Lipid modulation of thermal transient receptor potential channels.

PubMed

Hernández-García, Enrique; Rosenbaum, Tamara

2014-01-01

There is a subgroup of transient receptor potential (TRP) ion channels that are responsive to temperature (thermo-TRP channels). These are important to a variety of sensory and physiological phenomena such as pain and taste perception. All thermo-TRP channels known to date are subject to modulation by lipidic molecules of many kinds, from the ubiquitous cholesterol to more specialized molecules such as prostaglandins. Although the mechanisms and sites of binding of lipids on thermo-TRPs are largely unknown, the explosion on research of lipids and ion channels has revealed previously unsuspected roles for them. Diacyl glycerol is a lipid produced by phospholipase C (PLC) and it was discovered to modulate TRP channels in the eye of the fly, and many mammal TRP channels have been found to interact with lipids. While most of the lipids acting on thermo-TRP channels have been found to activate them, there are a few capable of inhibition. Phosphatidylinositol 4,5-bisphosphate is even capable of both inhibition and activation on a couple of thermo-TRPs, depending on the cellular context. More data is required to assess the mechanism through which lipids affect thermo-TRP channel activity and the physiological importance of this interaction.

Broadly tunable thin-film intereference coatings: active thin films for telecom applications

NASA Astrophysics Data System (ADS)

Domash, Lawrence H.; Ma, Eugene Y.; Lourie, Mark T.; Sharfin, Wayne F.; Wagner, Matthias

2003-06-01

Thin film interference coatings (TFIC) are the most widely used optical technology for telecom filtering, but until recently no tunable versions have been known except for mechanically rotated filters. We describe a new approach to broadly tunable TFIC components based on the thermo-optic properties of semiconductor thin films with large thermo-optic coefficients 3.6X10[-4]/K. The technology is based on amorphous silicon thin films deposited by plasma-enhanced chemical vapor deposition (PECVD), a process adapted for telecom applications from its origins in the flat-panel display and solar cell industries. Unlike MEMS devices, tunable TFIC can be designed as sophisticated multi-cavity, multi-layer optical designs. Applications include flat-top passband filters for add-drop multiplexing, tunable dispersion compensators, tunable gain equalizers and variable optical attenuators. Extremely compact tunable devices may be integrated into modules such as optical channel monitors, tunable lasers, gain-equalized amplifiers, and tunable detectors.

Thermo-Osmotic Flow in Thin Films.

PubMed

Bregulla, Andreas P; Würger, Alois; Günther, Katrin; Mertig, Michael; Cichos, Frank

2016-05-06

We report on the first microscale observation of the velocity field imposed by a nonuniform heat content along the solid-liquid boundary. We determine both radial and vertical velocity components of this thermo-osmotic flow field by tracking single tracer nanoparticles. The measured flow profiles are compared to an approximate analytical theory and to numerical calculations. From the measured slip velocity we deduce the thermo-osmotic coefficient for both bare glass and Pluronic F-127 covered surfaces. The value for Pluronic F-127 agrees well with Soret data for polyethylene glycol, whereas that for glass differs from literature values and indicates the complex boundary layer thermodynamics of glass-water interfaces.

Thermo-mechanical analysis of an internal cooling system with various configurations of a combustion liner after shell

NASA Astrophysics Data System (ADS)

Moon, Hokyu; Kim, Kyung Min; Park, Jun Su; Kim, Beom Seok; Cho, Hyung Hee

2015-12-01

The after-shell section, which is part of the gas turbine combustion liner, is exposed to the hottest combustion gas. Various cooling schemes have been applied to protect against severe thermal load. However, there is a significant discrepancy in the thermal expansion with large temperature differences, resulting in thermo-mechanical crack formation. In this study, to reduce combustion liner damage, thermo-mechanical analysis was conducted on three after-shell section configurations: inline-discrete divider wall, staggered divider wall, and swirler wall arrays. These array components are well-known heat-transfer enhancement structures in the duct. In the numerical analyses, the heat transfer characteristics, temperature and thermo-mechanical stress distribution were evaluated using finite volume method and finite element method commercial codes. As a result, we demonstrated that the temperature and the thermo-mechanical stress distribution were readily dependent on the structural array for cooling effectiveness and structural support in each modified cooling system. Compared with the reference model, the swirler wall array was most effective in diminishing the thermo-mechanical stress concentration, especially on the inner ring that is vulnerable to crack formation.

Mechanism study of biopolymer hair as a coupled thermo-water responsive smart material

NASA Astrophysics Data System (ADS)

Xiao, Xueliang; Zhou, Hongtao; Qian, Kun

2017-03-01

Animal hairs existing broadly in nature are found to be effectively responsive to stimuli of heat and water in sequence for shape deformation and recovery, namely, coupled shape memory function (CSMF). In the paper, the ability of thermo-water sensitive CSMF was first time investigated for animal hairs, the structural and molecular networks for net-points and switches were therefrom identified. Experimentally, animal hair manifested a high ability of shape fixation in thermal processing and good shape recovery by water stimulus. Characterizations of two stimuli (heating and hydration) were performed systematically on hair’s deformation, recovery, viscoelasticity and chemical components (crystalline phase, key bonds inamorphous area). The variations of related chemical components in molecular networks were also explored. A hybrid structural network model was thereafter proposed to interpret the thermo-water sensitive CSMF of hair. This study of two-sequential-stimuli CSMF is original and inspired to explore more complex functions of other smart natural materials and expected to make much smarter synthetic polymers.

FE-simulation of hot forging with an integrated heat treatment with the objective of residual stress prediction

NASA Astrophysics Data System (ADS)

Behrens, Bernd-Arno; Chugreeva, Anna; Chugreev, Alexander

2018-05-01

Hot forming as a coupled thermo-mechanical process comprises numerous material phenomena with a corresponding impact on the material behavior during and after the forming process as well as on the final component performance. In this context, a realistic FE-simulation requires reliable mathematical models as well as detailed thermo-mechanical material data. This paper presents experimental and numerical results focused on the FE-based simulation of a hot forging process with a subsequent heat treatment step aiming at the prediction of the final mechanical properties and residual stress state in the forged component made of low alloy CrMo-steel DIN 42CrMo4. For this purpose, hot forging experiments of connecting rod geometry with a corresponding metallographic analysis and x-ray residual stress measurements have been carried out. For the coupled thermo-mechanical-metallurgical FE-simulations, a special user-defined material model based on the additive strain decomposition method and implemented in Simufact Forming via MSC.Marc solver features has been used.

Strain Compatible Oxidation and Corrosion Protection Coatings for Enhanced Thermo-Mechanical Durability of Turbine Airfoils

DTIC Science & Technology

2011-12-05

Report: Grant N00014-08-0331 Technical Objectives As critical components of advanced aircraft engines , turbine airfoils require coatings for...advanced aircrafi engines , turbine airfoils require coatings for enhancement of oxidation, corrosion and thermal capabilities . Airfoil coatings ofien...Oxidation and Corrosion Protection Coatings for Enhanced Thermo-Mechanical Durability of Turbine Airfoils 5b. GRANT NUMBER N00014-08-l-0331 5c

Thermally activated TRP channels: molecular sensors for temperature detection.

PubMed

Castillo, Karen; Diaz-Franulic, Ignacio; Canan, Jonathan; Gonzalez-Nilo, Fernando; Latorre, Ramon

2018-01-24

Temperature sensing is one of the oldest capabilities of living organisms, and is essential for sustaining life, because failure to avoid extreme noxious temperatures can result in tissue damage or death. A subset of members of the transient receptor potential (TRP) ion channel family is finely tuned to detect temperatures ranging from extreme cold to noxious heat, giving rise to thermoTRP channels. Structural and functional experiments have shown that thermoTRP channels are allosteric proteins, containing different domains that sense changes in temperature, among other stimuli, triggering pore opening. Although temperature-dependence is well characterized in thermoTRP channels, the molecular nature of temperature-sensing elements remains unknown. Importantly, thermoTRP channels are involved in pain sensation, related to pathological conditions. Here, we provide an overview of thermoTRP channel activation. We also discuss the structural and functional evidence supporting the existence of an intrinsic temperature sensor in this class of channels, and we explore the basic thermodynamic principles for channel activation. Finally, we give a view of their role in painful pathophysiological conditions.

Thermodynamic potential of free energy for thermo-elastic-plastic body

NASA Astrophysics Data System (ADS)

Śloderbach, Z.; Pająk, J.

2018-01-01

The procedure of derivation of thermodynamic potential of free energy (Helmholtz free energy) for a thermo-elastic-plastic body is presented. This procedure concerns a special thermodynamic model of a thermo-elastic-plastic body with isotropic hardening characteristics. The classical thermodynamics of irreversible processes for material characterized by macroscopic internal parameters is used in the derivation. Thermodynamic potential of free energy may be used for practical determination of the level of stored energy accumulated in material during plastic processing applied, e.g., for industry components and other machinery parts received by plastic deformation processing. In this paper the stored energy for the simple stretching of austenitic steel will be presented.

Automatic Analyzers and Signal Indicators of Toxic and Dangerously Explosive Substances in Air,

DTIC Science & Technology

1980-01-09

of air are used also thermo- conductometry and electroconductometric methods. The thermo- conductometry method of analysis is based on a change of the... conductometry gas analyzers is very limited and is reduced in essence to the analysis of two-component mixtures or multicomponent ones, all whose...differs. Rain disadvantage in tae tnormo- conductometry gas analyzers - increased sensitivity to a change in the ambient conditions, in consequence of

Online monitoring of thermo-cycles and its correlation with microstructure in laser cladding of nickel based super alloy

NASA Astrophysics Data System (ADS)

Muvvala, Gopinath; Patra Karmakar, Debapriya; Nath, Ashish Kumar

2017-01-01

Laser cladding, basically a weld deposition technique, is finding applications in many areas including surface coatings, refurbishment of worn out components and generation of functionally graded components owing to its various advantages over conventional methods like TIG, PTA etc. One of the essential requirements to adopt this technique in industrial manufacturing is to fulfil the increasing demand on product quality which could be controlled through online process monitoring and correlating the signals with the mechanical and metallurgical properties. Rapid thermo-cycle i.e. the fast heating and cooling rates involved in this process affect above properties of the deposited layer to a great extent. Therefore, the current study aims to monitor the thermo-cycles online, understand its variation with process parameters and its effect on different quality aspects of the clad layer, like microstructure, elemental segregations and mechanical properties. The effect of process parameters on clad track geometry is also studied which helps in their judicious selection to deposit a predefined thickness of coating. In this study Inconel 718, a nickel based super alloy is used as a clad material and AISI 304 austenitic steel as a substrate material. The thermo-cycles during the cladding process were recorded using a single spot monochromatic pyrometer. The heating and cooling rates were estimated from the recorded thermo-cycles and its effects on microstructures were characterised using SEM and XRD analyses. Slow thermo-cycles resulted in severe elemental segregations favouring Laves phase formation and increased γ matrix size which is found to be detrimental to the mechanical properties. Slow cooling also resulted in termination of epitaxial growth, forming equiaxed grains near the surface, which is not preferred for single crystal growth. Heat treatment is carried out and the effect of slow cooling and the increased γ matrix size on dissolution of segregated elements in metal matrix is studied.

Macroscopic constitutive equations of thermo-poroviscoelasticity derived using eigenstrains

NASA Astrophysics Data System (ADS)

Suvorov, A. P.; Selvadurai, A. P. S.

2010-10-01

Macroscopic constitutive equations for thermo-viscoelastic processes in a fully saturated porous medium are re-derived from basic principles of micromechanics applicable to solid multi-phase materials such as composites. Simple derivations of the constitutive relations and the void occupancy relationship are presented. The derivations use the notion of eigenstrain or, equivalently, eigenstress applied to the separate phases of a porous medium. Governing coupled equations for the displacement components and the fluid pressure are also obtained.

Rapid analysis of controlled substances using desorption electrospray ionization mass spectrometry.

PubMed

Rodriguez-Cruz, Sandra E

2006-01-01

The recently developed technique of desorption electrospray ionization (DESI) has been applied to the rapid analysis of controlled substances. Experiments have been performed using a commercial ThermoFinnigan LCQ Advantage MAX ion-trap mass spectrometer with limited modifications. Results from the ambient sampling of licit and illicit tablets demonstrate the ability of the DESI technique to detect the main active ingredient(s) or controlled substance(s), even in the presence of other higher-concentration components. Full-scan mass spectrometry data provide preliminary identification by molecular weight determination, while rapid analysis using the tandem mass spectrometry (MS/MS) mode provides fragmentation data which, when compared to the laboratory-generated ESI-MS/MS spectral library, provide structural information and final identification of the active ingredient(s). The consecutive analysis of tablets containing different active components indicates there is no cross-contamination or interference from tablet to tablet, demonstrating the reliability of the DESI technique for rapid sampling (one tablet/min or better). Active ingredients have been detected for tablets in which the active component represents less than 1% of the total tablet weight, demonstrating the sensitivity of the technique. The real-time sampling of cannabis plant material is also presented.

ε-Polylysine-based thermo-responsive adsorbents for immunoglobulin adsorption-desorption under mild conditions.

PubMed

Maruyama, Masashi; Shibuya, Keisuke

2017-08-22

Thermo-responsive adsorbents for immunoglobulin G (IgG) employing ε-polylysine (EPL) as a polymer backbone were developed. The introduction of mercaptoethylpyridine (MEP) as an IgG-binding ligand and hydrophobization of side chains afforded thermo-responsive IgG adsorbents, whose thermo-responsive IgG desorption ratio was up to 88% (EPL/MEP derivative 3m). The changes in surface densities of active MEP groups, which are caused by thermal conformational changes of the adsorbents, play key roles for IgG desorption. Although a trade-off of IgG adsorption capacity and IgG desorption ratio was observed, the present study offers a novel molecular design for thermo-responsive adsorbents with high synthetic accessibility and potentially low toxicity.

Microstructural Evolution and Constitutive Relationship of M350 Grade Maraging Steel During Hot Deformation

NASA Astrophysics Data System (ADS)

Chakravarthi, K. V. A.; Koundinya, N. T. B. N.; Narayana Murty, S. V. S.; Nageswara Rao, B.

2017-03-01

Maraging steels exhibit extraordinary strength coupled with toughness and are therefore materials of choice for critical structural applications in defense, aerospace and nuclear engineering. Thermo-mechanical processing is an important step in the manufacture of these structural components. This process assumes significance as these materials are expensive and the mechanical properties obtained depend on the microstructure evolved during thermo-mechanical processing. In the present study, M350 grade maraging steel specimens were hot isothermally compressed in the temperature range of 900-1200 °C and in the strain rate range of 0.001-100 s-1, and true stress-true strain curves were generated. The microstructural evolution as a function of strain rate and temperature in the deformed compression specimens was studied. The effect of friction between sample and compression dies was evaluated, and the same was found to be low. The measured flow stress data was used for the development of a constitutive model to represent the hot deformation behavior of this alloy. The proposed equation can be used as an input in the finite element analysis to obtain the flow stress at any given strain, strain rate, and temperature useful for predicting the flow localization or fracture during thermo-mechanical simulation. The activation energy for hot deformation was calculated and is found to be 370.88 kJ/mol, which is similar to that of M250 grade maraging steel.

Modelling of the Thermo-Physical and Physical Properties for Solidification of Al-Alloys

NASA Astrophysics Data System (ADS)

Saunders, N.; Li, X.; Miodownik, A. P.; Schillé, J.-P.

The thermo-physical and physical properties of the liquid and solid phases are critical components in casting simulations. Such properties include the fraction solid transformed, enthalpy release, thermal conductivity, volume and density, all as a function of temperature. Due to the difficulty in experimentally determining such properties at solidification temperatures, little information exists for multi-component alloys. As part of the development of a new computer program for modelling of materials properties (JMatPro) extensive work has been carried out on the development of sound, physically based models for these properties. Wide ranging results will presented for Al-based alloys, which will include more detailed information concerning the density change of the liquid that intrinsically occurs during solidification due to its change in composition.

Thermo-mechanical performance of precision C/SiC mounts

NASA Astrophysics Data System (ADS)

Goodman, William A.; Mueller, Claus E.; Jacoby, Marc T.; Wells, Jim D.

2001-12-01

For complex shaped, lightweight, high precision opto- mechanical structures that must operate in adverse environments and over wide ranges of temperature, we consider IABG's optical grade silicon carbide composite ceramic (C/SiC) as the material of choice. C/SiC employs conventional NC machining/milling equipment to rapidly fabricate near-net shape parts, providing substantial schedule, cost, and risk savings for high precision components. Unlike powder based SiC ceramics, C/SiC does not experience significant shrinkage during processing, nor does it suffer from incomplete densification. If required, e.g. for large-size components, a fully-monolithic ceramic joining technique can be applied. Generally, the thermal and mechanical properties of C/SiC are tunable in certain ranges by modifying certain process steps. This paper focuses on the thermo-mechanical performance of new, high precision mounts designed by Schafer Corporation and manufactured by IABG. The mounts were manufactured using standard optical grade C/SiC (formulation internally called A-3). The A-3 formulation has a near-perfect CTE match with silicon, making it the ideal material to athermally support Schafer produced Silicon Lightweight Mirrors (SLMs) that will operate in a cryogenic environment. Corresponding thermo- mechanical testing and analysis is presented in this manuscript.

Synthesis, characterization, and antibacterial activity of chitosan/TiO2 nanocomposite against Xanthomonas oryzae pv. oryzae.

PubMed

Li, Bin; Zhang, Yang; Yang, Yingzi; Qiu, Wen; Wang, Xiaoxuan; Liu, Baoping; Wang, Yanli; Sun, Guochang

2016-11-05

This present study deals with synthesis, characterization and antibacterial activity of chitosan/TiO2 nanocomposites. Results indicated that chitosan/TiO2 nanocomposite at the ratio of 1:5 showed the strongest inhibition in growth of rice bacterial pathogen Xanthomonas oryzae pv. oryzae (Xoo). Furthermore, the antibacterial activity of chitosan/TiO2 nanocomposite against Xoo is significantly higher than that of the two individual components under both light and dark conditions. Regardless of the presence or absence of extracellular polymeric substances, chitosan/TiO2 nanocomposite showed strong antibacterial activity, however, the absence increased the sensitivity of Xoo to chitosan/TiO2 nanocomposite. In addition, the surface morphology and physicochemical properties of chitosan/TiO2 nanocomposite is different from the two individual components based on scanning electron microscopic observation, fourier transform infrared spectra, and X-ray diffraction pattern, as well as elemental and thermo gravimetric analysis. Overall, this study indicated that this synthesized chitosan/TiO2 nanocomposite is promising to be developed as a new antibacterial material. Copyright © 2016 Elsevier Ltd. All rights reserved.

Fifty Years of Soviet and Russian Drilling Activity in Polar and Non-Polar Ice: A Chronological History

DTIC Science & Technology

2007-10-01

max 175 m) Thermo-electric point “Elektroigla ETI-1” Sukhanov et al., 1974 113 Thermal drill LKTBM-1 1973 50.7 Thermal Coring drill...Glacier (West Caucasus), #C3 IGAS, Moscow State University 20 m (?) Thermo-electric point Sukhanov et al., 1974 1970, 1971 Five holes with...total depth of 405 m (max 111 m) Thermo-electric point Elektroigla ETI-1 Sukhanov , 1973; Sukhanov et al., 1974 1972 A few holes with total

An organic solvent-, detergent-, and thermo-stable alkaline protease from the mesophilic, organic solvent-tolerant Bacillus licheniformis 3C5.

PubMed

Rachadech, W; Navacharoen, A; Ruangsit, W; Pongtharangkul, T; Vangnai, A S

2010-01-01

Bacillus licheniformis 3C5, isolated as mesophilic bacterium, exhibited tolerance towards a wide range of non-polar and polar organic solvents at 45 degrees C. It produced an extracellular organic solvent-stable protease with an apparent molecular mass of approximately 32 kDa. The inhibitory effect of PMSF and EDTA suggested it is likely to be an alkaline serine protease. The protease was active over abroad range of temperatures (45-70 degrees C) and pH (8-10) range with an optimum activity at pH 10 and 65 degrees C. It was comparatively stable in the presence ofa relatively high concentration (35% (v/v)) of organic solvents and various types of detergents even at a relatively high temperature (45 degrees C). The protease production by B. licheniformis 3C5 was growth-dependent. The optimization of carbon and nitrogen sources for cell growth and protease production revealed that yeast extract was an important medium component to support both cell growth and the protease production. The overall properties of the protease produced by B. licheniformis 3C5 suggested that this thermo-stable, solvent-stable, detergent-stable alkaline protease is a promising potential biocatalyst for industrial and environmental applications.

Evaluation of the effectiveness and safety of the thermo-treatment process to dispose of recombinant DNA waste from biological research laboratories.

PubMed

Li, Meng-Nan; Zheng, Guang-Hong; Wang, Lei; Xiao, Wei; Fu, Xiao-Hua; Le, Yi-Quan; Ren, Da-Ming

2009-01-01

The discharge of recombinant DNA waste from biological laboratories into the eco-system may be one of the pathways resulting in horizontal gene transfer or "gene pollution". Heating at 100 degrees C for 5-10 min is a common method for treating recombinant DNA waste in biological research laboratories in China. In this study, we evaluated the effectiveness and the safety of the thermo-treatment method in the disposal of recombinant DNA waste. Quantitative PCR, plasmid transformation and electrophoresis technology were used to evaluate the decay/denaturation efficiency during the thermo-treatment process of recombinant plasmid, pET-28b. Results showed that prolonging thermo-treatment time could improve decay efficiency of the plasmid, and its decay half-life was 2.7-4.0 min during the thermo-treatment at 100 degrees C. However, after 30 min of thermo-treatment some transforming activity remained. Higher ionic strength could protect recombinant plasmid from decay during the treatment process. These results indicate that thermo-treatment at 100 degrees C cannot decay and inactivate pET-28b completely. In addition, preliminary results showed that thermo-treated recombinant plasmids were not degraded completely in a short period when they were discharged into an aquatic environment. This implies that when thermo-treated recombinant DNAs are discharged into the eco-system, they may have enough time to re-nature and transform, thus resulting in gene diffusion.

Applicability of thermo-alkali-stable and cellulase-free xylanase from a novel thermo-halo-alkaliphilic Bacillus halodurans in producing xylooligosaccharides.

PubMed

Kumar, Vikash; Satyanarayana, T

2011-11-01

An alkaliphilic, moderately thermophilic and halophilic bacterial isolate capable of producing a high titer of extracellular thermo-alkali-stable, cellulase-free endoxylanase was isolated from the paper mill effluents. It was identified as Bacillus halodurans. The purified xylanase was active from pH 7 to 12 and 30 to 100°C with optimal activity at pH 9.0 and 80°C. It had T(1/2) values of 40 and 15 min at 70 and 80°C, respectively. Activity was stimulated by dithiothreitol but strongly inhibited by N-bromosuccinimide. Its action on birchwood xylan and agro-residues liberated xylooligosaccharides of 2-7 degree of polymerization, and thus, the mode of action is similar to endoxylanases of the family 10 glucoside hydrolases.

Mechanisms of Thermosensation in TRP Channels

NASA Astrophysics Data System (ADS)

Talavera, Karel; Voets, Thomas; Nilius, Bernd

The transient receptor potential (TRP) superfamily encompasses a large number of cationic channels that are modulated by a wide variety of physical and chemical stimuli. A notorious subgroup of TRP channels, dubbed thermoTRPs, shows a dramatic dependence on temperature, which can be up to tenfold higher than that of classical ionic channels. Consequently, some thermoTRPs are thought to have a prominent role in the mechanisms of thermosensation and thermoregulation. However, the mechanisms underlying the high temperature sensitivity of thermoTRP activation are, for the most part, obscure. Only four out of the nine thermoTRPs known so far are sufficiently well characterised to allow a comprehensive model to be put forward. Temperature modulates the gating of TRPM8, TRPV1, TRPM4 and TRPM5 by shifting the voltage dependence of channel activation towards more negative potentials, which can be accounted for by a model in which voltage-dependent gating is directly affected by temperature. Heat activation of TRPV3 seems to be consistent with this mechanism, although a modification of the pore may also take place. For TRPV4, it has been proposed that an, as yet unidentified, diffusible ligand mediates activation by heat. The mechanisms for TRPV2, TRPA1 and TRPM2 are still unknown.

Mechanical and Tribological Characteristics of the AMC, Prepared by P/M Route along with Thermo-Mechanical Treatment

NASA Astrophysics Data System (ADS)

Mohapatra, Sambit Kumar; Maity, Kalipada; Bhuyan, Subrat Kumar; Prasad Satpathy, Mantra

2018-03-01

Thermo mechanical treatments have the ameliorated impacts on the mechanical and tribological properties of powder metallurgy components. In this investigation an aluminium matrix composite (AMC) {Al (92) + Mg (5) + Gr (1) + Ti (2)} has been prepared by following powder metallurgy technique, with double axial compaction and ulterior sintering. Secondary thermo-mechanical treatment i.e. hot extrusion through mathematical contoured cosine profiled die was considered. The die causes minimum velocity relative differences across the extrusion exit cross-section, which provides smooth material flow. Comparative result analysis for the mechanical and tribological characteristics of the specimen before and after extrusion was concentrated. Extrusion engenders significant amount of improvements of the properties those are attributed to excellent bond strength and uniform density distribution due to high compressive stress. Oxidative and delaminated wear mechanisms were found predominating type. To furnish the suitable explanation scanning electron microscopies have been performed for the wear surfaces.

A coupled chemo-thermo-hygro-mechanical model of concrete at high temperature and failure analysis

NASA Astrophysics Data System (ADS)

Li, Xikui; Li, Rongtao; Schrefler, B. A.

2006-06-01

A hierarchical mathematical model for analyses of coupled chemo-thermo-hygro-mechanical behaviour in concretes at high temperature is presented. The concretes are modelled as unsaturated deforming reactive porous media filled with two immiscible pore fluids, i.e. the gas mixture and the liquid mixture, in immiscible-miscible levels. The thermo-induced desalination process is particularly integrated into the model. The chemical effects of both the desalination and the dehydration processes on the material damage and the degradation of the material strength are taken into account. The mathematical model consists of a set of coupled, partial differential equations governing the mass balance of the dry air, the mass balance of the water species, the mass balance of the matrix components dissolved in the liquid phases, the enthalpy (energy) balance and momentum balance of the whole medium mixture. The governing equations, the state equations for the model and the constitutive laws used in the model are given. A mixed weak form for the finite element solution procedure is formulated for the numerical simulation of chemo-thermo-hygro-mechanical behaviours. Special considerations are given to spatial discretization of hyperbolic equation with non-self-adjoint operator nature. Numerical results demonstrate the performance and the effectiveness of the proposed model and its numerical procedure in reproducing coupled chemo-thermo-hygro-mechanical behaviour in concretes subjected to fire and thermal radiation.

In situ Mössbauer investigation of iron oxide catalyst in water gas shift reaction - Impact of oxyreduction potential and temperature

NASA Astrophysics Data System (ADS)

Cherkezova-Zheleva, Z.; Mitov, I.

2010-03-01

The aim of the study is to obtain the exact state of iron oxide catalyst active phase in reaction conditions, as well as the correlation between the active phase and catalytic properties of iron-containing catalysts. In situ Mössbauer spectroscopy is the major investigation technique. It is established that the change of reaction conditions (temperature and gas reaction mixture) lead to redistribution of the relative weight of spectra components and influence mainly tetrahedrally and octahedrally coordinated cations in Fe3O4 phase. It was concluded, that the active sites of the catalyst in studied reaction are probably pairs of Fe3++Fe2+-(Fe2.5+) ions, i.e. the mixed valance iron ions. The obtained catalytic activity can be explained with combination of the natural thermo-activated and catalytically induced electron exchange and better synchronizing of oxidation and reduction steps of the catalytic reaction.

Computational Investigation on the performance of thermo-acoustically driven pulse tube refrigerator

NASA Astrophysics Data System (ADS)

Skaria, Mathew; Rasheed, K. K. Abdul; Shafi, K. A.; Kasthurirengan, S.; Behera, Upendra

2017-02-01

A Thermoacoustic Pulse Tube Refrigeration (TAPTR) system employs a thermo acoustic engine as the pressure wave generator instead of mechanical compressor. Such refrigeration systems are highly reliable due to the absence of moving components, structural simplicity and the use of environmental friendly working fluids. In the present work, a traveling wave thermoacoustic primmover (TWTAPM) has been developed and it is coupled to a pulse tube cryocooler. The performance of TAPTR depends on the operating and working fluid parameters. Simulation studies of the system has been performed using ANSYS Fluent and compared with experimental results.

Thermos reactors

DOE Office of Scientific and Technical Information (OSTI.GOV)

Labrousse, M.; Lerouge, B.; Dupuy, G.

1978-04-01

THERMOS is a water reactor designed to provide hot water up to 120/sup 0/C for district heating or for desalination applications. It is a 100-MW reactor based on proven technology: oxide fuel plate elements, integrated primary circuit, and reactor vessel located in the bottom of a pool. As in swimming pool reactors, the pool is used for biological shielding, emergency core cooling, and fission product filtering (in case of an accident). Before economics, safety is the main characteristic of the concept: no fuel failure admitted, core under water in any accidental configuration, inspection of every ''nuclear'' component, and double-wall containment.

Thermo-Oxidization of Municipal Wastewater Treatment Plant Sludge for Production of Class A Biosolids

EPA Science Inventory

Bench-scale reactors were used to test a novel thermo-oxidation process on municipal wastewater treatment plant (WWTP) waste activated sludge (WAS) using hydrogen peroxide (H₂O₂) to achieve a Class A sludge product appropriate for land application. Reactor ...

Occurrence of extractable ink residuals in packaging materials used in the Czech Republic.

PubMed

Dupáková, Z; Dobiás, J; Votavová, L; Klaudisová, K; Voldrich, M

2010-01-01

Residues of printing ink components were determined in 94 samples of packaging materials commercially used in the Czech Republic for food packaging. The samples tested included printed polyethylene and polypropylene films, co-extruded and laminated films, paperboard beverages boxes, foils for thermo sealing of polystyrene cups, and polypropylene cups. Printing ink components were extracted with diethylether, then separated and determined using gas chromatography-mass spectrometry (GC/MS). Fifty compounds potentially originating from printing were isolated, identified and quantified. No acute health risk for consumers were identified, even though several findings of high levels of photo-initiators (e.g. in polyethylene terephthalate (PET) films for thermo sealing of polystyrene cups) as well as plasticizers (acetyl tributyl citrate, tributyl aconitate, 2-butoxyethyl oleate and 2-ethylhexyl diphenyl phosphate in co-extruded films) indicate that their real migration into food and/or food simulants needs to be undertaken for a proper safety evaluation.

Thermodynamic Database for the NdO(1.5)-YO(1.5)-YbO(1.5)-ScO(1.5)-ZrO2 System

NASA Technical Reports Server (NTRS)

Jacobson, Nathan S.; Copland, Evan H.; Kaufman, Larry

2001-01-01

A database for YO(1.5)-NdO(1.5)-YbO(1.5)-ScO(1.5)-ZrO2 for ThermoCalc (ThermoCalc AB, Stockholm, Sweden) has been developed. The basis of this work is the YO(1.5)-ZrO2 assessment by Y. Du, Z. Jin, and P. Huang, 'Thermodynamic Assessment of the ZrO2-YO(1.5) System'. Experimentally only the YO(1.5)-ZrO2 system has been well-studied. All other systems are only approximately known. The major simplification in this work is the treatment of each single cation unit as a component. The pure liquid oxides are taken as reference states and two term lattice stability descriptions are used for each of the components. The limited experimental phase diagrams are reproduced.

Enhancing the functional and economical efficiency of a novel combined thermo chemical disperser disintegration of waste activated sludge for biogas production.

PubMed

Kavitha, S; Jayashree, C; Adish Kumar, S; Kaliappan, S; Rajesh Banu, J

2014-12-01

In this investigation, an effort was made to pretreat surplus waste activated sludge (WAS) inexpensively by a novel combined process involving thermo chemical disperser pretreatment. This pretreatment was found to be efficient at a specific energy (SE) consumption of 3360.94 kJ/kg TS, with the chemical oxygen demand (COD) solubilization of 20%. This was comparatively higher than thermo chemically treated sludge where the solubilization was found to be 15.5% at a specific energy consumption of 10,330 kJ/kg TS respectively. Higher production of volatile fatty acids (VFA) (675 mg/L) in anaerobic fermentation of pretreated WAS indicates better hydrolysis performance. The biogas production potential of sludge pretreated through this combined technique was found to be 0.455 (L/gVS) and comparatively higher than thermo chemically pretreated sludge. Economic investigation provides 90% net energy savings in this combined pretreatment. Therefore, this combined process was considered to be potentially effective and economical in sludge disintegration. Copyright © 2014 Elsevier Ltd. All rights reserved.

New Strategies to Develop Novel Pain Therapies: Addressing Thermoreceptors from Different Points of View

PubMed Central

Fernández-Carvajal, Asia; Fernández-Ballester, Gregorio; Devesa, Isabel; González-Ros, José Manuel; Ferrer-Montiel, Antonio

2011-01-01

One approach to develop successful pain therapies is the modulation of dysfunctional ion channels that contribute to the detection of thermal, mechanical and chemical painful stimuli. These ion channels, known as thermoTRPs, promote the sensitization and activation of primary sensory neurons known as nociceptors. Pharmacological blockade and genetic deletion of thermoTRP have validated these channels as therapeutic targets for pain intervention. Several thermoTRP modulators have progressed towards clinical development, although most failed because of the appearance of unpredicted side effects. Thus, there is yet a need to develop novel channel modulators with improved therapeutic index. Here, we review the current state-of-the art and illustrate new pharmacological paradigms based on TRPV1 that include: (i) the identification of activity-dependent modulators of this thermoTRP channel; (ii) the design of allosteric modulators that interfere with protein-protein interaction involved in the functional coupling of stimulus sensing and gate opening; and (iii) the development of compounds that abrogate the inflammation-mediated increase of receptor expression in the neuronal surface. These new sites of action represent novel strategies to modulate pathologically active TRPV1, while minimizing an effect on the TRPV1 subpopulation involved in physiological and protective roles, thus increasing their potential therapeutic use. PMID:24288041

Active plasmonics in WDM traffic switching applications

NASA Astrophysics Data System (ADS)

Papaioannou, Sotirios; Kalavrouziotis, Dimitrios; Vyrsokinos, Konstantinos; Weeber, Jean-Claude; Hassan, Karim; Markey, Laurent; Dereux, Alain; Kumar, Ashwani; Bozhevolnyi, Sergey I.; Baus, Matthias; Tekin, Tolga; Apostolopoulos, Dimitrios; Avramopoulos, Hercules; Pleros, Nikos

2012-09-01

With metal stripes being intrinsic components of plasmonic waveguides, plasmonics provides a ``naturally'' energy-efficient platform for merging broadband optical links with intelligent electronic processing, instigating a great promise for low-power and small-footprint active functional circuitry. The first active Dielectric-Loaded Surface Plasmon Polariton (DLSPP) thermo-optic (TO) switches with successful performance in single-channel 10 Gb/s data traffic environments have led the inroad towards bringing low-power active plasmonics in practical traffic applications. In this article, we introduce active plasmonics into Wavelength Division Multiplexed (WDM) switching applications, using the smallest TO DLSPP-based Mach-Zehnder interferometric switch reported so far and showing its successful performance in 4×10 Gb/s low-power and fast switching operation. The demonstration of the WDM-enabling characteristics of active plasmonic circuits with an ultra-low power × response time product represents a crucial milestone in the development of active plasmonics towards real telecom and datacom applications, where low-energy and fast TO operation with small-size circuitry is targeted.

Exploring the engineering limit of heat flux of a W/RAFM divertor target for fusion reactors

NASA Astrophysics Data System (ADS)

Mao, X.; Fursdon, M.; Chang, X. B.; Zhang, J. W.; Liu, P.; Ellwood, G.; Qian, X. Y.; Qin, S. J.; Peng, X. B.; Barrett, T. R.; Liu, P.

2018-06-01

The design and development of a fusion reactor divertor plasma facing component (PFC) is one of the many challenging issues on the road to commercial use of fusion energy. The divertor PFC is expected to exhaust steady state heat loads in the region of 10 MW m‑2 while keeping temperatures and thermo-mechanical stresses in its structure within the allowable limits. For ITER (International Thermo-Nuclear Experimental Reactor) a water cooled W/CuCrZr divertor PFC concept has been developed. However, this concept is not necessarily assured for use in future fusion reactors mainly because the neutron radiation dose would be at least an order magnitude higher, resulting in limited thermo-mechanical performance and considerably more activated waste products. In the present study, a water cooled divertor PFC using reduced activation ferritic-martensitic (RAFM) steel as the heat sink pipe has been designed with pressurised water reactor-like cooling conditions (pressure of 15.5 MPa, velocity of 10–20 m s‑1 and temperature of 300 °C). The PFC is made up of a number of rectangular tungsten tiles, each with an inner circular hole (so-called monoblocks), joined onto a RAFM steel pipe with copper interlayers. The thermo-mechanical performance of the PFC has been studied in detail. The heat transfer coefficient between the RAFM pipe inner surface and the water was calculated using published correlations. Geometric parameters and water velocity were optimized with finite element (FE) thermal analysis, to achieve acceptable temperatures in the structure given the target exhaust heat load of 10 MW m‑2. Under this heat load and the optimised thermal design parameters, the structure of the PFC was further assessed by mechanical analysis. We find that under these conditions the RAFM steel pipe experiences cyclic plasticity, and fails the common linear elastic ratchetting (3 Sm) rule. Nevertheless, the designed W/RAFM divertor PFU can withstand 10 MW m‑2 heat load, albeit with a fatigue life of approximately 0.55 years based on the expected operation scenario of a prototype or test reactor. This study extends the state of knowledge of the technological limit of a divertor based on a RAFM steel pipe structure.

ASTM and VAMAS activities in titanium matrix composites test methods development

NASA Technical Reports Server (NTRS)

Johnson, W. S.; Harmon, D. M.; Bartolotta, P. A.; Russ, S. M.

1994-01-01

Titanium matrix composites (TMC's) are being considered for a number of aerospace applications ranging from high performance engine components to airframe structures in areas that require high stiffness to weight ratios at temperatures up to 400 C. TMC's exhibit unique mechanical behavior due to fiber-matrix interface failures, matrix cracks bridged by fibers, thermo-viscoplastic behavior of the matrix at elevated temperatures, and the development of significant thermal residual stresses in the composite due to fabrication. Standard testing methodology must be developed to reflect the uniqueness of this type of material systems. The purpose of this paper is to review the current activities in ASTM and Versailles Project on Advanced Materials and Standards (VAMAS) that are directed toward the development of standard test methodology for titanium matrix composites.

Aerosol in the Pacific troposphere

NASA Technical Reports Server (NTRS)

Clarke, Antony D.

1989-01-01

The use of near real-time optical techniques is emphasized for the measurement of mid-tropospheric aerosol over the Central Pacific. The primary focus is on measurement of the aerosol size distribution over the range of particle diameters from 0.15 to 5.0 microns that are essential for modeling CO2 backscatter values in support of the laser atmospheric wind sounder (LAWS) program. The measurement system employs a LAS-X (Laser Aerosol Spectrometer-PMS, Boulder, CO) with a custom 256 channel pulse height analyzer and software for detailed measurement and analysis of aerosol size distributions. A thermal preheater system (Thermo Optic Aerosol Descriminator (TOAD) conditions the aerosol in a manner that allows the discrimination of the size distribution of individual aerosol components such as sulfuric acid, sulfates and refractory species. This allows assessment of the relative contribution of each component to the BCO2 signal. This is necessary since the different components have different sources, exhibit independent variability and provide different BCO2 signals for a given mass and particle size. Field activities involve experiments designed to examine both temporal and spatial variability of these aerosol components from ground based and aircraft platforms.

Development of antimicrobial active packaging materials based on gluten proteins.

PubMed

Gómez-Heincke, Diana; Martínez, Inmaculada; Partal, Pedro; Guerrero, Antonio; Gallegos, Críspulo

2016-08-01

The incorporation of natural biocide agents into protein-based bioplastics, a source of biodegradable polymeric materials, manufactured by a thermo-mechanical method is a way to contribute to a sustainable food packaging industry. This study assesses the antimicrobial activity of 10 different biocides incorporated into wheat gluten-based bioplastics. The effect that formulation, processing, and further thermal treatments exert on the thermo-mechanical properties, water absorption characteristics and rheological behaviour of these materials is also studied. Bioplastics containing six of the 10 examined bioactive agents have demonstrated suitable antimicrobial activity at 37 °C after their incorporation into the bioplastic. Moreover, the essential oils are able to create an antimicrobial atmosphere within a Petri dish. Depending on the selected biocide, its addition may alter the bioplastics protein network in a different extent, which leads to materials exhibiting less water uptake and different rheological and thermo-mechanical behaviours. © 2015 Society of Chemical Industry. © 2015 Society of Chemical Industry.

Reduced energy consumption by massive thermoelectric waste heat recovery in light duty trucks

NASA Astrophysics Data System (ADS)

Magnetto, D.; Vidiella, G.

2012-06-01

The main objective of the EC funded HEATRECAR project is to reduce the energy consumption and curb CO2 emissions of vehicles by massively harvesting electrical energy from the exhaust system and re-use this energy to supply electrical components within the vehicle or to feed the power train of hybrid electrical vehicles. HEATRECAR is targeting light duty trucks and focuses on the development and the optimization of a Thermo Electric Generator (TEG) including heat exchanger, thermoelectric modules and DC/DC converter. The main objective of the project is to design, optimize and produce a prototype system to be tested on a 2.3l diesel truck. The base case is a Thermo Electric Generator (TEG) producing 1 KWel at 130 km/h. We present the system design and estimated output power from benchmark Bi2Te3 modules. We discuss key drivers for the optimization of the thermal-to-electric efficiency, such as materials, thermo-mechanical aspects and integration.

Coupled Thermo-Electro-Magneto-Elastic Response of Smart Stiffened Panels

NASA Technical Reports Server (NTRS)

Bednarcyk, Brett A.; Yarrington, Phillip W.

2009-01-01

This report documents the procedures developed for incorporating smart laminate and panel analysis capabilities within the HyperSizer aerospace structural sizing software package. HyperSizer analyzes stiffened panels composed of arbitrary composite laminates through stiffener homogenization, or "smearing " techniques. The result is an effective constitutive equation for the stiffened panel that is suitable for use in a full vehicle-scale finite element analysis via MSC/NASTRAN. The existing thermo-elastic capabilities of HyperSizer have herein been extended to include coupled thermo-electro-magneto-elastic analysis capabilities. This represents a significant step toward realization of design tools capable of guiding the development of the next generation of smart aerospace structures. Verification results are presented that compare the developed smart HyperSizer capability with an ABAQUS piezoelectric finite element solution for a facesheet-flange combination. These results show good agreement between HyperSizer and ABAQUS, but highlight a limitation of the HyperSizer formulation in that constant electric field components are assumed.

Computational thermo-fluid dynamics contributions to advanced gas turbine engine design

NASA Technical Reports Server (NTRS)

Graham, R. W.; Adamczyk, J. J.; Rohlik, H. E.

1984-01-01

The design practices for the gas turbine are traced throughout history with particular emphasis on the calculational or analytical methods. Three principal components of the gas turbine engine will be considered: namely, the compressor, the combustor and the turbine.

ThermoTRPs and Pain

PubMed Central

Laing, Robyn J; Dhaka, Ajay

2015-01-01

The ability of the body to perceive noxious stimuli lies in a heterogeneous group of primary somatosensory neurons termed nociceptors. The molecular receptors of noxious mechanical, temperature or chemical stimuli are expressed in these neurons and have drawn considerable attention as possible targets for analgesic development to improve treatment for the millions who suffer from chronic pain conditions. A number of thermoTRPs, a subset of the transient receptor potential family of ion channels, are activated by a wide range on noxious stimuli. In this review, we review the function of these channels and examine the evidence that thermoTRPs play a vital role in acute, inflammatory and neuropathic nociception. PMID:25608689

Effect of microstructure on the thermo-oxidation of solid isotactic polypropylene-based polyolefins

PubMed Central

Hoyos, Mario; Tiemblo, Pilar; Gómez-Elvira, José Manuel

2008-01-01

In the present work we aim to clarify the role of the microstructure and the crystalline distribution from the thermo-oxidation of solid isotactic PP (iPP) and ethylene-propylene (EP) copolymers. The effects of the content and quality of the isotacticity interruptions, together with the associated average isotactic length, on the induction time (ti) as well as on the activation energy (Eact) of the thermo-oxidation are analysed. Both parameters have been found to change markedly at an average isotactic length (n1) of 30 propylene units. While ti reaches a minimum when n1 is approximately 30 units, Eact increases quasi-exponentially as the number of units decreases from 30. This variation can be explained in terms of changes induced in the crystalline interphase, i.e. local molecular dynamics, which are closely linked to the initiation of the thermo-oxidation of isotactic PP-based polyolefins. PMID:27877971

On nonlinear thermo-electro-elasticity.

PubMed

Mehnert, Markus; Hossain, Mokarram; Steinmann, Paul

2016-06-01

Electro-active polymers (EAPs) for large actuations are nowadays well-known and promising candidates for producing sensors, actuators and generators. In general, polymeric materials are sensitive to differential temperature histories. During experimental characterizations of EAPs under electro-mechanically coupled loads, it is difficult to maintain constant temperature not only because of an external differential temperature history but also because of the changes in internal temperature caused by the application of high electric loads. In this contribution, a thermo-electro-mechanically coupled constitutive framework is proposed based on the total energy approach. Departing from relevant laws of thermodynamics, thermodynamically consistent constitutive equations are formulated. To demonstrate the performance of the proposed thermo-electro-mechanically coupled framework, a frequently used non-homogeneous boundary-value problem, i.e. the extension and inflation of a cylindrical tube, is solved analytically. The results illustrate the influence of various thermo-electro-mechanical couplings.

On nonlinear thermo-electro-elasticity

PubMed Central

Mehnert, Markus; Hossain, Mokarram

2016-01-01

Electro-active polymers (EAPs) for large actuations are nowadays well-known and promising candidates for producing sensors, actuators and generators. In general, polymeric materials are sensitive to differential temperature histories. During experimental characterizations of EAPs under electro-mechanically coupled loads, it is difficult to maintain constant temperature not only because of an external differential temperature history but also because of the changes in internal temperature caused by the application of high electric loads. In this contribution, a thermo-electro-mechanically coupled constitutive framework is proposed based on the total energy approach. Departing from relevant laws of thermodynamics, thermodynamically consistent constitutive equations are formulated. To demonstrate the performance of the proposed thermo-electro-mechanically coupled framework, a frequently used non-homogeneous boundary-value problem, i.e. the extension and inflation of a cylindrical tube, is solved analytically. The results illustrate the influence of various thermo-electro-mechanical couplings. PMID:27436985

Thermo-optically tunable thin film devices

NASA Astrophysics Data System (ADS)

Domash, Lawrence H.

2003-10-01

We report advances in tunable thin film technology and demonstration of multi-cavity tunable filters. Thin film interference coatings are the most widely used optical technology for telecom filtering, but until recently no tunable versions have been known except for mechanically rotated filters. We describe a new approach to broadly tunable components based on the properties of semiconductor thin films with large thermo-optic coefficients. The technology is based on amorphous silicon deposited by plasma-enhanced chemical vapor deposition (PECVD), a process adapted for telecom applications from its origins in the flat-panel display and solar cell industries. Unlike MEMS devices, tunable thin films can be constructed in sophisticated multi-cavity, multi-layer optical designs.

Cyclic oxidation behavior of plasma sprayed NiCrAlY/WC-Co/cenosphere coating

NASA Astrophysics Data System (ADS)

Mathapati, Mahantayya; Ramesh M., R.; Doddamani, Mrityunjay

2018-04-01

Components working at elevated temperature like boiler tubes of coal and gas fired power generation plants, blades of gas and steam turbines etc. experience degradation owing to oxidation. Oxidation resistance of such components can be increased by developing protective coatings. In the present investigation NiCrAlY-WC-Co/Cenosphere coating is deposited on MDN 321 steel substrate using plasma spray coating. Thermo cyclic oxidation behavior of coating and substrate is studied in static air at 600 °C for 20 cycles. The thermo gravimetric technique is used to approximate the kinetics of oxidation. X-Ray Diffraction (XRD), Scanning Electron Microscope (SEM), Energy Dispersive Spectroscopy (EDS) and X-ray mapping techniques are used to characterize the oxidized samples. NiCrAlY-WC-Co/Cenosphere coating exhibited lower oxidation rate in comparison to MDN 321 steel substrate. The lower oxidation rate of coating is attributed to formation of Al2O3, Cr2O3, NiO and CoWO4 oxides on the outermost surface.

Thermo-Chemical Conversion of Microwave Activated Biomass Mixtures

NASA Astrophysics Data System (ADS)

Barmina, I.; Kolmickovs, A.; Valdmanis, R.; Vostrikovs, S.; Zake, M.

2018-05-01

Thermo-chemical conversion of microwave activated wheat straw mixtures with wood or peat pellets is studied experimentally with the aim to provide more effective application of wheat straw for heat energy production. Microwave pre-processing of straw pellets is used to provide a partial decomposition of the main constituents of straw and to activate the thermo-chemical conversion of wheat straw mixtures with wood or peat pellets. The experimental study includes complex measurements of the elemental composition of biomass pellets (wheat straw, wood, peat), DTG analysis of their thermal degradation, FTIR analysis of the composition of combustible volatiles entering the combustor, the flame temperature, the heat output of the device and composition of the products by comparing these characteristics for mixtures with unprocessed and mw pre-treated straw pellets. The results of experimental study confirm that mw pre-processing of straw activates the thermal decomposition of mixtures providing enhanced formation of combustible volatiles. This leads to improvement of the combustion conditions in the flame reaction zone, completing thus the combustion of volatiles, increasing the flame temperature, the heat output from the device, the produced heat energy per mass of burned mixture and decreasing at the same time the mass fraction of unburned volatiles in the products.

TRPV2 enhances axon outgrowth through its activation by membrane stretch in developing sensory and motor neurons.

PubMed

Shibasaki, Koji; Murayama, Namie; Ono, Katsuhiko; Ishizaki, Yasuki; Tominaga, Makoto

2010-03-31

Thermosensitive TRP (thermo TRP) channels are well recognized for their contributions to sensory transduction, responding to a wide variety of stimuli including temperature, nociceptive stimuli, touch, and osmolarity. However, the precise roles for the thermo TRP channels during development have not been determined. To explore the functional importance of thermo TRP channels during neural development, the temporal expression was determined in embryonic mice. Interestingly, TRPV2 expression was detected in spinal motor neurons in addition to the dorsal root ganglia from embryonic day 10.5 and was localized in axon shafts and growth cones, suggesting that the channel is important for axon outgrowth regulation. We revealed that endogenous TRPV2 was activated in a membrane stretch-dependent manner in developing neurons by knocking down the TRPV2 function with dominant-negative TRPV2 and TRPV2-specific shRNA and significantly promoted axon outgrowth. Thus, for the first time we revealed that TRPV2 is an important regulator for axon outgrowth through its activation by membrane stretch during development.

Effect of Multipass TIG and Activated TIG Welding Process on the Thermo-Mechanical Behavior of 316LN Stainless Steel Weld Joints

NASA Astrophysics Data System (ADS)

Ganesh, K. C.; Balasubramanian, K. R.; Vasudevan, M.; Vasantharaja, P.; Chandrasekhar, N.

2016-04-01

The primary objective of this work was to develop a finite element model to predict the thermo-mechanical behavior of an activated tungsten inert gas (ATIG)-welded joint. The ATIG-welded joint was fabricated using 10 mm thickness of 316LN stainless steel plates in a single pass. To distinguish the merits of ATIG welding process, it was compared with manual multipass tungsten inert gas (MPTIG)-welded joint. The ATIG-welded joint was fabricated with square butt edge configuration using an activating flux developed in-house. The MPTIG-welded joint was fabricated in thirteen passes with V-groove edge configuration. The finite element model was developed to predict the transient temperature, residual stress, and distortion of the welded joints. Also, microhardness, impact toughness, tensile strength, ferrite measurement, and microstructure were characterized. Since most of the recent publications of ATIG-welded joint was focused on the molten weld pool dynamics, this research work gives an insight on the thermo-mechanical behavior of ATIG-welded joint over MPTIG-welded joint.

Protease inhibitor in scorpion (Mesobuthus eupeus) venom prolongs the biological activities of the crude venom.

PubMed

Ma, Hakim; Xiao-Peng, Tang; Yang, Shi-Long; Lu, Qiu-Min; Lai, Ren

2016-08-01

It is hypothesized that protease inhibitors play an essential role in survival of venomous animals through protecting peptide/protein toxins from degradation by proteases in their prey or predators. However, the biological function of protease inhibitors in scorpion venoms remains unknown. In the present study, a trypsin inhibitor was purified and characterized from the venom of scorpion Mesobuthus eupeus, which enhanced the biological activities of crude venom components in mice when injected in combination with crude venom. This protease inhibitor, named MeKTT-1, belonged to Kunitz-type toxins subfamily. Native MeKTT-1 selectively inhibited trypsin with a Kivalue of 130 nmol·L(-1). Furthermore, MeKTT-1 was shown to be a thermo-stable peptide. In animal behavioral tests, MeKTT-1 prolonged the pain behavior induced by scorpion crude venom, suggesting that protease inhibitors in scorpion venom inhibited proteases and protect the functionally important peptide/protein toxins from degradation, consequently keeping them active longer. In conclusion, this was the first experimental evidence about the natural existence of serine protease inhibitor in the venom of scorpion Mesobuthus eupeus, which preserved the activity of venom components, suggests that scorpions may use protease inhibitors for survival. Copyright © 2016 China Pharmaceutical University. Published by Elsevier B.V. All rights reserved.

Non-Self-Maintained Discharge Application for Fuel Activation

DTIC Science & Technology

2010-09-21

provision of law, no person shall be subject to any penalty for failing to comply with a collection of information if it does not display a currently ...voltage accelerating tube (1); - An injector of electrons with the thermo emission heated cathode (2); - The high-voltage rectifier (3); - A...auxiliary systems of the accelerator. The electron injector (2) is supplied by the thermo - emission cathode, allowing to generate an electron

Solar-mediated thermo-electrochemical oxidation of sodium dodecyl benzene sulfonate by modulating the effective oxidation potential and pathway for green remediation of wastewater.

PubMed

Gu, Di; Gao, Simeng; Jiang, TingTing; Wang, Baohui

2017-03-15

To match the relentless pursuit of three research hot points - efficient solar utilization, green and sustainable remediation of wastewater and advanced oxidation processes, solar-mediated thermo-electrochemical oxidation of surfactant was proposed and developed for green remediation of surfactant wastewater. The solar thermal electrochemical process (STEP), fully driven with solar energy to electric energy and heat and without an input of other energy, sustainably serves as efficient thermo-electrochemical oxidation of surfactant, exemplified by SDBS, in wastewater with the synergistic production of hydrogen. The electrooxidation-resistant surfactant is thermo-electrochemically oxidized to CO 2 while hydrogen gas is generated by lowing effective oxidation potential and suppressing the oxidation activation energy originated from the combination of thermochemical and electrochemical effect. A clear conclusion on the mechanism of SDBS degradation can be proposed and discussed based on the theoretical analysis of electrochemical potential by quantum chemical method and experimental analysis of the CV, TG, GC, FT-IR, UV-vis, Fluorescence spectra and TOC. The degradation data provide a pilot for the treatment of SDBS wastewater that appears to occur via desulfonation followed by aromatic-ring opening. The solar thermal utilization that can initiate the desulfonation and activation of SDBS becomes one key step in the degradation process.

Solar-mediated thermo-electrochemical oxidation of sodium dodecyl benzene sulfonate by modulating the effective oxidation potential and pathway for green remediation of wastewater

PubMed Central

Gu, Di; Gao, Simeng; Jiang, TingTing; Wang, Baohui

2017-01-01

To match the relentless pursuit of three research hot points - efficient solar utilization, green and sustainable remediation of wastewater and advanced oxidation processes, solar-mediated thermo-electrochemical oxidation of surfactant was proposed and developed for green remediation of surfactant wastewater. The solar thermal electrochemical process (STEP), fully driven with solar energy to electric energy and heat and without an input of other energy, sustainably serves as efficient thermo-electrochemical oxidation of surfactant, exemplified by SDBS, in wastewater with the synergistic production of hydrogen. The electrooxidation-resistant surfactant is thermo-electrochemically oxidized to CO2 while hydrogen gas is generated by lowing effective oxidation potential and suppressing the oxidation activation energy originated from the combination of thermochemical and electrochemical effect. A clear conclusion on the mechanism of SDBS degradation can be proposed and discussed based on the theoretical analysis of electrochemical potential by quantum chemical method and experimental analysis of the CV, TG, GC, FT-IR, UV-vis, Fluorescence spectra and TOC. The degradation data provide a pilot for the treatment of SDBS wastewater that appears to occur via desulfonation followed by aromatic-ring opening. The solar thermal utilization that can initiate the desulfonation and activation of SDBS becomes one key step in the degradation process. PMID:28294180

Solar-mediated thermo-electrochemical oxidation of sodium dodecyl benzene sulfonate by modulating the effective oxidation potential and pathway for green remediation of wastewater

NASA Astrophysics Data System (ADS)

Gu, Di; Gao, Simeng; Jiang, Tingting; Wang, Baohui

2017-03-01

To match the relentless pursuit of three research hot points - efficient solar utilization, green and sustainable remediation of wastewater and advanced oxidation processes, solar-mediated thermo-electrochemical oxidation of surfactant was proposed and developed for green remediation of surfactant wastewater. The solar thermal electrochemical process (STEP), fully driven with solar energy to electric energy and heat and without an input of other energy, sustainably serves as efficient thermo-electrochemical oxidation of surfactant, exemplified by SDBS, in wastewater with the synergistic production of hydrogen. The electrooxidation-resistant surfactant is thermo-electrochemically oxidized to CO2 while hydrogen gas is generated by lowing effective oxidation potential and suppressing the oxidation activation energy originated from the combination of thermochemical and electrochemical effect. A clear conclusion on the mechanism of SDBS degradation can be proposed and discussed based on the theoretical analysis of electrochemical potential by quantum chemical method and experimental analysis of the CV, TG, GC, FT-IR, UV-vis, Fluorescence spectra and TOC. The degradation data provide a pilot for the treatment of SDBS wastewater that appears to occur via desulfonation followed by aromatic-ring opening. The solar thermal utilization that can initiate the desulfonation and activation of SDBS becomes one key step in the degradation process.

Reversible Self-Actuated Thermo-Responsive Pore Membrane

PubMed Central

Park, Younggeun; Gutierrez, Maria Paz; Lee, Luke P.

2016-01-01

Smart membranes, which can selectively control the transfer of light, air, humidity and temperature, are important to achieve indoor climate regulation. Even though reversible self-actuation of smart membranes is desirable in large-scale, reversible self-regulation remains challenging. Specifically, reversible 100% opening/closing of pore actuation showing accurate responsiveness, reproducibility and structural flexibility, including uniform structure assembly, is currently very difficult. Here, we report a reversible, thermo-responsive self-activated pore membrane that achieves opening and closing of pores. The reversible, self-actuated thermo-responsive pore membrane was fabricated with hybrid materials of poly (N-isopropylacrylamide), (PNIPAM) within polytetrafluoroethylene (PTFE) to form a multi-dimensional pore array. Using Multiphysics simulation of heat transfer and structural mechanics based on finite element analysis, we demonstrated that pore opening and closing dynamics can be self-activated at environmentally relevant temperatures. Temperature cycle characterizations of the pore structure revealed 100% opening ratio at T = 40 °C and 0% opening ratio at T = 20 °C. The flexibility of the membrane showed an accurate temperature-responsive function at a maximum bending angle of 45°. Addressing the importance of self-regulation, this reversible self-actuated thermo-responsive pore membrane will advance the development of future large-scale smart membranes needed for sustainable indoor climate control. PMID:27991563

Reversible Self-Actuated Thermo-Responsive Pore Membrane

NASA Astrophysics Data System (ADS)

Park, Younggeun; Gutierrez, Maria Paz; Lee, Luke P.

2016-12-01

Smart membranes, which can selectively control the transfer of light, air, humidity and temperature, are important to achieve indoor climate regulation. Even though reversible self-actuation of smart membranes is desirable in large-scale, reversible self-regulation remains challenging. Specifically, reversible 100% opening/closing of pore actuation showing accurate responsiveness, reproducibility and structural flexibility, including uniform structure assembly, is currently very difficult. Here, we report a reversible, thermo-responsive self-activated pore membrane that achieves opening and closing of pores. The reversible, self-actuated thermo-responsive pore membrane was fabricated with hybrid materials of poly (N-isopropylacrylamide), (PNIPAM) within polytetrafluoroethylene (PTFE) to form a multi-dimensional pore array. Using Multiphysics simulation of heat transfer and structural mechanics based on finite element analysis, we demonstrated that pore opening and closing dynamics can be self-activated at environmentally relevant temperatures. Temperature cycle characterizations of the pore structure revealed 100% opening ratio at T = 40 °C and 0% opening ratio at T = 20 °C. The flexibility of the membrane showed an accurate temperature-responsive function at a maximum bending angle of 45°. Addressing the importance of self-regulation, this reversible self-actuated thermo-responsive pore membrane will advance the development of future large-scale smart membranes needed for sustainable indoor climate control.

Thermodynamic stability of carbonic anhydrase: measurements of binding affinity and stoichiometry using ThermoFluor.

PubMed

Matulis, Daumantas; Kranz, James K; Salemme, F Raymond; Todd, Matthew J

2005-04-05

ThermoFluor (a miniaturized high-throughput protein stability assay) was used to analyze the linkage between protein thermal stability and ligand binding. Equilibrium binding ligands increase protein thermal stability by an amount proportional to the concentration and affinity of the ligand. Binding constants (K(b)) were measured by examining the systematic effect of ligand concentration on protein stability. The precise ligand effects depend on the thermodynamics of protein stability: in particular, the unfolding enthalpy. An extension of current theoretical treatments was developed for tight binding inhibitors, where ligand effect on T(m) can also reveal binding stoichiometry. A thermodynamic analysis of carbonic anhydrase by differential scanning calorimetry (DSC) enabled a dissection of the Gibbs free energy of stability into enthalpic and entropic components. Under certain conditions, thermal stability increased by over 30 degrees C; the heat capacity of protein unfolding was estimated from the dependence of calorimetric enthalpy on T(m). The binding affinity of six sulfonamide inhibitors to two isozymes (human type 1 and bovine type 2) was analyzed by both ThermoFluor and isothermal titration calorimetry (ITC), resulting in a good correlation in the rank ordering of ligand affinity. This combined investigation by ThermoFluor, ITC, and DSC provides a detailed picture of the linkage between ligand binding and protein stability. The systematic effect of ligands on stability is shown to be a general tool to measure affinity.

Role of segregation and precipitates on interfacial strengthening mechanisms in metal matrix composites when subjected to thermo-mechanical processing

NASA Astrophysics Data System (ADS)

Myriounis, Dimitrios

Metal Matrix ceramic-reinforced composites are rapidly becoming strong candidates as structural materials for many high temperatures and aerospace applications. Metal matrix composites combine the ductile properties of the matrix with a brittle phase of the reinforcement, leading to high stiffness and strength with a reduction in structural weight. The main objective of using a metal matrix composite system is to increase service temperature or improve specific mechanical properties of structural components by replacing existing superalloys.The satisfactory performance of metal matrix composites depends critically on their integrity, the heart of which is the quality of the matrix-reinforcement interface. The nature of the interface depends on the processing of the metal matrix composite component. At the micro-level the development of local stress concentration gradients around the ceramic reinforcement, as the metal matrix attempts to deform during processing, can be very different to the nominal conditions and play a crucial role in important microstructural events such as segregation and precipitation at the matrix-reinforcement interface. These events dominate the cohesive strength and subsequent mechanical properties of the interface.At present the relationship between the strength properties of metal matrix composites and the details of the thermo-mechanical forming processes is not well understood.The purpose of the study is to investigate several strengthening mechanisms and the effect of thermo-mechanical processing of SiCp reinforced A359 aluminium alloy composites on the particle-matrix interface and the overall mechanical properties of the material. From experiments performed on composite materials subjected to various thermo-mechanical conditions and by observation using SEM microanalysis and mechanical testing, data were obtained, summarised and mathematically/statistically analysed upon their significance.The Al/SiCp composites studied, processed in specific thermo-mechanical conditions in order to attain higher values of interfacial fracture strength, due to precipitation hardening and segregation mechanisms, also exhibited enhanced bulk mechanical and fracture resistant properties.An analytical model to predict the interfacial fracture strength in the presence of material segregation was also developed during this research effort. Its validity was determined based on the data gathered from the experiments.The tailoring of the properties due to the microstructural modification of the composites was examined in relation to the experimental measurements obtained, which define the macroscopical behaviour of the material.

Athermal laser design.

PubMed

Bovington, Jock; Srinivasan, Sudharsanan; Bowers, John E

2014-08-11

This paper discusses circuit based and waveguide based athermalization schemes and provides some design examples of athermalized lasers utilizing fully integrated athermal components as an alternative to power hungry thermo-electric controllers (TECs), off-chip wavelength lockers or monitors with lookup tables for tunable lasers. This class of solutions is important for uncooled transmitters on silicon.

Comprehensive nonlocal analysis of piezoelectric nanobeams with surface effects in bending, buckling and vibrations under magneto-electro-thermo-mechanical loading

NASA Astrophysics Data System (ADS)

Ebrahimi-Nejad, Salman; Boreiry, Mahya

2018-03-01

The bending, buckling and vibrational behavior of size-dependent piezoelectric nanobeams under thermo-magneto-mechano-electrical environment are investigated by performing a parametric study, in the presence of surface effects. The Gurtin-Murdoch surface elasticity and Eringen’s nonlocal elasticity theories are applied in the framework of Euler–Bernoulli beam theory to obtain a new non-classical size-dependent beam model for dynamic and static analyses of piezoelectric nanobeams. In order to satisfy the surface equilibrium equations, cubic variation of stress with beam thickness is assumed for the bulk stress component which is neglected in classical beam models. Results are obtained for clamped - simply-supported (C-S) and simply-supported - simply-supported (S-S) boundary conditions using a proposed analytical solution method. Numerical examples are presented to demonstrate the effects of length, surface effects, nonlocal parameter and environmental changes (temperature, magnetic field and external voltage) on deflection, critical buckling load and natural frequency for each boundary condition. Results of this study can serve as benchmarks for the design and analysis of nanostructures of magneto-electro-thermo-elastic materials.

On the effects of thermal history on the development and relaxation of thermo-mechanical stress in cryopreservation

NASA Astrophysics Data System (ADS)

Eisenberg, David P.; Steif, Paul S.; Rabin, Yoed

2014-11-01

This study investigates the effects of the thermal protocol on the development and relaxation of thermo-mechanical stress in cryopreservation by means of glass formation, also known as vitrification. The cryopreserved medium is modeled as a homogeneous viscoelastic domain, constrained within either a stiff cylindrical container or a highly compliant bag. Annealing effects during the cooling phase of the cryopreservation protocol are analyzed. Results demonstrate that an intermediate temperature-hold period can significantly reduce the maximum tensile stress, thereby decreasing the potential for structural damage. It is also demonstrated that annealing at temperatures close to glass transition significantly weakens the dependency of thermo-mechanical stress on the cooling rate. Furthermore, a slower initial rewarming rate after cryogenic storage may drastically reduce the maximum tensile stress in the material, which supports previous experimental observations on the likelihood of fracture at this stage. This study discusses the dependency of the various stress components on the storage temperature. Finally, it is demonstrated that the stiffness of the container wall can affect the location of maximum stress, with implications on the development of cryopreservation protocols.

Correlation between some thermo-mechanical and physico-chemical properties in multi-component glasses of Se-Te-Sn-Cd system

NASA Astrophysics Data System (ADS)

Kumar, Amit; Mehta, Neeraj

2017-06-01

The glass transition phenomenon is guided by the swift cooling of a melt (glass-forming liquid). Consequently, the glass as a final product consists of a considerable number of micro-voids having the size of the order of atomic and/or molecular sizes. The model of free volume fluctuation helps in describing the diverse physico-chemical properties of amorphous materials (like glasses and polymers). This theory is based on the fraction of fluctuation free frozen at the glass transition temperature and it forms a basis for determination of various significant thermo-mechanical properties. In the present work, Vickers hardness test method is employed that provides useful information concerning the mechanical behavior of brittle solids. The present work emphasizes the results of micro-indentation measurements on recently synthesized novel Se78- x Te20Sn2Cd x glassy system. Basic thermo-mechanical parameters such as micro-hardness, volume ( V h), formation energy ( E h) of micro-voids in the glassy network and modulus of elasticity ( E) have been determined and their variation with glass composition has been investigated.

Lifing of Engine Components

NASA Technical Reports Server (NTRS)

2005-01-01

The successful development of advanced aerospace engines depends greatly on the capabilities of high performance materials and structures. Advanced materials, such as nickel based single crystal alloys, metal foam, advanced copper alloys, and ceramics matrix composites, have been engineered to provide higher engine temperature and stress capabilities. Thermal barrier coatings have been developed to improve component durability and fuel efficiency, by reducing the substrate hot wall metal temperature and protecting against oxidation and blanching. However, these coatings are prone to oxidation and delamination failures. In order to implement the use of these materials in advanced engines, it is necessary to understand and model the evolution of damage of the metal substrate as well as the coating under actual engine conditions. The models and the understanding of material behavior are utilized in the development of a life prediction methodology for hot section components. The research activities were focused on determining the stress and strain fields in an engine environment under combined thermo-mechanical loads to develop life prediction methodologies consistent with the observed damage formation of the coating and the substrates.

Distribution and local hydrographic impact of rapid permafrost degradation by thermo-erosion and gullying of ice-wedge polygons in glacier valley C-79 on on Bylot Island , Nunavut, Canada

NASA Astrophysics Data System (ADS)

Godin, E.; Fortier, D.

2010-12-01

Glaciers flowing from local ice-cap in the Canadian High-Arctic often feed fluvio-glacial outwashes flowing toward the sea. These fluvio-glacial outwashes are often bordered by terraces in which ice-wedge polygons developed during the Holocene (Fortier et al. 2004). In the valley of glacier C-79 on Bylot Island, Nunavut (N 73° 09’ - W 79° 57’) these ice-wedge polygons were recently destabilized very rapidly by processes of thermo-erosion related to surface run-off. Thirty-five such gullies were identified, mapped by remote sensing, characterized and georeferenced in detail during field surveys in 2009-2010. The objectives of this paper are to: 1) quantify the area and shape of gully systems in the valley of glacier C-79 in relation with its depositional environment and 2) evaluate the impact of gully development on the local hydrography in the valley. Degradation of permafrost by thermo-erosion processes is very active in the valley C-79. It covered in 2010 an area of approximately 152000 m2, the average gully length was 542 m with a maximum of 3520 m. Thermo-erosion gullies induced by snowmelt runoff water were formed in 3 distinct depositional environments within the valley: 1) in aeolian, organic-poor deposits near the pro-glacial river outwash, 2) in organic-rich, humid, ice-wedges polygon terraces, and 3) in colluviums close to the valley walls. Thermo-erosion of ice wedge polygons resulted in typical landforms such as: sinkholes and tunnels, gully channels with alluvial levees, retrogressive thaw-slump, active layer detachment slide and baydjarakhs (Godin and Fortier, in press). Positive feedback effects, especially at the gully head and around sinkholes, sustain processes of thermo-erosion and enhance permafrost degradation. Thermo-erosion processes and associated heat transfers combined with the effects of gullying significantly affected ice-wedges polygons terraces. The formation of gullies created permanent changes in the landscape and in the hydrographic network such as the total or partial destruction of polygons, drainage of adjacent wetlands and the birth of new drainage systems (Fortier et al. 2007). The hydrographic network layout is affected by newly formed gullies, streams running on the terrace being diverted from their beds toward gully systems. A stabilized gully where thermo-erosion is no more active will continue to drain the terrace and thus these processes causes irreversible changes to the geomorphic configuration of ice wedge polygon terraces. Fortier, D., Allard, M., Shur, Y. 2007. Observation of Rapid Drainage System Development by Thermal Erosion of Ice Wedges on Bylot Island, Canadian Arctic Archipelago. Permafrost and Periglacial Processes, 18: 229-243. Fortier, D., Allard, M. 2004. Late Holocene Syngenetic Ice-wedge Polygons Development, Bylot Island, Canadian Arctic Archipelago. Canadian Journal of Earth Sciences, 41: 997-1012. Godin, E., Fortier, D. (in press) Geomorphology of thermo-erosion gullies - case study from Bylot Island, Nunavut, Canada. Proceedings 6th Canadian Permafrost Conference and 63rd Canadian Geotechnical Conference, Calgary, October 2010.

Thermo-Mechanical Analyses of Dynamically Loaded Rubber Cylinders

NASA Technical Reports Server (NTRS)

Johnson, Arthur R.; Chen, Tzi-Kang

2002-01-01

Thick rubber components are employed by the Army to carry large loads. In tanks, rubber covers road wheels and track systems to protect roadways. It is difficult for design engineers to simulate the details of the hysteretic heating for large strain viscoelastic deformations. In this study, an approximation to the viscoelastic energy dissipated per unit time is investigated for use in estimating mechanically induced viscoelastic heating. Coupled thermo-mechanical simulations of large cyclic deformations of rubber cylinders are presented. The cylinders are first compressed axially and then cyclically loaded about the compressed state. Details of the algorithm and some computational issues are discussed. The coupled analyses are conducted for tall and short rubber cylinders both with and without imbedded metal disks.

Distribution of apparent activation energy counterparts during thermo - And thermo-oxidative degradation of Aronia melanocarpa (black chokeberry).

PubMed

Janković, Bojan; Marinović-Cincović, Milena; Janković, Marija

2017-09-01

Kinetics of degradation for Aronia melanocarpa fresh fruits in argon and air atmospheres were investigated. The investigation was based on probability distributions of apparent activation energy of counterparts (ε a ). Isoconversional analysis results indicated that the degradation process in an inert atmosphere was governed by decomposition reactions of esterified compounds. Also, based on same kinetics approach, it was assumed that in an air atmosphere, the primary compound in degradation pathways could be anthocyanins, which undergo rapid chemical reactions. A new model of reactivity demonstrated that, under inert atmospheres, expectation values for ε a occured at levels of statistical probability. These values corresponded to decomposition processes in which polyphenolic compounds might be involved. ε a values obeyed laws of binomial distribution. It was established that, for thermo-oxidative degradation, Poisson distribution represented a very successful approximation for ε a values where there was additional mechanistic complexity and the binomial distribution was no longer valid. Copyright © 2017 Elsevier Ltd. All rights reserved.

Polymer materials and component evaluation in acidic-radiation environments

NASA Astrophysics Data System (ADS)

Celina, M.; Gillen, K. T.; Malone, G. M.; Clough, R. L.; Nelson, W. H.

2001-07-01

Polymeric materials used for cable/wire insulation, electrical connectors, O-rings, seals, and in critical components such as motors, level switches and resistive thermo-devices were evaluated under accelerated degradation conditions in combined radiation-oxidative elevated-temperature acidic-vapor (nitric/oxalic) environments relevant to conditions in isotope processing facilities. Experiments included the assessment of individual materials such as PEEK, polyimides, polyolefin based cable insulation, EPDM rubbers, various epoxy systems, commercial caulking materials as well as some functional testing of components. We discuss how to conduct laboratory experiments to simulate such complex hostile environments, describe some degradation effects encountered, and evaluate the impact on appropriate material and component selection.

Multi-sector thermo-physiological head simulator for headgear research

NASA Astrophysics Data System (ADS)

Martinez, Natividad; Psikuta, Agnes; Corberán, José Miguel; Rossi, René M.; Annaheim, Simon

2017-02-01

A novel thermo-physiological human head simulator for headgear testing was developed by coupling a thermal head manikin with a thermo-physiological model. As the heat flux at head-site is directly measured by the head manikin, this method provides a realistic quantification of the heat transfer phenomena occurring in the headgear, such as moisture absorption-desorption cycles, condensation, or moisture migration across clothing layers. Before coupling, the opportunities of the head manikin for representing the human physiology were evaluated separately. The evaluation revealed reduced precision in forehead and face temperature predictions under extreme heterogeneous temperature distributions and no initial limitation for simulating temperature changes observed in the human physiology. The thermo-physiological model predicted higher sweat rates when applied for coupled than for pure virtual simulations. After coupling, the thermo-physiological human head simulator was validated using eight human experiments. It precisely predicted core, mean skin, and forehead temperatures with average rmsd values within the average experimental standard deviation (rmsd of 0.20 ± 0.15, 0.83 ± 0.34, and 1.04 ± 0.54 °C, respectively). However, in case of forehead, precision was lower for the exposures including activity than for the sedentary exposures. The representation of the human sweat evaporation could be affected by a reduced evaporation efficiency and the manikin sweat dynamics. The industry will benefit from this thermo-physiological human head simulator leading to the development of helmet designs with enhanced thermal comfort and, therefore, with higher acceptance by users.

Texture evolution and their effects on the mechanical properties of duplex Mg-Li alloy

DOE Office of Scientific and Technical Information (OSTI.GOV)

Zou, Yun; Zhang, Lehao; Wang, Hongtao

Texture evolution is strongly dependent on the deformation mode during thermo-mechanical treatments. In this paper, we report the texture evolution in a duplex Mg-Li alloy. The results provide an evidence of deformation mode transition in the hexagonal-close-packed (hcp) alpha phase with various thickness reductions. The activation sequence of deformation modes is basal slip first, and then pyramidal slip during hot-rolling to a thickness reduction of 40%. The relative activity of slip decreases with further thickness reduction. After annealing, basal texture is strengthened and pyramidal component disappears due to static recrystallization and grain growth. The microstructure, specifically texture evolution in bothmore » hcp alpha and body-centered cubic (bcc) beta phase and their effects on mechanical properties are quantitatively analyzed and assessed. (C) 2016 Elsevier B.V. All rights reserved.« less

Texture evolution and their effects on the mechanical properties of duplex Mg-Li alloy

DOE PAGES

Zou, Yun; Zhang, Lehao; Wang, Hongtao; ...

2016-01-27

Texture evolution is strongly dependent on the deformation mode during thermo-mechanical treatments. In this paper, we report the texture evolution in a duplex Mg-Li alloy. The results provide an evidence of deformation mode transition in the hexagonal-close-packed (hcp) alpha phase with various thickness reductions. The activation sequence of deformation modes is basal slip first, and then pyramidal slip during hot-rolling to a thickness reduction of 40%. The relative activity of slip decreases with further thickness reduction. After annealing, basal texture is strengthened and pyramidal component disappears due to static recrystallization and grain growth. The microstructure, specifically texture evolution in bothmore » hcp alpha and body-centered cubic (bcc) beta phase and their effects on mechanical properties are quantitatively analyzed and assessed. (C) 2016 Elsevier B.V. All rights reserved.« less

UV-vis spectroscopic studies of CaF2 photo-thermo-refractive glass

NASA Astrophysics Data System (ADS)

Stoica, Martina; Herrmann, Andreas; Hein, Joachim; Rüssel, Christian

2016-12-01

A photo-thermo-refractive glass based on the system Na2O/K2O/CaO/CaF2/Al2O3/ZnO/SiO2 doped with Ag2O, CeO2, SnO2, Sb2O3 and KBr was investigated. This glass undergoes a permanent refractive index change after UV irradiation and subsequent two step heat treatment at temperatures above Tg. This is due to the formation of Ag metal clusters which act as nucleation centers for CaF2 crystallization. Oxidation of Ce3+ by UV light is the initial reaction and acts as photosensitizer in the glass. The UV-vis absorption spectra during this photo-induced crystallization process were measured. The spectral components that form the absorption spectra of cerium were studied in detail by a band separation with Gaussian functions. Deconvolution of the cerium absorption bands shows an envelope of five spectral components for the trivalent cerium due to the 4f-5d transitions and two spectral components for the tetravalent cerium caused by charge transfer transitions. The effect of different dopants and melting conditions on the photo-thermal process were studied to investigate the influence of glass technology on the photoprocess.

Functional characterization of steam jet-cooked buckwheat flour as a fat replacer in cake-baking

USDA-ARS?s Scientific Manuscript database

Fancy buckwheat flour was thermo-mechanically modified by steam jet-cooking and the resulting product was evaluated as a fat replacer for the use in cakes with reduced-fat content. Steam jet-cooking caused the integrity of buckwheat flour components to be disrupted, significantly changing the physi...

GRIZZLY

DOE Office of Scientific and Technical Information (OSTI.GOV)

2012-12-17

Grizzly is a simulation tool for assessing the effects of age-related degradation on systems, structures, and components of nuclear power plants. Grizzly is built on the MOOSE framework, and uses a Jacobian-free Newton Krylov method to obtain solutions to tightly coupled thermo-mechanical simulations. Grizzly runs on a wide range of hardware, from a single processor to massively parallel machines.

Feasibility study on measuring axial and transverse stress/strain components in composite materials using Bragg sensors

NASA Astrophysics Data System (ADS)

Luyckx, G.; Degrieck, J.; De Waele, W.; Van Paepegem, W.; Van Roosbroeck, J.; Chah, K.; Vlekken, J.; McKenzie, I.; Obst, A.

2017-11-01

A fibre optic sensor design is proposed for simultaneously measuring the 3D stress (or strain) components and temperature inside thermo hardened composite materials. The sensor is based on two fibre Bragg gratings written in polarisation maintaining fibre. Based on calculations of the condition number, it will be shown that reasonable accuracies are to be expected. First tests on the bare sensors and on the sensors embedded in composite material, which confirm the expected behaviour, will be presented.

Recent progress in InP/polymer-based devices for telecom and data center applications

NASA Astrophysics Data System (ADS)

Kleinert, Moritz; Zhang, Ziyang; de Felipe, David; Zawadzki, Crispin; Maese Novo, Alejandro; Brinker, Walter; Möhrle, Martin; Keil, Norbert

2015-02-01

Recent progress on polymer-based photonic devices and hybrid photonic integration technology using InP-based active components is presented. High performance thermo-optic components, including compact polymer variable optical attenuators and switches are powerful tools to regulate and control the light flow in the optical backbone. Polymer arrayed waveguide gratings integrated with InP laser and detector arrays function as low-cost optical line terminals (OLTs) in the WDM-PON network. External cavity tunable lasers combined with C/L band thinfilm filter, on-chip U-groove and 45° mirrors construct a compact, bi-directional and color-less optical network unit (ONU). A tunable laser integrated with VOAs, TFEs and two 90° hybrids builds the optical front-end of a colorless, dual-polarization coherent receiver. Multicore polymer waveguides and multi-step 45°mirrors are demonstrated as bridging devices between the spatialdivision- multiplexing transmission technology using multi-core fibers and the conventional PLCbased photonic platforms, appealing to the fast development of dense 3D photonic integration.

Double differential light charged particle emission cross sections for some structural fusion materials

NASA Astrophysics Data System (ADS)

Sarpün, Ismail Hakki; n, Abdullah Aydı; Tel, Eyyup

2017-09-01

In fusion reactors, neutron induced radioactivity strongly depends on the irradiated material. So, a proper selection of structural materials will have been limited the radioactive inventory in a fusion reactor. First-wall and blanket components have high radioactivity concentration due to being the most flux-exposed structures. The main objective of fusion structural material research is the development and selection of materials for reactor components with good thermo-mechanical and physical properties, coupled with low-activation characteristics. Double differential light charged particle emission cross section, which is a fundamental data to determine nuclear heating and material damages in structural fusion material research, for some elements target nuclei have been calculated by the TALYS 1.8 nuclear reaction code at 14-15 MeV neutron incident energy and compared with available experimental data in EXFOR library. Direct, compound and pre-equilibrium reaction contribution have been theoretically calculated and dominant contribution have been determined for each emission of proton, deuteron and alpha particle.

Cloning and characterization of a new cold-adapted and thermo-tolerant ι-carrageenase from marine bacterium Flavobacterium sp. YS-80-122.

PubMed

Li, Shangyong; Hao, Jianhua; Sun, Mi

2017-09-01

ι-Carrageenases play a role in marine ι-carrageenan degradation, and their enzymatic hydrolysates are thought to be excellent antioxidants. In this study, we identified a new ι-carrageenase, encoded by cgiF, in psychrophilic bacterium Flavobacterium sp. YS-80-122. The deduced ι-carrageenase, CgiF, belongs to glycoside hydrolase family 82 and shows less than 40% amino acid identity with characterized ι-carrageenases. The activity of recombinant CgiF peaked at 30°C (1,207.8U/mg). Notably, CgiF is a cold-adapted ι-carrageenase, which showed 36.5% and 57% of the maximum activity at 10°C and 15°C, respectively. In addition, it is a thermo-tolerant enzyme that recovered 58.2% of its initial activity after heat shock. Furthermore, although the activity of CgiF was enhanced by NaCl, the enzyme is active in absence of NaCl. This study also shows that CgiF is an endo-type ι-carrageenase that hydrolyzes β-1,4-linkages of ι-carrageenan, yielding neo-ι-carratetraose as the main product. Its cold-adaptation, thermo-tolerance, NaCl independence and high neo-ι-carratetraose yield make CgiF an excellent candidate for industrial applications in production of ι-carrageen oligosaccharides from seaweed polysaccharides. Copyright © 2017. Published by Elsevier B.V.

Essential oil composition, antioxidant and antifungal activities of Salvia sclarea L. from Munzur Valley in Tunceli, Turkey.

PubMed

Yuce, E; Yildirim, N; Yildirim, N C; Paksoy, M Y; Bagci, E

2014-06-15

The essential oil composition and in vitro antioxidant and antifungal activity of the Salvia sclarea L. from Munzur Valley in Tunceli, Turkey were evaluated in this research. The in vitro antifungal activity of ethanol, hexane and aqueous extracts of S. sclarea against pathogen fungi Epicoccum nigrum and Colletotrichum coccodes were investigated. The essential oil of aerial parts of S. sclarea was obtained by hydrodistillation and was analysed by GC and GC—MS. Total antioxidant status was determined by using Rel assay diagnostics TAS assay kit (Lot.RL024) by Multiscan FC (Thermo). 33 compounds were identified representing the 85.0% of the total oil. The most abundant components (>5%) of the S. sclarea essential oils were caryophyllene oxide (24.1%), sclareol (11.5%), spathulenol (11.4%), 1H-naphtho (2,1,6) pyran (8.6%) and b—caryophyllene (5.1%). The best antifungal and antioxidant effect was seen in ethanolic S. sclarea extract. It can be said that Salvia sclerae could be used as natural antioxidant.

Compact and Thermosensitive Nature-inspired Micropump

PubMed Central

Kim, Hyejeong; Kim, Kiwoong; Lee, Sang Joon

2016-01-01

Liquid transportation without employing a bulky power source, often observed in nature, has been an essential prerequisite for smart applications of microfluidic devices. In this report, a leaf-inspired micropump (LIM) which is composed of thermo-responsive stomata-inspired membrane (SIM) and mesophyll-inspired agarose cryogel (MAC) is proposed. The LIM provides a durable flow rate of 30 μl/h · cm2 for more than 30 h at room temperature without external mechanical power source. By adapting a thermo-responsive polymer, the LIM can smartly adjust the delivery rate of a therapeutic liquid in response to temperature changes. In addition, as the LIM is compact, portable, and easily integrated into any liquid, it might be utilized as an essential component in advanced hand-held drug delivery devices. PMID:27796357

Opportunities and challenges for 3D printing of solid-state lighting systems

NASA Astrophysics Data System (ADS)

Narendran, Nadarajah; Perera, Indika U.; Mou, Xi; Thotagamuwa, Dinusha R.

2017-09-01

Low energy use and reduced maintenance have made the LED, a solid-state light (SSL) source, the preferred technology for many lighting applications. With the explosion of products in the marketplace and subsequent price erosion, manufacturers are looking for lower cost materials and manufacturing methods. 3-D printing, also known as additive manufacturing, could be a potential solution. Recently, manufacturers in the automotive, aerospace, and medical industries have embraced 3-D printing for manufacturing parts and systems. This could pave the way for the lighting industry to produce lower cost, custom lighting systems that are 3-D printed on-site to achieve on-time and on-demand manufacturing. One unique aspect of LED fixture manufacturing is that it requires thermo-mechanical, electrical, and optical components. The goal of our investigation was to understand if current 3-D printing technologies and materials can be used to manufacture functional thermo-mechanical, electrical, and optical components for SSL fixtures. We printed heat sink components and electrical traces using an FFF-type 3-D printer with different filaments. The results showed that the printed heat sinks achieved higher thermal conductivity values compared to components made with plastic materials. For electrical traces, graphene-infused PLA showed low resistivity but it is much higher than bulk copper resistivity. For optics, SLA-printed optical components showed that print resolution, print orientation, and postprocessing affect light transmission and light scatter properties. Overall, 3-D printing offers an opportunity for mass customization of SSL fixtures and changing architectural lighting practice, but several challenges in terms of process and materials still have to be overcome.

Multi-sector thermo-physiological head simulator for headgear research.

PubMed

Martinez, Natividad; Psikuta, Agnes; Corberán, José Miguel; Rossi, René M; Annaheim, Simon

2017-02-01

A novel thermo-physiological human head simulator for headgear testing was developed by coupling a thermal head manikin with a thermo-physiological model. As the heat flux at head-site is directly measured by the head manikin, this method provides a realistic quantification of the heat transfer phenomena occurring in the headgear, such as moisture absorption-desorption cycles, condensation, or moisture migration across clothing layers. Before coupling, the opportunities of the head manikin for representing the human physiology were evaluated separately. The evaluation revealed reduced precision in forehead and face temperature predictions under extreme heterogeneous temperature distributions and no initial limitation for simulating temperature changes observed in the human physiology. The thermo-physiological model predicted higher sweat rates when applied for coupled than for pure virtual simulations. After coupling, the thermo-physiological human head simulator was validated using eight human experiments. It precisely predicted core, mean skin, and forehead temperatures with average rmsd values within the average experimental standard deviation (rmsd of 0.20 ± 0.15, 0.83 ± 0.34, and 1.04 ± 0.54 °C, respectively). However, in case of forehead, precision was lower for the exposures including activity than for the sedentary exposures. The representation of the human sweat evaporation could be affected by a reduced evaporation efficiency and the manikin sweat dynamics. The industry will benefit from this thermo-physiological human head simulator leading to the development of helmet designs with enhanced thermal comfort and, therefore, with higher acceptance by users.

Thermo-sensitive and swelling properties of cellouronic acid sodium/poly (acrylamide-co-diallyldimethylammonium chloride) semi-IPN.

PubMed

Zhang, Heng; Gao, Xin; Chen, Keli; Li, Hui; Peng, Lincai

2018-02-01

In current study, cellouronic acid sodium (CAS), obtained from bagasse pith, has been introduced into poly(acrylamide-co-diallyldimethylammonium chloride) (poly(AM-co-DAC)) network to form novel thermo-sensitive semi-IPNs. The structure and morphology of the hydrogels were proved by Fourier transformation infrared spectroscopy (FT-IR), X-ray photoelectron spectroscopy (XPS) and scanning electron microscopy (SEM). The effects of CAS content, initiator charge, cross-linker dosage and swelling-medium property on the thermo-responsive water absorptivity were investigated in detail. The results elucidated that the prepared gels exhibited a thermo-sensibility with an upper critical solution temperature (UCST) and a high water-absorbency. And the values of UCST and equilibrium swelling ratio largely depended on the inner structure of the semi-IPNs and the external solvent property. It was also revealed that the swelling process conformed to the Schott's pseudo second order model and diffusion type was non-Fickian diffusion. The value of activation energy for this polyelectrolyte was found to be 8.74kJ/mol. Copyright © 2017 Elsevier Ltd. All rights reserved.

Grizzly Usage and Theory Manual

DOE Office of Scientific and Technical Information (OSTI.GOV)

Spencer, B. W.; Backman, M.; Chakraborty, P.

2016-03-01

Grizzly is a multiphysics simulation code for characterizing the behavior of nuclear power plant (NPP) structures, systems and components (SSCs) subjected to a variety of age-related aging mechanisms. Grizzly simulates both the progression of aging processes, as well as the capacity of aged components to safely perform. This initial beta release of Grizzly includes capabilities for engineering-scale thermo-mechanical analysis of reactor pressure vessels (RPVs). Grizzly will ultimately include capabilities for a wide range of components and materials. Grizzly is in a state of constant development, and future releases will broaden the capabilities of this code for RPV analysis, as wellmore » as expand it to address degradation in other critical NPP components.« less

[System continuity and energy distribution in laser-induced thermo therapy (LITT)].

PubMed

Pech, M; Werk, M; Beck, A; Stohlmann, A; Ricke, J

2002-06-01

Evaluation of the continuity and energy distribution of a laser system for laser-induced thermo therapy. For evaluation of the continuity of laser optical devices, laser generating units and optical fibers of three different manufactures (Dornier, Hüttinger, Somatex), we used the equipment to generate a laser beam of 25 Watt for 60 minutes. Measurements of the applied energy were done sequentially with two MY Test (Fa. Hüttinger) units. We also performed two in vitro ablations of animal liver tissue with different fiber optics [Mikrodom A 13-0540, Microflexx REF A 13-0561 (Hüttinger), Diffusor-Tip H-6111-T 3, Diffusor H-6111-T 4 (Dornier), Somaflex-Diffusor (Somatex)] over 20 minutes at- an energy flow of 25 J per second. We then evaluated the geometry of coagulation. The different equipment used for our tests showed differences of a maximum of 10 %. Some components did not work properly in certain configurations even though the manufacturer assured it would. We saw significant differences in the ablation characteristics of the different fiber optics, especially in axial and frontal directions. Knowledge of the different characteristics in energy distribution and ablation characteristics are an important factor in performing a successful laser-induced thermo therapy.

Electro-Thermo-Mechanical Transient Modeling of Stress Development in AlGaN/GaN High Electron Mobility Transistors (HEMTs) (Postprint)

DTIC Science & Technology

2014-02-01

Applied Drain Voltage Ids Drain-to-Source current MPa Megapascals σxx x-Component of Stress INTRODUCTION Gallium nitride (GaN) based high electron...the thermodynamic model to obtain the current densities within a semiconductor device. In doing so, it is possible to determine the electric

A kinetic study of pyrolysis and combustion of microalgae Chlorella vulgaris using thermo-gravimetric analysis.

PubMed

Agrawal, Ankit; Chakraborty, Saikat

2013-01-01

This work uses thermo-gravimetric, differential thermo-gravimetric and differential thermal analyses to evaluate the kinetics of pyrolysis (in inert/N(2) atmosphere) and (oxidative) combustion of microalgae Chlorella vulgaris by heating from 50 to 800 °C at heating rates of 5-40 °C/min. This study shows that combustion produces higher biomass conversion than pyrolysis, and that three stages of decomposition occur in both cases, of which, the second one--consisting of two temperature zones--is the main stage of devolatization. Proteins and carbohydrates are decomposed in the first of the two zones at activation energies of 51 and 45 kJ/mol for pyrolysis and combustion, respectively, while lipids are decomposed in its second zone at higher activation energies of 64 and 63 kJ/mol, respectively. The kinetic expressions of the reaction rates in the two zones for pyrolysis and combustion have been obtained and it has been shown that increased heating rates result in faster and higher conversion. Copyright © 2012 Elsevier Ltd. All rights reserved.

DOE Office of Scientific and Technical Information (OSTI.GOV)

Zaupa, M., E-mail: matteo.zaupa@igi.cnr.it; Consorzio RFX, Corso Stati Uniti 4, Padova 35127; Sartori, E.

Megavolt ITER Injector Concept Advancement is the full scale prototype of the heating and current drive neutral beam injectors for ITER, to be built at Consorzio RFX (Padova). The engineering design of its components is challenging: the total heat loads they will be subjected to (expected between 2 and 19 MW), the high heat fluxes (up to 20 MW/m{sup 2}), and the beam pulse duration up to 1 h, set demanding requirements for reliable active cooling circuits. In support of the design, the thermo-hydraulic behavior of each cooling circuit under steady state condition has been investigated by using one-dimensional models.more » The final results, obtained considering a number of optimizations for the cooling circuits, show that all the requirements in terms of flow rate, temperature, and pressure drop are properly fulfilled.« less

Dissection of the components for PIP2 activation and thermosensation in TRP channels

PubMed Central

Brauchi, Sebastian; Orta, Gerardo; Mascayano, Carolina; Salazar, Marcelo; Raddatz, Natalia; Urbina, Hector; Rosenmann, Eduardo; Gonzalez-Nilo, Fernando; Latorre, Ramon

2007-01-01

Phosphatidylinositol 4,5-bisphosphate (PIP2) plays a central role in the activation of several transient receptor potential (TRP) channels. The role of PIP2 on temperature gating of thermoTRP channels has not been explored in detail, and the process of temperature activation is largely unexplained. In this work, we have exchanged different segments of the C-terminal region between cold-sensitive (TRPM8) and heat-sensitive (TRPV1) channels, trying to understand the role of the segment in PIP2 and temperature activation. A chimera in which the proximal part of the C-terminal of TRPV1 replaces an equivalent section of TRPM8 C-terminal is activated by PIP2 and confers the phenotype of heat activation. PIP2, but not temperature sensitivity, disappears when positively charged residues contained in the exchanged region are neutralized. Shortening the exchanged segment to a length of 11 aa produces voltage-dependent and temperature-insensitive channels. Our findings suggest the existence of different activation domains for temperature, PIP2, and voltage. We provide an interpretation for channel–PIP2 interaction using a full-atom molecular model of TRPV1 and PIP2 docking analysis. PMID:17548815

Commissioning of the Liquid Nitrogen Thermo-Siphon System for NASA-JSC Chamber A

NASA Technical Reports Server (NTRS)

Homan, J.; Montz, M.; Ganni, V.; Sidi-Yekhlef, A.; Knudsen, P.; Garcia, S.; Garza, J.

2013-01-01

NASA s Space Environment Simulation Laboratory s (SESL) Chamber A, located at the Johnson Space Center in Houston Texas has recently implemented major enhancements of its cryogenic and vacuum systems. The new liquid nitrogen (LN) thermo-siphon system was successfully commissioned in August of 2012. Chamber A, which has 20 K helium cryo-panels (or shrouds ) which are shielded by 80 K nitrogen shrouds, is capable of simulating a deep space environment necessary to perform ground testing of NASA s James Webb Space Telescope (JWST). Chamber A s previous system used forced flow LN cooling with centrifugal pumps, requiring 220,000 liters of LN to cool-down and consuming 180,000 liters per day of LN in steady operation. The LN system did not have the reliability required to meet the long duration test of the JWST, and the cost estimate provided in the initial approach to NASA-JSC by the subcontractor for refurbishment of the system to meet the reliability goals was prohibitive. At NASA-JSC s request, the JLab Cryogenics Group provided alternative options in 2007, including a thermo-siphon, or natural flow system. This system, eliminated the need for pumps and used one tenth of the original control valves, relief valves, and burst disks. After the thermo-siphon approach was selected, JLab provided technical assistance in the process design, mechanical design, component specification development and commissioning oversight, while the installation and commissioning operations of the system was overseen by the Jacobs Technology/ESC group at JSC. The preliminary commissioning data indicate lower shroud temperatures, 68,000 liters to cool-down and less than 91,000 liters per day consumed in steady operation. All of the performance capabilities have exceeded the design goals. This paper will outline the comparison between the original system and the predicted results of the selected design option, and the commissioning results of thermo-siphon system.

Commissioning of the Liquid Nitrogen Thermo-Siphon System for NASA-JSC Chamber-A

NASA Technical Reports Server (NTRS)

Homan, J.; Montz, M.; Ganni, V.; Sidi-Yekhlef, A.; Knudsen, P.; Garcia, S.; Garza, J.

2013-01-01

NASA's Space Environment Simulation Laboratory's (SESL) Chamber A, located at the Johnson Space Center in Houston Texas has recently implemented major enhancements of its cryogenic and vacuum systems. The new liquid nitrogen (LN2) thermo-siphon system was successfully commissioned in August of 2012. Chamber A, which has 20 K helium cryo-panels (or shrouds ) which are shielded by 80 K nitrogen shrouds, is capable of simulating a deep space environment necessary to perform ground testing of NASA s James Webb Space Telescope (JWST). Chamber A s previous system used forced flow LN2 cooling with centrifugal pumps, requiring 200,000 liters of LN2 to cool-down and consuming 180,000 liters per day of LN2 in steady operation. The LN2 system did not have the reliability required to meet the long duration test of the JWST, and the cost estimate provided in the initial approach to NASA-JSC by the sub-contractor for refurbishment of the system to meet the reliability goals was prohibitive. At NASA-JSC's request, the JLab Cryogenics Group provided alternative options in 2007, including a thermo-siphon, or natural flow system. This system, eliminated the need for pumps and used one tenth of the original control valves, relief valves, and burst disks. After the thermo-siphon approach was selected, JLab provided technical assistance in the process design, mechanical design, component specification development and commissioning oversight, while the installation and commissioning operations of the system was overseen by the Jacobs Technology/ESC group at JSC. The preliminary commissioning data indicate lower shroud temperatures, 70,000 liters to cool-down and less than 90,000 liters per day consumed in steady operation. All of the performance capabilities have exceeded the design goals. This paper will outline the comparison between the original system and the predicted results of the selected design option, and the commissioning results of thermo-siphon system.

Two-dimensional beam steering using a thermo-optic silicon photonic optical phased array

NASA Astrophysics Data System (ADS)

Rabinovich, William S.; Goetz, Peter G.; Pruessner, Marcel W.; Mahon, Rita; Ferraro, Mike S.; Park, Doe; Fleet, Erin; DePrenger, Michael J.

2016-11-01

Many components for free-space optical (FSO) communication systems have shrunken in size over the last decade. However, the steering systems have remained large and power hungry. Nonmechanical beam steering offers a path to reducing the size of these systems. Optical phased arrays can allow integrated beam steering elements. One of the most important aspects of an optical phased array technology is its scalability to a large number of elements. Silicon photonics can potentially offer this scalability using CMOS foundry techniques. A phased array that can steer in two dimensions using the thermo-optic effect is demonstrated. No wavelength tuning of the input laser is needed and the design allows a simple control system with only two inputs. A benchtop FSO link with the phased array in both transmit and receive mode is demonstrated.

Improving performance in thermodynamics: Integrating learning by teaching pedagogy

NASA Astrophysics Data System (ADS)

Campagni, Jamie Anthony

Historically, Thermo is perceived to be the most challenging course in the MET Curriculum at UNC Charlotte. The complexity and difficulties of this course have contributed to the some of the highest DFW rates compared to any other courses offered within the MET program. One hypothesis contributing to high DFW rates is the pedagogy in which Thermo is taught, which is the foundation of this study. Implementation of LBT in the spring 2014 offering of Thermo was deemed a success. The DFW rate in spring 2014 was reduced by 19 percentage points compared to the DFW rate in spring 2013, which exceeded the target of 10 percentage points. However, only cumulative GPA was a significant predictor of whether a student passed or failed the course. The semester in which students took Thermo was not a significant predictor. Students in the spring 2014 semester also exhibited statistically significant higher final exam averages compared to the 2012 and 2013 semesters. In general, students felt that LBT activities enhanced their learning and application of Thermodynamic concepts. Students had a very positive perception of LBT compared to traditional lecture in that 100% of students would recommend this teaching style to other students.

Thermo-tolerant phosphate-solubilizing microbes for multi-functional biofertilizer preparation.

PubMed

Chang, Cheng-Hsiung; Yang, Shang-Shyng

2009-02-01

In order to prepare the multi-functional biofertilizer, thermo-tolerant phosphate-solubilizing microbes including bacteria, actinomycetes, and fungi were isolated from different compost plants and biofertilizers. Except Streptomycesthermophilus J57 which lacked pectinase, all isolates possessed amylase, CMCase, chitinase, pectinase, protease, lipase, and nitrogenase activities. All isolates could solubilize calcium phosphate and Israel rock phosphate; various isolates could solubilize aluminum phosphate, iron phosphate, and hydroxyapatite. During composting, biofertilizers inoculated with the tested microbes had a significantly higher temperature, ash content, pH, total nitrogen, soluble phosphorus content, and germination rate than non-inoculated biofertilizer; total organic carbon and carbon-to-nitrogen ratio showed the opposite pattern. Adding these microbes can shorten the period of maturity, improve the quality, increase the soluble phosphorus content, and enhance the populations of phosphate-solubilizing and proteolytic microbes in biofertilizers. Therefore, inoculating thermo-tolerant phosphate-solubilizing microbes into agricultural and animal wastes represents a practical strategy for preparing multi-functional biofertilizer.

Active control of electromagnetic radiation through an enhanced thermo-optic effect

PubMed Central

Sheng, Chong; Liu, Hui; Zhu, Shining; Genov, Dentcho A.

2015-01-01

The control of electromagnetic radiation in transformation optical metamaterials brings the development of vast variety of optical devices. Of a particular importance is the possibility to control the propagation of light with light. In this work, we use a structured planar cavity to enhance the thermo-optic effect in a transformation optical waveguide. In the process, a control laser produces apparent inhomogeneous refractive index change inside the waveguides. The trajectory of a second probe laser beam is then continuously tuned in the experiment. The experimental results agree well with the developed theory. The reported method can provide a new approach toward development of transformation optical devices where active all-optical control of the impinging light can be achieved. PMID:25746689

Investigation of Prediction Method and Fundamental Thermo-decomposition Properties on Gasification of Woody Biomass

NASA Astrophysics Data System (ADS)

Morita, Akihiro

Recently, development of energy transfer technology based on woody biomass remarkably has been forwarding accompanied biomass boom for gasification and liquefaction. To elevate on yield of energy into biomass for transportation and exergy is extremely important for essential utilization and production of bio-fuels. Because, conversion to bio-fuel must be discussion in detail thermo-decomposition characteristics for biomass main composition formed on cellulose and hemicelluloses, lignin. In this research, we analyze thermo-decomposition characteristics of each biomass main composition on both active (air) and passive (N2) atmosphere. Especially, we suggest predict model of gasification based on change of atomic carbon ratio with thermo-decomposition. 1) Even if it heat-treats cedar chip by 473K, loss of energy hardly produces it. From this, it acquired that the substance contributed to weight reduction was a low ingredient of energy value. 2) If cedar chip is heated in the 473K around, it can be predicted that the substance with a low energy value like water or acetic acid has arisen by thermal decomposition. It suggested that the transportation performance of the biomass improved by choosing and eliminating these. 3) Each ingredient of hydrogen, nitrogen, and oxygen which dissipated in the gasification process acquired that it was direct proportion to the carbonaceous dissipation rate. 4) The action at the time of thermo-decomposition of (the carbon, hydrogen, nitrogen, oxygen which are) the main constituent factors of the biomass suggested a possibility of being predicted by a statistical method.

Two dimensional thermo-optic beam steering using a silicon photonic optical phased array

NASA Astrophysics Data System (ADS)

Mahon, Rita; Preussner, Marcel W.; Rabinovich, William S.; Goetz, Peter G.; Kozak, Dmitry A.; Ferraro, Mike S.; Murphy, James L.

2016-03-01

Components for free space optical communication terminals such as lasers, amplifiers, and receivers have all seen substantial reduction in both size and power consumption over the past several decades. However, pointing systems, such as fast steering mirrors and gimbals, have remained large, slow and power-hungry. Optical phased arrays provide a possible solution for non-mechanical beam steering devices that can be compact and lower in power. Silicon photonics is a promising technology for phased arrays because it has the potential to scale to many elements and may be compatible with CMOS technology thereby enabling batch fabrication. For most free space optical communication applications, two-dimensional beam steering is needed. To date, silicon photonic phased arrays have achieved two-dimensional steering by combining thermo-optic steering, in-plane, with wavelength tuning by means of an output grating to give angular tuning, out-of-plane. While this architecture might work for certain static communication links, it would be difficult to implement for moving platforms. Other approaches have required N2 controls for an NxN element phased array, which leads to complexity. Hence, in this work we demonstrate steering using the thermo-optic effect for both dimensions with a simplified steering mechanism requiring only two control signals, one for each steering dimension.

All-optical control of light on a graphene-on-silicon nitride chip using thermo-optic effect.

PubMed

Qiu, Ciyuan; Yang, Yuxing; Li, Chao; Wang, Yifang; Wu, Kan; Chen, Jianping

2017-12-06

All-optical signal processing avoids the conversion between optical signals and electronic signals and thus has the potential to achieve a power efficient photonic system. Micro-scale all-optical devices for light manipulation are the key components in the all-optical signal processing and have been built on the semiconductor platforms (e.g., silicon and III-V semiconductors). However, the two-photon absorption (TPA) effect and the free-carrier absorption (FCA) effect in these platforms deteriorate the power handling and limit the capability to realize complex functions. Instead, silicon nitride (Si 3 N 4 ) provides a possibility to realize all-optical large-scale integrated circuits due to its insulator nature without TPA and FCA. In this work, we investigate the physical dynamics of all-optical control on a graphene-on-Si 3 N 4 chip based on thermo-optic effect. In the experimental demonstration, a switching response time constant of 253.0 ns at a switching energy of ~50 nJ is obtained with a device dimension of 60 μm × 60 μm, corresponding to a figure of merit (FOM) of 3.0 nJ mm. Detailed coupled-mode theory based analysis on the thermo-optic effect of the device has been performed.

Optimization of culture conditions for production of a novel cold-active lipase from Pichia lynferdii NRRL Y-7723

USDA-ARS?s Scientific Manuscript database

Lipases with abnormal properties such as thermo stability, alkalinity, acidity and cold-activity receive industrial attention because of their usability under restricted reaction conditions. Most microbial cold-active lipases originate from psychrotrophic and psychrophilic microorganisms found in An...

Enhanced pathway efficiency of Saccharomyces cerevisiae by introducing thermo-tolerant devices.

PubMed

Liu, Yueqin; Zhang, Genli; Sun, Huan; Sun, Xiangying; Jiang, Nisi; Rasool, Aamir; Lin, Zhanglin; Li, Chun

2014-10-01

In this study, thermo-tolerant devices consisting of heat shock genes from thermophiles were designed and introduced into Saccharomyces cerevisiae for improving its thermo-tolerance. Among ten engineered thermo-tolerant yeasts, T.te-TTE2469, T.te-GroS2 and T.te-IbpA displayed over 25% increased cell density and 1.5-4-fold cell viability compared with the control. Physiological characteristics of thermo-tolerant strains revealed that better cell wall integrity, higher trehalose content and enhanced metabolic energy were preserved by thermo-tolerant devices. Engineered thermo-tolerant strain was used to investigate the impact of thermo-tolerant device on pathway efficiency by introducing β-amyrin synthesis pathway, showed 28.1% increased β-amyrin titer, 28-35°C broadened growth temperature range and 72h shortened fermentation period. The results indicated that implanting heat shock proteins from thermophiles to S. cerevisiae would be an efficient approach to improve its thermo-tolerance. Copyright © 2014 Elsevier Ltd. All rights reserved.

Computational homogenisation for thermoviscoplasticity: application to thermally sprayed coatings

NASA Astrophysics Data System (ADS)

Berthelsen, Rolf; Denzer, Ralf; Oppermann, Philip; Menzel, Andreas

2017-11-01

Metal forming processes require wear-resistant tool surfaces in order to ensure a long life cycle of the expensive tools together with a constant high quality of the produced components. Thermal spraying is a relatively widely applied coating technique for the deposit of wear protection coatings. During these coating processes, heterogeneous coatings are deployed at high temperatures followed by quenching where residual stresses occur which strongly influence the performance of the coated tools. The objective of this article is to discuss and apply a thermo-mechanically coupled simulation framework which captures the heterogeneity of the deposited coating material. Therefore, a two-scale finite element framework for the solution of nonlinear thermo-mechanically coupled problems is elaborated and applied to the simulation of thermoviscoplastic material behaviour including nonlinear thermal softening in a geometrically linearised setting. The finite element framework and material model is demonstrated by means of numerical examples.

Dynamic detailed model of a molten salt tower receiver, with ThermoSysPro library: Impacts of several failures or operational transients on the receiver dynamic behavior

NASA Astrophysics Data System (ADS)

Hefni, Baligh El; Bourdil, Charles

2017-06-01

Molten salt technology represents nowadays the most cost-effective technology for electricity generation for solar power plant. The molten salt tower receiver is based on a field of individually sun-tracking mirrors (heliostats) that reflect the incident sunshine to a receiver at the top of a centrally located tower. The objective of this study is to assess the impact of several transients issued from different scenarios (failure or normal operation mode) on the receiver dynamic behavior. A dynamic detailed model of Solar Two molten salt central receiver has been developed. The component model is meant to be used for receiver modeling with the ThermoSysPro library, developed by EDF. The paper also gives the results of the dynamic simulation for the selected scenarios on Solar Two receiver.

An Approximate Dissipation Function for Large Strain Rubber Thermo-Mechanical Analyses

NASA Technical Reports Server (NTRS)

Johnson, Arthur R.; Chen, Tzi-Kang

2003-01-01

Mechanically induced viscoelastic dissipation is difficult to compute. When the constitutive model is defined by history integrals, the formula for dissipation is a double convolution integral. Since double convolution integrals are difficult to approximate, coupled thermo-mechanical analyses of highly viscous rubber-like materials cannot be made with most commercial finite element software. In this study, we present a method to approximate the dissipation for history integral constitutive models that represent Maxwell-like materials without approximating the double convolution integral. The method requires that the total stress can be separated into elastic and viscous components, and that the relaxation form of the constitutive law is defined with a Prony series. Numerical data is provided to demonstrate the limitations of this approximate method for determining dissipation. Rubber cylinders with imbedded steel disks and with an imbedded steel ball are dynamically loaded, and the nonuniform heating within the cylinders is computed.

Microwave propagation and absorption and its thermo-mechanical consequences in heterogeneous rocks.

PubMed

Meisels, R; Toifl, M; Hartlieb, P; Kuchar, F; Antretter, T

2015-02-10

A numerical analysis in a two-component model rock is presented including the propagation and absorption of a microwave beam as well as the microwave-induced temperature and stress distributions in a consistent way. The analyses are two-dimensional and consider absorbing inclusions (discs) in a non-absorbing matrix representing the model of a heterogeneous rock. The microwave analysis (finite difference time domain - FDTD) is performed with values of the dielectric permittivity typical for hard rocks. Reflections at the discs/matrix interfaces and absorption in the discs lead to diffuse scattering with up to 20% changes of the intensity in the main beam compared to a homogeneous model rock. The subsequent thermo-mechanical finite element (FE) analysis indicates that the stresses become large enough to initiate damage. The results are supported by preliminary experiments on hard rock performed at 2.45 GHz.

Current status of final design and R&D for ITER blanket shield blocks in Korea

NASA Astrophysics Data System (ADS)

Ha, M. S.; Kim, S. W.; Jung, H. C.; Hwang, H. S.; Heo, Y. G.; Kim, D. H.; Ahn, H. J.; Lee, H. G.; Jung, K. J.

2015-07-01

The main function of the ITER blanket shield block (SB) is to provide nuclear shielding and support the first wall (FW) panel. It needs to accommodate all the components located on the vacuum vessel (in particular the in-vessel coils, blanket manifolds and the diagnostics). The conceptual, preliminary and final design reviews have been completed in the framework of the Blanket Integrated Product Team. The Korean Domestic Agency has successfully completed not only the final design activities, including thermo-hydraulic and thermo-mechanical analyses for SBs #2, #6, #8 and #16, but also the SB full scale prototype (FSP) pre-qualification program prior to issuing of the procurement agreement. SBs #2 and #6 are located at the in-board region of the tokamak. The pressure drop was less than 0.3 MPa and fully satisfied the design criteria. The thermo-mechanical stresses were also allowable even though the peak stresses occurred at nearby radial slit end holes, and their fatigue lives were evaluated over many more than 30 000 cycles. SB #8 is one of the most difficult modules to design, since this module will endure severe thermal loading not only from nuclear heating but also from plasma heat flux at uncovered regions by the FW. In order to resolve this design issue, the neutral beam shine-through module concept was applied to the FW uncovered region and it has been successfully verified as a possible design solution. SB #16 is located at the out-board central region of the tokamak. This module is under much higher nuclear loading than other modules and is covered by an enhanced heat flux FW panel. In the early design stage, many cooling headers on the front region were inserted to mitigate peak stresses near the access hole and radial slit end hole. However, the cooling headers on the front region needed to be removed in order to reduce the risk from cover welding during manufacturing. A few cooling headers now remain after efforts through several iterations to remove them and to optimize the cooling channels. The SB #8 FSP was manufactured and tested in accordance with the pre-qualification program based on the preliminary design, and related R&D activities were implemented to resolve the fabrication issues. This paper provides the current status of the final design and relevant R&D activities of the blanket SB.

Thermo-Gas-Dynamic Model of Afterburning in Explosions

DOE Office of Scientific and Technical Information (OSTI.GOV)

Kuhl, A L; Ferguson, R E; Bell, J B

2003-07-27

A theoretical model of afterburning in explosions created by turbulent mixing of the detonation products from fuel-rich charges with air is described. It contains three key elements: (i) a thermodynamic-equilibrium description of the fluids (fuel, air, and products), (ii) a multi-component gas-dynamic treatment of the flow field, and (iii) a sub-grid model of molecular processes of mixing, combustion and equilibration.

Design and characterization of Ge passive waveguide components on Ge-on-insulator wafer for mid-infrared photonics

NASA Astrophysics Data System (ADS)

Kang, Jian; Takagi, Shinichi; Takenaka, Mitsuru

2018-04-01

We present the design methodology for Ge passive components including single-mode waveguide, grating couplers, multimode interferometer (MMI) couplers, and micro-ring resonators on the Ge-on-insulator wafer at a 1.95 µm wavelength. Characterizations of the fabricated Ge passive devices reveal a good consistence between the experimental and simulation results. By using the Ge micro-ring device, we also reveal that the thermo-optic coefficient in the Ge strip waveguide is 5.74 × 10-4/°C, which is much greater than that in Si.

Thermo-mechanical fatigue behavior of reduced activation ferrite/martensite stainless steels

NASA Astrophysics Data System (ADS)

Petersen, C.; Rodrian, D.

2002-12-01

The thermo-mechanical cycling fatigue (TMCF) behavior of reduced activation ferrite/martensite stainless steels is examined. The test rig consists of a stiff load frame, which is directly heated by the digitally controlled ohmic heating device. Cylindrical specimens are used with a wall thickness of 0.4 mm. Variable strain rates are applied at TMCF test mode, due to the constant heating rate of 5.8 K/s and variable temperature changes. TMCF results of as received EUROFER 97 in the temperature range between 100 and 500-600 °C show a reduction in life time (a factor of 2) compared to F82H mod. and OPTIFER IV. TMCF-experiments with hold times of 100 and 1000 s show dramatic reduction in life time for all three materials.

Melting and reactive flow of a volatilized mantle beneath mid-ocean ridges: theory and numerical models

NASA Astrophysics Data System (ADS)

Keller, Tobias; Katz, Richard F.

2015-04-01

Laboratory experiments indicate that even small concentrations volatiles (H2O or CO2) in the upper mantle significantly affect the silicate melting behavior [HK96,DH06]. The presence of volatiles stabilizes volatile-rich melt at high pressure, thus vastly increasing the volume of the upper mantle expected to be partially molten [H10,DH10]. These small-degree melts have important consequences for chemical differentiation and could affect the dynamics of mantle flow. We have developed theory and numerical implementation to simulate thermo-chemically coupled magma/mantle dynamics in terms of a two-phase (rock+melt), three component (dunite+MORB+volatilized MORB) physical model. The fluid dynamics is based on McKenzie's equations [McK84], while the thermo-chemical formulation of the system is represented by a novel disequilibrium multi-component melting model based on thermo-dynamic theory [RBS11]. This physical model is implemented as a parallel, two-dimensional, finite-volume code that leverages tools from the PETSc toolkit. Application of this simulation code to a mid-ocean ridge system suggests that the methodology captures the leading-order features of both hydrated and carbonated mantle melting, including deep, low-degree, volatile-rich melt formation. Melt segregation leads to continuous dynamic thermo-chemical dis-equilibration, while phenomenological reaction rates are applied to continually move the system towards re-equilibration. The simulations will be used first to characterize volatile extraction from the MOR system assuming a chemically homogeneous mantle. Subsequently, simulations will be extended to investigate the consequences of heterogeneity in lithology [KW12] and volatile content. These studies will advance our understanding of the role of volatiles in the dynamic and chemical evolution of the upper mantle. Moreover, they will help to gauge the significance of the coupling between the deep carbon cycle and the ocean/atmosphere system. REFERENCES HK96 Hirth & Kohlstedt (1996), Earth Planet Sci Lett DH06 Dasgupta & Hirschmann (2006), doi:10.1038/nature04612. H10 Hirschmann (2010), doi:10.1016/j.pepi.2009.12.003. DH10 Dasgupta & Hirschmann (2010), doi:10.1016/j.epsl.2010.06.039. McK84 McKenzie (1984), J Pet KW12 Katz & Weatherley (2012), doi: 10.1016/j.epsl.2012.04.042. RBS11 Rudge, Bercovici & Spiegelman (2011), doi: 10.1111/j.1365-246X.2010.04870.x

Did Life Emerge in Thermo-Acidic Conditions?

NASA Astrophysics Data System (ADS)

Holmes, D. S.

2017-12-01

There is widespread, but not unanimous, agreement that life emerged in hot conditions by exploiting redox and pH disequilibria found on early earth. Although there are several hypotheses to explain the postulated pH disequilibria, few of these consider that life evolved at very low pH (<4). Such environments are thought to be hostile to life and certainly a poor area to search for clues for the abiotic to biotic transition and the early evolution of energetic pathways. However, low pH environments offer some remarkable opportunities for early biological evolution. This presentation will evaluate the pros and cons of the hypothesis that the early evolution of life occurred in thermo-acidic conditions. Such environments are thought to have been abundant on early earth and were probably rich in hydrogen and soluble metals including iron and sulfur that could have served as sources and sinks of electrons. Extant thermo-acidophiles thrive in such conditions. Low pH environments are rich in protons that are the major drivers of energy conservation by coupling to phosphorylation in virtually all organisms on earth; this may be a "biochemical fossil" reflecting the use of protons (low pH) in primitive energy conservation. It has also been proposed that acidic conditions favored the evolution of an RNA world with expanded catalytic activities. On the other hand, the idea that life emerged in thermo-acidic conditions can be challenged because of the proposed difficulties of folding and stabilizing proteins simultaneously exposed to high temperature and low pH. In addition, although thermo-acidophiles root to the base of the phylogenetic tree of life, consistent with the proposition that they evolved early, yet there are problems of interpretation of their subsequent evolution that cloud this simplistic phylogenetic view. We propose solutions to these problems and hypothesize that life evolved in thermo-acidic conditions.

ThermoFit: A Set of Software Tools, Protocols and Schema for the Organization of Thermodynamic Data and for the Development, Maintenance, and Distribution of Internally Consistent Thermodynamic Data/Model Collections

NASA Astrophysics Data System (ADS)

Ghiorso, M. S.

2013-12-01

Internally consistent thermodynamic databases are critical resources that facilitate the calculation of heterogeneous phase equilibria and thereby support geochemical, petrological, and geodynamical modeling. These 'databases' are actually derived data/model systems that depend on a diverse suite of physical property measurements, calorimetric data, and experimental phase equilibrium brackets. In addition, such databases are calibrated with the adoption of various models for extrapolation of heat capacities and volumetric equations of state to elevated temperature and pressure conditions. Finally, these databases require specification of thermochemical models for the mixing properties of solid, liquid, and fluid solutions, which are often rooted in physical theory and, in turn, depend on additional experimental observations. The process of 'calibrating' a thermochemical database involves considerable effort and an extensive computational infrastructure. Because of these complexities, the community tends to rely on a small number of thermochemical databases, generated by a few researchers; these databases often have limited longevity and are universally difficult to maintain. ThermoFit is a software framework and user interface whose aim is to provide a modeling environment that facilitates creation, maintenance and distribution of thermodynamic data/model collections. Underlying ThermoFit are data archives of fundamental physical property, calorimetric, crystallographic, and phase equilibrium constraints that provide the essential experimental information from which thermodynamic databases are traditionally calibrated. ThermoFit standardizes schema for accessing these data archives and provides web services for data mining these collections. Beyond simple data management and interoperability, ThermoFit provides a collection of visualization and software modeling tools that streamline the model/database generation process. Most notably, ThermoFit facilitates the rapid visualization of predicted model outcomes and permits the user to modify these outcomes using tactile- or mouse-based GUI interaction, permitting real-time updates that reflect users choices, preferences, and priorities involving derived model results. This ability permits some resolution of the problem of correlated model parameters in the common situation where thermodynamic models must be calibrated from inadequate data resources. The ability also allows modeling constraints to be imposed using natural data and observations (i.e. petrologic or geochemical intuition). Once formulated, ThermoFit facilitates deployment of data/model collections by automated creation of web services. Users consume these services via web-, excel-, or desktop-clients. ThermoFit is currently under active development and not yet generally available; a limited capability prototype system has been coded for Macintosh computers and utilized to construct thermochemical models for H2O-CO2 mixed fluid saturation in silicate liquids. The longer term goal is to release ThermoFit as a web portal application client with server-based cloud computations supporting the modeling environment.

Passive and electro-optic polymer photonics and InP electronics integration

NASA Astrophysics Data System (ADS)

Zhang, Z.; Katopodis, V.; Groumas, P.; Konczykowska, A.; Dupuy, J.-.; Beretta, A.; Dede, A.; Miller, E.; Choi, J. H.; Harati, P.; Jorge, F.; Nodjiadjim, V.; Dinu, R.; Cangini, G.; Vannucci, A.; Felipe, D.; Maese-Novo, A.; Keil, N.; Bach, H.-.; Schell, Martin; Avramopoulos, H.; Kouloumentas, Ch.

2015-05-01

Hybrid photonic integration allows individual components to be developed at their best-suited material platforms without sacrificing the overall performance. In the past few years a polymer-enabled hybrid integration platform has been established, comprising 1) EO polymers for constructing low-complexity and low-cost Mach-Zehnder modulators (MZMs) with extremely high modulation bandwidth; 2) InP components for light sources, detectors, and high-speed electronics including MUX drivers and DEMUX circuits; 3) Ceramic (AIN) RF board that links the electronic signals within the package. On this platform, advanced optoelectronic modules have been demonstrated, including serial 100 Gb/s [1] and 2x100 Gb/s [2] optical transmitters, but also 400 Gb/s optoelectronic interfaces for intra-data center networks [3]. To expand the device functionalities to an unprecedented level and at the same time improve the integration compatibility with diversified active / passive photonic components, we have added a passive polymer-based photonic board (polyboard) as the 4th material system. This passive polyboard allows for low-cost fabrication of single-mode waveguide networks, enables fast and convenient integration of various thin-film elements (TFEs) to control the light polarization, and provides efficient thermo-optic elements (TOEs) for wavelength tuning, light amplitude regulation and light-path switching.

Capillary thermoconcentration instability and processes of heat and mass transfer in laser technology

NASA Astrophysics Data System (ADS)

Maiorov, Vladimir S.

2002-04-01

The paper gives a description of the phenomenon that has a considerable, and often a decisive, influence on the course of physical processes under laser radiation interaction with a substance having at least one liquid phase. The explanation of the essence of this phenomenon lies at the intersection of two branches of science: mechanics of liquids and gases, and physical chemistry (thermodynamics of heterogeneous systems). Capillary thermo-concentration instability (CTCI) is present at any non-isotropic input of energy to a heterogeneous thermodynamical system having several phases. This instability manifests itself at the phase boundary and causes processes of mass transfer, redistribution of components, emergence of new phases, relaxation vibrations. This phenomenon is most pronounced in local processes at interaction of laser radiation with matter. The theory and practice of this phenomenon unite and describe a new class of effects widely spread in nature, which play a decisive role in many physical and chemical processes and find even more various spheres of practical application. A number of examples of capillary thermo- concentration instability application are given: separation of liquid mixtures to components under thermal action of laser beam; a new method of thermal silver-free photography; control of liquid metal convection in laser alloying.

The effect of raw materials on thermo-oxidative stability and glycidyl ester content of palm oil during frying.

PubMed

Aniołowska, Magda A; Kita, Agnieszka M

2016-04-01

The objective of this research was to determine the effects of the water content of food incorporated into frying oil on oil degradation and the content of glycidyl esters. Potato chips, French fries and snacks were fried intermittently in palm oil, which was heated at 180 °C for 8 h per day over five consecutive days. Thermo-oxidative and physical alterations, changes in fatty acid composition, total polar components, polar fraction composition, and water content were analysed. The content of glycidyl esters was measured by liquid chromatography-tandem mass spectrometry. More polar compounds were formed in the oil used for frying chips (252 g kg(-1)) than for French fries (229 g kg(-1)) or snacks (196 g kg(-1)). Reductions in glycidyl esters were found in oils used for frying--greater for frying snacks and French fries (95% and 93%) than for potato chips (87%). The rate of decrease of glycidyl esters was correlated with frying parameters, most strongly with the concentrations of diacylglycerols (r = 0.98) and total polar components (r = -0.98). The raw material had a greater influence on polymerization conversion and glycidyl ester content than on hydrolytic and oxidative changes in the frying oil. © 2015 Society of Chemical Industry.

Tracking and Control of Gas Turbine Engine Component Damage/Life

NASA Technical Reports Server (NTRS)

Jaw, Link C.; Wu, Dong N.; Bryg, David J.

2003-01-01

This paper describes damage mechanisms and the methods of controlling damages to extend the on-wing life of critical gas turbine engine components. Particularly, two types of damage mechanisms are discussed: creep/rupture and thermo-mechanical fatigue. To control these damages and extend the life of engine hot-section components, we have investigated two methodologies to be implemented as additional control logic for the on-board electronic control unit. This new logic, the life-extending control (LEC), interacts with the engine control and monitoring unit and modifies the fuel flow to reduce component damages in a flight mission. The LEC methodologies were demonstrated in a real-time, hardware-in-the-loop simulation. The results show that LEC is not only a new paradigm for engine control design, but also a promising technology for extending the service life of engine components, hence reducing the life cycle cost of the engine.

Characterization of recombinantly expressed dihydroxy-acid dehydratase from Sulfobus solfataricus-A key enzyme for the conversion of carbohydrates into chemicals.

PubMed

Carsten, Jörg M; Schmidt, Anja; Sieber, Volker

2015-10-10

Dihydroxyacid dehydratases (DHADs) are excellent biocatalysts for the defunctionalization of biomass. Here, we report on the recombinant production of DHAD from Sulfolobus solfataricus (SsDHAD) in E. coli and its characterization with special focus on activity toward non-natural substrates, thermo-stability, thermo-inactivation kinetics and activation capabilities and its application within multi-step cascades for chemicals production. Using a simple heat treatment of cell lysate as major purification step we achieved a specific activity of 4.4 units per gram cell mass toward the substrate d-gluconate. The optimal temperature and pH value for this reaction are 77°C and pH 6.2. The inhibitory concentration (IC50, 50% residual activity) of different alcohols was determined to be 15% (v/v) for ethanol, 4.5% (v/v) for butanol and 4% (v/v) for isobutanol. Besides d-gluconate and the natural substrate 2,3-dihydroxyisovalerate (DHIV) SsDHAD is able to convert the C3-sugar-acid d-glycerate to pyruvate, a reaction, which does not occur in natural metabolic pathways, with a specific activity of 10.7±0.4mU/mg. The specific activity of the enzyme can be increased 3-fold by incubation with 2-mercaptoethanol. The activation has no impact on temperature dependence, but modulates the thermo-inactivation tolerance at 50°C. The total turnover numbers for all of the three reactions was found to be 35.5×10(3)±1.0×10(3) for the conversion of d-gluconate to 2-keto-3-deoxygluconate (KDG), 28.2×10(3)±0.8×10(3) for DHIV to 2-ketovalerate (KIV) and 943±0.28×10(2) for d-glycerate to pyruvate. With activated SsDHAD these values could be further increased 5- and 4-fold for the d-gluconate and d-glycerate conversion, respectively. Copyright © 2015 Elsevier B.V. All rights reserved.

Cooling Device for Combat Vehicle Crew Drinking Water. Phase 1.

DTIC Science & Technology

1988-03-21

stainless steel . A third concept, in which the water container is plastic and the vacuum space is replaced by plastic foam, was also considered. The glass...Btu/ftO/=F/hr Glass Thermos 0.0905 Stainless Steel Thermos 0.1724 Foam Insulated Thermos 0.527 16 5.2. Thermal Electric Cooler Evaluation The TEC is... stainless steel thermos, which has a heat transfer coefficient approximately twice that of the glass thermos, is preferred for the vehicular use because it

Production of a Novel Cold-Active Lipase from Pichia lynferdii Y-7723

USDA-ARS?s Scientific Manuscript database

Lipase (triacylglycerol acylhydrolases, E.C. 3.1.1.3.) is one of the most important enzymes applied to the broad range of industrial application field. Especially, lipases with abnormal functionality such as thermo stability, alkaline, acidic, cold-activity gain special attention because of their a...

Active control of thermoacoustic amplification in a thermo-acousto-electric engine

NASA Astrophysics Data System (ADS)

Olivier, Come; Penelet, Guillaume; Poignand, Gaelle; Lotton, Pierrick

2014-05-01

In this paper, a new approach is proposed to control the operation of a thermoacoustic Stirling electricity generator. This control basically consists in adding an additional acoustic source to the device, connected through a feedback loop to a reference microphone, a phase-shifter, and an audio amplifier. Experiments are performed to characterize the impact of the feedback loop (and especially that of the controlled phase-shift) on the overall efficiency of the thermal to electric energy conversion performed by the engine. It is demonstrated that this external forcing of thermoacoustic self-sustained oscillations strongly impacts the performance of the engine, and that it is possible under some circumstances to improve the efficiency of the thermo-electric transduction, compared to the one reached without active control. Applicability and further directions of investigation are also discussed.

What Controls Thermo-osmosis? Molecular Simulations Show the Critical Role of Interfacial Hydrodynamics

NASA Astrophysics Data System (ADS)

Fu, Li; Merabia, Samy; Joly, Laurent

2017-11-01

Thermo-osmotic and related thermophoretic phenomena can be found in many situations from biology to colloid science, but the underlying molecular mechanisms remain largely unexplored. Using molecular dynamics simulations, we measure the thermo-osmosis coefficient by both mechanocaloric and thermo-osmotic routes, for different solid-liquid interfacial energies. The simulations reveal, in particular, the crucial role of nanoscale interfacial hydrodynamics. For nonwetting surfaces, thermo-osmotic transport is largely amplified by hydrodynamic slip at the interface. For wetting surfaces, the position of the hydrodynamic shear plane plays a key role in determining the amplitude and sign of the thermo-osmosis coefficient. Finally, we measure a giant thermo-osmotic response of the water-graphene interface, which we relate to the very low interfacial friction displayed by this system. These results open new perspectives for the design of efficient functional interfaces for, e.g., waste-heat harvesting.

The TRPM2 channel: A thermo-sensitive metabolic sensor.

PubMed

Kashio, Makiko; Tominaga, Makoto

2017-09-03

Living organisms continually experience changes in ambient temperature. To detect such temperature changes for adaptive behavioral responses, we evolved the ability to sense temperature. Thermosensitive transient receptor potential (TRP) channels, so-called thermo-TRPs, are involved in many physiologic functions in diverse organisms and constitute important temperature sensors. One of the important roles of thermo-TRPs is detecting ambient temperature in sensory neurons. Importantly, the functional expression of thermo-TRPs is observed not only in sensory neurons but also in tissues and cells that are not exposed to drastic temperature changes, indicating that thermo-TRPs are involved in many physiologic functions within the body's normal temperature range. Among such thermo-TRPs, this review focuses on one thermo-sensitive metabolic sensor in particular, TRPM2, and summarizes recent progress to clarify the regulatory mechanisms and physiologic functions of TRPM2 at body temperature under various metabolic states.

What Controls Thermo-osmosis? Molecular Simulations Show the Critical Role of Interfacial Hydrodynamics.

PubMed

Fu, Li; Merabia, Samy; Joly, Laurent

2017-11-24

Thermo-osmotic and related thermophoretic phenomena can be found in many situations from biology to colloid science, but the underlying molecular mechanisms remain largely unexplored. Using molecular dynamics simulations, we measure the thermo-osmosis coefficient by both mechanocaloric and thermo-osmotic routes, for different solid-liquid interfacial energies. The simulations reveal, in particular, the crucial role of nanoscale interfacial hydrodynamics. For nonwetting surfaces, thermo-osmotic transport is largely amplified by hydrodynamic slip at the interface. For wetting surfaces, the position of the hydrodynamic shear plane plays a key role in determining the amplitude and sign of the thermo-osmosis coefficient. Finally, we measure a giant thermo-osmotic response of the water-graphene interface, which we relate to the very low interfacial friction displayed by this system. These results open new perspectives for the design of efficient functional interfaces for, e.g., waste-heat harvesting.

Consortium inoculum of five thermo-tolerant phosphate solubilizing Actinomycetes for multipurpose biofertilizer preparation

PubMed Central

Nandimath, Arusha P.; Karad, Dilip D.; Gupta, Shantikumar G.; Kharat, Arun S.

2017-01-01

Background and Objectives: Alkaline pH of the soil facilitates the conversion of phosphate present in phosphate fertilizer applied in the field to insoluble phosphate which is not available to plants. Problem of soluble phosphate deficiency arises, primarily due to needless use of phosphate fertilizer. We sought to biofertilizer with the thermo-tolerant phosphate solubilizing actinomycetes consortium that could convert insoluble phosphate to soluble phosphate at wider temperature range. Materials and Methods: In the present investigation consortium of five thermo-tolerant phosphate solubilizing actinomycetes was applied for preparation of inoculum to produce multipurpose bio-fertilizer. Phosphates solubilizing thermo-tolerant 32 actinomycetes strains were processed for identification with the use of PIBWIN software and were screened for phosphate solubilizing activity. Results: Amongst these five actinomycetes were selected on the basis of their ability to produce cellulase, chitinase, pectinase, protease, lipase, amylase and phosphate solubilizing enzymes. Ability to produce these enzymes at 28°C and 50°C were examined. Biofertilizer was prepared by using agricultural waste as a raw material. While preparation of bio-fertilizer the pH decreased from 7.5 to 4.3 and temperature increased up to 74°C maximum at the end of 4th week and in subsequent week it started to decline gradually till it reached around 50°C, which was found to be stable up to eighth week. This thermo-tolerant actinomycetes consortium released soluble phosphate of up to 46.7 μg ml−1. Conclusion: As the mesophilic organisms die out at high temperature of composting hence thormo-tolerant actinomycetes would be the better substitute for preparation of phosphate solubilizing bio-fertilizer with added potential to degrade complex macromolecules in composting. PMID:29296275

Consortium inoculum of five thermo-tolerant phosphate solubilizing Actinomycetes for multipurpose biofertilizer preparation.

PubMed

Nandimath, Arusha P; Karad, Dilip D; Gupta, Shantikumar G; Kharat, Arun S

2017-10-01

Alkaline pH of the soil facilitates the conversion of phosphate present in phosphate fertilizer applied in the field to insoluble phosphate which is not available to plants. Problem of soluble phosphate deficiency arises, primarily due to needless use of phosphate fertilizer. We sought to biofertilizer with the thermo-tolerant phosphate solubilizing actinomycetes consortium that could convert insoluble phosphate to soluble phosphate at wider temperature range. In the present investigation consortium of five thermo-tolerant phosphate solubilizing actinomycetes was applied for preparation of inoculum to produce multipurpose bio-fertilizer. Phosphates solubilizing thermo-tolerant 32 actinomycetes strains were processed for identification with the use of PIBWIN software and were screened for phosphate solubilizing activity. Amongst these five actinomycetes were selected on the basis of their ability to produce cellulase, chitinase, pectinase, protease, lipase, amylase and phosphate solubilizing enzymes. Ability to produce these enzymes at 28°C and 50°C were examined. Biofertilizer was prepared by using agricultural waste as a raw material. While preparation of bio-fertilizer the pH decreased from 7.5 to 4.3 and temperature increased up to 74°C maximum at the end of 4 th week and in subsequent week it started to decline gradually till it reached around 50°C, which was found to be stable up to eighth week. This thermo-tolerant actinomycetes consortium released soluble phosphate of up to 46.7 μg ml -1 . As the mesophilic organisms die out at high temperature of composting hence thormo-tolerant actinomycetes would be the better substitute for preparation of phosphate solubilizing bio-fertilizer with added potential to degrade complex macromolecules in composting.

Reversible thermo-pneumatic valves on centrifugal microfluidic platforms.

PubMed

Aeinehvand, Mohammad Mahdi; Ibrahim, Fatimah; Harun, Sulaiman Wadi; Kazemzadeh, Amin; Rothan, Hussin A; Yusof, Rohana; Madou, Marc

2015-08-21

Centrifugal microfluidic systems utilize a conventional spindle motor to automate parallel biochemical assays on a single microfluidic disk. The integration of complex, sequential microfluidic procedures on these platforms relies on robust valving techniques that allow for the precise control and manipulation of fluid flow. The ability of valves to consistently return to their former conditions after each actuation plays a significant role in the real-time manipulation of fluidic operations. In this paper, we introduce an active valving technique that operates based on the deflection of a latex film with the potential for real-time flow manipulation in a wide range of operational spinning speeds. The reversible thermo-pneumatic valve (RTPV) seals or reopens an inlet when a trapped air volume is heated or cooled, respectively. The RTPV is a gas-impermeable valve composed of an air chamber enclosed by a latex membrane and a specially designed liquid transition chamber that enables the efficient usage of the applied thermal energy. Inputting thermo-pneumatic (TP) energy into the air chamber deflects the membrane into the liquid transition chamber against an inlet, sealing it and thus preventing fluid flow. From this point, a centrifugal pressure higher than the induced TP pressure in the air chamber reopens the fluid pathway. The behaviour of this newly introduced reversible valving system on a microfluidic disk is studied experimentally and theoretically over a range of rotational frequencies from 700 RPM to 2500 RPM. Furthermore, adding a physical component (e.g., a hemispherical rubber element) to induce initial flow resistance shifts the operational range of rotational frequencies of the RTPV to more than 6000 RPM. An analytical solution for the cooling of a heated RTPV on a spinning disk is also presented, which highlights the need for the future development of time-programmable RTPVs. Moreover, the reversibility and gas impermeability of the RTPV in the microfluidic networks are validated on a microfluidic disk designed for performing liquid circulation. Finally, an array of RTPVs is integrated into a microfluidic cartridge to enable sequential aliquoting for the conversion of dengue virus RNA to cDNA and the preparation of PCR reaction mixtures.

Agro-industrial residue from starch extraction of Pachyrhizus ahipa as filler of thermoplastic corn starch films.

PubMed

López, O V; Versino, F; Villar, M A; García, M A

2015-12-10

Biocomposites films based on thermoplastic corn starch (TPS) containing 0.5% w/w fibrous residue from Pachyrhizus ahipa starch extraction (PASR) were obtained by melt-mixing and compression molding. PASR is mainly constituted by remaining cell walls and natural fibers, revealed by Scanning Electron Microscopy (SEM). Chemical composition of the residue indicated that fiber and starch were the principal components. Biocomposites thermo-stability was determined by Thermo-Gravimetric Analysis. A continuous PASR-TPS interface was observed by SEM, as a result of a good adhesion of the fibrous residue to starch matrix. Likewise, films containing PASR presented fewer superficial cracks than TPS ones, whereas their fracture surfaces were more irregular. Besides, the presence of PASR increased starch films roughness, due to fibers agglomerates. Films reinforced with PASR showed significantly lower water vapor permeability (WVP). In addition, PARS filler increased maximum tensile strength and Young's modulus of TPS films, thus leading to more resistant starch matrixes. Copyright © 2015 Elsevier Ltd. All rights reserved.

Fabrication of stable electrode/diffusion barrier layers for thermoelectric filled skutterudite devices

DOEpatents

Jie, Qing; Ren, Zhifeng; Chen, Gang

2015-12-08

Disclosed are methods for the manufacture of n-type and p-type filled skutterudite thermoelectric legs of an electrical contact. A first material of CoSi.sub.2 and a dopant are ball-milled to form a first powder which is thermo-mechanically processed with a second powder of n-type skutterudite to form a n-type skutterudite layer disposed between a first layer and a third layer of the doped-CoSi.sub.2. In addition, a plurality of components such as iron, and nickel, and at least one of cobalt or chromium are ball-milled form a first powder that is thermo-mechanically processed with a p-type skutterudite layer to form a p-type skutterudite layer "second layer" disposed between a first and a third layer of the first powder. The specific contact resistance between the first layer and the skutterudite layer for both the n-type and the p-type skutterudites subsequent to hot-pressing is less than about 10.0 .mu..OMEGA.cm.sup.2.

Fabrication of stable electrode/diffusion barrier layers for thermoelectric filled skutterudite devices

DOEpatents

Jie, Qing; Ren, Zhifeng; Chen, Gang

2017-08-01

Disclosed are methods for the manufacture of n-type and p-type filled skutterudite thermoelectric legs of an electrical contact. A first material of CoSi.sub.2 and a dopant are ball-milled to form a first powder which is thermo-mechanically processed with a second powder of n-type skutterudite to form a n-type skutterudite layer disposed between a first layer and a third layer of the doped-CoSi.sub.2. In addition, a plurality of components such as iron, and nickel, and at least one of cobalt or chromium are ball-milled form a first powder that is thermo-mechanically processed with a p-type skutterudite layer to form a p-type skutterudite layer "second layer" disposed between a first and a third layer of the first powder. The specific contact resistance between the first layer and the skutterudite layer for both the n-type and the p-type skutterudites subsequent to hot-pressing is less than about 10.0 .mu..OMEGA.cm.sup.2.

PETher - Physical Properties of Thermal Water under In-situ-Conditions

NASA Astrophysics Data System (ADS)

Herfurth, Sarah; Schröder, Elisabeth

2016-04-01

The objective of PETher, a research project funded by the German Federal Ministry for Economic Affairs and Energy (BMWi), is to experimentally determine thermo-physical properties (specific isobaric heat capacity, kinematic viscosity, density and thermal conductivity) of geothermal water in-situ-conditions (pressure, temperature, chemical composition including gas content of the brine) present in geothermal applications. Knowing these thermo-physical properties reduces the uncertainties with respect to estimating the thermal output and therefore the economic viability of the power plant. Up to now, only a limited number of measurements of selected physical properties have been made, usually under laboratory conditions and for individual geothermal plants. In-situ measured parameters, especially in the temperature range of 120°C and higher, at pressures of 20 bar and higher, as well as with a salinity of up to 250 g/l, are sparse to non-existing. Therefore, pure water properties are often used as reference data and for designing the power plant and its components. Currently available numerical models describing the thermo-physical properties are typically not valid for the conditions in geothermal applications and do not consider the substantial influence of the chemical composition of the thermal water. Also, actual geothermal waters have not been subject of detailed measurements systematically performed under operational conditions on a large-scale basis. Owing to the lack of reliable data, a validation of numerical models for investigating geothermal systems is not possible. In order to determine the dependency of the thermo-physical properties of geothermal water on temperature, pressure and salinity in-situ measurements are conducted. The measurements are taking place directly at several geothermal applications located in Germany's hydrogeothermal key regions. In order to do this, a mobile testing unit was developed and refined with instruments specifically designed in-house to meet any geothermal reservoir conditions present in Germany. The obtained results will be compared with standard analytical methods as well as used to calibrate laboratory measurements that simulate the encountered in-situ conditions. A series of measurements will be performed to create a data base. In addition, these data can be used as reference data for developing and validating numerical models. In-situ measurements - in contrast to laboratory measurements - record the data online and instantaneously during normal operation of the plant and without changing the properties of the investigated fluid (pressure, temperature, etc.). Due to this, the uncertainties in the thermo-physical properties caused by degassing and precipitation are studiously avoided. As a result, the thermo-physical properties density, specific isobaric heat capacity, kinematic viscosity and thermal conductivity have been measured as functions of the geothermal water temperature, pressure and salinity at five sites, up to now. The measurements show that the thermo-physical properties correlate strongly with the salinity and therefore differ considerably from pure water values when a significant salt content is present.

Thermo-reversible inhibition makes aqualysin 1 from Thermus aquaticus a potent tool for studying the contribution of the wheat gluten network to the crumb texture of fresh bread.

PubMed

Verbauwhede, Annelien E; Lambrecht, Marlies A; Fierens, Ellen; Hermans, Senne; Shegay, Oksana; Brijs, Kristof; Delcour, Jan A

2018-10-30

The thermo-active serine peptidase aqualysin 1 (Aq1) of Thermus aquaticus was applied in bread making to study the relative contribution of thermoset gluten to bread crumb texture. Aq1 is active between 30 °C and 90 °C with an optimum activity temperature of around 65 °C. It is inhibited by wheat endogenous serine peptidase inhibitors during dough mixing and fermentation and starts hydrolyzing gluten proteins during baking above 80 °C when the enzyme is no longer inhibited and most of the starch is gelatinized and contributes to structure formation. Aq1 activity reduced the molecular weight of gluten proteins and significantly increased their extractability in sodium dodecyl sulfate containing medium. While it had no impact on the specific bread volume and only limited impact on hardness, cohesiveness, springiness, resilience and chewiness, it impacted bread crumb coherence. We conclude that starch has a greater impact on crumb texture than thermoset gluten. Copyright © 2018 Elsevier Ltd. All rights reserved.

New preparation method of {beta}{double_prime}-alumina and application for AMTEC

DOE Office of Scientific and Technical Information (OSTI.GOV)

Nishi, Toshiro; Tsuru, Yasuhiko; Yamamoto, Hirokazu

1995-12-31

The Alkali Metal Thermo-Electric Converter(AMTEC) is an energy conversion system that converts heat to electrical energy with high efficiency. The {beta}{double_prime}-alumina solid electrolyte (BASE) is the most important component in the AMTEC system. In this paper, the relationship among the conduction property, the microstructure and the amount of chemical component for BASE is studied. As an analysis of the chemical reaction for each component, the authors established a new BASE preparation method rather than using the conventional method. They also report the AMTFC cell performance using this electrolyte tube on which Mo or TiC electrode is filmed by the screenmore » printing method. Then, an electrochemical analysis and a heat cycle test of AMTEC cell are studied.« less

Sub-surface defects detection of by using active thermography and advanced image edge detection

NASA Astrophysics Data System (ADS)

Tse, Peter W.; Wang, Gaochao

2017-05-01

Active or pulsed thermography is a popular non-destructive testing (NDT) tool for inspecting the integrity and anomaly of industrial equipment. One of the recent research trends in using active thermography is to automate the process in detecting hidden defects. As of today, human effort has still been using to adjust the temperature intensity of the thermo camera in order to visually observe the difference in cooling rates caused by a normal target as compared to that by a sub-surface crack exists inside the target. To avoid the tedious human-visual inspection and minimize human induced error, this paper reports the design of an automatic method that is capable of detecting subsurface defects. The method used the technique of active thermography, edge detection in machine vision and smart algorithm. An infrared thermo-camera was used to capture a series of temporal pictures after slightly heating up the inspected target by flash lamps. Then the Canny edge detector was employed to automatically extract the defect related images from the captured pictures. The captured temporal pictures were preprocessed by a packet of Canny edge detector and then a smart algorithm was used to reconstruct the whole sequences of image signals. During the processes, noise and irrelevant backgrounds exist in the pictures were removed. Consequently, the contrast of the edges of defective areas had been highlighted. The designed automatic method was verified by real pipe specimens that contains sub-surface cracks. After applying such smart method, the edges of cracks can be revealed visually without the need of using manual adjustment on the setting of thermo-camera. With the help of this automatic method, the tedious process in manually adjusting the colour contract and the pixel intensity in order to reveal defects can be avoided.

Accuracy of the Thermo Fisher Scientific (Sensititre™) dry-form broth microdilution MIC product when testing ceftaroline.

PubMed

Jones, Ronald N; Holliday, Nicole M; Critchley, Ian A

2015-04-01

Ceftaroline, the active metabolite of the ceftaroline fosamil pro-drug, was the first advanced-spectrum cephalosporin with potent activity against methicillin-resistant Staphylococcus aureus to be approved by the US Food and Drug Administration for acute bacterial skin and skin structure infections. After 4 years of clinical use, few ceftaroline commercial susceptibility testing devices other than agar diffusion methods (disks and stable gradient) are available. Here, we validate a broth microdilution product (Sensititre™; Thermo Fisher Scientific, Cleveland, OH, USA) that achieved 99.2% essential agreement (manual and automated reading) and 95.3-100.0% categorical agreement, with high reproducibility (98.0-100.0%). Sensititre™ MIC values for ceftaroline, however, were slightly skewed toward an elevated value (0.5 × log2 dilution step), greatest when testing for streptococci and Enterobacteriaceae. Copyright © 2015 Elsevier Inc. All rights reserved.

NASALIFE - Component Fatigue and Creep Life Prediction Program

NASA Technical Reports Server (NTRS)

Gyekenyesi, John Z.; Murthy, Pappu L. N.; Mital, Subodh K.

2014-01-01

NASALIFE is a life prediction program for propulsion system components made of ceramic matrix composites (CMC) under cyclic thermo-mechanical loading and creep rupture conditions. Although the primary focus was for CMC components, the underlying methodologies are equally applicable to other material systems as well. The program references empirical data for low cycle fatigue (LCF), creep rupture, and static material properties as part of the life prediction process. Multiaxial stresses are accommodated by Von Mises based methods and a Walker model is used to address mean stress effects. Varying loads are reduced by the Rainflow counting method or a peak counting type method. Lastly, damage due to cyclic loading and creep is combined with Minor's Rule to determine damage due to cyclic loading, damage due to creep, and the total damage per mission and the number of potential missions the component can provide before failure.

Efficient heterologous expression, functional characterization and molecular modeling of annular seabream digestive phospholipase A2.

PubMed

Smichi, Nabil; Othman, Houcemeddine; Achouri, Neila; Noiriel, Alexandre; Triki, Soumaya; Arondel, Vincent; Srairi-Abid, Najet; Abousalham, Abdelkarim; Gargouri, Youssef; Miled, Nabil; Fendri, Ahmed

2018-03-01

Here we report the cDNA cloning of a phospholipase A 2 (PLA 2 ) from five Sparidae species. The deduced amino acid sequences show high similarity with pancreatic PLA 2 . In addition, a phylogenetic tree derived from alignment of various available sequences revealed that Sparidae PLA 2 are closer to avian PLA 2 group IB than to mammals' ones. In order to understand the structure-function relationships of these enzymes, we report here the recombinant expression in E.coli, the refolding and characterization of His-tagged annular seabream PLA 2 (AsPLA 2 ). A single Ni-affinity chromatography step was used to obtain a highly purified recombinant AsPLA 2 with a molecular mass of 15kDa as attested by gel electrophoresis and MALDI-TOF mass spectrometry data. The enzyme has a specific activity of 400U.mg -1 measured on phosphatidylcholine at pH 8.5 and 50°C. The enzyme high thermo-activity and thermo-stability make it a potential candidate in various biological applications. The 3D structure models of these enzymes were compared with structures of phylogenetically related pancreatic PLA 2 . By following these models and utilizing molecular dynamics simulations, the resistance of the AsPLA 2 at high temperatures was explained. Using the monomolecular film technique, AsPLA 2 was found to be active on various phospholipids spread at the air/water interface at a surface pressure between 12 and 25dyncm -1 . Interestingly, this enzyme was shown to be mostly active on dilauroyl-phosphatidylglycerol monolayers and this behavior was confirmed by molecular docking and dynamics simulations analysis. The discovery of a thermo-active new member of Sparidae PLA 2 , provides new insights on structure-activity relationships of fish PLA 2 . Copyright © 2017 Elsevier B.V. All rights reserved.

Laser reflector with an interference coating

DOE Office of Scientific and Technical Information (OSTI.GOV)

Vol'pyan, O D; Semenov, A A; Yakovlev, P P

1998-10-31

An analysis was made of the reflectivity of interference coatings intended for the use in optical pumping of solid-state lasers. Ruby and Nd{sup 3+}:YAG lasers were used as models in comparative pumping efficiency measurements, carried out employing reflectors with interference and silver coatings. Estimates of the service life of reflectors with interference coatings were obtained. The power of a thermo-optical lens was reduced by the use of such coatings in cw lasers. (laser system components)

Integrated Micro-Power System (IMPS) Development at NASA Glenn Research Center

NASA Technical Reports Server (NTRS)

Wilt, David; Hepp, Aloysius; Moran, Matt; Jenkins, Phillip; Scheiman, David; Raffaelle, Ryne

2003-01-01

Glenn Research Center (GRC) has a long history of energy related technology developments for large space related power systems, including photovoltaics, thermo-mechanical energy conversion, electrochemical energy storage. mechanical energy storage, power management and distribution and power system design. Recently, many of these technologies have begun to be adapted for small, distributed power system applications or Integrated Micro-Power Systems (IMPS). This paper will describe the IMPS component and system demonstration efforts to date.

Thermo-mechanical design aspects of mercury bombardment ion thrusters.

NASA Technical Reports Server (NTRS)

Schnelker, D. E.; Kami, S.

1972-01-01

The mechanical design criteria are presented as background considerations for solving problems associated with the thermomechanical design of mercury ion bombardment thrusters. Various analytical procedures are used to aid in the development of thruster subassemblies and components in the fields of heat transfer, vibration, and stress analysis. Examples of these techniques which provide computer solutions to predict and control stress levels encountered during launch and operation of thruster systems are discussed. Computer models of specific examples are presented.

ThermoData Engine Database

National Institute of Standards and Technology Data Gateway

SRD 103a NIST ThermoData Engine Database (PC database for purchase)   ThermoData Engine is the first product fully implementing all major principles of the concept of dynamic data evaluation formulated at NIST/TRC.

Thermo-chemical pretreatment and enzymatic hydrolysis for enhancing saccharification of catalpa sawdust.

PubMed

Jin, Shuguang; Zhang, Guangming; Zhang, Panyue; Li, Fan; Fan, Shiyang; Li, Juan

2016-04-01

To improve the reducing sugar production from catalpa sawdust, thermo-chemical pretreatments were examined and the chemicals used including NaOH, Ca(OH)2, H2SO4, and HCl. The hemicellulose solubilization and cellulose crystallinity index (CrI) were significantly increased after thermo-alkaline pretreatments, and the thermo-Ca(OH)2 pretreatment showed the best improvement for reducing sugar production comparing to other three pretreatments. The conditions of thermo-Ca(OH)2 pretreatment and enzymatic hydrolysis were systematically optimized. Under the optimal conditions, the reducing sugar yield increased by 1185.7% comparing to the control. This study indicates that the thermo-Ca(OH)2 pretreatment is ideal for the saccharification of catalpa sawdust and that catalpa sawdust is a promising raw material for biofuel. Copyright © 2016 Elsevier Ltd. All rights reserved.

Scale-Invariant Forms of Conservation Equations in Reactive Fields and a Modified Hydro-Thermo-Diffusive Theory of Laminar Flames

NASA Technical Reports Server (NTRS)

Sohrab, Siavash H.; Piltch, Nancy (Technical Monitor)

2000-01-01

A scale-invariant model of statistical mechanics is applied to present invariant forms of mass, energy, linear, and angular momentum conservation equations in reactive fields. The resulting conservation equations at molecular-dynamic scale are solved by the method of large activation energy asymptotics to describe the hydro-thermo-diffusive structure of laminar premixed flames. The predicted temperature and velocity profiles are in agreement with the observations. Also, with realistic physico-chemical properties and chemical-kinetic parameters for a single-step overall combustion of stoichiometric methane-air premixed flame, the laminar flame propagation velocity of 42.1 cm/s is calculated in agreement with the experimental value.

Removal of elemental mercury by TiO₂doped with WO₃ and V₂O₅ for their photo- and thermo-catalytic removal mechanisms.

PubMed

Shen, Huazhen; Ie, Iau-Ren; Yuan, Chung-Shin; Hung, Chung-Hsuang; Chen, Wei-Hsiang

2016-03-01

The catalytic removal of Hg(0) was investigated to ascertain whether the catalysts could simultaneously possess both thermo- and photo-catalytic reactivity. The immobilized V2O5/TiO2 and WO3/TiO2 catalysts were synthesized by sol-gel method and then coated on the surface of glass beads for catalytic removal of Hg(0). They were also characterized by SEM, BET, XRD, UV-visible, and XPS analysis, and their catalytic reactivity was tested under 100-160 °C under the near-UV irradiation. The results indicated that V2O5/TiO2 solely possessed the thermo-catalytic reactivity while WO3/TiO2 only had photo-catalytic reactivity. Although the synthesis catalytic reactivity has not been found for these catalysts up to date, but compared with TiO2, the removal efficiencies of Hg(0) at 140 and 160 °C were enhanced; particularly, the efficiency was improved from 20 % at 160 °C by TiO2 to nearly 90 % by WO3/TiO2 under the same operating conditions. The effects of doping amount of V2O5 and WO3 were also investigated, and the results showed that 10 % V2O5 and 5 % WO3/TiO2 were the best immobilized catalysts for thermo- and photo-catalytic reactivity, respectively. The effect of different influent concentrations of Hg(0) was demonstrated that the highest concentration of Hg(0) led to the best removal efficiencies for V2O5/TiO2 and WO3/TiO2 at 140 and 160 °C, because high Hg(0) concentration increased the mass transfer rate of Hg(0) toward the surface of catalysts and drove the reaction to proceed. At last, the effect of single gas component on the removal of Hg(0) was also investigated.

Studies on thermo-elastic heating of horns used in ultrasonic plastic welding.

PubMed

Roopa Rani, M; Prakasan, K; Rudramoorthy, R

2015-01-01

Ultrasonic welding horn is half wavelength section or tool used to focus the ultrasonic vibrations to the components being welded. The horn is designed in such a way that it maximizes the amplitude of the sound wave passing through it. The ends of the horn represent the displacement anti-nodes and the center the 'node' of the wave. As the horns perform 20,000 cycles of expansion and contraction per second, they are highly stressed at the nodes and are heated owing to thermo-elastic effects. Considerable temperature rise may be observed in the horn, at the nodal region when working at high amplitudes indicating high stress levels leading to failure of horns due to cyclic loading. The limits for amplitude must therefore be evaluated for the safe working of the horn. Horns made of different materials have different thermo-elastic behaviors and hence different temperatures at the nodes and antinodes. This temperature field can be used as a control mechanism for setting the amplitude/weld parameters. Safe stress levels can be predicted using modal and harmonic analyses followed by a stress analysis to study the effect of cyclic loads. These are achieved using 'Ansys'. The maximum amplitude level obtained from the stress analysis is used as input for 'Comsol' to predict the temperature field. The actual temperature developed in the horn during operation is measured using infrared camera and compared with the simulated temperature. From experiments, it is observed that horn made of titanium had the lowest temperature rise at the critical region and can be expected to operate at amplitudes up to 77 μm without suffering failure due to cyclic loading. The method of predicting thermo-elastic stresses and temperature may be adopted by the industry for operating the horn within the safe stress limits thereby extending the life of the horn. Copyright © 2014 Elsevier B.V. All rights reserved.

Effect of thermo-mechanical treatments on the microstructure and mechanical properties of an ODS ferritic steel

NASA Astrophysics Data System (ADS)

Oksiuta, Z.; Mueller, P.; Spätig, P.; Baluc, N.

2011-05-01

The Fe-14Cr-2W-0.3Ti-0.3Y 2O 3 oxide dispersion strengthened (ODS) reduced activation ferritic (RAF) steel was fabricated by mechanical alloying of a pre-alloyed, gas atomised powder with yttria nano-particles, followed by hot isostatic pressing and thermo-mechanical treatments (TMTs). Two kinds of TMT were applied: (i) hot pressing, or (ii) hot rolling, both followed by annealing in vacuum at 850 °C. The use of a thermo-mechanical treatment was found to yield strong improvement in the microstructure and mechanical properties of the ODS RAF steel. In particular, hot pressing leads to microstructure refinement, equiaxed grains without texture, and an improvement in Charpy impact properties, especially in terms of the upper shelf energy (about 4.5 J). Hot rolling leads to elongated grains in the rolling direction, with a grain size ratio of 6:1, higher tensile strength and reasonable ductility up to 750 °C, and better Charpy impact properties, especially in terms of the ductile-to-brittle transition temperature (about 55 °C).

Thermo-msf-parser: an open source Java library to parse and visualize Thermo Proteome Discoverer msf files.

PubMed

Colaert, Niklaas; Barsnes, Harald; Vaudel, Marc; Helsens, Kenny; Timmerman, Evy; Sickmann, Albert; Gevaert, Kris; Martens, Lennart

2011-08-05

The Thermo Proteome Discoverer program integrates both peptide identification and quantification into a single workflow for peptide-centric proteomics. Furthermore, its close integration with Thermo mass spectrometers has made it increasingly popular in the field. Here, we present a Java library to parse the msf files that constitute the output of Proteome Discoverer. The parser is also implemented as a graphical user interface allowing convenient access to the information found in the msf files, and in Rover, a program to analyze and validate quantitative proteomics information. All code, binaries, and documentation is freely available at http://thermo-msf-parser.googlecode.com.

Thermo-elastic optical coherence tomography.

PubMed

Wang, Tianshi; Pfeiffer, Tom; Wu, Min; Wieser, Wolfgang; Amenta, Gaetano; Draxinger, Wolfgang; van der Steen, Antonius F W; Huber, Robert; Soest, Gijs van

2017-09-01

The absorption of nanosecond laser pulses induces rapid thermo-elastic deformation in tissue. A sub-micrometer scale displacement occurs within a few microseconds after the pulse arrival. In this Letter, we investigate the laser-induced thermo-elastic deformation using a 1.5 MHz phase-sensitive optical coherence tomography (OCT) system. A displacement image can be reconstructed, which enables a new modality of phase-sensitive OCT, called thermo-elastic OCT. An analysis of the results shows that the optical absorption is a dominating factor for the displacement. Thermo-elastic OCT is capable of visualizing inclusions that do not appear on the structural OCT image, providing additional tissue type information.

2La chromosomal inversion enhances thermal tolerance of Anopheles gambiae larvae.

PubMed

Rocca, Kyle A C; Gray, Emilie M; Costantini, Carlo; Besansky, Nora J

2009-07-02

The mosquito Anopheles gambiae is broadly distributed throughout sub-Saharan Africa and this contributes to making it the most efficient vector of malaria on the continent. The pervasiveness of this species is hypothesized to originate in local adaptations facilitated by inversion polymorphisms. One inversion, named 2La, is strongly associated with aridity clines in West and Central Africa: while 2La is fixed in arid savannas, the 2L+a arrangement is predominantly found in the rainforest. Ability to survive high temperature exposure is an essential component of aridity tolerance, particularly in immature stages that are restricted to shallow puddles. Toward deciphering the role of the 2La inversion in local adaptation, the present investigation focused on variation in larval and pupal thermo-tolerance in two populations dissimilar solely in 2La arrangement. A laboratory colony of A. gambiae that is polymorphic for 2La but standard for all other known inversions was used to create 2 homokaryotypic populations (2L+a and 2La). The survival of 4th instar larvae and pupae from both populations was then tested following exposure to thermal stress with and without prior heat hardening. Larvae responded identically to a 40 degrees C heat stress, with about 50% of larvae dying after 1.5-2 h and few larvae surviving a 3 h stress. When heat hardened prior to the thermal stress, thermo-tolerance of both larval populations increased, with 2La 24 h survival significantly exceeding that of 2L+a. Pupae were generally more thermo-tolerant than larvae, although 2La pupae were less so than 2L+a. Heat hardening had no positive effect on pupal thermo-tolerance. The increased thermo-tolerance observed in 2La larvae following heat hardening suggests higher responsiveness (i.e., thermal sensitivity) of the inverted karyotype. By responding more drastically to the heat shock, 2La larvae are better equipped to resist the potentially lethal temperatures that occur in arid habitats. The lower survival of 2La pupae compared with 2L+a may reflect the cost of this sensitivity, whereby the thermal resistance mechanisms prevent successful completion of metamorphosis. The costs and benefits of thermal resistance are discussed in light of the climates characterizing either end of the 2La frequency cline.

Interactive evolution concept for analyzing a rock salt cavern under cyclic thermo-mechanical loading

NASA Astrophysics Data System (ADS)

König, Diethard; Mahmoudi, Elham; Khaledi, Kavan; von Blumenthal, Achim; Schanz, Tom

2016-04-01

The excess electricity produced by renewable energy sources available during off-peak periods of consumption can be used e.g. to produce and compress hydrogen or to compress air. Afterwards the pressurized gas is stored in the rock salt cavities. During this process, thermo-mechanical cyclic loading is applied to the rock salt surrounding the cavern. Compared to the operation of conventional storage caverns in rock salt the frequencies of filling and discharging cycles and therefore the thermo-mechanical loading cycles are much higher, e.g. daily or weekly compared to seasonally or yearly. The stress strain behavior of rock salt as well as the deformation behavior and the stability of caverns in rock salt under such loading conditions are unknown. To overcome this, existing experimental studies have to be supplemented by exploring the behavior of rock salt under combined thermo-mechanical cyclic loading. Existing constitutive relations have to be extended to cover degradation of rock salt under thermo-mechanical cyclic loading. At least the complex system of a cavern in rock salt under these loading conditions has to be analyzed by numerical modeling taking into account the uncertainties due to limited access in large depth to investigate material composition and properties. An interactive evolution concept is presented to link the different components of such a study - experimental modeling, constitutive modeling and numerical modeling. A triaxial experimental setup is designed to characterize the cyclic thermo-mechanical behavior of rock salt. The imposed boundary conditions in the experimental setup are assumed to be similar to the stress state obtained from a full-scale numerical simulation. The computational model relies primarily on the governing constitutive model for predicting the behavior of rock salt cavity. Hence, a sophisticated elasto-viscoplastic creep constitutive model is developed to take into account the dilatancy and damage progress, as well as the temperature effects. The contributed input parameters in the constitutive model are calibrated using the experimental measurements. In the following, the initial numerical simulation is modified based on the introduced constitutive model implemented in a finite element code. However, because of the significant levels of uncertainties involved in the design procedure of such structures, a reliable design can be achieved by employing probabilistic approaches. Therefore, the numerical calculation is extended by statistical tools such as sensitivity analysis, probabilistic analysis and robust reliability-based design. Uncertainties e.g. due to limited site investigation, which is always fragmentary within these depths, can be compensated by using data sets of field measurements for back calculation of input parameters with the developed numerical model. Monitoring concepts can be optimized by identifying sensor localizations e.g. using sensitivity analyses.

Molecular cloning, expression, and characterization of four novel thermo-alkaliphilic enzymes retrieved from a metagenomic library.

PubMed

Maruthamuthu, Mukil; van Elsas, Jan Dirk

2017-01-01

Enzyme discovery is a promising approach to aid in the deconstruction of recalcitrant plant biomass in an industrial process. Novel enzymes can be readily discovered by applying metagenomics on whole microbiomes. Our goal was to select, examine, and characterize eight novel glycoside hydrolases that were previously detected in metagenomic libraries, to serve biotechnological applications with high performance. Here, eight glycosyl hydrolase family candidate genes were selected from metagenomes of wheat straw-degrading microbial consortia using molecular cloning and subsequent gene expression studies in Escherichia coli. Four of the eight enzymes had significant activities on either p NP-β-d-galactopyranoside, p NP-β-d-xylopyranoside, p NP-α-l-arabinopyranoside or p NP-α-d-glucopyranoside. These proteins, denoted as proteins 1, 2, 5 and 6, were his-tag purified and their nature and activities further characterized using molecular and activity screens with the p NP-labeled substrates. Proteins 1 and 2 showed high homologies with (1) a β-galactosidase (74%) and (2) a β-xylosidase (84%), whereas the remaining two (5 and 6) were homologous with proteins reported as a diguanylate cyclase and an aquaporin, respectively. The β-galactosidase- and β-xylosidase-like proteins 1 and 2 were confirmed as being responsible for previously found thermo-alkaliphilic glycosidase activities of extracts of E. coli carrying the respective source fosmids. Remarkably, the β-xylosidase-like protein 2 showed activities with both p NP-Xyl and p NP-Ara in the temperature range 40-50 °C and pH range 8.0-10.0. Moreover, proteins 5 and 6 showed thermotolerant α-glucosidase activity at pH 10.0. In silico structure prediction of protein 5 revealed the presence of a potential "GGDEF" catalytic site, encoding α-glucosidase activity, whereas that of protein 6 showed a "GDSL" site, encoding a 'new family' α-glucosidase activity. Using a rational screening approach, we identified and characterized four thermo-alkaliphilic glycosyl hydrolases that have the potential to serve as constituents of enzyme cocktails that produce sugars from lignocellulosic plant remains.

Study of Polyolefines Waste Thermo-Destruction in Large Laboratory and in Industrial Installations

DTIC Science & Technology

2014-12-15

coke ”–waste after thermo-destruction carried out on the module No 2 showed an content to 46.1% of ash [20]. This ash content indicates a very large... coke (post-production waste) from the wastes thermo-destruction on 2 modules of vertical modular installation for thermo-destruction of used polymer...of receivedwaste water, the quantity of received coke , the quantity of gaseous product in periods of carrying out installation work before (first

Thermo-Mechanical Fatigue of a Fiber Reinforced Titanium Aluminide Composite

DTIC Science & Technology

1991-03-01

Puiitr]on Air Foic. Base, Oiio 91 10 25 038 DTIC 4E L L E C :i<. THERMO- MECHAN I CAL FAT I GUE OF A FIBER REINFORCED TITANIUM ALUMINIDE COMPOSITE Thesis...reinforced titanium aluminide composite was investigated. Three test specimens were subjected to in-phase thermo- mechanical cycling and four to out-of...Unclassified UL ............................... AFIT/GAE/ENY/91S-1 THERMO- MECHANICAL FATIGUE OF A FIBER REINFORCED TITANIUM ALUMINIDE COMPOSITE THESIS

Investigation on thermo-acoustic instability dynamic characteristics of hydrocarbon fuel flowing in scramjet cooling channel based on wavelet entropy method

NASA Astrophysics Data System (ADS)

Zan, Hao; Li, Haowei; Jiang, Yuguang; Wu, Meng; Zhou, Weixing; Bao, Wen

2018-06-01

As part of our efforts to find ways and means to further improve the regenerative cooling technology in scramjet, the experiments of thermo-acoustic instability dynamic characteristics of hydrocarbon fuel flowing have been conducted in horizontal circular tubes at different conditions. The experimental results indicate that there is a developing process from thermo-acoustic stability to instability. In order to have a deep understanding on the developing process of thermo-acoustic instability, the method of Multi-scale Shannon Wavelet Entropy (MSWE) based on Wavelet Transform Correlation Filter (WTCF) and Multi-Scale Shannon Entropy (MSE) is adopted in this paper. The results demonstrate that the developing process of thermo-acoustic instability from noise and weak signals is well detected by MSWE method and the differences among the stability, the developing process and the instability can be identified. These properties render the method particularly powerful for warning thermo-acoustic instability of hydrocarbon fuel flowing in scramjet cooling channels. The mass flow rate and the inlet pressure will make an influence on the developing process of the thermo-acoustic instability. The investigation on thermo-acoustic instability dynamic characteristics at supercritical pressure based on wavelet entropy method offers guidance on the control of scramjet fuel supply, which can secure stable fuel flowing in regenerative cooling system.

Thermo-Mechanical Methodology for Stabilizing Shape Memory Alloy Response

NASA Technical Reports Server (NTRS)

Padula, Santo

2013-01-01

This innovation is capable of significantly reducing the amount of time required to stabilize the strain-temperature response of a shape memory alloy (SMA). Unlike traditional stabilization processes that take days to weeks to achieve stabilized response, this innovation accomplishes stabilization in a matter of minutes, thus making it highly useful for the successful and practical implementation of SMA-based technologies in real-world applications. The innovation can also be applied to complex geometry components, not just simple geometries like wires or rods.

Macroscopic constitutive equations of thermo-poroelasticity derived using eigenstrain-eigenstress approaches

NASA Astrophysics Data System (ADS)

Suvorov, Alexander P.; Selvadurai, A. P. S.

2011-06-01

Macroscopic constitutive equations for thermoelastic processes in a fluid-saturated porous medium are re-derived using the notion of eigenstrain or, equivalently, eigenstress. The eigenstrain-stress approach is frequently used in micromechanics of solid multi-phase materials, such as composites. Simple derivations of the stress-strain constitutive relations and the void occupancy relationship are presented for both fully saturated and partially saturated porous media. Governing coupled equations for the displacement components and the fluid pressure are also obtained.

Development of Microstructure and Crystallographic Texture in a Double-Sided Friction Stir Welded Microalloyed Steel

NASA Astrophysics Data System (ADS)

Rahimi, S.; Wynne, B. P.; Baker, T. N.

2017-01-01

The evolution of microstructure and crystallographic texture has been investigated in double-sided friction stir welded microalloyed steel, using electron backscatter diffraction (EBSD). The microstructure analyses show that the center of stirred zone reached a temperature between Ac1 and Ac3 during FSW, resulting in a dual-phase austenitic/ ferritic microstructure. The temperatures in the thermo-mechanically affected zone and the overlapped area between the first and second weld pass did not exceed the Ac1. The shear generated by the rotation probe occurs in austenitic/ferritic phase field where the austenite portion of the microstructure is transformed to a bainitic ferrite, on cooling. Analysis of crystallographic textures with regard to shear flow lines generated by the probe tool shows the dominance of simple shear components across the whole weld. The austenite texture at Ac1 - Ac3 is dominated by the B { {1bar{1}2} }< 110rangle and bar{B} { {bar{1}1bar{2}} }< bar{1}bar{1}0rangle simple shear texture components, where the bainite phase textures formed on cooling were inherited from the shear textures of the austenite phase with relatively strong variant selection. The ferrite portion of the stirred zone and the ferrites in the thermo-mechanically affected zones and the overlapped area underwent shear deformation with textures dominated by the D1 { {bar{1}bar{1}2} }< 111rangle and D2 { {11bar{2}} }< 111rangle simple shear texture components. The formation of ultrafine equiaxed ferrite with submicron grain size has been observed in the overlapped area between the first and second weld pass. This is due to continuous dynamic strain-induced recrystallization as a result of simultaneous severe shear deformation and drastic undercooling.

DOE Office of Scientific and Technical Information (OSTI.GOV)

Ammigan, K.; Hurh, P.

The Radiation Damage In Accelerator Target Environments (RaDIATE) collaboration was founded in 2012 and currently consists of over 50 participants and 11 institutions globally. Due to the increasing power of future proton accelerator sources in target facilities, there is a critical need to further understand the physical and thermo-mechanical radiation response of target facility materials. Thus, the primary objective of the RaDIATE collaboration is to draw on existing expertise in the nuclear materials and accelerator targets fields to generate new and useful materials data for application within the accelerator and fission/fusion communities. Current research activities of the collaboration include postmore » irradiation examination (PIE) of decommissioned components from existing beamlines such as the NuMI beryllium beam window and graphite NT-02 target material. PIE of these components includes advanced microstructural analyses (SEM/TEM, EBSD, EDS) and micro-mechanics technique such as nano-indentation, to help characterize any microstructural radiation damage incurred during operation. New irradiation campaigns of various candidate materials at both low and high energy beam facilities are also being pursued. Beryllium helium implantation studies at the University of Surrey as well as high energy proton irradiation of various materials at Brookhaven National Laboratory’s BLIP facility have been initiated. The program also extends to beam-induced thermal shock experiments using high intensity beam pulses at CERN’s HiRadMat facility, followed by advanced PIE activities to evaluate thermal shock resistance of the materials. Preliminary results from ongoing research activities, as well as the future plans of the RaDIATE collaboration R&D program will be discussed.« less

Improving Thermo-Oxidative Stability of Nitrile Rubber Composites by Functional Graphene Oxide.

PubMed

Zhong, Rui; Zhang, Zhao; Zhao, Hongguo; He, Xianru; Wang, Xin; Zhang, Rui

2018-05-30

Graphene oxide (GO), modified with anti-aging agent p -phenylenediamine (PPD), was added into nitrile rubber (NBR) in order to improve the thermo-oxidative stability of NBR. The modification of GO and the transformation of functional groups were characterized by Fourier transform infrared spectroscopy (FTIR), Raman, and X-ray diffraction (XRD). Mechanical performances of NBR composites before and after the thermo-oxidative aging were recorded. The results of dynamic mechanical analysis (DMA) show an increased storage modulus (G') and a decreased value of area of tan δ peak after introducing modified GO into NBR. It indicates that filler particles show positive interaction with molecular chains. The thermo-oxidative stability of composites was investigated by thermogravimetric analysis (TG) and differential scanning calorimetry (DSC). Then, the thermo-oxidative aging kinetic parameters were obtained by the Flynn⁻Wall⁻Ozawa (FWO) equation. The results of aging tests show that the thermo-oxidative stability of rubber matrix increases obviously after introducing GO⁻PPD. In addition, mechanical properties (tensile strength and elongation at break) of both before and after aged NBR/GO⁻PPD composites were superior to that of NBR. This work provides meaningful guidance for achieving multifunction thermo-oxidative aging resistance rubber composites.

A Mathematical Model of the Thermo-Anemometric Flowmeter

PubMed Central

Korobiichuk, Igor; Bezvesilna, Olena; Ilchenko, Andriі; Shadura, Valentina; Nowicki, Michał; Szewczyk, Roman

2015-01-01

A thermo-anemometric flowmeter design and the principles of its work are presented in the article. A mathematical model of the temperature field in a stream of biofuel is proposed. This model allows one to determine the fuel consumption with high accuracy. Numerical modeling of the heater heat balance in the fuel flow of a thermo-anemometric flowmeter is conducted and the results are analyzed. Methods for increasing the measurement speed and accuracy of a thermo-anemometric flowmeter are proposed. PMID:26378535

A Mathematical Model of the Thermo-Anemometric Flowmeter.

PubMed

Korobiichuk, Igor; Bezvesilna, Olena; Ilchenko, Andriі; Shadura, Valentina; Nowicki, Michał; Szewczyk, Roman

2015-09-11

A thermo-anemometric flowmeter design and the principles of its work are presented in the article. A mathematical model of the temperature field in a stream of biofuel is proposed. This model allows one to determine the fuel consumption with high accuracy. Numerical modeling of the heater heat balance in the fuel flow of a thermo-anemometric flowmeter is conducted and the results are analyzed. Methods for increasing the measurement speed and accuracy of a thermo-anemometric flowmeter are proposed.

A novel cold-adapted esterase from Enterobacter cloacae: Characterization and improvement of its activity and thermostability via the site of Tyr193Cys.

PubMed

Gao, Haofeng; Li, Chanjuan; Bandikari, Ramesh; Liu, Ziduo; Hu, Nan; Yong, Qiang

2018-03-19

In industries lipolytic reactions occur in insensitive conditions such as high temperature thus novel stout esterases with unique properties are attracts to the industrial application. Protein engineering is the tool to obtain desirable characters of enzymes. A novel esterase gene was isolated from South China Sea and subjected to a random mutagenesis and site directed mutagenesis for higher activity and thermo-stability compared to wild type. A novel esterase showed the highest hydrolytic activity against p-nitrophenyl acetate (pNPA, C2) and the optimal activity at 40 °C and pH 8.5. It was a cold-adapted enzyme and retained approximately 40% of its maximum activity at 0 °C. A mutant, with higher activity and thermo-stability was obtained by random mutagenesis. Kinetic analysis indicated that the mutant Val29Ala/Tyr193Cys shown 43.5% decrease in K m , 2.6-fold increase in K cat , and 4.7-fold increase in K cat /K m relative to the wild type. Single mutants V29A and Y193C were constructed and their kinetic parameters were measured. The results showed that the values of K m , K cat , and K cat /K m of V29A were similar to those of the wild type while Y193C showed 52.7% decrease in K m , 2.7-fold increase in K cat , and 5.6-fold increase in K cat /K m compared with the wild type. The 3-D structure and docking analysis revealed that the replacement of Tyr by Cys could enlarge the binding pocket. Moreover Y193C also showed a better thermo-stability for the reason its higher hydrophobicity and retained 67% relative activity after incubation for 3 h at 50 °C. The superior quality of modified esterase suggested it has great potential application in extreme conditions and the mutational work recommended that important information for the study of esterase structure and function.

Binary blend of glyceryl monooleate and glyceryl monostearate for magnetically induced thermo-responsive local drug delivery system.

PubMed

Mengesha, Abebe E; Wydra, Robert J; Hilt, J Zach; Bummer, Paul M

2013-12-01

To develop a novel monoglycerides-based thermal-sensitive drug delivery system, specifically for local intracavitary chemotherapy. Lipid matrices containing mixtures of glyceryl monooleate (GMO) and glyceryl monostearate (GMS) were evaluated for their potential application as magnetically induced thermo-responsive local drug delivery systems using a poorly water-soluble model drug, nifedipine (NF). Oleic acid-modified iron oxide (OA-Fe3O4) nanoparticles were embedded into the GMO-GMS matrix for remote activation of the drug release using an alternating magnetic field (AMF). The crystallization behavior of binary blends of GMO and GMS as characterized by DSC did show temperature dependent phase transition. GMO-GMS (75:25 wt%) blend showed a melting (T m ) and crystallization (T c ) points at 42°C and 37°C, respectively indicating the potential of the matrix to act as an 'on-demand' drug release. The matrix released only 35% of the loaded drug slowly in 10 days at 37°C whereas 96% release was obtained at 42°C. A concentration of 0.5% OA-Fe3O4 heated the matrix to 42.3 and 45.5°C within 5 min and 10 min of AMF exposure, respectively. The in vitro NF release profiles form the monoglycerides matrix containing 0.5% OA-Fe3O4 nanoparticles after AMF activation confirmed the thermo-responsive nature of the matrix that could provide pulsatile drug release 'on-demand'.

Thermo-Responsive Amphiphilic Block Copolymers Stablilized Gold Nanoparticles: Synthesis and High Catalytic Properties.

PubMed

Lü, Jianhua; Yang, Yu; Gao, Junfang; Duan, Haichao; Lü, Changli

2018-06-19

A series of novel well-defined 8-hydroxyquinoline (HQ)-containing thermo-responsive amphiphilic diblock copolymers poly(styrene-co-5-(2-methacryloylethyloxy- methyl)-8-quinolinol)-b-poly(N-isopropylacrylamide) P(St-co-MQ)-b-PNIPAm (P1,2), P(NIPAm- co-MQ)-b-PSt (P3,4) and triblock copolymer poly(N-isopropylacrylamide)-b-poly(methyl- methacrylate-co-5-(2-methacryloylethyloxymethyl)-8-quinolinol)-b-polystyrene PNIPAm-b- P(MMA-co-MQ)-b-PSt (P5) were prepared by reversible addition fragmentation chain transfer (RAFT) polymerization, and their self-assembly behaviors were studied. The block copolymers P1-P5 stabilized gold nanoparticles (Au@P1-Au@P5) with small size and narrow distribution were obtained through in situ reduction of gold precursors in aqueous solution of polymer micelles with HQ as the coordination groups. The resulting Au@P nanohybrids possessed excellent catalytic activities for the reduction of nitrophenols using NaBH4. The size, morphology and surface chemistry of Au NPs could be controlled by adjusting the structure of block polymers with HQ in different block positions, which plays an important role in the catalytic properties. It was found that longer chain length of hydrophilic or hydrophobic segments of block copolymers were beneficial to elevate the catalytic activity of Au NPs for the reduction of nitrophenols, and the spherical nanoparticles (Au@P5) stabilized with triblock copolymer exhibit higher catalytic performance. Surprisingly, the gold nanowires (Au@P4) produced with P4 have a highest catalytic activity due to large abundance of grain boundaries. Excellent thermo-responsive behaviors for catalytic reaction make the as-prepared Au@P hybrids become an environmentally responsive nano-catalytic materials.

Development and characterization of thermal responsivehydrogel films for biomedical sensor application

NASA Astrophysics Data System (ADS)

López-Barriguete, Jesús Eduardo; Isoshima, Takashi; Bucio, Emilio

2018-04-01

Two flexible stimuli-responsive hydrogel films were elaborated as biomedical sensor application. The hydrogel systems were contained in glass moulds and synthesized using gamma radiation at a dose rate of 10.1 kGy h‑1, and absorbed dose of 50 kGy. The poly(NIPAAm) with a low critical solution temperature (LCST) close to the human body temperature, was employed as the principal component for the responsive materials. The addition of dimethyl acrylamide (DMAAm) for hydrophilic effect, methyl methacrylate (MMA) for mechanical property, and ethoxyethyl methacrylate (EEM) for mechanical property, modified the thermo dynamic transition point, obtaining viable responsive films with LCST of 36 °C and 39 °C. The samples were characterized by DSC to analyse the LCST, FT-IR to characterize the functional groups of the resulting films, AFM to examine the surface morphology, and swelling measurement to support the flexibility. Responsive ‘intelligent’ films with thermo sensitivity, biocompatibility, resistance, and conformableness are important to the development of flexible polymers for the application of biological sensor, smart membranes, or flexible electronics.

Thermo-optical Modelling of Laser Matter Interactions in Selective Laser Melting Processes.

NASA Astrophysics Data System (ADS)

Vinnakota, Raj; Genov, Dentcho

Selective laser melting (SLM) is one of the promising advanced manufacturing techniques, which is providing an ideal platform to manufacture components with zero geometric constraints. Coupling the electromagnetic and thermodynamic processes involved in the SLM, and developing the comprehensive theoretical model of the same is of great importance since it can provide significant improvements in the printing processes by revealing the optimal parametric space related to applied laser power, scan velocity, powder material, layer thickness and porosity. Here, we present a self-consistent Thermo-optical model which simultaneously solves the Maxwell's and the heat transfer equations and provides an insight into the electromagnetic energy released in the powder-beds and the concurrent thermodynamics of the particles temperature rise and onset of melting. The numerical calculations are compared with developed analytical model of the SLM process providing insight into the dynamics between laser facilitated Joule heating and radiation mitigated rise in temperature. These results provide guidelines toward improved energy efficiency and optimization of the SLM process scan rates. The current work is funded by the NSF EPSCoR CIMM project under award #OIA-1541079.

Space Shuttle Orbiter Wing-Leading-Edge Panel Thermo-Mechanical Analysis for Entry Conditions

NASA Technical Reports Server (NTRS)

Knight, Norman F., Jr.; Song, Kyongchan; Raju, Ivatury S.

2010-01-01

Linear elastic, thermo-mechanical stress analyses of the Space Shuttle Orbiter wing-leading-edge panels is presented for entry heating conditions. The wing-leading-edge panels are made from reinforced carbon-carbon and serve as a part of the overall thermal protection system. Three-dimensional finite element models are described for three configurations: integrated configuration, an independent single-panel configuration, and a local lower-apex joggle segment. Entry temperature conditions are imposed and the through-the-thickness response is examined. From the integrated model, it was concluded that individual panels can be analyzed independently since minimal interaction between adjacent components occurred. From the independent single-panel model, it was concluded that increased through-the-thickness stress levels developed all along the chord of a panel s slip-side joggle region, and hence isolated local joggle sections will exhibit the same trend. From the local joggle models, it was concluded that two-dimensional plane-strain models can be used to study the influence of subsurface defects along the slip-side joggle region of these panels.

A High-Rate, Single-Crystal Model for Cyclotrimethylene Trinitramine including Phase Transformations and Plastic Slip

DOE PAGES

Addessio, Francis L.; Luscher, Darby Jon; Cawkwell, Marc Jon; ...

2017-05-14

A continuum model for the high-rate, thermo-mechanical deformation of single-crystal cyclotrimethylene trinitramine (RDX) is developed. The model includes the effects of anisotropy, large deformations, nonlinear thermo-elasticity, phase transformations, and plastic slip. A multiplicative decomposition of the deformation gradient is used. The volumetric elastic component of the deformation is accounted for through a free-energy based equation of state for the low- (α) and high-pressure (γ) polymorphs of RDX. Crystal plasticity is addressed using a phenomenological thermal activation model. The deformation gradient for the phase transformation is based on an approach that has been applied to martensitic transformations. Simulations were conducted andmore » compared to high-rate, impact loading of oriented RDX single crystals. The simulations considered multiple orientations of the crystal relative to the direction of shock loading and multiple sample thicknesses. Thirteen slip systems, which were inferred from indentation and x-ray topography, were used to model the α-polymorph. It is shown that by increasing the number of slip systems from the previously considered number of six (6) to thirteen (13) in the α-polymorph, better comparisons with data may be obtained. Simulations of impact conditions in the vicinity of the α- to γ-polymorph transformation (3.8 GPa) are considered. Eleven of the simulations, which were at pressures below the transformation value (3.0 GPa), were compared to experimental data. Comparison of the model was also made with available data for one experiment above the transformation pressure (4.4 GPa). Also, simulations are provided for a nominal pressure of 7.5 GPa to demonstrate the effect of the transformation kinetics on the deformation of a high-rate plate impact problem.« less

A High-Rate, Single-Crystal Model for Cyclotrimethylene Trinitramine including Phase Transformations and Plastic Slip

DOE Office of Scientific and Technical Information (OSTI.GOV)

Addessio, Francis L.; Luscher, Darby Jon; Cawkwell, Marc Jon

A continuum model for the high-rate, thermo-mechanical deformation of single-crystal cyclotrimethylene trinitramine (RDX) is developed. The model includes the effects of anisotropy, large deformations, nonlinear thermo-elasticity, phase transformations, and plastic slip. A multiplicative decomposition of the deformation gradient is used. The volumetric elastic component of the deformation is accounted for through a free-energy based equation of state for the low- (α) and high-pressure (γ) polymorphs of RDX. Crystal plasticity is addressed using a phenomenological thermal activation model. The deformation gradient for the phase transformation is based on an approach that has been applied to martensitic transformations. Simulations were conducted andmore » compared to high-rate, impact loading of oriented RDX single crystals. The simulations considered multiple orientations of the crystal relative to the direction of shock loading and multiple sample thicknesses. Thirteen slip systems, which were inferred from indentation and x-ray topography, were used to model the α-polymorph. It is shown that by increasing the number of slip systems from the previously considered number of six (6) to thirteen (13) in the α-polymorph, better comparisons with data may be obtained. Simulations of impact conditions in the vicinity of the α- to γ-polymorph transformation (3.8 GPa) are considered. Eleven of the simulations, which were at pressures below the transformation value (3.0 GPa), were compared to experimental data. Comparison of the model was also made with available data for one experiment above the transformation pressure (4.4 GPa). Also, simulations are provided for a nominal pressure of 7.5 GPa to demonstrate the effect of the transformation kinetics on the deformation of a high-rate plate impact problem.« less

Fabrication of thermo-responsive PNIPAAm-g-ETFE for cell culture dishes by pre-irradiation grafting

NASA Astrophysics Data System (ADS)

Yamahara, Yumi; Nagasawa, Naotsugu; Taguchi, Mitsumasa; Oshima, Akihiro; Washio, Masakazu

2018-01-01

Thermo-responsive templates for the cell cultivation based on Poly(tetrafluoroethylene-co-ethylene) (ETFE) were fabricated by pre-irradiation grafting of N-isoproplyacrylamide (NIPAAm) monomer by electron beam (EB) irradiation under nitrogen gas atmosphere at room temperature, and their characteristic properties were studied. The detachment of cultured HeLa cells from fabricated thermo-responsive templates were attempted. Furthermore, the reaction mechanism is proposed using ESR spectroscopy and FT-IR spectroscopy. It is confirmed that the cultured HeLa cells were detached from fabricated thermo-responsive templates at 20 °C. Water contact angle analysis indicated that obtained templates had thermo-response around 30 °C. It is suggested that the grafted polymer chains would mainly react with peroxy radicals (-CF2-CF(OO･)-) on tetrafluoroethylene unit in ETFE.

Development of an injectable pseudo-bone thermo-gel for application in small bone fractures.

PubMed

Kondiah, Pariksha J; Choonara, Yahya E; Kondiah, Pierre P D; Kumar, Pradeep; Marimuthu, Thashree; du Toit, Lisa C; Pillay, Viness

2017-03-30

A pseudo-bone thermo-gel was synthesized and evaluated for its physicochemical, mechanical and rheological properties, with its application to treat small bone fractures. The pseudo-bone thermo-gel was proven to have thermo-responsive properties, behaving as a solution in temperatures below 25°C, and forming a gelling technology when maintained at physiological conditions. Poly propylene fumerate (PPF), Pluronic F127 and PEG-PCL-PEG were strategically blended, obtaining a thermo-responsive delivery system, to mimic the mechanical properties of bone with sufficient matrix hardness and resilience. A Biopharmaceutics Classification System (BCS) class II drug, simvastatin, was loaded in the pseudo-bone thermo-gel, selected for its bone healing properties. In vitro release analysis was undertaken on a series of experimental formulations, with the ideal formulations obtaining its maximum controlled drug release profile up to 14days. Ex vivo studies were undertaken on an induced 4mm diameter butterfly-fractured osteoporotic human clavicle bone samples. X-ray, ultrasound as well as textural analysis, undertaken on the fractured bones before and after treatment displayed significant bone filling, matrix hardening and matrix resilience properties. These characteristics of the pseudo-bone thermo-gel thus proved significant potential for application in small bone fractures. Copyright © 2017 Elsevier B.V. All rights reserved.

Analysis of volatiles in fire debris by combination of activated charcoal strips (ACS) and automated thermal desorption-gas chromatography-mass spectrometry (ATD/GC-MS).

PubMed

Martin Fabritius, Marie; Broillet, Alain; König, Stefan; Weinmann, Wolfgang

2018-06-04

Adsorption of volatiles in gaseous phase to activated charcoal strip (ACS) is one possibility for the extraction and concentration of ignitable liquid residues (ILRs) from fire debris in arson investigations. Besides liquid extraction using carbon dioxide or hexane, automated thermo-desorption can be used to transfer adsorbed residues to direct analysis by gas chromatography-mass spectrometry (GC-MS). We present a fire debris analysis work-flow with headspace adsorption of volatiles onto ACS and subsequent automated thermo-desorption (ATD) GC-MS analysis. Only a small portion of the ACS is inserted in the ATD tube for thermal desorption coupled to GC-MS, allowing for subsequent confirmation analysis with another portion of the same ACS. This approach is a promising alternative to the routinely used ACS method with solvent extraction of retained volatiles, and the application to fire debris analysis is demonstrated. Copyright © 2018 Elsevier B.V. All rights reserved.

Numerical simulation of a battlefield Nd:YAG laser

NASA Astrophysics Data System (ADS)

Henriksson, Markus; Sjoqvist, Lars; Uhrwing, Thomas

2005-11-01

A numeric model has been developed to identify the critical components and parameters in improving the output beam quality of a flashlamp pumped Q-switched Nd:YAG laser with a folded Porro-prism resonator and polarization output coupling. The heating of the laser material and accompanying thermo-optical effects are calculated using the finite element partial differential equations package FEMLAB allowing arbitrary geometries and time distributions. The laser gain and the cavity are modeled with the physical optics simulation code GLAD including effects such as gain profile, thermal lensing and stress-induced birefringence, the Pockels cell rise-time and component aberrations. The model is intended to optimize the pumping process of an OPO providing radiation to be used for ranging, imaging or optical countermeasures.

WMAP Observatory Thermal Design and On-Orbit Thermal Performance

NASA Technical Reports Server (NTRS)

Glazer, Stuart D.; Brown, Kimberly D.; Michalek, Theodore J.; Ancarrow, Walter C.

2003-01-01

The Wilkinson Microwave Anisotropy Probe (WMAP) observatory, launched June 30, 2001, is designed to measure the cosmic microwave background radiation with unprecedented precision and accuracy while orbiting the second Lagrange point (L2). The instrument cold stage must be cooled passively to <95K, and systematic thermal variations in selected instrument components controlled to less than 0.5 mK (rms) per spin period. This paper describes the thermal design and testing of the WMAP spacecraft and instrument. Flight thermal data for key spacecraft and instrument components are presented from launch through the first year of mission operations. Effects of solar flux variation due to the Earth's elliptical orbit about the sun, surface thermo-optical property degradations, and solar flares on instrument thermal stability are discussed.

Extravehicular mobility unit thermal simulator

NASA Technical Reports Server (NTRS)

Hixon, C. W.; Phillips, M. A.

1973-01-01

The analytical methods, thermal model, and user's instructions for the SIM bay extravehicular mobility unit (EMU) routine are presented. This digital computer program was developed for detailed thermal performance predictions of the crewman performing a command module extravehicular activity during transearth coast. It accounts for conductive, convective, and radiative heat transfer as well as fluid flow and associated flow control components. The program is a derivative of the Apollo lunar surface EMU digital simulator. It has the operational flexibility to accept card or magnetic tape for both the input data and program logic. Output can be tabular and/or plotted and the mission simulation can be stopped and restarted at the discretion of the user. The program was developed for the NASA-JSC Univac 1108 computer system and several of the capabilities represent utilization of unique features of that system. Analytical methods used in the computer routine are based on finite difference approximations to differential heat and mass balance equations which account for temperature or time dependent thermo-physical properties.

Wood-Graphene Oxide Composite for Highly Efficient Solar Steam Generation and Desalination.

PubMed

Liu, Keng-Ku; Jiang, Qisheng; Tadepalli, Sirimuvva; Raliya, Ramesh; Biswas, Pratim; Naik, Rajesh R; Singamaneni, Srikanth

2017-03-01

Solar steam generation is a highly promising technology for harvesting solar energy, desalination and water purification. We introduce a novel bilayered structure composed of wood and graphene oxide (GO) for highly efficient solar steam generation. The GO layer deposited on the microporous wood provides broad optical absorption and high photothermal conversion resulting in rapid increase in the temperature at the liquid surface. On the other hand, wood serves as a thermal insulator to confine the photothermal heat to the evaporative surface and to facilitate the efficient transport of water from the bulk to the photothermally active space. Owing to the tailored bilayer structure and the optimal thermo-optical properties of the individual components, the wood-GO composite structure exhibited a solar thermal efficiency of ∼83% under simulated solar excitation at a power density of 12 kW/m 2 . The novel composite structure demonstrated here is highly scalable and cost-efficient, making it an attractive material for various applications involving large light absorption, photothermal conversion and heat localization.

Electron backscatter and X-ray diffraction studies on the deformation and annealing textures of austenitic stainless steel 310S

DOE Office of Scientific and Technical Information (OSTI.GOV)

Nezakat, Majid, E-mail: majid.nezakat@usask.ca

We studied the texture evolution of thermo-mechanically processed austenitic stainless steel 310S. This alloy was cold rolled up to 90% reduction in thickness and subsequently annealed at 1050 °C. At the early stages of deformation, strain-induced martensite was formed from deformed austenite. By increasing the deformation level, slip mechanism was found to be insufficient to accommodate higher deformation strains. Our results demonstrated that twinning is the dominant deformation mechanism at higher deformation levels. Results also showed that cold rolling in unidirectional and cross rolling modes results in Goss/Brass and Brass dominant textures in deformed samples, respectively. Similar texture components aremore » observed after annealing. Thus, the annealing texture was greatly affected by texture of the deformed parent phase and martensite did not contribute as it showed an athermal reversion during annealing. Results also showed that when the fraction of martensite exceeds a critical point, its grain boundaries impeded the movement of austenite grain boundaries during annealing. As a result, recrystallization incubation time would increase. This caused an incomplete recrystallization of highly deformed samples, which led to a rational drop in the intensity of the texture components. - Highlights: •Thermo-mechanical processing through different cold rolling modes can induce different textures. •Martensite reversion is athermal during annealing. •Higher fraction of deformation-induced martensite can increase the annealing time required for complete recrystallization. •Annealing texture is mainly influenced by the deformation texture of austenite.« less

Lateral spread of heat during thyroidectomy using different haemostatic devices.

PubMed

Adamczewski, Zbigniew; Król, Aleksander; Kałużna-Markowska, Karolina; Brzeziński, Jan; Lewiński, Andrzej; Dedecjus, Marek

2015-01-01

The presented study is an attempt to comprehensively analyze the lateral spread of heat during thyroidectomy. Obtained results may be valuable in other surgical disciplines in which thermal analysis is difficult or impossible. The aim of the study was to evaluate the temperature distribution in the operating field during thyroidectomy performed with the use of modern haemostatic instruments, and to define the safety margin for the investigated devices. Ninety-three patients were thyroidectomised due to thyroid neoplasm. During all the operations the thermovisual measurements were carried out along with continuous intraoperative neuromonitoring of the recurrent laryngeal nerve (CIONM). Investigated patients were divided into 5 groups, named according to the applied haemostatic technique: LigaSure (N=17); ThermoStapler (N=20); Focus (N=19); SonoSurg (N=17) and Monopolar (N=20). At maximal performance settings, the highest working temperature was observed for the ThermoStapler, while the lowest temperature was recorded for the Monopolar. Safety margin and working time were increased in Focus and SonoSurg, compared to LigaSure and ThermoStapler. The differences in the necrosis thickness were negligible. The largest distance of the midline of the active blade from isotherm of 42ºC observed in the study was 5.51 mm; none of investigated devices used at a bigger distance had influence on the morphology of the electric signal of CIONM. The thermo-visual camera allows non-invasive, safe, and real-time monitoring and analysis of temperature distribution in the operation area during thyroidectomy. Proposed minimal safety margin for the analysed devices is 5.51 mm.

TPV Power Source Using Infrared-Sensitive Cells with Commercially Available Radiant Tube Burner

NASA Astrophysics Data System (ADS)

Fraas, Lewis; Minkin, Leonid; Hui, She; Avery, James; Howells, Christopher

2004-11-01

Over the last several years, JX Crystals has invented and systematically developed the key components for thermophotovoltaic systems. These key components include GaSb infrared sensitive cells, high power density shingle circuits, dielectric filters, and hydrocarbon-fueled radiant tube burners. Most recently, we invented and demonstrated an antireflection (AR)-coated tungsten IR emitter which when integrated with the other key components should make TPV systems with efficiencies over 10% practical. However, the use of the AR tungsten emitter requires an oxygen-free hermetic seal enclosure. During a 2003 Small Business Innovative Research (SBIR) Phase I contract, we integrated a tungsten emitter foil and a commercial SiC radiant tube burner within an emitter thermos and successfully demonstrated its operation at high temperature. We also designed a complete stand alone 500 W TPV generator. During the upcoming SBIR Phase II, we plan to implement this design in hardware.

Monolithic optical phased-array transceiver in a standard SOI CMOS process.

PubMed

Abediasl, Hooman; Hashemi, Hossein

2015-03-09

Monolithic microwave phased arrays are turning mainstream in automotive radars and high-speed wireless communications fulfilling Gordon Moores 1965 prophecy to this effect. Optical phased arrays enable imaging, lidar, display, sensing, and holography. Advancements in fabrication technology has led to monolithic nanophotonic phased arrays, albeit without independent phase and amplitude control ability, integration with electronic circuitry, or including receive and transmit functions. We report the first monolithic optical phased array transceiver with independent control of amplitude and phase for each element using electronic circuitry that is tightly integrated with the nanophotonic components on one substrate using a commercial foundry CMOS SOI process. The 8 × 8 phased array chip includes thermo-optical tunable phase shifters and attenuators, nano-photonic antennas, and dedicated control electronics realized using CMOS transistors. The complex chip includes over 300 distinct optical components and over 74,000 distinct electrical components achieving the highest level of integration for any electronic-photonic system.

Inert gas narcosis has no influence on thermo-tactile sensation.

PubMed

Jakovljević, Miroljub; Vidmar, Gaj; Mekjavic, Igor B

2012-05-01

Contribution of skin thermal sensors under inert gas narcosis to the raising hypothermia is not known. Such information is vital for understanding the impact of narcosis on behavioural thermoregulation, diver safety and judgment of thermal (dis)comfort in the hyperbaric environment. So this study aimed at establishing the effects of normoxic concentration of 30% nitrous oxide (N(2)O) on thermo-tactile threshold sensation by studying 16 subjects [eight females and eight males; eight sensitive (S) and eight non-sensitive (NS) to N(2)O]. Their mean (SD) age was 22.1 (1.8) years, weight 72.8 (15.3) kg, height 1.75 (0.10) m and body mass index 23.8 (3.8) kg m(-2). Quantitative thermo-tactile sensory testing was performed on forearm, upper arm and thigh under two experimental conditions: breathing air (air trial) and breathing normoxic mixture of 30% N(2)O (N(2)O trial) in the mixed sequence. Difference in thermo-tactile sensitivity thresholds between two groups of subjects in two experimental conditions was analysed by 3-way mixed-model analysis of covariance. There were no statistically significant differences in thermo-tactile thresholds either between the Air and N(2)O trials, or between S and NS groups, or between females and males, or with respect to body mass index. Some clinically insignificant lowering of thermo-tactile thresholds occurred only for warm thermo-tactile thresholds on upper arm and thigh. The results indicated that normoxic mixture of 30% N(2)O had no influence on thermo-tactile sensation in normothermia.

Electroluminescence and cathodoluminescence from polyethylene and polypropylene films: Spectra reconstruction from elementary components and underlying mechanisms

DOE Office of Scientific and Technical Information (OSTI.GOV)

Qiao, B.; Teyssedre, G.; Laurent, C.

The mechanisms of electroluminescence from large band gap polymers used as insulation in electric components are still under debate. It becomes important to unravel the underlying physics of the emission because of increasing thermo-electric stress and a possible relationship between electroluminescence and field withstand. We report herein on the cathodoluminescence spectra of polyethylene and polypropylene films as a way to uncover the nature of its contributions to electroluminescence emission. It is shown that spectra from the two materials are structured around four elementary components, each of them being associated with a specific process contributing to the overall emission with differentmore » weights depending on excitation conditions and on materials. The cathodoluminescence and electroluminescence spectra of each material are reconstructed from the four spectral components and their relative contribution are discussed. It is shown that electroluminescence from polyethylene and polypropylene has the same origin pointing towards generic mechanisms in both.« less

Scaleable two-component gelator from phthalic acid derivatives and primary alkyl amines: acid-base interaction in the cooperative assembly.

PubMed

Su, Ting; Hong, Kwon Ho; Zhang, Wannian; Li, Fei; Li, Qiang; Yu, Fang; Luo, Genxiang; Gao, Honghe; He, Yu-Peng

2017-06-07

A series of phthalic acid derivatives (P) with a carbon-chain tail was designed and synthesized as single-component gelators. A combination of the single-component gelator P and a non-gelling additive n-alkylamine A through acid-base interaction brought about a series of novel phase-selective two-component gelators PA. The gelation capabilities of P and PA, and the structural, morphological, thermo-dynamic and rheological properties of the corresponding gels were investigated. A molecular dynamics simulation showed that the H-bonding network in PA formed between the NH of A and the carbonyl oxygen of P altered the assembly process of gelator P. Crude PA could be synthesized through a one-step process without any purification and could selectively gel the oil phase without a typical heating-cooling process. Moreover, such a crude PA and its gelation process could be amplified to the kilogram scale with high efficiency, which offers a practical economically viable solution to marine oil-spill recovery.

NASALife-Component Fatigue and Creep Life Prediction Program and Illustrative Examples

NASA Technical Reports Server (NTRS)

Murthy, Pappu L. N.; Mital, Subodh K.; Gyekenyesi, John Z.

2005-01-01

NASALife is a life prediction program for propulsion system components made of ceramic matrix composites (CMC) under cyclic thermo-mechanical loading and creep rupture conditions. Although, the primary focus was for CMC components the underlying methodologies are equally applicable to other material systems as well. The program references data for low cycle fatigue (LCF), creep rupture, and static material properties as part of the life prediction process. Multiaxial stresses are accommodated by Von Mises based methods and a Walker model is used to address mean stress effects. Varying loads are reduced by the Rainflow counting method. Lastly, damage due to cyclic loading (Miner s rule) and creep are combined to determine the total damage per mission and the number of missions the component can survive before failure are calculated. Illustration of code usage is provided through example problem of a CMC turbine stator vane made of melt-infiltrated, silicon carbide fiber-reinforced, silicon carbide matrix composite (MI SiC/SiC)

ThermoData Engine Database - Pure Compounds and Binary Mixtures

National Institute of Standards and Technology Data Gateway

SRD 103b NIST ThermoData Engine Version 6.0 - Pure CompoThermoData Engine Database - Pure Compounds and Binary Mixtures (PC database for purchase)   This database contains property data for more than 21,000 pure compounds, 37,500 binary mixtures, 10,000 ternary mixtures, and 6,000 chemical reactions.

Rheological properties of a biological thermo-responsive hydrogel produced from soybean oil polymers

USDA-ARS?s Scientific Manuscript database

The rheological properties of a newly developed biological thermo-hydrogel made from vegetable oil were investigated. The material named HPSO-HG is a hydrolytic product of polymerized soybean oil (PSO). HPSO-HG is a thermo-responsive gel, and it exhibited viscoelastic behavior above 2% (wt.%) at roo...

Physics of thermo-acoustic sound generation

NASA Astrophysics Data System (ADS)

Daschewski, M.; Boehm, R.; Prager, J.; Kreutzbruck, M.; Harrer, A.

2013-09-01

We present a generalized analytical model of thermo-acoustic sound generation based on the analysis of thermally induced energy density fluctuations and their propagation into the adjacent matter. The model provides exact analytical prediction of the sound pressure generated in fluids and solids; consequently, it can be applied to arbitrary thermal power sources such as thermophones, plasma firings, laser beams, and chemical reactions. Unlike existing approaches, our description also includes acoustic near-field effects and sound-field attenuation. Analytical results are compared with measurements of sound pressures generated by thermo-acoustic transducers in air for frequencies up to 1 MHz. The tested transducers consist of titanium and indium tin oxide coatings on quartz glass and polycarbonate substrates. The model reveals that thermo-acoustic efficiency increases linearly with the supplied thermal power and quadratically with thermal excitation frequency. Comparison of the efficiency of our thermo-acoustic transducers with those of piezoelectric-based airborne ultrasound transducers using impulse excitation showed comparable sound pressure values. The present results show that thermo-acoustic transducers can be applied as broadband, non-resonant, high-performance ultrasound sources.

Relation of Giant Thermo-EMF, Magnetothermo-EMF, Magnetoresistance, and Magnetization to Magnetic Impurity States in Manganites Nd(1- x)Sr x MnO3 and Sm(1- x)Sr x MnO3

NASA Astrophysics Data System (ADS)

Koroleva, L. I.; Batashev, I. K.; Morozov, A. S.; Balbashov, A. M.; Szymczak, H.; Slawska-Waniew, A.

2018-02-01

Thermo-EMF, magnetothermo-EMF, magnetoresistance, and magnetization of single-crystal samples of Nd(1- x)Sr x MnO3 and Sm(1- x)Sr x MnO3 with 0 ≤ x ≤ 0.3 have been studied experimentally. A sharp increase in the thermo-EMF and giant magnetothermo-EMF and magnetoresistance has been observed near the Curie point T C in compounds with 0.15 ≤ x ≤ 0.3. At the same time, no peculiarities have been found in compositions with x = 0. Since compounds with x > 0 consist of ferromagnetic clusters of the ferron type that reside in an antiferromagnetic A-type matrix, this means that the sharp increase in the thermo-EMF near T C is caused by ferrons. Indeed, the disappearance of ferrons due to a magnetic field or heating above T C leads to an abrupt decrease in the thermo-EMF. Therefore, thermo-EMF in alloyed magnetic semiconductors has been determined by the impurity concentration and the sample volume.

Thermo-chemotherapy Induced miR-218 upregulation inhibits the invasion of gastric cancer via targeting Gli2 and E-cadherin.

PubMed

Ruan, Qiang; Fang, Zhi-Yuan; Cui, Shu-Zhong; Zhang, Xiang-Liang; Wu, Yin-Bing; Tang, Hong-Sheng; Tu, Yi-Nuo; Ding, Yan

2015-08-01

Thermo-chemotherapy has been proven to reduce the invasion capability of cancer cells. However, the molecular mechanism underlying this anti-invasion effect is still unclear. In this study, the role of thermo-chemotherapy in the inhibition of tumor invasion was studied. The results demonstrated that expression of miR-218 was downregulated in gastric cancer tissues, which had a positive correlation with tumor invasion and metastasis. In vitro thermo-chemotherapy increased miR-218 expression in SGC7901 cells and inhibited both proliferation and invasion of cancer cells. Gli2 was identified as a downstream target of miR-218, and its expression was negatively regulated by miR-218. The thermo-chemotherapy induced miR-218 upregulation was also accompanied by increasing of E-cadherin expression. In conclusion, the present study indicates that thermo-chemotherapy can effectively decrease the invasion capability of cancer cells and increase cell-cell adhesion. miR-218 and its downstream target Gli2, as well as E-cadherin, participate in the anti-invasion process.

Anomalous aging of EPDM and FEPM under combined thermo-oxidative and hydrolytic conditions

DOE Office of Scientific and Technical Information (OSTI.GOV)

Redline, Erica M.; Celina, Mathias C.; Harris, Charles E.

Previous observation of EPDM and FEPM materials aged in thermo-oxidative and thermo-oxidative plus hydrolytic environments revealed an unusual trend: the degradation and disintegration of these polymers in the former case but the ability to maintain mechanical performance and shape in the latter. No abnormalities were observed in the chemical (oxidation rates, FTIR spectra, solvent uptake, gel content, and weight loss vs. temperature) or physical (modulus profile) measurements that could explain these empirically observed aging differences. A second controlled aging test was conducted to verify this trend using only EPDM. Once again it was shown that thermo-oxidative conditions appear to causemore » more degradative damage (enhanced embrittlement) than observed for the combined thermo-oxidative plus hydrolytic environments. From these data we conclude that water may favorably interfere with normal thermo-oxidative degradation processes. This interference may occur via some combination of chemical and physical property changes in the presence of steam such as: oxidation rate and O 2 permeability changes, additional sensitivity to hydrolytic damage, and/or mechanistic changes in relation to pH and hydroperoxide formation.« less

Anomalous aging of EPDM and FEPM under combined thermo-oxidative and hydrolytic conditions

DOE PAGES

Redline, Erica M.; Celina, Mathias C.; Harris, Charles E.; ...

2017-09-15

Previous observation of EPDM and FEPM materials aged in thermo-oxidative and thermo-oxidative plus hydrolytic environments revealed an unusual trend: the degradation and disintegration of these polymers in the former case but the ability to maintain mechanical performance and shape in the latter. No abnormalities were observed in the chemical (oxidation rates, FTIR spectra, solvent uptake, gel content, and weight loss vs. temperature) or physical (modulus profile) measurements that could explain these empirically observed aging differences. A second controlled aging test was conducted to verify this trend using only EPDM. Once again it was shown that thermo-oxidative conditions appear to causemore » more degradative damage (enhanced embrittlement) than observed for the combined thermo-oxidative plus hydrolytic environments. From these data we conclude that water may favorably interfere with normal thermo-oxidative degradation processes. This interference may occur via some combination of chemical and physical property changes in the presence of steam such as: oxidation rate and O 2 permeability changes, additional sensitivity to hydrolytic damage, and/or mechanistic changes in relation to pH and hydroperoxide formation.« less

Thermo-Plasmonics for Localized Graphitization and Welding of Polymeric Nanofibers

PubMed Central

Zillohu, Ahnaf Usman; Alissawi, Nisreen; Abdelaziz, Ramzy; Elbahri, Mady

2014-01-01

There is a growing interest in modulating the temperature under the illumination of light. As a heat source, metal nanoparticles (NPs) have played an important role to pave the way for a new branch of plasmonics, i.e., thermo-plasmonics. While thermo-plasmonics have been well established in photo-thermal therapy, it has received comparatively less attention in materials science and chemistry. Here, we demonstrate the first proof of concept experiment of local chemistry and graphitization of metalized polymeric nanofibers through thermo-plasmonic effect. In particular, by tuning the plasmonic absorption of the nanohybrid through a change in the thickness of the deposited silver film on the fibers, the thermo-plasmonic effect can be adjusted in such a way that high enough temperature is generated enabling local welding and graphitization of the polymeric nanofibers. PMID:28788459

Effects of thermo-resistant non-starch polysaccharide degrading multi-enzyme on growth performance, meat quality, relative weights of body organs and blood profile in broiler chickens.

PubMed

Mohammadi Gheisar, M; Hosseindoust, A; Kim, I H

2016-06-01

This research was conducted to study the performance and carcass parameters of broiler chickens fed diets supplemented with heat-treated non-starch polysaccharide degrading enzyme. A total of 432 one-day old Ross 308 broiler chickens were allocated to five treatments: (i) CON (basal diet), (ii) E1: CON + 0.05% multi-enzyme, (iii) E2: CON + 0.1% multi-enzyme, (iv) E3: CON + 0.05% thermo-resistant multi-enzyme and (v) E4: CON + 0.1% thermo-resistant multi-enzyme, each treatment consisted of six replications and 12 chickens in each replication. The chickens were housed in three floor battery cages during 28-day experimental period. On days 1-7, gain in body weight (BWG) improved by feeding the diets supplemented with thermo-resistant multi-enzyme. On days 7-21 and 1-28, chickens fed the diets containing thermo-resistant multi-enzyme showed improved (p < 0.05) BWG and feed conversion ratio (FCR) compared to CON group. Supplementing the diets with multi-enzyme or thermo-resistant multi-enzyme affected the percentage of drip loss on d 1 (p < 0.05). Drip loss percentage on days 3 and 5 and also meat colour were not affected significantly. Supplementing the diets with multi-enzyme or thermo-resistant multi-enzyme did not affect the relative weights of organs but compared to CON group, relative weight of breast muscle increased and abdominal fat decreased (p < 0.05). Among measured blood constituents, chickens fed supplemented diets with thermo-resistant multi-enzyme showed higher (p < 0.05) IgG. Counts of red and white blood cells and lymphocyte percentage were not affected. In conclusion, the results demonstrated that supplementing pelleted diets with thermo-resistant multi-enzyme improved performance of broiler chickens. Journal of Animal Physiology and Animal Nutrition © 2015 Blackwell Verlag GmbH.

Control and gating of kinesin-microtubule motility on electrically heated thermo-chips.

PubMed

Ramsey, Laurence; Schroeder, Viktor; van Zalinge, Harm; Berndt, Michael; Korten, Till; Diez, Stefan; Nicolau, Dan V

2014-06-01

First lab-on-chip devices based on active transport by biomolecular motors have been demonstrated for basic detection and sorting applications. However, to fully employ the advantages of such hybrid nanotechnology, versatile spatial and temporal control mechanisms are required. Using a thermo-responsive polymer, we demonstrated a temperature controlled gate that either allows or disallows the passing of microtubules through a topographically defined channel. The gate is addressed by a narrow gold wire, which acts as a local heating element. It is shown that the electrical current flowing through a narrow gold channel can control the local temperature and as a result the conformation of the polymer. This is the first demonstration of a spatially addressable gate for microtubule motility which is a key element of nanodevices based on biomolecular motors.

An experimental test plan for the characterization of molten salt thermochemical properties in heat transport systems

DOE Office of Scientific and Technical Information (OSTI.GOV)

Pattrick Calderoni

2010-09-01

Molten salts are considered within the Very High Temperature Reactor program as heat transfer media because of their intrinsically favorable thermo-physical properties at temperatures starting from 300 C and extending up to 1200 C. In this context two main applications of molten salt are considered, both involving fluoride-based materials: as primary coolants for a heterogeneous fuel reactor core and as secondary heat transport medium to a helium power cycle for electricity generation or other processing plants, such as hydrogen production. The reference design concept here considered is the Advanced High Temperature Reactor (AHTR), which is a large passively safe reactormore » that uses solid graphite-matrix coated-particle fuel (similar to that used in gas-cooled reactors) and a molten salt primary and secondary coolant with peak temperatures between 700 and 1000 C, depending upon the application. However, the considerations included in this report apply to any high temperature system employing fluoride salts as heat transfer fluid, including intermediate heat exchangers for gas-cooled reactor concepts and homogenous molten salt concepts, and extending also to fast reactors, accelerator-driven systems and fusion energy systems. The purpose of this report is to identify the technical issues related to the thermo-physical and thermo-chemical properties of the molten salts that would require experimental characterization in order to proceed with a credible design of heat transfer systems and their subsequent safety evaluation and licensing. In particular, the report outlines an experimental R&D test plan that would have to be incorporated as part of the design and operation of an engineering scaled facility aimed at validating molten salt heat transfer components, such as Intermediate Heat Exchangers. This report builds on a previous review of thermo-physical properties and thermo-chemical characteristics of candidate molten salt coolants that was generated as part of the same project [1]. However, this work focuses on two materials: the LiF-BeF2 eutectic (67 and 33 mol%, respectively, also known as flibe) as primary coolant and the LiF-NaF-KF eutectic (46.5, 11.5, and 52 mol%, respectively, also known as flinak) as secondary heat transport fluid. At first common issues are identified, involving the preparation and purification of the materials as well as the development of suitable diagnostics. Than issues specific to each material and its application are considered, with focus on the compatibility with structural materials and the extension of the existing properties database.« less

Recent developments in biocatalysis in multiphasic ionic liquid reaction systems.

PubMed

Meyer, Lars-Erik; von Langermann, Jan; Kragl, Udo

2018-06-01

Ionic liquids are well known and frequently used 'designer solvents' for biocatalytic reactions. This review highlights recent achievements in the field of multiphasic ionic liquid-based reaction concepts. It covers classical biphasic systems including supported ionic liquid phases, thermo-regulated multi-component solvent systems (TMS) and polymerized ionic liquids. These powerful concepts combine unique reaction conditions with a high potential for future applications on a laboratory and industrial scale. The presence of a multiphasic system simplifies downstream processing due to the distribution of the catalyst and reactants in different phases.

Hair waving natural product: Dillenia indica seed sap.

PubMed

Saikia, Jyoti Prasad

2013-02-01

Knowing keratin is the main component and mechanical strength of hair a study was performed to evaluate whether Dillenia indica seed sap can affect molecular strength of hair or not. In the present study the human hair collected from barber shop waste were subjected to purified sap for 12 h and then analysed using Fourier transform infrared spectroscopy (FTIR) for documenting evidence for keratin degradation. Further the deterioration was confirmed by thermo gravimetric analysis (TGA) and scanning electron microscopy (SEM). Copyright © 2012 Elsevier B.V. All rights reserved.

Influence of coupling on thermal forces and dynamic friction in plasmas with multiple ion species

NASA Astrophysics Data System (ADS)

Kagan, Grigory; Baalrud, Scott D.; Daligault, Jérôme

2017-07-01

The recently proposed effective potential theory [Phys. Rev. Lett. 110, 235001 (2013)] is used to investigate the influence of coupling on inter-ion-species diffusion and momentum exchange in multi-component plasmas. Thermo-diffusion and the thermal force are found to diminish rapidly as strong coupling onsets. For the same coupling parameters, the dynamic friction coefficient is found to tend to unity. These results provide an impetus for addressing the role of coupling on diffusive processes in inertial confinement fusion experiments.

Influence of coupling on thermal forces and dynamic friction in plasmas with multiple ion species

DOE PAGES

Kagan, Grigory; Baalrud, Scott D.; Daligault, Jérôme

2017-07-05

The recently proposed effective potential theory [Phys. Rev. Lett. 110, 235001 (2013)] is used to investigate the influence of coupling on inter-ion-species diffusion and momentum exchange in multi-component plasmas. Thermo-diffusion and the thermal force are found to diminish rapidly as strong coupling onsets. We found that for the same coupling parameters, the dynamic friction coefficient there tends to be unity. Our results provide an impetus for addressing the role of coupling on diffusive processes in inertial confinement fusion experiments.

Influence of coupling on thermal forces and dynamic friction in plasmas with multiple ion species

DOE Office of Scientific and Technical Information (OSTI.GOV)

Kagan, Grigory; Baalrud, Scott D.; Daligault, Jérôme

The recently proposed effective potential theory [Phys. Rev. Lett. 110, 235001 (2013)] is used to investigate the influence of coupling on inter-ion-species diffusion and momentum exchange in multi-component plasmas. Thermo-diffusion and the thermal force are found to diminish rapidly as strong coupling onsets. We found that for the same coupling parameters, the dynamic friction coefficient there tends to be unity. Our results provide an impetus for addressing the role of coupling on diffusive processes in inertial confinement fusion experiments.

The association of SNPs in Hsp90β gene 5' flanking region with thermo tolerance traits and tissue mRNA expression in two chicken breeds.

PubMed

Chen, Zhuo-Yu; Gan, Jian-Kang; Xiao, Xiong; Jiang, Li-Yan; Zhang, Xi-Quan; Luo, Qing-Bin

2013-09-01

Thermo stress induces heat shock proteins (HSPs) expression and HSP90 family is one of them that has been reported to involve in cellular protection against heat stress. But whether there is any association of genetic variation in the Hsp90β gene in chicken with thermo tolerance is still unknown. Direct sequencing was used to detect possible SNPs in Hsp90β gene 5' flanking region in 3 chicken breeds (n = 663). Six mutations, among which 2 SNPs were chosen and genotypes were analyzed with PCR-RFLP method, were found in Hsp90β gene in these 3 chicken breeds. Association analysis indicated that SNP of C.-141G>A in the 5' flanking region of the Hsp90β gene in chicken had some effect on thermo tolerance traits, which may be a potential molecular marker of thermo tolerance, and the genotype GG was the thermo tolerance genotype. Hsp90β gene mRNA expression in different tissues detected by quantitative real-time PCR assay were demonstrated to be tissue dependent, implying that different tissues have distinct sensibilities to thermo stress. Besides, it was shown time specific and varieties differences. The expression of Hsp90β mRNA in Lingshan chickens in some tissues including heart, liver, brain and spleen were significantly higher or lower than that of White Recessive Rock (WRR). In this study, we presume that these mutations could be used in marker assisted selection for anti-heat stress chickens in our breeding program, and WRR were vulnerable to tropical thermo stress whereas Lingshan chickens were well adapted.

Characterization of purified and xerogel immobilized novel lignin peroxidase produced from Trametes versicolor IBL-04 using solid state medium of corncobs.

PubMed

Asgher, Muhammad; Iqbal, Hafiz Muhammad Nasir; Irshad, Muhammad

2012-08-03

Cost-effective production of industrially important enzymes is a key for their successful exploitation on industrial scale. Keeping in view the extensive industrial applications of lignin peroxidase (LiP), this study was performed to purify and characterize the LiP from an indigenous strain of Trametes versicolor IBL-04. Xerogel matrix enzyme immobilization technique was applied to improve the kinetic and thermo-stability characteristics of LiP to fulfil the requirements of the modern enzyme consumer sector of biotechnology. A novel LiP was isolated from an indigenous T. versicolor IBL-04 strain. T. versicolor IBL-04 was cultured in solid state fermentation (SSF) medium of corn cobs and maximum LiP activity of 592 ± 6 U/mL was recorded after five days of incubation under optimum culture conditions. The crude LiP was 3.3-fold purified with specific activity of 553 U/mg after passing through the DEAE-cellulose and Sephadex-G-100 chromatography columns. The purified LiP exhibited a relatively low molecular weight (30 kDa) homogenous single band on native and SDS-PAGE. The LiP was immobilized by entrapping in xerogel matrix of trimethoxysilane (TMOS) and proplytetramethoxysilane (PTMS) and maximum immobilization efficiency of 88.6% was achieved. The free and immobilized LiPs were characterized and the results showed that the free and immobilized LiPs had optimum pH 6 and 5 while optimum temperatures were 60°C and 80°C, respectively. Immobilization was found to enhance the activity and thermo-stability potential of LiP significantly and immobilized LiP remained stable over broad pH and temperature range as compare to free enzyme. Kinetic constants K(m) and V(max) were 70 and 56 μM and 588 and 417 U/mg for the free and immobilized LiPs, respectively. Activity of this novel extra thermo-stable LiP was stimulated to variable extents by Cu(2+), Mn(2+) and Fe(2+) whereas, Cystein, EDTA and Ag(+) showed inhibitory effects. The indigenously isolated white rot fungal strain T. versicolor IBL-04 showed tremendous potential for LiP synthesis in SSF of corncobs in high titters (592 U/mL) than other reported Trametes (Coriolus, Polyporus) species. The results obtained after dual phase characterization suggested xerogel matrix entrapment a promising tool for enzyme immobilization, hyper-activation and stabilization against high temperature and inactivating agents. The pH and temperature optima, extra thermo-stability features and kinetic characteristics of this novel LiP of T. versicolor IBL-04 make it a versatile enzyme for various industrial and biotechnological applications.

Characterization of purified and Xerogel immobilized Novel Lignin Peroxidase produced from Trametes versicolor IBL-04 using solid state medium of Corncobs

PubMed Central

2012-01-01

Background Cost-effective production of industrially important enzymes is a key for their successful exploitation on industrial scale. Keeping in view the extensive industrial applications of lignin peroxidase (LiP), this study was performed to purify and characterize the LiP from an indigenous strain of Trametes versicolor IBL-04. Xerogel matrix enzyme immobilization technique was applied to improve the kinetic and thermo-stability characteristics of LiP to fulfil the requirements of the modern enzyme consumer sector of biotechnology. Results A novel LiP was isolated from an indigenous T. versicolor IBL-04 strain. T. versicolor IBL-04 was cultured in solid state fermentation (SSF) medium of corn cobs and maximum LiP activity of 592 ± 6 U/mL was recorded after five days of incubation under optimum culture conditions. The crude LiP was 3.3-fold purified with specific activity of 553 U/mg after passing through the DEAE-cellulose and Sephadex-G-100 chromatography columns. The purified LiP exhibited a relatively low molecular weight (30 kDa) homogenous single band on native and SDS-PAGE. The LiP was immobilized by entrapping in xerogel matrix of trimethoxysilane (TMOS) and proplytetramethoxysilane (PTMS) and maximum immobilization efficiency of 88.6% was achieved. The free and immobilized LiPs were characterized and the results showed that the free and immobilized LiPs had optimum pH 6 and 5 while optimum temperatures were 60°C and 80°C, respectively. Immobilization was found to enhance the activity and thermo-stability potential of LiP significantly and immobilized LiP remained stable over broad pH and temperature range as compare to free enzyme. Kinetic constants Km and Vmax were 70 and 56 μM and 588 and 417 U/mg for the free and immobilized LiPs, respectively. Activity of this novel extra thermo-stable LiP was stimulated to variable extents by Cu2+, Mn2+ and Fe2+ whereas, Cystein, EDTA and Ag+ showed inhibitory effects. Conclusions The indigenously isolated white rot fungal strain T. versicolor IBL-04 showed tremendous potential for LiP synthesis in SSF of corncobs in high titters (592 U/mL) than other reported Trametes (Coriolus, Polyporus) species. The results obtained after dual phase characterization suggested xerogel matrix entrapment a promising tool for enzyme immobilization, hyper-activation and stabilization against high temperature and inactivating agents. The pH and temperature optima, extra thermo-stability features and kinetic characteristics of this novel LiP of T. versicolor IBL-04 make it a versatile enzyme for various industrial and biotechnological applications. PMID:22862820

Data for effects of lanthanum complex on the thermo-oxidative aging of natural rubber.

PubMed

Zheng, Wei; Liu, Li; Zhao, Xiuying; He, Jingwei; Wang, Ao; Chan, Tung W; Wu, Sizhu

2015-12-01

Novel mixed antioxidants composed of antioxidant IPPD and lanthanum (La) complex were added as a filler to form natural rubber (NR) composites. By mechanical testing, Fourier transform infrared spectroscopy with attenuated total reflectance (FTIR-ATR) and thermogravimetric analysis (TGA), a string of data, including the mechanical properties, the variation of internal groups and the thermal and thermo-oxidative decompositions of NR, was presented in this data article. The data accompanying its research article [1] studied the thermo-oxidative aging properties of NR in detail. The density function theoretical (DFT) calculations were also used as an assistant to study the thermo-oxidative aging mechanism of NR. The data revealed that this new rare-earth antioxidant could indeed enhance the thermo-oxidative aging resistance of NR, which is associated with its different function mechanism from that of the pure antioxidant IPPD.

A novel graphene oxide-polyimide as optical waveguide material: Synthesis and thermo-optic switch properties

NASA Astrophysics Data System (ADS)

Cao, Tianlin; Zhao, Fanyu; Da, Zulin; Qiu, Fengxian; Yang, Dongya; Guan, Yijun; Cao, Guorong; Zhao, Zerun; Li, Jiaxin; Guo, Xiaotong

2016-10-01

In this work, a novel graphene oxide-polyimide (GOPI) as optical waveguide material was prepared. The structure, mechanical, thermal property and morphology of the GOPI was characterized by using fourier transform infrared, UV-visible spectroscopy, near-infrared spectrum, thermogravimetric analysis, differential scanning calorimetry, scanning electron microscope and transmission electron microscopy. The thermo-optic coefficients (dn/dT) are -9.16 × 10-4 (532 nm), -7.56 × 10-4 (650 nm) and -4.82 × 10-4 (850 nm) °C-1, respectively. Based on the thermo-optic effect of prepared GOPI as waveguide material, a Y-branch with branching angle of 0.143° and Mach-Zehnder thermo-optic switches were designed. Using finite difference beam propagation method (FD-BPM) method, the simulation results such as power consumptions and response times of two different thermo-optic switches were obtained.

Thermo-responsive gels that absorb moisture and ooze water.

PubMed

Matsumoto, Kazuya; Sakikawa, Nobuki; Miyata, Takashi

2018-06-13

The water content of thermo-responsive hydrogels can be drastically altered by small changes in temperature because their polymer chains change from hydrophilic to hydrophobic above their low critical solution temperature (LCST). In general, such smart hydrogels have been utilized in aqueous solutions or in their wet state, and no attempt has been made to determine the phase-transition behavior of the gels in their dried states. Here we demonstrate an application of the thermo-responsive behavior of an interpenetrating polymer network (IPN) gel comprising thermo-responsive poly(N-isopropylacrylamide) and hydrophilic sodium alginate networks in their dried states. The dried IPN gel absorbs considerable moisture from air at temperatures below its LCST and oozes the absorbed moisture as liquid water above its LCST. These phenomena provide energy exchange systems in which moisture from air can be condensed to liquid water using the controllable hydrophilic/hydrophobic properties of thermo-responsive gels with a small temperature change.

Data for effects of lanthanum complex on the thermo-oxidative aging of natural rubber

PubMed Central

Zheng, Wei; Liu, Li; Zhao, Xiuying; He, Jingwei; Wang, Ao; Chan, Tung W.; Wu, Sizhu

2015-01-01

Novel mixed antioxidants composed of antioxidant IPPD and lanthanum (La) complex were added as a filler to form natural rubber (NR) composites. By mechanical testing, Fourier transform infrared spectroscopy with attenuated total reflectance (FTIR-ATR) and thermogravimetric analysis (TGA), a string of data, including the mechanical properties, the variation of internal groups and the thermal and thermo-oxidative decompositions of NR, was presented in this data article. The data accompanying its research article [1] studied the thermo-oxidative aging properties of NR in detail. The density function theoretical (DFT) calculations were also used as an assistant to study the thermo-oxidative aging mechanism of NR. The data revealed that this new rare-earth antioxidant could indeed enhance the thermo-oxidative aging resistance of NR, which is associated with its different function mechanism from that of the pure antioxidant IPPD. PMID:26693513

Biopolyester-based systems containing naturally occurring compounds with enhanced thermo-oxidative stability.

PubMed

Arrigo, Rossella; Morici, Elisabetta; Dintcheva, Nadka Tzankova

2016-11-02

This work presents a sustainable approach for the stabilization of polylactic acid (PLA) against thermo-oxidative aging. Naturally occurring phenolic and polyphenolic compounds, such as ferulic acid (FerAc), vanillic acid (VanAc), quercetin (Querc) and vitamin E (VitE), were introduced into PLA. The preliminary characterization of the systems formulated containing different amounts of natural stabilizers showed that all compounds used acted as plasticizers, leading to a decrease in rheological functions with respect to neat PLA, without significantly modifying the crystallinity of the raw material. The study of the thermo-oxidative behavior of neat PLA and PLA/natural compound systems, performed by spectrometric and thermal analyses, indicated that all stabilizers considered were able to exert a remarkable antioxidant action against thermo-oxidative phenomena. All natural compounds considered are thus proposed as ecofriendly stabilizers, to get fully bio-based polymer systems with enhanced thermo-oxidative stability, suitable for biomedical applications.

A thermo-degradable hydrogel with light-tunable degradation and drug release.

PubMed

Hu, Jingjing; Chen, Yihua; Li, Yunqi; Zhou, Zhengjie; Cheng, Yiyun

2017-01-01

The development of thermo-degradable hydrogels is of great importance in drug delivery. However, it still remains a huge challenge to prepare thermo-degradable hydrogels with inherent degradation, reproducible, repeated and tunable dosing. Here, we reported a thermo-degradable hydrogel that is rapidly degraded above 44 °C by a facile chemistry. Besides thermo-degradability, the hydrogel also undergoes rapid photolysis with ultraviolet light. By embedding photothermal nanoparticles or upconversion nanoparticles into the gel, it can release the entrapped cargoes such as dyes, enzymes and anticancer drugs in an on-demand and dose-tunable fashion upon near-infrared light exposure. The smart hydrogel works well both in vitro and in vivo without involving sophisticated syntheses, and is well suited for clinical cancer therapy due to the high transparency and non-invasiveness features of near-infrared light. Copyright © 2016 Elsevier Ltd. All rights reserved.

Role of redox homeostasis in thermo-tolerance under a climate change scenario

PubMed Central

de Pinto, Maria Concetta; Locato, Vittoria; Paradiso, Annalisa; De Gara, Laura

2015-01-01

Background Climate change predictions indicate a progressive increase in average temperatures and an increase in the frequency of heatwaves, which will have a negative impact on crop productivity. Over the last decade, a number of studies have addressed the question of how model plants or specific crops modify their metabolism when exposed to heat stress. Scope This review provides an overview of the redox pathways that contribute to how plants cope with heat stress. The focus is on the role of reactive oxygen species (ROS), redox metabolites and enzymes in the signalling pathways leading to the activation of defence responses. Additional attention is paid to the regulating mechanisms that lead to an increase in specific ROS-scavenging systems during heat stress, which have been studied in different model systems. Finally, increasing thermo-tolerance in model and crop plants by exposing them to heat acclimation or to exogenous treatments is discussed. Conclusions Although there is clear evidence that several strategies are specifically activated according to the intensity and the duration of heat stress, as well as the capacity of the different species or genotypes to overcome stress, an alteration in redox homeostasis seems to be a common event. Different mechanisms that act to enhance redox systems enable crops to overcome heat stress more effectively. Knowledge of thermo-tolerance within agronomic biodiversity is thus of key importance to enable researchers to identify new strategies for overcoming the impacts of climate change, and for decision-makers in planning for an uncertain future with new choices and options open to them. PMID:26034009

Thermal Energy Harvesting on the Bodily Surfaces of Arms and Legs through a Wearable Thermo-Electric Generator.

PubMed

Proto, Antonino; Bibbo, Daniele; Cerny, Martin; Vala, David; Kasik, Vladimir; Peter, Lukas; Conforto, Silvia; Schmid, Maurizio; Penhaker, Marek

2018-06-13

This work analyzes the results of measurements on thermal energy harvesting through a wearable Thermo-electric Generator (TEG) placed on the arms and legs. Four large skin areas were chosen as locations for the placement of the TEGs. In order to place the generator on the body, a special manufactured band guaranteed the proper contact between the skin and TEG. Preliminary measurements were performed to find out the value of the resistor load which maximizes the power output. Then, an experimental investigation was conducted for the measurement of harvested energy while users were performing daily activities, such as sitting, walking, jogging, and riding a bike. The generated power values were in the range from 5 to 50 μW. Moreover, a preliminary hypothesis based on the obtained results indicates the possibility to use TEGs on leg for the recognition of locomotion activities. It is due to the rather high and different biomechanical work, produced by the gastrocnemius muscle, while the user is walking rather than jogging or riding a bike. This result reflects a difference between temperatures associated with the performance of different activities.

Use of asymptotic analysis of the large activation-energy limit to compare graphical methods of treating thermogravimetry data

Treesearch

A. Broido; F.A. Williams

1973-01-01

An earIier numerical analysis showed that the second approximate method of Horotitz and Metzger can be rendered exceedingly accurate for reduction of thermo-gravimetry data. It is demonstrated here that this result can be justified on the basis of an asymptotic expansion with a nondimensional activation energy as the large parameter. The order of magnitude of the error...

Performance evaluation of the active-flow personal DataRAM PM 2.5 mass monitor (Thermo Anderson pDR-1200) designed for continuous personal exposure measurements

NASA Astrophysics Data System (ADS)

Chakrabarti, Bhabesh; Fine, Philip M.; Delfino, Ralph; Sioutas, Constantinos

The need for continuous personal monitoring for exposure to particulate matter has been demonstrated by recent health studies showing effects of PM exposure on time scales of less than a few hours. Filter-based methods cannot measure this short-term variation of PM levels, which can be quite significant considering human activity patterns. The goal of this study was to evaluate the active-flow personal DataRAM for PM 2.5 (MIE pDR-1200; Thermo Electron Corp., Franklin, MA) designed as a wearable monitor to continuously measure particle exposure. The instrument precision was found to be good (2.1%) and significantly higher than the passive pDR configuration tested previously. A comparison to other proven continuous monitors resulted in good agreement at low relative humidities. Results at higher humidity followed predictable trends and provided a correction scheme that improved the accuracy of pDR readings. The pDR response to particle size also corresponded to previously observed and theoretical errors. The active flow feature of the pDR allows collection of the sampled particles on a back-up filter. The 24-h mass measured on this filter was found to compare very well with a Federal Reference Method for PM 2.5 mass.

High-efficiency Agrobacterium rhizogenes-mediated transformation of heat inducible sHSP18.2-GUS in Nicotiana tabacum.

PubMed

Chen, Shih-Cheng; Liu, Hui-Wen; Lee, Kung-Ta; Yamakawa, Takashi

2007-01-01

The chimerical gene, Arabidopsis thaliana sHSP18.2 promoter fused to E. coli gusA gene, was Agrobacterium rhizogenes-mediated transformed into Nicotiana tabacum as a heat-regulatable model, and the thermo-inducible expression of GUS activity in N. tabacum transgenic hairy roots was profiled. An activation of A. rhizogenes with acetosyringone (AS) before cocultured with tobacco's leaf disc strongly promoted transgenic hairy roots formation. Transgenic hairy roots formation efficiency of A. rhizogenes precultured with 200 microM AS supplementation was 3.1-fold and 7.5-fold, respectively, compared to the formation efficiency obtained with and without AS supplementation in coculture. Transgenic hairy roots transformed with different AS concentration exhibited a similar pattern of thermo-inducibility after 10 min to 3 h heat treatments detected by GUS expression. The peak of expressed GUS specific activity, 399,530 pmol MUG per mg total protein per min, of the transgenic hairy roots was observed at 48 h after 3 h of 42 degrees C heat treatment, and the expressed GUS specific activity was 7-26 times more than that reported in A. thaliana, tobacco BY-2 cells and Nicotiana plumbaginifolia. Interference caused by AS supplementation on the growth of transgenic hairy roots, time-course of GUS expression and its expression level were not observed.

A Comparison of Predictive Thermo and Water Solvation Property Prediction Tools and Experimental Data for Selected Traditional Chemical Warfare Agents and Simulants II: COSMO RS and COSMOTherm

DTIC Science & Technology

2017-04-01

A COMPARISON OF PREDICTIVE THERMO AND WATER SOLVATION PROPERTY PREDICTION TOOLS AND EXPERIMENTAL DATA FOR...4. TITLE AND SUBTITLE A Comparison of Predictive Thermo and Water Solvation Property Prediction Tools and Experimental Data for Selected...1  2.  EXPERIMENTAL PROCEDURE

A resonance-free nano-film airborne ultrasound emitter

NASA Astrophysics Data System (ADS)

Daschewski, Maxim; Harrer, Andrea; Prager, Jens; Kreutzbruck, Marc; Beck, Uwe; Lange, Thorid; Weise, Matthias

2013-01-01

In this contribution we present a novel thermo-acoustic approach for the generation of broad band airborne ultrasound and investigate the applicability of resonance-free thermo-acoustic emitters for very short high pressure airborne ultrasound pulses. We report on measurements of thermo-acoustic emitter consisting of a 30 nm thin metallic film on a usual soda-lime glass substrate, generating sound pressure values of more than 140 dB at 60 mm distance from the transducer and compare the results with conventional piezoelectric airborne ultrasound transducers. Our experimental investigations show that such thermo-acoustic devices can be used as broad band emitters using pulse excitation.

Thermoelastic Damping in FGM Nano-Electromechanical System in Axial Vibration Based on Eringen Nonlocal Theory

NASA Astrophysics Data System (ADS)

Rahimi, Z.; Rashahmadi, S.

2017-11-01

The thermo-elastic damping is a dominant source of internal damping in micro-electromechanical systems (MEMS) and nano-electromechanical systems (NEMS). The internal damping cannot neither be controlled nor minimized unless either mechanical or geometrical properties are changed. Therefore, a novel FGMNEM system with a controllable thermo-elastic damping of axial vibration based on Eringen nonlocal theory is considered. The effects of different parameter like the gradient index, nonlocal parameter, length of nanobeam and ambient temperature on the thermo-elastic damping quality factor are presented. It is shown that the thermo-elastic damping can be controlled by changing different parameter.

Thermo-mechanical design and testing of a microbalance for space applications

NASA Astrophysics Data System (ADS)

Scaccabarozzi, Diego; Saggin, Bortolino; Tarabini, Marco; Palomba, Ernesto; Longobardo, Andrea; Zampetti, Emiliano

2014-12-01

This work focuses on the thermo-mechanical design of the microbalance used for the VISTA (Volatile In Situ Thermogravimetry Analyzer) sensor. VISTA has been designed to operate in situ in different space environments (asteroids, Mars, icy satellites). In this paper we focus on its application on Mars, where the expected environmental conditions are the most challenging for the thermo-mechanical design. The microbalance holding system has been designed to ensure piezoelectric crystal integrity against the high vibration levels during launch and landing and to cope with the unavoidable thermo-elastic differential displacements due to CTE and temperature differences between the microbalance elements. The crystal holding system, based on three symmetrical titanium supports, provides also the electrical connections needed for crystal actuation, microbalance heating and temperature measurement on the electrode area. On the microbalance crystal surfaces the electrodes, a micro film heater (optimized to perform thermo-gravimetric analysis up to 400 °C) and a resistive thermometer are deposited through a vacuum sputtering process. A mockup of the system has been manufactured and tested at the expected vibration levels and the thermal control effectiveness has been verified in thermo-vacuum environment.

Enhanced Thermo-Optical Switching of Paraffin-Wax Composite Spots under Laser Heating

PubMed Central

Said, Asmaa; Salah, Abeer; Abdel Fattah, Gamal

2017-01-01

Thermo-optical switches are of particular significance in communications networks where increasingly high switching speeds are required. Phase change materials (PCMs), in particular those based on paraffin wax, provide wealth of exciting applications with unusual thermally-induced switching properties, only limited by paraffin’s rather low thermal conductivity. In this paper, the use of different carbon fillers as thermal conductivity enhancers for paraffin has been investigated, and a novel structure based on spot of paraffin wax as a thermo-optic switch is presented. Thermo-optical switching parameters are enhanced with the addition of graphite and graphene, due to the extreme thermal conductivity of the carbon fillers. Differential Scanning Calorimetry (DSC) and Scanning electron microscope (SEM) are performed on paraffin wax composites, and specific heat capacities are calculated based on DSC measurements. Thermo-optical switching based on transmission is measured as a function of the host concentration under conventional electric heating and laser heating of paraffin-carbon fillers composites. Further enhancements in thermo-optical switching parameters are studied under Nd:YAG laser heating. This novel structure can be used in future networks with huge bandwidth requirements and electric noise free remote aerial laser switching applications. PMID:28772884

Enhanced Thermo-Optical Switching of Paraffin-Wax Composite Spots under Laser Heating.

PubMed

Said, Asmaa; Salah, Abeer; Fattah, Gamal Abdel

2017-05-12

Thermo-optical switches are of particular significance in communications networks where increasingly high switching speeds are required. Phase change materials (PCMs), in particular those based on paraffin wax, provide wealth of exciting applications with unusual thermally-induced switching properties, only limited by paraffin's rather low thermal conductivity. In this paper, the use of different carbon fillers as thermal conductivity enhancers for paraffin has been investigated, and a novel structure based on spot of paraffin wax as a thermo-optic switch is presented. Thermo-optical switching parameters are enhanced with the addition of graphite and graphene, due to the extreme thermal conductivity of the carbon fillers. Differential Scanning Calorimetry (DSC) and Scanning electron microscope (SEM) are performed on paraffin wax composites, and specific heat capacities are calculated based on DSC measurements. Thermo-optical switching based on transmission is measured as a function of the host concentration under conventional electric heating and laser heating of paraffin-carbon fillers composites. Further enhancements in thermo-optical switching parameters are studied under Nd:YAG laser heating. This novel structure can be used in future networks with huge bandwidth requirements and electric noise free remote aerial laser switching applications.

Statistical analysis of low level atmospheric turbulence

NASA Technical Reports Server (NTRS)

Tieleman, H. W.; Chen, W. W. L.

1974-01-01

The statistical properties of low-level wind-turbulence data were obtained with the model 1080 total vector anemometer and the model 1296 dual split-film anemometer, both manufactured by Thermo Systems Incorporated. The data obtained from the above fast-response probes were compared with the results obtained from a pair of Gill propeller anemometers. The digitized time series representing the three velocity components and the temperature were each divided into a number of blocks, the length of which depended on the lowest frequency of interest and also on the storage capacity of the available computer. A moving-average and differencing high-pass filter was used to remove the trend and the low frequency components in the time series. The calculated results for each of the anemometers used are represented in graphical or tabulated form.

Optimisation and characterisation of tungsten thick coatings on copper based alloy substrates

NASA Astrophysics Data System (ADS)

Riccardi, B.; Montanari, R.; Casadei, M.; Costanza, G.; Filacchioni, G.; Moriani, A.

2006-06-01

Tungsten is a promising armour material for plasma facing components of nuclear fusion reactors because of its low sputter rate and favourable thermo-mechanical properties. Among all the techniques able to realise W armours, plasma spray looks particularly attractive owing to its simplicity and low cost. The present work concerns the optimisation of spraying parameters aimed at 4-5 mm thick W coating on copper-chromium-zirconium (Cu,Cr,Zr) alloy substrates. Characterisation of coatings was performed in order to assess microstructure, impurity content, density, tensile strength, adhesion strength, thermal conductivity and thermal expansion coefficient. The work performed has demonstrated the feasibility of thick W coatings on flat and curved geometries. These coatings appear as a reliable armour for medium heat flux plasma facing component.

Thermo-responsive methylcellulose hydrogels as temporary substrate for cell sheet biofabrication.

PubMed

Altomare, Lina; Cochis, Andrea; Carletta, Andrea; Rimondini, Lia; Farè, Silvia

2016-05-01

Methylcellulose (MC), a water-soluble polymer derived from cellulose, was investigated as a possible temporary substrate having thermo-responsive properties favorable for cell culturing. MC-based hydrogels were prepared by a dispersion technique, mixing MC powder (2, 4, 6, 8, 10, 12 % w/v) with selected salts (sodium sulphate, Na2SO4), sodium phosphate, calcium chloride, or phosphate buffered saline, to evaluate the influence of different compositions on the thermo-responsive behavior. The inversion test was used to determine the gelation temperatures of the different hydrogel compositions; thermo-mechanical properties and thermo-reversibility of the MC hydrogels were investigated by rheological analysis. Gelation temperatures and rheological behavior depended on the MC concentration and type and concentration of salt used in hydrogel preparation. In vitro cytotoxicity tests, performed using L929 mouse fibroblasts, showed no toxic release from all the tested hydrogels. Among the investigated compositions, the hydrogel composed of 8 % w/v MC with 0.05 M Na2SO4 had a thermo-reversibility temperature at 37 °C. For that reason, this formulation was thus considered to verify the possibility of inducing in vitro spontaneous detachment of cells previously seeded on the hydrogel surface. A continuous cell layer (cell sheet) was allowed to grow and then detached from the hydrogel surface without the use of enzymes, thanks to the thermo-responsive behavior of the MC hydrogel. Immunofluorescence observation confirmed that the detached cell sheet was composed of closely interacting cells.

Ceramic Composite Development for Gas Turbine Engine Hot Section Components

NASA Technical Reports Server (NTRS)

DiCarlo, James A.; VANrOODE, mARK

2006-01-01

The development of ceramic materials for incorporation into the hot section of gas turbine engines has been ongoing for about fifty years. Researchers have designed, developed, and tested ceramic gas turbine components in rigs and engines for automotive, aero-propulsion, industrial, and utility power applications. Today, primarily because of materials limitations and/or economic factors, major challenges still remain for the implementation of ceramic components in gas turbines. For example, because of low fracture toughness, monolithic ceramics continue to suffer from the risk of failure due to unknown extrinsic damage events during engine service. On the other hand, ceramic matrix composites (CMC) with their ability to display much higher damage tolerance appear to be the materials of choice for current and future engine components. The objective of this paper is to briefly review the design and property status of CMC materials for implementation within the combustor and turbine sections for gas turbine engine applications. It is shown that although CMC systems have advanced significantly in thermo-structural performance within recent years, certain challenges still exist in terms of producibility, design, and affordability for commercial CMC turbine components. Nevertheless, there exist some recent successful efforts for prototype CMC components within different engine types.

Etude par elements finis du comportement thermo-chimiomecanique de la pâte monolithique

NASA Astrophysics Data System (ADS)

Girard, Pierre-Luc

Aluminum industry is in a fierce international competition requiring the constant improvement of the electrolysis cell effectiveness and longevity. The selection of the cell's materials components becomes an important factor to increase the cell's life. The ramming paste, used to seal the cathode lining, is compacted in the joints between the cathode and the side wall of the cell. It is a complex thermo-chemo-reactive material whose proprieties change with the evolution of his baking level. Therefore, the objective of this project is to propose a thermo-chemo-mechanical constitutive law for the ramming paste and implement it in the finite element software ANSYSRTM. A constitutive model was first chosen from the available literature on the subject. It is a pressure dependent model that uses hardening, softening and baking mechanisms in its definition to mimic the behavior of carbon-based materials. Subsequently, the numerical tool was validated using the finite element toolbox FESh++, which contains the most representative carbon-based thermochimio- mechanical material constitutive law at this time. Finally, a validation of the experimental setup BERTA (Banc d'essai de resistance thermomecanique ALCAN) was made in prevision of a larger scale experimental validation of the constitutive law in a near future. However, the analysis of the results shows that BERTA is not suited to adequately measure the mechanical deformation of such kind of material. Following this project, the numerical tool will be used in numerical simulation to introduce the various effects of the baking of the ramming paste during the cell startup. This new tool will help the industrial partner to enhance the understanding of Hall-Heroult cell start-up and optimize this critical step.

Bioreactor mechanically guided 3D mesenchymal stem cell chondrogenesis using a biocompatible novel thermo-reversible methylcellulose-based hydrogel.

PubMed

Cochis, A; Grad, S; Stoddart, M J; Farè, S; Altomare, L; Azzimonti, B; Alini, M; Rimondini, L

2017-03-23

Autologous chondrocyte implantation for cartilage repair represents a challenge because strongly limited by chondrocytes' poor expansion capacity in vitro. Mesenchymal stem cells (MSCs) can differentiate into chondrocytes, while mechanical loading has been proposed as alternative strategy to induce chondrogenesis excluding the use of exogenous factors. Moreover, MSC supporting material selection is fundamental to allow for an active interaction with cells. Here, we tested a novel thermo-reversible hydrogel composed of 8% w/v methylcellulose (MC) in a 0.05 M Na 2 SO 4 solution. MC hydrogel was obtained by dispersion technique and its thermo-reversibility, mechanical properties, degradation and swelling were investigated, demonstrating a solution-gelation transition between 34 and 37 °C and a low bulk degradation (<20%) after 1 month. The lack of any hydrogel-derived immunoreaction was demonstrated in vivo by mice subcutaneous implantation. To induce in vitro chondrogenesis, MSCs were seeded into MC solution retained within a porous polyurethane (PU) matrix. PU-MC composites were subjected to a combination of compression and shear forces for 21 days in a custom made bioreactor. Mechanical stimulation led to a significant increase in chondrogenic gene expression, while histological analysis detected sulphated glycosaminoglycans and collagen II only in loaded specimens, confirming MC hydrogel suitability to support load induced MSCs chondrogenesis.

Thermo-reversible supramolecular hydrogels of trehalose-type diblock methylcellulose analogues.

PubMed

Yamagami, Mao; Kamitakahara, Hiroshi; Yoshinaga, Arata; Takano, Toshiyuki

2018-03-01

This paper describes the design and synthesis of new trehalose-type diblock methylcellulose analogues with nonionic, cationic, and anionic cellobiosyl segments, namely 1-(tri-O-methyl-cellulosyl)-4-[β-d-glucopyranosyl-(1→4)-β-d-glucopyranosyloxymethyl]-1H-1,2,3-triazole (1), 1-(tri-O-methyl-cellulosyl)-4-[(6-amino-6-deoxy-β-d-glucopyranosyl)-(1→4)- 6-amino-6-deoxy-β-d-glucopyranosyloxymethyl]-1H-1,2,3-triazole (2), and 4-(tri-O-methyl-cellulosyloxymethyl)-1-[β-d-glucopyranuronosyl-(1→4)-β-d-glucopyranuronosyl]-1H-1,2,3-triazole (3), respectively. Aqueous solutions of all of the 1,2,3-triazole-linked diblock methylcellulose analogues possessed higher surface activities than that of industrially produced methylcellulose and exhibited lower critical solution temperatures, that allowed the formation of thermoresponsive supramolecular hydrogels at close to human body temperature. Supramolecular structures of thermo-reversible hydrogels based on compounds 1, 2, and 3 were investigated by means of scanning electron microscopy (SEM) and transmission electron microscopy (TEM). Detailed structure-property-function relationships of compounds 1, 2, and 3 were discussed. Not only nonionic hydrophilic segment but also ionic hydrophilic segments of diblock methylcellulose analogues were valid for the formation of thermo-reversible supramolecular hydrogels based on end-functionalized methylcellulose. Copyright © 2017 Elsevier Ltd. All rights reserved.

Making the Most of Waste Energy

NASA Technical Reports Server (NTRS)

2005-01-01

The Thermo-Mechanical Systems Branch at NASA s Glenn Research Center is responsible for planning and conducting research efforts to advance thermal systems for space, aerospace, and non-aerospace applications. Technological areas pertain to solar and thermal energy conversion. For example, thermo-mechanical systems researchers work with gas (Stirling) and liquid/vapor (Rankine) systems that convert thermal energy to electrical power, as well as solar dynamic power systems that concentrate sunlight to electrical power. The branch s development of new solar and thermal energy technologies is propelling NASA s missions deep into unfamiliar territories of space. Solar dynamic power systems are actively improving the health of orbiting satellites, giving them longer life and a stronger radiation tolerance, thus, creating less need for on-orbit maintenance. For future missions, NASA may probe even deeper into the mysterious cosmos, with the adoption of highly efficient thermal energy converters that have the potential to serve as the source of onboard electrical power for satellites and spacecraft. Research indicates that these thermal converters can deliver up to 5 times as much power as radioisotope thermoelectric generators in use today, for the same amount of radioisotope. On Earth, energy-converting technologies associated with NASA s Thermo-Mechanical Systems Branch are being used to recover and transform low-temperature waste heat into usable electric power, with a helping hand from NASA.

Spontaneous combustion of hydrogen

NASA Technical Reports Server (NTRS)

Nusselt, Wilhelm; Pothmann, PH

1923-01-01

It is shown by the author's experiments that hydrogen which escapes to the atmosphere through openings in the system may burn spontaneously if it contains dust. Purely thermal reasoning can not account for the combustion. It seems to be rather an electrical ignition. In order to determine whether the cause of the spontaneous ignition was thermo-chemical, thermo-mechanical, or thermo-electrical, the experiments in this paper were performed.

An improved thermo-time domain reflectometry method for determination of ice contents in partially frozen soils

NASA Astrophysics Data System (ADS)

Tian, Zhengchao; Ren, Tusheng; Kojima, Yuki; Lu, Yili; Horton, Robert; Heitman, Joshua L.

2017-12-01

Measuring ice contents (θi) in partially frozen soils is important for both engineering and environmental applications. Thermo-time domain reflectometry (thermo-TDR) probes can be used to determine θi based on the relationship between θi and soil heat capacity (C). This approach, however, is accurate in partially frozen soils only at temperatures below -5 °C, and it performs poorly on clayey soils. In this study, we present and evaluate a soil thermal conductivity (λ)-based approach to determine θi with thermo-TDR probes. Bulk soil λ is described with a simplified de Vries model that relates λ to θi. From this model, θi is estimated using inverse modeling of thermo-TDR measured λ. Soil bulk density (ρb) and thermo-TDR measured liquid water content (θl) are also needed for both C-based and λ-based approaches. A theoretical analysis is performed to quantify the sensitivity of C-based and λ-based θi estimates to errors in these input parameters. The analysis indicates that the λ-based approach is less sensitive to errors in the inputs (C, λ, θl, and ρb) than is the C-based approach when the same or the same percentage errors occur. Further evaluations of the C-based and λ-based approaches are made using experimentally determined θi at different temperatures on eight soils with various textures, total water contents, and ρb. The results show that the λ-based thermo-TDR approach significantly improves the accuracy of θi measurements at temperatures ≤-5 °C. The root mean square errors of λ-based θi estimates are only half those of C-based θi. At temperatures of -1 and -2 °C, the λ-based thermo-TDR approach also provides reasonable θi, while the C-based approach fails. We conclude that the λ-based thermo-TDR method can reliably determine θi even at temperatures near the freezing point of water (0 °C).

Thermo-mechanical behavior of power electronic packaging assemblies: From characterization to predictive simulation of lifetimes

NASA Astrophysics Data System (ADS)

Dalverny, O.; Alexis, J.

2018-02-01

This article deals with thermo-mechanical behavior of power electronic modules used in several transportation applications as railway, aeronautic or automotive systems. Due to a multi-layered structures, involving different materials with a large variation of coefficient of thermal expansion, temperature variations originated from active or passive cycling (respectively from die dissipation or environmental constraint) induces strain and stresses field variations, giving fatigue phenomenon of the system. The analysis of the behavior of these systems and their dimensioning require the implementation of complex modeling strategies by both the multi-physical and the multi-scale character of the power modules. In this paper we present some solutions for studying the thermomechanical behavior of brazed assemblies as well as taking into account the interfaces represented by the numerous metallizations involved in the process assembly.

Methodology of investigation of ultra high temperature ceramics thermochemical stability and catalycity

NASA Astrophysics Data System (ADS)

Vaganov, A. V.; Zhestkov, B. E.; Lyamin, Yu. B.; Poilov, V. Z.; Pryamilova, E. N.

2016-10-01

The 12 ceramics samples of Ural Research Institute of Composite Materials were investigated in the wind tunnel VAT-104 of TsAGI in air plasma flow which simulated the hypervelocity flight. Model used were discs and blunted cones. All samples had withstood the tests without decomposition, the sample temperature and test time being respectively up to 2800 K and 1200 seconds. It was found there is a big delay in heating of the samples, thought they are of great thermo conductivity. A very interesting phenomenon, the formation of highly catalytic thermo barrier film on the front surface of sample, was also observed. It was a formation of this film that coursed a jump of 500-1000 K of surface temperature during the test. The sample catalytic activity was evaluated using modernized methodology based upon parametrical numerical simulation.

Irreversible temperature gating in trpv1 sheds light on channel activation

PubMed Central

Sánchez-Moreno, Ana; Guevara-Hernández, Eduardo; Contreras-Cervera, Ricardo; Rangel-Yescas, Gisela; Ladrón-de-Guevara, Ernesto; Rosenbaum, Tamara

2018-01-01

Temperature-activated TRP channels or thermoTRPs are among the only proteins that can directly convert temperature changes into changes in channel open probability. In spite of a wealth of functional and structural information, the mechanism of temperature activation remains unknown. We have carefully characterized the repeated activation of TRPV1 by thermal stimuli and discovered a previously unknown inactivation process, which is irreversible. We propose that this form of gating in TRPV1 channels is a consequence of the heat absorption process that leads to channel opening. PMID:29869983

Thick SS316 materials TIG welding development activities towards advanced fusion reactor vacuum vessel applications

NASA Astrophysics Data System (ADS)

Kumar, B. Ramesh; Gangradey, R.

2012-11-01

Advanced fusion reactors like ITER and up coming Indian DEMO devices are having challenges in terms of their materials design and fabrication procedures. The operation of these devices is having various loads like structural, thermo-mechanical and neutron irradiation effects on major systems like vacuum vessel, divertor, magnets and blanket modules. The concept of double wall vacuum vessel (VV) is proposed in view of protecting of major reactor subsystems like super conducting magnets, diagnostic systems and other critical components from high energy 14 MeV neutrons generated from fusion plasma produced by D-T reactions. The double walled vacuum vessel is used in combination with pressurized water circulation and some special grade borated steel blocks to shield these high energy neutrons effectively. The fabrication of sub components in VV are mainly used with high thickness SS materials in range of 20 mm- 60 mm of various grades based on the required protocols. The structural components of double wall vacuum vessel uses various parts like shields, ribs, shells and diagnostic vacuum ports. These components are to be developed with various welding techniques like TIG welding, Narrow gap TIG welding, Laser welding, Hybrid TIG laser welding, Electron beam welding based on requirement. In the present paper the samples of 20 mm and 40 mm thick SS 316 materials are developed with TIG welding process and their mechanical properties characterization with Tensile, Bend tests and Impact tests are carried out. In addition Vickers hardness tests and microstructural properties of Base metal, Heat Affected Zone (HAZ) and Weld Zone are done. TIG welding application with high thick SS materials in connection with vacuum vessel requirements and involved criticalities towards welding process are highlighted.

Mechanisms Underpinning Degradation of Protective Oxides and Thermal Barrier Coatings in High Hydrogen Content (HHC) - Fueled Turbines

DOE Office of Scientific and Technical Information (OSTI.GOV)

Mumm, Daniel

2013-08-31

The overarching goal of this research program has been to evaluate the potential impacts of coal-derived syngas and high-hydrogen content fuels on the degradation of turbine hot-section components through attack of protective oxides and thermal barrier coatings. The primary focus of this research program has been to explore mechanisms underpinning the observed degradation processes, and connections to the combustion environments and characteristic non-combustible constituents. Based on the mechanistic understanding of how these emerging fuel streams affect materials degradation, the ultimate goal of the program is to advance the goals of the Advanced Turbine Program by developing materials design protocols leadingmore » to turbine hot-section components with improved resistance to service lifetime degradation under advanced fuels exposures. This research program has been focused on studying how: (1) differing combustion environments – relative to traditional natural gas fired systems – affect both the growth rate of thermally grown oxide (TGO) layers and the stability of these oxides and of protective thermal barrier coatings (TBCs); and (2) how low levels of fuel impurities and characteristic non-combustibles interact with surface oxides, for instance through the development of molten deposits that lead to hot corrosion of protective TBC coatings. The overall program has been comprised of six inter-related themes, each comprising a research thrust over the program period, including: (i) evaluating the role of syngas and high hydrogen content (HHC) combustion environments in modifying component surface temperatures, heat transfer to the TBC coatings, and thermal gradients within these coatings; (ii) understanding the instability of TBC coatings in the syngas and high hydrogen environment with regards to decomposition, phase changes and sintering; (iii) characterizing ash deposition, molten phase development and infiltration, and associated corrosive/thermo-chemical attack mechanisms; (iv) developing a mechanics-based analysis of the driving forces for crack growth and delamination, based on molten phase infiltration, misfit upon cooling, and loss of compliance; (v) understanding changes in TGO growth mechanisms associated with these emerging combustion product streams; and (vi) identifying degradation resistant alternative materials (including new compositions or bi-layer concepts) for use in mitigating the observed degradation modes. To address the materials stability concerns, this program integrated research thrusts aimed at: (1) Conducting tests in simulated syngas and HHC environments to evaluate materials evolution and degradation mechanisms; assessing thermally grown oxide development unique to HHC environmental exposures; carrying out high-resolution imaging and microanalysis to elucidate the evolution of surface deposits (molten phase formation and infiltration); exploring thermo-chemical instabilities; assessing thermo-mechanical drivers and thermal gradient effects on degradation; and quantitatively measuring stress evolution due to enhanced sintering and thermo-chemical instabilities induced in the coating. (2) Executing experiments to study the melting and infiltration of simulated ash deposits, and identifying reaction products and evolving phases associated with molten phase corrosion mechanisms; utilizing thermal spray techniques to fabricate test coupons with controlled microstructures to study mechanisms of instability and degradation; facilitating thermal gradient testing; and developing new materials systems for laboratory testing; (3) Correlating information on the resulting combustion environments to properly assess materials exposure conditions and guide the development of lab-scale simulations of material exposures; specification of representative syngas and high-hydrogen fuels with realistic levels of impurities and contaminants, to explore differences in heat transfer, surface degradation, and deposit formation; and facilitating combustion rig testing of materials test coupons.« less

Enhancement of the thermo-optical response of silver nanoparticles due to surface plasmon resonance

NASA Astrophysics Data System (ADS)

Hashemi Zadeh, Sakineh; Rashidi-Huyeh, Majid; Palpant, Bruno

2017-10-01

Owing to their remarkable optical properties, noble metals' nanoparticles are proposed for many applications. Controlling the temperature dependence of these properties may then appear to be of great relevance. In this paper, we investigate the thermo-optical properties of silver nanoparticles. Different silver nanocolloids were prepared with different surface plasmon resonance modes. The thermo-extinction spectra of the colloidal solutions were then evaluated by measuring the extinction spectra at different temperatures. This reveals a typical peak-valley profile around each surface plasmon resonance mode. Mie theory was used to study theoretically the impact of nanoparticle size on the thermo-optical properties. The results allow us to interpret properly the experimental findings.

Polybenzimidazoles Via Aromatic Nucleophilic Displacement

NASA Technical Reports Server (NTRS)

Connell, John W.; Hergenrother, Paul M.; Smith, Joseph G.

1994-01-01

Soluble polybenzimidazoles (PBI's) synthesized by nucleophilic displacement reaction of di(hydroxyphenyl)-benzimidazole monomers with activated aromatic difluoride compounds in presence of anhydrous potassium carbonate. These polymers exhibit good thermal, thermo-oxidative, and chemical stability, and high mechanical properties. Using benzimidazole monomers, more economical, and new PBI's processed more easily than commercial PBI, without loss of desirable physical properties.

High energy flux thermo-mechanical test of 1D-carbon-carbon fibre composite prototypes for the SPIDER diagnostic calorimeter

DOE Office of Scientific and Technical Information (OSTI.GOV)

De Muri, M., E-mail: michela.demuri@igi.cnr.it; Pasqualotto, R.; Dalla Palma, M.

2014-02-15

Operation of the thermonuclear fusion experiment ITER requires additional heating via injection of neutral beams from accelerated negative ions. In the SPIDER test facility, under construction in Padova, the production of negative ions will be studied and optimised. STRIKE (Short-Time Retractable Instrumented Kalorimeter Experiment) is a diagnostic used to characterise the SPIDER beam during short pulse operation (several seconds) to verify if the beam meets the ITER requirements about the maximum allowed beam non-uniformity (below ±10%). The major components of STRIKE are 16 1D-CFC (Carbon-Carbon Fibre Composite) tiles, observed at the rear side by a thermal camera. This contribution givesmore » an overview of some tests under high energy particle flux, aimed at verifying the thermo-mechanical behaviour of several CFC prototype tiles. The tests were performed in the GLADIS facility at IPP (Max-Plank-Institut für Plasmaphysik), Garching. Dedicated linear and nonlinear simulations were carried out to interpret the experiments and a comparison of the experimental data with the simulation results is presented. The results of some morphological and structural studies on the material after exposure to the GLADIS beam are also given.« less

Thermo-electric analysis of the interconnection of the LHC main superconducting bus bars

NASA Astrophysics Data System (ADS)

Granieri, P. P.; Breschi, M.; Casali, M.; Bottura, L.; Siemko, A.

2013-01-01

Spurred by the question of the maximum allowable energy for the operation of the Large Hadron Collider (LHC), we have progressed in the understanding of the thermo-electric behavior of the 13 kA superconducting bus bars interconnecting its main magnets. A deep insight of the underlying mechanisms is required to ensure the protection of the accelerator against undesired effects of resistive transitions. This is especially important in case of defective interconnections which can jeopardize the operation of the whole LHC. In this paper we present a numerical model of the interconnections between the main dipole and quadrupole magnets, validated against experimental tests of an interconnection sample with a purposely built-in defect. We consider defective interconnections featuring a lack of bonding among the superconducting cables and the copper stabilizer components, such as those that could be present in the machine. We evaluate the critical defect length limiting the maximum allowable current for powering the magnets. We determine the dependence of the critical defect length on different parameters as the heat transfer towards the cooling helium bath, the quality of manufacturing, the operating conditions and the protection system parameters, and discuss the relevant mechanisms.

Thermo-acousto-photonics for noncontact temperature measurement in silicon wafer processing

NASA Astrophysics Data System (ADS)

Suh, Chii-Der S.; Rabroker, G. Andrew; Chona, Ravinder; Burger, Christian P.

1999-10-01

A non-contact thermometry technique has been developed to characterize the thermal state of silicon wafers during rapid thermal processing. Information on thermal variations is obtained from the dispersion relations of the propagating waveguide mode excited in wafers using a non-contact, broadband optical system referred to as Thermal Acousto- Photonics for Non-Destructive Evaluation. Variations of thermo-mechanical properties in silicon wafers are correlated to temperature changes by performing simultaneous time-frequency analyses on Lamb waveforms acquired with a fiber-tip interferometer sensor. Experimental Lamb wave data collected for cases ranging from room temperature to 400 degrees C is presented. The results show that the temporal progressions of all spectral elements found in the fundamental antisymmetric mode are strong functions of temperature. This particular attribute is exploited to achieve a thermal resolution superior to the +/- 5 degrees C attainable through current pyrometric techniques. By analyzing the temperature-dependent group velocity of a specific frequency component over the temperature range considered and then comparing the results to an analytical model developed for silicon wafers undergoing annealing, excellent agreement was obtained. Presented results demonstrate the feasibility of applying laser-induced stress waves as a temperature diagnostic during rapid thermal processing.

A facile construction of Au nanoparticles stabilized by thermo-responsive polymer-tethered carbon dots for enhanced catalytic performance

NASA Astrophysics Data System (ADS)

Li, Li; Zhang, Tianyi; Lü, Jianhua; Lü, Changli

2018-10-01

Carbon dots (CDs), the youngest member in the carbon nanomaterial family, have drawn considerable attention due to their interesting optical, physicochemical and electronic properties as well as broad promising applications. Here, we developed a facile and effective strategy for the preparation of Au nanoparticles stabilized by thermo-responsive poly(N-isopropylacrylamide) (PNIPAM) functionalized carbon dots (Au@CD@P) under the gentle water media. The as-designed dopamine(DA)-terminated PNIPAM can be easily anchored to CDs via mussel-inspired chemistry route. Both CD@P and CDs could well stabilize the Au nanoparticles with interesting assembled structure. The as-prepared Au@CD and Au@CD@P nanohybrids with good dispersibility and stability exhibited the intriguing catalytic activity for reduction of p-nitrophenol (p-NP). Especially, Au@CD@P as catalyst also played a switching role in regulating the catalytic rate by temperature. In addition, Au@CD@P exhibited excellent recyclability which may have potential in green chemical industry for developing high-activity catalysts and easy production methods.

Thermo-activated nano-material for use in optical devices

NASA Astrophysics Data System (ADS)

Mias, Solon; Sudor, Jan; Camon, Henri

2007-05-01

In this paper we describe the use of thermo-activated PNIPAM nano-material in optical switching devices. In other publications, the PNIPAM is used either as a carrier for crystalline colloidal array self-assemblies or as micro-particles that serve as pigment bags. In this publication we use a simpler-to-fabricate pure PNIPAM solution in a semi-dilute regime. The PNIPAM devices produced are transparent at temperatures below a critical temperature of 32°C and become diffusing above this temperature. We show that at 632nm the transmission through the devices is about 75% in the transparent state while the additional attenuation achieved in the diffusing state is of the order of 38 dB. The experimental fall and rise times obtained are large (about 300ms and 5s respectively) due to the non-optimised thermal addressing scheme. In addition, spectral measurements taken in the infrared spectrum (700-1000nm) demonstrate that the cell response is flat over a large portion of the infrared spectrum in both the transparent and the diffusing states.

Influence of thermo-mechanical treatment in ferritic phase field on microstructure and mechanical properties of reduced activation ferritic-martensitic steel

NASA Astrophysics Data System (ADS)

Prakash; Vanaja, J.; Laha, K.; Nageswara Rao, G. V. S.

2018-03-01

The present study focuses on the evaluation of microstructure and mechanical properties of reduced activation ferritic-martensitic (RAFM) steel (9Cr-1W-0.06Ta) subjected to thermo-mechanical treatment (TMT) in ferritic phase field. The results obtained were compared with the steel in conventional normalised plus tempered (N+T) condition. The microstructure of the steel in N+T and TMT conditions was assessed by optical and scanning electron microscopes. Hardness, tensile and creep studies were carried out and the results were correlated with the microstructural studies. While the TMT processed steel resulted in coarser prior austenite grains and exhibited ferritic microstructure with large distribution of fine M23C6 and MX precipitates, the N+T steel reveals tempered martensitic structure with finer prior austenitic grains with coarser M23C6 and MX precipitates. Although ferritic structure is present in TMT processed steel, it exhibits better tensile and creep rupture strengths than N+T steel due to the presence of increased dislocation density and finer distribution of precipitates.

Thermo-responsive magnetic liposomes for hyperthermia-triggered local drug delivery.

PubMed

Dai, Min; Wu, Cong; Fang, Hong-Ming; Li, Li; Yan, Jia-Bao; Zeng, Dan-Lin; Zou, Tao

2017-06-01

We prepared and characterised thermo-responsive magnetic liposomes, which were designed to combine features of magnetic targeting and thermo-responsive control release for hyperthermia-triggered local drug delivery. The particle size and zeta-potential of the thermo-responsive magnetic ammonium bicarbonate (MagABC) liposomes were about 210 nm and -14 mV, respectively. The MagABC liposomes showed encapsulation efficiencies of about 15% and 82% for magnetic nanoparticles (mean crystallite size 12 nm) and doxorubicin (DOX), respectively. The morphology of the MagABC liposomes was visualised using transmission electron microscope (TEM). The MagABC liposomes showed desired thermo-responsive release. The MagABC liposomes, when physically targeted to tumour cells in culture by a permanent magnetic field yielded a substantial increase in intracellular accumulation of DOX as compared to non-magnetic ammonium bicarbonate (ABC) liposomes. This resulted in a parallel increase in cytotoxicity for DOX loaded MagABC liposomes over DOX loaded ABC liposomes in tumour cells.

Understanding Fast and Robust Thermo-osmotic Flows through Carbon Nanotube Membranes: Thermodynamics Meets Hydrodynamics.

PubMed

Fu, Li; Merabia, Samy; Joly, Laurent

2018-04-19

Following our recent theoretical prediction of the giant thermo-osmotic response of the water-graphene interface, we explore the practical implementation of waste heat harvesting with carbon-based membranes, focusing on model membranes of carbon nanotubes (CNT). To that aim, we combine molecular dynamics simulations and an analytical model considering the details of hydrodynamics in the membrane and at the tube entrances. The analytical model and the simulation results match quantitatively, highlighting the need to take into account both thermodynamics and hydrodynamics to predict thermo-osmotic flows through membranes. We show that, despite viscous entrance effects and a thermal short-circuit mechanism, CNT membranes can generate very fast thermo-osmotic flows, which can overcome the osmotic pressure of seawater. We then show that in small tubes confinement has a complex effect on the flow and can even reverse the flow direction. Beyond CNT membranes, our analytical model can guide the search for other membranes to generate fast and robust thermo-osmotic flows.

Effect of Nb2O5 doping on improving the thermo-mechanical stability of sealing interfaces for solid oxide fuel cells.

PubMed

Zhang, Qi; Du, Xinhang; Tan, Shengwei; Tang, Dian; Chen, Kongfa; Zhang, Teng

2017-07-13

Nb 2 O 5 is added to a borosilicate sealing system to improve the thermo-mechanical stability of the sealing interface between the glass and Fe-Cr metallic interconnect (Crofer 22APU) in solid oxide fuel cells (SOFCs). The thermo-mechanical stability of the glass/metal interface is evaluated experimentally as well as by using a finite element analysis (FEA) method. The sealing glass doped with 4 mol.% Nb 2 O 5 shows the best thermo-mechanical stability, and the sealing couple of Crofer 22APU/glass/GDC (Gd 0.2 Ce 0.8 O 1.9 ) remains intact after 50 thermal cycles. In addition, all sealing couples show good joining after being held at 750 °C for 1000 h. Moreover, the possible mechanism on the thermo-mechanical stability of sealing interface is investigated in terms of stress-based and energy-based perspectives.

Investigating the effect of mutation on the thermo stability of GB1 protein

NASA Astrophysics Data System (ADS)

Sawitri, K. N.; Sumaryada, T.; Ambarsari, L.; Wahyudi, S. T.

2018-04-01

The thermo stability of wild-type and mutants of the B1 domain of Protein G (GB1 protein) have been studied using molecular dynamics simulation and free energy perturbation simulation. This research is aimed to examine what residue or what interaction that has a major role in the thermo stability of GB1 protein thermo stability by using the point mutation method. Based on the analysis, the unfolding of wild-type protein occurred in 500 K simulation at 704 ps. The mutations were chosen based on the changes in some analysis parameters and the calculated net solvation free energy change. It was found that a simple replacement of a positively charged residue in the β-sheet (K4S) decreases the stability of GB1 protein (unfolding at 452 ps), while the replacement of a negatively charged residue in the α-helix (E27G) increases the stability (unfolding at 846 ps). It was also found that the K4A mutation will break the α-helix and all β-sheet into the coil and turn. All those results suggest that the non-bonded interaction has the major role in the thermo stability of GB1 protein with the β-sheets were identified as the most important structure in the thermo stability of GB1 protein..

Phylogenetic and Comparative Sequence Analysis of Thermostable Alpha Amylases of kingdom Archea, Prokaryotes and Eukaryotes.

PubMed

Huma, Tayyaba; Maryam, Arooma; Rehman, Shahid Ur; Qamar, Muhammad Tahir Ul; Shaheen, Tayyaba; Haque, Asma; Shaheen, Bushra

2014-01-01

Alpha amylase family is generally defined as a group of enzymes that can hydrolyse and transglycosylase α-(1, 4) or α-(1, 6) glycosidic bonds along with the preservation of anomeric configuration. For the comparative analysis of alpha amylase family, nucleotide sequences of seven thermo stable organisms of Kingdom Archea i.e. Pyrococcus furiosus (100-105°C), Kingdom Prokaryotes i.e. Bacillus licheniformis (90-95°C), Geobacillus stearothermophilus (75°C), Bacillus amyloliquefaciens (72°C), Bacillus subtilis (70°C) and Bacillus KSM K38 (55°C) and Eukaryotes i.e. Aspergillus oryzae (60°C) were selected from NCBI. Primary structure composition analysis and Conserved sequence analysis were conducted through Bio Edit tools. Results from BioEdit shown only three conserved regions of base pairs and least similarity in MSA of the above mentioned alpha amylases. In Mega 5.1 Phylogeny of thermo stable alpha amylases of Kingdom Archea, Prokaryotes and Eukaryote was handled by Neighbor-Joining (NJ) algorithm. Mega 5.1 phylogenetic results suggested that alpha amylases of thermo stable organisms i.e. Pyrococcus furiosus (100-105°C), Bacillus licheniformis (90-95°C), Geobacillus stearothermophilus (75°C) and Bacillus amyloliquefaciens (72°C) are more distantly related as compared to less thermo stable organisms. By keeping in mind the characteristics of most thermo stable alpha amylases novel and improved features can be introduced in less thermo stable alpha amylases so that they become more thermo tolerant and productive for industry.

A geometrical multi-scale numerical method for coupled hygro-thermo-mechanical problems in photovoltaic laminates.

PubMed

Lenarda, P; Paggi, M

A comprehensive computational framework based on the finite element method for the simulation of coupled hygro-thermo-mechanical problems in photovoltaic laminates is herein proposed. While the thermo-mechanical problem takes place in the three-dimensional space of the laminate, moisture diffusion occurs in a two-dimensional domain represented by the polymeric layers and by the vertical channel cracks in the solar cells. Therefore, a geometrical multi-scale solution strategy is pursued by solving the partial differential equations governing heat transfer and thermo-elasticity in the three-dimensional space, and the partial differential equation for moisture diffusion in the two dimensional domains. By exploiting a staggered scheme, the thermo-mechanical problem is solved first via a fully implicit solution scheme in space and time, with a specific treatment of the polymeric layers as zero-thickness interfaces whose constitutive response is governed by a novel thermo-visco-elastic cohesive zone model based on fractional calculus. Temperature and relative displacements along the domains where moisture diffusion takes place are then projected to the finite element model of diffusion, coupled with the thermo-mechanical problem by the temperature and crack opening dependent diffusion coefficient. The application of the proposed method to photovoltaic modules pinpoints two important physical aspects: (i) moisture diffusion in humidity freeze tests with a temperature dependent diffusivity is a much slower process than in the case of a constant diffusion coefficient; (ii) channel cracks through Silicon solar cells significantly enhance moisture diffusion and electric degradation, as confirmed by experimental tests.

Objective and subjective measures of exercise intensity during thermo-neutral and hot yoga.

PubMed

Boyd, Corinne N; Lannan, Stephanie M; Zuhl, Micah N; Mora-Rodriguez, Ricardo; Nelson, Rachael K

2018-04-01

While hot yoga has gained enormous popularity in recent years, owing in part to increased environmental challenge associated with exercise in the heat, it is not clear whether hot yoga is more vigorous than thermo-neutral yoga. Therefore, the aim of this study was to determine objective and subjective measures of exercise intensity during constant intensity yoga in a hot and thermo-neutral environment. Using a randomized, crossover design, 14 participants completed 2 identical ∼20-min yoga sessions in a hot (35.3 ± 0.8 °C; humidity: 20.5% ± 1.4%) and thermo-neutral (22.1 ± 0.2 °C; humidity: 27.8% ± 1.6%) environment. Oxygen consumption and heart rate (HR) were recorded as objective measures (percentage of maximal oxygen consumption and percentage of maximal HR (%HRmax)) and rating of perceived exertion (RPE) was recorded as a subjective measure of exercise intensity. There was no difference in exercise intensity based on percentage of maximal oxygen consumption during hot versus thermo-neutral yoga (30.9% ± 2.3% vs. 30.5% ± 1.8%, p = 0.68). However, exercise intensity was significantly higher during hot versus thermo-neutral yoga based on %HRmax (67.0% ± 2.3% vs. 60.8% ± 1.9%, p = 0.01) and RPE (12 ± 1 vs. 11 ± 1, p = 0.04). According to established exercise intensities, hot yoga was classified as light-intensity exercise based on percentage of maximal oxygen consumption but moderate-intensity exercise based on %HRmax and RPE while thermo-neutral yoga was classified as light-intensity exercise based on percentage of maximal oxygen uptake, %HRmax, and RPE. Despite the added hemodynamic stress and perception that yoga is more strenuous in a hot environment, we observed similar oxygen consumption during hot versus thermo-neutral yoga, classifying both exercise modalities as light-intensity exercise.

Thermo-kinetic analysis space expansion for cyclophilin-ligand interactions - identification of a new nonpeptide inhibitor using Biacore™ T200.

PubMed

Wear, Martin A; Nowicki, Matthew W; Blackburn, Elizabeth A; McNae, Iain W; Walkinshaw, Malcolm D

2017-04-01

We have established a refined methodology for generating surface plasmon resonance sensor surfaces of recombinant his-tagged human cyclophilin-A. Our orientation-specific stabilisation approach captures his-tagged protein under 'physiological conditions' (150 mm NaCl, pH 7.5) and covalently stabilises it on Ni 2+ -nitrilotriacetic acid surfaces, very briefly activated for primary amine-coupling reactions, producing very stable and active surfaces (≥ 95% specific activity) of cyclophilin-A. Variation in protein concentration with the same contact time allows straightforward generation of variable density surfaces, with essentially no loss of activity, making the protocol easily adaptable for studying numerous interactions; from very small fragments, ~ 100 Da, to large protein ligands. This new method results in an increased stability and activity of the immobilised protein and allowed us to expand the thermo-kinetic analysis space, and to determine accurate and robust thermodynamic parameters for the cyclophilin-A-cyclosporin-A interaction. Furthermore, the increased sensitivity of the surface allowed identification of a new nonpeptide inhibitor of cyclophilin-A, from a screen of a fragment library. This fragment, 2,3-diaminopyridine, bound specifically with a mean affinity of 248 ± 60 μm. The X-ray structure of this 109-Da fragment bound in the active site of cyclophilin-A was solved to a resolution of 1.25 Å (PDB: 5LUD), providing new insight into the molecular details for a potential new series of nonpeptide cyclophilin-A inhibitors.

GaN-on-diamond electronic device reliability: Mechanical and thermo-mechanical integrity

NASA Astrophysics Data System (ADS)

Liu, Dong; Sun, Huarui; Pomeroy, James W.; Francis, Daniel; Faili, Firooz; Twitchen, Daniel J.; Kuball, Martin

2015-12-01

The mechanical and thermo-mechanical integrity of GaN-on-diamond wafers used for ultra-high power microwave electronic devices was studied using a micro-pillar based in situ mechanical testing approach combined with an optical investigation of the stress and heat transfer across interfaces. We find the GaN/diamond interface to be thermo-mechanically stable, illustrating the potential for this material for reliable GaN electronic devices.

Transient Phenomena in Multiphase and Multicomponent Systems: Research Report

NASA Astrophysics Data System (ADS)

Zur Beurteilung von Stoffen in der Landwirtschaft, Senatskommission

2000-09-01

Due to the reinforced risk and safety-analysis of industrial plants in chemical and energy-engineering there has been increased demand in industry for more information on thermo- and fluiddynamic effects of non-equilibria during strong transients. Therefore, the 'Deutsche Forschungsgemeinschaft' initiated a special research program focusing on the study of transient phenomena in multiphase systems with one or several components. This book describes macroscopic as well as microscopic transient situations. A large part of the book deals with numerical methods for describing transients in two-phase mixtures. New developments in measuring techniques are also presented.

Optical design of athermal, multispectral, radial GRIN lenses

NASA Astrophysics Data System (ADS)

Boyd, Andrew M.

2017-05-01

Military infrared systems generally must exhibit stable optical performance over a wide operating temperature range. We present a model for the first-order optical design of radial gradient-index systems, based on a form of the thermo-optic glass coefficient adapted to inhomogeneous material combinations. We find that GRIN components can significantly reduce the optical power balance of athermal, achromatic systems, which introduces the scope for a new class of broadband infrared imaging solutions. This novel first-order modelling technique is used to generate a starting point for optimisation of a SWIR/LWIR multispectral optical design.

Intelligent Life-Extending Controls for Aircraft Engines

NASA Technical Reports Server (NTRS)

Guo, Ten-Huei; Chen, Philip; Jaw, Link

2005-01-01

Aircraft engine controllers are designed and operated to provide desired performance and stability margins. The purpose of life-extending-control (LEC) is to study the relationship between control action and engine component life usage, and to design an intelligent control algorithm to provide proper trade-offs between performance and engine life usage. The benefit of this approach is that it is expected to maintain safety while minimizing the overall operating costs. With the advances of computer technology, engine operation models, and damage physics, it is necessary to reevaluate the control strategy fro overall operating cost consideration. This paper uses the thermo-mechanical fatigue (TMF) of a critical component to demonstrate how an intelligent engine control algorithm can drastically reduce the engine life usage with minimum sacrifice in performance. A Monte Carlo simulation is also performed to evaluate the likely engine damage accumulation under various operating conditions. The simulation results show that an optimized acceleration schedule can provide a significant life saving in selected engine components.

Improved activity and thermo-stability of the horse radish peroxidase with graphene quantum dots and its application in fluorometric detection of hydrogen peroxide

NASA Astrophysics Data System (ADS)

Xiaoyan, Zhou; Yuanyuan, Jiang; Zaijun, Li; Zhiguo, Gu; Guangli, Wang

2016-08-01

Graphene quantum dots (GQDs) have received extensive concern in many fields such as optical probe, bioimaging and biosensor. However, few reports refer on the influence of GQDs on enzyme performance. The paper reports two kinds of graphene quantum dots (termed as GO-GQDs and N,S-GQDs) that were prepared by cutting of graphene oxide and pyrolysis of citric acid and L-cysteine, and their use for the horse radish peroxidase (HRP) modification. The study reveals that GO-GQDs and N,S-GQDs exhibit an opposite effect on the HRP performance. Only HRP modified with GO-GQDs offers an enhanced activity (more than 1.9 times of pristine enzyme) and thermo-stability. This is because GO-GQDs offer a larger conjugate rigid plane and fewer hydrophilic groups compared to N,S-GQDs. The characteristics can make GO-GQDs induce a proper conformational change in the HRP for the catalytic performance, improving the enzyme activity and thermo-stability. The HRP modified with green luminescent GO-GQDs was also employed as a biocatalyst for sensing of H2O2 by a fluorometric sensor. The colorless tetramethylbenzidine (TMB) is oxidized into blue oxidized TMB in the presence of H2O2 by the assistance of HRP/GO-GQDs, leading to an obvious fluorescence quenching. The fluorescence intensity linearly decreases with the increase of H2O2 concentration in the range from 2 × 10 - 9 to 2 × 10 - 4 M with the detection limit of 6.8 × 10 - 10 M. The analytical method provides the advantage of sensitivity, stability and accuracy compared with present H2O2 sensors based on the pristine HRP. It has been successfully applied in the determination of H2O2 in real water samples. The study also opens a new avenue for modification of enzyme activity and stability that offers great promise in applications such as biological catalysis, biosensing and enzyme engineering.

Thermo-Magneto-Electric Generator Arrays for Active Heat Recovery System

PubMed Central

Chun, Jinsung; Song, Hyun-Cheol; Kang, Min-Gyu; Kang, Han Byul; Kishore, Ravi Anant; Priya, Shashank

2017-01-01

Continued emphasis on development of thermal cooling systems is being placed that can cycle low grade heat. Examples include solar powered unmanned aerial vehicles (UAVs) and data storage servers. The power efficiency of solar module degrades at elevated temperature, thereby, necessitating the need for heat extraction system. Similarly, data centres in wireless computing system are facing increasing efficiency challenges due to high power consumption associated with managing the waste heat. We provide breakthrough in addressing these problems by developing thermo-magneto-electric generator (TMEG) arrays, composed of soft magnet and piezoelectric polyvinylidene difluoride (PVDF) cantilever. TMEG can serve dual role of extracting the waste heat and converting it into useable electricity. Near room temperature second-order magnetic phase transition in soft magnetic material, gadolinium, was employed to obtain mechanical vibrations on the PVDF cantilever under small thermal gradient. TMEGs were shown to achieve high vibration frequency at small temperature gradients, thereby, demonstrating effective heat transfer. PMID:28145516

Direct Coupling of Thermo- and Photocatalysis for Conversion of CO2 -H2 O into Fuels.

PubMed

Zhang, Li; Kong, Guoguo; Meng, Yaping; Tian, Jinshu; Zhang, Lijie; Wan, Shaolong; Lin, Jingdong; Wang, Yong

2017-12-08

Photocatalytic CO 2 reduction into renewable hydrocarbon solar fuels is considered as a promising strategy to simultaneously address global energy and environmental issues. This study focused on the direct coupling of photocatalytic water splitting and thermocatalytic hydrogenation of CO 2 in the conversion of CO 2 -H 2 O into fuels. Specifically, it was found that direct coupling of thermo- and photocatalysis over Au-Ru/TiO 2 leads to activity 15 times higher (T=358 K; ca. 99 % CH 4 selectivity) in the conversion of CO 2 -H 2 O into fuels than that of photocatalytic water splitting. This is ascribed to the promoting effect of thermocatalytic hydrogenation of CO 2 by hydrogen atoms generated in situ by photocatalytic water splitting. © 2017 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.

Thermo-Optical and Mechanical Property Testing of Candidate Solar Sail Materials

NASA Technical Reports Server (NTRS)

Hollerman, WIlliam A.; Stanaland, T. L.; Womack, F.; Edwards, David; Hubbs, Whitney; Semmel, Charles

2003-01-01

Solar sailing is a unique form of propulsion where a spacecraft gains momentum from incident photons. Since sails are not limited by reaction mass, they provide continual acceleration, reduced only by the lifetime of the lightweight film in the space environment and the distance to the Sun. Practical solar sails can expand the number of possible missions, enabling new concepts that are difficult by conventional means. The National Aeronautics and Space Administration's Marshall Space Flight Center (MSFC) is concentrating research into the utilization of ultra-lightweight materials for spacecraft propulsion. Solar sails are generally composed of a highly reflective metallic front layer, a thin polymeric substrate, and occasionally a highly emissive back surface. The Space Environmental Effects Team at MSFC is actively characterizing candidate sails to evaluate the thermo-optical and mechanical properties after exposure to electrons. This poster will discuss the preliminary results of this research.

Thermo-Magneto-Electric Generator Arrays for Active Heat Recovery System.

PubMed

Chun, Jinsung; Song, Hyun-Cheol; Kang, Min-Gyu; Kang, Han Byul; Kishore, Ravi Anant; Priya, Shashank

2017-02-01

Continued emphasis on development of thermal cooling systems is being placed that can cycle low grade heat. Examples include solar powered unmanned aerial vehicles (UAVs) and data storage servers. The power efficiency of solar module degrades at elevated temperature, thereby, necessitating the need for heat extraction system. Similarly, data centres in wireless computing system are facing increasing efficiency challenges due to high power consumption associated with managing the waste heat. We provide breakthrough in addressing these problems by developing thermo-magneto-electric generator (TMEG) arrays, composed of soft magnet and piezoelectric polyvinylidene difluoride (PVDF) cantilever. TMEG can serve dual role of extracting the waste heat and converting it into useable electricity. Near room temperature second-order magnetic phase transition in soft magnetic material, gadolinium, was employed to obtain mechanical vibrations on the PVDF cantilever under small thermal gradient. TMEGs were shown to achieve high vibration frequency at small temperature gradients, thereby, demonstrating effective heat transfer.

Thermo-sensitive liposomes loaded with doxorubicin and lysine modified single-walled carbon nanotubes as tumor-targeting drug delivery system.

PubMed

Zhu, Xiali; Xie, Yingxia; Zhang, Yingjie; Huang, Heqing; Huang, Shengnan; Hou, Lin; Zhang, Huijuan; Li, Zhi; Shi, Jinjin; Zhang, Zhenzhong

2014-11-01

This report focuses on the thermo-sensitive liposomes loaded with doxorubicin and lysine-modified single-walled carbon nanotube drug delivery system, which was designed to enhance the anti-tumor effect and reduce the side effects of doxorubicin. Doxorubicin-lysine/single-walled carbon nanotube-thermo-sensitive liposomes was prepared by reverse-phase evaporation method, the mean particle size was 232.0 ± 5.6 nm, and drug entrapment efficiency was 86.5 ± 3.7%. The drug release test showed that doxorubicin released more quickly at 42℃ than at 37℃. Compared with free doxorubicin, doxorubicin-lysine/single-walled carbon nanotube-thermo-sensitive liposomes could efficiently cross the cell membranes and afford higher anti-tumor efficacy on the human hepatic carcinoma cell line (SMMC-7721) cells in vitro. For in vivo experiments, the relative tumor volumes of the sarcomaia 180-bearing mice in thermo-sensitive liposomes group and doxorubicin group were significantly smaller than those of N.S. group. Meanwhile, the combination of near-infrared laser irradiation at 808 nm significantly enhanced the tumor growth inhibition both on SMMC-7721 cells and the sarcomaia 180-bearing mice. The quality of life such as body weight, mental state, food and water intake of sarcomaia 180 tumor-bearing mice treated with doxorubicin-lysine/single-walled carbon nanotube-thermo-sensitive liposomes were much higher than those treated with doxorubicin. In conclusion, doxorubicin-lysine/single-walled carbon nanotube-thermo-sensitive liposomes combined with near-infrared laser irradiation at 808 nm may potentially provide viable clinical strategies for targeting delivery of anti-cancer drugs. © The Author(s) 2014 Reprints and permissions: sagepub.co.uk/journalsPermissions.nav.

Stripe-patterned thermo-responsive cell culture dish for cell separation without cell labeling.

PubMed

Kumashiro, Yoshikazu; Ishihara, Jun; Umemoto, Terumasa; Itoga, Kazuyoshi; Kobayashi, Jun; Shimizu, Tatsuya; Yamato, Masayuki; Okano, Teruo

2015-02-11

A stripe-patterned thermo-responsive surface is prepared to enable cell separation without labeling. The thermo-responsive surface containing a 3 μm striped pattern exhibits various cell adhesion and detachment properties. A mixture of three cell types is separated on the patterned surface based on their distinct cell-adhesion properties, and the composition of the cells is analyzed by flow cytometry. © 2014 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

Thermo-Oxidative Degradation Of SiC/Si3N4 Composites

NASA Technical Reports Server (NTRS)

Baaklini, George Y.; Batt, Ramakrishna T.; Rokhlin, Stanislav I.

1995-01-01

Experimental study conducted on thermo-oxidative degradation of composite-material specimens made of silicon carbide fibers in matrices of reaction-bonded silicon nitride. In SiC/Si3N4 composites of study, interphase is 3-micrometers-thick carbon-rich coat on surface of each SiC fiber. Thermo-oxidative degradation of these composites involves diffusion of oxygen through pores of composites to interphases damaged by oxidation. Nondestructive tests reveal critical exposure times.

[Thermo-sensitive period and critical temperature of fertility transition of thermo-photo-sensitive genic male sterile wheat].

PubMed

Zhang, Jiankui; Feng, Li; He, Liren; Yu, Guodong

2003-01-01

The thermo-sensitive period and the critical temperature of fertility transition of C49S, a principal thermo-photosensitive genic male sterile line in two-line hybrid wheat, was studied in the growth chambers for controlling temperature and photoperiod. The seeds were sown on different time for some years. The results showed that the thermo-sensitive period in fertility expression of C49S was from PMC formation stage to mature pollen stage, and there were two most sensitive stages to temperature on fertility expression. One was the PMC meiosis stage, and the other was the middle microspore stage. The critical temperatures evoking a complete male sterility were the mean minimum temperature at PMC meiosis stage (Tmin1), the mean temperature at microspore stage (T2) and the mean minimum temperature at microspore stage (Tmin2) lower than 8.5 degrees C, 13.5 degrees C and 10.5 degrees C, respectively. The critical temperatures keeping a nearly normal male fertility Tmin1 and T2 and Tmin2 were higher than 11.5 degrees C, 15.0 degrees C and 12.5 degrees C, respectively. The value as well as the conditions and the risks of thermo-photo-sensitive genic male sterile line of wheat applied to hybrid wheat were evaluated in this paper.

Forced synchronization and asynchronous quenching in a thermo-acoustic system

NASA Astrophysics Data System (ADS)

Mondal, Sirshendu; Pawar, Samadhan A.; Sujith, Raman

2017-11-01

Forced synchronization, which has been extensively studied in theory and experiments, occurs through two different mechanisms known as phase locking and asynchronous quenching. The latter indicates the suppression of oscillation amplitude. In most practical combustion systems such as gas turbine engines, the main concern is high amplitude pressure oscillations, known as thermo-acoustic instability. Thermo-acoustic instability is undesirable and needs to be suppressed because of its damaging consequences to an engine. In the present study, a systematic experimental investigation of forced synchronization is performed in a prototypical thermo-acoustic system, a Rijke tube, in its limit cycle operation. Further, we show a qualitatively similar behavior using a reduced order model. In the phase locking region, the simultaneous occurrence of synchronization and resonant amplification leads to high amplitude pressure oscillations. However, a reduction in the amplitude of natural oscillations by about 78% of the unforced amplitude is observed when the forcing frequency is far lower than the natural frequency. This shows the possibility of suppression of the oscillation amplitude through asynchronous quenching in thermo-acoustic systems.

The Influence of the Density of Coconut Fiber as Stack in Thermo-Acoustics Refrigeration System

NASA Astrophysics Data System (ADS)

Hartulistiyoso, E.; Yulianto, M.; Sucahyo, L.

2018-05-01

An experimental study of using coconut fiber as stack with varying density in thermo-acoustics refrigeration system has been done. Stack is a device which is described as the “heart” in thermo-acoustics refrigeration system. The length of stack is a fix parameter in this experiment. The performance of the coconut fiber was evaluated from the density of stack (varied from 30%, 50% and 70%), position of stack (varied from 0 to 34 cm from the sound generator), and frequency of sound generator (varied from 150 Hz, 200Hz, 250Hz and 300Hz). The inside, outside, and environment temperatures were collected every second using Data Acquisition (DAQ). The result showed that the increase of stack density will increase the performance of thermo-acoustics refrigeration system. The higher density produced temperature differences in cold side and hot side of 5.4°C. In addition, the position of stack and frequency of sound generator have an important role in the performance of thermo-acoustics refrigeration system for all variations of the density.

Strengthening of Aluminum Alloy 2219 by Thermo-mechanical Treatment

NASA Astrophysics Data System (ADS)

Li, Xifeng; Lei, Kun; Song, Peng; Liu, Xinqin; Zhang, Fei; Li, Jianfei; Chen, Jun

2015-10-01

Strengthening of aluminum alloy 2219 by thermo-mechanical treatment has been compared with artificial aging. Three simple deformation modes including pre-stretching, compression, and rolling have been used in thermo-mechanical treatment. The tensile strength, elongation, fracture feature, and precipitated phase have been investigated. The results show that the strengthening effect of thermo-mechanical treatment is better than the one of artificial aging. Especially, the yield strength significantly increases with a small decrease of elongation. When the specimen is pre-stretched to 8.0%, the yield strength reaches 385.0 MPa and increases by 22.2% in comparison to the one obtained in aging condition. The maximum tensile strength of 472.4 MPa is achieved with 4.0% thickness reduction by compression. The fracture morphology reveals locally ductile and brittle failure mechanism, while the coarse second-phase particles distribute on the fracture surface. The intermediate phases θ″ or θ' orthogonally precipitate in the matrix after thermo-mechanical treatment. As compared to artificial aging, the cold plastic deformation increases distribution homogeneity and the volume fraction of θ'' or θ' precipitates. These result in a better strengthening effect.

Thermo-controlled rheology of electro-assembled polyanionic polysaccharide (alginate) and polycationic thermo-sensitive polymers.

PubMed

Niang, Pape Momar; Huang, Zhiwei; Dulong, Virginie; Souguir, Zied; Le Cerf, Didier; Picton, Luc

2016-03-30

Several thermo-sensitive polyelectrolyte complexes were prepared by ionic self-association between an anionic polysaccharide (alginate) and a monocationic copolymer (polyether amine, Jeffamine®-M2005) with a 'Low Critical Solubility Temperature' (LCST). We show that electro-association must be established below the aggregation temperature of the free Jeffamine®, after which the organization of the system is controlled by the thermo-association of Jeffamine® that was previously electro-associated with the alginate. Evidence for this comes primarily from the rheology in the semi-dilute region. Electro- and thermo-associative behaviours are optimal at a pH corresponding to maximum ionization of both compounds (around pH 7). High ionic strength could prevent the electro-association. The reversibility of the transition is possible only at temperatures lower than the LCST of Jeffamine®. Similar behaviour has been obtained with carboxymethyl cellulose (CMC), which suggests that this behaviour can be observed using a range of anionic polyelectrolytes. In contrast, no specific properties have been found for pullulan, which is a neutral polysaccharide. Copyright © 2015 Elsevier Ltd. All rights reserved.

Fabrication of thermo-responsive cotton fabrics using poly(vinyl caprolactam-co-hydroxyethyl acrylamide) copolymer.

PubMed

Xiao, Min; González, Edurne; Monterroza, Alexis Martell; Frey, Margaret

2017-10-15

A thermo-responsive polymer with hydrophilic to hydrophobic transition behavior, poly(vinyl caprolactam-co-hydroxyethyl acrylamide) P(VCL-co-HEAA), was prepared by copolymerization of vinyl caprolactam and N-hydroxyethyl acrylamide via free radical solution polymerization. The resulting copolymer was characterized by Fourier transform infrared spectroscopy (FTIR), 1 H nuclear magnetic resonance (NMR), gel permeation chromatography (GPC), differential scanning calorimetry (DSC), and thermogravimetric analysis (TGA). The lower critical solution temperature (LCST) of P(VCL-co-HEAA) was determined at 34.5°C. This thermo-responsive polymer was then grafted onto cotton fabrics using 1,2,3,4-butanetetracarboxylic acid (BTCA) as crosslinker and sodium hypophosphite (SHP) as catalyst. FTIR and energy dispersive X-ray spectroscopy (EDS) studies confirmed the successful grafting reaction. The modified cotton fabric exhibited thermo-responsive behavior as evidenced by water vapor permeability measurement confirming decreased permeability at elevated temperature. This is the first demonstration that a PVCL based copolymer is grafted to cotton fabrics. This study provides a new thermo-responsive polymer for fabrication of smart cotton fabrics with thermally switchable hydrophilicity. Copyright © 2017 Elsevier Ltd. All rights reserved.

FASTSAT-HSV01 Thermal Math Model Correlation

NASA Technical Reports Server (NTRS)

McKelvey, Callie

2011-01-01

This paper summarizes the thermal math model correlation effort for the Fast Affordable Science and Technology SATellite (FASTSAT-HSV01), which was designed, built and tested by NASA's Marshall Space Flight Center (MSFC) and multiple partners. The satellite launched in November 2010 on a Minotaur IV rocket from the Kodiak Launch Complex in Kodiak, Alaska. It carried three Earth science experiments and two technology demonstrations into a low Earth circular orbit with an inclination of 72deg and an altitude of 650 kilometers. The mission has been successful to date with science experiment activities still taking place daily. The thermal control system on this spacecraft was a passive design relying on thermo-optical properties and six heaters placed on specific components. Flight temperature data is being recorded every minute from the 48 Resistance Temperature Devices (RTDs) onboard the satellite structure and many of its avionics boxes. An effort has been made to correlate the thermal math model to the flight temperature data using Cullimore and Ring's Thermal Desktop and by obtaining Earth and Sun vector data from the Attitude Control System (ACS) team to create an "as-flown" orbit. Several model parameters were studied during this task to understand the spacecraft's sensitivity to these changes. Many "lessons learned" have been noted from this activity that will be directly applicable to future small satellite programs.

Effective thermo-mechanical properties and shape memory effect of CNT/SMP composites

NASA Astrophysics Data System (ADS)

Yang, Qingsheng; Liu, Xia; Leng, Fangfang

2009-07-01

Shape memory polymer (SMP) has been applied in many fields as intelligent sensors and actuators. In order to improve the mechanical properties and recovery force of SMP, the addition of minor amounts of carbon nanotubes (CNT) into SMP has attracted wide attention. A micromechanical model and thermo-mechanical properties of CNT/SMP composites were studied in this paper. The thermo-mechanical constitutive relation of intellectual composites with isotropic and transversely isotropic CNT was obtained. Moreover, the shape memory effect of CNT/SMP composites and the effect of temperature and the volume fraction of CNT were discussed. The work shows that CNT/SMP composites exhibit excellent macroscopic thermo-mechanical properties and shape memory effect, while both of them can be affected remarkably by temperature and the microstructure parameters.

Athermalization of resonant optical devices via thermo-mechanical feedback

DOEpatents

Rakich, Peter; Nielson, Gregory N.; Lentine, Anthony L.

2016-01-19

A passively athermal photonic system including a photonic circuit having a substrate and an optical cavity defined on the substrate, and passive temperature-responsive provisions for inducing strain in the optical cavity of the photonic circuit to compensate for a thermo-optic effect resulting from a temperature change in the optical cavity of the photonic circuit. Also disclosed is a method of passively compensating for a temperature dependent thermo-optic effect resulting on an optical cavity of a photonic circuit including the step of passively inducing strain in the optical cavity as a function of a temperature change of the optical cavity thereby producing an elasto-optic effect in the optical cavity to compensate for the thermo-optic effect resulting on an optical cavity due to the temperature change.

Effects of Microstructural Variability on Thermo-Mechanical Properties of a Woven Ceramic Matrix Composite

NASA Technical Reports Server (NTRS)

Goldsmith, Marlana B.; Sankar, Bhavani V.; Haftka, Raphael T.; Goldberg, Robert K.

2013-01-01

The objectives of this paper include identifying important architectural parameters that describe the SiC/SiC five-harness satin weave composite and characterizing the statistical distributions and correlations of those parameters from photomicrographs of various cross sections. In addition, realistic artificial cross sections of a 2D representative volume element (RVE) are generated reflecting the variability found in the photomicrographs, which are used to determine the effects of architectural variability on the thermo-mechanical properties. Lastly, preliminary information is obtained on the sensitivity of thermo-mechanical properties to architectural variations. Finite element analysis is used in combination with a response surface and it is shown that the present method is effective in determining the effects of architectural variability on thermo-mechanical properties.

Irreversible temperature gating in trpv1 sheds light on channel activation.

PubMed

Sánchez-Moreno, Ana; Guevara-Hernández, Eduardo; Contreras-Cervera, Ricardo; Rangel-Yescas, Gisela; Ladrón-de-Guevara, Ernesto; Rosenbaum, Tamara; Islas, León D

2018-06-05

Temperature-activated TRP channels or thermoTRPs are among the only proteins that can directly convert temperature changes into changes in channel open probability. In spite of a wealth of functional and structural information, the mechanism of temperature activation remains unknown. We have carefully characterized the repeated activation of TRPV1 by thermal stimuli and discovered a previously unknown inactivation process, which is irreversible. We propose that this form of gating in TRPV1 channels is a consequence of the heat absorption process that leads to channel opening. © 2018, Sánchez-Moreno et al.

Vibration-free stirling cryocooler for high definition microscopy

NASA Astrophysics Data System (ADS)

Riabzev, S. V.; Veprik, A. M.; Vilenchik, H. S.; Pundak, N.; Castiel, E.

2009-12-01

The normal operation of high definition Scanning Electronic and Helium Ion microscope tools often relies on maintaining particular components at cryogenic temperatures. This has traditionally been accomplished by using liquid coolants such as liquid Nitrogen. This inherently limits the useful temperature range to above 77 K, produces various operational hazards and typically involves elevated ownership costs, inconvenient logistics and maintenance. Mechanical coolers, over-performing the above traditional method and capable of delivering required (even below 77 K) cooling to the above cooled components, have been well-known elsewhere for many years, but their typical drawbacks, such as high purchasing cost, cooler size, low reliability and high power consumption have so far prevented their wide-spreading. Additional critical drawback is inevitable degradation of imagery performance originated from the wideband vibration export as typical for the operation of the mechanical cooler incorporating numerous movable components. Recent advances in the development of reliable, compact, reasonably priced and dynamically quiet linear cryogenic coolers gave rise to so-called "dry cooling" technologies aimed at eventually replacing the traditional use of outdated liquid Nitrogen cooling facilities. Although much improved these newer cryogenic coolers still produce relatively high vibration export which makes them incompatible with modern high definition microscopy tools. This has motivated further research activity towards developing a vibration free closed-cycle mechanical cryocooler. The authors have successfully adapted the standard low vibration Stirling cryogenic refrigerator (Ricor model K535-LV) delivering 5 W@40 K heat lift for use in vibration-sensitive high definition microscopy. This has been achieved by using passive mechanical counterbalancing of the main portion of the low frequency vibration export in combination with an active feed-forward multi-axes suppression of the residual wideband vibration, thermo-conductive vibration isolation struts and soft vibration mounts. The attainable performance of the resulting vibration free linear Stirling cryocooler (Ricor model K535-ULV) is evaluated through a full-scale experimentation.

The effect of glutathione as chain transfer agent in PNIPAAm-based thermo-responsive hydrogels for controlled release of proteins.

PubMed

Drapala, Pawel W; Jiang, Bin; Chiu, Yu-Chieh; Mieler, William F; Brey, Eric M; Kang-Mieler, Jennifer J; Pérez-Luna, Victor H

2014-03-01

To control degradation and protein release using thermo-responsive hydrogels for localized delivery of anti-angiogenic proteins. Thermo-responsive hydrogels derived from N-isopropylacrylamide (NIPAAm) and crosslinked with poly(ethylene glycol)-co-(L-lactic acid) diacrylate (Acry-PLLA-b-PEG-b-PLLA-Acry) were synthesized via free radical polymerization in the presence of glutathione, a chain transfer agent (CTA) added to modulate their degradation and release properties. Immunoglobulin G (IgG) and the recombinant proteins Avastin® and Lucentis® were encapsulated in these hydrogels and their release was studied. The encapsulation efficiency of IgG was high (75-87%) and decreased with CTA concentration. The transition temperature of these hydrogels was below physiological temperature, which is important for minimally invasive therapies involving these materials. The toxicity from unreacted monomers and free radical initiators was eliminated with a minimum of three buffer extractions. Addition of CTA accelerated degradation and resulted in complete protein release. Glutathione caused the degradation products to become solubilized even at 37°C. Hydrogels prepared without glutathione did not disintegrate nor released protein completely after 3 weeks at 37°C. PEGylation of IgG postponed the burst release effect. Avastin® and Lucentis® released from degraded hydrogels retained their biological activity. These systems offer a promising platform for the localized delivery of proteins.

Bioreactor mechanically guided 3D mesenchymal stem cell chondrogenesis using a biocompatible novel thermo-reversible methylcellulose-based hydrogel

PubMed Central

Cochis, A.; Grad, S.; Stoddart, M. J.; Farè, S.; Altomare, L.; Azzimonti, B.; Alini, M.; Rimondini, L.

2017-01-01

Autologous chondrocyte implantation for cartilage repair represents a challenge because strongly limited by chondrocytes’ poor expansion capacity in vitro. Mesenchymal stem cells (MSCs) can differentiate into chondrocytes, while mechanical loading has been proposed as alternative strategy to induce chondrogenesis excluding the use of exogenous factors. Moreover, MSC supporting material selection is fundamental to allow for an active interaction with cells. Here, we tested a novel thermo-reversible hydrogel composed of 8% w/v methylcellulose (MC) in a 0.05 M Na2SO4 solution. MC hydrogel was obtained by dispersion technique and its thermo-reversibility, mechanical properties, degradation and swelling were investigated, demonstrating a solution-gelation transition between 34 and 37 °C and a low bulk degradation (<20%) after 1 month. The lack of any hydrogel-derived immunoreaction was demonstrated in vivo by mice subcutaneous implantation. To induce in vitro chondrogenesis, MSCs were seeded into MC solution retained within a porous polyurethane (PU) matrix. PU-MC composites were subjected to a combination of compression and shear forces for 21 days in a custom made bioreactor. Mechanical stimulation led to a significant increase in chondrogenic gene expression, while histological analysis detected sulphated glycosaminoglycans and collagen II only in loaded specimens, confirming MC hydrogel suitability to support load induced MSCs chondrogenesis. PMID:28332587

Star-shaped poly(oligoethylene glycol) copolymer-based gels: Thermo-responsive behaviour and bioapplicability for risedronate intranasal delivery.

PubMed

Soliman, Mahmoud E; Elmowafy, Enas; Casettari, Luca; Alexander, Cameron

2018-05-30

The aim of this work was to obtain an intranasal delivery system with improved mechanical and mucoadhesive properties that could provide prolonged retention time for the delivery of risedronate (RS). For this, novel in situ forming gels comprising thermo-responsive star-shaped polymers, utilizing either polyethylene glycol methyl ether (PEGMA-ME 188, Mn 188) or polyethylene glycol ethyl ether (PEGMA-EE 246, Mn 246), with polyethylene glycol methyl ether (PEGMA-ME 475, Mn 475), were synthesized and characterized. RS was trapped in the selected gel-forming solutions at a concentration of 0.2% w/v. The pH, rheological properties, in vitro drug release, ex vivo permeation as well as mucoadhesion were also examined. MTT assays were conducted to verify nasal tolerability of the developed formulations. Initial in vivo studies were carried out to evaluate anti-osteoporotic activity in a glucocorticoid induced osteoporosis model in rats. The results showed successful development of thermo-sensitive formulations with favorable mechanical properties at 37 °C, which formed non-irritant, mucoadhesive porous networks, facilitating nasal RS delivery. Moreover, sustained release of RS, augmented permeability and marked anti-osteoporotic efficacy as compared to intranasal (IN) and intravenous (IV) RS solutions were realized. The combined results show that the in situ gels should have promising application as nasal drug delivery systems. Copyright © 2018 Elsevier B.V. All rights reserved.

Behavior of a Quasi-Isotropic Ply Metal Matrix Composite under Thermo-Mechanical and Isothermal Fatigue Loading

DTIC Science & Technology

1992-12-01

tensile strength of the composite (20:14). After the heat treatment was accomplished, polishing was performed. Using an automated MAXIMET polishing machine ...AD-A258 902 AFIT/GAE/.ENY/92D-05 Behavior of a Quasi-Isotropic Ply Metal Matrix Composite Under Thermo- Mechanical and Isothermal Fatigue Loading...115 AFIT/GAE/ENY/92D-05 Behavior of a Quasi-Isotropic Ply Metal Matrix Composite Under Thermo- Mechanical and Isothermal Fatigue Loading THESIS

Reconfigurable silicon thermo-optical device based on spectral tuning of ring resonators.

PubMed

Fegadolli, William S; Almeida, Vilson R; Oliveira, José Edimar Barbosa

2011-06-20

A novel tunable and reconfigurable thermo-optical device is theoretically proposed and analyzed in this paper. The device is designed to be entirely compatible with CMOS process and to work as a thermo-optical filter or modulator. Numerical results, made by means of analytical and Finite-Difference Time-Domain (FDTD) methods, show that a compact device enables a broad bandwidth operation, of up to 830 GHz, which allows the device to work under a large temperature variation, of up to 96 K.

Micromechanical analysis of thermo-inelastic multiphase short-fiber composites

NASA Technical Reports Server (NTRS)

Aboudi, Jacob

1994-01-01

A micromechanical formulation is presented for the prediction of the overall thermo-inelastic behavior of multiphase composites which consist of short fibers. The analysis is an extension of the generalized method of cells that was previously derived for inelastic composites with continuous fibers, and the reliability of which was critically examined in several situations. The resulting three dimensional formulation is extremely general, wherein the analysis of thermo-inelastic composites with continuous fibers as well as particulate and porous inelastic materials are merely special cases.

Mechanical rejuvenation in bulk metallic glass induced by thermo-mechanical creep

DOE Office of Scientific and Technical Information (OSTI.GOV)

Tong, Yang; Dmowski, W.; Bei, Hongbin

Using high energy X-ray diffraction we studied the temperature, stress, and time effect on structural changes in a Zr-based bulk metallic glass induced by thermo-mechanical creep. Pair distribution functions obtained from two-dimensional diffraction patterns show that thermo-mechanical creep induces structural disordering, but only when the stress beyond a threshold is applied. A similar threshold behavior was observed for anelastic strain. We conclude that anelastic creep strain induces rejuvenation, whereas plastic strain does not.

Mechanical rejuvenation in bulk metallic glass induced by thermo-mechanical creep

DOE PAGES

Tong, Yang; Dmowski, W.; Bei, Hongbin; ...

2018-02-16

Using high energy X-ray diffraction we studied the temperature, stress, and time effect on structural changes in a Zr-based bulk metallic glass induced by thermo-mechanical creep. Pair distribution functions obtained from two-dimensional diffraction patterns show that thermo-mechanical creep induces structural disordering, but only when the stress beyond a threshold is applied. A similar threshold behavior was observed for anelastic strain. We conclude that anelastic creep strain induces rejuvenation, whereas plastic strain does not.

Integrated system for temperature-controlled fast protein liquid chromatography comprising improved copolymer modified beaded agarose adsorbents and a travelling cooling zone reactor arrangement.

PubMed

Müller, Tobias K H; Cao, Ping; Ewert, Stephanie; Wohlgemuth, Jonas; Liu, Haiyang; Willett, Thomas C; Theodosiou, Eirini; Thomas, Owen R T; Franzreb, Matthias

2013-04-12

An integrated approach to temperature-controlled chromatography, involving copolymer modified agarose adsorbents and a novel travelling cooling zone reactor (TCZR) arrangement, is described. Sepharose CL6B was transformed into a thermoresponsive cation exchange adsorbent (thermoCEX) in four synthetic steps: (i) epichlorohydrin activation; (ii) amine capping; (iii) 4,4'-azobis(4-cyanovaleric acid) immobilization; and 'graft from' polymerization of poly(N-isopropylacrylamide-co-N-tert-butylacrylamide-co-acrylic acid-co-N,N'-methylenebisacrylamide). FT-IR, (1)H NMR, gravimetry and chemical assays allowed precise determination of the adsorbent's copolymer composition and loading, and identified the initial epoxy activation step as a critical determinant of 'on-support' copolymer loading, and in turn, protein binding performance. In batch binding studies with lactoferrin, thermoCEX's binding affinity and maximum adsorption capacity rose smoothly with temperature increase from 20 to 50 °C. In temperature shifting chromatography experiments employing thermoCEX in thermally jacketed columns, 44-51% of the lactoferrin adsorbed at 42 °C could be desorbed under binding conditions by cooling the column to 22 °C, but the elution peaks exhibited strong tailing. To more fully exploit the potential of thermoresponsive chromatography adsorbents, a new column arrangement, the TCZR, was developed. In TCZR chromatography, a narrow discrete cooling zone (special assembly of copper blocks and Peltier elements) is moved along a bespoke fixed-bed separation columnfilled with stationary phase. In tests with thermoCEX, it was possible to recover 65% of the lactoferrin bound at 35 °C using 8 successive movements of the cooling zone at a velocity of 0.1mm/s; over half of the recovered protein was eluted in the first peak in more concentrated form than in the feed. Intra-particle diffusion of desorbed protein out of the support pores, and the ratio between the velocities of the cooling zone and mobile phase were identified as the main parameters affecting TCZR performance. In contrast to conventional systems, which rely on cooling the whole column to effect elution and permit only batch-wise operation, TCZR chromatography generates sharp concentrated elution peaks without tailing effects and appears ideally suited for continuous operation. Copyright © 2013 Elsevier B.V. All rights reserved.

Transition between free, mixed and forced convection

NASA Astrophysics Data System (ADS)

Jaeger, W.; Trimborn, F.; Niemann, M.; Saini, V.; Hering, W.; Stieglitz, R.; Pritz, B.; Fröhlich, J.; Gabi, M.

2017-07-01

In this contribution, numerical methods are discussed to predict the heat transfer to liquid metal flowing in rectangular flow channels. A correct representation of the thermo-hydraulic behaviour is necessary, because these numerical methods are used to perform design and safety studies of components with rectangular channels. Hence, it must be proven that simulation results are an adequate representation of the real conditions. Up to now, the majority of simulations are related to forced convection of liquid metals flowing in circular pipes or rod bundle, because these geometries represent most of the components in process engineering (e.g. piping, heat exchanger). Open questions related to liquid metal heat transfer, among others, is the behaviour during the transition of the heat transfer regimes. Therefore, this contribution aims to provide useful information related to the transition from forced to mixed and free convection, with the focus on a rectangular flow channel. The assessment of the thermo-hydraulic behaviour under transitional heat transfer regimes is pursued by means of system code simulations, RANS CFD simulations, LES and DNS, and experimental investigations. Thereby, each of the results will compared to the others. The comparison of external experimental data, DNS data, RANS data and system code simulation results shows that the global heat transfer can be consistently represented for forced convection in rectangular flow channels by these means. Furthermore, LES data is in agreement with RANS CFD results for different Richardson numbers with respect to temperature and velocity distribution. The agreement of the simulation results among each other and the hopefully successful validation by means of experimental data will fosters the confidence in the predicting capabilities of numerical methods, which can be applied to engineering application.

Survivability of Affordable High Temperature Polymer Matrix Composites for Propulsion Engine Components

NASA Technical Reports Server (NTRS)

Dean, Derrick; Haque, Anwar; Vaidya, Uday; Meador, Michael A. (Technical Monitor)

2003-01-01

PMR-type polyimides are regarded as state of the art high temperature polymers, due to their excellent thermo-mechanical properties and thermo-oxidative stability. One of their drawbacks, however is the inability to process them using cost-effective processing methods such as Resin Transfer Molding (RTM) and Resin Film Infusion (RFI). Development of low viscosity, high temperature polymers has been the subject of intense research. Recently, a new generation of low viscosity polyimides were synthesized by the introduction of twisted biphenyl or binapthyl groups into the backbone. This report details the progress for Year 1, which has involved acquiring samples and initiating Phases I and II of the proposed research. Specifically, studies of the process-property relationships of a series of polymers using oligomers based on 2,3,3' ,4'-biphenyltertracarboxylic dianhydride (PBDA) and a mixture of a diamine, BAX and a triamine, 1,3,5-Tris (4-aminophenoxybenzene), TAB, where the amount of TAB was varied have been initiated. The sample containing 10 percent TAB possesses a slightly higher degree of crystalline order versus that of the 20 percent TAB sample, based on x-ray diffraction studies of the b-staged oligomers. Both systems lose all of the crystalline order upon curing, however. The chemorheology has been studied as a function of the TAB content. While the magnitude of the viscosity is essentially the same for both systems, the cure kinetics of the 10 percent TAB system is faster than that for the 20 percent TAB system. The sample exhibits a melting-recrystallization-remelting behavior before the crosslinking commences. Correlation of other kinetic parameters, such as the activation energies for curing, the Tg and mechanical properties to the structure of these systems is underway. Future studies will involve characterization of mechanical and thermal properties of the pure resins and the fabrication of fiber reinforced composites using these materials.

Mach-Zehnder interferometer implementation for thermo-optical and Kerr effect study

NASA Astrophysics Data System (ADS)

Bundulis, Arturs; Nitiss, Edgars; Busenbergs, Janis; Rutkis, Martins

2018-04-01

In this paper, we propose the Mach-Zehnder interferometric method for third-order nonlinear optical and thermo-optical studies. Both effects manifest themselves as refractive index dependence on the incident light intensity and are widely employed for multiple opto-optical and thermo-optical applications. With the implemented method, we have measured the Kerr and thermo-optical coefficients of chloroform under CW, ns and ps laser irradiance. The application of lasers with different light wavelengths, pulse duration and energy allowed us to distinguish the processes responsible for refractive index changes in the investigated solution. Presented setup was also used for demonstration of opto-optical switching. Results from Mach-Zehnder experiment were compared to Z-scan data obtained in our previous studies. Based on this, a quality comparison of both methods was assessed and advantages and disadvantages of each method were analyzed.

Reflection-refraction of attenuated waves at the interface between a thermo-poroelastic medium and a thermoelastic medium

NASA Astrophysics Data System (ADS)

Sharma, M. D.

2018-07-01

Phenomenon of reflection and refraction is considered at the plane interface between a thermoelastic medium and thermo-poroelastic medium. Both the media are isotropic and behave dissipative to wave propagation. Incident wave in thermo-poroelastic medium is considered inhomogeneous with deviation allowed between the directions of propagation and maximum attenuation. For this incidence, four attenuated waves reflect back in thermo-poroelastic medium and three waves refract to the continuing thermoelastic medium. Each of these reflected/refracted waves is inhomogeneous and propagates with a phase shift. The propagation characteristics (velocity, attenuation, inhomogeneity, phase shift, amplitude, energy) of reflected and refracted waves are calculated as functions of propagation direction and inhomogeneity of the incident wave. Variations in these propagation characteristics with the incident direction are illustrated through a numerical example.

Contrastive Numerical Investigations on Thermo-Structural Behaviors in Mass Concrete with Various Cements

PubMed Central

Zhou, Wei; Feng, Chuqiao; Liu, Xinghong; Liu, Shuhua; Zhang, Chao; Yuan, Wei

2016-01-01

This work is a contrastive investigation of numerical simulations to improve the comprehension of thermo-structural coupled phenomena of mass concrete structures during construction. The finite element (FE) analysis of thermo-structural behaviors is used to investigate the applicability of supersulfated cement (SSC) in mass concrete structures. A multi-scale framework based on a homogenization scheme is adopted in the parameter studies to describe the nonlinear concrete behaviors. Based on the experimental data of hydration heat evolution rate and quantity of SSC and fly ash Portland cement, the hydration properties of various cements are studied. Simulations are run on a concrete dam section with a conventional method and a chemo-thermo-mechanical coupled method. The results show that SSC is more suitable for mass concrete structures from the standpoint of temperature control and crack prevention. PMID:28773517

Contrastive Numerical Investigations on Thermo-Structural Behaviors in Mass Concrete with Various Cements.

PubMed

Zhou, Wei; Feng, Chuqiao; Liu, Xinghong; Liu, Shuhua; Zhang, Chao; Yuan, Wei

2016-05-20

This work is a contrastive investigation of numerical simulations to improve the comprehension of thermo-structural coupled phenomena of mass concrete structures during construction. The finite element (FE) analysis of thermo-structural behaviors is used to investigate the applicability of supersulfated cement (SSC) in mass concrete structures. A multi-scale framework based on a homogenization scheme is adopted in the parameter studies to describe the nonlinear concrete behaviors. Based on the experimental data of hydration heat evolution rate and quantity of SSC and fly ash Portland cement, the hydration properties of various cements are studied. Simulations are run on a concrete dam section with a conventional method and a chemo-thermo-mechanical coupled method. The results show that SSC is more suitable for mass concrete structures from the standpoint of temperature control and crack prevention.

Use of a smart phone based thermo camera for skin prick allergy testing: a feasibility study (Conference Presentation)

NASA Astrophysics Data System (ADS)

Barla, Lindi; Verdaasdonk, Rudolf M.; Rustemeyer, Thomas; Klaessens, John; van der Veen, Albert

2016-02-01

Allergy testing is usually performed by exposing the skin to small quantities of potential allergens on the inner forearm and scratching the protective epidermis to increase exposure. After 15 minutes the dermatologist performs a visual check for swelling and erythema which is subjective and difficult for e.g. dark skin types. A small smart phone based thermo camera (FLIR One) was used to obtain quantitative images in a feasibility study of 17 patients Directly after allergen exposure on the forearm, thermal images were captured at 30 seconds interval and processed to a time lapse movie over 15 minutes. Considering the 'subjective' reading of the dermatologist as golden standard, in 11/17 pts (65%) the evaluation of dermatologist was confirmed by the thermo camera including 5 of 6 patients without allergic response. In 7 patients thermo showed additional spots. Of the 342 sites tested, the dermatologist detected 47 allergies of which 28 (60%) were confirmed by thermo imaging while thermo imaging showed 12 additional spots. The method can be improved with user dedicated acquisition software and better registration between normal and thermal images. The lymphatic reaction seems to shift from the original puncture site. The interpretation of the thermal images is still subjective since collecting quantitative data is difficult due to motion patient during 15 minutes. Although not yet conclusive, thermal imaging shows to be promising to improve the sensitivity and selectivity of allergy testing using a smart phone based camera.

The Metabolic Basis of Pollen Thermo-Tolerance: Perspectives for Breeding

PubMed Central

Paupière, Marine J.; van Heusden, Adriaan W.; Bovy, Arnaud G.

2014-01-01

Crop production is highly sensitive to elevated temperatures. A rise of a few degrees above the optimum growing temperature can lead to a dramatic yield loss. A predicted increase of 1–3 degrees in the twenty first century urges breeders to develop thermo-tolerant crops which are tolerant to high temperatures. Breeding for thermo-tolerance is a challenge due to the low heritability of this trait. A better understanding of heat stress tolerance and the development of reliable methods to phenotype thermo-tolerance are key factors for a successful breeding approach. Plant reproduction is the most temperature-sensitive process in the plant life cycle. More precisely, pollen quality is strongly affected by heat stress conditions. High temperature leads to a decrease of pollen viability which is directly correlated with a loss of fruit production. The reduction in pollen viability is associated with changes in the level and composition of several (groups of) metabolites, which play an important role in pollen development, for example by contributing to pollen nutrition or by providing protection to environmental stresses. This review aims to underline the importance of maintaining metabolite homeostasis during pollen development, in order to produce mature and fertile pollen under high temperature. The review will give an overview of the current state of the art on the role of various pollen metabolites in pollen homeostasis and thermo-tolerance. Their possible use as metabolic markers to assist breeding programs for plant thermo-tolerance will be discussed. PMID:25271355

The metabolic basis of pollen thermo-tolerance: perspectives for breeding.

PubMed

Paupière, Marine J; van Heusden, Adriaan W; Bovy, Arnaud G

2014-09-30

Crop production is highly sensitive to elevated temperatures. A rise of a few degrees above the optimum growing temperature can lead to a dramatic yield loss. A predicted increase of 1-3 degrees in the twenty first century urges breeders to develop thermo-tolerant crops which are tolerant to high temperatures. Breeding for thermo-tolerance is a challenge due to the low heritability of this trait. A better understanding of heat stress tolerance and the development of reliable methods to phenotype thermo-tolerance are key factors for a successful breeding approach. Plant reproduction is the most temperature-sensitive process in the plant life cycle. More precisely, pollen quality is strongly affected by heat stress conditions. High temperature leads to a decrease of pollen viability which is directly correlated with a loss of fruit production. The reduction in pollen viability is associated with changes in the level and composition of several (groups of) metabolites, which play an important role in pollen development, for example by contributing to pollen nutrition or by providing protection to environmental stresses. This review aims to underline the importance of maintaining metabolite homeostasis during pollen development, in order to produce mature and fertile pollen under high temperature. The review will give an overview of the current state of the art on the role of various pollen metabolites in pollen homeostasis and thermo-tolerance. Their possible use as metabolic markers to assist breeding programs for plant thermo-tolerance will be discussed.

Preparation and thermo-optic switch properties based on chiral azobenzene-containing polyurethane

NASA Astrophysics Data System (ADS)

Ye, Feiyan; Qiu, Fengxian; Yang, Dongya; Cao, Guorong; Guan, Yijun; Zhuang, Lin

2013-07-01

A chiral azo chromophore compound 4-(4'-nitro-phenyl-diazenyl)-phenyl-1,2-propanediol ether (NPDPPE) was prepared with p-nitroaniline, phenol and R(-)-3-chloro-1,2-propanediol by the diazo-coupling reaction. Then, the chromophore molecule NPDPPE was polymerized with isophorone diisocyanate (IPDI) to obtain novel chiral azobenzene-containing polyurethane (CACPU). The chemical structures of chromophore molecule and CACPU were characterized by the FT-IR and UV-visible spectroscopy. The physical properties (thermal conductivity, thermal diffusion coefficient, and specific heat capacity) and mechanical properties (tensile strength, elongation at break and hardness) of CACPU thin films were measured. The refractive index and thermo-optic (TO) coefficient (dn/dT) of CACPU thin film was investigated for TE (transversal electric) polarizations by using an attenuated total reflection (ATR) configuration at the wavelengths of 532, 650 and 850 nm. The transmission loss of film was measured using the charge coupled device (CCD) digital imaging devices. A Y-branch switch and Mach-Zehnder interferometer (MZI) thermo-optic switches based on thermo-optic effect were proposed and the performances of switches were simulated. The results showed that the power consumption of the Y-branch thermo-optic switch was only 3.28 mW. The rising and falling times of Y-branch and MZI switches were 12.0 ms and 2.0 ms, respectively. The conclusion has potential significance to improve and develop new Y-branch digital optical switch (DOS), MZI thermo-optic switch, directional coupler (DC) switch and optical modulators.

Synthesis, physical properties and simulation of thermo-optic switch based on azo benzothiazole heterocyclic polymer

NASA Astrophysics Data System (ADS)

Qiu, Fengxian; Chen, Caihong; Zhou, Qiaolan; Cao, Zhijuan; Cao, Guorong; Guan, Yijun; Yang, Dongya

2014-05-01

A chromophore molecule 4-[(benzothiazole-2-yl)diazenyl]phenyl-1,3-diamine (BTPD) was prepared with 2-amino benzothiazole and m-phenylenediamine by diazo-coupling reaction. Then, the BTPD was polymerized with polyether polyol (NJ-220) and isophorone diisocyanate (IPDI) to obtain novel azo benzothiazole polyurethane-urea (BTPUU). The chemical structures of BTPD and BTPUU were characterized by FT-IR and UV-visible spectroscopy. The thermal and mechanical properties of BTPUU film were investigated. The refractive index and transmission loss of BTPUU film were measured at different temperatures and different laser wavelengths (532 nm, 650 nm and 850 nm) by an attenuated total reflection (ATR) technique and CCD digital imaging devices. The thermo-optic coefficients of BTPUU are -4.7086 × 10-4 °C-1 (532 nm), -6.5257 × 10-4 °C-1 (650 nm) and -5.1029 × 10-4 °C-1 (850 nm), respectively. A Y-branch switch and Mach-Zehnder interferometer (MZI) thermo-optic switches based on thermo-optic effect were proposed and the performances of the switches were simulated, respectively. The results show that the power consumption of the Y-branch thermo-optic switch is only 3.28 mW. The response times of Y-branch and MZI switches are 8.0 ms and 2.0 ms, respectively. The results indicate that the prepared BTPUU has high potential for the applications of the Y-branch digital optical switch (DOS), MZI thermo-optic switch, directional coupler (DC) switch and optical modulators.

Improvement of activity, thermo-stability and fruit juice clarification characteristics of fungal exo-polygalacturonase.

PubMed

Amin, Faiza; Bhatti, Haq Nawaz; Bilal, Muhammad; Asgher, Muhammad

2017-02-01

An extracellular exo-polygalacturonase (exo-PG) from Penicillium notatum was immobilized in sodium-alginate matrix through two different protocols, viz. covalent bonding and adsorption to enhance its catalytic activity, thermal stability and life-time properties for industrial applications. Covalent immobilization was more efficient in terms of high relative activity (45.89%) and immobilization yield (71.6%) as compared to adsorption. Immobilized exo-PG derivatives displayed maximum activities at pH 5.5 and 55°C as compared to free enzyme which showed its optimum activity at pH 6.0 and 50°C. The affinity of enzyme towards its substrate (K m(app) ) was reduced after immobilization and V max of covalently immobilized exo-PG decreased to 66.7% while the V max value of adsorbed enzyme increased up to 150% as compared to free counterpart. Both immobilization techniques greatly enhanced the thermal stability profile of the enzyme. At 60°C, immobilized exo-PGs retained more than 90% of their residual activities after 60min of heating, while free enzyme did not show any activity at the same temperature. Thermodynamic properties (i.e., Ea, ΔH*, ΔS*and ΔG*) of the free and immobilized enzymes were also investigated. Sodium-alginate covalently immobilized and adsorbed enzymes showed excellent recycling efficiencies and retained 50.0% and 41.0% of original activities, respectively after seven consecutive batch reactions. Moreover, the immobilized enzymes treatment achieved promising results in turbidity and viscosity reduction as well as clarity amelioration in various fruit juices. Altogether catalytic, thermo-stability and fruit juices clarification characteristics of the immobilized ex-PGs suggest a high potential for biotechnological exploitability. Copyright © 2016 Elsevier B.V. All rights reserved.

Fluid mechanics phenomena in microgravity; ASME Winter Annual Meeting, Anaheim, CA, Nov. 8-13, 1992

NASA Technical Reports Server (NTRS)

Siginer, Dennis A. (Editor); Weislogel, Mark M. (Editor)

1992-01-01

This paper is the first in a series of symposia presenting research activity in microgravity fluid mechanics. General topics addressed include two-phase flow and transport phenomena, thermo-capillary flow, and interfacial stability. Papers present mathmatical models of fluid dynamics in the microgravity environment. Applications suggested include space manufacturing and storage of liquids in low gravity.

AC Electric Field Activated Shape Memory Polymer Composite

NASA Technical Reports Server (NTRS)

Kang, Jin Ho; Siochi, Emilie J.; Penner, Ronald K.; Turner, Travis L.

2011-01-01

Shape memory materials have drawn interest for applications like intelligent medical devices, deployable space structures and morphing structures. Compared to other shape memory materials like shape memory alloys (SMAs) or shape memory ceramics (SMCs), shape memory polymers (SMPs) have high elastic deformation that is amenable to tailored of mechanical properties, have lower density, and are easily processed. However, SMPs have low recovery stress and long response times. A new shape memory thermosetting polymer nanocomposite (LaRC-SMPC) was synthesized with conductive fillers to enhance its thermo-mechanical characteristics. A new composition of shape memory thermosetting polymer nanocomposite (LaRC-SMPC) was synthesized with conductive functionalized graphene sheets (FGS) to enhance its thermo-mechanical characteristics. The elastic modulus of LaRC-SMPC is approximately 2.7 GPa at room temperature and 4.3 MPa above its glass transition temperature. Conductive FGSs-doped LaRC-SMPC exhibited higher conductivity compared to pristine LaRC SMP. Applying an electric field at between 0.1 Hz and 1 kHz induced faster heating to activate the LaRC-SMPC s shape memory effect relative to applying DC electric field or AC electric field at frequencies exceeding1 kHz.

Thermo-alkaline pretreatment of waste activated sludge at low-temperatures: effects on sludge disintegration, methane production, and methanogen community structure.

PubMed

Kim, Jaai; Yu, Youngseob; Lee, Changsoo

2013-09-01

Low-temperature thermo-alkaline pretreatment of waste activated sludge (WAS) was studied, within the region of 0-0.2 M NaOH and 60-90°C, for the effects of NaOH concentration and temperature on sludge degradability in anaerobic digestion (AD). Significant disintegration of sludge solids (up to 75.6%) and an increase in methane production (up to 70.6%) were observed in the pretreatment trials. Two quadratic models were successfully generated by response surface analysis (R(2)>0.9, p<0.05) to approximate how the degree of sludge disintegration (SD) and methane production (MP) respond to changes in the pretreatment conditions. The maximum responses of SD (77.8%) and MP (73.9% increase over the control) were shown at [0.16 M NaOH, 90°C] and [0.10 M NaOH, 73.7°C], respectively. NaOH addition showed a significant influence on the evolution of methanogen community structure during AD, whereas temperature did not. Aceticlastic Methanosaeta and Methanosarcina speceies were likely the major methanogens. Copyright © 2013 Elsevier Ltd. All rights reserved.

Combined thermo-chemo-sonic disintegration of waste activated sludge for biogas production.

PubMed

Kavitha, S; Yukesh Kannah, R; Yeom, Ick Tae; Do, Khac-Uan; Banu, J Rajesh

2015-12-01

In the present study, there was an investigation about the impact of a new combined thermo-chemo-sonic disintegration of waste activated sludge (WAS) on biodegradability. The outcome of sludge disintegration reveals that maximum Suspended Solids (SS) reduction and Chemical Oxygen Demand (COD) solubilization effectuated at a specific energy input of 5290.5kJ/kgTS, and was found to be 20%, 16.4%, 15% and 27%, 22%, and 20%, respectively for the three alkalis (NaOH, KOH, and Ca(OH)2). The conversion coefficient of the Volatile Suspended Solids (VSS) to product Soluble COD (SCOD), calculated by nonlinear regression modeling, was found to be 0.5530gSCOD/gVSS, 0.4587gSCOD/gVSS, and 0.4195gSCOD/gVSS for NaOH, KOH, and Ca(OH)2, respectively. In the biodegradability studies, the parameter evaluation provides an estimate of parameter uncertainty and correlation, and elucidates that there is no significant difference in biodegradability (0.413gCOD/gCOD, 0.367gCOD/gCOD, and 0.342gCOD/gCOD) for three alkalis (NaOH, KOH, and Ca(OH)2). Copyright © 2015 Elsevier Ltd. All rights reserved.

A thermodynamic framework for thermo-chemo-elastic interactions in chemically active materials

NASA Astrophysics Data System (ADS)

Zhang, XiaoLong; Zhong, Zheng

2017-08-01

In this paper, a general thermodynamic framework is developed to describe the thermo-chemo-mechanical interactions in elastic solids undergoing mechanical deformation, imbibition of diffusive chemical species, chemical reactions and heat exchanges. Fully coupled constitutive relations and evolving laws for irreversible fluxes are provided based on entropy imbalance and stoichiometry that governs reactions. The framework manifests itself with a special feature that the change of Helmholtz free energy is attributed to separate contributions of the diffusion-swelling process and chemical reaction-dilation process. Both the extent of reaction and the concentrations of diffusive species are taken as independent state variables, which describe the reaction-activated responses with underlying variation of microstructures and properties of a material in an explicit way. A specialized isothermal formulation for isotropic materials is proposed that can properly account for volumetric constraints from material incompressibility under chemo-mechanical loadings, in which inhomogeneous deformation is associated with reaction and diffusion under various kinetic time scales. This framework can be easily applied to model the transient volumetric swelling of a solid caused by imbibition of external chemical species and simultaneous chemical dilation arising from reactions between the diffusing species and the solid.

Sonication-Induced Modification of Carbon Nanotubes: Effect on the Rheological and Thermo-Oxidative Behaviour of Polymer-Based Nanocomposites.

PubMed

Arrigo, Rossella; Teresi, Rosalia; Gambarotti, Cristian; Parisi, Filippo; Lazzara, Giuseppe; Dintcheva, Nadka Tzankova

2018-03-05

The aim of this work is the investigation of the effect of ultrasound treatment on the structural characteristics of carbon nanotubes (CNTs) and the consequent influence that the shortening induced by sonication exerts on the morphology, rheological behaviour and thermo-oxidative resistance of ultra-high molecular weight polyethylene (UHMWPE)-based nanocomposites. First, CNTs have been subjected to sonication for different time intervals and the performed spectroscopic and morphological analyses reveal that a dramatic decrease of the CNT's original length occurs with increased sonication time. The reduction of the initial length of CNTs strongly affects the nanocomposite rheological behaviour, which progressively changes from solid-like to liquid-like as the CNT sonication time increases. The study of the thermo-oxidative behaviour of the investigated nanocomposites reveals that the CNT sonication has a detrimental effect on the thermo-oxidative stability of nanocomposites, especially for long exposure times. The worsening of the thermo-oxidative resistance of sonicated CNT-containing nanocomposites could be attributed to the lower thermal conductivity of low-aspect-ratio CNTs, which causes the increase of the local temperature at the polymer/nanofillers interphase, with the consequent acceleration of the degradative phenomena.

Sonication-Induced Modification of Carbon Nanotubes: Effect on the Rheological and Thermo-Oxidative Behaviour of Polymer-Based Nanocomposites

PubMed Central

Teresi, Rosalia; Gambarotti, Cristian; Dintcheva, Nadka Tzankova

2018-01-01

The aim of this work is the investigation of the effect of ultrasound treatment on the structural characteristics of carbon nanotubes (CNTs) and the consequent influence that the shortening induced by sonication exerts on the morphology, rheological behaviour and thermo-oxidative resistance of ultra-high molecular weight polyethylene (UHMWPE)-based nanocomposites. First, CNTs have been subjected to sonication for different time intervals and the performed spectroscopic and morphological analyses reveal that a dramatic decrease of the CNT’s original length occurs with increased sonication time. The reduction of the initial length of CNTs strongly affects the nanocomposite rheological behaviour, which progressively changes from solid-like to liquid-like as the CNT sonication time increases. The study of the thermo-oxidative behaviour of the investigated nanocomposites reveals that the CNT sonication has a detrimental effect on the thermo-oxidative stability of nanocomposites, especially for long exposure times. The worsening of the thermo-oxidative resistance of sonicated CNT-containing nanocomposites could be attributed to the lower thermal conductivity of low-aspect-ratio CNTs, which causes the increase of the local temperature at the polymer/nanofillers interphase, with the consequent acceleration of the degradative phenomena. PMID:29510595

Evaluation of a combination tumor treatment using thermo-triggered liposomal drug delivery and carbon ion irradiation.

PubMed

Kokuryo, Daisuke; Aoki, Ichio; Yuba, Eiji; Kono, Kenji; Aoshima, Sadahito; Kershaw, Jeff; Saga, Tsuneo

2017-07-01

The combination of radiotherapy with chemotherapy is one of the most promising strategies for cancer treatment. Here, a novel combination strategy utilizing carbon ion irradiation as a high-linear energy transfer (LET) radiotherapy and a thermo-triggered nanodevice is proposed, and drug accumulation in the tumor and treatment effects are evaluated using magnetic resonance imaging relaxometry and immunohistology (Ki-67, n = 15). The thermo-triggered liposomal anticancer nanodevice was administered into colon-26 tumor-grafted mice, and drug accumulation and efficacy was compared for 6 groups (n = 32) that received or did not receive the radiotherapy and thermo trigger. In vivo quantitative R 1 maps visually demonstrated that the multimodal thermosensitive polymer-modified liposomes (MTPLs) can accumulate in the tumor tissue regardless of whether the region was irradiated by carbon ions or not. The tumor volume after combination treatment with carbon ion irradiation and MTPLs with thermo-triggering was significantly smaller than all the control groups at 8 days after treatment. The proposed strategy of combining high-LET irradiation and the nanodevice provides an effective approach for minimally invasive cancer treatment. Copyright © 2017 The Author(s). Published by Elsevier Inc. All rights reserved.

Zirconium tungstate/epoxy nanocomposites: effect of nanoparticle morphology and negative thermal expansivity.

PubMed

Wu, Hongchao; Rogalski, Mark; Kessler, Michael R

2013-10-09

The ability to tailor the coefficient of thermal expansion (CTE) of a polymer is essential for mitigating thermal residual stress and reducing microcracks caused by CTE mismatch of different components in electronic applications. This work studies the effect of morphology and thermal expansivity of zirconium tungstate nanoparticles on the rheological, thermo-mechanical, dynamic-mechanical, and dielectric properties of ZrW2O8/epoxy nanocomposites. Three types of ZrW2O8 nanoparticles were synthesized under different hydrothermal conditions and their distinct properties were characterized, including morphology, particle size, aspect ratio, surface area, and CTE. Nanoparticles with a smaller particle size and larger surface area led to a more significant reduction in gel-time and glass transition temperature of the epoxy nanocomposites, while a higher initial viscosity and significant shear thinning behavior was found in prepolymer suspensions containing ZrW2O8 with larger particle sizes and aspect ratios. The thermo- and dynamic-mechanical properties of epoxy-based nanocomposites improved with increasing loadings of the three types of ZrW2O8 nanoparticles. In addition, the introduced ZrW2O8 nanoparticles did not negatively affect the dielectric constant or the breakdown strength of the epoxy resin, suggesting potential applications of ZrW2O8/epoxy nanocomposites in the microelectronic insulation industry.

Moisture Management Behaviour of Knitted Fabric from Structurally Modified Ring and Vortex Spun Yarn

NASA Astrophysics Data System (ADS)

Sharma, Navendu; Kumar, Pawan; Bhatia, Dinesh; Sinha, Sujit Kumar

2016-10-01

The acceptability of a new product is decided by its performance, level of improvement in quality and economy of production. The basic aim of generating micro pores in a textile structure is to provide better thermo-physiological comfort by enhancing the breathability and hence improving moisture management behaviour. In the present study, an attempt has been made to create a relatively more open structure through removal of a component. A comparative assessment with a homogeneous and parent yarn was also made. Yarns of two linear densities, each from ring and vortex spinning systems were produced using 100 % polyester and 80:20 polyester/cotton blend. The modified yarn was produced by removing a component, viz; cotton, by treatment with sulphuric acid from the blended yarn. The knitted fabric from modified yarn was found to show significant improvement in air permeability, water vapour permeability and total absorbency while the wicking characteristic was found to decline.

Non Thermal Emission from Clusters of Galaxies: the Importance of a Joint LOFAR/Simbol-X View

NASA Astrophysics Data System (ADS)

Ferrari, C.

2009-05-01

Deep radio observations of galaxy clusters have revealed the existence of diffuse radio sources (``halos'' and ``relics'') related to the presence of relativistic electrons and weak magnetic fields in the intracluster volume. I will outline our current knowledge about the presence and properties of this non-thermal cluster component. Despite the recent progress made in observational and theoretical studies of the non-thermal emission in galaxy clusters, a number of open questions about its origin and its effects on the thermo-dynamical evolution of galaxy clusters need to be answered. I will show the importance of combining galaxy cluster observations by new-generation instruments such as LOFAR and Simbol-X. A deeper knowledge of the non-thermal cluster component, together with statistical studies of radio halos and relics, will allow to test the current cluster formation scenario and to better constrain the physics of large scale structure evolution.

Method for phosphorothioate antisense DNA sequencing by capillary electrophoresis with UV detection.

PubMed

Froim, D; Hopkins, C E; Belenky, A; Cohen, A S

1997-11-01

The progress of antisense DNA therapy demands development of reliable and convenient methods for sequencing short single-stranded oligonucleotides. A method of phosphorothioate antisense DNA sequencing analysis using UV detection coupled to capillary electrophoresis (CE) has been developed based on a modified chain termination sequencing method. The proposed method reduces the sequencing cost since it uses affordable CE-UV instrumentation and requires no labeling with minimal sample processing before analysis. Cycle sequencing with ThermoSequenase generates quantities of sequencing products that are readily detectable by UV. Discrimination of undesired components from sequencing products in the reaction mixture, previously accomplished by fluorescent or radioactive labeling, is now achieved by bringing concentrations of undesired components below the UV detection range which yields a 'clean', well defined sequence. UV detection coupled with CE offers additional conveniences for sequencing since it can be accomplished with commercially available CE-UV equipment and is readily amenable to automation.

Method for phosphorothioate antisense DNA sequencing by capillary electrophoresis with UV detection.

PubMed Central

Froim, D; Hopkins, C E; Belenky, A; Cohen, A S

1997-01-01

The progress of antisense DNA therapy demands development of reliable and convenient methods for sequencing short single-stranded oligonucleotides. A method of phosphorothioate antisense DNA sequencing analysis using UV detection coupled to capillary electrophoresis (CE) has been developed based on a modified chain termination sequencing method. The proposed method reduces the sequencing cost since it uses affordable CE-UV instrumentation and requires no labeling with minimal sample processing before analysis. Cycle sequencing with ThermoSequenase generates quantities of sequencing products that are readily detectable by UV. Discrimination of undesired components from sequencing products in the reaction mixture, previously accomplished by fluorescent or radioactive labeling, is now achieved by bringing concentrations of undesired components below the UV detection range which yields a 'clean', well defined sequence. UV detection coupled with CE offers additional conveniences for sequencing since it can be accomplished with commercially available CE-UV equipment and is readily amenable to automation. PMID:9336449

Proceedings of the European ISTVS Conference (6th), OVK Symposium (4th), on "Off Road Vehicles in Theory and Practice". Held at Vienna, Austria on 28-30 September 1994. Volume 2.

DTIC Science & Technology

1994-09-30

experimental proof-of-concept series hybrid thermo-mechano-elec- tromechanical and/or electromechanical All-Wheel-Driven (AWD) pro- pulsion, All-Wheel...caterpillar-tracks’ motorized sprocket-, road- and tensioner- wheels form a complete proof-of-concept series hybrid thermo- mechano-electromechanical and/or...tromechanical AWA supension spheres and skid-steering conversion spheres used as integral spheres together with future new concept hybrid thermo

ThermoSpots to detect hypothermia in children with severe acute malnutrition.

PubMed

Mole, Thomas B; Kennedy, Neil; Ndoya, Noel; Emond, Alan

2012-01-01

Hypothermia is a risk factor for increased mortality in children with severe acute malnutrition (SAM). Yet frequent temperature measurement remains unfeasible in under-resourced units in developing countries. ThermoSpot is a continuous temperature monitoring sticker designed originally for neonates. When applied to skin, its liquid crystals are designed to turn black with hypothermia and remain green with normothermia. To (i) estimate the diagnostic accuracy of ThermoSpots for detecting WHO-defined hypothermia (core temperature <35.5°C or peripheral temperature <35.0°C) in children with SAM and (ii) determine their acceptability amongst mothers. Children with SAM in a malnutrition unit in Malawi were enrolled during March-July 2010. The sensitivity and specificity of ThermoSpots were calculated by comparing the device colour against 'gold standard' rectal temperatures taken on admission and follow up peripheral temperatures taken until discharge. Guardians completed a questionnaire to assess acceptability. Hypothermia was uncommon amongst the 162 children enrolled. ThermoSpot successfully detected the one rectal temperature and two peripheral temperatures recorded that met the WHO definition of hypothermia. Overall, 3/846 (0.35%) temperature measurements were in the WHO-defined hypothermia range. Interpreting the brown transition colour (between black and green) as hypothermia improved sensitivities. For milder hypothermia definitions, sensitivities declined (<35.4°C, 50.0%; <35.9°C, 39.2%). Specificity was consistently above 94%. From questionnaires, 40/43 (93%) mothers reported they were 90-100% happy with the device overall. Free-text answers revealed themes of "Skin Rashes", "User-satisfaction" and "Empowerment". Although hypothermia was uncommon in this study, ThermoSpots successfully detected these episodes in malnourished children and were acceptable to mothers. Research in settings where hypothermia is common is needed to determine performance with certainty. Instructing users to act when the device's transition colour appears could improve accuracy. If reliable, ThermoSpots may offer simple, acceptable and continuous temperature measurement for high-burden areas and reduce the workload of over-stretched staff.

SPIDER beam dump as diagnostic of the particle beam

DOE Office of Scientific and Technical Information (OSTI.GOV)

Zaupa, M., E-mail: matteo.zaupa@igi.cnr.it; Sartori, E.; Consorzio RFX, Corso Stati Uniti 4, Padova 35127

The beam power produced by the negative ion source for the production of ion of deuterium extracted from RF plasma is mainly absorbed by the beam dump component which has been designed also for measuring the temperatures on the dumping panels for beam diagnostics. A finite element code has been developed to characterize, by thermo-hydraulic analysis, the sensitivity of the beam dump to the different beam parameters. The results prove the capability of diagnosing the beam divergence and the horizontal misalignment, while the entity of the halo fraction appears hardly detectable without considering the other foreseen diagnostics like tomography andmore » beam emission spectroscopy.« less

SPIDER beam dump as diagnostic of the particle beam

NASA Astrophysics Data System (ADS)

Zaupa, M.; Dalla Palma, M.; Sartori, E.; Brombin, M.; Pasqualotto, R.

2016-11-01

The beam power produced by the negative ion source for the production of ion of deuterium extracted from RF plasma is mainly absorbed by the beam dump component which has been designed also for measuring the temperatures on the dumping panels for beam diagnostics. A finite element code has been developed to characterize, by thermo-hydraulic analysis, the sensitivity of the beam dump to the different beam parameters. The results prove the capability of diagnosing the beam divergence and the horizontal misalignment, while the entity of the halo fraction appears hardly detectable without considering the other foreseen diagnostics like tomography and beam emission spectroscopy.

Conceptual design of ACB-CP for ITER cryogenic system

NASA Astrophysics Data System (ADS)

Jiang, Yongcheng; Xiong, Lianyou; Peng, Nan; Tang, Jiancheng; Liu, Liqiang; Zhang, Liang

2012-06-01

ACB-CP (Auxiliary Cold Box for Cryopumps) is used to supply the cryopumps system with necessary cryogen in ITER (International Thermonuclear Experimental Reactor) cryogenic distribution system. The conceptual design of ACB-CP contains thermo-hydraulic analysis, 3D structure design and strength checking. Through the thermohydraulic analysis, the main specifications of process valves, pressure safety valves, pipes, heat exchangers can be decided. During the 3D structure design process, vacuum requirement, adiabatic requirement, assembly constraints and maintenance requirement have been considered to arrange the pipes, valves and other components. The strength checking has been performed to crosscheck if the 3D design meets the strength requirements for the ACB-CP.

Periglacial Landscape Stabilization Following Rapid Permafrost Degradation by Thermo-erosion, Bylot Island, Nunavut, Canadian Arctic Archipelago

NASA Astrophysics Data System (ADS)

Fortier, D.; Godin, E.; Perreault, N.; Levesque, E.

2010-12-01

The Byam Martin Mountains that run southeast-northwest across Bylot Island are covered by an ice cap which is flowing towards the lowlands into valleys. The bottom of these valleys is filled with sediments shaped into various periglacial landforms that developed during the Holocene such as ice-wedge polygons, pingos, and thermokarst lakes (Fortier and Allard, 2004). At the study site (N 73° 09’ - W 79° 53’), snow-melt run-off driven processes of thermo-erosion have recently drastically modified the periglacial landscape by creating extensive network of gullies in ice-wedge polygons. In the valley of glacier C-79, thirty five gullies, hundreds of meters to kilometers long, were identified and studied in the field. The formation of these gullies has changed the local hydrographic network by connecting the valley walls to a proglacial river flowing in the valley. The gully heads were characterized by active thermo-erosion processes operating underground and at the surface for a number of years (Fortier et al. 2007). Downstream, the gully walls were affected by various permafrost degradation processes such as active-layer detachment, retrogressive thaw slumping, drainage of the active layer of the polygons into the gully channel and differential thaw settlement of the surface (Godin and Fortier, 2010). It was observed that after a few years the downstream parts of the gully systems were stabilized and the gully walls partially colonized by vegetation. Drilling and coring operations into stabilized areas revealed the presence of ground ice a few decimeters below the surface with cryostructures indicative of permafrost aggradation. On stabilized gully walls, the sediments were aligned parallel to the slope and showed ice-rich reticulate to suspended cryostructures. Down to about one meter, the sediments were separated by centimeters-thick ice lenses which contained air bubbles aligned perpendicular to the slope. We propose that drainage of the soils on the slope and the subsequent colonization of stabilized slopes by vegetation changed the thermal properties of the soil which resulted in a thinning of the active layer and ground ice aggradation in the upper part of the permafrost. These negative feedback effects contributed to permafrost recovery and ground ice aggradation. The latent heat of this ice-rich zone will act as a buffer to global warming and contributes to the long-term stability of the gullies in the new periglacial landscape. Fortier, D., Allard, M. 2004. Late Holocene Syngenetic Ice-wedge Polygons Development, Bylot Island, Canadian Arctic Archipelago. Canadian Journal of Earth Sciences, 41: 997-1012. Fortier, D., Allard, M., Shur, Y. 2007. Observation of Rapid Drainage System Development by Thermal Erosion of Ice Wedges on Bylot Island, Canadian Arctic Archipelago. Permafrost and Periglacial Processes, 18: 229-243. Godin, E., Fortier, D. (in press) Geomorphology of thermo-erosion gullies - case study from Bylot Island, Nunavut, Canada. Proceedings 6th Canadian Permafrost Conference and 63rd Canadian Geotechnical Conference, Calgary, October 2010.

Thermo-Reflectance Spectra of Eros: Unambiguous Detection of Olivine

NASA Technical Reports Server (NTRS)

Lucey, P. G.; Hinrichs, J. L.; Urquhart-Kelly, M.; Wellnitz, D.; Bell, J. F., III; Clark, B. E.

2001-01-01

Olivine is readily detected on 433 Eros using the new thermo-reflectance spectral technique applied to near-IR spectra obtained at Eros by the NEAR spacecraft. Additional information is contained in the original extended abstract.

Integrated optical transceiver with electronically controlled optical beamsteering

DOE Office of Scientific and Technical Information (OSTI.GOV)

Davids, Paul; DeRose, Christopher; Tauke-Pedretti, Anna

A beam-steering optical transceiver is provided. The transceiver includes one or more modules, each comprising an antenna chip and a control chip bonded to the antenna chip. Each antenna chip has a feeder waveguide, a plurality of row waveguides that tap off from the feeder waveguide, and a plurality of metallic nanoantenna elements arranged in a two-dimensional array of rows and columns such that each row overlies one of the row waveguides. Each antenna chip also includes a plurality of independently addressable thermo-optical phase shifters, each configured to produce a thermo-optical phase shift in a respective row. Each antenna chipmore » also has, for each row, a row-wise heating circuit configured to produce a respective thermo-optic phase shift at each nanoantenna element along its row. The control chip includes controllable current sources for the independently addressable thermo-optical phase shifters and the row-wise heating circuits.« less

Monolithic optofluidic mode coupler for broadband thermo- and piezo-optical characterization of liquids.

PubMed

Pumpe, Sebastian; Chemnitz, Mario; Kobelke, Jens; Schmidt, Markus A

2017-09-18

We present a monolithic fiber device that enables investigation of the thermo- and piezo-optical properties of liquids using straightforward broadband transmission measurements. The device is a directional mode coupler consisting of a multi-mode liquid core and a single-mode glass core with pronounced coupling resonances whose wavelength strongly depend on the operation temperature. We demonstrated the functionality and flexibility of our device for carbon disulfide, extending the current knowledge of the thermo-optic coefficient by 200 nm at 20 °C and uniquely for high temperatures. Moreover, our device allows measuring the piezo-optic coefficient of carbon disulfide, confirming results first obtained by Röntgen in 1891. Finally, we applied our approach to obtain the dispersion of the thermo-optic coefficients of benzene and tetrachloroethylene between 450 and 800 nm, whereas no data was available for the latter so far.

Biodegradable packing materials from hydrolysates of collagen waste proteins.

PubMed

Langmaier, F; Mokrejs, P; Kolomaznik, K; Mladek, M

2008-01-01

Enzymatic hydrolysates of waste collagen proteins (H), from current industrial manufacture (leather, edible meat product casings, etc.) of mean molecular mass 20-30 kDa by a reaction with dialdehyde starch (DAS), produces hydrogels applicable as biodegradable (or even edible) packaging materials for food, cosmetic and pharmaceutical products. Thermo-reversibility of prepared hydrogels is given by concentrations of H and DAS in a reaction mixture. At concentrations of H 25-30% (w/w) and that of DAS 15-20% (related to weight of hydrolysate), thermo-reversible hydrogels arise, which can be processed into packaging materials by a technique similar to that of soft gelatin capsules (SGC). Exceeding the limit of 20% DAS leads to hydrogels that are thermo-reversible only in part, a further increase in DAS concentration then leads to thermo-irreversible gels whose processing into biodegradable packaging materials necessitates employment of other procedures.

Thermo-optic characteristic of DNA thin solid film and its application as a biocompatible optical fiber temperature sensor.

PubMed

Hong, Seongjin; Jung, Woohyun; Nazari, Tavakol; Song, Sanggwon; Kim, Taeoh; Quan, Chai; Oh, Kyunghwan

2017-05-15

We report unique thermo-optical characteristics of DNA-Cetyl tri-methyl ammonium (DNA-CTMA) thin solid film with a large negative thermo-optical coefficient of -3.4×10^-4/°C in the temperature range from 20°C to 70°C without any observable thermal hysteresis. By combining this thermo-optic DNA film and fiber optic multimode interference (MMI) device, we experimentally demonstrated a highly sensitive compact temperature sensor with a large spectral shift of 0.15 nm/°C. The fiber optic MMI device was a concatenated structure with single-mode fiber (SMF)-coreless silica fiber (CSF)-single mode fiber (SMF) and the DNA-CTMA film was deposited on the CSF. The spectral shifts of the device in experiments were compared with the beam propagation method, which showed a good agreement.

Fiber Optic Thermo-Hygrometers for Soil Moisture Monitoring.

PubMed

Leone, Marco; Principe, Sofia; Consales, Marco; Parente, Roberto; Laudati, Armando; Caliro, Stefano; Cutolo, Antonello; Cusano, Andrea

2017-06-20

This work deals with the fabrication, prototyping, and experimental validation of a fiber optic thermo-hygrometer-based soil moisture sensor, useful for rainfall-induced landslide prevention applications. In particular, we recently proposed a new generation of fiber Bragg grating (FBGs)-based soil moisture sensors for irrigation purposes. This device was realized by integrating, inside a customized aluminum protection package, a FBG thermo-hygrometer with a polymer micro-porous membrane. Here, we first verify the limitations, in terms of the volumetric water content (VWC) measuring range, of this first version of the soil moisture sensor for its exploitation in landslide prevention applications. Successively, we present the development, prototyping, and experimental validation of a novel, optimized version of a soil VWC sensor, still based on a FBG thermo-hygrometer, but able to reliably monitor, continuously and in real-time, VWC values up to 37% when buried in the soil.

Fiber Optic Thermo-Hygrometers for Soil Moisture Monitoring

PubMed Central

Leone, Marco; Principe, Sofia; Consales, Marco; Parente, Roberto; Laudati, Armando; Caliro, Stefano; Cutolo, Antonello; Cusano, Andrea

2017-01-01

This work deals with the fabrication, prototyping, and experimental validation of a fiber optic thermo-hygrometer-based soil moisture sensor, useful for rainfall-induced landslide prevention applications. In particular, we recently proposed a new generation of fiber Bragg grating (FBGs)-based soil moisture sensors for irrigation purposes. This device was realized by integrating, inside a customized aluminum protection package, a FBG thermo-hygrometer with a polymer micro-porous membrane. Here, we first verify the limitations, in terms of the volumetric water content (VWC) measuring range, of this first version of the soil moisture sensor for its exploitation in landslide prevention applications. Successively, we present the development, prototyping, and experimental validation of a novel, optimized version of a soil VWC sensor, still based on a FBG thermo-hygrometer, but able to reliably monitor, continuously and in real-time, VWC values up to 37% when buried in the soil. PMID:28632172

Analytical Expressions for Thermo-Osmotic Permeability of Clays

NASA Astrophysics Data System (ADS)

Gonçalvès, J.; Ji Yu, C.; Matray, J.-M.; Tremosa, J.

2018-01-01

In this study, a new formulation for the thermo-osmotic permeability of natural pore solutions containing monovalent and divalent cations is proposed. The mathematical formulation proposed here is based on the theoretical framework supporting thermo-osmosis which relies on water structure alteration in the pore space of surface-charged materials caused by solid-fluid electrochemical interactions. The ionic content balancing the surface charge of clay minerals causes a disruption in the hydrogen bond network when more structured water is present at the clay surface. Analytical expressions based on our heuristic model are proposed and compared to the available data for NaCl solutions. It is shown that the introduction of divalent cations reduces the thermo-osmotic permeability by one third compared to the monovalent case. The analytical expressions provided here can be used to advantage for safety calculations in deep underground nuclear waste repositories.

Enhanced lipid production in thermo-tolerant mutants of Chlorella pyrenoidosa NCIM 2738.

PubMed

Sachdeva, Neha; Gupta, Ravi Prakash; Mathur, Anshu Shankar; Tuli, Deepak Kumar

2016-12-01

The present study aimed to develop thermo-tolerant mutants of Chlorella pyrenoidosa NCIM 2738 for high lipids production. For this, ethyl methane sulfonate was used, which generated two effective thermo-tolerant mutants, M18 and M24 of Chlorella pyrenoidosa NCIM 2738, capable of surviving at temperature up to 47°C and showing improved lipid and biomass yields. They showed 59.62% and 50.75% increase, respectively in lipid content compared to wild type at 30°C, which could not grow at temperature above 35°C. The novelty of this study lied in incorporation of PAM Flurometry with mutagenesis to generate thermo-tolerant mutants of C. pyrenoidosa and investigating the reasons for increased yields of mutants at cellular and photosynthetic levels with the aim to use them for commercial biodiesel production. Copyright © 2016 Elsevier Ltd. All rights reserved.

Thermo-optical properties and nonlinear optical response of smectic liquid crystals containing gold nanoparticles.

PubMed

de Melo, P B; Nunes, A M; Omena, L; do Nascimento, S M S; da Silva, M G A; Meneghetti, M R; de Oliveira, I N

2015-10-01

The present work is devoted to the study of the thermo-optical and nonlinear optical properties of smectic samples containing gold nanoparticles with different shapes. By using the time-resolved Z-scan technique, we determine the effects of nanoparticle addition on the critical behavior of the thermal diffusivity and thermo-optical coefficient at the vicinity of the smectic-A-nematic phase transition. Our results reveal that introduction of gold nanoparticles affects the temperature dependence of thermo-optical parameters, due to the local distortions in the orientational order and heat generation provided by guest particles during the laser exposure. Further, we show that a nonlinear optical response may take place at temperatures where the smectic order is well established. We provide a detailed discussion of the effects associated with the introduction gold nanoparticles on the mechanisms behind the thermal transport and optical nonlinearity in liquid-crystal samples.

Application of Thermo-Mechanical Measurements of Plastic Packages for Reliability Evaluation of PEMS

NASA Technical Reports Server (NTRS)

Sharma, Ashok K.; Teverovsky, Alexander

2004-01-01

Thermo-mechanical analysis (TMA) is typically employed for measurements of the glass transition temperature (Tg) and coefficients of thermal expansion (CTE) in molding compounds used in plastic encapsulated microcircuits (PEMs). Application of TMA measurements directly to PEMs allows anomalies to be revealed in deformation of packages with temperature, and thus indicates possible reliability concerns related to thermo-mechanical integrity and stability of the devices. In this work, temperature dependencies of package deformation were measured in several types of PEMs that failed environmental stress testing including temperature cycling, highly accelerated stress testing (HAST) in humid environments, and bum-in (BI) testing. Comparison of thermo-mechanical characteristics of packages and molding compounds in the failed parts allowed for explanation of the observed failures. The results indicate that TMA of plastic packages might be used for quality evaluation of PEMs intended for high-reliability applications.

High-pressure tolerance of earthworm fibrinolytic and digestive enzymes.

PubMed

Akazawa, Shin-Ichi; Tokuyama, Haruka; Sato, Shunsuke; Watanabe, Toshinori; Shida, Yosuke; Ogasawara, Wataru

2018-02-01

Earthworms contain several digestive and therapeutic enzymes that are beneficial to our health and useful for biomass utilization. Specifically, earthworms contain potent fibrinolytic enzymes called lumbrokinases, which are highly stable even at room temperature and remain active in dried earthworm powder. However, the high-temperature sterilization method leads to the inactivation of enzymes. Therefore, we investigated the effect of high-pressure treatment (HPT) (from 0.1 MPa to 500 MPa at 25°C and 50°C) on the enzymatic activity of lumbrokinase (LK), α-amylase (AMY), endoglucanase (EG), β-glucosidase (BGL), and lipase (LP) of the earthworm Eisenia fetida, Waki strain, and its sterilization ability in producing dietary supplement. LK showed thermo- and high-pressure tolerance. In addition, HPT may have resulted in pressure-induced stabilization and activation of LK. Although AMY activity was maintained up to 400 MPa at 25°C, the apparent activity decreased slightly at 50°C with HPT. EG showed almost the same pattern as AMY. However, it is possible that the effects of temperature and pressure compensated each other under 100 MPa at 50°C. BGL was shown to be a pressure- and temperature-sensitive enzyme, and LP showed a thermo- and high-pressure tolerance. The slight decrease in apparent activity occurred under 200 MPa at both temperatures. Furthermore, the low-temperature and pressure treatment completely sterilized the samples. These results provide a basis for the development of a novel earthworm dietary supplement with fibrinolytic and digestive activity and of high-pressure-tolerant enzymes to be used for biomass pretreatment. Copyright © 2017 The Society for Biotechnology, Japan. Published by Elsevier B.V. All rights reserved.

Characterization of the organic matter in submicron urban aerosols using a Thermo-Desorption Proton-Transfer-Reaction Time-of-Flight Mass Spectrometer (TD-PTR-TOF-MS)

NASA Astrophysics Data System (ADS)

Salvador, Christian Mark; Ho, T.-T.; Chou, Charles C.-K.; Chen, M.-J.; Huang, W.-R.; Huang, S.-H.

2016-09-01

Organic matter is the most complicated and unresolved major component of atmospheric aerosol particles. Its sources and global budget are still highly uncertain and thereby necessitate further research efforts with state-of-the-art instrument. This study employed a Thermo-Desorption Proton-Transfer-Reaction Time-of-Flight Mass Spectrometer (TD-PTR-TOF-MS) for characterization of ambient organic aerosols. First, five authentic standard substances, which include phthalic acid, levoglucosan, arabitol, cis-pinonic acid and glutaric acid, were utilized to examine the response of the instrument. The results demonstrated the linearity of the TD-PTR-TOF-MS signals against a range of mass loading of specific species on filters. However, it was found that significant fragmentation happened to those challenging compounds, although the proton-transfer-reaction (PTR) was recognized as a soft ionization technique. Consequently, quantitative characterization of aerosols with the TD-PTR-TOF-MS depended on the availability of the fragmentation pattern in mass spectra and the recovery rate with the quantification ion peak(s). The instrument was further deployed to analyze a subset of submicron aerosol samples collected at the TARO (Taipei Aerosol and Radiation Observatory) in Taipei, Taiwan during August 2013. The results were compared with the measurements from a conventional DRI thermo-optical carbon analyzer. The inter-comparison indicated that the TD-PTR-TOF-MS underestimated the mass of total organic matter (TOM) in aerosol samples by 27%. The underestimation was most likely due to the thermo-decomposition during desorption processes and fragmentation in PTR drift tube, where undetectable fragments were formed. Besides, condensation loss of low vapor pressure species in the transfer components was also responsible for the underestimation to a certain degree. Nevertheless, it was showed that the sum of the mass concentrations of the major detected ion peaks correlated strongly with the TOM determined by DRI analyzer (R2 = 0.8578), suggesting that the TD-PTR-TOF-MS measurements explained more than 85% of the variance in the time series of TOM. In addition to identification by comparing with the fragmentation pattern obtained from the mass spectra of the authentic substances, most of the major ions were attributed to protonated or acylium ions of specific parent compounds. Amongst the quantified species with full calibration with authentic standard, phthalic acid was found accounting for 7.0% of the mass loading of TOM. In addition, a high-end estimation of 9.4% was suggested for the mass contribution from glutaric acid, which was made by assuming that the ion with m/z of 73.027 was totally produced from fragmentation of glutaric acid as characterization of authentic standard despite of the formation of protonated methyl-glyoxal ion. Moreover, a substantial contribution from ions corresponding to protonated acetic acid and acetone was measured, which could be produced from fragmentation of larger oxygenated molecules. The TD-PTR-TOF-MS measurements suggested that low molecular weight carboxylic acid (LMWCA), products of photochemical oxidation of gaseous hydrocarbons and fatty acids, constituted a major fraction of secondary organic aerosols in Taipei, Taiwan, a typical subtropical urban area.

Using a two-lens afocal compensator for thermal defocus correction of catadioptric system

NASA Astrophysics Data System (ADS)

Ivanov, S. E.; Romanova, G. E.; Bakholdin, A. V.

2017-08-01

The work associates with the catadioptric systems with two-component afocal achromatic compensator. The most catadioptric systems with afocal compensator have the power mirror part and the correctional lens part. The correctional lens part can be in parallel, in convergent beam or in both. One of the problems of such systems design is the thermal defocus by reason of the thermal aberration and the housing thermal expansion. We introduce the technique of thermal defocus compensation by choosing the optical material of the afocal compensator components. The components should be made from the optical materials with thermo-optical characteristics so after temperature changing the compensator should become non-afocal with the optical power enough to compensate the image plane thermal shift. Abbe numbers of the components should also have certain values for correction chromatic aberrations that reduces essentially the applicable optical materials quantity. The catalogues of the most vendors of optical materials in visible spectral range are studied for the purpose of finding the suitable couples for the technique. As a result, the advantages and possibilities of the plastic materials application in combination with optical glasses are shown. The examples of the optical design are given.

Thermo-mechanical stress analysis of cryopreservation in cryobags and the potential benefit of nanowarming.

PubMed

Solanki, Prem K; Bischof, John C; Rabin, Yoed

2017-06-01

Cryopreservation by vitrification is the only promising solution for long-term organ preservation which can save tens of thousands of lives across the world every year. One of the challenges in cryopreservation of large-size tissues and organs is to prevent fracture formation due to the tendency of the material to contract with temperature. The current study focuses on a pillow-like shape of a cryobag, while exploring various strategies to reduce thermo-mechanical stress during the rewarming phase of the cryopreservation protocol, where maximum stresses are typically found. It is demonstrated in this study that while the level of stress may generally increase with the increasing amount of CPA filled in the cryobag, the ratio between width and length of the cryobag play a significant role. Counterintuitively, the overall maximum stress is not found when the bag is filled to its maximum capacity (when the filled cryobag resembles a sphere). Parametric investigation suggests that reducing the initial rewarming rate between the storage temperature and the glass transition temperature may dramatically decrease the thermo-mechanical stress. Adding a temperature hold during rewarming at the glass transition temperature may reduce the thermo-mechanical stress in some cases, but may have an adverse effect in other cases. Finally, it is demonstrated that careful incorporation of volumetric heating by means on nanoparticles in an alternating magnetic field, or nanowarming, can dramatically reduce the resulting thermo-mechanical stress. These observations display the potential benefit of a thermo-mechanical design of the cryopreservation protocols in order to prevent structural damage. Copyright © 2017 Elsevier Inc. All rights reserved.

Thermo-Optical Properties of Thin-Film TiO2–Al2O3 Bilayers Fabricated by Atomic Layer Deposition

PubMed Central

Ali, Rizwan; Saleem, Muhammad Rizwan; Pääkkönen, Pertti; Honkanen, Seppo

2015-01-01

We investigate the optical and thermo-optical properties of amorphous TiO2–Al2O3 thin-film bilayers fabricated by atomic layer deposition (ALD). Seven samples of TiO2–Al2O3 bilayers are fabricated by growing Al2O3 films of different thicknesses on the surface of TiO2 films of constant thickness (100 nm). Temperature-induced changes in the optical refractive indices of these thin-film bilayers are measured by a variable angle spectroscopic ellipsometer VASE®. The optical data and the thermo-optic coefficients of the films are retrieved and calculated by applying the Cauchy model and the linear fitting regression algorithm, in order to evaluate the surface porosity model of TiO2 films. The effects of TiO2 surface defects on the films’ thermo-optic properties are reduced and modified by depositing ultra-thin ALD-Al2O3 diffusion barrier layers. Increasing the ALD-Al2O3 thickness from 20 nm to 30 nm results in a sign change of the thermo-optic coefficient of the ALD-TiO2. The thermo-optic coefficients of the 100 nm-thick ALD-TiO2 film and 30 nm-thick ALD-Al2O3 film in a bilayer are (0.048 ± 0.134) × 10−4 °C−1 and (0.680 ± 0.313) × 10−4 °C−1, respectively, at a temperature T = 62 °C.

CAS-ATLID (co-alignment sensor of ATLID instrument) thermo-structural design and performance

NASA Astrophysics Data System (ADS)

Moreno, Javier; Serrano, Javier; González, David; Rodríguez, Gemma; Manjón, Andrés.; Vásquez, Eloi; Carretero, Carlos; Martínez, Berta

2017-11-01

This paper describes the main thermo-mechanical design features and performances of the Co-Alignment Sensor (CAS) developed by LIDAX and CRISA under ESA program with AIRBUS Defence and Space as industry prime.

Observing Muostakh Island disappear: erosion of a ground-ice-rich coast in response to summer warming and sea ice reduction on the East Siberian shelf

NASA Astrophysics Data System (ADS)

Günther, F.; Overduin, P. P.; Baranskaya, A.; Opel, T.; Grigoriev, M. N.

2013-08-01

Observations of coastline retreat using contemporary very high resolution satellite and historical aerial imagery were compared to measurements of open water fractions and summer air temperatures. We analyzed seasonal and interannual variations of thawing-induced cliff top retreat (thermo-denudation) and marine abrasion (thermo-abrasion) on Muostakh Island in the southern central Laptev Sea. The island is composed of ground-ice-rich permafrost deposits of Ice Complex type that render it particularly susceptible to erosion along the coast, resulting in land loss. Based on topographic reference measurements during field campaigns, we generated digital elevation models using stereophotogrammetry, in order to block adjust and ortho-rectify aerial photographies from 1951 and GeoEye, QuickBird, WorldView-1, and WorldView-2 imagery from 2010 to 2012 for change detection. Coastline retreat for erosive segments ranged from -13 to -585 m and was -109 ± 81 m (-1.8 ± 1.3 m a-1) on average during the historical period. Current seasonal dynamics of cliff top retreat revealed rapid thermo-denudation rates of -10.2 ± 4.5 m a-1 in mid summer and -4.1 ± 2.0 m a-1 on average during the 2010-2012 observation period. Using sea ice concentration data from the Special Sensor Microwave Imager (SSM/I) and air temperature time series from Tiksi, we calculated seasonal duration available for thermo-abrasion, expressed as open water days, and for thermo-denudation, based on thawing degree days. Geomorphometric analysis revealed that total ground ice content on Muostakh is made up of equal amounts of intrasedimentary and macro ground ice, while its vertical hourglass distribution provides favorable local preconditions for subsidence and the acceleration of coastal thermo-erosion under intensifying environmental forcings. Our results showed a~close relationship between mean summer air temperature and coastal thermo-erosion rates, in agreement with observations made for various permafrost coastlines different from East Siberian Ice Complex coasts elsewhere in the Arctic. Seasonality and recent interannual variations of coastline retreat rates suggest that the combination of macro ground ice distribution in the ground and changes in enviromental forcing generate a cyclicity in coastal thermo-erosion, that is currently increasing in frequency.

Development and application of W/Cu flat-type plasma facing components at ASIPP

NASA Astrophysics Data System (ADS)

Li, Q.; Zhao, S. X.; Sun, Z. X.; Xu, Y.; Li, B.; Wei, R.; Wang, W. J.; Qin, S. G.; Shi, Y. L.; Xie, C. Y.; Wang, J. C.; Wang, X. L.; Missirlian, M.; Guilhem, D.; Liu, G. H.; Yang, Z. S.; Luo, G.-N.

2017-12-01

W/Cu flat-type plasma facing components (PFCs) were widely used in divertor of fusion device because of its advantages, such as low cost, light in weight and good machinability. However, it is very difficult to manufacture them due to the large mismatch between the thermo-mechanical properties of W and Cu. Institute of Plasma Physics, Chinese Academy of Sciences (ASIPP) has successfully developed W/Cu flat-type PFCs for EAST W/Cu divertor project by hot isostatic pressing (HIP) technology. This paper presents the development and application of W/Cu flat-type PFCs at ASIPP. The optimized manufacturing process is to cast pure copper onto the rear side of W tiles at temperature of 1200 °C firstly, and then to HIP the W/Cu tiles onto CuCrZr heat sink at temperature of 600 °C, pressure of 150 MPa and duration of 3 h. W/Cu flat-type testing mock-up for EAST survived 1000 cycles at heat load of 5 MW m-2 in high heat flux tests. And then ASIPP prepared two mock-ups for CEA’s tungsten environment in steady-state tokamak (WEST) project. One mock-up withstood successfully 302 cycles of 20 MW m-2, which are far beyond the design requirement. Since 2014, W/Cu flat-type PFCs were wildly used in EAST upper divertor as baffle and dome components which showed excellent performance in 2015 and 2016 campaigns. Given the success in EAST upper divertor, W/Cu flat-type concept is as well applied in the design of actively cooled Langmuir probes which will be mounted onto EAST divertor targets soon.

Computational modeling of residual stress formation during the electron beam melting process for Inconel 718

DOE PAGES

Prabhakar, P.; Sames, William J.; Dehoff, Ryan R.; ...

2015-03-28

Here, a computational modeling approach to simulate residual stress formation during the electron beam melting (EBM) process within the additive manufacturing (AM) technologies for Inconel 718 is presented in this paper. The EBM process has demonstrated a high potential to fabricate components with complex geometries, but the resulting components are influenced by the thermal cycles observed during the manufacturing process. When processing nickel based superalloys, very high temperatures (approx. 1000 °C) are observed in the powder bed, base plate, and build. These high temperatures, when combined with substrate adherence, can result in warping of the base plate and affect themore » final component by causing defects. It is important to have an understanding of the thermo-mechanical response of the entire system, that is, its mechanical behavior towards thermal loading occurring during the EBM process prior to manufacturing a component. Therefore, computational models to predict the response of the system during the EBM process will aid in eliminating the undesired process conditions, a priori, in order to fabricate the optimum component. Such a comprehensive computational modeling approach is demonstrated to analyze warping of the base plate, stress and plastic strain accumulation within the material, and thermal cycles in the system during different stages of the EBM process.« less

Biot number and thermos bottle effect: implications for magma-chamber convection

DOE Office of Scientific and Technical Information (OSTI.GOV)

Carrigan, C.R.

1988-09-01

Thermal boundary conditions model the coupling between a convecting magmatic body and its host. Such conditions need to be considered in models of igneous systems that involve thermal histories, crystallization and fractionation of melt, formation of aureoles by contact metamorphism, and any other processes in which transport of heat plays a role. Usually, investigations of magmatic systems have tended to emphasize modeling the interior convective regime relative to treatment of the thermal coupling. Yet it is found that the thermal nature of an intrusion is likely to be influenced more by coupling to its host than by the details ofmore » internal convective flows. Evaluation of a parameter having the form of a Biot number (Bi) provides a basis for estimating which boundary conditions are most appropriate. It is found that Bi less than or equal to 0.1 (constant heat-flux limit) for models of several caldera systems. For such values of the Biot number, the host regime behaves somewhat like a thermos bottle by limiting the flow of heat through the magma-host system so that convective stirring of magma has little effect on the cooling rate of the intrusion. Because of this insulating effect, boundary temperatures assumed in convection models should approach magmatic values even if an active hydrothermal system is present. However, high boundary temperatures do not imply that melting and assimilation of host rock by magma must occur. Despite the thermos bottle effect, magmatic convection can still be quite vigorous.« less

Infrared sensing of non-observable human biometrics

NASA Astrophysics Data System (ADS)

Willmore, Michael R.

2005-05-01

Interest and growth of biometric recognition technologies surged after 9/11. Once a technology mainly used for identity verification in law enforcement, biometrics are now being considered as a secure means of providing identity assurance in security related applications. Biometric recognition in law enforcement must, by necessity, use attributes of human uniqueness that are both observable and vulnerable to compromise. Privacy and protection of an individual's identity is not assured during criminal activity. However, a security system must rely on identity assurance for access control to physical or logical spaces while not being vulnerable to compromise and protecting the privacy of an individual. The solution resides in the use of non-observable attributes of human uniqueness to perform the biometric recognition process. This discussion will begin by presenting some key perspectives about biometric recognition and the characteristic differences between observable and non-observable biometric attributes. An introduction to the design, development, and testing of the Thermo-ID system will follow. The Thermo-ID system is an emerging biometric recognition technology that uses non-observable patterns of infrared energy naturally emanating from within the human body. As with all biometric systems, the infrared patterns recorded and compared within the Thermo-ID system are unique and individually distinguishable permitting a link to be confirmed between an individual and a claimed or previously established identity. The non-observable characteristics of infrared patterns of human uniqueness insure both the privacy and protection of an individual using this type of biometric recognition system.

Bonding of wood fiber composites using a synthetic chelator-lignin activation system

Treesearch

D. Yelle; B. Goodell; D.J. Gardner; A. Amirbahman; P. Winistofer; S. Shaler

2004-01-01

Wood fibers, after thermo-mechanical pulping, have a high concentration of lignin on the outer surface of the fiber; the residual middle lamella of the woody cell wall. When wood fibers are oxidatively treated with a chelator produced by Gloeophyllum trabeum (a brown-rot fungus), in the presence of hydrogen peroxide (H2O2) and ferric iron (FeIII), free radicals are...

Proof-of-Principle Dermal Decontamination Experiments: Swine Skin

DTIC Science & Technology

2007-04-01

approvals it was decided to first demonstrate the proof-of-principle of dermal decontamination for this model using swine skin samples ex vivo . When...appropriate individual protection equipment (IPE) and dosimetry . 3. All activities were monitored by the DRDC Ottawa RadSO. 4. The workstation...while working with the radionuclides, as well as the necessary dosimetry . All personnel wore standard Health Canada issued thermo- luminescent

Reconfigurable Integrated Optoelectronics

DTIC Science & Technology

2011-01-01

state -changing could be done also using thermo-optical, mechano-optical, magneto-optical or opto-optical inputs. The speed of reconfiguration can be fast... quantum computers, is a futuristic activity; however, Jeremy O’Brien believes that the time horizon for OQC suc- cess can be brought closer in by using ...2011 Richard Soref. This is an open access article distributed under the Creative Commons Attribution License, which permits unrestricted use

4. BUILDING NO. 404, THERMO CHEMISTRY LABORATORY, LOOKING SOUTHEAST AT ...

Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

4. BUILDING NO. 404, THERMO CHEMISTRY LABORATORY, LOOKING SOUTHEAST AT SOUTH AND WEST SIDES OF BUILDING. ORIGINALLY USED AS A STOREHOUSE. - Picatinny Arsenal, 400 Area, Gun Bag Loading District, State Route 15 near I-80, Dover, Morris County, NJ

5. BUILDING NO. 404, THERMO CHEMISTRY LABORATORY, LOOKING NORTHWEST AT ...

Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

5. BUILDING NO. 404, THERMO CHEMISTRY LABORATORY, LOOKING NORTHWEST AT SOUTH SIDE OF BUILDING. BUILDING NO. 403 IN BACKGROUND RIGHT. - Picatinny Arsenal, 400 Area, Gun Bag Loading District, State Route 15 near I-80, Dover, Morris County, NJ

Web Thermo Tables (WTT) - Lite Edition

National Institute of Standards and Technology Data Gateway

SRD 202 NIST/TRC Web Thermo Tables (WTT) - Lite Edition (Online Subscription)   WTT - Lite Edition, a Web version of the TRC Thermodynamic Tables, represents a collection of critically evaluated thermodynamic property data for 150 commonly-used (primarily organic) pure compounds.

Biocompatible patterning of proteins on wettability gradient surface by thermo-transfer printing.

PubMed

Kim, Sungho; Ryu, Yong-Sang; Suh, Jeng-Hun; Keum, Chang-Min; Sohn, Youngjoo; Lee, Sin-Doo

2014-08-01

We develop a simple and biocompatible method of patterning proteins on a wettability gradient surface by thermo-transfer printing. The wettability gradient is produced on a poly(dimethylsiloxane) (PDMS)-modified glass substrate through the temperature gradient during thermo-transfer printing. The water contact angle on the PDMS-modified surface is found to gradually increase along the direction of the temperature gradient from a low to a high temperature region. Based on the wettability gradient, the gradual change in the adsorption and immobilization of proteins (cholera toxin B subunit) is achieved in a microfluidic cell with the PDMS-modified surface.

Thermo-optical properties of 1H[3,4-b] quinoline films used in electroluminescent devices

NASA Astrophysics Data System (ADS)

Jaglarz, Janusz; Kępińska, Mirosława; Sanetra, Jerzy

2014-06-01

Electroluminescence cells with H[3,4-b] quinoline layers are promising devices for a blue light emitting EL diode. This work measured the optical reflectance as a function of temperature in copolymers PAQ layers deposited on Si crystalline substrate. Using the extended Cauchy dispersion model of the film refractive index we determined the thermo-optical coefficients for quinoline layers in the temperature range of 76-333 K from combined ellipsometric and spectrofotometric studies. The obtained values of thermo-optical coefficients of thin PAQ film, were negative and ranged in 5-10 × 10-4 [1/K].

Design and synthesis study of the thermo-sensitive poly (N-vinylpyrrolidone-b- N, N-diethylacrylamide).

PubMed

Zhang, Xiayun; Yang, Zhongduo; Xie, Dengmin; Liu, Donglei; Chen, Zhenbin; Li, Ke; Li, Zhizhong; Tichnell, Brandon; Liu, Zhen

2018-01-01

The reversible addition fragmentation chain transfer (RAFT) polymerization method was adopted here to prepare a series of thermo-sensitive copolymers, poly (N,N-diethyl- acrylamide-b-N-vinylpyrrolidone). Their structures, molecular weight distribution and temperature sensitivity performances were characterized by the nuclear magnetic resonance ( 1 HNMR), the gel permeation chromatography (GPC) and the fluorescence spectrophotometer, respectively. It has been identified that the synthesis reaction of the block copolymer was living polymerization. The thermo-sensitivity study suggested that N-vinylpyrrolidone (NVP), played a key role on the lower critical solution temperature (LCST) performance.

Sustained release of VEGF from PLGA nanoparticles embedded thermo-sensitive hydrogel in full-thickness porcine bladder acellular matrix

NASA Astrophysics Data System (ADS)

Geng, Hongquan; Song, Hua; Qi, Jun; Cui, Daxiang

2011-12-01

We fabricated a novel vascular endothelial growth factor (VEGF)-loaded poly(lactic- co-glycolic acid) (PLGA)-nanoparticles (NPs)-embedded thermo-sensitive hydrogel in porcine bladder acellular matrix allograft (BAMA) system, which is designed for achieving a sustained release of VEGF protein, and embedding the protein carrier into the BAMA. We identified and optimized various formulations and process parameters to get the preferred particle size, entrapment, and polydispersibility of the VEGF-NPs, and incorporated the VEGF-NPs into the (poly(ethylene oxide)-poly(propylene oxide)-poly(ethylene oxide) (Pluronic®) F127 to achieve the preferred VEGF-NPs thermo-sensitive gel system. Then the thermal behavior of the system was proven by in vitro and in vivo study, and the kinetic-sustained release profile of the system embedded in porcine bladder acellular matrix was investigated. Results indicated that the bioactivity of the encapsulated VEGF released from the NPs was reserved, and the VEGF-NPs thermo-sensitive gel system can achieve sol-gel transmission successfully at appropriate temperature. Furthermore, the system can create a satisfactory tissue-compatible environment and an effective VEGF-sustained release approach. In conclusion, a novel VEGF-loaded PLGA NPs-embedded thermo-sensitive hydrogel in porcine BAMA system is successfully prepared, to provide a promising way for deficient bladder reconstruction therapy.

Thermo-electrochemical analysis of lithium ion batteries for space applications using Thermal Desktop

NASA Astrophysics Data System (ADS)

Walker, W.; Ardebili, H.

2014-12-01

Lithium-ion batteries (LIBs) are replacing the Nickel-Hydrogen batteries used on the International Space Station (ISS). Knowing that LIB efficiency and survivability are greatly influenced by temperature, this study focuses on the thermo-electrochemical analysis of LIBs in space orbit. Current finite element modeling software allows for advanced simulation of the thermo-electrochemical processes; however the heat transfer simulation capabilities of said software suites do not allow for the extreme complexities of orbital-space environments like those experienced by the ISS. In this study, we have coupled the existing thermo-electrochemical models representing heat generation in LIBs during discharge cycles with specialized orbital-thermal software, Thermal Desktop (TD). Our model's parameters were obtained from a previous thermo-electrochemical model of a 185 Amp-Hour (Ah) LIB with 1-3 C (C) discharge cycles for both forced and natural convection environments at 300 K. Our TD model successfully simulates the temperature vs. depth-of-discharge (DOD) profiles and temperature ranges for all discharge and convection variations with minimal deviation through the programming of FORTRAN logic representing each variable as a function of relationship to DOD. Multiple parametrics were considered in a second and third set of cases whose results display vital data in advancing our understanding of accurate thermal modeling of LIBs.

Thermo-sensitively and magnetically ordered mesoporous carbon nanospheres for targeted controlled drug release and hyperthermia application.

PubMed

Chen, Lin; Zhang, Huan; Zheng, Jing; Yu, Shiping; Du, Jinglei; Yang, Yongzhen; Liu, Xuguang

2018-03-01

A multifunctional nanoplatform based on thermo-sensitively and magnetically ordered mesoporous carbon nanospheres (TMOMCNs) is developed for effective targeted controlled release of doxorubicin hydrochloride (DOX) and hyperthermia in this work. The morphology, specific surface area, porosity, thermo-stability, thermo-sensitivity, as well as magnetism properties of TMOMCNs were verified by high resolution transmission electron microscopy, field emission scanning electron microscopy, thermo-gravimetric analysis, X-ray diffraction, Brunauer-Emmeltt-Teller surface area analysis, dynamic light scattering and vibrating sample magnetometry measurement. The results indicate that TMOMCNs have an average diameter of ~146nm with a lower critical solution temperature at around 39.5°C. They are superparamagnetic with a magnetization of 10.15emu/g at 20kOe. They generate heat when inductive magnetic field is applied to them and have a normalized specific absorption rate of 30.23W/g at 230kHz and 290Oe, showing good potential for hyperthermia. The DOX loading and release results illustrate that the loading capacity is 135.10mg/g and release performance could be regulated by changing pH and temperature. The good targeting, DOX loading and release and hyperthermia properties of TMOMCNs offer new probabilities for high effectiveness and low toxicity of cancer chemotherapy. Copyright © 2017 Elsevier B.V. All rights reserved.

Solar-driven thermo- and electrochemical degradation of nitrobenzene in wastewater: Adaptation and adoption of solar STEP concept.

PubMed

Gu, Di; Shao, Nan; Zhu, Yanji; Wu, Hongjun; Wang, Baohui

2017-01-05

The STEP concept has successfully been demonstrated for driving chemical reaction by utilization of solar heat and electricity to minimize the fossil energy, meanwhile, maximize the rate of thermo- and electrochemical reactions in thermodynamics and kinetics. This pioneering investigation experimentally exhibit that the STEP concept is adapted and adopted efficiently for degradation of nitrobenzene. By employing the theoretical calculation and thermo-dependent cyclic voltammetry, the degradation potential of nitrobenzene was found to be decreased obviously, at the same time, with greatly lifting the current, while the temperature was increased. Compared with the conventional electrochemical methods, high efficiency and fast degradation rate were markedly displayed due to the co-action of thermo- and electrochemical effects and the switch of the indirect electrochemical oxidation to the direct one for oxidation of nitrobenzene. A clear conclusion on the mechanism of nitrobenzene degradation by the STEP can be schematically proposed and discussed by the combination of thermo- and electrochemistry based the analysis of the HPLC, UV-vis and degradation data. This theory and experiment provide a pilot for the treatment of nitrobenzene wastewater with high efficiency, clean operation and low carbon footprint, without any other input of energy and chemicals from solar energy. Copyright © 2016 Elsevier B.V. All rights reserved.

Synthesis and characterization of PEPO grafted carboxymethyl guar and carboxymethyl tamarind as new thermo-associating polymers.

PubMed

Gupta, Nivika R; Torris A T, Arun; Wadgaonkar, Prakash P; Rajamohanan, P R; Ducouret, Guylaine; Hourdet, Dominique; Creton, Costantino; Badiger, Manohar V

2015-03-06

New thermo associating polymers were designed and synthesized by grafting amino terminated poly(ethylene oxide-co-propylene oxide) (PEPO) onto carboxymethyl guar (CMG) and carboxymethyl tamarind (CMT). The grafting was performed by coupling reaction between NH2 groups of PEPO and COOH groups of CMG and CMT using water-soluble EDC/NHS as coupling agents. The grafting efficiency and the temperature of thermo-association, T(assoc) in the copolymer were studied by NMR spectroscopy. The graft copolymers, CMG-g-PEPO and CMT-g-PEPO exhibited interesting thermo-associating behavior which was evidenced by the detailed rheological and fluorescence measurements. The visco-elastic properties (storage modulus, G'; loss modulus, G") of the copolymer solutions were investigated using oscillatory shear experiments. The influence of salt and surfactant on the T(assoc) was also studied by rheology, where the phenomenon of "Salting out" and "Salting in" was observed for salt and surfactant, respectively, which can give an easy access to tunable properties of these copolymers. These thermo-associating polymers with biodegradable nature of CMG and CMT can have potential applications as smart injectables in controlled release technology and as thickeners in cosmetics and pharmaceutical formulations. Copyright © 2014 Elsevier Ltd. All rights reserved.

Cytological characterization of a thermo-sensitive cytoplasmic male-sterile wheat line having K-type cytoplasm of Aegilops kotschyi.

PubMed

Meng, Liying; Liu, Zihan; Zhang, Lingli; Hu, Gan; Song, Xiyue

2016-12-01

Male sterility is an important tool for obtaining crop heterosis. A thermo-sensitive cytoplasmic male-sterile (TCMS) line was developed recently using a new method based on tiller regeneration. In the present study, we explored the critical growth stages required to maintain thermo-sensitive male sterility in TCMS lines and found that fertility is associated with abnormal tapetal and microspore development. We investigated the fertility and cytology of temperature-treated plant anthers at various developmental stages. TCMS line KTM3315A exhibited thermo-sensitive male sterility in Zadoks growth stages 41-49 and 58-59. Morphologically, the line exhibited thermo-sensitive male sterility at 3-9 days before heading and at 3-6 days before flowering, and it was partially restored in three locations during spring and summer. TCMS line KTM3315A plants exhibited premature tapetal programmed cell death (PCD) from the early uninucleate stage of microspore development until the tapetal cells degraded completely. Microspore development was then blocked and the pollen abortion type was stainable abortion. Thus, male fertility in the line KTM3315A is sensitive to temperature and premature tapetal PCD is the main cause of pollen abortion, where it determines the starting period and affects male fertility conversion in K-type TCMS lines at certain temperatures.

Effect of Yb doping on the refractive index and thermo-optic coefficient of YVO₄ single crystals.

PubMed

Soharab, M; Bhaumik, Indranil; Bhatt, R; Saxena, A; Karnal, A K; Gupta, P K

2017-02-20

Single crystals of YVO₄ with different doping concentrations of Yb (1.5, 3.0, 8.0, and 15.0 at. %) and with good crystalline quality (FWHM ∼43-55 arc sec of rocking curve) were grown by the optical floating zone technique. Refractive index measurements were carried out at four wavelengths as a function of temperature. The measurements show that as the doping concentration of Yb is increased, the refractive index varies marginally for n_e whereas there is a significant change in the value of n_o. The thermo-optic coefficient (dn/dT) was found to be positive with a value ∼10^-5/°C, which is 1 order higher than that for the undoped YVO₄ crystal. The thermo-optic coefficient is higher for n_e compared to that of n_o. Also, a set of relations describing the wavelength dependence of the thermo-optic coefficient were established that are useful for calculating the thermo-optic coefficient at any temperature in the range 30°C-150°C and at any wavelength in the range 532-1551 nm.

Development of Advanced Environmental Barrier Coatings for SiC/SiC Composites at NASA GRC: Prime-Reliant Design and Durability Perspectives

NASA Technical Reports Server (NTRS)

Zhu, Dongming

2017-01-01

Environmental barrier coatings (EBCs) are considered technologically important because of the critical needs and their ability to effectively protect the turbine hot-section SiC/SiC ceramic matrix composite (CMC) components in harsh engine combustion environments. The development of NASA's advanced environmental barrier coatings have been aimed at significantly improved the coating system temperature capability, stability, erosion-impact, and CMAS resistance for SiC/SiC turbine airfoil and combustors component applications. The NASA environmental barrier coating developments have also emphasized thermo-mechanical creep and fatigue resistance in simulated engine heat flux and environments. Experimental results and models for advanced EBC systems will be presented to help establishing advanced EBC composition design methodologies, performance modeling and life predictions, for achieving prime-reliant, durable environmental coating systems for 2700-3000 F engine component applications. Major technical barriers in developing environmental barrier coating systems and the coating integration with next generation composites having further improved temperature capability, environmental stability, EBC-CMC fatigue-environment system durability will be discussed.

Plasma facing components: a conceptual design strategy for the first wall in FAST tokamak

NASA Astrophysics Data System (ADS)

Labate, C.; Di Gironimo, G.; Renno, F.

2015-09-01

Satellite tokamaks are conceived with the main purpose of developing new or alternative ITER- and DEMO-relevant technologies, able to contribute in resolving the pending issues about plasma operation. In particular, a high criticality needs to be associated to the design of plasma facing components, i.e. first wall (FW) and divertor, due to physical, topological and thermo-structural reasons. In such a context, the design of the FW in FAST fusion plant, whose operational range is close to ITER’s one, takes place. According to the mission of experimental satellites, the FW design strategy, which is presented in this paper relies on a series of innovative design choices and proposals with a particular attention to the typical key points of plasma facing components design. Such an approach, taking into account a series of involved physical constraints and functional requirements to be fulfilled, marks a clear borderline with the FW solution adopted in ITER, in terms of basic ideas, manufacturing aspects, remote maintenance procedure, manifolds management, cooling cycle and support system configuration.

Upper- and mid-mantle interaction between the Samoan plume and the Tonga-Kermadec slabs

NASA Astrophysics Data System (ADS)

Chang, Sung-Joon; Ferreira, Ana M. G.; Faccenda, Manuele

2016-02-01

Mantle plumes are thought to play a key role in transferring heat from the core-mantle boundary to the lithosphere, where it can significantly influence plate tectonics. On impinging on the lithosphere at spreading ridges or in intra-plate settings, mantle plumes may generate hotspots, large igneous provinces and hence considerable dynamic topography. However, the active role of mantle plumes on subducting slabs remains poorly understood. Here we show that the stagnation at 660 km and fastest trench retreat of the Tonga slab in Southwestern Pacific are consistent with an interaction with the Samoan plume and the Hikurangi plateau. Our findings are based on comparisons between 3D anisotropic tomography images and 3D petrological-thermo-mechanical models, which self-consistently explain several unique features of the Fiji-Tonga region. We identify four possible slip systems of bridgmanite in the lower mantle that reconcile the observed seismic anisotropy beneath the Tonga slab (VSH>VSV) with thermo-mechanical calculations.

Cryo-optical testing of large aspheric reflectors operating in the sub mm range

NASA Astrophysics Data System (ADS)

Roose, S.; Houbrechts, Y.; Mazzoli, A.; Ninane, N.; Stockman, Y.; Daddato, R.; Kirschner, V.; Venacio, L.; de Chambure, D.

2006-02-01

The cryo-optical testing of the PLANCK primary reflector (elliptical off-axis CFRP reflector of 1550 mm x 1890 mm) is one of the major issue in the payload development program. It is requested to measure the changes of the Surface Figure Error (SFE) with respect to the best ellipsoid, between 293 K and 50 K, with a 1 μm RMS accuracy. To achieve this, Infra Red interferometry has been used and a dedicated thermo mechanical set-up has been constructed. This paper summarises the test activities, the test methods and results on the PLANCK Primary Reflector - Flight Model (PRFM) achieved in FOCAL 6.5 at Centre Spatial de Liege (CSL). Here, the Wave Front Error (WFE) will be considered, the SFE can be derived from the WFE measurement. After a brief introduction, the first part deals with the general test description. The thermo-elastic deformations will be addressed: the surface deformation in the medium frequency range (spatial wavelength down to 60 mm) and core-cell dimpling.

Immobilization of natural anti-oxidants on carbon nanotubes and aging behavior of ultra-high molecular weight polyethylene-based nanocomposites

NASA Astrophysics Data System (ADS)

Dintcheva, Nadka Tzankova; Arrigo, Rossella; Gambarotti, Cristian; Guenzi, Monica; Carroccio, Sabrina; Cicogna, Francesca; Filippone, Giovanni

2014-05-01

The use of natural antioxidants is an attractive way to formulate nanocomposites with extended durability and with potential applications in bio-medical field. In this work, Vitamin E (VE) in the form of α-tocopherol and Quercetin (Q) are physically immobilized on the outer surface of multi-walled carbon nanotubes (CNTs). Afterward, the CNTs-VE and CNTs-Q are used to formulate thermally stable ultra high molecular weight polyethylene based nanocomposites. The obtained results in the study of the thermo-oxidation behavior suggest a beneficial effect of the natural anti-oxidant carbon nanotubes systems. The unexpected excellent thermo-resistance of the nanocomposites seems to be due to a synergistic effect of the natural anti-oxidant and carbon nanotubes, i.e. strong interaction between CNT surface and anti-oxidant molecules. Particularly, these interactions cause the formation of structural defects onto outer CNT surfaces, which, in turn, increase the CNT radical scavenging activity.

Electrochemical product detection of an asymmetric convective polymerase chain reaction.

PubMed

Duwensee, Heiko; Mix, Maren; Stubbe, Marco; Gimsa, Jan; Adler, Marcel; Flechsig, Gerd-Uwe

2009-10-15

For the first time, we describe the application of heated microwires for an asymmetric convective polymerase chain reaction (PCR) in a modified PCR tube in a small volume. The partly single-stranded product was labeled with the electrochemically active compound osmium tetroxide bipyridine using a partially complementary protective strand with five mismatches compared to the single-stranded product. The labeled product could be successfully detected at a gold electrode modified with a complementary single-stranded capture probe immobilized via a thiol-linker. Our simple thermo-convective PCR yielded electrochemically detectable products after only 5-10 min. A significant discrimination between complementary and non-complementary target was possible using different immobilized capture probes. The total product yield was approx. half the amount of the classical thermocycler PCR. Numerical simulations describing the thermally driven convective PCR explain the received data. Discrimination between complementary capture probes and non-complementary capture probes was performed using square-wave voltammetry. The coupling of asymmetric thermo-convective PCR with electrochemical detection is very promising for future compact DNA sensor devices.

Comparative analysis of the main bioactive components of Xin-Sheng-Hua granule and its single herbs by ultrahigh performance liquid chromatography with tandem mass spectrometry.

PubMed

Pang, Hanqing; Wang, Jun; Tang, Yuping; Xu, Huiqin; Wu, Liang; Jin, Yi; Zhu, Zhenhua; Guo, Sheng; Shi, Xuqin; Huang, Shengliang; Sun, Dazheng; Duan, Jin-Ao

2016-11-01

Xin-Sheng-Hua granule, a representative formula for postpartum hemorrhage, has been used clinically to treat postpartum diseases. Its main bioactive components comprise aromatic acids, phthalides, alkaloids, flavonoids, and gingerols among others. To investigate the changes in main bioactive constituents in its seven single herbs before and after compatibility, a rapid, simple, and sensitive method was developed for comparative analysis of 27 main bioactive components by using ultrahigh-performance liquid chromatography with triple quadrupole electrospray tandem mass spectrometry for the first time. The sufficient separation of 27 target constituents was achieved on a Thermo Scientific Hypersil GOLD column (100 mm × 3 mm, 1.9 μm) within 20 min under the optimized chromatographic conditions. Compared with the theoretical content, the observed content of each analyte showed remarkable differences in Xin-Sheng-Hua granule except thymine, p-coumaric acid, senkyunolide I, senkyunolide H, and ligustilide; the total contents of 27 components increased significantly, and the content variation degrees for the different components were gingerols > flavonoids > aromatic acids > alkaloids > phthalides. The results could provide a good reference for the quality control of Xin-Sheng-Hua granule and might be helpful to interpret the drug interactions based on variation of bioactive components in formulae. © 2016 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

Statistical Analysis of CMC Constituent and Processing Data

NASA Technical Reports Server (NTRS)

Fornuff, Jonathan

2004-01-01

Ceramic Matrix Composites (CMCs) are the next "big thing" in high-temperature structural materials. In the case of jet engines, it is widely believed that the metallic superalloys currently being utilized for hot structures (combustors, shrouds, turbine vanes and blades) are nearing their potential limits of improvement. In order to allow for increased turbine temperatures to increase engine efficiency, material scientists have begun looking toward advanced CMCs and SiC/SiC composites in particular. Ceramic composites provide greater strength-to-weight ratios at higher temperatures than metallic alloys, but at the same time require greater challenges in micro-structural optimization that in turn increases the cost of the material as well as increases the risk of variability in the material s thermo-structural behavior. to model various potential CMC engine materials and examines the current variability in these properties due to variability in component processing conditions and constituent materials; then, to see how processing and constituent variations effect key strength, stiffness, and thermal properties of the finished components. Basically, this means trying to model variations in the component s behavior by knowing what went into creating it. inter-phase and manufactured by chemical vapor infiltration (CVI) and melt infiltration (MI) were considered. Examinations of: (1) the percent constituents by volume, (2) the inter-phase thickness, (3) variations in the total porosity, and (4) variations in the chemical composition of the Sic fiber are carried out and modeled using various codes used here at NASA-Glenn (PCGina, NASALife, CEMCAN, etc...). The effects of these variations and the ranking of their respective influences on the various thermo-mechanical material properties are studied and compared to available test data. The properties of the materials as well as minor changes to geometry are then made to the computer model and the detrimental effects observed using statistical analysis software. The ultimate purpose of this study is to determine what variations in material processing can lead to the most critical changes in the materials property. The work I have taken part in this summer explores, in general, the key properties needed In this study SiC/SiC composites of varying architectures, utilizing a boron-nitride (BN)

Thermosensitive transient receptor potential channels (thermo-TRPs) in human corneal epithelial cells

PubMed Central

Mergler, Stefan; Garreis, Fabian; Sahlmüller, Monika; Reinach, Peter S.; Paulsen, Friedrich; Pleyer, Uwe

2010-01-01

Thermosensitive transient receptor potential proteins (TRPs) such as TRPV1-TRPV4 are all heat-activated non-selective cation channels that are modestly permeable to Ca2+. TRPV1, TRPV3 and TRPV4 functional expression were previously identified in human corneal epithelial cells (HCEC). However, the membrane currents were not described underlying their activation by either selective agonists or thermal variation. This study characterized the membrane currents and [Ca 2+]i transients induced by thermal and agonist TRPV1 and 4 stimulation. TRPV1 and 4 expressions were confirmed by RT-PCR and TRPV2 transcripts were also detected. In fura2-loaded HCEC, a TRPV1-3 selective agonist, 100 µM 2-aminoethoxydiphenyl borate (2-APB), induced intracellular Ca2+ transients and an increase in non-selective cation outward currents that were suppressed by ruthenium-red (RuR) (10–20 µM), a nonselective TRPV channel blocker. These changes were also elicited by rises in ambient temperature from 25 °C to over 40 °C. RuR (5 µM) and a selective TRPV1 channel blocker capsazepine (CPZ) (10 µM) or another related blocker, lanthanum chloride (La3+) (100 µM) suppressed these temperature-induced Ca2+ increases. Planar patch-clamp technique was used to characterize the currents underlying Ca2+ transients. Increasing the temperature to over 40 °C induced reversible rises in non-selective cation currents. Moreover, a hypotonic challenge (25 %) increased non-selective cation currents confirming TRPV4 activity. We conclude that HCEC possess in addition to thermo-sensitive TRPV3 activity TRPV1, TRPV2 and TRPV4 activity. Their activation confers temperature sensitivity at the ocular surface, which may protect the cornea against such stress. PMID:21506114

Hydrazine-induced thermo-reversible optical shifts in silver-gelatin bionanocomposites

NASA Astrophysics Data System (ADS)

Aimé, Carole; Rietveld, Ivo B.; Coradin, Thibaud

2011-03-01

Bionanocomposites formed by in situ growth of silver nanoparticles within gelatin gels exhibit large (up to 100 nm) thermo-reversible optical shifts resulting from the enhancement of gel matrix scattering by the interaction of the biopolymer with the hydrazine reducing agent.

Physical modeling and characterization of thermo-acoustic loudspeakers made of silver nano-wire films

NASA Astrophysics Data System (ADS)

La Torraca, P.; Larcher, L.; Bobinger, M.; Pavan, P.; Seeber, B.; Lugli, P.

2017-06-01

Recent developments of ultra-low heat capacity nanostructured materials revived the interest in the thermo-acoustic (TA) loudspeaker technology, which shows important advantages compared to the classical dynamic loudspeakers as they feature a lower cost and weight, flexibility, conformability to the surface of various shapes, and transparency. The development of the TA loudspeaker technology requires accurate physical models connecting the material properties to the thermal and acoustic speaker's performance. We present here a combined theoretical and experimental analysis of TA loudspeakers, where the electro-thermal and the thermo-acoustic transductions are handled separately, thus allowing an in-depth description of both the pressure and temperature dynamics. The electro-thermal transduction is analyzed by accounting for all the heat flow processes taking place between the TA loudspeaker and the surrounding environment, with focus on their frequency dependence. The thermo-acoustic conversion is studied by solving the coupled thermo-acoustic equations, derived from the Navier-Stokes equations, and by exploiting the Huygens-Fresnel principle to decompose the TA loudspeaker surface into a dense set of TA point sources. A general formulation of the 3D pressure field is derived summing up the TA point source contributions via a Rayleigh integral. The model is validated against temperature and sound pressure level measured on the TA loudspeaker sample made of a Silver Nanowire random network deposited on a polyimide substrate. A good agreement is found between measurements and simulations, demonstrating that the model is capable of connecting material properties to the thermo-acoustic performance of the device, thus providing a valuable tool for the design and optimization of TA loudspeakers.

Use of thermo-coagulation as an alternative treatment modality in a 'screen-and-treat' programme of cervical screening in rural Malawi.

PubMed

Campbell, Christine; Kafwafwa, Savel; Brown, Hilary; Walker, Graeme; Madetsa, Belito; Deeny, Miriam; Kabota, Beatrice; Morton, David; Ter Haar, Reynier; Grant, Liz; Cubie, Heather A

2016-08-15

The incidence of cervical cancer in Malawi is the highest in the world and projected to increase in the absence of interventions. Although government policy supports screening using visual inspection with acetic acid (VIA), screening provision is limited due to lack of infrastructure, trained personnel, and the cost and availability of gas for cryotherapy. Recently, thermo-coagulation has been acknowledged as a safe and acceptable procedure suitable for low-resource settings. We introduced thermo-coagulation for treatment of VIA-positive lesions as an alternative to cryotherapy within a cervical screening service based on VIA, coupled with appropriate, sustainable pathways of care for women with high-grade lesions and cancers. Detailed planning was undertaken for VIA clinics, and approvals were obtained from the Ministry of Health, Regional and Village Chiefs. Educational resources were developed. Thermo-coagulators were introduced into hospital and health centre settings, with theoretical and practical training in safe use and maintenance of equipment. A total of 7,088 previously unscreened women attended VIA clinics between October 2013 and March 2015. Screening clinics were held daily in the hospital and weekly in the health centres. Overall, VIA positivity was 6.1%. Almost 90% received same day treatment in the hospital setting, and 3- to 6-month cure rates of more than 90% are observed. Thermo-coagulation proved feasible and acceptable in this setting. Effective implementation requires comprehensive training and provider support, ongoing competency assessment, quality assurance and improvement audit. Thermo-coagulation offers an effective alternative to cryotherapy and encouraged VIA screening of many more women. © 2016 The Authors International Journal of Cancer published by John Wiley & Sons Ltd on behalf of UICC.

Thermo-Mechanical Modeling and Analysis for Turbopump Assemblies

NASA Technical Reports Server (NTRS)

Platt, Mike; Marsh, Matt

2003-01-01

Life, reliability, and cost are strongly impacted by steady and transient thermo-mechanical effect. Design cycle can suffer big setbacks when working a transient stress/deflection issue. Balance between objectives and constrains is always difficult. Requires assembly-level analysis early in the design cycle.

Why individual thermo sensation and pain perception varies? Clue of disruptive mutations in TRPVs from 2504 human genome data.

PubMed

Ghosh, Arijit; Kaur, Navneet; Kumar, Abhishek; Goswami, Chandan

2016-09-02

Every individual varies in character and so do their sensory functions and perceptions. The molecular mechanism and the molecular candidates involved in these processes are assumed to be similar if not same. So far several molecular factors have been identified which are fairly conserved across the phylogenetic tree and are involved in these complex sensory functions. Among all, members belonging to Transient Receptor Potential (TRP) channels have been widely characterized for their involvement in thermo-sensation. These include TRPV1 to TRPV4 channels which reveal complex thermo-gating behavior in response to changes in temperature. The molecular evolution of these channels is highly correlative with the thermal response of different species. However, recent 2504 human genome data suggest that these thermo-sensitive TRPV channels are highly variable and carry possible deleterious mutations in human population. These unexpected findings may explain the individual differences in terms of complex sensory functions.

Coherent Generation of Photo-Thermo-Acoustic Wave from Graphene Sheets

NASA Astrophysics Data System (ADS)

Tian, Yichao; Tian, He; Wu, Yanling; Zhu, Leilei; Tao, Luqi; Zhang, Wei; Shu, Yi; Xie, Dan; Yang, Yi; Wei, Zhiyi; Lu, Xinghua; Ren, Tian-Ling; Shih, Chih-Kang; Zhao, Jimin

Many remarkable properties of graphene are derived from its large energy window for Dirac-like electronic states and have been explored for applications in electronics and photonics. In addition, strong electron-phonon interaction in graphene has led to efficient photo-thermo energy conversions, which has been harnessed for energy applications. By combining the wavelength independent absorption property and the efficient photo-thermo energy conversion, here we report a new type of applications in sound wave generation underlined by a photo-thermo-acoustic energy conversion mechanism. Most significantly, by utilizing ultrafast optical pulses, we demonstrate the ability to control the phase of sound waves generated by the photo-thermal-acoustic process. Our finding paves the way for new types of applications for graphene, such as remote non-contact speakers, optical-switching acoustic devices, etc. National Basic Research Program of China MOST (2012CB821402), External Cooperation Program of Chinese Academy of Sciences (GJHZ1403), and National Natural Science Foundation of China (11274372).

Giant thermo-optical relaxation oscillations in millimeter-size whispering gallery mode disk resonators.

PubMed

Diallo, Souleymane; Lin, Guoping; Chembo, Yanne K

2015-08-15

In this Letter, we show that giant thermo-optical oscillations can be triggered in millimeter (mm)-size whispering gallery mode (WGM) disk resonators when they are pumped by a resonant continuous-wave laser. Our resonator is an ultrahigh-Q barium fluoride cavity that features a positive thermo-optic coefficient and a negative thermo-elastic coefficient. We demonstrate for the first time, to our knowledge, that the complex interplay between these two thermic coefficients and the intrinsic Kerr nonlinearity yields very sharp slow-fast relaxation oscillations with a slow timescale that can be exceptionally large, typically of the order of 1 s. We use a time-domain model to gain understanding into this instability, and we find that both the experimental and theoretical results are in excellent agreement. The understanding of these thermal effects is an essential requirement for every WGM-related application and our study demonstrates that even in the case of mm-size resonators, such effects can still be accurately analyzed using nonlinear time-domain models.

Open loop, auto reversing liquid nitrogen circulation thermal system for thermo vacuum chamber

NASA Astrophysics Data System (ADS)

Naidu, M. C. A.; Nolakha, Dinesh; Saharkar, B. S.; Kavani, K. M.; Patel, D. R.

2012-11-01

In a thermo vacuum chamber, attaining and controlling low and high temperatures (-100 Deg. C to +120 Deg. C) is a very important task. This paper describes the development of "Open loop, auto reversing liquid nitrogen based thermal system". System specifications, features, open loop auto reversing system, liquid nitrogen flow paths etc. are discussed in this paper. This thermal system consists of solenoid operated cryogenic valves, double embossed thermal plate (shroud), heating elements, temperature sensors and PLC. Bulky items like blowers, heating chambers, liquid nitrogen injection chambers, huge pipe lines and valves were not used. This entire thermal system is very simple to operate and PLC based, fully auto system with auto tuned to given set temperatures. This system requires a very nominal amount of liquid nitrogen (approx. 80 liters / hour) while conducting thermo vacuum tests. This system was integrated to 1.2m dia thermo vacuum chamber, as a part of its augmentation, to conduct extreme temperature cycling tests on passive antenna reflectors of satellites.

Challenges of designing and testing a highly stable sensor platform: Cesic solves MTG star sensor bracket thermoelastic requirements

NASA Astrophysics Data System (ADS)

Kroedel, Matthias; Zauner, Christoph

2017-09-01

The Meteosat Third Generation's extreme pointing requirements call for a highly stable bracket for mounting the Star Trackers. HB-Cesic®, a chopped fibre reinforced silicon carbide, was selected as a base material for the sensor bracket. The high thermal conductivity and low thermal expansion of HB-Cesic® were the key properties to fulfil the demanding thermo-elastic pointing requirements of below 1μrad/K for the Star Trackers mounting interfaces. Dominated by thermoelastic stability requirements, the design and analysis of the Bracket required a multidisciplinary approach with the focus on thermal and thermo-elastic analyses. Dedicated modal and thermal post-processing strategies have been applied in the scope of the light weighting process. The experimental verification of this thermo-elastic stable system has been a challenging task of its own. A thermo-elastic distortion measurement rig was developed with a stability of <0.1μrad/K in all three rotational degrees of freedom.

Design and performance of a vacuum-bottle solid-state calorimeter

DOE Office of Scientific and Technical Information (OSTI.GOV)

Bracken, D.S.; Biddle, R.; Cech, R.

1997-11-01

EG and G Mound Applied Technologies calorimetry personnel have developed a small, thermos-bottle solid-state calorimeter, which is now undergoing performance testing at Los Alamos National Laboratory. The thermos-bottle solid-state calorimeter is an evaluation prototype for characterizing the heat output of small heat standards and other homogeneous heat sources. The current maximum sample size is 3.5 in. long with a diameter of 0.8 in. The overall size of the thermos bottle and thermoelectric cooling device is 9.25 in. high by 3.75 in. diameter and less than 3 lb. Coupling this unit with compact electronics and a laptop computer makes this calorimetermore » easily hand carried by a single individual. This compactness was achieved by servo controlling the reference temperature below room temperature and replacing the water bath used in conventional calorimeter design with the thermos-bottle insulator. Other design features will also be discussed. The performance of the calorimeter will be presented.« less

Effect of Water on the Thermo-Mechanical Behavior of Carbon Cloth Phenolic

NASA Technical Reports Server (NTRS)

Sullivan, Roy M.; Stokes, Eric; Baker, Eric H.

2011-01-01

The results of thermo-mechanical experiments, which were conducted previously by one of the authors, are reviewed. The strain in the direction normal to the fabric plane was measured as a function of temperature for a variety of initial moisture contents and heating rates. In this paper, the general features of the thermo-mechanical response are discussed and the effect of heating rate and initial moisture content are highlighted. The mechanical interaction between the phenolic polymer and water trapped within its free volumes as the polymer is heated to high temperatures is discussed. An equation for the internal stresses which are generated within the polymer due to trapped water is obtained from the total stress expression for a binary mixture of polymer and water. Numerical solutions for moisture diffusion in the thermo-mechanical experiments were performed and the results of these solutions are presented. The results of the moisture diffusion solutions help to explain the effects of heating rate and moisture content on the strain behavior normal to the fabric plane.

Innovative plasticized alginate obtained by thermo-mechanical mixing: Effect of different biobased polyols systems.

PubMed

Gao, Chengcheng; Pollet, Eric; Avérous, Luc

2017-02-10

Plasticized alginate films with different biobased polyols (glycerol and sorbitol) and their mixtures were successfully prepared by thermo-mechanical mixing instead of the usual casting-evaporation procedure. The microstructure and properties of the different plasticized alginate formulations were investigated by SEM, FTIR, XRD, DMTA and uniaxial tensile tests. SEM and XRD results showed that native alginate particles were largely destructured with the plasticizers (polyols and water), under a thermo-mechanical input. With increasing amount of plasticizers, the samples showed enhanced homogeneity while their thermal and mechanical properties decreased. Compared to sorbitol, glycerol resulted in alginate films with a higher flexibility due to its better plasticization efficiency resulting from its smaller size and higher hydrophilic character. Glycerol and sorbitol mixtures seemed to be an optimum to obtain the best properties. This work showed that thermo-mechanical mixing is a promising method to produce, at large scale, plasticized alginate-based films with improved properties. Copyright © 2016 Elsevier Ltd. All rights reserved.

Thermo- and electro-optical properties of photonic liquid crystal fibers doped with gold nanoparticles.

PubMed

Siarkowska, Agata; Chychłowski, Miłosz; Budaszewski, Daniel; Jankiewicz, Bartłomiej; Bartosewicz, Bartosz; Woliński, Tomasz R

2017-01-01

Thermo- and electro-optical properties of a photonic liquid crystal fiber (PLCF) enhanced by the use of dopants have been investigated. A 6CHBT nematic liquid crystal was doped with four different concentrations of gold nanoparticles (NPs), 0.1, 0.3, 0.5 and 1.0 wt %, for direct comparison of the influence of the dopant on the properties of the PLCF. The thermo-optical effects of the liquid crystal doped with gold NPs were compared in three setups, an LC cell, a microcapillary and within the PLCF, to determine if the observed responses to external factors are caused by the properties of the infiltration material or due to the setup configuration. The results obtained indicated that with increasing NP doping a significant reduction of the rise time under an external electric field occurs with a simultaneous decrease in the nematic-isotropic phase transition temperature, thus improving the thermo- and electro-optical properties of the PLCF.

Large thermo-erosional tunnel for a river in northeast Greenland

NASA Astrophysics Data System (ADS)

Docherty, Catherine L.; Hannah, David M.; Riis, Tenna; Rosenhøj Leth, Simon; Milner, Alexander M.

2017-12-01

Thermo-erosional river bank undercutting is caused by the combined action of thermal and mechanical erosion of the permafrost by Arctic rivers whilst the overlying sediment withstands collapse temporarily. Here, we report the discovery of a large thermo-erosional tunnel that formed in the banks of a meltwater-fed stream in northeast Greenland in summer 2015. The tunnel was observed over eight days (14-22 July), during which period the tunnel remained open but bank-side slumping increased. Stream solute load increased immediately downstream and remained high 800 m from the tunnel. Whilst this field observation was opportunistic and information somewhat limited, our study provides a rare insight into an extreme event impacting permafrost, local geomorphology and stream habitat. With accelerated climate change in Arctic regions, increased permafrost degradation and warmer stream water temperature are predicted thereby enhancing potential for thermo-erosional niche development and associated stream bank slumping. This change could have significant implications for stream physicochemical habitat and, in turn, stream benthic communities, through changes in aquatic habitat conditions.

Zinc impregnated cellulose nanocomposites: Synthesis, characterization and applications

NASA Astrophysics Data System (ADS)

Ali, Attarad; Ambreen, Sidra; Maqbool, Qaisar; Naz, Sania; Shams, Muhammad Fahad; Ahmad, Madiha; Phull, Abdul Rehman; Zia, Muhammad

2016-11-01

Nanocomposite materials have broad applicability due to synergistic effect of combined components. In present investigation, cellulose isolated from citrus peel waste is used as a supporting material; impregnation of zinc oxide nanoparticles via co-precipitation method. The characterization of nano composite is carried out through Fourier transform infrared spectroscopy (FTIR), X-ray diffraction (XRD) analysis, scanning electron microscopy (SEM) and Thermo-gravimetric analysis (TGA) resulting less than 10 μm cellulose fiber and approx. 50 nm ZnO NPs. Zinc oxide impregnated cellulose (ZnO-Cel) exhibited significant bacterial devastation property when compared to ZnO NPs or Cellulose via disc diffusion and colony forming unit methods. In addition, the ZnO-Cel exhibited significant total antioxidant, and minor DPPH free radical scavenging and total reducing power activities. The nano composite also showed time dependent increase in photocatalytic by effectively degrading methylene blue dye up to 69.5% under sunlight irradiation within 90 min. The results suggest effective utilization of cellulose obtained from citrus waste and synthesis of pharmacologically important nano-composites that can be exploited in wound dressing; defence against microbial attack and healing due to antioxidative property, furthermore can also be used for waste water treatment.

Constitutive modeling of the mechanical behavior of high strength ferritic steels for static and dynamic applications

NASA Astrophysics Data System (ADS)

Abed, Farid H.

2010-11-01

A constitutive relation is presented in this paper to describe the plastic behavior of ferritic steel over a broad range of temperatures and strain rates. The thermo-mechanical behavior of high strength low alloy (HSLA-65) and DH-63 naval structural steels is considered in this study at strains over 40%. The temperatures and strain rates are considered in the range where dynamic strain aging is not effective. The concept of thermal activation analysis as well as the dislocation interaction mechanism is used in developing the flow model for both the isothermal and adiabatic viscoplastic deformation. The flow stresses of the two steels are very sensitive to temperature and strain rate, the yield stresses increase with decreasing temperatures and increasing strain rates. That is, the thermal flow stress is mainly captured by the yield stresses while the hardening stresses are totally pertained to the athermal component of the flow stress. The proposed constitutive model predicts results that compare very well with the measured ones at initial temperature range of 77 K to 1000 K and strain rates between 0.001 s-1 and 8500 s-1 for both steels.

Air Liquide's pulse tube cryocooler systems for space applications

NASA Astrophysics Data System (ADS)

Trollier, T.; Tanchon, J.; Rey, J. C.; Ravex, A.; Buquet, J.

2009-05-01

Thanks to important development efforts completed internally and with the European Space Agency (ESA) funding, Air Liquide Advanced Technology Division (AL/DTA) is now in position to propose two Pulse Tube cooler systems in the 40-80K temperature range for coming Earth Observation missions such as Meteosat Third Generation (MTG), SIFTI, etc... The Miniature Pulse Tube Cooler (MPTC) is lifting up to 2.47W@80K with 50W maximal compressor input power and 10°C rejection temperature. The weight is 2.8 kg. The Large Pulse Tube Cooler (LPTC) is providing 2.3W@50K for 160W input power and 10°C rejection temperature. This product is weighing 5.1 kg. The two pulse tube coolers thermo-mechanical units are qualified against environmental constraints as per ESA ECSS-E-30. They are both using dual opposed pistons flexure bearing compressor with moving magnet linear motors in order to ensure very high lifetime. The associated Cooler Drive Electronics is also an important aspect specifically regarding the active control of the cooler thermo-mechanical unit during the launch phase and the active reduction of the vibrations induced by the compressor (partly supported by the French Agency CNES). This paper details the presentation of the two Pulse Tube Coolers together with the Cooler Drive Electronics aspects.

Mid-Mantle Interaction Between the Big, Active Samoan Plume and the Tonga-Kermadec Slabs

NASA Astrophysics Data System (ADS)

Chang, S. J.; Ferreira, A. M. G.; Faccenda, M.

2015-12-01

Mantle plumes play an efficient role in transferring heat from the core-mantle boundary to the surface, where they significantly influence plate tectonics. It is well known that, upon impinging on the lithosphere at spreading ridges or intra-oceanic settings, mantle plumes generate hotspots, Large Igneous Provinces and considerable dynamic topography. However, it is still poorly understood which is the active role of mantle plumes on subducting slabs. Here we show that the stagnancy and fastest trench retreat of the Tonga slab in Southwestern Pacific are consistent with an interaction with the big Samoan plume and the Hikurangi plateau. Our findings are based on comparisons between 3-D anisotropic tomography images and 3-D petrological-thermo-mechanical models, which show complex mantle flow around the slab and intense deformation and anisotropy in the transition zone, explaining several unique features in the Fiji-Tonga area self-consistently. We also found that horizontally polarized shear waves (SH) are faster than vertically polarized shear waves (SV) in the mid mantle beneath the Tonga slab, which may indicate a dominant dislocation creep mechanism during the slab-plume interaction. We propose possible slip systems of bridgmanite in the lower mantle that reconcile the observed seismic anisotropy with thermo-mechanical calculations.

Air liquide's space pulse tube cryocooler systems

NASA Astrophysics Data System (ADS)

Trollier, T.; Tanchon, J.; Buquet, J.; Ravex, A.

2017-11-01

Thanks to important development efforts completed with ESA funding, Air Liquide Advanced Technology Division (AL/DTA), is now in position to propose two Pulse Tube cooler systems in the 40-80K temperature range for coming Earth Observation missions such as Meteosat Third Generation (MTG), SIFTI, etc… The Miniature Pulse Tube Cooler (MPTC) is lifting up to 2.47W@80K with 50W compressor input power and 10°C rejection temperature. The weight is 2.8 kg. The Large Pulse Tube Cooler (LPTC) is providing 2.3W@50K for 160W input power and 10°C rejection temperature. This product is weighing 5.1 kg. The two pulse tube coolers thermo-mechanical units are qualified against environmental constraints as per ECSS-E-30. They are both using dual opposed pistons flexure bearing compressor with moving magnet linear motors in order to ensure very high lifetime. The associated Cooler Drive Electronics is also an important aspect specifically regarding the active control of the cooler thermo-mechanical unit during the launch phase and the active reduction of the vibrations induced by the compressor (partly supported by the French Agency CNES). This paper details the presentation of the two Pulse Tube Coolers together with the Cooler Drive Electronics aspects.

Thermally tunable grating using thermo-responsive magnetic fluid

NASA Astrophysics Data System (ADS)

Zaibudeen, A. W.; Philip, John

2017-04-01

We report a thermally tunable grating prepared using poly(N-isopropylacrylamide) and super paramagnetic iron oxide nanoparticles. The array spacing is reversibly tuned by varying the temperature between 5 and 38 °C. Here, the ability of thermo-responsive polymer brushes to alter their conformation at an interface is exploited to control the grating spacing in nanoscale. The underlying mechanism for the temperature dependent conformational changes are studied by measuring the subtle intermolecular forces between the polymer covered interfaces. It is observed that the interparticle forces are repulsive and exponentially decaying with distance. The thermo-responsive grating is simple to use and offers a wide range of applications.

Approximations of thermoelastic and viscoelastic control systems

NASA Technical Reports Server (NTRS)

Burns, J. A.; Liu, Z. Y.; Miller, R. E.

1990-01-01

Well-posed models and computational algorithms are developed and analyzed for control of a class of partial differential equations that describe the motions of thermo-viscoelastic structures. An abstract (state space) framework and a general well-posedness result are presented that can be applied to a large class of thermo-elastic and thermo-viscoelastic models. This state space framework is used in the development of a computational scheme to be used in the solution of a linear quadratic regulator (LQR) control problem. A detailed convergence proof is provided for the viscoelastic model and several numerical results are presented to illustrate the theory and to analyze problems for which the theory is incomplete.

Quantum electron-vibrational dynamics at finite temperature: Thermo field dynamics approach

NASA Astrophysics Data System (ADS)

Borrelli, Raffaele; Gelin, Maxim F.

2016-12-01

Quantum electron-vibrational dynamics in molecular systems at finite temperature is described using an approach based on the thermo field dynamics theory. This formulation treats temperature effects in the Hilbert space without introducing the Liouville space. A comparison with the theoretically equivalent density matrix formulation shows the key numerical advantages of the present approach. The solution of thermo field dynamics equations with a novel technique for the propagation of tensor trains (matrix product states) is discussed. Numerical applications to model spin-boson systems show that the present approach is a promising tool for the description of quantum dynamics of complex molecular systems at finite temperature.

Design, qualification, manufacturing and integration of IXV Ablative Thermal Protection System

NASA Astrophysics Data System (ADS)

Cioeta, Mario; Di Vita, Gandolfo; Signorelli Maria, Teresa; Bianco, Gianluca; Cutroni, Maurizio; Damiani, Francesco; Ferretti, Viviana; Rotondo, Adriano

2016-07-01

In the present paper, all the activities carried out by Avio S.p.A in order to define, qualify, manufacture and integrate the IXV Ablative TPS will be presented. In particular the extensive numerical simulation in both small and full scale testing activities will be overviewed. Wide-ranging testing activity has been carried out in order to verify, confirm and correlate the numerical models used for TPS sizing. Tests ranged from classical thermo-mechanical characterization traction specimens to tests in plasma wind tunnels on dedicated prototypes. Finally manufacturing and integration activities will be described emphasizing technological aspects solved in order to meet the stringent requirements in terms of shape accuracy and integration tolerances.

Hazardous Waste Cleanup: Thermo King de Puerto Rico Incorporated in Arecibo, Puerto Rico

EPA Pesticide Factsheets

Thermo King de Puerto Rico, Inc. facility is located in the Zeno Gandia Industrial Area in Arecibo, Puerto Rico. Major features of the facility include six buildings used for manufacturing and storage, a wastewater treatment plant, a hazardous waste and no

Preparation of Thermo-Responsive and Cross-Linked Fluorinated Nanoparticles via RAFT-Mediated Aqueous Polymerization in Nanoreactors.

PubMed

Ma, Jiachen; Zhang, Luqing; Geng, Bing; Azhar, Umair; Xu, Anhou; Zhang, Shuxiang

2017-01-25

In this work, a thermo-responsive and cross-linked fluoropolymer poly(2,2,2-Trifluoroethyl) methacrylate (PTFEMA) was successfully prepared by reversible addition-fragmentation chain transfer (RAFT) mediated aqueous polymerization with a thermo-responsive diblock poly(dimethylacrylamide- b - N -isopropylacrylamide) (PDMA- b -PNIPAM) that performed a dual function as both a nanoreactor and macro-RAFT agent. The cross-linked polymer particles proved to be in a spherical-like structure of about 50 nm in diameter and with a relatively narrow particle size distribution. ¹H-NMR and 19 F-NMR spectra showed that thermo-responsive diblock P(DMA- b -NIPAM) and cross-linked PTFEMA particles were successfully synthesized. Influence of the amount of ammonium persulfate (APS), the molar ratio of monomers to RAFT agent, influence of the amount of cross-linker on aqueous polymerization and thermo-responsive characterization of the particles are investigated. Monomer conversion increased from 44% to 94% with increasing the molar ratio of APS and P(DMA- b -NIPAM) from 1:9 to1:3. As the reaction proceeded, the particle size increased from 29 to 49 nm due to the consumption of TFEMA monomer. The size of cross-linked nanoparticles sharply decreased from 50.3 to 40.5 nm over the temperature range 14-44 °C, suggesting good temperature sensitivity for these nanoparticles.

Cytological characterization of a thermo-sensitive cytoplasmic male-sterile wheat line having K-type cytoplasm of Aegilops kotschyi

PubMed Central

Meng, Liying; Liu, Zihan; Zhang, Lingli; Hu, Gan; Song, Xiyue

2016-01-01

Male sterility is an important tool for obtaining crop heterosis. A thermo-sensitive cytoplasmic male-sterile (TCMS) line was developed recently using a new method based on tiller regeneration. In the present study, we explored the critical growth stages required to maintain thermo-sensitive male sterility in TCMS lines and found that fertility is associated with abnormal tapetal and microspore development. We investigated the fertility and cytology of temperature-treated plant anthers at various developmental stages. TCMS line KTM3315A exhibited thermo-sensitive male sterility in Zadoks growth stages 41–49 and 58–59. Morphologically, the line exhibited thermo-sensitive male sterility at 3–9 days before heading and at 3–6 days before flowering, and it was partially restored in three locations during spring and summer. TCMS line KTM3315A plants exhibited premature tapetal programmed cell death (PCD) from the early uninucleate stage of microspore development until the tapetal cells degraded completely. Microspore development was then blocked and the pollen abortion type was stainable abortion. Thus, male fertility in the line KTM3315A is sensitive to temperature and premature tapetal PCD is the main cause of pollen abortion, where it determines the starting period and affects male fertility conversion in K-type TCMS lines at certain temperatures. PMID:28163591

Numerical and experimental study of electron-beam coatings with modifying particles FeB and FeTi

NASA Astrophysics Data System (ADS)

Kryukova, Olga; Kolesnikova, Kseniya; Gal'chenko, Nina

2016-07-01

An experimental study of wear-resistant composite coatings based on titanium borides synthesized in the process of electron-beam welding of components thermo-reacting powders are composed of boron-containing mixture. A model of the process of electron beam coating with modifying particles of boron and titanium based on physical-chemical transformations is supposed. The dissolution process is described on the basis of formal kinetic approach. The result of numerical solution is the phase and chemical composition of the coating under nonequilibrium conditions, which is one of the important characteristics of the coating forming during electron beam processing. Qualitative agreement numerical calculations with experimental data was shown.

Analytical method for thermal stress analysis of plasma facing materials

NASA Astrophysics Data System (ADS)

You, J. H.; Bolt, H.

2001-10-01

The thermo-mechanical response of plasma facing materials (PFMs) to heat loads from the fusion plasma is one of the crucial issues in fusion technology. In this work, a fully analytical description of the thermal stress distribution in armour tiles of plasma facing components is presented which is expected to occur under typical high heat flux (HHF) loads. The method of stress superposition is applied considering the temperature gradient and thermal expansion mismatch. Several combinations of PFMs and heat sink metals are analysed and compared. In the framework of the present theoretical model, plastic flow and the effect of residual stress can be quantitatively assessed. Possible failure features are discussed.

TOUGHREACT: a new code of the TOUGH Family for Non-Isothermal multiphase reactive geochemical transport in variably saturated geologic media

DOE Office of Scientific and Technical Information (OSTI.GOV)

Xu, Tianfu; Sonnenthal, Eric; Spycher, Nicolas

Coupled modeling of subsurface multiphase fluid and heat flow, solute transport and chemical reactions can be used for the assessment of acid mine drainage remediation, waste disposal sites, hydrothermal convection, contaminant transport, and groundwater quality. We have developed a comprehensive numerical simulator, TOUGHREACT, which considers non-isothermal multi-component chemical transport in both liquid and gas phases. A wide range of subsurface thermo-physical-chemical processes is considered under various thermohydrological and geochemical conditions of pressure, temperature, water saturation, and ionic strength. The code can be applied to one-, two- or three-dimensional porous and fractured media with physical and chemical heterogeneity.

Manufacturing of highly integrated mechatronic modules by using the technology of embedding stereolithography

NASA Astrophysics Data System (ADS)

Rechtenwald, Thomas; Frick, Thomas; Schmidt, Michael

The embedding stereolithography is an additive, hybrid process, which allows the construction of highly integrated 3D assemblies for the use in automotive applications. The flexible process of stereolithography is combined with the embedding of functional components and supplemented by the additive manufacturing of electrical or optical conductive structures. This combination of sub-processes implies a high potential regarding the obtainable integration density of mechatronical modules. This work considers basic restrictions, which limit the mechanical stability of the manufactured modules by calculating the superposition of residual and external stress using a thermo-mechanical finite element model and develops a procedure to qualify stereolithography matrix materials for the process of the embedding stereolithography.

High temperature and dynamic testing of AHSS for an analytical description of the adiabatic cutting process

NASA Astrophysics Data System (ADS)

Winter, S.; Schmitz, F.; Clausmeyer, T.; Tekkaya, A. E.; F-X Wagner, M.

2017-03-01

In the automotive industry, advanced high strength steels (AHSS) are widely used as sheet part components to reduce weight, even though this leads to several challenges. The demand for high-quality shear cutting surfaces that do not require reworking can be fulfilled by adiabatic shear cutting: High strain rates and local temperatures lead to the formation of adiabatic shear bands (ASB). While this process is well suited to produce AHSS parts with excellent cutting surface quality, a fundamental understanding of the process is still missing today. In this study, compression tests in a Split-Hopkinson Pressure Bar with an initial strain rate of 1000 s-1 were performed in a temperature range between 200 °C and 1000 °C. The experimental results show that high strength steels with nearly the same mechanical properties at RT may possess a considerably different behavior at higher temperatures. The resulting microstructures after testing at different temperatures were analyzed by optical microscopy. The thermo-mechanical material behavior was then considered in an analytical model. To predict the local temperature increase that occurs during the adiabatic blanking process, experimentally determined flow curves were used. Furthermore, the influence of temperature evolution with respect to phase transformation is discussed. This study contributes to a more complete understanding of the relevant microstructural and thermo-mechanical mechanisms leading to the evolution of ASB during cutting of AHSS.

Modeling Hemispheric Detonation Experiments in 2-Dimensions

DOE Office of Scientific and Technical Information (OSTI.GOV)

Howard, W M; Fried, L E; Vitello, P A

2006-06-22

Experiments have been performed with LX-17 (92.5% TATB and 7.5% Kel-F 800 binder) to study scaling of detonation waves using a dimensional scaling in a hemispherical divergent geometry. We model these experiments using an arbitrary Lagrange-Eulerian (ALE3D) hydrodynamics code, with reactive flow models based on the thermo-chemical code, Cheetah. The thermo-chemical code Cheetah provides a pressure-dependent kinetic rate law, along with an equation of state based on exponential-6 fluid potentials for individual detonation product species, calibrated to high pressures ({approx} few Mbars) and high temperatures (20000K). The parameters for these potentials are fit to a wide variety of experimental data,more » including shock, compression and sound speed data. For the un-reacted high explosive equation of state we use a modified Murnaghan form. We model the detonator (including the flyer plate) and initiation system in detail. The detonator is composed of LX-16, for which we use a program burn model. Steinberg-Guinan models5 are used for the metal components of the detonator. The booster and high explosive are LX-10 and LX-17, respectively. For both the LX-10 and LX-17, we use a pressure dependent rate law, coupled with a chemical equilibrium equation of state based on Cheetah. For LX-17, the kinetic model includes carbon clustering on the nanometer size scale.« less

Nanoscale deformation measurements for reliability assessment of material interfaces

NASA Astrophysics Data System (ADS)

Keller, Jürgen; Gollhardt, Astrid; Vogel, Dietmar; Michel, Bernd

2006-03-01

With the development and application of micro/nano electronic mechanical systems (MEMS, NEMS) for a variety of market segments new reliability issues will arise. The understanding of material interfaces is the key for a successful design for reliability of MEMS/NEMS and sensor systems. Furthermore in the field of BIOMEMS newly developed advanced materials and well known engineering materials are combined despite of fully developed reliability concepts for such devices and components. In addition the increasing interface-to volume ratio in highly integrated systems and nanoparticle filled materials are challenges for experimental reliability evaluation. New strategies for reliability assessment on the submicron scale are essential to fulfil the needs of future devices. In this paper a nanoscale resolution experimental method for the measurement of thermo-mechanical deformation at material interfaces is introduced. The determination of displacement fields is based on scanning probe microscopy (SPM) data. In-situ SPM scans of the analyzed object (i.e. material interface) are carried out at different thermo-mechanical load states. The obtained images are compared by grayscale cross correlation algorithms. This allows the tracking of local image patterns of the analyzed surface structure. The measurement results are full-field displacement fields with nanometer resolution. With the obtained data the mixed mode type of loading at material interfaces can be analyzed with highest resolution for future needs in micro system and nanotechnology.

Organo-modified bentonites as new flame retardant fillers in epoxy resin nanocomposites

NASA Astrophysics Data System (ADS)

Benelli, Tiziana; D'Angelo, Emanuele; Mazzocchetti, Laura; Saraga, Federico; Sambri, Letizia; Franchini, Mauro Comes; Giorgini, Loris

2016-05-01

The present work deals with two organophilic bentonites, based on nitrogen-containing compounds: these organoclays were synthesized via an ion exchange process starting from pristine bentonite with 6-(4-butylphenyl)-1,3,5-triazine-2,4-diamine (BFTDA) and 11-amino-N-(pyridine-2yl)undecanamide (APUA) and then used for the production of epoxy-based flame retardant nanocomposites. The amount of organic modifier in the organoclays Bento-BFTDA and Bento-APUA was determined with a TGA analysis and is around 0.4mmol/g for both samples. The effect of the organoclays on a commercial epoxy resin nanocomposite's thermo-mechanical and flammability properties was investigated. Composites containing 3wt% and 5wt% of the nanofillers were prepared by solventless addition of each organoclay to the epoxy resin, followed by further addition of the hardener component. For the sake of comparison a similar nanocomposite with the plain unmodified bentonite was produced in similar condition. The nanocomposites's thermo-mechanical properties of all the produced samples were measured and they resulted slightly improved or practically unaffected. On the contrary, when the flame behaviour was assessed in the cone-calorimeter, an encouraging decrease of 17% in the peak heat released rate (pHRR) was obtained at 3wt% loading level with Bento-APUA. This is a promising result, assessing that the APUA modified organoclay might act as flame retardant.

Short and long-term thermo-erosion of ice-rich permafrost coasts in the Laptev Sea region

NASA Astrophysics Data System (ADS)

Günther, F.; Overduin, P. P.; Sandakov, A. V.; Grosse, G.; Grigoriev, M. N.

2013-02-01

Permafrost coasts in the Arctic are susceptible to a variety of changing environmental factors all of which currently point to increasing coastal erosion rates and mass fluxes of sediment and carbon to the shallow arctic shelf seas. Rapid erosion along high yedoma coasts composed of Ice Complex permafrost deposits creates impressive coastal ice cliffs and inspired research for designing and implementing change detection studies for a long time, but continuous quantitative monitoring and a qualitative inventory of coastal thermo-erosion for large coastline segments is still lacking. Our goal is to use observations of thermo-erosion along the mainland coast of the Laptev Sea in eastern Siberia to understand how erosion rates depend on coastal geomorphology and the relative contributions of waterline and atmospheric drivers to coastal thermo-erosion over the past 4 decades and in the past few years. We compared multitemporal sets of orthorectified satellite imagery from 1965 to 2011 for three segments of coastline with a length of 73 to 95 km each and analyzed thermo-denudation (TD) along cliff top and thermo-abrasion (TA) along cliff bottom for two nested time periods: long-term rates (the past 39-43 yr) and short term rates (the past 1-3 yr). The Normalized Difference Thermo-erosion Index (NDTI) was used as a proxy that qualitatively describes the relative proportions of TD and TA. Mean annual erosion rates at all three sites were higher in recent years (-5.3 ± 1.31 m a-1) than over the long term mean (-2.2 ± 0.13 m a-1). The Mamontov Klyk coast exhibit primarily spatial variations of thermo-erosion, while intrasite-specific variations were strongest at the Buor Khaya coast, where slowest long-term rates around -0.5 ± 0.08 m a-1 were observed. The Oyogos Yar coast showed continuously rapid erosion up to -6.5 ± 0.19 m a-1. In general, variable characteristics of coastal thermo-erosion were observed not only between study sites and over time, but also within single coastal transects along the cliff profile. Varying intensities of cliff bottom and top retreat are leading to diverse qualities of coastal erosion that have different impacts on coastal mass fluxes. The different extents of Ice Complex permafrost degradation within our study sites turned out to influence not only the degree of coupling between TD and TA, and the magnitude of effectively eroded volumes, but also the quantity of organic carbon released to the shallow Laptev Sea from coastal erosion, which ranged on a long-term from 88 ± 21.0 to 800 ± 61.1 t per km coastline per year and will correspond to considerably higher amounts, if recently observed more rapid coastal erosion rates prove to be persistent.

75 FR 62423 - Barnstead Thermolyne Corporation, a Subsidiary of Thermo Fisher Scientific, Including On-Site...

Federal Register 2010, 2011, 2012, 2013, 2014

2010-10-08

... related to the production of scientific laboratory equipment. New information shows that workers leased... Corporation, a Subsidiary of Thermo Fisher Scientific, Including On-Site Leased Workers From Sedona Staffing... Scientific, including on- site leased workers from Sedona Staffing, Dubuque, Iowa. The notice was published...

Thermo- and electro-dual responsive poly(ionic liquid) electrolyte based smart windows.

PubMed

Chen, Fei; Ren, Yongyuan; Guo, Jiangna; Yan, Feng

2017-01-31

Thermo- and electro-dual responsive poly(ionic liquid) (PIL) based electrolytes were synthesized by co-polymerization of N-isopropylacrylamide (NIPAM) with (or without) 3-butyl-1-vinyl-imidazolium bromide ([BVIm][Br]) using diallyl-viologen (DAV) as both the cross-linking agent and electrochromic material.

Short, multi-needle FDR sensor suitable for measuring soil water content

USDA-ARS?s Scientific Manuscript database

Time domain reflectometry (TDR) is a well-established electromagnetic technique used to measure soil water content. TDR sensors have been combined with heat pulse sensors to produce thermo-TDR sensors. Thermo-TDR sensors are restricted to having relatively short needles in order to accurately measur...

Web Thermo Tables (WTT) - Professional Edition

National Institute of Standards and Technology Data Gateway

SRD 203 NIST/TRC Web Thermo Tables (WTT) - Professional Edition (Online Subscription)   WTT - Professional Edition, a Web version of the TRC Thermodynamic Tables, represents a complete collection of critically evaluated thermodynamic property data primarily for pure organic compounds. As of Nov. 2011, WTT contains information on 23999 compounds.

Rheological properties of a biological thermo-responsive hydrogel produced from soybean oil polymers

USDA-ARS?s Scientific Manuscript database

The rheological properties of a newly developed biological thermo-hydrogel made from vegetable oil were investigated. The material named HPSO-VI is a hydrolytic product of polymerized soybean oil (PSO). HPSO-VI exhibited viscoelastic behavior above 2% (wt. %) at room temperature and viscous fluid ...

Rheological Properties of a Biological Thermo-Hydrogel Produced from Soybean Oil Polymers

USDA-ARS?s Scientific Manuscript database

The rheological properties of a newly developed biological thermo-hydrogel made from vegetable oil were investigated. The material named HPSO-HG is a hydrolytic product of polymerized soybean oil (PSO). HPSO-HG exhibited viscoelastic behavior above 2% (wt.%) at room temperature and viscous fluid b...

Biochemical and thermodynamic characteristics of thermo-alkali-stable xylanase from a novel polyextremophilic Bacillus halodurans TSEV1.

PubMed

Kumar, Vikash; Satyanarayana, T

2013-09-01

The purified extracellular xylanase of polyextremophilic Bacillus halodurans TSEV1 has been visualized as a single band on SDS-PAGE and eluted as single peak by gel filtration, with a molecular mass of 40 kDa. The peptide finger print and cloned xylanase gene sequence analyses indicate that this enzyme belongs to GH family 10. The active site carboxyl residues are mainly involved in catalysis, while tryptophan residues are involved in substrate binding. The enzyme is optimally active at 80 °C and pH 9.0, and stable in the pH range of 7.0-12.0 with T 1/2 of 35 min at 80 °C (pH 9.0). Activation energy for birch wood xylan hydrolysis is 30.51 kJ mol(-1). The K m, V max and k cat (birchwood xylan) are 2.05 mg ml(-1), 333.33 μmol mg(-1 )min(-1) and 3.33 × 10(4) min(-1), respectively. The pKa1 and pKa2 of ionizable groups of the active site that influence V max are 8.51 and 11.0. The analysis of thermodynamic parameters for xylan hydrolysis suggests this as a spontaneous process. The enzyme is resistant to chemical denaturants like urea and guanidinium-HCl. The site-directed mutagenesis of catalytic glutamic acid residues (E196 and E301) resulted in a complete loss of activity. The birch wood xylan hydrolyzate contained xylobiose and xylotriose as the main products without any trace of xylose, and the enzyme hydrolyzes xylotetraose and xylopentaose rapidly to xylobiose. Thermo-alkali-stability, resistance to various chemical denaturants and mode of action make it a useful biocatalyst for generating xylo-oligosaccharides from agro-residues and bleaching of pulp in paper industries.

A hyaluronic acid nanogel for photo-chemo theranostics of lung cancer with simultaneous light-responsive controlled release of doxorubicin

NASA Astrophysics Data System (ADS)

Khatun, Zehedina; Nurunnabi, Md; Nafiujjaman, Md; Reeck, Gerald R.; Khan, Haseeb A.; Cho, Kwang Jae; Lee, Yong-Kyu

2015-06-01

The combined delivery of photo- and chemo-therapeutic agents is an emerging strategy to overcome drug resistance in treating cancer, and controlled light-responsive drug release is a proven tactic to produce a continuous therapeutic effect for a prolonged duration. Here, a combination of light-responsive graphene, chemo-agent doxorubicin and pH-sensitive disulfide-bond linked hyaluronic acid form a nanogel (called a graphene-doxorubicin conjugate in a hyaluronic acid nanogel) that exerts an activity with multiple effects: thermo and chemotherapeutic, real-time noninvasive imaging, and light-glutathione-responsive controlled drug release. The nanogel is mono-dispersed with an average diameter of 120 nm as observed by using TEM and a hydrodynamic size analyzer. It has excellent photo-luminescence properties and good stability in buffer and serum solutions. Graphene itself, being photoluminescent, can be considered an optical imaging contrast agent as well as a heat source when excited by laser irradiation. Thus the nanogel shows simultaneous thermo-chemotherapeutic effects on noninvasive optical imaging. We have also found that irradiation enhances the release of doxorubicin in a controlled manner. This release synergizes therapeutic activity of the nanogel in killing tumor cells. Our findings demonstrate that the graphene-doxorubicin conjugate in the hyaluronic acid nanogel is very effective in killing the human lung cancer cell line (A549) with limited toxicity in the non-cancerous cell line (MDCK).The combined delivery of photo- and chemo-therapeutic agents is an emerging strategy to overcome drug resistance in treating cancer, and controlled light-responsive drug release is a proven tactic to produce a continuous therapeutic effect for a prolonged duration. Here, a combination of light-responsive graphene, chemo-agent doxorubicin and pH-sensitive disulfide-bond linked hyaluronic acid form a nanogel (called a graphene-doxorubicin conjugate in a hyaluronic acid nanogel) that exerts an activity with multiple effects: thermo and chemotherapeutic, real-time noninvasive imaging, and light-glutathione-responsive controlled drug release. The nanogel is mono-dispersed with an average diameter of 120 nm as observed by using TEM and a hydrodynamic size analyzer. It has excellent photo-luminescence properties and good stability in buffer and serum solutions. Graphene itself, being photoluminescent, can be considered an optical imaging contrast agent as well as a heat source when excited by laser irradiation. Thus the nanogel shows simultaneous thermo-chemotherapeutic effects on noninvasive optical imaging. We have also found that irradiation enhances the release of doxorubicin in a controlled manner. This release synergizes therapeutic activity of the nanogel in killing tumor cells. Our findings demonstrate that the graphene-doxorubicin conjugate in the hyaluronic acid nanogel is very effective in killing the human lung cancer cell line (A549) with limited toxicity in the non-cancerous cell line (MDCK). Electronic supplementary information (ESI) available: In vitro stability study method and results, FT-IR data, optical properties and thermal stability (TGA and DTA), cell image and in vivo optical image and histological images. See DOI: 10.1039/c5nr01075f

Fabrication and Characterization of Thermo-Optic Mach-Zehnder Silicon Modulator

NASA Astrophysics Data System (ADS)

Park, Yeongho

This thesis focuses on the modeling, design, and fabrication of the Thermo-Optic Mach-Zehnder Modulator, which is one of the simple active devices in silicon photonics. The Mach-Zehnder interferometer (MZI) was formed as an optical path on a silicon on insulator (SOI) wafer of 2040+/-80 nm thick, and the thermo-optic effect was used to modulate the infrared light of 1553 nm wavelength by controlling the temperature of the one arm of the MZI. To fabricate and understand the Si photonic device, the whole process from theory to the measurement setup is introduced. Additionally, all the fabrication details and some informative experiments which were performed during the fabrication are discussed for students who will study the more developed devices. The width of the designed waveguide is 4 mum, but the width of the fabricated waveguide is 3.0+/-0.2 mum due to the isotropic etching. For the lithography for both patterning waveguides and metal contacts, the AZ 5214 photoresist was used, and the details of the lithography was discussed. Furthermore, the lift-off method was performed and introduced to solve the over-etching problem. The fabricated metal contacts can withstand up to 1.6W, and the electric power 0.3W is required to make Pi phase difference according to the simulation result by the simulation software Lumerical. The optical output of the device was not detected due to the huge losses from the sidewall roughness and the insertion loss, so it is discussed in the experimental measurement chapter.

The development of a thermostable CiP (Coprinus cinereus peroxidase) through in silico design.

PubMed

Kim, Su Jin; Lee, Jeong Ah; Joo, Jeong Chan; Yoo, Young Je; Kim, Yong Hwan; Song, Bong Keun

2010-01-01

Protein thermostability is a crucial issue in the practical application of enzymes, such as inorganic synthesis and enzymatic polymerization of phenol derivatives. Much attention has been focused on the enhancement and numerous successes have been achieved through protein engineering methods. Despite fruitful results based on random mutagenesis, it was still necessary to develop a novel strategy that can reduce the time and effort involved in this process. In this study, a rapid and effective strategy is described for increasing the thermal stability of a protein. Instead of random mutagenesis, a rational strategy was adopted to theoretically stabilize the thermo labile residues of a protein using computational methods. Protein residues with high flexibility can be thermo labile due to their large range of movement. Here, residue B factor values were used to identify putatively thermo labile residues and the RosettaDesign program was applied to search for stable sequences. Coprinus cinereus (CiP) heme peroxidase was selected as a model protein for its importance in commercial applications, such as the polymerization of phenolic compounds. Eleven CiP residues with the highest B factor values were chosen as target mutation sites for thermostabilization, and then redesigned using RosettaDesign to identify sequences. Eight mutants based on the redesigns, were produced as functional enzymes and two of these (S323Y and E328D) showed increased thermal stability over the wild-type in addition to conserved catalytic activity. Thus, this strategy can be used as a rapid and effective in silico design tool for obtaining thermostable proteins. (c) 2010 American Institute of Chemical Engineers

Highly thermo-halo-alkali-stable β-1,4-endoxylanase from a novel polyextremophilic strain of Bacillus halodurans.

PubMed

Kumar, Vikash; Syal, Poonam; Satyanarayana, T

2013-05-01

A novel bacterial isolate, capable of producing extracellular highly thermostable, halo-alkali-stable and cellulase-free xylanase, was isolated from soil and identified as Bacillus halodurans TSPV1 by polyphasic approach. The Plackett-Burman design identified wheat bran, lactose, tryptone and NaCl as the factors that significantly affect xylanase production, and thus, these were optimized by response surface methodology. The data analysis suggested that optimum levels of wheat bran (15-20 g L(-1)), lactose (1.0-1.5 g L(-1)), tryptone (2-2.5 g L(-1)) and NaCl (7.0-8.0 g L(-1)) support 6.75-fold higher xylanase production than that in the un-optimized medium. The xylanase is optimally active at 90 °C and pH 10, and stable for 4 h at 90 °C (T 1/2 60 h) over a broad range of NaCl concentrations (0-29 %). This is the first report on the isolation of polyextremophilic B. halodurans strain that produces thermo-halo-alkali-stable xylanase in submerged fermentation. This enzyme efficiently saccharifies agro residues like wheat bran and corncobs. Fifty-six percent of hemicellulose of wheat bran could be hydrolyzed by xylanase (100 U g(-1) substrate) along with cellulase (22 U FPase and 50 U CMCase g(-1)). The xylanase, being thermo-alkali stable and cellulase free, can find applications in pre-bleaching of paper pulps and hydrolysis of xylan in agricultural residues.

Commercializing potassium terbium fluoride, KTF (KTb3F10) faraday crystals for high laser power optical isolator applications

NASA Astrophysics Data System (ADS)

Schlichting, Wolfgang; Stevens, Kevin; Foundos, Greg; Payne, Alexis

2017-10-01

Many scientific lasers and increasingly industrial laser systems operate in <500W and kW output power regime, require high-performance optical isolators to prevent disruptive light feedback into the laser cavity. The optically active Faraday material is the key optical element inside the isolator. SYNOPTICS has been supplying the laser market with Terbium Gallium Garnet (TGG - Tb3Ga5O12) for many years. It is the most commonly used material for the 650-1100nm range and the key advantages for TGG include its cubic crystal structure for alignment free processing, little to no intrinsic birefringence, and ease of manufacture. However, for high-power laser applications TGG is limited by its absorption at 1064nm and its thermo-optic coefficient, dn/dT. Specifically, thermal lensing and depolarization effects become a limiting factor at high laser powers. While TGG absorption has improved significantly over the past few years, there is an intrinsic limit. Now, SYNOPTICS is commercializing the enhanced new crystal Potassium Terbium Fluoride KTF (KTb3F10) that exhibits much smaller nonlinear refractive index and thermo-optic coefficients, and still exhibits a Verdet constant near that of TGG. This cubic crystal has relatively low absorption and thermo-optic coefficients. It is now fully characterized and available for select production orders. At OPTIFAB in October 2017 we present recent results comparing the performance of KTF to TGG in optical isolators and show SYNOPTICS advances in large volume crystal growth and the production ramp up.

Thermo-mechanical evaluation of carbon-carbon primary structure for SSTO vehicles

NASA Astrophysics Data System (ADS)

Croop, Harold C.; Lowndes, Holland B.; Hahn, Steven E.; Barthel, Chris A.

1998-01-01

An advanced development program to demonstrate carbon-carbon composite structure for use as primary load carrying structure has entered the experimental validation phase. The component being evaluated is a wing torque box section for a single-stage-to-orbit (SSTO) vehicle. The validation or demonstration component features an advanced carbon-carbon design incorporating 3D woven graphite preforms, integral spars, oxidation inhibited matrix, chemical vapor deposited (CVD) oxidation protection coating, and ceramic matrix composite fasteners. The validation component represents the culmination of a four phase design and fabrication development effort. Extensive developmental testing was performed to verify material properties and integrity of basic design features before committing to fabrication of the full scale box. The wing box component is now being set up for testing in the Air Force Research Laboratory Structural Test Facility at Wright-Patterson Air Force Base, Ohio. One of the important developmental tests performed in support of the design and planned testing of the full scale box was the fabrication and test of a skin/spar trial subcomponent. The trial subcomponent incorporated critical features of the full scale wing box design. This paper discusses the results of the trial subcomponent test which served as a pathfinder for the upcoming full scale box test.

Effect of gadolinium dopant on structural, magneto-transport, magnetic and thermo-power of Pr0.8Sr0.2MnO3

NASA Astrophysics Data System (ADS)

Poojary, Thrapthi; Babu, P. D.; Sanil, Tejaswini; Daivajna, Mamatha D.

2018-07-01

In the present investigation structural, magneto-transport, magnetic and thermo-power measurements of Gadolinium (Gd) doped Pr0.8-xGdxSr0.2MnO3 (0, 0.2, 0.25 and 0.3) manganites have been done. All the samples are single phased with orthorhombic structure. Temperature variation of resistance exhibits a high temperature transition occurring at 156 K and a low temperature cusp at around 95 K for pristine sample. With Gd doping resistance behavior shows insulating behavior throughout the whole temperature range. Magneto-Resistance (MR%) increases with Gd doping. A huge increase in thermo-electric power is observed with Gd doping.

Noise Abatement and Internal Vibrational Absorption in Potential Structural Materials

DTIC Science & Technology

1975-03-01

martensitic transformation tempera- ture ranges. In contrast, much acoustic activity was detected dur- ing transformation in experiments using 7^ P...S0 Hi alloys in which "burst-type" martensitic transformation is known to occur (4). The above experiments indicate that the mechanism of... martensitic trans- formation in the highly damping NiTi alloys is of the thermo-elas- tic mode. In order to establish a stable transformation behavior as

Thermoset nanocomposites from two-component waterborne polyurethanes and cellulose whiskers.

PubMed

Wu, Guo-min; Chen, Jian; Huo, Shu-ping; Liu, Gui-feng; Kong, Zhen-wu

2014-05-25

We prepared thermoset nancomposites from biomass-based two-component waterborne polyurethane (2K-WPU) and cellulose namowhiskers (CNWs). Due to the formation of hydrogen bonds, the viscosity of 2K-WPU dispersion was found to be increased with the addition of CNWs. SEM images showed "sea-island structure" corresponding to the microphase separation between CNWs nano-filler and the 2K-WPU matrix. The α-relaxation temperature (Tα) and glass transition temperature (Tg) increased with the increase of CNWs content, which was due to the formation of a rigid CNWs nano-phase acting as crosslinking points in the 2K-WPU matrix. Mechanical properties from tensile test showed Young's modulus and tensile strength of 2K-WPU/CNWs nanocomposites were reinforced by the addition of CNWs. Thermo-stability of 2K-WPU/CNWs nanocomposites decreased slightly with the increase of CNWs content, which could be attributed to the increased thermal conductivity of the material after adding CNWs. Copyright © 2014 Elsevier Ltd. All rights reserved.

High pressure and temperature optical flow cell for near-infra-red spectroscopic analysis of gas mixtures.

PubMed

Norton, C G; Suedmeyer, J; Oderkerk, B; Fieback, T M

2014-05-01

A new optical flow cell with a new optical arrangement adapted for high pressures and temperatures using glass fibres to connect light source, cell, and spectrometer has been developed, as part of a larger project comprising new methods for in situ analysis of bio and hydrogen gas mixtures in high pressure and temperature applications. The analysis is based on measurements of optical, thermo-physical, and electromagnetic properties in gas mixtures with newly developed high pressure property sensors, which are mounted in a new apparatus which can generate gas mixtures with up to six components with an uncertainty of composition of as little as 0.1 mol. %. Measurements of several pure components of natural gases and biogases to a pressure of 20 MPa were performed on two isotherms, and with binary mixtures of the same pure gases at pressures to 17.5 MPa. Thereby a new method of analyzing the obtained spectra based on the partial density of methane was investigated.

Some Interesting Thermodynamics of the Thermos Flask

ERIC Educational Resources Information Center

Berger, Roland

2007-01-01

When opening a thermos flask filled with coffee, one often "hears" the equalization of the pressure difference that appears to be present between the air cavity inside the flask and the surrounding room atmosphere. Recently we discussed this phenomenon while drinking coffee and guessed about the direction of the gas stream accompanying the…

Investigating physical field effects on the size-dependent dynamic behavior of inhomogeneous nanoscale plates

NASA Astrophysics Data System (ADS)

Ebrahimi, Farzad; Reza Barati, Mohammad

2017-02-01

This article investigates the thermo-mechanical vibration frequencies of magneto-electro-thermo-elastic functionally graded (METE-FG) nanoplates in the framework of refined four-unknown shear deformation plate theory. The present nanoplate is subjected to various kinds of thermal loads with uniform, linear and nonlinear distributions. The nonlinear distribution is considered as heat conduction and sinusoidal temperature rise. The present refined theory captures the influences of shear deformations without the need for shear correction factors. Thermo-magneto-electro-elastic coefficients of the FG nanoplate vary gradually along the thickness according to the power-law form. The scale coefficient is taken into consideration implementing the nonlocal elasticity of Eringen. The governing equations are derived through Hamilton's principle and are solved analytically. The frequency response is compared with those of previously published data. The obtained results are presented for the thermo-mechanical vibrations of the FG nanobeams to investigate the effects of material graduation, nonlocal parameter, mode number, slenderness ratio and thermal loading in detail. The present study is associated to aerospace, mechanical and nuclear engineering structures which are under thermal loads.

Experimental study of thermo-mechanical behavior of a thermosetting shape-memory polymer

NASA Astrophysics Data System (ADS)

Liu, Ruoxuan; Li, Yunxin; Liu, Zishun

2018-01-01

The thermo-mechanical behavior of shape-memory polymers (SMPs) serves for the engineering applications of SMPs. Therefore the understanding of thermo-mechanical behavior of SMPs is of great importance. This paper investigates the influence of loading rate and loading level on the thermo-mechanical behavior of a thermosetting shape-memory polymer through experimental study. A series of cyclic tension tests and shape recovery tests at different loading conditions are performed to study the strain level and strain rate effect. The results of tension tests show that the thermosetting shape-memory polymer will behave as rubber material at temperature lower than the glass transition temperature (Tg) and it can obtain a large shape fix ratio at cyclic loading condition. The shape recovery tests exhibit that loading rate and loading level have little effect on the beginning and ending of shape recovery process of the thermosetting shape-memory polymer. Compared with the material which is deformed at temperature higher than Tg, the material deformed at temperature lower than Tg behaves a bigger recovery speed.

Thermo-optical interactions in a dye-microcavity photon Bose-Einstein condensate

NASA Astrophysics Data System (ADS)

Alaeian, Hadiseh; Schedensack, Mira; Bartels, Clara; Peterseim, Daniel; Weitz, Martin

2017-11-01

Superfluidity and Bose-Einstein condensation are usually considered as two closely related phenomena. Indeed, in most macroscopic quantum systems, like liquid helium, ultracold atomic Bose gases, and exciton-polaritons, condensation and superfluidity occur in parallel. In photon Bose-Einstein condensates realized in the dye microcavity system, thermalization does not occur by direct interaction of the condensate particles as in the above described systems, i.e. photon-photon interactions, but by absorption and re-emission processes on the dye molecules, which act as a heat reservoir. Currently, there is no experimental evidence for superfluidity in the dye microcavity system, though effective photon interactions have been observed from thermo-optic effects in the dye medium. In this work, we theoretically investigate the implications of effective thermo-optic photon interactions, a temporally delayed and spatially non-local effect, on the photon condensate, and derive the resulting Bogoliubov excitation spectrum. The calculations suggest a linear photon dispersion at low momenta, fulfilling the Landau’s criterion of superfluidity. We envision that the temporally delayed and long-range nature of the thermo-optic photon interaction offer perspectives for novel quantum fluid phenomena.

Acoustical and thermo physical properties of metal-ceramics composites in dependence on few volume concentration of metal

NASA Astrophysics Data System (ADS)

Abramovich, A.

2016-04-01

Metal-ceramics composites (cermets) are modern construction material used in different industry branches. Their strength and heat resistance depend on elastic and thermos physical properties. In this work cermets based on corundum and stainless steel (sintered in high vacuum at temperatures 1500 - 1600°C) are investigated. The volume steel concentration in the samples varies up 2 to 20 vol %. The elastic modules were measured by ultrasonic method at room temperature, measuring of thermo conductivity coefficient were carried out at temperatures 100, 200°C by method of continued heating in adiabatic calorimeter. We founded appearance of two extremes on dependences of elastic modules (E, G) on stainless steel concentrations, nature of which is unknown, modules values change in range: E = 110 - 310, G = 60 - 130GPa (for different temperatures of sintering). Similar dependence is observed for thermo conductivity coefficient which values varies up 10 to 40 W/(m.K). There is presented also discussion of results based on structure cermet model as multiphase micro heterogeneous media with isotropic physical properties in the work.

Supramolecular structure, phase behavior and thermo-rheological properties of a poly (L-lactide-co-ε-caprolactone) statistical copolymer.

PubMed

Ugartemendia, Jone M; Muñoz, M E; Santamaria, A; Sarasua, J R

2015-08-01

PLAcoCL samples, both unaged, termed PLAcoCLu, and aged over time, PLAcoCLa, were prepared and analyzed to study the phase structure, morphology, and their evolution under non-quiescent conditions. X- ray diffraction, Differential Scanning Calorimetry and Atomic Force Microscopy were complemented with thermo-rheological measurements to reveal that PLAcoCL evolves over time from a single amorphous metastable state to a 3 phase system, made up of two compositionally different amorphous phases and a crystalline phase. The supramolecular arrangements developed during aging lead to a rheological complex behavior in the PLAcoCLa copolymer: Around Tt=131 °C thermo-rheological complexity and a peculiar chain mobility reduction were observed, but at T>Tt the thermo-rheological response of a homogeneous system was recorded. In comparison with the latter, the PLLA/PCL 70:30 physical blend counterpart showed double amorphous phase behavior at all temperatures, supporting the hypothesis that phase separation in the PLAcoCLa copolymer is caused by the crystallization of polylactide segment blocks during aging. Copyright © 2015 Elsevier Ltd. All rights reserved.

Design guidelines for avoiding thermo-acoustic oscillations in helium piping systems

DOE PAGES

Gupta, Prabhat Kumar; Rabehl, Roger

2015-04-02

Thermo-acoustic oscillations are a commonly observed phenomenon in helium cryogenic systems, especially in tubes connecting hot and cold areas. The open ends of these tubes are connected to the lower temperature (typically at 4.5 K), and the closed ends of these tubes are connected to the high temperature (300 K). Cryogenic instrumentation installations provide ideal conditions for these oscillations to occur due to the steep temperature gradient along the tubing. These oscillations create errors in measurements as well as an undesirable heat load to the system. The work presented here develops engineering guidelines to design oscillation-free helium piping. This workmore » also studies the effect of different piping inserts and shows how the proper geometrical combinations have to be chosen to avoid thermo-acoustic oscillations. The effect of an 80 K intercept is also studied and shows that thermo-oscillations can be dampened by placing the intercept at an appropriate location. As a result, the design of helium piping based on the present work is also verified with the experimental results available in open literature.« less

Development of advanced high heat flux and plasma-facing materials

NASA Astrophysics Data System (ADS)

Linsmeier, Ch.; Rieth, M.; Aktaa, J.; Chikada, T.; Hoffmann, A.; Hoffmann, J.; Houben, A.; Kurishita, H.; Jin, X.; Li, M.; Litnovsky, A.; Matsuo, S.; von Müller, A.; Nikolic, V.; Palacios, T.; Pippan, R.; Qu, D.; Reiser, J.; Riesch, J.; Shikama, T.; Stieglitz, R.; Weber, T.; Wurster, S.; You, J.-H.; Zhou, Z.

2017-09-01

Plasma-facing materials and components in a fusion reactor are the interface between the plasma and the material part. The operational conditions in this environment are probably the most challenging parameters for any material: high power loads and large particle and neutron fluxes are simultaneously impinging at their surfaces. To realize fusion in a tokamak or stellarator reactor, given the proven geometries and technological solutions, requires an improvement of the thermo-mechanical capabilities of currently available materials. In its first part this article describes the requirements and needs for new, advanced materials for the plasma-facing components. Starting points are capabilities and limitations of tungsten-based alloys and structurally stabilized materials. Furthermore, material requirements from the fusion-specific loading scenarios of a divertor in a water-cooled configuration are described, defining directions for the material development. Finally, safety requirements for a fusion reactor with its specific accident scenarios and their potential environmental impact lead to the definition of inherently passive materials, avoiding release of radioactive material through intrinsic material properties. The second part of this article demonstrates current material development lines answering the fusion-specific requirements for high heat flux materials. New composite materials, in particular fiber-reinforced and laminated structures, as well as mechanically alloyed tungsten materials, allow the extension of the thermo-mechanical operation space towards regions of extreme steady-state and transient loads. Self-passivating tungsten alloys, demonstrating favorable tungsten-like plasma-wall interaction behavior under normal operation conditions, are an intrinsic solution to otherwise catastrophic consequences of loss-of-coolant and air ingress events in a fusion reactor. Permeation barrier layers avoid the escape of tritium into structural and cooling materials, thereby minimizing the release of tritium under normal operation conditions. Finally, solutions for the unique bonding requirements of dissimilar material used in a fusion reactor are demonstrated by describing the current status and prospects of functionally graded materials.

Band-to-Band Tunneling-Dominated Thermo-Enhanced Field Electron Emission from p-Si/ZnO Nanoemitters.

PubMed

Huang, Zhizhen; Huang, Yifeng; Xu, Ningsheng; Chen, Jun; She, Juncong; Deng, Shaozhi

2018-06-13

Thermo-enhancement is an effective way to achieve high performance field electron emitters, and enables the individually tuning on the emission current by temperature and the electron energy by voltage. The field emission current from metal or n-doped semiconductor emitter at a relatively lower temperature (i.e., < 1000 K) is less temperature sensitive due to the weak dependence of free electron density on temperature, while that from p-doped semiconductor emitter is restricted by its limited free electron density. Here, we developed full array of uniform individual p-Si/ZnO nanoemitters and demonstrated the strong thermo-enhanced field emission. The mechanism of forming uniform nanoemitters with well Si/ZnO mechanical joint in the nanotemplates was elucidated. No current saturation was observed in the thermo-enhanced field emission measurements. The emission current density showed about ten-time enhancement (from 1.31 to 12.11 mA/cm 2 at 60.6 MV/m) by increasing the temperature from 323 to 623 K. The distinctive performance did not agree with the interband excitation mechanism but well-fit to the band-to-band tunneling model. The strong thermo-enhancement was proposed to be benefit from the increase of band-to-band tunneling probability at the surface portion of the p-Si/ZnO nanojunction. This work provides promising cathode for portable X-ray tubes/panel, ionization vacuum gauges and low energy electron beam lithography, in where electron-dose control at a fixed energy is needed.

Low vibration microminiature split Stirling cryogenic cooler for infrared aerospace applications

NASA Astrophysics Data System (ADS)

Veprik, A.; Zechtzer, S.; Pundak, N.; Kirkconnel, C.; Freeman, J.; Riabzev, S.

2011-06-01

The operation of the thermo-mechanical unit of a cryogenic cooler may originate a resonant excitation of the spacecraft frame, optical bench or components of the optical train. This may result in degraded functionality of the inherently vibration sensitive space-borne infrared imager directly associated with the cooler or neighboring instrumentation typically requiring a quiet micro-g environment. The best practice for controlling cooler induced vibration relies on the principle of active momentum cancellation. In particular, the pressure wave generator typically contains two oppositely actuated piston compressors, while the single piston expander is counterbalanced by an auxiliary active counter-balancer. Active vibration cancellation is supervised by a dedicated DSP feed-forward controller, where the error signals are delivered by the vibration sensors (accelerometers or load cells). This can result in oversized, overweight and overpriced cryogenic coolers with degraded electromechanical performance and impaired reliability. The authors are advocating a reliable, compact, cost and power saving approach capitalizing on the combined application of a passive tuned dynamic absorber and a low frequency vibration isolator. This concept appears to be especially suitable for low budget missions involving mini and micro satellites, where price, size, weight and power consumption are of concern. The authors reveal the results of theoretical study and experimentation on the attainable performance using a fullscale technology demonstrator relying on a Ricor model K527 tactical split Stirling cryogenic cooler. The theoretical predictions are in fair agreement with the experimental data. From experimentation, the residual vibration export is quite suitable for demanding wide range of aerospace applications. The authors give practical recommendations on heatsinking and further maximizing performance.

Short- and long-term thermo-erosion of ice-rich permafrost coasts in the Laptev Sea region

NASA Astrophysics Data System (ADS)

Günther, F.; Overduin, P. P.; Sandakov, A. V.; Grosse, G.; Grigoriev, M. N.

2013-06-01

Permafrost coasts in the Arctic are susceptible to a variety of changing environmental factors all of which currently point to increasing coastal erosion rates and mass fluxes of sediment and carbon to the shallow arctic shelf seas. Rapid erosion along high yedoma coasts composed of Ice Complex permafrost deposits creates impressive coastal ice cliffs and inspired research for designing and implementing change detection studies for a long time, but continuous quantitative monitoring and a qualitative inventory of coastal thermo-erosion for large coastline segments is still lacking. Our goal is to use observations of thermo-erosion along the mainland coast of the Laptev Sea, in eastern Siberia, to understand how it depends on coastal geomorphology and the relative contributions of water level and atmospheric drivers. We compared multi-temporal sets of orthorectified satellite imagery from 1965 to 2011 for three segments of coastline ranging in length from 73 to 95 km and analyzed thermo-denudation (TD) along the cliff top and thermo-abrasion (TA) along the cliff bottom for two nested time periods: long-term rates (the past 39-43 yr) and short-term rates (the past 1-4 yr). The Normalized Difference Thermo-erosion Index (NDTI) was used as a proxy to qualitatively describe the relative proportions of TD and TA. Mean annual erosion rates at all three sites were higher in recent years (-5.3 ± 1.3 m a-1) than over the long-term mean (-2.2 ± 0.1 m a-1). The Mamontov Klyk coast exhibits primarily spatial variations of thermo-erosion, while intrasite-specific variations caused by local relief were strongest at the Buor Khaya coast, where the slowest long-term rates of around -0.5 ± 0.1 m a-1 were observed. The Oyogos Yar coast showed continuously rapid erosion up to -6.5 ± 0.2 m a-1. In general, variable characteristics of coastal thermo-erosion were observed not only between study sites and over time, but also within single coastal transects along the cliff profile. Varying intensities of cliff bottom and top erosion are leading to diverse qualities of coastal erosion that have different impacts on coastal mass fluxes. The different extents of Ice Complex permafrost degradation within our study sites turned out to influence not only the degree of coupling between TD and TA, and the magnitude of effectively eroded volumes, but also the quantity of organic carbon released to the shallow Laptev Sea from coastal erosion, which ranged on a long-term from 88 ± 21 to 800 ± 61 t per km coastline per year and will correspond to considerably higher amounts, if recently observed more rapid coastal erosion rates prove to be persistent.

Control of Thermo-Acoustics Instabilities: The Multi-Scale Extended Kalman Approach

NASA Technical Reports Server (NTRS)

Le, Dzu K.; DeLaat, John C.; Chang, Clarence T.

2003-01-01

"Multi-Scale Extended Kalman" (MSEK) is a novel model-based control approach recently found to be effective for suppressing combustion instabilities in gas turbines. A control law formulated in this approach for fuel modulation demonstrated steady suppression of a high-frequency combustion instability (less than 500Hz) in a liquid-fuel combustion test rig under engine-realistic conditions. To make-up for severe transport-delays on control effect, the MSEK controller combines a wavelet -like Multi-Scale analysis and an Extended Kalman Observer to predict the thermo-acoustic states of combustion pressure perturbations. The commanded fuel modulation is composed of a damper action based on the predicted states, and a tones suppression action based on the Multi-Scale estimation of thermal excitations and other transient disturbances. The controller performs automatic adjustments of the gain and phase of these actions to minimize the Time-Scale Averaged Variances of the pressures inside the combustion zone and upstream of the injector. The successful demonstration of Active Combustion Control with this MSEK controller completed an important NASA milestone for the current research in advanced combustion technologies.

Human Milk Processing: A Systematic Review of Innovative Techniques to Ensure the Safety and Quality of Donor Milk.

PubMed

Peila, Chiara; Emmerik, Nikki E; Giribaldi, Marzia; Stahl, Bernd; Ruitenberg, Joost E; van Elburg, Ruurd M; Moro, Guido E; Bertino, Enrico; Coscia, Alessandra; Cavallarin, Laura

2017-03-01

Pasteurization, performed at 62.5°C for 30 minutes (holder pasteurization), is currently recommended in all international human milk banks guidelines, but it affects some human milk bioactive and nutritive components. The present systematic review is aimed at critically reviewing evidence on the suitability of human milk processing techniques other than holder pasteurization, both thermal and nonthermal, to ensure microbiological safety, and on the effects of these techniques on biologically active donor milk components. A systematic review of English and non-English articles using Medline, PubMed, Embase, SCOPUS, and CAB Abstracts, with no restriction in publication date was performed. Search terms included: human, breast, donor, or banked milk, breastmilk, breast fed, breastfed, breastfeed; HTST, Flash, High Pressure, UV, ultrasonic or nonthermal; process, pasteuris, pasteuriz. Only primary research articles published in peer-reviewed journals were included, providing or not a comparison with holder pasteurized human milk, provided that the pasteurization technique was clearly described, and not intended for domestic use. Additional studies were identified by searching bibliographies of relevant articles. Twenty-six studies were identified as being relevant. Two examined both High Pressure Processing and High-Temperature-Short-Time pasteurization; 10 only examined High Pressure Processing; 10 only examined High-Temperature-Short-Time; 2 articles examined ultraviolet irradiation; 2 articles examined (thermo-)ultrasonic processing. The results indicate that data about safety for microbiological control are still scarce for most of the novel technologies, and that consensus on processing conditions is necessary for nonthermal technologies, before any conclusions on the qualitative and nutritional advantages of these techniques can be drawn.

Advanced Ceramics from Preceramic Polymers Modified at the Nano-Scale: A Review.

PubMed

Bernardo, Enrico; Fiocco, Laura; Parcianello, Giulio; Storti, Enrico; Colombo, Paolo

2014-03-06

Preceramic polymers, i.e. , polymers that are converted into ceramics upon heat treatment, have been successfully used for almost 40 years to give advanced ceramics, especially belonging to the ternary SiCO and SiCN systems or to the quaternary SiBCN system. One of their main advantages is the possibility of combining the shaping and synthesis of ceramics: components can be shaped at the precursor stage by conventional plastic-forming techniques, such as spinning, blowing, injection molding, warm pressing and resin transfer molding, and then converted into ceramics by treatments typically above 800 °C. The extension of the approach to a wider range of ceramic compositions and applications, both structural and thermo-structural (refractory components, thermal barrier coatings) or functional (bioactive ceramics, luminescent materials), mainly relies on modifications of the polymers at the nano-scale, i.e. , on the introduction of nano-sized fillers and/or chemical additives, leading to nano-structured ceramic components upon thermal conversion. Fillers and additives may react with the main ceramic residue of the polymer, leading to ceramics of significant engineering interest (such as silicates and SiAlONs), or cause the formation of secondary phases, significantly affecting the functionalities of the polymer-derived matrix.

Photovoltaic solar panels of crystalline silicon: Characterization and separation.

PubMed

Dias, Pablo Ribeiro; Benevit, Mariana Gonçalves; Veit, Hugo Marcelo

2016-03-01

Photovoltaic panels have a limited lifespan and estimates show large amounts of solar modules will be discarded as electronic waste in a near future. In order to retrieve important raw materials, reduce production costs and environmental impacts, recycling such devices is important. Initially, this article investigates which silicon photovoltaic module's components are recyclable through their characterization using X-ray fluorescence, X-ray diffraction, energy dispersion spectroscopy and atomic absorption spectroscopy. Next, different separation methods are tested to favour further recycling processes. The glass was identified as soda-lime glass, the metallic filaments were identified as tin-lead coated copper, the panel cells were made of silicon and had silver filaments attached to it and the modules' frames were identified as aluminium, all of which are recyclable. Moreover, three different components segregation methods have been studied. Mechanical milling followed by sieving was able to separate silver from copper while chemical separation using sulphuric acid was able to detach the semiconductor material. A thermo gravimetric analysis was performed to evaluate the use of a pyrolysis step prior to the component's removal. The analysis showed all polymeric fractions present degrade at 500 °C. © The Author(s) 2016.

Investigation of Structure and Property of Indian Cocos nucifera L. Fibre

NASA Astrophysics Data System (ADS)

Basu, Gautam; Mishra, Leena; Samanta, Ashis Kumar

2017-12-01

Structure and physico-mechanical properties of Cocos nucifera L. fibre from a specific agro-climatic region of India, was thoroughly studied. Fine structure of the fibre was examined by Fourier Transform Infra-Red (FTIR) spectroscopy, Thermo-Gravimetric Analysis (TGA), X-Ray Diffraction (XRD), component analysis, Scanning Electron Microscope (SEM) and optical microscope. SEM shows prominent longitudinal cracks and micro-pores on the surface. XRD shows a low degree of crystallinity (45%), bigger crystallite size, and even the presence of appreciable amount of non-cellulose matter. FTIR reveals presence of large quantities of hydroxyl, phenolic and aldehyde groups. Component and thermal analyses indicates presence of cellulose and lignin as major components. Physical parameters reveal that, fibres are highly variable in length (range 44-305 mm), and diameter (range 100-795 µm). Mechanical properties of the fibre viz. breaking tenacity, breaking extensibility, specific work of rupture, and coefficient of friction were measured. Microbial decomposition test under soil reveals excellent durability of coconut fibre which makes it appropriate for the application in geotextiles. Mass specific electrical resistance of 4 Ω-kg/m2 indicates its enhanced insulation as compared to the jute.

75 FR 30099 - Office of Hazardous Materials Safety; Notice of Applications for Modification of Special Permit

Federal Register 2010, 2011, 2012, 2013, 2014

2010-05-28

... to authorize 175.3 (Former the addition of Boron Grantee: Thermo trifluoride. Measure Tech), Sugar..., 175.3. the addition of Boron Thermo Measure trifluoride. Tech), Sugar Land, TX 14466-M Alaska Central... authorize Holdingford, MN the use of an alternative duplex stainless steel. 14763-M Weatherford 49 CFR 173...

Vibration isolation technology: Sensitivity of selected classes of experiments to residual accelerations

NASA Technical Reports Server (NTRS)

Alexander, J. Iwan D.

1991-01-01

Work was completed on all aspects of the following tasks: order of magnitude estimates; thermo-capillary convection - two-dimensional (fixed planar surface); thermo-capillary convection - three-dimensional and axisymmetric; liquid bridge/floating zone sensitivity; transport in closed containers; interaction: design and development stages; interaction: testing flight hardware; and reporting. Results are included in the Appendices.

Clinical phase I/II research on ultrasound thermo-chemotherapy in oral and maxillofacial-head and neck carcinoma

NASA Astrophysics Data System (ADS)

Shen, Guofeng; Ren, Guoxin; Guo, Wei; Chen, Yazhu

2012-11-01

The principle of a ultrasound thermo-chemotherapy instrument and the clinical phase I/II research on short-term and long-term therapeutic effect and main side-effect of ultrasound hyperthermia combined with chemotherapy in oral and maxillofacial-head & neck carcinoma by the instrument will be presented in this paper.

Rheological and thermo-mechanical properties of poly(lactic acid)/lignin-coated cellulose nanocrystal composites

Treesearch

Anju Gupta; William Simmons; Gregory T. Schueneman; Donald Hylton; Eric A. Mintz

2017-01-01

Improving the processability and physical properties of sustainable biobased polymers and biobased fillers is essential to preserve its biodegradability and make them suitable for different end user applications. Herein, we report the use of spray-dried lignin-coated cellulose nanocrystals (L-CNCs), a biobased filler, to modify the rheological and thermos-mechanical...

Torrefaction? What’s that?

Treesearch

D. Mitchell; T. Elder

2010-01-01

Torrefaction is a thermo-chemical process that reduces the moisture content of wood and transforms it into a brittle, char-type material. The thermo-chemical process can reduce the mass of wood by 20-30% resulting in a denser, higher-valued product that can be transported more economically than traditional wood chips. Through torrefaction, wood may retain 90% of the...

77 FR 5291 - Thermo Tech Technologies Inc., T.V.G. Technologies Ltd., and Visual Frontier, Inc.; Order of...

Federal Register 2010, 2011, 2012, 2013, 2014

2012-02-02

... SECURITIES AND EXCHANGE COMMISSION [File No. 500-1] Thermo Tech Technologies Inc., T.V.G. Technologies Ltd., and Visual Frontier, Inc.; Order of Suspension of Trading January 31, 2012. It appears to... is a lack of current and accurate information concerning the securities of T.V.G. Technologies Ltd...

Thermo-elastic behaviour of liquid crystal elastomer

NASA Astrophysics Data System (ADS)

J, Jessy P.; Mani, Santosh A.; Amare, Jyoti R.; Gharde, Rita A.

2015-06-01

The effect of temperature on Liquid Crystal Elastomer was studied to understand thermo-elastic behaviour of these fantastic soft materials. The investigations were performed using Polarizing Microscopy Studies (PMS) and Differential Thermal Analysis (DTA). The relative length shows hysteresis as function of temperature. As temperature increases, the length shrinks, while it returns to original shape on cooling.

Numerical Simulations of Single Flow Element in a Nuclear Thermal Thrust Chamber

NASA Technical Reports Server (NTRS)

Cheng, Gary; Ito, Yasushi; Ross, Doug; Chen, Yen-Sen; Wang, Ten-See

2007-01-01

The objective of this effort is to develop an efficient and accurate computational methodology to predict both detailed and global thermo-fluid environments of a single now element in a hypothetical solid-core nuclear thermal thrust chamber assembly, Several numerical and multi-physics thermo-fluid models, such as chemical reactions, turbulence, conjugate heat transfer, porosity, and power generation, were incorporated into an unstructured-grid, pressure-based computational fluid dynamics solver. The numerical simulations of a single now element provide a detailed thermo-fluid environment for thermal stress estimation and insight for possible occurrence of mid-section corrosion. In addition, detailed conjugate heat transfer simulations were employed to develop the porosity models for efficient pressure drop and thermal load calculations.

ThermoBuild: Online Method Made Available for Accessing NASA Glenn Thermodynamic Data

NASA Technical Reports Server (NTRS)

McBride, Bonnie; Zehe, Michael J.

2004-01-01

The new Web site program "ThermoBuild" allows users to easily access and use the NASA Glenn Thermodynamic Database of over 2000 solid, liquid, and gaseous species. A convenient periodic table allows users to "build" the molecules of interest and designate the temperature range over which thermodynamic functions are to be displayed. ThermoBuild also allows users to build custom databases for use with NASA's Chemical Equilibrium with Applications (CEA) program or other programs that require the NASA format for thermodynamic properties. The NASA Glenn Research Center has long been a leader in the compilation and dissemination of up-to-date thermodynamic data, primarily for use with the NASA CEA program, but increasingly for use with other computer programs.

Thermo-optic characteristics and switching power limit of slow-light photonic crystal structures on a silicon-on-insulator platform.

PubMed

Chahal, Manjit; Celler, George K; Jaluria, Yogesh; Jiang, Wei

2012-02-13

Employing a semi-analytic approach, we study the influence of key structural and optical parameters on the thermo-optic characteristics of photonic crystal waveguide (PCW) structures on a silicon-on-insulator (SOI) platform. The power consumption and spatial temperature profile of such structures are given as explicit functions of various structural, thermal and optical parameters, offering physical insight not available in finite-element simulations. Agreement with finite-element simulations and experiments is demonstrated. Thermal enhancement of the air-bridge structure is analyzed. The practical limit of thermo-optic switching power in slow light PCWs is discussed, and the scaling with key parameters is analyzed. Optical switching with sub-milliwatt power is shown viable.

Thermo-Physical Properties of Intermediate Temperature Heat Pipe Fluids

NASA Technical Reports Server (NTRS)

Beach, Duane E. (Technical Monitor); Devarakonda, Angirasa; Anderson, William G.

2005-01-01

Heat pipes are among the most promising technologies for space radiator systems. The paper reports further evaluation of potential heat pipe fluids in the intermediate temperature range of 400 to 700 K in continuation of two recent reports. More thermo-physical property data are examined. Organic, inorganic, and elemental substances are considered. The evaluation of surface tension and other fluid properties are examined. Halides are evaluated as potential heat pipe fluids. Reliable data are not available for all fluids and further database development is necessary. Many of the fluids considered are promising candidates as heat pipe fluids. Water is promising as a heat pipe fluid up to 500 to 550 K. Life test data for thermo-chemical compatibility are almost non-existent.

Aiding flow Thermo-Solutal Convection in Porous Cavity: ANN approach

NASA Astrophysics Data System (ADS)

Jafer Kazi1, Mohammed; Ameer Ahamad, N.; Yunus Khan, T. M.

2017-08-01

The transfer of thermal energy along with the diffusion of mass is common phenomenon that occurs in nature. The thermos-solutal convection in porous medium arises due to combined effect of diffusion of heat as well as mass inside the domain. The density variation of fluid due to absorbed heat at one end of porous cavity leads to fluid movement which in turn initiates the heat transfer. The mass diffusion inside the porous regime occurs due to concentration difference between two ends of cavity. Generally this phenomenon is studied with the help of numerical methods but current work emphasis the successful usage of artificial neural network in predicting the thermos-solutal convection of aiding flow in porous medium.

THERMOS. 30-Group ENDF/B Scattered Kernels

DOE Office of Scientific and Technical Information (OSTI.GOV)

McCrosson, F.J.; Finch, D.R.

1973-12-01

These data are 30-group THERMOS thermal scattering kernels for P0 to P5 Legendre orders for every temperature of every material from s(alpha,beta) data stored in the ENDF/B library. These scattering kernels were generated using the FLANGE2 computer code. To test the kernels, the integral properties of each set of kernels were determined by a precision integration of the diffusion length equation and compared to experimental measurements of these properties. In general, the agreement was very good. Details of the methods used and results obtained are contained in the reference. The scattering kernels are organized into a two volume magnetic tapemore » library from which they may be retrieved easily for use in any 30-group THERMOS library.« less

Universal mechanism of thermo-mechanical deformation in metallic glasses

DOE PAGES

Dmowski, W.; Tong, Y.; Iwashita, T.; ...

2015-02-11

Here we investigated the atomistic structure of metallic glasses subjected to thermo-mechanical creep deformation using high energy x-ray diffraction and molecular dynamics simulation. The experiments were performed in-situ, at high temperatures as a time dependent deformation in the elastic regime, and ex-situ on samples quenched under stress. We show that all the anisotropic structure functions of the samples undergone thermo-mechanical creep can be scaled into a single curve, regardless of the magnitude of anelastic strain, stress level and the sign of the stress, demonstrating universal behavior and pointing to unique atomistic unit of anelastic deformation. The structural changes due tomore » creep are strongly localized within the second nearest neighbors, involving only a small group of atoms.« less

Thermo-Physical Properties of Intermediate Temperature Heat Pipe Fluids

NASA Technical Reports Server (NTRS)

Devarakonda, Angirasa; Anderson, William G.

2004-01-01

Heat pipes are among the most promising technologies for space radiator systems. The paper reports further evaluation of potential heat pipe fluids in the intermediate temperature range of 400 to 700 K in continuation of two recent reports. More thermo-physical property data are examined. Organic, inorganic and elemental substances are considered. The evaluation of surface tension and other fluid properties are examined. Halides are evaluated as potential heat pipe fluids. Reliable data are not available for all fluids and further database development in necessary. Many of the fluids considered are promising candidates as heat pipe fluids. Water is promising as a heat pipe fluid up to 500-550 K. Life test data for thermo-chemical compatibility are almost non-existent.

Improved high-temperature resistant matrix resins

NASA Technical Reports Server (NTRS)

Green, H. E.; Chang, G. E.; Wright, W. F.; Ueda, K.; Orell, M. K.

1989-01-01

A study was performed with the objective of developing matrix resins that exhibit improved thermo-oxidative stability over state-of-the-art high temperature resins for use at temperatures up to 644 K (700 F) and air pressures up to 0.7 MPa (100 psia). The work was based upon a TRW discovered family of polyimides currently licensed to and marketed by Ethyl Corporation as EYMYD(R) resins. The approach investigated to provide improved thermo-oxidative properties was to use halogenated derivatives of the diamine, 2, 2-bis (4-(4-aminophenoxy)phenyl) hexafluoropropane (4-BDAF). Polyimide neat resins and Celion(R) 12,000 composites prepared from fluorine substituted 4-BDAF demonstrated unexpectedly lower glass transition temperatures (Tg) and thermo-oxidative stabilities than the baseline 4-BDAF/PMDA polymer.

Photoperiod- and thermo-sensitive genic male sterility in rice are caused by a point mutation in a novel noncoding RNA that produces a small RNA.

PubMed

Zhou, Hai; Liu, Qinjian; Li, Jing; Jiang, Dagang; Zhou, Lingyan; Wu, Ping; Lu, Sen; Li, Feng; Zhu, Liya; Liu, Zhenlan; Chen, Letian; Liu, Yao-Guang; Zhuang, Chuxiong

2012-04-01

Photoperiod- and thermo-sensitive genic male sterility (PGMS and TGMS) are the core components for hybrid breeding in crops. Hybrid rice based on the two-line system using PGMS and TGMS lines has been successfully developed and applied widely in agriculture. However, the molecular mechanism underlying the control of PGMS and TGMS remains obscure. In this study, we mapped and cloned a major locus, p/tms12-1 (photo- or thermo-sensitive genic male sterility locus on chromosome 12), which confers PGMS in the japonica rice line Nongken 58S (NK58S) and TGMS in the indica rice line Peiai 64S (PA64S, derived from NK58S). A 2.4-kb DNA fragment containing the wild-type allele P/TMS12-1 was able to restore the pollen fertility of NK58S and PA64S plants in genetic complementation. P/TMS12-1 encodes a unique noncoding RNA, which produces a 21-nucleotide small RNA that we named osa-smR5864w. A substitution of C-to-G in p/tms12-1, the only polymorphism relative to P/TMS12-1, is present in the mutant small RNA, namely osa-smR5864m. Furthermore, overexpression of a 375-bp sequence of P/TMS12-1 in transgenic NK58S and PA64S plants also produced osa-smR5864w and restored pollen fertility. The small RNA was expressed preferentially in young panicles, but its expression was not markedly affected by different day lengths or temperatures. Our results reveal that the point mutation in p/tms12-1, which probably leads to a loss-of-function for osa-smR5864m, constitutes a common cause for PGMS and TGMS in the japonica and indica lines, respectively. Our findings thus suggest that this noncoding small RNA gene is an important regulator of male development controlled by cross-talk between the genetic networks and environmental conditions.

Integrated approach for stress based lifing of aero gas turbine blades

NASA Astrophysics Data System (ADS)

Abu, Abdullahi Obonyegba

In order to analyse the turbine blade life, the damage due to the combined thermal and mechanical loads should be adequately accounted for. This is more challenging when detailed component geometry is limited. Therefore, a compromise between the level of geometric detail and the complexity of the lifing method to be implemented would be necessary. This research focuses on how the life assessment of aero engine turbine blades can be done, considering the balance between available design inputs and adequate level of fidelity. Accordingly, the thesis contributes to developing a generic turbine blade lifing method that is based on the engine thermodynamic cycle; as well as integrating critical design/technological factors and operational parameters that influence the aero engine blade life. To this end, thermo-mechanical fatigue was identified as the critical damage phenomenon driving the life of the turbine blade.. The developed approach integrates software tools and numerical models created using the minimum design information typically available at the early design stages. Using finite element analysis of an idealised blade geometry, the approach captures relevant impacts of thermal gradients and thermal stresses that contribute to the thermo-mechanical fatigue damage on the gas turbine blade. The blade life is evaluated using the Neu/Sehitoglu thermo-mechanical fatigue model that considers damage accumulation due to fatigue, oxidation, and creep. The leading edge is examined as a critical part of the blade to estimate the damage severity for different design factors and operational parameters. The outputs of the research can be used to better understand how the environment and the operating conditions of the aircraft affect the blade life consumption and therefore what is the impact on the maintenance cost and the availability of the propulsion system. This research also finds that the environmental (oxidation) effect drives the blade life and the blade coolant side was the critical location. Furthermore, a parametric and sensitivity study of the Neu/Sehitoglu model parameters suggests that in addition to four previously reported parameters, the sensitivity of the phasing to oxidation damage would be critical to overall blade life..

PRE_X Programme: Aerothermodynamic Objectives and Aeroshape Definition for in Flight Experiments

NASA Astrophysics Data System (ADS)

Lambert, O.; Tribot, J.-P.; Saint-Cloud, F.

2002-01-01

As the expendable launch vehicles (ELV) are limited in their trend to lower costs, the reusability (Reusable Launch Vehicle, RLV) could be the way to make drastic step. By the year 2001, CNES proposed through the ANGEL phase 1 programme to preprare the required technical maturity before that RLV's become alternatives to ELV's. In such way, system ,propulsion, ground based demonstrations, aero-thermo-dynamics as well as in flight experimentation are planned. This paper is focused on the aero-thermo-dynamics (ATD) and in flight demonstration activities with emphasis on the better understanding of ATD problems emerging from past programmes among them shock wave transitionnal boundary layer interaction on surface control, boundary layer transition, local aerothermodynamic effects, gas- surface interaction, catalycity, base flow prediction,...In order to minimize as small as possible the management risk a first generation of vehicle dubbed Pre_X is designed to validate technological choices and to have as soon as possible re-entry data to calibrate the various tools involved in the future RLV definition. In addition, the main requirement for PRE_X aeroshape definition and the two different design approaches considered by Dassault Aviation and EADS-LV are discussed. Then, the more promising concept for the PRE_X application is presented. Finally, the current status of the ATD activities is given as well as the perspectives.

Dynamics of meso and thermo citrate synthases with implicit solvation

NASA Astrophysics Data System (ADS)

Cordeiro, J. M. M.

The dynamics of hydration of meso and thermo citrate synthases has been investigated using the EEF1 methodology implemented with the CHARMM program. The native enzymes are composed of two identical subunits, each divided into a small and large domain. The dynamics behavior of both enzymes at 30°C and 60°C has been compared. The results of simulations show that during the hydration process, each subunit follows a different pathway of hydration, in spite of the identical sequence. The hydrated structures were compared with the crystalline structure, and the root mean square deviation (RMSD) of each residue along the trajectory was calculated. The regions with larger and smaller mobility were identified. In particular, helices belonging to the small domain are more mobile than those of the large domain. In contrast, the residues that constitute the active site show a much lower displacement compared with the crystalline structure. Hydration free energy calculations point out that Thermoplasma acidophilum citrate synthase (TCS) is more stable than chicken citrate synthase (CCS), at high temperatures. Such result has been ascribed to the higher number of superficial charges in the thermophilic homologue, which stabilizes the enzyme, while the mesophilic homologue denatures. These results are in accord with the experimental found that TCS keeps activity at temperatures farther apart from the catalysis regular temperature than the CCS.

Baseline Air Quality Assessment of Goods Movement Activities before the Port of Charleston Expansion: A Community–University Collaborative

PubMed Central

Wilson, Sacoby M.; Tarver, Siobhan L.; Svendsen, Erik; Jiang, Chengsheng; Ogunsakin, Olalekan A.; Zhang, Hongmei; Campbell, Dayna; Fraser-Rahim, Herbert

2017-01-01

Abstract As the demand for goods continues to increase, a collective network of transportation systems is required to facilitate goods movement activities. This study examines air quality near the Port of Charleston before its expansion and briefly describes the establishment and structure of a community–university partnership used to monitor existing pollution. Particulate matter (PM) concentrations (PM2.5 and PM10) were measured using the Thermo Fisher Scientific Partisol 2000i-D Dichotomous Air Sampler, Thermo Scientific Dichotomous Sequential Air Sampler Partisol-Plus 2025-D, and Rupprecht & Patashnick TEOM Series 1400 Sampler at neighborhood (Union Heights, Rosemont, and Accabee) and reference (FAA2.5 and Jenkins Street) sites. Descriptive statistics were performed and an ANOVA (analysis of variance) was calculated to find the difference in overall mean 24-hour PM average concentrations in communities impacted by environmental injustice. PM2.5 (15.2 μg/m3) and PM10 (27.2 μg/m3) maximum concentrations were highest in neighborhoods such as Union Heights neighborhoods due to more goods movement activities. Nevertheless, there was no statistically significant difference in mean concentrations of PM2.5 and PM10 across neighborhood sites. In contrast, mean PM10 neighborhood concentrations were significantly lower than mean PM10 reference concentrations for Union Heights (p = 0.00), Accabee (p ≤ 0.0001), and Rosemont (p = 0.01). Although PM concentrations were lower than current National Ambient Air Quality Standards, this study demonstrated how community–university partners can work collectively to document baseline PM concentrations that will be used to examine changes in air quality after the port expansion brings additional goods movement activities to the area. PMID:29576842

Halloysite nanotubes loaded with peppermint essential oil as filler for functional biopolymer film.

PubMed

Biddeci, G; Cavallaro, G; Di Blasi, F; Lazzara, G; Massaro, M; Milioto, S; Parisi, F; Riela, S; Spinelli, G

2016-11-05

The purpose of this paper is to show how a functional bionanocomposite film with both antioxidant and antimicrobial activities was successfully prepared by the filling of a pectin matrix with modified Halloysite nanotubes (HNT) containing the essential peppermint oil (PO). Firstly, HNT surfaces were functionalized with cucurbit[6]uril (CB[6]) molecules with the aim to enhance the affinity of the nanofiller towards PO, which was estimated by means of HPLC experiments. The HNT/CB[6] hybrid was characterized by several methods (thermogravimetry, FT-IR spectroscopy and scanning electron microscopy) highlighting the influence of the supramolecular interactions on the composition, thermal behavior and morphology of the filler. Then, a pectin+HNT/CB[6] biofilm was prepared by the use of the casting method under specific experimental conditions in order to favor the entrapment of the volatile PO into the nanocomposite structure. Water contact angle measurements, thermogravimetry and tensile tests evidenced the effects of the modified filler on the thermo-mechanical and wettability properties of pectin, which were correlated to the microscopic structure of the biocomposite film. In addition, PO release in food simulant solvent was investigated at different temperatures (4 and 25°C), whereas the antioxidant activity of the nanocomposite film was estimated using the DPPH method. Finally, we studied the in vitro antibacterial activity of the biofilm against Escherichia coli (Gram-negative) and Staphylococcus aureus (Gram-positive), which were isolated by beef and cow milk, respectively. These experiments were carried out at specific temperatures (4, 37 and 65°C) that can be useful for a multi-step food conservation. This paper puts forwards an easy strategy to prepare a functional sustainable edible film with thermo-sensitive antioxidant/antimicrobial activity. Copyright © 2016 Elsevier Ltd. All rights reserved.

Thermo-acoustical molecular interaction study in binary mixtures of glycerol and ethylene glycol

NASA Astrophysics Data System (ADS)

Kaur, Kirandeep; Juglan, K. C.; Kumar, Harsh

2017-07-01

Ultrasonic velocity, density and viscosity are measured over the entire composition range for binary liquid mixtures of glycerol (CH2OH-CHOH-CH2OH) and ethylene glycol (HOCH2CH2OH) at different temperatures and constant frequency of 2MHz using ultrasonic interferometer, specific gravity bottle and viscometer respectively. Measured experimental values are used to obtained various acoustical parameters such as adiabatic compressibility, acoustic impedance, intermolecular free length, relaxation time, ultrasonic attenuation, effective molar weight, free volume, available volume, molar volume, Wada's constant, Rao's constant, Vander Waal's constant, internal pressure, Gibb's free energy and enthalpy. The variation in acoustical parameters are interpreted in terms of molecular interactions between the components of molecules of binary liquid mixtures.

The Classification of Ground Roasted Decaffeinated Coffee Using UV-VIS Spectroscopy and SIMCA Method

NASA Astrophysics Data System (ADS)

Yulia, M.; Asnaning, A. R.; Suhandy, D.

2018-05-01

In this work, an investigation on the classification between decaffeinated and non- decaffeinated coffee samples using UV-VIS spectroscopy and SIMCA method was investigated. Total 200 samples of ground roasted coffee were used (100 samples for decaffeinated coffee and 100 samples for non-decaffeinated coffee). After extraction and dilution, the spectra of coffee samples solution were acquired using a UV-VIS spectrometer (Genesys™ 10S UV-VIS, Thermo Scientific, USA) in the range of 190-1100 nm. The multivariate analyses of the spectra were performed using principal component analysis (PCA) and soft independent modeling of class analogy (SIMCA). The SIMCA model showed that the classification between decaffeinated and non-decaffeinated coffee samples was detected with 100% sensitivity and specificity.

Numerical modeling of fluid migration in subduction zones

NASA Astrophysics Data System (ADS)

Walter, M. J.; Quinteros, J.; Sobolev, S. V.

2015-12-01

It is well known that fluids play a crucial role in subduction evolution. For example, mechanical weakening along tectonic interfaces, due to high fluid pressure, may enable oceanic subduction. Hence, the fluid content seems to be a critical parameter for subduction initiation. Studies have also shown a correlation between the location of slab dehydration and intermediate seismic activity. Furthermore, expelled fluids from the subduction slab affect the melting temperature, consequently, contributing to partial melting in the wedge above the down-going plate and extensive volcanism. In summary, fluids have a great impact on tectonic processes and therefore should be incorporated into geodynamic numerical models. Here we use existing approaches to couple and solve fluid flow equations in the SLIM-3D thermo-mechanical code. SLIM-3D is a three-dimensional thermo-mechanical code capable of simulating lithospheric deformation with elasto-visco-plastic rheology. It has been successfully applied to model geodynamic processes at different tectonic settings, including subduction zones. However, although SLIM-3D already includes many features, fluid migration has not been incorporated into the model yet. To this end, we coupled solid and fluid flow assuming that fluids flow through a porous and deformable solid. Thereby, we introduce a two-phase flow into the model, in which the Stokes flow is coupled with the Darcy law for fluid flow. Ultimately, the evolution of porosity is governed by a compaction pressure and the advection of the porous solid. We show the details of our implementation of the fluid flow into the existing thermo-mechanical finite element code and present first results of benchmarks and experiments. We are especially interested in the coupling of subduction processes and the evolution of the magmatic arc. Thereby, we focus on the key factors controlling magma emplacement and its influence on subduction processes.

Drug releasing nanoplatforms activated by alternating magnetic fields.

PubMed

Mertz, Damien; Sandre, Olivier; Bégin-Colin, Sylvie

2017-06-01

The use of an alternating magnetic field (AMF) to generate non-invasively and spatially a localized heating from a magnetic nano-mediator has become very popular these last years to develop magnetic hyperthermia (MH) as a promising therapeutic modality already used in the clinics. AMF has become highly attractive this last decade over others radiations, as AMF allows a deeper penetration in the body and a less harmful ionizing effect. In addition to pure MH which induces tumor cell death through local T elevation, this AMF-generated magneto-thermal effect can also be exploited as a relevant external stimulus to trigger a drug release from drug-loaded magnetic nanocarriers, temporally and spatially. This review article is focused especially on this concept of AMF induced drug release, possibly combined with MH. The design of such magnetically responsive drug delivery nanoplatforms requires two key and complementary components: a magnetic mediator which collects and turns the magnetic energy into local heat, and a thermoresponsive carrier ensuring thermo-induced drug release, as a consequence of magnetic stimulus. A wide panel of magnetic nanomaterials/chemistries and processes are currently developed to achieve such nanoplatforms. This review article presents a broad overview about the fundamental concepts of drug releasing nanoplatforms activated by AMF, their formulations, and their efficiency in vitro and in vivo. This article is part of a Special Issue entitled "Recent Advances in Bionanomaterials" Guest Editors: Dr. Marie-Louise Saboungi and Dr. Samuel D. Bader. Copyright © 2017 Elsevier B.V. All rights reserved.

Thermo-mechanical Modelling of Pebble Beds in Fusion Blankets and its Implementation by a Return-Mapping Algorithm

DOE Office of Scientific and Technical Information (OSTI.GOV)

Gan, Yixiang; Kamlah, Marc

In this investigation, a thermo-mechanical model of pebble beds is adopted and developed based on experiments by Dr. Reimann at Forschungszentrum Karlsruhe (FZK). The framework of the present material model is composed of a non-linear elastic law, the Drucker-Prager-Cap theory, and a modified creep law. Furthermore, the volumetric inelastic strain dependent thermal conductivity of beryllium pebble beds is taken into account and full thermo-mechanical coupling is considered. Investigation showed that the Drucker-Prager-Cap model implemented in ABAQUS can not fulfill the requirements of both the prediction of large creep strains and the hardening behaviour caused by creep, which are of importancemore » with respect to the application of pebble beds in fusion blankets. Therefore, UMAT (user defined material's mechanical behaviour) and UMATHT (user defined material's thermal behaviour) routines are used to re-implement the present thermo-mechanical model in ABAQUS. An elastic predictor radial return mapping algorithm is used to solve the non-associated plasticity iteratively, and a proper tangent stiffness matrix is obtained for cost-efficiency in the calculation. An explicit creep mechanism is adopted for the prediction of time-dependent behaviour in order to represent large creep strains in high temperature. Finally, the thermo-mechanical interactions are implemented in a UMATHT routine for the coupled analysis. The oedometric compression tests and creep tests of pebble beds at different temperatures are simulated with the help of the present UMAT and UMATHT routines, and the comparison between the simulation and the experiments is made. (authors)« less

Synthesis of Mg{sub 2}SiO{sub 4}:Dy{sup 3+} nanoparticles by hydrothermal method and investigation of their thermo and photo luminescence properties

DOE Office of Scientific and Technical Information (OSTI.GOV)

Ghahari, M., E-mail: maghahari@icrc.ac.ir; Mostafavi, K.

2016-05-15

Highlights: • Mg{sub 2}SiO{sub 4}:Dy{sup 3+} nanoparticles have been prepared by hydrothermal and combustion methods. • Thermo and photo luminescent behavior of Mg{sub 2}SiO{sub 4}:Dy{sup 3+} was studied. • The effect of synthesis method on TL properties of Mg{sub 2}SiO{sub 4}:Dy{sup 3+} was investigated. • The optimal dopant concentration for thermo-luminescent property was obtained. - Abstract: In this study, photo and thermo-luminescent properties of Nano crystalline Mg{sub 2}SiO{sub 4}:Dy{sup 3+} prepared by a hydrothermal method were studied and compared to those of nanoparticles prepared by combustion method. The synthesized sample was characterized by X-ray diffraction, transmission electron microscopy, scanning electronmore » microscopy and photoluminescence spectroscopy. The effect of Dy concentration on photo and thermoluminescent intensities was studied. The X-ray diffraction (XRD) patterns of the samples revealed that forsterite was formed as a major phase for all the samples. The crystallite size was found to be in the range of 20–50 nm. The thermo luminescent glow curve indicated that the hydrothermal sample was more efficient than the combustion sample. Two prominent TL bands located at 200 nm and 320 nm were recorded. The prepared nanoparticles exhibited a roughly linear dose response to absorbed dose of 1000 Gy received from 60Co gamma source, suggesting that nanomaterial could be a good candidate for high dose dosimetry.« less

Thermo-responsive mesoporous silica/lipid bilayer hybrid nanoparticles for doxorubicin on-demand delivery and reduced premature release.

PubMed

Zhang, Qing; Chen, Xuanxuan; Shi, Huihui; Dong, Gaoqiu; Zhou, Meiling; Wang, Tianji; Xin, Hongliang

2017-12-01

Hybrid nanocarriers based on mesoporous silica nanoparticles (MSNs) and supported lipid bilayer (SLB) have been studied as drug delivery system. It still remains challenges to develop these nanocarriers (SLB-MSNs) with on-demand drug release profile for chemotherapy. Here, we reported the biocompatible SLB-MSNs with high drug loading, which could release doxorubicin (DOX) in response to hyperthermia and reduce premature release. After synthesis of MSNs via a sol-gel procedure, the thermo-responsive SLB was deposited on the MSNs by sonication to completely seal the mesopores. The obtained SLB-MSNs consisted of 50 nm-sized MSN cores and 6.3 nm-thick SLB shells. Due to the big surface and pore volume of MSNs, the high drug loading content (7.30±0.02%) and encapsulation efficiency (91.16±0.28%) were achieved. The SLB blocking the mesopores reduced 50% of premature release and achieved on-demand release in a thermo-responsive manner. Moreover, SLB-MSNs showed good hemocompatibility at any tested concentration (25-700μg/mL), while bare MSNs caused 100% of hemolysis at concentration larger than 325μg/mL. In addition, in vitro U251 cell uptake experiment demonstrated that compared with uncapped MSNs, SLB-MSNs could prevent untargeted cellular uptake of DOX owing to reduced premature release and steric hindrance of PEG, which would be beneficial to minimize toxicity for healthy tissues. These results indicated that SLB-MSNs with thermo-responsive release capacity possessed great potential in future synergistic thermo-chemotherapy. Copyright © 2017 Elsevier B.V. All rights reserved.

High-capacity thermo-responsive magnetic molecularly imprinted polymers for selective extraction of curcuminoids.

PubMed

You, Qingping; Zhang, Yuping; Zhang, Qingwen; Guo, Junfang; Huang, Weihua; Shi, Shuyun; Chen, Xiaoqin

2014-08-08

Thermo-responsive magnetic molecularly imprinted polymers (TMMIPs) for selective recognition of curcuminoids with high capacity and selectivity have firstly been developed. The resulting TMMIPs were characterized by TEM, FT-IR, TGA, VSM and UV, which indicated that TMMIPs showed thermo-responsiveness [lower critical solution temperature (LCST) at 33.71°C] and rapid magnetic separation (5s). The polymerization, adsorption and release conditions were optimized in detail to obtain the highest binding capacity, selectivity and release ratio. We found that the adopted thermo-responsive monomer [N-isopropylacrylamide (NIPAm)] could be considered not only as inert polymer backbone for thermo-responsiveness but also as functional co-monomers combination with basic monomer (4-VP) for more specific binding sites when ethanol was added in binding solution. The maximum adsorption capacity with highest selectivity of curcumin was 440.3μg/g (1.93 times that on MMIPs with no thermosensitivity) at 45°C (above LCST) in 20% (v/v) ethanol solution on shrunk TMMIPs, and the maximum release proportion was about 98% at 20°C (below LCST) in methanol-acetic acid (9/1, v/v) solution on swelled TMMIPs. The adsorption process between curcumin and TMMIPs followed Langumuir adsorption isotherm and pseudo-first-order reaction kinetics. The prepared TMMIPs also showed high reproducibility (RSD<6% for batch-to-batch evaluation) and stability (only 7% decrease after five cycles). Subsequently, the TMMIPs were successfully applied for selective extraction of curcuminoids from complex natural product, Curcuma longa. Copyright © 2014 Elsevier B.V. All rights reserved.

Absence of Sperm Factors as in the Parthenogenesis Does Not Interfere on Bovine Embryo Sensitiveness to Heat Shock at Pre-Implantation Stage.

PubMed

Camargo, L S A; Paludo, F; Pereira, M M; Wohlres-Viana, S; Gioso, M M; Carvalho, B C; Quintao, C C R; Viana, J H M

2016-02-01

Oocyte has been considered the major contributor for embryo thermo-tolerance. However, it was shown that sperm factors can be transferred to the oocyte during fertilization, raising the question of whether the absence of such factors could interfere on embryo thermo-tolerance. In this study, we used parthenogenesis to generate bovine embryos without spermatozoa in order to test whether the absence of sperm factors could influence their thermo-sensitiveness at early stages. In vitro fertilized (IVF) and parthenogenetic (PA) embryos at 44 h post-insemination/chemical activation were exposed to 38.5°C (control) or 41°C (heat shock) for 12 h and then developed for 48 h and up to blastocyst stage. Apoptosis index and expression of PRDX1, GLUT1, GLUT5 and IGF1r genes in blastocysts derived from heat-shocked embryos were also evaluated. The heat shock decreased the blastocyst rate at day seven (p < 0.05) for IVF embryos and at day eight (p < 0.01) for both IVF and PA embryos. Total cell number was not affected by heat shock in IVF and PA blastocysts, but there was an increased proportion (p < 0.05) of apoptotic cells in heat-shocked embryos when compared to controls. There was no interaction (p > 0.05) between method of activation (IVF and PA) and temperature (38.5°C or 41.5°C) for all developmental parameters evaluated. Expression of GLUT1 gene was downregulated (p < 0.05) by heat shock in both IVF and PA blastocyst whereas expression of GLUT5 and IGF1r genes was downregulated (p < 0.05) by heat shock in PA blastocysts. Those data show that the heat shock affects negatively the embryo development towards blastocysts stage, increases the apoptotic index and disturbed the expression of some genes in both IVF and PA embryos, indicating that the presence or absence of sperm factors does not influence the sensitivity of the bovine embryo to heat shock. © 2015 Blackwell Verlag GmbH.

Influence of condensed species on thermo-physical properties of LTE and non-LTE SF6-Cu mixture

NASA Astrophysics Data System (ADS)

Chen, Zhexin; Wu, Yi; Yang, Fei; Sun, Hao; Rong, Mingzhe; Wang, Chunlin

2017-10-01

SF6-Cu mixture is frequently formed in high-voltage circuit breakers due to the electrode erosion and metal vapor diffusion. During the interruption process, the multiphase effect and deviation from local thermal equilibrium (non-LTE assumption) can both affect the thermo-physical of the arc plasma and further influence the performance of circuit breaker. In this paper, thermo-physical properties, namely composition, thermodynamic properties and transport coefficients are calculated for multiphase SF6-Cu mixture with and without LTE assumption. The composition is confirmed by combining classical two-temperature mass action law with phase equilibrium condition deduced from second law of thermodynamics. The thermodynamic properties and transport coefficients are calculated using the multiphase composition result. The influence of condensed species on thermo-physical properties is discussed at different temperature, pressure (0.1-10 atm), non-equilibrium degrees (1-10), and copper molar proportions (0-50%). It is found that the multiphase effect has significant influence on specific enthalpy, specific heat and heavy species thermal conductivity in both LTE and non-LTE SF6-Cu system. This paper provides a more accurate database for computational fluid dynamic calculation.

Ultra-compact and wide-spectrum-range thermo-optic switch based on silicon coupled photonic crystal microcavities

DOE Office of Scientific and Technical Information (OSTI.GOV)

Zhang, Xingyu, E-mail: xzhang@utexas.edu, E-mail: swapnajit.chakravarty@omegaoptics.com, E-mail: chenrt@austin.utexas.edu; Chung, Chi-Jui; Pan, Zeyu

2015-11-30

We design, fabricate, and experimentally demonstrate a compact thermo-optic gate switch comprising a 3.78 μm-long coupled L0-type photonic crystal microcavities on a silicon-on-insulator substrate. A nanohole is inserted in the center of each individual L0 photonic crystal microcavity. Coupling between identical microcavities gives rise to bonding and anti-bonding states of the coupled photonic molecules. The coupled photonic crystal microcavities are numerically simulated and experimentally verified with a 6 nm-wide flat-bottom resonance in its transmission spectrum, which enables wider operational spectrum range than microring resonators. An integrated micro-heater is in direct contact with the silicon core to efficiently drive the device. The thermo-opticmore » switch is measured with an optical extinction ratio of 20 dB, an on-off switching power of 18.2 mW, a thermo-optic tuning efficiency of 0.63 nm/mW, a rise time of 14.8 μs, and a fall time of 18.5 μs. The measured on-chip loss on the transmission band is as low as 1 dB.« less

Thermo-electronic solar power conversion with a parabolic concentrator

NASA Astrophysics Data System (ADS)

Olukunle, Olawole C.; De, Dilip K.

2016-02-01

We consider the energy dynamics of the power generation from the sun when the solar energy is concentrated on to the emitter of a thermo-electronic converter with the help of a parabolic mirror. We use the modified Richardson-Dushman equation. The emitter cross section is assumed to be exactly equal to the focused area at a height h from the base of the mirror to prevent loss of efficiency. We report the variation of output power with solar insolation, height h, reflectivity of the mirror, and anode temperature, initially assuming that there is no space charge effect. Our methodology allows us to predict the temperature at which the anode must be cooled in order to prevent loss of efficiency of power conversion. Novel ways of tackling the space charge problem have been discussed. The space charge effect is modeled through the introduction of a parameter f (0 < f < 1) in the thermos-electron emission equation. We find that the efficiency of the power conversion depends on solar insolation, height h, apart from radii R of the concentrator aperture and emitter, and the collector material properties. We have also considered solar thermos electronic power conversion by using single atom-layer graphene as an emitter.

Thermo-mechanical simulations of early-age concrete cracking with durability predictions

NASA Astrophysics Data System (ADS)

Havlásek, Petr; Šmilauer, Vít; Hájková, Karolina; Baquerizo, Luis

2017-09-01

Concrete performance is strongly affected by mix design, thermal boundary conditions, its evolving mechanical properties, and internal/external restraints with consequences to possible cracking with impaired durability. Thermo-mechanical simulations are able to capture those relevant phenomena and boundary conditions for predicting temperature, strains, stresses or cracking in reinforced concrete structures. In this paper, we propose a weakly coupled thermo-mechanical model for early age concrete with an affinity-based hydration model for thermal part, taking into account concrete mix design, cement type and thermal boundary conditions. The mechanical part uses B3/B4 model for concrete creep and shrinkage with isotropic damage model for cracking, able to predict a crack width. All models have been implemented in an open-source OOFEM software package. Validations of thermo-mechanical simulations will be presented on several massive concrete structures, showing excellent temperature predictions. Likewise, strain validation demonstrates good predictions on a restrained reinforced concrete wall and concrete beam. Durability predictions stem from induction time of reinforcement corrosion, caused by carbonation and/or chloride ingress influenced by crack width. Reinforcement corrosion in concrete struts of a bridge will serve for validation.

Tunable thermo-responsive hydrogels: synthesis, structural analysis and drug release studies.

PubMed

Cirillo, Giuseppe; Spataro, Tania; Curcio, Manuela; Spizzirri, U Gianfranco; Nicoletta, Fiore Pasquale; Picci, Nevio; Iemma, Francesca

2015-03-01

Thermo-responsive hydrogel films, synthesized by UV-initiated radical polymerization, are proposed as delivery devices for non-steroidal anti-inflammatory drugs (Diclofenac sodium and Naproxen). N-isopropylacrylamide and N,N'-ethylenebisacrylamide were chosen as thermo-sensitive monomer and crosslinker, respectively. Infrared spectroscopy was used to assess the incorporation of monomers into the network, and the network density of hydrogel films was found to strictly depend on both feed composition and film thickness. Calorimetric analyses showed negative thermo-responsive behaviour with shrinking/swelling transition values in the range 32.8-36.1°C. Equilibrium swelling studies around the LCST allowed the correlation between the structural changes and the temperature variations. The mesh size, indeed, rapidly changed from a collapsed to a swollen state, with beneficial effects in applications such as size-selective permeation or controlled drug delivery, while the crosslinking degree, the film thickness, and the loading method deeply influenced the drug release profiles at 25 and 40°C. The analysis of both 3D-network structure, release kinetics and diffusional constraints at different temperatures was evaluated by mathematical modelling. Copyright © 2014 Elsevier B.V. All rights reserved.

Preparation, thermo-optic property and simulation of optical switch based on azo benzothiazole polymer

NASA Astrophysics Data System (ADS)

Cao, Zhijuan; Qiu, Fengxian; Wang, Qing; Cao, Guorong; Guan, Yijun; Zhuang, Lin; Xu, Xiaolong; Wang, Jie; Chen, Qian; Yang, Dongya

2013-04-01

An azo chromophore molecule 4-[(benzothiazole-2-yl)diazenyl]phenyl-1,3-diamine (BTPD) was prepared with 2-amino benzothiazole and m-phenylenediamine by diazo-coupling reaction. Then, the chromophore molecule BTPD was polymerized with NJ-210 and isophorone diisocyanate (IPDI) to obtain novel azo benzothiazole polymer (BTPU). The structures of BTPD and BTPU were characterized using the Fourier transform infrared, UV-visible spectroscopy, DSC and TGA. The physical properties of the obtained BTPU were investigated. The refractive index ( n) of BTPU was demonstrated at different temperature and wavelength (532, 650 and 850 nm) using attenuated total reflection technique. The transmission loss and dispersion characteristic of BTPU film were investigated using the CCD digital imaging devices and Sellmeyer equation. A Y-branch and 2 × 2 Mach-Zehnder interferometer (MZI) polymeric thermo-optic switches based on the thermo-optic effect of prepared BTPU were proposed and the performance of switches was simulated. The results indicated that the power consumption of the Y-branch thermo-optic switch could be only 0.6 mW. The Y-branch and MZI switching rising and falling times obtained were 8.0 and 1.8 ms.

Effect of PbO on the spectral and thermo-optical properties of Nd3+-doped phosphate laser glass

NASA Astrophysics Data System (ADS)

Yin, Qianwen; Kang, Shuai; Wang, Xue; Li, Shunguang; He, Dongbing; Hu, Lili

2017-04-01

Nd3+-doped P2O5-K2O-Al2O3-BaO-PbO phosphate glasses with various PbO/BaO ratios were synthesized using the melt quenching technique. Raman, absorption, and emission spectra were measured to investigate the effects of PbO/BaO ratios on the structures and spectroscopic properties of the glasses. The emission cross-sections of the Nd3+-doped phosphate glasses were calculated using the Judd-Ofelt theory, and were found to increase from 4.37 × 10-20 to 4.50 × 10-20 cm2 as the PbO/BaO ratio increased. In addition, thermo-optical properties were measured using an interferometric technique. The thermo-optical coefficients, which were -1.49 × 10-6, -1.65 × 10-6, and -1.64 × 10-6 K-1, respectively, were all largely negative values. The thermal expansion coefficients of the three glass samples varied within a small range. The results showed that increasing the PbO/BaO ratio of phosphate glasses can improve the laser properties while maintaining their good thermo-optical properties.

Mining of Novel Thermo-Stable Cellulolytic Genes from a Thermophilic Cellulose-Degrading Consortium by Metagenomics

PubMed Central

Xia, Yu; Ju, Feng; Fang, Herbert H. P.; Zhang, Tong

2013-01-01

In this study, metagenomics was applied to characterize the microbial community and to discover carbohydrate-active genes of an enriched thermophilic cellulose-degrading sludge. The 16S analysis showed that the sludge microbiome was dominated by genus of cellulolytic Clostridium and methanogenesis Methanothermobacter. In order to retrieve genes from the metagenome, de novo assembly of the 11,930,760 Illumina 100 bp paired-end reads (totally 1.2 Gb) was carried out. 75% of all reads was utilized in the de novo assembly. 31,499 ORFs (Open Reading Frame) with an average length of 852 bp were predicted from the assembly; and 64% of these ORFs were predicted to present full-length genes. Based on the Hidden Markol Model, 253 of the predicted thermo-stable genes were identified as putatively carbohydrate-active. Among them the relative dominance of GH9 (Glycoside Hydrolase) and corresponding CBM3 (Carbohydrate Binding Module) revealed a cellulosome-based attached metabolism of polysaccharide in the thermophilic sludge. The putative carbohydrate-active genes ranged from 20% to 100% amino acid sequence identity to known proteins in NCBI nr database, with half of them showed less than 50% similarity. In addition, the coverage of the genes (in terms of ORFs) identified in the sludge were developed into three clear trends (112×, 29× and 8×) in which 85% of the high coverage trend (112×) mainly consisted of phylum of Firmicutes while 49.3% of the 29× trend was affiliated to the phylum of Chloroflexi. PMID:23341999

Numerical simulation of metallic wire arc additive manufacturing (WAAM)

NASA Astrophysics Data System (ADS)

Graf, M.; Pradjadhiana, K. P.; Hälsig, A.; Manurung, Y. H. P.; Awiszus, B.

2018-05-01

Additive-manufacturing technologies have been gaining tremendously in popularity for some years in the production of single-part series with complex, close-to-final-contour geometries and the processing of special or hybrid materials. In principle, the processes can be subdivided into wire-based and powder-based processes in accordance with the Association of German Engineers (VDI) Guideline 3405. A further subdivision is made with respect to the smelting technology. In all of the processes, the base material is applied in layers at the points where it is needed in accordance with the final contour. The process that was investigated was wire-based, multi-pass welding by means of gas-metal arc welding. This was accomplished in the present study by determining the material parameters (thermo-mechanical and thermo-physical characteristics) of the welding filler G3Si1 (material number: 1.5125) that were necessary for the numerical simulation and implementing them in a commercial FE program (MSC Marc Mentat). The focus of this paper was on simulation and validation with respect to geometry and microstructural development in the welding passes. The resulting minimal deviation between reality and simulation was a result of the measurement inertia of the thermocouples. In general, however, the FE model can be used to make a very good predetermination of the cooling behaviour, which affects the microstructural development and thus the mechanical properties of the joining zone, as well as the geometric design of the component (distortion, etc.).

Biofilm formation and interspecies interactions in mixed cultures of thermo-acidophilic archaea Acidianus spp. and Sulfolobus metallicus.

PubMed

Castro, Camila; Zhang, Ruiyong; Liu, Jing; Bellenberg, Sören; Neu, Thomas R; Donati, Edgardo; Sand, Wolfgang; Vera, Mario

2016-09-01

The understanding of biofilm formation by bioleaching microorganisms is of great importance for influencing mineral dissolution rates and to prevent acid mine drainage (AMD). Thermo-acidophilic archaea such as Acidianus, Sulfolobus and Metallosphaera are of special interest due to their ability to perform leaching at high temperatures, thereby enhancing leaching rates. In this work, leaching experiments and visualization by microscopy of cell attachment and biofilm formation patterns of the crenarchaeotes Sulfolobus metallicus DSM 6482(T) and the Acidianus isolates DSM 29038 and DSM 29099 in pure and mixed cultures on sulfur or pyrite were studied. Confocal laser scanning microscopy (CLSM) combined with fluorescent dyes as well as fluorescently labeled lectins were used to visualize different components (e.g. DNA, proteins or glycoconjugates) of the aforementioned species. The data indicate that cell attachment and the subsequently formed biofilms were species- and substrate-dependent. Pyrite leaching experiments coupled with pre-colonization and further inoculation with a second species suggest that both species may negatively influence each other during pyrite leaching with respect to initial attachment and pyrite dissolution rates. In addition, the investigation of binary biofilms on pyrite showed that both species were heterogeneously distributed on pyrite surfaces in the form of individual cells or microcolonies. Physical contact between the two species seems to occur, as revealed by specific lectins able to specifically bind single species within mixed cultures. Copyright © 2016 Institut Pasteur. Published by Elsevier Masson SAS. All rights reserved.

Analysis of the hologram recording on the novel chloride photo-thermo-refractive glass

NASA Astrophysics Data System (ADS)

Ivanov, S. A.; Nikonorov, N. V.; Dubrovin, V. D.; Krykova, V. A.

2017-05-01

In this research, we present new holographic material based on fluoride photo-thermo-refractive glass(PTR) - chloride PTR glass. One of the benefit of this type of PTR glass is positive refractive index change. During this work, for the first-time volume Bragg gratings were recorded in this kind of material. The first experiments revealed that such gratings are mixed i.e. possess both absorption and phase components. Complex analysis shows that both refractive index and absorption coefficient are modulated inside the grating structure. We found out that at first there is no strict dependence of the refractive index change from dosage, but as we continue the process of thermal treatment - dependence is appear. Exposure influence on the refractive index change for this glass differs from fluoride one and shows some sort of saturation after the exposure of 4-6 J/cm2 . We distinguished refractive index change and absorption coefficient change and observed both behavior with increasing thermal treatment time. We found out that the increase of thermal treatment time results in the significant refractive index change. At the same time the absorption does `not practically change. It was found that maximum modulation of refractive index is comparable with fluoride PTR glass and achieves value of 1600 ppm. The modulation of absorption is equal to induced absorption caused by silver nanoparticles and depends from reading wavelength. Our study shows that almost all absorption is modulated inside the grating.

Coupled Thermo-Hydro-Mechanical Numerical Framework for Simulating Unconventional Formations

NASA Astrophysics Data System (ADS)

Garipov, T. T.; White, J. A.; Lapene, A.; Tchelepi, H.

2016-12-01

Unconventional deposits are found in all world oil provinces. Modeling these systems is challenging, however, due to complex thermo-hydro-mechanical processes that govern their behavior. As a motivating example, we consider in situ thermal processing of oil shale deposits. When oil shale is heated to sufficient temperatures, kerogen can be converted to oil and gas products over a relatively short timespan. This phase change dramatically impact both the mechanical and hydrologic properties of the rock, leading to strongly coupled THMC interactions. Here, we present a numerical framework for simulating tightly-coupled chemistry, geomechanics, and multiphase flow within a reservoir simulator (the AD-GPRS General Purpose Research Simulator). We model changes in constitutive behavior of the rock using a thermoplasticity model that accounts for microstructural evolution. The multi-component, multiphase flow and transport processes of both mass and heat are modeled at the macroscopic (e.g., Darcy) scale. The phase compositions and properties are described by a cubic equation of state; Arrhenius-type chemical reactions are used to represent kerogen conversion. The system of partial differential equations is discretized using a combination of finite-volumes and finite-elements, respectively, for the flow and mechanics problems. Fully implicit and sequentially implicit method are used to solve resulting nonlinear problem. The proposed framework is verified against available analytical and numerical benchmark cases. We demonstrate the efficiency, performance, and capabilities of the proposed simulation framework by analyzing near well deformation in an oil shale formation.

Thermo-mechanical characterization of silicone foams

DOE Office of Scientific and Technical Information (OSTI.GOV)

Rangaswamy, Partha; Smith, Nickolaus A.; Cady, Carl M.

Cellular solids such as elastomeric foams are used in many structural applications to absorb and dissipate energy, due to their light weight (low density) and high energy absorption capability. In this paper we will discuss foams derived from S5370, a silicone foam formulation developed by Dow Corning. In the application presented, the foam is consolidated into a cushion component of constant thickness but variable density. A mechanical material model developed by Lewis (2013), predicts material response, in part, as a function of relative density. To determine the required parameters for this model we have obtained the mechanical response in compressionmore » for ambient, cold and hot temperatures. The variable density cushion provided samples sufficient samples so that the effect of sample initial density on the mechanical response could be studied. The mechanical response data showed extreme sensitivity to relative density. We also observed at strains corresponding to 1 MPa a linear relationship between strain and initial density for all temperatures. Samples taken from parts with a history of thermal cycling demonstrated a stiffening response that was a function of temperature, with the trend of more stiffness as temperature increased above ambient. This observation is in agreement with the entropic effects on the thermo-mechanical behavior of silicone polymers. In this study, we present the experimental methods necessary for the development of a material model, the testing protocol, analysis of test data, and a discussion of load (stress) and gap (strain) as a function of sample initial densities and temperatures« less

ThermoData Engine (TDE): software implementation of the dynamic data evaluation concept. 9. Extensible thermodynamic constraints for pure compounds and new model developments.

PubMed

Diky, Vladimir; Chirico, Robert D; Muzny, Chris D; Kazakov, Andrei F; Kroenlein, Kenneth; Magee, Joseph W; Abdulagatov, Ilmutdin; Frenkel, Michael

2013-12-23

ThermoData Engine (TDE) is the first full-scale software implementation of the dynamic data evaluation concept, as reported in this journal. The present article describes the background and implementation for new additions in latest release of TDE. Advances are in the areas of program architecture and quality improvement for automatic property evaluations, particularly for pure compounds. It is shown that selection of appropriate program architecture supports improvement of the quality of the on-demand property evaluations through application of a readily extensible collection of constraints. The basis and implementation for other enhancements to TDE are described briefly. Other enhancements include the following: (1) implementation of model-validity enforcement for specific equations that can provide unphysical results if unconstrained, (2) newly refined group-contribution parameters for estimation of enthalpies of formation for pure compounds containing carbon, hydrogen, and oxygen, (3) implementation of an enhanced group-contribution method (NIST-Modified UNIFAC) in TDE for improved estimation of phase-equilibrium properties for binary mixtures, (4) tools for mutual validation of ideal-gas properties derived through statistical calculations and those derived independently through combination of experimental thermodynamic results, (5) improvements in program reliability and function that stem directly from the recent redesign of the TRC-SOURCE Data Archival System for experimental property values, and (6) implementation of the Peng-Robinson equation of state for binary mixtures, which allows for critical evaluation of mixtures involving supercritical components. Planned future developments are summarized.

Characterization of a cold-active esterase from Serratia sp. and improvement of thermostability by directed evolution.

PubMed

Jiang, Huang; Zhang, Shaowei; Gao, Haofeng; Hu, Nan

2016-01-22

In recent years, cold-active esterases have received increased attention due to their attractive properties for some industrial applications such as high catalytic activity at low temperatures. An esterase-encoding gene (estS, 909 bp) from Serratia sp. was identified, cloned and expressed in Escherichia coli DE3 (BL21). The estS encoded a protein (EstS) of 302 amino acids with a predicted molecular weight of 32.5 kDa. It showed the highest activity at 10 °C and pH 8.5. EstS was cold active and retained ~92 % of its original activity at 0 °C. Thermal inactivation analysis showed that the T1/2 value of EstS was 50 min at 50 °C (residual activity 41.23 %) after 1 h incubation. EstS is also quite stable in high salt conditions and displayed better catalytic activity in the presence of 4 M NaCl. To improve the thermo-stability of EstS, variants of estS gene were created by error-prone PCR. A mutant 1-D5 (A43V, R116W, D147N) that showed higher thermo-stability than its wild type predecessor was selected. 1-D5 showed enhanced T1/2 of 70 min at 50 °C and retained 63.29 % of activity after incubation at 50 °C for 60 min, which were about 22 % higher than the wild type (WT). CD spectrum showed that the secondary structure of WT and 1-D5 are more or less similar, but an increase in β-sheets was recorded, which enhanced the thermostability of mutant protein. EstS was a novel cold-active and salt-tolerant esterase and half-life of mutant 1-D5 was enhanced by 1.4 times compared with WT. The features of EstS are interesting and can be exploited for commercial applications. The results have also provided useful information about the structure and function of Est protein.

Materials characterization study of conductive flexible second surface mirrors

NASA Technical Reports Server (NTRS)

Levadou, F.; Bosma, S. J.; Paillous, A.

1981-01-01

The status of prequalification and qualification work on conductive flexible second surface mirrors is described. The basic material is FEP Teflon witn either aluminium or silver vacuum deposited reflectors. The top layer has been made conductive by deposition of layer of a indium oxide. The results of a prequalification program comprised of decontamination, humidity, thermal cycling, thermal shock and vibration tests are presented. Thermo-optical and electrical properties. The results of a prequalification program comprised of decontamination, humidity, thermal cycling, thermal shock and vibration tests are presented. Thermo-optical and electrical properties, the electrostatic behavior of the materials under simulated substorm environment and electrical conductivity at low temperatures are characterized. The effects of simulated ultra violet and particles irradiation on electrical and thermo-optical properties of the materials are also presented.

Warm Forming of Aluminum Alloys using a Coupled Thermo-Mechanical Anisotropic Material Model

DOE Office of Scientific and Technical Information (OSTI.GOV)

Abedrabbo, Nader; Pourboghrat, Farhang; Carsley, John E.

Temperature-dependant anisotropic material models for two types of automotive aluminum alloys (5754-O and 5182-O) were developed and implemented in LS-Dyna as a user material subroutine (UMAT) for coupled thermo-mechanical finite element analysis (FEA) of warm forming of aluminum alloys. The anisotropy coefficients of the Barlat YLD2000 plane stress yield function for both materials were calculated for the range of temperatures 25 deg. C-260 deg. C. Curve fitting was used to calculate the anisotropy coefficients of YLD2000 and the flow stress as a function of temperature. This temperature-dependent material model was successfully applied to the coupled thermo-mechanical analysis of stretching ofmore » aluminum sheets and results were compared with experiments.« less

A Numerical Study of Coupled Non-Linear Equations of Thermo-Viscous Fluid Flow in Cylindrical Geometry

NASA Astrophysics Data System (ADS)

Pothanna, N.; Aparna, P.; Gorla, R. S. R.

2017-12-01

In this paper we present numerical solutions to coupled non-linear governing equations of thermo-viscous fluid flow in cylindrical geometry using MATHEMATICA software solver. The numerical results are presented in terms of velocity, temperature and pressure distribution for various values of the material parameters such as the thermo-mechanical stress coefficient, thermal conductivity coefficient, Reiner Rivlin cross viscosity coefficient and the Prandtl number in the form of tables and graphs. Also, the solutions to governing equations for slow steady motion of a fluid have been obtained numerically and compared with the existing analytical results and are found to be in excellent agreement. The results of the present study will hopefully enable a better understanding applications of the flow under consideration.

The development and production of thermo-mechanically forged tool steel spur gears

NASA Technical Reports Server (NTRS)

Bamberger, E. N.

1973-01-01

A development program to establish the feasibility and applicability of high energy rate forging procedures to tool steel spur gears was performed. Included in the study were relatively standard forging procedures as well as a thermo-mechanical process termed ausforming. The subject gear configuration utilized was essentially a standard spur gear having 28 teeth, a pitch diameter of 3.5 inches and a diametral pitch of 8. Initially it had been planned to use a high contact ratio gear design, however, a comprehensive evaluation indicated that severe forging problems would be encountered as a result of the extremely small teeth required by this type of design. The forging studies were successful in achieving gear blanks having integrally formed teeth using both standard and thermo-mechanical forging procedures.

Thermo-optical dynamics in an optically pumped Photonic Crystal nano-cavity.

PubMed

Brunstein, M; Braive, R; Hostein, R; Beveratos, A; Rober-Philip, I; Sagnes, I; Karle, T J; Yacomotti, A M; Levenson, J A; Moreau, V; Tessier, G; De Wilde, Y

2009-09-14

Linear and non-linear thermo-optical dynamical regimes were investigated in a photonic crystal cavity. First, we have measured the thermal relaxation time in an InP-based nano-cavity with quantum dots in the presence of optical pumping. The experimental method presented here allows one to obtain the dynamics of temperature in a nanocavity based on reflectivity measurements of a cw probe beam coupled through an adiabatically tapered fiber. Characteristic times of 1.0+/-0.2 micros and 0.9+/-0.2 micros for the heating and the cooling processes were obtained. Finally, thermal dynamics were also investigated in a thermo-optical bistable regime. Switch-on/off times of 2 micros and 4 micros respectively were measured, which could be explained in terms of a simple non-linear dynamical representation.

Numerical simulation of machining distortions on a forged aerospace component following a one and a multi-step approaches

NASA Astrophysics Data System (ADS)

Prete, Antonio Del; Franchi, Rodolfo; Antermite, Fabrizio; Donatiello, Iolanda

2018-05-01

Residual stresses appear in a component as a consequence of thermo-mechanical processes (e.g. ring rolling process) casting and heat treatments. When machining these kinds of components, distortions arise due to the redistribution of residual stresses due to the foregoing process history inside the material. If distortions are excessive, they can lead to a large number of scrap parts. Since dimensional accuracy can affect directly the engines efficiency, the dimensional control for aerospace components is a non-trivial issue. In this paper, the problem related to the distortions of large thin walled aeroengines components in nickel superalloys has been addressed. In order to estimate distortions on inner diameters after internal turning operations, a 3D Finite Element Method (FEM) analysis has been developed on a real industrial test case. All the process history, has been taken into account by developing FEM models of ring rolling process and heat treatments. Three different strategies of ring rolling process have been studied and the combination of related parameters which allows to obtain the best dimensional accuracy has been found. Furthermore, grain size evolution and recrystallization phenomena during manufacturing process has been numerically investigated using a semi empirical Johnson-Mehl-Avrami-Kohnogorov (JMAK) model. The volume subtractions have been simulated by boolean trimming: a one step and a multi step analysis have been performed. The multi-step procedure has allowed to choose the best material removal sequence in order to reduce machining distortions.