temperature changes are negligible and the soil temperature is nearly equal to the mean annual air temperature. Likewise, the results have been compared with those reported by other researchers. Overall, the predicted soil temperature can be readily adopted in various engineering applications in Malaysia.

  14. Microstructure engineering of Pt-Al alloy thin films through Monte Carlo simulations

    NASA Astrophysics Data System (ADS)

    Harris, R. A.; Terblans, J. J.; Swart, H. C.

    2014-06-01

    A kinetic algorithm, based on the regular solution model, was used in conjunction with the Monte Carlo method to simulate the evolution of a micro-scaled thin film system during exposure to a high temperature environment. Pt-Al thin films were prepared via electron beam physical vapor deposition (EB-PVD) with an atomic concentration ratio of Pt63:Al37. These films were heat treated at an annealing temperature of 400 °C for 16 and 49 minutes. Scanning Auger Microscopy (SAM) (PHI 700) was used to obtain elemental maps while sputtering through the thin films. Simulations were run for the same annealing temperatures and thin-film composition. From these simulations theoretical depth profiles and simulated microstructures were obtained. These were compared to the experimentally measured depth profiles and elemental maps.

  15. Auger electron spectroscopy and depth profile study of oxidation of modified 440C steel

    NASA Technical Reports Server (NTRS)

    Ferrante, J.

    1974-01-01

    Auger electron spectroscopy (AES) and sputtering were used to study selective oxidation of modified 440C steel. The sample was polycrystalline. Oxidation was performed on initially clean surfaces for pressures ranging from 1 x 10 to the minus 7th power to 1 x 10 to the minus 5th power torr and temperatures ranging from room temperature to 800 C. AES traces were taken during oxidation. In situ sputtering depth profiles are also obtained. A transition temperature is observed in the range 600 to 700 C for which the composition of the outer surface oxide changed from iron oxide to chromium oxide. Heating in vacuum about 5 x 10 to the minus 10 power torr to 700 C causes conversion of the iron oxide surface to chromium oxide.

  16. Mixed layer warming-deepening in the Mediterranean Sea and its effect on the marine environment

    NASA Astrophysics Data System (ADS)

    Rivetti, Irene; Boero, Ferdinando; Fraschetti, Simonetta; Zambianchi, Enrico; Lionello, Piero

    2015-04-01

    This work aims at investigating the evolution of the ocean mixed layer in the Mediterranean Sea and linking it to the occurrence of mass mortalities of benthic invertebrates. The temporal evolution of selected parameters describing the mixed layer and the seasonal thermocline is provided for the whole Mediterranean Sea for spring, summer and autumn and for the period 1945-2011. For this analysis all temperature profiles collected in the basin with bottles, Mechanical Bathy-Thermographs (MBT), eXpendable Bathy-Thermographs (XBT), and Conductivity-Temperature-Depth (CTD) have been used (166,990). These data have been extracted from three public sources: the MEDAR-MEDATLAS, the World Ocean Database 2013 and the MFS-VOS program. Five different methods for estimating the mixed layer depth are compared using temperature profiles collected at the DYFAMED station in the Ligurian Sea and one method, the so-called three-segment method, has been selected for a systematic analysis of the evolution of the uppermost part of the whole Mediterranean Sea. This method approximates the upper water column with three segments representing mixed layer, thermocline and deep layer and has shown to be the most suitable method for capturing the mixed layer depth for most shapes of temperature profiles. Mass mortalities events of benthic invertebrates have been identified by an extensive search of all data bases in ISI Web of Knowledge considering studies published from 1945 to 2011. Studies reporting the geographical coordinates, the timing of the events, the species involved and the depth at which signs of stress occurred have been considered. Results show a general increase of thickness and temperature of the mixed layer, deepening and cooling of the thermocline base in summer and autumn. Possible impacts of these changes are mass mortalities events of benthic invertebrates that have been documented since 1983 mainly in summer and autumn. It is also shown that most mass mortalities occurred in months with anomalously high mixed layer depth temperature leading to the conclusion that warming of upper Mediterranean Sea has allowed interannual temperature variability to reach environmental conditions beyond the thermal tolerance of some species.

  17. SCUBA divers as oceanographic samplers: The potential of dive computers to augment aquatic temperature monitoring

    PubMed Central

    Wright, Serena; Hull, Tom; Sivyer, David B.; Pearce, David; Pinnegar, John K.; Sayer, Martin D. J.; Mogg, Andrew O. M.; Azzopardi, Elaine; Gontarek, Steve; Hyder, Kieran

    2016-01-01

    Monitoring temperature of aquatic waters is of great importance, with modelled, satellite and in-situ data providing invaluable insights into long-term environmental change. However, there is often a lack of depth-resolved temperature measurements. Recreational dive computers routinely record temperature and depth, so could provide an alternate and highly novel source of oceanographic information to fill this data gap. In this study, a citizen science approach was used to obtain over 7,000 scuba diver temperature profiles. The accuracy, offset and lag of temperature records was assessed by comparing dive computers with scientific conductivity-temperature-depth instruments and existing surface temperature data. Our results show that, with processing, dive computers can provide a useful and novel tool with which to augment existing monitoring systems all over the globe, but especially in under-sampled or highly changeable coastal environments. PMID:27445104

  18. Magnetic nonuniformity and thermal hysteresis of magnetism in a manganite thin film.

    PubMed

    Singh, Surendra; Fitzsimmons, M R; Lookman, T; Thompson, J D; Jeen, H; Biswas, A; Roldan, M A; Varela, M

    2012-02-17

    We measured the chemical and magnetic depth profiles of a single crystalline (La(1-x)Pr(x))(1-y)Ca(y)MnO(3-δ) (x=0.52±0.05, y=0.23±0.04, δ=0.14±0.10) film grown on a NdGaO(3) substrate using x-ray reflectometry, electron microscopy, electron energy-loss spectroscopy, and polarized neutron reflectometry. Our data indicate that the film exhibits coexistence of different magnetic phases as a function of depth. The magnetic depth profile is correlated with a variation of chemical composition with depth. The thermal hysteresis of ferromagnetic order in the film suggests a first-order ferromagnetic transition at low temperatures.

  19. Depth profiles of oxygen precipitates in nitride-coated silicon wafers subjected to rapid thermal annealing

    NASA Astrophysics Data System (ADS)

    Voronkov, V. V.; Falster, R.; Kim, TaeHyeong; Park, SoonSung; Torack, T.

    2013-07-01

    Silicon wafers, coated with a silicon nitride layer and subjected to high temperature Rapid Thermal Annealing (RTA) in Ar, show—upon a subsequent two-step precipitation anneal cycle (such as 800 °C + 1000 °C)—peculiar depth profiles of oxygen precipitate densities. Some profiles are sharply peaked near the wafer surface, sometimes with a zero bulk density. Other profiles are uniform in depth. The maximum density is always the same. These profiles are well reproduced by simulations assuming that precipitation starts from a uniformly distributed small oxide plates originated from RTA step and composed of oxygen atoms and vacancies ("VO2 plates"). During the first step of the precipitation anneal, an oxide layer propagates around this core plate by a process of oxygen attachment, meaning that an oxygen-only ring-shaped plate emerges around the original plate. These rings, depending on their size, then either dissolve or grow during the second part of the anneal leading to a rich variety of density profiles.

  20. SIMULATION OF DISSOLVED OXYGEN PROFILES IN A TRANSPARENT, DIMICTIC LAKE

    EPA Science Inventory

    Thrush Lake is a small, highly transparent lake in northeastern Minnesota. rom 1986 to 1991, vertical profiles of water temperature, dissolved oxygen, chlorophyll a concentration, underwater light irradiance, and Secchi depths were measured at monthly intervals during the ice-fre...

  1. How does whole ecosystem warming of a peatland affect methane production and consumption?

    NASA Astrophysics Data System (ADS)

    Hopple, A.; Brunik, K.; Keller, J.; Pfeifer-Meister, L.; Woerndle, G.; Zalman, C.; Hanson, P.; Bridgham, S. D.

    2017-12-01

    Peatlands are among Earth's most important terrestrial ecosystems due to their massive soil carbon (C) stores and significant release of methane (CH4) into the atmosphere. Methane has a sustained-flux global warming potential 45-times greater than carbon dioxide (CO2), and the accuracy of Earth system model projections relies on our mechanistic understanding of peatland CH4 cycling in the context of environmental change. The objective of this study was to determine, under in situ conditions, how heating of the peat profile affects ecosystem-level anaerobic C cycling. We assessed the response of CO2 and CH4 production, as well as the anaerobic oxidation of CH4 (AOM), in a boreal peatland following 13 months of deep peat heating (DPH) and 16 months of subsequent whole-ecosystem warming (surface and deep heating; WEW) as part of the Spruce and Peatland Responses Under Changing Environments (SPRUCE) project in northern Minnesota, USA. The study uses a regression-based experimental design including 5 temperature treatments that warmed the entire 2 m peat profile from 0 to +9 °C above ambient temperature. Soil cores were collected at multiple depths (25-200 cm) from each experimental chamber at the SPRUCE site and anaerobically incubated at in situ temperatures for 1-2 weeks. Methane and CO2 production in surface peat were positively correlated with elevated temperature, but no consistent temperature response was found at depth (75-200 cm) following DPH. However, during WEW, we observed significant increases in both surface and deep peat methanogenesis with increasing temperature. Surface peat had greater CH4 production rates than deeper peat, implying that the increased CH4 emissions observed in the field were largely driven by surface peat warming. The CO2:CH4 ratio was inversely correlated with temperature across all depths following 16 months of WEW, indicating that the entire peat profile is becoming more methanogenic with warming. We also observed AOM throughout the whole peat profile, with the highest rates observed at the surface and initial data suggesting a positive correlation with increasing temperature. While SPRUCE will continue for many years, our initial results suggest that the vast C stores at depth in peatlands are minimally responsive to warming and any response will be driven largely by surface peat.

  2. Upper Ocean Profiles Measurements with ASIP

    NASA Astrophysics Data System (ADS)

    Ward, B.; Callaghan, A. H.; Fristedt, T.; Vialard, J.; Cuypers, Y.; Weller, R. A.; Grosch, C. E.

    2009-04-01

    This presentation describes results from the Air-Sea Interaction Profiler (ASIP), an autonomous profiling instrument for upper ocean measurements. The measurements from ASIP are well suited to enhancing research on air-sea interfacial and near surface processes. Autonomous profiling is accomplished with a thruster, which submerges ASIP to a programmed depth. Once this depth is reached the positively buoyant instrument will ascend to the surface acquiring data. ASIP can profile from a maximum depth of 100 m to the surface, allowing both mixed layer and near-surface measurements to be conducted. The sensor payload on ASIP include microstructure sensors (two shear probes and a thermistor); a slow response accurate thermometer; a pair of conductivity sensors; pressure for a record of depth; PAR for measurements of light absorption in the water column. Other non-environmental sensors are acceleration, rate, and heading for determination of vehicle motion. Power is provided with rechargable lithium-ion batteries, supplying 1000 Whr, allowing approximately 300 profiles. ASIP also contains an iridium/GPS system, which allows realtime reporting of its position. ASIP was deployed extensively during the Cirene Indian Ocean campaign and our results focus on the data from the temperature, salinity, light, and shear sensors.

  3. Observations of pockmark flow structure in Belfast Bay, Maine, Part 1: current-induced mixing

    USGS Publications Warehouse

    Fandel, Christina L.; Lippmann, Thomas C.; Irish, James D.; Brothers, Laura L.

    2017-01-01

    Field observations of current profiles and temperature, salinity, and density structure were used to examine vertical mixing within two pockmarks in Belfast Bay, Maine. The first is located in 21 m water depth (sea level to rim), nearly circular in shape with a 45 m rim diameter and 12 m rim-to-bottom relief. The second is located in 25 m water depth, more elongated in shape with an approximately 80 m (36 m) major (minor) axis length at the rim, and 17 m relief. Hourly averaged current profiles were acquired from bottom-mounted acoustic Doppler current profilers deployed on the rim and center of each pockmark over successive 42 h periods in July 2011. Conductivity–temperature–depth casts at the rim and center of each pockmark show warmer, fresher water in the upper water column, evidence of both active and fossil thermocline structure 5–8 m above the rim, and well-mixed water below the rim to the bottom. Vertical velocities show up- and down-welling events that extend into the depths of each pockmark. An observed temperature change at both the rim and center occurs coincident with an overturning event below the rim, and suggests active mixing of the water column into the depths of each pockmark. Vertical profiles of horizontal velocities show depth variation at both the center and rim consistent with turbulent logarithmic current boundary layers, and suggest that form drag may possibly be influencing the local flow regime. While resource limitations prevented observation of the current structure and water properties at a control site, the acquired data suggest that active mixing and overturning within the sampled pockmarks occur under typical benign conditions, and that current flows are influenced by upstream bathymetric irregularities induced by distant pockmarks.

  4. A measurement system for vertical seawater profiles close to the air-sea interface

    NASA Astrophysics Data System (ADS)

    Sims, Richard P.; Schuster, Ute; Watson, Andrew J.; Yang, Ming Xi; Hopkins, Frances E.; Stephens, John; Bell, Thomas G.

    2017-09-01

    This paper describes a near-surface ocean profiler, which has been designed to precisely measure vertical gradients in the top 10 m of the ocean. Variations in the depth of seawater collection are minimized when using the profiler compared to conventional CTD/rosette deployments. The profiler consists of a remotely operated winch mounted on a tethered yet free-floating buoy, which is used to raise and lower a small frame housing sensors and inlet tubing. Seawater at the inlet depth is pumped back to the ship for analysis. The profiler can be used to make continuous vertical profiles or to target a series of discrete depths. The profiler has been successfully deployed during wind speeds up to 10 m s-1 and significant wave heights up to 2 m. We demonstrate the potential of the profiler by presenting measured vertical profiles of the trace gases carbon dioxide and dimethylsulfide. Trace gas measurements use an efficient microporous membrane equilibrator to minimize the system response time. The example profiles show vertical gradients in the upper 5 m for temperature, carbon dioxide and dimethylsulfide of 0.15 °C, 4 µatm and 0.4 nM respectively.

  5. Ortho-para-hydrogen equilibration on Jupiter

    NASA Technical Reports Server (NTRS)

    Carlson, Barbara E.; Lacis, Andrew A.; Rossow, William B.

    1992-01-01

    Voyager IRIS observations reveal that the Jovian para-hydrogen fraction is not in thermodynamic equilibrium near the NH3 cloud top, implying that a vertical gradient exists between the high-temperature equilibrium value of 0.25 at depth and the cloud top values. The height-dependent para-hydrogen profile is obtained using an anisotropic multiple-scattering radiative transfer model. A vertical correlation is found to exist between the location of the para-hydrogen gradient and the NH3 cloud, strongly suggesting that paramagnetic conversion on NH3 cloud particle surfaces is the dominant equilibration mechanism. Below the NH3 cloud layer, the para fraction is constant with depth and equal to the high-temperature equilibrium value of 0.25. The degree of cloud-top equilibration appears to depend on the optical depth of the NH3 cloud layer. Belt-zone variations in the para-hydrogen profile seem to be due to differences in the strength of the vertical mixing.

  6. Evaluation of the Sparton tight-tolerance AXBT

    NASA Technical Reports Server (NTRS)

    Boyd, Janice D.; Linzell, Robert S.

    1993-01-01

    Forty-six near-simultaneous pairs of conductivity - temperature - depth (CTD) and Sparton 'tight tolerance' air expendable bathythermograph (AXBT) temperature profiles were obtained in summer 1991 from a location in the Sargasso Sea. The data were analyzed to assess the temperature and depth accuracies of the Sparton AXBTs. The tight-tolerance criterion was not achieved using the manufacturer's equations but may have been achieved using customized equations computed from the CTD data. The temperature data from the customized equations had a one standard deviation error of 0.13 C. A customized elapsed fall time-to-depth conversion equation was found to be z = 1.620t - 2.2384 x 10(exp -4) t(exp 2) + 1.291 x 10(exp -7) t(exp 3), with z the depth in meters and t the elapsed fall time after probe release in seconds. The standard deviation of the depth error was about 5 m; a rule of thumb for estimating maximum bounds on the depth error below 100 m could be expressed as +/-2% of depth or +/- 10 m, whichever is greater. This equation gave greater depth accuracy than either the manufacturer's supplied equation or the navy standard equation.

  7. Implantation of sodium ions into germanium

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Korol', V. M., E-mail: vkorol@ctsnet.ru; Kudriavtsev, Yu.

    The donor properties of Na atoms introduced by ion implantation into p-Ge with the resistivity 20-40 {Omega} cm are established for the first time. Na profiles implanted into Ge (the energies 70 and 77 keV and the doses (0.8, 3, 30) Multiplication-Sign 10{sup 14} cm{sup -2}) are studied. The doses and annealing temperatures at which the thermoprobe detects n-type conductivity on the sample surface are established. After implantation, the profiles exhibit an extended tail. The depth of the concentration maximum is in good agreement with the calculated mean projected range of Na ions R{sub p}. Annealing for 30 min atmore » temperatures of 250-700 Degree-Sign C brings about a redistribution of Na atoms with the formation of segregation peaks at a depth, which is dependent on the ion dose, and is accompanied by the diffusion of Na atoms to the surface with subsequent evaporation. After annealing at 700 Degree-Sign C less than 7% of the implanted ions remain in the matrix. The shape of the profile tail portions measured after annealing at temperatures 300-400 Degree-Sign C is indicative of the diffusion of a small fraction of Na atoms into the depth of the sample.« less

  8. Soil Temperature and Moisture Profile (STAMP) System Handbook

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Cook, David R.

    The soil temperature and moisture profile system (STAMP) provides vertical profiles of soil temperature, soil water content (soil-type specific and loam type), plant water availability, soil conductivity, and real dielectric permittivity as a function of depth below the ground surface at half-hourly intervals, and precipitation at one-minute intervals. The profiles are measured directly by in situ probes at all extended facilities of the SGP climate research site. The profiles are derived from measurements of soil energy conductivity. Atmospheric scientists use the data in climate models to determine boundary conditions and to estimate the surface energy flux. The data are alsomore » useful to hydrologists, soil scientists, and agricultural scientists for determining the state of the soil. The STAMP system replaced the SWATS system in early 2016.« less

  9. Nonextensive statistics and skin depth of transverse wave in collisional plasma

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Hashemzadeh, M., E-mail: hashemzade@gmail.com

    Skin depth of transverse wave in a collisional plasma is studied taking into account the nonextensive electron distribution function. Considering the kinetic theory for charge particles and using the Bhatnagar-Gross-Krook collision model, a generalized transverse dielectric permittivity is obtained. The transverse dispersion relation in different frequency ranges is investigated. Obtaining the imaginary part of the wave vector from the dispersion relation, the skin depth for these frequency ranges is also achieved. Profiles of the skin depth show that by increasing the q parameter, the penetration depth decreases. In addition, the skin depth increases by increasing the electron temperature. Finally, itmore » is found that in the high frequency range and high electron temperature, the penetration depth decreases by increasing the collision frequency. In contrast, by increasing the collision frequency in a highly collisional frequency range, the skin depth of transverse wave increases.« less

  10. Laser depth profiling studies of helium diffusion in Durango fluorapatite

    NASA Astrophysics Data System (ADS)

    van Soest, Matthijs C.; Monteleone, Brian D.; Hodges, Kip V.; Boyce, Jeremy W.

    2011-05-01

    Ultraviolet lasers coupled with sensitive mass spectrometers provide a useful way to measure laboratory-induced noble gas diffusion profiles in minerals, thus enabling the calculation of diffusion parameters. We illustrate this laser ablation depth profiling (LADP) technique for a previously well-studied mineral-isotopic system: 4He in Durango fluorapatite. LADP studies were conducted on oriented, polished slabs from a single crystal that were heated under vacuum to a variety of temperatures between 300 and 450 °C for variable times. The resolved 4He profiles exhibited error-function loss as predicted by previous bulk 4He diffusion studies. All of the slabs, regardless of crystallographic orientation, yielded modeled diffusivities that are statistically co-linear on an Arrhenius diagram, suggesting no diffusional anisotropy of 4He in this material. The data indicate an activation energy of 142.2 ± 5.0 (2 σ) kJ/mol and diffusivity at infinite temperature - reported as ln( D0) - of -4.71 ± 0.94 (2 σ) m 2/s. These values imply a bulk closure temperature for 4He in Durango fluorapatite of 74 °C for a 50 μm radius grain, infinite cylinder geometry, and a cooling rate of 10 °C/Myr.

  11. High Resolution Near-Bed Observations in Winter Near Cape Hatteras, North Carolina

    DTIC Science & Technology

    2010-06-01

    Druck pressure sensors, Campbell optical backscatter, and Seatech or Wetlabs CSTAR transmission sensors. All the transmissometers were 25 cm path...14.0 m Depth Flobee Tripods Sontek hydra Acoustic Doppler velocimeter (ADV), thermistor 3D flow velocity, temperature 8 Hz for 17.5 min hourly Pulse...coherent acoustic Doppler profiler (PCADP), thermistor Profiles of 3D flow velocity, temperature 1 Hz for 17.5 min hourly, 6.3 cm bins Pressure

  12. Oxygen depth profiling by resonant RBS in NiTi after plasma immersion ion implantation

    NASA Astrophysics Data System (ADS)

    Mändl, S.; Lindner, J. K. N.

    2006-08-01

    NiTi exhibits super-elastic as well as shape-memory properties, which results in a large potential application field in biomedical technology. Using oxygen ion implantation at elevated temperatures, it is possible to improve the biocompatibility. Resonant Rutherford backscattering spectroscopy (RRBS) is used to investigate the oxygen depth profile obtained after oxygen plasma immersion ion implantation (PIII) at 25 kV and 400-600 °C. At all temperatures, a layered structure consisting of TiO2/Ni3Ti/NiTi was found with sharp interfaces while no discernible content of oxygen inside Ni3Ti or nickel in TiO2 was found. These data are compatible with a titanium diffusion from the bulk towards the implanted oxygen.

  13. An approach to parameter estimation for breast tumor by finite element method

    NASA Astrophysics Data System (ADS)

    Xu, A.-qing; Yang, Hong-qin; Ye, Zhen; Su, Yi-ming; Xie, Shu-sen

    2009-02-01

    The temperature of human body on the surface of the skin depends on the metabolic activity, the blood flow, and the temperature of the surroundings. Any abnormality in the tissue, such as the presence of a tumor, alters the normal temperature on the skin surface due to increased metabolic activity of the tumor. Therefore, abnormal skin temperature profiles are an indication of diseases such as tumor or cancer. This study is to present an approach to detect the female breast tumor and its related parameter estimations by combination the finite element method with infrared thermography for the surface temperature profile. A 2D simplified breast embedded a tumor model based on the female breast anatomical structure and physiological characteristics was first established, and then finite element method was used to analyze the heat diffuse equation for the surface temperature profiles of the breast. The genetic optimization algorithm was used to estimate the tumor parameters such as depth, size and blood perfusion by minimizing a fitness function involving the temperature profiles simulated data by finite element method to the experimental data obtained by infrared thermography. This preliminary study shows it is possible to determine the depth and the heat generation rate of the breast tumor by using infrared thermography and the optimization analysis, which may play an important role in the female breast healthcare and diseases evaluation or early detection. In order to develop the proposed methodology to be used in clinical, more accurate anatomy 3D breast geometry should be considered in further investigations.

  14. Insights into accumulation variability over the last 2000 years at James Ross Island, Antarctic Peninsula

    NASA Astrophysics Data System (ADS)

    Massam, A.; Mulvaney, R.; McConnell, J.; Abram, N.; Arienzo, M. M.; Whitehouse, P. L.

    2016-12-01

    The James Ross Island ice core, drilled to 364 m on the northern tip of the Antarctic Peninsula, preserves a climate record that spans beyond the Holocene period to the end of the last glacial maximum (LGM). Reanalysis of the ice core using high-resolution continuous flow analysis (CFA) highlighted errors in the identification of events of known age that had been used to constrain the earlier chronology. The new JRI2 chronology is annual layer counted to 300 years, with the remaining profile reconstructed using a new age-depth model that is tied to age horizons identified in the annual-layer counted WAIS Divide ice core record. An accurate age-depth profile requires reliable known-age horizons along the ice core profile. In addition, these allow us to determine a solution for the accumulation history and rate of compaction due to vertical strain. The accuracy of the known-age constraints used in JRI2 allows only a small uncertainty in the reconstruction of the most recent 2000 years of accumulation variability. Independently, the surface temperature profile has been estimated from the stable water isotope profile and calibrated to borehole temperature observations. We present the accumulation, vertical thinning and temperature history interpreted from the James Ross Island ice core for the most recent 2000 years. JRI2 reconstructions show accumulation variability on a decadal to centennial timescale up to 20% from the present-day mean annual accumulation rate of 0.63 m yr-1. Analysis of the accumulation profile for James Ross Island offers insight into the sensitivity of accumulation to a change in surface temperature, as well as the reliability of the assumed relationship between accumulation and surface temperature in climate reconstructions using stable water isotope proxies.

  15. Lunar electrical conductivity and magnetic permeability

    NASA Technical Reports Server (NTRS)

    Dyal, P.; Parkin, C. W.; Daily, W. D.

    1975-01-01

    Improved analytical techniques are applied to a large Apollo magnetometer data set to yield values of electroconductivity, temperature, magnetic permeability, and iron abundance. Average bulk electroconductivity of the moon is calculated to be .0007 mho/m; a rapid increase with depth to about .003 mho/m within 250 km is indicated. The temperature profile, obtained from the electroconductivity profile for olivine, indicates high lunar temperatures at relatively shallow depths. Magnetic permeability of the moon relative to its environment is calculated to be 1.008 plus or minus .005; a permeability relative to free space of 1.012 plus 0.011, minus 0.008 is obtained. Lunar iron abundances corresponding to this permeability value are 2.5 plus 2.3, minus 1.7 wt% free iron and 5.0-13.5 wt% total iron for a moon composed of a combination of free iron, olivine, and orthopyroxene.

  16. Comment on Rayleigh-Scattering Calculations for the Terrestrial Atmosphere

    NASA Astrophysics Data System (ADS)

    On, Ois-Marie

    1998-01-01

    It is shown that, for a given surface pressure, the atmospheric vertical temperature profile has a negligible influence on the Rayleigh optical depth. This contradicts the Bucholtz recommendation for the use of values that vary with air mass type. The influence of atmospheric water vapor amount on the Rayleigh optical depth is also investigated.

  17. Diurnal variations in optical depth at Mars

    NASA Technical Reports Server (NTRS)

    Colburn, D. S.; Pollack, J. B.; Haberle, R. M.

    1989-01-01

    Viking lander camera images of the Sun were used to compute atmospheric optical depth at two sites over a period of 1 to 1/3 martian years. The complete set of 1044 optical depth determinations is presented in graphical and tabular form. Error estimates are presented in detail. Otpical depths in the morning (AM) are generally larger than in the afternoon (PM). The AM-PM differences are ascribed to condensation of water vapor into atmospheric ice aerosols at night and their evaporation in midday. A smoothed time series of these differences shows several seasonal peaks. These are simulated using a one-dimensional radiative convective model which predicts martial atmospheric temperature profiles. A calculation combinig these profiles with water vapor measurements from the Mars Atmospheric Water Detector is used to predict when the diurnal variations of water condensation should occur. The model reproduces a majority of the observed peaks and shows the factors influencing the process. Diurnal variation of condensation is shown to peak when the latitude and season combine to warm the atmosphere to the optimum temperature, cool enough to condense vapor at night and warm enough to cause evaporation at midday.

  18. Capacitive radio frequency discharges with a single ring-shaped narrow trench of various depths to enhance the plasma density and lateral uniformity

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Ohtsu, Y., E-mail: ohtsuy@cc.saga-u.ac.jp; Matsumoto, N.; Schulze, J.

    2016-03-15

    Spatial structures of the electron density and temperature in ring-shaped hollow cathode capacitive rf plasma with a single narrow trench of 2 mm width have been investigated at various trench depths of D = 5, 8, 10, 12, and 15 mm. It is found that the plasma density is increased in the presence of the trench and that the radial profile of the plasma density has a peak around the narrow hollow trench near the cathode. The density becomes uniform further away from the cathode at all trench depths, whereas the electron temperature distribution remains almost uniform. The measured radial profiles of the plasmamore » density are in good agreement with a theoretical diffusion model for all the trench depths, which explains the local density increase by a local enhancement of the electron heating. Under the conditions investigated, the trench of 10 mm depth is found to result in the highest plasma density at various axial and radial positions. The results show that the radial uniformity of the plasma density at various axial positions can be improved by using structured electrodes of distinct depths rather than planar electrodes.« less

  19. Behavioural thermoregulation by subyearling fall (autumn) Chinook salmon oncorhynchus tshawytscha in a reservoir

    USGS Publications Warehouse

    Tiffan, K.F.; Kock, T.J.; Connor, W.P.; Steinhorst, R.K.; Rondorf, D.W.

    2009-01-01

    This study investigated behavioural thermoregulation by subyearling fall (autumn) Chinook salmon Oncorhynchus tshawytscha in a reservoir on the Snake River, Washington, U.S.A. During the summer, temperatures in the reservoir varied from 23?? C on the surface to 11?? C at 14 m depth. Subyearlings implanted with temperature-sensing radio transmitters were released at the surface at temperatures >20?? C during three blocks of time in summer 2004. Vertical profiles were taken to measure temperature and depth use as the fish moved downstream over an average of 5??6-7??2 h and 6??0-13??8 km. The majority of the subyearlings maintained average body temperatures that differed from average vertical profile temperatures during most of the time they were tracked. The mean proportion of the time subyearlings tracked within the 16-20?? C temperature range was larger than the proportion of time this range was available, which confirmed temperature selection opposed to random use. The subyearlings selected a depth and temperature combination that allowed them to increase their exposure to temperatures of 16-20?? C when temperatures 20?? C were available at lower and higher positions in the water column. A portion of the subyearlings that selected a temperature c. 17??0?? C during the day, moved into warmer water at night coincident with an increase in downstream movement rate. Though subyearlings used temperatures outside of the 16-20?? C range part of the time, behavioural thermoregulation probably reduced the effects of intermittent exposure to suboptimal temperatures. By doing so, it might enhance growth opportunity and life-history diversity in the population of subyearlings studied.

  20. Oxygen isotope exchange in rocks and minerals from the Cerro Prieto geothermal system: Indicators of temperature distribution and fluid flow

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Williams, A.E.; Elders, W.A.

    1981-01-01

    Oxygen isotopic compositions have been measured in drill cuttings and core samples from more than 40 wells ranging in depth to more than 3.5 km in the Cerro Prieto geothermal field. Profiles of isotopic ratios versus sampling depths provide information on the three-dimensional distribution of temperature and fluid flow. These parameters also indicate variations in the history of hydrothermal processes in different areas of the geothermal field.

  1. Chemical depth profiles of the GaAs/native oxide interface

    NASA Technical Reports Server (NTRS)

    Grunthaner, P. J.; Vasquez, R. P.; Grunthaner, F. J.

    1980-01-01

    The final-state oxidation products and their distribution in thin native oxides (30-40 A) on GaAs have been studied using X-ray photoelectron spectroscopy in conjunction with chemical depth profiling. Extended room-temperature-oxidation conditions have been chosen to allow the native oxide to attain its equilibrium composition and structure. The work emphasizes the use of chemical depth-profiling methods which make it possible to examine the variation in chemical reactivity of the oxide structure. A minimum of two distinct regions of Ga2O3 with differing chemical reactivity is observed. Chemical shift data indicate the presence of As2O3 in the oxide together with an elemental As overlayer at the interface. A change in relative charge transfer between oxygen and both arsenic and gallium-oxide species is observed in the region of the interface.

  2. Multilevel groundwater monitoring of hydraulic head and temperature in the eastern Snake River Plain aquifer, Idaho National Laboratory, Idaho, 2007-08

    USGS Publications Warehouse

    Fisher, Jason C.; Twining, Brian V.

    2011-01-01

    During 2007 and 2008, the U.S. Geological Survey, in cooperation with the U.S. Department of Energy, collected quarterly depth-discrete measurements of fluid pressure and temperature in six boreholes located in the eastern Snake River Plain aquifer of Idaho. Each borehole was instrumented with a multilevel monitoring system consisting of a series of valved measurement ports, packer bladders, casing segments, and couplers. Hydraulic heads (head) and water temperatures in boreholes were monitored at 86 hydraulically-isolated depth intervals located 448.0 to 1,377.6 feet below land surface. The calculation of head is most sensitive to fluid pressure and the altitude of the pressure transducer at each port coupling; it is least sensitive to barometric pressure and water temperature. An analysis of errors associated with the head calculation determined the accuracy of an individual head measurement at +/- 2.3 feet. Many of the sources of measurement error are diminished when considering the differences between two closely-spaced readings of head; therefore, a +/- 0.1 foot measurement accuracy was assumed for vertical head differences (and gradients) calculated between adjacent monitoring zones. Vertical head and temperature profiles were unique to each borehole, and were characteristic of the heterogeneity and anisotropy of the eastern Snake River Plain aquifer. The vertical hydraulic gradients in each borehole remained relatively constant over time with minimum Pearson correlation coefficients between head profiles ranging from 0.72 at borehole USGS 103 to 1.00 at boreholes USGS 133 and MIDDLE 2051. Major inflections in the head profiles almost always coincided with low permeability sediment layers. The presence of a sediment layer, however, was insufficient for identifying the location of a major head change in a borehole. The vertical hydraulic gradients were defined for the major inflections in the head profiles and were as much as 2.2 feet per foot. Head gradients generally were downward in boreholes USGS 133, 134, and MIDDLE 2050A, zero in boreholes USGS 103 and 132, and exhibited a reversal in direction in borehole MIDDLE 2051. Water temperatures in all boreholes ranged from 10.2 to 16.3 degrees Celsius. Boreholes USGS 103 and 132 are in an area of concentrated volcanic vents and fissures, and measurements show water temperature decreasing with depth. All other measurements in boreholes show water temperature increasing with depth. A comparison among boreholes of the normalized mean head over time indicates a moderately positive correlation.

  3. Soil Water and Temperature System (SWATS) Instrument Handbook

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Cook, David R.

    2016-04-01

    The soil water and temperature system (SWATS) provides vertical profiles of soil temperature, soil-water potential, and soil moisture as a function of depth below the ground surface at hourly intervals. The temperature profiles are measured directly by in situ sensors at the Central Facility and many of the extended facilities of the U.S. Department of Energy (DOE)’s Atmospheric Radiation Measurement (ARM) Climate Research Facility Southern Great Plains (SGP) site. The soil-water potential and soil moisture profiles are derived from measurements of soil temperature rise in response to small inputs of heat. Atmospheric scientists use the data in climate models tomore » determine boundary conditions and to estimate the surface energy flux. The data are also useful to hydrologists, soil scientists, and agricultural scientists for determining the state of the soil.« less

  4. Five-band microwave radiometer system for noninvasive brain temperature measurement in newborn babies: Phantom experiment and confidence interval

    NASA Astrophysics Data System (ADS)

    Sugiura, T.; Hirata, H.; Hand, J. W.; van Leeuwen, J. M. J.; Mizushina, S.

    2011-10-01

    Clinical trials of hypothermic brain treatment for newborn babies are currently hindered by the difficulty in measuring deep brain temperatures. As one of the possible methods for noninvasive and continuous temperature monitoring that is completely passive and inherently safe is passive microwave radiometry (MWR). We have developed a five-band microwave radiometer system with a single dual-polarized, rectangular waveguide antenna operating within the 1-4 GHz range and a method for retrieving the temperature profile from five radiometric brightness temperatures. This paper addresses (1) the temperature calibration for five microwave receivers, (2) the measurement experiment using a phantom model that mimics the temperature profile in a newborn baby, and (3) the feasibility for noninvasive monitoring of deep brain temperatures. Temperature resolutions were 0.103, 0.129, 0.138, 0.105 and 0.111 K for 1.2, 1.65, 2.3, 3.0 and 3.6 GHz receivers, respectively. The precision of temperature estimation (2σ confidence interval) was about 0.7°C at a 5-cm depth from the phantom surface. Accuracy, which is the difference between the estimated temperature using this system and the measured temperature by a thermocouple at a depth of 5 cm, was about 2°C. The current result is not satisfactory for clinical application because the clinical requirement for accuracy must be better than 1°C for both precision and accuracy at a depth of 5 cm. Since a couple of possible causes for this inaccuracy have been identified, we believe that the system can take a step closer to the clinical application of MWR for hypothermic rescue treatment.

  5. Oceanic Residual Depth Anomalies Maintained by a Shallow Asthenospheric Channel

    NASA Astrophysics Data System (ADS)

    Richards, F. D.; Hoggard, M.; White, N.

    2016-12-01

    Oceanic residual depth anomalies vary on wavelengths of 800-2,000 km and have amplitudesof ±1 km. There is also evidence from glacio-isostatic adjustment, plate motions and seismicanisotropy studies for the existence of a low-viscosity asthenospheric channel immediately beneaththe lithospheric plates. Here, we investigate whether global residual depth anomalies are consistentwith temperature variations within a sub-plate channel. For a given channel thickness, we convertresidual depth anomalies into temperature anomalies, assuming thermal isostasy alone (i.e. no mantle flow). Using aparameterisation that is calibrated against stacked oceanic shear wave velocity profiles, we convertthese temperature anomalies into velocity variations. We then compare the inferred velocity vari-ations with published seismic tomographic models. We find that thermal anomalies of ±100 °Cwithin a 150 ± 50 km thick channel yield a good match to > 95% of global residual depth anoma-lies. These temperature variations are consistent with geochemical evidence from mid-oceanic ridgebasalts and oceanic crustal thicknesses. The apparent success of this simple isostatic approach sup-ports the existence of a low-viscosity asthenospheric channel that plays a key role in controllingresidual depth anomalies. Far from subduction zones and from plume conduits, dynamic topog-raphy in the oceanic realm appears to be primarily controlled by temperature-induced buoyancyvariations within this channel.

  6. Consequences of a chromospheric temperature gradient on the width of H Alpha in late-type giants

    NASA Technical Reports Server (NTRS)

    Zarro, D. M.

    1984-01-01

    An analytic expression for the integrated H alpha optical depth profile is derived for a one dimensional slab geometry model chromosphere, with electron temperature increasing as a power law with height. The formula predicts H alpha opacity and profile width to be sensitive functions of the thermal gradient. Application of the model to observation reveals that broad H alpha absorption widths in G and K giant stars are consistent with a mean H alpha chromospheric optical depth of 50, while narrower widths in M stars indicate slightly lower opacities. It is proposed that differences in H alpha width between late-type giants of similar spectral type may be due, in part, to differences in their chromospheric thermal gradient, and associated H alpha opacity.

  7. Finite Element Modeling and Long Wave Infrared Imaging for Detection and Identification of Buried Objects

    DTIC Science & Technology

    surface temperature profile of a sandbox containing buried objects using a long-wave infrared camera. Images were recorded for several days under ambient...time of day . Best detection of buried objects corresponded to shallow depths for observed intervals where maxima/minima ambient temperatures coincided

  8. HCMM energy budget data as a model input for assessing regions of high potential groundwater pollution. [South Dakota

    NASA Technical Reports Server (NTRS)

    Moore, D. G. (Principal Investigator); Heilman, J. L.

    1980-01-01

    The author has identified the following significant results. Day thermal data were analyzed to assess depth to groundwater in the test site. HCMM apparent temperature was corrected for atmospheric effects using lake temperature of the Oahe Reservoir in central South Dakota. Soil surface temperatures were estimated using an equation developed for ground studies. A significant relationship was found between surface soil temperature and depth to groundwater, as well as between the surface soil-maximum air temperature differential and soil water content (% of field capacity) in the 0 cm and 4 cm layer of the profile. Land use for the data points consisted of row crops, small grains, stubble, and pasture.

  9. Modeling englacial radar attenuation at Siple Dome, West Antarctica, using ice chemistry and temperature data

    USGS Publications Warehouse

    MacGregor, J.A.; Winebrenner, D.P.; Conway, H.; Matsuoka, K.; Mayewski, P.A.; Clow, G.D.

    2007-01-01

    The radar reflectivity of an ice-sheet bed is a primary measurement for discriminating between thawed and frozen beds. Uncertainty in englacial radar attenuation and its spatial variation introduces corresponding uncertainty in estimates of basal reflectivity. Radar attenuation is proportional to ice conductivity, which depends on the concentrations of acid and sea-salt chloride and the temperature of the ice. We synthesize published conductivity measurements to specify an ice-conductivity model and find that some of the dielectric properties of ice at radar frequencies are not yet well constrained. Using depth profiles of ice-core chemistry and borehole temperature and an average of the experimental values for the dielectric properties, we calculate an attenuation rate profile for Siple Dome, West Antarctica. The depth-averaged modeled attenuation rate at Siple Dome (20.0 ?? 5.7 dB km-1) is somewhat lower than the value derived from radar profiles (25.3 ?? 1.1 dB km-1). Pending more experimental data on the dielectric properties of ice, we can match the modeled and radar-derived attenuation rates by an adjustment to the value for the pure ice conductivity that is within the range of reported values. Alternatively, using the pure ice dielectric properties derived from the most extensive single data set, the modeled depth-averaged attenuation rate is 24.0 ?? 2.2 dB km-1. This work shows how to calculate englacial radar attenuation using ice chemistry and temperature data and establishes a basis for mapping spatial variations in radar attenuation across an ice sheet. Copyright 2007 by the American Geophysical Union.

  10. A new temperature profiling probe for investigating groundwater-surface water interaction

    USGS Publications Warehouse

    Naranjo, Ramon C.; Robert Turcotte,

    2015-01-01

    Measuring vertically nested temperatures at the streambed interface poses practical challenges that are addressed here with a new discrete subsurface temperature profiling probe. We describe a new temperature probe and its application for heat as a tracer investigations to demonstrate the probe's utility. Accuracy and response time of temperature measurements made at 6 discrete depths in the probe were analyzed in the laboratory using temperature bath experiments. We find the temperature probe to be an accurate and robust instrument that allows for easily installation and long-term monitoring in highly variable environments. Because the probe is inexpensive and versatile, it is useful for many environmental applications that require temperature data collection for periods of several months in environments that are difficult to access or require minimal disturbance.

  11. Positron depth profiling of the structural and electronic structure transformations of hydrogenated Mg-based thin films

    NASA Astrophysics Data System (ADS)

    Eijt, S. W. H.; Kind, R.; Singh, S.; Schut, H.; Legerstee, W. J.; Hendrikx, R. W. A.; Svetchnikov, V. L.; Westerwaal, R. J.; Dam, B.

    2009-02-01

    We report positron depth-profiling studies on the hydrogen sorption behavior and phase evolution of Mg-based thin films. We show that the main changes in the depth profiles resulting from the hydrogenation to the respective metal hydrides are related to a clear broadening in the observed electron momentum densities in both Mg and Mg2Ni films. This shows that positron annihilation methods are capable of monitoring these metal-to-insulator transitions, which form the basis for important applications of these types of films in switchable mirror devices and hydrogen sensors in a depth-sensitive manner. Besides, some of the positrons trap at the boundaries of columnar grains in the otherwise nearly vacancy-free Mg films. The combination of positron annihilation and x-ray diffraction further shows that hydrogen loading at elevated temperatures, in the range of 480-600 K, leads to a clear Pd-Mg alloy formation of the Pd catalyst cap layer. At the highest temperatures, the hydrogenation induces a partial delamination of the ˜5 nm thin capping layer, as sensitively monitored by positron depth profiling of the fraction of ortho-positronium formed at interface with the cap layer. The delamination effectively blocks the hydrogen cycling. In Mg-Si bilayers, we investigated the reactivity upon hydrogen loading and heat treatments near 480 K, which shows that Mg2Si formation is fast relative to MgH2. The combination of positron depth profiling and transmission electron microscopy shows that hydrogenation promotes a complete conversion to Mg2Si for this destabilized metal hydride system, while a partially unreacted, Mg-rich amorphous prelayer remains on top of Mg2Si after a single heat treatment in an inert gas environment. Thin film studies indicate that the difficulty of rehydrogenation of Mg2Si is not primarily the result from slow hydrogen dissociation at surfaces, but is likely hindered by the presence of a barrier for removal of Mg from the readily formed Mg2Si.

  12. Arc Jet Test and Analysis of Asbestos Free Solid Rocket Motor Nozzle Dome Ablative Materials

    NASA Technical Reports Server (NTRS)

    Clayton, J. Louie

    2017-01-01

    Asbestos free solid motor internal insulation samples were recently tested at the MSFC Hyperthermal Arc Jet Facility. Objectives of the test were to gather data for solid rocket motor analog characterization of ablative and in-depth thermal performance of rubber materials subject to high enthalpy/pressure flow conditions. Tests were conducted over a range of convective heat fluxes for both inert and chemically reactive sub-sonic free stream gas flow. Active instrumentation included use of total calorimeters, in-depth thermocouples, and a surface pyrometer for in-situ surface temperature measurement. Post-test sample forensics involved determination of eroded depth, charred depth, total sample weight loss, and documentation of the general condition of the eroded profile. A complete Charring Material Ablator (CMA) style aero thermal analysis was conducted for the test matrix and results compared to the measured data. In general, comparisons were possible for a number of the cases and the results show a limited predictive ability to model accurately both the ablative response and the in-depth temperature profiles. Lessons learned and modeling recommendations are made regarding future testing and modeling improvements that will increase understanding of the basic chemistry/physics associated with the complicated material ablation process of rubber materials.

  13. Porosity and Mineralogy Control on the Thermal Properties of Sediments in Off-Shimokita Deep-Water Coal Bed Basin

    NASA Astrophysics Data System (ADS)

    Tanikawa, W.; Tadai, O.; Morita, S.; Lin, W.; Yamada, Y.; Sanada, Y.; Moe, K.; Kubo, Y.; Inagaki, F.

    2014-12-01

    Heat transport properties such as thermal conductivity, heat capacity, and thermal diffusivity are significant parameters that influence on geothermal process in sedimentary basins at depth. We measured the thermal properties of sediment core samples at off-Shimokita basin obtained from the IODP Expedition 337 and Expedition CK06-06 in D/V Chikyu shakedown cruise. Overall, thermal conductivity and thermal diffusivity increased with depth and heat capacity decreased with depth, although the data was highly scattered at the depth of approximately 2000 meters below sea floor, where coal-layers were formed. The increase of thermal conductivity is mainly explained by the porosity reduction of sediment by the consolidation during sedimentation. The highly variation of the thermal conductivity at the same core section is probably caused by the various lithological rocks formed at the same section. Coal shows the lowest thermal conductivity of 0.4 Wm-1K-1, and the calcite cemented sandstone/siltstone shows highest conductivity around 3 Wm-1K-1. The thermal diffusivity and heat capacity are influenced by the porosity and lithological contrast as well. The relationship between thermal conductivity and porosity in this site is well explained by the mixed-law model of Maxwell or geometric mean. One dimensional temperature-depth profile at Site C0020 in Expedition 337 estimated from measured physical properties and radiative heat production data shows regression of thermal gradient with depth. Surface heat flow value was evaluated as 29~30 mWm-2, and the value is consistent with the heat flow data near this site. Our results suggest that increase of thermal conductivity with depth significantly controls on temperature profile at depth of basin. If we assume constant thermal conductivity or constant geothermal gradient, we might overestimate temperature at depth, which might cause big error to predict the heat transport or hydrocarbon formation in deepwater sedimentary basins.

  14. A methodology for using borehole temperature-depth profiles under ambient, single and cross-borehole pumping conditions to estimate fracture hydraulic properties

    NASA Astrophysics Data System (ADS)

    Klepikova, Maria V.; Le Borgne, Tanguy; Bour, Olivier; Davy, Philippe

    2011-09-01

    SummaryTemperature profiles in the subsurface are known to be sensitive to groundwater flow. Here we show that they are also strongly related to vertical flow in the boreholes themselves. Based on a numerical model of flow and heat transfer at the borehole scale, we propose a method to invert temperature measurements to derive borehole flow velocities. This method is applied to an experimental site in fractured crystalline rocks. Vertical flow velocities deduced from the inversion of temperature measurements are compared with direct heat-pulse flowmeter measurements showing a good agreement over two orders of magnitudes. Applying this methodology under ambient, single and cross-borehole pumping conditions allows us to estimate fracture hydraulic head and local transmissivity, as well as inter-borehole fracture connectivity. Thus, these results provide new insights on how to include temperature profiles in inverse problems for estimating hydraulic fracture properties.

  15. Improving Representations of Near-Surface Permafrost and Soil Temperature Profiles in the Regional Arctic System Model (RASM)

    NASA Astrophysics Data System (ADS)

    Gergel, D. R.; Hamman, J.; Nijssen, B.

    2017-12-01

    Permafrost and seasonally frozen soils are a key characteristic of the terrestrial Arctic, and the fate of near-surface permafrost as a result of climate change is projected to have strong impacts on terrestrial biogeochemistry. The active layer thickness (ALT) is the layer of soil that freezes and thaws annually, and shifts in the depth of the ALT are projected to occur over large areas of the Arctic that are characterized by discontinuous permafrost. Faithful representation of permafrost in land models in climate models is a product of both soil dynamics and the coupling of air and soil temperatures. A common problem is a large bias in simulated ALT due to a model depth that is too shallow. Similarly, soil temperatures often show systematic biases, which lead to biases in air temperature due to poorly modeled air-soil temperature feedbacks in a coupled environment. In this study, we use the Regional Arctic System Model (RASM), a fully-coupled regional earth system model that is run at a 50-km land/atmosphere resolution over a pan-Arctic domain and uses the Variable Infiltration Capacity (VIC) model as its land model. To understand what modeling decisions are necessary to accurately represent near-surface permafrost and soil temperature profiles, we perform a large number of RASM simulations with prescribed atmospheric forcings (e.g. VIC in standalone mode in RASM) while varying the model soil depth, thickness of soil moisture layers, number of soil layers and the distribution of soil nodes. We compare modeled soil temperatures and ALT to observations from the Circumpolar Active Layer Monitoring (CALM) network. CALM observations include annual ALT observations as well as daily soil temperature measurements at three soil depths for three sites in Alaska. In the future, we will use our results to inform our modeling of permafrost dynamics in fully-coupled RASM simulations.

  16. Electrical conductivity of the Earth's mantle after one year of SWARM magnetic field measurements

    NASA Astrophysics Data System (ADS)

    Civet, François; Thebault, Erwan; Verhoeven, Olivier; Langlais, Benoit; Saturnino, Diana

    2015-04-01

    We present a global EM induction study using L1b Swarm satellite magnetic field measurements data down to a depth of 2000 km. Starting from raw measurements, we first derive a model for the main magnetic field, correct the data for a lithospheric field model, and further select the data to reduce the contributions of the ionospheric field. These computations allowed us to keep a full control on the data processes. We correct residual field from outliers and estimate the spherical harmonic coefficients of the transient field for periods between 2 and 256 days. We used full latitude range and all local times to keep a maximum amount of data. We perform a Bayesian inversion and construct a Markov chain during which model parameters are randomly updated at each iteration. We first consider regular layers of equal thickness and extra layers are added where conductivity contrast between successive layers exceed a threshold value. The mean and maximum likelihood of the electrical conductivity profile is then estimated from the probability density function. The obtained profile particularly shows a conductivity jump in the 600-700 km depth range, consistent with the olivine phase transition at 660 km depth. Our study is the first one to show such a conductivity increase in this depth range without any a priori informations on the internal strucutres. Assuming a pyrolitic mantle composition, this profile is interpreted in terms of temperature variations in the depth range where the probability density function is the narrowest. We finally obtained a temperature gradient in the lower mantle close to adiabatic.

  17. Assessing XCTD Fall Rate Errors using Concurrent XCTD and CTD Profiles in the Southern Ocean

    NASA Astrophysics Data System (ADS)

    Millar, J.; Gille, S. T.; Sprintall, J.; Frants, M.

    2010-12-01

    Refinements in the fall rate equation for XCTDs are not as well understood as those for XBTs, due in part to the paucity of concurrent and collocated XCTD and CTD profiles. During February and March 2010, the Diapycnal and Isopycnal Mixing Experiment in the Southern Ocean (DIMES) conducted 31 collocated 1000-meter XCTD and CTD casts in the Drake Passage. These XCTD/CTD profile pairs are closely matched in space and time, with a mean distance between casts of 1.19 km and a mean lag time of 39 minutes. The profile pairs are well suited to address the XCTD fall rate problem specifically in higher latitude waters, where existing fall rate corrections have rarely been assessed. Many of these XCTD/CTD profile pairs reveal an observable depth offset in measurements of both temperature and conductivity. Here, the nature and extent of this depth offset is evaluated.

  18. Test and Analysis of Solid Rocket Motor Nozzle Ablative Materials

    NASA Technical Reports Server (NTRS)

    Clayton, J. Louie

    2017-01-01

    Asbestos free solid motor internal insulation samples were tested at the MSFC Hyperthermal Facility. Objectives of the test were to gather data for analog characterization of ablative and in-depth thermal performance of rubber materials subject to high enthalpy/pressure flow conditions. Tests were conducted over a range of convective heat fluxes for both inert and chemically reactive sub-sonic free stream gas flow. Instrumentation included use of total calorimeters, thermocouples, and a surface pyrometer for surface temperature measurement. Post-test sample forensics involved measurement of eroded depth, charred depth, total sample weight loss, and documentation of the general condition of the eroded profile. A complete Charring Material Ablator (CMA) style aero-thermal analysis was conducted for the test matrix and results compared to the measured data. In general, comparisons were possible for a number of the cases and the results show a limited predictive ability to model accurately both the ablative response and the in-depth temperature profiles. Lessons learned and modeling recommendations are made regarding future testing and modeling improvements that will increase understanding of the basic chemistry/physics associated with the complicated material ablation process of rubber materials.

  19. Diurnal variations in optical depth at Mars: Observations and interpretations

    NASA Technical Reports Server (NTRS)

    Colburn, D. S.; Pollack, J. B.; Haberle, R. M.

    1988-01-01

    Viking lander camera images of the Sun were used to compute atmospheric optical depth at two sites over a period of 1 to 1/3 martian years. The complete set of 1044 optical depth determinations is presented in graphical and tabular form. Error estimates are presented in detail. Optical depths in the morning (AM) are generally larger than in the afternoon (PM). The AM-PM differences are ascribed to condensation of water vapor into atmospheric ice aerosols at night and their evaporation in midday. A smoothed time series of these differences shows several seasonal peaks. These are simulated using a one-dimensional radiative convective model which predicts martial atmospheric temperature profiles. A calculation combining these profiles with water vapor measurements from the Mars Atmospheric Water Detector is used to predict when the diurnal variations of water condensation should occur. The model reproduces a majority of the observed peaks and shows the factors influencing the process. Diurnal variation of condensation is shown to peak when the latitude and season combine to warm the atmosphere to the optimum temperature, cool enough to condense vapor at night and warm enough to cause evaporation at midday.

  20. Heat-flow studies in the northwest geysers geothermal field, California

    USGS Publications Warehouse

    Williams, Colin F.; Galanis, S. Peter; Moses, Thomas H.; Grubb, Frederick V.; ,

    1993-01-01

    Temperature and thermal conductivity data were acquired from 3 idle production wells in the Northwest Geysers. Heat-flow profiles derived from data recorded in the caprock which overlies the steam reservoir reveal a decrease of heat flow with depth in 2 of the 3 wells. These observations contradict the generally accepted theory that conductive heat flow is constant with depth within The Geysers caprock. There are several possible explanations for this, but the available data suggest that these profiles reflect a local recession or cooling of the reservoir top within the past 5000 to 10000 years.

  1. A summary report on the search for current technologies and developers to develop depth profiling/physical parameter end effectors

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Nguyen, Q.H.

    1994-09-12

    This report documents the search strategies and results for available technologies and developers to develop tank waste depth profiling/physical parameter sensors. Sources searched include worldwide research reports, technical papers, journals, private industries, and work at Westinghouse Hanford Company (WHC) at Richland site. Tank waste physical parameters of interest are: abrasiveness, compressive strength, corrosiveness, density, pH, particle size/shape, porosity, radiation, settling velocity, shear strength, shear wave velocity, tensile strength, temperature, viscosity, and viscoelasticity. A list of related articles or sources for each physical parameters is provided.

  2. Using Heat as a Tracer to Estimate Saline Groundwater Fluxes from the Deep Aquifer System to the Shallow Aquifers and the Rio Grande in the Mesilla Basin, New Mexico, USA

    NASA Astrophysics Data System (ADS)

    Pepin, J. D.; Robertson, A.; Ferguson, C.; Burns, E. R.

    2017-12-01

    Heat is used as a tracer to estimate vertical groundwater flow and associated saline fluxes from deep (greater than 1 km) parts of the Mesilla Basin regional aquifer to the Rio Grande. Profiles of temperature with depth below ground surface are used to locate groundwater upflow zones and to estimate associated salinity fluxes. The results of this study will inform understanding of the impact of deep saline groundwater on regional water supplies. The Mesilla Basin in southern New Mexico, Texas, and Chihuahua, Mexico was designated by the U.S. as a priority transboundary aquifer in part because of the presence of the Rio Grande within the basin. Declining water levels, deteriorating water quality in both the aquifer and the river, and increasing use of water resources on both sides of the international border raise concerns about the sustainability of regional water supplies. The Rio Grande chloride concentration increases by about 130% (120 ppm to 280 ppm) as the river traverses the Mesilla Basin. Previous research attributed this reduction in water quality to the upwelling of deep sedimentary brines and geothermal waters within the basin. However, the spatial distribution of these upflow zones and their groundwater flow rates are poorly understood. Temperature profiles from 374 existing boreholes within the Mesilla Basin indicate that temperature-profile shape is affected by heat advection in the basin. Three distinct geothermal upflow zones were identified along regional fault zones in the study area based on the temperature profiles. Groundwater in these zones is considered thermal, having temperatures greater than 50°C at depths of less than 200 m. Identification of upflow-zone profiles combines analysis of temperature profiles, lithologic records, well-completion data, and profile derivatives. The Bredehoeft and Papadopulos (1965) one-dimensional heat-transport analytical solution will be applied to upflow-zone profiles to estimate the corresponding vertical groundwater flow rates. Temperature, heat flow, and salinity maps will be constructed to approximate the areal extents of identified upflow zones. These areal estimates will then be combined with the 1D vertical groundwater flow calculations and salinity data to quantify volumetric salinity fluxes to the shallow aquifer system and Rio Grande.

  3. Quantifying the variability of snowpack properties and processes in a small-forested catchment representative of the boreal zone

    NASA Astrophysics Data System (ADS)

    Parajuli, A.; Nadeau, D.; Anctil, F.; Parent, A. C.; Bouchard, B.; Jutras, S.

    2017-12-01

    In snow-fed catchments, it is crucial to monitor and to model snow water equivalent (SWE), particularly to simulate the melt water runoff. However, the distribution of SWE can be highly heterogeneous, particularly within forested environments, mainly because of the large variability in snow depths. Although the boreal forest is the dominant land cover in Canada and in a few other northern countries, very few studies have quantified the spatiotemporal variability of snow depths and snowpack dynamics within this biome. The objective of this paper is to fill this research gap, through a detailed monitoring of snowpack dynamics at nine locations within a 3.57 km2 experimental forested catchment in southern Quebec, Canada (47°N, 71°W). The catchment receives 6 m of snow annually on average and is predominantly covered with balsam fir stand with some traces of spruce and white birch. In this study, we used a network of nine so-called `snow profiling stations', providing automated snow depth and snowpack temperature profile measurements, as well as three contrasting sites (juvenile, sapling and open areas) where sublimation rates were directly measured with flux towers. In addition, a total of 1401 manual snow samples supported by 20 snow pits measurements were collected throughout the winter of 2017. This paper presents some preliminary analyses of this unique dataset. Simple empirical relations relying SWE with easy-to-determine proxies, such as snow depths and snow temperature, are tested. Then, binary regression trees and multiple regression analysis are used to model SWE using topographic characteristics (slope, aspect, elevation), forest features (tree height, tree diameter, forest density and gap fraction) and meteorological forcing (solar radiation, wind speed, snow-pack temperature profile, air temperature, humidity). An analysis of sublimation rates comparing open area, saplings and juvenile forest is also presented in this paper.

  4. Large Area and Depth-Profiling Dislocation Imaging and Strain Analysis in Si/SiGe/Si Heterostructures

    DTIC Science & Technology

    2014-01-01

    of the defect trapping state ( Higgs & Kittler, 2441994), the temperature dependence of c is determined by the 245temperature dependence of lifetime...Lett 65(22), 2804–2806. 397KITTLER, M., ULHAQBOUILLET, C. & HIGGS , V. (1995). Influence of 398copper contamination on recombination activity of misfit

  5. Reconstruction of the thermal environment evolution in urban areas from underground temperature distribution.

    PubMed

    Yamano, Makoto; Goto, Shusaku; Miyakoshi, Akinobu; Hamamoto, Hideki; Lubis, Rachmat Fajar; Monyrath, Vuthy; Taniguchi, Makoto

    2009-04-15

    It is possible to estimate the ground surface temperature (GST) history of the past several hundred years from temperature profiles measured in boreholes because the temporal variation in GST propagates into the subsurface by thermal diffusion. This "geothermal method" of reconstructing GST histories can be applied to studies of thermal environment evolution in urban areas, including the development of "heat islands." Temperatures in boreholes were logged at 102 sites in Bangkok, Jakarta, Taipei, Seoul and their surrounding areas in 2004 to 2007. The effects of recent surface warming can be recognized in the shapes of most of the obtained temperature profiles. The preliminary results of reconstruction of GST histories through inversion analysis show that GST increased significantly in the last century. Existing temperature profile data for the areas in and around Tokyo and Osaka can also be used to reconstruct GST histories. Because most of these cities are located on alluvial plains in relatively humid areas, it is necessary to use a model with groundwater flow and a layered subsurface structure for reconstruction analysis. Long-term records of subsurface temperatures at multiple depths may demonstrate how the GST variation propagates downward through formations. Time series data provide information on the mechanism of heat transfer (conduction or advection) and the thermal diffusivity. Long-term temperature monitoring has been carried out in a borehole located on the coast of Lake Biwa, Japan. Temperatures at 30 and 40 m below the ground surface were measured for 4 years and 2 years, respectively, with a resolution of 1 mK. The obtained records indicate steady increases at both depths with different rates, which is probably the result of some recent thermal event(s) near the surface. Borehole temperatures have also been monitored at selected sites in Bangkok, Jakarta, and Taiwan.

  6. Detection of Intermediate Mediterranean Waters in the Atlantic Ocean by ARGO Floats Data

    NASA Astrophysics Data System (ADS)

    Filyushkin, B. N.; Lebedev, K. V.; Kozhelupova, N. G.

    2017-11-01

    Peculiarities of the spatial distribution of intermediate Mediterranean waters (MW), which are the main source to maintain the heat and salt budgets at depths of 600-1500 m in the Atlantic Ocean, have been studied using the ARGO floats measurements database. About 75000 temperature and salinity profiles recorded by 900 ARGO floats in 2005-2014 in the Atlantic Ocean for latitudes from 20° to 50° N were used. To process these data, we used the ARGO-Based Model for Investigation of the Global Ocean (AMIGO). This technique allowed us for the first time to obtain a complete set of oceanographic characteristics up to a depth of 2000 m for different time averaging intervals (month, season, years). Joint analysis of the temperature, salinity, and velocity distributions at 700-1000 m depths made it possible to revise the distribution of MW and their penetration into the western part of the ocean across the Mid-Atlantic Ridge (MAR). It is shown that at depths of 700 and 1000 m, the Mid-Atlantic Ridge is a barrier to advective propagation of salty waters (>35.5 PSU) to the west and is transparent to fragments of destroyed intrathermocline lenses (ITL) with lower salinity (<35.4 PSU). In the Atlantic region, from 20° to 35° N and from 30° to 70° W, individual lens profiles with an anomalous salinity distribution were sought using ARGO measurements to detect ITL and its separate fragments. About 24 000 measurements from 370 ARGO floats were analyzed, and only about 3% of them showed weak salinity anomalies at 800-1200 m depths. No ITL were found from these observations. Analysis of long-term drifting of individual floats recording temperature and salinity profiles with anomalous layers made it possible to study the nature of MW transport through the MAR.

  7. Impact of oxygen diffusion on superconductivity in YBa2Cu3O7 -δ thin films studied by positron annihilation spectroscopy

    NASA Astrophysics Data System (ADS)

    Reiner, M.; Gigl, T.; Jany, R.; Hammerl, G.; Hugenschmidt, C.

    2018-04-01

    The oxygen deficiency δ in YBa2Cu3O7 -δ (YBCO) plays a crucial role for affecting high-temperature superconductivity. We apply (coincident) Doppler broadening spectroscopy of the electron-positron annihilation line to study in situ the temperature dependence of the oxygen concentration and its depth profile in single crystalline YBCO film grown on SrTiO3 (STO) substrates. The oxygen diffusion during tempering is found to lead to a distinct depth dependence of δ , which is not accessible using x-ray diffraction. A steady state reached within a few minutes is defined by both, the oxygen exchange at the surface and at the interface to the STO substrate. Moreover, we reveal the depth-dependent critical temperature Tc in the as prepared and tempered YBCO film.

  8. A one-dimensional Fickian model to predict the Ga depth profiles in three-stage Cu(In,Ga)Se{sub 2}

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Rodriguez-Alvarez, H., E-mail: humberto.rodriguez@helmholtz-berlin.de; Helmholtz-Zentrum Berlin, Hahn-Meitner Platz 1, 14109 Berlin; Mainz, R.

    2014-05-28

    We present a one-dimensional Fickian model that predicts the formation of a double Ga gradient during the fabrication of Cu(In,Ga)Se{sub 2} thin films by three-stage thermal co-evaporation. The model is based on chemical reaction equations, structural data, and effective Ga diffusivities. In the model, the Cu(In,Ga)Se{sub 2} surface is depleted from Ga during the deposition of Cu-Se in the second deposition stage, leading to an accumulation of Ga near the back contact. During the third deposition stage, where In-Ga-Se is deposited at the surface, the atomic fluxes within the growing layer are inverted. This results in the formation of amore » double Ga gradient within the Cu(In,Ga)Se{sub 2} layer and reproduces experimentally observed Ga distributions. The final shape of the Ga depth profile strongly depends on the temperatures, times and deposition rates used. The model is used to evaluate possible paths to flatten the marked Ga depth profile that is obtained when depositing at low substrate temperatures. We conclude that inserting Ga during the second deposition stage is an effective way to achieve this.« less

  9. Upper ocean moored current and density profiler applied to winter conditions near Bermuda

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Eriksen, C.C.; Dahlen, J.M.; Shillingford, J.T. Jr.

    1982-09-20

    A new moored instrument which makes repeated high vertical resolution profiles of current, temperature, and salinity in the upper ocean over extended periods was used to observe midwinter conditions near Bermuda. The operation and performance of the instrument, called the profiling current meter (PCM), in the surface wave environment of winter storms is reported here. The PCM profiles along the upper portion of a slightly subsurface mooring by adjusting its buoyancy under computer control. This design decouples the instrument from vertical motions of the mooring induced by surface waves, so that its electromagnetic current sensor operates in a favorable mean-to-fluctuatingmore » flow regime. Current, temperature, and electrical conductivity are (vector) averaged into contiguous preselected bins several meters wide over the possible profile range of 20- to 250-m depth. The PCM is capable of collecting 1000--4000 profiles in a 6- to 12-month period, depending on depth range and ambient currents. A variety of baroclinic motions are evident in the Bermuda observations. Upper ocean manifestations of both Kelvin and superinertial island-trapped waves dominate longshore currents. Vertical coherence of onshore current and temperature suggest that internal wave vertical wave number energy distribution is independent of frequency but modified by island bathymetry. Kinetic energy in shear integrated over a 115.6-m-thick layer in the upper ocean is limited to values less than or equal to the potential energy required to mix the existing stratification. Mixing events occur when kinetic energy associated with shear drives the bulk Richardson number (defined by the ratio of energy integrals over the range profiles) to unity, where it remains while shear and stratification disappear together.« less

  10. Water Plume Temperature Measurements by an Unmanned Aerial System (UAS)

    PubMed Central

    DeMario, Anthony; Lopez, Pete; Plewka, Eli; Wix, Ryan; Xia, Hai; Zamora, Emily; Gessler, Dan; Yalin, Azer P.

    2017-01-01

    We report on the development and testing of a proof of principle water temperature measurement system deployed on an unmanned aerial system (UAS), for field measurements of thermal discharges into water. The primary elements of the system include a quad-copter UAS to which has been integrated, for the first time, both a thermal imaging infrared (IR) camera and an immersible probe that can be dipped below the water surface to obtain vertical water temperature profiles. The IR camera is used to take images of the overall water surface to geo-locate the plume, while the immersible probe provides quantitative temperature depth profiles at specific locations. The full system has been tested including the navigation of the UAS, its ability to safely carry the sensor payload, and the performance of both the IR camera and the temperature probe. Finally, the UAS sensor system was successfully deployed in a pilot field study at a coal burning power plant, and obtained images and temperature profiles of the thermal effluent. PMID:28178215

  11. Water Plume Temperature Measurements by an Unmanned Aerial System (UAS).

    PubMed

    DeMario, Anthony; Lopez, Pete; Plewka, Eli; Wix, Ryan; Xia, Hai; Zamora, Emily; Gessler, Dan; Yalin, Azer P

    2017-02-07

    We report on the development and testing of a proof of principle water temperature measurement system deployed on an unmanned aerial system (UAS), for field measurements of thermal discharges into water. The primary elements of the system include a quad-copter UAS to which has been integrated, for the first time, both a thermal imaging infrared (IR) camera and an immersible probe that can be dipped below the water surface to obtain vertical water temperature profiles. The IR camera is used to take images of the overall water surface to geo-locate the plume, while the immersible probe provides quantitative temperature depth profiles at specific locations. The full system has been tested including the navigation of the UAS, its ability to safely carry the sensor payload, and the performance of both the IR camera and the temperature probe. Finally, the UAS sensor system was successfully deployed in a pilot field study at a coal burning power plant, and obtained images and temperature profiles of the thermal effluent.

  12. Inorganic material profiling using Arn+ cluster: Can we achieve high quality profiles?

    NASA Astrophysics Data System (ADS)

    Conard, T.; Fleischmann, C.; Havelund, R.; Franquet, A.; Poleunis, C.; Delcorte, A.; Vandervorst, W.

    2018-06-01

    Retrieving molecular information by sputtering of organic systems has been concretized in the last years due to the introduction of sputtering by large gas clusters which drastically eliminated the compound degradation during the analysis and has led to strong improvements in depth resolution. Rapidly however, a limitation was observed for heterogeneous systems where inorganic layers or structures needed to be profiled concurrently. As opposed to organic material, erosion of the inorganic layer appears very difficult and prone to many artefacts. To shed some light on these problems we investigated a simple system consisting of aluminum delta layer(s) buried in a silicon matrix in order to define the most favorable beam conditions for practical analysis. We show that counterintuitive to the small energy/atom used and unlike monoatomic ion sputtering, the information depth obtained with large cluster ions is typically very large (∼10 nm) and that this can be caused both by a large roughness development at early stages of the sputtering process and by a large mixing zone. As a consequence, a large deformation of the Al intensity profile is observed. Using sample rotation during profiling significantly improves the depth resolution while sample temperature has no significant effect. The determining parameter for high depth resolution still remains the total energy of the cluster instead of the energy per atom in the cluster.

  13. Species Profiles. Life Histories and Environmental Requirements of Coastal Fishes and Invertebrates (Pacific Northwest). Dungeness Crab.

    DTIC Science & Technology

    1986-08-01

    variety of factors crab eggs has been linked to increased including depth, latitude, tempera- egg mortality because of mechanical ture, salinity and...time. crabs seem less dependent on epibenthic cover and can be found over more exposed substrates. Most crabs Temperature- Salinity Interactions remain...13 Salinity . .. ....... ........................................ 14 Temperature- Salinity Interactions. .. .... ....... ....... 14

  14. Lethal soil temperatures during burning of masticated forest residues

    Treesearch

    Matt D. Busse; Ken R. Hubbert; Gary O. Fiddler; Carol J. Shestak; Robert F. Powers

    2005-01-01

    Mastication of woody shrubs is used increasingly as a management option to reduce fire risk at the wildland-urban interface. Whether the resulting mulch layer leads to extreme soil heating, if burned, is unknown. We measured temperature profiles in a clay loam soil during burning of Arctostaphylos residues. Four mulch depths were burned (0, 2.5, 7.5...

  15. The influence of agricultural management on soil's CO2 regime in semi-arid and arid regions

    NASA Astrophysics Data System (ADS)

    Eshel, G.; Lifshithz, D.; Sternberg, M.; Ben-Dor, E.; Bonfile, D. J.; Arad, B.; Mingelgrin, U.; Fine, P.; Levy, G. J.

    2008-12-01

    Two of the more important parameters which may help us better evaluate the impact of agricultural practices on the global carbon cycle are the in-situ soil pCO2 profile and the corresponding CO2 fluxes to the atmosphere. In an ongoing study, we monitored the pCO2 to a depth of 5 m in two adjacent irrigated Avocado orchards in the coastal plain of Israel (semi-arid region), and to a depth of 2 m in a semi- arid rain-fed and a arid rain-fed wheat fields in southern Israel. The soil pCO2 profiles and CO2 fluxes measurements were supplemented by measurements of soil moisture and temperature. The results showed differences in the CO2 profiles (both in the depth of the highest concentration and its absolute values) and the CO2 fluxes between the orchards and the wheat fields as well as along the year. In the irrigated Avocado orchards pCO2 values were in the range of 1.5 kPa at a depth of 0.5 m up to 8 kPa at depths of 3-5 m (even though Avocado trees are characterized by shallow roots). Such levels could affect reactions (e.g., enhancement of inorganic carbon dissolution) that may take place in the soil and some of its chemical properties (e.g., pH). As expected, soil pCO2 was affected by soil moisture and temperature, and the distance from the trees. Maximum soil respiration was observed during the summer when the orchards are under irrigation. In the wheat fields pCO2 level ranged from 0.2- 0.6 kPa at a depth of 0.2 m to 0.2-1 kPa at depths of 1-1.5 m (in arid and semiarid respectively). These pCO2 levels were much lower than those obtained in the irrigated orchards and seemed to depend on the wheat growing cycle (high concentration were noted at depth of 1-1.5 m close to the end of grain filling) and precipitation gradient (arid vs. semiarid). Since CO2 fluxes are directly affected by the pCO2 profile and soil moister and temperature the CO2 fluxes from the wheat fields were much lower (0.02- 0.2 ml min-1 m-2) compared to those obtained from the Avocado orchards (2-7 ml min-1 m-2). Our results clearly demonstrate the large variability in soil pCO2 concentration and flux to the atmosphere, and its dependence on the soil moisture regime (annual precipitation and irrigation) and type of cropping (orchard vs. field crop).

  16. Electrical conductivity of the Earth's mantle from the first Swarm magnetic field measurements

    NASA Astrophysics Data System (ADS)

    Civet, F.; Thébault, E.; Verhoeven, O.; Langlais, B.; Saturnino, D.

    2015-05-01

    We present a 1-D electrical conductivity profile of the Earth's mantle down to 2000 km derived from L1b Swarm satellite magnetic field measurements from November 2013 to September 2014. We first derive a model for the main magnetic field, correct the data for a lithospheric field model, and additionally select the data to reduce the contributions of the ionospheric field. We then model the primary and induced magnetospheric fields for periods between 2 and 256 days and perform a Bayesian inversion to obtain the probability density function for the electrical conductivity as function of depth. The conductivity increases by 3 orders of magnitude in the 400-900 km depth range. Assuming a pyrolitic mantle composition, this profile is interpreted in terms of temperature variations leading to a temperature gradient in the lower mantle that is close to adiabatic.

  17. Evaluating the Ocean Component of the US Navy Earth System Model

    NASA Astrophysics Data System (ADS)

    Zamudio, L.

    2017-12-01

    Ocean currents, temperature, and salinity observations are used to evaluate the ocean component of the US Navy Earth System Model. The ocean and atmosphere components of the system are an eddy-resolving (1/12.5° equatorial resolution) version of the HYbrid Coordinate Ocean Model (HYCOM), and a T359L50 version of the NAVy Global Environmental Model (NAVGEM), respectively. The system was integrated in hindcast mode and the ocean results are compared against unassimilated observations, a stand-alone version of HYCOM, and the Generalized Digital Environment Model ocean climatology. The different observation types used in the system evaluation are: drifting buoys, temperature profiles, salinity profiles, and acoustical proxies (mixed layer depth, sonic layer depth, below layer gradient, and acoustical trapping). To evaluate the system's performance in each different metric, a scorecard is used to translate the system's errors into scores, which provide an indication of the system's skill in both space and time.

  18. DOE Office of Scientific and Technical Information (OSTI.GOV)

    Tabbagh, A.; Lardy, M.

    Temperature measurements on shallow vertical profiles undertaken on Matthews and Hunter volcanoes of the New Hebrides arc (SW Pacific) demonstrate the absence of both unsteady and steady conductive abnormal flux at the location of the studied profiles. The reasons for this absence are explained in terms of limits in depth or magnitude for possible sources of heat inside the volcanoes. It implies that the magma chamber is of rather limited extent. This type of flux measurement has a low cost and it will be possible to implant a series of such temperature profiles on an edifice in order to obtainmore » a map of the flux that could be widely used for the location of heat sources.« less

  19. Stability of Zircon and its Isotopic Ratios in High-Temperature Fluids: Long-Term (4 months) Isotope Exchange Experiment at 850 °C and 50 MPa

    NASA Astrophysics Data System (ADS)

    Bindeman, Ilya N.; Schmitt, Axel K.; Lundstrom, Craig C.; Hervig, Richard L.

    2018-05-01

    Stability of zircon in hydrothermal fluids and vanishingly slow rates of diffusion identify zircon as a reliable recorder of its formation conditions in recent and ancient rocks. Debate, however, persists on how rapidly oxygen and key trace elements (e.g., Li, B, Pb) diffuse when zircon is exposed to hot aqueous fluids. Here, we report results of a nano- to micrometer-scale investigation of isotopic exchange using natural zircon from Mesa Falls Tuff (Yellowstone) treated with quartz-saturated, isotopically (18O, D, 7Li, and 11B) labeled water with a nominal δ18O value of +450‰ over 4 months at 850°C and 50 MPa. Frontside (crystal rim inwards) δ18O depth profiling of zircon by magnetic sector SIMS shows initially high but decreasing 18O/16O over a 130 nm non-Fickian profile, with a decay length comparable to the signal from surficial Au coating deposited onto zircon. In contrast, backside (crystal interior outwards) depth profiling on a 2-3 µm thick wafer cut and thinned from treated zircon by focused ion beam (FIB) milling lacks any significant increase in 18O/16O during penetration of the original surface layer. Near-surface time-of-flight (TOF-SIMS) frontside profiles of uncoated zircon from 4-month and 1-day-long experiments as well as untreated zircons display similar enrichments of 18O over a distance of 20 nm. All frontside 18O profiles are here interpreted as transient surface signals from nm-thick surface enrichment or contamination unrelated to diffusion. Likewise, frontside depth profiling of H, Li, and B isotopes are similar for long- and short-duration experiments. Additionally, surface U-Pb dating of zircon from the 4-month experiment returned U-Pb ages by depth profiling with 1 µm penetration that were identical to untreated samples. Frontside and backside depth-profiling thus demonstrate that diffusive 18O enrichment in the presence of H2O is much slower than predicted from experiments in Watson and Cherniak (1997). Instead, intracrystalline exchange of oxygen between fluid and zircon in wet experimental conditions with excess silica occurred over length-scales equivalent to those predicted for dry diffusion. Oxygen diffusion coefficients even under wet conditions and elevated temperatures (850 °C) are <1-3×10-23 m2/sec, underscoring a virtual lack of oxygen diffusion and an outstanding survivability of zircons

  20. Influence of the Sampling Rate and Noise Characteristics on Prediction of the Maximal Safe Laser Exposure in Human Skin Using Pulsed Photothermal Radiometry

    NASA Astrophysics Data System (ADS)

    Vidovič, L.; Milanič, M.; Majaron, B.

    2013-09-01

    Pulsed photothermal radiometry (PPTR) allows for noninvasive determination of the laser-induced temperature depth profile in strongly scattering samples, including human skin. In a recent experimental study, we have demonstrated that such information can be used to derive rather accurate predictions of the maximal safe radiant exposure on an individual patient basis. This has important implications for efficacy and safety of several laser applications in dermatology and aesthetic surgery, which are often compromised by risk of adverse side effects (e.g., scarring, and dyspigmentation) resulting from nonselective absorption of strong laser light in epidermal melanin. In this study, the differences between the individual maximal safe radiant exposure values as predicted from PPTR temperature depth profiling performed using a commercial mid-IR thermal camera (as used to acquire the original patient data) and our customized PPTR setup are analyzed. To this end, the latter has been used to acquire 17 PPTR records from three healthy volunteers, using 1 ms laser irradiation at 532 nm and a signal sampling rate of 20 000 . The laser-induced temperature profiles are reconstructed first from the intact PPTR signals, and then by binning the data to imitate the lower sampling rate of the IR camera (1000 fps). Using either the initial temperature profile in a dedicated numerical model of heat transfer or protein denaturation dynamics, the predicted levels of epidermal thermal damage and the corresponding are compared. A similar analysis is performed also with regard to the differences between noise characteristics of the two PPTR setups.

  1. Observational Evidence of Changes in Soil Temperatures across Eurasian Continent

    NASA Astrophysics Data System (ADS)

    Zhang, T.

    2015-12-01

    Soil temperature is one of the key climate change indicators and plays an important role in plant growth, agriculture, carbon cycle and ecosystems as a whole. In this study, variability and changes in ground surface and soil temperatures up to 3.20 m were investigated based on data and information obtained from hydrometeorological stations across Eurasian continent since the early 1950s. Ground surface and soil temperatures were measured daily by using the same standard method and by the trained professionals across Eurasian continent, which makes the dataset unique and comparable over a large study region. Using the daily soil temperature profiles, soil seasonal freeze depth was also obtained through linear interpolation. Preliminary results show that soil temperatures at various depths have increased dramatically, almost twice as much as air temperature increase over the same period. Regionally, soil temperature increase was more dramatically in high northern latitudes than mid/lower latitude regions. Air temperature changes alone may not be able to fully explain the magnitude of changes in soil temperatures. Further study indicates that snow cover establishment started later in autumn and snow cover disappearance occurred earlier in spring, while winter snow depth became thicker with a decreasing trend of snow density. Changes in snow cover conditions may play an important role in changes of soil temperatures over the Eurasian continent.

  2. Estimating the effect of shallow groundwater on diurnal heat transport in a vadose zone

    NASA Astrophysics Data System (ADS)

    Jiang, Jianmei; Zhao, Lin; Zhai, Zhe

    2016-09-01

    The influence of shallow groundwater on the diurnal heat transport of the soil profile was analyzed using a soil sensor automatic monitoring system that continuously measures temperature and water content of soil profiles to simulate heat transport based on the Philip and de Vries (PDV) model. Three experiments were conducted to measure soil properties at depths of 5 cm, 10 cm, 20 cm, and 30 cm when groundwater tables reached 10 cm, 30 cm, and 60 cm (Experiments I, II, and III). Results show that both the soil temperature near shallow groundwater and the soil water content were effectively simulated by the PDV model. The root mean square errors of the temperature at depths of 5 cm, 10 cm, and 20 cm were 1.018°C, 0.909°C, and 0.255°C, respectively. The total heat flux generated the convergent and divergent planes in space-time fields with valley values of-161.5W•m-2 at 7:30 and-234.6W•m-2 at 11:10 in Experiments II and III, respectively. The diurnal heat transport of the saturated soil occurred in five stages, while that of saturated-unsaturated and unsaturated soil profiles occurred in four stages because high moisture content led to high thermal conductivity, which hastened the heat transport.

  3. Heat transport in the Red Lake Bog, Glacial Lake Agassiz Peatlands

    USGS Publications Warehouse

    McKenzie, J.M.; Siegel, D.I.; Rosenberry, D.O.; Glaser, P.H.; Voss, C.I.

    2007-01-01

    We report the results of an investigation on the processes controlling heat transport in peat under a large bog in the Glacial Lake Agassiz Peatlands. For 2 years, starting in July 1998, we recorded temperature at 12 depth intervals from 0 to 400 cm within a vertical peat profile at the crest of the bog at sub-daily intervals. We also recorded air temperature 1 m above the peat surface. We calculate a peat thermal conductivity of 0.5 W m-1 ??C-1 and model vertical heat transport through the peat using the SUTRA model. The model was calibrated to the first year of data, and then evaluated against the second year of collected heat data. The model results suggest that advective pore-water flow is not necessary to transport heat within the peat profile and most of the heat is transferred by thermal conduction alone in these waterlogged soils. In the spring season, a zero-curtain effect controls the transport of heat through shallow depths of the peat. Changes in local climate and the resulting changes in thermal transport still may cause non-linear feedbacks in methane emissions related to the generation of methane deeper within the peat profile as regional temperatures increase. Copyright ?? 2006 John Wiley & Sons, Ltd.

  4. Climate change for the last 1,000 years inferred from borehole temperatures

    NASA Astrophysics Data System (ADS)

    Kitaoka, K.; Arimoto, H.; Hamamoto, H.; Taniguchi, M.; Takeuchi, T.

    2013-12-01

    Subsurface temperatures are an archive of temperature changes occurred at the ground surface in the recent past (Lachenbruch and Marshall, 1986; Pollack, 1993). In order to investigate the local surface temperature histories in Osaka Plane, Japan, we observed subsurface temperatures in existing boreholes, using a thermometer logger. Many temperature-depth profiles within 200 m depth from the ground surface have been obtained, but they show considerable variability. The geological formations in the area consist of horizontally stratified sedimentary layers of about 1,000 m in thickness overlaid on bedrock of granite. There exists a vertical disordered structure in the formations, which may be relating to an active fault (Uemachi fault) in the bedrock (Takemura, et al, 2013). It is considered that groundwater in the horizontal layers cannot move vertically, but can move vertically along the vertical disordered zone. Various temperature profiles might be related to occurrence of vertical groundwater flow in the zone. Analytical models of subsurface temperature which include heat conduction and convection due to vertical groundwater flow in the zone have been constructed under the boundary conditions of prescribing time dependent surface temperature and uniform geothermal flux from greater depths. To solve as one-dimensional problem, heat transfer between the vertical zone and the surrounding medium of no groundwater flow is assumed. Prescribing surface temperatures were given as exponential and periodic functions of the time. Climate change can be considered to comprise both natural and artificial changes. Artificial change, which occurs by the increasing combustion of fossil fuels, is considered roughly to be an exponential increase of the ground surface temperature during the last 150 years. Natural change, which can correlate to solar activity (Lassen and Friis-Christensen, 1995), is assumed roughly to be periodic with the period of about 1200 y at the minimum time of 1620 AD for the last 2,000 years, based on the proxy data in literature (Kitagawa, 1995; Moberg, et al, 2005). Analytical solutions have been obtained by applying a superimpose method. Optimum values of parameters included in the model have been obtained by fitting the solutions to the data of temperature-depth profiles by a least-square method. As a result, the amplitude of natural oscillation in the area is about 0.8 degree in average, which is in agreement with the result of tree ring analysis of Yakushima cedar (Kitagawa, 1995). Greater upward groundwater flow rates (up to 1.0 m/y, Darcy flux) are seen along the vertical disordered structure. However, the increasing rate of ground surface temperature is greater than that in atmospheric temperature during the last 140 years at Osaka Meteorological Observatory, Japan Meteorological Agency. The high increasing rate of the ground surface temperature suggests that the change in atmospheric temperature is influenced by the change in long wave radiation from the ground surface.

  5. Use of temperature profiles beneath streams to determine rates of vertical ground-water flow and vertical hydraulic conductivity

    USGS Publications Warehouse

    Lapham, Wayne W.

    1989-01-01

    The use of temperature profiles beneath streams to determine rates of vertical ground-water flow and effective vertical hydraulic conductivity of sediments was evaluated at three field sites by use of a model that numerically solves the partial differential equation governing simultaneous vertical flow of fluid and heat in the Earth. The field sites are located in Hardwick and New Braintree, Mass., and in Dover, N.J. In New England, stream temperature varies from about 0 to 25 ?C (degrees Celsius) during the year. This stream-temperature fluctuation causes ground-water temperatures beneath streams to fluctuate by more than 0.1 ?C during a year to a depth of about 35 ft (feet) in fine-grained sediments and to a depth of about 50 ft in coarse-grained sediments, if ground-water velocity is 0 ft/d (foot per day). Upward flow decreases the depth affected by stream-temperature fluctuation, and downward flow increases the depth. At the site in Hardwick, Mass., ground-water flow was upward at a rate of less than 0.01 ft/d. The maximum effective vertical hydraulic conductivity of the sediments underlying this site is 0.1 ft/d. Ground-water velocities determined at three locations at the site in New Braintree, Mass., where ground water discharges naturally from the underlying aquifer to the Ware River, ranged from 0.10 to 0.20 ft/d upward. The effective vertical hydraulic conductivity of the sediments underlying this site ranged from 2.4 to 17.1 ft/d. Ground-water velocities determined at three locations at the Dover, N.J., site, where infiltration from the Rockaway River into the underlying sediments occurs because of pumping, were 1.5 ft/d downward. The effective vertical hydraulic conductivity of the sediments underlying this site ranged from 2.2 to 2.5 ft/d. Independent estimates of velocity at two of the three sites are in general agreement with the velocities determined using temperature profiles. The estimates of velocities and conductivities derived from the temperature measurements generally fall within the ranges of expected rates of flow in, and conductivities of, the sediments encountered at the test sites. Application of the method at the three test sites demonstrates the feasibility of using the method to determine the rate of ground-water flow between a stream and underlying sediments and the effective vertical hydraulic conductivity of the sediments.

  6. Measuring vertical oxygen profiles in the hyporheic zone using planar optodes

    NASA Astrophysics Data System (ADS)

    Vieweg, M.; Fleckenstein, J. H.; Schmidt, C.

    2012-04-01

    On of the key parameters, controlling biogeochemical reactions in the hyporheic zone (HZ) is the distribution of oxygen. A reliable measurement of the vertical oxygen distribution is an important tool to understand the dynamic fluctuations of the aerobic zone within the HZ. With repeated measurements of continuous profiles, mixing of surface water and groundwater as well as the consumption of oxygen can be evaluated. We present a novel approach for the in situ measurements of vertical oxygen distribution in the riverbed using a planar optode. The luminescence based optode measurement enables a non invasive measurement without consumption of oxygen, no creation of preferential flow paths and only minimal disturbance of the flow field. Possible atmospheric contamination by pumping pore water into a vessel can be avoided and the readings are independent of flow velocity. A self manufactured planar optode is wrapped around an acrylic tube and installed in the riverbed. The measurement is performed by vertically moving a profiler-piston inside the acrylic tube. The piston holds a robust polymer optical fibre which emits a modulated light signal through the acrylic glass to the optode-foil and transmits the induced luminescence signal back to a commercially available trace oxygen meter. Temperature compensation is accomplished using a depth-oriented temperature probe nearby and processing the raw data within a Matlab script. Robust and unbiased oxygen profiles are obtained by averaging multiple consecutive measurements. To ensure a constant velocity of the profiler for replicating the exact measuring depths, an electric motor device is used. First results at our test site show a variable oxygen profile down to 40 cm depth which is strongly influenced by stream level and upwelling groundwater conditions. The measured oxygen profiles will serve as input parameter for a 3D solute transport and chemical reaction subsurface model of the HZ.

  7. A comparison of diel nest temperature and nest site selection for two sympatric species of freshwater turtles

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Bodie, J.R.; Burke, V.J.; Smith, K.R.

    1996-07-01

    Diel nest temperature profiles were recorded form natural nests of eastern mud turtles (Kinosternon subrubrum) and Florida cooters (Pseudemys floridana) to determine whether nest microhabitat selection compensates for the effect of interspecific differences in nest depth on nest temperature. Kinosternon subrubrum nest depths were significantly shallower than those of P. floridana (t = 2.93, P < 0.01). We predicted that differences in nest depth would result in K. subrubrum nests being cooler at night and warmer during daylight than the deeper P. floridana nests. Diel temperature patterns agreed with out predictions at night, but P. floridana nest temperatures were notmore » lower than K. subrubrum nest temperatures during the day. Soil composition, slope and soil moisture were similar for the nest of both species. However, the amount of sunlight reaching the soil above K. subrubrum nest sites was substantially less than the amount above P. floridana nest sites. We suggest that these species select habitats for oviposition that differ in the amount and types of vegetative cover, which in turn affect exposure to sunlight and ultimately nest temperature. 27 refs., 2 figs.« less

  8. Sand and nest temperatures and an estimate of hatchling sex ratio from the Heron Island green turtle ( Chelonia mydas) rookery, Southern Great Barrier Reef

    NASA Astrophysics Data System (ADS)

    Booth, David T.; Freeman, Candida

    2006-11-01

    Sand and nest temperatures were monitored during the 2002-2003 nesting season of the green turtle, Chelonia mydas, at Heron Island, Great Barrier Reef, Australia. Sand temperatures increased from ˜ 24°C early in the season to 27-29°C in the middle, before decreasing again. Beach orientation affected sand temperature at nest depth throughout the season; the north facing beach remained 0.7°C warmer than the east, which was 0.9°C warmer than the south, but monitored nest temperatures were similar across all beaches. Sand temperature at 100 cm depth was cooler than at 40 cm early in the season, but this reversed at the end. Nest temperatures increased 2-4°C above sand temperatures during the later half of incubation due to metabolic heating. Hatchling sex ratio inferred from nest temperature profiles indicated a strong female bias.

  9. Multi-layer thermoelectric-temperature-mapping microbial incubator designed for geo-biochemistry applications.

    PubMed

    Wu, Jin-Gen; Liu, Man-Chi; Tsai, Ming-Fei; Yu, Wei-Shun; Chen, Jian-Zhang; Cheng, I-Chun; Lin, Pei-Chun

    2012-04-01

    We demonstrate a novel, vertical temperature-mapping incubator utilizing eight layers of thermoelectric (TE) modules mounted around a test tube. The temperature at each layer of the TE module is individually controlled to simulate the vertical temperature profile of geo-temperature variations with depth. Owing to the constraint of non-intrusion to the filled geo-samples, the temperature on the tube wall is adopted for measurement feedback. The design considerations for the incubator include spatial arrangement of the energy transfer mechanism, heating capacity of the TE modules, minimum required sample amount for follow-up instrumental or chemical analysis, and the constraint of non-intrusion to the geo-samples during incubation. The performance of the incubator is experimentally evaluated with two tube conditions and under four preset temperature profiles. Test tubes are either empty or filled with quartz sand, which has comparable thermal properties to the materials in the geo-environment. The applied temperature profiles include uniform, constant temperature gradient, monotonic-increasing parabolic, and parabolic. The temperature on the tube wall can be controlled between 20 °C and 90 °C with an averaged root mean squared error of 1 °C. © 2012 American Institute of Physics

  10. Oceanic lithosphere and asthenosphere - Thermal and mechanical structure

    NASA Technical Reports Server (NTRS)

    Schubert, G.; Yuen, D. A.; Froidevaux, C.

    1976-01-01

    A coupled thermomechanical subsolidus model of the oceanic lithosphere and asthenosphere is developed which includes vertical heat conduction, a temperature-dependent thermal conductivity, heat advection by a horizontal and vertical mass flow that depends on depth and age, contributions of viscous dissipation or shear heating, a linear or nonlinear deformation law relating shear stress and strain rate, as well as a temperature- and pressure-dependent viscosity. The model requires a constant horizontal velocity and temperature at the surface, but zero horizontal velocity and constant temperature at great depths. The depth- and age-dependent temperature, horizontal and vertical velocities, and viscosity structure of the lithosphere and asthenosphere are determined along with the age-dependent shear stress in those two zones. The ocean-floor topography, oceanic heat flow, and lithosphere thickness are deduced as functions of ocean-floor age; seismic velocity profiles which exhibit a marked low-velocity zone are constructed from the age-dependent geotherms and assumed values of the elastic parameters. It is found that simple boundary-layer cooling determines the thermal structure at young ages, while effects of viscous dissipation become more important at older ages.

  11. Heat sources within the Greenland Ice Sheet: dissipation, temperate paleo-firn and cryo-hydrologic warming

    DOE PAGES

    Lüthi, M. P.; Ryser, C.; Andrews, L. C.; ...

    2015-01-01

    Ice temperature profiles from the Greenland Ice Sheet contain information on the deformation history, past climates and recent warming. We present full-depth temperature profiles from two drill sites on a flow line passing through Swiss Camp, West Greenland. Numerical modeling reveals that ice temperatures are considerably higher than would be expected from heat diffusion and dissipation alone. The possible causes for this extra heat are evaluated using a Lagrangian heat flow model. The model results reveal that the observations can be explained with a combination of different processes: enhanced dissipation (strain heating) in ice-age ice, temperate paleo-firn, and cryo-hydrologic warmingmore » in deep crevasses.« less

  12. Path homogeneity along a horizontal line-of-sight path during the FESTER experiment: first results

    NASA Astrophysics Data System (ADS)

    Gunter, W. H.; Maritz, B.; Koago, M.; Wainman, C. K.; Gardener, M. E.; February, F.; van Eijk, A. M. J.

    2016-10-01

    The First European South African Experiment (FESTER) was conducted over about a 10 month period at the Institute of Maritime Technology (IMT) in False Bay, South Africa. One of the important goals was the establishment of the air-sea temperature difference (ASTD) homogeneity along the main propagation link atmospheric path since it is a basic assumption for most of the atmospheric turbulence models (caused by refractive index variations). The ASTD was measured from a small scientific work boat (called Sea Lab) moving along a straight in- and outbound track along the main propagation link path. The air temperature on-board was measured using standard weather sensors, while the sea surface temperature was measured using a long wavelength infrared radiometer, which was compared to the bulk sea temperature half a meter below the sea surface. This was obtained by an under water temperature sensor mounted on a `surfboard' that was towed alongside Sea Lab. Vertical water temperature profiles were also measured along the main propagation path in order to determine the depth of the surface mixed layer and thermocline using a Conductivity Temperature Depth profiler (CTD). First results investigated the ASTD variation along the horizontal line-of-sight path used by the principal electro-optic transmission link monitoring equipment (i.e. scintillometer and multi-spectral radiometer-transmissometer system).

  13. Numerical determination of vertical water flux based on soil temperature profiles

    NASA Astrophysics Data System (ADS)

    Tabbagh, Alain; Cheviron, Bruno; Henine, Hocine; Guérin, Roger; Bechkit, Mohamed-Amine

    2017-07-01

    High sensitivity temperature sensors (0.001 K sensitivity Pt100 thermistors), positioned at intervals of a few centimetres along a vertical soil profile, allow temperature measurements to be made which are sensitive to water flux through the soil. The development of high data storage capabilities now makes it possible to carry out in situ temperature recordings over long periods of time. By directly applying numerical models of convective and conductive heat transfer to experimental data recorded as a function of depth and time, it is possible to calculate Darcy's velocity from the convection transfer term, thus allowing water infiltration/exfiltration through the soil to be determined as a function of time between fixed depths. In the present study we consider temperature data recorded at the Boissy-le-Châtel (Seine et Marne, France) experimental station between April 16th, 2009 and March 8th, 2010, at six different depths and 10-min time intervals. We make use of two numerical finite element models to solve the conduction/convection heat transfer equation and compare their merits. These two models allow us to calculate the corresponding convective flux rate every day using a group of three sensors. The comparison of the two series of calculated values centred at 24 cm shows reliable results for periods longer than 8 days. These results are transformed in infiltration/exfiltration value after determining the soil volumetric heat capacity. The comparison with the rainfall and evaporation data for periods of ten days shows a close accordance with the behaviour of the system governed by rainfall evaporation rate during winter and spring.

  14. A non-steady-state condition in sediments at the gas hydrate stability boundary off West Spitsbergen: Evidence for gas hydrate dissociation or just dynamic methane transport

    NASA Astrophysics Data System (ADS)

    Treude, Tina; Krause, Stefan; Bertics, Victoria; Steinle, Lea; Niemann, Helge; Liebetrau, Volker; Feseker, Tomas; Burwicz, Ewa; Krastel, Sebastian; Berndt, Christian

    2015-04-01

    In 2008, a large area with several hundred methane plumes was discovered along the West Spitsbergen continental margin at water depths between 150 and 400 m (Westbrook et al. 2009). Many of the observed plumes were located at the boundary of gas hydrate stability (~400 m water depth). It was speculated that the methane escape at this depth was correlated with gas hydrate destabilization caused by recent increases in water temperatures recorded in this region. In a later study, geochemical analyses of authigenic carbonates and modeling of heat flow data combined with seasonal changes in water temperature demonstrated that the methane seeps were active already prior to industrial warming but that the gas hydrate system nevertheless reacts very sensitive to even seasonal temperature changes (Berndt et al. 2014). Here, we report about a methane seep site at the gas hydrate stability boundary (394 m water depth) that features unusual geochemical profiles indicative for non-steady state conditions. Sediment was recovered with a gravity corer (core length 210 cm) and samples were analyzed to study porewater geochemistry, methane concentration, authigenic carbonates, and microbial activity. Porewater profiles revealed two zones of sulfate-methane transition at 50 and 200 cm sediment depth. The twin zones were confirmed by a double peaking in sulfide, total alkalinity, anaerobic oxidation of methane, and sulfate reduction. d18O values sharply increased from around -2.8 ‰ between 0 and 126 cm to -1.2 ‰ below 126 cm sediment depth. While U/Th isotope measurements of authigenic seep carbonates that were collected from different depths of the core illustrated that methane seepage must be occurring at this site since at least 3000 years, the biogeochemical profiles suggest that methane flux must have been altered recently. By applying a multi-phase reaction-transport model using known initial parameters from the study site (e.g. water depth, temperature profile, salinity, and sediment surface concentrations of CH4, SO4, DIC, and POC) were able to show that the observed twin sulfate-methane transition zones are an ephemeral phenomenon occurring during increase of methane production in the sediment, which can be introduced by, e.g., gas hydrate dissociation. References Berndt, C., T. Feseker, T. Treude, S. Krastel, V. Liebetrau, H. Niemann, V. J. Bertics, I. Dumke, K. Dunnbier, B. Ferre, C. Graves, F. Gross, K. Hissmann, V. Huhnerbach, S. Krause, K. Lieser, J. Schauer and L. Steinle (2014). "Temporal constraints on hydrate-controlled methane seepage off svalbard." Science 343: 284-287. Westbrook, G. K., K. E. Thatcher, E. J. Rohling, A. M. Piotrowski, H. Pälike, A. H. Osborne, E. G. Nisbet, T. A. Minshull, M. Lanoiselle, R. H. James, V. Hühnerbach, D. Green, R. E. Fisher, A. J. Crocker, A. Chabert, C. Bolton, A. Beszczynska-Möller, C. Berndt and A. Aquilina (2009). "Escape of methane gas from the seabed along the West Spitsbergen continental margin." Geophys. Res. Let. 36: doi:10.1029/2009GL039191.

  15. Thermal Variability in Gravel Bars and its Potential Consequences for CO2 Evasion from Alpine Coldwater Streams

    NASA Astrophysics Data System (ADS)

    Boodoo, K. S.; Schelker, J.; Battin, T. J.

    2016-12-01

    Gravel bars (GB) are ubiquitous in-stream structures with relatively large exposed surfaces, capable of absorbing heat and possibly acting as a heat source to the underlying hyporheic zone (HZ). The distinctive mixing of groundwater and surface water within their HZ largely determines its characteristic physical and biogeochemical properties, including temperature distribution. To study thermal variability within GBs and its possible consequences for CO2 evasion fluxes we analysed high frequency spatio-temporal data for a range of stream and atmospheric physical parameters including the vertical GB temperature, in an Alpine cold water stream (Oberer Seebach, Austria) over the course of a year. We found the vertical temperature profiles within the GB to vary seasonally and with discharge. During warm summer months, diurnal vertical temperature patterns were most pronounced and were detected throughout all one-meter-depth profiles. Furthermore, permanently wetted GB sediment (-56 cm depth) temperatures above that of stream and groundwater occurred 17% of the year, particularly during summer. This is further evidence for downward heat transfer to the wetted HZ. Average CO2 flux from the GB was significantly higher than that of streamwater during summer and winter, with significantly higher temperatures and CO2 outgassing rates occurring at the GB tail as compared to streamwater and the head and mid of the GB throughout the year. Higher cumulative (over 6 h) GB temperatures were associated with increased CO2 evasion fluxes; the strength of the relationship increased with depth (max. r2 = 0.61 at -100cm depth). This enhanced CO2 flux may result from the input of warmer CO2-rich groundwater into the HZ in autumn and winter, while downward heat transfer in summer may enhance GB metabolism and therefore CO2 evasion. The importance of these processes is likely to increase, particularly in cold-water streams, due to the occurrence of more frequent and intense warm temperature events, as well as altered flow regimes, likely consequences of climatic change.

  16. Characterisation of Seasonal Temperature Variation in a Shallow, Urban Aquifer: Implications for the Sustainable Development of Ground Source Heating Systems

    NASA Astrophysics Data System (ADS)

    Patton, Ashley M.; Farr, Gareth J.; Boon, David P.; James, David R.

    2017-04-01

    Groundwater thermally enhanced by the Urban Heat Island effect can be utilised by ground source heating systems (GSHSs). However, the near subsurface is subject to seasonal temperature variation reflected in shallow groundwater that can differ by several degrees throughout the year. To sustainably manage the near surface thermal resource an understanding of factors which control variation in groundwater temperature and how these are transmitted through the aquifer is needed. We show that even in relatively small urban areas (Cardiff, U.K., situated on a shallow gravel aquifer) the Zone of Seasonal Fluctuation (ZSF) can vary in depth by 8m. GSHSs are more efficient if they are sited below the ZSF, where temperatures are more stable. In Spring 2014, 48 groundwater monitoring boreholes were profiled at a 1m resolution to measure groundwater temperature across Cardiff. These were reprofiled that Autumn and compared to the Spring temperatures, defining the ZSF. The average depth to the base of the ZSF was 9.5mbgl but ranged from 7.1-15.5mbgl. The amplitude of the differences between Spring and Autumn temperatures also varied. To better understand the high spatial variability 60 boreholes were instrumented with in situ temperature loggers, recording at half-hourly intervals. The first year's data revealed the amplitudes of temperature variation within boreholes with loggers at similar depths were not always consistent. It was also noted that lag times between air temperature and groundwater temperature were not uniform across the sites. The data also showed that where gravels occurred at shallower depths the ZSF tended to be shallower and lag times shorter. The wide spatial variability of the ZSF may be partially explained by differing landuse. Those boreholes in open, grassed areas showed a deeper ZSF than those in built-up areas but built-up areas generally showed the greatest variation between Spring and Autumn temperature profiles, suggesting heat loss from buildings and underground infrastructure plays a part. Natural and anthropogenic factors affecting spatial and temporal groundwater temperatures, either separately or in combination, that have been considered in this study include landuse, depth, lithology/lithostratigraphy, material properties, hydrogeological setting, thermal conductivity, buried infrastructure, land surface temperature, weather effects and solar radiation. This study shows that urban groundwater temperatures can vary greatly across a small area, which has implications for the successful development, and long-term performance of open- and closed-loop GSHSs, and the environmental regulation of these systems. Key to the effective wide-scale use of GSHSs is an understanding of the hydrogeological setting, chiefly how heat is transferred across the aquifer. This study attempts to provide insight into an array of factors which determine heat transfer in the ZSF.

  17. Assessment of thermal efficiency of heat recovery coke making

    NASA Astrophysics Data System (ADS)

    Tiwari, H. P.; Saxena, V. K.; Haldar, S. K.; Sriramoju, S. K.

    2017-08-01

    The heat recovery stamp charge coke making process is quite complicated due to the evolved volatile matter during coking, is partially combusted in oven crown and sole flue in a controlled manner to provide heat for producing metallurgical coke. Therefore, the control and efficient utilization of heat in the oven crown, and sole flue is difficult, which directly affects the operational efficiency. Considering the complexity and importance of thermal efficiency, evolution of different gases, combustion of gasses in oven crown and sole flue, and heating process of coke oven has been studied. A nonlinear regression methodology was used to predict temperature profile of different depth of coal cake during the coking. It was observed that the predicted temperature profile is in good agreement with the actual temperature profile (R2 = 0.98) and is validated with the actual temperature profile of other ovens. A complete study is being done to calculate the material balance, heat balance, and heat losses. This gives an overall understanding of heat flow which affects the heat penetration into the coal cake. The study confirms that 60% heat was utilized during coking.

  18. Biogenic emissions of CO2 and N2O at multiple depths increase exponentially during a simulated soil thaw for a northern prairie Mollisol

    USDA-ARS?s Scientific Manuscript database

    Soil respiration occurs at depths below the surface, but belowground data are lacking to support multilayer models of soil CO2 and N2O emissions. In particular, Q10s for CO2 and N2O within soil profiles are needed to determine if temperature sensitivities calculated at the surface are similar to th...

  19. CHARACTERIZING THE DISPERSIVE STATE OF CONVECTIVE BOUNDARY LAYERS FOR APPLIED DISPERSION MODELING

    EPA Science Inventory

    Estimates from semiempirical models that characterize surface heat flux, mixing depth, and profiles of temperature, wind, and turbulence are compared with observations from atmospheric field Studies conducted in Colorado, Illinois, Indiana, and Minnesota. In addition, for wind an...

  20. Surface profile changes of scuffed bearing surfaces. [before and after acid treatment

    NASA Technical Reports Server (NTRS)

    Lauer, J. L.; Fung, S. S.; Jones, W. R., Jr.

    1982-01-01

    A phase locked interference microscope capable of resolving depth differences to 30 A and planar displacements of 6000 A was constructed for the examination of the profiles of bearing surfaces without physical contact. This instrument was used to determine surface chemical reactivity by applying a drop of dilute alcoholic hydrochloric acid and measuring the profile of the solid surface before and after application of this probe. Scuffed bearing surfaces reacted much faster than unscuffed ones, but bearing surfaces which had been previously exposed to lubricants containing an organic chloride reacted much more slowly. In a separate series of experiments, a number of stainless steel plates were heated in a nitrogen atmosphere to different temperatures and their reactivity examined later at room temperature. The change of surface contour as a result of the probe reaction followed an Arrhenius type relation with respect to heat treatment temperature. This result could have implications on the scuffing mechanism.

  1. Analysis of the NASA AirMOSS Root Zone Soil Water and Soil Temperature from Three North American Ecosystems

    NASA Astrophysics Data System (ADS)

    Hagimoto, Y.; Cuenca, R. H.

    2015-12-01

    Root zone soil water and temperature are controlling factors for soil organic matter accumulation and decomposition which contribute significantly to the CO2 flux of different ecosystems. An in-situ soil observation protocol developed at Oregon State University has been deployed to observe soil water and temperature dynamics in seven ecological research sites in North America as part of the NASA AirMOSS project. Three instrumented profiles defining a transect of less than 200 m are installed at each site. All three profiles collect data for in-situ water and temperature dynamics employing seven soil water and temperature sensors installed at seven depth levels and one infrared surface temperature sensor monitoring the top of the profile. In addition, two soil heat flux plates and associated thermocouples are installed at one of three profiles at each site. At each profile, a small 80 cm deep access hole is typically made, and all below ground sensors are installed into undisturbed soil on the side of the hole. The hole is carefully refilled and compacted so that root zone soil water and temperature dynamics can be observed with minimum site disturbance. This study focuses on the data collected from three sites: a) Tonzi Ranch, CA; b) Metolius, OR and c) BERMS Old Jack Pine Site, Saskatchewan, Canada. The study describes the significantly different seasonal root zone water and temperature dynamics under the various physical and biological conditions at each site. In addition, this study compares the soil heat flux values estimated by the standard installation using the heat flux plates and thermocouples installed near the surface with those estimated by resolving the soil heat storage based on the soil water and temperature data collected over the total soil profile.

  2. Probing the magnetic profile of diluted magnetic semiconductors using polarized neutron reflectivity.

    PubMed

    Luo, X; Tseng, L T; Lee, W T; Tan, T T; Bao, N N; Liu, R; Ding, J; Li, S; Lauter, V; Yi, J B

    2017-07-24

    Room temperature ferromagnetism has been observed in the Cu doped ZnO films deposited under an oxygen partial pressure of 10 -3 and 10 -5 torr on Pt (200 nm)/Ti (45 nm)/Si (001) substrates using pulsed laser deposition. Due to the deposition at relatively high temperature (873 K), Cu and Ti atoms diffuse to the surface and interface, which significantly affects the magnetic properties. Depth sensitive polarized neutron reflectometry method provides the details of the composition and magnetization profiles and shows that an accumulation of Cu on the surface leads to an increase in the magnetization near the surface. Our results reveal that the presence of the copper at Zn sites induces ferromagnetism at room temperature, confirming intrinsic ferromagnetism.

  3. Improving the Representation of Snow Crystal Properties within a Single-Moment Microphysics Scheme

    NASA Technical Reports Server (NTRS)

    Molthan, Andrew L.; Petersen, Walter A.; Case, Jonathan L.; Dembek, Scott R.

    2010-01-01

    The assumptions of a single-moment microphysics scheme (NASA Goddard) were evaluated using a variety of surface, aircraft and radar data sets. Fixed distribution intercepts and snow bulk densities fail to represent the vertical variability and diversity of crystal populations for this event. Temperature-based equations have merit, but they can be adversely affected by complex temperature profiles that are inverted or isothermal. Column-based approaches can mitigate complex profiles of temperature but are restricted by the ability of the model to represent cloud depth. Spheres are insufficient for use in CloudSat reflectivity comparisons due to Mie resonance, but reasonable for Rayleigh scattering applications. Microphysics schemes will benefit from a greater range of snow crystal characteristics to accommodate naturally occurring diversity.

  4. On the appropriate definition of soil profile configuration and initial conditions for land surface-hydrology models in cold regions

    NASA Astrophysics Data System (ADS)

    Sapriza-Azuri, Gonzalo; Gamazo, Pablo; Razavi, Saman; Wheater, Howard S.

    2018-06-01

    Arctic and subarctic regions are amongst the most susceptible regions on Earth to global warming and climate change. Understanding and predicting the impact of climate change in these regions require a proper process representation of the interactions between climate, carbon cycle, and hydrology in Earth system models. This study focuses on land surface models (LSMs) that represent the lower boundary condition of general circulation models (GCMs) and regional climate models (RCMs), which simulate climate change evolution at the global and regional scales, respectively. LSMs typically utilize a standard soil configuration with a depth of no more than 4 m, whereas for cold, permafrost regions, field experiments show that attention to deep soil profiles is needed to understand and close the water and energy balances, which are tightly coupled through the phase change. To address this gap, we design and run a series of model experiments with a one-dimensional LSM, called CLASS (Canadian Land Surface Scheme), as embedded in the MESH (Modélisation Environmentale Communautaire - Surface and Hydrology) modelling system, to (1) characterize the effect of soil profile depth under different climate conditions and in the presence of parameter uncertainty; (2) assess the effect of including or excluding the geothermal flux in the LSM at the bottom of the soil column; and (3) develop a methodology for temperature profile initialization in permafrost regions, where the system has an extended memory, by the use of paleo-records and bootstrapping. Our study area is in Norman Wells, Northwest Territories of Canada, where measurements of soil temperature profiles and historical reconstructed climate data are available. Our results demonstrate a dominant role for parameter uncertainty, that is often neglected in LSMs. Considering such high sensitivity to parameter values and dependency on the climate condition, we show that a minimum depth of 20 m is essential to adequately represent the temperature dynamics. We further show that our proposed initialization procedure is effective and robust to uncertainty in paleo-climate reconstructions and that more than 300 years of reconstructed climate time series are needed for proper model initialization.

  5. Condition and biochemical profile of blue mussels (Mytilus edulis L.) cultured at different depths in a cold water coastal environment

    NASA Astrophysics Data System (ADS)

    Gallardi, Daria; Mills, Terry; Donnet, Sebastien; Parrish, Christopher C.; Murray, Harry M.

    2017-08-01

    The growth and health of cultured blue mussels (Mytilus edulis) are affected by environmental conditions. Typically, culture sites are situated in sheltered areas near shore (i.e., < 1 km distance from land, < 20 m depth); however, land runoff, user conflicts and environmental impact in coastal areas are concerns and interest in developing deep water (> 20 m depth) mussel culture has been growing. This study evaluated the effect of culture depth on blue mussels in a cold water coastal environment (Newfoundland, Canada). Culture depth was examined over two years from September 2012 to September 2014; mussels from three shallow water (5 m) and three deep water (15 m) sites were compared for growth and biochemical composition; culture depths were compared for temperature and chlorophyll a. Differences between the two years examined were noted, possibly due to harsh winter conditions in the second year of the experiment. In both years shallow and deep water mussels presented similar condition; in year 2 deep water mussels had a significantly better biochemical profile. Lipid and glycogen analyses showed seasonal variations, but no significant differences between shallow and deep water were noted. Fatty acid profiles showed a significantly higher content of omega-3 s (20:5ω3; EPA) and lower content of bacterial fatty acids in deep water sites in year 2. Everything considered, deep water appeared to provide a more favorable environment for mussel growth than shallow water under harsher weather conditions.

  6. Integrity Testing of Pile Cover Using Distributed Fibre Optic Sensing

    PubMed Central

    Rui, Yi; Kechavarzi, Cedric; O’Leary, Frank; Barker, Chris; Nicholson, Duncan; Soga, Kenichi

    2017-01-01

    The integrity of cast-in-place foundation piles is a major concern in geotechnical engineering. In this study, distributed fibre optic sensing (DFOS) cables, embedded in a pile during concreting, are used to measure the changes in concrete curing temperature profile to infer concrete cover thickness through modelling of heat transfer processes within the concrete and adjacent ground. A field trial was conducted at a high-rise building construction site in London during the construction of a 51 m long test pile. DFOS cables were attached to the reinforcement cage of the pile at four different axial directions to obtain distributed temperature change data along the pile. The monitoring data shows a clear development of concrete hydration temperature with time and the pattern of the change varies due to small changes in concrete cover. A one-dimensional axisymmetric heat transfer finite element (FE) model is used to estimate the pile geometry with depth by back analysing the DFOS data. The results show that the estimated pile diameter varies with depth in the range between 1.40 and 1.56 m for this instrumented pile. This average pile diameter profile compares well to that obtained with the standard Thermal Integrity Profiling (TIP) method. A parametric study is conducted to examine the sensitivity of concrete and soil thermal properties on estimating the pile geometry. PMID:29257094

  7. Integrity Testing of Pile Cover Using Distributed Fibre Optic Sensing.

    PubMed

    Rui, Yi; Kechavarzi, Cedric; O'Leary, Frank; Barker, Chris; Nicholson, Duncan; Soga, Kenichi

    2017-12-19

    The integrity of cast-in-place foundation piles is a major concern in geotechnical engineering. In this study, distributed fibre optic sensing (DFOS) cables, embedded in a pile during concreting, are used to measure the changes in concrete curing temperature profile to infer concrete cover thickness through modelling of heat transfer processes within the concrete and adjacent ground. A field trial was conducted at a high-rise building construction site in London during the construction of a 51 m long test pile. DFOS cables were attached to the reinforcement cage of the pile at four different axial directions to obtain distributed temperature change data along the pile. The monitoring data shows a clear development of concrete hydration temperature with time and the pattern of the change varies due to small changes in concrete cover. A one-dimensional axisymmetric heat transfer finite element (FE) model is used to estimate the pile geometry with depth by back analysing the DFOS data. The results show that the estimated pile diameter varies with depth in the range between 1.40 and 1.56 m for this instrumented pile. This average pile diameter profile compares well to that obtained with the standard Thermal Integrity Profiling (TIP) method. A parametric study is conducted to examine the sensitivity of concrete and soil thermal properties on estimating the pile geometry.

  8. Mission simulator test data. [an overview of a real time mission simulation test program of a nickel cadmium battery

    NASA Technical Reports Server (NTRS)

    Hendee, E. A.

    1980-01-01

    A real time mission simulation test program of nickel cadmium cells, performed in conjunction with the Anik 1A2 satellite, is reviewed. Simulation of the temperature profiles, the electrical profiles, the depth of discharge, and the rate of charge and discharge is reported. The type of separator used in the cells and the transfer of electrolytes during overcharge are discussed.

  9. XBT Fall-rate study in the Southern Ocean

    NASA Astrophysics Data System (ADS)

    Ribeiro, N.; Mata, M. M.; Azevedo, J. L.

    2016-02-01

    Several studies have observed a more prominent warming of the Southern Ocean when compared to other ocean regions of the world in response to global climate change. However, the vast majority of available temperature data for that region is composed by eXpendable BathyTermographers profiles (XBTs). These probes are not equipped with a pressure sensor and thus do not measure depth directly. Depth is inferred by a fall-rate equation offered by the manufacturer that does not seem to adequately represent the extremely cold and high viscosity conditions of the region. Probes fall slower than expected and thus lead to an overestimation in heat content for those areas. In this study, a set of 850 collocated XBT (DB/T7 type) and CTD stations obtained from World Ocean Database (2013) and separated by a maximum distance of 12.5 nm and 10 hours is used. Those pairs are used to identify and quantify the depth errors in the XBT's temperature profiles, proposing a regional equation correction able to represent the peculiarities of the region. Hanawa et al. (1995) and Cheng et al. (2014) correction methods were applied to the dataset, with the latter producing better results. For the pairs in Drake Passage (151), South of Africa (244) and South of Tasmania (455), we found the ideal A coefficients to change by -0.88%, -1.4% and -2.2% from the original values, respectively. When a temperature profile is more homogeneous, there is no significant change if different values of B are used, which was proven to be true since they were .0021 for Drake Passage and .0020 for the other chokings. The ideal fall-rate equation for the Southern Ocean was determined using all pairs, being defined as instead of the proposed by the manufacturer. Overall, the results further support the hypothesis of a regional dependence of the XBT fall-rate on water temperature, and suggest the need of developing a bias correction scheme specific for the polar regions.

  10. Subsurface thermal regime to delineate the paleo-groundwater flow system in an arid area, Al Kufra, Libya

    NASA Astrophysics Data System (ADS)

    Salem, Zenhom El-Said

    2016-12-01

    The purpose of this study was to understand the groundwater flow system in Al Kufra basin, Libya, as a case study of arid areas using subsurface temperature. The temperature-depth profiles and water levels were measured in eight boreholes in the area. Well 6 is considered a recharge type profile with low geothermal gradient (0.0068 °C/m) and an estimated paleo-temperature around 19.5 °C. The other profiles are of discharge type with higher geothermal gradient (0.0133 to 0.0166 °C/m). The constructed horizontal 2D distribution maps of the hydraulic heads and the subsurface temperature measurements reveal that the main recharge area is located to the south with low temperature while the main discharge area is located to the north with higher temperature. Vertical 2D distribution maps show that location of well 4 has low hydraulic heads and higher temperature indicating that the fault defined in the area may have affected the groundwater flow system. The estimated groundwater flux ranges from 0.001 to 0.1 mm/day for the recharge area and from -0.3 to -0.7 mm/day in average in the discharge area.

  11. Enhanced Carbon Diffusion in Austenitic Stainless Steel Carburized at Low Temperature

    NASA Astrophysics Data System (ADS)

    Ernst, F.; Avishai, A.; Kahn, H.; Gu, X.; Michal, G. M.; Heuer, A. H.

    2009-08-01

    Austenitic stainless steel AISI 316L was carburized by a novel, low-temperature gas-phase process. Using a calibrated scanning Auger microprobe (SAM) analysis of cross-sectional specimens under dynamic sputtering, we determined the fraction-depth profile of carbon. The profile is concave—very different from the shape expected for concentration-independent diffusion—and indicates a carbide-free solid solution with carbon levels up to 15 at. pct and a case depth of ≈30 μm. A Boltzmann-Matano analysis with a careful evaluation of the stochastic and potential systematic errors indicates that increasing levels of carbon significantly enhance carbon diffusion. For the highest carbon level observed (15 at. pct), the carbon diffusion coefficient is more than two orders of magnitude larger than in dilute solution. The most likely explanation for this strong increase is that carbon-induced local expansion of metal-metal atom distances, observed as an expansion of the lattice parameter, reduces the activation energy for carbon diffusion.

  12. DOE Office of Scientific and Technical Information (OSTI.GOV)

    Donald, Scott B.; Siekhaus, Wigbert J.; Nelson, Art J.

    X-ray photoelectron spectroscopy in combination with secondary ion mass spectrometry depth profiling were used to investigate the surface and interfacial chemistry of C + ion implanted polycrystalline uranium subsequently oxidized in air for over 10 years at ambient temperature. The original implantation of 33 keV C + ions into U 238 with a dose of 4.3 × 10 17 cm –3 produced a physically and chemically modified surface layer that was characterized and shown to initially prevent air oxidation and corrosion of the uranium after 1 year in air at ambient temperature. The aging of the surface and interfacial layersmore » were examined by using the chemical shift of the U 4f, C 1s, and O 1s photoelectron lines. In addition, valence band spectra were used to explore the electronic structure of the aged carbide surface and interface layer. Moreover, the time-of-flight secondary ion mass spectrometry depth profiling results for the aged sample confirmed an oxidized uranium carbide layer over the carbide layer/U metal interface.« less

  13. Intensity-corrected Herschel Observations of Nearby Isolated Low-mass Clouds

    NASA Astrophysics Data System (ADS)

    Sadavoy, Sarah I.; Keto, Eric; Bourke, Tyler L.; Dunham, Michael M.; Myers, Philip C.; Stephens, Ian W.; Di Francesco, James; Webb, Kristi; Stutz, Amelia M.; Launhardt, Ralf; Tobin, John J.

    2018-01-01

    We present intensity-corrected Herschel maps at 100, 160, 250, 350, and 500 μm for 56 isolated low-mass clouds. We determine the zero-point corrections for Herschel Photodetector Array Camera and Spectrometer (PACS) and Spectral Photometric Imaging Receiver (SPIRE) maps from the Herschel Science Archive (HSA) using Planck data. Since these HSA maps are small, we cannot correct them using typical methods. Here we introduce a technique to measure the zero-point corrections for small Herschel maps. We use radial profiles to identify offsets between the observed HSA intensities and the expected intensities from Planck. Most clouds have reliable offset measurements with this technique. In addition, we find that roughly half of the clouds have underestimated HSA-SPIRE intensities in their outer envelopes relative to Planck, even though the HSA-SPIRE maps were previously zero-point corrected. Using our technique, we produce corrected Herschel intensity maps for all 56 clouds and determine their line-of-sight average dust temperatures and optical depths from modified blackbody fits. The clouds have typical temperatures of ∼14–20 K and optical depths of ∼10‑5–10‑3. Across the whole sample, we find an anticorrelation between temperature and optical depth. We also find lower temperatures than what was measured in previous Herschel studies, which subtracted out a background level from their intensity maps to circumvent the zero-point correction. Accurate Herschel observations of clouds are key to obtaining accurate density and temperature profiles. To make such future analyses possible, intensity-corrected maps for all 56 clouds are publicly available in the electronic version. Herschel is an ESA space observatory with science instruments provided by European-led Principal Investigator consortia and with important participation from NASA.

  14. The size prediction of potential inclusions embedded in the sub-surface of fused silica by damage morphology

    NASA Astrophysics Data System (ADS)

    Gao, Xiang; Qiu, Rong; Wang, Kunpeng; Zhang, Jiangmei; Zhou, Guorui; Yao, Ke; Jiang, Yong; Zhou, Qiang

    2017-04-01

    A model for predicting the size ranges of different potential inclusions initiating damage on the surface of fused silica has been presented. This accounts for the heating of nanometric inclusions whose absorptivity is described based on Mie Theory. The depth profile of impurities has been measured by ICP-OES. By the measured temporal pulse profile on the surface of fused silica, the temperature and thermal stress has been calculated. Furthermore, considering the limit conditions of temperature and thermal stress strength for different damage morphologies, the size range of potential inclusions for fused silica is discussed.

  15. Analysis of temperature time series to estimate direction and magnitude of water fluxes in near-surface sediments

    NASA Astrophysics Data System (ADS)

    Munz, Matthias; Oswald, Sascha E.; Schmidt, Christian

    2017-04-01

    The application of heat as a hydrological tracer has become a standard method for quantifying water fluxes between groundwater and surface water. Typically, time series of temperatures in the surface water and in the sediment are observed and are subsequently evaluated by a vertical 1D representation of heat transport by advection and dispersion. Several analytical solutions as well as their implementation into user-friendly software exist in order to estimate water fluxes from the observed temperatures. The underlying assumption of a stationary, one-dimensional vertical flow field is frequently violated in natural systems. Here subsurface water flow often has a significant horizontal component. We developed a methodology for identifying the geometry of the subsurface flow field based on the variations of diurnal temperature amplitudes with depths. For instance: Purely vertical heat transport is characterized by an exponential decline of temperature amplitudes with increasing depth. Pure horizontal flow would be indicated by a constant, depth independent vertical amplitude profile. The decline of temperature amplitudes with depths could be fitted by polynomials of different order whereby the best fit was defined by the highest Akaike Information Criterion. The stepwise model optimization and selection, evaluating the shape of vertical amplitude ratio profiles was used to determine the predominant subsurface flow field, which could be systematically categorized in purely vertical and horizontal (hyporheic, parafluvial) components. Analytical solutions to estimate water fluxes from the observed temperatures are restricted to specific boundary conditions such as a sinusoidal upper temperature boundary. In contrast numerical solutions offer higher flexibility and can handle temperature data which is characterized by irregular variations such as storm-event induced temperature changes and thus cannot readily be incorporated in analytical solutions. There are several numerical models that simulate heat transport in porous media (e.g. VS2DH, HydroGeoSphere, FEFLOW) but there can be a steep learning curve to the modelling frameworks and may therefore not readily accessible to routinely infer water fluxes between groundwater and surface water. We developed a user-friendly, straightforeward to use software to estimate water FLUXes Based On Temperatures- FLUX-BOT. FLUX-BOT is a numerical code written in MATLAB that calculates time variable vertical water fluxes in saturated sediments based on the inversion of measured temperature time series observed at multiple depths. It applies a cell-centered Crank-Nicolson implicit finite difference scheme to solve the one-dimensional heat advection-conduction equation (FLUX-BOT can be downloaded from the following web site: https://bitbucket.org/flux-bot/flux-bot). We provide applications of FLUX-BOT to generic as well as to measured temperature data to demonstrate its performance. Both, the empirical analysis of temperature amplitudes as well as the numerical inversion of measured temperature time series to estimate the vertical magnitude of water fluxes extent the suite of current heat tracing methods and may provide insight into temperature data from an additional perspective.

  16. Laser-induced damage of coatings on Yb:YAG crystals at cryogenic condition

    NASA Astrophysics Data System (ADS)

    Wang, He; Zhang, Weili; Chen, Shunli; Zhu, Meiping; He, Hongbo; Fan, Zhengxiu

    2011-12-01

    As large amounts of heat need to be dissipated during laser operation, some diode pumped solid state lasers (DPSSL), especially Yb:YAG laser, operate at cryogenic condition. This work investigated the laser induced damage of coatings (high-reflective and anti-reflective coatings) on Yb:YAG crystals at cryogenic temperature and room temperature. The results show that the damage threshold of coatings at cryogenic temperature is lower than the one at room temperature. Field-emission scanning electron microscopy (FESEM), optical profiler, step profiler and Atomic force microscope (AFM) were used to obtain the damage morphology, size and depth. Taking alteration of physical parameters, microstructure of coatings and the environmental pollution into consideration, we analyzed the key factor of lowering the coating damage threshold at cryogenic conditions. The results are important to understand the mechanisms leading to damage at cryogenic condition.

  17. Objective characterization of bruise evolution using photothermal depth profiling and Monte Carlo modeling

    NASA Astrophysics Data System (ADS)

    Vidovič, Luka; Milanič, Matija; Majaron, Boris

    2015-01-01

    Pulsed photothermal radiometry (PPTR) allows noninvasive determination of laser-induced temperature depth profiles in optically scattering layered structures. The obtained profiles provide information on spatial distribution of selected chromophores such as melanin and hemoglobin in human skin. We apply the described approach to study time evolution of incidental bruises (hematomas) in human subjects. By combining numerical simulations of laser energy deposition in bruised skin with objective fitting of the predicted and measured PPTR signals, we can quantitatively characterize the key processes involved in bruise evolution (i.e., hemoglobin mass diffusion and biochemical decomposition). Simultaneous analysis of PPTR signals obtained at various times post injury provides an insight into the variations of these parameters during the bruise healing process. The presented methodology and results advance our understanding of the bruise evolution and represent an important step toward development of an objective technique for age determination of traumatic bruises in forensic medicine.

  18. The Acquisition, Calibration, and Analysis of CTD Data. Unesco Technical Papers in Marine Science No. 54. (A Report of SCOR Working Group 51).

    ERIC Educational Resources Information Center

    United Nations Educational, Scientific, and Cultural Organization, Paris (France). Div. of Marine Sciences.

    In this report the members of the Scientific Committee on Ocean Research Working Group 51 have attempted to describe the total process involved in obtaining salinity and temperature profiles with modern conductivity-temperature-depth (CTD) instruments. Their objective has been to provide a guide to procedures which will, if allowed, lead to the…

  19. Analysis of the Tikhonov regularization to retrieve thermal conductivity depth-profiles from infrared thermography data

    NASA Astrophysics Data System (ADS)

    Apiñaniz, Estibaliz; Mendioroz, Arantza; Salazar, Agustín; Celorrio, Ricardo

    2010-09-01

    We analyze the ability of the Tikhonov regularization to retrieve different shapes of in-depth thermal conductivity profiles, usually encountered in hardened materials, from surface temperature data. Exponential, oscillating, and sigmoidal profiles are studied. By performing theoretical experiments with added white noises, the influence of the order of the Tikhonov functional and of the parameters that need to be tuned to carry out the inversion are investigated. The analysis shows that the Tikhonov regularization is very well suited to reconstruct smooth profiles but fails when the conductivity exhibits steep slopes. We check a natural alternative regularization, the total variation functional, which gives much better results for sigmoidal profiles. Accordingly, a strategy to deal with real data is proposed in which we introduce this total variation regularization. This regularization is applied to the inversion of real data corresponding to a case hardened AISI1018 steel plate, giving much better anticorrelation of the retrieved conductivity with microindentation test data than the Tikhonov regularization. The results suggest that this is a promising way to improve the reliability of local inversion methods.

  20. Microwave remote sensing of soil water content

    NASA Technical Reports Server (NTRS)

    Cihlar, J.; Ulaby, F. T.

    1975-01-01

    Microwave remote sensing of soils to determine water content was considered. A layered water balance model was developed for determining soil water content in the upper zone (top 30 cm), while soil moisture at greater depths and near the surface during the diurnal cycle was studied using experimental measurements. Soil temperature was investigated by means of a simulation model. Based on both models, moisture and temperature profiles of a hypothetical soil were generated and used to compute microwave soil parameters for a clear summer day. The results suggest that, (1) soil moisture in the upper zone can be predicted on a daily basis for 1 cm depth increments, (2) soil temperature presents no problem if surface temperature can be measured with infrared radiometers, and (3) the microwave response of a bare soil is determined primarily by the moisture at and near the surface. An algorithm is proposed for monitoring large areas which combines the water balance and microwave methods.

  1. Photothermal modeling of thulium fibre laser-tissue interactions

    NASA Astrophysics Data System (ADS)

    Warnaby, Catherine E.; Coleman, Daniel J.; King, Terence A.

    2003-10-01

    A one-dimensional finite difference model has been used to investigate the temperature distribution within thulium fibre laser-irradiated tissue. Temperature-time and temperature-depth profiles are presented for various laser stimulus parameters in the 2 micron region. These current calculations are aimed at determining theoretical temperature distributions in the application of relatively low power fibre lasers for thermal stimulation of cutaneous nerves in human pain processing. Theoretical skin surface temperatures are compared with those from thermal camera measurements during thulium fibre laser irradiation. The effectiveness of the thulium fibre laser for thermally stimulating cutaneous nerves is confirmed.

  2. Simulation of Soil Frost and Thaw Fronts Dynamics with Community Land Model 4.5

    NASA Astrophysics Data System (ADS)

    Gao, J.; Xie, Z.

    2016-12-01

    Freeze-thaw processes in soils, including changes in frost and thaw fronts (FTFs) , are important physical processes. The movement of FTFs affects soil water and thermal characteristics, as well as energy and water exchanges between land surface and the atmosphere, and then the land surface hydrothermal process. In this study, a two-directional freeze and thaw algorithm for simulating FTFs is incorporated into the community land surface model CLM4.5, which is called CLM4.5-FTF. The simulated FTFs depth and soil temperature of CLM4.5-FTF compared well with the observed data both in D66 station (permafrost) and Hulugou station (seasonally frozen soil). Because the soil temperature profile within a soil layer can be estimated according to the position of FTFs, CLM4.5 performed better in soil temperature simulation. Permafrost and seasonally frozen ground conditions in China from 1980 to 2010 were simulated using the CLM4.5-FTF. Numerical experiments show that the spatial distribution of simulated maximum frost depth by CLM4.5-FTF has seasonal variation obviously. Significant positive active-layer depth trends for permafrost regions and negative maximum freezing depth trends for seasonal frozen soil regions are simulated in response to positive air temperature trends except west of Black Sea.

  3. Recent climate variations in Chile: constraints from borehole temperature profiles

    NASA Astrophysics Data System (ADS)

    Pickler, Carolyne; Gurza Fausto, Edmundo; Beltrami, Hugo; Mareschal, Jean-Claude; Suárez, Francisco; Chacon-Oecklers, Arlette; Blin, Nicole; Cortés Calderón, Maria Teresa; Montenegro, Alvaro; Harris, Rob; Tassara, Andres

    2018-04-01

    We have compiled, collected, and analyzed 31 temperature-depth profiles from boreholes in the Atacama Desert in central and northern Chile. After screening these profiles, we found that only nine profiles at four different sites were suitable to invert for ground temperature history. For all the sites, no surface temperature variations could be resolved for the period 1500-1800. In the northern coastal region of Chile, there is no perceptible temperature variation at all from 1500 to present. In the northern central Chile region, between 26 and 28° S, the data suggest a cooling from ≈ 1850 to ≈ 1980 followed by a 1.9 K warming starting ≈ 20-40 years BP. This result is consistent with the ground surface temperature histories for Peru and the semiarid regions of South America. The duration of the cooling trend is poorly resolved and it may coincide with a marked short cooling interval in the 1960s that is found in meteorological records. The total warming is greater than that inferred from proxy climate reconstructions for central Chile and southern South America, and by the PMIP3-CMIP5 surface temperature simulations for the north-central Chile grid points. The differences among different climate reconstructions, meteorological records, and models are likely due to differences in spatial and temporal resolution among the various data sets and the models.

  4. Interfacial mixing in as-deposited Si/Ni/Si layers analyzed by x-ray and polarized neutron reflectometry

    NASA Astrophysics Data System (ADS)

    Bhattacharya, Debarati; Basu, Saibal; Singh, Surendra; Roy, Sumalay; Dev, Bhupendra Nath

    2012-12-01

    Interdiffusion occurring across the interfaces in a Si/Ni/Si layered system during deposition at room temperature was probed using x-ray reflectivity (XRR) and polarized neutron reflectivity (PNR). Exploiting the complementarity of these techniques, both structural and magnetic characterization with nanometer depth resolution could be achieved. Suitable model fitting of the reflectivity profiles identified the formation of Ni-Si mixed alloy layers at the Si/Ni and Ni/Si interfaces. The physical parameters of the layered structure, including quantitative assessment of the stoichiometry of interfacial alloys, were obtained from the analyses of XRR and PNR patterns. In addition, PNR provided magnetic moment density profile as a function of depth in the stratified medium.

  5. A thermal profile method to identify potential ground-water discharge areas and preferred salmonid habitats for long river reaches

    USGS Publications Warehouse

    Vaccaro, J.J.; Maloy, K.J.

    2006-01-01

    The thermal regime of riverine systems is a major control on aquatic ecosystems. Ground water discharge is an important abiotic driver of the aquatic ecosystem because it provides preferred thermal structure and habitat for different types of fish at different times in their life history. In large diverse river basins with an extensive riverine system, documenting the thermal regime and ground-water discharge is difficult and problematic. A method was developed to thermally profile long (5-25 kilometers) river reaches by towing in a Lagrangian framework one or two probes that measure temperature, depth, and conductivity. One probe is towed near the streambed and, if used, a second probe is towed near the surface. The probes continuously record data at 1-3-second intervals while a Global Positioning System logs spatial coordinates. The thermal profile provides valuable information about spatial and temporal variations in habitat, and, notably, indicates ground-water discharge areas. This method was developed and tested in the Yakima River Basin, Washington, in summer 2001 during low flows in an extreme drought year. The temperature profile comprehensively documents the longitudinal distribution of a river's temperature regime that cannot be captured by fixed station data. The example profile presented exhibits intra-reach diversity that reflects the many factors controlling the temperature of a parcel of water as it moves downstream. Thermal profiles provide a new perspective on riverine system temperature regimes that represent part of the aquatic habitat template for lotic community patterns.

  6. The Acoustic Model Evaluation Committee (AMEC) Reports. Volume 3. Evaluation of the RAYMODE X Propagation Loss Model. Book 1

    DTIC Science & Technology

    1982-09-01

    and run on single sound speed profile. This model the UNIVAC 1108 computer. Other RAYMODE is in exteasive fleet usage, supporting versions were not...sought for significant disparities. (U) In addition to a sound speed versus depth or temperature versus depth plus a (U) Taken together, the two accuracy...as- constant salinity value, the program can sessment techniques, the Difference and access historical sound speed data FOM techniques, lead to

  7. Temperature profiles in the earth of importance to deep electrical conductivity models

    NASA Astrophysics Data System (ADS)

    Čermák, Vladimír; Laštovičková, Marcela

    1987-03-01

    Deep in the Earth, the electrical conductivity of geological material is extremely dependent on temperature. The knowledge of temperature is thus essential for any interpretation of magnetotelluric data in projecting lithospheric structural models. The measured values of the terrestrial heat flow, radiogenic heat production and thermal conductivity of rocks allow the extrapolation of surface observations to a greater depth and the calculation of the temperature field within the lithosphere. Various methods of deep temperature calculations are presented and discussed. Characteristic geotherms are proposed for major tectonic provinces of Europe and it is shown that the existing temperatures on the crust-upper mantle boundary may vary in a broad interval of 350 1,000°C. The present work is completed with a survey of the temperature dependence of electrical conductivity for selected crustal and upper mantle rocks within the interval 200 1,000°C. It is shown how the knowledge of the temperature field can be used in the evaluation of the deep electrical conductivity pattern by converting the conductivity-versustemperature data into the conductivity-versus-depth data.

  8. The layered evolution of fabric and microstructure of snow at Point Barnola, Central East Antarctica

    NASA Astrophysics Data System (ADS)

    Calonne, Neige; Montagnat, Maurine; Matzl, Margret; Schneebeli, Martin

    2017-02-01

    Snow fabric, defined as the distribution of the c-axis orientations of the ice crystals in snow, is poorly known. So far, only one study exits that measured snow fabric based on a statistically representative technique. This recent study has revealed the impact of temperature gradient metamorphism on the evolution of fabric in natural snow, based on cold laboratory experiments. On polar ice sheets, snow properties are currently investigated regarding their strong variability in time and space, notably because of their potential influence on firn processes and consequently on ice core analysis. Here, we present measurements of fabric and microstructure of snow from Point Barnola, East Antarctica (close to Dome C). We analyzed a snow profile from 0 to 3 m depth, where temperature gradients occur. The main contributions of the paper are (1) a detailed characterization of snow in the upper meters of the ice sheet, especially by providing data on snow fabric, and (2) the study of a fundamental snow process, never observed up to now in a natural snowpack, namely the role of temperature gradient metamorphism on the evolution of the snow fabric. Snow samples were scanned by micro-tomography to measure continuous profiles of microstructural properties (density, specific surface area and pore thickness). Fabric analysis was performed using an automatic ice texture analyzer on 77 representative thin sections cut out from the samples. Different types of snow fabric could be identified and persist at depth. Snow fabric is significantly correlated with snow microstructure, pointing to the simultaneous influence of temperature gradient metamorphism on both properties. We propose a mechanism based on preferential grain growth to explain the fabric evolution under temperature gradients. Our work opens the question of how such a layered profile of fabric and microstructure evolves at depth and further influences the physical and mechanical properties of snow and firn. More generally, it opens the way to further studies on the influence of the snow fabric in snow processes related to anisotropic properties of ice such as grain growth, mechanical response, electromagnetic behavior.

  9. A novel approach to making microstructure measurements in the ice-covered Arctic Ocean.

    NASA Astrophysics Data System (ADS)

    Guthrie, J.; Morison, J.; Fer, I.

    2014-12-01

    As part of the 2014 Field Season of the North Pole Environmental Observatory, a 7-day microstructure experiment was performed. A Rockland Scientific Microrider with 2 FP07 fast response thermistors and 2 SBE-7 micro-conductivity probes was attached to a Seabird 911+ Conductivity-Temperature-Depth unit to allow for calibration of the microstructure probes against the highly accurate Seabird temperature and conductivity sensors. From a heated hut, the instrument package was lowered through a 0.75-m hole in the sea ice down to 350 m depth using a lightweight winch powered with a 3-phase, frequency-controlled motor that produced a smooth, controlled lowering speed of 25 cm s-1. Focusing on temperature and conductivity microstructure and using the special winch removed many of the complications involved with the use of free-fall microstructure profilers under the ice. The slow profiling speed permits calculation of Χ, the dissipation of thermal variance, without relying on fits to theoretical spectra to account for the unresolved variance. The dissipation rate of turbulent kinetic energy, ɛ, can then be estimated using the temperature gradient spectrum and the Ruddick et al. [2001] maximum likelihood method. Outside of a few turbulent patches, thermal diffusivity ranged between O(10-7) and O(10-6) m2s-1, resulting in negligible turbulent heat fluxes. Estimated ɛ was often at or below the noise level of most shear-based microstructure profilers. The noise level of Χ is estimated at O(10-11) °C2s-1, revealing the utility and applicability of this technique in future Arctic field work.

  10. Map showing the depth to the base of the deepest ice-bearing permafrost as determined from well logs, North Slope, Alaska

    USGS Publications Warehouse

    Collett, T.S.; Bird, K.J.; Kvenvolden, K.A.; Magoon, L.B.

    1989-01-01

    Because gas hydrates from within a limited temperature range, subsurface equilibrium temperature data are necessary to calculate the depth and thickness of the gas-hydrate stability field.  Acquiring these data is difficult because drilling activity often disrupts equilibrium temperatures in the subsurface, and a well mush lie undisturbed until thermal equilibrium is reestablished (Lachenbruch and Brewer, 1959).  On the North Slope if Akaska, a series of 46 oil and gas exploratory wells, which were considered to be near thermal equilibrium (Lachenbruch and others, 1982; 1987), were surveyed with high-resolution temperature devices (see table 1).  However, several thousand other exploratory and production wells have been drilled on the North Slope, and although they do not include temperature profiles, their geophysical logs often allow descrimination between ice-bearing and non-ice-bearing strata.  At the outset of this study, the coincidence of the base of ice-bearing strata being near the same depth as the 0°C isotherm at Prudhoe Bay (Lachenbruch and others, 1982) appeared to offer an opportunity to quickly and inexpensively expand the size of our subsurface temperature data base merely by using well logs to identify the base of the ice-bearing strata.

  11. Subsoil denitrification experiments at KBS MSU

    NASA Astrophysics Data System (ADS)

    Shcherbak, I.; Robertson, G. P.

    2011-12-01

    Denitrification is a major soil process that produces nitrous oxide (N2O), a potent greenhouse gas. Most research on denitrification has, for various reasons, concentrated on the top soil layer, ignoring depths below 10-20 cm. Although denitrification is considered to be the most active in top soil, this layer usually accounts for only 10% of the total volume of the soil profile. Our research addresses the questions: How significant is denitrification at depth in the soil profile and how does it vary with land-use? We have two field experiments at the W. K. Kellogg Biological Station (KBS) in southwest Michigan: 1) tilled versus no-tillage rainfed fertilized corn and 2) rainfed versus irrigated corn at six fertilizer levels, with N2O concentrations measured at 10 depths (3, 7, 15, 20, 25, 50, 55, 70, 75, 125 cm) and 5 depths (10, 20, 30, 50, 75 cm), respectively , along with N2O fluxes to the atmosphere in both. Soil environment data (texture, water content, temperature and nitrate content) represent a combination of measured values and simulated values using the SALUS (System Approach to Land Use Sustainability) model. We used diffusion and water balance equations that incorporated carbon dioxide concentrations and flux data collected simultaneously with N2O to determine diffusivity as a function of water content and soil temperature. We used the same diffusivity to obtain N2O production as function of moisture, temperature, and nitrate availability. Further validation of the production function was performed with data collected from the KBS Long-Term Ecological Research (LTER) site , where we also measured belowground concentrations during the 2011 growing season.

  12. Molecular Dynamics Simulation of Hydrogen Trapping on Sigma 5 Tungsten Grain Boundaries

    NASA Astrophysics Data System (ADS)

    Al-Shalash, Aws Mohammed Taha

    Tungsten as a plasma facing material is the predominant contender for future Tokamak reactor environments. The interaction between the plasma particles and tungsten is crucial to be studied for successful usage and design of tungsten in the plasma facing components ensuring the reliability and longevity of the fusion reactors. The bombardment of the sigma 5 polycrystalline tungsten was modeled using the molecular dynamics simulation through the large-scale atomic/molecular massively parallel simulator (LAMMPS) code and Tersoff type interatomic potential. By simulating the operational conditions of the Tokamak reactors, the hydrogen trapping rate, implantation distribution, and bubble formation was investigated at various temperatures (300-1200 K) and various hydrogen incident energy (20-100 eV). The substrate's temperature increases the deflected H atoms, and increases the penetration depth for the ones that go through. As well, the lower temperature tungsten substrates retain more H atoms. Increasing the bombarded hydrogen's energy increases the trapping and retention rate and the depth of penetration. Another experiments were conducted to determine whether the Sigma5 grain boundary's (GB) location affects the trapping profiles in H. The findings are ranges from small effect on deflection rates at low H energies to no effect at high H energies. However, there is a considerable effect on shifting the trapping depth profile upward toward the surface when raising the GB closer to the surface. Hydrogen atoms are highly mobile on tungsten substrate, yet no bubble formation was witnessed.

  13. Thermal and dissolved oxygen characteristics of a South Carolina cooling reservoir

    USGS Publications Warehouse

    Oliver, James L.; Hudson, Patrick L.

    1987-01-01

    Temperature and dissolved oxygen concentrations were measured monthly from January 1971 to December 1982 at 1-m depth intervals at 13 stations in Keowee Reservoir in order to characterize spatial and temporal changes associated with operation of the Oconee Nuclear Station. The reservoir water column was i to 4°C warmer in operational than in non-operational years. The thermo-dine was at depths of 5 to 15 m before the operation of Oconee Nuclear Station, but was always below the upper level of the intake (20 m) after the station was in full operation; this suggests that pumping by the Oconee Nuclear Station had depleted all available cool hypolimnetic water to this depth. As a result summer water temperatures at depths greater than 10 m were usually 10°C higher after plant operation began than before. By fall the reservoir was nearly homothemious to a depth of 27 m, where a thermocine developed. Seasonal temperature profiles varied with distance from the plant; a cool water plume was evident in spring and a warm water plume was present in the summer, fall, and winter. A cold water plume also developed in the northern section of the reservoir due to the operation of Jocassee Pumped Storage Station. Increases in the mean water temperature of the reservoir during operational periods were correlated with the generating output of the power plant. The annual heat load to the reservoir increased by one-third after plant operations began. The alteration of the thermal stratification of the receiving water during the summer also caused the dissolved oxygen to mix to greater depths.

  14. Advanced analysis of thermal data observed in subsurface wells unmasks the ancient climate

    NASA Astrophysics Data System (ADS)

    Eppelbaum, Lev; Kutasov, Izzy

    2014-05-01

    Conventional methods of studying the ancient climate history are associated with statistical processing of accomplished meteorological data. These investigations have focused attention on meteorological records of air temperature, which can provide information on the only last 100-200 years. Number of the records is absolutely insufficient and their areal coverage is limited, some oldest meteorological stations may have been affected by local warming connected with urban and industrial growth. At the same time significant climate changes are accompanied by the corresponding variations in the Earth's surface (soil) temperature. This effect is based on the known physical law that temperature waves at the surface propagate downward into the subsurface with an amplitude attenuation and time delay increasing with depth. Earth's temperature profiles, measured by precise temperature logging T(z) in boreholes to depth of about 80-300 meters, have a 'memory' on what has happened on the surface during approximately several last centuries. Knowledge of the past climate in archaeology is necessary not only for tracing some ancient events and more deep understanding some historical facts, but also for estimation of past harvests, analysis of some physical conditions of different constructions built in the past, and in many other fields (Eppelbaum, 2010; Eppelbaum et al., 2010). The first attempts to recover the past ground surface temperature history (GSTH) from measured T(z) profiles date back to the mid-1960s, however only after Lachenbruch et al. (1988) pointed out that the magnitude and timing of the ground surface warming in Alaska is consistent with models of the recent warming, the method became popular (Cermak et al., 1996). Let us assume that tx years ago from now the ground surface temperature started to increase (warming) or reduce (cooling). Prior to this moment the subsurface temperature is: Ta(z,t = 0) = T0a + Γ z, (1) where T0a is the mean ground surface temperature at the moment of time t = 0 years; z is the vertical depth and Γ is the geothermal gradient. It is also assumed that the host medium is homogeneous with constant thermal properties. Now the current (t = tx) subsurface temperature is (in case of warming): Tc(z,t = tx) = T0c +f (z), (2) where T0c is the current (at the time (date) of temperature logging) mean ground surface temperature; and f(z) is a function of depth that could be obtained from the field data. In some cases the value of T0c can be obtained by extrapolation of the function Tc to z = 0. However, in most cases, the value T0c can be estimated by trial and error method: Assuming an interval of values for T0c, calculating for each T0c value of the temperature profiles Tcfor various models of change in the ground surface temperature (GST) with time and, finally, finding a best match between calculated and field measured Tc profiles. In our study we found that a quadratic regression can be utilized to estimate the value of T0c = a0 (Kutasov et al., 2000): Tc(z,t = tx) = a0 + a1z +a2z2, (3) where a0, a1, and a2 are the coefficients. We will consider four different models (Eppelbaum et al., 2006). Apparently each of these models is more suitable (applicable) under concrete physical-geological conditions. In the first model we assumed that txC years ago the GSTvalue suddenly changed from T0 to T0c. The current temperature anomaly (the reduced temperature) is TR (z) = T0c + f(z) - T0 - Γ z (4) and the solution is ( ) TRC = TR = ΔT0Φ *(x) -;z- ,t = txC, 2 at (5) ΔT0 = T0c - T0, (6)

  15. Shallow Groundwater Temperatures and the Urban Heat Island Effect: the First U.K City-wide Geothermal Map to Support Development of Ground Source Heating Systems Strategy

    NASA Astrophysics Data System (ADS)

    Patton, Ashley M.; Farr, Gareth J.; Boon, David P.; James, David R.; Williams, Bernard; Newell, Andrew J.

    2015-04-01

    The first UK city-wide heat map is described based on measurements of groundwater from a shallow superficial aquifer in the coastal city of Cardiff, Wales, UK. The UK Government has a target of reducing greenhouse gas emissions by 80% by 2050 (Climate Change Act 2008) and low carbon technologies are key to achieving this. To support the use of ground source heating we characterised the shallow heat potential of an urban aquifer to produce a baseline dataset which is intended to be used as a tool to inform developers and to underpin planning and regulation. We exploited an existing network of 168 groundwater monitoring boreholes across the city, recording the water temperature in each borehole at 1m depth intervals up to a depth of 20m. We recorded groundwater temperatures during the coldest part of 2014, and repeat profiling of the boreholes in different seasons has added a fourth dimension to our results and allowed us to characterise the maximum depth of seasonal temperature fluctuation. The temperature profiles were used to create a 3D model of heat potential within the aquifer using GOCAD® and the average borehole temperatures were contoured using Surfer® 10 to generate a 2D thermal resource map to support future assessment of urban Ground Source Heat Pumps prospectively. The average groundwater temperature in Cardiff was found to be above the average for England and Wales (11.3°C) with 90% of boreholes in excess of this figure by up to 4°C. The subsurface temperature profiles were also found to be higher than forecast by the predicted geothermal gradient for the area. Potential sources for heat include: conduction from buildings, basements and sub-surface infrastructure; insulation effects of the urban area and of the geology, and convection from leaking sewers. Other factors include recharge inhibition by drains, localised confinement and rock-water interaction in specific geology. It is likely to be a combination of multiple factors which we are hoping to make the focus of future study. The next stage of this work will be to develop conceptual models of the thermal groundwater regime, and monitoring under abstraction conditions to confirm the sustainability of groundwater temperatures as a long-term thermal resource. We have also instrumented a non-infiltration Sustainable Urban Drainage System (SuDS) scheme, where we will characterise the effect upon the thermal groundwater resource as localised infiltration is reduced.

  16. The formation of microvoids in MgO by helium ion implantation and thermal annealing

    NASA Astrophysics Data System (ADS)

    van Veen, A.; Schut, H.; Fedorov, A. V.; Labohm, F.; Neeft, E. A. C.; Konings, R. J. M.

    1999-01-01

    The formation of microvoids in metal oxides by helium implantation and thermal annealing is observed under similar conditions as has been shown earlier for silicon. Cleaved MgO (1 0 0) single crystals were implanted with 30 keV 3He ions with doses varying from 10 15 to 10 16 cm -2 and subsequently thermally annealed from RT to 1500 K. Monitoring of the defect depth profile and the retained amount of helium was performed by positron beam analysis and neutron depth profiling, respectively. For a dose larger than 2 × 10 15 cm -2 annealing of the defects was observed in two stages: at 1000 K helium filled monovacancies dissociated, and other defects still retaining the helium were formed, and at 1300 K all helium left the sample while an increase of positron-valence-electron annihilations was observed, indicating an increase of the volume available in the defects. The voids of nm size were located at shallower depth than the implanted helium. At lower dose no voids were left after high temperature annealing. Voids can also be created, and even more effectively, by hydrogen or deuterium implantation. The voids are stable to temperatures of 1500 K. The use of the nanovoids as a precursor state for nanoprecipitates of metals or other species is discussed.

  17. Dynamic topography and gravity anomalies for fluid layers whose viscosity varies exponentially with depth

    NASA Technical Reports Server (NTRS)

    Revenaugh, Justin; Parsons, Barry

    1987-01-01

    Adopting the formalism of Parsons and Daly (1983), analytical integral equations (Green's function integrals) are derived which relate gravity anomalies and dynamic boundary topography with temperature as a function of wavenumber for a fluid layer whose viscosity varies exponentially with depth. In the earth, such a viscosity profile may be found in the asthenosphere, where the large thermal gradient leads to exponential decrease of viscosity with depth, the effects of a pressure increase being small in comparison. It is shown that, when viscosity varies rapidly, topography kernels for both the surface and bottom boundaries (and hence the gravity kernel) are strongly affected at all wavelengths.

  18. Multilevel groundwater monitoring of hydraulic head and temperature in the eastern Snake River Plain aquifer, Idaho National Laboratory, Idaho, 2009–10

    USGS Publications Warehouse

    Twining, Brian V.; Fisher, Jason C.

    2012-01-01

    During 2009 and 2010, the U.S. Geological Survey’s Idaho National Laboratory Project Office, in cooperation with the U.S. Department of Energy, collected quarterly, depth-discrete measurements of fluid pressure and temperature in nine boreholes located in the eastern Snake River Plain aquifer. Each borehole was instrumented with a multilevel monitoring system consisting of a series of valved measurement ports, packer bladders, casing segments, and couplers. Multilevel monitoring at the Idaho National Laboratory has been ongoing since 2006. This report summarizes data collected from three multilevel monitoring wells installed during 2009 and 2010 and presents updates to six multilevel monitoring wells. Hydraulic heads (heads) and groundwater temperatures were monitored from 9 multilevel monitoring wells, including 120 hydraulically isolated depth intervals from 448.0 to 1,377.6 feet below land surface. Quarterly head and temperature profiles reveal unique patterns for vertical examination of the aquifer’s complex basalt and sediment stratigraphy, proximity to aquifer recharge and discharge, and groundwater flow. These features contribute to some of the localized variability even though the general profile shape remained consistent over the period of record. Major inflections in the head profiles almost always coincided with low-permeability sediment layers and occasionally thick sequences of dense basalt. However, the presence of a sediment layer or dense basalt layer was insufficient for identifying the location of a major head change within a borehole without knowing the true areal extent and relative transmissivity of the lithologic unit. Temperature profiles for boreholes completed within the Big Lost Trough indicate linear conductive trends; whereas, temperature profiles for boreholes completed within the axial volcanic high indicate mostly convective heat transfer resulting from the vertical movement of groundwater. Additionally, temperature profiles provide evidence for stratification and mixing of water types along the southern boundary of the Idaho National Laboratory. Vertical head and temperature change were quantified for each of the nine multilevel monitoring systems. The vertical head gradients were defined for the major inflections in the head profiles and were as high as 2.1 feet per foot. Low vertical head gradients indicated potential vertical connectivity and flow, and large gradient inflections indicated zones of relatively low vertical connectivity. Generally, zones that primarily are composed of fractured basalt displayed relatively small vertical head differences. Large head differences were attributed to poor vertical connectivity between fracture units because of sediment layering and/or dense basalt. Groundwater temperatures in all boreholes ranged from 10.2 to 16.3˚C. Normalized mean hydraulic head values were analyzed for all nine multilevel monitoring wells for the period of record (2007-10). The mean head values suggest a moderately positive correlation among all boreholes, which reflects regional fluctuations in water levels in response to seasonality. However, the temporal trend is slightly different when the location is considered; wells located along the southern boundary, within the axial volcanic high, show a strongly positive correlation.

  19. Overview of SIMS-Based Experimental Studies of Tracer Diffusion in Solids and Application to Mg Self-Diffusion

    DOE PAGES

    Kulkarni, Nagraj S.; Bruce Warmack, Robert J.; Radhakrishnan, Bala; ...

    2014-09-23

    Tracer diffusivities provide the most fundamental information on diffusion in materials and are the foundation of robust diffusion databases. Compared to traditional radiotracer techniques that utilize radioactive isotopes, the secondary ion mass spectrometry (SIMS) based thin-film technique for tracer diffusion is based on the use of enriched stable isotopes that can be accurately profiled using SIMS. Experimental procedures & techniques that are utilized for the measurement of tracer diffusion coefficients are presented for pure magnesium, which presents some unique challenges due to the ease of oxidation. The development of a modified Shewmon-Rhines diffusion capsule for annealing Mg and an ultra-highmore » vacuum (UHV) system for sputter deposition of Mg isotopes are discussed. Optimized conditions for accurate SIMS depth profiling in polycrystalline Mg are provided. An automated procedure for the correction of heat-up and cool-down times during tracer diffusion annealing is discussed. The non-linear fitting of a SIMS depth profile data using the thin film Gaussian solution to obtain the tracer diffusivity along with the background tracer concentration and tracer film thickness is discussed. An Arrhenius fit of the Mg self-diffusion data obtained using the low-temperature SIMS measurements from this study and the high-temperature radiotracer measurements of Shewmon and Rhines (1954) was found to be a good representation of both types of diffusion data that cover a broad range of temperatures between 250 - 627° C (523 900 K).« less

  20. Highly Resolved Mg/Ca Depth Profiles of Planktic Foraminifer test Walls Using Single shot Measurements of fs-LA-ICPMS

    NASA Astrophysics Data System (ADS)

    Jochum, K. P.; Schiebel, R.; Stoll, B.; Weis, U.; Haug, G. H.

    2017-12-01

    Foraminifers are sensitive archives of changes in climate and marine environment. It has been shown that the Mg/Ca signal is a suitable proxy of seawater temperature, because the incorporation of Mg depends on ambient water temperature. In contrast to most former studies, where this ratio is determined by solution-based bulk analysis of 20 - 30 specimens, we have investigated Mg/Ca in single specimens and single chambers at high resolution. A new fs-200 nm-LA-ICPMS technique was developed for the µm-sized layered calcite shells. To generate depth profiles with a resolution of about 50 nm/shot, we chose a low fluence of about 0.3 Jcm-2 and performed single shot measurements of the double charged 44Ca++ and the single charged 25Mg+ ions together. Precision (RSD) of the Mg/Ca data is about 5 %. Calibration was performed with the carbonate reference material MACS-3 from the USGS. Our results for different species from the Arabian Sea and Caribbean Sea demonstrate that Mg/Ca of different chambers vary and indicate that the foraminifer individuals built their chambers in different water depths and/or experienced seasonal changes in seawater temperature caused, for example, by upwelling (cold) versus stratified (warm) conditions. Typically, the Mg/Ca ratios of the final two chambers of the planktic foraminifer Globorotalia menardii from a sediment core of the Arabian Sea differ by about 5 mmol/mol from earlier chambers (2 mmol/mol) corresponding to seawater temperatures of 28 °C and 18 °C, respectively. In addition, mass fractions of other elements like Sr, Mn, Fe, Ba, and U have been determined with fs-LA-ICPMS using fast line scans, and thus provide further insights in the ecology of foraminifers.

  1. Depth Profiles of Mg, Si, and Zn Implants in GaN by Trace Element Accelerator Mass Spectrometry

    NASA Astrophysics Data System (ADS)

    Ravi Prasad, G. V.; Pelicon, P.; Mitchell, L. J.; McDaniel, F. D.

    2003-08-01

    GaN is one of the most promising electronic materials for applications requiring high-power, high frequencies, or high-temperatures as well as opto-electronics in the blue to ultraviolet spectral region. We have recently measured depth profiles of Mg, Si, and Zn implants in GaN substrates by the TEAMS particle counting method for both matrix and trace elements, using a gas ionization chamber. Trace Element Accelerator Mass Spectrometry (TEAMS) is a combination of Secondary Ion Mass Spectrometry (SIMS) and Accelerator Mass Spectrometry (AMS) to measure trace elements at ppb levels. Negative ions from a SIMS like source are injected into a tandem accelerator. Molecular interferences inherent with the SIMS method are eliminated in the TEAMS method. Negative ion currents are extremely low with GaN as neither gallium nor nitrogen readily forms negative ions making the depth profile measurements more difficult. The energies of the measured ions are in the range of 4-8 MeV. A careful selection of mass/charge ratios of the detected ions combined with energy-loss behavior of the ions in the ionization chamber eliminated molecular interferences.

  2. Comparison of Two Global Ocean Reanalyses, NRL Global Ocean Forecast System (GOFS) and U. Maryland Simple Ocean Data Assimilation (SODA)

    NASA Astrophysics Data System (ADS)

    Richman, J. G.; Shriver, J. F.; Metzger, E. J.; Hogan, P. J.; Smedstad, O. M.

    2017-12-01

    The Oceanography Division of the Naval Research Laboratory recently completed a 23-year (1993-2015) coupled ocean-sea ice reanalysis forced by NCEP CFS reanalysis fluxes. The reanalysis uses the Global Ocean Forecast System (GOFS) framework of the HYbrid Coordinate Ocean Model (HYCOM) and the Los Alamos Community Ice CodE (CICE) and the Navy Coupled Ocean Data Assimilation 3D Var system (NCODA). The ocean model has 41 layers and an equatorial resolution of 0.08° (8.8 km) on a tri-polar grid with the sea ice model on the same grid that reduces to 3.5 km at the North Pole. Sea surface temperature (SST), sea surface height (SSH) and temperature-salinity profile data are assimilated into the ocean every day. The SSH anomalies are converted into synthetic profiles of temperature and salinity prior to assimilation. Incremental analysis updating of geostrophically balanced increments is performed over a 6-hour insertion window. Sea ice concentration is assimilated into the sea ice model every day. Following the lead of the Ocean Reanalysis Intercomparison Project (ORA-IP), the monthly mean upper ocean heat and salt content from the surface to 300 m, 700m and 1500 m, the mixed layer depth, the depth of the 20°C isotherm, the steric sea surface height and the Atlantic Meridional Overturning Circulation for the GOFS reanalysis and the Simple Ocean Data Assimilation (SODA 3.3.1) eddy-permitting reanalysis have been compared on a global uniform 0.5° grid. The differences between the two ocean reanalyses in heat and salt content increase with increasing integration depth. Globally, GOFS trends to be colder than SODA at all depth. Warming trends are observed at all depths over the 23 year period. The correlation of the upper ocean heat content is significant above 700 m. Prior to 2004, differences in the data assimilated lead to larger biases. The GOFS reanalysis assimilates SSH as profile data, while SODA doesn't. Large differences are found in the Western Boundary Currents, Southern Ocean and equatorial regions. In the Indian Ocean, the Equatorial Counter Current extends to far to the east and the subsurface flow in the thermocline is too weak in GOFS. The 20°C isotherm is biased 2 m shallow in SODA compared to GOFS, but the monthly anomalies in the depth are highly correlated.

  3. Proceedings of a Seminar on Water Quality Data Interpretation, 8-9 February 1978, Atlanta, Georgia.

    DTIC Science & Technology

    1978-01-01

    patterns of growth are confused by variable rates of mortality and internal translocations of mass above and below ground. The oxygen technique...top of the heavier 40 C water. Second and more important, the density of water decreases with an escalating rate with increasing temperatures above...including the amount of oxidizable material, the settling rate of the oxidizable material, the water temperature, and the bottom profile and depth of

  4. Anomalies of the upper water column in the Mediterranean Sea

    NASA Astrophysics Data System (ADS)

    Rivetti, Irene; Boero, Ferdinando; Fraschetti, Simonetta; Zambianchi, Enrico; Lionello, Piero

    2017-04-01

    The evolution of the upper water column in the Mediterranean Sea during more than 60 years is reconstructed in terms of few parameters describing the mixed layer and the seasonal thermocline. The analysis covers the period 1945-2011 using data from three public sources: MEDAR-MEDATLAS, World Ocean Database, MFS-VOS program. Five procedures for estimating the mixed layer depth are described, discussed and compared using the 20-year long time series of temperature profiles of the DYFAMED station in the Ligurian Sea. On this basis the so-called three segments profile model (which approximates the upper water column with three segments representing mixed layer, thermocline and deep layer) has been selected for a systematic analysis at Mediterranean scale. A widespread increase of the thickness and temperature of the mixed layer, increase of the depth and decrease of the temperature of the thermocline base have been observed in summer and autumn during the recent decades. It is shown that positive temperature extremes of the mixed layer and of its thickness are potential drivers of the mass mortalities of benthic invertebrates documented since 1983. Hotspots of mixed layer anomalies have been also identified. These results refine previous analyses showing that ongoing and future warming of upper Mediterranean is likely to increase mass mortalities by producing environmental conditions beyond the limit of tolerance of some benthic species.

  5. SCSPOD14, a South China Sea physical oceanographic dataset derived from in situ measurements during 1919-2014.

    PubMed

    Zeng, Lili; Wang, Dongxiao; Chen, Ju; Wang, Weiqiang; Chen, Rongyu

    2016-04-26

    In addition to the oceanographic data available for the South China Sea (SCS) from the World Ocean Database (WOD) and Array for Real-time Geostrophic Oceanography (Argo) floats, a suite of observations has been made by the South China Sea Institute of Oceanology (SCSIO) starting from the 1970s. Here, we assemble a SCS Physical Oceanographic Dataset (SCSPOD14) based on 51,392 validated temperature and salinity profiles collected from these three datasets for the period 1919-2014. A gridded dataset of climatological monthly mean temperature, salinity, and mixed and isothermal layer depth derived from an objective analysis of profiles is also presented. Comparisons with the World Ocean Atlas (WOA) and IFREMER/LOS Mixed Layer Depth Climatology confirm the reliability of the new dataset. This unique dataset offers an invaluable baseline perspective on the thermodynamic processes, spatial and temporal variability of water masses, and basin-scale and mesoscale oceanic structures in the SCS. We anticipate improvements and regular updates to this product as more observations become available from existing and future in situ networks.

  6. SCSPOD14, a South China Sea physical oceanographic dataset derived from in situ measurements during 1919–2014

    PubMed Central

    Zeng, Lili; Wang, Dongxiao; Chen, Ju; Wang, Weiqiang; Chen, Rongyu

    2016-01-01

    In addition to the oceanographic data available for the South China Sea (SCS) from the World Ocean Database (WOD) and Array for Real-time Geostrophic Oceanography (Argo) floats, a suite of observations has been made by the South China Sea Institute of Oceanology (SCSIO) starting from the 1970s. Here, we assemble a SCS Physical Oceanographic Dataset (SCSPOD14) based on 51,392 validated temperature and salinity profiles collected from these three datasets for the period 1919–2014. A gridded dataset of climatological monthly mean temperature, salinity, and mixed and isothermal layer depth derived from an objective analysis of profiles is also presented. Comparisons with the World Ocean Atlas (WOA) and IFREMER/LOS Mixed Layer Depth Climatology confirm the reliability of the new dataset. This unique dataset offers an invaluable baseline perspective on the thermodynamic processes, spatial and temporal variability of water masses, and basin-scale and mesoscale oceanic structures in the SCS. We anticipate improvements and regular updates to this product as more observations become available from existing and future in situ networks. PMID:27116565

  7. XPS and SIMS study of the surface and interface of aged C + implanted uranium

    DOE PAGES

    Donald, Scott B.; Siekhaus, Wigbert J.; Nelson, Art J.

    2016-09-08

    X-ray photoelectron spectroscopy in combination with secondary ion mass spectrometry depth profiling were used to investigate the surface and interfacial chemistry of C + ion implanted polycrystalline uranium subsequently oxidized in air for over 10 years at ambient temperature. The original implantation of 33 keV C + ions into U 238 with a dose of 4.3 × 10 17 cm –3 produced a physically and chemically modified surface layer that was characterized and shown to initially prevent air oxidation and corrosion of the uranium after 1 year in air at ambient temperature. The aging of the surface and interfacial layersmore » were examined by using the chemical shift of the U 4f, C 1s, and O 1s photoelectron lines. In addition, valence band spectra were used to explore the electronic structure of the aged carbide surface and interface layer. Moreover, the time-of-flight secondary ion mass spectrometry depth profiling results for the aged sample confirmed an oxidized uranium carbide layer over the carbide layer/U metal interface.« less

  8. An analysis of the vertical structure equation for arbitrary thermal profiles

    NASA Technical Reports Server (NTRS)

    Cohn, Stephen E.; Dee, Dick P.

    1989-01-01

    The vertical structure equation is a singular Sturm-Liouville problem whose eigenfunctions describe the vertical dependence of the normal modes of the primitive equations linearized about a given thermal profile. The eigenvalues give the equivalent depths of the modes. The spectrum of the vertical structure equation and the appropriateness of various upper boundary conditions, both for arbitrary thermal profiles were studied. The results depend critically upon whether or not the thermal profile is such that the basic state atmosphere is bounded. In the case of a bounded atmosphere it is shown that the spectrum is always totally discrete, regardless of details of the thermal profile. For the barotropic equivalent depth, which corresponds to the lowest eigen value, upper and lower bounds which depend only on the surface temperature and the atmosphere height were obtained. All eigenfunctions are bounded, but always have unbounded first derivatives. It was proved that the commonly invoked upper boundary condition that vertical velocity must vanish as pressure tends to zero, as well as a number of alternative conditions, is well posed. It was concluded that the vertical structure equation always has a totally discrete spectrum under the assumptions implicit in the primitive equations.

  9. An analysis of the vertical structure equation for arbitrary thermal profiles

    NASA Technical Reports Server (NTRS)

    Cohn, Stephen E.; Dee, Dick P.

    1987-01-01

    The vertical structure equation is a singular Sturm-Liouville problem whose eigenfunctions describe the vertical dependence of the normal modes of the primitive equations linearized about a given thermal profile. The eigenvalues give the equivalent depths of the modes. The spectrum of the vertical structure equation and the appropriateness of various upper boundary conditions, both for arbitrary thermal profiles were studied. The results depend critically upon whether or not the thermal profile is such that the basic state atmosphere is bounded. In the case of a bounded atmosphere it is shown that the spectrum is always totally discrete, regardless of details of the thermal profile. For the barotropic equivalent depth, which corresponds to the lowest eigen value, upper and lower bounds which depend only on the surface temperature and the atmosphere height were obtained. All eigenfunctions are bounded, but always have unbounded first derivatives. It was proved that the commonly invoked upper boundary condition that vertical velocity must vanish as pressure tends to zero, as well as a number of alternative conditions, is well posed. It was concluded that the vertical structure equation always has a totally discrete spectrum under the assumptions implicit in the primitive equations.

  10. High-Frequency Focused Water-Coupled Ultrasound Used for Three-Dimensional Surface Depression Profiling

    NASA Technical Reports Server (NTRS)

    Roth, Don J.; Whalen, Mike F.; Hendricks, J. Lynne; Bodis, James R.

    2001-01-01

    To interface with other solids, many surfaces are engineered via methods such as plating, coating, and machining to produce a functional surface ensuring successful end products. In addition, subsurface properties such as hardness, residual stress, deformation, chemical composition, and microstructure are often linked to surface characteristics. Surface topography, therefore, contains the signatures of the surface and possibly links to volumetric properties, and as a result serves as a vital link between surface design, manufacturing, and performance. Hence, surface topography can be used to diagnose, monitor, and control fabrication methods. At the NASA Glenn Research Center, the measurement of surface topography is important in developing high-temperature structural materials and for profiling the surface changes of materials during microgravity combustion experiments. A prior study demonstrated that focused air-coupled ultrasound at 1 MHz could profile surfaces with a 25-m depth resolution and a 400-m lateral resolution over a 1.4-mm depth range. In this work, we address the question of whether higher frequency focused water-coupled ultrasound can improve on these specifications. To this end, we employed 10- and 25-MHz focused ultrasonic transducers in the water-coupled mode. The surface profile results seen in this investigation for 25-MHz water-coupled ultrasound, in comparison to those for 1-MHz air-coupled ultrasound, represent an 8 times improvement in depth resolution (3 vs. 25 m seen in practice), an improvement of at least 2 times in lateral resolution (180 vs. 400 m calculated and observed in practice), and an improvement in vertical depth range of 4 times (calculated).

  11. Physical and Chemical Behaviors of HCl on Ice Surface: Insights from an XPS and NEXAFS Study

    NASA Astrophysics Data System (ADS)

    Kong, X.; Waldner, A.; Orlando, F.; Birrer, M.; Artiglia, L.; Ammann, M.; Bartels-Rausch, T.

    2016-12-01

    Ice and snow play active roles for the water cycle, the energy budget of the Earth, and environmental chemistry in the atmosphere and cryosphere. Trace gases can be taken up by ice, and physical and chemical fates of the impurities could modify surface properties significantly and consequently influence atmospheric chemistry and the climate system. However, the understanding of chemical behaviour of impurities on ice surface are very poor, which is largely limited by the difficulties to apply high sensitivity experimental approaches to ambient air conditions, e.g. studies of volatile surfaces, because of the strict requirements of vacuum experimental conditions. In this study, we employed synchrotron-based X-ray photoelectron spectroscopy (XPS) and partial electron yield Near Edge X-ray Absorption Fine Structure (NEXAFS) in a state-of-the-art near-ambient pressure photoelectron (NAPP) spectroscopy end station. The NAPP enables to utilize the surface sensitive experimental methods, XPS and NEXAFS, on volatile surfaces, i.e. ice at temperatures approaching 0°C. XPS and NEXAFS together provide unique information of hydrogen bonding network, dopants surface concentration, dopant depth profile, and acidic dissociation on the surfaces1. Taking the advantages of the highly sensitive techniques, the adsorption, dissociation and depth profile of Hydrogen Chloride (HCl) on ice were studied. In brief, two states of Chloride on ice surface are identified from the adsorbed HCl, and they are featured with different depth profiles along the ice layers. Combining our results and previously reported constants from literatures (e.g. HCl diffusion coefficients in ice)2, a layered kinetic model has been constructed to fit the depth profiles of two states of Chloride. On the other side, pure ice and doped ice are compared for their surface structure change caused by temperature and the presence of HCl, which shows how the strong acid affect the ice surface in turn. 1. Orlando, F., et al., Top Catal 2016, 59, 591-604. 2. Huthwelker, T.; Malmstrom, M. E.; Helleis, F.; Moortgat, G. K.; Peter, T., J Phys Chem A 2004, 108, 6302-6318.

  12. Diversity of Methane-Oxidizing Bacteria in Soils from “Hot Lands of Medolla” (Italy) Featured by Anomalous High-Temperatures and Biogenic CO2 Emission

    PubMed Central

    Cappelletti, Martina; Ghezzi, Daniele; Zannoni, Davide; Capaccioni, Bruno; Fedi, Stefano

    2016-01-01

    “Terre Calde di Medolla” (TCM) (literally, “Hot Lands of Medolla”) refers to a farming area in Italy with anomalously high temperatures and diffuse emissions of biogenic CO2, which has been linked to CH4 oxidation processes from a depth of 0.7 m to the surface. We herein assessed the composition of the total bacterial community and diversity of methane-oxidizing bacteria (MOB) in soil samples collected at a depth at which the peak temperature was detected (0.6 m). Cultivation-independent methods were used, such as: i) a clone library analysis of the 16S rRNA gene and pmoA (coding for the α-subunit of the particulate methane monooxygenase) gene, and ii) Terminal Restriction Fragment Length Polymorphism (T-RFLP) fingerprinting. The 16S rRNA gene analysis assessed the predominance of Actinobacteria, Acidobacteria, Proteobacteria, and Bacillus in TCM samples collected at a depth of 0.6 m along with the presence of methanotrophs (Methylocaldum and Methylobacter) and methylotrophs (Methylobacillus). The phylogenetic analysis of pmoA sequences showed the presence of MOB affiliated with Methylomonas, Methylocystis, Methylococcus, and Methylocaldum in addition to as yet uncultivated and uncharacterized methanotrophs. Jaccard’s analysis of T-RFLP profiles at different ground depths revealed a similar MOB composition in soil samples at depths of 0.6 m and 0.7 m, while this similarity was weaker between these samples and those taken at a depth of 2.5 m, in which the genus Methylocaldum was absent. These results correlate the anomalously high temperatures of the farming area of “Terre Calde di Medolla” with the presence of microbial methane-oxidizing bacteria. PMID:27645100

  13. Diversity of Methane-Oxidizing Bacteria in Soils from "Hot Lands of Medolla" (Italy) Featured by Anomalous High-Temperatures and Biogenic CO2 Emission.

    PubMed

    Cappelletti, Martina; Ghezzi, Daniele; Zannoni, Davide; Capaccioni, Bruno; Fedi, Stefano

    2016-12-23

    "Terre Calde di Medolla" (TCM) (literally, "Hot Lands of Medolla") refers to a farming area in Italy with anomalously high temperatures and diffuse emissions of biogenic CO 2 , which has been linked to CH 4 oxidation processes from a depth of 0.7 m to the surface. We herein assessed the composition of the total bacterial community and diversity of methane-oxidizing bacteria (MOB) in soil samples collected at a depth at which the peak temperature was detected (0.6 m). Cultivation-independent methods were used, such as: i) a clone library analysis of the 16S rRNA gene and pmoA (coding for the α-subunit of the particulate methane monooxygenase) gene, and ii) Terminal Restriction Fragment Length Polymorphism (T-RFLP) fingerprinting. The 16S rRNA gene analysis assessed the predominance of Actinobacteria, Acidobacteria, Proteobacteria, and Bacillus in TCM samples collected at a depth of 0.6 m along with the presence of methanotrophs (Methylocaldum and Methylobacter) and methylotrophs (Methylobacillus). The phylogenetic analysis of pmoA sequences showed the presence of MOB affiliated with Methylomonas, Methylocystis, Methylococcus, and Methylocaldum in addition to as yet uncultivated and uncharacterized methanotrophs. Jaccard's analysis of T-RFLP profiles at different ground depths revealed a similar MOB composition in soil samples at depths of 0.6 m and 0.7 m, while this similarity was weaker between these samples and those taken at a depth of 2.5 m, in which the genus Methylocaldum was absent. These results correlate the anomalously high temperatures of the farming area of "Terre Calde di Medolla" with the presence of microbial methane-oxidizing bacteria.

  14. Episodic thermal perturbations associated with groundwater flow: An example from Kilauea Volcano, Hawaii

    USGS Publications Warehouse

    Hurwitz, S.; Ingebritsen, S.E.; Sorey, M.L.

    2002-01-01

    Temperature measurements in deep drill holes on volcano summits or upper flanks allow a quantitative analysis of groundwater induced heat transport within the edifice. We present a new temperature-depth profile from a deep well on the summit of Kilauea Volcano, Hawaii, and analyze it in conjunction with a temperature profile measured 26 years earlier. We propose two groundwater flow models to interpret the complex temperature profiles. The first is a modified confined lateral flow model (CLFM) with a continuous flux of hydrothermal fluid. In the second, transient flow model (TFM), slow conductive cooling follows a brief, advective heating event. We carry out numerical simulations to examine the timescales associated with each of the models. Results for both models are sensitive to the initial conditions, and with realistic initial conditions it takes between 750 and 1000 simulation years for either model to match the measured temperature profiles. With somewhat hotter initial conditions, results are consistent with onset of a hydrothermal plume ???550 years ago, coincident with initiation of caldera subsidence. We show that the TFM is consistent with other data from hydrothermal systems and laboratory experiments and perhaps is more appropriate for this highly dynamic environment. The TFM implies that volcano-hydrothermal systems may be dominated by episodic events and that thermal perturbations may persist for several thousand years after hydrothermal flow has ceased.

  15. Upper limit for the effect of elastic bending stress on the saturation magnetization of L a0.8S r0.2Mn O3

    NASA Astrophysics Data System (ADS)

    Wang, Q.; Chen, A. P.; Guo, E. J.; Roldan, M. A.; Jia, Q. X.; Fitzsimmons, M. R.

    2018-01-01

    Using polarized neutron reflectometry, we measured the influence of elastic bending stress on the magnetization depth profile of a L a0.8S r0.2Mn O3 (LSMO) epitaxial film grown on a SrTi O3 substrate. The elastic bending strain of ±0.03 % has no obvious effect on the magnetization depth profile at saturation. This result is in stark contrast to that of (L a1 -xP rx)1 -y C ayMn O3 (LPCMO) films for which strain of ±0.01 % produced dramatic changes in the magnetization profile and Curie temperature. We attribute the difference between the influence of strain on the saturation magnetization in LSMO (weak or none) and LPCMO (strong) to a difference in the ability of LSMO (weak or none) and LPCMO (strong) to phase separate. Our observation provides an upper limit of tuning LSMO saturation magnetization via elastic strain effect.

  16. Evaluation of HCMM data for assessing soil moisture and water table depth. [South Dakota

    NASA Technical Reports Server (NTRS)

    Moore, D. G.; Heilman, J. L.; Tunheim, J. A.; Westin, F. C.; Heilman, W. E.; Beutler, G. A.; Ness, S. D. (Principal Investigator)

    1981-01-01

    Soil moisture in the 0-cm to 4-cm layer could be estimated with 1-mm soil temperatures throughout the growing season of a rainfed barley crop in eastern South Dakota. Empirical equations were developed to reduce the effect of canopy cover when radiometrically estimating the soil temperature. Corrective equations were applied to an aircraft simulation of HCMM data for a diversity of crop types and land cover conditions to estimate the soil moisture. The average difference between observed and measured soil moisture was 1.6% of field capacity. Shallow alluvial aquifers were located with HCMM predawn data. After correcting the data for vegetation differences, equations were developed for predicting water table depths within the aquifer. A finite difference code simulating soil moisture and soil temperature shows that soils with different moisture profiles differed in soil temperatures in a well defined functional manner. A significant surface thermal anomaly was found to be associated with shallow water tables.

  17. The summit part of Mount Etna revealed by High Resolution DC Electrical Resistivity Tomography coupled with complementary geophysical and soil gas techniques

    NASA Astrophysics Data System (ADS)

    Finizola, Anthony; Ricci, Tullio; Antoine, Raphael; Delcher, Eric; Peltier, Aline; Bernard, Julien; Brothelande, Elodie; Fargier, Yannick; Fauchard, Cyrille; Foucart, Brice; Gailler, Lydie; Gusset, Rachel; Lazarte, Ivonne; Martin, Erwan; Mézon, Cécile; Portal, Angélie; Poret, Matthieu; Rossi, Matteo

    2016-04-01

    In the framework of the EC FP7 project "MEDiterranean SUpersite Volcanoes", one profile coupling DC electrical resistivity tomography (Pole-Dipole configuration with a remote electrode located between 8-10 km from the middle of the different acquisitions, 64 electrodes and 40 m spacing between the electrodes), self-potential, soil CO2 degassing, Radon measurements and sub-surface (30cm depth) temperature have been performed between June 25th and July 13th 2015. This profile, NE-SW direction, crossed the summit part of Mount Etna. A total 5720m of profile was performed, with a roll along protocol of 1/4 of the dispositive, for each new acquisitions. A total of 6 acquisitions was made to complete the entire profile. For the first time in the world, a multi-electrodes DC ERT profile, of high resolution (40 m of spacing between the electrodes) reached, thanks to a pole-dipole configuration, 900m for the depth of investigation. The ERT profile clearly evidences the hydrothermal system of Mount Etna: the lowest resistivity values are associated with a large scale positive self-potential anomaly, and smaller wavelength anomalies for temperature, CO2 concentration and Radon, in the area where the electrical conductor reach the surface. Structural discontinuities such as the Elliptic crater, was clearly evidenced by a sharp decrease of the self-potential values in the inner part of this crater. The striking result of this profile is the presence of a resistive body located just below the NE crater. This structure displays the highest degassing values of the entire profile. We interpret this resistive body as a consequence of the thermic over-heated plume rising from the top of the shallow feeding system. Indeed, above several hundred of degrees Celsuis, it is impossible to consider rain water infiltration and the presence of a wet hydrothermal system. The consequence would be therefore to obtain this resistive body, centred on the area of main heat transfer. Above this resistive body, we clearly note a preferential hydrothermal fluid flow, associated with maximum of self-potential anomaly, temperature and radon, and reaching the surface on the highest elevation area along the profile.

  18. Zonally asymmetric response of the Southern Ocean mixed-layer depth to the Southern Annular Mode

    NASA Astrophysics Data System (ADS)

    Sallée, J. B.; Speer, K. G.; Rintoul, S. R.

    2010-04-01

    Interactions between the atmosphere and ocean are mediated by the mixed layer at the ocean surface. The depth of this layer is determined by wind forcing and heating from the atmosphere. Variations in mixed-layer depth affect the rate of exchange between the atmosphere and deeper ocean, the capacity of the ocean to store heat and carbon and the availability of light and nutrients to support the growth of phytoplankton. However, the response of the Southern Ocean mixed layer to changes in the atmosphere is not well known. Here we analyse temperature and salinity data from Argo profiling floats to show that the Southern Annular Mode (SAM), the dominant mode of atmospheric variability in the Southern Hemisphere, leads to large-scale anomalies in mixed-layer depth that are zonally asymmetric. From a simple heat budget of the mixed layer we conclude that meridional winds associated with departures of the SAM from zonal symmetry cause anomalies in heat flux that can, in turn, explain the observed changes of mixed-layer depth and sea surface temperature. Our results suggest that changes in the SAM, including recent and projected trends attributed to human activity, drive variations in Southern Ocean mixed-layer depth, with consequences for air-sea exchange, ocean sequestration of heat and carbon, and biological productivity.

  19. A Spectrally Selective Attenuation Mechanism-Based Kpar Algorithm for Biomass Heating Effect Simulation in the Open Ocean

    NASA Astrophysics Data System (ADS)

    Chen, Jun; Zhang, Xiangguang; Xing, Xiaogang; Ishizaka, Joji; Yu, Zhifeng

    2017-12-01

    Quantifying the diffuse attenuation coefficient of the photosynthetically available radiation (Kpar) can improve our knowledge of euphotic depth (Zeu) and biomass heating effects in the upper layers of oceans. An algorithm to semianalytically derive Kpar from remote sensing reflectance (Rrs) is developed for the global open oceans. This algorithm includes the following two portions: (1) a neural network model for deriving the diffuse attention coefficients (Kd) that considers the residual error in satellite Rrs, and (2) a three band depth-dependent Kpar algorithm (TDKA) for describing the spectrally selective attenuation mechanism of underwater solar radiation in the open oceans. This algorithm is evaluated with both in situ PAR profile data and satellite images, and the results show that it can produce acceptable PAR profile estimations while clearly removing the impacts of satellite residual errors on Kpar estimations. Furthermore, the performance of the TDKA algorithm is evaluated by its applicability in Zeu derivation and mean temperature within a mixed layer depth (TML) simulation, and the results show that it can significantly decrease the uncertainty in both compared with the classical chlorophyll-a concentration-based Kpar algorithm. Finally, the TDKA algorithm is applied in simulating biomass heating effects in the Sargasso Sea near Bermuda, with new Kpar data it is found that the biomass heating effects can lead to a 3.4°C maximum positive difference in temperature in the upper layers but could result in a 0.67°C maximum negative difference in temperature in the deep layers.

  20. Multisensor Capacitance Probes for Simultaneously Monitoring Rice Field Soil-Water- Crop-Ambient Conditions.

    PubMed

    Brinkhoff, James; Hornbuckle, John; Dowling, Thomas

    2017-12-26

    Multisensor capacitance probes (MCPs) have traditionally been used for soil moisture monitoring and irrigation scheduling. This paper presents a new application of these probes, namely the simultaneous monitoring of ponded water level, soil moisture, and temperature profile, conditions which are particularly important for rice crops in temperate growing regions and for rice grown with prolonged periods of drying. WiFi-based loggers are used to concurrently collect the data from the MCPs and ultrasonic distance sensors (giving an independent reading of water depth). Models are fit to MCP water depth vs volumetric water content (VWC) characteristics from laboratory measurements, variability from probe-to-probe is assessed, and the methodology is verified using measurements from a rice field throughout a growing season. The root-mean-squared error of the water depth calculated from MCP VWC over the rice growing season was 6.6 mm. MCPs are used to simultaneously monitor ponded water depth, soil moisture content when ponded water is drained, and temperatures in root, water, crop and ambient zones. The insulation effect of ponded water against cold-temperature effects is demonstrated with low and high water levels. The developed approach offers advantages in gaining the full soil-plant-atmosphere continuum in a single robust sensor.

  1. Acclimation to different depths by the marine angiosperm Posidonia oceanica: transcriptomic and proteomic profiles

    PubMed Central

    Dattolo, Emanuela; Gu, Jenny; Bayer, Philipp E.; Mazzuca, Silvia; Serra, Ilia A.; Spadafora, Antonia; Bernardo, Letizia; Natali, Lucia; Cavallini, Andrea; Procaccini, Gabriele

    2013-01-01

    For seagrasses, seasonal and daily variations in light and temperature represent the mains factors driving their distribution along the bathymetric cline. Changes in these environmental factors, due to climatic and anthropogenic effects, can compromise their survival. In a framework of conservation and restoration, it becomes crucial to improve our knowledge about the physiological plasticity of seagrass species along environmental gradients. Here, we aimed to identify differences in transcriptomic and proteomic profiles, involved in the acclimation along the depth gradient in the seagrass Posidonia oceanica, and to improve the available molecular resources in this species, which is an important requisite for the application of eco-genomic approaches. To do that, from plant growing in shallow (−5 m) and deep (−25 m) portions of a single meadow, (i) we generated two reciprocal Expressed Sequences Tags (EST) libraries using a Suppressive Subtractive Hybridization (SSH) approach, to obtain depth/specific transcriptional profiles, and (ii) we identified proteins differentially expressed, using the highly innovative USIS mass spectrometry methodology, coupled with 1D-SDS electrophoresis and labeling free approach. Mass spectra were searched in the open source Global Proteome Machine (GPM) engine against plant databases and with the X!Tandem algorithm against a local database. Transcriptional analysis showed both quantitative and qualitative differences between depths. EST libraries had only the 3% of transcripts in common. A total of 315 peptides belonging to 64 proteins were identified by mass spectrometry. ATP synthase subunits were among the most abundant proteins in both conditions. Both approaches identified genes and proteins in pathways related to energy metabolism, transport and genetic information processing, that appear to be the most involved in depth acclimation in P. oceanica. Their putative rules in acclimation to depth were discussed. PMID:23785376

  2. Acclimation to different depths by the marine angiosperm Posidonia oceanica: transcriptomic and proteomic profiles.

    PubMed

    Dattolo, Emanuela; Gu, Jenny; Bayer, Philipp E; Mazzuca, Silvia; Serra, Ilia A; Spadafora, Antonia; Bernardo, Letizia; Natali, Lucia; Cavallini, Andrea; Procaccini, Gabriele

    2013-01-01

    For seagrasses, seasonal and daily variations in light and temperature represent the mains factors driving their distribution along the bathymetric cline. Changes in these environmental factors, due to climatic and anthropogenic effects, can compromise their survival. In a framework of conservation and restoration, it becomes crucial to improve our knowledge about the physiological plasticity of seagrass species along environmental gradients. Here, we aimed to identify differences in transcriptomic and proteomic profiles, involved in the acclimation along the depth gradient in the seagrass Posidonia oceanica, and to improve the available molecular resources in this species, which is an important requisite for the application of eco-genomic approaches. To do that, from plant growing in shallow (-5 m) and deep (-25 m) portions of a single meadow, (i) we generated two reciprocal Expressed Sequences Tags (EST) libraries using a Suppressive Subtractive Hybridization (SSH) approach, to obtain depth/specific transcriptional profiles, and (ii) we identified proteins differentially expressed, using the highly innovative USIS mass spectrometry methodology, coupled with 1D-SDS electrophoresis and labeling free approach. Mass spectra were searched in the open source Global Proteome Machine (GPM) engine against plant databases and with the X!Tandem algorithm against a local database. Transcriptional analysis showed both quantitative and qualitative differences between depths. EST libraries had only the 3% of transcripts in common. A total of 315 peptides belonging to 64 proteins were identified by mass spectrometry. ATP synthase subunits were among the most abundant proteins in both conditions. Both approaches identified genes and proteins in pathways related to energy metabolism, transport and genetic information processing, that appear to be the most involved in depth acclimation in P. oceanica. Their putative rules in acclimation to depth were discussed.

  3. Temperature sensitivity differences with depth and season between carbon, nitrogen, and phosphorus cycling enzyme activities in an ombrotrophic peatland system

    NASA Astrophysics Data System (ADS)

    Steinweg, J. M.; Kostka, J. E.; Hanson, P. J.; Schadt, C. W.

    2017-12-01

    Northern peatlands have large amounts of soil organic matter due to reduced decomposition. Breakdown of organic matter is initially mediated by extracellular enzymes, the activity of which may be controlled by temperature, moisture, and substrate availability, all of which vary seasonally throughout the year and with depth. In typical soils the majority of the microbial biomass and decomposition occurs within the top 30cm due to reduced organic matter inputs in the subsurface however peatlands by their very nature contain large amounts of organic matter throughout their depth profile. We hypothesized that potential enzyme activity would be greatest at the surface of the peat due to a larger microbial biomass compared to 40cm and 175cm below the surface and that temperature sensitivity would be greatest at the surface during winter but lowest during the summer due to high temperatures and enzyme efficiency. Peat samples were collected in February, July, and August 2012 from the DOE Spruce and Peatland Responses Under Climatic and Environmental Change project at Marcell Experimental Forest S1 bog. We measured potential activity of hydrolytic enzymes involved in three different nutrient cycles: beta-glucosidase (carbon), leucine amino peptidase (nitrogen), and phosphatase (phosphorus) at 15 temperature points ranging from 3°C to 65°C. Enzyme activity decreased with depth as expected but there was no concurrent change in activation energy (Ea). The reduction in enzyme activity with depth indicates a smaller pool which coincided with a decreased microbial biomass. Differences in enzyme activity with depth also mirrored the changes in peat composition from the acrotelm to the catotelm. Season did play a role in temperature sensitivity with Ea of β-glucosidase and phosphatase being the lowest in August as expected but leucine amino peptidase (a nitrogen acquiring enzyme) Ea was not influenced by season. As temperatures rise, especially in winter months, enzymatic carbon and phosphorus acquisition in the Marcell bog may increase whereas nitrogen acquisition would remain unchanged. The lack of temperature response for leucine amino peptidase has been measured in other systems but may be less of a concern in the Marcell bog due to low microbial biomass and enzymatic activity at depth and relatively low peat C:N ratios.

  4. X-ray Photoelectron Spectroscopy of High-κ Dielectrics

    NASA Astrophysics Data System (ADS)

    Mathew, A.; Demirkan, K.; Wang, C.-G.; Wilk, G. D.; Watson, D. G.; Opila, R. L.

    2005-09-01

    Photoelectron spectroscopy is a powerful technique for the analysis of gate dielectrics because it can determine the elemental composition, the chemical states, and the compositional depth profiles non-destructively. The sampling depth, determined by the escape depth of the photoelectrons, is comparable to the thickness of current gate oxides. A maximum entropy algorithm was used to convert photoelectron collection angle dependence of the spectra to compositional depth profiles. A nitrided hafnium silicate film is used to demonstrate the utility of the technique. The algorithm balances deviations from a simple assumed depth profile against a calculated depth profile that best fits the angular dependence of the photoelectron spectra. A flow chart of the program is included in this paper. The development of the profile is also shown as the program is iterated. Limitations of the technique include the electron escape depths and elemental sensitivity factors used to calculate the profile. The technique is also limited to profiles that extend to the depth of approximately twice the escape depth. These limitations restrict conclusions to comparison among a family of similar samples. Absolute conclusions about depths and concentrations must be used cautiously. Current work to improve the algorithm is also described.

  5. Quantitative evaluation of sputtering induced surface roughness and its influence on AES depth profiles of polycrystalline Ni/Cu multilayer thin films

    NASA Astrophysics Data System (ADS)

    Yan, X. L.; Coetsee, E.; Wang, J. Y.; Swart, H. C.; Terblans, J. J.

    2017-07-01

    The polycrystalline Ni/Cu multilayer thin films consisting of 8 alternating layers of Ni and Cu were deposited on a SiO2 substrate by means of electron beam evaporation in a high vacuum. Concentration-depth profiles of the as-deposited multilayered Ni/Cu thin films were determined with Auger electron spectroscopy (AES) in combination with Ar+ ion sputtering, under various bombardment conditions with the samples been stationary as well as rotating in some cases. The Mixing-Roughness-Information depth (MRI) model used for the fittings of the concentration-depth profiles accounts for the interface broadening of the experimental depth profiling. The interface broadening incorporates the effects of atomic mixing, surface roughness and information depth of the Auger electrons. The roughness values extracted from the MRI model fitting of the depth profiling data agrees well with those measured by atomic force microscopy (AFM). The ion sputtering induced surface roughness during the depth profiling was accordingly quantitatively evaluated from the fitted MRI parameters with sample rotation and stationary conditions. The depth resolutions of the AES depth profiles were derived directly from the values determined by the fitting parameters in the MRI model.

  6. Depth perception: the need to report ocean biogeochemical rates as functions of temperature, not depth

    NASA Astrophysics Data System (ADS)

    Brewer, Peter G.; Peltzer, Edward T.

    2017-08-01

    For over 50 years, ocean scientists have oddly represented ocean oxygen consumption rates as a function of depth but not temperature in most biogeochemical models. This unique tradition or tactic inhibits useful discussion of climate change impacts, where specific and fundamental temperature-dependent terms are required. Tracer-based determinations of oxygen consumption rates in the deep sea are nearly universally reported as a function of depth in spite of their well-known microbial basis. In recent work, we have shown that a carefully determined profile of oxygen consumption rates in the Sargasso Sea can be well represented by a classical Arrhenius function with an activation energy of 86.5 kJ mol-1, leading to a Q10 of 3.63. This indicates that for 2°C warming, we will have a 29% increase in ocean oxygen consumption rates, and for 3°C warming, a 47% increase, potentially leading to large-scale ocean hypoxia should a sufficient amount of organic matter be available to microbes. Here, we show that the same principles apply to a worldwide collation of tracer-based oxygen consumption rate data and that some 95% of ocean oxygen consumption is driven by temperature, not depth, and thus will have a strong climate dependence. The Arrhenius/Eyring equations are no simple panacea and they require a non-equilibrium steady state to exist. Where transient events are in progress, this stricture is not obeyed and we show one such possible example. This article is part of the themed issue 'Ocean ventilation and deoxygenation in a warming world'.

  7. A Search for HI Self-Absorption in the SGPS

    NASA Astrophysics Data System (ADS)

    Kavars, D. W.; Dickey, J. D.; McClure-Griffiths, N. M.; Gaensler, B. M.; Green, A. J.

    2003-12-01

    Using data from the Southern Galactic Plane Survey(SGPS) we present a routine to search for cold HI clouds in the Galaxy, based on their HI self-absorption(HISA) signature. The data was obtained using the Australia Telescope Compact Array and the Parkes Radio Telescope. The SGPS, because of its good angular and velocity resolution, is excellent for searching for HISA clouds. We have already analyzed a few of the more prominent HISA features, finding spin temperatures, Ts ˜ 20K, column densities, NHI ˜ 2 x 1020}cm{-2, and optical depths of ˜ 1. The next step is to search the entire SGPS. A search by eye is possible, but is biased towards the most pronounced features. To better understand the role HISA plays in the ISM, an automated search technique is required. Our routine takes the first and second derivatives of the HI emission brightness temperature with respect to velocity. Due to the sharp drop in the emission profile through a HISA cloud, the derivative profiles show characteristic positive and/or negative peaks. These peaks represent a population of clouds separate from random HI emission fluctuations. By setting thresholds on the derivative maps and defining HISA only if it passes both derivative tests, we can build an unbiased catalog of HISA candidates in the Galaxy. The number distribution can be used to put constraints on the parameters used to find the spin temperature and optical depth, allowing us to more accurately determine the temperature, column density, and optical depth distribution of HISA clouds. We also compare HISA with 12CO emission. In the Inner Galaxy from l=313 deg to l=338 deg we find 30-50% of HISA is associated with 12CO at a brightness temperature of at least 1K. This work was supported by NSF grant AST 97-32695 to the University of Minnesota.

  8. The mineralogy of global magnetic anomalies

    NASA Technical Reports Server (NTRS)

    Haggerty, S. E. (Principal Investigator)

    1981-01-01

    Progress is reported in developing predictive abilities to evaluate the potential stabilities of magnetic minerals in the Earth crust and mantle by: (1) computing oxidation state profiling as a function of temperature and pressure; (2) compiling data on basalts to establish validity of the oxidation state profiles; (3) determining Fe-Ni alloys in association with magnetitie as a function of temperature and oxidation state; and (4) acquiring large chemical data banks on the mineral ilmenite which decomposes to mineral spinel in the presence of high sulfur or carbonate environments in the lower crust upper mantle. In addition to acquiring these data which are related to constraining Curie isotherm depths, an excellent correlation was found between MAGSAT anomaly data and the geology of West Africa.

  9. Surface topographical changes measured by phase-locked interferometry

    NASA Technical Reports Server (NTRS)

    Lauer, J. L.; Fung, S. S.

    1984-01-01

    An electronic optical laser interferometer capable of resolving depth differences of as low as 30 A and planar displacements of 6000 A was constructed to examine surface profiles of bearing surfaces without physical contact. Topological chemical reactivity was determined by applying a drop of dilute alcoholic hydrochloric acid and measuring the profile of the solid surface before and after application of this probe. Scuffed bearing surfaces reacted much faster than virgin ones but that bearing surfaces exposed to lubricants containing an organic chloride reacted much more slowly. The reactivity of stainless steel plates, heated in a nitrogen atmosphere to different temperatures, were examined later at ambient temperature. The change of surface contour as a result of the probe reaction followed Arrhenius-type relation with respect to heat treatment temperature. The contact area of the plate of a ball/plate sliding elastohydrodynamic contact run on trimethylopropane triheptanoate with or without additives was optically profiled periodically. As scuffing was approached, the change of profile within the contact region changed much more rapidly by the acid probe and assumed a constant high value after scuffing. A nonetching metallurgical phase was found in the scuff mark, which was apparently responsible for the high reactivity.

  10. CREST-SAFE: Snow LST validation, wetness profiler creation, and depth/SWE product development

    NASA Astrophysics Data System (ADS)

    Perez Diaz, C. L.; Lakhankar, T.; Romanov, P.; Khanbilvardi, R.; Munoz Barreto, J.; Yu, Y.

    2017-12-01

    CREST-SAFE: Snow LST validation, wetness profiler creation, and depth/SWE product development The Field Snow Research Station (also referred to as Snow Analysis and Field Experiment, SAFE) is operated by the NOAA Center for Earth System Sciences and Remote Sensing Technologies (CREST) in the City University of New York (CUNY). The field station is located within the premises of the Caribou Municipal Airport (46°52'59'' N, 68°01'07'' W) and in close proximity to the National Weather Service (NWS) Regional Forecast Office. The station was established in 2010 to support studies in snow physics and snow remote sensing. The Visible Infrared Imager Radiometer Suite (VIIRS) Land Surface Temperature (LST) Environmental Data Record (EDR) and Moderate Resolution Imaging Spectroradiometer (MODIS) LST product (provided by the Terra and Aqua Earth Observing System satellites) were validated using in situ LST (T-skin) and near-surface air temperature (T-air) observations recorded at CREST-SAFE for the winters of 2013 and 2014. Results indicate that T-air correlates better than T-skin with VIIRS LST data and that the accuracy of nighttime LST retrievals is considerably better than that of daytime. Several trends in the MODIS LST data were observed, including the underestimation of daytime values and night-time values. Results indicate that, although all the data sets showed high correlation with ground measurements, day values yielded slightly higher accuracy ( 1°C). Additionally, we created a liquid water content (LWC)-profiling instrument using time-domain reflectometry (TDR) at CREST-SAFE and tested it during the snow melt period (February-April) immediately after installation in 2014. Results displayed high agreement when compared to LWC estimates obtained using empirical formulas developed in previous studies, and minor improvement over wet snow LWC estimates. Lastly, to improve on global snow cover mapping, a snow product capable of estimating snow depth and snow water equivalent (SWE) using microwave remote sensing and the CREST Snow Depth Regression Tree Model (SDRTM) was developed. Data from AMSR2 onboard the JAXA GCOM-W1 satellite is used to produce daily global snow depth and SWE maps in automated fashion at a 10-km resolution.

  11. VERTICAL DIFFUSION IN SMALL STRATIFIED LAKES: DATA AND ERROR ANALYSIS

    EPA Science Inventory

    Water temperature profiles were measured at 2-min intervals in a stratified temperate lake with a surface area of 0.06 km2 and a aximum depth of 10 m from May 7 to August 9, 1989. he data were used to calculate the vertical eddy diffusion coefficient K2 in the hypolimnion. he dep...

  12. Ground-water temperature of the Wyoming quadrangle in central Delaware : with application to ground-water-source heat pumps

    USGS Publications Warehouse

    Hodges, Arthur L.

    1982-01-01

    Ground-water temperature was measured during a one-year period (1980-81) in 20 wells in the Wyoming Quadrangle in central Delaware. Data from thermistors set at fixed depths in two wells were collected twice each week, and vertical temperature profiles of the remaining 18 wells were made monthly. Ground-water temperature at 8 feet below land surface in well Jc55-1 ranged from 45.0 degrees F in February to 70.1 degrees F in September. Temperature at 35 feet below land surface in the same well reached a minimum of 56.0 degrees F in August, and a maximum of 57.8 degrees F in February. Average annual temperature of ground water at 25 feet below land surface in all wells ranged from 54.6 degrees F to 57.8 degrees F. Variations of average temperature probably reflect the presence or absence of forestation in the recharge areas of the wells. Ground-water-source heat pumps supplied with water from wells 30 or more feet below land surface will operate more efficiently in both heating and cooling modes than those supplied with water from shallower depths. (USGS)

  13. The Simulation of Temperature Field Based on 3D Modeling and Its Comparison versus Measured Temperature Distribution of Daqing Oilfield, NE China

    NASA Astrophysics Data System (ADS)

    Shi, Y.; Jiang, G.; Hu, S.

    2017-12-01

    Daqing, as the largest oil field of China with more than 50 years of exploration and production history for oil and gas, its geothermal energy utilization was started in 2000, with a main focus on district heating and direct use. In our ongoing study, data from multiple sources are collected, including BHT, DST, steady state temperature measurements in deep wells and thermophysical properties of formations. Based on these measurements, an elaborate investigation of the temperature field of Daqing Oilfield is made. Moreover, through exploration for oil and gas, subsurface geometry, depth, thickness and properties of the stratigraphic layers have been extensively delineated by well logs and seismic profiles. A 3D model of the study area is developed incorporating the information of structure, stratigraphy, basal heat flow, and petrophysical and thermophysical properties of strata. Based on the model, a simulation of the temperature field of Daqing Oilfield is generated. A purely conductive regime is presumed, as demonstrated by measured temperature log in deep wells. Wells W1, W2 and SK2 are used as key wells for model calibration. Among them, SK2, as part of the International Continental Deep Drilling Program, has a designed depth of 6400m, the steady state temperature measurement in the borehole has reached the depth of 4000m. The results of temperature distribution generated from simulation and investigation are compared, in order to evaluate the potential of applying the method to other sedimentary basins with limited borehole temperature measurements but available structural, stratigraphic and thermal regime information.

  14. Highlights from two years of geoelectrical monitoring of permafrost at the Magnetköpfl/Kitzsteinhorn

    NASA Astrophysics Data System (ADS)

    Jochum, Birgit; Ottowitz, David; Pfeiler, Stefan; Supper, Robert; Keuschnig, Markus; Hartmeyer, Ingo; Kim, Jung-Ho

    2014-05-01

    Changes of climate parameters due to global warming generate increased permafrost warming and deglaciation in alpine regions. The area of interest is the Magnetköpfl, a peak below the Kitzsteinhorn (3203 m), where scientists observe increasing rock instability due to the probable degradation of permafrost and the rapid lowering of the glacier surfaces adjacent to the rock faces (loss of natural abutment, exposure of rock to atmospheric influences). Geoelectric measurements are an adequate method to measure permafrost, since the underground electric resistivity is highly dependent on temperature and the amount of unfrozen pore water. In October 2011 a geoelectrical monitoring profile with the GEOMON4D was installed on the north facing ridge of the Magnetköpfl. Measurements of soil temperature on the profile support the interpretation of geoelectric data. Maximum active layer depth at the Magnetköpfl is approximately 3 m. Seasonal variations of ground temperature can be observed up to a depth of 8-10 m below surface. The two year period of data collection allows us to analyse time series of average apparent resistivities compared with the climatic seasons. It can be seen that different temperature periods have a direct correlation to average apparent resistivity. Inversion results of geoelectrical monitoring data are derived from an innovative 4D resistivity inversion approach (Kim et al, 2013). In three selected events (thawing and freezing in spring, thawing in summer, freezing in fall) difference images of the 4D inversion show the depth range of the temperature influence. The temperature sensors at the profile only reach 0.8 m below ground level.The geoelectrical monitoring data is able to deliver far more (thermal) information than single point temperature measurements since the underground electric resistivity is highly dependent on temperature. The geoelectrical monitoring is supported by the project "TEMPEL", funded by the Federal Ministry for Transport, Innovation & Technology (BMVIT) and the Austrian Science Fund (FWF): TRP 175-N21 and internal funds of the Geological Survey of Austria. The recording of the ground temperature is conducted within MOREXPERT administered by alpS - Centre for Climate Change Adaptation and the University of Salzburg. Kim J.-H., Supper R., Tsourlos P. and Yi M.-J. 2013. Four-dimensional inversion of resistivity monitoring data through Lp norm minimizations. Geophysical Journal International, 2013-11-21 Supper R., Ottowitz D., Jochum B., Römer A., Pfeiler S., Kauer S., Keuschnig M. and Ita A. Geoelectrical monitoring of frozen ground and permafrost in alpine areas: field studies and considerations towards an improved measuring technology. Near Surface Geophysics, 2014, 12, 93-115

  15. High Altitude, Wavelength-dependent Extinction in Titan's Atmosphere from the 2003 Nov. 14 Occultation

    NASA Astrophysics Data System (ADS)

    Zalucha, A.; Elliot, J. L.; Fitzsimmons, A.; Dhillon, V.; Marsh, T.; Hammel, H. B.; Irwin, P.; Thomas-Osip, J.; Taylor, F.

    2005-08-01

    A stellar occultation by Titan on 2003 Nov. 14 was observed from La Palma Observatory (Fitzsimmons et al., RAS Time Domain Astrophysics, 2004) using ULTRACAM with three Sloan filters: u', g', and i' (350, 480, and 770 nm, respectively; Dhillon and Marsh, NewAR, 25, 91, 2001). The latitudes probed during immersion and emersion were 1.1S and 1.8N, respectively. A central flash was seen in only the i' filter, indicating wavelength-dependent atmospheric extinction. The light curves were inverted to obtain six lower-limit temperature profiles between 360 and 500 km (30 and 2 microbar) altitude. The i' profiles agreed with the model of Yelle (ApJ, 383, 380, 1991) above 415 km (10 microbar). The temperature profiles are expected to be independent of wavelength; instead, it is found that the profiles obtained at different wavelengths diverged as altitude decreases, which implies significant extinction in the light curves. The onset of extinction occurred between 550 and 600 km (0.9 and 0.4 microbar) altitude with optical depth increasing below this height. This is ˜ 50-100 km higher than the detached haze layer seen by Cassini in 2004 (Porco et al., Nature, 434, 159, 2005). No discrete haze layers have yet been resolved in our data. Applying the model used by Elliot and Young (AJ, 103, 991,1992) gives the altitudes of optical depth equal to unity: 382 ± 5 km and 436 ± 5 km (u' immersion and emersion); 406 ± 4 km and 403 ± 10 km (g' immersion and emersion); and 345 ± 5 km and 326 ± 3 km (i' immersion and emersion). Another method shows that the optical depth behaved as a power law in wavelength, with exponent approximately -3. We gratefully acknowledge support from NSF grant AST-0073447 and NASA grant NNG04GF25G

  16. A holistic aging model for Li(NiMnCo)O2 based 18650 lithium-ion batteries

    NASA Astrophysics Data System (ADS)

    Schmalstieg, Johannes; Käbitz, Stefan; Ecker, Madeleine; Sauer, Dirk Uwe

    2014-07-01

    Knowledge on lithium-ion battery aging and lifetime estimation is a fundamental aspect for successful market introduction in high-priced goods like electric mobility. This paper illustrates the parameterization of a holistic aging model from accelerated aging tests. More than 60 cells of the same type are tested to analyze different impact factors. In calendar aging tests three temperatures and various SOC are applied to the batteries. For cycle aging tests especially different cycle depths and mean SOC are taken into account. Capacity loss and resistance increase are monitored as functions of time and charge throughput during the tests. From these data physical based functions are obtained, giving a mathematical description of aging. To calculate the stress factors like temperature or voltage, an impedance based electric-thermal model is coupled to the aging model. The model accepts power and current profiles as input, furthermore an ambient air temperature profile can be applied. Various drive cycles and battery management strategies can be tested and optimized using the lifetime prognosis of this tool. With the validation based on different realistic driving profiles and temperatures, a robust foundation is provided.

  17. Weathering profiles in soils and rocks on Earth and Mars

    NASA Astrophysics Data System (ADS)

    Hausrath, E.; Adcock, C. T.; Bamisile, T.; Baumeister, J. L.; Gainey, S.; Ralston, S. J.; Steiner, M.; Tu, V.

    2017-12-01

    Interactions of liquid water with rock, soil, or sediments can result in significant chemical and mineralogical changes with depth. These changes can include transformation from one phase to another as well as translocation, addition, and loss of material. The resulting chemical and mineralogical depth profiles can record characteristics of the interacting liquid water such as pH, temperature, duration, and abundance. We use a combined field, laboratory, and modeling approach to interpret the environmental conditions preserved in soils and rocks. We study depth profiles in terrestrial field environments; perform dissolution experiments of primary and secondary phases important in soil environments; and perform numerical modeling to quantitatively interpret weathering environments. In our field studies we have measured time-integrated basaltic mineral dissolution rates, and interpreted the impact of pH and temperature on weathering in basaltic and serpentine-containing rocks and soils. These results help us interpret fundamental processes occurring in soils on Earth and on Mars, and can also be used to inform numerical modeling and laboratory experiments. Our laboratory experiments provide fundamental kinetic data to interpret processes occurring in soils. We have measured dissolution rates of Mars-relevant phosphate minerals, clay minerals, and amorphous phases, as well as dissolution rates under specific Mars-relevant conditions such as in concentrated brines. Finally, reactive transport modeling allows a quantitative interpretation of the kinetic, thermodynamic, and transport processes occurring in soil environments. Such modeling allows the testing of conditions under longer time frames and under different conditions than might be possible under either terrestrial field or laboratory conditions. We have used modeling to examine the weathering of basalt, olivine, carbonate, phosphate, and clay minerals, and placed constraints on the duration, pH, and solution chemistry of past aqueous alteration occurring on Mars.

  18. Seasonal cycle of the mixed layer depth, of the seasonal thermocline and of the upper-ocean heat rate in the Mediterranean Sea: an observational approach

    NASA Astrophysics Data System (ADS)

    Houpert, Loïc; Testor, Pierre; Durrieu de Madron, Xavier; Somot, Samuel; D'Ortenzio, Fabrizio; Estournel, Claude; Lavigne, Héloïse

    2014-05-01

    We present a relatively high resolution Mediterranean climatology (0.5°x0.5°x12 months) of the seasonal thermocline based on a comprehensive collection of temperature profiles of the last 44 years (1969-2012). The database includes more than 190,000 profiles, merging CTD, XBT, profiling floats, and gliders observations. This data set is first used to describe the seasonal cycle of the mixed layer depth and of the seasonal thermocline and on the whole Mediterranean on a monthly climatological basis. Our analysis discriminates several regions with coherent behaviors, in particular the deep water formation sites, characterized by significant differences in the winter mixing intensity. Heat Storage Rate (HSR) is calculated as the time rate of change of the heat content due to variations in the temperature integrated from the surface down to the base of the seasonal thermocline. Heat Entrainment Rate (HER) is calculated as the time rate of change of the heat content due to the deepening of thermocline base. We propose a new independent estimate of the seasonal cycle of the Net surface Heat Flux, calculated on average over the Mediterranean Sea for the 1979-2011 period, based only on in-situ observations. We used our new climatologies of HSR and of HER, combined to existing climatology of the horizontal heat flux at Gibraltar Strait. Although there is a good agreement between our estimation of NHF, from observations, with modeled NHF, some differences may be noticed during specific periods. A part of these differences may be explained by the high temporal and spatial variability of the Mixed Layer Depth and of the seasonal thermocline, responsible for very localized heat transfer in the ocean.

  19. Heat and Groundwater Flow in the San Gabriel Mountains, California

    NASA Astrophysics Data System (ADS)

    Newman, A. A.; Becker, M.; Laton, W. R., Jr.

    2017-12-01

    Groundwater flow paths in mountainous terrain often vary widely in both time and space. Such systems remain difficult to characterize due to fracture-dominated flow paths, high topographic relief, and sparse hydrologic data. We develop a hydrogeologic conceptual model of the Western San Gabriel Mountains in Southern California based on geophysical, thermal, and hydraulic head data. Boreholes are located along the San Gabriel Fault Zone (SGFZ) and cover a wide range of elevations to capture the heterogeneity of the hydrogeologic system. Long term (2016-2017) monitoring of temperature and hydraulic head was carried out in four shallow (300-600m depth) boreholes within the study area using fiber-optic distributed temperature sensing (DTS). Borehole temperature profiles were used to assess the regional groundwater flow system and local flows in fractures intersecting the borehole. DTS temperature profiles were compared with available borehole geophysical logs and head measurements collected with grouted vibrating wire pressure transducers (VWPT). Spatial and temporal variations in borehole temperature profiles suggest that advective heat transfer due to fluid flow affected the subsurface thermal regime. Thermal evidence of groundwater recharge and/or discharge and flow through discrete fractures was found in all four boreholes. Analysis of temporal changes to the flow system in response to seasonal and drilling-induced hydraulic forcing was useful in reducing ambiguities in noisy datasets and estimating interborehole relationships. Acoustic televiewer logs indicate fractures were primarily concentrated in densely fractured intervals, and only a minor decrease of fracture density was observed with depth. Anomalously high hydraulic gradients across the SGFZ suggest that the feature is a potential barrier to lateral flow. However, transient thermal anomalies consistent with groundwater flow within the SGFZ indicate this feature may be a potential conduit to vertical flow. This study builds upon the limited hydrogeologic understanding of the region and demonstrates the value of DTS in characterization efforts.

  20. Advanced 3D Geological Modelling Using Multi Geophysical Data in the Yamagawa Geothermal Field, Japan

    NASA Astrophysics Data System (ADS)

    Mochinaga, H.; Aoki, N.; Mouri, T.

    2017-12-01

    We propose a robust workflow of 3D geological modelling based on integrated analysis while honouring seismic, gravity, and wellbore data for exploration and development at flash steam geothermal power plants. We design the workflow using temperature logs at less than 10 well locations for practical use at an early stage of geothermal exploration and development. In the workflow, geostatistical technique, multi-attribute analysis, and artificial neural network are employed for the integration of multi geophysical data. The geological modelling is verified by using a 3D seismic data which was acquired in the Yamagawa Demonstration Area (approximately 36 km2), located at the city of Ibusuki in Kagoshima, Japan in 2015. Temperature-depth profiles are typically characterized by heat transfer of conduction, outflow, and up-flow which have low frequency trends. On the other hand, feed and injection zones with high permeability would cause high frequency perturbation on temperature-depth profiles. Each trend is supposed to be caused by different geological properties and subsurface structures. In this study, we estimate high frequency (> 2 cycles/km) and low frequency (< 1 cycle/km) models separately by means of different types of attribute volumes. These attributes are mathematically generated from P-impedance and density volumes derived from seismic inversion, an ant-tracking seismic volume, and a geostatistical temperature model prior to application of artificial neural network on the geothermal modelling. As a result, the band-limited stepwise approach predicts a more precise geothermal model than that of full-band temperature profiles at a time. Besides, lithofacies interpretation confirms reliability of the predicted geothermal model. The integrated interpretation is significantly consistent with geological reports from previous studies. Isotherm geobodies illustrate specific features of geothermal reservoir and cap rock, shallow aquifer, and its hydrothermal circulation in 3D visualization. The advanced workflow of 3D geological modelling is suitable for optimization of well locations for production and reinjection in geothermal fields.

  1. Warm ocean processes and carbon cycling in the Eocene.

    PubMed

    John, Eleanor H; Pearson, Paul N; Coxall, Helen K; Birch, Heather; Wade, Bridget S; Foster, Gavin L

    2013-10-28

    Sea surface and subsurface temperatures over large parts of the ocean during the Eocene epoch (55.5-33.7 Ma) exceeded modern values by several degrees, which must have affected a number of oceanic processes. Here, we focus on the effect of elevated water column temperatures on the efficiency of the biological pump, particularly in relation to carbon and nutrient cycling. We use stable isotope values from exceptionally well-preserved planktonic foraminiferal calcite from Tanzania and Mexico to reconstruct vertical carbon isotope gradients in the upper water column, exploiting the fact that individual species lived and calcified at different depths. The oxygen isotope ratios of different species' tests are used to estimate the temperature of calcification, which we converted to absolute depths using Eocene temperature profiles generated by general circulation models. This approach, along with potential pitfalls, is illustrated using data from modern core-top assemblages from the same area. Our results indicate that, during the Early and Middle Eocene, carbon isotope gradients were steeper (and larger) through the upper thermocline than in the modern ocean. This is consistent with a shallower average depth of organic matter remineralization and supports previously proposed hypotheses that invoke high metabolic rates in a warm Eocene ocean, leading to more efficient recycling of organic matter and reduced burial rates of organic carbon.

  2. Atmospheric CH4 oxidation by Arctic permafrost and mineral cryosols as a function of water saturation and temperature.

    PubMed

    Stackhouse, B; Lau, M C Y; Vishnivetskaya, T; Burton, N; Wang, R; Southworth, A; Whyte, L; Onstott, T C

    2017-01-01

    The response of methanotrophic bacteria capable of oxidizing atmospheric CH 4 to climate warming is poorly understood, especially for those present in Arctic mineral cryosols. The atmospheric CH 4 oxidation rates were measured in microcosms incubated at 4 °C and 10 °C along a 1-m depth profile and over a range of water saturation conditions for mineral cryosols containing type I and type II methanotrophs from Axel Heiberg Island (AHI), Nunavut, Canada. The cryosols exhibited net consumption of ~2 ppmv CH 4 under all conditions, including during anaerobic incubations. Methane oxidation rates increased with temperature and decreased with increasing water saturation and depth, exhibiting the highest rates at 10 °C and 33% saturation at 5 cm depth (260 ± 60 pmol CH 4 gdw -1 d -1 ). Extrapolation of the CH 4 oxidation rates to the field yields net CH 4 uptake fluxes ranging from 11 to 73 μmol CH 4  m -2 d -1 , which are comparable to field measurements. Stable isotope mass balance indicates ~50% of the oxidized CH 4 is incorporated into the biomass regardless of temperature or saturation. Future atmospheric CH 4 uptake rates at AHI with increasing temperatures will be determined by the interplay of increasing CH 4 oxidation rates vs. water saturation and the depth to the water table during summer thaw. © 2016 John Wiley & Sons Ltd.

  3. Surface magnetometer experiments: Internal lunar properties

    NASA Technical Reports Server (NTRS)

    Dyal, P.; Parkin, C. W.; Daily, W. D.

    1973-01-01

    Magnetic fields have been measured on the lunar surface at the Apollo 12, 14, 15, and 16 landing sites. The remanent field values at these sites are respectively 38 gammas, 103 gammas (maximum), 3 gammas, and 327 gammas. Simultaneous magnetic field and solar plasma pressure measurements show that the remanent fields at the Apollo 12 and 16 sites are compressed and that the scale size of the Apollo 16 remanent field is 5 or = L 100 km. The global eddy current fields, induced by magnetic step transients in the solar wind, were analyzed to calculate an electrical conductivity profile. From nightside data it was found that deeper than 170 km into the moon, the conductivity rises from 0.0003 mhos/m to 0.01 mhos/m at 1000 km depth. Analysis of dayside transient data using a spherically symmetric two-layer model yields a homogeneous conducting core of radios 0.9 R and conductivity sigma = 0.001 mhos/m, surrounded by a nonconducting shell of thickness 0.1 R. This result is in agreement with a nonconducting profile determined from nightside data. The conductivity profile is used to calculate the temperature for an assumed lunar material of peridotite. In an outer layer the temperature rises to 850 to 1050 K, after which it gradually increases to 1200 to 1500 K at a depth of approximately 1000 km.

  4. THE CHROMOSPHERIC SOLAR MILLIMETER-WAVE CAVITY ORIGINATES IN THE TEMPERATURE MINIMUM REGION

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    De la Luz, Victor; Raulin, Jean-Pierre; Lara, Alejandro

    2013-01-10

    We present a detailed theoretical analysis of the local radio emission at the lower part of the solar atmosphere. To accomplish this, we have used a numerical code to simulate the emission and transport of high-frequency electromagnetic waves from 2 GHz up to 10 THz. As initial conditions, we used VALC, SEL05, and C7 solar chromospheric models. In this way, the generated synthetic spectra allow us to study the local emission and absorption processes with high resolution in both altitude and frequency. Associated with the temperature minimum predicted by these models, we found that the local optical depth at millimetermore » wavelengths remains constant, producing an optically thin layer that is surrounded by two layers of high local emission. We call this structure the Chromospheric Solar Millimeter-wave Cavity (CSMC). The temperature profile, which features temperature minimum layers and a subsequent temperature rise, produces the CSMC phenomenon. The CSMC shows the complexity of the relation between the theoretical temperature profile and the observed brightness temperature and may help us to understand the dispersion of the observed brightness temperature in the millimeter wavelength range.« less

  5. Dissolved organic carbon in soil solution of peat-moorsh soils on Kuwasy Mire

    NASA Astrophysics Data System (ADS)

    Jaszczyński, J.; Sapek, A.

    2009-04-01

    Key words: peat-moorsh soils, soil solution, dissolved organic carbon (DOC), temperature of soil, redox potential. The objective this study was the dissolved organic carbon concentration (DOC) in soil solution on the background of soil temperature, moisture and redox potential. The investigations were localized on the area of drained and agricultural used Kuwasy Mire, which are situated in the middle basin of Biebrza River, in North-East Poland. Research point was placed on a low peat soil of 110 cm depth managed as extensive grassland. The soil was recognized as peat-moorsh with the second degree of the moorshing process (with 20 cm of moorsh layer). The ceramic suction cups were installed in three replications at 30 cm depth of soil profile. The soil solution was continuously sampled by pomp of the automatic field station. The successive samples comprised of solution collected at the intervals of 21 days. Simultaneously, at the 20, 30 and 40 cm soil depths the measurements of temperature and determination of soil moisture and redox potential were made automatically. The mean twenty-four hours data were collected. The concentrations of DOC were determined by means of the flow colorimeter using the Skalar standard methods. Presented observations were made in 2001-2006. Mean DOC concentration in soil solution was 66 mg.dm-3 within all research period. A significant positive correlation between studied compound concentration and temperature of soil at 30 cm depth was observed; (correlation coefficient - r=0.55, number of samples - n=87). The highest DOC concentrations were observed during the season from July to October, when also a lower ground water level occurred. The DOC concentration in soil solution showed as well a significant correlation with the soil redox potential at 20 cm level. On this depth of describing soil profile a frontier layer between moorshing layer and peat has been existed. This layer is the potentially most active in the respect to biochemical transformation. On the other hand it wasn't possible to shown dependences on the DOC concentration from soil moisture. That probably results from a huge water-holding capacity of these type of peat soils, which are keeping a high moisture content even at a long time after decreasing of the groundwater table.

  6. Monitoring of active layer thermal regime and depth on CALM-S site, James Ross Island, Eastern Antarctic Peninsula

    NASA Astrophysics Data System (ADS)

    Hrbáček, Filip; Kňažková, Michaela; Nývlt, Daniel; Láska, Kamil; Mueller, Carsten W.; Ondruch, Jakub

    2017-04-01

    Active layer thickness and its dynamic are considered one of the key parameters of permafrost-affected ground. They variability are very sensitive to specific local conditions, especially climate, vegetation, snow cover or soil texture and moisture. To better understand the local variability of active layer thickness in Antarctica, the original Circumpolar Active Layer Monitoring protocol (CALM) was adapted as its southern form (CALM-S) with respect to specific conditions of Antarctica. To date, almost 40 CALM-S sites were registered across the Antarctic continent with the highest density on western Antarctic Peninsula (South Shetlands) and Victoria Land in East Antarctica (McMurdo region). On James Ross Island, CALM-S site was established in February 2014 as the first CALM-S in the eastern Antarctic Peninsula region. The CALM-S site is located near the Johann Gregor Mendel Station on the northern coast of James Ross Island. The area delimited to 80 × 70 m is elevated at 8 to 11 m asl. Geologically it consists of a Holocene marine terrace ( 80% of CALM-S area) with typical sandy material and passes to lithified to poorly disintegrated sedimentary rocks of Cretaceous Whisky Bay Formation ( 20% of CALM-S area) with a more muddy material and a typical bimodal composition. For both geologically different parts of CALM-S site, ground temperature was measured at two profiles at several levels up to 200 cm depth using resistance thermometers Pt100/8 (accuracy ± 0.15 °C). The air temperature at 2 m above surface was monitored at the automatic weather station near Johann Gregor Mendel Station using resistance thermometer Pt100/A (accuracy ± 0.15 °C). Data used in this study were obtained during the period from 1 March 2013 to 6 February 2016. Mechanical probing of active layer depth was performed in 72 grid points at the end of January, or beginning of February in 2014 to 2016. During the whole study period, mean annual air temperature varied between -7.0 °C (2013) and -6.7 °C (2015), while the mean annual ground temperature at 5 cm ranged from -5.6 °C (2013) to -5.3 °C (2014). Thawing season started in mid-November between 17th (2013/14) and 24th (2014/15) and ended at the end of February (22nd in 2014/15) and beginning of March (7th in 2013/14). The maximum active layer thickness determined from 0°C isotherm varied from 86 to 87 cm at profile 1, while it reached only 51 to 65 cm at profile 2. The mean probed active layer depth varied between 66 cm (2013/4) and 78 cm (2014/15). The maximum probed active layer depth increased from 100 cm in 2014 to 113 cm in 2016. High variability of active layer depth across CALM-S site was caused by different ground thermal properties of Holocene marine terrace sand and Cretaceous clayey sandstones. These results differ significantly from another CALM-S sites in Antarctica, where the main factors affecting thawing depth variability were snow cover and topography. These results confirmed previous observation from James Ross Island, where variability of active layer depth was related primarily to different ground properties (texture, moisture, physical characteristic) then local climate or snow cover.

  7. Glacial-interglacial dynamics of Antarctic firn columns: comparison between simulations and ice core air-?15N measurements

    NASA Astrophysics Data System (ADS)

    Capron, E.; Landais, A.; Buiron, D.; Cauquoin, A.; Chappellaz, J. A.; Debret, M.; Jouzel, J.; Leuenberger, M.; Martinerie, P.; Masson-Delmotte, V.; Mulvaney, R.; Parrenin, F.; Prié, F.

    2013-12-01

    Correct estimation of the firn lock-in depth is essential for correctly linking gas and ice chronologies in ice core studies. Here, two approaches to constrain the firn depth evolution in Antarctica are presented over the last deglaciation: outputs of a firn densification model, and measurements of δ15N of N2 in air trapped in ice core, assuming that δ15N is only affected by gravitational fractionation in the firn column. Since the firn densification process is largely governed by surface temperature and accumulation rate, we have investigated four ice cores drilled in coastal (Berkner Island, BI, and James Ross Island, JRI) and semi-coastal (TALDICE and EPICA Dronning Maud Land, EDML) Antarctic regions. Combined with available ice core air- δ15N measurements from the EPICA Dome C (EDC) site, the studied regions encompass a large range of surface accumulation rates and temperature conditions. Our δ15N profiles reveal a heterogeneous response of the firn structure to glacial-interglacial climatic changes. While firn densification simulations correctly predict TALDICE δ15N variations, they systematically fail to capture the large millennial-scale δ15N variations measured at BI and the δ15N glacial levels measured at JRI and EDML - a mismatch previously reported for central East Antarctic ice cores. New constraints of the EDML gas-ice depth offset during the Laschamp event (41 ka) and the last deglaciation do not favour the hypothesis of a large convective zone within the firn as the explanation of the glacial firn model- δ15N data mismatch for this site. While we could not conduct an in-depth study of the influence of impurities in snow for firnification from the existing datasets, our detailed comparison between the δ15N profiles and firn model simulations under different temperature and accumulation rate scenarios suggests that the role of accumulation rate may have been underestimated in the current description of firnification models.

  8. Glacial-interglacial dynamics of Antarctic firn columns: comparison between simulations and ice core air-δ15N measurements

    NASA Astrophysics Data System (ADS)

    Capron, E.; Landais, A.; Buiron, D.; Cauquoin, A.; Chappellaz, J.; Debret, M.; Jouzel, J.; Leuenberger, M.; Martinerie, P.; Masson-Delmotte, V.; Mulvaney, R.; Parrenin, F.; Prié, F.

    2013-05-01

    Correct estimation of the firn lock-in depth is essential for correctly linking gas and ice chronologies in ice core studies. Here, two approaches to constrain the firn depth evolution in Antarctica are presented over the last deglaciation: outputs of a firn densification model, and measurements of δ15N of N2 in air trapped in ice core, assuming that δ15N is only affected by gravitational fractionation in the firn column. Since the firn densification process is largely governed by surface temperature and accumulation rate, we have investigated four ice cores drilled in coastal (Berkner Island, BI, and James Ross Island, JRI) and semi-coastal (TALDICE and EPICA Dronning Maud Land, EDML) Antarctic regions. Combined with available ice core air-δ15N measurements from the EPICA Dome C (EDC) site, the studied regions encompass a large range of surface accumulation rates and temperature conditions. Our δ15N profiles reveal a heterogeneous response of the firn structure to glacial-interglacial climatic changes. While firn densification simulations correctly predict TALDICE δ15N variations, they systematically fail to capture the large millennial-scale δ15N variations measured at BI and the δ15N glacial levels measured at JRI and EDML - a mismatch previously reported for central East Antarctic ice cores. New constraints of the EDML gas-ice depth offset during the Laschamp event (~41 ka) and the last deglaciation do not favour the hypothesis of a large convective zone within the firn as the explanation of the glacial firn model-δ15N data mismatch for this site. While we could not conduct an in-depth study of the influence of impurities in snow for firnification from the existing datasets, our detailed comparison between the δ15N profiles and firn model simulations under different temperature and accumulation rate scenarios suggests that the role of accumulation rate may have been underestimated in the current description of firnification models.

  9. Temperature data from Norwegian and Russian waters of the northern Barents Sea collected by free-living ringed seals

    NASA Astrophysics Data System (ADS)

    Lydersen, Christian; Anders Nøst, Ole; Kovacs, Kit M.; Fedak, Mike A.

    2004-05-01

    Free-living ringed seals ( N=11) equipped with satellite-relayed data loggers (SRDLs) with incorporated oceanographic-quality temperature sensors were used to collect data from a large sector of the northern Barents Sea during the autumn and early winter. A total of 2346 temperature profiles were collected over a 4-month period from Norwegian and Russian arctic waters in areas that were at times 90-100% ice-covered. Temperature distributions at different depths from northeastern parts of Svalbard, Norway show warm North Atlantic water (NAW) flowing along the continental slope and gradually cooling at all depths as it flows eastwards. The data suggest that most of the cooling takes place west of 30°E. Vertical temperature profiles from the area between Svalbard and Franz Josef Land, Russia show how the surface water cools during freeze-up and demonstrate a warm water flow, which is probably NAW, coming in from the north through a deep trench west of Franz Josef Land. Global oceanographic and climate models require improved oceanographic databases from crucial areas where important hydrological phenomena occur. Such areas in arctic waters are often inaccessible during winter and logistically difficult to reach even in summer. The present study demonstrates how large amounts of oceanographic information can be collected and retrieved in a cost-efficient manner using ice-associated marine mammals as carrier of oceanographic sampling equipment. In addition to the oceanographic value of the data collected by marine mammals in this manner, a vast amount of information regarding the habitat of these animals is concomitantly sampled.

  10. Uptake of Light Elements in Thin Metallic Films

    NASA Astrophysics Data System (ADS)

    Markwitz, Andreas; Waldschmidt, Mathias

    Ion beam analysis was used to investigate the influence of substrate temperature on the inclusion of impurities during the deposition process of thin metallic single and double layers. Thin layers of gold and aluminium were deposited at different temperatures onto thin copper layers evaporated on silicon wafer substrates. The uptake of oxygen in the layers was measured using the highly sensitive non-resonant reaction 16O(d,p)170O at 920 keV. Nuclear reaction analysis was also used to probe for carbon and nitrogen with a limit of detection better than 20 ppm. Hydrogen depth profiles were measured using elastic recoil detection on the nanometer scale. Rutherford backscattering spectroscopy was used to determine the depth profiles of the metallic layers and to study diffusion processes. The combined ion beam analyses revealed an uptake of oxygen in the layers depending on the different metallic cap layers and the deposition temperature. Lowest oxygen values were measured for the Au/Cu layers, whereas the highest amount of oxygen was measured in Al/Cu layers deposited at 300°C. It was also found that with single copper layers produced at various temperatures, oxygen contamination occurred during the evaporation process and not afterwards, for example, as a consequence of the storage of the films under normal conditions for several days. Hydrogen, carbon, and nitrogen were found as impurities in the single and double layered metallic films, a finding that is in agreement with the measured oxidation behaviour of the metallic films.

  11. Correction Factor for Determining the London Penetration Depth from Strip Resonators

    NASA Technical Reports Server (NTRS)

    Romanofsky, Robert R.

    1995-01-01

    A significant disagreement is often seen between the theoretical temperature dependent magnetic penetration depth profile and experimentally derived calculations based on stripline type resonators. This short paper shows that the disagreement can be attributed to the susceptance coupled into the resonator from the gap discontinuity as well as the feed line. When the effect is taken into account, the natural resonant frequency of the resonator is increased, and the frequency shift due to kinetic inductance can be calculated much more accurately. While it is necessary to include this effect to determine the penetration depth, it is shown that the impact on unloaded quality factor is generally negligible. The situation when the strip characteristic impedance is not matched to the generator is included.

  12. Bull trout (Salvelinus confluentus) movement in relation to water temperature, season, and habitat features in Arrowrock Reservoir, Idaho, 2012

    USGS Publications Warehouse

    Maret, Terry R.; Schultz, Justin E.

    2013-01-01

    Acoustic telemetry was used to determine spring to summer (April–August) movement and habitat use of bull trout (Salvelinus confluentus) in Arrowrock Reservoir (hereafter “Arrowrock”), a highly regulated reservoir in the Boise River Basin of southwestern Idaho. Water management practices annually use about 86 percent of the reservoir water volume to satisfy downstream water demands. These practices might be limiting bull trout habitat and movement patterns. Bull trout are among the more thermally sensitive coldwater species in North America, and the species is listed as threatened throughout the contiguous United States under the Endangered Species Act. Biweekly water-temperature and dissolved-oxygen profiles were collected by the Bureau of Reclamation at three locations in Arrowrock to characterize habitat conditions for bull trout. Continuous streamflow and water temperature also were measured immediately upstream of the reservoir on the Middle and South Fork Boise Rivers, which influence habitat conditions in the riverine zones of the reservoir. In spring 2012, 18 bull trout ranging in total length from 306 to 630 millimeters were fitted with acoustic transmitters equipped with temperature and depth sensors. Mobile boat tracking and fixed receivers were used to detect released fish. Fish were tagged from March 28 to April 20 and were tracked through most of August. Most bull trout movements were detected in the Middle Fork Boise River arm of the reservoir. Fifteen individual fish were detected at least once after release. Water surface temperature at each fish detection location ranged from 6.0 to 16.2 degrees Celsius (°C) (mean=10.1°C), whereas bull trout body temperatures were colder, ranging from 4.4 to 11.6°C (mean=7.3°C). Bull trout were detected over deep-water habitat, ranging from 8.0 to 42.6 meters (m) (mean=18.1 m). Actual fish depths were shallower than total water depth, ranging from 0.0 to 24.5 m (mean=6.7 m). The last bull trout was detected in early June, suggesting that fish used little, if any, summertime habitat within the reservoir. Water-quality profile measurements indicated that temperature could limit bull trout use of the reservoir during warm, summer months that coincide with decreased water volume. Thermal refuge during this study appeared to be limited based on scarcity of water that was 15°C and cooler. From the first week of August through the latter part of September, little if any suitable habitat remained for bull trout, with most temperatures exceeding 15°C at all locations where water quality profiles were measured.

  13. Diffusion induced atomic islands on the surface of Ni/Cu nanolayers

    NASA Astrophysics Data System (ADS)

    Takáts, Viktor; Csik, Attila; Hakl, József; Vad, Kálmán

    2018-05-01

    Surface islands formed by grain-boundary diffusion has been studied in Ni/Cu nanolayers by in-situ low energy ion scattering spectroscopy, X-ray photoelectron spectroscopy, scanning probe microscopy and ex-situ depth profiling based on ion sputtering. In this paper a new experimental approach of measurement of grain-boundary diffusion coefficients is presented. Appearing time of copper atoms diffused through a few nanometer thick nickel layer has been detected by low energy ion scattering spectroscopy with high sensitivity. The grain-boundary diffusion coefficient can be directly calculated from this appearing time without using segregation factors in calculations. The temperature range of 423-463 K insures the pure C-type diffusion kinetic regime. The most important result is that surface coverage of Ni layer by Cu atoms reaches a maximum during annealing and stays constant if the annealing procedure is continued. Scanning probe microscopy measurements show a Volmer-Weber type layer growth of Cu layer on the Ni surface in the form of Cu atomic islands. Depth distribution of Cu in Ni layer has been determined by depth profile analysis.

  14. In situ probing of temperature in radio frequency thermal plasma using Yttrium ion emission lines during synthesis of yttria nanoparticles

    NASA Astrophysics Data System (ADS)

    Dhamale, G. D.; Tiwari, N.; Mathe, V. L.; Bhoraskar, S. V.; Ghorui, S.

    2017-07-01

    Particle feeding is used in the most important applications of radio frequency (r.f.) thermal plasmas like synthesis of nanoparticles and particle spheroidization. The study reports an in-situ investigation of radial distribution of temperature in such devices using yttrium ion emission lines under different rates of particle loading during synthesis of yttria nanoparticles. A number of interesting facts about the response of r.f. plasma to the rate of particle loading, hitherto unknown, are revealed. Observed phenomena are supported with experimental data from fast photographic experiments and actual synthesis results. The use of the Abel inversion technique together with simultaneous multi-track acquisition of emission spectra from different spatial locations using a CCD based spectrometer allowed us to extract accurate distribution of temperature inside the plasma in the presence of inherent instabilities. The temperature profiles of this type of plasma have been measured possibly for the first time while particles are being fed into the plasma. Observed changes in the temperature profiles as the particle feed rate increases are very significant. Reaction forces resulting from particle evaporation, and increased skin depth owing to the decrease in electrical conductivity in the edge region are proposed as the two different mechanisms to account for the observed changes in the temperature profile as the powder feed rate is increased. Quantitative analyses supporting the proposed mechanisms are presented.

  15. Impact of Land Model Depth on Long Term Climate Variability and Change.

    NASA Astrophysics Data System (ADS)

    Gonzalez-Rouco, J. F.; García-Bustamante, E.; Hagemann, S.; Lorentz, S.; Jungclaus, J.; de Vrese, P.; Melo, C.; Navarro, J.; Steinert, N.

    2017-12-01

    The available evidence indicates that the simulation of subsurface thermodynamics in current General Circulation Models (GCMs) is not accurate enough due to the land-surface model imposing a zero heat flux boundary condition that is too close to the surface. Shallow land model components distort the amplitude and phase of the heat propagation in the subsurface with implications for energy storage and land-air interactions. Off line land surface model experiments forced with GCM climate change simulations and comparison with borehole temperature profiles indicate there is a large reduction of the energy storage of the soil using the typical shallow land models included in most GCMs. However, the impact of increasing the depth of the soil model in `on-line' GCM simulations of climate variability or climate change has not yet been systematically explored. The JSBACH land surface model has been used in stand alone mode, driven by outputs of the MPIESM to assess the impacts of progressively increasing the depth of the soil model. In a first stage, preindustrial control simulations are developed increasing the lower depth of the zero flux bottom boundary condition placed for temperature at the base of the fifth model layer (9.83 m) down to 294.6 m (layer 9), thus allowing for the bottom layers to reach equilibrium. Starting from piControl conditions, historical and scenario simulations have been performed since 1850 yr. The impact of increasing depths on the subsurface layer temperatures is analysed as well as the amounts of energy involved. This is done also considering permafrost processes (freezing and thawing). An evaluation on the influence of deepening the bottom boundary on the simulation of low frequency variability and temperature trends is provided.

  16. Depth perception: the need to report ocean biogeochemical rates as functions of temperature, not depth.

    PubMed

    Brewer, Peter G; Peltzer, Edward T

    2017-09-13

    For over 50 years, ocean scientists have oddly represented ocean oxygen consumption rates as a function of depth but not temperature in most biogeochemical models. This unique tradition or tactic inhibits useful discussion of climate change impacts, where specific and fundamental temperature-dependent terms are required. Tracer-based determinations of oxygen consumption rates in the deep sea are nearly universally reported as a function of depth in spite of their well-known microbial basis. In recent work, we have shown that a carefully determined profile of oxygen consumption rates in the Sargasso Sea can be well represented by a classical Arrhenius function with an activation energy of 86.5 kJ mol -1 , leading to a Q 10 of 3.63. This indicates that for 2°C warming, we will have a 29% increase in ocean oxygen consumption rates, and for 3°C warming, a 47% increase, potentially leading to large-scale ocean hypoxia should a sufficient amount of organic matter be available to microbes. Here, we show that the same principles apply to a worldwide collation of tracer-based oxygen consumption rate data and that some 95% of ocean oxygen consumption is driven by temperature, not depth, and thus will have a strong climate dependence. The Arrhenius/Eyring equations are no simple panacea and they require a non-equilibrium steady state to exist. Where transient events are in progress, this stricture is not obeyed and we show one such possible example.This article is part of the themed issue 'Ocean ventilation and deoxygenation in a warming world'. © 2017 The Author(s).

  17. Double perovskite cathodes for proton-conducting ceramic fuel cells: are they triple mixed ionic electronic conductors?

    NASA Astrophysics Data System (ADS)

    Téllez Lozano, Helena; Druce, John; Cooper, Samuel J.; Kilner, John A.

    2017-12-01

    18O and 2H diffusion has been investigated at a temperature of 300 °C in the double perovskite material PrBaCo2O5+δ (PBCO) in flowing air containing 200 mbar of 2H216O. Secondary ion mass spectrometry (SIMS) depth profiling of exchanged ceramics has shown PBCO still retains significant oxygen diffusivity ( 1.3 × 10-11 cm2s-1) at this temperature and that the presence of water (2H216O), gives rise to an enhancement of the surface exchange rate over that in pure oxygen by a factor of 3. The 2H distribution, as inferred from the 2H216O- SIMS signal, shows an apparent depth profile which could be interpreted as 2H diffusion. However, examination of the 3-D distribution of the signal shows it to be nonhomogeneous and probably related to the presence of hydrated layers in the interior walls of pores and is not due to proton diffusion. This suggests that PBCO acts mainly as an oxygen ion mixed conductor when used in PCFC devices, although the presence of a small amount of protonic conductivity cannot be discounted in these materials.

  18. Temperature profile in apricot tree canopies under the soil and climate conditions of the Romanian Black Sea Coast.

    PubMed

    Paltineanu, Cristian; Septar, Leinar; Chitu, Emil

    2016-03-01

    The paper describes the temperature profiles determined by thermal imagery in apricot tree canopies under the semi-arid conditions of the Black Sea Coast in a chernozem of Dobrogea Region, Romania. The study analyzes the thermal vertical profile of apricot orchards for three representative cultivars during summertime. Measurements were done when the soil water content (SWC) was at field capacity (FC) within the rooting depth, after intense sprinkler irrigation applications. Canopy temperature was measured during clear sky days at three heights for both sides of the apricot trees, sunlit (south), and shaded (north). For the SWC studied, i.e., FC, canopy height did not induce a significant difference between the temperature of apricot tree leaves (Tc) and the ambient air temperature (Ta) within the entire vertical tree profile, and temperature measurements by thermal imagery can therefore be taken at any height on the tree crown leaves. Differences between sunlit and shaded sides of the canopy were significant. Because of these differences for Tc-Ta among the apricot tree cultivars studied, lower base lines (LBLs) should be determined for each cultivar separately. The use of thermal imagery technique under the conditions of semi-arid coastal areas with low range of vapor pressure deficit could be useful in irrigation scheduling of apricot trees. The paper discusses the implications of the data obtained in the experiment under the conditions of the coastal area of the Black Sea, Romania, and neighboring countries with similar climate, such as Bulgaria and Turkey.

  19. The Radiative Effects of Martian Water Ice Clouds on the Local Atmospheric Temperature Profile

    NASA Technical Reports Server (NTRS)

    Colaprete, Anthony; Toon, Owen B.

    2000-01-01

    Mars Pathfinder made numerous discoveries, one of which was a deep temperature inversion that extended from about 15 km down to 8 km above the surface. It has been suggested by Haberle et al. (1999. J. Geophys. Res. 104, 8957-8974.) that radiative cooling by a water ice cloud may generate such an inversion. Clouds can strongly affect the local air temperature due to their ability to radiate efficiently in the infrared and due to the low air mass of the martian atmosphere, which allows the temperature to change during the relatively short lifetime of a cloud. We utilize a time-dependent microphysical aerosol model coupled to a radiative--convective model to explore the effects water ice clouds have on the local martian temperature profile. We constrain the dust and water vapor abundance using data from the Viking Missions and Mars Pathfinder. Water t ice clouds with visible optical depths of r > 0.1 form readily in these simulations. These clouds alter the local air temperature directly, through infrared cooling, and indirectly, by redistributing atmospheric dust. With this model we are able to reproduce the temperature inversions observed by Mars Pathfinder and Mars Global t Surveyor 2000 Academic Press

  20. UNDERSTANDING THE STRUCTURE OF THE HOT INTERSTELLAR MEDIUM IN NORMAL EARLY-TYPE GALAXIES.

    NASA Astrophysics Data System (ADS)

    Traynor, Liam; Kim, Dong-Woo; Chandra Galaxy Atlas

    2018-01-01

    The hot interstellar medium (ISM) of early-type galaxies (ETG's) provides crucial insight into the understanding of their formation and evolution. Mechanisms such as type Ia supernovae heating, AGN feedback, deepening potential depth through dark matter assembly and ramp-pressure stripping are known to affect the structure of the ISM. By using temperature maps and radial temperature profiles of the hot ISM from ~70 ETG's with archival Chandra data, it is possible to classify the galaxy's ISM into common structural types. This is extended by using 3D fitting of the radial temperature profile in order to provide models that further constrain the structural types. Five structural types are present, negative (temperature decreases with radii), positive (temperature increases with radii), hybrid-dip (temperature decreases at small radii and increases at large radii), hybrid-bump (inverse of hybrid-dip) and quasi-isothermal (temperature is constant at all radii). This work will be continued by 1) determining which mechanisms are present in which galaxies and 2) analysing the model parameters between galaxies within each structural type to determine whether each type can be described by a single set of model parameters, indicating that the same physical processes are responsible for creating that structural type.

  1. Depth profile measurement with lenslet images of the plenoptic camera

    NASA Astrophysics Data System (ADS)

    Yang, Peng; Wang, Zhaomin; Zhang, Wei; Zhao, Hongying; Qu, Weijuan; Zhao, Haimeng; Asundi, Anand; Yan, Lei

    2018-03-01

    An approach for carrying out depth profile measurement of an object with the plenoptic camera is proposed. A single plenoptic image consists of multiple lenslet images. To begin with, these images are processed directly with a refocusing technique to obtain the depth map, which does not need to align and decode the plenoptic image. Then, a linear depth calibration is applied based on the optical structure of the plenoptic camera for depth profile reconstruction. One significant improvement of the proposed method concerns the resolution of the depth map. Unlike the traditional method, our resolution is not limited by the number of microlenses inside the camera, and the depth map can be globally optimized. We validated the method with experiments on depth map reconstruction, depth calibration, and depth profile measurement, with the results indicating that the proposed approach is both efficient and accurate.

  2. Laser nitriding of iron: Nitrogen profiles and phases

    NASA Astrophysics Data System (ADS)

    Illgner, C.; Schaaf, P.; Lieb, K. P.; Schubert, E.; Queitsch, R.; Bergmann, H.-W.

    1995-07-01

    Armco iron samples were surface nitrided by irradiating them with pulses of an excimer laser in a nitrogen atmosphere. The resulting nitrogen depth profiles measured by Resonant Nuclear Reaction Analysis (RNRA) and the phase formation determined by Conversion Electron Mössbauer Spectroscopy (CEMS) were investigated as functions of energy density and the number of pulses. The nitrogen content of the samples was found to be independent of the number of pulses in a layer of 50 nm from the surface and to increase in depths exceeding 150 nm. The phase composition did not change with the number of pulses. The nitrogen content can be related to an enhanced nitrogen solubility based on high temperatures and high pressures due to the laser-induced plasma above the sample. With increasing pulse energy density, the phase composition changes towards phases with higher nitrogen contents. Nitrogen diffusion seems to be the limiting factor for the nitriding process.

  3. DOE Office of Scientific and Technical Information (OSTI.GOV)

    Nazareth, A.S.; Sood, D.K.; Zmood, R.B.

    A focusing grid broad beam Kaufman source, using argon ions on a target of nominal composition Nd{sub 2}Fe{sub 14}B has been employed to sputter deposit magnetic thin films of thicknesses ranging from 800 {angstrom} to 1300 {angstrom} on silicon-(111) substrates at room temperature. These films were characterized for their composition depth profile by Rutherford Backscattering Spectroscopy, while x-ray diffraction was used to study the crystallographic structure. Due to a close match between (111) Si with (220) Nd{sub 2}Fe{sub 14}B lattice spacings, preferred crystallographic texturing was expected, and experimental results showed a greatly enhanced (220) texture. The degradation in magnetic propertiesmore » was attributed to the presence of oxygen in the films as indicated by concentration depth profiles. It is premised that another significant role of oxygen may be to relieve the misfit strain across the interface by its incorporation within the Nd{sub 2}Fe{sub 14}B phase.« less

  4. Ice core age dating and paleothermometer calibration based on isotope and temperature profiles from deep boreholes at Vostok Station (East Antarctica)

    NASA Astrophysics Data System (ADS)

    Salamatin, Andrey N.; Lipenkov, Vladimir Y.; Barkov, Nartsiss I.; Jouzel, Jean; Petit, Jean Robert; Raynaud, Dominique

    1998-04-01

    An interpretation of the deuterium profile measured along the Vostok (East Antarctica) ice core down to 2755 m has been attempted on the basis of the borehole temperature analysis. An inverse problem is solved to infer a local "geophysical metronome," the orbital signal in the surface temperature oscillations expressed as a sum of harmonics of Milankovich periods. By correlating the smoothed isotopic temperature record to the metronome, a chronostratigraphy of the Vostok ice core is derived with an accuracy of ±3.0-4.5 kyr. The developed timescale predicts an age of 241 kyr at a depth of 2760 m. The ratio δD/δTi between deuterium content and cloud temperature fluctuations (at the top of the inversion layer) is examined by fitting simulated and measured borehole temperature profiles. The conventional estimate of the deuterium-temperature slope corresponding to the present-day spatial ratio (9 per mil/°C) is confirmed in general. However, the mismatch between modeled and measured borehole temperatures decreases noticeably if we allow surface temperature, responsible for the thermal state of the ice sheet, to undergo more intensive precession oscillations than those of the inversion temperature traced by isotope record. With this assumption, we obtain the long-term temporal deuterium-temperature slope to be 5.8-6.5 per mil/°C which implies that the glacial-interglacial temperature increase over central Antarctica was about 15°C in the surface temperature and 10°C in the inversion temperature. Past variations of the accumulation rate and the corresponding changes in the ice-sheet surface elevation are simultaneously simulated.

  5. Fiber Optic Distributed Temperature Sensing of Recharge Basin Percolation Dynamics

    NASA Astrophysics Data System (ADS)

    Becker, M.; Allen, E. M.; Hutchinson, A.

    2014-12-01

    Infiltration (spreading) basins are a central component of managed aquifer and recovery operations around the world. The concept is simple. Water is percolated into an aquifer where it can be withdrawn at a later date. However, managing infiltration basins can be complicated by entrapped air in sediments, strata of low permeability, clogging of the recharge surface, and biological growth, among other factors. Understanding the dynamics of percolation in light of these complicating factors provides a basis for making management decisions that increase recharge efficiency. As an aid to understanding percolation dynamics, fiber optic distribute temperature sensing (DTS) was used to track heat as a tracer of water movement in an infiltration basin. The diurnal variation of temperature in the basin was sensed at depth. The time lag between the oscillating temperature signal at the surface and at depth indicated the velocity of water percolation. DTS fiber optic cables were installed horizontally along the basin and vertically in boreholes to measure percolation behavior. The horizontal cable was installed in trenches at 0.3 and 1 m depth, and the vertical cable was installed using direct push technology. The vertical cable was tightly wound to produce a factor of 10 increase in spatial resolution of temperature measurements. Temperature was thus measured every meter across the basin and every 10 cm to a depth of 10 m. Data from the trenched cable suggested homogeneous percolation across the basin, but infiltration rates were a function of stage indicating non-ideal percolation. Vertical temperature monitoring showed significant lateral flow in sediments underlying the basin both during saturation and operation of the basin. Deflections in the vertical temperature profile corresponded with fine grained layers identified in core samples indicating a transient perched water table condition. The three-dimensional flow in this relatively homogenous surficial geology calls into question the relevance of simple wetting models for predicting percolation behavior in infiltration basins.

  6. Fine resolution 3D temperature fields off Kerguelen from instrumented penguins

    NASA Astrophysics Data System (ADS)

    Charrassin, Jean-Benoît; Park, Young-Hyang; Le Maho, Yvon; Bost, Charles-André

    2004-12-01

    The use of diving animals as autonomous vectors of oceanographic instruments is rapidly increasing, because this approach yields cost-efficient new information and can be used in previously poorly sampled areas. However, methods for analyzing the collected data are still under development. In particular, difficulties may arise from the heterogeneous data distribution linked to animals' behavior. Here we show how raw temperature data collected by penguin-borne loggers were transformed to a regular gridded dataset that provided new information on the local circulation off Kerguelen. A total of 16 king penguins ( Aptenodytes patagonicus) were equipped with satellite-positioning transmitters and with temperature-time-depth recorders (TTDRs) to record dive depth and sea temperature. The penguins' foraging trips recorded during five summers ranged from 140 to 600 km from the colony and 11,000 dives >100 m were recorded. Temperature measurements recorded during diving were used to produce detailed 3D temperature fields of the area (0-200 m). The data treatment included dive location, determination of the vertical profile for each dive, averaging and gridding of those profiles onto 0.1°×0.1° cells, and optimal interpolation in both the horizontal and vertical using an objective analysis. Horizontal fields of temperature at the surface and 100 m are presented, as well as a vertical section along the main foraging direction of the penguins. Compared to conventional temperature databases (Levitus World Ocean Atlas and historical stations available in the area), the 3D temperature fields collected from penguins are extremely finely resolved, by one order finer. Although TTDRs were less accurate than conventional instruments, such a high spatial resolution of penguin-derived data provided unprecedented detailed information on the upper level circulation pattern east of Kerguelen, as well as the iron-enrichment mechanism leading to a high primary production over the Kerguelen Plateau.

  7. Observations of ebb flows on tidal flats: Evidence of dewatering?

    NASA Astrophysics Data System (ADS)

    Rinehimer, J. P.; Thomson, J. M.; Chickadel, C.

    2010-12-01

    Incised channels are a common morphological feature of tidal flats. When the flats are inundated, flows are generally forced by the tidally varying sea surface height. During low tide, however, these channels continue to drain throughout flat exposure even without an upstream source of water. While the role of porewater is generally overlooked due to the low permeability of marine muds, it remains the only potential source of flows through the channels during low tide. In situ and remotely sensed observations (Figure 1) at an incised channel on a tidal flat in Willapa Bay from Spring 2010 indicate that dewatering of the flats may be driving these low tide flows. High resolution Aquadopp ADCP velocity profiles are combined with observations from tower-based infrared (IR) video to produce a complete time series of surface velocity measurements throughout low tide. The IR video observations provide a measurement of surface currents even when the channel depth is below the blanking distance of the ADCP (10 cm). As the depth within the channel drops from 50 cm to 10 cm surface velocities increase from 10 cm/s to 60 cm/s even as the tide level drops below the channel flanks and the flats are dry. As the drainage continues, the temperature of the flow rises throughout low tide, mirroring temperatures within the sediment bed on the tidal flat. Drainage salinity falls despite the lack of any freshwater input to the flat indicating that less saline porewater may be the source. The likely source of the drainage water is from the channel flanks where time-lapse video shows slumping and compaction of channel sediments. Velocity profiles, in situ temperatures, and IR observations also are consistent with the presence of fluid muds and a hyperpycnal, density driven outflow at the channel mouth highlighting a possible pathway for sediment delivery from the flats to the main distributary channels of the bay. Figure 1: Time series of tidal flat channel velocities and temperatures. Top: (soild) Water depth within the channel and (dashed) tidal flat elevation. Center: Channel surface velocities as measured by an (black) ADCP and (red) a Fourier technique using infrared video. Bottom: Temperatures of (blue) near bed water downstream of the incised channel, (black) channel outflow, and (red) tidal flat sediment at 10 cm depth within the bed.

  8. Thermal regime of a continental permafrost associated gas hydrate occurrence a continuous temperature profile record after drilling

    NASA Astrophysics Data System (ADS)

    Henninges, J.; Huenges, E.; Mallik Working Group

    2003-04-01

    Both the size and the distribution of natural methane hydrate occurrences, as well as the release of gaseous methane through the dissociation of methane hydrate, are affected by the subsurface pressure and temperature conditions. During a field experiment, which was carried out in the Mackenzie Delta, NWT, Canada, within the framework of the Mallik 2002 Production Research Well Program*, the variation of temperature within three 40 m spaced, 1200 m deep wells was measured deploying the Distributed Temperature Sensing (DTS) technology. An innovative experimental design for the monitoring of spatial and temporal variations of temperature along boreholes was developed and successfully applied under extreme arctic conditions. A special feature is the placement of the fibre-optic sensor cable inside the cement annulus between the casing and the wall of the borehole. Temperature profiles were recorded with a sampling interval of 0.25 m and 5 min, and temperatures can be determined with a resolution of 0.3 °C. The observed variation of temperature over time shows the decay of the thermal disturbances caused by the drilling and construction of the wells. An excellent indicator for the location of the base of the ice-bonded permafrost layer, which stands out as a result of the latent heat of the frozen pore fluid, is a sharp rise in temperature at 604 m depth during the period of equilibration. A similar effect can be detected in the depth interval between 1105 m and 1110 m, which is interpreted as an indicator for the depth to the base of the methane hydrate stability zone. Nine months after the completion of the wells the measured borehole temperatures are close to equilibrium. The mean temperature gradient rises from 9.4 K/km inside the permafrost to 25.4 K/km in the ice-free sediment layers underneath. The zone of the gas hydrate occurrences between 900 m and 1100 m shows distinct variations of the geothermal gradient, which locally rises up to 40 K/km. At the lower boundary of the methane hydrate stability zone a temperature of 12.2 °C was measured. (*) The program participants include 8 partners; The Geological Survey of Canada (GSC), The Japan National Oil Corporation (JNOC), GeoForschungsZentrum Potsdam (GFZ), United States Geological Survey (USGS), United States Department of the Energy (USDOE), India Ministry of Petroleum and Natural Gas (MOPNG)/Gas Authority of India (GAIL) and the Chevron-BP-Burlington joint venture group.

  9. A comparison of hydrographically and optically derived mixed layer depths

    USGS Publications Warehouse

    Zawada, D.G.; Zaneveld, J.R.V.; Boss, E.; Gardner, W.D.; Richardson, M.J.; Mishonov, A.V.

    2005-01-01

    Efforts to understand and model the dynamics of the upper ocean would be significantly advanced given the ability to rapidly determine mixed layer depths (MLDs) over large regions. Remote sensing technologies are an ideal choice for achieving this goal. This study addresses the feasibility of estimating MLDs from optical properties. These properties are strongly influenced by suspended particle concentrations, which generally reach a maximum at pycnoclines. The premise therefore is to use a gradient in beam attenuation at 660 nm (c660) as a proxy for the depth of a particle-scattering layer. Using a global data set collected during World Ocean Circulation Experiment cruises from 1988-1997, six algorithms were employed to compute MLDs from either density or temperature profiles. Given the absence of published optically based MLD algorithms, two new methods were developed that use c660 profiles to estimate the MLD. Intercomparison of the six hydrographically based algorithms revealed some significant disparities among the resulting MLD values. Comparisons between the hydrographical and optical approaches indicated a first-order agreement between the MLDs based on the depths of gradient maxima for density and c660. When comparing various hydrographically based algorithms, other investigators reported that inherent fluctuations of the mixed layer depth limit the accuracy of its determination to 20 m. Using this benchmark, we found a ???70% agreement between the best hydrographical-optical algorithm pairings. Copyright 2005 by the American Geophysical Union.

  10. The effect of magnetohydrodynamic nano fluid flow through porous cylinder

    NASA Astrophysics Data System (ADS)

    Widodo, Basuki; Arif, Didik Khusnul; Aryany, Deviana; Asiyah, Nur; Widjajati, Farida Agustini; Kamiran

    2017-08-01

    This paper concerns about the analysis of the effect of magnetohydrodynamic nano fluid flow through horizontal porous cylinder on steady and incompressible condition. Fluid flow is assumed opposite gravity and induced by magnet field. Porous cylinder is assumed had the same depth of porous and was not absorptive. The First thing to do in this research is to build the model of fluid flow to obtain dimentional governing equations. The dimentional governing equations are consist of continuity equation, momentum equation, and energy equation. Furthermore, the dimensional governing equations are converted to non-dimensional governing equation by using non-dimensional parameters and variables. Then, the non-dimensional governing equations are transformed into similarity equations using stream function and solved using Keller-Box method. The result of numerical solution further is obtained by taking variation of magnetic parameter, Prandtl number, porosity parameter, and volume fraction. The numerical results show that velocity profiles increase and temperature profiles decrease when both of the magnetic and the porosity parameter increase. However, the velocity profiles decrease and the temperature profiles increase when both of the magnetic and the porosity parameter increase.

  11. The internal boundary layer — A review

    NASA Astrophysics Data System (ADS)

    Garratt, J. R.

    1990-03-01

    A review is given of relevant work on the internal boundary layer (IBL) associated with: (i) Small-scale flow in neutral conditions across an abrupt change in surface roughness, (ii) Small-scale flow in non-neutral conditions across an abrupt change in surface roughness, temperature or heat/moisture flux, (iii) Mesoscale flow, with emphasis on flow across the coastline for both convective and stably stratified conditions. The major theme in all cases is on the downstream, modified profile form (wind and temperature), and on the growth relations for IBL depth.

  12. Thermal-Hydrology Simulations of Disposal of High-Level Radioactive Waste in a Single Deep Borehole

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Hadgu, Teklu; Stein, Emily; Hardin, Ernest

    2015-11-01

    Simulations of thermal-hydrology were carried out for the emplacement of spent nuclear fuel canisters and cesium and strontium capsules using the PFLOTRAN simulator. For the cesium and strontium capsules the analysis looked at disposal options such as different disposal configurations and surface aging of waste to reduce thermal effects. The simulations studied temperature and fluid flux in the vicinity of the borehole. Simulation results include temperature and vertical flux profiles around the borehole at selected depths. Of particular importance are peak temperature increases, and fluxes at the top of the disposal zone. Simulations of cesium and strontium capsule disposal predictmore » that surface aging and/or emplacement of the waste at the top of the disposal zone reduces thermal effects and vertical fluid fluxes. Smaller waste canisters emplaced over a longer disposal zone create the smallest thermal effect and vertical fluid fluxes no matter the age of the waste or depth of emplacement.« less

  13. Upper limit for the effect of elastic bending stress on the saturation magnetization of L a 0.8 S r 0.2 Mn O 3

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Wang, Qiang; Chen, A. P.; Guo, Erjia J.

    In this study, using polarized neutron reflectometry, we measured the influence of elastic bending stress on the magnetization depth profile of a La 0.8Sr 0.2MnO 3 (LSMO) epitaxial film grown on a SrTiO 3 substrate. The elastic bending strain of ±0.03% has no obvious effect on the magnetization depth profile at saturation. This result is in stark contrast to that of (La 1-xPr x)1-yCayMnO 3 (LPCMO) films for which strain of ±0.01% produced dramatic changes in the magnetization profile and Curie temperature. We attribute the difference between the influence of strain on the saturation magnetization in LSMO (weak or none)more » and LPCMO (strong) to a difference in the ability of LSMO (weak or none) and LPCMO (strong) to phase separate. Our observation provides an upper limit of tuning LSMO saturation magnetization via elastic strain effect.« less

  14. Upper limit for the effect of elastic bending stress on the saturation magnetization of L a 0.8 S r 0.2 Mn O 3

    DOE PAGES

    Wang, Qiang; Chen, A. P.; Guo, Erjia J.; ...

    2018-01-31

    In this study, using polarized neutron reflectometry, we measured the influence of elastic bending stress on the magnetization depth profile of a La 0.8Sr 0.2MnO 3 (LSMO) epitaxial film grown on a SrTiO 3 substrate. The elastic bending strain of ±0.03% has no obvious effect on the magnetization depth profile at saturation. This result is in stark contrast to that of (La 1-xPr x)1-yCayMnO 3 (LPCMO) films for which strain of ±0.01% produced dramatic changes in the magnetization profile and Curie temperature. We attribute the difference between the influence of strain on the saturation magnetization in LSMO (weak or none)more » and LPCMO (strong) to a difference in the ability of LSMO (weak or none) and LPCMO (strong) to phase separate. Our observation provides an upper limit of tuning LSMO saturation magnetization via elastic strain effect.« less

  15. Laboratory-based electrical conductivity at Martian mantle conditions

    NASA Astrophysics Data System (ADS)

    Verhoeven, Olivier; Vacher, Pierre

    2016-12-01

    Information on temperature and composition of planetary mantles can be obtained from electrical conductivity profiles derived from induced magnetic field analysis. This requires a modeling of the conductivity for each mineral phase at conditions relevant to planetary interiors. Interpretation of iron-rich Martian mantle conductivity profile therefore requires a careful modeling of the conductivity of iron-bearing minerals. In this paper, we show that conduction mechanism called small polaron is the dominant conduction mechanism at temperature, water and iron content conditions relevant to Mars mantle. We then review the different measurements performed on mineral phases with various iron content. We show that, for all measurements of mineral conductivity reported so far, the effect of iron content on the activation energy governing the exponential decrease in the Arrhenius law can be modeled as the cubic square root of the iron content. We recast all laboratory results on a common generalized Arrhenius law for iron-bearing minerals, anchored on Earth's mantle values. We then use this modeling to compute a new synthetic profile of Martian mantle electrical conductivity. This new profile matches perfectly, in the depth range [100,1000] km, the electrical conductivity profile recently derived from the study of Mars Global Surveyor magnetic field measurements.

  16. Tree density and permafrost thaw depth influence water limitations on stomatal conductance in Siberian Arctic boreal forests

    NASA Astrophysics Data System (ADS)

    Kropp, H.; Loranty, M. M.; Natali, S.; Kholodov, A. L.; Alexander, H. D.; Zimov, N.

    2017-12-01

    Boreal forests may experience increased water stress under global climate change as rising air temperatures increase evaporative demand and decrease soil moisture. Increases in plant water stress can decrease stomatal conductance, and ultimately, decrease primary productivity. A large portion of boreal forests are located in Siberia, and are dominated by deciduous needleleaf trees, Larix spp. We investigated the variability and drivers of canopy stomatal conductance in upland Larix stands with different stand density that arose from differing fire severity. Our measurements focus on an open canopy stand with low tree density and deep permafrost thaw depth, and a closed canopy stand with high tree density and shallow permafrost thaw depth. We measured canopy stomatal conductance, soil moisture, and micrometeorological variables. Our results demonstrate that canopy stomatal conductance was significantly lower in the closed canopy stand with a significantly higher sensitivity to increases in atmospheric evaporative demand. Canopy stomatal conductance in both stands was tightly coupled to precipitation that occurred over the previous week; however, the closed canopy stand showed a significantly greater sensitivity to increases in precipitation compared to the open canopy stand. Differences in access to deep versus shallow soil moisture and the physical characteristics of the soil profile likely contribute to differences in sensitivity to precipitation between the two stands. Our results indicate that Larix primary productivity may be highly sensitive to changes in evaporative demand and soil moisture that can result of global climate change. However, the effect of increasing air temperatures and changes in precipitation will differ significantly depending on stand density, thaw depth, and the hydraulic characteristics of the soil profile.

  17. Synthesis, thermal stability and the effects of ion irradiation in amorphous Si-O-C alloys

    NASA Astrophysics Data System (ADS)

    Colón Santana, Juan A.; Mora, Elena Echeverría; Price, Lloyd; Balerio, Robert; Shao, Lin; Nastasi, Michael

    2015-05-01

    Amorphous films of Si-O-C alloys were synthesized via sputtering deposition at room temperature. These alloys were characterized using grazing incidence diffraction, both as a function of temperature and irradiation dose. It was found that the material retained its amorphous structure, both at high temperatures (up to 1200 °C) and ion irradiation doses up to 1.0 dpa. The depth profile from photoemission spectroscopy provided evidence of the oxidation state of these alloys and their atomic composition. The studies suggest that Si-O-C alloys might belong to a group of radiation tolerant materials suitable for applications in reactor-like harsh environments.

  18. Experimental and numerical study on plasma nitriding of AISI P20 mold steel

    NASA Astrophysics Data System (ADS)

    Nayebpashaee, N.; Vafaeenezhad, H.; Kheirandish, Sh.; Soltanieh, M.

    2016-09-01

    In this study, plasma nitriding was used to fabricate a hard protective layer on AISI P20 steel, at three process temperatures (450°C, 500°C, and 550°C) and over a range of time periods (2.5, 5, 7.5, and 10 h), and at a fixed gas N2:H2 ratio of 75vol%:25vol%. The morphology of samples was studied using optical microscopy and scanning electron microscopy, and the formed phase of each sample was determined by X-ray diffraction. The elemental depth profile was measured by energy dispersive X-ray spectroscopy, wavelength dispersive spectroscopy, and glow dispersive spectroscopy. The hardness profile of the samples was identified, and the microhardness profile from the surface to the sample center was recorded. The results show that ɛ-nitride is the dominant species after carrying out plasma nitriding in all strategies and that the plasma nitriding process improves the hardness up to more than three times. It is found that as the time and temperature of the process increase, the hardness and hardness depth of the diffusion zone considerably increase. Furthermore, artificial neural networks were used to predict the effects of operational parameters on the mechanical properties of plastic mold steel. The plasma temperature, running time of imposition, and target distance to the sample surface were all used as network inputs; Vickers hardness measurements were given as the output of the model. The model accurately reproduced the experimental outcomes under different operational conditions; therefore, it can be used in the effective simulation of the plasma nitriding process in AISI P20 steel.

  19. Maintenance of Coastal Surface Blooms by Surface Temperature Stratification and Wind Drift

    PubMed Central

    Ruiz-de la Torre, Mary Carmen; Maske, Helmut; Ochoa, José; Almeda-Jauregui, César O.

    2013-01-01

    Algae blooms are an increasingly recurrent phenomenon of potentially socio-economic impact in coastal waters globally and in the coastal upwelling region off northern Baja California, Mexico. In coastal upwelling areas the diurnal wind pattern is directed towards the coast during the day. We regularly found positive Near Surface Temperature Stratification (NSTS), the resulting density stratification is expected to reduce the frictional coupling of the surface layer from deeper waters and allow for its more efficient wind transport. We propose that the net transport of the top layer of approximately 2.7 kilometers per day towards the coast helps maintain surface blooms of slow growing dinoflagellate such as Lingulodinium polyedrum. We measured: near surface stratification with a free-rising CTD profiler, trajectories of drifter buoys with attached thermographs, wind speed and direction, velocity profiles via an Acoustic Doppler Current Profiler, Chlorophyll and cell concentration from water samples and vertical migration using sediment traps. The ADCP and drifter data agree and show noticeable current shear within the first meters of the surface where temperature stratification and high cell densities of L. polyedrum were found during the day. Drifters with 1m depth drogue moved towards the shore, whereas drifters at 3 and 5 m depth showed trajectories parallel or away from shore. A small part of the surface population migrated down to the sea floor during night thus reducing horizontal dispersion. The persistent transport of the surface bloom population towards shore should help maintain the bloom in favorable environmental conditions with high nutrients, but also increasing the potential socioeconomic impact of the blooms. The coast wise transport is not limited to blooms but includes all dissolved and particulate constituents in surface waters. PMID:23593127

  20. Maintenance of coastal surface blooms by surface temperature stratification and wind drift.

    PubMed

    Ruiz-de la Torre, Mary Carmen; Maske, Helmut; Ochoa, José; Almeda-Jauregui, César O

    2013-01-01

    Algae blooms are an increasingly recurrent phenomenon of potentially socio-economic impact in coastal waters globally and in the coastal upwelling region off northern Baja California, Mexico. In coastal upwelling areas the diurnal wind pattern is directed towards the coast during the day. We regularly found positive Near Surface Temperature Stratification (NSTS), the resulting density stratification is expected to reduce the frictional coupling of the surface layer from deeper waters and allow for its more efficient wind transport. We propose that the net transport of the top layer of approximately 2.7 kilometers per day towards the coast helps maintain surface blooms of slow growing dinoflagellate such as Lingulodinium polyedrum. We measured: near surface stratification with a free-rising CTD profiler, trajectories of drifter buoys with attached thermographs, wind speed and direction, velocity profiles via an Acoustic Doppler Current Profiler, Chlorophyll and cell concentration from water samples and vertical migration using sediment traps. The ADCP and drifter data agree and show noticeable current shear within the first meters of the surface where temperature stratification and high cell densities of L. polyedrum were found during the day. Drifters with 1m depth drogue moved towards the shore, whereas drifters at 3 and 5 m depth showed trajectories parallel or away from shore. A small part of the surface population migrated down to the sea floor during night thus reducing horizontal dispersion. The persistent transport of the surface bloom population towards shore should help maintain the bloom in favorable environmental conditions with high nutrients, but also increasing the potential socioeconomic impact of the blooms. The coast wise transport is not limited to blooms but includes all dissolved and particulate constituents in surface waters.

  1. The structure of the stably stratified internal boundary layer in offshore flow over the sea

    NASA Astrophysics Data System (ADS)

    Garratt, J. R.; Ryan, B. F.

    1989-04-01

    Observations obtained mainly from a research aircraft are presented of the mean and turbulent structure of the stably stratified internal boundary layer (IBL) over the sea formed by warm air advection from land to sea. The potential temperature and humidity fields reveal the vertical extent of the IBL, for fetches out to several hundred of kilometres, geostrophic winds of 20 25 m s-1, and potential temperature differences between undisturbed continental air and the sea surface of 7 to 17 K. The dependence of IBL depth on these external parameters is discussed in the context of the numerical results of Garratt (1987), and some discrepancies are noted. Wind observations show the development of a low-level wind maximum (wind component normal to the coast) and rotation of the wind to smaller cross-isobar flow angles. Potential temperature (θ) profiles within the IBL reveal quite a different structure to that found in the nocturnal boundary layer (NBL) over land. Over the sea, θ profiles have large positive curvature with vertical gradients increasing monotonically with height; this reflects the dominance of turbulent cooling within the layer. The behaviour is consistent with known behaviour in the NBL over land where curvature becomes negative (vertical gradients of θ decreasing with height) as radiative cooling becomes dominant. Turbulent properties are discussed in terms of non-dimensional quantities, normalised by the surface friction velocity, as functions of normalised height using the IBL depth. Vertical profiles of these and the normalised wavelength of the spectral maximum agree well with known results for the stable boundary layer over land (Caughey et al., 1979).

  2. Numerical analysis of seawater circulation in carbonate platforms: I. Geothermal convection

    USGS Publications Warehouse

    Sanford, W.E.; Whitaker, F.F.; Smart, P.L.; Jones, G.

    1998-01-01

    Differences in fluid density between cold ocean water and warm ground water can drive the circulation of seawater through carbonate platforms. The circulating water can be the major source of dissolved constituents for diagenetic reactions such as dolomitization. This study was undertaken to investigate the conditions under which such circulation can occur and to determine which factors control both the flux and the patterns of fluid circulation and temperature distribution, given the expected ranges of those factors in nature. Results indicate that the magnitude and distribution of permeability within a carbonate platform are the most important parameters. Depending on the values of horizontal and vertical permeability, heat transport within a platform can occur by one of three mechanisms: conduction, forced convection, or free convection. Depth-dependent relations for porosity and permeability in carbonate platforms suggest circulation may decrease rapidly with depth. The fluid properties of density and viscosity are controlled primarily by their dependency on temperature. The bulk thermal conductivity of the rocks within the platform affects the conductive regime to some extent, especially if evaporite minerals are present within the section. Platform geometry has only a second-order effect on circulation. The relative position of sealevel can create surface conditions that range from exposed (with a fresh-water lens present) to shallow water (with hypersaline conditions created by evaporation in constricted flow conditions) to submerged or drowned (with free surface water circulation), but these boundary conditions and associated ocean temperature profiles have only a second-order effect on fluid circulation. Deep, convective circulation can be caused by horizon tal temperature gradients and can occur even at depths below the ocean bottom. Temperature data from deep holes in the Florida and Bahama platforms suggest that geothermal circulation is actively occurring today to depths as great as several kilometers.

  3. Autonomous profiling float observations of the high biomass plume downstream of the Kerguelen plateau in the Southern Ocean

    NASA Astrophysics Data System (ADS)

    Grenier, M.; Della Penna, A.; Trull, T. W.

    2014-12-01

    Natural iron fertilisation from Southern Ocean islands results in high primary production and phytoplankton biomass accumulations readily visible in satellite ocean colour observations. These images reveal great spatial complexity with highly varying concentrations of chlorophyll, presumably reflecting both variations in iron supply and conditions favouring phytoplankton accumulation. To examine the second aspect, in particular the influences of variations in temperature and stratification, we deployed four autonomous profiling floats in the Antarctic Circumpolar Current near the Kerguelen plateau in the Indian sector of the Southern Ocean. Each "bio-profiler" measured more than 250 profiles of temperature (T), salinity (S), dissolved oxygen, chlorophyll fluorescence (Chl a), and particle backscatter in the top 300 m of the water column, sampling up to 5 profiles per day along meandering trajectories extending up to 1000 km. Comparison of surface Chl a estimates (top 50 m depth; analogous to values from satellite images) with total water column inventories revealed largely linear relationships, suggesting that dilution of chlorophyll by mixed layer depth variations plays only a minor role in the spatial distributions observed by satellite, and correspondingly that these images provide credible information on total and not just surface biomass accumulations. Regions of very high Chl a accumulation (1.5-10 μg L-1) were associated predominantly with a narrow T-S class of surface waters, which appears to derive from the northern Kerguelen plateau. In contrast, waters with only moderate Chl a enrichments (0.5-1.5 μg L-1) displayed no clear correlation with water properties, including no dependence on mixed layer depth, suggesting a diversity of sources of iron and/or its efficient dispersion across filaments of the plume. The lack of dependence on mixed layer depth also indicates a limited influence on production by light limitation. One float became trapped in a cyclonic eddy, allowing temporal evaluation of the water column in early autumn. During this period, decreasing surface Chl a inventories corresponded with decreases in oxygen inventories on sub-mixed layer density surfaces, consistent with significant export of organic matter and its respiration and storage as dissolved inorganic carbon in the ocean interior. These results are encouraging for the expanded use of autonomous observing platforms to study biogeochemical, carbon cycle, and ecological problems, although the complex blend of Lagrangian and Eulerian sampling achieved by the floats suggests that arrays rather than single floats will often be required.

  4. Tissue temperature profile in the human forearm during thermal stress at thermal stability.

    PubMed

    Ducharme, M B; VanHelder, W P; Radomski, M W

    1991-11-01

    The purpose of the present study was to investigate the effect of a range of water temperatures (Tw from 15 to 36 degrees C) on the tissue temperature profile of the resting human forearm at thermal stability. Tissue temperature (Tti) was continuously monitored by a calibrated multicouple probe during 3 h of immersion of the forearm. The probe was implanted approximately 9 cm distal from the olecranon process along the ulnar ridge. Tti was measured every 5 mm, from the longitudinal axis of the forearm (determined from computed tomography scanning) to the skin surface. Along with Tti, skin temperature (Tsk), rectal temperature (Tre), and blood flow were measured during the immersions. For all temperature conditions, the temperature profile inside the limb was linear as a function of the radial distance from the forearm axis (P less than 0.001). Temperature gradient measured in the forearm ranged from 0.2 +/- 0.1 degrees C C cm (Tw = 36 degrees C) to 2.3 +/- 0.5 degrees C cm (Tw = 15 degrees C). The maximal Tti was measured in all cases at the longitudinal axis of the forearm and was in all experimental conditions lower than Tre. On immersion at Tw less than 36 degrees C, the whole forearm can be considered to be part of the shell of the body. With these experimental data, mathematical equations were developed to predict, with an accuracy of at least 0.6 degrees C, the Tti at any depth inside the forearm at steady state during thermal stress.(ABSTRACT TRUNCATED AT 250 WORDS)

  5. Selected Heat-Sensitive Antibiotics Are Not Inactivated During Polymethylmethacrylate Curing and Can Be Used in Cement Spacers for Periprosthetic Joint Infection.

    PubMed

    Carli, Alberto V; Sethuraman, Arvinth S; Bhimani, Samrath J; Ross, Frederick P; Bostrom, Mathias P G

    2018-06-01

    Antibiotic use in polymethylmethacrylate (PMMA) spacers has historically been limited to those which are "heat-stable" and thus retain their antimicrobial properties after exposure to the high temperatures which occur during PMMA curing. This study examines the requirement of "heat stability" by measuring temperatures of Palacos and Simplex PMMA as they cure inside commercial silicone molds of the distal femur and proximal tibia. Temperature probes attached to thermocouples were placed at various depths inside the molds and temperatures were recorded for 20 minutes after PMMA introduced and a temperature curve for each PMMA product was determined. A "heat-stable" antibiotic, vancomycin, and a "heat-sensitive" antibiotic, ceftazidime, were placed in a programmable thermocycler and exposed to the same profile of PMMA curing temperatures. Antimicrobial activity against Staphylococcus aureus was compared for heat-treated antibiotics vs room temperature controls. Peak PMMA temperatures were significantly higher in tibial (115.2°C) vs femoral (85.1°C; P < .001) spacers. In the hottest spacers, temperatures exceeded 100°C for 3 minutes. Simplex PMMA produced significantly higher temperatures (P < .05) compared with Palacos. Vancomycin bioactivity did not change against S aureus with heat exposure. Ceftazidime bioactivity did not change when exposed to femoral temperature profiles and was reduced only 2-fold with tibial profiles. The curing temperatures of PMMA in knee spacers are not high enough or maintained long enough to significantly affect the antimicrobial efficacy of ceftazidime, a known "heat-sensitive" antibiotic. Future studies should investigate if more "heat-sensitive" antibiotics could be used clinically in PMMA spacers. Copyright © 2018 Elsevier Inc. All rights reserved.

  6. Subsurface temperature distribution in a tropical alluvial fan

    NASA Astrophysics Data System (ADS)

    Chen, Wenfu; Chang, Minhsiang; Chen, Juier; Lu, Wanchung; Huang, Chihc; Wang, Yunshuen

    2017-04-01

    As a groundwater intensive use country, Taiwan's 1/3 water supplies are derived from groundwater. The major aquifers consist of sand and gravel formed in alluvial fans which border the fronts of central mountains. Thanks to high density of monitoring wells which provide a window to see the details of the subsurface temperature distribution and the thermal regime in an alluvial fan system. Our study area, the Choshui Alluvial Fan, is the largest groundwater basin in Taiwan and, located within an area of 2,000 km2, has a population of over 1.5 million. For this work, we investigated temperature-depth profiles using 70 groundwater monitoring wells during 2000 to 2015. Our results show that the distribution of subsurface temperature is influenced by various factors such as groundwater recharge, groundwater flow field, air temperature and land use. The groundwater recharge zone, hills to the upper fan, contains disturbed and smaller geothermal gradients. The lack of clay layers within the upper fan aquifers and fractures that developed in the hills should cause the convection and mixing of cooler recharge water to groundwater, resulting in smaller geothermal gradients. The groundwater temperatures at a depth to 300 m within the upper fan and hill were approximately only 23-24 °C while the current mean ground surface temperature is approximately 26 °C.

  7. A 1-D Cryothermal Model of Ceres’ Megaregolith: Predictions for Surface Vapor Flux, Subsurface Temperatures and Pore Ice Distribution

    NASA Astrophysics Data System (ADS)

    Reynolds, Dylan; Wood, Stephen E.; Bapst, Jonathan; Mehlhaff, Joshua; Griffiths, Stephen G.

    2014-11-01

    We have applied a self-consistent 1-D model for heat diffusion, vapor diffusion, and ice condensation/sublimation, and surface energy balance to investigate our hypothesis for the source of the recently observed water vapor around Ceres [1]. As described in a companion presentation [2], we find that the estimated global flux of 6 kg/s can be produced by steady-state sublimation of subsurface ice driven by the “geothermal” temperature gradient for a heat flux of 1 mW/m2 - the value estimated for a chondritic abundance of heat-producing elements [3,4]. We will present a detailed description of our Ceres cryothermal diffusion model and comparisons with previous models. One key difference is the use of a new physics-based analytic model (‘MaxRTCM’) for calculating the thermal conductivity (Kth) of planetary regolith [5] that has been validated by comparisons to a wide range of laboratory data [6]. MaxRTCM predicts much lower Kth values in the upper regolith than those in previous work [3]. It also accounts for a process first modeled in a study of unstable equatorial ground ice on Mars [7,8], where vapor diffusing up from a receding ice table toward the surface can recondense at shallower depths - eventually forming a steady-state profile of pore ice volume fraction that increases with depth and maintains a constant flux of vapor at all depths [7]. Using MaxRTCM we calculate the corresponding Kth(z) profiles and will present predictions and implications of the resulting temperature profile in the upper few kilometers of Ceres’ megaregolith.References: [1] Küppers et al. (2014), Nature, 505(7484), 525-527. [2] Wood et al., 2014, this meeting. [3] Fanale & Salvail (1989) Icarus 82, 97-110. [4] McCord and Sotin (2005) JGR 110, E05009. [5] Wood (2013) LPSC Abs. 44, 3077. [6] Wood (2014), Icarus, in revision. [7] Mellon et al. (1997), JGR, 102, 19357-69. [8] Clifford (1993), JGR, 98, 10973-11016.

  8. Depth profiling analysis of solar wind helium collected in diamond-like carbon film from Genesis

    DOE PAGES

    Bajo, Ken-ichi; Olinger, Chad T.; Jurewicz, Amy J.G.; ...

    2015-01-01

    The distribution of solar-wind ions in Genesis mission collectors, as determined by depth profiling analysis, constrains the physics of ion solid interactions involving the solar wind. Thus, they provide an experimental basis for revealing ancient solar activities represented by solar-wind implants in natural samples. We measured the first depth profile of ⁴He in a collector; the shallow implantation (peaking at <20 nm) required us to use sputtered neutral mass spectrometry with post-photoionization by a strong field. The solar wind He fluence calculated using depth profiling is ~8.5 x 10¹⁴ cm⁻². The shape of the solar wind ⁴He depth profile ismore » consistent with TRIM simulations using the observed ⁴He velocity distribution during the Genesis mission. It is therefore likely that all solar-wind elements heavier than H are completely intact in this Genesis collector and, consequently, the solar particle energy distributions for each element can be calculated from their depth profiles. Ancient solar activities and space weathering of solar system objects could be quantitatively reproduced by solar particle implantation profiles.« less

  9. The 2003 November 14 occultation by Titan of TYC 1343-1865-1. II. Analysis of light curves

    NASA Astrophysics Data System (ADS)

    Zalucha, A.; Fitzsimmons, A.; Elliot, J. L.; Thomas-Osip, J.; Hammel, H. B.; Dhillon, V. S.; Marsh, T. R.; Taylor, F. W.; Irwin, P. G. J.

    2007-12-01

    We observed a stellar occultation by Titan on 2003 November 14 from La Palma Observatory using ULTRACAM with three Sloan filters: u, g, and i (358, 487, and 758 nm, respectively). The occultation probed latitudes 2° S and 1° N during immersion and emersion, respectively. A prominent central flash was present in only the i filter, indicating wavelength-dependent atmospheric extinction. We inverted the light curves to obtain six lower-limit temperature profiles between 335 and 485 km (0.04 and 0.003 mb) altitude. The i profiles agreed with the temperature measured by the Huygens Atmospheric Structure Instrument [Fulchignoni, M., and 43 colleagues, 2005. Nature 438, 785-791] above 415 km (0.01 mb). The profiles obtained from different wavelength filters systematically diverge as altitude decreases, which implies significant extinction in the light curves. Applying an extinction model [Elliot, J.L., Young, L.A., 1992. Astron. J. 103, 991-1015] gave the altitudes of line of sight optical depth equal to unity: 396±7 and 401±20 km ( u immersion and emersion); 354±7 and 387±7 km ( g immersion and emersion); and 336±5 and 318±4 km ( i immersion and emersion). Further analysis showed that the optical depth follows a power law in wavelength with index 1.3±0.2. We present a new method for determining temperature from scintillation spikes in the occulting body's atmosphere. Temperatures derived with this method are equal to or warmer than those measured by the Huygens Atmospheric Structure Instrument. Using the highly structured, three-peaked central flash, we confirmed the shape of Titan's middle atmosphere using a model originally derived for a previous Titan occultation [Hubbard, W.B., and 45 colleagues, 1993. Astron. Astrophys. 269, 541-563].

  10. Temperature profile for glacial ice at the South Pole: Implications for life in a nearby subglacial lake

    PubMed Central

    Price, P. Buford; Nagornov, Oleg V.; Bay, Ryan; Chirkin, Dmitry; He, Yudong; Miocinovic, Predrag; Richards, Austin; Woschnagg, Kurt; Koci, Bruce; Zagorodnov, Victor

    2002-01-01

    Airborne radar has detected ≈100 lakes under the Antarctic ice cap, the largest of which is Lake Vostok. International planning is underway to search in Lake Vostok for microbial life that may have evolved in isolation from surface life for millions of years. It is thought, however, that the lakes may be hydraulically interconnected. If so, unsterile drilling would contaminate not just one but many of them. Here we report measurements of temperature vs. depth down to 2,345 m in ice at the South Pole, within 10 km from a subglacial lake seen by airborne radar profiling. We infer a temperature at the 2,810-m deep base of the South Pole ice and at the lake of −9°C, which is 7°C below the pressure-induced melting temperature of freshwater ice. To produce the strong radar signal, the frozen lake must consist of a mix of sediment and ice in a flat bed, formed before permanent Antarctic glaciation. It may, like Siberian and Antarctic permafrost, be rich in microbial life. Because of its hydraulic isolation, proximity to South Pole Station infrastructure, and analog to a Martian polar cap, it is an ideal place to test a sterile drill before risking contamination of Lake Vostok. From the semiempirical expression for strain rate vs. shear stress, we estimate shear vs. depth and show that the IceCube neutrino observatory will be able to map the three-dimensional ice-flow field within a larger volume (0.5 km3) and at lower temperatures (−20°C to −35°C) than has heretofore been possible. PMID:12060731

  11. Comparison of stable boundary layer depth estimation from sodar and profile mast.

    NASA Astrophysics Data System (ADS)

    Dieudonne, Elsa; Anderson, Philip

    2015-04-01

    The depth of the atmospheric turbulent mixing layer next to the earths surface, hz, is a key parameter in analysis and modeling of the interaction of the atmosphere with the surface. The transfer of momentum, heat, moisture and trace gases are to a large extent governed by this depth, which to a first approximation acts as a finite reservoir to these quantities. Correct estimates of the evolution of hz assists the would allow accurate prognosis of the near-surface accumulation of these variables, that is, wind speed, temperature, humidity and tracer concentration. Measuring hz however is not simple, especially where stable stratification acts to reduce internal mixing, and indeed, it is not clear whether hz is similar for momentum, heat and tracer. Two methods are compared here, to assess their similarity: firstly using acoustic back-scatter is used as an indicator of turbulent strength, the upper limit implying a change to laminar flow and the top of the boundary layer. Secondly, turbulence kinetic energy profiles, TKE(z), are extrapolated to estimate z for TKE(z) = 0, again implying laminar flow. Both techniques have the implied benefit of being able to run continually (via sodar and turbulence mast respectively) with the prospect of continual, autonomous data analysis generating time series of hz. This report examines monostatic sodar echo and sonic anemometer-derived turbulence profile data from Halley Station on the Brunt Ice Shelf Antarctica, during the austral winter of 2003. We report that the two techniques frequently show significant disagreement in estimated depth, and still require manual intervention, but further progress is possible.

  12. Flow characteristics control turnover of polar trace organic compounds in the hyporheic zone of an urban lowland river

    NASA Astrophysics Data System (ADS)

    Schaper, Jonas L.; Seher, Wiebke; Jaeger, Anna; Galloway, Jason; Nuetzmann, Gunnar; Putschew, Anke; Lewandowski, Joerg

    2017-04-01

    Hyporheic zones are hypothesized to be important sinks for polar trace organic compounds (TrOCs) in lotic systems, mitigating potential adverse effects of TrOCs on ecosystem functioning and drinking water production. Predicting the fate of TrOCs in the hyporheic zone, however, is difficult as the attenuation rate itself as well as the biogeochemical factors and hydrological conditions controlling attenuation rates are unknown. We used time series of temperature depth profiles as well as heat pulse sensing with a 1D advection dispersion transport model to calculate first order attenuation rates of several TrOCs from equilibrium depth profiles in an urban lowland river in Berlin, Germany. Ring enclosures were used to prohibit horizontal flow and to create distinct biogeochemical conditions within the hyporheic zone. Flow characteristics as well as biogeochemical conditions showed pronounced differences between depth profiles inside and outside of enclosures. TrOCs attenuation rates varied considerably among compounds reflecting their general susceptibility to biodegradation and sorption. While for some compounds such as benzotriazole and sulfamethoxazole redox conditions had an influence on attenuation rates, the fate of other compounds was not affected by biogeochemical parameters. Under loosing conditions, hyporheic zones of urban lowland rivers can thus be regarded as sinks for TrOCs. Their effectiveness is dependent on both, hyporheic exchange characteristics as well as biogeochemical parameters.

  13. Hybrid Organic/Inorganic Materials Depth Profiling Using Low Energy Cesium Ions

    NASA Astrophysics Data System (ADS)

    Noël, Céline; Houssiau, Laurent

    2016-05-01

    The structures developed in organic electronics, such as organic light emitting diodes (OLEDs) or organic photovoltaics (OPVs) devices always involve hybrid interfaces, joining metal or oxide layers with organic layers. No satisfactory method to probe these hybrid interfaces physical chemistry currently exists. One promising way to analyze such interfaces is to use in situ ion beam etching, but this requires ion beams able to depth profile both inorganic and organic layers. Mono- or diatomic ion beams commonly used to depth profile inorganic materials usually perform badly on organics, while cluster ion beams perform excellently on organics but yield poor results when organics and inorganics are mixed. Conversely, low energy Cs+ beams (<500 eV) allow organic and inorganic materials depth profiling with comparable erosion rates. This paper shows a successful depth profiling of a model hybrid system made of metallic (Au, Cr) and organic (tyrosine) layers, sputtered with 500 eV Cs+ ions. Tyrosine layers capped with metallic overlayers are depth profiled easily, with high intensities for the characteristic molecular ions and other specific fragments. Metallic Au or Cr atoms are recoiled into the organic layer where they cause some damage near the hybrid interface as well as changes in the erosion rate. However, these recoil implanted metallic atoms do not appear to severely degrade the depth profile overall quality. This first successful hybrid depth profiling report opens new possibilities for the study of OLEDs, organic solar cells, or other hybrid devices.

  14. Estimation of bare soil evaporation for different depths of water table in the wind-blown sand area of the Ordos Basin, China

    NASA Astrophysics Data System (ADS)

    Chen, Li; Wang, Wenke; Zhang, Zaiyong; Wang, Zhoufeng; Wang, Qiangmin; Zhao, Ming; Gong, Chengcheng

    2018-04-01

    Soil surface evaporation is a significant component of the hydrological cycle, occurring at the interface between the atmosphere and vadose zone, but it is affected by factors such as groundwater level, soil properties, solar radiation and others. In order to understand the soil evaporation characteristics in arid regions, a field experiment was conducted in the Ordos Basin, central China, and high accuracy sensors of soil moisture, moisture potential and temperature were installed in three field soil profiles with water-table depths (WTDs) of about 0.4, 1.4 and 2.2 m. Soil-surface-evaporation values were estimated by observed data combined with Darcy's law. Results showed that: (1) soil-surface-evaporation rate is linked to moisture content and it is also affected by air temperature. When there is sufficient moisture in the soil profile, soil evaporation increases with rising air temperature. For a WTD larger than the height of capillary rise, the soil evaporation is related to soil moisture content, and when air temperature is above 25 °C, the soil moisture content reduces quickly and the evaporation rate lowers; (2) phreatic water contributes to soil surface evaporation under conditions in which the WTD is within the capillary fringe. This indicates that phreatic water would not participate in soil evaporation for a WTD larger than the height of capillary rise. This finding developed further the understanding of phreatic evaporation, and this study provides valuable information on recognized soil evaporation processes in the arid environment.

  15. Neogene Uplift and Magmatism of Anatolia: Insights From Drainage Analysis and Basaltic Geochemistry

    NASA Astrophysics Data System (ADS)

    McNab, F.; Ball, P. W.; Hoggard, M. J.; White, N. J.

    2018-01-01

    It is agreed that mantle dynamics have played a role in generating and maintaining the elevated topography of Anatolia during Neogene times. However, there is debate about the relative importance of subduction zone and asthenospheric processes. Key issues concern onset and cause of regional uplift, thickness of the lithospheric plate, and the presence/absence of temperature and/or compositional anomalies within the convecting mantle. Here, we tackle these interlinked issues by analyzing and modeling two disparate suites of observations. First, a drainage inventory of 1,844 longitudinal river profiles is assembled. This database is inverted to calculate the variation of Neogene regional uplift through time and space by minimizing the misfit between observed and calculated river profiles subject to independent calibration. Our results suggest that regional uplift commenced at 20 Ma in the east and propagated westward. Second, we have assembled a database of geochemical analyses of basaltic rocks. Two different approaches have been used to quantitatively model this database with a view to determining the depth and degree of asthenospheric melting across Anatolia. Our results suggest that melting occurs at depths as shallow as 60 km in the presence of mantle potential temperatures as high as 1400°C. There is evidence that temperatures are higher in the east, consistent with the pattern of subplate shear wave velocity anomalies. Our combined results are consistent with isostatic and admittance analyses and suggest that elevated asthenospheric temperatures beneath thinned Anatolian lithosphere have played a first-order role in generating and maintaining regional dynamic topography and basaltic magmatism.

  16. PATCHY ACCRETION DISKS IN ULTRA-LUMINOUS X-RAY SOURCES

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Miller, J. M.; Bachetti, M.; Barret, D.

    2014-04-10

    The X-ray spectra of the most extreme ultra-luminous X-ray sources—those with L ≥ 10{sup 40} erg s{sup –1}—remain something of a mystery. Spectral roll-over in the 5-10 keV band was originally detected in the deepest XMM-Newton observations of the brightest sources; this is confirmed in subsequent NuSTAR spectra. This emission can be modeled via Comptonization, but with low electron temperatures (kT{sub e} ≅ 2 keV) and high optical depths (τ ≅ 10) that pose numerous difficulties. Moreover, evidence of cooler thermal emission that can be fit with thin disk models persists, even in fits to joint XMM-Newton and NuSTAR observations.more » Using NGC 1313 X-1 as a test case, we show that a patchy disk with a multiple temperature profile may provide an excellent description of such spectra. In principle, a number of patches within a cool disk might emit over a range of temperatures, but the data only require a two-temperature profile plus standard Comptonization, or three distinct blackbody components. A mechanism such as the photon bubble instability may naturally give rise to a patchy disk profile, and could give rise to super-Eddington luminosities. It is possible, then, that a patchy disk (rather than a disk with a standard single-temperature profile) might be a hallmark of accretion disks close to or above the Eddington limit. We discuss further tests of this picture and potential implications for sources such as narrow-line Seyfert-1 galaxies and other low-mass active galactic nuclei.« less

  17. The failure of 1D seismic model fitting to constrain lower mantle composition

    NASA Astrophysics Data System (ADS)

    Houser, C. T.; Hernlund, J. W.; Valencia-Cardona, J. J.; Wentzcovitch, R.

    2017-12-01

    Tests of lower mantle composition models often compare mineral physics data bearing on the elasticity and density of lower mantle phases to the average seismic velocity profile determined by seismology, such a PREM or ak135. We demonstrate why such comparisons between mineralogy and seismology are an inadequate method for definitive discrimination between different scenarios. One issue is that the seismic velocity is more sensitive to temperature than composition for most lower mantle minerals. In practice, this allows one the freedom to choose the geotherm that brings the predicted seismic and density data into agreement with observations. It is commonly assumed that the temperature profile should be adiabatic, however, such a profile presupposes a particular state of the mantle and is only applicable in the absence of layering, buoyancy fluctuations, compositional segregation, and rheological complexities. The mantle temperature should depend on the composition since the latter influences the viscosity of rocks. However, the precise relation between composition, viscosity, and heat transfer would need to be specified, but unfortunately remains highly uncertain. If the mantle contains a mixture of domains with multiple bulk compositions, then the 1D seismic profile comparison is inherently non-unique. Rocks with different bulk composition likely have different isotopic abundances, and can exhibit differing degrees of internal heating and therefore distinct temperatures. Different composition domains can also exhibit variable densities, and tend to congregate at different depths in ways that also affect their thermal evolution and temperature. Therefore, fitting a 1D seismic model alone is an inadequate tool to evaluate lower mantle composition.

  18. Utility of bromide and heat tracers for aquifer characterization affected by highly transient flow conditions

    NASA Astrophysics Data System (ADS)

    Ma, Rui; Zheng, Chunmiao; Zachara, John M.; Tonkin, Matthew

    2012-08-01

    A tracer test using both bromide and heat tracers conducted at the Integrated Field Research Challenge site in Hanford 300 Area (300A), Washington, provided an instrument for evaluating the utility of bromide and heat tracers for aquifer characterization. The bromide tracer data were critical to improving the calibration of the flow model complicated by the highly dynamic nature of the flow field. However, most bromide concentrations were obtained from fully screened observation wells, lacking depth-specific resolution for vertical characterization. On the other hand, depth-specific temperature data were relatively simple and inexpensive to acquire. However, temperature-driven fluid density effects influenced heat plume movement. Moreover, the temperature data contained "noise" caused by heating during fluid injection and sampling events. Using the hydraulic conductivity distribution obtained from the calibration of the bromide transport model, the temperature depth profiles and arrival times of temperature peaks simulated by the heat transport model were in reasonable agreement with observations. This suggested that heat can be used as a cost-effective proxy for solute tracers for calibration of the hydraulic conductivity distribution, especially in the vertical direction. However, a heat tracer test must be carefully designed and executed to minimize fluid density effects and sources of noise in temperature data. A sensitivity analysis also revealed that heat transport was most sensitive to hydraulic conductivity and porosity, less sensitive to thermal distribution factor, and least sensitive to thermal dispersion and heat conduction. This indicated that the hydraulic conductivity remains the primary calibration parameter for heat transport.

  19. Utility of Bromide and Heat Tracers for Aquifer Characterization Affected by Highly Transient Flow Conditions

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Ma, Rui; Zheng, Chunmiao; Zachara, John M.

    A tracer test using both bromide and heat tracers conducted at the Integrated Field Research Challenge site in Hanford 300 Area (300A), Washington, provided an instrument for evaluating the utility of bromide and heat tracers for aquifer characterization. The bromide tracer data were critical to improving the calibration of the flow model complicated by the highly dynamic nature of the flow field. However, most bromide concentrations were obtained from fully screened observation wells, lacking depth-specific resolution for vertical characterization. On the other hand, depth-specific temperature data were relatively simple and inexpensive to acquire. However, temperature-driven fluid density effects influenced heatmore » plume movement. Moreover, the temperature data contained “noise” caused by heating during fluid injection and sampling events. Using the hydraulic conductivity distribution obtained from the calibration of the bromide transport model, the temperature depth profiles and arrival times of temperature peaks simulated by the heat transport model were in reasonable agreement with observations. This suggested that heat can be used as a cost-effective proxy for solute tracers for calibration of the hydraulic conductivity distribution, especially in the vertical direction. However, a heat tracer test must be carefully designed and executed to minimize fluid density effects and sources of noise in temperature data. A sensitivity analysis also revealed that heat transport was most sensitive to hydraulic conductivity and porosity, less sensitive to thermal distribution factor, and least sensitive to thermal dispersion and heat conduction. This indicated that the hydraulic conductivity remains the primary calibration parameter for heat transport.« less

  20. Elastic and anelastic structure of the lowermost mantle beneath the Western Pacific from waveform inversion

    NASA Astrophysics Data System (ADS)

    Konishi, Kensuke; Fuji, Nobuaki; Deschamps, Frédéric

    2017-03-01

    We investigate the elastic and anelastic structure of the lowermost mantle at the western edge of the Pacific large low shear velocity province (LLSVP) by inverting a collection of S and ScS waveforms. The transverse component data were obtained from F-net for 31 deep earthquakes beneath Tonga and Fiji, filtered between 12.5 and 200 s. We observe a regional variation of S and ScS arrival times and amplitude ratios, according to which we divide our region of interest into three subregions. For each of these subregions, we then perform 1-D (depth-dependent) waveform inversions simultaneously for radial profiles of shear wave velocity (VS) and seismic quality factor (Q). Models for all three subregions show low VS and low Q structures from 2000 km depth down to the core-mantle boundary. We further find that VS and Q in the central subregion, sampling the Caroline plume, are substantially lower than in the surrounding regions, whatever the depth. In the central subregion, VS-anomalies with respect to PREM (dVS) and Q are about -2.5 per cent and 216 at a depth of 2850 km, and -0.6 per cent and 263 at a depth of 2000 km. By contrast, in the two other regions, dVS and Q are -2.2 per cent and 261 at a depth of 2850 km, and -0.3 per cent and 291 at a depth of 2000 km. At depths greater than ∼2500 km, these differences may indicate lateral variations in temperature of ∼100 K within the Pacific LLSVP. At shallower depths, they may be due to the temperature difference between the Caroline plume and its surroundings, and possibly to a small fraction of iron-rich material entrained by the plume.

  1. Synthetic receiver function profiles through the upper mantle and the transition zone for upwelling scenarios

    NASA Astrophysics Data System (ADS)

    Nagel, Thorsten; Düsterhöft, Erik; Schiffer, Christian

    2017-04-01

    We investigate the signature relevant mantle lithologies leave in the receiver function record for different adiabatic thermal gradients down to 800 kilometers depth. The parameter space is chosen to target the visibility of upwelling mantle (a plume). Seismic velocities for depleted mantle, primitive mantle, and three pyroxenites are extracted from thermodynamically calculated phases diagrams, which also provide the adiabatic decompression paths. Results suggest that compositional variations, i.e. the presence or absence of considerable amounts of pyroxenites in primitive mantle should produce a clear footprint while horizontal differences in thermal gradients for similar compositions might be more subtle. Peridotites best record the classic discontinuities at around 410 and 650 kilometers depth, which are associated with the olivin-wadsleyite and ringwoodite-perovskite transitions, respectively. Pyroxenites, instead, show the garnet-perovskite transition below 700 kilometers depth and SiO2-supersaturated compositions like MORB display the coesite-stishovite transition between 300 and 340 kilometers depth. The latter shows the strongest temperature-depth dependency of all significant transitions potentially allowing to infer information about the thermal state if the mantle contains a sufficient fraction of MORB-like compositions. For primitive and depleted mantle compositions, the olivin-wadsleyite transition shows a certain temperature-depth dependency reflected in slightly larger delay times for higher thermal gradients. The lower-upper-mantle discontinuity, however, is predicted to display larger delay times for higher thermal gradients although the associated assemblage transition occurs at shallower depths thus requiring a very careful depth migration if a thermal anomaly should be recognized. This counterintuitive behavior results from the downward replacement of the assemblage wadsleyite+garnet with the assemblage garnet+periclase at high temperatures. This transition causes even lower seismic velocities with greater depth (following an adiabatic gradient), the highly continuous nature of the reaction, however, should produce only a smooth negative conversion. In contrast, a small positive conversion is expected at normal thermal gradients in the same depth range between 500 and 550 kilometers because of the wadsleyite-ringwoodite-transition. Hence, the polarity of the 520 discontinuity also offers a possibility to recognize the thermal state of the upper mantle.

  2. Vertical Mixing In Western Lake Constance Due To Long Internal Waves

    NASA Astrophysics Data System (ADS)

    Boehrer, B.

    Current profiles in the pelagic waters of western Lake Constance have been broken up into modes of the internal wave equation [1,2]. All current profiles can be well represented by a combination of the first and second mode wave. The temporal vari- ation of the modal composition with the interaction of the first and second mode im- plies current shear at varying depths. From current and density profiles, the gradient Richardson number can be evaluated in its spatial and temporal pattern with occa- tional occurence of supercritical values at all depths, also in the deep hypolimnion. An empiric connection between gradient Richardson number and diapycnical mixing [3] is applied to yield a profile of vertical transport coefficients, which can be com- pared with transport coefficients from gradient flux calculations of temperature and electrical conductivity profiles [4]. [1] B. Boehrer, J. Ilmberger and K.O. Münnich (2000): Vertical Structure of Current in Western Lake Constance, JGR-Oceans, 105 (12), 28823-28835 [2] B. Boehrer (2000): Modal Response of a Deep Stratified Lake: Western Lake Con- stance, JGR-Oceans, 105 (12), 28837-28845 [3] H. Peeters, M.C. Gregg and J.M. Toole (1988): On the parameterization of equa- torial turbulence, JGR, 93, 1199-1218 [4] G. Heinz, J. Ilmberger and M. Schimmele (1990): Vertical Mixing in Überlinger See, western part of Lake Constance, Aquat. Sci., 52(3), 256-268

  3. High-latitude stratospheric aerosols measured by the SAM II satellite system in 1978 and 1979

    NASA Technical Reports Server (NTRS)

    Mccormick, M. P.; Chu, W. P.; Mcmaster, L. R.; Grams, G. W.; Hamill, P.; Steele, H. M.; Swissler, T. J.; Herman, B. M.; Pepin, T. J.; Russell, P. B.

    1981-01-01

    Results of the first year of data collection by the SAM (Stratospheric Aerosol Measurement) II satellite system are presented. Almost 10,000 profiles of stratospheric aerosol extinction in the Arctic and Antarctic regions are used to construct plots of weekly averaged aerosol extinction versus altitude and time and stratospheric optical depth versus time. Corresponding temperature fields are presented. These data show striking similarities in the aerosol behavior for corresponding seasons. Wintertime polar stratospheric clouds that are strongly correlated with temperature are documented. They are much more prevalent in the Antarctic stratosphere during the cold austral winter and increase the stratospheric optical depths by as much as an order of magnitude for a period of about 2 months. These clouds might represent a sink for stratospheric water vapor and must be considered in the radiative budget for this region and time.

  4. Nitridation of silicon by nitrogen neutral beam

    NASA Astrophysics Data System (ADS)

    Hara, Yasuhiro; Shimizu, Tomohiro; Shingubara, Shoso

    2016-02-01

    Silicon nitridation was investigated at room temperature using a nitrogen neutral beam (NB) extracted at acceleration voltages of less than 100 V. X-ray photoelectron spectroscopy (XPS) analysis confirmed the formation of a Si3N4 layer on a Si (1 0 0) substrate when the acceleration voltage was higher than 20 V. The XPS depth profile indicated that nitrogen diffused to a depth of 36 nm for acceleration voltages of 60 V and higher. The thickness of the silicon nitrided layer increased with the acceleration voltages from 20 V to 60 V. Cross-sectional transmission electron microscopy (TEM) analysis indicated a Si3N4 layer thickness of 3.1 nm was obtained at an acceleration voltage of 100 V. Moreover, it was proved that the nitrided silicon layer formed by the nitrogen NB at room temperature was effective as the passivation film in the wet etching process.

  5. Thermal stability of implanted dopants in GaN

    NASA Astrophysics Data System (ADS)

    Wilson, R. G.; Pearton, S. J.; Abernathy, C. R.; Zavada, J. M.

    1995-04-01

    Results are reported of measurements of depth profiles and stability against redistribution with annealing up to 800 or 900 °C, for implanted Be, C, Mg, Si, S, Zn, Ge, and Se as dopants in GaN. The results confirm the high-temperature stability of dopants in this material up to temperatures that vary from 600 to 900 °C. S redistributes for temperatures above 600 °C, and Zn and Se, for temperatures above 800 °C. All of the other elements are stable to 900 °C. These results indicate that direct implantation of dopants rather than masked diffusion will probably be necessary to define selective area doping of III-V nitride device structures based on these results for GaN.

  6. Subsurface temperatures and geothermal gradients on the North Slope, Alaska

    USGS Publications Warehouse

    Collett, Timothy S.; Bird, Kenneth J.; Magoon, Leslie B.

    1989-01-01

    Geothermal gradients as interpreted from a series of high-resolution stabilized well-bore-temperature surveys from 46 North Slope, Alaska, wells vary laterally and vertically throughout the near-surface sediment (0-2,000 m). The data from these surveys have been used in conjunction with depths of ice-bearing permafrost, as interpreted from 102 well logs, to project geothermal gradients within and below the ice-bearing permafrost sequence. The geothermal gradients calculated from the projected temperature profiles are similar to the geothermal gradients measured in the temperature surveys. Measured and projected geothermal gradients in the ice-bearing permafrost sequence range from 1.5??C/100m in the Prudhoe Bay area to 5.1??C/100m in the National Petroleum Reserve in Alaska (NPRA).

  7. Microscopic contour changes of tribological surfaces by chemical and mechanical action

    NASA Technical Reports Server (NTRS)

    Lauer, J. L.; Fung, S. S.

    1982-01-01

    An electronic optical laser interferometer capable of resolving depth differences of as low as 30 A and planar displacements of 6000 A was constructed for the examination of surface profiles of bearing surfaces without physical contact. This instrument was used to determine topological chemical reactivity by applying a drop of dilute alcoholic hydrochloric acid and measuring the profile of the solid surface before and after application of this probe. It was found that scuffed bearing surfaces reacted much faster than virgin ones but that bearing surfaces exposed to lubricants containing an organic chloride reacted much more slowly. In a separate series of experiments, a number of stainless steel plates were heated in a nitrogen atmosphere to different temperatures and their reactivity examined later at ambient temperature. The change of surface contour as a result of the probe reaction was found to follow an Arrhenius-type relation with respect to heat treatment temperature. This result could have implications on the scuffing mechanism.

  8. 3D-modelling of the thermal circumstances of a lake under artificial aeration

    NASA Astrophysics Data System (ADS)

    Tian, Xiaoqing; Pan, Huachen; Köngäs, Petrina; Horppila, Jukka

    2017-12-01

    A 3D-model was developed to study the effects of hypolimnetic aeration on the temperature profile of a thermally stratified Lake Vesijärvi (southern Finland). Aeration was conducted by pumping epilimnetic water through the thermocline to the hypolimnion without breaking the thermal stratification. The model used time transient equation based on Navier-Stokes equation. The model was fitted to the vertical temperature distribution and environmental parameters (wind, air temperature, and solar radiation) before the onset of aeration, and the model was used to predict the vertical temperature distribution 3 and 15 days after the onset of aeration (1 August and 22 August). The difference between the modelled and observed temperature was on average 0.6 °C. The average percentage model error was 4.0% on 1 August and 3.7% on 22 August. In the epilimnion, model accuracy depended on the difference between the observed temperature and boundary conditions. In the hypolimnion, the model residual decreased with increasing depth. On 1 August, the model predicted a homogenous temperature profile in the hypolimnion, while the observed temperature decreased moderately from the thermocline to the bottom. This was because the effect of sediment was not included in the model. On 22 August, the modelled and observed temperatures near the bottom were identical demonstrating that the heat transfer by the aerator masked the effect of sediment and that exclusion of sediment heat from the model does not cause considerable error unless very short-term effects of aeration are studied. In all, the model successfully described the effects of the aerator on the lake's temperature profile. The results confirmed the validity of the applied computational fluid dynamic in artificial aeration; based on the simulated results, the effect of aeration can be predicted.

  9. Effect of high night temperature on storage lipids and transcriptome changes in developing seeds of oilseed rape.

    PubMed

    Zhou, Longhua; Yan, Tao; Chen, Xin; Li, Zhilan; Wu, Dezhi; Hua, Shuijin; Jiang, Lixi

    2018-03-24

    Global warming causes a faster increase of night temperature than of day temperature in tropical and subtropical zones. Little is known about the effect of high night temperature on storage lipids and transcriptome changes in oilseed rape. This study compared the total fatty acids and fatty acid compositions in seeds of two oilseed rape cultivars between high and low night temperatures. Their transcriptome profiles were also analyzed. High night temperature significantly affected the total fatty acids and fatty acid compositions in seeds of both low and high oil content cultivars, namely Jiuer-13 and Zheyou-50, thereby resulting in 18.9% and 13.7% total fatty acid reductions, respectively. In particular, high night temperature decreased the relative proportions of C18:0 and C18:1 but increased the proportions of C18:2 and C18:3 in both cultivars. In-depth analysis of transcriptome profiles revealed that high night temperature up-regulated gibberellin signaling during the night-time. This up-regulation was associated with the active expression of genes involved in fatty acid catabolism, such as those in β-oxidation and glyoxylate metabolism pathways. Although the effect of temperature on plant lipids has been previously examined, the present study is the first to focus on night temperature and its effect on the fatty acid composition in seeds.

  10. Titanite chronology, thermometry, and speedometry of ultrahigh-temperature (UHT) calc-silicates from south Madagascar: U-Pb dates, Zr temperatures, and lengthscales of trace-element diffusion

    NASA Astrophysics Data System (ADS)

    Holder, R. M.; Hacker, B. R.

    2017-12-01

    Calc-silicate rocks are often overlooked as sources of pressure-temperature-time data in granulite-UHT metamorphic terranes due to the strong dependence of calc-silicate mineral assemblages on complex fluid compositions and a lack of thermodynamic data on common high-temperature calc-silicate minerals such as scapolite. In the Ediacaran-Cambrian UHT rocks of southern Madagascar, clinopyroxene-scapolite-feldspar-quartz-zircon-titanite calc-silicate rocks are wide-spread. U-Pb dates of 540-520 Ma from unaltered portions of titanite correspond to cooling of the rocks through upper-amphibolite facies and indicate UHT metamorphism occurred before 540 Ma. Zr concentrations in these domains preserve growth temperatures of 900-950 °C, consistent with peak temperatures calculated by pseudosection modeling of nearby osumilite-bearing gneisses. Younger U-Pb dates (510-490 Ma) correspond to fluid-mediated Pb loss from titanite grains, which occurred below their diffusive Pb-closure temperature, along fractures. The extent of fluid alteration is seen clearly in back-scattered electron images and Zr-, Al-, Fe-, Ce-, and Nb-concentration maps. Laser-ablation depth profiling of idioblastic titanite grains shows preserved Pb diffusion profiles at grain rims, but there is no evidence for Zr diffusion, indicating that it was effectively immobile even at UHT.

  11. Elephant Seals and Temperature Data: Calibrations and Limitations.

    NASA Astrophysics Data System (ADS)

    Simmons, S. E.; Tremblay, Y.; Costa, D. P.

    2006-12-01

    In recent years with technological advances, instruments deployed on diving marine animals have been used to sample the environment in addition to their behavior. Of all oceanographic variables one of the most valuable and easiest to record is temperature. Here we report on a series of lab calibration and field validation experiments that consider the accuracy of temperature measurements from animal borne ocean samplers. Additionally we consider whether sampling frequency or animal behavior affects the quality of the temperature data collected by marine animals. Rapid response, external temperature sensors on eight Wildlife Computers MK9 time-depth recorders (TDRs) were calibrated using water baths at the Naval Postgraduate School (Monterey, CA). These water baths are calibrated using a platinum thermistor to 0.001° C. Instruments from different production batches were calibrated before and after deployments on adult female northern elephant seals, to examine tag performance over time and under `normal' usage. Tag performance in the field was validated by comparisons with temperature data from a Seabird CTD. In April/May of 2004, casts to 200m were performed over the Monterey Canyon using a CTD array carrying MK9s. These casts were performed before and after the release of a juvenile elephant seal from the boat. The seal was also carrying an MK9 TDR, allowing the assessment of any animal effect on temperature profiles. Sampling frequency during these field validations was set at one second intervals and the data from TDRs on both the CTD and the seals was sub-sampled at four, eight, 30 and 300 (5 min) seconds. The sub-sampled data was used to determine thermocline depth, a thermocline depth zone and temperature gradients and assess whether sampling frequency or animal behavior affects the quality of temperature data. Preliminary analyses indicate that temperature sensors deployed on elephant seals can provide water column temperature data of high quality and precision.

  12. Secondary ion mass spectrometry study of ex situ annealing of epitaxial GaAs grown on Si substrates

    NASA Technical Reports Server (NTRS)

    Radhakrishnan, G.; Mccullough, O.; Cser, J.; Katz, J.

    1988-01-01

    Samples of epitaxial GaAs grown on (100) Si substrates using molecular beam epitaxy were annealed at four different temperatures, from 800 to 950 C. Following annealing, the samples were analyzed using secondary ion mass spectrometry. Depth profiles of Ga, As, and Si reveal optimum conditions for annealing, and place a lower limit on a damage threshold for GaAs/Si substrates.

  13. Soil ecology of a rock outcrop ecosystem: Abiotic stresses, soil respiration, and microbial community profiles in limestone cedar glades

    USGS Publications Warehouse

    Cartwright, Jennifer M.; Advised by Dzantor, E. Kudjo

    2015-01-01

    Stress factors quantified by this research include shallow soil (depth to bedrock ranging from 2.4 to 22.6 cm), volumetric soil water content levels seasonally ranging from xeric (below 5%) to saturated (above 50%), and seasonally extreme ground-surface temperatures (above 48°C). Findings from this research indicate that spatial and temporal heterogeneity exists in limestone cedar glades in terms of abiotic stress factors and soil physical and chemical properties. Several such soil properties (e.g. soil depth, organic matter levels, pH, and particle size distribution) are spatially correlated. These soil properties were statistically related to ecological structures and functions such as vegetation patterns, soil respiration, the density of culturable heterotrophic microbes in soil and metabolic diversity of soil microbial community profiles. In general, zones within limestone cedar glades that had relatively shallow soil, alkaline pH, low levels of organic matter and high levels of silt also tended to have depressed rates of soil respiration and reduced densities and metabolic diversity of culturable heterotrophic soil microbes. Additionally, seasonally-relevant stress factors including soil water content and temperatures at or near the soil surface were related to the same set of ecological structures and functions.

  14. Double perovskite cathodes for proton-conducting ceramic fuel cells: are they triple mixed ionic electronic conductors?

    PubMed Central

    Téllez Lozano, Helena; Druce, John; Cooper, Samuel J.; Kilner, John A.

    2017-01-01

    Abstract 18O and 2H diffusion has been investigated at a temperature of 300 °C in the double perovskite material PrBaCo2O5+δ (PBCO) in flowing air containing 200 mbar of 2H2 16O. Secondary ion mass spectrometry (SIMS) depth profiling of exchanged ceramics has shown PBCO still retains significant oxygen diffusivity (~1.3 × 10−11 cm2s−1) at this temperature and that the presence of water (2H2 16O), gives rise to an enhancement of the surface exchange rate over that in pure oxygen by a factor of ~3. The 2H distribution, as inferred from the 2H2 16O− SIMS signal, shows an apparent depth profile which could be interpreted as 2H diffusion. However, examination of the 3-D distribution of the signal shows it to be nonhomogeneous and probably related to the presence of hydrated layers in the interior walls of pores and is not due to proton diffusion. This suggests that PBCO acts mainly as an oxygen ion mixed conductor when used in PCFC devices, although the presence of a small amount of protonic conductivity cannot be discounted in these materials. PMID:29383047

  15. Study of Opacity Effects on Emission Lines at EXTRAP T2R RFP

    NASA Astrophysics Data System (ADS)

    Stancalie, Viorica; Rachlew, Elisabeth

    We have investigated the influence of opacity on hydrogen (H-α and Ly-β) and Li-like oxygen emission lines from the EXTRAP T2R reversed field pinch. We used the Atomic Data Analysis System (AzDAS) based on the escape factor approximation for radiative transfer to calculate metastable and excited population densities via a collisional-radiative model. Population escape factor, emergent escape factor and modified line profiles are plotted vs. optical depth. The simulated emission line ratios in the density/temperature plane are in good agreement with experimental data for electron density and temperature measurements.

  16. Temporal Variability in Vertical Groundwater Fluxes and the Effect of Solar Radiation on Streambed Temperatures Based on Vertical High Resolution Distributed Temperature Sensing

    NASA Astrophysics Data System (ADS)

    Sebok, E.; Karan, S.; Engesgaard, P. K.; Duque, C.

    2013-12-01

    Due to its large spatial and temporal variability, groundwater discharge to streams is difficult to quantify. Methods using vertical streambed temperature profiles to estimate vertical fluxes are often of coarse vertical spatial resolution and neglect to account for the natural heterogeneity in thermal conductivity of streambed sediments. Here we report on a field investigation in a stream, where air, stream water and streambed sediment temperatures were measured by Distributed Temperature Sensing (DTS) with high spatial resolution to; (i) detect spatial and temporal variability in groundwater discharge based on vertical streambed temperature profiles, (ii) study the thermal regime of streambed sediments exposed to different solar radiation influence, (iii) describe the effect of solar radiation on the measured streambed temperatures. The study was carried out at a field site located along Holtum stream, in Western Denmark. The 3 m wide stream has a sandy streambed with a cobbled armour layer, a mean discharge of 200 l/s and a mean depth of 0.3 m. Streambed temperatures were measured with a high-resolution DTS system (HR-DTS). By helically wrapping the fiber optic cable around two PVC pipes of 0.05 m and 0.075 m outer diameter over 1.5 m length, temperature measurements were recorded with 5.7 mm and 3.8 mm vertical spacing, respectively. The HR-DTS systems were installed 0.7 m deep in the streambed sediments, crossing both the sediment-water and the water-air interface, thus yielding high resolution water and air temperature data as well. One of the HR-DTS systems was installed in the open stream channel with only topographical shading, while the other HR-DTS system was placed 7 m upstream, under the canopy of a tree, thus representing the shaded conditions with reduced influence of solar radiation. Temperature measurements were taken with 30 min intervals between 16 April and 25 June 2013. The thermal conductivity of streambed sediments was calibrated in a 1D flow and heat transport model (HydroGeoSphere). Subsequently, time series of vertical groundwater fluxes were computed based on the high-resolution vertical streambed sediment temperature profiles by coupling the model with PEST. The calculated vertical flux time series show spatial differences in discharge between the two HR-DTS sites. A similar temporal variability in vertical fluxes at the two test sites can also be observed, most likely linked to rainfall-runoff processes. The effect of solar radiation as streambed conduction is visible both at the exposed and shaded test site in form of increased diel temperature oscillations up to 14 cm depth from the streambed surface, with the test site exposed to solar radiation showing larger diel temperature oscillations.

  17. Poling-assisted bleaching of soda-lime float glasses containing silver nanoparticles with a decreasing filling factor across the depth

    NASA Astrophysics Data System (ADS)

    Deparis, Olivier; Kazansky, Peter G.; Podlipensky, Alexander; Abdolvand, Amin; Seifert, Gerhard; Graener, Heinrich

    2006-08-01

    The recently discovered poling-assisted bleaching of glass with embedded silver nanoparticles has renewed the interest in thermal poling as a simple, reliable, and low-cost technique for controlling locally the surface-plasmon-resonant optical properties of metal-doped nanocomposite glasses. In the present study, the emphasis is put on the influence of the volume filling factor of metallic clusters on poling-assisted bleaching. Soda-lime silicate glass samples containing spherical silver nanoparticles with a decreasing filling factor across the depth were subject to thermal poling experiments with various poling temperatures, voltages, and times. Optical extinction spectra were measured from ultraviolet to near-infrared ranges and the surface-plasmon-resonant extinction due to silver nanoparticles (around 410nm) was modeled by the Maxwell Garnett [Philos. Trans. R. Soc. London, Ser. A 203, 385 (1904); 205, 237 (1906)] effective medium theory which was adapted in order to take into account the filling factor depth profile. A method was proposed for the retrieval of the filling factor depth profile from optical extinction spectra recorded in fresh and chemically etched samples. A stretched exponential depth profile turned out to be necessary in order to model samples having a high filling factor near the surface. Based on the fact that the electric-field-assisted dissolution of embedded metallic nanoparticles proceeded progressively from the top surface, a bleaching front was defined that moved forward in depth as time elapsed. The position of the bleaching front was determined after each poling experiment by fitting the measured extinction spectrum to the theoretical one. In samples with higher peak value and steeper gradient of the filling factor, the bleaching front reached more rapidly a steady-state depth as poling time increased. Also it increased less strongly with increasing poling voltage. These results were in agreement with the physics of the dissolution process. Finally, clear evidence of injection of hydrogenated ionic species from the atmosphere into the sample during poling was obtained from the growth of the infrared extinction peak associated with OH radicals.

  18. Eddy Seeding in the Labrador Sea: a Submerged Autonomous Launching Platform (SALP) Application

    NASA Astrophysics Data System (ADS)

    Furey, Heather H.; Femke de Jong, M.; Bower, Amy S.

    2013-04-01

    A simplified Submerged Autonomous Launch Platform (SALP) was used to release profiling floats into warm-core Irminger Rings (IRs) in order to investigate their vertical structure and evolution in the Labrador Sea from September 2007 - September 2009. IRs are thought to play an important role in restratification after convection in the Labrador Sea. The SALP is designed to release surface drifters or subsurface floats serially from a traditional ocean mooring, using real-time ocean measurements as criteria for launch. The original prototype instrument used properties measured at multiple depths, with information relayed to the SALP controller via acoustic modems. In our application, two SALP carousels were attached at 500 meters onto a heavily-instrumented deep water mooring, in the path of recently-shed IRs off the west Greenland shelf. A release algorithm was designed to use temperature and pressure measured at the SALP depth only to release one or two APEX profiling drifters each time an IR passed the mooring, using limited historical observations to set release thresholds. Mechanically and electronically, the SALP worked well: out of eleven releases, there was only one malfunction when a float was caught in the cage after the burn-wire had triggered. However, getting floats trapped in eddies met with limited success due to problems with the release algorithm and float ballasting. Out of seven floats launched from the platform using oceanographic criteria, four were released during warm water events that were not related to passing IRs. Also, after float release, it took on average about 2.6 days for the APEX to adjust from its initial ballast depth, about 600 meters, to its park point of 300 meters, leaving the float below the trapped core of water in the IRs. The other mooring instruments (at depths of 100 to 3000 m), revealed that 12 IRs passed by the mooring in the 2-year monitoring period. With this independent information, we were able to assess and improve the release algorithm, still based on ocean conditions measured only at one depth. We found that much better performance could have been achieved with an algorithm that detected IRs based on a temperature difference from a long-term running mean rather than a fixed temperature threshold. This highlights the challenge of designing an appropriate release strategy with limited a priori information on the amplitude and time scales of the background variability.

  19. Enhanced exchange bias in MnN/CoFe bilayers after high-temperature annealing

    NASA Astrophysics Data System (ADS)

    Dunz, M.; Schmalhorst, J.; Meinert, M.

    2018-05-01

    We report an exchange bias of more than 2700 Oe at room temperature in MnN/CoFe bilayers after high-temperature annealing. We studied the dependence of exchange bias on the annealing temperature for different MnN thicknesses in detail and found that samples with tMnN > 32nm show an increase of exchange bias for annealing temperatures higher than TA = 400 °C. Maximum exchange bias values exceeding 2000 Oe with reasonably small coercive fields around 600 Oe are achieved for tMnN = 42, 48 nm. The median blocking temperature of those systems is determined to be 180 °C after initial annealing at TA = 525 °C. X-ray diffraction measurements and Auger depth profiling show that the large increase of exchange bias after high-temperature annealing is accompanied by strong nitrogen diffusion into the Ta buffer layer of the stacks.

  20. Annual soil CO_{2} production in Moscow Botanical Garden (Russia).

    NASA Astrophysics Data System (ADS)

    Udovenko, Maria; Goncharova, Olga; Matyshak, Georgy

    2017-04-01

    Soil respiration is an essential component of the carbon cycle, determining 25-40 % of carbon dioxide in the atmosphere. Urban soils are subject to significant anthropogenic influences. Anthropogenic impact affects both the plants and the soil microbiota. So, soil CO2 efflux and soil profile CO2 concentration probably differ in urban and natural soils. Influence of abiotic factors on soil carbon dioxide production is explored insufficiently. The research of their impact on soil carbon dioxide production is necessary to predict soil response to anthropogenic climate change. The aim of this study was estimation of annual soil CO2 production and the impact of climatic factors on it. The research took place in Moscow State University Botanical Garden Arboretum (southern taiga). Investigations were carried out at two sites: the areas planted with Picea obovata and Carpinus betulus. The study was conducted with 1-2 weeks intervals between November 2014 and December 2015. Emission measurement were carried out by closed chamber technique, profile concentration were measured by soil air sampling tubes method. Annual carbon dioxide soil surface efflux of soil planted with Picea obovata was 1370 gCO2/(m2 * year), soil planted with Carpinus betulus - 1590 gCO2/(m2 * year). Soil CO2 concentration increased with depth in average of 3300 to 12000 ppm (at 80 cm depth). Maximum concentration values are confined to the end of vegetation period (high biological activity) and to beginning of spring (spring ice cover of soil prevents CO2 emission). Soil CO2 efflux depends on soil temperature at 10 cm depth (R = 0.89; p <0.05), in a less degree it correlate with soil surface temperature and with soil temperature at 20 cm depth (r=0.88; p<0.05). Soil moisture has a little effect on CO2 efflux in the annual cycle (r=-0.16; p<0.05). However in vegetation period efflux of carbon dioxide largely depends on soil moisture, due to the fact, that soil moisture is limiting factor for soil microbiota activity and plant respiration.

  1. Estimation of hydraulic conductivity in an alluvial system using temperatures.

    PubMed

    Su, Grace W; Jasperse, James; Seymour, Donald; Constantz, Jim

    2004-01-01

    Well water temperatures are often collected simultaneously with water levels; however, temperature data are generally considered only as a water quality parameter and are not utilized as an environmental tracer. In this paper, water levels and seasonal temperatures are used to estimate hydraulic conductivities in a stream-aquifer system. To demonstrate this method, temperatures and water levels are analyzed from six observation wells along an example study site, the Russian River in Sonoma County, California. The range in seasonal ground water temperatures in these wells varied from <0.2 degrees C in two wells to approximately 8 degrees C in the other four wells from June to October 2000. The temperature probes in the six wells are located at depths between 3.5 and 7.1 m relative to the river channel. Hydraulic conductivities are estimated by matching simulated ground water temperatures to the observed ground water temperatures. An anisotropy of 5 (horizontal to vertical hydraulic conductivity) generally gives the best fit to the observed temperatures. Estimated conductivities vary over an order of magnitude in the six locations analyzed. In some locations, a change in the observed temperature profile occurred during the study, most likely due to deposition of fine-grained sediment and organic matter plugging the streambed. A reasonable fit to this change in the temperature profile is obtained by decreasing the hydraulic conductivity in the simulations. This study demonstrates that seasonal ground water temperatures monitored in observation wells provide an effective means of estimating hydraulic conductivities in alluvial aquifers.

  2. Estimation of hydraulic conductivity in an alluvial system using temperatures

    USGS Publications Warehouse

    Su, G.W.; Jasperse, James; Seymour, D.; Constantz, J.

    2004-01-01

    Well water temperatures are often collected simultaneously with water levels; however, temperature data are generally considered only as a water quality parameter and are not utilized as an environmental tracer. In this paper, water levels and seasonal temperatures are used to estimate hydraulic conductivities in a stream-aquifer system. To demonstrate this method, temperatures and water levels are analyzed from six observation wells along an example study site, the Russian River in Sonoma County, California. The range in seasonal ground water temperatures in these wells varied from < 0.2??C in two wells to ???8??C in the other four wells from June to October 2000. The temperature probes in the six wells are located at depths between 3.5 and 7.1 m relative to the river channel. Hydraulic conductivities are estimated by matching simulated ground water temperatures to the observed ground water temperatures. An anisotropy of 5 (horizontal to vertical hydraulic conductivity) generally gives the best fit to the observed temperatures. Estimated conductivities vary over an order of magnitude in the six locations analyzed. In some locations, a change in the observed temperature profile occurred during the study, most likely due to deposition of fine-grained sediment and organic matter plugging the streambed. A reasonable fit to this change in the temperature profile is obtained by decreasing the hydraulic conductivity in the simulations. This study demonstrates that seasonal ground water temperatures monitored in observation wells provide an effective means of estimating hydraulic conductivities in alluvial aquifers.

  3. Modeling carbon cycle process of soil profile in Loess Plateau of China

    NASA Astrophysics Data System (ADS)

    Yu, Y.; Finke, P.; Guo, Z.; Wu, H.

    2011-12-01

    SoilGen2 is a process-based model, which could reconstruct soil formation under various climate conditions, parent materials, vegetation types, slopes, expositions and time scales. Both organic and inorganic carbon cycle processes could be simulated, while the later process is important in carbon cycle of arid and semi-arid regions but seldom being studied. After calibrating parameters of dust deposition rate and segments depth affecting elements transportation and deposition in the profile, modeling results after 10000 years were confronted with measurements of two soil profiles in loess plateau of China, The simulated trends of organic carbon and CaCO3 in the profile are similar to measured values. Relative sensitivity analysis for carbon cycle process have been done and the results show that the change of organic carbon in long time scale is more sensitive to precipitation, temperature, plant carbon input and decomposition parameters (decomposition rate of humus, ratio of CO2/(BIO+HUM), etc.) in the model. As for the inorganic carbon cycle, precipitation and potential evaporation are important for simulation quality, while the leaching and deposition of CaCO3 are not sensitive to pCO2 and temperature of atmosphere.

  4. Specifics of soil temperature under winter oilseed rape canopy

    NASA Astrophysics Data System (ADS)

    Krčmářová, Jana; Středa, Tomáš; Pokorný, Radovan

    2014-09-01

    The aim of this study was to evaluate the course of soil temperature under the winter oilseed rape canopy and to determine relationships between soil temperature, air temperature and partly soil moisture. In addition, the aim was to describe the dependence by means of regression equations usable for pests and pathogens prediction, crop development, and yields models. The measurement of soil and near the ground air temperatures was performed at the experimental field Žabiče (South Moravia, the Czech Republic). The course of temperature was determined under or in the winter oilseed rape canopy during spring growth season in the course of four years (2010 - 2012 and 2014). In all years, the standard varieties (Petrol, Sherpa) were grown, in 2014 the semi-dwarf variety PX104 was added. Automatic soil sensors were positioned at three depths (0.05, 0.10 and 0.20 m) under soil surface, air temperature sensors in 0.05 m above soil surfaces. The course of soil temperature differs significantly between standard (Sherpa and Petrol) and semi-dwarf (PX104) varieties. Results of the cross correlation analysis showed, that the best interrelationships between air and soil temperature were achieved in 2 hours delay for the soil temperature in 0.05 m, 4 hour delay for 0.10 m and 7 hour delay for 0.20 m for standard varieties. For semi-dwarf variety, this delay reached 6 hour for the soil temperature in 0.05 m, 7 hour delay for 0.10 m and 11 hour for 0.20 m. After the time correction, the determination coefficient (R2) reached values from 0.67 to 0.95 for 0.05 m, 0.50 to 0.84 for 0.10 m in variety Sherpa during all experimental years. For variety PX104 this coefficient reached values from 0.51 to 0.72 in 0.05 m depth and from 0.39 to 0.67 in 0.10 m depth in the year 2014. The determination coefficient in the 0.20 m depth was lower for both varieties; its values were from 0.15 to 0.65 in variety Sherpa. In variety PX104 the values of R2 from 0.23 to 0.57 were determined. When using multiple regressions with quadratic spacing (modelling of hourly soil temperature based on the hourly near surface air temperature and hourly soil moisture in the 0.10-0.40 m profile), the difference between the measured and modelled soil temperatures in the depth of 0.05 m was -3.92 to 3.99°C. The regression equation paired with alternative agrometeorological instruments enables relatively accurate modelling of soil temperatures (R2 = 0.95).

  5. The effect of sediment thermal conductivity on vertical groundwater flux estimates

    NASA Astrophysics Data System (ADS)

    Sebok, Eva; Müller, Sascha; Engesgaard, Peter; Duque, Carlos

    2015-04-01

    The interaction between groundwater and surface water is of great importance both from ecological and water management perspective. The exchange fluxes are often estimated based on vertical temperature profiles taken from shallow sediments assuming a homogeneous standard value of sediment thermal conductivity. Here we report on a field investigation in a stream and in a fjord, where vertical profiles of sediment thermal conductivity and temperatures were measured in order to, (i) define the vertical variability in sediment thermal conductivity, (ii) quantify the effect of heterogeneity in sediment thermal conductivity on the estimated vertical groundwater fluxes. The study was carried out at field sites located in Ringkøbing fjord and Holtum stream in Western Denmark. Both locations have soft, sandy sediments with an upper organic layer at the fjord site. First 9 and 12 vertical sediment temperature profiles up to 0.5 m depth below the sediment bed were collected in the fjord and in the stream, respectively. Later sediment cores of 0.05 m diameter were removed at the location of the temperature profiles. Sediment thermal conductivity was measured in the sediment cores at 0.1 m intervals with a Decagon KD2 Pro device. A 1D flow and heat transport model (HydroGeoSphere) was set up and vertical groundwater fluxes were estimated based on the measured vertical sediment temperature profiles by coupling the model with PEST. To determine the effect of heterogeneity in sediment thermal conductivity on estimated vertical groundwater fluxes, the model was run by assigning (i) a homogeneous thermal conductivity for all sediment layers, calculated as the average sediment thermal conductivity of the profile, (ii) measured sediment thermal conductivities to the different model layers. The field survey showed that sediment thermal conductivity over a 0.5 m profile below the sediment bed is not uniform, having the largest variability in the fjord where organic sediments were also present. Using the measured sediment thermal conductivity for the different model layers instead of a homogeneous distribution did not result in a better fit between observed and simulated sediment temperature profiles. The estimated groundwater fluxes however were greatly affected by using the measured thermal conductivities resulting in changes of ± 45% in estimated vertical fluxes.

  6. Stacked Corrugated Horn Rings

    NASA Technical Reports Server (NTRS)

    Sosnowski, John B.

    2010-01-01

    This Brief describes a method of machining and assembly when the depth of corrugations far exceeds the width and conventional machining is not practical. The horn is divided into easily machined, individual rings with shoulders to control the depth. In this specific instance, each of the corrugations is identical in profile, and only differs in diameter and outer profile. The horn is segmented into rings that are cut with an interference fit (zero clearance with all machining errors biased toward contact). The interference faces can be cut with a reverse taper to increase the holding strength of the joint. The taper is a compromise between the interference fit and the clearance of the two faces during assembly. Each internal ring is dipped in liquid nitrogen, then nested in the previous, larger ring. The ring is rotated in the nest until the temperature of the two parts equalizes and the pieces lock together. The resulting assay is stable, strong, and has an internal finish that cannot be achieved through other methods.

  7. Heat-induced redistribution of surface oxide in uranium

    NASA Astrophysics Data System (ADS)

    Swissa, Eli; Shamir, Noah; Mintz, Moshe H.; Bloch, Joseph

    1990-09-01

    The redistribution of oxygen and uranium metal at the vicinity of the metal-oxide interface of native and grown oxides due to vacuum thermal annealing was studied for uranium and uranium-chromium alloy using Auger depth profiling and metallographic techniques. It was found that uranium metal is segregating out through the uranium oxide layer for annealing temperatures above 450°C. At the same time the oxide is redistributed in the metal below the oxide-metal interface in a diffusion like process. By applying a diffusion equation of a finite source, the diffusion coefficients for the process were obtained from the oxygen depth profiles measured for different annealing times. An Arrhenius like behavior was found for the diffusion coefficient between 400 and 800°C. The activation energy obtained was Ea = 15.4 ± 1.9 kcal/mole and the pre-exponential factor, D0 = 1.1 × 10 -8cm2/ s. An internal oxidation mechanism is proposed to explain the results.

  8. Vertical profiles of Fukushima Dai-ichi NPP-derived radiocesium concentrations in the waters of the southwestern Okhotsk Sea (2011-2017).

    PubMed

    Inoue, Mutsuo; Morokado, Toshiki; Fujimoto, Ken; Miki, Shizuho; Kofuji, Hisaki; Isoda, Yutaka; Nagao, Seiya

    2018-04-30

    We examined the vertical 134 Cs and 137 Cs concentration profiles in the southwestern Okhotsk Sea in 2011, 2013, and 2017. In June 2011, atmospheric deposition-derived 134 Cs from the Fukushima Dai-ichi Nuclear Power Plant (FDNPP) was detected at depths of 0-200 m (0.06-0.6 mBq/L). In July 2013, 134 Cs detected at depths of 100-200 m (∼0.05 mBq/L) was ascribed to the transport of low-level 134 Cs-contaminated water and/or the convection of radioactive depositions (<0.03 mBq/L at depths of 0-50 m). In July 2017, 134 Cs was detected in water samples at depths above 300 m (0.03-0.05 mBq/L), and the inventory, decay-corrected to the FDNPP accident date, exhibited its maximum value (85 Bq/m 2 ) during this period. Combining temperature-salinity data with the concentrations of global fallout-derived 137 Cs led to a plausible explanation for this observation, which is a consequence of re-entry of FDNPP-derived radiocesium through the Kuril Strait from the northwestern North Pacific Ocean to the Okhotsk Sea and subsequent mixing with the south Okhotsk subsurface layer until 2017. Copyright © 2018 Elsevier Ltd. All rights reserved.

  9. Direct band gap measurement of Cu(In,Ga)(Se,S){sub 2} thin films using high-resolution reflection electron energy loss spectroscopy

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Heo, Sung; College of Information and Communication Engineering, Sungkyunkwan University, Cheoncheon-dong 300, Jangan-gu, Suwon 440-746; Lee, Hyung-Ik

    2015-06-29

    To investigate the band gap profile of Cu(In{sub 1−x},Ga{sub x})(Se{sub 1−y}S{sub y}){sub 2} of various compositions, we measured the band gap profile directly as a function of in-depth using high-resolution reflection energy loss spectroscopy (HR-REELS), which was compared with the band gap profile calculated based on the auger depth profile. The band gap profile is a double-graded band gap as a function of in-depth. The calculated band gap obtained from the auger depth profile seems to be larger than that by HR-REELS. Calculated band gaps are to measure the average band gap of the spatially different varying compositions with respectmore » to considering its void fraction. But, the results obtained using HR-REELS are to be affected by the low band gap (i.e., out of void) rather than large one (i.e., near void). Our findings suggest an analytical method to directly determine the band gap profile as function of in-depth.« less

  10. AES study on the chemical composition of ferroelectric BaTiO3 thin films RF sputter-deposited on silicon

    NASA Technical Reports Server (NTRS)

    Dharmadhikari, V. S.; Grannemann, W. W.

    1983-01-01

    AES depth profiling data are presented for thin films of BaTiO3 deposited on silicon by RF sputtering. By profiling the sputtered BaTiO3/silicon structures, it was possible to study the chemical composition and the interface characteristics of thin films deposited on silicon at different substrate temperatures. All the films showed that external surface layers were present, up to a few tens of angstroms thick, the chemical composition of which differed from that of the main layer. The main layer had stable composition, whereas the intermediate film-substrate interface consisted of reduced TiO(2-x) oxides. The thickness of this intermediate layer was a function of substrate temperature. All the films showed an excess of barium at the interface. These results are important in the context of ferroelectric phenomena observed in BaTiO3 thin films.

  11. Compositional depth profiles of the type 316 stainless steel undergone the corrosion in liquid lithium using laser-induced breakdown spectroscopy

    NASA Astrophysics Data System (ADS)

    Li, Ying; Ke, Chuan; Liu, Xiang; Gou, Fujun; Duan, Xuru; Zhao, Yong

    2017-12-01

    Liquid metal lithium cause severe corrosion on the surface of metal structure material that used in the blanket and first wall of fusion device. Fast and accurate compositional depth profile measurement for the boundary layer of the corroded specimen will reveal the clues for the understanding and evaluation of the liquid lithium corrosion process as well as the involved corrosion mechanism. In this work, the feasibility of laser-induced breakdown spectroscopy for the compositional depth profile analysis of type 316 stainless steel which was corroded by liquid lithium in certain conditions was demonstrated. High sensitivity of LIBS was revealed especially for the corrosion medium Li in addition to the matrix elements of Fe, Cr, Ni and Mn by the spectral analysis of the plasma emission. Compositional depth profile analysis for the concerned elements which related to corrosion was carried out on the surface of the corroded specimen. Based on the verified local thermodynamic equilibrium shot-by-shot along the depth profile, the matrix effect was evaluated as negligible by the extracted physical parameter of the plasmas generated by each laser pulse in the longitudinal depth profile. In addition, the emission line intensity ratios were introduced to further reduce the impact on the emission line intensity variations arise from the strong inhomogeneities on the corroded surface. Compositional depth profiles for the matrix elements of Fe, Cr, Ni, Mn and the corrosion medium Li were constructed with their measured relative emission line intensities. The distribution and correlations of the concerned elements in depth profile may indicate the clues to the complicated process of composition diffusion and mass transfer. The results obtained demonstrate the potentiality of LIBS as an effective technique to perform spectrochemical measurement in the research fields of liquid metal lithium corrosion.

  12. DOE Office of Scientific and Technical Information (OSTI.GOV)

    Su, Grace W.; Jasperse, James; Seymour, Donald

    Well water temperatures are often collected simultaneously with water levels; however, temperature data are generally considered only as a water quality parameter and are not utilized as an environmental tracer. In this paper, water levels and seasonal temperatures are used to estimate hydraulic conductivities in a stream-aquifer system. To demonstrate this method, temperatures and water levels are analyzed from six observation wells along an example study site, the Russian River in Sonoma County, California. The range in seasonal ground water temperatures in these wells varied from <0.28C in two wells to {approx}88C in the other four wells from June tomore » October 2000. The temperature probes in the six wells are located at depths between 3.5 and 7.1 m relative to the river channel. Hydraulic conductivities are estimated by matching simulated ground water temperatures to the observed ground water temperatures. An anisotropy of 5 (horizontal to vertical hydraulic conductivity) generally gives the best fit to the observed temperatures. Estimated conductivities vary over an order of magnitude in the six locations analyzed. In some locations, a change in the observed temperature profile occurred during the study, most likely due to deposition of fine-grained sediment and organic matter plugging the streambed. A reasonable fit to this change in the temperature profile is obtained by decreasing the hydraulic conductivity in the simulations. This study demonstrates that seasonal ground water temperatures monitored in observation wells provide an effective means of estimating hydraulic conductivities in alluvial aquifers.« less

  13. Electrical conductivity structure of the mantle derived from inversion of geomagnetic observatory data: implications for lateral variations in temperature, composition and water content.

    NASA Astrophysics Data System (ADS)

    Munch, Federico; Grayver, Alexander; Khan, Amir; Kuvshinov, Alexey

    2017-04-01

    As most of Earth's interior remains geochemically unsampled, geophysical techniques based on seismology, geodesy, gravimetry, and electromagnetic studies play prominent roles because of their ability to sense structure at depth. Although seismic tomography maps show a variety of structures, separating thermal and compositional contributions from seismic velocities alone still remains a challenging task. Alternatively, as electrical conductivity is sensitive to temperature, chemical composition, oxygen fugacity, water content, and the presence of melt, it can serve for determining chemistry, mineralogy, and physical structure of the deep mantle. In this work we estimate and invert local C-responses (period range 3-100 days) for a number of worldwide geomagnetic observatories to map lateral variations of electrical conductivity in Earth's mantle (400-1600 km depth). The obtained conductivity profiles are interpreted in terms of basalt fraction in a basalt-harzburgite mixture, temperature structure, and water content variations. Interpretation is based on a self-consistent thermodynamic calculation of mineral phase equilibria, electrical conductivity databases, and probabilistic inverse methods.

  14. Characterization of a new commercial single crystal diamond detector for photon- and proton-beam dosimetry.

    PubMed

    Akino, Yuichi; Gautam, Archana; Coutinho, Len; Würfel, Jan; Das, Indra J

    2015-11-01

    A synthetic single crystal diamond detector (SCDD) is commercially available and is characterized for radiation dosimetry in various radiation beams in this study. The characteristics of the commercial SCDD model 60019 (PTW) with 6- and 15-MV photon beams, and 208-MeV proton beams, were investigated and compared with the pre-characterized detectors: Semiflex (model 31010) and PinPoint (model 31006) ionization chambers (PTW), the EDGE diode detector (Sun Nuclear Corp) and the SFD Stereotactic Dosimetry Diode Detector (IBA). To evaluate the effects of the pre-irradiation, the diamond detector, which had not been irradiated on the day, was set up in the water tank, and the response to 100 MU was measured every 20 s. The depth-dose and profiles data were collected for various field sizes and depths. For all radiation types and field sizes, the depth-dose data of the diamond chamber showed identical curves to those of the ionization chambers. The profile of the diamond detector was very similar to those of the EDGE and SFD detectors, although the Semiflex and PinPoint chambers showed volume-averaging effects in the penumbrae region. The temperature dependency was within 0.7% in the range of 4-41°C. A dose of 900 cGy and 1200 cGy was needed to stabilize the chamber to the level within 0.5% and 0.2%, respectively. The PTW type 60019 SCDD detector showed suitable characteristics for radiation dosimetry, for relative dose, depth-dose and profile measurements for a wide range of field sizes. However, at least 1000 cGy of pre-irradiation will be needed for accurate measurements. © The Author 2015. Published by Oxford University Press on behalf of The Japan Radiation Research Society and Japanese Society for Radiation Oncology.

  15. Laser microprobe and resonant laser ablation for depth profile measurements of hydrogen isotope atoms contained in graphite.

    PubMed

    Yorozu, M; Yanagida, T; Nakajyo, T; Okada, Y; Endo, A

    2001-04-20

    We measured the depth profile of hydrogen atoms in graphite by laser microprobing combined with resonant laser ablation. Deuterium-implanted graphite was employed for the measurements. The sample was ablated by a tunable laser with a wavelength corresponding to the resonant wavelength of 1S-2S of deuterium with two-photon excitation. The ablated deuterium was ionized by a 2 + 1 resonant ionization process. The ions were analyzed by a time-of-flight mass spectrometer. The deuterium ions were detected clearly with the resonant ablation. The detection limit was estimated to be less than 10(16) atoms/cm(3) in our experiments. We determined the depth profile by considering the etching profile and the etching rate. The depth profile agreed well with Monte Carlo simulations to within a precision of 23 mum for the center position and 4-mum precision for distributions for three different implantation depths.

  16. Positron annihilation spectroscopy for the determination of thickness and defect profile in thin semiconductor layers

    NASA Astrophysics Data System (ADS)

    Zubiaga, A.; García, J. A.; Plazaola, F.; Tuomisto, F.; Zúñiga-Pérez, J.; Muñoz-Sanjosé, V.

    2007-05-01

    We present a method, based on positron annihilation spectroscopy, to obtain information on the defect depth profile of layers grown over high-quality substrates. We have applied the method to the case of ZnO layers grown on sapphire, but the method can be very easily generalized to other heterostructures (homostructures) where the positron mean diffusion length is small enough. Applying the method to the ratio of W and S parameters obtained from Doppler broadening measurements, W/S plots, it is possible to determine the thickness of the layer and the defect profile in the layer, when mainly one defect trapping positron is contributing to positron trapping at the measurement temperature. Indeed, the quality of such characterization is very important for potential technological applications of the layer.

  17. Effects of groundwater withdrawal on borehole flow and salinity measured in deep monitor wells in Hawai'i-implications for groundwater management

    USGS Publications Warehouse

    Rotzoll, Kolja

    2010-01-01

    Water-resource managers in Hawai`i rely heavily on salinity profiles from deep monitor wells to estimate the thickness of freshwater and the depth to the midpoint of the transition zone between freshwater and saltwater in freshwater-lens systems. The deep monitor wells are typically open boreholes below the water table and extend hundreds of feet below sea level. Because of possible borehole-flow effects, there is concern that salinity profiles measured in these wells may not accurately reflect the salinity distribution in the aquifer and consequently lead to misinterpretations that adversely affect water-resource management. Steplike changes in salinity or temperature with depth in measured profiles from nonpumped deep monitor wells may be indicative of water moving within the well, and such changes are evident to some extent in all available profiles. The maximum vertical step length, or displacement, in measured profiles ranges from 7 to 644 feet. Vertical steps longer than 70 feet exceed the typical thickness of massive lava flows; they therefore cannot be attributed entirely to geologic structure and may be indicative of borehole flow. The longest vertical steps occur in monitor wells located in southern O'ahu, coinciding with the most heavily developed part of the aquifer. Although regional groundwater withdrawals have caused a thinning of the freshwater lens over the past several decades, the measured midpoint of the transition zone in most deep monitor wells has shown only inconsequential depth displacement in direct response to short-term variations in withdrawals from nearby production wells. For profiles from some deep monitor wells, however, the depth of the measured top of the transition zone, indicated by a specific-conductance value of 1,000 microsiemens per centimeter, has risen several hundred feet in response to withdrawals from nearby production wells. For these deep monitor wells, monitoring the apparent top of the transition zone may not provide an accurate indication of water quality in the adjacent aquifer. Hence, the measured midpoint in boreholes is a better proxy for freshwater-lens thickness. Brackish water transported upward in a deep monitor well can exit the borehole in the upper, freshwater part of the aquifer and affect the water quality in nearby production wells. Piezometers installed at different depths will provide the best information on aquifer salinity because they are unaffected by borehole flow. Despite the effects of borehole flow, monitoring the midpoint in deep monitor wells is still useful to identify long-term trends in the movement of the transition zone.

  18. Seasonal surface circulation, temperature, and salinity in Prince William Sound, Alaska

    NASA Astrophysics Data System (ADS)

    Musgrave, David L.; Halverson, Mark J.; Scott Pegau, W.

    2013-02-01

    Salinity, temperature, and depth profiles from 1973 to 2010 were used to construct a seasonal climatology of surface temperature, surface salinity, mixed layer depth (MLD), potential energy of mixing, and surface geostrophic circulation in Prince William Sound (PWS) and the adjacent Gulf of Alaska. Surface salinity is greatest in winter and least in summer due to the influence of increased freshwater runoff in summer. It is generally lowest in the northwest and highest in the Gulf of Alaska. The surface temperature is lowest in the winter and highest in the summer when surface heating is greatest, with little spatial variability across the Sound. The MLD is deepest in winter (9-27 m) and shallowest in summer (4-5 m). The work by winds was estimated from meteorological buoy data in central PWS and compared to the potential energy of mixing of the upper water column. The potential depth to which winds mix the upper water column was generally consistent with the MLD. The surface geostrophic circulation in the central Sound has: a southerly flow in the western central Sound in the winter; a closed, weak anticyclonic cell in spring; a closed, cyclonic cell in the summer; an open, cyclonic circulation in the fall. In the western passages, a southerly flow occurs in spring, summer, and fall. These results have important implications for oil spill response in PWS, the use of oil dispersants, and for comparison to numerical studies.

  19. Evaluating lake stratification and temporal trends by using near-continuous water-quality data from automated profiling systems for water years 2005-09, Lake Mead, Arizona and Nevada

    USGS Publications Warehouse

    Veley, Ronald J.; Moran, Michael J.

    2012-01-01

    The U.S. Geological Survey, in cooperation with the National Park Service and Southern Nevada Water Authority, collected near-continuous depth-dependent water-quality data at Lake Mead, Arizona and Nevada, as part of a multi-agency monitoring network maintained to provide resource managers with basic data and to gain a better understanding of the hydrodynamics of the lake. Water-quality data-collection stations on Lake Mead were located in shallow water (less than 20 meters) at Las Vegas Bay (Site 3) and Overton Arm, and in deep water (greater than 20 meters) near Sentinel Island and at Virgin and Temple Basins. At each station, near-continual depth-dependent water-quality data were collected from October 2004 through September 2009. The data were collected by using automatic profiling systems equipped with multiparameter water-quality sondes. The sondes had sensors for temperature, specific conductance, dissolved oxygen, pH, turbidity, and depth. Data were collected every 6 hours at 2-meter depth intervals (for shallow-water stations) or 5-meter depth intervals (for deep-water stations) beginning at 1 meter below water surface. Data were analyzed to determine water-quality conditions related to stratification of the lake and temporal trends in water-quality parameters. Three water-quality parameters were the main focus of these analyses: temperature, specific conductance, and dissolved oxygen. Statistical temporal-trend analyses were performed for a single depth at shallow-water stations [Las Vegas Bay (Site 3) and Overton Arm] and for thermally-stratified lake layers at deep-water stations (Sentinel Island and Virgin Basin). The limited period of data collection at the Temple Basin station prevented the application of statistical trend analysis. During the summer months, thermal stratification was not observed at shallow-water stations, nor were major maxima or minima observed for specific-conductance or dissolved-oxygen profiles. A clearly-defined thermocline and well-defined maxima and minima in specific-conductance and dissolved-oxygen profiles were observed at deep-water stations during the summer months. Specific-conductance maxima were likely the result of inflow of water from either the Las Vegas Wash or Muddy/Virgin Rivers or both, while the minima were likely the result of inflow of water from the Colorado River. Maxima and minima for dissolved oxygen were likely the result of primary productivity blooms and their subsequent decay. Temporal-trend analyses indicated that specific conductance decreased at all stations over the period of record, except for Las Vegas Bay (Site 3), where specific conductance increased. Temperature also decreased over the period of record at deep-water stations for certain lake layers. Decreasing temperature and specific conductance at deep-water stations is the result of decreasing values in these parameters in water coming from the Colorado River. Quagga mussels (Dreissena rostriformis bugensis), however, could play a role in trends of decreasing specific conductance through incorporation of calcite in their shells. Trends of decreasing turbidity and pH at deep-water stations support the hypothesis that quagga mussels could be having an effect on the physical properties and water chemistry of Lake Mead. Unlike other stations, Las Vegas Bay (Site 3) had increasing specific conductance and is interpreted as the result of lowering lake levels decreasing the volume of lake water available for mixing and dilution of the high-conductance water coming from Las Vegas Wash. Dissolved oxygen increased over the period of record in some lake layers at the deep-water stations. Increasing dissolved oxygen at deep-water stations is believed to result, in part, from a reduction of phosphorus entering Lake Mead and the concomitant reduction of biological oxygen demand.

  20. Characteristics of early winter high Arctic atmospheric boundary layer profiles

    NASA Astrophysics Data System (ADS)

    Wickström, Siiri; Vihma, Timo; Nygård, Tiina; Kramer, Daniel; Palo, Timo; Jonassen, Marius

    2017-04-01

    For a large part of the year, the Arctic climate system is characterised by a stably stratified atmospheric boundary layer, with strong temperature inversions isolating the surface from the air aloft. These nversions are typically driven by longwave radiative cooling, warm-air advection aloft, or subsidence. All these mechanisms are affected by the synoptic sate of the atmosphere in the high Arctic. In this study we present data from an intensive measurement campaign in Svalbard in October 2014, when atmospheric profiles were measured with a tethered balloon in Adventdalen and Hornsund. In addition radiosonde soundings from Ny-Ålesund were analysed. A total of 115 individual profiles were analysed, almost all of them showing a surface-based temperature inversion. Our preliminary results show that the strongest and deepest inversions are observed at the beginning of a warm-air advection event, but as the temperature, wind and cloudiness increase the inversion strength and depth decrease rapidly. The inversion curvature parameter seems to be strongly dependent on the longwave radiative balance with the highest curvatures (strongest vertical temperature gradient close to the surface) associated with strong longwave radiative heat loss from the surface. The different processes affecting the stable atmospheric boundary layer during a low-pressure passage are determined, and the effects of the synoptic scale changes are isolated from those caused by local topographic forcing.

  1. Lake Energy Budget and Temperature Profiles Under Future Greenhouse Gas Scenarios

    NASA Astrophysics Data System (ADS)

    Lofgren, B. M.; Xiao, C.

    2017-12-01

    Future climates under higher concentrations of greenhouse gases are expected to feature higher air and water temperatures, and shifts in surface heat fluxes. We investigate in greater detail the evolution of this in terms of the annual cycle of lake temperature profiles, stratification, and ice formation. Other work has found that, although shallower water promotes more rapid changes in surface water temperature within a season, change in surface water temperature across decades is more prominent in locations with greater water depth. Our simulations using the Weather Research and Forecasting (WRF) model and its lake module, WRF-Lake, show a trend toward longer periods of summer stratification, both through earlier onset in the spring and later decay of stratification in the fall. They also show a general increase in temperature throughout the water column, but most pronounced near the surface during the summer. Likewise, ice duration is much shorter and more restricted to shallow embayments. High latent and sensible heat flux during the fall and winter are less intense but longer lasting under the future scenario. Sources of uncertainty are cumulative—actual future greenhouse gas concentrations, global sensitivity of climate change, cloud feedbacks, the combined formulation of the regional climate model (WRF) and its global driving model, and more.

  2. The whole-soil carbon flux in response to warming

    NASA Astrophysics Data System (ADS)

    Hicks Pries, Caitlin E.; Castanha, C.; Porras, R. C.; Torn, M. S.

    2017-03-01

    Soil organic carbon harbors three times as much carbon as Earth’s atmosphere, and its decomposition is a potentially large climate change feedback and major source of uncertainty in climate projections. The response of whole-soil profiles to warming has not been tested in situ. In a deep warming experiment in mineral soil, we found that CO2 production from all soil depths increased with 4°C warming; annual soil respiration increased by 34 to 37%. All depths responded to warming with similar temperature sensitivities, driven by decomposition of decadal-aged carbon. Whole-soil warming reveals a larger soil respiration response than many in situ experiments (most of which only warm the surface soil) and models.

  3. Assessing the magnitude and timing of anthropogenic warming of a shallow aquifer: example from Virginia Beach, USA

    USGS Publications Warehouse

    Eggleston, John R.; McCoy, Kurt J.

    2015-01-01

    Groundwater temperature measurements in a shallow coastal aquifer in Virginia Beach, Virginia, USA, suggest groundwater warming of +4.1 °C relative to deeper geothermal gradients. Observed warming is related to timing and depth of influence of two potential thermal drivers—atmospheric temperature increases and urbanization. Results indicate that up to 30 % of groundwater warming at the water table can be attributed to atmospheric warming while up to 70 % of warming can be attributed to urbanization. Groundwater temperature readings to 30-m depth correlate positively with percentage of impervious cover and negatively with percentage of tree canopy cover; thus, these two land-use metrics explain up to 70 % of warming at the water table. Analytical and numerical modeling results indicate that an average vertical groundwater temperature profile for the study area, constructed from repeat measurement at 11 locations over 15 months, is consistent with the timing of land-use change over the past century in Virginia Beach. The magnitude of human-induced warming at the water table (+4.1 °C) is twice the current seasonal temperature variation, indicating the potential for ecological impacts on wetlands and estuaries receiving groundwater discharge from shallow aquifers.

  4. Forward-looking infrared imaging predicts ultimate burn depth in a porcine vertical injury progression model.

    PubMed

    Miccio, Joseph; Parikh, Shruti; Marinaro, Xavier; Prasad, Atulya; McClain, Steven; Singer, Adam J; Clark, Richard A F

    2016-03-01

    Current methods of assessing burn depth are limited and are primarily based on visual assessments by burn surgeons. This technique has been shown to have only 60% accuracy and a more accurate, simple, noninvasive method is needed to determine burn wound depth. Forward-looking infrared (FLIR) thermography is both noninvasive and user-friendly with the potential to rapidly assess burn depth. The purpose of this paper is to determine if early changes in burn temperature (first 3 days) can be a predictor of burn depth as assessed by vertical scarring 28 days after injury. While under general anesthesia, 20 burns were created on the backs of two female Yorkshire swine using a 2.5cm×2.5cm×7.5cm, 150g aluminum bar, for a total of 40 burns. FLIR imaging was performed at both early (1, 2 and 3 days) and late (7, 10, 14, 17, 21, 24 and 28 days) time points. Burns were imaged from a height of 12 inches from the skin surface. FLIR ExaminIR(©) software was used to examine the infrared thermographs. One hundred temperature points from burn edge to edge across the center of the burn were collected for each burn at all time points and were exported as a comma-separated values (CSV) file. The CSV file was processed and analyzed using a MATLAB program. The temperature profiles through the center of the burns generated parabola-like curves. The lowest temperature (temperature minimum) and a line midway between the temperature minimum and ambient skin temperature at the burn edges was defined and the area of the curve calculated (the "temperature half-area"). Half-area values 2 days after burn had higher correlations with scar depth than did the minimum temperatures. However, burns that became warmer from 1 day to 2 days after injury had a lower scar depth then burns that became cooler and this trend was best predicted by temperature minima. When data were analyzed as a diagnostic test for sensitivity and specificity using >3mm scarring, i.e. a full-thickness burn, as a clinically relevant criterion standard, temperature minima at 2 days after burn was found to be the most sensitive and specific test. FLIR imaging is a fast and simple tool that has been shown to predict burn wound outcome in a porcine vertical injury progression model. Data showed that more severe burn wounds get cooler between 1 and 2 days after burn. We found four analytic methods of FLIR images that were predictive of burn progression at 1 and 2 days after burn; however, temperature minima 2 days after burn appeared to be the best predictive test for injury progression to a full-thickness burn. Although these results must be validated in clinical studies, FLIR imaging has the potential to aid clinicians in assessing burn severity and thereby assisting in burn wound management. Copyright © 2015 Elsevier Ltd and ISBI. All rights reserved.

  5. Microstructure evolution of the Ir-inserted Ni silicides with additional annealing

    NASA Astrophysics Data System (ADS)

    Yoon, Kijeong; Song, Ohsung

    2009-02-01

    Thermally-evaporated 10 nm-Ni/1 nm-Ir/(poly)Si structures were fabricated in order to investigate the thermal stability of Ir-inserted nickel silicide after additional annealing. The silicide samples underwent rapid thermal annealing at 300 ° C to 1200 ° C for 40 s, followed by 30 min annealing at the given RTA temperatures. Silicides suitable for the salicide process were formed on the top of the single crystal and polycrystalline silicon substrates, mimicking actives and gates. The sheet resistance was measured using a four-point probe. High resolution x-ray diffraction and Auger depth profiling were used for phase and chemical composition analysis, respectively. Transmission electron microscope and scanning probe microscope were used to determine the cross-section structure and surface roughness. The silicide, which formed on single crystal silicon substrate with surface agglomeration after additional annealing, could defer the transformation of Ni(Ir)Si to Ni(Ir)Si2 and was stable at temperatures up to 1200 °C. Moreover, the silicide thickness doubled. There were no outstanding changes in the silicide thickness on polycrystalline silicon. However, after additional annealing, the silicon-silicide mixing became serious and showed high resistance at temperatures >700 °C. Auger depth profiling confirmed the increased thickness of the silicide layers after additional annealing without a change in composition. For a single crystal silicon substrate, the sheet resistance increased slightly due to the significant increases in surface roughness caused by surface agglomeration after additional annealing. Otherwise, there were almost no changes in surface roughness on the polycrystalline silicon substrate. The Ir-inserted nickel monosilicide was able to maintain a low resistance in a wide temperature range and is considered suitable for the nano-thick silicide process.

  6. A time-dependent radiative model of HD 209458b

    NASA Astrophysics Data System (ADS)

    Iro, N.; Bézard, B.; Guillot, T.

    2005-06-01

    We present a time-dependent radiative model of the atmosphere of HD 209458b and investigate its thermal structure and chemical composition. In a first step, the stellar heating profile and radiative timescales were calculated under planet-averaged insolation conditions. We find that 99.99% of the incoming stellar flux has been absorbed before reaching the 7 bar level. Stellar photons cannot therefore penetrate deeply enough to explain the large radius of the planet. We derive a radiative time constant which increases with depth and reaches about 8 h at 0.1 bar and 2.3 days at 1 bar. Time-dependent temperature profiles were also calculated, in the limit of a zonal wind that is independent of height (i.e. solid-body rotation) and constant absorption coefficients. We predict day-night variations of the effective temperature of ~600 K, for an equatorial rotation rate of 1 km s-1, in good agreement with the predictions by Showmann & Guillot (2002). This rotation rate yields day-to-night temperature variations in excess of 600 K above the 0.1-bar level. These variations rapidly decrease with depth below the 1-bar level and become negligible below the ~5-bar level for rotation rates of at least 0.5 km s-1. At high altitudes (mbar pressures or less), the night temperatures are low enough to allow sodium to condense into Na2S. Synthetic transit spectra of the visible Na doublet show a much weaker sodium absorption on the morning limb than on the evening limb. The calculated dimming of the sodium feature during planetary transites agrees with the value reported by Charbonneau et al. (2002).

  7. The Tropical Convective Spectrum. Part 1; Archetypal Vertical Structures

    NASA Technical Reports Server (NTRS)

    Boccippio, Dennis J.; Petersen, Walter A.; Cecil, Daniel J.

    2005-01-01

    A taxonomy of tropical convective and stratiform vertical structures is constructed through cluster analysis of 3 yr of Tropical Rainfall Measuring Mission (TRMM) "warm-season" (surface temperature greater than 10 C) precipitation radar (PR) vertical profiles, their surface rainfall, and associated radar-based classifiers (convective/ stratiform and brightband existence). Twenty-five archetypal profile types are identified, including nine convective types, eight stratiform types, two mixed types, and six anvil/fragment types (nonprecipitating anvils and sheared deep convective profiles). These profile types are then hierarchically clustered into 10 similar families, which can be further combined, providing an objective and physical reduction of the highly multivariate PR data space that retains vertical structure information. The taxonomy allows for description of any storm or local convective spectrum by the profile types or families. The analysis provides a quasi-independent corroboration of the TRMM 2A23 convective/ stratiform classification. The global frequency of occurrence and contribution to rainfall for the profile types are presented, demonstrating primary rainfall contribution by midlevel glaciated convection (27%) and similar depth decaying/stratiform stages (28%-31%). Profiles of these types exhibit similar 37- and 85-GHz passive microwave brightness temperatures but differ greatly in their frequency of occurrence and mean rain rates, underscoring the importance to passive microwave rain retrieval of convective/stratiform discrimination by other means, such as polarization or texture techniques, or incorporation of lightning observations. Close correspondence is found between deep convective profile frequency and annualized lightning production, and pixel-level lightning occurrence likelihood directly tracks the estimated mean ice water path within profile types.

  8. Electro-optical characterization of GaAs solar cells

    NASA Technical Reports Server (NTRS)

    Olsen, Larry C.; Dunham, Glen; Addis, F. W.; Huber, Dan; Daling, Dave

    1987-01-01

    The electro-optical characterization of gallium arsenide p/n solar cells is discussed. The objective is to identify and understand basic mechanisms which limit the performance of high efficiency gallium arsenide solar cells. The approach involves conducting photoresponse and temperature dependent current-voltage measurements, and interpretation of the data in terms of theory to determine key device parameters. Depth concentration profiles are also utilized in formulating a model to explain device performance.

  9. A possible width-luminosity correlation of the Ca II K1 and Mg II k1 features. [of stellar atmospheres

    NASA Technical Reports Server (NTRS)

    Ayres, T. R.; Shine, R. A.; Linsky, J. L.

    1975-01-01

    Existing high resolution stellar profiles of the Ca II and Mg II resonance lines suggest a possible width-luminosity correlation of the K1 minimum features. It is shown that such a correlation can be simply understood if the continuum optical depth of the stellar temperature minimum is relatively independent of surface gravity as suggested by three stars studied in detail.

  10. Discussion of "Evaluating vertical velocities between the stream and the hyporheic zone from temperature data" by Seydell, I., Wawra, B.E., and Zanke, U.C.E. [Chapter 5].

    Treesearch

    John M. Buffington; Daniele Tonina

    2008-01-01

    Hyporheic exchange is principally driven by spatial variations of near-bed pressure, which can be sensitive to seasonal changes in discharge, flow depth, and watersurface profile (Tonina and Buffington, 2003, 2007). Simulations of hyporheic exchange across two-dimensional pool-riffle topography show that the strength and spatial extent of the hyporheic exchange vary...

  11. Airborne Lidar Detection and Characterization of Internal Waves in a Shallow Fjord

    DTIC Science & Technology

    2012-01-01

    Graduate Center studying the statistics of optical propagation through refractive turbulence in the clear atmosphere . He then became a member of...instrumentation comprised a Seabird conductivity, temperature, depth (CTD) profiler with a Wetlabs AC-9 to measure the optical absorption and beam ...the depolarization of an initially polarized beam will be D, .=■ 2-d \\-d (10) where D is the ratio of the backscattering perpendicular to the

  12. Dynamic Vertical Profiles of Peat Porewater Chemistry in a Northern Peatland

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Griffiths, Natalie A.; Sebestyen, Stephen D.

    We measured pH, cations, nutrients, and total organic carbon (TOC) over 3 years to examine weekly to monthly variability in porewater chemistry depth profiles (0–3.0 m) in an ombrotrophic bog in Minnesota, USA. We also compared temporal variation at one location to spatial variation in depth profiles at 16 locations across the bog. Most solutes exhibited large gradients with depth. pH increased by two units and calcium concentrations increased over 20 fold with depth, and may reflect peatland development from minerotrophic to ombrotrophic conditions. Ammonium concentrations increased almost 20 fold and TOC concentrations decreased by half with depth, and thesemore » patterns likely reflect mineralization of peat or decomposition of TOC. There was also considerable temporal variation in the porewater chemistry depth profiles. Ammonium, soluble reactive phosphorus, and potassium showed greater temporal variation in near-surface porewater, while pH, calcium, and TOC varied more at depth. This variation demonstrates that deep peat porewater chemistry is not static. Lastly, temporal variation in solute chemistry depth profiles was greater than spatial variation in several instances, especially in shallow porewaters. In conclusion, characterizing both temporal and spatial variability is necessary to ensure representative sampling in peatlands, especially when calculating solute pools and fluxes and parameterizing process-based models.« less

  13. Dynamic Vertical Profiles of Peat Porewater Chemistry in a Northern Peatland

    DOE PAGES

    Griffiths, Natalie A.; Sebestyen, Stephen D.

    2016-10-14

    We measured pH, cations, nutrients, and total organic carbon (TOC) over 3 years to examine weekly to monthly variability in porewater chemistry depth profiles (0–3.0 m) in an ombrotrophic bog in Minnesota, USA. We also compared temporal variation at one location to spatial variation in depth profiles at 16 locations across the bog. Most solutes exhibited large gradients with depth. pH increased by two units and calcium concentrations increased over 20 fold with depth, and may reflect peatland development from minerotrophic to ombrotrophic conditions. Ammonium concentrations increased almost 20 fold and TOC concentrations decreased by half with depth, and thesemore » patterns likely reflect mineralization of peat or decomposition of TOC. There was also considerable temporal variation in the porewater chemistry depth profiles. Ammonium, soluble reactive phosphorus, and potassium showed greater temporal variation in near-surface porewater, while pH, calcium, and TOC varied more at depth. This variation demonstrates that deep peat porewater chemistry is not static. Lastly, temporal variation in solute chemistry depth profiles was greater than spatial variation in several instances, especially in shallow porewaters. In conclusion, characterizing both temporal and spatial variability is necessary to ensure representative sampling in peatlands, especially when calculating solute pools and fluxes and parameterizing process-based models.« less

  14. Oxygen fugacity profile of the oceanic upper mantle and the depth of redox melting beneath ridges

    NASA Astrophysics Data System (ADS)

    Davis, F. A.; Cottrell, E.

    2014-12-01

    Oxygen fugacity (fO2) of a mantle mineral assemblage, controlled primarily by Fe redox chemistry, sets the depth of the diamond to carbonated melt reaction (DCO3). Near-surface fO2 recorded by primitive MORB glasses and abyssal peridotites anchor the fO2 profile of the mantle at depth. If the fO2-depth relationship of the mantle is known, then the depth of the DCO3 can be predicted. Alternatively, if the DCO3 can be detected geophysically, then its depth can be used to infer physical and chemical characteristics of upwelling mantle. We present an expanded version of a model of the fO2-depth profile of adiabatically upwelling mantle first presented by Stagno et al. (2013), kindly provided by D. Frost. The model uses a chemical mass balance and empirical fits to experimental data to calculate compositions and modes of mantle minerals at specified P, T, and bulk Fe3+/ƩFe. We added P and T dependences to the partitioning of Al and Ca to better simulate the mineralogical changes in peridotite at depth and included majorite component in garnet to increase the depth range of the model. We calculate fO2 from the mineral assemblages using the grt-ol-opx oxybarometer (Stagno et al., 2013). The onset of carbonated melting occurs at the intersection of a Fe3+/ƩFe isopleth with the DCO3. Upwelling mantle is tied to the DCO3 until all native C is oxidized to form carbonated melts by reduction of Fe3+ to Fe2+. The depth of intersection of a parcel of mantle with the DCO3 is a function of bulk Fe3+/ƩFe, potential temperature, and bulk composition. We predict that fertile mantle (PUM) along a 1400 °C adiabat, with 50 ppm bulk C, and Fe3+/ƩFe = 0.05 after C oxidation begins redox melting at a depth of 250 km. The model contextualizes observations of MORB redox chemistry. Because fertile peridotite is richer in Al2O3, the Fe2O3-bearing components of garnet are diluted leading to lower fO2 at a given depth compared to refractory mantle under the same conditions. This may indicate that the negativecorrelation observed between enrichment and fO2 at ridges (Cottrell and Kelley, 2013) is a consequence of the increased fertility of remixing recycled crust into the mantle. Addition of reduced C to the mantle during subduction can also explain this observation. Geophysical detection of the depth of the DCO3 may resolve these hypotheses.

  15. Selected micrometeorological, soil-moisture, and evapotranspiration data at Amargosa Desert Research Site in Nye County near Beatty, Nevada, 2001-05

    USGS Publications Warehouse

    Johnson, Michael J.; Mayers, C. Justin; Garcia, C. Amanda; Andraski, Brian J.

    2007-01-01

    Selected micrometeorological and soil-moisture data were collected at the Amargosa Desert Research Site adjacent to a low-level radio-active waste and hazardous chemical waste facility near Beatty, Nevada, 2001-05. Evapotranspiration data were collected from February 2002 through the end of December 2005. Data were col-lected in support of ongoing research to improve the understanding of hydrologic and contaminant-transport processes in arid environments. Micrometeorological data include solar radiation, net radiation, air temperature, relative humidity, saturated and ambient vapor pressure, wind speed and direction, barometric pressure, precipitation, near-surface soil temperature, soil-heat flux and soil-water content. All micrometeorological data were collected using a 10-second sampling interval by data loggers that output daily and hourly mean values. Daily maximum and minimum values are based on hourly mean values. Precipitation data output includes daily and hourly totals. Selected soil-moisture profiles at depth include periodic measurements of soil volumetric water-content measurements at nine neutron-probe access tubes to depths ranging from 5.25 to 29.25 meters. Evapotranspiration data include measurement of daily evapotranspiration and 15-minute fluxes of the four principal energy budget components of latent-heat flux, sensible-heat flux, soil-heat flux, and net radiation. Other data collected and used in equations to determine evapotranspiration include temperature and water content of soil, temperature and vapor pressure of air, and covariance values. Evapotranspiration and flux estimates during 15-minute intervals were calculated at a 0.1-second execution interval using the eddy covariance method. Data files included in this report contain the complete micrometeorological, soil-moisture, and evapotranspiration field data sets. These data files are presented in tabular Excel spreadsheet format. This report highlights selected data contained in the computer generated data files using figures, tables, and brief discussions. Instrumentation used for data collection also is described. Water-content profiles are shown to demonstrate variability of water content with depth. Time-series data are plotted to illustrate temporal variations in micrometeorological, soil-water content, and evapotranspiration data.

  16. Spatial distribution of microbial biomass, activity, community structure, and the biodegradation of linear alkylbenzene sulfonate (LAS) and linear alcohol ethoxylate (LAE) in the subsurface.

    PubMed

    Federle, T W; Ventullo, R M; White, D C

    1990-12-01

    The vertical distribution of microbial biomass, activity, community structure and the mineralization of xenobiotic chemicals was examined in two soil profiles in northern Wisconsin. One profile was impacted by infiltrating wastewater from a laundromat, while the other served as a control. An unconfined aquifer was present 14 meters below the surface at both sites. Biomass and community structure were determined by acridine orange direct counts and measuring concentrations of phospholipid-derived fatty acids (PLFA). Microbial activity was estimated by measuring fluorescein diacetate (FDA) hydrolysis, thymidine incorporation into DNA, and mixed amino acid (MAA) mineralization. Mineralization kinetics of linear alkylbenzene sulfonate (LAS) and linear alcohol ethoxylate (LAE) were determined at each depth. Except for MAA mineralization rates, measures of microbial biomass and activity exhibited similar patterns with depth. PLFA concentration and rates of FDA hydrolysis and thymidine incorporation decreased 10-100 fold below 3 m and then exhibited little variation with depth. Fungal fatty acid markers were found at all depths and represented from 1 to 15% of the total PLFAs. The relative proportion of tuberculostearic acid (TBS), an actinomycete marker, declined with depth and was not detected in the saturated zone. The profile impacted by wastewater exhibited higher levels of PLFA but a lower proportion of TBS than the control profile. This profile also exhibited faster rates of FDA hydrolysis and amino acid mineralization at most depths. LAS was mineralized in the upper 2 m of the vadose zone and in the saturated zone of both profiles. Little or no LAS biodegradation occurred at depths between 2 and 14 m. LAE was mineralized at all depths in both profiles, and the mineralization rate exhibited a similar pattern with depth as biomass and activity measurements. In general, biomass and biodegradative activities were much lower in groundwater than in soil samples obtained from the same depth.

  17. Electromagnetic Surveying in the Mangrove Lakes Region of Everglades National Park

    NASA Astrophysics Data System (ADS)

    Whitman, D.; Price, R.; Frankovich, T.; Fourqurean, J.

    2015-12-01

    The Mangrove Lakes are an interconnected set of shallow (~ 1m), brackish lake and creek systems on the southern margin of the Everglades adjacent to Florida Bay. Current efforts associated with the Comprehensive Everglades Restoration Plan (CERP) aim to increase freshwater flow into this region. This study describes preliminary results of geophysical surveys in the lakes conducted to assess changes in the groundwater chemistry as part of a larger hydrologic and geochemical study in the Everglades Lakes region. Marine geophysical profiles were conducted in Alligator Creek (West Lake) and McCormick Creek systems in May, 2014. Data included marine electromagnetic (EM) profiles and soundings, water depth measurements, surface water conductivity and salinity measurements. A GSSI Profiler EMP-400 multi-frequency EM conductivity meter continuously recorded in-phase and quadrature field components at 1, 8, and 15 KHz. The system was deployed in a flat bottomed plastic kayak towed behind a motorized skiff. Lake water depths were continuously measured with a sounder/chart plotter which was calibrated with periodic sounding rod measurements. At periodic intervals during the survey, the profiling was stopped and surface water conductivity, temperature and salinity are recorded with a portable YSI probe on the tow boat. Over 40,000 discrete 3-frequency EM measurements were collected. The data were inverted to 2-layer models representing the water layer thickness and conductivity and the lake bottom conductivity. At spot locations, models were constrained with water depth soundings and surface water conductivity measurements. At other locations along the profiles, the water depth and conductivity were allowed to be free, but the free models were generally consistent with the constrained models. Multilayer sub-bottom models were also explored but were found to be poorly constrained. In West Lake, sub-bottom conductivities decreased from 400 mS/m in the west to 200 mS/m in the east indicating a general W to E decrease in groundwater salinity. In the McCormick Creek system, sub-bottom conductivities increased from 200 mS/m at the north end of Seven Palm Lake to over 650 mS/m at the southern end of Monroe Lake indicating a general N to S increase in ground water salinity. Additional profiles are planned in August, 2015.

  18. Hydrography and circulation of ice-marginal lakes at Bering Glacier, Alaska, U.S.A.

    USGS Publications Warehouse

    Josberger, E.G.; Shuchman, R.A.; Meadows, G.A.; Savage, S.; Payne, J.

    2006-01-01

    An extensive suite of physical oceanographic, remotely sensed, and water quality measurements, collected from 2001 through 2004 in two ice-marginal lakes at Bering Glacier, Alaska-Berg Lake and Vitus Lake-show that each has a unique circulation controlled by their specific physical forcing within the glacial system. Conductivity profiles from Berg Lake, perched 135 m a.s.l., show no salt in the lake, but the temperature profiles indicate an apparently unstable situation, the 4??C density maximum is located at 10 m depth, not at the bottom of the lake (90 m depth). Subglacial discharge from the Steller Glacier into the bottom of the lake must inject a suspended sediment load sufficient to marginally stabilize the water column throughout the lake. In Vitus Lake, terminus positions derived from satellite imagery show that the glacier terminus rapidly retreated from 1995 to the present resulting in a substantial expansion of the volume of Vitus Lake. Conductivity and temperature profiles from the tidally influenced Vitus Lake show a complex four-layer system with diluted (???50%) seawater in the bottom of the lake. This lake has a complex vertical structure that is the result of convection generated by ice melting in salt water, stratification within the lake, and freshwater entering the lake from beneath the glacier and surface runoff. Four consecutive years, from 2001 to 2004, of these observations in Vitus Lake show little change in the deep temperature and salinity conditions, indicating limited deep water renewal. The combination of the lake level measurements with discharge measurements, through a tidal cycle, by an acoustic Doppler Current Profiler (ADCP) deployed in the Seal River, which drains the entire Bering system, showed a strong tidal influence but no seawater entry into Vitus Lake. The ADCP measurements combined with lake level measurements established a relationship between lake level and discharge, which when integrated over a tidal cycle, gives a tidally averaged discharge ranging from 1310 to 1510 m3 s-1. ?? 2006 Regents of the University of Colorado.

  19. Neutron Depth Profiling: Overview and Description of NIST Facilities

    PubMed Central

    Downing, R. G.; Lamaze, G. P.; Langland, J. K.; Hwang, S. T.

    1993-01-01

    The Cold Neutron Depth Profiling (CNDP) instrument at the NIST Cold Neutron Research Facility (CNRF) is now operational. The neutron beam originates from a 16 L D2O ice cold source and passes through a filter of 135 mm of single crystal sapphire. The neutron energy spectrum may be described by a 65 K Maxwellian distribution. The sample chamber configuration allows for remote controlled scanning of 150 × 150 mm sample areas including the varying of both sample and detector angle. The improved sensitivity over the current thermal depth profiling instrument has permitted the first nondestructive measurements of 17O profiles. This paper describes the CNDP instrument, illustrates the neutron depth profiling (NDP) technique with examples, and gives a separate bibliography of NDP publications. PMID:28053461

  20. Does body type really matter? Relating climate change, coral morphology and resiliency

    NASA Astrophysics Data System (ADS)

    Camp, M.; Shein, K. A.; Foster, K.; Hendee, J. C.

    2016-02-01

    Average sea temperatures in many tropical regions are rising approximately 1-2˚C per century, and are thought to be a major driver of increased frequency of coral bleaching. However, certain coral morphologies appear to be more resilient to changes in the environment, particularly to sea temperature variations resulting from global climate change. Although branching corals (e.g., Acropora cervicornis, A. palmata) are highly susceptible to coral bleaching, this morphology is commonly used in coral restoration efforts because of its fast growth rate. Massive corals show higher resistance and resilience to elevated temperature events than branching species, but are less common in coral nurseries. The objective of this study was to compare coral resilience among morphology types in Little Cayman, a remote tropical island with <200 inhabitants where it is possible to decouple environmental and anthropogenic stressors. Three morphological groups (branching, intermediary and massive) were surveyed at 17 sites to estimate the percent cover of each group. Temperature profiles were observed at six moorings around the island, allowing for direct comparison between sea surface temperature, sea temperature at the reef depths, and coral cover, per morphology. The relationship between coral morphological coverage and temperature variation at depth was assessed in the context of geographic variation around the island. Understanding the relationship between coral morphology and resilience to temperature variability will enhance current coral restoration practices by identifying which morphologies have the highest chance of long-term survivorship following outplanting, concurrently optimizing cumulative reef survivorship.

  1. Correlation study of actual temperature profile and in-line metrology measurements for within-wafer uniformity improvement and wafer edge yield enhancement (Conference Presentation)

    NASA Astrophysics Data System (ADS)

    Fang, Fang; Vaid, Alok; Vinslava, Alina; Casselberry, Richard; Mishra, Shailendra; Dixit, Dhairya; Timoney, Padraig; Chu, Dinh; Porter, Candice; Song, Da; Ren, Zhou

    2018-03-01

    It is getting more important to monitor all aspects of influencing parameters in critical etch steps and utilize them as tuning knobs for within-wafer uniformity improvement and wafer edge yield enhancement. Meanwhile, we took a dive in pursuing "measuring what matters" and challenged ourselves for more aspects of signals acquired in actual process conditions. Among these factors which are considered subtle previously, we identified Temperature, especially electrostatic chuck (ESC) Temperature measurement in real etch process conditions have direct correlation to in-line measurements. In this work, we used SensArray technique (EtchTemp-SE wafer) to measure ESC temperature profile on a 300mm wafer with plasma turning on to reproduce actual temperature pattern on wafers in real production process conditions. In field applications, we observed substantial correlation between ESC temperature and in-line optical metrology measurements and since temperature is a process factor that can be tuning through set-temperature modulations, we have identified process knobs with known impact on physical profile variations. Furthermore, ESC temperature profile on a 300mm wafer is configured as multiple zones upon radius and SensArray measurements mechanism could catch such zonal distribution as well, which enables detailed temperature modulations targeting edge ring only where most of chips can be harvested and critical zone for yield enhancement. Last but not least, compared with control reference (ESC Temperature in static plasma-off status), we also get additional factors to investigate in chamber-to-chamber matching study and make process tool fleet match on the basis really matters in production. KLA-Tencor EtchTemp-SE wafer enables Plasma On wafer temperature monitoring of silicon etch process. This wafer is wireless and has 65 sensors with measurement range from 20 to 140°C. the wafer is designed to run in real production recipe plasma on condition with maximum RF power up to 7KW. The wafer surface is coated with Yttrium oxide film which allows Silicon Etch chemistry. At Fab-8, we carried investigations in 14 nm FEOL critical etch process which has direct impact on yield, using SensorArray EtchTemp-SE wafer, we measured ESC temperature profile across multiple chambers, for both plasma on and plasma off, promising results achieved on chamber temperature signature identification, guideline for chamber to chamber matching improvement. Correlation between wafer mean temperature and determining criticality-process parameters of recess depth and CD is observed. Furthermore, detail zonal temperature/profile correlation is investigated to identify individual correlation in each chuck zone, and provided unique process knobs corresponding to each chunk. Meanwhile, passive ESC Chuck DOE was done to modulate wafer temperature at different zones, and Sensor Array wafer measurements verified temperature responding well with the ESC set point. Correlation R2 = 0.9979 for outer ring and R2 = 0.9981 for Mid Outer ring is observed, as shown in . Experiments planning to modulate edge zone ESC temperature to tune profile within-wafer uniformity and prove gain in edge yield enhancement and to improve edge yield is underway.

  2. Groundwater noble gas, age, and temperature signatures in an Alpine watershed: Valuable tools in conceptual model development

    USGS Publications Warehouse

    Manning, Andrew H.; Caine, Jonathan S.

    2007-01-01

    Bedrock groundwater in alpine watersheds is poorly understood, mainly because of a scarcity of wells in alpine settings. Groundwater noble gas, age, and temperature data were collected from springs and wells with depths of 3–342 m in Handcart Gulch, an alpine watershed in Colorado. Temperature profiles indicate active groundwater circulation to a maximum depth (aquifer thickness) of about 200 m, or about 150 m below the water table. Dissolved noble gas data show unusually high excess air concentrations (>0.02 cm3 STP/g, ΔNe > 170%) in the bedrock, consistent with unusually large seasonal water table fluctuations (up to 50 m) observed in the upper part of the watershed. Apparent 3H/3He ages are positively correlated with sample depth and excess air concentrations. Integrated samples were collected from artesian bedrock wells near the trunk stream and are assumed to approximate flow‐weighted samples reflecting bedrock aquifer mean residence times. Exponential mean ages for these integrated samples are remarkably consistent along the stream, four of five being from 8 to 11 years. The tracer data in combination with other hydrologic and geologic data support a relatively simple conceptual model of groundwater flow in the watershed in which (1) permeability is primarily a function of depth; (2) water table fluctuations increase with distance from the stream; and (3) recharge, aquifer thickness, and porosity are relatively uniform throughout the watershed in spite of the geological complexity of the Proterozoic crystalline rocks that underlie it.

  3. Evidence for Depth-Dependent Metasomatism in Cratonic Lithosphere

    NASA Astrophysics Data System (ADS)

    Eeken, T.; Goes, S. D. B.; Pedersen, H.; Arndt, N. T.; Bouilhol, P.

    2017-12-01

    The long-term stability of the cratonic cores of continents has been attributed to low temperatures and depletion in iron and water. However, a long-standing enigma is that steady-state thermal models based on heat flow measurements and xenoliths systematically overpredict the seismic velocities in Archean lithospheric mantle. We perform a Monte-Carlo inversion for thermal parameters and water content (leading to metasomatism) to fit 1-D geotherms to average Rayleigh-wave dispersion curves for the Archean Kaapvaal, Yilgarn and Slave cratons and the Proterozoic Baltic Shield below Finland. To satisfactorily match the seismic profiles, we need a significant amount of hydrous and/or carbonated minerals starting between the Moho and 70 km depth and extending down to at least 100-150 km depth (if distributed over this depth range, this requires 0.5 and 1 wt% water for amphiboles, or 0.2 wt% water plus sufficient potassium to form phlogopites or 5 wt% CO2 and sufficient Ca to make carbonate, or a combination thereof). Lithospheric temperatures that lead to a good fit of the seismic constraints are commonly lower than those inferred from xenoliths, but consistent with heat flow constraints. The dispersion data also require differences in Moho heatflux between regions and 100-200°C lower sublithospheric mantle temperatures below Yilgarn, Slave and Finland than below Kaapvaal, consistent with regional tectonic settings inferred from global tomography. Thus, significant upward-increasing metasomatism by water and CO2-rich fluids is a plausible mechanism to explain the average seismic structure of cratonic lithosphere. Such metasomatism would also contribute to the positive chemical buoyancy of cratonic roots.

  4. Seismic evidence for depth-dependent metasomatism in cratons

    NASA Astrophysics Data System (ADS)

    Eeken, Thomas; Goes, Saskia; Pedersen, Helle A.; Arndt, Nicholas T.; Bouilhol, Pierre

    2018-06-01

    The long-term stability of cratons has been attributed to low temperatures and depletion in iron and water, which decrease density and increase viscosity. However, steady-state thermal models based on heat flow and xenolith constraints systematically overpredict the seismic velocity-depth gradients in cratonic lithospheric mantle. Here we invert for the 1-D thermal structure and a depth distribution of metasomatic minerals that fit average Rayleigh-wave dispersion curves for the Archean Kaapvaal, Yilgarn and Slave cratons and the Proterozoic Baltic Shield below Finland. To match the seismic profiles, we need a significant amount of hydrous and/or carbonate minerals in the shallow lithospheric mantle, starting between the Moho and 70 km depth and extending down to at least 100-150 km. The metasomatic component can consist of 0.5-1 wt% water bound in amphibole, antigorite and chlorite, ∼0.2 wt% water plus potassium to form phlogopite, or ∼5 wt% CO2 plus Ca for carbonate, or a combination of these. Lithospheric temperatures that fit the seismic data are consistent with heat flow constraints, but most are lower than those inferred from xenolith geothermobarometry. The dispersion data require differences in Moho heat flux between individual cratons, and sublithospheric mantle temperatures that are 100-200 °C less beneath Yilgarn, Slave and Finland than beneath Kaapvaal. Significant upward-increasing metasomatism by water and CO2-rich fluids is not only a plausible mechanism to explain the average seismic structure of cratonic lithosphere but such metasomatism may also lead to the formation of mid-lithospheric discontinuities and would contribute to the positive chemical buoyancy of cratonic roots.

  5. Means of determining extrusion temperatures

    DOEpatents

    McDonald, Robert E.; Canonico, Domenic A.

    1977-01-01

    In an extrusion process comprising the steps of fabricating a metal billet, heating said billet for a predetermined time and at a selected temperature to increase its plasticity and then forcing said heated billet through a small orifice to produce a desired extruded object, the improvement comprising the steps of randomly inserting a plurality of small metallic thermal tabs at different cross sectional depths in said billet as a part of said fabricating step, and examining said extruded object at each thermal tab location for determining the crystal structure at each extruded thermal tab thus revealing the maximum temperature reached during extrusion in each respective tab location section of the extruded object, whereby the thermal profile of said extruded object during extrusion may be determined.

  6. Semiempirical photospheric models of a solar flare on May 28, 2012

    NASA Astrophysics Data System (ADS)

    Andriets, E. S.; Kondrashova, N. N.

    2015-02-01

    The variation of the photosphere physical state during the decay phase of SF/B6.8-class solar flare on May 28, 2012 in active region NOAA 11490 is studied. We used the data of the spectropolarimetric observations with the French-Italian solar telescope THEMIS (Tenerife, Spain). Semi-empirical model atmospheres are derived from the inversion with SIR (Stokes Inversion based on Response functions) code. The inversion was based on Stokes profiles of six photospheric lines. Each model atmosphere has a two-component structure: a magnetic flux tube and non-magnetic surroundings. The Harvard Smithsonian Reference Atmosphere (HSRA) has been adopted for the surroundings. The macroturbulent velocity and the filling factor were assumed to be constant with the depth. The optical depth dependences of the temperature, magnetic field strength, and line-of-sight velocity are obtained from inversion. According to the received model atmospheres, the parameters of the magnetic field and the thermodynamical parameters changed during the decay phase of the flare. The model atmospheres showed that the photosphere remained in a disturbed state during observations after the maximum of the flare. There are temporal changes in the temperature and the magnetic field strength optical depth dependences. The temperature enhancement in the upper photospheric layers is found in the flaring atmospheres relative to the quiet-Sun model. The downflows are found in the low and upper photosphere at the decay phase of the flare.

  7. Observations of High-frequency Internal Wave Energy Offshore of Point Loma, California

    NASA Astrophysics Data System (ADS)

    Rhee, K.; Crosby, S. C.; Fiedler, J. W.

    2016-12-01

    As coastally directed internal wave energy shoals in shallow water, the resulting bores can transport cold, dense, nutrient-rich waters shoreward, influencing local fauna and ultimately dissipating tidal energy into heat. Understanding the mechanisms, propagation, and resultant transport is crucial for determining the physical-biological interactions along our coasts. We observed significant internal wave energy offshore of Point Loma, San Diego using a thermistor chain moored in 22m depth. Temperature observations spaced 1.5m apart from 0 to 18m were sampled at 2Hz and recorded for a period of ten days during July 2016. Temperature, salinity, oxygen, and nutrient profiles were obtained at 3 stations further offshore during deployment and recovery cruises. At the time of mooring deployment, thermocline depth was 10 to 20m. During recovery we observed a significant decrease of thermocline depth, which was likely caused by surface mixing during a strong wind event. During the 10-day deployment we observed many high frequency (5 to 10 minute periods) internal waves events. In addition, we noticed rapid temperature changes (4oC in less than a minute) suggestive of internal bores; however, other events appeared to be linear, possibly indicating unbroken internal waves. Here, we examine the critical slope for linear mode-1 propagation, the correlation of these events with tidal ebb and flow, and infer how a deeper mixed layer effects internal wave propagation.

  8. Storm-induced water dynamics and thermohaline structure at the tidewater Flade Isblink Glacier outlet to the Wandel Sea (NE Greenland)

    NASA Astrophysics Data System (ADS)

    Kirillov, Sergei; Dmitrenko, Igor; Rysgaard, Søren; Babb, David; Toudal Pedersen, Leif; Ehn, Jens; Bendtsen, Jørgen; Barber, David

    2017-11-01

    In April 2015, an ice-tethered conductivity-temperature-depth (CTD) profiler and a down-looking acoustic Doppler current profiler (ADCP) were deployed from the landfast ice near the tidewater glacier terminus of the Flade Isblink Glacier in the Wandel Sea, NE Greenland. The 3-week time series showed that water dynamics and the thermohaline structure were modified considerably during a storm event on 22-24 April, when northerly winds exceeded 15 m s-1. The storm initiated downwelling-like water dynamics characterized by on-shore water transport in the surface (0-40 m) layer and compensating offshore flow at intermediate depths. After the storm, currents reversed in both layers, and the relaxation phase of downwelling lasted ˜ 4 days. Although current velocities did not exceed 5 cm s-1, the enhanced circulation during the storm caused cold turbid intrusions at 75-95 m depth, which are likely attributable to subglacial water from the Flade Isblink Ice Cap. It was also found that the semidiurnal periodicities in the temperature and salinity time series were associated with the lunar semidiurnal tidal flow. The vertical structure of tidal currents corresponded to the first baroclinic mode of the internal tide with a velocity minimum at ˜ 40 m. The tidal ellipses rotate in opposite directions above and below this depth and cause a divergence of tidal flow, which was observed to induce semidiurnal internal waves of about 3 m height at the front of the glacier terminus. Our findings provide evidence that shelf-basin interaction and tidal forcing can potentially modify coastal Wandel Sea waters even though they are isolated from the atmosphere by landfast sea ice almost year-round. The northerly storms over the continental slope cause an enhanced circulation facilitating a release of cold and turbid subglacial water to the shelf. The tidal flow may contribute to the removal of such water from the glacial terminus.

  9. Depth resolution and preferential sputtering in depth profiling of sharp interfaces

    NASA Astrophysics Data System (ADS)

    Hofmann, S.; Han, Y. S.; Wang, J. Y.

    2017-07-01

    The influence of preferential sputtering on depth resolution of sputter depth profiles is studied for different sputtering rates of the two components at an A/B interface. Surface concentration and intensity depth profiles on both the sputtering time scale (as measured) and the depth scale are obtained by calculations with an extended Mixing-Roughness-Information depth (MRI)-model. The results show a clear difference for the two extreme cases (a) preponderant roughness and (b) preponderant atomic mixing. In case (a), the interface width on the time scale (Δt(16-84%)) increases with preferential sputtering if the faster sputtering component is on top of the slower sputtering component, but the true resolution on the depth scale (Δz(16-84%)) stays constant. In case (b), the interface width on the time scale stays constant but the true resolution on the depth scale varies with preferential sputtering. For similar order of magnitude of the atomic mixing and the roughness parameters, a transition state between the two extremes is obtained. While the normalized intensity profile of SIMS represents that of the surface concentration, an additional broadening effect is encountered in XPS or AES by the influence of the mean electron escape depth which may even cause an additional matrix effect at the interface.

  10. How deep does disturbance go? The legacy of hurricanes on tropical forest soil biogeochemistry

    NASA Astrophysics Data System (ADS)

    Gutiérrez del Arroyo, O.; Silver, W. L.

    2016-12-01

    Ecosystem-scale disturbances, such as hurricanes and droughts, are periodic events with the capacity to cycle vast amounts of energy and matter. Such is the case of hurricanes in wet tropical forests, where intense winds defoliate the forest canopy and deposit large quantities of debris on the forest floor. These disturbances strongly affect soil biogeochemistry by altering soil moisture and temperature regimes, as well as litterfall, decomposition rates, and ultimately soil carbon (C) pools. Although these impacts are mostly concentrated near the soil surface, it is critical to consider the long-term effects on hurricanes on the deep soil profile, given the potential for soil C sequestration to occur at depth. Our study was conducted in the Canopy Trimming Experiment, an ongoing experiment within the Luquillo LTER in Puerto Rico. Ten years prior to our study, treatments including canopy trimming and debris deposition, independently and in combination, were imposed on 30 x 30 m plots within Tabonuco forests. We sampled 12 soil profiles (4 treatments, n=3) from 0 to 100 cm, at 10 cm intervals, and measured a suite of biogeochemical properties to explore treatment effects, as well as changes with depth. After a decade of recovery from the imposed treatments, there were no significant differences in soil moisture or soil pH among treatments at any depth, although significant changes with depth occurred for both variables. Iron concentrations, despite showing no treatment effects, decreased markedly with depth, highlighting the biogeochemical thresholds that occur along the soil profile. Notably, debris deposition resulted in significantly higher soil C, nitrogen (N), and phosphorus (P) concentrations in bulk soils, with effects being detected even at depths >50 cm. Moreover, density fractionation analyses of surface and deep soils revealed potential pathways for the measured increases in C, N, and P, including the accumulation of organic matter in the light fraction, as well as physiochemical interactions between organic molecules and minerals in the heavy fraction. Together, our data suggests that hurricane disturbances, by providing unusually large quantities of litterfall, can serve as a periodic subsidy of organic matter to the soil, which helps to maintain soil fertility and promote soil C sequestration.

  11. Trapping of Momentum due to Low Salinity Water in the north Bay of Bengal

    NASA Astrophysics Data System (ADS)

    Chaudhuri, D.; Tandon, A.; Farrar, T.; Weller, R. A.; Venkatesan, R.; S, S.; MacKinnon, J. A.; D'Asaro, E. A.; Sengupta, D.

    2016-02-01

    We study the relation between near-surface ocean stratification and upper ocean currents (momentum) during the diurnal cycle and subseasonal "active-break cycle" of the summer monsoon in the north Bay of Bengal. We use time series of hourly observations from NIOT moorings BD08, BD09 and an INCOIS mooring near 18 N, 89 E in 2013, and data collected during two research cruises of ORV Sagar Nidhi in August-September 2014 and 2015. Our analyses are based on upper ocean profiles of temperature, salinity and density (from moorings and a shipborne underway conductivity-temperature-depth profiler), velocity (Acoustic Doppler Current Profiler), and surface forcing (meterology sensors on moored buoy and ship). Monsoon breaks are characterized by low rainfall, low wind speed (0-5 m/s) and high incident shortwave radiation, whereas active phases are marked by intense rainfall, high wind speed (8-16 m/s) and low incident sunlight. Our main findings are: (i) Net surface heat flux is positive (ocean gains heat) during break spells, and sea surface temperature (SST) rises by upto 1.5 C in 1-2 weeks. (ii) During breaks, day-night SST difference can reach 1.5C; mixed layer depth (MLD) shoals to 5m during day time, and deepens to 15-20 m by late night/early morning. (iii) During active spells, SST cools on subseasonal scales; MLD is deep (exceeding 20 m), and diurnal re-stratification is weak or absent. (iv) Once very low-salinity water (<30 psu) from rivers arrives at the moorings in late August, MLD remains shallow, and is insensitive to subseasonal changes in surface forcing. (v) Moored data and high-resolution observations from the summer 2014 and 2015 cruises reveal trapping of momentum from winds in a relatively thin surface layer when surface salinity is low and the shallow stratification is strong. Results of ingoing analyses will be presented at the meeting.

  12. Mixed convective/dynamic roll vortices and their effects on initial wind and temperature profiles

    NASA Technical Reports Server (NTRS)

    Haack, Tracy; Shirer, Hampton N.

    1991-01-01

    The onset and development of both dynamically and convectively forced boundary layer rolls are studied with linear and nonlinear analyses of a truncated spectral model of shallow Boussinesq flow. Emphasis is given here on the energetics of the dominant roll modes, on the magnitudes of the roll-induced modifications of the initial basic state wind and temperature profiles, and on the sensitivity of the linear stability results to the use of modified profiles as basic states. It is demonstrated that the roll circulations can produce substantial changes to the cross-roll component of the initial wind profile and that significant changes in orientation angle estimates can result from use of a roll-modified profile in the stability analysis. These results demonstrate that roll contributions must be removed from observed background wind profiles before using them to investigate the mechanisms underlying actual secondary flows in the boundary layer. The model is developed quite generally to accept arbitrary basic state wind profiles as dynamic forcing. An Ekman profile is chosen here merely to provide a means for easy comparison with other theoretical boundary layer studies; the ultimate application of the model is to study observed boundary layer profiles. Results of the analytic stability analysis are validated by comparing them with results from a larger linear model. For an appropriate Ekman depth, a complete set of transition curves is given in forcing parameter space for roll modes driven both thermally and dynamically. Preferred orientation angles, horizontal wavelengths and propagation frequencies, as well as energetics and wind profile modifications, are all shown to agree rather well with results from studies on Ekman layers as well as with studies on near-neutral and convective atmospheric boundary layers.

  13. Vertical Structure of Ice Cloud Layers From CloudSat and CALIPSO Measurements and Comparison to NICAM Simulations

    NASA Technical Reports Server (NTRS)

    Ham, Seung-Hee; Sohn, Byung-Ju; Kato, Seiji; Satoh, Masaki

    2013-01-01

    The shape of the vertical profile of ice cloud layers is examined using 4 months of CloudSat and Cloud-Aerosol Lidar and Infrared Pathfinder Satellite Observation (CALIPSO) global measurements taken on January, April, July, and October 2007. Ice clouds are selected using temperature profiles when the cloud base is located above the 253K temperature level. The obtained ice water content (IWC), effective radius, or extinction coefficient profiles are normalized by their layer mean values and are expressed in the normalized vertical coordinate, which is defined as 0 and 1 at the cloud base and top heights, respectively. Both CloudSat and CALIPSO observations show that the maximum in the IWC and extinction profiles shifts toward the cloud bottom, as the cloud depth increases. In addition, clouds with a base reaching the surface in a high-latitude region show that the maximum peak of the IWC and extinction profiles occurs near the surface, which is presumably due to snow precipitation. CloudSat measurements show that the seasonal difference in normalized cloud vertical profiles is not significant, whereas the normalized cloud vertical profile significantly varies depending on the cloud type and the presence of precipitation. It is further examined if the 7 day Nonhydrostatic Icosahedral Atmospheric Model (NICAM) simulation results from 25 December 2006 to 1 January 2007 generate similar cloud profile shapes. NICAM IWC profiles also show maximum peaks near the cloud bottom for thick cloud layers and maximum peaks at the cloud bottom for low-level clouds near the surface. It is inferred that oversized snow particles in the NICAM cloud scheme produce a more vertically inhomogeneous IWC profile than observations due to quick sedimentation.

  14. Effect of thermal annealing on the redistribution of alkali metals in Cu(In,Ga)Se2 solar cells on glass substrate

    NASA Astrophysics Data System (ADS)

    Kamikawa, Yukiko; Nishinaga, Jiro; Ishizuka, Shogo; Tayagaki, Takeshi; Guthrey, Harvey; Shibata, Hajime; Matsubara, Koji; Niki, Shigeru

    2018-03-01

    The precise control of alkali-metal concentrations in Cu(In,Ga)Se2 (CIGS) solar cells via post deposition treatment (PDT) has recently attracted attention. When PDT is performed at an elevated temperature, an accompanying annealing effect is expected. Here, we investigate how thermal annealing affects the redistribution of alkali metals in CIGS solar cells on glass substrates and the properties of the solar cells. In addition, we investigate the origin of non-homogeneous alkali-metal depth profiles that are typical of CIGS grown using a three-stage process. In particular, we use secondary-ion mass spectrometry measurements of the ion concentration as a function of distance from the CIGS surface to investigate the impact of thermal annealing on the distribution of alkali metals (Na, Ka, and Rb) and constituent elements (Ga and In) in the CIGS absorbers. We find that the depth profiles of the alkali metals strongly reflect the density of sites that tend to accommodate alkali metals, i.e., vacancies. Annealing at elevated temperature caused a redistribution of the alkali metals. The thermal-diffusion kinetics of alkali metals depends strongly on the species involved. We introduced low flux potassium fluoride (KF) to study a side effect of KF-PDT, i.e., Na removal from CIGS, separately from its predominant effects such as surface modification. When sufficient amounts of Na are supplied from the soda lime glass via annealing at an elevated temperature, the negative effect was not apparent. Conversely, when the Na supply was not sufficient, it caused a deterioration of the photovoltaic properties.

  15. Heat-flow data and their relation to observed geothermal phenomena near Klamath Falls, Oregon

    USGS Publications Warehouse

    Sass, J.H.; Sammel, Edward A.

    1976-01-01

    Two holes were drilled to depths of about 180 m in the Lower Klamath Lake basin south of Klamath Falls, Oregon, to obtain heat flow data and to provide estimates of the thermal conductivity of the valley fill. Twenty-nine thermal conductivity determinations on eight cores give a mean conductivity of 1.82 mcal/cm s °C (0.75 W/m °K). Curvature in the upper 50 m of both terriperature profiles indicates a decrease in surface temperature of about 1.8°C, presumably resulting frorn reclamation of what was marshland in the early part of this century. A surprisingly low heat flow of 0.3 HFU (1 HFU = 10−6 cal/cm2 s = 41.8 mW/m2) was measured at site LS near the center of the basin. At site OC-1, 7 km east of LS and 2 km from the Klamath Hills geothermal zone, the heat flow was 1.44 HFU, also a low value in this setting. Temperature profiles in 15 unused water wells in the area had linear gradients ranging from 47° to 170°C/km. The corresponding lower limits of heat flow (conductivities measured at the two heat flow sites being used) range from 0.8 to 3.1 HFU. These variations in heat flow evidently are caused by temperature variations in a convecting system within the near-surface volcanic rocks and do not provide firm constraints on the nature of heat sources at depth.

  16. First Autonomous Bio-Optical Profiling Float in the Gulf of Mexico Reveals Dynamic Biogeochemistry in Deep Waters

    PubMed Central

    Green, Rebecca E.; Bower, Amy S.; Lugo-Fernández, Alexis

    2014-01-01

    Profiling floats equipped with bio-optical sensors well complement ship-based and satellite ocean color measurements by providing highly-resolved time-series data on the vertical structure of biogeochemical processes in oceanic waters. This is the first study to employ an autonomous profiling (APEX) float in the Gulf of Mexico for measuring spatiotemporal variability in bio-optics and hydrography. During the 17-month deployment (July 2011 to December 2012), the float mission collected profiles of temperature, salinity, chlorophyll fluorescence, particulate backscattering (bbp), and colored dissolved organic matter (CDOM) fluorescence from the ocean surface to a depth of 1,500 m. Biogeochemical variability was characterized by distinct depth trends and local “hot spots”, including impacts from mesoscale processes associated with each of the water masses sampled, from ambient deep waters over the Florida Plain, into the Loop Current, up the Florida Canyon, and eventually into the Florida Straits. A deep chlorophyll maximum (DCM) occurred between 30 and 120 m, with the DCM depth significantly related to the unique density layer ρ = 1023.6 (R2 = 0.62). Particulate backscattering, bbp, demonstrated multiple peaks throughout the water column, including from phytoplankton, deep scattering layers, and resuspension. The bio-optical relationship developed between bbp and chlorophyll (R2 = 0.49) was compared to a global relationship and could significantly improve regional ocean-color algorithms. Photooxidation and autochthonous production contributed to CDOM distributions in the upper water column, whereas in deep water, CDOM behaved as a semi-conservative tracer of water masses, demonstrating a tight relationship with density (R2 = 0.87). In the wake of the Deepwater Horizon oil spill, this research lends support to the use of autonomous drifting profilers as a powerful tool for consideration in the design of an expanded and integrated observing network for the Gulf of Mexico. PMID:24992646

  17. Profilometric characterization of DOEs with continuous microrelief

    NASA Astrophysics Data System (ADS)

    Korolkov, V. P.; Ostapenko, S. V.; Shimansky, R. V.

    2008-09-01

    Methodology of local characterization of continuous-relief diffractive optical elements has been discussed. The local profile depth can be evaluated using "approximated depth" defined without taking a profile near diffractive zone boundaries into account. Several methods to estimate the approximated depth have been offered.

  18. Comparison of Air Fluorescence and Ionization Measurements of E.M. Shower Depth Profiles: Test of a UHECR Detector Technique

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Belz, J.; Cao, Z.; Huentemeyer, P.

    Measurements are reported on the fluorescence of air as a function of depth in electromagnetic showers initiated by bunches of 28.5 GeV electrons. The light yield is compared with the expected and observed depth profiles of ionization in the showers. It validates the use of atmospheric fluorescence profiles in measuring ultra high energy cosmic rays.

  19. Identification of shallow geothermal anomalies in the Timanfaya National Park (Lanzarote, Canary Islands) through combined geophysical prospecting techniques

    NASA Astrophysics Data System (ADS)

    Gómez-Ortiz, David; Blanco-Montenegro, Isabel; Martín-Crespo, Tomás; Arnoso, José; Solla, Mercedes; Montesinos, Fuensanta G.; Vélez, Emilio; Calvo-Rathert, Manuel; Sánchez, Nieves; Lorenzo, Henrique; Soler, Vicente

    2017-04-01

    The Timanfaya National Park is a volcanic area in the southwest of Lanzarote Island (Canary Archipelago, Spain) resulting from the 1730-1736 eruption period. Several active geothermal anomalies have been identified from 1970's. Their location is important to prevent hazards in this restricted touristic area of the park. Presently, only some regional geophysical studies based on gravity, magnetic and seismic data have been undertaken to model the crustal structure of Lanzarote Island. This work presents a new study about the geothermal anomalies in the Timanfaya National Park by the analysis and joint interpretation of electrical resistivity tomography (ERT), magnetic anomalies and electromagnetic induction data (EMI). All analyzed data have been obtained over areas which had not been surveyed before. The studied geothermal field is located at the Islote de Hilario visitor's centre. One 50m-long GPR profile was carried out in May 2012 along the location of a known geothermal anomaly developed over pyroclastic deposits. The two main characteristics are: a) no continuous subhorizontal reflections are displayed up to 12 m depth and, b) the intensity of the reflections varies laterally in good agreement with the location of the geothermal anomalies (the higher the ground temperature, the greater the intensity of the GPR signal). Thus, an outline of the subsurface area with higher temperatures can be observed, indicating that the heat source is deeper at the beginning of the profile and extends laterally and progressively shallower towards the end. Temporal variation of the shallow temperature distribution was also investigated by repeating the same GPR profile in April 2015. Although both profiles look quite similar, subtle variations of the GPR signal intensity suggest a certain temporal variation of the ground temperature. In November 2012 a land magnetic survey was carried out in Timanfaya. In the Islote de Hilario area, total field magnetic data were acquired with an Overhauser magnetometer following a 75m-long profile which coincides in the first 50 m with the GPR profile. Three additional profiles (two of them parallel and one orthogonal to the first one) completed the survey, allowing the interpolation of the data into a regular grid. The resulting reduced-to-the-pole anomaly map displays some magnetic lows which could be related with high temperatures at shallow depths causing the loss of magnetic properties within the subsurface volcanic rocks. Forward modelling has been carried out to characterize the magnetic sources and to analyze the correlations with GPR data. These models have been constrained with NRM and susceptibility data measured in the laboratory for samples from the Timanfaya lava flows. Preliminary results of EMI data show high resistivity areas in good agreement with the location of the shallow geothermal anomalies, the magnetic lows and the high GPR signal intensity. The comparison of the results obtained from the different techniques reveals that the joint interpretation of ERT, magnetic anomalies and EMI methods provides reliable models useful for the location of shallow geothermal anomalies. These non-destructive geophysical techniques are of crucial importance in areas of special protection such as National Parks.

  20. Effect of varying chromophores used in light-activated protein solders on tensile strength and thermal damage profile of repairs.

    PubMed

    Hoffman, Grant T; Byrd, Brian D; Soller, Eric C; Heintzelman, Douglas L; McNally-Heintzelman, Karen M

    2003-01-01

    Clinical adoption of laser tissue welding (LTW) techniques has been beleaguered by problems associated with thermal damage of tissue and insufficient strength of the resulting tissue bond. The magnitude of these problems has been significantly reduced with the incorporation of indocyanine green (ICG)-doped protein solders into the LTW procedure to form a new technique known as laser tissue soldering (LTS). With the addition of ICG, a secondary concern has arisen relating to the potential harmful effects of the degradation products of the chromophore upon thermal denaturation of the protein solder with a laser. In this study, two different food colorings were investigated, including blue #1 and green consisting of yellow #5 and blue #1, as alternative chromophores for use in LTS techniques. Food coloring has been found to have a suitable stability and safety profile for enteral use when heated to temperatures above 200 degrees C; thus, it is a promising candidate chromophore for LTS which typically requires temperatures between 50 degrees C and 100 degrees C. Experimental investigations were conducted to test the tensile strength of ex vivo repairs formed using solders doped with these alternative chromophores in a bovine model. Two commonly used chromophores, ICG and methylene blue (MB), were investigated as a reference. In addition, the temperature rise, depth of thermal coagulation in the protein solder, and the extent of thermal damage in the surrounding tissue were measured. Temperature rise at the solder/tissue interface, and consequently the degree of solder coagulation and collateral tissue thermal damage, was directly related to the penetration depth of laser light in the protein solder. Variation of the chromophore concentration such that the laser light penetrated to a depth approximately equal to half the thickness of the solder resulted in uniform results between each group of chromophores investigated. Optimal tensile strength of repairs was achieved by optimizing laser and solder parameters to obtain a temperature of approximately 65 degrees C at the solder/tissue interface. The two alternative chromophores tested in this study show considerable promise for application in LTS techniques, with equivalent tensile strength to solders doped with ICG or MB, and the potential advantage of eliminating the risks associated with harmful byproducts.

  1. Radiation Testing of PICA at the Solar Power Tower

    NASA Technical Reports Server (NTRS)

    White, Susan M.

    2010-01-01

    Sandia National Laboratory's Solar Power Tower was used to irradiate specimens of Phenolic Impregnated Carbon Ablator (PICA), in order to evaluate whether this thermal protection system material responded differently to potential shock layer radiative heating than to convective heating. Tests were run at 50, 100 and 150 Watts per square centimeter levels of concentrated solar radiation. Experimental results are presented both from spectral measurements on 1- 10 mm thick specimens of PICA, as well as from in-depth temperature measurements on instrumented thicker test specimens. Both spectral measurements and measured in-depth temperature profiles showed that, although it is a porous, low-density material, PICA does not exhibit problematic transparency to the tested high levels of NIR radiation, for all pragmatic cm-to-inch scale thicknesses. PICA acted as a surface absorber to efficiently absorb the incident visible and near infrared incident radiation in the top 2 millimeter layer in the Solar Power Tower tests up to 150 Watts per square centimeter.

  2. Ocean, Land and Meteorology Studies Using Space-Based Lidar Measurements

    NASA Technical Reports Server (NTRS)

    Hu,Yongxiang

    2009-01-01

    CALIPSO's main mission objective is studying the climate impact of clouds and aerosols in the atmosphere. CALIPSO also collects information about other components of the Earth's ecosystem, such as oceans and land. This paper introduces the physics concepts and presents preliminary results for the valueadded CALIPSO Earth system science products. These include ocean surface wind speeds, column atmospheric optical depths, ocean subsurface backscatter, land surface elevations, atmospheric temperature profiles, and A-train data fusion products.

  3. Acquisition of Ice-Tethered Profilers with Velocity (ITP-V) Instruments for Future Arctic Studies

    DTIC Science & Technology

    2016-11-15

    instrument that measures sea water temperature and salinity versus depth, the ITP-V adds a multi-axis acoustic -travel-time current meter and...housing capped by an ultra-high-molecular-weight polyethylene dome. The electronics case sits within a foam body designed to provide buoyancy for...then transmits them by satellite to a logger computer at WHO I. The ITP-V instruments add a multi-axis acoustic -travel-time current meter and

  4. Quantifying mantle structure and dynamics using plume tracing in seismic tomography

    NASA Astrophysics Data System (ADS)

    O'Farrell, K. A.; Eakin, C. M.; Jackson, M. G.; Jones, T. D.; Lekic, V.; Lithgow-Bertelloni, C. R.

    2017-12-01

    Directly linking deep mantle processes with surface features and dynamics is a complex problem. Hotspot volcanism gives us surface observables of mantle signatures, but the depth and source of the mantle plumes feeding these hotspots are highly debated. To address these issues, it is necessary to consider the entire journey of a plume through the mantle. By analyzing the behavior of mantle plumes we can constrain the vigor of mantle convection, the net rotation of the mantle and the role of thermal versus chemical anomalies as well as the bulk physical properties such as the viscosity profile. To do this, we developed a new algorithm to trace plume-like features in shear-wave (Vs) seismic tomography models based on picking local minima in the velocity and searching for continuous features with depth. We applied this method to recent tomographic models and find 60+ continuous plume conduits that are > 750 km long. Approximately a third of these can be associated with known hotspots at the surface. We analyze the morphology of these continuous conduits and infer large scale mantle flow patterns and properties. We find the largest lateral deflections in the conduits occur near the base of the lower mantle and in the upper mantle (near the thermal boundary layers). The preferred orientation of the plume deflections show large variability at all depths and indicate no net mantle rotation. Plate by plate analysis shows little agreement in deflection below particular plates, indicating these deflected features might be long lived and not caused by plate shearing. Changes in the gradient of plume deflection are inferred to correspond with viscosity contrasts in the mantle and found below the transition zone as well as at 1000 km depth. From this inferred viscosity structure, we explore the dynamics of a plume through these viscosity jumps. We also retrieve the Vs profiles for the conduits and compare with the velocity profiles predicted for different mantle adiabat temperatures. We are able to constrain the average temperature anomaly of the conduits to be around 150 K. We use these thermal anomalies in conjunction with our measured plume tilts/deflections to further explore the dynamics of plume conduits in the lower mantle and transition zone.

  5. Profiling defect depth in composite materials using thermal imaging NDE

    NASA Astrophysics Data System (ADS)

    Obeidat, Omar; Yu, Qiuye; Han, Xiaoyan

    2018-04-01

    Sonic Infrared (IR) NDE, is a relatively new NDE technology; it has been demonstrated as a reliable and sensitive method to detect defects. SIR uses ultrasonic excitation with IR imaging to detect defects and flaws in the structures being inspected. An IR camera captures infrared radiation from the target for a period of time covering the ultrasound pulse. This period of time may be much longer than the pulse depending on the defect depth and the thermal properties of the materials. With the increasing deployment of composites in modern aerospace and automobile structures, fast, wide-area and reliable NDE methods are necessary. Impact damage is one of the major concerns in modern composites. Damage can occur at a certain depth without any visual indication on the surface. Defect depth information can influence maintenance decisions. Depth profiling relies on the time delays in the captured image sequence. We'll present our work on the defect depth profiling by using the temporal information of IR images. An analytical model is introduced to describe heat diffusion from subsurface defects in composite materials. Depth profiling using peak time is introduced as well.

  6. A methodology for using borehole temperature-depth profiles under ambient, single and cross-borehole pumping conditions to estimate fracture hydraulic properties

    NASA Astrophysics Data System (ADS)

    Klepikova, M.; Le Borgne, T.; Bour, O.; Lavenant, N.

    2011-12-01

    In fractured aquifers flow generally takes place in a few fractured zones. The identification of these main flow paths is critical as it controls the transfer of fluids in the subsurface. For realistic modeling of the flow the knowledge about the spatial variability of hydraulic properties is required. Inverse problems based on hydraulic head data are generally strongly underconstrained. A possible way of reducing the uncertainty is to combine different type of data, such as flow measurements, temperature profiles or tracer test data. Here, we focus on the use of temperature, which can be seen as a natural tracer of ground water flow. Previous studies used temperature anomalies to quantify vertical or horizontal regional groundwater flow velocities. Most of these studies assume that water in the borehole is stagnant, and, thus, the temperature profile in the well is representative of the temperature in the aquifer. In fractured media, differences in hydraulic head between flow paths connected to a borehole generally create ambient vertical flow within the borehole. These differences in hydraulic head are in general due to regional flow conditions. Estimation of borehole vertical flow is of interest as it can be used to derive large scale hydraulic connections. Under a single-borehole configuration, the estimation of vertical flow can be used to estimate the local transimissivities and the hydraulic head differences driving the flow through the borehole. Under a cross-borehole set up, it can be used to characterize hydraulic connections and estimate their hydraulic properties. Using a flow and heat transfer numerical model, we find that the slope of the temperature profile is related directly to vertical borehole flow velocity. Thus, we propose a method to invert temperature measurements to derive borehole flow velocities and subsequently the fracture zone hydraulic and connectivity properties. The advantage of temperature measurements compared to flowmeter measurements is that temperature can be measured easily and very accurately, continuously in space and time. To test the methodology, we have performed a field experiment at a crystalline rocks field site, located in Ploemeur, Brittany (France). The site is composed of three 100 meters deep boreholes, located at 6-10 m distances from each other. The experiment consisted in measuring the borehole temperature profiles under all possible pumping configurations. Hence, the pumping and monitoring wells were successively changed. The thermal response in observation well induced by changes in pumping conditions is related to changes in vertical flow velocities and thus to the inter-borehole fracture connectivity. Based on this dataset, we propose a methodology to include temperature profiles in inverse problem for characterizing the spatial distribution of fracture zone hydraulic properties.

  7. Characterization of an alluvial aquifer with thermal tracer tomography

    NASA Astrophysics Data System (ADS)

    Somogyvári, Márk; Bayer, Peter

    2017-04-01

    In the summer of 2015, a series of thermal tracer tests was performed at the Widen field site in northeast Switzerland. At this site numerous hydraulic, tracer, geophysical and hydrogeophysical field tests have been conducted in the past to investigate a shallow alluvial aquifer. The goals of the campaign in 2015 were to design a cost-effective thermal tracer tomography setup and to validate the concept of travel time-based thermal tracer tomography under field conditions. Thermal tracer tomography uses repeated thermal tracer injections with different injection depths and distributed temperature measurements to map the hydraulic conductivity distribution of a heterogeneous aquifer. The tracer application was designed with minimal experimental time and cost. Water was heated in inflatable swimming pools using direct sunlight of the warm summer days, and it was injected as low temperature pulses in a well. Because of the small amount of injected heat, no long recovery times were required between the repeated heat tracer injections and every test started from natural thermal conditions. At Widen, four thermal tracer tests were performed during a period of three days. Temperatures were measured in one downgradient well using a distributed temperature measurement system installed at seven depth points. Totally 12 temperature breakthrough curves were collected. Travel time based tomographic inversion assumes that thermal transport is dominated by advection and the travel time of the thermal tracer can be related to the hydraulic conductivities of the aquifer. This assumption is valid in many shallow porous aquifers where the groundwater flow is fast. In our application, the travel time problem was treated by a tomographic solver, analogous to seismic tomography, to derive the hydraulic conductivity distribution. At the test site, a two-dimensional cross-well hydraulic conductivity profile was reconstructed with the travel time based inversion. The reconstructed profile corresponds well with the findings of the earlier hydraulic and geophysical experiments at the site.

  8. Depth Effects on the Decomposition Dynamics of Plant-derived C at Diverse Sites

    NASA Astrophysics Data System (ADS)

    Gregorich, E.; Ellert, B.; Janzen, H.; Beare, M.; Helgason, B. L.; Curtin, D.

    2017-12-01

    Decay of plant residues is tied to many ecosystem functions and affects atmospheric CO2, plant-available nutrients, microbial diversity, soil organic matter quality, among others. The rate of decay, in turn, is governed by soil type and management, location in the soil profile, and environmental variables, some of which may be changing in coming decades. Our objective in this study was to elucidate the decomposition dynamics of plant-derived C and N at different soil depths. To characterize the importance of these variables across a broad scale, we established a long-term study at two sites in Canada and one site in New Zealand. At each site, labelled barley straw (13C = 10.2 atom%,C = 37.9%; N = 0.95%; C:N = 40) was installed at 3 depths (5-10, 20-25 and 40-45 cm). Soil temperature was logged at each depth. Samples were collected at different times over 5-6 years after application of the residues. Results showed that substantial decay occurred at all depths within a relatively short time (< 1 year). Decay was greatest at the warmest site and depth affected the concentration of viable microbes. However, depth had no effect on residue decay after about 5 years.

  9. Zirconia dental implants degradation by confocal Raman microspectroscopy: analytical simulation and experiments

    PubMed Central

    Djaker, Nadia; Wulfman, Claudine; Sadoun, Michaël; Lamy de la Chapelle, Marc

    2013-01-01

    Subsurface hydrothermal degradation of yttria stabilized tetragonal zirconia polycrystals (3Y-TZP) is presented. Evaluation of low temperature degradation (LTD) phase transformation induced by aging in 3Y-TZP is experimentally studied by Raman confocal microspectroscopy. A non-linear distribution of monoclinic volume fraction is determined in depth by using different pinhole sizes. A theoretical simulation is proposed based on the convolution of the excitation intensity profile and the Beer-Lambert law (optical properties of zirconia) to compare between experiment and theory. The calculated theoretical degradation curves matche closely to the experimental ones. Surface transformation (V0) and transformation factor in depth (T) are obtained by comparing simulation and experience for each sample with nondestructive optical sectioning. PMID:23667788

  10. Estimates of Oceanic Eddy Heat and Salt Transports from Satellite Altimetry and Argo Profile Data.

    NASA Astrophysics Data System (ADS)

    Amores Maimo, A. M.; Melnichenko, O.; Maximenko, N. A.

    2016-12-01

    Horizontal heat and salt fluxes by mesoscale eddies are estimated in the near-global ocean (10°-60° N and 10°-60° S) by combining historical records of Argo temperature/salinity profiles and satellite sea level anomaly data in the framework of the eddy tracking technique. The eddy fluxes are expectedly strong in the western boundary currents and in the Southern Ocean along the Antarctic Circumpolar Current (ACC). The fluxes are generally weak, but not negligible in gyre interiors. In the vertical, the eddy heat and salt fluxes are surface-intensified and confined mainly to the upper 600m layer, but their distribution with depth is not homogeneous throughout the ocean. In the Kuroshio Extension (KE) region, for example, the heat flux is poleward everywhere in the surface layer above the thermocline, but oppositely signed relative to the jet's axis in a deeper layer between approximately 300-800 m, where the flux is poleward on the northern side of the jet and equatorward on its southern side. Relatively strong fluxes at depth are also observed in the ACC, particularly in the Indian sector, and in the subtropical North Atlantic at the level of the Mediterranean Water (MW) at around 1000 m depth. The latter exemplifies the role of eddies in MW spreading. These and other features of the longitude-latitude-depth distributions of the eddy heat and salt fluxes, constructed for the first time from observational data, are presented and discussed.

  11. Soil microbial community profiles and functional diversity in limestone cedar glades

    USGS Publications Warehouse

    Cartwright, Jennifer M.; Dzantor, E. Kudjo; Momen, Bahram

    2016-01-01

    Rock outcrop ecosystems, such as limestone cedar glades (LCGs), are known for their rare and endemic plant species adapted to high levels of abiotic stress. Soils in LCGs are thin (< 25 cm), soil-moisture conditions fluctuate seasonally between xeric and saturated, and summer soil temperatures commonly exceed 48 °C. The effects of these stressors on soil microbial communities (SMC) remain largely unstudied, despite the importance of SMC-plant interactions in regulating the structure and function of terrestrial ecosystems. SMC profiles and functional diversity were characterized in LCGs using community level physiological profiling (CLPP) and plate-dilution frequency assays (PDFA). Most-probable number (MPN) estimates and microbial substrate-utilization diversity (H) were positively related to soil thickness, soil organic matter (OM), soil water content, and vegetation density, and were diminished in alkaline soil relative to circumneutral soil. Soil nitrate showed no relationship to SMCs, suggesting lack of N-limitation. Canonical correlation analysis indicated strong correlations between microbial CLPP patterns and several physical and chemical properties of soil, primarily temperature at the ground surface and at 4-cm depth, and secondarily soil-water content, enabling differentiation by season. Thus, it was demonstrated that several well-described abiotic determinants of plant community structure in this ecosystem are also reflected in SMC profiles.

  12. Soil-water movement under natural-site and waste-site conditions: A multiple-year field study in the Mojave Desert, Nevada

    USGS Publications Warehouse

    Andraski, Brian J.

    1997-01-01

    Soil-water movement under natural-site and simulated waste-site conditions were compared by monitoring four experimental sites in the Mojave Desert, Nevada, during a 5-year period: one vegetated soil profile, one soil profile where vegetation was removed, and two nonvegetated test trenches. Precipitation ranged from 14 to 162 mm/yr. Temporal changes in water content measured by neutron probe were limited to the upper 0.5–1 m; values ranged from 0.01 to 0.19 m3/m3. Water potential and temperature were measured by thermocouple psychrometers; 77% remained operable for ≥4.5 years. For vegetated soil, precipitation that accumulated in the upper 0.75 m of soil was removed by evapotranspiration: water potentials decreased seasonally by 4 to >8 MPa. During 2 years with below-average precipitation, water potentials below the app arent root zone decreased by 2.3 (1.2-m depth) to 0.4 MPa (5-m depth), and the gradients became predominantly upward. Water potentials then rebounded during 2 years with near- and above-average precipitation, and seasonally variant water potential gradients were reestablished above the 4.2-m depth. Under nonvegetated waste-site conditions, data indicated the long-term accumulation and shallow, but continued, penetration of precipitation: water potentials showed moisture penetration to depths of 0.75−1.85 m. The method of simulated-waste drum placement (stacked versus random) and the associated differences in subsidence showed no measurable influence on the water balance of the trenches: subsidence totaled ≤13 mm during the study. Water potentials below the trenches and below the 2-m depth for the nonvegetated soil remained low (≈−5.5 to −7.5 MPa) and indicated the persistence of typically upward driving forces for isothermal water flow. Water fluxes estimated from water potential and temperature data suggested that isothermal liquid, isothermal vapor, and nonisothermal vapor flow need to be considered in the conceptualization of unsaturated flow at the field sites. Below the depth of temporal water content change, the estimated liquid fluxes ranged from 10−10 to 10−15 cm/s, isothermal vapor fluxes ranged from 10−10 to 10−13 cm/s, and the nonisothermal vapor fluxes ranged from 10−8 to 10−10cm/s.

  13. Nondestructive strain depth profiling with high energy X-ray diffraction: System capabilities and limitations

    NASA Astrophysics Data System (ADS)

    Zhang, Zhan; Wendt, Scott; Cosentino, Nicholas; Bond, Leonard J.

    2018-04-01

    Limited by photon energy, and penetration capability, traditional X-ray diffraction (XRD) strain measurements are only capable of achieving a few microns depth due to the use of copper (Cu Kα1) or molybdenum (Mo Kα1) characteristic radiation. For deeper strain depth profiling, destructive methods are commonly necessary to access layers of interest by removing material. To investigate deeper depth profiles nondestructively, a laboratory bench-top high-energy X-ray diffraction (HEXRD) system was previously developed. This HEXRD method uses an industrial 320 kVp X-Ray tube and the Kα1 characteristic peak of tungsten, to produces a higher intensity X-ray beam which enables depth profiling measurement of lattice strain. An aluminum sample was investigated with deformation/load provided using a bending rig. It was shown that the HEXRD method is capable of strain depth profiling to 2.5 mm. The method was validated using an aluminum sample where both the HEXRD method and the traditional X-ray diffraction method gave data compared with that obtained using destructive etching layer removal, performed by a commercial provider. The results demonstrate comparable accuracy up to 0.8 mm depth. Nevertheless, higher attenuation capabilities in heavier metals limit the applications in other materials. Simulations predict that HEXRD works for steel and nickel in material up to 200 µm, but experiment results indicate that the HEXRD strain profile is not practical for steel and nickel material, and the measured diffraction signals are undetectable when compared to the noise.

  14. Upper mantle electrical conductivity for seven subcontinental regions of the Earth

    USGS Publications Warehouse

    Campbell, W.H.; Schiffmacher, E.R.

    1988-01-01

    Spherical harmonic analysis coefficients of the external and internal parts of the quiet-day geomagnetic field variations (Sq) separated for the 7 continental regions of the observatories have been used to determine conductivity profiles to depths of about 600 km by the Schmucker equivalent substitute conductor method. The profiles give evidence of increases in conductivity between about 150 and 350 km depth, then a general increase in conductivity thereafter. For South America we found a high conductivity at shallow depths. The European profile showed a highly conducting layer near 125 km. At the greater depths, Europe, Australia and South America had the lowest values of conductivity. North America and east Asia had intermediate values whereas the African and central Asian profiles both showed the conductivities rising rapidly beyond 450 km depth. The regional differences indicate that there may be considerable lateral heterogeneity of electrical conductivity in the Earth's upper mantle. -Authors

  15. Interactions between soil thermal and hydrological dynamics in the response of Alaska ecosystems to fire disturbance

    USGS Publications Warehouse

    Yi, Shuhua; McGuire, A. David; Harden, Jennifer; Kasischke, Eric; Manies, Kristen L.; Hinzman, Larry; Liljedahl, Anna K.; Randerson, J.; Liu, Heping; Romanovsky, Vladimir E.; Marchenko, Sergey S.; Kim, Yongwon

    2009-01-01

    Soil temperature and moisture are important factors that control many ecosystem processes. However, interactions between soil thermal and hydrological processes are not adequately understood in cold regions, where the frozen soil, fire disturbance, and soil drainage play important roles in controlling interactions among these processes. These interactions were investigated with a new ecosystem model framework, the dynamic organic soil version of the Terrestrial Ecosystem Model, that incorporates an efficient and stable numerical scheme for simulating soil thermal and hydrological dynamics within soil profiles that contain a live moss horizon, fibrous and amorphous organic horizons, and mineral soil horizons. The performance of the model was evaluated for a tundra burn site that had both preburn and postburn measurements, two black spruce fire chronosequences (representing space-for-time substitutions in well and intermediately drained conditions), and a poorly drained black spruce site. Although space-for-time substitutions present challenges in model-data comparison, the model demonstrates substantial ability in simulating the dynamics of evapotranspiration, soil temperature, active layer depth, soil moisture, and water table depth in response to both climate variability and fire disturbance. Several differences between model simulations and field measurements identified key challenges for evaluating/improving model performance that include (1) proper representation of discrepancies between air temperature and ground surface temperature; (2) minimization of precipitation biases in the driving data sets; (3) improvement of the measurement accuracy of soil moisture in surface organic horizons; and (4) proper specification of organic horizon depth/properties, and soil thermal conductivity.

  16. Soil temperature synchronisation improves estimation of daily variation of ecosystem respiration in Sphagnum peatlands

    NASA Astrophysics Data System (ADS)

    D'Angelo, Benoît; Gogo, Sébastien; Le Moing, Franck; Jégou, Fabrice; Guimbaud, Christophe; Laggoun, Fatima

    2015-04-01

    Ecosystem respiration (ER) is a key process in the global C cycle and thus, plays an important role in the climate regulation. Peatlands contain a third of the world soil C in spite of their relatively low global area (3% of land area). Although these ecosystems represent potentially a significant source of C under global change, they are still not taken into account accordingly in global climatic models. Therefore, ER variations have to be accounted for, especially by estimating its dependence to temperature.s The relationship between ER and temperature often relies only on one soil temperature depth and the latter is generally taken in the first 10 centimetres. Previous studies showed that the temperature dependence of ER depends on the depth at which the temperature is recorded. The depth selection for temperature measurement is thus a predominant issue. A way to deal with this is to analyse the time-delay between ER and temperature. The aim of this work is to assess whether using synchronised data in models leads to a better ER daily variation estimation than using non-synchronised data. ER measurements were undertaken in 2013 in 4 Sphagnum peatlands across France: La Guette (N 47°19'44', E 2°17'04', 154m) in July, Landemarais (N 48°26'30', E -1°10'54', 145m) in August, Frasne (N 46°49'35', E 6°10'20', 836m) in September, and Bernadouze (N 42°48'09', E 1°25'24', 1500m) in October. A closed method chamber was used to measure ER hourly during 72 hours in each of the 4 replicates installed in each site. Average ER ranged from 1.75 μmol m-2 s-1 to 6.13 μmol m-2 s-1. A weather station was used to record meteorological data and soil temperature profiles (5, 10, 20 and 30 cm). Synchronised data were determined for each depth by selecting the time-delay leading to the best correlation between ER and soil temperature. The data were used to simulate ER according to commonly used equations: linear, exponential with Q10, Arrhenius, Lloyd and Taylor. Models comparison was performed using RMSE (goodness-of-fit) and AIC (goodness-of-fit and model complexity) as indicators to assess their relative quality. Both indicators showed a wide variation between sites. However, for each site differences between synchronised and non-synchronised data were larger than the differences between models equations. According to the AIC, models using synchronised data produced better ER estimations than models using non-synchronised data, at all depth. RMSE support this result for all sites for superficial peat layer. In some locations, mainly Frasne, synchronised data at 5 cm depth provide better estimation than air temperature, i.e. 25.0 vs. 26.4 for RMSE and 337.1 vs. 379.8 for AIC, respectively. The equation of the most appropriate model varies between sites, but the differences between them are small. At a daily scale, data synchronisation in Sphagnum peatlands improves ER estimation regardless of the model used. Moreover, to estimate ER flux, the use of synchronised data at 5 cm depth seems the most adequate method.

  17. A Crystallization-Temperature Profile Through Paleo-Oceanic Crust (Wadi Gideah Transect, Oman Ophiolite): Application of the REE-in-Plagioclase-Clinopyroxene Partitioning Thermometer

    NASA Astrophysics Data System (ADS)

    Mueller, S.; Hasenclever, J.; Garbe-Schönberg, D.; Koepke, J.; Hoernle, K.

    2017-12-01

    The accretion mechanisms forming oceanic crust at fast spreading ridges are still under controversial discussion. Thermal, petrological, and geochemical observations predict different end-member models, i.e., the gabbro glacier and the sheeted sill model. They all bear implications for heat transport, temperature distribution, mode of crystallization and hydrothermal heat removal over crustal depth. In a typical MOR setting, temperature is the key factor driving partitioning of incompatible elements during crystallization. LA-ICP-MS data for co-genetic plagioclase and clinopyroxene in gabbros along a transect through the plutonic section of paleo-oceanic crust (Wadi Gideah Transect, Oman ophiolite) reveal that REE partitioning coefficients are relatively constant in the layered gabbro section but increase for the overlying foliated gabbros, with an enhanced offset towards HREEs. Along with a systematic enrichment of REE's with crustal height, these trends are consistent with a system dominated by in-situ crystallization for the lower gabbros and a change in crystallization mode for the upper gabbros. Sun and Liang (2017) used experimental REE partitioning data for calibrating a new REE-in-plagioclase-clinopyroxene thermometer that we used here for establishing the first crystallization-temperature depth profile through oceanic crust that facilitates a direct comparison with thermal models of crustal accretion. Our results indicate crystallization temperatures of about 1220±8°C for the layered gabbros and lower temperatures of 1175±8°C for the foliated gabbros and a thermal minimum above the layered-to-foliated gabbro transition. Our findings are consistent with a hybrid accretion model for the oceanic crust. The thermal minimum is assumed to represent a zone where the descending crystal mushes originating from the axial melt lens meet with mushes that have crystallized in situ. These results can be used to verify and test thermal models (e.g., Maclennan et al., 2004, Theissen-Krah et al., 2016) and their predictions for heat flow and temperature distribution in the crust. Maclennan, J., Hulme, T., & Singh, S. C. (2004), G3, 5(2). / Sun, C., & Liang, Y., (2017), CMP, 172(4). / Theissen-Krah, S., Rüpke, L. H., & Hasenclever, J. (2016), GRL, 43(3).

  18. Physical oceanographic data from the OTEC Punta Tuna, Puerto Rico Site, September 1979-June 1980

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Frye, D.; Davison, A.; Leavitt, K.

    1981-01-01

    The first results of an oceanographic measurement program being conducted off the southeast corner of Puerto Rico are presented. The study site is a proposed OTEC site and is located about 20 km off Punta Tuna. The objectives of the measurement program are to document the physical oceanography of the site as related to the engineering and environmental factors involved in OTEC design and operation. Oceanographic measurements include: (1) a subsurface mooring instrumented with five current, temperature, and pressure recorders; and (2) quarterly hydrographic cruises to measure salinity, temperature, and depth profiles on a grid of 33 stations in themore » vicinity of the mooring site. The first cruise, conducted between 16 and 21 June 1980, included the initial mooring deployment and a CTD (conductivity, temperature, and depth) and XBT (expendable bathythermograph) survey. The CTD/XBT measurements are presented. Also included are results of in situ current, temperature, and pressure measurements made during two previous programs. In September 1979, Coastal Marine Research (CMR) deployed a mooring at approximately the same site as the present mooring. Results from three of these instruments are included. The Naval Underwater Systems Center deployed a mooring at this site in February 1979 and partial results from one instrument on this mooring are also presented. (WHK)« less

  19. The deep atmosphere of Venus and the possible role of density-driven separation of CO2 and N2

    NASA Astrophysics Data System (ADS)

    Lebonnois, Sebastien; Schubert, Gerald

    2017-07-01

    With temperatures around 700 K and pressures of around 75 bar, the deepest 12 km of the atmosphere of Venus are so hot and dense that the atmosphere behaves like a supercritical fluid. The Soviet VeGa-2 probe descended through the atmosphere in 1985 and obtained the only reliable temperature profile for the deep Venusian atmosphere thus far. In this temperature profile, the atmosphere appears to be highly unstable at altitudes below 7 km, contrary to expectations. We argue that the VeGa-2 temperature profile could be explained by a change in the atmospheric gas composition, and thus molecular mass, with depth. We propose that the deep atmosphere consists of a non-homogeneous layer in which the abundance of N2--the second most abundant constituent of the Venusian atmosphere after CO2--gradually decreases to near-zero at the surface. It is difficult to explain a decline in N2 towards the surface with known nitrogen sources and sinks for Venus. Instead we suggest, partly based on experiments on supercritical fluids, that density-driven separation of N2 from CO2 can occur under the high pressures of Venus's deep atmosphere, possibly by molecular diffusion, or by natural density-driven convection. If so, the amount of nitrogen in the atmosphere of Venus is 15% lower than commonly assumed. We suggest that similar density-driven separation could occur in other massive planetary atmospheres.

  20. Hardness depth profile of lattice strained cemented carbide modified by high-energy boron ion implantation

    NASA Astrophysics Data System (ADS)

    Yoshida, Y.; Matsumura, A.; Higeta, K.; Inoue, T.; Shimizu, S.; Motonami, Y.; Sato, M.; Sadahiro, T.; Fujii, K.

    1991-07-01

    The hardness depth profiles of cemented carbides which were implanted with high-energy B + ions have been estimated using a dynamic microhardness tester. The B + implantations into (16% Co)-cemented WC alloys were carried out under conditions where the implantation energies were 1-3 MeV and the fluences 1 × 10 17-1 × 10 18ions/cm 2. The profiles show that the implanted layer becomes harder as fluences are chosen at higher values and there is a peak at a certain depth which depends on the implantation energy. In X-ray diffraction (XRD) studies of the implanted surface the broadened refraction peaks of only WC and Co are detected and the increments of lattice strain and of residual stress in the near-surface region are observed. It is supposed that the hardening effect should be induced by an increase in residual stress produced by lattice strain. The hardness depth profile in successive implantation of ions with different energies agrees with the compounded profile of each one of the implantations. It is concluded that the hardness depth profile can be controlled under adequate conditions of implantation.

  1. Effect of soil moisture on the temperature sensitivity of Northern soils

    NASA Astrophysics Data System (ADS)

    Minions, C.; Natali, S.; Ludwig, S.; Risk, D.; Macintyre, C. M.

    2017-12-01

    Arctic and boreal ecosystems are vast reservoirs of carbon and are particularly sensitive to climate warming. Changes in the temperature and precipitation regimes of these regions could significantly alter soil respiration rates, impacting atmospheric concentrations and affecting climate change feedbacks. Many incubation studies have shown that both temperature and soil moisture are important environmental drivers of soil respiration; this relationship, however, has rarely been demonstrated with in situ data. Here we present the results of a study at six field sites in Alaska from 2016 to 2017. Low-power automated soil gas systems were used to measure soil surface CO2 flux from three forced diffusion chambers and soil profile concentrations from three soil depth chambers at hourly intervals at each site. HOBO Onset dataloggers were used to monitor soil moisture and temperature profiles. Temperature sensitivity (Q10) was determined at each site using inversion analysis applied over different time periods. With highly resolved data sets, we were able to observe the changes in soil respiration in response to changes in temperature and soil moisture. Through regression analysis we confirmed that temperature is the primary driver in soil respiration, but soil moisture becomes dominant beyond a certain threshold, suppressing CO2 flux in soils with high moisture content. This field study supports the conclusions made from previous soil incubation studies and provides valuable insights into the impact of both temperature and soil moisture changes on soil respiration.

  2. Root Water Uptake and Soil Moisture Pattern Dynamics - Capturing Connections, Controls and Causalities

    NASA Astrophysics Data System (ADS)

    Blume, T.; Heidbuechel, I.; Hassler, S. K.; Simard, S.; Guntner, A.; Stewart, R. D.; Weiler, M.

    2015-12-01

    We hypothesize that there is a shift in controls on landscape scale soil moisture patterns when plants become active during the growing season. Especially during the summer soil moisture patterns are not only controlled by soils, topography and related abiotic site characteristics but also by root water uptake. Root water uptake influences soil moisture patterns both in the lateral and vertical direction. Plant water uptake from different soil depths is estimated based on diurnal fluctuations in soil moisture content and was investigated with a unique setup of 46 field sites in Luxemburg and 15 field sites in Germany. These sites cover a range of geologies, soils, topographic positions and types of vegetation. Vegetation types include pasture, pine forest (young and old) and different deciduous forest stands. Available data at all sites includes information at high temporal resolution from 3-5 soil moisture and soil temperature profiles, matrix potential, piezometers and sapflow sensors as well as standard climate data. At sites with access to a stream, discharge or water level is also recorded. The analysis of soil moisture patterns over time indicates a shift in regime depending on season. Depth profiles of root water uptake show strong differences between different forest stands, with maximum depths ranging between 50 and 200 cm. Temporal dynamics of signal strength within the profile furthermore suggest a locally shifting spatial distribution of root water uptake depending on water availability. We will investigate temporal thresholds (under which conditions spatial patterns of root water uptake become most distinct) as well as landscape controls on soil moisture and root water uptake dynamics.

  3. Ultra-Wideband Radiometry Remote Sensing of Polar Ice Sheet Temperature Profile, Sea Ice and Terrestrial Snow Thickness: Forward Modeling and Data Analysis

    NASA Astrophysics Data System (ADS)

    Tsang, L.; Tan, S.; Sanamzadeh, M.; Johnson, J. T.; Jezek, K. C.; Durand, M. T.

    2017-12-01

    The recent development of an ultra-wideband software defined radiometer (UWBRAD) operating over the unprotected spectrum of 0.5 2.0 GHz using radio-frequency interference suppression techniques offers new methodologies for remote sensing of the polar ice sheets, sea ice, and terrestrial snow. The instrument was initially designed for remote sensing of the intragalcial temperature profile of the ice sheet, where a frequency dependent penetration depth yields a frequency dependent brightness temperature (Tb) spectrum that can be linked back to the temperature profile of the ice sheet. The instrument was tested during a short flight over Northwest Greenland in September, 2016. Measurements were successfully made over the different snow facies characteristic of Greenland including the ablation, wet snow and percolation facies, and ended just west of Camp Century during the approach to the dry snow zone. Wide-band emission spectra collected during the flight have been processed and analyzed. Results show that the spectra are highly sensitive to the facies type with scattering from ice lenses being the dominant reason for low Tbs in the percolation zone. Inversion of Tb to physical temperature at depth was conducted on the measurements near Camp Century, achieving a -1.7K ten-meter error compared to borehole measurements. However, there is a relatively large uncertainty in the lower part possibly due to the large scattering near the surface. Wideband radiometry may also be applicable to sea ice and terrestrial snow thickness retrieval. Modeling studies suggest that the UWBRAD spectra reduce ambiguities inherent in other sea ice thickness retrievals by utilizing coherent wave interferences that appear in the Tb spectrum. When applied to a lossless medium such as terrestrial snow, this coherent oscillation turns out to be the single key signature that can be used to link back to snow thickness. In this paper, we report our forward modeling findings in support of instrument development and data analysis. The effects of density fluctuations and layered roughness are examined using a partially coherent model; we also report the results of applying such models to analyze the UWBRAD Greenland data. The approach of combining active L- band observations from PALSAR with UWBRAD Tb spectra is also discussed.

  4. Behavior of grain boundary chemistry and precipitates upon thermal treatment of controlled purity alloy 690

    NASA Astrophysics Data System (ADS)

    Angeliu, Thomas M.; Was, Gary S.

    1990-08-01

    Grain boundary composition and carbide composition and structure were characterized for various microstructures of controlled purity alloy 690. Heat treatments produced varying degrees of grain boundary chromium depletion and precipitate distributions which were characterized via scanning transmission electron microscopy (STEM). Convergent beam electron diffraction revealed that the dominant carbide is M23C6, and energy dispersive X-ray analysis (EDAX) determined that the metallic content was about 90 at. pct chromium. A discontinuous precipitation reaction was observed and is attributed to a high degree of carbon supersaturation. Grain boundary composition measurements confirm that chromium depletion is controlled by volume diffusion of chromium to chromium-rich grain boundary carbides in the temperature range of 873 to 1073 K. Grain boundary chromium levels as low as 18.8 at. pct were obtained by thermal treatment at 873 K for 250 hours and 973 K for 1 hour. A thermodynamic and kinetic model developed for alloy 600 was modified to describe the development of the chromium depletion profile in alloy 690 during thermal treatment. Experimentally measured chromium profiles agree well with the model results for the dependence of the chromium depletion zone width and depth on various input parameters. The establishment of the model for alloy 690 allows the chromium depletion zone width and depth to be computed as a function of alloy composition, grain size, and temperature. The chromium depletion profiles and the precipitate structure and composition of controlled purity 690 are compared to those of controlled purity 600. A thermodynamic analysis of the carbide stability indicates that other factors, such as favorable orientation relationships, play an important role in controlling the precipitation of Cr23C6 in nickel-base alloys.

  5. ToF-SIMS Depth Profiling Of Insulating Samples, Interlaced Mode Or Non-interlaced Mode?

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Wang, Zhaoying; Jin, Ke; Zhang, Yanwen

    2014-11-01

    Dual beam depth profiling strategy has been widely adopted in ToF-SIMS depth profiling, in which two basic operation modes, interlaced mode and non-interlaced mode, are commonly used. Generally, interlaced mode is recommended for conductive or semi-conductive samples, whereas non-interlaced mode is recommended for insulating samples, where charge compensation can be an issue. Recent publications, however, show that the interlaced mode can be used effectively for glass depth profiling, despite the fact that glass is an insulator. In this study, we provide a simple guide for choosing between interlaced mode and non-interlaced mode for insulator depth profiling. Two representative cases aremore » presented: (1) depth profiling of a leached glass sample, and (2) depth profiling of a single crystal MgO sample. In brief, the interlaced mode should be attempted first, because (1) it may provide reasonable-quality data, and (2) it is time-saving for most cases, and (3) it introduces low H/C/O background. If data quality is the top priority and measurement time is flexible, non-interlaced mode is recommended because interlaced mode may suffer from low signal intensity and poor mass resolution. A big challenge is tracking trace H/C/O in a highly insulating sample (e.g., MgO), because non-interlaced mode may introduce strong H/C/O background but interlaced mode may suffer from low signal intensity. Meanwhile, a C or Au coating is found to be very effective to improve the signal intensity. Surprisingly, the best analyzing location is not on the C or Au coating, but at the edge (outside) of the coating.« less

  6. Void formation in INCONEL MA-754 by high temperature oxidation

    NASA Astrophysics Data System (ADS)

    Rosenstein, Alan H.; Tien, John K.; Nix, William D.

    1986-01-01

    Subsurface void formation in oxide dispersion strengthened MA-754 caused by high temperature oxidation was investigated at temperatures of 1100, 1150, and 1200 °C for times of 1, 10, 50, and 100 hours. Material exposed at 1200 °C was examined using microprobe, SEM, and optical microscopy techniques. After exposure in air at 1200 °C for 100 hours, chromium depletion by as much as 10 wt pct was observed near the surface, and voids of various sizes up to 15 µm in diameter were found to depths of 300 µm. The fraction of voids increases with exposure time and, with the exception of anomalous values near the surface, decreases with depth. The maximum area fraction of voids observed was approximately 8 pct. Correlation of the void area fraction profile with the measured chromium depletion through a diffusion analysis shows that void formation is due to vacancy injection. Similar void formation in Ni-Cr alloys without oxide dispersions suggests that void formation is not dependent upon the presence of oxide dispersions. The diffusion coefficient for chromium in MA-754 at 1200 °C was computed from microprobe data to be 4 × 10-10 cm2 per second.

  7. Investigation of low-latitude hydrogen emission in terms of a two-component interstellar gas model

    NASA Technical Reports Server (NTRS)

    Baker, P. L.; Burton, W. B.

    1975-01-01

    High-resolution 21-cm hydrogen line observations at low galactic latitude are analyzed to determine the large-scale distribution of galactic hydrogen. Distribution parameters are found by model fitting, optical depth effects are computed using a two-component gas model suggested by the observations, and calculations are made for a one-component uniform spin-temperature gas model to show the systematic departures between this model and data obtained by incorrect treatment of the optical depth effects. Synthetic 21-cm line profiles are computed from the two-component model, and the large-scale trends of the observed emission profiles are reproduced together with the magnitude of the small-scale emission irregularities. Values are determined for the thickness of the galactic hydrogen disk between half density points, the total observed neutral hydrogen mass of the galaxy, and the central number density of the intercloud hydrogen atoms. It is shown that typical hydrogen clouds must be between 1 and 13 pc in diameter and that optical thinness exists on large-scale despite the presence of optically thin gas.

  8. Myocardial temperature distribution under cw Nd:YAG laser irradiation in in vitro and in vivo situations: theory and experiment

    NASA Astrophysics Data System (ADS)

    Splinter, Robert; Littmann, Laszlo; Tuntelder, Jan R.; Svenson, Robert H.; Chuang, Chi Hui; Tatsis, George P.; Semenov, Serguei Y.; Nanney, Glenn A.

    1995-01-01

    Tissue samples ranging from 2 to 16 mm in thickness were irradiated at 1064 nm with energies ranging from 40 to 2400 J. Coagulation lesions of in vitro and in vivo experiments were subjected to temperature profiling and submitted for histology. Irreversible damage was calculated with the damage integral formalism, following the bioheat equation solved with Monte Carlo computer light-distribution simula-tions. Numerical temperature rise and coagulation depth compared well with the in vitro results. The in vivo data required a change in the optical properties based on integrating sphere measurements for high irradiance to make the experimental and numerical data converge. The computer model has successfully solved several light-tissue interaction situations in which scattering dominates over absorption.

  9. Target-depth estimation in active sonar: Cramer-Rao bounds for a bilinear sound-speed profile.

    PubMed

    Mours, Alexis; Ioana, Cornel; Mars, Jérôme I; Josso, Nicolas F; Doisy, Yves

    2016-09-01

    This paper develops a localization method to estimate the depth of a target in the context of active sonar, at long ranges. The target depth is tactical information for both strategy and classification purposes. The Cramer-Rao lower bounds for the target position as range and depth are derived for a bilinear profile. The influence of sonar parameters on the standard deviations of the target range and depth are studied. A localization method based on ray back-propagation with a probabilistic approach is then investigated. Monte-Carlo simulations applied to a summer Mediterranean sound-speed profile are performed to evaluate the efficiency of the estimator. This method is finally validated on data in an experimental tank.

  10. Depth elemental characterization of 1D self-aligned TiO2 nanotubes using calibrated radio frequency glow discharge optical emission spectroscopy (GDOES)

    NASA Astrophysics Data System (ADS)

    Mohajernia, Shiva; Mazare, Anca; Hwang, Imgon; Gaiaschi, Sofia; Chapon, Patrick; Hildebrand, Helga; Schmuki, Patrik

    2018-06-01

    In this work we study the depth composition of anodic TiO2 nanotube layers. We use elemental depth profiling with Glow Discharge Optical Emission Spectroscopy and calibrate the results of this technique with X-ray photoelectron spectroscopy (XPS) and energy dispersive spectroscopy (EDS). We establish optimized sputtering conditions for nanotubular structures using the pulsed RF mode, which causes minimized structural damage during the depth profiling of the nanotubular structures. This allows to obtain calibrated sputter rates that account for the nanotubular "porous" morphology. Most importantly, sputter-artifact free compositional profiles of these high aspect ratio 3D structures are obtained, as well as, in combination with SEM, elegant depth sectional imaging.

  11. Distributed fiber-optic temperature sensing for hydrologic systems

    NASA Astrophysics Data System (ADS)

    Selker, John S.; ThéVenaz, Luc; Huwald, Hendrik; Mallet, Alfred; Luxemburg, Wim; van de Giesen, Nick; Stejskal, Martin; Zeman, Josef; Westhoff, Martijn; Parlange, Marc B.

    2006-12-01

    Instruments for distributed fiber-optic measurement of temperature are now available with temperature resolution of 0.01°C and spatial resolution of 1 m with temporal resolution of fractions of a minute along standard fiber-optic cables used for communication with lengths of up to 30,000 m. We discuss the spectrum of fiber-optic tools that may be employed to make these measurements, illuminating the potential and limitations of these methods in hydrologic science. There are trade-offs between precision in temperature, temporal resolution, and spatial resolution, following the square root of the number of measurements made; thus brief, short measurements are less precise than measurements taken over longer spans in time and space. Five illustrative applications demonstrate configurations where the distributed temperature sensing (DTS) approach could be used: (1) lake bottom temperatures using existing communication cables, (2) temperature profile with depth in a 1400 m deep decommissioned mine shaft, (3) air-snow interface temperature profile above a snow-covered glacier, (4) air-water interfacial temperature in a lake, and (5) temperature distribution along a first-order stream. In examples 3 and 4 it is shown that by winding the fiber around a cylinder, vertical spatial resolution of millimeters can be achieved. These tools may be of exceptional utility in observing a broad range of hydrologic processes, including evaporation, infiltration, limnology, and the local and overall energy budget spanning scales from 0.003 to 30,000 m. This range of scales corresponds well with many of the areas of greatest opportunity for discovery in hydrologic science.

  12. Physical, Chemical and Biological Data, CLIMAX I Expedition, 19 September-28 September 1968.

    DTIC Science & Technology

    1974-09-01

    Continous salinity, temperature, depth profiles (S/T/D) were taken in the late morning, near noon and early evening hours. Bottle casts for nutrients...chlorophyll-a and phaeo-pigment analyses were made in the late morning and early evening. Submarine photometer and secchi disc lowerings were made near ...September, was done at first in the center of the triangle, then for a short distance near one drogue only, and finally, between a pair of drogues

  13. Thermal Modeling on Planetary Regoliths

    NASA Technical Reports Server (NTRS)

    Hale, A. S.; Hapke, B.W.

    2002-01-01

    The thermal region of the spectrum is one of special interest in planetary science as it is the only region where planetary emission is significant. Studying how planetary surfaces emit in the thermal infrared can tell us about their physical makeup and chemical composition, as well as their temperature profile with depth. This abstract will discuss a model of thermal energy transfer in planetary regoliths on airless bodies which includes both conductive and radiative processes while including the time dependence of the solar input function.

  14. Positron annihilation at the Si/SiO2 interface

    NASA Astrophysics Data System (ADS)

    Leung, T. C.; Weinberg, Z. A.; Asoka-Kumar, P.; Nielsen, B.; Rubloff, G. W.; Lynn, K. G.

    1992-01-01

    Variable-energy positron annihilation depth-profiling has been applied to the study of the Si/SiO2 interface in Al-gate metal-oxide-semiconductor (MOS) structures. For both n- and p-type silicon under conditions of negative gate bias, the positron annihilation S-factor characteristic of the interface (Sint) is substantially modified. Temperature and annealing behavior, combined with known MOS physics, suggest strongly that Sint depends directly on holes at interface states or traps at the Si/SiO2 interface.

  15. Ultrafast eclogite formation via melting-induced overpressure

    NASA Astrophysics Data System (ADS)

    Chu, Xu; Ague, Jay J.; Podladchikov, Yury Y.; Tian, Meng

    2017-12-01

    The conventional wisdom holds that metamorphic reactions take place at pressures near-lithostatic so that the thermodynamic pressure, reflected by the mineral assemblage, is directly correlated with depth. On the other hand, recent field-based observations and geodynamic simulations suggest that heterogeneous stress and significant pressure deviations above lithostatic (overpressure) can occur in Earth's crust. Here we show that eclogite, normally interpreted to form at great depths in subduction zones and Earth's mantle, may form at much shallower depths via local overpressure generated in crustal shear zones. The eclogites studied crop out as lenses hosted by felsic paragneiss in a sheared thrust slice and represent a local pressure and temperature anomaly in the Taconic orogenic belt, southern New England. Sharply-defined chemical zones in garnet, which record ∼5 kbar pressure rise and fall accompanied by a temperature increase of 150-200 °C, demonstrate extremely short timescales of diffusion. This requires anomalously fast compression (∼500 yrs) and decompression. We use coupled phase equilibria and garnet diffusion forward modeling to fit the observed garnet profiles and test the likely P- T- t paths using a Monte Carlo-type approach, accounting for off-center sectioning of garnet. The simulation shows that a ∼5 kbar pressure increase after the temperature peak is necessary to reproduce the garnet zoning. Remarkably, this post-peak-T compression (from 9 kbar to 14 kbar) lasted only ∼500 yrs. If the compression was due to burial along a lithostatic pressure gradient, the descent speed would exceed 30 m yr-1, defying any observed or modeled subduction rates. Local overpressure in response to partial melting in a confined volume (Vrijmoed et al., 2009) caused by transient shear heating can explain the ultra-fast compression without necessitating burial to great depth.

  16. The effects of snowpack grain size on satellite passive microwave observations from the Upper Colorado River Basin

    USGS Publications Warehouse

    Josberger, E.G.; Gloersen, P.; Chang, A.; Rango, A.

    1996-01-01

    Understanding the passive microwave emissions of a snowpack, as observed by satellite sensors, requires knowledge of the snowpack properties: water equivalent, grain size, density, and stratigraphy. For the snowpack in the Upper Colorado River Basin, measurements of snow depth and water equivalent are routinely available from the U.S. Department of Agriculture, but extremely limited information is available for the other properties. To provide this information, a field program from 1984 to 1995 obtained profiles of snowpack grain size, density, and temperature near the time of maximum snow accumulation, at sites distributed across the basin. A synoptic basin-wide sampling program in 1985 showed that the snowpack exhibits consistent properties across large regions. Typically, the snowpack in the Wyoming region contains large amounts of depth hoar, with grain sizes up to 5 mm, while the snowpack in Colorado and Utah is dominated by rounded snow grains less than 2 mm in diameter. In the Wyoming region, large depth hoar crystals in shallow snowpacks yield the lowest emissivities or coldest brightness temperatures observed across the entire basin. Yearly differences in the average grain sizes result primarily from variations in the relative amount of depth hoar within the snowpack. The average grain size for the Colorado and Utah regions shows much less variation than do the grain sizes from the Wyoming region. Furthermore, the greatest amounts of depth hoar occur in the Wyoming region during 1987 and 1992, years with strong El Nin??o Southern Oscillation, but the Colorado and Utah regions do not show this behavior.

  17. Pluto's Solar Occultation from New Horizons

    NASA Astrophysics Data System (ADS)

    Young, Leslie; Kammer, Joshua; Steffl, Andrew J.; Gladstone, Randy; Summers, Michael; Strobel, Darrell F.; Hinson, David P.; Stern, S. Alan; Weaver, Harold A.; Olkin, Catherine; Ennico, Kimberly; McComas, Dave; New Horizons Atmospheres Science Theme Team

    2017-10-01

    The Alice instrument on NASA’s New Horizons spacecraft observed an ultraviolet solar occultation by Pluto's atmosphere on 2015 July 14. We derived line-of-sight abundances and local number densities for the major species (N2 and CH4) and minor hydrocarbons (C2H2, C2H4, C2H6), and line-of-sight optical depth and extinction coefficients for the haze. Our major conclusions are that (1) we confirmed temperatures in Pluto’s upper atmosphere that were colder than expected before the New Horizons flyby, with upper atmospheric temperatures near 65-68 K, and subsequently lower escape rates, (2) the lower atmosphere was very stable, placing the homopause within 12 km of the surface, (3) the abundance profiles of the “C2Hx hydrocarbons” had non-exponential density profiles that compare favorably with models for hydrocarbon production near 300-400 km and haze condensation near 200 km, and (4) haze had an extinction coefficient approximately proportional to N2 density.This work was supported by NASA’s New Horizons project.

  18. Effects of Cross-Shelf Physical Forcing on Satellite Bio-Optical Properties

    NASA Astrophysics Data System (ADS)

    Ladner, S. D.; Teague, W. J.; Mitchell, D. A.; Goode, W. A.; Gould, R. W.; Arnone, R. A.

    2005-05-01

    Our goal is to determine the effects of cross-shelf physical forcing on the optical properties in the northern Gulf of Mexico using in situ optical profiles and surface ocean color satellite images from SeaWiFS. The Naval Research Laboratory at Stennis Space Center is conducting an extensive monitoring program in the Northeast Gulf of Mexico west of the Desoto Canyon. During the Slope to Shelf Energetics and Exchange Dynamics (SEED) project, 14 bottom mounted Acoustic Doppler Current Profilers (ADCP's) were deployed from May-December 2004 along the shelf break at depths ranging from 60 to 1000 meters to improve understanding of cross-shelf exchange processes. Analysis of the May current data indicate abnormal events, including 30 cm/s off-shelf currents throughout the water column and a 3° Celsius elevation in bottom temperature. Coincident optical profiles were collected in May (absorption, scattering coefficients) and are compared with currents and physical properties (temperature, salinity). Similar subsurface abnormalities with stronger currents occurred in September during the passing of Hurricane Ivan over the mooring sites. We will show a time series of near-surface current speeds and their effect on the surface-satellite optical properties over the entire SEED sampling exercise.

  19. Depth Profilometry via Multiplexed Optical High-Coherence Interferometry

    PubMed Central

    Kazemzadeh, Farnoud; Wong, Alexander; Behr, Bradford B.; Hajian, Arsen R.

    2015-01-01

    Depth Profilometry involves the measurement of the depth profile of objects, and has significant potential for various industrial applications that benefit from non-destructive sub-surface profiling such as defect detection, corrosion assessment, and dental assessment to name a few. In this study, we investigate the feasibility of depth profilometry using an Multiplexed Optical High-coherence Interferometry MOHI instrument. The MOHI instrument utilizes the spatial coherence of a laser and the interferometric properties of light to probe the reflectivity as a function of depth of a sample. The axial and lateral resolutions, as well as imaging depth, are decoupled in the MOHI instrument. The MOHI instrument is capable of multiplexing interferometric measurements into 480 one-dimensional interferograms at a location on the sample and is built with axial and lateral resolutions of 40 μm at a maximum imaging depth of 700 μm. Preliminary results, where a piece of sand-blasted aluminum, an NBK7 glass piece, and an optical phantom were successfully probed using the MOHI instrument to produce depth profiles, demonstrate the feasibility of such an instrument for performing depth profilometry. PMID:25803289

  20. Depth profilometry via multiplexed optical high-coherence interferometry.

    PubMed

    Kazemzadeh, Farnoud; Wong, Alexander; Behr, Bradford B; Hajian, Arsen R

    2015-01-01

    Depth Profilometry involves the measurement of the depth profile of objects, and has significant potential for various industrial applications that benefit from non-destructive sub-surface profiling such as defect detection, corrosion assessment, and dental assessment to name a few. In this study, we investigate the feasibility of depth profilometry using an Multiplexed Optical High-coherence Interferometry MOHI instrument. The MOHI instrument utilizes the spatial coherence of a laser and the interferometric properties of light to probe the reflectivity as a function of depth of a sample. The axial and lateral resolutions, as well as imaging depth, are decoupled in the MOHI instrument. The MOHI instrument is capable of multiplexing interferometric measurements into 480 one-dimensional interferograms at a location on the sample and is built with axial and lateral resolutions of 40 μm at a maximum imaging depth of 700 μm. Preliminary results, where a piece of sand-blasted aluminum, an NBK7 glass piece, and an optical phantom were successfully probed using the MOHI instrument to produce depth profiles, demonstrate the feasibility of such an instrument for performing depth profilometry.

  1. High Spectral Resolution Lidar Data

    DOE Data Explorer

    Eloranta, Ed

    2004-12-01

    The HSRL provided calibrated vertical profiles of optical depth, backscatter cross section and depoloarization at a wavelength of 532 nm. Profiles were acquired at 2.5 second intervals with 7.5 meter resolution. Profiles extended from an altitude of 100 m to 30 km in clear air. The lidar penetrated to a maximum optical depth of ~ 4 under cloudy conditions. Our data contributed directly to the aims of the M-PACE experiment, providing calibrated optical depth and optical backscatter measurements which were not available from any other instrument.

  2. Spectral analysis of aeromagnetic profiles for depth estimation principles, software, and practical application

    USGS Publications Warehouse

    Sadek, H.S.; Rashad, S.M.; Blank, H.R.

    1984-01-01

    If proper account is taken of the constraints of the method, it is capable of providing depth estimates to within an accuracy of about 10 percent under suitable circumstances. The estimates are unaffected by source magnetization and are relatively insensitive to assumptions as to source shape or distribution. The validity of the method is demonstrated by analyses of synthetic profiles and profiles recorded over Harrat Rahat, Saudi Arabia, and Diyur, Egypt, where source depths have been proved by drilling.

  3. Seismic Imaging of Circumpolar Deep Water Exchange across the Shelf Break of the Antarctic Peninsula

    NASA Astrophysics Data System (ADS)

    Gunn, K.; White, N.; Larter, R. D.; Falder, M.; Caulfield, C. C. P.

    2016-02-01

    The western Antarctic Peninsula is an area of recent extreme atmospheric warming. In the adjacent ocean, there is particular interest in on-shelf movement of Circumpolar Deep Water as a possible link to changing climate by affecting ice shelf processes. Here, we investigate on-shelf intrusions using two-dimensional seismic imaging of the water column which has vertical and horizontal resolutions of 10 m. 8 seismic profiles were acquired in February 2015 using the RRS James Clark Ross. These profiles traverse the shelf break and cross two bathymetric features, the Marguerite and Biscoe troughs, which may play a role in water exchange processes. Seismic data were acquired using two Generator-Injector air guns fired every 10 s with a pressure of 2000 psi. Reflections were recorded on a 2.4 km streamer of 192 receivers spaced every 12.5 m. Observed reflections in the processed records are caused by rapid changes of temperature ( 80%) and salinity ( 20%), delineating water masses of different properties. 13 XCTDs and XBTs plus a 38 kHz echo-sounder profile were simultaneously acquired along seismic profiles and used for calibration. Preliminary results show the top of the Winter Water layer as a bright reflection at 50-120 m depth across the entire survey, corresponding to temperatures ≤ -1°C. Curved, discontinuous, eddy-like reflections, also seen on echo-sounder profiles, are attributed to modified Upper Circumpolar Deep Water with temperatures ≥ 1.34°C. A warm core eddy, 11 km long and 220 m high, is visible 2 km inland of the shelf break. Pure Upper Circumpolar Deep Water of temperatures ≥ 1.80°C is aligned with weak but discernible, lens-shaped reflections. Eddy-like structures and the overall reflective morphology yield useful insights into shelf exchange processes, suggestive of three potential mechanisms: (i) topography controlled flow; (ii) an 'ice-pump' mechanism; and (iii) mesoscale eddies.

  4. Sea surface cooling in the Northern South China Sea observed using Chinese Sea-wing Underwater Glider measurements

    NASA Astrophysics Data System (ADS)

    Qiu, C.; Mao, H.; Wu, J.

    2016-02-01

    Based on 26 days of Chinese Seawing underwater Glider measurements and satellite microwave data, we documented cooling of the upper mixed layer of the ocean in response to changes in the wind in the Northern South China Sea (NSCS) from September 19, 2014, to October 15, 2014. The Seawing underwater glider measured 177 profiles of temperature, salinity, and pressure within a 55 km נ55 km area, and reached a depth of 1000 m at a temporal resolution of 4 h. The study area experienced two cooling events, Cooling I and Cooling II, according to their timing. During Cooling I, water temperature at 1m depth (T1) decreased by 1.0°C, and the corresponding satellitederived surface winds increased locally by 4.2 m/s. During Cooling II, T1 decreased sharply by 1.7°C within a period of 4 days; sea surface winds increased by 7 m/s and covered the entire NSCS. The corresponding mixed layer depth (MLD) deepened sharply from 30 m to 60 m during Cooling II, and remained steady during Cooling I. We estimated temperature tendencies using a ML model. High resolution Seawing underwater glider measurements provided an estimation of MLD migration, allowing us to obtain the temporal entrainment rate of cool sub thermocline water. Quantitative analysis confirmed that the entrainment rate and latent heat flux were the two major components that regulated cooling of the ML, and that the Ekman advection and sensible heat flux were small.

  5. Physiological plasticity related to zonation affects hsp70 expression in the reef-building coral Pocillopora verrucosa

    PubMed Central

    Poli, Davide; Fabbri, Elena; Goffredo, Stefano; Airi, Valentina

    2017-01-01

    This study investigates for the first time the transcriptional regulation of a stress-inducible 70-kDa heat shock protein (hsp70) in the scleractinian coral Pocillopora verrucosa sampled at three locations and two depths (3 m and 12 m) in Bangka Island waters (North Sulawesi, Indonesia). Percentage of coral cover indicated reduced habitat suitability with depth and at the Tanjung Husi (TA) site, which also displayed relatively higher seawater temperatures. Expression of the P. verrucosa hsp70 transcript evaluated under field conditions followed a depth-related profile, with relatively higher expression levels in 3-m collected nubbins compared to the 12-m ones. Expression levels of metabolism-related transcripts ATP synthase and NADH dehydrogenase indicated metabolic activation of nubbins to cope with habitat conditions of the TA site at 3 m. After a 14-day acclimatization to common and fixed temperature conditions in the laboratory, corals were subjected for 7 days to an altered thermal regime, where temperature was elevated at 31°C during the light phase and returned to 28°C during the dark phase. Nubbins collected at 12 m were relatively more sensitive to thermal stress, as they significantly over-expressed the selected transcripts. Corals collected at 3 m appeared more resilient, as they showed unaffected mRNA expressions. The results indicated that local habitat conditions may influence transcription of stress-related genes in P. verrucosa. Corals exhibiting higher basal hsp70 levels may display enhanced tolerance towards environmental stressors. PMID:28199351

  6. Ion beam promoted lithium absorption in glassy polymeric carbon

    NASA Astrophysics Data System (ADS)

    Ila, D.; Zimmerman, R. L.; Jenkins, G. M.; Maleki, H.; Poker, D. B.

    1995-12-01

    Glassy Polymeric Carbon (GPC) samples prepared from a precursor possess accessible pore volume that depends on the heat treatment temperature. We have shown that lithium percolates without diffusion into the accessible pores of GPC samples immersed in a molten lithium salt bath at 700°C. Ion bombardment with 10 MeV Au atoms increases the total pore volume available for lithium occupation even for samples normally impermeable to lithium. The lithium concentration depth profile is measured using Li7(p,2α) nuclear reaction analysis. We will report on lithium percolation into GPC prepared at temperatures between 500°C and 1000°C and activated by a 10 MeV gold ion bombardment.

  7. THE TEMPERATURE OF HOT GAS IN GALAXIES AND CLUSTERS: BARYONS DANCING TO THE TUNE OF DARK MATTER

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Hansen, Steen H.; Maccio, Andrea V.; Romano-Diaz, Emilio

    2011-06-10

    The temperature profile of hot gas in galaxies and galaxy clusters is largely determined by the depth of the total gravitational potential and thereby by the dark matter (DM) distribution. We use high-resolution hydrodynamical simulations of galaxy formation to derive a surprisingly simple relation between the gas temperature and DM properties. We show that this relation holds not just for galaxy clusters but also for equilibrated and relaxed galaxies at radii beyond the central stellar-dominated region of typically a few kpc. It is then clarified how a measurement of the temperature and density of the hot gas component can leadmore » to an indirect measurement of the DM velocity anisotropy in galaxies. We also study the temperature relation for galaxy clusters in the presence of self-regulated, recurrent active galactic nuclei (AGNs), and demonstrate that this temperature relation even holds outside the inner region of {approx}30 kpc in clusters with an active AGN.« less

  8. Evaluation of Variable-Depth Liner Configurations for Increased Broadband Noise Reduction

    NASA Technical Reports Server (NTRS)

    Jones, M. G.; Watson, W. R.; Nark, D. M.; Howerton, B. M.

    2015-01-01

    This paper explores the effects of variable-depth geometry on the amount of noise reduction that can be achieved with acoustic liners. Results for two variable-depth liners tested in the NASA Langley Grazing Flow Impedance Tube demonstrate significant broadband noise reduction. An impedance prediction model is combined with two propagation codes to predict corresponding sound pressure level profiles over the length of the Grazing Flow Impedance Tube. The comparison of measured and predicted sound pressure level profiles is sufficiently favorable to support use of these tools for investigation of a number of proposed variable-depth liner configurations. Predicted sound pressure level profiles for these proposed configurations reveal a number of interesting features. Liner orientation clearly affects the sound pressure level profile over the length of the liner, but the effect on the total attenuation is less pronounced. The axial extent of attenuation at an individual frequency continues well beyond the location where the liner depth is optimally tuned to the quarter-wavelength of that frequency. The sound pressure level profile is significantly affected by the way in which variable-depth segments are distributed over the length of the liner. Given the broadband noise reduction capability for these liner configurations, further development of impedance prediction models and propagation codes specifically tuned for this application is warranted.

  9. Active layer monitoring at CALM-S site near J.G.Mendel Station, James Ross Island, eastern Antarctic Peninsula.

    PubMed

    Hrbáček, Filip; Kňažková, Michaela; Nývlt, Daniel; Láska, Kamil; Mueller, Carsten W; Ondruch, Jakub

    2017-12-01

    The Circumpolar Active Layer Monitoring - South (CALM-S) site was established in February 2014 on James Ross Island as the first CALM-S site in the eastern Antarctic Peninsula region. The site, located near Johann Gregor Mendel Station, is labelled CALM-S JGM. The grid area is gently sloped (<3°) and has an elevation of between 8 and 11ma.s.l. The lithology of the site consists of the muddy sediments of Holocene marine terrace and clayey-sandy Cretaceous sedimentary rocks, which significantly affect the texture, moisture content, and physical parameters of the ground within the grid. Our objective was to study seasonal and interannual variability of the active layer depth and thermal regime at the CALM-S site, and at two ground temperature measurement profiles, AWS-JGM and AWS-CALM, located in the grid. The mean air temperature in the period March 2013 to February 2016 reached -7.2°C. The mean ground temperature decreased with depth from -5.3°C to -5.4°C at 5cm, to -5.5°C to -5.9°C at 200cm. Active layer thickness was significantly higher at AWS-CALM and ranged between 86cm (2014/15) and 87cm (2015/16), while at AWS-JGM it reached only 51cm (2013/14) to 65cm (2015/16). The mean probed active layer depth increased from 66.4cm in 2013/14 to 78.0cm in 2014/15. Large differences were observed when comparing the minimum (51cm to 59cm) and maximum (100cm to 113cm) probed depths. The distribution of the active layer depth and differences in the thermal regime of the uppermost layer of permafrost at CALM-S JGM clearly show the effect of different lithological properties on the two lithologically distinct parts of the grid. Copyright © 2017 Elsevier B.V. All rights reserved.

  10. Climate-induced changes in lake ecosystem structure inferred from coupled neo- and paleoecological approaches

    USGS Publications Warehouse

    Saros, Jasmine E.; Stone, Jeffery R.; Pederson, Gregory T.; Slemmons, Krista; Spanbauer, Trisha; Schliep, Anna; Cahl, Douglas; Williamson, Craig E.; Engstrom, Daniel R.

    2015-01-01

    Over the 20th century, surface water temperatures have increased in many lake ecosystems around the world, but long-term trends in the vertical thermal structure of lakes remain unclear, despite the strong control that thermal stratification exerts on the biological response of lakes to climate change. Here we used both neo- and paleoecological approaches to develop a fossil-based inference model for lake mixing depths and thereby refine understanding of lake thermal structure change. We focused on three common planktonic diatom taxa, the distributions of which previous research suggests might be affected by mixing depth. Comparative lake surveys and growth rate experiments revealed that these species respond to lake thermal structure when nitrogen is sufficient, with species optima ranging from shallower to deeper mixing depths. The diatom-based mixing depth model was applied to sedimentary diatom profiles extending back to 1750 AD in two lakes with moderate nitrate concentrations but differing climate settings. Thermal reconstructions were consistent with expected changes, with shallower mixing depths inferred for an alpine lake where treeline has advanced, and deeper mixing depths inferred for a boreal lake where wind strength has increased. The inference model developed here provides a new tool to expand and refine understanding of climate-induced changes in lake ecosystems.

  11. The radiative versus entraining effects of overlying humidity on the Lagrangian evolution of subtropical stratocumulus

    NASA Astrophysics Data System (ADS)

    Eastman, R. M.; Wood, R.

    2017-12-01

    This study observes the 24-hour Lagrangian evolution of stratocumulus cloud amount and PBL depth in four eastern subtropical ocean basins: the NE Pacific, SE Pacific, SE Atlantic, and E Indian. Nearly 170,000 trajectories are computed using the 2-D wind field at 925mb and cloud properties are sampled along these trajectories twice daily as the A-Train satellite constellation passes overhead. Concurrent measurements of the overlying humidity and temperature profiles are interpolated from the ERA-Interim reanalysis grids. Cloud properties are sampled by MODIS and a measure of planetary boundary layer (PBL) depth is calculated using MODIS cloud top temperatures, CALIPSO lidar observations of cloud top heights, and ERA-Interim sea surface temperatures. High humidity overlying the PBL can reduce cloud top cooling by counteracting radiative cooling and by reducing evaporation within the entrainment zone. Both of these effects can slow the entrainment rate and change cloud evolution. To discern which effect is more important the humidity profile is broken into two distinct components: the specific humidity directly above the inversion, which is entraining into the boundary layer, and the column of specific humidity above that layer, which is radiatively interacting with the PBL, but not directly entraining. These two measures of humidity are compared in the Lagrangian framework. Results suggest that humidity above the PBL has a stronger effect on the Lagrangian PBL deepening rate compared to lower tropospheric stability. A comparison of PBL deepening rates driven by the entraining humidity versus the radiating humidity shows that the radiative effects of overlying humidity are dominant with respect to entrainment. However, the entraining effects of humidity are more important in prolonging cloud lifetime.

  12. Effect of thermal annealing on the redistribution of alkali metals in Cu(In,Ga)Se 2 solar cells on glass substrate

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Kamikawa, Yukiko; Nishinaga, Jiro; Ishizuka, Shogo

    The precise control of alkali-metal concentrations in Cu(In,Ga)Se 2 (CIGS) solar cells via post deposition treatment (PDT) has recently attracted attention. When PDT is performed at an elevated temperature, an accompanying annealing effect is expected. Here, we investigate how thermal annealing affects the redistribution of alkali metals in CIGS solar cells on glass substrates and the properties of the solar cells. In addition, we investigate the origin of non-homogeneous alkali-metal depth profiles that are typical of CIGS grown using a three-stage process. In particular, we use secondary-ion mass spectrometry measurements of the ion concentration as a function of distance frommore » the CIGS surface to investigate the impact of thermal annealing on the distribution of alkali metals (Na, Ka, and Rb) and constituent elements (Ga and In) in the CIGS absorbers. We find that the depth profiles of the alkali metals strongly reflect the density of sites that tend to accommodate alkali metals, i.e., vacancies. Annealing at elevated temperature caused a redistribution of the alkali metals. The thermal-diffusion kinetics of alkali metals depends strongly on the species involved. We introduced low flux potassium fluoride (KF) to study a side effect of KF-PDT, i.e., Na removal from CIGS, separately from its predominant effects such as surface modification. When sufficient amounts of Na are supplied from the soda lime glass via annealing at an elevated temperature, the negative effect was not apparent. Conversely, when the Na supply was not sufficient, it caused a deterioration of the photovoltaic properties.« less

  13. Stochastic Inversion of Geomagnetic Observatory Data Including Rigorous Treatment of the Ocean Induction Effect With Implications for Transition Zone Water Content and Thermal Structure

    NASA Astrophysics Data System (ADS)

    Munch, F. D.; Grayver, A. V.; Kuvshinov, A.; Khan, A.

    2018-01-01

    In this paper we estimate and invert local electromagnetic (EM) sounding data for 1-D conductivity profiles in the presence of nonuniform oceans and continents to most rigorously account for the ocean induction effect that is known to strongly influence coastal observatories. We consider a new set of high-quality time series of geomagnetic observatory data, including hitherto unused data from island observatories installed over the last decade. The EM sounding data are inverted in the period range 3-85 days using stochastic optimization and model exploration techniques to provide estimates of model range and uncertainty. The inverted conductivity profiles are best constrained in the depth range 400-1,400 km and reveal significant lateral variations between 400 km and 1,000 km depth. To interpret the inverted conductivity anomalies in terms of water content and temperature, we combine laboratory-measured electrical conductivity of mantle minerals with phase equilibrium computations. Based on this procedure, relatively low temperatures (1200-1350°C) are observed in the transition zone (TZ) underneath stations located in Southern Australia, Southern Europe, Northern Africa, and North America. In contrast, higher temperatures (1400-1500°C) are inferred beneath observatories on islands, Northeast Asia, and central Australia. TZ water content beneath European and African stations is ˜0.05-0.1 wt %, whereas higher water contents (˜0.5-1 wt %) are inferred underneath North America, Asia, and Southern Australia. Comparison of the inverted water contents with laboratory-constrained water storage capacities suggests the presence of melt in or around the TZ underneath four geomagnetic observatories in North America and Northeast Asia.

  14. Effect of thermal annealing on the redistribution of alkali metals in Cu(In,Ga)Se 2 solar cells on glass substrate

    DOE PAGES

    Kamikawa, Yukiko; Nishinaga, Jiro; Ishizuka, Shogo; ...

    2018-03-07

    The precise control of alkali-metal concentrations in Cu(In,Ga)Se 2 (CIGS) solar cells via post deposition treatment (PDT) has recently attracted attention. When PDT is performed at an elevated temperature, an accompanying annealing effect is expected. Here, we investigate how thermal annealing affects the redistribution of alkali metals in CIGS solar cells on glass substrates and the properties of the solar cells. In addition, we investigate the origin of non-homogeneous alkali-metal depth profiles that are typical of CIGS grown using a three-stage process. In particular, we use secondary-ion mass spectrometry measurements of the ion concentration as a function of distance frommore » the CIGS surface to investigate the impact of thermal annealing on the distribution of alkali metals (Na, Ka, and Rb) and constituent elements (Ga and In) in the CIGS absorbers. We find that the depth profiles of the alkali metals strongly reflect the density of sites that tend to accommodate alkali metals, i.e., vacancies. Annealing at elevated temperature caused a redistribution of the alkali metals. The thermal-diffusion kinetics of alkali metals depends strongly on the species involved. We introduced low flux potassium fluoride (KF) to study a side effect of KF-PDT, i.e., Na removal from CIGS, separately from its predominant effects such as surface modification. When sufficient amounts of Na are supplied from the soda lime glass via annealing at an elevated temperature, the negative effect was not apparent. Conversely, when the Na supply was not sufficient, it caused a deterioration of the photovoltaic properties.« less

  15. Quantitative detection of caffeine in human skin by confocal Raman spectroscopy--A systematic in vitro validation study.

    PubMed

    Franzen, Lutz; Anderski, Juliane; Windbergs, Maike

    2015-09-01

    For rational development and evaluation of dermal drug delivery, the knowledge of rate and extent of substance penetration into the human skin is essential. However, current analytical procedures are destructive, labor intense and lack a defined spatial resolution. In this context, confocal Raman microscopy bares the potential to overcome current limitations in drug depth profiling. Confocal Raman microscopy already proved its suitability for the acquisition of qualitative penetration profiles, but a comprehensive investigation regarding its suitability for quantitative measurements inside the human skin is still missing. In this work, we present a systematic validation study to deploy confocal Raman microscopy for quantitative drug depth profiling in human skin. After we validated our Raman microscopic setup, we successfully established an experimental procedure that allows correlating the Raman signal of a model drug with its controlled concentration in human skin. To overcome current drawbacks in drug depth profiling, we evaluated different modes of peak correlation for quantitative Raman measurements and offer a suitable operating procedure for quantitative drug depth profiling in human skin. In conclusion, we successfully demonstrate the potential of confocal Raman microscopy for quantitative drug depth profiling in human skin as valuable alternative to destructive state-of-the-art techniques. Copyright © 2015 Elsevier B.V. All rights reserved.

  16. A physically based algorithm for non-blackbody correction of the cloud top temperature for the convective clouds

    NASA Astrophysics Data System (ADS)

    Wang, C.; Luo, Z. J.; Chen, X.; Zeng, X.; Tao, W.; Huang, X.

    2012-12-01

    Cloud top temperature is a key parameter to retrieval in the remote sensing of convective clouds. Passive remote sensing cannot directly measure the temperature at the cloud tops. Here we explore a synergistic way of estimating cloud top temperature by making use of the simultaneous passive and active remote sensing of clouds (in this case, CloudSat and MODIS). Weighting function of the MODIS 11μm band is explicitly calculated by feeding cloud hydrometer profiles from CloudSat retrievals and temperature and humidity profiles based on ECMWF ERA-interim reanalysis into a radiation transfer model. Among 19,699 tropical deep convective clouds observed by the CloudSat in 2008, the averaged effective emission level (EEL, where the weighting function attains its maximum) is at optical depth 0.91 with a standard deviation of 0.33. Furthermore, the vertical gradient of CloudSat radar reflectivity, an indicator of the fuzziness of convective cloud top, is linearly proportional to, d_{CTH-EEL}, the distance between the EEL of 11μm channel and cloud top height (CTH) determined by the CloudSat when d_{CTH-EEL}<0.6km. Beyond 0.6km, the distance has little sensitivity to the vertical gradient of CloudSat radar reflectivity. Based on these findings, we derive a formula between the fuzziness in the cloud top region, which is measurable by CloudSat, and the MODIS 11μm brightness temperature assuming that the difference between effective emission temperature and the 11μm brightness temperature is proportional to the cloud top fuzziness. This formula is verified using the simulated deep convective cloud profiles by the Goddard Cumulus Ensemble model. We further discuss the application of this formula in estimating cloud top buoyancy as well as the error characteristics of the radiative calculation within such deep-convective clouds.

  17. Temperature Inversions and Nighttime Convection in the Martian Tropics

    NASA Astrophysics Data System (ADS)

    Hinson, D. P.; Spiga, A.; Lewis, S.; Tellmann, S.; Paetzold, M.; Asmar, S. W.; Häusler, B.

    2013-12-01

    We are using radio occultation measurements from Mars Express, Mars Reconnaissance Orbiter, and Mars Global Surveyor to characterize the diurnal cycle in the lowest scale height above the surface. We focus on northern spring and summer, using observations from 4 Martian years at local times of 4-5 and 15-17 h. We supplement the observations with results obtained from large-eddy simulations and through data assimilation by the UK spectral version of the LMD Mars Global Circulation Model. We previously investigated the depth of the daytime convective boundary layer (CBL) and its variations with surface elevation and surface properties. We are now examining unusual aspects of the temperature structure observed at night. Most important, predawn profiles in the Tharsis region contain an unexpected layer of neutral static stability at pressures of 200-300 Pa with a depth of 4-5 km. The mixed layer is bounded above by a midlevel temperature inversion and below by another strong inversion adjacent to the surface. The sharp temperature minimum at the base of the midlevel inversion suggests the presence of a thin water ice cloud layer, with the further implication that radiative cooling at cloud level can induce convective activity at lower altitudes. Conversely, nighttime profiles in Amazonis show no sign of a midlevel inversion or a detached mixed layer. These regional variations in the nighttime temperature structure appear to arise in part from large-scale variations in topography, which have several notable effects. First, the CBL is much deeper in the Tharsis region than in Amazonis, owing to a roughly 6-km difference in surface elevation. Second, large-eddy simulations show that daytime convection is not only deeper above Tharsis but also considerably more intense than it is in Amazonis. Finally, the daytime surface temperatures are comparable in the two regions, so that Tharsis acts as an elevated heat source throughout the CBL. These topographic effects are expected to enhance the vertical mixing of water vapor above elevated terrain, which might lead to the formation and regional confinement of nighttime clouds.

  18. Direct depth distribution measurement of deuterium in bulk tungsten exposed to high-flux plasma

    DOE PAGES

    Taylor, Chase N.; Shimada, M.

    2017-05-08

    Understanding tritium retention and permeation in plasma-facing components is critical for fusion safety and fuel cycle control. Glow discharge optical emission spectroscopy (GD-OES) is shown to be an effective tool to reveal the depth profile of deuterium in tungsten. Results confirm the detection of deuterium. Furthermore, a ~46 µm depth profile revealed that the deuterium content decreased precipitously in the first 7 µm, and detectable amounts were observed to depths in excess of 20 µm. The large probing depth of GD-OES (up to 100s of µm) enables studies not previously accessible to the more conventional techniques for investigating deuterium retention.more » Of particular applicability is the use of GD-OES to measure the depth profile for experiments where high diffusion is expected: deuterium retention in neutron irradiated materials, and ultra-high deuterium fluences in burning plasma environment.« less

  19. Direct depth distribution measurement of deuterium in bulk tungsten exposed to high-flux plasma

    NASA Astrophysics Data System (ADS)

    Taylor, C. N.; Shimada, M.

    2017-05-01

    Understanding tritium retention and permeation in plasma-facing components is critical for fusion safety and fuel cycle control. Glow discharge optical emission spectroscopy (GD-OES) is shown to be an effective tool to reveal the depth profile of deuterium in tungsten. Results confirm the detection of deuterium. A ˜46 μm depth profile revealed that the deuterium content decreased precipitously in the first 7 μm, and detectable amounts were observed to depths in excess of 20 μm. The large probing depth of GD-OES (up to 100s of μm) enables studies not previously accessible to the more conventional techniques for investigating deuterium retention. Of particular applicability is the use of GD-OES to measure the depth profile for experiments where high deuterium concentration in the bulk material is expected: deuterium retention in neutron irradiated materials, and ultra-high deuterium fluences in burning plasma environment.

  20. Depth profiling of ion-induced damage in D9 alloy using X-ray diffraction

    NASA Astrophysics Data System (ADS)

    Dey, S.; Gayathri, N.; Mukherjee, P.

    2018-04-01

    The ion-induced depthwise damage profile in 35 MeV α-irradiated D9 alloy samples with doses of 5 × 1015 He2+/cm2, 6.4 × 1016 He2+/cm2 and 2 × 1017 He2+/cm2 has been assessed using X-ray diffraction technique. The microstructural characterisation has been done along the depth from beyond the stopping region (peak damage region) to the homogeneous damage region (surface) as simulated from SRIM. The parameters such as domain size and microstrain have been evaluated using two different X-ray diffraction line profile analysis techniques. The results indicate that at low dose the damage profile shows a prominent variation as a function of depth but, with increasing dose, it becomes more homogeneous along the depth. This suggests that enhanced defect diffusion and their annihilation in pre-existing and newly formed sinks play a significant role in deciding the final microstructure of the irradiated sample as a function of depth.

  1. Time-of-flight secondary ion mass spectrometry studies of cluster ion analysis for semiconductors and diffusion of manganese in gallium arsenide at low temperatures

    NASA Astrophysics Data System (ADS)

    Goacher, Robyn Elizabeth

    Secondary Ion Mass Spectrometry (SIMS) is an established method for the quantitative analysis of dopants in semiconductors. The quasi-parallel mass acquisition of Time-of-Flight SIMS, along with the development of polyatomic primary ions, have rapidly increased the use of SIMS for analysis of organic and biological specimens. However, the advantages and disadvantages of using cluster primary ions for quantitative analysis of inorganic materials are not clear. The research described in this dissertation investigates the consequences of using polyatomic primary ions for the analysis of inorganic compounds in ToF-SIMS. Furthermore, the diffusion of Mn in GaAs, which is important in Spintronic material applications such as spin injection, is also studied by quantitative ToF-SIMS depth profiling. In the first portion of this work, it was discovered that primary ion bombardment of pre-sputtered compound semiconductors GaAs and InP for the purpose of spectral analysis resulted in the formation of cluster secondary ions, as well as atomic secondary ions (Chapter 2). In particular, bombardment using a cluster primary ion such as Bi3q + or C60q+ resulted in higher yields of high-mass cluster secondary ions. These cluster secondary ions did not have bulk stoichiometry, "non-stoichiometric", in contrast to the paradigm of stoichiometric cluster ions generated from salts. This is attributed to the covalent bonding of the compound semiconductors, as well as to preferential sputtering. The utility of high-mass cluster secondary ions in depth profiling is also discussed. Relative sensitivity factors (RSFs) calculated for ion-implanted Fe and Mn samples in GaAs also exhibit differences based on whether monatomic or polyatomic primary ions are utilized (Chapter 3). These RSFs are important for the quantitative conversion of intensity to concentration. When Bi 32+ primary ions are used for analysis instead of Bi + primary ions, there is a significantly higher proportion of Mn and Fe ions present in the spectra, as referenced to the matrix species. The magnitude of this effect differs depending on the sputtering ion, Cs or C60. The use of C60cluster primary ions for depth profiling of GaAs is also investigated (Chapter 4). In particular, for quantitative depth profiling, parameters such as depth resolution, ion and sputter yields, and relative sensitivity factors are pertinent to profiling thin layered structures quantitatively and quickly. C60 sputtering is compared to Cs sputtering in all of these aspects. It is found that 10 keV C60+ is advantageous for the analysis of metals (such as Au contacts on Si) but that previously reported roughness problems prohibit successful analysis in Si. For Al delta layers and quantum wells in GaAs, C60 q+ sputtering induced very little roughness in the sample, and resulted in high ion yields and excellent signal-to-noise as compared to Cs+ sputtering. However, the depth resolution of C60 is at best equivalent to 1 keV Cs+ and does not extend into the sub 2-nm range. Furthermore, C60 sputtering results in significant carbon implantation. In the second portion of this work, quantitative ToF-SIMS depth profiling was used to evaluate the diffusion of Mn into GaAs. Samples were prepared by Molecular Beam Epitaxy in the department of Physics. Mn diffusion from MnAs was investigated first, and Mn diffusion from layered epitaxial structures of GaAs / Ga1-xMnxAs / GaAs was investigated second. Diffusion experiments were conducted by annealing portions of the samples in sealed glass ampoules at low temperatures (200-400°C). Different sputtering rates were measured for MnAs and GaAs and the measured depth profiles were corrected for these effects. RSFs measured for Mn ion-implanted standards were used to calibrate the intensity scale. For diffusion from MnAs, thin MnAs layers resulted in no measurable changes except in the surface transient. For thick MnAs layers, it was determined that substantial loss of As occurred at 400°C, resulting in severe sample roughening, which inhibited proper SIMS analysis. Results for the diffusion of Mn out of a thick buried layer of Ga1-xMnxAs show that annealing induces diffusion of Mn species from the Ga1-xMnxAs layer into the neighboring GaAs with an activation energy of 0.69+/-0.09 eV. This results in doping of the GaAs layer, which is detrimental to spin injection for Spintronics devices.

  2. Quantitative operando visualization of the energy band depth profile in solar cells.

    PubMed

    Chen, Qi; Mao, Lin; Li, Yaowen; Kong, Tao; Wu, Na; Ma, Changqi; Bai, Sai; Jin, Yizheng; Wu, Dan; Lu, Wei; Wang, Bing; Chen, Liwei

    2015-07-13

    The energy band alignment in solar cell devices is critically important because it largely governs elementary photovoltaic processes, such as the generation, separation, transport, recombination and collection of charge carriers. Despite the expenditure of considerable effort, the measurement of energy band depth profiles across multiple layers has been extremely challenging, especially for operando devices. Here we present direct visualization of the surface potential depth profile over the cross-sections of operando organic photovoltaic devices using scanning Kelvin probe microscopy. The convolution effect due to finite tip size and cantilever beam crosstalk has previously prohibited quantitative interpretation of scanning Kelvin probe microscopy-measured surface potential depth profiles. We develop a bias voltage-compensation method to address this critical problem and obtain quantitatively accurate measurements of the open-circuit voltage, built-in potential and electrode potential difference.

  3. Quantitative operando visualization of the energy band depth profile in solar cells

    PubMed Central

    Chen, Qi; Mao, Lin; Li, Yaowen; Kong, Tao; Wu, Na; Ma, Changqi; Bai, Sai; Jin, Yizheng; Wu, Dan; Lu, Wei; Wang, Bing; Chen, Liwei

    2015-01-01

    The energy band alignment in solar cell devices is critically important because it largely governs elementary photovoltaic processes, such as the generation, separation, transport, recombination and collection of charge carriers. Despite the expenditure of considerable effort, the measurement of energy band depth profiles across multiple layers has been extremely challenging, especially for operando devices. Here we present direct visualization of the surface potential depth profile over the cross-sections of operando organic photovoltaic devices using scanning Kelvin probe microscopy. The convolution effect due to finite tip size and cantilever beam crosstalk has previously prohibited quantitative interpretation of scanning Kelvin probe microscopy-measured surface potential depth profiles. We develop a bias voltage-compensation method to address this critical problem and obtain quantitatively accurate measurements of the open-circuit voltage, built-in potential and electrode potential difference. PMID:26166580

  4. The role of mass removal mechanisms in the onset of ns-laser induced plasma formation

    NASA Astrophysics Data System (ADS)

    Autrique, D.; Clair, G.; L'Hermite, D.; Alexiades, V.; Bogaerts, A.; Rethfeld, B.

    2013-07-01

    The present study focuses on the role of mass removal mechanisms in ns-laser ablation. A copper sample is placed in argon, initially set at standard pressure and temperature. Calculations are performed for a 6 ns laser pulse with a wavelength of 532 nm and laser fluences up to 10 J/cm2. The transient behavior in and above the copper target is described by a hydrodynamic model. Transmission profiles and ablation depths are compared with experimental results and similar trends are found. Our calculations reveal an interesting self-inhibiting mechanism: volumetric mass removal in the supercritical region triggers plasma shielding and therefore stops proceeding. This self-limiting process indicates that volumetric mass removal does not necessarily result in large ablation depths.

  5. On the influence of recrystallization on snow fabric and microstructure: study of a snow profile in Central East Antarctica

    NASA Astrophysics Data System (ADS)

    Calonne, Neige; Schneebeli, Martin; Montagnat, Maurine; Matzl, Margret

    2016-04-01

    Temperature gradient metamorphism affects the Antarctic snowpack up to 5 meters depth, which lead to a recrystallization of the ice grains by sublimation of ice and deposition of water vapor. By this way, it is well known that the snow microstructure evolves (geometrical changes). Also, a recent study shows an evolution of the snow fabric, based on a cold laboratory experiment. Both fabric and microstructure are required to better understand mechanical behavior and densification of snow, firn and ice, given polar climatology. The fabric of firn and ice has been extensively investigated, but the publications by Stephenson (1967, 1968) are to our knowledge the only ones describing the snow fabric in Antarctica. In this context, our work focuses on snow microstructure and fabric in the first meters depth of the Antarctic ice sheet, where temperature gradients driven recrystallization occurs. Accurate details of the snow microstructure are observed using micro-computed tomography. Snow fabrics were measured at various depths from thin sections of impregnated snow with an Automatic Ice Texture Analyzer (AITA). A definite relationship between microstructure and fabric is found and highlights the influence of metamorphism on both properties. Our results also show that the metamorphism enhances the differences between the snow layers properties. Our work stresses the significant and complex evolution of snow properties in the upper meters of the ice sheet and opens the question of how these layer properties will evolve at depth and may influence the densification.

  6. Genetic Algorithm for Opto-thermal Skin Hydration Depth Profiling Measurements

    NASA Astrophysics Data System (ADS)

    Cui, Y.; Xiao, Perry; Imhof, R. E.

    2013-09-01

    Stratum corneum is the outermost skin layer, and the water content in stratum corneum plays a key role in skin cosmetic properties as well as skin barrier functions. However, to measure the water content, especially the water concentration depth profile, within stratum corneum is very difficult. Opto-thermal emission radiometry, or OTTER, is a promising technique that can be used for such measurements. In this paper, a study on stratum corneum hydration depth profiling by using a genetic algorithm (GA) is presented. The pros and cons of a GA compared against other inverse algorithms such as neural networks, maximum entropy, conjugate gradient, and singular value decomposition will be discussed first. Then, it will be shown how to use existing knowledge to optimize a GA for analyzing the opto-thermal signals. Finally, these latest GA results on hydration depth profiling of stratum corneum under different conditions, as well as on the penetration profiles of externally applied solvents, will be shown.

  7. He, U, and Th Depth Profiling of Apatite and Zircon Using Laser Ablation Noble Gas Mass Spectrometry and SIMS

    NASA Astrophysics Data System (ADS)

    Monteleone, B. D.; van Soest, M. C.; Hodges, K. V.; Hervig, R.; Boyce, J. W.

    2008-12-01

    Conventional (U-Th)/He thermochronology utilizes single or multiple grain analyses of U- and Th-bearing minerals such as apatite and zircon and does not allow for assessment of spatial variation in concentration of He, U, or Th within individual crystals. As such, age calculation and interpretation require assumptions regarding 4He loss through alpha ejection, diffusive redistribution of 4He, and U and Th distribution as an initial condition for these processes. Although models have been developed to predict 4He diffusion parameters, correct for the effect of alpha ejection on calculated cooling ages, and account for the effect of U and Th zonation within apatite and zircon, measurements of 4He, U, and Th distribution have not been combined within a single crystal. We apply ArF excimer laser ablation, combined with noble gas mass spectrometry, to obtain depth profiles within apatite and zircon crystals in order to assess variations in 4He concentration with depth. Our initial results from pre-cut, pre-heated slabs of Durango apatite, each subjected to different T-t schedules, suggest a general agreement of 4He profiles with those predicted by theoretical diffusion models (Farley, 2000). Depth profiles through unpolished grains give reproducible alpha ejection profiles in Durango apatite that deviate from alpha ejection profiles predicted for ideal, homogenous crystals. SIMS depth profiling utilizes an O2 primary beam capable of sputtering tens of microns and measuring sub-micron resolution variation in [U], [Th], and [Sm]. Preliminary results suggest that sufficient [U] and [Th] zonation is present in Durango apatite to influence the form of the 4He alpha ejection profile. Future work will assess the influence of measured [U] and [Th] zonation on previously measured 4He depth profiles. Farley, K.A., 2000. Helium diffusion from apatite; general behavior as illustrated by Durango fluorapatite. J. Geophys. Res., B Solid Earth Planets 105 (2), 2903-2914.

  8. Seismic velocity uncertainties and their effect on geothermal predictions: A case study

    NASA Astrophysics Data System (ADS)

    Rabbel, Wolfgang; Köhn, Daniel; Bahadur Motra, Hem; Niederau, Jan; Thorwart, Martin; Wuttke, Frank; Descramble Working Group

    2017-04-01

    Geothermal exploration relies in large parts on geophysical subsurface models derived from seismic reflection profiling. These models are the framework of hydro-geothermal modeling, which further requires estimating thermal and hydraulic parameters to be attributed to the seismic strata. All petrophysical and structural properties involved in this process can be determined only with limited accuracy and thus impose uncertainties onto the resulting model predictions of temperature-depth profiles and hydraulic flow, too. In the present study we analyze sources and effects of uncertainties of the seismic velocity field, which translate directly into depth uncertainties of the hydraulically and thermally relevant horizons. Geological sources of these uncertainties are subsurface heterogeneity and seismic anisotropy, methodical sources are limitations in spread length and physical resolution. We demonstrate these effects using data of the EU-Horizon 2020 project DESCRAMBLE investigating a shallow super-critical geothermal reservoir in the Larderello area. The study is based on 2D- and 3D seismic reflection data and laboratory measurements on representative rock samples under simulated in-situ conditions. The rock samples consistently show P-wave anisotropy values of 10-20% order of magnitude. However, the uncertainty of layer depths induced by anisotropy is likely to be lower depending on the accuracy, with which the spatial orientation of bedding planes can be determined from the seismic reflection images.

  9. Interpretation of TOF SIMS depth profiles from ultrashallow high-k dielectric stacks assisted by hybrid collisional computer simulation

    NASA Astrophysics Data System (ADS)

    Ignatova, V. A.; Möller, W.; Conard, T.; Vandervorst, W.; Gijbels, R.

    2005-06-01

    The TRIDYN collisional computer simulation has been modified to account for emission of ionic species and molecules during sputter depth profiling, by introducing a power law dependence of the ion yield as a function of the oxygen surface concentration and by modelling the sputtering of monoxide molecules. The results are compared to experimental data obtained with dual beam TOF SIMS depth profiling of ZrO2/SiO2/Si high-k dielectric stacks with thicknesses of the SiO2 interlayer of 0.5, 1, and 1.5 nm. Reasonable agreement between the experiment and the computer simulation is obtained for most of the experimental features, demonstrating the effects of ion-induced atomic relocation, i.e., atomic mixing and recoil implantation, and preferential sputtering. The depth scale of the obtained profiles is significantly distorted by recoil implantation and the depth-dependent ionization factor. A pronounced double-peak structure in the experimental profiles related to Zr is not explained by the computer simulation, and is attributed to ion-induced bond breaking and diffusion, followed by a decoration of the interfaces by either mobile Zr or O.

  10. A Trip Through the Virtual Ocean: Understanding Basic Oceanic Process Using Real Data and Collaborative Learning

    NASA Astrophysics Data System (ADS)

    Hastings, D. W.

    2012-12-01

    How can we effectively teach undergraduates the fundamentals of physical, chemical and biological processes in the ocean? Understanding physical circulation and biogeochemical processes is essential, yet it can be difficult for an undergraduate to easily grasp important concepts such as using temperature and salinity as conservative tracers, nutrient distribution, ageing of water masses, and thermocline variability. Like many other topics, it is best learned not in a lecture setting, but working with real data: plotting values, making predictions, and making mistakes. Part I: Using temperature and salinity values from any location in the world ocean (World Ocean Atlas), combined with an excellent user interface (http://ferret.pmel.noaa.gov), students are asked to answer a series of specific questions related to ocean circulation. Using established temperature and salinity values to characterize different water masses, students are able to identify various water masses and gain insight to physical circulation processes. Questions related to ocean circulation include: How far south and at what depth does NADW extend into the S. Atlantic? Is deep water formed in the North Pacific? How and why does the depth of the thermocline vary with latitude in the Atlantic Ocean? How deep does the Mediterranean Water descend as it leaves the Straits of Gibraltar? How far into the Atlantic can you see the influence of the Amazon River? Is there any Antarctic Bottom Water in the North Pacific? Collaborating with another student typically leads to increased engagement. Especially in large lecture settings, where one teacher is not able to address student questions or concerns, working in pairs or in groups of three is best. Part II: Using the same web-based viewer and data set students are subsequently assigned one oceanic property (phosphate, nitrate, silicate, O2, or AOU) and asked to construct three different plots: 1) vertical depth profile at one location; 2) latitude vs. depth at 20°W; and 3) a latitude vs. longitude at 4,000 m depth in the entire ocean. Students do this work at home, and come to class prepared with hypotheses that explain variations of their variable observed in their figures. Nutrients, for example, are typically depleted in the surface ocean, increase at intermediate depths, and then typically decrease in deep water. How do oceanic processes drive these variations? In the context of the other variables, and with the help of other group members, they typically develop an understanding of surface productivity, respiration of organic matter in deeper waters, upwelling of deeper water, ocean circulation, insolation, evaporation, precipitation, and temperature dependence of gas solubility. Students then prepare a written explanation to accompany the plots. Cartoon-like depictions of nutrient profiles typically presented in introductory texts have their place, but they lack the complexity inherent in real data. The objective is to mimic the excitement of discovery and the challenge of developing a hypothesis to explain existing data. The ability to develop viable hypotheses to explain real data with real variability are what motivate and inspire many scientists. How can we expect to motivate and inspire students with lackluster descriptions of ocean processes?

  11. Advances of a Brillouin Scattering Lidar System for the Detection of Temperature Profiles in the Ocean: Laboratory Measurements and Field Test

    NASA Astrophysics Data System (ADS)

    Walther, T.; Rupp, D.; Friman, S.; Trees, C.; Fournier, G.

    2016-02-01

    Recently we have demonstrated the feasibility of remotely measuring temperature profiles in water under a laboratory environment employing our real-time Brillouin Scattering LIDAR (BSL) system. The working principle is based on the frequency and time resolved detection of the backscattered spontaneous Brillouin signal of a short light pulse fired into the ocean. The light source consists of a frequency-doubled fiber-amplified External Cavity Diode Laser (ECDL) providing high-energy, Fourier transform-limited laser pulses in the green spectral range. The Brillouin shift is detected with high accuracy (low uncertainty) by employing an edge filter based on an Excited State Faraday Anomalous Dispersion Optical Filter (ESFADOF). Time-resolution allows for the depth resolution and the frequency resolved shift is proportional to the speed of sound. Thus, the temperature profile can be extracted from the measurements. In our laboratory setup we were able to resolve water temperatures with a mean accuracy of up to 0.07 oC and a spatial resolution of 1 m depending on the amount of averaging. In order to prepare the system for a first field test under realistic conditions on the coast of the Mediterranean at CMRE in La Spezia, almost all of the components have been upgraded. This first test is planned for November 2015. We will present the above mentioned measurements, details about the upgrades and report on our experiences during this maritime field test.Ultimately, the plan is to operate the system from a mobile platform, e.g., a helicopter or vessel, in order to precisely determine the temperature of the surface mixed layer of the ocean with high spatial resolution.

  12. Lithospheric structure of the Eastern Iranian plateau from integrated geophysical modeling: A transect from Makran to the Turan platform

    NASA Astrophysics Data System (ADS)

    Entezar-Saadat, Vahid; Motavalli-Anbaran, Seyed-Hani; Zeyen, Hermann

    2017-05-01

    We present a 2D profile of density and temperature distribution in the lithosphere across Iran along a more than 1600 km long profile extending from the Oman Gulf in the South to the Kopeh-Dagh and the Turan platform in the North. Gravity, geoid, topography and surface heat flow data were used for modeling, assuming local isostatic equilibrium. As much as possible, crustal structure has been constrained by seismic data. Crustal thickening is found under the Taftan-Bazman volcanic-arc (up to 47 km), under the Binalud foreland (∼54 km) and beneath the Kopeh-Dagh mountains (up to 50 km) whereas thin crust has been obtained under the Oman Gulf (20 km). Moho depth under the Lut block and the Turan platform is about 40 km. The lithospheric thickness is ∼90 km under the Oman Gulf and increases slightly until the Jazmourian depression. Then the lithospheric-asthenospheric boundary (LAB) bends significantly and sinks to ∼260 km under the Taftan-Bazman volcanic-arc. The LAB depth is about 190 km beneath the Lut block. A slight increase of LAB depth under the Binalud foreland towards the North may indicate a suture zone. Under the Turan platform, the LAB depth reaches ∼210 km. We also modeled two possible positions of the deep suture zone in NE Iran (along the main Kopeh-Dagh fault or along the Atrak River) and concluded that, when the suture zone is along the Atrak River, we obtained the better fit between calculated and measured data.

  13. Fluid flow in the resurgent dome of Long Valley Caldera: Implications from thermal data and deep electrical sounding

    USGS Publications Warehouse

    Pribnow, D.F.C.; Schutze, C.; Hurter, S.J.; Flechsig, C.; Sass, J.H.

    2003-01-01

    Temperatures of 100??C are measured at 3 km depth in a well located on the resurgent dome in the center of Long Valley Caldera, California, despite an assumed >800??C magma chamber at 6-8 km depth. Local downflow of cold meteoric water as a process for cooling the resurgent dome is ruled out by a Pecle??t-number analysis of temperature logs. These analyses reveal zones with fluid circulation at the upper and lower boundaries of the Bishop Tuff, and an upflow zone in the metasedimentary rocks. Vertical Darcy velocities range from 10 to 70 cm a-1. A 21-km-long geoelectrical profile across the caldera provides resistivity values to the order of 100 to >103 ??m down to a depth of 6 km, as well as variations of self-potential. Interpretation of the electrical data with respect to hydrothermal fluid movement confirms that there is no downflow beneath the resurgent dome. To explain the unexpectedly low temperatures in the resurgent dome, we challenge the common view that the caldera as a whole is a regime of high temperatures and the resurgent dome is a local cold anomaly. Instead, we suggest that the caldera was cooled to normal thermal conditions by vigorous hydrothermal activity in the past, and that a present-day hot water flow system is responsible for local hot anomalies, such as Hot Creek and the area of the Casa Diablo geothermal power plant. The source of hot water has been associated with recent shallow intrusions into the West Moat. The focus of planning for future power plants should be to locate this present-day flow system instead of relying on heat from the old magma chamber. ?? 2003 Elsevier B.V. All rights reserved.

  14. Fluid flow in the resurgent dome of Long Valley Caldera: implications from thermal data and deep electrical sounding

    NASA Astrophysics Data System (ADS)

    Pribnow, Daniel F. C.; Schütze, Claudia; Hurter, Suzanne J.; Flechsig, Christina; Sass, John H.

    2003-10-01

    Temperatures of 100°C are measured at 3 km depth in a well located on the resurgent dome in the center of Long Valley Caldera, California, despite an assumed >800°C magma chamber at 6-8 km depth. Local downflow of cold meteoric water as a process for cooling the resurgent dome is ruled out by a Peclét-number analysis of temperature logs. These analyses reveal zones with fluid circulation at the upper and lower boundaries of the Bishop Tuff, and an upflow zone in the metasedimentary rocks. Vertical Darcy velocities range from 10 to 70 cm a -1. A 21-km-long geoelectrical profile across the caldera provides resistivity values to the order of 10 0 to >10 3 Ωm down to a depth of 6 km, as well as variations of self-potential. Interpretation of the electrical data with respect to hydrothermal fluid movement confirms that there is no downflow beneath the resurgent dome. To explain the unexpectedly low temperatures in the resurgent dome, we challenge the common view that the caldera as a whole is a regime of high temperatures and the resurgent dome is a local cold anomaly. Instead, we suggest that the caldera was cooled to normal thermal conditions by vigorous hydrothermal activity in the past, and that a present-day hot water flow system is responsible for local hot anomalies, such as Hot Creek and the area of the Casa Diablo geothermal power plant. The source of hot water has been associated with recent shallow intrusions into the West Moat. The focus of planning for future power plants should be to locate this present-day flow system instead of relying on heat from the old magma chamber.

  15. Resolving Discrepancies Between Observed and Predicted Dynamic Topography on Earth

    NASA Astrophysics Data System (ADS)

    Richards, F. D.; Hoggard, M.; White, N. J.

    2017-12-01

    Compilations of well-resolved oceanic residual depth measurements suggest that present-day dynamic topography differs from that predicted by geodynamic simulations in two significant respects. At short wavelengths (λ ≤ 5,000 km), much larger amplitude variations are observed, whereas at long wavelengths (λ > 5,000 km), observed dynamic topography is substantially smaller. Explaining the cause of this discrepancy with a view to reconciling these different approaches is central to constraining the structure and dynamics of the deep Earth. Here, we first convert shear wave velocity to temperature using an experimentally-derived anelasticity model. This relationship is calibrated using a pressure and temperature-dependent plate model that satisfies age-depth subsidence, heat flow measurements, and seismological constraints on the depth to the lithosphere-asthenosphere boundary. In this way, we show that, at short-wavelengths, observed dynamic topography is consistent with ±150 ºC asthenospheric temperature anomalies. These inferred thermal buoyancy variations are independently verified by temperature measurements derived from geochemical analyses of mid-ocean ridge basalts. Viscosity profiles derived from the anelasticity model suggest that the asthenosphere has an average viscosity that is two orders of magnitude lower than that of the underlying upper mantle. The base of this low-viscosity layer coincides with a peak in azimuthal anisotropy observed in recent seismic experiments. This agreement implies that lateral asthenospheric flow is rapid with respect to the underlying upper mantle. We conclude that improved density and viscosity models of the uppermost mantle, which combine a more comprehensive physical description of the lithosphere-asthenosphere system with recent seismic tomographic models, can help to resolve spectral discrepancies between observed and predicted dynamic topography. Finally, we explore possible solutions to the long-wavelength discrepancy that exploit the velocity to density conversion described above combined with radial variation of mantle viscosity.

  16. Advanced surface characterization of silver nanocluster segregation in Ag-TiCN bioactive coatings by RBS, GDOES, and ARXPS.

    PubMed

    Escobar Galindo, R; Manninen, N K; Palacio, C; Carvalho, S

    2013-07-01

    Surface modification by means of wear protective and antibacterial coatings represents, nowadays, a crucial challenge in the biomaterials field in order to enhance the lifetime of bio-devices. It is possible to tailor the properties of the material by using an appropriate combination of high wear resistance (e.g., nitride or carbide coatings) and biocide agents (e.g., noble metals as silver) to fulfill its final application. This behavior is controlled at last by the outmost surface of the coating. Therefore, the analytical characterization of these new materials requires high-resolution analytical techniques able to provide information about surface and depth composition down to the nanometric level. Among these techniques are Rutherford backscattering spectrometry (RBS), glow discharge optical emission spectroscopy (GDOES), and angle resolved X-ray photoelectron spectroscopy (ARXPS). In this work, we present a comparative RBS-GDOES-ARXPS study of the surface characterization of Ag-TiCN coatings with Ag/Ti atomic ratios varying from 0 to 1.49, deposited at room temperature and 200 °C. RBS analysis allowed a precise quantification of the silver content along the coating with a non-uniform Ag depth distribution for the samples with higher Ag content. GDOES surface profiling revealed that the samples with higher Ag content as well as the samples deposited at 200 °C showed an ultrathin (1-10 nm) Ag-rich layer on the coating surface followed by a silver depletion zone (20-30 nm), being the thickness of both layers enhanced with Ag content and deposition temperature. ARXPS analysis confirmed these observations after applying general algorithm involving regularization in addition to singular value decomposition techniques to obtain the concentration depth profiles. Finally, ARXPS measurements were used to provide further information on the surface morphology of the samples obtaining an excellent agreement with SEM observations when a growth model of silver islands with a height d = 1.5 nm and coverage θ = 0.20 was applied to the sample with Ag/Ti = 1.49 and deposited at room temperature.

  17. Common-midpoint radar surveys of ice sheets: a tool for better ice and bed property inversions

    NASA Astrophysics Data System (ADS)

    Holschuh, N.; Christianson, K.; Anandakrishnan, S.; Alley, R. B.; Jacobel, R. W.

    2016-12-01

    In response to the demand for observationally derived boundary conditions in ice-sheet models, geophysicists are striving to more quantitatively interpret the reflection amplitudes of ice penetrating radar data. Inversions for ice-flow parameters and basal properties typically use common-offset radar data, which contain a single observation of bed reflection amplitude at each location in the survey; however, the radar equation has more than one unknown - ice temperature, subglacial water content, and bedrock roughness cannot be uniquely determined without additional constraints. In this study, we adapt traditional seismic property inversion techniques to radar data, using additional information collected with a common-midpoint (CMP) radar survey geometry (which varies the source-receiver offset for each subsurface target). Using two of the first common-midpoint ice-penetrating radar data sets collected over thick ice in Antarctica and Greenland, we test the hypothesis that these data can be used to disentangle the contributions of ice conductivity and bed permittivity to the received reflection amplitudes. We focus specifically on the corrections for the angular dependence of antenna gain and surface reflectivity, refractive focusing effects, and surface scattering losses. Inferred temperature profiles, derived from the constrained ice conductivities at Kamb Ice Stream and the North East Greenland Ice Stream, suggest higher than expected depth-integrated temperatures, as well as non-physical depth trends (with elevated temperatures near the surface). We hypothesize that this is driven in part by offset-dependent interferences between the sub-wavelength layers that make up a single nadir reflection, and present a convolutional model that describes how this interference might systematically reduce reflection power with offset (thereby elevating the inferred attenuation rate). If these additional offset-dependent power losses can be isolated and removed, common-midpoint profiles could provide a promising new way to calibrate property inversions that use the more laterally extensive, airborne, common-offset radar surveys.

  18. Evaluating COSMO's lake module (FLake) for an East-African lake using a comprehensive set of lake temperature profiles

    NASA Astrophysics Data System (ADS)

    Thiery, W.; Martynov, A.; Darchambeau, F.; Demuzere, M.; van Lipzig, N.

    2012-04-01

    The African great lakes are of utmost importance for the local economy (fishing), as well as being essential to the survival of the local people. During last decades, these lakes have been changing rapidly and their evolution is a major concern. Hence, it is important to correctly represent them in regional climate models for simulations over tropical Africa. However, so far lake models have been developed and tested primarily for boreal conditions. In this study, for the first time the freshwater lake model FLake is evaluated over East-Africa, more specifically over lake Kivu. Meteorological observations from January 2003 to December 2008 from an automatic weather station in Bukavu, DRC, are used to drive the standalone version of FLake. For the evaluation, a unique dataset is used which contains over 200 temperature profiles recorded since 2002. Results show that FLake in its default configuration is very successful at reproducing both the timing and magnitude of the seasonal cycle at 5 m depth. Flake captures that this seasonality is regulated by the water vapour pressure, which constrains evaporation except during summer (JJA). A positive bias of ~1 K is attributed to the driving data, which are collected in the city and are therefore expected to mirror higher temperatures and lower wind speeds compared to the lake surface. The evaluation also showed that driving FLake with Era-Interim from the nearest pixel does only slightly deteriorate the model performance. Using forcing fields from the Canadian Regional Climate Model, version 5 (CRCM5) simulation output gives similar performance as Era-Interim. Furthermore, a drawback of FLake is that it does not account for salinity and its effect upon lake stratification, and therefore requires artificial initial conditions for both lake depth and bottom temperature in order to reproduce the correct mixing regime in lake Kivu. Further research will therefore aim at improving FLake's representation of tropical lakes.

  19. Permafrost investigation in the Mont Blanc massif steep rock walls: a combined measurement, modelling and geophysical approach

    NASA Astrophysics Data System (ADS)

    Magnin, Florence; Deline, Philip; Ravanel, Ludovic; Gruber, Stephan; Krautblatter, Michael

    2014-05-01

    The steep rockwalls of the Mont Blanc massif have been affected by an increase in rockfall activity in the last decades. Permafrost degradation is suggested as the most likely triggering factor. To better understand geomorphic processes we investigate permafrost distribution and address questions on its pattern in steep alpine bedrock. We use GIS-modeling to simulate Mean Annual Rock Surface Temperature (MARST) distribution. Rock temperature measurements including three 10-m-deep borehole monitoring at the Aiguille du Midi (AdM, 3842 m a.s.l) serve to estimate the temperature offset (i.e. temperature difference between rock surface and depth of negligible inter-annual temperature varibility). The estimation of the lower extent of permafrost distribution is derived from a combination of both approaches and hypotheses on permafrost occurrence are evaluated with Electrical Resistivity Tomography (ERT) measurements. The MARST model indicates that the 0°C isotherm extends down to 2600 m a.s.l in the most shaded faces and rises up to 3800 m in the most sun-exposed areas. According to recent literature and the AdM borehole thermal profiles, we postulate that permafrost could extends down below MARST reaching up to 3°C due to temperature offset processes. ERT measurements performed along 160-m-long profiles at six different sites which the top are located from 3360 m a.s.l to 2760 m a.s.l and the MARST range from <-1°C to > 3°C are the first of this kind. Five of sites are located in the granite area making them directly comparable. They all show high resistivity values at depth (>200 kΩ) interpreted as permafrost bodies. Lower resistivity values (< 90 kΩ) are found either above the high resistivity bodies and interpreted as thawed active layer, or below MARST warmer than 2-3°C and interpreted as non-perenially frozen rock. Two sites were measured in autumn 2012 and autumn 2013 allowing for time-lapse investigation which demonstrates the change in resistivity in repeated measurements. These preliminary results could confirm that steep alpine bedrock permafrost exists below surface temperature reaching up to 3°C. A temperature-resistivity calibration will be performed in a freezing laboratory at the Technical University of Munich to better assess ERT results and their interpretation in terms of permafrost occurrence and interannual changes.

  20. The vertical dependence in the horizontal variability of salinity and temperature at the ocean surface

    NASA Astrophysics Data System (ADS)

    Asher, W.; Drushka, K.; Jessup, A. T.; Clark, D.

    2016-02-01

    Satellite-mounted microwave radiometers measure sea surface salinity (SSS) as an area-averaged quantity in the top centimeter of the ocean over the footprint of the instrument. If the horizontal variability in SSS is large inside this footprint, sub-grid-scale variability in SSS can affect comparison of the satellite-retrieved SSS with in situ measurements. Understanding the magnitude of horizontal variability in SSS over spatial scales that are relevant to the satellite measurements is therefore important. Horizontal variability of SSS at the ocean surface can be studied in situ using data recorded by thermosalinographs (TSGs) that sample water from a depth of a few meters. However, it is possible measurements made at this depth might underestimate the horizontal variability at the surface because salinity and temperature can become vertically stratified in a very near surface layer due to the effects of rain, solar heating, and evaporation. This vertical stratification could prevent horizontal gradients from propagating to the sampling depths of ship-mounted TSGs. This presentation will discuss measurements made using an underway salinity profiling system installed on the R/V Thomas Thompson that made continuous measurements of SSS and SST in the Pacific Ocean. The system samples at nominal depths of 2-m, 3-m, and 5-m, allowing the depth dependence of the horizontal variability in SSS and SST to be measured. Horizontal variability in SST is largest at low wind speeds during daytime, when a diurnal warm layer forms. In contrast, the diurnal signal in the variability of SSS was smaller with variability being slightly larger at night. When studied as a function of depth, the results show that over 100-km scales, the horizontal variability in both SSS and SST at a depth of 2 m is approximately a factor of 4 higher than the variability at 5 m.

  1. Air-cooled volcanoes ? New insights on convective airflow process within Miyakejima and Piton de la Fournaise volcanoes

    NASA Astrophysics Data System (ADS)

    Antoine, R.; Geshi, N.; Kurita, K.; Aoki, Y.; Ichihara, M.; Staudacher, T.; Bachelery, P.

    2012-04-01

    Subsurface airflow in the unsaturated zone of the soil has been extensively investigated in a variety of disciplines such as mining, nuclear waste or agriculture science. In volcanology, the recent discovery of subsurface airflow close to the terminal cone of Piton de La Fournaise volcano (La Réunion Island, France) provides for the first time insights into the convective behavior of air within the unsaturated layer [1]. The characteristics of the aerothermal system, its occurrence in other volcanoes, its ability to transport heat during quiescent periods and the perturbation of this system before eruptions are the key questions we want to address following this discovery. In this study, we present observations of subsurface convective airflow within opened fractures located at the summit of Miyakejima and Piton de la Fournaise volcanoes from anemometric and temperature data. Two anemometers and thermocouples were placed at the surface and at the center of the fracture at two-meter depth during a diurnal cycle. Six thermocouples also measured the temperature at 1 meter-depth, on a profile set perpendicularly to the fracture. Finally, a thermal camera was used to make punctual measurements of the surface temperature of the fracture. At Miyakejima, two surveys were realized in winter 2010 and summer 2011. During the winter, mild air exit was detected from the fracture with a central vertical velocity of 20 to 50 cm/s. The temperature of the site was constant during the diurnal cycle (~ 22°C), leading to a maximum temperature contrast of 15°C between the fracture and the atmosphere just before sunrise. During summer, a different hydrodynamic behavior was observed: Air inflow was detected during the whole diurnal cycle with a mean velocity of 20 cm/s. The temperature of the fracture followed the temperature of the atmosphere at 2 meters-depth. In the case of Piton de la Fournaise volcano, the same convective behavior was observed at two different fractures during winter 2008 and summer 2010. Moreover, the velocities and temperature contrast between the fracture and the atmosphere were close to the ones recorded at Miyakejima. Finally, the temperature profiles realized across the fractures and confirmed by the infrared thermography data allowed us to define the convective patterns. This study represents the first detection and characterization of air convection at a seasonal scale within fractures on volcanoes. It constitutes a preliminary step to further investigations dedicated to the understanding of the perturbation of such systems before eruptions. [1] Antoine R., Baratoux D., Rabinowicz M., Fontaine F.J., Bachèlery P., Staudacher T., Saracco G., Finizola A., Thermal infrared images analysis of a quiescent cone on Piton de La Fournaise volcano: Evidence for convective air flow within an unconsolidated soil, Journal of Volcanology and Geothermal Research, Volume 183, Issues 3-4, 2009, Pages 228-244.

  2. Surface layer and bloom dynamics observed with the Prince William Sound Autonomous Profiler

    NASA Astrophysics Data System (ADS)

    Campbell, R. W.

    2016-02-01

    As part of a recent long term monitoring effort, deployments of a WETLabs Autonomous Moored Profiler (AMP) began Prince William Sound (PWS) in 2013. The PWS AMP consists of a positively buoyant instrument frame, with a winch and associated electronics that profiles the frame from a park depth (usually 55 m) to the surface by releasing and retrieving a thin UHMWPE tether; it generally conducts a daily cast and measures temperature, salinity, chlorophyll-a fluorescence, turbidity, and oxygen and nitrate concentrations. Upward and downward looking ADCPs are mounted on a float below the profiler, and an in situ plankton imager is in development and will be installed in 2016. Autonomous profilers are a relatively new technology, and early deployments experienced a number of failures from which valuable lessons may be learned. Nevertheless, an unprecedented time series of the seasonal biogeochemical procession in the surface waters coastal Gulf of Alaska was collected in 2014 and 2015. The northern Gulf of Alaska has experienced a widespread warm anomaly since early 2014, and surface layer temperature anomalies in PWS were strongly positive during winter 2014. The spring bloom observed by the profiler began 2-3 weeks earlier than average, with surface nitrate depleted by late April. Although surface temperatures were still above average in 2015, bloom timing was much later, with a short vigorous bloom in late April and a subsurface bloom in late May that coincided with significant nitrate drawdown. As well as the vernal blooms, wind-driven upwelling events lead to several small productivity pulses that were evident in changes in nitrate and oxygen concentrations, and chlorophyll-a fluorescence. As well as providing a mechanistic understanding of surface layer biogeochemistry, high frequency observations such as these put historical observations in context, and provide new insights into the scales of variability in the annual cycles of the surface ocean in the North Pacific.

  3. A perspective on two chemometrics tools: PCA and MCR, and introduction of a new one: Pattern recognition entropy (PRE), as applied to XPS and ToF-SIMS depth profiles of organic and inorganic materials

    NASA Astrophysics Data System (ADS)

    Chatterjee, Shiladitya; Singh, Bhupinder; Diwan, Anubhav; Lee, Zheng Rong; Engelhard, Mark H.; Terry, Jeff; Tolley, H. Dennis; Gallagher, Neal B.; Linford, Matthew R.

    2018-03-01

    X-ray photoelectron spectroscopy (XPS) and time-of-flight secondary ion mass spectrometry (ToF-SIMS) are much used analytical techniques that provide information about the outermost atomic and molecular layers of materials. In this work, we discuss the application of multivariate spectral techniques, including principal component analysis (PCA) and multivariate curve resolution (MCR), to the analysis of XPS and ToF-SIMS depth profiles. Multivariate analyses often provide insight into data sets that is not easily obtained in a univariate fashion. Pattern recognition entropy (PRE), which has its roots in Shannon's information theory, is also introduced. This approach is not the same as the mutual information/entropy approaches sometimes used in data processing. A discussion of the theory of each technique is presented. PCA, MCR, and PRE are applied to four different data sets obtained from: a ToF-SIMS depth profile through ca. 100 nm of plasma polymerized C3F6 on Si, a ToF-SIMS depth profile through ca. 100 nm of plasma polymerized PNIPAM (poly (N-isopropylacrylamide)) on Si, an XPS depth profile through a film of SiO2 on Si, and an XPS depth profile through a film of Ta2O5 on Ta. PCA, MCR, and PRE reveal the presence of interfaces in the films, and often indicate that the first few scans in the depth profiles are different from those that follow. PRE and backward difference PRE provide this information in a straightforward fashion. Rises in the PRE signals at interfaces suggest greater complexity to the corresponding spectra. Results from PCA, especially for the higher principal components, were sometimes difficult to understand. MCR analyses were generally more interpretable.

  4. Meteoric 10Be in soil profiles - A global meta-analysis

    USGS Publications Warehouse

    Graly, Joseph A.; Bierman, Paul R.; Reusser, Lucas J.; Pavich, Milan J.

    2010-01-01

    In order to assess current understanding of meteoric 10Be dynamics and distribution in terrestrial soils, we assembled a database of all published meteoric 10Be soil depth profiles, including 104 profiles from 27 studies in globally diverse locations, collectively containing 679 individual measurements. This allows for the systematic comparison of meteoric 10Be concentration to other soil characteristics and the comparison of profile depth distributions between geologic settings. Percent clay, 9Be, and dithionite-citrate extracted Al positively correlate to meteoric 10Be in more than half of the soils where they were measured, but the lack of significant correlation in other soils suggests that no one soil factor controls meteoric 10Be distribution with depth. Dithionite-citrate extracted Fe and cation exchange capacity are only weakly correlated to meteoric 10Be. Percent organic carbon and pH are not significantly related to meteoric 10Be concentration when all data are complied.The compilation shows that meteoric 10Be concentration is seldom uniform with depth in a soil profile. In young or rapidly eroding soils, maximum meteoric 10Be concentrations are typically found in the uppermost 20 cm. In older, more slowly eroding soils, the highest meteoric 10Be concentrations are found at depth, usually between 50 and 200 cm. We find that the highest measured meteoric 10Be concentration in a soil profile is an important metric, as both the value and the depth of the maximum meteoric 10Be concentration correlate with the total measured meteoric 10Be inventory of the soil profile.In order to refine the use of meteoric 10Be as an estimator of soil erosion rate, we compare near-surface meteoric 10Be concentrations to total meteoric 10Be soil inventories. These trends are used to calibrate models of meteoric 10Be loss by soil erosion. Erosion rates calculated using this method vary based on the assumed depth and timing of erosional events and on the reference data selected.

  5. Magnetotelluric evidence for massive sulphide mineralization in intruded sediments of the outer Vøring Basin, mid-Norway

    NASA Astrophysics Data System (ADS)

    Corseri, Romain; Senger, Kim; Selway, Kate; Abdelmalak, Mohamed Mansour; Planke, Sverre; Jerram, Dougal A.

    2017-06-01

    A highly conductive body (0.1-0.8 Ω·m) is identified at mid-crustal depth (8-13 km) in the north Gjallar Ridge from magnetotelluric (MT) data and further investigated in light of other remote-sensing geophysical data (seismic reflection, gravity, aeromagnetic). A commercial 3D controlled-source electromagnetic survey was conducted in the Vøring Basin in 2014 and, although primarily designed for hydrocarbon exploration, good quality MT data were extracted at periods ranging from 100 to 103 s. Dimensionality analysis indicates clear 1D to 2D characteristics in the MT data. 2D inversion was carried out on four profiles (totalling 94 km) oriented perpendicular to the electromagnetic strike and one profile along strike ( 45 km), using a 1D subset of the data. All inversions converged quickly to RMS values close to unity and display a very good agreement with borehole resistivity data from well 6705/10-1 located in the survey area. A striking feature on all profiles is a highly conductive (0.1-0.8 Ω·m) body at 8-13 km depth. To explain the prominent conductive anomaly, integration of geophysical data favours the hypothesis of electrical conduction across well-connected mineral network in pre-Cretaceous sediments. Seismic interpretation suggests a link between the conductor and intruded sedimentary successions below a detachment level and associated low-angle faults. In the Vøring Basin, low magnetic signal and temperature at the conductor's depth indicate that such thick mineral deposits could display non-magnetic behaviour while occurring well below the magnetite Curie isotherm ( 585 °C). Natural occurrences and magnetic properties of common iron-sulphide minerals favour a geological interpretation of mid-crustal conductivity as thick pyrrhotite deposits formed in intrusion's contact metamorphic aureoles.

  6. Breadth and Depth of Vocabulary Knowledge and Their Effects on L2 Vocabulary Profiles

    ERIC Educational Resources Information Center

    Bardakçi, Mehmet

    2016-01-01

    Breadth and depth of vocabulary knowledge have been studied from many different perspectives, but the related literature lacks serious studies dealing with their effects on vocabulary profiles of EFL learners. In this paper, with an aim to fill this gap, the relative effects of breadth and depth of vocabulary knowledge on L2 vocabulary profiles…

  7. XPS investigation of depth profiling induced chemistry

    NASA Astrophysics Data System (ADS)

    Pratt, Quinn; Skinner, Charles; Koel, Bruce; Chen, Zhu

    2017-10-01

    Surface analysis is an important tool for understanding plasma-material interactions. Depth profiles are typically generated by etching with a monatomic argon ion beam, however this can induce unintended chemical changes in the sample. Tantalum pentoxide, a sputtering standard, and PEDOT:PSS, a polymer that was used to mimic the response of amorphous carbon-hydrogen co-deposits, were studied. We compare depth profiles generated with monatomic and gas cluster argon ion beams (GCIB) using X-ray photoelectron spectroscopy (XPS) to quantify chemical changes. In both samples, monatomic ion bombardment led to beam-induced chemical changes. Tantalum pentoxide exhibited preferential sputtering of oxygen and the polymer experienced significant bond modification. Depth profiling with clusters is shown to mitigate these effects. We present sputtering rates for Ta2O5 and PEDOT:PSS as a function of incident energy and flux. Support was provided through DOE Contract Number DE-AC02-09CH11466.

  8. Influence of surface topography on depth profiles obtained with secondary-ion mass spectrometry

    NASA Astrophysics Data System (ADS)

    Walker, A. J.; Borchert, M. T.; Vriezema, C. J.; Zalm, P. C.

    1990-11-01

    Lithographically generated well-defined surface topography of submicron dimensions has been etched into silicon (100) previously implanted with 25 keV 11B to a fluence of 2×1014 atoms/cm2. The thus-obtained samples were depth profiled via secondary-ion mass spectrometry (SIMS). The boron concentration distributions measured were contrasted against those found on undisturbed flat parts of the target. From this intercomparison the otherwise trivial observation that surface topography causes profile distortion becomes suddenly alarming as an apparent improvement of depth resolution occurs. Scanning electron microscope images enable identification of the origin of this remarkable phenomenon. The present results imply that (i) the hitherto commonly accepted assumption in the interpretation of SIMS depth profiles that perceived gradients are never steeper than actual ones is subject to revision; (ii) it may prove very difficult, if not impossible, to construct SIMS equipment for reliable on-chip analysis of submicron details.

  9. Chemical and valence reconstruction at the surface of SmB6 revealed by means of resonant soft x-ray reflectometry

    NASA Astrophysics Data System (ADS)

    Zabolotnyy, V. B.; Fürsich, K.; Green, R. J.; Lutz, P.; Treiber, K.; Min, Chul-Hee; Dukhnenko, A. V.; Shitsevalova, N. Y.; Filipov, V. B.; Kang, B. Y.; Cho, B. K.; Sutarto, R.; He, Feizhou; Reinert, F.; Inosov, D. S.; Hinkov, V.

    2018-05-01

    Samarium hexaboride (SmB6), a Kondo insulator with mixed valence, has recently attracted much attention as a possible host for correlated topological surface states. Here, we use a combination of x-ray absorption and reflectometry techniques, backed up with a theoretical model for the resonant M4 ,5 absorption edge of Sm and photoemission data, to establish laterally averaged chemical and valence depth profiles at the surface of SmB6. We show that upon cleaving, the highly polar (001) surface of SmB6 undergoes substantial chemical and valence reconstruction, resulting in boron termination and a Sm3 + dominated subsurface region. Whereas at room temperature, the reconstruction occurs on a timescale of less than 2 h, it takes about 24 h below 50 K. The boron termination is eventually established, irrespective of the initial termination. Our findings reconcile earlier depth resolved photoemission and scanning tunneling spectroscopy studies performed at different temperatures and are important for better control of surface states in this system.

  10. Low Temperature Ohmic Contact Formation of Ni2Si on N-type 4H-SiC and 6H-SiC

    NASA Technical Reports Server (NTRS)

    Elsamadicy, A. M.; Ila, D.; Zimmerman, R.; Muntele, C.; Evelyn, L.; Muntele, I.; Poker, D. B.; Hensley, D.; Hirvonen, J. K.; Demaree, J. D.; hide

    2001-01-01

    Nickel Silicide (Ni2Si) is investigated as possible ohmic contact to heavily nitrogen-doped N-type 4H-SiC and 6H-SiC. Nickel Silicide was deposited via electron gun with various thicknesses on both Si and C faces of the SiC substrates. The Ni2Si contacts were formed at room temperature as well as at elevated temperatures (400 to 1000 K). Contact resistivities and I-V characteristics were measured at temperatures between 100 and 700 C. To investigate the electric properties, I-V characteristics were studied and the Transmission Line Method (TLM) was used to determine the specific contact resistance for the samples at each annealing temperature. Both Rutherford Backscattering Spectroscopy (RBS) and Auger Electron Spectroscopy (AES) were used for depth profiling of the Ni2Si, Si, and C. X-ray Photoemission Spectroscopy (XPS) was used to study the chemical structure of the Ni2Si/SiC interface.

  11. Observations of Strong Surface Radar Ducts over the Persian Gulf.

    NASA Astrophysics Data System (ADS)

    Brooks, Ian M.; Goroch, Andreas K.; Rogers, David P.

    1999-09-01

    Ducting of microwave radiation is a common phenomenon over the oceans. The height and strength of the duct are controlling factors for radar propagation and must be determined accurately to assess propagation ranges. A surface evaporation duct commonly forms due to the large gradient in specific humidity just above the sea surface; a deeper surface-based or elevated duct frequently is associated with the sudden change in temperature and humidity across the boundary layer inversion.In April 1996 the U.K. Meteorological Office C-130 Hercules research aircraft took part in the U.S. Navy Ship Antisubmarine Warfare Readiness/Effectiveness Measuring exercise (SHAREM-115) in the Persian Gulf by providing meteorological support and making measurements for the study of electromagnetic and electro-optical propagation. The boundary layer structure over the Gulf is influenced strongly by the surrounding desert landmass. Warm dry air flows from the desert over the cooler waters of the Gulf. Heat loss to the surface results in the formation of a stable internal boundary layer. The layer evolves continuously along wind, eventually forming a new marine atmospheric boundary layer. The stable stratification suppresses vertical mixing, trapping moisture within the layer and leading to an increase in refractive index and the formation of a strong boundary layer duct. A surface evaporation duct coexists with the boundary layer duct.In this paper the authors present aircraft- and ship-based observations of both the surface evaporation and boundary layer ducts. A series of sawtooth aircraft profiles map the boundary layer structure and provide spatially distributed estimates of the duct depth. The boundary layer duct is found to have considerable spatial variability in both depth and strength, and to evolve along wind over distances significant to naval operations (100 km). The depth of the evaporation duct is derived from a bulk parameterization based on Monin-Obukhov similarity theory using near-surface data taken by the C-130 during low-level (30 m) flight legs and by ship-based instrumentation. Good agreement is found between the two datasets. The estimated evaporation ducts are found to be generally uniform in depth; however, localized regions of greatly increased depth are observed on one day, and a marked change in boundary layer structure resulting in merging of the surface evaporation duct with the deeper boundary layer duct was observed on another. Both of these cases occurred within exceptionally shallow boundary layers (100 m), where the mean evaporation duct depths were estimated to be between 12 and 17 m. On the remaining three days the boundary layer depth was between 200 and 300 m, and evaporation duct depths were estimated to be between 20 and 35 m, varying by just a few meters over ranges of up to 200 km.The one-way radar propagation factor is modeled for a case with a pronounced change in duct depth. The case is modeled first with a series of measured profiles to define as accurately as possible the refractivity structure of the boundary layer, then with a single profile collocated with the radar antenna and assuming homogeneity. The results reveal large errors in the propagation factor when derived from a single profile.

  12. Deep drilling at the Siljan Ring impact structure: oxygen-isotope geochemistry of granite

    USGS Publications Warehouse

    Komor, S.C.; Valley, J.W.

    1990-01-01

    The Siljan Ring is a 362-Ma-old impact structure formed in 1700-Ma-old I-type granites. A 6.8-km-deep borehole provides a vertical profile through granites and isolated horizontal diabase sills. Fluid-inclusion thermometry, and oxygen-isotope compositions of vein quartz, granite, diabase, impact melt, and pseudotachylite, reveal a complex history of fluid activity in the Siljan Ring, much of which can be related to the meteorite impact. In granites from the deep borehole, ??18O values of matrix quartz increase with depth from near 8.0 at the surface to 9.5??? at 5760 m depth. In contrast, feldspar ??18O values decrease with depth from near 10 at the surface to 7.1??? at 5760 m, forming a pattern opposite to the one defined by quartz isotopic compositions. Values of ??18O for surface granites outside the impact structure are distinct from those in near-surface samples from the deep borehole. In the deep borehole, feldspar coloration varies from brick-red at the surface to white at 5760 m, and the abundances of crack-healing calcite and other secondary minerals decrease over the same interval. Superimposed on the overall decrease in alteration intensity with depth are localized fracture zones at 4662, 5415, and 6044 m depth that contain altered granites, and which provided pathways for deep penetration of surface water. The antithetic variation of quartz and feldspar ??18O values, which can be correlated with mineralogical evidence of alteration, provides evidence for interaction between rocks and impact-heated fluids (100-300?? C) in the upper 2 km of the pluton. Penetration of water to depths below 2 km was restricted by a general decrease in impact-fracturing with depth, and by a 60-m-thick diabase sill at 1500 m depth that may have been an aquitard. At depths below 4 km in the pluton, where water/rock ratios were low, oxygen isotopic compositions preserve evidence for limited high-temperature (>500?? C) exchange between alkali feldspar and fluids. The high-temperature exchange may have been a post-impact event involving impact-heated fluids, or a post-magmatic event. ?? 1990 Springer-Verlag.

  13. Tool life and surface integrity aspects when drilling nickel alloy

    NASA Astrophysics Data System (ADS)

    Kannan, S.; Pervaiz, S.; Vincent, S.; Karthikeyan, R.

    2018-04-01

    Nickel based super alloys manufactured through powder metallurgy (PM) route are required to increase the operational efficiency of gas turbine engines. They are material of choice for high pressure components due to their superior high temperature strength, excellent corrosion, oxidation and creep resistance. This unique combination of mechanical and thermal properties makes them even more difficult-to-machine. In this paper, the hole making process using coated carbide inserts by drilling and plunge milling for a nickel-based powder metallurgy super alloy has been investigated. Tool life and process capability studies were conducted using optimized process parameters using high pressure coolants. The experimental trials were directed towards an assessment of the tendency for surface malformations and detrimental residual stress profiles. Residual stresses in both the radial and circumferential directions have been evaluated as a function of depth from the machined surface using the target strain gauge / center hole drilling method. Circumferential stresses near workpiece surface and at depth of 512 µm in the starting material was primarily circumferential compression which was measured to be average of –404 MPa. However, the radial stresses near workpiece surface was tensile and transformed to be compressive in nature at depth of 512 µm in the starting material (average: -87 Mpa). The magnitude and the depth below the machined surface in both radial and circumferential directions were primarily tensile in nature which increased with hole number due to a rise of temperature at the tool–workpiece interface with increasing tool wear. These profiles are of critical importance for the selection of cutting strategies to ensure avoidance/minimization of tensile residual stresses that can be detrimental to the fatigue performance of the components. These results clearly show a tendency for the circumferential stresses to be more tensile than the radial stresses. Overall the results indicate that the effect of drilling and milling parameters is most marked in terms of surface quality in the circumferential direction. Material removal rates and tool flank wear must be maintained within the control limits to maintain hole integrity.

  14. Water-quality data for the Ohio River from New Cumberland Dam to Pike Island Dam, West Virginia and Ohio, May-October 1993

    USGS Publications Warehouse

    Miller, K.F.; Messinger, Terence; Waldron, M.C.; Faulkenburg, C.W.

    1996-01-01

    This report contains water-quality data for the Ohio River from river mile 51.1 (3.3 miles upstream from New Cumberland Dam) to river mile 84.0 (0.2 miles upstream from Pike Island Dam) that were collected during the summer and fall of 1993. The data were collected to establish the water quality of the Ohio River and to use in assessing the proposed effects of hydropower development on the water quality of the Ohio River. Water quality was determined by a combination of repeated synoptic field measurements, continuous-record monitoring, and laboratory analyses. Synoptic measurements were made along a longitudinal transect with 18 mid-channel sampling sites; cross-sectional transects of water-quality measurements were made at 5 of these sites. Water-quality measurements also were made at two sites located on the back-channel (Ohio) side of Browns Island. At each longitudinal-transect and back-channel sampling site, measurements were made of specific conductance, pH, water temperature, and dissolved oxygen conentration. Longitudinal-transect and back-channel stations were sampled at four depths (at the surface, about 3.3 feet below the surface, middle of the water column, and near the bottom of the river). Cross-sectional transects consisted of three to four detailed vertical profiles of the same characteristics. Water samples were collected from three depths at the mid-channel vertical profile in each cross-sectional transect and were analyzed for concentrations of phytoplankton photosynthetic pigments chlorophyll a and chlorophyll b. Estimates of the depth of light penetration (Secchi-disk transparency) were made at pigment-sampling locations whenever light and river-surface conditions were appropriate. Synoptic sampling usually was completed in 12 hours or less and was repeated 10 times from May through October 1993. Continuous-record monitoring of water quality consisted of hourly measurements of specific conductance, pH, water temperature, and dissolved oxygen concentration, made at a depth of 6.6 feet upstream and downstream of New Cumberland Dam. Continuous monitors were operated from May through October 1993.

  15. Water-quality data for the Ohio River from Willow Island Dam to Belleville Dam, West Virginia and Ohio, May-October 1993

    USGS Publications Warehouse

    Miller, K.F.

    1996-01-01

    This report contains water-quality data for the Ohio River from river mile 160.6 (1.1 mile upstream from Willow Island Dam) to river mile 203.6 (0.3 mile upstream from Belleville Dam) that were collected during the summer and fall of 1993. The data were collected to establish the water quality of the Ohio River and to use in assessing the proposed effects of hydropower development on the water quality of the Ohio River. Water quality was monitored by a combination of synoptic field measurements, laboratory analyses, and continuous- record monitoring. Field measurements of water- quality characteristics were made along a longitudinal transect with 24 mid-channel sampling sites; cross-sectional transects of water-quality measurements were made at six of these sites. Water-quality measurements also were made at six sites located on the back-channel (West Virginia) sides of Marietta, Muskingum, and Blennerhassett Islands. At each longitudinal-transect and back- channel sampling site, measurements of specific conductance, pH, water temperature, and dissolved oxygen concentration were made at three depths (about 3.3 feet below the surface of the water, middle of the water column, and near the bottom of the river). Cross-sectional transects consisted of three to four detailed vertical profiles of the same characteristics. Water samples were collected at three depths in the mid-channel vertical profile in each cross-sectional transect and were analyzed for concentrations of phytoplankton chlorophyll a and chlorophyll b. Estimates of the depth of light penetration (Secchi disk transparency) were made at phytoplankton- pigment-sampling locations whenever light and river-surface conditions were appropriate. Each synoptic sampling event was completed in 2 days or less. The entire network was sampled 10 times from May 24 to October 27, 1993. Continuous-record monitoring of water quality consisted of hourly measurments of specific conductance, pH, water temperature, and dissolved oxygen concentration that were made at a depth of 6.6 feet at the ends of the upstream and downstream wingwalls at Willow Island Dam. Continuous-record monitors were operated from May through October 1993.

  16. Depth-Related Changes in Community Structure of Culturable Mineral Weathering Bacteria and in Weathering Patterns Caused by Them along Two Contrasting Soil Profiles

    PubMed Central

    Huang, Jing; Xi, Jun; Huang, Zhi; Wang, Qi; Zhang, Zhen-Dong

    2014-01-01

    Bacteria play important roles in mineral weathering and soil formation. However, few reports of mineral weathering bacteria inhabiting subsurfaces of soil profiles have been published, raising the question of whether the subsurface weathering bacteria are fundamentally distinct from those in surface communities. To address this question, we isolated and characterized mineral weathering bacteria from two contrasting soil profiles with respect to their role in the weathering pattern evolution, their place in the community structure, and their depth-related changes in these two soil profiles. The effectiveness and pattern of bacterial mineral weathering were different in the two profiles and among the horizons within the respective profiles. The abundance of highly effective mineral weathering bacteria in the Changshu profile was significantly greater in the deepest horizon than in the upper horizons, whereas in the Yanting profile it was significantly greater in the upper horizons than in the deeper horizons. Most of the mineral weathering bacteria from the upper horizons of the Changshu profile and from the deeper horizons of the Yanting profile significantly acidified the culture media in the mineral weathering process. The proportion of siderophore-producing bacteria in the Changshu profile was similar in all horizons except in the Bg2 horizon, whereas the proportion of siderophore-producing bacteria in the Yanting profile was higher in the upper horizons than in the deeper horizons. Both profiles existed in different highly depth-specific culturable mineral weathering community structures. The depth-related changes in culturable weathering communities were primarily attributable to minor bacterial groups rather than to a change in the major population structure. PMID:24077700

  17. Spatio-temporal variability of the atmospheric boundary layer depth over the Paris agglomeration: An assessment of the impact of the urban heat island intensity

    NASA Astrophysics Data System (ADS)

    Pal, S.; Xueref-Remy, I.; Ammoura, L.; Chazette, P.; Gibert, F.; Royer, P.; Dieudonné, E.; Dupont, J.-C.; Haeffelin, M.; Lac, C.; Lopez, M.; Morille, Y.; Ravetta, F.

    2012-12-01

    Within the framework of a French nationally funded project (CO2-MEGAPARIS) for quantifying the CO2 emissions of the Paris area, a lidar-based experimental investigation of the variability of the atmospheric boundary layer (ABL) depths was performed over four days in March 2011 under clear sky conditions. The prevailing synoptic settings were mainly characterized by anti-cyclonic situations with low wind. The key aim of this paper is to assess the impact of the urban heat island intensity (UHII) on the spatio-temporal variability of the ABL depths over the Paris megacity. A network of fixed aerosol lidars was deployed inside the city and in the vicinity of sub-urban and rural areas. Additionally, the spatial heterogeneity of the nocturnal boundary layer (NBL) depths over greater Paris area is addressed, thanks in particular, to the deployment of a 355-nm elastic lidar in a mobile van to measure the aerosol distributions. Radiosonde-derived profiles (twice a day) of thermodynamic variables over the sub-urban site helped investigate the temperature inversion above ground and hence to compare the lidar-derived ABL depths. Comparing these two results, an excellent concordance was found with a correlation coefficient of 0.994. Five important factors closely related to the ABL circulation, namely, spatio-temporal variability of the ABL depths, growth rate of the ABL depths, entrainment zone thickness, and near-surface temperature fields including resultant UHII were considered to infer the urban-rural contrasts. The mean NBL depth over the urban area was on average 63 m (45%) higher than its adjacent sub-urban area which was, on occasion, as much as (74 m) 58% higher mainly due to the effect of UHII. Daytime well-mixed convective boundary layer and associated strong turbulent mixing near its top over the urban area showed higher entrainment zone thickness (326 m) than over sub-urban (234 m) and rural (200 m) areas. Temperature growth rates during sunrise increased up to more than 3 °C h-1 over the sub-urban area while over the urban region it was 2.5 °C h-1 or even less. The ABL depths over the urban site decayed more slowly (500 m h-1) than over the sub-urban area (600 m h-1) during the late afternoon transition period suggesting an impact of the UHII on the ABL dynamics over the urban area.

  18. Metabolic rates of benthic deep-sea decapod crustaceans decline with increasing depth primarily due to the decline in temperature

    NASA Astrophysics Data System (ADS)

    Childress, J. J.; Cowles, D. L.; Favuzzi, J. A.; Mickel, T. J.

    1990-06-01

    The oxygen consumption rates of 11 species of benthic deep-sea decapod crustaceans were measured at a variety of temperatures to test the hypothesis that the metabolic rates of benthic crustaceans decline with increasing depth of occurrence only to the extent explained by the decline in temperature with depth. The species were captured at depths between 150 and 2000m off Southern California using an epibenthic beam trawl equipped with a thermally protecting cod-end to bring the animals to the surface uncontaminated by sediment and at the depth temperature. The data, combined with those for six species of shallower-living crustaceans from California waters, showed a significant decline in oxygen consumption rate with increased species' depths of occurrence, when the measurements were made at temperatures appropriate to each species' depth range. There was no significant relation between wet weight and depth of occurrence in these species. When the data were adjusted to 10°C using a moderate temperature effect factor (corresponding to Q10 values of 2-2.3 depending on the species and temperature range), the significant relationship between oxygen consumption rate and depth was lost, indicating that the observed decline with depth was due to the decline in temperature with depth. When the relationship between metabolic rate and depth of occurrence for the most active (carideans and penaeid) species were compared (ANCOVA) with that for the rest of the species, the active species had significantly higher rates. By combining this data set with data from the literature for a wide variety of shallow-living benthic decapod crustaceans, it was possible to create a data set of 35 species in which the effects of temperature, minimum depth of occurrence and body mass could be separated by multiple linear regression. This demonstrated highly significant effects of size and temperature, but no significant effect of depth for the entire data set and for the data set excluding penaeids and carideans. In contrast, the carideans showed a significant effect of depth on metabolic rate. This is discussed in terms of the adaptive and selective factors responsible for the well-known decline in metabolic rates of midwater crustaceans and fishes, an effect which does exceed the effect of temperature. It is suggested that the typical pattern for deeper living animals may be that metabolic rates on average vary as a function of depth due primarily to variation in temperature, except for the visually orienting pelagic groups (cephalopods, crustaceans and fishes). For those benthic forms which are particularly visually oriented and/or partially pelagic some significant depth-related decline in metabolism beyond that due to the decline in temperature is expected.

  19. Geophysical techniques for reconnaissance investigations of soils and surficial deposits in mountainous terrain

    USGS Publications Warehouse

    Olson, C.G.; Doolittle, J.A.

    1985-01-01

    Two techniques were assessed for their capabilities in reconnaissance studies of soil characteristics: depth to the water table and depth to bedrock beneath surficial deposits in mountainous terrain. Ground-penetrating radar had the best near-surface resolution in the upper 2 m of the profile and provided continuous interpretable imagery of soil profiles and bedrock surfaces. Where thick colluvium blankets side slopes, the GPR could not consistently define the bedrock interface. In areas with clayey or shaley sediments, the GPR is also more limited in defining depth and is less reliable. Seismic refraction proved useful in determining the elevation of the water table and depth to bedrock, regardless of thickness of overlying material, but could not distinguish soil-profile characteristics.-from Authors

  20. Enhanced retained dose uniformity in NiTi spinal correction rod treated by three-dimensional mesh-assisted nitrogen plasma immersion ion implantation

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Lu, Q. Y.; Hu, T.; Kwok, Dixon T. K.

    2010-05-15

    Owing to the nonconformal plasma sheath in plasma immersion ion implantation of a rod sample, the retained dose can vary significantly. The authors propose to improve the implant uniformity by introducing a metal mesh. The depth profiles obtained with and without the mesh are compared and the implantation temperature at various locations is evaluated indirectly by differential scanning calorimeter. Our results reveal that by using the metal mesh, the retained dose uniformity along the length is greatly improved and the effects of the implantation temperature on the localized mechanical properties of the implanted NiTi shape memory alloy rod are nearlymore » negligible.« less

  1. SPRUCE Deep Peat Heating (DPH) Peat Water Content and Temperature Profiles for Experimental Plot Cores, June 2014 through June 2015

    DOE Data Explorer

    Kluber, Lauren A. [Oak Ridge National Laboratory, U.S. Department of Energy, Oak Ridge, Tennessee, U.S.A.; Phillips, Jana R. [Oak Ridge National Laboratory, U.S. Department of Energy, Oak Ridge, Tennessee, U.S.A.; Hanson, Paul J. [Oak Ridge National Laboratory, U.S. Department of Energy, Oak Ridge, Tennessee, U.S.A.; Schadt, Christopher W. [Oak Ridge National Laboratory, U.S. Department of Energy, Oak Ridge, Tennessee, U.S.A.

    2016-01-01

    This data set provides the peat water content and peat temperature at time of sampling for peat cores collected before and during the SPRUCE Deep Peat Heating (DPH) study. Cores were collected during three sampling events: 03 June 2014, 09 September 2014, and 16 June 2015. Two cores were extracted from hollow locations in each of the 10 experimental plots (4, 6, 8, 10, 11, 13, 16, 17, 19, and 20). Cores were partitioned into samples at 11 depth increments: 0-10, 10-20, 20-30, 30-40, 40-50, 50-75, 75-100, 100-125, 125-150, 150-175, and 175-200 cm below surface of the hollow.

  2. The effects of wavelength on photodegradation depth profiles in Japanese cedar (Cryptomeria japonica D. Don) earlywood

    Treesearch

    Yutaka Kataoka; Makoto Kiguchi; R. Sam Williams; Philip D. Evans

    2006-01-01

    FT-IR microscopy was used to depth profile the photodegradation of Japanese cedar earlywood exposed to monochromatic light in the UV and visible ranges (band pass: 20nm). Parallel experiments assessed the transmission of the light through thin sections of Japanese cedar. The depth of photodegradation increased with wavelength up to and including the violet region of...

  3. Comparison of experimental three-band IR detection of buried objects and multiphysics simulations

    NASA Astrophysics Data System (ADS)

    Rabelo, Renato C.; Tilley, Heather P.; Catterlin, Jeffrey K.; Karunasiri, Gamani; Alves, Fabio D. P.

    2018-04-01

    A buried-object detection system composed of a LWIR, a MWIR and a SWIR camera, along with a set of ground and ambient temperature sensors was constructed and tested. The objects were buried in a 1.2x1x0.3 m3 sandbox and surface temperature (using LWIR and MWIR cameras) and reflection (using SWIR camera) were recoded throughout the day. Two objects (aluminum and Teflon) with volume of about 2.5x10-4 m3 , were placed at varying depths during the measurements. Ground temperature sensors buried at three different depths measured the vertical temperature profile within the sandbox, while the weather station recorded the ambient temperature and solar radiation intensity. Images from the three cameras were simultaneously acquired in five-minute intervals throughout many days. An algorithm to postprocess and combine the images was developed in order to maximize the probability of detection by identifying thermal anomalies (temperature contrast) resulting from the presence of the buried object in an otherwise homogeneous medium. A simplified detection metric based on contrast differences was established to allow the evaluation of the image processing method. Finite element simulations were performed, reproducing the experiment conditions and, when possible, incorporated with data coming from actual measurements. Comparisons between experiment and simulation results were performed and the simulation parameters were adjusted until images generated from both methods are matched, aiming at obtaining insights of the buried material properties. Preliminary results show a great potential for detection of shallowburied objects such as land mines and IEDs and possible identification using finite element generated maps fitting measured surface maps.

  4. SIMS study of oxygen diffusion in monoclinic HfO2

    NASA Astrophysics Data System (ADS)

    Mueller, Michael P.; De Souza, Roger A.

    2018-01-01

    The diffusion of oxygen in dense ceramics of monoclinic HfO2 was studied by means of (18O/16O) isotope exchange annealing and subsequent determination of isotope depth profiles by Secondary Ion Mass Spectrometry. Anneals were performed in the temperature range of 573 ≤T /K ≤ 973 at an oxygen partial pressure of p O2=200 mbar . All measured isotope profiles exhibited two features: the first feature, closer to the surface, was attributed mainly to slow oxygen diffusion in an impurity silicate phase; the second feature, deeper in the sample, was attributed to oxygen diffusion in bulk monoclinic HfO2 . The activation enthalpy of oxygen tracer diffusion in bulk HfO2 was found to be ΔHD∗≈0.5 eV .

  5. The design and analysis of channel transmission communication system of XCTD profiler

    NASA Astrophysics Data System (ADS)

    Zheng, Yu; Wang, Xiao-Rui; Jin, Xiang-Yu; Song, Guo-Min; Shang, Ying-Sheng; Li, Hong-Zhi

    2016-10-01

    In this paper, a channel transmission communication system of expendable conductivity-temperature-depth is established in accordance to the operation characteristics of the transmission line to more accurately assess the characteristics of deep-sea abandoned profiler channel. The wrapping inductance is eliminated to maximum extent through the wrapping pattern of the underwater spool and the overwater spool and the calculation of the wrapping diameter. The feasibility of the proposed channel transmission communication system is verified through theoretical analysis and practical measurement of the transmission signal error rate in the amplitude shift keying (ASK) modulation. The proposed design provides a new research method for the channel assessment of complex abandoned measuring instrument and an important experiment evidence for the rapid development of the deep-sea abandoned measuring instrument.

  6. The design and analysis of channel transmission communication system of XCTD profiler.

    PubMed

    Zheng, Yu; Wang, Xiao-Rui; Jin, Xiang-Yu; Song, Guo-Min; Shang, Ying-Sheng; Li, Hong-Zhi

    2016-10-01

    In this paper, a channel transmission communication system of expendable conductivity-temperature-depth is established in accordance to the operation characteristics of the transmission line to more accurately assess the characteristics of deep-sea abandoned profiler channel. The wrapping inductance is eliminated to maximum extent through the wrapping pattern of the underwater spool and the overwater spool and the calculation of the wrapping diameter. The feasibility of the proposed channel transmission communication system is verified through theoretical analysis and practical measurement of the transmission signal error rate in the amplitude shift keying (ASK) modulation. The proposed design provides a new research method for the channel assessment of complex abandoned measuring instrument and an important experiment evidence for the rapid development of the deep-sea abandoned measuring instrument.

  7. Lithium diffusion in polyether ether ketone and polyimide stimulated by in situ electron irradiation and studied by the neutron depth profiling method

    NASA Astrophysics Data System (ADS)

    Vacik, J.; Hnatowicz, V.; Attar, F. M. D.; Mathakari, N. L.; Dahiwale, S. S.; Dhole, S. D.; Bhoraskar, V. N.

    2014-10-01

    Diffusion of lithium from a LiCl aqueous solution into polyether ether ketone (PEEK) and polyimide (PI) assisted by in situ irradiation with 6.5 MeV electrons was studied by the neutron depth profiling method. The number of the Li atoms was found to be roughly proportional to the diffusion time. Regardless of the diffusion time, the measured depth profiles in PEEK exhibit a nearly exponential form, indicating achievement of a steady-state phase of a diffusion-reaction process specified in the text. The form of the profiles in PI is more complex and it depends strongly on the diffusion time. For the longer diffusion time, the profile consists of near-surface bell-shaped part due to Fickian-like diffusion and deeper exponential part.

  8. A Comparison of Sea Ice Type, Sea Ice Temperature, and Snow Thickness Distributions in the Arctic Seasonal Ice Zones with the DMSP SSM/I

    NASA Technical Reports Server (NTRS)

    St.Germain, Karen; Cavalieri, Donald J.; Markus, Thorsten

    1997-01-01

    Global climate studies have shown that sea ice is a critical component in the global climate system through its effect on the ocean and atmosphere, and on the earth's radiation balance. Polar energy studies have further shown that the distribution of thin ice and open water largely controls the distribution of surface heat exchange between the ocean and atmosphere within the winter Arctic ice pack. The thickness of the ice, the depth of snow on the ice, and the temperature profile of the snow/ice composite are all important parameters in calculating surface heat fluxes. In recent years, researchers have used various combinations of DMSP SSMI channels to independently estimate the thin ice type (which is related to ice thickness), the thin ice temperature, and the depth of snow on the ice. In each case validation efforts provided encouraging results, but taken individually each algorithm gives only one piece of the information necessary to compute the energy fluxes through the ice and snow. In this paper we present a comparison of the results from each of these algorithms to provide a more comprehensive picture of the seasonal ice zone using passive microwave observations.

  9. Muon Spin Rotation and Relaxation in LaCoO3

    NASA Astrophysics Data System (ADS)

    Giblin, Sean; Terry, Ian; Leighton, Chris; Wu, Jing

    2004-03-01

    We have performed Muon Spin Rotation and Relaxation (MUSR) measurements upon single and polycrystalline samples of LaCoO3 between 10K and 300K. The magnetic properties of LaCoO3 are believed to be dominated by a thermally induced spin transition around 80K and bulk Transverse Field MUSR has clearly identified the spin transition with a dephasing of the muons: to our knowledge this is the first time such a transition has been observed. At lower temperatures around 50K a peak in the depolarisation rate is observed suggesting another transition. We have also investigated with Zero Field MUSR, observing a superposition of decay rates below 50K, indicative of separate depolarisation mechanisms. We have repeated these measurements with low energy MUSR to obtain a depth profile of the depolarisation rate. Our results indicate the depolarisation rate is depth independent (20nm to 165nm) but the dephasing of the muons increases towards the surface of all temperatures. Using ab-initio electronic structure calculations with the CASTEP program we have been able to identify the position of the implanted muon, enabling a detailed interpretation of the MUSR data. We conclude that the low temperature MUSR results are related to the defect induced magnetism known to exist in LaCoO3.

  10. Gradient Nanostructured Tantalum by Thermal-Mechanical Ultrasonic Impact Energy.

    PubMed

    Chae, Jong-Min; Lee, Keun-Oh; Amanov, Auezhan

    2018-03-20

    Microstructural evolution and wear performance of Tantalum (Ta) treated by ultrasonic nanocrystalline surface modification (UNSM) at 25 and 1000 °C were reported. The UNSM treatment modified a surface along with subsurface layer with a thickness in the range of 20 to 150 µm, which depends on the UNSM treatment temperature, via the surface severe plastic deformation (S²PD) method. The cross-sectional microstructure of the specimens was observed by electron backscattered diffraction (EBSD) in order to confirm the microstructural alteration in terms of effective depth and refined grain size. The surface hardness measurement results, including depth profile, revealed that the hardness of the UNSM-treated specimens at both temperatures was increased in comparison with those of the untreated ones. The increase in UNSM treatment temperature led to a further increase in hardness. Moreover, both the UNSM-treated specimens with an increased hardness resulted in a higher resistance to wear in comparison with those of the untreated ones under dry conditions. The increase in hardness and induced compressive residual stress that depend on the formation of severe plastically deformed layer with the refined nano-grains are responsible for the enhancement in wear resistance. The findings of this study may be implemented in response to various industries that are related to strength improvement and wear enhancement issues of Ta.

  11. Gradient Nanostructured Tantalum by Thermal-Mechanical Ultrasonic Impact Energy

    PubMed Central

    Chae, Jong-Min; Lee, Keun-Oh; Amanov, Auezhan

    2018-01-01

    Microstructural evolution and wear performance of Tantalum (Ta) treated by ultrasonic nanocrystalline surface modification (UNSM) at 25 and 1000 °C were reported. The UNSM treatment modified a surface along with subsurface layer with a thickness in the range of 20 to 150 µm, which depends on the UNSM treatment temperature, via the surface severe plastic deformation (S2PD) method. The cross-sectional microstructure of the specimens was observed by electron backscattered diffraction (EBSD) in order to confirm the microstructural alteration in terms of effective depth and refined grain size. The surface hardness measurement results, including depth profile, revealed that the hardness of the UNSM-treated specimens at both temperatures was increased in comparison with those of the untreated ones. The increase in UNSM treatment temperature led to a further increase in hardness. Moreover, both the UNSM-treated specimens with an increased hardness resulted in a higher resistance to wear in comparison with those of the untreated ones under dry conditions. The increase in hardness and induced compressive residual stress that depend on the formation of severe plastically deformed layer with the refined nano-grains are responsible for the enhancement in wear resistance. The findings of this study may be implemented in response to various industries that are related to strength improvement and wear enhancement issues of Ta. PMID:29558402

  12. Coupled Ablation, Heat Conduction, Pyrolysis, Shape Change and Spallation of the Galileo Probe

    NASA Technical Reports Server (NTRS)

    Milos, Frank S.; Chen, Y.-K.; Rasky, Daniel J. (Technical Monitor)

    1995-01-01

    The Galileo probe enters the atmosphere of Jupiter in December 1995. This paper presents numerical methodology and detailed results of our final pre-impact calculations for the heat shield response. The calculations are performed using a highly modified version of a viscous shock layer code with massive radiation coupled with a surface thermochemical ablation and spallation model and with the transient in-depth thermal response of the charring and ablating heat shield. The flowfield is quasi-steady along the trajectory, but the heat shield thermal response is dynamic. Each surface node of the VSL grid is coupled with a one-dimensional thermal response calculation. The thermal solver includes heat conduction, pyrolysis, and grid movement owing to surface recession. Initial conditions for the heat shield temperature and density were obtained from the high altitude rarefied-flow calculations of Haas and Milos. Galileo probe surface temperature, shape, mass flux, and element flux are all determined as functions of time along the trajectory with spallation varied parametrically. The calculations also estimate the in-depth density and temperature profiles for the heat shield. All this information is required to determine the time-dependent vehicle mass and drag coefficient which are necessary inputs for the atmospheric reconstruction experiment on board the probe.

  13. The regional climate model REMO (v2015) coupled with the 1-D freshwater lake model FLake (v1): Fenno-Scandinavian climate and lakes

    NASA Astrophysics Data System (ADS)

    Pietikäinen, Joni-Pekka; Markkanen, Tiina; Sieck, Kevin; Jacob, Daniela; Korhonen, Johanna; Räisänen, Petri; Gao, Yao; Ahola, Jaakko; Korhonen, Hannele; Laaksonen, Ari; Kaurola, Jussi

    2018-04-01

    The regional climate model REMO was coupled with the FLake lake model to include an interactive treatment of lakes. Using this new version, the Fenno-Scandinavian climate and lake characteristics were studied in a set of 35-year hindcast simulations. Additionally, sensitivity tests related to the parameterization of snow albedo were conducted. Our results show that overall the new model version improves the representation of the Fenno-Scandinavian climate in terms of 2 m temperature and precipitation, but the downside is that an existing wintertime cold bias in the model is enhanced. The lake surface water temperature, ice depth and ice season length were analyzed in detail for 10 Finnish, 4 Swedish and 2 Russian lakes and 1 Estonian lake. The results show that the model can reproduce these characteristics with reasonably high accuracy. The cold bias during winter causes overestimation of ice layer thickness, for example, at several of the studied lakes, but overall the values from the model are realistic and represent the lake physics well in a long-term simulation. We also analyzed the snow depth on ice from 10 Finnish lakes and vertical temperature profiles from 5 Finnish lakes and the model results are realistic.

  14. Thermal stress cycling of GaAs solar cells

    NASA Technical Reports Server (NTRS)

    Francis, Robert W.

    1987-01-01

    Thermal stress cycling was performed on gallium arsenide solar cells to investigate their electrical, mechanical, and structural integrity. Cells were cycled under low Earth orbit (LEO) simulated temperature conditions in vacuum. Cell evaluations consisted of power output values, spectral response, optical microscopy and ion microprobe mass analysis, and depth profiles on both front surface inter-grid areas and metallization contact grid lines. Cells were examined for degradation after 500, 5,000, 10,000 and 15,245 thermal cycles. No indication of performance degradation was found for any vendor's cell lot.

  15. p-type zinc-blende GaN on GaAs substrates

    NASA Astrophysics Data System (ADS)

    Lin, M. E.; Xue, G.; Zhou, G. L.; Greene, J. E.; Morkoç, H.

    1993-08-01

    We report p-type cubic GaN. The Mg-doped layers were grown on vicinal (100) GaAs substrates by plasma-enhanced molecular beam epitaxy. Thermally sublimed Mg was, with N2 carrier gas, fed into an electron-cyclotron resonance source. p-type zinc-blende-structure GaN films were achieved with hole mobilities as high as 39 cm2/V s at room temperature. The cubic nature of the films were confirmed by x-ray diffractometry. The depth profile of Mg was investigated by secondary ions mass spectroscopy.

  16. Response to Comment on "The whole-soil carbon flux in response to warming".

    PubMed

    Hicks Pries, Caitlin E; Castanha, C; Porras, R; Phillips, Claire; Torn, M S

    2018-02-23

    Temperature records and model predictions demonstrate that deep soils warm at the same rate as surface soils, contrary to Xiao et al 's assertions. In response to Xiao et al 's critique of our Q 10 analysis, we present the results with all data points included, which show Q 10 values of >2 throughout the soil profile, indicating that all soil depths responded to warming. Copyright © 2018 The Authors, some rights reserved; exclusive licensee American Association for the Advancement of Science. No claim to original U.S. Government Works.

  17. Simulation of hydrodynamics, water quality, and lake sturgeon habitat volumes in Lake St. Croix, Wisconsin and Minnesota, 2013

    USGS Publications Warehouse

    Smith, Erik A.; Kiesling, Richard L.; Ziegeweid, Jeffrey R.; Elliott, Sarah M.; Magdalene, Suzanne

    2018-01-05

    Lake St. Croix is a naturally impounded, riverine lake that makes up the last 40 kilometers of the St. Croix River. Substantial land-use changes during the past 150 years, including increased agriculture and urban development, have reduced Lake St. Croix water-quality and increased nutrient loads delivered to Lake St. Croix. A recent (2012–13) total maximum daily load phosphorus-reduction plan set the goal to reduce total phosphorus loads to Lake St. Croix by 20 percent by 2020 and reduce Lake St. Croix algal bloom frequencies. The U.S. Geological Survey, in cooperation with the National Park Service, developed a two-dimensional, carbon-based, laterally averaged, hydrodynamic and water-quality model, CE–QUAL–W2, that addresses the interaction between nutrient cycling, primary production, and trophic dynamics to predict responses in the distribution of water temperature, oxygen, and chlorophyll a. Distribution is evaluated in the context of habitat for lake sturgeon, including a combination of temperature and dissolved oxygen conditions termed oxy-thermal habitat.The Lake St. Croix CE–QUAL–W2 model successfully reproduced temperature and dissolved oxygen in the lake longitudinally (from upstream to downstream), vertically, and temporally over the seasons. The simulated water temperature profiles closely matched the measured water temperature profiles throughout the year, including the prediction of thermocline transition depths (often within 1 meter), the absolute temperature of the thermocline transitions (often within 1.0 degree Celsius), and profiles without a strong thermocline transition. Simulated dissolved oxygen profiles matched the trajectories of the measured dissolved oxygen concentrations at multiple depths over time, and the simulated concentrations matched the depth and slope of the measured concentrations.Additionally, trends in the measured water-quality data were captured by the model simulation, gaining some potential insights into the underlying mechanisms of critical Lake St. Croix metabolic processes. The CE–QUAL–W2 model tracked nitrate plus nitrite, total nitrogen, and total phosphorus throughout the year. Inflow nutrient contributions (loads), largely dominated by upstream St. Croix River loads, were the most important controls on Lake St. Croix water quality. Close to 60 percent of total phosphorus to the lake was from phosphorus derived from organic matter, and about 89 percent of phosphorus to Lake St. Croix was delivered by St. Croix River inflows. The Lake St. Croix CE–QUAL–W2 model offered potential mechanisms for the effect of external and internal loadings on the biotic response regarding the modeled algal community types of diatoms, green algae, and blue-green algae. The model also suggested the seasonal dominance of blue-green algae in all four pools of the lake.A sensitivity analysis was completed to test the total maximum daily load phosphorus-reduction scenario responses of total phosphorus and chlorophyll a. The modeling indicates that phosphorus reductions would result in similar Lake St. Croix reduced concentrations, although chlorophyll a concentrations did not decrease in the same proportional amounts as the total phosphorus concentrations had decreased. The smaller than expected reduction in algal growth rates highlighted that although inflow phosphorus loads are important, other constituents also can affect the algal response of the lake, such as changes in light penetration and the breakdown of organic matter releasing nutrients.The available habitat suitable for lake sturgeon was evaluated using the modeling results to determine the total volume of good-growth habitat, optimal growth habitat, and lethal temperature habitat. Overall, with the calibrated model, the fish habitat volume in general contained a large proportion of good-growth habitat and a sustained period of optimal growth habitat in the summer. Only brief periods of lethal oxy-thermal habitat were present in Lake St. Croix during the model simulation.

  18. Soil thermal properties at two different sites on James Ross Island in the period 2012/13

    NASA Astrophysics Data System (ADS)

    Hrbáček, Filip; Láska, Kamil

    2015-04-01

    James Ross Island (JRI) is the largest island in the eastern part of the Antarctic Peninsula. Ulu Peninsula in the northern part of JRI is considered the largest ice free area in the Maritime Antarctica region. However, information about permafrost on JRI, active layer and its soil properties in general are poorly known. In this study, results of soil thermal measurements at two different sites on Ulu Peninsula are presented between 1 April 2012 and 30 April 2013. The study sites are located (1) on an old Holocene marine terrace (10 m a. s. l.) in the closest vicinity of Johann Gregor Mendel (JGM) Station and (2) on top of a volcanic plateau named Johnson Mesa (340 m a. s. l.) about 4 km south of the JGM Station. The soil temperatures were measured at 30 min interval using platinum resistance thermometers Pt100/8 in two profiles up to 200 cm at JGM Station and 75 cm at Johnson Mesa respectively. Decagon 10HS volumetric water content sensors were installed up 30 cm at Johnson Mesa to 50 cm at JGM Station, while Hukseflux HFP01 soil heat flux sensors were used for direct monitoring of soil physical properties at 2.5 cm depth at both sites. The mean soil temperature varied between -5.7°C at 50 cm and -6.3°C at 5 cm at JGM Station, while that for Johnson Mesa varied between -6.9°C at 50 cm and -7.1°C at 10 cm. Maximum active layer thickness estimated from 0 °C isotherm reached 52 cm at JGM Station and 50 cm at Johnson Mesa respectively which corresponded with maximum observed annual temperature at 50 cm at both sites. The warmest part of both profiles detected at 50 cm depth corresponded with maximum thickness of active layer, estimated from 0°C isotherm, reached 52 cm at JGM Station and 50 cm at Johnson Mesa respectively. Volumetric water content at 5 cm varied around 0.25 m3m-3 at both sites. The slight increase to 0.32 m3m-3 was observed at JGM Station at 50 cm and at Johnson Mesa at 30 cm depth. Soil texture analysis showed distinctly higher share of coarser fraction >2 mm at Johnson Mesa than at JGM Station. Comparison of both sites indicated that mean ground temperature at 50 cm depth was higher by 1.2 °C at JGM station, although the active layer was thicker by 2 cm only. It can therefore be concluded that soil physical properties like texture and moisture may significantly affect thermal regime at boundary between AL and permafrost table during individual thawing seasons.

  19. Modeling ground thermal regime of an ancient buried ice body in Beacon Valley, Antarctica using a 1-D heat equation with latent heat effect

    NASA Astrophysics Data System (ADS)

    Liu, L.; Sletten, R. S.; Hallet, B.; Waddington, E. D.; Wood, S. E.

    2013-12-01

    An ancient massive ice body buried under several decimeters of debris in Beacon Valley, Antarctica is believed to be over one million years old, making it older than any known glacier or ice cap. It is fundamentally important as a reservoir of water, proxy for climatic information, and an expression of the periglacial landscape. It is also one of Earth's closest analog for widespread, near-surface ice found in Martian soils and ice-cored landforms. We are interested in understanding controls on how long this ice may persist since our physical model of sublimation suggests it should not be stable. In these models, the soil temperatures and the gradient are important because it determines the direction and magnitude of the vapor flux, and thus sublimation rates. To better understand the heat transfer processes and constrain the rates of processes governing ground ice stability, a model of the thermal behavior of the permafrost is applied to Beacon Valley, Antarctica. It calculates soil temperatures based on a 1-D thermal diffusion equation using a fully implicit finite volume method (FVM). This model is constrained by soil physical properties and boundary conditions of in-situ ground surface temperature measurements (with an average of -23.6oC, a maximum of 20.5oC and a minimum of -54.3oC) and ice-core temperature record at ~30 m. Model results are compared to in-situ temperature measurements at depths of 0.10 m, 0.20 m, 0.30 m, and 0.45 m to assess the model's ability to reproduce the temperature profile for given thermal properties of the debris cover and ice. The model's sensitivity to the thermal diffusivity of the permafrost and the overlaying debris is also examined. Furthermore, we incorporate the role of ice condensation/sublimation which is calculated using our vapor diffusion model in the 1-D thermal diffusion model to assess potential latent heat effects that in turn affect ground ice sublimation rates. In general, the model simulates the ground thermal regime well. Detailed temperature comparison suggests that the 1-D thermal diffusion model results closely approximate the measured temperature at all depths with the average square root of the mean squared error (SRMSE) of 0.15oC; a linear correlation between modeled and measured temperatures yields an average R2 value of 0.9997. Prominent seasonal temperature variations diminish with depth, and it equilibrates to mean annual temperature at about 21.5 m depth. The amount of heat generated/consumed by ice condensation/sublimation is insufficient to significantly impact the thermal regime.

  20. Towards nanometric resolution in multilayer depth profiling: a comparative study of RBS, SIMS, XPS and GDOES.

    PubMed

    Escobar Galindo, Ramón; Gago, Raul; Duday, David; Palacio, Carlos

    2010-04-01

    An increasing amount of effort is currently being directed towards the development of new functionalized nanostructured materials (i.e., multilayers and nanocomposites). Using an appropriate combination of composition and microstructure, it is possible to optimize and tailor the final properties of the material to its final application. The analytical characterization of these new complex nanostructures requires high-resolution analytical techniques that are able to provide information about surface and depth composition at the nanometric level. In this work, we comparatively review the state of the art in four different depth-profiling characterization techniques: Rutherford backscattering spectroscopy (RBS), secondary ion mass spectrometry (SIMS), X-ray photoelectron spectroscopy (XPS) and glow discharge optical emission spectroscopy (GDOES). In addition, we predict future trends in these techniques regarding improvements in their depth resolutions. Subnanometric resolution can now be achieved in RBS using magnetic spectrometry systems. In SIMS, the use of rotating sample holders and oxygen flooding during analysis as well as the optimization of floating low-energy ion guns to lower the impact energy of the primary ions improves the depth resolution of the technique. Angle-resolved XPS provides a very powerful and nondestructive technique for obtaining depth profiling and chemical information within the range of a few monolayers. Finally, the application of mathematical tools (deconvolution algorithms and a depth-profiling model), pulsed sources and surface plasma cleaning procedures is expected to greatly improve GDOES depth resolution.

  1. High-resolution depth profiling using a range-gated CMOS SPAD quanta image sensor.

    PubMed

    Ren, Ximing; Connolly, Peter W R; Halimi, Abderrahim; Altmann, Yoann; McLaughlin, Stephen; Gyongy, Istvan; Henderson, Robert K; Buller, Gerald S

    2018-03-05

    A CMOS single-photon avalanche diode (SPAD) quanta image sensor is used to reconstruct depth and intensity profiles when operating in a range-gated mode used in conjunction with pulsed laser illumination. By designing the CMOS SPAD array to acquire photons within a pre-determined temporal gate, the need for timing circuitry was avoided and it was therefore possible to have an enhanced fill factor (61% in this case) and a frame rate (100,000 frames per second) that is more difficult to achieve in a SPAD array which uses time-correlated single-photon counting. When coupled with appropriate image reconstruction algorithms, millimeter resolution depth profiles were achieved by iterating through a sequence of temporal delay steps in synchronization with laser illumination pulses. For photon data with high signal-to-noise ratios, depth images with millimeter scale depth uncertainty can be estimated using a standard cross-correlation approach. To enhance the estimation of depth and intensity images in the sparse photon regime, we used a bespoke clustering-based image restoration strategy, taking into account the binomial statistics of the photon data and non-local spatial correlations within the scene. For sparse photon data with total exposure times of 75 ms or less, the bespoke algorithm can reconstruct depth images with millimeter scale depth uncertainty at a stand-off distance of approximately 2 meters. We demonstrate a new approach to single-photon depth and intensity profiling using different target scenes, taking full advantage of the high fill-factor, high frame rate and large array format of this range-gated CMOS SPAD array.

  2. Auger analysis of a fiber/matrix interface in a ceramic matrix composite

    NASA Technical Reports Server (NTRS)

    Honecy, Frank S.; Pepper, Stephen V.

    1988-01-01

    Auger electron spectroscopy (AES) depth profiling was used to characterize the fiber/matrix interface of an SiC fiber, reaction bonded Si3N4 matrix composite. Depth profiles of the as received double coated fiber revealed concentration oscillations which disappeared after annealing the fiber in the environment used to fabricate the composite. After the composite was fractured, the Auger depth profiles showed that failure occurred in neither the Beta-SiC fiber body nor in the Si3N4 matrix but, concurrently, at the fiber coating/matrix interface and within the fiber coating itself.

  3. Sea surface cooling in the Northern South China Sea observed using Chinese sea-wing underwater glider measurements

    NASA Astrophysics Data System (ADS)

    Qiu, Chunhua; Mao, Huabin; Yu, Jiancheng; Xie, Qiang; Wu, Jiaxue; Lian, Shumin; Liu, Qinyan

    2015-11-01

    Based on 26 days of Chinese Sea-wing underwater glider measurements and satellite microwave data, we documented cooling of the upper mixed layer of the ocean in response to changes in the wind in the Northern South China Sea (NSCS) from September 19, 2014, to October 15, 2014. The Sea-wing underwater glider measured 177 profiles of temperature, salinity, and pressure within a 55 km×55 km area, and reached a depth of 1000 m at a temporal resolution of ∼4 h. The study area experienced two cooling events, Cooling I and Cooling II, according to their timing. During Cooling I, water temperature at 1-m depth (T1) decreased by ∼1.0 °C, and the corresponding satellite-derived surface winds increased locally by 4.2 m/s. During Cooling II, T1 decreased sharply by 1.7 °C within a period of 4 days; sea surface winds increased by 7 m/s and covered the entire NSCS. The corresponding mixed layer depth (MLD) deepened sharply from 30 m to 60 m during Cooling II, and remained steady during Cooling I. We estimated temperature tendencies using a ML model. High resolution Sea-wing underwater glider measurements provided an estimation of MLD migration, allowing us to obtain the temporal entrainment rate of cool sub-thermocline water. Quantitative analysis confirmed that the entrainment rate and latent heat flux were the two major components that regulated cooling of the ML, and that the Ekman advection and sensible heat flux were small.

  4. Lateral changes in temperature at the base of the Laurentide ice sheet inferred from borehole temperature data

    NASA Astrophysics Data System (ADS)

    Mareschal, J.; Rolandone, F.; Jaupart, C.

    2001-12-01

    Three temperature depth profiles from very deep (1720-2800m) boreholes in Canada were inverted to determine temporal changes in ground surface temperature. These boreholes are sufficiently deep to be affected by the ground surface temperature during and after the last glacial episode when the three sites were beneath the Laurentide ice sheet. At Sept Iles, Québec, on the north shore of the Bay of St Lawrence, the inversion of an 1820m deep profile suggests that temperature was <-4 \\deg C at the end of the Last Glacial Maximum, vs 3 \\deg C now. For FlinFlon, Manitoba, the inversion of a 2800m hole suggests that ground temperature was moderately colder (≈-1\\deg C) at the end of the LGM than at present (≈3\\deg C). This result is within the bounds suggested by Sass et al. [1971]. For a 1720m deeep borehole near Balmertown, Ontario, northwest of Lake Superior, the inversion shows almost no change in ground surface temperature (3+/-1 \\deg C) for the past 50,000 years. The difference between Balmertown and FlinFlon is difficult to explain within the framework of accepted ice sheet models because the two sites are at about the same distance from the center of the ice sheet and have experienced the same ice accumulation history. Simple models will be presented that explain how the temperature at the base of a large glacier is affected by the geometry and the flow of the ice sheet. Sass, J.H., A.H. Lachenbruch, & A.M. Jessop, Uniform heat flow in a deep hole in the Canadian Shield and its paleoclimatic implications, J. Geophys. Res., 76, 8586-8596, 1971.

  5. Measurement and inference of profile soil-water dynamics at different hillslope positions in a semiarid agricultural watershed

    NASA Astrophysics Data System (ADS)

    Green, Timothy R.; Erskine, Robert H.

    2011-12-01

    Dynamics of profile soil water vary with terrain, soil, and plant characteristics. The objectives addressed here are to quantify dynamic soil water content over a range of slope positions, infer soil profile water fluxes, and identify locations most likely influenced by multidimensional flow. The instrumented 56 ha watershed lies mostly within a dryland (rainfed) wheat field in semiarid eastern Colorado. Dielectric capacitance sensors were used to infer hourly soil water content for approximately 8 years (minus missing data) at 18 hillslope positions and four or more depths. Based on previous research and a new algorithm, sensor measurements (resonant frequency) were rescaled to estimate soil permittivity, then corrected for temperature effects on bulk electrical conductivity before inferring soil water content. Using a mass-conservation method, we analyzed multitemporal changes in soil water content at each sensor to infer the dynamics of water flux at different depths and landscape positions. At summit positions vertical processes appear to control profile soil water dynamics. At downslope positions infrequent overland flow and unsaturated subsurface lateral flow appear to influence soil water dynamics. Crop water use accounts for much of the variability in soil water between transects that are either cropped or fallow in alternating years, while soil hydraulic properties and near-surface hydrology affect soil water variability across landscape positions within each management zone. The observed spatiotemporal patterns exhibit the joint effects of short-term hydrology and long-term soil development. Quantitative methods of analyzing soil water patterns in space and time improve our understanding of dominant soil hydrological processes and provide alternative measures of model performance.

  6. An Alternate Method for Estimating Dynamic Height from XBT Profiles Using Empirical Vertical Modes

    NASA Technical Reports Server (NTRS)

    Lagerloef, Gary S. E.

    1994-01-01

    A technique is presented that applies modal decomposition to estimate dynamic height (0-450 db) from Expendable BathyThermograph (XBT) temperature profiles. Salinity-Temperature-Depth (STD) data are used to establish empirical relationships between vertically integrated temperature profiles and empirical dynamic height modes. These are then applied to XBT data to estimate dynamic height. A standard error of 0.028 dynamic meters is obtained for the waters of the Gulf of Alaska- an ocean region subject to substantial freshwater buoyancy forcing and with a T-S relationship that has considerable scatter. The residual error is a substantial improvement relative to the conventional T-S correlation technique when applied to this region. Systematic errors between estimated and true dynamic height were evaluated. The 20-year-long time series at Ocean Station P (50 deg N, 145 deg W) indicated weak variations in the error interannually, but not seasonally. There were no evident systematic alongshore variations in the error in the ocean boundary current regime near the perimeter of the Alaska gyre. The results prove satisfactory for the purpose of this work, which is to generate dynamic height from XBT data for coanalysis with satellite altimeter data, given that the altimeter height precision is likewise on the order of 2-3 cm. While the technique has not been applied to other ocean regions where the T-S relation has less scatter, it is suggested that it could provide some improvement over previously applied methods, as well.

  7. Atmospheric Structure and Diurnal Variations at Low Altitudes in the Martian Tropics

    NASA Astrophysics Data System (ADS)

    Hinson, David P.; Spiga, A.; Lewis, S.; Tellmann, S.; Pätzold, M.; Asmar, S.; Häusler, B.

    2013-10-01

    We are using radio occultation measurements from Mars Express, Mars Reconnaissance Orbiter, and Mars Global Surveyor to characterize the diurnal cycle in the lowest scale height above the surface. We focus on northern spring and summer, using observations from 4 Martian years at local times of 4-5 and 15-17 h. We supplement the observations with results obtained from large-eddy simulations and through data assimilation by the UK spectral version of the LMD Mars Global Circulation Model. We previously investigated the depth of the daytime convective boundary layer (CBL) and its variations with surface elevation and surface properties. We are now examining unusual aspects of the temperature structure observed at night. Most important, predawn profiles in the Tharsis region contain an unexpected layer of neutral static stability at pressures of 200-300 Pa with a depth of 4-5 km. The mixed layer is bounded above by a midlevel temperature inversion and below by another strong inversion adjacent to the surface. The narrow temperature minimum at the base of the midlevel inversion suggests the presence of a water ice cloud layer, with the further implication that radiative cooling at cloud level can induce convective activity at lower altitudes. Conversely, nighttime profiles in Amazonis show no sign of a midlevel inversion or a detached mixed layer. These regional variations in the nighttime temperature structure appear to arise in part from large-scale variations in topography, which have several notable effects. First, the CBL is much deeper in the Tharsis region than in Amazonis, owing to a roughly 6-km difference in surface elevation. Second, large-eddy simulations show that daytime convection is not only deeper above Tharsis but also considerably more intense than it is in Amazonis. Finally, the daytime surface temperatures are comparable in the two regions, so that Tharsis acts as an elevated heat source throughout the CBL. These topographic effects are expected to enhance the vertical mixing of water vapor above elevated terrain, which might lead to the formation and regional confinement of nighttime clouds.

  8. Soil moisture, dielectric permittivity and emissivity of soil: effective depth of emission measured by the L-band radiometer ELBARA

    NASA Astrophysics Data System (ADS)

    Usowicz, Boguslaw; Lukowski, Mateusz; Marczewski, Wojciech; Usowicz, Jerzy; Lipiec, Jerzy; Rojek, Edyta; Slominska, Ewa; Slominski, Jan

    2014-05-01

    Due to the large variation of soil moisture in space and in time, obtaining soil water balance with an aid of data acquired from the surface is still a challenge. Microwave remote sensing is widely used to determine the water content in soil. It is based on the fact that the dielectric constant of the soil is strongly dependent on its water content. This method provides the data in both local and global scales. Very important issue that is still not solved, is the soil depth at which radiometer "sees" the incoming radiation and how this "depth of view" depends on water content and physical properties of soil. The microwave emission comes from its entire profile, but much of this energy is absorbed by the upper layers of soil. As a result, the contribution of each layer to radiation visible for radiometer decreases with depth. The thickness of the surface layer, which significantly contributes to the energy measured by the radiometer is defined as the "penetration depth". In order to improve the physical base of the methodology of soil moisture measurements using microwave remote sensing and to determine the effective emission depth seen by the radiometer, a new algorithm was developed. This algorithm determines the reflectance coefficient from Fresnel equations, and, what is new, the complex dielectric constant of the soil, calculated from the Usowicz's statistical-physical model (S-PM) of dielectric permittivity and conductivity of soil. The model is expressed in terms of electrical resistance and capacity. The unit volume of soil in the model consists of solid, water and air, and is treated as a system made up of spheres, filling volume by overlapping layers. It was assumed that connections between layers and spheres in the layer are represented by serial and parallel connections of "resistors" and "capacitors". The emissivity of the soil surface is calculated from the ratio between the brightness temperature measured by the ELBARA radiometer (GAMMA Remote Sensing AG) and the physical temperature of the soil surface measured by infrared sensor. As the input data for S-PM: volumes of soil components, mineralogical composition, organic matter content, specific surface area and bulk density of the soil were used. Water contents in the model are iteratively changed, until emissivities calculated from the S-PM reach the best agreement with emissivities measured by the radiometer. Final water content will correspond to the soil moisture measured by the radiometer. Then, the examined soil profile will be virtually divided into thin slices where moisture, temperature and thermal properties will be measured and simultaneously modelled via S-PM. In the next step, the slices will be "added" starting from top (soil surface), until the effective soil moisture will be equal to the soil moisture measured by ELBARA. The thickness of obtained stack will be equal to desired "penetration depth". Moreover, it will be verified further by measuring the moisture content using thermal inertia. The work was partially funded by the Government of Poland through an ESA Contract under the PECS ELBARA_PD project No. 4000107897/13/NL/KML.

  9. Water quality of Lake Tuscaloosa and streamflow and water quality of selected tributaries to Lake Tuscaloosa, Alabama, 1982-86

    USGS Publications Warehouse

    Slack, L.J.

    1987-01-01

    Lake Tuscaloosa, created in 1969 by the impoundment of North River, provides the primary water supply for Tuscaloosa, Alabama , and surrounding areas. This report describes the percent contribution of major tributaries to the mean inflow to the lake; water quality; and changes in water quality in the lake and selected tributaries. During base flow, about 60% of the total flow into Lake Tuscaloosa is contributed by Binion and Carroll Creeks, which drain only 22% of the Lake Tuscaloosa basin. Binion and Carroll Creek basins are underlain primarily by sand and gravel deposits of the Coker Formation. Mean inflow to the lake was 1,150 cu ft/sec during 1983, a wet year, and 450 cu ft/sec during 1985, a relatively dry year. More than 80% of the total inflow during both years was contributed by North River and Binion, Cripple, and Carroll Creeks. About 59% was contributed by North River during those years. Except for pH, sulfate, and dissolved and total recoverable iron and manganese, the water quality of the tributaries is generally within drinking water limits and acceptable for most uses. The water quality of Lake Tuscaloosa is generally within drinking water limits and acceptable for most uses. The maximum and median concentrations of sulfate increased every year at the dam from 1979 to 1985 (7.2 to 18 mg/L and 6.2 to 14 mg/L, respectively). The dissolved solids concentrations for water at the dam have varied (1979-86) from 27 to 43 mg/L; the sulfate, 5.2 to 18 mg/L; and the dissolved iron, 10 to 250 micrograms/L--all within the recommended drinking water limits. However, concentrations of dissolved manganese and total recoverable iron and manganese at the dam commonly exceeded the recommended drinking water limits. In November 1985, after the summer warmup and increase in biological activity, the water quality at five depth profiles sites on Lake Tuscaloosa was acceptable for most uses, generally. However, a dissolved oxygen concentration of 1 mg/L or less was observed within 5 to 10 ft of the bottom for several depth profiles. At depths > 35 to 40 ft (out of a total depth of about 50 to 100 ft) the dissolved oxygen concentration was < 5 mg/L at several sites. By mid-January 1986, the temperature and dissolved oxygen depth profiles were virtually constant from top to bottom of the lake at all five sites; this indicated that lake turnover was complete. However, significant variation existed in pH depth profiles. (Author 's abstract)

  10. SAM 2 measurements of the polar stratospheric aerosol. Volume 9: October 1982 - April 1983

    NASA Technical Reports Server (NTRS)

    Mcmaster, L. R.; Powell, K. A.

    1991-01-01

    The Stratospheric Aerosol Measurement (SAM) II sensor aboard Nimbus 7 is providing 1.0 micron extinction measurements of Antarctic and Arctic stratospheric aerosols with a vertical resolution of 1 km. Representative examples and weekly averages including corresponding temperature profiles provided by NOAA for the time and place of each SAM II measurement are presented. Contours of aerosol extinction as a function of altitude and longitude or time are plotted, and aerosol optical depths are calculated for each week. Typical values of aerosol extinction and stratospheric optical depth in the Arctic are unusually large due to the presence of material from the El Chichon volcano eruption in the Spring of 1982. For example, the optical depth peaked at 0.068, more than 50 times background values. Typical values of aerosol extinction and stratospheric optical depth in the Antarctic varied considerably during this period due to the transport and arrival of the material from the El Chichon eruption. For example, the stratospheric optical depth varied from 0.002 in October 1982, to 0.021 in January 1983. Polar stratospheric clouds were observed during the Arctic winter, as expected. A representative sample is provided of the ninth 6-month period of data to be used in atmospheric and climatic studies.

  11. Analysing the mechanisms of soil water and vapour transport in the desert vadose zone of the extremely arid region of northern China

    NASA Astrophysics Data System (ADS)

    Du, Chaoyang; Yu, Jingjie; Wang, Ping; Zhang, Yichi

    2018-03-01

    The transport of water and vapour in the desert vadose zone plays a critical role in the overall water and energy balances of near-surface environments in arid regions. However, field measurements in extremely dry environments face many difficulties and challenges, so few studies have examined water and vapour transport processes in the desert vadose zone. The main objective of this study is to analyse the mechanisms of soil water and vapour transport in the desert vadose zone (depth of ∼350 cm) by using measured and modelled data in an extremely arid environment. The field experiments are implemented in an area of the Gobi desert in northwestern China to measure the soil properties, daily soil moisture and temperature, daily water-table depth and temperature, and daily meteorological records from DOYs (Days of Year) 114-212 in 2014 (growing season). The Hydrus-1D model, which simulates the coupled transport of water, vapour and heat in the vadose zone, is employed to simulate the layered soil moisture and temperature regimes and analyse the transport processes of soil water and vapour. The measured results show that the soil water and temperatures near the land surface have visible daily fluctuations across the entire soil profile. Thermal vapour movement is the most important component of the total water flux and the soil temperature gradient is the major driving factor that affects vapour transport in the desert vadose zone. The most active water and heat exchange occurs in the upper soil layer (depths of 0-25 cm). The matric potential change from the precipitation mainly re-draws the spatio-temporal distribution of the isothermal liquid water in the soil near the land surface. The matric potential has little effect on the isothermal vapour and thermal liquid water flux. These findings offer new insights into the liquid water and vapour movement processes in the extremely arid environment.

  12. Response of seasonal soil freeze depth to climate change across China

    NASA Astrophysics Data System (ADS)

    Peng, Xiaoqing; Zhang, Tingjun; Frauenfeld, Oliver W.; Wang, Kang; Cao, Bin; Zhong, Xinyue; Su, Hang; Mu, Cuicui

    2017-05-01

    The response of seasonal soil freeze depth to climate change has repercussions for the surface energy and water balance, ecosystems, the carbon cycle, and soil nutrient exchange. Despite its importance, the response of soil freeze depth to climate change is largely unknown. This study employs the Stefan solution and observations from 845 meteorological stations to investigate the response of variations in soil freeze depth to climate change across China. Observations include daily air temperatures, daily soil temperatures at various depths, mean monthly gridded air temperatures, and the normalized difference vegetation index. Results show that soil freeze depth decreased significantly at a rate of -0.18 ± 0.03 cm yr-1, resulting in a net decrease of 8.05 ± 1.5 cm over 1967-2012 across China. On the regional scale, soil freeze depth decreases varied between 0.0 and 0.4 cm yr-1 in most parts of China during 1950-2009. By investigating potential climatic and environmental driving factors of soil freeze depth variability, we find that mean annual air temperature and ground surface temperature, air thawing index, ground surface thawing index, and vegetation growth are all negatively associated with soil freeze depth. Changes in snow depth are not correlated with soil freeze depth. Air and ground surface freezing indices are positively correlated with soil freeze depth. Comparing these potential driving factors of soil freeze depth, we find that freezing index and vegetation growth are more strongly correlated with soil freeze depth, while snow depth is not significant. We conclude that air temperature increases are responsible for the decrease in seasonal freeze depth. These results are important for understanding the soil freeze-thaw dynamics and the impacts of soil freeze depth on ecosystem and hydrological process.

  13. Decalin-assisted light emitting porous Si formation and its optical, surface and morphological properties

    NASA Astrophysics Data System (ADS)

    Karatutlu, Ali; Istengir, Sumeyra; Cosgun, Sedat; Seker, Isa; Unal, Bayram

    2017-11-01

    In this research paper, light emitting porous silicon (Lep-Si) samples were fabricated by a surfactant-mediated chemical stain etching solution in order to form homogenous luminescent nanostructures at room temperature. As an industrially important solvent, decalin (decahydronaphtalene) was used as a surfactant in the HF/HNO3 solutions in order to control the etching process. Morphological, surface and optical properties of the Lep-Si samples were examined using atomic force microscopy, X-ray photoelectron spectroscopy, photoluminescence (PL) spectroscopy, and laser scanning confocal microscopy (LSCM) techniques. These characterization techniques were correlated with the various etching times including depth dependent luminescence profiles for the first time. We report the optimum conditions for production of the most efficient Lep-Si using decalin (decahydronaphtalene) and possible structural origins of light emission using the depth dependent luminescence measurements.

  14. Atomic transport during solid-phase epitaxial recrystallization of amorphous germanium

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Radek, M.; Bracht, H., E-mail: bracht@uni-muenster.de; Johnson, B. C.

    2015-08-24

    The atomic mixing of matrix atoms during solid-phase epitaxy (SPE) is studied by means of isotopically enriched germanium (Ge) multilayer structures that were amorphized by Ge ion implantation up to a depth of 1.5 μm. Recrystallization of the amorphous structure is performed at temperatures between 350 °C and 450 °C. Secondary-ion-mass-spectrometry is used to determine the concentration-depth profiles of the Ge isotope before and after SPE. An upper limit of 0.5 nm is deduced for the displacement length of the Ge matrix atoms by the SPE process. This small displacement length is consistent with theoretical models and atomistic simulations of SPE, indicating that themore » SPE mechanism consists of bond-switching with nearest-neighbours across the amorphous-crystalline (a/c) interface.« less

  15. Relationship between the upper mantle high velocity seismic lid and the continental lithosphere

    NASA Astrophysics Data System (ADS)

    Priestley, Keith; Tilmann, Frederik

    2009-04-01

    The lithosphere-asthenosphere boundary corresponds to the base of the "rigid" plates - the depth at which heat transport changes from advection in the convecting deeper upper mantle to conduction in the shallow upper mantle. Although this boundary is a fundamental feature of the Earth, mapping it has been difficult because it does not correspond to a sharp change in temperature or composition. Various definitions of the lithosphere and asthenosphere are based on the analysis of different types of geophysical and geological observations. The depth to the lithosphere-asthenosphere boundary determined from these different observations often shows little agreement when they are applied to the same region because the geophysical and geological observations (i.e., seismic velocity, strain rate, electrical resistivity, chemical depletion, etc.) are proxies for the change in rheological properties rather than a direct measure of the rheological properties. In this paper, we focus on the seismic mapping of the upper mantle high velocity lid and low velocity zone and its relationship to the lithosphere and asthenosphere. We have two goals: (a) to examine the differences in how teleseismic body-wave travel-time tomography and surface-wave tomography image upper mantle seismic structure; and (b) to summarise how upper mantle seismic velocity structure can be related to the structure of the lithosphere and asthenosphere. Surface-wave tomography provides reasonably good depth resolution, especially when higher modes are included in the analysis, but lateral resolution is limited by the horizontal wavelength of the long-period surface waves used to constrain upper mantle velocity structure. Teleseismic body-wave tomography has poor depth resolution in the upper mantle, particularly when no strong lateral contrasts are present. If station terms are used, features with large lateral extent and gradual boundaries are attenuated in the tomographic image. Body-wave models are not useful in mapping the thickness of the high velocity upper mantle lid because this type of analysis often determines wave speed perturbations from an unknown horizontal average and not absolute velocities. Thus, any feature which extends laterally across the whole region beneath a seismic network becomes invisible in the teleseismic body-wave tomographic image. We compare surface-wave and body-wave tomographic results using southern Africa as an example. Surface-wave tomographic images for southern Africa show a strong, high velocity upper mantle lid confined to depths shallower than ~ 200 km, whereas body-wave tomographic images show weak high velocity in the upper mantle extending to depths of ~ 300 km or more. However, synthetic tests show that these results are not contradictory. The absolute seismic velocity structure of the upper mantle provided by surface wave analysis can be used to map the thermal lithosphere. Priestley and McKenzie (Priestley, K., McKenzie, D., 2006. The thermal structure of the lithosphere from shear wave velocities. Earth and Planetary Science Letters 244, 285-301.) derive an empirical relationship between shear wave velocity and temperature. This relationship is used to obtain temperature profiles from the surface-wave tomographic models of the continental mantle. The base of the lithosphere is shown by a change in the gradient of the temperature profiles indicative of the depth where the mode of heat transport changes from conduction to advection. Comparisons of the geotherms determined from the conversion of surface-wave wave speeds to temperatures with upper mantle nodule-derived geotherms demonstrate that estimates of lithospheric thickness from Vs and from the nodule mineralogy agree to within about 25 km. The lithospheric thickness map for Africa derived from the surface-wave tomographic results shows that thick lithosphere underlies most of the Archean crust in Africa. The distribution of diamondiferous kimberlites provides an independent estimate of where thick lithosphere exists. Diamondiferous kimberlites generally occur where the lower part of the thermal lithosphere as indicated by seismology is in the diamond stability field.

  16. Determination of rare earth elements concentration at different depth profile of Precambrian pegmatites using instrumental neutron activation analysis.

    PubMed

    Sadiq Aliyu, Abubakar; Musa, Yahaya; Liman, M S; Abba, Habu T; Chaanda, Mohammed S; Ngene, Nnamani C; Garba, N N

    2018-01-01

    The Keffi area hosts abundant pegmatite bodies as a result of the surrounding granitic intrusions. Keffi is part of areas that are geologically classified as North Central Basement Complex. Data on the mineralogy and mineralogical zonation of the Keffi pegmatite are scanty. Hence the need to understand the geology and mineralogical zonation of Keffi pegmatites especially at different depth profiles is relevant as a study of the elemental composition of the pegmatite is essential for the estimation of its economic viability. Here, the relative standardization method of instrumental neutron activation analysis (INAA) has been used to investigate the vertical deviations of the elemental concentrations of rare earth elements (REEs) at different depth profile of Keffi pegmatite. This study adopted the following metrics in investigating the vertical variations of REEs concentrations. Namely, the total contents of rare earth elements (∑REE); ratio of light to heavy rare earth elements (LREE/HREE), which defines the enrichment or depletion of REEs; europium anomaly (Eu/Sm); La/Lu ratio relative to chondritic meteorites. The study showed no significant variations in the total content of rare elements between the vertical depth profiles (100-250m). However, higher total concentrations of REEs (~ 92.65ppm) were recorded at the upper depth of the pegmatite and the europium anomaly was consistently negative at all the depth profiles suggesting that the Keffi pegmatite is enriched with light REEs. Copyright © 2017 Elsevier Ltd. All rights reserved.

  17. Gas buildup in Lake Nyos, Cameroon: The recharge process and its consequences

    USGS Publications Warehouse

    Evans, William C.; Kling, G.W.; Tuttle, M.L.; Tanyileke, G.; White, L.D.

    1993-01-01

    The gases dissolved in Lake Nyos, Cameroon, were quantified recently (December 1989 and September 1990) by two independent techniques: in-situ measurements using a newly designed probe and laboratory analyses of samples collected in pre-evacuated stainless steel cylinders. The highest concentrations of CO2 and CH4 were 0.30 mol/kg and 1.7 mmol/kg, respectively, measured in cylinders collected 1 m above lake bottom. Probe measurements of in-situ gas pressure at three different stations showed that horizontal variations in total dissolved gas were negligible. Total dissolved-gas pressure near the lake bottom is 1.06 MPa (10.5 atm), 50% as high as the hydrostatic pressure of 2.1 MPa (21 atm). Comparing the CO2 profile constructed from the 1990 data to one obtained in May 1987 shows that CO2 concentrations have increased at depths to below 150 m. Based on these profiles, the average rate of CO2 input to bottom waters was 2.6 ?? 108 mol/a. Increased deep-water temperatures require an average heat flow of 0.32 MW into the hypolimnion over the same time period. The transport rates of CO2, heat, and major ions into the hypolimnion suggest that a low-temperature reservoir of free CO2 exists a short distance below lake bottom and that convective cycling of lake water through the sediments is involved in transporting the CO2 into the lake from the underlying diatreme. Increased CH4 concentrations at all depths below the oxycline and a high 14C content (41% modern) in the CH4 4 m above lake bottom show that much of the CH4 is biologically produced within the lake. The CH4 production rate may vary with time, but if the CO2 recharge rate remains constant, CO2 saturation of the entire hypolimnion below 50 m depth would require ???140 a, given present-day concentrations. ?? 1993.

  18. Dynamic vertical profiles of peat porewater chemistry in a northern peatland

    Treesearch

    Natalie A. Griffiths; Stephen D. Sebestyen

    2016-01-01

    We measured pH, cations, nutrients, and total organic carbon (TOC) over 3 years to examine weekly to monthly variability in porewater chemistry depth profiles (0–3.0 m) in an ombrotrophic bog in Minnesota, USA. We also compared temporal variation at one location to spatial variation in depth profiles at 16 locations across the bog. Most solutes exhibited large...

  19. A geophysical perspective on mantle water content and melting: Inverting electromagnetic sounding data using laboratory-based electrical conductivity profiles

    NASA Astrophysics Data System (ADS)

    Khan, A.; Shankland, T. J.

    2012-02-01

    This paper applies electromagnetic sounding methods for Earth's mantle to constrain its thermal state, chemical composition, and "water" content. We consider long-period inductive response functions in the form of C-responses from four stations distributed across the Earth (Europe, North America, Asia and Australia) covering a period range from 3.9 to 95.2 days and sensitivity to ~ 1200 km depth. We invert C-responses directly for thermo-chemical state using a self-consistent thermodynamic method that computes phase equilibria as functions of pressure, temperature, and composition (in the Na2O-CaO-FeO-MgO-Al2O3-SiO2 model system). Computed mineral modes are combined with recent laboratory-based electrical conductivity models from independent experimental research groups (Yoshino (2010) and Karato (2011)) to compute bulk conductivity structure beneath each of the four stations from which C-responses are estimated. To reliably allocate water between the various mineral phases we include laboratory-measured water partition coefficients for major upper mantle and transition zone minerals. This scheme is interfaced with a sampling-based algorithm to solve the resulting non-linear inverse problem. This approach has two advantages: (1) It anchors temperatures, composition, electrical conductivities, and discontinuities that are in laboratory-based forward models, and (2) At the same time it permits the use of geophysical inverse methods to optimize conductivity profiles to match geophysical data. The results show lateral variations in upper mantle temperatures beneath the four stations that appear to persist throughout the upper mantle and parts of the transition zone. Calculated mantle temperatures at 410 and 660 km depth lie in the range 1250-1650 °C and 1500-1750 °C, respectively, and generally agree with the experimentally-determined temperatures at which the measured phase reactions olivine → β-spinel and γ-spinel → ferropericlase + perovskite occur. The retrieved conductivity structures beneath the various stations tend to follow trends observed for temperature with the strongest lateral variations in the uppermost mantle; for depths > 300 km conductivities appear to depend less on the particular conductivity database. Conductivities at 410 km and at 660 km depth are found to agree overall with purely geophysically-derived global and semi-global one-dimensional conductivity models. Both electrical conductivity databases point to < 0.01 wt.% H2O in the upper mantle. For transition zone minerals results from the laboratory database of Yoshino (2010) suggest that a much higher water content (up to 2 wt.% H2O) is required than in the other database (Karato, 2011), which favors a relatively "dry" transition zone (< 0.01 wt.% H2O). Incorporating laboratory measurements of hydrous silicate melting relations and available conductivity data allows us to consider the possibility of hydration melting and a high-conductivity melt layer above the 410-km discontinuity. The latter appears to be 1) regionally localized and 2) principally a feature from the Yoshino (2010) database. Further, there is evidence of lateral heterogeneity: The mantle beneath southwestern North America and central China appears "wetter" than that beneath central Europe or Australia.

  20. Simple dielectric mixing model in the monitoring of CO2 leakage from geological storage aquifer

    NASA Astrophysics Data System (ADS)

    Abidoye, L. K.; Bello, A. A.

    2017-03-01

    The principle of the dielectric mixing for multiphase systems in porous media has been employed to investigate CO2-water-porous media system and monitor the leakage of CO2, in analogy to scenarios that can be encountered in geological carbon sequestration. A dielectric mixing model was used to relate the relative permittivity for different subsurface materials connected with the geological carbon sequestration. The model was used to assess CO2 leakage and its upward migration, under the influences of the depth-dependent characteristics of the subsurface media as well as the fault-connected aquifers. The results showed that for the upward migration of CO2 in the subsurface, the change in the bulk relative permittivity (εb) of the CO2-water-porous media system clearly depicts the leakage and movement of CO2, especially at depth shallower than 800 m. At higher depth, with higher pressure and temperature, the relative permittivity of CO2 increases with pressure, while that of water decreases with temperature. These characteristics of water and supercritical CO2, combine to limit the change in the εb, at higher depth. Furthermore, it was noted that if the pore water was not displaced by the migrating CO2, the presence of CO2 in the system increases the εb. But, with the displacement of pore water by the migrating CO2, it was shown how the εb profile decreases with time. Owing to its relative simplicity, composite dielectric behaviour of multiphase materials can be effectively deployed for monitoring and enhancement of control of CO2 movement in the geological carbon sequestration.

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