Size and performance of anoxic limestone drains to neutralize acdic mine drainagei

USGS Publications Warehouse

Cravotta, C.A.

2003-01-01

Acidic mine drainage (AMD) can be neutralized effectively in underground, anoxic limestone drains (ALDs). Owing to reaction between the AMD and limestone (CaCO3), the pH and concentrations of alkalinity and calcium increase asymptotically with detention time in the ALD, while concentrations of sulfate, ferrous iron, and manganese typically are unaffected. This paper introduces a method to predict the alkalinity produced within an ALD and to estimate the mass of limestone required for its construction on the basis of data from short-term, closed-container (cubitainer) tests. The cubitainer tests, which used an initial mass of 4 kg crushed limestone completely inundated with 2.8 L AMD, were conducted for 11 to 16 d and provided estimates for the initial and maximum alkalinities and corresponding rates of alkalinity production and limestone dissolution. Long-term (5-11 yr) data for alkalinity and CaCO3 flux at the Howe Bridge, Morrison, and Buck Mountain ALDs in Pennsylvania, USA, indicate that rates of alkalinity production and limestone dissolution under field conditions were comparable with those in cubitainers filled with limestone and AMD from each site. The alkalinity of effluent and intermediate samples along the flow path through the ALDs and long-term trends in the residual mass of limestone and the effluent alkalinity were estimated as a function of the computed detention time within the ALD and second-order dissolution rate models for cubitainer tests. Thus, cubitainer tests can be a useful tool for designing ALDs and predicting their performance.

Characterization of the spatial distribution of porosity in the eogenetic karst Miami Limestone using ground penetrating radar

NASA Astrophysics Data System (ADS)

Mount, G. J.; Comas, X.; Wright, W. J.; McClellan, M. D.

2014-12-01

Hydrogeologic characterization of karst limestone aquifers is difficult due to the variability in the spatial distribution of porosity and dissolution features. Typical methods for aquifer investigation, such as drilling and pump testing, are limited by the scale or spatial extent of the measurement. Hydrogeophysical techniques such as ground penetrating radar (GPR) can provide indirect measurements of aquifer properties and be expanded spatially beyond typical point measures. This investigation used a multiscale approach to identify and quantify porosity distribution in the Miami Limestone, the lithostratigraphic unit that composes the uppermost portions of the Biscayne Aquifer in Miami Dade County, Florida. At the meter scale, laboratory measures of porosity and dielectric permittivity were made on blocks of Miami Limestone using zero offset GPR, laboratory and digital image techniques. Results show good correspondence between GPR and analytical porosity estimates and show variability between 22 and 66 %. GPR measurements at the field scale 10-1000 m investigated the bulk porosity of the limestone based on the assumption that a directly measured water table would remain at a consistent depth in the GPR reflection record. Porosity variability determined from the changes in the depth to water table resulted in porosity values that ranged from 33 to 61 %, with the greatest porosity variability being attributed to the presence of dissolution features. At the larger field scales, 100 - 1000 m, fitting of hyperbolic diffractions in GPR common offsets determined the vertical and horizontal variability of porosity in the saturated subsurface. Results indicate that porosity can vary between 23 and 41 %, and delineate potential areas of enhanced recharge or groundwater / surface water interactions. This study shows porosity variability in the Miami Limestone can range from 22 to 66 % within 1.5 m distances, with areas of high macroporosity or karst dissolution features occupying the higher end of the range. Spatial variability in porosity distribution may affect ground water recharge, allowing zones of high porosity and thus enhanced infiltration to concentrate contaminants into the aquifer and may play a role in small and regional scale aquifer models.

Diagenesis and porosity preservation in Eocene microporous limestones, South Florida, USA

NASA Astrophysics Data System (ADS)

Maliva, Robert G.; Missimer, Thomas M.; Clayton, Edward A.; Dickson, J. A. D.

2009-05-01

Microporous limestones may contain immobile, capillary-bound (irreducible) water that is only in diffusional contact with mobile pore waters or in some reservoirs may contain producible hydrocarbons. The preservation and distribution of microporosity impact both subsurface fluid flow and solute transport. The diagenesis of microporous limestones has received relatively little attention because their very fine grains and cements are not amenable to standard analytical methods. The Ocala Limestone (Upper Eocene) and upper Avon Park Formation (Middle Eocene) in South Florida contain microporous micritic limestones (mudstones to packstones) that are at an intermediate stage of diagenesis. The limestones have been exposed to the active near-surface environment, but have not yet reached a burial depth sufficient for intense chemical compaction and associated porosity reduction. Nuclear magnetic resonance (NMR) logging allowed for the quantification of total porosity, pore-size distribution, and permeability. The Ocala Limestone and Avon Park Formation have different predominant microfacies and porosity size distributions, but yet both retain total porosities predominantly between 35% and 37%. Estimated microporosities range mostly between 12% and 45%. The mudstones and wackestones of the Ocala Limestone have significantly lower permeabilities (mostly 3 to 12 md) than the wackestones to grainstones of the Avon Park Formation (commonly in the 100 to 3000 md range), which have more mixed and overall coarser pore sizes. Computer modeling using carbon and oxygen stable data indicates that the studied microporous limestones underwent only a low degree of chemical diagenetic alteration, despite likely experiencing episodes of freshwater flushing associated with post-depositional sea-level lowstands. The Ocala Limestone and Avon Park Formation limestones illustrate the general concept that total porosity is often largely preserved through early diagenesis (although may undergo intra-formational redistribution) and that confined aquifers are diagenetic quiescent environments.

Field trial of a pulsed limestone diversion well

USGS Publications Warehouse

Sibrell, Philip L.; Denholm, C.; Dunn, Margaret

2013-01-01

The use of limestone diversion wells to treat acid mine drainage (AMD) is well-known, but in many cases, acid neutralization is not as complete as would be desired. Reasons for this include channeling of the water through the limestone bed, and the slow reaction rate of the limestone gravel. A new approach to improve the performance of the diversion well was tested in the field at the Jennings Environmental Education Center, near Slippery Rock, PA. In this approach, a finer size distribution of limestone was used so as to allow fluidization of the limestone bed, thus eliminating channeling and increasing particle surface area for faster reaction rates. Also, water flow was regulated through the use of a dosing siphon, so that consistent fluidization of the limestone sand could be achieved. Testing began late in the summer of 2010, and continued through November of 2011. Initial system performance during the 2010 field season was good, with the production of net alkaline water, but hydraulic problems involving air release and limestone sand retention were observed. In the summer of 2011, a finer size of limestone sand was procured for use in the system. This material fluidized more readily, but acid neutralization tapered off after several days. Subsequent observations indicated that the hydraulics of the system was compromised by the formation of iron oxides in the pipe leading to the limestone bed, which affected water distribution and flow through the bed. Although results from the field trial were mixed, it is believed that without the formation of iron oxides and plugging of the pipe, better acid neutralization and treatment would have occurred. Further tests are being considered using a different hydraulic configuration for the limestone sand fluidized bed.

Geology of an area near Brentwood, Williamson County, Tennessee

USGS Publications Warehouse

Hanchar, D.W.

1988-01-01

The geology and structure of an area near Brentwood, Williamson County, Tennessee, were studied to define the potential aquifers and confining units that comprise the groundwater flow system of the area. Four different formations were identified. These formations are, in descending order, the Bigby-Cannon Limestone, the Hermitage Formation, the Carters Limestone, and the Lebanon Limestone. The Bigby-Cannon Limestone and the Hermitage Formation have been affected by recent erosion. Any variation of the Carters Limestone is controlled by pre-Carters erosion of the top of the Lebanon Limestone. The thickness of this formation ranges from 65 to 79 ft. A small scale anticline-syncline pair is evident. This structure is not a result of erosion and also occurs in the T-3 bentonite bed in the Carters Limestone. (USGS)

Diversity and biogeography of land snails (Mollusca, Gastropoda) in the limestone hills of Perak, Peninsular Malaysia

PubMed Central

Foon, Junn Kitt; Clements, Gopalasamy Reuben; Liew, Thor-Seng

2017-01-01

Abstract Limestone hills are now gaining global conservation attention as hotspots for short-range endemic species. Levels of land snail endemism can be high at limestone hills, especially at hill clusters that are geographically isolated. In the State of Perak, Peninsular Malaysia, limestone hills have been opportunistically surveyed for land snails in the past, but the majority have yet to be surveyed. To address this knowledge gap, we systematically surveyed the terrestrial malacofauna of 12 limestone hills that, based on our opinion, are a representation of the limestone land snail assemblages within the State. Our inventory yielded high sampling completeness (>85%). We found 122 species of land snails, of which 34 species were unique to one of the surveyed hills. We identified 30 species that are potentially new to science. The number of land snail species recorded at each hill ranged between 39 and 63 species. Four of the sampled limestone hills namely, Prk 01 G. Tempurung, Prk 55 G. Pondok, Prk 47 Kanthan, and Prk 64 Bt Kepala Gajah, have high levels of species richness and unique species, representing 91% of the total species recorded in this study. We identified two clusters of limestone hills in central Perak with distinct differences in land snail species composition – a northern hill cluster on elevated granite bedrock and southern hill cluster in a low-lying valley surrounded by alluvial soils. As limestone hills continue to be quarried to meet the cement demand, the four identified limestone hills, along with other hills from the two clusters, warrant urgent conservation attention in order to maintain high species diversity within Perak’s terrestrial malacofauna. PMID:28769723

Pathogen and chemical transport in the karst limestone of the Biscayne aquifer: 3. Use of microspheres to estimate the transport potential of Cryptosporidium parvum oocysts

USGS Publications Warehouse

Harvey, Ronald W.; Metge, David W.; Shapiro, Allen M.; Renken, Robert A.; Osborn, Christina L.; Ryan, Joseph N.; Cunningham, Kevin J.; Landkamer, Lee L.

2008-01-01

The vulnerability of a municipal well in the Northwest well field in southeastern Florida to potential contamination by Cryptosporidium parvum oocysts was assessed in a large‐scale, forced‐gradient (convergent) injection and recovery test. The field study involved a simultaneous pulse introduction of a nonreactive tracer (SF6, an inert gas) and oocyst‐sized (1.6, 2.9, and 4.9 μm diameter) carboxylated polystyrene microspheres into karst limestone of the Biscayne aquifer characterized by a complex triple (matrix, touching‐vug, and conduit) porosity. Fractional recoveries 97 m down gradient were inversely related to diameter and ranged from 2.9% for the 4.9 μm microspheres to 5.8% for 1.6 μm microspheres. Their centers of mass arrived at the pumping well approximately threefold earlier than that of the nonreactive tracer SF6 (gas), underscoring the need for use of colloid tracers and field‐scale tracer tests for these kinds of evaluations. In a modified triaxial cell using near in situ chemical conditions, 2.9 and 4.9 μm microspheres underestimated by fourfold to sixfold the attachment potential of the less electronegative 2.9–4.1 μm oocysts in the matrix porosity of limestone core samples. The field and laboratory results collectively suggested that it may take 200–300 m of transport to ensure even a 1‐log unit removal of oocysts, even though the limestone surfaces exhibited a substantive capability for their sorptive removal. The study further demonstrated the utility of microspheres as oocyst surrogates in field‐scale assessments of well vulnerability in limestone, provided that differences in attachment behaviors between oocysts and microspheres are taken into account.

DOE Office of Scientific and Technical Information (OSTI.GOV)

Bizzozero, Julien, E-mail: julien.bizzozero@gmail.com; Scrivener, Karen L.

This paper reports a study of ternary blends composed of calcium aluminate cement, calcium sulfate hemihydrate and limestone. Compressive strength tests and hydration kinetics were studied as a function of limestone and calcium sulfate content. The phase evolution and the total porosity were followed and compared to thermodynamic simulation to understand the reactions involved and the effect of limestone on these binders. The reaction of limestone leads to the formation of hemicarboaluminate and monocarboaluminate. Increasing the ratio between sulfate and aluminate decreases the extent of limestone reaction.

Toxicity of acid mine pit lake water remediated with limestone and phosphorus.

PubMed

Neil, Luke L; McCullough, Clint D; Lund, Mark A; Evans, Louis H; Tsvetnenko, Yuri

2009-11-01

Pit lakes are increasingly common worldwide and have potential to provide many benefits. However, lake water toxicity may require remediation before beneficial end uses can be realised. Three treatments to remediate AMD (pH approximately 4.8) pit lake water containing elevated concentrations of Al and Zn from Collie, Western Australia were tested in mesocosms. Treatments were: (a) limestone neutralisation (L), (b) phosphorus amendment (P), and (c) combined limestone neutralisation and phosphorus amendment (L+P). Laboratory bioassays with Ceriodaphnia cf. dubia, Chlorella protothecoides and Tetrahymena thermophila assessed remediation. Limestone neutralisation increased pH and reduced heavy metal concentrations by 98% (Al) to 14% (Mg), removing toxicity to the three test species within 2 months. Phosphorus amendment removed toxicity after 6 months of treatment. However, phosphorus amendment to prior limestone neutralisation failed to reduce toxicity more than limestone neutralisation alone. Low concentrations of both phosphorus and nitrogen appear to limit phytoplankton population growth in all treatments.

Mineralogical characterization of the Shelburne marble and the Salem limestone

DOE Office of Scientific and Technical Information (OSTI.GOV)

McGee, E.S.

Samples of Shelburne marble and Salem limestone were selected to represent marbles and limestones used in buildings and monuments. The Royal variety of Shelburne marble is a white marble predominantly composed of calcite but has heterogeneously distributed gray inclusions. The select buff Salem limestone is a beige, homogeneous, fossiliferous limestone, predominantly composed of fragments of echinoderms and bryozoans. The author reports that both samples are appropriate test stones for the National Acid Precipitation Assessment Program stone exposure studies.

Configuration of the top of the Floridan aquifer, Southwest Florida Water Management District and adjacent areas

USGS Publications Warehouse

Buono, A.; Rutledge, A.T.

1978-01-01

This map depicts the approximate top of the rock that composes the Floridan aquifer. The contours represent the elevation of the top of the Floridan aquifer to mean sea level. Rock units recognized to be part of the Floridan aquifer are limestone and dolomite ranging from middle Eocene to early Miocene. They are Lake City Limestone, Avon Park Limestone, Ocala Limestone, Suwannee Limestone, and Tampa Limestone. In this report, the top of the Floridan aquifer is a limestone defined as the first consistent rock of early Miocene age or older below which occur no clay confining beds. Although the Hawthorn formation of middle Miocene is considered part of the Floridan aquifer when it is in direct hydrologic contact with lower lying rock units, it is not considered here because of a lack of detailed delineation of areas where contact exists. (Woodard-USGS)

Toxicity of acid mine pit lake water remediated with limestone and phosphorus

DOE Office of Scientific and Technical Information (OSTI.GOV)

Neil, L.L.; McCullough, C.D.; Lund, M.A.

2009-11-15

Pit lakes are increasingly common worldwide and have potential to provide many benefits. However, lake water toxicity may require remediation before beneficial end uses can be realised. Three treatments to remediate AMD (pH similar to 4.8) pit lake water containing elevated concentrations of Al and Zn from Collie, Western Australia were tested in mesocosms. Treatments were: (a) limestone neutralisation (L), (b) phosphorus amendment (P), and c) combined limestone neutralisation and phosphorus amendment (L+P). Laboratory bioassays with Ceriodaphnia cf. dubia, Chlorella protothecoides and Tetrahymena thermophila assessed remediation. Limestone neutralisation increased pH and reduced heavy metal concentrations by 98% (Al) to 14%more » (Mg), removing toxicity to the three test species within 2 months. Phosphorus amendment removed toxicity after 6 months of treatment. However, phosphorus amendment to prior limestone neutralisation failed to reduce toxicity more than limestone neutralisation alone. Low concentrations of both phosphorus and nitrogen appear to limit phytoplankton population growth in all treatments.« less

Permeability hysterisis of limestone during isotropic compression.

PubMed

Selvadurai, A P S; Głowacki, A

2008-01-01

The evolution of permeability hysterisis in Indiana Limestone during application of isotropic confining pressures up to 60 MPa was measured by conducting one-dimensional constant flow rate tests. These tests were carried out either during monotonic application of the confining pressure or during loading-partial unloading cycles. Irreversible permeability changes occurred during both monotonic and repeated incremental compression of the limestone. Mathematical relationships are developed for describing the evolution of path-dependent permeability during isotropic compression.

Biocalcifying Bacillus subtilis cells effectively consolidate deteriorated Globigerina limestone.

PubMed

Micallef, Roderick; Vella, Daniel; Sinagra, Emmanuel; Zammit, Gabrielle

2016-07-01

Microbially induced calcite precipitation occurs naturally on ancient limestone surfaces in Maltese hypogea. We exploited this phenomenon and treated deteriorated limestone with biocalcifying bacteria. The limestone was subjected to various mechanical and physical tests to present a statistically robust data set to prove that treatment was indeed effective. Bacillus subtilis conferred uniform bioconsolidation to a depth of 30 mm. Drilling resistance values were similar to those obtained for freshly quarried limestone (9 N) and increased up to 15 N. Treatment resulted in a high resistance to salt deterioration and a slow rate of water absorption. The overall percentage porosity of treated limestone varied by ±6 %, thus the pore network was preserved. We report an eco-friendly treatment that closely resembles the mineral composition of limestone and that penetrates into the porous structure without affecting the limestones' natural properties. The treatment is of industrial relevance since it compares well with stone consolidants available commercially.

Exploration for limestone deposit at Onigbedu, South-Western Nigeria

NASA Astrophysics Data System (ADS)

Oyedele, Kayode F.; Oladele, Sunday; Emakpor, Charles A.

2016-09-01

The Onigbedu limestone deposit was investigated using the aeromagnetic data, resistivity soundings and borings with the aim of characterizing the limestone deposit and estimating its reserves. The subsurface structural features and depth to basement were identified with the analysis of aeromagnetic data. Twenty nine boreholes were drilled for subsurface appraisal and correlation of the limestone deposit. Eighty nine Vertical Electrical Sounding (VES) were acquired using the Schlumberger array. The results showed NE-SW trending lineaments that segmented the limestone. Depth to basement varied from 144.2 m to 1090 m. The VES results showed four to six layers indicating the topsoil (7-315 Ωm), clay (2-25 Ωm), shale (6-31 Ωm), limestone (20-223 Ωm), sandstone (>200 Ωm) and sandy materials. The VES results correlated well with the lithological unit delineated from the borehole. The overburden thickness ranged from 3.3 m to 28 m, while the limestone thickness varies between 18.1 m and 48.3 m. The limestone reserve was estimated at 1.9 × 109 t. This study concluded that the study area had vast occurrence of the limestone deposits, which would be of economic importance, if exploited.

Subsurface stratigraphy and oil fields in the Salem Limestone and associated rocks in Indiana

DOE Office of Scientific and Technical Information (OSTI.GOV)

Keller, S.J.; Becker, L.E.

An area of 11 counties in southwestern Indiana was studied because (1) the subsurface geology of the Salem Limestone and associated rocks in the area contained numerous correlation discrepancies; (2) it was the locus of recent oil exploration and oil discoveries in these rocks; (3) the last subsurface study of this rock section was made in 1957; and (4) since that time, subsurface data from newly drilled petroleum-test wells have increased a hundredfold. Because of their abundance, geophysical logs were used extensively for correlation. Drill cuttings, where available, were also used in studying the rock units. The upper boundary ofmore » the Salem was based on geophysical-log correlations as supported by available drill cuttings. The lower boundary of the Salem was based on drill cuttings. Commercial oil is produced from porous calcarenite zones in the St. Louis and Salem Limestones and from coarsely crystalline limestone in the Harrodsburg Limestone. The lower part of the St. Louis Limestone yields oil from a porous carbonate rock that resembles Salem calcarenite and that we have formally named the Sission Member in the St. Louis. The Salem calcarenite facies ranges in thickness from a low of 10 percent of the total Salem in the southern part of the study area to a high of 80 percent in the northern part. Oil is produced from porous zones in the calcarenite. Oil production from the St. Louis, Salem, and Harrodsburg Limestones in Indiana amounted to 8,880,078 barrels as of December 31, 1978. Production in 1977 was 1,534,320 barrels, and production in 1978 was 1,157,450 barrels. About 80 percent of the 1977 and 1978 production came from Union-Bowman Consolidated and Sisson Fields in Gibson, Knox, and Pike counties and the Owensville North Consolidated and Mt. Carmel Consolidated Fields in Gibson County. 15 figures, 3 tables.« less

Hydrologic and Geochemical Evaluation of Aquifer Storage Recovery in the Santee Limestone/Black Mingo Aquifer, Charleston, South Carolina, 1998-2002

USGS Publications Warehouse

Petkewich, Matthew D.; Parkhurst, David L.; Conlon, Kevin J.; Campbell, Bruce G.; Mirecki, June E.

2004-01-01

The hydrologic and geochemical effects of aquifer storage recovery were evaluated to determine the potential for supplying the city of Charleston, South Carolina, with large quantities of potable water during emergencies, such as earthquakes, hurricanes, or hard freezes. An aquifer storage recovery system, including a production well and three observation wells, was installed at a site located on the Charleston peninsula. The focus of this study was the 23.2-meter thick Tertiary-age carbonate and sand aquifer of the Santee Limestone and the Black Mingo Group, the northernmost equivalent of the Floridan aquifer system. Four cycles of injection, storage, and recovery were conducted between October 1999 and February 2002. Each cycle consisted of injecting between 6.90 and 7.19 million liters of water for storage periods of 1, 3, or 6 months. The volume of recovered water that did not exceed the U.S. Environmental Protection Agency secondary standard for chloride (250 milligrams per liter) varied from 1.48 to 2.46 million liters, which is equivalent to 21 and 34 percent of the total volume injected for the individual tests. Aquifer storage recovery testing occurred within two productive zones of the brackish Santee Limestone/Black Mingo aquifer. The individual productive zones were determined to be approximately 2 to 4 meters thick, based on borehole geophysical logs, electromagnetic flow-meter testing, and specific-conductance profiles collected within the observation wells. A transmissivity and storage coefficient of 37 meters squared per day and 3 x 10-5, respectively, were determined for the Santee Limestone/Black Mingo aquifer. Water-quality and sediment samples collected during this investigation documented baseline aquifer and injected water quality, aquifer matrix composition, and changes in injected/aquifer water quality during injection, storage, and recovery. A total of 193 water-quality samples were collected and analyzed for physical properties, major and minor ions, and nutrients. The aquifer and treated surface water were sodiumchloride and calcium/sodium-bicarbonate water types, respectively. Forty-five samples were collected and analyzed for total trihalomethane. Total trihalomethane data collected during aquifer storage recovery cycle 4 indicated that this constituent would not restrict the use of recovered water for drinking-water purposes. Analysis of six sediment samples collected from a cored well located near the aquifer storage recovery site showed that quartz and calcite were the dominant minerals in the Santee Limestone/Black Mingo aquifer. Estimated cation exchange capacity ranged from 12 to 36 milliequivalents per 100 grams in the lower section of the aquifer. A reactive transport model was developed that included two 2-meter thick layers to describe each of the production zones. The four layers composing the production zones were assigned porosities ranging from 0.1 to 0.3 and hydraulic conductivities ranging from 1 to 8.4 meters per day. Specific storage of the aquifer and confining units was estimated to be 1.5 x 10-5 meter-1. Longitudinal dispersivity of all layers was specified to be 0.5 meter. Leakage through the confining unit was estimated to be minimal and, therefore, not used in the reactive transport modeling. Inverse geochemical modeling indicates that mixing, cation exchange, and calcite dissolution are the dominant reactions that occur during aquifer storage recovery testing in the Santee Limestone/Black Mingo aquifer. Potable water injected into the Santee Limestone/Black Mingo aquifer evolved chemically by mixing with brackish background water and reaction with calcite and cation exchangers in the sediment. Reactive-transport model simulations indicated that the calcite and exchange reactions could be treated as equilibrium processes. Simulations with the calibrated reactive transport model indicated that approximately one-fourth of the total volume of water injected into

Geochemical Models of Water-Quality Changes During Aquifer Storage Recovery (ASR) Cycle Tests, Phase 1: Geochemical Models Using Existing Data

DTIC Science & Technology

2006-09-01

Richardson, in review). Figure 1 shows the lithostratigraphic setting for Eocene through Miocene strata, and the occurrence of hydrostratigraphic units of...basal Haw- thorn unit lies unconformably on lithologies informally called “ Eocene limestones,” which consist of Suwannee Limestone, Ocala Limestone

Hydrogen sulfide capture by limestone and dolomite at elevated pressure. 2: Sorbent particle conversion modeling

DOE Office of Scientific and Technical Information (OSTI.GOV)

Zevenhoven, C.A.P.; Yrjas, K.P.; Hupa, M.M.

1996-03-01

The physical structure of a limestone or dolomite to be used in in-bed sulfur capture in fluidized bed gasifiers has a great impact on the efficiency of sulfur capture and sorbent use. In this study an unreacted shrinking core model with variable effective diffusivity is applied to sulfidation test data from a pressurized thermogravimetric apparatus (P-TGA) for a set of physically and chemically different limestone and dolomite samples. The particle size was 250--300 {micro}m for all sorbents, which were characterized by chemical composition analysis, particle density measurement, mercury porosimetry, and BET internal surface measurement. Tests were done under typical conditionsmore » for a pressurized fluidized-bed gasifier, i.e., 20% CO{sub 2}, 950 C, 20 bar. At these conditions the limestone remains uncalcined, while the dolomite is half-calcined. Additional tests were done at low CO{sub 2} partial pressures, yielding calcined limestone and fully calcined dolomite. The generalized model allows for determination of values for the initial reaction rate and product layer diffusivity.« less

Comparison of deformation mechanics for two different carbonates: oolitic limestone and laminites

NASA Astrophysics Data System (ADS)

Zihms, Stephanie; Lewis, Helen; Couples, Gary; Hall, Stephen; Somerville, Jim

2016-04-01

Carbonate rocks form under a range of conditions which leads to a diverse rock group. Even though carbonates are overall mineralogically simple, the solid-space distribution ranges from simple compositions such as oolitic limestones to highly complex networks of pores and solids as seen in coquinas. Their fundamental mechanical behaviour has been identified to be like clastic rocks (Vajdova 2004, Brantut, Heap et al. 2014). However it is very likely that this observation is not true for more complex carbonates. Triaxial tests were performed on cylindrical samples of two different carbonates; a) oolitic limestone (Bicqueley quarry, France) and b) laminite (Ariripe basin, Brazil). The samples were deformed under confining pressures of 8, 12 and 20MPa, and 20, 30 and 40MPa, respectively. All tests were stopped as soon as peak load was observed to preserve as many deformation characteristics as possible. Photographs of the samples were taken before and after deformation to allow surface analysis of deformation features. Additionally, samples were analysed post-deformation with X-ray tomography (XRT) (using the Zeiss XRadia XRM 520 at the 4D Imaging Lab at Lund University). The 3D tomography images represent the post-deformation samples' density distribution, allowing detailed, non-destructive, 3D analysis of the deformation features that developed in the triaxial testing, including the complex geometries and interactions of fractures, deformation bands and sedimentary layering. They also provide an insight into the complexity of deformation features produced due to the carbonate response. Initial results show that the oolitic limestone forms single shear bands almost the length of the sample, exhibiting similar characteristics to sandstones deformed under similar conditions. These features are observed for all three applied loads. The laminate sample deformed at the lowest confining pressure exhibits compactive features. However, the laminite samples deformed at the two higher confining pressures both show highly complex fracture networks comprising open fractures and fracture propagation. This suggests that the laminate changes from compactive to dilational responses over the selected confining conditions. The XRT analysis indicates that a more complex fracture distribution could be linked to rock component properties e.g. grain size and composition. For the laminite these are variable with the layers. This is in agreement with field observations of laminite microfabrics (Calvo, Rodriguez-Pascua et al. 1998). Additionally, the typical grain size of the laminate (μm) is much smaller than the oolitic limestone (mm), which suggests that fracture network complexity can also be linked to bulk system complexity i.e. pore & grain network. These deformation experiments show that, as previously observed, oolitic limestones seem to behave similarly to sandstones. However this observation is not true for laminites and it is very likely that more complex carbonates will develop even more complicated deformation behaviour. It is therefore necessary to systematically test different carbonate rocks to understand the impact of geometry and composition, as well as the interplay with the pore network. Brantut, N., et al. (2014). Journal of Geophysical Research: Solid Earth 119(7): 5444-5463. Calvo, J. P., et al. (1998). Sedimentology 45: 279-292. Vajdova, V. (2004). Journal of Geophysical Research 109(B5).

Experimental method for estimation of compaction in the Oxfordian bedded limestones of the southern Kraków-Częstochowa Upland, Southern Poland

NASA Astrophysics Data System (ADS)

Kochman, Alicja; Matyszkiewicz, Jacek

2013-12-01

Kochman, A. and Matyszkiewicz, J. 2013. Experimental method for estimation of compaction in the Oxfordian bedded limestones of the southern Krakow-Częstochowa Upland, Southern Poland. Acta Geologica Polonica, 63(4), 681-696. Warszawa. The Upper Jurassic carbonates exposed in the southern part of the Krakow-Częstochowa Upland are well known for their significant facies diversity related to the presence of microbial and microbial-sponge carbonate buildups and bedded detrital limestone in between. Both the buildups and detrital limestones revealed differential susceptibility to compaction which, apart from differential subsidence of the Palaeozoic basement and synsedimentary faulting, was one of the factors controlling seafloor palaeorelief in the Late Jurassic sedimentary basin. The compaction of the detrital limestones has been estimated with an experimental oedometric method in which specially prepared mixtures made of ground limestones from a quarry in the village of Żary were subjected to oedometer tests. The diameters of the detrital grains and their percentages in the limestones were determined by microscopic examinations of thin sections. The diameters were assigned to predetermined classes corresponding to the Udden-Wentworth scale. The rock samples were then ground down to the grain sizes observed in thin sections. From such materials, mixtures were prepared of grain size distributions corresponding to those observed in thin sections. After adding water the mixtures were subjected to oedometer tests. Analysis of the compression of such mixtures under specific loads enabled preparation of a mathematical formula suitable for the estimation of mechanical compaction of the limestone. The obtained values varied from 27.52 to 55.53% for a load corresponding to 300 metres burial depth. The most significant effect of mechanical compaction was observed for loads representing only 2 metres burial depth. Further loading resulted in a much smaller reduction in sample height. The results of the oedometer tests cannot be used directly to determine compaction of the detrital limestones. Mainly because microscopic observations of thin sections of the experimental material show that chemical compaction was also an important factor influencing thickness reduction of the limestones.

Devonian and Mississippian rocks of the northern Antelope Range, Eureka County, Nevada

USGS Publications Warehouse

Hose, Richard Kenneth; Armstrong, A.K.; Harris, A.G.; Mamet, B.L.

1982-01-01

Lower through Upper Devonian rocks of the northern Antelope Range, Nev., consist of four formational rank units more than 800 m thick, separated from Mississippian units by an unconformity. The lower three Devonian units, the Beacon Peak Dolomite, McColley Canyon Formation, and Denay Limestone are known in other areas; the top unit, the Fenstermaker Wash Formation, is new. The Mississippian units, more than 280 m thick, are divisible into three units which are unlike coeval units elsewhere, and are herein named the Davis Spring Formation, Kinkead Spring Limestone, and Antelope Range Formation. Systematic sampling of the Devonian sequence has yielded relatively abundant conodonts containing several biostratigraphic ally significant taxa. The Mississippian units contain redeposited conodonts of chiefly Late Devonian and Early Mississippian (Kinderhookian) age together with indigenous Osagean foraminifers and algae in the Kinkead Spring Limestone.

Downflow limestone beds for treatment of net-acidic, oxic, iron-laden drainage from a flooded anthracite mine, Pennsylvania, USA: 2. Laboratory evaluation

USGS Publications Warehouse

Cravotta, C.A.; Ward, S.J.; Hammarstrom, J.M.

2008-01-01

Acidic mine drainage (AMD) containing elevated concentrations of dissolved iron and other metals can be neutralized to varying degrees by reactions with limestone in passive treatment systems. We evaluated the chemical and mineralogical characteristics and the effectiveness of calcitic and dolomitic limestone for the neutralization of net-acidic, oxic, iron-laden AMD from a flooded anthracite mine. The calcitic limestone, with CaCO3 and MgCO3 contents of 99.8 and <0.1 wt%, respectively, and the dolomitic limestone, with CaCO3 and MgCO3 contents of 60.3 and 40.2 wt%, were used to construct a downflow treatment system in 2003 at the Bell Mine, a large source of AMD and baseflow to the Schuylkill River in the Southern Anthracite Coalfield, in east-central Pennsylvania. In the winter of 2002-2003, laboratory neutralization-rate experiments evaluated the evolution of effluent quality during 2 weeks of continuous contact between AMD from the Bell Mine and the crushed calcitic or dolomitic limestone in closed, collapsible containers (cubitainers). The cubitainer tests showed that: (1) net-alkaline effluent could be achieved with detention times greater than 3 h, (2) effluent alkalinities and associated dissolution rates were equivalent for uncoated and Fe(OH)3-coated calcitic limestone, and (3) effluent alkalinities and associated dissolution rates for dolomitic limestone were about half those for calcitic limestone. The dissolution rate data for the cubitainer tests were used with data on the volume of effuent and surface area of limestone in the treatment system at the Bell Mine to evaluate the water-quality data for the first 1.5 years of operation of the treatment system. These rate models supported the interpretation of field results and indicated that treatment benefits were derived mainly from the dissolution of calcitic limestone, despite a greater quantity of dolomitic limestone within the treatment system. The dissolution-rate models were extrapolated on a decadal scale to indicate the expected decreases in the mass of limestone and associated alkalinities resulting from the long-term reaction of AMD with the treatment substrate. The models indicated the calcitic limestone would need to be replenished approaching the 5-year anniversary of treatment operations to maintain net-alkaline effluent quality. ?? 2008 Springer-Verlag.

Estimating porosity and solid dielectric permittivity in the Miami Limestone using high-frequency ground penetrating radar (GPR) measurements at the laboratory scale

NASA Astrophysics Data System (ADS)

Mount, Gregory J.; Comas, Xavier

2014-10-01

Subsurface water flow in South Florida is largely controlled by the heterogeneous nature of the karst limestone in the Biscayne aquifer and its upper formation, the Miami Limestone. These heterogeneities are amplified by dissolution structures that induce changes in the aquifer's material and physical properties (i.e., porosity and dielectric permittivity) and create preferential flow paths. Understanding such patterns are critical for the development of realistic groundwater flow models, particularly in the Everglades, where restoration of hydrological conditions is intended. In this work, we used noninvasive ground penetrating radar (GPR) to estimate the spatial variability in porosity and the dielectric permittivity of the solid phase of the limestone at centimeter-scale resolution to evaluate the potential for field-based GPR studies. A laboratory setup that included high-frequency GPR measurements under completely unsaturated and saturated conditions was used to estimate changes in electromagnetic wave velocity through Miami Limestone samples. The Complex Refractive Index Model was used to derive estimates of porosity and dielectric permittivity of the solid phase of the limestone. Porosity estimates of the samples ranged between 45.2 and 66.0% and showed good correspondence with estimates of porosity using analytical and digital image techniques. Solid dielectric permittivity values ranged between 7.0 and 13.0. This study shows the ability of GPR to image the spatial variability of porosity and dielectric permittivity in the Miami Limestone and shows potential for expanding these results to larger scales and other karst aquifers.

Hydrogeology of the karst of Puerto Rico

USGS Publications Warehouse

Giusti, Ennio V.

1978-01-01

About one-fifth of Puerto Rico is covered by a tropical karst formed on a series of six limestone formations ranging in age from middle-Oligocene to middle Miocene. These formations strike east to west and crop out over the north coast of the island. Structurally, the rocks form a simple wedge abutting southward against a mountain chain of volcanic origin and thickening northward to about 1,400 meters by the seashore. All stages of karstification are present: from the incipient, found at the western end of the belt to the residual, found at the eastern end. Maximum development of sinkholes occurs on the Aguada Limestone and upper part of the Aymanom Limestone. These formations have a CaCO3 content range from about 85 to 95 percent. The denudation rate of the Limestone belt through solution is computed as 0.70 mm per year with some evidence that abrasion may increase the denudation rate locally by as much as 40 percent. (Woodard-USGS)

Appraisal of iron deposits in southern and western Turkey

USGS Publications Warehouse

Gair, Jacob Eugene; Capan, Ussal Z.

1972-01-01

Between May 20 and June 17, 1969, previously known iron deposits were examined widely at eight separate localities in western Turkey. The object of the examinations was to learn the, nature, geologic setting, and approximate size of each deposit, to review prior estimates of size, and possibly recommend additional exploratory work.. The full extent of each deposit is poorly known at the present time, so recommended additional work entails drilling, digging trenches or pits, geologic mapping or, combinations of these activities. On Qaldagi Mountain an area of about 1 sq km is capped by bredciated chert under which may be a continuous zone of mixed iron oxides and chert fragments. The thickness of the ferruginous zone is poorly known but is as much as 12 meters, in at least one place. The- ferruginous material and chert appear to have formed by the weathering of serpentine, bun this concept needs further testing. Drilling is recommended to determine the grade, thickness, and extent-of the ferruginous zone beneath the cherty cap. Inasmuch as mining by hand sorting is in progress, part of the deposit can be considered to be marginally in the category of iron reserves. The Keceborlu iron deposit consists of earthy to slightly compacted hematite and limonite mixed with small chert fragments. The surface area underlain by ferruginous rock is about 5,000 to 7,500 sq meters. The maximum known thickness of the deposit is about 7 meters. Iron appears to have been concentrated by weathering and oxidation of cherty limestone. The deposit is probably either a remnant of a once more extensive weathered cap, or a sink hole filling. The Keceborlu area warrants a low priority for further exploration, but one drill hole is recommended to test the thickness of the deposit. The iron deposits at Mellec are layered and vein-magnetite replacements of limestone. The six known deposits are discontinuous. No additional. work is recommended. ' The Gilindire Iron deposit consists of irregular concentrations of pisolitic and earthy hematite and 'limonite along an unconformity or disconformity between two groups of limestone. The ferruginous zone is incompletely known around the rim of the large Gilindire syncline. Data from trenches 5 to 6 km around the syncline--about ? the possible length of the ferruginous zone--provide the main knowledge about the size and grade of ferruginous lenses. The ferruginous lenses range in thickness from a fraction of a meter, to about 3 meters, but appear to average 1 meter or less, and range in grade from about 10 to 37 percent iron. No additional exploration work is recommended at Gilindire. The Buyukeceli deposit consists of veinlike masses of earthy and compact hematite and limonite cutting fresh limestone. The veins apparently originally contained siderite which has been weathered and converted to iron oxide. Further exploration by drilling is recommended at such time as other largest deposits are able to be brought into the development stage in the Mediterranean coastal area of Turkey. The iron deposits overlooking Bayas on the Gulf of Iskenderun ere in one or more layers along the west-facing front of the Amanus Mountain Range, between beds of gently to moderately east-dipping limestone. Isolated exposures may represent a once-continuous ferruginous bed that has been blockfaulted and intruded by serpentine. The ferruginous bed (or beds) is 20-30 meters thick, and consists of a mixture of very fine grained hematite and claylike material. Iron content ranges from 20 to 40 percent and aluminum, averages about 15 percent. Available data on distribution are scant but suggest that one ferruginous bed may be 1-2 kilometers long, 500 meters wide and 20 meters thick. The potentially large size of the Payas deposits warrants an early coordinated program of drilling end beneficiation testing. An iron deposit was examined on a conspicuous limestone ridge in the Syrian graben east of the Amanus Moun

Selection, procurement and description of Salem Limestone samples used to study the effects of acid rain

NASA Astrophysics Data System (ADS)

Ross, M.; Knab, L.

1984-07-01

The selection, procurement, and description of the Salem Limestone to be used in field exposure tests to assess the effects of acid rain on building stone are described. The rationale for choosing Salem Limestone is given and a brief geological description of the stone is provided. Preparation of the stone samples for field exposure, including cutting, surface finishing and labelling is presented.

Hydrogeology of the gray limestone aquifer in southern Florida

USGS Publications Warehouse

Reese, Ronald S.; Cunningham, Kevin J.

2000-01-01

Results from 35 new test coreholes and aquifer-test, water-level, and water-quality data were combined with existing hydrogeologic data to define the extent, thickness, hydraulic properties, and degree of confinement of the gray limestone aquifer in southern Florida. This aquifer, previously known to be present only in southeastern Florida (Miami-Dade, Broward, and Palm Beach Counties) below, and to the west of, the Biscayne aquifer, extends over most of central-south Florida, including eastern and central Collier County and southern Hendry County; it is the same as the lower Tamiami aquifer to the north, and it becomes the water-table aquifer and the upper limestone part of the lower Tamiami aquifer to the west. The aquifer generally is composed of gray, shelly, lightly to moderately cemented limestone with abundant shell fragments or carbonate sand, abundant skeletal moldic porosity, and minor quartz sand. The gray limestone aquifer comprises the Ochopee Limestone of the Tamiami Formation, and, in some areas, the uppermost permeable part of an unnamed formation principally composed of quartz sand. Underlying the unnamed formation is the Peace River Formation of the upper Hawthorn Group, the top of which is the base of the surficial aquifer system. Overlying the aquifer and providing confinement in much of the area is the Pinecrest Sand Member of the Tamiami Formation. The thickness of the aquifer is comparatively uniform, generally ranging from 30 to 100 feet. The unnamed formation part of the aquifer is up to 20 feet thick. The Ochopee Limestone accumulated in a carbonate ramp depositional system and contains a heterozoan carbonate-particle association. The principal rock types of the aquifer are pelecypod lime rudstones and floatstones and permeable quartz sands and sandstones. The pore types are mainly intergrain and separate vug (skeletal-moldic) pore spaces. The rock fabric and associated primary and secondary pore spaces combine to form a dual diffuse-carbonate and conduit flow system capable of producing high values of hydraulic conductivity. Transmissivity values of the aquifer are commonly greater than 50,000 feet squared per day to the west of Miami-Dade and Broward Counties. Hydraulic conductivity ranges from about 200 to 12,000 feet per day and generally increases from east to west; an east-to-west shallowing of the depositional profile of the Ochopee Limestone carbonate ramp contributes to this spatial trend. The aquifer contains two areas of high transmissivity, both of which trend northwest-southeast. One area extends through southern Hendry County. The other area extends through eastern Collier County, with a transmissivity as high as 300,000 feet squared per day; in this area, the aquifer is structurally high, the top of the aquifer is close to land surface, and it is unconfined to semiconfined. The confinement of the aquifer is good to the north and east in parts of southern Hendry, Palm Beach, Collier, Broward, and Miami-Dade Counties. In these areas, the upper confining unit approaches or is greater than 50 feet thick, and vertical leakance is less than 1.0 x 10-3 l/day. In most of the study area, the specific conductance in water from the gray limestone aquifer is 1,500 microsiemens per centimeter or less (chloride concentration of about 250 milligrams per liter or less). Areas where specific conductance is greater than 3,000 microsiemens per centimeter are found where there is a low horizontal-head gradient and the upper confining unit is greater than 50 feet thick. An area with specific conductance less than 1,500 microsiemens per centimeter extends from southern Hendry County to the southeast into western Broward County and coincides with an area of high transmissivity. However, much of this area has good confinement. The potentiometric gradient also is to the southeast in much of the area, and this area of low specific conductance is probably caused by a relatively rapid downgradient movement of fres

Laboratory and field evaluation of a flushable oxic limestone drain for treatment of net-acidic drainage from a flooded anthracite mine, Pennsylvania, USA

USGS Publications Warehouse

Cravotta, C.A.

2008-01-01

This paper demonstrates the use of dissolution-rate data obtained in the laboratory to indicate the potential quality of effluent from a field-scale oxic limestone drain (OLD) treatment system for neutralization of dilute acidic mine drainage (AMD). Effluent from the Reevesdale Mine South Dip Tunnel, a large source of AMD and base flow to the Wabash Creek and Little Schuylkill River in the Southern Anthracite Coalfield of east-central Pennsylvania, is representative of AMD with low concentrations but high loadings of dissolved Fe, Al and other metals because of a high flow rate. In January 2003, rapid neutralization of the AMD from the Reevesdale Mine was achieved in laboratory tests of its reaction rate with crushed limestone in closed, collapsible containers (Cubitainers). The tests showed that net-alkaline effluent could be achieved with retention times greater than 3 h and that effluent alkalinities and associated dissolution rates were equivalent for Fe(OH)3-coated and uncoated limestone. On the basis of the laboratory results, a flushable OLD containing 1450 metric tons of high-purity calcitic limestone followed by two 0.7-m deep wetlands were constructed at the Reevesdale Mine. During the first year of operation, monthly data at the inflow, outflow and intermediate points within the treatment system were collected (April 2006-2007). The inflow to the treatment system ranged from 6.8 to 27.4 L/s, with median pH of 4.7, net acidity of 9.1 mg/L CaCO3, and concentrations of dissolved Al, Fe and Mn of 1.0, 1.9 and 0.89 mg/L, respectively. The corresponding effluent from the OLD had computed void-volume retention times of 4.5-18 h, with median pH of 6.6, net acidity of -93.2 mg/L CaCO3, and concentrations of dissolved Al, Fe and Mn of <0.1, 0.08 and 0.52 mg/L, respectively. The wetlands below the OLD were effective for retaining metal-rich solids flushed at monthly or more frequent intervals from the OLD, but otherwise had little effect on the effluent quality. During the first year of operation, approximately 43 metric tons of limestone were dissolved and 2 metric tons of Al, Fe and Mn were precipitated within the OLD. However, because of the accumulation of these metals within the OLD and possibly other debris from the mine, the effectiveness of the treatment system declined. Despite the installation of a flush-pipe network at the base of the OLD to remove precipitated solids, the limestone bed clogged near the inflow. Consequently, a large fraction of the AMD bypassed the treatment system. To promote flow through the OLD, the flush pipes were open continuously during the last 4 months of the study; however, this effluent was only partially treated because short-circuiting through the pipes decreased contact between the effluent and limestone. A reconfiguration of the flow path through the limestone bed from horizontal to vertical upward could increase the limestone surface area exposed to the metal-laden influent, increase the cross-sectional area perpendicular to flow, decrease the flow path for solids removal, and, consequently, decrease potential for clogging.

Effects of different limestone particle sizes in the diet of broiler breeders post molting on their performance, egg quality, incubation results, and pre-starter performance of their progeny.

PubMed

Bueno, I J M; Surek, D; Rocha, C; Schramm, V G; Muramatsu, K; Dahlke, F; Maiorka, A

2016-04-01

An experiment was conducted to test the hypothesis that a coarse limestone diet improves productivity, reproductive performance and the calcium utilization of molted broiler breeders. In total, 640 broiler breeder females, 73-week-old and sixty-four 27-week-old cockerels, Cobb 500, were evaluated during 10 weeks, according to a randomized block design composed of 4 treatments with 8 replicates each. Treatments consisted of diets with the inclusion of 100% fine limestone-fine PS (0.2 mm GMD-geometric mean diameter); PS1: 30% fine limestone+70% limestone with 1.0 mm GMD; PS2: 30% fine limestone+70% limestone with 2.0 mm GMD; and PS3: 30% fine limestone+70% limestone with 3.0 mm GMD. Calcium retention in the gizzard of the breeders, bone characteristics, and breeder performance, egg characteristics, eggshell quality, incubation performance, chick quality and yield, chick pre-starter live performance, and chick bone characteristics were determined. There was no significant difference (P>0.05) in the rate of lay, percentage of non-settable eggs, egg weight, egg shape index, egg specific gravity, eggshell weight, thickness, and percentage hatchability and egg weight loss of broiler breeders fed with diets with different limestone particle sizes. The chick quality and yield, chick pre-starter live performance, and chick bone characteristics were not affected (P>0.05) by any of the limestone particle sizes. It was concluded that live and reproductive performance parameters of broiler breeders post molting is not affected by limestone particle size in the feed. © 2016 Poultry Science Association Inc.

Hydrogeology of the surficial aquifer system, Dade County, Florida

USGS Publications Warehouse

Fish, J.E.; Stewart, M.T.

1991-01-01

An investigation of the surficial aquifer system in Dade County, begun in 1983, is part of a regional study of the aquifer system in southeastern Florida. Test drilling for lithologic samples, flow measurements during drilling, aquifer testing, and analyses of earlier data permitted delineation of the hydraulic conductivity distribution (on hydrogeologic sections), the aquifers in the system, the generalized transmissivity distribution, and interpretation of the ground-water flow system. The surficial aquifer system, in which an unconfined ground-water flow system exists, is composed of the sediments from land surface downward to the top of a regionally extensive zone of sediments of low permeability called the intermediate confining unit. The aquifer system units, which vary in composition from clay-size sediments to cavernous limestone, are hydro stratigraphically divided into the Biscayne aquifer at the top; an intervening semiconfining unit that consists principally of clayey sand; a predominantly gray limestone aquifer in the Tamiami Formation in western and west-central Dade County; and sand or clayey sand near the base of the surficial aquifer system. The base of the surficial aquifer system ranges from a depth of about 175 to 210 feet below land surface in westernmost Dade County to greater than 270 feet in northeastern Dade County. Test drilling and aquifer-test data indicate a complex hydraulic conductivity distribution. Hydraulic conductivities of the very highly permeable zone of the Biscayne aquifer commonly exceed 10,000 feet per day; in the gray limestone aquifer, they range from 210 to 780 feet per day. Transmissivities of the surficial aquifer system vary locally but have a recognizable areal trend. Estimated values generally are about 300,000 feet squared per day or greater in nearly all of central and eastern Dade County. Transmissivity is lower to the west, decreasing to less than 75,000 feet squared per day in western Dade County. High transmissivity usually is associated with thick sections of the Fort Thompson Formation within the Biscayne aquifer. The gray limestone aquifer of the Tamiami Formation has transmissivities that range from 5,800 to 39,000 feet squared per day in western Dade County. The transition from high transmissivity to relatively low transmissivity is often only a few miles wide and coincides with the decrease in thickness of the very highly permeable Fort Thompson Formation, which marks the western boundary of the Biscayne aquifer. More effective drainage as a result of extensive canal systems and large-scale pumping from municipal well fields has greatly altered the predevelopment flow system in eastern Dade County by: (1) eliminating or greatly reducing a seasonal and coastal ground-water ridge; (2) reducing deep circulation; (3) reducing or eliminating seasonal westward movement of ground water; (4) causing accelerated stormwater runoff and short ground-water flow paths; and (5) generally lowering the water table and inducing saltwater intrusion. Under predevelopment conditions in western Dade County, water entered the gray limestone aquifer by lateral movement from Broward and Collier Counties, and by downward seepage from The Everglades and the Biscayne aquifer, and moved southward and southeastward into Dade County to coastal discharge areas. Circulation in the Biscayne aquifer inland also was primarily to the south and southeast. In eastern Dade County, the seasonal ground-water ridge that formed under predevelopment conditions supported both easterly and westerly ground-water flow away from the ridge axis. This seasonal flow created a zone of lower dissolved solids.

Reduction of particulate carryover from a pressurized fluidized bed

NASA Technical Reports Server (NTRS)

Patch, R. W.

1979-01-01

A bench scale fluidized bed combustor was constructed with a conical shape so that the enlarged upper part of the combustor would also serve as a granular bed filter. The combustor was fed coal and limestone. Ninety-nine tests of about four hours each were conducted over a range of conditions. Coal-to-air ratio varied from 0.033 to 0.098 (all lean). Limestone-to-coal ratio varied from 0.06 to 0.36. Bed depth varied from 3.66 to 8.07 feet. Temperature varied from 1447 to 1905 F. Pressure varied from 40 to 82 psia. Heat transfer area had the range zero to 2.72 ft squared. Two cone angles were used. The average particulate carry over of 2.5 grains/SCF was appreciably less than cylindrical fluidized bed combustors. The carry over was correlated by multiple regression analysis to yield the dependence on bed depth and hence the collection efficiency, which was 20%. A comparison with a model indicated that the exhaust port may be below the transport disengaging height for most of the tests, indicating that further reduction in carry over and increase in collection efficiency could be affected by increasing the freeboard and height of the exhaust port above the bed.

High Resolution ground penetrating radar (GPR) measurements at the laboratory scale to model porosity and permeability in the Miami Limestone in South Florida.

NASA Astrophysics Data System (ADS)

Mount, G. J.; Comas, X.

2015-12-01

Subsurface water flow within the Biscayne aquifer is controlled by the heterogeneous distribution of porosity and permeability in the karst Miami Limestone and the presence of numerous dissolution and mega-porous features. The dissolution features and other high porosity areas can create preferential flow paths and direct recharge to the aquifer, which may not be accurately conceptualized in groundwater flow models. As hydrologic conditions are undergoing restoration in the Everglades, understanding the distribution of these high porosity areas within the subsurface would create a better understanding of subsurface flow. This research utilizes ground penetrating radar to estimate the spatial variability of porosity and dielectric permittivity of the Miami Limestone at centimeter scale resolution at the laboratory scale. High frequency GPR antennas were used to measure changes in electromagnetic wave velocity through limestone samples under varying volumetric water contents. The Complex Refractive Index Model (CRIM) was then applied in order to estimate porosity and dielectric permittivity of the solid phase of the limestone. Porosity estimates ranged from 45.2-66.0% from the CRIM model and correspond well with estimates of porosity from analytical and digital image techniques. Dielectric permittivity values of the limestone solid phase ranged from 7.0 and 13.0, which are similar to values in the literature. This research demonstrates the ability of GPR to identify the cm scale spatial variability of aquifer properties that influence subsurface water flow which could have implications for groundwater flow models in the Biscayne and potentially other shallow karst aquifers.

Collapse of caves at shallow depth in Gaziantep city center, Turkey: a case study

NASA Astrophysics Data System (ADS)

Canakci, Hanifi

2007-12-01

This paper focuses on an investigation of the possible causes for the collapse of limestone caves in Gaziantep, Turkey. The city contains a lot of man-made caves, at a shallow depth, of various width and length. These caves were mainly excavated to provide work or storage space. As the city has been growing fast with increased population, many structures were constructed over these caves. Recently, two caves collapsed and five houses were damaged. These caves are all made of limestone and it was observed after the collapse that the limestone was saturated with water due to sewer pipe leakage and surface water. Tests were carried out on the limestone and it was determined that the compressive strength of limestone decreases by about 50% and the tensile strength decreased by about 80% when saturated with water. It was concluded that the reduced strength of the limestone combined with additional loads due to the factors mentioned above seem to be the main reason for these collapses.

Geological applications of Nimbus radiation data in Middle East

NASA Technical Reports Server (NTRS)

Allison, L. J.

1976-01-01

Plateaus of Eocene limestone and exposed limestone escarpments, in Egypt and Saudi Arabia respectively, were indicated by cool brightness temperatures T sub B (less than 240 to 265 K) by the Nimbus 5 electrically scanning microwave radiometer (ESMR) over a 2-year period. Nubian sandstone, desert eolian sand and igneous metamorphic rocks were differentiated from these limestone areas by warm T sub B values (more than 265 to 300 K). Cool T sub B values in the form of a V were found over broad areas of the Nile Valley and in the western desert of central Egypt. Similar cool T sub B values were shown over limestone-dolomitic hills of the interior Homocline and the Hadramawt plateau of Saudi Arabia. Nimbus 5 and 6 ESMR T sub B values selectively identified intermediate dense rock types (limestone versus sandstone/granite) in the Lake Nasser region whose thermal inertia ranged from 0.035 to 0.06 cal cm to minus 2 C sec 1/2 to minus one half.

The behavior limestone under explosive load

NASA Astrophysics Data System (ADS)

Orlov, M. Yu; Orlova, Yu N.; Bogomolov, G. N.

2016-11-01

Limestone behavior under explosive loading was investigated. The behavior of the limestone by the action of the three types of explosives, including granular, ammonite and emulsion explosives was studied in detail. The shape and diameter of the explosion craters were obtained. The observed fragments after the blast have been classified as large, medium and small fragments. Three full-scale experiments were carried out. The research results can be used as a qualitative test for the approbation of numerical methods.

Stratigraphy of the Sarkisla area, Sivas basin, eastern central Anatolia

DOE Office of Scientific and Technical Information (OSTI.GOV)

Bilgic, T.; Sumengen, M.; Terlemez, I.

1988-08-01

The stratigraphy of the Sarkisla area, southeastern Central Anatolian Massif, is characterized by a succession of rock units ranging from late Paleocene to Pliocene in age. The Caldag group mostly consists of deep-water units and forms the base of the Tertiary rocks. However, its relation to the basement rocks is not observed in the area. This group is represented by late Paleocene-Lutetian-age turbiditic pyroclastics and limestones, andesitic lavas and pyroclastics topped with reefal limestones, and turbiditic limestones and pyroclastics alternating with limestone blocks. During Lutetian to early Priabonian time, shallow marine clastics were deposited along the southern margin of themore » basin, while continental clastics and platform limestones accumulated along the northern margin. Late Priabonian to early Oligocene time is represented by gypsiferous deposits followed by late Oligocene-age fluvial clastics. The gypsiferous deposits conformably overlie the shallow marine formations but rest on the Caldag group unconformably. During early to middle Miocene time, alternating lacustrine limestones, gypsum, and basalts formed on the fluvial clastics; to the north, basalts formed on the platform limestones. The uppermost sequence of the basin, composed of Tortonian-early Pliocene-age fluvial clastics, lacustrine limestones, and fan deposits, unconformably overlies the older formations. The stratigraphy of the study area is similar to the Ulukisla basin, southwestern Central Anatolian Massif. Therefore, this basin can be considered to be the prolongation of the Ulukisla basin offset by the Ecemis fault.« less

THERMAL TECHNOLOGY TESTED FOR CONTAMINANT RECOVERY

EPA Science Inventory

A research project on steam enhanced remediation (SER) for the recovery of dense nonaqueous phase liquid (DNAPL) from fractured limestone has been undertaken at the former Loring Air Force Base Quarry site in Limestone, ME. Participants in the project include the Maine Departmen...

Investigations of a Cretaceous limestone with spectral induced polarization and scanning electron microscopy

NASA Astrophysics Data System (ADS)

Johansson, Sara; Sparrenbom, Charlotte; Fiandaca, Gianluca; Lindskog, Anders; Olsson, Per-Ivar; Dahlin, Torleif; Rosqvist, Håkan

2017-02-01

Characterization of varying bedrock properties is a common need in various contexts, ranging from large infrastructure pre-investigations to environmental protection. A direct current resistivity and time domain induced polarization (IP) survey aiming to characterize properties of a Cretaceous limestone was carried out in the Kristianstad basin, Sweden. The time domain IP data was processed with a recently developed method in order to suppress noise from the challenging urban setting in the survey area. The processing also enabled extraction of early decay times resulting in broader spectra of the time decays and inversion for Cole-Cole parameters. The aims of this study is to investigate if large-scale geoelectrical variations as well as small-scale structural and compositional variations exist within the Kristianstad limestone, and to evaluate the usefulness of Cole-Cole inverted IP data in early time ranges for bedrock characterization. The inverted sections showed variations within the limestone that could be caused by variations in texture and composition. Samples from a deep drilling in the Kristianstad basin were investigated with scanning electron microscopy and energy dispersive X-ray spectroscopy, and the results showed that varying amounts of pyrite, glauconite and clay matrix were present at different levels in the limestone. The local high IP anomalies in the limestone could be caused by these minerals otherwise the IP responses were generally weak. There were also differences in the texture of the limestone at different levels, governed by fossil shapes and composition, proportions of calcareous cement and matrix as well as amount of silicate grains. Textural variations may have implications on the variation in Cole-Cole relaxation time and frequency factor. However, more research is needed in order to directly connect microgeometrical properties in limestone to spectral IP responses. The results from this study show that it is possible to recover useable spectral information from early decay times. We also show that under certain conditions (e.g. relatively short relaxation times in the subsurface), it is possible to extract spectral information from time domain IP data measured with on-off times as short as 1 s.

New Ediacara fossils preserved in marine limestone and their ecological implications

PubMed Central

Chen, Zhe; Zhou, Chuanming; Xiao, Shuhai; Wang, Wei; Guan, Chengguo; Hua, Hong; Yuan, Xunlai

2014-01-01

Ediacara fossils are central to our understanding of animal evolution on the eve of the Cambrian explosion, because some of them likely represent stem-group marine animals. However, some of the iconic Ediacara fossils have also been interpreted as terrestrial lichens or microbial colonies. Our ability to test these hypotheses is limited by a taphonomic bias that most Ediacara fossils are preserved in sandstones and siltstones. Here we report several iconic Ediacara fossils and an annulated tubular fossil (reconstructed as an erect epibenthic organism with uniserial arranged modular units), from marine limestone of the 551–541 Ma Dengying Formation in South China. These fossils significantly expand the ecological ranges of several key Ediacara taxa and support that they are marine organisms rather than terrestrial lichens or microbial colonies. Their close association with abundant bilaterian burrows also indicates that they could tolerate and may have survived moderate levels of bioturbation. PMID:24566959

New Ediacara fossils preserved in marine limestone and their ecological implications.

PubMed

Chen, Zhe; Zhou, Chuanming; Xiao, Shuhai; Wang, Wei; Guan, Chengguo; Hua, Hong; Yuan, Xunlai

2014-02-25

Ediacara fossils are central to our understanding of animal evolution on the eve of the Cambrian explosion, because some of them likely represent stem-group marine animals. However, some of the iconic Ediacara fossils have also been interpreted as terrestrial lichens or microbial colonies. Our ability to test these hypotheses is limited by a taphonomic bias that most Ediacara fossils are preserved in sandstones and siltstones. Here we report several iconic Ediacara fossils and an annulated tubular fossil (reconstructed as an erect epibenthic organism with uniserial arranged modular units), from marine limestone of the 551-541 Ma Dengying Formation in South China. These fossils significantly expand the ecological ranges of several key Ediacara taxa and support that they are marine organisms rather than terrestrial lichens or microbial colonies. Their close association with abundant bilaterian burrows also indicates that they could tolerate and may have survived moderate levels of bioturbation.

Heat transfer to horizontal tubes in a pilot-scale fluidized-bed combustor burning low-rank coals

DOE Office of Scientific and Technical Information (OSTI.GOV)

Grewal, N.S.; Goblirsch, G.

Experimental data are obtained for the heat transfer coefficient between immersed horizontal tube bundles and an atmospheric-fluidized-bed combustor burning low-rank coals. Silica sand and limestone are used as bed material. The tests are conducted, with and without limestone addition and ash recycle, at average bed temperatures ranging from 1047 to 1125 K, superficial fluidizing velocity of 1.66 to 2.04 m/s, and excess air levels of 15 to 40 percent. The experimental data are examined in the light of the existing correlations for the heat transfer coefficient. The predicted values of heat transfer coefficient from the correlations proposed by Grewal andmore » Bansal et al. are found to be within + or - 25 percent of the experimental values of heat transfer coefficient, when the contribution due to radiation is also included.« less

Water quality changes in acid mine drainage streams in Gangneung, Korea, 10 years after treatment with limestone

DOE Office of Scientific and Technical Information (OSTI.GOV)

Shim, Moo Joon; Choi, Byoung Young; Lee, Giehyeon

To determine the long-term effectiveness of the limestone treatment for acid mine drainage (AMD) in Gangneung, Korea, we investigated the elemental distribution in streams impacted by AMD and compared the results of previous studies before and approximately 10 years after the addition of limestone. Addition of limestone in 1999 leads to a pH increase in 2008, and with the exception of Ca, the elemental concentrations (e.g., Fe, Mn, Mg, Sr, Ni, Zn, S) in the streams decreased. The pH was 2.5–3 before the addition of limestone and remained stable at around 4.5–5 from 2008 to 2011, suggesting the reactivity ofmore » the added limestone was diminished and that an alternative approach is needed to increase the pH up to circumneutral range and maintain effective long-term treatment. To identify the processes causing the decrease in the elemental concentrations, we also examined the spatial (approximately 7 km) distribution over three different types of streams affected by the AMD. Lastly, the elemental distribution was mainly controlled by physicochemical processes including redox reactions, dilution on mixing, and co-precipitation/adsorption with Fe (hydr)oxides.« less

Modifying the properties of finely ground limestone by tumbling granulation

NASA Astrophysics Data System (ADS)

Macho, Oliver; Eckert, Maroš; Tomášová, Barbora; Peciar, Peter; Ščasný, Martin; Fekete, Roman; Peciar, Marián

2016-06-01

Calcium carbonate in the form of finely ground limestone is a material that has found its application in a wide range of industries, in the chemical, rubber, agricultural, and paper industries, is used for desulfurization of boilers and other. In civil engineering, ground limestone is used for the production of building materials, plaster and mortar mixtures, as a filler in concrete mixtures, in road construction, and as an essential component of mastic asphalt. This paper deals with examining the modification of the properties of finely ground limestone by the tumbling agglomeration method. It has been shown that the components of concrete with a round grain have a positive effect on the pumping of concrete in comparison with an elongated grain or the rough surface of crushed stone. The experiments will be carried out on a granulation plate using a variety of granulation liquid. The agglomerates and their properties were compared with untreated finely ground limestone, with a focus on detecting changes in compressibility, density and particle size. The output of this paper is a description and graphical representation of the changes in the properties of ground limestone before and after the agglomeration process.

Water quality changes in acid mine drainage streams in Gangneung, Korea, 10 years after treatment with limestone

DOE PAGES

Shim, Moo Joon; Choi, Byoung Young; Lee, Giehyeon; ...

2015-09-28

To determine the long-term effectiveness of the limestone treatment for acid mine drainage (AMD) in Gangneung, Korea, we investigated the elemental distribution in streams impacted by AMD and compared the results of previous studies before and approximately 10 years after the addition of limestone. Addition of limestone in 1999 leads to a pH increase in 2008, and with the exception of Ca, the elemental concentrations (e.g., Fe, Mn, Mg, Sr, Ni, Zn, S) in the streams decreased. The pH was 2.5–3 before the addition of limestone and remained stable at around 4.5–5 from 2008 to 2011, suggesting the reactivity ofmore » the added limestone was diminished and that an alternative approach is needed to increase the pH up to circumneutral range and maintain effective long-term treatment. To identify the processes causing the decrease in the elemental concentrations, we also examined the spatial (approximately 7 km) distribution over three different types of streams affected by the AMD. Lastly, the elemental distribution was mainly controlled by physicochemical processes including redox reactions, dilution on mixing, and co-precipitation/adsorption with Fe (hydr)oxides.« less

Full-scale results for TAM limestone injection

DOE Office of Scientific and Technical Information (OSTI.GOV)

Baer, S.

1996-12-31

Information is outlined on the use of thermally active marble (TAM) sorbents in boilers. Data are presented on: the comparison of TAM to limestone; NOVACON process development history; CFB test history; CFB pilot scale test; full-scale CFB trial; August, 1996 CFB demonstration; Foster Wheeler Mount Carmel sorbent feed rate comparison and Ca:S comparison; unburned carbon is ash; and advantages and savings in CFB boilers.

SOX OUT ON A LIMB (LIMESTONE INJECTION MULTISTAGE BURNER)

EPA Science Inventory

The paper describes the most recent results from the Limestone Injection Multistage Burner (LIMB) program, covering results from the wall-fired demonstration. Tests were conducted to determine the efficacy of commercial calcium hydroxide (Ca(OH)2) and of calcium-lignosulfonate-mo...

DEVELOPMENTS IN LIMB (LIMESTONE INJECTION MULTISTAGE BURNER) TECHNOLOGY

EPA Science Inventory

The paper describes the most recent results from the Limestone Injection Multistage Burner (LIMB) program, results from the wall-fired demonstration. Tests were conducted to determine the efficacy of commercial calcium hydroxide--Ca(OH)2--supplied by Marblehead Lime Co. and of ca...

The negative effect of environmental geological conditions of some geo-archaeological sites of North Coast and Alexandria

NASA Astrophysics Data System (ADS)

Ibrahim, Hani; Kamh, Gamal

2005-12-01

Three geo-archaeological sites at the North Coast and Alexandria, namely, the Alexandria wall (El Shalalat Park site), Abu Soir temple, and Marina excavations, were investigated to determine the negative impact of a salty environmental condition. The monuments suffer from rock decay of different rates. The geo-archaeological sites were built mainly from oolitic limestone blocks (i.e., the Alexandria wall at the El Shalalat Park site and Abu Soir temple) or excavated on them (i.e., Marina excavations). Field inspection and a lab analysis were carried out to understand the weathering mechanism. Salt weathering criteria such as disintegration, pitting, scaling, exfoliation, and honeycomb are observed on the Alexandria wall and upper parts of the Abu Soir temple, while dangerous cracks are detected on the Marina excavation tombs. The petrographic study of the oolitic limestone samples shows that they consist mainly of oolities and drusy sparite as a cement (oolitic grainstone). Some oolities have quartz grains as nuclei. Hydrochemical analysis shows that the total dissolved salts of extracted solutions of the North Coast quarry samples range from 539 to 686 ppm and dramatically increase (i.e., ten times) for extracted solutions from monument samples, ranging from 5395 to 6880 ppm. The dominant cation is sodium while the dominant anion is chlorine. Acid insoluble residue analysis shows that the carbonate content ranges from 89.2% to 96.4% for fresh samples from quarries and from 9.2% to 94.8% for weathered monument samples. The weight loss of the quarry oolitic limestone samples range from 30.7% to 32.7% and its physical and mechanical properties become worse after being subjected to 15 cycles of a durability simulation soundness test (using a sodium sulphate solution). Our main recommendations are to use suitable grouting for binding the cracks, high durability reconstruction rocks, and suitable cleaning methods to remove salts from the monuments.

Performance and application of a fluidized bed limestone reactor designed for control of alkalinity, hardness and pH at the Warm Springs Regional Fisheries Center

USDA-ARS?s Scientific Manuscript database

Springs serving the Warm Springs Regional Fisheries Center, Warm Springs, Georgia, have pH, alkalinity, and hardness levels that lie under the range required for successful fish propagation while free CO2 is well above allowable targets. We evaluate a pretreatment process that exploits limestone's (...

A new species of Isoperla (Insecta, Plecoptera) from the Karawanken, with considerations on the Southern Limestone Alps as centers of endemism.

PubMed

Graf, Wolfram; Konar, Martin; Murányi, Dávid; Orci, Kirill Márk; Vitecek, Simon

2014-01-01

A new species of the genus Isoperla (Plecoptera, Perlodidae), belonging to the oxylepis species-group is described, and the male mating call is characterized. Its range falls within a small region of the Southern Limestone Alps which is well known to be one endemism-centre of aquatic insects.

Seismic Velocities and Thicknesses of Alluvial Deposits along Baker Creek in the Great Basin National Park, East-Central Nevada

USGS Publications Warehouse

Allander, Kip K.; Berger, David L.

2009-01-01

To better understand how proposed large-scale water withdrawals in Snake Valley may affect the water resources and hydrologic processes in the Great Basin National Park, the National Park Service needs to have a better understanding of the relations between streamflow and groundwater flow through alluvium and karst topography of the Pole Canyon Limestone. Information that is critical to understanding these relations is the thickness of alluvial deposits that overlay the Pole Canyon Limestone. In mid-April 2009, the U.S. Geological Survey and National Park Service used seismic refraction along three profiles adjacent to Baker Creek to further refine understanding of the local geology. Two refractors and three distinct velocity layers were detected along two of the profiles and a single refractor and two distinct velocity layers were detected along a third profile. In the unsaturated alluvium, average velocity was 2,000 feet per second, thickness ranged from about 7 to 20 feet along two profiles downstream of the Narrows, and thickness was at least 100 feet along a single profile upstream of the Narrows. Saturated alluvium was only present downstream of the Narrows - average velocity was 4,400 feet per second, and thickness ranged from about 40 to 110 feet. The third layer probably represented Pole Canyon Limestone or Tertiary granitic rock units with an average velocity of 12,500 feet per second. Along the upstream and middle profiles (profiles 3 and 1, respectively), the depth to top of the third layer ranged from at least 60 to 110 feet below land surface and is most likely the Pole Canyon Limestone. The third layer at the farthest downstream profile (profile 2) may be a Tertiary granitic rock unit. Baker Creek is disconnected from the groundwater system along the upstream profile (profile 3) and streamflow losses infiltrate vertically downward to the Pole Canyon Limestone. Along the downstream and middle profiles (profiles 2 and 1, respectively), the presence of a shallow water table indicates that low permeability Tertiary granitic rock may extend across the Baker Creek Drainage intersecting the Pole Canyon Limestone. The Tertiary granitic rock may be acting as a barrier to groundwater flow within the Pole Canyon Limestone.

SHAWNEE LIME/LIMESTONE SCRUBBING COMPUTERIZED DESIGN/COST-ESTIMATE MODEL USERS MANUAL

EPA Science Inventory

The manual gives a general description of the Shawnee lime/limestone scrubbing computerized design/cost-estimate model and detailed procedures for using it. It describes all inputs and outputs, along with available options. The model, based on Shawnee Test Facility scrubbing data...

Lateral capacity of rock sockets in limestone under cyclic and repeated loading.

DOT National Transportation Integrated Search

2010-08-01

This report contains the results from full scale lateral load testing of two short rock socketed shafts in : limestone, and the development of recommendations for p-y analysis using those results. Two short shafts 42 : inches in diameter were constru...

A modified ASTM C1012 procedure for qualifying blended cements containing limestone and SCMs for use in sulfate-rich environments

DOE Office of Scientific and Technical Information (OSTI.GOV)

Barcelo, Laurent, E-mail: laurent.barcelo@lafarge.com; Lafarge Centre de Recherche, 95 rue du Montmurier, 38291 St Quentin Fallavier; Gartner, Ellis

2014-09-15

Blended Portland cements containing up to 15% limestone have recently been introduced into Canada and the USA. These cements were initially not allowed for use in sulfate environments but this restriction has been lifted in the Canadian cement specification, provided that the “limestone cement” includes sufficient SCM and that it passes a modified version of the CSA A3004-C8 (equivalent to ASTM C1012) test procedure run at a low temperature (5 °C). This new procedure is proposed as a means of predicting the risk of the thaumasite form of sulfate attack in concretes containing limestone cements. The goal of the presentmore » study was to better understand how this approach works both in practice and in theory. Results from three different laboratories utilizing the CSA A3004-C8 test procedure are compared and analyzed, while also taking into account the results of thermodynamic modeling and of thaumasite formation experiments conducted in dilute suspensions.« less

Prediction of Building Limestone Physical and Mechanical Properties by Means of Ultrasonic P-Wave Velocity

PubMed Central

Concu, Giovanna; De Nicolo, Barbara; Valdes, Monica

2014-01-01

The aim of this study was to evaluate ultrasonic P-wave velocity as a feature for predicting some physical and mechanical properties that describe the behavior of local building limestone. To this end, both ultrasonic testing and compressive tests were carried out on several limestone specimens and statistical correlation between ultrasonic velocity and density, compressive strength, and modulus of elasticity was studied. The effectiveness of ultrasonic velocity was evaluated by regression, with the aim of observing the coefficient of determination r 2 between ultrasonic velocity and the aforementioned parameters, and the mathematical expressions of the correlations were found and discussed. The strong relations that were established between ultrasonic velocity and limestone properties indicate that these parameters can be reasonably estimated by means of this nondestructive parameter. This may be of great value in a preliminary phase of the diagnosis and inspection of stone masonry conditions, especially when the possibility of sampling material cores is reduced. PMID:24511286

Prediction of building limestone physical and mechanical properties by means of ultrasonic P-wave velocity.

PubMed

Concu, Giovanna; De Nicolo, Barbara; Valdes, Monica

2014-01-01

The aim of this study was to evaluate ultrasonic P-wave velocity as a feature for predicting some physical and mechanical properties that describe the behavior of local building limestone. To this end, both ultrasonic testing and compressive tests were carried out on several limestone specimens and statistical correlation between ultrasonic velocity and density, compressive strength, and modulus of elasticity was studied. The effectiveness of ultrasonic velocity was evaluated by regression, with the aim of observing the coefficient of determination r(2) between ultrasonic velocity and the aforementioned parameters, and the mathematical expressions of the correlations were found and discussed. The strong relations that were established between ultrasonic velocity and limestone properties indicate that these parameters can be reasonably estimated by means of this nondestructive parameter. This may be of great value in a preliminary phase of the diagnosis and inspection of stone masonry conditions, especially when the possibility of sampling material cores is reduced.

The use of CTAB as an addition of DAP for improvement resisting acid rain on limestone

NASA Astrophysics Data System (ADS)

Xu, Feigao; Li, Dan

2017-11-01

The effect of hydroxyapatite (HA) formed by reacting limestone with mixture of diammonium hydrogen phosphate (DAP) and cetyltrimethylammonium bromide (CTAB) in the consolidation and protection of carbonate stones was investigated. Different concentration of CTAB was used in the experiments with mild condition in order to study how the CTAB affect the structure of HA. Moreover, the strengthening effect was evaluated with artificially limestone samples. The result of BET and XRD both showed that the structure of HA remained almost unchanged except its crystallinity was affected and specific surface area was decreased as the consequence of the addition of CTAB. A double application (as both coupling agent and consolidant) was also investigated, in which the samples were coated with DAP then followed by self-made product. The Scotch Tape test and hardness test both proved the cohesion between consolidant and limestone powder as well as its ability against acid rain were increased, which were ascribed to HA and CTAB.

Analysis and design of a calcium-based sulfur sorbent for applications in integrated gasification combined cycle energy systems

NASA Astrophysics Data System (ADS)

Hasler, David Johann Ludwig

The reactivity of various Ca-based sorbent materials in pelletized form with H2S or CO2 was investigated at high temperatures (750--880°C). An extensive study was conducted to compare the performance of sorbent pellets derived from plaster of Paris and limestone. Multicycle absorption and regeneration tests showed that plaster-based pellets out performed the limestone-based pellets primarily due to a higher surface area and mesoporosity. The effect of pore-modifiers on the reactivity of limestone with H 2S was investigated by incorporating additives such as cornstarch, graphite and polyvinylalcohol (PVA) in the sorbent. Multicycle sulfidation and regeneration tests of the modified sorbent showed that starch did not improve the reactivity of the limestone, graphite reduced the reactivity, while PVA improved it. The effect of the chemical additives MgO and SrO on the performance of CaO-based sorbent pellets was investigated. The effect of MgO was tested by starting with materials that contained MgCO3 in a natural form, such as dolomite. The effect of SrO was tested by starting with SrCO 3 either co-precipitated with CaCO3 or by wet-mixing SrCO 3 with limestone in slurry form. The MgO was found to improve the thermal stability of the CaO-based sorbent but lowered the overall absorption capacity of the material when reacted with CO2 or H2S, while SrO decreased the thermal stability of the sorbent when it was reacted with CO2; no absorption tests were run with H2S. A study of the performance of pelletized CaO-based cores coated with a refractory material such as alumina and limestone or alumina and kaolin was conducted. The reactivity of the core and shell pellets with H2S was determined. The strength and durability of the pellets were determined by using crushing strength analysis and abrasion resistance tests. Pellets coated with either alumina and limestone or alumina and kaolin proved to be strong and adequate for use in industrial reactors. A semi-empirical mathematical model was developed to represent the reaction of H2S with a sorbent pellet. The model was based on the well-known shrinking core model and it was applied successfully for the analysis of both pellet cores and core and shell pellets reacting with H2S.

Product layer development during sulfation and sulfidation of uncalcined limestone particles at elevated pressures

DOE Office of Scientific and Technical Information (OSTI.GOV)

Zevenhoven, C.A.P.; Yrjas, K.P.; Hupa, M.M.

1998-07-01

Fluidized bed combustion or gasification allows for in-bed sulfur capture with a calcium-based sorbent such as limestone or dolomite. Sorbent particle size, porosity, internal surface, and their variation during conversion have great influence on the conversion of the sorbent. The uptake of SO{sub 2} and H{sub 2}S by five physically different limestones is discussed, for typical pressurized fluidized bed combustor or gasifier conditions: 850/950 C, 15/20 bar. Tests were done in a pressurized thermogravimetric apparatus (P-TGA), the size of the limestone particles was 250--300 {micro}m. It is stressed that the limestones remain uncalcined. A changing internal structure (CIS) model ismore » presented in which reaction kinetics and product layer diffusion are related to the intraparticle surface of reaction, instead of the outer particle surface as in unreacted shrinking core (USC)-type models. The random pore model was used for describing the changing internal pore and reaction surfaces. Rate parameters were extracted for all five limestones using the CIS model and a USC model with variable effective diffusivity. Differences in the sulfur capture performance of the limestones were evaluated. Plots of the CaSO{sub 4} or CaS product layer thickness as a function of conversion are given, and the relative importance of limestone porosity and internal surface is discussed.« less

Abandoned mine drainage in the Swatara Creek Basin, southern anthracite coalfield, Pennsylvania, USA: 2. performance of treatment systems

USGS Publications Warehouse

Cravotta, Charles A.

2010-01-01

A variety of passive and semi-passive treatment systems were constructed by state and local agencies to neutralize acidic mine drainage (AMD) and reduce the transport of dissolved metals in the upper Swatara Creek Basin in the Southern Anthracite Coalfield in eastern Pennsylvania. To evaluate the effectiveness of selected treatment systems installed during 1995–2001, the US Geological Survey collected water-quality data at upstream and downstream locations relative to each system eight or more times annually for a minimum of 3 years at each site during 1996–2007. Performance was normalized among treatment types by dividing the acid load removed by the size of the treatment system. For the limestone sand, open limestone channel, oxic limestone drain, anoxic limestone drain (ALD), and limestone diversion well treatment systems, the size was indicated by the total mass of limestone; for the aerobic wetland systems, the size was indicated by the total surface area of ponds and wetlands. Additionally, the approximate cost per tonne of acid treated over an assumed service life of 20 years was computed. On the basis of these performance metrics, the limestone sand, ALD, oxic limestone drain, and limestone diversion wells had similar ranges of acid-removal efficiency and cost efficiency. However, the open limestone channel had lower removal efficiency and higher cost per ton of acid treated. The wetlands effectively attenuated metals transport but were relatively expensive considering metrics that evaluated acid removal and cost efficiency. Although the water-quality data indicated that all treatments reduced the acidity load from AMD, the ALD was most effective at producing near-neutral pH and attenuating acidity and dissolved metals. The diversion wells were effective at removing acidity and increasing pH of downstream water and exhibited unique potential to treat moderate to high flows associated with storm flow conditions.

Spectroscopic characterization of natural calcite minerals.

PubMed

Gunasekaran, S; Anbalagan, G

2007-11-01

The FT-IR, FT-Raman, NMR spectral data of ten different limestone samples have been compared. FT-IR and FT-Raman spectral data show that calcium carbonate in limestone, principally in the form of calcite, as identified by its main absorption bands at 1426, 1092, 876 and 712 cm(-1). The sharp diffractions at the d-spacings, 3.0348, 1.9166 and 1.8796 confirm the presence of calcite structure and the calculated lattice parameters are: a=4.9781 A, c=17.1188 A. The range of 13C chemical shifts for different limestone samples is very small, varying from 198.38 to 198.42 ppm. The observed chemical shifts are consistent with the identical C-O bonding in different limestone samples. 27Al MAS NMR spectra of the samples exhibit a central line at 1 ppm and another line at 60 ppm corresponding to octahedral and tetrahedral Al ions, respectively. The five component resonances were observed in 29Si MAS NMR spectrum of limestone and these resonances were assigned to Si (4 Al), Si (3 Al), Si (2 Al), Si (1 Al) and Si (0 Al) from low field to high field.

MX Siting Investigation. Geotechnical Evaluation. Verification Study - Pahroc Valley, Nevada. Volume I. Synthesis.

DTIC Science & Technology

1981-06-30

Range both consist of Paleozoic limestone and dolomite overlain by Tertiary ash-flow tuffs and undiffer- entiated volcanic rocks. The central portion...andesite, detrital material, volcanic tuff, pumice). FAULT - A plane or zone of fracture along which there has been * I displacement. FAULT BLOCK...D2850-70). To conduct the test, a cylindrical specimen of soil is surrounded by a fluid in a pressure chamber and subjected to an isotropic pressure . An

MX Siting Investigation. Water Resources Program Progress Report.

DTIC Science & Technology

1981-02-13

avoided. o Limestones and dolomites (carbonates) of Devonian age appear to be the major regional aquifers which hydrologically con- nect many valleys...that of the aquifer itself. Carbonate Aquifer. A aquifer, contained in limestone or dolomite rock, which occurs beneath the unconsolidated valley-fill...sediments and in the mountain ranges. Flow is believed to be primarily through fracture and solution openings rather than through normal inter

A new species of Isoperla (Insecta, Plecoptera) from the Karawanken, with considerations on the Southern Limestone Alps as centers of endemism

PubMed Central

Graf, Wolfram; Konar, Martin; Murányi, Dávid; Orci, Kirill Márk; Vitecek, Simon

2014-01-01

Abstract A new species of the genus Isoperla (Plecoptera, Perlodidae), belonging to the oxylepis species-group is described, and the male mating call is characterized. Its range falls within a small region of the Southern Limestone Alps which is well known to be one endemism-centre of aquatic insects. PMID:25408608

Flue gas desulfurization chemistry studies: limestone grindability. Volume 1. FGD reagent mapping. Final report

DOE Office of Scientific and Technical Information (OSTI.GOV)

Richmann, D.L.; Rossi, J.P.; Rashin, E.B.

1984-07-01

The major objective of this project is to provide electric utilities with information concerning the availability of flue gas desulfurization (FGD) system reagents. Data presented in this report were obtained primarily from a comprehensive review of available literature. These were augmented by information gathered through interviews with knowledgeable individuals from industry, government, and academic institutions. Limestone data are presented on regional and state maps displaying, respectively, annual limestone production and number of active quarries by county; and areas most likely to contain potentially commercial deposits of high-Ca (greater than or equal to 90% CaCO/sub 3/) limestone. Lime data are presentedmore » on regional maps indicating ranges of annual production and number of active lime plants by county. Identification of commercial versus captive operations and estimates of lime availability on the open market are summarized in tables accompanying each map.« less

Microfacies and diagenesis of the reefal limestone, Callovian Tuwaiq Mountain Limestone Formation, central Saudi Arabia

NASA Astrophysics Data System (ADS)

EL-Sorogy, Abdelbaset S.; Almadani, Sattam A.; Al-Dabbagh, Mohammad E.

2016-03-01

In order to document the microfacies and diagenesis of the reefal limestone in the uppermost part of the Callovian Tuwaiq Mountain Limestone Formation at Khashm Al-Qaddiyah area, central Saudi Arabia, scleractinian corals and rock samples were collected and thin sections were prepared. Coral framestone, coral floatstone, pelloidal packstone, bioclastic packstone, bioclastic wacke/packstone, algal wackestone and bioclastic foraminiferal wacke/packstone were the recorded microfacies types. Cementation, recrystallization, silicification and dolomitization are the main diagenetic alterations affected the aragonitic skeletons of scleractinian corals. All coral skeletons were recrystallized, while some ones were dolomitized and silicified. Microfacies types, as well as the fossil content of sclearctinian corals, bivalves, gastropods, brachiopods and foraminifera indicated a deposition in environments ranging from shelf lagoon with open circulation in quiet water below wave base to shallow reef flank and organic build up for the uppermost reefal part of the Tuwaiq Formation in the study area.

Assessment of characteristics and remedial alternatives for abandoned mine drainage : case study at Staple Bend Tunnel unit of Allegheny Portage Railroad National Historic Site, Cambria County, Pennsylvania, 2004

USGS Publications Warehouse

Cravotta, Charles A.

2005-01-01

This report describes field, laboratory, and computational methods that could be used to assess remedial strategies for abandoned mine drainage (AMD). During April-June, 2004, the assessment process was applied to AMD from bituminous coal deposits at a test site in the Staple Bend Tunnel Unit of Allegheny Portage Railroad National Historic Site (ALPO-SBTU) in Cambria County, Pennsylvania. The purpose of this study was (1) to characterize the AMD quantity and quality within the ALPO-SBTU test site; (2) to evaluate the efficacy of limestone or steel slag for neutralization of the AMD on the basis of reaction-rate measurements; and (3) to identify possible alternatives for passive or active treatment of the AMD. The data from this case study ultimately will be used by the National Park Service (NPS) to develop a site remediation plan. The approach used in this study could be applicable at other sites subject to drainage from abandoned coal or metal mines.During April 2004, AMD from 9 sources (sites1, 1Fe, Fe, 2, 3, 3B, 5, 6, and 7) at the ALPO-SBTU test site had a combined flow rate of 1,420 gallons per minute (gal/min) and flow-weighted averages for pH of 3.3, net acidity of 55 milligrams per liter (mg/L) as CaCO3, and concentrations of dissolved sulfate, aluminum, iron, and manganese of 694 mg/L, 4.4 mg/L, 0.74 mg/L, and 1.2 mg/L, respectively. These pH, net acidity, sulfate, and aluminum values exceed effluent criteria for active mines in Pennsylvania.During April-June 2004, limestone and steel slag that were locally available were tested in the laboratory for their composition, approximate surface area, and potential to neutralize samples of the AMD. Although the substrates had a similar particle-size distribution and identical calcium content (43 percent as calcium oxide), the limestone was composed of crystalline carbonates and the slag was composed of silicate glass and minerals. After a minimum of 8 hours contact between the AMD and limestone or steel slag in closed containers (cubitainers), near-neutral effluent was produced. With prolonged contact between the AMD and limestone or steel slag, the concentrations of iron, aluminum, and most dissolved trace elements in effluent from the cubitainers declined while pH was maintained greater than 6.0 and less than 9.0. The cubitainer testing demonstrated (1) lower alkalinity production but higher pH of AMD treated with steel slag compared to limestone, and (2) predictable relations between the effluent quality, detention time, and corresponding flow rate and bulk volume for a bed of crushed limestone or steel slag in an AMD passive-treatment system.The process for evaluating AMD remedial strategies at the ALPO-SBTU test site involved the computation and ranking of the metal loadings during April 2004 for each of the AMD sources and a comparison of the data on AMD flow and chemistry (alkalinity, acidity, dissolved oxygen, ferric iron, aluminum) with published criteria for selection of passive-treatment technology. Although neutralization of the AMD by reaction with limestone was demonstrated with cubitainer tests, an anoxic limestone drain (ALD) was indicated as inappropriate for any AMD source at the test site because all had excessive concentrations of dissolved oxygen and (or) aluminum. One passive-treatment scenario that was identified for the individual or combined AMD sources involved an open limestone channel (OLC) to collect the AMD source(s), a vertical flow compost wetland (VFCW) to add alkalinity, and an aerobic wetland to facilitate iron and manganese oxidation and retention of precipitated solids. Innovative passive-system designs that direct flow upward through submerged layers of limestone and/or steel slag and that incorporate siphons for automatic flushing of solids to a pond also may warrant consideration. Alternatively, an active-treatment system with a hydraulic-powered lime doser could be employed instead of the VFCW or upflow system. Now, given these data on AMD flow and chemistry and identified remedial technologies, a resource manager can use a publicly available computer program such as "AMDTreat" to evaluate the potential sizes and costs of various remedial alternatives.

Modelling mechanical behaviour of limestone under reservoir conditions

NASA Astrophysics Data System (ADS)

Carvalho Coelho, Lúcia; Soares, Antonio Claudio; Ebecken, Nelson Francisco F.; Drummond Alves, José Luis; Landau, Luiz

2006-12-01

High porosity and low permeability limestone has presented pore collapse. As fluid is withdrawn from these reservoirs, the effective stresses acting on the rock increase. If the strength of the rock is overcome, pore collapse may occur, leading to irreversible compaction of porous media with permeability and porosity reduction. It impacts on fluid withdrawal. Most of reservoirs have been discovered in weak formations, which are susceptible to this phenomenon. This work presents a study on the mechanical behaviour of a porous limestone from a reservoir located in Campos Basin, offshore Brazil. An experimental program was undergone in order to define its elastic plastic behaviour. The tests reproduced the loading path conditions expected in a reservoir under production. Parameters of the cap model were fitted to these tests and numerical simulations were run. The numerical simulations presented a good agreement with the experimental tests. Copyright

Diagenetic evolution and stable isotopes of Lower Permian platform marginal carbonates (Trogkofel Limestone, Carnic Alps, Austria)

NASA Astrophysics Data System (ADS)

Schaffhauser, Maria; Krainer, Karl; Sanders, Diethard Gerald; Spötl, Christoph

2010-05-01

The Trogkofel massif in the Carnic Alps, Austria/Italy, consists of a succession up to 400 m thick of limestones deposited along a platform margin (Trogkofel Limestone; Artinskian). The top of the Trogkofel Limestone is erosively overlain by the Tarvis Breccia. Up-section, the Trogkofel Limestone consists of well-bedded shallow-water bioclastic limestones with intercalated mud mounds, overlain by thick-bedded to unbedded limestones (bioclastic grainstones, packstones, rudstones) and cementstone mounds rich in phylloid algae, Tubiphytes, bryozoans and Archaeolithoporella. In the cementstone mounds, bioclasts are coated by thick fringes and botryoids of fibrous calcite, and of calcite spar that probably represents calcitized aragonite. Primary and intrinsic pores are filled by microbialite, and/or by mudstone to bioclastic wackestone. Shallow-water bioclastic grainstones are cemented by isopachous fringes of fibrous calcite, or by sparry calcite. Throughout the succession, evidence for meteoric-vadose dissolution is present. The Trogkofel Limestone is riddled by palaeokarstic dykes and caverns filled by (a) isopachous cement fringes up to a few decimetres thick, and/or (b) by red, geopetally-laminated lime mudstone to bio-lithoclastic wackestone; geopetal laminasets locally display convolute bedding. Small dissolution cavities are filled by grey internal sediment, or by crystal silt. Brecciated internal sediments overlain by unbrecciated, geopetally-laminated infillings record deformation during or after deposition of the Trogkofel Limestone. Polyphase fractures cemented by calcite may cross-cut both internal sediments and host rock. In the Trogkofel Limestone, local dolomitization is common. Replacement dolomites show a wide range of shapes and fabrics, including: (a) fine-crystalline anhedral xenotopic fabric, (b) coarse-crystalline subhedral to euhedral, hypidiotopic to idiotopic fabric of turbid or optically zoned crystals, and (c) saddle dolomite as replacement and filling of fractures. Closely below the erosional surface at the top of the Trogkofel Limestone, the dolomite is characterized by vuggy porosity. The Tarvis Breccia, which represents coarse alluvial fan deposits, in turn, is thick-bedded, poorly sorted, typically clast-supported, and consists of angular lithoclasts embedded in a matrix of former lime mudstone. Both, matrix as well as lithoclasts, are dolomitized. Various types of cement (isopachous, botryoidal, microbialite, calcite spar), karstic cavity fills (isopachous cements, internal sediments), and replacement dolomites of the Trogkofel section, as well as of the Tarvis Breccia were analysed for their stable isotopic composition. δ18O and δ13C data produced so far allow to differentiate between replacement dolomites and saddle dolomite of the Trogkofel Limestone and the Tarvis Breccia. Saddle dolomite shows the most depleted oxygen isotope values, suggesting formation during relatively high temperatures. Carbon isotope values are invariably positive in all dolomite types indicating lacking influence of organic diagenesis on the alkalinity of the deep-burial pore water. Matrix dolomite from the Tarvis Breccia shows slightly positive δ18O values. Calcite cements show a wide range in δ18O values (ca. -1 to -7 permil VPDB), which overlaps the composition of unaltered brachiopod shells (ca. -3 permil VPDB). Oxygen isotope values of calcite cements reveal a trend towards depleted δ18O values. This trend is reflecting most likely increasing temperature.

Water-resources reconnaissance of Isle de la Gonave, Haiti

USGS Publications Warehouse

Troester, J.W.; Turvey, M.D.

2004-01-01

Isle de la Gonave is a 750-km2 island off the coast of Haiti. The depth to the water table ranges from less than 30 m in the Eocene and Upper Miocene limestones to over 60 m in the 300-m-thick Quaternary limestone. Annual precipitation ranges from 800-1,400 mm. Most precipitation is lost through evapotranspiration and there is virtually no surface water. Roughly estimated from chloride mass balance, about 4% of the precipitation recharges the karst aquifer. Cave pools and springs are a common source for water. Hand-dug wells provide water in coastal areas. Few productive wells have been drilled deeper than 60 m. Reconnaissance field analyses indicate that groundwater in the interior is a calcium-bicarbonate type, whereas water at the coast is a sodium-chloride type that exceeds World Health Organization recommended values for sodium and chloride. Tests for the presence of hydrogen sulfide-producing bacteria were negative in most drilled wells, but positive in cave pools, hand-dug wells, and most springs, indicating bacterial contamination of most water sources. Because of the difficulties in obtaining freshwater, the 110,000 inhabitants use an average of only 7 L per person per day.

Attrition of limestone by impact loading in fluidized beds

DOE Office of Scientific and Technical Information (OSTI.GOV)

Fabrizio Scala; Fabio Montagnaro; Piero Salatino

2007-09-15

The present study addresses limestone attrition and fragmentation associated with impact loading, a process which may occur extensively in various regions of fluidized bed (FB) combustors/gasifiers, primarily the jetting region of the bottom bed, the exit region of the riser, and the cyclone. An experimental protocol for the characterization of the propensity of limestone to undergo attrition/fragmentation by impact loading is reported. The application of the protocol is demonstrated with reference to an Italian limestone whose primary fragmentation and attrition by surface wear have already been characterized in previous studies. The experimental procedure is based on the characterization of themore » amount and particle size distribution of the debris generated upon the impact of samples of sorbent particles against a target. Experiments were carried out at a range of particle impact velocities between 10 and 45 m/s, consistent with jet velocities corresponding to typical pressure drops across FB gas distributors. The protocol has been applied to either raw or preprocessed limestone samples. In particular, the effect of calcination, sulfation, and calcination/recarbonation cycles on the impact damage suffered by sorbent particles has been assessed. The measurement of particle voidage and pore size distribution by mercury intrusion was also accomplished to correlate fragmentation with the structural properties of the sorbent samples. Fragmentation by impact loading of the limestone is significant. Lime displays the largest propensity to undergo impact damage, followed by the sorbent sulfated to exhaustion, the recarbonated sorbent, and the raw limestone. Fragmentation of the raw limestone and of the sulfated lime follows a pattern typical of the failure of brittle materials. The fragmentation behavior of lime and recarbonated lime better conforms to a disintegration failure mode, with an extensive generation of very fine fragments. 27 refs., 9 figs. 1 tab.« less

Performance of portland limestone cements: Cements designed to be more sustainable that include up to 15% limestone addition

NASA Astrophysics Data System (ADS)

Barrett, Timothy J.

In 2009, ASTM and AASHTO permitted the use of up to 5% interground limestone in ordinary portland cement (OPC) as a part of a change to ASTM C150/AASHTO M85. When this work was initiated a new proposal was being discussed that would enable up to 15% interground limestone cement to be considered in ASTM C595/AASHTO M234. This work served to provide rapid feedback to the state department of transportation and concrete industry for use in discussions regarding these specifications. Since the time this work was initiated, ASTM C595/AASHTO M234 was passed (2012c) and PLCs are now able to be specified, however they are still not widely used. The proposal for increasing the volume of limestone that would be permitted to be interground in cement is designed to enable more sustainable construction, which may significantly reduce the CO2 that is embodied in the built infrastructure while also extending the life of cement quarries. Research regarding the performance of cements with interground limestone has been conducted by the cement industry since these cements became widely used in Europe over three decades ago, however this work focuses on North American Portland Limestone Cements (PLCs) which are specifically designed to achieve similar performance as the OPCs they replace.This thesis presents a two-phase study in which the potential for application of cements containing limestone was assessed. The first phase of this study utilized a fundamental approach to determine whether cement with up to 15% of interground or blended limestone can be used as a direct substitute to ordinary portland cement. The second phase of the study assessed the concern of early age shrinkage and cracking potential when using PLCs, as these cements are typically ground finer than their OPC counterparts. For the first phase of the study, three commercially produced PLCs were obtained and compared to three commercially produced OPCs made from the same clinker. An additional cement was tested where the limestone was blended (i.e., not interground) as needed, enabling variation of the size of the limestone particles. In addition, one of the commercially produced OPCs and PLCs were used with fly ash. A series of standardized tests were run to assess the physical effects of intergrinding limestone in portland cement, the effect of limestone presence and method of inclusion on the hydration reaction, and the associated mechanical and transport properties of concretes made with these limestone cements. The second phase of the study used a commercially produced OPC, a PLC, and a PLC-slag all made from the same parent clinker to quantify the early age shrinkage and cracking potential. The study presents a series of tests that quantify the fundamental origins of shrinkage in cementitious materials to elucidate the differences between PLC and OPC. The bulk shrinkage of these systems is then quantified under free and restrained conditions to provide an assessment of the susceptibility for cracking in portland limestone cements. The results of the first phase of this thesis showed that in general the PLC and OPC systems have similar hydration, set, and mechanical performance. Transport properties in this study show behavior that is +/- 30% of the conventional OPC system depending on the system. Literature has shown similar freeze-thaw resistance when these materials are used in properly air entrained mixtures, and the results for PLC systems with fly ash show added performance. Based on these results it appears that PLC that meets ASTM C595/AASHTO M234 should be able to be used interchangeably with OPC, while it should also be noted that the investigation of the influence of salts and sulfates on PLCs is still ongoing and should be monitored. The results of the second phase of this thesis showed that while the PLCs are finer, this comes primarily by reducing the very large particles (clinker particles greater than 30 microns) using advanced separator technology and increasing the number of very fine limestone particles. This results in the cements tested having similar autogenous shrinkage development in the PLC systems compared to the OPC, with slightly less shrinkage in the PLC-slag system. The stress that develops when this shrinkage is restrained is very similar in comparing the OPC, PLC and PLC-slag systems and the PLC mixture tends to crack at a similar or slightly earlier times.

Geology and ore deposits of the Pioche district, Nevada

USGS Publications Warehouse

Westgate, L.G.; Knopf, Adolph

1932-01-01

LOCATION AND SURFACE FEATURES The Bristol Range, Highland, and Ely Range quadrangles make up the larger part of a. rectangular area 35 miles north and south by 24 miles east and west, which lies 19 miles west of the Nevada-Utah line and about 250 miles southwest of Salt Lake City. The district lies within the Great Basin, a semiarid region of alternating mountain ranges and intermontane plains floored largely by outwash from the mountains. The plain, which slopes away from the ranges, stands between 4,700 and 6,000 feet above the sea. The Bristol and Highland Ranges, which are separated only by a low gap, form an almost continuous north-south range that rises about 2,500 feet above the highest part of the surrounding plain, to general altitudes of 8,000 to 9,000 feet, though the highest point, Highland Peak, reaches 9,395 feet. A lower range, the Ely Range, with a northwesterly trend, lies farther east and nearly in touch with the Bristol-Highland Range. The town of Pioche lies midway on the. eastern foot of the Ely Range. ROOKS OF THE PIOOHB REGION The rocks of the ranges are Paleozoic sediments, Tertiary (?) lavas and intrusive rocks, and Pliocene (?) tuffs. The Paleozoic sediments have a total thickness of nearly 18,000 feet. Over 8,000 feet of the Cambrian has been measured without reaching its base. The lowest Cambrian formation is a quartzite, of which only the upper 1,500 feet is exposed, and this is followed by 1,200 feet of shale, 400 feet of limestone, aoid 150 feet of shale. Above this second shale the upper three-fourths of the Cambrian consists of limestone and dolomitic limestone. It is in the quartzite and in the limestone interbedded in and bounding the shales that the main ore bodies of the district have been found. Above the Cambrian comes 1,795 feet of Ordovician limestone, with some interbedded dolomite and with a 50-foot quartzite a, third of the way down from the top; 75 feet of Silurian dolomite; 3,000 feet of Middle Devonian dolomite with thin interbedded quartzite near the top, followed by 550 feet of Upper Devonian limestone; 3,775 feet of Mississippian limestone with a heavy quartzitic sandstone just below the middle; then, at the top of the series, 700 feet of Pennsylvania n limestone.The Paleozoic formations are tilted, bent, and faulted, but sharp folding is extremely rare. Dips between 10° and 30° are common, but there are few greater than 40°. The rocks are cut by many large and innumerable small normal faults, which in many parts of the area are difficult to recognize because they cut thick formations of similar rocks. A large thrust fault occurs along the west side of the Bristol-Highland Range. A thick series of lavas with interbedded tuffs lies along the flanks of the ranges and makes up a large part of the hilly northwest corner of the Bristol quadrangle. The lavas lie unconformably on the Paleozoic sediments and consist mainly of dacite, latite, and andesite, with some basalt and a little rhyolite. About 6,000 feet of lavas and tuffs were measured in Condor Canyon, near the south end of the Ely Range. The age of the lavas is not sharply fixed; they may be early Tertiary or even late Mesozoic. It is not unlikely that they are the result of volcanic action extending over a long period. The lavas are tilted and faulted, though their average dip is less than that of the Paleozoic sediments. At Blind Mountain, on the west side of the Bristol Range, stocks of quartz monzonite and dikes of similar composition cut an infaulted block consisting of sediments, chiefly Devonian, and lavas. Both the sediments and the lavas are metamorphosed, and a belt of marked metamorphism extends south along the west base of the Bristol-Highland Range for several miles. The quartz porphyry dikes of the region, including those near Pioche, are believed to have come in at the same time. The plain west of the Bristol-Highland Range is a. valley of interior drainage floored with outwash from the mountains, coarser near the range but finer and making a clay flat along the west side of the Bristol Range and Highland quadrangles. The valley east of the Bristol-Highland Range, however, has outside drainage by way of Meadow Valley to the Virgin and Colorado Rivers. The stream in upper Meadow Valley and its tributaries have cut through the surface wash from the mountains and laid bare several hundred feet of white, yellow, and red water-laid Pliocene tuffs that lie in nearly the position in which they were laid down. This erosion has developed a striking badland topography in the Pliocene beds. HISTORICAL SUMMARY The general succession of events may be summarized as follows: 1. Sedimentation during most of Paleozoic time from Cambrian to Pennsylvanian. 2. Uplift, slight warping, and erosion. 3. Volcanism of perhaps late Mesozoic or early Tertiary time, producing lavas and tuffs. This period of volcanism may have lasted a long time and spanned one or more of the epochs of faulting. 4. Tilting and normal faulting. 5. Thrust faulting. 6. Quartz monzonite intrusions at Blind Mountain. 7. Normal block faulting of the Basin Range type. 8. Erosion of the faulted blocks to maturity and to essen-. tially the topography of to-day. 9. Outbursts of volcanic ash, probably in late Pliocene time, and the deposition of several hundred feet of water-laid tuffs in the valleys. 10. In Meadow Valley, valley cutting, which has produced a badland topography in the soft Pliocene tuffs and canyons where the streams cross the harder Paleozoic limestones. ECONOMIC GEOLOGY The Pioche district during four years in the early seventies was second only to the Comstock district in output of silver. The bonanza ore of those stirring times came from fissure veins in the Prospect Mountain quartzite, of Lower Cambrian age. In recent years the main interest has shifted to the bedded replacement deposits of silver-bearing lead-zinc sulphide ore occurring in the limestone members of the Pioche shale a type of ore body which was discovered accidentally during the prospecting of the fissure veins. The ore deposits of the district comprise three groups (1) silver-bearing fissure veins in quartzite; (2) silver-bearing mineralized granite porphyry; (3) replacement deposits in limestone and dolomite. All of them appear to have been formed at about the same time, in the epoch of mineralization that occurred shortly after the intrusion of the granitic rocks and their allied dikes of granite porphyry and lamprophyre. The entire present output of the district is coming from the replacement deposits in limestone and dolomite, but exploratory work is still in progress on the fissure veins and mineralized porphyry. The replacement deposits include both replacement fissure veins and stratiform ("bedded") replacement deposits. The replacement fissure veins dip steeply and cut across the bedding of the carbonate rocks in which they are inclosed. They are thoroughly oxidized, as deep at least as 1,100 feet, for on none of them have the mine workings penetrated to water level, and they are highly manganiferous and limonitic and low in silica. At-certain horizons stratiform replacement deposits extend out as lateral branches from the fissure veins. Deposits of this kind occur mainly in the Mendha limestone, Highland Peak limestone, and Lyndon limestone. The stratigraphic range is therefore at least 5,500 feet, and as some of the fissure veins extend down through the underlying Pioche shale the indicated range may exceed 6,500 feet. The most notable representatives of the replacement fissure veins are at the Bristol mine, where they yield silver-bearing copper-leadzinc ores. So far unique among the ore bodies of the district is the pipe of wad and pyrolusite ore at the Jackrabbit mine, the periphery of the pipe consisting of a girdle of extraordinarily coarse white calcite spar produced by the recrystallization of the surrounding limestones. The stratiform replacement deposits that are attracting most attention occur at the intersections of steep fissures with the limestone members of the Pioche shale. In recent years the " bedded " ore of the Combined Metals mine has been of main interest. The ore is essentially a.n intimate intergrowth of pyrite, sphalerite, and galena. Although above water level, the ore is unoxidized. It extends on both sides of the mineralizing fissure as far as 100 feet. At the Prince mine ore beds were formed at seven successively higher horizons in the Pioche shale and the overlying Lyndon and Highland Peak limestones. The ore " beds " above water level in the Prince mine are thoroughly oxidized and consist of manganese-iron oxides low in silver, lead, and zinc. About 800,000 tons of ore carrying 2.5 to 3 ounces of silver to the ton, 3 per cent of lead, 35 per cent of iron, and 15 per cent of manganese has been shipped. The Prince mine was in 1915-1918 the premier producer of lead in Nevada. The ore " bed " that occurs here below water level consists of sphalerite, galena, and pyrite in a gangue of manganosiderite and minor quartz. This is the only locality in the district in which the primary source of the abundant oxidized manganese minerals (wad, pyrolusite, and braunite) has so far been found. Some of the stratiform ore bodies the ore beds, as they are locally called were formed adjacent to exceedingly insignificant-looking fissures; and this dependence on inconspicuous mineralizing fissures is beyond doubt one of the most impressive features in the geology of the district. It opens the possibility that there may be many other bedded deposits which, like the Combined Metals ore bed, do not crop out. To find these ore bodies will be difficult, but their discovery will be aided primarily by applying skillfully a knowledge of the geologic column and by determining the faulting that has disturbed or changed the normal sequence of the strata.

Geochemistry, environmental and provenance study of the Middle Miocene Leitha limestones (Central Paratethys)

NASA Astrophysics Data System (ADS)

Ali, Ahmed; Wagreich, Michael

2017-06-01

Mineralogical, major, minor, REE and trace element analyses of rock samples were performed on Middle Miocene limestones (Leitha limestones, Badenian) collected from four localities from Austria (Mannersdorf, Wöllersdorf, Kummer and Rosenberg quarries) and the Fertőrákos quarry in Hungary. Impure to pure limestones (i.e. limited by Al2O3 contents above or below 0.43 wt. %) were tested to evaluate the applicability of various geochemical proxies and indices in regard to provenance and palaeoenvironmental interpretations. Pure and impure limestones from Mannersdorf and Wöllersdorf (southern Vienna Basin) show signs of detrital input (REEs = 27.6 ± 9.8 ppm, Ce anomaly = 0.95 ± 0.1 and the presence of quartz, muscovite and clay minerals in impure limestones) and diagenetic influence (low contents of, e.g., Sr = 221 ± 49 ppm, Na is not detected, Ba = 15.6 ± 8.8 ppm in pure limestones). Thus, in both limestones the reconstruction of original sedimentary palaeoenvironments by geochemistry is hampered. The Kummer and Fertőrákos (Eisenstadt-Sopron Basin) comprise pure limestones (e.g., averages Sr = 571 ± 139 ppm, Na = 213 ± 56 ppm, Ba = 21 ± 4 ppm, REEs = 16 ± 3 ppm and Ce anomaly = 0.62 ± 0.05 and composed predominantly of calcite) exhibiting negligible diagenesis. Deposition under a shallow-water, well oxygenated to intermittent dysoxic marine environment can be reconstructed. Pure to impure limestones at Rosenberg-Retznei (Styrian Basin) are affected to some extent by detrital input and volcano-siliciclastic admixture. The Leitha limestones at Rosenberg have the least diagenetic influence among the studied localities (i.e. averages Sr = 1271 ± 261 ppm, Na = 315 ± 195 ppm, Ba = 32 ± 15 ppm, REEs = 9.8 ± 4.2 ppm and Ce anomaly = 0.77 ± 0.1 and consist of calcite, minor dolomite and quartz). The siliciclastic sources are characterized by immobile elemental ratios (i.e. La/Sc and Th/Co) which apply not only for the siliciclastics, but also for marls and impure limestones. At Mannersdorf the detrital input source varies between intermediate to silicic igneous rocks, while in Kummer and Rosenberg the source is solely silicic igneous rocks. The Chemical Index of Alteration (CIA) is only applicable in the shale-contaminated impure limestones. CIA values of the Leitha limestones from Mannersdorf indicate a gradual transition from warm to temperate palaeoclimate within the limestone succession of the Badenian.

Distribution of end bearing, tip shear and rotation on drilled shafts with combined loading in Florida limestone : final report, May 2008.

DOT National Transportation Integrated Search

2008-05-01

The study investigated the behavior of large diameter drilled shafts embedded short distances in Florida Limestone (i.e. L/D=1 &3). The work was performed via laboratory (centrifuge) tests and at two field sites (17th Street and Fuller Warren Bridges...

DOE Office of Scientific and Technical Information (OSTI.GOV)

Rao, S.M.; Brinkar, C.J.; Rao, S.M.

We are testing an anti-weathering preservation strategy that is specific to limestone surfaces. The strategy involves the application of a mineral-specific, bifunctional, passivating/coupling agent that binds to both the limestone surface and to the consolidating inorganic polymer matrix. The sol-gel based reactions form composite materials with desirable conservation and anti-weathering properties. We present the results of our efforts, the highlights of which are: (1) scanning probe microscopy of moisture-free calcite crystals treated with the trisilanol form of silylalkylaminocarboxylate (SAAC), reveals porous agglomerates that offer no significant resistance to the mild leaching action of deionized water. When the crystals are furthermore » consolidated with a silica-based consolidant (A2**), no dissolution is seen although the positive role of the passivant molecule is not yet delineated. (2) Modulus of rupture tests on limestone cores treated with an aminoalkylsilane (AEAPS) and A2** showed a 25-35% increase in strength compared to the untreated samples. (3) Environmental scanning electron microscopy of treated limestone subjected to a concentrated acid attack showed degradation of the surface except in areas where thick layers of the consolidant were deposited.« less

Summary of hydrologic testing in Tertiary limestone aquifer, Tenneco offshore exploratory well--Atlantic OCS, lease-block 427 (Jacksonville NH 17-5)

USGS Publications Warehouse

Johnston, Richard H.; Bush, Peter W.; Krause, Richard E.; Miller, James A.; Sprinkle, Craig L.

1982-01-01

A summary of hydrologic testing in an offshore oil-test well (LB427) drilled for Tenneco, Inc., 55 miles east of Fernandina Beach, Florida, is presented. The interval tested (1,050 to 1,070 feet below sea level) is in a calcarenite that is equivalent to the Ocala Limestone (late Eocene) of onshore Florida and South Georgia. At this site the Ocala forms the highly productive Tertiary limestone aquifer system of the southeastern United States. Pressure-head measurements indicate an equivalent freshwater head of 24 to 29 feet above sea level. These pressure-head measurements and an earlier one made in the nearby JOIDES J- I hole are the only hydraulic head determinations to date in the offshore extensions of any of the aquifers underlying the Atlantic coastal plain. A drill-stem test recovered water samples containing about 7,000 milligrams per liter chloride. However, seawater used in the drilling process apparently contaminated the samples and the formation water is considered slightly fresher. The head and salinity data from the Tenneco well suggest that the sampled interval lies in the transition zone between fresh and seawater in the limestone aquifer. These data, when viewed with similar data from JOIDES J-I, show the transition zone to slope very slightly landward. The interface position is probably intermediate between a position compatible with present-day heads and a position compatible with predevelopment heads.

Environmental Assessment: For Joint Biological Point Detection System (JBPDS) at Multiple Test Ranges, Eglin Air Force Base, Florida

DTIC Science & Technology

2003-06-01

bed. This clay layer restricts the downward migration of pollutants and restricts saline water from Choctawhatchee Bay and the Gulf of Mexico from...Because it is saline , the Lower Limestone unit is not used as a water source (U.S. Air Force, 1995). Groundwater storage and movement in the Upper... purslane , among others. Inland from the produne zone is the “scrub” zone. Vegetation found in this zone is usually stunted and wind/salt sprayed

Actinobacterial diversity in limestone deposit sites in Hundung, Manipur (India) and their antimicrobial activities

PubMed Central

Nimaichand, Salam; Devi, Asem Mipeshwaree; Tamreihao, K.; Ningthoujam, Debananda S.; Li, Wen-Jun

2015-01-01

Studies on actinobacterial diversity in limestone habitats are scarce. This paper reports profiling of actinobacteria isolated from Hundung limestone samples in Manipur, India using ARDRA as the molecular tool for preliminary classification. A total of 137 actinobacteria were clustered into 31 phylotypic groups based on the ARDRA pattern generated and representative of each group was subjected to 16S rRNA gene sequencing. Generic diversity of the limestone isolates consisted of Streptomyces (15 phylotypic groups), Micromonospora (4), Amycolatopsis (3), Arthrobacter (3), Kitasatospora (2), Janibacter (1), Nocardia (1), Pseudonocardia (1) and Rhodococcus (1). Considering the antimicrobial potential of these actinobacteria, 19 showed antimicrobial activities against at least one of the bacterial and candidal test pathogens, while 45 exhibit biocontrol activities against at least one of the rice fungal pathogens. Out of the 137 actinobacterial isolates, 118 were found to have at least one of the three biosynthetic gene clusters (PKS-I, PKS-II, NRPS). The results indicate that 86% of the strains isolated from Hundung limestone deposit sites possessed biosynthetic gene clusters of which 40% exhibited antimicrobial activities. It can, therefore, be concluded that limestone habitat is a promising source for search of novel secondary metabolites. PMID:25999937

Mycorrhiza of plants in different vegetation types in tropical ecosystems of Xishuangbanna, southwest China.

PubMed

Muthukumar, T; Sha, Liqing; Yang, Xiaodong; Cao, Min; Tang, Jianwei; Zheng, Zheng

2003-12-01

We examined plants growing in four tropical vegetation types (primary forest, secondary forest, limestone forest and a slash and burn field) in Xishuangbanna, southwest China for mycorrhizal associations. Of the 103 plant species examined (belonging to 47 families), 81 had arbuscular mycorrhizal (AM) associations, while three species possessed orchid mycorrhiza. AM colonization levels ranged between 6% and 91% and spore numbers ranged between 1.36 spores and 25.71 spores per 10 g soil. Mean AM colonization level was higher in primary and secondary forest species than in plant species from limestone forests and a slash and burn field. In contrast, mean AM fungal spore numbers of the primary and limestone forest were lower than in the secondary forest or the slash and burn field. AM fungal spores belonging to Glomus and Acaulospora were the most frequent in soils of Xishuangbanna. AM fungal colonization and spore numbers were significantly correlated to each other and were significantly influenced by vegetation type.

{sup 13}C chemical shift anisotropies for carbonate ions in cement minerals and the use of {sup 13}C, {sup 27}Al and {sup 29}Si MAS NMR in studies of Portland cement including limestone additions

DOE Office of Scientific and Technical Information (OSTI.GOV)

Sevelsted, Tine F.; Herfort, Duncan; Skibsted, Jørgen, E-mail: jskib@chem.au.dk

2013-10-15

{sup 13}C isotropic chemical shifts and chemical shift anisotropy parameters have been determined for a number of inorganic carbonates relevant in cement chemistry from slow-speed {sup 13}C MAS or {sup 13}C({sup 1}H) CP/MAS NMR spectra (9.4 T or 14.1 T) for {sup 13}C in natural abundance. The variation in the {sup 13}C chemical shift parameters is relatively small, raising some doubts that different carbonate species in Portland cement-based materials may not be sufficiently resolved in {sup 13}C MAS NMR spectra. However, it is shown that by combining {sup 13}C MAS and {sup 13}C({sup 1}H) CP/MAS NMR carbonate anions in anhydrousmore » and hydrated phases can be distinguished, thereby providing valuable information about the reactivity of limestone in cement blends. This is illustrated for three cement pastes prepared from an ordinary Portland cement, including 0, 16, and 25 wt.% limestone, and following the hydration for up to one year. For these blends {sup 29}Si MAS NMR reveals that the limestone filler accelerates the hydration for alite and also results in a smaller fraction of tetrahedrally coordinated Al incorporated in the C-S-H phase. The latter result is more clearly observed in {sup 27}Al MAS NMR spectra of the cement–limestone blends and suggests that dissolved aluminate species in the cement–limestone blends readily react with carbonate ions from the limestone filler, forming calcium monocarboaluminate hydrate. -- Highlights: •{sup 13}C chemical shift anisotropies for inorganic carbonates from {sup 13}C MAS NMR. •Narrow {sup 13}C NMR chemical shift range (163–171 ppm) for inorganic carbonates. •Anhydrous and hydrated carbonate species by {sup 13}C MAS and {sup 13}C({sup 1}H) CP/MAS NMR. •Limestone accelerates the hydration for alite in Portland – limestone cements. •Limestone reduces the amount of aluminium incorporated in the C-S-H phase.« less

Stratigraphy and lithofacies of Lisburne Group carbonate rocks (Carboniferous - Permian) in the National Petroleum Reserve - Alaska

USGS Publications Warehouse

Dumoulin, Julie A.; Bird, Kenneth J.; Houseknecht, David W.

2001-01-01

Carbonate rocks of the Lisburne Group (Carboniferous-Permian) occur widely throughout northern Alaska. In the NPRA, seismic mapping and well penetrations show that the Lisburne occurs throughout the subsurface except in northernmost NPRA where it is missing by depositional onlap. Lisburne strata encountered in 11 exploratory wells in the northern part of the NPRA are essentially undeformed, consist of limestone and lesser dolostone, sandstone, siltstone, and shale, encompass a wide array of chiefly shallow-water facies, and range in age from Early Mississippian to Permian. Basins and platforms that formed during Mississippian (and possibly Devonian) time greatly affected depositional patterns of the Lisburne. Total thickness of the Lisburne in northern NPRA wells varies from almost 4000 ft in the Ikpikpuk-Umiat Basin to 300 ft on the north edge of the Fish Creek Platform. Lisburne strata of Mississippian age are found in northeastern NPRA, comprise three subunits (lower limestone, middle dolostone, and upper limestone) and are oldest (Osagean) in the Ikpikpuk-Umiat Basin. All wells that penetrated the Lisburne in northern NPRA encountered rocks of Pennsylvanian age; these intervals are mainly limestone and characterized by decameter-scale shallowing-upward sequences. Lisburne sections of prob-able Early-middle Permian age range from thin (≤60 ft) intervals of dolostone and limestone in the Fish Creek Platform area to thick (500-1000 ft) successions of interbedded limestone and siliciclastic sediment in the Ikpikpuk-Umiat Basin and northwestern NPRA. Abundant non-carbonate detritus, primarily quartz and chert with locally notable plagioclase feldspar and metamorphic lithic clasts, occurs throughout the Lisburne Group in northern NPRA. Per-mian strata and a persistent non-carbonate detrital component are also seen in the Lisburne in subsurface beneath the Chukchi Sea (Hanna Trough) to the northwest, but are not found in Lisburne successions elsewhere in Alaska.

Evaluation of Nondestructive Methods for Determining Pavement Thickness

DTIC Science & Technology

2011-09-01

38, PCC 10.38 10.38 9.57 N/A 39, PCC 11.21 11.21 10.31 N/A 40c*, PCC 8.92 8.92 9.84 N/A SB = stabilized limestone base, PCC = portland cement ...PCC 8.92 8.92 8.07 8.92 SB = stabilized limestone base, PCC = portland cement concrete, and AC = asphalt concrete. * Denotes a test location used as...10.38 N/A N/A 39, PCC 11.21 11.21 N/A N/A 40c*, PCC 8.92 8.92 N/A N/A SB = stabilized limestone base, PCC = portland cement concrete, and AC

Heat transfer to horizontal tubes in a pilot-scale fluidized-bed combustor burning low-rank coals

DOE Office of Scientific and Technical Information (OSTI.GOV)

Grewal, N.S.; Goblirsch, G.

Experimental data are obtained for the heat transfer coefficient between immersed horizontal tube bundles and an atmospheric-fluidized-bed combustor burning low-rank coals. Silica sand (d/sub p/ = 888 to 1484 ..mu..m) and limestone (d/sub p/ = 716 to 1895 ..mu..m) are used as bed material. The tests are conducted, with and without limestone addition and ash recycle, at average bed temperatures ranging from 1047 to 1125/sup 0/K, superficial fluidizing velocity of 1.66 to 2.04 m/s, and excess air levels of 15 to 40 percent. The experimental data are examined in the light of the existing correlations for the heat transfer coefficient.more » The predicted values of heat transfer coefficient from the correlations proposed by Grewal (1981) and Bansal et al. (1980) are found to be within +-25 percent of the experimental values of heat transfer coefficient, when the contribution due to radiation is also included. 5 figures, 5 tables.« less

Distal facies variability within the Upper Triassic part of the Otuk Formation in northern Alaska

USGS Publications Warehouse

Whidden, Katherine J.; Dumoulin, Julie A.; Whalen, M.T.; Hutton, E.; Moore, Thomas; Gaswirth, Stephanie

2014-01-01

The Triassic-Jurassic Otuk Formation is a potentially important source rock in allochthonous structural positions in the northern foothills of the Brooks Range in the North Slope of Alaska. This study focuses on three localities of the Upper Triassic (Norian) limestone member, which form a present-day, 110-km-long, east-west transect in the central Brooks Range. All three sections are within the structurally lowest Endicott Mountain allochthon and are interpreted to have been deposited along a marine outer shelf with a ramp geometry.The uppermost limestone member of the Otuk was chosen for this study in order to better understand lateral and vertical variability within carbonate source rocks, to aid prediction of organic richness, and ultimately, to evaluate the potential for these units to act as continuous (or unconventional) reservoirs. At each locality, 1 to 4 m sections of the limestone member were measured and sampled in detail to capture fine-scale features. Hand sample and thin section descriptions reveal four major microfacies in the study area, and one diagenetically recrystallized microfacies. Microfacies 1 and 2 are interpreted to represent redeposition of material by downslope transport, whereas microfacies 3 and 4 have high total organic carbon (TOC) values and are classified as primary depositional organofacies. Microfacies 3 is interpreted to have been deposited under primarily high productivity conditions, with high concentrations of radiolarian tests. Microfacies 4 was deposited under the lowest relative-oxygen conditions, but abundant thin bivalve shells indicate that the sediment-water interface was probably not anoxic.The Otuk Formation is interpreted to have been deposited outboard of a southwest-facing ramp margin, with the location of the three limestone outcrops likely in relatively close proximity during deposition. All three sections have evidence of transported material, implying that the Triassic Alaskan Basin was not a low-energy, deep-water setting, but rather a dynamic system with intermittent, yet significant, downslope flow. Upwelling played an important role in the small-scale vertical variability in microfacies. The zone of upwelling and resultant oxygen-minimum zone may have migrated across the ramp during fourth- or fifth-order sea-level changes.

Sequence-Stratigraphic Analysis of the Regional Observation Monitoring Program (ROMP) 29A Test Corehole and Its Relation to Carbonate Porosity and Regional Transmissivity in the Floridan Aquifer System, Highlands County, Florida

USGS Publications Warehouse

Ward, W. C.; Cunningham, K.J.; Renken, R.A.; Wacker, M.A.; Carlson, J.I.

2003-01-01

An analysis was made to describe and interpret the lithology of a part of the Upper Floridan aquifer penetrated by the Regional Observation Monitoring Program (ROMP) 29A test corehole in Highlands County, Florida. This information was integrated into a one-dimensional hydrostratigraphic model that delineates candidate flow zones and confining units in the context of sequence stratigraphy. Results from this test corehole will serve as a starting point to build a robust three-dimensional sequence-stratigraphic framework of the Floridan aquifer system. The ROMP 29A test corehole penetrated the Avon Park Formation, Ocala Limestone, Suwannee Limestone, and Hawthorn Group of middle Eocene to Pliocene age. The part of the Avon Park Formation penetrated in the ROMP 29A test corehole contains two composite depositional sequences. A transgressive systems tract and a highstand systems tract were interpreted for the upper composite sequence; however, only a highstand systems tract was interpreted for the lower composite sequence of the deeper Avon Park stratigraphic section. The composite depositional sequences are composed of at least five high-frequency depositional sequences. These sequences contain high-frequency cycle sets that are an amalgamation of vertically stacked high-frequency cycles. Three types of high-frequency cycles have been identified in the Avon Park Formation: peritidal, shallow subtidal, and deeper subtidal high-frequency cycles. The vertical distribution of carbonate-rock diffuse flow zones within the Avon Park Formation is heterogeneous. Porous vuggy intervals are less than 10 feet, and most are much thinner. The volumetric arrangement of the diffuse flow zones shows that most occur in the highstand systems tract of the lower composite sequence of the Avon Park Formation as compared to the upper composite sequence, which contains both a backstepping transgressive systems tract and a prograding highstand systems tract. Although the porous and permeable layers are not thick, some intervals may exhibit lateral continuity because of their deposition on a broad low-relief ramp. A thick interval of thin vuggy zones and open faults forms thin conduit flow zones mixed with relatively thicker carbonate-rock diffuse flow zones between a depth of 1,070 and 1,244 feet below land surface (bottom of the test corehole). This interval is the most transmissive part of the Avon Park Formation penetrated in the ROMP 29A test corehole and is included in the highstand systems tract of the lower composite sequence. The Ocala Limestone is considered to be a semiconfining unit and contains three depositional sequences penetrated by the ROMP 29A test corehole. Deposited within deeper subtidal depositional cycles, no zones of enhanced porosity and permeability are expected in the Ocala Limestone. A thin erosional remnant of the shallow marine Suwannee Limestone overlies the Ocala Limestone, and permeability seems to be comparatively low because moldic porosity is poorly connected. Rocks that comprise the lower Hawthorn Group, Suwannee Limestone, and Ocala Limestone form a permeable upper zone of the Upper Floridan aquifer, and rocks of the lower Ocala Limestone and Avon Park Formation form a permeable lower zone of the Upper Floridan aquifer. On the basis of a preliminary analysis of transmissivity estimates for wells located north of Lake Okeechobee, spatial relations among groups of relatively high and low transmissivity values within the upper zone are evident. Upper zone transmissivity is generally less than 10,000 feet squared per day in areas located south of a line that extends through Charlotte, Sarasota, DeSoto, Highlands, Polk, Osceola, Okeechobee, and St. Lucie Counties. Transmissivity patterns within the lower zone of the Avon Park Formation cannot be regionally assessed because insufficient data over a wide areal extent have not been compiled.

Paleomagnetism of Cretaceous limestones from western Tarim basin suggests negligible latitudinal offset yet significant clockwise rotation

NASA Astrophysics Data System (ADS)

Tan, X.; Gilder, S.; Chen, Y.; Cogné, J. P.; Courtillot, V. E.; Cai, J.

2017-12-01

Large northward translation of central Asian crustal blocks has been reported from paleomagnetism of Cretaceous and Tertiary terrestrial sediments. This motion was initially taken as evidence of deformation occurred in the Asian interior as a result of indentation of the Indian Plate. However, because the amount of motion is far greater than geological observations, accuracy of the paleomagnetic record has become a controversial issue. To solve the problem, it has been shown that the latitudinal offset can be entirely attributed to inclination shallowing during deposition and compaction processes (Tan et al., 2003; Tauxe and Kent, 2004). On the other hand, coeval volcanic rocks from central Asia did record steeper paleomagnetic inclinations than terrestrial rocks (Gilder et al., 2003). To extend the effort of solving the controversy, we report paleomagnetic results of Cretaceous limestones from western Tarim basin. Our results show that the majority of our collections have been overprinted. Fortunately, a special type of limestones preserved stable characteristic remanence. Fold tests suggest a primary origin of the magnetization. Comparison of the paleomagnetic direction with the coeval expected direction from reference poles indicates a negligible amount of northward movement consistent with previous result of inclination correction based on magnetic fabrics, and a pattern of clockwise rotation symmetric with the style observed in the western flank of the Pamir ranges. Rock magnetic data will also be presented to support the accurate paleomagnetic record.

Limestone quarrying and quarry reclamation in Britain

NASA Astrophysics Data System (ADS)

Gunn, J.; Bailey, D.

1993-06-01

Limestones have been worked for many thousands of years — initially for building stone and agricultural lime and more recently for a wide range of construction and industrial uses. In most industrialized countries limestone quarries represent the most visually obvious and, in both process and landform terms, the most dramatic anthropogenic impact on karst terrain. However, quarrying has, to date, received surprisingly little attention from karst scientists. Research in the English Peak District suggested that the postexcavation evolution of quarried limestone rock faces was in part a result of the methods used in their excavation, and this led to the development of a technique designed to reduce the visual and environmental impacts of modern quarries by “Landform replication. ” This involves the use of controlled “restoration blasting” techniques on quarried rock slopes to construct a landform sequence similar to that in the surrounding natural landscape. The constructed landforms are then partially revegetated using appropriate wildflower, grass, and/or tree species.

A Novel Treatment for Acid Mine Drainage Utilizing Reclaimed Limestone Residual

DOE Office of Scientific and Technical Information (OSTI.GOV)

Horace K. Moo-Young; Charles E. Ochola

2004-08-31

The viability of utilizing Reclaimed Limestone Residual (RLR) to remediate Acid Mine Drainage (AMD) was investigated. Physical and chemical characterization of RLR showed that it is composed of various minerals that contain significant quantities of limestone or calcium bearing compounds that can be exploited for acid neutralization. Acid Neutralization Potential (ANP) test results showed that RLR has a neutralization potential of approximately 83% as calcium carbonate (CaCO{sub 3}). Neutralization tests with most of the heavy metals associated with AMD showed removal efficiencies of over 99%. An unexpected benefit of utilizing RLR was the removal of hexavalent chromium Cr (VI) frommore » the aqueous phase. Due to an elevation in pH by RLR most AMD heavy metals are removed from solution by precipitation as their metal hydroxides. Cr (VI) however is not removed by pH elevation and therefore subsequent ongoing tests to elucidate the mechanism responsible for this reaction were conducted.« less

Hydrogeologic data from the US Geological Survey test wells near Waycross, Ware County, Georgia

USGS Publications Warehouse

Matthews, S.E.; Krause, R.E.

1983-01-01

Two wells were constructed near Waycross, Ware County, Georgia, from July 1980 to May 1981 to collect stratigraphic, structural, geophysical, hydrologic, hydraulic, and geochemical information for the U.S. Geological Survey Tertiary Limestone Regional Aquifer-System Analysis. Data collection included geologic sampling and coring, borehole geophysical logging, packer testing, water-level measuring, water-quality sampling, and aquifer testing. In the study area, the Tertiary limestone aquifer system is about 1,300 feet thick and is confined and overlain by about 610 feet of clastic sediments. The aquifer system consists of limestone, dolomite, and minor evaporites and has high porosity and permeability. A 4-day continuous discharge aquifer test was conducted, from which a transmissivity of about 1 million feet squared per day and a storage coefficient of 0.0001 were calculated. Water from the upper part of the aquifer is of a calcium bicarbonate type. The deeper highly mineralized zone produces a sodium bicarbonate type water in which concentrations of magnesium, sulfate, chloride, sodium, and some trace metals increase with depth. (USGS)

Response of infaunal organisms represented by trace fossils to sea-level changes in the Ordovician Black River and Trenton Group limestones, upstate New York

DOE Office of Scientific and Technical Information (OSTI.GOV)

Tegan, J.R.; Curran, H.A.

Small-scale fluctuations in sea level were revealed by detailed analysis of trace fossil assemblages formed by infaunal organisms within the Lowville (Black River Grp.), Napanee, and Kings Falls limestones (Trenton Grp.) at Ingham Mills. The paleodepositional environment of the Lowville Limestone (LL) is interpreted as peritidal, representing the high intertidal to shallow subtidal zones. The trace fossil assemblages define clearly several fluctuations within this environment. Large, well-formed specimens of the trace fossil Beaconites barretti occur within tidal channel and levee beds of the LL. In other regions this trace fossil has consistently been associated with channel and levee beds, mostmore » commonly in fluvial settings. The occurrence of Beaconites in the LL extends the age range of this ichnogenus to Ordovician time (oldest previous record is Silurian) and broadens its paleoenvironment range. The Napanee (Np) and lower Kings Falls (KF), limestones have most commonly been described as being deposited in a lagoonal setting. Both formations contain well-preserved trace fossils; the primary difference being that the Np exhibits much lower trace and body fossil diversities than the KF. The low diversity of trace fossils in the Np was most likely the result of limiting environmental conditions such as low oxygen and/or hypersalinity. The higher diversity of trace fossils in the KF indicates that the ancient lagoon became increasingly controlled by normal marine conditions, and, therefore, hospitable to a more diverse group of organisms. The trace fossil assemblages of the Black River and Trenton Group limestones indicate that the infaunal organisms of these Ordovician communities were highly sensitive to small-scale sea-level fluctuations.« less

Piedramuelle Limestone in the building heritage of Oviedo, Spain, and adjacent towns.

NASA Astrophysics Data System (ADS)

Cardenes Van den Eynde, Victor; Mateos, Felix Javier; Valdeon, Luis; Rojo, Araceli

2017-04-01

The Piedramuelle limestone has a very important representation in the building heritage of Oviedo, historical capital of Asturias (Spain) and surrounding towns. This argillaceous limestone has been quarried since the High Middle Ages until the beginning of the XX century. The main mineralogical components are carbonates (mainly calcite and sometimes ankerite, 70-90%), quartz (5-15%), terrigenous minerals (6-15%) and iron oxides (<5%). Two different facies, with different constructive uses, can be clearly distinguished depending on the grain size: fine-grained facies and coarse-grained facies. The fine-grained facies has color ranging from red to yellow, slightly higher content in carbonates, higher terrigenous components and a micro crystalline texture. The coarse-grained facies is mainly yellow, with detrital clastic texture. The open porosity is higher for the coarse-grained facies (16-20%), while for the fine-grained facies it ranges between 5 and 15%. The fine-grained facies is more vulnerable to weathering than the coarse-grained one, and it is used in the building heritage mainly for ornamental details, while the coarse-grained one is found in the bigger blocks and ashlars of the buildings. Some of the buildings constructed with Piedramuelle limestone are the Cathedral, the Old University and the Palaces from the XVII and XVIII centuries. The ambiance and historical architecture of Oviedo and adjacent towns is closely linked with the textures and colors of this stone. Nowadays, the Piedramuelle limestone is not exploited anymore, being the quarries exhausted. This represents an issue from a conservation point of view, since there is not a suitable stone for replacement. In order to preserve and maintain the building heritage of these towns, it is very important to prospect and protect the remaining outcrops still able to supply this characteristic stone.

Stratigraphic and structural data for the Conasauga Group and the Rome Formation on the Copper Creek fault block near Oak Ridge, Tennessee: preliminary results from test borehole ORNL-JOY No. 2

DOE Office of Scientific and Technical Information (OSTI.GOV)

Haase, C.S.; Walls, E.C.; Farmer, C.D.

1985-06-01

To resolve long-standing problems with the stratigraphy of the Conasauga Group and the Rome Formation on the Copper Creek fault block near Oak Ridge National Laboratory (ORNL), an 828.5-m-deep test borehole was drilled. Continuous rock core was recovered from the 17.7- to 828.5-m-deep interval; temperature, caliper, neutron, gamma-ray, and acoustic (velocity and televiewer) logs were obtained. The Conasauga Group at the study site is 572.4 m thick and comprises six formations that are - in descending stratigraphic order - Maynardville Limestone (98.8 m), Nolichucky Shale (167.9 m), Maryville Limestone (141.1 m), Rogersville Shale (39.6 m), Rutledge Limestone (30.8 m), andmore » Pumpkin Valley Shale (94.2 m). The formations are lithologically complex, ranging from clastics that consist of shales, mudstones, and siltstones to carbonates that consist of micrites, wackestones, packstones, and conglomerates. The Rome Formation is 188.1 m thick and consists of variably bedded mudstones, siltstones, and sandstones. The Rome Formation thickness represents 88.1 m of relatively undeformed section and 100.0 m of highly deformed, jumbled, and partially repeated section. The bottom of the Rome Formation is marked by a tectonic disconformity that occurs within a 46-m-thick, intensely deformed interval caused by motion along the Copper Creek fault. Results from this study establish the stratigraphy and the lithology of the Conasauga Group and the Rome Formation near ORNL and, for the first time, allow for the unambiguous correlation of cores and geophysical logs from boreholes elsewhere in the ORNL vicinity. 45 refs., 26 figs., 2 tabs.« less

Digital model evaluation of the predevelopment flow system of the Tertiary limestone aquifer, Southeast Georgia, Northeast Florida, and South South Carolina

USGS Publications Warehouse

Krause, Richard E.

1982-01-01

A computer model using finite-difference techniques was used successfully to simulate the predevelopment flow regime within the multilayered Tertiary limestone aquifer system in Southeastern Georgia, Northeastern Florida, and Southern South Carolina as part of the U.S. Geological Survey 's Tertiary Limestone Regional Aquifer System analysis. The aquifer, of early Eocene to Miocene age, ranges from thin interbedded clastics and marl in the updip area to massive limestone and dolomite 1,500 feet thick in the downdip area. The aquifer is confined above by Miocene clay beds, and terminates at depth in low-permeability rocks or the saltwater interface. Model-simulated transmissivity of the upper permeable zone ranged from about 1 x 10 super 3 foot squared per day in the updip area and within parts of the Gulf Trough (a series of alinement basins filled by fine clastic in material) to about 1 x 10 super 6 foot squared per day in South Georgia, and area having large secondarily developed solution channels. The model results indicate that only about 540 cubic feet per second of water flowed through the predeveloped system, from the updip highland area of high altitude and in the areas north of Valdosta and southwest of Jacksonville, to discharge along streams in the updip area and diffuse upward leakage in the downdip area near the coast and offshore. (USGS)

Treatment of highly polluted groundwater by novel iron removal process.

PubMed

Sim, S J; Kang, C D; Lee, J W; Kim, W S

2001-01-01

The removal of ferrous iron (Fe(II)) in groundwater has been generally achieved by simple aeration, or the addition of an oxidizing agent. Aeration has been shown to be very efficient in insolubilization ferrous iron at a pH level greater than 6.5. In this study, pH was maintained over 6.5 using limestone granules under constant aeration to oxidize ferrous iron in groundwater in a limestone packed column. A sedimentation unit coupled with a membrane filtration was also developed to precipitate and filtrate the oxidized ferric compound simultaneously. Several bench-scale studies, including the effects of the limestone granule sizes, amounts and hydraulic retention time on iron removal in the limestone packed column were investigated. It was found that 550 g/L of the 7-8 mesh size limestone granules, and 20 min of hydraulic retention time in the limestone packed column, were necessary for the sufficient oxidation of 40 mg/L of iron(II) in groundwater. Long-term operation was successfully achieved in contaminated waters by removing the iron deposits on the surface of the limestone granule by continuous aeration from the bottom of the column. Periodic reverse flow helped to remove caking and fouling of membrane surface caused by the continuous filtration. Recycling of the treated water from the membrane right after reverse flow operation made possible an admissible limit of iron concentration of the treated water for drinking. The pilot-scale process was constructed and has been tested in the rural area of Korea.

Sequential capture of CO2 and SO2 in a pressurized TGA simulating FBC conditions.

PubMed

Sun, Ping; Grace, John R; Lim, C Jim; Anthony, Edward J

2007-04-15

Four FBC-based processes were investigated as possible means of sequentially capturing SO2 and CO2. Sorbent performance is the key to their technical feasibility. Two sorbents (a limestone and a dolomite) were tested in a pressurized thermogravimetric analyzer (PTGA). The sorbent behaviors were explained based on complex interaction between carbonation, sulfation, and direct sulfation. The best option involved using limestone or dolomite as a SO2-sorbent in a FBC combustor following cyclic CO2 capture. Highly sintered limestone is a good sorbent for SO2 because of the generation of macropores during calcination/carbonation cycling.

Pilot-scale Limestone Emission Control (LEC) process: A development project. Volume 1, Main report and appendices A, B, C, and D: Final report

DOE Office of Scientific and Technical Information (OSTI.GOV)

Prudich, M.E.; Appell, K.W.; McKenna, J.D.

ETS, Inc., a pollution consulting firm with headquarters in Roanoke, Virginia, has developed a dry, limestone-based flue gas desulfurization (FGD) system. This SO{sub 2} removal system, called Limestone Emission Control (LEC), can be designed for installation on either new or existing coal-fired boilers. In the LEC process, the SO{sub 2} in the flue gas reacts with wetted granular limestone that is contained in a moving bed. A surface layer of principally calcium sulfate (CaSO{sub 4}) is formed on the limestone. Periodic removal of this surface layer by mechanical agitation allows high utilization of the limestone granules. A nominal 5,000 acfmmore » LEC pilot plant has been designed, fabricated and installed on the slipstream of a 70,000 pph stoker boiler providing steam to Ohio University`s Athens, Ohio campus. A total of over 90 experimental trials have been performed using the pilot-scale moving-bed LEC dry scrubber as a part of this research project with run times ranging up to a high of 125 hours. SO{sub 2} removal efficiencies as high as 99.9% were achievable for all experimental conditions studied during which sufficient humidification was added to the LEC bed. The LEC process and conventional limestone scrubbing have been compared on an equatable basis using flue gas conditions that would be expected at the outlet of the electrostatic precipitator (ESP) of a 500 MW coal-fired power plant. The LEC was found to have a definite economic advantage in both direct capital costs and operating costs. Based on the success and findings of the present project, the next step in LEC process development will be a full-scale commercial demonstration unit.« less

Current use of carbonate rocks and lime for controlling emissions from coal-fired plants in Kentucky

DOE Office of Scientific and Technical Information (OSTI.GOV)

Dever, G.R. Jr.

1993-03-01

Seven coal-fired power plants in Kentucky currently are operating wet-scrubbing systems for flue-gas desulfurization. Atmospheric fluidized-bed combustion (AFBC) units are being used for SO[sub 2] emission control at a petroleum refinery, and a 160-MW utility-scale AFBC demonstration plant is being operated by the Tennessee Valley Authority. A lime-based spray-dryer reactor system has been installed on an industrial boiler, and a spray-dryer system is being tested at a utility pilot-plant facility. Four of the seven power plants operate limestone-based wet-scrubbing systems and require about 885,000 tons of stone per year. Stone is obtained from Mississippian limestones, principally the Ste. Genevieve Limestone,more » produced at four quarries in Kentucky, Indiana, and Illinois. Scrubber limestone specifications include CaCO[sub 3] content (minimum 88--90%), MgCO[sub 3] content (maximum 4--6%), and grindability (maximum Bond Work Index of 11--12). Three power plants operate lime-based scrubbers, requiring about 250,000 tons of lime per year. The scrubbers currently use (1) lime manufactured from an Ordovician dolomitic limestone, mined in north-central Kentucky, and (2) carbide lime, a chemical-industry byproduct. Fluidized-bed units at the petroleum refinery require about 100,000 tons of sorbent stone per year. The sorbent consists of about equal amounts of Silurian dolomite from Ohio and Ordovician dolomitic limestone from Kentucky. The utility-scale AFBC demonstration plant uses a limestone sorbent and currently requires about 200,000 tons of stone per year. Limestone is obtained from the Ste. Genevieve in western Kentucky.« less

Use of nanotomographic images for structure analysis of carbonate rocks

DOE Office of Scientific and Technical Information (OSTI.GOV)

Nagata, Rodrigo; Appoloni, Carlos Roberto

Carbonate rocks store more than 50% of world's petroleum. These rocks' structures are highly complex and vary depending on many factors regarding their formation, e.g., lithification and diagenesis. In order to perform an effective extraction of petroleum it is necessary to know petrophysical parameters, such as total porosity, pore size and permeability of the reservoir rocks. Carbonate rocks usually have a range of pore sizes that goes from nanometers to meters or even dozen of meters. The nanopores and micropores might play an important role in the pores connectivity of carbonate rocks. X-ray computed tomography (CT) has been widely usedmore » to analyze petrophysical parameters in recent years. This technique has the capability to generate 2D images of the samples' inner structure and also allows the 3D reconstruction of the actual analyzed volume. CT is a powerful technique, but its results depend on the spatial resolution of the generated image. Spatial resolution is a measurement parameter that indicates the smallest object that can be detected. There are great difficulties to generate images with nanoscale resolution (nanotomographic images). In this work three carbonate rocks, one dolomite and two limestones (that will be called limestone A and limestone B) were analyzed by nanotomography. The measurements were performed with the SkyScan2011 nanotomograph, operated at 60 kV and 200 μA to measure the dolomite sample and 40 kV and 200 μA to measure the limestone samples. Each sample was measured with a given spatial resolution (270 nm for the dolomite sample, 360 nm for limestone A and 450 nm for limestone B). The achieved results for total porosity were: 3.09 % for dolomite, 0.65% for limestone A and 3.74% for limestone B. This paper reports the difficulties to acquire nanotomographic images and further analysis about the samples' pore sizes.« less

Effect of acidity and elevated PCO2 on acid. Neutralization within pulsed limestone bed reactors receiving coal mine drainage

USGS Publications Warehouse

Watten, B.J.; Sibrell, P.L.; Schwartz, M.F.

2004-01-01

Limestone has potential for reducing reagent costs and sludge volume associated with the treatment of acid mine drainage (AMD), but its use has been restricted by slow dissolution rates and sensitivity to scale forming reactions that retard transport of H+ at the solid-liquid interface. We evaluated a pulsed limestone bed (PLB) remediation process designed to circumvent these problems through use of intermittently fluidized beds of granular limestone and elevated carbon dioxide pressure. PLB limestone dissolution (LD, mg/L), and effluent alkalinity (Alk, mg/L) were correlated with reactor pressure (PCO2, kPa), influent acidity (Acy, mg/L) and reactor bed height (H, cm) using a prototype capable of processing 10 L/min. The PLB process effectively neutralized sulfuric acid acidity over the range of 6-1033 mg/L (as CaCO3) while generating high concentrations of alkalinity (36-1086 mg/L) despite a hydraulic residence time of just 4.2-5.0 min. Alk and LD (mg/L CaCO3) rose with increases in influent acidity and PCO2 (p < 0.001) according to the models: Alk = 58 + 38.4 (PCO2)0.5 + 0.080 (Acy) - 0.0059(PCO2) 0.5 (Acy); LD = 55 + 38.3 (PCO2)0.5 + 1.08 (Acy) - 0.0059 (PCO2)0.5 (Acy). Alkalinity decreased at an increasing rate with reductions in H over the range of 27.3-77.5 cm (p < 0.001). Carbon dioxide requirements (Q(avg)CO2, L/min) increased with PCO2 (p < 0.001) following the model Q(avg)CO2 = 0.858 (PCO2)0.620, resulting in a greater degree of pH buffering (depression) within the reactors, a rise in limestone solubility and an increase in limestone dissolution related to carbonic acid attack. Corresponding elevated concentrations of effluent alkalinity allow for sidestream treatment with blending. Numerical modeling demonstrated that carbon dioxide requirements are reduced as influent acidity rises and when carbon dioxide is recovered from system effluent and recycled. Field trials demonstrated that the PLB process is capable of raising the pH of AMD above that required for hydrolysis and precipitation of Fe3+ and Al 3+ but not Fe2+ and Mn2+.

Water transport in limestone by X-ray CAT scanning

USGS Publications Warehouse

Mossoti, Victor G.; Castanier, Louis M.

1989-01-01

The transport of water through the interior of Salem limestone test briquettes can be dynamically monitored by computer aided tomography (commonly called CAT scanning in medical diagnostics). Most significantly, unless evaporation from a particular face of the briquette is accelerated by forced air flow (wind simulation), the distribution of water in the interior of the briquette remains more or less uniform throughout the complete drying cycle. Moreover, simulated solar illumination of the test briquette does not result in the production of significant water gradients in the briquette under steady-state drying conditions.

Influence of mineralogical, petrographical, and geochemical characteristics of impure limestones on the composition of fired hydraulic lime: a case study on Lower Palaeozoic limestones from the Prague Basin (Barrandian area, Czech Republic)

NASA Astrophysics Data System (ADS)

Kozlovcev, Petr; Přikryl, Richard

2014-05-01

Prague Basin, making part of the Barrandian area (Bohemian Massif, Czech Republic), is a rift-like depression filled with non-metamorphosed sedimentary series of Upper Proterozoic - Lower Palaeozoic age. Among other sedimentary rocks, different types of limestones are present. These limestone were historically exploited and used for various purposes including natural and decorative stone, common construction material, and also a raw material for firing of inorganic binders: aerial lime, hydraulic lime and/or, more recently, Ordinary Portland Cement (OPC). Lithotypes with higher amount of silica and/or clay component were of special interest due to the hydraulicity of fired product known as "pasta di Praga" in Baroque. However, our recent knowledge of these limestones is incomplete in terms of the contribution of mineralogical, geochemical, and petrographical characteristics on the properties of fired hydraulic lime. In the recent study, representative samples of 4 facies of the Lower Devonian limestone (Kosoř ls., Řeporyje ls., Dvorce-Prokop ls., and Zlíchov ls.) were subjected to a detailed mineralogical and petrographic study of raw material by means of polarizing microscopy, cathodoluminiscence of thin sections and scanning electron microscopy with an energy dispersive spectrometer (SEM-EDS). X-ray diffraction (XRD) of insoluble residues obtained by treatment with both the hydrochloric acid and the acetic acid solution was used. Wet silicate analysis provided data on the content of major elements from which standard cement and lime indexes and modules were calculated. Laboratory firing experiments of these limestone were performed by a calcination at temperature ranging from 850 to 1200°C (after 50°C). XRD of fired products shows that limestones with high content of silica (some of the Dvorce-Prokop ls.) produced binder with high amount of newly formed calcium silicates (larnite). Gehlenite and others calcium aluminates and aluminosilicates are typical for firing of limestones with higher content of clay minerals (illite and kaolinite) which are common in Kosoř ls., Řeporyje ls., and Dvorce-Prokop ls. Brownmillerite was formed in limestones exhibiting higher proportion of Fe-oxihydroxides (specifically Řeporyje ls). Presence of free lime and portlandite correlates with decreasing content of non-carbonate material (some varieties of the Dvorce-Prokop ls. from Bráník Rocks).

Kinematic hardening of a porous limestone

NASA Astrophysics Data System (ADS)

Cheatham, J. B.; Allen, M. B.; Celle, C. C.

1984-10-01

A concept for a kinematic hardening yield surface in stress space for Cordova Cream limestone (Austin Chalk) developed by Celle and Cheatham (1981) has been improved using Ziegler's modification of Prager's hardening rule (Ziegler, 1959). Data to date agree with the formulated concepts. It is shown how kinematic hardening can be used to approximate the yield surface for a wide range of stress states past the initial yield surface. The particular difficulty of identifying the yield surface under conditions of unloading or extension is noted. A yield condition and hardening rule which account for the strain induced anisotropy in Cordova Cream Limestone were developed. Although the actual yield surface appears to involve some change of size and shape, it is concluded that true kinematic hardening provides a basis for engineering calculations.

Trepostome and cystoporate bryozoans from the Lexington Limestone and the Clays Ferry Formation (Middle and Upper Ordovician) of Kentucky

USGS Publications Warehouse

Karklins, O.L.

1984-01-01

The Lexington Limestone and the Clays Ferry Formation of Kentucky contain an abundant and diversified fossil invertebrate fauna. This report is concerned with the trepostome and cystoporate bryozoans that constitute a major part of that fauna. The Lexington Limestone, largely a biofragmental fossiliferous limestone, rests disconformably on the Tyrone Limestone (Middle Ordovician). The Clays Ferry Formation consists of approximately equal amounts of biofragmentallimestone and shale, and it overlies conformably, or intertongues with, the upper part of the Lexington Limestone. The Clays Ferry Formation is overlain by the Garrard Siltstone (Upper Ordovician) in central Kentucky and intertongues with the Kope Formation (Upper Ordovician) in northern Kentucky. The MiddleUpper Ordovician boundary falls within the upper part of the Lexington Limestone and laterally equivalent strata of the Clays Ferry Formation. The Lexington Limestone has been divided into 12 members, consisting of calcarenites, calcisiltites, calcilutites, nodular limestones, and shales in various amounts, that intertongue complexly. Because of the great abundance of bryozoans this study is generally limited to bryozoans recovered from, in ascending order, the Grier Limestone Member, the Perryville Limestone Member, the Brannon Member, the Tanglewood Limestone Member, and the Millersburg Member of the Lexington Limestone and from the Clays Ferry Formation and its Point Pleasant Tongue. The trepostome and cystoporate bryozoans discussed are referred to 36 species belonging to 22 genera. The trepostome component includes 29 species belonging to 16 genera: Amplexopora, Atactoporella, Balticopora, Batostoma, Cyphotrypa, Dekayia, Eridotrypa, Hetero-_ trypa, Homotrypa, Homotrypella, Mesotrypa, Parvohallopora, Peronopora, Prasopora, Stigmatella, and Tarphophragma, a new genus. Five of the trepostome species are new: Balticopora arcuatilis, Cyphotrypa switzeriensis, Dekayia epetrima, Eridotrypa sadievillensis, and Homotrypa cressmani. The cystoporate bryozoans include 7 species belonging to 6 genera: Acanthoceramoporella, Ceramophylla, Ceramoporella, Constellaria, Crepipora, and Papillalunaria. One cystoporate species is new: Acanthoceramoporella valliensis. The trepostome and cystoporate fauna on the generic level is, with few exceptions, cosmopolitan. Five genera, Eridotrypa, Parvohallopora, Heterotrypa, Constellaria, and Peronopora, dominate the fauna, comprising about 77 percent of the thin-sectioned specimens. On the species level the fauna is endemic to the Ordovician of eastern North America and is biostratigraphically restricted to strata of late Blackriveran Stage (Middle Ordovician) to early Maysvillian Stage (middle Late Ordovician). In Kentucky the species of this fauna are restricted to strata between the base of the Lexington Limestone (Kirkfieldian Stage, Middle Ordovician) and the top of the Clays Ferry Formation and its lateral equivalent the Kope Formation (Edenian Stage, lower Upper Ordovician), with few species ranging into strata of early Maysvillian Stage (middle Late Ordovician) in adjacent areas of Indiana and Ohio. On the basis of the known geographic distribution of the various species, the fauna in Kentucky consists of an intermingling of immigrant and endemic species. The immigrant component (11 species) is generally limited to the lower half of the Lexington-Clays Ferry depositional sequence and permits the establishment of a degree of biostratigraphic equivalence with outcrop areas in Minnesota-Iowa and New York. On the species level the fauna in Kentucky is dominated by four: Constellaria teres, Heterotrypa foliacea, Parvohallopora nodulosa, and Eridotrypa mutabilis, in decreasing relative abundance. The first three species are restricted to the upper part of the Lexington Limestone and the Clays Ferry Formation. Eridotrypa mutabilis is restricted to the middle part of the Lexington Limestone and the lower half of the Clays Fer

Downflow limestone beds for treatment of net-acidic, oxic, iron-laden drainage from a flooded Anthracite Mine, Pennsylvania, USA: 1. Field evaluation

USGS Publications Warehouse

Cravotta, C.A.; Ward, S.J.

2008-01-01

Passive-treatment systems that route acidic mine drainage (AMD) through crushed limestone and/or organic-rich substrates have been used to remove the acidity and metals from various AMD sources, with a wide range of effects. This study evaluates treatment of net-acidic, oxic, iron-laden AMD with limestone alone, and with organic-rich compost layered with the limestone. In the fall of 2003, a treatment system consisting of two parallel, 500-m2 downflow cells followed by a 400-m2 aerobic settling pond and wetland was installed to neutralize the AMD from the Bell Mine, a large source of AMD and baseflow to the Schuylkill River in the Southern Anthracite Coalfield, in east-central Pennsylvania. Each downflow cell consisted of a lower substrate layer of 1,090 metric tons (t) of dolomitic limestone (60 wt% CaCO3) and an upper layer of 300 t of calcitic limestone (95 wt% CaCO3); one of the downflow cells also included a 0.3 m thick layer of mushroom compost over the limestone. AMD with pH of 3.5-4.3, dissolved oxygen of 6.6-9.9 mg/L, iron of 1.9-5.4 mg/L, and aluminum of 0.8-1.9 mg/L flooded each cell to a depth 0.65 m above the treatment substrates, percolated through the substrates to underlying, perforated outflow pipes, and then flowed through the aerobic pond and wetland before discharging to the Schuylkill River. Data on the flow rates and chemistry of the effluent for the treatment system indicated substantial neutralization by the calcitic limestone but only marginal effects from the dolomitic limestone or compost. Because of its higher transmissivity, the treatment cell containing only limestone neutralized greater quantities of acidity than the cell containing compost and limestone. On average, the treatment system removed 62% of the influent acidity, 47% of the dissolved iron, 34% of the dissolved aluminum, and 8% of the dissolved manganese. Prior to treatment of the Bell Discharge, the Schuylkill River immediately below its confluence with the discharge had pH as low as 4.1 and supported few, if any, fish. However, within the first year of treatment, the pH was maintained at values of 5.0 or greater and native brook trout were documented immediately below the treatment system, though not above. ?? 2008 Springer-Verlag.

Effects of MERV 16 filters and routine work practices on enclosed cabs for reducing respirable dust and DPM exposures in an underground limestone mine

PubMed Central

Noll, J.D.; Cecala, A.B.; J.A.Organiscak; Rider, J.P.

2015-01-01

An effective technique to minimize miners’ respirable dust and diesel exposure on mobile mining equipment is to place mine operators in enclosed cabs with designed filtration and pressurization systems. Many factors affect the performance of these enclosed cab systems, and one of the most significant factors is the effectiveness of the filtration system. High-efficiency particulate air (HEPA)-type filters are typically used because they are highly efficient at capturing all types and sizes of particles, including those in the submicron range such as diesel particulate matter (DPM). However, in laboratory tests, minimum efficiency reporting value (MERV) 16 filters have proven to be highly efficient for capturing DPM and respirable dust. Also, MERV 16 filters can be less restrictive to cab airflow and less expensive than HEPA filters. To verify their effectiveness in the field, MERV 16 filters were used in the enclosed cab filtration system on a face drill and roof bolting mining machine and tested at an underground limestone mine. Test results showed that DPM and respirable dust concentrations were reduced by more than 90% when the cabs were properly sealed. However, when the cab door was opened periodically throughout the shift, the reduction efficiency of the MERV 16 filters was reduced to 80% on average. PMID:26236044

Uranium in the Mayoworth area, Johnson County, Wyoming - a preliminary report

USGS Publications Warehouse

Love, J.D.

1954-01-01

The uranium mineral, metatyuyamunite, occurs in the basal limestone of the Sundance formation of late Jurassic age along the east flank of the Bighorn Mountains, about 2 miles southwest of the abandoned Mayoworth post office. This occurrence is of particular interest because it is the first uranium mineralization reported from a marine limestone in Wyoming. The discovery uranium claims were filed in July 1953, by J.S. Masek, Dan Oglesby, and Jack Emery of Casper, Wyo. Subsequent reconnaissance investigations have been made by private individuals and geologists of the U.S. Geological Survey and Atomic Energy Commission. The metatyuyamunite is concentrated in a hard gray oolitic limestone that forms the basal bed of the Sundance formation. A selected sample of limestone from a fresh face in the northernmost deposit known at the time of the field examination contained 0.70 percent equivalent uranium and 0.71 percent uranium. Eight samples of the limestone taken at the sample place by the Atomic Energy Commission contained from 0.007 to 0.22 percent uranium. A chip sample from the weathered outcrop at the top of this limestone half a mile to the southeast contained 0.17 percent equivalent uranium and 0.030 percent uranium. A dinosaur bone from the middle part of the Morrison formation contained 0.044 percent equivalent uranium and 0.004 percent uranium. metatyuyamunite forms a conspicuous yellow coating along fracture planes cutting the oolitic limestone and has also replaced many of the oolites within the solid limestone and has also replaced many of the oolites within the solid limestone even where fractures are not present. Many radioactive spots in the basal limestone of the Sundance formation were examined in a reconnaissance fashion along the outcrop for a distance of half a mile south of the initial discovery. Samples were taken for analysis only at the northern and southern margins of this interval. Outcrops farther north and south were not studied. There are not sufficient data to make even rough estimates of tonnage and grade of the occurrences. The extent of the limestone, the approximate boundaries of the area of above-normal radioactivity, and the possibilities of other radioactive zones have not been thoroughly investigated. Although dinosaur bones in the Morrison formation were radioactive wherever they were tested, no significant amount of radioactivity was observed in rocks adjacent to the bones.

Nomination of the Globigerina Limestone of the Maltese Islands as a "Global Heritage Stone Resource"

NASA Astrophysics Data System (ADS)

Cassar, JoAnn

2016-04-01

The Maltese Islands consist of two main islands, Malta and Gozo, as well as a small number of islets, and lie in the central Mediterranean Sea approximately 90 km south of Sicily. Although only 316 square kilometres in size, the Islands contain a rich concentration of archaeological sites and historic buildings, as well as vernacular architecture and modern buildings, for the most part built of the local Globigerina Limestone, which is one of the few natural resources of the Islands. This stone can be described as a typical "soft limestone", very easy to carve and shape. It forms part of the large family of Oligo-Miocene "soft limestones" widely diffused in the Mediterranean Basin. The Maltese Globigerina Limestone Formation is one of five main Formations, and varies in thickness from 20 to over 200 m. The material used for building is located stratigraphically in the lower part of the Globigerina Limestone Formation, called the Lower Globigerina Limestone. This Formation is stratified into thick beds at outcrop. Sections where bioturbation is concentrated often also occur. This limestone is fine-grained, yellow to pale grey in colour, almost wholly composed of the tests of globigerinid planktonic foraminifera. Petrographically, Globigerina Limestone can be described as a bioclastic packstone, with bioclastic wackestones also occurring. This limestone has always been used as the predominant building material in the Islands. The Maltese prehistoric Temples, which were constructed approximately 6000 years ago, bear testimony to this. Between 1530 and 1798 the Order of the Knights of St John built kilometres of fortifications in this same material to protect the Island from the expanding Ottoman Empire. Fortifications, impressive churches, auberges and palaces were built of this stone during this period. The capital city of Valletta, a rich and dense manifestation of Baroque architecture in Globigerina Limestone, is included on the UNESCO World Heritage List, as are the prehistoric Temples. Even today, this local building stone is still much in demand, with many modern buildings still being constructed in this material; it is also widely used for the repair and restoration of historic buildings and many local quarries are still active, with this stone even today being a keystone of the local economy. This stone is thus being nominated as a suitable "Global Heritage Stone Resource".

Hydrogeologic evaluation of the Upper Floridan aquifer in the southwestern Albany area, Georgia

USGS Publications Warehouse

Warner, Debbie

1997-01-01

A cooperative study by the Albany Water, Gas, and Light Commission and the U.S. Geological Survey was conducted to evaluate the hydrogeology of the Upper Floridan aquifer in an area southwest of Albany and west of the Flint River in Dougherty County, Ga. The study area lies in the Dougherty Plain district of the Coastal Plain physiographic province. In this area, the Upper Floridan aquifer is comprised of the upper Eocene Ocala Limestone, confined below by the middle Eocene Lisbon Formation, and semiconfined above by the undifferentiated Quaternary overburden. The overburden ranges in thickness from about 30 to 50 feet and consists of fine to coarse quartz sand, clayey sand, sandy clay, and clay. The Upper Floridan aquifer has been subdivided into an upper water-bearing zone and a lower water-bearing zone based on differences in lithology and yield. In the study area, the upper water-bearing zone generally consists of dense, highly weathered limestone of low permeability and ranges in thickness from 40 to 80 feet. The lower water-bearing zone consists of hard, slightly weathered limestone that exhibits a high degree of secondary permeability that has developed along fractures and joints, and ranges in thickness from about 60 to 80 feet. Borehole geophysical logs and borehole video surveys indicate two areas of high permeability in the lower water-bearing zone-one near the top and one near the base of the zone. A wellfield consisting of one production well and five observation-well clusters (one deep, intermediate, and shallow well in each cluster) was constructed for this study. Spinner flowmeter tests were conducted in the production well between the depths of 110 and 140 feet below land surface to determine the relative percentages of water contributed by selected vertical intervals of the lower water-bearing zone. Pumping rates during these tests were 1,080, 2,200, and 3,400 gallons per minute. The results of these pumping tests show that the interval between 118 and 124 feet below land surface contributes a significant percentage of the total yield to the well. An aquifer test was conducted by pumping the production well at a constant rate of 3,300 gallons per minute for about 49 hours. Time-dependent water-level data were collected throughout the pumping and recovery phases of the test in the pumped well and the observation wells. The maximum measured drawdown in the observation wells was about 2.6 ft. At about 0.5 mile from the pumped well, there was little measurable effect from pumping. Water levels increased during the test in wells located within about 3.75 miles of the Flint River (about 0.5 miles east of the pumping well). This water-level increase correlated with a 3.5-feet increase in the stage of the Flint River. The hydraulic characteristics of the Upper Floridan aquifer were evaluated using the Hantush-Jacob curve-matching and Jacob straight-line methods. Using the Hantush-Jacob method, values for transmissivity ranged from about 120,000 to 506,000 feet squared per day; values for storage coefficient ranged from 1.4 x 10-4 to 6.3 x 10-4; and values for vertical hydraulic conductivity of the overlying sediments ranged from 4.9 to 6.8 feet per day. Geometric averages for these values of transmissivity, storage coefficient, and vertical hydraulic conductivity were calculated to be 248,000 feet squared per day, 2.7 x 10-4, and 5.5 feet per day, respectively. If a dual porosity aquifer model (fracture flow plus matrix flow) is assumed instead of leakage, and the Jacob straight-line method is used with late time-drawdown data, the calculated transmissivity of the fractures ranged from about 233,000 to 466,000 feet squared per day; and storage coefficient of the fractures plus the matrix ranged from 5.1 x 10-4 to 2.9 x 10-2.

Pathogen and chemical transport in the karst limestone of the Biscayne aquifer: 1. Revised conceptualization of groundwater flow

USGS Publications Warehouse

Renken, Robert A.; Cunningham, Kevin J.; Shapiro, Allen M.; Harvey, Ronald W.; Zygnerski, Michael R.; Metge, David W.; Wacker, Michael A.

2008-01-01

The Biscayne aquifer is a highly transmissive karst limestone that serves as the sole source of drinking water to over two million residents in south Florida. The aquifer is characterized by eogenetic karst, where the most transmissive void space can be an interconnected, touching‐vug, biogenically influenced porosity of biogenic origin. Public supply wells in the aquifer are in close proximity to lakes established by surface mining. The mining of the limestone has occurred to the same depths as the production wells, which has raised concerns about pathogen and chemical transport from these surface water bodies. Hydraulic and forced gradient tracer tests were conducted to augment geologic and geophysical studies and to develop a hydrogeologic conceptual model of groundwater flow and chemical transport in the Biscayne aquifer. Geologic and geophysical data indicate multiple, areally extensive subhorizontal preferential flow zones of vuggy limestone separated by rock with a matrix pore system. The hydraulic response from an aquifer test suggests that the Biscayne aquifer behaves as a dual‐porosity medium; however, the results of the tracer test showed rapid transport similar to other types of karst. The tracer test and concurrent temperature logging revealed that only one of the touching‐vug flow zones dominates transport near the production wells. On the basis of the rising limb of the breakthrough curve, the dispersivity is estimated to be less than 3% of the tracer travel distance, which suggests that the fastest flow paths in the formation are likely to yield limited dilution of chemical constituents.

Salt weathering in Egyptian limestone after laboratory simulations with continuous flow of salt solutions at different temperatures

NASA Astrophysics Data System (ADS)

Aly, Nevin; Gomez-Heras, Miguel; Hamed, Ayman; Alvarez de Buergo, Monica

2013-04-01

weathering in Egyptian limestone after laboratory simulations with continuous flow of salt solutions at different temperatures Nevin Aly Mohamed (1), Miguel Gomez - Heras(2), Ayman Hamed Ahmed (1), and Monica Alvarez de Buergo(2). (1) Faculty of Pet. & Min. Engineering- Suez Canal University, Suez, Egypt, (2) Instituto de Geociencias (CSIC-UCM) Madrid. Spain. Limestone is one of the most frequent building stones in Egypt and is used since the time of ancient Egyptians and salt weathering is one of the main threats to its conservation. Most of the limestone used in historical monuments in Cairo is a biomicrite extracted from the Mid-Eocene Mokattam Group. During this work, cylindrical samples (2.4 cm diameter and approx. 4.8 cm length) were subjected, in a purpose-made simulation chamber, to simulated laboratory weathering tests with fixed salt concentration (10% weight NaCl solution), at different temperatures, which were kept constant throughout each test (10, 20, 30, 40 oC). During each test, salt solutions flowed continuously imbibing samples by capilarity. Humidity within the simulation chamber was reduced using silica gel to keep it low and constant to increase evaporation rate. Temperature, humidity inside the simulation chamber and samples weight were digitally monitored during each test. Results show the advantages of the proposed experimental methodology using a continuous flow of salt solutions and shed light on the effect of temperature on the dynamics of salt crystallization on and within samples. Research funded by mission sector of high education ministry, Egypt and Geomateriales S2009/MAT-1629.

Selected data on characteristics of glacial-deposit and carbonate-rock aquifers, midwestern basins and arches region

USGS Publications Warehouse

Joseph, R.L.; Eberts, S.M.

1994-01-01

In 1988, the Geological Survey (USGS) began study to examine the hydrogeologic framework, ground-water-flow systems, water chemistry, and withdrawal response of aquifers in glacial deposits and carbonate rock in the Midwestern Basins and Arches Region in western Ohio and eastern Indiana. As part of this study, data from pumped-well tests and instantaneous-rechange tests (slug tests) of wells completed in the glacial-deposit and carbonate-rock aquifers were compiled from reports and information on file with State agencies, environmental consulting firms, drilling firms, municipalities, universities, and the USGS. The data, from 73 counties in Ohio and Indiana, were entered into a computerized data base in a spreadsheet format and subsequently into a geographic information system (GIS). Aquifer-characteristics data from this compilation include the results of 105 pumped-well tests and 39 slug tests in wells completed in glacial deposits, 174 pumped-well tests in wells completed in the carbonate-rock aquifer, and 4 slug tests in wells completed in limestones and shales of Ordovician age. Transmissivities from the pumped-well tests in wells completed in glacial till and glacial-deposit aquifers (sands and gravels) range from 1.54 to 69,700 feet squared per day. Storage coefficients or specific yields range from 0.00002 to 0.38 at these wells. Horizontal-hydraulic conductivities from the slug tests in wells completed in glacial-deposit aquifers range from 0.33 to 1,000 feet per day. Transmissivities from the pumped-well tests in wells completed in the carbonate-rock aquifer range from 70 to 52,000 feet squared per day. Storage coefficient or specific yields at these wells range from 0.00001 to 0.05. Horizontal hydraulic conductivities from the slug tests in wells completed in limestones and shales of Ordovician age range from 0.0016 to 12 feet per day. These data are summarized in tables and figures within this report. The collection and compilation of selected aquifer-characteristic data for the glacial-deposit and carbonate-rock aquifers within the Midwestern Basin and Arches Region of Shaver (1985) are an essential part of the Midwestern Basins and Arches Regional Aquifer-Systems Analysis (Midwestern Basins and Arches RASA) project of the U.S. Geological Survey (USGS). Specifically, the data are needed to help describe ground-water flow in the regional aquifer system, which isone of the objectives of the Midwestern Basins and Arches RASA project (Bugliosi, 1990). To meet this objective, the Midwestern Basins and Arches RASA began subprojects in the Ohio and Indiana offices of the USGS to collect and compile available aquifer-characteristics data from aquifer tests of the glacial-deposit and carbonate-rock aquifers. The data were not reanalyzed to verify accuracy because of time constraints and insufficient data in many cases.

Soro West: A non-seismically defined, fault cut-off prospect in the Papuan Fold and Thrust Belt, Papua New Guinea

DOE Office of Scientific and Technical Information (OSTI.GOV)

Robinson, W.F.; Swift, C.M. Jr.

Soro West is a fault cut-off prospect located in the frontal portion of the Papuan Fold and Thrust Belt. Prospective Toro and Imburu sandstones are interpreted to be in the hanging wall of the Soro Thrust. Truncation against the thrust, both updip and through lateral ramps, provides the trapping mechanism. The Soro West Prospect was defined using geological, geochemical, remote sensing, and geophysical data. The definition and location of the trap is a primary risk and work was focused on this aspect. Surface geological data (lithology, strikes, and dips) topography and synthetic aperture radar imagery were incorporated into the evaluation.more » Statistical curvature analysis techniques helped define the shape of the structure and the locations of the lateral ramps. Strontium isotope analyses of Darai Limestone surface samples refined erosional levels using a locally-derived reference curve. Severe karst precludes the acquisition of coherent surface seismic data, so the primary geophysical tool used was magnetotellurics (MT). A detailed, pre-survey feasibility study defined expected responses from alternative structural models. The MT data demonstrated that the limestone at surface is underlain by thick conductive clastics and not another Darai Limestone sheet. The data also constrained the range of fault cut-off positions significantly. Multiple, three-dimensionally consistent, restorable alternative structural models were created using results from all analyses. These led to a positive assessment of the prospect and an exploratory test is to be drilled in 1996.« less

Geohydrology and evaluation of water-resource potential of the upper Floridan Aquifer in the Albany area, southwestern Georgia

USGS Publications Warehouse

Torak, L.J.; Davis, G.S.; Strain, G.A.; Herndon, J.G.

1993-01-01

In the Albany area of southwestern Georgia, the Upper Floridan aquifer lies entirely within the Dougherty Plain district of the Coastal Plain physiographic province, and consists of the Ocala Limestone of late Eocene age. The aquifer is divided throughout most of the study area into an upper and a lower lithologic unit, which creates an upper and a lower water-bearing zone. The lower waterbearing zone consists of alternating layers of sandy limestone and medium-brown, recrystallized dolomitic limestone, and ranges in thickness from about 50 ft to 100 ft. It is highly fractured and exhibits well-developed permeability by solution features that are responsible for transmitting most of the ground water in the aquifer. Transmissivity of the lower water-bearing zone ranges from about 90,000 to 178,000 ft2/d. The upper water-bearing zone is a finely crystallized-to-oolitic, locally dolomitic limestone having an average thickness of about 60 ft. Transmissivities are considerably less in the upper water-bearing zone than in the lower water-bearing zone. The Upper Floridan aquifer is overlain by about 20-120 ft of undifferentiated overburden consisting of fine-to-coarse quartz sand and noncalcareous clay. A clay zone about 10-30 ft thick may be continuous throughout the southwestern part of the Albany area and, where present, causes confinement of the Upper Floridan aquifer and creates perched ground water after periods of heavy rainfall. The Upper Floridan aquifer is confined below by the Lisbon Formation, a mostly dolomitic limestone that contains trace amounts of glauconite. The Lisbon Formation is at least 50 ft thick in the study area and acts as an impermeable base to the Upper Floridan aquifer. The quality of ground water in the Upper Floridan aquifer is suitable for most uses; wells generally yield water of the hard, calcium-bicarbonate type that meets the U.S. Environmental Protection Agency's Primary or Secondary Drinking-Water Regulations. The water-resource potential of the Upper Floridan aquifer was evaluated by compiling results of drilling and aquifer testing in the study area, and by conducting computer simulations of the ground-water flow system under the seasonally low conditions of November 1985, and under conditions of pumping within a 12-mi 2 area located southwest of Albany. Results of test drilling, aquifer testing, and water-quality analyses indicate that, in the area southwest of Albany, geohydrologic conditions in the Upper Floridan aquifer, undifferentiated overburden, and Lisbon Formation were favorable for the aquifer to provide a large quantity of water without having adverse effects on the groundwater system. The confinement of the Upper Floridan aquifer by the undifferentiated overburden and the rural setting of the area of potential development decrease the likelihood that chemical constituents will enter the aquifer during development of the ground-water resources. Computer simulations of ground-water flow in the Upper Floridan aquifer, incorporating conditions for regional flow across model boundaries, leakage from rivers and other surface-water features, and vertical leakage from the undifferentiated overburden, were conducted by using a finite-element model for ground-water flow in two dimensions. Comparison of computed and measured water levels in the Upper Floridan aquifer for November 1985 at 74 locations indicated that computed water levels generally were within 5 ft of the measured values, which is the accuracy to which measured water levels were known. Water-level altitudes ranged from about 260 ft to 130 ft above sea level in the study area during calibration. Aquifer discharge to the Flint River downstream from the Lake Worth dam was computed by the calibrated model to be about 1 billion gallons per day; about 300 million gallons per day (Mgal/d) greater than was measured for similar lowflow conditions. The excess computed discharge was attributed partially to stream withdrawals for

Morphological evaluation of heterogeneous oolitic limestone under pressure and fluid flow using X-ray microtomography

NASA Astrophysics Data System (ADS)

Zhang, Yihuai; Lebedev, Maxim; Al-Yaseri, Ahmed; Yu, Hongyan; Nwidee, Lezorgia N.; Sarmadivaleh, Mohammad; Barifcani, Ahmed; Iglauer, Stefan

2018-03-01

Pore-scale analysis of carbonate rock is of great relevance to the oil and gas industry owing to their vast application potentials. Although, efficient fluid flow at pore scale is often disrupted owing to the tight rock matrix and complex heterogeneity of limestone microstructures, factors such as porosity, permeability and effective stress greatly impact the rock microstructures; as such an understanding of the effect of these variables is vital for various natural and engineered processes. In this study, the Savonnières limestone as a carbonate mineral was evaluated at micro scales using X-ray micro-computed tomography at high resolutions (3.43 μm and 1.25 μm voxel size) under different effective stress (0 MPa, 20 MPa) to ascertain limestone microstructure and gas permeability and porosity effect. The waterflooding (5 wt% NaCl) test was conducted using microCT in-situ scanning and nanoindentation test was also performed to evaluate microscale geomechanical heterogeneity of the rock. The nanoindentation test results showed that the nano/micro scale geomechanical properties are quite heterogeneous where the indentation modulus for the weak consolidated area was as low as 1 GPa. We observed that the fluid flow easily broke some less-consolidated areas (low indentation modulus) area, coupled with increase in porosity; and consistent with fines/particles migration and re-sedimentation were identified, although the effective stress showed only a minor effect on the rock microstructure.

Thermo-poroelastic response of an argillaceous limestone

NASA Astrophysics Data System (ADS)

Selvadurai, Patrick; Najari, Meysam

2016-04-01

Argillaceous limestones are now being considered by many countries that intend to develop deep geologic storage facilities for siting both high-level and intermediate- to low-level nuclear fuel wastes. In deep geologic settings for high level nuclear wastes, the heating due to radioactive decay is transmitted through an engineered barrier, which consists of the waste container and an engineered geologic barrier, which consists of an encapsulating compacted bentonite. The heat transfer process therefore leads to heating of the rock mass where the temperature of the rock is substantially lower than the surface temperature of the waste container. This permits the use of mathematical theories of poroelastic media where phase transformations, involving conversion of water to a vapour form are absent. While the thermo-poroelastic responses of geologic media such as granite and porous tuff have been investigated in the literature, the investigation of thermo-poroelastic responses of argillaceous limestones is relatively new. Argillaceous limestones are considered to be suitable candidates for siting deep geologic repositories owing to the ability to accommodate stress states with generation of severe defects that can influence their transmissivity characteristics. Also the clay fraction in such rocks can contribute to long term healing type phenomena, which is a considerable advantage. This research presents the results of a laboratory investigation and computational modelling of the same that examines the applicability of the theory of thermo-poroelasticity, which extend Biot's classical theory of poroelasticity to include uncoupled heat conduction. The experimental configuration involves the boundary heating of a cylinder of the Cobourg Limestone from southern Ontario, Canada. The cylinder measuring 150 mm in diameter and 278 mm in length contains an axisymmetric fluid-filled cylindrical cavity measuring 26 mm in diameter and 139 mm in length. Thermo-poroelastic effects are induced by instantaneously raising the boundary temperature of the cylinder from 25oC to either 40oC or 60oC. The thermo-poroelastic effects will lead to the generation of pore fluid pressures in the sealed cavity. The cavity fluid pressures will increase with time and will decay as the excess pressure diffuse into the argillaceous limestone. This pressure pulse signature is used to validate the applicability of a thermo-hydro-mechanical model, where the mechanical, physical and flow parameters used have been determined form separate tests. The correlation between the experimental results and the computational predictions are also assessed in terms of a sensitivity study where ranges of estimates are assigned for parameters with critical influences. _____________________________________________ 1 William Scott Professor and James McGill Professor 2 Post Doctoral Fellow

Acid neutralization within limestone sand reactors receiving coal mine drainage

USGS Publications Warehouse

Watten, B.J.; Sibrell, P.L.; Schwartz, M.F.

2005-01-01

Pulsed bed treatment of acid mine drainage (AMD) uses CO2 to accelerate limestone dissolution and intermittent fluidization to abrade and carry away metal hydrolysis products. Tests conducted with a prototype of 60 L/min capacity showed effective removal of H+ acidity over the range 196-584 mg/L (CaCO3) while concurrently generating surplus acid neutralization capacity. Effluent alkalinity (mg/L CaCO3) rose with increases in CO2 (DC, mg/L) according to the model Alkalinity = 31.22 + 2.97(DC)0.5, where DC was varied from 11-726 mg/L. Altering fluidization and contraction periods from 30 s/30 s to 10 s/50 s did not influence alkalinity but did increase energy dissipation and bed expansion ratios. Field trials with three AMD sources demonstrated the process is capable of raising AMD pH above that required for hydrolysis and precipitation of Fe3+ and Al3+ but not Fe2+ and Mn2+. Numerical modeling showed CO2 requirements are reduced as AMD acidity increases and when DC is recycled from system effluent. ?? 2005 Elsevier Ltd. All rights reserved.

A remarkable sea-level drop and relevant biotic responses across the Guadalupian-Lopingian (Permian) boundary in low-latitude mid-Panthalassa: Irreversible changes recorded in accreted paleo-atoll limestones in Akasaka and Ishiyama, Japan

NASA Astrophysics Data System (ADS)

Kofukuda, Daisuke; Isozaki, Yukio; Igo, Hisayoshi

2014-03-01

The Capitanian (Upper Guadalupian) to Wuchiapingian (Lower Lopingian) shallow-marine limestones at Akasaka and Ishiyama in central Japan record unique aspects of the extinction-related Guadalupian-Lopingian boundary (G-LB) interval. The ca. 140 m-thick Akasaka Limestone consists of the Capitanian black limestone (Unit B; 112 m) and the Wuchiapingian light gray dolomitic limestone (Unit W; 21 m), with a black/white striped limestone (Unit S; 9 m) between them. The G-LB horizon is assigned at the base of Unit W, on the basis of the first occurrence of the Wuchiapingian fusulines. The Capitanian Unit B and the Wuchiapingian Unit W were deposited mostly in the subtidal zone of a lagoon, whereas the intervened Unit S and the lowermost Unit W were in the intertidal zone. A hiatus with a remarkable erosional feature was newly identified at the top of Unit S. These records indicate that the sea-level has dropped significantly around the G-LB to have exposed the top of the atoll complex above the sea-level. The Ishiyama Limestone, located ca. 10 km to the north of the Akasaka limestone, retains almost the same depositional records. The extinction of large-tested fusuline (Yabeina) and large bivalves (Alatoconchidae) occurred in the upper part of Unit B, and the overlying 20 m-thick limestone (the uppermost Unit B and Unit S) below the hiatus represents a unique barren interval. The upper half of the barren interval is more depleted in fossils than the lower half, and this likely represents a duration of the severest environmental stress(es) for the shallow-marine protists/animals on the mid-oceanic paleo-atoll complex. Small-tested fusulines re-appeared at the base of Unit W above the hiatus. These facts prove that the elimination of shallow-marine biota occurred during the Capitanian shallowing of Akasaka paleo-atoll before the subaerial exposure/erosion across the G-LB. The overall shallowing and the development of such a clear hiatus at the top of a mid-oceanic seamount, in accordance with the contemporary sea-level curve based on continental shelf records, indicates that a remarkable sea-level drop has occurred globally during the latest Capitanian. This further suggests that a cool climate likely has appeared even in the low-latitude domains in Panthalassa to cause the decline of the Middle Permian shallow-water protists/animals that adapted to warmer seawater. The Wuchiapingian biota first appeared immediately after this erosional episode, i.e., during the onset of warming after the G-LB.

Description and testing of three moisture sensors for measuring surface wetness on carbonate building stones

USGS Publications Warehouse

See, R.B.; Reddy, M.M.; Martin, R.G.

1987-01-01

Three sensors were tested on building stones exposed to conditions that produce deposition of moisture. A relative humidity probe, a gypsum collected circuit grid, and a limestone block resistor were tested as sensors for determining surface wetness. Sensors were tested under laboratory conditions of constant relative humidity and temperature and also under on-site conditions of variable relative humidity and temperature for 8 weeks at Newcomb, New York. Laboratory tests indicated that relative humidity alone did not cause sensors to become saturated. However, relative humidity did control the rate at which sensors dried after being saturated with distilled water. On-site testing of the relative humidity probe and the gypsum coated circuit grid indicated that they respond to a diurnal wetting and drying cycle; the limestone block resistor only responded to rainfall. (Author 's abstract)

Changing Water-Resources on Ile de la Gonave, Haiti

NASA Astrophysics Data System (ADS)

Troester, J. W.

2002-12-01

Ile de la Gonave is a 750-square-kilometer island off the western coast of Haiti. The island is composed of Eocene and Miocene limestones unconformably overlain by Pleistocene limestone. The highest elevation is 778 meters. Annual precipitation varies across the island because of the orographic effect and ranges from 800 to 1,400 millimeters. There is no surface water except immediately after large storms. Droughts, some extending for more than one year, and frequent crop failures due to droughts have been reported. Potential evaporation is estimated to be about 2,000 millimeters at the coast, but less at higher elevations. Consequently most rain is lost through evapotranspiration; recharge to the limestone aquifers apparently occurs only after large storms and is estimated to be about 4 percent of the mean annul precipitation based on a chloride mass balance. Depth to the water table ranges from less than 30 meters in the Eocene and Miocene limestones to over 60 meters in the 300-meter thick Quaternary limestone. Average annual precipitation at Port au-Prince (50 kilometers to the east and on the main island of Hispaniola) has decreased from about 1600 millimeters in 1860's to about 1300 mm in the 1950's. Precipitation data from Port-au-Prince after the 1950's are sporadic, making further comments about climate change difficult. Even without decreasing precipitation, which may be due in part to climate change or the deforestation of Haiti, the increasing population on Ile de la Gonave has and will continue to exacerbate the scarce water supply, particularly because of the small number of sources (springs, cave pools, and wells) where people can obtain water. Women take an average of almost three hours per day to travel an average of 2.5 kilometers (one-way) to obtain water for their families. Because of the difficulties in obtaining freshwater, the 100,000 inhabitants use an average of only 7 to 13 liters per person per day. Reconnaissance field analyses indicate that ground water in the interior of the island is of a calcium-bicarbonate type, while water at the coast is of a sodium-chloride type and has mixed with as much as 20 percent seawater. Tests for the presence of hydrogen sulfide-producing bacteria were negative in most drilled wells, but positive in most capped springs and positive in all springs, cave pools, and hand-dug wells, indicating contamination of most drinking-water sources. Widespread bacterial contamination of the water is not surprising, in that there are few latrines on the island and livestock grazes everywhere, enabling waste to be washed into the drinking water sources. The contaminated drinking water likely causes typhoid fever, which is frequently seen in the one hospital on the island.

Cyclic carbonation calcination studies of limestone and dolomite for CO{sub 2} separation from combustion flue gases - article no. 011801

DOE Office of Scientific and Technical Information (OSTI.GOV)

Senthoorselvan, S.; Gleis, S.; Hartmut, S.

2009-01-15

Naturally occurring limestone and dolomite samples, originating from different geographical locations, were tested as potential sorbents for carbonation/calcination based CO{sub 2} capture from combustion flue gases. Samples have been studied in a thermogravimetric analyzer under simulated flue gas conditions at three calcination temperatures, viz., 750{sup o}C, 875{sup o}C, and 930{sup o}C for four carbonation calcination reaction (CCR) cycles. The dolomite sample exhibited the highest rate of carbonation than the tested limestones. At the third cycle, its CO{sub 2} capture capacity per kilogram of the sample was nearly equal to that of Gotland, the highest reacting limestone tested. At the fourthmore » cycle it surpassed Gotland, despite the fact that the CaCO{sub 3} content of the Sibbo dolomite was only 2/3 of that of the Gotland. Decay coefficients were calculated by a curve fitting exercise and its value is lowest for the Sibbo dolomite. That means, most probably its capture capacity per kilogram of the sample would remain higher well beyond the fourth cycle. There was a strong correlation between the calcination temperature, the specific surface area of the calcined samples, and the degree of carbonation. It was observed that the higher the calcination temperature, the lower the sorbent reactivity. For a given limestone/dolomite sample, sorbents CO{sub 2} capture capacity depended on the number of CCR cycles and the calcination temperature. According to the equilibrium thermodynamics, the CO{sub 2} partial pressure in the calciner should be lowered to lower the calcination temperature. This can be achieved by additional steam supply into the calciner. Steam could then be condensed in an external condenser to single out the CO{sub 2} stream from the exit gas mixture of the calciner. A calciner design based on this concept is illustrated.« less

Preliminary map showing freshwater heads for the Mission Canyon and Lodgepole limestones and equivalent rocks of Mississippian age in the Northern Great Plains of Montana, North Dakota, South Dakota, and Wyoming

USGS Publications Warehouse

Miller, W. Roger; Strausz, S.A.

1980-01-01

A potentiometric-surface map showing freshwater heads for the Mission Canyon and Lodgepole Limestones of Mississippian age has been prepared as part of a study to determine the water-resources potential of the Mississippian Madison Limestone and associated rocks in the Northern Great Plains of Montana, North and South Dakota, and Wyoming. Most of the data used to prepare the map are from drill-stem tests of exploration and development wells drilled by the petroleum industry from 1946 to 1978. Some data are also from cased oil wells, water-production wells, and springs. A short explanation describes the seven categories of reliability used to evaluate the drill-stem-test data and identifies several factors that might explain the apparent anomalous highs and lows on the potentiometric surface. The map is at a scale of 1:1,000,000 and the potentiometric contour intervals are 100, 200, and 500 feet. (USGS)

Oxic limestone drains for treatment of dilute, acidic mine drainage

USGS Publications Warehouse

Cravotta, Charles A.

1998-01-01

Limestone treatment systems can be effective for remediation of acidic mine drainage (AMD) that contains moderate concentrations of dissolved O2 , Fe3+ , or A13+ (1‐5 mg‐L‐1 ). Samples of water and limestone were collected periodically for 1 year at inflow, outflow, and intermediate points within underground, oxic limestone drains (OLDs) in Pennsylvania to evaluate the transport of dissolved metals and the effect of pH and Fe‐ and Al‐hydrolysis products on the rate of limestone dissolution. The influent was acidic and relatively dilute (pH <4; acidity < 90 mg‐L‐1 ) but contained 1‐4 mg‐L‐1 Of O2 , Fe3+ , A13+ , and Mn2+ . The total retention time in the OLDs ranged from 1.0 to 3.1 hours. Effluent remained oxic (02 >1 mg‐L‐1 ) but was near neutral (pH = 6.2‐7.0); Fe and Al decreased to less than 5% of influent concentrations. As pH increased near the inflow, hydrous Fe and Al oxides precipitated in the OLDs. The hydrous oxides, nominally Fe(OH)3 and AI(OH)3, were visible as loosely bound, orange‐yellow coatings on limestone near the inflow. As time elapsed, Fe(OH)3 and AI(OH)3 particles were transported downflow. During the first 6 months of the experiment, Mn 2+ was transported conservatively through the OLDs; however, during the second 6 months, concentrations of Mn in effluent decreased by about 50% relative to influent. The accumulation of hydrous oxides and elevated pH (>5) in the downflow part of the OLDs promoted sorption and coprecipitation of Mn as indicated by its enrichment relative to Fe in hydrous‐oxide particles and coatings on limestone. Despite thick (~1 mm) hydrous‐oxide coatings on limestone near the inflow, CaCO3 dissolution was more rapid near the inflow than at downflow points within the OLD where the limestone was not coated. The rate of limestone dissolution decreased with increased residence time, pH, and concentrations of Ca2+ and HCO3‐ and decreased PCO2. The following overall reaction shows alkalinity as an ultimate product of the iron hydrolysis reaction in an OLD:Fe2+ + 0.25 O2 +CaCO3 + 2.5 H2O --> Fe(OH)3 + 2 Ca2+ + 2 HCO3-where 2 moles of CaCO3 dissolve for each mole of Fe(OH)3 produced. Hence, in an OLD, rapidly dissolving limestone surfaces are not stable substrates for Fe(OH)3 attachment and armoring. Because overall efficiency is increased by combining neutralization and hydrolysis reactions, an OLD followed by a settling pond requires less land area than needed for a two‐stage treatment system consisting of an anoxic limestone drain an oxidation‐settling pond or wetland. To facilitate removal of hydrous‐oxide sludge, a perforated‐pipe subdrain can be installed within an OLD.

A survey of the water resources of St. Croix, Virgin Islands

USGS Publications Warehouse

Jordan, Donald George

1975-01-01

St. Croix consists of two mountainous volcanic rock cores separated by a graben containing clays with minor limestone and conglomerate that is overlain by about 300 feet of marl and limestone. Predominantly fine-grained alluvium mantles much of the limestone and marl area and fills overdeepened south-trending valleys to depths of as much as 100 feet. Rainfall follows an orographic pattern ranging from about 30 inches in eastern St. Croix to 55 inches in the northwestern mountains. Four streams, all heading in the Northside Range, have intermittent reaches. All other streams in St. Croix are ephemeral, flowing only for a few hours or days following major rainstorms. Flow in the intermittent streams ranges from about 1 to 9 percent of the total rainfall and usually half or more of the flow is storm runoff resulting from two or three major storms. Storm runoff from individual storms seldom exceeds 5 percent of the rainfall. Only from 2 storms, one of 5 inches and the other of 7 inches in less than 48 hours, did runoff reach 20 percent, both times on River Gut at Golden Grove. The lack of storm runoff is attributed to the capability of the soil zone to accept large volumes of water and deficient soil moisture most of the year. The dissolved-solids content of the water of St. Croix. reflects the influence of the sea and land. Bulk precipitation is believed to be the source of the initial mineral content of the island water. Additional mineralization, particularly of ground water, results from the solution of soluble salts, mixing with residual sea water, and concentration by evapotranspiration. Water in the volcanic rocks is basically a calcium bicarbonate sodium chloride type with dissolved solids ranging from 500 to 1,000 mg/l (milligrams per liter), and chloride concentration of 100 to 300 mg/1. By contrast, water in the limestone is a sodium bicarbonate sodium chloride type with dissolved-solids content ranging from less than 1,000 to more than 20,000 mg/1 and chloride concentration from less than 100 to more than 10,000 mg/l. The mineral content of water in the limestone invariably increases with depth. Water in the alluvial deposits and in the streams usually reflects the characteristics of water from the adjacent bedrock. The retention of large volumes of rainfall in the soil zone from which it is evaporated and transpired by plants greatly reduces the water available for recharge to the aquifers of the island. Estimates of effective recharge to the aquifers range from less than 0.5 inch in some volcanic and marl rocks to 5 inches annually in more porous limestone and alluvium. Long-term yield from the aquifers is also affected by their storage capacity which may range from less than 1 percent in volcanic rocks and marl to 10 to 15 percent in limestone and alluvium. The ground-water potential (equivalent to the quantity of recharge) of St. Croix is estimated at 3.9 mgd (million gallons per day)--0.9 mgd from the Northside Range (Area 1) ; 0.4 mgd from the East End Range (Area 2), and 2.6 mgd from the central lowlands (Area 3). Most areas where major ground-water supplies are .available, principally in Central St. Croix, have already been developed. The Castle Coakley area, with a potential yield of 400,000 gpd, is the only major ground-water area still undeveloped. The ground-water potential could be increased by reducing the brush and forest cover thus reducing water losses from transpiration; artificial recharge of alluvial aquifer by water spreading; utilizing streamflow (including storm runoff) or treated sewage effluent; or by lowering the ground-water level adjacent to streams to induce infiltration. Advancements in desalination have made the brackish ground water in the Kingshill Marl (estimated at 35 billion recoverable gallons by Robison, 1972) a potential source of water. Recovery of this water would partly de-water the aquifer, which would cause water of better quality in the overlying rocks to

The effects of diagenesis and dolomitization on Ca and Mg isotopes in marine platform carbonates: Implications for the geochemical cycles of Ca and Mg

NASA Astrophysics Data System (ADS)

Fantle, Matthew S.; Higgins, John

2014-10-01

The Ca, Mg, O, and C isotopic and trace elemental compositions of marine limestones and dolostones from ODP Site 1196A, which range in depth (∼58 to 627 mbsf) and in depositional age (∼5 and 23 Ma), are presented. The objectives of the study are to explore the potential for non-traditional isotope systems to fingerprint diagenesis, to quantify the extent to which geochemical proxies are altered during diagenesis, and to investigate the importance of diagenesis within the global Ca and Mg geochemical cycles. The data suggest that Ca, which has a relatively high solid to fluid mass ratio, can be isotopically altered during diagenesis. In addition, the alteration of Ca correlates with the alteration of Mg in such a way that both can serve as useful tools for deciphering diagenesis in ancient rocks. Bulk carbonate δ44Ca values vary between 0.60 and 1.31‰ (SRM-915a scale); the average limestone δ44Ca is 0.97 ± 0.24‰ (1SD), identical within error to the average dolostone (1.03 ± 0.15 1SD ‰). Magnesium isotopic compositions (δ26Mg, DSM-3 scale) range between -2.59‰ and -3.91‰, and limestones (-3.60 ± 0.25‰) and dolostones (-2.68 ± 0.07‰) are isotopically distinct. Carbon isotopic compositions (δ13C, PDB scale) vary between 0.86‰ and 2.47‰, with average limestone (1.96 ± 0.31‰) marginally offset relative to average dolostone (1.68 ± 0.57‰). The oxygen isotopic compositions (δ18O, PDB scale) of limestones (-1.22 ± 0.94‰) are substantially lower than the dolostones measured (2.72 ± 1.07‰). The isotopic data from 1196A suggest distinct and coherent trends in isotopic and elemental compositions that are interpreted in terms of diagenetic trajectories. Numerical modeling supports the contention that such trends can be interpreted as diagenetic, and suggests that the appropriate distribution coefficient (KMg) associated with limestone diagenesis is ∼1 to 5 × 10-3, distinctly lower than those values (>0.015) reported in laboratory studies. With respect to Mg isotopes, the modeling also suggest that diagenetic fractionation factors of ∼0.9955 (-4.5‰) and 0.9980 (-2‰) are appropriate for limestone diagenesis and dolomitization, respectively.

Minimum Temperatures, Diurnal Temperature Ranges and Temperature Inversions in Limestone Sinkholes of Different Sizes and Shapes

DOE Office of Scientific and Technical Information (OSTI.GOV)

Whiteman, Charles D.; Haiden, Thomas S.; Pospichal, Bernhard

2004-08-01

Air temperature data from five enclosed limestone sinkholes of various sizes and shapes on the 1300 m MSL Duerrenstein Plateau near Lunz, Austria have been analyzed to determine the effect of sinkhole geometry on temperature minima, diurnal temperature ranges, temperature inversion strengths and vertical temperature gradients. Data were analyzed for a non-snow-covered October night and for a snow-covered December night when the temperature fell as low as -28.5°C. Surprisingly, temperatures were similar in two sinkholes with very different drainage areas and depths. A three-layer model was used to show that the sky-view factor is the most important topographic parameter controllingmore » cooling for basins in this size range and that the cooling slows when net longwave radiation at the floor of the sinkhole is nearly balanced by the ground heat flux.« less

Evaluation of Different Mineral Filler Aggregates for Asphalt Mixtures

NASA Astrophysics Data System (ADS)

Wasilewska, Marta; Małaszkiewicz, Dorota; Ignatiuk, Natalia

2017-10-01

Mineral filler aggregates play an important role in asphalt mixtures because they fill voids in paving mix and improve the cohesion of asphalt binder. Limestone powder containing over 90% of CaCO3 is the most frequently used type of filler. Waste material from the production of coarse aggregate can be successfully used as a mineral filler aggregate for hot asphalt concrete mixtures as the limestone powder replacement. This paper presents the experimental results of selected properties of filler aggregates which were obtained from rocks with different mineral composition and origin. Five types of rocks were used as a source of the mineral filler aggregate: granite, gabbro, trachybasalt, quartz sandstone and rocks from postglacial deposits. Limestone filler was used in this study as the reference material. The following tests were performed: grading (air jet sieving), quality of fines according to methylene blue test, water content by drying in a ventilated oven, particle density using pyknometer method, Delta ring and ball test, Bitumen Number, fineness determined as Blaine specific surface area. Mineral filler aggregates showed significant differences when they were mixed with bitumen and stiffening effect in Delta ring and ball test was evaluated. The highest values were achieved when gabbro and granite fillers were used. Additionally, Scanning Electron Microscopy (SEM) analysis of grain shape and size was carried out. Significant differences in grain size and shape were observed. The highest non-homogeneity in size was determined for quartz sandstone, gabbro and granite filler. Their Blaine specific surface area was lower than 2800 cm2/g, while for limestone and postglacial fillers with regular and round grains it exceeded 3000 cm2/g. All examined mineral filler aggregates met requirements of Polish National Specification WT-1: 2014 and could be used in asphalt mixtures.

Ground penetrating radar imaging of cap rock, caliche and carbonate strata

USGS Publications Warehouse

Kruse, S.E.; Schneider, J.C.; Campagna, D.J.; Inman, J.A.; Hickey, T.D.

2000-01-01

Field experiments show ground penetrating radar (GPR) can be used to image shallow carbonate stratigraphy effectively in a variety of settings. In south Florida, the position and structure of cap rock cover on limestone can be an important control on surface water flow and vegetation, but larger scale outcrops (tens of meters) of cap rock are sparse. GPR mapping through south Florida prairie, cypress swamp and hardwood hammock resolves variations in thickness and structure of cap rock to ~3 m and holds the potential to test theories for cap rock-vegetation relationships. In other settings, carbonate strata are mapped to test models for the formation of local structural anomalies. A test of GPR imaging capabilities on an arid caliche (calcrete) horizon in southeastern Nevada shows depth penetration to ~2 m with resolution of the base of caliche. GPR profiling also succeeds in resolving more deeply buried (~5 m) limestone discontinuity surfaces that record subaerial exposure in south Florida. (C) 2000 Elsevier Science B.V. All rights reserved.Field experiments show ground penetrating radar (GPR) can be used to image shallow carbonate stratigraphy effectively in a variety of settings. In south Florida, the position and structure of cap rock cover on limestone can be an important control on surface water flow and vegetation, but larger scale outcrops (tens of meters) of cap rock are sparse. GPR mapping through south Florida prairie, cypress swamp and hardwood hammock resolves variations in thickness and structure of cap rock to approx. 3 m and holds the potential to test theories for cap rock-vegetation relationships. In other settings, carbonate strata are mapped to test models for the formation of local structural anomalies. A test of GPR imaging capabilities on an arid caliche (calcrete) horizon in southeastern Nevada shows depth penetration to approx. 2 m with resolution of the base of caliche. GPR profiling also succeeds in resolving more deeply buried (approx. 5 m) limestone discontinuity surfaces that record subaerial exposure in south Florida.

Comparison of Limestone and Ground Fish for Treatment of Nutritional Rickets in Children in Nigeria.

PubMed

Thacher, Tom D; Bommersbach, Tanner J; Pettifor, John M; Isichei, Christian O; Fischer, Philip R

2015-07-01

To determine whether children with calcium-deficiency rickets respond better to treatment with calcium as limestone or as ground fish. Nigerian children with active rickets (n = 96) were randomized to receive calcium as powdered limestone (920 mg of elemental calcium) or ground fish (952 mg of elemental calcium) daily for 24 weeks. Radiographic healing was defined as achieving a score of 1.5 or less on a 10-point scale. The median (range) age of enrolled children was 35 (6-151) months. Of the 88 children who completed the study, 29 (66%) in the ground fish group and 24 (55%) in the limestone group achieved the primary outcome of a radiographic score of 1.5 or less within 6 months (P = .39). The mean radiographic score improved from 6.2 ± 2.4 to 1.8 ± 2.2 in the ground fish group and from 6.3 ± 2.2 to 2.1 ± 2.4 in the limestone group (P = .68 for group comparison). In an intention to treat analysis adjusted for baseline radiographic score, age, milk calcium intake, and serum 25-hydroxyvitamin D concentration, the response to treatment did not differ between the 2 groups (P = .39). Younger age was associated with more complete radiographic healing in the adjusted model (aOR 0.74 [95% CI 0.57-0.92]). After 24 weeks of treatment, serum alkaline phosphatase had decreased, calcium and 25-hydroxyvitamin D increased, and bone mineral density increased in both groups, without significant differences between treatment groups. In children with calcium-deficiency rickets, treatment with calcium as either ground fish or limestone for 6 months healed rickets in the majority of children. Copyright © 2015 The Authors. Published by Elsevier Inc. All rights reserved.

Wolfcampian brachiopods from the Bird Spring Group, Wamp Spring area, Las Vegas Range, Clark County, Nevada ( USA).

USGS Publications Warehouse

Mills, P.C.; Langenheim, R.L.

1987-01-01

The Wamp Spring section of the Bird Spring Group is subdivided into a basal platy limestone member, lower cliff-forming member, and upper cliff-forming member. Triticites, Schwagerina, and Schubertella kingi in the platy limestone member indicate an early Wolfcampian age. Schwagerina, Schubertella kingi, and a distinctive assemblage of brachiopods, similar to the West Texas fauna, indicate that the upper cliff-forming member is late Wolfcampian. The lower cliff-forming member is tentatively assigned to the middle Wolfcampian. The Wamp Spring sequence correlates temporally with the BSe 'formation' of the Bird Spring Group. The fossil-rich upper cliff-forming limestone member includes the new species Pontisia boodi, Crurithyris wampensis, and Calliprotonia(?) n. sp. A, as well as Hustedia culcitula, Crenispirifer(?) sp., Cenorhynchia(?) sp., Kutorginella(?) sp., marginiferids, lyssacine hexactinellid sponges, pleurotomarid and bellerophontid gastropods, cidaroid echinoids, rugose corals, cylindrical cryptostome bryozoans, and nuculids. -from Authors

Age and correlation of the Calera Limestone in the Permanente terrane of northern California

USGS Publications Warehouse

Sliter, William V.; McGann, Mary

1992-01-01

Planktonic foraminifers indicate that outcrops of Calera Limestone from the Permanente terrane in the Franciscan Complex of northern California range in age from possibly as old as Barremian to late Turonian. Underlying black limestone, which is devoid of planktonic foraminifers, presumably is Barremian in age or older. The top of the sequence exposed in major quarries is always faulted. Improved biostratigraphic resolution shows two patterns of missing time intervals. The primary pattern, which is found at all localities and involves missing planktonic foraminiferal zones in the late Aptian to early Albian and the late Albian, is linked to paleoceanographic changes in the Cretaceous Pacific Ocean. The secondary pattern, which is found at the scattered outcrops outside the major quarries and involves missing zones in the Albian and Cenomanian, suggests the results of a common tectonic history related to the accretion of a large seamount.

Condition assessment of a highly porous limestone fortress: damage categories and structural integrity

NASA Astrophysics Data System (ADS)

Török, Ákos; Czinder, Balázs; Farkas, Orsolya; Görög, Péter; Kopecskó, Katalin; Lógó, János; Rozgonyi-Boissinot, Nikoletta; Vásárhelyi, Balázs

2016-04-01

An emblematic monument the Citadella fortress of Budapest has been studied in details to assess the condition of stone structure. The fortress is a large stone structure of 220 m in length and 60 m in width. The height of the porous limestone walls are in between 12-16 metres. The fortress was completed in 1854 but has been partly rebuilt due to changes in function and war related structural damages. The present paper provides an overview of the lithology, weathering forms and structural condition of the fortress related to a forthcoming restoration-reconstruction project. To assess the condition of stone both on site and laboratory analyses were performed. Lithological varieties were documented. Major identified lithotypes are porous oolitic limestone, less porous bioclastic limestone and fine grained highly porous limestone. To identify wet zones portable moisture meter was applied. Surface strength and weathering grade were also assessed using Schmidt hammer and Duroscop. Decay features were diagnosed and mapped. The most common forms are white weathering crusts, scaling and blistering of crusts as well as granular disintegration. Black weathering crusts were also recognized. Laboratory tests were focused on mechanical properties of stones and on mineralogical and chemical compositional analyses. Small samples of stone were collected and tested by optical microscopy, SEM-EDX, XRD and Thermogravimetric analyses. Laboratory analyses proved that the major salt responsible for the damage of external walls is gypsum, although significant amount of halite and hygroscopic salts were found both on the external walls and in the interior parts of the fortress. During structural analyses displacement of walls, tilting and major amount of cracks were recognized. Loss of material and subsidence also caused problems and at some places unstable wall sections were recognized.

Properties, sustainability and elevated temperature behavior of concrete containing Portland limestone cement

NASA Astrophysics Data System (ADS)

El-Hawary, Moetaz; Ahmed, Mahmoud

2017-09-01

The utilization of some type of cheap filler as partial cement replacement is an effective way of improving concrete sustainability. With the recent trends to reduce water to cement ratio and improve compaction, there is no enough space or water for complete hydration of cement. This means that actually, a portion of mixed cement acts as expensive filler. Replacing this portion with cheaper filler that requires less energy to produce is, therefore, beneficial. Crushed limestone is the most promising filler. This work is to investigate the effect of the amount of limestone fillers on the sustainability and the fresh and mechanical properties of the resulting concrete. A rich mix is designed with a low water/cement ratio of 0.4. Lime is introduced as a replacement percentage of cement. Ratios of 0, 10, 20 and 30% were used. Slump, compressive strength, specific gravity and water absorption are evaluated for every mix. In addition, the effect of the amount of lime on the residual strength of concrete subjected to elevated temperatures is also investigated. Samples are subjected to six different temperature stations of 20, 100, 200, 300, 500 and 700°C for six hours before being cooled and subsequently tested for compressive strength and specific gravity. Sustainability of the tested mixes is evaluated through reductions in the emitted carbon dioxide, energy and reduction in cost. Based on the annual use of concrete in Kuwait, the sustainability benefits resulting from the use of limestone filler in Kuwait are evaluated and assessed. The paper is concluded with the recommendation of the use of 15% limestone filler as partial cement replacement where the properties and the behavior under high temperature of the resulting concrete are almost the same as those of conventional concrete with considerable cost and sustainability benefits.

Paleolatitudes of the Tibetan Himalaya from primary and secondary magnetizations of Jurassic to Lower Cretaceous sedimentary rocks

NASA Astrophysics Data System (ADS)

Huang, Wentao; van Hinsbergen, Douwe J. J.; Dekkers, Mark J.; Garzanti, Eduardo; Dupont-Nivet, Guillaume; Lippert, Peter C.; Li, Xiaochun; Maffione, Marco; Langereis, Cor G.; Hu, Xiumian; Guo, Zhaojie; Kapp, Paul

2015-01-01

The Tibetan Himalaya represents the northernmost continental unit of the Indian plate that collided with Asia in the Cenozoic. Paleomagnetic studies on the Tibetan Himalaya can help constrain the dimension and paleogeography of "Greater India," the Indian plate lithosphere that subducted and underthrusted below Asia after initial collision. Here we present a paleomagnetic investigation of a Jurassic (limestones) and Lower Cretaceous (volcaniclastic sandstones) section of the Tibetan Himalaya. The limestones yielded positive fold test, showing a prefolding origin of the isolated remanent magnetizations. Detailed paleomagnetic analyses, rock magnetic tests, end-member modeling of acquisition curves of isothermal remanent magnetization, and petrographic investigation reveal that the magnetic carrier of the Jurassic limestones is authigenic magnetite, whereas the dominant magnetic carrier of the Lower Cretaceous volcaniclastic sandstones is detrital magnetite. Our observations lead us to conclude that the Jurassic limestones record a prefolding remagnetization, whereas the Lower Cretaceous volcaniclastic sandstones retain a primary remanence. The volcaniclastic sandstones yield an Early Cretaceous paleolatitude of 55.5°S [52.5°S, 58.6°S] for the Tibetan Himalaya, suggesting it was part of the Indian continent at that time. The size of "Greater India" during Jurassic time cannot be estimated from these limestones. Instead, a paleolatitude of the Tibetan Himalaya of 23.8°S [21.8°S, 26.1°S] during the remagnetization process is suggested. It is likely that the remagnetization, caused by the oxidation of early diagenetic pyrite to magnetite, was induced during 103-83 or 77-67 Ma. The inferred paleolatitudes at these two time intervals imply very different tectonic consequences for the Tibetan Himalaya.

Remediation of acid mine drainage at the friendship hill national historic site with a pulsed limestone bed process

USGS Publications Warehouse

Sibrell, P.L.; Watten, B.; Boone, T.; ,

2003-01-01

A new process utilizing pulsed fluidized limestone beds was tested for the remediation of acid mine drainage at the Friendship Hill National Historic Site, in southwestern Pennsylvania. A 230 liter-per-minute treatment system was constructed and operated over a fourteen-month period from June 2000 through September 2001. Over this period of time, 50,000 metric tons of limestone were used to treat 50 million liters of water. The influent water pH was 2.5 and acidity was 1000 mg/L as CaCO3. Despite the high potential for armoring at the site, effluent pH during normal plant operation ranged from 5.7 to 7.8 and averaged 6.8. As a result of the high influent acidity, sufficient CO2 was generated and recycled to provide a net alkaline discharge with about 50 mg/L as CaCO3 alkalinity. Additions of commercial CO2 increased effluent alkalinity to as high as 300 mg/L, and could be a useful process management tool for transient high flows or acidities. Metal removal rates were 95% for aluminum (60 mg/L in influent), 50 to 90% for iron (Fe), depending on the ratio of ferrous to ferric iron, which varied seasonally (200 mg/L in influent), and <10% of manganese (Mn) (10 mg/L in influent). Ferrous iron and Mn removal was incomplete because of the high pH required for precipitation of these species. Iron removal could be improved by increased aeration following neutralization, and Mn removal could be effected by a post treatment passive settling/oxidation pond. Metal hydroxide sludges were settled in settling tanks, and then hauled from the site for aesthetic purposes. Over 450 metric tons of sludge were removed from the water over the life of the project. The dried sludge was tested by the Toxicity Characteristics Leaching Protocol (TCLP) and was found to be non-hazardous. Treatment costs were $43,000 per year and $1.08 per m 3, but could be decreased to $22,000 and $0.51 per m3 by decreasing labor use and by onsite sludge handling. These results confirm the utility of the new process in treatment of acid impaired waters that were previously not amenable to low cost limestone treatment.

Damage characterization in dimension limestone cladding using noncollinear ultrasonic wave mixing

NASA Astrophysics Data System (ADS)

McGovern, Megan; Reis, Henrique

2016-01-01

A method capable of characterizing artificial weathering damage in dimension stone cladding using access to one side only is presented. Dolomitic limestone test samples with increasing levels of damage were created artificially by exposing undamaged samples to increasing temperature levels of 100°C, 200°C, 300°C, 400°C, 500°C, 600°C, and 700°C for a 90 min period of time. Using access to one side only, these test samples were nondestructively evaluated using a nonlinear approach based upon noncollinear wave mixing, which involves mixing two critically refracted dilatational ultrasonic waves. Criteria were used to assure that the detected scattered wave originated via wave interaction in the limestone and not from nonlinearities in the testing equipment. Bending tests were used to evaluate the flexure strength of beam samples extracted from the artificially weathered samples. It was observed that the percentage of strength reduction is linearly correlated (R2=98) with the temperature to which the specimens were exposed; it was noted that samples exposed to 400°C and 600°C had a strength reduction of 60% and 90%, respectively. It was also observed that results from the noncollinear wave mixing approach correlated well (R2=0.98) with the destructively obtained percentage of strength reduction.

Design of rock socketed drilled shafts

DOT National Transportation Integrated Search

1998-09-01

Three field load tests of drilled shafts socketed in Burlington limestone were conducted using the Osterberg load cell. The objective of these tests was to compare the shaft capacities obtained from the field load tests with capacities predicted usin...

Moving granular-bed filter development program, Option III: Development of moving granular-bed filter technology for multi-contaminant control. Task 14: Test plan; Topical report

DOE Office of Scientific and Technical Information (OSTI.GOV)

Haas, J.C.; Olivo, C.A.; Wilson, K.B.

1994-04-01

An experimental test plan has been prepared for DOE/METC review and approval to develop a filter media suitable for multi-contaminant control in granular-bed filter (GBF) applications. The plan includes identification, development, and demonstration of methods for enhanced media morphology, chemical reactivity, and mechanical strength. The test plan includes media preparation methods, physical and chemical characterization methods for fresh and reacted media, media evaluation criteria, details of test and analytical equipment, and test matrix of the proposed media testing. A filter media composed of agglomerated limestone and clay was determined to be the best candidate for multi-contaminate control in GBF operation.more » The combined limestone/clay agglomerate has the potential to remove sulfur and alkali species, in addition to particulate, and possibly halogens and trace heavy metals from coal process streams.« less

Description and testing of three moisture sensors for measuring surface wetness on carbonate building stones

USGS Publications Warehouse

See, R.B.; Reddy, M.M.; Martin, R.G.

1988-01-01

Three moisture sensors were tested as a means for determining the surface wetness on carbonate building stones exposed to conditions that produce deposition of moisture. A relative-humidity probe, a gypsum-coated circuit grid, and a limestone-block resistor were tested as sensors for determining surface wetness. Sensors were tested under laboratory conditions of constant relative humidity and temperature and also under on-site conditions of variable relative humidity and temperature for eight weeks at Newcomb, NY. Laboratory tests indicated that relative humidity alone did not cause sensors to become saturated with water. However, the rates of drying indicated by the sensors after an initial saturation were inversely related to the relative humidity. On-site testing of the relative-humidity probe and the gypsum-coated ciruit grid indicated that they respond to a diurnal wetting and drying cycle; the limestone-block resistor responded only to rainfall.

Role of multiple substrates (spent mushroom compost, ochre, steel slag, and limestone) in passive remediation of metal-containing acid mine drainage.

PubMed

Molahid, Verma Loretta M; Mohd Kusin, Faradiella; Madzin, Zafira

2018-01-12

The potential of selected materials in treating metal-rich acid mine drainage (AMD) has been investigated in a series of batch experiment. The efficiencies of both single and mixed substrates under two conditions i.e. low- and high-concentration solutions containing heavy metals were evaluated. Synthetic metal-containing AMD was used in the experiments treated using spent mushroom compost (SMC), ochre, steel slag (SS), and limestone. Different ratios of treatment materials were incorporated in the substrate mix and were tested in an anoxic condition. In the batch test, physicochemical parameters (pH, redox potential, total dissolved solids, conductivity, and Ca concentration) and heavy metals (Fe, Mn, Pb, Zn, and Al) were analysed. The mixed substrates have shown satisfactory performance in increasing pH with increasing Ca concentration and removing metals. It has been found that SS and ochre played an important role in the treatment of AMD. The results showed that the mixed substrates SM1 (i.e. 10% SMC mixed with 20% ochre, 30% steel slag, and 40% limestone) and SM2 (i.e. 20% SMC mixed with 30% ochre, 40% steel slag, and 10% limestone) were effective in increasing the pH from as low as 3.5-8.09, and removing heavy metals with more than 90% removal efficiencies.

Stratigraphy and depositional history of the West Franklin Limestone (Pennsylvanian) in the southernmost part of the Illinois Basin, western Kentucky

DOE Office of Scientific and Technical Information (OSTI.GOV)

King, N.R.

1994-04-01

The West Franklin Limestone in the subsurface of Webster and Union Counties, Kentucky includes 7.5--18m of strata deposited during portions of four depositional cycles in the latest Desmoinesian and earliest Missourian (Pennsylvanian). These cycles began with marine flooding and deposition of limestone, followed by progradation of siliciclastics in three of the four cycles, and ended with emergence. The basal West Franklin is micritic limestone (0.5--3m) that rests on rooted mudstone. Overlying the limestone are siliciclastics (1.5--7m) dominated by red and green claystone that is rooted at the top. Next is a middle limestone zone that includes either a paleokarsted micriticmore » limestone, or a thin bioclastic micritic limestone bed associated with phosphatic shale and locally a second bioclastic micritic limestone. Above that is another siliciclastic interval (4--9m) capped by rooted mudstone and locally a thin coal. The overlying micritic limestone (1.5--2.5m) marks the top of the West Franklin. Depositional events included: (1) marine flooding of an emergent shelf producing the basal limestone; (2) progradation of siliciclastics followed by emergence and paleosol development; (3) marine flooding producing a second limestone; (4) emergence and karstification of erosional remnants of the second limestone; (5) renewed marine flooding depositing shell hash'' limestones and phosphatic shale; (6) progradation of siliciclastics culminating in emergency; and (7) marine flooding producing the upper limestone. Thus, two flooding-emergence cycles are represented by the middle limestone zone. The second, locally-developed shell-hash'' limestone in the middle zone was deposited during the regressive phase of a depositional cycle. All of the other limestones were deposited during transgression.« less

Stratigraphy and depositional environments of the Lower Mississippian Joana Limestone in southern White Pine and northern Lincoln Counties, Nevada

DOE Office of Scientific and Technical Information (OSTI.GOV)

Gilmore, T.J.

1990-04-01

The Lower Mississippian Joana Limestone in the southern Schell Creek and Egan ranges of east-central Nevada is composed of three depositional facies: the unbedded wackestone with grainstone/packstone facies or Facies 1; the bedded wackestone with mudstone facies or Facies 2; and the restricted wackestone, mudstone/shale facies, or Facies 3. Facies 1 is characterized by Waulsortian-type carbonate buildups with massive unbedded wackestone cores, grainstone flanking beds and grainstone/packstone capping units. Facies 2 is characterized by an upward progression of sedimentary bedding types from thinly laminated to large scale trough cross-bedding that indicates a shoaling upward of this facies. Facies 3 ismore » characterized by sparse wackestones, mudstones, and shale which show a decrease in both faunal types and diversity and an increase in fine clastics. The restricted wackestone, mudstone/shale facies grades upward into the Mississippian Chainman Shale. The age of the Joana Limestone is confirmed as late Kinderhookian to early Osagean based primarily on conodonts and foraminifera. In the middle beds of the Joana Limestone, the previously unreported upper Siphonodella crenulata conodont zone occurs which helps correlate the Joana Limestone with regional transgressive/regressive sea level events. Color alteration indices of these conodonts are 1.5 to 2, and occur in the oil generation window. Additionally, oil staining was observed in numerous samples located primarily in the lower half of the formation, represented by Facies 3, the unbedded wackestone with grainstone/packstone facies.« less

Durability assessment of limestone subjected to surface treatments

NASA Astrophysics Data System (ADS)

Theodoridou, Magdalini; Charalambous, Cleopatra; Ioannou, Ioannis

2017-04-01

Weathering is inevitable in existing limestone structures due to their exposure to fluctuating and aggressive environmental conditions, such as wetting/drying, and the presence of salts. Therefore, conservation treatments are often deemed necessary in order to prevent or at least delay the progress of deterioration and to strengthen weathered stones. This paper focuses on the effect of an ethanol-based laboratory produced water repellent and three water-based commercial products (water repellent, pure acrylic emulsion mixed with a water repellent with thermal insulation properties and consolidant) on the durability and other properties of three different types of limestone (massive chalk, calcarenite and bioclastic limestone). All test specimens were subjected to micro-destructive cutting tests before/after the application of the aforementioned surface treatments to investigate changes in resistance to cutting on the area close to the treated surface. They were also subjected to two cycles of salt contamination with 20% w/w Na2SO4•10H2O solution by capillary absorption through their bottom face, until 2 mm of pore space was theoretically filled with salt crystals. Drying after salt contamination took place at 70 °C. The results of the micro-destructive cutting tests showed increases in cutting resistance at the topmost area (1-2 mm below the treated surface) of the massive chalk and the calcarenite, but no significant changes in the case of the rather non-homogeneous bioclastic limestone. At the same time, the performance of each surface treatment varied from lithotype to lithotype. The laboratory produced water repellent showed a generally better performance; no signs of damage were detected due to the formation of salt crystals within the pores of the materials, i.e. subflorescence, when applied on the calcarenite and the bioclastic limestone. Very poor performance was observed for all treatments when applied on the massive chalk. This accounted for (i) intense salt efflorescence, (ii) blistering, (iii) cracking and detachment of stone surface material due to subflorescence and (iv) cracking of the vertical sides. The calcarenite proved to be more durable than the other two lithotypes under investigation, with the treated samples showing no sign of damage whatsoever. Nevertheless, the two commercial water repellents proved to be inappropriate for the bioclastic limestone, since more severe damage in the form of multiple cracking was observed to the treated sample, compared with the untreated one. In all the cases, the damage observed is attributed to the suppression of stage I drying by the surface treatments applied; this leads to evaporation of the salt solution mainly by vapour phase diffusion through the treated surfaces, which is a very slow process promoting damaging subflorescence.

Ground water hydrology of the Elizabethtown area, Kentucky

USGS Publications Warehouse

Mull, D.S.; Lyverse, M.A.

1984-01-01

The principal aquifer in a 52 square mile karst area in north central Kentucky is the St. Louis Limestone of Mississippian age. Unconsolidated residuum and surficial deposits of slumped material may store water and recharge the underlying limestone aquifer. Precipitation averages 49 inches annually; 6 inches recharges ground-water reservoirs. The shallow ground-water velocity ranged from 0.30 to 1.40 feet per second. Flow net analysis indicates that about 2 million gallons of water per day flows through a 1.8 mile wide section of the aquifer. A water-level contour map indicates that the hydraulic gradient averages 40 feet per mile and that the water levels near the city supply wells have not lowered in 10 years. The effects of three faults on the ground-water flow system is shown as ponding on the upthrown side of the faults. Caliper logs suggest that shallow ground-water flow occurs in sheet-like openings within 100 feet of land surface. The openings range in height from 1 inch or less to 6 feet. A test well penetrated 5 zones of horizontal openings. The specific capacity ranged from 11.5 to 12.1 gallons per minute per foot of drawdown after 12 and 72 hours of pumping at 280 to 510 gallons per minute. Water in 28 wells and springs meets most drinking water standards and generally is a very hard calcium bicarbonate type. Heavily pumped industrial and public-supply wells tend to yield water with high values of specific conductance and sulfate. Coliform bacteria varied widely in rural wells and the city springs. Seven wells had no coliform bacteria. (USGS)

Tests for injecting, storing, and recovering freshwater in a saline artesian aquifer, Lee County, Florida

USGS Publications Warehouse

Fitzpatrick, D.J.

1986-01-01

An investigation was made of the suitability of a saline, artesian limestone aquifer for the injection, storage, and recovery of freshwater from the Caloosahatchee River. The tests were conducted on a well tapping a leaky artesian system that has a transmissivity of 800 square feet per day, a storage of 1 x 10-4, and a leakance of 0.01 per day. The specific capacity of the injection well was increased through acidizing and was decreased as a result of well clogging during injection. Three injection tests were made wherein the amounts of freshwater injected, the storage duration, and the quality of water injected varied. Analysis of the test data showed that freshwater recoverability ranged from 9.7 to 38.7 percent of the total injected. Differences were attributed principally to differences in the quality of water injected and storage duration. Repeated injection-recovery cycles probably would result in greater recoverability. Head buildup, nearly 200 feet in one test, was a prime problem related chiefly to clogging from suspended material in the injected water and to bacterial growth at the wellbore-limestone interface. Regular backflushing was required. Total head buildup decreased as a result of acidizing the injection well. No coliforms or fecal streptococcus were noted in the recovered water. Growth of anaerobic bacteria occurred. Changes in the quality of the recovered water included decreases in concentration of dissolved organic carbon by as much as 15 mg/L (milligrams per liter), organic nitrogen by as much as 0.80 mg/L, and nitrate by as much as 0.50 mg/L. Increases were noted in ammonia by 0.40 mg/L, and iron by as much as 0.60 mg/L. These changes are consistent with the presence of an anaerobic bacterial ecosystem.

Effects of acidic deposition on the erosion of carbonate stone — experimental results from the U.S. National Acid Precipitation Assessment Program (NAPAP)

NASA Astrophysics Data System (ADS)

Baedecker, Philip A.; Reddy, Michael M.; Reimann, Karl J.; Sciammarella, Cesar A.

One of the goals of NAPAP-sponsored research on the effects of acidic deposition on carbonate stone has been to quantify the incremental effects of wet and dry deposition of hydrogen ion, sulfur dioxide and nitrogen oxides on stone erosion. Test briquettes and slabs of freshly quarried Indiana limestone and Vermont marble have been exposed to ambient environmental conditions in a long-term exposure program. Physical measurements of the recession of test stones exposed to ambient conditions at an angle of 30° to horizontal at the five NAPAP materials exposure sites range from ˜ 15 to ˜ 30 μm yr -1 for marble, and from ˜ 25 to ˜ 45 μm yr -1 for limestone, and are approximately double the recession estimates based on the observed calcium content of run-off solutions from test slabs. The difference between the physical and chemical recession measurements is attributed to the loss of mineral grains from the stone surfaces that are not measured in the run-off experiments. The erosion due to grain loss does not appear to be influenced by rainfall acidity, however, preliminary evidence suggests that grain loss may be influenced by dry deposition of sulfur dioxide between rainfall events. Chemical analyses of the run-off solutions and associated rainfall blanks suggest that ˜ 30% of erosion by dissolution can be attributed to the wet deposition of hydrogen ion and the dry deposition of sulfur dioxide and nitric acid between rain events. The remaining ˜ 70% of erosion by dissolution is accounted for by the solubility of carbonate stone in rain that is in equilibrium with atmospheric carbon dioxide ("clean rain"). These results are for marble and limestone slabs exposed at an angle of 30° from horizontal. The relative contribution of sulfur dioxide to chemical erosion is significantly enhanced for stone slabs having an inclination of 60° or 85°. The dry deposition of alkaline particulate material has a mitigating effect at the two urban field exposure sites at Washington, DC, and Steubenville, OH.

Effects of acidic deposition on the erosion of carbonate stone - experimental results from the U.S. National Acid Precipitation Assessment Program (NAPAP)

USGS Publications Warehouse

Baedecker, P.A.; Reddy, M.M.; Reimann, K.J.; Sciammarella, C.A.

1992-01-01

One of the goals of NAPAP-sponsored research on the effects of acidic deposition on carbonate stone has been to quantify the incremental effects of wet and dry deposition of hydrogen ion, sulfur dioxide and nitrogen oxides on stone erosion. Test briquettes and slabs of freshly quarried Indiana limestone and Vermont marble have been exposed to ambient environmental conditions in a long-term exposure program. Physical measurements of the recession of test stones exposed to ambient conditions at an angle of 30?? to horizontal at the five NAPAP materials exposure sites range from ~15 to ~30?? ??m yr-1 for marble, and from ~25 to ~45 ??m yr -1 for limestone, and are approximately double the recession estimates based on the observed calcium content of run-off solutions from test slabs. The difference between the physical and chemical recession measurements is attributed to the loss of mineral grains from the stone surfaces that are not measured in the run-off experiments. The erosion due to grain loss does not appear to be influenced by rainfall acidity, however, preliminary evidence suggests that grain loss may be influenced by dry deposition of sulfur dioxide between rainfall events. Chemical analyses of the run-off solutions and associated rainfall blanks suggest that ~30% of erosion by dissolution can be attributed to the wet deposition of hydrogen ion and the dry deposition of sulfur dioxide and nitric acid between rain events. The remaining ~70% of erosion by dissolution is accounted for by the solubility of carbonate stone in rain that is in equilibrium with atmospheric carbon dioxide ('clean rain'). These results are for marble and limestone slabs exposed at an angle of 30?? from horizontal. The relative contribution of sulfur dioxide to chemical erosion is significantly enhanced for stone slabs having an inclination of 60?? or 85??. The dry deposition of alkaline particulate material has a mitigating effect at the two urban field exposure sites at Washington, DC, and Steubenville, OH.

Novel Hydroxyapatite Coatings for the Conservation of Marble and Limestone

NASA Astrophysics Data System (ADS)

Naidu, Sonia

Marble and limestone are calcite-based materials used in the construction of various structures, many of which have significant artistic and architectural value. Unfortunately, due to calcite's high dissolution rate, these stones are susceptible to chemically-induced weathering in nature. Limestone, due to its inherent porosity, also faces other environmental weathering processes that cause weakening from disintegration at grain boundaries. The treatments presently available are all deficient in one way or another. The aim of this work is to examine the feasibility of using hydroxyapatite (HAP) as a novel protective coating for marble and limestone, with two goals: i) to reduce acid corrosion of marble and ii) to consolidate physically weathered limestone. The motivation for using HAP is its low dissolution rate and structural compatibility with calcite. Mild, wet chemical synthesis routes, in which inorganic phosphate-based solutions were reacted with marble and limestone, alone and with other precursors, were used to produce HAP films. Film nucleation, growth and phase evolution were studied on marble to understand film formation and determine the optimal synthesis route. An acid resistance test was developed to investigate the attack mechanism on marble and quantify the efficacy of HAP-based coatings. Film nucleation and growth were dependent on substrate surface roughness and increased with calcium and carbonate salt additions during synthesis. Acid attack on marble occurred via simultaneous dissolution at grain boundaries, twin boundaries and grain surfaces. HAP provided intermediate protection against acid attack, when compared to two conventional treatments. Its ability to protect the stone from acid was not as significant as predicted from dissolution kinetics and this was attributed to incomplete coverage and residual porosity within the film, arising from its flake-like crystal growth habit, which enabled acid to access the underlying substrate. The effectiveness of HAP as a consolidant for weathered limestone, alone and coupled with a commercially available consolidant (ConservareRTM OH-100), was also investigated. To artificially weather limestone in the lab, a reproducible thermal degradation technique was utilised. The dynamic elastic modulus, water sorptivity and coating composition of treated stones were evaluated. HAP was found to be an effective consolidant for limestone, as it restored the elastic modulus of damaged stones to their original values and exhibited superior performance to ConservareRTM OH-100.

Comparison of Paleogene paleogeography: Southern Coast Ranges and western Transverse Ranges

DOE Office of Scientific and Technical Information (OSTI.GOV)

Schussler, S.A.

1991-02-01

The paleogene stratigraphic sequence exposed in the southwestern San Rafael Mountains at the southern terminus of the Coast Ranges, consists of up to 850 m (2,800 ft) of the marine limestone, sandstone, and mudstone that lies with a unique depositional contact upon Franciscan Complex rocks. Lithofacies identified represent four sedimentary environments: (1) foreslope talus deposits of a neritic algal bank (Sierra Blanca limestone), (2) bathyal basin plain and outer submarine fan deposits (Juncal/Anita Formation and Cozy Dell Shale), (3) suprafan lobe deposits of a bathyal submarine fan (lower Mitilija Sandstone), and (4) sublittoral shelf deposits (upper Matilija Sandstone). Similarities betweenmore » paleogene rocks in the southwest San Rafael mountains and the western Santa Ynez Mountains of the Transverse Ranges, approximately 60 km (40 mi) to the west, suggest deposition in a similar paleogeographic setting. Paleomagnetic data suggests post-Paleogene clockwise rotations of the western Transverse Ranges of 90{degree}+. Counterclockwise rotation of the western Transverse Ranges by this amount aligns the similar depositional sequences of the western Transverse Ranges with the northwest-trending Paleogene forearc basin of the southern Coast Ranges and eliminates the necessity for an east-west-oriented Paleogene basin at the site of the present western Transverse Ranges.« less

End-member modelling of isothermal remanent magnetization (IRM) acquisition curves: a novel approach to diagnose remagnetization

NASA Astrophysics Data System (ADS)

Gong, Z.; Dekkers, M. J.; Heslop, D.; Mullender, T. A. T.

2009-08-01

To identify remagnetization is essential for palaeomagnetic studies and their geodynamic implications. The traditional approach is often based on directional analysis of palaeomagnetic data and field tests, which may be inconclusive if the apparent polar wander path (APWP) is poorly constrained or if the remagnetization predates folding. In several cases, rock magnetic work, particularly, the measurement of hysteresis loops allows identification of the so-called `remagnetized' and `non-remagnetized' trends. However, for weakly magnetic samples, this approach can be equivocal. Here, to improve the diagnosis of remagnetization, we investigated 192 isothermal remanent magnetization (IRM) acquisition curves (up to 700 mT) of remagnetized and non-remagnetized limestones from the Organyà Basin, northern Spain. Also, 96 IRM acquisition curves from non-remagnetized marls were studied as a cross-check for the non-remagnetized limestones. A non-parametric end-member modelling approach is used to analyse the IRM acquisition curve data sets. First, remagnetized and non-remagnetized groups were treated separately. Two or three end-members were found to adequately describe the data variability: one end-member represents the high-coercivity contribution, whereas the low-coercivity part can be described by either one end-member or two reasonably similar end-members. In the remagnetized limestones, the low-coercivity end-members tend to saturate at higher field values than in the non-remagnetized limestones. When the entire data set was processed together, a three-end-member model was judged optimal. This model consists of a high-coercivity end-member, a low-coercivity end-member that saturates at ~300-400 mT and a low-coercivity end-member that approximately saturates at 700 mT. Higher contributions of the latter end-member appear to occur dominantly in the remagnetized limestones, whereas the reverse is true for the non-remagnetized limestones, so they plot in clearly distinguishable areas. Meanwhile, the IRM curves from non-remagnetized marls show a behaviour similar to that of the non-remagnetized end-member in the limestones. Therefore, this new approach can be a very useful tool to diagnose remagnetization in weakly magnetic limestones and marls. We recommend applying it to other areas of potentially remagnetized low-intensity sediments.

Recyclability of Concrete Pavement Incorporating High Volume of Fly Ash.

PubMed

Yoshitake, Isamu; Ishida, Takeo; Fukumoto, Sunao

2015-08-21

Recyclable concrete pavement was made from fly ash and crushed limestone sand and gravel as aggregates so that the concrete pavement could be recycled to raw materials for cement production. With the aim to use as much fly ash as possible for the sustainable development of society, while achieving adequate strength development, pavement concrete having a cement-replacement ratio of 40% by mass was experimentally investigated, focusing on the strength development at an early age. Limestone powder was added to improve the early strength; flexural strength at two days reached 3.5 MPa, the minimum strength for traffic service in Japan. The matured fly ash concrete made with a cement content of 200 kg/m3 achieved a flexural strength almost equal to that of the control concrete without fly ash. Additionally, Portland cement made from the tested fly ash concrete was tested to confirm recyclability, with the cement quality meeting the Japanese classification of ordinary Portland cement. Limestone-based recyclable fly ash concrete pavement is, thus, a preferred material in terms of sustainability.

Recyclability of Concrete Pavement Incorporating High Volume of Fly Ash

PubMed Central

Yoshitake, Isamu; Ishida, Takeo; Fukumoto, Sunao

2015-01-01

Recyclable concrete pavement was made from fly ash and crushed limestone sand and gravel as aggregates so that the concrete pavement could be recycled to raw materials for cement production. With the aim to use as much fly ash as possible for the sustainable development of society, while achieving adequate strength development, pavement concrete having a cement-replacement ratio of 40% by mass was experimentally investigated, focusing on the strength development at an early age. Limestone powder was added to improve the early strength; flexural strength at two days reached 3.5 MPa, the minimum strength for traffic service in Japan. The matured fly ash concrete made with a cement content of 200 kg/m3 achieved a flexural strength almost equal to that of the control concrete without fly ash. Additionally, Portland cement made from the tested fly ash concrete was tested to confirm recyclability, with the cement quality meeting the Japanese classification of ordinary Portland cement. Limestone-based recyclable fly ash concrete pavement is, thus, a preferred material in terms of sustainability. PMID:28793518

Geohydrology and Numerical Simulation of Alternative Pumping Distributions and the Effects of Drought on the Ground-Water Flow System of Tinian, Commonwealth of the Northern Mariana Islands

USGS Publications Warehouse

Gingerich, Stephen B.

2002-01-01

Ground water in a freshwater lens is the main source of freshwater on Tinian, Commonwealth of the Northern Mariana Islands. Four major geologic units make up the island with high-permeability limestone units overlying low-permeability volcanic rocks. Estimates of limestone hydraulic conductivity range from 21 to 23,000 feet per day. Estimates of water-budget components for Tinian are 82 inches per year of rainfall, about 6 inches per year of runoff, 46 inches per year of evapotranspiration, and 30 inches per year of recharge. From 1990?97, ground-water withdrawal from the Municipal well, the major source of water, averaged about 780 gallons per minute. A two-dimensional, steady-state, ground-water flow model using the computer code SHARP was developed for Tinian, to enhance the understanding of (1) the distribution of aquifer hydraulic properties, (2) the conceptual framework of the ground-water flow system, and (3) the effects of various pumping distributions and drought on water levels and the freshwater/saltwater transition zone. For modeling purposes, Tinian was divided into three horizontal hydraulic-conductivity zones: (1) highly permeable limestone, (2) less-permeable, clay-rich limestone, and (3) low-permeability volcanic rocks. The following horizontal hydraulic conductivities were estimated: (1) 10,500 feet per day for the highly permeable limestone, (2) 800 feet per day for the less-permeable clay-rich limestone, and (3) 0.2 foot per day for the volcanic rocks. To estimate the hydrologic effects of different pumping distributions on the aquifer, three different steady-state pumping scenarios were simulated, (1) a scenario with no ground-water pumping, (2) a 2001-pumping scenario, and (3) a maximum-pumping scenario. The results of the no-pumping scenario showed that the freshwater/saltwater interface beneath the Municipal well would be about 7 feet deeper and ground-water discharge to the coast would be higher along both the east and west coasts of the island when compared with 1990-97 pumping conditions. For the maximum pumping scenario, the model-calculated freshwater/saltwater interface is about 7 feet shallower than the position calculated in the base-case scenario. To estimate the hydrologic effects of drought on the freshwater lens, the 2001- and maximum-pumping scenarios were simulated using three combinations of aquifer porosity values covering a range of possible limestone properties. In all scenarios, recharge was reduced to 10 percent of average estimated recharge and the transient response was simulated for 1 year. These simulations demonstrated that the ground-water resource is adequate to withstand a drought similar to that experienced in 1998 using existing infrastructure.

A conodont-based standard reference section in central Nevada for the lower Middle Ordovician Whiterockian Series

USGS Publications Warehouse

Sweet, W.C.; Ethington, Raymond L.; Harris, A.G.

2005-01-01

Ranges of conodonts in stratigraphic sections at five localities in the Monitor and Antelope ranges of central Nevada are used graphically to assemble a standard reference section for the lower Middle Ordovician Whiterockian Series. The base of the series is officially 0.3 m above the base of the Antelope Valley Limestone in the stratotype in Whiterock Canyon (Monitor Range). The top is the level at which Baltoniodus gerdae makes a brief appearance in an exposure of the Copenhagen Formation on the flanks of Hill 8308 in the western Antelope Range. Graphic compilation of the sections considered in this report also indicates that a level correlative with the base of the Whiterockian Series in the stratotype section is 66 m above the base of the Antelope Valley Limestone in its de facto type section on Martin Ridge in the eastern part of the Monitor Range. Ranges, diversity, and the composition of the conodont faunas differ markedly in lithofacies adjacent to the basal boundary of the series; hence we are unable to identify a single conodont species, in a credible developmental sequence, to serve as biological marker of that boundary.

Interactions between abundant fungal species influence the fungal community assemblage on limestone

PubMed Central

Morón-Ríos, Alejandro; Ortega-Morales, Benjamin Otto; De la Rosa-García, Susana; Partida-Martínez, Laila Pamela; Quintana, Patricia; Alayón-Gamboa, José Armando; Cappello-García, Silvia; González-Gómez, Santiago

2017-01-01

The assembly of fungal communities on stone materials is mainly influenced by the differential bioreceptivity of such materials and environmental conditions. However, little is known about the role of fungal interactions in the colonization and establishment of fungal species. We analyzed the effects of intra- and interspecific interactions between 11 species of fungi in oligotrophic and copiotrophic media and on limestone coupons. In a previous study, these species were the most frequently isolated in the epilithic biofilms of limestone walls exposed to a subtropical climate. In the culture media, we found a greater frequency of intra- and interspecific inhibitory effects in the oligotrophic medium than in the copiotrophic medium. On the limestone coupons, all fungi were able to establish; however, the colonization success rate varied significantly. Cladosporium cladosporioides had a less extensive colonization in isolation (control) than in dual interactions (coexistence) with other species. Phoma eupyrena exhibited the highest colonization success rate and competitive dominance among all tested species. X-ray diffraction (XRD) and scanning electron microscope (SEM) analyses revealed that Pestalotiopsis maculans and Paraconiothyrium sp. produced calcium oxalate crystals during their growth on coupon surfaces, both in isolation and in dual interactions. Our results demonstrate that interactions between abundant fungal species influence the fungal colonization on substrates, the biomineralization and the fungal community assemblage growing in limestone biofilms. PMID:29211748

Fracture Decoupling of Small Chemical Explosions in Granite and Limestone

NASA Astrophysics Data System (ADS)

Stroujkova, A. F.; Bonner, J. L.; Reinke, R.; Lenox, E. A.

2012-12-01

Reduction of the seismic amplitudes produced by underground explosions due to dissipation in a low-coupling medium poses a significant challenge for nuclear test monitoring. We examined the data from two experiments, which involved conducting explosions in the damage zone created by previous explosions ("repeat shots"). The first experiment was conducted in central New Hampshire in a fluid saturated granodiorite. The experiment involved detonating two 46 kg explosions: one in virgin rock and the other in the fractured rock zone produced by a larger (232 kg) explosion. The second experiment took place near Albuquerque, NM, in dry limestone. In this scenario the second explosion was conducted in the cavity created by the first explosion. Both limestone explosions had yields of 90.5 kg. The reduction of the seismic amplitudes was observed for both repeat shots: in granodiorite the amplitudes were reduced by a factor of 2-3, in limestone by a factor of 3-4 compared to the shots in the undamaged rocks. For the granodiorite repeat shot the decoupling ratios were frequency dependent with stronger amplitude reduction at higher frequencies. In addition, the virgin rock shot produced higher corner frequency and overshoot parameter than the repeat shot. For the limestone shot the decoupling ratios were nearly flat at all frequencies with similar corner frequencies. This observation suggests different mechanisms of energy dissipation for the two experiments.

Soil ecology of a rock outcrop ecosystem: Abiotic stresses, soil respiration, and microbial community profiles in limestone cedar glades

USGS Publications Warehouse

Cartwright, Jennifer M.; Advised by Dzantor, E. Kudjo

2015-01-01

Stress factors quantified by this research include shallow soil (depth to bedrock ranging from 2.4 to 22.6 cm), volumetric soil water content levels seasonally ranging from xeric (below 5%) to saturated (above 50%), and seasonally extreme ground-surface temperatures (above 48°C). Findings from this research indicate that spatial and temporal heterogeneity exists in limestone cedar glades in terms of abiotic stress factors and soil physical and chemical properties. Several such soil properties (e.g. soil depth, organic matter levels, pH, and particle size distribution) are spatially correlated. These soil properties were statistically related to ecological structures and functions such as vegetation patterns, soil respiration, the density of culturable heterotrophic microbes in soil and metabolic diversity of soil microbial community profiles. In general, zones within limestone cedar glades that had relatively shallow soil, alkaline pH, low levels of organic matter and high levels of silt also tended to have depressed rates of soil respiration and reduced densities and metabolic diversity of culturable heterotrophic soil microbes. Additionally, seasonally-relevant stress factors including soil water content and temperatures at or near the soil surface were related to the same set of ecological structures and functions.

Ground-water geology of the Gonaives Plain, Haiti

USGS Publications Warehouse

Taylor, George C.; Lemoine, Rémy C.

1950-01-01

The Gonaives Plain lies in northern Haiti at the head of the Gulf of Gonaives. Ground water in the plain is used widely for domestic and stock purposes but only to limited extent for irrigation. The future agricultural development of the plain will depend in large measure on the proper utilization of available ground-water supplies for irrigation. The rocks in the region of the Gonaives Plain belong to the upper (?) Cretaceous series of the Cretaceous system, the Nocene and Oligovene series of the Tertiary system, and the Pleistocene and Recent series of the Quarternary system. The structural depression occupied by the Gonaives Plain was formed in post-Miocene time by the dislocation of Oligocene and older rocks along normal faults and by the tilting of the adjacent crustal blocks. The lower parts of the depression contain a Pleistocene and Recent alluvial fill deposited by streams tributary to the plain. The upper (?) Cretaceous rocks include aniesite and basalt lava flows locally intercalated with some beds of tuff and agglomerate. These rocks are generally dense and impervious but locally small springs rise from fractures and bedding planes or from weathered zones. The Nocene rocks are hard, thin-bedded, cherty limestones with some beds of massive chalky limestone. Considerable ground water circulates through joints, bedding planes, and solution passages in these rocks giving rise to important springs such as Sources Madame Charles. These springs discharge at the rate of about 110 liters per second. The Oligocene rocks include limestone, shely limestone, limy sandstone, marl, and shale. The limestone beds contain solution passages and other openings and these may afford capacity for the circulation of ground water. However, no wells or springs in Oligocene rocks were observed during the present study. The alluvial fill of the plain is composed of interbedded lenses of clay, silt, sand, and gravel. These deposits contain a zone of saturation whose upper limit is marked by a water table. The depth to the water table beneath the alluvial lowland of the plain ranges from less than one meter to about 20 meters. In most places in the plain the depth to water is less that 15 meters. Where present in the zone of saturation the coarse, well-sorted sand and gravel beds of the alluvium will probably yield moderate to large supplies of water to wells and infiltration galleries. The individual yields of existing wells range from a few liters to about 60 liters per second. The most favorable part of the plain for ground-water prospecting and development lies 5 to 10 kilometers northeast of Gonaives. In this area yields of 10 to 50 liters per second could be obtained from the alluvium in simple wells drilled to depths of about 35 to 45 meters. Additional information on the yield and physical character of aquifers in the alluvium would be provided by test wells drilled to depths of 40 to 60 meters.

Measurement of thoron exhalation rates from building materials.

PubMed

de With, G; de Jong, P; Röttger, A

2014-09-01

Thoron (220Rn) exhalation from building materials has become increasingly recognized as a potential source for radiation exposure in dwellings. However, contrary to radon (220Rn), limited information on thoron exposure is available. The purpose of this study is to develop a test method for the determination of the thoron exhalation rate from building materials. The method is validated, and subsequently the thoron exhalation rates from 10 widely-applied concretes, gypsums, brick, limestone, and mortar are determined. The measured thoron exhalation rates of these materials range from 0.01 Bq m-2 s-1 to 0.43 Bq m-2 s-1, with relative standard uncertainties between 6% to 14%.

Consolidation of degraded ornamental porous limestone stone by calcium carbonate precipitation induced by the microbiota inhabiting the stone.

PubMed

Jimenez-Lopez, C; Rodriguez-Navarro, C; Piñar, G; Carrillo-Rosúa, F J; Rodriguez-Gallego, M; Gonzalez-Muñoz, M T

2007-08-01

Although it has already been shown that calcareous stone can be consolidated by using a bacterially inoculated culture medium, a more user-friendly method is the in situ application of a sterile culture medium that is able to activate, among the microbial community of the stone, those bacteria with a potential for calcium carbonate precipitation. In order to test this new method for stone consolidation, non-sterilized decayed porous limestone was immersed in sterile nutritional media. Results were compared to those of the runs in which stone sterilized prior to the treatment was used. The effects of the microbial community on stone consolidation were determined by recording the evolution of the culture media chemistry. The treated stone was tested for mechanical resistance and porosity. Results demonstrate that the tested media were able to activate bacteria from the microbial community of the stone. As a consequence of the growth of these bacteria, an alkalinization occurred that resulted in calcium carbonate precipitation. The new precipitate was compatible with the substrate and consolidated the stone without pore plugging. Therefore, a good candidate to in situ consolidate decayed porous limestone is the application of a sterile culture medium with the characteristics specified in the present study.

Effect of the specimen length on ultrasonic P-wave velocity in some volcanic rocks and limestones

NASA Astrophysics Data System (ADS)

Karaman, Kadir; Kaya, Ayberk; Kesimal, Ayhan

2015-12-01

Ultrasonic P-wave velocity (UPV) is commonly used in different fields such as civil, mining, geotechnical, and rock engineering. One of the significant parameters which affect the UPV of rock materials is likely to be the length of test cores although it is not mentioned in the literature. In this study, in order to explore the influence of the specimen length on the UPV, rock samples were collected from eight different locations in Turkey. The NX-sized core specimens having different length of 50, 75, 100, 125, and 150 mm were prepared. Before the analyses, rocks were divided into two groups in terms of their geological origins such as volcanic and chemical sedimentary (limestone) rocks. The UPV tests were carried out under dry and saturated conditions for each 200 core specimens. By evaluating the test results, it was shown that the length of the specimens significantly affects the UPV values. Based on the regression analyses, a method was developed to determine the threshold specimen length of studied rocks. Fluctuations in UPVdry and UPVsat values were generally observed for cores smaller than the threshold specimen length. In this study, the threshold specimen length was determined as 79 mm for volcanic rocks and 109 mm for limestones.

Lithologic and structural controls of limestone-hosted Pb-Zn-Ag mineralization in Chihuahua, Mexico

DOE Office of Scientific and Technical Information (OSTI.GOV)

Lofquist, D.J.; Ruiz, J.

1985-01-01

The state of Chihuahua contains some of the most important limestone-hosted ore deposits in Mexico. The best example are Santa Eulalia and Naica which together have produced 53 million tons or ore averaging 7.7% Pb, 6.4% Zn, and 280 g/ton Ag. These deposits occur as mantos and chimneys often accompanied by calc-silicates. Among the most critical questions in this type of deposit is the control that the limestone-host exerts on the mineralizing process. Here the authors present the first detailed data on the stratigraphic and lithologic character of the limestone-hosts at Naica and Santa Eulalia. All ore at Naica andmore » Santa Eulalia is hosted by micrites, biomicrites and biosparites indicative of generally quiet marine deposition. The authors work suggests that the western edge of the this trough might be a low angle, east dipping ramp which extends below the Sierra Madre Occidental. The primary permeability of the limestone that hosts Naica and Santa Eulalia is in the micro to nanodarcy range. The effective permeability has been augmented by 3 or 4 stages of micro-fracturing. Most of the ore is controlled by these fractures and by felsic dikes, which in cases are mostly endoskarn. Stylolites also appear to have exerted a control on the mineralizing process. Numerous instances of alteration and recrystallization confined to one side of a horizontal stylolite have been noted. At Santa Eulalia, horizontal stylolites have controlled the emplacement of massive sulfide mantos, suggesting that the mineralizing process was rather passive.« less

50. EAST CORNER OF BUILDING 365 (ARMAMENT TESTING BUILDING) IN ...

Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

50. EAST CORNER OF BUILDING 365 (ARMAMENT TESTING BUILDING) IN BASE SPARES AREA. - Loring Air Force Base, Weapons Storage Area, Northeastern corner of base at northern end of Maine Road, Limestone, Aroostook County, ME

49. NORTHEAST FRONT ELEVATION OF BUILDING 365 (ARMAMENT TESTING BUILDING) ...

Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

49. NORTHEAST FRONT ELEVATION OF BUILDING 365 (ARMAMENT TESTING BUILDING) IN BASE SPARES AREA. - Loring Air Force Base, Weapons Storage Area, Northeastern corner of base at northern end of Maine Road, Limestone, Aroostook County, ME

Some perisphinctoid ammonites of the Štramberk Limestone and their dating with associated microfossils (Tithonian to Lower Berriasian, Outer Western Carpathians, Czech Republic)

NASA Astrophysics Data System (ADS)

Vašíček, Zdeněk; Reháková, Daniela; Skupien, Petr

2017-08-01

The present contribution deals with the taxonomy of seven species of perisphinctoid ammonite from the Štramberk Limestone (Outer Western Carpathians, Czech Republic) deposited in Moravian-Silesian museums. The age of these studied ammonites is compared with that of index microfossils contained in the matrix adhering to or infilling the studied specimens. The ammonites document a stratigraphic range from earliest Tithonian to early Berriasian. In addition to taxonomy and new ontogenetic data on some species, we also present data on their palaeogeographic distribution. The occurrence of Subboreal himalayitids in the Štramberk Limestone of an early Berriasian age is determined by both the microfauna and accompanying ammonites, which indicate connection of the Silesian-part of the Tethyan Carpathian area with the Subboreal Russian Platform Basin. These records also suggest an early Berriasian age (Jacobi Chron) for the lowermost part of the Ryazanian stage in its type area.

Some perisphinctoid ammonites of the Štramberk Limestone and their dating with associated microfossils (Tithonian to Lower Berriasian, Outer Western Carpathians, Czech Republic)

NASA Astrophysics Data System (ADS)

Vašíček, Zdeněk; Reháková, Daniela; Skupien, Petr

2016-08-01

The present contribution deals with the taxonomy of seven species of perisphinctoid ammonite from the Štramberk Limestone (Outer Western Carpathians, Czech Republic) deposited in Moravian-Silesian museums. The age of these studied ammonites is compared with that of index microfossils contained in the matrix adhering to or infilling the studied specimens. The ammonites document a stratigraphic range from earliest Tithonian to early Berriasian. In addition to taxonomy and new ontogenetic data on some species, we also present data on their palaeogeographic distribution. The occurrence of Subboreal himalayitids in the Štramberk Limestone of an early Berriasian age is determined by both the microfauna and accompanying ammonites, which indicate connection of the Silesian-part of the Tethyan Carpathian area with the Subboreal Russian Platform Basin. These records also suggest an early Berriasian age (Jacobi Chron) for the lowermost part of the Ryazanian stage in its type area.

Effects of limestone on starch digestion in Holstein steers.

PubMed

Tissera, G H; Vandersall, J H; Erdman, R A

1988-03-01

Eight calcitic and three dolomitic limestones were examined for particle size and reactivity with hydrochloric acid at pH 3.5 and 5.5. Reactivity was higher in calcitic than dolomitic limestone. Within calcitic limestones, reactivity was highly related to particle size. A highly reactive limestone was selected for use in two digestion trials with Holstein steers. In Trial 1, 4 steers (approximately 300 kg) were fed diets consisting of 40% corn silage and 60% concentrate (DM basis) with .62 or 2.34% limestone in a single reversal trial with 3-wk experimental periods. Added limestone affected only starch digestibility, which increased from 91.3 to 93.2%. Fecal pH increased from 5.7 to 6.4 by limestone addition. In trial 2, four rumen and duodenally cannulated steers (approximately 475 kg) were fed the same diets in the same design. Limestone addition increased fecal pH from 5.7 to 6.5. There were no effects of limestone on rumen or total tract digestion of starch or other nutrients. Limestone addition had no effect on rumen pH, buffering capacity, or VFA concentrations. Addition of a highly reactive limestone to diets containing high amounts of starch had little effect on starch digestion in either the rumen or lower gastrointestinal tract.

Chip and scrub seal field test results for Hwy 17 and Hwy 35.

DOT National Transportation Integrated Search

2009-11-09

This report contains field test results from two pavements located in Mississippi containing chip seals and scrub seals. Limestone aggregate from the same source was used with PASS-CR emulsion. The pavements were tested at three intervals. One or bot...

Biostratigraphy and structural setting of the Permian Coyote Butte Formation of central Oregon.

USGS Publications Warehouse

Wardlaw, B.R.; Nestell, M.K.; Dutro, J.T.

1982-01-01

Larger isolated outcrops of the limestones of the Coyote Butte Formation consistently contain younger over older faunas that range through most of the Leonardian Series of the Early Permian. The outcrops of the Coyote Butte Formation are interpreted as right- side up blocks probably introduced into the area as one massive exotic unit. The Coyote Butte Formation is very similar to the Lower Permain limestone near Quinn River Crossing, Nevada, and both are suggested to have a similar origin. The Coyote Butte Formation was probably introduced during a late-stage event to deforming Mesozoic oceanic sediments in Mesozoic time. -Authors

Contrasting fluid/rock interaction between the Notch Peak granitic intrusion and argillites and limestones in western Utah: evidence from stable isotopes and phase assemblages

USGS Publications Warehouse

Nabelek, P.I.; Labotka, T.C.; O'Neil, J.R.; Papike, J.J.

1984-01-01

The Jurassic Notch Peak granitic stock, western Utah, discordantly intrudes Cambrian interbedded pure limestones and calcareous argillites. Contact metamorphosed argillite and limestone samples, collected along traverses away from the intrusion, were analyzed for ??18O, ??13C, and ??D. The ??13C and ??18O values for the limestones remain constant at about 0.5 (PDB) and 20 (SMOW), respectively, with increasing metamorphic grade. The whole rock ??18O values of the argillites systematically decrease from 19 to as low as 8.1, and the ??13C values of the carbonate fraction from 0.5 to -11.8. The change in ??13C values can be explained by Rayleigh decarbonation during calcsilicate reactions, where calculated {Mathematical expression} is about 4.5 permil for the high-grade samples and less for medium and low-grade samples suggesting a range in temperatures at which most decarbonation occurred. However, the amount of CO2 released was not anough to decrease the whole rock ??18O to the values observed in the argillites. The low ??18O values close to the intrusion suggest interaction with magmatic water that had a ??18O value of 8.5. The extreme lowering of ??13C by fractional devolatilization and the lowering of ??18O in argillites close to the intrusion indicates oxgen-equivalent fluid/rock ratios in excess of 1.0 and X(CO2)F of the fluid less than 0.2. Mineral assemblages in conjunction with the isotopic data indicate a strong influence of water infiltration on the reaction relations in the argillites and separate fluid and thermal fronts moving thru the argillites. The different stable isotope relations in limestones and argillites attest to the importance of decarbonation in the enhancement of permeability. The flow of fluids was confined to the argillite beds (argillite aquifers) whereas the limestones prevented vertical fluid flow and convective cooling of the stock. ?? 1984 Springer-Verlag.

The Research Process on Converter Steelmaking Process by Using Limestone

NASA Astrophysics Data System (ADS)

Tang, Biao; Li, Xing-yi; Cheng, Han-chi; Wang, Jing; Zhang, Yun-long

2017-08-01

Compared with traditional converter steelmaking process, steelmaking process with limestone uses limestone to replace lime partly. A lot of researchers have studied about the new steelmaking process. There are much related research about material balance calculation, the behaviour of limestone in the slag, limestone powder injection in converter and application of limestone in iron and steel enterprises. The results show that the surplus heat of converter can meet the need of the limestone calcination, and the new process can reduce the steelmaking process energy loss in the whole steelmaking process, reduce carbon dioxide emissions, and improve the quality of the gas.

Cross-borehole slug test analysis in a fractured limestone aquifer

NASA Astrophysics Data System (ADS)

Audouin, Olivier; Bodin, Jacques

2008-01-01

SummaryThis work proposes new semi-analytical solutions for the interpretation of cross-borehole slug tests in fractured media. Our model is an extension of a previous work by Barker [Barker, J.A., 1988. A generalized radial flow model for hydraulic tests in fractured rock. Water Resources Research 24 (10), 1796-1804; Butler Jr., J.J., Zhan X., 2004. Hydraulic tests in highly permeable aquifers. Water Resources Research 40, W12402. doi:10.1029/2003/WR002998]. It includes inertial effects at both test and observation wells and a fractional flow dimension in the aquifer. The model has five fitting parameters: flow dimension n, hydraulic conductivity K, specific storage coefficient Ss, and effective lengths of test well Le and of observation well Leo. The results of a sensitivity analysis show that the most sensitive parameter is the flow dimension n. The model sensitivity to other parameters may be ranked as follows: K > Le ˜ Leo > Ss. The sensitivity to aquifer storage remains one or two orders of magnitude lower than that to other parameters. The model has been coupled to an automatic inversion algorithm for facilitating the interpretation of real field data. This inversion algorithm is based on a Gauss-Newton optimization procedure conditioned by re-scaled sensitivities. It has been used to interpret successfully cross-borehole slug test data from the Hydrogeological Experimental Site (HES) of Poitiers, France, consisting of fractured and karstic limestones. HES data provide flow dimension values ranging between 1.6 and 2.5, and hydraulic conductivity values ranging between 4.4 × 10 -5 and 7.7 × 10 -4 m s -1. These values are consistent with previous interpretations of single-well slug tests. The results of the sensitivity analysis are confirmed by calculations of relative errors on parameter estimates, which show that accuracy on n and K is below 20% and that on Ss is about one order of magnitude. The K-values interpreted from cross-borehole slug tests are one order of magnitude higher than those previously interpreted from interference pumping tests. These findings suggest that cross-borehole slug tests focus on preferential flowpath networks made by fractures and karstic channels, i.e. the head perturbation induced by a slug test propagates only through those flowpaths with the lowest hydraulic resistance. As a result, cross-borehole slug tests are expected to identify the hydrodynamic properties of karstic-channels and fracture flowpaths, and may be considered as complementary to pumping tests which more likely provide bulk properties of the whole fracture/karstic-channel/matrix system.

Characterization of limestone reacted with acid-mine drainage in a pulsed limestone bed treatment system at the Friendship Hill National Historical Site, Pennsylvania, USA

USGS Publications Warehouse

Hammarstrom, J.M.; Sibrell, P.L.; Belkin, H.E.

2003-01-01

Armoring of limestone is a common cause of failure in limestone-based acid-mine drainage (AMD) treatment systems. Limestone is the least expensive material available for acid neutralization, but is not typically recommended for highly acidic, Fe-rich waters due to armoring with Fe(III) oxyhydroxide coatings. A new AMD treatment technology that uses CO2 in a pulsed limestone bed reactor minimizes armor formation and enhances limestone reaction with AMD. Limestone was characterized before and after treatment with constant flow and with the new pulsed limestone bed process using AMD from an inactive coal mine in Pennsylvania (pH = 2.9, Fe = 150 mg/l, acidity = 1000 mg/l CaCO3). In constant flow experiments, limestone is completely armored with reddish-colored ochre within 48 h of contact in a fluidized bed reactor. Effluent pH initially increased from the inflow pH of 2.9 to over 7, but then decreased to 6 during operation. Limestone removed from a pulsed bed pilot plant is a mixture of unarmored, rounded and etched limestone grains and partially armored limestone and refractory mineral grains (dolomite, pyrite). The ???30% of the residual grains in the pulsed flow reactor that are armored have thicker (50- to 100-??m), more aluminous coatings and lack the gypsum rind that develops in the constant flow experiment. Aluminium-rich zones developed in the interior parts of armor rims in both the constant flow and pulsed limestone bed experiments in response to pH changes at the solid/solution interface. ?? 2003 Elsevier Ltd. All rights reserved.

Hydrogen sulfide capture by limestone and dolomite at elevated pressure. 1: Sorbent performance

DOE Office of Scientific and Technical Information (OSTI.GOV)

Yrjas, K.P.; Zevenhoven, C.A.P.; Hupa, M.M.

1996-01-01

Sulfur emission control in fossil fuel gasification plants implies the removal of H{sub 2}S from the product gas either inside the furnace or in the gas clean-up system. In a fluidized-bed gasifier, in-bed sulfur capture can be accomplished by adding a calcium-based sorbent such as limestone or dolomite to the bend and removing the sulfur from the system with the bottom ash in the form of CaS. This work describes the H{sub 2}S uptake by a set of physically and chemically different limestones and dolomites under pressurized conditions, typically for those in a pressurized fluidized-bed gasifier (2 MPa, 950 C).more » The tests were done with a pressurized thermobalance at two p{sub CO{sub 2}} levels. Thus, the sulfidation of both calcined and uncalcined sorbents could be analyzed. The effect of p{sub H{sub 2}S} was also investigated for uncalcined limestones and half-calcined dolomites. The results are presented as conversion of CaCO{sub 3} or CaO to CaS vs time plots. The results are also compared with the sulfur capture performance of the same sorbents under pressurized combustion conditions.« less

Study on the influence of the decoking agent on the activity of limestone in wet flue gas desulfurization

NASA Astrophysics Data System (ADS)

Li, Qianjun; Xu, Dongyang; Wu, Yunxia; Yu, Jin

2017-01-01

Influence of the main components of decoking agent (magnesium nitrate, aluminum nitrate, copper nitrate, ammonium nitrate and actual decoking agent) on the activity of limestone is studied in laboratory by MET method. Results show that magnesium nitrate, ammonium nitrate and copper nitrate almost has no effect on the activity of limestone. With the concentration increasing, aluminum nitrate has an increasing inhibition on the dissolution of limestone. Fly ash has inhibition on dissolution of limestone due to the blockage of limestone pore by fly ash. The actual decoking agent has almost no effect on the limestone.

Optimization of nanolime solvent for the consolidation of coarse porous limestone

NASA Astrophysics Data System (ADS)

Borsoi, Giovanni; Lubelli, Barbara; van Hees, Rob; Veiga, Rosário; Silva, António Santos

2016-09-01

The potentialities of nanomaterials for application in the field of conservation have been widely investigated in the last two decades. Among nanomaterials, nanolimes, i.e., dispersions of lime nanoparticles in alcohols are promising consolidating products for calcareous materials. Nanolimes are effective in recovering the very superficial loss of cohesion of decayed materials, but they do not always provide sufficient mass consolidation. This limitation is mainly related to the deposition of the nanoparticles nearby the surface of the material. Experimental research has been set up with the aim of improving the in-depth deposition of lime nanoparticles. Previous research by the authors has shown that nanolime deposition within a substrate can be controlled by adapting the nanolimes properties (kinetic stability and evaporation rate) to the moisture transport behavior of the substrate. Nanolime properties can be modified by the use of different solvents. In this research, nanolime dispersions have been further optimized for application on Maastricht limestone, a coarse porous limestone. Firstly, nanolimes were synthesized and dispersed in ethanol and/or water, both pure and mixed in different percentages. Subsequently, based on the kinetic stability of the nanolime dispersions, the most promising solvent mixtures were selected and applied on the limestone. The deposition of lime nanoparticles within the limestone was studied by phenolphthalein test, optical microscopy and scanning electron microscopy. The results confirm that nanolime dispersed in a mixture of ethanol (95 %) and water (5 %) can guarantee a better nanoparticles in-depth deposition within coarse porous substrates, when compared to dispersions in pure ethanol.

Effluent characterization from a conical pressurized fluid bed

NASA Technical Reports Server (NTRS)

Priem, R. J.; Rollbuhler, R. J.; Patch, R. W.

1977-01-01

To obtain useable corrosion and erosion results it was necessary to have data with several levels of particulate matter in the hot gases. One level of particulate loading was as low as possible so that ideally no erosion and only corrosion occurred. A conical fluidized bed was used to obtain some degree of filtration through the top of the bed which would not be highly fluidized. This would minimize the filtration required for the hot gases or conversely the amount of particulate matter in the hot gases after a given level of filtration by cyclones and/or filters. The data obtained during testing characterized the effluent from the bed at different test conditions. A range of bed heights, coal flows, air flows, limestone flows, and pressure are represented. These tests were made to determine the best operating conditions prior to using the bed to determine erosion and corrosion rates of typical turbine blade materials.

The Role of Source Material in Basin Sedimentation, as Illustrated within Eureka Valley, Death Valley National Park, CA.

NASA Astrophysics Data System (ADS)

Lawson, M. J.; Yin, A.; Rhodes, E. J.

2015-12-01

Steep landscapes are known to provide sediment to sink regions, but often petrological factors can dominate basin sedimentation. Within Eureka Valley, in northwestern Death Valley National Park, normal faulting has exposed a steep cliff face on the western margin of the Last Chance range with four kilometers of vertical relief from the valley floor and an angle of repose of nearly 38 degrees. The cliff face is composed of Cambrian limestone and dolomite, including the Bonanza King, Carrara and Wood Canyon formations. Interacting with local normal faulting, these units preferentially break off the cliff face in coherent blocks, which result in landslide deposits rather than as finer grained material found within the basin. The valley is well known for a large sand dune, which derives its sediment from distal sources to the north, instead of from the adjacent Last Chance Range cliff face. During the Holocene, sediment is sourced primary from the northerly Willow Wash and Cucomungo canyon, a relatively small drainage (less than 80 km2) within the Sylvan Mountains. Within this drainage, the Jurassic quartz monzonite of Beer Creek is heavily fractured due to motion of the Fish Valley Lake - Death Valley fault zone. Thus, the quartz monzonite is more easily eroded than the well-consolidated limestone and dolomite that forms the Last Change Range cliff face. As well, the resultant eroded material is smaller grained, and thus more easily transported than the limestone. Consequently, this work highlights an excellent example of the strong influence that source material can have on basin sedimentation.

Provenance of Modern Soils and Limestone and Chert Bedrock of Middle Tennessee Assessed Using Detrital Zircon U-Pb Geochronology

NASA Astrophysics Data System (ADS)

Ayers, J. C.; Katsiaficas, N. J.; Wang, X.

2014-12-01

Relatively thick soils mantle limestone bedrock throughout much of middle TN. Detrital zircon U-Pb geochronology was used to test two hypotheses: 1) That soil formed by accumulation of insoluble residue during chemical weathering of "dirty" limestone bedrock. 2) That an exotic component, perhaps wind-blown loess, was deposited and weathered to form soil. Samples of soil and underlying bedrock were collected from flat surfaces at the tops of cliffs. At Site 1 the Mississippian cherty limestone of the Fort Payne Formation was collected along with the B1 and B2 horizons of the overlying ultisol. At Site 2 a composite sample of A and B horizons of an alfisol and a sample of the underlying Ordovician limestone of the Hermitage Formation were collected. Zircon was recovered from soil and limestone samples, imaged using cathodoluminescence, and analyzed for trace elements and U-Pb isotopes using a 193 nm laser and quadrupole ICP-MS. Discordant analyses were discarded and 206Pb/238U ages are reported. Trace element concentrations and ratios in zircon seem to not be useful as provenance indicators. However, comparison of U-Pb age spectra showed that soils at both sites predominantly formed by weathering of limestone, with a small exotic component. The Hermitage has significant age peaks at ~1330, 1043, 955 and 439 Ma, and its overlying soil has age peaks at 1410, 1235, 1036 and 442 Ma. The age spectra are significantly different (Kolmogorov-Smirnov probability P = 0.01 < 0.05 significance). The Fort Payne has age peaks at ~1253, 967 and 417 Ma, while the B1 has age peaks at 1440, 1182, 1012 and 450 Ma (K-S P = 0.051) and the B2 at 1240, 941, 362, 81 and 33 Ma (K-S P = 0.073). The young ages in B2 require an exotic component that may account for ~25% of the measured ages. The source of the exotic material has not yet been identified, but its zircon age spectrum does not match previously published age spectra for the regional Pleistocene Peoria loess. Bedrock age peaks overlap with the Grenville, Taconic and Acadian orogenies of eastern North America. This study demonstrates that dating of detrital zircon is a powerful tool for determining the provenance of soil and limestone.

Installation and performance of lightweight aggregate asphaltic concrete test sections.

DOT National Transportation Integrated Search

1970-01-01

In 1966 and 1968 test sections of asphaltic concrete overlays fabricated with coarse lightweight aggregate and fine limestone were installed in the Roanoke-Bedford area. The experimental mixes used were designed in an attempt to develop skid resistan...

Optimization of Limestone Feed Size of a Pressurized Fluidized Bed Combustor

NASA Astrophysics Data System (ADS)

Shimizu, Tadaaki; Saastamolnen, Jaakko

Limestone attrition is a major cause of loss of limestone during pressurized fluidized bed combustion. In the authors' previous works, the analysis of published results of solid attrition and desulfurization was conducted to determine the attrition rate expression. The specific attrition rate (rate of decrease in diameter) was estimated to be second order with respect to particle diameter in the previous work. This rate expression implies that reduction of feed size of limestone is effective for suppression of loss of limestone by attrition. However, too much grinding of raw limestone will increase the content of fine particles that are readily elutriated by gas stream and do not contribute to the sulfur capture. In this work, modeling works are conducted for particle attrition and desulfurization in order to predict the effect of feed size of limestone on total consumption of limestone and desulfurization is discussed. Optimum particle size to suppress limestone consumption was approximately 0.7 mm (as D p50 ). However, the control of solid drain rate from the bottom was found to have more influence on total limestone consumption rate. Emissions of SO2 from low sulfur coal (S=0.33%) could be sufficiently low irrespective of limestone feed size but SO2 emissions from coals with higher sulfur content than 0.5% were anticipated to increase drastically. Such drastic change in SO2 emissions with the change in sulfur content is attributable to non-linear nature of reaction rate for attrition-enhanced desulfurization by limestone.

Wet separation processes as method to separate limestone and oil shale

NASA Astrophysics Data System (ADS)

Nurme, Martin; Karu, Veiko

2015-04-01

Biggest oil shale industry is located in Estonia. Oil shale usage is mainly for electricity generation, shale oil generation and cement production. All these processes need certain quality oil shale. Oil shale seam have interlayer limestone layers. To use oil shale in production, it is needed to separate oil shale and limestone. A key challenge is find separation process when we can get the best quality for all product types. In oil shale separation typically has been used heavy media separation process. There are tested also different types of separation processes before: wet separation, pneumatic separation. Now oil shale industry moves more to oil production and this needs innovation methods for separation to ensure fuel quality and the changes in quality. The pilot unit test with Allmineral ALLJIG have pointed out that the suitable new innovation way for oil shale separation can be wet separation with gravity, where material by pulsating water forming layers of grains according to their density and subsequently separates the heavy material (limestone) from the stratified material (oil shale)bed. Main aim of this research is to find the suitable separation process for oil shale, that the products have highest quality. The expected results can be used also for developing separation processes for phosphorite rock or all others, where traditional separation processes doesn't work property. This research is part of the study Sustainable and environmentally acceptable Oil shale mining No. 3.2.0501.11-0025 http://mi.ttu.ee/etp and the project B36 Extraction and processing of rock with selective methods - http://mi.ttu.ee/separation; http://mi.ttu.ee/miningwaste/

Conodont biostratigraphy and biofacies of the Lisburne Group

DOE Office of Scientific and Technical Information (OSTI.GOV)

Harris, A.G.; Krumhardt, A.P.; Watts, K.F.

1995-05-01

Conodont data from the Lisburne Group are presented in three parts. Part 1 summarizes the thesis work of Andrea P. Krumhardt on the conodont biostratigraphy and biofacies of the Wahoo Limestone in the eastern Sadlerochit Mountains. This is virtually the same report as Krumhardt and others. A more detailed report on the Wahoo Limestone is in the final stages of preparation as a US Geological Survey Professional Paper. The major results of this study include the precise determination of the Mississippian-Pennsylvanian boundary within the lower member of the Wahoo Limestone and establishment of a conodont biostratigraphy for the Pennsylvanian partmore » of the Wahoo that is applicable to northern Alaska. Conodont biofacies are related to depositional environments and compared with carbonate microfacies analyses; both indicate high-energy, chiefly normal-marine conditions in the northern part ANWR. Part 2 describes the conodont zonation used for the middle Carboniferous in northern Alaska and the criteria used for assigning ages. A series of chronostratigraphic diagrams illustrates age variations and correlation of the Lisburne Group in ANWR, at two localities in the central Brooks Range, and in wells in the National Petroleum Reserve in Alaska. Part 3 includes a map showing conodont color alteration indices. Variations in the thermal history of different parts of ANWR are related to the tectonics of the northeastern Brooks Range.« less

Sulfur determination in concrete samples using laser-induced breakdown spectroscopy and limestone standards

NASA Astrophysics Data System (ADS)

Hrdlička, Aleš; Hegrová, Jitka; Novotný, Karel; Kanický, Viktor; Prochazka, David; Novotný, Jan; Modlitbová, Pavlína; Sládková, Lucia; Pořízka, Pavel; Kaiser, Jozef

2018-04-01

A LIBS equipment operating at 532 nm was optimized and used for sulfur determination in concrete samples. The influence of He atmosphere in a gas-tight chamber (1000-200 mbar) on S I 921.29 nm line sensitivity, signal-to-background and signal-to-noise ratio was studied at gate delays 100-2000 ns. Wide range of gate delays from 500 to about 1000 ns and pressures from several hundreds of mbar to the atmospheric pressure can be used for the desired detection of sulfur. The LIBS quantification was done using a simple calibration method. A synthetic limestone enriched by defined amounts of sodium sulfate was newly employed for direct quantification of S in concrete. This powder material was pressed into pellets and ablated with the LIBS system. The average content of sulfur as SO3 in the samples was 0.41-0.70 wt% by LIBS and 0.43-0.61 wt% by a reference standard procedure employing gravimetry and Inductively Coupled Plasma Triple Quad Mass Spectrometry (ICP-QQQMS). The uncertainty of the yielded LIBS results covers also the dispersion of the points in the calibration line and ranges from 16 to 28% at the probability level of 95%. The uncertainty of the ICP-QQQMS results was almost 10%. No correction on different signal response on the limestone and on the concrete was necessary.

Assessment of kinetic models on Fe adsorption in groundwater using high-quality limestone

NASA Astrophysics Data System (ADS)

Akbar, N. A.; Kamil, N. A. F. Mohd; Zin, N. S. Md; Adlan, M. N.; Aziz, H. A.

2018-04-01

During the groundwater pumping process, dissolved Fe2+ is oxidized into Fe3+ and produce rust-coloured iron mineral. Adsorption kinetic models are used to evaluate the performance of limestone adsorbent and describe the mechanism of adsorption and the diffusion processes of Fe adsorption in groundwater. This work presents the best kinetic model of Fe adsorption, which was chosen based on a higher value of coefficient correlation, R2. A batch adsorption experiment was conducted for various contact times ranging from 0 to 135 minutes. From the results of the batch study, three kinetic models were analyzed for Fe removal onto limestone sorbent, including the pseudo-first order (PFO), pseudo-second order (PSO) and intra-particle diffusion (IPD) models. Results show that the adsorption kinetic models follow the sequence: PSO > PFO > IPD, where the values of R2 are 0.997 > 0.919 > 0.918. A high value of R2 (0.997) reveals better fitted experimental data. Furthermore, the value of qe cal in the PSO kinetic model is very near to qe exp rather than that in other models. This finding therefore suggests that the PSO kinetic model has the good fitted with the experimental data which involved chemisorption process of divalent Fe removal in groundwater solution. Thus, limestone adsorbent media found to be an alternative and effective treatment of Fe removal from groundwater.

Shear Model Development of Limestone Joints with Incorporating Variations of Basic Friction Coefficient and Roughness Components During Shearing

NASA Astrophysics Data System (ADS)

Mehrishal, Seyedahmad; Sharifzadeh, Mostafa; Shahriar, Korosh; Song, Jae-Jon

2017-04-01

In relation to the shearing of rock joints, the precise and continuous evaluation of asperity interlocking, dilation, and basic friction properties has been the most important task in the modeling of shear strength. In this paper, in order to investigate these controlling factors, two types of limestone joint samples were prepared and CNL direct shear tests were performed on these joints under various shear conditions. One set of samples were travertine and another were onyx marble with slickensided surfaces, surfaces ground to #80, and rough surfaces were tested. Direct shear experiments conducted on slickensided and ground surfaces of limestone indicated that by increasing the applied normal stress, under different shearing rates, the basic friction coefficient decreased. Moreover, in the shear tests under constant normal stress and shearing rate, the basic friction coefficient remained constant for the different contact sizes. The second series of direct shear experiments in this research was conducted on tension joint samples to evaluate the effect of surface roughness on the shear behavior of the rough joints. This paper deals with the dilation and roughness interlocking using a method that characterizes the surface roughness of the joint based on a fundamental combined surface roughness concept. The application of stress-dependent basic friction and quantitative roughness parameters in the continuous modeling of the shear behavior of rock joints is an important aspect of this research.

Effect of confining pressure on diffusion coefficients in clay-rich, low-permeability sedimentary rocks.

PubMed

Xiang, Y; Al, T; Mazurek, M

2016-12-01

The effect of confining pressure (CP) on the diffusion of tritiated-water (HTO) and iodide (I - ) tracers through Ordovician rocks from the Michigan Basin, southwestern Ontario, Canada, and Opalinus Clay from Schlattingen, Switzerland was investigated in laboratory experiments. Four samples representing different formations and lithologies in the Michigan Basin were studied: Queenston Formation shale, Georgian Bay Formation shale, Cobourg Formation limestone and Cobourg Formation argillaceous limestone. Estimated in situ vertical stresses at the depths from which the samples were retrieved range from 12.0 to 17.4MPa (Michigan Basin) and from 21 to 23MPa (Opalinus Clay). Effective diffusion coefficients (D e ) were determined in through-diffusion experiments. With HTO tracer, applying CP resulted in decreases in D e of 12.5% for the Queenston Formation shale (CP max =12MPa), 30% for the Georgian Bay Formation shale (15MPa), 34% for the Cobourg Formation limestone (17.4MPa), 31% for the Cobourg Formation argillaceous limestone (17.4MPa) and 43-46% for the Opalinus Clay (15MPa). Decreases in D e were larger for the I - tracer: 13.8% for the Queenston shale, 42% for the Georgian Bay shale, 50% for the Cobourg Formation limestone, 55% for the Cobourg Formation argillaceous limestone and 63-68% for the Opalinus Clay. The tracer-specific nature of the response is attributed to an increasing influence of anion exclusion as the pore size decreases at higher CP. Results from the shales (including Opalinus Clay) indicate that the pressure effect on D e can be represented by a linear relationship between D e and ln(CP), which provides valuable predictive capability. The nonlinearity results in a relatively small change in D e at high CP, suggesting that it is not necessary to apply the exact in situ pressure conditions in order to obtain a good estimate of the in situ diffusion coefficient. Most importantly, the CP effect on shale is reversible (±12%) suggesting that, for argillaceous rocks, it is possible to obtain D e values that are representative of the in-situ condition by conducting measurements on re-pressurized samples that were obtained with standard drilling practices. This may not be the case for brittle rock samples as the results from limestone suggest that irreversible damage occurred during the pressure cycling. Copyright © 2016 Elsevier B.V. All rights reserved.

Cretaceous planktic foraminiferal biostratigraphy of the Calera Limestone, Northern California, USA

USGS Publications Warehouse

Sliter, W.V.

1999-01-01

The Calera Limestone is the largest, most stratigraphically extensive limestone unit of oceanic character included in the Franciscan Complex of northern California. The aim of this paper is to place the Calera Limestone at its type locality (Rockaway Beach, Pacifica) in a high-resolution biostratigraphy utilizing planktic foraminifers studied in thin section. A section, about 110 m-thick, was measured from the middle thrust slice exposed by quarrying on the southwest side of Calera Hill at Pacifica Quarry. Lithologically, the section is divided in two units; a lower unit with 73 m of black to dark-grey limestone, black chert and tuff, and an upper unit with 36.8 m of light-grey limestone and medium-grey chert. Two prominent black-shale layers rich in organic carbon occur 11 m below the top of the lower black unit and at the boundary with overlying light-grey unit, yielding a total organic content (TOC) of 4.7% and 1.8% t.w., respectively. The fossiliferous Calera Limestone section measured at Pacifica Quarry, from the lower black shale, contains eleven zones and three subzones that span approximately 26 m.y. from the early Aptian to the late Cenomanian. The zones indentified range from the Globigerinelloides blowi Zone to the Dicarinella algeriana Subzone of the Rotalipora cushmani Zone. Within this biostratigraphic interval, the Ticinella bejaouaensis and Hedbergella planispira Zones at the Aptian/Albian boundary are missing as are the Rotalipora subticinensis Subzone of the Biticinella breggiensis Zone and the overlying Rotalipora ticinensis Zone in the late Albian owing both to low-angle thrust faulting and to unconformities. The abundance and preservation of planktic foraminifers are poor in the lower part and improve only within the upper G. algerianus Zone. The faunal relationship indicate that the lower black shale occurs in the upper part of the G. blowi Zone and correlates with the Selli Event recognized at global scale in the early Aptian. The upper black shale occurs at or near the boundary between the G. ferreolensis and G. algerianus Zone in the late Aptian. This black layer, or Thalmann Event as named here, seems to represent the sedimentary expression, at the scale of Permanente Terrane, of a global perturbation of the carbon cycle.

New Tertiary stratigraphy for the Florida Keys and southern peninsula of Florida

USGS Publications Warehouse

Cunningham, K.J.; McNeill, D.F.; Guertin, L.A.; Ciesielski, P.F.; Scott, T.M.; De Verteuil, L.

1998-01-01

Seven lithologic formations, ranging in age from Oligocene to Pleistocene, were recently penetrated by core holes in southernmost Florida. From bottom to top, they are the early Oligocene Suwannee Limestone; late-early Oligocene-to-Miocene Arcadia Formation, basal Hawthorn Group; late Miocene Peace River Formation, upper Hawthorn Group; newly proposed late Miocene-to-Pliocene Long Key and Stock Island Formations; and Pleistocene Key Largo and Miami Limestones. The rocks of the Suwannee Limestone form a third-order sequence. Although the entire thickness was not penetrated, 96 m of Suwannee core from one well contains at least 50 vertically stacked, exposure-capped limestone cycles, presumably related to rapid eustatic fluctuations while experiencing tropical to subtropical conditions. The Arcadia Formation is a composite sequence containing four high-frequency sequences composed of multiple vertically stacked carbonate cycles. Most cycles do not show evidence of subaerial exposure and were deposited under more temperate conditions, relative to the Suwannee Limestone. The Arcadia Formation in southernmost Florida is bounded by regional unconformities representing third-order sequence boundaries. Post-Arcadia transgression produced a major backstepping of sediment accumulation above the upper sequence boundary of the Arcadia Formation. The Peace River Formation, composed of diatomaceous mudstones, has been identified only beneath the Florida peninsula and is not present beneath the Florida Keys. Deposition occurred during marine transgressive to high-stand conditions and a local phosphatization event (recorded in northeast Florida). The transgression is possibly related to a global rise in sea level, which resulted in upwelling of relatively cooler, relatively nutrient-rich water masses onto the Florida Platform. It is proposed that the absence of Peace River sediments beneath the Keys is due to sediment bypass of the upper surface of the Arcadia, a result of sediment sweeping by an ancestral Florida current. During late Miocene to Pliocene time in the Florida Keys, siliciclastics of the Long Key Formation and fine-grained carbonates of the Stock Island Formation prograded toward the southern edge of the Florida Platform and downlapped onto the regional unconformity at the top of the Arcadia. Shallow-marine Pleistocene limestones (Key Largo and Miami Limestones), deposited during tropical to subtropical conditions, drape over accretionary successions of the Long Key and Stock Island Formations.

MX Siting Investigation Water Resources Program.

DTIC Science & Technology

1980-10-31

bedrock units are highly dependent upon the degree of secondary permeability ( fractures and solution open- ings). Although the first unit is believed to...the Fortification Range. Carbonate rocks, largely limestone and dolomite , are exposed in the Bristol and Highland I ranges. Deposits composing the...infiltration of precipitation, surface runoff, and subsurface underflow from fractured or solutioned volcanic and/or carbonate bedrock. Recharge by di- Irect

Spectral reflectance and soil morphology characteristics of Santa Rita Experimental Range soils

Treesearch

A. Karim Batchily; Donald F. Post; R. B. Bryant; Donald J. Breckenfeld

2003-01-01

The Santa Rita Experimental Range (SRER) soils are mostly transported alluvial sediments that occur on the piedmont slope flanking the Santa Rita Mountains in Arizona. The major geomorphic land forms are alluvial fans or fan terraces, but there are also areas of residual soils formed on granite and limestone bedrock, basin floor, stream terraces, and flood plains. The...

Monitoring regional effects of high pressure injection of wastewater in a limestone aquifer

USGS Publications Warehouse

Faulkner, Glen L.; Pascale, Charles A.

1975-01-01

More than 10 billion gallons (38 × 106 m3) of acid industrial liquid waste has been injected in about 11 years under high pressure into a saline-water-filled part of a limestone aquifer of low transmissivity between 1,400 and 1,700 feet (430 and 520 m) below land surface near Pensacola, Florida. A similar waste disposal system is planned for the same zone at a site about 8.5 miles (13.7 km) to the east. The injection zone is the lower limestone of the Floridan aquifer. The lower limestone is overlain by a confining layer of plastic clay about 220 feet (67 m) thick at the active injection site and underlain by another confining layer of shale and clay. The upper confining layer is overlain by the upper limestone of the Floridan aquifer.The active injection system consists of two injection wells about a quarter of a mile (0.4 km) apart and three monitor wells. Two of the monitor wells (deep monitors) are used to observe hydraulic and geochemical effects of waste injection in the injection zone at locations about 1.5 miles (2.4 km) south and 1.9 miles (3.1 km) north of the center of the injection site. The third well (shallow monitor), used to observe any effects in the upper limestone, is about 100 feet (30 m) from one of the injection wells. Since 1972 the injection zone has also been monitored at a test well at the planned new injection site. Three more monitor wells in the injection zone were activated in early 1974 at sites 17 miles (27 km) northeast, 22 miles (35 km) east and 33 miles (53 km) northeast of the injection site. The six deep monitors provide a system for evaluating the regional effects of injecting wastes. No change in pressure or water quality due to injection was, by mid-1974, evident in the upper limestone at the injection site, but static pressures in the lower limestone at the site had increased 8 fold since injection began in 1963. Chemical analyses indicated probable arrival of the diluted waste at the south monitor well in 1973. By mid-1974 waste evidently had not reached the north monitor well.Calculations indicate that by mid-1974 pressure effects from waste injection extended radially more than 40 miles (64 km) from the injection site. By mid-1974 pressure effects of injection were evident from water-level measurements made at the five deep monitor wells nearest the active injection site. No effects were recognized at the well 33 miles (53 km) away. Less than 20 miles (32 km) northeast of the active injection site, the lower limestone contains fresh water. Changes in the pressure regime due to injection indicate a tendency for northeastward movement of the fresh-water/salt-water interface in the lower limestone.

DOE Office of Scientific and Technical Information (OSTI.GOV)

Burnett, W.C.

Hundreds of islands in the tropical Pacific Ocean contain phosphate deposits ranging from inconsequential to economically significant in size. Although many of these deposits clearly have formed by the interaction of avian guano with underlying limestone, some display evidence of having developed within an aqueous environment. Several of the emergent carbonate islands in the southern part of Palau contain phosphate deposits that the authors speculate formed in anoxic marine lakes, similar to those which still occur on a few of these islands. Lake water, sediments, and sediment pore waters from Jellyfish Lake, on the island of Eil Malk in Palau,more » were analyzed during an expedition in 1987. The results of this investigation supported, but did not provide, conclusive evidence of our hypothesis. Pore water profiles of phosphate and fluoride confirmed precipitation of carbonate fluorapatite. However, the extremely high bulk sediment accumulation rate, driven by the high biological productivity of the surface waters of the lake, dilutes authigenic phosphate to low levels. They have refined their original proposal to suggest that phosphate deposits may form either by: (1) subaerial weathering and concentration of phosphatic sediments after these lakes disappear; or (2) interaction of phosphate-enriched sediment pore solutions with limestone at the underlying contact. Another expedition to test these concepts is being planned.« less

Regional stratigraphic framework of the Lisburne Group of ANWR

DOE Office of Scientific and Technical Information (OSTI.GOV)

Watts, K.F.; Carlson, R.C.; Harris, A.G.

1995-05-01

The Carboniferous Lisburne Group, a major carbonate platform succession, is widely exposed in the Brooks Range and forms an extensive hydrocarbon target in the subsurface of the North Slope of Alaska. Gradationally beneath carbonates of the Lisburne Group, terrigenous sediments of the Mississippian Endicott Group (conglomerate and sandstone of the Kekiktuk Formation overlain by the Kayak Shale) were derived from local and northern (Ellesmerian) source areas. Locally, at the Endicott-Lisburne transition, sandy limestones of the Itkilyariak Formation record another phase of siliciclastic influx that lies above and/or is a lateral equivalent of the Kayak Shale and Lisburne Group in areasmore » adjacent to paleotopographic highs. This siliciclastic to carbonate transition represents a major transgressive succession that onlaps northward over the sub-Mississippian unconformity, a regional angular unconformity and sequence boundary in northern Alaska. The age and nature of onlap depend upon the paleotopography of the underlying sub-Mississippian rocks and regional passive margin subsidence. The Lisburne Group is a thick succession of carbonate rocks subdivided into the Alapah Limestone and overlying Wahoo Limestone, both having informal members.« less

Carbonate crystals precipitated by freshwater bacteria and their use as a limestone consolidant.

PubMed

Zamarreño, Dania V; Inkpen, Robert; May, Eric

2009-09-01

Bacterial carbonate precipitation is known to be a natural phenomenon associated with a wide range of bacterial species. Recently, the ability of bacteria to produce carbonates has been studied for its value in the conservation of limestone monuments and concrete. This paper describes investigations of carbonate crystals precipitated by freshwater bacteria by means of histological (Loeffler's methylene blue and alcian blue-periodic acid-Schiff stain) and fluorescence (CTC [5-cyano-2,3-ditolyl tetrazolium chloride]) stains, determination of cell viability inside carbonate crystals, and pore size reduction in limestone by image analysis. Carbonate crystals were found to be composed of bacteria embedded in a matrix of neutral and acid polysaccharides. Cell viability inside the carbonate crystals decreased with time. On stone, bacteria were found to form carbonate crystals, with only a few bacteria remaining as isolated cells or as cell aggregates. Pore size was reduced by about 50%, but no blockage was detected. Taken together, the results of this research provide some reassurance to conservators that biocalcification by bacteria could be a safe consolidation tool in a restoration strategy for building stone conservation.

Carbonate Crystals Precipitated by Freshwater Bacteria and Their Use as a Limestone Consolidant▿

PubMed Central

Zamarreño, Dania V.; Inkpen, Robert; May, Eric

2009-01-01

Bacterial carbonate precipitation is known to be a natural phenomenon associated with a wide range of bacterial species. Recently, the ability of bacteria to produce carbonates has been studied for its value in the conservation of limestone monuments and concrete. This paper describes investigations of carbonate crystals precipitated by freshwater bacteria by means of histological (Loeffler's methylene blue and alcian blue-periodic acid-Schiff stain) and fluorescence (CTC [5-cyano-2,3-ditolyl tetrazolium chloride]) stains, determination of cell viability inside carbonate crystals, and pore size reduction in limestone by image analysis. Carbonate crystals were found to be composed of bacteria embedded in a matrix of neutral and acid polysaccharides. Cell viability inside the carbonate crystals decreased with time. On stone, bacteria were found to form carbonate crystals, with only a few bacteria remaining as isolated cells or as cell aggregates. Pore size was reduced by about 50%, but no blockage was detected. Taken together, the results of this research provide some reassurance to conservators that biocalcification by bacteria could be a safe consolidation tool in a restoration strategy for building stone conservation. PMID:19617383

CALCIUM CARBONATE DISSOLUTION RATE IN LIMESTONE CONTACTORS

EPA Science Inventory

The rate of carbonate mineral dissolution from limestone was studied using a rotating disk apparatus and samples of limestone of varied composition. The purpose of this study was to determine the effect of limestone composition on the kinetics of carbonate mineral dissolution. Th...

Enhancement of the sulfur capture capacity of limestones by the addition of Na2CO3 and NaCl.

PubMed

Laursen, K; Grace, J R; Lim, C J

2001-11-01

The ability of Na2CO3 and NaCl to enhance the sulfur capture capacity of three limestones was evaluated via fixed-bed calcination and sulfation experiments. The tested limestones represent three different sulfation morphologies: unreacted-core, network, and uniformly sulfated. Treatment with aqueous or powdered Na2CO3 significantly increased the Ca-utilization for two stones which normally sulfate in an unreacted-core pattern (20% to 45%) and network pattern (33% to 49%). The increase was lower for the uniformly sulfated stone (44% to 48%). Na2CO3 treatment increased the number of macropores leading to uniform sulfation of all particles, nearly eliminating the normal strong dependence of utilization on limestone type and particle size. The effect of Na2CO3 is believed to be associated with formation of a eutectic melt which enhances ionic diffusion and accelerates molecular rearrangement of the CaO. Treatment with aqueous NaCl solution caused a decrease in utilization, probably due to formation of large grains and plugging of pores caused by formation of a large amount of eutectic melt. The effect of Na2CO3 is less sensitive than that of NaCl to the amount added and the combustion environment (temperature and gas composition). In addition, Na2CO3 neither promotes corrosion nor forms chlorinated byproducts, which are main concerns associated with NaCl. Thus, Na2CO3 appears to have significant advantages over NaCl for enhancement of limestone sulfur capture capacity in fluidized-bed combustors.

Integration of spectral, spatial and morphometric data into lithological mapping: A comparison of different Machine Learning Algorithms in the Kurdistan Region, NE Iraq

NASA Astrophysics Data System (ADS)

Othman, Arsalan A.; Gloaguen, Richard

2017-09-01

Lithological mapping in mountainous regions is often impeded by limited accessibility due to relief. This study aims to evaluate (1) the performance of different supervised classification approaches using remote sensing data and (2) the use of additional information such as geomorphology. We exemplify the methodology in the Bardi-Zard area in NE Iraq, a part of the Zagros Fold - Thrust Belt, known for its chromite deposits. We highlighted the improvement of remote sensing geological classification by integrating geomorphic features and spatial information in the classification scheme. We performed a Maximum Likelihood (ML) classification method besides two Machine Learning Algorithms (MLA): Support Vector Machine (SVM) and Random Forest (RF) to allow the joint use of geomorphic features, Band Ratio (BR), Principal Component Analysis (PCA), spatial information (spatial coordinates) and multispectral data of the Advanced Space-borne Thermal Emission and Reflection radiometer (ASTER) satellite. The RF algorithm showed reliable results and discriminated serpentinite, talus and terrace deposits, red argillites with conglomerates and limestone, limy conglomerates and limestone conglomerates, tuffites interbedded with basic lavas, limestone and Metamorphosed limestone and reddish green shales. The best overall accuracy (∼80%) was achieved by Random Forest (RF) algorithms in the majority of the sixteen tested combination datasets.

Use of limestone powder during incorporation of Pb-containing cathode ray tube waste in self-compacting concrete.

PubMed

Sua-iam, Gritsada; Makul, Natt

2013-10-15

For several decades, cathode ray tubes (CRTs) were the primary display component of televisions and computers. The CRT glass envelope contains sufficient levels of lead oxide (PbO) to be considered hazardous, and there is a need for effective methods of permanently encapsulating this material during waste disposal. We examined the effect of adding limestone powder (LS) on the fresh and cured properties of self-compacting concrete (SCC) mixtures containing waste CRT glass. The SCC mixtures were prepared using Type 1 Portland cement at a constant cement content of 600 kg/m(3) and a water-to-cement ratio (w/c) of 0.38. CRT glass waste cullet was blended with river sand in proportions of 20 or 40% by weight. To suppress potential viscosity effects limestone powder was added at levels of 5, 10, or 15% by weight. The slump flow time, slump flow diameter, V-funnel flow time, Marsh cone flow time, and setting time of the fresh concrete were tested, as well as the compressive strength and ultrasonic pulse velocity of the hardened concrete. Addition of limestone powder improved the fresh and hardened properties. Pb leaching levels from the cured concrete were within US EPA allowable limits. Copyright © 2013 Elsevier Ltd. All rights reserved.

The role of fly-ash particulate material and oxide catalysts in stone degradation

NASA Astrophysics Data System (ADS)

Hutchinson, A. J.; Johnson, J. B.; Thompson, G. E.; Wood, G. C.; Sage, P. W.; Cooke, M. J.

Studies of fly-ash composition identified the presence of calcium and sulphur, indicating their potential role as sources of calcium sulphate. Residual acidity (particularly for oil fly ash) suggested the possibility of enhanced chemical reaction, and the presence of transition metals, probably as oxides, might accelerate the oxidation of SO 2 to SO 42-. Exposure tests in a laboratory-based rig simulating dry deposition on Portland and Monks Park limestone, either seeded or unseeded with fly-ash particulate material or transition metal oxide catalysts, were carried out using an SO 2-containing environment at 95% r.h. Enhanced sulphation of these seeded limestones due to the above factors was minimal; at high loadings of fly ash, there was even evidence of masking the limestone surface, reducing sulphation. However, pure CaCO 3 powder in the exposure rig showed increases in sulphation when seeded with metal oxide catalysts. Thus the limestones examined contained sufficient inherent catalysts for the oxidation of SO 2 to SO 42- to proceed at such a rate that external catalysts were superfluous. This implies that dissolution rate of SO 2 in moisture films controls the availability of species for reaction with these carbonate-based stones and that fly ash deposited from the atmosphere does not enhance the reaction.

Laser scan of the Grimming Mts. (Austria) with the latest LiDAR VZ-4000 equipment: preliminary results

NASA Astrophysics Data System (ADS)

Bauer, Harald; Hatzenbichler, Georg; Amon, Philipp; Fallah, Mohammad; Tari, Gabor; Grasemann, Bernhard

2013-04-01

As part of a cooperation project between OMV, RIEGL and the University of Vienna the new LiDAR (Light Detection and Ranging) VZ-4000 laser scanner was tested at the Grimming Mts. of the Eastern Alps in Austria. The prominent Grimming Mts. lies in the eastern part of the Dachstein Massif at the southern margin of the Northern Calcareous Alps. The Grimming, with a peak of 2,351 m above sea level, is one of the highest isolated mountains in Europe. Because of its spectacular topography, the Grimming has been used as an important surface reference mark since 1822. From a structural geology standpoint, the Grimming forms a huge antiform made up of dominantly well-bedded Triassic Dachstein Limestone. Because of the relatively well exposed bedrock surfaces above the tree-line and the fairly complex internal structure, the Grimming Mts. provides an ideal target for testing new high resolution laser scan techniques and devices. The maximum distance from the scanning positions on the nearby valley floor to the mountain face was about 4,500 m and the generated point cloud has an average resolution of 25 points per square meter. The purpose of this work was to test the latest version of the high resolution LiDAR laser equipment in a setting which falls beyond the capabilities of most existing LiDAR devices. The results of the pilot study include high-resolution spatial data on bedding planes, fault planes and the thickness variations of individual beds within the Dachstein Limestone. For the first time, the data obtained can be directly used to generate the proper 3D geometry of folds and faults observed on the Grimming Mts. This leads to a modern understanding of this prominent Alpine anticline in terms of structural geology.

The effect of stress on limestone permeability and its effective stress behavior

NASA Astrophysics Data System (ADS)

Meng, F.; Baud, P.; Ge, H.; Wong, T. F.

2017-12-01

The evolution of permeability and its effective stress behavior is related to inelastic deformation and failure mode. This was investigated in Indiana and Purbeck limestones with porosities of 18% and 13%, respectively. Hydrostatic and triaxial compression tests were conducted at room temperature on water-saturated samples at pore pressure of 5 MPa and confining pressures up to 90 MPa. Permeability was measured using steady flow at different stages of deformation. For Indiana limestone, under hydrostatic loading pore collapse initiated at critical pressure P* 55 MPa with an accelerated reduction of permeability by 1/2. At a confinement of 35 MPa and above, shear-enhanced compaction initiated at critical stress C*, beyond which permeability reduction up to a factor of 3 was observed. At a confinement of 15 MPa and below, dilatancy initiated at critical stress C', beyond which permeability continued to decrease, with a negative correlation between porosity and permeability changes. Purbeck limestone showed similar evolution of permeability. Microstructural and mercury porosimetry data showed that pore size distribution in both Indiana and Purbeck limestones is bimodal, with significant proportions of macropores and micropores. The effective stress behaviour of a limestone with dual porosity is different from the prediction for a microscopically homogeneous assemblage, in that its effective stress coefficients for permeability and porosity change may attain values significantly >1. Indeed this was confirmed by our measurements (at confining pressures of 7-15 MPa and pore pressures of 1-3 MPa) in samples that had not been deformed inelastically. We also investigated the behavior in samples hydrostatically and triaxially compacted to beyond the critical stresses P* and C*, respectively. Experimental data for these samples consistently showed effective stress coefficients for both permeability and porosity change with values <1. Thus the effective stress behavior in an inelastically compacted sample is fundamentally different, with attributes akin to that of a microscopically homogeneous assemblage. This is likely related to compaction from pervasive collapse of macropores, which would effectively homogenize the initially bimodal pore size distribution.

Calcium silicate cement sorbent for H/sub 2/S removal and improved gasification processes. Final report

DOE Office of Scientific and Technical Information (OSTI.GOV)

Yoo, H.J.; Steinberg, M.

1983-10-01

Based on the studies performed on the agglomerated cement sorbent (ACS) pellet for in-situ desulfurization of gases and for improved gasification, in low and medium Btu fluidized bed coal gasifier (FBG) systems, the following conclusions can be drawn: (1) The pelletization method by a drum pelletizer is a good way of agglomerating large sized (>20 US mesh) ACS pellets having high sorbent performance. (2) The ACS pellets have a sulfur capture capacity of about 60% at 950/sup 0/C, are 100% regenerable, and so not lose reactivity during cyclic use. (3) The rate of sulfidation increases linearly with H/sub 2/S concentrationmore » in the feed gas stream up to 1.0%. (4) The rate of sulfidation first increases with temperature in an Arrhenius fashion in the temperature range of 800/sup 0/C to 1000/sup 0/C and then decreases with further increase in temperatures, giving rise to an optimum sulfidation temperature of about 1000/sup 0/C. (5) The gasification of coal or coal char either with CO/sub 2/ gas or by partial oxidation in a 40 mm ID FBG shows that the gasification efficiency of coal (or coal char) is very much enhanced with the ACS pellets and with Greer limestone over the coal (or coal char) alone. There is, however, not much difference between the ACS pellets and Greer limestone in the degree of enhancement. (6) The gasification of coal by partial oxidation with air to low Btu gas in a 1-inch coal-fired FBG unit shows that in the temperature range of 800/sup 0/ to 900/sup 0/C the efficiency of coal gasification is improved by as much as 40% when ACS pellets are used compared to the use of Greer limestone. At the same time the sulfur removal efficiency is increased from 50 to 65% with Greer limestone to over 95% with the ACS pellets.« less

Diagenetic evidence for an epigenetic origin of the Courtbrown Zn-Pb deposit, Ireland

NASA Astrophysics Data System (ADS)

Reed, Christopher P.; Wallace, Malcolm W.

2001-08-01

Mineralisation at the Courtbrown deposit in south-western Ireland is concentrated in the basal section of the Chadian Waulsortian Limestone, immediately above the Courceyan Ballysteen Limestone. Two episodes of sulphide deposition have been identified: an early stage of minor pyrite precipitation, and a later base-metal-rich mineralisation event. Sphalerite, galena and pyrite of the later mineralisation event occur predominantly as replacement phases along stylolites, dissolution seams, and within the micritic matrix of the host limestone. These sulphide minerals also occur as cements within late stage fractures. The following diagenetic phases are present in the Waulsortian and Ballysteen Limestones in the Courtbrown area (from oldest to youngest): non-luminescent synsedimentary calcite cements, non-luminescent equant calcite cements, bright luminescent calcite cement, dull luminescent calcite cement, planar dolomite cement and replacement dolomite (regional dolomite), saddle dolomite cement, and fibrous dull luminescent calcite cement filling pressure-shadows around the sulphide minerals. Homogenisation temperatures for primary fluid inclusions within dull luminescent calcite cements (precipitated penecontemporaneously with base-metal mineralisation) range from 160 to 200 °C, with a mode at 170-180 °C. These values are unlikely to be representative of mineralisation temperatures as the fluid inclusions may have been significantly affected by heating and/or deformation during late burial (maximum paleotemperatures from Ro and CAI data around 310 °C). The observed paragenetic sequence indicates that mineralisation is completely epigenetic. As the earliest mineralisation is hosted by macro-stylolites, the sequence must have obtained a minimum burial depth of around 800 m prior to the onset of mineralisation. A burial depth of 800 m would correspond to an approximate early Chadian age for the Courtbrown area. Pressure-shadows around sphalerite further indicate that mineralisation preceded the major phase of Variscan deformation. Therefore, the base-metal mineralisation at Courtbrown is epigenetic, and the age of mineralisation is in the range of 350 to 307 Ma.

Grainstones and cementstone mounds: The Trogkofel summit section (Lower Permian, Carnic Alps, Austria).

NASA Astrophysics Data System (ADS)

Schaffhauser, M.; Sanders, D.; Krainer, K.

2009-04-01

In the Carnic Alps, Austria, an Artinskian succession 400 m thick of shallow-water bioclastic limestones and of mounds composed of ?Archaeolithophyllum, Archaeolithoporella and abundant fibrous cementstone (after former aragonite) records deposition along a "grainstone-dominated" platform margin. The section was taken along the route through the east-facing cliff of Trogkofel. The Trogkofel Limestone (Artinskian pro parte) is excellently exposed and preserved the most complete along this route, but no section has hitherto been logged. The total thickness of the Trogkofel Limestone probably is about 550 meters; the summit section comprises its upper 400 meters. The section consists mainly of shallow-water bioclastic limestones (grainstones, packstones, rudstones) intercalated with cementstone mounds. Both the bioclastic limestones and the mounds typically are thick-bedded to, more commonly, unbedded. Throughout the section, intervals a few tens of meters in thickness dominated by bioclastic limestones change vertically with intervals dominated by cementstone mounds. Up-section, no clear-cut trend with respect to prevalent facies, mean depositional water depth, and energy index is obvious. Furthermore, no lime-muddy, meter-scale peritidal cycles, and no teepee structures and no pisolite levels were identified; thin intervals of fenestral lime mudstones and/or of cryptmicrobially-laminated limestones are very rare. The bioclastic limestones commonly weather out unstratified, or show subhorizontal stratification or, more rarely, low-angle cross-stratification. In the upper 100 meters of section, grainstones to fine-grained rudstones rich in keystone vugs are prevalent. The cementstone mounds comprise intervals up to a few meters in thickness; the biogenic component is characterized by foliose crusts pertaining to ?Archaeolithophyllum hidensis and Archaeolithoporella, overgrown by Tubiphytes and fenestrate bryozoans. The ?Archaeolithophyllum-Archaeolithoporella crusts are overgrown by abundant, thick fringes and botryoids of fibrous cement that is interpreted as calcitized aragonite cement. In addition, brachiopods, crustose red algae, and a few solitary and colonial rugose corals are typical. By volume, the former aragonite cement comprises the majority of the mounds. Intrinsic pores within the cementstone fabrics typically are filled by micropeloidal grainstone and/or by lime mudstone. The Trogkofel Limestone is locally dolomitized. Replacement dolomites show a wide range of crystal shapes and textures, but overall comprise (a) finely-crystalline, limpid dolostone of xenotopic or hypidiotopic fabrics that broadly mimick the texture of replaced sediment and cements, (b) coarse-crystalline fabrics of hypidiotopic to idiotopic, limpid or optically zoned dolomite, and (c) replacement saddle dolomite. The Trogkofel Limestone is riddled by karstic dykes and caverns that are mainly filled by, both or either of, geopetally-laminated red lime mudstone, terrigenous red sandstones, or thick fringes of fibrous cement. In the karstic cavity fills, packages of convolute geopetal lamination and brecciated internal sediments (internal seismites) overlain by infills with non-convolute lamination, fracture of fibrous cements, and dykes filled by multi-phase fracture breccias record tectonism during or after deposition of the Trogkofel Limestone. The Trogkofel Limestone is capped by a truncation surface which, in turn, is overlain by an interval of extremely poorly sorted, thick-bedded breccias with a former matrix of lime mudstone ("Trogkofel Breccia"). Both the components and the matrix of the Trogkofel Breccia are dolomitized. We interpret the facies and facies architecture of the eastern cliff section of Trogkofel as succession from the seaward side of a "grainstone-dominated" platform margin with cementstone mounds. The lack of clear-cut vertical trends in prevalent facies suggests that the platform margin developed mainly by aggradation. The timing and processes of replacement dolomitization(s) to date are poorly constrained. The presence of saddle dolomite nevertheless indicates passage of dolomitizing fluids of more than 90-100°C.

Vertical small scale variations of sorption and mineralization of three herbicides in subsurface limestone and sandy aquifer

NASA Astrophysics Data System (ADS)

Janniche, G. S.; Mouvet, C.; Albrechtsen, H.-J.

2011-04-01

Vertical variation in sorption and mineralization potential of mecoprop (MCPP), isoproturon and acetochlor were investigated at low concentrations (μg-range) at the cm-scale in unsaturated sub-surface limestone samples and saturated sandy aquifer samples from an agricultural catchment in Brévilles, France. From two intact core drills, four heterogenic limestone sections were collected from 4.50 to 26.40 m below surface (mbs) and divided into 12 sub-samples of 8-25 cm length, and one sandy aquifer section from 19.20 to 19.53 m depth divided into 7 sub-samples of 4-5 cm length. In the sandy aquifer section acetochlor and isoproturon sorption increased substantially with depth; in average 78% (acetochlor) and 61% (isoproturon) per 5 cm. Also the number of acetochlor and isoproturon degraders (most-probable-number) was higher in the bottom half of the aquifer section (93-> 16 000/g) than in the upper half (4-71/g). One 50 cm long limestone section with a distinct shift in color showed a clear shift in mineralization, number of degraders and sorption: In the two brown, uppermost samples, up to 31% mecoprop and up to 9% isoproturon was mineralized during 231 days, the numbers of mecoprop and isoproturon degraders were 1300 to > 16 000/g, and the sorption of both isoproturon and acetochlor was more than three times higher, compared to the two deeper, grayish samples just below where mineralization (≤ 4%) and numbers of degraders (1-520/g) were low for all three herbicides. In both unsaturated limestone and sandy aquifer, variations and even distinct shifts in both mineralization, number of specific degraders and sorption were seen within just 4-15 cm of vertical distance. A simple conceptual model of herbicides leaching to groundwater through a 10 m unsaturated limestone was established, and calculations showed that a 30 cm active layer with the measured sorption and mineralization values hardly impacted the fate of the investigated herbicides, whereas a total thickness of layers of 1 m would substantially increase natural attenuation.

Evaluation of Skid Resistance of Wearing Course Made Of Stone Mastic Asphalt Mixture in Laboratory Conditions

NASA Astrophysics Data System (ADS)

Wasilewska, Marta

2017-10-01

This paper presents the comparison of skid resistance of wearing course made of SMA (Stone Mastic Asphalt) mixtures which differ in resistance to polishing of coarse aggregate. Dolomite, limestone, granite and trachybasalt were taken for investigation. SMA mixtures have the same nominal size of aggregate (11 mm) and very similar aggregate particle-size distribution in mineral mixtures. Tested SMA11 mixtures were designed according to EN 13108-5 and Polish National Specification WT-2: 2014. Evaluation of the skid resistance has been performed using the FAP (Friction After Polishing) test equipment also known as the Wehner/Schulze machine. Laboratory method enables to compare the skid resistance of different types of mixtures under specified conditions simulating polishing processes. Tests were performed on both the specimens made of each coarse aggregate and SMA11 mixtures containing these aggregates. Measuring of friction coefficient μm was conducted before and during polishing process up to 180 0000 passes of polishing head. Comparison of the results showed differences in sensitivity to polishing among particular mixtures which depend on the petrographic properties of rock used to produce aggregate. Limestone and dolomite tend to have a fairly uniform texture with low hardness which makes these rock types susceptible to rapid polishing. This caused lower coefficient of friction for SMA11 mixtures with limestone and dolomite in comparison with other test mixtures. These significant differences were already registered at the beginning of the polishing process. Limestone aggregate had lower value of μm before starting the process than trachybasalt and granite aggregate after its completion. Despite the differences in structure and mineralogical composition between the granite and trachybasalt, slightly different values of the friction coefficient at the end of polishing were obtained. Images of the surface were taken with the optical microscope for better understanding of the phenomena occurring on the surface of specimen. Results may be valuable information when selecting aggregate to asphalt mixtures at the stage of its design and maintenance of existing road pavements.

A quantitative comparison of moldic and vuggy porosity structure in karst aquifers using image and geospatial analysis

NASA Astrophysics Data System (ADS)

Culpepper, A. R.; Manda, A. K.

2011-12-01

Limestone aquifers are vital sources of groundwater for domestic and industrial use throughout the world. To sustain rising population throughout the southeastern United States, aquifers are increasingly exploited to provide the populace clean and reliable water resources. The moldic Castle Hayne and the vuggy Biscayne aquifer systems are two highly productive aquifers that provide critical water resources to millions of citizens in eastern North Carolina and southeastern Florida, respectively. In order to better understand karst aquifers and evaluate the potential for contaminant transport, detailed investigation of 2D porosity and pore geometry using image and geospatial analysis were undertaken. The objective of this study is to compare and contrast the porosity structure of moldic and vuggy karst aquifers by quantifying 2D porosity and pore geometry from images of slabbed core samples and optical televiewer images. Televiewer images and images of painted core samples from the Spring Garden Member of the Castle Hayne aquifer and Miami Limestone Formation of the Biscayne aquifer were acquired for analysis of porosity structure. The procedure for converting images of slabbed core and televiewer images to a GIS useable format consisted of rectification, calibration, image enhancement, classification, recoding and filtering. In GIS, raster or vector formats were used to assess pore attributes (e.g., area and perimeter) and structure. Preliminary results show that both pore area and perimeter for the Spring Garden Member of the Castle Hayne and Miami Limestone Formation of the Biscayne aquifers can be described by exponential distributions. In both sets of slabbed core images the relatively small pores have the highest occurrence, whereas larger pores occur less frequently. However, the moldic Spring Garden Member of the Castle Hayne aquifer has larger pore sizes derived from cores images than the vuggy Miami Limestone Formation of Biscayne aquifer. Total porosity derived from core images for the Spring Garden Member averages 37.5% whereas total porosity from the Miami Limestone Formation ranges between 10-48%. Analyses of televiewer images reveal the Miami Limestone Formation consists of conduits that range in aperture from a minimum of 0.86 cm to a maximum of 159 cm with an occurrence frequency of one conduit every two meters. Whereas, televiewer images of the Spring Garden Member of the Castle Aquifer do not reveal any conduits. This study presents an example of how quantitative measures of pore attributes and structure can be used to compare karst media with different porosity characteristics. Such measures will lead to a better understanding of porosity structure in karst aquifers that can be useful for designing and running ground water flow models and assessing transport mechanisms in karst media.

PILOT PLANT TESTING OF ELEMENTAL MERCURY RE-EMISSION FROM WET SCRUBBERS

EPA Science Inventory

A pilot-scale wet lime/limestone flue gas desulfurization scrubber system was designed to conduct mercury emission control research. The first tests focused on investigating the phenomenon of Hgo re-emission from wet scrubbers with a specific objective of developing a Hgo re-emis...

Hot mix asphalt (HMA) characterization for the 2002 AASHTO design guide.

DOT National Transportation Integrated Search

2008-09-30

The two study objectives were to conduct dynamic modulus and APA rutting tests of selected Mississippi HMA mixtures. A total of twenty-five mixtures were tested including aggregate combinations of gravel and gravel/limestone; 9.5mm, 12.5mm and 19.0mm...

Stratigraphic and palaeoenvironmental summary of the south-east Georgia Embayment: a correlation of exploratory wells

USGS Publications Warehouse

Poppe, L.J.; Popenoe, P.; Poag, C.W.; Swift, B.A.

1995-01-01

A Continental Offshore Stratigraphic Test (COST) well and six exploratory wells have been drilled in the south-east Georgia embayment. The oldest rocks penetrated are weakly metamorphosed Lower Ordovician quartz arenites and Silurian shales and argillites in the Transco 1005-1 well and Upper Devonian argillites in the COST GE-1 well. The Palaeozoic strata are unconformably overlain by interbedded non-marine Jurassic sandstones and shales and marginal marine Lower Cretaceous rocks. Together, these rocks are stratigraphically equivalent to the onshore Fort Pierce and Cotton Valley(?) Formations and rocks of the Lower Cretaceous Comanchean Provincial Series. The Upper Cretaceous part of the section is composed mainly of neritic calcareous shales and shaley limestones stratigraphically equivalent to the primarily marginal marine facies of the onshore Atkinson, Cape Fear and Middendorf Formations and Black Creek Group, and to limestones and shales of the Lawson Limestone and Peedee Formations. Cenozoic strata are also described. -from Authors

Microbiological assessment of the application of quicklime and limestone as a measure to stabilize the structure of compaction-prone soils

NASA Astrophysics Data System (ADS)

Deltedesco, Evi; Bauer, Lisa-Maria; Unterfrauner, Hans; Peticzka, Robert; Zehetner, Franz; Keiblinger, Katharina Maria

2014-05-01

Compaction of soils is caused by increasing mechanization of agriculture and forestry, construction of pipelines, surface mining and land recultivation. This results in degradation of aggregate stability and a decrease of pore space, esp. of macropores. It further impairs the water- and air permeability, and restricts the habitat of soil organisms. A promising approach to stabilize the structure and improve the permeability of soils is the addition of polyvalent ions like Ca2+ which can be added in form of quicklime (CaO) and limestone (CaCO3). In this study, we conducted a greenhouse pot experiment using these two different sources of calcium ions in order to evaluate their effect over time on physical properties and soil microbiology. We sampled silty and clayey soils from three different locations in Austria and incubated them with and without the liming materials (application 12.5 g) for 3 months in four replicates. In order to assess short-term and medium-term effects, soil samples were taken 2 days, 1 month and 3 months after application of quicklime and limestone, respectively. For these samples, we determined pH, bulk density, aggregate stability and water retention characteristics. Further, we measured microbiological parameters, such as potential enzyme activities (cellulase, phosphatase, chitinase, protease, phenoloxidase and peroxidase activity), PLFAs, microbial biomass carbon and nitrogen, dissolved organic carbon and nitrogen, nitrate nitrogen and ammonium nitrogen. In contrast to limestone, quicklime significantly improved soil aggregate stability in all tested soils only 2 days after application. Initially, soil pH was strongly increased by quicklime; however, after the second sampling (one month) the pH values of all tested soils returned to levels comparable to the soils treated with limestone. Our preliminary microbiological results show an immediate inhibition effect of quicklime on most potential hydrolytic enzyme activities and an increase in oxidative enzyme activities. These effects seem to be less pronounced in the medium term. In summary our results indicate, that the application of quicklime is a feasible measure for immediate stabilization of the structure of compaction-prone soils, showing only short-term impact on most microbial parameters.

Dry and stable excavations in limestones of the greater Kansas City area of Missouri and Kansas

DOE Office of Scientific and Technical Information (OSTI.GOV)

Goebel, E.D.; Parizek, E.J.; Stauffer, T.P.

In the Greater Kansas City area of Missouri and Kansas the bedrock consists largely of a thick sequence of limestone and shale formations of Pennsylvanian age. Three formations are of interest in this report. The Swope Formation contains the Bethany Falls Limestone, the Wyandotte Formation contains the Argentine Limestone and the Farley Limestone, and the Oread Formation contains the Plattsmouth Limestone. Underground workings have been developed by industry in these three formations for a variety of uses, including factories, offices and warehouses. The Bethany Falls Limestone is the unit most widely developed for secondary underground use. The industries which design,more » excavate, and occupy this man-made underground space consider it to be essentially dry and stable. Identification and description of the geologic, topographic, hydrologic, and possible other unique features which allow this operational decision is the primary goal of this investigation.« less

21 CFR 184.1409 - Ground limestone.

Code of Federal Regulations, 2011 CFR

2011-04-01

... 21 Food and Drugs 3 2011-04-01 2011-04-01 false Ground limestone. 184.1409 Section 184.1409 Food... Specific Substances Affirmed as GRAS § 184.1409 Ground limestone. (a) Ground limestone consists essentially (not less than 94 percent) of calcium carbonate (CaCO3) and is prepared by the crushing, grinding, and...

21 CFR 184.1409 - Ground limestone.

Code of Federal Regulations, 2010 CFR

2010-04-01

... 21 Food and Drugs 3 2010-04-01 2009-04-01 true Ground limestone. 184.1409 Section 184.1409 Food... Specific Substances Affirmed as GRAS § 184.1409 Ground limestone. (a) Ground limestone consists essentially (not less than 94 percent) of calcium carbonate (CaCO3) and is prepared by the crushing, grinding, and...

Modeling of Hydration, Compressive Strength, and Carbonation of Portland-Limestone Cement (PLC) Concrete.

PubMed

Wang, Xiao-Yong

2017-01-26

Limestone is widely used in the construction industry to produce Portland limestone cement (PLC) concrete. Systematic evaluations of hydration kinetics, compressive strength development, and carbonation resistance are crucial for the rational use of limestone. This study presents a hydration-based model for evaluating the influences of limestone on the strength and carbonation of concrete. First, the hydration model analyzes the dilution effect and the nucleation effect of limestone during the hydration of cement. The degree of cement hydration is calculated by considering concrete mixing proportions, binder properties, and curing conditions. Second, by using the gel-space ratio, the compressive strength of PLC concrete is evaluated. The interactions among water-to-binder ratio, limestone replacement ratio, and strength development are highlighted. Third, the carbonate material contents and porosity are calculated from the hydration model and are used as input parameters for the carbonation model. By considering concrete microstructures and environmental conditions, the carbon dioxide diffusivity and carbonation depth of PLC concrete are evaluated. The proposed model has been determined to be valid for concrete with various water-to-binder ratios, limestone contents, and curing periods.

Modeling of Hydration, Compressive Strength, and Carbonation of Portland-Limestone Cement (PLC) Concrete

PubMed Central

Wang, Xiao-Yong

2017-01-01

Limestone is widely used in the construction industry to produce Portland limestone cement (PLC) concrete. Systematic evaluations of hydration kinetics, compressive strength development, and carbonation resistance are crucial for the rational use of limestone. This study presents a hydration-based model for evaluating the influences of limestone on the strength and carbonation of concrete. First, the hydration model analyzes the dilution effect and the nucleation effect of limestone during the hydration of cement. The degree of cement hydration is calculated by considering concrete mixing proportions, binder properties, and curing conditions. Second, by using the gel–space ratio, the compressive strength of PLC concrete is evaluated. The interactions among water-to-binder ratio, limestone replacement ratio, and strength development are highlighted. Third, the carbonate material contents and porosity are calculated from the hydration model and are used as input parameters for the carbonation model. By considering concrete microstructures and environmental conditions, the carbon dioxide diffusivity and carbonation depth of PLC concrete are evaluated. The proposed model has been determined to be valid for concrete with various water-to-binder ratios, limestone contents, and curing periods. PMID:28772472

INITIAL TEST RESULTS OF THE LIMESTONE INJECTION MULTISTAGE BURNER (LIMB) DEMONSTRATION PROJECT

EPA Science Inventory

The paper discusses SO2 removal efficiency and low-NOx burner performance obtained during short term tests, as well as the impact of LIMB ash on electrostatic precipitator (ESP) performance at Ohio Edison's Edgewater Station. Project goals are to demonstrate 50% or more SO2 remov...

DOE Office of Scientific and Technical Information (OSTI.GOV)

Lu, D.Y.; Hughes, R.W.; Anthony, E.J.

Sintering during calcination/carbonation may introduce substantial economic penalties for a CO{sub 2} looping cycle using limestone/dolomite-derived sorbents. Cyclic carbonation and calcination reactions were investigated for CO{sub 2} capture under fluidized bed combustion (FBC) conditions. The cyclic carbonation characteristics of CaCO{sub 3}-derived sorbents were compared at various calcination temperatures (700-925{sup o} C) and different gas stream compositions: pure -2 and a realistic calciner environment where high concentrations of CO{sub 2}>80-90% are expected. The conditions during carbonation were 700 {sup o}C and 15% CO{sub 2} in N{sub 2} and 0.18% or 0.50% SO{sub 2} in selected tests. Up to 20 calcination/carbonation cyclesmore » were conducted using a thermogravimetric analyzer (TGA) apparatus. Three Canadian limestones were tested: Kelly Rock, Havelock, and Cadomin, using a prescreened particle size range of 400-650 {mu} m. Calcined Kelly Rock and Cadomin samples were hydrated by steam and examined. Sorbent reactivity was reduced whenever SO{sub 2} was introduced to either the calcining or carbonation streams. The multicyclic capture capacity of CaO for CO{sub 2} was substantially reduced at high concentrations of CO{sub 2} during the sorbent regeneration process and carbonation conversion of the Kelly Rock sample obtained after 20 cycles was only 10.5%. Hydrated sorbents performed better for CO{sub 2} capture but showed deterioration following calcination in high CO{sub 2} gas streams indicating that high CO{sub 2} and SO{sub 2} levels in the gas stream lead to lower CaO conversion because of enhanced sintering and irreversible formation of CaSO{sub 4}.« less

Lithostratigraphy of Upper Ordovician strata exposed in Kentucky

USGS Publications Warehouse

Weir, Gordon Whitney; Peterson, Warren Lee; Swadley, W.C.

1984-01-01

Ordovician formations above the Lexington Limestone crop out in the Blue Grass region of Kentucky and along the Cumberland River and its tributaries. The formations are all conformable and in places intertongue and intergrade. The major Ordovician units above the Lexington Limestone in the Blue Grass region are: The Clays Ferry Formation, the Kope Formation, the Garrard Siltstone, the Fairview Formation, the Calloway Creek Limestone, the Grant Lake Limestone, the Ashlock Formation, the Bull Fork Formation, and the Drakes Formation. The Clays Ferry Formation is made up of subequal amounts of fossiliferous limestone and shale and minor siltstone; the Clays Ferry is as much as 300 ft thick and intertongues with the Lexington Limestone and the Kope Formation. The Kope Formation resembles the partly equivalent Clays Ferry but has a higher shale content (60-80 percent) and thicker layers of shale; the Kope, as much as 275 ft thick, is mostly restricted to the northern part of the State. The Garrard Siltstone, which consists of very calcitic siltstone and minor shale, overlies the Clays Ferry Formation in the southeastern part of the Blue Grass region; the Garrard, as much as 100 ft thick, feathers out into the upper part of the Clays Ferry in southern central and northern east-central Kentucky. The Fairview Formation is characterized by even-bedded limestone interlayered with nearly equal amounts of shale and minor siltstone. The Fairview crops out in the northern part of the Blue Grass region, where it generally overlies the Kope Formation or the Garrard Siltstone; it grades southward into the Calloway Creek Limestone. The Calloway Creek contains more limestone (generally at least 70 percent) and is more irregularly and thinner bedded than the Fairview. The Grant Lake Limestone is composed of nodular-bedded limestone (70-90 percent), interlayered and intermixed with shale; it overlies the Fairview Formation in the northern part of the Blue Grass region and the Calloway Creek Limestone in the western and central parts. In east-central Kentucky, the Grant Lake is classified as a member of the Ashlock Formation, an assemblage of lithologically distinct units that were combined to facilitate mapping in the southeastern and southern part of the region. The Ashlock consists of the following members, in ascending order: The Tate (calcitic and dolomitic mudstone), the Grant Lake, the Gilbert (micrograined limestone and shale), the Stingy Creek (nodular-bedded mudstone and limestone), the Terrill (dolomitic and calcitic mudstone), the Sunset (micrograined limestone), and the Reba (nodular-bedded limestone and shale). The Bull Fork Formation, which overlies the Grant Lake Limestone, is made up of subequal amounts of thin-bedded highly fossiliferous limestone and shale; limestone makes up about 80 percent of the basal part of the formation and decreases in abundance irregularly upward to only 20 percent of the top part. On the east side of the Blue Grass region, the Bull Fork grades into the Reba Member of the Ashlock Formation; on the west side, it grades into the Grant Lake. The uppermost formation in the region is the Drakes Formation, which in east-central Kentucky consists of the Rowland Member (calcitic to dolomitic mudstone) overlain by the Preachersville Member (dolomitic to calcitic mudstone and dolomite and dolomitic siltstone). In northeast Kentucky, the Drakes is represented by only the Preachersville Member. In most of central and north-central Kentucky, the formation consists of three members: the Rowland at the base (dolomitic mudstone to muddy limestone), the Bardstown (fossiliferous limestone and shale), and the Saluda Dolomite (dolomite, in part calcitic and muddy). In northern north-central Kentucky, the Drakes is represented by only the Saluda Dolomite Member. The top of the Ordovician sequence in the Blue Grass region is generally formed by members of the Drakes Formation, which are overlain by str

Geology and ground-water resources of the Rawlins area, Carbon County, Wyoming

USGS Publications Warehouse

Berry, Delmar W.

1960-01-01

The Rawlins area in west-central Carbon County, south-central Wyoming includes approximately 634 square miles of plains and valleys grading into relatively rugged uplifts. The climate is characterized by low precipitation, rapid evaporation, and a wide range of temperature. Railroading and ranching are the principal occupations in the area. The exposed rocks in the area range in age from Precambrian through Recent. The older formations are exposed in the uplifted parts, the oldest being exposed along the apex of the Rawlins uplift. The formations dip sharply away from the anticlines and other uplifts and occur in the subsurface throughout the remainder of the area. The Cambrian rocks (undifferentiated), Madison limestone, Tensleep sandstone, Sun dance formation, Cloverly formation, Frontier formation, and Miocene and Pliocene rocks (undifferentiated) yield water to domestic and stock wells in the area. In the vicinity of the Rawlins uplift, the rocks of Cambrian age, Madison limestone, and Tensleep sandstone yield water to a few public-supply wells. The Cloverly formation yields water to public-supply wells in the Miller Hill and Sage Creek basin area. Wells that tap the Madison limestone, Tensleep sandstone, and Cloverly formation yield water under sufficient artesian pressure to flow at the land surface. The Browns Park formation yields water to springs that supply most of the Rawlins city water and supply water for domestic and stock use. Included on the geologic map are location of wells and test wells, depths to water below land surface, and location of springs. Depths to water range from zero in the unconsolidated deposits along the valley of Sugar Creek at the southern end of the Rawlins uplift to as much as 129 feet below the land surface in the Tertiary sedimentary rocks along the Continental Divide in the southern part of the area. The aquifers are recharged principally by precipitation that falls upon the area, by percolation from streams and ponds, and by movement of ground water from adjacent areas. Water is discharged from the ground-water reservoir by evaporation and transpiration, by seeps and springs, through wells, and by underflow out of the area. Although most water supplies in the area are obtained from springs, some domestic, stock, and public supplies are obtained from drilled wells, many yielding water under artesian pressure, and some flowing. Dissolved solids in the water from several geologic sources, ranging from 181 to 6,660 parts per million (ppm), indicate the varied chemical quality of ground water in the Rawlins area. Water from the Cambrian rocks, Tensleep sandstone, Cloverly formation, Frontier formation, Browns Park formation, and Miocene and Pliocene rocks is generally suitable for domestic and stock use. However, water yielded to the only well sampled in the lower part of the Frontier formation contained a high concentration of fluoride. Water from the rocks mentioned above contains less than 1,000 ppm of dissolved solids but in some places may contain iron in troublesome amounts. Water from the Madison limestone and Tensleep sandstone combined, Permian rocks, and Sundance formation contains more than 1,000 ppm of dissolved solids. Water in the Sundance, Cloverly, and Frontier :formations is very soft. More ground water can be obtained in the Rawlins area than is now being used. Many springs are undeveloped, and water can be obtained from additional wells without unduly lowering ground-water levels.

An Experimental Study on Normal Stress and Shear Rate Dependency of Basic Friction Coefficient in Dry and Wet Limestone Joints

NASA Astrophysics Data System (ADS)

Mehrishal, Seyedahmad; Sharifzadeh, Mostafa; Shahriar, Korosh; Song, Jae-Jon

2016-12-01

Among all parameters that affect the friction of rocks, variable normal stress and slip rate are the most important second-order parameters. The shear-rate- and normal-stress-dependent friction behavior of rock discontinuities may significantly influence the dynamic responses of rock mass. In this research, two limestone rock types, which were travertine and onyx marble with slickenside and grinded #80 surfaces, were prepared and CNL direct shear tests were performed on the joints under various shear conditions. The shearing rate varied from 0.1 to 50 mm/min under different normal stresses (from 2 to 30 % of UCS) in both dry and wet conditions. Experiments showed that the friction coefficient of slickensided and ground #80 surfaces of limestone increased with the increasing shear velocity and decreased with the increasing normal stress. Micro-asperity interlocking between ground #80 surfaces showed higher wear and an increase in friction coefficient ( µ) compared to slickensided surfaces. Slickensided samples with moist surfaces showed an increase in the coefficient of friction compared to dry surfaces; however, on ground #80 surfaces, the moisture decreased the coefficient of friction to a smaller value. Slickenside of limestone typically slides stably in a dry condition and by stick-slip on moist surfaces. The observed shear-rate- and normal-stress-dependent friction behavior can be explained by a similar framework to that of the adhesion theory of friction and a friction mechanism that involves the competition between microscopic dilatant slip and surface asperity deformation. The results have important implications for understanding the behavior of basic and residual friction coefficients of limestone rock surfaces.

Recovery technologies for building materials

NASA Astrophysics Data System (ADS)

Karu, Veiko; Nurme, Martin; Valgma, Ingo

2015-04-01

Mining industry provides building materials for construction. Civil engineers have settled the quality parameters for construction materials. When we produce high quality building materials from carbonate rock (limestone, dolostone), then the estimated waste share is 25% to 30%, depending on crushing principles and rock quality. The challenge is to find suitable technology for waste recovery. During international mining waste related cooperation project MIN-NOVATION (www.min-novation.eu), partners mapped possibilities for waste recovery in mining industry and pointed out good examples and case studies. One example from Estonia showed that when we produce limestone aggregate, then we produce up to 30% waste material (fines with size 0-4mm). This waste material we can see as secondary raw material for building materials. Recovery technology for this fine grained material has been achieved with CDE separation plant. During the process the plant washes out minus 63 micron material from the limestone fines. This technology allows us to use 92% of all limestone reserves. By-product from 63 microns to 4 mm we can use as filler in concrete or as fine limestone aggregate for building or building materials. MIN-NOVATION project partners also established four pilot stations to study other mineral waste recovery technologies and solutions. Main aims on this research are to find the technology for recovery of mineral wastes and usage for new by-products from mineral mining waste. Before industrial production, testing period or case studies are needed. This research is part of the study of Sustainable and environmentally acceptable Oil shale mining No. 3.2.0501.11-0025 http://mi.ttu.ee/etp and the project B36 Extraction and processing of rock with selective methods - http://mi.ttu.ee/separation; http://mi.ttu.ee/miningwaste/

The influence of petrography, mineralogy and chemistry on burnability and reactivity of quicklime produced in Twin Shaft Regenerative (TSR) kilns from Neoarchean limestone (Transvaal Supergroup, South Africa)

NASA Astrophysics Data System (ADS)

Vola, Gabriele; Sarandrea, Luca; Della Porta, Giovanna; Cavallo, Alessandro; Jadoul, Flavio; Cruciani, Giuseppe

2017-12-01

This study evaluates the influence of chemical, mineralogical and petrographic features of the Neoarchean limestone from the Ouplaas Mine (Griqualand West, South Africa) on its burnability and quicklime reactivity, considering the main use as raw material for high-grade lime production in twin shaft regenerative (TSR) kilns. This limestone consists of laminated clotted peloidal micrite and fenestrate microbial boundstone with herringbone calcite and organic carbon (kerogen) within stylolites. Diagenetic modifications include hypidiotopic dolomite, micrite to microsparite recrystallization, stylolites, poikilotopic calcite, chert and saddle dolomite replacements. Burning and technical tests widely attest that the Neoarchean limestone is sensitive to high temperature, showing an unusual and drastically pronounced sintering or overburning tendency. The slaking reactivity, according to EN 459-2 is high for lime burnt at 1050 °C, but rapidly decreases for lime burnt at 1150 °C. The predominant micritic microbial textures, coupled with the organic carbon, are key-factors influencing the low burnability and the high sintering tendency. The presence of burial cementation, especially poikilotopic calcite, seems to promote higher burnability, either in terms of starting calcination temperature, or in terms of higher carbonate dissociation rate. In fact, the highest calcination velocity determined by thermal analysis is consistent with the highest slaking reactivity of the lower stratum of the quarry, enriched in poikilotopic calcite. Secondly, locally concentered dolomitic marly limestones, and sporadic back shales negatively affects the quicklime reactivity, as well. This study confirms that a multidisciplinary analytical approach is essential for selecting the best raw mix for achieving the highest lime reactivity in TSR kilns.

Petrographic Evidence of Microbial Mats in the Upper Cretaceous Fish-Bearing, Organic-Rich Limestone, Agua Nueva Formation, Central Mexico

NASA Astrophysics Data System (ADS)

Blanco, A.; Maurrasse, F. J.; Hernández-Ávila, J.; Ángeles-Trigueros, S. A.; García-Cabrera, M. E.

2013-05-01

We document petrographic evidence of microbial mats in the Upper Cretaceous Agua Nueva Formation in the area of Xilitla (San Luis Potosí, Central Mexico), located in the southern part of the Tampico-Misantla basin. The sequence consists predominantly of alternating decimeter-thick beds of fossiliferous dark laminated limestone (C-org > 1.0wt%), and light gray, bioturbated limestone (C-org < 1.0wt%), with occasional brown shale and green bentonite layers. Well-preserved fossil-fish assemblages occur in the laminated dark limestone beds, which include shark teeth (cf. Ptychodus), scales of teleosteans (Ichthyodectiformes), as well as skeletal remains of holosteans (Nursallia. sp), and teleosteans (cf. Rhynchodercetis, Tselfatia, and unidentified Enchodontids). Thin section and SEM analyses of the laminated, dark limestones, reveal a micritic matrix consisting of dark and light sub-parallel wavy laminae, continuous and discontinuous folded laminae with shreds of organic matter, filaments, oncoids, and interlocking structures. The structures are identical to those previously described for the Cenomanian-Turonian Indidura Fm at Parras de la Fuente (Coahuila state) demonstrated to be of microbial origin (Duque-Botero and Maurrasse, 2005; 2008). These structures are also analogous to microbial mats in present environments, and Devonian deposits (Kremer, 2006). In addition, the laminae at Xilitla include filamentous bacterial structures, as thin and segmented red elements. In some thin sections, filaments appear to be embedded within the crinkly laminae and shreds showing the same pattern of folding, suggestive of biomorphic elements that represent the main producers of the organic matter associated with the laminae. Thus, exceptional bacterial activity characterizes sedimentation during the accumulation of the Agua Nueva Formation. Oxygen-deficient conditions related to the microbial mats were an important element in the mass mortality and preservation of the fish assemblages. Absence of bioturbation, pervasive framboidal pyrite, and the high concentration of organic matter (TOC ranges from 1.2% to 8wt%) in the dark limestones are consistent with persistent recurring dysoxic/anoxic conditions, and the light-gray bioturbated limestones represent relatively well-oxygenated episodes. Planktonic foraminifera (Rotalipora cushmani) and Inoceramu labiatus indicate a time interval from the latest Cenomanian through the earliest Turonian, thus this long interval of severe oxygen deficiency is coeval with Oceanic Anoxic Event 2 (OAE-2). [Duque-Botero and Maurrasse. 2005. Jour. Iberian Geology (31), 85-98; 2008. Cret. Res., 29, 957-964; Kremer. 2006. Acta Palaeontologica Polonica (51, 1), 143-154

The Biot coefficient for a low permeability heterogeneous limestone

NASA Astrophysics Data System (ADS)

Selvadurai, A. P. S.

2018-04-01

This paper presents the experimental and theoretical developments used to estimate the Biot coefficient for the heterogeneous Cobourg Limestone, which is characterized by its very low permeability. The coefficient forms an important component of the Biot poroelastic model that is used to examine coupled hydro-mechanical and thermo-hydro-mechanical processes in the fluid-saturated Cobourg Limestone. The constraints imposed by both the heterogeneous fabric and its extremely low intact permeability [K \\in (10^{-23},10^{-20}) m2 ] require the development of alternative approaches to estimate the Biot coefficient. Large specimen bench-scale triaxial tests (150 mm diameter and 300 mm long) that account for the scale of the heterogeneous fabric are complemented by results for the volume fraction-based mineralogical composition derived from XRD measurements. The compressibility of the solid phase is based on theoretical developments proposed in the mechanics of multi-phasic elastic materials. An appeal to the theory of multi-phasic elastic solids is the only feasible approach for examining the compressibility of the solid phase. The presence of a number of mineral species necessitates the use of the theories of Voigt, Reuss and Hill along with the theories proposed by Hashin and Shtrikman for developing bounds for the compressibility of the multi-phasic geologic material composing the skeletal fabric. The analytical estimates for the Biot coefficient for the Cobourg Limestone are compared with results for similar low permeability rocks reported in the literature.

Puerto Rican Karst-A Vital Resource

Treesearch

Ariel E. Lugo; Leopoldo Miranda Castro; Abel Vale; Tania del Mar López; Enrique Hernández Prieto; Andrés García Martinó; Alberto R. Puente Rolón; Adrianne G. Tossas; Donald A. McFarlane; Tom Miller; Armando Rodríguez; Joyce Lundberg; John Thomlinson; José Colón; Johannes H. Schellekens; Olga Ramos; Eileen Helmer

2001-01-01

The limestone region of Puerto Rico covers about 27.5 percent of the island’s surface and is subdivided into the northern, southern, and dispersed limestone areas. All limestone areas have karst features. The karst belt is that part of the northern limestone with the most spectacular surficial karst landforms. It covers 142,544 ha or 65 percent of the northern...

Alaska research natural areas: 2. Limestone jags.

Treesearch

G.P. Juday

1989-01-01

The 2083-hectare Limestone Jags Research Natural Area in the White Mountains National Recreation Area of central Alaska contains old limestone terrain features––caves, natural bridges, disappearing streams, and cold springs in a subarctic setting. A limestone dissolution joint-type cave in the area is one of the largest reported in high-latitude North America. A...

Undiscovered petroleum resources for the Woodford Shale and Thirteen Finger Limestone-Atoka Shale assessment units, Anadarko Basin

USGS Publications Warehouse

Higley, Debra K.

2011-01-01

In 2010 the U.S. Geological Survey assessed undiscovered oil and gas resources for the Anadarko Basin Province of Colorado, Kansas, Oklahoma, and Texas. The assessment included three continuous (unconventional) assessment units (AU). Mean undiscovered resources for the (1) Devonian Woodford Shale Gas AU are about 16 trillion cubic feet of gas (TCFG) and 192 million barrels of natural gas liquids (MMBNGL), (2) Woodford Shale Oil AU are 393 million barrels of oil (MMBO), 2 TCFG, and 59 MMBNGL, and (3) Pennsylvanian Thirteen Finger Limestone-Atoka Shale Gas AU are 6.8 TCFG and 82 MMBNGL. The continuous gas AUs are mature for gas generation within the deep basin of Oklahoma and Texas. Gas generation from the Woodford Shale source rock started about 335 Ma, and from the Thirteen Finger Limestone-Atoka Shale AU about 300 Ma. Maturation results are based on vitrinite reflectance data, and on 1D and 4D petroleum system models that calculated vitrinite reflectance (Ro), and Rock-Eval and hydrous pyrolysis transformation (HP) ratios through time for petroleum source rocks. The Woodford Shale Gas AU boundary and sweet spot were defined mainly on (1) isopach thickness from well-log analysis and published sources; (2) estimated ultimate recoverable production from existing, mainly horizontal, wells; and (3) levels of thermal maturation. Measured and modeled Ro ranges from about 1.2% to 5% in the AU, which represents marginally mature to overmature for gas generation. The sweet spot included most of the Woodford that was deposited within eroded channels in the unconformably underlying Hunton Group. The Thirteen Finger Limestone-Atoka Shale Gas AU has no known production in the deep basin. This AU boundary is based primarily on the gas generation window, and on thickness and distribution of organic-rich facies from these mainly thin shale and limestone beds. Estimates of organic richness were based on well-log signatures and published data.

Accelerated weathering of limestone for CO2 mitigation opportunities for the stone and cement industries

USGS Publications Warehouse

Langer, W.H.; Juan, C.A.S.; Rau, G.H.; Caldeira, K.

2009-01-01

Large amounts of limestone fines coproduced during the processing of crushed limestone may be useful in the sequestration of carbon dioxide (CO 2). Accelerated weathering of limestone (AWL) is proposed as a low-tech method to capture and sequester CO2 from fossil fuel-fired power plants and other point-sources such as cement manufacturing. AWL reactants are readily available, inexpensive, and environmentally benign. Waste CO 2 is hydrated with water to produce carbonic acid, which then reacts with and is neutralized by limestone fines, thus converting CO2 gas to dissolved calcium bicarbonate. AWL waste products can be disposed of in the ocean. Feasibility requires access to an inexpensive source of limestone and to seawater, thus limiting AWL facilities within about 10 km of the coastline. The majority of U.S. coastal power generating facilities are within economical transport distance of limestone resources. AWL presents opportunities for collaborative efforts among the crushed stone industry, electrical utilities, cement manufactures, and research scientists.

40 CFR 98.7 - What standardized methods are incorporated by reference into this part?

Code of Federal Regulations, 2012 CFR

2012-07-01

....astm.org. (1) ASTM C25-06 Standard Test Method for Chemical Analysis of Limestone, Quicklime, and....194(c), and § 98.334(b). (2) ASTM C114-09 Standard Test Methods for Chemical Analysis of Hydraulic... approved for § 98.6. (4) ASTM D240-02 (Reapproved 2007) Standard Test Method for Heat of Combustion of...

40 CFR 98.7 - What standardized methods are incorporated by reference into this part?

Code of Federal Regulations, 2013 CFR

2013-07-01

....astm.org. (1) ASTM C25-06 Standard Test Method for Chemical Analysis of Limestone, Quicklime, and....194(c), and § 98.334(b). (2) ASTM C114-09 Standard Test Methods for Chemical Analysis of Hydraulic... approved for § 98.6. (4) ASTM D240-02 (Reapproved 2007) Standard Test Method for Heat of Combustion of...

A brief geological history of Cockspur Island at Fort Pulaski National Monument, Chatham County, Georgia

USGS Publications Warehouse

Swezey, Christopher S.; Seefelt, Ellen L.; Parker, Mercer

2018-03-09

Fort Pulaski National Monument is located on Cockspur Island in Chatham County, Georgia, within the Atlantic Coastal Plain province. The island lies near the mouth of the Savannah River, and consists of small mounds (hummocks), salt marshes, and sediment dredged from the river. A 1,017-foot (ft) (310-meter [m])-deep core drilled at Cockspur Island in 2010 by the U.S. Geological Survey revealed several sedimentary units ranging in age from 43 million years old to present. Sand and mud are present at drilling depths from 0 to 182 ft (56 m), limestone is present at depths from 182 ft (56 m) to 965 ft (295 m), and glauconitic sand is present at depths from 965 ft (295 m) to 1,017 ft (310 m). The limestone and the water within the limestone are referred to collectively as the Floridan aquifer system, which is the primary source of drinking water for the City of Savannah and surrounding communities. In addition to details of the subsurface geology, this fact sheet identifies the following geologic materials used in the construction of Fort Pulaski: (1) granite, (2) bricks, (3) sandstone, and (4) lime mud with oyster shells.

Carbonaceous fuel combustion with improved desulfurization

DOEpatents

Yang, Ralph T.; Shen, Ming-shing

1980-01-01

Lime utilization for sulfurous oxides adsorption in fluidized combustion of carbonaceous fuels is improved by impregnation of porous lime particulates with iron oxide. The impregnation is achieved by spraying an aqueous solution of mixed iron sulfate and sulfite on the limestone before transfer to the fluidized bed combustor, whereby the iron compounds react with the limestone substrate to form iron oxide at the limestone surface. The iron oxide present in the spent limestone is found to catalyze the regeneration rate of the spent limestone in a reducing environment. Thus both the calcium and iron components may be recycled.

Saline-water intrusion related to well construction in Lee County, Florida

USGS Publications Warehouse

Boggess, Durward Hoye; Missimer, T.M.; O'Donnell, T. H.

1977-01-01

Ground water is the principle source of water supply in Lee County, Florida where an estimated 30,000 wells have been drilled since 1990. These wells ranges in depth from about 10 to 1,240 feet and tap the water table aquifer or one or more of the artesian water-bearing units or zones in the Tamiami Formation, the upper part of the Hawthorn Formation, the lower part of the Hawthorn Formation and the Tampa Limestone and the Suwannee Limestone. Before 1968, nearly all wells were constructed with galvanized or black iron pipe. Many of these wells are sources of saline-water intrusion into freshwater-bearing zones. The water-bearing zones in the lower part of the Hawthorn Formation, Tampa Limestone, and Suwannee Limestone are artesian-they have higher water levels and usually contain water with a higher concentration of dissolved solids than do the aquifers occurring at shallower depths. The water from these deeper aquifers generally range in dissolved solids concentration from about 1,500 to 2,400 mg/L, and in chloride from about 500 to 1,00 mg/L. A maximum chloride concentration of 15,200 mg/L has been determined. Few of the 3,00 wells estimated to have been drilled to these zones contain sufficient casing to prevent upward flow into overlaying water-bearing zones. Because of water-level differentials, upward movement and lateral intrusion of saline water occurs principally into the upper part of the Hawthorn Formation where the chloride concentrations in water unaffected by saline-water intrusion ranges from about 80 to 150 mg/L. Where intrusion from deep artesian zones has occurred, the chloride concentration in water from the upper part of the Hawthorn Formation ranges from about 300 to more than 2,100 mg/L Surface discharges of the saline water from wells tapping the lower part of the Hawthorn Formation and the Suwannee Limestone also had affected the water-table aquifer which normally contains water with 10 to 50 mg/L of chloride. In one area, the chloride concentration in water from the water table aquifer ranged from 200 to 590 mg/L as a result of intrusion. In areas adjacent to tidal-water bodies, the water table aquifer contains water that is very saline, Where the wells in such areas have been constructed with metal casings, the metal corrodes when exposed to the saline water, and many ultimately develop holes. This permits saline water to leak into the well where the water level in the well is lower than the water table. The intrusion of saline water from the water-table aquifer into the upper part of the Hawthorn Formation is a major problem in parts of Cape Coral. Withdrawal of water from the upper part of the Hawthorn Formation has caused water levels to decline below the lowest annual position of the water table, so that downward leakage is perennial. In some coastal areas, wells that tap the upper part of the Hawthorn Formation contain water whose chloride concentration is as much as 9,500 mg/L. Upward leakage of saline water from the deep artesian aquifers and downward leakage of saline water from the water-table aquifer can be prevented by proper well construction.

Hydrology and simulation of ground-water flow in the Aguadilla to Rio Camuy area, Puerto Rico

USGS Publications Warehouse

Tucci, Patrick; Martinez, M.I.

1995-01-01

The aquifers of the Aguadilla to Rio Camuy area, in the northwestern part of Puerto Rico, are the least developed of those on the north coast, and relatively little information is available concerning the ground-water system. The present study, which was part of a comprehensive appraisal of the ground-water resources of the North Coast Province, attempts to interpret the hydrology of the area within the constraints of available data. The study area consists of an uplifted rolling plain that is 200 to 400 feet above sea level and a heavily forested, karst upland. The only major streams in the area are the Rfo Camuy and the Rio Guajataca. Most water used in the area is obtained from Lago de Guajataca, just south of the study area, and ground-water use is minimal (less than 5 million gallons per day). Sedimentary rocks of Tertiary age, mainly limestone and calcareous clays, comprise the aquifers of the Aguadilla to Rio Camuy area. The rocks generally dip from 4 to 7 degrees to the north, and the total sedimentary rock sequence may be as much as 6,000 feet thick near the Atlantic coast. Baseflows for the Rio Camuy are 58 cubic feet per second near Bayaney and 72 cubic feet per second near Hatillo. The ground-water discharge to the Rio Camuy between these stations is estimated to be 15 cubic feet per second, or 2.6 cubic feet per second per linear mile. The flow of the Rio Guajataca is regulated by the Guajataca Dam at Lago de Guajataca. Ground-water discharge to the Rio Guajataca between the dam and the coast is estimated to be about 17 cubic feet per.second, based on the average ground-water discharge per linear mile estimated for the Rio Camuy. Both water-table and artesian aquifers are present in the Aguadilla to Rio Camuy area; how-ever, most ground water occurs within the watertable aquifer, which was the primary focus of this study. The top of the confining unit, below the water-table aquifer, generally is within the unnamed upper member of the Cibao Formation; however, it is within the Los Puertos Formation in the eastern part of the study area. The water-table aquifer primarily is composed of rocks of the Aymam6n Limestone and the Los Puertos Formation. The estimated saturated thickness of the water-table aquifer ranges from zero at the southern limit of the aquifer to more than 600 feet south of Isabela. Hydraulic conductivity of the Aymam6n Limestone, based on specific-capacity test data for seven wells, ranges from about 1 to about 25 feet per day and averages 7.5 feet per day. Hydraulic conductivity of the Los Puertos Formation, based on specific-capacity test data for four wells, generally was less than 7 feet. per day. The average hydraulic-conductivity value for both the Aymam6n Limestone and the Los Puertos Formation, based on specific-capacity test data, is estimated to be about 6.0 feet per day. These hydraulic-conductivity values are much less than average values for the water-table aquifer reported for other parts of the North Coast Province. Transmissivity values, based on the average hydraulic-conductivity value for the aquifer derived from specific-capacity tests, range from zero to about 4,000 feet squared per day; however, these values were adjusted upward during model calibration. Ground water generally moves from the highlands in the south toward the sea to the north and west, and locally, to streams. A major groundwater divide extends from the southeastern corner of the study area to the northwest, and separates flow north and east into the study area from flow to the southwest toward the Rio Culebrinas. Nearly all recharge to the aquifer is from infiltration of rainfall into the karst uplands. Discharge from the aquifer primarily occurs as leakage to streams and to the sea, and to a lesser degree as flow to wells. A two-layer, three-dimensional, steady-state, numerical model was constructed to simulateground-water flow in the water-table aquifer between Aguadilla and the R/o Camuy area. A basic a

Potential effects of deepening the St. Johns River navigation channel on saltwater intrusion in the surficial aquifer system, Jacksonville, Florida

USGS Publications Warehouse

Bellino, Jason C.; Spechler, Rick M.

2013-01-01

The U.S. Army Corps of Engineers (USACE) has proposed dredging a 13-mile reach of the St. Johns River navigation channel in Jacksonville, Florida, deepening it to depths between 50 and 54 feet below North American Vertical Datum of 1988. The dredging operation will remove about 10 feet of sediments from the surficial aquifer system, including limestone in some locations. The limestone unit, which is in the lowermost part of the surficial aquifer system, supplies water to domestic wells in the Jacksonville area. Because of density-driven hydrodynamics of the St. Johns River, saline water from the Atlantic Ocean travels upstream as a saltwater “wedge” along the bottom of the channel, where the limestone is most likely to be exposed by the proposed dredging. A study was conducted to determine the potential effects of navigation channel deepening in the St. Johns River on salinity in the adjacent surficial aquifer system. Simulations were performed with each of four cross-sectional, variable-density groundwater-flow models, developed using SEAWAT, to simulate hypothetical changes in salinity in the surficial aquifer system as a result of dredging. The cross-sectional models were designed to incorporate a range of hydrogeologic conceptualizations to estimate the effect of uncertainty in hydrogeologic properties. The cross-sectional models developed in this study do not necessarily simulate actual projected conditions; instead, the models were used to examine the potential effects of deepening the navigation channel on saltwater intrusion in the surficial aquifer system under a range of plausible hypothetical conditions. Simulated results for modeled conditions indicate that dredging will have little to no effect on salinity variations in areas upstream of currently proposed dredging activities. Results also indicate little to no effect in any part of the surficial aquifer system along the cross section near River Mile 11 or in the water-table unit along the cross section near River Mile 8. Salinity increases of up to 4.0 parts per thousand (ppt) were indicated by the model incorporating hydrogeologic conceptualizations with both a semiconfining bed over the limestone unit and a preferential flow layer within the limestone along the cross section near River Mile 8. Simulated increases in salinity greater than 0.2 ppt in this area were generally limited to portions of the limestone unit within about 75 feet of the channel on the north side of the river. The potential for saltwater to move from the river channel to the surficial aquifer system is limited, but may be present in areas where the head gradient from the aquifer to the river is small or negative and the salinity of the river is sufficient to induce density-driven advective flow into the aquifer. In some areas, simulated increases in salinity were exacerbated by the presence of laterally extensive semiconfining beds in combination with a high-conductivity preferential flow zone in the limestone unit of the surficial aquifer system and an upgradient source of saline water, such as beneath the salt marshes near Fanning Island. The volume of groundwater pumped in these areas is estimated to be low; therefore, saltwater intrusion will not substantially affect regional water supply, although users of the surficial aquifer system east of Dames Point along the northern shore of the river could be affected. Proposed dredging operations pose no risk to salinization of the Floridan aquifer system; in the study area, the intermediate confining unit ranges in thickness from more than 300 to about 500 feet and provides sufficient hydraulic separation between the surficial and Floridan aquifer systems.

Mineral resources of the southern half of Zone III Santander, Norte de Santander and Boyaca, Colombia

USGS Publications Warehouse

Ward, Dwight Edward; Goldsmith, Richard; Cruz, Bruna B.; Restrepo, Jaime; Hernan, A.

1970-01-01

The areas covered by this report lies in the eastern Cordillera of the Colombian Andes in the region around Bucaramanga. This part of the eastern Cordillera consists of a structurally complex core of metamorphic and igneous rocks of Precambrian to Mesozoic age, flanked to east and west by faulted and folded sedimentary strata of late Paleozoic to Tertiary age. Infaulted blocks of sedimentary rocks are locally present in the massif. Unconsolidated deposits of Quaternary age, primarily terraced alluvium, are 10cally extensive in valleys on the flanks of the range. The crystalline central core of the range is called the Santander massif. In it are located the principal sold deposits and scattered deposits of copper, lead, zinc, and fluorite. The sedimentary rocks flanking the massif contain significant deposits of phosphate rock and gypsum, as well as other nonmetallic industrial minerals such as limestone, barite, glass sand, and coal. A belt of lead-zinc prospects in carbonate and sandstone beds of Cretaceous age on the east side of the range warrants further investigation. Gold and silver are the only important metallic minerals that have been produced in the Santander massif. Mining dates back to colonial and possibly to pre-colonial times and continues on a small scale at present. The California and Vetas district was the main area of investigation of metallic minerals during the present project. Results of geochemical sampling of stream sediments and assays of vein material indicate that the main potential of the area is in gold with lesser potentials in copper, lead, zinc, and silver. Mineralization of the district is probably younger than Early Cretaceous. Although no copper minerals have been mined elsewhere in the massif, small amounts of copper minerals in various rocks in scattered areas is revealed by green and blue stains of copper carbonates and sulfates. Deposits of greatest areal extent are in arkosic conglomeratic beds of the Giron Formation. These are being explored and sampled at the present time (1969). A little lead has been mined and smelted in the past but operations were on a very small scale and of short duration. Small amounts of lead, zinc, and copper minerals accompany dolomite replacement of Cretaceous limestone in a few scattered places, and several promising prospects are being investigated by means of trenches and drilling. One magnetite and several hematite prospects were examined but none offers any potential for economic development. Thick beds of gypsum in Lower Cretaceous limestone on Mesa de Los Santos, south of Bucaramanga are being quarried from outcrops for use in cement manufacture. The deposit was discovered shortly before the present project began, and although its extent beneath overlying strata is not yet determined by drilling, it appears to be in a small evaporite basin of about three kilometers in radius. Reserves of gypsum are large, but future development will have to be by underground mining. Outcrops of Cretaceous limestone of high purity are widespread and are more than adequate to meet all demands, which at present are for cement and calcined lime, road construction material, and to a small extent for agricultural lime and polished decorative stone. Upper Paleozoic limestone of the Diamante Formation crops out in a few places; it has been used near Bucaramanga for cement manufacture. Marble is present in several localities of the Santander massif in Lower Paleozoic and Devonian rocks. Impurities, fractures, and solution cavities render most of it unsuitable for decorative purposes, but selected parts are used in floor tile and terrazo. Recrystallized limestone of the Diamante Formation in the same area, usually referred to as marble, is of uniform high purity throughout a thick and uninterrupted section, and offers a good source of limestone raw material. A little is now used for agricultural lime. The potential of this resource has not been fully evalua

51. CONTEXT VIEW LOOKING NORTHWEST OF BUILDING 365 (ARMAMENT TESTING ...

Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

51. CONTEXT VIEW LOOKING NORTHWEST OF BUILDING 365 (ARMAMENT TESTING BUILDING) IN BASE SPARES AREA WITH BUILDING 367 (ADMINISTRATIVE OFFICE BUILDING) IN MIDDLE GROUND AND BUILDING 368 (WAREHOUSE) IN BACKGROUND. - Loring Air Force Base, Weapons Storage Area, Northeastern corner of base at northern end of Maine Road, Limestone, Aroostook County, ME

Seawater pH at the advent of metazoan calcification

NASA Astrophysics Data System (ADS)

Ries, Justin; Gonzalez-Roubaud, Cécile; Douville, Eric; Montagna, Paolo

2016-04-01

The boron isotopic composition (δ11B) of bulk limestones provides a potentially powerful tool for reconstructing seawater pH deep into the geologic past (Kasemann et al., 2005; Paris et al., 2010; Ohnemueller et al., 2014). Here, we present δ11B of 35 calcitic limestones derived from a ca. 9 m.y. interval of the terminal Proterozoic Nama Group of southern Namibia. These units immediately precede the so-called Cambrian Radiation - the greatest diversification of metazoans in Earth history marked by the near-simultaneous advent of calcification across most animal phyla. The Nama Group represents one of the best preserved (average [Sr] = 1805 ppm; Mn/Sr < 2; δ18O > -10‰) and most continuous terminal Proterozoic limestone sequences known in the world. The carbonate units investigated here were deposited between ca. 552 and 543 Ma in a semi-divided foreland basin of the Kalahari Craton (Grotzinger and Miller, 2008). Depositional environments were shore-associated and ranged from upper shoreline/tidal flats to below-wave-base lower shoreface, and comprise calcisiltites, calcarenites, heterolithic interbeds, grainstones, and microbialites (Saylor et al., 1998; Grotzinger and Miller, 2008). The δ11B of the 35 sampled Nama Group carbonates were obtained via MC-ICP-MS. Samples were screened for contamination of the δ11B signal by clays (using [Al] as a proxy for clay content) (Paris et al., 2010) and by open-system meteoric diagenesis (δ11B-δ18O correlation). The δ11B values of the limestones ranged from 0.5 to 10.8‰ (avg. = 5.3‰), which is consistent with the previously observed increasing trend in carbonate δ11B (Paris et al., 2010) from the -6.2 to 2.7‰ values reported for Neoproterozoic cap carbonate dolostones (Kasemann et al., 2005) to the ca. 25‰ value reported for most modern marine carbonates. B/Ca ratios for the sampled limestones ranged from 3.4 to 24.0 ppm (avg. = 11.0). Assuming a seawater temperature of 25° C, a salinity of 35, a depth of 10 m, a seawater δ11B of 25‰ (based upon 380 Ma halites; Paris et al., 2010), and a boron isotope fractionation factor of 1.0272 (Klochko et al., 2006), the measured δ11B of the Nama Group carbonates suggests that seawater pH ranged from ca. 7.6 to 8.6 (avg. = 8.2) over the 9 My interval of Neoproterozoic time. Furthermore, seawater pH exhibited consistent oscillations of 0.6 to 1.0 units over relatively short timescales (200 ky to 1 my) between 552 to 545 Ma. Notably, seawater pH stabilized between 545 and 543 Ma - the 2 my interval immediately preceding the Cambrian Radiation of animal life. These results raise the possibility that it was the relative stabilization of seawater pH within carbonate shelf environments that fostered the polyphyletic advent of calcification within the animal kingdom during this remarkable period of Earth history.

Nitrogen utilization and digestibility of amino acids by lambs fed a high-concentrate diet with limestone or magnesium oxide.

PubMed

Christiansen, M L; Webb, K E

1990-07-01

Effects were evaluated of high dietary levels of magnesium oxide (MgO) or limestone on DM, OM and CP digestibility, N balance and intestinal absorption of amino acids by lambs fed a high concentrate diet. Twelve wether lambs equipped with abomasal and ileal cannulas were blocked by weight and breeding and allotted to treatments in a randomized block design in two consecutive trials. Diets were control (800 g), control plus 1.5% MgO (812 g), control plus 1.5% limestone (812 g) and control plus 3.0% limestone (824 g) fed in two equal portions at 12-h intervals. Ruminal fluid pH differences were small. The pH of ileal digesta was greater (P less than .05) with MgO than with limestone (8.23 vs 7.73). Fecal pH was higher (P less than .01) for lambs fed all mineral treatments (avg 8.75) than for lambs fed the control (7.61) and was higher (P less than .01) when MgO (9.53) rather than limestone (8.36) was fed. Ruminal NH3N was lower (P less than .01) when lambs were fed MgO (11.9 mg/dl) compared with limestone (avg 31.2 mg/dl). Preintestinal DM digestibility was greatest (P less than .10) with limestone (avg 49.5%) feeding compared with feeding MgO (31.2%) or the control (35.4%). About 41.5% more essential (P less than .05) and 48% more nonessential (P less than .03) amino acids reached the small intestine when MgO was fed than when limestone was fed. Partial digestibility of amino acids in the small intestine was reduced (P less than .03) an average of 5 percentage units when MgO or limestone was fed. Feeding high levels of MgO or limestone to lambs did not improve the overall digestibility of DM, OM or CP. In fact, feeding high levels of MgO or limestone appeared to be detrimental, reducing intestinal absorption of amino acids.

Stabilization of the As-contaminated soil from the metal mining areas in Korea.

PubMed

Ko, Myoung-Soo; Kim, Ju-Yong; Bang, Sunbeak; Lee, Jin-Soo; Ko, Ju-In; Kim, Kyoung-Woong

2012-01-01

The stabilization efficiencies of arsenic (As) in contaminated soil were evaluated using various additives such as limestone, steel mill slag, granular ferric hydroxide (GFH), and mine sludge collected from an acid mine drainage treatment system. The soil samples were collected from the Chungyang area, where abandoned Au-Ag mines are located. Toxicity characteristic leaching procedure, synthetic precipitation leaching procedure, sequential extraction analysis, aqua regia digestion, cation exchange capacity, loss on ignition, and particle size distribution were conducted to assess the physical and chemical characteristics of highly arsenic-contaminated soils. The total concentrations of arsenic in the Chungyang area soil ranged up to 145 mg/kg. After the stabilization tests, the removal percentages of dissolved As(III) and As(V) were found to differ from the additives employed. Approximately 80 and 40% of the As(V) and As(III), respectively, were removed with the use of steel mill slag. The addition of limestone had a lesser effect on the removal of arsenic from solution. However, more than 99% of arsenic was removed from solution within 24 h when using GFH and mine sludge, with similar results observed when the contaminated soils were stabilized using GFH and mine sludge. These results suggested that GFH and mine sludge may play a significant role on the arsenic stabilization. Moreover, this result showed that mine sludge can be used as a suitable additive for the stabilization of arsenic.

Major, trace element and stable isotope geochemistry of synorogenic breccia bodies, Ellsworth Mountains, Antarctica

USGS Publications Warehouse

Craddock, J.P.; McGillion, M.S.; Webers, G.F.

2007-01-01

Cambrian carbonates in the Heritage Range of the Ellsworth Mountains, West Antarctica host a series of carbonate-rich breccia bodies that formed contemporaneously with the Permian Gondwanide orogen. The breccia bodies had a three-stage genesis, with the older breccias containing Cambrian limestone (and marble) clasts supported by calcite, whereas the younger breccias are nearly clast-free and composed entirely of matrix calcite. Breccia clasts, calcite matrix and detrital matrix samples were analyzed using x-ray fluorescence (major and trace elements), x-ray diffraction, and stable isotopes (C, O) and suggest that the breccias formed as part of a closed geochemical system, at considerable depth, within the Cambrian limestone host as the Ellsworth Mountains deformed into a fold-and-thrust belt along the margin of Gondwana

Acid processing of pre-Tertiary radiolarian cherts and its impact on faunal content and biozonal correlation

USGS Publications Warehouse

Blome, C.D.; Reed, K.M.

1993-01-01

Destruction of radiolarians during both diagenesis and HF processing severely reduces faunal abundance and diversity and affects the taxonomic and biostratigraphic utility of chert residues. The robust forms that survive the processing represent only a small fraction of the death assemblage, and delicate skeletal structures used for species differentiation, are either poorly preserved or dissolved in many coeval chert residues. First and last occurrences of taxa in chert sequences are likely to be coarse approximations of their true stratigraphic ranges. Precise correlation is difficult between biozonations based solely on index species from cherts and those constructed from limestone faunas. Careful selection of samples in sequence, use of weaker HF solutions, and study of both chert and limestone faunas should yield better biostratigraphic information. -from Authors

Stream ecosystem response to limestone treatment in acid impacted watersheds of the allegheny plateau

USGS Publications Warehouse

McClurg, S.E.; Petty, J.T.; Mazik, P.M.; Clayton, J.L.

2007-01-01

Restoration programs are expanding worldwide, but assessments of restoration effectiveness are rare. The objectives of our study were to assess current acid-precipitation remediation programs in streams of the Allegheny Plateau ecoregion of West Virginia (USA), identify specific attributes that could and could not be fully restored, and quantify temporal trends in ecosystem recovery. We sampled water chemistry, physical habitat, periphyton biomass, and benthic macroinvertebrate and fish community structure in three stream types: acidic (four streams), naturally circumneutral (eight streams), and acidic streams treated with limestone sand (eight streams). We observed no temporal trends in ecosystem recovery in treated streams despite sampling streams that ranged from 2 to 20 years since initial treatment. Our results indicated that the application of limestone sand to acidic streams was effective in fully recovering some characteristics, such as pH, alkalinity, Ca2+, Ca:H ratios, trout biomass and density, and trout reproductive success. However, recovery of many other characteristics was strongly dependent upon spatial proximity to treatment, and still others were never fully recovered. For example, limestone treatment did not restore dissolved aluminum concentrations, macroinvertebrate taxon richness, and total fish biomass to circumneutral reference conditions. Full recovery may not be occurring because treated streams continue to drain acidic watersheds and remain isolated in a network of acidic streams. We propose a revised stream restoration plan for the Allegheny Plateau that includes restoring stream ecosystems as connected networks rather than isolated reaches and recognizes that full recovery of acidified watersheds may not be possible. ?? 2007 by the Ecological Society of America.

Statistical and simulation analysis of hydraulic-conductivity data for Bear Creek and Melton Valleys, Oak Ridge Reservation, Tennessee

USGS Publications Warehouse

Connell, J.F.; Bailey, Z.C.

1989-01-01

A total of 338 single-well aquifer tests from Bear Creek and Melton Valley, Tennessee were statistically grouped to estimate hydraulic conductivities for the geologic formations in the valleys. A cross-sectional simulation model linked to a regression model was used to further refine the statistical estimates for each of the formations and to improve understanding of ground-water flow in Bear Creek Valley. Median hydraulic-conductivity values were used as initial values in the model. Model-calculated estimates of hydraulic conductivity were generally lower than the statistical estimates. Simulations indicate that (1) the Pumpkin Valley Shale controls groundwater flow between Pine Ridge and Bear Creek; (2) all the recharge on Chestnut Ridge discharges to the Maynardville Limestone; (3) the formations having smaller hydraulic gradients may have a greater tendency for flow along strike; (4) local hydraulic conditions in the Maynardville Limestone cause inaccurate model-calculated estimates of hydraulic conductivity; and (5) the conductivity of deep bedrock neither affects the results of the model nor does it add information on the flow system. Improved model performance would require: (1) more water level data for the Copper Ridge Dolomite; (2) improved estimates of hydraulic conductivity in the Copper Ridge Dolomite and Maynardville Limestone; and (3) more water level data and aquifer tests in deep bedrock. (USGS)

Geochemistry and origin of regional dolomites

NASA Astrophysics Data System (ADS)

Hanson, G. N.; Meyers, W. J.

1989-12-01

The major goal of the carbonate research program at Stony Brook is to better understand the conditions and processes leading to regional diagenesis of carbonate rocks. Our research focuses on studies of ancient, massive dolostones, but we are also studying limestone diagenesis for its own importance, and as it relates to dolomitization. Our approach has been to carry out a very detailed petrographic and geochemical case study to the Mississippian Burlington-Keokuk Fms. of Iowa, Illinois and Missouri, and to develop this as a testing ground for new geochemical and modelling techniques, and for testing various models for regional dolomitization in epicontinental carbonates. The ideas and techniques developed in our Burlington-Keokuk studies are being expanded and applied to carbonate sequences of other ages (Devonian to Neogene), and other tectono-sedimentary settings. The emphasis of this report will be on new developments and results on the Burlington-Keokuk studies and on our diagenetic studies of other strata. Recent research on Burlington-Keokuk rocks include development and application of boron isotopes and the U--Th--Pb system to dolomite studies, investigations of porosity and permeability in the dolostones. Projects on other strata include dolomitization and limestones diagenesis of Devonian carbonates of Alberta and Western Australia, Miocene reefal carbonates of Spain, Neogene carbonates of Curacao and Bonaire, Waulsortian limestones of Ireland, modelling of trace elements and stable isotopes, and experimental growth of calcites to investigate crystallographic controls of trace element incorporation.

Manufacturing of novel low-cost adsorbent: Co-granulation of limestone and coffee waste.

PubMed

Iakovleva, Evgenia; Sillanpää, Mika; Maydannik, Philipp; Liu, Jiang Tao; Allen, Stephen; Albadarin, Ahmad B; Mangwandi, Chirangano

2017-12-01

Limestone and coffee waste were used during the wet co-granulation process for the production of efficient adsorbents to be used in the removal of anionic and cationic dyes. The adsorbents were characterized using different analytical techniques such as XRD, SEM, FTIR, organic elemental analysis, the nitrogen adsorption method, with wettability, strength and adsorption tests. The adsorption capacity of granules was determined by removal of methylene blue (MB) and orange II (OR) from single and mixed solutions. In the mixed solution, co-granules removed 100% of MB and 85% of OR. The equilibria were established after 6 and 480 h for MB and OR, respectively. Copyright © 2017 Elsevier Ltd. All rights reserved.

Catalytic iron oxide for lime regeneration in carbonaceous fuel combustion

DOEpatents

Shen, Ming-Shing; Yang, Ralph T.

1980-01-01

Lime utilization for sulfurous oxides absorption in fluidized combustion of carbonaceous fuels is improved by impregnation of porous lime particulates with iron oxide. The impregnation is achieved by spraying an aqueous solution of mixed iron sulfate and sulfite on the limestone before transfer to the fluidized bed combustor, whereby the iron compounds react with the limestone substrate to form iron oxide at the limestone surface. It is found that iron oxide present in the spent limestone acts as a catalyst to regenerate the spent limestone in a reducing environment. With only small quantities of iron oxide the calcium can be recycled at a significantly increased rate.

Accelerated weathering of limestone for CO2 mitigation: Opportunities for the stone and cement industries

USGS Publications Warehouse

Langer, William H.; San, Juan A.; Rau, Greg H.; Caldeira, Ken

2009-01-01

Large amounts of limestone fines co-produced during the processing of crushed limestone may be useful in the sequestration of carbon dioxide (CO2). Accelerated weathering of limestone (AWL) is proposed as a low-tech method to capture and sequester CO2 from fossil fuel-fired power plants and other point sources such as cement manufacturing. AWL reactants are readily available, inexpensive and environmentally benign. Waste CO2 is hydrated with water to produce carbonic acid. This reacts with and is neutralized by limestone fines, thus converting CO2 gas to dissolved calcium bicarbonate.

Cyrtocrinids from the Štramberk-type limestones of southern Poland

NASA Astrophysics Data System (ADS)

Trzęsiok, Dawid

2017-04-01

In the Upper Jurassic Štramberk-type limestones of southern Poland are reported 11 cyrtocrinid taxa (Eugeniacrinites zitelli, E. alexandrowiczi, Phyllocrinus malbosianus, P. stellaris, P. sinuatus, Sclerocrinus polonicus, Strambergocrinus cf. jurassicus, Ascidicrinus pentagonus, Tetracrinus baumilleri, Salamonicrinus prodigiosum and Cotylederma sp.), along with isocrinids (Isocrinus sp.) and comatulids (Notocrinidae indet.). It is worth mentioning that Salamonicrinus is a transitional link between Hemicrinus and Ancepsicrinus, and that all these taxa should be included into the family Sclerocrinidae. Conducted biometric analysis evidenced that the most frequent phyllocrinids within our test material belong to rather four, instead of the usual three, morphotypes. Consequently they may belong to four different species. Additionally Early Jurassic genus Eudesicrinus appears as the oldest cyrtocrinid representative, thus providing an ancestor-rooting baseline to stemless hemibrachiocrinids and brachiomonocrinids (Hemibrachiocrinidae; Brachiomonocrinidae), and as having reduced stem and/or reduced number of arms (e.g., Ancepsicrinus, Cyrtocrinus, Hemicrinus, Salamonicrinus and Strambergocrinus). References: Salamon Mariusz A. and Gorzelak Przemysław, 2010: Cyrtocrinids (Echinodermata, Crinoidea) from Upper Jurassic Štramberk-type limestones in southern Poland. Palaeontology, 53(4): 869-885.

Foaming of E-Glass II (Report for G Plus Project for PPG)

DOE Office of Scientific and Technical Information (OSTI.GOV)

Kim, Dong-Sang; Portch, Matthew P.; Matyas, Josef

2005-09-23

In a previous study, the effect of the furnace atmosphere on E glass foaming was investigated with the specific goal to understand the impact of increased water content on foaming in oxy-fired furnaces. The present study extended the previous study and focused on the effect of glass batch chemical composition on E-glass foaming. The present study also included reruns of foam tests performed in a previous study, which resulted in the same trend: the foaming extent increased nearly linearly with the heating rate and no foam was produced when CO2 + 55% H2O atmosphere was introduced at 300°C. It wasmore » shown that the lack of foaming in the test with CO2 + 55% H2O atmosphere introduced at 300°C was caused by a loss of sulfate at T <1250°C because of higher water content at the early stages of melting. The tests with new batches in the present study showed that replacing quicklime with limestone tend to decrease foaming, possibly caused by increased sulfate loss during early stages of melting in the batch with limestone. The batches where Na2SO4 was replaced with NaNO3, NaNO3 + CeO2, or CeO2, produced only very limited foaming regardless of the replacing components. As expected, the foaming extent increased as the sulfate content in the batch increased. The results of the present study suggest that foaming can be reduced by using limestone over quicklime and by decreasing the sulfate addition to a minimum required for refining.« less

Development of design parameters for virtual cement and concrete testing : [summary].

DOT National Transportation Integrated Search

2013-12-01

At its most basic, concrete is made from cement : and aggregate, often Portland cement and gravel : (or in Florida, limestone). Varying ingredients and : their proportions directly influences the behavior : of the final cement and concrete products. ...

0-6686 : improving DMS 9210 requirements for limestone rock asphalt : [project summary].

DOT National Transportation Integrated Search

2013-08-01

Limestone rock asphalt (LRA) mixtures have : been produced and placed for several decades : using specification requirements currently listed : under DMS 9210, Limestone Rock Asphalt (LRA). : Several Texas Department of Transportation : (TxDOT) distr...

Porosity change after gypsum crust formation on macro-porous limestones

NASA Astrophysics Data System (ADS)

Dewanckele, Jan; Cnudde, Veerle; de Kock, Tim; Boone, Marijn; Boone, Matthieu; van Hoorebeke, Luc; Jacobs, Patric

2010-05-01

The deterioration of stone is a complex process in which physical, biological and chemical mechanisms are involved. In this research, pore structure changes inside two types of porous limestone were analyzed before, during and after strong acid tests with SO2. Sulphatation and crust formation phenomena on natural building stones exposed to a polluted environment, are largely described in literature. As far as rocks rich in calcium carbonate are concerned, the main processes involved are the dissolution of the calcium carbonate and the formation of gypsum (CaSO4.2H2O) in presence of an acid atmosphere. The low mobility of this newly formed salt favours its accumulation in porous materials and at the surface of less porous media. The main actor in the process of gypsum crystallization on limestone is the aggressive sulphur dioxide gas (SO2). In this study, the Savonnières and Euville limestone were subjected to tests with a strong acid. According to the standard EN 13919:2002E, samples were put in acid environment for 21 days. At the bottom of the container a mixture of 500 ± 10 ml H2SO3 and 150 ± 10 ml de-mineralized H2O was added. No airborne particles or oxides of nitrogen (NOx) were added. Before exposure, after 6 days in the polluted environment and at the end of the test, the two samples were scanned with X-ray computed tomography (X-ray CT) at the Centre for X-ray Tomography at Ghent University, Belgium (UGCT; www.ugct.ugent.be). This visualization technique allows 2D and 3D reconstructions on a micrometer scale of the internal structure of an object without damaging the material. It thus enables to scan the same sample in a sequential way. In order to obtain information about the sample's interior of which the characteristics can be compared before, during and after the test, the same scanning parameters (exposure time, amount of frames, energy, etc.) were used. In addition, the same adjustments like beam hardening correction, normalizing, ring and spot filter, etc. were applied for the reconstruction. Total porosity, open and closed porosity and radial porosity were calculated for each sample by using the in-house developed software program Morpho+. The analysis of the various scans revealed that the Euville limestone developed a distinct gypsum crust, behind which a secondary porous layer of 100 μm thickness had developed. Inside the sample the porosity decreased by infilling of the large pore spaces with gypsum. However, after 6 days exposure the total porosity of the sample increased from 5.70% to 8.45%. In this case, the formation of secondary porosity behind the newly formed exterior gypsum layer prevailed upon the crystallizing of gypsum inside the pores located in the sample's interior. Also, the firstly formed gypsum crystals prevented the further interaction of the sulphuric acid with the stone material. After 21 days, the total porosity of the sample still reached 8.45%. The results of the radial porosity measurements were also the same after 6 and 21 days, indicating that the secondary porosity and the filling of pores inside the samples were stabilized. On the other hand, the gypsum crust on the Savonnières limestone was less visible. No secondary formed porous layer was measured and the total porosity decreased from 12.10% to 10.94% after 6 days and further to 10.31% at the end of the test. The decrease of porosity was still measurable at a depth of 500 μm inside the sample. The combination of micro-CT, image analysis and induced weathering tests are a promising combination of tools and techniques that allow for a better understanding of gypsum crust formation and pore structure change just behind the crust and deeper inside the rock sample.

The Chachil Limestone (Pliensbachian-earliest Toarcian) Neuquén Basin, Argentina: U-Pb age calibration and its significance on the Early Jurassic evolution of southwestern Gondwana

NASA Astrophysics Data System (ADS)

Leanza, H. A.; Mazzini, A.; Corfu, F.; Llambías, E. J.; Svensen, H.; Planke, S.; Galland, O.

2013-03-01

New radiometric U-Pb ages obtained on zircon crystals from Early Jurassic ash layers found within beds of the Chachil Limestone at its type locality in the Chachil depocentre (southern Neuquén Basin) confirm a Pliensbachian age (186.0 ± 0.4 Ma). Additionally, two ash layers found in limestone beds in Chacay Melehue at the Cordillera del Viento depocentre (central Neuquén Basin) gave Early Pliensbachian (185.7 ± 0.4 Ma) and earliest Toarcian (182.3 ± 0.4 Ma) U-Pb zircon ages. Based on these new datings and regional geological observations, we propose that the limestones cropping out at Chacay Melehue are correlatable with the Chachil Limestone. Recent data by other authors from limestones at Serrucho creek in the upper Puesto Araya Formation (Valenciana depocentre, southern Mendoza) reveal ages of 182.16 ± 0.6 Ma. Based on these new evidences, we consider the Chachil Limestone an important Early Jurassic stratigraphic marker, representing an almost instantaneous widespread flooding episode in western Gondwana. The unit marks the initiation in the Neuquén Basin of the Cuyo Group, followed by widespread black shale deposition. Accordingly, these limestones can be regarded as the natural seal of the Late Triassic -earliest Jurassic Precuyano Cycle, which represents the infill of halfgrabens and/or grabens related to a strong extensional regime. Paleontological evidence supports that during Pliensbachian-earliest Toarcian times these limestones were deposited in western Gondwana in marine warm water environments.

Inelastic Compaction in High-Porosity Limestone Monitored Using Acoustic Emissions

NASA Astrophysics Data System (ADS)

Baud, Patrick; Schubnel, Alexandre; Heap, Michael; Rolland, Alexandra

2017-12-01

We performed a systematic investigation of mechanical compaction and strain localization in Saint-Maximin limestone, a quartz-rich, high-porosity (37%) limestone from France. Our new data show that the presence of a significant proportion of secondary mineral (i.e., quartz) did not impact the mechanical strength of the limestone in both the brittle faulting and cataclastic flow regimes, but that the presence of water exerted a significant weakening effect. In contrast to previously published studies on deformation in limestones, inelastic compaction in Saint-Maximin limestone was accompanied by abundant acoustic emission (AE) activity. The location of AE hypocenters during triaxial experiments revealed the presence of compaction localization. Two failure modes were identified in agreement with microstructural analysis and X-ray computed tomography imaging: compactive shear bands developed at low confinement and complex diffuse compaction bands formed at higher confinement. Microstructural observations on deformed samples suggest that the recorded AE activity associated with inelastic compaction, unusual for a porous limestone, could have been due to microcracking at the quartz grain interfaces. Similar to published data on high-porosity macroporous limestones, the crushing of calcite grains was the dominant micromechanism of inelastic compaction in Saint-Maximin limestone. New P wave velocity data show that the effect of microcracking was dominant near the yield point and resulted in a decrease in P wave velocity, while porosity reduction resulted in a significant increase in P wave velocity beyond a few percent of plastic volumetric strain. These new data highlight the complex interplay between mineralogy, rock microstructure, and strain localization in porous rocks.

40 CFR 81.301 - Alabama.

Code of Federal Regulations, 2010 CFR

2010-07-01

... County Lawrence County Lee County Limestone County Lowndes County Macon County Madison County Marengo... Lauderdale County Lawrence County Lee County Limestone County Lowndes County Macon County Madison County... Lamar County Lauderdale County Lawrence County Lee County Limestone County Lowndes County Macon County...

40 CFR 81.301 - Alabama.

Code of Federal Regulations, 2011 CFR

2011-07-01

... County Lawrence County Lee County Limestone County Lowndes County Macon County Madison County Marengo... County Houston County Jackson County Lamar County Lauderdale County Lawrence County Lee County Limestone... County Houston County Jackson County Lamar County Lauderdale County Lawrence County Lee County Limestone...

New paleomagnetic results from Cretaceous rocks of the Gyaring Co fault region, central Tibet

NASA Astrophysics Data System (ADS)

Finn, D.; Zhao, X.; Lippert, P. C.; Yin, A.; Li, Y.; Wang, C.; Meng, J.; Zhang, S.; Li, H.

2010-12-01

Conjugate strike-slip faults are widespread features throughout the Alpine-Himalayan collision zone. They often exhibit V-shapes in map view and trend 60-75° from the maximum compressive-stress (σ1). Andersonian fault mechanics, however, predict faults to form X-shaped at ~30° from σ1. Consequently, V-shaped conjugate faults have been thought to initiate at ~30° to σ1, and subsequently rotate into their current orientation through continued shortening. Alternatively, the Paired General Shear Zone (PGSZ) model may explain development of conjugate strike-slip faults in their modern orientations, predicting no rotation. Strike-slip faulting produces rigid-body motion and internal deformation quantifiable by paleomagnetism when integrated with structural information. We wonder if paleomagnetic studies of the fault-bounded blocks in central Tibet would allow us to differentiate the two competing models for the formation of V-shaped conjugate faults. We collected over 300 paleomagnetic samples (40 sites) from stratigraphic sections in Shengza and Nima areas of central Tibet. The rocks we collected range from Jurassic to Oligocene, and are mainly grey limestones and red sediments including siltstone, mudstone, sandstone, and conglomerate, offering opportunity of applying paleomagnetic fold and conglomerate tests to check the stability of the remanent magnetization. Up to present, useful results were obtained for 150 of the early Cretaceous limestone and sandstone samples (Langshan and Duoni formations, respectively). We have characterized the stable components of natural remanent magnetization (NRM) of these samples through detailed thermal (mainly) and alternating field (AF) demagnetization. We have also conducted rock magnetic investigation to identify the magnetic carriers in these rocks. Most limestone and red sandstones exhibit two distinctive components of magnetization. The lower unblocking-temperature component is an overprint. The higher unblocking-temperature component is the characteristic component (ChRM), is well defined in vector demagnetization plots with both normal and reversed polarities and carried by magnetite and hematite. The site-mean directions pass the local fold test at more than 95% confidence level. Our new results indicate that there has been no rotation of this region relative to Eurasia, Mongolia, and the North and South China blocks since the lower Cretaceous. Thus paleomagnetic evidence appears to favor the PGSZ model and supports geological estimates for the shortening north of the Bangong suture zone, leading to an improved tectonic interpretation of the region.

A cost-effective system for in-situ geological arsenic adsorption from groundwater.

PubMed

Shan, Huimei; Ma, Teng; Wang, Yanxin; Zhao, Jie; Han, Hongyin; Deng, Yamin; He, Xin; Dong, Yihui

2013-11-01

An effective and low-cost in-situ geological filtration system was developed to treat arsenic-contaminated groundwater in remote rural areas. Hangjinhouqi in western Hetao Plain of Inner Mongolia, China, where groundwater contains a high arsenic concentration, was selected as the study area. Fe-mineral and limestone widely distributed in the study area were used as filter materials. Batch and column experiments as well as field tests were performed to determine optimal filtration parameters and to evaluate the effectiveness of the technology for arsenic removal under different hydrogeochemical conditions. A mixture containing natural Fe-mineral (hematite and goethite) and limestone at a mass ratio of 2:1 was found to be the most effective for arsenic removal. The results indicated that Fe-mineral in the mixture played a major role for arsenic removal. Meanwhile, limestone buffered groundwater pH to be conducive for the optimal arsenic removal. As(III) adsorption and oxidation by iron mineral, and the formation of Ca-As(V) precipitation with Ca contributed from limestone dissolution were likely mechanisms leading to the As removal. Field demonstrations revealed that a geological filter bed filled with the proposed mineral mixture reduced groundwater arsenic concentration from 400 μg/L to below 10 μg/L. The filtration system was continuously operated for a total volume of 365,000L, which is sufficient for drinking water supplying a rural household of 5 persons for 5 years at a rate of 40 L per person per day. © 2013.

Substratum type affects recruitment and development of marine assemblages over artificial substrata: A case study in the Alboran Sea

NASA Astrophysics Data System (ADS)

Sempere-Valverde, Juan; Ostalé-Valriberas, Enrique; Farfán, Gonzalo M.; Espinosa, Free

2018-05-01

There are more than 27,000 harbours along coasts worldwide and construction is expected to increase. The development and application of new ecological engineering ideas, for both old and new structures, is now imperative in order to reduce perturbation on marine coastal biota and to avoid the spread of non-native species. In this study, the early benthic assessment of subtidal and intertidal communities is tracked on five artificial substrata differing in origin, roughness, and chemical composition: Oyster Sandstone, Limestone, Gabbro, Slate and Concrete. Within substrata, Sandstone was the roughest on a 1-2 mm scale. Also, Sandstone and Limestone had predominantly calcareous composition while silicon was abundant in Concrete, Gabbro and Slate. In the intertidal zone, results showed that primary productivity and diatom abundance markedly increased with substratum roughness. In the subtidal zone, species richness and diversity over experimental substrata were lower than in adjacent rocky reefs. Nonetheless, during the first year of colonization communities varied within the experimental substrata. Coverage was higher on Sandstone than Concrete and Gabbro, and species richness was higher on Sandstone than Limestone. The differences are related to intrinsic substratum-type characteristics and showed Limestone, Gabbro and Concrete hold relatively poor ecological benefits in the first phases of ecological succession. The results may help to promote future research in this field and to test different substrata combinations and heterogeneities, for more environmentally sustainable surfaces in design of coastal structures.

Analysis of medieval limestone sculpture from southwestern France and the Paris Basin by NAA

DOE Office of Scientific and Technical Information (OSTI.GOV)

Holmes, L.; Harbottle, G.

1994-12-31

Compositional characterization of limestone from sources known to medieval craftsmen and from the monuments they built can be used in conjunction with stylistic and iconographic criteria to infer geographic origin of sculptures that have lost their histories. Limestone from 47 quarrying locations in France and from numerous medieval monuments have been subjected to neutron activation analysis (NAA) to form the nucleus of the Brookhaven Limestone Database. Even though the method and techniques of NAA are well established, this paper briefly summarizes the parameters and experimental conditions useful for determining those concentration variables for which limestone from different sources exhibits significantmore » and reproducible differences.« less

Portable audio magnetotellurics - experimental measurements and joint inversion with radiomagnetotelluric data from Gotland, Sweden

NASA Astrophysics Data System (ADS)

Shan, Chunling; Kalscheuer, Thomas; Pedersen, Laust B.; Erlström, Mikael; Persson, Lena

2017-08-01

Field setup of an audio magnetotelluric (AMT) station is a very time consuming and heavy work load. In contrast, radio magnetotelluric (RMT) equipment is more portable and faster to deploy but has shallower investigation depth owing to its higher signal frequencies. To increase the efficiency in the acquisition of AMT data from 10 to 300 Hz, we introduce a modification of the AMT method, called portable audio magnetotellurics (PAMT), that uses a lighter AMT field system and (owing to the disregard of signals at frequencies of less than 10 Hz) shortened data acquisition time. PAMT uses three magnetometers pre-mounted on a rigid frame to measure magnetic fields and steel electrodes to measure electric fields. Field tests proved that the system is stable enough to measure AMT fields in the given frequency range. A PAMT test measurement was carried out on Gotland, Sweden along a 3.5 km profile to study the ground conductivity and to map shallow Silurian marlstone and limestone formations, deeper Silurian, Ordovician and Cambrian sedimentary structures and crystalline basement. RMT data collected along a coincident profile and regional airborne very low frequency (VLF) data support the interpretation of our PAMT data. While only the RMT and VLF data constrain a shallow ( 20-50 m deep) transition between Silurian conductive (< 30 Ωm resistivity) marlstone and resistive (> 1000 Ωm resistivity) limestone, the single-method inversion models of both the PAMT and the RMT data show a transition into a conductive layer of 3 to 30 Ωm resistivity at 80 m depth suggesting the compatibility of the two data sets. This conductive layer is interpreted as saltwater saturated succession of Silurian, Ordovician and Cambrian sedimentary units. Towards the lower boundary of this succession (at 600 m depth according to boreholes), only the PAMT data constrain the structure. As supported by modelling tests and sensitivity analysis, the PAMT data only contain a vague indication of the underlying crystalline basement. A PAMT and RMT joint inversion model reveals all the aforementioned units including the less than 80 m deep limestone and marlstone formations and the conductive sedimentary succession of Silurian, Ordovician and Cambrian units. Our test measurements have proven the PAMT modification to be time saving and easy to set up. However, PAMT data suffer from the same noise disturbances as regular AMT data. Since man-made EM noise can propagate over great distances through resistive underground, PAMT measurements are recommended to be carried out in areas with low resistivity. The PAMT method is proven to be applicable in shallow depth studies, especially in areas where normal AMT measurements are inconvenient and/or too expensive to carry out.

Stratigraphy and Mesozoic–Cenozoic tectonic history of northern Sierra Los Ajos and adjacent areas, Sonora, Mexico

USGS Publications Warehouse

Page, William R.; Gray, Floyd; Iriondo, Alexander; Miggins, Daniel P.; Blodgett, Robert B.; Maldonado, Florian; Miller, Robert J.

2010-01-01

Geologic mapping in the northern Sierra Los Ajos reveals new stratigraphic and structural data relevant to deciphering the Mesozoic–Cenozoic tectonic evolution of the range. The northern Sierra Los Ajos is cored by Proterozoic, Cambrian, Devonian, Mississippian, and Pennsylvanian strata, equivalent respectively to the Pinal Schist, Bolsa Quartzite and Abrigo Limestone, Martin Formation, Escabrosa Limestone, and Horquilla Limestone. The Proterozoic–Paleozoic sequence is mantled by Upper Cretaceous rocks partly equivalent to the Fort Crittenden and Salero Formations in Arizona, and the Cabullona Group in Sonora, Mexico.Absence of the Upper Jurassic–Lower Cretaceous Bisbee Group below the Upper Cretaceous rocks and above the Proterozoic–Paleozoic rocks indicates that the Sierra Los Ajos was part of the Cananea high, a topographic highland during the Late Jurassic and Early Cretaceous. Deposition of Upper Cretaceous rocks directly on Paleozoic and Proterozoic rocks indicates that the Sierra Los Ajos area had subsided as part of the Laramide Cabullona basin during Late Cretaceous time. Basal beds of the Upper Cretaceous sequence are clast-supported conglomerate composed locally of basement (Paleozoic) clasts. The conglomerate represents erosion of Paleozoic basement in the Sierra Los Ajos area coincident with development of the Cabullona basin.The present-day Sierra Los Ajos reaches elevations of greater than 2600 m, and was uplifted during Tertiary basin-and-range extension. Upper Cretaceous rocks are exposed at higher elevations in the northern Sierra Los Ajos and represent an uplifted part of the inverted Cabullona basin. Tertiary uplift of the Sierra Los Ajos was largely accommodated by vertical movement along the north-to-northwest-striking Sierra Los Ajos fault zone flanking the west side of the range. This fault zone structurally controls the configuration of the headwaters of the San Pedro River basin, an important bi-national water resource in the US-Mexico border region.

Hydrogeology of south-central St Croix, US Virgin Islands

USGS Publications Warehouse

Graves, R.P.

1995-01-01

The subsurface geology of south-central St. Croix consists of alluvium and underlying carbonate rocks. The alluvial deposits consist of sand and gravel with cobbles and boulders and, locally, thin lenses of silt and clay. The carbonate rocks consist of the Oligocene to Middle Miocene age Jealousy formation, the Miocene and Pliocene are Kingshill Limestone, and the Pliocene and younger age Post-Kingshill Carbonates. Ground water occurs under water-table conditions in the alluvial, Post-Kingshill Carbonates, and Kingshill Limestone deposits. These deposits are hydraulically connected and are considered to be a single hydrologic unit. The top of the water-table aquifer can range from 5 to 68 feet below land surface. The top of the Jealousy Formation is considered to be the bottom of the water- table aquifer and generally is from 85 to greater than 120 feet below land surface. Aquifer yields in south- central St. Croix can range from less than 5 gallons per minute to 80 gallons per minute. The ground- water in the study area is of the sodium-chloride type. Ground-water samples collected from selected wells had chloride concentrations ranging from 64 to 4,400 milligrams per liter, and dissolved solid concen- trations ranging from 619 to 7,540 milligrams per liter. Connate water is suspected as being the source of sodium chloride in the ground water.

Sustainable Blended Cements-Influences of Packing Density on Cement Paste Chemical Efficiency.

PubMed

Knop, Yaniv; Peled, Alva

2018-04-18

This paper addresses the development of blended cements with reduced clinker amount by partial replacement of the clinker with more environmentally-friendly material (e.g., limestone powders). This development can lead to more sustainable cements with reduced greenhouse gas emission and energy consumption during their production. The reduced clicker content was based on improved particle packing density and surface area of the cement powder by using three different limestone particle diameters: smaller (7 µm, 3 µm) or larger (70 µm, 53 µm) than the clinker particles, or having a similar size (23 µm). The effects of the different limestone particle sizes on the chemical reactivity of the blended cement were studied by X-ray diffraction (XRD), thermogravimetry and differential thermogravimetry (TG/DTG), loss on ignition (LOI), isothermal calorimetry, and the water demand for reaching normal consistency. It was found that by blending the original cement with limestone, the hydration process and the reactivity of the limestone itself were increased by the increased surface area of the limestone particles. However, the carbonation reaction was decreased with the increased packing density of the blended cement with limestone, having various sizes.

Early Bashkirian Rugosa (Anthozoa) from the Donets Basin (Ukraine). Part 6. The Family Aulophyllidae Dybowski, 1873

NASA Astrophysics Data System (ADS)

Fedorowski, Jerzy

2017-12-01

Seven genera (one new), belonging to four subfamilies, seven named species (six new), four species left in open nomenclature and two specimens included in this paper as unnamed Aulophyllidae are described from strata ranging from the lowermost Bashkirian Limestone D510 to the lower Bashkirian Limestone F1. A new genus: Voragoaxum and six new species: Dibunophyllum medium, Dibunophylloides columnatus, D. paulus, D. similis, Voragoaxum cavum and Rozkowskia lenta are introduced. Comparison of the ontogeny of the earliest Bashkirian species of Nina Fedorowski, 2017a and Dibunophylloides Fomichev, 1953 suggest the derivation by descent of the Family Bothrophyllidae from the Subfamily Dibunophyllinae. This means that true bothrophylla are absent in the Mississippian strata of the Western European Province and, perhaps, in the contemporaneous strata of other areas as well.

STEAM INJECTION INTO FRACTURED LIMESTONE AT LORING AIR FORCE BASE

EPA Science Inventory

A research project on steam injection for the remediation of spent chlorinated solvents from fractured limestone was recently undertaken at the former Loring AFB in Limestone, ME. Participants in the project include the Maine Department of Environmental Protection, EPA Region I,...

Structure of the top of the Karnak Limestone Member (Ste. Genevieve) in Illinois

DOE Office of Scientific and Technical Information (OSTI.GOV)

Bristol, H.M.; Howard, R.H.

1976-01-01

To facilitate petroleum exploration in Illinois, the Illinois State Geological Survey presents a structure map (for most of southern Illinois) of the Karnak Limestone Member--a relatively pure persistent limestone unit (generally 10 to 35 ft thick) in the Ste. Genevieve Limestone of Genevievian age. All available electric logs and selected studies of well cuttings were used in constructing the map. Oil and gas development maps containing Karnak-structure contours are on open file at the ISGS.

Field Test of Expedient Pavement Repairs (Test Items 16-35).

DTIC Science & Technology

1980-11-01

82 61 Surface Profiles After Repairs, Item 34 ............ ... 83 62 Cracking of Bond, Item 34 ..... ................. . 84 ix JI x LIST OF...Limestone Base Course .... ............... . 79 18 Summary of Test Results ...... .................. . 88 x ABBREVIATIONS AND NOMENCLATURE Abbreviations AFESC...coverage$ Lateral quarter X - M5 coverages -020- - 0.251 +0.10- centerline -0.05- 0 0 I> + o.IO_ quarter point -0.10 -0.20- - 0.25+ TRAFFIC ZONES . Lonituina

Use of limestone karst forests by Bornean orangutans (Pongo pygmaeus morio) in the Sangkulirang peninsula, east Kalimantan, Indonesia.

PubMed

Marshall, Andrew J; Salas, Leonardo A; Stephens, Suzette; Engström, Linda; Meijaard, Erik; Stanley, Scott A

2007-02-01

The Indonesian province of East Kalimantan is home to some of the largest remaining contiguous tracts of lowland Dipterocarp forest on the island of Borneo. Nest surveys recently conducted in these forests indicated the presence of a substantial population of Eastern Bornean orangutans (Pongo pygmaeus morio) in the Berau and East Kutai regencies in the northern half of the province. The Sangkulirang Peninsula contains extensive limestone karst forests in close proximity to the lowland Dipterocarp forests inhabited by orangutans in these regencies. Orangutans have been sighted in these limestone karst forests, but the importance of this forest type for orangutans has been unclear. Therefore, we conducted 49 km of nest surveys in limestone karst forest to obtain the first quantitative estimates of orangutan densities in this habitat, and walked 28 km of surveys in nearby lowland Dipterocarp forests for comparison. We also gathered basic ecological data along our transects in an attempt to identify correlates of orangutan abundance across these habitat types. Undisturbed limestone karst forests showed the lowest orangutan densities (147 nests/km(2), 0.82 indiv/km(2)), disturbed limestone forests had intermediate densities (301 nests/km(2), 1.40 indiv/km(2)), and undisturbed lowland Dipterocarp forests contained the highest density (987 nests/km(2), 5.25 indiv/km(2)), significantly more than the undisturbed limestone karst forests. This difference was not correlated with variation in liana abundance, fig stem density, or stump density (an index of forest disturbance). Therefore, other factors, such as the relatively low tree species diversity of limestone karst forests, may explain why orangutans appear to avoid these areas. We conclude that limestone karst forests are of low relevance for safeguarding the future of orangutans in East Kalimantan.

Stable isotope evidence for hydrologic conditions during regional metamorphism in the Panamint Mountains, California

DOE Office of Scientific and Technical Information (OSTI.GOV)

Bergfeld, D.; Nabelek, P.I.; Labotka, T.C.

1992-01-01

The Kingston Peak Formation forms part of the Panamint Mountains, California, metamorphic core-complex. Peak tremolite-grade metamorphism as exhibited in Wildrose Canyon occurred in the Jurassic; a retrograde thermal event may have occurred in the Cretaceous. The formation consists dominantly of interbedded siliceous limestones and graphitic calcareous schists. Stable isotopic analysis shows two distinct groups of data. delta O-18 values of calcite from the limestones range between 15.3 and 17.3[per thousand], probably reflecting their original Proterozoic depositional values. Likewise the delta C-13 values are also unshifted, ranging from +1% to +3.8%o. In contrast, delta O-18 values of calcite from the schistsmore » are for the most part > 20[per thousand]. These high values could reflect the original depostional conditions; however, they may be due to equilibration with silicate minerals which range from 14.9 to 17.9[per thousand]. Overall, the combined oxygen and carbon isotopic data indicate that most isotopic changes can be explained by closed-system equilibration. Only a limited amount of interaction with externally-derived fluids during metamorphism is evident in the isotopic data. The interaction may have been confined to vicinities of faults and fractures which are common in Wildrose Canyon.« less

Stylolitization as source of cement in Mississippian Salem Limestone, west-central Indiana

DOE Office of Scientific and Technical Information (OSTI.GOV)

Finkel, E.A.; Wilkinson, B.H.

The Mississippian Salem Limestone of west-central Indiana is a homogeneous cross-bedded grainstone containing numerous stylolites with amplitudes ranging up to 25 cm. Petrographic and geochemical analyses of closely spaced samples from four 1-m thick stylolite-bounded units document spatial trends in grainstone texture and composition, which correlate with proximity to bounding solution seams. Textural data indicate that stylolitization was locally preceded by grain compaction and that seam solution preferentially occurred within layers where grain packing was tightest. Amount of cement largely corresponds to volume of available pore space, and remaining porosity varies inversely to stylolite proximity. Trace-element compositions demonstrate that intergranularmore » spar is enriched in Mn and depleted in Mg relative to grains, and suggest a significant contribution of carbonate cement to grainstone pores from bounding solution seams. Data on grainstone and stylolite insoluble contents indicate that stylolite amplitude records 43% of actual section shortening. On average, seam solution within the Salem Limestone could have provided no less than 47% and no more than 90% of the CaCO{sub 3}, Fe, and Mn mass now in grainstone pores as intergranular spar cement. As such, stylolitization has played an important role during burial diagenesis, porosity occlusion, and permeability reduction within this Mississippian grainstone sequence. 17 figs., 1 tab.« less

Borehole geophysical and flowmeter data for eight boreholes in the vicinity of Jim Woodruff Lock and Dam, Lake Seminole, Jackson County, Florida

USGS Publications Warehouse

Clarke, John S.; Hamrick, Michael D.; Holloway, O. Gary

2011-01-01

Borehole geophysical logs and flowmeter data were collected in April 2011 from eight boreholes to identify the depth and orientation of cavernous zones within the Miocene Tampa Limestone in the vicinity of Jim Woodruff Lock and Dam in Jackson County, Florida. These data are used to assess leakage near the dam. Each of the eight boreholes was terminated in limestone at depths ranging from 84 to 104 feet. Large cavernous zones were encountered in most of the borings, with several exceeding 20-inches in diameter. The cavernous zones generally were between 1 and 5 feet in height, but a cavern in one of the borings reached a height of about 6 feet. The resistivity of limestone layers penetrated by the boreholes generally was less than 1,000 ohm-meters. Formation resistivity near the cavernous zones did not show an appreciable contrast from surrounding bedrock, probably because the bedrock is saturated, owing to its primary permeability. Measured flow rates in the eight boreholes determined using an electromagnetic flowmeter were all less than ±0.1 liter per second. These low flow rates suggest that vertical hydraulic gradients in the boreholes are negligible and that hydraulic head in the various cavernous zones shows only minor, if any, variation.

DOE Office of Scientific and Technical Information (OSTI.GOV)

Sari, A.; Geze, Y.

The studied area is a lake basin located in Bolu basin in Turkey. In the basin, from Upper Cretaceous to Upper Miocene 3,000-m thickness sediments were deposited. Upper Miocene Himmetoglu formation consisted of sandstone, claystone, and marl. To the middle level of the formation are located coal, bituminous limestone, and bituminous shales. In the basin, there are two coal beds whose thicknesses range from 1 to 13 m. The coals are easily breakable and black in color. In the coal beds exists some bituminous limestone and bituminous shales, and their thicknesses are between 5 and 45 cm. The amount ofmore » organic matter of the bituminous rocks from the Upper Miocene Himmetoglu formation are between 6.83 and 56.34 wt%, and the amount of organic matter of the bituminous limestone from the formation are between 13.58 and 57.16 wt%. These values indicate that these rocks have very good source potential. According to hydrogen index (HI), S2/S3, HI-T{sub max}, and HI-OI (oxygen index) parameters, kerogen types of the bituminous rocks and coals belonging to Upper Miocene Himmetoglu formation are Type I, Type II, and Type III. In accordance with HI, S2/S3, HI-T{sub max}, and HI-OI parameters, the bituminous rocks and coals from the Upper Miocene Himmetoglu formation are mostly immature.« less

Use of limestone screenings in S-5 surface mixes : final report.

DOT National Transportation Integrated Search

1982-01-01

It is often practical to use limestone screenings in non-polishing S-5 surface mixes in some western areas of Virginia. Also, there has been some conjecture that limestone increases the durability of these mixes. Although the fine aggregate usually h...

Stratigraphy and structure of the Miners Mountain area, Wayne County, Utah

USGS Publications Warehouse

Luedke, Robert G.

1953-01-01

The Miners Mountain area includes about 85 square miles in Wayne County, south-central Utah. The area is semiarid and characterized by cliffs and deep canyons. Formations range in age from Permian to Upper Jurassic and have an aggregate thickness of about 3,500 feet. Permian formations are the buff Coconino sandstone and the overlying white, limy, shert-containing Kaibab limestone. Unconformably overlying the Kaihab is the lower Triassic Moenkopi formation of reddish-brown and yellow mudstone, siltstone, and sandstone; it contains the Sinbad limestone member (?) in the lower part. Thin, lenticular Shinarump conglomerate unconformably overlies the Moenkopi, but grades upward into the Upper Triassic Chinle formation of variegated mudstone with some interbedded sandstone and limestone lenses. Uncomformably overlying the Chinle are the Wingate sandstone, Kayenta formation, and Navajo sandstone of the Jurassic (?) Glen Canyon group, which consist of red to white sandstone. Only the lower part of the Carmel formation of the Upper Jurassic San Rafael group is exposed in the area; it consists of variegated siltstone, sandstone, limestone, and gypsum. The conspicuous structural feature in the area is the Teasdale anticline which trends northwest, is about 14 miles long, and is asymmetric with a steeper west flank. Bounding the anticline on the northeast and east is the Capitol Reef monocline, the northern part of the Waterpocket Fold. Strata in the area are broken by steeply-dipping normal faults with small displacements, except for the Teasdale fault which has a maximum displacement of over 1,000 feet. Jointing is prominent in some formations. The major orogenic movement in the area is believed to be late Upper Cretaceous to early Tertiary. Epeirogenic uplift occurred intermittently throughout Tertiary and perhaps Quaternary time.

Estimating amplitudes of fifth-order sea level fluctuations from peritidal through basinal carbonate deposits, Lower Mississippian, Wyoming-Montana

DOE Office of Scientific and Technical Information (OSTI.GOV)

Elrick, M.; Read, J.F.

1990-05-01

Three types of 1-10-m upward-shallowing cycles are observed in the Lower Mississippian Lodgepole and lower Madison formations of Wyoming and Montana. Typical peritidal cycles have pellet grainstone bases overlain by algal laminites, which are rarely capped by paleosol/regolith horizons. Shallow ramp cycles have burrowed pellet-skeletal wackestone bases overlain by cross-bedded ooid/crinoid grainstone caps. Deep ramp cycles are characterized by sub-wave base limestone/argillite, storm-deposited limestone, overlain by hummocky stratified grainstone caps. Average cycle periods range from 17-155 k.y. This, rhythmically bedded limestone/argillite deposits of basinal facies do not contain shallowing-upward cycles, but do contain 2-4 k.y. limestone/argillite rhythms. These sub-wave basemore » deposit are associated with Waulsortian-type mud mounds which have >50 m synoptic relief. This relief provides minimum water depth estimates for the deposits, and implies storm-wave base was less than 50 m. Two-dimensional computer modeling of cyclic platform through noncyclic basinal deposits allows for bracketing of fifth-order sea level fluctuation amplitudes, thought responsible for cycle formation. Computer models using fifth-order amplitudes less than 20 m do not produce cycles on the deep ramp (assuming a 25-30 m storm-wave base). Amplitudes >30 m produce water depths on the inner ramp that are too deep, and disconformities extend too far into the basin. The absence of meter-scale cycles in the basin suggests water depths were too great to record the effects of sea level oscillations occurring on the platform, or climatic fluctuation, associated with glacio-eustatic sea level oscillations, were not sufficient to affect hemipelagic depositional patterns in the tropical basin environment.« less

Oxygen-Carbon and Strontium Isotope Evidence for the Origin and Evolution of CO2-rich Volatiles from Oligocene to Miocene Mantle Magmas, Southwestern Colorado and Northwestern New Mexico

NASA Astrophysics Data System (ADS)

Gonzales, D. A.; Zbrozek, M.

2012-12-01

Oligocene to Miocene, alkaline mafic to ultramafic, rocks that are exposed in the Navajo volcanic field and dikes on the northern San Juan basin (NVSJ) contain calcite in vugs, veins, and breccias. Oxygen-carbon and Sr isotope signatures of bulk carbonate samples from these rocks were used to test hypotheses on the history of volatiles related to this pulse of mantle magmatism. Elevated fluorine in rocks, and fluorite-calcite breccias in some outcrops, indicate that magmatic volatiles were released by NVSJ melts. Oxygen and carbon isotope data for carbonate samples record a complex paragenetic history. δ13C values are mostly -8‰ to -4‰ with a mean value of -5.3 ± 2.0‰, similar to δ13C for primary mantle-derived carbonate. A subset of δ18O values are +5‰ to +10‰ which are within the accepted range of δ18O values for magmatic carbonate in carbonatite and kimberlite. A majority of δ18O values, however, range from +10‰ to +24‰ revealing that low-δ18O magmatic volatiles were overprinted by processes that caused enrichment of 18O at some stage during melt generation and emplacement. A subset of 87Sr/86Sri data from carbonate samples are nearly identical to 87Sr/86Sri for related rocks, hinting that the melts and volatiles came from the same source. Generally, NVSJ calcite samples have higher 87Sr/86Sri ratios than those of rocks, reflecting different melt-volatile sources or crustal contamination from Paleozoic limestone. Field and petrologic evidence does not lend convincing support for crustal contamination. Limestone fragments comprise less than 1% of xenoliths in NVSJ rocks. Also, rock samples do not show elevated CaO, MgO, FeO, Ba or Sr with increasing δ18O calcite which is expected for contamination of magmas with limestone. We propose that CO2-H2O-F volatiles in NVSJ magmas came from distinct melt-volatile sources, similar to the interpretation of Nowell (1993). Our assertion is that CO2-rich volatiles that exsolved from low δ18O mafic melts interacted with volatiles and melts from carbonate-bearing metasomatized lithospheric mantle. This is consistent with the subtle increase of 87Sr/86Sri rock and fluorine over the +6‰ to +24‰ range of δ18Ocalcite values recorded in minette samples. This hypothesis is supported by other studies that document +21‰ to +25‰ δ18O for carbonate in mantle xenoliths from Pliocene alkaline basalts in the region. Incipient to extensive alteration of olivine and phlogopite phenocrysts in NVSJ rocks reveals that deuteric isotopic exchange with H2O-CO2 magmatic fluids was a plausible factor for some of the variation in δ18O of calcite samples. In addition, melt contamination with limestone cannot be ruled out, but it requires nearly complete digestion of xenoliths in feeder dikes that had relatively low volumes of magma and cooled quickly. Overall, the isotope data combined with field and petrologic results are not consistent with models that invoke groundwater as the main source of volatiles in NVSJ magmas.

Stromatolitic structures associated with sulfur-bearing limestones from the Miocene (Badenian) of the Carpathian Foredeep (S Poland)

NASA Astrophysics Data System (ADS)

Siewicz, Andrzej Gä; Olchowy, Piotr

2010-05-01

The Middle Badenian (Miocene) evaporitic unit is widespread in the Miocene of the Carpathian Foredeep (South Poland). The unit is predominated by sulfates (gypsum + anhydrite) and locally in the northern marginal part of the foredeep contains carbonate complexes up to 45 m thick. The carbonate series are lithologically heterogenous and change from clayey and marl interlayers through marly to pure limestones and may be either sulfur-bearing or barren limestones locally intercalated by sulfate beds and layers. The bulk of the limestones consist of more or less calcareous, either non-bedded or bedded, laminated or streaky mudstones. The series is locally intercalated by breccia, rudstone (nodular) and gypsum-ghost facies. A characteristic feature of the carbonate mudstones lithofacies is the presence of variously developed sparse, thin and finely laminated layers and small (up to few centimeters in height) domal forms clearly resembling stromatolitic structures. The laminated layers usually are up to about 20 cm, discontinuous (up to a few tens meters long) and occur in various stratigraphic positions. The structures reveal wavy or flat, thin and subtle lamination consisting of intercalation of discontinuous native sulfur and calcareous laminae. They are lacking of gypsum selenite relics. There are two kinds of laminae: 1) thicker ones composed of finer to coarser crystalline calcite, sometimes with various clay admixtures and 2) thinner, commonly more or less discontinuous composed of subtle, fine crystalline and pure native sulfur. The calcite laminae are commonly barren with microfossils. The native sulfur laminae are commonly re-crystallized but often contain honey-comb like structures and local pockets with variously preserved sulfur microbial remains. The microfossils are poorly preserved and include coccoid and filamentous remains. The microbial structures are locally associated with irregular patches of structureless amorphous material resembling mucilage associated with many recent microorganisms. The calcite laminae are characterized by variable 18O values ranging in between -3.3 and -6.8‰ PDB and 13C ones from -31.7 to -57.2‰ PDB. The native sulfur forming laminae has positive 34S values changing from 4.6 to 17.2‰ CDT. Both the structural and isotopic data allow to interpret the stromatolitic structures as a result of microbial activity of syntropic sulfate-reducing and methanotrophic consortia + sulfide oxidizing bacteria. As it may be inferred from sedimentological and geochemical features of both the sulfur stromatolitic structures and associated sulfur-bearing limestones, the environment was generally shallow water, penesaline and euxinic, interrupted by meteoric influxes with precipitation of calcite and native sulfur, supply of both detrital and produced in situ organic matter. Such laminated structures have commonly been believed as a lithological equivalent of stromatolitic gypsum beds preserved due to massive replacement of solid gypsum by limestones and limestones + native sulfur. However, a more detailed comparison of geometry and distribution, sedimentological and petrologic features, as well as geochemical signatures accordingly exclude the native sulfur stromatolites as an analogue of the stromatolitic gypsum selenites. It argues against epigenetic replacement of solid sulfates and for syndepositional origin sulfur-bearing limestones.

Groundwater monitoring of an open-pit limestone quarry: groundwater characteristics, evolution and their connections to rock slopes.

PubMed

Eang, Khy Eam; Igarashi, Toshifumi; Fujinaga, Ryota; Kondo, Megumi; Tabelin, Carlito Baltazar

2018-03-06

Groundwater flow and its geochemical evolution in mines are important not only in the study of contaminant migration but also in the effective planning of excavation. The effects of groundwater on the stability of rock slopes and other mine constructions especially in limestone quarries are crucial because calcite, the major mineral component of limestone, is moderately soluble in water. In this study, evolution of groundwater in a limestone quarry located in Chichibu city was monitored to understand the geochemical processes occurring within the rock strata of the quarry and changes in the chemistry of groundwater, which suggests zones of deformations that may affect the stability of rock slopes. There are three distinct geological formations in the quarry: limestone layer, interbedded layer of limestone and slaty greenstone, and slaty greenstone layer as basement rock. Although the hydrochemical facies of all groundwater samples were Ca-HCO 3 type water, changes in the geochemical properties of groundwater from the three geological formations were observed. In particular, significant changes in the chemical properties of several groundwater samples along the interbedded layer were observed, which could be attributed to the mixing of groundwater from the limestone and slaty greenstone layers. On the rainy day, the concentrations of Ca 2+ and HCO 3 - in the groundwater fluctuated notably, and the groundwater flowing along the interbedded layer was dominated by groundwater from the limestone layer. These suggest that groundwater along the interbedded layer may affect the stability of rock slopes.

Stratigraphy and sedimentology of the Upper Cretaceous (Campanian) Anacacho Limestone, Texas, USA

USGS Publications Warehouse

Swezey, C.S.; Sullivan, E.C.

2004-01-01

The Upper Cretaceous Anacacho Limestone is exposed in outcrops between the cities of San Antonio and Del Rio, Texas. A detailed study of four outcrops (Blanco Creek section, Sabinal River section, Seco Creek section, Hondo Creek section) shows that the Anacacho Limestone rests on the Upson Clay (which contains fauna of early Campanian age) and is overlain by the Corsicana Marl (which contains fauna of early Maastrichtian age). An unconformity within the Anacacho Limestone is used herein to separate the limestone into a lower member and an upper member. The lower Anacacho member contains fauna of early Campanian age, whereas the upper Anacacho member contains fauna of middle Campanian age. The lower Anacacho member consists predominantly of wackestones to packstones, which are overlain by packstones to grainstones capped by the unconformity. This unconformity is interpreted as a marine flooding surface, delineating a transition from carbonate grainstones deposited in shallow water (<30 m depth) to a chalk deposited in deeper water. Above the unconformity, the upper Anacacho member is characterized by a chalk, overlain by wackestones and packstones. The uppermost section of the Anacacho Limestone consists of packstones and grainstones with abundant and diverse fossils. Most of the Anacacho Limestone developed in relatively shallow water (<50 m depth) leeward of a large carbonate build-up (possibly a rudistid reef) that now comprises the Anacacho Mountains. The environment, however, was open to marine water throughout deposition of the Anacacho Limestone. ?? 2004 Elsevier Ltd. All rights reserved.

DOSAGE DES ELEMENTS EN TRACE DES CALCAIRES AU SERVICE DE L'ARCHEOLOGIE

DOE Office of Scientific and Technical Information (OSTI.GOV)

BLANC,A.; HOLMES,L.; HARBOTTLE,G.

1998-05-01

Numerous quarries in the Lutetian limestone formations of the Paris Basin provided stone for the building and the decoration of monuments from antiquity to the present. To determine the origin of stone used for masonry and sculptures in these monuments, a team of geologists and archaeologists has investigated 300 quarries and collected 2,300 samples. Petrographic and paleontologic examination of thin sections allows geologists to distinguish Lutetian limestones from Jurassic and Cretaceous limestones. Geologists also seek to formulate hypotheses regarding the origin of Lutetian limestones used for building and sculpture in the Paris region. In the search for the sources ofmore » building and sculptural stone, the analytical methods of geologists are limited because often several quarries produce the same lithofacies. A new tool is now available, however, to attack questions of provenance raised by art historians. Because limestones from different sources have distinctive patterns of trace-element concentrations, compositional analysis by neutron activation allows them to compare building or sculptural stone from one monument with stone from quarries or other monuments. This analytical method subjects a powdered limestone sample to standard neutron activation analysis procedures at Brookhaven National Laboratory. With the help of computer programs, the compositional fingerprints of Lutetian limestones can be determined and stored in a database. The limestone database contains data for approximately 2,100 samples from monuments, sculptures and quarries. It is particularly rich in samples from the Paris Basin.« less

Limestone fluidized bed treatment of acid-impacted water at the Craig Brook National Fish Hatchery, Maine, USA

USGS Publications Warehouse

Sibrell, P.L.; Watten, B.J.; Haines, T.A.; Spaulding, B.W.

2006-01-01

Decades of atmospheric acid deposition have resulted in widespread lake and river acidification in the northeastern U.S. Biological effects of acidification include increased mortality of sensitive aquatic species such as the endangered Atlantic salmon (Salmo salar). The purpose of this paper is to describe the development of a limestone-based fluidized bed system for the treatment of acid-impacted waters. The treatment system was tested at the Craig Brook National Fish Hatchery in East Orland, Maine over a period of 3 years. The product water from the treatment system was diluted with hatchery water to prepare water supplies with three different levels of alkalinity for testing of fish health and survival. Based on positive results from a prototype system used in the first year of the study, a larger demonstration system was used in the second and third years with the objective of decreasing operating costs. Carbon dioxide was used to accelerate limestone dissolution, and was the major factor in system performance, as evidenced by the model result: Alk = 72.84 ?? P(CO2)1/2; R2 = 0.975. No significant acidic incursions were noted for the control water over the course of the study. Had these incursions occurred, survivability in the untreated water would likely have been much more severely impacted. Treated water consistently provided elevated alkalinity and pH above that of the hatchery source water. ?? 2005 Elsevier B.V. All rights reserved.

Geochemistry and origin of regional dolomites

DOE Office of Scientific and Technical Information (OSTI.GOV)

Hanson, G.N.; Meyers, W.J.

1989-12-01

The major goal of the carbonate research program at Stony Brook is to better understand the conditions and processes leading to regional diagenesis of carbonate rocks. Our research focuses on studies of ancient, massive dolostones, but we are also studying limestone diagenesis for its own importance, and as it relates to dolomitization. Our approach has been to carry out a very detailed petrographic and geochemical case study to the Mississippian Burlington-Keokuk Fms. of Iowa, Illinois and Missouri, and to develop this as a testing ground for new geochemical and modelling techniques, and for testing various models for regional dolomitization inmore » epicontinental carbonates. The ideas and techniques developed in our Burlington-Keokuk studies are being expanded and applied to carbonate sequences of other ages (Devonian to Neogene), and other tectono-sedimentary settings. The emphasis of this report will be on new developments and results on the Burlington-Keokuk studies and on our diagenetic studies of other strata. Recent research on Burlington-Keokuk rocks include development and application of boron isotopes and the U--Th--Pb system to dolomite studies, investigations of porosity and permeability in the dolostones. Projects on other strata include dolomitization and limestones diagenesis of Devonian carbonates of Alberta and Western Australia, Miocene reefal carbonates of Spain, Neogene carbonates of Curacao and Bonaire, Waulsortian limestones of Ireland, modelling of trace elements and stable isotopes, and experimental growth of calcites to investigate crystallographic controls of trace element incorporation. 118 refs., 46 figs.« less

Correlation between high-resolution remote-sensing imagery and detailed field mapping in Cordilleran Miogeocline

DOE Office of Scientific and Technical Information (OSTI.GOV)

Feldman, S.C.; Taranik, J.V.

1986-05-01

Selected areas were mapped at a scale of 1:6000 in the southern hot Creek Range (south-central Nevada), which is underlain by Paleozoic autochthonous limestone, shale, and sandstone, Paleozoic allochthonous chert and siltstone, and Tertiary rhyolitic to dactitic ash flow tuff. The mapping was compared with computer-processed Airborne Imaging Spectrometer (AIS) data and Landsat Thematic Mapper (TM) imagery. The AIS imagery of the Hot Creek Range was acquired in 1984 by a NASA C-130 aircraft; it has a spatial resolution of 12 m, and swath width of 380 m. The sensor was developed by the Jet Propulsion Laboratory and is themore » first in a series of NASA imaging spectrometers. The AIS collects 128 spectral bands, having a bandwidth of approximately 9 nm, in the short-wave infrared between 1.2 and 2.4 ..mu..m. This part of the spectrum contains important narrow spectral absorption features for the carbonate ion, hydroxyl ion, and water of hydration. Using computer-processed AIS imagery, therefore, the authors can separate calcite from dolomite, and kaolinite from illite and montmorillonite as well as differentiate geologic units containing these minerals. On the AIS imagery, the Upper Mississippian Tripon Pass Limestone shows a distinctive calcite absorption feature at 2.34 ..mu..m; this feature is not as pronounced in Cambrian and Ordovician limestones. The dolomitized Nevada Formation exhibits the dolomite absorption feature at 2.32 ..mu..m. Clay mineral absorption features near 2.2 ..mu..m can be distinguished in altered volcanics. Mineralogic identification was confirmed with field and laboratory spectroradiometer measurements, thin-section examination, and x-ray analysis. AIS results and field mapping were also compared to computer-processed Landsat TM imagery, the highest spectral and spatial resolution worldwide data set currently available.« less

Microbiome and ecotypic adaption of Holcus lanatus (L.) to extremes of its soil pH range, investigated through transcriptome sequencing.

PubMed

Young, Ellen; Carey, Manus; Meharg, Andrew A; Meharg, Caroline

2018-03-20

Plants can adapt to edaphic stress, such as nutrient deficiency, toxicity and biotic challenges, by controlled transcriptomic responses, including microbiome interactions. Traditionally studied in model plant species with controlled microbiota inoculation treatments, molecular plant-microbiome interactions can be functionally investigated via RNA-Seq. Complex, natural plant-microbiome studies are limited, typically focusing on microbial rRNA and omitting functional microbiome investigations, presenting a fundamental knowledge gap. Here, root and shoot meta-transcriptome analyses, in tandem with shoot elemental content and root staining, were employed to investigate transcriptome responses in the wild grass Holcus lanatus and its associated natural multi-species eukaryotic microbiome. A full factorial reciprocal soil transplant experiment was employed, using plant ecotypes from two widely contrasting natural habitats, acid bog and limestone quarry soil, to investigate naturally occurring, and ecologically meaningful, edaphically driven molecular plant-microbiome interactions. Arbuscular mycorrhizal (AM) and non-AM fungal colonization was detected in roots in both soils. Staining showed greater levels of non-AM fungi, and transcriptomics indicated a predominance of Ascomycota-annotated genes. Roots in acid bog soil were dominated by Phialocephala-annotated transcripts, a putative growth-promoting endophyte, potentially involved in N nutrition and ion homeostasis. Limestone roots in acid bog soil had greater expression of other Ascomycete genera and Oomycetes and lower expression of Phialocephala-annotated transcripts compared to acid ecotype roots, which corresponded with reduced induction of pathogen defense processes, particularly lignin biosynthesis in limestone ecotypes. Ascomycota dominated in shoots and limestone soil roots, but Phialocephala-annotated transcripts were insignificant, and no single Ascomycete genus dominated. Fusarium-annotated transcripts were the most common genus in shoots, with Colletotrichum and Rhizophagus (AM fungi) most numerous in limestone soil roots. The latter coincided with upregulation of plant genes involved in AM symbiosis initiation and AM-based P acquisition in an environment where P availability is low. Meta-transcriptome analyses provided novel insights into H. lanatus transcriptome responses, associated eukaryotic microbiota functions and taxonomic community composition. Significant edaphic and plant ecotype effects were identified, demonstrating that meta-transcriptome-based functional analysis is a powerful tool for the study of natural plant-microbiome interactions.

Laboratory Investigations in Support of Carbon Dioxide-Limestone Sequestration in the Ocean

DOE Office of Scientific and Technical Information (OSTI.GOV)

Dan Golomb; Eugene Barry; David Ryan

2005-11-01

This semi-annual progress reports includes further findings on CO{sub 2}-in-Water (C/W) emulsions stabilized by fine particles. In previous semi-annual reports we described the formation of stable C/W emulsions using pulverized limestone (CaCO{sub 3}), flyash, beach sand, shale and lizardite, a rock rich in magnesium silicate. For the creation of these emulsions we used a High-Pressure Batch Reactor (HPBR) equipped with view windows for illumination and video camera recording. For deep ocean sequestration, a C/W emulsion using pulverized limestone may be the most suitable. (a) Limestone (mainly CaCO{sub 3}) is cheap and plentiful; (b) limestone is innocuous for marine organisms (inmore » fact, it is the natural ingredient of shells and corals); (c) it buffers the carbonic acid that forms when CO{sub 2} dissolves in water. For large-scale sequestration of a CO{sub 2}/H{sub 2}O/CaCO{sub 3} emulsion a device is needed that mixes the ingredients, liquid carbon dioxide, seawater, and a slurry of pulverized limestone in seawater continuously, rather than incrementally as in a batch reactor. A practical mixing device is a Kenics-type static mixer. The static mixer has no moving parts, and the shear force for mixing is provided by the hydrostatic pressure of liquid CO{sub 2} and CaCO{sub 3} slurry in the delivery pipes from the shore to the disposal depth. This semi-annual progress report is dedicated to the description of the static mixer and the results that have been obtained using a bench-scale static mixer for the continuous formation of a CO{sub 2}/H{sub 2}O/CaCO{sub 3} emulsion. The static mixer has an ID of 0.63 cm, length 23.5 cm, number of baffles 27. Under pressure, a slurry of CaCO{sub 3} in artificial seawater (3.5% by weight NaCl) and liquid CO{sub 2} are co-injected into the mixer. From the mixer, the resulting emulsion flows into a Jerguson cell with two oblong windows on opposite sides, then it is vented. A fully ported ball valve inserted after the Jerguson cell allows the emulsion to be stopped in the cell. In such a manner the emulsion can be photographed while it is flowing through the cell, or after it has stagnated in the cell. A slurry of 10 g/L CaCO{sub 3} (Sigma Chemicals C-4830 reagent grade) in artificial seawater, co-injected into the static mixer at a rate of 1.5 L/min with liquid CO{sub 2} at a rate of 150 mL/min, at temperature 5-10 C, pressure 10 MPa, produced an emulsion with mean globule diameter in the 70-100 {micro}m range. In a HPBR, using the same materials, proportions, temperature and pressure, mixed with a magnetic stir bar at 1300 rpm, the mean globule diameter is in the 200-300 {micro}m range. Evidently, the static mixer produces an emulsion with smaller globule diameters and narrower distribution of globule diameters than a batch reactor.« less

Colmenar limestone as a resource for built heritage

NASA Astrophysics Data System (ADS)

Fort, Rafael; Álvarez de Buergo, Mónica; Varas-Muriel, MªJosé; Mercedes Pérez-Monserrat, Elena

2013-04-01

The Colmenar stone (or Colmenar limestone) has been used in the construction of significant builidings of the Central area of Spain, such as the Royal Palace of Aranjuez (16th -18th centuries) or the Royal Palace of Madrid (18th century). Nowadays this building stone is still widely used, both for new construction and restoration works, as well as for the indoor ornamentation of emblematic buildings such as the Royal Theater of Madrid (20th century). There are many quarries from where this stone was exploited, being the most prestigious ones those located in Colmenar de Oreja, at 50 km Southeast the city of Madrid. The high quality of the stone in these quarries, its whiteness and pureness, made this locality the most relevant in these stonés extractive activities, concentrating the most relevant exploitations and providing the stone the denomination of the municipality (Colmenar). It was an underground mining extraction until the 20th century in order to reach the highest quality level of the mine, the so called "Banco Gordo" (Thick Bank). Generically known as moorland limestone, this rock belongs to the fluvial-lacustrine carbonates of the Upper Miocene Unit of the Tertiary Madrid's Basin. Its tonality mainly ranges from white to cream and even light grey. Under a petrographic point of view, this limestone is constituted by 40% of bioclasts (characea, ostracods and gasteropods), 20-30% of micritic matrix and 30-40% of sparitic cement. Therefore, it can be classified as a biomicrite/biosparite limestone or as a bioclastic packstone. Some particularities of these limestones regarding their appearance are related to some karstic processes they underwent linked to some dissolution phenomena during the Pliocene. All of this resulted on an abundance of cavities with terra rossa fillings, a non-soluble clayey residue, iron enriched, which is the responsible for the reddish and pinkish color that the Colmenar stone sometimes shows. These petrographic characteristics define the petrophysical properties that make this rock a high quality building material. Its bulk density is 2580 ± 30 kg/m3 and its anisotropy grade is low (dM 3.1%). Its open porosity (accessible to water) is 3.8%, its water absorption is 0.8% and the ultrasound propagation velocity (Vp) is 5941 ± 111 m/s. Regarding mechanical strength, compression and flexural resistances are 78 ± 34 MPa and 9.1 ± 3.1 MPa, respectively. Microporosity is significant in this stone, with an 80% of the pores (accessible to mercury) with a diameter ranging from 0.01 to 0.1 µm. The particularities of this stone pore system, with scarce capillar porosity, makes difficult the entry of water towards its interior. Therefore the material shows a good hydric behavior, with a high durability against frost-defrost processes and thermal shock cycles, as well to salt crystallisation phenomena. Acknowledgments: Special thanks are given to the Geomaterials (S2009/MAT 1629) and CONSOLIDER-TCP (CSD2007-0058) Programmes, as well as the Complutense University of Madrid's research group on the alteration and conservation of heritage stone (921349).

Habitat Association, Size, Stomach Contents, and Reproductive Condition of Puerto Rican Boas (Epicrates inornatus)

Treesearch

JAMES W. WILEY

2003-01-01

The Puerto Rican boa occurs in a variety of habitats, including wet montane forest, lowland wet forest, mangrove forest, wet limestone karst, and offshore cays, and from sea level to 480 m. Mean SVL of 49 encountered boas (live and road-killed) was 136.9 ± 35.1 (range = 38.8–205 cm), with a mean mass of 952.1 ± 349.0 g (n = 47; range = 140–1662 g). Prey in digestive...

Limestone - A Crucial and Versatile Industrial Mineral Commodity

USGS Publications Warehouse

Bliss, James D.; Hayes, Timothy S.; Orris, Greta J.

2008-01-01

Limestone, as used by the minerals industry, is any rock composed mostly of calcium carbonate (CaCO3). Although limestone is common in many parts of the United States, it is critically absent from some. Limestone is used to produce Portland cement, as aggregate in concrete and asphalt, and in an enormous array of other products, making it a truly versatile commodity. Portland cement is essential to the building industry, but despite our Nation's abundance of limestone, there have been cement shortages in recent years. These have been caused in part by a need to find new areas suitable for quarrying operations. To help manage our Nation's resources of such essential mineral commodities, the U.S. Geological Survey (USGS) provides crucial data and scientific information to industry, policymakers, and the public.

Influence of limestone characteristics on mercury re-emission in WFGD systems.

PubMed

Ochoa-González, Raquel; Díaz-Somoano, Mercedes; Martínez-Tarazona, M Rosa

2013-03-19

This work evaluates the influence of the effect of the properties of limestones on their reactivity and the re-emission of mercury under typical wet scrubber conditions. The influence of the composition, particle size, and porosity of limestones on their reactivity and the effect of sorbent concentration, pH, redox potential, and the sulphite and iron content of the slurry on Hg(0) re-emission was assessed. A small particle size, a high porosity and a low magnesium content increased the high reactivity of the limestones. Moreover, it was found that the higher the reactivity of the sample the greater the amount of mercury captured in the scrubber. Although sulphite ions did not cause the re-emission of mercury from the suspensions of the gypsums, the limestones enriched in iron increased Hg(0) re-emission under low oxygen conditions. It was observed that the low pH values of the gypsum suspensions favored the cocapture of mercury because Fe(2+) formation was avoided. The partitioning of the mercury in the byproducts of the scrubber depended on the impurities of the limestones rather than on their particle size. No leaching of mercury from the gypsum samples occurred suggesting that mercury was either tightly bound to the impurities of the limestone or was transformed into insoluble mercury species.

Effect of environmental conditions on the decay of stone in archaeological site of Volubilis - Morocco

NASA Astrophysics Data System (ADS)

Aalil, Issam; Chaaba, Ali; Cherkaoui, Khalid; Brunetaud, Xavier; Beck, Kevin; Al-Mukhtar, Muzahim

2015-04-01

Volubilis is the most excavated and the best preserved archaeological site of Morocco. Located about thirty kilometres north of Meknes, it was a Mauritanian capital founded in the 3rd century B.C., and became an important outpost of the Roman Empire. Volubilis monuments are constructed with five regional lithotypes of limestone. A grey massive limestone and beige-yellowish calcarenite limestone are the two most largely used on Volubilis site, representing respectively about 30% and 60 % of the total volume of building stones. Field observations showed that the calcarenite limestone is more decayed than the massive limestone and is mainly affected by scaling, alveolization and sanding. This work aims to estimate the role of environmental conditions on the decay of the calcarenite stone through the effect of thermal stresses and freezing-thawing action. Air temperature data of Meknes station is analysed. Furthermore, mineralogical composition of the calcarenite limestone and its intrinsic properties required for stress calculation are determined. The results of this study show that the calcarenite limestone is a quite soft carbonate stone, contains about 71 % of calcite, 18 % of quartz and others accessory minerals. Besides, there is no risk of damage due to freezing-thawing processes. Nonetheless, thermal stresses may have an important role in the decay of calcarenite stones of the Volubilis site.

Intrinsic and specific vulnerability of groundwater in central Spain: the risk of nitrate pollution

NASA Astrophysics Data System (ADS)

Martínez-Bastida, Juan J.; Arauzo, Mercedes; Valladolid, Maria

2010-05-01

The intrinsic vulnerability of groundwater in the Comunidad de Madrid (central Spain) was evaluated using the DRASTIC and GOD indexes. Groundwater vulnerability to nitrate pollution was also assessed using the composite DRASTIC (CD) and nitrate vulnerability (NV) indexes. The utility of these methods was tested by analyzing the spatial distribution of nitrate concentrations in the different aquifers located in the study area: the Tertiary Detrital Aquifer, the Moor Limestone Aquifer, the Cretaceous Limestone Aquifer and the Quaternary Aquifer. Vulnerability maps based on these four indexes showed very similar results, identifying the Quaternary Aquifer and the lower sub-unit of the Moor Limestone Aquifer as deposits subjected to a high risk of nitrate pollution due to intensive agriculture. As far as the spatial distribution of groundwater nitrate concentrations is concerned, the NV index showed the greatest statistical significance ( p < 0.01). This new type of multiplicative model offers greater accuracy in estimations of specific vulnerability with respect to the real impact of each type of land use. The results of this study provide a basis on which to guide the designation of nitrate vulnerable zones in the Comunidad de Madrid, in line with European Union Directive 91/676/EEC.

Impacts of air pollution on cultural heritage corrosion at European level: What has been achieved and what are the future scenarios.

PubMed

Di Turo, Francesca; Proietti, Chiara; Screpanti, Augusto; Fornasier, M Francesca; Cionni, Irene; Favero, Gabriele; De Marco, Alessandra

2016-11-01

The interaction of pollutants with Cultural Heritage materials leads to artworks and materials degradation and loss, causing an unpriceless damage. This works aims to estimate the impacts of air pollution and meteorological conditions on limestone, copper and bronze and represents the European risk assessment for corrosion of Cultural Heritage materials. The measures and policies for atmospheric pollution reduction have cut off the SO 2 concentration and consequently its impact on materials is drastically reduced. Indeed, in 1980 the number of UNESCO sites in danger was extremely high (94% for limestone, 54% for copper and 1% for bronze) while in 2010 these sites did not exceed the tolerable value of surface recession and corrosion. However, some problem related to air pollution persists. In particular, Random Forest Analysis (RFA), highlights PM 10 as the main responsible for materials corrosion, in 2010. Two scenarios in 2030 have been tested, highlighting that the corrosion levels of limestone, copper and bronze exceed the tolerable limits only in the Balkan area and Turkey. Our results show the importance in the air quality modelling as a powerful tool for the UNESCO sites conservation. Copyright © 2016 Elsevier Ltd. All rights reserved.

Aggregate freeze-thaw testing and d-cracking field performance : 30 years later.

DOT National Transportation Integrated Search

2014-09-01

Premature deterioration of concrete pavement due to D-cracking has been a problem in Kansas since the 1930s. Kansas : geology includes mineable limestone coarse aggregates with variable durability in the eastern portion of the state. Due : to this va...

In situ stabilization of cadmium-, lead-, and zinc-contaminated soil using various amendments.

PubMed

Lee, Sang-Hwan; Lee, Jin-Soo; Choi, Youn Jeong; Kim, Jeong-Gyu

2009-11-01

Chemical stabilization is an in situ remediation method that uses inexpensive amendments to reduce contaminant availability in polluted soil. We tested the effects of several amendments (limestone, red-mud, and furnace slag) on the extractability of heavy metals, microbial activities, phytoavailability of soil metals (assessed using lettuce, Lactuca sativa L.), and availability of heavy metals in ingested soil to the human gastrointestinal system (assessed using the physiologically based extraction test). The application of soil amendments significantly decreased the amount of soluble and extractable heavy metals in the soil (p<0.05). The decreased extractable metal content of soil was accompanied by increased microbial activity and decreased plant uptake of heavy metals. Soil microbial activities (soil respiration, urease, and dehydrogenase activity) significantly increased in limestone and red-mud-amended soils. Red-mud was the most effective treatment in decreasing heavy-metal concentrations in lettuce. Compared to non-amended control soil, lettuce uptake of Cd, Pb, and Zn was reduced 86%, 58%, and 73%, respectively, by the addition of red-mud.

Integrating borehole logs and aquifer tests in aquifer characterization

USGS Publications Warehouse

Paillet, Frederick L.; Reese, R.S.

2000-01-01

Integration of lithologic logs, geophysical logs, and hydraulic tests is critical in characterizing heterogeneous aquifers. Typically only a limited number of aquifer tests can be performed, and these need to be designed to provide hydraulic properties for the principle aquifers in the system. This study describes the integration of logs and aquifer tests in the development of a hydrostratigraphic model for the surficial aquifer system in and around Big Cypress National Preserve in eastern Collier County, Florida. Borehole flowmeter tests provide qualitative permeability profiles in most of 26 boreholes drilled in the Study area. Flow logs indicate the depth of transmissive units, which are correlated across the study area. Comparison to published studies in adjacent areas indicates that the main limestone aquifer of the 000000Tamiami Formation in the study area corresponds with the gray limestone aquifer in western Dade County and the water table and lower Tamiami Aquifer in western Collier County. Four strategically located, multiwell aquifer tests are used to quantify the qualitative permeability profiles provided by the flowmeter log analysis. The hydrostratigraphic model based on these results defines the main aquifer in the central part of the study area as unconfined to semiconfined with a transmissivity as high as 30,000 m2/day. The aquifer decreases in transmissivity to less than 10,000 m2/day in some parts of western Collier County, and becomes confined to the east and northeast of the study area, where transmissivity decreases to below 5000 m2/day.Integration of lithologic logs, geophysical logs, and hydraulic tests is critical in characterizing heterogeneous aquifers. Typically only a limited number of aquifer tests can be performed, and these need to be designed to provide hydraulic properties for the principle aquifers in the system. This study describes the integration of logs and aquifer tests in the development of a hydrostratigraphic model for the surficial aquifer system in and around Big Cypress National Preserve in eastern Collier County, Florida. Borehole flowmeter tests provide qualitative permeability profiles in most of 26 boreholes drilled in the study area. Flow logs indicate the depth of transmissive units, which are correlated across the study area. Comparison to published studies in adjacent areas indicates that the main limestone aquifer of the Tamiami Formation in the study area corresponds with the gray limestone aquifer in western Dade County and the water table and lower Tamiami Aquifer in western Collier County. Four strategically located, multiwell aquifer tests are used to quantify the qualitative permeability profiles provided by the flowmeter log analysis. The hydrostratigraphic model based on these results defines the main aquifer in the central part of the study area as unconfined to semiconfined with a transmissivity as high as 30,000 m2/day. The aquifer decreases in transmissivity to less than 10,000 m2/day in some parts of western Collier County, and becomes confined to the east and northeast of the study area, where transmissivity decreases to below 5000 m2/day.

The material from Lampung as coarse aggregate to substitute andesite for concrete-making

NASA Astrophysics Data System (ADS)

Amin, M.; Supriyatna, Y. I.; Sumardi, S.

2018-01-01

Andesite stone is usually used for split stone material in the concrete making. However, its availability is decreasing. Lampung province has natural resources that can be used for coarse aggregate materials to substitute andesite stone. These natural materials include limestone, feldspar stone, basalt, granite, and slags from iron processing waste. Therefore, a research on optimizing natural materials in Lampung to substitute andesite stone for concrete making is required. This research used laboratory experiment method. The research activities included making cubical object samples of 150 x 150 x 150 mm with material composition referring to a standard of K.200 and w/c 0.61. Concrete making by using varying types of aggregates (basalt, limestone, slag) and aggregate sizes (A = 5-15 mm, B = 15-25 mm, and 25-50 mm) was followed by compressive strength test. The results showed that the obtained optimal compressive strengths for basalt were 24.47 MPa for 50-150 mm aggregate sizes, 21.2 MPa for 15-25 mm aggregate sizes, and 20.7 MPa for 25-50 mm aggregate sizes. These results of basalt compressive strength values were higher than the same result for andesite (19.69 MPa for 50-150 mm aggregate sizes), slag (22.72 MPa for 50-150 mm aggregate sizes), and limestone (19.69 Mpa for 50-150 mm aggregate sizes). These results indicated that basalt, limestone, and slag aggregates were good enough to substitute andesite as materials for concrete making. Therefore, natural resources in Lampung can be optimized as construction materials in concrete making.

Effective stress law for the permeability and deformation of four porous limestones

NASA Astrophysics Data System (ADS)

Wang, Y.; Meng, F.; Wang, X.; Baud, P.; Wong, T. F.

2017-12-01

The effective stress behavior of a rock is related to the geometric of its pore space. In a microscopically homogeneous assemblage, effective stress coefficients for permeability, volumetric strain and porosity change are predicted to be equal to or less than unity. Experimental measurements are in basic agreement with this prediction, with exceptions particularly in clay-rich sandstones, for which effective stress coefficient for permeability up to 7 was documented. Little is known about carbonates, but Ghabezloo et al. [2009] studied the permeability of an oolitic limestone (from Nimes, France) with 17% porosity and reported effective stress coefficients up to 2.4. We investigated this phenomenon in Indiana, Leitha, Purbeck, and Thala limestones with porosities of 13-30%. Measurements were made at room temperature on water-saturated samples at confining and pore pressures of 7-15 MPa and 1-3 MPa, respectively. Unlike previous studies limited to the permeability, we also determined the effective stress coefficients for volumetric strain and porosity change. Indiana limestone is oolitic, and not surprisingly its behaviour was similar to Nimes limestone, with an effective stress coefficient for permeability of 2.5. Our Indiana limestone data showed that whereas the effective stress coefficient for volumetric strain was <1, that for porosity change was >1. Measurements on Purbeck and Thala limestones are consistent with these inequalities, with effective stress coefficients for permeability and porosity change >1 and that for volumetric strain <1. Even though Purbeck and Thala limestones are micritic with appreciable amount of quartz and dolomite, microstructural and mercury porosimetry data showed that their pore spaces are similar to the oolitic limestones, in that the pore size distribution is bimodal with significant fractions of both macropores and micropores. Berryman [1992] analyzed theoretically a rock made up of two porous constituents. Our new data are in agreement with inequalities he derived for these effective stress coefficients. For comparison, we also studied Leitha limestone predominately made up of macropores. Our measurements showed that in this case all three effective stress coefficients were <1, as predicted for a microscopically homogeneous assemblage.

Drenov Grič black limestone as a heritage stone from Slovenia

NASA Astrophysics Data System (ADS)

Kramar, Sabina; Rožič, Boštjan; Žbona, Nina; Bedjanič, Mojca; Mladenović, Ana

2016-04-01

The limestone known as Drenov Grič black limestone is considered one of the most beautiful Slovenian natural stones due to its homogenous black colour interwoven with white veins. Over the centuries it has been exploited from three major quarries west of Ljubljana, with the main quarry at Drenov Grič playing the primary role in supplying building material for the central parts of Slovenia. All the quarries are currently not active. In the area of Drenov grič, one locality of black limestone is protected - Kuclerjev kamnolom quarry. It has the status of 'valuable natural feature of national importance' and is protected as a natural monument. This well-stratified micritic limestone of Triassic (Carnian) age occurs in 10-80 cm thick beds, with thin marl interlayers. The stone contains abundant fossil bivalves and ostracods. Apart from calcite as the main component, dolomite, quartz, illite/muscovite and pyrite are also present. The limestone is relatively rich in carbonaceous and bituminous organic matter, which is responsible for the black colour of the stone. This component does not have any adverse effect on mechanical and physical characteristics. As the lime¬stone is dense, thus facilitating a good polish, it has been commercially considered as marble. The stone has been widely used in Slovenian monuments, not only in Ljubljana but also in other regions of Slovenia. Many inner and outdoor architectural elements were made of this limestone, particularly in the baroque period, which was known for the extensive use of black limestones also in other European countries. The most significant use of this limestone has been recorded in sculptured portals and altars. Some of the important buildings decorated utilising this stone, are the Ljubljana Cathedral, the St. James's Parish Church, and the Franciscan Church of the Annunciation, all of which are located in Ljubljana, some of them having been declared as cultural monuments of local or national importance. When exposed to climatic influences, chromatic weathering and salt weathering are recognized as the main deterioration phenomena of this limestone on monuments.

Steam Cured Self-Consolidating Concrete and the Effects of Limestone Filler

NASA Astrophysics Data System (ADS)

Aqel, Mohammad A.

The purpose of this thesis is to determine the effect and the mechanisms associated with replacing 15% of the cement by limestone filler on the mechanical properties and durability performance of self-consolidating concrete designed and cured for precast/prestressed applications. This study investigates the role of limestone filler on the hydration kinetics, mechanical properties (12 hours to 300 days), microstructural and durability performance (rapid chloride permeability, linear shrinkage, sulfate resistance, freeze-thaw resistance and salt scaling resistance) of various self-consolidating concrete mix designs containing 5% silica fume and steam cured at a maximum holding temperature of 55°C. This research also examines the resistance to delayed ettringite formation when the concrete is steam cured at 70°C and 82°C and its secondary consequences on the freeze-thaw resistance. The effect of several experimental variables related to the concrete mix design and also the curing conditions are examined, namely: limestone filler fineness, limestone filler content, cement type, steam curing duration and steam curing temperature. In general, the results reveal that self-consolidating concrete containing 15% limestone filler, steam cured at 55°C, 70°C and 82°C, exhibited similar or superior mechanical and transport properties as well as long term durability performance compared to similar concrete without limestone filler. When the concrete is steam cured at 55°C, the chemical reactivity of limestone filler has an important role in enhancing the mechanical properties at 16 hours (compared to the concrete without limestone filler) and compensating for the dilution effect at 28 days. Although, at 300 days, the expansion of all concrete mixes are below 0.05%, the corresponding freeze-thaw durability factors vary widely and are controlled by the steam curing temperature and the chemical composition of the cement. Overall, the material properties indicate that the use of 15% limestone filler as cement replacement is a viable option for the precast/prestressed concrete applications, and in addition, would also have economic and environmental benefits.

Microcracks induced during dilatancy and compaction in a porous oolithic carbonate rock

NASA Astrophysics Data System (ADS)

Fortin, Jérôme; Stanchits, Sergei; Dresen, Georg; Guéguen, Yves

2010-05-01

Reservoir rocks can undergo irreversible deformation (dilatancy or compaction) as a result of a change in effective stress during production of hydrocarbon or during CO2 storage; and whether deformation occurs in conjunction with dilatation or compaction, it has important implications on fluid transport processes. In this study, we investigated the mechanical behavior of the Chauvigny limestone. This porous limestone is one of the rocks, which constitutes the Dogger, a deep saline aquifer, one of the favorable geological reservoirs for CO2 storage in France. This limestone is an oolithic one and is characterized by a dual porosity: a micro-porosity (inside the ooliths) of ~13% and a macro-porosity of ~4%. The total porosity is ~17%. Previous studies performed on limestone, even the ones with very low porosity like Carrara marble, show at room temperature, a transition with increasing pressure from brittle regime to catalastic flow. Two mechanisms are involved during failure of limestone: cracking, and crystal plasticity, which can be activated at room temperature. To investigate the brittle-ductile transition in this porous limestone, we performed 8 conventional triaxial experiments, at confining pressure in the range of 5-100 MPa, at room temperature and at a constant strain rate of 2.10-4s-1. In addition, the evolutions of elastic wave velocities were measured periodically with loading. The elastic wave velocities are affected by two competing mechanisms: porosity reduction -which increases the velocities-, and cracking -which decreases the velocities-. However the elastic wave velocities are much more sensitive to cracking than to porosity reduction. Our results show that diltatant (nucleation and propagation of cracks) and compaction micro-mechanisms (plastic pore collapse) compete. Two limit cases can be distinguished. During hydrostatic compression, the inelastic volumetric strain seems to be mainly associated with plastic pore collapse, whereas for the triaxial experiments at confining pressure < 30 MPa, the inelastic volumetric strain seems to be mainly associated with the development of shear-induced cracks. For the triaxial experiments at confining pressure > 30 MPa, we are able to distinguish a first critical stress state where plastic pore collapse occurs, and a second stress state where shear-induced cracks are initiated. Reference: J. Fortin, S. Stanchits, G. Dresen and Y. Gueguen, 2009. Micro-mechanisms involved during inelastic deformation of porous carbonate rocks. Poromechanics IV, Proceedings of the fourth Biot conference, edited by H. Ling, A. Smyth, and R. Betti, 378-38

Petrophysical and transport parameters evolution during acid percolation through structurally different limestones

NASA Astrophysics Data System (ADS)

Martinez Perez, Laura; Luquot, Linda

2017-04-01

Processes affecting geological media often show complex and unpredictable behavior due to the presence of heterogeneities. This remains problematic when facing contaminant transport problems, in the CO2 storage industry or dealing with the mechanisms underneath natural processes where chemical reactions can be observed during the percolation of rock non-equilibrated fluid (e.g. karst formation, seawater intrusion). To understand the mechanisms taking place in a porous medium as a result of this water-rock interaction, we need to know the flow parameters that control them, and how they evolve with time as a result of that concurrence. This is fundamental to ensure realistic predictions of the behavior of natural systems in response of reactive transport processes. We investigate the coupled influence of structural and hydrodynamic heterogeneities in limestone rock samples tracking its variations during chemical reactions. To do so we use laboratory petrophysical techniques such as helium porosimetry, gas permeability, centrifugue, electrical resistivity and sonic waves measurements to obtain the parameters that characterize flow within rock matrix (porosity, permeability, retention curve and pore size distribution, electrical conductivity, formation factor, cementation index and tortuosity) before and after percolation experiments. We built an experimental setup that allows injection of acid brine into core samples under well controlled conditions, monitor changes in hydrodynamic properties and obtain the chemical composition of the injected solution at different stages. 3D rock images were also acquired before and after the experiments using a micro-CT to locate the alteration processes and perform an acurate analysis of the structural changes. Two limestones with distinct textural classification and thus contrasting transport properties have been used in the laboratory experiments: a crinoid limestone and an oolithic limestone. Core samples dimensions were 1 inch in diameter and varied from 0.5 to 2 inches in length. Experiments were performed at room temperature, 8 bar of total pressure and 3 bar of PCO2. The acidic fluid has been injected at constant flow rate ranging from 0.4 mL/min to 6.7 mL/min depending of the rock typology and sample length. As expected, limestone dissolution occurred during the different percolation experiments, porosity and permeability augmented and sonic waves speed propagation decreased, showing an increase in the degree of heterogeneity of the rocks. The integration of all these parameters measured at different stages of dissolution provides contrasted and realistic geochemical, hydrodynamic and structural parameters to improve numerical simulations.

Summary of well construction, testing, and preliminary findings from the Alligator Alley test well, Broward County, Florida

USGS Publications Warehouse

Meyer, F.W.

1988-01-01

A 2,811-foot deep test well was drilled during 1980 in The Everglades along Alligator Alley as part of the Floridan Regional Aquifer Systems Analysis project. The well was cased 895 feet deep. Hydraulic packers were used to isolate selected zones in the open hole for water samples and measurement of water levels. The well penetrated the surficial and intermediate aquifers into the Floridan aquifer system. The top of the Floridan aquifer system occurs at 770 feet and includes limestone ranging in age from Oligocene to early Eocene. About 67 percent of the total thickness of the Floridan aquifer system was penetrated by the well. The chief water-producing zones in the Floridan aquifer system occur at about 1,030 feet and at about 2,560 feet. The 1,030-foot zone contains brackish artesian groundwater, and the 2,560-foot zone contains salty artesian groundwater similar in composition to seawater. The static water geothermal gradient is indicated, and radiocarbon activities suggest that the saltwater in the lower zone is younger than brackish groundwater in the upper zone. (USGS)

Testing and Development of a Percussive Augmenter for Rotary Drills

NASA Technical Reports Server (NTRS)

Donnelly, Christopher; Bar-Cohen, Yoseph; Chang, Zensheu; Badescu, Mircea; Sherrit, Stewart

2011-01-01

Hammering drills are effective in fracturing the drilled medium while rotary drills remove cuttings. The combination provides a highly effective penetration mechanism. Piezoelectric actuators were integrated into an adapter to produce ultrasonic percussion; augmenting rotary drilling. The drill is capable of operating at low power, low applied force and, with proper tuning, low noise. These characteristics are of great interest for future NASA missions and the construction/remodeling industry. The developed augmenter connects a commercially available drill and bit and was tested to demonstrate its capability. Input power to the drill was read using a multimeter and the augmenter received a separate input voltage. The drive frequency of the piezoelectric actuator was controlled by a hill climb algorithm that optimizes and records average power usage to operate the drill at resonating frequency. Testing the rotary drill and augmenter across a range of combinations with total power constant at 160 Watts has shown results in concrete and limestone samples that are as good as or better than the commercial drill. The drill rate was increased 1.5 to over 10 times when compared to rotation alone.

Diagenetic patterns and pore space distribution along a platform to outer-shelf transect (Urgonian limestone, Barremian-Aptian, SE France)

NASA Astrophysics Data System (ADS)

Léonide, Philippe; Fournier, François; Reijmer, John J. G.; Vonhof, Hubert; Borgomano, Jean; Dijk, Jurrien; Rosenthal, Maelle; van Goethem, Manon; Cochard, Jean; Meulenaars, Karlien

2014-06-01

The Urgonian limestones of Late Barremian/Early Aptian from Provence (SE, France) are characterized by the occurrence of microporous limestones at regional scale alternating with tight carbonates. This study, based on petrographical (sediment texture, facies) and diagenetical analyses (cement stratigraphy, porosity and isotope geochemistry) of more than 800 limestone samples provides insight into the parameters controlling the genesis, preservation or occlusion of microporosity along an inner platform to outer shelf transect. The tight and microporous Urgonian limestones from Provence can be grouped into 5 rock-types based on textures, associated depositional environments, porosity and pore-type, being: (1) tight inner-platform: TIP; (2) porous inner platform: PIP; (3) tight outer platform: TOP; (4) porous outer platform: POP and (5) tight outer shelf: TOS. In tight (TIP, TOP and TOS types) limestones intergranular and intragranular pore spaces were entirely occluded by early marine and/or early meteoric cementation, whereas in microporous (PIP, POP) limestones a significant fraction of the intergranular macroporosity was preserved during early and shallow burial diagenesis. Micrite neomorphism (hybrid Ostwald ripening process) occurred during meteoric shallow burial diagenesis in PIP and POP limestones during the regional Durancian Uplift event (Albian-Lower Cenomanian). This process resulted in microporosity enhancement and preservation. Circulation of meteoric fluids during exhumation produces intercrystalline microporosity enhancement and moldic porosity development. The present study documents the important role that both early diagenetic and depositional cycles and long-term tectonic processes have on pore space evolution and distribution in Mesozoic platform carbonates.

Ground-water exploration in Al Marj area, Cyrenaica, United Kingdom of Libya

USGS Publications Warehouse

Newport, T.G.; Haddor, Yousef

1963-01-01

The present report, based largely on fieldwork during 1959-61, describes the results of reconnaissance hydrogeologic studies and exploratory drilling to evaluate the general water-bearing properties of the rocks and the availability of groundwater supplies for irrigation, stock, and village uses in Al Marj area. These studies and the drilling were conducted under the auspices of the U.S. Operations Mission of the International Cooperation Administration. Al Marj area, located in the Province of Cyrenaica on the southern coast of the Mediterranean Sea, contains a land area of about 6,770 square kilometers. Along the Mediterranean shore is a narrow coastal plain that rises evenly to the base of an escarpment that forms the seaward front of an undulating plateau known as. Al Jabal al Akhgiar. The climate is semiarid; seasonal rainfall occurs during the winter months. Owing to orographic effects, the rainfall is somewhat higher in the Jabal than in the coastal plain. The average annual rainfall ranges from about 250 millimeters in the coastal plain to 450 millimeters on the Jabal. All the streams (wadis) of the area are ephemeral and flow only in response to heavy rains of the winter season. From a drainage divide on the Jabal some streams flow north and northwest toward the sea and the others, south and southeast to the interior desert. Solution features, such as limestone sink holes, are common in the coastal plain and a large solution depression occurs near Al Marj. The rocks of A1 Marj area consist predominantly of limestone and some sandstone and shale; they range from Cretaceous to Miocene age. On the coastal plain Miocene limestone is locally mantled by Quaternary alluvial, beach and lagoonal deposits. The Miocene and older beds have a regional southerly dip. These rocks are broken by northeast-trending normal faults in the coastal and inland escarpments. The ground-water reservoir is contained chiefly in fractures, bedding planes, and solution openings in the limestone country rock. The upper limit of this reservoir is marked by a water table which generally lies within 40 meters of the land surface in the coastal plain but is 100 meters or more below the surface of most of the Jabal and the interior desert. The ground-water reservoir is replenished chiefly by infiltration from surface-water runoff in wadis and to less extent by direct infiltration of rainfall. Ground water moves north and northwest toward the Mediterranean Sea and south toward the interior desert from a ground-water divide near the crest of A1 Jabal al Akhgiar. Discharge of ground water takes place by submarine outflow, spring flow, evapotranspiration, and withdrawals from wells. Wells, springs, and cisterns furnish almost all water supplies for municipal, village, stock and irrigation purposes. Bengasi, A1 Marj, and A1 Abyar are the only centers of population with municipal distribution systems. Drafts from individual dug wells used for irrigation in the coastal plain generally are no more than 10 to 15 cubic meters per day. In the Jabal and the interior desert drafts from individual stock and village wells are generally less than 10 cubic meters per day and from most wells only a few thousand liters per day. Some 21 test wells were put down during the present investigation to depths ranging from 30 to 309 meters. The yields obtained by test pump and bailer ranged from 45 to 0.6 cubic meters per hour. With few exceptions, well yields sufficient for stock and village requirements were obtained. Well yields sufficient for irrigation even on a moderate scale, however, are not everywhere available. In the Jabal and the interior desert the ground water is generally of good to fair chemical quality and suitable for most purposes. In the coastal plain, however, the ground water is in places moderately to highly mineralized, and consequently for irrigation use it must be applied to the land under optimum crop soil, and drainage conditions.

Limestone and chert in tectonic blocks from the Esk Head subterrane, South Island, New Zealand

USGS Publications Warehouse

Silberling, Norman J.; Nichols, K.M.; Bradshaw, J.D.; Blome, C.D.

1988-01-01

The Esk Head subterrane is a continuous belt, generally 10-20 km wide, of tectonic melange and broken formation on the South Island of New Zealand. This subterrane separates older and younger parts of the Torlesse terrane which is an extensive accretionary prism composed mostly of quartzo-feldspathic, submarine-fan deposits ranging from Permian to Early Cretaceous in age. The Esk Head subterrane of the Torlesse is especially informative because it includes within it conspicuous tectonic blocks of submarine basalt and a variety of basalt-associated seamount and sea-floor limestones and cherty rocks thought to be representative of the subducted plate. Paleogeographic inferences drawn from megafossils, bioclasts, and radiolarians, as well as from carbonate cements, indicate deposition of the oceanic sedimentary rocks at paleolatitudes somewhat lower than that of the New Zealand part of the Gondwana margin, but higher than paleoequatorial latitudes. -Authors

Geochemistry of Precambrian carbonates. IV - Early Paleoproterozoic (2.25 +/- 0.25 Ga) seawater

NASA Technical Reports Server (NTRS)

Veizer, Jan; Clayton, R. N.; Hinton, R. W.

1992-01-01

The mineralogy, chemistry, and isotopic composition of the Malmani Dolomite, Duck Creek Dolomite, and Bruce 'Limestone' Member of the Espanola Formation are studied in an effort to restrict the first- and second-order variations in isotopic composition of Early Paleoproterozoic seawater. The diagenetic rank is found to increase in the order Duck Creek less than Bruce less than Malmani. The interpolation of alteration trends to 'best' value yields an estimate of 0.70550 for Sr-87/Sr-86. For delta C-13, the measured range of 0 +/- 1.5 percent PDB is similar to that observed for Phanerozoic marine carbonates, while the 'best' delta O-18 value for dolostones is -5 percent PDB, depleted in O-18 relative to Phanerozoic counterparts but comparable to estimates obtained for Archean facies. The isotope geochemistry and mineralogy of Bruce 'Limestone' Member is consistent with the proposition that the sequence was deposited in a lacustrine environment.

Suggested nomenclature change and new reference locality for Dequeen Formation, Pike County, Arkansas

DOE Office of Scientific and Technical Information (OSTI.GOV)

Ham, T.L.; Landry, R.J.

1983-09-01

The DeQueen Formation of the Trinity Group, Comanchean Cretaceous, crops out in southwestern Arkansas and southeastern Oklahoma. The outcrop, located in the Highland gypsum quarry of Pike County, southwestern Arkansas, is described in detail in this paper and presented as a reference locality. Data from the locality provide the basis for a nomenclature change from the DeQueen Limestone Member to the DeQueen Formation. The formation consists of 64.23% clastic sediments, 24.72% gypsum, and 11.05% limestone. Hopper salt casts, ripple marks, scattered pyrite and marcasite nodules, celestite, and chickenwire gypsum can also be found. The DeQueen Formation is underlain by claysmore » and the Ultima Thule Gravel lentil, while the top is unconformably overlain by Upper Cretaceous Tokio gravels. The general paleoenvironment represents a normally low-energy subtidal environment ranging from brackish to normal to hypersaline waters in a lagoonal setting that shallows upward.« less

STEAM ENHANCED REMEDIATION RESEARCH FOR DNAPL IN FRACTURED ROCK, LORING AIR FORCE BASE, LIMESTONE, MAINE

EPA Science Inventory

This report details a research project on Steam Enhanced Remediation (SER) for the recovery of volatile organic compounds from fractured limestone that was carried out at the Quarry at the former Loring Air Force Base in Limestone, Maine. This project was carried out by USEPA, Ma...

OPTIMIZATION OF A PULSED LIMESTONE BED REACTOR AT THE ARGO TUNNEL IN IDAHO SPRINGS, COLORADO

EPA Science Inventory

Acid Mine Drainage (AMD) is an unintended consequence of coal and metal mining that adversely affects thousands of miles of streams both in the eastern and western regions of the U.S. A novel AMD treatment process based on limestone based on limestone neutralization has been dev...

Geologic framework and hydrogeologic characteristics of the Glen Rose limestone, Camp Stanley Storage Activity, Bexar County, Texas

USGS Publications Warehouse

Clark, Allan K.

2004-01-01

The Trinity aquifer is a regional water source in the Hill Country of south-central Texas that supplies water for agriculture, commercial, domestic, and stock purposes. Rocks of the Glen Rose Limestone, which compose the upper zone and upper part of the middle zone of the Trinity aquifer, crop out at the Camp Stanley Storage Activity (CSSA), a U.S. Army weapons and munitions supply, maintenance, and storage facility in northern Bexar County (San Antonio area) (fig. 1). On its northeastern, eastern, and southern boundaries, the CSSA abuts the Camp Bullis Training Site, a U.S. Army field training site for military and Federal government agencies. During 2003, the U.S. Geological Survey (USGS), in cooperation with the U.S. Army, studied the outcropping Glen Rose Limestone at the CSSA and immediately adjacent area (Camp Stanley study area, fig. 1) to identify and map the hydrogeologic subdivisions and faults of the Glen Rose Limestone at the facility. The results of the study are intended to help resource managers improve their understanding of the distribution of porosity and permeability of the outcropping rocks, and thus the conditions for recharge and the potential for contaminants to enter the Glen Rose Limestone. This study followed a similar study done by the USGS at Camp Bullis (Clark, 2003). The purpose of this report is to present the geologic framework and hydrogeologic characteristics of the Glen Rose Limestone in the study area. The hydrogeologic nomenclature follows that introduced by Clark (2003) for the outcropping Glen Rose Limestone at Camp Bullis in which the upper member of the Glen Rose Limestone (hereinafter, upper Glen Rose Limestone), which is coincident with the upper zone of the Trinity aquifer, is divided into five intervals on the basis of observed lithologic and hydrogeologic properties. An outcrop map, two generalized sections, related illustrations, and a table summarize the description of the framework and distribution of characteristics.

Modulus of elasticity, creep and shrinkage of concrete, phase II : part 1, creep study, final report.

DOT National Transportation Integrated Search

2009-10-01

A laboratory testing program was performed to evaluate the physical and mechanical properties of typical Class II, IV, V, and VI concrete mixtures made with a Miami Oolite limestone, a Georgia granite, and a lightweight aggregate Stalite, including c...

EXTERIOR OVERVIEW, LOOKING NORTH, OF THIS 400' DEEP LIMESTONE QUARRY ...

Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

EXTERIOR OVERVIEW, LOOKING NORTH, OF THIS 400' DEEP LIMESTONE QUARRY PIT ('THE OLD PIT') WITH LEDGE PREPARED FOR LIMESTONE EXTRACTION. AN ELEVEN-HOLE SHOT WILL DISLODGE APPROXIMATELY 25,000 TONS OF LIMESTONE WHICH, AFTER LOADING AND CRUSHING, WILL BE USED FOR ROAD CONSTRUCTION. THE CALERA QUARRY IS ONE OF FOUR ACTIVE VULCAN MATERIALS COMPANY QUARRIES IN THE DISTRICT. VULCAN MATERIALS, A FORTUNE 500 FIRM, ESTABLISHED IN BIRMINGHAM IN 1906 AS BIRMINGHAM SLAG COMPANY, VULCAN MATERIALS IS THE NATION'S FOREMOST PRODUCER OF CONSTRUCTION AGGREGATE AND A LEADING CHEMICALS MANUFACTURER. - Vulcan Material Company, Calera Quarry, 1614 Highway 84, Calera, Shelby County, AL

EXTERIOR OVERVIEW, LOOKING NORTH, OF THIS 400' DEEP LIMESTONE QUARRY ...

Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

EXTERIOR OVERVIEW, LOOKING NORTH, OF THIS 400' DEEP LIMESTONE QUARRY PIT ("THE OLD PIT") WITH LEDGE PREPARED FOR LIMESTONE EXTRACTION. AN ELEVEN-HOLE SHOT WILL DISLODGE APPROXIMATELY 25,000 TONS OF LIMESTONE WHICH, AFTER LOADING AND CRUSHING, WILL BE USED FOR ROAD CONSTRUCTION. THE CALERA QUARRY IS ONE OF FOUR ACTIVE VULCAN MATERIALS COMPANY QUARRIES IN THE DISTRICT. VULCAN MATERIALS, A FORTUNE 500 FIRM, ESTABLISHED IN BIRMINGHAM IN 1906 AS BIRMINGHAM SLAG COMPANY, VULCAN MATERIALS IS THE NATION'S FOREMOST PRODUCER OF CONSTRUCTION AGGREGATE AND A LEADING CHEMICALS MANUFACTURER - Vulcan Material Company, Calera Quarry, 1614 Highway 84, Calera, Shelby County, AL

ACOUSTICAL IMAGING AND MECHANICAL PROPERTIES OF SOFT ROCK AND MARINE SEDIMENTS

DOE Office of Scientific and Technical Information (OSTI.GOV)

Thurman E. Scott, Jr., Ph.D.; Younane Abousleiman, Ph.D.; Musharraf Zaman, Ph.D., P.E.

2001-07-01

Mechanically weak formations, such as chalks, high porosity sandstones, and marine sediments, pose significant problems for oil and gas operators. Problems such as compaction, subsidence, and loss of permeability can affect reservoir production operations. For example, the unexpected subsidence of the Ekofisk chalk in the North Sea required over one billion dollars to re-engineer production facilities to account for losses created during that compaction (Sulak 1991). Another problem in weak formations is that of shallow water flows (SWF). Deep water drilling operations sometimes encounter cases where the marine sediments, at shallow depths just below the seafloor, begin to uncontrollably flowmore » up and around the drill pipe. SWF problems created a loss of $150 million for the Ursa development project in the U.S. Gulf Coast SWF (Furlow 1998a,b; 1999a,b). The goal of this project is to provide a database on both the rock mechanical properties and the geophysical properties of weak rocks and sediments. These could be used by oil and gas companies to detect, evaluate, and alleviate potential production and drilling problems. The results will be useful in, for example, pre-drill detection of events such as SWF's by allowing a correlation of seismic data (such as hazard surveys) to rock mechanical properties. The data sets could also be useful for 4-D monitoring of the compaction and subsidence of an existing reservoir and imaging the zones of damage. During the second quarter of the project the research team has: (1) completed acoustic sensor construction, (2) conducted reconnaissance tests to map the deformational behaviors of the various rocks, (3) developed a sample assembly for the measurement of dynamic elastic and poroelastic parameters during triaxial testing, and (4) conducted a detailed review of the scientific literature and compiled a bibliography of that review. During the first quarter of the project the research team acquired several rock types for testing including: (a) Danian chalk, (b) Cordoba Cream limestone, (c) Indiana limestone, (d) Ekofisk chalk, (e) Oil Creek sandstone, (f) unconsolidated Oil Creek sand, and (g) unconsolidated Brazos river sand. During the second quarter experiments were begun on these rock types. A series of reconnaissance experiments have been carried out on all but the Ekofisk (for which there is a preliminary data set already inhouse). A series of triaxial tests have been conducted on the Danian chalk, the Cordoba Cream limestone, the Indiana limestone, and sand samples to make a preliminary determination of the deformational mechanisms present in these samples.« less

A 'Propagating' Active Across-Arc Normal Fault Shows Rupture Process of the Basement: the Case of the Southwestern Ryukyu Arc

NASA Astrophysics Data System (ADS)

Matsumoto, T.; Shinjo, R.; Nakamura, M.; Kubo, A.; Doi, A.; Tamanaha, S.

2011-12-01

Ryukyu Arc is located on the southwestern extension of Japanese Island-arc towards the east of Taiwan Island along the margin of the Asian continent off China. The island-arc forms an arcuate trench-arc-backarc system. A NW-ward subduction of the Philippine Sea Plate (PSP)at a rate of 6-8 cm/y relative to the Eurasian Plate (EP) causes frequent earthquakes. The PSP is subducting almost normally in the north-central area and more obliquely around the southwestern area. Behind the arc-trench system, the Okinawa Trough (OT) was formed by back-arc rifting, where active hydrothermal vent systems have been discovered. Several across-arc submarine faults are located in the central and southern Ryukyu Arc. The East Ishigaki Fault (EIF) is one of the across-arc normal faults located in the southwestern Ryukyu Arc, ranging by 44km and extending from SE to NW. This fault was surveyed by SEABAT8160 multibeam echo sounder and by ROV Hyper-Dolphin in 2005 and 2008. The result shows that the main fault consists of five fault segments. A branched segment from the main fault was also observed. The southernmost segment is most mature (oldest but still active) and the northernmost one is most nascent. This suggests the north-westward propagation of the fault rupture corresponding to the rifting of the southwestern OT and the southward retreat of the arc-trench system. Considering that the fault is segmented and in some part branched, propagation might take place episodically rather than continuously from SE to NW. The ROV survey also revealed the rupture process of the limestone basement along this fault from the nascent stage to the mature stage. Most of the rock samples collected from the basement outcrop were limestone blocks (or calcareous sedimentary rocks). Limestone basement was observed to the west on the hanging wall far away from the main fault scarp. Then fine-grained sand with ripple marks was observed towards the main scarp. Limestone basement was observed on the main scarp and on the footwall. These suggest that basically the both sides are composed of the same material, that the whole study area is characterised by Ryukyu limestone exposure and that the basement was split by the across-arc normal fault. Coarse-grained sand and gravels/rubbles were observed towards and on the trough of the fault. On the main scarp an outcrop of limestone basement was exposed and in some part it was broken into rubbles. These facts suggest that crash of the basement due to rupturing is taking place repeatedly on the scarp and the trough. The observed fine-grained sand on the hanging wall might be the final product by the process of the crash of the limestone basement.

Long-Term Effectiveness, under a Mountain Environment, of a Novel Conservation Nanomaterial Applied on Limestone from a Roman Archaeological Site.

PubMed

Elhaddad, Farid; Carrascosa, Luis A M; Mosquera, Maria J

2018-04-28

A novel alkoxysilane-based product was applied on limestone samples from a Roman archaeological site. The study consisted of an initial phase to evaluate site environmental conditions in order to choose the most suitable product type to be applied. The decay that was produced in the site is mainly caused by natural action, with water being the main vehicle for the decay agents. Thus, the effectiveness of an innovative product with hydrophobic/consolidant properties and two commercial products (consolidant and hydrophobic agent) were evaluated on limestone from Acinipo site, under laboratory conditions. Next, the long-term effectiveness of the three products under study was evaluated by the exposure of limestone samples in the archaeological site for a period of three years. Since the recognized incompatibility between alkoxysilanes and pure carbonate stones, the interaction between the products and the limestones was widely investigated. The results that were obtained allow for it to be concluded that the innovative product presents adequate compatibility and adherence to the limestone under study, producing a long-term effective, homogeneous, and continuous coating with a depth of penetration of up to 10 mm. However, the commercial products produced discontinuous aggregates on the limestone surface, did not penetrate into its porous structure and it did not produce long-lasting effects.

A Metagenomic Survey of Limestone Hill in Taiwan

NASA Astrophysics Data System (ADS)

Hsu, Y. W.; Li, K. Y.; Chen, Y. W.; Huang, T. Y.; Chen, W. J.; Shih, Y. J.; Chen, J. S.; Fan, C. W.; Hsu, B. M.

2016-12-01

The limestone of Narro-Sky in Tainliao, Taiwan is of Pleistocene reef limestones interbedded in clastic layers that covered the Takangshan anticlines. Understanding how microbial relative abundance was changed in response to changes of environmental factors may contribute to better comprehension of roles that microorganisms play in altering the landscape structures. In this study, microorganisms growing on the wall of limestone, in the water dripping from the limestone wall and of soil underneath the wall were collected from different locations where the environmental factors such as daytime illumination, humidity, or pH are different. Next generation sequencing (NGS) was carried out to examine the compositions and richness of microbial community. The metagenomics were clustered into operational taxonomic units (OTUs) to analyze relative abundance, diversities and principal coordinates analysis (PCoA). Our results showed the soil sample has the highest alpha diversity while water sample has the lowest. Four major phyla, which are Proteobacteria, Acidobacteria, Actinobacteria, and Cyanobacteria, account for 80 % of total microbial biomass in all groups. Cyanobacteria were found most abundantly in limestone wall instead of water or soil of weathering limestone. The PCoA dimensional patterns of each phylum showed a trace of microbial community dynamic changes, which might be affected by environmental factors. This study provides the insights to understand how environmental factors worked together with microbial community to shape landscape structures.

Evaluation of steel slag coarse aggregate in hot mix asphalt concrete.

PubMed

Ahmedzade, Perviz; Sengoz, Burak

2009-06-15

This paper presents the influences of the utilization of steel slag as a coarse aggregate on the properties of hot mix asphalt. Four different asphalt mixtures containing two types of asphalt cement (AC-5; AC-10) and coarse aggregate (limestone; steel slag) were used to prepare Marshall specimens and to determine optimum bitumen content. Mechanical characteristics of all mixtures were evaluated by Marshall stability, indirect tensile stiffness modulus, creep stiffness, and indirect tensile strength tests. The electrical sensitivity of the specimens were also investigated in accordance with ASTM D257-91. It was observed that steel slag used as a coarse aggregate improved the mechanical properties of asphalt mixtures. Moreover, volume resistivity values demonstrated that the electrical conductivity of steel slag mixtures were better than that of limestone mixtures.

Integrated Assessment of Vegetation and Soil Conditions Following Herbicide Application

DTIC Science & Technology

2017-07-25

41. The white suspension formed when mixing Remedy Ultra (RU) with water...or shallow soil to a petrocalcic horizon. Soils are well drained and form in loamy calcareous gravelly alluvium. Typical locations for Cho soil are...drained soils. Nuff soil is formed in interbedded marl, limestone, and shale with slopes ranging between 1 and 6%. This soil is formed on erosional

Distribution and character of upper mesozoic subduction complexes along the west coast of North America

USGS Publications Warehouse

Jones, D.L.; Blake, M.C.; Bailey, E.H.; McLaughlin, R.J.

1978-01-01

Structurally complex sequences of sedimentary, volcanic, and intrusive igneous rocks characterize a nearly continuous narrow band along the Pacific coast of North America from Baja California, Mexico to southern Alaska. They occur in two modes: (1) as complexly folded but coherent sequences of graywacke and argillite that locally exhibit blueschist-grade metamorphism, and (2) as melanges containing large blocks of graywacke, chert, volcanic and plutonic rocks, high-grade schist, and limestone in a highly sheared pelitic, cherty, or sandstone matrix. Fossils from the coherent graywacke sequences range in age from late Jurassic to Eocene; fossils from limestone blocks in the melanges range in age from mid-Paleozoic to middle Cretaceous. Fossils from the matrix surrounding the blocks, however, are of Jurassic, Cretaceous, and rarely, Tertiary age, indicating that fossils from the blocks cannot be used to date the time of formation of the melanges. Both the deformation of the graywacke, with accompanying blueschist metamorphism, as well as the formation of the melanges, are believed to be the result of late Mesozoic and early Tertiary subduction. The origin of the melanges, particularly the emplacement of exotic tectonic blocks, is not understood. ?? 1978.

Performance of portland limestone cements : cements designed to be more sustainable that include up to 15% limestone addition.

DOT National Transportation Integrated Search

2013-11-01

In 2009, ASTM and AASHTO permitted the use of up to 5% interground limestone in ordinary portland cement (OPC) as a part of ASTM : C150/AASHTO M85. When this project was initiated a new proposal was being discussed that would enable up to 15% intergr...

Diagenetic comparisons between non-tropical Cenozoic limestones of New Zealand and tropical Mississippian limestones from Indiana, USA: Is the non-tropical model better than the tropical model?

NASA Astrophysics Data System (ADS)

Dodd, J. Robert; Nelson, Campbell S.

1998-10-01

Mississippian limestones exposed in Indiana, U.S.A., were deposited in a shallow tropical ocean. However, many properties of these limestones are more like those of modern and Cenozoic non-tropical limestones such as those found in New Zealand. The dominant skeletal grains in the Indiana limestones are calcitic echinoderms, bryozoans, and brachiopods. The dominant skeletal grains in most Cenozoic limestones of New Zealand are calcitic bryozoans, echinoderms, bivalve molluscs, and foraminifera. In contrast, modern and Cenozoic tropical limestones contain an abundance of aragonitic green algae, corals, and molluscs. Early in diagenesis the metastable aragonite dissolves and reprecipitates as calcite, causing early cementation of the sediments. Originally aragonitic fossils that have dissolved can be identified as molds that are commonly filled with secondary calcite. Because they contained little aragonite, most of the Indiana and New Zealand limestones did not have an abundant source of early cement. Except for local cases in which grains were cemented in contact with carbonate supersaturated seawater, grainstones were relatively deeply buried with little cement between the grains. This resulted in mechanical and chemical compaction of skeletal grains, producing a `fitted fabric' with greatly reduced pore space, either open or filled with cement between the grains. Cement in these aragonite-poor grainstones comes largely from pressure dissolution between grains and along stylolitic seams in the rock, features that are common only after burial beyond a few hundred meters. The final product of deeply buried (up to 2000 m) Cenozoic New Zealand grainstones is similar to the Mississippian grainstones of Indiana. In the Indiana limestones we have only the final product of this extensive burial diagenesis. However, the New Zealand sediments and rocks reveal all steps of formation of the final deeply buried limestone. The reason for the scarcity of originally aragonitic fossil grains in Paleozoic rocks worldwide is unknown. Organisms with aragonitic skeletons such as some molluscan groups and calcareous green algae were present, but seldom in much abundance. The aragonitic scleractinian corals had not yet evolved. Previous researchers have noted that non-skeletal precipitates such as ooids and cements have at times during the Paleozoic been predominantly aragonite and at other times calcite. They have attributed this difference to secular variation in seawater chemistry (icehouse vs. greenhouse seas). Abundance of aragonitic and calcitic skeletal grains does not follow this pattern.

Effect of limestone particle size and calcium to non-phytate phosphorus ratio on true ileal calcium digestibility of limestone for broiler chickens.

PubMed

Anwar, M N; Ravindran, V; Morel, P C H; Ravindran, G; Cowieson, A J

2016-10-01

The purpose of this study was to determine the effect of limestone particle size and calcium (Ca) to non-phytate phosphorus (P) ratio on the true ileal Ca digestibility of limestone for broiler chickens. A limestone sample was passed through a set of sieves and separated into fine (<0.5 mm) and coarse (1-2 mm) particles. The analysed Ca concentration of both particle sizes was similar (420 g/kg). Six experimental diets were developed using each particle size with Ca:non-phytate P ratios of 1.5:1, 2.0:1 and 2.5:1, with ratios being adjusted by manipulating the dietary Ca concentrations. A Ca-free diet was also developed to determine the basal ileal endogenous Ca losses. Titanium dioxide (3 g/kg) was incorporated in all diets as an indigestible marker. Each experimental diet was randomly allotted to 6 replicate cages (8 birds per cage) and fed from d 21 to 24 post hatch. Apparent ileal digestibility of Ca was calculated using the indicator method and corrected for basal endogenous losses to determine the true Ca digestibility. The basal ileal endogenous Ca losses were determined to be 127 mg/kg of dry matter intake. Increasing Ca:non-phytate P ratios reduced the true Ca digestibility of limestone. The true Ca digestibility coefficients of limestone with Ca:non-phytate P ratios of 1.5, 2.0 and 2.5 were 0.65, 0.57 and 0.49, respectively. Particle size of limestone had a marked effect on the Ca digestibility, with the digestibility being higher in coarse particles (0.71 vs. 0.43).

Paleocene orthophragminids from the Lakadong Limestone, Mawmluh Quarry section, Meghalaya (Shillong, NE India): implications for the regional geology and paleobiogeography

NASA Astrophysics Data System (ADS)

Özcan, Ercan; Pignatti, Johannes; Pereira, Christer; Osman Yücel, Ali; Drobne, Katica; Barattolo, Filippo; Saraswati, Pratul Kumar

2018-04-01

The late Paleocene orthophragminids, hitherto poorly known from the Himalayan foreland basins, are studied from the Lakadong Limestone in Meghalaya, northeastern India, in order to establish a systematic, biostratigraphic, and paleobiogeographical framework for them in the eastern Tethys. In the Mawmluh Quarry section (MQS) on the Shillong Plateau, to the southeast of Tibet, orthophragminids are associated with typical Paleocene orbitoidiform taxa endemic to the Indian subcontinent, i.e., Lakadongia Matsumaru & Jauhri ( = Setia Ferràndez-Cañadell) and Orbitosiphon Rao, and various species of alveolinids, miscellaneids, and rotaliids, characterizing the Shallow Benthic Zones (SBZ) 3 and 4. The orthophragminids belong to two lineages of the genus Orbitoclypeus Silvestri: O. schopeni (Checchia-Rispoli) and O. multiplicatus (Gümbel), both well known from the peri-Mediterranean region and Europe (western Tethys). The latter species is identified here for the first time from the eastern Tethys. Previous records of the genus Discocyclina Gümbel from the Lakadong Limestone actually correspond to misidentified Orbitoclypeus; this implies that the late Paleocene orthophragminid assemblages from Meghalaya and eastern Tethys were less diverse than in the western Tethys. The lineage of Orbitoclypeus schopeni in the lower part of the Lakadong Limestone (SBZ 3) is identified as O. schopeni cf. ramaraoi based on the morphometry of a few specimens, whereas in the upper part (SBZ 4) it corresponds to a transitional development stage between O. schopeni ramaraoi and O. schopeni neumannae (with average Dmean values ranging between 192 and 199 µm). The embryon diameters of O. multiplicatus, recorded only in SBZ 4, range between 300 and 319 µm on average, corresponding to transitional development stages of O. multiplicatus haymanaensis and O. multiplicatus multiplicatus. Our data, along with a review of previous Paleocene and Eocene records from India and Pakistan, suggest that Orbitoclypeus is the only orthophragminid in the Paleocene of the eastern Tethys, whereas Discocyclina first appears in early Eocene times, being mainly represented by endemic taxa confined to the Indian subcontinent. Facies change in the MQS from a marine to continental setting within SBZ 4 corresponds to the oldest record from the Indian plate in the Paleogene, which may be linked to the flexural uplift of the passive margin of the Indian plate, marking the onset of the collision of the Indian and Eurasian plates.

Combined Neutron and X-Ray Radiographic/Tomographic Analysis of Dissolution Limestones under Acidic Conditions

NASA Astrophysics Data System (ADS)

Anovitz, L. M.; Cole, D. R.; Hussey, D. S.; LaManna, J.; Swift, A.; Jacobson, D. L.

2016-12-01

Carbon dioxide capture and sequestration in deep geological formations is an important option for reducing greenhouse gas emissions. While the importance of porosity and pore-evolution has long been recognized, the evolution of porosity and permeability in reactive carbonates exposed to CO2-loaded brines is not well constrained. A typical pH range for CO2-acidified brine is 3 to 4.5 depending on alkalinity. This represents a substantial perturbation of typical brines that range from pH 6 to 8. The key questions include how accessible are the pores to fluid transport and how does the pore network evolve as the matrix reacts with the acidic solution? Limestones and dolostones contain nano- to macroscale porosity comprised of cracks, grain boundaries, fluid inclusions, single pores, vugs and networks of pores of random shapes and orientations. Accessible, interconnected pores may act as pore throats, constraining overall flow and are the most likely locations for extensive rock alteration. Neutron imaging is well suited to interrogation of fluid flow in porous media. Because of the large scattering cross section of hydrogen it can be used to directly image water or hydrocarbons without an added contrast medium that might modify interfacial tension and fluid/fluid interactions. In order to understand the reaction of acidified fluids we used simultaneous neutron and X-ray tomography to study the uptake and reaction of water and an acidic fluid (pH 1 HCl) with two types of Indiana limestone, one with a permeability of 2-4 mD, and the other 70 mD. One set of experiments explored capillary uptake in a dry core. These documented rapid uptake and CO2 bubble formation at the inlet. A second set introduced at a constant forced flow rate of 10 ml/min. Both core types exhibited wormhole formation, but the low perm limestone wormhole consisted of one well-delineated channel with a few side "tributaries," whereas the high perm core exhibited a more diffuse array of channels. Post-flow neutron and X-ray tomography showed that grain boundaries and other initial parts of the porous network play an important role in controlling the dissolution process. Neutron radiography and tomography have the potential to significantly advance our understanding of fluid flow and reactive behavior relevant to a wide variety of subsurface applications.

Le domaine Tariquide (arc de Gibraltar, Espagne et Maroc) : succession et hiatus de la sédimentation du Jurassique supérieur au Paléocène

NASA Astrophysics Data System (ADS)

Durand-Delga, Michel; Esteras, Manuel; Gardin, Silvia; Paquet, Hélène

2005-07-01

The originality of the Malm-Cretaceous series of the Tariquides (Gibraltar arc), as compared to those of the Rifian-Betic 'Dorsale' (Alboran domain), and especially with the Penibetic (Iberia) domain, is emphasized. In the Los Pastores Group, near Algeciras, Upper Tithonian nodular limestones directly lie on the Dogger and are followed by Aptychus-bearing limestones (Late Berriasian to Barremian). In the Musa Group, Rif, radiolarites are followed by siliceous limestones (Kimmeridgian-Tithonian), then by karst and massflow breccias connected to a Berriasian tectonics, by Aptychus-bearing marly limestones, then by karst filled by Turonian limestones, and finally by Maastrichtian-Palaeocene polychrome pelites, whose micropalaeontological and mineral compositions (clay minerals, Fe sbnd Mn nodules) refer to a deep-sea, probably infra-CCD, sedimentation. To cite this article: M. Durand-Delga et al., C. R. Geoscience 337 (2005).

Geological mapping and analysis in determining resource recitivity limestone rocks in the village of Mersip and surrounding areas, district Limun, Sorolangun Regency, Jambi Province

NASA Astrophysics Data System (ADS)

Dona, Obie Mario; Ibrahim, Eddy; Susilo, Budhi Kuswan

2017-11-01

The research objective is to describe potential, to analyze the quality and quantity of limestone, and to know the limit distribution of rocks based on the value of resistivity, the pattern of distribution of rocks by drilling, the influence mineral growing on rock against resistivity values, the model deposition of limestone based on the value resistivity of rock and drilling, and the comparison between the interpretation resistivity values based on petrographic studies by drilling. Geologic Formations study area consists of assays consisting of altered sandstone, phyllite, slate, siltstone, grewake, and inset limestone. Local quartz sandstone, schist, genealogy, which is Member of Mersip Stylists Formation, consists of limestone that formed in shallow seas. Stylists Formation consists of slate, shale, siltstone and sandstone. This research methodology is quantitative using experimental observation by survey. This type of research methodology by its nature is descriptive analysis.

PREVENTION OF ELEMENTAL MERCURY REEMISSIONS FROM ILLINOIS COAL WET SCRUBBERS

EPA Science Inventory

This research conducted pilot plant tests to investigate techniques for controlling and reducing Hg⁰ re-emissions. A pilot-scale (0.01MW) wet scrubber was designed to simulate the wet limestone flue gas desulfurization system. Hg⁰ re-emissions, manifested by...

Damage characteristics and thermo-physical properties changes of limestone and sandstone during thermal treatment from -30 °C to 1000 °C

NASA Astrophysics Data System (ADS)

Shen, Yanjun; Yang, Yang; Yang, Gengshe; Hou, Xin; Ye, Wanjun; You, Zhemin; Xi, Jiami

2018-05-01

A series of experiments were carried out to measure the damage characteristics of two common sedimentary rocks of limestone and sandstone at temperatures ranging from -30 °C to 1000 °C The apparent thermal conductivity, thermal diffusivity and specific heat capacity were investigated respectively. Then, several discrepancy reasons for the damage characteristics and thermo-physical properties of limestone and sandstone were probed. The results show that water migration and phase transition are two core factors for the frost damage and thermal behaviors improvement during the cooling process(20 °C → -30 °C).The heating process (20 °C → 1000 °C) was divided into three stages of 20 °C → 200 °C, 200 °C → 600 °Cand 600 °C → 1000 °C. The first stage was closely related to pore-water evaporation, and the next two stages were attributed to the thermal reactions of mineral partials. The mineral decomposition tended to be intensified and resulted in the interior damage or even the accelerated degradation of thermal properties until at a threshold temperature of 600 °C. In essential, the structural features and the sensitivity of mineral composition to temperature were two mainly influential factors on the damage effects and heat conduct of the sedimentary rocks during variations in environmental temperature.

Study of Upper Miocene Oysters(Plecypoda) From the Mishan Formation in south west of Firuzabad, Fars, Iran(Zagros mountain)

NASA Astrophysics Data System (ADS)

Dehbozorgi, Mehdi; Sabouhi, Mostafa; Nabavi, Hamid

2010-05-01

The out crapes of Mishan Formation located in Aghar area(Firuzabad city) south west of Fars and 70km south west of Firuzabad. this Formation mostly consist of limestone, marly limestone and marlstone with 800m thickness. 6key beds distinctive from limestone beds are recognized in this area. this key beds are useful for local and regional correlation in Zagros mountains. the key beds from base to top are: Red algae, Bryozoa, Gastropoda and Plecypoda, Crabs and Oysters. Mishan Formation in this area is between Gachsaran F.M(Under Formation), Conformable and Aghajari F.M(Upper Formation), Conformable. With due attention to rang and distribution of the Macrofossils, 5 local assmblage biozone were recognized, that is confirming time limit from Early- Upper Miocene. this research cheked and controled a biostrom Plecypoda(Oysters) level by thickness 3- 4m. this biostrom located around 550m the base of section. Ofcurse more of this Plecypoda be assinged to order pterriodia and Genus Oyster. Along with Oysters, Pecten and Venus can be see. This biostrom made up a bioclastic shoal shallow deep in the margin of sea Miocene. This Oysters report from Mishan Formation of Firuzabad, Fars, Zagros, Iran: Ostrea virleti var. crassicostat, Ostrea virleti Desh var. persica, Ostrea digitatai Echiwald var. rohlfsi, Ostrea lamellose. Ostrea cf. biowwondeli. Master of science in Geology (Paleontology), University of Isfahan, Iran.

Limestone percussion tools from the late Early Pleistocene sites of Barranco León and Fuente Nueva 3 (Orce, Spain).

PubMed

Barsky, Deborah; Vergès, Josep-María; Sala, Robert; Menéndez, Leticia; Toro-Moyano, Isidro

2015-11-19

In recent years, there is growing interest in the study of percussion scars and breakage patterns on hammerstones, cores and tools from Oldowan African and Eurasian lithic assemblages. Oldowan stone toolkits generally contain abundant small-sized flakes and their corresponding cores, and are characterized by their structural dichotomy of heavy- and light-duty tools. This paper explores the significance of the lesser known heavy-duty tool component, providing data from the late Lower Pleistocene sites of Barranco León and Fuente Nueva 3 (Orce, Spain), dated 1.4-1.2 Myr. Using quantitative and qualitative data from the large-sized limestone industries from these two major sites, we present a new methodology highlighting their morpho-technological features. In the light of the results, we discuss the shortfalls of extant classificatory methods for interpreting the role of percussive technology in early toolkits. This work is rooted in an experimental program designed to reproduce the wide range of percussion marks observed on the limestone artefacts from these two sites. A visual and descriptive reference is provided as an interpretative aid for future comparative research. Further experiments using a variety of materials and gestures are still needed before the elusive traces yield the secrets of the kinds of percussive activities carried out by hominins at these, and other, Oldowan sites. © 2015 The Author(s).

Limestone percussion tools from the late Early Pleistocene sites of Barranco León and Fuente Nueva 3 (Orce, Spain)

PubMed Central

Barsky, Deborah; Vergès, Josep-María; Sala, Robert; Menéndez, Leticia; Toro-Moyano, Isidro

2015-01-01

In recent years, there is growing interest in the study of percussion scars and breakage patterns on hammerstones, cores and tools from Oldowan African and Eurasian lithic assemblages. Oldowan stone toolkits generally contain abundant small-sized flakes and their corresponding cores, and are characterized by their structural dichotomy of heavy- and light-duty tools. This paper explores the significance of the lesser known heavy-duty tool component, providing data from the late Lower Pleistocene sites of Barranco León and Fuente Nueva 3 (Orce, Spain), dated 1.4–1.2 Myr. Using quantitative and qualitative data from the large-sized limestone industries from these two major sites, we present a new methodology highlighting their morpho-technological features. In the light of the results, we discuss the shortfalls of extant classificatory methods for interpreting the role of percussive technology in early toolkits. This work is rooted in an experimental program designed to reproduce the wide range of percussion marks observed on the limestone artefacts from these two sites. A visual and descriptive reference is provided as an interpretative aid for future comparative research. Further experiments using a variety of materials and gestures are still needed before the elusive traces yield the secrets of the kinds of percussive activities carried out by hominins at these, and other, Oldowan sites. PMID:26483530

Transport and retention of engineered Al2O3, TiO2, and SiO2 nanoparticles through various sedimentary rocks.

PubMed

Bayat, Ali Esfandyari; Junin, Radzuan; Shamshirband, Shahaboddin; Chong, Wen Tong

2015-09-16

Engineered aluminum oxide (Al2O3), titanium dioxide (TiO2), and silicon dioxide (SiO2) nanoparticles (NPs) are utilized in a broad range of applications; causing noticeable quantities of these materials to be released into the environment. Issues of how and where these particles are distributed into the subsurface aquatic environment remain as major challenges for those in environmental engineering. In this study, transport and retention of Al2O3, TiO2, and SiO2 NPs through various saturated porous media were investigated. Vertical columns were packed with quartz-sand, limestone, and dolomite grains. The NPs were introduced as a pulse suspended in aqueous solutions and breakthrough curves in the column outlet were generated using an ultraviolet-visible spectrophotometer. It was found that Al2O3 and TiO2 NPs are easily transported through limestone and dolomite porous media whereas NPs recoveries were achieved two times higher than those found in the quartz-sand. The highest and lowest SiO2-NPs recoveries were also achieved from the quartz-sand and limestone columns, respectively. The experimental results closely replicated the general trends predicted by the filtration and DLVO calculations. Overall, NPs mobility through a porous medium was found to be strongly dependent on NP surface charge, NP suspension stability against deposition, and porous medium surface charge and roughness.

Geochemical evidence of Saharan dust parent material for soils developed on Quaternary limestones of Caribbean and western Atlantic islands

USGS Publications Warehouse

Muhs, D.R.; Bush, C.A.; Stewart, K.C.; Rowland, T.R.; Crittenden, R.C.

1990-01-01

Most previous workers have regarded the insoluble residues of high-purity Quaternary limestones (coral reefs and oolites) as the most important parent material for well-developed, clay-rich soils on Caribbean and western Atlantic islands, but this genetic mechanism requires unreasonable amounts of limestone solution in Quaternary time. Other possible parent materials from external sources are volcanic ash from the Lesser Antilles island arc and Saharan dust carried across the Atlantic Ocean on the northeast trade winds. Soils on Quaternary coral terraces and carbonate eolianites on Barbados, Jamaica, the Florida Keys (United States), and New Providence Island (Bahamas) were studied to determine which, if either, external source was important. Caribbean volcanic ashes and Saharan dust can be clearly distinguished using ratios of relatively immobile elements ( Al2O3 TiO2, Ti Y, Ti Zr, and Ti Th). Comparison of these ratios in 25 soils, where estimated ages range from 125,000 to about 870,000 yr, shows that Saharan dust is the most important parent material for soils on all islands. These results indicate that the northeast trade winds have been an important component of the regional climatology for much of the Quaterary. Saharan dust may also be an important parent material for Caribbean island bauxites of much greater age. ?? 1990.

Trace metal distribution and control in the pilot-scale bubbling fluidized bed combustor equipped with the pulse-jet fabric filter, limestone injection, and the humidification reactor.

PubMed

Kouvo, Petri

2003-04-01

This work focused on trace metal behavior and removal in a fabric filter or in a humidification reactor during the cofiring of sawdust and refuse-derived fuels (RDFs) in a pilot-scale bubbling fluidized bed (BFB) boiler. Trace metal emissions measurements before and after the fabric filter revealed that removal efficiency in the fabric filter was in the range of 80-100%, and that the European Union (EU) Directive on Incineration of Waste restrictions for trace metal emissions are easily achieved even if addition of RDFs substantially increases the concentration of trace metals in fuel blends. Limestone injection enhanced the removal of As and Se but had no noticeable effect on the removal of other trace metals. Extensive formation of HgCl2 and condensation on fly ash particles during sawdust plus 40% RDF cofiring resulted in a 92% Hg removal efficiency in the fabric filter. Limestone injection had no effect on the Hg removal in the fabric filter but decreased the Hg removal in a humidification reactor from 40 to 28%. Results of the bed material and fly ash analysis suggested capture of Cu, Pb, Mn, Ni, and Zn in the bed material but also suggested that these metals may be released from the bed if the fuel characteristics or process conditions are changed.

Calculation of the rockwall recession rate of a limestone cliff, affected by rockfalls, using cosmogenic chlorine-36. Case study of the Montsec Range (Eastern Pyrenees, Spain)

NASA Astrophysics Data System (ADS)

Domènech, Guillem; Corominas, Jordi; Mavrouli, Olga; Merchel, Silke; Abellán, Antonio; Pavetich, Stefan; Rugel, Georg

2018-04-01

Cliff erosion may be a major problem in settled areas affecting populations and producing economic and ecological losses. In this paper we present a procedure to calculate the long-term retreat rate of a cliff affected by rockfalls in the Montsec Range, Eastern Pyrenees (Spain). It is composed of low, densely fractured limestones; and the rockwall is affected by rockfalls of different sizes. The rockfall scars are clearly distinguishable by their regular boundaries and by their orange colour, which contrast with the greyish old reference surface (S0) of the cliff face. We have dated different stepped surfaces of the rockwall, including S0, using cosmogenic 36Cl. The total amount of material released by rockfall activity was calculated using a high definition point cloud of the slope face obtained with a terrestrial laser scanner (TLS). The present rockwall surface has been subtracted from the reconstructed old cliff surface. This has allowed the calculation of the total volume released by rockfalls and of the retreat rate. The latter ranges from 0.31 to 0.37 mm·a- 1. This value is of the same order of magnitude as that obtained by other researchers in neighbouring regions in Spain, having similar geology and affected by rockfalls.

Characterization of Limestone as Raw Material to Hydrated Lime

NASA Astrophysics Data System (ADS)

Salem Hwidi, Rajeb; Nuraiti Tengku Izhar, Tengku; Saad, Farah Naemah Mohd

2018-03-01

In Malaysia, limestone is essentially important for the economic growth as raw materials in the industry sector. Nevertheless, a little attention was paid to the physical, chemical, mineralogical, and morphological properties of the limestone using X-ray fluorescence (X-RF), X-ray diffraction (X-RD), Fourier transform infrared spectroscopy (FTIR), and Scanning electron microscopy / energy dispersive x-ray spectroscopy (SEM-EDS) respectively. Raw materials (limestone rocks) were collected from Bukit Keteri area, Chuping, Kangar, Perlis, Malaysia. Lab crusher and lab sieved were utilized to prepare five different size of ground limestone at (75 µm, 150 µm, 225 µm, 300, and 425 µm) respectively. It is found that the main chemical composition of bulk limestone was Calcium oxide (CaO) at 97.58 wt.% and trace amount of MnO, Al2O3, and Fe2O3 at 0.02%, 0.35%, and 0.396% respectively. XRD diffractograms showed characteristic peaks of calcite and quartz. Furthermore, main FTIR absorption bands at 1,419, 874.08 and 712.20 cm-1 indicated the presence of calcite. The micrographs showed clearly the difference of samples particle size. Furthermore, EDS peaks of Ca, O, and C elements confirmed the presence of CaCO3 in the samples.

Passive bioremediation technology incorporating lignocellulosic spent mushroom compost and limestone for metal- and sulfate-rich acid mine drainage.

PubMed

Muhammad, Siti Nurjaliah; Kusin, Faradiella Mohd; Md Zahar, Mohd Syakirin; Mohamat Yusuff, Ferdaus; Halimoon, Normala

2017-08-01

Passive bioremediation of metal- and sulfate-containing acid mine drainage (AMD) has been investigated in a batch study. Multiple substrates were used in the AMD remediation using spent mushroom compost (SMC), limestone, activated sludge (AS), and woodchips (WC) under anoxic conditions suitable for bacterial sulfate reduction (BSR). Limestones used were of crushed limestone (CLS) and uncrushed limestone, provided at two different ratios in mixed substrates treatment and varied by the proportion of SMC and limestone. The SMC greatly assisted the removals of sulfate and metals and also acted as an essential carbon source for BSR. The mixed substrate composed of 40% CLS, 30% SMC, 20% AS, and 10% WC was found to be effective for metal removal. Mn, Cu, Pb, and Zn were greatly removed (89-100%) in the mixed substrates treatment, while Fe was only removed at 65%. Mn was found to be removed at a greatly higher rate than Fe, suggesting important Mn adsorption onto organic materials, that is, greater sorption affinity to the SMC. Complementary with multiple treatment media was the main mechanism assisting the AMD treatment through microbial metal reduction reactions.

Effect of limestone reactivity and percent on production by dairy cows in early lactation.

PubMed

Nocek, J E; Braund, D G; English, J E

1983-12-01

Seventy-two Holstein cows (16 first lactation) were assigned to four treatments: A) normal-grind limestone (800 to 1000 mu) added to provide .77% calcium (total ration dry basis); B) fine-grind limestone (less than 150 mu) at .77% calcium; C) normal-grind at 1.15% calcium; and D) fine-grind limestone at 1.15% calcium. Cows fed diets containing .77% calcium had higher percent milk fat and fat yield than those fed 1.15% calcium diets, and cows fed fine-grind limestone had greater percent fat and fat yield than those fed normal-grind limestone. Four percent fat-corrected milk was higher for cows fed .77% calcium diets. Trends were similar for heifers in first lactation. Dry matter intake was higher for cows fed .77% calcium diets, and nutrient efficiency for milk synthesis favored cows fed fine-grind 1.15% calcium. Fecal pH was higher during wk 4 on treatment for cows fed high calcium diets; however, 8 wk were not different. Fecal starch and calcium and phosphorus in plasma were not different between treatments: however, heifers fed fine-grind 1.15% calcium showed a decrease of fecal starch with time.

Geologic controls on cave development in Burnsville Cove, Bath and Highland Counties, Virginia

USGS Publications Warehouse

Swezey, Christopher; Haynes, John T.; Lucas, Philip C.; Lambert, Richard A.

2017-01-01

Burnsville Cove in Bath and Highland Counties (Virginia, USA) is a karst region in the Valley and Ridge Province of the Appalachian Mountains. The region contains many caves in Silurian to Devonian limestone, and is well suited for examining geologic controls on cave location and cave passage morphology. In Burnsville Cove, many caves are located preferentially near the axes of synclines and anticlines. For example, Butler Cave is an elongate cave where the trunk channel follows the axis of Sinking Creek syncline and most of the side passages follow joints at right angles to the syncline axis. In contrast, the Water Sinks Subway Cave, Owl Cave, and Helictite Cave have abundant maze patterns, and are located near the axis of Chestnut Ridge anticline. The maze patterns may be related to fact that the anticline axis is the site of the greatest amount of flexure, leading to more joints and (or) greater enlargement of joints. Many of the larger caves of Burnsville Cove (e.g., Breathing Cave, Butler Cave–Sinking Creek Cave System, lower parts of the Water Sinks Cave System) are developed in the Silurian Tonoloway Limestone, the stratigraphic unit with the greatest surface exposure in the area. Other caves are developed in the Silurian to Devonian Keyser Limestone of the Helderberg Group (e.g., Owl Cave, upper parts of the Water Sinks Cave System) and in the Devonian Shriver Chert and (or) Licking Creek Limestone of the Helderberg Group (e.g., Helictite Cave). Within the Tonoloway Limestone, the larger caves are developed in the lower member of the Tonoloway Limestone immediately below a bed of silica-cemented sandstone. In contrast, the larger caves in the Keyser Limestone are located preferentially in limestone beds containing stromatoporoid reefs, and some of the larger caves in the Licking Creek Limestone are located in beds of cherty limestone below the Devonian Oriskany Sandstone. Geologic controls on cave passage morphology include joints, bedding planes, and folds. The influence of joints results in tall and narrow cave passages, whereas the influence of bedding planes results in cave passages with flat ceilings and (or) floors. The influence of folds is less common, but a few cave passages follow fold axes and have distinctive arched ceilings.

The Significance of Podpe limestone in the Cultural Heritage of Slovenia

NASA Astrophysics Data System (ADS)

Kramar, Sabina; Bedjanič, Mojca; Mirtič, Breda; Mladenović, Ana; Rožič, Boštjan; Skaberne, Dragomir; Zupančič, Nina

2013-04-01

Podpeč limestone is characterized by its dark grey, or nearly black colour, with white fossil shells of the Lithiotis. These beds, which have been dated as Lower Jurassic, occur in southern and south-western Slovenia, and are particularly common in areas southwest of Ljubljana. The main quarry, which is not active, is located next to the village of Podpeč near Ljubljana, and has been declared as a geological natural value of national importance; as such, it is officially protected as a natural monument. In the close vicinity of the village there are some other smaller quarries, but all of them have been abandoned. With its very low porosity (0.9%) and water absorption (0.13 - 0.30 % by mass), but relatively high compressive strength (185 MPa), this limestone is quite durable, although its colouring becomes somewhat bleached when situated outdoors. The use of Podpeč limestone was first documented in the case of the Roman period in Slovenia, when it was used for funerary stelae, votive altars, boundary stones, and other artefacts. At the end of the 5th Century AD, with the fall of the Roman Empire, stone-cutting ceased at Podpeč for the next few centuries. Before 1850 Podpeč limestone had no special value. Only very few portals or pilasters made of this stone are known, and no evidence has been found in churches. However, towards the end of the 19th Century Podpeč limestone became better-known, although before the first half of the 20th Century there were no significant stonecutting workshops in Podpeč. After this, stone was supplied progressively from the main quarry. Large numbers of buildings in Ljubljana and central Slovenia have sills, lintels and jambs made of Podpeč limestone. Production stopped in 1967. The internationally renowned Slovenian architect Jože Plečnik (1872-1957) used Podpeč limestone in various Slovenian buildings - the central stadium in Ljubljana, the National University Library, many altars and churches (Bogojina, the Ši\\vska and Bežigrad districts of Ljubljana), parts of the Parliament of the Republic of Slovenia (Ljubljana), and Ljubljana's first skyscraper. With the exception of the Antonius Church in Belgrade, which was constructed by Plečnik, where part of the altar was made of Podpeč limestone, the international use of Podpeč limestone is not known.

Experimental study on the relationship between the mineral production capability and the physiochemical properties in the coproduction of Q phase-3CaO·3Al2O3·CaSO4 cement clinker.

PubMed

He, Chao; Tian, Chaochao; Li, Gang; Mei, Yahe; Zhang, Quanguo; Jiao, Youzhou

2018-01-01

A coproduction tests of quaternary (Q) phase(6CaO·4Al2O3·MgO·SiO2) -3CaO·3Al2O3·CaSO4 cement clinker and an experimental study on the relationship between the mineral production capability and the physiochemical properties are conducted in a two-stage multiphase reaction test bed with Changguang coal. X-ray diffractometer (XRD) analyses are performed on the coproduction clinker samples. The results demonstrate that, with the reduction in particle sizes of the coal powder and the additives and expanded screening level differences between them, both the proportion of Q phase and the mass of 3CaO·3Al2O3·CaSO4 in the clinker increase accordingly. When mixed coal powder particles are prepared through reducing particle sizes and expanding screening level differences between coal powder and additives, the additives CaO and MgO are more likely to be enclosed by coal powder to form globular polymerized particles. In addition, this preparation aids in polymerization and promotes even distribution of CaO, MgO and coal minerals, thus facilitating clinker mineral formation reactions of inorganic substances in the mixed coal powder. Target minerals, such as 2CaO·SiO2 and Q phase, are found in both industrial high-calcium limestone and low-calcium limestone coproduction clinker samples. A diffraction peak of free CaO is also evident in both samples. Compared with a coproduction clinker sample of high-calcium limestone, that of low-calcium limestone exhibits higher diffraction peaks for 2CaO·SiO2 and Q phase. With the current state of the art, it is not yet the optimum choice to substitute CaCO3 for CaO in Q-phase cement clinker coproduction. Before the technology matures and gains practical application, further study on the form and the mixing process of calcium-based additives for cement clinker coproduction will be required.

Storage of treated sewage effluent and stormwater in a saline aquifer, Pinellas Peninsula, Florida

USGS Publications Warehouse

Rosenshein, J.S.; Hickey, J.J.

1977-01-01

The Pinellas Peninsula, an area of 750 square kilometres (290 square miles) in coastal west-central Florida, is a small hydrogeologic replica of Florida. Most of the Peninsula's water supply is imported from well fields as much as 65 kilometres (40 miles) inland. Stresses on the hydrologic environment of the Peninsula and on adjacent water bodies, resulting from intensive water-resources development and waste discharge, have resulted in marked interest in subsurface storage of waste water (treated effluent and untreated storm water) and in future retrieval of the stored water for nonpotable use. If subsurface storage is approved by regulatory agencies, as much as 265 megalitres per day (70 million gallons a day) of waste water could be stored underground within a few years, and more than 565 megalitres per day (150 million gallons a day) could be stored in about 25 years. This storage would constitute a large resource of nearly fresh water in the saline aquifers underlying about 520 square kilometres (200 square miles) of the Peninsula.The upper 1,060 metres (3,480 feet) of the rock column underlying four test sites on the Pinellas Peninsula have been explored. The rocks consist chiefly of limestone and dolomite. Three moderately to highly transmissive zones, separated by leaky confining beds, (low permeability limestone) from about 225 to 380 metres (740 to 1,250 feet) below mean sea level, have been identified in the lower part of the Floridan aquifer in the Avon Park Limestone. Results of withdrawal and injection tests in Pinellas County indicate that the middle transmissive zone has the highest estimated transmissivity-about 10 times other reported values. The chloride concentration of water in this zone, as well as in the two other transmissive zones in the Avon Park Limestone in Pinellas Peninsula, is about 19,000 milligrams per litre. If subsurface storage is approved and implemented, this middle zone probably would be used for storage of the waste water and the zone would become the most extensively used in Florida for this purpose.

Experimental study on the relationship between the mineral production capability and the physiochemical properties in the coproduction of Q phase-3CaO·3Al2O3·CaSO4 cement clinker

PubMed Central

Tian, Chaochao; Li, Gang; Mei, Yahe; Zhang, Quanguo; Jiao, Youzhou

2018-01-01

A coproduction tests of quaternary (Q) phase(6CaO·4Al2O3·MgO·SiO2) -3CaO·3Al2O3·CaSO4 cement clinker and an experimental study on the relationship between the mineral production capability and the physiochemical properties are conducted in a two-stage multiphase reaction test bed with Changguang coal. X-ray diffractometer (XRD) analyses are performed on the coproduction clinker samples. The results demonstrate that, with the reduction in particle sizes of the coal powder and the additives and expanded screening level differences between them, both the proportion of Q phase and the mass of 3CaO·3Al2O3·CaSO4 in the clinker increase accordingly. When mixed coal powder particles are prepared through reducing particle sizes and expanding screening level differences between coal powder and additives, the additives CaO and MgO are more likely to be enclosed by coal powder to form globular polymerized particles. In addition, this preparation aids in polymerization and promotes even distribution of CaO, MgO and coal minerals, thus facilitating clinker mineral formation reactions of inorganic substances in the mixed coal powder. Target minerals, such as 2CaO·SiO2 and Q phase, are found in both industrial high-calcium limestone and low-calcium limestone coproduction clinker samples. A diffraction peak of free CaO is also evident in both samples. Compared with a coproduction clinker sample of high-calcium limestone, that of low-calcium limestone exhibits higher diffraction peaks for 2CaO·SiO2 and Q phase. With the current state of the art, it is not yet the optimum choice to substitute CaCO3 for CaO in Q-phase cement clinker coproduction. Before the technology matures and gains practical application, further study on the form and the mixing process of calcium-based additives for cement clinker coproduction will be required. PMID:29634732

Reducing energy-related CO2 emissions using accelerated weathering of limestone

USGS Publications Warehouse

Rau, Greg H.; Knauss, Kevin G.; Langer, William H.; Caldeira, Ken

2007-01-01

The use and impacts of accelerated weathering of limestone (AWL; reaction: CO2+H2O+CaCO3→Ca2++2(HCO3-) is explored as a CO2 capture and sequestration method. It is shown that significant limestone resources are relatively close to a majority of CO2-emitting power plants along the coastal US, a favored siting location for AWL. Waste fines, representing more than 20% of current US crushed limestone production (>109 tonnes/yr), could provide an inexpensive or free source of AWL carbonate. With limestone transportation then as the dominant cost variable, CO2 mitigation costs of $3-$4/tonne appear to be possible in certain locations. Perhaps 10–20% of US point–source CO2 emissions could be mitigated in this fashion. It is experimentally shown that CO2 sequestration rates of 10-6 to 10-5 moles/sec per m2 of limestone surface area are achievable, with reaction densities on the order of 10-2 tonnes CO2 m-3day-1, highly dependent on limestone particle size, solution turbulence and flow, and CO2 concentration. Modeling shows that AWL would allow carbon storage in the ocean with significantly reduced impacts to seawater pH relative to direct CO2 disposal into the atmosphere or sea. The addition of AWL-derived alkalinity to the ocean may itself be beneficial for marine biota.

Identification of an Archean marine oxygen oasis

DOE Office of Scientific and Technical Information (OSTI.GOV)

Riding, Dr Robert E; Fralick, Dr Philip; Liang, Liyuan

2014-01-01

The early Earth was essentially anoxic. A number of indicators suggest the presence of oxygenic photosynthesis 2700 3000 million years (Ma) ago, but direct evidence for molecular oxygen (O2) in seawater has remained elusive. Here we report rare earth element (REE) analyses of 2800 million year old shallowmarine limestones and deep-water iron-rich sediments at Steep Rock Lake, Canada. These show that the seawater from which extensive shallow-water limestones precipitated was oxygenated, whereas the adjacent deeper waters where iron-rich sediments formed were not. We propose that oxygen promoted limestone precipitation by oxidative removal of dissolved ferrous iron species, Fe(II), to insolublemore » Fe(III) oxyhydroxide, and estimate that at least 10.25 M oxygen concentration in seawater was required to accomplish this at Steep Rock. This agrees with the hypothesis that an ample supply of dissolved Fe(II) in Archean oceans would have hindered limestone formation. There is no direct evidence for the oxygen source at Steep Rock, but organic carbon isotope values and diverse stromatolites in the limestones suggest the presence of cyanobacteria. Our findings support the view that during the Archean significant oxygen levels first developed in protected nutrient-rich shallow marine habitats. They indicate that these environments were spatially restricted, transient, and promoted limestone precipitation. If Archean marine limestones in general reflect localized oxygenic removal of dissolved iron at the margins of otherwise anoxic iron-rich seas, then early oxygen oases are less elusive than has been assumed.« less

Benthic foraminiferal assemblages and microfacies analysis of the Upper Cretaceous-Paleocene (?) platform carbonate sequence in the Central Taurides, S Turkey

NASA Astrophysics Data System (ADS)

Solak, Cemile; Taslı, Kemal; Koç, Hayati

2017-04-01

The Upper Cretaceous succession outcropping in the area known as Anamas-Akseki Autochton or Geyikdaǧı Unit, which is situated western part of the Central Taurides, consists of approximately 500 m thick purely platform carbonate sediments. Integrated microfacies/facies studies and biostratigraphic analysis of the Kuyucak stratigraphic section provided to recognise depositional settings and benthic foraminiferal biozones. The Upper Cretaceous begins with Cenomanian limestones intercalated with limestone breccias (Unit 1) containing mainly Pseudorhapydionina dubia, Cuneolina pavonia, Nezzazata simplex (Association 1) and unconformably overlies the Lower Cretaceous (Barremian-Aptian) limestones with Vercorsella laurentii, Praechrysalidina infracretacea and Salpingoporella hasi. The Cenomanian limestones include benthic foraminiferal packstone/wackestone, peloidal packstone/wackestone and mudstone microfacies deposited restricted platform conditions. Intercalations of emersion breccias suggest sporadic subaerial exposure of the platform. The Cenomanian succession are truncated by an unconformity characterised by locale bauxite infills. Immediately above the unconformable surface, dolomitic limestones and rudistid limestones (Unit 2) are assigned to the upper Campanian based on the benthic foraminiferal assemblage (Association 2) comprising mainly Murciella cuvillieri, Pseudocyclammina sphaeroidea, Accordiella conica, Scandonea samnitica and Fleuryana adriatica. The upper Campanian limestones composed of dominantly benthic foraminiferal packstone/wackestone microfacies deposited in shallow water environments with low water energy, subjected to restriction in water circulation, The following limestones of the Unit 2 is characterised by sporadic intercalation of "open shelf" Orbitoides, Omphalocyclus, Siderolites assemblage (Association 3), assigned to the Maastrichtian, in addition to pre-existing "restricted platform" species. Pseudedomia hekimhanensis and Helenocyclina beotica are occasionally accompanied this association. In the upper half of this biozone, the Rhapydionina liburnica subzone (Association 3b) is distinguished by the first occurences of Valvulina aff. triangularis, Loftusia minor as well as the nominal species. The Maastrichtian limestones with sporadically open marine influence consist mostly of bioclastic/microbioclastic (rudist-bearing) wackestone/packstone/grainstone, benthic foraminiferal packstone/wackestone with rudist fragments and peloidal/intraclastic packstone/wackestone microfacies deposited in shallow subtidal-subtidal (lagoonal) environments characterised by different hydrodynamic regimes (low to high energy). The Upper Cretaceous succession passes upwardly into 70 meters thick limestones and clayey limestones (Unit 3) which do not contain rudists and pre-existing foraminiferal assemblage with one exception Valvulina aff. triangularis. Variable amounts of ostracoda, Discorbidae, Miliolidae, dasycladacean algae and Stomatorbina sp. (Association 4) occur into muddy-rich microfacies suggesting restricted conditions with low water energy. A probable Paleocene age is proposed for the Unit 3 based on the occurence of Valvulina aff. triangularis and Stomatorbina sp. which were previously recorded from Paleocene of peri-Tethian platforms. The Upper Cretaceous-Paleocene(?) platform carbonate succession is unconformably overlain by conglomerate, limestone with Nummulites and siliciclastic sediments of the Eocene age. We thank to the Scientific and Technological Research Council of Turkey (TUBITAK) for a financial support with project no:115Y130.

Quaternary remagnetization of the Neoproterozoic limestone of Negash Synclinorium (Arabian-Nubian Shield, northern Ethiopia): With implications of no paleomagnetic testing for the proposed Snowball Earth events

NASA Astrophysics Data System (ADS)

Kidane, Tesfaye; Bachtadse, Valerian; Alene, Mulugeta

2014-10-01

Eighty-one paleomagnetic cores were collected from 10 locations across a black limestone unit within the core of Negash Synclinorium, northern Ethiopia in order to test the proposed Snowball Earth events for the diamictite unit of the Tambien Group. Cores were cut into two standard paleomagnetic specimens and were subjected to stepwise demagnetizations using both Thermal (TH) and alternating field (AF) techniques. Rock magnetic analyses on representative specimens were done and results revealed goethite, pyrrhotite, titano-magnetite, and titano-hematite to be the major magnetic materials carrying the magnetizations with PSD (pseudo single domain) grain size range. In most cases paleomagnetic directions are defined by a single component of magnetization, where a viscous component is present it is usually removed by heating to a temperature of ∼200 °C or an AF of ∼10 mT. The high stability component isolated above temperature of 200 °C or AF of 15 mT, defined straight line trajectories directed towards the origin and considered as the Characteristic Remanent Magnetization Direction (ChRM). The direction of magnetization of the ChRM is determined for samples with stable straight line segments by the best-fit line using the least square technique of Kirschvink (1980). In the cases of overlapping spectra and unblocking temperatures, direction of magnetization is determined by remagnetization circles of Halls (1976, 1978). When site mean ChRM directions are plotted on stereogram, their distribution is relatively clustered in geographic coordinates and the overall mean direction is Decg = 358.5°, Incg = 16.6° (α95 = 3.8°, K = 162.8, N = 10). After a structural restoration to the horizontal is made the directions disperse and fail the fold test of both McElhinny’s and McFadden’s tests and the mean direction is Decs = 353.5°, Incs = 8.8° (α95 = 18.9°, K = 7.5, N = 10). This is interpreted to result from a later remagnetization of the black limestone. All directions are normal in polarity and have mean unrestored paleomagnetic directions comparable to the Quaternary paleomagnetic directions. Virtual Geomagnetic poles (VGP) in the unrestored position is used to calculate overall mean VGP position resulting long = 235.7°E, latg = 84.5°N (A95 = 3.0°, N = 10). Comparison of the obtained pole with the apparent polar wander path (APWP) curve for Africa of Besse and Courtillot (1991, 2003) and with the 2 Ma reference pole of stable Africa (Kidane et al., 2003) is found to be consistent with remagnetizations during the Quaternary period. Hence supporting evidence for the proposed Snowball Earth event of the Sturtian glaciation in the Negash rocks could not, unfortunately, be obtained from paleomagnetism.

Salt-water encroachment, geology, and ground-water resources of Savannah area, Georgia and South Carolina

USGS Publications Warehouse

Counts, H.B.; Donsky, Ellis

1964-01-01

The Savannah area consists of about 2,300 square miles of the Coastal Plain along the coast of eastern Georgia and southeastern South Carolina. Savannah is near the center of the area. Most of the large ground-water developments are in or near Savannah. About 98 percent of the approximately 60 mgd of ground water used is pumped from the principal artesian aquifer, which is composed of about 600 feet of limestone of middle Eocene, Oligocene, and early Miocene ages. Industrial and other wells of large diameter yield as much as 4,200 gpm from the principal artesian aquifer. Pumping tests and flow-net analyses show that the coefficient of transmissibility averages about 200,000 gpd per ft in the immediate Savannah area. The specific capacity of wells in the principal artesian aquifer generally is about 50 gpm per ft of drawdown. The coefficient of storage of the principal artesian aquifer is about 0.0003 in the Savannah area. Underlying the Savannah area are a series of unconsolidated and semiconsolidated sediments ranging in age from Late Cretaceous to Recent. The Upper Cretaceous, Paleocene, and lower Eocene sediments supply readily available and usable water in other parts of the Coastal Plain, but although the character and physical properties of these formations are similar in the Savannah area to the same properties in other areas, the hydraulic and structural conditions appear to be different. Deep test wells are needed to evaluate the ground-water potential of these rocks. The lower part of the sediments of middle Eocene age acts as a confining layer to the vertical movement of water into or out of the principal artesian aquifer. Depending on the location and depth, the principal artesian aquifer consists of from one to five geologic units. The lower boundary of the aquifer is determined by a reduction in permeability and an increase in salt-water content. Although the entire limestone section is considered water bearing, most of the ground water used in the area comes from the upper part of the Ocala limestone of late Eocene age and the limestones of Oligocene age. The greatest volume of water comes from the upper part of the Ocala limestone, but the greatest number of wells are supplied from the rocks of Oligocene age. The Tampa limestone and Hawthorn formation of early Miocene age are generally water bearing; the amount and quality of the water depends on the location. The water from some wells in the Tampa and most of the water from the Hawthorn is high in hydrogen sulfide. In the northeastern part of the area the principal artesian aquifer is close to the land surface. Here the confining layer is thin and in some of the estauaries it may be completely cut through by the scouring action of the streams during tidal fluctuations. In this part of the area artesian groundwater at one time discharged from the aquifer as submarine springs. Now a reverse effect may be occurring; ocean and river water may be entering the aquifer. The silts, clays, and very fine sands of the upper Miocene and Pliocene ( ?) series generally have low permeabilities and form the upper confining layer for the principal artesian aquifer. Although all the sediments overlying the principal artesian aquifer are considered to be part of the confining layer, locally some of the upper units are water bearing. The uppermost geologic units in the Savannah area are sediments of Pliocene ( ?) to Recent age and consist of sands, silts, and clays with shell and gravel beds which are a source of water for shallow wells. The first large ground-water supply from the principal artesian aquifer was developed in 1886 by the city of Savannah. Additional municipal and industrial supplies have been developed since that time. Pumpage progressively increased to a peak of 62 mgd in 1957. Outside of the city and industrial area the 1957 pumpage was about 9 mgd. In 1958 the total pumpage in the Savannah area was about 68 mgd or about 3 mgd less th

Assessment of Rock Slope Stability in Limestone Quarries in the Tournai's Region (Belgium) Using Structural Data

NASA Astrophysics Data System (ADS)

Tshibangu, Jean-Pierre; Deloge, K. Pierre-Alexandre; Deschamps, Benoît; Coudyzer, Christophe

The Tournais region is characterised by famous outcrops of carboniferous limestone which is mined out for cement and raw material production. The four main quarries found in the Region, i.e. Gaurain-Ramecroix, Milieu, Antoing and Lemay; are owned by the three main cement producers in Belgium: Italcimenti, Holcim and CBR. The global production of limestone is about 20 millions tons per year, giving big pits with depths up to 150 m. With the growth of the pits, the quarries are approaching each other leading to the problem of managing the reserves contained in the separating walls and their mechanical stability. The limestone deposit is composed of different seams having varying thickness, chemical com- position and even mechanical properties. The deposit has an overall horizontal dip and is intersected by two main sets of discontinuities with a spacing of about 10 m or less. It is also crossed by a set of east to west faults but the quarries are implanted in the in between areas, so to not be crossed by these faults. The layers and specially the shallow ones are characterised by a typical karstic weathering giving open or filled cavities. This paper presents the global work quarried out in order to study the stability of the Lemays quarry. First a description of the orientation and spacing of discontinuities is presented, and an attempt made to correlate to the development of weathering. Mechanical laboratory tests have been performed and a qualification of the rock mass assessed. A coupled approach is then presented using a mining planning analysis and mechanical simulation (i.e. Finite Element method).

Frictional processes during flank motion at Mount Etna (Italy): experimental characterisation of slip on similar and dissimilar volcanic and sedimentary rocks.

NASA Astrophysics Data System (ADS)

Rozanski, Wojciech; Lavallee, Yan; Kendrick, Jackie; Castagna, Angela; Mitchell, Thomas; Heap, Michael; Vinciguerra, Sergio; Hirose, Takehiro; Dingwell, Donald

2015-04-01

The edifice of Mount Etna (Italy) is structurally unstable, exhibiting a near continuous ESE seaward sliding along a set of faults due to interplay between regional tectonics, gravity instability and magma intrusion. Continuous seismic and ground deformation monitoring reveals the resulting large-scale flank motion at variable rates. The mechanisms controlling this faulting kinetic remains, however, poorly constrained. Examination of the fault zones reveals a range of rock types along the different fault segments: fresh and altered basalt, clay and limestone. As lithological contrasts can jeopardise the structural stability of an edifice, we experimentally investigate the frictional properties of these rocks using low- to high-velocity-rotary shear tests on similar and dissimilar rocks to better understand episodes of slow flank motion as well as rapid and catastrophic sector collapse events. The first set of experiments was performed at velocities up to 1.2 m/s and at normal stresses of 1.5 MPa, commensurate with depths of the contacts seen in the Etna edifice. Friction experiments on clay gouge shows the strong rate-weakening dependence of slip in this material as well as the release of carbon dioxide. Friction experiments on solid rocks show a wider range of mechanical behaviour. At high velocity (>0.6 m/s) volcanic rocks tend to melt whereas the clay and limestone do not; rather they decarbonate, which prevents the rock from achieving the temperature required for melting. Experiments on dissimilar rocks clearly show that composition of host rocks affects the composition and viscosity of the resultant frictional melt, which can have a dramatic effect on shear stress leading to fault weakening or strengthening depending on the combination of host rock samples. A series of low- to moderate-slip velocity experiments is now being conducted to complement our dataset and provide a more complete rock friction model applicable to Mount Etna.

Reducing Energy-Related CO2 Emissions Using Accelerated Limestone Weathering

DOE Office of Scientific and Technical Information (OSTI.GOV)

Rau, G H; Knauss, K G; Langer, W H

2004-04-27

Following earlier descriptions, the use and impacts of accelerated weathering of limestone AWL; reaction: CO{sub 2} + H{sub 2}O + CaCO{sub 3} {yields} Ca{sup 2+} + 2(HCO{sub 3}{sup -}) as a CO{sub 2} capture and sequestration method is further explored. Since ready access to the ocean is likely an essential requirement for AWL, it is shown that significant limestone resources are relatively close to a majority of CO{sub 2}-emitting power plants along the coastal US. Furthermore, waste fines, representing more than 20% of current US crushed limestone production (>10{sup 9} tonnes/yr), could be used in many instances as an inexpensivemore » or free source of AWL carbonate. With limestone transportation to coastal sites then as the dominant cost variable, CO{sub 2} sequestration (plus capture) costs of $3-$4/tonne are achievable in certain locations. While there is vastly more limestone and water on earth than that required for AWL to capture and sequester all fossil fuel CO{sub 2} production, the transportation cost of bringing limestone, seawater, and waste CO{sub 2} into contact likely limits the method's applicability to perhaps 10-20% of US point-source emissions. Using a bench-scale laboratory reactor, it is shown that CO{sub 2} sequestration rates of 10{sup -6} to 10{sup -5} moles/sec per m{sup 2} of limestone surface area are readily achievable using seawater. This translates into reaction densities as high as 2 x 10{sup -2} tonnes CO{sub 2} m{sup -3}day{sup -1}, highly dependent on limestone particle size, solution turbulence and flow, and CO{sub 2} concentration. Modeling of AWL end-solution disposal in the ocean shows significantly reduced effects on ocean pH and carbonate chemistry relative to those caused by direct CO{sub 2} disposal into the atmosphere or ocean. In fact the increase in ocean Ca{sup 2+} and bicarbonate offered by AWL should significantly enhance the growth of corals and other marine calcifiers whose health is currently being threatened by anthropogenic CO{sub 2} invasion and pH reduction in the ocean.« less

Timing and genesis of early marine caymanites in the hydrothermal palaeokarst system of Buda Hills, Hungary

NASA Astrophysics Data System (ADS)

Korpás, L.; Lantos, M.; Nagymarosy, A.

1999-01-01

Sedimentological, biostratigraphic and magnetostratigraphic studies were carried out on five Late Eocene-Early Oligocene profiles in the Buda Hills, Hungary. The Szépvölgy Limestone Formation accumulated on the pre-Eocene basement. Basal strata of the limestone consist of a thin conglomerate followed by a coralgal limestone. The overlying limestone contains abundant Nummulites, Discocyclina. The contact between these two members is sharp. The Szépvölgy Limestone body, covering 60-65 km 2, is considered a carbonate bank. Above the limestone, the siliciclastic slope deposits of the pelagic and turbiditic Buda Marl, and the euxinic Tard Clay accumulated. A huge multiphase hydrothermal cave system developed in the Szépvölgy Limestone resulting in a long-term composite palaeokarstic evolution lasting from the Late Eocene to the Quaternary. The first palaeokarst phase during the Late Eocene is represented by two generations of early marine cavity filling sediments of caymanite-type, deposited at sea-level. The earlier, carbonate infilling is conformable while the younger, siliciclastic one is disconformable with the bedding of the host rock. Bio- and magnetostratigraphic studies indicate that deposition of the caymanites-bearing palaeokarst host sequence started in the Late Eocene, during Chron C15r (35.3 Ma) and terminated in the Early Oligocene during Chron C13n (33 Ma). Two marker horizons are present, the first is between the Szépvölgy Limestone and Buda Marl at ˜34.6 Ma, and the second horizon is between the Buda Marl and the Tard Clay at 33.5 Ma. The Szépvölgy Limestone, deposited on a mobile shelf, represents a deepening upward sequence, interrupted by two lowstand events. They can be correlated with the PHd event of Keller et al., 1987 (Global distribution of late Palaeogene hiatuses. Geology 15, 199-203) and resulted in marine palaeokarstification. The carbonate shelf with the infillings drowned at 34.6 Ma. The caymanites accumulated at about 35.2-35.0 Ma and represent short-term palaeokarstic events. Their deposition record was estimated in several thousand years.

Sedimentology and paleoenvironments of the Las Chacritas carbonate paleolake, Cañadón Asfalto Formation (Jurassic), Patagonia, Argentina

NASA Astrophysics Data System (ADS)

Cabaleri, Nora G.; Benavente, Cecilia A.

2013-02-01

The Las Chacritas Member is the lower part of the Cañadón Asfalto Formation (Jurassic). The unit is a completely continental limestone succession with volcanic contributions that were deposited during the development of the Cañadón Asfalto Rift Basin (Chubut province, Patagonia, Argentina). A detailed sedimentological analysis was performed in the Fossati depocenter to determine the paleoenvironments that developed in the context of this rift. The Las Chacritas Member represents a carbonate paleolake system with ramp-shaped margins associated with wetlands that were eventually affected by subaerial exposure and pedogenesis. This process is represented by three main subenvironments: a) a lacustrine setting sensu stricto (lacustrine limestone facies association), represented by Mudstones/Wackestones containing porifera spicules (F1), Intraclastic packstones (F6) and Tabular stromatolites (F10) in which deposition and diagenesis were entirely subaqueous; b) a palustrine setting (palustrine limestone facies association) containing Microbial Mudstones (F2), Intraclastic sandy packstone with ostracode remains (F3), Oncolitic packstone (F5), Brecciated limestone (F7) and Nodular-Mottled limestone (F8) representing shallow marginal areas affected by groundwater fluctuations and minor subaerial exposure; and c) a pedogenic paleoenvironment (pedogenic limestone facies association) including Intraclastic limestone (F4) and Packstones containing Microcodium (F9) facies displaying the major features of subaerial exposure, pedogenic diagenesis and the development of paleosols. The fluvial-palustrine-lacustrine succession shows a general shallow upward trend in which contraction-expansion cycles are represented (delimited by exposure and surface erosion). The variations in the successive formations reflect the responses to fluctuations in a combination of two major controls, the tectonic and local climatic variables. The predominance of the palustrine facies associations was determined by its accommodation space as well as the local climate conditions. The variations in the lacustrine limestone facies associations reflect differential patterns of subsidence within the sub-basin. The diagnostic features of the palustrine limestone facies associations (organic matter (OM) content, microinvertebrate fauna, abundant mud cracks, brecciation, presence of evaporitic minerals) frame the sub-basin in a climatic context intermediate between arid and subhumid conditions.

Timing of porosity destruction related to pressure-solution in limestones

NASA Astrophysics Data System (ADS)

Beaudoin, Nicolas; Koehn, Daniel; Aharonov, Einat; Boyce, Adrian; Billi, Andrea; Hamilton, Andrea

2017-04-01

Among effects that affect sedimentary rocks during diagenesis, pressure-solution has a very strong impact on the physical properties of rocks such as porosity and permeability. Intergranular pressure-solution results in rough or wavy surfaces called stylolites, which are very common in sedimentary basins, especially in limestone. According to the opening of the system, dissolved material can precipitate locally, leading to the destruction of the porosity around the stylolite. That can namely occur during the development of sedimentary stylolites, when no fracture of fault can allow dissolved material to flow away before precipitating again. This contribution aims at unravelling the depth at which the material dissolved during compaction precipitated in the open porosity, adding new data to discuss when pressure-solution starts to be an efficient mechanism of deformation in limestone during strata burial in sedimentary basins. We report the results of the study of cements that fill the fractures developed at the tips of stylolites in a sample of dolostone from the Jurassic Calcare Massiccio formation, coming from the Umbria-Marche area (Italy). The fractures developed from stylolite-induced stress, and the filling cements' oxygen and carbon isotopic values range between 10.6‰ to -6.1‰ PDB and -8.2‰ to -0.6‰ PDB, respectively. Considering a closed system, we use fractionation equations to convert δ18O values into temperature, which shows that the material put in solution during pressure-solution precipitated at a temperature ranging from 18°C to 39°C. Temperature range and geothermal gradient estimates suggest that the mechanism of pressure-solution actually was primarily active at depth as low as 1 km. In the studied sample, up to 18% of the original volume has been dissolved on stylolites, and that volume loss would have occurred in the first 2 km of the burial history. This natural example feeds the growing body of evidence that stylolites can start developing at a very low depth level. Our results suggest that the porosity in sedimentary rocks can be destroyed very early during burial, both by dissolution and by precipitation, which make the pressure-solution mechanism's impact on fluid flow in basin likely to be underestimated.

Blind Inlet as a Possible Technology for the Remediation of Phosphorus from Surface Runoff

NASA Astrophysics Data System (ADS)

Sturmlechner, M.; Wu, X.; Livingston, S.; Klik, A.; Huang, C. H.

2015-12-01

Phosphorus (P) is an essential element for plant life, but too much P in runoff water can cause eutrophication and harmful algal blooms. Hence, mitigation of agricultural P losses into the water cycle is a very important issue. In-stream P treatment is difficult to implement because the large amount of storm runoff needs to be treated in short durations. In this research, we evaluated the potential to use blind inlet as an in-field P treatment technology. A box system was built to simulate hydrological and chemical processes occurring in a blind inlet. Current blind inlets, which are already installed in the field, use a bed of limestone with a sand/pea gravel layer on the top. In this study, steel slags has been tested, which has a very high P sorption potential, as the filter media through a series of adsorption and desorption experiments. The P mass balance results are compared with the limestone material used in current blind inlet construction. The total mass of P which was absorbed by the limestone was 14 % of the P input into the system whereas 26 % P was absorbed by the steel slags. Therefore the steel slags show potential to sequester dissolved P. Additional research is on-going to come up with a design criteria for field implementation.

Geological structure, recharge processes and underground drainage of a glacierised karst aquifer system, Tsanfleuron-Sanetsch, Swiss Alps

NASA Astrophysics Data System (ADS)

Gremaud, Vivian; Goldscheider, Nico; Savoy, Ludovic; Favre, Gérald; Masson, Henri

2009-12-01

The relationships between stratigraphic and tectonic setting, recharge processes and underground drainage of the glacierised karst aquifer system ‘Tsanfleuron-Sanetsch’ in the Swiss Alps have been studied by means of various methods, particularly tracer tests (19 injections). The area belongs to the Helvetic nappes and consists of Jurassic to Palaeogene sedimentary rocks. Strata are folded and form a regional anticlinorium. Cretaceous Urgonian limestone constitutes the main karst aquifer, overlain by a retreating glacier in its upper part. Polished limestone surfaces are exposed between the glacier front and the end moraine of 1855/1860 (Little Ice Age); typical alpine karrenfields can be observed further below. Results show that (1) large parts of the area are drained by the Glarey spring, which is used as a drinking water source, while marginal parts belong to the catchments of other springs; (2) groundwater flow towards the Glarey spring occurs in the main aquifer, parallel to stratification, while flow towards another spring crosses the entire stratigraphic sequence, consisting of about 800 m of marl and limestone, along deep faults that were probably enlarged by mass movements; (3) the variability of glacial meltwater production influences the shape of the tracer breakthrough curves and, consequently, flow and transport in the aquifer.

The effect of chalk on the finger-hold friction coefficient in rock climbing.

PubMed

Amca, Arif Mithat; Vigouroux, Laurent; Aritan, Serdar; Berton, Eric

2012-11-01

The main purpose of this study was to examine the effect of chalk on the friction coefficient between climber's fingers and two different rock types (sandstone and limestone). The secondary purpose was to investigate the effects of humidity and temperature on the friction coefficient and on the influence of chalk. Eleven experienced climbers took part in this study and 42 test sessions were performed. Participants hung from holds which were fixed on a specially designed hang board. The inclination of the hang board was progressively increased until the climber's hand slipped from the holds. The angle of the hang board was simultaneously recorded by using a gyroscopic sensor and the friction coefficient was calculated at the moment of slip. The results showed that there was a significant positive effect of chalk on the coefficient of friction (+18.7% on limestone and +21.6% on sandstone). Moreover sandstone had a higher coefficient of friction than limestone (+15.6% without chalk, +18.4% with chalk). These results confirmed climbers' belief that chalk enhances friction. However, no correlation with humidity/temperature and friction coefficient was noted which suggested that additional parameters should be considered in order to understand the effects of climate on finger friction in rock climbing.

Geological applications of Nimbus radiation data in the Middle East

NASA Technical Reports Server (NTRS)

Allison, L. J.

1977-01-01

Large plateaus of Eocene limestone and exposed limestone escarpments, in Egypt and Saudi Arabia, respectively, were indicated by cool brightness temperatures recorded by the Nimbus-5 electrically scanning microwave radiometer (ESMR), over a 2-year period. Nubian sandstone, desert eolian sand, and igneous-metamorphic rock of the Pliocene, Miocene, Oligocene, and Cretaceous periods were differentiated from these limestone areas by warm T sub B values. These brightness temperature differences are a result of seasonal in-situ ground temperatures and differential emissivity of limestone and sand, sandstone and granite, whose dielectric constants are 6 to 8.9 and 2.9 and 4.2 to 5.3, respectively, at 19.35 GHz.

Home range characteristics and overwintering ecology of the stripe-necked musk turtle (Sternotherus minor peltifer) in middle Tennessee

USGS Publications Warehouse

Ennen, Joshua R.; Scott, A. Floyd

2013-01-01

Little is known about the movement behavior of the stripe-necked musk turtle, Sternotherus minor peltifer. Using radiotelemetry, we calculated mean (± SD) home range length, which was 341.4 ± 90.3 m, with home range length not differing between the sexes (males, 335 ± 194 m; females, 346 ± 79.5 m). Sternotherus m. peltifer were active in every month of the year but decreased their movement distance and frequency between December and March; during nonwinter and winter periods, individuals used limestone bluffs most often.

Devonian-Carboniferous boundary succession in Eastern Taurides, Turkey

NASA Astrophysics Data System (ADS)

Atakul-Özdemir, Ayşe; Altıner, Demir; Özkan-Altıner, Sevinç

2015-04-01

The succession covering the Devonian-Carboniferous boundary in Eastern Taurides comprises mainly limestones, shales and siltstones. The studied section starts at the base with bioturbated limestones alternating with shales and is followed upwards by platy limestones, and continues with the alternations of bioturbated and platy limestones. Towards the upper part of the succession the alternations of limestone, shales and siltstones reappear again and the top of the section is capped by quartz arenitic sandstone. The studied section spanning the Uppermost Devonian-Lower Carboniferous interval yields a not very abundant, but quite important assemblage of conodont taxa including species of Bispathodus, Polygnathus, Palmatolepis, Spathognathodus and Vogelgnathus. The uppermost Devonian part of the succession is characterized by the presence of Bispathodus costatus, Bispathodus aculeatus aculeatus, Polygnathus communis communis, Palmatolepis gracilis gracilis and Spathognathodus sp.. The Lower Carboniferous in the studied section is represented by the appearance of Polygnathus inornatus and Polygnathus communis communis. Based on the recovered conodont assemblages, Devonian-Carboniferous boundary in Eastern Turides has been determined by the appearance and disappearance of major conodont species.

Facies development and paleoenvironment of the Hajajah Limestone Member, Aruma Formation, central Saudi Arabia

NASA Astrophysics Data System (ADS)

El-Sorogy, Abdelbaset S.; Ismail, Abdelmoneim; Youssef, Mohamed; Nour, Hamdy

2016-12-01

The Campanian Hajajah Limestone Member of the Aruma Formation was formed during two regressive episodes. Each of them formed of three depositional facies, from base to top: 1) intra-shelf basin facies, made up of fossiliferous green shale and mudstone with ostracods and badly preserved foraminifers. 2) fore-reef facies, consists of hard, massive, marly coralline limestone. The upper part is rich with low divers, badly to moderate preserved, solitary and colonial corals, and, 3) back reef and near-shore facies, consists of fossiliferous sandy dolomitized, bioturbated limestone with abundant reworked corals, bivalves, gastropods, and aggregate grains. On the basis of field observations, micro-and macrofossils and microfacies analysis, the Hajajah Limestone Member was deposited in distal marine settings below storm wave base in a low-energy environment changed upward to fore-reef framework in an open marine environment with moderate to high energy conditions and terminated with shallow marine facies with accumulation of skeletal grains by storms during regression.

Discontinuity surfaces and event stratigraphy of Okha Shell Limestone Member: Implications for Holocene sea level changes, western India

NASA Astrophysics Data System (ADS)

Bhonde, Uday; Desai, Bhawanisingh G.

2011-08-01

The Okha Shell Limestone Member of Chaya Formation is the coarse grained, shell rich deposit commonly recognized as the beach rocks. It has been age bracketed between Late Pleistocene and Holocene. Late Quaternary sea level changes have been studied with beach rocks along the Saurashtra coastal region. The present study has been carried out in the Okhamandal area of the Saurashtra peninsula especially on the Okha Shell Limestone Member as exposed at various locations along the coast from north to south. Temporal and spatial correlations of the observations have revealed three events in the Okha Shell Limestone Member of Chaya Formation that are correlated laterally. The events show depositional breaks represented by discontinuity surfaces, the taphofacies varieties and ichnological variations. The present study in the context of available geochrnological data of the region suggests a prominent depositional break representing low sea level stand (regression) during an Early Holocene during the deposition of Okha Shell Limestone Member.

CO2 mitigation via accelerated limestone weathering

USGS Publications Warehouse

Rau, Greg H.; Knauss, Kevin G.; Langer, William H.; Caldeira,

2004-01-01

We evaluate accelerated weathering of limestone (AWL: CO2 + CaCO3 + H2O=> Ca2+ + 2HCO3-) as a low-tech, inexpensive, high-capacity, environmentally-friendly CO2 capture and sequestration technology. With access to seawater and limestone being essential to this approach, significant limestone resources are close to most CO2-emitting power plants along the coastal US. Waste fines, representing more than 20% of current US crushed limestone production (>109 tonnes/yr), could be used as an inexpensive source of AWL carbonate. Under such circumstances CO2 mitigation cost could be as low as $3-$4/tonne. More broadly, 10-20% of US point-source CO2 emissions could be treated at $20-$30/tonne CO2. AWL end-solution disposal in the ocean would significantly reduce effects on ocean pH and carbonate chemistry relative to those caused by direct atmospheric or ocean CO2 disposal. Indeed, the increase in ocean Ca2+ and bicarbonate offered by AWL should enhance growth of corals and other calcifying marine organisms.

Hydrogeologic terranes and potential yield of water to wells in the Valley and Ridge Physiographic Province in the eastern and southeastern United States

USGS Publications Warehouse

Hollyday, E.F.; Hileman, G.E.

1996-01-01

The Valley and Ridge Physiographic Province is underlain by deformed sedimentary rock of Paleozoic age including dolomite, limestone, shale, and sandstone. Regolith (soil, sediment, and weathered rock) covers the Paleozoic rock throughout most of the province. Local differences in lithology, structure, and weathering can result in four orders of magnitude variation in the water-yielding properties of the geologic units that underlie the area. Selected rock types, however, can account for a substantial part of this variation because of the unique way in which these dense, consolidated sedimentary rock types deform and weather to produce secondary openings.On the basis of relations among rock type, water-yielding openings, and water-yielding properties (as indicated by specific capacity), the regolith and consolidated rock were classified and mapped as five hydrogeologic terranes alluvium, dolomite, limestone, argillaceous carbonate rock, and siliciclastic rock. The hydrogeologic terranes are named after the predominant outcrop lithology within them. The western toe of the Blue Ridge Mountains is classified as a subdivision of the dolomite hydrogeologic terrane that may produce yields of water in excess of 1,000 gallons per minute (gal/min) to public and industrial supply wells. Specific-capacity data for homogeneous data sets, which consist of all wells that have the same characteristics in regard to casing diameter, primary use of the water, and topographic setting, revealed significant differences in water-yielding properties among the five hydrogeologic terranes. According to results of Tukey statistical tests at a probability (alpha level) of 0.05, 8 out of 10 pairs of hydrogeologic terranes (for example, alluvium/limestone) had significantly different median specific-capacity values. The median value for public and industrial supply wells in the western toe is three times greater than the value for comparable wells in the dolomite hydrogeologic terrane elsewhere. Estimates of potential yields to public and industrial supply wells were calculated from specific-capacity data for most-productive wells, which have casing diameter of 7 in. or more, discharge water primarily for public or industrial supply, and are in a valley. Median constant drawdowns, calculated from reported drawdowns, were assumed to be between 10 and 90 ft for wells completed in each of the five hydrogeologic terranes, and well-entrance losses were assumed to be negligible. Estimated interquartile ranges in potential yields to 412 mostproductive wells in the five hydrogeologic terranes were 170 to 580 gal/min, alluvium; 210 to 1,400 gal/min, dolomite; 80 to 720 gal/min, limestone; 65 to 850 gal/min, argillaceous carbonate rock; and 70 to 280 gal/min, siliciclastic rock.

Strontium and carbon isotope stratigraphy of the Late Jurassic shallow marine limestone in western Palaeo-Pacific, northwest Borneo

NASA Astrophysics Data System (ADS)

Kakizaki, Yoshihiro; Weissert, Helmut; Hasegawa, Takashi; Ishikawa, Tsuyoshi; Matsuoka, Jun; Kano, Akihiro

2013-09-01

Strontium and carbon isotope stratigraphy was applied to a 202 m-thick shallow marine carbonate section within the Late Jurassic Bau Limestone at the SSF quarry in northwest Borneo, Malaysia, which was deposited in the western Palaeo-Pacific. Strontium isotopic ratios of rudist specimens suggest that the SSF section was formed between the latest Oxfordian (155.95 Ma) and the Late Kimmeridgian (152.70 Ma), which is consistent with previous biostratigraphy. The δ13Ccarb values of bulk carbonate range from -0.10 to +2.28‰ and generally show an increasing upward trend in the lower part of the section and a decreasing upward trend in the upper part of the section. A comparable pattern is preserved in the δ13Corg isotope record. Limestone samples of the SSF section mainly preserve the initial δ13Ccarb values, except for the interval 84-92 m, where an apparent negative anomaly likely developed as a result of meteoric diagenesis. Comparing with the Tethyan δ13Ccarb profile, a negative anomaly in the lower SSF section can be correlated with the lowered δ13C values around the Oxfordian/Kimmeridgian boundary. In addition, δ13Ccarb values of the Bau Limestone are generally ∼1‰ lower than the Tethyan values, but comparable with the values reported from Scotland and Russia, located in Boreal realm during the Late Jurassic. This suggests that either the Tethyan record or the other records have been affected by the δ13C values of regionally variable dissolved inorganic carbon (DIC). The Late Jurassic δ13CDIC values are thought to have been regionally variable as a result of their palaeoceanographic settings. This study shows that δ13C chemostratigraphy of the Palaeo-Pacific region contributes to an improved understanding of global carbon cycling and oceanography during this time period.

Estimation of deep infiltration in unsaturated limestone environments using cave lidar and drip count data

NASA Astrophysics Data System (ADS)

Mahmud, K.; Mariethoz, G.; Baker, A.; Treble, P. C.; Markowska, M.; McGuire, E.

2016-01-01

Limestone aeolianites constitute karstic aquifers covering much of the western and southern Australian coastal fringe. They are a key groundwater resource for a range of industries such as winery and tourism, and provide important ecosystem services such as habitat for stygofauna. Moreover, recharge estimation is important for understanding the water cycle, for contaminant transport, for water management, and for stalagmite-based paleoclimate reconstructions. Caves offer a natural inception point to observe both the long-term groundwater recharge and the preferential movement of water through the unsaturated zone of such limestone. With the availability of automated drip rate logging systems and remote sensing techniques, it is now possible to deploy the combination of these methods for larger-scale studies of infiltration processes within a cave. In this study, we utilize a spatial survey of automated cave drip monitoring in two large chambers of Golgotha Cave, south-western Western Australia (SWWA), with the aim of better understanding infiltration water movement and the relationship between infiltration, stalactite morphology, and unsaturated zone recharge. By applying morphological analysis of ceiling features from Terrestrial LiDAR (T-LiDAR) data, coupled with drip time series and climate data from 2012 to 2014, we demonstrate the nature of the relationships between infiltration through fractures in the limestone and unsaturated zone recharge. Similarities between drip rate time series are interpreted in terms of flow patterns, cave chamber morphology, and lithology. Moreover, we develop a new technique to estimate recharge in large-scale caves, engaging flow classification to determine the cave ceiling area covered by each flow category and drip data for the entire observation period, to calculate the total volume of cave discharge. This new technique can be applied to other cave sites to identify highly focussed areas of recharge and can help to better estimate the total recharge volume.

Estimation of deep infiltration in unsaturated limestone environments using cave LiDAR and drip count data

NASA Astrophysics Data System (ADS)

Mahmud, K.; Mariethoz, G.; Baker, A.; Treble, P. C.; Markowska, M.; McGuire, E.

2015-09-01

Limestone aeolianites constitute karstic aquifers covering much of the western and southern Australian coastal fringe. They are a key groundwater resource for a range of industries such as winery and tourism, and provide important ecosystem services such as habitat for stygofauna. Moreover, recharge estimation is important for understanding the water cycle, for contaminant transport, for water management and for stalagmite-based paleoclimate reconstructions. Caves offer a natural inception point to observe both the long-term groundwater recharge and the preferential movement of water through the unsaturated zone of such limestone. With the availability of automated drip rate logging systems and remote sensing techniques, it is now possible to deploy the combination of these methods for larger scale studies of infiltration processes within a cave. In this study, we utilize a spatial survey of automated cave drip monitoring in two large chambers of the Golgotha Cave, South-West Western Australia (SWWA), with the aim of better understanding infiltration water movement and the relationship between infiltration, stalactite morphology and unsaturated zone recharge. By applying morphological analysis of ceiling features from Terrestrial LiDAR (T-LiDAR) data, coupled with drip time series and climate data from 2012-2014, we demonstrate the nature of the relationships between infiltration through fractures in the limestone and unsaturated zone recharge. Similarities between drip-rate time series are interpreted in terms of flow patterns, cave chamber morphology and lithology. Moreover, we develop a new technique to estimate recharge in large scale caves, engaging flow classification to determine the cave ceiling area covered by each flow category and drip data for the entire observation period, to calculate the total volume of cave discharge. This new technique can be applied to other cave sites to identify highly focused areas of recharge and can help to better estimate the total recharge volume.

Mineral Dissolution and Precipitation due to Carbon Dioxide-Water-Rock Interactions: The Significance of Accessory Minerals in Carbonate Reservoirs (Invited)

NASA Astrophysics Data System (ADS)

Kaszuba, J. P.; Marcon, V.; Chopping, C.

2013-12-01

Accessory minerals in carbonate reservoirs, and in the caprocks that seal these reservoirs, can provide insight into multiphase fluid (CO2 + H2O)-rock interactions and the behavior of CO2 that resides in these water-rock systems. Our program integrates field data, hydrothermal experiments, and geochemical modeling to evaluate CO2-water-rock reactions and processes in a variety of carbonate reservoirs in the Rocky Mountain region of the US. These studies provide insights into a wide range of geologic environments, including natural CO2 reservoirs, geologic carbon sequestration, engineered geothermal systems, enhanced oil and gas recovery, and unconventional hydrocarbon resources. One suite of experiments evaluates the Madison Limestone on the Moxa Arch, Southwest Wyoming, a sulfur-rich natural CO2 reservoir. Mineral textures and geochemical features developed in the experiments suggest that carbonate minerals which constitute the natural reservoir will initially dissolve in response to emplacement of CO2. Euhedral, bladed anhydrite concomitantly precipitates in response to injected CO2. Analogous anhydrite is observed in drill core, suggesting that secondary anhydrite in the natural reservoir may be related to emplacement of CO2 into the Madison Limestone. Carbonate minerals ultimately re-precipitate, and anhydrite dissolves, as the rock buffers the acidity and reasserts geochemical control. Another suite of experiments emulates injection of CO2 for enhanced oil recovery in the Desert Creek Limestone (Paradox Formation), Paradox Basin, Southeast Utah. Euhedral iron oxyhydroxides (hematite) precipitate at pH 4.5 to 5 and low Eh (approximately -0.1 V) as a consequence of water-rock reaction. Injection of CO2 decreases pH to approximately 3.5 and increases Eh by approximately 0.1 V, yielding secondary mineralization of euhedral pyrite instead of iron oxyhydroxides. Carbonate minerals also dissolve and ultimately re-precipitate, as determined by experiments in the Madison Limestone, but pyrite will persist and iron oxyhydroxides will not recrystallize.

Sedimentology and diagenesis of Miocene Lirio Limestone, Isla de Mona, Puerto Rico

DOE Office of Scientific and Technical Information (OSTI.GOV)

Ruiz, H.; Gonzalez, L.A.; Budd, A.F.

1991-03-01

Isla de Mona is a carbonate plateau, 50 mi west of Puerto Rico. The island lies on the southern portion of the Mona Platform. It is composed mostly of two Miocene carbonate units: Isla de Mona Dolomite overlain by Lirio Limestone. The Lirio Limestone was deposited on a sloping erosional surface over the Isla de Mona Dolomite. The Miocene Lirio Limestone consists mostly of backreef sands (packstones) with a reefal sequence (boundstones and grainstones) present in the southwestern portion of the island. The reefal sequence is made up mostly of Stylophora, Porites, and Millepora. Thin, discreet pockets of carbonate mud,more » rich in planktonic foraminifera and radiolarians and mixed with shallow benthic fauna/flora (foraminifera, echinoderms, red algae, and corals) interpreted as storm deposits, are found throughout the unit. An extensive reefal zone can be inferred to be present throughout the southwestern to southern portions of the Mona Platform. The Lirio Limestone is heavily karstified and is riddled with sinkholes on the plateau surfaces and caves around the periphery of the island. Caves are exposed around the periphery of the island, radiating from a depression in the central portions of the Lirio Limestone, near contacts with the Isla de Mona Dolomite, are partially dolomitized. The southwestern outcrops exhibit partial dolomitization throughout. The distribution of sinkholes, seaward caverns, and partial dolomitization of the lowermost Lirio Limestone suggests diagenetic modifications by meteoric fluids in central exposed portions of the island and by marine-meteoric fluids in the lowermost portions of the phreatic lens.« less

Reinterpretation of the peninsular Florida oligocene: An integrated stratigraphic approach

USGS Publications Warehouse

Brewster-Wingard, G. L.; Scott, T.M.; Edwards, L.E.; Weedman, S.D.; Simmons, K.R.

1997-01-01

A very thick (> 300 m) nearly continuous Oligocene section exists in southern peninsular Florida, as revealed by lithostratigraphic, biostratigraphic (mollusks and dinocysts), chronostratigraphic (Sr isotopes) and petrographic analyses of twelve cores and two quarries. The Oligocene deposits in the subsurface of southern Florida are the thickest documented in the southeastern U.S., and they also may represent the most complete record of Oligocene deposition in this region. No major unconformities within the Oligocene section are detected in the southern portion of the peninsula; hiatuses at the Eocene-Oligocene boundary, the early Oligocene-late Oligocene boundary, and the late Oligocene-Miocene boundary, are of limited duration if they exist at all. No significant disconformity is recognized between the Suwannee Limestone and the Arcadia Formation in southern Florida. However, on the east coast of Florida a hiatus of more than 12 m.y., spanning from at least the middle of the early Oligocene to early Miocene is present. The Suwannee Limestone was deposited during the early Oligocene. The top of the Suwannee Limestone appears to be diachronous across the platform. The 'Suwannee' Limestone, previously identified incorrectly as a late Oligocene unit, is herein documented to be early Oligocene and is encompassed in the lower Oligocene Suwannee Limestone. An unnamed limestone, found on the east coast of the peninsula is, at least in part, correlative with the Suwannee Limestone. The Arcadia Formation, basal Hawthorn Group, accounts for a large portion of the Oligocene deposition in southern Florida, spanning the interval from the middle of the early Oligocene to at least the early Miocene. Comparisons of the depositional patterns, and the distribution of dolomite and phosphate within the Suwannee Limestone and the Arcadia Formation, suggest fluctuating sea levels and that the paleo-Gulf Stream played a role in determining the nature and extent of Oligocene deposition in peninsular Florida.

Transport and retention of 14C-perfluorooctanoic acid (PFOA) in saturated limestone and sand porous media: Effects of input concentration, ionic strength and cation type

NASA Astrophysics Data System (ADS)

Xueyan, L.; Gao, B.; Sun, Y.; Wu, J.

2017-12-01

Perfluorooctanoic acid (PFOA) has been used in a wide variety of industrial and consumer product applications. PFOA has been detected around the world at ng/L to μg/L levels in groundwater, and at ng/g levels in soil.The physicochemical properties of porous media were proven to play pivotal roles in determining the transport behavior of various pollutants. It is anticipated that physicochemical properties of porous media will strongly influence the transport behavior of PFOA. In addition, previous investigations have revealed that input concentration significantly influence the transport behavior of nanoparticles and antibiotics. Thus, this study was designed experimentally and fundamentally to gain insight into transport and retention of PFOA in various porous medias at different input concentrations, solution IS and cation type. Unlike in quartz sand porous media, the BTCs in limestone porous media exhibited increasing retention rate and high degree of tailing in limestone porous media. Results showed that higher relative retention occurred in limestone porous media than in quartz sand porous media under the same solution chemistry. This result was attributed to the less negative zeta-potentials, rougher surface and larger specific surface area, and the presence of hydroxyl groups and organic matters of limestone grains. Higher ionic strength and Ca2+ had little impact on the mobility of PFOA in quartz sand porous media, but significantly enhanced the retention of PFOA in limestone porous media. The difference is likely due to the compression of the electrical double layer, and the surface-charge neutralization and cation-bridging effect of Ca2+. Higher input concentration resulted in lower relative PFOA retention in limestone porous media, but the influence were insignificant in quartz sand porous media. This effect is likely because attachment sites in limestone responced to the variety of input concentration differently than quartz.

Geology of the surficial aquifer system, Broward County, Florida; lithologic logs

USGS Publications Warehouse

Causaras, C.R.

1985-01-01

The geologic framework of the surficial aquifer system, of which the Biscayne aquifer is the major component in Broward County, Florida, is presented in eight geologic cross sections. The cross sections are based on detailed lithologic logs of 27 test wells that were drilled, in the summer of 1981, through the sediments overlying the relatively impermeable units of the Hawthorn Formation, of Miocene age. The cross sections show the aquifer system as a wedge-shaped sequence of Cenozoic sediments. The aquifer thickness gradually decreases from more than 400 feet along the coast to about 160 feet in the west and southwest parts of Broward County. The sediments that comprise the aquifer system range in age from Pliocene to Pleistocene and are assigned to the following stratigraphic units from bottom to top: Tamiami Formation, Caloosahatchee Marl, Fort Thompson Formation, Key Largo Limestone, Anastasia Formation, Miami Oolite, and Pamlico Sand. (USGS)

Lenticular stretch structures in eastern Nevada - possible trapping mechanism in supposed graben

DOE Office of Scientific and Technical Information (OSTI.GOV)

Walker, C.T.; Dennis, J.G.; Lumsden, W.W.

Eastern Nevada is widely recognized as a region of tectonic extension. The dominant structures are generally agreed to be low-dipping, younger over older faults and steeper listric faults that are responsible for the basins (grabens) and ranges (horsts). In the Schell Creek-Duck Creek Range, east of Ely, and in the White Pine Range, southwest of Ely, small lenticular structures bounded by tectonic discontinuities can be clearly seen in the field. These lenticular units, or stretch structures, range in length from a few meters to more than 200 m. All lenticular stretch structures that can be clearly seen in the fieldmore » are stratigraphically restricted; the stretched formations are the Eureka Quartzite, the Pilot Shale, the Joana Limestone, and the Chainman Shale. Still larger stretch structures, which may include several formations, are inferred, and the authors suggest that extension has created lenticular structures at all scales. The Duck Creek and Schell Creek Ranges east of Ely consist mostly of Devonian and older rocks. They are separated by a topographically lower area containing mostly Mississippian and Pennsylvanian rocks. This structure, which separates the ranges, has been referred to as a graben, but field evidence suggests that it is a large-scale lenticular stretch structure. Unlike a true graben, the structure does not extend downward. For example, in several places within the supposed graben, Cambrian and Ordovician rocks project through a cover of Carboniferous Chainman Shale and Ely Limestone, suggesting the Chainman-Ely is a thin sheet underlain by Cambrian-Ordovician rocks. Accordingly, they suggest that extension in the Duck Creek-Schell Creek Ranges stretched the formations into lenticular bodies. Between the Duck Creek and Schell Creek Ranges, the Cambrian-Ordovician is attenuated, and the resulting tectonic depression is occupied by a lenticular mass of Carboniferous rocks.« less

Nitrogen-isotope analysis of groundwater nitrate in carbonate aquifers: Natural sources versus human pollution

NASA Astrophysics Data System (ADS)

Kreitler, Charles W.; Browning, Lawrence A.

1983-02-01

Results of nitrogen-isotope analyses of nitrate in the waters of the Cretaceous Edwards aquifer in Texas, U.S.A., indicate that the source of the nitrate is naturally-occurring nitrogen compounds in the recharge streams. In contrast, nitrogen isotopes of nitrate in the fresh waters of the Pleistocene Ironshore Formation on Grand Cayman Island, West Indies, indicate that human wastes are the source of the nitrate. The Cretaceous Edwards Limestone is a prolific aquifer that produces principally from fracture porosity along the Balcones Fault Zone. Recharge is primarily by streams crossing the fault zone. Rainfall is ˜ 70 cm yr. -1, and the water table is generally deeper than 30 m below land surface. The δ15 N of 73 samples of nitrate from Edwards waters ranged from + 1.9 to + 10‰ with an average of + 6.2‰. This δ15 N range is within the range of nitrate in surface water in the recharge streams ( δ 15N range = + 1 to + 8.3‰ ) and within the range of nitrate in surface water from the Colorado River, Texas, ( δ 15N range = + 1 to + 11‰ ). No sample was found to be enriched in 15N, which would suggest the presence of nitrate from animal waste ( δ 15N range = + 10 to + 22‰ ). The Ironshore Formation contains a small freshwater lens that is recharged entirely by percolation through the soil. Average rainfall is 165 cm yr. -1, and the water table is within 3 m of land surface. The δ15 N of four nitrate samples from water samples of the Ironshore Formation ranged from + 18 to + 23.9‰, which indicates a cesspool/septictank source of the nitrate. Limestone aquifers in humid environments that are recharged by percolation through the soil appear to be more susceptible to contamination by septic tanks than are aquifers in subhumid environments that feature thick unsaturated sections and are recharged by streams.

ARD remediation with limestone in a CO2 pressurized reactor

USGS Publications Warehouse

Sibrell, Philip L.; Watten, Barnaby J.; Friedrich, Andrew E.; Vinci, Brian J.

2000-01-01

We evaluated a new process for remediation of acid rock drainage (ARD). The process treats ARD with intermittently fluidized beds of granular limestone maintained within a continuous flow reactor pressurized with CO2. Tests were performed over a thirty day period at the Toby Creek mine drainage treatment plant, Elk County, Pennsylvania in cooperation with the Pennsylvania Department of Environmental Protection. Equipment performance was established at operating pressures of 0, 34, 82, and 117 kPa using an ARD flow of 227 L/min. The ARD had the following characteristics: pH, 3.1; temperature, 10 °C; dissolved oxygen, 6.4 mg/L; acidity, 260 mg/L; total iron, 21 mg/L; aluminum, 22 mg/L; manganese, 7.5 mg/L; and conductivity, 1400 μS/cm. In all cases tested, processed ARD was net alkaline with mean pH and alkalinities of 6.7 and 59 mg/L at a CO2 pressure of 0 kPa, 6.6 and 158 mg/L at 34 kPa, 7.4 and 240 mg/L at 82 kPa, and 7.4 and 290 mg/L at 117 kPa. Processed ARD alkalinities were correlated to the settled bed depth (p<0.001) and CO2 pressure (p<0.001). Iron, aluminum, and manganese removal efficiencies of 96%, 99%, and 5%, respectively, were achieved with filtration following treatment. No indications of metal hydroxide precipitation or armoring of the limestone were observed. The surplus alkalinity established at 82 kPa was successful in treating an equivalent of 1136 L/min (five-fold dilution) of the combined three ARD streams entering the Toby Creek Plant. This side-stream capability provides savings in treatment unit scale as well as flexibility in treatment effect. The capability of the system to handle higher influent acidity was tested by elevating the acidity to 5000 mg/L with sulfuric acid. Net alkaline effluent was produced, indicating applicability of the process to highly acidic ARD.

Calcium silicate cement sorbent for H/sub 2/S removal and improved gasification processes. Annual progress report, October 1, 1981-September 30, 1982

DOE Office of Scientific and Technical Information (OSTI.GOV)

Yoo, H.J.; Steinberg, M.

1982-10-01

Commercial calcium silicate bearing Portland cement type III (PC III), in the form of agglomerated cement sorbent (ACS) pellets, is being investigated for in-situ desulfurization of fuel gases and for improved coal gasification. The preparation procedure and conditions for pelletizing agglomerated cement sorbent (ACS) by a low energy, low cost agglomeration technique have been modified using a two-stage pelletization procedure, which yields ACS pellets of greater mechanical strength. A 40 mm ID bench scale fluidized bed gasifier (FBG) was used to determine sulfur removal efficiency of ACS pellets as well as their attrition resistance, using a simulated gas mixture. Thesemore » tests show that 90% or more of the sulfur removal from the gas is achieved until 35% of the ACS pellet is sulfidated and that it has excellent attrition resistance (less than 0.1% wt loss) during cyclic tests excluding the first conditioning cycle. The gasification of coal by partial oxidation with air to low Btu gas was conducted in a 1-inch bench scale FBG unit by our collaborator, the Foster Wheeler Corporation (FWC). At temperatures between 800/sup 0/C and 950/sup 0/C the efficiency of coal gasification is improved by as much as 40% when ACS pellets are used compared to the use of Greer limestone. At the same time the sulfur removal efficiency is increased from 50 to 65% with Greer limestone to over 95% with the ACS pellets. The test on sulfur fixation characteristics of the sorbent in the 1-inch FBG unit using a simulated gas also shows that the ACS pellet is much more reactive toward H/sub 2/S than Greer limestone. The ability of ACS pellets to simultaneously desulfurize and improve the gasification efficiency of coal in FBG justifies further investigation.« less

On the use of a laser ablation as a laboratory seismic source

NASA Astrophysics Data System (ADS)

Shen, Chengyi; Brito, Daniel; Diaz, Julien; Zhang, Deyuan; Poydenot, Valier; Bordes, Clarisse; Garambois, Stéphane

2017-04-01

Mimic near-surface seismic imaging conducted in well-controlled laboratory conditions is potentially a powerful tool to study large scale wave propagations in geological media by means of upscaling. Laboratory measurements are indeed particularly suited for tests of theoretical modellings and comparisons with numerical approaches. We have developed an automated Laser Doppler Vibrometer (LDV) platform, which is able to detect and register broadband nano-scale displacements on the surface of various materials. This laboratory equipment has already been validated in experiments where piezoelectric transducers were used as seismic sources. We are currently exploring a new seismic source in our experiments, a laser ablation, in order to compensate some drawbacks encountered with piezoelectric sources. The laser ablation source is considered to be an interesting ultrasound wave generator since the 1960s. It was believed to have numerous potential applications such as the Non-Destructive Testing (NDT) and the measurements of velocities and attenuations in solid samples. We aim at adapting and developing this technique into geophysical experimental investigations in order to produce and explore complete micro-seismic data sets in the laboratory. We will first present the laser characteristics including its mechanism, stability, reproducibility, and will evaluate in particular the directivity patterns of such a seismic source. We have started by applying the laser ablation source on the surfaces of multi-scale homogeneous aluminum samples and are now testing it on heterogeneous and fractured limestone cores. Some other results of data processing will also be shown, especially the 2D-slice V P and V S tomographic images obtained in limestone samples. Apart from the experimental records, numerical simulations will be carried out for both the laser source modelling and the wave propagation in different media. First attempts will be done to compare quantitatively the experimental data with simulations. Meanwhile, CT-scan X-ray images of these limestone cores will be used to check the relative pertinences of velocity tomography images produced by this newly developed laser ablation seismic source.

Construction, geologic, and water-level data for observation wells near Brentwood, Williamson County, Tennessee

USGS Publications Warehouse

Hanchar, Dorothea Withington

1989-01-01

Thirty-four observation wells were installed at 17 sites in the area of a hazardous-waste disposal site near Brentwood, in Williamson County, Tennessee. These wells were installed to supplement data collected from domestic wells in the area, to help define the geology of the study area and to determine the water levels. Both lithologic and geophysical logs were obtained for each well drilled to help define the formations encountered. Four limestone units, corresponding to the Bigby-Cannon limestone, the Hermitage Formation, the Carters Limestone (including the T-3 bentonite), and the Lebanon Limestone, were described from well cuttings and borehole geophysical logs. Water levels have been collected at both the shallow and deep wells at each site. (USGS)

Hydrogeological, Hydrogeochemical and Isotope Geochemical Features of the Geothermal Waters in Seferihisar and Environs, Western Anatolia, Turkey

NASA Astrophysics Data System (ADS)

Özgür, Nevzat; Aras Pala, Ebru; Degirmenci, Saliha

2017-12-01

The study area of Seferihisar is located within the Izmir-Ankara suture in the NW of the Menderes Massif in western Anatolia, Turkey. The Paleozoic metamorphic rocks of the Menderes Massif form the basement rocks in the area which are overlain by 760 m thick Izmir-flysch series consisting of metamorphic rocks, limestones and ultrabasic rocks tectonically. The Pliocene Bahçecik formation which consists of an alternation of conglomerates, sandstones, claystones, lignite and limestones and shows a thickness of 300 m overlies the (İzmir) flysch series discordantly. This is overlain by 430 m thick Yeniköy formation composed of conglomerates, sandstones, claystones and clayey limestones discordantly. The Miocene volcanic rocks of Cumaovası overlie the Yeniköy formation concordantly which are overlain by alluvium and travertine deposits. Geothermal waters which are observed in the localities of Tuzla, Cumalı, Doğanbey and Karakoç are associated with NE-SW trending faults in the area. The geothermal waters in the area are considered as Na-Cl or Na-Cl-HCO3 type waters. The geothermal waters of Seferihisar and environs are identified to be Na+K>Ca>Mg dominant cations and Cl>HCO3>SO4 dominant anions. According to the diagram of Na/100-K/100-√Mg, a certainly part of the thermal waters can be considered as equilibrated thermal waters during some waters are of immature waters. According to the results of geochemical thermometers, the reservoir temperatures of thermal waters range from 150 to 240°C. The δ2H values of thermal waters are between -13,3 to -31,9, while δ18O values range from -2,55 to -5,70. The tritium contents of thermal waters are between 13 to 64±10 TU.

Environmental Assessment: Installation Development at Vance Air Force Base, Oklahoma

DTIC Science & Technology

2007-04-01

intensity, frequency, and duration. Sound is created by acoustic energy, which produces minute pressure waves that travel through a medium, like...acoustic energy increases, the intensity or amplitude of these pressure waves increase, and the ear senses louder noise. The unit used to measure the...shale, siltstone, sandstone, limestone, and dolomite ranging in age from Cambrian-Ordovician through Permian. These sedimentary units rest upon the Pre

An innovative carbonate coprecipitation process for the removal of zinc and manganese from mining impacted waters

USGS Publications Warehouse

Sibrell, P.L.; Chambers, M.A.; Deaguero, A.L.; Wildeman, T.R.; Reisman, D.J.

2007-01-01

Although mine drainage is usually thought of as acidic, there are many cases where the water is of neutral pH, but still contains metal species that can be harmful to human or aquatic animal health, such as manganese (Mn) and zinc (Zn). Typical treatment of mine drainage waters involves pH adjustment, but this often results in excessive sludge formation and removal of nontoxic species such as magnesium and calcium. Theoretical consideration of the stability of metal carbonate species suggests that the target metals could be removed from solution by coprecipitation with calcium carbonate. The U.S. Geological Survey has developed a limestone-based process for remediation of acid mine drainage that increases calcium carbonate saturation. This treatment could then be coupled with carbonate coprecipitation as an innovative method for removal of toxic metals from circumneutral mine drainage waters. The new process was termed the carbonate coprecipitation (CCP) process. The CCP process was tested at the laboratory scale using a synthetic mine water containing 50 mg/L each of Mn and Zn. Best results showed over 95% removal of both Mn and Zn in less than 2 h of contact in a limestone channel. The process was then tested on a sample of water from the Palmerton zinc superfund site, near Palmerton, Pennsylvania, containing over 300 mg/L Zn and 60 mg/L Mn. Treatment of this water resulted in removal of over 95% of the Zn and 40% of the Mn in the limestone channel configuration. Because of the potential economic advantages of the CCP process, further research is recommended for refinement of the process for the Palmerton water and for application to other mining impacted waters as well. ?? Mary Ann Liebert, Inc.

Larger foraminifera of the Devil's Den and Blue Hole sinkholes, Florida

NASA Astrophysics Data System (ADS)

Cotton, Laura J.; Eder, Wolfgang; Floyd, James

2018-03-01

Shallow-water carbonate deposits are well-known from the Eocene of the US Gulf Coast and Caribbean. These deposits frequently contain abundant larger benthic foraminifera (LBF). However, whilst integrated stratigraphic studies have helped to refine the timing of LBF overturning events within the Tethys and Indo-Pacific regions with respect to global bio- and chemo-stratigraphic records, little recent work has been carried out in the Americas. The American LBF assemblages are distinctly different from those of Europe and the Indo-Pacific. It is therefore essential that the American bio-province is included in studies of LBF evolution, biodiversity and climate events to understand these processes on a global scale.Here we present the LBF ranges from two previously unpublished sections spanning 35 and 29 m of the upper Eocene Ocala limestone, as the early stages of a larger project addressing the taxonomy and biostratigraphy of the LBF of Florida. The study indicates that the lower member of the Ocala limestone may be Bartonian rather than Priabonian in age, with implications for the biostratigraphy of the region. In addition, the study highlights the need for multiple sites to assess the LBF assemblages and fully constrain ranges across Florida and the US Gulf and suggests potential LBF events for future integrated stratigraphic study.

Cyclicity in Upper Mississippian Bangor Limestone, Blount County, Alabama

DOE Office of Scientific and Technical Information (OSTI.GOV)

Bronner, R.L.

1988-01-01

The Upper Mississippian (Chesterian) Bangor Limestone in Alabama consists of a thick, complex sequence of carbonate platform deposits. A continuous core through the Bangor on Blount Mountain in north-central Alabama provides the opportunity to analyze the unit for cyclicity and to identify controls on vertical facies sequence. Lithologies from the core represent four general environments of deposition: (1) subwave-base, open marine, (2) shoal, (3) lagoon, and (4) peritidal. Analysis of the vertical sequence of lithologies in the core indicates the presence of eight large-scale cycles dominated by subtidal deposits, but defined on the basis of peritidal caps. These large-scale cyclesmore » can be subdivided into 16 small-scale cycles that may be entirely subtidal but illustrate upward shallowing followed by rapid deepening. Large-scale cycles range from 33 to 136 ft thick, averaging 68 ft; small-scale cycles range from 5 to 80 ft thick and average 34 ft. Small-scale cycles have an average duration of approximately 125,000 years, which is compatible with Milankovitch periodicity. The large-scale cycles have an average duration of approximately 250,000 years, which may simply reflect variations in amplitude of sea level fluctuation or the influence of tectonic subsidence along the southeastern margin of the North American craton.« less

25 CFR 212.3 - Definitions.

Code of Federal Regulations, 2012 CFR

2012-04-01

..., cinders, granite, building stone, limestone, clay, silt, or any other energy or non-energy mineral... treatment of minerals; Provided, when sand, gravel, pumice, cinders, granite, building stone, limestone...

25 CFR 212.3 - Definitions.

Code of Federal Regulations, 2014 CFR

2014-04-01

..., cinders, granite, building stone, limestone, clay, silt, or any other energy or non-energy mineral... treatment of minerals; Provided, when sand, gravel, pumice, cinders, granite, building stone, limestone...

Kerford Limestone Company

EPA Pesticide Factsheets

The EPA is providing notice of a proposed Administrative Penalty Assessment against Kerford Limestone Company, for alleged violations at the facility located at 36111 Fletcher Avenue, Weeping Water NE 68463.

Fluids along the North Anatolian Fault, Niksar basin, north central Turkey: Insight from stable isotopic and geochemical analysis of calcite veins

NASA Astrophysics Data System (ADS)

Sturrock, Colin P.; Catlos, Elizabeth J.; Miller, Nathan R.; Akgun, Aykut; Fall, András; Gabitov, Rinat I.; Yilmaz, Ismail Omer; Larson, Toti; Black, Karen N.

2017-08-01

Six limestone assemblages along the North Anatolian Fault (NAF) Niksar pull-apart basin in northern Turkey were analyzed for δ18OPDB and δ13CPDB using bulk isotope ratio mass spectrometry (IRMS). Matrix-vein differences in δ18OPDB (-2.1 to 6.3‰) and δ13CPDB (-0.9 to 4.6‰) suggest a closed fluid system and rock buffering. Veins in one travertine and two limestone assemblages were further subjected to cathodoluminescence, trace element (Laser Ablation Inductively Coupled Plasma Mass Spectrometry) and δ18OPDB (Secondary Ion Mass Spectrometry, SIMS) analyses. Fluid inclusions in one limestone sample yield Th of 83.8 ± 7.3 °C (±1σ, mean average). SIMS δ18OPDB values across veins show fine-scale variations interpreted as evolving thermal conditions during growth and limited rock buffering seen at a higher-resolution than IRMS. Rare earth element data suggest calcite veins precipitated from seawater, whereas the travertine has a hydrothermal source. The δ18OSMOW-fluid for the mineralizing fluid that reproduces Th is +2‰, in range of Cretaceous brines, as opposed to negative δ18OSMOW-fluid from meteoric, groundwater, and geothermal sites in the region and highly positive δ18OSMOW-fluid expected for mantle-derived fluids. Calcite veins at this location do not record evidence for deeply-sourced metamorphic and magmatic fluids, an observation that differs from what is reported for the NAF elsewhere along strike.

Ultrasonic-assisted conversion of limestone into needle-like hydroxyapatite nanoparticles.

PubMed

Klinkaewnarong, Jutharatana; Utara, Songkot

2018-09-01

Needle-like hydroxyapatite nanoparticles were successfully synthesized via a reaction between calcium oxide (CaO) that was obtained from calcined limestone and orthophosphoric acid (H 3 PO 4 ) under ultrasonic irradiation at 25 °C. The reaction systems were exposed to ultrasonic waves of 20 kHz for various times ranging from 0 to 4 h. The initial and final pH values of the mixtures of CaO and H 3 PO 4 solution were continuously observed (pH < 4.0) after ultrasonic irradiation. The powder was then dried at 60 °C and calcined at 300 °C for 3 h (3 °C/min). The products were characterized using X-ray diffraction (XRD), Fourier transform infrared spectroscopy (FTIR) and transmission electron microscopy (TEM). The results showed that the formation of needle-like hydroxyapatite (HAp) nanoparticles was substantially accelerated compared with the reaction without ultrasonic irradiation. The HAp phase was increasingly visible with longer ultrasonic irradiation time compared with the monetite phase (CaHPO 4 ). This suggests that ultrasonic waved induced a phase transition from the monetite to HAp phase. A smaller needle-like structure of HAp (diameter ∼ 7.4 nm) with a lower contamination of monetite phase was obtained following sonication for 3 h. This study shows that Thai limestone can used as a starting material for synthesizing needle-like HAp nanoparticles with the aid of ultrasonic methods. Copyright © 2018 Elsevier B.V. All rights reserved.

Transport and retention of engineered Al2O3, TiO2, and SiO2 nanoparticles through various sedimentary rocks

PubMed Central

Esfandyari Bayat, Ali; Junin, Radzuan; Shamshirband, Shahaboddin; Tong Chong, Wen

2015-01-01

Engineered aluminum oxide (Al2O3), titanium dioxide (TiO2), and silicon dioxide (SiO2) nanoparticles (NPs) are utilized in a broad range of applications; causing noticeable quantities of these materials to be released into the environment. Issues of how and where these particles are distributed into the subsurface aquatic environment remain as major challenges for those in environmental engineering. In this study, transport and retention of Al2O3, TiO2, and SiO2 NPs through various saturated porous media were investigated. Vertical columns were packed with quartz-sand, limestone, and dolomite grains. The NPs were introduced as a pulse suspended in aqueous solutions and breakthrough curves in the column outlet were generated using an ultraviolet-visible spectrophotometer. It was found that Al2O3 and TiO2 NPs are easily transported through limestone and dolomite porous media whereas NPs recoveries were achieved two times higher than those found in the quartz-sand. The highest and lowest SiO2-NPs recoveries were also achieved from the quartz-sand and limestone columns, respectively. The experimental results closely replicated the general trends predicted by the filtration and DLVO calculations. Overall, NPs mobility through a porous medium was found to be strongly dependent on NP surface charge, NP suspension stability against deposition, and porous medium surface charge and roughness. PMID:26373598

Assessment of postcrumble addition of limestone and calcium-specific appetite in broilers during the starter phase1

PubMed Central

Li, W.; Angel, R.; Kim, S.-W.; Jiménez-Moreno, E.; Proszkowiec-Weglarz, M.; Iglesias, B. F.; Wilkinson, S. J.; Cowieson, A. J.

2014-01-01

A study was done to determine whether broilers can regulate Ca intake when limestone is provided separately or mixed with a crumbled feed of variable Ca and P content, and the influence of this on performance and apparent ileal digestibility (AID) of Ca and P (AIDP). Twelve crumbled diets were fed from 10 to 20 d of age (8 replicates, 8 broilers/replicate). Diets A to D contained 0.28% nonphytate P (nPP) and 0.27, 0.51, 0.77, and 1.02% Ca, respectively. Diets E to H contained 0.48% nPP and 0.41, 0.51, 0.77, and 1.02% Ca, respectively. A large particle size limestone was mixed manually to the crumbled diet on a daily basis to achieve 1.02% total Ca in diets A to H. Diets I to L had the same Ca and nPP as diets A to D, but limestone was provided in a separate feeder to assess spatial importance of limestone supply. Limestone consumption, provided in a separate feeder, decreased as Ca concentration increased in the crumble diet (P < 0.05). Calcium intake increased as Ca concentration in crumbled diets increased (P < 0.05). Increased tibia ash and decreased AIDP were observed as Ca intake increased (P < 0.05). When limestone was added to diets containing 0.28% nPP postcrumble, Ca intake (6.38 g/bird), tibia ash (717 mg/bone), and AIDP (39.78%) were not affected by crumbled diet Ca concentration or consumed Ca. Broilers fed diets containing 0.48% nPP and limestone mixed with the crumble, Ca intake changed (5.96, 6.93, 6.59, and 6.04 g/bird for crumble diet with 0.41, 0.51, 0.77, and 1.02% Ca, respectively). Increasing Ca concentration in the crumble from 0.41 to 1.02% resulted in greater tibia ash (875 mg/bone) but lower AIDP (P < 0.05), although Ca intake was similar. In conclusion, when large particle size limestone was provided ad libitum, the ability of broilers to select for Ca was not sufficient to meet their requirement when crumble Ca was less than 0.77%. The AIDP was highest in birds fed the 0.27% Ca concentration diet. PMID:25085931

Geology of Raymond Canyon, Sublette Range, western Wyoming

DOE Office of Scientific and Technical Information (OSTI.GOV)

Shoemaker, W.A.

1984-07-01

Raymond Canyon is located on the west side of the Sublette Range, Lincoln County, Wyoming. The study area is just east of the Idaho border and 10 mi (16 km) southeast of Geneva, Idaho. Formations exposed range in age from Late Pennsylvanian to Tertiary (Pliocene) and include: the lower part of the Wells Formation (Pennsylvanian, total thickness 720 ft or 219 m); the upper part of the Wells Formation and the Phosphoria Formation (both Permian, 153-210 ft or 47-64 m); the Dinwoody Formation (185 ft or 56 m); Woodside Shale (540 ft or 165 m); Thaynes Limestone (2345 ft ormore » 715 m); and Ankareh Formation (930 ft or 283 m), all of Triassic age; the Nugget Sandstone (1610 ft or 491 m), Twin Creek Limestone, Preuss Sandstone, and Stump Formation, all of Jurassic age; and the Salt Lake formation and the Sublette conglomerate, both Pliocene postorogenic continental deposits. Generally these formations are thinner than in nearby areas to the west and northwest. Raymond Canyon lies on the upper plate of the Tunp thrust and the lower plate of the Crawford thrust of the Idaho-Wyoming thrust belt. Thus, it lies near the middle of the imbricate stack of shallowly dipping thrust faults that formed in the late Mesozoic. Study of the stratigraphy, structure, petrography, and inferred depositional environments exposed in Raymond Canyon may be helpful to those engaged in energy development in the Idaho-Wyoming thrust belt.« less

Carbonate chemistry of surface waters in a temperate karst region: the southern Yorkshire Dales, UK

NASA Astrophysics Data System (ADS)

Pentecost, Allan

1992-11-01

A detailed study of surface water chemistry is described from an important limestone region in northern England. Major ions and pH were determined for 485 sites (springs, seeps, streams, rivers and lakes) during summertime. The saturation state of the waters with respect to calcite was determined as the calcite saturation ratio (Ω). An unexpectedly large number of samples were found to be supersaturated (65.5% of the 268 km of watercourses surveyed). As a consequence, several streams entering major cave systems were incapable of further limestone solution, at least during periods of low flow. Many waters were supersaturated from their source and some deposited travertine. A significant negative correlation was found between spring discharge and both (Ω) and pH. Supersaturation was caused primarily by atmospheric degassing, with some contribution from aquatic plant photosynthesis. The median total dissolved inorganic carbon and Ca concentrations were 2.49 and 1.35 millimoles 1 -1 respectively. Calcium originated exclusively from limestone, and carbon dioxide mainly from the soil and dissolved limestone. South facing catchments provided springwaters with significantly higher levels of TDIC and Ca when compared with north facing catchments. The study suggests that acid rain made a measurable contribution to limestone dissolution. Carboniferous limestone denudation rates were estimated as 54 to 63 m 3 km -2 a -1 (54 to 63 mm 1000 years -1). About 50% of the Mg came from limestone and the remainder, together with most K, Na, SO 4 and Cl from precipitation. Concentrations of dissolved nutrients were low, medians for NO 3, NH 4, total PO 4 and SiO 3 were 24 μmol, 1.4 μmol, 0.64 μmol and 15.5 μmol 1 -1 respectively. The concentration of a further 23 trace elements was determined.

Porosity and Permeability Evolution in Cemented Rock Cores under Reactive Flowing Conditions: Comparative Analysis between Limestone and Sandstone Host Rocks

NASA Astrophysics Data System (ADS)

Cao, P.; Karpyn, Z.; Li, L.

2013-12-01

CO2-brine has the potential to alter wellbore cement in depleted oil and gas reservoirs under geological CO2 sequestration conditions. A better understanding of CO2-brine-cement-rock interaction is needed to evaluate the seal integrity of candidate sequestration formation in the long run. This work investigates possible alteration of wellbore cement when bonded by different host formation rock upon exposure to CO2-saturated brine. Composite cement-sandstone and cement-limestone core samples were created to perform reactive coreflood experiments. After an eight-day dynamic flow-through period, both cores had a similar extent of porosity increase, while the cement-limestone core experienced a ten-fold higher increase in permeability. With the aid of X-ray Micro-CT imaging and Scanning Electron Microscopy, it is observed that cement underwent greater degradation at the cement-sandstone interface. Degradation of cement-limestone core mainly took place on the host rock matrix. Worm holes were developed and a solution channel was formed in the limestone, creating a dominant flow path that altered both flow and reaction behavior. Limestone buffered the injected acidic brine preventing further deterioration of cement near the core outlet. Changes in fluid chemistry of limestone and sandstone coreflood effluents are compared. Results from this work are aimed at assisting the development and validation of robust reactive transport models through direct measurement of cemented rock core porosity and permeability evolution as well as the effluent aqueous chemistry change. This will subsequently improve predictive capabilities of reactive transport models associated with CO2 sequestration in geologic environments. Permeability Evolution of Cement-Rock Core Sample during Dynamic Flow of CO2-Brine

Ground-water resources investigation in the Amran Valley, Yeman Arab Republic

USGS Publications Warehouse

Tibbitts, G. Chase; Aubel, James

1980-01-01

A program of hydrologic studies and exploratory drilling was conducted intermittently between 1974 and 1978 to evaluate the water-bearing properties of the unconsolidated alluvial sediments and associated rocks in the semi-arid Amran Valley basin, an 800-square-kilometer area in north-central Yemen Arab Republic. Inventory data from 395 wells were compiled, observation well and rain-gage networks were established and 16 standard complete chemical analyses were made for samples from selected wells. The water resources of the area were overexploited. The chemical quality of the water is generally good. Four aquifer tests were run to determine transmissivity and storage characteristics. The pumping tests show that groundwater occurs under semi-confined leaky-aquifer conditions in the valley fill. Wells drilled in the alluvial fill of the south-central part of the valley have the highest yields. Wells penetrating the limestone and volcanic rocks generally have little or no yield except in fracture zones. Basalt flows occur interbedded with the wadi alluvium at several depths. Cropping out rocks in the Amran Valley range in age from late Jurassic to Holocene. (USGS)

Geological and geomechanical properties of the carbonate rocks at the eastern Black Sea Region (NE Turkey)

NASA Astrophysics Data System (ADS)

Ersoy, Hakan; Yalçinalp, Bülent; Arslan, Mehmet; Babacan, Ali Erden; Çetiner, Gözde

2016-11-01

Turkey located in the Alpine-Himalayan Mountain Belt has 35% of the natural stone reserves of the world and has good quality marble, limestone, travertine and onyx reserves especially in the western regions of the country. The eastern Black Sea Region with a 1.4 million meters cubes reserve has a little role on the natural stone production in the country. For this reason, this paper deals with investigation on the potential of carbonate stone in the region and determination of the geological and geo-mechanical properties of these rocks in order to provide economic contribution to the national economy. While the study sites are selected among the all carbonate rock sites, the importance as well as the representative of the sites were carefully considered for the region. After representative samples were analyzed for major oxide and trace element compositions to find out petrochemical variations, the experimental program conducted on rock samples for determination of both physical and strength properties of the carbonate rocks. The results of the tests showed that there are significant variations in the geo-mechanical properties of the studied rock groups. The density values vary from 2.48 to 2.70 gr/cm3, water absorption by weight values range from 0.07 to 1.15% and the apparent porosity of the carbonate rocks are between 0.19 and 3.29%. However, the values of the UCS shows variation from 36 to 80 MPa. Tensile and bending strength values range from 3.2 to 7.5 MPa and 6.0-9.2 MPa respectively. Although the onyx samples have the lowest values of apparent porosity and water absorption by weight, these samples do not have the highest values of UCS values owing to occurrence of the micro-cracks. The UCS values of the rock samples were also found after cycling tests However, the limestone samples have less than 5% deterioration after freezing-thawing and wetting-drying tests, but travertine and onyx samples have more than 15% deterioration. Exception of the apparent porosity values of travertine samples, all geo-mechanical properties of the studied carbonate rocks were determined in the acceptance values given by Turkish Standards Institute (TSE) for using as a natural dimension stone. After these investigations, it is anticipated that in the near future the number of quarries and factories will increase and more types of natural stones will be discovered in the eastern Black Sea Region and thus this will provide economic contribution to the economy of the country.

Kinetics of autotrophic denitrification process and the impact of sulphur/limestone ratio on the process performance.

PubMed

Kilic, Arzu; Sahinkaya, Erkan; Cinar, Ozer

2014-01-01

Kinetics of sulphur-limestone autotrophic denitrification process in batch assays and the impact of sulphur/limestone ratio on the process performance in long-term operated packed-bed bioreactors were evaluated. The specific nitrate and nitrite reduction rates increased almost linearly with the increasing initial nitrate and nitrite concentrations, respectively. The process performance was evaluated in three parallel packed-bed bioreactors filled with different sulphur/limestone ratios (1:1, 2:1 and 3:1, v/v). Performances of the bioreactors were studied under varying nitrate loadings (0.05 - 0.80 gNO(-)(3) - NL⁻¹ d⁻¹) and hydraulic retention times (3-12 h). The maximum nitrate reduction rate of 0.66 g L⁻¹ d⁻¹ was observed at the loading rate of 0.80 g NO(-)(3) - N L⁻¹ d⁻¹ in the reactor with sulphur/limestone ratio of 3:1. Throughout the study, nitrite concentrations remained quite low (i.e. below 0.5 mg L⁻¹ NO(-)(2) -N. The reactor performance increased in the order of sulphur/limestone ratio of 3:1, 2:1 and 1:1. Denaturing gradient gel electrophoresis analysis of 16S rRNA genes showed quite stable communities in the reactors with the presence of Methylo virgulaligni, Sulfurimonas autotrophica, Sulfurovum lithotrophicum, Thiobacillus aquaesulis and Sulfurimonas autotrophica related species.

Tidal rhythmites infine-grained Carboniferous limestones, U.S.A.

USGS Publications Warehouse

Archer, A.W.; Feldman, H.R.

1994-01-01

Analyses of fine-grained limestones reveals that many exhibit fine-scale laminations. Laminations can be normally graded and consist of a coarser-grained lower part and a finer-grained upper part. The upper part can also contain finely disseminated organic material. Despite the similarities of such graded laminae to yearly varves and turbidites, it can be demonstrated by use of laminae-thickness periodicities that some graded laminae are reasonably interpreted as the product of tidal processes. Within siliciclastic systems, modern analogues of such processes are available for comparisons. In fine-grained facies of the Salem Limestone (Visean; Indiana, U.S.A.), periodicities observed within sequential-laminae thicknesses indicate a dominant control by neap-spring tidal processes. Similarly, laminae within limestones of the vertebrate-bearing Hamilton paleochannel (Stephanian; Kansas, U.S.) exhibit similar features, including fine-scale tidal bundles. This limestone is noted for the abundance of articulated fish fossils. Carbonates containing articulated fish from the Wild Cow Formation (Stephanian; New Mexico, U.S.), exhibit diffuse laminations; however, closely associated siliciclastic mudstones contain laminae that exhibit tidal periodicities. There are many similarities between tidal periodicities and patterns of lamination thicknesses of these rocks. A tidal interpretation for these rocks allows for localized, very rapid rates of deposition. Such rapid deposition may, in part, help to explain how articulated fish and other vertebrates can become preserved within such fine-grained limestones. ?? 1994.

Hydrologic conditions: Dade County, Florida

USGS Publications Warehouse

Kohout, Francis Anthony; Klein, Howard; Sherwood, C.B.; Leach, Stanley D.

1964-01-01

Thin layers of dense limestone of low permeability that occur near the top of the Biscayne aquifer in the vicinity of the north end of Levee 30 in Dade County, Florida are of hydrologic importance because they retard the downward infiltration of ponded water in Conservation Area No. 3. This retarding effect frequently results in high head differentials across the levee. Tests made in a small area adjacent to Levee 30 indicate that the coefficient of transmissibility of the aquifer is 3,600,000 gpd (gallons per day) per foot, and the coefficient of vertical permeability of the dense limestones is 13 gpd per square foot. If ground-water flow beneath the levee is laminar, the total inflow to the Levee 30 Canal from Conservation Area No. 3 will be about 350 mgd (million gallons per day), or 540 cfs (cubic feet per second), per mile length of levee when the head difference across the levee is 10 feet.

Spatial and layer-controlled variability in fracture networks

NASA Astrophysics Data System (ADS)

Procter, Andrew; Sanderson, David J.

2018-03-01

Topological sampling, based on 1) node counting and 2) circular sampling areas, is used to measure fracture intensity in surface exposures of a layered limestone/shale sequence in north Somerset, UK. This method provides similar levels of precision as more traditional line samples, but is about 10 times quicker and allows characterization of the network topology. Georeferencing of photographs of the sample sites allows later analysis of trace lengths and orientations, and identification of joint set development. ANOVA tests support a complex interaction of within-layer, between-layer and between-location variability in fracture intensity, with the different layers showing anomalous intensity at different locations. This variation is not simply due to bed thickness, nor can it be related to any obvious compositional or textural variation between the limestone beds. These results are used to assess approaches to the spatial mapping of fracture intensity.

Faunas of Mississippian oolitic limestones: Evidence from Salem Limestone, southern Indiana

DOE Office of Scientific and Technical Information (OSTI.GOV)

Feldman, H.R.

In the Salem Limestone of southern Indiana, a correlation exists between the faunal assemblage and abundance of grains with superficial oolitic coatings in grainstones. Coarse, poorly sorted fossiliferous grainstones are dominated by an echinoderm-bryozoan-brachiopod assemblage of fossils with few mollusks. The presence of large whole fossils, such as articulated crinoid calyces, suggest limited transport of skeletal components. Grainstones, dominated by grains with superficial coatings, and foraminifers tend to contain a diverse mollusk-dominated assemblage of gastropods, bivalves, rostroconchs, chitins, and scaphopods. These fossils are disarticulated, but generally are not fragmented even though many of them are thin and delicate. Echinoderms, brachiopods,more » and bryozoans are repsented in the mollusk-domdinated assemblage almost exclusively by well-rounded and coated fragments, suggesting that they are not in situ. The presence of similar molluscan assemblages in other Mississippian coated-grain grainstones from Alabama (the Monteagle Limestone) and Oklahoma (an unnamed limestone) indicates that the assemblage may have been wide-spread. Mississippian grainstones dominated by oolites (which are not prominent in the Salem) generally have very few fossils.« less

Limestone weathering rates accelerated by micron-scale grain detachment

NASA Astrophysics Data System (ADS)

Emmanuel, S.; Levenson, Y.

2014-12-01

The weathering rates of carbonate rocks is often thought to be controlled by chemical dissolution, although some studies have suggested that mechanical erosion could also play an important role. Quantifying the rates of the different processes has proved challenging due to the high degree of variability encountered in both field and lab settings. To determine the rates and mechanisms controlling long-term limestone weathering, we analyse a lidar scan of the Western Wall, a Roman period edifice located in Jerusalem. Weathering rates in fine-grained micritic limestone blocks are up to 2 orders of magnitude higher than the average rates estimated for coarse-grained limestone blocks at the same site. In addition, in experiments that use atomic force microscopy to image dissolving micritic limestone, we show that these higher reaction rates could be due to rapid dissolution along micron-scale grain boundaries, followed by mechanical detachment of tiny particles from the surface. Our analysis indicates that micron-scale grain detachment, rather than pure chemical dissolution, could be the dominant erosional mode for fine-grained rocks in many carbonate terrains.

Extreme limestone weathering rates due to micron-scale grain detachment

NASA Astrophysics Data System (ADS)

Emmanuel, Simon; Levenson, Yael

2014-05-01

Chemical dissolution is often assumed to control the weathering rates of carbonate rocks, although some studies have indicated that mechanical erosion could also play a significant role. Quantifying the rates of the different processes is challenging due to the high degree of variability encountered in both field and lab settings. To measure the rates and mechanisms controlling long-term limestone weathering, we analyse a lidar scan of the Western Wall, a Roman period edifice located in Jerusalem. Surface retreat rates in fine-grained micritic limestone blocks are found to be as much as 2 orders of magnitude higher than the average rates estimated for coarse-grained limestone blocks at the same site. In addition, in experiments that use atomic force microscopy to image dissolving micritic limestone, we show that these elevated reaction rates could be due to rapid dissolution along micron-scale grain boundaries, followed by mechanical detachment of tiny particles from the surface. Our analysis indicates that micron-scale grain detachment, rather than pure chemical dissolution, could be the dominant erosional mode for fine-grained carbonate rocks.

Geologic Setting of Mosul Dam and Its Engineering Implications

DTIC Science & Technology

2007-09-01

thought that an increase in vol- ume, produced during alteration of interbedded anhydrite to gypsum, generated sufficient pressure to fracture the...construction.. ..................................................................23 Figure 8. Geologic sections with water- pressure test values and...contains fragments or clasts of limestone, dolomite , or larger pieces of insoluble rocks of collapsed material. The upper portion of the accumulation

40 CFR Table 8 to Subpart Sssss of... - Continuous Compliance with Operating Limits

Code of Federal Regulations, 2011 CFR

2011-07-01

... activity level of the catalyst at least every 12 months and taking any necessary corrective action, such as... temperature measured during the most recent performance test; and vi. Checking the activity level of the... hopper. c. Maintain the limestone feeder setting at or above the level established during the most recent...

CHEMICALLY ACTIVE FLUID-BED PROCESS FOR SULPHUR REMOVAL DURING GASIFICATION OF HEAVY FUEL OIL - SECOND PHASE

EPA Science Inventory

The report describes the second phase of studies on the CAFB process for desulfurizing gasification of heavy fuel oil in a bed of hot lime. The first continuous pilot plant test with U.S. limestone BCR 1691 experienced local stone sintering and severe production of sticky dust du...

International Symposium on Military Applications of Blast Simulation (5th)

DTIC Science & Technology

1977-06-22

Centre d’Etudes de Grainat, Gramat , France, de- scribed their work in designing a blast simulator with a test section of 12—rn width and 7—rn height...de Gramat , Gramat , France) on the dynamic behavior of limestone. Through a series of high—pressure experiments of the type developed in the recent

EXPERIMENTAL STUDY OF HIGH LEVELS OF SO2 REMOVAL IN ATMOSPHERIC-PRESSURE FUIDIZED-BED COMBUSTORS

EPA Science Inventory

The report describes tests conducted in an atmospheric-pressure-fluidized-bed combustor (FBC) with a cross-section of 1 x 1.6 m) to demonstrate high levels of S02 removal when burning a high-sulfur coal and feeding limestone sorbent for S02 removal. The goal was to achieve 90-plu...

Tracer tests and the structure of permeability in the Corallian limestone aquifer of northern England, UK

NASA Astrophysics Data System (ADS)

Foley, Aidan; Cachandt, Gerd; Franklin, Janine; Willmore, Fergus; Atkinson, Tim

2012-05-01

The Corallian limestone of northern England (UK) is widely exploited for water supplies and exhibits the karstic phenomena of sinking rivers, conduit development and groundwater velocities of several kilometres per day. To test a number of model-derived source protection zones and elucidate contaminant transport mechanisms in the aquifer, three tracer tests were conducted from a set of swallow-holes draining the River Derwent toward public water supply wells in the eastern part of the aquifer. Tracers used included: Enterobacter cloacae (bacteriophage), Photine C (optical brightener), sodium fluorescein (fluorescent dye) and sulphur hexafluoride (dissolved gas), the varying properties of which make them suitable analogues for different types of potential contaminant. Observed tracer transport times and arrival patterns indicate that tracer transport occurs through karstic channels embedded in a network of primary fissures which exert control over tracer concentrations once initial tracer plumes have passed. A dipole flow system is observed between the swallow-holes and the closest abstraction well, whilst previously modelled source protection zones do not accurately reflect either groundwater velocity or those areas of the aquifer supplying the wells. These findings imply that managing such aquifers for potential contamination should rely upon empirical tracer evidence for source-protection zone modelling.

Pacific Enewetak Atoll Crater Exploration (PEACE) program, Enewetak Atoll, Republic of the Marshall Islands; Part 1, Drilling operations and descriptions of boreholes in vicinity of KOA and OAK craters

USGS Publications Warehouse

Henry, T.W.; Wardlaw, B.R.; Skipp, Betty; Major, R. P.; Tracey, J.I.

1986-01-01

Evidence of a post-Cretaceous uplift of the Sioux Quartzite ridge in southeastern South Dakota consists of deformation of the Dakota Formation, Graneros Shale, Greenhorn Limestone, Carlile Shale, and Niobrara Formation of Cretaceous age. The Greenhorn is warped upward about 400 ft on the Sioux Quartzite with a formation dip ranging from 30-50 ft/mi. Elsewhere in eastern South Dakota the dip of the Greenhorn ranges from 3-8 ft/mi. (Author 's abstract)

Genesis of the Doğankuzu and Mortaş Bauxite deposits, Taurides, Turkey: separation of Al, Fe, and Mn and implications for passive margin metallogeny

USGS Publications Warehouse

Öztürk, Hüseyin; Hein, James R.; Hanilçi, Nurullah

2002-01-01

The Taurides region of Turkey is host to a number of important bauxite, Al-rich laterite, and Mn deposits. The most important bauxite deposits, Doğankuzu and Mortaş, are karst-related, unconformity-type deposits in Upper Cretaceous limestone. The bottom contact of the bauxite ore is undulatory, and bauxite fills depressions and sinkholes in the footwall limestone, whereas its top surface is concordant with the hanging-wall limestone. The thickness of the bauxite varies from 1 to 40 m and consists of böhmite, hematite, pyrite, marcasite, anatase, diaspore, gypsum, kaolinite, and smectite. The strata-bound, sulfide- and sulfate-bearing, low-grade lower part of the bauxite ore bed contains pyrite pseudomorphs after hematite and is deep red in outcrop owing to supergene oxidation. The lower part of the bauxite body contains local intercalations of calcareous conglomerate that formed in fault-controlled depressions and sinkholes. Bauxite ore is overlain by fine-grained Fe sulfide-bearing and calcareous claystone and argillaceous limestone, which are in turn overlain by massive, compact limestone of Santonian age. That 50-m-thick limestone is in turn overlain by well-bedded bioclastic limestone of Campanian or Maastrichtian age, rich with rudist fossils. Fracture fillings in the bauxite orebody are up to 1 m thick and consist of bluish-gray-green pyrite and marcasite (20%) with böhmite, diaspore, and anatase. These sulfide veins crosscut and offset the strata-bound sulfide zones. Sulfur for the sulfides was derived from the bacterial reduction of seawater sulfate, and Fe was derived from alteration of oxides in the bauxite. Iron sulfides do not occur within either the immediately underlying or overlying limestone. The platform limestone and shale that host the bauxite deposits formed at a passive margin of the Tethys Ocean. Extensive vegetation developed on land as the result of a humid climate, thereby creating thick and acidic soils and enhancing the transport of large amounts of organic matter to the ocean. Alteration of the organic matter provided CO2 that contributed to formation of a relatively 12C-rich marine footwall limestone. Relative sea-level fall resulted from strike-slip faulting associated with closure of the ocean and local uplift of the passive margin. That uplift resulted in karstification and bauxite formation in topographic lows, as represented by the Doğankuzu and Mortaş deposits. During stage 1 of bauxite formation, Al, Fe, Mn, and Ti were mobilized from deeply weathered aluminosilicate parent rock under acidic conditions and accumulated as hydroxides at the limestone surface owing to an increase in pH. During stage 2, Al, Fe, and Ti oxides and clays from the incipient bauxite (bauxitic soil) were transported as detrital phases and accumulated in the fault-controlled depressions and sinkholes. During stage 3, the bauxitic material was concentrated by repeated desilicification, which resulted in the transport of Si and Mn to the ocean through a well-developed karst drainage system. The transported Mn was deposited in offshore muds as Mn carbonates. The sulfides also formed in stage 3 during early diagenesis. Transgression into the foreland basin resulted from shortening of the ocean basin and nappe emplacement during the latest Cretaceous. During that time bioclastic limestone was deposited on the nappe ramp, which overlapped bauxite accumulation.

Laboratory Testing of a Fluidized-Bed Dry-Scrubbing Process for the Removal of Acidic Gases from a Simulated Incinerator Flue Gas

DTIC Science & Technology

1989-04-01

100 MW). Cost data for two conventional wet processes (limestone and wet lime) are shown in Table 5.1. Table 5.1. Costs for flue gas desulfurization ...Results of short-term dry-scrubbing tests ............... 8 5.1 Costs for flue gas desulfurization systems .............. 15 A.1 Detailed description of...this report is part of an effort by USATHAMA to develop and test a flue gas dry-scrubbing system that can be used as a replacement for wet scrubbers for

In situ observation of fracture processes in high-strength concretes and limestone using high-speed X-ray phase-contrast imaging

DOE Office of Scientific and Technical Information (OSTI.GOV)

Parab, Niranjan D.; Guo, Zherui; Hudspeth, Matthew

The mechanical properties and fracture mechanisms of geomaterials and construction materials such as concrete are reported to be dependent on the loading rates. However, the in situ cracking inside such specimens cannot be visualized using traditional optical imaging methods since the materials are opaque. In this study, the in situ sub-surface failure/damage mechanisms in Cor-Tuf (a reactive powder concrete), a high-strength concrete (HSC) and Indiana limestone under dynamic loading were investigated using high-speed synchrotron X-ray phase-contrast imaging. Dynamic compressive loading was applied using a modified Kolsky bar and fracture images were recorded using a synchronized high-speed synchrotron X-ray imaging set-up.more » Three-dimensional synchrotron X-ray tomography was also performed to record the microstructure of the specimens before dynamic loading. In the Cor-Tuf and HSC specimens, two different modes of cracking were observed: straight cracking or angular cracking with respect to the direction of loading. In limestone, cracks followed the grain boundaries and voids, ultimately fracturing the specimen. Cracks in HSC were more tortuous than the cracks in Cor-Tuf specimens. The effects of the microstructure on the observed cracking behaviour are discussed. This article is part of the themed issue ‘Experimental testing and modelling of brittle materials at high strain rates’.« less

Treatment of acid rock drainage using a sulfate-reducing bioreactor with zero-valent iron.

PubMed

Ayala-Parra, Pedro; Sierra-Alvarez, Reyes; Field, James A

2016-05-05

This study assessed the bioremediation of acid rock drainage (ARD) in flow-through columns testing zero-valent iron (ZVI) for the first time as the sole exogenous electron donor to drive sulfate-reducing bacteria in permeable reactive barriers. Columns containing ZVI, limestone or a mixture of both materials were inoculated with an anaerobic mixed culture and fed a synthetic ARD containing sulfuric acid and heavy metals (initially copper, and later also cadmium and lead). ZVI significantly enhanced sulfate reduction and the heavy metals were extensively removed (>99.7%). Solid-phase analyses showed that heavy metals were precipitated with biogenic sulfide in the columns packed with ZVI. Excess sulfide was sequestered by iron, preventing the discharge of dissolved sulfide. In the absence of ZVI, heavy metals were also significantly removed (>99.8%) due to precipitation with hydroxide and carbonate ions released from the limestone. Vertical-profiles of heavy metals in the columns packing, at the end of the experiment, demonstrated that the ZVI columns still had excess capacity to remove heavy metals, while the capacity of the limestone control column was approaching saturation. The ZVI provided conditions that enhanced sulfate reduction and generated alkalinity. Collectively, the results demonstrate an innovative passive ARD remediation process using ZVI as sole electron-donor. Copyright © 2016 Elsevier B.V. All rights reserved.

Hydrologic monitoring of a waste-injection well near Milton, Florida, June 1975 - June 1977

USGS Publications Warehouse

Pascale, Charles A.; Martin, J.B.

1978-01-01

This report presents the hydraulic and chemical data collected from June 1, 1975, when injection began, to June 30, 1977 through a monitoring program at a deep-well waste-injection system at the American Cyanamid Company's plant near Milton, about 12 miles northwest of Pensacola. The injection system consists of a primary injection well, a standby injection well, and two deep monitor wells all completed open hole in the lower limestone of the Floridan aquifer and one shallow-monitor well completed in the upper limestone of the Floridan aquifer. Two of the monitor wells and the standby injection well are used to observe hydraulic and geochemical effects of waste injection in the injection zone at locations 8,180 feet northeast, 1,560 feet south, and 1,025 feet southwest of the primary injection well. The shallow-monitor well, used to observe any effects in the first permeable zone above the 200-foot-thick confining bed, is 28 feet north of the primary injection well. Since injection began in June 1975, 607 million gallons of treated industrial liquid waste with a pH of 4.6 to 6.3 and containing high concentrations of nitrate, organic nitrogen and carbon have been injected into a saline-water-filled limestone aquifer. Wellhead pressure at the injection well in June 1977 average 137 pounds per square inch and the hydraulic pressure gradient was 0.53 pound per square inch per foot of depth to the top of the injection zone. Water levels rose from 36 to 74 feet at the three wells used to monitor the injection zone during the 25-month period. The water level in the shallow-monitor well declined about 8 feet. No changes were detected in the chemical character of water from the shallow-monitor well and deep-monitor well-north. Increases in concentration of bicarbonate and dissolved organic carbon were detected in water from the deep-test monitor well in February 1976 and at the standby injection well in August 1976. In addition to increases in bicarbonate and dissolved organic carbon, sulfate, total organic nitrogen, and total nitrogen concentrations have also increased substantially in samples from these wells. Nitrogen gas concentrations in water samples collected at the three deep-monitor wells ranged from 19 to 176 milligrams per liter, methane from 4.5 to 11.4 milligrams per liter, and carbon dioxide from 7.7 to 44 milligrams per liter. The most probable number of denitrifying bacteria in water samples collected at the three deep-monitor wells ranged from less than 2 colonies to 17 colonies per 100 milliliters. None of the water samples collected in April 1977 at the three deep-monitor wells showed positive concentrations of acetone, ethanol, methanol, or acrylonitrile.

State summaries: Kentucky

USGS Publications Warehouse

Greb, S.F.; Anderson, W.H.

2006-01-01

Kentucky mines coal, limestone, clay, sand and gravel. Coal mining operations are carried out mainly in the Western Kentucky Coal Field and the Eastern Kentucky Coal field. As to nonfuel minerals, Mississippian limestones are mined in the Mississippian Plateaus Region and along Pine Mountain in southeastern Kentucky. Ordovician and Silurian limestones are mined from the central part of the state. Clay minerals that are mined in the state include common clay, ceramic and ball clays, refractory clay and shale. Just like in 2004, mining activities in the state remain significant.

Estimating Yield and Depth of Burial from Rg (POSTPRINT) Annual Report 2

DTIC Science & Technology

2012-03-20

sec) and are representative of more competent bedrock ( limestone ). Similarly, the Q is lower (2 to 15) to the west of the fault than to the east (15...faster (0.8 to 2 km/sec) and are representative of more competent bedrock ( limestone ). Similarly, the Q is lower (2 to 15) to the west of the fault...similar geologies as detonation. The only exception is the 100-lb C4 shot at GRABS (134 lb TNT equivalent) which propagated in limestone and granite

Kerford Limestone Company - Clean Water Act Public Notice

EPA Pesticide Factsheets

The EPA is providing notice of a proposed Administrative Penalty Assessment against Kerford Limestone Company, for alleged violations at the facility located at 36111 Fletcher Avenue, Weeping Water NE 68463.

Syntectic Reactions involving Limestones and Limestone-Derived Carbonatitic Melts in the Generation of some Peralkalic Magmas: Reflections on Reginald Daly's Insights 100 Years Later

NASA Astrophysics Data System (ADS)

Lentz, D.

2017-12-01

The theoretical analysis of how sedimentary limestones and marbles could melt as a result of infiltrative contact metasomatism associated with silicate magmas, enables reconsideration of the limestone syntectic (assimilation) hypothesis for the origin of some peralkalic rocks. Reginald Daly's syntectic model published in detail in early 1918 fell out of favor because experimental evidence from the early 1960's suggested; 1) that limestone assimilation would increase P(CO2) and cause solidification of the silicate intrusion, 2) that there is a thermal barrier between silica-saturated and undersaturated magmas that would inhibit extensive desilication of the magma, and 3) the endothermic decarbonation reactions would require heat via magmatic crystallization of near-solidus magmas. However, these concerns were not as critical for high-T mafic melts relative to more low-T silicic melts, although most subsequent researchers dismissed syntexis as isotopic arguments also seemed robust. However, skarn-related limestone melts can interact much more easily with silicate magma, resulting in calc-silicate-forming (endoskarn-like) limestone syntectic (desilication - calcification-magnesification processes) decarbonation reactions with compositional evolution into the silica-undersaturated field. If mafic in composition originally when syntectically modified, then the CO2-bearing derivative peralkalic melt may subsequently react with the dominant volume magma or fractionate separately into a more evolved composition. As well, an increase in P(CO2) within the modified silicate fraction coupled with compositional evolution to more silica-undersaturated compositions enhances the stability of the immiscible, extremely low viscosity carbonate melt fraction. In addition, dynamic interaction of these co-existing immiscible melts (analogous to the current hypothesis) would partition elements, as well as isotopic signatures, such that they would be virtually unrecognizable as having a crustal level syntectic origin, based on mass-balance principles and Rayleigh decarbonation isotopic equilibria, as they do in many infiltrative skarn systems. Essentially, this partly vindicates the basic premise of Daly's limestone syntectic hypothesis for the origin of some peralkalic igneous rocks.

Paleozoic Hydrocarbon-Seep Limestones

NASA Astrophysics Data System (ADS)

Peckmann, J.

2007-12-01

To date, five Paleozoic hydrocarbon-seep limestones have been recognized based on carbonate fabrics, associated fauna, and stable carbon isotopes. These are the Middle Devonian Hollard Mound from the Antiatlas of Morocco [1], Late Devonian limestone lenses with the dimerelloid brachiopod Dzieduszyckia from the Western Meseta of Morocco [2], Middle Mississippian limestones with the dimerelloid brachiopod Ibergirhynchia from the Harz Mountains of Germany [3], Early Pennsylvanian limestones from the Tantes Mound in the High Pyrenees of France [4], and Late Pennsylvanian limestone lenses from the Ganigobis Shale Member of southern Namibia [5]. Among these examples, the composition of seepage fluids varied substantially as inferred from delta C-13 values of early diagenetic carbonate phases. Delta C-13 values as low as -50 per mil from the Tantes Mound and -51 per mil from the Ganigobis limestones reveal seepage of biogenic methane, whereas values of -12 per mil from limestones with Dzieduszyckia associated with abundant pyrobitumen agree with oil seepage. Intermediate delta C-13 values of carbonate cements from the Hollard Mound and Ibergirhynchia deposits probably reflect seepage of thermogenic methane. It is presently very difficult to assess the faunal evolution at seeps in the Paleozoic based on the limited number of examples. Two of the known seeps were typified by extremely abundant rhynchonellide brachiopods of the superfamily Dimerelloidea. Bivalve mollusks and tubeworms were abundant at two of the known Paleozoic seep sites; one was dominated by bivalve mollusks (Hollard Mound, Middle Devonian), another was dominated by tubeworms (Ganigobis Shale Member, Late Pennsylvanian). The tubeworms from these two deposits are interpreted to represent vestimentiferan worms, based on studies of the taphonomy of modern vestimentiferans. However, this interpretation is in conflict with the estimated evolutionary age of vestimentiferans based on molecular clock methods, which suggest a maximal age of 126 million years for this group. 1. Peckmann et al. (1999) Facies 40, 281. 2. Peckmann et al. (2007) Palaios 22, 114. 3. Peckmann et al. (2001) Geology 29, 271. 4. Buggisch and Krumm (2005) Facies 51, 566. 5. Himmler et al. (submitted) Palaeogeogr., Palaeoclimatol., Palaeoecol.

Durability of building stones against artificial salt crystallization

NASA Astrophysics Data System (ADS)

Min, K.; Park, J.; Han, D.

2005-12-01

Salts have been known as the most powerful weathering agents, especially when combined with frost action. Salt crystallization test along with freezing-thawing test and acid immersion test was carried out to assess the durability of building stones against weathering. Granite, limestone, marble and basalt were sampled from different quarries in south Korea for this study. One cycle of artificial salt crystallization test was composed of immersion of cored rock specimens in oversaturated solutions of CaCl2, KCl, NaCl and Na2SO4, respectively for 15 hours and successive drying in an oven of 105°C for 3 hours and cooling at room temperature. Tests were performed up to 30 cycles, and specific gravity and ultrasonic velocity were measured after experiencing every 10 cycles and uniaxial compressive strength was measured only after 30 cycles. During the repeated Na2SO4 salt crystallization, some rock samples were gradually deformed excessively and burst after 20 to 30 cycles of test. The variation patterns of physical properties during the salt crystallization tests are too variable to generalize the effect of salt weathering on physical properties but limestone, marble and basalt samples showed relatively greater change of physical properties than granite samples. The recrystallized salts were well observed in the cracks of rock samples through the scanning electron microscope. In the all salt crystallization tests, apparent specific gravities for all tested samples increased generally but not so significantly due to recrystallization of salts. It can be inferred that filling the pores with salt crystals cause the increase of ultrasonic velocity during the early stage of salt crystallization and then in later stages the repeated cycles of salt crystallization result in development of cracks leading decrease of ultrasonic velocity for some rock samples.

Mineral resource of the month: lime

USGS Publications Warehouse

,

2009-01-01

The article presents facts about lime, which is said to be a caustic chemical manufactured from limestone or other calcium carbonates in a kiln at temperatures ranging from 935 to 1,350 degrees Celsius. It states that lime is widely used in industries such as steelmaking, paper production and chemical manufacturing. It also mentions that global lime production amounts up to 280 million metric tons annually. However, it notes that international trade in lime is limited.

Limestone Caverns

ERIC Educational Resources Information Center

Powell, Richard L.

1970-01-01

Describes the origin of limestone caverns, using Mammoth Cave as an example, with particular reference to the importance of groundwater information of caverns, the present condition of groundwater, and how caverns develop within fluctuating groundwater zones. (BR)

The Öland limestone - A Swedish stone used for more than one thousand years

NASA Astrophysics Data System (ADS)

Schouenborg, Björn; Wickström, Linda; Mikaelsson, Jan

2016-04-01

The second largest island in Sweden is the home of the "Öland limestone", a condensed and bedded limestone whose origin dates back to Lower Ordovician, i.e. about 480 M years ago. Öland is a part of the palaeocontinent Baltica that, at the time, was situated at low latitudes with deposition of the calcareous sediments in a cool water environment. The limestone on Öland represents a proximal ramp tectonic setting, with the oldest sediments deposited in the west and younger sediments deposited towards east and southeast. Fluctuating sea-levels have created erosional hard grounds such as the Flowery sheet. These hardgrounds are recognised by their vivid colours and trace fossils, and can be traced all over Baltica, but is maybe best represented on Öland. Ordovician limestones are present in many places in Sweden, but it is the occurrence on Öland that is the most renowned in a building stone perspective. One reason for this is the favourable trading location, an island off the Swedish East coast in middle of the trading routes between the Baltic countries and the continent. Other reasons are the pleasant aesthetical values with numerous orthoceratites and other fossils. The limestones on Öland differ in colour. From the red varieties (with oxidized iron) to brownish and grey. The bedding is mostly in the cm-scale which easily enables very exploitable thickness of slabs. Every mm limestone represents about 1000 years of deposition. The limestone has most likely been used in a very crude way for many thousand years, but archaeological evidence of a more industrialized usage is just a little more than 1000 years. It is known from the literature that the first official Swedish king, Gustav Vasa (16th century), desired this stone. At the time it was called "Öland marble", and the king "imported" specialists to process it further at the Royal Stone workshop on northern Öland. Remnants of tools and working sites still remain in an outdoor museum. Export of the Ölandic limestone was intense even during Hanseatic times (14th to 17th centuries) and it can for example be found as floorings, mantel pieces, baptismal fonts in many German castles and manors. The literature tells us that export to Denmark, Poland and even southern Germany was intense during late medieval ages. This is because a lot of churches were built in Northern Europe at that time. However, the modern industrialised production had to wait until the early 20th century. Today, three companies quarry and process the limestones on a regular basis. They are primarily used for flooring, stairs, crazy stones for gardens, table tops, kitchen tops and, in some cases, also external cladding and paving. The latter only with more durable layers free of clay and open stylolites, so called "core stone" (direct translation). The presentation will show that the Öland limestone covers all aspects and requirements for being a Global heritage resource.

Importance of granulometry on phase evolution and phase-to-phase relationships of experimentally burned impure limestones intended for production of hydraulic lime and/or natural cement

NASA Astrophysics Data System (ADS)

Kozlovcev, Petr; Přikryl, Richard; Přikrylová, Jiřina

2015-04-01

In contrast to modern ordinary Portland cement production from finely ground raw material blends, ancient burning of hydraulic lime was conducted by burning larger pieces of natural raw material. Due to natural variability of raw material composition, exploitation of different beds from even one formation can result the product with significantly different composition and/or properties. Prague basin (Neoproterozoic to pre-Variscan Palaeozoic of the central part of the Bohemian Massif - the so-called Barrandian area, Czech Republic) represents a classical example of the limestone-rich region with long-term history of limestone burning for quick lime and/or various types of hydraulic binders. Due to the fact that burning of natural hydraulic lime has been abandoned in this region at the turn of 19th/20th c., significant gap in knowledge on the behavior of various limestone types and on the influence of minor variance in composition on the quality of burned product is encountered. Moreover, the importance of employment of larger pieces of raw material for burning for the development of proper phase-to-phase relationships (i.e. development of hydraulic phases below sintering temperature at mutual contacts of minerals) has not been examined before. To fill this gap, a representative specimens of major limestone types from the Prague basin have been selected for experimental study: Upper Silurian limestone types (Přídolí and Kopanina Lms.), and Lower Devonian limestones (Radotín, Kotýs, Řeporyje, Dvorce-Prokop, and Zlíchov Lms.). Petrographic character of the experimental material was examined by polarizing microscopy, cathodoluminescence, scanning electron microscopy with an energy dispersive spectrometer (SEM-EDS), and X-ray diffraction (XRD) of insoluble residue. Based on the data from wet silicate analyses, modal composition of studied impure limestones was computed. Experimental raw material was burned in laboratory electric furnace at 1000 and 1200°C for 3 and/or 6 hours. Burned samples were examined by XRD for phase composition and by SEM-EDS for phase-to-phase relationships due to the burning. Based on our data it is evident that larnite-belite (dicalcium-silicate) is dominant phase in burned silica-rich limestones (represented by e.g. Dvorce-Prokop, Přídolí and/or Kopanina Lms.). In clay-rich limestones containing kaolinite and illite, gehlenite and other calcium aluminates and aluminosilicates were detected (represented by Kosoř, Řeporyje, and/or a portion of Dvorce-Prokop Lms.). Due to higher proportion of Fe-oxihydroxides in the Řeporyje Lms., brownmillerite (calcium aluminoferrite) forms as a typical minor phases during burning. Free-lime (plus its hydrated form - portlandite) makes dominant phase in limestones exhibiting low non-carbonate admixture (Kotýs and/or a portion of Kopanina Lms.). These results clearly demonstrate that presence of certain non-carbonate minerals governs formation of certain hydraulic phases in burned product, whilst mutual proportions of individual minerals in raw materials influence amount of newly formed phases.

Contribution in support of a Global Heritage Stone designation for the Leitha Limestone s.l. of eastern Austria because of its use in Roman times

NASA Astrophysics Data System (ADS)

Moshammer, Beatrix; Rohatsch, Andreas

2015-04-01

The Leitha Limestone s.l., which has been proposed for Global Heritage Stone listing, comprises the red algae dominated sediments of shallow water carbonate platforms distributed around the Leitha Mountains, the Ruster Hills and other parts of the Vienna Basin. In our sense it comprehends the Leithakalk faciostratotype of the Badenian regional stage along with its lateral equivalents of near shore calcareous sandstones, breccias and conglomerates. It also includes the so called detrital Leithakalk, an informal name for calcareous algae sandstones of the Sarmatian regional stage that is perhaps comparable with the Skalica Formation and finally it covers the algae strata known from the Pannonian regional stage. Thus the Leitha Limestone s.l. belongs to the middle and upper part of the Miocene, i.e. ranging from about 16 to 10 my BP. The geoscientific focus of this multidisciplinary research is on deciphering the petrological types and carbonate facies of stone monuments and building stones and on comparing them with the successions of the strata outcropping in abandoned quarries. We are recording distinguishing lithological features and collecting appropriate field samples for microscopic, petrophysical, and geochemical analysis. The results of these analyses will be used to characterise the different varieties of Leitha Limestone s.l. of the investigated stone objects, with a view to setting up a catalogue based on lithological types that could be of considerable value for restoration and conservation too. Carnuntum was the regional metropolis of the Roman province Pannonia Superior and one of the legionary camps along the Danube Limes from about 40 AD to the end of the 5th century. It is situated about 40 km east of Vienna city centre, in the present-day market-town of Petronell-Carnuntum. Most of the stone objects from Carnuntum are made of the local quarried Leitha Limestone s.l. from the Hainburg Mountains and from ancient quarries in the Leitha Mountains probably in the region between Winden, Jois and Bruckneudorf. As part of the same research project, the above-mentioned methods are also being applied to a Roman stone inventory from Vindobona and to individual discoveries from the surrounding region. The remains of Vindobona lie in the centre of Vienna - it was another legionary camp of the Danube Limes, from the 1st to the 5th century AD. Gravestones and ornamented architectural parts (for example) have been identified as Leitha Limestone s.l. from local quarries along the western border of the Vienna Basin as well as from further afield in the Leitha Mountains. Compared with Carnuntum, the geological hinterland of Vindobona contains a greater variety of natural stone resources and the catchment area for rock used in Vindobona appears to have extended southwards along the Alpine margin as far as Bad Fischau. In addition to our understanding of the geology and petrology of the Leitha Limestone s.l., archaeological conclusions will be drawn regarding the historic and economic value of the resources contained in the identified quarry districts during the Roman period. FWF-Project P 26368. Stone monuments and stone quarrying in the Carnuntum - Vindobona area. Project Leader: Gabrielle Kremer, Österreichische Akademie der Wissenschaften, Institut für Kulturgeschichte der Antike.

Multi-scale fracture networks within layered shallow water tight carbonates

NASA Astrophysics Data System (ADS)

Panza, Elisa; Agosta, Fabrizio; Rustichelli, Andrea; Vinciguerra, Sergio; Zambrano, Miller; Prosser, Giacomo; Tondi, Emanuele

2015-04-01

The work is aimed at deciphering the contribution of background deformation and persistent fracture zones on the fluid flow properties of tight platform carbonates. Taking advantage of 3D exposures present in the Murge area of southern Italy, the fracture networks crosscutting at different scales the layered Cretaceous limestone of the Altamura Fm. were analyzed. The rock multi-layer is characterized by 10's of cm-thick, sub-horizontal, laterally continuous carbonate beds. Each bed commonly represents a shallowing-upward peritidal cycle made up of homogeneous micritic limestones grading upward to cm-thick stromatolitic limestones and/or fenestral limestones. The bed interfaces are formed by sharp maximum flooding surfaces. Porosity measurements carried out on 40 limestone samples collected from a single carbonate bed show values ranging between 0,5% and 5,5%. Background deformation includes both stratabound and non-stratabound fractures. The former elements consist of bed-perpendicular joints and sheared joints, which are confined within a single bed and often displace small, bed-parallel stylolites. Non-stratabound fractures consist of incipient, cm offset, sub-vertical strike-slip faults, which crosscut the bed interfaces. The aforementioned elements are often confined within individual bed-packages, which are identified by presence of pronounced surfaces locally marked by veneers of reddish clayey paleosoils. Persistent fracture zones consist of 10's of m-high, 10's of cm-offset strike-slip faults that offset the bed-package interfaces and are confined within individual bed-packages association. Laterally discontinuous, cm- to a few m-thick paleokarstic breccia levels separate the different bed-packages associations. Persistent fracture zones include asymmetric fractured damage zones and mm-thick veneers of discontinuous fault rocks. The fracture networks that pervasively crosscut the study limestone multi-layer are investigated by mean of scanline and scanarea methodologies. The dimensional, spatial and scaling properties of both stratabound and non-stratabound fractures are documented along single beds and bed-packages, respectively. Persistent fracture zones are studied from individual bed-package associations. By computing the intensity, height distribution, aspect ratio, aperture of each fracture/fault set, DFN (Discrete Fracture Network) models are built for the aforementioned different scales of observation. DFN models of single beds and bed-packages include stratabound and non-stratabound fractures. Differently, the DFN model of a bed-packages association also includes persistent fracture zones and related damage zones. To check the results of our computations, we also build up a smaller scale, 1m3 geocellular volume in which fractures are inserted one at time in the model. All DFN models do not include the matrix porosity. Porosity and 3D permeability (Kx, Ky, Kz) values are obtained as outputs of the DFN models. The results are consistent with the most prominet set of non-stratabound fractures being the major control on the petrophysical properties of both single beds and bed-packages. As expected, the persistent fractures zones strongly affect both porosity and permeability of the bed-packages association. The results of ongoing laboratory analyses on representative limestone samples not only will provide a quantitative assessment of the physical properties of the matrix in terms of porosity and permeability, but also will shed new light on the geometry, density and anisotropy of microfractures and their role on fluid flow properties.

Preliminary results in larger benthic foraminifera assemblage in a mixed siliciclastic-carbonate platform from the Upper Cretaceous of the External Prebetic Domain (Valencia province, SE Spain)

NASA Astrophysics Data System (ADS)

Robles-Salcedo, Raquel; Vicedo, Vicent

2016-04-01

In the External Prebetic Domain (Betic Mountain Range, Valencia province, SE Spain) it is difficult to find good outcrops to study larger benthic foraminifera (LBF), particularly in the Upper Cretaceous deposits, because of three main reasons. During the Upper Cretaceous, the complex paleogeography in the northern Prebetic Domain developed a complex system of shallow-water platforms. This is directly linked to the complexity in the distribution of the facies observed nowadays, which may change drastically in lateral, closely related outcrops having a special negative impact in the lateral extension of stratigraphical levels containing LBF. The second reason is the nature of the shallow water environments in which the larger foraminifera lived. The local continental influence derived in the establishment of very complex mixed platforms. Thus, there is not a complete register through carbonate rocks, but an alternation of microconglomerates, sandstones, calcarenites and carbonates that can be observed in the stratigraphic series of the Upper Cretaceous. This affects negatively in observing changes in the evolutionary trends of taxa. The third reason difficulting the study of LBF in northern localities of the Prebetic Domain is diagenetic. Dolomitization affects a huge part of the Mesozoic rocks deleting all fossil microfauna in the affected rocks. Such three reasons are behind the difficulty in developing correlations and having a comprehensive understanding of the biostratigraphy and phylogeny of the taxa involved. However, after several field trips developed in the northern Prebetic area, an excellent reference section for the study of the LBF in the Prebetic Domain has been identified in the surroundings of the Pinet village (Valencia province). Here, a relatively continuous section with scarce dolomitization and good conditions of accessibility exists. The larger foraminifera assemblages appering in the Pinet section will be compared with other paleobiogeographic areas such as the Pyrenees (S France and NE Spain) or Salento (SE Italy) regions. The Pinet section measures about 150 m, with coarsening upward sequences consisting, from bottom to top: 56 m of fine sandstones; 25 m with several coarsening upward, well-stratified limestones; 36 m with fine to coarse dolomitic sandstones intercalated with calcarenites; 15 m with fine and well-stratified limestones and, 20 m of dolomitic massive limestone at the top. Finally, the stratigraphical succession is completed by continental deposits. An abundant content of lamellar-perforate foraminifera (siderolitids, orbitoidiforms, clypeorbids) and agglutinated foraminifera (dicyclinids) has been identified in the preliminary studies. From bottom to top, in the fine sandstone deposits abundant specimens identified as Praesiderolites sp. occur. The coarsening upward limestones provide Praesiderolites sp., Pseudosiderolites sp., "Orbitoides" cf. concavatus, Orbitoides spp., Lepidorbitoides campaniensis and Sirtina cf. orbitoidiformis. The calcaretinic deposits contain rounded bioclastic fauna with Orbitoides spp. and cf. Wannierina. The fine limestones display abundant ostracods, miliolids and Dicyclina sp. and there are wackestone limestones deposits with carophytes at the top of the sequence. No larger benthic foraminifera have been identified in the massive dolomitic limestone. The results obtained after a first analysis, considering the LBF assemblage, indicate that the Pinet section deposits can be dated as earliest to middle Late Campanian, contrarily to the Campanian-Maastrichtian age suggested by previous studies.

Effects of aquifer heterogeneity on ground-water flow and chloride concentrations in the Upper Floridan aquifer near and within an active pumping well field, west-central Florida

USGS Publications Warehouse

Tihansky, A.B.

2005-01-01

Chloride concentrations have been increasing over time in water from wells within and near the Eldridge-Wilde well field, near the coast in west-central Florida. Variable increases in chloride concentrations from well to well over time are the combined result of aquifer heterogeneity and ground-water pumping within the Upper Floridan aquifer. Deep mineralized water and saline water associated with the saltwater interface appear to move preferentially along flow zones of high transmissivity in response to ground-water withdrawals. The calcium-bicarbonate-type freshwater of the Upper Floridan aquifer within the study area is variably enriched with ions by mixing with introduced deep and saline ground water. The amount and variability of increases in chloride and sulfate concentrations at each well are related to well location, depth interval, and permeable intervals intercepted by the borehole. Zones of high transmissivity characterize the multilayered carbonate rocks of the Upper Floridan aquifer. Well-developed secondary porosity within the Tampa/Suwannee Limestones and the Avon Park Formation has created producing zones within the Upper Floridan aquifer. The highly transmissive sections of the Avon Park Formation generally are several orders of magnitude more permeable than the Tampa/Suwannee Limestones, but both are associated with increased ground-water flow. The Ocala Limestone is less permeable and is dominated by primary, intergranular porosity. Acoustic televiewer logging, caliper logs, and borehole flow logs (both electromagnetic and heat pulse) indicate that the Tampa/Suwannee Limestone units are dominated by porosity owing to dissolution between 200 and 300 feet below land surface, whereas the porosity of the Avon Park Formation is dominated by fractures that occur primarily from 600 to 750 feet below land surface and range in angle from horizontal to near vertical. Although the Ocala Limestone can act as a semiconfining unit between the Avon Park Formation and the Tampa/Suwannee Limestones, seismic-reflection data and photolinear analyses indicate that fractures and discontinuities in the Ocala Limestone are present within the southwestern part of the well field. It is possible that some fracture zones extend upward from the Avon Park Formation through the Ocala, Suwannee, and Tampa Limestones to land surface. These fractures may provide a more direct hydrologic connection between transmissive zones that are vertically separated by less permeable stratigraphic units. Ground water moves along permeable zones within the Upper Floridan aquifer in response to changes in head gradients as a result of pumping. Borehole geophysical measurements, including flow logs, specific conductance logs, and continuous monitoring of specific conductance at selected fixed depths, indicate that borehole specific conductance varies substantially with time and in response to pumping stresses. Ground-water mixing between hydrogeologic units likely occurs along highly transmissive zones and within boreholes of active production wells. Ground-water movement and water-quality changes were greatest along the most transmissive zones. Variable mixing of three water-type end members (freshwater, deepwater, and saltwater) occurs throughout the study area. Both deepwater and saltwater are likely sources for elevated chloride and sulfate concentrations in ground water. Mass-balance calculations of mixtures of the three end members indicate that deepwater is found throughout the aquifer units. Samples from wells within the southwestern part of the well field indicate that deepwater migrates into the shallow permeable units in the southwestern part of the well field. Deepwater contributes to elevated sulfate and chloride concentrations, which increase with depth and are elevated in wells less than 400 feet deep. The greatest increases in chloride concentrations over time are found in water from wells closest to the saltwater interface. Gro

Geohydrologic data from Port Royal Sound, Beaufort County, South Carolina

USGS Publications Warehouse

Burt, R.A.; Belval, D.L.; Crouch, Michael; Hughes, W.B.

1986-01-01

Nine offshore wells were drilled through overlying sediments into the Upper Floridan aquifer in Port Royal Sound, South Carolina and the adjacent Atlantic Ocean, to obtain geologic, hydrologic, and water quality data. The Upper Floridan aquifer consists predominantly of light-gray, poorly consolidated, fossiliferous limestone. In the Port Royal Sound area, the Upper Floridan is overlain by olive-gray, medium to course sand and silty sand. Falling-head permeability tests on these overlying clastic sediments indicate permeabilities of 1,100 to 4.3 x 10 to the 7th power centimeters/sec. Other geologic and hydrologic data, including geophysical logs, sieve analyses, and detailed core descriptions were obtained, along with continuous water level records of the wells, tidal records, and barometric pressure records. Water collected from the Upper Floridan aquifer beneath Port Royal Sound and the ocean ranged in concentration of chloride from 54 to 12,000 mg/l. Measured pH ranged from 6.8 to 8.4, and alkalinity ranged from 122 to 368 mg/l as CaC03. Other water quality data obtained include temperature, specific conductance, carbon-13, carbon-14, tritium , deuterium, oxygen-18, dissolved oxygen, dissolved solids, nitrogen species, phosphorus, organic carbon, cyanide, sulfide, calcium, magnesium, sodium, potassium, sulfate, fluoride, silica , bromide, iodide, and selected trace metals. (USGS)

Geohydrology of the Cross-Florida Barge Canal area, with special reference to the Ocala vicinity

USGS Publications Warehouse

Faulkner, Glen L.

1970-01-01

The Cross-Florida Barge Canal route commences at Palatka on the St. Johns River, about 75 miles upstream from the Atlantic Ocean, and extends 110 miles southwestward across Peninsular Florida into deep water in the Gulf of Mexico near Yankeetown. The canal will be equipped with five locks, each 600 feet long and 84 feet wide, and the channel will be a minimum of 12 feet deep and 150 feet wide. From near Ocala northeastward, the canal channel will replace much of the natural channel of the Oklawaha River, and will be excavated into beds of the so-called shallow sand aquifer of Miocene and younger age, which overlies limestone of the Floridan aquifer. Westward from Ocala most of the canal will be excavated below the potentiometric surface into limestone and dolomite of the Floridan aquifer. Water levels of Rodman, Eureka, and Inglis Pools will be controlled by dams and spillways with limited exchange of water between the pools and the aquifers. The water levels in the Summit Pool will fluctuate with the natural changes in the ground-water level of the Floridan aquifer, although the stage of the pool will be partially controlled by the stage held in the Eureka Pool. A dynamic inflow-outflow relationship will exist between the Sun, nit Pool and the Floridan aquifer. The Floridan aquifer in the canal area is 1,000 to 1,200 feet thick and consists of limestone and dolomite of middle Eocene to Miocene age, including, from older to younger the Lake City, Avon Park and Ocala limestones plus permeable sandy, dolomitic limestone in the lower part of the Hawthorn Formation. It is possible that most of the flow to the two major springs in the area occurs in the upper 100 feet or so of the aquifer in the Ocala Limestone. The aquifer is underlain by the Oldsmar Limestone of early Eocene age and is overlain by sand, clayey sand, clay and shell beds of Miocene through Holocene age, ranging from a few feet to two or three hundred feet thick. The permeable beds overlying the Floridan aquifer constitute the shallow aquifer, while the poorly permeable ones act as confining beds where the Floridan aquifer is under artesian conditions. A north-south line drawn separating the head of Silver Springs on the west from the Oklawaha River on the east marks the approximate westward limit of a continuous blanket of Miocene-Pliocene(?) age materials covering the rocks of the Floridan aquifer. East of the line much of the aquifer is under artesian conditions, particularly in the Oklawaha River valley, although in some areas east of the valley direct recharge through thick permeable Miocene-Pliocene(?) sands occurs. West of the line, only scattered remnants of a once continuous Miocene-Pliocene(?) cover remains. Lack of the cover is a result of erosion on the crest and flanks of the Ocala Uplift, a broad northwest-southeast trending anticlinal upwarp, the axis of which is crossed by the canal route in the Dunnellon area. Over most of this area the Floridan aquifer is unconfined, and receives direct recharge through a cover of a few tens of feet of sand and clayey sand of Quaternary age. Tensional stresses during the structural evolution of the Ocala Uplift produced an intersecting system of fractures and normal faults in rocks of the Florida Aquifer. The fractures and faults are important controls for orientation of solution channels, and, therefore, for development of ground-water circulation patterns. When the system of surface streams which once drained the Barge Canal area eroded the poorly permeable Miocene-Pliocene(?) cover from the flanks of the Ocala Uplift, surface runoff was reduced and precipitation began to directly infiltrate the underlying limestones. Now only principal rivers, such as the Oklawaha and Withlacoochee Rivers, and a few short tributaries remain, while one of the most highly developed subsurface drainage systems in the world has evolved in the cavernous limestones of the Floridan aquifer. Two of the larger fresh water spr

Blended aggregate bituminous mixes.

DOT National Transportation Integrated Search

1975-01-01

Virginia has provided skid resistant pavements in the limestone area of the state by placing thin overlays of sand mixes incorporating local materials, by sprinkling highly skid resistant aggregates on limestone bituminous mixes prior to rolling, and...

1. SOUTH FACADE. CONSTRUCTED (ca. 1895) OF INDIGENOUS LIMESTONE AND ...

Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

1. SOUTH FACADE. CONSTRUCTED (ca. 1895) OF INDIGENOUS LIMESTONE AND USED AS LOCKPORTS CENTRAL HIGH SCHOOL FOR MORE THAN SIXTY YEARS. - Lockport Historic District, Central High School, Lockport, Will County, IL

5. Foreground: ore bridges, ore/coke/limestone bins, Detroit River; background: stock ...

Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

5. Foreground: ore bridges, ore/coke/limestone bins, Detroit River; background: stock house on left, stripper building, BOF. Looking south/southwest - Rouge Steel Company, 3001 Miller Road, Dearborn, MI

Blasting methods for heterogeneous rocks in hillside open-pit mines with high and steep slopes

NASA Astrophysics Data System (ADS)

Chen, Y. J.; Chang, Z. G.; Chao, X. H.; Zhao, J. F.

2017-06-01

In the arid desert areas in Xinjiang, most limestone quarries are hillside open-pit mines (OPMs) where the limestone is hard, heterogeneous, and fractured, and can be easily broken into large blocks by blasting. This study tried to find effective technical methods for blasting heterogeneous rocks in such quarries based on an investigation into existing problems encountered in actual mining at Hongshun Limestone Quarry in Xinjiang. This study provided blasting schemes for hillside OPMs with different heights and slopes. These schemes involve the use of vertical deep holes, oblique shallow holes, and downslope hole-by-hole sublevel or simultaneous detonation techniques. In each bench, the detonations of holes in a detonation unit occur at intervals of 25-50 milliseconds. The research findings can offer technical guidance on how to blast heterogeneous rocks in hillside limestone quarries.

Freshwater biodissolution rates of limestone in the temperate climate of the Dinaric karst in Slovenia

NASA Astrophysics Data System (ADS)

Mulec, J.; Prelovšek, M.

2015-01-01

Dissolution rates in two freshwater karst systems were determined by using tablets of dense micrite-biopelmicrite Cretaceous limestone. Submerged limestone tablets in riverbeds were subjected to a natural gradient from complete darkness to direct sunlight. Higher light rates significantly (p < 0.05) increased the epilithic biomass of phototrophs and the overall dissolution rates, which were highest at the Unica spring (- 49.2 μm a- 1), but the exact portion of light-dependent dissolution remains elusive. In the karst river Unica, with its big fluctuations in environmental parameters (e.g., discharge), light rates can be used in estimating the dissolution rates enhanced by phototrophs. Natural biofilms in aquatic systems have important implications for landform evolution, and the impact on limestone dissolution rates is comparable with rates of debris falling from steep slopes.

Sedum tarokoense (Crassulaceae), a new species from a limestone area in Taiwan.

PubMed

Lu, Chang-Tse; Lin, Hung-Wen; Liou, Wei-Ting; Wang, Jenn-Che

2013-12-01

An unknown Sedum was found from the limestone region in Taiwan. After a detailed comparison with other congeners in Taiwan and neighboring countries, we identified this plant as a new species. This new taxon resembles S. nokoense Yamamoto, S. alfredii Hance, and S. uniflorum Hook. & Arn. subsp. oryzifolium (Makino) H. Ohba, but differs in leaf shape, sepal morphology, and seed testa micro-morphology. Ecologically, this new taxon occurs exclusively on limestone, while S. nokoense and S. alfredii grow in non-limestone areas and S. uniflorum subsp. oryzifolium is only found on sandy seashores. Sedum tarokoense H.W. Lin & J.C. Wang is described as a new species. We provide a description, line drawing, and distribution map, as well as photograph, a key and a table to distinguish S. tarokoense from its related species.

Hydrothermal karst and associated breccias in Neoproterozoic limestone from the Barker-Villa Cacique area (Tandilia belt), Argentina

NASA Astrophysics Data System (ADS)

Dristas, Jorge A.; Martínez, Juan C.; van den Kerkhof, Alfons M.; Massonne, Hans-Joachim; Theye, Thomas; Frisicale, María C.; Gregori, Daniel A.

2017-07-01

In the Barker-Villa Cacique area (Tandilia belt), remarkable megabreccias, limestone breccias and phosphate-bearing breccias hosted in black limestone and along the contact with the upper section of the sedimentary succession are exposed. These rocks are the result of extensive hydrothermal alteration of the original micritic limestone and other fine-grained clastic sediments. Typical alteration minerals are sericite, chlorite, interstratified chlorite/K-white mica, kaolinite, dickite, pyrite, chalcopyrite, goethite, quartz, calcite, Fe-calcite, dolomite, ankerite, fluor-apatite, barite and aluminium-phosphate-sulfate (APS) minerals. Quartz and calcite cements from hydraulic breccias in the limestone contain low-salinity aqueous fluid inclusions. Corresponding homogenization temperatures display 200-220 °C and 110-140 °C in hydrothermal quartz, and 130-150 °C in late calcite cement. Carbon and oxygen stable isotope analyses of carbonates from the Loma Negra quarry (LNQ) support the major role of hydrothermal activity. A significant difference was found between δ18Ocar values from unaltered micritic limestone (ca. 23.8‰ SMOW) and secondary calcite (ca. 18.5‰ SMOW). The lower δ18Ocar values are interpreted as a result of calcite precipitation from hot hydrothermal fluids. At a late stage, the hydrothermal fluid containing H2S mixed with descending and oxidizing meteoric waters. Circulation of the ensuing acid fluids resulted in the partly dissolution and collapse brecciation of the Loma Negra Formation. The hydrothermal stage can be tentatively dated ca. 590-620 Ma corresponding to the Brasiliano orogeny.

Dietary adaptations of Assamese macaques (Macaca assamensis) in limestone forests in Southwest China.

PubMed

Huang, Zhonghao; Huang, Chengming; Tang, Chuangbin; Huang, Libin; Tang, Huaxing; Ma, Guangzhi; Zhou, Qihai

2015-02-01

Limestone hills are an unusual habitat for primates, prompting them to evolve specific behavioral adaptations to the component karst habitat. From September 2012 to August 2013, we collected data on the diet of one group of Assamese macaques living in limestone forests at Nonggang National Nature Reserve, Guangxi Province, China, using instantaneous scan sampling. Assamese macaques were primarily folivorous, young leaves accounting for 75.5% and mature leaves an additional 1.8% of their diet. In contrast, fruit accounted for only 20.1%. The young leaves of Bonia saxatilis, a shrubby, karst-endemic bamboo that is superabundant in limestone hills, comprised the bulk of the average monthly diet. Moreover, macaques consumed significantly more bamboo leaves during the season when the availability of fruit declined, suggesting that bamboo leaves are an important fallback food for Assamese macaques in limestone forests. In addition, diet composition varied seasonally. The monkeys consumed significantly more fruit and fewer young leaves in the fruit-rich season than in the fruit-lean season. Fruit consumption was positively correlated with fruit availability, indicating that fruit is a preferred food for Assamese macaques. Of seventy-eight food species, only nine contributed >0.5% of the annual diet, and together these nine foods accounted for 90.7% of the annual diet. Our results suggest that bamboo consumption represents a key factor in the Assamese macaque's dietary adaptation to limestone habitat. © 2014 Wiley Periodicals, Inc.

Mapping and modelling of collapse sinkholes in soluble rock: the Münsterdorf site, northern Germany

NASA Astrophysics Data System (ADS)

Kaufmann, Georg; Romanov, Douchko

2017-04-01

Münsterdorf is a small village in the north of Hamburg, located along the northern rim of a salt diapir. The Permian rocks are uplifted and overlying rocks such as the cretaceous limestone, normally in several kilometres depth, have been pushed up close to the surface. In Münsterdorf, the cretaceous limestone can be found in around 20 m depth, and about 2 km further south, cretaceous limestones are quarried in a large open-pit mine. Since 2004, collapse sinkholes form on a sporting ground in Münsterdorf, with a frequency of about 1 per year, about 2-3 m in diameter and 3-5 m deep. The collapse sinkholes do not reach the underlying limestone, but seem to be related to accelerated dissolution in that formation. Above the cretacious limestone, quaternary gravels and glacial marls provide a non-soluble, but permeable and heterogeneous cover of about 20 m thickness. We have mapped the sporting ground and its vicinity with gravity (GRAV), electrical resistivity imaging (ERI), self-potential measurements (SP), and ground-penetrating radar (GPR). While GRAV and SP is fairly unspectacular, the ERI profiles indicate a significant change in the surface layer, from thin and irregular in the northern part to thicker and more homogeneous in the southern part of the sporting ground. GPR profiles confirm this result. With numerically modelling the evolution of flow and porosity in the cretaceous limestone, we discuss the potential cause of the sinkhole formation and its sudden onset.

Oolitic sandbody depositional models and geometries, Mississippian of southwest Britain: implications for petroleum exploration in carbonate ramp settings

NASA Astrophysics Data System (ADS)

Burchette, Trevor P.; Paul Wright, V.; Faulkner, Tom J.

1990-07-01

A 1000 m thick early Mississippian carbonate supersequence, the "Carboniferous Limestone" of southwest Britain, consists of three third-order depositional sequences. These comprise parasequences in various configurations, and the whole forms a carbonate ramp stack. Within this framework five major oolitic carbonate sandbodies developed: (a) Castell Coch Limestone, (b) Stowe Oolite, (c) Brofiscin Oolite, (d) Gully Oolite, and (e) High Tor Limestone. The depositional regime was storm- and wave-dominated throughout and the major sandbodies represent a range of progradational carbonate beaches, barriers and detached subtidal shoals. Analysis of the three-dimensional shapes and distribution of these five examples shows that they evolved to produce three major carbonate sandbody geometries: (a) strings, (b) sheets, and (c) wedges. These geometries are characterised using the five field examples and offered as a template which may assist in the exploration and reservoir modelling of petroleum-rich high-energy ramp systems. Progradation, for up to 40 km, of barrier islands (Stowe Oolite) and beach-ridge plains (Gully Oolite Formation) generated strings, and "thick" sheets individually up to 10-20 m thick. "Thin" shoreface-retreat carbonate packstone/grainstone sheets up to 5 m thick (High Tor limestone) developed during transgressions as veneers across flooding surfaces. These are comparable with sheet sands developed in siliciclastic shelf depositional systems. Progradation, for up to 30 km, and vertical aggradation of shoreline-detached oolite shoals (Castell Coch limestone, Brofiscin Oolite), generated basinwards-expanding or thinning wedges up to 30 m thick. Tectonically controlled stacking of strandplain sheets produced a composite carbonate sandbody up to 80 m thick (Gully Oolite). The intrinsic (sedimentary) and extrinsic (eustacy, tectonism, climate) factors which controlled these sandbody geometries are addressed. Establishing the positions of the sandbodies accurately within depositional sequences allows them to be located within inferred seismic sequence geometries and provides one possible solution to the difficult problem of predicting carbonate facies distribution in subtle stratigraphic plays. In this ramp system, the most homogeneous sandbodies (up to 30 m grainstones), with greatest reservoir facies potential, are represented by shoal-belt wedges. Potential grainstone reservoir facies in the prograding shorelines are limited to the upper parts of individual shoreface sequences (max. 10 m grainstones). For shoreline carbonate sandbodies, the greatest reservoir and stratigraphic trapping potential exists in the earliest ramp parasequences where enveloping offshore sediments are siliciclastic mudstones. In later stages, potential seals are likely to be less reliable, low-porosity outer ramp carbonates.

Bioweathering Potential of Cultivable Fungi Associated with Semi-Arid Surface Microhabitats of Mayan Buildings.

PubMed

Ortega-Morales, Benjamín O; Narváez-Zapata, José; Reyes-Estebanez, Manuela; Quintana, Patricia; De la Rosa-García, Susana Del C; Bullen, Heather; Gómez-Cornelio, Sergio; Chan-Bacab, Manuel J

2016-01-01

Soil and rock surfaces support microbial communities involved in mineral weathering processes. Using selective isolation, fungi were obtained from limestone surfaces of Mayan monuments in the semi-arid climate at Yucatan, Mexico. A total of 101 isolates representing 53 different taxa were studied. Common fungi such as Fusarium, Pestalotiopsis, Trichoderma, and Penicillium were associated with surfaces and were, probably derived from airborne spores. In contrast, unusual fungi such as Rosellinia, Annulohypoxylon, and Xylaria were predominantly identified from mycelium particles of biofilm biomass. Simulating oligotrophic conditions, agar amended with CaCO3 was inoculated with fungi to test for carbonate activity. A substantial proportion of fungi, in particular those isolated from mycelium (59%), were capable of solubilizing calcium by means of organic acid release, notably oxalic acid as evidenced by ion chromatography. Contrary to our hypothesis, nutrient level was not a variable influencing the CaCO3 solubilization ability among isolates. Particularly active fungi (Annulohypoxylon stygium, Penicillium oxalicum, and Rosellinia sp.) were selected as models for bioweathering experiments with limestone-containing mesocosms to identify if other mineral phases, in addition to oxalates, were linked to bioweathering processes. Fungal biofilms were seen heavily covering the stone surface, while a biomineralized front was also observed at the stone-biofilm interface, where network of hyphae and mycogenic crystals was observed. X-ray diffraction analysis (XRD) identified calcite as the main phase, along with whewellite and wedellite. In addition, lower levels of citrate were detected by Attenuated Total Reflectance-Fourier-Transform Infrared Spectroscopy (ATR-FTIR). Overall, our results suggest that a diverse fungal community is associated with limestone surfaces insemi-arid climates. A subset of this community is geochemically active, excreting organic acids under quasi-oligotrophic conditions, suggesting that the high metabolic cost of exuding organic acids beneficial under nutrient limitation. Oxalic acid release may deteriorate or stabilize limestone surfaces, depending on microclimatic dynamics.

Bioweathering Potential of Cultivable Fungi Associated with Semi-Arid Surface Microhabitats of Mayan Buildings

PubMed Central

Ortega-Morales, Benjamín O.; Narváez-Zapata, José; Reyes-Estebanez, Manuela; Quintana, Patricia; De la Rosa-García, Susana del C.; Bullen, Heather; Gómez-Cornelio, Sergio; Chan-Bacab, Manuel J.

2016-01-01

Soil and rock surfaces support microbial communities involved in mineral weathering processes. Using selective isolation, fungi were obtained from limestone surfaces of Mayan monuments in the semi-arid climate at Yucatan, Mexico. A total of 101 isolates representing 53 different taxa were studied. Common fungi such as Fusarium, Pestalotiopsis, Trichoderma, and Penicillium were associated with surfaces and were, probably derived from airborne spores. In contrast, unusual fungi such as Rosellinia, Annulohypoxylon, and Xylaria were predominantly identified from mycelium particles of biofilm biomass. Simulating oligotrophic conditions, agar amended with CaCO3 was inoculated with fungi to test for carbonate activity. A substantial proportion of fungi, in particular those isolated from mycelium (59%), were capable of solubilizing calcium by means of organic acid release, notably oxalic acid as evidenced by ion chromatography. Contrary to our hypothesis, nutrient level was not a variable influencing the CaCO3 solubilization ability among isolates. Particularly active fungi (Annulohypoxylon stygium, Penicillium oxalicum, and Rosellinia sp.) were selected as models for bioweathering experiments with limestone-containing mesocosms to identify if other mineral phases, in addition to oxalates, were linked to bioweathering processes. Fungal biofilms were seen heavily covering the stone surface, while a biomineralized front was also observed at the stone-biofilm interface, where network of hyphae and mycogenic crystals was observed. X-ray diffraction analysis (XRD) identified calcite as the main phase, along with whewellite and wedellite. In addition, lower levels of citrate were detected by Attenuated Total Reflectance-Fourier-Transform Infrared Spectroscopy (ATR-FTIR). Overall, our results suggest that a diverse fungal community is associated with limestone surfaces insemi-arid climates. A subset of this community is geochemically active, excreting organic acids under quasi-oligotrophic conditions, suggesting that the high metabolic cost of exuding organic acids beneficial under nutrient limitation. Oxalic acid release may deteriorate or stabilize limestone surfaces, depending on microclimatic dynamics. PMID:26941725

Black soiling of an architectural limestone during two-year term exposure to urban air in the city of Granada (S Spain).

PubMed

Urosevic, Maja; Yebra-Rodríguez, Africa; Sebastián-Pardo, Eduardo; Cardell, Carolina

2012-01-01

A two-year term aging test was carried out on a building limestone under different urban conditions in the city of Granada (Southern Spain) to assess its Cultural Heritage sustainability. For this purpose stone tablets were placed vertically at four sites with contrasting local pollution micro-environments and exposure conditions (rain-sheltered and unsheltered). The back (rain-sheltered) and the front (rain-unsheltered) faces of the stone tablets were studied for each site. The soiling process (surface blackening) was monitored through lightness (ΔL*) and chroma changes (ΔC*). Additionally atmospheric particles deposited on the stone surfaces and on PM10 filters during the exposure time were studied through a multianalytical approach including scanning electron microscopy (SEM-EDX), transmission electron microscopy (TEM) and micro-Raman spectroscopy. The identified atmospheric particles (responsible for stone soiling) were mainly soot and soil dust particles; also fly ash and aged salt particles were found. The soiling process was related to surface texture, exposure conditions and proximity to dense traffic streets. On the front faces of all stones, black soiling and surface roughness promoted by differential erosion between micritic and sparitic calcite were noticed. Moreover, it was found that surface roughness enhanced a feedback process that triggers further black soiling. The calculated effective area coverage (EAC) by light absorbing dust ranged from 10.2 to 20.4%, exceeding by far the established value of 2% EAC (limit perceptible to the human eye). Soiling coefficients (SC) were estimated based on square-root and bounded exponential fittings. Estimated black carbon (BC) concentration resulted in relatively similar SC for all studied sites and thus predicts the soiling process better than using particulate matter (PM10) concentration. Copyright © 2011 Elsevier B.V. All rights reserved.

Ground water in the carbonate rocks of the Franklin area, Tennessee

USGS Publications Warehouse

Zurawski, Ann; Burchett, C.R.

1980-01-01

A study of ground water in the Franklin area, Tennessee, was undertaken to fill a growing need for information on ground-water occurrence in the carbonate rocks of central Tennessee. Fifteen drilling sites were selected that had one or more of the following characteristics: medium- to thick-bedded limestones within 200 feet of land surface, structural lows, significant streamflow gains and losses, elongated sinkholes, straight stream reaches, linear features or other surface indications of solution cavities at depth. The 15 test wells produced from less than 1 to about 600 gallons per minute and had an average yield of 68 gallons per minute, measured while pumping the wells with compressed air. The average driller-reported yield for the area is five gallons per minute. Specific capacities for the four highest yielding wells ranged from 0.6 to 357 gallons per minute per foot of drawdown after 8 hours of pumping at rates ranging from 70 to 225 gallons per minute. Additional drilling at two sites revealed extensive solution openings. At one site, drawdown in five observation wells did not exceed 8.5 feet during 48 hours of pumping at an average rate of 502 gallons per minute. Raw water in the test wells meets most drinking-water standards and is of rather uniform quality from well to well and throughout the year. (USGS)

Hydrogeology of the Mammoth Spring groundwater basin and vicinity, Markagunt Plateau, Garfield, Iron, and Kane Counties, Utah

USGS Publications Warehouse

Spangler, Lawrence E.

2012-01-01

The Markagunt Plateau, in southwestern Utah, lies at an altitude of about 9,500 feet, largely within Dixie National Forest. The plateau is capped primarily by Tertiary- and Quaternary-age volcanic rocks that overlie Paleocene- to Eocene-age limestone of the Claron Formation, which forms escarpments on the west and south sides of the plateau. In the southwestern part of the plateau, an extensive area of sinkholes has formed that resulted primarily from dissolution of the underlying limestone and subsequent subsidence and (or) collapse of the basalt, producing sinkholes as large as 1,000 feet across and 100 feet deep. Karst development in the Claron Formation likely has been enhanced by high infiltration rates through the basalt. Numerous large springs discharge from the volcanic rocks and underlying limestone on the Markagunt Plateau, including Mammoth Spring, one of the largest in Utah, with discharge that ranges from less than 5 to more than 300 cubic feet per second (ft3/s). In 2007, daily mean peak discharge of Mammoth Spring was bimodal, reaching 54 and 56 ft3/s, while daily mean peak discharge of the spring in 2008 and in 2009 was 199 ft3/s and 224 ft3/s, respectively. In both years, the rise from baseflow, about 6 ft3/s, to peak flow occurred over a 4- to 5-week period. Discharge from Mammoth Spring accounted for about 54 percent of the total peak streamflow in Mammoth Creek in 2007 and 2008, and about 46 percent in 2009, and accounted for most of the total streamflow during the remainder of the year. Results of major-ion analyses for water samples collected from Mammoth and other springs on the plateau during 2006 to 2009 indicated calcium-bicarbonate type water, which contained dissolved-solids concentrations that ranged from 91 to 229 milligrams per liter. Concentrations of major ions, trace elements, and nutrients did not exceed primary or secondary drinking-water standards; however, total and fecal coliform bacteria were present in water from Mammoth and other springs. Temperature and specific conductance of water from Mammoth and other springs showed substantial variance and generally were inversely related to changes in discharge during snowmelt runoff and rainfall events. Over the 3-year study period, daily mean temperature and specific conductance of water from Mammoth Spring ranged from 3.4 degrees Celsius (°C) and 112 microsiemens per centimeter (μS/cm) during peak flow from snowmelt runoff to 5.3°C and 203 μS/cm during baseflow conditions. Increases in specific conductance of the spring water prior to an increase in discharge in 2008–09 were likely the result of drainage of increasingly older water from storage. Variations in these parameters in water from two rise pools upstream from Mammoth Spring were the largest observed in relation to discharge and indicate a likely hydraulic connection to Mammoth Creek. Variations in water quality, discharge, and turbidity indicate a high potential for transport of contaminants from surface sources to Mammoth and other large springs in a matter of days. Results of dye-tracer tests indicated that recharge to Mammoth Spring largely originates from southwest of the spring and outside of the watershed for Mammoth Creek, particularly along the drainages of Midway and Long Valley Creeks, and in the Red Desert, Horse Pasture, and Hancock Peak areas, where karst development is greatest. A significant component of recharge to the spring takes place by both focused and diffuse infiltration through the basalt and into the underlying Claron limestone. Losing reaches along Mammoth Creek are also a source of rapid recharge to the spring. Maximum groundwater travel time to the spring during the snowmelt runoff period was about 7 days from sinking streams as far as 9 miles away and 1,900 feet higher, indicating a velocity of more than a mile per day. Response of the spring to rainfall events in the recharge area, however, indicated potential lag times of only about 1 to 2 days. Samples collected from Mammoth Spring during baseflow conditions and analyzed for tritium and sulfur-35 showed that groundwater in storage is relatively young, with apparent ages ranging from less than 1 year to possibly a few tens of years. Ratios of oxygen-18 and deuterium also showed that water from the spring represents a mixture of waters from different sources and altitudes. On the basis of evaluating results of dye-tracer tests and relations to adjacent basins, the recharge area for Mammoth Spring probably includes about 40 square miles within the Mammoth Creek watershed as well as at least 25 square miles outside and to the south of the watershed. Additional dye-tracer tests are needed to better define boundaries between the groundwater basins for Mammoth Spring and Duck Creek, Cascade, and Asay Springs.

Evaluating performance of limestone prone to polishing.

DOT National Transportation Integrated Search

2009-12-01

This research project evaluated the effect of blending Vanport limestone and other aggregates on the frictional surface characteristic properties of constructed trial road surfaces. The study undertook the evaluation of the performance of different m...

Geology and hydrology of the Fort Belknap Indian Reservation, Montana

USGS Publications Warehouse

Alverson, Douglas C.

1965-01-01

The Fort Belknap Indian Reservation includes an area of 970 square miles in north-central Montana. At its north edge is the Milk River valley, which is underlain by Recent alluvium of the Milk River, glacial deposits, and alluvial deposits of the preglacial Missouri River, which carved and occupied this valley before the Pleistocene Epoch. Rising gently to the south is an undulating glaciated plain broken only by three small syenite porphyry intrusions. Underlying the glacial till of the plain are Upper Cretaceous shale and sandstone of the Bearpaw and Judith River Formations. At the south end of the reservation, 40 miles from the Milk River, an intrusion of syenite porphyry in Tertiary time uplifted, tilted, and exposed the succession of sedimentary rocks overlying the Precambrian metamorphic basement. The sedimentary rocks include 1,000 feet of sandstone and shale of Cambrian age; 2,000 feet of limestone and dolomite of Ordovician, Devonian, and Mississippian age; 400 feet of shale and limestone of Jurassic age; and 3,500 feet of sandstone, siltstone, and shale of Cretaceous age. Extensive gravel terraces of Tertiary and Quaternary age bevel the upturned bedrock formations exposed around the Little Rocky Mountains. Ground water under water-table conditions is obtained at present from alluvium, glaciofluvial deposits, and the Judith River Formation. The water table ranges in depth from a few feet beneath the surface in the Milk River valley alluvium to more than 100 feet deep in the Judith River Formation. Yields to wells are generally low but adequate for domestic and stock-watering use. Quality of the water ranges from highly mineralized and unusable to excellent; many wells in the Milk River valley have been abandoned because of the alkalinity of their water. Potential sources of additional ground-water supplies are the alluvial gravel of creeks issuing from the Little Rocky Mountains and some extensive areas of terrace gravel. The uplift and tilting of the sedimentary sequence around the Little Rocky Mountains and the minor intrusions in the central plain have created artesian conditions within aquifers. Wells obtain artesian water from sandstone aquifers in the Judith River, Eagle, and Kootenai Formations. Other potential aquifers, near their outcrop areas, are the Ellis Group and the Mission Canyon Limestone. Most wells that flow at the surface have small yields, but discharges of as much as 150 gallons per minute have been noted. Quality of artesian water ranges from poor to good. Well depths range from less than 50 to more than 300 feet.

Middle Devonian to Early Carboniferous event stratigraphy of Devils Gate and Northern Antelope Range sections, Nevada, U.S.A

USGS Publications Warehouse

Sandberg, C.A.; Morrow, J.R.; Poole, F.G.; Ziegler, W.

2003-01-01

The classic type section of the Devils Gate Limestone at Devils Gate Pass is situated on the eastern slope of a proto-Antler forebulge that resulted from convergence of the west side of the North American continent with an ocean plate. The original Late Devonian forebulge, the site of which is now located between Devils Gate Pass and the Northern Antelope Range, separated the continental-rise to deep-slope Woodruff basin on the west from the backbulge Pilot basin on the east. Two connections between these basins are recorded by deeper water siltstone beds at Devils Gate; the older one is the lower tongue of the Woodruff Formation, which forms the basal unit of the upper member of the type Devils Gate, and the upper one is the overlying, thin lower member of the Pilot Shale. The forebulge and the backbulge Pilot basin originated during the middle Frasnian (early Late Devonian) Early hassi Zone, shortly following the Alamo Impact within the punctata Zone in southern Nevada. Evidence of this impact is recorded by coeval and reworked shocked quartz grains in the Northern Antelope Range and possibly by a unique bypass-channel or megatsunami-uprush sandy diamictite within carbonate-platform rocks of the lower member of the type Devils Gate Limestone. Besides the Alamo Impact and three regional events, two other important global events are recorded in the Devils Gate section. The semichatovae eustatic rise, the maximum Late Devonian flooding event, coincides with the sharp lithogenetic change at the discordant boundary above the lower member of the Devils Gate Limestone. Most significantly, the Devils Gate section contains the thickest and most complete rock record in North America across the late Frasnian linguiformis Zone mass extinction event. Excellent exposures include not only the extinction shale, but also a younger. Early triangularis Zone tsunamite breccia, produced by global collapse of carbonate platforms during a shallowing event that continued into the next younger Famennian Stage. The Northern Antelope Range section is located near the top of the west side of the proto-Antler forebulge. Because of its unusual, tectonically active location, unmatched at any other Nevada localities, this section records only four regional and global events during a timespan slightly longer than that of the Devils Gate section. The global semichatovae rise and late Frasnian mass extinction event are largely masked because of the depositional complexities resulting from this location.

Preliminary evaluation of the shale gas prospectivity of the Lower Cretaceous Pearsall Formation in the onshore Gulf Coast region, United States

USGS Publications Warehouse

Enomoto, Catherine B.; Scott, Kristina; Valentine, Brett J.; Hackley, Paul C.; Dennen, Kristin; Lohr, Celeste D.

2012-01-01

Recent work by the U.S. Geological Survey indicated that the Lower Cretaceous Pearsall Formation contains an estimated mean undiscovered, technically recoverable unconventional gas resource of 8.8 trillion cubic ft in the Maverick Basin, South Texas. Cumulative gas production from horizontal wells in the core area of the emerging play has exceeded 5 billion cubic ft since 2008. However, very little information is available to characterize the Pearsall Formation as an unconventional gas resource beyond the Maverick Basin in the greater Gulf Coast region. Therefore, this reconnaissance study examines spatial distribution, thickness, organic richness and thermal maturity of the Pearsall Formation in the onshore U.S. Gulf states using wireline logs and drill cuttings sample analysis. Spontaneous potential and resistivity curves of approximately forty wireline logs from wells in five Gulf Coast states were correlated to ascertain the thickness of the Pearsall Formation and delineate its three members: Pine Island Shale, James Limestone or Cow Creek Limestone, and Bexar Shale, in ascending stratigraphic order. In Florida and Alabama the Pearsall Formation is up to about 300 ft thick; in Mississippi, Louisiana, Arkansas, and East Texas, thickness is up to as much as 800 ft. Drill cuttings sampled from 11 wells at depths ranging from 4600 to 19,600 feet subsurface indicate increasingly oxygenated depositional environments (predominance of red shale) towards the eastern part of the basin. Cuttings vary widely in lithology but indicate interbedded clastics and limestones throughout the Pearsall Formation, consistent with previous regional studies. Organic petrographic and geochemical analyses of 17 cutting samples in the Pearsall Formation indicate a wide range in thermal maturity, from immature (0.43% Ro [vitrinite reflectance]) in paleo-high structural locations to the peak oil window (0.99% Ro) in the eastern portion of the Gulf Coast Basin. This is in contrast to dry gas thermal maturity throughout the Pearsall Formation in the South Texas Maverick Basin. Organic carbon content is low overall, even in immature samples, with a range of 0.17 to 1.08 wt.% by Leco in 22 Pearsall Formation samples. The pyrolysis output range was 0.23 to 2.33 mg hydrocarbon/g rock. The thermal maturity and Rock-Eval pyrolysis data and organic petrologic observations from this study will be used to better focus specific areas of investigation where the Pearsall Formation may be prospective as an unconventional hydrocarbon source and reservoir.

Evolution of a Permo-Triassic sedimentary melange, Grindstone terrane, east-central Oregon

USGS Publications Warehouse

Blome, C.D.; Nestell, M.K.

1991-01-01

Perceives the Grindstone rocks to be a sedimentary melange composed of Paleozoic limestone slide and slump blocks that became detached from a carbonate shelf fringing a volcanic knoll or edifice in Late Permian to Middle Triassic time and were intermixed with Permian and Triassic slope to basinal clastic and volcaniclastic rocks in a forearc basin setting. Paleogeographic affinities of the Grindstone limestone faunas and volcaniclastic debris in the limestone and clastic rocks all indicate deposition in promixity to an island-arc system near the North American craton. -from Authors

Vatica najibiana (Dipterocarpaceae), a new species from limestone in Peninsular Malaysia

PubMed Central

Ummul-Nazrah, Abdul Rahman; Mohd Hairul, Mohd Amin; Kamin, Imin; Kiew, Ruth; Ong, Poh Teck

2018-01-01

Abstract Vatica najibiana Ummul-Nazrah (Dipterocarpaceae), from the Relai Forest Reserve, Gua Musang, Kelantan and Gua Tanggang, Merapoh, Pahang, is described and illustrated. This species is Endangered and known from small populations restricted to two isolated karst limestone hills. The type locality, Relai Forest Reserve limestone, is currently under threat from encroaching oil palm plantations and ongoing logging, which, if it continues, will threaten the Kelantan population with extinction. The morphology of V. najibiana and the similar V. odorata subsp. odorata and V. harmandiana is compared.

Rapid method to determine actinides and 89/90Sr in limestone and marble samples

DOE PAGES

Maxwell, Sherrod L.; Culligan, Brian; Hutchison, Jay B.; ...

2016-04-12

A new method for the determination of actinides and radiostrontium in limestone and marble samples has been developed that utilizes a rapid sodium hydroxide fusion to digest the sample. Following rapid pre-concentration steps to remove sample matrix interferences, the actinides and 89/90Sr are separated using extraction chromatographic resins and measured radiometrically. The advantages of sodium hydroxide fusion versus other fusion techniques will be discussed. Lastly, this approach has a sample preparation time for limestone and marble samples of <4 hours.

Sedimentary and tectonic evolution of the southern Qiangtang basin: Implications for the Lhasa-Qiangtang collision timing

NASA Astrophysics Data System (ADS)

Ma, Anlin; Hu, Xiumian; Garzanti, Eduardo; Han, Zhong; Lai, Wen

2017-07-01

The Mesozoic stratigraphic record of the southern Qiangtang basin in central Tibet records the evolution and closure of the Bangong-Nujiang ocean to the south. The Jurassic succession includes Toarcian-Aalenian shallow-marine limestones (Quse Formation), Aalenian-Bajocian feldspatho-litho-quartzose to feldspatho-quartzo-lithic sandstones (shallow-marine Sewa Formation and deep-sea Gaaco Formation), and Bathonian outer platform to shoal limestones (Buqu Formation). This succession is truncated by an angular unconformity, overlain by upper Bathonian to lower Callovian fan-delta conglomerates and litho-quartzose to quartzo-lithic sandstones (Biluoco Formation) and Callovian shoal to outer platform limestones (Suowa Formation). Sandstone petrography coupled with detrital-zircon U-Pb and Hf isotope analysis indicate that the Sewa and Gaaco formations contain intermediate to felsic volcanic detritus and youngest detrital zircons (183-170 Ma) with ɛHf(t) ranging widely from +13 to -25, pointing to continental-arc provenance from igneous rocks with mixed mantle and continental-crust contributions. An arc-trench system thus developed toward the end of the Early Jurassic, with the southern Qiangtang basin representing the fore-arc basin. Above the angular unconformity, the Biluoco Formation documents a change to dominant sedimentary detritus including old detrital zircons (mainly >500 Ma ages in the lower part of the unit) with age spectra similar to those from Paleozoic strata in the central Qiangtang area. A major tectonic event with intense folding and thrusting thus took place in late Bathonian time (166 ± 1 Ma), when the Qiangtang block collided with another microcontinental block possibly the Lhasa block.

Hydrology of area 18, Eastern Coal Province, Tennessee

USGS Publications Warehouse

May, V.J.

1981-01-01

The Eastern Coal Province is divided into 24 hydrologic reporting areas. This report describes the hydrology of area 18 which is located in the Cumberland River basin in central Tennessee near the southern end of the Province. Hydrologic information and sources are presented as text, tables, maps, and other illustrations designed to be useful to mine owners, operators, and consulting engineers in implementing permit applications that comply with the environmental requirements of the ' Surface Mining Control and Reclamation Act of 1977. ' Area 18 encompasses parts of three physiographic regions; from east to west the Cumberland Plateau, Highland Rim, and Central Basin. The Plateau is underlain by sandstones and shales, with thin interbedded coal beds, of Pennsylvanian age. The Highland Rim and Central Basin are underlain by limestone and dolomite of Mississippian age. Field and laboratory analyses of chemical and physical water-quality parameters of streamflow samples show no widespread water quality problems. Some streams, however, in the heavily mined areas have concentrations of sulfate, iron, manganese, and sediment above natural levels, and pH values below natural levels. Mine seepage and direct mine drainage were not sampled. Ground water occurs in and moves through fractures in the sandstones and shales and solution openings in the limestones and dolomites. Depth to water is variable, ranging from about 5 to 70 feet below land-surface in the limestones and dolomites, and 15 to 40 feet in the coal-bearing rocks. The quality of ground water is generally good. Locally, in coal-bearing rocks, acidic water and high concentrations of manganese, chloride, and iron have been detected. (USGS)

Some contrasting biostratigraphic links between the Baker and Olds Ferry Terranes, eastern Oregon

USGS Publications Warehouse

Nestell, Merlynd K.; Blome, Charles D.

2016-01-01

New stratigraphic and paleontologic data indicate that ophiolitic melange windows in the Olds Ferry terrane of eastern Oregon contain limestone blocks and chert that are somewhat different in age than those present in the adjacent Baker terrane melange. The melange windows in the Olds Ferry terrane occur as inliers in the flyschoid Early and Middle Jurassic age Weatherby Formation, which depositionally overlies the contact between the melange-rich Devonian to Upper Triassic rocks of the Baker terrane on the north, and Upper Triassic and Early Jurassic volcanic arc rocks of the Huntington Formation on the south. The Baker terrane and Huntington Formation represent fragments of a subduction complex and related volcanic island arc, whereas the Weatherby Formation consists of forearc basin sedimentary deposits. The tectonic blocks in the melange windows of the Weatherby Formation (in the Olds Ferry terrane) are dated by scarce biostratigraphic evidence as Upper Pennsylvanian to Lower Permian and Upper Triassic. In contrast, tectonic blocks of limestone in theBaker terrane yield mostly fusulinids and small foraminifers of Middle Pennsylvanian Moscovian age at one locality.Middle Permian (Guadalupian) Tethyan fusulinids and smaller foraminifers (neoschwagerinids and other Middle Permian genera) are present at a few other localities. Late Triassic conodonts and bryozoans are also present in a few of the Baker terrane tectonic blocks. These limestone blocks are generally embedded in Permian and Triassic radiolarian bearing chert or argillite. Based on conodont, radiolarian and fusulinid data, the age limits of the meange blocks in the Weatherby Formation range from Pennsylvanian to Late Triassic.

Distribution of uranium in the Bisbee district, Cochise County, Arizona

USGS Publications Warehouse

Wallace, Stewart R.

1956-01-01

The Bisbee district has been an important source of copper for many years, and substantial amounts of lead and zinc ore and minor amounts of manganese ore have been mined during certain periods. The copper deposits occur both as low-grade disseminated ore in the Sacramento Hill stock and as massive sulfide (and secondary oxide and carbonate) replacement bodies in Paleozoic limestones that are intruded by the stock and related igneous bodies. The lead-zinc production has come almost entirely from limestone replacement bodies. The disseminated ore exhibits no anomalous radioactivity, and samples from the Lavender pit contain from 0.002 to less than 0.001 percent equivalent uranium. The limestone replacement ores are distinctly radioactive and stoping areas can be readily distinguished from from unmineralized ground on the basis of radioactivity alone. The equivalent uranium content of the copper replacement ores ranges from 0.002 to 0.014 percent and averages about 0.005 percent; the lead-zinc replacement ores average more than 0.007 percent equivalent uranium. Most of the uranium in the copper ores of the district is retained in the smelter slag of a residual concentrate; the slag contains about 0.009 percent equivalent uranium. Uranium carried off each day by acid mine drainage is roughly equal to 1 percent of that being added to the slag dump. Although the total amount of uranium in the district is large, no minable concentrations of ore-grade material are known; samples of relatively high-grade material represent only small fractions of tons at any one locality.

Hydrostratigraphy of Tree Island Cores from Water Conservation Area 3

USGS Publications Warehouse

McNeill, Donald F.; Cunningham, Kevin J.

2003-01-01

Cores and borehole-geophysical logs collected on and around two tree islands in Water Conservation Area 3 have been examined to develop a stratigraphic framework for these ecosystems. Especially important is the potential for the exchange of ground water and surface water within these features. The hydrostratigraphic results from this study document the lithologic nature of the foundation of the tree islands, the distribution of porous intervals, the potential for paleotopographic influence on their formation, and the importance of low-permeability, subaerial-exposure horizons on the vertical exchange of ground water and surface water. Figure 1. Location of Tree Islands 3AS3 and 3BS1. [larger image] Results from this hydrostratigraphic study indicate that subtle differences occur in lithofacies and topography between the on-island and off-island subsurface geologic records. Specifics are described herein. Firstly, at both tree-island sites, the top of the limestone bedrock is slightly elevated beneath the head of the tree islands relative to the off-island core sites and the tail of the tree islands, which suggests that bedrock 'highs' acted as 'seeds' for the development of the tree islands of this study and possibly many others. Secondly, examination of the recovered core and the caliper logs tentatively suggest that the elevated limestone beneath the tree islands may have a preferentially more porous framework relative to limestone beneath the adjacent areas, possibly providing a ground-water-to-surface-water connection that sustains the tree island system. Finally, because the elevation of the top of the limestone bedrock at the head of Tree Island 3AS3 is slightly higher than the surrounding upper surface of the peat, and because the wetland peats have a lower hydraulic conductivity than the limestone bedrock (Miami Limestone and Fort Thompson Formation), it is possible that there is a head difference between surface water of the wetlands and the ground water in underlying limestone bedrock.

Use of fly ash in diets of cage and floor broilers

DOE Office of Scientific and Technical Information (OSTI.GOV)

Pharr, C.L.; Andrews, L.D.

1980-09-01

Three experiments were conducted to compare limestone to fly ash from a coal-fired generator station as a calcium source for broilers. In experiment 1, 5 male and 5 female broiler chicks were placed in each of 32 cages. Sixteen cages of birds were fed a ration with limestone supplying 30% of the total calcium and 16 cages were fed a ration with 30% of the total calcium supplied by fly ash. The total calcium and phosphorus levels of the rations were 1.0% and .5%, respectively. In this experiment no significant difference was found for 8-week body weight between diets wheremore » the added calcium was from limestone or fly ash. In experiment 2 a group of 40 male and 40 female cage reared broilers and 40 male and 40 female floor reared broilers were fed a basal diet of limestone providing 33% of the total calcium. Three diets with increasing fly ash levels were fed to three cage groups of 40 male and 40 female broilers providing 33, 46, and 45% of the total calcium of .9, 1.1, and 1.8%, respectively. Broilers fed the highest fly ash level weighed significantly less at 8 weeks than the caged controls but did not differ from the other treatments. Bone breaking strength as measured by the Allo Kramer Shear Press was similar between the basal and low level fly ash group and increased with higher fly ash levels. In experiment 3 four groups of 40 male broilers in cages were fed limestone diets with graded levels of limestone for the calcium source. Another four groups of 40 caged male broilers were fed fly ash diets with equivalent graded levels of fly ash for the calcium source. Both limestone and fly ash diets provided .17, .34, .51, and .68% calcium of a total calcium content of .28, .45, .62, and .79%, respectively.« less

Characterization of environmentally-friendly alkali activated slag cements and ancient building materials

NASA Astrophysics Data System (ADS)

Sakulich, Aaron Richard

Alternative cement technologies are an area of increasing interest due to growing environmental concerns and the relatively large carbon footprint of the cement industry. Many new cements have been developed, but one of the most promising is that made from granulated, ground blast furnace slag activated by a high-pH solution. Another is related to the discovery that some of the pyramid limestone blocks may have been cast using a combination of diatomaceous earth activated by lime which provides the high pH needed to dissolve the diatomaceous earth and bind the limestone aggregate together. The emphasis of this thesis is not on the latter---which was explored elsewhere---but on the results supplying further evidence that some of the pyramid blocks were indeed reconstituted limestone. The goal of this work is to chemically and mechanically characterize both alkali-activated slag cements as well as a number of historic materials, which may be ancient analogues to cement. Alkali activated slag cements were produced with a number of additives; concretes were made with the addition of a fine limestone aggregate. These materials were characterized mechanically and by XRD, FTIR, SEM, and TGA. Samples from several Egyptian pyramids, an 'ancient floor' in Colorado, and the 'Bosnian Pyramids' were investigated. In the cements, it has been unequivocally shown that C-S-H, the same binding phase that is produced in ordinary portland cement, has been produced, as well as a variety of mineral side products. Significant recarbonation occurs during the first 20 months, but only for the Na2CO3-activated formulae. Radiocarbon dating proves that the 'Bosnian Pyramids' and 'ancient floors' are not made from any type of recarbonated lime; however, Egyptian pyramid limestones were finite, thus suggesting that they are of a synthetic nature. XRD and FTIR results were inconclusive, while TGA results indicate the limestones are identical to naturally occurring limestones, and SEM/EDS analysis shows the presence of a Si-rich species.

Improving DMS 9210 requirements for limestone rock asphalt - final report.

DOT National Transportation Integrated Search

2015-03-01

Limestone Rock Asphalt (LRA) mixtures have been produced and placed for several decades using : specification requirements currently listed under DMS 9210. Several districts have had placement issues : and premature failures at the beginning of 2010....

Response of macroinvertebrate communities to remediation-simulating conditions in Pennsylvania streams influenced by acid mine drainage

USGS Publications Warehouse

Ross, R.M.; Long, E.S.; Dropkin, D.S.

2008-01-01

We compared naturally alkaline streams with limestone lithology to freestone streams with and without acid mine drainage (AMD) to predict benthic macroinvertebrate community recovery from AMD in limestone-treated watersheds. Surrogate-recovered (limestone) and, in many cases, freestone systems had significantly higher macroinvertebrate densities; diversity; taxa richness; Ephemeroptera, Plecoptera, and Trichoptera (EPT) taxa; EPT/chironomid ratios; scraper/collector - gatherer ratios; herbivores; collector - filterers; and scrapers. AMD-influenced systems had significantly greater numbers of Diptera and collector - gatherers. An entire trophic level (herbivores) was 'restored' in surrogate-recovered streams, which also showed greater trophic specialization. Indicator analysis identified seven taxa (within Crustacea, Diptera, Nematoda, Trichoptera, and Ephemeroptera) as significant indicators of limestone systems and six taxa (within Ephemeroptera, Plecoptera, Tricoptera, Coleoptera, and Mollusca) as significant freestone indicators, all useful as biological indicators of recovery from AMD. ?? Springer Science+Business Media B.V. 2007.

Franciscan complex calera limestones: Accreted remnants of farallon plate oceanic plateaus

USGS Publications Warehouse

Tarduno, J.A.; McWilliams, M.; Debiche, M.G.; Sliter, W.V.; Blake, M.C.

1985-01-01

The Calera Limestone, part of the Franciscan Complex of northern California, may have formed in a palaeoenvironment similar to Hess and Shatsky Rises of the present north-west Pacific1. We report here new palaeomagnetic results, palaeontological data and recent plate-motion models that reinforce this assertion. The Calera Limestone may have formed on Farallon Plate plateaus, north of the Pacific-Farallon spreading centre as a counterpart to Hess or Shatsky Rises. In one model2, the plateaus were formed by hotspots close to the Farallon_Pacific ridge axis. On accretion to North America, plateau dissection in the late Cretaceous to Eocene (50-70 Myr) could explain the occurrence of large volumes of pillow basalt and exotic blocks of limestone in the Franciscan Complex. Partial subduction of the plateaus could have contributed to Laramide (70-40 Myr) compressional events3. ?? 1985 Nature Publishing Group.

Statistical scaling of pore-scale Lagrangian velocities in natural porous media.

PubMed

Siena, M; Guadagnini, A; Riva, M; Bijeljic, B; Pereira Nunes, J P; Blunt, M J

2014-08-01

We investigate the scaling behavior of sample statistics of pore-scale Lagrangian velocities in two different rock samples, Bentheimer sandstone and Estaillades limestone. The samples are imaged using x-ray computer tomography with micron-scale resolution. The scaling analysis relies on the study of the way qth-order sample structure functions (statistical moments of order q of absolute increments) of Lagrangian velocities depend on separation distances, or lags, traveled along the mean flow direction. In the sandstone block, sample structure functions of all orders exhibit a power-law scaling within a clearly identifiable intermediate range of lags. Sample structure functions associated with the limestone block display two diverse power-law regimes, which we infer to be related to two overlapping spatially correlated structures. In both rocks and for all orders q, we observe linear relationships between logarithmic structure functions of successive orders at all lags (a phenomenon that is typically known as extended power scaling, or extended self-similarity). The scaling behavior of Lagrangian velocities is compared with the one exhibited by porosity and specific surface area, which constitute two key pore-scale geometric observables. The statistical scaling of the local velocity field reflects the behavior of these geometric observables, with the occurrence of power-law-scaling regimes within the same range of lags for sample structure functions of Lagrangian velocity, porosity, and specific surface area.

Stratigraphy and depositional environment of early Mississippian Joana limestone of east-central Nevada

DOE Office of Scientific and Technical Information (OSTI.GOV)

Gilmore, T.

1987-08-01

The Early Mississippian Joana Limestone in the southern Schell Creek and Egan Ranges of east-central Nevada is divided into nine rock types: mudstone, fossiliferous mudstone, wackestone, peloidal wackestone, pelmatozoan wackestone, pelmatozoan packstone, pelmatozoan grainstone, and ooid packstone. From the combined rock type and larger scale outcrop information, three depositional facies were identified: (1) unbedded subtidal, (2) bedded subtidal, and (3) restricted subtidal, each containing a unique set of diagnostic microfacies. Facies thicknesses, lithologies, and contacts with adjacent stratigraphic units indicate a highly varied paleotopography of localized highs and basins during Joana deposition. It is suggested that Waulsortian-type buildups occur downslopemore » of some paleohighs in the unbedded subtidal facies. An age of upper Kinderhookian to lowest Osagean within the Mississippian Period was determined for the Joana, based primarily on conodonts and foraminifera. In the middle beds of the Joana, the previously unreported upper Siphonodella crenulata conodont zone occurs and relates the timing of the Joana to regional geologic events. Color alteration indices of these conodonts are 1.5 to 2, and occur in the oil generation window. Additionally, oil staining was noted in numerous samples primarily from the lower half of the formation, represented by the unbedded subtidal facies. Porosities of the formation are varied, ranging from no visible porosity to over 20% interparticle porosity in some pelmatozoan grainstones.« less

Acid mine treatment with open limestone channels

DOE Office of Scientific and Technical Information (OSTI.GOV)

Ziemkiewicz, P.F.; Brant, D.L.; Skousen, J.G.

1996-12-31

Acid mine drainage (AMD) is often associated with mining of pyritic coal and metal deposits. Typical AMD associated with coal mines in the eastern US can have acidity and iron concentrations ranging from the teens to the thousands of mg/l. Aluminum and manganese can be present in concentrations ranging from zero to the low hundreds of mg/l. Much attention has been devoted to developing inexpensive, limestone (LS)-based systems for treating AMID with little or no maintenance. However, LS tends to coat with metal hydroxides when exposed to AMID in an oxidized state, a process known as {open_quotes}armoring{close_quotes}. It is generallymore » assumed that once armored, LS ceases to neutralize acid. Another problem is that the hydroxides tend to settle into plug the pore spaces in LS beds forcing water to move around rather than through the LS. While both are caused by the precipitation of metal hydroxides, armoring and plugging are two different problems. Plugging of LS pores can be avoided by maintaining a high flushing rate through the LS bed. Armoring, however, occurs regardless of water velocity. This study investigated the influence of armoring on LS solubility and the implications of armoring and plugging on the construction of open (oxidizing) LS channels for treating AMD. We evaluated the AMID treatment performance of armored and unarmored LS in oxidizing environments both in laboratory and field studies.« less

Correlation of Mohawkian (Ordovician) K-bentonites in post-Black River rocks of Ohio, Kentucky, and Michigan

DOE Office of Scientific and Technical Information (OSTI.GOV)

Schumacher, G.A.; Carlton, R.W.; Bergstroem, S.M.

1992-01-01

One to 10 K-bentonites are recognized in the Curdsville and Logana Members of the Lexington Limestone of Kentucky and southwestern Ohio and in coeval strata in west-central and northwestern Ohio and southeastern Michigan. These beds occur in the Phragmodus undatus and Amorphognathus tyaerensis conodont zones and the Orthograptus ruedemanni and Climacograptus spiniferus graptolite zones. Individual beds range in thickness from 1 mm to 30 cm and occur 16 cm to 19 m above the base of the Lexington Limestone and equivalents. Seventy-five percent of the observed K-bentonites occur in three narrow stratigraphic intervals. Some K-bentonites are traceable over parts ofmore » Ohio but insufficient data from northern Kentucky and west-central Ohio complicate regional lithostratigraphic correlation. Conodont biostratigraphy suggests that each k-bentonite complex is correlative regionally. Most conodont species range throughout all, or most, of the study interval but the ranges of Belodina compressa, Polyplacognathus ramosus, and Amorphognathus tyaerensis show only minor overlap. Preliminary correlation suggests that the oldest K- bentonite complex occurs in the interval characterized by B. compressa, the second complex in the P. Ramosus interval, and the third complex in the A. tyaerensis interval. This study provides the basis for potential correlation with coeval K-bentonites in areas outside of the study area. Also it provides an enhanced understanding of the lithostratigraphy and conodont biofacies of this complex stratigraphic interval. The K-bentonite succession also adds information on the timing of the initiation of the Sebree Trough.« less

Dynamics of soil organic carbon in density fractions during post-agricultural succession over two lithology types, southwest China.

PubMed

Wen, Li; Li, Dejun; Chen, Hao; Wang, Kelin

2017-10-01

Agricultural abandonment has been proposed as an effective way to enhance soil organic carbon (SOC) sequestration. Nevertheless, SOC sequestration in the long term is largely determined by whether the stable SOC fractions will increase. Here the dynamics of SOC fractions during post-agricultural succession were investigated in a karst region, southwest China using a space-for-time substitution approach. Cropland, grassland, shrubland and secondary forest were selected from areas underlain by dolomite and limestone, respectively. Density fractionation was used to separate bulk SOC into free light fraction (FLFC) and heavy fraction (HFC). FLFC contents were similar over dolomite and limestone, but bulk SOC and HFC contents were greater over limestone than over dolomite. FLFC content in the forest was greater than in the other vegetation types, but bulk SOC and HFC contents increased from the cropland through to the forest for areas underlain by dolomite. The contents of bulk SOC and its fractions were similar among the four vegetation types over limestone. The proportion of FLFC in bulk SOC was higher over dolomite than over limestone, but the case was inverse for the proportion of HFC, indicating SOC over limestone was more stable. However, the proportions of both FLFC and HFC were similar among the four vegetation types, implying that SOC stability was not changed by cropland conversion. Exchangeable calcium explained most of the variance of HFC content. Our study suggests that lithology not only affects SOC content and its stability, but modulates the dynamics of SOC fractions during post-agricultural succession. Copyright © 2017 Elsevier Ltd. All rights reserved.

Constraints on a Late Cretaceous uplift, denudation, and incision of the Grand Canyon region, southwestern Colorado Plateau, USA, from U-Pb dating of lacustrine limestone

NASA Astrophysics Data System (ADS)

Hill, Carol A.; Polyak, Victor J.; Asmerom, Yemane; P. Provencio, Paula

2016-04-01

The uplift and denudation of the Colorado Plateau is important in reconstructing the geomorphic and tectonic evolution of western North America. A Late Cretaceous (64 ± 2 Ma) U-Pb age for the Long Point limestone on the Coconino Plateau, which overlies a regional erosional surface developed on Permo-Triassic formations, supports unroofing of the Coconino Plateau part of Grand Canyon by that time. U-Pb analyses of three separate outcrops of this limestone gave ages of 64.0 ± 0.7, 60.5 ± 4.6, and 66.3 ± 3.9 Ma, which dates are older than a fossil-based, early Eocene age. Samples of the Long Point limestone were dated using the isotope dilution isochron method on well-preserved carbonates having high-uranium and low-lead concentrations. Our U-Pb ages on the Long Point limestone place important constraints on the (1) time of tectonic uplift of the southwestern Colorado Plateau and Kaibab arch, (2) time of denudation of the Coconino Plateau, and (3) Late Cretaceous models of paleocanyon incision west of, or across, the Kaibab arch. We propose that the age of the Long Point limestone, interbedded within the Music Mountain Formation in the Long Point area, represents a period of regional aggradation and a time of drainage blockage northward and eastward across the Kaibab arch, with possible diversion of northward drainage on the Coconino Plateau westward around the arch via a Laramide paleo-Grand Canyon.

Assessment of Environmental Impacts of Limestone Quarrying Operations in Thailand

NASA Astrophysics Data System (ADS)

Kittipongvises, Suthirat

2017-11-01

Environmental impacts of the mineral extraction have been a public concern. Presently, there is widespread global interest in the area of mining and its sustainability that focused on the need to shift mining industry to a more sustainable framework. The aim of this study was to systematically assess all possible environmental and climate change related impacts of the limestone quarrying operation in Thailand. By considering the life cycle assessment method, the production processes were divided into three phases: raw material extraction, transportation, and comminution. Both IMPACT 2002+ and the Greenhouse Gas Protocol methods were used. Results of IMPACT 2002+ analysis showed that per 1 ton crushed limestone rock production, the total depletion of resource and GHGs emissions were 79.6 MJ and 2.76 kg CO2 eq., respectively. Regarding to the four damage categories, `resources' and `climate change' categories were the two greatest environmental impacts of the limestone rock production. Diesel fuel and electricity consumption in the mining processes were the main causes of those impacts. For climate change, the unit of CO2 eq. was expressed to quantify the total GHGs emissions. Estimated result was about 3.13 kg CO2 eq. per ton limestone rock product. The results obtained by the Greenhouse Gas Protocol were also similar to IMPACT 2002+ method. Electrical energy consumption was considered as the main driver of GHGs, accounting for approximately 46.8 % of total fossil fuel CO2 emissions. A final point should be noted that data uncertainties in environmental assessment over the complete life cycle of limestone quarrying operation have to be carefully considered.

Late Mississippian productoid brachiopods Inflatia, Keokukia, and Adairia, Ozark region of Oklahoma and Arkansas

USGS Publications Warehouse

Gordon, M.; Henry, T.W.; Treworgy, J.D.

1993-01-01

Specimens of the Late Mississippian productoid genera Inflatia and Keokukia from northeastern Oklahoma and northwestern Arkansas, collected from the Boone and "Moorefield' formations, Hindsville Limestone, and Fayetteville Shale, display morphologic similarities and differences that delineate species and determine their biostratigraphic ranges. Generic assignments are based primarily on internal characters. Systematic descriptions include seven species of Inflatia Muir-Wood and Cooper. Also proposed and described is a new genus, Adairia, with its type species Productus (Marginifera) adairensis Drake. All these species of Inflatia, Keokukia and Adairia have biostratigraphically restricted ranges within the Meramecian and Chesterian sequence in the Ozark region. -from Authors

DOE Office of Scientific and Technical Information (OSTI.GOV)

Kristiansen, J.I.; Balliny, N.; Saxov, S.

Some available information on thermal conductivity of earth materials from the Scandinavian area is collected. The mean conductivities as reported from individual localities are grouped in crystalline and sedimentary rocks. Mean results are displayed in histograms and localities are mapped. The collocation of conductivity information contains new results of granites and sedimentary rocks from Sweden and of limestones and clays from Danish borings. The new values are presented as histograms of individual measurements and given as mean values with standard errors of mean. The crystalline rocks range from about 2 to about 4 W/ (m K), and the sedimentary rocksmore » range from about 0.8 to about 6 W/ (m K).« less

Habitat association, size, stomach contents, and reproductive condition of Puerto Rican boas (Epicrates inornatus)

USGS Publications Warehouse

Wiley, J.W.

2003-01-01

The Puerto Rican boa occurs in a variety of habitats, including wet montane forest, lowland wet forest, mangrove forest, wet limestone karst, and offshore cays, and from sea level to 480 m. Mean SVL of 49 encountered boas (live and road-killed) was 136.9 ?? 35.1 (range = 38.8-205 cm), with a mean mass of 952.1 ?? 349.0 g (n = 47; range = 140-1662 g). Prey in digestive tracts (n = 29) included remains of black rats, house mice, three species of anoles, bats, common ground-doves, domestic fowl chicks, and invertebrates. Females were in reproductive condition in late April through mid-August and had an average brood size of 21.8 ?? 6.0 (n = 9, range = 13-30 ).