Nonlinear Constitutive Relations for High Temperature Application, 1984

NASA Technical Reports Server (NTRS)

1985-01-01

Nonlinear constitutive relations for high temperature applications were discussed. The state of the art in nonlinear constitutive modeling of high temperature materials was reviewed and the need for future research and development efforts in this area was identified. Considerable research efforts are urgently needed in the development of nonlinear constitutive relations for high temperature applications prompted by recent advances in high temperature materials technology and new demands on material and component performance. Topics discussed include: constitutive modeling, numerical methods, material testing, and structural applications.

High-Temperature Phase Change Materials (PCM) Candidates for Thermal Energy Storage (TES) Applications

DOE Office of Scientific and Technical Information (OSTI.GOV)

Gomez, J. C.

2011-09-01

It is clearly understood that lower overall costs are a key factor to make renewable energy technologies competitive with traditional energy sources. Energy storage technology is one path to increase the value and reduce the cost of all renewable energy supplies. Concentrating solar power (CSP) technologies have the ability to dispatch electrical output to match peak demand periods by employing thermal energy storage (TES). Energy storage technologies require efficient materials with high energy density. Latent heat TES systems using phase change material (PCM) are useful because of their ability to charge and discharge a large amount of heat from amore » small mass at constant temperature during a phase transformation like melting-solidification. PCM technology relies on the energy absorption/liberation of the latent heat during a physical transformation. The main objective of this report is to provide an assessment of molten salts and metallic alloys proposed as candidate PCMs for TES applications, particularly in solar parabolic trough electrical power plants at a temperature range from 300..deg..C to 500..deg.. C. The physical properties most relevant for PCMs service were reviewed from the candidate selection list. Some of the PCM candidates were characterized for: chemical stability with some container materials; phase change transformation temperatures; and latent heats.« less

NASA Space applications of high-temperature superconductors

NASA Technical Reports Server (NTRS)

Heinen, Vernon O.; Sokoloski, Martin M.; Aron, Paul R.; Bhasin, Kul B.; Wintucky, Edwin G.; Connolly, Denis J.

1992-01-01

The application of superconducting technology in space has been limited by the requirement of cooling to near liquid helium temperatures. The only means of obtaining these temperatures has been with cryogenic fluids which severely limit mission lifetime. The development of materials with superconducting transition temperatures above 77 K has made superconducting technology more attractive and feasible for employment in aerospace systems. Here, potential applications of high temperature superconducting technology in cryocoolers, remote sensing, communications, and power systems are discussed.

Materials technology assessment for stirling engines

NASA Technical Reports Server (NTRS)

Stephens, J. R.; Witzke, W. R.; Watson, G. K.; Johnston, J. R.; Croft, W. J.

1977-01-01

A materials technology assessment of high temperature components in the improved (metal) and advanced (ceramic) Stirling engines was undertaken to evaluate the current state-of-the-art of metals and ceramics, identify materials research and development required to support the development of automotive Stirling engines, and to recommend materials technology programs to assure material readiness concurrent with engine system development programs. The most critical component for each engine is identified and some of the material problem areas are discussed.

Novel Thin Film Sensor Technology for Turbine Engine Hot Section Components

NASA Technical Reports Server (NTRS)

Wrbanek, John D.; Fralick, Gustave C.

2007-01-01

Degradation and damage that develops over time in hot section components can lead to catastrophic failure of the turbine section of aircraft engines. A range of thin film sensor technology has been demonstrated enabling on-component measurement of multiple parameters either individually or in sensor arrays including temperature, strain, heat flux, and flow. Conductive ceramics are beginning to be investigated as new materials for use as thin film sensors in the hot section, leveraging expertise in thin films and high temperature materials. The current challenges are to develop new sensor and insulation materials capable of withstanding the extreme hot section environment, and to develop techniques for applying sensors onto complex high temperature structures for aging studies of hot propulsion materials. The technology research and development ongoing at NASA Glenn Research Center for applications to future aircraft, launch vehicles, space vehicles, and ground systems is outlined.

Phase Change Fabrics Control Temperature

NASA Technical Reports Server (NTRS)

2009-01-01

Originally featured in Spinoff in 1997, Outlast Technologies Inc. (formerly Gateway Technologies Inc.) has built its entire product line on microencapsulated phase change materials, developed in Small Business Innovation Research (SBIR) contracts with Johnson Space Center after initial development for the U.S. Air Force. The Boulder, Colorado-based company acquired the exclusive patent rights and now integrates these materials into textiles or onto finished apparel, providing temperature regulation in bedding materials and a full line of apparel for both ordinary and extreme conditions.

Ultra-High Temperature Materials Characterization for Propulsion Applications

NASA Technical Reports Server (NTRS)

Rogers, Jan; Hyers, Robert

2007-01-01

Propulsion system efficiency increases as operating temperatures are increased. Some very high-temperature materials are being developed, including refractory metal alloys, carbides, borides, and silicides. System design requires data for materials properties at operating temperatures. Materials property data are not available for many materials of interest at the desired operating temperatures (up to approx. 3000 K). The objective of this work is to provide important physical property data at ultra-high temperatures. The MSFC Electrostatic levitation (ESL) facility can provide measurements of thermophysical properties which include: creep strength, density and thermal expansion for materials being developed for propulsion applications. The ESL facility uses electrostatic fields to position samples between electrodes during processing and characterization studies. Because the samples float between the electrodes during studies, they are free from any contact with a container or test apparatus. This provides a high purity environment for the study of high-temperature, reactive materials. ESL can be used to process a wide variety of materials including metals, alloys, ceramics, glasses and semiconductors. The MSFC ESL has provided non-contact measurements of properties of materials up to 3400 C. Density and thermal expansion are measured by analyzing digital images of the sample at different temperatures. Our novel, non-contact method for measuring creep uses rapid rotation to deform the sample. Digital images of the deformed samples are analyzed to obtain the creep properties, which match those obtained using ASTM Standard E-139 for Nb at 1985 C. Data from selected ESL-based characterization studies will be presented. The ESL technique could support numerous propulsion technologies by advancing the knowledge base and the technology readiness level for ultra-high temperature materials. Applications include non-eroding nozzle materials and lightweight, high-temperature alloys for turbines and structures.

NASA space applications of high-temperature superconductors

NASA Technical Reports Server (NTRS)

Heinen, Vernon O.; Sokoloski, Martin M.; Aron, Paul R.; Bhasin, Kul B.

1992-01-01

The application of superconducting technology in space has been limited by the requirement of cooling to near liquid helium temperatures. The only means of attaining these temperatures has been with cryogenic fluids which severely limits mission lifetime. The development of materials with superconducting transition temperatures (T sub c) above 77 K has made superconducting technology more attractive and feasible for employment in aerospace systems. Potential applications of high-temperature superconducting technology in cryocoolers and remote sensing, communications, and power systems are discussed.

Enabling Dissimilar Material Joining Using Friction Stir Scribe Technology

DOE Office of Scientific and Technical Information (OSTI.GOV)

Hovanski, Yuri; Upadyay, Piyush; Kleinbaum, Sarah

2017-04-05

One challenge in adapting welding processes to dissimilar material joining is the diversity of melting temperatures of the different materials. Although the use of mechanical fasteners and adhesives have mostly paved the way for near-term implementation of dissimilar material systems, these processes only accentuate the need for low-cost welding processes capable of joining dissimilar material components regardless of alloy, properties, or melting temperature. Friction stir scribe technology was developed to overcome the challenges of joining dissimilar material components where melting temperatures vary greatly, and properties and/or chemistry are not compatible with more traditional welding processes. Although the friction stir scribemore » process is capable of joining dissimilar metals and metal/polymer systems, a more detailed evaluation of several aluminum/steel joints is presented herein to demonstrate the ability to both chemically and mechanically join dissimilar materials.« less

Enabling Dissimilar Material Joining Using Friction Stir Scribe Technology

DOE PAGES

Hovanski, Yuri; Upadyay, Piyush; Kleinbaum, Sarah; ...

2017-04-05

One challenge in adapting welding processes to dissimilar material joining is the diversity of melting temperatures of the different materials. Although the use of mechanical fasteners and adhesives have mostly paved the way for near-term implementation of dissimilar material systems, these processes only accentuate the need for low-cost welding processes capable of impartially joining dissimilar material components regardless of alloy, properties, or melting temperature. Friction stir scribe technology was developed to overcome the challenges of joining dissimilar material components where melting temperatures vary greatly, and properties and/or chemistry are not compatible with more traditional welding processes. Finally, although the frictionmore » stir scribe process is capable of joining dissimilar metals and metal/polymer systems, a more detailed evaluation of several aluminum/steel joints is presented herein to demonstrate the ability to both chemically and mechanically join dissimilar materials.« less

NDE standards for high temperature materials

NASA Technical Reports Server (NTRS)

Vary, Alex

1991-01-01

High temperature materials include monolithic ceramics for automotive gas turbine engines and also metallic/intermetallic and ceramic matrix composites for a range of aerospace applications. These are materials that can withstand extreme operating temperatures that will prevail in advanced high-efficiency gas turbine engines. High temperature engine components are very likely to consist of complex composite structures with three-dimensionality interwoven and various intermixed ceramic fibers. The thermomechanical properties of components made of these materials are actually created in-place during processing and fabrication stages. The complex nature of these new materials creates strong incentives for exact standards for unambiguous evaluations of defects and microstructural characteristics. NDE techniques and standards that will ultimately be applicable to production and quality control of high temperature materials and structures are still emerging. The needs range from flaw detection to below 100 micron levels in monolithic ceramics to global imaging of fiber architecture and matrix densification anomalies in composites. The needs are different depending on the processing stage, fabrication method, and nature of the finished product. The standards are discussed that must be developed in concert with advances in NDE technology, materials processing research, and fabrication development. High temperature materials and structures that fail to meet stringent specifications and standards are unlikely to compete successfully either technologically or in international markets.

Advanced High-Temperature Engine Materials Technology Progresses

NASA Technical Reports Server (NTRS)

1995-01-01

The objective of the Advanced High Temperature Engine Materials Technology Program (HITEMP) is to generate technology for advanced materials and structural analysis that will increase fuel economy, improve reliability, extend life, and reduce operating costs for 21st century civil propulsion systems. The primary focus is on fan and compressor materials (polymer-matrix composites--PMC's), compressor and turbine materials (superalloys, and metal-matrix and intermetallic-matrix composites--MMC's and IMC's) and turbine materials (ceramic-matrix composites--CMC's). These advanced materials are being developed by in-house researchers and on grants and contracts. NASA considers this program to be a focused materials and structures research effort that builds on our base research programs and supports component-development projects. HITEMP is coordinated with the Advanced Subsonic Technology (AST) Program and the Department of Defense/NASA Integrated High-Performance Turbine Engine Technology (IHPTET) Program. Advanced materials and structures technologies from HITEMP may be used in these future applications. Recent technical accomplishments have not only improved the state-of-the-art but have wideranging applications to industry. A high-temperature thin-film strain gage was developed to measure both dynamic and static strain up to 1100 C (2000 F). The gage's unique feature is that it is minimally intrusive. This technology, which received a 1995 R&D 100 Award, has been transferred to AlliedSignal Engines, General Electric Company, and Ford Motor Company. Analytical models developed at the NASA Lewis Research Center were used to study Textron Specialty Materials' manufacturing process for titanium-matrix composite rings. Implementation of our recommendations on tooling and processing conditions resulted in the production of defect free rings. In the Lincoln Composites/AlliedSignal/Lewis cooperative program, a composite compressor case is being manufactured with a Lewis-developed matrix, VCAP. The compressor case, which will reduce weight by 30 percent and costs by 50 percent, is scheduled to be engine tested in the near future.

Lewis materials research and technology: An overview

NASA Technical Reports Server (NTRS)

Grisaffe, Salvatore J.

1987-01-01

The Materials Division at the Lewis Research Center has a long record of contributions to both materials and process technology as well as to the understanding of key high-temperature phenomena. An overview of the division staff, facilities, past history, recent progress, and future interests is presented.

NASA. Lewis Research Center materials research and technology: An overview

NASA Technical Reports Server (NTRS)

Grisaffe, Salvatore J.

1990-01-01

The Materials Division at the Lewis Research Center has a long record of contributions to both materials and process technology as well as to the understanding of key high-temperature phenomena. This paper overviews the division staff, facilities, past history, recent progress, and future interests.

Synthesis and design of silicide intermetallic materials

DOE Office of Scientific and Technical Information (OSTI.GOV)

Petrovic, J.J.; Castro, R.G.; Butt, D.P.

1997-04-01

The overall objective of this program is to develop structural silicide-based materials with optimum combinations of elevated temperature strength/creep resistance, low temperature fracture toughness, and high temperature oxidation and corrosion resistance for applications of importance to the U.S. processing industry. A further objective is to develop silicide-based prototype industrial components. The ultimate aim of the program is to work with industry to transfer the structural silicide materials technology to the private sector in order to promote international competitiveness in the area of advanced high temperature materials and important applications in major energy-intensive U.S. processing industries. The program presently has amore » number of developing industrial connections, including a CRADA with Schuller International Inc. targeted at the area of MoSi{sub 2}-based high temperature materials and components for fiberglass melting and processing applications. The authors are also developing an interaction with the Institute of Gas Technology (IGT) to develop silicides for high temperature radiant gas burner applications, for the glass and other industries. Current experimental emphasis is on the development and characterization of MoSi{sub 2}-Si{sub 3}N{sub 4} and MoSi{sub 2}-SiC composites, the plasma spraying of MoSi{sub 2}-based materials, and the joining of MoSi{sub 2} materials to metals.« less

Metals and Ceramics Division progress report for period ending December 31, 1993

DOE Office of Scientific and Technical Information (OSTI.GOV)

Craig, D.F.; Bradley, R.A.; Weir, J.R. Jr.

1994-07-01

This report provides an overview of activities and accomplishsments of the division from October 1992 through December 1993; the division is organized to provide technical support, mainly in the area of high-temperature materials, for technologies being developed by DOE. Activities span the range from basic research to industrial interactions (cooperative research and technology transfer). Sections 1-5 describe the different functional groups (engineering materials, high-temperature materials, materials science, ceramics, nuclear fuel materials). Sect. 6 provides an alternative view of the division in terms of the major programs, most of which cross group lines. Sect. 7 summarizes external interactions including cooperative Rmore » and D programs and technology transfer functions. Finally, Sect. 8 briefly describes the division`s involvement in educational activities. Several organizational changes were effected during this period.« less

Mission oriented R and D and the advancement of technology: The impact of NASA contributions, volume 2

NASA Technical Reports Server (NTRS)

Robbins, M. D.; Kelley, J. A.; Elliott, L.

1972-01-01

NASA contributions to the advancement of major developments in twelve selected fields of technology are presented. The twelve fields of technology discussed are: (1) cryogenics, (2) electrochemical energy conversion and storage, (3) high-temperature ceramics, (4) high-temperature metals (5) integrated circuits, (6) internal gas dynamics (7) materials machining and forming, (8) materials joining, (9) microwave systems, (10) nondestructive testing, (11) simulation, and (12) telemetry. These field were selected on the basis of both NASA and nonaerospace interest and activity.

Foundations of low-temperature plasma enhanced materials synthesis and etching

NASA Astrophysics Data System (ADS)

Oehrlein, Gottlieb S.; Hamaguchi, Satoshi

2018-02-01

Low temperature plasma (LTP)-based synthesis of advanced materials has played a transformational role in multiple industries, including the semiconductor industry, liquid crystal displays, coatings and renewable energy. Similarly, the plasma-based transfer of lithographically defined resist patterns into other materials, e.g. silicon, SiO2, Si3N4 and other electronic materials, has led to the production of nanometer scale devices that are the basis of the information technology, microsystems, and many other technologies based on patterned films or substrates. In this article we review the scientific foundations of both LTP-based materials synthesis at low substrate temperature and LTP-based isotropic and directional etching used to transfer lithographically produced resist patterns into underlying materials. We cover the fundamental principles that are the basis of successful application of the LTP techniques to technological uses and provide an understanding of technological factors that may control or limit material synthesis or surface processing with the use of LTP. We precede these sections with a general discussion of plasma surface interactions, the LTP-generated particle fluxes including electrons, ions, radicals, excited neutrals and photons that simultaneously contact and modify surfaces. The surfaces can be in the line of sight of the discharge or hidden from direct interaction for structured substrates. All parts of the article are extensively referenced, which is intended to help the reader study the topics discussed here in more detail.

Rhenium Rocket Manufacturing Technology

NASA Technical Reports Server (NTRS)

1997-01-01

The NASA Lewis Research Center's On-Board Propulsion Branch has a research and technology program to develop high-temperature (2200 C), iridium-coated rhenium rocket chamber materials for radiation-cooled rockets in satellite propulsion systems. Although successful material demonstrations have gained much industry interest, acceptance of the technology has been hindered by a lack of demonstrated joining technologies and a sparse materials property data base. To alleviate these concerns, we fabricated rhenium to C-103 alloy joints by three methods: explosive bonding, diffusion bonding, and brazing. The joints were tested by simulating their incorporation into a structure by welding and by simulating high-temperature operation. Test results show that the shear strength of the joints degrades with welding and elevated temperature operation but that it is adequate for the application. Rhenium is known to form brittle intermetallics with a number of elements, and this phenomena is suspected to cause the strength degradation. Further bonding tests with a tantalum diffusion barrier between the rhenium and C-103 is planned to prevent the formation of brittle intermetallics.

High temperature thruster technology for spacecraft propulsion

NASA Technical Reports Server (NTRS)

Schneider, Steven J.

1991-01-01

A technology program intended to develop high-temperature oxidation-resistant thrusters for spacecraft applications is considered. The program will provide the requisite material characterizations and fabrication to incorporate iridium coated rhenium material into small rockets for spacecraft propulsion. This material increases the operating temperature of thrusters to 2200 C, a significant increase over the 1400 C of the silicide-coated niobium chambers currently used. Stationkeeping class 22 N engines fabricated from iridium-coated rhenium have demonstrated steady state specific impulses 20-25 seconds higher than niobium chambers. These improved performances are obtained by reducing or eliminating the fuel film cooling requirements in the combustion chamber while operating at the same overall mixture ratio as conventional engines.

Advanced Rankine and Brayton cycle power systems - Materials needs and opportunities

NASA Technical Reports Server (NTRS)

Grisaffe, S. J.; Guentert, D. C.

1974-01-01

Conceptual advanced potassium Rankine and closed Brayton power conversion cycles offer the potential for improved efficiency over steam systems through higher operating temperatures. However, for utility service of at least 100,000 hours, materials technology advances will be needed for such high temperature systems. Improved alloys and surface protection must be developed and demonstrated to resist coal combustion gases as well as potassium corrosion or helium surface degradation at high temperatures. Extensions in fabrication technology are necessary to produce large components of high temperature alloys. Long-time property data must be obtained under environments of interest to assure high component reliability.

Advanced Rankine and Brayton cycle power systems: Materials needs and opportunities

NASA Technical Reports Server (NTRS)

Grisaffe, S. J.; Guentert, D. C.

1974-01-01

Conceptual advanced potassium Rankine and closed Brayton power conversion cycles offer the potential for improved efficiency over steam systems through higher operating temperatures. However, for utility service of at least 100,000 hours, materials technology advances will be needed for such high temperature systems. Improved alloys and surface protection must be developed and demonstrated to resist coal combustion gases as well as potassium corrosion or helium surface degradation at high temperatures. Extensions in fabrication technology are necessary to produce large components of high temperature alloys. Long time property data must be obtained under environments of interest to assure high component reliability.

Advanced Electrical Materials and Components Being Developed

NASA Technical Reports Server (NTRS)

Schwarze, Gene E.

2004-01-01

All aerospace systems require power management and distribution (PMAD) between the energy and power source and the loads. The PMAD subsystem can be broadly described as the conditioning and control of unregulated power from the energy source and its transmission to a power bus for distribution to the intended loads. All power and control circuits for PMAD require electrical components for switching, energy storage, voltage-to-current transformation, filtering, regulation, protection, and isolation. Advanced electrical materials and component development technology is a key technology to increasing the power density, efficiency, reliability, and operating temperature of the PMAD. The primary means to develop advanced electrical components is to develop new and/or significantly improved electronic materials for capacitors, magnetic components, and semiconductor switches and diodes. The next important step is to develop the processing techniques to fabricate electrical and electronic components that exceed the specifications of presently available state-of-the-art components. The NASA Glenn Research Center's advanced electrical materials and component development technology task is focused on the following three areas: 1) New and/or improved dielectric materials for the development of power capacitors with increased capacitance volumetric efficiency, energy density, and operating temperature; 2) New and/or improved high-frequency, high-temperature soft magnetic materials for the development of transformers and inductors with increased power density, energy density, electrical efficiency, and operating temperature; 3) Packaged high-temperature, high-power density, high-voltage, and low-loss SiC diodes and switches.

Spacesuit Materials Add Comfort to Undergarments

NASA Technical Reports Server (NTRS)

2013-01-01

Phase change materials (PCMs) were one of the technologies NASA used to help astronauts maintain a "just right" temperature in their space gloves. To incorporate PCMs in spacesuit fabrics, Johnson Space Center collaborated with Outlast Technologies Inc. In 2011, Jockey International, headquartered in Kenosha, Wisconsin, released a line of men's and women's undergarments incorporating the NASA technology

Technology. The Hot Cup Caper. Probing for Scientific Knowledge.

ERIC Educational Resources Information Center

Ramondetta, June

1994-01-01

Students can explore temperature and heat conductivity by examining materials that make good cups for hot cocoa. Using temperature probes from computer-based science packages, students can measure gradual change in the liquid's temperature, watch as data are plotted on the computer, and explain why they chose a specific material. (SM)

Cost/benefit analysis of advanced materials technologies for future aircraft turbine engines

NASA Technical Reports Server (NTRS)

Stephens, G. E.

1980-01-01

The materials technologies studied included thermal barrier coatings for turbine airfoils, turbine disks, cases, turbine vanes and engine and nacelle composite materials. The cost/benefit of each technology was determined in terms of Relative Value defined as change in return on investment times probability of success divided by development cost. A recommended final ranking of technologies was based primarily on consideration of Relative Values with secondary consideration given to changes in other economic parameters. Technologies showing the most promising cost/benefits were thermal barrier coated temperature nacelle/engine system composites.

Attrition Rate of Oxygen Carriers in Chemical Looping Combustion Systems

NASA Astrophysics Data System (ADS)

Feilen, Harry Martin

This project developed an evaluation methodology for determining, accurately and rapidly, the attrition resistance of oxygen carrier materials used in chemical looping technologies. Existing test protocols, to evaluate attrition resistance of granular materials, are conducted under non-reactive and ambient temperature conditions. They do not accurately reflect the actual behavior under the unique process conditions of chemical looping, including high temperatures and cyclic operation between oxidizing and reducing atmospheres. This project developed a test method and equipment that represented a significant improvement over existing protocols. Experimental results obtained from this project have shown that hematite exhibits different modes of attrition, including both due to mechanical stresses and due to structural changes in the particles due to chemical reaction at high temperature. The test methodology has also proven effective in providing reactivity changes of the material with continued use, a property, which in addition to attrition, determines material life. Consumption/replacement cost due to attrition or loss of reactivity is a critical factor in the economic application of the chemical looping technology. This test method will allow rapid evaluation of a wide range of materials that are best suited for this technology. The most important anticipated public benefit of this project is the acceleration of the development of chemical looping technology for lowering greenhouse gas emissions from fossil fuel combustion.

Nonlinear Constitutive Relations for High Temperature Applications, 1986

NASA Technical Reports Server (NTRS)

1988-01-01

The purpose of the symposium was to review the state-of-the-art in nonlinear constitutive modeling of high temperature materials for aeronautics applications and to identify the need for future research and development efforts in this area. Through this symposium, it was recognized that considerable research efforts are urgently needed in the development of nonlinear constitutive relations for high temperature applications. In the aerospace industry this need is further prompted by recent advances in high temperature materials technology and new demands on material and component performance.

Civil propulsion technology for the next twenty-five years

NASA Technical Reports Server (NTRS)

Rosen, Robert; Facey, John R.

1987-01-01

The next twenty-five years will see major advances in civil propulsion technology that will result in completely new aircraft systems for domestic, international, commuter and high-speed transports. These aircraft will include advanced aerodynamic, structural, and avionic technologies resulting in major new system capabilities and economic improvements. Propulsion technologies will include high-speed turboprops in the near term, very high bypass ratio turbofans, high efficiency small engines and advanced cycles utilizing high temperature materials for high-speed propulsion. Key fundamental enabling technologies include increased temperature capability and advanced design methods. Increased temperature capability will be based on improved composite materials such as metal matrix, intermetallics, ceramics, and carbon/carbon as well as advanced heat transfer techniques. Advanced design methods will make use of advances in internal computational fluid mechanics, reacting flow computation, computational structural mechanics and computational chemistry. The combination of advanced enabling technologies, new propulsion concepts and advanced control approaches will provide major improvements in civil aircraft.

Metals and Ceramics Division annual progress report, October 1, 1978-June 30, 1979

DOE Office of Scientific and Technical Information (OSTI.GOV)

Peterson, S.

Research is reported concerning: (1) engineering materials including materials compatibility, mechanical properties, nondestructive testing, pressure vessel technology, and welding and brazing; (2) fuels and processes consisting of ceramic technology, fuel cycle technology, fuels evaluation, fuels fabrication and metals processing; and (3) materials science which includes, ceramic studies, physical metallurgy and properties, radiation effects and microstructural analysis, metastable and superconducting materials, structure and properties of surfaces, theoretical research, and x-ray research and applications. Highlights of the work of the metallographic group and the current status of the High-Temperature Materials Laboratory (HTML) and the Materials and Structures Technology Management Center (MSTMC) aremore » presented. (FS)« less

Advanced Flip Chips in Extreme Temperature Environments

NASA Technical Reports Server (NTRS)

Ramesham, Rajeshuni

2010-01-01

The use of underfill materials is necessary with flip-chip interconnect technology to redistribute stresses due to mismatching coefficients of thermal expansion (CTEs) between dissimilar materials in the overall assembly. Underfills are formulated using organic polymers and possibly inorganic filler materials. There are a few ways to apply the underfills with flip-chip technology. Traditional capillary-flow underfill materials now possess high flow speed and reduced time to cure, but they still require additional processing steps beyond the typical surface-mount technology (SMT) assembly process. Studies were conducted using underfills in a temperature range of -190 to 85 C, which resulted in an increase of reliability by one to two orders of magnitude. Thermal shock of the flip-chip test articles was designed to induce failures at the interconnect sites (-40 to 100 C). The study on the reliability of flip chips using underfills in the extreme temperature region is of significant value for space applications. This technology is considered as an enabling technology for future space missions. Flip-chip interconnect technology is an advanced electrical interconnection approach where the silicon die or chip is electrically connected, face down, to the substrate by reflowing solder bumps on area-array metallized terminals on the die to matching footprints of solder-wettable pads on the chosen substrate. This advanced flip-chip interconnect technology will significantly improve the performance of high-speed systems, productivity enhancement over manual wire bonding, self-alignment during die joining, low lead inductances, and reduced need for attachment of precious metals. The use of commercially developed no-flow fluxing underfills provides a means of reducing the processing steps employed in the traditional capillary flow methods to enhance SMT compatibility. Reliability of flip chips may be significantly increased by matching/tailoring the CTEs of the substrate material and the silicon die or chip, and also the underfill materials. Advanced packaging interconnects technology such as flip-chip interconnect test boards have been subjected to various extreme temperature ranges that cover military specifications and extreme Mars and asteroid environments. The eventual goal of each process step and the entire process is to produce components with 100 percent interconnect and satisfy the reliability requirements. Underfill materials, in general, may possibly meet demanding end use requirements such as low warpage, low stress, fine pitch, high reliability, and high adhesion.

Technology Developments in Radiation-Hardened Electronics for Space Environments

NASA Technical Reports Server (NTRS)

Keys, Andrew S.; Howell, Joe T.

2008-01-01

The Radiation Hardened Electronics for Space Environments (RHESE) project consists of a series of tasks designed to develop and mature a broad spectrum of radiation hardened and low temperature electronics technologies. Three approaches are being taken to address radiation hardening: improved material hardness, design techniques to improve radiation tolerance, and software methods to improve radiation tolerance. Within these approaches various technology products are being addressed including Field Programmable Gate Arrays (FPGA), Field Programmable Analog Arrays (FPAA), MEMS, Serial Processors, Reconfigurable Processors, and Parallel Processors. In addition to radiation hardening, low temperature extremes are addressed with a focus on material and design approaches. System level applications for the RHESE technology products are discussed.

High temperature coatings from post processing Fe-based chips and Ni-based alloys as a solution for critical raw materials

NASA Astrophysics Data System (ADS)

Dudziak, T.; Olbrycht, A.; Polkowska, A.; Boron, L.; Skierski, P.; Wypych, A.; Ambroziak, A.; Krezel, A.

2018-03-01

Due to shortage of natural resources worldwide, it is a need to develop innovative technologies, to save natural resources and secure Critical Raw Materials (CRM). On the other hand, these new technologies should move forward materials engineering in order to develop better materials for extreme conditions. One way to develop new materials is to use post processing chips of austenitic steels (i.e. 304L stainless steel: 18/10 Cr/Ni) and other materials such as Ni-based alloy with high Cr content. In this work, the results of the preliminary study on the High Velocity Oxy Fuel (HVOF) coatings developed from 304L stainless steel chips and Haynes® 282® Ni- based alloys are shown. The study obeys development of the powder for HVOF technology. The produced coatings were exposed at high temperature at 500 and 700 °C for 100 and 300 hours respectively to assess corrosion behaviour.

Progress in advanced high temperature materials technology

NASA Technical Reports Server (NTRS)

Freche, J. C.; Ault, G. M.

1976-01-01

Significant progress has recently been made in many high temperature material categories pertinent to such applications by the industrial community. These include metal matrix composites, superalloys, directionally solidified eutectics, coatings, and ceramics. Each of these material categories is reviewed and the current state-of-the-art identified, including some assessment, when appropriate, of progress, problems, and future directions.

Crystal growth within a phase change memory cell.

PubMed

Sebastian, Abu; Le Gallo, Manuel; Krebs, Daniel

2014-07-07

In spite of the prominent role played by phase change materials in information technology, a detailed understanding of the central property of such materials, namely the phase change mechanism, is still lacking mostly because of difficulties associated with experimental measurements. Here, we measure the crystal growth velocity of a phase change material at both the nanometre length and the nanosecond timescale using phase-change memory cells. The material is studied in the technologically relevant melt-quenched phase and directly in the environment in which the phase change material is going to be used in the application. We present a consistent description of the temperature dependence of the crystal growth velocity in the glass and the super-cooled liquid up to the melting temperature.

High Temperature Materials for Chemical Propulsion Applications

NASA Technical Reports Server (NTRS)

Elam, Sandra; Hickman, Robert; O'Dell, Scott

2007-01-01

Radiation or passively cooled thrust chambers are used for a variety of chemical propulsion functions including apogee insertion, reaction control for launch vehicles, and primary propulsion for planetary spacecraft. The performance of these thrust chambers is limited by the operating temperature of available materials. Improved oxidation resistance and increased operating temperatures can be achieved with the use of thermal barrier coatings such as zirconium oxide (ZrO2) and hafnium oxide (HfO2). However, previous attempts to include these materials showed cracking and spalling of the oxide layer due to poor bonding. Current research at NASA's Marshall Space Flight Center (MSFC) has generated unique, high temperature material options for in-space thruster designs that are capable of up to 2500 C operating temperatures. The research is focused on fabrication technologies to form low cost Iridium,qF_.henium (Ir/Re) components with a ceramic hot wall created as an integral, functionally graded material (FGM). The goal of this effort is to further de?celop proven technologies for embedding a protective ceramic coating within the Ir/Re liner to form a robust functional gradient material. Current work includes the fabrication and testing of subscale samples to evaluate tensile, creep, thermal cyclic/oxidation, and thermophysical material properties. Larger test articles have also being fabricated and hot-fire tested to demonstrate the materials in prototype thrusters at 1O0 lbf thrust levels.

Materials and processing science: Limits for microelectronics

NASA Astrophysics Data System (ADS)

Rosenberg, R.

1988-09-01

The theme of this talk will be to illustrate examples of technologies that will drive materials and processing sciences to the limit and to describe some of the research being pursued to understand materials interactions which are pervasive to projected structure fabrication. It is to be expected that the future will see a progression to nanostructures where scaling laws will be tested and quantum transport will become more in evidence, to low temperature operation for tighter control and improved performance, to complex vertical profiles where 3D stacking and superlattices will produce denser packing and device flexibility, to faster communication links with optoelectronics, and to compatible packaging technologies. New low temperature processing techniques, such as epitaxy of silicon, PECVD of dielectrics, low temperature high pressure oxidation, silicon-germanium heterostructures, etc., must be combined with shallow metallurgies, new lithographic technologies, maskless patterning, rapid thermal processing (RTP) to produce needed profile control, reduce process incompatibilities and develop new device geometries. Materials interactions are of special consequence for chip substrates and illustrations of work in metal-ceramic and metal-polymer adhesion will be offered.

Time-temperature-stress capabilities of composite materials for advanced supersonic technology application

NASA Technical Reports Server (NTRS)

Kerr, James R.; Haskins, James F.

1987-01-01

Advanced composites will play a key role in the development of the technology for the design and fabrication of future supersonic vehicles. However, incorporating the material into vehicle usage is contingent on accelerating the demonstration of service capacity and design technology. Because of the added material complexity and lack of extensive data, laboratory replication of the flight service will provide the most rapid method to document the airworthiness of advanced composite systems. Consequently, a laboratory program was conducted to determine the time-temperature-stress capabilities of several high temperature composites. Tests included were thermal aging, environmental aging, fatigue, creep, fracture, tensile, and real-time flight simulation exposure. The program had two phases. The first included all the material property determinations and aging and simulation exposures up through 10,000 hours. The second continued these tests up to 50,000 cumulative hours. This report presents the results of the Phase 1 baseline and 10,000-hr aging and flight simulation studies, the Phase 2 50,000-hr aging studies, and the Phase 2 flight simulation tests, some of which extended to almost 40,000 hours.

High-temperature gas-cooled reactor technology development program. Annual progress report for period ending December 31, 1982

DOE Office of Scientific and Technical Information (OSTI.GOV)

Kasten, P.R.; Rittenhouse, P.L.; Bartine, D.E.

1983-06-01

During 1982 the High-Temperature Gas-Cooled Reactor (HTGR) Technology Program at Oak Ridge National Laboratory (ORNL) continued to develop experimental data required for the design and licensing of cogeneration HTGRs. The program involves fuels and materials development (including metals, graphite, ceramic, and concrete materials), HTGR chemistry studies, structural component development and testing, reactor physics and shielding studies, performance testing of the reactor core support structure, and HTGR application and evaluation studies.

Solar synthesis of advanced materials: A solar industrial program initiative

NASA Astrophysics Data System (ADS)

Lewandowski, A.

1992-06-01

This is an initiative for accelerating the use of solar energy in the advanced materials manufacturing industry in the United States. The initiative will be based on government-industry collaborations that will develop the technology and help US industry compete in the rapidly expanding global advanced materials marketplace. Breakthroughs in solar technology over the last 5 years have created exceptional new tools for developing advanced materials. Concentrated sunlight from solar furnaces can produce intensities that approach those on the surface of the sun and can generate temperatures well over 2000 C. Very thin layers of illuminated surfaces can be driven to remarkably high temperatures in a fraction of a second. Concentrated solar energy can be delivered over large areas, allowing for rapid processing and high production rates. By using this technology, researchers are transforming low-cost raw materials into high-performance products. Solar synthesis of advanced materials uses bulk materials and energy more efficiently, lowers processing costs, and reduces the need for strategic materials -- all with a technology that does not harm the environment. The Solar Industrial Program has built a unique, world class solar furnace at NREL to help meet the growing need for applied research in advanced materials. Many new advanced materials processes have been successfully demonstrated in this facility, including metalorganic deposition, ceramic powders, diamond-like carbon materials, rapid heat treating, and cladding (hard coating).

Future requirements for advanced materials

NASA Technical Reports Server (NTRS)

Olstad, W. B.

1980-01-01

Recent advances and future trends in aerospace materials technology are reviewed with reference to metal alloys, high-temperature composites and adhesives, tungsten fiber-reinforced superalloys, hybrid materials, ceramics, new ablative materials, such as carbon-carbon composite and silica tiles used in the Shuttle Orbiter. The technologies of powder metallurgy coupled with hot isostatic pressing, near net forging, complex large shape casting, chopped fiber molding, superplastic forming, and computer-aided design and manufacture are emphasized.

Formation of Green compact structure of low-temperature ceramics with taking into account the thermal degradation of the binder

NASA Astrophysics Data System (ADS)

Tovpinets, A. O.; Leytsin, V. N.; Dmitrieva, M. A.; Ivonin, I. V.; Ponomarev, S. V.

2017-12-01

The solution of the tasks in the field of creating and processing materials for additive technologies requires the development of a single theory of materials for various applications and processes. A separate class of materials that are promising for use in additive technologies includes materials whose consolidation is ensured by the presence of low-melting components in the initial mixture which form a matrix at a temperature not exceeding the melting point, recrystallization or destruction of any of the responsible refractory components of the initial dispersion. The study of the contribution of the binder thermal destruction to the structure and phase composition of the initial compact of the future composite is essential for the development of modern technologies for the synthesis of low-temperature ceramics. This paper investigates the effect of the thermal destruction of a binder on the formation of a green compact of low-temperature ceramics and the structural-mechanical characteristics of sintered ceramics. The approach proposed in Ref. [1] for evaluating the structure and physical characteristics of sintered low-temperature ceramics is improved to clarify the structure of green compacts obtained after thermal destruction of the polymer binder, with taking into account the pores formed and the infusible residue. The obtained results enable a more accurate prediction of thermal stresses in the matrix of sintered ceramics and serve as a basis for optimization.

Power Electronics Packaging Reliability | Transportation Research | NREL

Science.gov Websites

interface materials, are a key enabling technology for compact, lightweight, low-cost, and reliable power , reliability, and cost. High-temperature bonded interface materials are an important facilitating technology for compact, lightweight, low-cost, reliable power electronics packaging that fully utilizes the

Packaging Technologies for 500 C SiC Electronics and Sensors: Challenges in Material Science and Technology

NASA Technical Reports Server (NTRS)

Chen, Liang-Yu; Neudeck, Philip G.; Behelm, Glenn M.; Spry, David J.; Meredith, Roger D.; Hunter, Gary W.

2015-01-01

This paper presents ceramic substrates and thick-film metallization based packaging technologies in development for 500C silicon carbide (SiC) electronics and sensors. Prototype high temperature ceramic chip-level packages and printed circuit boards (PCBs) based on ceramic substrates of aluminum oxide (Al2O3) and aluminum nitride (AlN) have been designed and fabricated. These ceramic substrate-based chip-level packages with gold (Au) thick-film metallization have been electrically characterized at temperatures up to 550C. The 96 alumina packaging system composed of chip-level packages and PCBs has been successfully tested with high temperature SiC discrete transistor devices at 500C for over 10,000 hours. In addition to tests in a laboratory environment, a SiC junction field-effect-transistor (JFET) with a packaging system composed of a 96 alumina chip-level package and an alumina printed circuit board was tested on low earth orbit for eighteen months via a NASA International Space Station experiment. In addition to packaging systems for electronics, a spark-plug type sensor package based on this high temperature interconnection system for high temperature SiC capacitive pressure sensors was also developed and tested. In order to further significantly improve the performance of packaging system for higher packaging density, higher operation frequency, power rating, and even higher temperatures, some fundamental material challenges must be addressed. This presentation will discuss previous development and some of the challenges in material science (technology) to improve high temperature dielectrics for packaging applications.

The potential for CMCs to replace superalloys in engine exhaust ducts

NASA Astrophysics Data System (ADS)

Roth, Richard; Clark, Joel P.; Field, Frank R.

1994-01-01

The Materials Systems Laboratory at the Massachusetts Institute of Technology has conducted research to develop decision tools that can facilitate materials selection and provide a deeper understanding of the design tradeoffs that occur when choosing among advanced aerospace materials for high-temperature applications. As an illustration of the use of these tools, this paper describes research done to evaluate the material alternatives currently under consideration for exhaust ducts in aircraft gas turbine engines. Although nickel-based superalloys currently prevail for this application, the increasing temperatures of modern engines are necessitating the usage of higher temperature materials.

Mechanical Properties of T650-35/AFR-PE-4 at Elevated Temperatures for Lightweight Aeroshell Designs

NASA Technical Reports Server (NTRS)

Whitley, Karen S.; Collins, TImothy J.

2006-01-01

Considerable efforts have been underway to develop multidisciplinary technologies for aeroshell structures that will significantly increase the allowable working temperature for the aeroshell components, and enable the system to operate at higher temperatures while sustaining performance and durability. As part of these efforts, high temperature polymer matrix composites and fabrication technologies are being developed for the primary load bearing structure (heat shield) of the spacecraft. New high-temperature resins and composite material manufacturing techniques are available that have the potential to significantly improve current aeroshell design. In order to qualify a polymer matrix composite (PMC) material as a candidate aeroshell structural material, its performance must be evaluated under realistic environments. Thus, verification testing of lightweight PMC's at aeroshell entry temperatures is needed to ensure that they will perform successfully in high-temperature environments. Towards this end, a test program was developed to characterize the mechanical properties of two candidate material systems, T650-35/AFR-PE-4 and T650-35/RP46. The two candidate high-temperature polyimide resins, AFR-PE-4 and RP46, were developed at the Air Force Research Laboratory and NASA Langley Research Center, respectively. This paper presents experimental methods, strength, and stiffness data of the T650-35/AFR-PE-4 material as a function of elevated temperatures. The properties determined during the research test program herein, included tensile strength, tensile stiffness, Poisson s ratio, compressive strength, compressive stiffness, shear modulus, and shear strength. Unidirectional laminates, a cross-ply laminate and two eight-harness satin (8HS)-weave laminates (4-ply and 10-ply) were tested according to ASTM standard methods at room and elevated temperatures (23, 316, and 343 C). All of the relevant test methods and data reduction schemes are outlined along with mechanical data. These data contribute to a database of material properties for high-temperature polyimide composites that will be used to identify the material characteristics of potential candidate materials for aeroshell structure applications.

Time-temperature-stress capabilities of composite materials for advanced supersonic technology application, phase 1

NASA Technical Reports Server (NTRS)

Kerr, J. R.; Haskins, J. F.

1980-01-01

Implementation of metal and resin matrix composites into supersonic vehicle usage is contingent upon accelerating the demonstration of service capacity and design technology. Because of the added material complexity and lack of extensive service data, laboratory replication of the flight service will provide the most rapid method of documenting the airworthiness of advanced composite systems. A program in progress to determine the time temperature stress capabilities of several high temperature composite materials includes thermal aging, environmental aging, fatigue, creep, fracture, and tensile tests as well as real time flight simulation exposure. The program has two parts. The first includes all the material property determinations and aging and simulation exposures up through 10,000 hours. The second continues these tests up to 50,000 cumulative hours. Results are presented of the 10,000 hour phase, which has now been completed.

Achieving ultra-high temperatures with a resistive emitter array

NASA Astrophysics Data System (ADS)

Danielson, Tom; Franks, Greg; Holmes, Nicholas; LaVeigne, Joe; Matis, Greg; McHugh, Steve; Norton, Dennis; Vengel, Tony; Lannon, John; Goodwin, Scott

2016-05-01

The rapid development of very-large format infrared detector arrays has challenged the IR scene projector community to also develop larger-format infrared emitter arrays to support the testing of systems incorporating these detectors. In addition to larger formats, many scene projector users require much higher simulated temperatures than can be generated with current technology in order to fully evaluate the performance of their systems and associated processing algorithms. Under the Ultra High Temperature (UHT) development program, Santa Barbara Infrared Inc. (SBIR) is developing a new infrared scene projector architecture capable of producing both very large format (>1024 x 1024) resistive emitter arrays and improved emitter pixel technology capable of simulating very high apparent temperatures. During earlier phases of the program, SBIR demonstrated materials with MWIR apparent temperatures in excess of 1400 K. New emitter materials have subsequently been selected to produce pixels that achieve even higher apparent temperatures. Test results from pixels fabricated using the new material set will be presented and discussed. A 'scalable' Read In Integrated Circuit (RIIC) is also being developed under the same UHT program to drive the high temperature pixels. This RIIC will utilize through-silicon via (TSV) and Quilt Packaging (QP) technologies to allow seamless tiling of multiple chips to fabricate very large arrays, and thus overcome the yield limitations inherent in large-scale integrated circuits. Results of design verification testing of the completed RIIC will be presented and discussed.

Space radioisotope power source requirements update and technology status

DOE Office of Scientific and Technical Information (OSTI.GOV)

Mondt, J.F.

1998-07-01

The requirements for a space advanced radioisotope power source are based on potential deep space missions being investigated for the NASA Advanced Space Systems Development Program. Since deep space missions have not been approved, updating requirements is a continuos parallel process of designing the spacecraft and the science instruments to accomplish the potential missions and developing the power source technology to meet changing requirements. There are at least two potential missions, Pluto/Kuiper Express and Europa Orbiter, which may require space advanced radioisotope power sources. The Europa Orbiter has been selected as the preferred first potential mission. However the final decisionmore » will depend on the technology readiness of all the subsystems and the project must be able to switch to Pluto Kuiper Express as the first mission as late as the beginning of fiscal year 2000. Therefore the requirements for the power source will cover both potential missions. As the deep space spacecraft design evolves to meet the science requirements and the Alkali Metal Thermal to Electric (AMTEC) technology matures the advanced radioisotope power source design requirements are updated The AMTEC technology developed to date uses stainless steel for the sodium containment material. The higher efficiency required for the space power system dictates that the AMTEC technology must operate at a higher temperature than possible with stainless steel. Therefore refractory materials have been selected as the baseline material for the AMTEC cell. These refractory materials are Nb1Zr for the hot side and Nb1Zr or Nb10Hf1Ti for the cold side. These materials were selected so the AMTEC cell can operate at 1150K to 1350K hot side temperature and 600K to 700K cold side temperature and meet the present power and mass requirements using four to six general purpose heat source modules as the heat source. The new containment materials and brazes will be evaluated as to lifetime, compatibility and performance with the AMTEC beta prime Alumina, the TiN electrodes, the sodium and the molybdenum current collectors. AMTEC cell components and cells will be built with the baseline containment materials and brazes and tested to determine the performance as a function of temperature. These containment materials will be also be tested with all the other AMTEC components to determine acceleration factors needed to predict AMTEC performance degradation and failure as a function of operating time at temperature.« less

Strain sensing technology for high temperature applications

NASA Technical Reports Server (NTRS)

Williams, W. Dan

1993-01-01

This review discusses the status of strain sensing technology for high temperature applications. Technologies covered are those supported by NASA such as required for applications in hypersonic vehicles and engines, advanced subsonic engines, as well as material and structure development. The applications may be at temperatures of 540 C (1000 F) to temperatures in excess of 1400 C (2500 F). The most promising technologies at present are the resistance strain gage and remote sensing schemes. Resistance strain gages discussed include the BCL gage, the LaRC compensated gage, and the PdCr gage. Remote sensing schemes such as laser based speckle strain measurement, phase-shifling interferometry, and x-ray extensometry are discussed. Present status and limitations of these technologies are presented.

High Accuracy Thermal Expansion Measurement At Cryogenic Temperatures

NASA Technical Reports Server (NTRS)

Stallcup, Michael; Presson, Joan; Tucker, James; Daspit, Gregory; Nein, Max

2003-01-01

A new, interferometer based system for measuring thermal expansion to an absolute accuracy of 20 ppb or better at cryogenic temperatures has been developed. Data from NIST Copper SRM 736 measured from room temperature to 15 K will be presented along with data from many other materials including beryllium, ULE, Zerodur, and composite materials. Particular attention will be given to a study by the Space Optics Manufacturing Technology Center (SOMTC) investigating the variability of ULE and beryllium materials used in the AMSD program. Approximately 20 samples of each material, tested from room temperature to below 30 K are compared as a function of billet location.

High Accuracy Thermal Expansion Measurement at Cryogenic Temperatures

NASA Technical Reports Server (NTRS)

Tucker, Jim; Despit, Gregory; Stallcup, Michael; Presson, Joan; Nein, Max

2003-01-01

A new, interferometer-based system for measuring thermal expansion to an absolute accuracy of 20 ppb or better at cryogenic temperatures has been developed. Data from NIST Copper SRM 736 measured from room temperature to 15 K will be presented along with data from many other materials including beryllium, ULE, Zerodur, and composite materials. Particular attention will be given to a study by the Space Optics Manufacturing Technology Center (SOMTC) investigating the variability of ULE and beryllium materials used in the AMSD program Approximately 20 samples of each material, tested from room temperature to below 30 K are compared as a function of billet location.

Intermetallic and ceramic matrix composites for 815 to 1370 C (1500 to 2500 F) gas turbine engine applications

NASA Technical Reports Server (NTRS)

Stephens, Joseph R.

1989-01-01

Light weight and potential high temperature capability of intermetallic compounds, such as the aluminides, and structural ceramics, such as the carbides and nitrides, make these materials attractive for gas turbine engine applications. In terms of specific fuel consumption and specific thrust, revolutionary improvements over current technology are being sought by realizing the potential of these materials through their use as matrices combined with high strength, high temperature fibers. The U.S. along with other countries throughout the world have major research and development programs underway to characterize these composites materials; improve their reliability; identify and develop new processing techniques, new matrix compositions, and new fiber compositions; and to predict their life and failure mechanisms under engine operating conditions. The status is summarized of NASA's Advanced High Temperature Engine Materials Technology Program (HITEMP) and the potential benefits are described to be gained in 21st century transport aircraft by utilizing intermetallic and ceramic matrix composite materials.

Development of Meandering Winding Magnetometer (MWM (Register Trademark)) Eddy Current Sensors for the Health Monitoring, Modeling and Damage Detection of High Temperature Composite Materials

NASA Technical Reports Server (NTRS)

Russell, Richard; Washabaugh, Andy; Sheiretov, Yanko; Martin, Christopher; Goldfine, Neil

2011-01-01

The increased use of high-temperature composite materials in modern and next generation aircraft and spacecraft have led to the need for improved nondestructive evaluation and health monitoring techniques. Such technologies are desirable to improve quality control, damage detection, stress evaluation and temperature measurement capabilities. Novel eddy current sensors and sensor arrays, such as Meandering Winding Magnetometers (MWMs) have provided alternate or complimentary techniques to ultrasound and thermography for both nondestructive evaluation (NDE) and structural health monitoring (SHM). This includes imaging of composite material quality, damage detection and .the monitoring of fiber temperatures and multidirectional stresses. Historically, implementation of MWM technology for the inspection of the Space Shuttle Orbiter Reinforced Carbon-Carbon Composite (RCC) leading edge panels was developed by JENTEK Sensors and was subsequently transitioned by NASA as an operational pre and post flight in-situ inspection at the Kennedy Space Center. A manual scanner, which conformed'automatically to the curvature of the RCC panels was developed and used as a secondary technique if a defect was found during an infrared thermography screening, During a recent proof of concept study on composite overwrapped pressure vessels (COPV's), three different MWM sensors were tested at three orientations to demonstrate the ability of the technology to measure stresses at various fiber orientations and depths. These results showed excellent correlation with actual surface strain gage measurements. Recent advancements of this technology have been made applying MWM sensor technology for scanning COPVs for mechanical damage. This presentation will outline the recent advance in the MWM.technology and the development of MWM techniques for NDE and SHM of carbon wraped composite overwrapped pressure vessels (COPVs) including the measurement of internal stresses via a surface mounted sensor array. In addition, this paper will outline recent efforts to produce sensors capable of making real-time measurements at temperatures up to 850 C, and discuss previous results demonstrating capability to monitor carbon fiber temperature changes within a composite material.

Challenges and Opportunities in Design, Fabrication, and Testing of High Temperature Joints in Ceramics and Ceramic Composites

NASA Technical Reports Server (NTRS)

Singh, M.; Levine, S. R. (Technical Monitor)

2001-01-01

Ceramic joining has been recognized as an enabling technology for successful utilization of advanced ceramics and composite materials. A number of joint design and testing issues have been discussed for ceramic joints in silicon carbide-based ceramics and fiber-reinforced composites. These joints have been fabricated using an affordable, robust ceramic joining technology (ARCJoinT). The microstructure and good high temperature mechanical capability (compressive and flexural strengths) of ceramic joints in silicon carbide-based ceramics and composite materials are reported.

Critical Materials Needs

DTIC Science & Technology

1975-05-01

Waste-to-energy systems Recycling of materials from refuse Desulfurization of flue gases from electric power plants Sattelle Specialists...High-Temperature Gas -Turbine Engines for Automotive Applications Initiation of Task II and Task III (Task II: Description of Technologies and...3 - • Mining and Minerals Processing • Ocean Engineering • Transportation • Waste Treatment and Environmental Control The technologies

Progress of applied superconductivity research at Materials Research Laboratories, ITRI (Taiwan)

NASA Technical Reports Server (NTRS)

Liu, R. S.; Wang, C. M.

1995-01-01

A status report based on the applied high temperature superconductivity (HTS) research at Materials Research Laboratories (MRL), Industrial Technology Research Institute (ITRI) is given. The aim is to develop fabrication technologies for the high-TC materials appropriate to the industrial application requirements. To date, the majorities of works have been undertaken in the areas of new materials, wires/tapes with long length, prototypes of magnets, large-area thin films, SQUID's and microwave applications.

500 C Electronic Packaging and Dielectric Materials for High Temperature Applications

NASA Technical Reports Server (NTRS)

Chen, Liang-yu; Neudeck, Philip G.; Spry, David J.; Beheim, Glenn M.; Hunter, Gary W.

2016-01-01

High-temperature environment operable sensors and electronics are required for exploring the inner solar planets and distributed control of next generation aeronautical engines. Various silicon carbide (SiC) high temperature sensors, actuators, and electronics have been demonstrated at and above 500C. A compatible packaging system is essential for long-term testing and application of high temperature electronics and sensors. High temperature passive components are also necessary for high temperature electronic systems. This talk will discuss ceramic packaging systems developed for high temperature electronics, and related testing results of SiC circuits at 500C and silicon-on-insulator (SOI) integrated circuits at temperatures beyond commercial limit facilitated by these high temperature packaging technologies. Dielectric materials for high temperature multilayers capacitors will also be discussed. High-temperature environment operable sensors and electronics are required for probing the inner solar planets and distributed control of next generation aeronautical engines. Various silicon carbide (SiC) high temperature sensors, actuators, and electronics have been demonstrated at and above 500C. A compatible packaging system is essential for long-term testing and eventual applications of high temperature electronics and sensors. High temperature passive components are also necessary for high temperature electronic systems. This talk will discuss ceramic packaging systems developed for high electronics and related testing results of SiC circuits at 500C and silicon-on-insulator (SOI) integrated circuits at temperatures beyond commercial limit facilitated by high temperature packaging technologies. Dielectric materials for high temperature multilayers capacitors will also be discussed.

A nickel metal hydride battery for electric vehicles

NASA Astrophysics Data System (ADS)

Ovshinsky, S. R.; Fetcenko, M. A.; Ross, J.

1993-04-01

An efficient battery is the key technological element to the development of practical electric vehicles. The science and technology of a nickel metal hydride battery, which stores hydrogen in the solid hydride phase and has high energy density, high power, long life, tolerance to abuse, a wide range of operating temperature, quick-charge capability, and totally sealed maintenance-free operation, is described. A broad range of multi-element metal hydride materials that use structural and compositional disorder on several scales of length has been engineered for use as the negative electrode in this battery. The battery operates at ambient temperature, is made of nontoxic materials, and is recyclable. Demonstration of the manufacturing technology has been achieved.

Micro/nano composited tungsten material and its high thermal loading behavior

NASA Astrophysics Data System (ADS)

Fan, Jinglian; Han, Yong; Li, Pengfei; Sun, Zhiyu; Zhou, Qiang

2014-12-01

Tungsten (W) is considered as promising candidate material for plasma facing components (PFCs) in future fusion reactors attributing to its many excellent properties. Current commercial pure tungsten material in accordance with the ITER specification can well fulfil the performance requirements, however, it has defects such as coarse grains, high ductile-brittle transition temperature (DBTT) and relatively low recrystallization temperature compared with its using temperature, which cannot meet the harsh wall loading requirement of future fusion reactor. Grain refinement has been reported to be effective in improving the thermophysical and mechanical properties of W. In this work, rare earth oxide (Y2O3/La2O3) and carbides (TiC/ZrC) were used as dispersion phases to refine W grains, and micro/nano composite technology with a process of "sol gel - heterogeneous precipitation - spray drying - hydrogen reduction - ordinary consolidation sintering" was invented to introduce these second-phase particles uniformly dispersed into W grains and grain-boundaries. Via this technology, fine-grain W materials with near-full density and relatively high mechanical properties compared with traditional pure W material were manufactured. Preliminary transient high-heat flux tests were performed to evaluate the thermal response under plasma disruption conditions, and the results show that the W materials prepared by micro/nano composite technology can endure high-heat flux of 200 MW/m2 (5 ms).

Microgravity fluid management requirements of advanced solar dynamic power systems

NASA Technical Reports Server (NTRS)

Migra, Robert P.

1987-01-01

The advanced solar dynamic system (ASDS) program is aimed at developing the technology for highly efficient, lightweight space power systems. The approach is to evaluate Stirling, Brayton and liquid metal Rankine power conversion systems (PCS) over the temperature range of 1025 to 1400K, identify the critical technologies and develop these technologies. Microgravity fluid management technology is required in several areas of this program, namely, thermal energy storage (TES), heat pipe applications and liquid metal, two phase flow Rankine systems. Utilization of the heat of fusion of phase change materials offers potential for smaller, lighter TES systems. The candidate TES materials exhibit large volume change with the phase change. The heat pipe is an energy dense heat transfer device. A high temperature application may transfer heat from the solar receiver to the PCS working fluid and/or TES. A low temperature application may transfer waste heat from the PCS to the radiator. The liquid metal Rankine PCS requires management of the boiling/condensing process typical of two phase flow systems.

DE-FOA-EE0005502 Advanced Percussive Drilling Technology for Geothermal Exploration and Development Phase II Report.

DOE Office of Scientific and Technical Information (OSTI.GOV)

Su, Jiann-Cherng; Raymond, David W.; Prasad, Somuri V.

Percussive hammers are a promising advance in drilling technology for geothermal since they rely upon rock reduction mechanisms that are well-suited for use in the hard, brittle rock characteristic of geothermal formations. The project research approach and work plan includes a critical path to development of a high-temperature (HT) percussive hammer using a two- phase approach. The work completed in Phase I of the project demonstrated the viability of percussive hammers and that solutions to technical challenges in design, material technology, and performance are likely to be resolved. Work completed in Phase II focused on testing the findings from Phasemore » I and evaluating performance of the materials and designs at high- operating temperatures. A high-operating temperature (HOT) drilling facility was designed, built, and used to test the performance of the DTH under extreme conditions. Results from the testing indicate that a high-temperature capable hammer can be developed and is a viable alternative for user in the driller's toolbox.« less

Advanced Percussive Drilling Technology for Geothermal Exploration and Development

DOE Office of Scientific and Technical Information (OSTI.GOV)

Su, Jiann; Raymond, David; Prasad, Somuri

Percussive hammers are a promising advance in drilling technology for geothermal since they rely upon rock reduction mechanisms that are well-suited for use in the hard, brittle rock characteristic of geothermal formations. The project research approach and work plan includes a critical path to development of a high-temperature (HT) percussive hammer using a two phase approach. The work completed in Phase I of the project demonstrated the viability of percussive hammers and that solutions to technical challenges in design, material technology, and performance are likely to be resolved. Work completed in Phase II focused on testing the findings from Phasemore » I and evaluating performance of the materials and designs at high operating temperatures. A high-operating temperature (HOT) drilling facility was designed, built, and used to test the performance of the DTH under extreme conditions. Results from the testing indicate that a high-temperature capable hammer can be developed and is a viable alternative for use in the driller’s toolbox.« less

Functional Characterization of a Novel Shape Memory Alloy

NASA Astrophysics Data System (ADS)

Collado, M.; Cabás, R.; San Juan, J.; López-Ferreño, I.

2014-07-01

A novel shape memory alloy (SMA) has been developed as an alternative to currently available alloys. This alloy, commercially known by its proprietary brand SMARQ, shows a higher working range of temperatures with respect to the SMA materials used until now in actuators, limited to environment temperatures below 90 °C. SMARQ is a high temperature SMA (HTSMA) based on a fully European material technology and production processes, which allows the manufacture of high quality products, with tuneable transformation temperatures up to 200 °C. Both, material and production processes have been evaluated for its use in space applications. A full characterization test campaign has been completed in order to obtain the material properties and check its suitability to be used as active material in space actuators. In order to perform the functional characterization of the material, it has been considered as the key element of a basic SMA actuator, consisting in the SMA wire and the mechanical and electrical interfaces. The functional tests presented in this work have been focused on the actuator behavior when heated by means of an electrical current. Alloy composition has been adjusted in order to match a transition temperature (As) of +145 °C, which satisfies the application requirements of operating temperatures in the range of -70 and +125 °C. Details of the tests and results of the characterization test campaign, focused in the material unique properties for their use in actuators, will be presented in this work. Some application examples in the field of space mechanisms and actuators, currently under development, will be summarized as part of this work, demonstrating the technology suitability as active material for space actuators.

Carboxylate-based molecular magnet: One path toward achieving stable quantum correlations at room temperature

DOE PAGES

Cruz, C.; Soares-Pinto, D. O.; Brandão, P.; ...

2016-03-07

The control of quantum correlations in solid-state systems by means of material engineering is a broad avenue to be explored, since it makes possible steps toward the limits of quantum mechanics and the design of novel materials with applications on emerging quantum technologies. This letter explores the potential of molecular magnets to be prototypes of materials for quantum information technology in this context. More precisely, we engineered a material and from its geometric quantum discord we found significant quantum correlations up to 9540 K (even without entanglement); and, a pure singlet state occupied up to around 80 K (above liquidmore » nitrogen temperature), additionally. Our results could only be achieved due to the carboxylate group promoting a metal-to-metal huge magnetic interaction.« less

NASA's high-temperature engine materials program for civil aeronautics

NASA Technical Reports Server (NTRS)

Gray, Hugh R.; Ginty, Carol A.

1992-01-01

The Advanced High-Temperature Engine Materials Technology Program is described in terms of its research initiatives and its goal of developing propulsion systems for civil aeronautics with low levels of noise, pollution, and fuel consumption. The program emphasizes the analysis and implementation of structural materials such as polymer-matrix composites in fans, casings, and engine-control systems. Also investigated in the program are intermetallic- and metal-matrix composites for uses in compressors and turbine disks as well as ceramic-matrix composites for extremely high-temperature applications such as turbine vanes.

Progress in materials and structures at Lewis Research Center

NASA Technical Reports Server (NTRS)

Glasgow, T. K.; Lauver, R. W.; Halford, G. R.; Davies, R. L.

1980-01-01

The development of power and propulsion system technology is discussed. Specific emphasis is placed on the following: high temperature materials; composite materials; advanced design and life prediction; and nondestructive evaluation. Future areas of research are also discussed.

Materials and structural aspects of advanced gas-turbine helicopter engines

NASA Technical Reports Server (NTRS)

Freche, J. C.; Acurio, J.

1979-01-01

Advances in materials, coatings, turbine cooling technology, structural and design concepts, and component-life prediction of helicopter gas-turbine-engine components are presented. Stationary parts including the inlet particle separator, the front frame, rotor tip seals, vanes and combustors and rotating components - compressor blades, disks, and turbine blades - are discussed. Advanced composite materials are considered for the front frame and compressor blades, prealloyed powder superalloys will increase strength and reduce costs of disks, the oxide dispersion strengthened alloys will have 100C higher use temperature in combustors and vanes than conventional superalloys, ceramics will provide the highest use temperature of 1400C for stator vanes and 1370C for turbine blades, and directionally solidified eutectics will afford up to 50C temperature advantage at turbine blade operating conditions. Coatings for surface protection at higher surface temperatures and design trends in turbine cooling technology are discussed. New analytical methods of life prediction such as strain gage partitioning for high temperature prediction, fatigue life, computerized prediction of oxidation resistance, and advanced techniques for estimating coating life are described.

Microscopic origins of the large piezoelectricity of leadfree (Ba,Ca)(Zr,Ti)O3

NASA Astrophysics Data System (ADS)

Nahas, Yousra; Akbarzadeh, Alireza; Prokhorenko, Sergei; Prosandeev, Sergey; Walter, Raymond; Kornev, Igor; Íñiguez, Jorge; Bellaiche, L.

2017-06-01

In light of directives around the world to eliminate toxic materials in various technologies, finding lead-free materials with high piezoelectric responses constitutes an important current scientific goal. As such, the recent discovery of a large electromechanical conversion near room temperature in (1-x)Ba(Zr0.2Ti0.8)O3-x(Ba0.7Ca0.3)TiO3 compounds has directed attention to understanding its origin. Here, we report the development of a large-scale atomistic scheme providing a microscopic insight into this technologically promising material. We find that its high piezoelectricity originates from the existence of large fluctuations of polarization in the orthorhombic state arising from the combination of a flat free-energy landscape, a fragmented local structure, and the narrow temperature window around room temperature at which this orthorhombic phase is the equilibrium state. In addition to deepening the current knowledge on piezoelectricity, these findings have the potential to guide the design of other lead-free materials with large electromechanical responses.

An Overview of 2014 SBIR Phase I and Phase II Materials Structures for Extreme Environments

NASA Technical Reports Server (NTRS)

Nguyen, Hung D.; Steele, Gynelle C.; Morris, Jessica R.

2015-01-01

NASA's Small Business Innovation Research (SBIR) program focuses on technological innovation by investing in development of innovative concepts and technologies to help NASA mission directorates address critical research needs for Agency programs. This report highlights nine of the innovative SBIR 2014 Phase I and Phase II projects that emphasize one of NASA Glenn Research Center's six core competencies-Materials and Structures for Extreme Environments. The technologies cover a wide spectrum of applications such as high temperature environmental barrier coating systems, deployable space structures, solid oxide fuel cells, and self-lubricating hard coatings for extreme temperatures. Each featured technology describes an innovation, technical objective, and highlights NASA commercial and industrial applications. This report provides an opportunity for NASA engineers, researchers, and program managers to learn how NASA SBIR technologies could help their programs and projects, and lead to collaborations and partnerships between the small SBIR companies and NASA that would benefit both.

Seal Technology for Hypersonic Vehicle and Propulsion: An Overview

NASA Technical Reports Server (NTRS)

Steinetz, Bruce M.

2008-01-01

Hypersonic vehicles and propulsion systems pose an extraordinary challenge for structures and materials. Airframes and engines require lightweight, high-temperature materials and structural configurations that can withstand the extreme environment of hypersonic flight. Some of the challenges posed include very high temperatures, heating of the whole vehicle, steady-state and transient localized heating from shock waves, high aerodynamic loads, high fluctuating pressure loads, potential for severe flutter, vibration, and acoustic loads and erosion. Correspondingly high temperature seals are required to meet these aggressive requirements. This presentation reviews relevant seal technology for both heritage (e.g. Space Shuttle, X-15, and X-38) vehicles and presents several seal case studies aimed at providing lessons learned for future hypersonic vehicle seal development. This presentation also reviews seal technology developed for the National Aerospace Plane propulsion systems and presents several seal case studies aimed at providing lessons learned for future hypersonic propulsion seal development.

High-Power, High-Temperature Superconductor Technology Development

NASA Technical Reports Server (NTRS)

Bhasin, Kul B.

2005-01-01

Since the first discovery of high-temperature superconductors (HTS) 10 years ago, the most promising areas for their applications in microwave systems have been as passive components for communication systems. Soon after the discovery, experiments showed that passive microwave circuits made from HTS material exceeded the performance of conventional devices for low-power applications and could be 10 times as small or smaller. However, for superconducting microwave components, high-power microwave applications have remained elusive until now. In 1996, DuPont and Com Dev Ltd. developed high-power superconducting materials and components for communication applications under a NASA Lewis Research Center cooperative agreement, NCC3-344 "High Power High Temperature Superconductor (HTS) Technology Development." The agreement was cost shared between the Defense Advanced Research Projects Agency's (DARPA) Technology Reinvestment Program Office and the two industrial partners. It has the following objectives: 1) Material development and characterization for high-power HTS applications; 2) Development and validation of generic high-power microwave components; 3) Development of a proof-of-concept model for a high-power six-channel HTS output multiplexer.

Plasma technologies application for building materials surface modification

NASA Astrophysics Data System (ADS)

Volokitin, G. G.; Skripnikova, N. K.; Volokitin, O. G.; Shehovtzov, V. V.; Luchkin, A. G.; Kashapov, N. F.

2016-01-01

Low temperature arc plasma was used to process building surface materials, such as silicate brick, sand lime brick, concrete and wood. It was shown that building surface materials modification with low temperature plasma positively affects frost resistance, water permeability and chemical resistance with high adhesion strength. Short time plasma processing is rather economical than traditional processing thermic methods. Plasma processing makes wood surface uniquely waterproof and gives high operational properties, dimensional and geometrical stability. It also increases compression resistance and decreases inner tensions level in material.

High Temperature Polymeric Materials for Space Transportation Propulsion Applications

NASA Technical Reports Server (NTRS)

Meador, Michael A.; Campbell, Sandi G.; Chuang, Kathy C.; Scheimann, Daniel A.; Mintz, Eric; Hylton, Donald; Veazie, David; Criss, James; Kollmansberg, Ron; Tsotsis, Tom

2003-01-01

High temperature polymer matrix composites are attractive materials for space transporation propulsion systems because of their low density and high specific strength. However, the relatively poor stability and processability of these materials can render them unsuitable for many of these applications. New polymeric materials have been developed under the Propulsion Research and Technology Program through the use of novel resin chemistry and nanotechnology. These new materials can significantly enhance the durability and weight and improve the processability and affordability of propulsion components for advanced space transportation systems.

Advanced Power Electronics Components

NASA Technical Reports Server (NTRS)

Schwarze, Gene E.

2004-01-01

This paper will give a description and status of the Advanced Power Electronics Materials and Components Technology program being conducted by the NASA Glenn Research Center for future aerospace power applications. The focus of this research program is on the following: 1) New and/or significantly improved dielectric materials for the development of power capacitors with increased volumetric efficiency, energy density, and operating temperature. Materials being investigated include nanocrystalline and composite ceramic dielectrics and diamond-like carbon films; 2) New and/or significantly improved high frequency, high temperature, low loss soft magnetic materials for the development of transformers/inductors with increased power/energy density, electrical efficiency, and operating temperature. Materials being investigated include nanocrystalline and nanocomposite soft magnetic materials; 3) Packaged high temperature, high power density, high voltage, and low loss SiC diodes and switches. Development of high quality 4H- and 6H- SiC atomically smooth substrates to significantly improve device performance is a major emphasis of the SiC materials program; 4) Demonstration of high temperature (> 200 C) circuits using the components developed above.

Microwave processed NiMg ferrite: Studies on structural and magnetic properties

NASA Astrophysics Data System (ADS)

Chandra Babu Naidu, K.; Madhuri, W.

2016-12-01

Ferrites are magnetic semiconductors realizing an important role in electrical and electronic circuits where electrical and magnetic property coupling is required. Though ferrite materials are known for a long time, there is a large scope in the improvement of their properties (vice sintering and frequency dependence of electrical and magnetic properties) with the current technological trends. Forth coming technology is aimed at miniaturization and smart gadgets, electrical components like inductors and transformers cannot be included in integrated circuits. These components are incorporated into the circuit as surface mount devices whose fabrication involves low temperature co-firing of ceramics and microwave monolithic integrated circuits technologies. These technologies demand low temperature sinter-ability of ferrites. This article presents low temperature microwave sintered Ni-Mg ferrites of general chemical formula Ni1-xMgxFe2O4 (x=0, 0.2, 0.4, 0.5, 0.6, 0.8, 1) for potential applications as transformer core materials. The series of ferrites are characterized using X-ray diffractometer, scanning electron microscopy, Fourier transform infrared and vibrating sample magnetometer for investigating structural, morphological and magnetic properties respectively. The initial permeability is studied with magnesium content, temperature and frequency in the temperature range of 308 K-873 K and 42 Hz-5 MHz.

High-Temperature Structures, Adhesives, and Advanced Thermal Protection Materials for Next-Generation Aeroshell Design

NASA Technical Reports Server (NTRS)

Collins, Timothy J.; Congdon, William M.; Smeltzer, Stanley S.; Whitley, Karen S.

2005-01-01

The next generation of planetary exploration vehicles will rely heavily on robust aero-assist technologies, especially those that include aerocapture. This paper provides an overview of an ongoing development program, led by NASA Langley Research Center (LaRC) and aimed at introducing high-temperature structures, adhesives, and advanced thermal protection system (TPS) materials into the aeroshell design process. The purpose of this work is to demonstrate TPS materials that can withstand the higher heating rates of NASA's next generation planetary missions, and to validate high-temperature structures and adhesives that can reduce required TPS thickness and total aeroshell mass, thus allowing for larger science payloads. The effort described consists of parallel work in several advanced aeroshell technology areas. The areas of work include high-temperature adhesives, high-temperature composite materials, advanced ablator (TPS) materials, sub-scale demonstration test articles, and aeroshell modeling and analysis. The status of screening test results for a broad selection of available higher-temperature adhesives is presented. It appears that at least one (and perhaps a few) adhesives have working temperatures ranging from 315-400 C (600-750 F), and are suitable for TPS-to-structure bondline temperatures that are significantly above the traditional allowable of 250 C (482 F). The status of mechanical testing of advanced high-temperature composite materials is also summarized. To date, these tests indicate the potential for good material performance at temperatures of at least 600 F. Application of these materials and adhesives to aeroshell systems that incorporate advanced TPS materials may reduce aeroshell TPS mass by 15% - 30%. A brief outline is given of work scheduled for completion in 2006 that will include fabrication and testing of large panels and subscale aeroshell test articles at the Solar-Tower Test Facility located at Kirtland AFB and operated by Sandia National Laboratories. These tests are designed to validate aeroshell manufacturability using advanced material systems, and to demonstrate the maintenance of bondline integrity at realistically high temperatures and heating rates. Finally, a status is given of ongoing aeroshell modeling and analysis efforts which will be used to correlate with experimental testing, and to provide a reliable means of extrapolating to performance under actual flight conditions. The modeling and analysis effort includes a parallel series of experimental tests to determine TSP thermal expansion and other mechanical properties which are required for input to the analysis models.

Department of Defense Advisory Group on Electron Devices. Special Technology Area Review on Microwave Packaging Technology. Appendix

DTIC Science & Technology

1993-02-01

sintered in hydrogen furnace at very high temperatures . Multiple furnace firing occurs until the binders are removed and part density is achieved "* Process...and base Low temperature co-fired ceramic - Metallized for shielding and grounding - Low resistance thick-film metallization - High thermal resistance...ESPECIALLY LOW TEMPERATURE COFIRED CERAMIC CERAMICS HIGH THERMAL CONDUCTIVITY,MATCHED GaAS AND SILICON SUBSTRATE MATERIALS I I,1Z#A,17Mr1 J, TI

Harsh Environment Silicon Carbide Sensor Technology for Geothermal Instrumentation

DOE Office of Scientific and Technical Information (OSTI.GOV)

Pisano, Albert P.

2013-04-26

This project utilizes Silicon Carbide (SiC) materials platform to fabricate advanced sensors to be used as high-temperature downhole instrumentation for the DOE’s Geothermal Technologies Program on Enhanced Geothermal Systems. The scope of the proposed research is to 1) develop a SiC pressure sensor that can operate in harsh supercritical conditions, 2) develop a SiC temperature sensor that can operate in harsh supercritical conditions, 3) develop a bonding process for adhering SiC sensor die to well casing couplers, and 4) perform experimental exposure testing of sensor materials and the sensor devices.

Radiation Hardened Electronics for Extreme Environments

NASA Technical Reports Server (NTRS)

Keys, Andrew S.; Watson, Michael D.

2007-01-01

The Radiation Hardened Electronics for Space Environments (RHESE) project consists of a series of tasks designed to develop and mature a broad spectrum of radiation hardened and low temperature electronics technologies. Three approaches are being taken to address radiation hardening: improved material hardness, design techniques to improve radiation tolerance, and software methods to improve radiation tolerance. Within these approaches various technology products are being addressed including Field Programmable Gate Arrays (FPGA), Field Programmable Analog Arrays (FPAA), MEMS Serial Processors, Reconfigurable Processors, and Parallel Processors. In addition to radiation hardening, low temperature extremes are addressed with a focus on material and design approaches.

Jet engine applications for materials with nanometer-scale dimensions

NASA Technical Reports Server (NTRS)

Appleby, J. W., Jr.

1995-01-01

The performance of advanced military and commercial gas turbine engines is often linked to advances in materials technology. High performance gas turbine engines being developed require major material advances in strength, toughness, reduced density and improved temperature capability. The emerging technology of nanostructured materials has enormous potential for producing materials with significant improvements in these properties. Extraordinary properties demonstrated in the laboratory include material strengths approaching theoretical limit, ceramics that demonstrate ductility and toughness, and materials with ultra-high hardness. Nanostructured materials and coatings have the potential for meeting future gas turbine engine requirements for improved performance, reduced weight and lower fuel consumption.

Jet engine applications for materials with nanometer-scale dimensions

NASA Technical Reports Server (NTRS)

Appleby, J. W., Jr.

1995-01-01

The performance of advanced military and commercial gas turbine engines is often linked to advances in materials technology. High performance gas turbine engines being developed require major material advances in strength, toughness, reduced density and improved temperature capability. The emerging technology of nanostructured materials has enormous potential for producing materials with significant improvements in these properties. Extraordinary properties demonstrated in the laboratory include material strengths approaching theoretical limit, ceramics that demonstrate ductility and toughness, and material with ultra-high hardness. Nanostructured materials and coatings have the potential for meeting future gas turbine engine requirements for improved performance, reduced weight and lower fuel consumption.

Piezoelectricity above the Curie temperature? Combining flexoelectricity and functional grading to enable high-temperature electromechanical coupling

DOE Office of Scientific and Technical Information (OSTI.GOV)

Mbarki, R.; Baccam, N.; Dayal, Kaushik

Most technologically relevant ferroelectrics typically lose piezoelectricity above the Curie temperature. This limits their use to relatively low temperatures. In this Letter, exploiting a combination of flexoelectricity and simple functional grading, we propose a strategy for high-temperature electromechanical coupling in a standard thin film configuration. We use continuum modeling to quantitatively demonstrate the possibility of achieving apparent piezoelectric materials with large and temperature-stable electromechanical coupling across a wide temperature range that extends significantly above the Curie temperature. With Barium and Strontium Titanate, as example materials, a significant electromechanical coupling that is potentially temperature-stable up to 900 °C is possible.

Non-destructive inspection approach using ultrasound to identify the material state for amorphous and semi-crystalline materials

NASA Astrophysics Data System (ADS)

Jost, Elliott; Jack, David; Moore, David

2018-04-01

At present, there are many methods to identify the temperature and phase of a material using invasive techniques. However, most current methods require physical contact or implicit methods utilizing light reflectance of the specimen. This work presents a nondestructive inspection method using ultrasonic wave technology that circumvents these disadvantages to identify phase change regions and infer the temperature state of a material. In the present study an experiment is performed to monitor the time of flight within a wax as it undergoes melting and the subsequent cooling. Results presented in this work show a clear relationship between a material's speed of sound and its temperature. The phase change transition of the material is clear from the time of flight results, and in the case of the investigated material, this change in the material state occurs over a range of temperatures. The range of temperatures over which the wax material melts is readily identified by speed of sound represented as a function of material temperature. The melt temperature, obtained acoustically, is validated using Differential Scanning Calorimetry (DSC), which uses shifts in heat flow rates to identify phase transition temperature ranges. The investigated ultrasonic NDE method has direct applications in many industries, including oil and gas, food and beverage, and polymer composites, in addition to many implications for future capabilities of nondestructive inspection of multi-phase materials.

Research on precise control of 3D print nozzle temperature in PEEK material

NASA Astrophysics Data System (ADS)

Liu, Zhichao; Wang, Gong; Huo, Yu; Zhao, Wei

2017-10-01

3D printing technology has shown more and more applicability in medication, designing and other fields for its low cost and high timeliness. PEEK (poly-ether-ether-ketone), as a typical high-performance special engineering plastic, become one of the most excellent materials to be used in 3D printing technology because of its excellent mechanical property, good lubricity, chemical resistance, and other properties. But the nozzle of 3D printer for PEEK has also a series of very high requirements. In this paper, we mainly use the nozzle temperature control as the research object, combining with the advantages and disadvantages of PID control and fuzzy control. Finally realize a kind of fuzzy PID controller to solve the problem of the inertia of the temperature system and the seriousness of the temperature control hysteresis in the temperature control of the nozzle, and to meet the requirements of the accuracy of the nozzle temperature control and rapid reaction.

Orbital transfer rocket engine technology program: Soft wear ring seal technology

NASA Technical Reports Server (NTRS)

Lariviere, Brian W.

1992-01-01

Liquid oxygen (LOX) compatibility tests, including autogenous ignition, promoted ignition, LOX impact tests, and friction and wear tests on different PV products were conducted for several polymer materials as verification for the implementation of soft wear ring seals in advanced rocket engine turbopumps. Thermoplastics, polyimide based materials, and polyimide-imide base materials were compared for oxygen compatibility, specific wear coefficient, wear debris production, and heat dissipation mechanisms. A thermal model was generated that simulated the frictional heating input and calculated the surface temperature and temperature distribution within the seal. The predictions were compared against measured values. Heat loads in the model were varied to better match the test data and determine the difference between the measured and the calculated coefficients of friction.

Flexible MEMS: A novel technology to fabricate flexible sensors and electronics

NASA Astrophysics Data System (ADS)

Tu, Hongen

This dissertation presents the design and fabrication techniques used to fabricate flexible MEMS (Micro Electro Mechanical Systems) devices. MEMS devices and CMOS(Complementary Metal-Oxide-Semiconductor) circuits are traditionally fabricated on rigid substrates with inorganic semiconductor materials such as Silicon. However, it is highly desirable that functional elements like sensors, actuators or micro fluidic components to be fabricated on flexible substrates for a wide variety of applications. Due to the fact that flexible substrate is temperature sensitive, typically only low temperature materials, such as polymers, metals, and organic semiconductor materials, can be directly fabricated on flexible substrates. A novel technology based on XeF2(xenon difluoride) isotropic silicon etching and parylene conformal coating, which is able to monolithically incorporate high temperature materials and fluidic channels, was developed at Wayne State University. The technology was first implemented in the development of out-of-plane parylene microneedle arrays that can be individually addressed by integrated flexible micro-channels. These devices enable the delivery of chemicals with controlled temporal and spatial patterns and allow us to study neurotransmitter-based retinal prosthesis. The technology was further explored by adopting the conventional SOI-CMOS processes. High performance and high density CMOS circuits can be first fabricated on SOI wafers, and then be integrated into flexible substrates. Flexible p-channel MOSFETs (Metal-Oxide-Semiconductor Field-Effect-Transistors) were successfully integrated and tested. Integration of pressure sensors and flow sensors based on single crystal silicon has also been demonstrated. A novel smart yarn technology that enables the invisible integration of sensors and electronics into fabrics has been developed. The most significant advantage of this technology is its post-MEMS and post-CMOS compatibility. Various high-performance MEMS devices and electronics can be integrated into flexible substrates. The potential of our technology is enormous. Many wearable and implantable devices can be developed based on this technology.

Development of high temperature containerless processing equipment and the design and evaluation of associated systems required for microgravity materials processing and property measurements

NASA Technical Reports Server (NTRS)

Rey, Charles A.

1991-01-01

The development of high temperature containerless processing equipment and the design and evaluation of associated systems required for microgravity materials processing and property measurements are discussed. Efforts were directed towards the following task areas: design and development of a High Temperature Acoustic Levitator (HAL) for containerless processing and property measurements at high temperatures; testing of the HAL module to establish this technology for use as a positioning device for microgravity uses; construction and evaluation of a brassboard hot wall Acoustic Levitation Furnace; construction and evaluation of a noncontact temperature measurement (NCTM) system based on AGEMA thermal imaging camera; construction of a prototype Division of Amplitude Polarimetric Pyrometer for NCTM of levitated specimens; evaluation of and recommendations for techniques to control contamination in containerless materials processing chambers; and evaluation of techniques for heating specimens to high temperatures for containerless materials experimentation.

Development of high temperature containerless processing equipment and the design and evaluation of associated systems required for microgravity materials processing and property measurements

NASA Astrophysics Data System (ADS)

Rey, Charles A.

1991-03-01

The development of high temperature containerless processing equipment and the design and evaluation of associated systems required for microgravity materials processing and property measurements are discussed. Efforts were directed towards the following task areas: design and development of a High Temperature Acoustic Levitator (HAL) for containerless processing and property measurements at high temperatures; testing of the HAL module to establish this technology for use as a positioning device for microgravity uses; construction and evaluation of a brassboard hot wall Acoustic Levitation Furnace; construction and evaluation of a noncontact temperature measurement (NCTM) system based on AGEMA thermal imaging camera; construction of a prototype Division of Amplitude Polarimetric Pyrometer for NCTM of levitated specimens; evaluation of and recommendations for techniques to control contamination in containerless materials processing chambers; and evaluation of techniques for heating specimens to high temperatures for containerless materials experimentation.

Processing of extraterrestrial materials by high temperature vacuum vaporization

NASA Technical Reports Server (NTRS)

Grimley, R. T.; Lipschutz, M. E.

1983-01-01

It is noted that problems associated with the extraction and concentration of elements and commpounds important for the construction and operation of space habitats have received little attention. High temperature vacuum vaporization is considered a promising approach; this is a technique for which the space environment offers advantages in the form of low ambient pressures and temperatures and the possibility of sustained high temperatures via solar thermal energy. To establish and refine this new technology, experimental determinations must be made of the material release profiles as a function of temperature, of the release kinetics and chemical forms of material being transported, and of the various means of altering release kinetics. Trace element data determined by neutron activation analysis of meteorites heated to 1400 C in vacuum is summarized. The principal tool, high temperature spectrometry, is used to examine the vaporization thermodynamics and kinetics of major and minor elements from complex multicomponent extraterrestrial materials.

Thermoelectric Energy Conversion Technology for High-Altitude Airships

NASA Technical Reports Server (NTRS)

Choi, Sang H.; Elliott, James R.; King, Glen C.; Park, Yeonjoon; Kim, Jae-Woo; Chu, Sang-Hyon

2011-01-01

The High Altitude Airship (HAA) has various application potential and mission scenarios that require onboard energy harvesting and power distribution systems. The power technology for HAA maneuverability and mission-oriented applications must come from its surroundings, e.g. solar power. The energy harvesting system considered for HAA is based on the advanced thermoelectric (ATE) materials being developed at NASA Langley Research Center. The materials selected for ATE are silicon germanium (SiGe) and bismuth telluride (Bi2Te3), in multiple layers. The layered structure of the advanced TE materials is specifically engineered to provide maximum efficiency for the corresponding range of operational temperatures. For three layers of the advanced TE materials that operate at high, medium, and low temperatures, correspondingly in a tandem mode, the cascaded efficiency is estimated to be greater than 60 percent.

Iron Disilicide as High-Temperature Reference Material for Traceable Measurements of Seebeck Coefficient Between 300 K and 800 K

NASA Astrophysics Data System (ADS)

Ziolkowski, Pawel; Stiewe, Christian; de Boor, Johannes; Druschke, Ines; Zabrocki, Knud; Edler, Frank; Haupt, Sebastian; König, Jan; Mueller, Eckhard

2017-01-01

Thermoelectric generators (TEGs) convert heat to electrical energy by means of the Seebeck effect. The Seebeck coefficient is a central thermoelectric material property, measuring the magnitude of the thermovoltage generated in response to a temperature difference across a thermoelectric material. Precise determination of the Seebeck coefficient provides the basis for reliable performance assessment in materials development in the field of thermoelectrics. For several reasons, measurement uncertainties of up to 14% can often be observed in interlaboratory comparisons of temperature-dependent Seebeck coefficient or in error analyses on currently employed instruments. This is still too high for an industrial benchmark and insufficient for many scientific investigations and technological developments. The TESt (thermoelectric standardization) project was launched in 2011, funded by the German Federal Ministry of Education and Research (BMBF), to reduce measurement uncertainties, engineer traceable and precise thermoelectric measurement techniques for materials and TEGs, and develop reference materials (RMs) for temperature-dependent determination of the Seebeck coefficient. We report herein the successful development and qualification of cobalt-doped β-iron disilicide ( β-Fe0.95Co0.05Si2) as a RM for high-temperature thermoelectric metrology. A brief survey on technological processes for manufacturing and machining of samples is presented. Focus is placed on metrological qualification of the iron disilicide, results of an international round-robin test, and final certification as a reference material in accordance with ISO-Guide 35 and the "Guide to the expression of uncertainty in measurement" by the Physikalisch-Technische Bundesanstalt, the national metrology institute of Germany.

The preparation and infrared radar stealth performance test of a new paraffin-based phase transition microcapsule

NASA Astrophysics Data System (ADS)

Chen, Yingming; Zhang, Honghong; Gao, Weiting; Chen, Yingmin; Wang, Yifan

2018-04-01

For the problems that the phase change material apply to infrared stealth exists easy to broken, hard to control temperature, narrow infrared channel and based on the basic principles of infrared stealth technology, this paper proposed a scheme of thermal infrared composite invisibility multi-layer wrapping, which based on two sides, one is to control the material surface temperature, another is to reduce its infrared emissivity and combine with visible light pigment and electromagnetic wave absorbing material, to realize the materials' wide band compatible stealth. First, choose urea formaldehyde resin and paraffin to prepare multiphase-change microcapsules, and then combine it with the ferroferric oxide absorbing material, zinc oxide visible light pigment, to make the stealth material of wide band. The experimental results show that the new phase change capsule can realize the function of temperature control and infrared stealth in a special temperature range.

Lewis Researcher in the Materials and Stresses Building

NASA Image and Video Library

1952-12-21

A materials researcher at the NACA’s Lewis Flight Propulsion Laboratory examines a surface crack detection apparatus in the Materials and Stresses Building during December 1952. Materials research was an important aspect of propulsion technology. Advanced engine systems relied upon alloys, and later composites, that were strong, lightweight, and impervious to high temperatures. Jet engines which became increasingly popular in the late 1940s, produced much higher temperatures than piston engines. These higher temperatures stressed engine components, particularly turbines. Although Lewis materials research began during World War II, the Materials and Thermodynamics Division was not created until 1949. Its primary laboratories were located in the Materials and Stresses Building. The group sought to create new, improved materials and to improve engine design through increased understanding of materials. The Lewis materials researchers of the 1950s made contributions to nickel-aluminum alloys, cermet blades, metal matrix composites, oxide dispersion strengthened superalloys, and universal slopes.

RECENT ADVANCES IN HIGH TEMPERATURE ELECTROLYSIS AT IDAHO NATIONAL LABORATORY: STACK TESTS

DOE Office of Scientific and Technical Information (OSTI.GOV)

X, Zhang; J. E. O'Brien; R. C. O'Brien

2012-07-01

High temperature steam electrolysis is a promising technology for efficient sustainable large-scale hydrogen production. Solid oxide electrolysis cells (SOECs) are able to utilize high temperature heat and electric power from advanced high-temperature nuclear reactors or renewable sources to generate carbon-free hydrogen at large scale. However, long term durability of SOECs needs to be improved significantly before commercialization of this technology. A degradation rate of 1%/khr or lower is proposed as a threshold value for commercialization of this technology. Solid oxide electrolysis stack tests have been conducted at Idaho National Laboratory to demonstrate recent improvements in long-term durability of SOECs. Electrolytesupportedmore » and electrode-supported SOEC stacks were provided by Ceramatec Inc., Materials and Systems Research Inc. (MSRI), and Saint Gobain Advanced Materials (St. Gobain), respectively for these tests. Long-term durability tests were generally operated for a duration of 1000 hours or more. Stack tests based on technology developed at Ceramatec and MSRI have shown significant improvement in durability in the electrolysis mode. Long-term degradation rates of 3.2%/khr and 4.6%/khr were observed for MSRI and Ceramatec stacks, respectively. One recent Ceramatec stack even showed negative degradation (performance improvement) over 1900 hours of operation. A three-cell short stack provided by St. Gobain, however, showed rapid degradation in the electrolysis mode. Improvements on electrode materials, interconnect coatings, and electrolyteelectrode interface microstructures contribute to better durability of SOEC stacks.« less

High-temperature MIRAGE XL (LFRA) IRSP system development

NASA Astrophysics Data System (ADS)

McHugh, Steve; Franks, Greg; LaVeigne, Joe

2017-05-01

The development of very-large format infrared detector arrays has challenged the IR scene projector community to develop larger-format infrared emitter arrays. Many scene projector applications also require much higher simulated temperatures than can be generated with current technology. This paper will present an overview of resistive emitterbased (broadband) IR scene projector system development, as well as describe recent progress in emitter materials and pixel designs applicable for legacy MIRAGE XL Systems to achieve apparent temperatures >1000K in the MWIR. These new high temperature MIRAGE XL (LFRA) Digital Emitter Engines (DEE) will be "plug and play" equivalent with legacy MIRAGE XL DEEs, the rest of the system is reusable. Under the High Temperature Dynamic Resistive Array (HDRA) development program, Santa Barbara Infrared Inc. (SBIR) is developing a new infrared scene projector architecture capable of producing both very large format (>2k x 2k) resistive emitter arrays and improved emitter pixel technology capable of simulating very high apparent temperatures. During earlier phases of the program, SBIR demonstrated materials with MWIR apparent temperatures in excess of 1500 K. These new emitter materials can be utilized with legacy RIICs to produce pixels that can achieve 7X the radiance of the legacy systems with low cost and low risk. A 'scalable' Read-In Integrated Circuit (RIIC) is also being developed under the same HDRA program to drive the high temperature pixels. This RIIC will utilize through-silicon via (TSV) and Quilt Packaging (QP) technologies to allow seamless tiling of multiple chips to fabricate very large arrays, and thus overcome the yield limitations inherent in large-scale integrated circuits. These quilted arrays can be fabricated in any N x M size in 512 steps.

A review of high magnetic moment thin films for microscale and nanotechnology applications

DOE PAGES

Scheunert, Gunther; Heinonen, O.; Hardeman, R.; ...

2016-02-17

Here, the creation of large magnetic fields is a necessary component in many technologies, ranging from magnetic resonance imaging, electric motors and generators, and magnetic hard disk drives in information storage. This is typically done by inserting a ferromagnetic pole piece with a large magnetisation density M S in a solenoid. In addition to large M S, it is usually required or desired that the ferromagnet is magnetically soft and has a Curie temperature well above the operating temperature of the device. A variety of ferromagnetic materials are currently in use, ranging from FeCo alloys in, for example, hard diskmore » drives, to rare earth metals operating at cryogenic temperatures in superconducting solenoids. These latter can exceed the limit on M S for transition metal alloys given by the Slater-Pauling curve. This article reviews different materials and concepts in use or proposed for technological applications that require a large M S, with an emphasis on nanoscale material systems, such as thin and ultra-thin films. Attention is also paid to other requirements or properties, such as the Curie temperature and magnetic softness. In a final summary, we evaluate the actual applicability of the discussed materials for use as pole tips in electromagnets, in particular, in nanoscale magnetic hard disk drive read-write heads; the technological advancement of the latter has been a very strong driving force in the development of the field of nanomagnetism.« less

Space applications for high temperature superconductivity - Brief review

NASA Technical Reports Server (NTRS)

Krishen, Kumar

1990-01-01

An overview is presented of materials and devices based on high-temperature superconductivity (HTS) that could have useful space-oriented applications. Of specific interest are applications of HTS technologies to mm and microwave systems, spaceborne and planet-surface sensors, and to magnetic subsystems for robotic, rescue, and docking maneuvers. HTS technologies can be used in optoelectronics, magnetic-field detectors, antennae, transmission/delay lines, and launch/payload coils.

Additive Manufacturing of Advanced High Temperature Masking Fixtures for EBPVD TBC Coating

DOE Office of Scientific and Technical Information (OSTI.GOV)

List, III, Frederick Alyious; Feuerstein, Albert; Dehoff, Ryan

2016-03-30

The purpose of this Manufacturing Demonstration Facility (MDF) technical collaboration project between Praxair Surface Technologies, Inc. (PST) and Oak Ridge National Laboratory (ORNL) was to develop an additive manufacturing process to fabricate next generation high temperature masking fixtures for coating of turbine airfoils with ceramic Thermal Barrier Coatings (TBC) by the Electron Beam Physical Vapor Deposition (EBPVD) process. Typical masking fixtures are sophisticated designs and require complex part manipulation in order to achieve the desired coating distribution. Fixtures are typically fabricated from high temperature nickel (Ni) based superalloys. The fixtures are fabricated from conventional processes by welding of thin sheetmore » material into a complex geometry, to decrease the weight load for the manipulator and to reduce the thermal mass of the fixture. Recent attempts have been made in order to fabricate the fixtures through casting, but thin walled sections are difficult to cast and have high scrap rates. This project focused on understanding the potential for fabricating high temperature Ni based superalloy fixtures through additive manufacturing. Two different deposition processes; electron beam melting (EBM) and laser powder bed fusion were evaluated to determine the ideal processing route of these materials. Two different high temperature materials were evaluated. The high temperature materials evaluated were Inconel 718 and another Ni base alloy, designated throughout the remainder of this document as Alloy X, as the alloy composition is sensitive. Inconel 718 is a more widely utilized material for additive manufacturing although it is not currently the material utilized for current fixtures. Alloy X is the alloy currently used for the fixtures, but is not a commercially available alloy for additive manufacturing. Praxair determined it was possible to build the fixture using laser powder bed technology from Inconel 718. ORNL fabricated the fixture geometry using the EBM technology in order to compare deposition features such as surface roughness, geometric accuracy, deposition rate, surface and subsurface porosity, and material quality. It was determined that the laser powder bed technology was ideal for the geometry and requirements of the fixture set by Praxair, and Praxair moved forward with the purchase of a laser powder bed system. The subsequent portion of the project focused on determining the ideal processing parameters for alloy X for the laser powder bed system using ORNL’s Renishaw laser powder bed system. Praxair supplied gas atomized powders of alloy X material with properties specified by ORNL. ORNL printed text cube arrays in order to determine the ideal combination of laser powder and laser travel speed in order to maximize material density, improve surface quality, and maintain geometric accuracy. Additional powder supplied by Praxair was used to fabricate a full-scale fixture component.« less

Progress in advanced high temperature turbine materials, coatings, and technology

NASA Technical Reports Server (NTRS)

Freche, J. C.; Ault, G. M.

1977-01-01

Material categories as well as coatings and recent turbine cooling developments are reviewed. Current state of the art is identified, and as assessment, when appropriate, of progress, problems, and future directions is provided.

Alternative High-Performance Motors with Non-Rare Earth Materials, Final Publishable Report

DOE Office of Scientific and Technical Information (OSTI.GOV)

Galioto, Steven; Johnson, Francis

Electric drive systems, which include electric machines and power electronics, are a key enabling technology for advanced vehicle propulsion systems that reduce the petroleum dependence of the transportation sector. To have significant effect, electric drive technologies must be economical in terms of cost, weight, and size while meeting performance and reliability expectations. The goal of the project is to develop traction motors that reduce or eliminate the use of rare-earth materials and meet the DoE specifications for such a traction motor. This is accomplished by evaluating and developing multiple motor topologies in conjunction with advanced materials. Eight non-permanent magnet motormore » topologies and two reduced or non-rare earth motor topologies are analyzed and compared using a common set of requirements. Five of the motors are built and tested to validate the analysis. This paper provides a detailed quantitative comparison of the different machine topologies that reduce or eliminate rare-earth materials. Conclusions are drawn from the analysis and test data to show the tradeoffs related to selecting each of the motor topologies with the hope of providing practicing engineers and researchers in the field enough guidelines for choosing the “optimum” machine topology that suits their applications and set of performance requirements. Four materials technologies were investigated for their ability to enable a reduced rare earth electric motor. Two of the technologies were soft magnetic materials, one was a non-rare-earth containing permanent magnet technology, and the last was an insulation material. These processing and performance of these materials were first demonstrated in small coupons. The coupon tests justified proceeding to larger scale processing for two of the materials technologies: 1) a dual-phase soft magnetic material for use in rotor laminates and 2) a high temperature insulation material for use as a slot liner in the stator. The dual phase soft magnetic material was produced at a scale sufficient to build and test a sub-scale motor prototype. The high temperature insulation material was first evaluated in a series of “statorettes” before being demonstrated in the stator of one of the full-scale motor prototypes. Testing of the dual phase material revealed issues with process variability in larger production volumes that are being addressed in a subsequent project. The performance of the high-temperature slot liner insulation was demonstrated during the operation of a full-scale prototype. Furthermore, the insulation material was shown to survive aging tests of 2000 hours and 280 °C and 800 hours at 300 °C. This program provides analysis and data to accelerate the introduction of hybrid electric vehicles into the U.S. road vehicle fleet and bring the added benefits of reduced fuel consumption and environmental impacts« less

Innovative potential of plasma technology

NASA Astrophysics Data System (ADS)

Budaev, V. P.

2017-11-01

The review summarizes recent experimental observations of materials exposed to extreme hot plasma loads in fusion devices and plasma facilities with high-temperature plasma. Plasma load on the material in such devices lead to the stochastic clustering and fractal growth of the surface on scales from tens of nanometers to hundreds of micrometers forming statistical self-similarity of the surface roughness with extremely high specific area. Statistical characteristics of hierarchical granularity and scale invariance of such materials surface qualitatively differ from the properties of the roughness of the ordinary Brownian surface which provides a potential of innovative plasma technologies for synthesis of new nanostructured materials with programmed roughness properties, for hypersonic technologies, for biotechnology and biomedical applications.

Sample environment for neutron scattering measurements of internal stresses in engineering materials in the temperature range of 6 K to 300 K.

PubMed

Kirichek, O; Timms, J D; Kelleher, J F; Down, R B E; Offer, C D; Kabra, S; Zhang, S Y

2017-02-01

Internal stresses in materials have a considerable effect on material properties including strength, fracture toughness, and fatigue resistance. The ENGIN-X beamline is an engineering science facility at ISIS optimized for the measurement of strain and stress using the atomic lattice planes as a strain gauge. Nowadays, the rapidly rising interest in the mechanical properties of engineering materials at low temperatures has been stimulated by the dynamic development of the cryogenic industry and the advanced applications of the superconductor technology. Here we present the design and discuss the test results of a new cryogenic sample environment system for neutron scattering measurements of internal stresses in engineering materials under a load of up to 100 kN and in the temperature range of 6 K to 300 K. Complete cooling of the system starting from the room temperature down to the base temperature takes around 90 min. Understanding of internal stresses in engineering materials at cryogenic temperatures is vital for the modelling and designing of cutting-edge superconducting magnets and other superconductor based applications.

Sample environment for neutron scattering measurements of internal stresses in engineering materials in the temperature range of 6 K to 300 K

NASA Astrophysics Data System (ADS)

Kirichek, O.; Timms, J. D.; Kelleher, J. F.; Down, R. B. E.; Offer, C. D.; Kabra, S.; Zhang, S. Y.

2017-02-01

Internal stresses in materials have a considerable effect on material properties including strength, fracture toughness, and fatigue resistance. The ENGIN-X beamline is an engineering science facility at ISIS optimized for the measurement of strain and stress using the atomic lattice planes as a strain gauge. Nowadays, the rapidly rising interest in the mechanical properties of engineering materials at low temperatures has been stimulated by the dynamic development of the cryogenic industry and the advanced applications of the superconductor technology. Here we present the design and discuss the test results of a new cryogenic sample environment system for neutron scattering measurements of internal stresses in engineering materials under a load of up to 100 kN and in the temperature range of 6 K to 300 K. Complete cooling of the system starting from the room temperature down to the base temperature takes around 90 min. Understanding of internal stresses in engineering materials at cryogenic temperatures is vital for the modelling and designing of cutting-edge superconducting magnets and other superconductor based applications.

Physics and Technology of Transparent Ceramic Armor: Sintered Al2O3 vs Cubic Materials

DTIC Science & Technology

2006-08-01

4,841,195, June 20, 1989. [20] N. Saito, Sh.-I. Matsuda, T . Ikegami , "Fabrication of transparent yttria ceramics at low temperature using...Hutzler, T .; Klimke, J. (2005) Physics and Technology of Transparent Ceramic Armor: Sintered Al2O3 vs Cubic Materials. In Nanomaterials Technology...a greater loss of transmission. Or vice versa: all components with a real in-line transmission T < Tth suffer a loss (Tth - T ), and this loss

DOE Office of Scientific and Technical Information (OSTI.GOV)

Dr. Mohit Jain; Dr. Ganesh Skandan; Dr. Gordon E. Khose

Generation IV Very High Temperature power generating nuclear reactors will operate at temperatures greater than 900 oC. At these temperatures, the components operating in these reactors need to be fabricated from materials with excellent thermo-mechanical properties. Conventional pure or composite materials have fallen short in delivering the desired performance. New materials, or conventional materials with new microstructures, and associated processing technologies are needed to meet these materials challenges. Using the concept of functionally graded materials, we have fabricated a composite material which has taken advantages of the mechanical and thermal properties of ceramic and metals. Functionally-graded composite samples with variousmore » microstructures were fabricated. It was demonstrated that the composition and spatial variation in the composition of the composite can be controlled. Some of the samples were tested for irradiation resistance to neutrons. The samples did not degrade during initial neutron irradiation testing.« less

Investigation of the Phase Formation of AlSi-Coatings for Hot Stamping of Boron Alloyed Steel

NASA Astrophysics Data System (ADS)

Veit, R.; Hofmann, H.; Kolleck, R.; Sikora, S.

2011-01-01

Hot stamping of boron alloyed steel is gaining more and more importance for the production of high strength automotive body parts. Within hot stamping of quenchenable steels the blank is heated up to austenitization temperature, transferred to the tool, formed rapidly and quenched in the cooled tool. To avoid scale formation during the heating process of the blank, the sheet metal can be coated with an aluminium-silicum alloy. The meltimg temperature of this coating is below the austenitization temperature of the base material. This means, that a diffusion process between base material and coating has to take place during heating, leading to a higher melting temperature of the coating. In conventional heating devices, like roller hearth furnaces, the diffusion process is reached by relatively low heating rates. New technologies, like induction heating, reach very high heating rates and offer great potentials for the application in hot stamping. Till now it is not proofed, that this technology can be used with aluminum-silicon coated materials. This paper will present the results of comparative heating tests with a conventional furnace and an induction heating device. For different time/temperature-conditions the phase formation within the coating will be described.

Characterization of sapphire: For its material properties at high temperatures

NASA Astrophysics Data System (ADS)

Bal, Harman Singh

There are numerous needs for sensing, one of which is in pressure sensing for high temperature application such as combustion related process and embedded in aircraft wings for reusable space vehicles. Currently, silicon based MEMS technology is used for pressure sensing. However, due to material properties the sensors have a limited range of approximately 600 °C which is capable of being pushed towards 1000 °C with active cooling. This can introduce reliability issues when you add more parts and high flow rates to remove large amounts of heat. To overcome this challenge, sapphire is investigated for optical based pressure transducers at temperatures approaching 1400 °C. Due to its hardness and chemical inertness, traditional cutting and etching methods used in MEMS technology are not applicable. A method that is being investigated as a possible alternative is laser machining using a picosecond laser. In this research, we study the material property changes that occur from laser machining and quantify the changes with the experimental results obtained by testing sapphire at high-temperature with a standard 4-point bending set-up.

Materials technology for an advanced space power nuclear reactor concept: Program summary

NASA Technical Reports Server (NTRS)

Gluyas, R. E.; Watson, G. K.

1975-01-01

The results of a materials technology program for a long-life (50,000 hr), high-temperature (950 C coolant outlet), lithium-cooled, nuclear space power reactor concept are reviewed and discussed. Fabrication methods and compatibility and property data were developed for candidate materials for fuel pins and, to a lesser extent, for potential control systems, reflectors, reactor vessel and piping, and other reactor structural materials. The effects of selected materials variables on fuel pin irradiation performance were determined. The most promising materials for fuel pins were found to be 85 percent dense uranium mononitride (UN) fuel clad with tungsten-lined T-111 (Ta-8W-2Hf).

SYNTHESIS of MOLECULE/POLYMER-BASED MAGNETIC MATERIALS

DOE Office of Scientific and Technical Information (OSTI.GOV)

Miller, Joel S.

2016-02-01

We have synthesized and characterized several families of organic-based magnets, a new area showing that organic species can exhibit the technologically important property of magnetic ordering. Thin film magnets with ordering temperatures exceeding room temperature have been exceeded. Hence, organic-based magnets represent a new class of materials that exhibit magnetic ordering and do not require energy-intensive metallurgical processing and are based upon Earth-abundant elements.

The elastocaloric effect of Ni50.8Ti49.2 shape memory alloys

NASA Astrophysics Data System (ADS)

Zhou, Min; Li, Yushuang; Zhang, Chen; Li, Shaojie; Wu, Erfu; Li, Wei; Li, Laifeng

2018-04-01

Solid-state cooling technologies are considered as possible alternatives for vapor compression cooling systems. The elastocaloric cooling (whose caloric effects are driven by uniaxial stress) technology, as an efficient and clean solid-state cooling technology, is receiving a great deal of attention very recently. Herein, a NiTi-based elastocaloric bulk material was reported. A large coefficient-of-performance of the material (COPmater) of 4.5 was obtained, which was even higher than that of other NiTi bulk materials. The temperature changes (ΔT) increased with increasing applied strain (ɛ), and reached 18 K upon loading and  -11 K upon unloading when the ɛ value increased to 4%. The high temperature changes were attributed to the large stress-induced entropy changes (the maximum ΔS σ value was 37 J kg-1 K-1). The temperature changes decreased with loading-unloading tensile cycles, and stabilized at 6.5 K upon loading and  -6 K upon unloading after tens of mechanical cycles. The Ni50.8Ti49.2 shape memory alloy showed great promise for application in solid-state refrigeration (or as heat pumps).

Resistance fail strain gage technology as applied to composite materials

NASA Technical Reports Server (NTRS)

Tuttle, M. E.; Brinson, H. F.

1985-01-01

Existing strain gage technologies as applied to orthotropic composite materials are reviewed. The bonding procedures, transverse sensitivity effects, errors due to gage misalignment, and temperature compensation methods are addressed. Numerical examples are included where appropriate. It is shown that the orthotropic behavior of composites can result in experimental error which would not be expected based on practical experience with isotropic materials. In certain cases, the transverse sensitivity of strain gages and/or slight gage misalignment can result in strain measurement errors.

Advanced intermediate temperature sodium-nickel chloride batteries with ultra-high energy density.

PubMed

Li, Guosheng; Lu, Xiaochuan; Kim, Jin Y; Meinhardt, Kerry D; Chang, Hee Jung; Canfield, Nathan L; Sprenkle, Vincent L

2016-02-11

Sodium-metal halide batteries have been considered as one of the more attractive technologies for stationary electrical energy storage, however, they are not used for broader applications despite their relatively well-known redox system. One of the roadblocks hindering market penetration is the high-operating temperature. Here we demonstrate that planar sodium-nickel chloride batteries can be operated at an intermediate temperature of 190 °C with ultra-high energy density. A specific energy density of 350 Wh kg(-1), higher than that of conventional tubular sodium-nickel chloride batteries (280 °C), is obtained for planar sodium-nickel chloride batteries operated at 190 °C over a long-term cell test (1,000 cycles), and it attributed to the slower particle growth of the cathode materials at the lower operating temperature. Results reported here demonstrate that planar sodium-nickel chloride batteries operated at an intermediate temperature could greatly benefit this traditional energy storage technology by improving battery energy density, cycle life and reducing material costs.

Advanced intermediate temperature sodium-nickel chloride batteries with ultra-high energy density

NASA Astrophysics Data System (ADS)

Li, Guosheng; Lu, Xiaochuan; Kim, Jin Y.; Meinhardt, Kerry D.; Chang, Hee Jung; Canfield, Nathan L.; Sprenkle, Vincent L.

2016-02-01

Sodium-metal halide batteries have been considered as one of the more attractive technologies for stationary electrical energy storage, however, they are not used for broader applications despite their relatively well-known redox system. One of the roadblocks hindering market penetration is the high-operating temperature. Here we demonstrate that planar sodium-nickel chloride batteries can be operated at an intermediate temperature of 190 °C with ultra-high energy density. A specific energy density of 350 Wh kg-1, higher than that of conventional tubular sodium-nickel chloride batteries (280 °C), is obtained for planar sodium-nickel chloride batteries operated at 190 °C over a long-term cell test (1,000 cycles), and it attributed to the slower particle growth of the cathode materials at the lower operating temperature. Results reported here demonstrate that planar sodium-nickel chloride batteries operated at an intermediate temperature could greatly benefit this traditional energy storage technology by improving battery energy density, cycle life and reducing material costs.

High temperature dynamic engine seal technology development

NASA Technical Reports Server (NTRS)

Steinetz, Bruce M.; Dellacorte, Christopher; Machinchick, Michael; Mutharasan, Rajakkannu; Du, Guang-Wu; Ko, Frank; Sirocky, Paul J.; Miller, Jeffrey H.

1992-01-01

Combined cycle ramjet/scramjet engines being designed for advanced hypersonic vehicles, including the National Aerospace Plane (NASP), require innovative high temperature dynamic seals to seal the sliding interfaces of the articulated engine panels. New seals are required that will operate hot (1200 to 2000 F), seal pressures ranging from 0 to 100 psi, remain flexible to accommodate significant sidewall distortions, and resist abrasion over the engine's operational life. This report reviews the recent high temperature durability screening assessments of a new braided rope seal concept, braided of emerging high temperature materials, that shows promise of meeting many of the seal demands of hypersonic engines. The paper presents durability data for: (1) the fundamental seal building blocks, a range of candidate ceramic fiber tows; and for (2) braided rope seal subelements scrubbed under engine simulated sliding, temperature, and preload conditions. Seal material/architecture attributes and limitations are identified through the investigations performed. The paper summarizes the current seal technology development status and presents areas in which future work will be performed.

Low Cost High Performance Nanostructured Spectrally Selective Coating

DOE Office of Scientific and Technical Information (OSTI.GOV)

Jin, Sungho

2017-04-05

Sunlight absorbing coating is a key enabling technology to achieve high-temperature high-efficiency concentrating solar power operation. A high-performance solar absorbing material must simultaneously meet all the following three stringent requirements: high thermal efficiency (usually measured by figure of merit), high-temperature durability, and oxidation resistance. The objective of this research is to employ a highly scalable process to fabricate and coat black oxide nanoparticles onto solar absorber surface to achieve ultra-high thermal efficiency. Black oxide nanoparticles have been synthesized using a facile process and coated onto absorber metal surface. The material composition, size distribution and morphology of the nanoparticle are guidedmore » by numeric modeling. Optical and thermal properties have been both modeled and measured. High temperature durability has been achieved by using nanocomposites and high temperature annealing. Mechanical durability on thermal cycling have also been investigated and optimized. This technology is promising for commercial applications in next-generation high-temperature concentration solar power (CSP) plants.« less

Thermal Testing and Analysis of an Efficient High-Temperature Multi-Screen Internal Insulation

NASA Technical Reports Server (NTRS)

Weiland, Stefan; Handrick, Karin; Daryabeigi, Kamran

2007-01-01

Conventional multi-layer insulations exhibit excellent insulation performance but they are limited to the temperature range to which their components reflective foils and spacer materials are compatible. For high temperature applications, the internal multi-screen insulation IMI has been developed that utilizes unique ceramic material technology to produce reflective screens with high temperature stability. For analytical insulation sizing a parametric material model is developed that includes the main contributors for heat flow which are radiation and conduction. The adaptation of model-parameters based on effective steady-state thermal conductivity measurements performed at NASA Langley Research Center (LaRC) allows for extrapolation to arbitrary stack configurations and temperature ranges beyond the ones that were covered in the conductivity measurements. Experimental validation of the parametric material model was performed during the thermal qualification test of the X-38 Chin-panel, where test results and predictions showed a good agreement.

Stirling material technology

NASA Technical Reports Server (NTRS)

Titran, R. H.; Stephens, J. R.; Scheuermann, C. M.

1984-01-01

The Stirling engine is an external combustion engine that offers the advantage of high fuel economy, low emissions, low noise, and low vibrations compared to current internal combustion automotive engines. The most critical component from a materials viewpoint is the heater head consisting of the cylinders, heating tubes, and regenerator housing. Materials requirements for the heater head include compatibility with hydrogen, resistance to hydrogen permeation, high temperature oxidation/corrosion resistance, and high temperature creep-rupture and fatigue properties. A materials research and technology program identified the wrought alloys CG-27 and 12RN72 and the cast alloys XF-818, NASAUT 4G-A1, and NASACC-1 as candidate replacements for the cobalt containing alloys used in current prototype engines. It is concluded that manufacture of the engine is feasible from low cost iron-base alloys rather than the cobalt alloys used in prototype engines. Results of research that lead to this conclusion are presented.

Development of an ultra-high temperature infrared scene projector at Santa Barbara Infrared Inc.

NASA Astrophysics Data System (ADS)

Franks, Greg; Laveigne, Joe; Danielson, Tom; McHugh, Steve; Lannon, John; Goodwin, Scott

2015-05-01

The rapid development of very-large format infrared detector arrays has challenged the IR scene projector community to develop correspondingly larger-format infrared emitter arrays to support the testing needs of systems incorporating these detectors. As with most integrated circuits, fabrication yields for the read-in integrated circuit (RIIC) that drives the emitter pixel array are expected to drop dramatically with increasing size, making monolithic RIICs larger than the current 1024x1024 format impractical and unaffordable. Additionally, many scene projector users require much higher simulated temperatures than current technology can generate to fully evaluate the performance of their systems and associated processing algorithms. Under the Ultra High Temperature (UHT) development program, Santa Barbara Infrared Inc. (SBIR) is developing a new infrared scene projector architecture capable of producing both very large format (>1024x1024) resistive emitter arrays and improved emitter pixel technology capable of simulating very high apparent temperatures. During an earlier phase of the program, SBIR demonstrated materials with MWIR apparent temperatures in excess of 1000K. New emitter materials have subsequently been selected to produce pixels that achieve even higher apparent temperatures. Test results from pixels fabricated using the new material set will be presented and discussed. Also in development under the same UHT program is a 'scalable' RIIC that will be used to drive the high temperature pixels. This RIIC will utilize through-silicon vias (TSVs) and quilt packaging (QP) technologies to allow seamless tiling of multiple chips to fabricate very large arrays, and thus overcome the inherent yield limitations of very-large-scale integrated circuits. Current status of the RIIC development effort will also be presented.

NASA R and T aerospace plane vehicles: Progress and plans

NASA Technical Reports Server (NTRS)

Dixon, S. C.

1985-01-01

Progress made in key technologies such as materials, structures, aerothermodynamics, hypersonic aerodynamics, and hypersonic airbreathing propulsion are reported. Advances were made in more generic, areas such as active controls, flight computer hardware and software, and interdisciplinary analytical design methodology. These technology advances coupled with the development of and experiences with the Space Shuttle make feasible aerospace plane-type vehicles that meet the more demanding requirements of various DOD missions and/or an all-weather Shuttle II with reduced launch costs. Technology needs and high payoff technologies, and the technology advancements in propulsion, control-configured-vehicles, aerodynamics, aerothermodynamics, aerothermal loads, and materials and structures were studied. The highest payoff technologies of materials and structures including thermal-structural analysis and high temperature test techniques are emphasized. The high priority technology of propulsion, and plans, of what remains to be done rather than firm program commitments, are briefly discussed.

Ab initio thermodynamic approach to identify mixed solid sorbents for CO 2 capture technology

DOE PAGES

Duan, Yuhua

2015-10-15

Because the current technologies for capturing CO 2 are still too energy intensive, new materials must be developed that can capture CO 2 reversibly with acceptable energy costs. At a given CO 2 pressure, the turnover temperature (T t) of the reaction of an individual solid that can capture CO 2 is fixed. Such T t may be outside the operating temperature range (ΔT o) for a practical capture technology. To adjust T t to fit the practical ΔT o, in this study, three scenarios of mixing schemes are explored by combining thermodynamic database mining with first principles density functionalmore » theory and phonon lattice dynamics calculations. Our calculated results demonstrate that by mixing different types of solids, it’s possible to shift T t to the range of practical operating temperature conditions. According to the requirements imposed by the pre- and post- combustion technologies and based on our calculated thermodynamic properties for the CO 2 capture reactions by the mixed solids of interest, we were able to identify the mixing ratios of two or more solids to form new sorbent materials for which lower capture energy costs are expected at the desired pressure and temperature conditions.« less

Titan probe technology assessment and technology development plan study

NASA Technical Reports Server (NTRS)

Castro, A. J.

1980-01-01

The need for technology advances to accomplish the Titan probe mission was determined by defining mission conditions and requirements and evaluating the technology impact on the baseline probe configuration. Mission characteristics found to be technology drivers include (1) ten years dormant life in space vacuum; (2) unknown surface conditions, various sample materials, and a surface temperature; and (3) mission constraints of the Saturn Orbiter Dual Probe mission regarding weight allocation. The following areas were identified for further development: surface sample acquisition system; battery powered system; nonmetallic materials; magnetic bubble memory devices, and the landing system. Preentry science, reliability, and weight reduction and redundancy must also be considered.

Testing of Candidate Rigid Heatshield Materials at LHMEL for the Entry, Descent, and Landing Technology Development Project

NASA Technical Reports Server (NTRS)

Sepka, Steven; Gasch, Matthew; Beck, Robin A.; White, Susan

2012-01-01

The material testing results described in this paper were part of a material development program of vendor-supplied, proposed heat shield materials. The goal of this program was to develop low density, rigid material systems with an appreciable weight savings over phenolic-impregnated carbon ablator (PICA) while improving material response performance. New technologies, such as PICA-like materials in honeycomb or materials with variable density through-the-thickness were tested. The material testing took place at the Wright-Patterson Air Force Base Laser Hardened Materials Laboratory (LHMEL) using a 10.6 micron CO2 laser operating with the test articles immersed in a nitrogen-gas environment at 1 atmosphere pressure. Test measurements included thermocouple readings of in-depth temperatures, pyrometer readings of surface temperatures, weight scale readings of mass loss, and sectioned-sample readings of char depth. Two laser exposures were applied. The first exposure was at an irradiance of 450 W/cm2 for 50 or 60 seconds to simulate an aerocapture maneuver. The second laser exposure was at an irradiance of 115 W/cm2 for 100 seconds to simulate a planetary entry. Results from Rounds 1 and 2 of these screening tests are summarized.

Non-Destructive Inspection Approach Using Ultrasound to Identify the Material State for Amorphous and Semi-Crystalline Materials

DOE Office of Scientific and Technical Information (OSTI.GOV)

Jost, Elliott; Jack, David; Moore, David G.

At present, there are many methods to identify the temperature and phase of a material using invasive techniques. However, most current methods require physical contact or implicit methods utilizing light reflectance of the specimen. In this paper, we present a nondestructive inspection method using ultrasonic wave technology that circumvents these disadvantages to identify phase change regions and infer the temperature state of a material. In the present study an experiment is performed to monitor the time of flight within a wax as it undergoes melting and the subsequent cooling. Results presented in this work show a clear relationship between amore » material’s speed of sound and its temperature. The phase change transition of the material is clear from the time of flight results, and in the case of the investigated material, this change in the material state occurs over a range of temperatures. The range of temperatures over which the wax material melts is readily identified by speed of sound represented as a function of material temperature. The melt temperature, obtained acoustically, is validated using Differential Scanning Calorimetry (DSC), which uses shifts in heat flow rates to identify phase transition temperature ranges. Lastly, the investigated ultrasonic NDE method has direct applications in many industries, including oil and gas, food and beverage, and polymer composites, in addition to many implications for future capabilities of nondestructive inspection of multi-phase materials.« less

Non-Destructive Inspection Approach Using Ultrasound to Identify the Material State for Amorphous and Semi-Crystalline Materials

DOE PAGES

Jost, Elliott; Jack, David; Moore, David G.

2018-04-01

At present, there are many methods to identify the temperature and phase of a material using invasive techniques. However, most current methods require physical contact or implicit methods utilizing light reflectance of the specimen. In this paper, we present a nondestructive inspection method using ultrasonic wave technology that circumvents these disadvantages to identify phase change regions and infer the temperature state of a material. In the present study an experiment is performed to monitor the time of flight within a wax as it undergoes melting and the subsequent cooling. Results presented in this work show a clear relationship between amore » material’s speed of sound and its temperature. The phase change transition of the material is clear from the time of flight results, and in the case of the investigated material, this change in the material state occurs over a range of temperatures. The range of temperatures over which the wax material melts is readily identified by speed of sound represented as a function of material temperature. The melt temperature, obtained acoustically, is validated using Differential Scanning Calorimetry (DSC), which uses shifts in heat flow rates to identify phase transition temperature ranges. Lastly, the investigated ultrasonic NDE method has direct applications in many industries, including oil and gas, food and beverage, and polymer composites, in addition to many implications for future capabilities of nondestructive inspection of multi-phase materials.« less

Application of dynamic milling in stainless steel processing

NASA Astrophysics Data System (ADS)

Shan, Wenju

2017-09-01

This paper mainly introduces the method of parameter setting for NC programming of stainless steel parts by dynamic milling. Stainless steel is of high plasticity and toughness, serious hard working, large cutting force, high temperature in cutting area and easy wear of tool. It is difficult to process material. Dynamic motion technology is the newest NC programming technology of Mastercam software. It is an advanced machining idea. The tool path generated by the dynamic motion technology is more smooth, more efficient and more stable in the machining process. Dynamic motion technology is very suitable for cutting hard machining materials.

Advanced ceramic matrix composites for TPS

NASA Technical Reports Server (NTRS)

Rasky, Daniel J.

1992-01-01

Recent advances in ceramic matrix composite (CMC) technology provide considerable opportunity for application to future aircraft thermal protection system (TPS), providing materials with higher temperature capability, lower weight, and higher strength and stiffness than traditional materials. The Thermal Protection Material Branch at NASA Ames Research Center has been making significant progress in the development, characterization, and entry simulation (arc-jet) testing of new CMC's. This protection gives a general overview of the Ames Thermal Protection Materials Branch research activities, followed by more detailed descriptions of recent advances in very-high temperature Zr and Hf based ceramics, high temperature, high strength SiC matrix composites, and some activities in polymer precursors and ceramic coating processing. The presentation closes with a brief comparison of maximum heat flux capabilities of advanced TPS materials.

Integrated photonics for fiber optic based temperature sensing

NASA Astrophysics Data System (ADS)

Evenblij, R. S.; van Leest, T.; Haverdings, M. B.

2017-09-01

One of the promising space applications areas for fibre sensing is high reliable thermal mapping of metrology structures for effects as thermal deformation, focal plane distortion, etc. Subsequently, multi-point temperature sensing capability for payload panels and instrumentation instead of, or in addition to conventional thermo-couple technology will drastically reduce electrical wiring and sensor materials to minimize weight and costs. Current fiber sensing technologies based on solid state ASPIC (Application Specific Photonic Integrated Circuits) technology, allow significant miniaturization of instrumentation and improved reliability. These imperative aspects make the technology candidate for applications in harsh environments such as space. One of the major aspects in order to mature ASPIC technology for space is assessment on radiation hardness. This paper describes the results of radiation hardness experiments on ASPIC including typical multipoint temperature sensing and thermal mapping capabilities.

Emerging applications of high temperature superconductors for space communications

NASA Technical Reports Server (NTRS)

Heinen, Vernon O.; Bhasin, Kul B.; Long, Kenwyn J.

1990-01-01

Proposed space missions require longevity of communications system components, high input power levels, and high speed digital logic devices. The complexity of these missions calls for a high data bandwidth capacity. Incorporation of high temperature superconducting (HTS) thin films into some of these communications system components may provide a means of meeting these requirements. Space applications of superconducting technology has previously been limited by the requirement of cooling to near liquid helium temperatures. Development of HTS materials with transition temperatures above 77 K along with the natural cooling ability of space suggest that space applications may lead the way in the applications of high temperature superconductivity. In order for HTS materials to be incorporated into microwave and millimeter wave devices, the material properties such as electrical conductivity, current density, surface resistivity and others as a function of temperature and frequency must be well characterized and understood. The millimeter wave conductivity and surface resistivity were well characterized, and at 77 K are better than copper. Basic microwave circuits such as ring resonators were used to determine transmission line losses. Higher Q values than those of gold resonator circuits were observed below the transition temperature. Several key HTS circuits including filters, oscillators, phase shifters and phased array antenna feeds are feasible in the near future. For technology to improve further, good quality, large area films must be reproducibly grown on low dielectric constant, low loss microwave substrates.

A levitation instrument for containerless study of molten materials.

PubMed

Nordine, Paul C; Merkley, Dennis; Sickel, Jeffrey; Finkelman, Steve; Telle, Rainer; Kaiser, Arno; Prieler, Robert

2012-12-01

A new aero-acoustic levitation instrument (AAL) has been installed at the Institute for Mineral Engineering at RWTH University in Aachen, Germany. The AAL employs acoustically stabilized gas jet levitation with laser-beam heating and melting to create a contact-free containerless environment for high temperature materials research. Contamination-free study of liquids is possible at temperatures in excess of 3000 °C and of undercooled liquids at temperatures far below the melting point. Digital control technology advances the art of containerless experiments to obtain long-term levitation stability, allowing new experiments in extreme temperature materials research and to study operation of the levitation instrument itself. Experiments with liquid Al(2)O(3) at temperatures more than 3200 °C, 1200 °C above the melting point, and with liquid Y(3)Al(5)O(12) far below the melting point are reported. Fast pyrometry and video recording instruments yield crystallization rates in undercooled liquid Al(2)O(3) as a function of temperature. Levitation of dense liquid HfO(2) at temperatures above 2900 °C is demonstrated. Capabilities are described for resonant frequency matching in the three-axis acoustic positioning system, acoustic control of sample spin, and position control of standing wave nodes to stabilize levitation under changing experimental conditions. Further development and application of the levitation technology is discussed based on the results of experiments and modeling of instrument operations.

A levitation instrument for containerless study of molten materials

NASA Astrophysics Data System (ADS)

Nordine, Paul C.; Merkley, Dennis; Sickel, Jeffrey; Finkelman, Steve; Telle, Rainer; Kaiser, Arno; Prieler, Robert

2012-12-01

A new aero-acoustic levitation instrument (AAL) has been installed at the Institute for Mineral Engineering at RWTH University in Aachen, Germany. The AAL employs acoustically stabilized gas jet levitation with laser-beam heating and melting to create a contact-free containerless environment for high temperature materials research. Contamination-free study of liquids is possible at temperatures in excess of 3000 °C and of undercooled liquids at temperatures far below the melting point. Digital control technology advances the art of containerless experiments to obtain long-term levitation stability, allowing new experiments in extreme temperature materials research and to study operation of the levitation instrument itself. Experiments with liquid Al2O3 at temperatures more than 3200 °C, 1200 °C above the melting point, and with liquid Y3Al5O12 far below the melting point are reported. Fast pyrometry and video recording instruments yield crystallization rates in undercooled liquid Al2O3 as a function of temperature. Levitation of dense liquid HfO2 at temperatures above 2900 °C is demonstrated. Capabilities are described for resonant frequency matching in the three-axis acoustic positioning system, acoustic control of sample spin, and position control of standing wave nodes to stabilize levitation under changing experimental conditions. Further development and application of the levitation technology is discussed based on the results of experiments and modeling of instrument operations.

ASRDI Oxygen Technological Survey. Volume 9; Oxygen Systems Engineering Review

NASA Technical Reports Server (NTRS)

Schmidt, H. W.; Forney, D. E.

1975-01-01

The design and safe operation of O2 systems at high pressures and temperatures are discussed. Data cover O2 reactivity with system materials, environmental limits, flow rate, contamination, and physical and chemical stresses of materials.

Nanotechnology Based Green Energy Conversion Devices with Multifunctional Materials at Low Temperatures.

PubMed

Lu, Yuzheng; Afzal, Muhammad; Zhu, Bin; Wang, Baoyuan; Wang, Jun; Xia, Chen

2017-07-10

Nanocomposites (integrating the nano and composite technologies) for advanced fuel cells (NANOCOFC) demonstrate the great potential to reduce the operational temperature of solid oxide fuel cell (SOFC) significantly in the low temperature (LT) range 300-600ºC. NANOCOFC has offered the development of multi-functional materials composed of semiconductor and ionic materials to meet the requirements of low temperature solid oxide fuel cell (LTSOFC) and green energy conversion devices with their unique mechanisms. This work reviews the recent developments relevant to the devices and the patents in LTSOFCs from nanotechnology perspectives that reports advances including fabrication methods, material compositions, characterization techniques and cell performances. Finally, the future scope of LTSOFC with nanotechnology and the practical applications are also discussed. Copyright© Bentham Science Publishers; For any queries, please email at epub@benthamscience.org.

Electrode materials: a challenge for the exploitation of protonic solid oxide fuel cells

PubMed Central

Fabbri, Emiliana; Pergolesi, Daniele; Traversa, Enrico

2010-01-01

High temperature proton conductor (HTPC) oxides are attracting extensive attention as electrolyte materials alternative to oxygen-ion conductors for use in solid oxide fuel cells (SOFCs) operating at intermediate temperatures (400–700 °C). The need to lower the operating temperature is dictated by cost reduction for SOFC pervasive use. The major stake for the deployment of this technology is the availability of electrodes able to limit polarization losses at the reduced operation temperature. This review aims to comprehensively describe the state-of-the-art anode and cathode materials that have so far been tested with HTPC oxide electrolytes, offering guidelines and possible strategies to speed up the development of protonic SOFCs. PMID:27877342

Multiyear Program Plan for the High Temperature Materials Laboratory

DOE Office of Scientific and Technical Information (OSTI.GOV)

Arvid E. Pasto

2000-03-17

Recently, the U.S. Department of Energy's (DOE) Office of Heavy Vehicle Technologies (OHVT) prepared a Technology Roadmap describing the challenges facing development of higher fuel efficiency, less polluting sport utility vehicles, vans, and commercial trucks. Based on this roadmap, a multiyear program plan (MYPP) was also developed, in which approaches to solving the numerous challenges are enumerated. Additional planning has been performed by DOE and national laboratory staff, on approaches to solving the numerous challenges faced by heavy vehicle system improvements. Workshops and planning documents have been developed concerning advanced aerodynamics, frictional and other parasitic losses, and thermal management. Similarly,more » the Heavy Vehicle Propulsion Materials Program has developed its own multiyear program plan. The High Temperature Materials Laboratory, a major user facility sponsored by OHVT, has now developed its program plan, described herein. Information was gathered via participation in the development of OHVT's overall Technology Roadmap and MYPP, through personal contacts within the materials-user community, and from attendance at conferences and expositions. Major materials issues for the heavy vehicle industry currently center on trying to increase efficiency of (diesel) engines while at the same time reducing emissions (particularly NO{sub x} and particulates). These requirements dictate the use of increasingly stronger, higher-temperature capable and more corrosion-resistant materials of construction, as well as advanced catalysts, particulate traps, and other pollution-control devices. Exhaust gas recirculation (EGR) is a technique which will certainly be applied to diesel engines in the near future, and its use represents a formidable challenge, as will be described later. Energy-efficient, low cost materials processing methods and surface treatments to improve wear, fracture, and corrosion resistance are also required.« less

Temperature characteristics for PTC material heating diesel fuel

NASA Astrophysics Data System (ADS)

Gu, Lefeng; Li, Xiaolu; Wang, Jun; Li, Ying; Li, Ming

2010-08-01

This paper gives a way which utilizes the PTC (Positive Temperature Coefficient) material to preheat diesel fuel in the injector in order to improve the cold starting and emissions of engine. A new injector is also designed. In order to understand the preheating process in this new injector, a dynamic temperature testing system combined with the MSP430F149 data acquisition system is developed for PTC material heating diesel fuel. Especially, the corresponding software and hardware circuits are explained. The temperature of diesel fuel preheating by PTC ceramics is measured under different voltages and distances, which Curie point is 75 °C. Diesel fuel is heated by self-defined temperature around the Curie point of PTC ceramics. The diesel fuel temperature rises rapidly in 2 minutes of the beginning, then can reach 60 °C within 5 minutes as its distance is 5mm away from the surface of PTC ceramics. However, there are a lot of fundamental studies and technology to be resolved in order to apply PTC material in the injector successfully.

NASA Glenn Research Center UEET (Ultra-Efficient Engine Technology) Program: Agenda and Abstracts

NASA Technical Reports Server (NTRS)

Manthey, Lri

2001-01-01

Topics discussed include: UEET Overview; Technology Benefits; Emissions Overview; P&W Low Emissions Combustor Development; GE Low Emissions Combustor Development; Rolls-Royce Low Emissions Combustor Development; Honeywell Low Emissions Combustor Development; NASA Multipoint LDI Development; Stanford Activities In Concepts for Advanced Gas Turbine Combustors; Large Eddy Simulation (LES) of Gas Turbine Combustion; NASA National Combustion Code Simulations; Materials Overview; Thermal Barrier Coatings for Airfoil Applications; Disk Alloy Development; Turbine Blade Alloy; Ceramic Matrix Composite (CMC) Materials Development; Ceramic Matrix Composite (CMC) Materials Characterization; Environmental Barrier Coatings (EBC) for Ceramic Matrix Composite (CMC) Materials; Ceramic Matrix Composite Vane Rig Testing and Design; Ultra-High Temperature Ceramic (UHTC) Development; Lightweight Structures; NPARC Alliance; Technology Transfer and Commercialization; and Turbomachinery Overview; etc.

Measuring Thermal Conductivity at LH2 Temperatures

NASA Technical Reports Server (NTRS)

Selvidge, Shawn; Watwood, Michael C.

2004-01-01

For many years, the National Institute of Standards and Technology (NIST) produced reference materials for materials testing. One such reference material was intended for use with a guarded hot plate apparatus designed to meet the requirements of ASTM C177-97, "Standard Test Method for Steady-State Heat Flux Measurements and Thermal Transmission Properties by Means of the Guarded-Hot-Plate Apparatus." This apparatus can be used to test materials in various gaseous environments from atmospheric pressure to a vacuum. It allows the thermal transmission properties of insulating materials to be measured from just above ambient temperature down to temperatures below liquid hydrogen. However, NIST did not generate data below 77 K temperature for the reference material in question. This paper describes a test method used at NASA's Marshall Space Flight Center (MSFC) to optimize thermal conductivity measurements during the development of thermal protection systems. The test method extends the usability range of this reference material by generating data at temperatures lower than 77 K. Information provided by this test is discussed, as are the capabilities of the MSFC Hydrogen Test Facility, where advanced methods for materials testing are routinely developed and optimized in support of aerospace applications.

Magnetic Materials Suitable for Fission Power Conversion in Space Missions

NASA Technical Reports Server (NTRS)

Bowman, Cheryl L.

2012-01-01

Terrestrial fission reactors use combinations of shielding and distance to protect power conversion components from elevated temperature and radiation. Space mission systems are necessarily compact and must minimize shielding and distance to enhance system level efficiencies. Technology development efforts to support fission power generation scenarios for future space missions include studying the radiation tolerance of component materials. The fundamental principles of material magnetism are reviewed and used to interpret existing material radiation effects data for expected fission power conversion components for target space missions. Suitable materials for the Fission Power System (FPS) Project are available and guidelines are presented for bounding the elevated temperature/radiation tolerance envelope for candidate magnetic materials.

Polyimide Boosts High-Temperature Performance

NASA Technical Reports Server (NTRS)

2008-01-01

Maverick Corporation, of Blue Ash, Ohio, licensed DMBZ-15 polyimide technology from Glenn Research Center. This ultrahigh-temperature material provides substantial weight savings and reduced machining costs compared to the same component made with more traditional metallic materials. DMBZ-15 has a wide range of applications from aerospace (aircraft engine and airframe components, space transportation systems, and missiles) to non-aerospace (oil drilling, rolling mill), and is particularly well-suited to use as face sheets with honey cones or thermal protection systems for reusable launch vehicles, which encounter elevated temperatures during launch and re-entry.

Minimizing material damage using low temperature irradiation

NASA Astrophysics Data System (ADS)

Craven, E.; Hasanain, F.; Winters, M.

2012-08-01

Scientific advancements in healthcare driven both by technological breakthroughs and an aging and increasingly obese population have lead to a changing medical device market. Complex products and devices are being developed to meet the demands of leading edge medical procedures. Specialized materials in these medical devices, including pharmaceuticals and biologics as well as exotic polymers present a challenge for radiation sterilization as many of these components cannot withstand conventional irradiation methods. The irradiation of materials at dry ice temperatures has emerged as a technique that can be used to decrease the radiation sensitivity of materials. The purpose of this study is to examine the effect of low temperature irradiation on a variety of polymer materials, and over a range of temperatures from 0 °C down to -80 °C. The effectiveness of microbial kill is also investigated under each of these conditions. The results of the study show that the effect of low temperature irradiation is material dependent and can alter the balance between crosslinking and chain scission of the polymer. Low temperatures also increase the dose required to achieve an equivalent microbiological kill, therefore dose setting exercises must be performed under the environmental conditions of use.

DU Processing Efficiency and Reclamation: Plasma Arc Melting

DOE Office of Scientific and Technical Information (OSTI.GOV)

Imhoff, Seth D.; Aikin, Jr., Robert M.; Swenson, Hunter

The work described here corresponds to one piece of a larger effort to increase material usage efficiency during DU processing operations. In order to achieve this goal, multiple technologies and approaches are being tested. These technologies occupy a spectrum of technology readiness levels (TRLs). Plasma arc melting (PAM) is one of the technologies being investigated. PAM utilizes a high temperature plasma to melt materials. Depending on process conditions, there are potential opportunities for recycling and material reclamation. When last routinely operational, the LANL research PAM showed extremely promising results for recycling and reclamation of DU and DU alloys. The currentmore » TRL is lower due to machine idleness for nearly two decades, which has proved difficult to restart. This report describes the existing results, promising techniques, and the process of bringing this technology back to readiness at LANL.« less

Ceramics Technology Project database: September 1991 summary report. [Materials for piston ring-cylinder liner for advanced heat/diesel engines

DOE Office of Scientific and Technical Information (OSTI.GOV)

Keyes, B.L.P.

1992-06-01

The piston ring-cylinder liner area of the internal combustion engine must withstand very-high-temperature gradients, highly-corrosive environments, and constant friction. Improving the efficiency in the engine requires ring and cylinder liner materials that can survive this abusive environment and lubricants that resist decomposition at elevated temperatures. Wear and friction tests have been done on many material combinations in environments similar to actual use to find the right materials for the situation. This report covers tribology information produced from 1986 through July 1991 by Battelle columbus Laboratories, Caterpillar Inc., and Cummins Engine Company, Inc. for the Ceramic Technology Project (CTP). All datamore » in this report were taken from the project's semiannual and bimonthly progress reports and cover base materials, coatings, and lubricants. The data, including test rig descriptions and material characterizations, are stored in the CTP database and are available to all project participants on request. Objective of this report is to make available the test results from these studies, but not to draw conclusions from these data.« less

Radiation and temperature effects on electronic components investigated under the CSTI high capacity power project

NASA Technical Reports Server (NTRS)

Schwarze, Gene E.; Niedra, Janis M.; Frasca, Albert J.; Wieserman, William R.

1993-01-01

The effects of nuclear radiation and high temperature environments must be fully known and understood for the electronic components and materials used in both the Power Conditioning and Control subsystem and the reactor Instrumentation and Control subsystem of future high capacity nuclear space power systems. This knowledge is required by the designer of these subsystems in order to develop highly reliable, long-life power systems for future NASA missions. A review and summary of the experimental results obtained for the electronic components and materials investigated under the power management element of the Civilian Space Technology Initiative (CSTI) high capacity power project are presented: (1) neutron, gamma ray, and temperature effects on power semiconductor switches, (2) temperature and frequency effects on soft magnetic materials; and (3) temperature effects on rare earth permanent magnets.

Combustor technology for future small gas turbine aircraft

NASA Technical Reports Server (NTRS)

Lyons, Valerie J.; Niedzwiecki, Richard W.

1993-01-01

Future engine cycles proposed for advanced small gas turbine engines will increase the severity of the operating conditions of the combustor. These cycles call for increased overall engine pressure ratios which increase combustor inlet pressure and temperature. Further, the temperature rise through the combustor and the corresponding exit temperature also increase. Future combustor technology needs for small gas turbine engines is described. New fuel injectors with large turndown ratios which produce uniform circumferential and radial temperature patterns will be required. Uniform burning will be of greater importance because hot gas temperatures will approach turbine material limits. The higher combustion temperatures and increased radiation at high pressures will put a greater heat load on the combustor liners. At the same time, less cooling air will be available as more of the air will be used for combustion. Thus, improved cooling concepts and/or materials requiring little or no direct cooling will be required. Although presently there are no requirements for emissions levels from small gas turbine engines, regulation is expected in the near future. This will require the development of low emission combustors. In particular, nitrogen oxides will increase substantially if new technologies limiting their formation are not evolved and implemented. For example, staged combustion employing lean, premixed/prevaporized, lean direct injection, or rich burn-quick quench-lean burn concepts could replace conventional single stage combustors.

Novel Thermal Storage Technologies for Concentrating Solar Power Generation

DOE Office of Scientific and Technical Information (OSTI.GOV)

Neti, Sudhakar; Oztekin, Alparslan; Chen, John

2013-06-20

The technologies that are to be developed in this work will enable storage of thermal energy in 100 MW e solar energy plants for 6-24 hours at temperatures around 300°C and 850°C using encapsulated phase change materials (EPCM). Several encapsulated phase change materials have been identified, fabricated and proven with calorimetry. Two of these materials have been tested in an airflow experiment. A cost analysis for these thermal energy storage systems has also been conducted that met the targets established at the initiation of the project.

Development of material formula and structure property indicators for low cold-resistant characterization of Cables’ Material

NASA Astrophysics Data System (ADS)

Sun, W.; Cai, Y. G.; Feng, Y. M.; Li, Y. L.; Zhou, H. Y.; Zhou, Y.

2018-01-01

Alpine regions account for about 27.9% of total land area in China. Northeast China, Inner Mongolia, Northwest China and other regions are located in alpine regions, wherein the above regions are rich in energy. However, the low-temperature impact embrittlement temperature of traditional PVC cable materials is between -15°C and -20°C, which is far lower than actual operation requirements. Cable insulation and sheath are always damaged during cable laying in alpine regions. Therefore, it is urgent to develop low-temperature-resistant cables applicable to low-temperature environment in alpine regions, and safe and stable operation of power grids in the alpine regions can be guaranteed. In the paper, cold-resistant PVC formula systems were mainly trial-manufactured and studied. Appropriate production technologies and formulas were determined through selecting raw materials and modified materials. The low-temperature impact embrittlement temperature was adjusted below -50°C under the precondition that PVC cable materials met national standard property requirements. Cold-resistant PVC cable materials were prepared, which were characterized by excellent physical and mechanical properties, and sound extrusion process, and cold-resistant PVC cable materials can meet production requirements of low-temperature-resistant cables. Meanwhile, the prepared cold-resistant cable material was used for extruding finished product cables and trial-manufacturing sample cables. Type tests of low temperature elongation ratio, 15min withstand voltage, etc. were completed for 35kV and lower sample cables in Mohe Low-temperature Test Site. All properties were consistent with standard requirements.

Development of near-zero water consumption cement materials via the geopolymerization of tektites and its implication for lunar construction

PubMed Central

Wang, Kai-tuo; Tang, Qing; Cui, Xue-min; He, Yan; Liu, Le-ping

2016-01-01

The environment on the lunar surface poses some difficult challenges to building long-term lunar bases; therefore, scientists and engineers have proposed the creation of habitats using lunar building materials. These materials must meet the following conditions: be resistant to severe lunar temperature cycles, be stable in a vacuum environment, have minimal water requirements, and be sourced from local Moon materials. Therefore, the preparation of lunar building materials that use lunar resources is preferred. Here, we present a potential lunar cement material that was fabricated using tektite powder and a sodium hydroxide activator and is based on geopolymer technology. Geopolymer materials have the following properties: approximately zero water consumption, resistance to high- and low-temperature cycling, vacuum stability and good mechanical properties. Although the tektite powder is not equivalent to lunar soil, we speculate that the alkali activated activity of lunar soil will be higher than that of tektite because of its low Si/Al composition ratio. This assumption is based on the tektite geopolymerization research and associated references. In summary, this study provides a feasible approach for developing lunar cement materials using a possible water recycling system based on geopolymer technology. PMID:27406467

Development of near-zero water consumption cement materials via the geopolymerization of tektites and its implication for lunar construction.

PubMed

Wang, Kai-Tuo; Tang, Qing; Cui, Xue-Min; He, Yan; Liu, Le-Ping

2016-07-13

The environment on the lunar surface poses some difficult challenges to building long-term lunar bases; therefore, scientists and engineers have proposed the creation of habitats using lunar building materials. These materials must meet the following conditions: be resistant to severe lunar temperature cycles, be stable in a vacuum environment, have minimal water requirements, and be sourced from local Moon materials. Therefore, the preparation of lunar building materials that use lunar resources is preferred. Here, we present a potential lunar cement material that was fabricated using tektite powder and a sodium hydroxide activator and is based on geopolymer technology. Geopolymer materials have the following properties: approximately zero water consumption, resistance to high- and low-temperature cycling, vacuum stability and good mechanical properties. Although the tektite powder is not equivalent to lunar soil, we speculate that the alkali activated activity of lunar soil will be higher than that of tektite because of its low Si/Al composition ratio. This assumption is based on the tektite geopolymerization research and associated references. In summary, this study provides a feasible approach for developing lunar cement materials using a possible water recycling system based on geopolymer technology.

High-temperature optical fiber sensors for characterization of advanced composite aerospace materials

NASA Astrophysics Data System (ADS)

Wavering, Thomas A.; Greene, Jonathan A.; Meller, Scott A.; Bailey, Timothy A.; Kozikowski, Carrie L.; Lenahan, Shannon M.; Murphy, Kent A.; Camden, Michael P.; Simmons, Larry W.

1999-01-01

Optical fiber sensors have numerous advantages over conventional sensing technologies. One such advantage is that optical fiber sensors can operate in high temperature environments. While most conventional electrical-based sensors do not operate reliably over 300 degrees C, fused silica based optical fiber sensors can survive up to 900 degrees C, and sapphire based optical fiber sensors can survive up to 2000 degrees C. Using both fused silica and sapphire technologies, we present result for high temperature strain, pressure, and temperature sensors using Extrinsic Fabry-Perot INterferometric-based and Bragg grating sensors. High temperature strain and temperature sensors were used to conduct fatigue testing of composite coupons at 600 degrees C. The results from these specific high temperature applications are presented along with future applications and directions for these sensors.

Application of thermogravimetry-differential thermal analysis (TG-DTA) technique to study the ancient potteries from Vellore dist, Tamilnadu, India

NASA Astrophysics Data System (ADS)

Ravisankar, R.; Naseerutheen, A.; Rajalakshmi, A.; Raja Annamalai, G.; Chandrasekaran, A.

2014-08-01

The characterization of archeological ceramic and pottery can be studied for the determination of firing temperature and the presence of raw materials by thermal analysis. Clay minerals are the main material for the production of ceramic and pottery and show some characteristic reactions such as dehydration, dehydroxylation and transformation. This is key point of criteria for the elucidation of firing temperature and raw material analysis. In the present work, DTA-TG, XRD and EDXRF technique are applied on representative potsherds from Vellore dist., Tamilnadu, India to derive the information about the production technology, raw materials and firing temperature. From the analysis, all the samples were considered to be fired from 800 °C to 900 °C and organic material might be added intestinally as a binder in the preparation of pottery.

Thermal Energy for Lunar In Situ Resource Utilization: Technical Challenges and Technology Opportunities

NASA Technical Reports Server (NTRS)

Gordon, Pierce E. C.; Colozza, Anthony J.; Hepp, Aloysius F.; Heller, Richard S.; Gustafson, Robert; Stern, Ted; Nakamura, Takashi

2011-01-01

Oxygen production from lunar raw materials is critical for sustaining a manned lunar base but is very power intensive. Solar concentrators are a well-developed technology for harnessing the Sun s energy to heat regolith to high temperatures (over 1375 K). The high temperature and potential material incompatibilities present numerous technical challenges. This study compares and contrasts different solar concentrator designs that have been developed, such as Cassegrains, offset parabolas, compound parabolic concentrators, and secondary concentrators. Differences between concentrators made from lenses and mirrors, and between rigid and flexible concentrators are also discussed. Possible substrate elements for a rigid mirror concentrator are selected and then compared, using the following (target) criteria: (low) coefficient of thermal expansion, (high) modulus of elasticity, and (low) density. Several potential lunar locations for solar concentrators are compared; environmental and processing-related challenges related to dust and optical surfaces are addressed. This brief technology survey examines various sources of thermal energy that can be utilized for materials processing on the lunar surface. These include heat from nuclear or electric sources and solar concentrators. Options for collecting and transporting thermal energy to processing reactors for each source are examined. Overall system requirements for each thermal source are compared and system limitations, such as maximum achievable temperature are discussed.

Novel protein crystal growth technology: Proof of concept

NASA Technical Reports Server (NTRS)

Nyce, Thomas A.; Rosenberger, Franz

1989-01-01

A technology for crystal growth, which overcomes certain shortcomings of other techniques, is developed and its applicability to proteins is examined. There were several unknowns to be determined: the design of the apparatus for suspension of crystals of varying (growing) diameter, control of the temperature and supersaturation, the methods for seeding and/or controlling nucleation, the effect on protein solutions of the temperature oscillations arising from the circulation, and the effect of the fluid shear on the suspended crystals. Extensive effort was put forth to grow lysozyme crystals. Under conditions favorable to the growth of tetragonal lysozyme, spontaneous nucleation could be produced but the number of nuclei could not be controlled. Seed transfer techniques were developed and implemented. When conditions for the orthorhombic form were tried, a single crystal 1.5 x 0.5 x 0.2 mm was grown (after in situ nucleation) and successfully extracted. A mathematical model was developed to predict the flow velocity as a function of the geometry and the operating temperatures. The model can also be used to scaleup the apparatus for growing larger crystals of other materials such as water soluble non-linear optical materials. This crystal suspension technology also shows promise for high quality solution growth of optical materials such as TGS and KDP.

Power system applications of high temperature superconductors

NASA Astrophysics Data System (ADS)

Garlick, W. G.

This paper presents an overview of potential applications for high temperature superconductors (HTSs) in the field of power engineering. For almost 10 years material scientists, chemists and physicists have had the freedom to find, explore and characterize the properties of new HTS materials. 10 years is not a long time in the development of a revolutionary technology, but it seems like an age to the engineer who has recognized its potential and waits impatiently for the technology to stabilize in order to apply it. Largely due to Government and Industry partnerships, only a few years after the discovery of HTS, electrical power applications based on HTS are now being designed and tested. These applications offer many benefits to the resident electrical system: increased energy efficiency, smaller equipment, reduced emissions, increased stability and reliability, deferred expansion and flexible transmission and distribution. They have a common focus: lower electricity costs, improved environmental quality and more competitive products for a global market. For HTS to become a commercial success, the development of materials technologies is necessary but not sufficient on its own; the development of a capability to design and manufacture products that use the materials is also fundamental to a viable and successful industrial base.

Time domain reflectometry measured moisture content of sewage sludge compost across temperatures.

PubMed

Cai, Lu; Chen, Tong-Bin; Gao, Ding; Liu, Hong-Tao; Chen, Jun; Zheng, Guo-Di

2013-01-01

Time domain reflectometry (TDR) is a prospective measurement technology for moisture content of sewage sludge composting material; however, a significant dependence upon temperature has been observed. The objective of this study was to assess the impacts of temperature upon moisture content measurement and determine if TDR could be used to monitor moisture content in sewage sludge compost across a range of temperatures. We also investigated the combined effects of temperature and conductivity on moisture content measurement. The results revealed that the moisture content of composting material could be determined by TDR using coated probes, even when the measured material had a moisture content of 0.581 cm(3)cm(-3), temperature of 70°C and conductivity of 4.32 mS cm(-1). TDR probes were calibrated as a function of dielectric properties that included temperature effects. When the bulk temperature varied from 20°C to 70°C, composting material with 0.10-0.70 cm(3)cm(-3) moisture content could be measured by TDR using coated probes, and calibrations based on different temperatures minimized the errors. Copyright © 2012. Published by Elsevier Ltd.

InGaN High-Temperature Photovoltaic Cells

NASA Technical Reports Server (NTRS)

Starikov, David

2015-01-01

This Phase II project developed Indium-Gallium-Nitride (InGaN) photovoltaic cells for high-temperature and high-radiation environments. The project included theoretical and experimental refinement of device structures produced in Phase I as well as modeling and optimization of solar cell device processing. The devices have been tested under concentrated air mass zero (AM0) sunlight, at temperatures from 100 degC to 250 degC, and after exposure to ionizing radiation. The results are expected to further verify that InGaN can be used for high-temperature and high-radiation solar cells. The large commercial solar cell market could benefit from the hybridization of InGaN materials to existing solar cell technology, which would significantly increase cell efficiency without relying on highly toxic compounds. In addition, further development of this technology to even lower bandgap materials for space applications would extend lifetimes of satellite solar cell arrays due to increased radiation hardness. This could be of importance to the Departmentof Defense (DoD) and commercial satellite manufacturers.

Processing of Ni30Pt20Ti50 High-Temperature Shape-Memory Alloy Into Thin Rod Demonstrated

NASA Technical Reports Server (NTRS)

Noebe, Ronald D.; Draper, Susan L.; Biles, Tiffany A.; Leonhardt, Todd

2005-01-01

High-temperature shape-memory alloys (HTSMAs) based on nickel-titanium (NiTi) with significant ternary additions of palladium (Pd), platinum (Pt), gold (Au), or hafnium (Hf) have been identified as potential high-temperature actuator materials for use up to 500 C. These materials provide an enabling technology for the development of "smart structures" used to control the noise, emissions, or efficiency of gas turbine engines. The demand for these high-temperature versions of conventional shape-memory alloys also has been growing in the automotive, process control, and energy industries. However these materials, including the NiPtTi alloys being developed at the NASA Glenn Research Center, will never find widespread acceptance unless they can be readily processed into useable forms.

Computational Modeling of Mixed Solids for CO2 CaptureSorbents

DOE Office of Scientific and Technical Information (OSTI.GOV)

Duan, Yuhua

2015-01-01

Since current technologies for capturing CO2 to fight global climate change are still too energy intensive, there is a critical need for development of new materials that can capture CO2 reversibly with acceptable energy costs. Accordingly, solid sorbents have been proposed to be used for CO2 capture applications through a reversible chemical transformation. By combining thermodynamic database mining with first principles density functional theory and phonon lattice dynamics calculations, a theoretical screening methodology to identify the most promising CO2 sorbent candidates from the vast array of possible solid materials has been proposed and validated. The calculated thermodynamic properties of differentmore » classes of solid materials versus temperature and pressure changes were further used to evaluate the equilibrium properties for the CO2 adsorption/desorption cycles. According to the requirements imposed by the pre- and post- combustion technologies and based on our calculated thermodynamic properties for the CO2 capture reactions by the solids of interest, we were able to screen only those solid materials for which lower capture energy costs are expected at the desired pressure and temperature conditions. Only those selected CO2 sorbent candidates were further considered for experimental validations. The ab initio thermodynamic technique has the advantage of identifying thermodynamic properties of CO2 capture reactions without any experimental input beyond crystallographic structural information of the solid phases involved. Such methodology not only can be used to search for good candidates from existing database of solid materials, but also can provide some guidelines for synthesis new materials. In this presentation, we apply our screening methodology to mixing solid systems to adjust the turnover temperature to help on developing CO2 capture Technologies.« less

Large Deployable Reflector Science and Technology Workshop. Volume 3: Systems and Technology Assessment

NASA Technical Reports Server (NTRS)

Leidich, C. A. (Editor); Pittman, R. B. (Editor)

1984-01-01

The results of five technology panels which convened to discuss the Large Deployable Reflector (LDR) are presented. The proposed LDR is a large, ambient-temperature, far infrared/submillimeter telescope designed for space. Panel topics included optics, materials and structures, sensing and control, science instruments, and systems and missions. The telescope requirements, the estimated technology levels, and the areas in which the generic technology work has to be augmented are enumerated.

Fabrication and Qualification of Coated Chip-on-Board Technology for Miniaturized Space Systems

NASA Technical Reports Server (NTRS)

Maurer, R. H.; Le, B. Q.; Nhan, E.; Lew, A. L.; Darrin, M. Ann Garrison

1997-01-01

The results of a study carried out in order to manufacture and verify the quality of chip-on-board (COB) packaging technology are presented. The COB, designed for space applications, was tested under environmental stresses, temperature cycling, and temperature-humidity-bias. Both robustness in space applications and in environmental protection on the ground-complete reliability without hermeticity were searched for. The epoxy-parylene combinations proved to be superior to other materials tested.

Improved Durability of SOEC Stacks for High Temperature Electrolysis

DOE Office of Scientific and Technical Information (OSTI.GOV)

James E. O'Brien; Robert C. O'Brien; Xiaoyu Zhang

2013-01-01

High temperature steam electrolysis is a promising technology for efficient and sustainable large-scale hydrogen production. Solid oxide electrolysis cells (SOECs) are able to utilize high temperature heat and electric power from advanced high-temperature nuclear reactors or renewable sources to generate carbon-free hydrogen at large scale. However, long term durability of SOECs needs to be improved significantly before commercialization of this technology can be realized. A degradation rate of 1%/khr or lower is proposed as a threshold value for commercialization of this technology. Solid oxide electrolysis stack tests have been conducted at Idaho National Laboratory to demonstrate recent improvements in long-termmore » durability of SOECs. Electrolyte-supported and electrode-supported SOEC stacks were provided by Ceramatec Inc. and Materials and Systems Research Inc. (MSRI), respectively, for these tests. Long-term durability tests were generally operated for a duration of 1000 hours or more. Stack tests based on technologies developed at Ceramatec and MSRI have shown significant improvement in durability in the electrolysis mode. Long-term degradation rates of 3.2%/khr and 4.6%/khr were observed for MSRI and Ceramatec stacks, espectively. One recent Ceramatec stack even showed negative degradation (performance improvement) over 1900 hours of operation. Optimization of electrode materials, interconnect coatings, and electrolyte-electrode interface microstructures contribute to better durability of SOEC stacks.« less

Numerical modeling of the effect of heat and mass transfer in porous low-temperature heat insulation in composite material structures on the magnitude of stresses which develop

NASA Astrophysics Data System (ADS)

Kuznetsov, G. V.; Rudzinskaya, N. V.

1997-05-01

The stressed state of multilayer low-temperature heat insulation for a cryogenic fuel tank is considered. Account is taken of heat and mass transfer in foam plastic (the main heat insulation material) occurring at cryogenic temperatures. A method is developed for solving a set of differential equations and boundary conditions. Numerical studies of the main features of these processes are performed. It is established that below 200 K the stresses which arise in foam plastic markedly exceed the ultimate strength for this material. Stresses develop as a result of both a reduction in temperature and a drop in pressure in the foam plastic pores connected with material cooling. On the basis of the results obtained it is established that the combination of thermophysical processes which occur in foam plastic during cooling to cryogenic temperatures leads to changes in the stress-strained state of structure, which should be considered in planning aerospace technology.

Advanced intermediate temperature sodium–nickel chloride batteries with ultra-high energy density

PubMed Central

Li, Guosheng; Lu, Xiaochuan; Kim, Jin Y.; Meinhardt, Kerry D.; Chang, Hee Jung; Canfield, Nathan L.; Sprenkle, Vincent L.

2016-01-01

Sodium-metal halide batteries have been considered as one of the more attractive technologies for stationary electrical energy storage, however, they are not used for broader applications despite their relatively well-known redox system. One of the roadblocks hindering market penetration is the high-operating temperature. Here we demonstrate that planar sodium–nickel chloride batteries can be operated at an intermediate temperature of 190 °C with ultra-high energy density. A specific energy density of 350 Wh kg−1, higher than that of conventional tubular sodium–nickel chloride batteries (280 °C), is obtained for planar sodium–nickel chloride batteries operated at 190 °C over a long-term cell test (1,000 cycles), and it attributed to the slower particle growth of the cathode materials at the lower operating temperature. Results reported here demonstrate that planar sodium–nickel chloride batteries operated at an intermediate temperature could greatly benefit this traditional energy storage technology by improving battery energy density, cycle life and reducing material costs. PMID:26864635

Insulating Material for Next-Generation Spacecraft

NASA Technical Reports Server (NTRS)

White, Susan; Johnson, Sylvia; Salerno, Louis; Kittel, Peter; Roach, Pat; Helvensteijn, Ben; Kashani, Ali

2006-01-01

A report discusses the development of a flexible thermal-insulation material for cryogenic tanks in next-generation spacecraft. This material is denoted Advanced Reusable All-temperature Multimode Insulation System (ARAMIS). The report begins by describing the need for ARAMIS and the technological challenges of developing a single material that is useable throughout the temperature range from storage of liquid hydrogen (20 K) to atmospheric-reentry heating (>2,000 K), has the requisite low thermal conductivity, resists condensation of moisture without need for a gas purge, and withstands reentry heating for a 400-mission lifetime. The report then discusses laboratory apparatuses for testing materials that have been and will be considered as candidates for the development of ARAMIS.

Temperature dependent absorption measurement of various transition metal doped laser materials

NASA Astrophysics Data System (ADS)

Horackova, Lucie; Šulc, Jan; Jelinkova, Helena; Jambunathan, Venkatesan; Lucianetti, Antonio; Mocek, Tomás.

2015-05-01

In recent years, there has been a vast development of high energy class lasers of the order of 100 J to kJ level which have potential applications in the field of science and technology. Many such systems use the gain media cooled at cryogenic temperatures which will help in enhancing the spectroscopic and thermo-optical properties. Nevertheless, parasitic effects like amplified spontaneous emission enhance and affect the overall efficiency. The best way to suppress this effect is to use cladding element attached to the gain material. Based on these facts, this work was focused on the systematic investigation of temperature dependent absorption of several materials doped with transition metals, which can be used as cladding, as laser gain material, or as passive Q-switching element. The Ti:sapphire, Cr:YAG, V:YAG, and Co:MALO samples were measured in temperature range from 80 K to 330 K by step of 50 K. Using Beer-Lambert law we estimated the absorption coefficient of these materials.

Advances in Ultra High Temperature Ceramics for Hot Structures

NASA Astrophysics Data System (ADS)

Scatteia, Luigi; Monteverde, Federico; Alfano, Davide; Cantoni, Stefania

The objective of this paper is to describe the current state of the art of the research on Ultra High Temperature Ceramic materials with particular reference to their space applications, and also to report on the activities performed on UHTC in the past decade by the Italian Aerospace Research Centre in the specific technological field of structural thermal protection systems. Within several internal research project, various UHTC composition, mainly based upon Zirconium Diboride and Hafnium Diboride with added secondary phases and sintering aid were examined characterized in their mechanical properties and oxidation resistance. Two main composition were selected as the most promising for hot structure manufacturing: these materials were extensively characterized in order to obtain a comprehensive database of properties to feed the thermomechanical design of prototype hot structures. Technological demonstrators were manufactured by hot pressing followed by further fine machining with Electrical Discharge methods, and then tested at high temperature for long times in a plasma torch facility. The main outstanding results obtained are discussed in this paper. Future outlooks related to the UHTC technology and its further development are also provided.

3-D inelastic analysis methods for hot section components (base program). [turbine blades, turbine vanes, and combustor liners

NASA Technical Reports Server (NTRS)

Wilson, R. B.; Bak, M. J.; Nakazawa, S.; Banerjee, P. K.

1984-01-01

A 3-D inelastic analysis methods program consists of a series of computer codes embodying a progression of mathematical models (mechanics of materials, special finite element, boundary element) for streamlined analysis of combustor liners, turbine blades, and turbine vanes. These models address the effects of high temperatures and thermal/mechanical loadings on the local (stress/strain) and global (dynamics, buckling) structural behavior of the three selected components. These models are used to solve 3-D inelastic problems using linear approximations in the sense that stresses/strains and temperatures in generic modeling regions are linear functions of the spatial coordinates, and solution increments for load, temperature and/or time are extrapolated linearly from previous information. Three linear formulation computer codes, referred to as MOMM (Mechanics of Materials Model), MHOST (MARC-Hot Section Technology), and BEST (Boundary Element Stress Technology), were developed and are described.

Flexible sample environment for high resolution neutron imaging at high temperatures in controlled atmosphere

DOE Office of Scientific and Technical Information (OSTI.GOV)

Makowska, Małgorzata G.; Theil Kuhn, Luise; Cleemann, Lars N.

In high material penetration by neutrons allows for experiments using sophisticated sample environments providing complex conditions. Thus, neutron imaging holds potential for performing in situ nondestructive measurements on large samples or even full technological systems, which are not possible with any other technique. Our paper presents a new sample environment for in situ high resolution neutron imaging experiments at temperatures from room temperature up to 1100 degrees C and/or using controllable flow of reactive atmospheres. The design also offers the possibility to directly combine imaging with diffraction measurements. Design, special features, and specification of the furnace are described. In addition,more » examples of experiments successfully performed at various neutron facilities with the furnace, as well as examples of possible applications are presented. Our work covers a broad field of research from fundamental to technological investigations of various types of materials and components.« less

Flexible sample environment for high resolution neutron imaging at high temperatures in controlled atmosphere

DOE PAGES

Makowska, Małgorzata G.; Theil Kuhn, Luise; Cleemann, Lars N.; ...

2015-12-17

In high material penetration by neutrons allows for experiments using sophisticated sample environments providing complex conditions. Thus, neutron imaging holds potential for performing in situ nondestructive measurements on large samples or even full technological systems, which are not possible with any other technique. Our paper presents a new sample environment for in situ high resolution neutron imaging experiments at temperatures from room temperature up to 1100 degrees C and/or using controllable flow of reactive atmospheres. The design also offers the possibility to directly combine imaging with diffraction measurements. Design, special features, and specification of the furnace are described. In addition,more » examples of experiments successfully performed at various neutron facilities with the furnace, as well as examples of possible applications are presented. Our work covers a broad field of research from fundamental to technological investigations of various types of materials and components.« less

Design, Fabrication and Characterization of High Temperature Joints in Ceramic Composites

NASA Technical Reports Server (NTRS)

Singh, M.

1999-01-01

Ceramic joining has been recognized as one of the enabling technologies for the successful utilization of ceramic components in a number of demanding, high temperature applications. Various joint design philosophies and design issues have been discussed along with an affordable, robust ceramic joining technology (ARCJoinT). A wide variety of silicon carbide-based composite materials, in different shapes and sizes, have been joined using this technology. This technique is capable of producing joints with tailorable thickness and composition. The room and high temperature mechanical properties and fractography of ceramic joints have been reported. These joints maintain their mechanical strength up to 1200 C in air. This technology is suitable for the joining of large and complex shaped ceramic composite components and with certain modifications, can be applied to repair of ceramic components damaged in service.

Design, Fabrication, and Characterization of High Temperature Joints in Ceramic Composites

NASA Technical Reports Server (NTRS)

Singh, M.

1999-01-01

Ceramic joining has been recognized as one of the enabling technologies for the successful utilization of ceramic components in a number of demanding, high temperature applications. Various joint design philosophies and design issues have been discussed along with an affordable, robust ceramic joining technology (ARCJoinT). A wide variety of silicon carbide-based composite materials, in different shapes and sizes, have been joined using this technology. This technique is capable of producing joints with tailorable thickness and composition. The room and high temperature mechanical properties and fractography of ceramic joints have been reported. These joints maintain their mechanical strength up to 1200C in air. This technology is suitable for the joining of large and complex shaped ceramic composite components and with certain modifications, can be applied to repair of ceramic components damaged in service.

The operation of 0.35 μm partially depleted SOI CMOS technology in extreme environments

NASA Astrophysics Data System (ADS)

Li, Ying; Niu, Guofu; Cressler, John D.; Patel, Jagdish; Liu, S. T.; Reed, Robert A.; Mojarradi, Mohammad M.; Blalock, Benjamin J.

2003-06-01

We evaluate the usefulness of partially depleted SOI CMOS devices fabricated in a 0.35 μm technology on UNIBOND material for electronics applications requiring robust operation under extreme environment conditions consisting of low and/or high temperature, and under substantial radiation exposure. The threshold voltage, effective mobility, and the impact ionization parameters were determined across temperature for both the nFETs and the pFETs. The radiation response was characterized using threshold voltage shifts of both the front-gate and back-gate transistors. These results suggest that this 0.35 μm partially depleted SOI CMOS technology is suitable for operation across a wide range of extreme environment conditions consisting of: cryogenic temperatures down to 86 K, elevated temperatures up to 573 K, and under radiation exposure to 1.3 Mrad(Si) total dose.

Prospects and progress of high Tc superconductivity for space applications

NASA Technical Reports Server (NTRS)

Romanofsky, Robert R.; Sokoloski, Marty M.

1991-01-01

Current research in the area of high temperature superconductivity is organized around four key areas: communications and data, sensors and cryogenics, propulsion and power, and space materials technology. Recently, laser ablated YBa2Cu3O(7-x) films on LaAlO3 produced far superior RF characteristics when compared to metallic films on the same substrate. The achievement has enabled a number of unique microwave device applications, such as low insertion loss phase shifters and high-Q filters. Melt texturing and melt-quenched techniques are being used to produce bulk material with optimized magnetic properties. These yttrium-enriched materials possess enhanced flux pinning characteristics and could lead to prototype cryocooler bearings. Significant progress has also occurred in bolometer and current lead technology. Studies were conducted to evaluate the effect of high temperature superconducting materials on the performance and life of high power magnetoplasma-dynamic thrusters. Extended studies were also performed to evaluate the benefit of superconducting magnetic energy storage for LEO space station, lunar, and Mars mission applications.

Environmental Screening of Electrode Materials for a Rechargeable Aluminum Battery with an AlCl₃/EMIMCl Electrolyte.

PubMed

Ellingsen, Linda Ager-Wick; Holland, Alex; Drillet, Jean-Francois; Peters, Willi; Eckert, Martin; Concepcion, Carlos; Ruiz, Oscar; Colin, Jean-François; Knipping, Etienne; Pan, Qiaoyan; Wills, Richard G A; Majeau-Bettez, Guillaume

2018-06-01

Recently, rechargeable aluminum batteries have received much attention due to their low cost, easy operation, and high safety. As the research into rechargeable aluminum batteries with a room-temperature ionic liquid electrolyte is relatively new, research efforts have focused on finding suitable electrode materials. An understanding of the environmental aspects of electrode materials is essential to make informed and conscious decisions in aluminum battery development. The purpose of this study was to evaluate and compare the relative environmental performance of electrode material candidates for rechargeable aluminum batteries with an AlCl₃/EMIMCl (1-ethyl-3-methylimidazolium chloride) room-temperature ionic liquid electrolyte. To this end, we used a lifecycle environmental screening framework to evaluate 12 candidate electrode materials. We found that all of the studied materials are associated with one or more drawbacks and therefore do not represent a "silver bullet" for the aluminum battery. Even so, some materials appeared more promising than others did. We also found that aluminum battery technology is likely to face some of the same environmental challenges as Li-ion technology but also offers an opportunity to avoid others. The insights provided here can aid aluminum battery development in an environmentally sustainable direction.

An Insertable Passive LC Pressure Sensor Based on an Alumina Ceramic for In Situ Pressure Sensing in High-Temperature Environments.

PubMed

Xiong, Jijun; Li, Chen; Jia, Pinggang; Chen, Xiaoyong; Zhang, Wendong; Liu, Jun; Xue, Chenyang; Tan, Qiulin

2015-08-31

Pressure measurements in high-temperature applications, including compressors, turbines, and others, have become increasingly critical. This paper proposes an implantable passive LC pressure sensor based on an alumina ceramic material for in situ pressure sensing in high-temperature environments. The inductance and capacitance elements of the sensor were designed independently and separated by a thermally insulating material, which is conducive to reducing the influence of the temperature on the inductance element and improving the quality factor of the sensor. In addition, the sensor was fabricated using thick film integrated technology from high-temperature materials that ensure stable operation of the sensor in high-temperature environments. Experimental results showed that the sensor accurately monitored pressures from 0 bar to 2 bar at temperatures up to 800 °C. The sensitivity, linearity, repeatability error, and hysteretic error of the sensor were 0.225 MHz/bar, 95.3%, 5.5%, and 6.2%, respectively.

An Insertable Passive LC Pressure Sensor Based on an Alumina Ceramic for In Situ Pressure Sensing in High-Temperature Environments

PubMed Central

Xiong, Jijun; Li, Chen; Jia, Pinggang; Chen, Xiaoyong; Zhang, Wendong; Liu, Jun; Xue, Chenyang; Tan, Qiulin

2015-01-01

Pressure measurements in high-temperature applications, including compressors, turbines, and others, have become increasingly critical. This paper proposes an implantable passive LC pressure sensor based on an alumina ceramic material for in situ pressure sensing in high-temperature environments. The inductance and capacitance elements of the sensor were designed independently and separated by a thermally insulating material, which is conducive to reducing the influence of the temperature on the inductance element and improving the quality factor of the sensor. In addition, the sensor was fabricated using thick film integrated technology from high-temperature materials that ensure stable operation of the sensor in high-temperature environments. Experimental results showed that the sensor accurately monitored pressures from 0 bar to 2 bar at temperatures up to 800 °C. The sensitivity, linearity, repeatability error, and hysteretic error of the sensor were 0.225 MHz/bar, 95.3%, 5.5%, and 6.2%, respectively. PMID:26334279

Room temperature organic magnets derived from sp3 functionalized graphene.

PubMed

Tuček, Jiří; Holá, Kateřina; Bourlinos, Athanasios B; Błoński, Piotr; Bakandritsos, Aristides; Ugolotti, Juri; Dubecký, Matúš; Karlický, František; Ranc, Václav; Čépe, Klára; Otyepka, Michal; Zbořil, Radek

2017-02-20

Materials based on metallic elements that have d orbitals and exhibit room temperature magnetism have been known for centuries and applied in a huge range of technologies. Development of room temperature carbon magnets containing exclusively sp orbitals is viewed as great challenge in chemistry, physics, spintronics and materials science. Here we describe a series of room temperature organic magnets prepared by a simple and controllable route based on the substitution of fluorine atoms in fluorographene with hydroxyl groups. Depending on the chemical composition (an F/OH ratio) and sp 3 coverage, these new graphene derivatives show room temperature antiferromagnetic ordering, which has never been observed for any sp-based materials. Such 2D magnets undergo a transition to a ferromagnetic state at low temperatures, showing an extraordinarily high magnetic moment. The developed theoretical model addresses the origin of the room temperature magnetism in terms of sp 2 -conjugated diradical motifs embedded in an sp 3 matrix and superexchange interactions via -OH functionalization.

Room temperature organic magnets derived from sp3 functionalized graphene

PubMed Central

Tuček, Jiří; Holá, Kateřina; Bourlinos, Athanasios B.; Błoński, Piotr; Bakandritsos, Aristides; Ugolotti, Juri; Dubecký, Matúš; Karlický, František; Ranc, Václav; Čépe, Klára; Otyepka, Michal; Zbořil, Radek

2017-01-01

Materials based on metallic elements that have d orbitals and exhibit room temperature magnetism have been known for centuries and applied in a huge range of technologies. Development of room temperature carbon magnets containing exclusively sp orbitals is viewed as great challenge in chemistry, physics, spintronics and materials science. Here we describe a series of room temperature organic magnets prepared by a simple and controllable route based on the substitution of fluorine atoms in fluorographene with hydroxyl groups. Depending on the chemical composition (an F/OH ratio) and sp3 coverage, these new graphene derivatives show room temperature antiferromagnetic ordering, which has never been observed for any sp-based materials. Such 2D magnets undergo a transition to a ferromagnetic state at low temperatures, showing an extraordinarily high magnetic moment. The developed theoretical model addresses the origin of the room temperature magnetism in terms of sp2-conjugated diradical motifs embedded in an sp3 matrix and superexchange interactions via –OH functionalization. PMID:28216636

3D Printable Graphene Composite

NASA Astrophysics Data System (ADS)

Wei, Xiaojun; Li, Dong; Jiang, Wei; Gu, Zheming; Wang, Xiaojuan; Zhang, Zengxing; Sun, Zhengzong

2015-07-01

In human being’s history, both the Iron Age and Silicon Age thrived after a matured massive processing technology was developed. Graphene is the most recent superior material which could potentially initialize another new material Age. However, while being exploited to its full extent, conventional processing methods fail to provide a link to today’s personalization tide. New technology should be ushered in. Three-dimensional (3D) printing fills the missing linkage between graphene materials and the digital mainstream. Their alliance could generate additional stream to push the graphene revolution into a new phase. Here we demonstrate for the first time, a graphene composite, with a graphene loading up to 5.6 wt%, can be 3D printable into computer-designed models. The composite’s linear thermal coefficient is below 75 ppm·°C-1 from room temperature to its glass transition temperature (Tg), which is crucial to build minute thermal stress during the printing process.

Life prediction of materials exposed to monotonic and cyclic loading: Bibliography

NASA Technical Reports Server (NTRS)

Carpenter, J. L., Jr.; Moya, N.; Stuhrke, W. F.

1975-01-01

This bibliography is comprised of approximately 1200 reference citations related to the mechanics of failure in aerospace structures. Most of the references are for information on life prediction for materials exposed to monotonic and cyclic loading in elevated temperature environments such as that in the hot end of a gas turbine engine. Additional citations listed are for documents on the thermal and mechanical effects on solar cells in the cryogenic vacuum environment; radiation effects on high temperature mechanical properties; and high cycle fatigue technology as applicable to gas turbine engine bearings. The bibliography represents a search of the literature published in the period April 1962 through April 1974 and is largely limited to documents published in the United States. It is a companion volume to NASA CR-134750, Life Prediction of Materials Exposed to Monotonic and cyclic Loading - A Technology Survey.

3D Printable Graphene Composite

PubMed Central

Wei, Xiaojun; Li, Dong; Jiang, Wei; Gu, Zheming; Wang, Xiaojuan; Zhang, Zengxing; Sun, Zhengzong

2015-01-01

In human being’s history, both the Iron Age and Silicon Age thrived after a matured massive processing technology was developed. Graphene is the most recent superior material which could potentially initialize another new material Age. However, while being exploited to its full extent, conventional processing methods fail to provide a link to today’s personalization tide. New technology should be ushered in. Three-dimensional (3D) printing fills the missing linkage between graphene materials and the digital mainstream. Their alliance could generate additional stream to push the graphene revolution into a new phase. Here we demonstrate for the first time, a graphene composite, with a graphene loading up to 5.6 wt%, can be 3D printable into computer-designed models. The composite’s linear thermal coefficient is below 75 ppm·°C−1 from room temperature to its glass transition temperature (Tg), which is crucial to build minute thermal stress during the printing process. PMID:26153673

NEET Enhanced Micro-Pocket Fission Detector for High Temperature Reactors - FY16 Status Report

DOE Office of Scientific and Technical Information (OSTI.GOV)

Unruh, Troy; Reichenberger, Michael; Stevenson, Sarah

2016-09-01

A collaboration between the Idaho National Laboratory (INL), the Kansas State University (KSU), and the French Atomic Energy Agency, Commissariat à l'Énergie Atomique et aux Energies Alternatives, (CEA), has been initiated by the Nuclear Energy Enabling Technologies (NEET) Advanced Sensors and Instrumentation (ASI) program for developing and testing High Temperature Micro-Pocket Fission Detectors (HT MPFD), which are compact fission chambers capable of simultaneously measuring thermal neutron flux, fast neutron flux and temperature within a single package for temperatures up to 800 °C. The MPFD technology utilizes a small, multi-purpose, robust, in-core fission chambers and thermocouple. As discussed within this report,more » the small size, variable sensitivity, and increased accuracy of the MPFD technology represent a revolutionary improvement over current methods used to support irradiations in US Material Test Reactors (MTRs). Previous research conducted through NEET ASI1-3 has shown that the MPFD technology could be made robust and was successfully tested in a reactor core. This new project will further the MPFD technology for higher temperature regimes and other reactor applications by developing a HT MPFD suitable for temperatures up to 800 °C. This report summarizes the research progress for year two of this three year project. Highlights from research accomplishments include: • Continuation of a joint collaboration between INL, KSU, and CEA. Note that CEA is participating at their own expense because of interest in this unique new sensor. • An updated parallel wire HT MPFD design was developed. • Program support for HT MPFD deployments was given to Accident Tolerant Fuels (ATF) and Advanced Gas-cooled Reactor (AGR) irradiation test programs. • Quality approved materials for HT MPFD construction were procured by irradiation test programs for upcoming deployments. • KSU improved and performed electrical contact and fissile material plating. • KSU delivered fissile HT MPFD parts to INL for final construction of HT MPFD prototype. • A prototype HT MPFD was constructed and analyzed at INL. • The HT MPFD has been modeled in MCNP to optimize the amount of fissile material deposition. • The HT MPFD has been modeled in MCNP to optimize the sensor location in the irradiation test. • The fissile material deposition is undergoing independent verifications. • Detector amplifier electronics have been revised and tested by KSU. • Several project meetings were held at INL and KSU to discuss the roles and responsibilities between INL, KSU, and CEA for development and deployment of the HT MPFDs. As documented in this report, FY16 funding has allowed the project to meet year two planned accomplishments to develop a HT MPFD. In addition, the accomplishments of this project have attracted independent funding from other Department of Energy Office of Nuclear Energy (DOE-NE) programs for MTR irradiations of the MPFD technology. These are significant opportunities for this NEET Enhanced Micro-Pocket Fission Detector for High Temperature Reactors project because the irradiation expense of these experiments could not be included in the original project scope.« less

Development of High Temperature Gas Sensor Technology

NASA Technical Reports Server (NTRS)

Hunter, Gary W.; Chen, Liang-Yu; Neudeck, Philip G.; Knight, Dak; Liu, Chung-Chiun; Wu, Quing-Hai; Zhou, Huan-Jun

1997-01-01

The measurement of engine emissions is important for their monitoring and control. However, the ability to measure these emissions in-situ is limited. We are developing a family of high temperature gas sensors which are intended to operate in harsh environments such as those in an engine. The development of these sensors is based on progress in two types of technology: (1) The development of SiC-based semiconductor technology; and (2) Improvements in micromachining and microfabrication technology. These technologies are being used to develop point-contact sensors to measure gases which are important in emission control especially hydrogen, hydrocarbons, nitrogen oxides, and oxygen. The purpose of this paper is to discuss the development of this point-contact sensor technology. The detection of each type of gas involves its own challenges in the fields of materials science and fabrication technology. Of particular importance is sensor sensitivity, selectivity, and stability in long-term, high temperature operation. An overview is presented of each sensor type with an evaluation of its stage of development. It is concluded that this technology has significant potential for use in engine applications but further development is necessary.

Application specific beam profiles: new surface and thin-film refinement processes using beam shaping technologies

NASA Astrophysics Data System (ADS)

Hauschild, Dirk

2017-02-01

Today, the use of laser photons for materials processing is a key technology in nearly all industries. Most of the applications use circular beam shapes with Gaussian intensity distribution that is given by the resonator of the laser or by the power delivery via optical fibre. These beam shapes can be typically used for material removal with cutting or drilling and for selective removal of material layers with ablation processes. In addition to the removal of materials, it is possible to modify and improve the material properties in case the dose of laser photons and the resulting light-material interaction addresses a defined window of energy and dwell-time. These process windows have typically dwell-times between µs and s because of using sintering, melting, thermal diffusion or photon induced chemical and physical reaction mechanisms. Using beam shaping technologies the laser beam profiles can be adapted to the material properties and time-temperature and the space-temperature envelopes can be modified to enable selective annealing or crystallization of layers or surfaces. Especially the control of the process energy inside the beam and at its edges opens a large area of laser applications that can be addressed only with an optimized spatial and angular beam profile with down to sub-percent intensity variation used in e.g. immersion lithography tools with ArF laser sources. LIMO will present examples for new beam shapes and related material refinement processes even on large surfaces and give an overview about new mechanisms in laser material processing for current and coming industrial applications.

A Metal Bump Bonding Method Using Ag Nanoparticles as Intermediate Layer

NASA Astrophysics Data System (ADS)

Fu, Weixin; Nimura, Masatsugu; Kasahara, Takashi; Mimatsu, Hayata; Okada, Akiko; Shoji, Shuichi; Ishizuka, Shugo; Mizuno, Jun

2015-11-01

The future development of low-temperature and low-pressure bonding technology is necessary for fine-pitch bump application. We propose a bump structure using Ag nanoparticles as an intermediate layer coated on a fine-pitch Cu pillar bump. The intermediate layer is prepared using an efficient and cost-saving squeegee-coating method followed by a 100°C baking process. This bump structure can be easily flattened before the bonding process, and the low-temperature sinterability of the nanoparticles is retained. The bonding experiment was successfully performed at 250°C and 39.8 MPa and the bonding strength was comparable to that achieved via other bonding technology utilizing metal particles or porous material as bump materials.

Investigation of Materials Processing Technology

DTIC Science & Technology

1993-07-01

Figure 6: Time-temperature curves of A357 casting in Cu mold ................. 12 Figure 7: Time-temperature curves of 17 -4 casting in ceramic mold...simulation of 17 -4 ................ 17 Figure 12: IHTC from IHEAT simulation of 17 -4 casting ..................... 18 Figure 13: Temperature profiles...mold used for Ti castings .......................... 23 Figure 16: Cooling curves for a Ti casting in ceramic mold .................. 24 Figure 17

Ceramics Technology Project database: September 1991 summary report

DOE Office of Scientific and Technical Information (OSTI.GOV)

Keyes, B.L.P.

1992-06-01

The piston ring-cylinder liner area of the internal combustion engine must withstand very-high-temperature gradients, highly-corrosive environments, and constant friction. Improving the efficiency in the engine requires ring and cylinder liner materials that can survive this abusive environment and lubricants that resist decomposition at elevated temperatures. Wear and friction tests have been done on many material combinations in environments similar to actual use to find the right materials for the situation. This report covers tribology information produced from 1986 through July 1991 by Battelle columbus Laboratories, Caterpillar Inc., and Cummins Engine Company, Inc. for the Ceramic Technology Project (CTP). All datamore » in this report were taken from the project`s semiannual and bimonthly progress reports and cover base materials, coatings, and lubricants. The data, including test rig descriptions and material characterizations, are stored in the CTP database and are available to all project participants on request. Objective of this report is to make available the test results from these studies, but not to draw conclusions from these data.« less

Overview of Lightweight Structures for Rotorcraft Engines and Drivetrains

NASA Technical Reports Server (NTRS)

Roberts, Gary D.

2011-01-01

This is an overview presentation of research being performed in the Advanced Materials Task within the NASA Subsonic Rotary Wing Project. This research is focused on technology areas that address both national goals and project goals for advanced rotorcraft. Specific technology areas discussed are: (1) high temperature materials for advanced turbines in turboshaft engines; (2) polymer matrix composites for lightweight drive system components; (3) lightweight structure approaches for noise and vibration control; and (4) an advanced metal alloy for lighter weight bearings and more reliable mechanical components. An overview of the technology in each area is discussed, and recent accomplishments are presented.

High voltage insulation of bushing for HTS power equipment

NASA Astrophysics Data System (ADS)

Kim, Woo-Jin; Choi, Jae-Hyeong; Kim, Sang-Hyun

2012-12-01

For the operation of high temperature superconducting (HTS) power equipments, it is necessary to develop insulating materials and high voltage (HV) insulation technology at cryogenic temperature of bushing. Liquid nitrogen (LN2) is an attractive dielectric liquid. Also, the polymer insulating materials are expected to be used as solid materials such as glass fiber reinforced plastic (GFRP), polytetra-fluoroethylene (PTFE, Teflon), Silicon (Si) rubber, aromatic polyamide (Nomex), EPDM/Silicon alloy compound (EPDM/Si). In this paper, the surface flashover characteristics of various insulating materials in LN2 are studied. These results are studied at both AC and impulse voltage under a non-uniform field. The use of GFRP and Teflon as insulation body for HTS bushing should be much desirable. Especially, GFRP is excellent material not only surface flashover characteristics but also mechanical characteristics at cryogenic temperature. The surface flashover is most serious problem for the shed design in LN2 and operation of superconducting equipments.

Thermocouples--The Most Widely Used Temperature Sensor in Manufacturing

ERIC Educational Resources Information Center

Mitts, Charles R.

2006-01-01

Researchers predict that future developments in nanotechnology will bring incredible, almost inconceivable, change to the manufacturing industry. For now, though, one of technology's most trusted tools remains very relevant: In the field of thermometry, thermocouples are a tried and true technology. As a consequence, material on thermocouples…

2007 Insensitive Munitions and Energetic Materials Technology Symposium

DTIC Science & Technology

2007-10-18

Flat end rod Round end rod Flat cookie -cutter Spherical fragment Simple shaped charge jet Real shaped charge jet Thin plate Constant Temperature...while the press is running • No one allowed in the facility before dough -up • Maximum pressures, torque and temperatures set. • First warnings and

Temperature-Dependent Refractive Index of Cleartran® ZnS to Cryogenic Temperatures

NASA Technical Reports Server (NTRS)

Leviton, Doug; Frey, Brad

2013-01-01

First, let's talk about the CHARMS facility at NASA's Goddard Space Flight Center: Cryogenic, High-Accuracy Refraction Measuring System (CHARMS); design features for highest accuracy and precision; technologies we rely on; data products and examples; optical materials for which we've measured cryogenic refractive index.

NASA Subsonic Rotary Wing Project - Structures and Materials Discipline

NASA Technical Reports Server (NTRS)

Halbig, Michael C.; Johnson, Susan M.

2008-01-01

The Structures & Materials Discipline within the NASA Subsonic Rotary Wing Project is focused on developing rotorcraft technologies. The technologies being developed are within the task areas of: 5.1.1 Life Prediction Methods for Engine Structures & Components 5.1.2 Erosion Resistant Coatings for Improved Turbine Blade Life 5.2.1 Crashworthiness 5.2.2 Methods for Prediction of Fatigue Damage & Self Healing 5.3.1 Propulsion High Temperature Materials 5.3.2 Lightweight Structures and Noise Integration The presentation will discuss rotorcraft specific technical challenges and needs as well as details of the work being conducted in the six task areas.

Fire retardancy using applied materials

NASA Technical Reports Server (NTRS)

Feldman, R.

1971-01-01

An example of advanced technology transfer from the Little Joe, Surveyor, Comsat, re-entry and Apollo age to everyday fire protection needs is presented. Utilizing the principle of sublimation cooling for thermostatic temperature control, the material meets a wide range of fire retardancy and heat transmission control requirements. Properties vary from flexible tape for conduits and electrical cables to rigid coatings for column protection, with a broad spectrum of sublimation temperatures available. The material can be applied in the field or in the factory, utilizing mass production techniques, yielding a product that is reliable, effective, widely available and low in cost.

Technology development of a biowaste resistojet, volume 1

NASA Technical Reports Server (NTRS)

Phillips, D. G.

1972-01-01

The materials research effort conducted in support of a NASA-sponsored biowaste resistojet development program is summarized. The resistojet concept under development is the concentric tube design wherein the final pass of the gases through the thruster is through the resistance heated center tube. To produce high specific impulses, this center tube must operate at very high temperatures and it is this element that is most critical in the design. Because of the corrosive nature of the biowaste gases at high temperature, and because of the limited data available for many potential materials, the subject materials study was conducted.

The Use of Combustion Reactions for Processing Mineral Raw Materials: Metallothermy and Self-propagating High-temperature Synthesis (Review)

NASA Astrophysics Data System (ADS)

Urakaev, Farit Kh.; Akmalaev, Kenzhebek A.; Orynbekov, Eljan S.; Balgysheva, Beykut D.; Zharlykasimova, Dinar N.

2016-02-01

The use of metallothermy (MT) and self-propagating high-temperature synthesis (SHS) is considered for processing different geological and technogenic materials. Traditional MT and SHS processes for production of various metals and nonmetal materials are widely known. Another rapidly developing direction is that connected with the use of ores, concentrates, minerals, and technogenic waste products as one of the components of a thermite mixture, both for the treatment of mineral raw by means of MT or SHS resulting in semi-products and for technological, analytical, and ecological purposes.

Temperature control transport system

DOEpatents

Schabron, John F; Sorini-Wong, Susan S

2014-12-09

Embodiments of the inventive technology may involve the use of layered, insulated PCM assemblage that itself comprises: modular insulating foam material 8 that, upon establishment as part of the assemblage, defines inner foam material sides 9 and outer foam material sides 10; thin reflective material 11 established against (whether directly in contact with or not) at least either the inner foam material sides or the outer foam materials sides, and modular, enclosed PCM sections 12 established between the modular insulating foam material and the interior center.

Novel Materials, Processing and Device Technologies for Space Exploration with Potential Dual-Use Applications

NASA Technical Reports Server (NTRS)

Hepp, A. F.; Bailey, S. G.; McNatt, J. S.; Chandrashekhar, M. V. S.; Harris, J. D.; Rusch, A. W.; Nogales, K. A.; Goettsche, K.V.; Hanson, W.; Amos, D.;

Novel Materials, Processing, and Device Technologies for Space Exploration with Potential Dual-Use Applications

NASA Technical Reports Server (NTRS)

Hepp, A. F.; Bailey, S. G.; McNatt, J. S.; Chandrashekhar, M. V. S.; Harris, J. D.; Rusch, A. W.; Nogales, K. A.; Goettsche, K. V.; Hanson, W.; Amos, D.;

Bone regeneration of critical calvarial defect in goat model by PLGA/TCP/rhBMP-2 scaffolds prepared by low-temperature rapid-prototyping technology.

PubMed

Yu, D; Li, Q; Mu, X; Chang, T; Xiong, Z

2008-10-01

Active artificial bone composed of poly lactide-co-glycolide (PLGA)/ tricalcium phosphate (TCP) was prefabricated using low-temperature rapid-prototyping technology so that the process of osteogenesis could be observed in it. PLGA and TCP were the primary materials, they were molded at low temperature, then recombinant human bone morphogenetic protein-2 (rhBMP-2) was added to form an active artificial bone. Goats with standard cranial defects were randomly divided into experimental (implants with rhBMP-2 added) and control (implants without rhBMP-2) groups, and osteogenesis was observed and evaluated by imaging and biomechanical and histological examinations. The PLGA-TCP artificial bone scaffold (90% porosity) had large and small pores of approximately 360microm and 3-5microm diameter. Preliminary and complete repair of the cranial defect in the goats occurred 12 and 24 weeks after surgery, respectively. The three-point bending strength of the repaired defects attained that of the normal cranium. In conclusion, low-temperature rapid-prototyping technology can preserve the biological activity of this scaffold material. The scaffold has a good three-dimensional structure and it becomes an active artificial bone after loading with rhBMP-2 with a modest degradation rate and excellent osteogenesis in the goat.

Proceedings of the Second Noncontact Temperature Measurement Workshop

NASA Technical Reports Server (NTRS)

Hale, Robert R. (Editor)

1989-01-01

The state of the art in noncontact temperature measurement (NCTM) technology was reviewed and the NCTM requirements of microgravity materials processing community identified. The workshop included technical presentations and discussions which ranged from research on advanced concepts for temperature measurement to laboratory research and development regarding measurement principles and state-of-the-art engineering practices for NCTM methodology in commercial and industrial applications. Technical presentations were made concerning: NCTM needs as perceived by several NASA centers, recent ground-based NCT, research and development of industry, NASA, academia, and selected national laboratories, work-in-progress communication, and technical issues of the implementation of temperature measurement in the space environment to facilitate future U.S. materials science investigations.

Combustion synthesis of ceramic-metal composite materials in microgravity

NASA Technical Reports Server (NTRS)

Moore, John

1995-01-01

Combustion synthesis, self-propagating high temperature synthesis (SHS) or reactive synthesis provides an attractive alternative to conventional methods of producing advanced materials since this technology is based on the ability of highly exothermic reactions to be self sustaining and, therefore, energetically efficient. The exothermic SHS reaction is initiated at the ignition temperature, T(sub ig), and generates heat which is manifested in a maximum or combustion temperature, T(sub c), which can exceed 3000 K . Such high combustion temperatures are capable of melting and/or volatilizing reactant and product species and, therefore, present an opportunity for producing structure and property modification and control through liquid-solid, vapor-liquid-solid, and vapor-solid transformations.

NEET Enhanced Micro Pocket Fission Detector for High Temperature Reactors - FY15 Status Report

DOE Office of Scientific and Technical Information (OSTI.GOV)

Unruh, Troy; McGregor, Douglas; Ugorowski, Phil

2015-09-01

A new project, that is a collaboration between the Idaho National Laboratory (INL), the Kansas State University (KSU), and the French Atomic Energy Agency, Commissariat à l'Énergie Atomique et aux Energies Alternatives, (CEA), has been initiated by the Nuclear Energy Enabling Technologies (NEET) Advanced Sensors and Instrumentation (ASI) program for developing and testing High Temperature Micro-Pocket Fission Detectors (HT MPFD), which are compact fission chambers capable of simultaneously measuring thermal neutron flux, fast neutron flux and temperature within a single package for temperatures up to 800 °C. The MPFD technology utilizes a small, multi-purpose, robust, in-core parallel plate fission chambermore » and thermocouple. As discussed within this report, the small size, variable sensitivity, and increased accuracy of the MPFD technology represent a revolutionary improvement over current methods used to support irradiations in US Material Test Reactors (MTRs). Previous research conducted through NEET ASI1-3 has shown that the MPFD technology could be made robust and was successfully tested in a reactor core. This new project will further the MPFD technology for higher temperature regimes and other reactor applications by developing a HT MPFD suitable for temperatures up to 800 °C. This report summarizes the research progress for year one of this three year project. Highlights from research accomplishments include: A joint collaboration was initiated between INL, KSU, and CEA. Note that CEA is participating at their own expense because of interest in this unique new sensor. An updated HT MPFD design was developed. New high temperature-compatible materials for HT MPFD construction were procured. Construction methods to support the new design were evaluated at INL. Laboratory evaluations of HT MPFD were initiated. Electrical contact and fissile material plating has been performed at KSU. Updated detector electronics are undergoing evaluations at KSU. A project meeting was held at KSU to discuss the roles and responsibilities between INL and KSU for development of the HT MPFDs. Provide input to various irradiation programs for installation of the MPFD technology in irradiation tests. As documented in this report, FY15 funding has allowed the project to meet year one planned accomplishments to develop a HT MPFD that offers US MTR users enhanced capabilities for real-time measurement of flux and temperature with a single detector. In addition, the accomplishments of this project have attracted funding from other Department of Energy Office of Nuclear Energy (DOE-NE) programs for additional applications. The work in those programs will build on current activities completed in this NEETASI HT MPFD project, but the MPFD will be specifically tailored to meet their program needs.« less

Design and development of the CubeSat Infrared Atmospheric Sounder (CIRAS)

NASA Astrophysics Data System (ADS)

Pagano, Thomas S.; Abesamis, Carlo; Andrade, Andres; Aumann, Hartmut; Gunapala, Sarath; Heneghan, Cate; Jarnot, Robert; Johnson, Dean; Lamborn, Andy; Maruyama, Yuki; Rafol, Sir; Raouf, Nasrat; Rider, David; Ting, Dave; Wilson, Dan; Yee, Karl; Cole, Jerold; Good, Bill; Kampe, Tom; Soto, Juancarlos; Adams, Arn; Buckley, Matt; Nicol, Fred; Vengel, Tony

2017-09-01

The CubeSat Infrared Atmospheric Sounder (CIRAS) is a NASA Earth Science Technology Office (ESTO) sponsored mission to demonstrate key technologies used in very high spectral resolution infrared remote sensing of Earth's atmosphere from space. CIRAS was awarded under the ESTO In-flight Validation of Earth Science Technologies (InVEST) program in 2015 and is currently under development at NASA JPL with key subsystems being developed by industry. CIRAS incorporates key new instrument technologies including a 2D array of High Operating Temperature Barrier Infrared Detector (HOT-BIRD) material, selected for its high uniformity, low cost, low noise and higher operating temperatures than traditional materials. The second key technology is an MWIR Grating Spectrometer (MGS) designed to provide imaging spectroscopy for atmospheric sounding in a CubeSat volume. The MGS is under development by Ball Aerospace with the grating and slit developed by JPL. The third key technology is a blackbody fabricated with JPL's black silicon to have very high emissivity in a flat plate construction. JPL will also develop the mechanical, electronic and thermal subsystems for CIRAS, while the spacecraft will be a 6U CubeSat developed by Blue Canyon Technologies. This paper provides an overview of the design and acquisition approach, and provides a status of the current development.

Evolution of technologies applied to space and aeronautic structures

NASA Astrophysics Data System (ADS)

Abiven, H.

Advanced materials in aerospace structures and their use in reusable launch vehicles are discussed. It is found that composite materials can be used for structures with temperatures up to 400 C, and for most structures with heat shielding. For structures with temperatures up to 1000 C, metals such as Norsial, based on rene alloys could be used. It is concluded that a combination of silicon and carbon composites with Aerocoat/TH hydrotranspiration heat shielding give a heat flux resistant structure with no thermal dilation problems.

Study of powder coatings formation modes in Transport Machine-Building Industry

NASA Astrophysics Data System (ADS)

Bodrov, A. S.; Panichkin, A. V.; Kamanin, Y. N.; Kulev, M. V.

2018-03-01

This article describes the use of powder coating materials as an effective corrosion protection system. The correlation between the substrate heating temperature on the optical characteristics of the radiator used and coating material applied was analyzed. The assumption that the process of thermoradiation curing of powder coatings is influenced by two factors (temperature and radiation effect) is confirmed. It was determined that there is a possibility of improving the resource-saving technology based on the conducted studies.

High density circuit technology, part 2

NASA Technical Reports Server (NTRS)

Wade, T. E.

1982-01-01

A multilevel metal interconnection system for very large scale integration (VLSI) systems utilizing polyimides as the interlayer dielectric material is described. A complete characterization of polyimide materials is given as well as experimental methods accomplished using a double level metal test pattern. A low temperature, double exposure polyimide patterning procedure is also presented.

Application of CFCC technology to hot gas filtration applications

DOE Office of Scientific and Technical Information (OSTI.GOV)

Richlen, S.

1995-06-01

Discussion will feature high temperature filter development under the DOE`s Office of Industrial Technologies Continuous Fiber Ceramic Composite (CFCC) Program. Within the CFCC Program there are four industry projects and a national laboratory technology support project. Atlantic Research, Babcock & Wilcox, DuPont Lanxide Composites, and Textron are developing processing methods to produce CFCC Components with various types of matrices and composites, along with the manufacturing methods to produce industrial components, including high temperature gas filters. The Oak Ridge National Laboratory is leading a National Laboratory/University effort to increase knowledge of such generic and supportive technology areas as environmental degradation, measurementmore » of mechanical properties, long-term performance, thermal shock and thermal cycling, creep and fatigue, and non-destructive characterization. Tasks include composite design, materials characterization, test methods, and performance-related phenomena, that will support the high temperature filter activities of industry and government.« less

High temperature and frequency pressure sensor based on silicon-on-insulator layers

NASA Astrophysics Data System (ADS)

Zhao, Y. L.; Zhao, L. B.; Jiang, Z. D.

2006-03-01

Based on silicon on insulator (SOI) technology, a novel high temperature pressure sensor with high frequency response is designed and fabricated, in which a buried silicon dioxide layer in the silicon material is developed by the separation by implantation of oxygen (SIMOX) technology. This layer can isolate leak currents between the top silicon layer for the detecting circuit and body silicon at a temperature of about 200 °C. In addition, the technology of silicon and glass bonding is used to create a package of the sensor without internal strain. A structural model and test data from the sensor are presented. The experimental results showed that this kind of sensor possesses good static performance in a high temperature environment and high frequency dynamic characteristics, which may satisfy the pressure measurement demands of the oil industry, aviation and space, and so on.

Effect of strain on the Curie temperature and band structure of low-dimensional SbSI

NASA Astrophysics Data System (ADS)

Wang, Yiping; Hu, Yang; Chen, Zhizhong; Guo, Yuwei; Wang, Dong; Wertz, Esther A.; Shi, Jian

2018-04-01

Photoferroelectric materials show great promise for developing alternative photovoltaics and photovoltaic-type non-volatile memories. However, the localized nature of the d orbital and large bandgap of most natural photoferroelectric materials lead to low electron/hole mobility and limit the realization of technologically practical devices. Antimony sulpho-iodide (SbSI) is a photoferroelectric material which is expected to have high electron/hole mobility in the ferroelectric state due to its non-local band dispersion and narrow bandgap. However, SbSI exhibits the paraelectric state close to room temperature. In this report, as a proof of concept, we explore the possibility to stabilize the SbSI ferroelectric phase above room temperature via mechanical strain engineering. We synthesized thin low-dimensional crystals of SbSI by chemical vapor deposition, confirmed its crystal structure with electron diffraction, studied its optical properties via photoluminescence spectroscopy and time-resolved photoluminescence spectroscopy, and probed its phase transition using temperature-dependent steady-state photoluminescence spectroscopy. We found that introducing external mechanical strain to these low-dimensional crystals may lead to an increase in their Curie temperature (by ˜60 K), derived by the strain-modified optical phase transition in SbSI and quantified by Kern formulation and Landau theory. The study suggests that strain engineering could be an effective way to stabilize the ferroelectric phase of SbSI at above room temperature, providing a solution enabling its application for technologically useful photoferroelectric devices.

High-Temperature Coatings Offer Energy Savings

NASA Technical Reports Server (NTRS)

2012-01-01

The U.S. X-Plane Program included the first-of-its-kind research in aerodynamics and astronautics with experimental vehicles, including the first aircraft to break the sound barrier; the first aircraft to fly in excess of 100,000, then 200,000, and then 300,000 feet; and the first aircraft to fly at three, four, five, and then six times the speed of sound. During the 1990s, NASA started developing a new thermal protection material to test on the X-33 and X-34 supersonic aircraft. The X-33 was intended to demonstrate the technologies needed for a new reusable launch vehicle and was projected to reach an altitude of approximately 50 miles and speeds of more than Mach 11. The X-34, a small, reusable technology demonstrator for a launch vehicle, was intended to reach an altitude of 250,000 feet and fly at speeds of Mach 8. As a result of its research and development efforts, NASA s Ames Research Center invented the Protective Ceramic Coating Material (PCCM). Applied to a surface, the thin, lightweight coating could protect the material underneath from extreme temperatures. The capability of the technology came from its emissivity, which radiated heat away from the surface it covered, thereby decreasing the amount of heat transferred to the underlying material. PCCM not only increased the capability of materials to withstand higher temperatures, it also exhibited impressive thermal shock, vibration, and acoustic performance. In addition, it proved to be resistant to abrasion and mechanical damage and was also environmentally safe, due to it being water-based and containing no solvents. Even though funding for the X-33 and X-34 ended in 2001, PCCM continued on a path of innovation.

Research and application of self - propagating welding technology

NASA Astrophysics Data System (ADS)

Ma, Yunhe; Li, Zhizun; Wang, Jianjiang; Sun, Liming

2018-04-01

Self-propagating welding is an important application area of self-propagating high-temperature synthesis technology (SHS technology), suitable for special environment and special materials welding. This paper briefly introduces the principle of self - propagating welding and its technical characteristics, and briefly summarizes the current research and application of SHS welding around three aspects of thin film welding, welding of refractory welding and emergency welding of battlefield.

Thin Film Physical Sensor Instrumentation Research and Development at NASA Glenn Research Center

NASA Technical Reports Server (NTRS)

Wrbanek, John D.; Fralick, Gustave C.

2006-01-01

A range of thin film sensor technology has been demonstrated enabling measurement of multiple parameters either individually or in sensor arrays including temperature, strain, heat flux, and flow. Multiple techniques exist for refractory thin film fabrication, fabrication and integration on complex surfaces and multilayered thin film insulation. Leveraging expertise in thin films and high temperature materials, investigations for the applications of thin film ceramic sensors has begun. The current challenges of instrumentation technology are to further develop systems packaging and component testing of specialized sensors, further develop instrumentation techniques on complex surfaces, improve sensor durability, and to address needs for extreme temperature applications. The technology research and development ongoing at NASA Glenn for applications to future launch vehicles, space vehicles, and ground systems is outlined.

Engineering Materials for Very High Temperatures: An ONRL Workshop

DTIC Science & Technology

1988-08-29

solving various pro- blems related to high temperature applications in which thermostructural ( turbojet and motor engines) or special (electromagnetic wave...the carbon (glassy carbon, polycrystalline gra- phite, pyrolytic carbon...) and mainly upon the temperature range of use. For the 1000-20000C...Bundesministerium fir Forschung und Technologie, Federal Ministry for Research and Technology), no doubt scared by the oil crisis and encouraged by the activity

Annual Fuze Conference and Munitions Technology Symposium VI (43rd)

DTIC Science & Technology

1999-04-07

part manufacture and assembly and identify the parameters that we must control through production. Analyzing the coefficients of variation and the...processing energetic materials. The extruder is equipped with four independent temperature control zones, segmented screws, a jacketed die block capable of...and has vacuum capability. Data monitoring capabilities include melt temperature and pressure, torque, screw speed, and temperatures in all of the

Heat Treatment Used to Strengthen Enabling Coating Technology for Oil-Free Turbomachinery

NASA Technical Reports Server (NTRS)

Edmonds, Brian J.; DellaCorte, Christopher

2002-01-01

The PS304 high-temperature solid lubricant coating is a key enabling technology for Oil- Free turbomachinery propulsion and power systems. Breakthroughs in the performance of advanced foil air bearings and improvements in computer-based finite element modeling techniques are the key technologies enabling the development of Oil-Free aircraft engines being pursued by the Oil-Free Turbomachinery team at the NASA Glenn Research Center. PS304 is a plasma spray coating applied to the surface of shafts operating against foil air bearings or in any other component requiring solid lubrication at high temperatures, where conventional materials such as graphite cannot function.

Affordable Manufacturing Technologies Being Developed for Actively Cooled Ceramic Components

NASA Technical Reports Server (NTRS)

Bhatt, Ramakrishna T.

1999-01-01

Efforts to improve the performance of modern gas turbine engines have imposed increasing service temperature demands on structural materials. Through active cooling, the useful temperature range of nickel-base superalloys in current gas turbine engines has been extended, but the margin for further improvement appears modest. Because of their low density, high-temperature strength, and high thermal conductivity, in situ toughened silicon nitride ceramics have received a great deal of attention for cooled structures. However, high processing costs have proven to be a major obstacle to their widespread application. Advanced rapid prototyping technology, which is developing rapidly, offers the possibility of an affordable manufacturing approach.

Combined caloric effects in a multiferroic Ni-Mn-Ga alloy with broad refrigeration temperature region

NASA Astrophysics Data System (ADS)

Hu, Yong; Li, Zongbin; Yang, Bo; Qian, Suxin; Gan, Weimin; Gong, Yuanyuan; Li, Yang; Zhao, Dewei; Liu, Jian; Zhao, Xiang; Zuo, Liang; Wang, Dunhui; Du, Youwei

2017-04-01

Solid-state refrigeration based on the caloric effects is promising to replace the traditional vapor-compressing refrigeration technology due to environmental protection and high efficiency. However, the narrow working temperature region has hindered the application of these refrigeration technologies. In this paper, we propose a method of combined caloric, through which a broad refrigeration region can be realized in a multiferroic alloy, Ni-Mn-Ga, by combining its elastocaloric and magnetocaloric effects. Moreover, the materials' efficiency of elastocaloric effect has been greatly improved in our sample. These results illuminate a promising way to use multiferroic alloys for refrigeration with a broad refrigeration temperature region.

High-Temperature Electronics: A Role for Wide Bandgap Semiconductors?

NASA Technical Reports Server (NTRS)

Neudeck, Philip G.; Okojie, Robert S.; Chen, Liang-Yu

2002-01-01

It is increasingly recognized that semiconductor based electronics that can function at ambient temperatures higher than 150 C without external cooling could greatly benefit a variety of important applications, especially-in the automotive, aerospace, and energy production industries. The fact that wide bandgap semiconductors are capable of electronic functionality at much higher temperatures than silicon has partially fueled their development, particularly in the case of SiC. It appears unlikely that wide bandgap semiconductor devices will find much use in low-power transistor applications until the ambient temperature exceeds approximately 300 C, as commercially available silicon and silicon-on-insulator technologies are already satisfying requirements for digital and analog very large scale integrated circuits in this temperature range. However, practical operation of silicon power devices at ambient temperatures above 200 C appears problematic, as self-heating at higher power levels results in high internal junction temperatures and leakages. Thus, most electronic subsystems that simultaneously require high-temperature and high-power operation will necessarily be realized using wide bandgap devices, once the technology for realizing these devices become sufficiently developed that they become widely available. Technological challenges impeding the realization of beneficial wide bandgap high ambient temperature electronics, including material growth, contacts, and packaging, are briefly discussed.

Correlation of microstructure and thermo-mechanical properties of a novel hydrogen transport membrane

NASA Astrophysics Data System (ADS)

Zhang, Yongjun

A key part of the FutureGen concept is to support the production of hydrogen to fuel a "hydrogen economy," with the use of clean burning hydrogen in power-producing fuel cells, as well as for use as a transportation fuel. One of the key technical barriers to FutureGen deployment is reliable and efficient hydrogen separation technology. Most Hydrogen Transport Membrane (HTM) research currently focuses on separation technology and hydrogen flux characterization. No significant work has been performed on thermo-mechanical properties of HTMs. The objective of the thesis is to understand the structure-property correlation of HTM and to characterize (1) thermo mechanical properties under different reducing environments and thermal cycles (thermal shock), and (2) evaluate the stability of the novel HTM material. A novel HTM cermet bulk sample was characterized for its physical and mechanical properties at both room temperature and at elevated temperature up to 1000°C. Micro-structural properties and residual stresses were evaluated in order to understand the changing mechanism of the microstructure and its effects on the mechanical properties of materials. A correlation of the microstructural and thermo mechanical properties of the HTM system was established for both HTM and the substrate material. Mechanical properties of both selected structural ceramics and the novel HTM cermet bulk sample are affected mainly by porosity and microstructural features, such as grain size and pore size-distribution. The Young's Modulus (E-value) is positively correlated to the flexural strength for materials with similar crystallographic structure. However, for different crystallographic materials, physical properties are independent of mechanical properties. Microstructural properties, particularly, grain size and crystallographic structure, and thermodynamic properties are the main factors affecting the mechanical properties at both room and high temperatures. The HTM cermet behaves more like an elastic material at room temperature and as a ductile material at temperature above 850°C. The oxidation and the plasticity of Pd phase mainly affected the mechanical properties of HTM cermet at high temperature, also as a result of thermal cycling. Residual stress induced in the HTM by thermo cycles also plays a very critical role in defining the thermo-mechanical properties.

High Temperature Joining and Characterization of Joint Properties in Silicon Carbide-Based Composite Materials

NASA Technical Reports Server (NTRS)

Halbig, Michael C.; Singh, Mrityunjay

2015-01-01

Advanced silicon carbide-based ceramics and composites are being developed for a wide variety of high temperature extreme environment applications. Robust high temperature joining and integration technologies are enabling for the fabrication and manufacturing of large and complex shaped components. The development of a new joining approach called SET (Single-step Elevated Temperature) joining will be described along with the overview of previously developed joining approaches including high temperature brazing, ARCJoinT (Affordable, Robust Ceramic Joining Technology), diffusion bonding, and REABOND (Refractory Eutectic Assisted Bonding). Unlike other approaches, SET joining does not have any lower temperature phases and will therefore have a use temperature above 1315C. Optimization of the composition for full conversion to silicon carbide will be discussed. The goal is to find a composition with no remaining carbon or free silicon. Green tape interlayers were developed for joining. Microstructural analysis and preliminary mechanical tests of the joints will be presented.

Calibration of non-contact ultrasound as an online sensor for wood characterization: Effects of temperature, moisture, and scanning direction

NASA Astrophysics Data System (ADS)

Vun, R. Y.; Hoover, K.; Janowiak, J.; Bhardwaj, M.

2008-01-01

Numerous handheld moisture meters are available for measuring moisture levels of wood and building materials for a vast range of quality control and moisture diagnosis applications. However, many methods currently available require physical contact of a probe with the test material to operate. The contact requirement of such devices has limited applications for these purposes. There is a tremendous demand for dynamic online quality assessment of in-process materials for moisture content (MC) measurements. In this paper, a non-destructive non-contact ultrasound technology was used to evaluate the effects of increasing temperature in two MC levels and of increasing MC in lumber. The results show that the ultrasonic absolute transmittance and velocity parameters are directly correlated very well (R2≥0.87) with temperature for the two moisture levels in wood. At constant temperature, however, the velocity is inversely correlated with MC. It was also found that the distribution of MC along the length is marginally insignificant to both ultrasonic measurements. The transmittance measurement along the orthogonal thickness direction is insignificant above the fiber saturation MC; similarly, the velocity measurement is marginally insignificant. The study concludes a positive correlation and a good fit for this technology to advance into the development of an automated device for determining wood moisture levels, which will in turn be used to control the dynamics of wood drying/sterilization processes. Further calibration research is recommended to ascertain the constraints and limitations of the technology to specific wood species and dimension.

High-Temperature Modal Survey of a Hot-Structure Control Surface

NASA Technical Reports Server (NTRS)

Spivey, Natalie Dawn

2010-01-01

Ground vibration tests or modal surveys are routinely conducted for supporting flutter analysis for subsonic and supersonic vehicles; however, for hypersonic vehicle applications, thermoelastic vibration testing techniques are not well established and are not routinely performed for supporting hypersonic flutter analysis. New high-temperature material systems, fabrication technologies and high-temperature sensors expand the opportunities to develop advanced techniques for performing ground vibration tests at elevated temperatures. High-temperature materials have the unique property of increasing in stiffness when heated. When these materials are incorporated into a hot-structure, which includes metallic components that decrease in stiffness with increasing temperature, the interaction between the two materials systems needs to be understood because that interaction could ultimately affect the hypersonic flutter analysis. Performing a high-temperature modal survey will expand the research database for hypersonics and will help build upon the understanding of the dual material interaction. This paper will discuss the vibration testing of the Carbon-Silicon Carbide Ruddervator Subcomponent Test Article which is a truncated version of the full-scale X-37 hot-structure control surface. In order to define the modal characteristics of the test article during the elevated-temperature modal survey, two series of room-temperature modal test configurations had to be performed. The room-temperature test series included one with the test article suspended from a bungee cord (free-free) and the second with it mounted on the strongback (fixed boundary condition) in NASA Dryden's Flight Loads Lab large nitrogen test chamber.

Review on the EFDA programme on tungsten materials technology and science

NASA Astrophysics Data System (ADS)

Rieth, M.; Boutard, J. L.; Dudarev, S. L.; Ahlgren, T.; Antusch, S.; Baluc, N.; Barthe, M.-F.; Becquart, C. S.; Ciupinski, L.; Correia, J. B.; Domain, C.; Fikar, J.; Fortuna, E.; Fu, C.-C.; Gaganidze, E.; Galán, T. L.; García-Rosales, C.; Gludovatz, B.; Greuner, H.; Heinola, K.; Holstein, N.; Juslin, N.; Koch, F.; Krauss, W.; Kurzydlowski, K. J.; Linke, J.; Linsmeier, Ch.; Luzginova, N.; Maier, H.; Martínez, M. S.; Missiaen, J. M.; Muhammed, M.; Muñoz, A.; Muzyk, M.; Nordlund, K.; Nguyen-Manh, D.; Norajitra, P.; Opschoor, J.; Pintsuk, G.; Pippan, R.; Ritz, G.; Romaner, L.; Rupp, D.; Schäublin, R.; Schlosser, J.; Uytdenhouwen, I.; van der Laan, J. G.; Veleva, L.; Ventelon, L.; Wahlberg, S.; Willaime, F.; Wurster, S.; Yar, M. A.

2011-10-01

All the recent DEMO design studies for helium cooled divertors utilize tungsten materials and alloys, mainly due to their high temperature strength, good thermal conductivity, low erosion, and comparably low activation under neutron irradiation. The long-term objective of the EFDA fusion materials programme is to develop structural as well as armor materials in combination with the necessary production and fabrication technologies for future divertor concepts. The programmatic roadmap is structured into four engineering research lines which comprise fabrication process development, structural material development, armor material optimization, and irradiation performance testing, which are complemented by a fundamental research programme on "Materials Science and Modeling". This paper presents the current research status of the EFDA experimental and testing investigations, and gives a detailed overview of the latest results on fabrication, joining, high heat flux testing, plasticity, modeling, and validation experiments.

High temperature, harsh environment sensors for advanced power generation systems

NASA Astrophysics Data System (ADS)

Ohodnicki, P. R.; Credle, S.; Buric, M.; Lewis, R.; Seachman, S.

2015-05-01

One mission of the Crosscutting Technology Research program at the National Energy Technology Laboratory is to develop a suite of sensors and controls technologies that will ultimately increase efficiencies of existing fossil-fuel fired power plants and enable a new generation of more efficient and lower emission power generation technologies. The program seeks to accomplish this mission through soliciting, managing, and monitoring a broad range of projects both internal and external to the laboratory which span sensor material and device development, energy harvesting and wireless telemetry methodologies, and advanced controls algorithms and approaches. A particular emphasis is placed upon harsh environment sensing for compatibility with high temperature, erosive, corrosive, and highly reducing or oxidizing environments associated with large-scale centralized power generation. An overview of the full sensors and controls portfolio is presented and a selected set of current and recent research successes and on-going projects are highlighted. A more detailed emphasis will be placed on an overview of the current research thrusts and successes of the in-house sensor material and device research efforts that have been established to support the program.

Sputtering and ion plating for aerospace applications

NASA Technical Reports Server (NTRS)

Spalvins, T.

1981-01-01

Sputtering and ion plating technologies are reviewed in terms of their potential and present uses in the aerospace industry. Sputtering offers great universality and flexibility in depositing any material or in the synthesis of new ones. The sputter deposition process has two areas of interest: thin film and fabrication technology. Thin film sputtering technology is primarily used for aerospace mechanical components to reduce friction, wear, erosion, corrosion, high temperature oxidation, diffusion and fatigue, and also to sputter-construct temperature and strain sensors for aircraft engines. Sputter fabrication is used in intricate aircraft component manufacturing. Ion plating applications are discussed in terms of the high energy evaporant flux and the high throwing power. Excellent adherence and 3 dimensional coverage are the primary attributes of this technology.

Sputtering and ion plating for aerospace applications

NASA Technical Reports Server (NTRS)

Spalvins, T.

1981-01-01

Sputtering and ion plating technologies are reviewed in terms of their potential and present uses in the aerospace industry. Sputtering offers great universality and flexibility in depositing any material or in the synthesis of new ones. The sputter deposition process has two areas of interest: thin film and fabrication technology. Thin film sputtering technology is primarily used for aerospace mechanical components to reduce friction, wear, erosion, corrosion, high temperature oxidation, diffusion and fatigue, and also to sputter-construct temperature and strain sensors for aircraft engines. Sputter fabrication is used in intricate aircraft component manufacturing. Ion plating applications are discussed in terms of the high energy evaporant flux and the high throwing power. Excellent adherence and 3-dimensional coverage are the primary attributes of this technology.

A wireless passive pressure microsensor fabricated in HTCC MEMS technology for harsh environments.

PubMed

Tan, Qiulin; Kang, Hao; Xiong, Jijun; Qin, Li; Zhang, Wendong; Li, Chen; Ding, Liqiong; Zhang, Xiansheng; Yang, Mingliang

2013-08-02

A wireless passive high-temperature pressure sensor without evacuation channel fabricated in high-temperature co-fired ceramics (HTCC) technology is proposed. The properties of the HTCC material ensure the sensor can be applied in harsh environments. The sensor without evacuation channel can be completely gastight. The wireless data is obtained with a reader antenna by mutual inductance coupling. Experimental systems are designed to obtain the frequency-pressure characteristic, frequency-temperature characteristic and coupling distance. Experimental results show that the sensor can be coupled with an antenna at 600 °C and max distance of 2.8 cm at room temperature. The senor sensitivity is about 860 Hz/bar and hysteresis error and repeatability error are quite low.

Heating and Cooling Efficiency for Homes

NASA Technical Reports Server (NTRS)

2004-01-01

Over 40 years ago, NASA developed Radiant Barrier technology to protect astronauts in the Apollo Program from temperatures that ranged from 250 F above to 400 F below zero Fahrenheit. This feat in temperature control technology enabled the astronauts to work inside the Apollo Command Module wearing short-sleeve shirts, with temperatures similar to those of a regular business office. The Radiant Barrier has been applied to virtually all spacecraft since then, including unmanned spacecraft with delicate instruments that need protection from temperature extremes. It is also applied to the astronauts space suits, protecting them during space walks. Made of aluminized polymer film, the Radiant Barrier both bars and lets in heat to maintain a consistent temperature in an environment where ordinary insulation methods will not suffice. The aluminization of the material provides a reflective surface that keeps more than 95 percent of the radiated energy in space from reaching the spacecraft s interior. In space suits, the thin and flexible material reflects the astronauts body heat back to them for warmth, while at the same time reflecting the sun s radiation away from them to keep them cool. Using conventional insulation, a space suit would have required a 7-foot-thick protective layer.

Structures and materials technology issues for reusable launch vehicles

NASA Technical Reports Server (NTRS)

Dixon, S. C.; Tenney, D. R.; Rummler, D. R.; Wieting, A. R.; Bader, R. M.

1985-01-01

Projected space missions for both civil and defense needs require significant improvements in structures and materials technology for reusable launch vehicles: reductions in structural weight compared to the Space Shuttle Orbiter of up to 25% or more, a possible factor of 5 or more increase in mission life, increases in maximum use temperature of the external surface, reusable containment of cryogenic hydrogen and oxygen, significant reductions in operational costs, and possibly less lead time between technology readiness and initial operational capability. In addition, there is increasing interest in hypersonic airbreathing propulsion for launch and transmospheric vehicles, and such systems require regeneratively cooled structure. The technology issues are addressed, giving brief assessments of the state-of-the-art and proposed activities to meet the technology requirements in a timely manner.

Prepreg and Melt Infiltration Technology Developed for Affordable, Robust Manufacturing of Ceramic Matrix Composites

NASA Technical Reports Server (NTRS)

Singh, Mrityunjay; Petko, Jeannie F.

2004-01-01

Affordable fiber-reinforced ceramic matrix composites with multifunctional properties are critically needed for high-temperature aerospace and space transportation applications. These materials have various applications in advanced high-efficiency and high-performance engines, airframe and propulsion components for next-generation launch vehicles, and components for land-based systems. A number of these applications require materials with specific functional characteristics: for example, thick component, hybrid layups for environmental durability and stress management, and self-healing and smart composite matrices. At present, with limited success and very high cost, traditional composite fabrication technologies have been utilized to manufacture some large, complex-shape components of these materials. However, many challenges still remain in developing affordable, robust, and flexible manufacturing technologies for large, complex-shape components with multifunctional properties. The prepreg and melt infiltration (PREMI) technology provides an affordable and robust manufacturing route for low-cost, large-scale production of multifunctional ceramic composite components.

High-Temperature Modal Survey of a Hot-Structure Control Surface

NASA Technical Reports Server (NTRS)

Spivey, Natalie D.

2011-01-01

Ground vibration tests are routinely conducted for supporting flutter analysis for subsonic and supersonic vehicles; however, for hypersonic vehicles, thermoelastic vibration testing techniques are neither well established nor routinely performed. New high-temperature material systems, fabrication technologies and high-temperature sensors expand the opportunities to develop advanced techniques for performing ground vibration tests at elevated temperatures. When high-temperature materials, which increase in stiffness when heated, are incorporated into a hot-structure that contains metallic components that decrease in stiffness when heated, the interaction between those materials can affect the hypersonic flutter analysis. A high-temperature modal survey will expand the research database for hypersonics and improve the understanding of this dual-material interaction. This report discusses the vibration testing of the carbon-silicon carbide Ruddervator Subcomponent Test Article, which is a truncated version of a full-scale hot-structure control surface. Two series of room-temperature modal test configurations were performed in order to define the modal characteristics of the test article during the elevated-temperature modal survey: one with the test article suspended from a bungee cord (free-free) and the second with it mounted on the strongback (fixed boundary). Testing was performed in the NASA Dryden Flight Research Center Flight Loads Laboratory Large Nitrogen Test Chamber.

Effects of radiation and temperature on gallium nitride (GaN) metal-semiconductor-metal ultraviolet photodetectors

NASA Astrophysics Data System (ADS)

Chiamori, Heather C.; Angadi, Chetan; Suria, Ateeq; Shankar, Ashwin; Hou, Minmin; Bhattacharya, Sharmila; Senesky, Debbie G.

2014-06-01

The development of radiation-hardened, temperature-tolerant materials, sensors and electronics will enable lightweight space sub-systems (reduced packaging requirements) with increased operation lifetimes in extreme harsh environments such as those encountered during space exploration. Gallium nitride (GaN) is a ceramic, semiconductor material stable within high-radiation, high-temperature and chemically corrosive environments due to its wide bandgap (3.4 eV). These material properties can be leveraged for ultraviolet (UV) wavelength photodetection. In this paper, current results of GaN metal-semiconductor-metal (MSM) UV photodetectors behavior after irradiation up to 50 krad and temperatures of 15°C to 150°C is presented. These initial results indicate that GaN-based sensors can provide robust operation within extreme harsh environments. Future directions for GaN-based photodetector technology for down-hole, automotive and space exploration applications are also discussed.

Materials Needs for Future In-Space Propulsion Systems

NASA Technical Reports Server (NTRS)

Johnson, Les

2006-01-01

NASA's In-Space Propulsion Technology Project is developing the next generation of in-space propulsion systems in support of robotic exploration missions throughout the solar system. The propulsion technologies being developed are non-traditional and have stressing materials performance requirements. Earth-storable bipropellant performance is constrained by temperature limitations of the columbium used in the chamber. Iridium/rhenium (Ir/Re) is now available and has been implemented in initial versions of Earth- Storable rockets with specific impulses about 10 seconds higher than columbium rocket chambers. New chamber fabrication methods that improve process and performance of Ir/Re and other promising material systems are needed. The solar sail is a propellantless propulsion system that gains momentum by reflecting sunlight. The sails need to be very large in area (from 10000 sq m up to 62500 sq m) yet be very lightweight in order to achieve adequate accelerations for realistic mission times. Lightweight materials that can be manufactured in thicknesses of less than 1 micron and that are not harmed by the space environment are desired. Blunt Body Aerocapture uses aerodynamic drag to slow an approaching spacecraft and insert it into a science orbit around any planet or moon with an atmosphere. The spacecraft is enclosed by a rigid aeroshell that protects it from the entry heating and aerodynamic environment. Lightweight, high-temperature structural systems, adhesives, insulators, and ablatives are key components for improving aeroshell efficiencies at heating rates of 1000-2000 W/sq cm and beyond. Inflatable decelerators in the forms of ballutes and inflatable aeroshells will use flexible polymeric thin film materials, high temperature fabrics, and structural adhesives. The inflatable systems will be tightly packaged during cruise and will be inflated prior to entry interface at the destination. Materials must maintain strength and flexibility while packaged at cold temperatures (-100 C) for up to 10 years and then withstand the high temperatures (500 C) encountered during aerocapture.

Beta-manganese dioxide nanorods for sufficient high-temperature electromagnetic interference shielding in X-band

NASA Astrophysics Data System (ADS)

Song, Wei-Li; Cao, Mao-Sheng; Hou, Zhi-Ling; Lu, Ming-Ming; Wang, Chan-Yuan; Yuan, Jie; Fan, Li-Zhen

2014-09-01

As the development of electronic and communication technology, electromagnetic interference (EMI) shielding and attenuation is an effective strategy to ensure the operation of the electronic devices. Among the materials for high-performance shielding in aerospace industry and related high-temperature working environment, the thermally stable metal oxide semiconductors with narrow band gap are promising candidates. In this work, beta-manganese dioxide ( β-MnO2) nanorods were synthesized by a hydrothermal method. The bulk materials of the β-MnO2 were fabricated to evaluate the EMI shielding performance in the temperature range of 20-500 °C between 8.2 and 12.4 GHz (X-band). To understand the mechanisms of high-temperature EMI shielding, the contribution of reflection and absorption to EMI shielding was discussed based on temperature-dependent electrical properties and complex permittivity. Highly sufficient shielding effectiveness greater than 20 dB was observed over all the investigated range, suggesting β-MnO2 nanorods as promising candidates for high-temperature EMI shielding. The results have also established a platform to develop high-temperature EMI shielding materials based on nanoscale semiconductors.

Encapsulation of High Temperature Phase Change Materials for Thermal Energy Storage

NASA Astrophysics Data System (ADS)

Nath, Rupa

Thermal energy storage is a major contributor to bridge the gap between energy demand (consumption) and energy production (supply) by concentrating solar power. The utilization of high latent heat storage capability of phase change materials is one of the keys to an efficient way to store thermal energy. However, some of the limitations of the existing technology are the high volumetric expansion and low thermal conductivity of phase change materials (PCMs), low energy density, low operation temperatures and high cost. The present work deals with encapsulated PCM system, which operates at temperatures above 500°C and takes advantage of the heat transfer modes at such high temperatures to overcome the aforementioned limitations of PCMs. Encapsulation with sodium silicate coating on preformed PCM pellets were investigated. A low cost, high temperature metal, carbon steel has been used as a capsule for PCMs with a melting point above 500° C. Sodium silicate and high temperature paints were used for oxidation protection of steel at high temperatures. The emissivity of the coatings to enhance heat transfer was investigated.

Candidate materials for advanced fire-resistant photovoltaic modules

NASA Technical Reports Server (NTRS)

Sugimura, R. S.; Otth, D. H.; Ross, R. G., Jr.; Arnett, J. C.; Samuelson, G.

1985-01-01

A cooperative, cost-sharing research effort to develop a technology base required to construct fire-ratable photovoltaic modules has resulted in the identification of several high-temperature, back-surface candidate materials capable of raising the fire-resistance of modules using hydrocarbon encapsulants to Class A and B levels. Advanced experimental module configurations have been developed using back surfaces consisting of Kapton, Tedlar laminates, metal-foils, and fiberglass materials with high-temperature coatings. Test results (October 1984; March 1985; May 1985; and October 1985) indicate that several of these advanced module configurations are capable of achieving Class B fire-resistance levels, while a few configurations can achieve Class A levels. The paper summarizes activities to date, discussing flammability failure mechanisms, time-temperature profiles, and results of Block V environmental exposure tests of a candidate material suitable for both Class B and Class A fire-resistance levels.

Separators - Technology review: Ceramic based separators for secondary batteries

DOE Office of Scientific and Technical Information (OSTI.GOV)

Nestler, Tina; Schmid, Robert; Münchgesang, Wolfram

Besides a continuous increase of the worldwide use of electricity, the electric energy storage technology market is a growing sector. At the latest since the German energy transition ('Energiewende') was announced, technological solutions for the storage of renewable energy have been intensively studied. Storage technologies in various forms are commercially available. A widespread technology is the electrochemical cell. Here the cost per kWh, e. g. determined by energy density, production process and cycle life, is of main interest. Commonly, an electrochemical cell consists of an anode and a cathode that are separated by an ion permeable or ion conductive membranemore » - the separator - as one of the main components. Many applications use polymeric separators whose pores are filled with liquid electrolyte, providing high power densities. However, problems arise from different failure mechanisms during cell operation, which can affect the integrity and functionality of these separators. In the case of excessive heating or mechanical damage, the polymeric separators become an incalculable security risk. Furthermore, the growth of metallic dendrites between the electrodes leads to unwanted short circuits. In order to minimize these risks, temperature stable and non-flammable ceramic particles can be added, forming so-called composite separators. Full ceramic separators, in turn, are currently commercially used only for high-temperature operation systems, due to their comparably low ion conductivity at room temperature. However, as security and lifetime demands increase, these materials turn into focus also for future room temperature applications. Hence, growing research effort is being spent on the improvement of the ion conductivity of these ceramic solid electrolyte materials, acting as separator and electrolyte at the same time. Starting with a short overview of available separator technologies and the separator market, this review focuses on ceramic-based separators. Two prominent examples, the lithium-ion and sodium-sulfur battery, are described to show the current stage of development. New routes are presented as promising technologies for safe and long-life electrochemical storage cells.« less

Separators - Technology review: Ceramic based separators for secondary batteries

NASA Astrophysics Data System (ADS)

Nestler, Tina; Schmid, Robert; Münchgesang, Wolfram; Bazhenov, Vasilii; Schilm, Jochen; Leisegang, Tilmann; Meyer, Dirk C.

2014-06-01

Besides a continuous increase of the worldwide use of electricity, the electric energy storage technology market is a growing sector. At the latest since the German energy transition ("Energiewende") was announced, technological solutions for the storage of renewable energy have been intensively studied. Storage technologies in various forms are commercially available. A widespread technology is the electrochemical cell. Here the cost per kWh, e. g. determined by energy density, production process and cycle life, is of main interest. Commonly, an electrochemical cell consists of an anode and a cathode that are separated by an ion permeable or ion conductive membrane - the separator - as one of the main components. Many applications use polymeric separators whose pores are filled with liquid electrolyte, providing high power densities. However, problems arise from different failure mechanisms during cell operation, which can affect the integrity and functionality of these separators. In the case of excessive heating or mechanical damage, the polymeric separators become an incalculable security risk. Furthermore, the growth of metallic dendrites between the electrodes leads to unwanted short circuits. In order to minimize these risks, temperature stable and non-flammable ceramic particles can be added, forming so-called composite separators. Full ceramic separators, in turn, are currently commercially used only for high-temperature operation systems, due to their comparably low ion conductivity at room temperature. However, as security and lifetime demands increase, these materials turn into focus also for future room temperature applications. Hence, growing research effort is being spent on the improvement of the ion conductivity of these ceramic solid electrolyte materials, acting as separator and electrolyte at the same time. Starting with a short overview of available separator technologies and the separator market, this review focuses on ceramic-based separators. Two prominent examples, the lithium-ion and sodium-sulfur battery, are described to show the current stage of development. New routes are presented as promising technologies for safe and long-life electrochemical storage cells.

Threshold temperature optical fibre sensors

NASA Astrophysics Data System (ADS)

Stasiewicz, K. A.; Musial, J. E.

2016-12-01

This paper presents a new approach to manufacture a threshold temperature sensor based on a biconical optical fibre taper. The presented sensor employs the influence of variable state of concentration of some isotropic materials like wax or paraffin. Application of the above- mentioned materials is an attempt to prove that there is a possibility to obtain a low-cost, repeatable and smart sensor working as an in-line element. Optical fibre taper was obtained from a standard single mode fibre (SMF28®) by using a low pressure gas burner technique. The diameter of the manufactured tapers was 6.0 ± 0.5 μm with the length of elongation equal to 30.50 ± 0.16 mm. The applied technology allowed to produce tapers with the losses of 0.183 ± 0.015 dB. Application of materials with different temperature transition points made it possible to obtain the threshold work at the temperatures connected directly with their conversion temperature. External materials at the temperatures above their melting points do not influence the propagation losses. For each of them two types of the protection area and position of the optical fibre taper were applied.

Estimating the stability of electrical conductivity of filled polymers under the influence of negative temperatures

NASA Astrophysics Data System (ADS)

Minakova, N. N.; Ushakov, V. Ya.

2017-12-01

One of the key problems in modern materials technology is synthesis of materials for electrotechnical devices capable of operating under severe conditions. Electrical and power engineering, in particular, demands for electrically conductive composite materials operating at high and low temperatures, various mechanical loads, electric fields, etc. Chaotic arrangement of electrically conductive component in the matrix and its structural and geometrical inhomogeneity can increase the local electric and thermal energy flux densities up to critical values even when their average values remain moderate. Elastomers filled with technical carbon being a promising component for electrotechnical devices was chosen as an object of study.

Salt materials testing for a spacecraft adiabatic demagnetization refrigerator

NASA Technical Reports Server (NTRS)

Savage, M. L.; Kittel, P.; Roellig, T.

1990-01-01

As part of a technology development effort to qualify adiabatic demagnetization refrigerators for use in a NASA spacecraft, such as the Space Infrared Telescope Facility, a study of low temperature characteristics, heat capacity and resistance to dehydration was conducted for different salt materials. This report includes results of testing with cerrous metaphosphate, several synthetic rubies, and chromic potassium alum (CPA). Preliminary results show that CPA may be suitable for long-term spacecraft use, provided that the salt is property encapsulated. Methods of salt pill construction and testing for all materials are discussed, as well as reliability tests. Also, the temperature regulation scheme and the test cryostat design are briefly discussed.

JPRS Report, Science & Technology, Europe & Latin America.

DTIC Science & Technology

1987-08-28

Rhine Westfalia) has recently agreed to purchase a new high performance laser which is supposed to • prepare the ground for new processing and...Transition Temperature Lies Within a Very Limited Area"] [Excerpts] VDI-N, Bochum, 15/5/87— High temperature, high current superconductors with a transition...applications of superconductive materials. Dr Kahn was able to produce a high temperature superconductor with high current flow based on the known oxide

NASA Examines Technology To Fold Aircraft Wings In Flight

NASA Image and Video Library

2018-01-17

NASA conducts a flight test series to investigate the ability of an innovative technology to fold the outer portions of wings in flight as part of the Spanwise Adaptive Wing project, or SAW. Flight tests took place at NASA Armstrong Flight Research Center in California, using a subscale UAV called Prototype Technology-Evaluation Research Aircraft, or PTERA, provided by Area-I. NASA Glenn Research Center in Cleveland developed the alloy material, and worked with Boeing Research & Technology to integrate the material into an actuator. The alloy is triggered by temperature to move the outer portions of wings up or down in flight. The ability to fold wings to the ideal position of various flight conditions may produce several aerodynamic benefits for both subsonic and supersonic aircraft.

An overview of Japanese CELSS research activities

NASA Technical Reports Server (NTRS)

Nitta, Keiji

1987-01-01

Development of Controlled Ecological Life Support System (CELSS) technology is inevitable for future long duration stays of human beings in space, for lunar base construction and for manned Mars flight programs. CELSS functions can be divided into 2 categories, Environmental Control and Material Recycling. Temperature, humidity, total atmospheric pressure and partial pressure of oxygen and carbon dioxide, necessary for all living things, are to be controlled by the environment control function. This function can be performed by technologies already developed and used as the Environment Control Life Support System (ECLSS) of Space Shuttle and Space Station. As for material recycling, matured technologies have not yet been established for fully satisfying the specific metabolic requirements of each living thing including human beings. Therefore, research activities for establishing CELSS technology should be focused on material recycling technologies using biological systems such as plants and animals and physico-chemical systems, for example, a gas recycling system, a water purifying and recycling system and a waste management system. Japanese research activities were conducted and will be continued accordingly.

Review on plasmas in extraordinary media: plasmas in cryogenic conditions and plasmas in supercritical fluids

NASA Astrophysics Data System (ADS)

Stauss, Sven; Muneoka, Hitoshi; Terashima, Kazuo

2018-02-01

Plasma science and technology has enabled advances in very diverse fields: micro- and nanotechnology, chemical synthesis, materials fabrication and, more recently, biotechnology and medicine. While many of the currently employed plasma tools and technologies are very advanced, the types of plasmas used in micro- and nanofabrication pose certain limits, for example, in treating heat-sensitive materials in plasma biotechnology and plasma medicine. Moreover, many physical properties of plasmas encountered in nature, and especially outer space, i.e. very-low-temperature plasmas or plasmas that occur in high-density media, are not very well understood. The present review gives a short account of laboratory plasmas generated under ’extreme’ conditions: at cryogenic temperatures and in supercritical fluids. The fundamental characteristics of these cryogenic plasmas and cryoplasmas, and plasmas in supercritical fluids, especially supercritical fluid plasmas, are presented with their main applications. The research on such exotic plasmas is expected to lead to further understanding of plasma physics and, at the same time, enable new applications in various technological fields.

The development of silicon carbide-based power electronics devices

NASA Astrophysics Data System (ADS)

Hopkins, Richard H.; Perkins, John F.

1995-01-01

In 1989 Westinghouse created an internally funded initiative to develop silicon carbide materials and device technology for a variety of potential commercial and military applications. Westinghouse saw silicon carbide as having the potential for dual use. For space applications, size and weight reductions could be achieved, together with increased reliability. Terrestrially, uses in harsh-temperature environments would be enabled. Theoretically, the physical and electrical properties of silicon carbide were highly promising for high-power, high-temperature, radiation-hardened electronics. However, bulk material with the requisite electronic qualities was not available, and the methods needed to produce a silicon carbide wafer—to fabricate high-quality devices—and to transition these technologies into a commercial product were considered to be a high-risk investment. It was recognized that through a collaborative effort, the CCDS could provide scientific expertise in several areas, thus reducing this risk. These included modeling of structures, electrical contacts, dielectrics, and epitaxial growth. This collaboration has been very successful, with developed technologies being transferred to Westinghouse.

Technological process and optimum design of organic materials vacuum pyrolysis and indium chlorinated separation from waste liquid crystal display panels.

PubMed

Ma, En; Xu, Zhenming

2013-12-15

In this study, a technology process including vacuum pyrolysis and vacuum chlorinated separation was proposed to convert waste liquid crystal display (LCD) panels into useful resources using self-design apparatuses. The suitable pyrolysis temperature and pressure are determined as 300°C and 50 Pa at first. The organic parts of the panels were converted to oil (79.10 wt%) and gas (2.93 wt%). Then the technology of separating indium was optimized by central composite design (CCD) under response surface methodology (RSM). The results indicated the indium recovery ratio was 99.97% when the particle size is less than 0.16 mm, the weight percentage of NH4Cl to glass powder is 50 wt% and temperature is 450°C. The research results show that the organic materials, indium and glass of LCD panel can be recovered during the recovery process efficiently and eco-friendly. Copyright © 2013 Elsevier B.V. All rights reserved.

Preparation and Characteristics of Porous Ceramics by a foaming Technology at Low Temperature

NASA Astrophysics Data System (ADS)

Zhang, H. Q.; Wang, S. P.; Wen, J.; Wu, N.; Xu, S. H.

2017-12-01

Recycling and converting coal gangue and red mud into porous ceramics with good performance is a feasible disposal route. In this present work, porous foam ceramics was prepared using coal gangue and red mud as main raw materials at low sintering temperature, The amount of coal gangue and red mud were up to 70 wt%. To regulate the forming and sintering performance of the product, quartz sands and clay material were added to the formula. The green body was formed by a foaming technology using aluminum powders as foaming agents at room temperature. After foamed, the specimens were dried at 60-80 °C, and then calcined at 1060°C. Effects of concentration of NaOH and amount of aluminum powders on the phase, mechanical properties and microstructure were investigated here. Such study is expected to provide a new utilization route of the coal gangue and red mud, and brings both intensive environmental and economic benefits.

Development of high temperature transport technology for LiCl-KCl eutectic salt in pyroprocessing

DOE Office of Scientific and Technical Information (OSTI.GOV)

Lee, Sung Ho; Lee, Hansoo; Kim, In Tae

The development of high-temperature transport technologies for molten salt is a prerequisite and a key issue in the industrialization of pyro-reprocessing for advanced fuel cycle scenarios. The solution of a molten salt centrifugal pump was discarded because of the high corrosion power of a high temperature molten salt, so the suction pump solution was selected. An apparatus for salt transport experiments by suction was designed and tested using LiC-KCl eutectic salt. The experimental results of lab-scale molten salt transport by suction showed a 99.5% transport rate (ratio of transported salt to total salt) under a vacuum range of 100 mtorrmore » - 10 torr at 500 Celsius degrees. The suction system has been integrated to the PRIDE (pyroprocessing integrated inactive demonstration) facility that is a demonstrator using non-irradiated materials (natural uranium and surrogate materials). The performance of the suction pump for the transport of molten salts has been confirmed.« less

A new lead alloy for automotive batteries operating under high-temperature conditions

NASA Astrophysics Data System (ADS)

Albert, L.; Goguelin, A.; Jullian, E.

The operating conditions of automotive and some industrial batteries are involving increasingly higher temperatures and heavier duty cycles. These place stress on the positive-grid materials which are presently not sufficiently resistant to corrosion and to creep. Conventional lead-calcium-tin-aluminium alloys can usually be optimized by a proper choice of calcium and tin contents for each specific manufacturing technology. With the new requirements of customers and the typical behaviour of these conventional alloys, however, there is no more room for improvement without searching for additional alloying elements. The work reported here shows how the doping of conventional lead-calcium-tin-aluminium alloys with barium improves mechanical properties (tensile strength and creep resistance) and increases corrosion resistance at temperatures between 50 and 75°C. Grid materials prepared by two manufacturing technologies (gravity cast; continuous cast followed by expansion) are investigated. Both the mechanical properties and the corrosion behaviour of the resulting grids are evaluated.

DOE Office of Scientific and Technical Information (OSTI.GOV)

Stewart, Gary

The primary objective of this project was to demonstrate the feasibility and reliability of utilizing high-temperature superconducting (HTS) materials in a Transmission Level Superconducting Fault Current Limiter (SFCL) application. During the project, the type of high-temperature superconducting material used evolved from 1 st generation (1G) BSCCO-2212 melt cast bulk high-temperature superconductors to 2 nd generation (2G) YBCO-based high-temperature superconducting tape. The SFCL employed SuperPower's “Matrix” technology, that offers modular features to enable scale up to transmission voltage levels. The SFCL consists of individual modules that contain elements and parallel inductors that assist in carrying the current during the fault. Amore » number of these modules are arranged in an m x n array to form the current-limiting matrix.« less

Affordable, Robust Ceramic Joining Technology (ARCJoint) Developed

NASA Technical Reports Server (NTRS)

Steele, Gynelle C.

2001-01-01

Affordable, Robust Ceramic Joining Technology (ARCJoint) is a method for joining high temperature- resistant ceramic pieces together, establishing joints that are strong, and allowing joining to be done in the field. This new way of joining allows complex shapes to be formed by joining together geometrically simple shapes. The joining technology at NASA is one of the enabling technologies for the application of silicon-carbide-based ceramic and composite components in demanding and high-temperature applications. The technology is being developed and tested for high-temperature propulsion parts for aerospace use. Commercially, it can be used for joining ceramic pieces used for high temperature applications in the power-generating and chemical industries, as well as in the microelectronics industry. This innovation could yield big payoffs for not only the power-generating industry but also the Silicon Valley chipmakers. This technology, which was developed at the NASA Glenn Research Center by Dr. Mrityunjay Singh, is a two-step process involving first using a paste to join together ceramic pieces and bonding them by heating the joint to 110 to 120 C for between 10 and 20 min. This makes the joint strong enough to be handled for the final joining. Then, a silicon-based substance is applied to the joint and heated to 1400 C for 10 to 15 min. The resulting joint is as strong as the original ceramic material and can withstand the same high temperatures.

Laser beam joining of material combinations for automotive applications

NASA Astrophysics Data System (ADS)

Schubert, Emil; Zerner, Ingo; Sepold, Gerd

1997-08-01

An ideal material for automotive applications would combine the following properties: high corrosion resistance, high strength, high stiffness and not at least a low material price. Today a single material is not able to meet all these requirements. Therefore, in the future different materials will be placed where they meet the requirements best. The result of this consideration is a car body with many different alloys and metals, which have to be joined to one another. BIAS is working on the development of laser based joining technologies for different material combinations, especially for thin sheets used in automotive applications. One result of the research is a joining technology for an aluminum-steel-joint. Using a Nd:YAG laser the problem of brittle intermetallic phases between these materials was overcome. Using suitable temperature-time cycles, elected by a FEM-simulation, the thickness of intermetallic phases was kept below 10 micrometers . This technology was also applied to coated steels, which were joined with different aluminum alloys. Further it is demonstrated that titanium alloys, e.g. used for racing cars, can also be joined with aluminum alloys.

Correlation between some technological parameters and properties of composite material based on recycled tires and polymer binder

NASA Astrophysics Data System (ADS)

Plesuma, Renate; Malers, Laimonis

2015-04-01

The present article is dedicated to the determination of a possible connection between the composition, specific properties of the composite material and molding pressure as an important technological parameter. Apparent density, Shore C hardness, compressive modulus of elasticity and compressive stress at 10% deformation was determined for composite material samples. Definite formation conditions - varying molding pressure conditions at ambient temperature and corresponding relative air humiditywere realized. The results obtained showed a significant effect of molding pressure on the apparent density, mechanical properties of composite material as well as on the compressive stress change at a cyclic mode of loading. Some general regularities were determined - mechanical properties of the composite material, as well as values of Shore C hardness increases with an increase of molding pressure.

A review of nanostructured lithium ion battery materials via low temperature synthesis.

PubMed

Chen, Jiajun

2013-01-01

Nanostructured materials afford us new opportunities to improve the current technology for synthesizing Li ion batteries. Generating nanomaterials with new properties via an inexpensive approach offers a tremendous potential for realizing high performance Li-ion batteries. In this review, I mainly summarize some of the recent progress made, and describe the patents awarded on synthesizing nanostructured cathode materials for these batteries via low temperature wet- chemistry methods. From an economical view, such syntheses, especially hydrothermal synthesis, may offer the opportunities for significantly lowering the cost of manufacturing battery materials, while conferring distinct environmental advantages. Recent advances in in-situ (real time) X-ray diffraction for studying hydrothermal synthesis have great potential for bettering the rational design of advanced lithium-electrode materials. The development of this technique also will be discussed.

Advances in central receivers for concentrating solar applications

DOE Office of Scientific and Technical Information (OSTI.GOV)

Ho, Clifford K.

This paper provides a review of current state-of-the-art commercial central receiver systems and emerging technologies intended to increase the outlet temperature to >700 °C. Research on particle-based, gas-based, and liquid-based receiver designs that can achieve these higher temperatures are discussed. Particle-based technologies include directly irradiated designs (free-falling, obstructed, centrifugal) and enclosed designs (gravity fed, fluidized). New gas-based receivers include micro-channel designs and light-trapping configurations that increase the surface area, heat transfer, and solar absorptance to enable higher fluxes and pressures. Liquid-based receivers and materials that are reviewed include high-temperature halide salts (chlorides and fluorides), carbonate salts, and liquid metals (sodiummore » and lead bismuth). Advantages and challenges associated with each of the technologies and receiver designs are presented.« less

Advances in central receivers for concentrating solar applications

DOE PAGES

Ho, Clifford K.

2017-04-09

This paper provides a review of current state-of-the-art commercial central receiver systems and emerging technologies intended to increase the outlet temperature to >700 °C. Research on particle-based, gas-based, and liquid-based receiver designs that can achieve these higher temperatures are discussed. Particle-based technologies include directly irradiated designs (free-falling, obstructed, centrifugal) and enclosed designs (gravity fed, fluidized). New gas-based receivers include micro-channel designs and light-trapping configurations that increase the surface area, heat transfer, and solar absorptance to enable higher fluxes and pressures. Liquid-based receivers and materials that are reviewed include high-temperature halide salts (chlorides and fluorides), carbonate salts, and liquid metals (sodiummore » and lead bismuth). Advantages and challenges associated with each of the technologies and receiver designs are presented.« less

Wind effect on PV module temperature: Analysis of different techniques for an accurate estimation.

NASA Astrophysics Data System (ADS)

Schwingshackl, Clemens; Petitta, Marcello; Ernst Wagner, Jochen; Belluardo, Giorgio; Moser, David; Castelli, Mariapina; Zebisch, Marc; Tetzlaff, Anke

2013-04-01

In this abstract a study on the influence of wind to model the PV module temperature is presented. This study is carried out in the framework of the PV-Alps INTERREG project in which the potential of different photovoltaic technologies is analysed for alpine regions. The PV module temperature depends on different parameters, such as ambient temperature, irradiance, wind speed and PV technology [1]. In most models, a very simple approach is used, where the PV module temperature is calculated from NOCT (nominal operating cell temperature), ambient temperature and irradiance alone [2]. In this study the influence of wind speed on the PV module temperature was investigated. First, different approaches suggested by various authors were tested [1], [2], [3], [4], [5]. For our analysis, temperature, irradiance and wind data from a PV test facility at the airport Bolzano (South Tyrol, Italy) from the EURAC Institute of Renewable Energies were used. The PV module temperature was calculated with different models and compared to the measured PV module temperature at the single panels. The best results were achieved with the approach suggested by Skoplaki et al. [1]. Preliminary results indicate that for all PV technologies which were tested (monocrystalline, amorphous, microcrystalline and polycrystalline silicon and cadmium telluride), modelled and measured PV module temperatures show a higher agreement (RMSE about 3-4 K) compared to standard approaches in which wind is not considered. For further investigation the in-situ measured wind velocities were replaced with wind data from numerical weather forecast models (ECMWF, reanalysis fields). Our results show that the PV module temperature calculated with wind data from ECMWF is still in very good agreement with the measured one (R² > 0.9 for all technologies). Compared to the previous analysis, we find comparable mean values and an increasing standard deviation. These results open a promising approach for PV module temperature estimation using meteorological parameters. References: [1] Skoplaki, E. et al., 2008: A simple correlation for the operating temperature of photovoltaic modules of arbitrary mounting, Solar Energy Materials & Solar Cells 92, 1393-1402 [2] Skoplaki, E. et al., 2008: Operating temperature of photovoltaic modules: A survey of pertinent correlations, Renewable Energy 34, 23-29 [3] Koehl, M. et al., 2011: Modeling of the nominal operating cell temperature based on outdoor weathering, Solar Energy Materials & Solar Cells 95, 1638-1646 [4] Mattei, M. et al., 2005: Calculation of the polycrystalline PV module temperature using a simple method of energy balance, Renewable Energy 31, 553-567 [5] Kurtz, S. et al.: Evaluation of high-temperature exposure of rack-mounted photovoltaic modules

Thermoelectric Properties of Complex Oxide Heterostructures

NASA Astrophysics Data System (ADS)

Cain, Tyler Andrew

Thermoelectrics are a promising energy conversion technology for power generation and cooling systems. The thermal and electrical properties of the materials at the heart of thermoelectric devices dictate conversion efficiency and technological viability. Studying the fundamental properties of potentially new thermoelectric materials is of great importance for improving device performance and understanding the electronic structure of materials systems. In this dissertation, investigations on the thermoelectric properties of a prototypical complex oxide, SrTiO3, are discussed. Hybrid molecular beam epitaxy (MBE) is used to synthesize La-doped SrTiO3 thin films, which exhibit high electron mobilities and large Seebeck coefficients resulting in large thermoelectric power factors at low temperatures. Large interfacial electron densities have been observed in SrTiO3/RTiO 3 (R=Gd,Sm) heterostructures. The thermoelectric properties of such heterostructures are investigated, including the use of a modulation doping approach to control interfacial electron densities. Low-temperature Seebeck coefficients of extreme electron-density SrTiO3 quantum wells are shown to provide insight into their electronic structure.

Research of interaction between technological and material parameters during densification of sunflower hulls

NASA Astrophysics Data System (ADS)

Križan, Peter; Matúš, Miloš; Beniak, Juraj; Šooš, Ľubomír

2018-01-01

During the biomass densification can be recognized various technological variables and also material parameters which significantly influences the final solid biofuels (pellets) quality. In this paper, we will present the research findings concerning relationships between technological and material variables during densification of sunflower hulls. Sunflower hulls as an unused source is a typical product of agricultural industry in Slovakia and belongs to the group of herbaceous biomass. The main goal of presented experimental research is to determine the impact of compression pressure, compression temperature and material particle size distribution on final biofuels quality. Experimental research described in this paper was realized by single-axis densification, which was represented by experimental pressing stand. The impact of mentioned investigated variables on the final briquettes density and briquettes dilatation was determined. Mutual interactions of these variables on final briquettes quality are showing the importance of mentioned variables during the densification process. Impact of raw material particle size distribution on final biofuels quality was also proven by experimental research on semi-production pelleting plant.

Electrostatic levitation technology for thermophysical properties of molten materials

NASA Technical Reports Server (NTRS)

Rhim, Won-Kyu

1993-01-01

Measurements of thermophysical properties of undercooled liquids often require some kind of levitator which isolates samples from container walls. We introduce in this presentation a high temperature/high vacuum electrostatic levitator (HTHVESL) which promises some unique capabilities for the studies of thermophysical properties of molten materials. Although substantial progress has been made in the past several months, this technology is still in the development stage, therefore, in this presentation we only focus on the present state of the HTHVESL(1) and point out other capabilities which might be realized in the near future.

Overview of CMC Development Activities in NASA's Ultra-Efficient Engine Technology (UEET) Program

NASA Technical Reports Server (NTRS)

Brewer, Dave

2001-01-01

The primary objective of the UEET (Ultra-Efficient Engine Technology) Program is to address two of the most critical propulsion issues: performance/efficiency and reduced emissions. High performance, low emissions engine systems will lead to significant improvement in local air quality, minimum impact on ozone depletion and level to an overall reduction in aviation contribution to global warming. The Materials and Structures for High Performance project will develop and demonstrate advanced high temperature materials to enable high-performance, high efficiency, and environmentally compatible propulsion systems.

Comparison of aged polyamide powders for selective laser sintering

NASA Astrophysics Data System (ADS)

Martínez, A.; Ibáñez, A.; Sánchez, A.; León, M. A.

2012-04-01

Selective Laser Sintering (SLS) is an additive manufacturing technology in which a three-dimensional object is manufactured layer by layer by melting powder materials with heat generated from a CO2 laser. However, a disadvantage of sintered materials is that the unsintered powder material during the process can be reused only a limited number of cycles, as during the heating phase in the sintering chamber the material remains at a temperature near the fusion point for a certain period of time and lose properties. This work shows the study of two polyamides (PA12)-based powders used in SLS with the aim of understanding the modification of their properties mainly with the temperature and the time at which they are exposed during the processing.

Rocket-powered single-stage-to-orbit vehicles for safe economical access to low earth orbit

NASA Astrophysics Data System (ADS)

Andrews, D. G.; Davis, E. E.; Bangsund, E. L.

1991-10-01

Rocket-powered SSTO vehicles were investigated during the SSTO technology demonstration contracts. Vehicle configurations were defined to include various technology concepts such as advanced rocket or air breathing engines, takeoff assist options, and advanced high temperature structural materials. Results of these investigations are summarized and performance and turnaround data are presented.

Cryogenic Insulation Standard Data and Methodologies Project

NASA Technical Reports Server (NTRS)

Summerfield, Burton; Thompson, Karen; Zeitlin, Nancy; Mullenix, Pamela; Fesmire, James; Swanger, Adam

2015-01-01

Extending some recent developments in the area of technical consensus standards for cryogenic thermal insulation systems, a preliminary Inter-Laboratory Study of foam insulation materials was performed by NASA Kennedy Space Center and LeTourneau University. The initial focus was ambient pressure cryogenic boil off testing using the Cryostat-400 flat-plate instrument. Completion of a test facility at LETU has enabled direct, comparative testing, using identical cryostat instruments and methods, and the production of standard thermal data sets for a number of materials under sub-ambient conditions. The two sets of measurements were analyzed and indicate there is reasonable agreement between the two laboratories. Based on cryogenic boiloff calorimetry, new equipment and methods for testing thermal insulation systems have been successfully developed. These boiloff instruments (or cryostats) include both flat plate and cylindrical models and are applicable to a wide range of different materials under a wide range of test conditions. Test measurements are generally made at large temperature difference (boundary temperatures of 293 K and 78 K are typical) and include the full vacuum pressure range. Results are generally reported in effective thermal conductivity (ke) and mean heat flux (q) through the insulation system. The new cryostat instruments provide an effective and reliable way to characterize the thermal performance of materials under subambient conditions. Proven in through thousands of tests of hundreds of material systems, they have supported a wide range of aerospace, industry, and research projects. Boiloff testing technology is not just for cryogenic testing but is a cost effective, field-representative methodology to test any material or system for applications at sub-ambient temperatures. This technology, when adequately coupled with a technical standards basis, can provide a cost-effective, field-representative methodology to test any material or system for applications at sub-ambient to cryogenic temperatures. A growing need for energy efficiency and cryogenic applications is creating a worldwide demand for improved thermal insulation systems for low temperatures. The need for thermal characterization of these systems and materials raises a corresponding need for insulation test standards and thermal data targeted for cryogenic-vacuum applications. Such standards have a strong correlation to energy, transportation, and environment and the advancement of new materials technologies in these areas. In conjunction with this project, two new standards on cryogenic insulation were recently published by ASTM International: C1774 and C740. Following the requirements of NPR 7120.10, Technical Standards for NASA Programs and Projects, the appropriate information in this report can be provided to the NASA Chief Engineer as input for NASA's annual report to NIST, as required by OMB Circular No. A-119, describing NASA's use of voluntary consensus standards and participation in the development of voluntary consensus standards and bodies.

Fabrication of Lanthanum Telluride 14-1-11 Zintl High-Temperature Thermoelectric Couple

NASA Technical Reports Server (NTRS)

Ravi, Vilupanur A.; Li, Billy Chun-Yip; Fleurial, Pierre; Star, Kurt

2010-01-01

The development of more efficient thermoelectric couple technology capable of operating with high-grade heat sources up to 1,275 K is key to improving the performance of radioisotope thermoelectric generators. Lanthanum telluride La3-xTe4 and 14-1-11 Zintls (Yb14MnSb11) have been identified as very promising materials. The fabrication of advanced high-temperature thermoelectric couples requires the joining of several dissimilar materials, typically including a number of diffusion bonding and brazing steps, to achieve a device capable of operating at elevated temperatures across a large temperature differential (up to 900 K). A thermoelectric couple typically comprises a heat collector/ exchanger, metallic interconnects on both hot and cold sides, n-type and ptype conductivity thermoelectric elements, and cold-side hardware to connect to the cold-side heat rejection and provide electrical connections. Differences in the physical, mechanical, and chemical properties of the materials that make up the thermoelectric couple, especially differences in the coefficients of thermal expansion (CTE), result in undesirable interfacial stresses that can lead to mechanical failure of the device. The problem is further complicated by the fact that the thermoelectric materials under consideration have large CTE values, are brittle, and cracks can propagate through them with minimal resistance. The inherent challenge of bonding brittle, high-thermal-expansion thermoelectric materials to a hot shoe material that is thick enough to carry the requisite electrical current was overcome. A critical advantage over prior art is that this device was constructed using all diffusion bonds and a minimum number of assembly steps. The fabrication process and the materials used are described in the following steps: (1) Applying a thin refractory metal foil to both sides of lanthanum telluride. To fabricate the n-type leg of the advanced thermoelectric couple, the pre-synthesized lanthanum telluride coupon was diffusion bonded to the metal foil using a thin adhesion layer. (2) Repeating a similar process for the 14-1-11 Zintl p-type leg of the advanced thermoelectric couple. (3) Bonding thick CTE-matched metal plates on the metallized lanthanum telluride and Yb14MnSb11 to form the hot and cold sides of the thermoelectric couple. The calculated conversion efficiency of such an advanced couple would be about 10.5 percent, about 35 percent better than heritage radioisotope thermoelectric technology that relies on Si-Ge alloys. In addition, unlike Si-Ge alloys, these materials can be combined with many other thermoelectric materials optimized for operation at lower temperatures to achieve conversion efficiency in excess of 15 percent (a factor of 2 increase over heritage technology).

SUPERFUND TREATABILITY CLEARINGHOUSE: PILOT INVESTIGATION OF LOW-TEMPERATURE STRIPPING OF VOLATILE ORGANIC COMPOUNDS (VOCS) FROM SOIL: VOLUME 1 - TECHNICAL REPORT AND VOLUME II APPENDICES

EPA Science Inventory

The U.S. Army Toxic and Hazardous Materials Agency (USATHAMA) is investigating technologies to treat soils contaminated with solvents. A pilot study of low temperature thermal stripping was conducted at Letterkenny Army Depot (LEAD) near Chambersburg, Pennsylvania, from 8/5/...

Self-Recovery Experiments in Extreme Environments Using a Field Programmable Transistor Array

NASA Technical Reports Server (NTRS)

Stoica, Adrian; Keymeulen, Didier; Arslan, Tughrul; Duong, Vu; Zebulum, Ricardo; Ferguson, Ian; Guo, Xin

2004-01-01

Temperature and radiation tolerant electronics, as well as long life survivability are key capabilities required for future NASA missions. Current approaches to electronics for extreme environments focus on component level robustness and hardening. However, current technology can only ensure very limited lifetime in extreme environments. This paper describes novel experiments that allow adaptive in-situ circuit redesign/reconfiguration during operation in extreme temperature and radiation environments. This technology would complement material/device advancements and increase the mission capability to survive harsh environments. The approach is demonstrated on a mixed-signal programmable chip (FPTA-2), which recovers functionality for temperatures until 28 C and with total radiation dose up to 250kRad.

Temperature-dependent Refractive Index of Silicon and Germanium

NASA Technical Reports Server (NTRS)

Frey, Bradley J.; Leviton, Douglas B.; Madison, Timothy J.

2006-01-01

Silicon and germanium are perhaps the two most well-understood semiconductor materials in the context of solid state device technologies and more recently micromachining and nanotechnology. Meanwhile, these two materials are also important in the field of infrared lens design. Optical instruments designed for the wavelength range where these two materials are transmissive achieve best performance when cooled to cryogenic temperatures to enhance signal from the scene over instrument background radiation. In order to enable high quality lens designs using silicon and germanium at cryogenic temperatures, we have measured the absolute refractive index of multiple prisms of these two materials using the Cryogenic, High-Accuracy Refraction Measuring System (CHARMS) at NASA's Goddard Space Flight Center, as a function of both wavelength and temperature. For silicon, we report absolute refractive index and thermo-optic coefficient (dn/dT) at temperatures ranging from 20 to 300 K at wavelengths from 1.1 to 5.6 pin, while for germanium, we cover temperatures ranging from 20 to 300 K and wavelengths from 1.9 to 5.5 microns. We compare our measurements with others in the literature and provide temperature-dependent Sellmeier coefficients based on our data to allow accurate interpolation of index to other wavelengths and temperatures. Citing the wide variety of values for the refractive indices of these two materials found in the literature, we reiterate the importance of measuring the refractive index of a sample from the same batch of raw material from which final optical components are cut when absolute accuracy greater than k5 x 10" is desired.

Temperature variation in metal ceramic technology analyzed using time domain optical coherence tomography

NASA Astrophysics Data System (ADS)

Sinescu, Cosmin; Topala, Florin I.; Negrutiu, Meda Lavinia; Duma, Virgil-Florin; Podoleanu, Adrian G.

2014-01-01

The quality of dental prostheses is essential in providing good quality medical services. The metal ceramic technology applied in dentistry implies ceramic sintering inside the dental oven. Every ceramic material requires a special sintering chart which is recommended by the producer. For a regular dental technician it is very difficult to evaluate if the temperature inside the oven remains the same as it is programmed on the sintering chart. Also, maintaining the calibration in time is an issue for the practitioners. Metal ceramic crowns develop a very accurate pattern for the ceramic layers depending on the temperature variation inside the oven where they are processed. Different patterns were identified in the present study for the samples processed with a variation in temperature of +30 °C to +50 °C, respectively - 30 0°C to -50 °C. The OCT imagistic evaluations performed for the normal samples present a uniform spread of the ceramic granulation inside the ceramic materials. For the samples sintered at a higher temperature an alternation between white and darker areas between the enamel and opaque layers appear. For the samples sintered at a lower temperature a decrease in the ceramic granulation from the enamel towards the opaque layer is concluded. The TD-OCT methods can therefore be used efficiently for the detection of the temperature variation due to the ceramic sintering inside the ceramic oven.

DOE Office of Scientific and Technical Information (OSTI.GOV)

Tan, Lizhen; Yang, Ying; Tyburska-Puschel, Beata

The mission of the Nuclear Energy Enabling Technologies (NEET) program is to develop crosscutting technologies for nuclear energy applications. Advanced structural materials with superior performance at elevated temperatures are always desired for nuclear reactors, which can improve reactor economics, safety margins, and design flexibility. They benefit not only new reactors, including advanced light water reactors (LWRs) and fast reactors such as sodium-cooled fast reactor (SFR) that is primarily designed for management of high-level wastes, but also life extension of the existing fleet when component exchange is needed. Developing and utilizing the modern materials science tools (experimental, theoretical, and computational tools)more » is an important path to more efficient alloy development and process optimization. Ferritic-martensitic (FM) steels are important structural materials for nuclear reactors due to their advantages over other applicable materials like austenitic stainless steels, notably their resistance to void swelling, low thermal expansion coefficients, and higher thermal conductivity. However, traditional FM steels exhibit a noticeable yield strength reduction at elevated temperatures above ~500°C, which limits their applications in advanced nuclear reactors which target operating temperatures at 650°C or higher. Although oxide-dispersion-strengthened (ODS) ferritic steels have shown excellent high-temperature performance, their extremely high cost, limited size and fabricability of products, as well as the great difficulty with welding and joining, have limited or precluded their commercial applications. Zirconium has shown many benefits to Fe-base alloys such as grain refinement, improved phase stability, and reduced radiation-induced segregation. The ultimate goal of this project is, with the aid of computational modeling tools, to accelerate the development of a new generation of Zr-bearing ferritic alloys to be fabricated using conventional steelmaking practices, which have excellent radiation resistance and enhanced high-temperature creep performance greater than Grade 91.« less

JPRS Report, Science & Technology, Japan, High Temperature Materials

DTIC Science & Technology

1990-11-09

3 This restriction is heavy. The inconvenience that the material powder of the imido thermal composition method, for example, which shows the best...procedures, system composition , features of formability, and forming characteristic of forming samples using alumina material will be made. 2...Osmotic V Process Forming System 2.1 System Composition of Process A system block diagram of the process is shown in Figure 1. The V process forming system

Thermally Stabilized Transmit/Receive Modules

NASA Technical Reports Server (NTRS)

Hoffman, James; DelCastillo, Linda; Miller, Jennifer; Birur, Gaj

2011-01-01

RF-hybrid technologies enable smaller packaging and mass reduction in radar instruments, especially for subsystems with dense electronics, such as electronically steered arrays. We are designing thermally stabilized RF-hybrid T/R modules using new materials for improved thermal performance of electronics. We are combining advanced substrate and housing materials with a thermal reservoir material, and develop new packaging techniques to significantly improve thermal-cycling reliability and performance stability over temperature.

Review of an assortment of IR materials-devices technologies used for imaging in spectral bands ranging from the visible to very long wavelengths

NASA Astrophysics Data System (ADS)

DeWames, Roger E.

2016-05-01

In this paper we review the intrinsic and extrinsic technological properties of the incumbent technology, InP/In0.53Ga0.47As/InP, for imaging in the visible- short wavelength spectral band, InSb and HgCdTe for imaging in the mid-wavelength spectral band and HgCdTe for imaging in the long wavelength spectral band. These material systems are in use for a wide range of applications addressing compelling needs in night vision imaging, low light level astronomical applications and defense strategic satellite sensing. These materials systems are direct band gap energy semiconductors hence the internal quantum efficiency η, is near unity over a wide spectral band pass. A key system figure of merit of a shot noise limited detector technology is given by the equation (1+Jdark. /Jphoton), where Jdark is the dark current density and Jphoton ~qηΦ is the photocurrent density; Φ is the photon flux incident on the detector and q is the electronic charge. The capability to maintain this factor for a specific spectral band close to unity for low illumination conditions and low temperature onset of non-ideal dark current components, basically intrinsic diffusion limited performance all the way, is a marker of quality and versatility of a semiconductor detector technology. It also enables the highest temperature of operation for tactical illumination conditions. A purpose of the work reported in this paper is to explore the focal plane array data sets of photodiode detector technologies widely used to bench mark their fundamental and technology properties and identify paths for improvements.

Ultrasonic High-Temperature Sensors: Past Experiments and Prospects for Future Use

NASA Astrophysics Data System (ADS)

Laurie, M.; Magallon, D.; Rempe, J.; Wilkins, C.; Pierre, J.; Marquié, C.; Eymery, S.; Morice, R.

2010-09-01

Ultrasonic thermometry sensors (UTS) have been intensively studied in the past to measure temperatures from 2080 K to 3380 K. This sensor, which uses the temperature dependence of the acoustic velocity in materials, was developed for experiments in extreme environments. Its major advantages, which are (a) capability of measuring a temperature profile from multiple sensors on a single probe and (b) measurement near the sensor material melting point, can be of great interest when dealing with on-line monitoring of high-temperature safety tests. Ultrasonic techniques were successfully applied in several severe accident related experiments. With new developments of alternative materials, this instrument may be used in a wide range of experimental areas where robustness and compactness are required. Long-term irradiation experiments of nuclear fuel to extremely high burn-ups could benefit from this previous experience. After an overview of UTS technology, this article summarizes experimental work performed to improve the reliability of these sensors. The various designs, advantages, and drawbacks are outlined and future prospects for long-term high-temperature irradiation experiments are discussed.

Growth and characterization of pure and Cadmium chloride doped KDP Crystals grown by gel medium

NASA Astrophysics Data System (ADS)

Kalaivani, M. S.; Asaithambi, T.

2016-10-01

Crystal growth technology provides an important basis for many industrial branches. Crystals are the unrecognized pillars of modern technology. Without crystals, there is no electronic industry, no photonic industry, and no fiber optic communications. Single crystals play a major role and form the strongest base for the fast growing field of engineering, science and technology. Crystal growth is an interdisciplinary subject covering physics, chemistry, material science, chemical engineering, metallurgy, crystallography, mineralogy, etc. In past few decades, there has been a keen interest on crystal growth processes, particularly in view of the increasing demand of materials for technological applications. Optically good quality pure and metal doped KDP crystals have been grown by gel method at room temperature and their characterization have been studied. Gel method is a much uncomplicated method and can be utilized to synthesize crystals which are having low solubility. Potassium dihydrogen orthophosphate KH2PO4 (KDP) continues to be an interesting material both academically and industrially. KDP is a representative of hydrogen bonded materials which possess very good electro - optic and nonlinear optical properties in addition to interesting electrical properties. Due to this interesting properties, we made an attempt to grow pure and cadmium chloride doped KDP crystals in various concentrations (0.002, 0.004, 0.006, 0.008 and 0.010) using gel method. The grown crystals were collected after 20 days. We get crystals with good quality and shaped. The dc electrical conductivity (resistance, capacitance and dielectric constant) values were measured at frequencies in the range of 1 KHZ and 100 HZ of pure and cadmium chloride added crystal with a temperature range of 400C to 1300C using simple two probe setup with Q band digital LCR meter present in our lab. The electrical conductivity increases with increase of temperature. The dielectric constants of metal doped KDP crystals were slightly decreased compared to pure KDP crystals.

Research on the treatment of oily wastewater by coalescence technology.

PubMed

Li, Chunbiao; Li, Meng; Zhang, Xiaoyan

2015-01-01

Recently, oily wastewater treatment has become a hot research topic across the world. Among the common methods for oily wastewater treatment, coalescence is one of the most promising technologies because of its high efficiency, easy operation, smaller land coverage, and lower investment and operational costs. In this research, a new type of ceramic filter material was chosen to investigate the effects of some key factors including particle size of coarse-grained materials, temperature, inflow direction and inflow velocity of the reactor. The aim was to explore the optimum operating conditions for coarse-graining. Results of a series of tests showed that the optimum operating conditions were a combination of grain size 1-3 mm, water temperature 35 °C and up-flow velocity 8 m/h, which promised a maximum oil removal efficiency of 93%.

DOE Office of Scientific and Technical Information (OSTI.GOV)

Makowska, Małgorzata G., E-mail: malg@dtu.dk; European Spallation Source ESS AB, P.O. Box 176, SE-221 00 Lund; Theil Kuhn, Luise

High material penetration by neutrons allows for experiments using sophisticated sample environments providing complex conditions. Thus, neutron imaging holds potential for performing in situ nondestructive measurements on large samples or even full technological systems, which are not possible with any other technique. This paper presents a new sample environment for in situ high resolution neutron imaging experiments at temperatures from room temperature up to 1100 °C and/or using controllable flow of reactive atmospheres. The design also offers the possibility to directly combine imaging with diffraction measurements. Design, special features, and specification of the furnace are described. In addition, examples of experimentsmore » successfully performed at various neutron facilities with the furnace, as well as examples of possible applications are presented. This covers a broad field of research from fundamental to technological investigations of various types of materials and components.« less

DOE Office of Scientific and Technical Information (OSTI.GOV)

Johnson, Francis

A team led by GE Global Research developed new magnetic refrigerant materials needed to enhance the commercialization potential of residential appliances such as refrigerators and air conditioners based on the magnetocaloric effect (a nonvapor compression cooling cycle). The new magnetic refrigerant materials have potentially better performance at lower cost than existing materials, increasing technology readiness level. The performance target of the new magnetocaloric material was to reduce the magnetic field needed to achieve 4 °C adiabatic temperature change from 1.5 Tesla to 0.75 Tesla. Such a reduction in field minimizes the cost of the magnet assembly needed for a magneticmore » refrigerator. Such a reduction in magnet assembly cost is crucial to achieving commercialization of magnetic refrigerator technology. This project was organized as an iterative alloy development effort with a parallel material modeling task being performed at George Washington University. Four families of novel magnetocaloric alloys were identified, screened, and assessed for their performance potential in a magnetic refrigeration cycle. Compositions from three of the alloy families were manufactured into regenerator components. At the beginning of the project a previously studied magnetocaloric alloy was selected for manufacturing into the first regenerator component. Each of the regenerators was tested in magnetic refrigerator prototypes at a subcontractor at at GE Appliances. The property targets for operating temperature range, operating temperature control, magnetic field sensitivity, and corrosion resistance were met. The targets for adiabatic temperature change and thermal hysteresis were not met. The high thermal hysteresis also prevented the regenerator components from displaying measurable cooling power when tested in prototype magnetic refrigerators. Magnetic refrigerant alloy compositions that were predicted to have low hysteresis were not attainable with conventional alloy processing methods. Preliminary experiments with rapid solidification methods showed a path towards attaining low hysteresis compositions should this alloy development effort be continued.« less

Drop dynamics in space and interference with acoustic field (M-15)

NASA Technical Reports Server (NTRS)

Yamanaka, Tatsuo

1993-01-01

The objective of the experiment is to study contactless positioning of liquid drops, excitation of capillary waves on the surface of acoustically levitated liquid drops, and deformation of liquid drops by means of acoustic radiation pressure. Contactless positioning technologies are very important in space materials processing because the melt is processed without contacting the wall of a crucible which can easily contaminate the melt specifically for high melting temperatures and chemically reactive materials. Among the contactless positioning technologies, an acoustic technology is especially important for materials unsusceptible to electromagnetic fields such as glasses and ceramics. The shape of a levitated liquid drop in the weightless condition is determined by its surface tension and the internal and external pressure distribution. If the surface temperature is constant and there exist neither internal nor external pressure perturbations, the levitated liquid drop forms a shape of perfect sphere. If temperature gradients on the surface and internal or external pressure perturbations exist, the liquid drop forms various modes of shapes with proper vibrations. A rotating liquid drop was specifically studied not only as a classical problem of theoretical mechanics to describe the shapes of the planets of the solar system, as well as their arrangement, but it is also more a contemporary problem of modern non-linear mechanics. In the experiment, we are expecting to observe various shapes of a liquid drop such as cocoon, tri-lobed, tetropod, multi-lobed, and doughnut.

Ceramic Technology for Advanced Heat Engines Project

DOE Office of Scientific and Technical Information (OSTI.GOV)

Not Available

1989-08-01

The Ceramic Technology for Advanced Heat Engines Project was developed by the Department of Energy's Office of Transportation Systems (OTS) in Conservation and Renewable Energy. This project, part of the OTS's Advanced Materials Development Program, was developed to meet the ceramic technology requirements of the OTS's automotive technology programs. Significant accomplishments in fabricating ceramic components for the Department of Energy (DOE), National Aeronautics and Space Administration (NASA), and Department of Defense (DoD) advanced heat engine programs have provided evidence that the operation of ceramic parts in high-temperature engine environments is feasible. However, these programs have also demonstrated that additional researchmore » is needed in materials and processing development, design methodology, and data base and life prediction before industry will have a sufficient technology base from which to produce reliable cost-effective ceramic engine components commercially.« less

DOE Office of Scientific and Technical Information (OSTI.GOV)

Johnson, R.D.

The purpose of the Heavy Vehicle Propulsion System Materials Program is the development of materials: ceramics, intermetallics, metal alloys, and metal and ceramic coatings, to support the dieselization of class 1-3 trucks to realize a 35% fuel-economy improvement over current gasoline-fueled trucks and to support commercialization of fuel-flexible LE-55 low-emissions, high-efficiency diesel engines for class 7-8 trucks. The Office of Transportation Technologies, Office of Heavy Vehicle Technologies (OIT OHVT) has an active program to develop the technology for advanced LE-55 diesel engines with 55% efficiency and low emissions levels of 2.0 g/bhp-h NOX and 0.05 g/bhp-h particulate. The goal ismore » also for the LE-55 engine to run on natural gas with efficiency approaching that of diesel fuel. The LE-55 program is being completed in FY 1997 and, after approximately 10 years of effort, has largely met the program goals of 55% efficiency and low emissions. However, the commercialization of the LE-55 technology requires more durable materials than those that have been used to demonstrate the goals. Heavy Vehicle Propulsion System Materials will, in concert with the heavy duty diesel engine companies, develop the durable materials required to commercialize the LE-55 technologies. OIT OHVT also recognizes a significant opportunity for reduction in petroleum consumption by dieselization of pickup trucks, vans, and sport utility vehicles. Application of the diesel engine to class 1,2, and 3 trucks is expected to yield a 35% increase in fuel economy per vehicle. The foremost barrier to diesel use in this market is emission control. Once an engine is made certifiable, subsequent challenges will be in cost; noise, vibration, and harshness (NVH); and performance. The design of advanced components for high-efficiency diesel engines has, in some cases, pushed the performance envelope for materials of construction past the point of reliable operation. Higher mechanical and tribological stresses and higher temperatures of advanced designs limit the engine designer; advanced materials allow the design of components that may operate reliably at higher stresses and temperatures, thus enabling more efficient engine designs. Advanced materials also offer the opportunity to improve the emissions, NVH, and performance of diesel engines for pickup trucks, vans, and sport utility vehicles. The principal areas of research are: (1) Cost Effective High Performance Materials and Processing; (2) Advanced Manufacturing Technology; (3)Testing and Characterization; and (4) Materials and Testing Standards.« less

High-temperature electronics

NASA Technical Reports Server (NTRS)

Matus, Lawrence G.; Seng, Gary T.

1990-01-01

To meet the needs of the aerospace propulsion and space power communities, the high temperature electronics program at the Lewis Research Center is developing silicon carbide (SiC) as a high temperature semiconductor material. This program supports a major element of the Center's mission - to perform basic and developmental research aimed at improving aerospace propulsion systems. Research is focused on developing the crystal growth, characterization, and device fabrication technologies necessary to produce a family of SiC devices.

High performance polymer development

NASA Technical Reports Server (NTRS)

Hergenrother, Paul M.

1991-01-01

The term high performance as applied to polymers is generally associated with polymers that operate at high temperatures. High performance is used to describe polymers that perform at temperatures of 177 C or higher. In addition to temperature, other factors obviously influence the performance of polymers such as thermal cycling, stress level, and environmental effects. Some recent developments at NASA Langley in polyimides, poly(arylene ethers), and acetylenic terminated materials are discussed. The high performance/high temperature polymers discussed are representative of the type of work underway at NASA Langley Research Center. Further improvement in these materials as well as the development of new polymers will provide technology to help meet NASA future needs in high performance/high temperature applications. In addition, because of the combination of properties offered by many of these polymers, they should find use in many other applications.

Application of high temperature phase change materials for improved efficiency in waste-to-energy plants.

PubMed

Dal Magro, Fabio; Xu, Haoxin; Nardin, Gioacchino; Romagnoli, Alessandro

2018-03-01

This study reports the thermal analysis of a novel thermal energy storage based on high temperature phase change material (PCM) used to improve efficiency in waste-to-energy plants. Current waste-to-energy plants efficiency is limited by the steam generation cycle which is carried out with boilers composed by water-walls (i.e. radiant evaporators), evaporators, economizers and superheaters. Although being well established, this technology is subjected to limitations related with high temperature corrosion and fluctuation in steam production due to the non-homogenous composition of solid waste; this leads to increased maintenance costs and limited plants availability and electrical efficiency. The proposed solution in this paper consists of replacing the typical refractory brick installed in the combustion chamber with a PCM-based refractory brick capable of storing a variable heat flux and to release it on demand as a steady heat flux. By means of this technology it is possible to mitigate steam production fluctuation, to increase temperature of superheated steam over current corrosion limits (450°C) without using coated superheaters and to increase the electrical efficiency beyond 34%. In the current paper a detailed thermo-mechanical analysis has been carried out in order to compare the performance of the PCM-based refractory brick against the traditional alumina refractory bricks. The PCM considered in this paper is aluminium (and its alloys) whereas its container consists of high density ceramics (such as Al 2 O 3 , AlN and Si 3 N 4 ); the different coefficient of linear thermal expansion for the different materials requires a detailed thermo-mechanical analysis to be carried out to ascertain the feasibility of the proposed technology. Copyright © 2017 Elsevier Ltd. All rights reserved.

Materials thermal and thermoradiative properties/characterization technology

NASA Technical Reports Server (NTRS)

Dewitt, D. P.; Ho, C. Y.

1989-01-01

Reliable properties data on well characterized materials are necessary for design of experiments and interpretation of experimental results. The activities of CINDAS to provide data bases and predict properties are discussed. An understanding of emissivity behavior is important in order to select appropriate methods for non-contact temperature determination. Related technical issues are identified and recommendations are offered.

Celebrate with SATELLITES: An International Polar Year Partnership to Study Earth's Materials

ERIC Educational Resources Information Center

Hedley, Mikell Lynne; Czajkowski, Kevin; Struble, Janet; Benko, Terri; Shellito, Brad; Sheridan, Scott; Stasiuk, Mandy Munroe

2009-01-01

The SATELLITES program uses geospatial technologies to study surface temperatures of Earth's materials, such as sand, soil, grass, and water. Data are collected using Global Learning and Observations to Benefit the Environment (GLOBE) protocols, which are then used in research projects that are a part of the International Polar Year (IPY).…

Materials Needs for Future In-space Propulsion Systems

NASA Technical Reports Server (NTRS)

Johnson, Charles Les

2008-01-01

NASA is developing the next generation of in-space propulsion systems in support of robotic exploration missions throughout the solar system. The propulsion technologies being developed are non-traditional and have stressing materials performance requirements. (Chemical Propulsion) Earth-storable chemical bipropellant performance is constrained by temperature limitations of the columbium used in the chamber. Iridium/rhenium (Ir/Re) is now available and has been implemented in initial versions of Earth-Storable rockets with specific impulses (Isp) about 10 seconds higher than columbium rocket chambers. New chamber fabrication methods that improve process and performance of Ir/Re and other promising material systems are needed. (Solar Sail Propulsion) The solar sail is a propellantless propulsion system that gains momentum by reflecting sunlight. The sails need to be very large in area (from 10000 m2 up to 62500 m2) yet be very lightweight in order to achieve adequate accelerations for realistic mission times. Lightweight materials that can be manufactured in thicknesses of less than 1 micron and that are not harmed by the space environment are desired. (Aerocapture) Blunt Body Aerocapture uses aerodynamic drag to slow an approaching spacecraft and insert it into a science orbit around any planet or moon with an atmosphere. The spacecraft is enclosed by a rigid aeroshell that protects it from the entry heating and aerodynamic environment. Lightweight, high-temperature structural systems, adhesives, insulators, and ablatives are key components for improving aeroshell efficiencies at heating rates of 1000-2000 W/cu cm and beyond. Inflatable decelerators in the forms of ballutes and inflatable aeroshells will use flexible polymeric thin film materials, high temperature fabrics, and structural adhesives. The inflatable systems will be tightly packaged during cruise and will be inflated prior to entry interface at the destination. Materials must maintain strength and flexibility while packaged at cold temperatures (_100oC) for up to 10 years and then withstand the high temperatures (500oC) encountered during aerocapture. The presentation will describe the status of each propulsion technology and summarize the materials needed for their implementation.

Synthesis, purification and bulk crystal growth of radiation detector materials using melt growth technique

NASA Astrophysics Data System (ADS)

Surabhi, Raja Rahul Reddy

In the past decade, there has been new and increased usage of radiation-detection technologies for applications in homeland security, non-proliferation, and national defense. Most of these applications require a portable device with high gamma-ray energy resolution and detection efficiency, compact size, room-temperature operation, and low cost. Consequently, there is a renewed understanding of the material limitations for these technologies and a great demand to develop next-generation radiation-detection materials that can operate at room temperature. Mercuric iodide (HgI2), Lead iodide (PbI2), and CdZnTe (CZT) are the current leading candidates for radiation detector applications. This is because of their high atomic number and large band gap that makes them particularly well suited for fabrication of high resolution and high efficiency compact devices. PbI2 is a promising material for room temperature nuclear radiation detectors, characterized by its wide band gap (EG=2.32eV) and high-density (rho=6.2g/cm3). It has been reported that PbI2 crystal detectors are able to detect gamma-ray in the range of 1KeV-1MeV, with good energy resolution. However, PbI 2 detectors have not been studied in detail because of non-availability of high quality single crystals. This study presents the synthesis, purification, growth and characterization of PbI2 single crystals grown. In this research, solid-state synthesis technique has been utilized for obtaining PbI2 as a starting material. For the first time, a unique low-temperature purification technique has been developed to obtain high-purity starting material. The crystals were grown using 2-zone Bridgman-Stockbarger (B.S) technique wherein growth rate and temperature gradient at the solid-liquid interface were optimized. Single crystals of PbI2 were successfully grown in quartz glass ampoule under different growth conditions. Material purity was determined by measuring the elemental concentration using the Inductively coupled plasma-optical emission spectroscopy (ICP-OES). ICP-OES is utilized for estimating impurities present in the low-temperature purified material, zone refined material and melt grown PbI2 crystals. The zone-refined material contains no traceable amounts of impurities, whereas the low-temperature purified material and melt grown PbI2 crystals show very low concentration of K (potassium) and Na (sodium) impurities. Crystal characterization has been performed for determining optical properties by UV-VIS spectroscopy. The energy band gap (EG) is an important parameter for materials used for room temperature gamma-ray detector applications. The absorption peak at 530nm is a characteristic of PbI2 and corresponds to the onset of the transitions from the valence band to the exciton level. From this absorption spectrum the calculated indirect band gap of PbI 2 was 2.33+/-0.025 eV at room temperature. For measuring the electrical properties (Dielectric and I-V characteristics) of the crystal, Ag (silver) contacts are applied to both sides of the sample. Dielectric analysis on melt grown PbI2 showed that space charge polarization was dominant at lower frequencies but stabilizes at higher frequencies over different operating temperatures. On the other hand, dielectric analysis for zone-refined material space charge polarization was constant over the operating range resulting in fewer lattice defects. Therefore the low temperature purified material followed by zone-refined purification provides detector grade material with fewer lattice defects. The measured electrical resistivity for melt grown PbI2 and zone-refined material are 3.185 x 10 10 O-cm and 0.754 x 109 O-cm at room temperature along (001) plane respectively.

JETC (Japanese Technology Evaluation Center) Panel Report on High Temperature Superconductivity in Japan

NASA Technical Reports Server (NTRS)

Shelton, Duane; Gamota, George

1989-01-01

The Japanese regard success in R and D in high temperature superconductivity as an important national objective. The results of a detailed evaluation of the current state of Japanese high temperature superconductivity development are provided. The analysis was performed by a panel of technical experts drawn from U.S. industry and academia, and is based on reviews of the relevant literature and visits to Japanese government, academic and industrial laboratories. Detailed appraisals are presented on the following: Basic research; superconducting materials; large scale applications; processing of superconducting materials; superconducting electronics and thin films. In all cases, comparisons are made with the corresponding state-of-the-art in the United States.

Detection of Micro-Leaks Through Complex Geometries Under Mechanical Load and at Cryogenic Temperature

NASA Technical Reports Server (NTRS)

Rivers, H. Kevin; Sikora, J. G.; Sankaran, S. N.

2001-01-01

Polymer Matrix Composite (PMC) hydrogen tanks have been proposed as an enabling technology for reducing the weight of Single-Stage-to-Orbit reusable launch vehicles where structural mass has a large impact on vehicle performance. A key development issue of these lightweight structures is the leakage of hydrogen through the composite material. The rate of hydrogen leakage can be a function of the material used, method of 6 fabrication used to manufacture the tank, mechanical load the tank must react, internal damage-state of the material, and the temperatures at which the tank must operate. A method for measuring leakage through a geometrically complex structure at cryogenic temperature and under mechanical load was developed, calibrated and used to measure hydrogen leakage through complex X-33 liquid-hydrogen tank structure sections.

Measurement component technology. Volume 1: Cryogenic pressure measurement technology, high pressure flange seals, hydrogen embrittlement of pressure transducer material, close coupled versus remote transducer installation and temperature compensation of pressure transducers

NASA Technical Reports Server (NTRS)

Hayakawa, K. K.; Udell, D. R.; Iwata, M. M.; Lytle, C. F.; Chrisco, R. M.; Greenough, C. S.; Walling, J. A.

1972-01-01

The results are presented of an investigation into the availability and performance capability of measurement components in the area of cryogenic temperature, pressure, flow and liquid detection components and high temperature strain gages. In addition, technical subjects allied to the components were researched and discussed. These selected areas of investigation were: (1) high pressure flange seals, (2) hydrogen embrittlement of pressure transducer diaphragms, (3) The effects of close-coupled versus remote transducer installation on pressure measurement, (4) temperature transducer configuration effects on measurements, and (5) techniques in temperature compensation of strain gage pressure transducers. The purpose of the program was to investigate the latest design and application techniques in measurement component technology and to document this information along with recommendations for upgrading measurement component designs for future S-2 derivative applications. Recommendations are provided for upgrading existing state-of-the-art in component design, where required, to satisfy performance requirements of S-2 derivative vehicles.

Electrodrift purification of materials for room temperature radiation detectors

DOEpatents

James, R.B.; Van Scyoc, J.M. III; Schlesinger, T.E.

1997-06-24

A method of purifying nonmetallic, crystalline semiconducting materials useful for room temperature radiation detecting devices by applying an electric field across the material is disclosed. The present invention discloses a simple technology for producing purified ionic semiconducting materials, in particular PbI{sub 2} and preferably HgI{sub 2}, which produces high yields of purified product, requires minimal handling of the material thereby reducing the possibility of introducing or reintroducing impurities into the material, is easy to control, is highly selective for impurities, retains the stoichiometry of the material and employs neither high temperatures nor hazardous materials such as solvents or liquid metals. An electric field is applied to a bulk sample of the material causing impurities present in the sample to drift in a preferred direction. After all of the impurities have been transported to the ends of the sample the current flowing through the sample, a measure of the rate of transport of mobile impurities, falls to a low, steady state value, at which time the end sections of the sample where the impurities have concentrated are removed leaving a bulk sample of higher purity material. Because the method disclosed here only acts on the electrically active impurities, the stoichiometry of the host material remains substantially unaffected. 4 figs.

Electrodrift purification of materials for room temperature radiation detectors

DOEpatents

James, Ralph B.; Van Scyoc, III, John M.; Schlesinger, Tuviah E.

1997-06-24

A method of purifying nonmetallic, crystalline semiconducting materials useful for room temperature radiation detecting devices by applying an electric field across the material. The present invention discloses a simple technology for producing purified ionic semiconducting materials, in particular PbI.sub.2 and preferably HgI.sub.2, which produces high yields of purified product, requires minimal handling of the material thereby reducing the possibility of introducing or reintroducing impurities into the material, is easy to control, is highly selective for impurities, retains the stoichiometry of the material and employs neither high temperatures nor hazardous materials such as solvents or liquid metals. An electric field is applied to a bulk sample of the material causing impurities present in the sample to drift in a preferred direction. After all of the impurities have been transported to the ends of the sample the current flowing through the sample, a measure of the rate of transport of mobile impurities, falls to a low, steady state value, at which time the end sections of the sample where the impurities have concentrated are removed leaving a bulk sample of higher purity material. Because the method disclosed here only acts on the electrically active impurities, the stoichiometry of the host material remains substantially unaffected.

Using of material-technological modelling for designing production of closed die forgings

NASA Astrophysics Data System (ADS)

Ibrahim, K.; Vorel, I.; Jeníček, Š.; Káňa, J.; Aišman, D.; Kotěšovec, V.

2017-02-01

Production of forgings is a complex and demanding process which consists of a number of forging operations and, in many cases, includes post-forge heat treatment. An optimized manufacturing line is a prerequisite for obtaining prime-quality products which in turn are essential to profitable operation of a forging company. Problems may, however, arise from modifications to the manufacturing route due to changing customer needs. As a result, the production may have to be suspended temporarily to enable changeover and optimization. Using material-technological modelling, the required modifications can be tested and optimized under laboratory conditions outside the plant without disrupting the production. Thanks to material-technological modelling, the process parameters can be varied rapidly in response to changes in market requirements. Outcomes of the modelling runs include optimum parameters for the forging part’s manufacturing route, values of mechanical properties, and results of microstructure analysis. This article describes the use of material-technological modelling for exploring the impact of the amount of deformation and the rate of cooling of a particular forged part from the finish-forging temperature on its microstructure and related mechanical properties.

Basic materials and structures aspects for hypersonic transport vehicles (HTV)

NASA Astrophysics Data System (ADS)

Steinheil, E.; Uhse, W.

A Mach 5 transport design is used to illustrate structural concepts and criteria for materials selections and also key technologies that must be followed in the areas of computational methods, materials and construction methods. Aside from the primary criteria of low weight, low costs, and conceivable risks, a number of additional requirements must be met, including stiffness and strength, corrosion resistance, durability, and a construction adequate for inspection, maintenance and repair. Current aircraft construction requirements are significantly extended for hypersonic vehicles. Additional consideration is given to long-duration temperature resistance of the airframe structure, the integration of large-volume cryogenic fuel tanks, computational tools, structural design, polymer matrix composites, and advanced manufacturing technologies.

Thermal protection using very high temperature ceramics

NASA Technical Reports Server (NTRS)

Adamczyk, George R.

1992-01-01

The purpose of the paper is to expose the reader to a technology that may solve some of the toughest materials problems facing thermal protection for use in aerospace. Supermaterials has created a system capable of producing unique material properties. Over 10 years and many man-hours have been invested in the development of this technology. Applications range from the food industry to the rigors of outer space. The flexibility of the system allows for customization not found in many other processes and at a reasonable cost. The ranges of materials and alloys that can be created are endless. Many cases with unique characteristics have been identified and we can expect even more with further development.

Synthesis and thermal conductivity of type II silicon clathrates

NASA Astrophysics Data System (ADS)

Beekman, M.; Nolas, G. S.

2006-08-01

We have synthesized and characterized polycrystalline Na 1Si 136 and Na 8Si 136, compounds possessing the type II clathrate hydrate crystal structure. Resistivity measurements from 10 to 300 K indicate very large resistivities in this temperature range, with activated temperature dependences indicative of relatively large band gap semiconductors. The thermal conductivity is very low; two orders-of-magnitude lower than that of diamond-structure silicon at room temperature. The thermal conductivity of Na 8Si 136 displays a temperature dependence that is atypical of crystalline solids and more indicative of amorphous materials. This work is part of a continuing effort to explore the many different compositions and structure types of clathrates, a class of materials that continues to be of interest for scientific and technological applications.

DOE Office of Scientific and Technical Information (OSTI.GOV)

Li, Lu

The objective of this research is to investigate the high-field magnetic properties of high temperature superconductors, materials that conduct electricity without loss. A technique known as high-resolution torque magnetometry that was developed to directly measure the magnetization of high temperature superconductors. This technique was implemented using the 65 Tesla pulsed magnetic field facility that is part of the National High Magnetic Field Laboratory at Los Alamos National Laboratory. This research addressed unanswered questions about the interplay between magnetism and superconductivity, determine the electronic structure of high temperature superconductors, and shed light on the mechanism of high temperature superconductivity and onmore » potential applications of these materials in areas such as energy generation and power transmission. Further applications of the technology resolve the novel physical phenomena such as correlated topological insulators, and spin liquid state in quantum magnets.« less

Method of production of pure hydrogen near room temperature from aluminum-based hydride materials

DOEpatents

Pecharsky, Vitalij K.; Balema, Viktor P.

2004-08-10

The present invention provides a cost-effective method of producing pure hydrogen gas from hydride-based solid materials. The hydride-based solid material is mechanically processed in the presence of a catalyst to obtain pure gaseous hydrogen. Unlike previous methods, hydrogen may be obtained from the solid material without heating, and without the addition of a solvent during processing. The described method of hydrogen production is useful for energy conversion and production technologies that consume pure gaseous hydrogen as a fuel.

Electrical research on solar cells and photovoltaic materials

NASA Technical Reports Server (NTRS)

Orehotsky, J.

1985-01-01

A systematic study of the properties of various polymer pottant materials and of the electrochemical corrosion mechanisms in solar cell materials is required for advancing the technology of terrestrial photovoltaic modules. The items of specific concern in this sponsored research activity involve: (1) kinetics of plasticizer loss in PVB, (2) kinetics of water absorption and desorption in PVB, (3) kinetics of water absorption and desorption in EVA, (4) the electrical properties at PVB as a function of temperature and humidity, (5) the electrical properties of EVA as a function of temperature and humidity, (6) solar cell corrosion characteristics, (7) water absorption effects in PVB and EVA, and (8) ion implantation and radiation effects in PVB and EVA.

The effects of the bottom anti-reflective coating with different baked temperatures and thicknesses on nanoscale patterns

NASA Astrophysics Data System (ADS)

Zheng, Jie; Li, Ling; Chen, Weidong

2015-12-01

The bottom anti-reflective coating (BARC) material can enhance the resolution of the nanopatterns structures in laser interference lithography process. In this study, WIDE-B ARC material was investigated to confirm the reduction of the vertical standing wave which leads to defect of nanopatterns. And the critical dimension (CD) of 100 nm L/S patterns with and without the application of BARC material was fabricated by laser interference lithography technology. The compared results showed that BARC can effectively reduce CD swing and obtain more uniform nanopatterns. Meanwhile, we also verified the influence of cured temperature and film thickness of BARC on the uniformity of nanopatterns.

Development of high temperature liquid metal test facilities for qualification of materials and investigations of thermoelectrical modules

NASA Astrophysics Data System (ADS)

Onea, A.; Hering, W.; Reiser, J.; Weisenburger, A.; Diez de los Rios Ramos, N.; Lux, M.; Ziegler, R.; Baumgärtner, S.; Stieglitz, R.

2017-07-01

Three classes of experimental liquid metal facilities have been completed during the LIMTECH project aiming the qualification of materials, investigation of thermoelectrical modules, investigation of sodium transitional regimes and fundamental thermo-dynamical flows in concentrating solar power (CSP) relevant geometries. ATEFA facility is dedicated to basic science investigation focussed on the alkali metal thermal-to-electric converter (AMTEC) technology. Three SOLTEC facilities are aimed to be used in different laboratories for long term material investigation sodium environment up to a 1000 K temperature and for long term tests of AMTEC modules. The medium scale integral facility KASOLA is planned as the backbone for CSP development and demonstration.

Heavy Vehicle Propulsion System Materials Program Semiannual Progress Report for April 2000 Through September 2000

DOE Office of Scientific and Technical Information (OSTI.GOV)

Johnson, DR

2000-12-11

The purpose of the Heavy Vehicle Propulsion System Materials Program is the development of materials: ceramics, intermetallics, metal alloys, and metal and ceramic coatings, to support the dieselization of class 1-3 trucks to realize a 35% fuel-economy improvement over current gasoline-fueled trucks and to support commercialization of fuel-flexible LE-55 low-emissions, high-efficiency diesel engines for class 7-8 trucks. The Office of Transportation Technologies, Office of Heavy Vehicle Technologies (OTT OHVT) has an active program to develop the technology for advantages LE-55 diesel engines with 55% efficiency and low emissions levels of 2.0 g/bhp-h NOx and 0.05 g/bhp-h particulates. The goal ismore » also for the LE-55 engine to run on natural gas with efficiency approaching that of diesel fuel. The LE-55 program is being completed in FY 1997 and, after approximately 10 years of effort, has largely met the program goals of 55% efficiency and low emissions. However, the commercialization of the LE-55 technology requires more durable materials than those that have been used to demonstrate the goals. Heavy Vehicle Propulsion System Materials will, in concert with the heavy duty diesel engine companies, develop the durable materials required to commercialize the LE-55 technologies. OTT OHVT also recognizes a significant opportunity for reduction in petroleum consumption by dieselization of pickup trucks, vans, and sport utility vehicles. Application of the diesel engine to class 1, 2, and 3 trucks is expected to yield a 35% increase in fuel economy per vehicle. The foremost barrier to diesel use in this market is emission control. Once an engine is made certifiable, subsequent challenges will be in cost; noise, vibration, and harshness (NVH); and performance. The design of advanced components for high-efficiency diesel engines has, in some cases, pushed the performance envelope for materials of construction past the point of reliable operation. Higher mechanical and tribological stresses and higher temperatures of advanced designs limit the engine designer; advanced materials allow the design of components that may operate reliably at higher stresses and temperatures, thus enabling more efficient engine designs. Advanced materials also offer the opportunity to improve the emissions, NVH, and performance of diesel engines for pickup trucks, vans, and sport utility vehicles.« less

Study of the thermal properties of filaments for 3D printing

DOE Office of Scientific and Technical Information (OSTI.GOV)

Trhlíková, Lucie, E-mail: xctrhlikova@fch.vutbr.cz; Zmeskal, Oldrich, E-mail: zmeskal@fch.vutbr.cz; Florian, Pavel, E-mail: xcflorianp@fch.vutbr.cz

Various materials are used for 3D printing, most commonly Acrylonitrile butadiene styrene (ABS), Polylactic acid (PLA), Polyethylene (PET) and Polypropylene (PP). These materials differ mainly in their melting point, which significantly influences the properties of the final products. Filaments are melted in the print head during the printing process. The temperature range is from 150 °C to 250 °C depending on the technology used. The optimum temperature for the cooling substrate on which printing is carried out is chosen so as to ensure uniform cooling and deformation. It generally varies between (40 – 100) °C. From the above it ismore » clear that both temperatures can significantly affect the properties of the printed 3D object. It is therefore important to determine the thermal parameters (thermal conductivity, specific heat and thermal diffusivity) of the materials used across the entire range of temperatures. For evaluating the properties of different types of PLA materials, the step transient method was used, which allows determination of all required parameters using a fractal heat transfer model.« less

Nanoscale Skyrmions in a Nonchiral Metallic Multiferroic: Ni 2MnGa

DOE PAGES

Phatak, Charudatta; Heinonen, Olle; De Graef, Marc; ...

2016-05-17

Magnetic skyrmions belong to a set of topologically nontrivial spin textures at the nanoscale that have received increased attention due to their emergent behavior and novel potential spintronic applications. Discovering materials systems that can host skyrmions at room temperature in the absence of external magnetic field is of crucial importance not only from a fundamental aspect, but also from a technological point of view. So far, the observations of skyrmions in bulk metallic ferromagnets have been limited to low temperatures and to materials that exhibit strong chiral interactions. In this paper, we show the formation of nanoscale skyrmions in amore » nonchiral multiferroic material, which is ferromagnetic and ferroelastic, Ni 2MnGa at room temperature without the presence of external magnetic fields. By using Lorentz transmission electron microscopy in combination with micromagnetic simulations, we elucidate their formation, behavior, and stability under applied magnetic fields at room temperature. Finally, the formation of skyrmions in a multiferroic material with no broken inversion symmetry presents new exciting opportunities for the exploration of the fundamental physics of topologically nontrivial spin textures.« less

Emissivity of Candidate Materials for VHTR Applicationbs: Role of Oxidation and Surface Modification Treatments

DOE Office of Scientific and Technical Information (OSTI.GOV)

Sridharan, Kumar; Allen, Todd; Anderson, Mark

The Generation IV (GEN IV) Nuclear Energy Systems Initiative was instituted by the Department of Energy (DOE) with the goal of researching and developing technologies and materials necessary for various types of future reactors. These GEN IV reactors will employ advanced fuel cycles, passive safety systems, and other innovative systems, leading to significant differences between these future reactors and current water-cooled reactors. The leading candidate for the Next Generation Nuclear Plant (NGNP) to be built at Idaho National Lab (INL) in the United States is the Very High Temperature Reactor (VHTR). Due to the high operating temperatures of the VHTR,more » the Reactor Pressure Vessel (RPV) will partially rely on heat transfer by radiation for cooling. Heat expulsion by radiation will become all the more important during high temperature excursions during off-normal accident scenarios. Radiant power is dictated by emissivity, a material property. The NGNP Materials Research and Development Program Plan [1] has identified emissivity and the effects of high temperature oxide formation on emissivity as an area of research towards the development of the VHTR.« less

Trends in high pressure developments for new perspectives

NASA Astrophysics Data System (ADS)

Largeteau, Alain; Prakasam, Mythili

2018-06-01

Temperature and Pressure are two parameters in the universe, where pressure represents the largest scale in comparison to temperature. The design of high pressure equipment depends mainly on the media used which could be gas, liquid or solid and the objective could be synthesis of materials or in situ characterization. The development of new research fields requiring high pressure equipment which are currently in Bordeaux - France are based on the historical development of high pressure domain initiated by Professor Gerard DEMAZEAU and his team during the last half century, which is discussed here. The main concepts governing the effect of pressure on materials synthesis is by the combination of high pressure and high temperature which are described with apt examples. There is an upsurge in various technologies for strong development for the synthesis of materials to drive several possibilities, for example: to reach very high density to obtain optical ceramics (by conventional SPS), to diminish parameters (P, T, t) of synthesis (by HP-SPS), to sinter at low temperature thermal sensitive composition (by HyS), to consolidate porous materials (by FIP), to densify biocomposite with cold decontamination (by HHP) simultaneously, etc.

Technology Risk Mitigation Research and Development for the Matter-Radiation Interactions in Extremes (MaRIE) Project

NASA Astrophysics Data System (ADS)

Barnes, Cris W.; Fernández, Juan; Hartsfield, Thomas; Sandberg, Richard; Sheffield, Richard; Tapia, John P.; Wang, Zhehui

2017-06-01

NNSA does not have a capability to understand and test the response of materials and conditions necessary to determine the linkages between microstructure of materials and performance in extreme weapons-relevant environments. Required is an x-ray source, coherent to optimize imaging capability, brilliant and high repetition-rate to address all relevant time scales, and with high enough energy to see into and through the amount of material in the middle or mesoscale where microstructure determines materials response. The Department of Energy has determined there is a mission need for a MaRIE Project to deliver this capability. There are risks to the Project to successfully deliver all the technology needed to provide the capability for the mission need and to use those photons to control the time-dependent production and performance of materials. The present technology risk mitigation activities for the MaRIE project are: developing ultrafast high-energy x-ray detectors, combining the data from several imaging probes to obtain multi-dimensional information about the sample, and developing techniques for bulk dynamic measurements of temperature. This talk will describe these efforts and other critical technology elements requiring future investment by the project.

The European Microkelvin Platform

NASA Astrophysics Data System (ADS)

Pickett, George; Enss, Christian

2018-03-01

The growing demands of quantum materials, engineering and technology make access to microkelvin temperatures ever more essential. Experience in Europe suggests that new working methods, encouraged by an imaginative funding atmosphere, can accelerate progress in this frontier field.

Superconducting accelerator magnet technology in the 21st century: A new paradigm on the horizon?

NASA Astrophysics Data System (ADS)

Gourlay, S. A.

2018-06-01

Superconducting magnets for accelerators were first suggested in the mid-60's and have since become one of the major components of modern particle colliders. Technological progress has been slow but steady for the last half-century, based primarily on Nb-Ti superconductor. That technology has reached its peak with the Large Hadron Collider (LHC). Despite the superior electromagnetic properties of Nb3Sn and adoption by early magnet pioneers, it is just now coming into use in accelerators though it has not yet reliably achieved fields close to the theoretical limit. The discovery of the High Temperature Superconductors (HTS) in the late '80's created tremendous excitement, but these materials, with tantalizing performance at high fields and temperatures, have not yet been successfully developed into accelerator magnet configurations. Thanks to relatively recent developments in both Bi-2212 and REBCO, and a more focused international effort on magnet development, the situation has changed dramatically. Early optimism has been replaced with a reality that could create a new paradigm in superconducting magnet technology. Using selected examples of magnet technology from the previous century to define the context, this paper will describe the possible innovations using HTS materials as the basis for a new paradigm.

Cast-in-place, ambiently-dried, silica-based, high-temperature insulation

DOE Office of Scientific and Technical Information (OSTI.GOV)

Cheng, Eric Jianfeng; Thompson, Travis; Salvador, James R.

A novel sol-gel chemistry approach was developed to enable the simple integration of a cast-in-place, ambiently-dried insulation into high temperature applications. The insulation was silica based, synthesized using methyltrimethoxysilane (MTMS) as the precursor. MTMS created a unique silica microstructure that was mechanically robust, macroporous, and superhydrophobic. To allow for casting into and around small, orthogonal features, zirconia fibers were added to increase stiffness and minimize contraction that could otherwise cause cracking during drying. Radiative heat transport was reduced by adding titania powder as an opacifier. To assess relevance to high temperature thermoelectric generator technology, a comprehensive set of materials characterizationsmore » were conducted. The silica gel was thermally stable, retained superhydrophobicity with a water contact angle > 150° , and showed a high electrical resistance > 1 GΩ, regardless of heating temperature (up to 600 °C in Ar for 4 h). In addition, it exhibited a Young's modulus ~3.7 MPa in room temperature and a low thermal conductivity < 0.08 W/m.K before and after heat treatment. Thus, based on the simplicity of the manufacturing process and optimized material properties, we believe this technology can act as an effective cast-in-place thermal insulation (CTI) for thermoelectric generators and myriad other applications requiring improved thermal efficiency.« less

Cast-in-place, ambiently-dried, silica-based, high-temperature insulation

DOE PAGES

Cheng, Eric Jianfeng; Thompson, Travis; Salvador, James R.; ...

2017-02-03

A novel sol-gel chemistry approach was developed to enable the simple integration of a cast-in-place, ambiently-dried insulation into high temperature applications. The insulation was silica based, synthesized using methyltrimethoxysilane (MTMS) as the precursor. MTMS created a unique silica microstructure that was mechanically robust, macroporous, and superhydrophobic. To allow for casting into and around small, orthogonal features, zirconia fibers were added to increase stiffness and minimize contraction that could otherwise cause cracking during drying. Radiative heat transport was reduced by adding titania powder as an opacifier. To assess relevance to high temperature thermoelectric generator technology, a comprehensive set of materials characterizationsmore » were conducted. The silica gel was thermally stable, retained superhydrophobicity with a water contact angle > 150° , and showed a high electrical resistance > 1 GΩ, regardless of heating temperature (up to 600 °C in Ar for 4 h). In addition, it exhibited a Young's modulus ~3.7 MPa in room temperature and a low thermal conductivity < 0.08 W/m.K before and after heat treatment. Thus, based on the simplicity of the manufacturing process and optimized material properties, we believe this technology can act as an effective cast-in-place thermal insulation (CTI) for thermoelectric generators and myriad other applications requiring improved thermal efficiency.« less

Green chemistry solutions for sol-gel micro-encapsulation of phase change materials for high-temperature thermal energy storage

NASA Astrophysics Data System (ADS)

Romero-Sanchez, Maria Dolores; Piticescu, Radu-Robert; Motoc, Adrian Mihail; Aran-Ais, Francisca; Tudor, Albert Ioan

2018-06-01

NaNO3 has been selected as phase change material (PCM) due to its convenient melting and crystallization temperatures for thermal energy storage (TES) in solar plants or recovering of waste heat in industrial processes. However, incorporation of PCMs and NaNO3 in particular requires its protection (i.e. encapsulation) into containers or support materials to avoid incompatibility or chemical reaction with the media where incorporated (i.e. corrosion in metal storage tanks). As a novelty, in this study, microencapsulation of an inorganic salt has been carried out also using an inorganic compound (SiO2) instead of the conventional polymeric shells used for organic microencapsulations and not suitable for high temperature applications (i.e. 300-500 °C). Thus, NaNO3 has been microencapsulated by sol-gel technology using SiO2 as shell material. Feasibility of the microparticles synthetized has been demonstrated by different experimental techniques in terms of TES capacity and thermal stability as well as durability through thermal cycles. The effectiveness of microencapsulated NaNO3 as TES material depends on the core:shell ratio used for the synthesis and on the maximum temperature supported by NaNO3 during use.

High Strength and Wear Resistant Aluminum Alloy for High Temperature Applications

NASA Technical Reports Server (NTRS)

Lee, Jonathan A.; Munafo, Paul M. (Technical Monitor)

2002-01-01

In this paper, a new high strength and wear resistant aluminum cast alloy invented by NASA-MSFC for high temperature applications will be presented. Developed to meet U.S. automotive legislation requiring low-exhaust emission, the novel NASA 398 aluminum-silicon alloy offers dramatic improvement in tensile and fatigue strengths at elevated temperatures (500 F-800 F), enabling new pistons to utilize less material, which can lead to reducing part weight and cost as well as improving performance. NASA 398 alloy also offers greater wear resistance, surface hardness, dimensional stability, and lower thermal expansion compared to conventional aluminum alloys for several commercial and automotive applications. The new alloy can be produced economically using permanent steel molds from conventional gravity casting or sand casting. The technology was developed to stimulate the development of commercial aluminum casting products from NASA-developed technology by offering companies the opportunity to license this technology.

NGNP Data Management and Analysis System Analysis and Web Delivery Capabilities

DOE Office of Scientific and Technical Information (OSTI.GOV)

Cynthia D. Gentillon

2010-09-01

Projects for the Very High Temperature Reactor Technology Development Office provide data in support of Nuclear Regulatory Commission licensing of the very high temperature reactor. Fuel and materials to be used in the reactor are tested and characterized to quantify performance in high-temperature and high-fluence environments. In addition, thermal-hydraulic experiments are conducted to validate codes used to assess reactor safety. The Very High Temperature Reactor Technology Development Office has established the NGNP Data Management and Analysis System (NDMAS) at the Idaho National Laboratory to ensure that very high temperature reactor data are (1) qualified for use, (2) stored in amore » readily accessible electronic form, and (3) analyzed to extract useful results. This document focuses on the third NDMAS objective. It describes capabilities for displaying the data in meaningful ways and for data analysis to identify useful relationships among the measured quantities.« less

Ceramic or metallic? - material aspects of compact heat regenerator energy efficiency

NASA Astrophysics Data System (ADS)

Wnek, M.

2012-05-01

The metal industry cannot afford the financial mismanagement in the era of rising energy prices and thus, the high efficiency devices should be used. In the metallurgical thermal processes the combustion air temperature increasing is one of the methods for obtaining the heat transfer intensification and the furnaces efficiency rising. Therefore the new and effective heating technologies in thermal processes are demanded all the time. The regenerative systems are most effective in terms of the heated air level. The individual regenerators for burners are the newest solutions where the temperature of 1100 °C is reachable for the exhaust temperature of 1200 °C. Based on research results, performed for the assumed exhaust temperature of 1100 °C, the paper presents possibilities of changeable different materials using as a regenerator filling in the aspect of its operation efficiency. Such materials as high-temperature steel, Al2O3 and SiC have been considered. The paper presents the selected data research, dealing with the air combustion temperature obtained for the same type of regenerator filling of considered materials. The fuel consumption reduction and reduction of CO2 emission, for metal regenerator filling, have been presented finally as an economic and environmental aspect accordingly to the air preheated.

Adhesive evaluation of LARC-TPI and a water-soluble version of LARC-TPI

NASA Technical Reports Server (NTRS)

Progar, D. J.

1985-01-01

The results of a study to evaluate two Langley Research Center thermoplastic polimide (TPI) materials, identified as TPI/MTC for the material from Mitsui Toatsu Chemicals Inc. and TPI/H2O for the material from United Technologies Research Center, as high temperature thermoplastic adhesives and primers for bonding titanium (6AL-4V) adherends are discussed. A limited characterization of the materials was performed using a Diffuse Reflectance-Fourier Transform Infrared Spectroscopy (DR-FTIR) technique. Thermomechanical Analysis (TMA) and torsional braid techniques were used to determine glass transition temperature. The adhesive's strength, as determined by simple lap shear tests, as used to evaluate the effects of long term thermal exposure (up to 1000 hrs) at 204 deg C and a 72-hour water-boil.

Review of Rover fuel element protective coating development at Los Alamos

NASA Technical Reports Server (NTRS)

Wallace, Terry C.

1991-01-01

The Los Alamos Scientific Laboratory (LASL) entered the nuclear propulsion field in 1955 and began work on all aspects of a nuclear propulsion program with a target exhaust temperature of about 2750 K. A very extensive chemical vapor deposition coating technology for preventing catastrophic corrosion of reactor core components by the high temperature, high pressure hydrogen propellant gas was developed. Over the 17-year term of the program, more than 50,000 fuel elements were coated and evaluated. Advances in performance were achieved only through closely coupled interaction between the developing fuel element fabrication and protective coating technologies. The endurance of fuel elements in high temperature, high pressure hydrogen environment increased from several minutes at 2000 K exit gas temperature to 2 hours at 2440 K exit gas temperature in a reactor test and 10 hours at 2350 K exit gas temperature in a hot gas test. The purpose of this paper is to highlight the rationale for selection of coating materials used (NbC and ZrC), identify critical fuel element-coat interactions that had to be modified to increase system performance, and review the evolution of protective coating technology.

Design and proof of concept of an innovative very high temperature ceramic solar absorber

NASA Astrophysics Data System (ADS)

Leray, Cédric; Ferriere, Alain; Toutant, Adrien; Olalde, Gabriel; Peroy, Jean-Yves; Chéreau, Patrick; Ferrato, Marc

2017-06-01

Hybrid solar gas-turbine (HSGT) is an attractive technology to foster market penetration of CSP. HSGT offers some major advantages like for example high solar-to-electric conversion efficiency, reduced water requirement and low capital cost. A very high temperature solar receiver is needed when elevated solar share is claimed. A few research works, as reported by Karni et al. [8] and by Buck et al. [1], have been dedicated to solar receiver technologies able to deliver pressurized air at temperature above 750°C. The present work focuses on research aiming at developing an efficient and reliable solar absorber able to provide pressurized air at temperature up to 1000°C and more. A surface absorber technology is selected and a modular design of receiver is proposed in which each absorber module is made of BOOSTEC® SiC ceramic (silicon carbide) as bulk material with straight air channels inside. Early stage experimental works done at CNRS/PROMES on lab-scale absorbers showed that the thermo-mechanical behavior of this material is a critical issue, resulting in elevated probability of failure under severe conditions like large temperature gradient or steep variation of solar flux density in situations of cloud covering. This paper reports on recent progress made at CNRS/PROMES to address this critical issue. The design of the absorber has been revised and optimized according to thermo-mechanical numerical simulations, and an experimental proof of concept has been done on a pilot-scale absorber module at Themis solar tower facility.

Ultra-Lightweight Hybrid Thin-Film Solar Cells: A Survey of Enabling Technologies for Space Power Applications

NASA Technical Reports Server (NTRS)

Hepp, Aloysius F.; McNatt, Jeremiah S.; Bailey, Sheila G.; Dickman, John E.; Raffaelle, Ryne P.; Landi, Brian J.; Anctil, Annick; DiLeo, Roberta; Jin, Michael H.-C.; Lee, Chung-Young;

The impact of individual materials parameters on color temperature reproducibility among phosphor converted LED sources

NASA Astrophysics Data System (ADS)

Schweitzer, Susanne; Nemitz, Wolfgang; Sommer, Christian; Hartmann, Paul; Fulmek, Paul; Nicolics, Johann; Pachler, Peter; Hoschopf, Hans; Schrank, Franz; Langer, Gregor; Wenzl, Franz P.

2014-09-01

For a systematic approach to improve the white light quality of phosphor converted light-emitting diodes (LEDs) for general lighting applications it is imperative to get the individual sources of error for color temperature reproducibility under control. In this regard, it is imperative to understand how compositional, optical and materials properties of the color conversion element (CCE), which typically consists of phosphor particles embedded in a transparent matrix material, affect the constancy of a desired color temperature of a white LED source. In this contribution we use an LED assembly consisting of an LED die mounted on a printed circuit board (PCB) by chip-on-board technology and a CCE with a glob-top configuration as a model system and discuss the impact of potential sources for color temperature deviation among individual devices. Parameters that are investigated include imprecisions in the amount of materials deposition, deviations from the target value for the phosphor concentration in the matrix material, deviations from the target value for the particle sizes of the phosphor material, deviations from the target values for the refractive indexes of phosphor and matrix material as well as deviations from the reflectivity of the substrate surface. From these studies, some general conclusions can be drawn which of these parameters have the largest impact on color deviation and have to be controlled most precisely in a fabrication process in regard of color temperature reproducibility among individual white LED sources.

Armored instrumentation cable for geothermal well logging

DOE Office of Scientific and Technical Information (OSTI.GOV)

Dennis, B.R.; Johnson, J.; Todd, B.

1981-01-01

Multiconductor armored well-logging cable is used extensively by the oil and natural gas industry to lower various instruments used to measure the geological and geophysical parameters into deep wellbores. Advanced technology in oil-well drilling makes it possible to achieve borehole depths of 9 km (30,000 ft). The higher temperatures in these deeper boreholes demand advancements in the design and manufacturing of wireline cable and in the electrical insulating and armoring materials used as integral components. If geothermal energy is proved an abundant economic resource, drilling temperatures approaching and exceeding 300/sup 0/C will become commonplace. The adaptation of teflons as electricalmore » insulating material permitted use of armored cable in geothermal wellbores where temperatures are slightly in excess of 200/sup 0/C, and where the concentrations of corrosive minerals and gases are high. Teflon materials presently used in wireline cables, however, are not capable of continuous operation at the anticipated higher temperatures.« less

Room temperature ferroelectricity in one-dimensional single chain molecular magnets [{M(Δ)M(Λ)}(ox)2(phen)2]n (M = Fe and Mn)

NASA Astrophysics Data System (ADS)

Bhatt, Pramod; Mukadam, M. D.; Meena, S. S.; Mishra, S. K.; Mittal, R.; Sastry, P. U.; Mandal, B. P.; Yusuf, S. M.

2017-03-01

The ferroelectric materials are mainly focused on pure inorganic oxides; however, the organic molecule based materials have recently attracted great attention because of their multifunctional properties. The mixing of oxalate and phenanthroline ligands with metal ions (Fe or Mn) at room temperature followed by hydrothermal treatment results in the formation of one-dimensional single chain molecular magnets which exhibit room temperature dielectric and ferroelectric behavior. The compounds are chiral in nature, and exhibit a ferroelectric behavior, attributed to the polar point group C2, in which they crystallized. The compounds are also associated with a dielectric loss and thus a relaxation process. The observed electric dipole moment, essential for a ferroelectricity, has been understood quantitatively in terms of lattice distortions at two different lattice sites within the crystal structure. The studied single chain molecular magnetic materials with room temperature ferroelectric and dielectric properties could be of great technological importance in non-volatile memory elements, and high-performance insulators.

High-Temperature, Thin-Film Ceramic Thermocouples Developed

NASA Technical Reports Server (NTRS)

Sayir, Ali; Blaha, Charles A.; Gonzalez, Jose M.

2005-01-01

To enable long-duration, more distant human and robotic missions for the Vision for Space Exploration, as well as safer, lighter, quieter, and more fuel efficient vehicles for aeronautics and space transportation, NASA is developing instrumentation and material technologies. The high-temperature capabilities of thin-film ceramic thermocouples are being explored at the NASA Glenn Research Center by the Sensors and Electronics Branch and the Ceramics Branch in partnership with Case Western Reserve University (CWRU). Glenn s Sensors and Electronics Branch is developing thin-film sensors for surface measurement of strain, temperature, heat flux, and surface flow in propulsion system research. Glenn s Ceramics Branch, in conjunction with CWRU, is developing structural and functional ceramic technology for aeropropulsion and space propulsion.

Luminescence of Eu(3+) doped SiO2 Thin Films and Glass Prepared by Sol-gel Technology

NASA Technical Reports Server (NTRS)

Castro, Lymari; Jia, Weiyi; Wang, Yanyun; Santiago, Miguel; Liu, Huimin

1998-01-01

Trivalent europium ions are an important luminophore for lighting and display. The emission of (5)D0 to (7)F2 transition exhibits a red color at about 610 nm, which is very attractive and fulfills the requirement for most red-emitting phosphors including lamp and cathode ray phosphorescence materials. Various EU(3+) doped phosphors have been developed, and luminescence properties have been extensively studied. On the other hand, sol-gel technology has been well developed by chemists. In recent years, applications of this technology to optical materials have drawn a great attention. Sol-gel technology provides a unique way to obtain homogeneous composition distribution and uniform doping, and the processing temperature can be very low. In this work, EU(3+) doped SiO2 thin films and glasses were prepared by sol-gel technology and their spectroscopic properties were investigated.

Site Directed Nucleation and Growth of Ceramic Films on Metallic Surfaces

DTIC Science & Technology

2009-04-30

ceramics and other nanoscale composite materials research with the ultimate goal being the cell-free, nanocrystalline assembly of adaptive bioceramic...for high temperature or high wear environments. Other applications/technology developments for this research include adaptive materials, wear...bound vesicles that form the surface membrane of gastropod nacre. 19 Folia formation was observed by recovering titanium and aluminum disc implants

Adhesive Bonding Characterization of Composite Joints for Cryogenic Usage

NASA Technical Reports Server (NTRS)

Graf, Neil A.; Schieleit, Gregory F.; Biggs, Robert

2000-01-01

The development of polymer composite cryogenic tanks is a critical step in creating the next generation of launch vehicles. Future reusable launch vehicles need to minimize the gross liftoff weight (GLOW). This weight reduction is possible due to the large reduction in weight that composite materials can provide over current aluminum technology. In addition to composite technology, adhesively bonded joints potentially have several benefits over mechanically fastened joints, such as weight savings and cryogenic fluid containment. Adhesively bonded joints may be used in several areas of these cryogenic tanks, such as in lobe-to-lobe joints (in a multi-lobe concept), skirt-to-tank joint, strut-to-tank joint, and for attaching stringers and ring frames. The bonds, and the tanks themselves, must be able to withstand liquid cryogenic fuel temperatures that they contain. However, the use of adhesively bonded composite joints at liquid oxygen and hydrogen temperatures is largely unknown and must be characterized. Lockheed Martin Space Systems Company, Michoud Operations performed coupon-level tests to determine effects of material selection, cure process parameters, substrate surface preparation, and other factors on the strength of these composite joints at cryogenic temperatures. This led to the selection of a material and process that would be suitable for a cryogenic tank. KEY WORDS: Composites, Adhesive Bonding, Cryogenics

Sorbent-based Oxygen Production for Energy Systems

DOE Office of Scientific and Technical Information (OSTI.GOV)

Sethi, Vijay

Project DE-FE0024075 deals with the development of a moderate-temperature sorbent-based oxygen production technology. Sorbent-based oxygen production process utilizes oxygen-storage properties of Perovskites to (1) adsorb oxygen from air in a solid sorbent, and (2) release the adsorbed oxygen into a sweep gas such as CO 2 and/or steam for gasification systems or recycled flue gas for oxy-combustion systems. Pure oxygen can be produced by the use of vacuum instead of a sweep gas to affect the pressure swing. By developing more efficient and stable, higher sorption capacity, newer class of materials operating at moderate temperatures this process represents a majormore » advancement in air separation technology. Newly developed perovskite ceramic sorbent materials with order-disorder transition have a higher O 2 adsorption capacity, potentially 200 °C lower operating temperatures, and up to two orders of magnitude faster desorption rates than those used in earlier development efforts. The performance advancements afforded by the new materials lead to substantial savings in capital investment and operational costs. Cost of producing oxygen using sorbents could be as much as 26% lower than VPSA and about 13% lower than a large cryogenic air separation unit. Cost advantage against large cryogenic separation is limited because sorbent-based separation numbers up sorbent modules for achieving the larger capacity.« less

NCTM of liquids at high temperatures using polarization techniques

NASA Technical Reports Server (NTRS)

Krishnan, Shankar; Weber, J. K. Richard; Nordine, Paul C.; Schiffman, Robert A.

1990-01-01

Temperature measurement and control is extremely important in any materials processing application. However, conventional techniques for non-contact temperature measurement (mainly optical pyrometry) are very uncertain because of unknown or varying surface emittance. Optical properties like other properties change during processing. A dynamic, in-situ measurement of optical properties including the emittance is required. Intersonics is developing new technologies using polarized laser light scattering to determine surface emittance of freely radiating bodies concurrent with conventional optical pyrometry. These are sufficient to determine the true surface temperature of the target. Intersonics is currently developing a system called DAPP, the Division of Amplitude Polarimetric Pyrometer, that uses polarization information to measure the true thermodynamic temperature of freely radiating objects. This instrument has potential use in materials processing applications in ground and space based equipment. Results of thermophysical and thermodynamic measurements using laser reflection as a temperature measuring tool are presented. The impact of these techniques on thermophysical property measurements at high temperature is discussed.

A Summary of Research on Energy Saving and Emission Reduction of Transportation

NASA Astrophysics Data System (ADS)

Cheng, Dongxiang; Wu, Lufen

2017-12-01

Road transport is an important part of transportation, and road in the field of energy-saving emission reduction is a very important industry. According to the existing problems of road energy saving and emission reduction, this paper elaborates the domestic and international research on energy saving and emission reduction from three aspects: road network optimization, pavement material and pavement maintenance. Road network optimization may be overlooked, and the research content is still relatively preliminary; pavement materials mainly from the asphalt pavement temperature mixed asphalt technology research; pavement maintenance technology development is relatively comprehensive.

The technological raw material heating furnaces operation efficiency improving issue

NASA Astrophysics Data System (ADS)

Paramonov, A. M.

2017-08-01

The issue of fuel oil applying efficiency improving in the technological raw material heating furnaces by means of its combustion intensification is considered in the paper. The technical and economic optimization problem of the fuel oil heating before combustion is solved. The fuel oil heating optimal temperature defining method and algorithm analytically considering the correlation of thermal, operating parameters and discounted costs for the heating furnace were developed. The obtained optimization functionality provides the heating furnace appropriate thermal indices achievement at minimum discounted costs. The carried out research results prove the expediency of the proposed solutions using.

Non-Contact Measurements of Creep Properties of Refractory Materials

NASA Technical Reports Server (NTRS)

Lee, Jonghyun; Bradshaw, Richard C.; Hyers, Robert W.; Rogers, Jan R.; Rathz, Thomas J.; Wall, James J.; Choo, Hahn; Liaw, Peter

2006-01-01

State-of-the-art technologies for hypersonic aircraft, nuclear electric/thermal propulsion for spacecraft, and more efficient jet engines are driving ever more demanding needs for high-temperature (>2000 C) materials. At such high temperatures, creep rises as one of the most important design factors to be considered. Since conventional measurement techniques for creep resistance are limited to about 17OO0C, a new technique is in demand for higher temperatures. This paper presents a non-contact method using electrostatic levitation (ESL) which is applicable to both metallic and non-metallic materials. The samples were rotated quickly enough to cause creep deformation by centrifugal acceleration. The deformation of the samples was captured with a high speed camera and then the images were analyzed to estimate creep resistance. Finite element analyses were performed and compared to the experiments to verify the new method. Results are presented for niobium and tungsten, representative refractory materials at 2300 C and 2700 C respectively.

High-Temperature Proton-Conducting Ceramics Developed

NASA Technical Reports Server (NTRS)

Sayir, Ali; Dynys, Frederick W.; Berger, M. H.

2005-01-01

High-temperature protonic conductors (HTPC) are needed for hydrogen separation, hydrogen sensors, fuel cells, and hydrogen production from fossil fuels. The HTPC materials for hydrogen separation at high temperatures are foreseen to be metal oxides with the perovskite structure A(sup 2+)B(sup 4+)C(sup 2-, sub 3) and with the trivalent cation (M(sup 3+)) substitution at the B(sup 4+)-site to introduce oxygen vacancies. The high affinity for hydrogen ions (H(sup +)) is advantageous for protonic transport, but it increases the reactivity toward water (H2O) and carbon dioxide (CO2), which can lead to premature membrane failure. In addition, there are considerable technological challenges related to the processing of HTPC materials. The high melting point and multi-cation chemistry of HTPC materials creates difficulties in in achieving high-density, single-phase membranes by solid-state sintering. The presence of secondary phases and grain-boundary interfaces are detrimental to the protonic conduction and environmental stability of polycrystalline HTPC materials.

Textile composite fuselage structures development

NASA Technical Reports Server (NTRS)

Jackson, Anthony C.; Barrie, Ronald E.; Chu, Robert L.

1993-01-01

Phase 2 of the NASA ACT Contract (NAS1-18888), Advanced Composite Structural Concepts and Materials Technology for Transport Aircraft Structures, focuses on textile technology, with resin transfer molding or powder coated tows. The use of textiles has the potential for improving damage tolerance, reducing cost and saving weight. This program investigates resin transfer molding (RTM), as a maturing technology for high fiber volume primary structures and powder coated tows as an emerging technology with a high potential for significant cost savings and superior structural properties. Powder coated tow technology has promise for significantly improving the processibility of high temperature resins such as polyimides.

Laser-Induced Thermal-Mechanical Damage Characteristics of Cleartran Multispectral Zinc Sulfide with Temperature-Dependent Properties

NASA Astrophysics Data System (ADS)

Peng, Yajing; Jiang, Yanxue; Yang, Yanqiang

2015-01-01

Laser-induced thermal-mechanical damage characteristics of window materials are the focus problems in laser weapon and anti-radiation reinforcement technology. Thermal-mechanical effects and damage characteristics are investigated for cleartran multispectral zinc sulfide (ZnS) thin film window materials irradiated by continuous laser using three-dimensional (3D) thermal-mechanical model. Some temperature-dependent parameters are introduced into the model. The temporal-spatial distributions of temperature and thermal stress are exhibited. The damage mechanism is analyzed. The influences of temperature effect of material parameters and laser intensity on the development of thermal stress and the damage characteristics are examined. The results show, the von Mises equivalent stress along the thickness direction is fluctuant, which originates from the transformation of principal stresses from compressive stress to tensile stress with the increase of depth from irradiated surface. The damage originates from the thermal stress but not the melting. The thermal stress is increased and the damage is accelerated by introducing the temperature effect of parameters or the increasing laser intensity.

Benchmarking the expected stack manufacturing cost of next generation, intermediate-temperature protonic ceramic fuel cells with solid oxide fuel cell technology

NASA Astrophysics Data System (ADS)

Dubois, Alexis; Ricote, Sandrine; Braun, Robert J.

2017-11-01

Recent progress in the performance of intermediate temperature (500-600 °C) protonic ceramic fuel cells (PCFCs) has demonstrated both fuel flexibility and increasing power density that approach commercial application requirements. These developments may eventually position the technology as a viable alternative to solid oxide fuel cells (SOFCs) and molten carbonate fuel cells (MCFCs). The PCFCs investigated in this work are based on a BaZr0.8Y0.2O3-δ (BZY20) thin electrolyte supported by BZY20/Ni porous anodes, and a triple conducting cathode material comprised of BaCo0.4Fe0.4Zr0.1Y0.1O3-δ (BCFZY0.1). These cells are prepared using a low-cost solid-state reactive sintering (SSRS) process, and are capable of power densities of 0.156 W cm-2 at 500 °C operating directly from methane fuel. We develop a manufacturing cost model to estimate the Nth generation production costs of PCFC stack technology using high volume manufacturing processes and compare them to the state-of-the-art in SOFC technology. The low-cost cell manufacturing enabled by the SSRS technique compensates for the lower PCFC power density and the trade-off between operating temperature and efficiency enables the use of lower-cost stainless steel materials. PCFC stack production cost estimates are found to be as much as 27-37% lower at 550 °C than SOFCs operating at 800 °C.

FRICTION STIR LAP WELDING OF ALUMINUM - POLYMER USING SCRIBE TECHNOLOGY

DOE Office of Scientific and Technical Information (OSTI.GOV)

Upadhyay, Piyush; Hovanski, Yuri; Fifield, Leonard S.

2015-02-16

Friction Stir Scribe (FSS) technology is a relatively new variant of Friction Stir Welding (FSW) which enables lap joining of dissimilar material with very different melting points and different high temperature flow behaviors. The cutter scribe attached at the tip of FSW tool pin effectively cuts the high melting point material such that a mechanically interlocking feature is created between the dissimilar materials. The geometric shape of this interlocking feature determines the shear strength attained by the lap joint. This work presents first use of scribe technology in joining polymers to aluminum alloy. Details of the several runs of scribemore » welding performed in lap joining of ~3.175mm thick polymers including HDPE, filled and unfilled Nylon 66 to 2mm thick AA5182 are presented. The effect of scribe geometry and length on weld interlocking features is presented along with lap shear strength evaluations.« less

The Influence of Technological Regimes of Synthesizing a Solar Furnace on the Phase Composition of TiO2-CuO Cermets and the Optical Properties of Coatings on Their Basis

NASA Astrophysics Data System (ADS)

Suleimanov, S. Kh.; Dyskin, V. G.; Dzhanklich, M. U.; Dudko, O. A.; Kulagina, N. A.

2018-01-01

We present the results of studying the effect of technological synthesis regimes of a solar furnace using the method of a partial metal reduction of one of the oxides on the phase formation of cermet composite materials of the TiO2-CuO system. It has been established that the phase composition of the synthesized cermet composite materials depends on the carbon concentration, melting temperature and cooling rate. The dependence of the spectral-optical properties of selectively absorbing coatings on the production technology and properties of synthesized composite materials has been presented. It has been found that the coatings fabricated by melting in air with overheating at a melt cooling rate of about 105-106°C/s have the highest values of the integral absorption coefficient, α s = 91.0-94.5%.

Next-Generation Electrochemical Energy Materials for Intermediate Temperature Molten Oxide Fuel Cells and Ion Transport Molten Oxide Membranes.

PubMed

Belousov, Valery V

2017-02-21

High temperature electrochemical devices such as solid oxide fuel cells (SOFCs) and oxygen separators based on ceramic materials are used for efficient energy conversion. These devices generally operate in the temperature range of 800-1000 °C. The high operating temperatures lead to accelerated degradation of the SOFC and oxygen separator materials. To solve this problem, the operating temperatures of these electrochemical devices must be lowered. However, lowering the temperature is accompanied by decreasing the ionic conductivity of fuel cell electrolyte and oxygen separator membrane. Therefore, there is a need to search for alternative electrolyte and membrane materials that have high ionic conductivity at lower temperatures. A great many opportunities exist for molten oxides as electrochemical energy materials. Because of their unique electrochemical properties, the molten oxide innovations can offer significant benefits for improving energy efficiency. In particular, the newly developed electrochemical molten oxide materials show high ionic conductivities at intermediate temperatures (600-800 °C) and could be used in molten oxide fuel cells (MOFCs) and molten oxide membranes (MOMs). The molten oxide materials containing both solid grains and liquid channels at the grain boundaries have advantages compared to the ceramic materials. For example, the molten oxide materials are ductile, which solves a problem of thermal incompatibility (difference in coefficient of thermal expansion, CTE). Besides, the outstanding oxygen selectivity of MOM materials allows us to separate ultrahigh purity oxygen from air. For their part, the MOFC electrolytes show the highest ionic conductivity at intermediate temperatures. To evaluate the potential of molten oxide materials for technological applications, the relationship between the microstructure of these materials and their transport and mechanical properties must be revealed. This Account summarizes the latest results on oxygen ion transport in potential MOM materials and MOFC electrolytes. In addition, we consider the rapid oxygen transport in a molten oxide scale formed on a metal surface during catastrophic oxidation and show that the same transport could be used beneficially in MOMs and MOFCs. A polymer model explaining the oxygen transport in molten oxides is also considered. Understanding the oxygen transport mechanisms in oxide melts is important for the development of new generation energy materials, which will contribute to more efficient operation of electrochemical devices at intermediate temperatures. Here we highlight the progress made in developing this understanding. We also show the latest advances made in search of alternative molten oxide materials having high mixed ion electronic and ionic conductivities for use in MOMs and MOFCs, respectively. Prospects for further research are presented.

Smart Crack Control in Concrete through Use of Phase Change Materials (PCMs): A Review

PubMed Central

2018-01-01

Cracks in concrete structures present a threat to their durability. Therefore, numerous research studies have been devoted to reducing concrete cracking. In recent years, a new approach has been proposed for controlling temperature related cracking—utilization of phase change materials (PCMs) in concrete. Through their ability to capture heat, PCMs can offset temperature changes and reduce gradients in concrete structures. Nevertheless, they can also influence concrete properties. This paper presents a comprehensive overview of the literature devoted to using PCMs to control temperature related cracking in concrete. First, types of PCMs and ways of incorporation in concrete are discussed. Then, possible uses of PCMs in concrete technology are discussed. Further, the influences of PCMs on concrete properties (fresh, hardened, durability) are discussed in detail. This is followed by a discussion of modelling techniques for PCM-concrete composites and their performance. Finally, a summary and the possible research directions for future work are given. This overview aims to assure the researchers and asset owners of the potential of this maturing technology and bring it one step closer to practical application. PMID:29695076

Smart Crack Control in Concrete through Use of Phase Change Materials (PCMs): A Review.

PubMed

Šavija, Branko

2018-04-24

Cracks in concrete structures present a threat to their durability. Therefore, numerous research studies have been devoted to reducing concrete cracking. In recent years, a new approach has been proposed for controlling temperature related cracking—utilization of phase change materials (PCMs) in concrete. Through their ability to capture heat, PCMs can offset temperature changes and reduce gradients in concrete structures. Nevertheless, they can also influence concrete properties. This paper presents a comprehensive overview of the literature devoted to using PCMs to control temperature related cracking in concrete. First, types of PCMs and ways of incorporation in concrete are discussed. Then, possible uses of PCMs in concrete technology are discussed. Further, the influences of PCMs on concrete properties (fresh, hardened, durability) are discussed in detail. This is followed by a discussion of modelling techniques for PCM-concrete composites and their performance. Finally, a summary and the possible research directions for future work are given. This overview aims to assure the researchers and asset owners of the potential of this maturing technology and bring it one step closer to practical application.

Advances in Thin Film Sensor Technologies for Engine Applications

NASA Technical Reports Server (NTRS)

Lei, Jih-Fen; Martin, Lisa C.; Will, Herbert A.

1997-01-01

Advanced thin film sensor techniques that can provide accurate surface strain and temperature measurements are being developed at NASA Lewis Research Center. These sensors are needed to provide minimally intrusive characterization of advanced materials (such as ceramics and composites) and structures (such as components for Space Shuttle Main Engine, High Speed Civil Transport, Advanced Subsonic Transports and General Aviation Aircraft) in hostile, high-temperature environments and for validation of design codes. This paper presents two advanced thin film sensor technologies: strain gauges and thermocouples. These sensors are sputter deposited directly onto the test articles and are only a few micrometers thick; the surface of the test article is not structurally altered and there is minimal disturbance of the gas flow over the surface. The strain gauges are palladium-13% chromium based and the thermocouples are platinum-13% rhodium vs. platinum. The fabrication techniques of these thin film sensors in a class 1000 cleanroom at the NASA Lewis Research Center are described. Their demonstration on a variety of engine materials, including superalloys, ceramics and advanced ceramic matrix composites, in several hostile, high-temperature test environments are discussed.

Thermally Conductive-Silicone Composites with Thermally Reversible Cross-links.

PubMed

Wertz, J T; Kuczynski, J P; Boday, D J

2016-06-08

Thermally conductive-silicone composites that contain thermally reversible cross-links were prepared by blending diene- and dienophile-functionalized polydimethylsiloxane (PDMS) with an aluminum oxide conductive filler. This class of thermally conductive-silicones are useful as thermal interface materials (TIMs) within Information Technology (IT) hardware applications to allow rework of valuable components. The composites were rendered reworkable via retro Diels-Alder cross-links when temperatures were elevated above 130 °C and required little mechanical force to remove, making them advantageous over other TIM materials. Results show high thermal conductivity (0.4 W/m·K) at low filler loadings (45 wt %) compared to other TIM solutions (>45 wt %). Additionally, the adhesion of the material was found to be ∼7 times greater at lower temperatures (25 °C) and ∼2 times greater at higher temperatures (120 °C) than commercially available TIMs.

Bioinspired Thermoresponsive Photonic Polymers with Hierarchical Structures and Their Unique Properties.

PubMed

Lu, Tao; Zhu, Shenmin; Ma, Jun; Lin, Jinyou; Wang, Wanlin; Pan, Hui; Tian, Feng; Zhang, Wang; Zhang, Di

2015-10-01

Thermoresponsive photonic materials having hierarchical structures are created by combining a template of Morpho butterfly wings with poly(N-isopropylacrylamide) (PNIPAM) through a chemical bonding and polymerization route. These materials show temperature-induced color tunability. Through reacting with both NIPAM monomers and the amino groups of chitosan in wing scales, glutaraldehyde workes as a bridge by creating chemical bonding between the biotemplate and the PNIPAM. The corresponding reflection peaks red-shift with increase in temperature-an opposite phenomenon to previous studies, demonstrating a thermoresponsive photonic property. This unique phenomenon is caused by the refractive index change due to the volume change of PNIPAM during the temperature rising. This work sets up an efficient strategy for the fabrication of stimuli-responsive photonic materials with hierarchical structures toward extensive applications in science and technology. © 2015 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

PMR Extended Shelf Life Technology Given 2000 R and D 100 Award

NASA Technical Reports Server (NTRS)

Meador, Michael A.

2001-01-01

An approach developed at the NASA Glenn Research Center for extending the shelf life of PMR polyimide solutions and prepregs received an R&D 100 Award this year. PMR polyimides, in particular PMR-15, have become attractive materials for a variety of aerospace applications because of their outstanding high-temperature stability and performance. PMR-15 can be used in components with exposures to temperatures as high as 290 C, which leads to substantial reductions in weight, as much as 30 percent over metal components. PMR-15 composites are used widely in aerospace applications ranging from ducts and external components in aircraft engines to an engine access door for the Space Shuttle Main Engine. A major barrier to more widespread use of these materials is high component costs. Recent efforts at Glenn have addressed the various factors that contribute to these costs in an attempt to more fully utilize these lightweight, high-temperature materials.

Super Stable Ferroelectrics with High Curie Point.

PubMed

Gao, Zhipeng; Lu, Chengjia; Wang, Yuhang; Yang, Sinuo; Yu, Yuying; He, Hongliang

2016-04-07

Ferroelectric materials are of great importance in the sensing technology due to the piezoelectric properties. Thermal depoling behavior of ferroelectrics determines the upper temperature limit of their application. So far, there is no piezoelectric material working above 800 °C available. Here, we show Nd2Ti2O7 with a perovskite-like layered structure has good resistance to thermal depoling up to 1400 °C. Its stable behavior is because the material has only 180° ferroelectric domains, complex structure change at Curie point (Tc) and their sintering temperature is below their Tc, which avoided the internal stresses produced by the unit cell volume change at Tc. The phase transition at Tc shows a first order behavior which involving the tilting and rotation of the octahedron. The Curie - Weiss temperature is calculated, which might explain why the thermal depoling starts at about 1400 °C.

High-efficiency machining methods for aviation materials

NASA Astrophysics Data System (ADS)

Kononov, V. K.

1991-07-01

The papers contained in this volume present results of theoretical and experimental studies aimed at increasing the efficiency of cutting tools during the machining of high-temperature materials and titanium alloys. Specific topics discussed include a study of the performance of disk cutters during the machining of flexible parts of a high-temperature alloy, VZhL14N; a study of the wear resistance of cutters of hard alloys of various types; effect of a deformed electric field on the precision of the electrochemical machining of gas turbine engine components; and efficient machining of parts of composite materials. The discussion also covers the effect of the technological process structure on the residual stress distribution in the blades of gas turbine engines; modeling of the multiparameter assembly of engineering products for a specified priority of geometrical output parameters; and a study of the quality of the surface and surface layer of specimens machined by a high-temperature pulsed plasma.

Super Stable Ferroelectrics with High Curie Point

PubMed Central

Gao, Zhipeng; Lu, Chengjia; Wang, Yuhang; Yang, Sinuo; Yu, Yuying; He, Hongliang

2016-01-01

Ferroelectric materials are of great importance in the sensing technology due to the piezoelectric properties. Thermal depoling behavior of ferroelectrics determines the upper temperature limit of their application. So far, there is no piezoelectric material working above 800 °C available. Here, we show Nd2Ti2O7 with a perovskite-like layered structure has good resistance to thermal depoling up to 1400 °C. Its stable behavior is because the material has only 180° ferroelectric domains, complex structure change at Curie point (Tc) and their sintering temperature is below their Tc, which avoided the internal stresses produced by the unit cell volume change at Tc. The phase transition at Tc shows a first order behavior which involving the tilting and rotation of the octahedron. The Curie – Weiss temperature is calculated, which might explain why the thermal depoling starts at about 1400 °C. PMID:27053338

Manufacturing a 9-Meter Thermoplastic Composite Wind Turbine Blade: Preprint

DOE Office of Scientific and Technical Information (OSTI.GOV)

Murray, Robynne; Snowberg, David R; Berry, Derek S

Currently, wind turbine blades are manufactured from a combination of glass and/or carbon fiber composite materials with a thermoset resin such as epoxy, which requires energy-intensive and expensive heating processes to cure. Newly developed in-situ polymerizing thermoplastic resin systems for composite wind turbine blades polymerize at room temperature, eliminating the heating process and significantly reducing the blade manufacturing cycle time and embodied energy, which in turn reduces costs. Thermoplastic materials can also be thermally welded, eliminating the need for adhesive bonds between blade components and increasing the overall strength and reliability of the blades. As well, thermoplastic materials enable end-of-lifemore » blade recycling by reheating and decomposing the materials, which is a limitation of existing blade technology. This paper presents a manufacturing demonstration for a 9-m-long thermoplastic composite wind turbine blade. This blade was constructed in the Composites Manufacturing Education and Technology facility at the National Wind Technology Center at the National Renewable Energy Laboratory (NREL) using a vacuum-assisted resin transfer molding process. Johns Manville fiberglass and an Arkema thermoplastic resin called Elium were used. Additional materials included Armacell-recycled polyethylene terephthalate foam from Creative Foam and low-cost carbon- fiber pultruded spar caps (manufactured in collaboration with NREL, Oak Ridge National Laboratory, Huntsman, Strongwell, and Chomarat). This paper highlights the development of the thermoplastic resin formulations, including an additive designed to control the peak exothermic temperatures. Infusion and cure times of less than 3 hours are also demonstrated, highlighting the efficiency and energy savings associated with manufacturing thermoplastic composite blades.« less

Aerospace Ceramic Materials: Thermal, Environmental Barrier Coatings and SiC/SiC Ceramic Matrix Composites for Turbine Engine Applications

NASA Technical Reports Server (NTRS)

Zhu, Dongming

2018-01-01

Ceramic materials play increasingly important roles in aerospace applications because ceramics have unique properties, including high temperature capability, high stiffness and strengths, excellent oxidation and corrosion resistance. Ceramic materials also generally have lower densities as compared to metallic materials, making them excellent candidates for light-weight hot-section components of aircraft turbine engines, rocket exhaust nozzles, and thermal protection systems for space vehicles when they are being used for high-temperature and ultra-high temperature ceramics applications. Ceramic matrix composites (CMCs), including non-oxide and oxide CMCs, are also recently being incorporated in gas turbine engines for high pressure and high temperature section components and exhaust nozzles. However, the complexity and variability of aerospace ceramic processing methods, compositions and microstructures, the relatively low fracture toughness of the ceramic materials, still remain the challenging factors for ceramic component design, validation, life prediction, and thus broader applications. This ceramic material section paper presents an overview of aerospace ceramic materials and their characteristics. A particular emphasis has been placed on high technology level (TRL) enabling ceramic systems, that is, turbine engine thermal and environmental barrier coating systems and non-oxide type SiC/SiC CMCs. The current status and future trend of thermal and environmental barrier coatings and SiC/SiC CMC development and applications are described.

The nematode Caenorhabditis elegans survives subfreezing temperatures in an isochoric system

DOE Office of Scientific and Technical Information (OSTI.GOV)

Mikus, Hannah; Miller, Alexander; Nastase, Gabriel, E-mail: traznasa@gmail.com

This study is the first experimental evidence showing that a living multicellular organism, the nematode Caenorhabditis elegans, can survive subfreezing temperatures in an isochoric (constant volume) thermodynamic system, while immersed in a simple isotonic solution, without the addition of cryoprotectants. Some of the test conditions were more extreme than those found at the ice/water interface of the Antarctic subglacial Vostok lake. On earth, life takes place in an isobaric (constant pressure) environment. In isobaric systems, subfreezing temperature survival of organisms in nature and subfreezing temperature preservation of living material for biotechnology and medicine, is made possible by use of cryoprotectivemore » chemicals additives. Our theoretical thermodynamic studies suggested that in an isochoric system, living biological material could survive subfreezing temperatures, without any cryoprotective chemicals. By confirming the theoretical predictions, this paper suggests a new technology for subfreezing preservation of cells, organs and organisms of possible value for biotechnology and medicine as well as new possible mechanisms of living organism survival in nature. - Highlights: • Preservation of biological materials at, subfreezing temperatures, in an isochoric system, is demonstrated. • Experiments were performed with Caenorhabditis elegans to pressures of 65 MPa and temperatures of −6 °C. • Isochoric subfreezing temperature is a new preservation method that does not require the use of cryoprotectants.« less

High Temperature Superconductors: From Delivery to Applications (Presentation from 2011 Ernest Orlando Lawrence Award-winner, Dr. Amit Goyal, and including introduction by Energy Secretary, Dr. Steven Chu)

ScienceCinema

Goyal, Amit [Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)

2018-04-27

Dr. Amit Goyal, a high temperature superconductivity (HTS) researcher at Oak Ridge National Laboratory, was named a 2011 winner of the Department of Energy's Ernest Orlando Lawrence Award honoring U.S. scientists and engineers for exceptional contributions in research and development supporting DOE and its mission. Winner of the award in the inaugural category of Energy Science and Innovation, Dr. Goyal was cited for his work in 'pioneering research and transformative contributions to the field of applied high temperature superconductivity, including fundamental materials science advances and technical innovations enabling large-scale applications of these novel materials.' Following his basic research in grain-to-grain supercurrent transport, Dr. Goyal focused his energy in transitioning this fundamental understanding into cutting-edge technologies. Under OE sponsorship, Dr. Goyal co-invented the Rolling Assisted Bi-Axially Textured Substrate technology (RABiTS) that is used as a substrate for second generation HTS wires. OE support also led to the invention of Structural Single Crystal Faceted Fiber Substrate (SSIFFS) and the 3-D Self Assembly of Nanodot Columns. These inventions and associated R&D resulted in 7 R&D 100 Awards including the 2010 R&D Magazine's Innovator of the Year Award, 3 Federal Laboratory Consortium Excellence in Technology Transfer National Awards, a DOE Energy 100 Award and many others. As a world authority on HTS materials, Dr. Goyal has presented OE-sponsored results in more than 150 invited talks, co-authored more than 350 papers and is a fellow of 7 professional societies.

2009 Insensitive Munitions and Energetic Materials Technology Symposium

DTIC Science & Technology

2009-05-14

Multilayer Structure 1D STIMULI Flat end rod Round end rod Flat cookie -cutter Spherical fragment Simple shaped charge jet Real shaped charge jet Thin plate... cookie -cutter Spherical fragment Simple shaped charge jet Real shaped charge jet Thin plate Constant Temperature Rising Temperature Multilayer...Propellants  Plasticizer mixed into the Propellant - Dough NO SURFACE COATING Formulation Impetus (J/g) Flame Temp (K) Mw (g/mole) A

Physics and Process Modeling (PPM) and Other Propulsion R and T. Volume 1; Materials Processing, Characterization, and Modeling; Lifting Models

NASA Technical Reports Server (NTRS)

1997-01-01

This CP contains the extended abstracts and presentation figures of 36 papers presented at the PPM and Other Propulsion R&T Conference. The focus of the research described in these presentations is on materials and structures technologies that are parts of the various projects within the NASA Aeronautics Propulsion Systems Research and Technology Base Program. These projects include Physics and Process Modeling; Smart, Green Engine; Fast, Quiet Engine; High Temperature Engine Materials Program; and Hybrid Hyperspeed Propulsion. Also presented were research results from the Rotorcraft Systems Program and work supported by the NASA Lewis Director's Discretionary Fund. Authors from NASA Lewis Research Center, industry, and universities conducted research in the following areas: material processing, material characterization, modeling, life, applied life models, design techniques, vibration control, mechanical components, and tribology. Key issues, research accomplishments, and future directions are summarized in this publication.

Energy-technological complex with reactor for torrefaction

NASA Astrophysics Data System (ADS)

Kuzmina, J. S.; Director, L. B.; Zaichenko, V. M.

2016-11-01

To eliminate shortcomings of raw plant materials pelletizing process with thermal treatment (low-temperature pyrolysis or torrefaction) can be applied. This paper presents a mathematical model of energy-technological complex (ETC) for combined production of heat, electricity and solid biofuels torrefied pellets. According to the structure the mathematical model consists of mathematical models of main units of ETC and the relationships between them and equations of energy and material balances. The equations describe exhaust gas straining action through a porous medium formed by pellets. Decomposition rate of biomass was calculated by using the gross-reaction diagram, which is responsible for the disintegration of raw material. A mathematical model has been tested according to bench experiments on one reactor module. From nomographs, designed for a particular configuration of ETC it is possible to determine the basic characteristics of torrefied pellets (rate of weight loss, heating value and heat content) specifying only two parameters (temperature and torrefaction time). It is shown that the addition of reactor for torrefaction to gas piston engine can improve the energy efficiency of power plant.

Comprehensive Enhancement of Nanostructured Lithium-Ion Battery Cathode Materials via Conformal Graphene Dispersion

DOE Office of Scientific and Technical Information (OSTI.GOV)

Chen, Kan-Sheng; Xu, Rui; Luu, Norman S.

Efficient energy storage systems based on lithium-ion batteries represent a critical technology across many sectors including consumer electronics, electrified transportation, and a smart grid accommodating intermittent renewable energy sources. Nanostructured electrode materials present compelling opportunities for high-performance lithium-ion batteries, but inherent problems related to the high surface area to volume ratios at the nanometer-scale have impeded their adoption for commercial applications. Here, we demonstrate a materials and processing platform that realizes high-performance nanostructured lithium manganese oxide (nano-LMO) spinel cathodes with conformal graphene coatings as a conductive additive. The resulting nanostructured composite cathodes concurrently resolve multiple problems that have plagued nanoparticle-basedmore » lithium-ion battery electrodes including low packing density, high additive content, and poor cycling stability. Moreover, this strategy enhances the intrinsic advantages of nano-LMO, resulting in extraordinary rate capability and low temperature performance. With 75% capacity retention at a 20C cycling rate at room temperature and nearly full capacity retention at -20 degrees C, this work advances lithium-ion battery technology into unprecedented regimes of operation.« less

Floating the Ball: Advances in the Technology of Electrostatic Levitation

NASA Technical Reports Server (NTRS)

Rogers, Jan R.

2006-01-01

Electrostatic Levitation (ESL) is an emerging technology. The MSFC ESL is a NASA facility that supports investigations of refractory solids and melts. The facility can be used to process a wide variety of materials including metals, alloys, ceramics, glasses and semiconductors. Containerless processing via ESL provides a high-purity environment for the study of high temperature materials and access to metastable states. Scientific topics investigated in the facility include nucleation, undercooling, metastable state formation and metallic glass formation. Additionally, the MSFC ESL provides data for the determination of phase diagrams, time-temperature-transition diagrams, viscosity, surface tension, density, heat capacity and creep resistance. In order to support a diverse research community, the MSFC ESL facility has developed a number of technical capabilities, including a portable system for in situ studies of structural tran$hrmations during processing at the high-energy X-ray beamline at the Advanced Photon Source of Argonne National Laboratory. The capabilities of the MSFC ESL facilities will be discussed and selected results of materials processing and characterization studies will be presented.

Comprehensive Enhancement of Nanostructured Lithium-Ion Battery Cathode Materials via Conformal Graphene Dispersion.

PubMed

Chen, Kan-Sheng; Xu, Rui; Luu, Norman S; Secor, Ethan B; Hamamoto, Koichi; Li, Qianqian; Kim, Soo; Sangwan, Vinod K; Balla, Itamar; Guiney, Linda M; Seo, Jung-Woo T; Yu, Xiankai; Liu, Weiwei; Wu, Jinsong; Wolverton, Chris; Dravid, Vinayak P; Barnett, Scott A; Lu, Jun; Amine, Khalil; Hersam, Mark C

2017-04-12

Efficient energy storage systems based on lithium-ion batteries represent a critical technology across many sectors including consumer electronics, electrified transportation, and a smart grid accommodating intermittent renewable energy sources. Nanostructured electrode materials present compelling opportunities for high-performance lithium-ion batteries, but inherent problems related to the high surface area to volume ratios at the nanometer-scale have impeded their adoption for commercial applications. Here, we demonstrate a materials and processing platform that realizes high-performance nanostructured lithium manganese oxide (nano-LMO) spinel cathodes with conformal graphene coatings as a conductive additive. The resulting nanostructured composite cathodes concurrently resolve multiple problems that have plagued nanoparticle-based lithium-ion battery electrodes including low packing density, high additive content, and poor cycling stability. Moreover, this strategy enhances the intrinsic advantages of nano-LMO, resulting in extraordinary rate capability and low temperature performance. With 75% capacity retention at a 20C cycling rate at room temperature and nearly full capacity retention at -20 °C, this work advances lithium-ion battery technology into unprecedented regimes of operation.

Pumping and Depressurizing of Insulation Materials

NASA Technical Reports Server (NTRS)

Porter, Amber

2010-01-01

The Fluids Testing and Technology Branch is a group that researches and tests efficient ways to use various Cryogenic Fluids, such as Liquid Nitrogen or Liquid Helium, in ground and space systems. Their main goal is to develop new technologies involving Cryogenic temperatures as well as making sure the existing technologies are understood. During my time here a lot of insulation testing has been done which is where insulation systems are tested for cryogenic systems that are in space for long durations.

Development of superconducting YBa2Cu3O(x) wires with low resistance electrical contacts

NASA Technical Reports Server (NTRS)

Buoncristiani, A. M.; Byvik, C. E.; Caton, R.; Selim, R.; Lee, B. I.; Modi, V.; Sherrill, M.; Leigh, H. D.; Fain, C. C.; Lewis, G.

1993-01-01

Materials exhibiting superconductivity above liquid nitrogen temperatures (77 K) will enable new applications of this phenomena. One of the first commercial applications of this technology will be superconducting magnets for medical imaging. However, a large number of aerospace applications of the high temperature superconducting materials have also been identified. These include magnetic suspension and balance of models in wind tunnels and resistanceless leads to anemometers. The development of superconducting wires fabricated from the ceramic materials is critical for these applications. The progress in application of a patented fiber process developed by Clemson University for the fabrication of superconducting wires is reviewed. The effect of particle size and heat treatment on the quality of materials is discussed. Recent advances made at Christopher Newport College in the development of micro-ohm resistance electrical contacts which are capable of carrying the highest reported direct current to this material is presented.

Development of superconducting YBa2Cu3O(x) wires with low resistance electrical contacts

NASA Astrophysics Data System (ADS)

Buoncristiani, A. M.; Byvik, C. E.; Caton, R.; Selim, R.; Lee, B. I.; Modi, V.; Sherrill, M.; Leigh, H. D.; Fain, C. C.; Lewis, G.

Materials exhibiting superconductivity above liquid nitrogen temperatures (77 K) will enable new applications of this phenomena. One of the first commercial applications of this technology will be superconducting magnets for medical imaging. However, a large number of aerospace applications of the high temperature superconducting materials have also been identified. These include magnetic suspension and balance of models in wind tunnels and resistanceless leads to anemometers. The development of superconducting wires fabricated from the ceramic materials is critical for these applications. The progress in application of a patented fiber process developed by Clemson University for the fabrication of superconducting wires is reviewed. The effect of particle size and heat treatment on the quality of materials is discussed. Recent advances made at Christopher Newport College in the development of micro-ohm resistance electrical contacts which are capable of carrying the highest reported direct current to this material is presented.

Low-cost compact thermal imaging sensors for body temperature measurement

NASA Astrophysics Data System (ADS)

Han, Myung-Soo; Han, Seok Man; Kim, Hyo Jin; Shin, Jae Chul; Ahn, Mi Sook; Kim, Hyung Won; Han, Yong Hee

2013-06-01

This paper presents a 32x32 microbolometer thermal imaging sensor for human body temperature measurement. Waferlevel vacuum packaging technology allows us to get a low cost and compact imaging sensor chip. The microbolometer uses V-W-O film as sensing material and ROIC has been designed 0.35-um CMOS process in UMC. A thermal image of a human face and a hand using f/1 lens convinces that it has a potential of human body temperature for commercial use.

Focused technology: Nuclear propulsion

NASA Technical Reports Server (NTRS)

Miller, Thomas J.

1991-01-01

The topics presented are covered in viewgraph form and include: nuclear thermal propulsion (NTP), which challenges (1) high temperature fuel and materials, (2) hot hydrogen environment, (3) test facilities, (4) safety, (5) environmental impact compliance, and (6) concept development, and nuclear electric propulsion (NEP), which challenges (1) long operational lifetime, (2) high temperature reactors, turbines, and radiators, (3) high fuel burn-up reactor fuels, and designs, (4) efficient, high temperature power conditioning, (5) high efficiency, and long life thrusters, (6) safety, (7) environmental impact compliance, and (8) concept development.

High Temperature Polymer Matrix Composites

NASA Technical Reports Server (NTRS)

1985-01-01

These are the proceedings of the High Temperature Polymer Matrix Composites Conference held at the NASA Lewis Research Center on March 16 to 18, 1983. The purpose of the conference is to provide scientists and engineers working in the field of high temperature polymer matrix composites an opportunity to review, exchange, and assess the latest developments in this rapidly expanding area of materials technology. Technical papers are presented in the following areas: (1) matrix development; (2) adhesive development; (3) characterization; (4) environmental effects; and (5) applications.

Meeting No Resistance.

ERIC Educational Resources Information Center

Buzdin, Alexander; Varlamov, Andrey

1991-01-01

Describes the history and the development of the field of superconductivity. Identifies the significant interaction of electrons to form Cooper pairs. Presents background theory, describes approaches, and discusses problems encountered in the search for better high temperature superconducting materials. Provides technological applications of…

EMERGING TECHNOLOGY REPORT: DEVELOPMENT OF A PHOTOTHERMAL DETOXIFICATION UNIT

EPA Science Inventory

There has long been interest in utilizing photochemical methods for destroying hazardous organic materials. Unfortunately, the direct application of classic, low temperature photochemical processes to hazardous waste detoxification are often too slow to be practical for wide spr...

Thermal and mechanical properties of selected 3D printed thermoplastics in the cryogenic temperature regime

NASA Astrophysics Data System (ADS)

Weiss, K.-P.; Bagrets, N.; Lange, C.; Goldacker, W.; Wohlgemuth, J.

2015-12-01

Insulating materials for use in cryogenic boundary conditions are still limited to a proved selection as Polyamid, Glasfiber reinforced resins, PEEK, Vespel etc. These materials are usually formed to parts by mechanical machining or sometimes by cast methods. Shaping complex geometries in one piece is limited. Innovative 3D printing is now an upcoming revolutionary technology to construct functional parts from a couple of thermoplastic materials as ABS, Nylon and others which possess quite good mechanical stability and allow realizing very complex shapes with very subtle details. Even a wide range of material mixtures is an option and thermal treatments can be used to finish the material structure for higher performance. The use of such materials in cryogenic environment is very attractive but so far poor experience exists. In this paper, first investigations of the thermal conductivity, expansion and mechanical strength are presented for a few selected commercial 3D material samples to evaluate their application prospects in the cryogenic temperature regime.

Low-Temperature Solution Processable Electrodes for Piezoelectric Sensors Applications

NASA Astrophysics Data System (ADS)

Tuukkanen, Sampo; Julin, Tuomas; Rantanen, Ville; Zakrzewski, Mari; Moilanen, Pasi; Lupo, Donald

2013-05-01

Piezoelectric thin-film sensors are suitable for a wide range of applications from physiological measurements to industrial monitoring systems. The use of flexible materials in combination with high-throughput printing technologies enables cost-effective manufacturing of custom-designed, highly integratable piezoelectric sensors. This type of sensor can, for instance, improve industrial process control or enable the embedding of ubiquitous sensors in our living environment to improve quality of life. Here, we discuss the benefits, challenges and potential applications of piezoelectric thin-film sensors. The piezoelectric sensor elements are fabricated by printing electrodes on both sides of unmetallized poly(vinylidene fluoride) film. We show that materials which are solution processable in low temperatures, biocompatible and environmental friendly are suitable for use as electrode materials in piezoelectric sensors.

Ceramic Technology For Advanced Heat Engines Project

DOE Office of Scientific and Technical Information (OSTI.GOV)

Not Available

1990-12-01

Significant accomplishments in fabricating ceramic components for the Department of Energy (DOE), National Aeronautics and Space Administration (NASA), and Department of Defense (DoD) advanced heat engine programs have provided evidence that the operation of ceramic parts in high-temperature engine environments is feasible. However, these programs have also demonstrated that additional research is needed in materials and processing development, design methodology, and data base and life prediction before industry will have a sufficient technology base from which to produce reliable cost-effective ceramic engine components commercially. The objective of the project is to develop the industrial technology base required for reliable ceramicsmore » for application in advanced automotive heat engines. The project approach includes determining the mechanisms controlling reliability, improving processes for fabricating existing ceramics, developing new materials with increased reliability, and testing these materials in simulated engine environments to confirm reliability. Although this is a generic materials project, the focus is on the structural ceramics for advanced gas turbine and diesel engines, ceramic bearings and attachments, and ceramic coatings for thermal barrier and wear applications in these engines. This advanced materials technology is being developed in parallel and close coordination with the ongoing DOE and industry proof of concept engine development programs. To facilitate the rapid transfer of this technology to U.S. industry, the major portion of the work is being done in the ceramic industry, with technological support from government laboratories, other industrial laboratories, and universities. Abstracts prepared for appropriate papers.« less

Simulation of Field Dependence of Critical Current Densities of Bulk High Tc Superconducting Materials regarding Thermally Activated Flux Motion

NASA Astrophysics Data System (ADS)

Santosh, M.; Naik, S. Pavan Kumar; Koblischka, M. R.

2017-07-01

In the upcoming generation, bulk high temperature superconductors (HTS) will play a crucial and a promising role in numerous industrial applications ranging from Maglev trains to magnetic resonance imaging, etc. Especially, the bulk HTS as permanent magnets are suitable due to the fact that they can trap magnetic fields being several orders of magnitude higher than those of the best hard ferromagnets. The bulk HTS LREBa2Cu3O7-δ (LREBCO or LRE-123, LRE: Y, Gd, etc.,) materials could obtain very powerful compact superconducting super-magnets, which can be operated at the cheaper liquid nitrogen temperature or below due to higher critical temperatures (i.e., ∼90 K). As a result, the new advanced technology can be utilized in a more attractive manner for a variety of technological and medical applications which have the capacity to revolutionize the field. An understanding of the magnetic field dependence of the critical current density (J c(H)) is important to develop better adapted materials. To achieve this goal, a variety of Jc (H) behaviours of bulk LREBCO samples were modelled regarding thermally activated flux motion. In essence, the Jc (H) curves follows a certain criterion where an exponential model is applied. However, to fit the complete Jc (H) curve of the LRE-123 samples an unique model is necessary to explain the behavior at low and high fields. The modelling of the various superconducting materials could be understood in terms of the pinning mechanisms.

DOE Office of Scientific and Technical Information (OSTI.GOV)

Westover, Tyler; Emerson, Rachel Marie

Torrefaction is the thermal treatment of materials in the absence of oxygen in the temperature range of 200 to 300 °C and has been shown to improve handling and grinding properties, hydrophobicity, volatiles content, energy density, and combustion performance of renewable energy biomass feedstock materials. The disadvantages of torrefaction are its relative high cost compared to the low value input feedstock material and the energy that can be lost to volatized gases. This work will demonstrate a new technology developed by Advanced Torrefaction Systems (ATS), known as TorreCat™ Technology, that uses an oxidation catalyst in a closed system to combustmore » and destroy volatile organic compounds (VOCs) and other byproducts produced in the torrefaction process. An oxidation catalyst is a substance, or a combination of substances, that accelerate the rate of a chemical reaction without being consumed by the reaction. Catalytic combustion is a reaction that occurs at temperatures 50% lower than traditional combustion, such that essentially no NOx is created. The output of the oxidation catalyst (flue gas) consists mainly of superheated steam and inert gases (carbon dioxide and nitrogen), which can be used for heat in the thermal treatment process. INL has previously developed a pilot-scale Continuous-Feed Thermal Treatment System (CFTTS) that has 10 kg/hr capacity but does not reform the flue gas to reduce environmental concerns or capture all available heat from the biomass material. Using the TorreCat™ technology in INL’s thermal treatment system will demonstrate increased thermal efficiencies during the treatment process as well as reduced environmental impact and clean-up costs. The objective of this project is to determine the effectiveness of the Torrecat™ technology to reform the flue gas and capture as much of its heat content as possible.« less

Heteroepitaxial Growth of Germanium-on-Silicon Using Ultrahigh-Vacuum Chemical Vapor Deposition with RF Plasma Enhancement

NASA Astrophysics Data System (ADS)

Alharthi, Bader; Grant, Joshua M.; Dou, Wei; Grant, Perry C.; Mosleh, Aboozar; Du, Wei; Mortazavi, Mansour; Li, Baohua; Naseem, Hameed; Yu, Shui-Qing

2018-05-01

Germanium (Ge) films have been grown on silicon (Si) substrate by ultrahigh-vacuum chemical vapor deposition with plasma enhancement (PE). Argon plasma was generated using high-power radiofrequency (50 W) to assist in germane decomposition at low temperature. The growth temperature was varied in the low range of 250°C to 450°C to make this growth process compatible with complementary metal-oxide-semiconductor technology. The material and optical properties of the grown Ge films were investigated. The material quality was determined by Raman and x-ray diffraction techniques, revealing growth of crystalline films in the temperature range of 350°C to 450°C. Photoluminescence spectra revealed improved optical quality at growth temperatures of 400°C and 450°C. Furthermore, material quality study using transmission electron microscopy revealed existence of defects in the Ge layer grown at 400°C. Based on the etch pit density, the average threading dislocation density in the Ge layer obtained at this growth temperature was measured to be 4.5 × 108 cm-2. This result was achieved without any material improvement steps such as use of graded buffer or thermal annealing. Comparison between PE and non-plasma-enhanced growth, in the same machine at otherwise the same growth conditions, indicated increased growth rate and improved material and optical qualities for PE growth.

FY2017 Materials Annual Progress Report

DOE Office of Scientific and Technical Information (OSTI.GOV)

Wu, Felix; Gibbs, Jerry; Kleinbaum, Sarah

The Materials Technology subprogram supports the Vehicle Technology Office’s mission to help consumers and businesses reduce their transportation energy costs while meeting or exceeding vehicle performance expectations. The Propulsion Materials research portfolio seeks to develop higher performance materials that can withstand increasingly extreme environments and address the future properties needs of a variety of high efficiency powertrain types, sizes, fueling concepts, and combustion modes. Advanced Lightweight Materials research enables improvements in fuel economy by providing properties that are equal to or better than traditional materials at a lower weight. Because it takes less energy to accelerate a lighter object, replacingmore » cast iron and traditional steel components with lightweight materials such as high-strength steel, magnesium (Mg), aluminum (Al), and polymer composites can directly reduce a vehicle’s fuel consumption. Materials technology activities focus on the following cost and performance targets: (1) enable a 25 percent weight reduction for light-duty vehicles including body, chassis, and interior as compared to a 2012 baseline at no more than a $5/lb-saved increase in cost; and (2) validate a 25 percent improvement in high temperature (300°C) component strength relative to components made with 2010 baseline cast Al alloys (A319 or A356) for improved efficiency light-duty engines.« less

Mechanistic Studies Of Combustion And Structure Formation During Combustion Synthesis Of Advanced Materials: Phase Separation Mechanism For Bio-Alloys

NASA Technical Reports Server (NTRS)

Varma, A.; Lau, C.; Mukasyan, A.

2003-01-01

Among all implant materials, Co-Cr-Mo alloys demonstrate perhaps the most useful balance of resistance to corrosion, fatigue and wear, along with strength and biocompatibility [1]. Currently, these widely used alloys are produced by conventional furnace technology. Owing to high melting points of the main alloy elements (e.g. Tm.p.(Co) 1768 K), high-temperature furnaces and long process times (several hours) are required. Therefore, attempts to develop more efficient and flexible methods for production of such alloys with superior properties are of great interest. The synthesis of materials using combustion phenomena is an advanced approach in powder metallurgy [2]. The process is characterized by unique conditions involving extremely fast heating rates (up to 10(exp 6 K/s), high temperatures (up to 3500 K), and short reaction times (on the order of seconds). As a result, combustion synthesis (CS) offers several attractive advantages over conventional metallurgical processing and alloy development technologies. The foremost is that solely the heat of chemical reaction (instead of an external source) supplies the energy for the synthesis. Also, simple equipment, rather than energy-intensive high-temperature furnaces, is sufficient. This work was devoted to experiments on CS of Co-based alloys by utilizing thermite (metal oxide-reducing metal) reactions, where phase separation subsequently produces materials with tailored compositions and properties. Owing to high reaction exothermicity, the CS process results in a significant increase of temperature (up to 3000 C), which is higher than melting points of all products. Since the products differ in density, phase separation may be a gravitydriven process: the heavy (metallic phase) settles while the light (slag) phase floats. The goal was to determine if buoyancy is indeed the major mechanism that controls phase segregation.

Flexible Friction Stir Joining Technology

DOE Office of Scientific and Technical Information (OSTI.GOV)

Feng, Zhili; Lim, Yong Chae; Mahoney, Murray

2015-07-23

Reported herein is the final report on a U.S. Department of Energy (DOE) Advanced Manufacturing Office (AMO) project with industry cost-share that was jointly carried out by Oak Ridge National Laboratory (ORNL), ExxonMobil Upstream Research Company (ExxonMobil), and MegaStir Technologies (MegaStir). The project was aimed to advance the state of the art of friction stir welding (FSW) technology, a highly energy-efficient solid-state joining process, for field deployable, on-site fabrications of large, complex and thick-sectioned structures of high-performance and high-temperature materials. The technology innovations developed herein attempted to address two fundamental shortcomings of FSW: 1) the inability for on-site welding andmore » 2) the inability to weld thick section steels, both of which have impeded widespread use of FSW in manufacturing. Through this work, major advance has been made toward transforming FSW technology from a “specialty” process to a mainstream materials joining technology to realize its pervasive energy, environmental, and economic benefits across industry.« less

Attachment of Free Filament Thermocouples for Temperature Measurements on CMC

NASA Technical Reports Server (NTRS)

Lei, Jih-Fen; Cuy, Michael D.; Wnuk, Stephen P.

1997-01-01

Ceramic Matrix Composites (CMC) are being developed for use as enabling materials for advanced aeropropulsion engine and high speed civil transport applications. The characterization and testing of these advanced materials in hostile, high-temperature environments require accurate measurement of the material temperatures. Commonly used wire Thermo-Couples (TC) can not be attached to this ceramic based material via conventional spot-welding techniques. Attachment of wire TC's with commercially available ceramic cements fail to provide sufficient adhesion at high temperatures. While advanced thin film TC technology provides minimally intrusive surface temperature measurement and has good adhesion on the CMC, its fabrication requires sophisticated and expensive facilities and is very time consuming. In addition, the durability of lead wire attachments to both thin film TC's and the substrate materials requires further improvement. This paper presents a newly developed attachment technique for installation of free filament wire TC's with a unique convoluted design on ceramic based materials such as CMC's. Three CMC's (SiC/SiC CMC and alumina/alumina CMC) instrumented with type IC, R or S wire TC's were tested in a Mach 0.3 burner rig. The CMC temperatures measured from these wire TC's were compared to that from the facility pyrometer and thin film TC's. There was no sign of TC delamination even after several hours exposure to 1200 C. The test results proved that this new technique can successfully attach wire TC's on CMC's and provide temperature data in hostile environments. The sensor fabrication process is less expensive and requires very little time compared to that of the thin film TC's. The same installation technique/process can also be applied to attach lead wires for thin film sensor systems.

High temperature experimental characterization of microscale thermoelectric effects

NASA Astrophysics Data System (ADS)

Favaloro, Tela

Thermoelectric devices have been employed for many years as a reliable energy conversion technology for applications ranging from the cooling of sensors or charge coupled devices to the direct conversion of heat into electricity for remote power generation. However, its relatively low conversion efficiency has limited the implementation of thermoelectric materials for large scale cooling and waste heat recovery applications. Recent advances in semiconductor growth technology have enabled the precise and selective engineering of material properties to improve the thermoelectric figure of merit and thus the efficiency of thermoelectric devices. Accurate characterization at the intended operational temperature of novel thermoelectric materials is a crucial component of the optimization process in order to fundamentally understand material behavior and evaluate performance. The objective of this work is to provide the tools necessary to characterize high efficiency bulk and thin-film materials for thermoelectric energy conversion. The techniques developed here are not bound to specific material or devices, but can be generalized to any material system. Thermoreflectance imaging microscopy has proven to be invaluable for device thermometry owing to its high spatial and temporal resolutions. It has been utilized in this work to create two-dimensional temperature profiles of thermoelectric devices during operation used for performance analysis of novel materials, identification of defects, and visualization of high speed transients in a high-temperature imaging thermostat. We report the development of a high temperature imaging thermostat capable of high speed transient thermoelectric characterization. In addition, we present a noninvasive method for thermoreflectance coefficient calibration ideally suited for vacuum and thus high temperature employment. This is the first analysis of the thermoreflectance coefficient of commonly used metals at high-temperatures. High temperature vacuum thermostats are designed and fabricated with optical imaging capability and interchangeable measurement stages for various electrical and thermoelectric characterizations. We demonstrate the simultaneous measurement of in-plane electrical conductivity and Seebeck coefficient of thin-film or bulk thermoelectric materials. Furthermore, we utilize high-speed circuitry to implement the transient Harman technique and directly determine the cross-plane figure of merit of thin film thermoelectric materials at high temperatures. Transient measurements on thin film devices are subject to complications from the growth substrate, non-ideal contacts and other detrimental thermal and electrical effects. A strategy is presented for optimizing device geometry to mitigate the impact of these parasitics. This design enabled us to determine the cross-plane thermoelectric material properties in a single high temperature measurement of a 25mum InGaAs thin film with embedded ErAs (0.2%) nanoparticles using the bipolar transient Harman technique in conjunction with thermoreflectance thermal imaging. This approach eliminates discrepancies and potential device degradation from the multiple measurements necessary to obtain individual material parameters. Finite element method simulations are used to analyze non-uniform current and temperature distributions over the device area and determine the three dimensional current path for accurate extraction of material properties from the thermal images. Results match with independent measurements of thermoelectric material properties for the same material composition, validating this approach. We apply high magnification thermoreflectance imaging to create temperature maps of vanadium dioxide nanobeams and examine electro-thermal energy conversion along the nanobeam length. The metal to insulator transition of strongly correlated materials is subject to strong lattice coupling which brings about the unique one-dimensional alignment of metal-insulator domains along nanobeams. Many studies have investigated the effects of stress on the metal to insulator transition and hence the phase boundary, but few have directly examined the temperature profile across the metal-insulating interface. Here, thermoreflectance microscopy reveals the underlying behavior of single-crystalline VO2 nanobeams in the phase coexisting regime. We directly observe highly localized alternating Peltier heating and cooling as well as Joule heating concentrated at the domain interfaces, indicating the significance of the domain walls and band offsets. Moreover, we are able to elucidate strain accumulation along the nanobeam and distinguish between two insulating phases of VO 2 through detection of the opposite polarity of their respective thermoreflectance coefficients.

International SAMPE Symposium and Exhibition, 36th, San Diego, CA, Apr. 15-18, 1991, Proceedings. Books 1 2

DOE Office of Scientific and Technical Information (OSTI.GOV)

Stinson, J.; Adsit, R.; Gordaninejad, F.

This symposium presents papers in the fields of the design and development of space system structures, advanced textile preforming, low-cost processing of materials, and nondestructive testing. Also presented are adhesive and bonding technologies, resin transfer molding, filament winding, high-temperature composites, thermoplastic material properties, composites for marine environments, and thermoplastic processes and applications.

Solutions for Critical Raw Materials under Extreme Conditions: A Review

PubMed Central

Grilli, Maria Luisa; Bellezze, Tiziano; Gamsjäger, Ernst; Rinaldi, Antonio; Novak, Pavel; Balos, Sebastian; Piticescu, Radu Robert; Ruello, Maria Letizia

2017-01-01

In Europe, many technologies with high socio-economic benefits face materials requirements that are often affected by demand-supply disruption. This paper offers an overview of critical raw materials in high value alloys and metal-matrix composites used in critical applications, such as energy, transportation and machinery manufacturing associated with extreme working conditions in terms of temperature, loading, friction, wear and corrosion. The goal is to provide perspectives about the reduction and/or substitution of selected critical raw materials: Co, W, Cr, Nb and Mg. PMID:28772645

Thermal Effects on Microstructural Heterogeneity of Inconel 718 Materials Fabricated by Electron Beam Melting

DOE Office of Scientific and Technical Information (OSTI.GOV)

Sames, William J.; Unocic, Kinga A.; Dehoff, Ryan R.

2014-07-28

Additive manufacturing (AM) technologies, also known as 3D printing, have demonstrated the potential to fabricate complex geometrical components, but the resulting microstructures and mechanical properties of these materials are not well understood due to unique and complex thermal cycles observed during processing. The electron beam melting (EBM) process is unique because the powder bed temperature can be elevated and maintained at temperatures over 1000 °C for the duration of the process. This results in three specific stages of microstructural phase evolution: (a) rapid cool down from the melting temperature to the process temperature, (b) extended hold at the process temperature,more » and (c) slow cool down to the room temperature. In this work, the mechanisms for reported microstructural differences in EBM are rationalized for Inconel 718 based on measured thermal cycles, preliminary thermal modeling, and computational thermodynamics models. The relationship between processing parameters, solidification microstructure, interdendritic segregation, and phase precipitation (δ, γ´, and γ´´) are discussed.« less

Novel particle and radiation sources and advanced materials

NASA Astrophysics Data System (ADS)

Mako, Frederick

2016-03-01

The influence Norman Rostoker had on the lives of those who had the pleasure of knowing him is profound. The skills and knowledge I gained as a graduate student researching collective ion acceleration has fueled a career that has evolved from particle beam physics to include particle and radiation source development and advanced materials research, among many other exciting projects. The graduate research performed on collective ion acceleration was extended by others to form the backbone for laser driven plasma ion acceleration. Several years after graduate school I formed FM Technologies, Inc., (FMT), and later Electron Technologies, Inc. (ETI). Currently, as the founder and president of both FMT and ETI, the Rostoker influence can still be felt. One technology that we developed is a self-bunching RF fed electron gun, called the Micro-Pulse Gun (MPG). The MPG has important applications for RF accelerators and microwave tube technology, specifically clinically improved medical linacs and "green" klystrons. In addition to electron beam and RF source research, knowledge of materials and material interactions gained indirectly in graduate school has blossomed into breakthroughs in materials joining technologies. Most recently, silicon carbide joining technology has been developed that gives robust helium leak tight, high temperature and high strength joints between ceramic-to-ceramic and ceramic-to-metal. This joining technology has the potential to revolutionize the ethylene production, nuclear fuel and solar receiver industries by finally allowing for the practical use of silicon carbide as furnace coils, fuel rods and solar receptors, respectively, which are applications that have been needed for decades.

Novel particle and radiation sources and advanced materials

DOE Office of Scientific and Technical Information (OSTI.GOV)

Mako, Frederick

The influence Norman Rostoker had on the lives of those who had the pleasure of knowing him is profound. The skills and knowledge I gained as a graduate student researching collective ion acceleration has fueled a career that has evolved from particle beam physics to include particle and radiation source development and advanced materials research, among many other exciting projects. The graduate research performed on collective ion acceleration was extended by others to form the backbone for laser driven plasma ion acceleration. Several years after graduate school I formed FM Technologies, Inc., (FMT), and later Electron Technologies, Inc. (ETI). Currently,more » as the founder and president of both FMT and ETI, the Rostoker influence can still be felt. One technology that we developed is a self-bunching RF fed electron gun, called the Micro-Pulse Gun (MPG). The MPG has important applications for RF accelerators and microwave tube technology, specifically clinically improved medical linacs and “green” klystrons. In addition to electron beam and RF source research, knowledge of materials and material interactions gained indirectly in graduate school has blossomed into breakthroughs in materials joining technologies. Most recently, silicon carbide joining technology has been developed that gives robust helium leak tight, high temperature and high strength joints between ceramic-to-ceramic and ceramic-to-metal. This joining technology has the potential to revolutionize the ethylene production, nuclear fuel and solar receiver industries by finally allowing for the practical use of silicon carbide as furnace coils, fuel rods and solar receptors, respectively, which are applications that have been needed for decades.« less

Graphene-based vdW heterostructure Induced High-efficiency Thermoelectric Devices

NASA Astrophysics Data System (ADS)

Liang, Shijun; Ang, Lay Kee

Thermoelectric material (TE) can convert the heat into electricity to provide green energy source and its performance is characterized by a figure of merit (ZT) parameter. Traditional TE materials only give ZT equal to around 1 at room temperature. But, it is believed that materials with ZT >3 will find wide applications at this low temperature range. Prior studies have implied that the interrelation between electric conductivity and lattice thermal conductivity renders the goal of engineering ZT of bulk materials to reach ZT >3. In this work, we propose a high-efficiency van del Waals (vdW) heterostructure-based thermionic device with graphene electrodes, which is able to harvest wasted heat (around 400K) based on the newly established thermionic emission law of graphene electrodes instead of Seebeck effect, to boost the efficiency of power generation over 10% around room temperature. The efficiency can be above 20% if the Schottky barrier height and cross-plane lattice thermal conductivity of transition metal dichacogenides (TMD) materials can be fine-engineered. As a refrigerator at 260 K, the efficiency is 50% to 80% of Carnot efficiency. Finally, we identify two TMD materials as the ideal candidates of graphene/TMD/graphene devices based on the state-of-art technology.

Multi-Dimensional, Non-Pyrolyzing Ablation Test Problems

NASA Technical Reports Server (NTRS)

Risch, Tim; Kostyk, Chris

2016-01-01

Non-pyrolyzingcarbonaceous materials represent a class of candidate material for hypersonic vehicle components providing both structural and thermal protection system capabilities. Two problems relevant to this technology are presented. The first considers the one-dimensional ablation of a carbon material subject to convective heating. The second considers two-dimensional conduction in a rectangular block subject to radiative heating. Surface thermochemistry for both problems includes finite-rate surface kinetics at low temperatures, diffusion limited ablation at intermediate temperatures, and vaporization at high temperatures. The first problem requires the solution of both the steady-state thermal profile with respect to the ablating surface and the transient thermal history for a one-dimensional ablating planar slab with temperature-dependent material properties. The slab front face is convectively heated and also reradiates to a room temperature environment. The back face is adiabatic. The steady-state temperature profile and steady-state mass loss rate should be predicted. Time-dependent front and back face temperature, surface recession and recession rate along with the final temperature profile should be predicted for the time-dependent solution. The second problem requires the solution for the transient temperature history for an ablating, two-dimensional rectangular solid with anisotropic, temperature-dependent thermal properties. The front face is radiatively heated, convectively cooled, and also reradiates to a room temperature environment. The back face and sidewalls are adiabatic. The solution should include the following 9 items: final surface recession profile, time-dependent temperature history of both the front face and back face at both the centerline and sidewall, as well as the time-dependent surface recession and recession rate on the front face at both the centerline and sidewall. The results of the problems from all submitters will be collected, summarized, and presented at a later conference.

Investment casting using multi-jet modelling patterns: the thermogravimetric analysis of visijet® SR200 UV curable acrylate plastic

NASA Astrophysics Data System (ADS)

Hafsa, M. N.; Ibrahim, M.; Sharif, S.

2013-12-01

Rapid Prototyping (RP) technology is actively studied to be implemented in Investment Casting (IC) process. Nowadays RP techniques are studied for their feasibility as IC master patterns, in terms of pattern collapsibility and drainage during burnout. The purpose of the study is to determine the characteristic of Visijet® SR200 acrylate material during burnout process. Traditional IC patterns made from wax have properties that limit their application in precision casting, especially for parts with thin geometries that readily break or deform when handled or dipped in the refractory slurry. Furthermore, it is not economical when producing a small number of parts. Non wax patterns fabricated for IC process, revealed ceramic shell cracking due to excessive thermal expansions, incomplete collapsibility of pattern during burnout, residual ash and poor surface finish. Thermogravimetric analysis (TGA) was used to measured the weight loss of acrylate material as the temperature was increased. TGA measured the change of material's mass as it is heated. It represents the decomposition temperature after being subjected to varying temperatures, as well as the amount of residual ash. In this experiment, the temperature range was from 20°C to 700°C with 5°C increment. Experiment results show the values of material's optimum reaction temperature and decomposing temperature of Visijet® SR200 acrylate. The percentages of remaining materials were also monitored throughout the process to obtain the amount of residual ash. All of the temperature values obtained is a resemblance for the actual burnout process and can be used as references.

Study on the technology of compound enzymatic hydrolysis of whole passion fruit

NASA Astrophysics Data System (ADS)

Yang, Yu-xia; Duan, Zhen-hua; Kang, Chao; Zhu, Xiang-hao; Li, Ding-jin

2017-12-01

Fresh Whole Passion Fruit was used as raw material, The enzymatic hydrolysis technology of Passion Fruit by Complex enzyme were studied, The effects of enzyme dosage, Enzyme ratio(cellulose: pectinase), pH, temperature and time on the hydrolysis were investigated by single-tests and orthogonal tests, the hydrolysis indicators of single-factor tests and orthogonal tests were juice yield. The optimal hydrolysis conditions of Passion Fruit by Complex enzyme were enzyme dosage 0.12%, Enzyme ratio 5:1, hydrolysis temperature 50°C, pH4.0 and time 3.5 h. Under such conditions, juice yield of Passion Fruit was 92.91%.

Ceramic Integration Technologies for Aerospace and Energy Systems: Technical Challenges and Opportunities

NASA Technical Reports Server (NTRS)

Singh, Mrityunjay

2007-01-01

Ceramic integration technology has been recognized as an enabling technology for the implementation of advanced ceramic systems in a number of high-temperature applications in aerospace, power generation, nuclear, chemical, and electronic industries. Various ceramic integration technologies (joining, brazing, attachments, repair, etc.) play a role in fabrication and manufacturing of large and complex shaped parts of various functionalities. However, the development of robust and reliable integrated systems with optimum performance requires the understanding of many thermochemical and thermomechanical factors, particularly for high temperature applications. In this presentation, various challenges and opportunities in design, fabrication, and testing of integrated similar (ceramic-ceramic) and dissimilar (ceramic-metal) material systems will be discussed. Experimental results for bonding and integration of SiC based LDI fuel injector, high conductivity C/C composite based heat rejection system, solid oxide fuel cells system, ultra high temperature ceramics for leading edges, and ceramic composites for thermostructural applications will be presented. Potential opportunities and need for the development of innovative design philosophies, approaches, and integrated system testing under simulated application conditions will also be discussed.

Application of process analytical technology for monitoring freeze-drying of an amorphous protein formulation: use of complementary tools for real-time product temperature measurements and endpoint detection.

PubMed

Schneid, Stefan C; Johnson, Robert E; Lewis, Lavinia M; Stärtzel, Peter; Gieseler, Henning

2015-05-01

Process analytical technology (PAT) and quality by design have gained importance in all areas of pharmaceutical development and manufacturing. One important method for monitoring of critical product attributes and process optimization in laboratory scale freeze-drying is manometric temperature measurement (MTM). A drawback of this innovative technology is that problems are encountered when processing high-concentrated amorphous materials, particularly protein formulations. In this study, a model solution of bovine serum albumin and sucrose was lyophilized at both conservative and aggressive primary drying conditions. Different temperature sensors were employed to monitor product temperatures. The residual moisture content at primary drying endpoints as indicated by temperature sensors and batch PAT methods was quantified from extracted sample vials. The data from temperature probes were then used to recalculate critical product parameters, and the results were compared with MTM data. The drying endpoints indicated by the temperature sensors were not suitable for endpoint indication, in contrast to the batch methods endpoints. The accuracy of MTM Pice data was found to be influenced by water reabsorption. Recalculation of Rp and Pice values based on data from temperature sensors and weighed vials was possible. Overall, extensive information about critical product parameters could be obtained using data from complementary PAT tools. © 2015 Wiley Periodicals, Inc. and the American Pharmacists Association.

Structural materials challenges for advanced reactor systems

NASA Astrophysics Data System (ADS)

Yvon, P.; Carré, F.

2009-03-01

Key technologies for advanced nuclear systems encompass high temperature structural materials, fast neutron resistant core materials, and specific reactor and power conversion technologies (intermediate heat exchanger, turbo-machinery, high temperature electrolytic or thermo-chemical water splitting processes, etc.). The main requirements for the materials to be used in these reactor systems are dimensional stability under irradiation, whether under stress (irradiation creep or relaxation) or without stress (swelling, growth), an acceptable evolution under ageing of the mechanical properties (tensile strength, ductility, creep resistance, fracture toughness, resilience) and a good behavior in corrosive environments (reactor coolant or process fluid). Other criteria for the materials are their cost to fabricate and to assemble, and their composition could be optimized in order for instance to present low-activation (or rapid desactivation) features which facilitate maintenance and disposal. These requirements have to be met under normal operating conditions, as well as in incidental and accidental conditions. These challenging requirements imply that in most cases, the use of conventional nuclear materials is excluded, even after optimization and a new range of materials has to be developed and qualified for nuclear use. This paper gives a brief overview of various materials that are essential to establish advanced systems feasibility and performance for in pile and out of pile applications, such as ferritic/martensitic steels (9-12% Cr), nickel based alloys (Haynes 230, Inconel 617, etc.), oxide dispersion strengthened ferritic/martensitic steels, and ceramics (SiC, TiC, etc.). This article gives also an insight into the various natures of R&D needed on advanced materials, including fundamental research to investigate basic physical and chemical phenomena occurring in normal and accidental operating conditions, lab-scale tests to characterize candidate materials mechanical properties and corrosion resistance, as well as component mock-up tests on technology loops to validate potential applications while accounting for mechanical design rules and manufacturing processes. The selection, assessment and validation of materials necessitate a large number of experiments, involving rare and expensive facilities such as research reactors, hot laboratories or corrosion loops. The modelling and the codification of the behaviour of materials will always involve the use of such technological experiments, but it is of utmost importance to develop also a predictive material science. Finally, the paper stresses the benefit of prospects of multilateral collaboration to join skills and share efforts of R&D to achieve in the nuclear field breakthroughs on materials that have already been achieved over the past decades in other industry sectors (aeronautics, metallurgy, chemistry, etc.).

Low-temperature deposition manufacturing: A novel and promising rapid prototyping technology for the fabrication of tissue-engineered scaffold.

PubMed

Liu, Wei; Wang, Daming; Huang, Jianghong; Wei, You; Xiong, Jianyi; Zhu, Weimin; Duan, Li; Chen, Jielin; Sun, Rong; Wang, Daping

2017-01-01

Developed in recent years, low-temperature deposition manufacturing (LDM) represents one of the most promising rapid prototyping technologies. It is not only based on rapid deposition manufacturing process but also combined with phase separation process. Besides the controlled macropore size, tissue-engineered scaffold fabricated by LDM has inter-connected micropores in the deposited lines. More importantly, it is a green manufacturing process that involves non-heating liquefying of materials. It has been employed to fabricate tissue-engineered scaffolds for bone, cartilage, blood vessel and nerve tissue regenerations. It is a promising technology in the fabrication of tissue-engineered scaffold similar to ideal scaffold and the design of complex organs. In the current paper, this novel LDM technology is introduced, and its control parameters, biomedical applications and challenges are included and discussed as well. Copyright © 2016 Elsevier B.V. All rights reserved.

Nanobonding: A key technology for emerging applications in health and environmental sciences

NASA Astrophysics Data System (ADS)

Howlader, Matiar M. R.; Deen, M. Jamal; Suga, Tadatomo

2015-03-01

In this paper, surface-activation-based nanobonding technology and its applications are described. This bonding technology allows for the integration of electronic, photonic, fluidic and mechanical components into small form-factor systems for emerging sensing and imaging applications in health and environmental sciences. Here, we describe four different nanobonding techniques that have been used for the integration of various substrates — silicon, gallium arsenide, glass, and gold. We use these substrates to create electronic (silicon), photonic (silicon and gallium arsenide), microelectromechanical (glass and silicon), and fluidic (silicon and glass) components for biosensing and bioimaging systems being developed. Our nanobonding technologies provide void-free, strong, and nanometer scale bonding at room temperature or at low temperatures (<200 °C), and do not require chemicals, adhesives, or high external pressure. The interfaces of the nanobonded materials in ultra-high vacuum and in air correspond to covalent bonds, and hydrogen or hydroxyl bonds, respectively.

Experimental and numerical modeling research of rubber material during microwave heating process

NASA Astrophysics Data System (ADS)

Chen, Hailong; Li, Tao; Li, Kunling; Li, Qingling

2018-05-01

This paper aims to investigate the heating behaviors of block rubber by experimental and simulated method. The COMSOL Multiphysics 5.0 software was utilized in numerical simulation work. The effects of microwave frequency, power and sample size on temperature distribution are examined. The effect of frequency on temperature distribution is obvious. The maximum and minimum temperatures of block rubber increase first and then decrease with frequency increasing. The microwave heating efficiency is maximum in the microwave frequency of 2450 MHz. However, more uniform temperature distribution is presented in other microwave frequencies. The influence of microwave power on temperature distribution is also remarkable. The smaller the power, the more uniform the temperature distribution on the block rubber. The effect of power on microwave heating efficiency is not obvious. The effect of sample size on temperature distribution is evidently found. The smaller the sample size, the more uniform the temperature distribution on the block rubber. However, the smaller the sample size, the lower the microwave heating efficiency. The results can serve as references for the research on heating rubber material by microwave technology.

Multiphysics numerical modeling of the continuous flow microwave-assisted transesterification process.

PubMed

Muley, Pranjali D; Boldor, Dorin

2012-01-01

Use of advanced microwave technology for biodiesel production from vegetable oil is a relatively new technology. Microwave dielectric heating increases the process efficiency and reduces reaction time. Microwave heating depends on various factors such as material properties (dielectric and thermo-physical), frequency of operation and system design. Although lab scale results are promising, it is important to study these parameters and optimize the process before scaling up. Numerical modeling approach can be applied for predicting heating and temperature profiles including at larger scale. The process can be studied for optimization without actually performing the experiments, reducing the amount of experimental work required. A basic numerical model of continuous electromagnetic heating of biodiesel precursors was developed. A finite element model was built using COMSOL Multiphysics 4.2 software by coupling the electromagnetic problem with the fluid flow and heat transfer problem. Chemical reaction was not taken into account. Material dielectric properties were obtained experimentally, while the thermal properties were obtained from the literature (all the properties were temperature dependent). The model was tested for the two different power levels 4000 W and 4700 W at a constant flow rate of 840ml/min. The electric field, electromagnetic power density flow and temperature profiles were studied. Resulting temperature profiles were validated by comparing to the temperatures obtained at specific locations from the experiment. The results obtained were in good agreement with the experimental data.

In-Space Propulsion Technology Products Ready for Infusion on NASA's Future Science Missions

NASA Technical Reports Server (NTRS)

Anderson, David J.; Pencil, Eric; Peterson, Todd; Dankanich, John; Munk, Michele M.

2012-01-01

Since 2001, the In-Space Propulsion Technology (ISPT) program has been developing and delivering in-space propulsion technologies that will enable or enhance NASA robotic science missions. These in-space propulsion technologies are applicable, and potentially enabling, for future NASA flagship and sample return missions currently being considered. They have a broad applicability to future competed mission solicitations. The high-temperature Advanced Material Bipropellant Rocket (AMBR) engine, providing higher performance for lower cost, was completed in 2009. Two other ISPT technologies are nearing completion of their technology development phase: 1) NASA s Evolutionary Xenon Thruster (NEXT) ion propulsion system, a 0.6-7 kW throttle-able gridded ion system; and 2) Aerocapture technology development with investments in a family of thermal protection system (TPS) materials and structures; guidance, navigation, and control (GN&C) models of blunt-body rigid aeroshells; aerothermal effect models; and atmospheric models for Earth, Titan, Mars and Venus. This paper provides status of the technology development, applicability, and availability of in-space propulsion technologies that have recently completed their technology development and will be ready for infusion into NASA s Discovery, New Frontiers, SMD Flagship, or technology demonstration missions.

In-Space Propulsion Technology Products for NASA's Future Science and Exploration Missions

NASA Technical Reports Server (NTRS)

Anderson, David J.; Pencil, Eric; Peterson, Todd; Dankanich, John; Munk, Michelle M.

2011-01-01

Since 2001, the In-Space Propulsion Technology (ISPT) project has been developing and delivering in-space propulsion technologies that will enable or enhance NASA robotic science missions. These in-space propulsion technologies are applicable, and potentially enabling, for future NASA flagship and sample return missions currently being considered, as well as having broad applicability to future competed mission solicitations. The high-temperature Advanced Material Bipropellant Rocket (AMBR) engine providing higher performance for lower cost was completed in 2009. Two other ISPT technologies are nearing completion of their technology development phase: 1) NASA's Evolutionary Xenon Thruster (NEXT) ion propulsion system, a 0.6-7 kW throttle-able gridded ion system; and 2) Aerocapture technology development with investments in a family of thermal protection system (TPS) materials and structures; guidance, navigation, and control (GN&C) models of blunt-body rigid aeroshells; aerothermal effect models: and atmospheric models for Earth, Titan, Mars and Venus. This paper provides status of the technology development, applicability, and availability of in-space propulsion technologies that have recently completed their technology development and will be ready for infusion into NASA s Discovery, New Frontiers, Science Mission Directorate (SMD) Flagship, and Exploration technology demonstration missions

Effect of combined extrusion parameters on mechanical properties of basalt fiber-reinforced plastics based on polypropylene

NASA Astrophysics Data System (ADS)

Bashtannik, P. I.; Ovcharenko, V. G.; Boot, Yu. A.

1997-11-01

Basalt fibers are efficient reinforcing fillers for polypropylene because they increase both the mechanical and the tribotechnical properties of composites. Basalt fibers can compete with traditional fillers (glass and asbestos fibers) of polypropylene with respect to technological, economic, and toxic properties. The effect of technological parameters of producing polypropylene-based basalt fiber-reinforced plastics (BFRPs) by combined extrusion on their mechanical properties has been investigated. The extrusion temperature was found to be the main parameter determining the mechanical properties of the BFRPs. With temperature growth from 180 to 240°C, the residual length of the basalt fibers in the composite, as well as the adhesive strength of the polymer-fiber system, increased, while the composite defectiveness decreased. The tensile strength and elastic modulus increased from 35 to 42 MPa and 3.2 to 4.2 GPa, respectively. At the same time, the growth in composite solidity led to its higher brittleness. Thus, a higher temperature of extrusion allows us to produce materials which can be subjected to tensile and bending loads, while the materials produced at a lower temperature of extrusion are impact stable. The effect of the gap size between the extruder body and moving disks on the mechanical properties of the BFRPs is less significant than that of temperature. An increase of the gap size from 2 to 8 mm improves the impregnation quality of the fibers, but the extruder productivity diminishes. The possibility of controling the properties of reinforced polypropylene by varying the technological parameters of combined extrusion is shown. The polypropylene-based BFRPs produced by the proposed method surpass the properties of glass and asbestos fiber-reinforced plastics.

Graphene nanoribbon field effect transistor for nanometer-size on-chip temperature sensor

NASA Astrophysics Data System (ADS)

Banadaki, Yaser M.; Srivastava, Ashok; Sharifi, Safura

2016-04-01

Graphene has been extensively investigated as a promising material for various types of high performance sensors due to its large surface-to-volume ratio, remarkably high carrier mobility, high carrier density, high thermal conductivity, extremely high mechanical strength and high signal-to-noise ratio. The power density and the corresponding die temperature can be tremendously high in scaled emerging technology designs, urging the on-chip sensing and controlling of the generated heat in nanometer dimensions. In this paper, we have explored the feasibility of a thin oxide graphene nanoribbon (GNR) as nanometer-size temperature sensor for detecting local on-chip temperature at scaled bias voltages of emerging technology. We have introduced an analytical model for GNR FET for 22nm technology node, which incorporates both thermionic emission of high-energy carriers and band-to-band-tunneling (BTBT) of carriers from drain to channel regions together with different scattering mechanisms due to intrinsic acoustic phonons and optical phonons and line-edge roughness in narrow GNRs. The temperature coefficient of resistivity (TCR) of GNR FET-based temperature sensor shows approximately an order of magnitude higher TCR than large-area graphene FET temperature sensor by accurately choosing of GNR width and bias condition for a temperature set point. At gate bias VGS = 0.55 V, TCR maximizes at room temperature to 2.1×10-2 /K, which is also independent of GNR width, allowing the design of width-free GNR FET for room temperature sensing applications.

Creep of Hi-Nicalon S Fiber Tows at Elevated Temperature in Air and in Steam

DTIC Science & Technology

2013-03-01

materials”[28]. Materials have always been a limiting factor in the advancements of technology. The ever increasing demand for aerospace vehicles that are...matrix composites are designed to have load-carrying capacity at high temperatures in extreme environments. Ceramic matrix composites are prime...engines, gas turbines for electrical power/steam cogeneration , as well as nuclear power plant components. It is recognized that the structural

De Magnete et Meteorite: Cosmically Motivated Materials

DOE Office of Scientific and Technical Information (OSTI.GOV)

Lewis, LH; Pinkerton, FE; Bordeaux, N

2014-01-01

Meteorites, likely the oldest source of magnetic material known to mankind, are attracting renewed interest in the science and engineering community. Worldwide focus is on tetrataenite, a uniaxial ferromagnetic compound with the tetragonal L1(0) crystal structure comprised of nominally equiatomic Fe-Ni that is found naturally in meteorites subjected to extraordinarily slow cooling rates, as low as 0.3 K per million years. Here, the favorable permanent magnetic properties of bulk tetrataenite derived from the meteorite NWA 6259 are quantified. The measured magnetization approaches that of Nd-Fe-B (1.42 T) and is coupled with substantial anisotropy (1.0-1.3 MJ/m(3)) that implies the prospect formore » realization of technologically useful coercivity. A highly robust temperature dependence of the technical magnetic properties at an elevated temperature (20-200 degrees C) is confirmed, with a measured temperature coefficient of coercivity of -0.005%/ K, over one hundred times smaller than that of Nd-Fe-B in the same temperature range. These results quantify the extrinsic magnetic behavior of chemically ordered tetrataenite and are technologically and industrially significant in the current context of global supply chain limitations of rare-earth metals required for present-day high-performance permanent magnets that enable operation of a myriad of advanced devices and machines.« less

Thin-film thermoelectric devices with high room-temperature figures of merit.

PubMed

Venkatasubramanian, R; Siivola, E; Colpitts, T; O'Quinn, B

2001-10-11

Thermoelectric materials are of interest for applications as heat pumps and power generators. The performance of thermoelectric devices is quantified by a figure of merit, ZT, where Z is a measure of a material's thermoelectric properties and T is the absolute temperature. A material with a figure of merit of around unity was first reported over four decades ago, but since then-despite investigation of various approaches-there has been only modest progress in finding materials with enhanced ZT values at room temperature. Here we report thin-film thermoelectric materials that demonstrate a significant enhancement in ZT at 300 K, compared to state-of-the-art bulk Bi2Te3 alloys. This amounts to a maximum observed factor of approximately 2.4 for our p-type Bi2Te3/Sb2Te3 superlattice devices. The enhancement is achieved by controlling the transport of phonons and electrons in the superlattices. Preliminary devices exhibit significant cooling (32 K at around room temperature) and the potential to pump a heat flux of up to 700 W cm-2; the localized cooling and heating occurs some 23,000 times faster than in bulk devices. We anticipate that the combination of performance, power density and speed achieved in these materials will lead to diverse technological applications: for example, in thermochemistry-on-a-chip, DNA microarrays, fibre-optic switches and microelectrothermal systems.

The influence of using heat storage with PCM on inlet and outlet temperatures in substation in DHS

NASA Astrophysics Data System (ADS)

Nogaj, Kinga; Turski, Michał; Sekret, Robert

2017-11-01

The main objective of this article is to indicate the direction of development of new generation heating systems that use phase change materials, and the important criteria needed when choosing a phase change material. The work contains a detailed classification of materials using the latent heat of organic and inorganic PCM. This references the technical possibilities of existing heat storage technologies. A specific objective was adopted to determine the effect of using heat storage with PCM on inlet and outlet temperatures in substation in district heating systems. The scope of the study included determining the parameters of the heat distribution network as a function of an outdoor air temperature within the range of -20°C to + 12°C. The object of analysis was chosen to be the heating system parameters: supply 120°C and return 60°C. It is located on the surface of 160km2, and supplies heat to 240,000 residents. The total length of the district heating network is 170 km. Based on the study, it was found that the most advantageous material that accumulates heat depends on the return temperature in the heating network. For the above analyzed case, the return temperature was in the range of 46°C to 57°C. The analysis showed that the most preferred materials using heat of phase change, have possible applications in heating networks and received a return temperature including salt hydrates, such as MgSO4·7H2O and Na2S2O3·5H2. The introduction of stored heat for the district heating system with the phase change material in the form of salt hydrates, allows the return temperature in the district heating to remain at temperatures compatible with the adopted regulatory table for temperatures outside the standard heating season.

Support Services for Ceramic Fiber-Ceramic Matrix Composites

DOE Office of Scientific and Technical Information (OSTI.GOV)

Hurley, JP

2001-08-16

To increase national energy self-sufficiency for the near future, power systems will be required to fire low-grade fuels more efficiently than is currently possible. The typical coal-fired steam cycle used at present is limited to a maximum steam temperature of 540 C and a conversion efficiency of 35%. Higher working-fluid temperatures are required to boost efficiency, exposing subsystems to very damaging conditions. Issues of special concern to materials developers are corrosion and warping of hot-gas particulate filters and corrosion and erosion of high-temperature heat exchangers. The University of North Dakota Energy and Environmental Research Center (EERC) is working with themore » National Energy Technology Laboratory in conjunction with NCC Engineering, Inc., to provide technical assistance and coal by-products to the Fossil Energy Materials Advanced Research and Technology Development Materials Program investigating materials failure in fossil energy systems. The main activities of the EERC are to assemble coal slag and hot-gas filter ash samples for use by materials researchers, to assist in providing opportunities for realistic tests of advanced materials in pilot-scale fossil energy systems, and to provide analytical support in determining corrosion mechanisms of the exposed materials. In this final report for the project year of September 2000 through August 2001, the facilities at the EERC that can be used by researchers for realistic testing of materials are described. Researchers can include sample coupons in each of these facilities at no cost since they are being operated under separate funding. In addition, two pilot-scale coal combustion tests are described in which material sample coupons were included from researchers involved in the development of fossil energy materials. The results of scanning electron microscopy (SEM) energy dispersive x-ray analyses of the corrosion products and interactions between the surface scales of the coupons and the products of coal combustion found on the coupons exposed during those tests are reported. Finally, a relative comparison of ceramic and alloy material performance based on the SEM results is presented.« less

Materials for Advanced Ultra-supercritical (A-USC) Steam Turbines – A-USC Component Demonstration

DOE Office of Scientific and Technical Information (OSTI.GOV)

Purgert, Robert; Phillips, Jeffrey; Hendrix, Howard

The work by the United States Department of Energy (U.S. DOE)/Ohio Coal Development Office (OCDO) advanced ultra-supercritical (A-USC) Steam Boiler and Turbine Materials Consortia from 2001 through September 2015 was primarily focused on lab scale and pilot scale materials testing. This testing included air- or steam-cooled “loops” that were inserted into existing utility boilers to gain exposure of these materials to realistic conditions of high temperature and corrosion due to the constituents in the coal. Successful research and development resulted in metallic alloy materials and fabrication processes suited for power generation applications with metal temperatures up to approximately 1472°F (800°C).more » These materials or alloys have shown, in extensive laboratory tests and shop fabrication studies, to have excellent applicability for high-efficiency low CO 2 transformational power generation technologies previously mentioned. However, as valuable as these material loops have been for obtaining information, their scale is significantly below that required to minimize the risk associated with a power company building a multi-billion dollar A-USC power plant. To decrease the identified risk barriers to full-scale implementation of these advanced materials, the U.S. DOE/OCDO A-USC Steam Boiler and Turbine Materials Consortia identified the key areas of the technology that need to be tested at a larger scale. Based upon the recommendations and outcome of a Consortia-sponsored workshop with the U.S.’s leading utilities, a Component Test (ComTest) Program for A-USC was proposed. The A-USC ComTest program would define materials performance requirements, plan for overall advanced system integration, design critical component tests, fabricate components for testing from advanced materials, and carry out the tests. The AUSC Component Test was premised on the program occurring at multiple facilities, with the operating temperatures, pressure and/or size of these components determining the optimum test location. The first step of the ComTest, the steam turbine test, was determined best suited for a site in Youngstown, Ohio. Efforts were also undertaken to identify and evaluate other potential sites for high pressure testing.« less

On 3-D inelastic analysis methods for hot section components (base program)

NASA Technical Reports Server (NTRS)

Wilson, R. B.; Bak, M. J.; Nakazawa, S.; Banerjee, P. K.

1986-01-01

A 3-D Inelastic Analysis Method program is described. This program consists of a series of new computer codes embodying a progression of mathematical models (mechanics of materials, special finite element, boundary element) for streamlined analysis of: (1) combustor liners, (2) turbine blades, and (3) turbine vanes. These models address the effects of high temperatures and thermal/mechanical loadings on the local (stress/strain)and global (dynamics, buckling) structural behavior of the three selected components. Three computer codes, referred to as MOMM (Mechanics of Materials Model), MHOST (Marc-Hot Section Technology), and BEST (Boundary Element Stress Technology), have been developed and are briefly described in this report.

DOE Office of Scientific and Technical Information (OSTI.GOV)

Anthony D. Rollett; Hasso Weiland; Mohammed Alvi

Carnegie Mellon University was teamed with the Alcoa Technical Center with support from the US Dept. of Energy (Office of Industrial Technology) and the Pennsylvania Technology Investment Authority (PTIA) to make processing of aluminum less costly and more energy efficient. Researchers in the Department of Materials Science and Engineering have investigated how annealing processes in the early stages of aluminum processing affect the structure and properties of the material. Annealing at high temperatures consumes significant amounts of time and energy. By making detailed measurements of the crystallography and morphology of internal structural changes they have generated new information that willmore » provide a scientific basis for shortening processing times and consuming less energy during annealing.« less

Energy efficient engine high-pressure turbine detailed design report

NASA Technical Reports Server (NTRS)

Thulin, R. D.; Howe, D. C.; Singer, I. D.

1982-01-01

The energy efficient engine high-pressure turbine is a single stage system based on technology advancements in the areas of aerodynamics, structures and materials to achieve high performance, low operating economics and durability commensurate with commercial service requirements. Low loss performance features combined with a low through-flow velocity approach results in a predicted efficiency of 88.8 for a flight propulsion system. Turbine airfoil durability goals are achieved through the use of advanced high-strength and high-temperature capability single crystal materials and effective cooling management. Overall, this design reflects a considerable extension in turbine technology that is applicable to future, energy efficient gas-turbine engines.

Heat Stress Monitor

NASA Technical Reports Server (NTRS)

1994-01-01

The heavy, cumbersome body protection suits worn by members of hazardous materials response teams cause marked elevation of body temperatures, which can reduce effectiveness and lead to heat stress and injury. The CorTemp System, marketed by Human Technologies, Inc., provides the basis for a body temperature monitoring alarm system. Encased in a three-quarter-inch ingestible capsule, the system includes a mini-thermometer, miniature telemetry system, a microbattery and temperature sensor. It makes its way through the digestive system, continuously monitoring temperature. Findings are sent to the recorder by telemetry, and then displayed and stored for transfer to a computer.

Influence of DAD-TA temperature-reducing additive on physical and mechanical properties of bitumen and compaction of asphalt concrete.

NASA Astrophysics Data System (ADS)

Yadykina, V. V.; Akimov, A. E.; Trautvain, A. I.; Kholopov, V. S.

2018-03-01

The paper is devoted to the use of DAD-TA temperature-reducing additive for the preparation and pouring of asphalt concrete mixes at reduced temperatures. It also shows positive influence of the modified bitumen on the efficiency of organo-mineral composite compaction at reduced temperatures. Physical and mechanical properties of asphalt concrete with the use of bitumen modified by DAD-TA additive including indicators characterizing road surfacing life are presented. Arguments to use this material from the point of view of its production technology and environmental impact are given.

High temperature solar receiver

NASA Technical Reports Server (NTRS)

1981-01-01

The development of a high temperature solar thermal receiver is described. A prototype receiver and associated test support (auxiliary) hardware was fabricated. Shakedown and initial performance tests of the prototype receiver were performed. Maximum outlet temperatures of 1600 F were achieved at 100% solar (70-75 kW) input power with 900 F inlet temperatures and a subsequent testing was concluded by a 2550 F outlet run. The window retaining assembly was modified to improve its tolerance for thermal distortion of the flanges. It is shown that cost effective receiver designs can be implemented within the framework of present materials technology.

Room-temperature semiconductor heterostructure refrigeration

NASA Astrophysics Data System (ADS)

Chao, K. A.; Larsson, Magnus; Mal'shukov, A. G.

2005-07-01

With the proper design of semiconductor tunneling barrier structures, we can inject low-energy electrons via resonant tunneling, and take out high-energy electrons via a thermionic process. This is the operation principle of our semiconductor heterostructure refrigerator (SHR) without the need of applying a temperature gradient across the device. Even for the bad thermoelectric material AlGaAs, our calculation shows that at room temperature, the SHR can easily lower the temperature by 5-7K. Such devices can be fabricated with the present semiconductor technology. Besides its use as a kitchen refrigerator, the SHR can efficiently cool microelectronic devices.

Chemical Gas Sensors for Aeronautic and Space Applications

NASA Technical Reports Server (NTRS)

Hunter, Gary W.; Chen, Liang-Yu; Neudeck, Philip G.; Knight, Dak; Liu, Chung-Chiun; Wu, Quing-Hai; Zhou, Huan-Jun

1997-01-01

Aeronautic and space applications require the development of chemical sensors with capabilities beyond those of commercially available sensors. Two areas of particular interest are safety monitoring and emission monitoring. In safety monitoring, detection of low concentrations of hydrogen at potentially low temperatures is important while for emission monitoring the detection of nitrogen oxides, hydrogen, hydrocarbons and oxygen is of interest. This paper discusses the needs of aeronautic and space applications and the point-contact sensor technology being developed to address these needs. The development of these sensors is based on progress in two types of technology: (1) Micromachining and microfabrication technology to fabricate miniaturized sensors. (2) The development of high temperature semiconductors, especially silicon carbide. The detection of each type of gas involves its own challenges in the fields of materials science and fabrication technology. The number of dual-use commercial applications of this microfabricated gas sensor technology make this general area of sensor development a field of significant interest.

A novel multi-level IC-compatible surface microfabrication technology for MEMS with independently controlled lateral and vertical submicron transduction gaps

NASA Astrophysics Data System (ADS)

Cicek, Paul-Vahe; Elsayed, Mohannad; Nabki, Frederic; El-Gamal, Mourad

2017-11-01

An above-IC compatible multi-level MEMS surface microfabrication technology based on a silicon carbide structural layer is presented. The fabrication process flow provides optimal electrostatic transduction by allowing the creation of independently controlled submicron vertical and lateral gaps without the need for high resolution lithography. Adopting silicon carbide as the structural material, the technology ensures material, chemical and thermal compatibility with modern semiconductor nodes, reporting the lowest peak processing temperature (i.e. 200 °C) of all comparable works. This makes this process ideally suited for integrating capacitive-based MEMS directly above standard CMOS substrates. Process flow design and optimization are presented in the context of bulk-mode disk resonators, devices that are shown to exhibit improved performance with respect to previous generation flexural beam resonators, and that represent relatively complex MEMS structures. The impact of impending improvements to the fabrication technology is discussed.

Compact, High Power, Multi-Spectral Mid-Infrared Semiconductor Laser Package

NASA Astrophysics Data System (ADS)

Guo, Bujin; Hwang, Wen-Yen; Lin, Chich-Hsiang

2001-10-01

Through a vertically integrated effort involving atomic level material engineering, advanced device processing development, state-of-the-art optomechanical packaging, and thermal management, Applied Optoelectronics, Inc. (AOI), University of Houston (U H), and Physical Science, Inc. (PSI) have made progress in both Sb-based type-II semiconductor material and in P-based type-I laser device development. We have achieved record performance on inP based quantum cascade continuous wave (CW) laser (with more than 5 mW CW power at 210 K). Grating-coupled external-cavity quantum cascade lasers were studied for temperatures from 20 to 230 K. A tuning range of 88 nm has been obtained at 80 K. The technology can be made commercially available and represents a significant milestone with regard to the Dual Use Science and Technology (DUST) intention of fostering dual use commercial technology for defense need. AOI is the first commercial company to ship products of this licensed technology.

High-Temperature Capacitor Polymer Films

NASA Astrophysics Data System (ADS)

Tan, Daniel; Zhang, Lili; Chen, Qin; Irwin, Patricia

2014-12-01

Film capacitor technology has been under development for over half a century to meet various applications such as direct-current link capacitors for transportation, converters/inverters for power electronics, controls for deep well drilling of oil and gas, direct energy weapons for military use, and high-frequency coupling circuitry. The biaxially oriented polypropylene film capacitor remains the state-of-the-art technology; however, it is not able to meet increasing demand for high-temperature (>125°C) applications. A number of dielectric materials capable of operating at high temperatures (>140°C) have attracted investigation, and their modifications are being pursued to achieve higher volumetric efficiency as well. This paper highlights the status of polymer dielectric film development and its feasibility for capacitor applications. High-temperature polymers such as polyetherimide (PEI), polyimide, and polyetheretherketone were the focus of our studies. PEI film was found to be the preferred choice for high-temperature film capacitor development due to its thermal stability, dielectric properties, and scalability.

Design and Operation of a Fast, Thin-Film Thermocouple Probe on a Turbine Engine

NASA Technical Reports Server (NTRS)

Meredith, Roger D.; Wrbanek, John D.; Fralick, Gustave C.; Greer, Lawrence C., III; Hunter, Gary W.; Chen, Liang-Yu

2014-01-01

As a demonstration of technology maturation, a thin-film temperature sensor probe was fabricated and installed on a F117 turbofan engine via a borescope access port to monitor the temperature experienced in the bleed air passage of the compressor area during an engine checkout test run. To withstand the harsh conditions experienced in this environment, the sensor probe was built from high temperature materials. The thin-film thermocouple sensing elements were deposited by physical vapor deposition using pure metal elements, thus avoiding the inconsistencies of sputter-depositing particular percentages of materials to form standardized alloys commonly found in thermocouples. The sensor probe and assembly were subjected to a strict protocol of multi-axis vibrational testing as well as elevated temperature pressure testing to be qualified for this application. The thin-film thermocouple probe demonstrated a faster response than a traditional embedded thermocouple during the engine checkout run.

TiO x -Based Thermoelectric Modules: Manufacturing, Properties, and Operational Behavior

NASA Astrophysics Data System (ADS)

Martin, Hans-Peter; Pönicke, Andreas; Kluge, Martin; Sichert, Ina; Rost, Axel; Conze, Susan; Wätzig, Katja; Schilm, Jochen; Michaelis, Alexander

2016-03-01

Substoichiometric titanium oxides are attractive thermoelectric materials for high-temperature modules. Their advantages are availability, economy, and safety. This paper gives results of thermoelectric data on scale-up titanium suboxides, manufacturing technologies of TiO x modules, glass coating as an option for oxidation protection, and test results of TiO x modules. The thermoelectric efficiency of TiO x is low compared with established thermoelectric materials. However, TiO x is very attractive for economic reasons, and there are still expectations for efficiency rise by modification of the material's microstructure. TiO x can be produced in large quantities of several tens of kilograms. A manufacturing process for TiO x -based unileg n-type modules has been established, including all technological steps. The design of the TiO x -based modules was optimized for the thermoelectric conversion process and thermal robustness. A test device was used for experimental analysis with maximum temperature of 600°C at the hot side and 100°C at the cold side. This initial test revealed similar power output and internal resistance of all fabricated modules. Furthermore, thermal cycles with increasing and decreasing temperatures at the hot side were realized to characterize the reliability and stability of the modules. Additionally, modules were tested in a hot gas test rig to simulate the thermal stresses during power generation in the exhaust line of a passenger car.

Bonding at Metal-Ceramic Interfaces in Hybrid Materials.

DTIC Science & Technology

1990-12-31

an arena where America, Europe, and Japan will compete . Aerospace transport technologies will form the first link in this human endeavor. The...mechanical properties such as tranverse strength and shear properties and, more importantly, due to their high temperature capabilities [1]. The

Strategic need for a multi-purpose thermal hydraulic loop for support of advanced reactor technologies

DOE Office of Scientific and Technical Information (OSTI.GOV)

O'Brien, James E.; Sabharwall, Piyush; Yoon, Su -Jong

2014-09-01

This report presents a conceptual design for a new high-temperature multi fluid, multi loop test facility for the INL to support thermal hydraulic, materials, and thermal energy storage research for nuclear and nuclear-hybrid applications. In its initial configuration, the facility will include a high-temperature helium loop, a liquid salt loop, and a hot water/steam loop. The three loops will be thermally coupled through an intermediate heat exchanger (IHX) and a secondary heat exchanger (SHX). Research topics to be addressed with this facility include the characterization and performance evaluation of candidate compact heat exchangers such as printed circuit heat exchangers (PCHEs)more » at prototypical operating conditions, flow and heat transfer issues related to core thermal hydraulics in advanced helium-cooled and salt-cooled reactors, and evaluation of corrosion behavior of new cladding materials and accident-tolerant fuels for LWRs at prototypical conditions. Based on its relevance to advanced reactor systems, the new facility has been named the Advanced Reactor Technology Integral System Test (ARTIST) facility. Research performed in this facility will advance the state of the art and technology readiness level of high temperature intermediate heat exchangers (IHXs) for nuclear applications while establishing the INL as a center of excellence for the development and certification of this technology. The thermal energy storage capability will support research and demonstration activities related to process heat delivery for a variety of hybrid energy systems and grid stabilization strategies. Experimental results obtained from this research will assist in development of reliable predictive models for thermal hydraulic design and safety codes over the range of expected advanced reactor operating conditions. Proposed/existing IHX heat transfer and friction correlations and criteria will be assessed with information on materials compatibility and instrumentation needs. The experimental database will guide development of appropriate predictive methods and be available for code verification and validation (V&V) related to these systems.« less

Nanostructured Bulk Thermoelectric Generator for Efficient Power Harvesting for Self-powered Sensor Networks

DOE Office of Scientific and Technical Information (OSTI.GOV)

Zhang, Yanliang; Butt, Darryl; Agarwal, Vivek

2015-07-01

The objective of this Nuclear Energy Enabling Technology research project is to develop high-efficiency and reliable thermoelectric generators for self-powered wireless sensors nodes utilizing thermal energy from nuclear plant or fuel cycle. The power harvesting technology has crosscutting significance to address critical technology gaps in monitoring nuclear plants and fuel cycle. The outcomes of the project will lead to significant advancement in sensors and instrumentation technology, reducing cost, improving monitoring reliability and therefore enhancing safety. The self-powered wireless sensor networks could support the long-term safe and economical operation of all the reactor designs and fuel cycle concepts, as well asmore » spent fuel storage and many other nuclear science and engineering applications. The research is based on recent breakthroughs in high-performance nanostructured bulk (nanobulk) thermoelectric materials that enable high-efficiency direct heat-to-electricity conversion over a wide temperature range. The nanobulk thermoelectric materials that the research team at Boise State University and University of Houston has developed yield up to a 50% increase in the thermoelectric figure of merit, ZT, compared with state-of-the-art bulk counterparts. This report focuses on the selection of optimal thermoelectric materials for this project. The team has performed extensive study on two thermoelectric materials systems, i.e. the half-Heusler materials, and the Bismuth-Telluride materials. The report contains our recent research results on the fabrication, characterization and thermoelectric property measurements of these two materials.« less

CubeSat infrared atmospheric sounder (CIRAS) NASA InVEST technology demonstration

NASA Astrophysics Data System (ADS)

Pagano, Thomas S.

2017-02-01

Infrared sounders measure the upwelling radiation of the Earth in the Midwave Infrared (MWIR) and Longwave Infrared (LWIR) region of the spectrum with global daily coverage from space. The observed radiances are assimilated into weather forecast models and used to retrieve lower tropospheric temperature and water vapor for climate studies. There are several operational sounders today including the Atmospheric Infrared Sounder (AIRS) on Aqua, the Crosstrack Infrared Sounder (CrIS) on Suomi NPP and JPSS, and the Infrared Atmospheric Sounding Interferometer (IASI) on the MetOp spacecraft. The CubeSat Infrared Atmospheric Sounder (CIRAS) is a NASA In-flight Validation of Earth Science Technologies (InVEST) program to demonstrate three new instrument technologies in an imaging sounder configuration. The first is a 2D array of High Operating Temperature Barrier Infrared Detector (HOT-BIRD) material, selected for its high uniformity, low cost, low noise and higher operating temperatures than traditional materials. The detectors are hybridized to a commercial ROIC and commercial camera electronics. The second technology is a MWIR Grating Spectrometer (MGS) designed to provide imaging spectroscopy for atmospheric sounding in a CubeSat volume. The MGS employs an immersion grating or grism, has no moving parts, and is based on heritage spectrometers including the OCO- 2. The third technology is a Black Silicon infrared blackbody calibration target. The Black Silicon offers very low reflectance over a broad spectral range on a flat surface and is more robust than carbon nanotubes. JPL will also develop the mechanical, electronic and thermal subsystems for the CIRAS payload. The spacecraft will be a commercially available CubeSat. The integrated system will be a complete 6U CubeSat capable of measuring temperature and water vapor profiles with good lower tropospheric sensitivity. The low cost of CIRAS enables multiple units to be flown to improve temporal coverage or measure 3D Atmospheric Motion Vector (AMV) winds. CIRAS will launch in 2019 and is only a technology demonstration. However, what we learn will benefit future instruments that support operational weather forecasting and climate studies.

Material Challenges and Opportunities for Commercial Electric Aircraft

NASA Technical Reports Server (NTRS)

Misra, Ajay

2014-01-01

Significant reduction in carbon dioxide emission for future air transportation system will require adoption of electric propulsion system and more electric architectures. Various options for aircraft electric propulsion include hybrid electric, turboelectric, and full electric system. Realization of electric propulsion system for commercial aircraft applications will require significant increases in power density of electric motors and energy density of energy storage system, such as the batteries and fuel cells. In addition, transmission of MW of power in the aircraft will require high voltage power transmission system to reduce the weight of the power transmission system. Finally, there will be significant thermal management challenges. Significant advances in material technologies will be required to meet these challenges. Technologies of interest include materials with higher electrical conductivity than Cu, high thermal conductivity materials, and lightweight electrically insulating materials with high breakdown voltage, high temperature magnets, advanced battery and fuel cell materials, and multifunctional materials. The presentation will include various challenges for commercial electric aircraft and provide an overview of material improvements that will be required to meet these challenges.

Materials Advance Chemical Propulsion Technology

NASA Technical Reports Server (NTRS)

2012-01-01

In the future, the Planetary Science Division of NASA's Science Mission Directorate hopes to use better-performing and lower-cost propulsion systems to send rovers, probes, and observers to places like Mars, Jupiter, and Saturn. For such purposes, a new propulsion technology called the Advanced Materials Bipropellant Rocket (AMBR) was developed under NASA's In-Space Propulsion Technology (ISPT) project, located at Glenn Research Center. As an advanced chemical propulsion system, AMBR uses nitrogen tetroxide oxidizer and hydrazine fuel to propel a spacecraft. Based on current research and development efforts, the technology shows great promise for increasing engine operation and engine lifespan, as well as lowering manufacturing costs. In developing AMBR, ISPT has several goals: to decrease the time it takes for a spacecraft to travel to its destination, reduce the cost of making the propulsion system, and lessen the weight of the propulsion system. If goals like these are met, it could result in greater capabilities for in-space science investigations. For example, if the amount (and weight) of propellant required on a spacecraft is reduced, more scientific instruments (and weight) could be added to the spacecraft. To achieve AMBR s maximum potential performance, the engine needed to be capable of operating at extremely high temperatures and pressure. To this end, ISPT required engine chambers made of iridium-coated rhenium (strong, high-temperature metallic elements) that allowed operation at temperatures close to 4,000 F. In addition, ISPT needed an advanced manufacturing technique for better coating methods to increase the strength of the engine chamber without increasing the costs of fabricating the chamber.

Concentrating solar power (CSP) power cycle improvements through application of advanced materials

NASA Astrophysics Data System (ADS)

Siefert, John A.; Libby, Cara; Shingledecker, John

2016-05-01

Concentrating solar power (CSP) systems with thermal energy storage (TES) capability offer unique advantages to other renewable energy technologies in that solar radiation can be captured and stored for utilization when the sun is not shining. This makes the technology attractive as a dispatchable resource, and as such the Electric Power Research Institute (EPRI) has been engaged in research and development activities to understand and track the technology, identify key technical challenges, and enable improvements to meet future cost and performance targets to enable greater adoption of this carbon-free energy resource. EPRI is also involved with technically leading a consortium of manufacturers, government labs, and research organizations to enable the next generation of fossil fired power plants with advanced ultrasupercritical (A-USC) steam temperatures up to 760°C (1400°F). Materials are a key enabling technology for both of these seemingly opposed systems. This paper discusses how major strides in structural materials for A-USC fossil fired power plants may be translated into improved CSP systems which meet target requirements.

Proceedings of the Workshop on an Electromagnetic Positioning System in Space

NASA Technical Reports Server (NTRS)

Oran, W. A. (Editor)

1978-01-01

A workshop was convened to help determine if sufficient justification existed to proceed with the design of an electromagnetic (EM) positioning device for use in space. Those in attendance included experts in crystal growth, nucleation phenomena, containerless processing techniques, properties of materials, metallurgical techniques, and glass technology. Specific areas mentioned included the study of metallic glasses and investigations of the properties of high temperature materials.

High-temperature sapphire optical sensor fiber coatings

NASA Astrophysics Data System (ADS)

Desu, Seshu B.; Claus, Richard O.; Raheem, Ruby; Murphy, Kent A.

1990-10-01

Advanced coal-fired power generation systems, such as pressurized fluidized-bed combustors and integrated gasifier-combined cycles, may provide cost effective future alternatives for power generation, improve our utilization of coal resources, and decrease our dependence upon oil and gas. When coal is burned or converted to combustible gas to produce energy, mineral matter and chemical compounds are released as solid and gaseous contaminants. The control of contaminants is mandatory to prevent pollution as well as degradation of equipment in advanced power generation. To eliminate the need for expensive heat recovery equipment and to avoid efficiency losses it is desirable to develop a technology capable of cleaning the hot gas. For this technology the removal of particle contaminants is of major concern. Several prototype high temperature particle filters have been developed, including ceramic candle filters, ceramic bag filters, and ceramic cross-flow (CXF) filters. Ceramic candle filters are rigid, tubular filters typically made by bonding silicon carbide or alumina-silica grains with clay bonding materials and perhaps including alumina-silica fibers. Ceramic bag filters are flexible and are made from long ceramic fibers such as alumina-silica. CXF filters are rigid filters made of stacks of individual lamina through which the dirty and clean gases flow in cross-wise directions. CXF filters are advantageous for hot gas cleanup applications since they offer a large effective filter surface per unit volume. The relatively small size of the filters allows the pressurized vessel containing them to be small, thus reducing potential equipment costs. CXF filters have shown promise but have experienced degradation at normal operational high temperatures (close to 1173K) and high pressures (up to 24 bars). Observed degradation modes include delamination of the individual tile layers, cracking at either the tile-torid interface or at the mounting flange, or plugging of the filter. These modes may be attributed to a number of material degradation mechanisms, such as thermal shock, oxidation corrosion of the material, mechanical loads, or phase changes in the filter material. Development of high temperature optical fiber (sapphire) sensors embedded in the CXF filters would be very valuable for both monitoring the integrity of the filter during its use and understanding the mechanisms of degradation such that durable filter development will be facilitated. Since the filter operating environment is very harsh, the high temperature sapphire optical fibers need to be protected and for some sensing techniques the fiber must also be coated with low refractive index film (cladding). The objective of the present study is to identify materials and develop process technologies for the application of claddings and protective coatings that are stable and compatible with sapphire fibers at both high temperatures and pressures.

Investigation on Using SBS and Active Carbon Filler to Reduce the VOC Emission from Bituminous Materials.

PubMed

Cui, Peiqiang; Wu, Shaopeng; Li, Fuzhou; Xiao, Yue; Zhang, Honghua

2014-08-26

Bituminous materials are playing a vital role in pavement design and the roofing industry because of outstanding properties. Unfortunately, bituminous materials will release volatile organic compounds (VOC), making them non-environmentally friendly. Therefore, technologies that can be used to decrease the VOC emission are urgently required. In this research, the VOC emission and material behaviors were analyzed and compared to investigate the possibility of adding styrene butadiene styrene (SBS) and active carbon filler into bituminous materials to develop environmentally-friendly materials. Thermal gravimetric analysis-mass spectrometry (TG-MS) and ultraviolet-visible spectroscopy testing (UV-Vis) were employed to characterize the VOC emission process. Temperature sweep testing and frequency sweep testing were conducted to evaluate the rheological properties of bituminous materials. Research results indicated that the combined introduction of 4 wt% styrene butadiene styrene (SBS) and 4 wt% active carbon filler cannot only significantly lower the VOC emission speed and amount, but also improve the deformation resistance behavior at a higher temperature. SBS and active carbon filler can be used to reduce the VOC emission form bituminous materials.

Investigation on Using SBS and Active Carbon Filler to Reduce the VOC Emission from Bituminous Materials

PubMed Central

Cui, Peiqiang; Wu, Shaopeng; Li, Fuzhou; Xiao, Yue; Zhang, Honghua

2014-01-01

Bituminous materials are playing a vital role in pavement design and the roofing industry because of outstanding properties. Unfortunately, bituminous materials will release volatile organic compounds (VOC), making them non-environmentally friendly. Therefore, technologies that can be used to decrease the VOC emission are urgently required. In this research, the VOC emission and material behaviors were analyzed and compared to investigate the possibility of adding styrene butadiene styrene (SBS) and active carbon filler into bituminous materials to develop environmentally-friendly materials. Thermal gravimetric analysis-mass spectrometry (TG-MS) and ultraviolet-visible spectroscopy testing (UV-Vis) were employed to characterize the VOC emission process. Temperature sweep testing and frequency sweep testing were conducted to evaluate the rheological properties of bituminous materials. Research results indicated that the combined introduction of 4 wt% styrene butadiene styrene (SBS) and 4 wt% active carbon filler cannot only significantly lower the VOC emission speed and amount, but also improve the deformation resistance behavior at a higher temperature. SBS and active carbon filler can be used to reduce the VOC emission form bituminous materials. PMID:28788181

High Performance Arcjet Engines

NASA Technical Reports Server (NTRS)

Kennel, Elliot B.; Ivanov, Alexey Nikolayevich; Nikolayev, Yuri Vyacheslavovich

1994-01-01

This effort sought to exploit advanced single crystal tungsten-tantalum alloy material for fabrication of a high strength, high temperature arcjet anode. The use of this material is expected to result in improved strength, temperature resistance, and lifetime compared to state of the art polycrystalline alloys. In addition, the use of high electrical and thermal conductivity carbon-carbon composites was considered, and is believed to be a feasible approach. Highly conductive carbon-carbon composite anode capability represents enabling technology for rotating-arc designs derived from the Russian Scientific Research Institute of Thermal Processes (NIITP) because of high heat fluxes at the anode surface. However, for US designs the anode heat flux is much smaller, and thus the benefits are not as great as in the case of NIITP-derived designs. Still, it does appear that the tensile properties of carbon-carbon can be even better than those of single crystal tungsten alloys, especially when nearly-single-crystal fibers such as vapor grown carbon fiber (VGCF) are used. Composites fabricated from such materials must be coated with a refractory carbide coating in order to ensure compatibility with high temperature hydrogen. Fabrication of tungsten alloy single crystals in the sizes required for fabrication of an arcjet anode has been shown to be feasible. Test data indicate that the material can be expected to be at least the equal of W-Re-HfC polycrystalline alloy in terms of its tensile properties, and possibly superior. We are also informed by our colleagues at Scientific Production Association Luch (NP0 Luch) that it is possible to use Russian technology to fabricate polycrystalline W-Re-HfC or other high strength alloys if desired. This is important because existing engines must rely on previously accumulated stocks of these materials, and a fabrication capability for future requirements is not assured.

High performance arcjet engines

NASA Astrophysics Data System (ADS)

Kennel, Elliot B.; Ivanov, Alexey Nikolayevich; Nikolayev, Yuri Vyacheslavovich

1994-10-01

This effort sought to exploit advanced single crystal tungsten-tantalum alloy material for fabrication of a high strength, high temperature arcjet anode. The use of this material is expected to result in improved strength, temperature resistance, and lifetime compared to state of the art polycrystalline alloys. In addition, the use of high electrical and thermal conductivity carbon-carbon composites was considered, and is believed to be a feasible approach. Highly conductive carbon-carbon composite anode capability represents enabling technology for rotating-arc designs derived from the Russian Scientific Research Institute of Thermal Processes (NIITP) because of high heat fluxes at the anode surface. However, for US designs the anode heat flux is much smaller, and thus the benefits are not as great as in the case of NIITP-derived designs. Still, it does appear that the tensile properties of carbon-carbon can be even better than those of single crystal tungsten alloys, especially when nearly-single-crystal fibers such as vapor grown carbon fiber (VGCF) are used. Composites fabricated from such materials must be coated with a refractory carbide coating in order to ensure compatibility with high temperature hydrogen. Fabrication of tungsten alloy single crystals in the sizes required for fabrication of an arcjet anode has been shown to be feasible. Test data indicate that the material can be expected to be at least the equal of W-Re-HfC polycrystalline alloy in terms of its tensile properties, and possibly superior. We are also informed by our colleagues at Scientific Production Association Luch (NP0 Luch) that it is possible to use Russian technology to fabricate polycrystalline W-Re-HfC or other high strength alloys if desired. This is important because existing engines must rely on previously accumulated stocks of these materials, and a fabrication capability for future requirements is not assured.

Conductivity Analysis of Membranes for High-Temperature PEMFC Applications

DOE Office of Scientific and Technical Information (OSTI.GOV)

Reed, R.; Turner, J.A.

2005-01-01

Low-temperature operation requirements for per-fluorinated membranes are one factor that limits the viability of current fuel cell technology for transportation and other uses. Because of this, high-temperature membrane materials are being researched. The protonic conductivity of organic/inorganic hybrid composites, Nafion® analog material, and heteropoly acid doped Nafion membranes were studied using a BekkTech® conductivity test cell as a hydrogen pump. The goal was to find a high-temperature membrane with sufficient enough conductive properties to replace the currently implemented low-temperature membranes, such as Nafion. Four-point conductivity measurements were taken using a hydrogen pump experiment. Results showed that one of the organic/inorganicmore » membranes that we tested had similar protonic conductivity to Nafion. Nafion analog membranes were shown to have similar to slightly better conductivity than Nafion at high-temperatures. However, like Nafion, performance dropped upon dehydration of the membrane at higher temperatures. Of the heteropoly acid doped Nafion membranes studied, silicotungstic acid was found to be, overall, the most promising for use as a dopant.« less

High Temperature Piezoelectric Drill

NASA Technical Reports Server (NTRS)

Bao, Xiaoqi; Scott, James; Boudreau, Kate; Bar-Cohen, Yoseph; Sherrit, Stewart; Badescu, Mircea; Shrout, Tom; Zhang, Shujun

2009-01-01

The current NASA Decadal mission planning effort has identified Venus as a significant scientific target for a surface in-situ sampling/analyzing mission. The Venus environment represents several extremes including high temperature (460 deg C), high pressure (9 MPa), and potentially corrosive (condensed sulfuric acid droplets that adhere to surfaces during entry) environments. This technology challenge requires new rock sampling tools for these extreme conditions. Piezoelectric materials can potentially operate over a wide temperature range. Single crystals, like LiNbO3, have a Curie temperature that is higher than 1000 deg C and the piezoelectric ceramics Bismuth Titanate higher than 600 deg C. A study of the feasibility of producing piezoelectric drills that can operate in the temperature range up to 500 deg C was conducted. The study includes the high temperature properties investigations of engineering materials and piezoelectric ceramics with different formulas and doping. The drilling performances of a prototype Ultrasonic/Sonic Drill/Corer (USDC) using high temperate piezoelectric ceramics and single crystal were tested at temperature up to 500 deg C. The detailed results of our study and a discussion of the future work on performance improvements are presented in this paper.

New instrumentation technologies for testing the bonding of sensors to solid materials

NASA Technical Reports Server (NTRS)

Hashemian, H. M.; Shell, C. S.; Jones, C. N.

1996-01-01

This report presents the results of a comprehensive research and development project that was conducted over a three-year period to develop new technologies for testing the attachment of sensors to solid materials for the following NASA applications: (1) testing the performance of composites that are used for the lining of solid rocket motor nozzles, (2) testing the bonding of surface-mounted platinum resistance thermometers that are used on fuel and oxidizer lines of the space shuttle to detect valve leaks by monitoring temperature, (3) testing the attachment of strain gages that are used in testing the performance of space shuttle main engines, and (4) testing the thermocouples that are used for determining the performance of blast tube liner material in solid rocket boosters.

Ceramics for Molten Materials Transfer

NASA Technical Reports Server (NTRS)

Standish, Evan; Stefanescu, Doru M.; Curreri, Peter A.

2009-01-01

The paper reviews the main issues associated with molten materials transfer and handling on the lunar surface during the operation of a hig h temperature electrowinning cell used to produce oxygen, with molten iron and silicon as byproducts. A combination of existing technolog ies and purposely designed technologies show promise for lunar exploi tation. An important limitation that requires extensive investigation is the performance of refractory currently used for the purpose of m olten metal containment and transfer in the lunar environment associa ted with electrolytic cells. The principles of a laboratory scale uni t at a scale equivalent to the production of 1 metric ton of oxygen p er year are introduced. This implies a mass of molten materials to be transferred consistent with the equivalent of 1kg regolithlhr proces sed.

Consideration of Conductive Motor Winding Materials at Room and Elevated Temperatures

NASA Technical Reports Server (NTRS)

de Groh, Henry C., III

2015-01-01

A brief history of conductive motor winding materials is presented, comparing various metal motor winding materials and their properties in terms of conductivity, density and cost. The proposed use of carbon nanotubes (CNTs) and composites incorporating CNTs is explored as a potential way to improve motor winding conductivity, density, and reduce motor size which are important to electric aircraft technology. The conductivity of pure Cu, a CNT yarn, and a dilute Cu-CNT composite was measured at room temperature and at several temperatures up to 340 C. The conductivity of the Cu-CNT composite was about 3 percent lower than pure copper's at all temperatures measured. The conductivity of the CNT yarn was about 200 times lower than copper's, however, the yarn's conductivity dropped less with increasing temperature compared to Cu. It is believed that the low conductivity of the yarn is due primarily to high interfacial resistances and the presence of CNTs with low, semiconductor like electrical properties (s-CNT). It is believed the conductivity of the CNT-Cu composite could be improved by not using s-CNT, and instead using only CNTs with high, metallic like electrical properties (m-CNT); and by increasing the vol% m-CNTs.

System for maintaining materials at freezer temperatures for shipping

DOEpatents

Schabron, John F [Laramie, WY; Sorini-Wong, Susan S [Laramie, WY

2007-08-28

At least one embodiment of the inventive technology relates to a frozen environmental sample temperature control system that comprises a frozen formulation having water in an amount from substantially 87% to 78% by weight of the formulation, and salt in an amount from substantially 13% to 22% by weight of the formulation, the system further including at least one container containing the frozen formulation; and a cooler having insulating material disposed between an outer wall and an inner surface that defines an inner chamber into which the at least one container and the at least one frozen environmental sample may be placed for storage and/or transport. Various embodiments may incorporate specific types of insulating material and/or adaptations to an inner surface of the cooler to enhance the insulation effected thereby.

Holmium hafnate: An emerging electronic device material

NASA Astrophysics Data System (ADS)

Pavunny, Shojan P.; Sharma, Yogesh; Kooriyattil, Sudheendran; Dugu, Sita; Katiyar, Rajesh K.; Scott, James F.; Katiyar, Ram S.

2015-03-01

We report structural, optical, charge transport, and temperature properties as well as the frequency dependence of the dielectric constant of Ho2Hf2O7 (HHO) which make this material desirable as an alternative high-k dielectric for future silicon technology devices. A high dielectric constant of ˜20 and very low dielectric loss of ˜0.1% are temperature and voltage independent at 100 kHz near ambient conditions. The Pt/HHO/Pt capacitor exhibits exceptionally low Schottky emission-based leakage currents. In combination with the large observed bandgap Eg of 5.6 eV, determined by diffuse reflectance spectroscopy, our results reveal fundamental physics and materials science of the HHO metal oxide and its potential application as a high-k dielectric for the next generation of complementary metal-oxide-semiconductor devices.

Engineered materials for all-optical helicity-dependent magnetic switching

NASA Astrophysics Data System (ADS)

Fullerton, Eric

2014-03-01

The possibilities of manipulating magnetization without applied magnetic fields have attracted growing attention over the last fifteen years. The low-power manipulation of magnetization, preferably at ultra-short time scales, has become a fundamental challenge with implications for future magnetic information memory and storage technologies. Here we explore the optical manipulation of the magnetization of engineered materials and devices using 100 fs optical pulses. We demonstrate that all optical - helicity dependent switching (AO-HDS) can be observed not only in selected rare-earth transition-metal (RE-TM) alloy films but also in a much broader variety of materials, including alloys, multilayers, heterostructures and RE-free Co-Ir-based synthetic ferrimagnets. The discovery of AO-HDS in RE-free TM-based synthetic ferrimagnets can enable breakthroughs for numerous applications since it exploits materials that are currently used in magnetic data storage, memories and logic technologies. In addition, this materials study of AO-HDS offers valuable insight into the underlying mechanisms involved. Indeed the common denominator of the diverse structures showing AO-HDS in this study is that two ferromagnetic sub-lattices exhibit magnetization compensation (and therefore angular momentum compensation) at temperatures near or above room temperature. We are highlighting that compensation plays a major role and that this compensation can be established at the atomic level as in alloys but also over a larger nanometers scale as in the multilayers or in heterostructures. We will also discuss the potential to extend AO-HDS to new classes of magnetic materials. This work was done in collaboration with S. Mangin, M. Gottwald, C-H. Lambert, D. Steil, V. Uhlíř, L. Pang, M. Hehn, S. Alebrand, M. Cinchetti, G. Malinowski, Y. Fainman, and M. Aeschlimann. Supported by the ANR-10-BLANC-1005 ``Friends,'' a grant from the Advanced Storage Technology Consortium, Partner University Fund ``Novel Magnetic Materials for Spin Torque Physics'' as well as the European Project (OP2M FP7-IOF-2011-298060).

Small rocket research and technology

NASA Technical Reports Server (NTRS)

Schneider, Steven; Biaglow, James

1993-01-01

Small chemical rockets are used on nearly all space missions. The small rocket program provides propulsion technology for civil and government space systems. Small rocket concepts are developed for systems which encompass reaction control for launch and orbit transfer systems, as well as on-board propulsion for large space systems and earth orbit and planetary spacecraft. Major roles for on-board propulsion include apogee kick, delta-V, de-orbit, drag makeup, final insertions, north-south stationkeeping, orbit change/trim, perigee kick, and reboost. The program encompasses efforts on earth-storable, space storable, and cryogenic propellants. The earth-storable propellants include nitrogen tetroxide (NTO) as an oxidizer with monomethylhydrazine (MMH) or anhydrous hydrazine (AH) as fuels. The space storable propellants include liquid oxygen (LOX) as an oxidizer with hydrazine or hydrocarbons such as liquid methane, ethane, and ethanol as fuels. Cryogenic propellants are LOX or gaseous oxygen (GOX) as oxidizers and liquid or gaseous hydrogen as fuels. Improved performance and lifetime for small chemical rockets are sought through the development of new predictive tools to understand the combustion and flow physics, the introduction of high temperature materials to eliminate fuel film cooling and its associated combustion inefficiency, and improved component designs to optimize performance. Improved predictive technology is sought through the comparison of both local and global predictions with experimental data. Results indicate that modeling of the injector and combustion process in small rockets needs improvement. High temperature materials require the development of fabrication processes, a durability data base in both laboratory and rocket environments, and basic engineering property data such as strength, creep, fatigue, and work hardening properties at both room and elevated temperature. Promising materials under development include iridium-coated rhenium and a ceramic composite of mixed hafnium carbide and tantalum carbide reinforced with graphite fibers.

Preparation of activated carbon from waste plastics polyethylene terephthalate as adsorbent in natural gas storage

NASA Astrophysics Data System (ADS)

Yuliusman; Nasruddin; Sanal, A.; Bernama, A.; Haris, F.; Ramadhan, I. T.

2017-02-01

The main problem is the process of natural gas storage and distribution, because in normal conditions of natural gas in the gas phase causes the storage capacity be small and efficient to use. The technology is commonly used Compressed Natural Gas (CNG) and Liquefied Natural Gas (LNG). The weakness of this technology safety level is low because the requirement for high-pressure CNG (250 bar) and LNG requires a low temperature (-161°C). It takes innovation in the storage of natural gas using the technology ANG (Adsorbed Natural Gas) with activated carbon as an adsorbent, causing natural gas can be stored in a low pressure of about 34.5. In this research, preparation of activated carbon using waste plastic polyethylene terephthalate (PET). PET plastic waste is a good raw material for making activated carbon because of its availability and the price is a lot cheaper. Besides plastic PET has the appropriate characteristics as activated carbon raw material required for the storage of natural gas because the material is hard and has a high carbon content of about 62.5% wt. The process of making activated carbon done is carbonized at a temperature of 400 ° C and physical activation using CO2 gas at a temperature of 975 ° C. The parameters varied in the activation process is the flow rate of carbon dioxide and activation time. The results obtained in the carbonization process yield of 21.47%, while the yield on the activation process by 62%. At the optimum process conditions, the CO2 flow rate of 200 ml/min and the activation time of 240 minutes, the value % burn off amounted to 86.69% and a surface area of 1591.72 m2/g.

High Temperature Superconductors: From Delivery to Applications (Presentation from 2011 Ernest Orlando Lawrence Award-winner, Dr. Amit Goyal, and including introduction by Energy Secretary, Dr. Steven Chu)

DOE Office of Scientific and Technical Information (OSTI.GOV)

Goyal, Amit

Dr. Amit Goyal, a high temperature superconductivity (HTS) researcher at Oak Ridge National Laboratory, was named a 2011 winner of the Department of Energy's Ernest Orlando Lawrence Award honoring U.S. scientists and engineers for exceptional contributions in research and development supporting DOE and its mission. Winner of the award in the inaugural category of Energy Science and Innovation, Dr. Goyal was cited for his work in 'pioneering research and transformative contributions to the field of applied high temperature superconductivity, including fundamental materials science advances and technical innovations enabling large-scale applications of these novel materials.' Following his basic research in grain-to-grainmore » supercurrent transport, Dr. Goyal focused his energy in transitioning this fundamental understanding into cutting-edge technologies. Under OE sponsorship, Dr. Goyal co-invented the Rolling Assisted Bi-Axially Textured Substrate technology (RABiTS) that is used as a substrate for second generation HTS wires. OE support also led to the invention of Structural Single Crystal Faceted Fiber Substrate (SSIFFS) and the 3-D Self Assembly of Nanodot Columns. These inventions and associated R&D resulted in 7 R&D 100 Awards including the 2010 R&D Magazine's Innovator of the Year Award, 3 Federal Laboratory Consortium Excellence in Technology Transfer National Awards, a DOE Energy 100 Award and many others. As a world authority on HTS materials, Dr. Goyal has presented OE-sponsored results in more than 150 invited talks, co-authored more than 350 papers and is a fellow of 7 professional societies.« less

Combined process "helical rolling-pressing" and its effect on the microstructure of ferrous and non-ferrous materials

NASA Astrophysics Data System (ADS)

Naizabekov, Abdrakhman; Lezhnev, Sergey; Arbuz, Alexandr; Panin, Evgeniy

2018-02-01

Ultrafine-grained materials are one of the most promising structural and functional materials. However, the known methods of obtaining them are not enough powerful and technologically advanced for profitable industrial applications. Development of the combined process "helical rolling-pressing" is an attempt to bring technology to produce ultrafine-grained materials to the industry. The combination of intense processing of the surface by helical rolling and the entire cross section of workpiece in equal channel angular matrix, with intense deformation by torsion between rolls and matrix will increase the degree of deformation per pass and allows to mutually compensate disadvantages of these methods in the case of their separate use. This paper describes the development of a laboratory stand and study of influence of combined process "helical rolling-pressing"on the microstructure of tool steel, technical copper and high alloy stainless high-temperature steel.

Optical pH detector based on LTCC and sol-gel technologies

NASA Astrophysics Data System (ADS)

Tadaszak, R. J.; Łukowiak, A.; Golonka, L. J.

2013-01-01

This paper presents an investigation on using sol-gel thin film as a material for sensors application in LTCC (Low Temperature Co-fired Ceramics) technology. This material gives the opportunity to make new, low-cost highly integrated optoelectronic devices. Sensors with optical detection are a significant part of these applications. They can be used for quick and safe diagnostics of some parameters. Authors present a pH detector with the optical detection system made of the LTCC material. The main part of the device is a flow channel with the chamber and sol-gel active material. The silica sol-gel with bromocresol green indicator was used. As the absorbance of sol-gel layer changes with the pH value of a measured medium, the transmitted light power was measured. The pH detector was integrated with the electronic components on the LTCC substrate.

Fourth international cryogenic materials conference

DOE Office of Scientific and Technical Information (OSTI.GOV)

Reed, R.P.; Clark, A.F.

1982-01-01

In a comprehensive and current collection of 911 papers on a vest range of materials research topics in the field of cryogenic technology, this 924-page volume presents the most recent work of an international spectrum of materials and cyrogenic engineers at industrial and academic laboratories and institutions. The papers are collected under the broad headings of structural alloys; nometallics and composites; flux pinning in superconductors; high field superconductors; A15 superconductors; multiply-connected superconductors; superconductor properties and measurements; strain effects in superconductors; superconductor performance; the fabrication of superconductors; and the fabrication of structural alloys and composits. Ample and adequate photographic, plot, schematic,more » and tabulation illustration are included; the volume is also cross-referenced and has an author, materials, and subject index. It is volume 28 in a series which annually updates the existing knowledge of all areas of low-temperature technology.« less

Effects of temperature changes and stress loading on the mechanical and shape memory properties of thermoplastic materials with different glass transition behaviours and crystal structures.

PubMed

Iijima, Masahiro; Kohda, Naohisa; Kawaguchi, Kyotaro; Muguruma, Takeshi; Ohta, Mitsuru; Naganishi, Atsuko; Murakami, Takashi; Mizoguchi, Itaru

2015-12-01

To investigate the effects of temperature changes and stress loading on the mechanical and shape memory properties of thermoplastic materials with different glass transition behaviours and crystal structures. Five thermoplastic materials, polyethylene terephthalate glycol (Duran®, Scheu Dental), polypropylene (Hardcast®, Scheu Dental), and polyurethane (SMP MM®, SMP Technologies) with three different glass transition temperatures (T g) were selected. The T g and crystal structure were assessed using differential scanning calorimetry and X-ray diffraction. The deterioration of mechanical properties by thermal cycling and the orthodontic forces during stepwise temperature changes were investigated using nanoindentation testing and custom-made force-measuring system. The mechanical properties were also evaluated by three-point bending tests; shape recovery with heating was then investigated. The mechanical properties for each material were decreased significantly by 2500 cycles and great decrease was observed for Hardcast (crystal plastic) with higher T g (155.5°C) and PU 1 (crystalline or semi-crystalline plastic) with lower T g (29.6°C). The Duran, PU 2, and PU 3 with intermediate T g (75.3°C for Duran, 56.5°C for PU 2, and 80.7°C for PU 3) showed relatively stable mechanical properties with thermal cycling. The polyurethane polymers showed perfect shape memory effect within the range of intraoral temperature changes. The orthodontic force produced by thermoplastic appliances decreased with the stepwise temperature change for all materials. Orthodontic forces delivered by thermoplastic appliances may influence by the T g of the materials, but not the crystal structure. Polyurethane is attractive thermoplastic materials due to their unique shape memory phenomenon, but stress relaxation with temperature changes is expected. © The Author 2015. Published by Oxford University Press on behalf of the European Orthodontic Society. All rights reserved. For permissions, please email: journals.permissions@oup.com.

New Technology for Microfabrication and Testing of a Thermoelectric Device for Generating Mobile Electrical Power

NASA Technical Reports Server (NTRS)

Prasad, Narasimha S.; Taylor, Patrick J.; Trivedi, Sudhir B.; Kutcher, Susan

2012-01-01

Thermoelectric (TE) power generation is an increasingly important power generation technology. Major advantages include: no moving parts, low-weight, modularity, covertness/silence, high power density, low amortized cost, and long service life with minimum or no required maintenance. Despite low efficiency of power generation, there are many specialized needs for electrical power that TE technologies can uniquely and successfully address. Recent advances in thermoelectric materials technology have rekindled acute interest in thermoelectric power generation. We have developed single crystalline n- and p- type PbTe crystals and are also, developing PbTe bulk nanocomposites using PbTe nano powders and emerging filed assisted sintering technology (FAST). We will discuss the materials requirements for efficient thermoelectric power generation using waste heat at intermediate temperature range (6500 to 8500 K). We will present our recent results on production of n- and p- type PbTe crystals and their thermoelectric characterization. Relative characteristics and performance of PbTe bulk single crystals and nano composites for thermoelectric power generation will be discussed.

A review of recent measurements of optical and thermal properties of alpha-mercuric iodide

NASA Astrophysics Data System (ADS)

Burger, A.; Morgan, S. H.; Silberman, E.; Nason, D.; Cheng, A. Y.

The knowledge of the physical properties of a crystal and their relation to the nature and content of defects are essential for both applications and fundamental reasons. Alpha-mercuric iodide (alpha-HgI2) is a material which was found important applications as room temperature x ray and gamma ray detectors. Some recent thermal and optical measurements of this material, using the samples of improved crystallinity which are now available, are reviewed below. Heretofore, these properties have received less attention than the mechanical and electrical properties, particularly at elevated temperatures. In the technology of alpha-HgI2 where there is a continuing motivation to obtain larger single crystals without compromising the material quality, a better knowledge of the thermal and optical properties may lead to improvements in the processes of material purification, crystal growth, and device fabrication.

Thermoelectricity for future sustainable energy technologies

NASA Astrophysics Data System (ADS)

Weidenkaff, Anke

2017-07-01

Thermoelectricity is a general term for a number of effects describing the direct interconversion of heat and electricity. Thermoelectric devices are therefore promising, environmental-friendly alternatives to conventional power generators or cooling units. Since the mid-90s, research on thermoelectric properties and their applications has steadily increased. In the course of years, the development of high-temperature resistant TE materials and devices has emerged as one of the main areas of interest focusing both on basic research and practical applications. A wide range of innovative and cost-efficient material classes has been studied and their properties improved. This has also led to advances in synthesis and metrology. The paper starts out with thermoelectric history, basic effects underlying thermoelectric conversion and selected examples of application. The main part focuses on thermoelectric materials including an outline of the design rules, a review on the most common materials and the feasibility of improved future high-temperature thermoelectric converters.

Polymer substrates for flexible photovoltaic cells application in personal electronic system

NASA Astrophysics Data System (ADS)

Znajdek, K.; Sibiński, M.; Strąkowska, A.; Lisik, Z.

2016-01-01

The article presents an overview of polymeric materials for flexible substrates in photovoltaic (PV) structures that could be used as power supply in the personal electronic systems. Four types of polymers have been elected for testing. The first two are the most specialized and heat resistant polyimide films. The third material is transparent polyethylene terephthalate film from the group of polyesters which was proposed as a cheap and commercially available substrate for the technology of photovoltaic cells in a superstrate configuration. The last selected polymeric material is a polysiloxane, which meets the criteria of high elasticity, is temperature resistant and it is also characterized by relatively high transparency in the visible light range. For the most promising of these materials additional studies were performed in order to select those of them which represent the best optical, mechanical and temperature parameters according to their usage for flexible substrates in solar cells.

Enabling fast charging - A battery technology gap assessment

NASA Astrophysics Data System (ADS)

Ahmed, Shabbir; Bloom, Ira; Jansen, Andrew N.; Tanim, Tanvir; Dufek, Eric J.; Pesaran, Ahmad; Burnham, Andrew; Carlson, Richard B.; Dias, Fernando; Hardy, Keith; Keyser, Matthew; Kreuzer, Cory; Markel, Anthony; Meintz, Andrew; Michelbacher, Christopher; Mohanpurkar, Manish; Nelson, Paul A.; Robertson, David C.; Scoffield, Don; Shirk, Matthew; Stephens, Thomas; Vijayagopal, Ram; Zhang, Jiucai

2017-11-01

The battery technology literature is reviewed, with an emphasis on key elements that limit extreme fast charging. Key gaps in existing elements of the technology are presented as well as developmental needs. Among these needs are advanced models and methods to detect and prevent lithium plating; new positive-electrode materials which are less prone to stress-induced failure; better electrode designs to accommodate very rapid diffusion in and out of the electrode; measure temperature distributions during fast charge to enable/validate models; and develop thermal management and pack designs to accommodate the higher operating voltage.

Development of a Complimentary Low Temperature Decontamination Technique for Spacecraft Materials

NASA Astrophysics Data System (ADS)

Pottage, Thomas; Bennett, Allan; Walker, James; Fowler, Chantal; Weber, Christina; Rohr, Thomas; Kminek, Gerhard

Dry heat microbial reduction (DHMR) is one of the current processes used to ensure that the microbial burden of a spacecraft lander meets the predetermined levels set out within the COSPAR policy regarding planetary protection. DHMR involves heating the craft or compo-nents to approximately 110-125C for over 6-30hrs, and was previously used to decontaminate the entire Viking lander spacecraft and parts of almost all other spacecrafts sent to Mars after-wards. This process, whilst proving effective and reproducible is not compatible with the some highly sensitive sensor and electronic components of a modern spacecraft. For these components an alternative method for low temperature decontamination needs to be identified. The Health Protection Agency, UK, investigated three gaseous decontamination technologies in a project funded by European Space Agency. These technologies consisted of two hydrogen peroxide technologies (Vapour Hydrogen Peroxide, Steris Inc. and Hydrogen Peroxide Vapour, Bioquell Ltd.) and one chlorine dioxide (ClorDiSys) system. The technologies were chosen after a comprehensive literature study identified them as the most suitable technologies for the decontamination process. An environmental chamber (20m3 ) was used as the test chamber to expose two commercially available biological indicators, three naturally occurring organisms chosen by ESA and a range of spacecraft materials to each of the technologies. The commercial biological indicators, Bacil-lus atrophaeus and Geobacillus sterothermophilus, were exposed to 3 varying concentrations of each of the technologies in order to attempt to achieve a 6-log reduction in recoverable organ-isms. After these results were obtained the most efficacious cycle was chosen for each technology and the naturally occurring organisms and materials to be tested were exposed to three cy-cles. Whilst the microbial enumeration was completed at the HPA, material compatibility was undertaken at ESTEC and residue analysis at the Rutherford Appleton Laboratories, UK. The results demonstrate that a concentration of approximately 1.1mg/l of hydrogen peroxide injected into the test chamber (35o C) is adequate to demonstrate a 6-log reduction in biological organism recovery for all of the 5 organisms tested over a 20 min period using the Steris generator. The final phase of the work is currently underway and will be incorporated into the final presentation.

Advanced high temperature materials for the energy efficient automotive Stirling engine

NASA Technical Reports Server (NTRS)

Titran, R. H.; Stephens, J. R.

1984-01-01

The Stirling Engine is under investigated jointly by the Department of Energy and NASA Lewis as an alternative to the internal combustion engine for automotive applications. The Stirling Engine is an external combustion engine that offers the advantage of high fuel economy, low emissions, low noise, and low vibrations compared to current internal combustion automotive engines. The most critical component from a materials viewpoint is the heater head consisting of the cylinders, heating tubes, and regenerator housing. Materials requirements for the heater head include compatibility with hydrogen, resistance to hydrogen permeation, high temperature oxidation/corrosion resistance and high temperature creep-rupture and fatigue properties. A continuing supporting materials research and technology program has identified the wrought alloys CG-27 and 12RN72 and the cast alloys XF-818 and NASAUT 4G-A1 as candidate replacements for the cobalt containing alloys used in current prototype engines. Based on the materials research program in support of the automotive Stirling engine it is concluded that manufacture of the engine is feasible from low cost iron-base alloys rather than the cobalt alloys rather than the cobalt alloys used in prototype engines. This paper will present results of research that led to this conclusion.

On-Board Chemical Propulsion Technology

NASA Technical Reports Server (NTRS)

Reed, Brian D.

2004-01-01

On-board propulsion functions include orbit insertion, orbit maintenance, constellation maintenance, precision positioning, in-space maneuvering, de-orbiting, vehicle reaction control, planetary retro, and planetary descent/ascent. This paper discusses on-board chemical propulsion technology, including bipropellants, monopropellants, and micropropulsion. Bipropellant propulsion has focused on maximizing the performance of Earth storable propellants by using high-temperature, oxidation-resistant chamber materials. The performance of bipropellant systems can be increased further, by operating at elevated chamber pressures and/or using higher energy oxidizers. Both options present system level difficulties for spacecraft, however. Monopropellant research has focused on mixtures composed of an aqueous solution of hydroxl ammonium nitrate (HAN) and a fuel component. HAN-based monopropellants, unlike hydrazine, do not present a vapor hazard and do not require extraordinary procedures for storage, handling, and disposal. HAN-based monopropellants generically have higher densities and lower freezing points than the state-of-art hydrazine and can higher performance, depending on the formulation. High-performance HAN-based monopropellants, however, have aggressive, high-temperature combustion environments and require advances in catalyst materials or suitable non-catalytic ignition options. The objective of the micropropulsion technology area is to develop low-cost, high-utility propulsion systems for the range of miniature spacecraft and precision propulsion applications.

Vanadium—lithium in-pile loop for comprehensive tests of vanadium alloys and multipurpose coatings

NASA Astrophysics Data System (ADS)

Lyublinski, I. E.; Evtikhin, V. A.; Ivanov, V. B.; Kazakov, V. A.; Korjavin, V. M.; Markovchev, V. K.; Melder, R. R.; Revyakin, Y. L.; Shpolyanskiy, V. N.

1996-10-01

The reliable information on design and material properties of self-cooled Li sbnd Li blanket and liquid metal divertor under neutron radiation conditions can be obtained using the concept of combined technological and material in-pile tests in a vanadium—lithium loop. The method of in-pile loop tests includes studies of vanadium—base alloys resistance, weld resistance under mechanical stress, multipurpose coating formation processes and coatings' resistance under the following conditions: high temperature (600-700°C), lithium velocities up to 10 m/s, lithium with controlled concentration of impurities and technological additions, a neutron load of 0.4-0.5 MW/m 2 and level of irradiation doses up to 5 dpa. The design of such an in-pile loop is considered. The experimental data on corrosion and compatibility with lithium, mechanical properties and welding technology of the vanadium alloys, methods of coatings formation and its radiation tests in lithium environment in the BOR-60 reactor (fast neutron fluence up to 10 26 m -2, irradiation temperature range of 500-523°C) are presented and analyzed as a basis for such loop development.

Harsh environment sensor development for advanced energy systems

NASA Astrophysics Data System (ADS)

Romanosky, Robert R.; Maley, Susan M.

2013-05-01

Highly efficient, low emission power systems have extreme conditions of high temperature, high pressure, and corrosivity that require monitoring. Sensing in these harsh environments can provide key information that directly impacts process control and system reliability. To achieve the goals and demands of clean energy, the conditions under which fossil fuels are converted into heat and power are harsh compared to traditional combustion/steam cycles. Temperatures can extend as high as 1600 Celsius (°C) in certain systems and pressures can reach as high as 5000 pounds per square inch (psi)/340 atmospheres (atm). The lack of suitable measurement technology serves as a driver for the innovations in harsh environment sensor development. Two major considerations in the development of harsh environments sensors are the materials used for sensing and the design of the sensing device. This paper will highlight the U.S. Department of Energy's, Office of Fossil Energy and National Energy Technology Laboratory's Program in advanced sensing concepts that are aimed at addressing the technology needs and drivers through the development of new sensor materials and designs capable of withstanding harsh environment conditions. Recent developments with harsh environment sensors will be highlighted and future directions towards in advanced sensing will be introduced.

High Temperature Nanocomposites For Nuclear Thermal Propulsion and In-Space Fabrication by Hyperbaric Pressure Laser Chemical Vapor Deposition

NASA Astrophysics Data System (ADS)

Maxwell, J. L.; Webb, N. D.; Espinoza, M.; Cook, S.; Houts, M.; Kim, T.

Nuclear Thermal Propulsion (NTP) is an indispensable technology for the manned exploration of the solar system. By using Hyperbaric Pressure Laser Chemical Vapor Deposition (HP-LCVD), the authors propose to design and build a promising next-generation fuel element composed of uranium carbide UC embedded in a latticed matrix of highly refractory Ta4HfC5 for an NTP rocket capable of sustaining temperatures up to 4000 K, enabling an Isp of up to 1250 s. Furthermore, HP-LCVD technology can also be harnessed to enable 3D rapid prototyping of a variety of materials including metals, ceramics and composites, opening up the possibility of in-space fabrication of components, replacement parts, difficult-to-launch solar sails and panels and a variety of other space structures. Additionally, rapid prototyping with HP-LCVD makes a feasible "live off the land" strategy of interplanetary and interstellar exploration ­ the precursors commonly used in the technology are found, often in abundance, on other solar system bodies either as readily harvestable gas (e.g. methane) or as a raw material that could be converted into a suitable precursor (e.g. iron oxide into ferrocene on Mars).

Aerospace Plane Technology, Research and Development Efforts in Europe

DTIC Science & Technology

1991-07-25

to conventional titanium alloys. Moreover, ti- aluminide has one-half the weight of the material previously used at these high temperatures. Real Gas...for the engine’s blades , turbine blisk (a turbine disk with integral blades ), Page 44 GAO/NSIAID-91-194 Aerospace Plane Technology Chapter 3 European...X-30 fuselage section from silicon carbide-reinforced titanium and manufactured an X-30 fuel tank from a graphite-polyamide composite. Although

Metallurgical coatings and thin films; Proceedings of the International Conference, 18th, San Diego, CA, Apr. 22-26, 1991. Vols. 1 & 2

NASA Technical Reports Server (NTRS)

Mcguire, Gary E. (Editor); Mcintyre, Dale C. (Editor); Hofmann, Siegfried (Editor)

1991-01-01

A conference on metallurgical coatings and thin films produced papers in the areas of coatings for use at high temperatures; hard coatings and deposition technologies; diamonds and related materials; tribological coatings/surface modifications; thin films for microelectronics and high temperature superconductors; optical coatings, film characterization, magneto-optics, and guided waves; and methods for characterizing films and modified surfaces.

Feasibility of Cathode Surface Coating Technology for High-Energy Lithium-ion and Beyond-Lithium-ion Batteries.

PubMed

Kalluri, Sujith; Yoon, Moonsu; Jo, Minki; Liu, Hua Kun; Dou, Shi Xue; Cho, Jaephil; Guo, Zaiping

2017-12-01

Cathode material degradation during cycling is one of the key obstacles to upgrading lithium-ion and beyond-lithium-ion batteries for high-energy and varied-temperature applications. Herein, we highlight recent progress in material surface-coating as the foremost solution to resist the surface phase-transitions and cracking in cathode particles in mono-valent (Li, Na, K) and multi-valent (Mg, Ca, Al) ion batteries under high-voltage and varied-temperature conditions. Importantly, we shed light on the future of materials surface-coating technology with possible research directions. In this regard, we provide our viewpoint on a novel hybrid surface-coating strategy, which has been successfully evaluated in LiCoO 2 -based-Li-ion cells under adverse conditions with industrial specifications for customer-demanding applications. The proposed coating strategy includes a first surface-coating of the as-prepared cathode powders (by sol-gel) and then an ultra-thin ceramic-oxide coating on their electrodes (by atomic-layer deposition). What makes it appealing for industry applications is that such a coating strategy can effectively maintain the integrity of materials under electro-mechanical stress, at the cathode particle and electrode- levels. Furthermore, it leads to improved energy-density and voltage retention at 4.55 V and 45 °C with highly loaded electrodes (≈24 mg.cm -2 ). Finally, the development of this coating technology for beyond-lithium-ion batteries could be a major research challenge, but one that is viable. © 2017 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

Three-Dimensional (3D) Additive Construction: Printing with Regolith

NASA Technical Reports Server (NTRS)

Tsoras, Alexandra

2013-01-01

Three dimensional (3D) printing is a new and booming topic in many realms of research and engineering technology. When it comes to space science and aerospace engineering, it can be useful in numerous ways. As humans travel deeper into space and farther from Earth, sending large quantities of needed supplies from Earth for a mission becomes astronomically expensive and less plausible. In order to reach further to new places, In Situ Resource Utilization (ISRU), a project that pushes for technologies to use materials already present in the destination's environment, is necessary. By using materials already available in space such as regolith from the Moon, Mars, or an asteroid's surface, fewer materials need to be brought into space on a launched vehicle. This allows a vehicle to be filled with more necessary supplies for a deep space mission that may not be found in space, like food and fuel. This project's main objective was to develop a 3D printer that uses regolith to "print" large structures, such as a dome, to be used as a heat shield upon a vehicle's reentry into the atmosphere or even a habitat. 3D printing is a growing technology that uses many different methods to mix, heat, and mold a material into a specific shape. In order to heat the regolith enough to stick together into a solid shape, it must be sintered at each layer of material that is laid. Sintering is a process that heats and compresses a powdered material until it fuses into a solid, which requires a lot of energy input. As an alternative, a polymer can be mixed with the regolith before or as it is sent to the 3D printer head to be placed in the specific shape. The addition of the polymer, which melts and binds at much lower temperatures than sintering temperatures, greatly decreases the required heating temperature and energy input. The main task of the project was to identify a functional material for the printer. The first step was to find a miscible. polymer/solvent solution. This solution was added to the regolith and the solvent was evaporated essentially leaving polymer-coated regolith particles. This material would be sent through the printer head and heated layer by layer to melt the polymer and bind the regolith. This method was one of many in a large goal to utilize materials in space with a custom-made 3D printer that builds dome-shaped habitats and other essential equipment for future deep space missions.

Development of Electronics for Low-Temperature Space Missions

NASA Technical Reports Server (NTRS)

Patterson, Richard L.; Hammoud, Ahmad; Dickman, John E.; Gerber, Scott S.; Overton, Eric

2001-01-01

Electronic systems that are capable of operating at cryogenic temperatures will be needed for many future NASA space missions, including deep space probes and spacecraft for planetary surface exploration. In addition to being able to survive the harsh deep space environment, low-temperature electronics would help improve circuit performance, increase system efficiency, and reduce payload development and launch costs. Terrestrial applications where components and systems must operate in low-temperature environments include cryogenic instrumentation, superconducting magnetic energy storage, magnetic levitation transportation systems, and arctic exploration. An ongoing research and development project for the design, fabrication, and characterization of low-temperature electronics and supporting technologies at NASA Glenn Research Center focuses on efficient power systems capable of surviving in and exploiting the advantages of low-temperature environments. Supporting technologies include dielectric and insulating materials, semiconductor devices, passive power components, optoelectronic devices, and packaging and integration of the developed components into prototype flight hardware. An overview of the project is presented, including a description of the test facilities, a discussion of selected data from component testing, and a presentation of ongoing research activities being performed in collaboration with various organizations.

QC/QA differences between hot mix asphalt (HMA) and warm mix asphalt (WMA).

DOT National Transportation Integrated Search

2013-01-01

WMA represents a group of technologies which allow a reduction in temperatures at which asphalt mixtures are produced and placed on the road. ODOT Materials Division has conducted preliminary inquiries into QC/QA testing for WMA. Some respondents ind...

New Technology for Microfabrication and Testing of a Thermoelectric Device for Generating Mobile Electrical Power

NASA Technical Reports Server (NTRS)

Prasad, Narashimha S.; Taylor, Patrick J.; Trivedi, Sudhir B.; Kutcher, Susan

2010-01-01

We report the results of fabrication and testing of a thermoelectric power generation module. The module was fabricated using a new "flip-chip" module assembly technique that is scalable and modular. This technique results in a low value of contact resistivity ( < or = 10(exp 5) Ohms-sq cm). It can be used to leverage new advances in thin-film and nanostructured materials for the fabrication of new miniature thermoelectric devices. It may also enable monolithic integration of large devices or tandem arrays of devices on flexible or curved surfaces. Under mild testing, a power of 22 mW/sq cm was obtained from small (<100 K) temperature differences. At higher, more realistic temperature differences, approx.500 K, where the efficiency of these materials greatly improves, this power density would scale to between 0.5 and 1 Watt/cm2. These results highlight the excellent potential for the generation and scavenging of electrical power of practical and usable magnitude for remote applications using thermoelectric power generation technologies.

Stable biexcitons in two-dimensional metal-halide perovskites with strong dynamic lattice disorder

NASA Astrophysics Data System (ADS)

Thouin, Félix; Neutzner, Stefanie; Cortecchia, Daniele; Dragomir, Vlad Alexandru; Soci, Cesare; Salim, Teddy; Lam, Yeng Ming; Leonelli, Richard; Petrozza, Annamaria; Kandada, Ajay Ram Srimath; Silva, Carlos

2018-03-01

With strongly bound and stable excitons at room temperature, single-layer, two-dimensional organic-inorganic hybrid perovskites are viable semiconductors for light-emitting quantum optoelectronics applications. In such a technological context, it is imperative to comprehensively explore all the factors—chemical, electronic, and structural—that govern strong multiexciton correlations. Here, by means of two-dimensional coherent spectroscopy, we examine excitonic many-body effects in pure, single-layer (PEA) 2PbI4 (PEA = phenylethylammonium). We determine the binding energy of biexcitons—correlated two-electron, two-hole quasiparticles—to be 44 ±5 meV at room temperature. The extraordinarily high values are similar to those reported in other strongly excitonic two-dimensional materials such as transition-metal dichalcogenides. Importantly, we show that this binding energy increases by ˜25 % upon cooling to 5 K. Our work highlights the importance of multiexciton correlations in this class of technologically promising, solution-processable materials, in spite of the strong effects of lattice fluctuations and dynamic disorder.

Commercially Available Activated Carbon Fiber Felt Enables Efficient Solar Steam Generation.

PubMed

Li, Haoran; He, Yurong; Hu, Yanwei; Wang, Xinzhi

2018-03-21

Sun-driven steam generation is now possible and has the potential to help meet future energy needs. Current technologies often use solar condensers to increase solar irradiance. More recently, a technology for solar steam generation that uses heated surface water and low optical concentration is reported. In this work, a commercially available activated carbon fiber felt is used to generate steam efficiently under one sun illumination. The evaporation rate and solar conversion efficiency reach 1.22 kg m -2 h -1 and 79.4%, respectively. The local temperature of the evaporator with a floating activated carbon fiber felt reaches 48 °C. Apart from the high absorptivity (about 94%) of the material, the evaporation performance is enhanced thanks to the well-developed pores for improved water supply and steam escape and the low thermal conductivity, which enables reduced bulk water temperature increase. This study helps to find a promising material for solar steam generation using a water evaporator that can be produced economically (∼6 $/m 2 ) with long-term stability.

Thermoelectric Generation Of Current - Theoretical And Experimental Analysis

NASA Astrophysics Data System (ADS)

Ruciński, Adam; Rusowicz, Artur

2017-12-01

This paper provides some information about thermoelectric technology. Some new materials with improved figures of merit are presented. These materials in Peltier modules make it possible to generate electric current thanks to a temperature difference. The paper indicates possible applications of thermoelectric modules as interesting tools for using various waste heat sources. Some zero-dimensional equations describing the conditions of electric power generation are given. Also, operating parameters of Peltier modules, such as voltage and electric current, are analyzed. The paper shows chosen characteristics of power generation parameters. Then, an experimental stand for ongoing research and experimental measurements are described. The authors consider the resistance of a receiver placed in the electric circuit with thermoelectric elements. Finally, both the analysis of experimental results and conclusions drawn from theoretical findings are presented. Voltage generation of about 1.5 to 2.5 V for the temperature difference from 65 to 85 K was observed when a bismuth telluride thermoelectric couple (traditionally used in cooling technology) was used.

Heavy-section steel technology program. Semiannual progress report for period ending February 28, 1973

DOE Office of Scientific and Technical Information (OSTI.GOV)

None

1974-02-01

The materials investigations under the HSST program are divided into studies of unirradiated materials and studies of irradiation effects. The studies of unirradiated materials, which include inspection, characterization, metallurgy, variability determinations, transition temperature investigations, fracture mechanics studies, and fatigue-crack propagation tests, are discussed. The investigations of irradiated materials include studies of radiation effects on A-533-B steel. Results of studies on thick pressure vessels and pipes of ASTM A508 steel are also reported along with results of studies on Mode III crack extension in reactor piping. (JRD)

Multiple electrical phase transitions in Al substituted barium hexaferrite

NASA Astrophysics Data System (ADS)

Kumar, Sunil; Supriya, Sweety; Kar, Manoranjan

2017-12-01

Barium hexaferrite is known to be a very good ferromagnetic material. However, it shows very good dielectric properties, i.e., the dielectric constant is comparable to that of the ferroelectric material. However, its crystal symmetry does not allow it to be a ferroelectric material. Hence, the electrical properties have revived the considerable research interest on these materials, not only for academic interest, but also for technological applications. There are a few reports on temperature dependent dielectric behavior of these materials. However, the exact cause of dielectric as well as electrical conductivity is yet to be established. Hence, Al (very good conducting material) substituted barium hexaferrite (BaFe12-xAlxO19, x = 0.0-4.0) has been prepared by following the modified sol-gel method to understand the ac and DC electrical properties of these materials. The crystal structure and parameters have been studied by employing the XRD and FTIR techniques. There are two transition temperatures, which have been observed in the temperature dependent ac dielectric and DC resistivity measurement. The response of dielectric behaviors to temperature is similar to that of the ferroelectric material; however, the dielectric polarization is due to the polaron hopping, which is evident from the DC resistivity analysis. Hence, the present observations lead to understand the electrical properties of barium hexaferrite. The frequency dependent dielectric dispersion can be understood by the modified Debye model. More interestingly, the dielectric constant decreases and DC resistivity increases with the increase in the Al concentration, which has the correlation between bond length modifications in the crystal due to substitution.

Silicon Carbide Technologies for Lightweighted Aerospace Mirrors

NASA Astrophysics Data System (ADS)

Matson, L.; Chen, M.; Deblonk, B.; Palusinski, I.

The use of monolithic glass and beryllium to produce lightweighted aerospace mirror systems has reached its limits due to the long lead times, high processing costs, environmental effects and launch load/weight requirements. New material solutions and manufacturing processes are required to meet DoD's directed energy weapons, reconnaissance/surveillance, and secured communications needs. Over the past several years the Air Force, MDA, and NASA has focused their efforts on the fabrication, lightweighting, and scale-up of numerous silicon carbide (SiC) based materials. It is anticipated that SiC can be utilized for most applications from cryogenic to high temperatures. This talk will focus on describing the SOA for these (near term) SiC technology solutions for making mirror structural substrates, figuring and finishing technologies being investigated to reduce cost time and cost, and non-destructive evaluation methods being investigated to help eliminate risk. Mirror structural substrates made out of advanced engineered materials (far term solutions) such as composites, foams, and microsphere arrays for ultra lightweighting will also be briefly discussed.

Novel Hybrid Ablative/Ceramic Heatshield for Earth Atmospheric Re-Entry

NASA Astrophysics Data System (ADS)

Barcena, J.; Florez, S.; Perez, B.; Pinaud, G.; Bouilly, J.-M.; Fischer, W. P. P.; de Montburn, A.; Descomps, M.; Zuber, C.; Rotaermel, W.; Hald, H.; Pereira, C.; Mergia, K.; Triantou, K.; Marinou, A.; Vekinis, G.; Ionescu, G.; Ban, C.; Stefan, A.; Leroy, V.; Bernard, D.; Massuti, B.; Herdrich, G.

2014-06-01

Original approaches based on ablative materials and novel TPS solutions are required for space applications, where resistance to extreme oxidative environments and high temperatures are required. For future space exploration the demands for the thermal shield go beyond the current state-of-the-art. Therefore, the development of new thermal protection materials and systems at a reasonable mass budget is absolutely essential to ensure European non-dependence on corresponding restricted technologies. The three year long FP7 project HYDRA aims at the development of a novel thermal protection system through the integration of a low density ablative outer-shield on top of an advanced thermo-structural ceramic composite layer and will provide an innovative technology solution consistent with the capabilities of European technologies and material providers. This paper summarizes the current status of the scientific activities carried out after two years of progress in terms of design, integration and verification of a robust and lightweight thermal shield solution for atmospheric earth re-entry.

Use of cooling air heat exchangers as replacements for hot section strategic materials

NASA Technical Reports Server (NTRS)

Gauntner, J. W.

1983-01-01

Because of financial and political constraints, strategic aerospace materials required for the hot section of future engines might be in short supply. As an alternative to these strategic materials, this study examines the use of a cooling air heat exchanger in combination with less advanced hot section materials. Cycle calculations are presented for future turbofan systems with overall pressure ratios to 65, bypass ratios near 13, and combustor exit temperatures to 3260 R. These calculations quantify the effect on TSFC of using a decreased materials technology in a turbofan system. The calculations show that the cooling air heat exchanger enables the feasibility of these engines.

Composite structural materials

NASA Technical Reports Server (NTRS)

Ansell, G. S.; Loewy, R. G.; Wiberley, S. E.

1984-01-01

Progress is reported in studies of constituent materials composite materials, generic structural elements, processing science technology, and maintaining long-term structural integrity. Topics discussed include: mechanical properties of high performance carbon fibers; fatigue in composite materials; experimental and theoretical studies of moisture and temperature effects on the mechanical properties of graphite-epoxy laminates and neat resins; numerical investigations of the micromechanics of composite fracture; delamination failures of composite laminates; effect of notch size on composite laminates; improved beam theory for anisotropic materials; variation of resin properties through the thickness of cured samples; numerical analysis composite processing; heat treatment of metal matrix composites, and the RP-1 and RP2 gliders of the sailplane project.

3-D printing of liquid metals for stretchable and flexible conductors

NASA Astrophysics Data System (ADS)

Trlica, Chris; Parekh, Dishit Paresh; Panich, Lazar; Ladd, Collin; Dickey, Michael D.

2014-06-01

3-D printing is an emerging technology that has been used primarily on small scales for rapid prototyping, but which could also herald a wider movement towards decentralized, highly customizable manufacturing. Polymers are the most common materials to be 3-D printed today, but there is great demand for a way to easily print metals. Existing techniques for 3-D printing metals tend to be expensive and energy-intensive, and usually require high temperatures or pressures, making them incompatible with polymers, organics, soft materials, and biological materials. Here, we describe room temperature liquid metals as complements to polymers for 3-D printing applications. These metals enable the fabrication of soft, flexible, and stretchable devices. We survey potential room temperature liquid metal candidates and describe the benefits of gallium and its alloys for these purposes. We demonstrate the direct printing of a liquid gallium alloy in both 2-D and 3-D and highlight the structures and shapes that can be fabricated using these processes.

Effects of Cryogenic Treatment on the Strength Properties of Heat Resistant Stainless Steel (07X16H6)

NASA Astrophysics Data System (ADS)

Nadig, D. S.; Bhat, M. R.; Pavan, V. K.; Mahishi, Chandan

2017-09-01

Cryogenic treatment on metals is a well known technology where the materials are exposed to cryogenic temperature for prolonged time duration. The process involves three stages viz. slow cooling, holding at cryogenic temperature and warming to room temperature. During this process, hard and micro sized carbide particles are released within the steel material. In addition, soft and unconverted austenite of steel changes to strong martensite structure. These combined effects increase the strength and hardness of the cryotreated steel. In this experimental study, the effects of cryogenic treatment, austenitising and tempering on the mechanical properties of stainless steel (07X16H6) have been carried. After determining the strength properties of the original material, the specimens were cryotreated at 98K for 24 hours in a specially developed cryotreatment system. The effects of austenitising prior to cryogenic treatment and tempering post cryotreatment on the mechanical properties of steel samples have been experimentally determined and analysed.

Low thrust chemical rocket technology

NASA Technical Reports Server (NTRS)

Schneider, Steven J.

1992-01-01

An on-going technology program to improve the performance of low thrust chemical rockets for spacecraft on-board propulsion applications is reviewed. Improved performance and lifetime is sought by the development of new predictive tools to understand the combustion and flow physics, introduction of high temperature materials and improved component designs to optimize performance, and use of higher performance propellants. Improved predictive technology is sought through the comparison of both local and global predictions with experimental data. Predictions are based on both the RPLUS Navier-Stokes code with finite rate kinetics and the JANNAF methodology. Data were obtained with laser-based diagnostics along with global performance measurements. Results indicate that the modeling of the injector and the combustion process needs improvement in these codes and flow visualization with a technique such as 2-D laser induced fluorescence (LIF) would aid in resolving issues of flow symmetry and shear layer combustion processes. High temperature material fabrication processes are under development and small rockets are being designed, fabricated, and tested using these new materials. Rhenium coated with iridium for oxidation protection was produced by the Chemical Vapor Deposition (CVD) process and enabled an 800 K increase in rocket operating temperature. Performance gains with this material in rockets using Earth storable propellants (nitrogen tetroxide and monomethylhydrazine or hydrazine) were obtained through component redesign to eliminate fuel film cooling and its associated combustion inefficiency while managing head end thermal soakback. Material interdiffusion and oxidation characteristics indicated that the requisite lifetimes of tens of hours were available for thruster applications. Rockets were designed, fabricated, and tested with thrusts of 22, 62, 440 and 550 N. Performance improvements of 10 to 20 seconds specific impulse were demonstrated. Higher performance propellants were evaluated: Space storable propellants, including liquid oxygen (LOX) as the oxidizer with nitrogen hydrides or hydrocarbon as fuels. Specifically, a LOX/hydrazine engine was designed, fabricated, and shown to have a 95 pct theoretical c-star which translates into a projected vacuum specific impulse of 345 seconds at an area ratio of 204:1. Further performance improvment can be obtained by the use of LOX/hydrogen propellants, especially for manned spacecraft applications, and specific designs must be developed and advanced through flight qualification.

AGC 2 Irradiated Material Properties Analysis

DOE Office of Scientific and Technical Information (OSTI.GOV)

Rohrbaugh, David Thomas

2017-05-01

The Advanced Reactor Technologies Graphite Research and Development Program is conducting an extensive graphite irradiation experiment to provide data for licensing of a high temperature reactor (HTR) design. In past applications, graphite has been used effectively as a structural and moderator material in both research and commercial high temperature gas cooled reactor designs. , Nuclear graphite H 451, used previously in the United States for nuclear reactor graphite components, is no longer available. New nuclear graphite grades have been developed and are considered suitable candidates for new HTR reactor designs. To support the design and licensing of HTR core componentsmore » within a commercial reactor, a complete properties database must be developed for these current grades of graphite. Quantitative data on in service material performance are required for the physical, mechanical, and thermal properties of each graphite grade, with a specific emphasis on data accounting for the life limiting effects of irradiation creep on key physical properties of the HTR candidate graphite grades. Further details on the research and development activities and associated rationale required to qualify nuclear grade graphite for use within the HTR are documented in the graphite technology research and development plan.« less

Photophysical Properties of Novel Organic, Inorganic, and Hybrid Semiconductor Materials

NASA Astrophysics Data System (ADS)

Chang, Angela Yenchi

For the past 200 years, novel materials have driven technological progress, and going forward these advanced materials will continue to deeply impact virtually all major industrial sectors. Therefore, it is vital to perform basic and applied research on novel materials in order to develop new technologies for the future. This dissertation describes the results of photophysical studies on three novel materials with electronic and optoelectronic applications, namely organic small molecules DTDCTB with C60 and C70, colloidal indium antimonide (InSb) nanocrystals, and an organic-inorganic hybrid perovskite with the composition CH3NH3PbI 3-xClx, using transient absorption (TA) and photoluminescence (PL) spectroscopy. In chapter 2, we characterize the timescale and efficiency of charge separation and recombination in thin film blends comprising DTDCTB, a narrow-band gap electron donor, and either C60 or C70 as an electron acceptor. TA and time-resolved PL studies show correlated, sub-picosecond charge separation times and multiple timescales of charge recombination. Our results indicate that some donors fail to charge separate in donor-acceptor mixed films, which suggests material manipulations may improve device efficiency. Chapter 3 describes electron-hole pair dynamics in strongly quantum-confined, colloidal InSb nanocrystal quantum dots. For all samples, TA shows a bleach feature that, for several picoseconds, dramatically red-shifts prior to reaching a time-independent position. We suggest this unusual red-shift relates transient population flow through two energetically comparable conduction band states. From pump-power-dependent measurements, we also determine biexciton lifetimes. In chapter 4, we examine carrier dynamics in polycrystalline methylammonium lead mixed halide perovskite (CH3NH3PbI3-xCl x) thin films as functions of temperature and photoexcitation wavelength. At room temperature, the long-lived TA signals stand in contrast to PL dynamics, where the latter present a fast decay process prior to slower recombination. We show that this PL feature persists with similar decay amplitude and timescale for temperatures down to the phase transition temperature, and that it depends on pump photon energy at room temperature. Together with high-level electronic structure and dynamics calculations, we suggest the fast PL decay relates a characteristic organic-to-inorganic sub-lattice equilibration timescale at optoelectronic-relevant excitation energies.

Processing, Structure and High Temperature Oxidation Properties of Polymer-Derived and Hafnium Oxide Based Ceramic Systems

NASA Astrophysics Data System (ADS)

Terauds, Kalvis

Demands for hypersonic aircraft are driving the development of ultra-high temperature structural materials. These aircraft, envisioned to sustain Mach 5+, are expected to experience continuous temperatures of 1200--1800°C on the aircraft surface and temperatures as high as 2800°C in combustion zones. Breakthroughs in the development of fiber based ceramic matrix composites (CMCs) are opening the door to a new class of high-tech UHT structures for aerospace applications. One limitation with current carbon fiber or silicon carbide fiber based CMC technology is the inherent problem of material oxidation, requiring new approaches for protective environmental barrier coatings (EBC) in extreme environments. This thesis focuses on the development and characterization of SiCN-HfO2 based ceramic composite EBC systems to be used as a protective layer for silicon carbide fiber based CMCs. The presented work covers three main architectures for protection (i) multilayer films, (ii) polymer-derived HfSiCNO, and (iii) composite SiCN-HfO 2 infiltration. The scope of this thesis covers processing development, material characterization, and high temperature oxidation behavior of these three SiCN-HfO2 based systems. This work shows that the SiCN-HfO 2 composite materials react upon oxidation to form HfSiO4, offering a stable EBC in streaming air and water vapor at 1600°C.

SQUIDs: microscopes and nondestructive evaluation

NASA Astrophysics Data System (ADS)

Mück, Michael

2005-03-01

SQUIDs (Superconducting Quantum Interference Devices) are magnetic field sensores with unsurpassed sensitivity. They are amazingly versatile, being able to measure all physical quantities which can be converted to magnetic flux. They are routinely fabricated in thin film technology from two classes of superconducting materials: high-temperature superconductors (HTS) which are usually cooled to 77 K, and low-temperature superconductors (LTS), which have to be cooled to 4.2 K. SQUIDs have many applications, two of which shall be discussed in this paper. In SQUID microscopy, a SQUID scans a sample, which preferrably is at room temperature, and measures the two-dimensional magnetic field distribution at the surface of the sample. In order to achieve a relatively high spatial resolution, the stand-off distance between the sample and the SQUID is made as small as possible. SQUIDs show also promising results in the field of nondestructive testing of various materials. For example, ferromagnetic impurities in stainless steel formed by aging processes in the material can be detected with high probability, and cracks in conducting materials, for example aircraft parts, can be located using eddy current methods. Especially for the case of thick, highly conductive, or ferromagnetic materials, as well as sintered materials, it can be shown that a SQUID-based NDE system exhibits a much higher sensitivity compared to conventional eddy current NDE and ultrasonic testing.