Influence of corneal thickness on the intraocular pressure readings for Maklakoff's tonometer of different weight

NASA Astrophysics Data System (ADS)

Franus, D. V.

2018-05-01

Research is conducted into variation in the stress-strain state of the corneoscleral shell of the human eye under loading by a flat base stamp of varying weight. A three-dimensional finite-element model of the contact problem of loading of the corneoscleral shell in the ANSYS program package is presented. Cornea and sclera are modeled as conjugated transversely isotropic spherical shells. The cornea is modeled as a multilayer shell with variable thickness in which all modeled layers have their own individual elastic properties. The research deals with the numerical calculation of the diameter of the contact zone between the shell and the stamp. Values of correction coefficients for intraocular pressure are obtained depending on the thickness of the corneal shell in its center, allowing the true intraocular pressure to be determined more accurately.

Exciton in a spherical core/shell nanostructure: Influence of surface ligand

NASA Astrophysics Data System (ADS)

Anitha, B.; Nithiananthi, P.

2018-04-01

Studies on exciton in an inverted type I spherical GaAs/Al0.3Ga0.7As core/shell nanostructure (CSN) are made using variational method. Dielectric constant and effective mass mismatches of the core and shell materials are considered. The effect of core and the shell dimensions on the exciton binding energy (BE) are analyzed for different shell (Rs) and core radii (Rc). It is observed that with the core and the shell inducement, significant change in BE can be achieved. In addition, the influence of ligand enclosureon the BE as a function of shell thickness (ST) is reviewed. The result exhibits that the presence of ligand considerably affects the BE. Further the transmission probability of exciton for various Rc and Rs are reported. The notable changes are compared and examined with and without ligand inclusion.

Reconstruction of spherically symmetric objects from slit-imaged emission: limitations due to finite slit width

DOE Office of Scientific and Technical Information (OSTI.GOV)

Mueller, M.M.

1979-11-01

A simple method for reconstructing spherically symmetric objects from slit-imaged emission was recently described by Vest and Steel. Although this method is valid for infinitesimal slit widths and practically noise-free irradiance data, it is shown here that its validity does not extend to slits of practical width in the laser-fusion program. However, a method is given for reducing the Vest--Steel plots with practical apertures to obtain information on core diameter, shell diameter, and shell thickness.

Moment equations for chromatography using superficially porous spherical particles.

PubMed

Miyabe, Kanji

2011-01-01

New moment equations were developed for chromatography using superficially porous (shell-type) spherical particles, which have recently attracted much attention as one of separation media for fast separation with high efficiency. At first, the moment equations of the first absolute and second central moments in the real time domain were derived from the analytical solution in the Laplace domain of a set of basic equations of the general rate model of chromatography, which represent the mass balance, mass-transfer rate, and reaction kinetics in the column packed with shell-type particles. Then, the moment equations were used for analyzing the experimental data of chromatography of kallidin in a Halo column, which were published in a previous paper written by other researchers. It was tried to predict the chromatographic behavior of shell-type particles having different shell thicknesses. The new moment equations are useful for a detailed analysis of the chromatographic behavior of shell-type spherical particles. It is also concluded that they can be used for the preliminarily optimization of their structural characteristics.

Polar-direct-drive experiments with contoured-shell targets on OMEGA

DOE Office of Scientific and Technical Information (OSTI.GOV)

Marshall, F. J.; Radha, P. B.; Bonino, M. J.

Polar-driven direct-drive experiments recently performed on the OMEGA Laser System have demonstrated the efficacy of using a target with a contoured shell with varying thickness to improve the symmetry and fusion performance of the implosion. The polar-driven contoured-shell implosions have substantially reduced low mode perturbations compared to polar-driven spherical-shell implosions as diagnosed by x-ray radiographs up to shell stagnation. As a result, fusion yields were increased by more than a factor of ~2 without increasing the energy of the laser by the use of contoured shells.

Polar-direct-drive experiments with contoured-shell targets on OMEGA

DOE Office of Scientific and Technical Information (OSTI.GOV)

Marshall, F. J.; Radha, P. B.; Bonino, M. J.

Polar-driven direct-drive experiments recently performed on the OMEGA Laser System have demonstrated the efficacy of using a target with a contoured shell with varying thickness to improve the symmetry and fusion performance of the implosion. The polar-driven contoured-shell implosions have substantially reduced low mode perturbations compared to polar-driven spherical-shell implosions as diagnosed by x-ray radiographs up to shell stagnation. Fusion yields were increased by more than a factor of ∼2 without increasing the energy of the laser by the use of contoured shells.

Polar-direct-drive experiments with contoured-shell targets on OMEGA

DOE PAGES

Marshall, F. J.; Radha, P. B.; Bonino, M. J.; ...

2016-01-28

Polar-driven direct-drive experiments recently performed on the OMEGA Laser System have demonstrated the efficacy of using a target with a contoured shell with varying thickness to improve the symmetry and fusion performance of the implosion. The polar-driven contoured-shell implosions have substantially reduced low mode perturbations compared to polar-driven spherical-shell implosions as diagnosed by x-ray radiographs up to shell stagnation. As a result, fusion yields were increased by more than a factor of ~2 without increasing the energy of the laser by the use of contoured shells.

Tunable dielectric properties of mesoporous carbon hollow microspheres via textural properties.

PubMed

Xu, Hailong; Yin, Xiaowei; Li, Zhaochen; Liu, Chenglong; Wang, Zeyu; Li, Minghang; Zhang, Litong; Cheng, Laifei

2018-05-04

In this study, mesoporous carbon hollow microspheres (PCHMs) with tunable textural properties have been prepared through a facile hard template etching method. The PCHMs were characterized by scanning electron microscopy, transmission electron microscopy, x-ray diffraction, Raman spectra, and nitrogen adsorption and desorption systems. Uniform PCHMs with shell thickness ranging from 23 nm to 55 nm are realized. PCHMs with different textural properties can regulate dielectric and electromagnetic (EM) wave absorption effectively. The composite of paraffin wax mixed with 10 wt% PCHMs (the shell thickness of PCHMs is 35 nm) exhibits a minimum coefficient value of -53.8 dB at 8.8 GHz, with a thickness of 3.4 mm. Besides, it is remarkable that the effective absorption bandwidth covers all the X band with as low as a 10 wt% filler ratio, compared with other spherical EM wave absorbers. The excellent EM wave absorption capability of PCHMs can be ascribed to the better impendence matching and strong EM wave attenuation constant based on tunable textural properties. Our results provide a facile strategy to tune dielectric properties of spherical carbon absorbers based on textural properties, and can be extended to other spherical absorbers.

Tunable dielectric properties of mesoporous carbon hollow microspheres via textural properties

NASA Astrophysics Data System (ADS)

Xu, Hailong; Yin, Xiaowei; Li, Zhaochen; Liu, Chenglong; Wang, Zeyu; Li, Minghang; Zhang, Litong; Cheng, Laifei

2018-05-01

In this study, mesoporous carbon hollow microspheres (PCHMs) with tunable textural properties have been prepared through a facile hard template etching method. The PCHMs were characterized by scanning electron microscopy, transmission electron microscopy, x-ray diffraction, Raman spectra, and nitrogen adsorption and desorption systems. Uniform PCHMs with shell thickness ranging from 23 nm to 55 nm are realized. PCHMs with different textural properties can regulate dielectric and electromagnetic (EM) wave absorption effectively. The composite of paraffin wax mixed with 10 wt% PCHMs (the shell thickness of PCHMs is 35 nm) exhibits a minimum coefficient value of -53.8 dB at 8.8 GHz, with a thickness of 3.4 mm. Besides, it is remarkable that the effective absorption bandwidth covers all the X band with as low as a 10 wt% filler ratio, compared with other spherical EM wave absorbers. The excellent EM wave absorption capability of PCHMs can be ascribed to the better impendence matching and strong EM wave attenuation constant based on tunable textural properties. Our results provide a facile strategy to tune dielectric properties of spherical carbon absorbers based on textural properties, and can be extended to other spherical absorbers.

Direct solution for thermal stresses in a nose cap under an arbitrary axisymmetric temperature distribution

NASA Technical Reports Server (NTRS)

Davis, Randall C.

1988-01-01

The design of a nose cap for a hypersonic vehicle is an iterative process requiring a rapid, easy to use and accurate stress analysis. The objective of this paper is to develop such a stress analysis technique from a direct solution of the thermal stress equations for a spherical shell. The nose cap structure is treated as a thin spherical shell with an axisymmetric temperature distribution. The governing differential equations are solved by expressing the stress solution to the thermoelastic equations in terms of a series of derivatives of the Legendre polynomials. The process of finding the coefficients for the series solution in terms of the temperature distribution is generalized by expressing the temperature along the shell and through the thickness as a polynomial in the spherical angle coordinate. Under this generalization the orthogonality property of the Legendre polynomials leads to a sequence of integrals involving powers of the spherical shell coordinate times the derivative of the Legendre polynomials. The coefficients of the temperature polynomial appear outside of these integrals. Thus, the integrals are evaluated only once and their values tabulated for use with any arbitrary polynomial temperature distribution.

Final report SI 08-SI-004: Fusion application targets

DOE Office of Scientific and Technical Information (OSTI.GOV)

Biener, J; Kucheyev, S O; Wang, M Y

2010-12-03

Complex target structures are necessary to take full advantage of the unique laboratory environment created by inertial confinement fusion experiments. For example, uses-of-ignition targets that contain a thin layer of a low density nanoporous material inside a spherical ablator shell allow placing dopants in direct contact with the DT fuel. The ideal foam for this application is a low-density hydrocarbon foam that is strong enough to survive wetting with cryogenic hydrogen, and low enough in density (density less than {approx}30 mg/cc) to not reduce the yield of the target. Here, we discuss the fabrication foam-lined uses-of-ignition targets, and the developmentmore » of low-density foams that can be used for this application. Much effort has been directed over the last 20 years toward the development of spherical foam targets for direct-drive and fast-ignition experiments. In these targets, the spherical foam shell is used to define the shape of the cryogenic DT fuel layer, or acts as a surrogate to simulate the cryogenic fuel layer. These targets are fabricated from relatively high-density aerogels (>100 mg/cc) and coated with a few micron thick permeation barrier. With exception of the above mentioned fast ignition targets, the wall of these targets is typically larger than 100 microns. In contrast, the fusion application targets for indirect-drive experiments on NIF will require a much thinner foam shell surrounded by a much thicker ablator shell. The design requirements for both types of targets are compared in Table 1. The foam shell targets for direct-drive experiments can be made in large quantities and with reasonably high yields using an encapsulation technique pioneered by Takagi et al. in the early 90's. In this approach, targets are made by first generating unsupported foam shells using a triple-orifice droplet generator, followed by coating the dried foam shells with a thin permeation barrier. However, this approach is difficult, if not impossible, to transfer to the lower density and thinner wall foam shells required for indirect-drive uses-of-ignition targets for NIF that then would have to be coated with an at least hundred-micron-thick ablator film. So far, the thinnest shells that have been fabricated using the triple-orifice-droplet generator technique had a wall thickness of {approx}20 microns, but despite of being made from a higher-density foam formulation, the shells were mechanically very sensitive, difficult to dry, and showed large deviations from roundness. We thus decided to explore a different approach based on using prefabricated thick-walled spherical ablator shells as templates for the thin-walled foam shell. As in the case of the above mentioned encapsulation technique, the foam is made by sol-gel chemistry. However, our approach removes much the requirements on the mechanical stability of the foam shell as the foam shell is never handled in its free-standing form, and promises superior ablator uniformity and surface roughness. As discussed below, the success of this approach depends strongly on the availability of suitable aerogel chemistries (ideally pure hydrocarbon (CH)-based systems) with suitable rheological properties (high viscosity and high modulus near the gel point) that produce low-density and mechanically strong foams.« less

AFM Investigation of Liquid-Filled Polymer Microcapsules Elasticity.

PubMed

Sarrazin, Baptiste; Tsapis, Nicolas; Mousnier, Ludivine; Taulier, Nicolas; Urbach, Wladimir; Guenoun, Patrick

2016-05-10

Elasticity of polymer microcapsules (MCs) filled with a liquid fluorinated core is studied by atomic force microscopy (AFM). Accurately characterized spherical tips are employed to obtain the Young's moduli of MCs having four different shell thicknesses. We show that those moduli are effective ones because the samples are composites. The strong decrease of the effective MC elasticity (from 3.0 to 0.1 GPa) as the shell thickness decreases (from 200 to 10 nm) is analyzed using a novel numerical approach. This model describes the evolution of the elasticity of a coated half-space according to the contact radius, the thickness of the film, and the elastic moduli of bulk materials. This numerical model is consistent with the experimental data and allows simulating the elastic behavior of MCs at high frequencies (5 MHz). While the quasi-static elasticity of the MCs is found to be very dependent on the shell thickness, the high frequency (5 MHz) elastic behavior of the core leads to a stable behavior of the MCs (from 2.5 to 3 GPa according to the shell thickness). Finally, the effect of thermal annealing on the MCs elasticity is investigated. The Young's modulus is found to decrease because of the reduction of the shell thickness due to the loss of the polymer.

Curvature-driven morphing of non-Euclidean shells

NASA Astrophysics Data System (ADS)

Pezzulla, Matteo; Stoop, Norbert; Jiang, Xin; Holmes, D. P.

2017-05-01

We investigate how thin structures change their shape in response to non-mechanical stimuli that can be interpreted as variations in the structure's natural curvature. Starting from the theory of non-Euclidean plates and shells, we derive an effective model that reduces a three-dimensional stimulus to the natural fundamental forms of the mid-surface of the structure, incorporating expansion, or growth, in the thickness. Then, we apply the model to a variety of thin bodies, from flat plates to spherical shells, obtaining excellent agreement between theory and numerics. We show how cylinders and cones can either bend more or unroll, and eventually snap and rotate. We also study the nearly isometric deformations of a spherical shell and describe how this shape change is ruled by the geometry of a spindle. As the derived results stem from a purely geometrical model, they are general and scalable.

Primary and secondary particle contributions to the depth dose distribution in a phantom shielded from solar flare and Van Allen protons

NASA Technical Reports Server (NTRS)

Santoro, R. T.; Claiborne, H. C.; Alsmiller, R. G., Jr.

1972-01-01

Calculations have been made using the nucleon-meson transport code NMTC to estimate the absorbed dose and dose equivalent distributions in astronauts inside space vehicles bombarded by solar flare and Van Allen protons. A spherical shell shield of specific radius and thickness with a 30-cm-diam. tissue ball at the geometric center was used to simulate the spacecraft-astronaut configuration. The absorbed dose and the dose equivalent from primary protons, secondary protons, heavy nuclei, charged pions, muons, photons, and positrons and electrons are given as a function of depth in the tissue phantom. Results are given for solar flare protons with a characteristic rigidity of 100 MV and for Van Allen protons in a 240-nautical-mile circular orbit at 30 degree inclination angle incident on both 20-g/sq cm-thick aluminum and polyethylene spherical shell shields.

Novel Architecture for a Long-Life, Lightweight Venus Lander

DOE Office of Scientific and Technical Information (OSTI.GOV)

Bugby, D.; Seghi, S.; Kroliczek, E.

2009-03-16

This paper describes a novel concept for an extended lifetime, lightweight Venus lander. Historically, to operate in the 480 deg. C, 90 atm, corrosive, mostly CO{sub 2} Venus surface environment, previous landers have relied on thick Ti spherical outer shells and thick layers of internal insulation. But even the most resilient of these landers operated for only about 2 hours before succumbing to the environment. The goal on this project is to develop an architecture that extends lander lifetime to 20-25 hours and also reduces mass compared to the Pioneer Venus mission architecture. The idea for reducing mass is to:more » (a) contain the science instruments within a spherical high strength lightweight polymer matrix composite (PMC) tank; (b) surround the PMC tank with an annular shell of high performance insulation pre-pressurized to a level that (after landing) will exceed the external Venus surface pressure; and (c) surround the insulation with a thin Ti outer shell that contains only a net internal pressure, eliminating buckling overdesign mass. The combination of the PMC inner tank and thin Ti outer shell is lighter than a single thick Ti outer shell. The idea for extending lifetime is to add the following three features: (i) an expendable water supply that is placed within the insulation or is contained in an additional vessel within the PMC tank; (ii) a thin spherical evaporator shell placed within the insulation a short radial distance from the outer shell; and (iii) a thin heat-intercepting liquid cooled shield placed inboard of the evaporator shell. These features lower the temperature of the insulation below what it would have been with the insulation alone, reducing the internal heat leak and lengthening lifetime. The use of phase change materials (PCMs) inside the PMC tank is also analyzed as a lifetime-extending design option. The paper describes: (1) analytical modeling to demonstrate reduced mass and extended life; (2) thermal conductivity testing of high performance insulation as a function of temperature and pressure; (3) a bench-top ambient pressure thermal test of the evaporation system; and (4) a higher fidelity test, to be conducted in a high pressure, high temperature inert gas test chamber, of a small-scale Venus lander prototype (made from two hemispherical interconnecting halves) that includes all of the aforesaid features.22 CFR 125.4(b)(13) applicable.« less

Acoustic radiation force acting on elastic and viscoelastic spherical shells placed in a plane standing wave field.

PubMed

Mitri, F G

2005-08-01

The theory of the acoustic radiation force acting on elastic spherical shells suspended in a plane standing wave field is developed in relation to their thickness and the content of their hollow regions. The theory is modified to include the effect of a hysteresis type of absorption of compressional and shear waves in the material. The fluid-loading effect on the acoustic radiation force function Y(st) is analyzed as well. Results of numerical calculations are presented for a number of elastic and viscoelastic materials, with the hollow region filled with water or air. These results show how the damping due to absorption, the change of the interior fluid inside the shells' hollow regions, and the exterior fluid surrounding their structures, affect the acoustic radiation force.

Optical absorption of carbon-gold core-shell nanoparticles

NASA Astrophysics Data System (ADS)

Wang, Zhaolong; Quan, Xiaojun; Zhang, Zhuomin; Cheng, Ping

2018-01-01

In order to enhance the solar thermal energy conversion efficiency, we propose to use carbon-gold core-shell nanoparticles dispersed in liquid water. This work demonstrates theoretically that an absorbing carbon (C) core enclosed in a plasmonic gold (Au) nanoshell can enhance the absorption peak while broadening the absorption band; giving rise to a much higher solar absorption than most previously studied core-shell combinations. The exact Mie solution is used to evaluate the absorption efficiency factor of spherical nanoparticles in the wavelength region from 300 nm to 1100 nm as well as the electric field and power dissipation profiles inside the nanoparticles at specified wavelengths (mostly at the localized surface plasmon resonance wavelength). The field enhancement by the localized plasmons at the gold surfaces boosts the absorption of the carbon particle, resulting in a redshift of the absorption peak with increased peak height and bandwidth. In addition to spherical nanoparticles, we use the finite-difference time-domain method to calculate the absorption of cubic core-shell nanoparticles. Even stronger enhancement can be achieved with cubic C-Au core-shell structures due to the localized plasmonic resonances at the sharp edges of the Au shell. The solar absorption efficiency factor can exceed 1.5 in the spherical case and reach 2.3 in the cubic case with a shell thickness of 10 nm. Such broadband absorption enhancement is in great demand for solar thermal applications including steam generation.

Core–shell Ag@SiO{sub 2} nanoparticles of different silica shell thicknesses: Preparation and their effects on photoluminescence of lanthanide complexes

DOE Office of Scientific and Technical Information (OSTI.GOV)

Kang, Jie; Li, Yuan; Chen, Yingnan

Highlights: • Ag@SiO{sub 2} nanoparticles of different silica shell thicknesses were prepared via the Stöber process. • Sm and Dy complexes with benzoate, 1,10-phenanthroline and 2,2′-bipyridine were synthesized. • The complex-doped Ag@SiO{sub 2} composites show stronger luminescent intensities than pure complexes. • The luminescent intensities of the composites strongly depend on the SiO{sub 2} shell thickness. - Abstract: Three kinds of almost spherical core–shell Ag@SiO{sub 2} nanoparticles of different silica shell thicknesses (10, 25 and 80 nm) were prepared via the Stöber process. The Ag core nanoparticles were prepared by reducing silver nitrate with sodium citrate. The size, morphology andmore » structure of core–shell Ag@SiO{sub 2} nanoparticles were characterized by transmission electron microscopy. Subsequently, eight kinds of lanthanide complexes with benzoate, 1,10-phenanthroline and 2,2′-bipyridine were synthesized. The composition of the lanthanide complexes was characterized by elemental analysis, IR and UV spectra. Finally, lanthanide complexes were attached to the surface of Ag@SiO{sub 2} nanoparticles to form lanthanide-complex-doped Ag@SiO{sub 2} nanocomposites. The results show that the complex-doped Ag@SiO{sub 2} nanocomposites display much stronger luminescence intensities than the lanthanide complexes. Furthermore, the luminescence intensities of the lanthanide-complex-doped Ag@SiO{sub 2} nanocomposites with SiO{sub 2} shell thickness of 25 nm are stronger than those of the nanocomposites with SiO{sub 2} shell thickness of 10 and 80 nm.« less

Stability analysis of ultrasound thick-shell contrast agents

PubMed Central

Lu, Xiaozhen; Chahine, Georges L.; Hsiao, Chao-Tsung

2012-01-01

The stability of thick shell encapsulated bubbles is studied analytically. 3-D small perturbations are introduced to the spherical oscillations of a contrast agent bubble in response to a sinusoidal acoustic field with different amplitudes of excitation. The equations of the perturbation amplitudes are derived using asymptotic expansions and linear stability analysis is then applied to the resulting differential equations. The stability of the encapsulated microbubbles to nonspherical small perturbations is examined by solving an eigenvalue problem. The approach then identifies the fastest growing perturbations which could lead to the breakup of the encapsulated microbubble or contrast agent. PMID:22280568

Optimization and design of pigments for heat-insulating coatings

NASA Astrophysics Data System (ADS)

Wang, Guang-Hai; Zhang, Yue

2010-12-01

This paper reports that heat insulating property of infrared reflective coatings is obtained through the use of pigments which diffuse near-infrared thermal radiation. Suitable structure and size distribution of pigments would attain maximum diffuse infrared radiation and reduce the pigment volume concentration required. The optimum structure and size range of pigments for reflective infrared coatings are studied by using Kubelka—Munk theory, Mie model and independent scattering approximation. Taking titania particle as the pigment embedded in an inorganic coating, the computational results show that core-shell particles present excellent scattering ability, more so than solid and hollow spherical particles. The optimum radius range of core-shell particles is around 0.3 ~ 1.6 μm. Furthermore, the influence of shell thickness on optical parameters of the coating is also obvious and the optimal thickness of shell is 100-300 nm.

Spherical shells buckling to the sound of music

NASA Astrophysics Data System (ADS)

Lee, Anna; Marthelot, Joel; Reis, Pedro

We study how the critical buckling load of spherical elastic shells can be modified by a fluctuating external pressure field. In our experiments, we employ thin elastomeric shells of nearly uniform thickness fabricated by the coating of a hemispherical mold with a polymer solution, which upon curing yields elastic structures. A shell is submerged in a water bath and loaded quasi-statically until buckling occurs by reducing its inner volume with a syringe pump. Simultaneously, a plunger connected to an electromagnetic shaker is placed above the shell and driven sinusoidally to create a fluctuating external pressure field that can excite dynamic vibration modes of the shell. These dynamic modes induce effective compressive stresses, in addition to those from the inner pressure loading, which can modify the critical conditions for the onset of buckling. We systematically quantify how the frequency and amplitude of the external driving affects the buckling strength of our shells. In specific regions of the parameter space, we find that pressure fluctuations can result in large reductions of the critical buckling pressure. This is analogous to the classic knock-down effect in shells due to intrinsic geometric imperfections, albeit now in a way that can be controlled externally.

Core-Shell Magnetic Morphology of Structurally Uniform Magnetite Nanoparticles

NASA Astrophysics Data System (ADS)

Krycka, K. L.; Booth, R. A.; Hogg, C. R.; Ijiri, Y.; Borchers, J. A.; Chen, W. C.; Watson, S. M.; Laver, M.; Gentile, T. R.; Dedon, L. R.; Harris, S.; Rhyne, J. J.; Majetich, S. A.

2010-05-01

A new development in small-angle neutron scattering with polarization analysis allows us to directly extract the average spatial distributions of magnetic moments and their correlations with three-dimensional directional sensitivity in any magnetic field. Applied to a collection of spherical magnetite nanoparticles 9.0 nm in diameter, this enhanced method reveals uniformly canted, magnetically active shells in a nominally saturating field of 1.2 T. The shell thickness depends on temperature, and it disappears altogether when the external field is removed, confirming that these canted nanoparticle shells are magnetic, rather than structural, in origin.

Spherical and tubule nanocarriers for sustained drug release

PubMed Central

Shutava, T.; Fakhrullin, R.; Lvov, Y.

2014-01-01

We discuss new trends in Layer-by-Layer (LbL) encapsulation of spherical and tubular cores of 50–150 nm diameter and loaded with drugs. This core size decrease (from few micrometers to a hundred of nanometers) for LbL encapsulation required development of sonication assistant non-washing technique and shell PEGylation to reach high colloidal stability of drug nanocarriers at 2–3 mg/mL concentration in isotonic buffers and serum. For 120–170 nm spherical LbL nanocapsules of low soluble anticancer drugs, polyelectrolyte shell thickness controls drug dissolution. As for nanotube carriers, we concentrated on natural halloysite clay nanotubes as cores for LbL encapsulation that allows high drug loading and sustains its release over tens and hundreds hours. Further drug release prolongation was reached with formation of the tube-end stoppers. PMID:25450068

Sample-morphology effects on x-ray photoelectron peak intensities. III. Simulated spectra of model core–shell nanoparticles

DOE Office of Scientific and Technical Information (OSTI.GOV)

Powell, Cedric J., E-mail: cedric.powell@nist.gov; Chudzicki, Maksymilian; Werner, Wolfgang S. M.

2015-09-15

The National Institute of Standards and Technology database for the simulation of electron spectra for surface analysis has been used to simulate Cu 2p photoelectron spectra for four types of spherical copper–gold nanoparticles (NPs). These simulations were made to extend the work of Tougaard [J. Vac. Sci. Technol. A 14, 1415 (1996)] and of Powell et al. [J. Vac. Sci. Technol. A 31, 021402 (2013)] who performed similar simulations for four types of planar copper–gold films. The Cu 2p spectra for the NPs were compared and contrasted with analogous results for the planar films and the effects of elastic scatteringmore » were investigated. The new simulations were made for a monolayer of three types of Cu/Au core–shell NPs on a Si substrate: (1) an Au shell of variable thickness on a Cu core with diameters of 0.5, 1.0, 2.0, 5.0, and 10.0 nm; (2) a Cu shell of variable thickness on an Au core with diameters of 0.5, 1.0, 2.0, 5.0, and 10.0 nm; and (3) an Au shell of variable thickness on a 1 nm Cu shell on an Au core with diameters of 0.5, 1.0, 2.0, 5.0, and 10.0 nm. For these three morphologies, the outer-shell thickness was varied until the Cu 2p{sub 3/2} peak intensity was the same (within 2%) as that found in our previous work with planar Cu/Au morphologies. The authors also performed similar simulations for a monolayer of spherical NPs consisting of a CuAu{sub x} alloy (also on a Si substrate) with diameters of 0.5, 1.0, 2.0, 5.0, and 10.0 nm. In the latter simulations, the relative Au concentration (x) was varied to give the same Cu 2p{sub 3/2} peak intensity (within 2%) as that found previously. For each morphology, the authors performed simulations with elastic scattering switched on and off. The authors found that elastic-scattering effects were generally strong for the Cu-core/Au-shell and weak for the Au-core/Cu-shell NPs; intermediate elastic-scattering effects were found for the Au-core/Cu-shell/Au-shell NPs. The shell thicknesses required to give the selected Cu 2p{sub 3/2} peak intensity for the three types of core–shell NPs were less than the corresponding film thicknesses of planar samples since Cu 2p photoelectrons can be detected from the sides and, for the smaller NPs, bottoms of the NPs. Elastic-scattering effects were also observed on the Au atomic fractions found for the CuAu{sub x} NP alloys with different diameters.« less

Placental Volumetry by 2-D Sonography with a New Mathematical Formula: Prospective Study on the Shell of a Spherical Sector Model.

PubMed

Kozinszky, Zoltan; Surányi, Andrea; Péics, Hajnalka; Molnár, András; Pál, Attila

2015-08-01

The aim of this study was to determine the utility of a new mathematical model in volumetric assessment of the placenta using 2-D ultrasound. Placental volumetry was performed in a prospective cross-sectional survey by virtual organ computer-aided analysis (VOCAL) with the help of a shell-off method in 346 uncomplicated pregnancies according to STROBE (Strengthening the Reporting of Observational Studies in Epidemiology) guidelines. Furthermore, placental thickness, length and height were measured with the 2-D technique to estimate placental volume based on the mathematical formula for the volume of "the shell of the spherical sector." Fetal size was also assessed by 2-D sonography. The placental volumes measured by 2-D and 3-D techniques had a correlation of 0.86. In the first trimester, the correlation was 0.82, and later during pregnancy, it was 0.86. Placental volumetry using "the circle-shaped shell of the spherical sector" mathematical model with 2-D ultrasound technique may be introduced into everyday practice to screen for placental volume deviations associated with adverse pregnancy outcome. Copyright © 2015 World Federation for Ultrasound in Medicine & Biology. Published by Elsevier Inc. All rights reserved.

Monostatic lidar/radar invisibility using coated spheres.

PubMed

Zhai, Peng-Wang; You, Yu; Kattawar, George W; Yang, Ping

2008-02-04

The Lorenz-Mie theory is revisited to explicitly include materials whose permeability is different from unity. The expansion coefficients of the scattered field are given for light scattering by both homogeneous and coated spheres. It is shown that the backscatter is exactly zero if the impedance of the spherical particles is equal to the intrinsic impedance of the surrounding medium. If spherical particles are sufficiently large, the zero backscatter can be explained as impedance matching using the asymptotic expression for the radar backscattering cross section. In the case of a coated sphere, the shell can be regarded as a cloak if the product of the thickness and the imaginary part of the refractive index of the outer shell is large.

Bell-Plesset effects in Rayleigh-Taylor instability of finite-thickness spherical and cylindrical shells

NASA Astrophysics Data System (ADS)

Velikovich, A. L.; Schmit, P. F.

2015-11-01

Bell-Plesset effects accounting for the time dependence of the radius, velocity and acceleration of the Rayleigh-Taylor-unstable surface are ubiquitous in the instability of spherical laser targets and magnetically driven cylindrical liners. We present an analytical model that, for an ideal incompressible fluid and small perturbation amplitudes, exactly accounts for the Bell-Plesset effects in finite-thickness targets and liners through acceleration and deceleration phases. We derive the time-dependent dispersion equations determining the ``instantaneous growth rate'' and demonstrate that by integrating this growth rate over time (the WKB approximation) we accurately evaluate the number of perturbation e-foldings during the acceleration phase. In the limit of the small target/liner thickness, we obtain the exact thin-shell perturbation equations and approximate thin-shell dispersion relations, generalizing the earlier results of Harris (1962), Ott (1972) and Bud'ko et al. (1989). This research was supported by the US DOE/NNSA (A.L.V.), and in part by appointment to the Sandia National Laboratories Truman Fellowship in National Security Science and Engineering (P.F.S.), which is part of the Laboratory Directed Research and Development (LDRD) Program, Project No. 165746, and sponsored by Sandia Corporation (a wholly owned subsidiary of Lockheed Martin Corporation) as Operator of Sandia National Laboratories under its U.S. Department of Energy Contract No. DE-AC04-94AL85000.

Stability analysis of ultrasound thick-shell contrast agents.

PubMed

Lu, Xiaozhen; Chahine, Georges L; Hsiao, Chao-Tsung

2012-01-01

The stability of thick shell encapsulated bubbles is studied analytically. 3-D small perturbations are introduced to the spherical oscillations of a contrast agent bubble in response to a sinusoidal acoustic field with different amplitudes of excitation. The equations of the perturbation amplitudes are derived using asymptotic expansions and linear stability analysis is then applied to the resulting differential equations. The stability of the encapsulated microbubbles to nonspherical small perturbations is examined by solving an eigenvalue problem. The approach then identifies the fastest growing perturbations which could lead to the breakup of the encapsulated microbubble or contrast agent. © 2012 Acoustical Society of America.

Defect Implosion Experiments (DIME) at OMEGA

NASA Astrophysics Data System (ADS)

Cobble, J. A.; Schmitt, M. J.; Tregillis, I. L.; Obrey, K. D.; Magelssen, G. R.; Wilke, M. D.; Glebov, V.; Marshall, F. J.; Kim, Y. H.; Bradley, P. A.; Batha, S. H.

2010-11-01

The Los Alamos DIME campaign involves perturbed spherical implosions, driven by 60 OMEGA beams with uniform, symmetrical illumination. D-T-filled CH-shell targets with equatorial-plane defects are designed to produce a non-spherical neutron burn region. The objectives of the DIME series are to observe the non-spherical burn with the neutron imaging system (NIS) and to simulate the physics of the neutron and x-ray production. We have demonstrated adequate neutron yield for NIS imaging with targets of diameter 860 μm. All targets are filled with 5 atm of DT. We used two separate shell thicknesses: 8 μm and 15 μm, thus testing both exploding pusher and ablative designs. Defect channel depth ranges from 0 -- 8 μm. Width is 20 -- 40 μm. Perfect targets have no defect. Numerical simulations predict enhanced x-ray emission, that is suggested by experiment. Results from a recent DIME campaign will be discussed.

Amplitude-modulated acoustic radiation force experienced by elastic and viscoelastic spherical shells in progressive waves.

PubMed

Mitri, F G; Fellah, Z E A

2006-07-01

The dynamic acoustic radiation force resulting from a dual-frequency beam incident on spherical shells immersed in an inviscid fluid is examined theoretically in relation to their thickness and the contents of their interior hollow regions. The theory is modified to include a hysteresis type of absorption inside the shells' material. The results of numerical calculations are presented for stainless steel and absorbing lucite (PolyMethyMethacrylAte) shells with the hollow region filled with water or air. Significant differences occur when the interior fluid inside the hollow region is changed from water to air. It is shown that the dynamic radiation force function Yd deviates from the static radiation force function Yp when the modulation size parameter deltax = mid R:x2 - x1mid R: (x1 = k1a, x2 = k2a, k1 and k2 are the wave vectors of the incident ultrasound waves, and a is the outer radius of the shell) starts to exceed the width of the resonance peaks in the Yp curves.

Response of moderately thick laminated cross-ply composite shells subjected to random excitation

NASA Technical Reports Server (NTRS)

Elishakoff, Isaak; Cederbaum, Gabriel; Librescu, Liviu

1989-01-01

This study deals with the dynamic response of transverse shear deformable laminated shells subjected to random excitation. The analysis encompasses the following problems: (1) the dynamic response of circular cylindrical shells of finite length excited by an axisymmetric uniform ring loading, stationary in time, and (2) the response of spherical and cylindrical panels subjected to stationary random loadings with uniform spatial distribution. The associated equations governing the structural theory of shells are derived upon discarding the classical Love-Kirchhoff (L-K) assumptions. In this sense, the theory is formulated in the framework of the first-order transverse shear deformation theory (FSDT).

Core-shell structured SiO2@YVO4:Dy3+/Sm3+ phosphor particles: sol-gel preparation and characterization.

PubMed

Wang, H; Yu, M; Lin, C K; Lin, J

2006-08-01

Spherical SiO(2) particles have been coated with YVO(4):Dy(3+)/Sm(3+) phosphor layers by a Pechini sol-gel process, leading to the formation of core-shell structured SiO(2)@YVO(4):Dy(3+)/Sm(3+) particles. X-ray diffraction (XRD), Fourier-transform IR spectroscopy, field emission scanning electron microscopy (FE-SEM), transmission electron microscopy (TEM), photoluminescence (PL) spectra as well as lifetimes were used to characterize the resulting SiO(2)@YVO(4):Dy(3+)/Sm(3+) core-shell phosphors. The obtained core-shell phosphors have perfect spherical shape with narrow size distribution (average size ca. 300 nm), smooth surface and non-agglomeration. The thickness of shells could be easily controlled by changing the number of deposition cycles (20 nm for one deposition cycle). The core-shell particles show strong characteristic emission from Dy(3+) for SiO(2)@YVO(4):Dy(3+) and from Sm(3+) for SiO(2)@YVO(4):Sm(3+) due to an efficient energy transfer from YVO(4) host to them. The PL intensity of Dy(3+) and Sm(3+) increases with raising the annealing temperature and the number of coating cycles.

Synthesis and thermal stability of W/WS{sub 2} inorganic fullerene-like nanoparticles with core-shell structure

DOE Office of Scientific and Technical Information (OSTI.GOV)

Chang Lianxia; Yang Haibin; Fu Wuyou

W/WS{sub 2} inorganic fullerene-like (IF) nanoparticles with core-shell structure are synthesized by the reaction of tungsten nanospheres and sulfur at relatively low temperatures (380-600 deg. C) under hydrogen atmosphere, in which tungsten nanospheres were prepared by wire electrical explosion method. Images of transmission electron microscopy and high-resolution transmission electron microscopy show that the composite particles are of core-shell structure with spherical shape and the shell thickness is about 10 nm. X-ray powder diffraction results indicate that the interlayer spacing of IF-WS{sub 2} shell decreases and approaches that of 2H-WS{sub 2} with increasing annealing temperatures, representing an expansion of 3.3-1.6%. Amore » mechanism of IF-WS{sub 2} formation via sulfur diffusion into fullerene nanoparticles is discussed. Thermal analysis shows that the nanoparticles obtained at different temperatures exhibit similar thermal stability and the onset temperature of oxidization is about 410 deg. C. Encapsulating hard tungsten core into IF-WS{sub 2} and the spherical shape of the core-shell structures may enhance their performance in tribological applications.« less

Enceladus's crust as a non-uniform thin shell: I tidal deformations

NASA Astrophysics Data System (ADS)

Beuthe, Mikael

2018-03-01

The geologic activity at Enceladus's south pole remains unexplained, though tidal deformations are probably the ultimate cause. Recent gravity and libration data indicate that Enceladus's icy crust floats on a global ocean, is rather thin, and has a strongly non-uniform thickness. Tidal effects are enhanced by crustal thinning at the south pole, so that realistic models of tidal tectonics and dissipation should take into account the lateral variations of shell structure. I construct here the theory of non-uniform viscoelastic thin shells, allowing for depth-dependent rheology and large lateral variations of shell thickness and rheology. Coupling to tides yields two 2D linear partial differential equations of the fourth order on the sphere which take into account self-gravity, density stratification below the shell, and core viscoelasticity. If the shell is laterally uniform, the solution agrees with analytical formulas for tidal Love numbers; errors on displacements and stresses are less than 5% and 15%, respectively, if the thickness is less than 10% of the radius. If the shell is non-uniform, the tidal thin shell equations are solved as a system of coupled linear equations in a spherical harmonic basis. Compared to finite element models, thin shell predictions are similar for the deformations due to Enceladus's pressurized ocean, but differ for the tides of Ganymede. If Enceladus's shell is conductive with isostatic thickness variations, surface stresses are approximately inversely proportional to the local shell thickness. The radial tide is only moderately enhanced at the south pole. The combination of crustal thinning and convection below the poles can amplify south polar stresses by a factor of 10, but it cannot explain the apparent time lag between the maximum plume brightness and the opening of tiger stripes. In a second paper, I will study the impact of a non-uniform crust on tidal dissipation.

Ignition of deuterium-trtium fuel targets

DOEpatents

Musinski, Donald L.; Mruzek, Michael T.

1991-01-01

A method of igniting a deuterium-tritium ICF fuel target to obtain fuel burn in which the fuel target initially includes a hollow spherical shell having a frozen layer of DT material at substantially uniform thickness and cryogenic temperature around the interior surface of the shell. The target is permitted to free-fall through a target chamber having walls heated by successive target ignitions, so that the target is uniformly heated during free-fall to at least partially melt the frozen fuel layer and form a liquid single-phase layer or a mixed liquid/solid bi-phase layer of substantially uniform thickness around the interior shell surface. The falling target is then illuminated from exteriorly of the chamber while the fuel layer is at substantially uniformly single or bi-phase so as to ignite the fuel layer and release energy therefrom.

Ignition of deuterium-tritium fuel targets

DOEpatents

Musinski, D.L.; Mruzek, M.T.

1991-08-27

Disclosed is a method of igniting a deuterium-tritium ICF fuel target to obtain fuel burn in which the fuel target initially includes a hollow spherical shell having a frozen layer of DT material at substantially uniform thickness and cryogenic temperature around the interior surface of the shell. The target is permitted to free-fall through a target chamber having walls heated by successive target ignitions, so that the target is uniformly heated during free-fall to at least partially melt the frozen fuel layer and form a liquid single-phase layer or a mixed liquid/solid bi-phase layer of substantially uniform thickness around the interior shell surface. The falling target is then illuminated from exteriorly of the chamber while the fuel layer is at substantially uniformly single or bi-phase so as to ignite the fuel layer and release energy therefrom. 5 figures.

Waltzing route toward double-helix formation in cholesteric shells

NASA Astrophysics Data System (ADS)

Darmon, Alexandre; Benzaquen, Michael; Seč, David; Čopar, Simon; Dauchot, Olivier; Lopez-Leon, Teresa

2016-08-01

Liquid crystals, when confined to a spherical shell, offer fascinating possibilities for producing artificial mesoscopic atoms, which could then self-assemble into materials structured at a nanoscale, such as photonic crystals or metamaterials. The spherical curvature of the shell imposes topological constraints in the molecular ordering of the liquid crystal, resulting in the formation of defects. Controlling the number of defects, that is, the shell valency, and their positions, is a key success factor for the realization of those materials. Liquid crystals with helical cholesteric order offer a promising, yet unexplored way of controlling the shell defect configuration. In this paper, we study cholesteric shells with monovalent and bivalent defect configurations. By bringing together experiments and numerical simulations, we show that the defects appearing in these two configurations have a complex inner structure, as recently reported for simulated droplets. Bivalent shells possess two highly structured defects, which are composed of a number of smaller defect rings that pile up through the shell. Monovalent shells have a single radial defect, which is composed of two nonsingular defect lines that wind around each other in a double-helix structure. The stability of the bivalent configuration against the monovalent one is controlled by c = h/p, where h is the shell thickness and p the cholesteric helical pitch. By playing with the shell geometry, we can trigger the transition between the two configurations. This transition involves a fascinating waltz dynamics, where the two defects come closer while turning around each other.

Synthesis characterisation series of newly fabricated type II CdSe CdSe/CdTe nanocrystals and their optical properties

NASA Astrophysics Data System (ADS)

Ahmed, A. S.; Christopher, W.

2018-03-01

Nanocrystalline semiconductors exhibit different properties due to two basic factors. They possess high surface to volume ratio and the actual size of particle can determine the electronic and physical properties of the material. The small size results in an observable quantum confinement effect, defined by the increasing bandgap accompanied by the quantization of the energy levels to discrete values. In present work we have synthesized the series of cadmium selenide/cadmium telluride (CdSe/CdTe) core/shell and CdSe/CdTe/CdS core/shell/shell to investigate the biexciton energy through transient absorption measurements. These structures are type II nanocrystals are with a hole in the shell and the electron confined to the core. We specifically investigate the effect of nanoparticle shape on the electronic structure and ultrafast electronic dynamics in the band-edge exciton states of CdSe quantum dots, nanorods, and nanoplatelets. Particle size was chosen to enable straightforward comparisons of the effects of particle shape on the spectra and dynamics without retuning the laser source. In our results the Uv-vis showed only a mild redshift in the first excitonic an elongated tail with increasing shell thickness. High resolution Transmission Electron Microscopy (HRTEM) shows the slight agglomeration of the nanocrystals but still the size distribution was calculate able. Spherical small crystals ranging from 5.9 nm to 10 nm are observed. CdTe/CdSe structures were quasi spherical with a rough diameter 6 nm with some little agglomerated structure. . The spherical nanocrystals could be peanut shaped oriented along the c axis or the spherical only, which could explain the two peak emission. p-XRD results indicate the predominant wurtzite structure throughout.

First fossil gravid turtle provides insight into the evolution of reproductive traits in turtles.

PubMed

Zelenitsky, Darla K; Therrien, Franc Ois; Joyce, Walter G; Brinkman, Donald B

2008-12-23

Here we report on the first discovery of shelled eggs inside the body cavity of a fossil turtle and on an isolated egg clutch, both referable to the Cretaceous turtle Adocus. These discoveries provide a unique opportunity to gain insight into the reproductive traits of an extinct turtle and to understand the evolution of such traits among living turtles. The gravid adult and egg clutch indicate that Adocus laid large clutches of rigid-shelled spherical eggs and established their nests near rivers, traits that are shared by its closest living relatives, the soft-shelled turtles. Adocus eggshell, however, was probably more rigid than that of living turtles, based on its great thickness and structure, features that may represent unique adaptations to intense predation or to arid nest environments. In light of the reproductive traits observed in Adocus, the distribution of reproductive traits among turtles reveals that large clutches of rigid-shelled eggs are primitive for hidden-necked turtles (cryptodirans) and that spherical eggs may have evolved independently within this group.

Tearing of thin spherical shells adhered to equally curved rigid substrates

NASA Astrophysics Data System (ADS)

McMahan, Connor; Lee, Anna; Marthelot, Joel; Reis, Pedro

Lasik (Laser-Assisted in Situ Keratomileusis) eye surgery involves the tearing of the corneal epithelium to remodel the corneal stroma for corrections such as myopia, hyperopia and astigmatism. One issue with this procedure is that during the tearing of the corneal epithelium, if the two propagating cracks coalesce, a flap detaches which could cause significant complications in the recovery of the patient. We seek to gain a predictive physical understanding of this process by performing precision desktop experiments on an analogue model system. First, thin spherical shells of nearly uniform thickness are fabricated by the coating of hemispherical molds with a polymer solution, which upon curing yields an elastic and brittle structure. We then create two notches near the equator of the shell and tear a flap by pulling tangentially to the spherical substrate, towards its pole. The resulting fracture paths are characterized by high-resolution 3D digital scanning. Our primary focus is on establishing how the positive Gaussian curvature of the system affects the path of the crack tip. Our results are directly contrasted against previous studies on systems with zero Gaussian curvature, where films were torn from planar and cylindrical substrates.

Thickness of the Magnetic Crust of Mars from Magneto-Spectral Analysis

NASA Technical Reports Server (NTRS)

Voorhies, Coerte V.

2006-01-01

Previous analysis of the magnetic spectrum of Mars showed only a crustal source field. The observational spectrum was fairly well fitted by the spectrum expected from random dipolar sources scattered on a spherical shell about 46 plus or minus 10 km below Mars' 3389.5 km mean radius. This de-correlation depth overestimates the typical depth of extended magnetized structures, and so was judged closer to mean source layer thickness than twice its value. To better estimate the thickness of the magnetic crust of Mars, six different magnetic spectra were fitted with the theoretical spectrum expected from a novel, bimodal distribution of magnetic sources. This theoretical spectrum represents both compact and extended, laterally correlated sources, so source shell depth is doubled to obtain layer thickness. The typical magnetic crustal thickness is put at 47.8 plus or minus 8.2 km. The extended sources are enormous, typically 650 km across, and account for over half the magnetic energy at low degrees. How did such vast regions form?

Core-shell monodisperse spherical mSiO2/Gd2O3:Eu3+@mSiO2 particles as potential multifunctional theranostic agents

NASA Astrophysics Data System (ADS)

Eurov, Daniil A.; Kurdyukov, Dmitry A.; Kirilenko, Demid A.; Kukushkina, Julia A.; Nashchekin, Alexei V.; Smirnov, Alexander N.; Golubev, Valery G.

2015-02-01

Core-shell nanoparticles with diameters in the range 100-500 nm have been synthesized as monodisperse spherical mesoporous (pore diameter 3 nm) silica particles with size deviation of less than 4 %, filled with gadolinium and europium oxides and coated with a mesoporous silica shell. It is shown that the melt technique developed for filling with gadolinium and europium oxides provides a nearly maximum filling of mesopores in a single-run impregnation, with gadolinium and europium uniformly distributed within the particles and forming no bulk oxides on their surface. The coating with a shell does not impair the monodispersity and causes no coagulation. The coating technique enables controlled variation of the shell thickness within the range 5-100 % relative to the core diameter. The thus produced nanoparticles are easily dispersed in water, have large specific surface area (300 m2 g-1) and pore volume (0.3 cm3 g-1), and are bright solid phosphor with superior stability in aqueous media. The core-shell structured particles can be potentially used for cancer treatment as a therapeutic agent (gadolinium neutron-capture therapy and drug delivery system) and, simultaneously, as a multimodal diagnostic tool (fluorescence and magnetic resonance imaging), thereby serving as a multifunctional theranostic agent.

Synthesis, characterization and evaluation of uniformly sized core-shell imprinted microspheres for the separation trans-resveratrol from giant knotweed

NASA Astrophysics Data System (ADS)

Zhang, Zhaohui; Liu, Li; Li, Hui; Yao, Shouzhuo

2009-09-01

A novel core-shell molecularly imprinting microspheres (MIMs) with trans-resveratrol as the template molecule; acrylamide (AA) as functional monomer and ethylene glycol dimethacrylate (EGDMA) as cross-linker, was prepared based on SiO 2 microspheres with surface imprinting technique. These core-shell trans-resveratrol imprinted microspheres were characterized by infrared spectra (IR), scanning electron microscopy (SEM), thermogravimetric analysis (TGA), and high performance liquid chromatography (HPLC). The results showed that these core-shell imprinted microspheres, which take on perfect spherical shape with average shell thickness of 150 nm, exhibit especially selective recognition for trans-resveratrol. These imprinted microspheres were applied as solid-phase extraction materials for selective extraction of trans-resveratrol from giant knotweed extracting solution successfully.

NCSP IER 422 CED-3b Documentation

DOE Office of Scientific and Technical Information (OSTI.GOV)

Hutchinson, Jesson D.; Cutler, Theresa Elizabeth; Bahran, Rian Mustafa

2017-11-22

A Subcritical Copper-Reflected α-phase Plutonium (SCRαP) integral benchmark experiment has been designed and measured. In this experiment, multiplication is approximated using correlated neutron data from a detector system consisting of 3He tubes inside high density polyethylene (HDPE). Measurements were performed on various subcritical experimental configurations consisting of a weapons-grade plutonium sphere surrounded by different Cu thicknesses. In addition to the proposed base experimental configurations with Cu, additional configurations were performed with the plutonium ball nested in various thicknesses of interleaved HDPE spherical shells mixed in with the Cu shells. The HDPE is intended to provide fast neutron moderation and reflection,more » resulting in additional measurements with differing multiplication, spectra, and nuclear data sensitivity.« less

Radiative transfer in spherical shell atmospheres. 2: Asymmetric phase functions

NASA Technical Reports Server (NTRS)

Kattawar, G. W.; Adams, C. N.

1977-01-01

The effects are investigated of sphericity on the radiation reflected from a planet with a homogeneous, conservative scattering atmosphere of optical thicknesses of 0.25 and 1.0. A Henyey-Greenstein phase function with asymmetry factors of 0.5 and 0.7 is considered. Significant differences were found when these results were compared with the plane-parallel calculations. Also large violations of the reciprocity theorem, which is only true for plane-parallel calculations, were noted. Results are presented for the radiance versus height distributions as a function of planetary phase angle.

Hydrodynamic stability and Ti-tracer distribution in low-adiabat OMEGA direct-drive implosions

NASA Astrophysics Data System (ADS)

Joshi, Tirtha R.

We discuss the hydrodynamic stability of low-adiabat OMEGA direct-drive implosions based on results obtained from simultaneous emission and absorption spectroscopy of a titanium tracer added to the target. The targets were deuterium filled, warm plastic shells of varying thicknesses and filling gas pressures with a submicron Ti-doped tracer layer initially located on the inner surface of the shell. The spectral features from the titanium tracer are observed during the deceleration and stagnation phases of the implosion, and recorded with a time integrated spectrometer (XRS1), streaked crystal spectrometer (SSCA) and three gated, multi-monochromatic X-ray imager (MMI) instruments fielded along quasi-orthogonal lines-of-sight. The time-integrated, streaked and gated data show simultaneous emission and absorption spectral features associated with titanium K-shell line transitions but only the MMI data provides spatially resolved information. The arrays of gated spectrally resolved images recorded with MMI were processed to obtain spatially resolved spectra characteristic of annular contour regions on the image. A multi-zone spectroscopic analysis of the annular spatially resolved spectra permits the extraction of plasma conditions in the core as well as the spatial distribution of tracer atoms. In turn, the titanium atom distribution provides direct evidence of tracer penetration into the core and thus of the hydrodynamic stability of the shell. The observations, timing and analysis indicate that during fuel burning the titanium atoms have migrated deep into the core and thus shell material mixing is likely to impact the rate of nuclear fusion reactions, i.e. burning rate, and the neutron yield of the implosion. We have found that the Ti atom number density decreases towards the center in early deceleration phase, but later in time the trend is just opposite, i.e., it increases towards the center of the implosion core. This is in part a consequence of the convergent effect of spherical geometry. The spatial profiles of Ti areal densities in the implosion core are extracted from space-resolved spectra and also evaluated using 1D spherical scaling. The trends are similar to the Ti number density spatial profiles. The areal densities extracted from data and 1D spherical scaling are very comparable in the outer spherical zones of the implosion core but significantly deviate in the innermost zone. We have observed that approximately 85% of the Ti atoms migrate into the hot core, while 15% of the atoms are still on the shell-fuel interface and contributing to the absorption. In addition, a method to extract the hot spot size based on the formation of the absorption feature in a sequence of annular spectra will be discussed. Results and trends are discussed as a function of target shell thickness and filling pressure, and laser pulse shape.

Dose in critical body organs in low Earth orbit

NASA Technical Reports Server (NTRS)

Wilson, J. W.; Cucinotta, F.

1984-01-01

Human exposure to trapped radiations in low Earth orbit (LEO) are evaluated on the basis of a simple approximation of the human geometry for spherical shell shields of varying thickness. A data base is presented that may be used to make preliminary assessment of the impact of radiation exposure constraints on human performance. A sample impact assessment is discussed.

Resource Letter NSM-1: New insights into the nuclear shell model

DOE Office of Scientific and Technical Information (OSTI.GOV)

Dean, David Jarvis; Hamilton, J. H.

2011-01-01

This Resource Letter provides a guide to the literature on the spherical shell model as applied to nuclei. The nuclear shell model describes the structure of nuclei starting with a nuclear core developed by the classical neutron and proton magic numbers N,Z=2,8,20,28,50,82, 126, where gaps occur in the single-particle energies as a shell is filled, and the interactions of valence nucleons that reside beyond that core. Various modern extensions of this model for spherical nuclei are likewise described. Significant extensions of the nuclear shell model include new magic numbers for spherical nuclei and now for deformed nuclei as well. Whenmore » both protons and neutrons have shell gaps at the same spherical or deformed shapes, they can reinforce each other to give added stability to that shape and lead to new magic numbers. The vanishings of the classical spherical shell model energy gaps and magic numbers in new neutron-rich nuclei are described. Spherical and deformed shell gaps are seen to be critical for the existence of elements with Z > 100.« less

Thick shell tectonics on one-plate planets - Applications to Mars

NASA Technical Reports Server (NTRS)

Banerdt, W. B.; Saunders, R. S.; Phillips, R. J.; Sleep, N. H.

1982-01-01

Using the zero frequency equations of a self-gravitating elastic spherical shell overlying a strengthless fluid, a theory for stress distribution in thick lithospheric shells on one-plate planets is developed. For both the compensated and flexural modes, stress distributions in lithospheres are reviewed. For compensated modes, surface stresses depend only on surface topography, whereas for flexural modes it is shown that, for long wavelengths, stress trajectories are mainly dependent on the lithospheric lateral density distribution and not on elastic properties. Computational analyses are performed for Mars, and it is found that isostatically compensated models correctly predict the graben structure in the immediate Tharsis region and a flexural loading model is satisfactory in explaining the graben in the regions surrounding Tharsis. A three-stage model for the evolution of Tharsis is hypothesized: isostasy with north-south graben formation on Tharsis, followed by flexural loading and radial graben formation on the perimeter of Tharsis, followed by a last stage of loading with little or no regional deformation.

The pick-up of cometary protons by the solar wind

NASA Technical Reports Server (NTRS)

Neugebauer, M.; Goldstein, B. E.; Goldstein, R.; Lazarus, A. J.; Altwegg, K.; Balsiger, H.

1987-01-01

The HERS detector of the Ion Mass Spectrometer on the Giotto spacecraft measured the 3-dimensional distribution of picked-up cometary protons over a distance of about 8 million km upstream of the bow shock of comet P/Hally. The protons were observed to be elastically scattered out of their original cycloidal trajectories such that they were nonuniformly distributed over a spherical shell in velocity space. The shell radius (relative to its expected radius) and thickness increased as the bow shock was approached. Down-stream of the shock, the cometary protons could not be distinguished from the heated solar wind protons.

Global Curvature Buckling and Snapping of Spherical Shells.

NASA Astrophysics Data System (ADS)

Pezzulla, Matteo; Stoop, Norbert; Steranka, Mark; Bade, Abdikhalaq; Trejo, Miguel; Holmes, Douglas

A spherical shell under external pressure will eventually buckle locally through the development of a dimple. However, when a free spherical shell is subject to variations in natural curvature, it will either buckle globally or snap towards a buckled configuration. We study the similarities and differences between pressure and curvature instabilities in spherical shells. We show how the critical buckling natural curvature is largely independent of the thinness and half-angle of the shell, while the critical snapping natural curvature grows linearly with the half-angle. As a result, we demonstrate how a critical half-angle, depending only on the thinness of the shell, sets the threshold between two different kinds of snapping: as a rule of thumb, shallow shells snap into everted shells, while deep shells snap into buckled shells. As the developed models are purely geometrical, the results are applicable to a large variety of stimuli and scales. NSF CAREER CMMI-1454153.

Structure of Enceladus' Ice Shell

NASA Astrophysics Data System (ADS)

Hemingway, D.

2016-12-01

Constraining the internal structure of Enceladus is essential for understanding its evolution, its highly active south polar region, and its prospects for habitability. Of particular interest is the thickness of the icy shell, which has implications for the thermal structure, the effects of tidal stresses, and the conduits feeding the jets and plume. Since Enceladus' low order gravity field was first measured [1], several studies of shape and gravity have suggested the presence of an internal ocean beneath the icy shell [1-3]. These analyses, however, involve several assumptions and approximations and yield distinct shell thickness estimates (ranging from 18-60 km), only some of which are compatible with estimates from the measured physical librations (15-25 km [4,5]). Part of the challenge is that standard approaches to interior modeling (e.g., Radau-Darwin) are not well suited to Enceladus due to its fast rotation and relatively large non-hydrostatic topography [2,6]. Because of Enceladus' small radius, results are also sensitive to the details of the compensation model [7,8]. Here we apply an analytical compensation model that accommodates the spherical geometry in a manner that is distinct from previous studies, and employ a high fidelity numerical approach to modeling the hydrostatic equilibrium figure [6]. We show that the resulting shell thickness estimates are smaller than in previous models—in agreement with the libration observations—suggesting the possibility of an extremely thin ice crust at the south pole. While a range of mean shell thicknesses are permitted within the observational constraints, the amplitude of lateral shell thickness variations is well constrained. In particular, the shell is 10 km thicker at the north pole than at the south pole, potentially helping to explain the nature of the north-south polar asymmetry in endogenic activity. 1. Iess et al., Science. 344, 78-80 (2014). 2. McKinnon, Geophys. Res. Lett.42 (2015). 3. Cadek et al., Geophys. Res. Lett. (2016). 4. Thomas et al., Icarus. 264, 37-47 (2016). 5. Van Hoolst, Baland, Trinh, Icarus. 277, 311-318 (2016). 6. Tricarico, Astrophys. J. 782, 99 (2014). 7. Jeffreys, The Earth (Cambridge University Press, 6thed, 1976). 8. Turcotte, Willemann, Haxby, Norberry, J. Geophys. Res. 86, 3951-3959 (1981).

Synthesis and Characterization of SiO2@Y2MoO6:Eu3+ Core-Shell Structured Spherical Phosphors by Sol-Gel Process.

PubMed

Li, G Z; Liu, F H; Chu, Z S; Wu, D M; Yang, L B; Li, J L; Wang, M N; Wang, Z L

2016-04-01

SiO2@Y2MoO6:Eu3+ core-shell phosphors were prepared by the sol-gel process. X-ray diffraction (XRD), Fourier transform infrared spectroscopy (FT-IR), field emission scanning electron microscopy (FESEM), energy-dispersive X-ray spectra (EDS), transmission electron microscopy (TEM), photoluminescence (PL) spectra as well as kinetic decays were used to characterize the resulting SiO2@Y2MoO6:Eu3+ core-shell phosphors. The XRD results demonstrated that the Y2MoO6:Eu3+ layers on the SiO2 spheres crystallized after being annealed at 700 °C and the crystallinity increased with raising the annealing temperature. The obtained core-shell phosphors have spherical shape with narrow size distribution (average size ca. 640 nm), non-agglomeration, and smooth surface. The thickness of the Y2MoO6:Eu3+ shells on the SiO2 cores could be easily tailored by varying the number of deposition cycles (70 nm for four deposition cycles). The Eul+ shows a strong PL emission (dominated by 5D0-7F2 red emission at 614 nm) under the excitation of 347 nm UV light. The PL intensity of Eu3+ increases with increasing the annealing temperature and the number of coating cycles.

Insight into the electrical properties and chain conformation of spherical polyelectrolyte brushes by dielectric spectroscopy

NASA Astrophysics Data System (ADS)

Guo, Xiaoxia; Zhao, Kongshuang

2017-02-01

We report here a dielectric study on three kinds of anionic spherical polyelectrolyte brush (SPBs, consisting of a polystyrene (PS) core and three different poly (acrylic acid) chains grafted onto the core) suspensions over a frequency ranging from 40 Hz to 110 MHz. The relaxation behavior of the SPB suspensions shows significant changes in the brush-layer properties when the mass fraction of SPBs and the pH of the suspensions change. Two definite relaxations related to the interfacial polarization are observed around 100 kHz and 10 MHz. A single-layer spherical-shell model is applied to describe the SPB suspensions wherein the suspended SPB is modeled as a spherical-shell composite particle in which an insulated PS sphere is surrounded by a conducting ion-permeable shell (the polyelectrolyte chain layer). We developed the curve-fitting procedure to analyze the dielectric spectrum in order to obtain the dielectric properties of the components of the SPBs, especially the properties of the polyelectrolyte brush. Based on this method and model, the permittivity and conductivity of the brush layer, ζ potential, etc are calculated. The ordered orientation of the water molecules in the layer leads to an additional electrical dipole moment; increasing pH causes the brush layer to swell. In addition, the repulsive force between the SPB particles are evaluated using the brush-layer thickness, which is obtained by fitting dielectric spectra, combined with relative theoretical formulas. Increasing PH values or SPB concentration would improve the stability of the SPBs dispersion.

Radiative transfer in spherical shell atmospheres. II - Asymmetric phase functions

NASA Technical Reports Server (NTRS)

Kattawar, G. W.; Adams, C. N.

1978-01-01

This paper investigates the effects of sphericity on the radiation reflected from a planet with a homogeneous conservative-scattering atmosphere of optical thicknesses of 0.25 and 1.0. A Henyey-Greenstein phase function with asymmetry factors of 0.5 and 0.7 was considered. Significant differences were found when these results were compared with the plane-parallel calculations. Also, large violations of the reciprocity theorem, which is only true for plane-parallel calculations, were noted. Results are presented for the radiance versus height distributions as a function of planetary phase angle. These results will be useful to researchers in the field of remote sensing and planetary spectroscopy.

Localized tidal deformations and dissipation in Enceladus

NASA Astrophysics Data System (ADS)

Beuthe, M.

2017-12-01

The geologic activity at Enceladus's south pole remains unexplained, though tidal deformations are probably the ultimate cause. Recent gravity and libration data indicate that Enceladus's icy crust floats on a global ocean, is rather thin, and has a strongly non-uniform thickness. Tidal effects are enhanced by crustal thinning at the south pole, so that realistic models of tidal tectonics and dissipation should include lateral variations of shell structure. I solve this problem with a new theory of non-uniform viscoelastic thin shells, allowing for large lateral variations of crustal thickness as well as large 3D variations of crustal rheology. The coupling to tidal forcing takes into account self-gravity, density stratification below the shell, core viscoelasticity, and crustal compressibility. The resulting tidal thin shell equations are two partial differential equations defined on the spherical surface, which can be solved numerically much faster than 3D Finite Element Methods. The error on tidal displacements is less than 5% if the thickness is less than 10% of the radius while the error on the deviatoric stress varies between 0 and 10%. If Enceladus's shell is conductive with isostatic thickness variations, crustal thinning increases surface stresses by 60% at the north pole and by a factor of more than 3 at the south pole. Similarly, the surface flux resulting from crustal dissipation increases by a factor of 3 at the south pole. If dissipation is an order of magnitude higher than predicted by the Maxwell model (as suggested by recent experimental data), the power dissipated in the crust could reach 50% of the total power required to maintain the crust in thermal equilibrium, and most of the surface flux variation could be explained by latitudinal variations of crustal dissipation. In all cases, a large part of the heat budget must be generated below the crust.

Influence of the shell thickness and charge distribution on the effective interaction between two like-charged hollow spheres.

PubMed

Angelescu, Daniel G; Caragheorgheopol, Dan

2015-10-14

The mean-force and the potential of the mean force between two like-charged spherical shells were investigated in the salt-free limit using the primitive model and Monte Carlo simulations. Apart from an angular homogeneous distribution, a discrete charge distribution where point charges localized on the shell outer surface followed an icosahedral arrangement was considered. The electrostatic coupling of the model system was altered by the presence of mono-, trivalent counterions or small dendrimers, each one bearing a net charge of 9 e. We analyzed in detail how the shell thickness and the radial and angular distribution of the shell charges influenced the effective interaction between the shells. We found a sequence of the potential of the mean force similar to the like-charged filled spheres, ranging from long-range purely repulsive to short-range purely attractive as the electrostatic coupling increased. Both types of potentials were attenuated and an attractive-to-repulsive transition occurred in the presence of trivalent counterions as a result of (i) thinning the shell or (ii) shifting the shell charge from the outer towards the inner surface. The potential of the mean force became more attractive with the icosahedrally symmetric charge model, and additionally, at least one shell tended to line up with 5-fold symmetry axis along the longest axis of the simulation box at the maximum attraction. The results provided a basic framework of understanding the non-specific electrostatic origin of the agglomeration and long-range assembly of the viral nanoparticles.

Prospects For Earth-Based Measurements Of Europa's Librations

NASA Astrophysics Data System (ADS)

Margot, Jean-Luc; Campbell, D. B.; Peale, S. J.

2010-10-01

The exploration of Europa is of great interest because it may be hospitable to certain life forms [1]. Several lines of evidence suggest that a subsurface ocean exists beneath an icy shell [2,3], but there is debate about the thickness of the shell [4], which impacts Europa's astrobiological potential. As in the case of Mercury, it may be possible to determine whether an outer shell is decoupled from the interior and to evaluate the shell thickness by measuring the amplitude of forced longitude librations [5,6]. In the simplest configuration of a rigid shell decoupled from a spherically symmetric interior, the libration amplitude is amplified from the nominal value of 18" by C/Cs, where C is the polar moment of inertia of the body and Cs is that of the outer shell that participates in the librations. For a 100-km thick shell, the libration amplitude would reach 200", an estimate that remains valid even in the presence of gravitational coupling between asymmetrical layers [7]. If there are significant departures from rigid behavior, the shell may deform with the ocean underneath and exhibit a libration amplitude of 52" [8]. Europa reaches closest approach in October 2011, offering a once-in-a-decade opportunity to measure spin rate variations by tracking radar speckles, as advocated by Holin [9,10]. Librations of a rigid shell thinner than 100 km would be detectable. We will describe the experimental design and expected sensitivity. References: [1] NRC, Europa Science Strategy, 1999. [2,3] Kivelson et al, Greeley et al, in Jupiter, CUP, 2004. [4] Greenberg, Unmasking Europa, Praxis, 2008. [5] Peale, Nature 262, 1976. [6] Margot et al, Science 316, 2007. [7] van Hoolst et al, Icarus 195, 2008. [8] Goldreich and Mitchell, Icarus, in press. [9] Green, in Radar Astronomy, McGraw-Hill, 1968. [10] Holin, Radiophys. Quant. Elec. 31, 1988.

Nonlinear problems of the theory of heterogeneous slightly curved shells

NASA Technical Reports Server (NTRS)

Kantor, B. Y.

1973-01-01

An account if given of the variational method of the solution of physically and geometrically nonlinear problems of the theory of heterogeneous slightly curved shells. Examined are the bending and supercritical behavior of plates and conical and spherical cupolas of variable thickness in a temperature field, taking into account the dependence of the elastic parameters on temperature. The bending, stability in general and load-bearing capacity of flexible isotropic elastic-plastic shells with different criteria of plasticity, taking into account compressibility and hardening. The effect of the plastic heterogeneity caused by heat treatment, surface work hardening and irradiation by fast neutron flux is investigated. Some problems of the dynamic behavior of flexible shells are solved. Calculations are performed in high approximations. Considerable attention is given to the construction of a machine algorithm and to the checking of the convergence of iterative processes.

Nonlinear finite-element analysis of nanoindentation of viral capsids

NASA Astrophysics Data System (ADS)

Gibbons, Melissa M.; Klug, William S.

2007-03-01

Recent atomic force microscope (AFM) nanoindentation experiments measuring mechanical response of the protein shells of viruses have provided a quantitative description of their strength and elasticity. To better understand and interpret these measurements, and to elucidate the underlying mechanisms, this paper adopts a course-grained modeling approach within the framework of three-dimensional nonlinear continuum elasticity. Homogeneous, isotropic, elastic, thick-shell models are proposed for two capsids: the spherical cowpea chlorotic mottle virus (CCMV), and the ellipsocylindrical bacteriophage ϕ29 . As analyzed by the finite-element method, these models enable parametric characterization of the effects of AFM tip geometry, capsid dimensions, and capsid constitutive descriptions. The generally nonlinear force response of capsids to indentation is shown to be insensitive to constitutive particulars, and greatly influenced by geometric and kinematic details. Nonlinear stiffening and softening of the force response is dependent on the AFM tip dimensions and shell thickness. Fits of the models capture the roughly linear behavior observed in experimental measurements and result in estimates of Young’s moduli of ≈280-360MPa for CCMV and ≈4.5GPa for ϕ29 .

Fabrication of bifunctional core-shell Fe3O4 particles coated with ultrathin phosphor layer

PubMed Central

2013-01-01

Bifunctional monodispersed Fe3O4 particles coated with an ultrathin Y2O3:Tb3+ shell layer were fabricated using a facile urea-based homogeneous precipitation method. The obtained composite particles were characterized by powder X-ray diffraction, transmission electron microscopy (TEM), quantum design vibrating sample magnetometry, and photoluminescence (PL) spectroscopy. TEM revealed uniform spherical core-shell-structured composites ranging in size from 306 to 330 nm with a shell thickness of approximately 25 nm. PL spectroscopy confirmed that the synthesized composites displayed a strong eye-visible green light emission. Magnetic measurements indicated that the composite particles obtained also exhibited strong superparamagnetic behavior at room temperature. Therefore, the inner Fe3O4 core and outer Y2O3:Tb3+ shell layer endow the composites with both robust magnetic properties and strong eye-visible luminescent properties. These composite materials have potential use in magnetic targeting and bioseparation, simultaneously coupled with luminescent imaging. PMID:23962025

Fabrication of bifunctional core-shell Fe3O4 particles coated with ultrathin phosphor layer

NASA Astrophysics Data System (ADS)

Atabaev, Timur Sh; Kim, Hyung-Kook; Hwang, Yoon-Hwae

2013-08-01

Bifunctional monodispersed Fe3O4 particles coated with an ultrathin Y2O3:Tb3+ shell layer were fabricated using a facile urea-based homogeneous precipitation method. The obtained composite particles were characterized by powder X-ray diffraction, transmission electron microscopy (TEM), quantum design vibrating sample magnetometry, and photoluminescence (PL) spectroscopy. TEM revealed uniform spherical core-shell-structured composites ranging in size from 306 to 330 nm with a shell thickness of approximately 25 nm. PL spectroscopy confirmed that the synthesized composites displayed a strong eye-visible green light emission. Magnetic measurements indicated that the composite particles obtained also exhibited strong superparamagnetic behavior at room temperature. Therefore, the inner Fe3O4 core and outer Y2O3:Tb3+ shell layer endow the composites with both robust magnetic properties and strong eye-visible luminescent properties. These composite materials have potential use in magnetic targeting and bioseparation, simultaneously coupled with luminescent imaging.

DNA nanoparticles with core-shell morphology.

PubMed

Chandran, Preethi L; Dimitriadis, Emilios K; Lisziewicz, Julianna; Speransky, Vlad; Horkay, Ferenc

2014-10-14

Mannobiose-modified polyethylenimines (PEI) are used in gene therapy to generate nanoparticles of DNA that can be targeted to the antigen-presenting cells of the immune system. We report that the sugar modification alters the DNA organization within the nanoparticles from homogenous to shell-like packing. The depth-dependent packing of DNA within the nanoparticles was probed using AFM nano-indentation. Unmodified PEI-DNA nanoparticles display linear elastic properties and depth-independent mechanics, characteristic of homogenous materials. Mannobiose-modified nanoparticles, however, showed distinct force regimes that were dependent on indentation depth, with 'buckling'-like response that is reproducible and not due to particle failure. By comparison with theoretical studies of spherical shell mechanics, the structure of mannobiosylated particles was deduced to be a thin shell with wall thickness in the order of few nanometers, and a fluid-filled core. The shell-core structure is also consistent with observations of nanoparticle denting in altered solution conditions, with measurements of nanoparticle water content from AFM images, and with images of DNA distribution in Transmission Electron Microscopy.

Preparation, characterization, and optical properties of gold, silver, and gold-silver alloy nanoshells having silica cores.

PubMed

Kim, Jun-Hyun; Bryan, William W; Lee, T Randall

2008-10-07

This report describes the structural and optical properties of a series of spherical shell/core nanoparticles in which the shell is comprised of a thin layer of gold, silver, or gold-silver alloy, and the core is comprised of a monodispersed silica nanoparticle. The silica core particles were prepared using the Stöber method, functionalized with terminal amine groups, and then seeded with small gold nanoparticles (approximately 2 nm in diameter). The gold-seeded silica particles were coated with a layer of gold, silver, or gold-silver alloy via solution-phase reduction of an appropriate metal ion or mixture of metal ions. The size, morphology, and elemental composition of the composite nanoparticles were characterized by field emission scanning electron microscopy (FE-SEM), energy-dispersive X-ray spectroscopy (EDX), X-ray diffraction (XRD), Fourier transform infrared (FT-IR) spectroscopy, thermal gravimetric analysis (TGA), dynamic light scattering (DLS), and transmission electron microscopy (TEM). The optical properties of the nanoparticles were analyzed by UV-vis spectroscopy, which showed strong absorptions ranging from 400 nm into the near-IR region, where the position of the plasmon band reflected not only the thickness of the metal shell, but also the nature of the metal comprising the shell. Importantly, the results demonstrate a new strategy for tuning the position of the plasmon resonance without having to vary the core diameter or the shell thickness.

Luminescent properties of YVO4:Eu/SiO2 core-shell composite particles

NASA Astrophysics Data System (ADS)

Bao, Amurisana; Lai, Hua; Yang, Yuming; Liu, Zhilong; Tao, Chunyan; Yang, Hua

2010-02-01

We report an efficient process for preparing monodisperse SiO2@Y0.95Eu0.05VO4 core-shell phosphors using a simple citrate sol-gel method and without the use of surface-coupling silane agents or large stabilizers. X-ray diffraction (XRD), field emission scanning electron microscopy (FESEM), transmission electron microscopy (TEM), and photoluminescence (PL) spectra were used to characterize the resulting SiO2@Y0.95Eu0.05VO4 core-shell phosphors. The XRD results demonstrate that the Y0.95Eu0.05VO4 particles crystallization on the surface of SiO2 annealing at 800 °C is perfectly and the crystallinity increases with raising the annealing temperature. The obtained core-shell phosphors have a near perfect spherical shape with narrow size distribution (average size ca. 500 nm and an average thickness of 50 nm), are not agglomerated, and have a smooth surface. The thickness of the YVO4:Eu3+ shells on the SiO2 cores could be easily tailored by changing the mass ratio of shell to core ( W = [YVO4]/[SiO2]) ( 50 nm for W = 30%). The Eu3+ shows a strong PL luminescence (dominated by 5D0 - 7F2 red emission at 618 nm) under the excitation of 320 nm UV light. The PL intensity of Eu3+ increases with increasing the annealing temperature and the values of W.

Flexural models of trench/outer rise topography of coronae on Venus with axisymmetric spherical shell elastic plates

NASA Technical Reports Server (NTRS)

Moore, W.; Schubert, Gerald; Sandwell, David T.

1992-01-01

Magellan altimetry has revealed that many coronae on Venus have trenches or moats around their peripheries and rises outboard of the trenches. This trench/outer rise topographic signature is generally associated with the tectonic annulus of the corona. Sandwell and Schubert have interpreted the trench/outer rise topography and the associated tectonic annulus around coronae to be the result of elastic bending of the Venus lithosphere (though the tectonic structures are consequences of inelastic deformation of the lithosphere). They used two-dimensional elastic plate flexure theory to fit topographic profiles across a number of large coronae and inferred elastic lithosphere thicknesses between about 15 and 40 km, similar to inferred values of elastic thickness for the Earth's lithosphere at subduction zones around the Pacific Ocean. Here, we report the results of using axisymmetric elastic flexure theory for the deformation of thin spherical shell plates to interpret the trench/outer rise topography of the large coronae modeled by Sandwell and Schubert and of coronae as small as 250 km in diameter. In the case of a corona only a few hundred kilometers in diameter, the model accounts for the small planform radius of the moat and the nonradial orientation of altimetric traces across the corona. By fitting the flexural topography of coronae we determine the elastic thickness and loading necessary to account for the observed flexure. We calculate the associated bending moment and determine whether the corona interior topographic load can provide the required moment. We also calculate surface stresses and compare the stress distribution with the location of annular tectonic features.

Highly luminescent silica-coated CdS/CdSe/CdS nanoparticles with strong chemical robustness and excellent thermal stability

NASA Astrophysics Data System (ADS)

Wang, Nianfang; Koh, Sungjun; Jeong, Byeong Guk; Lee, Dongkyu; Kim, Whi Dong; Park, Kyoungwon; Nam, Min Ki; Lee, Kangha; Kim, Yewon; Lee, Baek-Hee; Lee, Kangtaek; Bae, Wan Ki; Lee, Doh C.

2017-05-01

We present facile synthesis of bright CdS/CdSe/CdS@SiO2 nanoparticles with 72% of quantum yields (QYs) retaining ca 80% of the original QYs. The main innovative point is the utilization of the highly luminescent CdS/CdSe/CdS seed/spherical quantum well/shell (SQW) as silica coating seeds. The significance of inorganic semiconductor shell passivation and structure design of quantum dots (QDs) for obtaining bright QD@SiO2 is demonstrated by applying silica encapsulation via reverse microemulsion method to three kinds of QDs with different structure: CdSe core and 2 nm CdS shell (CdSe/CdS-thin); CdSe core and 6 nm CdS shell (CdSe/CdS-thick); and CdS core, CdSe intermediate shell and 5 nm CdS outer shell (CdS/CdSe/CdS-SQW). Silica encapsulation inevitably results in lower photoluminescence quantum yield (PL QY) than pristine QDs due to formation of surface defects. However, the retaining ratio of pristine QY is different in the three silica coated samples; for example, CdSe/CdS-thin/SiO2 shows the lowest retaining ratio (36%) while the retaining ratio of pristine PL QY in CdSe/CdS-thick/SiO2 and SQW/SiO2 is over 80% and SQW/SiO2 shows the highest resulting PL QY. Thick outermost CdS shell isolates the excitons from the defects at surface, making PL QY relatively insensitive to silica encapsulation. The bright SiO2-coated SQW sample shows robustness against harsh conditions, such as acid etching and thermal annealing. The high luminescence and long-term stability highlights the potential of using the SQW/SiO2 nanoparticles in bio-labeling or display applications.

A numerical analysis of contact and limit-point behavior in a class of problems of finite elastic deformation

NASA Technical Reports Server (NTRS)

Endo, T.; Oden, J. T.; Becker, E. B.; Miller, T.

1984-01-01

Finite element methods for the analysis of bifurcations, limit-point behavior, and unilateral frictionless contact of elastic bodies undergoing finite deformation are presented. Particular attention is given to the development and application of Riks-type algorithms for the analysis of limit points and exterior penalty methods for handling the unilateral constraints. Applications focus on the problem of finite axisymmetric deformations, snap-through, and inflation of thick rubber spherical shells.

Viscous flow in and around a cavity surrounded by a concentric permeable patch

NASA Astrophysics Data System (ADS)

Palaniappan, D.

2017-11-01

Steady viscous incompressible fluid flow in and around a spherical fluid cavity of radius a surrounded by a permeable patch with thickness b - a is investigated in the limit of low-Reynolds number. Our model uses the Stokes equations in the pure fluid regions and the Darcy law in the concentric permeable patch. Analytic solutions for the velocity and pressure fields are derived in singularity form involving the key parameters such as the Darcy permeability coefficient k and the thickness of the permeable layer. The Faxen law for the hydrodynamical drag acting on the concentric spherical geometry due to an arbitrary incident flow is extracted from our singularity solutions. It is found that the thickness of the permeable layer and the permeability play a crucial role in controlling the drag. An expression for the mass of the fluid that enters the outer sphere is calculated by integrating the exterior radial velocity field. The hydrodynamic force on the concentric spherical shell due to the flow induced by a Stokeslet is also derived from our general expressions. Several special cases of interest are deduced from our exact analysis. The results are of some interest in the prediction of forces exerted on the walls in certain biological models with permeable layers. I request you to place my presentation on the 19th (Sunday) as I have to give final exams on Monday. Thank you.

Dynamical systems for modeling evolution of the magnetic field of the Sun, stars and planets

NASA Astrophysics Data System (ADS)

Popova, E.

2016-12-01

The magnetic activity of the Sun, stars and planets are connected with a dynamo process based on the combined action of the differential rotation and the alpha-effect. Application of this concept allows us to get different types of solutions which can describe the magnetic activity of celestial bodies. We investigated the dynamo model with the meridional circulation by the low-mode approach. This approach is based on an assumption that the magnetic field can be described by non-linear dynamical systems with a relatively small number of parameters. Such non-linear dynamical systems are based on the equations of dynamo models. With this method dynamical systems have been built for media which contains the meridional flow and thickness of the spherical shell where dynamo process operates. It was shown the possibility of coexistence of quiasi-biennial oscillations, 22-year cycle, and grand minima of magnetic activity which is consistent with the observational data for the solar activity. We obtained different regimes (oscillations, vacillations, dynamo-bursts) depending on a value of the dynamo-number, the meridional circulation, and thickness of the spherical shell. We discuss features of these regimes and compare them with the observed features of the magnetic fields of the Sun, stars and Earth. We built theoretical paleomagnetic time scale and butterfly-diagrams for the helicity and toroidal magnetic field for different regimes.

Application of an ultrasonic focusing radiator for acoustic levitation of submillimeter samples

NASA Technical Reports Server (NTRS)

Lee, M. C.

1981-01-01

An acoustic apparatus has been specifically developed to handle samples of submillimeter size in a gaseous medium. This apparatus consists of an acoustic levitation device, deployment devices for small liquid and solid samples, heat sources for sample heat treatment, acoustic alignment devices, a cooling system and data-acquisition instrumentation. The levitation device includes a spherical aluminum dish of 12 in. diameter and 0.6 in. thickness, 130 pieces of PZT transducers attached to the back side of the dish and a spherical concave reflector situated in the vicinity of the center of curvature of the dish. The three lowest operating frequencies for the focusing-radiator levitation device are 75, 105 and 163 kHz, respectively. In comparison with other levitation apparatus, it possesses a large radiation pressure and a high lateral positional stability. This apparatus can be used most advantageously in the study of droplets and spherical shell systems, for instance, for fusion target applications.

Hierarchical nanostructured hollow spherical carbon with mesoporous shell as a unique cathode catalyst support in proton exchange membrane fuel cell.

PubMed

Fang, Baizeng; Kim, Jung Ho; Kim, Minsik; Kim, Minwoo; Yu, Jong-Sung

2009-03-07

Hierarchical nanostructured spherical carbon with hollow macroporous core in combination with mesoporous shell has been explored to support Pt cathode catalyst with high metal loading in proton exchange membrane fuel cell (PEMFC). The hollow core-mesoporous shell carbon (HCMSC) has unique structural characteristics such as large specific surface area and mesoporous volume, ensuring uniform dispersion of the supported high loading (60 wt%) Pt nanoparticles with small particle size, and well-developed three-dimensionally interconnected hierarchical porosity network, facilitating fast mass transport. The HCMSC-supported Pt(60 wt%) cathode catalyst has demonstrated markedly enhanced catalytic activity toward oxygen reduction and greatly improved PEMFC polarization performance compared with carbon black Vulcan XC-72 (VC)-supported ones. Furthermore, the HCMSC-supported Pt(40 wt%) or Pt(60 wt%) outperforms the HCMSC-supported Pt(20 wt%) even at a low catalyst loading of 0.2 mg Pt cm(-2) in the cathode, which is completely different from the VC-supported Pt catalysts. The capability of supporting high loading Pt is supposed to accelerate the commercialization of PEMFC due to the anticipated significant reduction in the amount of catalyst support required, diffusion layer thickness and fabricating cost of the supported Pt catalyst electrode.

Suppression of an acoustic mode by an elastic mode of a liquid-filled spherical shell resonator.

PubMed

Lonzaga, Joel B; Raymond, Jason L; Mobley, Joel; Gaitan, D Felipe

2011-02-01

The purpose of this paper is to report on the suppression of an approximately radial (radially symmetric) acoustic mode by an elastic mode of a water-filled, spherical shell resonator. The resonator, which has a 1-in. wall thickness and a 9.5-in. outer diameter, was externally driven by a small transducer bolted to the external wall. Experiments showed that for the range of drive frequencies (19.7-20.6 kHz) and sound speeds in water (1520-1570 m/s) considered in this paper, a nonradial (radially nonsymmetric) mode was also excited, in addition to the radial mode. Furthermore, as the sound speed in the liquid was changed, the resonance frequency of the nonradial mode crossed with that of the radial one and the amplitude of the latter was greatly reduced near the crossing point. The crossing of the eigenfrequency curves of these two modes was also predicted theoretically. Further calculations demonstrated that while the radial mode is an acoustic one associated with the interior fluid, the nonradial mode is an elastic one associated with the shell. Thus, the suppression of the radial acoustic mode is apparently caused by the overlapping with the nonradial elastic mode near the crossing point.

Cracking the chocolate egg problem: polymeric films coated on curved substrates

NASA Astrophysics Data System (ADS)

Brun, Pierre-Thomas; Lee, Anna; Marthelot, Joel; Balestra, Gioele; Gallaire, François; Reis, Pedro

2015-11-01

Inspired by the traditional chocolate egg recipe, we show that pouring a polymeric solution onto spherical molds yields a simple and robust path of fabrication of thin elastic curved shells. The drainage dynamics naturally leads to uniform coatings frozen in time as the polymer cures, which are subsequently peeled off their mold. We show how the polymer curing affects the drainage dynamics and eventually selects the shell thickness and sets its uniformity. To this end, we perform coating experiments using silicon based elastomers, Vinylpolysiloxane (VPS) and Polydimethylsiloxane (PDMS). These results are rationalized combining numerical simulations of the lubrication flow field to a theoretical model of the dynamics yielding an analytical prediction of the formed shell characteristics. In particular, the robustness of the coating technique and its flexibility, two critical features for providing a generic framework for future studies, are shown to be an inherent consequence of the flow field (memory loss). The shell structure is both independent of initial conditions and tailorable by changing a single experimental parameter.

Elastic thickness determination based on Vening Meinesz-Moritz and flexural theories of isostasy

NASA Astrophysics Data System (ADS)

Eshagh, Mehdi

2018-06-01

Elastic thickness (Te) is one of mechanical properties of the Earth's lithosphere. The lithosphere is assumed to be a thin elastic shell, which is bended under the topographic, bathymetric and sediment loads on. The flexure of this elastic shell depends on its thickness or Te. Those shells having larger Te flex less. In this paper, a forward computational method is presented based on the Vening Meinesz-Moritz (VMM) and flexural theories of isostasy. Two Moho flexure models are determined using these theories, considering effects of surface and subsurface loads. Different values are selected for Te in the flexural method to see by which one, the closest Moho flexure to that of the VMM is achieved. The effects of topographic/bathymetric, sediments and crustal crystalline masses, and laterally variable upper mantle density, Young's modulus and Poisson's ratio are considered in whole computational process. Our mathematical derivations are based on spherical harmonics, which can be used to estimate Te at any single point, meaning that there is no edge effect in the method. However, the Te map needs to be filtered to remove noise at some points. A median filter with a window size of 5° × 5° and overlap of 4° works well for this purpose. The method is applied to estimate Te over South America using the data of CRUST1.0 and a global gravity model.

Spherical-shell boundaries for two-dimensional compressible convection in a star

NASA Astrophysics Data System (ADS)

Pratt, J.; Baraffe, I.; Goffrey, T.; Geroux, C.; Viallet, M.; Folini, D.; Constantino, T.; Popov, M.; Walder, R.

2016-10-01

Context. Studies of stellar convection typically use a spherical-shell geometry. The radial extent of the shell and the boundary conditions applied are based on the model of the star investigated. We study the impact of different two-dimensional spherical shells on compressible convection. Realistic profiles for density and temperature from an established one-dimensional stellar evolution code are used to produce a model of a large stellar convection zone representative of a young low-mass star, like our sun at 106 years of age. Aims: We analyze how the radial extent of the spherical shell changes the convective dynamics that result in the deep interior of the young sun model, far from the surface. In the near-surface layers, simple small-scale convection develops from the profiles of temperature and density. A central radiative zone below the convection zone provides a lower boundary on the convection zone. The inclusion of either of these physically distinct layers in the spherical shell can potentially affect the characteristics of deep convection. Methods: We perform hydrodynamic implicit large eddy simulations of compressible convection using the MUltidimensional Stellar Implicit Code (MUSIC). Because MUSIC has been designed to use realistic stellar models produced from one-dimensional stellar evolution calculations, MUSIC simulations are capable of seamlessly modeling a whole star. Simulations in two-dimensional spherical shells that have different radial extents are performed over tens or even hundreds of convective turnover times, permitting the collection of well-converged statistics. Results: To measure the impact of the spherical-shell geometry and our treatment of boundaries, we evaluate basic statistics of the convective turnover time, the convective velocity, and the overshooting layer. These quantities are selected for their relevance to one-dimensional stellar evolution calculations, so that our results are focused toward studies exploiting the so-called 321D link. We find that the inclusion in the spherical shell of the boundary between the radiative and convection zones decreases the amplitude of convective velocities in the convection zone. The inclusion of near-surface layers in the spherical shell can increase the amplitude of convective velocities, although the radial structure of the velocity profile established by deep convection is unchanged. The impact of including the near-surface layers depends on the speed and structure of small-scale convection in the near-surface layers. Larger convective velocities in the convection zone result in a commensurate increase in the overshooting layer width and a decrease in the convective turnover time. These results provide support for non-local aspects of convection.

Magnetic and Optical Properties of Submicron-Size Hollow Spheres

PubMed Central

Ye, Quan-Lin; Yoshikawa, Hirofumi; Awaga, Kunio

2010-01-01

Magnetic hollow spheres with a controlled diameter and shell thickness have emerged as an important class of magnetic nanomaterials. The confined hollow geometry and pronouncedly curved surfaces induce unique physical properties different from those of flat thin films and solid counterparts. In this paper, we focus on recent progress on submicron-size spherical hollow magnets (e.g., cobalt- and iron-based materials), and discuss the effects of the hollow shape and the submicron size on magnetic and optical properties.

Fabrication of precision glass shells by joining glass rods

DOEpatents

Gac, Frank D.; Blake, Rodger D.; Day, Delbert E.; Haggerty, John S.

1988-01-01

A method for making uniform spherical shells. The present invention allows niform hollow spheres to be made by first making a void in a body of material. The material is heated so that the viscosity is sufficiently low so that the surface tension will transform the void into a bubble. The bubble is allowed to rise in the body until it is spherical. The excess material is removed from around the void to form a spherical shell with a uniform outside diameter.

Hollow spherical shell manufacture

DOEpatents

O'Holleran, T.P.

1991-11-26

A process is disclosed for making a hollow spherical shell of silicate glass composition in which an aqueous suspension of silicate glass particles and an immiscible liquid blowing agent is placed within the hollow spherical cavity of a porous mold. The mold is spun to reduce effective gravity to zero and to center the blowing agent, while being heated so as to vaporize the immiscible liquid and urge the water carrier of the aqueous suspension to migrate into the body of the mold, leaving a green shell compact deposited around the mold cavity. The green shell compact is then removed from the cavity, and is sintered for a time and a temperature sufficient to form a silicate glass shell of substantially homogeneous composition and uniform geometry. 3 figures.

Hollow spherical shell manufacture

DOEpatents

O'Holleran, Thomas P.

1991-01-01

A process for making a hollow spherical shell of silicate glass composition in which an aqueous suspension of silicate glass particles and an immiscible liquid blowing agent is placed within the hollow spherical cavity of a porous mold. The mold is spun to reduce effective gravity to zero and to center the blowing agent, while being heated so as to vaporize the immiscible liquid and urge the water carrier of the aqueous suspension to migrate into the body of the mold, leaving a green shell compact deposited around the mold cavity. The green shell compact is then removed from the cavity, and is sintered for a time and a temperature sufficient to form a silicate glass shell of substantially homogeneous composition and uniform geometry.

Multi-shell spherical GaAs /AlxGa1-x As quantum dot shells-size distribution as a mechanism to generate intermediate band energy levels

NASA Astrophysics Data System (ADS)

Rodríguez-Magdaleno, K. A.; Pérez-Álvarez, R.; Martínez-Orozco, J. C.; Pernas-Salomón, R.

2017-04-01

In this work the generation of an intermediate band of energy levels from multi-shell spherical GaAs /AlxGa1-x As quantum dot shells-size distribution is reported. Within the effective mass approximation the electronic structure of a GaAs spherical quantum-dot surrounded by one, two and three shells is studied in detail using a numerically stable transfer matrix method. We found that a shells-size distribution characterized by continuously wider GaAs domains is a suitable mechanism to generate the intermediate band whose width is also dependent on the Aluminium concentration x. Our results suggest that this effective mechanism can be used for the design of wider intermediate band than reported in other quantum systems with possible solar cells enhanced performance.

Effect of metallic walls on dynamos generated by laminar boundary-driven flow in a spherical domain.

PubMed

Guervilly, Céline; Wood, Toby S; Brummell, Nicholas H

2013-11-01

We present a numerical study of dynamo action in a conducting fluid encased in a metallic spherical shell. Motions in the fluid are driven by differential rotation of the outer metallic shell, which we refer to as "the wall." The two hemispheres of the wall are held in counter-rotation, producing a steady, axisymmetric interior flow consisting of differential rotation and a two-cell meridional circulation with radial inflow in the equatorial plane. From previous studies, this type of flow is known to maintain a stationary equatorial dipole by dynamo action if the magnetic Reynolds number is larger than about 300 and if the outer boundary is electrically insulating. We vary independently the thickness, electrical conductivity, and magnetic permeability of the wall to determine their effect on the dynamo action. The main results are the following: (a) Increasing the conductivity of the wall hinders the dynamo by allowing eddy currents within the wall, which are induced by the relative motion of the equatorial dipole field and the wall. This processes can be viewed as a skin effect or, equivalently, as the tearing apart of the dipole by the differential rotation of the wall, to which the field lines are anchored by high conductivity. (b) Increasing the magnetic permeability of the wall favors dynamo action by constraining the magnetic field lines in the fluid to be normal to the wall, thereby decoupling the fluid from any induction in the wall. (c) Decreasing the wall thickness limits the amplitude of the eddy currents, and is therefore favorable for dynamo action, provided that the wall is thinner than the skin depth. We explicitly demonstrate these effects of the wall properties on the dynamo field by deriving an effective boundary condition in the limit of vanishing wall thickness.

Comparison of Large eddy dynamo simulation using dynamic sub-grid scale (SGS) model with a fully resolved direct simulation in a rotating spherical shell

NASA Astrophysics Data System (ADS)

Matsui, H.; Buffett, B. A.

2017-12-01

The flow in the Earth's outer core is expected to have vast length scale from the geometry of the outer core to the thickness of the boundary layer. Because of the limitation of the spatial resolution in the numerical simulations, sub-grid scale (SGS) modeling is required to model the effects of the unresolved field on the large-scale fields. We model the effects of sub-grid scale flow and magnetic field using a dynamic scale similarity model. Four terms are introduced for the momentum flux, heat flux, Lorentz force and magnetic induction. The model was previously used in the convection-driven dynamo in a rotating plane layer and spherical shell using the Finite Element Methods. In the present study, we perform large eddy simulations (LES) using the dynamic scale similarity model. The scale similarity model is implement in Calypso, which is a numerical dynamo model using spherical harmonics expansion. To obtain the SGS terms, the spatial filtering in the horizontal directions is done by taking the convolution of a Gaussian filter expressed in terms of a spherical harmonic expansion, following Jekeli (1981). A Gaussian field is also applied in the radial direction. To verify the present model, we perform a fully resolved direct numerical simulation (DNS) with the truncation of the spherical harmonics L = 255 as a reference. And, we perform unresolved DNS and LES with SGS model on coarser resolution (L= 127, 84, and 63) using the same control parameter as the resolved DNS. We will discuss the verification results by comparison among these simulations and role of small scale fields to large scale fields through the role of the SGS terms in LES.

Repeated crossing of two concentric spherical thin-shells with charge

NASA Astrophysics Data System (ADS)

Mazharimousavi, S. Habib; Halilsoy, M.

Interaction/collision of two concentric spherical thin-shells of linear fluid resulting in collapse has been considered recently. We show that addition of finely tuned electric charges on the shells apart from the cosmological constant serves to delay the collapse indefinitely, yielding an ever colliding system of two concentric fluid shells. Given the finely tuned charges, this provides an example of a perpetual two-body motion in general relativity.

Modeling mantle convection in the spherical annulus

NASA Astrophysics Data System (ADS)

Hernlund, John W.; Tackley, Paul J.

2008-12-01

Most methods for modeling mantle convection in a two-dimensional (2D) circular annular domain suffer from innate shortcomings in their ability to capture several characteristics of the spherical shell geometry of planetary mantles. While methods such as rescaling the inner and outer radius to reduce anomalous effects in a 2D polar cylindrical coordinate system have been introduced and widely implemented, such fixes may have other drawbacks that adversely affect the outcome of some kinds of mantle convection studies. Here we propose a new approach that we term the "spherical annulus," which is a 2D slice that bisects the spherical shell and is quantitatively formulated at the equator of a spherical polar coordinate system after neglecting terms in the governing equations related to variations in latitude. Spherical scaling is retained in this approximation since the Jacobian function remains proportional to the square of the radius. We present example calculations to show that the behavior of convection in the spherical annulus compares favorably against calculations performed in other 2D annular domains when measured relative to those in a fully three-dimensional (3D) spherical shell.

Numerical modeling of the 3D dynamics of ultrasound contrast agent microbubbles using the boundary integral method

NASA Astrophysics Data System (ADS)

Wang, Qianxi; Manmi, Kawa; Calvisi, Michael L.

2015-02-01

Ultrasound contrast agents (UCAs) are microbubbles stabilized with a shell typically of lipid, polymer, or protein and are emerging as a unique tool for noninvasive therapies ranging from gene delivery to tumor ablation. While various models have been developed to describe the spherical oscillations of contrast agents, the treatment of nonspherical behavior has received less attention. However, the nonspherical dynamics of contrast agents are thought to play an important role in therapeutic applications, for example, enhancing the uptake of therapeutic agents across cell membranes and tissue interfaces, and causing tissue ablation. In this paper, a model for nonspherical contrast agent dynamics based on the boundary integral method is described. The effects of the encapsulating shell are approximated by adapting Hoff's model for thin-shell, spherical contrast agents. A high-quality mesh of the bubble surface is maintained by implementing a hybrid approach of the Lagrangian method and elastic mesh technique. The numerical model agrees well with a modified Rayleigh-Plesset equation for encapsulated spherical bubbles. Numerical analyses of the dynamics of UCAs in an infinite liquid and near a rigid wall are performed in parameter regimes of clinical relevance. The oscillation amplitude and period decrease significantly due to the coating. A bubble jet forms when the amplitude of ultrasound is sufficiently large, as occurs for bubbles without a coating; however, the threshold amplitude required to incite jetting increases due to the coating. When a UCA is near a rigid boundary subject to acoustic forcing, the jet is directed towards the wall if the acoustic wave propagates perpendicular to the boundary. When the acoustic wave propagates parallel to the rigid boundary, the jet direction has components both along the wave direction and towards the boundary that depend mainly on the dimensionless standoff distance of the bubble from the boundary. In all cases, the jet directions for the coated and uncoated bubble are similar but the jet width and jet velocity are smaller for a coated bubble. The effects of shell thickness and shell viscosity are analyzed and determined to affect the bubble dynamics, including jet development.

Modeling and studying of white light emitting diodes based on CdS/ZnS spherical quantum dots

NASA Astrophysics Data System (ADS)

Hasanirokh, K.; Asgari, A.

2018-07-01

In this paper, we propose a quantum dot (QD) based white light emitting diode (WLED) structure to study theoretically the material gain and quantum efficiency of the system. We consider the spherical QDs with a II-VI semiconductor core (CdS) that covered with a wider band gap semiconductor acting as a shell (ZnS). In order to generate white light spectrum, we use layers with different dot size that can emit blue, green and red colors. The blue emission originating from CdS core combines to green/orange components originating from ZnS shell and creates an efficiency white light emission. To model this device, at first, we solve Schrödinger and Poisson equations self consistently and obtain eigen energies and wave functions. Then, we calculate the optical gain and internal quantum efficiency (IQE) of a CdS/ZnS LED sample. We investigate the structural parameter effects on the optical properties of the WLED. The numerical results show that the gain profile and IQE curves depend strongly on the structural parameters such as dot size, carrier density and volume scaling parameter. The gain profile becomes higher and wider with increasing the core radius while it becomes less and narrower with increasing the shell thickness. Furthermore, it is found that the volume scaling parameter can manage the system quantum efficiency.

Fabrication and characterization of millimeter-scale translucent La{sub 2}O{sub 3}-doped Al{sub 2}O{sub 3} ceramic hollow spheres

DOE Office of Scientific and Technical Information (OSTI.GOV)

Li, Haoting; Liao, Qilong, E-mail: liaoqilong@swust.edu.cn; Dai, Yunya

2016-04-15

Highlights: • Millimeter-scale translucent La{sub 2}O{sub 3}-doped Al{sub 2}O{sub 3} hollow spheres have been prepared. • The diameters of the prepared hollow spheres are 500–1300μm. • The degree of sphericity for the prepared hollow spheres is above 98%. • The mechanisms of transparency are discussed. - Abstract: Millimeter-scale translucent La{sub 2}O{sub 3}-doped Al{sub 2}O{sub 3} ceramic hollow spheres have been successfully prepared using the oil-in-water (paraffin-in-alumina sol) droplets as precursors made by self-made T-shape micro-emulsion device. The main crystalline phase of the obtained hollow sphere is alpha alumina. The prepared translucent La{sub 2}O{sub 3}-containing Al{sub 2}O{sub 3} ceramic hollow spheresmore » have diameters of 500–1300 μm, wall thickness of about 23 μm and the degree of sphericity of above 98%. With the increase of the La{sub 2}O{sub 3} content, grains and grain-boundaries of the alumina spherical shell for the prepared millimeter-scale hollow spheres become regular and clear gradually. When the La{sub 2}O{sub 3} content is 0.1 wt.%, the crystal surface of the obtained Al{sub 2}O{sub 3} spherical shell shows optimal grains and few pores, and its transmittance reaches 42% at 532 nm laser light. This method provides a promising technique of preparing millimeter-scale translucent ceramic hollow spheres for laser inertial confined fusion.« less

Design and calculation of low infrared transmittance and low emissivity coatings for heat radiative applications

NASA Astrophysics Data System (ADS)

Wang, Guang-Hai; Zhang, Yue; Zhang, Da-Hai; Fan, Jin-Peng

2012-02-01

The infrared transmittance and emissivity of heat-insulating coatings pigmented with various structural particles were studied using Kubelka-Munk theory and Mie theory. The primary design purpose was to obtain the low transmittance and low emissivity coatings to reduce the heat transfer by thermal radiation for high-temperature applications. In the case of silica coating layers constituted with various structural titania particles (solid, hollow, and core-shell spherical), the dependence of transmittance and emissivity of the coating layer on the particle structure and the layer thickness was investigated and optimized. The results indicate that the coating pigmented with core-shell titania particles exhibits a lower infrared transmittance and a lower emissivity value than that with other structural particles and is suitable to radiative heat-insulating applications.

Spherical neutron generator

DOEpatents

Leung, Ka-Ngo

2006-11-21

A spherical neutron generator is formed with a small spherical target and a spherical shell RF-driven plasma ion source surrounding the target. A deuterium (or deuterium and tritium) ion plasma is produced by RF excitation in the plasma ion source using an RF antenna. The plasma generation region is a spherical shell between an outer chamber and an inner extraction electrode. A spherical neutron generating target is at the center of the chamber and is biased negatively with respect to the extraction electrode which contains many holes. Ions passing through the holes in the extraction electrode are focused onto the target which produces neutrons by D-D or D-T reactions.

HYDRODYNAMICAL INTERACTION OF MILDLY RELATIVISTIC EJECTA WITH AN AMBIENT MEDIUM

DOE Office of Scientific and Technical Information (OSTI.GOV)

Suzuki, Akihiro; Maeda, Keiichi; Shigeyama, Toshikazu

2017-01-01

The hydrodynamical interaction of spherical ejecta freely expanding at mildly relativistic speeds into an ambient cold medium is studied in semianalytical and numerical ways to investigate how ejecta produced in energetic stellar explosions dissipate their kinetic energy through the interaction with the surrounding medium. We especially focus on the case in which the circumstellar medium (CSM) is well represented by a steady wind at a constant mass-loss rate, having been ejected from the stellar surface prior to the explosion. As a result of the hydrodynamical interaction, the ejecta and CSM are swept by the reverse and forward shocks, leading tomore » the formation of a geometrically thin shell. We present a semianalytical model describing the dynamical evolution of the shell and compare the results with numerical simulations. The shell can give rise to bright emission as it gradually becomes transparent to photons. We develop an emission model for the expected emission from the optically thick shell, in which photons in the shell gradually diffuse out to the interstellar space. Then we investigate the possibility that radiation powered by the hydrodynamical interaction is the origin of an underluminous class of gamma-ray bursts.« less

Hierarchical Mesoporous Organosilica-Silica Core-Shell Nanoparticles Capable of Controlled Fungicide Release.

PubMed

Luo, Leilei; Liang, Yucang; Erichsen, Egil Severin; Anwander, Reiner

2018-05-17

A new class of hierarchically structured mesoporous silica core-shell nanoparticles (HSMSCSNs) with a periodic mesoporous organosilica (PMO) core and a mesoporous silica (MS) shell is reported. The applied one-pot, two-step strategy allows rational control over the core/shell chemical composition, topology, and pore/particle size, simply by adjusting the reaction conditions in the presence of cetyltrimethylammonium bromide (CTAB) as structure-directing agent under basic conditions. The spherical, ethylene- or methylene-bridged PMO cores feature hexagonal (p6mm) or cage-like cubic symmetry (Pm3‾ n) depending on the organosilica precursor. The hexagonal MS shell was obtained by n-hexane-induced controlled hydrolysis of TEOS followed by directional co-assembly/condensation of silicate/CTAB composites at the PMO cores. The HSMSCSNs feature a hierarchical pore structure with pore diameters of about 2.7 and 5.6 nm in the core and shell domains, respectively. The core sizes and shell thicknesses are adjustable in the ranges of 90-275 and 15-50 nm, respectively, and the surface areas (max. 1300 m 2  g -1 ) and pore volumes (max. 1.83 cm 3  g -1 ) are among the highest reported for core-shell nanoparticles. The adsorption and controlled release of the fungicide propiconazole by the HSMSCSNs showed a three-stage release profile. © 2018 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.

Thin Shell Model for NIF capsule stagnation studies

NASA Astrophysics Data System (ADS)

Hammer, J. H.; Buchoff, M.; Brandon, S.; Field, J. E.; Gaffney, J.; Kritcher, A.; Nora, R. C.; Peterson, J. L.; Spears, B.; Springer, P. T.

2015-11-01

We adapt the thin shell model of Ott et al. to asymmetric ICF capsule implosions on NIF. Through much of an implosion, the shell aspect ratio is large so the thin shell approximation is well satisfied. Asymmetric pressure drive is applied using an analytic form for ablation pressure as a function of the x-ray flux, as well as time-dependent 3D drive asymmetry from hohlraum calculations. Since deviations from a sphere are small through peak velocity, we linearize the equations, decompose them by spherical harmonics and solve ODE's for the coefficients. The model gives the shell position, velocity and areal mass variations at the time of peak velocity, near 250 microns radius. The variables are used to initialize 3D rad-hydro calculations with the HYDRA and ARES codes. At link time the cold fuel shell and ablator are each characterized by a density, adiabat and mass. The thickness, position and velocity of each point are taken from the thin shell model. The interior of the shell is filled with a uniform gas density and temperature consistent with the 3/2PV energy found from 1D rad-hydro calculations. 3D linked simulations compare favorably with integrated simulations of the entire implosion. Through generating synthetic diagnostic data, the model offers a method for quickly testing hypothetical sources of asymmetry and comparing with experiment. Prepared by LLNL under Contract DE-AC52-07NA27344.

Human exposure in low Earth orbit

NASA Technical Reports Server (NTRS)

Wilson, J. W.; Cucinotta, F.

1984-01-01

Human exposure to trapped electrons and protons in low Earth orbit (LEO) is evaluated on a basis of a simple approximation of the human geometry for spherical shell shields of varying thickness. A data base is presented that may be used to make preliminary assessment of the impact of radiation exposure constraints on human performance. Detailed shielding studies should be performed before final design considerations. A sample impact assessment is discussed on the basis of presently accepted allowable exposure limits. A brief discussion is given on the anticipated impact of an ongoing reassessment of allowable exposure limits.

Scattering theory derivation of a 3D acoustic cloaking shell.

PubMed

Cummer, Steven A; Popa, Bogdan-Ioan; Schurig, David; Smith, David R; Pendry, John; Rahm, Marco; Starr, Anthony

2008-01-18

Through acoustic scattering theory we derive the mass density and bulk modulus of a spherical shell that can eliminate scattering from an arbitrary object in the interior of the shell--in other words, a 3D acoustic cloaking shell. Calculations confirm that the pressure and velocity fields are smoothly bent and excluded from the central region as for previously reported electromagnetic cloaking shells. The shell requires an anisotropic mass density with principal axes in the spherical coordinate directions and a radially dependent bulk modulus. The existence of this 3D cloaking shell indicates that such reflectionless solutions may also exist for other wave systems that are not isomorphic with electromagnetics.

Tidal deformation of Enceladus' ice shell with variable thickness and Maxwell rheology

NASA Astrophysics Data System (ADS)

Soucek, Ondrej; Behounkova, Marie; Cadek, Ondrej; Tobie, Gabriel; Choblet, Gael

2017-04-01

Tidal deformation of icy moons has been traditionally studied using the spectral approach which is very efficient for perfectly spherical bodies with radially dependent rheological structure. Measurements of Enceladus' topography (Nimmo et al., 2011) and low-degree gravity (Iess et al., 2014) indicate that the ice shell is significantly thinned in the southern hemisphere (Iess et al., 2014; McKinnon, 2015) and according to recent gravity, shape and libration inversion, it may be only a few kilometers thick at the south pole (Cadek et al., 2016). These variations may potentially have a significant effect on the amplitude and pattern of tidal deformation, stress and associated heating inside the shell, but cannot be straightforwardly incorporated into the existing spectral codes. In order to circumvent this difficulty and to quantify the effects of ice-shell thickness variations, we have developed a three-dimensional finite element code in the framework of FEniCS package (Alnaes et al., 2015). Using this numerical tool, we address the changes in tidally-induced deformation amplitude, stresses and tidal heating for structural models of Enceladus' ice shell of various complexity. Considering Maxwell viscoelastic rheology of the shell, we compare models with uniform thickness consistent with the libration data and with constant viscosity, synthetic models with analytically parameterized thinning in the south polar region and depth-dependent viscosity varying over several orders of magnitude, and finally, models with the shell topography and thickness based on the recent model of Cadek et al. (2016). We find that the thinning of the ice shell around the south pole may lead to amplification of the stress and displacement in this region region by a factor of up to 2 and 4, respectively, depending on the average ice shell thickness, the amplitude of thinning and the viscosity structure. Our results also suggest that lateral variations of ice thickness can induce significant anomalies of the surface heat flux and, together with other effects (e.g. Souček et al., 2016), may thus contribute to the hemispheric dichotomy observed on Enceladus. Alnaes, M. S., Blechta, J., Hake, J., Johansson, J., Kehlet, B., Logg, A., Richardson, C., Ring, J., Rognes, M. E.,Wells, G. N., 2015. The FEniCS Project Version 1.5. Archive of Numerical Software 3 (100), 9-23. Cadek, O., Tobie, G., van Hoolst, T., Masse, M., Choblet, G., Lefevre, A., Mitri, G., Baland, R.-M., Behounkova, M., Bourgeois, O., Trinh, A., 2016. Enceladus's internal ocean and ice shell constrained from Cassini gravity, shape, and libration data. Geophys. Res. Let. 46, 5653-5660. Iess, L., Stevenson, D. J., Parisi, M., Hemingway, D., Jacobson, R. A., Lunine, J. I., Nimmo, F., Armstrong, J. W., Asmar, S. W., Ducci, M., Tortora, P., Apr. 2014. The Gravity Field and Interior Structure of Enceladus. Science 344, 78-80. McKinnon, W. B., Apr. 2015. Effect of Enceladus's rapid synchronous spin on interpretation of Cassini gravity. Geophys. Res. Let. 42, 2137-2143. Nimmo, F., Bills, B. G., Thomas, P. C., 2011. Geophysical implications of the long-wavelength topography of the Saturnian satellites. J. Geophys. Res. 116 (E15), E11001. Soucek, O., Hron, J., Behounkova, M., Cadek, O., 2016. Effect of the tiger stripes on the deformation of Saturn's moon Enceladus. Geophys. Res. Let. 43, 7417-7423.

The classical D-type expansion of spherical H II regions

NASA Astrophysics Data System (ADS)

Williams, Robin J. R.; Bibas, Thomas G.; Haworth, Thomas J.; Mackey, Jonathan

2018-06-01

Recent numerical and analytic work has highlighted some shortcomings in our understanding of the dynamics of H II region expansion, especially at late times, when the H II region approaches pressure equilibrium with the ambient medium. Here we reconsider the idealized case of a constant radiation source in a uniform and spherically symmetric ambient medium, with an isothermal equation of state. A thick-shell solution is developed which captures the stalling of the ionization front and the decay of the leading shock to a weak compression wave as it escapes to large radii. An acoustic approximation is introduced to capture the late-time damped oscillations of the H II region about the stagnation radius. Putting these together, a matched asymptotic equation is derived for the radius of the ionization front which accounts for both the inertia of the expanding shell and the finite temperature of the ambient medium. The solution to this equation is shown to agree very well with the numerical solution at all times, and is superior to all previously published solutions. The matched asymptotic solution can also accurately model the variation of H II region radius for a time-varying radiation source.

How Spherical Is a Cube (Gravitationally)?

NASA Astrophysics Data System (ADS)

Sanny, Jeff; Smith, David

2015-02-01

An important concept that is presented in the discussion of Newton's law of universal gravitation is that the gravitational effect external to a spherically symmetric mass distribution is the same as if all of the mass of the distribution were concentrated at the center.1,2 By integrating over ring elements of a spherical shell, we show that the gravitational force on a point mass outside the shell is the same as that of a particle with the same mass as the shell at its center. This derivation works for objects with spherical symmetry while depending on the fact that the gravitational force between two point masses varies inversely as the square of their separation.3 If these conditions are not met, then the problem becomes more difficult. In this paper, we remove the condition of spherical symmetry and examine the gravitational force between two uniform cubes.

Alternating current dielectrophoresis of core-shell nanoparticles: Experiments and comparison with theory

NASA Astrophysics Data System (ADS)

Yang, Chungja

Nanoparticles are fascinating where physical and optical properties are related to size. Highly controllable synthesis methods and nanoparticle assembly are essential for highly innovative technological applications. Well-defined shaped and sized nanoparticles enable comparisons between experiments, theory and subsequent new models to explain experimentally observed phenomena. Among nanoparticles, nonhomogeneous core-shell nanoparticles (CSnp) have new properties that arise when varying the relative dimensions of the core and the shell. This CSnp structure enables various optical resonances, and engineered energy barriers, in addition to the high charge to surface ratio. Assembly of homogeneous nanoparticles into functional structures has become ubiquitous in biosensors (i.e. optical labeling), nanocoatings, and electrical circuits. Limited nonhomogenous nanoparticle assembly has only been explored. Many conventional nanoparticle assembly methods exist, but this work explores dielectrophoresis (DEP) as a new method. DEP is particle polarization via non-uniform electric fields while suspended in conductive fluids. Most prior DEP efforts involve microscale particles. Prior work on core-shell nanoparticle assemblies and separately, nanoparticle characterizations with dielectrophoresis and electrorotation, did not systematically explore particle size, dielectric properties (permittivity and electrical conductivity), shell thickness, particle concentration, medium conductivity, and frequency. This work is the first, to the best of our knowledge, to systematically examine these dielectrophoretic properties for core-shell nanoparticles. Further, we conduct a parametric fitting to traditional core-shell models. These biocompatible core-shell nanoparticles were studied to fill a knowledge gap in the DEP field. Experimental results (chapter 5) first examine medium conductivity, size and shell material dependencies of dielectrophoretic behaviors of spherical CSnp into 2D and 3D particle-assemblies. Chitosan (amino sugar) and poly-L-lysine (amino acid, PLL) CSnp shell materials were custom synthesized around a hollow (gas) core by utilizing a phospholipid micelle around a volatile fluid templating for the shell material; this approach proves to be novel and distinct from conventional core-shell models wherein a conductive core is coated with an insulative shell. Experiments were conducted within a 100 nl chamber housing 100 um wide Ti/Au quadrapole electrodes spaced 25 um apart. Frequencies from 100kHz to 80MHz at fixed local field of 5Vpp were tested with 10-5 and 10-3 S/m medium conductivities for 25 seconds. Dielectrophoretic responses of ~220 and 340(or ~400) nm chitosan or PLL CSnp were compiled as a function of medium conductivity, size and shell material. Experiments further examined shell thickness and particle concentration (chapter 6) dependencies on ~530 nm CSnp dielectrophoretic and electrorotational responses with ~30nm and ~80 nm shell thicknesses and at particle concentration count rates of 5000 +/- 500, 10000 +/- 500, and 15000 +/- 500 counts per second. Using similar experimental conditions, both dielectrophoretic and electrorotational CSnp responses were compiled versus frequency, shell thickness, and particle concentration. Knowledge gained from this study includes a unique resonance-like dielectrophoretic and electrorotational spectrum, which is significantly distinct from other cells and particles. CSnp dielectric properties were then calculated by parametrically fitting parameters to an existing core-shell model. The optimum conductivity and relative permittivity for the core and the shell are 1E-15 S/m, 1, 0.6 S/m, and 90, respectively. These properties can be exploited to rapidly assemble these unique core-shell particles for future structural color production in fabrics, vehicle, and wall painting.

Surface plasmon resonance enhanced light absorption and wavelength tuneable in gold-coated iron oxide spherical nanoparticle

NASA Astrophysics Data System (ADS)

Dasri, Thananchai; Chingsungnoen, Artit

2018-06-01

Surface plasmon in nano-sized particles, such as gold, silver, copper and their composites, has recently attracted a great deal of attention due to its possible uses in many applications, especially in life sciences. It is desirable for application devices with a tenability of surface plasmon wavelength and optical properties enhancement. This article presents enhanced optical light absorption and tunable wavelength in gold-coated magnetite (Fe3O4@Au core-shell) nanoparticles embedded in water using the theoretical method of discrete dipole approximation (DDA). The absorption spectra in the wavelengths from 350 to 900 nm were found to be the spectra obtained from Fe3O4@Au core-shell nanoparticles, and when compared with pure Fe3O4 nanoparticles, the surface plasmon resonance can be enhanced and tuned over the entire visible spectrum (viz. 350-800 nm) of the electromagnetic spectrum by varying the Au shell thickness (2-5 nm). Similarly, the Faraday rotation spectra can also be obtained.

Viscoelastic damped response of cross-ply laminated shallow spherical shells subjected to various impulsive loads

NASA Astrophysics Data System (ADS)

Şahan, Mehmet Fatih

2017-11-01

In this paper, the viscoelastic damped response of cross-ply laminated shallow spherical shells is investigated numerically in a transformed Laplace space. In the proposed approach, the governing differential equations of cross-ply laminated shallow spherical shell are derived using the dynamic version of the principle of virtual displacements. Following this, the Laplace transform is employed in the transient analysis of viscoelastic laminated shell problem. Also, damping can be incorporated with ease in the transformed domain. The transformed time-independent equations in spatial coordinate are solved numerically by Gauss elimination. Numerical inverse transformation of the results into the real domain are operated by the modified Durbin transform method. Verification of the presented method is carried out by comparing the results with those obtained by the Newmark method and ANSYS finite element software. Furthermore, the developed solution approach is applied to problems with several impulsive loads. The novelty of the present study lies in the fact that a combination of the Navier method and Laplace transform is employed in the analysis of cross-ply laminated shallow spherical viscoelastic shells. The numerical sample results have proved that the presented method constitutes a highly accurate and efficient solution, which can be easily applied to the laminated viscoelastic shell problems.

Effects of compressibility on the temperature jump at the interface of layered, spherical-shell convection

NASA Technical Reports Server (NTRS)

Yen, David A.; Zhang, Shuxia; Langenberger, Sherri E.

1988-01-01

Large temperature jumps at the interface of layered convection are important to the argument used against the likelihood of separate circulations in the upper and lower mantles. This problem was studied within the framework of a compressible, constant viscosity spherical-shell model. Both mechanical and thermal coupling configurations are considered. Although the temperature jumps are reduced by compressibility, their magnitudes remain quite large, in the case of mechanical coupling. For thermal coupling, the temperature jumps become smaller but still are substantial, between 500 to 1000 C. In layered spherical-shell convection, flows in the lower mantle are several times greater than the surface velocities.

Shape evolution of a core-shell spherical particle under hydrostatic pressure.

PubMed

Colin, Jérôme

2012-03-01

The morphological evolution by surface diffusion of a core-shell spherical particle has been investigated theoretically under hydrostatic pressure when the shear modulii of the core and shell are different. A linear stability analysis has demonstrated that depending on the pressure, shear modulii, and radii of both phases, the free surface of the composite particle may be unstable with respect to a shape perturbation. A stability diagram finally emphasizes that the roughness development is favored in the case of a hard shell with a soft core.

A thin-walled pressurized sphere exposed to external general corrosion and nonuniform heating

NASA Astrophysics Data System (ADS)

Sedova, Olga S.; Pronina, Yulia G.; Kuchin, Nikolai L.

2018-05-01

A thin-walled spherical shell subjected to simultaneous action of internal and external pressure, nonuniform heating and outside mechanochemical corrosion is considered. It is assumed that the shell is homogeneous, isotropic and linearly elastic. The rate of corrosion is linearly dependent on the equivalent stress, which is the sum of mechanical and temperature stress components. Paper presents a new analytical solution, which takes into account the effect of the internal and external pressure values themselves, not only their difference. At the same time, the new solution has a rather simple form as compared to the results based on the solution to the Lame problem for a thick-walled sphere under pressure. The solution obtained can serve as a benchmark for numerical analysis and for a qualitative forecast of durability of the vessel.

The theory of spherically symmetric thin shells in conformal gravity

NASA Astrophysics Data System (ADS)

Berezin, Victor; Dokuchaev, Vyacheslav; Eroshenko, Yury

The spherically symmetric thin shells are the nearest generalizations of the point-like particles. Moreover, they serve as the simple sources of the gravitational fields both in General Relativity and much more complex quadratic gravity theories. We are interested in the special and physically important case when all the quadratic in curvature tensor (Riemann tensor) and its contractions (Ricci tensor and scalar curvature) terms are present in the form of the square of Weyl tensor. By definition, the energy-momentum tensor of the thin shell is proportional to Diracs delta-function. We constructed the theory of the spherically symmetric thin shells for three types of gravitational theories with the shell: (1) General Relativity; (2) Pure conformal (Weyl) gravity where the gravitational part of the total Lagrangian is just the square of the Weyl tensor; (3) Weyl-Einstein gravity. The results are compared with these in General Relativity (Israel equations). We considered in detail the shells immersed in the vacuum. Some peculiar properties of such shells are found. In particular, for the traceless ( = massless) shell, it is shown that their dynamics cannot be derived from the matching conditions and, thus, is completely arbitrary. On the contrary, in the case of the Weyl-Einstein gravity, the trajectory of the same type of shell is completely restored even without knowledge of the outside solution.

Exchange-coupled Fe3O4/CoFe2O4 nanoparticles for advanced magnetic hyperthermia

NASA Astrophysics Data System (ADS)

Robles, J.; Das, R.; Glassell, M.; Phan, M. H.; Srikanth, H.

2018-05-01

We report a systematic study of the effects of core and shell size on the magnetic properties and heating efficiency of exchange-coupled Fe3O4/CoFe2O4 core/shell nanoparticles. The nanoparticles were synthesized using thermal decomposition of organometallic precursors. Transmission electron microscopy (TEM) confirmed the formation of spherical Fe3O4 and Fe3O4/CoFe2O4 nanoparticles. Magnetic measurements showed high saturation magnetization for the nanoparticles at room temperature. Increasing core diameter (6.4±0.7, 7.8±0.1, 9.6±1.2 nm) and/or shell thickness (˜1, 2, 4 nm) increased the coercive field (HC), while an optimal value of saturation magnetization (MS) was achieved for the Fe3O4 (7.8±0.1nm)/CoFe2O4 (2.1±0.1nm) nanoparticles. Magnetic hyperthermia measurements indicated a large increase in specific absorption rate (SAR) for 8.2±1.1 nm Fe3O4/CoFe2O4 compared to Fe3O4 nanoparticles of same size. The SAR of the Fe3O4/CoFe2O4 nanoparticles increased from 199 to 461 W/g for 800 Oe as the thickness of the CoFe2O4 shell was increased from 0.9±0.5 to 2.1±0.1 nm. The SAR enhancement is attributed to a combination of the large MS and the large HC. Therefore, these Fe3O4/CoFe2O4 core/shell nanoparticles can be a good candidate for advanced hyperthermia application.

Determination of the structure and composition of Au-Ag bimetallic spherical nanoparticles using single particle ICP-MS measurements performed with normal and high temporal resolution.

PubMed

Kéri, Albert; Kálomista, Ildikó; Ungor, Ditta; Bélteki, Ádám; Csapó, Edit; Dékány, Imre; Prohaska, Thomas; Galbács, Gábor

2018-03-01

In this study, the information that can be obtained by combining normal and high resolution single particle ICP-MS (spICP-MS) measurements for spherical bimetallic nanoparticles (BNPs) was assessed. One commercial certified core-shell Au-Ag nanoparticle and three newly synthesized and fully characterized homogenous alloy Au-Ag nanoparticle batches of different composition were used in the experiments as BNP samples. By scrutinizing the high resolution spICP-MS signal time profiles, it was revealed that the width of the signal peak linearly correlates with the diameter of nanoparticles. It was also observed that the width of the peak for same-size nanoparticles is always significantly larger for Au than for Ag. It was also found that it can be reliably determined whether a BNP is of homogeneus alloy or core-shell structure and that, in the case of the latter, the core comprises of which element. We also assessed the performance of several ICP-MS based analytical methods in the analysis of the quantitative composition of bimetallic nanoparticles. Out of the three methods (normal resolution spICP-MS, direct NP nebulization with solution-mode ICP-MS, and solution-mode ICP-MS after the acid dissolution of the nanoparticles), the best accuracy and precision was achieved by spICP-MS. This method allows the determination of the composition with less than 10% relative inaccuracy and better than 3% precision. The analysis is fast and only requires the usual standard colloids for size calibration. Combining the results from both quantitative and structural analyses, the core diameter and shell thickness of core-shell particles can also be calculated. Copyright © 2017 Elsevier B.V. All rights reserved.

Calculation of Thermally-Induced Displacements in Spherically Domed Ion Engine Grids

NASA Technical Reports Server (NTRS)

Soulas, George C.

2006-01-01

An analytical method for predicting the thermally-induced normal and tangential displacements of spherically domed ion optics grids under an axisymmetric thermal loading is presented. A fixed edge support that could be thermally expanded is used for this analysis. Equations for the displacements both normal and tangential to the surface of the spherical shell are derived. A simplified equation for the displacement at the center of the spherical dome is also derived. The effects of plate perforation on displacements and stresses are determined by modeling the perforated plate as an equivalent solid plate with modified, or effective, material properties. Analytical model results are compared to the results from a finite element model. For the solid shell, comparisons showed that the analytical model produces results that closely match the finite element model results. The simplified equation for the normal displacement of the spherical dome center is also found to accurately predict this displacement. For the perforated shells, the analytical solution and simplified equation produce accurate results for materials with low thermal expansion coefficients.

Nuclear Structure of 186Re

DTIC Science & Technology

2016-12-24

D population-depopulation . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 101 AME Atomic Mass Evaluation...this mass region are important for validating models of nuclear structure and reactions. The ENSDF feeds a specific data library relevant to nuclear...spherically asymmetric. Spherical asymmetry is common for nuclei between shell closures, such as those in the mid-shell 150  A  190 mass range of interest

Fluorescent nanodiamonds embedded in biocompatible translucent shells.

PubMed

Rehor, Ivan; Slegerova, Jitka; Kucka, Jan; Proks, Vladimir; Petrakova, Vladimira; Adam, Marie-Pierre; Treussart, François; Turner, Stuart; Bals, Sara; Sacha, Pavel; Ledvina, Miroslav; Wen, Amy M; Steinmetz, Nicole F; Cigler, Petr

2014-03-26

High pressure high temperature (HPHT) nanodiamonds (NDs) represent extremely promising materials for construction of fluorescent nanoprobes and nanosensors. However, some properties of bare NDs limit their direct use in these applications: they precipitate in biological solutions, only a limited set of bio-orthogonal conjugation techniques is available and the accessible material is greatly polydisperse in shape. In this work, we encapsulate bright 30-nm fluorescent nanodiamonds (FNDs) in 10-20-nm thick translucent (i.e., not altering FND fluorescence) silica shells, yielding monodisperse near-spherical particles of mean diameter 66 nm. High yield modification of the shells with PEG chains stabilizes the particles in ionic solutions, making them applicable in biological environments. We further modify the opposite ends of PEG chains with fluorescent dyes or vectoring peptide using click chemistry. High conversion of this bio-orthogonal coupling yielded circa 2000 dye or peptide molecules on a single FND. We demonstrate the superior properties of these particles by in vitro interaction with human prostate cancer cells: while bare nanodiamonds strongly aggregate in the buffer and adsorb onto the cell membrane, the shell encapsulated NDs do not adsorb nonspecifically and they penetrate inside the cells. © 2014 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

Fluorescent Nanodiamonds Embedded in Biocompatible Translucent Shells

PubMed Central

Rehor, Ivan; Slegerova, Jitka; Kucka, Jan; Proks, Vladimir; Petrakova, Vladimira; Adam, Marie-Pierre; Treussart, François; Turner, Stuart; Bals, Sara; Sacha, Pavel; Ledvina, Miroslav; Wen, Amy M.; Steinmetz, Nicole F.; Cigler, Petr

2016-01-01

High pressure high temperature (HPHT) nanodiamonds (NDs) represent extremely promising materials for construction of fluorescent nanoprobes and nanosensors. However, some properties of bare NDs limit their direct use in these applications: they precipitate in biological solutions, only a limited set of bio-orthogonal conjugation techniques is available and the accessible material is greatly polydisperse in shape. In this work, we encapsulate bright 30-nm fluorescent nanodiamonds (FNDs) in 10–20-nm thick translucent (i.e., not altering FND fluorescence) silica shells, yielding monodisperse near-spherical particles of mean diameter 66 nm. High yield modification of the shells with PEG chains stabilizes the particles in ionic solutions, making them applicable in biological environments. We further modify the opposite ends of PEG chains with fluorescent dyes or vectoring peptide using click chemistry. High conversion of this bio-orthogonal coupling yielded circa 2000 dye or peptide molecules on a single FND. We demonstrate the superior properties of these particles by in vitro interaction with human prostate cancer cells: while bare nanodiamonds strongly aggregate in the buffer and adsorb onto the cell membrane, the shell encapsulated NDs do not adsorb nonspecifically and they penetrate inside the cells. PMID:24500945

Vibration of Shells

NASA Technical Reports Server (NTRS)

Leissa, A. W.

1973-01-01

The vibrational characteristics and mechanical properties of shell structures are discussed. The subjects presented are: (1) fundamental equations of thin shell theory, (2) characteristics of thin circular cylindrical shells, (3) complicating effects in circular cylindrical shells, (4) noncircular cylindrical shell properties, (5) characteristics of spherical shells, and (6) solution of three-dimensional equations of motion for cylinders.

Theory of morphological transformation of viral capsid shell during the maturation process in the HK97 bacteriophage and similar viruses

NASA Astrophysics Data System (ADS)

Konevtsova, O. V.; Lorman, V. L.; Rochal, S. B.

2016-05-01

We consider the symmetry and physical origin of collective displacement modes playing a crucial role in the morphological transformation during the maturation of the HK97 bacteriophage and similar viruses. It is shown that the experimentally observed hexamer deformation and pentamer twist in the HK97 procapsid correspond to the simplest irreducible shear strain mode of a spherical shell. We also show that the icosahedral faceting of the bacteriophage capsid shell is driven by the simplest irreducible radial displacement field. The shear field has the rotational icosahedral symmetry group I while the radial field has the full icosahedral symmetry Ih. This difference makes their actions independent. The radial field sign discriminates between the icosahedral and the dodecahedral shapes of the faceted capsid shell, thus making the approach relevant not only for the HK97-like viruses but also for the parvovirus family. In the frame of the Landau-Ginzburg formalism we propose a simple phenomenological model valid for the first reversible step of the HK97 maturation process. The calculated phase diagram illustrates the discontinuous character of the virus shape transformation. The characteristics of the virus shell faceting and expansion obtained in the in vitro and in vivo experiments are related to the decrease in the capsid shell thickness and to the increase of the internal capsid pressure.

Enhanced oxidation stability of quasi core-shell alloyed CdSeS quantum dots prepared through aqueous microwave synthesis technique.

PubMed

Zhan, Hong-Ju; Zhou, Pei-Jiang; Ma, Rong; Liu, Xi-Jing; He, Yu-Ning; Zhou, Chuan-Yun

2014-01-01

Quasi core shell alloyed CdSeS quantum dots (QDs) have been prepared through a facile aqueous-phase route employing microwave irradiation technique. The optical spectroscopy and structure characterization evidenced the quasi core shell alloyed structures of CdSeS QDs. The X-ray diffraction patterns of the obtained CdSeS QDs displayed peak positions very close to those of bulk cubic CdS crystal structures and the result of X-ray photoelectron spectroscopy data re-confirmed the thick CdS shell on the CdSe core. The TEM images and HRTEM images of the CdSeS QDs ascertained the well-defined spherical particles and a relatively narrow size distribution. On the basis, the stability of the obtained QDs in an oxidative environment was also discussed using etching reaction by H2O2. The experiments result showed the as-prepared QDs present high tolerance towards H2O2, obviously superior to the commonly used CdTe QDs and core-shell CdTe/CdS QDs, which was attributed to the unique quasi core-shell CdSeS crystal structure and the small lattice mismatch between CdSe and CdS semiconductor materials. This assay provided insight to obtain high stable crystal structured semiconductor nanocrystals in the design and synthesis process.

Transient Temperature Analysis in a System of Thin Shells Combined with Convective and Radiative Cooling

NASA Astrophysics Data System (ADS)

Prasad, Ravindra; Samria, N. K.

1989-01-01

The problem considered has applications in the transient thermal analysis and time for attaining the steady state of the cylinder wall and cylinder head of an air-cooled internal-combustion engine. Numerical calculations based on finite difference approximations are carried out to assess the thermal response in a system of thin cylindrical and spherical shells having hot gases inside with convective boundary conditions. The outside surface is exposed to cooling medium where it looses heat by natural convection and radiation. As a special case, when radius is large, the surface may be considered to be a plane wall. The cylinder cover and cylinder wall of an internal-combustion engine are considered to be a plane wall for a comparatively higher ratio of cylinder diameter to the thickness of the wall, i.e., whend/δ varies from 80 to 100. A plot of temperature-time history and heat flow rates have been obtained.

Functional buckling behavior of silicone rubber shells for biomedical use.

PubMed

van der Houwen, E B; Kuiper, L H; Burgerhof, J G M; van der Laan, B F A M; Verkerke, G J

2013-12-01

The use of soft elastic biomaterials in medical devices enables substantial function integration. The consequent increased simplification in design can improve reliability at a lower cost in comparison to traditional (hard) biomaterials. Functional bi-stable buckling is one of the many new mechanisms made possible by soft materials. The buckling behavior of shells, however, is typically described from a structural failure point of view: the collapse of arches or rupture of steam vessels, for example. There is little or no literature about the functional elastic buckling of small-sized silicone rubber shells, and it is unknown whether or not theory can predict their behavior. Is functional buckling possible within the scale, material and pressure normally associated with physiological applications? An automatic speech valve is used as an example application. Silicone rubber spherical shells (diameter 30mm) with hinged and double-hinged boundaries were subjected to air pressure loading. Twelve different geometrical configurations were tested for buckling and reverse buckling pressures. Data were compared with the theory. Buckling pressure increases linearly with shell thickness and shell height. Reverse buckling shows these same relations, with pressures always below normal buckling pressure. Secondary hinges change normal/reverse buckling pressure ratios and promote symmetrical buckling. All tested configurations buckled within or closely around physiological pressures. Functional bi-stable buckling of silicone rubber shells is possible with adjustable properties in the physiological pressure range. Results can be predicted using the proposed relations and equations. Copyright © 2013 Elsevier Ltd. All rights reserved.

Dendronization-induced phase-transfer, stabilization and self-assembly of large colloidal Au nanoparticles

NASA Astrophysics Data System (ADS)

Malassis, Ludivine; Jishkariani, Davit; Murray, Christopher B.; Donnio, Bertrand

2016-07-01

The phase-transfer of CTAB-coated aqueous, spherical gold nanoparticles, with metallic core diameters ranging from ca. 27 to 54 nm, into organic solvents by exchanging the primitive polar bilayer with lipophilic, disulfide dendritic ligands is reported. The presence of such a thick nonpolar organic shell around these large nanoparticles enhances their stabilization against aggregation, in addition to enabling their transfer into a variety of solvents such as chloroform, toluene or tetrahydrofuran. Upon the slow evaporation of a chloroform suspension deposited on a solid support, the dendronized hybrids were found to self-assemble into ring structures of various diameters. Moreover, their self-assembly at the liquid-air interface affords the formation of fairly long-range ordered monolayers, over large areas, that can then be entirely transferred onto solid substrates.The phase-transfer of CTAB-coated aqueous, spherical gold nanoparticles, with metallic core diameters ranging from ca. 27 to 54 nm, into organic solvents by exchanging the primitive polar bilayer with lipophilic, disulfide dendritic ligands is reported. The presence of such a thick nonpolar organic shell around these large nanoparticles enhances their stabilization against aggregation, in addition to enabling their transfer into a variety of solvents such as chloroform, toluene or tetrahydrofuran. Upon the slow evaporation of a chloroform suspension deposited on a solid support, the dendronized hybrids were found to self-assemble into ring structures of various diameters. Moreover, their self-assembly at the liquid-air interface affords the formation of fairly long-range ordered monolayers, over large areas, that can then be entirely transferred onto solid substrates. Electronic supplementary information (ESI) available: TEM microscope images. See DOI: 10.1039/c6nr03404g

Cooperative effects in spherical spasers: Ab initio analytical model

NASA Astrophysics Data System (ADS)

Bordo, V. G.

2017-06-01

A fully analytical semiclassical theory of cooperative optical processes which occur in an ensemble of molecules embedded in a spherical core-shell nanoparticle is developed from first principles. Both the plasmonic Dicke effect and spaser generation are investigated for the designs in which a shell/core contains an arbitrarily large number of active molecules in the vicinity of a metallic core/shell. An essential aspect of the theory is an ab initio account of the feedback from the core/shell boundaries which significantly modifies the molecular dynamics. The theory provides rigorous, albeit simple and physically transparent, criteria for both plasmonic superradiance and surface plasmon generation.

Metal shell technology based upon hollow jet instability. [for inertial confinement fusion

NASA Technical Reports Server (NTRS)

Kendall, J. M.; Lee, M. C.; Wang, T. G.

1982-01-01

Spherical shells of submillimeter size are sought as ICF targets. Such shells must be dimensionally precise, smooth, of high strength, and composed of a high atomic number material. A technology for the production of shells based upon the hydrodynamic instability of an annular jet of molten metal is described. Shells in the 0.7-2.0 mm size range have been produced using tin as a test material. Specimens exhibit good sphericity, fair concentricity, and excellent finish over most of the surface. Work involving a gold-lead-antimony alloy is in progress. Droplets of this are amorphous and possess superior surface finish. The flow of tin models that of the alloy well; experiments on both metals show that the technique holds considerable promise.

On the shape and orientation control of an orbiting shallow spherical shell structure

NASA Technical Reports Server (NTRS)

Bainum, P. M.; Reddy, A. S. S. R.

1982-01-01

The dynamics of orbiting shallow flexible spherical shell structures under the influence of control actuators was studied. Control laws are developed to provide both attitude and shape control of the structure. The elastic modal frequencies for the fundamental and lower modes are closely grouped due to the effect of the shell curvature. The shell is gravity stabilized by a spring loaded dumbbell type damper attached at its apex. Control laws are developed based on the pole clustering techniques. Savings in fuel consumption can be realized by using the hybrid shell dumbbell system together with point actuators. It is indicated that instability may result by not including the orbital and first order gravity gradient effects in the plant prior to control law design.

A compact dust shell in the symbiotic system HM Sagittae

NASA Astrophysics Data System (ADS)

Sacuto, S.; Chesneau, O.; Vannier, M.; Cruzalèbes, P.

2007-04-01

Aims:We present high spatial resolution observations of the mid-infrared core of the dusty symbiotic system HM Sge. Methods: The MIDI interferometer was used with the VLT Unit Telescopes and Auxiliary Telescopes providing baselines oriented from PA = 42° to 105°. The MIDI visibilities are compared with the ones predicted in the frame of various spherical dust shells published in the literature involving single or double dusty shells intended to account for the influence of the hot White Dwarf. Results: The mid-IR environment is unresolved by a 8 m telescope (resolution ~ 300 mas) and the MIDI spectrum exhibits a level similar to the ISO spectra recorded 10 yr ago. The estimated Gaussian Half Width at Half Maximum of the shell of 7.8±1.3 mas (12 AU, assuming a distance of 1.5 kpc) in the 8-9 μm range, and 11.9±1.3 mas (18 AU) in the 11-12 μm range, are much smaller than the angular separation between the Mira and the White Dwarf of 40 mas (60 AU). The discrepancies between the HWHM at different angle orientations suggest an increasing level of asymmetry from 13 to 8 μm. The observations are surprisingly well fitted by the densest (optically thick in the N band) and smallest spherical model published in the literature based on the ISO data, although such a model does not account for the variations of near-IR photometry due to the Mira pulsation cycle suggesting a much smaller optical thickness. These observations also discard the two shells models, developed in an attempt to take into account the effect of the White Dwarf illumination onto the dusty wind of the Mira. These models are too extended, and lead to a level of asymmetry of the dusty environment tightly constrained by the MIDI visibilities. These observations show that a high rate of dust formation is occurring in the vicinity of the Mira which seems to be not highly perturbed by the hot companion. Based on observations made with the Very Large Telescope Interferometer at Paranal Observatory under programs 075.D-0484 and 077.D-0216. Visibility ans differential phase data are only available in electronic form at the CDS via anonymous ftp to cdsarc.u-strasbg.fr (130.79.128.5) or via http://cdsweb.u-strasbg.fr/cgi-bin/qcat?J/A+A/465/469 Appendices are only available in electronic form at http://www.aanda.org

Impact Crater Morphology and the Structure of Europa's Ice Shell

NASA Astrophysics Data System (ADS)

Silber, Elizabeth A.; Johnson, Brandon C.

2017-12-01

We performed numerical simulations of impact crater formation on Europa to infer the thickness and structure of its ice shell. The simulations were performed using iSALE to test both the conductive ice shell over ocean and the conductive lid over warm convective ice scenarios for a variety of conditions. The modeled crater depth-diameter is strongly dependent on the thermal gradient and temperature of the warm convective ice. Our results indicate that both a fully conductive (thin) shell and a conductive-convective (thick) shell can reproduce the observed crater depth-diameter and morphologies. For the conductive ice shell over ocean, the best fit is an approximately 8 km thick conductive ice shell. Depending on the temperature (255-265 K) and therefore strength of warm convective ice, the thickness of the conductive ice lid is estimated at 5-7 km. If central features within the crater, such as pits and domes, form during crater collapse, our simulations are in better agreement with the fully conductive shell (thin shell). If central features form well after the impact, however, our simulations suggest that a conductive-convective shell (thick shell) is more likely. Although our study does not provide a firm conclusion regarding the thickness of Europa's ice shell, our work indicates that Valhalla class multiring basins on Europa may provide robust constraints on the thickness of Europa's ice shell.

Time-frequency analysis of the bistatic acoustic scattering from a spherical elastic shell.

PubMed

Anderson, Shaun D; Sabra, Karim G; Zakharia, Manell E; Sessarego, Jean-Pierre

2012-01-01

The development of low-frequency sonar systems, using, for instance, a network of autonomous systems in unmanned vehicles, provides a practical means for bistatic measurements (i.e., when the source and receiver are widely separated) allowing for multiple viewpoints of the target of interest. Time-frequency analysis, in particular, Wigner-Ville analysis, takes advantage of the evolution time dependent aspect of the echo spectrum to differentiate a man-made target, such as an elastic spherical shell, from a natural object of the similar shape. A key energetic feature of fluid-loaded and thin spherical shell is the coincidence pattern, also referred to as the mid-frequency enhancement (MFE), that results from antisymmetric Lamb-waves propagating around the circumference of the shell. This article investigates numerically the bistatic variations of the MFE with respect to the monostatic configuration using the Wigner-Ville analysis. The observed time-frequency shifts of the MFE are modeled using a previously derived quantitative ray theory by Zhang et al. [J. Acoust. Soc. Am. 91, 1862-1874 (1993)] for spherical shell's scattering. Additionally, the advantage of an optimal array beamformer, based on joint time delays and frequency shifts is illustrated for enhancing the detection of the MFE recorded across a bistatic receiver array when compared to a conventional time-delay beamformer. © 2012 Acoustical Society of America.

Interplay of spherical closed shells and N /Z asymmetry in quasifission dynamics

NASA Astrophysics Data System (ADS)

Mohanto, G.; Hinde, D. J.; Banerjee, K.; Dasgupta, M.; Jeung, D. Y.; Simenel, C.; Simpson, E. C.; Wakhle, A.; Williams, E.; Carter, I. P.; Cook, K. J.; Luong, D. H.; Palshetkar, C. S.; Rafferty, D. C.

2018-05-01

Background: Quasifission (QF) has gained tremendous importance in heavy-ion nuclear physics research because of its strong influence on superheavy-element synthesis. Collisions involving closed-shell nuclei in the entrance channel are found to affect the QF reaction mechanism. Hence, it is important to improve the understanding of their effect on QF. Apart from that, some recent studies show that the difference in N /Z of reaction partners influences the reaction dynamics. Since heavier doubly magic nuclei have different N /Z than lighter doubly magic nuclei, it is important to understand the effect of N /Z mismatch as well as the effect of shell closures. Purpose: To investigate the effect of entrance-channel shell closures and N /Z asymmetry on QF. The reactions were chosen to decouple these effects from the contributions of other entrance-channel parameters. Method: Fission fragment mass-angle distributions were measured using the CUBE fission spectrometer, consisting of two large area position-sensitive multi-wire proportional counters (MWPCs), for five reactions, namely, 50Cr+208Pb , 52Cr+Pb,208206 , 54Cr+Pb,208204 . Result: Two components were observed in the measured fragment mass angle distribution, a fast mass-asymmetric quasifission and a slow mass-symmetric component having a less significant mass-angle correlation. The ratio of these components was found to depend on spherical closed shells in the entrance channel nuclei and the magnitude of the N /Z mismatch between the two reaction partners, as well as the beam energy. Conclusions: Entrance-channel spherical closed shells can enhance compound nucleus formation provided the N /Z asymmetry is small. Increase in the N /Z asymmetry is expected to destroy the effect of entrance-channel spherical closed shells, through nucleon transfer reactions.

An Explosive Bomb-Inspired Method to Prepare Collapsed and Ruptured Fe2 O3 /Nitrogen-Doped Carbon Capsules as Catalyst Support.

PubMed

Wu, Jie; Zhang, Hui; Feng, Yan; Zhang, Xiao; Yao, Tongjie; Lian, Yongfu

2017-12-01

Compared with integrated capsules, ruptured ones have better mass diffusion and transport properties due to large gaps in the shells. However, most studies focus on integrated capsules, whereas little attention has been paid to the ruptured counterparts. Herein, an explosive bomb-inspired method was employed to prepare collapsed and ruptured Fe 2 O 3 /nitrogen-doped carbon (CR-Fe 2 O 3 /NC) capsules by using polystyrene (PS) nanoparticles (NPs) as a hard template, and polypyrrole (PPy) with embedded Prussian blue (PB) NPs as the shell. During pyrolysis, PB is converted into Fe 2 O 3 , and PPy is carbonized to form NC. Importantly, the PS core decomposes into gas molecules, leading to high pressure inside of the capsule, which explodes the thin shell into pieces. The roles of shell thickness and amount of Fe 2 O 3 on determining the spherical or collapsed, and integrated or ruptured morphology were revealed. Taking advantage of structural merits, including large gaps, thin shells, low density, and high surface area, CR-Fe 2 O 3 /NC capsules were used as supports for Pd NPs. These capsules exhibited better catalytic activity than that of integrated ones. Due to the magnetic properties, they could be reused at least five times. © 2017 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.

OWL: A code for the two-center shell model with spherical Woods-Saxon potentials

NASA Astrophysics Data System (ADS)

Diaz-Torres, Alexis

2018-03-01

A Fortran-90 code for solving the two-center nuclear shell model problem is presented. The model is based on two spherical Woods-Saxon potentials and the potential separable expansion method. It describes the single-particle motion in low-energy nuclear collisions, and is useful for characterizing a broad range of phenomena from fusion to nuclear molecular structures.

A statistical spatial power spectrum of the Earth's lithospheric magnetic field

NASA Astrophysics Data System (ADS)

Thébault, E.; Vervelidou, F.

2015-05-01

The magnetic field of the Earth's lithosphere arises from rock magnetization contrasts that were shaped over geological times. The field can be described mathematically in spherical harmonics or with distributions of magnetization. We exploit this dual representation and assume that the lithospheric field is induced by spatially varying susceptibility values within a shell of constant thickness. By introducing a statistical assumption about the power spectrum of the susceptibility, we then derive a statistical expression for the spatial power spectrum of the crustal magnetic field for the spatial scales ranging from 60 to 2500 km. This expression depends on the mean induced magnetization, the thickness of the shell, and a power law exponent for the power spectrum of the susceptibility. We test the relevance of this form with a misfit analysis to the observational NGDC-720 lithospheric magnetic field model power spectrum. This allows us to estimate a mean global apparent induced magnetization value between 0.3 and 0.6 A m-1, a mean magnetic crustal thickness value between 23 and 30 km, and a root mean square for the field value between 190 and 205 nT at 95 per cent. These estimates are in good agreement with independent models of the crustal magnetization and of the seismic crustal thickness. We carry out the same analysis in the continental and oceanic domains separately. We complement the misfit analyses with a Kolmogorov-Smirnov goodness-of-fit test and we conclude that the observed power spectrum can be each time a sample of the statistical one.

Structural analysis of Fe–Mn–O nanoparticles in glass ceramics by small angle scattering

DOE Office of Scientific and Technical Information (OSTI.GOV)

Raghuwanshi, Vikram Singh, E-mail: vikram.raghuwanshi@helmholtz-berlin.de; Harizanova, Ruzha; Tatchev, Dragomir

2015-02-15

Magnetic nanocrystals containing Fe and Mn were obtained by annealing of silicate glasses with the composition 13.6Na{sub 2}O–62.9SiO{sub 2}–8.5MnO–15.0Fe{sub 2}O{sub 3−x} (mol%) at 580 °C for different periods of time. Here, we present Small Angle Neutron Scattering using Polarized neutrons (SANSPOL) and Anomalous Small Angle X-ray Scattering (ASAXS) investigation on these glass ceramic samples. Analysis of scattering data from both methods reveals the formation of spherical core–shell type of nanoparticles with mean sizes between 10 nm and 100 nm. ASAXS investigation shows the particles have higher concentration of iron atoms and the shell like region surrounding the particles is enrichedmore » in SiO{sub 2}. SANSPOL investigation shows the particles are found to be magnetic and are surrounded by a non-magnetic shell-like region. - Graphical abstract: Magnetic spherical core–shell nanoparticles in glass ceramics: SANSPOL and ASAXS investigations. - Highlights: • Formation and growth mechanisms of magnetic nanoparticles in silicate glass. • SANSPOL and ASAXS methods employed to evaluate quantitative information. • Analyses showed formation of nanoparticles with spherical core–shell structures. • Core of the particle is magnetic and surrounded by weak magnetic shell like region.« less

Shell Layer Thickness-Dependent Photocatalytic Activity of Sputtering Synthesized Hexagonally Structured ZnO-ZnS Composite Nanorods

PubMed Central

Liang, Yuan-Chang; Lo, Ya-Ru; Wang, Chein-Chung; Xu, Nian-Cih

2018-01-01

ZnO-ZnS core-shell nanorods are synthesized by combining the hydrothermal method and vacuum sputtering. The core-shell nanorods with variable ZnS shell thickness (7–46 nm) are synthesized by varying ZnS sputtering duration. Structural analyses demonstrated that the as-grown ZnS shell layers are well crystallized with preferring growth direction of ZnS (002). The sputtering-assisted synthesized ZnO-ZnS core-shell nanorods are in a wurtzite structure. Moreover, photoluminance spectral analysis indicated that the introduction of a ZnS shell layer improved the photoexcited electron and hole separation efficiency of the ZnO nanorods. A strong correlation between effective charge separation and the shell thickness aids the photocatalytic behavior of the nanorods and improves their photoresponsive nature. The results of comparative degradation efficiency toward methylene blue showed that the ZnO-ZnS nanorods with the shell thickness of approximately 17 nm have the highest photocatalytic performance than the ZnO-ZnS nanorods with other shell layer thicknesses. The highly reusable catalytic efficiency and superior photocatalytic performance of the ZnO-ZnS nanorods with 17 nm-thick ZnS shell layer supports their potential for environmental applications. PMID:29316671

A novel embeddable spherical smart aggregate for structural health monitoring: part I. Fabrication and electrical characterization

NASA Astrophysics Data System (ADS)

Kong, Qingzhao; Fan, Shuli; Bai, Xiaolong; Mo, Y. L.; Song, Gangbing

2017-09-01

Recently developed piezoceramic-based transducers, known as smart aggregates (SAs), have shown their applicability and versatility in various applications of structural health monitoring (SHM). The lead zirconate titanate (PZT) patches embedded inside SAs have different modes that are more suitable for generating or receiving different types of stress waves (e.g. P and S waves, each of which has a unique role in SHM). However, due to the geometry of the 2D PZT patch, the embedded SA can only generate or receive the stress wave in a single direction and thus greatly limits its applications. This paper is the first of a series of two companion papers that introduces the authors’ latest work in developing a novel, embeddable spherical smart aggregate (SSA) for the health monitoring of concrete structures. In addition to the 1D guided wave produced by SA, the SSA embedded in concrete structures can generate or receive omni-directional stress waves that can significantly improve the detection aperture and provide additional functionalities in SHM. In the first paper (Part I), the detailed fabrication procedures with the help of 3D printing technology and electrical characterization of the proposed SSA is presented. The natural frequencies of the SSA were experimentally obtained and further compared with the numerical results. In addition, the influence of the components’ thickness (spherical piezoceramic shell and epoxy) and outer radius (spherical piezoceramic shell and protection concrete) on the natural frequencies of the SSA were analytically studied. The results will help elucidate the key parameters that determine the natural frequencies of the SSA. The natural frequencies of the SSA can thus be designed for suitability in the damage detection of concrete structures. In the second paper (Part II), further numerical and experimental verifications on the performance of the proposed SSA in concrete structures will be discussed.

Polaronic effects on the off-center donor impurity in AlAs/GaAs/SiO2 spherical core/shell quantum dots

NASA Astrophysics Data System (ADS)

El Haouari, M.; Feddi, E.; Dujardin, F.; Restrepo, R. L.; Mora-Ramos, M. E.; Duque, C. A.

2017-11-01

The ground state of a conduction electron coupled to an off-center impurity donor in a AlAS/GaAs spherical core/shell quantum dot is investigated theoretically. The image-charge effect and the influence of the electron-polar-LO-phonon interaction are considered. The electron-impurity binding energy is calculated via a variational procedure and is reported both as a function of the shell width and of the radial position of the donor atom. The polaronic effects on this quantity are particularly discussed.

Family of spherical models with special gravitational properties

NASA Astrophysics Data System (ADS)

Kondratyev, B. P.

2015-03-01

A new method for studying the structural and gravitational properties of spherical systems based on an analysis of the ratio of the potentials for their subsystems and shells has been developed. It has been proven for the first time that the gravitational virial Z( r) of the subsystem without allowance for the influence of the outer shell is equal to twice the work done to disperce the subsystem's matter to infinity. A new class of spherical models has been constructed in which: (1) the ratio of the contribution to the potential at point r from the spherical subsystem to the contribution from the outer shell does not depend on radius and is equal to a constant γ; (2) the ratio of the gravitational energy W( r) to Z( r) for the spherical subsystem does not depend on r; and (3) the models are described by a power law of the density ρ = cr - κ and potential . Expressions for the gravitational energy W( r) and virial Z( r) have been found for the subsystem. The limiting case of ρ( r) ∝ r -5/2, where the subsystem's potential at any sampling point is exactly equal to the potential from the outer shell and Z( r) is equivalent to its gravitational energy W( r), is considered in detail. The results supplement the classical potential theory. The question about the application of the models to the superdense nuclear star cluster in the center of the Milky Way is discussed.

Early post-mortem formation of carbonate concretions around tusk-shells over week-month timescales

NASA Astrophysics Data System (ADS)

Yoshida, Hidekazu; Ujihara, Atsushi; Minami, Masayo; Asahara, Yoshihiro; Katsuta, Nagayoshi; Yamamoto, Koshi; Sirono, Sin-Iti; Maruyama, Ippei; Nishimoto, Shoji; Metcalfe, Richard

2015-09-01

Carbonate concretions occur in sedimentary rocks of widely varying geological ages throughout the world. Many of these concretions are isolated spheres, centered on fossils. The formation of such concretions has been variously explained by diffusion of inorganic carbon and organic matter in buried marine sediments. However, details of the syn-depositional chemical processes by which the isolated spherical shape developed and the associated carbon sources are little known. Here we present evidence that spherical carbonate concretions (diameters φ : 14 ~ 37 mm) around tusk-shells (Fissidentalium spp.) were formed within weeks or months following death of the organism by the seepage of fatty acid from decaying soft body tissues. Characteristic concentrations of carbonate around the mouth of a tusk-shell reveal very rapid formation during the decay of organic matter from the tusk-shell. Available observations and geochemical evidence have enabled us to construct a ‘Diffusion-growth rate cross-plot’ that can be used to estimate the growth rate of all kinds of isolated spherical carbonate concretions identified in marine formations. Results shown here suggest that isolated spherical concretions that are not associated with fossils might also be formed from carbon sourced in the decaying soft body tissues of non-skeletal organisms with otherwise low preservation potential.

Analysis of two colliding fractionally damped spherical shells in modelling blunt human head impacts

NASA Astrophysics Data System (ADS)

Rossikhin, Yury A.; Shitikova, Marina V.

2013-06-01

The collision of two elastic or viscoelastic spherical shells is investigated as a model for the dynamic response of a human head impacted by another head or by some spherical object. Determination of the impact force that is actually being transmitted to bone will require the model for the shock interaction of the impactor and human head. This model is indended to be used in simulating crash scenarios in frontal impacts, and provide an effective tool to estimate the severity of effect on the human head and to estimate brain injury risks. The model developed here suggests that after the moment of impact quasi-longitudinal and quasi-transverse shock waves are generated, which then propagate along the spherical shells. The solution behind the wave fronts is constructed with the help of the theory of discontinuities. It is assumed that the viscoelastic features of the shells are exhibited only in the contact domain, while the remaining parts retain their elastic properties. In this case, the contact spot is assumed to be a plane disk with constant radius, and the viscoelastic features of the shells are described by the fractional derivative standard linear solid model. In the case under consideration, the governing differential equations are solved analytically by the Laplace transform technique. It is shown that the fractional parameter of the fractional derivative model plays very important role, since its variation allows one to take into account the age-related changes in the mechanical properties of bone.

A comparison of no-slip, stress-free and inviscid models of rapidly rotating fluid in a spherical shell

PubMed Central

Livermore, Philip W.; Bailey, Lewis M.; Hollerbach, Rainer

2016-01-01

We investigate how the choice of either no-slip or stress-free boundary conditions affects numerical models of rapidly rotating flow in Earth’s core by computing solutions of the weakly-viscous magnetostrophic equations within a spherical shell, driven by a prescribed body force. For non-axisymmetric solutions, we show that models with either choice of boundary condition have thin boundary layers of depth E1/2, where E is the Ekman number, and a free-stream flow that converges to the formally inviscid solution. At Earth-like values of viscosity, the boundary layer thickness is approximately 1 m, for either choice of condition. In contrast, the axisymmetric flows depend crucially on the choice of boundary condition, in both their structure and magnitude (either E−1/2 or E−1). These very large zonal flows arise from requiring viscosity to balance residual axisymmetric torques. We demonstrate that switching the mechanical boundary conditions can cause a distinct change of structure of the flow, including a sign-change close to the equator, even at asymptotically low viscosity. Thus implementation of stress-free boundary conditions, compared with no-slip conditions, may yield qualitatively different dynamics in weakly-viscous magnetostrophic models of Earth’s core. We further show that convergence of the free-stream flow to its asymptotic structure requires E ≤ 10−5. PMID:26980289

Peculiarities of light absorption by spherical microcapsules

NASA Astrophysics Data System (ADS)

Geints, Yurii E.; Panina, Ekaterina K.; Zemlyanov, Alexander A.

2018-04-01

Optical radiation absorption in the poly-layer spherical microparticles simulating the inorganic/organic polyshell absorbing microcapsules is considered. With the aim of the finite-difference time-domain technique, the spatial distribution of the absorbed light power in microcapsules of various sizes and internal structure is numerically calculated. For the purpose of light absorption enhancement, we have engineered the optimal structure of a capsule consisting of a strong-refracting transparent outer coating and an absorbing layer which covers a liquid core. The proposed microcapsule prototype provides for a manifold increase in the absorbed light power density in comparison with the usual single-layer absorbing capsule. We show that for light-wavelengths-scaled microcapsules it is optimal to use a material with the refractive index larger than two as an outer shell, for example, titanium dioxide (TiO2). The highest values of the absorbed power density can be obtained in microcapsules with absorbing shell thickness of approximately a tenth of a laser wavelength. When laser radiation is scattered by a dimer constituted by two identical absorbing microcapsules the absorbed power density can be maximized by the choosing of proper dimer spatial configuration. In the case of strongly absorbing particles, the absorption maximum corresponds to a shift of the capsules to a distance of about their diameter, and in the case of weakly absorbing particles the absorption is maximal when particles are in geometrical shades of each other.

Nuclear mass formula with the shell energies obtained by a new method

DOE Office of Scientific and Technical Information (OSTI.GOV)

Koura, H.; Tachibana, T.; Yamada, M.

1998-12-21

Nuclear shapes and masses are estimated by a new method. The main feature of this method lies in estimating shell energies of deformed nuclei from spherical shell energies by mixing them with appropriate weights. The spherical shell energies are calculated from single-particle potentials, and, till now, two mass formulas have been constructed from two different sets of potential parameters. The standard deviation of the calculated masses from all the experimental masses of the 1995 Mass Evaluation is about 760 keV. Contrary to the mass formula by Tachibana, Uno, Yamada and Yamada in the 1987-1988 Atomic Mass Predictions, the present formulasmore » can give nuclear shapes and predict on super-heavy elements.« less

Ion beam inertial confinement target

DOEpatents

Bangerter, Roger O.; Meeker, Donald J.

1985-01-01

A target for implosion by ion beams composed of a spherical shell of frozen DT surrounded by a low-density, low-Z pusher shell seeded with high-Z material, and a high-density tamper shell. The target has various applications in the inertial confinement technology. For certain applications, if desired, a low-density absorber shell may be positioned intermediate the pusher and tamper shells.

Synthesis of carbon-coated Na2MnPO4F hollow spheres as a potential cathode material for Na-ion batteries

NASA Astrophysics Data System (ADS)

Wu, Ling; Hu, Yong; Zhang, Xiaoping; Liu, Jiequn; Zhu, Xing; Zhong, Shengkui

2018-01-01

Hollow sphere structure Na2MnPO4F/C composite is synthesized through spray drying, following in-situ pyrolytic carbon coating process. XRD results indicate that the well crystallized composite can be successfully synthesized, and no other impurity phases are detected. SEM and TEM results reveal that the Na2MnPO4F/C samples show intact hollow spherical architecture, and the hollow spherical shells with an average thickness of 150 nm-250 nm are composed of nanosized primary particles. Furthermore, the amorphous carbon layer is uniformly coated on the surface of the hollow sphere, and the nanosized Na2MnPO4F particles are well embedded in the carbon networks. Consequently, the hollow sphere structure Na2MnPO4F/C shows enhanced electrochemical performance. Especially, it is the first time that the obvious potential platforms (∼3.6 V) are observed during the charge and discharge process at room temperature.

Microstructure and Thermal Reliability of Microcapsules Containing Phase Change Material with Self-Assembled Graphene/Organic Nano-Hybrid Shells.

PubMed

Wang, Xianfeng; Guo, Yandong; Su, Junfeng; Zhang, Xiaolong; Han, Ningxu; Wang, Xinyu

2018-05-24

In recent decades, microcapsules containing phase change materials (microPCMs) have been the center of much attention in the field of latent thermal energy storage. The aim of this work was to prepare and investigate the microstructure and thermal conductivity of microPCMs containing self-assembled graphene/organic hybrid shells. Paraffin was used as a phase change material, which was successfully microencapsulated by graphene and polymer forming hybrid composite shells. The physicochemical characters of microPCM samples were investigated including mean size, shell thickness, and chemical structure. Scanning electron microscope (SEM) results showed that the microPCMs were spherical particles and graphene enhanced the degree of smoothness of the shell surface. The existence of graphene in the shells was proved by using the methods of X-ray photoelectron spectroscopy (XPS), transmission electron microscopy (TEM), and atomic force microscopy (AFM). It was found that graphene hybrid shells were constructed by forces of electric charge absorption and long-molecular entanglement. MicroPCMs with graphene had a higher degradation temperature of 300 °C. Graphene greatly enhanced the thermal stability of microPCMs. The thermal conductivity tests indicated that the phase change temperature of microPCMs was regulated by the graphene additive because of enhancement of the thermal barrier of the hybrid shells. Differential scanning calorimetry (DSC) tests proved that the latent thermal energy capability of microPCMs had been improved with a higher heat conduction rate. In addition, infrared thermograph observations implied that the microPCMs had a sensitivity response to heat during the phase change cycling process because of the excellent thermal conductivity of graphene.

Designing an extended energy range single-sphere multi-detector neutron spectrometer

NASA Astrophysics Data System (ADS)

Gómez-Ros, J. M.; Bedogni, R.; Moraleda, M.; Esposito, A.; Pola, A.; Introini, M. V.; Mazzitelli, G.; Quintieri, L.; Buonomo, B.

2012-06-01

This communication describes the design specifications for a neutron spectrometer consisting of 31 thermal neutron detectors, namely Dysprosium activation foils, embedded in a 25 cm diameter polyethylene sphere which includes a 1 cm thick lead shell insert that degrades the energy of neutrons through (n,xn) reactions, thus allowing to extension of the energy range of the response up to hundreds of MeV neutrons. The new spectrometer, called SP2 (SPherical SPectrometer), relies on the same detection mechanism as that of the Bonner Sphere Spectrometer, but with the advantage of determining the whole neutron spectrum in a single exposure. The Monte Carlo transport code MCNPX was used to design the spectrometer in terms of sphere diameter, number and position of the detectors, position and thickness of the lead shell, as well as to obtain the response matrix for the final configuration. This work focuses on evaluating the spectrometric capabilities of the SP2 design by simulating the exposure of SP2 in neutron fields representing different irradiation conditions (test spectra). The simulated SP2 readings were then unfolded with the FRUIT unfolding code, in the absence of detailed pre-information, and the unfolded spectra were compared with the known test spectra. The results are satisfactory and allowed approving the production of a prototypal spectrometer.

Confinement dynamics of a semiflexible chain inside nano-spheres

NASA Astrophysics Data System (ADS)

Fathizadeh, A.; Heidari, Maziar; Eslami-Mossallam, B.; Ejtehadi, M. R.

2013-07-01

We study the conformations of a semiflexible chain, confined in nano-scaled spherical cavities, under two distinct processes of confinement. Radial contraction and packaging are employed as two confining procedures. The former method is performed by gradually decreasing the diameter of a spherical shell which envelopes a confined chain. The latter procedure is carried out by injecting the chain inside a spherical shell through a hole on the shell surface. The chain is modeled with a rigid body molecular dynamics simulation and its parameters are adjusted to DNA base-pair elasticity. Directional order parameter is employed to analyze and compare the confined chain and the conformations of the chain for two different sizes of the spheres are studied in both procedures. It is shown that for the confined chains in the sphere sizes of our study, they appear in spiral or tennis-ball structures, and the tennis-ball structure is more likely to be observed in more compact confinements. Our results also show that the dynamical procedure of confinement and the rate of the confinement are influential parameters of the structure of the chain inside spherical cavities.

Static, free vibration and thermal analysis of composite plates and shells using a flat triangular shell element

NASA Astrophysics Data System (ADS)

Kapania, R. K.; Mohan, P.

1996-09-01

Finite element static, free vibration and thermal analysis of thin laminated plates and shells using a three noded triangular flat shell element is presented. The flat shell element is a combination of the Discrete Kirchhoff Theory (DKT) plate bending element and a membrane element derived from the Linear Strain Triangular (LST) element with a total of 18 degrees of freedom (3 translations and 3 rotations per node). Explicit formulations are used for the membrane, bending and membrane-bending coupling stiffness matrices and the thermal load vector. Due to a strong analogy between the induced strain caused by the thermal field and the strain induced in a structure due to an electric field the present formulation is readily applicable for the analysis of structures excited by surface bonded or embedded piezoelectric actuators. The results are presented for (i) static analysis of (a) simply supported square plates under doubly sinusoidal load and uniformly distributed load (b) simply supported spherical shells under a uniformly distributed load, (ii) free vibration analysis of (a) square cantilever plates, (b) skew cantilever plates and (c) simply supported spherical shells; (iii) Thermal deformation analysis of (a) simply supported square plates, (b) simply supported-clamped square plate and (c) simply supported spherical shells. A numerical example is also presented demonstrating the application of the present formulation to analyse a symmetrically laminated graphite/epoxy laminate excited by a layer of piezoelectric polyvinylidene flouride (PVDF). The results presented are in good agreement with those available in the literature.

Search for the Exotic Wobbling Mode in Rhenium-171

DTIC Science & Technology

2011-05-13

USB hard drive. The decay sequences mentioned above release all of their γ rays within a nanosecond (ns). Data will be recorded when multiple ...events in which multiple detectors measured γ rays within a 120 ns window. An event in which three detectors fired within the coincidence window is...spherical nuclei; however, if the nucleus is axially deformed (non-spherical), the shell model cannot accurately describe its features . The shell model

Direct Correlation of Excitonics with Efficiency in a Core-Shell Quantum Dot Solar Cell.

PubMed

Dana, Jayanta; Maiti, Sourav; Tripathi, Vaidehi S; Ghosh, Hirendra N

2018-02-16

Shell thickness dependent band-gap engineering of quasi type II core-shell material with higher carrier cooling time, lower interfacial defect states, and longer charge carrier recombination time can be a promising candidate for both photocatalysis and solar cell. In the present investigation, colloidal CdSe@CdS core-shells with different shell thickness (2, 4 and 6 monolayer CdS) were synthesized through hot injection method and have been characterized by high resolution transmission electron microscope (HRTEM) followed by steady state absorption and luminescence techniques. Ultrafast transient absorption (TA) studies suggest longer carrier cooling, lower interfacial surface states, and slower carrier recombination time in CdSe@CdS core-shell with increasing shell thickness. By TA spectroscopy, the role of CdS shell in power conversion efficiency (PCE) has been explained in detail. The measured PCE was found to initially increase and then decrease with increasing shell thickness. Shell thickness has been optimized to maximize the efficiency after correlating the shell controlled carrier cooling and recombination with PCE values and a maximum PCE of 3.88 % was obtained with 4 monolayers of CdS shell, which is found to be 57 % higher than compared to bare CdSe QDs. © 2018 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.

Measurement of the shell decompression in direct-drive inertial-confinement-fusion implosions

DOE PAGES

Michel, D. T.; Hu, S. X.; Davis, A. K.; ...

2017-05-10

Measurement of the effect of adiabat (α) on the shell thickness were performed in direct-drive implosions. When reducing the adiabat of the shell from α = 6 to α = 4:5, the shell thickness was measured to decrease from 75 μm to 60 μm, but when decreasing the adiabat further (α = 1:8), the shell thickness was measured to increase to 75 μm. The measured shell thickness, shell trajectories, neutron bang time, and neutron yield were reproduced by two dimensional simulations that include laser imprint, nonlocal thermal transport, cross-beam energy transfer, and first-principles equation-of-state models. The minimum core size wasmore » measured to decrease from 40 μm to 30 μm, consistent with the reduction of the adiabat from α = 6 to α = 1:8. Simulations that neglected imprint reproduced the measured core size of the entire adiabat scan, but signi cantly underestimate the shell thickness for adiabat below ~3. These results show that the decompression of the shell measured for low-adiabat implosions was a result of laser imprint.« less

Measurement of the shell decompression in direct-drive inertial-confinement-fusion implosions

DOE Office of Scientific and Technical Information (OSTI.GOV)

Michel, D. T.; Hu, S. X.; Davis, A. K.

Measurement of the effect of adiabat (α) on the shell thickness were performed in direct-drive implosions. When reducing the adiabat of the shell from α = 6 to α = 4:5, the shell thickness was measured to decrease from 75 μm to 60 μm, but when decreasing the adiabat further (α = 1:8), the shell thickness was measured to increase to 75 μm. The measured shell thickness, shell trajectories, neutron bang time, and neutron yield were reproduced by two dimensional simulations that include laser imprint, nonlocal thermal transport, cross-beam energy transfer, and first-principles equation-of-state models. The minimum core size wasmore » measured to decrease from 40 μm to 30 μm, consistent with the reduction of the adiabat from α = 6 to α = 1:8. Simulations that neglected imprint reproduced the measured core size of the entire adiabat scan, but signi cantly underestimate the shell thickness for adiabat below ~3. These results show that the decompression of the shell measured for low-adiabat implosions was a result of laser imprint.« less

MagIC: Fluid dynamics in a spherical shell simulator

NASA Astrophysics Data System (ADS)

Wicht, J.; Gastine, T.; Barik, A.; Putigny, B.; Yadav, R.; Duarte, L.; Dintrans, B.

2017-09-01

MagIC simulates fluid dynamics in a spherical shell. It solves for the Navier-Stokes equation including Coriolis force, optionally coupled with an induction equation for Magneto-Hydro Dynamics (MHD), a temperature (or entropy) equation and an equation for chemical composition under both the anelastic and the Boussinesq approximations. MagIC uses either Chebyshev polynomials or finite differences in the radial direction and spherical harmonic decomposition in the azimuthal and latitudinal directions. The time-stepping scheme relies on a semi-implicit Crank-Nicolson for the linear terms of the MHD equations and a Adams-Bashforth scheme for the non-linear terms and the Coriolis force.

Radiation-induced graft copolymerization of poly(ethylene glycol) monomethacrylate onto deoxycholate-chitosan nanoparticles as a drug carrier

NASA Astrophysics Data System (ADS)

Pasanphan, Wanvimol; Rattanawongwiboon, Thitirat; Rimdusit, Pakjira; Piroonpan, Thananchai

2014-01-01

Poly(ethylene glycol) monomethacrylate-grafted-deoxycholate chitosan nanoparticles (PEGMA-g-DCCSNPs) were successfully prepared by radiation-induced graft copolymerization. The hydrophilic poly(ethylene glycol) monomethacrylate was grafted onto deoxycholate-chitosan in an aqueous system. The radiation-absorbed dose is an important parameter on degree of grafting, shell thickness and particle size of PEGMA-g-DCCSNPs. Owing to their amphiphilic architecture, PEGMA-g-DCCSNPs self-assembled into spherical core-shell nanoparticles in aqueous media. The particle size of PEGMA-g-DCCSNPs measured by TEM varied in the range of 70-130 nm depending on the degree of grafting as well as the irradiation dose. Berberine (BBR) as a model drug was encapsulated into the PEGMA-g-DCCSNPs. Drug release study revealed that the BBR drug was slowly released from PEGMA-g-DCCSNPs at a mostly constant rate of 10-20% in PBS buffer (pH 7.4) at 37 °C over a period of 23 days.

Role of N-methyl-2-pyrrolidone for preparation of Fe3O4@SiO2 controlled the shell thickness

NASA Astrophysics Data System (ADS)

Wee, Sung-Bok; Oh, Hyeon-Cheol; Kim, Tae-Gyun; An, Gye-Seok; Choi, Sung-Churl

2017-04-01

We developed a simple and novel approach for the synthesis of Fe3O4@SiO2 nanoparticles with controlled shell thickness, and studied the mechanism. The introduction of N-methyl-2-pyrrolidone (NMP) led to trapping of monomer nuclei in single shell and controlled the shell thickness. Fe3O4@SiO2 controlled the shell thickness, showing a high magnetization value (64.47 emu/g). Our results reveal the role and change in the chemical structure of NMP during the core-shell synthesis process. NMP decomposed to 4-aminobutanoic acid in alkaline condition and decreased the hydrolysis rate of the silica coating process.

Double-shell CuS nanocages as advanced supercapacitor electrode materials

NASA Astrophysics Data System (ADS)

Guo, Jinxue; Zhang, Xinqun; Sun, Yanfang; Zhang, Xiaohong; Tang, Lin; Zhang, Xiao

2017-07-01

Metal sulfides hollow structures are advanced materials for energy storage applications of lithium-ion batteries and supercapacitors. However, constructing hollow metal sulfides with specific features, such as multi-shell and non-spherical shape, still remains great challenge. In this work, we firstly demonstrate the synthesis of CuS double-shell hollow nanocages using Cu2O nanocubes as precursors. The synthesis processes involve the repeated anion exchange reaction with Na2S and the controllable etching using hydrochloric acid. The whole synthesis processes are well revealed and the obtained double-shell CuS is tested as pseudocapacitive electrode material for supercapacitors. As expected, the CuS double-shell hollow nanocages deliver high specific capacitance, good rate performance and excellent cycling stability due to their unique nano-architecture. The present work contributes greatly to the exploration of hollow metal sulfides with complex architecture and non-spherical shape, as well as their promising application in high-performance electrochemical supercapacitors.

Nuclear tetrahedral symmetry: possibly present throughout the periodic table.

PubMed

Dudek, J; Goźdź, A; Schunck, N; Miśkiewicz, M

2002-06-24

More than half a century after the fundamental, spherical shell structure in nuclei had been established, theoretical predictions indicated that the shell gaps comparable or even stronger than those at spherical shapes may exist. Group-theoretical analysis supported by realistic mean-field calculations indicate that the corresponding nuclei are characterized by the TD(d) ("double-tetrahedral") symmetry group. Strong shell-gap structure is enhanced by the existence of the four-dimensional irreducible representations of TD(d); it can be seen as a geometrical effect that does not depend on a particular realization of the mean field. Possibilities of discovering the TD(d) symmetry in experiment are discussed.

Multilayer Films and Capsules of Sodium Carboxymethylcellulose and Polyhexamethylenguanidine Hydrochloride

NASA Astrophysics Data System (ADS)

Guzenko, Nataliia; Gabchak, Oleksandra; Pakhlov, Evgenij

The complexation of polyhexamethylenguanidine hydrochloride (PHMG) and sodium carboxymethylcellulose (CMC) was investigated for different conditions. Mixing of equiconcentrated aqueous solutions of the polyelectrolytes was found to result in the formation of an insoluble interpolyelectrolyte complex with an overweight of carboxymethylcellulose. A step-by-step formation of stable, irreversibly adsorbed multilayer film of the polymers was demonstrated using the quartz crystal microbalance method. Unusually thick polymer shells with a large number of loops and tails of the polyanion were formed by the method of layer-by-layer self-assembly of PHMG and CMC on spherical CaCO3 particles. Hollow multilayer capsules stable in neutral media were obtained by dissolution of the inorganic matrix in EDTA solution.

The Case of the Disappearing Magnetic Dipole

ERIC Educational Resources Information Center

Gough, W.

2008-01-01

The problem of an oscillating magnetic dipole at the centre of a lossless dielectric spherical shell is considered. For simplicity, the free-space wavelength is taken to be much greater than the shell radii, but the relative permittivity [epsilon][subscript r] of the shell is taken as much greater than unity, so the wavelength in the shell could…

Free Vibration of Fiber Composite Thin Shells in a Hot Environment

NASA Technical Reports Server (NTRS)

Gotsis, Pascal K.; Guptill, James D.

1995-01-01

Results are presented of parametric studies to assess the effects of various parameters on the free vibration behavior (natural frequencies) of (plus or minus theta)2, angle-ply fiber composite thin shells in a hot environment. These results were obtained by using a three-dimensional finite element structural analysis computer code. The fiber composite shell is assumed to be cylindrical and made from T-300 graphite fibers embedded in an intermediate-modulus high-strength matrix (IMHS). The residual stresses induced into the laminated structure during curing are taken into account. The following parameters are investigated: the length and the thickness of the shell, the fiber orientations, the fiber volume fraction, the temperature profile through the thickness of the laminate and the different ply thicknesses. Results obtained indicate that: the fiber orientations and the length of the laminated shell had significant effect on the natural frequencies. The fiber volume fraction, the laminate thickness and the temperature profile through the shell thickness had a weak effect on the natural frequencies. Finally, the laminates with different ply thicknesses had insignificant influence on the behavior of the vibrated laminated shell.

Nutrient shielding in clusters of cells

NASA Astrophysics Data System (ADS)

Lavrentovich, Maxim O.; Koschwanez, John H.; Nelson, David R.

2013-06-01

Cellular nutrient consumption is influenced by both the nutrient uptake kinetics of an individual cell and the cells' spatial arrangement. Large cell clusters or colonies have inhibited growth at the cluster's center due to the shielding of nutrients by the cells closer to the surface. We develop an effective medium theory that predicts a thickness ℓ of the outer shell of cells in the cluster that receives enough nutrient to grow. The cells are treated as partially absorbing identical spherical nutrient sinks, and we identify a dimensionless parameter ν that characterizes the absorption strength of each cell. The parameter ν can vary over many orders of magnitude among different cell types, ranging from bacteria and yeast to human tissue. The thickness ℓ decreases with increasing ν, increasing cell volume fraction ϕ, and decreasing ambient nutrient concentration ψ∞. The theoretical results are compared with numerical simulations and experiments. In the latter studies, colonies of budding yeast, Saccharomyces cerevisiae, are grown on glucose media and imaged under a confocal microscope. We measure the growth inside the colonies via a fluorescent protein reporter and compare the experimental and theoretical results for the thickness ℓ.

Quantitative investigation on the critical thickness of the dielectric shell for metallic nanoparticles determined by the plasmon decay length.

PubMed

Li, Anran; Lim, Xinyi; Guo, Lin; Li, Shuzhou

2018-04-20

Inert dielectric shells coating the surface of metallic nanoparticles (NPs) are important for enhancing the NPs' stability, biocompatibility, and realizing targeting detection, but they impair NPs' sensing ability due to the electric fields damping. The dielectric shell not only determines the distance of the analyte from the NP surface, but also affects the field decay. From a practical point of view, it is extremely important to investigate the critical thickness of the shell, beyond which the NPs are no longer able to effectively detect the analytes. The plasmon decay length of the shell-coated NPs determines the critical thickness of the coating layer. Extracting from the exponential fitting results, we quantitatively demonstrate that the critical thickness of the shell exhibits a linear dependence on the NP volume and the dielectric constants of the shell and the surrounding medium, but only with a small variation influenced by the NP shape where the dipole resonance is dominated. We show the critical thickness increases with enlarging the NP sizes, or increasing the dielectric constant differences between the shell and surrounding medium. The findings are essential for applications of shell-coated NPs in plasmonic sensing.

Quantitative investigation on the critical thickness of the dielectric shell for metallic nanoparticles determined by the plasmon decay length

NASA Astrophysics Data System (ADS)

Li, Anran; Lim, Xinyi; Guo, Lin; Li, Shuzhou

2018-04-01

Inert dielectric shells coating the surface of metallic nanoparticles (NPs) are important for enhancing the NPs’ stability, biocompatibility, and realizing targeting detection, but they impair NPs’ sensing ability due to the electric fields damping. The dielectric shell not only determines the distance of the analyte from the NP surface, but also affects the field decay. From a practical point of view, it is extremely important to investigate the critical thickness of the shell, beyond which the NPs are no longer able to effectively detect the analytes. The plasmon decay length of the shell-coated NPs determines the critical thickness of the coating layer. Extracting from the exponential fitting results, we quantitatively demonstrate that the critical thickness of the shell exhibits a linear dependence on the NP volume and the dielectric constants of the shell and the surrounding medium, but only with a small variation influenced by the NP shape where the dipole resonance is dominated. We show the critical thickness increases with enlarging the NP sizes, or increasing the dielectric constant differences between the shell and surrounding medium. The findings are essential for applications of shell-coated NPs in plasmonic sensing.

Ocean acidification and temperature increase impact mussel shell shape and thickness: problematic for protection?

PubMed

Fitzer, Susan C; Vittert, Liberty; Bowman, Adrian; Kamenos, Nicholas A; Phoenix, Vernon R; Cusack, Maggie

2015-11-01

Ocean acidification threatens organisms that produce calcium carbonate shells by potentially generating an under-saturated carbonate environment. Resultant reduced calcification and growth, and subsequent dissolution of exoskeletons, would raise concerns over the ability of the shell to provide protection for the marine organism under ocean acidification and increased temperatures. We examined the impact of combined ocean acidification and temperature increase on shell formation of the economically important edible mussel Mytilus edulis. Shell growth and thickness along with a shell thickness index and shape analysis were determined. The ability of M. edulis to produce a functional protective shell after 9 months of experimental culture under ocean acidification and increasing temperatures (380, 550, 750, 1000 μatm pCO 2, and 750, 1000 μatm pCO 2 + 2°C) was assessed. Mussel shells grown under ocean acidification conditions displayed significant reductions in shell aragonite thickness, shell thickness index, and changes to shell shape (750, 1000 μatm pCO 2) compared to those shells grown under ambient conditions (380 μatm pCO 2). Ocean acidification resulted in rounder, flatter mussel shells with thinner aragonite layers likely to be more vulnerable to fracture under changing environments and predation. The changes in shape presented here could present a compensatory mechanism to enhance protection against predators and changing environments under ocean acidification when mussels are unable to grow thicker shells. Here, we present the first assessment of mussel shell shape to determine implications for functional protection under ocean acidification.

Photocatalytic activity of Ag/ZnO core-shell nanoparticles with shell thickness as controlling parameter under green environment

NASA Astrophysics Data System (ADS)

Rajbongshi, Himanshu; Bhattacharjee, Suparna; Datta, Pranayee

2017-02-01

Plasmonic Ag/ZnO core-shell nanoparticles have been synthesized via a simple two-step wet chemical method for application in Photocatalysis. The morphology, size, crystal structure, composition and optical properties of the nanoparticles are investigated by x-ray diffraction, transmission electron microscopy (TEM), FTIR spectroscopy, ultraviolet-visible (UV-Vis) absorption spectroscopy and photoluminescence (PL) spectroscopy. The shell thicknesses are varied by varying the concentration of zinc nitrate hexa-hydrate and triethanolamine. The ZnO shell coating over Ag core enhances the charge separation, whereas the larger shell thickness and increased refractive index of surrounding medium cause red shifts of surface Plasmon resonance (SPR) peak of Ag core. The photoluminescence (PL) spectra of Ag/ZnO core-shell show that the larger shell thickness quenches the near band edge UV emission of ZnO. The electrochemical impedance spectra (EIS) i.e. Nyquist plots also confirm the higher charge transfer efficiency of the Ag/ZnO core-shell nanoparticles. The Photocatalytic activities of Ag/ZnO core-shell nanoparticles are investigated by the degradation of methylene blue (MB) dye under direct sunlight irradiation. Compared to pure ZnO nanoparticles (NPs), Ag/ZnO core-shell NPs display efficient sunlight plasmonic photocatalytic activity because of the influence of SPR of Ag core and the electron sink effect. The photocatalytic activity of Ag/ZnO core-shell NPs is found to be enhanced with increase in shell thickness.

High performance of PbSe/PbS core/shell quantum dot heterojunction solar cells: short circuit current enhancement without the loss of open circuit voltage by shell thickness control.

PubMed

Choi, Hyekyoung; Song, Jung Hoon; Jang, Jihoon; Mai, Xuan Dung; Kim, Sungwoo; Jeong, Sohee

2015-11-07

We fabricated heterojunction solar cells with PbSe/PbS core shell quantum dots and studied the precisely controlled PbS shell thickness dependency in terms of optical properties, electronic structure, and solar cell performances. When the PbS shell thickness increases, the short circuit current density (JSC) increases from 6.4 to 11.8 mA cm(-2) and the fill factor (FF) enhances from 30 to 49% while the open circuit voltage (VOC) remains unchanged at 0.46 V even with the decreased effective band gap. We found that the Fermi level and the valence band maximum level remain unchanged in both the PbSe core and PbSe/PbS core/shell with a less than 1 nm thick PbS shell as probed via ultraviolet photoelectron spectroscopy (UPS). The PbS shell reduces their surface trap density as confirmed by relative quantum yield measurements. Consequently, PbS shell formation on the PbSe core mitigates the trade-off relationship between the open circuit voltage and the short circuit current density. Finally, under the optimized conditions, the PbSe core with a 0.9 nm thick shell yielded a power conversion efficiency of 6.5% under AM 1.5.

Progress technology in microencapsulation methods for cell therapy.

PubMed

Rabanel, Jean-Michel; Banquy, Xavier; Zouaoui, Hamza; Mokhtar, Mohamed; Hildgen, Patrice

2009-01-01

Cell encapsulation in microcapsules allows the in situ delivery of secreted proteins to treat different pathological conditions. Spherical microcapsules offer optimal surface-to-volume ratio for protein and nutrient diffusion, and thus, cell viability. This technology permits cell survival along with protein secretion activity upon appropriate host stimuli without the deleterious effects of immunosuppressant drugs. Microcapsules can be classified in 3 categories: matrix-core/shell microcapsules, liquid-core/shell microcapsules, and cells-core/shell microcapsules (or conformal coating). Many preparation techniques using natural or synthetic polymers as well as inorganic compounds have been reported. Matrix-core/shell microcapsules in which cells are hydrogel-embedded, exemplified by alginates capsule, is by far the most studied method. Numerous refinement of the technique have been proposed over the years such as better material characterization and purification, improvements in microbead generation methods, and new microbeads coating techniques. Other approaches, based on liquid-core capsules showed improved protein production and increased cell survival. But aside those more traditional techniques, new techniques are emerging in response to shortcomings of existing methods. More recently, direct cell aggregate coating have been proposed to minimize membrane thickness and implants size. Microcapsule performances are largely dictated by the physicochemical properties of the materials and the preparation techniques employed. Despite numerous promising pre-clinical results, at the present time each methods proposed need further improvements before reaching the clinical phase. (c) 2009 American Institute of Chemical Engineers Biotechnol. Prog., 2009.

Layer-by-layer-based silica encapsulation of individual yeast with thickness control.

PubMed

Lee, Hojae; Hong, Daewha; Choi, Ji Yu; Kim, Ji Yup; Lee, Sang Hee; Kim, Ho Min; Yang, Sung Ho; Choi, Insung S

2015-01-01

In the area of cell-surface engineering with nanomaterials, the metabolic and functional activities of the encapsulated cells are manipulated and controlled by various parameters of the artificial shells that encase the cells, such as stiffness and elasticity, thickness, and porosity. The mechanical durability and physicochemical stability of inorganic shells prove superior to layer-by-layer-based organic shells with regard to cytoprotection, but it has been difficult to vary the parameters of inorganic shells including their thickness. In this work, we combine the layer-by-layer technique with a process of bioinspired silicification to control the thickness of the silica shells that encapsulate yeast Saccharomyces cerevisiae cells individually, and investigate the thickness-dependent microbial growth. © 2015 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

How Spherical Is a Cube (Gravitationally)?

ERIC Educational Resources Information Center

Sanny, Jeff; Smith, David

2015-01-01

An important concept that is presented in the discussion of Newton's law of universal gravitation is that the gravitational effect external to a spherically symmetric mass distribution is the same as if all of the mass of the distribution were concentrated at the center. By integrating over ring elements of a spherical shell, we show that the…

Spherical thin-shell wormholes and modified Chaplygin gas

DOE Office of Scientific and Technical Information (OSTI.GOV)

Sharif, M.; Azam, M., E-mail: msharif.math@pu.edu.pk, E-mail: azammath@gmail.com

2013-05-01

The purpose of this paper is to construct spherical thin-shell wormhole solutions through cut and paste technique and investigate the stability of these solutions in the vicinity of modified Chaplygin gas. The Darmois-Israel formalism is used to formulate the stresses of the surface concentrating the exotic matter. We explore the stability of the wormhole solutions by using the standard potential method. We conclude that there exist more stable as well as unstable solutions than the previous study with generalized Chaplygin gas [19].

Recombination energy for negatively charged excitons inside type-II core/shell spherical quantum dots

NASA Astrophysics Data System (ADS)

Chafai, A.; Essaoudi, I.; Ainane, A.; Dujardin, F.; Ahuja, R.

2018-07-01

The recombination energy of isolated neutral exciton and that of isolated negatively charged exciton inside a type-II core/shell spherical quantum dot are studied. Our investigation considers the charge-carriers effective mass discontinuity at the surface contact between the core and shell materials. Although our model omits the effect of the surface polarization, the dielectric-constant mismatch at the nanodot boundaries was taken into account. In order to achieve the exciton and negative trion energies, we proceed by a variational calculation in the framework of the envelope approximation. Our results reveal a strong correlation between the nanodot morphology and the energy spectrum of the neutral and negatively charged exciton.

Validity of the Aluminum Equivalent Approximation in Space Radiation Shielding

NASA Technical Reports Server (NTRS)

Badavi, Francis F.; Adams, Daniel O.; Wilson, John W.

2009-01-01

The origin of the aluminum equivalent shield approximation in space radiation analysis can be traced back to its roots in the early years of the NASA space programs (Mercury, Gemini and Apollo) wherein the primary radiobiological concern was the intense sources of ionizing radiation causing short term effects which was thought to jeopardize the safety of the crew and hence the mission. Herein, it is shown that the aluminum equivalent shield approximation, although reasonably well suited for that time period and to the application for which it was developed, is of questionable usefulness to the radiobiological concerns of routine space operations of the 21 st century which will include long stays onboard the International Space Station (ISS) and perhaps the moon. This is especially true for a risk based protection system, as appears imminent for deep space exploration where the long-term effects of Galactic Cosmic Ray (GCR) exposure is of primary concern. The present analysis demonstrates that sufficiently large errors in the interior particle environment of a spacecraft result from the use of the aluminum equivalent approximation, and such approximations should be avoided in future astronaut risk estimates. In this study, the aluminum equivalent approximation is evaluated as a means for estimating the particle environment within a spacecraft structure induced by the GCR radiation field. For comparison, the two extremes of the GCR environment, the 1977 solar minimum and the 2001 solar maximum, are considered. These environments are coupled to the Langley Research Center (LaRC) deterministic ionized particle transport code High charge (Z) and Energy TRaNsport (HZETRN), which propagates the GCR spectra for elements with charges (Z) in the range I <= Z <= 28 (H -- Ni) and secondary neutrons through selected target materials. The coupling of the GCR extremes to HZETRN allows for the examination of the induced environment within the interior' of an idealized spacecraft as approximated by a spherical shell shield, and the effects of the aluminum equivalent approximation for a good polymeric shield material such as genetic polyethylene (PE). The shield thickness is represented by a 25 g/cm spherical shell. Although one could imagine the progression to greater thickness, the current range will be sufficient to evaluate the qualitative usefulness of the aluminum equivalent approximation. Upon establishing the inaccuracies of the aluminum equivalent approximation through numerical simulations of the GCR radiation field attenuation for PE and aluminum equivalent PE spherical shells, we Anther present results for a limited set of commercially available, hydrogen rich, multifunctional polymeric constituents to assess the effect of the aluminum equivalent approximation on their radiation attenuation response as compared to the generic PE.

Singlet oxygen generation of photosensitizers effectively activated by Nd3+-doped upconversion nanoparticles of luminescence intensity enhancing with shell thickness decreasing

NASA Astrophysics Data System (ADS)

Zou, Haixia; Jin, Fengmin; Song, Xiaoyan; Xing, Jinfeng

2017-04-01

The introduction of a thick shell structure has been widely used to enhance the emission intensity of upconversion nanoparticles (UCNPs). However, a thick shell could increase the distance between UCNPs and photosensitizers, which is not favourable to the generation of singlet oxygen (1O2) in photodynamic therapy (PDT) due to the low fluorescence resonance energy transfer (FRET) efficiency. In this study, we used a facile method to prepare UCNPs that the emission intensity could increase with the shell thickness decreasing, which facilitated the efficient FRET between UCNPs and photosensitizers. In detail, the Nd3+-doped UCNPs with different dopant concentration of Yb3+ were prepared and characterized firstly. The Ir/g (intensity of red luminescence to green luminescence) was tuned to increase largely by precisely controlling Yb3+ concentration in core-shell, which could make UCNPs effectively activate methylene blue (MB). Then, a unique procedure was used to prepare NaYF4:Yb/Er/Nd@NaYF4:Nd (Yb3+:30%) core-shell nanoparticles with different shell thickness by tuning the amount of the core. The upconversion luminescence (UCL) intensity of those UCNPs enhanced dramatically with the shell thickness decreasing. Furthermore, UCNPs and MB were encapsulated into SiO2 nanoparticles. FRET efficiency between UCNPs and MB largely increased with the shell thickness of UCNPs decreasing. Correspondingly, the efficiency of 1O2 generation obviously increased. We provided a new method to optimize the UCL intensity and FRET efficiency at the same time to produce 1O2 efficiently.

Powder metallurgy processing and deformation characteristics of bulk multimodal nickel

DOE Office of Scientific and Technical Information (OSTI.GOV)

Farbaniec, L., E-mail: lfarban1@jhu.edu; Dirras, G., E-mail: dirras@univ-paris13.fr; Krawczynska, A.

2014-08-15

Spark plasma sintering was used to process bulk nickel samples from a blend of three powder types. The resulting multimodal microstructure was made of coarse (average size ∼ 135 μm) spherical microcrystalline entities (the core) surrounded by a fine-grained matrix (average grain size ∼ 1.5 μm) or a thick rim (the shell) distinguishable from the matrix. Tensile tests revealed yield strength of ∼ 470 MPa that was accompanied by limited ductility (∼ 2.8% plastic strain). Microstructure observation after testing showed debonding at interfaces between the matrix and the coarse entities, but in many instances, shallow dimples within the rim weremore » observed indicating local ductile events in the shell. Dislocation emission and annihilation at grain boundaries and twinning at crack tip were the main deformation mechanisms taking place within the fine-grained matrix as revealed by in-situ transmission electron microscopy. Estimation of the stress from loop's curvature and dislocation pile-up indicates that dislocation emission from grain boundaries and grain boundary overcoming largely contributes to the flow stress. - Highlights: • Bulk multi-modal Ni was processed by SPS from a powder blend. • Ultrafine-grained matrix or rim observed around spherical microcrystalline entities • Yield strength (470 MPa) and ductility (2.8% plastic strain) were measured. • Debonding was found at the matrix/microcrystalline entity interfaces. • In-situ TEM showed twinning, dislocation emission and annihilation at grain boundaries.« less

Fracture mechanics analyses of partial crack closure in shell structures

NASA Astrophysics Data System (ADS)

Zhao, Jun

2007-12-01

This thesis presents the theoretical and finite element analyses of crack-face closure behavior in shells and its effect on the stress intensity factor under a bending load condition. Various shell geometries, such as spherical shell, cylindrical shell containing an axial crack, cylindrical shell containing a circumferential crack and shell with double curvatures, are all studied. In addition, the influence of material orthotropy on the crack closure effect in shells is also considered. The theoretical formulation is developed based on the shallow shell theory of Delale and Erdogan, incorporating the effect of crack-face closure at the compressive edges. The line-contact assumption, simulating the crack-face closure at the compressive edges, is employed so that the contact force at the closure edges is introduced, which can be translated to the mid-plane of the shell, accompanied by an additional distributed bending moment. The unknown contact force is computed by solving a mixed-boundary value problem iteratively, that is, along the crack length, either the normal displacement of the crack face at the compressive edges is equal to zero or the contact pressure is equal to zero. It is found that due to the curvature effects crack closure may not always occur on the entire length of the crack, depending on the direction of the bending load and the geometry of the shell. The crack-face closure influences significantly the magnitude of the stress intensity factors; it increases the membrane component but decreases the bending component. The maximum stress intensity factor is reduced by the crack-face closure. The significant influence of geometry and material orthotropy on rack closure behavior in shells is also predicted based on the analytical solutions. Three-dimensional FEA is performed to validate the theoretical solutions. It demonstrates that the crack face closure occurs actually over an area, not on a line, but the theoretical solutions of the stress intensity factor and the FEA solutions are in good agreement, because the contact area is very small compared with the shell thickness.

Shell Thickness Dependence of Interparticle Energy Transfer in Core-Shell ZnSe/ZnSe Quantum Dots Doping with Europium

NASA Astrophysics Data System (ADS)

Liu, Ni; Li, Shuxin; Wang, Caifeng; Li, Jie

2018-04-01

Low-toxic core-shell ZnSe:Eu/ZnS quantum dots (QDs) were prepared through two steps in water solution: nucleation doping and epitaxial shell grown. The structural and morphological characteristics of ZnSe/ZnS:Eu QDs with different shell thickness were explored by transmission electron microscopy (TEM) and X-ray diffraction (XRD) results. The characteristic photoluminescence (PL) intensity of Eu ions was enhanced whereas that of band-edge luminescence and defect-related luminescence of ZnSe QDs was decreased with increasing shell thickness. The transformation of PL intensity revealed an efficient energy transfer process between ZnSe and Eu. The PL intensity ratio of Eu ions ( I 613) to ZnSe QDs ( I B ) under different shell thickness was systemically analyzed by PL spectra and time-resolved PL spectra. The obtained results were in agreement with the theory analysis results by the kinetic theory of energy transfer, revealing that energy was transmitted in the form of dipole-electric dipole interaction. This particular method of adjusting luminous via changing the shell thickness can provide valuable insights towards the fundamental understanding and application of QDs in the field of optoelectronics.

Quasi-spherical accretion in High Mass X-ray Binaries

NASA Astrophysics Data System (ADS)

Postnov, Konstantin

2016-07-01

Quasi-spherical accreion onto magnetized neutron stars from stellar winds in high-mass X-ray binaries is discussed. Depending on the X-ray luminosity of the neutron star, the accretion can proceed in two regimes (modes): at L_x ≳ 4× 10^{36} erg/s, Compton cooling of accreting matter near magnetosphere leads to a supersonic (Bondi) accretion, while at smaller X-ray luminosity the Compton cooling is ineffective, and subsonic settling accretion regime sets in. In this regime, a hot convective shell is formed around the magnetosphere, and the plasma entry rate into magnetosphere is controlled by less effective radiative plasma cooling. The shell mediates the angular momentum transfer from/to the neutron star magnetosphere. Observational evidences for the different accretion regimes in slowly rotating X-ray pulsars with moderate and low X-ray luminosity, as well as possible manifestations of non-stationary quasi-spherical settling accretion due to the magnetospheric shell instability in Supergiant Fast X-ray Transients will be presented.

Laminated Thin Shell Structures Subjected to Free Vibration in a Hygrothermal Environment

NASA Technical Reports Server (NTRS)

Gotsis, Pascal K.; Guptill, James D.

1994-01-01

Parametric studies were performed to assess the effects of various parameters on the free-vibration behavior (natural frequencies) of (+/- theta)(sub 2) angle-ply, fiber composite, thin shell structures in a hygrothermal environment. Knowledge of the natural frequencies of structures is important in considering their response to various kinds of excitation, especially when structures and force systems are complex and when excitations are not periodic. The three dimensional, finite element structural analysis computer code CSTEM was used in the Cray YMP computer environment. The fiber composite shell was assumed to be cylindrical and made from T300 graphite fibers embedded in an intermediate-modulus, high-strength matrix. The following parameters were investigated: the length and the laminate thickness of the shell, the fiber orientation, the fiber volume fraction, the temperature profile through the thickness of the laminate, and laminates with different ply thicknesses. The results indicate that the fiber orientation and the length of the laminated shell had significant effects on the natural frequencies. The fiber volume fraction, the laminate thickness, and the temperature profile through the shell thickness had weak effects on the natural frequencies. Finally, the laminates with different ply thicknesses had an insignificant influence on the behavior of the vibrated laminated shell. Also, a single through-the-thickness, eight-node, three dimensional composite finite element analysis appears to be sufficient for investigating the free-vibration behavior of thin, composite, angle-ply shell structures.

Collapsing shells and black holes: a quantum analysis

NASA Astrophysics Data System (ADS)

Leal, P.; Bernardini, A. E.; Bertolami, O.

2018-06-01

The quantization of a spherically symmetric null shells is performed and extended to the framework of phase-space noncommutative (NC) quantum mechanics. This shell is considered to be inside a black hole event horizon. The encountered properties are investigated making use of the Israel junction conditions on the shell, considering that it is the boundary between two spherically symmetric spacetimes. Using this method, and considering two different Kantowski–Sachs spacetimes as a representation for the Schwarzschild spacetime, the relevant quantities on the shell are computed, such as its stress-energy tensor and the action for the whole spacetime. From the obtained action, the Wheeler–deWitt equation is deduced in order to provide the quantum framework for the system. Solutions for the wave function of the system are found on both the commutative and NC scenarios. It is shown that, on the commutative version, the wave function has a purely oscillatory behavior in the interior of the shell. In the NC setting, it is shown that the wave function vanishes at the singularity, as well as, at the event horizon of the black hole.

Characterizing haploinsufficiency of SHELL gene to improve fruit form prediction in introgressive hybrids of oil palm.

PubMed

Teh, Chee-Keng; Muaz, Siti Dalila; Tangaya, Praveena; Fong, Po-Yee; Ong, Ai-Ling; Mayes, Sean; Chew, Fook-Tim; Kulaveerasingam, Harikrishna; Appleton, David

2017-06-08

The fundamental trait in selective breeding of oil palm (Eleais guineensis Jacq.) is the shell thickness surrounding the kernel. The monogenic shell thickness is inversely correlated to mesocarp thickness, where the crude palm oil accumulates. Commercial thin-shelled tenera derived from thick-shelled dura × shell-less pisifera generally contain 30% higher oil per bunch. Two mutations, sh MPOB (M1) and sh AVROS (M2) in the SHELL gene - a type II MADS-box transcription factor mainly present in AVROS and Nigerian origins, were reported to be responsible for different fruit forms. In this study, we have tested 1,339 samples maintained in Sime Darby Plantation using both mutations. Five genotype-phenotype discrepancies and eight controls were then re-tested with all five reported mutations (sh AVROS , sh MPOB , sh MPOB2 , sh MPOB3 and sh MPOB4 ) within the same gene. The integration of genotypic data, pedigree records and shell formation model further explained the haploinsufficiency effect on the SHELL gene with different number of functional copies. Some rare mutations were also identified, suggesting a need to further confirm the existence of cis-compound mutations in the gene. With this, the prediction accuracy of fruit forms can be further improved, especially in introgressive hybrids of oil palm. Understanding causative variant segregation is extremely important, even for monogenic traits such as shell thickness in oil palm.

Role of membrane stresses in the support of planetary topography

NASA Technical Reports Server (NTRS)

Turcotte, D. L.; Willemann, R. J.; Haxby, W. F.; Norberry, J.

1981-01-01

The role of membrane stresses and bending stresses in supporting topographic loads on planetary elastic lithospheres is examined. A dimensionless parameter is introduced in order to determine the ability of a spherical shell to support loads through membrane stresses. It is determined that when this parameter is large, membrane stresses can fully support topographic loads with flexure, and when it is small the influence of the membrane stresses can be neglected. Equations governing the behavior of a spherical shell are solved for a topographic load expressed in terms of spherical harmonics, and spherical harmonic expansions of the measured gravity and topography for Mars and the moon are compared with the theory. It is concluded that membrane stresses play an important role in the support of topographic loads on the moon and Mars. The correlation of observed gravitational potential anomalies with the topography on Mars is explained by membrane stresses in the elastic lithosphere.

Axisymmetric inertial modes in a spherical shell at low Ekman numbers

NASA Astrophysics Data System (ADS)

Rieutord, M.; Valdettaro, L.

2018-06-01

We investigate the asymptotic properties of axisymmetric inertial modes propagating in a spherical shell when viscosity tends to zero. We identify three kinds of eigenmodes whose eigenvalues follow very different laws as the Ekman number $E$ becomes very small. First are modes associated with attractors of characteristics that are made of thin shear layers closely following the periodic orbit traced by the characteristic attractor. Second are modes made of shear layers that connect the critical latitude singularities of the two hemispheres of the inner boundary of the spherical shell. Third are quasi-regular modes associated with the frequency of neutral periodic orbits of characteristics. We thoroughly analyse a subset of attractor modes for which numerical solutions point to an asymptotic law governing the eigenvalues. We show that three length scales proportional to $E^{1/6}$, $E^{1/4}$ and $E^{1/3}$ control the shape of the shear layers that are associated with these modes. These scales point out the key role of the small parameter $E^{1/12}$ in these oscillatory flows. With a simplified model of the viscous Poincar\\'e equation, we can give an approximate analytical formula that reproduces the velocity field in such shear layers. Finally, we also present an analysis of the quasi-regular modes whose frequencies are close to $\\sin(\\pi/4)$ and explain why a fluid inside a spherical shell cannot respond to any periodic forcing at this frequency when viscosity vanishes.

Method of forming cavitated objects of controlled dimension

DOEpatents

Anderson, Paul R.; Miller, Wayne J.

1982-01-01

A method of controllably varying the dimensions of cavitated objects such as hollow spherical shells wherein a precursor shell is heated to a temperature above the shell softening temperature in an ambient atmosphere wherein the ratio of gases which are permeable through the shell wall at that temperature to gases which are impermeable through the shell wall is substantially greater than the corresponding ratio for gases contained within the precursor shell. As the shell expands, the partial pressures of permeable gases internally and externally of the shell approach and achieve equilibrium, so that the final shell size depends solely upon the difference in impermeable gas partial pressures and shell surface tension.

Acoustic radiation force on a multilayered sphere in a Gaussian standing field

NASA Astrophysics Data System (ADS)

Wang, Haibin; Liu, Xiaozhou; Gao, Sha; Cui, Jun; Liu, Jiehui; He, Aijun; Zhang, Gutian

2018-03-01

We develop a model for calculating the radiation force on spherically symmetric multilayered particles based on the acoustic scattering approach. An expression is derived for the radiation force on a multilayered sphere centered on the axis of a Gaussian standing wave propagating in an ideal fluid. The effects of the sound absorption of the materials and sound wave on acoustic radiation force of a multilayered sphere immersed in water are analyzed, with particular emphasis on the shell thickness of every layer, and the width of the Gaussian beam. The results reveal that the existence of particle trapping behavior depends on the choice of the non-dimensional frequency ka, as well as the shell thickness of each layer. This study provides a theoretical basis for the development of acoustical tweezers in a Gaussian standing wave, which may benefit the improvement and development of acoustic control technology, such as trapping, sorting, and assembling a cell, and drug delivery applications. Project supported by National Key R&D Program (Grant No. 2016YFF0203000), the National Natural Science Foundation of China (Grant Nos. 11774167 and 61571222), the Fundamental Research Funds for the Central Universities of China (Grant No. 020414380001), the Key Laboratory of Underwater Acoustic Environment, Institute of Acoustics, Chinese Academy of Sciences (Grant No. SSHJ-KFKT-1701), and the AQSIQ Technology R&D Program of China (Grant No. 2017QK125).

Experiments on Thermal Convection in Rotating Spherical Shells With Radial Gravity: The Geophysical Fluid Flow Cell

NASA Technical Reports Server (NTRS)

Hart, John E.

1996-01-01

Experiments designed to study the fluid dynamics of buoyancy driven circulations in rotating spherical shells were conducted on the United States Microgravity Laboratory 2 spacelab mission. These experiments address several aspects of prototypical global convection relevant to large scale motions on the Sun, Earth, and on the giant planets. The key feature is the consistent modeling of radially directed gravity in spherical geometry by using dielectric polarization forces. Imagery of the planforms of thermally driven flows for rapidly-rotating regimes shows an initial separation and eventual merger of equatorial and polar convection as the heating (i.e. the Rayleigh number) is increased. At low rotation rates, multiple-states of motion for the same external parameters were observed.

Effect of MUF/Epoxy Microcapsules on Mechanical Properties and Fractography of Epoxy Materials

NASA Astrophysics Data System (ADS)

Ni, Zhuo; Lin, Yuhao; Du, Xuexiao

2017-12-01

Melamine-urea-formaldehyde (MUF) microcapsules were synthesized, morphology, shell thickness, average diameter and interface morphology were studied by scanning electron microscope (SEM). The spherical MUF microcapsules are size normal distribution without adhesion and accumulation, being compact, rough and uneven with a thickness of 3.2μm and a core contents is approximate 70%. A latent imidazoleas the curing agent for a cross-linking chemical reaction for cracking repairing. A good dispersion of MUF microcapsules and a good interfacial bonding are obtained. Effects of MUF microcapsule size and content on bending property and dynamic mechanical propertywere investigated. Both bending strength and storage modulus of the composite are considerably reduced with an increasing addition of the microcapsules whereas the glass transition temperatures are almost not influenced. Significant toughening effects of MUF microcapsules on the epoxy composites are observed at the conditions of different content and size of microcapsule especially at low microcapsule contents and small microcapsule sizes.

Tectonic evolution of the terrestrial planets.

PubMed

Head, J W; Solomon, S C

1981-07-03

The style and evolution of tectonics on the terrestrial planets differ substantially. The style is related to the thickness of the lithosphere and to whether the lithosphere is divided into distinct, mobile plates that can be recycled into the mantle, as on Earth, or is a single spherical shell, as on the moon, Mars, and Mercury. The evolution of a planetary lithosphere and the development of plate tectonics appear to be influenced by several factors, including planetary size, chemistry, and external and internal heat sources. Vertical tectonic movement due to lithospheric loading or uplift is similar on all of the terrestrial planets and is controlled by the local thickness and rheology of the lithosphere. The surface of Venus, although known only at low resolution, displays features both similar to those on Earth (mountain belts, high plateaus) and similar to those on the smaller planets (possible impact basins). Improved understanding of the tectonic evolution of Venus will permit an evaluation of the relative roles of planetary size and chemistry in determining evolutionary style.

Radar attenuation in Europa's ice shell: Obstacles and opportunities for constraining the shell thickness and its thermal structure

NASA Astrophysics Data System (ADS)

Kalousová, Klára; Schroeder, Dustin M.; Soderlund, Krista M.

2017-03-01

Young surface and possible recent endogenic activity make Europa one of the most exciting solar system bodies and a primary target for spacecraft exploration. Future Europa missions are expected to carry ice-penetrating radar instruments designed to investigate its subsurface thermophysical structure. Several authors have addressed the radar sounders' performance at icy moons, often ignoring the complex structure of a realistic ice shell. Here we explore the variation in two-way radar attenuation for a variety of potential thermal structures of Europa's shell (determined by reference viscosity, activation energy, tidal heating, surface temperature, and shell thickness) as well as for low and high loss temperature-dependent attenuation model. We found that (i) for all investigated ice shell thicknesses (5-30 km), the radar sounder will penetrate between 15% and 100% of the total thickness, (ii) the maximum penetration depth varies laterally, with deepest penetration possible through cold downwellings, (iii) direct ocean detection might be possible for shells of up to 15 km thick if the signal travels through cold downwelling ice or the shell is conductive, (iv) even if the ice/ocean interface is not directly detected, penetration through most of the shell could constrain the deep shell structure through returns from deep non-ocean interfaces or the loss of signal itself, and (v) for all plausible ice shells, the two-way attenuation to the eutectic point is ≲30 dB which shows a robust potential for longitudinal investigation of the ice shell's shallow thermophysical structure.

Accurate image-charge method by the use of the residue theorem for core-shell dielectric sphere

NASA Astrophysics Data System (ADS)

Fu, Jing; Xu, Zhenli

2018-02-01

An accurate image-charge method (ICM) is developed for ionic interactions outside a core-shell structured dielectric sphere. Core-shell particles have wide applications for which the theoretical investigation requires efficient methods for the Green's function used to calculate pairwise interactions of ions. The ICM is based on an inverse Mellin transform from the coefficients of spherical harmonic series of the Green's function such that the polarization charge due to dielectric boundaries is represented by a series of image point charges and an image line charge. The residue theorem is used to accurately calculate the density of the line charge. Numerical results show that the ICM is promising in fast evaluation of the Green's function, and thus it is useful for theoretical investigations of core-shell particles. This routine can also be applicable for solving other problems with spherical dielectric interfaces such as multilayered media and Debye-Hückel equations.

Effect of solvents on morphology, magnetic and dielectric properties of (α-Fe2O3@SiO2) core-shell nanoparticles.

PubMed

Joshi, Deepika P; Pant, Geeta; Arora, Neha; Nainwal, Seema

2017-02-01

Present work describes the formation of α-Fe 2 O 3 @SiO 2 core shell structure by systematic layer by layer deposition of silica shell on core iron oxide nanoparticles prepared via various solvents. Sol-gel method has been used to synthesize magnetic core and the dielectric shell. The average crystallite size of iron oxide nanoparticles was calculated ∼20 nm by X-ray diffraction pattern. Morphological study by scanning electron microscopy revealed that the core-shell nanoparticles were spherical in shape and the average size of nanoparticles increased by varying solvent from methanol to ethanol to isopropanol due to different chemical structure and nature of the solvents. It was also observed that the particles prepared by solvent ethanol were more regular and homogeneous as compared to other solvents. Magnetic measurements showed the weak ferromagnetic behaviour of both core α-Fe 2 O 3 and silica-coated iron oxide nanoparticles which remained same irrespective of the solvent chosen. However, magnetization showed dependency on the types of solvent chosen due to the variation in shell thickness. At room temperature, dielectric constant and dielectric loss of silica nanoparticles for all the solvents showed decrement with the increment in frequency. Decrement in the value of dielectric constant and increment in dielectric loss was observed for silica coated iron oxide nanoparticles in comparison of pure silica, due to the presence of metallic core. Homogeneous and regular silica layer prepared by using ethanol as a solvent could serve as protecting layer to shield the magnetic behaviour of iron oxide nanoparticles as well as to provide better thermal insulation over pure α-Fe 2 O 3 nanoparticles.

Evaluation of Optimal Formulas for Gravitational Tensors up to Gravitational Curvatures of a Tesseroid

NASA Astrophysics Data System (ADS)

Deng, Xiao-Le; Shen, Wen-Bin

2018-01-01

The forward modeling of the topographic effects of the gravitational parameters in the gravity field is a fundamental topic in geodesy and geophysics. Since the gravitational effects, including for instance the gravitational potential (GP), the gravity vector (GV) and the gravity gradient tensor (GGT), of the topographic (or isostatic) mass reduction have been expanded by adding the gravitational curvatures (GC) in geoscience, it is crucial to find efficient numerical approaches to evaluate these effects. In this paper, the GC formulas of a tesseroid in Cartesian integral kernels are derived in 3D/2D forms. Three generally used numerical approaches for computing the topographic effects (e.g., GP, GV, GGT, GC) of a tesseroid are studied, including the Taylor Series Expansion (TSE), Gauss-Legendre Quadrature (GLQ) and Newton-Cotes Quadrature (NCQ) approaches. Numerical investigations show that the GC formulas in Cartesian integral kernels are more efficient if compared to the previously given GC formulas in spherical integral kernels: by exploiting the 3D TSE second-order formulas, the computational burden associated with the former is 46%, as an average, of that associated with the latter. The GLQ behaves better than the 3D/2D TSE and NCQ in terms of accuracy and computational time. In addition, the effects of a spherical shell's thickness and large-scale geocentric distance on the GP, GV, GGT and GC functionals have been studied with the 3D TSE second-order formulas as well. The relative approximation errors of the GC functionals are larger with the thicker spherical shell, which are the same as those of the GP, GV and GGT. Finally, the very-near-area problem and polar singularity problem have been considered by the numerical methods of the 3D TSE, GLQ and NCQ. The relative approximation errors of the GC components are larger than those of the GP, GV and GGT, especially at the very near area. Compared to the GC formulas in spherical integral kernels, these new GC formulas can avoid the polar singularity problem.

Monte Carlo simulations of nematic and chiral nematic shells

NASA Astrophysics Data System (ADS)

Wand, Charlie R.; Bates, Martin A.

2015-01-01

We present a systematic Monte Carlo simulation study of thin nematic and cholesteric shells with planar anchoring using an off-lattice model. The results obtained using the simple model correspond with previously published results for lattice-based systems, with the number, type, and position of defects observed dependent on the shell thickness with four half-strength defects in a tetrahedral arrangement found in very thin shells and a pair of defects in a bipolar (boojum) configuration observed in thicker shells. A third intermediate defect configuration is occasionally observed for intermediate thickness shells, which is stabilized in noncentrosymmetric shells of nonuniform thickness. Chiral nematic (cholesteric) shells are investigated by including a chiral term in the potential. Decreasing the pitch of the chiral nematic leads to a twisted bipolar (chiral boojum) configuration with the director twist increasing from the inner to the outer surface.

Biotemplated synthesis of high specific surface area copper-doped hollow spherical titania and its photocatalytic research for degradating chlorotetracycline

NASA Astrophysics Data System (ADS)

Bu, Dan; Zhuang, Huisheng

2013-01-01

Copper-doped titania (Cu/TiO2) hollow microspheres were fabricated using the rape pollen as biotemplates via an improved sol-gel method and a followed calcinations process. In the fabricated process, a titanium(IV)-isopropoxide-based sol directly coated onto the surface of rape pollen. Subsequently, after calcinations, rape pollen was removed by high temperature and the hollow microsphere structure was retained. The average diameter of as-obtained hollow microspheres is 15-20 μm and the thickness of shell is approximately 0.6 μm. Knowing from XRD results, the main crystal phase of microspheres is anatase, coupled with rutile. The specific surface area varied between 141.80 m2/g and 172.51 m2/g. This hollow sphere photocatalysts with high specific surface area exhibited stronger absorption ability and higher photoactivity, stimulated by visible light. The degradation process of chlortetracycline (CTC) solution had been studied. The degradated results indicate that CTC could be effective degradated by fabricated hollow spherical materials. And the intermediate products formed in the photocatalytic process had been identified.

Interferometric observations of non-maser SiO emission from circumstellar envelopes of AGB stars - Acceleration regions and SiO depletion

NASA Technical Reports Server (NTRS)

Sahai, Raghvendra; Bieging, John H.

1993-01-01

High- and medium-resolution images of SiO J = 2-1(V = 0) from the circumstellar envelopes (CSEs) of three oxygen-rich stars, Chi Cyg, RX Boo, and IK Tau, were obtained. The SIO images were found to be roughly circular, implying that the CSEs are spherically symmetric on angular-size scales of about 3-9 arcsec. The observed angular half-maximum intensity source radius is nearly independent of the LSR velocity for all three CSEs. Chi Cyg and RX Boo are argued to be less than 450 pc distant, and have mass-loss rates larger than about 10 exp -6 solar mass/yr. In Chi Cyg and RX Boo, the line profiles at the peak of the brightness distribution are rounded, typical of optically-thick emission from a spherical envelope expanding with a constant velocity. In the IK Tau line profiles, an additional narrower central component is present, probably a result of emission from an inner circumstellar shell with a significantly smaller expansion velocity than the extended envelope.

Ballistic Simulation Method for Lithium Ion Batteries (BASIMLIB) Using Thick Shell Composites (TSC) in LS-DYNA

DTIC Science & Technology

2016-08-04

BAllistic SImulation Method for Lithium Ion Batteries (BASIMLIB) using Thick Shell Composites (TSC) in LS-DYNA Venkatesh Babu, Dr. Matt Castanier, Dr...Objective • Objective and focus of this work is to develop a – Robust simulation methodology to model lithium - ion based batteries in its module and full...unlimited  Lithium Ion Phosphate (LiFePO4) battery cell, module and pack was modeled in LS-DYNA using both Thin Shell Layer (TSL) and Thick Shell

Synthesis and Characterization of N-Doped Porous TiO2 Hollow Spheres and Their Photocatalytic and Optical Properties

PubMed Central

Li, Hongliang; Liu, Hui; Fu, Aiping; Wu, Guanglei; Xu, Man; Pang, Guangsheng; Guo, Peizhi; Liu, Jingquan; Zhao, Xiu Song

2016-01-01

Three kinds of N-doped mesoporous TiO2 hollow spheres with different N-doping contents, surface area, and pore size distributions were prepared based on a sol–gel synthesis and combined with a calcination process. Melamine formaldehyde (MF) microspheres have been used as sacrificial template and cetyltrimethyl ammonium bromide (CTAB) or polyvinylpyrrolidone (PVP) was selected as pore-directing agent. Core–shell intermediate spheres of titania-coated MF with diameters of 1.2–1.6 μm were fabricated by varying the volume concentration of TiO2 precursor from 1 to 3 vol %. By calcining the core–shell composite spheres at 500 °C for 3 h in air, an in situ N-doping process occurred upon the decomposition of the MF template and CTAB or PVP pore-directing surfactant. N-doped mesoporous TiO2 hollow spheres with sizes in the range of 0.4–1.2 μm and shell thickness from 40 to 110 nm were obtained. The composition and N-doping content, thermal stability, morphology, surface area and pore size distribution, wall thickness, photocatalytic activities, and optical properties of the mesoporous TiO2 hollow spheres derived from different conditions were investigated and compared based on Fourier-transformation infrared (FTIR), SEM, TEM, thermogravimetric analysis (TGA), nitrogen adsorption–desorption, and UV–vis spectrophotoscopy techniques. The influences of particle size, N-doping, porous, and hollow characteristics of the TiO2 hollow spheres on their photocatalytic activities and optical properties have been studied and discussed based on the composition analysis, structure characterization, and optical property investigation of these hollow spherical TiO2 matrices. PMID:28773967

49 CFR 179.220-25 - Stamping.

Code of Federal Regulations, 2010 CFR

2010-10-01

...: Material ASTM A240-316L. Shell thickness Shell 0.167 in. Head thickness Head 0.150 in. Tank builders initials ABC. Date of original test 00-0000. Outer shell: Material ASTM A285-C. Tank builders initials WYZ...

Free and Forced Vibrations of Thick-Walled Anisotropic Cylindrical Shells

NASA Astrophysics Data System (ADS)

Marchuk, A. V.; Gnedash, S. V.; Levkovskii, S. A.

2017-03-01

Two approaches to studying the free and forced axisymmetric vibrations of cylindrical shell are proposed. They are based on the three-dimensional theory of elasticity and division of the original cylindrical shell with concentric cross-sectional circles into several coaxial cylindrical shells. One approach uses linear polynomials to approximate functions defined in plan and across the thickness. The other approach also uses linear polynomials to approximate functions defined in plan, but their variation with thickness is described by the analytical solution of a system of differential equations. Both approaches have approximation and arithmetic errors. When determining the natural frequencies by the semi-analytical finite-element method in combination with the divide and conqure method, it is convenient to find the initial frequencies by the finite-element method. The behavior of the shell during free and forced vibrations is analyzed in the case where the loading area is half the shell thickness

Effects of zonal flows on correlation between energy balance and energy conservation associated with nonlinear nonviscous atmospheric dynamics in a thin rotating spherical shell

NASA Astrophysics Data System (ADS)

Ibragimov, Ranis N.

2018-03-01

The nonlinear Euler equations are used to model two-dimensional atmosphere dynamics in a thin rotating spherical shell. The energy balance is deduced on the basis of two classes of functorially independent invariant solutions associated with the model. It it shown that the energy balance is exactly the conservation law for one class of the solutions whereas the second class of invariant solutions provides and asymptotic convergence of the energy balance to the conservation law.

Effect of multiple spin species on spherical shell neutron transmission analysis

NASA Technical Reports Server (NTRS)

Semler, T. T.

1972-01-01

A series of Monte Carlo calculations were performed in order to evaluate the effect of separated against merged spin statistics on the analysis of spherical shell neutron transmission experiments for gold. It is shown that the use of separated spin statistics results in larger average capture cross sections of gold at 24 KeV. This effect is explained by stronger windows in the total cross section caused by the interference between potential and J(+) resonances and by J(+) and J(-) resonance overlap allowed by the use of separated spin statistics.

A vectorized Poisson solver over a spherical shell and its application to the quasi-geostrophic omega-equation

NASA Technical Reports Server (NTRS)

Mullenmeister, Paul

1988-01-01

The quasi-geostrophic omega-equation in flux form is developed as an example of a Poisson problem over a spherical shell. Solutions of this equation are obtained by applying a two-parameter Chebyshev solver in vector layout for CDC 200 series computers. The performance of this vectorized algorithm greatly exceeds the performance of its scalar analog. The algorithm generates solutions of the omega-equation which are compared with the omega fields calculated with the aid of the mass continuity equation.

Room-temperature ferromagnetic Cr-doped Ge/GeOx core-shell nanowires.

PubMed

Katkar, Amar S; Gupta, Shobhnath P; Seikh, Md Motin; Chen, Lih-Juann; Walke, Pravin S

2018-06-08

The Cr-doped tunable thickness core-shell Ge/GeO x nanowires (NWs) were synthesized and characterized using x-ray diffraction, field-emission scanning electron microscopy, transmission electron microscopy, energy-dispersive x-ray spectroscopy, x-ray photoelectron spectroscopy and magnetization studies. The shell thickness increases with the increase in synthesis temperature. The presence of metallic Cr and Cr 3+ in core-shell structure was confirmed from XPS study. The magnetic property is highly sensitive to the core-shell thickness and intriguing room temperature ferromagnetism is realized only in core-shell NWs. The magnetization decreases with an increase in shell thickness and practically ceases to exist when there is no core. These NWs show remarkably high Curie temperature (T C  > 300 K) with the dominating values of its magnetic remanence (M R ) and coercivity (H C ) compared to germanium dilute magnetic semiconductor nanomaterials. We believe that our finding on these Cr-doped Ge/GeO X core-shell NWs has the potential to be used as a hard magnet for future spintronic devices, owing to their higher characteristic values of ferromagnetic ordering.

Room-temperature ferromagnetic Cr-doped Ge/GeOx core–shell nanowires

NASA Astrophysics Data System (ADS)

Katkar, Amar S.; Gupta, Shobhnath P.; Motin Seikh, Md; Chen, Lih-Juann; Walke, Pravin S.

2018-06-01

The Cr-doped tunable thickness core–shell Ge/GeOx nanowires (NWs) were synthesized and characterized using x-ray diffraction, field-emission scanning electron microscopy, transmission electron microscopy, energy-dispersive x-ray spectroscopy, x-ray photoelectron spectroscopy and magnetization studies. The shell thickness increases with the increase in synthesis temperature. The presence of metallic Cr and Cr3+ in core–shell structure was confirmed from XPS study. The magnetic property is highly sensitive to the core–shell thickness and intriguing room temperature ferromagnetism is realized only in core–shell NWs. The magnetization decreases with an increase in shell thickness and practically ceases to exist when there is no core. These NWs show remarkably high Curie temperature (TC > 300 K) with the dominating values of its magnetic remanence (MR) and coercivity (HC) compared to germanium dilute magnetic semiconductor nanomaterials. We believe that our finding on these Cr-doped Ge/GeOX core–shell NWs has the potential to be used as a hard magnet for future spintronic devices, owing to their higher characteristic values of ferromagnetic ordering.

A Nonlinear Theory of Bending and Buckling of Thin Elastic Shallow Spherical Shells

NASA Technical Reports Server (NTRS)

Kaplan, A; Fung, Y C

1954-01-01

The problem of the finite displacement and buckling, of a shallow spherical dome is investigated both theoretically and experimentally. Experimental results seem to indicate that the classical criterion of buckling is applicable to very shallow spherical domes for which the theoretical calculation was made. A transition to energy criterion for higher domes is also indicated.

The sagitta and lens thickness: the exact solution and a matrix approximation for lenses with toric, spherical, and cylindrical surfaces.

PubMed

Harris, W F

1989-03-01

The exact equation for sagitta of spherical surfaces is generalized to toric surfaces which include spherical and cylindrical surfaces as special cases. Lens thickness, therefore, can be calculated accurately anywhere on a lens even in cases of extreme spherical and cylindrical powers and large diameters. The sagittae of tire- and barrel-form toric surfaces differ off the principal meridians, as is shown by a numerical example. The same holds for pulley- and capstan-form toric surfaces. A general expression is given for thickness at an arbitrary point on a toric lens. Approximate expressions are derived and re-expressed in terms of matrices. The matrix provides an elegant means of generalizing equations for spherical surfaces and lenses to toric surfaces and lenses.

Influence of Shell Thickness on the Colloidal Stability of Magnetic Core-Shell Particle Suspensions

PubMed Central

Neville, Frances; Moreno-Atanasio, Roberto

2018-01-01

We present a Discrete Element study of the behavior of magnetic core-shell particles in which the properties of the core and the shell are explicitly defined. Particle cores were considered to be made of pure iron and thus possessed ferromagnetic properties, while particle shells were considered to be made of silica. Core sizes ranged between 0.5 and 4.0 μm with the actual particle size of the core-shell particles in the range between 0.6 and 21 μm. The magnetic cores were considered to have a magnetization of one tenth of the saturation magnetization of iron. This study aimed to understand how the thickness of the shell hinders the formation of particle chains. Chain formation was studied with different shell thicknesses and particle sizes in the presence and absence of an electrical double layer force in order to investigate the effect of surface charge density on the magnetic core-shell particle interactions. For core sizes of 0.5 and 4.0 μm the relative shell thicknesses needed to hinder the aggregation process were approximately 0.4 and 0.6 respectively, indicating that larger core sizes are detrimental to be used in applications in which no flocculation is needed. In addition, the presence of an electrical double layer, for values of surface charge density of less than 20 mC/m2, could stop the contact between particles without hindering their vertical alignment. Only when the shell thickness was considerably larger, was the electrical double layer able to contribute to the full disruption of the magnetic flocculation process. PMID:29922646

Influence of Shell Thickness on the Colloidal Stability of Magnetic Core-Shell Particle Suspensions.

PubMed

Neville, Frances; Moreno-Atanasio, Roberto

2018-01-01

We present a Discrete Element study of the behavior of magnetic core-shell particles in which the properties of the core and the shell are explicitly defined. Particle cores were considered to be made of pure iron and thus possessed ferromagnetic properties, while particle shells were considered to be made of silica. Core sizes ranged between 0.5 and 4.0 μm with the actual particle size of the core-shell particles in the range between 0.6 and 21 μm. The magnetic cores were considered to have a magnetization of one tenth of the saturation magnetization of iron. This study aimed to understand how the thickness of the shell hinders the formation of particle chains. Chain formation was studied with different shell thicknesses and particle sizes in the presence and absence of an electrical double layer force in order to investigate the effect of surface charge density on the magnetic core-shell particle interactions. For core sizes of 0.5 and 4.0 μm the relative shell thicknesses needed to hinder the aggregation process were approximately 0.4 and 0.6 respectively, indicating that larger core sizes are detrimental to be used in applications in which no flocculation is needed. In addition, the presence of an electrical double layer, for values of surface charge density of less than 20 mC/m 2 , could stop the contact between particles without hindering their vertical alignment. Only when the shell thickness was considerably larger, was the electrical double layer able to contribute to the full disruption of the magnetic flocculation process.

Dynamics of Inhomogeneous Shell Systems Under Non-Stationary Loading (Survey)

NASA Astrophysics Data System (ADS)

Lugovoi, P. Z.; Meish, V. F.

2017-09-01

Experimental works on the determination of dynamics of smooth and stiffened cylindrical shells contacting with a soil medium under various non-stationary loading are reviewed. The results of studying three-layer shells of revolution whose motion equations are obtained within the framework of the hypotheses of the Timoshenko geometrically nonlinear theory are stated. The numerical results for shells with a piecewise or discrete filler enable the analysis of estimation of the influence of geometrical and physical-mechanical parameters of structures on their dynamics and reveal new mechanical effects. Basing on the classical theory of shells and rods, the effect of the discrete arrangement of ribs and coefficients of the Winkler or Pasternak elastic foundation on the normal frequencies and modes of rectangular planar cylindrical and spherical shells is studied. The number and shape of dispersion curves for longitudinal harmonic waves in a stiffened cylindrical shell are determined. The equations of vibrations of ribbed shells of revolution on Winkler or Pasternak elastic foundation are obtained using the geometrically nonlinear theory and the Timoshenko hypotheses. On applying the integral-interpolational method, numerical algorithms are developed and the corresponding non-stationary problems are solved. The special attention is paid to the statement and solution of coupled problems on the dynamical interaction of cylindrical or spherical shells with the soil water-saturated medium of different structure.

Tidal dissipation in the subsurface ocean of Enceladus

NASA Astrophysics Data System (ADS)

Matsuyama, I.; Hay, H.; Nimmo, F.; Kamata, S.

2017-12-01

Icy satellites of the outer solar system have emerged as potential habitable worlds due to the presence of subsurface oceans. As a long-term energy source, tidal heating in these oceans can influence the survivability of subsurface oceans, and the thermal, rotational, and orbital evolution of these satellites. Additionally, the spatial and temporal variation of tidal heating has implications for the interior structure and spacecraft observations. Previous models for dissipation in thin oceans are not generally applicable to icy satellites because either they ignore the presence of an overlying solid shell or use a thin shell membrane approximation. We present a new theoretical treatment for tidal dissipation in thin oceans with overlying shells of arbitrary thickness and apply it to Enceladus. The shell's resistance to ocean tides increases with shell thickness, reducing tidal dissipation as expected. Both the magnitude of energy dissipation and the resonant ocean thicknesses decrease as the overlying shell thickness increases, as previously shown using a membrane approximation. In contrast to previous work based on the traditional definition of the tidal quality factor, Q, our new definition is consistent with higher energy dissipation for smaller Q, and introduces a lower limit on Q. The dissipated power and tides are not in phase with the forcing tidal potential due to the delayed ocean response. The phase lag depends on the Rayleigh friction coefficient and ocean and shell thicknesses, which implies that phase lag observations can be used to constrain these parameters. Eccentricity heating produces higher dissipation near the poles, while obliquity heating produces higher dissipation near the equator, in contrast to the dissipation patterns in the shell. The time-averaged surface distribution of tidal heating can generate lateral shell thickness variations, providing an additional constraint on the Rayleigh friction coefficient. Explaining the endogenic power radiated from the south polar terrain requires shell thicknesses smaller than about 1 km, a value that is not consistent with recent libration, gravity and topography constraints.

Fast synthesis, formation mechanism, and control of shell thickness of CuS–polystyrene core–shell microspheres

DOE Office of Scientific and Technical Information (OSTI.GOV)

Zhao, Li-min, E-mail: zhaolimin@lcu.ecu.cn; Shao, Xin; Yin, Yi-bin

2012-09-15

Graphical abstract: Core–shell structure PSt/CuS were prepared using polystyrene which were modified by 3-methacryloxypropyltrimethoxysilane as template. The coating thickness of CuS can be controlled by the amount of 3-methacryloxypropyltrimethoxysilane and the UV–vis absorption intensity of PSt/CuS composite also changed with the coating thickness of CuS. Highlights: ► Core–shell structure PSt/CuS were prepared using silanol-modified polystyrene microspheres as template. ► The coating thickness of core–shell structure PSt/CuS can be controlled by a simple method. ► The UV–vis absorption intensity of PSt/CuS composite also changed with the coating thickness of CuS. -- Abstract: The silanol-modified polystyrene microspheres were prepared through dispersion polymerization.more » Then copper sulfide particles were grown on silanol-modified polystyrene through sonochemical deposition in an aqueous bath containing copper acetate and sulfide, released through the hydrolysis of thioacetamide. The resulting particles were continuous and uniform as characterized by scanning electron microscopy (SEM) and transmission electron microscopy (TEM). Fourier transform infrared, thermogravimetric analysis and UV–vis absorption spectroscopy were used to characterize the structure and properties of core–shell particles. The results showed the coating thickness of CuS shell can be controlled by the amount of silanol and the UV–vis absorption intensity of PSt/CuS composite also changed with the coating thickness of CuS.« less

One-dimensional MHD simulations of MTF systems with compact toroid targets and spherical liners

NASA Astrophysics Data System (ADS)

Khalzov, Ivan; Zindler, Ryan; Barsky, Sandra; Delage, Michael; Laberge, Michel

2017-10-01

One-dimensional (1D) MHD code is developed in General Fusion (GF) for coupled plasma-liner simulations in magnetized target fusion (MTF) systems. The main goal of these simulations is to search for optimal parameters of MTF reactor, in which spherical liquid metal liner compresses compact toroid plasma. The code uses Lagrangian description for both liner and plasma. The liner is represented as a set of spherical shells with fixed masses while plasma is discretized as a set of nested tori with circular cross sections and fixed number of particles between them. All physical fields are 1D functions of either spherical (liner) or small toroidal (plasma) radius. Motion of liner and plasma shells is calculated self-consistently based on applied forces and equations of state. Magnetic field is determined by 1D profiles of poloidal and toroidal fluxes - they are advected with shells and diffuse according to local resistivity, this also accounts for flux leakage into the liner. Different plasma transport models are implemented, this allows for comparison with ongoing GF experiments. Fusion power calculation is included into the code. We performed a series of parameter scans in order to establish the underlying dependencies of the MTF system and find the optimal reactor design point.

Optical and UV Spectra of the Remnant of SN 1885 (S And) in M31

NASA Astrophysics Data System (ADS)

Fesen, Robert A.; Weil, Kathryn E.; Hamilton, Andrew J. S.; Höflich, Peter A.

2017-10-01

We present multi-slit, 1D and 2D optical and UV spectra of the remnant of supernova 1885 (SN 1885; S And) taken using the Hubble Space Telescope’s Imaging Spectrograph (HST/STIS). These spectra of this probable subluminous Type Ia remnant, seen in silhouette against the central bulge of the Andromeda galaxy (M31), show strong and broad absorptions from neutral and singly ionized species of calcium, magnesium, and iron but with strikingly different distributions. Calcium H and K absorption indicates spherically distributed Ca-rich ejecta, densest in a lumpy shell expanding at 2000-6000 km s-1. Equally broad but weaker Ca I 4227 Å absorption is seen to extend out to velocities of ˜13,000 km s-1. Magnesium-rich ejecta in the remnant are detected for the first time through Mg I 2852 Å and Mg II 2796, 2803 Å absorptions concentrated in a shell with expansion velocities from ≃ 7000 {km} {{{s}}}-1 to at least 10,000 km s-1. Fe I 3720 Å absorption is detected as two discrete blueshifted and redshifted absorptions suggestive of an Fe I shell with expansion velocities of ±2000-8000 km s-1. Weak Fe II resonance absorptions in the wavelength region 2300-2700 Å are consistent with prior HST UV images showing Fe II-rich ejecta confined to a small number of optically thick plumes. The presence of such iron plumes extending out from the remnant’s core plus layered shells of calcium and magnesium point to a delayed-detonation explosion. The spectra also suggest a roughly spherical explosion, contrary to that expected by a merger or collision of two white dwarfs. We conclude that SN 1885 likely was an off-center, delayed-detonation explosion leading to a subluminous SN Ia similar to SN 1986G. Based on observations with the NASA/ESA Hubble Space Telescope, obtained at the Space Telescope Science Institute, which is operated by the Association of Universities for Research in Astronomy, Inc., under NASA contract No. NAS5-26555.

Gesellschaft fuer angewandte Mathematik und Mechanik, Scientific Annual Meeting, Universitaet Hannover, Hanover, Federal Republic of Germany, Apr. 8-12, 1990, Reports

NASA Astrophysics Data System (ADS)

Various papers on applied mathematics and mechanics are presented. Among the individual topics addressed are: dynamical systems with time-varying or unsteady structure, micromechanical modeling of creep rupture, forced vibrations of elastic sandwich plates with thick surface layers, postbuckling of a complete spherical shell under a line load, differential-geometric approach to the multibody system dynamics, stability of an oscillator with stochastic parametric excitation, identification strategies for crack-formation in rotors, identification of physical parameters of FEMs, impact model for elastic and partly plastic impacts on objects, varying delay and stability in dynamical systems. Also discussed are: parameter identification of a hybrid model for vibration analysis using the FEM, vibration behavior of a labyrinth seal with through-flow, similarities in the boundary layer of fiber composite materials, distortion parameter in shell theories, elastoplastic crack problem at finite strain, algorithm for computing effective stiffnesses of plates with periodic structure, plasticity of metal-matrix composites in a mixed stress-strain space formation, constitutive equations in directly formulated plate theories, microbuckling and homogenization for long fiber composites.

Soft resonator of omnidirectional resonance for acoustic metamaterials with a negative bulk modulus

PubMed Central

Jing, Xiaodong; Meng, Yang; Sun, Xiaofeng

2015-01-01

Monopolar resonance is of fundamental importance in the acoustic field. Here, we present the realization of a monopolar resonance that goes beyond the concept of Helmholtz resonators. The balloon-like soft resonator (SR) oscillates omnidirectionally and radiates from all parts of its spherical surface, eliminating the need for a hard wall for the cavity and baffle effects. For airborne sound, such a low-modulus resonator can be made extremely lightweight. Deep subwavelength resonance is achieved when the SR is tuned by adjusting the shell thickness, benefiting from the large density contrast between the shell material and the encapsulated gas. The SR resonates with near-perfect monopole symmetry, as demonstrated by the theoretical and experimental results, which are in excellent agreement. For a lattice of SRs, a band gap occurs and blocks near-total transmission, and the effective bulk modulus exhibits a prominent negative band, while the effective mass density remains unchanged. Our study shows that the SR is suitable for building 3D acoustic metamaterials and provides a basis for constructing left-handed materials as a new means of creating a negative bulk modulus. PMID:26538085

Gyroid Structures at Highly Asymmetric Volume Fractions by Blending of ABC Triblock Terpolymer and AB Diblock Copolymer

DOE Office of Scientific and Technical Information (OSTI.GOV)

Ahn, Seonghyeon; Kwak, Jongheon; Choi, Chungryong

Here, we investigated, via small angle X-ray scattering and transmission electron microscopy, the morphologies of binary blend of polyisoprene- b-polystyrene- b-poly(2-vinylpyridine) (ISP) triblock terpolymer and polyisoprene-b-polystyrene (IS) diblock copolymer. An asymmetric ISP with volume fractions ( f) of 0.12, 0.75, and 0.13 for PI, PS, and P2VP blocks, respectively, showed a new morphology: Coexistence of spheres and cylinders with tetragonal packing. Asymmetric IS with f I = 0.11 and f S =0.89 showed conventional body-centered cubic spherical microdomains. Very interestingly, a binary blend of ISP and IS with overall volume fractions of f I = 0.12, f S = 0.79,more » and f P = 0.09 exhibited core-shell double gyroid (CSG: Q 230 space group), where PI consists of thin core and PS forms thick shell, while P2VP becomes thin matrix. It is very unusual to form highly asymmetric CSG with the matrix having very small volume fraction (0.09).« less

Gyroid Structures at Highly Asymmetric Volume Fractions by Blending of ABC Triblock Terpolymer and AB Diblock Copolymer

DOE PAGES

Ahn, Seonghyeon; Kwak, Jongheon; Choi, Chungryong; ...

2017-11-08

Here, we investigated, via small angle X-ray scattering and transmission electron microscopy, the morphologies of binary blend of polyisoprene- b-polystyrene- b-poly(2-vinylpyridine) (ISP) triblock terpolymer and polyisoprene-b-polystyrene (IS) diblock copolymer. An asymmetric ISP with volume fractions ( f) of 0.12, 0.75, and 0.13 for PI, PS, and P2VP blocks, respectively, showed a new morphology: Coexistence of spheres and cylinders with tetragonal packing. Asymmetric IS with f I = 0.11 and f S =0.89 showed conventional body-centered cubic spherical microdomains. Very interestingly, a binary blend of ISP and IS with overall volume fractions of f I = 0.12, f S = 0.79,more » and f P = 0.09 exhibited core-shell double gyroid (CSG: Q 230 space group), where PI consists of thin core and PS forms thick shell, while P2VP becomes thin matrix. It is very unusual to form highly asymmetric CSG with the matrix having very small volume fraction (0.09).« less

X-ray Thomson scattering measurements of temperature and density from multi-shocked CH capsules

DOE PAGES

Fletcher, L. B.; Glenzer, S. H.; Kritcher, A.; ...

2013-05-24

Proof-of-principle measurements of the electron densities, temperatures, and ionization states of spherically compressed multi-shocked CH (polystyrene) capsules have been achieved using spectrally resolved x-ray Thomson scattering. A total energy of 13.5 kJ incident on target is used to compress a 70 μm thick CH shell above solid-mass density using three coalescing shocks. Separately, a laser-produced zinc He-α x-ray source at 9 keV delayed 200 ps-800 ps after maximum compression is used to probe the plasma in the non-collective scattering regime. The data show that x-ray Thomson scattering enables a complete description of the time-dependent hydrodynamic evolution of shock-compressed CH capsules,more » with a maximum measured density of ρ > 6 g cm –3. Additionally, the results demonstrate that accurate measurements of x-ray scattering from bound-free transitions in the CH plasma demonstrate strong evidence that continuum lowering is the primary ionization mechanism of carbon L-shell electrons.« less

Photophysical Properties of II-VI Semiconductor Nanocrystals

NASA Astrophysics Data System (ADS)

Gong, Ke

As it is well known, semiconductor nanocrystals (also called quantum dots, QDs) are being actively pursued for use in many different types of luminescent optical materials. These materials include the active media for luminescence downconversion in artificial lighting, lasers, luminescent solar concentrators and many other applications. Chapter 1 gives general introduction of QDs, which describe the basic physical properties and optical properties. Based on the experimental spectroscopic study, a semiquantitative method-effective mass model is employed to give theoretical prediction and guide. The following chapters will talks about several topics respectively. A predictive understanding of the radiative lifetimes is therefore a starting point for the understanding of the use of QDs for these applications. Absorption intensities and radiative lifetimes are fundamental properties of any luminescent material. Meantime, achievement of high efficiency with high working temperature and heterostructure fabrication with manipulation of lattice strain are not easy and need systematic investigation. To make accurate connections between extinction coefficients and radiative recombination rates, chapter 2 will consider three closely related aspects of the size dependent spectroscopy of II-VI QDs. First, it will consider the existing literature on cadmium selenide (CdSe) QD absorption spectra and extinction coefficients. From these results and fine structure considerations Boltzmann weighted radiative lifetimes are calculated. These lifetimes are compared to values measured on very high quality CdSe and CdSe coated with zinc selenide (ZnSe) shells. Second, analogous literature data are analyzed for cadmium telluride (CdTe) nanocrystals and compared to lifetimes measured for very high quality QDs. Furthermore, studies of the absorption and excitation spectra and measured radiative lifetimes for CdTe/CdSe Type-II core/shell QDs are reported. These results are also analyzed in terms of a Boltzmann population of exciton sublevels and calculated electron and hole wave functions. Much of the absorption data and fine structure calculations are already in the literature. These results are combined with new measurements of radiative lifetimes and electron-hole overlap calculations to produce an integrated picture of the II-VI QD spectroscopic fundamentals. Finally, we adopt recent synthetic advances to make very monodisperse zincblende CdSe/CdS quantum dots having near-unity photoluminescence quantum yields (PLQYs). Due the absence of nonradiative decay pathways, accurate values of the radiative lifetimes can be obtained from time resolved PL measurements. Radiative lifetimes can also be obtained from the Einstein relations, using the static absorption spectra and the relative thermal populations in the angular momentum sublevels. One of the inputs into these calculations is the shell thickness, and it is useful to be able to determine shell thickness from spectroscopic measurements. We use an empirically corrected effective mass model to produce a "map" of exciton wavelength as a function of core size and shell thickness. These calculations use an elastic continuum model and the known lattice and elastic constants to include the effect of lattice strain on the band gap energy. Radiative lifetimes calculated both experimentally and theoretically are checked and the size dependence is compared to previous studied Type-I, II and single component particles. However, it is not enough to just understanding these basic photophysics of absorption and emission. The emission intensities (related to QYs) also change with changes of the temperature. The temperature dependent PLs of II-VI QDs is extensively studied, but most of this work is at low temperatures. Temperatures well above ambient are of interest to lighting applications and in this regime both the reversible and irreversible loss of quantum yield (thermal quenching) are serious impediments to the implementation of QDs in commercial devices. Chapter 3 will elucidate the mechanism of static thermal quenching, in which the reduction of QYs does not affect the PL decay kinetics, on CdSe, CdTe and CdSe/ZnSe QDs as a function of particle sizes/shapes, surface composition and surface ligands. Through systematic experiments, this part of the dissertation discusses several possible mechanisms (e.g. structural, activated excited state, and electronic charging) and examines which the dominant cause for loss of QY at high temperature is. The more practical step is to develop the synthetic method of highly luminescent and stable core/shell QDs with minimum thermal quenching, which greatly enhance the energy efficiency of light emitting and photovoltaic devices. As the nonradiative Auger processed are induced by surface charging described in chapter 3, static and time-resolved fluorescence and high and low power transient absorption results on CdSe/CdS and CdSe/ZnSe core/shell particles are presented in chapter 4. Two CdS shell thicknesses were examined and all of the particles had either octadecylamine (ODA) and tributylphosphine (TBP) or just ODA ligands. The results can be understood in terms of a mechanism in which there is a thermal equilibrium between electrons being in the valence band or in chalcogenide localized surface states. Thermal promotion of a valence band electron to a surface state leaves the particle core positively charged. Photon absorption when the particle is in this state results in a positive trion, which undergoes a fast Auger recombination, making the particle nonluminescent. A lack of TBP ligands results in more empty surface orbitals and therefore shifts the equilibrium toward surface trapped electrons and hence trion formation. Low- and high-power transient absorption measurements give the trion and biexciton lifetimes and the ratio of the trion to biexciton Auger lifetimes are examined and compared to the degeneracies of Auger pathways. We also study the shell thickness and composition dependence of Auger times, which is compared to the scaling factors of effective volume and electron-hole overlap considerations. Core/shell QDs often exhibit much higher luminescence quantum yields (QYs), more stability, and are depicted as having a nearly spherical core and a shell of very nearly uniform thickness, which results in a very simple picture of surface passivation. The uniformity of the shell is crucial in obtaining QDs with well passivated surfaces. However, transmission electron microscope (TEM) images disprove the ideal situation. Defects and thickness inhomogeneity in shell materials are treated qualitatively as an analog to film thickness inhomogeneity in epitaxially grown thin films. More quantitatively, the extent to which the shell thickness of core/shell particles is constant can be determined by time-resolved PL studies that measure the dynamics of hole tunneling to acceptors that are adsorbed on the shell surface due that tunneling rates varies strongly with core-acceptor separation. Careful analysis of the hole transfer kinetics reveals the extent of shell thickness inhomogeneity, however, it may be complicated by the distribution of numbers of adsorbed acceptors. All the considerations can be incorporated into a model we establish in Chapter 5for the distribution of measured hole tunneling rates. From this analysis the distribution of shell thicknesses can be extracted from the luminescence kinetic results. This approach is therefore a sensitive measure of the distribution of tunneling distances. Thus, any defects or structural irregularities that allow the hole acceptors to adsorb closer to the particle core increases the hole tunneling rate and can be detected and quantified. A quantitative treatment of the lattice strain energy in determining the shell morphology of CdSe/CdS core/shell nanoparticles is presented in chapter 5. We use the inhomogeneity in hole tunneling rates through the shell to adsorbed hole acceptors to quantify the extent of shell thickness inhomogeneity. The results can be understood in terms of a model based on elastic continuum calculations, which indicate that the lattice strain energy depends on both core size and shell thickness. This model assumes thermodynamic equilibrium, i.e., that the shell morphology corresponds to a minimum total (lattice strain plus surface) energy. Comparison with the experimental results indicates that CdSe/CdS nanoparticles undergo an abrupt transition from smooth to rough shells when the total lattice strain energy exceeds about 27eV or the strain energy density exceeds 0.59 eV/nm2. The predictions of this model are not followed for CdSe/CdS nanoparticles when the shell is deposited at very low temperature and therefore equilibrium is not established. The effects of lattice strain on the spectroscopy and photoluminescence quantum yields of zincblende CdSe/CdS core/shell quantum dots are examined. The quantum yields are measured as a function of core size and shell thickness. High quantum yields are achieved as long as the lattice strain energy density is below ~0.85 eV/nm2, which is considerably greater than the limiting value of 0.59 eV/nm2 for thermodynamicstability of a smooth, defect free shell, as previously reported in chapter 5. Thus, core/shell quantum dots having strain energy densities between 0.59 and 0.85 eV/nm2 can have very high PL QYs, but are metastable with respect to surface defect formation. Such metastable core/shell QDs can be produced by shell deposition at comparatively low temperatures (< 140 °C). Annealing of these particles causes partial loss of core pressure, and a red shift of the spectrum.

Heat transport system, method and material

DOEpatents

Musinski, Donald L.

1987-01-01

A heat transport system, method and composite material in which a plurality of hollow spherical shells or microspheres having an outside diameter of less than or equal to 500 microns are encapsulated or embedded within a bulk material. Each shell has captured therein a volatile working fluid, such that each shell operates as a microsized heat pipe for conducting heat through the composite structure.

The jump-off velocity of an impulsively loaded spherical shell

DOE Office of Scientific and Technical Information (OSTI.GOV)

Chabaud, Brandon M.; Brock, Jerry S.

2012-04-13

We consider a constant temperature spherical shell of isotropic, homogeneous, linearly elastic material with density {rho} and Lame coefficients {lambda} and {mu}. The inner and outer radii of the shell are r{sub i} and r{sub o}, respectively. We assume that the inside of the shell is a void. On the outside of the shell, we apply a uniform, time-varying pressure p(t). We also assume that the shell is initially at rest. We want to compute the jump-off time and velocity of the pressure wave, which are the first time after t = 0 at which the pressure wave from themore » outer surface reaches the inner surface. This analysis computes the jump-off velocity and time for both compressible and incompressible materials. This differs substantially from [3], where only incompressible materials are considered. We will consider the behavior of an impulsively loaded, exponentially decaying pressure wave p(t) = P{sub 0{sup e}}{sup -{alpha}t}, where {alpha} {ge} 0. We notice that a constant pressure wave P(t) = P{sub 0} is a special case ({alpha} = 0) of a decaying pressure wave. Both of these boundary conditions are considered in [3].« less

Nutrient Shielding in Clusters of Cells

PubMed Central

Lavrentovich, Maxim O.; Koschwanez, John H.; Nelson, David R.

2014-01-01

Cellular nutrient consumption is influenced by both the nutrient uptake kinetics of an individual cell and the cells’ spatial arrangement. Large cell clusters or colonies have inhibited growth at the cluster's center due to the shielding of nutrients by the cells closer to the surface. We develop an effective medium theory that predicts a thickness ℓ of the outer shell of cells in the cluster that receives enough nutrient to grow. The cells are treated as partially absorbing identical spherical nutrient sinks, and we identify a dimensionless parameter ν that characterizes the absorption strength of each cell. The parameter ν can vary over many orders of magnitude between different cell types, ranging from bacteria and yeast to human tissue. The thickness ℓ decreases with increasing ν, increasing cell volume fraction ϕ, and decreasing ambient nutrient concentration ψ∞. The theoretical results are compared with numerical simulations and experiments. In the latter studies, colonies of budding yeast, Saccharomyces cerevisiae, are grown on glucose media and imaged under a confocal microscope. We measure the growth inside the colonies via a fluorescent protein reporter and compare the experimental and theoretical results for the thickness ℓ. PMID:23848711

Planetary Ice-Oceans: Numerical Modeling Study of Ice-Shell Growth in Convecting Two-Phase Systems

NASA Astrophysics Data System (ADS)

Allu Peddinti, Divya; McNamara, Allen

2017-04-01

Several icy bodies in the Solar system such as the icy moons Europa and Enceladus exhibit signs of subsurface oceans underneath an ice-shell. For Europa, the geologically young surface, the presence of surface features and the aligned surface chemistry pose interesting questions about formation of the ice-shell and its interaction with the ocean below. This also ties in with its astrobiological potential and implications for similar ice-ocean systems elsewhere in the cosmos. The overall thickness of the H2O layer on Europa is estimated to be 100-150 km while the thickness of the ice-shell is debated. Additionally, Europa is subject to tidal heating due to interaction with Jupiter's immense gravity field. It is of interest to understand how the ice-shell thickness varies in the presence of tidal internal heating and the localization of heating in different regions of the ice-shell. Thus this study aims to determine the effect of tidal internal heating on the growth rate of the ice-shell over time. We perform geodynamic modeling of the ice-ocean system in order to understand how the ice-shell thickness changes with time. The convection code employs the ice Ih-water phase diagram in order to model the two-phase convecting ice-ocean system. All the models begin from an initial warm thick ocean that cools from the top. The numerical experiments analyze three cases: case 1 with no tidal internal heating in the system, case 2 with constant tidal internal heating in the ice and case 3 with viscosity-dependent tidal internal heating in the ice. We track the ice-shell thickness as a function of time as the system cools. Modeling results so far have identified that the shell growth rate changes substantially at a point in time that coincides with a change in the planform of ice-convection cells. Additionally, the velocity vs depth plots indicate a shift from a conduction dominant to a convection dominant ice regime. We compare the three different cases to provide a comprehensive understanding of the temporal variation in the ice-shell thickness due to the addition of heating in the ice.

Probing crustal structures from neutron star compactness

NASA Astrophysics Data System (ADS)

Sotani, Hajime; Iida, Kei; Oyamatsu, Kazuhiro

2017-10-01

With various sets of the parameters that characterize the equation of state (EOS) of nuclear matter, we systematically examine the thickness of a neutron star crust and of the pasta phases contained therein. Then, with respect to the thickness of the phase of spherical nuclei, the thickness of the cylindrical phase and the crust thickness, we successfully derive fitting formulas that express the ratio of each thickness to the star's radius as a function of the star's compactness, the incompressibility of symmetric nuclear matter and the density dependence of the symmetry energy. In particular, we find that the thickness of the phase of spherical nuclei has such a strong dependence on the stellar compactness as the crust thickness, but both of them show a much weaker dependence on the EOS parameters. Thus, via determination of the compactness, the thickness of the phase of spherical nuclei as well as the crust thickness can be constrained reasonably, even if the EOS parameters remain to be well-determined.

Tube wall thickness measurement apparatus

DOEpatents

Lagasse, P.R.

1985-06-21

An apparatus for measuring the thickness of a tube's wall for the tube's entire length and radius by determining the deviation of the tube wall thickness from the known thickness of a selected standard item. The apparatus comprises a base and a first support member having first and second ends. The first end is connected to the base and the second end is connected to a spherical element. A second support member is connected to the base and spaced apart from the first support member. A positioning element is connected to and movable relative to the second support member. An indicator is connected to the positioning element and is movable to a location proximate the spherical element. The indicator includes a contact ball for first contacting the selected standard item and holding it against the spherical element. The contact ball then contacts the tube when the tube is disposed about the spherical element. The indicator includes a dial having a rotatable needle for indicating the deviation of the tube wall thickness from the thickness of the selected standard item.

Tube wall thickness measurement apparatus

DOEpatents

Lagasse, Paul R.

1987-01-01

An apparatus for measuring the thickness of a tube's wall for the tube's entire length and circumference by determining the deviation of the tube wall thickness from the known thickness of a selected standard item. The apparatus comprises a base and a first support member having first and second ends. The first end is connected to the base and the second end is connected to a spherical element. A second support member is connected to the base and spaced apart from the first support member. A positioning element is connected to and movable relative to the second support member. An indicator is connected to the positioning element and is movable to a location proximate the spherical element. The indicator includes a contact ball for first contacting the selected standard item and holding it against the spherical element. The contact ball then contacts the tube when the tube is disposed about the spherical element. The indicator includes a dial having a rotatable needle for indicating the deviation of the tube wall thickness from the thickness of the selected standard item.

First-Ply-Failure Performance of Composite Clamped Spherical Shells

NASA Astrophysics Data System (ADS)

Ghosh, A.; Chakravorty, D.

2018-05-01

The failure aspects of composites are available for plates, but studies of the literature on shells unveils that similar reports on them are very limited in number. The aim of this work was to investigate the first-ply-failure of industrially and aesthetically important spherical shells under uniform loadings. Apart from solving benchmark problems, numerical experiments were carried out with different variations of their parameters to obtain the first-ply-failure stresses by using the finite-element method. The load was increased in steps, and the lamina strains and stresses were put into well-established failure criteria to evaluate their first-ply-failure stress, the failed ply, the point of initiation of failure, and failure modes and tendencies. The results obtained are analyzed to extract the points of engineering significance.

Spherical collapse in chameleon models

DOE Office of Scientific and Technical Information (OSTI.GOV)

Brax, Ph.; Rosenfeld, R.; Steer, D.A., E-mail: brax@spht.saclay.cea.fr, E-mail: rosenfel@ift.unesp.br, E-mail: daniele.steer@apc.univ-paris7.fr

2010-08-01

We study the gravitational collapse of an overdensity of nonrelativistic matter under the action of gravity and a chameleon scalar field. We show that the spherical collapse model is modified by the presence of a chameleon field. In particular, we find that even though the chameleon effects can be potentially large at small scales, for a large enough initial size of the inhomogeneity the collapsing region possesses a thin shell that shields the modification of gravity induced by the chameleon field, recovering the standard gravity results. We analyse the behaviour of a collapsing shell in a cosmological setting in themore » presence of a thin shell and find that, in contrast to the usual case, the critical density for collapse in principle depends on the initial comoving size of the inhomogeneity.« less

Magnetization processes in core/shell exchange-spring structures.

DOE Office of Scientific and Technical Information (OSTI.GOV)

Jiang, J. S.

2015-03-27

The magnetization reversal processes in cylindrical and spherical soft core/hard shell exchange-spring structures are investigated via the analytical nucleation theory, and are verified with numerical micromagnetic simulations. At small core sizes, the nucleation of magnetic reversal proceeds via the modified bulging mode, where the transverse component of the magnetization is only semi-coherent in direction and the nucleation field contains a contribution from self-demagnetization. For large core sizes, the modified curling mode, where the magnetization configuration is vortex-like, is favored at nucleation. The preference for the modified curling mode is beneficial in that the fluxclosure allows cylindrical and spherical core/shell exchange-springmore » elements to be densely packed into bulk permanent magnets without affecting the nucleation field, thereby offering the potential for high energy product.« less

The Design of 3D-Printed Lattice-Reinforced Thickness-Varying Shell Molds for Castings.

PubMed

Shangguan, Haolong; Kang, Jinwu; Yi, Jihao; Zhang, Xiaochuan; Wang, Xiang; Wang, Haibin; Huang, Tao

2018-03-30

3D printing technologies have been used gradually for the fabrication of sand molds and cores for castings, even though these molds and cores are dense structures. In this paper, a generation method for lattice-reinforced thickness-varying shell molds is proposed and presented. The first step is the discretization of the STL (Stereo Lithography) model of a casting into finite difference meshes. After this, a shell is formed by surrounding the casting with varying thickness, which is roughly proportional to the surface temperature distribution of the casting that is acquired by virtually cooling it in the environment. A regular lattice is subsequently constructed to support the shell. The outside surface of the shell and lattice in the cubic mesh format is then converted to STL format to serve as the external surface of the new shell mold. The internal surface of the new mold is the casting's surface with the normals of all of the triangles in STL format reversed. Experimental verification was performed on an Al alloy wheel hub casting. Its lattice-reinforced thickness-varying shell mold was generated by the proposed method and fabricated by the binder jetting 3D printing. The poured wheel hub casting was sound and of good surface smoothness. The cooling rate of the wheel hub casting was greatly increased due to the shell mold structure. This lattice-reinforced thickness-varying shell mold generation method is of great significance for mold design for castings to achieve cooling control.

The Design of 3D-Printed Lattice-Reinforced Thickness-Varying Shell Molds for Castings

PubMed Central

Shangguan, Haolong; Kang, Jinwu; Yi, Jihao; Zhang, Xiaochuan; Wang, Xiang; Wang, Haibin; Huang, Tao

2018-01-01

3D printing technologies have been used gradually for the fabrication of sand molds and cores for castings, even though these molds and cores are dense structures. In this paper, a generation method for lattice-reinforced thickness-varying shell molds is proposed and presented. The first step is the discretization of the STL (Stereo Lithography) model of a casting into finite difference meshes. After this, a shell is formed by surrounding the casting with varying thickness, which is roughly proportional to the surface temperature distribution of the casting that is acquired by virtually cooling it in the environment. A regular lattice is subsequently constructed to support the shell. The outside surface of the shell and lattice in the cubic mesh format is then converted to STL format to serve as the external surface of the new shell mold. The internal surface of the new mold is the casting’s surface with the normals of all of the triangles in STL format reversed. Experimental verification was performed on an Al alloy wheel hub casting. Its lattice-reinforced thickness-varying shell mold was generated by the proposed method and fabricated by the binder jetting 3D printing. The poured wheel hub casting was sound and of good surface smoothness. The cooling rate of the wheel hub casting was greatly increased due to the shell mold structure. This lattice-reinforced thickness-varying shell mold generation method is of great significance for mold design for castings to achieve cooling control. PMID:29601543

SOME ENGINEERING PROPERTIES OF SHELLED AND KERNEL TEA (Camellia sinensis) SEEDS.

PubMed

Altuntas, Ebubekir; Yildiz, Merve

2017-01-01

Camellia sinensis is the source of tea leaves and it is an economic crop now grown around the World. Tea seed oil has been used for cooking in China and other Asian countries for more than a thousand years. Tea is the most widely consumed beverages after water in the world. It is mainly produced in Asia, central Africa, and exported throughout the World. Some engineering properties (size dimensions, sphericity, volume, bulk and true densities, friction coefficient, colour characteristics and mechanical behaviour as rupture force of shelled and kernel tea ( Camellia sinensis ) seeds were determined in this study. This research was carried out for shelled and kernel tea seeds. The shelled tea seeds used in this study were obtained from East-Black Sea Tea Cooperative Institution in Rize city of Turkey. Shelled and kernel tea seeds were characterized as large and small sizes. The average geometric mean diameter and seed mass of the shelled tea seeds were 15.8 mm, 10.7 mm (large size); 1.47 g, 0.49 g (small size); while the average geometric mean diameter and seed mass of the kernel tea seeds were 11.8 mm, 8 mm for large size; 0.97 g, 0.31 g for small size, respectively. The sphericity, surface area and volume values were found to be higher in a larger size than small size for the shelled and kernel tea samples. The shelled tea seed's colour intensity (Chroma) were found between 59.31 and 64.22 for large size, while the kernel tea seed's chroma values were found between 56.04 68.34 for large size, respectively. The rupture force values of kernel tea seeds were higher than shelled tea seeds for the large size along X axis; whereas, the rupture force values of along X axis were higher than Y axis for large size of shelled tea seeds. The static coefficients of friction of shelled and kernel tea seeds for the large and small sizes higher values for rubber than the other friction surfaces. Some engineering properties, such as geometric mean diameter, sphericity, volume, bulk and true densities, the coefficient of friction, L*, a*, b* colour characteristics and rupture force of shelled and kernel tea ( Camellia sinensis ) seeds will serve to design the equipment used in postharvest treatments.

Problems in understanding the structure and assembly of viruses

DOE Office of Scientific and Technical Information (OSTI.GOV)

King, J.

1997-12-01

Though viruses infect the cells of all groups of animals, plants, and microorganisms, their structures follow a limited number of general themes; spherical or cylindrical shells built of hundreds of repeated protein subunits enclosing a nucleic acid - DNA or RNA - genome. Since the 1960s it has been known that the protein shells of spherical viruses in fact conform to icosahedral symmetry or to subtle deviations from icosahedral symmetry. The construction of the shell lattices and the transformations they go through in the different stages of the viral life cycle are not fully understood. The shells contain the nucleicmore » in a highly condensed state, of unknown coiling/organization. Features of the well studied bacterial viruses will be reviewed, with examples from adenoviruses, herpesviruses, poliovirus, and HIV. The emergence of new viral disease has led to increased interest in the development of agents which interfere with virus reproduction at the level of the assembly or function of the organized particle. Recently computational approaches to the problem of virus assembly have made important contributions to clarifying shell assembly processes. 1 ref.« less

Using a novel rigid-fluoride polymer to control the interfacial thickness of graphene and tailor the dielectric behavior of poly(vinylidene fluoride-trifluoroethylene-chlorotrifluoroethylene) nanocomposites.

PubMed

Han, Xianghui; Chen, Sheng; Lv, Xuguang; Luo, Hang; Zhang, Dou; Bowen, Chris R

2018-01-24

Polymer nanocomposites based on conductive fillers for high performance dielectrics have attracted increasing attention in recent years. However, a number of physical issues are unclear, such as the effect of interfacial thickness on the dielectric properties of the polymer nanocomposites, which limits the enhancement of permittivity. In this research, two core-shell structured reduced graphene oxide (rGO)@rigid-fluoro-polymer conducting fillers with different shell thicknesses are prepared using a surface-initiated reversible-addition-fragmentation chain transfer polymerization method, which are denoted as rGO@PTFMS-1 with a thin shell and rGO@PTFMS-2 with a thick shell. A rigid liquid crystalline fluoride-polymer poly{5-bis[(4-trifluoro-methoxyphenyl)oxycarbonyl]styrene} (PTFMS) is chosen for the first time to tailor the shell thicknesses of rGO via tailoring the degree of polymerization. The effect of interfacial thickness on the dielectric behavior of the P(VDF-TrFE-CTFE) nanocomposites with rGO and modified rGO is studied in detail. The results demonstrate that the percolation threshold of the nanocomposites increased from 0.68 vol% to 1.69 vol% with an increase in shell thickness. Compared to the rGO@PTFMS-1/P(VDF-TrFE-CTFE) composites, the rGO@PTFMS-2/P(VDF-TrFE-CTFE) composites exhibited a higher breakdown strength and a lower dielectric constant, which can be interpreted by interfacial polarization and the micro-capacitor model, resulting from the insulating nature of the rigid-polymer shell and the change of rGO's morphology. The findings provide an innovative approach to tailor dielectric composites, and promote a deeper understanding of the influence of interfacial region thickness on the dielectric performance.

Thickness Constraints on the Icy Shells of the Galilean Satellites from a Comparison of Crater Shapes

NASA Technical Reports Server (NTRS)

Schenk, Paul M.

2002-01-01

A thin outer ice shell on Jupiter's large moon Europa would imply easy exchange between the surface and any organic or biotic material in its putative subsurface ocean. The thickness of the outer ice shell is poorly constrained, however, with model-dependent estimates ranging from a few kilometers of depths of impact craters on Europa, Ganymede and Callisto that reveal two anomalous transitions in crater shape with diameter. The first transition is probably related to temperature-dependent ductility of the crust at shallow depths (7-8 km on Europa). The second transition is attributed to the influence of subsurface oceans on all three satellites, which constrains Europa's icy shell to be at least 19 km thick. The icy lithospheres of Ganymede and Callisto are equally ice-rich, but Europa's icy shell has a thermal structure about 0.25-0.5 times the thickness of Ganymede's or Callisto's shells, depending on epoch. The appearances of the craters on Europa are inconsistent with thin-ice-shell models and indicate that exchange of oceanic and surface material could be difficult.

Effect of shell thickness on the exchange bias blocking temperature and coercivity in Co-CoO core-shell nanoparticles

NASA Astrophysics Data System (ADS)

Thomas, S.; Reethu, K.; Thanveer, T.; Myint, M. T. Z.; Al-Harthi, S. H.

2017-08-01

The exchange bias blocking temperature distribution of naturally oxidized Co-CoO core-shell nanoparticles exhibits two distinct signatures. These are associated with the existence of two magnetic entities which are responsible for the temperature dependence of an exchange bias field. One is from the CoO grains which undergo thermally activated magnetization reversal. The other is from the disordered spins at the Co-CoO interface which exhibits spin-glass-like behavior. We investigated the oxide shell thickness dependence of the exchange bias effect. For particles with a 3 nm thick CoO shell, the predominant contribution to the temperature dependence of exchange bias is the interfacial spin-glass layer. On increasing the shell thickness to 4 nm, the contribution from the spin-glass layer decreases, while upholding the antiferromagnetic grain contribution. For samples with a 4 nm CoO shell, the exchange bias training was minimal. On the other hand, 3 nm samples exhibited both the training effect and a peak in coercivity at an intermediate set temperature Ta. This is explained using a magnetic core-shell model including disordered spins at the interface.

Shell thickness-dependent antibacterial activity and biocompatibility of gold@silver core–shell nanoparticles

USDA-ARS?s Scientific Manuscript database

Antimicrobial activity of silver is highly effective and broad-spectrum; however, poor long-term antibacterial efficiency and cytotoxicity toward mammalian cells have restricted their applications. Here, we fabricated Au@Ag NPs with tailored shell thickness, and investigated their antibacterial acti...

The design and synthesis of heterostructured quantum dots with dual emission in the visible and infrared

DOE PAGES

Lin, Qianglu; Makarov, Nikolay S.; Koh, Weon-kyu; ...

2014-11-26

The unique optical properties exhibited by visible emitting core/shell quantum dots with especially thick shells are the focus of widespread study, but have yet to be realized in infrared (IR) -active nanostructures. We apply an effective-mass model to identify PbSe/CdSe core/shell quantum dots as a promising system for achieving this goal. We then synthesize colloidal PbSe/CdSe quantum dots with shell thicknesses of up to 4 nm that exhibit unusually slow hole intra-band relaxation from shell to core states, as evidenced by the emergence of dual emission, i.e., IR photoluminescence from the PbSe core observed simultaneously with visible emission from themore » CdSe shell. In addition to the large shell thickness, the development of slowed intraband relaxation is facilitated by the existence of a sharp core-shell interface without discernible alloying. Growth of thick shells without interfacial alloying or incidental formation of homogenous CdSe nanocrystals was accomplished using insights attained via a systematic study of the dynamics of the cation-exchange synthesis of both PbSe/CdSe as well as the related system PbS/CdS. Finally, we show that the efficiency of the visible photoluminescence can be greatly enhanced by inorganic passivation.« less

Models of Interacting Stellar Winds

NASA Astrophysics Data System (ADS)

Wilkin, Francis Patrick

Stars drive supersonic winds which interact violently with their surroundings. Analytic and numerical models of hypersonic, interacting circumstellar flows are presented for several important astrophysical problems. A new solution method for steady-state, axisymmetric, wind collision problems is applied to radiative bow shocks from moving stars and to the collision of two spherical winds in a binary star system. The solutions obtained describe the shape of the geometrically thin, shocked shell of matter, as well as its mass surface density and the tangential velocity within it. Analytic solutions are also obtained for non-axisymmetric bow shocks, where the asymmetry arises due to either a transverse gradient in the ambient medium, or a misaligned, axisymmetric stellar wind. While the solutions are all easily scaled in terms of their relevant dimensional parameters, the important assumption of radiative shocks implies that the models are most applicable towards systems with dense environments and low preshock velocities. The bow shock model has previously been applied to cometary, ultracompact HII regions by Van Buren et al. (1990), who discussed extensively the applicability of the thin shell approximation. I next model the collision between a protostellar wind and supersonic infall from a rotating cloud, employing a quasi-steady, thin-shell formulation. The spherical wind is initially crushed to the protostellar surface by nearly spherical infall. The centrifugal distortion of infalling matter eventually permits a wind-supported, trapped bubble to slowly expand on an evolutionary (~ 105 yr) time. The shell becomes progressively more extended along the rotational axis, due to the asymmetry of the infall. When the quasi-steady assumption breaks down, the shell has become a needle-like, bipolar configuration that may represent a precursor to protostellar jets. I stress, however, the likelihood of instability for the shell, and the possibility of oscillatory behavior in a fully time-dependent model.

Thermal invisibility based on scattering cancellation and mantle cloaking

PubMed Central

Farhat, M.; Chen, P.-Y.; Bagci, H.; Amra, C.; Guenneau, S.; Alù, A.

2015-01-01

We theoretically and numerically analyze thermal invisibility based on the concept of scattering cancellation and mantle cloaking. We show that a small object can be made completely invisible to heat diffusion waves, by tailoring the heat conductivity of the spherical shell enclosing the object. This means that the thermal scattering from the object is suppressed, and the heat flow outside the object and the cloak made of these spherical shells behaves as if the object is not present. Thermal invisibility may open new vistas in hiding hot spots in infrared thermography, military furtivity, and electronics heating reduction. PMID:25928664

-dimensional thin shell wormhole with deformed throat can be supported by normal matter

NASA Astrophysics Data System (ADS)

Mazharimousavi, S. Habib; Halilsoy, M.

2015-06-01

From the physics standpoint the exotic matter problem is a major difficulty in thin shell wormholes (TSWs) with spherical/cylindrical throat topologies. We aim to circumvent this handicap by considering angle dependent throats in dimensions. By considering the throat of the TSW to be deformed spherical, i.e., a function of and , we present general conditions which are to be satisfied by the shape of the throat in order to have the wormhole supported by matter with positive density in the static reference frame. We provide particular solutions/examples to the constraint conditions.

A Study of the Nearfield of an Excited Spherical Shell.

DTIC Science & Technology

1980-03-17

8217 tte exact wave harmonic series and the approximate Geometrical Theory of Diffraction (GTD) were used to predict the acoustic near field of an elastic...rr) )1/3 n 4 n14 XV e i+ (424 (ka) (2h (ka) nn an1 % Tte SkaI/ rA’ (k)2 nn in Ap ndi B]. =Q (ikc)~ (4.25)h(1 (a n Tn whee i adeayftore fo acosi prpaa3o...Approach to Scattering from Elastic Spherical Shells," NUC TP425, September 1974, Naval Undersea Center, San Diego, California. 36. Pathak, P. H. and

Organizational Forms of Matter: An Inorganic Super Fullerene and Keplerate Based on Molybdenum Oxide.

PubMed

Müller, Achim; Krickemeyer, Erich; Bögge, Hartmut; Schmidtmann, Marc; Peters, Frank

1998-12-31

Plato and Kepler would have been pleased. Despite the large number of atoms present the cluster anion 1 resembles an icosahedral-type structure. This represents definitively an unprecedented event in chemistry! The structure is made up of 12 {Mo 11 } fragments such that the fivefold symmetry axes are retained in the resulting spherical object. As an inscribed icosahedron can be recognized in the spherical shell of 1 (see picture), similarities with Kepler's famous shell model of the cosmos can be seen. © 1998 WILEY-VCH Verlag GmbH, Weinheim, Fed. Rep. of Germany.

A Variational Formulation for the Finite Element Analysis of Sound Wave Propagation in a Spherical Shell

NASA Technical Reports Server (NTRS)

Lebiedzik, Catherine

1995-01-01

Development of design tools to furnish optimal acoustic environments for lightweight aircraft demands the ability to simulate the acoustic system on a workstation. In order to form an effective mathematical model of the phenomena at hand, we have begun by studying the propagation of acoustic waves inside closed spherical shells. Using a fully-coupled fluid-structure interaction model based upon variational principles, we have written a finite element analysis program and are in the process of examining several test cases. Future investigations are planned to increase model accuracy by incorporating non-linear and viscous effects.

Photonic bandgap of inverse opals prepared from core-shell spheres

PubMed Central

2012-01-01

In this study, we synthesized monodispersed polystyrene (PS)-silica core-shell spheres with various shell thicknesses for the fabrication of photonic crystals. The shell thickness of the spheres was controlled by various additions of tetraethyl orthosilicate during the shell growth process. The shrinkage ratio of the inverse opal photonic crystals prepared from the core-shell spheres was significantly reduced from 14.7% to within 3%. We suspected that the improvement resulted from the confinement of silica shell to the contraction of PS space during calcination. Due to the shell effect, the inverse opals prepared from the core-shell spheres have higher filling fraction and larger wavelength of stop band maximum. PMID:22894600

Nonlinear theory for laminated and thick plates and shells including the effects of transverse shearing

NASA Technical Reports Server (NTRS)

Stein, M.

1985-01-01

Nonlinear strain displacement relations for three-dimensional elasticity are determined in orthogonal curvilinear coordinates. To develop a two-dimensional theory, the displacements are expressed by trigonometric series representation through-the-thickness. The nonlinear strain-displacement relations are expanded into series which contain all first and second degree terms. In the series for the displacements only the first few terms are retained. Insertion of the expansions into the three-dimensional virtual work expression leads to nonlinear equations of equilibrium for laminated and thick plates and shells that include the effects of transverse shearing. Equations of equilibrium and buckling equations are derived for flat plates and cylindrical shells. The shell equations reduce to conventional transverse shearing shell equations when the effects of the trigonometric terms are omitted and to classical shell equations when the trigonometric terms are omitted and the shell is assumed to be thin.

Enceladus: three-act play and current state

NASA Astrophysics Data System (ADS)

Luan, J.; Goldreich, P.

2017-12-01

Eccentricity (e) growth as Enceladus migrates deeper into mean motion resonance with Dione results in increased tidal heating. As the bottom of the ice shell melts, the rate of tidal heating jumps and runaway melting ensues. At the end of run-away melting, the shell's thickness has fallen below the value at which the frequency of free libration equals the orbital mean motion and e has damped to well below its current value. Subsequently, both the shell thickness and e partake in a limit cycle. As e damps toward its minimum value, the shell's thickness asymptotically approaches its resonant value from below. After minimum e, the shell thickens quickly and e grows even faster. This cycle is likely to have been repeated multiple times in the past. Currently, e is much smaller than its equilibrium value corresponding to the shell thickness. Physical libration resonance resolves this mystery, it ensures that the low-e and medium-thickness state is present for most of the time between consecutive limit cycles. It is a robust scenario that avoids fine tuning or extreme parameter choice, and naturally produces episodic stages of high heating, consistent with softening of topographical features on Enceladus.

Studies of phosphatidylcholine vesicles by spectroturbidimetric and dynamic light scattering methods

NASA Astrophysics Data System (ADS)

Khlebtsov, B. N.; Kovler, L. A.; Bogatyrev, V. A.; Khlebtsov, N. G.; Shchyogolev, S. Yu.

2003-09-01

A spectroturbidimetric method for the determination of the average size and thickness of the shell in polydisperse suspensions of liposome particles is discussed. The method is based on measuring the wavelength exponent of a suspension (a slope of the logarithmic turbidity spectrum) and the specific turbidity (the turbidity per unit mass concentration of the dispersed substance). The inverse problem was solved using an exact calculation of characteristics of light scattering for polydisperse suspensions of spherical bilayer particles with allowance for the spectral dependence of optical constants. A practical realization of this method is illustrated by the experimental determinations of the structural parameters of liposomes prepared from egg lecithin. Comparison experiments to determine the liposome size by the dynamic (quasielastic) light scattering method were performed as an independent control.

Effect of Ice-Shell Thickness Variations on the Tidal Deformation of Enceladus

NASA Astrophysics Data System (ADS)

Choblet, G.; Cadek, O.; Behounkova, M.; Tobie, G.; Kozubek, T.

2015-12-01

Recent analysis of Enceladus's gravity and topography has suggested that the thickness of the ice shell significantly varies laterally - from 30-40 km in the south polar region to 60 km elsewhere. These variations may influence the activity of the geysers and increase the tidal heat production in regions where the ice shell is thinned. Using a model including a regional or global subsurface ocean and Maxwell viscoelasticity, we investigate the impact of these variations on the tidal deformation of the moon and its heat production. For that purpose, we use different numerical approaches - finite elements, local application of 1d spectral method, and a generalized spectral method. Results obtained with these three approaches for various models of ice-shell thickness variations are presented and compared. Implications of a reduced ice shell thickness for the south polar terrain activity are discussed.

Free Vibrations of Nonthin Elliptic Cylindrical Shells of Variable Thickness

NASA Astrophysics Data System (ADS)

Grigorenko, A. Ya.; Efimova, T. L.; Korotkikh, Yu. A.

2017-11-01

The problem of the free vibrations of nonthin elliptic cylindrical shells of variable thickness under various boundary conditions is solved using the refined Timoshenko-Mindlin theory. To solve the problem, an effective numerical approach based on the spline-approximation and discrete-orthogonalization methods is used. The effect of the cross-sectional shape, thickness variation law, material properties, and boundary conditions on the natural frequency spectrum of the shells is analyzed.

Type II shell evolution in A = 70 isobars from the N ≥ 40 island of inversion

NASA Astrophysics Data System (ADS)

Morales, A. I.; Benzoni, G.; Watanabe, H.; Tsunoda, Y.; Otsuka, T.; Nishimura, S.; Browne, F.; Daido, R.; Doornenbal, P.; Fang, Y.; Lorusso, G.; Patel, Z.; Rice, S.; Sinclair, L.; Söderström, P.-A.; Sumikama, T.; Wu, J.; Xu, Z. Y.; Yagi, A.; Yokoyama, R.; Baba, H.; Avigo, R.; Bello Garrote, F. L.; Blasi, N.; Bracco, A.; Camera, F.; Ceruti, S.; Crespi, F. C. L.; de Angelis, G.; Delattre, M.-C.; Dombradi, Zs.; Gottardo, A.; Isobe, T.; Kojouharov, I.; Kurz, N.; Kuti, I.; Matsui, K.; Melon, B.; Mengoni, D.; Miyazaki, T.; Modamio-Hoybjor, V.; Momiyama, S.; Napoli, D. R.; Niikura, M.; Orlandi, R.; Sakurai, H.; Sahin, E.; Sohler, D.; Schaffner, H.; Taniuchi, R.; Taprogge, J.; Vajta, Zs.; Valiente-Dobón, J. J.; Wieland, O.; Yalcinkaya, M.

2017-02-01

The level structures of 70Co and 70Ni, populated from the β decay of 70Fe, have been investigated using β-delayed γ-ray spectroscopy following in-flight fission of a 238U beam. The experimental results are compared to Monte-Carlo Shell-Model calculations including the pf +g9/2 +d5/2 orbitals. The strong population of a (1+) state at 274 keV in 70Co is at variance with the expected excitation energy of ∼1 MeV from near spherical single-particle estimates. This observation indicates a dominance of prolate-deformed intruder configurations in the low-lying levels, which coexist with the normal near spherical states. It is shown that the β decay of the neutron-rich A = 70 isobars from the new island of inversion to the Z = 28 closed-shell regime progresses in accordance with a newly reported type of shell evolution, the so-called Type II, which involves many particle-hole excitations across energy gaps.

Tank measurements of scattering from a resin-filled fiberglass spherical shell with internal flaws.

PubMed

Tesei, Alessandra; Guerrini, Piero; Zampolli, Mario

2008-08-01

This paper presents results of acoustic inversion and structural health monitoring achieved by means of low to midfrequency elastic scattering analysis of simple, curved objects, insonified in a water tank. Acoustic elastic scattering measurements were conducted between 15 and 100 kHz on a 60-mm-radius fiberglass spherical shell, filled with a low-shear-speed epoxy resin. Preliminary measurements were conducted also on the void shell before filling, and on a solid sphere of the same material as the filler. These data were used to estimate the constituent material parameters via acoustic inversion. The objects were measured in the backscatter direction, suspended at midwater, and insonified by a broadband directional transducer. From the inspection of the response of the solid-filled shell it was possible to detect and characterize significant inhomogeneities of the interior (air pockets), the presence of which were later confirmed by x-ray CT scan and ultrasound measurements. Elastic wave analysis and a model-data comparison study support the physical interpretation of the measurements.

Synthesis of water dispersible boron core silica shell (B@SiO2) nanoparticles

NASA Astrophysics Data System (ADS)

Walton, Nathan I.; Gao, Zhe; Eygeris, Yulia; Ghandehari, Hamidreza; Zharov, Ilya

2018-04-01

Water dispersible boron nanoparticles have great potential as materials for boron neutron capture therapy of cancer and magnetic resonance imaging, if they are prepared on a large scale with uniform size and shape and hydrophilic modifiable surface. We report the first method to prepare spherical, monodisperse, water dispersible boron core silica shell nanoparticles (B@SiO2 NPs) suitable for aforementioned biomedical applications. In this method, 40 nm elemental boron nanoparticles, easily prepared by mechanical milling and carrying 10-undecenoic acid surface ligands, are hydrosilylated using triethoxysilane, followed by base-catalyzed hydrolysis of tetraethoxysilane, which forms a 10-nm silica shell around the boron core. This simple two-step process converts irregularly shaped hydrophobic boron particles into the spherically shaped uniform nanoparticles. The B@SiO2 NPs are dispersible in water and the silica shell surface can be modified with primary amines that allow for the attachment of a fluorophore and, potentially, of targeting moieties. [Figure not available: see fulltext.

Greenhouse Effect: Temperature of a Metal Sphere Surrounded by a Glass Shell and Heated by Sunlight

ERIC Educational Resources Information Center

Nguyen, Phuc H.; Matzner, Richard A.

2012-01-01

We study the greenhouse effect on a model satellite consisting of a tungsten sphere surrounded by a thin spherical, concentric glass shell, with a small gap between the sphere and the shell. The system sits in vacuum and is heated by sunlight incident along the "z"-axis. This development is a generalization of the simple treatment of the…

Heat transport system, method and material

DOEpatents

Musinski, D.L.

1987-04-28

A heat transport system, method and composite material are disclosed in which a plurality of hollow spherical shells or microspheres having an outside diameter of less than or equal to 500 microns are encapsulated or embedded within a bulk material. Each shell has captured therein a volatile working fluid, such that each shell operates as a microsized heat pipe for conducting heat through the composite structure. 1 fig.

Comparison of breaking strength and shell thickness as evaluators of white-faced ibis eggshell quality

USGS Publications Warehouse

Henny, C.J.; Bennett, J.K.

1990-01-01

Data from a 1986 field study of white-faced ibis (Plegadis chihi) nesting at Carson Lake, Nevada, were used to compare the utility of eggshell strength measurement and eggshell thickness as indicators of eggshell quality. The ibis population had a history of reproductive failure correlated with elevated egg concentrations of p,p`DDE, hereafter referred to as DDE. Eggs from 80 nests (one egg/nest) were tested for shell strength and thickness. Egg contents were analyzed for organochlorines, mercury and selenium; productivity at each nest (minus one egg) was monitored in the field. DDE-DDT concentrations in the eggs ranged from none detected (less than 0.1) to 29 ppm (wet weight). Shell thickness and shell strength were both negatively correlated with DDE (0.60, 0.61, respectively), but shell strength deteriorated at a faster rate than shell thickness. Scanning electron micrographs indicated the deterioration in strength was related to changes in ultrastructure as well as to decreased thickness. Fourteen eggs with less than 0.40 ppm DDE were used to exemplify normal control eggs. Of the eggs with higher concentrations of DDE (i.e., greater than or equal to 0.40 ppm), 11 of 66 were thinner (greater than 2 SD below 'control' mean) than normal, 11 of 59 were weaker than normal and 7 eggs were cracked so their strength could not be tested, although thickness was measured. Therefore, 17% of the eggs with greater than or equal to 0.40 ppm DDE were thinner than normal and 27% were either weaker than normal or cracked. Further, six eggs (four with greater than or equal to 15 ppm DDE) did not have abnormally thin shells, but did have abnormally weak shells. Nests with abnormal test eggs (thinner, weaker or cracked) produced fewer young than nests with normal eggs. Use of the shell strength parameter provides additional information for better evaluations of reproductive problems. The potential utility of monitoring eggshell quality goes beyond evaluating effects of organochlorines since recent work indicates that other environmental hazards can affect shell quality.

Enceladus's ice shell thickness and ocean depth from gravity, topography, and libration measurements

NASA Astrophysics Data System (ADS)

Trinh, A.; Rivoldini, A.; Beuthe, M.; Rekier, J.; Baland, R. M.; Van Hoolst, T.

2017-12-01

One of Cassini's major achievements is the discovery of a global ocean a few kilometres beneath Enceladus's south polar terrain. Here we infer the thickness of Enceladus's ice shell and ocean from Cassini's observations using our latest models of isostatic compensation, shell libration, and ocean dynamics.

Synthesis and Plasmonic Understanding of Core/Satellite and Core Shell Nanostructures

NASA Astrophysics Data System (ADS)

Ruan, Qifeng

Localized surface plasmon resonance, which stems from the collective oscillations of conduction-band electrons, endows Au nanocrystals with unique optical properties. Au nanocrystals possess extremely large scattering/absorption cross-sections and enhanced local electromagnetic field, both of which are synthetically tunable. Moreover, when Au nanocrystals are closely placed or hybridized with semiconductors, the coupling and interaction between the individual components bring about more fascinating phenomena and promising applications, including plasmon-enhanced spectroscopies, solar energy harvesting, and cancer therapy. The continuous development in the field of plasmonics calls for further advancements in the preparation of high-quality plasmonic nanocrystals, the facile construction of hybrid plasmonic nanostructures with desired functionalities, as well as deeper understanding and efficient utilization of the interaction between plasmonic nanocrystals and semiconductor components. In this thesis, I developed a seed-mediated growth method for producing size-controlled Au nanospheres with high monodispersity and assembled Au nanospheres of different sizes into core/satellite nanostructures for enhancing Raman signals. For investigating the interactions between Au nanocrystals and semiconductors, I first prepared (Au core) (TiO2 shell) nanostructures, and then studied their synthetically controlled plasmonic properties and light-harvesting applications. Au nanocrystals with spherical shapes are desirable in plasmon-coupled systems owing to their high geometrical symmetry, which facilitates the analysis of electrodynamic responses in a classical electromagnetic framework and the investigation of quantum tunneling and nonlocal effects. I prepared remarkably uniform Au nanospheres with diameters ranging from 20 nm to 220 nm using a simple seed-mediated growth method associated with mild oxidation. Core/satellite nanostructures were assembled out of differently sized Au nanospheres with molecular linkers. The plasmon resonances of the core/satellite nanostructures undergo red shifts in comparison to those of the sole Au cores, which is consistent with Mie theory analysis. As predicted by finite-difference time-domain simulations, the assembled core/satellite nanostructures exhibit large enhancements for Raman scattering. The facile growth of Au nanospheres and assembly of core/satellite nanostructures blaze a new way to the design of nanoarchitectures with desired plasmonic properties and functions. Coating semiconductors onto Au nanocrystals to form core shell configurations can increase the interactions between the two materials, benefiting from their large active interfacial area. The shell can also protect the Au nanocrystal core from aggregation, reshaping, and chemical corrosion. In this thesis, (Au nanocrystal core) (titania shell) nanostructures with tunable shell thicknesses were prepared by a facile wetchemistry method. Au nanocrystals with strong and tunable plasmon resonances in the visible and near-infrared regions can enhance and broaden the light utilization of TiO2 through the scattering/absorption enhancement, sensitization, and hot-electron injection. The integration of Au nanocrystals therefore hold the prospect of breaking the light-harvesting limit of TiO2 arising from its wide band gap. The resultant (Au core) (TiO2 shell) nanostructures were examined to be capable of efficiently generating reactive oxygen species under near-infrared resonant excitation. On the other hand, the transverse plasmon modes of Au nanorods, which are often too weak to be observed on scattering spectra, are enhanced by the TiO2 shell through energy transfer. With the increment of the shell thickness, the intensity of the transverse plasmon mode increases significantly and even becomes comparable with the longitudinal plasmon mode. Interestingly, both the transverse and longitudinal modes of the (Au core) (TiO2 shell) nanostructures exhibit asymmetric Fano line shapes. The Fano resonances result from the coupling between the core and shell, as understood by the mechanical oscillator model. Besides varying the shell thickness, the plasmonic bands of the core shell nanostructures can also be tailored by employing Au nanorods with different aspect ratios. The synthetically tunable plasmonic properties and synergistic interactions between the gold core and the titania shell make the hybrid nanostructure a multifunctional nanomaterial and ideal system for studying the plasmonic hybrid nanostructures.

Analysis of flexible layered shallow shells on elastic foundation

NASA Astrophysics Data System (ADS)

Stupishin, L.; Kolesnikov, A.; Tolmacheva, T.

2017-05-01

This paper contains numerical analysis of a layered geometric nonlinear flexible shallow shell based on an elastic foundation. Rise of arch in the center of the shell, width, length and type of support are given. The design variable is taken to be the thickness of the shallow shell, the form of the middle surface forming and the characteristic of elastic foundations. Critical force coefficient and stress of shells are calculated by Bubnov-Galerkin. Stress, characteristic of elastic foundations - thickness dependence are presented.

Interacting shells in AdS spacetime and chaos

NASA Astrophysics Data System (ADS)

Brito, Richard; Cardoso, Vitor; Rocha, Jorge V.

2016-07-01

We study the simplest two-body problem in asymptotically anti-de Sitter spacetime: two, infinitely thin, concentric spherical shells of matter. We include only gravitational interaction between the two shells, but we show that the dynamics of this system is highly nontrivial. We observe prompt collapse to a black hole, delayed collapse and even perpetual oscillatory motion, depending on the initial location of the shells (or their energy content). The system exhibits critical behavior, and we show strong hints that it is also chaotic.

Stability of thin shell wormholes with a modified Chaplygin gas in Einstein-Hoffman-Born-Infeld theory

NASA Astrophysics Data System (ADS)

Eid, A.

2017-11-01

In the framework of Darmois-Israel formalism, the dynamics of motion equations of spherically symmetric thin shell wormholes that are supported by a modified Chaplygin gas in Einstein-Hoffman-Born-Infeld theory are constructed. The stability analysis of a thin shell wormhole is also discussed using a linearized radial perturbation around static solutions at the wormhole throat. The existence of stable static solutions depends on the value of some parameters of dynamical shell.

A Theoretical Investigation of Composite Overwrapped Pressure Vessel (COPV) Mechanics Applied to NASA Full Scale Tests

NASA Technical Reports Server (NTRS)

Thesken, John C.; Murthy, Pappu L. N.; Phoenix, S. L.; Greene, N.; Palko, Joseph L.; Eldridge, Jeffrey; Sutter, James; Saulsberry, R.; Beeson, H.

2009-01-01

A theoretical investigation of the factors controlling the stress rupture life of the National Aeronautics and Space Administration's (NASA) composite overwrapped pressure vessels (COPVs) continues. Kevlar (DuPont) fiber overwrapped tanks are of particular concern due to their long usage and the poorly understood stress rupture process in Kevlar filaments. Existing long term data show that the rupture process is a function of stress, temperature and time. However due to the presence of a load sharing liner, the manufacturing induced residual stresses and the complex mechanical response, the state of actual fiber stress in flight hardware and test articles is not clearly known. This paper is a companion to a previously reported experimental investigation and develops a theoretical framework necessary to design full-scale pathfinder experiments and accurately interpret the experimentally observed deformation and failure mechanisms leading up to static burst in COPVs. The fundamental mechanical response of COPVs is described using linear elasticity and thin shell theory and discussed in comparison to existing experimental observations. These comparisons reveal discrepancies between physical data and the current analytical results and suggest that the vessel s residual stress state and the spatial stress distribution as a function of pressure may be completely different from predictions based upon existing linear elastic analyses. The 3D elasticity of transversely isotropic spherical shells demonstrates that an overly compliant transverse stiffness relative to membrane stiffness can account for some of this by shifting a thin shell problem well into the realm of thick shell response. The use of calibration procedures are demonstrated as calibrated thin shell model results and finite element results are shown to be in good agreement with the experimental results. The successes reported here have lead to continuing work with full scale testing of larger NASA COPV hardware.

Effects of radial distribution of entropy diffusivity on critical modes of anelastic thermal convection in rotating spherical shells

NASA Astrophysics Data System (ADS)

Sasaki, Youhei; Takehiro, Shin-ichi; Ishiwatari, Masaki; Yamada, Michio

2018-03-01

Linear stability analysis of anelastic thermal convection in a rotating spherical shell with entropy diffusivities varying in the radial direction is performed. The structures of critical convection are obtained in the cases of four different radial distributions of entropy diffusivity; (1) κ is constant, (2) κT0 is constant, (3) κρ0 is constant, and (4) κρ0T0 is constant, where κ is the entropy diffusivity, T0 is the temperature of basic state, and ρ0 is the density of basic state, respectively. The ratio of inner and outer radii, the Prandtl number, the polytropic index, and the density ratio are 0.35, 1, 2, and 5, respectively. The value of the Ekman number is 10-3 or 10-5 . In the case of (1), where the setup is same as that of the anelastic dynamo benchmark (Jones et al., 2011), the structure of critical convection is concentrated near the outer boundary of the spherical shell around the equator. However, in the cases of (2), (3) and (4), the convection columns attach the inner boundary of the spherical shell. A rapidly rotating annulus model for anelastic systems is developed by assuming that convection structure is uniform in the axial direction taking into account the strong effect of Coriolis force. The annulus model well explains the characteristics of critical convection obtained numerically, such as critical azimuthal wavenumber, frequency, Rayleigh number, and the cylindrically radial location of convection columns. The radial distribution of entropy diffusivity, or more generally, diffusion properties in the entropy equation, is important for convection structure, because it determines the distribution of radial basic entropy gradient which is crucial for location of convection columns.

Turbine Engine Component Analysis: Cantilevered Composite Flat Plate Analysis

DTIC Science & Technology

1989-11-01

4/5 element which translates into the ADIN. shell element (Type 7) with thickness correction. PATADI automatically generates midsurface normal vectors...for each node referenced by a shell element. Using thickness correction, the element thickness will be oriented along the midsurface direction. If no

Thickness constraints on the icy shells of the galilean satellites from a comparison of crater shapes.

PubMed

Schenk, Paul M

2002-05-23

A thin outer ice shell on Jupiter's large moon Europa would imply easy exchange between the surface and any organic or biotic material in its putative subsurface ocean. The thickness of the outer ice shell is poorly constrained, however, with model-dependent estimates ranging from a few kilometres to ten or more kilometres. Here I present measurements of depths of impact craters on Europa, Ganymede and Callisto that reveal two anomalous transitions in crater shape with diameter. The first transition is probably related to temperature-dependent ductility of the crust at shallow depths (7 8 km on Europa). The second transition is attributed to the influence of subsurface oceans on all three satellites, which constrains Europa's icy shell to be at least 19 km thick. The icy lithospheres of Ganymede and Callisto are equally ice-rich, but Europa's icy shell has a thermal structure about 0.25 0.5 times the thicknesses of Ganymede's or Callisto's shells, depending on epoch. The appearances of the craters on Europa are inconsistent with thin-ice-shell models and indicate that exchange of oceanic and surface material could be difficult.

Keeping eggs warm: thermal and developmental advantages for parasitic cuckoos of laying unusually thick-shelled eggs

NASA Astrophysics Data System (ADS)

Yang, Canchao; Huang, Qiuli; Wang, Longwu; Du, Wei-Guo; Liang, Wei; Møller, Anders Pape

2018-02-01

Obligate brood parasites have evolved unusually thick-shelled eggs, which are hypothesized to possess a variety of functions such as resistance to puncture ejection by their hosts. In this study, we tested the hypothesis that obligate brood parasites lay unusually thick-shelled eggs to retain more heat for the developing embryo and thus contribute to early hatching of parasite eggs. By doing so, we used an infrared thermal imaging system as a non-invasive method to quantify the temperature of eggshells of common cuckoos ( Cuculus canorus) and their Oriental reed warbler ( Acrocephalus orientalis) hosts in an experiment that artificially altered the duration of incubation. Our results showed that cuckoo eggshells had higher temperature than host eggs during incubation, but also less fluctuations in temperature during incubation disturbance. Therefore, there was a thermal and hence a developmental advantage for brood parasitic cuckoos of laying thick-shelled eggs, providing another possible explanation for the unusually thick-shelled eggs of obligate brood parasites and earlier hatching of cuckoo eggs compared to those of the host.

Keeping eggs warm: thermal and developmental advantages for parasitic cuckoos of laying unusually thick-shelled eggs.

PubMed

Yang, Canchao; Huang, Qiuli; Wang, Longwu; Du, Wei-Guo; Liang, Wei; Møller, Anders Pape

2018-01-02

Obligate brood parasites have evolved unusually thick-shelled eggs, which are hypothesized to possess a variety of functions such as resistance to puncture ejection by their hosts. In this study, we tested the hypothesis that obligate brood parasites lay unusually thick-shelled eggs to retain more heat for the developing embryo and thus contribute to early hatching of parasite eggs. By doing so, we used an infrared thermal imaging system as a non-invasive method to quantify the temperature of eggshells of common cuckoos (Cuculus canorus) and their Oriental reed warbler (Acrocephalus orientalis) hosts in an experiment that artificially altered the duration of incubation. Our results showed that cuckoo eggshells had higher temperature than host eggs during incubation, but also less fluctuations in temperature during incubation disturbance. Therefore, there was a thermal and hence a developmental advantage for brood parasitic cuckoos of laying thick-shelled eggs, providing another possible explanation for the unusually thick-shelled eggs of obligate brood parasites and earlier hatching of cuckoo eggs compared to those of the host.

Decorating an individual living cell with a shell of controllable thickness by cytocompatible surface initiated graft polymerization.

PubMed

Wang, Guan; Zhang, Kai; Wang, Yindian; Zhao, Changwen; He, Bin; Ma, Yuhong; Yang, Wantai

2018-05-03

Surface engineering of individual living cells is a promising field for cell-based applications. However, engineering individual cells with controllable thickness by chemical methods has been rarely studied. This article describes the development of a new cytocompatible chemical strategy to decorate individual living cells. The thicknesses of the crosslinked shells could be conveniently controlled by the irradiation time, visible light intensity, or monomer concentration. Moreover, the lag phase of the yeast cell division was extended and their stability against lysis was improved, which could also be tuned by controlling the shell thickness.

Structural and Optical Analysis of the Bio-mineralized Photonic Structures in the Shell of the Blue- Rayed Limpet Ansates Pellucida

NASA Astrophysics Data System (ADS)

Kolle, Mathias; Li, Ling; Kolle, Stefan; Weaver, James; Ortiz, Christine; Aizenberg, Joanna

2013-03-01

Many terrestrial biological organisms have evolved a variety of micro- and nanostructures that provide unique optical signatures including distinctive, dynamic coloration, high reflectivity or superior whiteness. Recently, photonic structures have also been found in the shells or spines of marine animals. Life under water imposes very distinct constraints on organisms relying on visual communication and on the designs and the materials involved in aquatic photonic structures. Here, we present a bio-mineralized calcium carbonate - based crystalline photonic system buried in the shell of the blue-rayed limpet Ansates pellucida. The structure consists of a layered stack of calcite lamellae with uniform thickness and inter-lamella spacing. This arrangement lies at the origin of the blue-green iridescence of the organism's characteristic stripes, which is caused by multilayer interference. The multilayer is supported by a disordered array of spherical particles with an average diameter of 300nm, likely serving to enhance the contrast of the blue stripes. We present a full structural and optical characterization of this bio-mineralised marine photonic system, supported by optical FDTD modeling. The authors gratefully acknowledge financial support by the Air Force Office of Scientific Research under Award No. FA9550-09-1-0669-DOD35CAP. M. Kolle is grateful for support from the Alexander von Humboldt - Foundation.

Preparation and in vitro evaluation of poly(D,L-lactide-co-glycolide) air-filled nanocapsules as a contrast agent for ultrasound imaging.

PubMed

Néstor, Mendoza-Muñoz; Kei, Noriega-Peláez Eddy; Guadalupe, Nava-Arzaluz María; Elisa, Mendoza-Elvira Susana; Adriana, Ganem-Quintanar; David, Quintanar-Guerrero

2011-10-01

The aim of this study was to prepare air-filled nanocapsules intended ultrasound contrast agents (UCAs) with a biodegradable polymeric shell composed of poly(d,l-lactide-co-glycolide) (PLGA). Because of their size, current commercial UCAs are not capable of penetrating the irregular vasculature that feeds growing tumors. The new generation of UCAs should be designed on the nanoscale to enhance tumor detection, in addition, the polymeric shell in contrast with monomolecular stabilized UCAs improves the mechanical properties against ultrasound pressure and lack of stability. The preparation method of air-filled nanocapsules was based on a modification of the double-emulsion solvent evaporation technique. Air-filled nanocapsules with a mean diameter of 370±96nm were obtained. Electronic microscopies revealed spherical-shaped particles with smooth surfaces and a capsular morphology, with a shell thickness of ∼50nm. Air-filled nanocapsules showed echogenic power in vitro, providing an enhancement of up to 15dB at a concentration of 0.045mg/mL at a frequency of 10MHz. Loss of signal for air-filled nanocapsules was 2dB after 30min, suggesting high stability. The prepared contrast agent in this work has the potential to be used in ultrasound imaging. Copyright © 2011 Elsevier B.V. All rights reserved.

Central depression in nuclear density and its consequences for the shell structure of superheavy nuclei

DOE Office of Scientific and Technical Information (OSTI.GOV)

Afanasjev, A.V.; Laboratory of Radiation Physics, Institute of Solid State Physics, University of Latvia, LV 2169 Salaspils, Miera str. 31; Frauendorf, S.

The influence of the central depression in the density distribution of spherical superheavy nuclei on the shell structure is studied within the relativistic mean-field theory. A large depression leads to the shell gaps at the proton Z=120 and neutron N=172 numbers, whereas a flatter density distribution favors N=184 and leads to the appearance of a Z=126 shell gap and to the decrease of the size of the Z=120 shell gap. The correlations between the magic shell gaps and the magnitude of the central depression are discussed for relativistic and nonrelativistic mean field theories.

Method of fabricating nested shells and resulting product

DOEpatents

Henderson, Timothy M.; Kool, Lawrence B.

1982-01-01

A multiple shell structure and a method of manufacturing such structure wherein a hollow glass microsphere is surface treated in an organosilane solution so as to render the shell outer surface hydrophobic. The surface treated glass shell is then suspended in the oil phase of an oil-aqueous phase dispersion. The oil phase includes an organic film-forming monomer, a polymerization initiator and a blowing agent. A polymeric film forms at each phase boundary of the dispersion and is then expanded in a blowing operation so as to form an outer homogeneously integral monocellular substantially spherical thermoplastic shell encapsulating an inner glass shell of lesser diameter.

Radiative shocks produced from spherical cryogenic implosions at the National Ignition Facilitya)

NASA Astrophysics Data System (ADS)

Pak, A.; Divol, L.; Gregori, G.; Weber, S.; Atherton, J.; Bennedetti, R.; Bradley, D. K.; Callahan, D.; Casey, D. T.; Dewald, E.; Döppner, T.; Edwards, M. J.; Frenje, J. A.; Glenn, S.; Grim, G. P.; Hicks, D.; Hsing, W. W.; Izumi, N.; Jones, O. S.; Johnson, M. G.; Khan, S. F.; Kilkenny, J. D.; Kline, J. L.; Kyrala, G. A.; Lindl, J.; Landen, O. L.; Le Pape, S.; Ma, T.; MacPhee, A.; MacGowan, B. J.; MacKinnon, A. J.; Masse, L.; Meezan, N. B.; Moody, J. D.; Olson, R. E.; Ralph, J. E.; Robey, H. F.; Park, H.-S.; Remington, B. A.; Ross, J. S.; Tommasini, R.; Town, R. P. J.; Smalyuk, V.; Glenzer, S. H.; Moses, E. I.

2013-05-01

Spherically expanding radiative shock waves have been observed from inertially confined implosion experiments at the National Ignition Facility. In these experiments, a spherical fusion target, initially 2 mm in diameter, is compressed via the pressure induced from the ablation of the outer target surface. At the peak compression of the capsule, x-ray and nuclear diagnostics indicate the formation of a central core, with a radius and ion temperature of ˜20 μm and ˜ 2 keV, respectively. This central core is surrounded by a cooler compressed shell of deuterium-tritium fuel that has an outer radius of ˜40 μm and a density of >500 g/cm3. Using inputs from multiple diagnostics, the peak pressure of the compressed core has been inferred to be of order 100 Gbar for the implosions discussed here. The shock front, initially located at the interface between the high pressure compressed fuel shell and surrounding in-falling low pressure ablator plasma, begins to propagate outwards after peak compression has been reached. Approximately 200 ps after peak compression, a ring of x-ray emission created by the limb-brightening of a spherical shell of shock-heated matter is observed to appear at a radius of ˜100 μm. Hydrodynamic simulations, which model the experiment and include radiation transport, indicate that the sudden appearance of this emission occurs as the post-shock material temperature increases and upstream density decreases, over a scale length of ˜10 μm, as the shock propagates into the lower density (˜1 g/cc), hot (˜250 eV) plasma that exists at the ablation front. The expansion of the shock-heated matter is temporally and spatially resolved and indicates a shock expansion velocity of ˜300 km/s in the laboratory frame. The magnitude and temporal evolution of the luminosity produced from the shock-heated matter was measured at photon energies between 5.9 and 12.4 keV. The observed radial shock expansion, as well as the magnitude and temporal evolution of the luminosity from the shock-heated matter, is consistent with 1-D radiation hydrodynamic simulations. Analytic estimates indicate that the radiation energy flux from the shock-heated matter is of the same order as the in-flowing material energy flux, and suggests that this radiation energy flux modifies the shock front structure. Simulations support these estimates and show the formation of a radiative shock, with a precursor that raises the temperature ahead of the shock front, a sharp μm-scale thick spike in temperature at the shock front, followed by a post-shock cooling layer.

Continuous and scalable polymer capsule processing for inertial fusion energy target shell fabrication using droplet microfluidics.

PubMed

Li, Jin; Lindley-Start, Jack; Porch, Adrian; Barrow, David

2017-07-24

High specification, polymer capsules, to produce inertial fusion energy targets, were continuously fabricated using surfactant-free, inertial centralisation, and ultrafast polymerisation, in a scalable flow reactor. Laser-driven, inertial confinement fusion depends upon the interaction of high-energy lasers and hydrogen isotopes, contained within small, spherical and concentric target shells, causing a nuclear fusion reaction at ~150 M°C. Potentially, targets will be consumed at ~1 M per day per reactor, demanding a 5000x unit cost reduction to ~$0.20, and is a critical, key challenge. Experimentally, double emulsions were used as templates for capsule-shells, and were formed at 20 Hz, on a fluidic chip. Droplets were centralised in a dynamic flow, and their shapes both evaluated, and mathematically modeled, before subsequent shell solidification. The shells were photo-cured individually, on-the-fly, with precisely-actuated, millisecond-length (70 ms), uniform-intensity UV pulses, delivered through eight, radially orchestrated light-pipes. The near 100% yield rate of uniform shells had a minimum 99.0% concentricity and sphericity, and the solidification processing period was significantly reduced, over conventional batch methods. The data suggest the new possibility of a continuous, on-the-fly, IFE target fabrication process, employing sequential processing operations within a continuous enclosed duct system, which may include cryogenic fuel-filling, and shell curing, to produce ready-to-use IFE targets.

Shape optimized headers and methods of manufacture thereof

DOEpatents

Perrin, Ian James

2013-11-05

Disclosed herein is a shape optimized header comprising a shell that is operative for collecting a fluid; wherein an internal diameter and/or a wall thickness of the shell vary with a change in pressure and/or a change in a fluid flow rate in the shell; and tubes; wherein the tubes are in communication with the shell and are operative to transfer fluid into the shell. Disclosed herein is a method comprising fixedly attaching tubes to a shell; wherein the shell is operative for collecting a fluid; wherein an internal diameter and/or a wall thickness of the shell vary with a change in pressure and/or a change in a fluid flow rate in the shell; and wherein the tubes are in communication with the shell and are operative to transfer fluid into the shell.

A semi-analytical solution for elastic analysis of rotating thick cylindrical shells with variable thickness using disk form multilayers.

PubMed

Zamani Nejad, Mohammad; Jabbari, Mehdi; Ghannad, Mehdi

2014-01-01

Using disk form multilayers, a semi-analytical solution has been derived for determination of displacements and stresses in a rotating cylindrical shell with variable thickness under uniform pressure. The thick cylinder is divided into disk form layers form with their thickness corresponding to the thickness of the cylinder. Due to the existence of shear stress in the thick cylindrical shell with variable thickness, the equations governing disk layers are obtained based on first-order shear deformation theory (FSDT). These equations are in the form of a set of general differential equations. Given that the cylinder is divided into n disks, n sets of differential equations are obtained. The solution of this set of equations, applying the boundary conditions and continuity conditions between the layers, yields displacements and stresses. A numerical solution using finite element method (FEM) is also presented and good agreement was found.

A Semi-Analytical Solution for Elastic Analysis of Rotating Thick Cylindrical Shells with Variable Thickness Using Disk Form Multilayers

PubMed Central

Zamani Nejad, Mohammad; Jabbari, Mehdi; Ghannad, Mehdi

2014-01-01

Using disk form multilayers, a semi-analytical solution has been derived for determination of displacements and stresses in a rotating cylindrical shell with variable thickness under uniform pressure. The thick cylinder is divided into disk form layers form with their thickness corresponding to the thickness of the cylinder. Due to the existence of shear stress in the thick cylindrical shell with variable thickness, the equations governing disk layers are obtained based on first-order shear deformation theory (FSDT). These equations are in the form of a set of general differential equations. Given that the cylinder is divided into n disks, n sets of differential equations are obtained. The solution of this set of equations, applying the boundary conditions and continuity conditions between the layers, yields displacements and stresses. A numerical solution using finite element method (FEM) is also presented and good agreement was found. PMID:24719582

CLASSICAL AREAS OF PHENOMENOLOGY: Material parameter equation for rotating elliptical spherical cloaks

NASA Astrophysics Data System (ADS)

Ma, Hua; Qu, Shao-Bo; Xu, Zhuo; Zhang, Jie-Qiu; Wang, Jia-Fu

2009-01-01

By using the coordinate transformation method, we have deduced the material parameter equation for rotating elliptical spherical cloaks and carried out simulation as well. The results indicate that the rotating elliptical spherical cloaking shell, which is made of meta-materials whose permittivity and permeability are governed by the equation deduced in this paper, can achieve perfect invisibility by excluding electromagnetic fields from the internal region without disturbing any external field.

Composite Materials for Maxillofacial Prostheses.

DTIC Science & Technology

1981-08-01

necessary and Identify byv block number) MAXILLOFACIAL PROSTHESES; PROSTHETIC MATERIALS: MICROCAPSULES : SOFT FILLERS; ELASTOMER COMPOSITES 2,. ABSTRACT...used as fillers in the fabrication of maxillofacial prostheses. The projected systems are elastomeric-shelled, liquid-filled microcapsules . Improvements...elastomeric-shelled, liquid-filled microcapsules . Experiments continued on the interfacial polymerization process, with spherical, sealed, capsules

Effective Simulation of Delamination in Aeronautical Structures Using Shells and Cohesive Elements

NASA Technical Reports Server (NTRS)

Davila, Carlos G.; Camanho, Pedro P.; Turon, Albert

2007-01-01

A cohesive element for shell analysis is presented. The element can be used to simulate the initiation and growth of delaminations between stacked, non-coincident layers of shell elements. The procedure to construct the element accounts for the thickness offset by applying the kinematic relations of shell deformation to transform the stiffness and internal force of a zero-thickness cohesive element such that interfacial continuity between the layers is enforced. The procedure is demonstrated by simulating the response and failure of the Mixed Mode Bending test and a skin-stiffener debond specimen. In addition, it is shown that stacks of shell elements can be used to create effective models to predict the inplane and delamination failure modes of thick components. The results indicate that simple shell models can retain many of the necessary predictive attributes of much more complex 3D models while providing the computational efficiency that is necessary for design.

Cohesive Elements for Shells

NASA Technical Reports Server (NTRS)

Davila, Carlos G.; Camanho, Pedro P.; Turon, Albert

2007-01-01

A cohesive element for shell analysis is presented. The element can be used to simulate the initiation and growth of delaminations between stacked, non-coincident layers of shell elements. The procedure to construct the element accounts for the thickness offset by applying the kinematic relations of shell deformation to transform the stiffness and internal force of a zero-thickness cohesive element such that interfacial continuity between the layers is enforced. The procedure is demonstrated by simulating the response and failure of the Mixed Mode Bending test and a skin-stiffener debond specimen. In addition, it is shown that stacks of shell elements can be used to create effective models to predict the inplane and delamination failure modes of thick components. The results indicate that simple shell models can retain many of the necessary predictive attributes of much more complex 3D models while providing the computational efficiency that is necessary for design.

Eggshell thickness in mourning dove populations

USGS Publications Warehouse

Kreitzer, J.F.

1971-01-01

Eggs (n = 452) of the mourning dove (Zenaidura macroura) were collected from 9 states in 1969 and 11 states in 1970, and shell thickness was compared with that of eggs (n = 97) collected from 24 states during the years 1861 to 1935. Mean shell thickness did not differ significantly in the test groups.

Radiative transfer in spherical shell atmospheres. I - Rayleigh scattering

NASA Technical Reports Server (NTRS)

Adams, C. N.; Kattawar, G. W.

1978-01-01

The plane-parallel approximation and the more realistic spherical shell approximation for the radiance reflected from a planetary atmosphere are compared and are applied to the study of a planet the size of the earth with a homogeneous conservative Rayleigh scattering atmosphere extending to a height of 100 km. Inadequacies of the approximations are considered. Radiance versus height distributions for both single and multiple scattering are presented, as are results for the fractional radiance from altitudes in the atmosphere which contribute to the total unidirectional reflected radiance at the top of the atmosphere. The data can be used for remote sensing applications and planetary spectroscopy.

Local-area simulations of rotating compressible convection and associated mean flows

NASA Technical Reports Server (NTRS)

Hurlburt, Neal E.; Brummell, N. H.; Toomre, Juri

1995-01-01

The dynamics of compressible convection within a curved local segment of a rotating spherical shell are considered in relation to the turbulent redistribution of angular momentum within the solar convection zone. Current supercomputers permit fully turbulent flows to be considered within the restricted geometry of local area models. By considering motions in a curvilinear geometry in which the Coriolos parameters vary with latitude, Rossby waves which couple with the turbulent convection are thought of as being possible. Simulations of rotating convection are presented in such a curved local segment of a spherical shell using a newly developed, sixth-order accurate code based on compact finite differences.

Coulomb matrix elements in multi-orbital Hubbard models.

PubMed

Bünemann, Jörg; Gebhard, Florian

2017-04-26

Coulomb matrix elements are needed in all studies in solid-state theory that are based on Hubbard-type multi-orbital models. Due to symmetries, the matrix elements are not independent. We determine a set of independent Coulomb parameters for a d-shell and an f-shell and all point groups with up to 16 elements (O h , O, T d , T h , D 6h , and D 4h ). Furthermore, we express all other matrix elements as a function of the independent Coulomb parameters. Apart from the solution of the general point-group problem we investigate in detail the spherical approximation and first-order corrections to the spherical approximation.

Nonlinear generation of large-scale magnetic fields in forced spherical shell dynamos

DOE Office of Scientific and Technical Information (OSTI.GOV)

Livermore, P. W.; Hughes, D. W.; Tobias, S. M.

2010-03-15

In an earlier paper [P. W. Livermore, D. W. Hughes, and S. M. Tobias, ''The role of helicity and stretching in forced kinematic dynamos in a spherical shell'', Phys. Fluids 19, 057101 (2007)], we considered the kinematic dynamo action resulting from a forced helical flow in a spherical shell. Although mean field electrodynamics suggests that the resulting magnetic field should have a significant mean (axisymmetric) component, we found no evidence for this; the dynamo action was distinctly small scale. Here we extend our investigation into the nonlinear regime in which the magnetic field reacts back on the velocity via themore » Lorentz force. Our main result is somewhat surprising, namely, that nonlinear effects lead to a considerable change in the structure of the magnetic field, its final state having a significant mean component. By investigating the dominant flow-field interactions, we isolate the dynamo mechanism and show schematically how the generation process differs between the kinematic and nonlinear regimes. In addition, we are able to calculate some components of the transport coefficient {alpha} and thus discuss our results within the context of mean field electrodynamics.« less

ShellFit: Reconstruction in the MiniCLEAN Detector

NASA Astrophysics Data System (ADS)

Seibert, Stanley

2010-02-01

The MiniCLEAN dark matter experiment is an ultra-low background liquid cryogen detector with a fiducial volume of approximately 150 kg. Dark matter candidate events produce ultraviolet scintillation light in argon at 128 nm and in neon at 80 nm. In order to detect this scintillation light, the target volume is enclosed by acrylic plates forming a spherical shell upon which an organic fluor, tetraphenyl butadiene (TPB), has been applied. TPB absorbs UV light and reemits visible light isotropically which can be detected by photomultiplier tubes. Two significant sources of background events in MiniCLEAN are decays of radon daughters embedded in the acrylic surface and external sources of neutrons, such as the photomultiplier tubes themselves. Both of these backgrounds can be mitigated by reconstructing the origin of the scintillation light and cutting events beyond a particular radius. The scrambling of photon trajectories at the TPB surface makes this task very challenging. The ``ShellFit'' algorithm for reconstructing event position and energy in a detector with a spherical wavelength-shifting shell will be described. The performance of ShellFit will be demonstrated using Monte Carlo simulation of several event types in the MiniCLEAN detector. )

Bandgap Engineering of InP QDs Through Shell Thickness and Composition

DOE Office of Scientific and Technical Information (OSTI.GOV)

Dennis, Allison M.; Mangum, Benjamin D.; Piryatinski, Andrei

2012-06-21

Fields as diverse as biological imaging and telecommunications utilize the unique photophysical and electronic properties of nanocrystal quantum dots (NQDs). The development of new NQD compositions promises material properties optimized for specific applications, while addressing material toxicity. Indium phosphide (InP) offers a 'green' alternative to the traditional cadmium-based NQDs, but suffers from extreme susceptibility to oxidation. Coating InP cores with more stable shell materials significantly improves nanocrystal resistance to oxidation and photostability. We have investigated several new InP-based core-shell compositions, correlating our results with theoretical predictions of their optical and electronic properties. Specifically, we can tailor the InP core-shell QDsmore » to a type-I, quasi-type-II, or type-II bandgap structure with emission wavelengths ranging from 500-1300 nm depending on the shell material used (ZnS, ZnSe, CdS, or CdSe) and the thickness of the shell. Single molecule microscopy assessments of photobleaching and blinking are used to correlate NQD properties with shell thickness.« less

Using Micro CT Scanning to Assess Pteropod Shells in the Modern Ocean

NASA Astrophysics Data System (ADS)

Oakes, R. L.; Urbanski, J. M.; Bralower, T. J.

2016-02-01

Anthropogenic activities are causing fundamental changes to ocean chemistry. Calcareous plankton and nekton are predicted to be affected by these chemical changes, especially by ocean acidification. These groups are at the base of the marine food chain and therefore their demise will have a strong effect on the marine ecosystem as a whole. One challenge moving forward is to find a method to assess how chemical changes manifest themselves in plankton and nekton shells. Recent advancements in computed tomographic (CT) scanning technology allows for organisms to be imaged in three dimensions at micrometer resolution. CT data enables quantitative measurements of properties such as shell thickness, volume, and morphology. We apply this method to look at pteropods, nektonic molluscs which make their shells from the more soluble form of calcium carbonate, aragonite. Their shell mineralogy, and the fact that some groups live in polar and upwelling waters, place them at high risk for ocean acidification. We have scanned over 70 pteropods from 5 different locations globally. Analysis shows that there is a significant difference in pteropod shell thickness in different ocean basins with the thinnest shells being found off the coast of Washington. Changes in shell thickness may affect pteropod swimming efficiency, predation, and rate of sinking. Shell volume does not seem to vary with shell thickness suggesting that changes will impact pteropods at all ontogenetic stages. We are working towards a geometric morphometric analysis of these shells to see if the shape differs in areas with different ocean conditions. This initial set of CT scans of pteropods can be used as a baseline to which future changes can be compared. Furthermore, this technique has the potential to be easily transferred to other organisms as a method of assessing shell change in response to ocean acidification and associated factors.

Fabrication of sub-micrometer-sized jingle bell-shaped hollow spheres from multilayered core-shell particles.

PubMed

Gu, Shunchao; Kondo, Tomohiro; Mine, Eiichi; Nagao, Daisuke; Kobayashi, Yoshio; Konno, Mikio

2004-11-01

Jingle bell-shaped hollow spheres were fabricated starting from multilayered particles composed of a silica core, a polystyrene inner shell, and a titania outer shell. Composite particles of silica core-polystyrene shell, synthesized by coating a 339-nm-sized silica core with a polystyrene shell of thickness 238 nm in emulsion polymerization, were used as core particles for a succeeding titania-coating. A sol-gel method was employed to form the titania outer shell with a thickness of 37 nm. The inner polystyrene shell in the multilayered particles was removed by immersing them in tetrahydrofuran. These successive procedures could produce jingle bell-shaped hollow spheres that contained a silica core in the titania shell.

The influence of ozone and aerosols on the brightness and color of the twilight zone

NASA Technical Reports Server (NTRS)

Adams, C. N.; Plass, G. N.; Kattawar, G. W.

1973-01-01

The radiance and color of the twilight sky are calculated for single scattered radiation with the use of spherically symmetric models of the earth's atmosphere. Spherical geometry is used throughout the calculations with no plane parallel approximations. Refraction effects are taken into account through fine subdivision of the atmosphere into spherical shells of fixed index of refraction. Shell's law of refraction is used to calculate a direction of travel each time that a photon traverses the interface between layers. Five different models of the atmosphere were used: a pure molecular scattering atmosphere; molecular atmosphere plus ozone absorption; and three models with aerosol concentrations of 1, 3, and 10 times normal together with molecular scattering and ozone absorption. The results of the calculations are shown for various observation positions and local viewing angles in the solar plane for wavelengths in the range of 0.40 microns to 0.75 microns.

Acoustical scattering by multilayer spherical elastic scatterer containing electrorheological layer.

PubMed

Cai, Liang-Wu; Dacol, Dacio K; Orris, Gregory J; Calvo, David C; Nicholas, Michael

2011-01-01

A computational procedure for analyzing acoustical scattering by multilayer concentric spherical scatterers having an arbitrary mixture of acoustic and elastic materials is proposed. The procedure is then used to analyze the scattering by a spherical scatterer consisting of a solid shell and a solid core encasing an electrorheological (ER) fluid layer, and the tunability in the scattering characteristics afforded by the ER layer is explored numerically. Tunable scatterers with two different ER fluids are analyzed. One, corn starch in peanut oil, shows that a significant increase in scattering cross-section is possible in moderate frequencies. Another, fine poly-methyl methacrylate (PMMA) beads in dodecane, shows only slight change in scattering cross-sections overall. But, when the shell is thin, a noticeable local resonance peak can appear near ka=1, and this resonance can be turned on or off by the external electric field.

Historical baselines and the future of shell calcification for a foundation species in a changing ocean

PubMed Central

Pfister, Catherine A.; Roy, Kaustuv; Wootton, J. Timothy; McCoy, Sophie J.; Paine, Robert T.; Suchanek, Thomas H.; Sanford, Eric

2016-01-01

Seawater pH and the availability of carbonate ions are decreasing due to anthropogenic carbon dioxide emissions, posing challenges for calcifying marine species. Marine mussels are of particular concern given their role as foundation species worldwide. Here, we document shell growth and calcification patterns in Mytilus californianus, the California mussel, over millennial and decadal scales. By comparing shell thickness across the largest modern shells, the largest mussels collected in the 1960s–1970s and shells from two Native American midden sites (∼1000–2420 years BP), we found that modern shells are thinner overall, thinner per age category and thinner per unit length. Thus, the largest individuals of this species are calcifying less now than in the past. Comparisons of shell thickness in smaller individuals over the past 10–40 years, however, do not show significant shell thinning. Given our sampling strategy, these results are unlikely to simply reflect within-site variability or preservation effects. Review of environmental and biotic drivers known to affect shell calcification suggests declining ocean pH as a likely explanation for the observed shell thinning. Further future decreases in shell thickness could have significant negative impacts on M. californianus survival and, in turn, negatively impact the species-rich complex that occupies mussel beds. PMID:27306049

Historical baselines and the future of shell calcification for a foundation species in a changing ocean

USGS Publications Warehouse

Pfister, Catherine A.; Roy, Kaustuv; Wootton, Timothy J.; McCoy, Sophie J.; Paine, Robert T.; Suchanek, Tom; Sanford, Eric

2016-01-01

Seawater pH and the availability of carbonate ions are decreasing due to anthropogenic carbon dioxide emissions, posing challenges for calcifying marine species. Marine mussels are of particular concern given their role as foundation species worldwide. Here, we document shell growth and calcification patterns in Mytilus californianus, the California mussel, over millennial and decadal scales. By comparing shell thickness across the largest modern shells, the largest mussels collected in the 1960s–1970s and shells from two Native American midden sites (∼1000–2420 years BP), we found that modern shells are thinner overall, thinner per age category and thinner per unit length. Thus, the largest individuals of this species are calcifying less now than in the past. Comparisons of shell thickness in smaller individuals over the past 10–40 years, however, do not show significant shell thinning. Given our sampling strategy, these results are unlikely to simply reflect within-site variability or preservation effects. Review of environmental and biotic drivers known to affect shell calcification suggests declining ocean pH as a likely explanation for the observed shell thinning. Further future decreases in shell thickness could have significant negative impacts on M. californianus survival and, in turn, negatively impact the species-rich complex that occupies mussel beds..

Historical baselines and the future of shell calcification for a foundation species in a changing ocean.

PubMed

Pfister, Catherine A; Roy, Kaustuv; Wootton, J Timothy; McCoy, Sophie J; Paine, Robert T; Suchanek, Thomas H; Sanford, Eric

2016-06-15

Seawater pH and the availability of carbonate ions are decreasing due to anthropogenic carbon dioxide emissions, posing challenges for calcifying marine species. Marine mussels are of particular concern given their role as foundation species worldwide. Here, we document shell growth and calcification patterns in Mytilus californianus, the California mussel, over millennial and decadal scales. By comparing shell thickness across the largest modern shells, the largest mussels collected in the 1960s-1970s and shells from two Native American midden sites (∼1000-2420 years BP), we found that modern shells are thinner overall, thinner per age category and thinner per unit length. Thus, the largest individuals of this species are calcifying less now than in the past. Comparisons of shell thickness in smaller individuals over the past 10-40 years, however, do not show significant shell thinning. Given our sampling strategy, these results are unlikely to simply reflect within-site variability or preservation effects. Review of environmental and biotic drivers known to affect shell calcification suggests declining ocean pH as a likely explanation for the observed shell thinning. Further future decreases in shell thickness could have significant negative impacts on M. californianus survival and, in turn, negatively impact the species-rich complex that occupies mussel beds. © 2016 The Author(s).

Emission Behavior of Fluorescently Labeled Silver Nanoshell: Enhanced Self-Quenching by Metal Nanostructure.

PubMed

Zhang, Jian; Fu, Yi; Lakowicz, Joseph R

2007-02-08

Labeled silica beads with an average diameter of 100 nm were synthesized by incorporating with 20-600 μM Ru(bpy)(3) (2+) complexes. Silver shells were deposited on the beads layer-by-layer with the shell thickness of 5-50 nm. The emission band became narrower and the intensity was enhanced depending on the shell thickness. Self-quenching of the probe was observed at high concentration. Poisson statistics were employed to analyze self-quenching of the fluorophores. The estimated quenching distance was extended from 6 to 16 nm with shell growth from 0 to 50 nm. Moreover, the silver shells were also labeled with Rhodamine 6G. Fluorescence enhancement and reduced lifetime were also observed for silver-silica shell containing R6G. We found that by adjustment of probe concentration and silver shell thickness, a Ru(bpy)(3) (2+)-labeled particle could be 600 times brighter than an isolated Ru(bpy)(3) (2+) molecule. We expect labeled metal core-shell structures can become useful probes for high sensitivity and/or single particle assay.

Gravitational potential energy of the earth: A spherical harmonic approach

NASA Technical Reports Server (NTRS)

Rubincam, D. P.

1977-01-01

A spherical harmonic equation for the gravitational potential energy of the earth is derived for an arbitrary density distribution by conceptually bringing in mass-elements from infinity and building up the earth shell upon spherical shell. The zeroth degree term in the spherical harmonic equation agrees with the usual expression for the energy of a radial density distribution. The second degree terms give a maximum nonhydrostatic energy in the mantle and crust of -2.77 x 10 to the twenty-ninth power ergs, an order of magnitude. If the earth is assumed to be a homogeneous viscous oblate spheroid relaxing to an equilibrium shape, then a lower limit to the mantle viscosity of 1.3 x 10 to the twentieth power poises is found by assuming the total geothermal flux is due to viscous dissipation. If the nonequilibrium figure is dynamically maintained by the earth acting as a heat engine at one per cent efficiency, then the viscosity is ten to the twenty second power poises, a number preferred by some as the viscosity of the mantle.

Acoustically excited surface waves on empty or fluid-filled cylindrical and spherical shells

NASA Astrophysics Data System (ADS)

Ahyi, A. Claude; Cao, H.; Raju, P. K.; Werby, M. F.; Bao, X. L.; Überall, H.

2002-05-01

A comparative study is presented of the acoustical excitation of circumferential (surface) waves on fluid-immersed cylindrical or spherical metal shells, which may be either evacuated, or filled with the same or a different fluid. The excited surface waves can manifest themselves by the resonances apparent in the sound scattering amplitude, which they cause upon phase matching following repeated circumnavigations of the target object, or by their re-radiation into the external fluid in the manner of head waves. We plot dispersion curves versus frequency of the surface waves, which for evacuated shells have a generally rising character, while the fluid filling adds an additional set of circumferential waves that descend with frequency. The resonances of these latter waves may also be interpreted as being due to phase matching, but they may alternately be interpreted as constituting the eigenfrequencies of the internal fluid contained in an elastic enclosure.

Invisible magnetic sensors

NASA Astrophysics Data System (ADS)

Mach-Batlle, Rosa; Navau, Carles; Sanchez, Alvaro

2018-04-01

Sensing magnetic fields is essential in many applications in biomedicine, transportation, or smart cities. The distortion magnetic sensors create in response to the field they are detecting may hinder their use, for example, in applications requiring dense packaging of sensors or accurately shaped field distributions. For sensing electromagnetic waves, cloaking shells that reduce the scattering of sensors have been introduced. However, the problem of making a magnetic sensor undetectable remains unsolved. Here, we present a general strategy on how to make a sensor magnetically invisible while keeping its ability to sense. The sensor is rendered undetectable by surrounding it with a spherical shell having a tailored magnetic permeability. Our method can be applied to arbitrary shaped magnetic sensors in arbitrary magnetic fields. The invisibility can be made exact when the sensor is spherical and the probed field is uniform. A metasurface composed of superconducting pieces is presented as a practical realization of the ideal invisibility shell.

Chemical Structure, Ensemble and Single-Particle Spectroscopy of Thick-Shell InP-ZnSe Quantum Dots.

PubMed

Reid, Kemar R; McBride, James R; Freymeyer, Nathaniel J; Thal, Lucas B; Rosenthal, Sandra J

2018-02-14

Thick-shell (>5 nm) InP-ZnSe colloidal quantum dots (QDs) grown by a continuous-injection shell growth process are reported. The growth of a thick crystalline shell is attributed to the high temperature of the growth process and the relatively low lattice mismatch between the InP core and ZnSe shell. In addition to a narrow ensemble photoluminescence (PL) line-width (∼40 nm), ensemble and single-particle emission dynamics measurements indicate that blinking and Auger recombination are reduced in these heterostructures. More specifically, high single-dot ON-times (>95%) were obtained for the core-shell QDs, and measured ensemble biexciton lifetimes, τ 2x ∼ 540 ps, represent a 7-fold increase compared to InP-ZnS QDs. Further, high-resolution energy dispersive X-ray (EDX) chemical maps directly show for the first time significant incorporation of indium into the shell of the InP-ZnSe QDs. Examination of the atomic structure of the thick-shell QDs by high-angle annular dark-field scanning transmission electron microscopy (HAADF-STEM) reveals structural defects in subpopulations of particles that may mitigate PL efficiencies (∼40% in ensemble), providing insight toward further synthetic refinement. These InP-ZnSe heterostructures represent progress toward fully cadmium-free QDs with superior photophysical properties important in biological labeling and other emission-based technologies.

Shell-Dependent Photoluminescence Studies Provide Mechanistic Insights into the Off-Grey-On Transitions of Blinking Quantum Dots.

PubMed

Gao, Feng; Bajwa, Pooja; Nguyen, Anh; Heyes, Colin D

2017-03-28

The majority of quantum dot (QD) blinking studies have used a model of switching between two distinct fluorescence intensity levels, "on" and "off". However, a distinct intermediate intensity level has been identified in some recent reports, a so-called "grey" or "dim" state, which has brought this binary model into question. While this grey state has been proposed to result from the formation of a trion, it is still unclear under which conditions it is present in a QD. By performing shell-dependent blinking studies on CdSe QDs, we report that the populations of the grey state and the on state are strongly dependent on both the shell material and its thickness. We found that adding a ZnS shell did not result in a significant population of the grey state. Using ZnSe as the shell material resulted in a slightly higher population of the grey state, although it was still poorly resolved. However, adding a CdS shell resulted in the population of a grey state, which depended strongly on its thickness up to 5 ML. Interestingly, while the frequency of transitions to and from the grey state showed a very strong dependence on CdS shell thickness, the brightness of and the dwell time in the grey state did not. Moreover, we found that the grey state acts as an on-pathway intermediate state between on and off states, with the thickness of the shell determining the transition probability between them. We also identified two types of blinking behavior in QDs, one that showed long-lived but lower intensity on states and another that showed short-lived but brighter on states that also depended on the shell thickness. Intensity-resolved single QD fluorescence lifetime analysis was used to identify the relationship between the various exciton decay pathways and the resulting intensity levels. We used this data to propose a model in which multiple on, grey, and off states exist whose equilibrium populations vary with time that give rise to the various intensity levels of single QDs and which depends on shell composition and thickness.

Hybrid indirect-drive/direct-drive target for inertial confinement fusion

DOE Office of Scientific and Technical Information (OSTI.GOV)

Perkins, Lindsay John

A hybrid indirect-drive/direct drive for inertial confinement fusion utilizing laser beams from a first direction and laser beams from a second direction including a central fusion fuel component; a first portion of a shell surrounding said central fusion fuel component, said first portion of a shell having a first thickness; a second portion of a shell surrounding said fusion fuel component, said second portion of a shell having a second thickness that is greater than said thickness of said first portion of a shell; and a hohlraum containing at least a portion of said fusion fuel component and at leastmore » a portion of said first portion of a shell; wherein said hohlraum is in a position relative to said first laser beam and to receive said first laser beam and produce X-rays that are directed to said first portion of a shell and said fusion fuel component; and wherein said fusion fuel component and said second portion of a shell are in a position relative to said second laser beam such that said second portion of a shell and said fusion fuel component receive said second laser beam.« less

Influence of shell thickness on thermal stability of bimetallic Al-Pd nanoparticles

NASA Astrophysics Data System (ADS)

Wen, John Z.; Nguyen, Ngoc Ha; Rawlins, John; Petre, Catalin F.; Ringuette, Sophie

2014-07-01

Aluminum-based bimetallic core-shell nanoparticles have shown promising applications in civil and defense industries. This study addresses the thermal stability of aluminum-palladium (Al-Pd) core/shell nanoparticles with a varying shell thickness of 5, 6, and 7 Å, respectively. The classic molecular dynamics (MD) simulations are performed in order to investigate the effects of the shell thickness on the ignition mechanism and subsequent energetic processes of these nanoparticles. The histograms of temperature change and structural evolution clearly show the inhibition role of the Pd shell during ignition. While the nanoparticle with a thicker shell is more thermally stable and hence requires more excess energy, stored as the potential energy of the nanoparticle and provided through numerically heating, to initiate the thermite reaction, a higher adiabatic temperature can be produced from this nanoparticle, thanks to its greater content of Pd. The two-stage thermite reactions are discussed with their activation energy based on the energy balance processes during MD heating and production. Analyses of the simulation results reveal that the inner pressure of the core-shell nanoparticle increases with both temperature and the absorbed thermal energy during heating, which may result in a breakup of the Pd shell.

Computer Simulation of Magnetic Nova Shell Expantion

NASA Astrophysics Data System (ADS)

Dudnikova, Galina; Nikitin, Sergei; Snytnikov, Valeri; Vshivkov, Vitali

2000-10-01

An asymmetrical character of the shell expantion observed at many Nova may be associated with infuence of an inherent star magnetic field. Magneto-dipole energy of a Nova is much less than a kinetic energy of an exploding envelope. By this reason the conventional hydrodynamic models of point-like explosion with a spherical outward-directed shock wave do not consider effect of star magnetic field on the plasma movement. We used the numerical model based on the system of equations of the hybrid type( MHD approximation for electrons and Vlasov kinetic equations for ions). PIC-method for solving Vlasov equations was used. It gives an opportunaty to consider a complicated multi-flow motion of particles in plasma at super-Alfven velocity. At the beginning there is an immobile (cold) background plasma of a homogeneous concentration in a cylindrical region with a dipole magnetic field. Into the central spherical region of radius R, where the magnetic field remains uniform and constant , the external plasma does not penetrate with elastic reflections of ions at the spherical core surface. This boundary is spaced at r<

Origin and thermal evolution of Mars

NASA Technical Reports Server (NTRS)

Schubert, Gerald; Soloman, S. C.; Turcotte, D. L.; Drake, M. J.; Sleep, N. H.

1990-01-01

The thermal evolution of Mars is governed by subsolidus mantle convection beneath a thick lithosphere. Models of the interior evolution are developed by parameterizing mantle convective heat transport in terms of mantle viscosity, the superadiabatic temperature rise across the mantle, and mantle heat production. Geological, geophysical, and geochemical observations of the compositon and structure of the interior and of the timing of major events in Martian evolution are used to constrain the model computations. Such evolutionary events include global differentiation, atmospheric outgassing, and the formation of the hemispherical dichotomy and Tharsis. Numerical calculations of fully three-dimensional, spherical convection in a shell the size of the Martian mantle are performed to explore plausible patterns of Martian mantel convection and to relate convective features, such as plumes, to surface features, such as Tharsis. The results from the model calculations are presented.

Advantages of using gold hollow nanoshells in cancer photothermal therapy

NASA Astrophysics Data System (ADS)

Abbasi, Sattar; Servatkhah, Mojtaba; Keshtkar, Mohammad Mehdi

2016-08-01

Lots of studies have been conducted on the optical properties of gold nanoparticles in the first region of near infrared (650 nm-950 nm), however new findings show that the second region of near-infrared (1000 nm-1350 nm) penetrates to the deeper tissues of the human body. Therefore, using the above-mentioned region in photo-thermal therapy (PTT) of cancer will be more appropriate. In this paper, absorption efficiency is calculated for gold spherical and rod-shaped nanoshells by the finite element method (FEM). The results show that the surface plasmon frequency of these nanostructures is highly dependent on the dimension and thickness of shell and it can be adjusted to the second region of near-infrared. Thus, due to their optical tunability and their high absorption efficiency the hollow nanoshells are the most appropriate options for eradicating cancer tissues.

X-ray and Neutron Scattering Study of the Formation of Core–Shell-Type Polyoxometalates

DOE PAGES

Yin, Panchao; Wu, Bin; Mamontov, Eugene; ...

2016-02-05

A typical type of core-shell polyoxometalates can be obtained through the Keggin-type polyoxometalate-templated growth of a layer of spherical shell structure of {Mo 72Fe 30}. Small angle X-ray scattering is used to study the structural features and stability of the core-shell structures in aqueous solutions. Time-resolved small angle X-ray scattering is applied to monitor the synthetic reactions and a three-stage formation mechanism is proposed to describe the synthesis of the core-shell polyoxometalates based on the monitoring results. Quasi-elastic and inelastic neutron scattering are used to probe the dynamics of water molecules in the core-shell structures and two different types ofmore » water molecules, the confined and structured water, are observed. These water molecules play an important role in bridging core and shell structures and stabilizing the cluster structures. A typical type of core shell polyoxometalates can be obtained through the Keggin-type polyoxometalate-templated growth of a layer of spherical shell structure of {Mo 72Fe 30}. Small-angle X-ray scattering is used to study the structural features and stability of the core shell structures in aqueous solutions. Time-resolved small-angle X-ray scattering is applied to monitor the synthetic reactions, and a three-stage formation mechanism is proposed to describe the synthesis of the core shell polyoxometalates based on the monitoring results. New protocols have been developed by fitting the X-ray data with custom physical models, which provide more convincing, objective, and completed data interpretation. Quasi-elastic and inelastic neutron scattering are used to probe the dynamics of water molecules in the core shell structures, and two different types of water molecules, the confined and structured water, are observed. These water molecules play an important role in bridging core and shell structures and stabilizing the cluster structures.« less

Retinal sensitivity and choroidal thickness in high myopia.

PubMed

Zaben, Ahmad; Zapata, Miguel Á; Garcia-Arumi, Jose

2015-03-01

To estimate the association between choroidal thickness in the macular area and retinal sensitivity in eyes with high myopia. This investigation was a transversal study of patients with high myopia, all of whom had their retinal sensitivity measured with macular integrity assessment microperimetry. The choroidal thicknesses in the macular area were then measured by optical coherence tomography, and statistical correlations between their functionality and the anatomical structuralism, as assessed by both types of measurements, were analyzed. Ninety-six eyes from 77 patients with high myopia were studied. The patients had a mean age ± standard deviation of 38.9 ± 13.2 years, with spherical equivalent values ranging from -6.00 diopter to -20.00 diopter (8.74 ± 2.73 diopter). The mean central choroidal thickness was 159.00 ± 50.57. The mean choroidal thickness was directly correlated with sensitivity (r = 0.306; P = 0.004) and visual acuity but indirectly correlated with the spherical equivalent values and patient age. The mean sensitivity was not significantly correlated with the macular foveal thickness (r = -0.174; P = 0.101) or with the overall macular thickness (r = 0.103; P = 0.334); furthermore, the mean sensitivity was significantly correlated with visual acuity (r = 0.431; P < 0.001) and the spherical equivalent values (r = -0.306; P = 0.003). Retinal sensitivity in highly myopic eyes is directly correlated with choroidal thickness and does not seem to be associated with retinal thickness. Thus, in patients with high myopia, accurate measurements of choroidal thickness may provide more accurate information about this pathologic condition because choroidal thickness correlates to a greater degree with the functional parameters, patient age, and spherical equivalent values.

Synthesis and Manipulation of Biofunctional Magnetic Particles

DTIC Science & Technology

2007-06-18

G. M., J Am. Chem. Soc., 2003, 125, 12704-12705. 6. "Asymmetric Dimers Can be Formed by Dewetting Half-Shells of Gold Deposited on the Surfaces of...Be Formed by Dewetting Half-Shells of Gold Deposited on the Surfaces of Spherical Silica Colloids", Lu, Y., Xiong, H. Jing, X., Xia, Y., Prentiss, M

Composite Materials for Maxillofacial Prostheses.

DTIC Science & Technology

1980-08-01

projected composite systems are elastomeric-shelled, liquid-filled * microcapsules . Experiments continued on the interfacial polymerization process with...filled microcapsules . Experiments continued on the interfacial polymerization process, with spherical, sealed, capsules achieved. Needs identified are...consists of liquid-filled, elastomeric-shelled microcapsules held together to form a deformable mass; this is to simulate the semi-liquid cellular structure

Mid-Infrared Interferometry on Spectral Lines. II. Continuum (Dust) Emission Around IRC +10216 and VY Canis Majoris

NASA Astrophysics Data System (ADS)

Monnier, J. D.; Danchi, W. C.; Hale, D. S.; Lipman, E. A.; Tuthill, P. G.; Townes, C. H.

2000-11-01

The University of California Berkeley Infrared Spatial Interferometer has measured the mid-infrared visibilities of the carbon star IRC +10216 and the red supergiant VY CMa. The dust shells around these sources have been previously shown to be time variable, and these new data are used to probe the evolution of the dust shells on a decade timescale, complementing contemporaneous studies at other wavelengths. Self-consistent, spherically symmetric models at maximum and minimum light both show the inner radius of the IRC +10216 dust shell to be much larger (150 mas) than expected from the dust-condensation temperature, implying that dust production has slowed or stopped in recent years. Apparently, dust does not form every pulsational cycle (638 days), and these mid-infrared results are consistent with recent near-infrared imaging, which indicates little or no new dust production in the last 3 yr. Spherically symmetric models failed to fit recent VY CMa data, implying that emission from the inner dust shell is highly asymmetric and/or time variable.

Morphology conserving aminopropyl functionalization of hollow silica nanospheres in toluene

NASA Astrophysics Data System (ADS)

Dobó, Dorina G.; Berkesi, Dániel; Kukovecz, Ákos

2017-07-01

Inorganic nanostructures containing cavities of monodisperse diameter distribution find applications in e.g. catalysis, adsorption and drug delivery. One of their possible synthesis routes is the template assisted core-shell synthesis. We synthesized hollow silica spheres around polystyrene cores by the sol-gel method. The polystyrene template was removed by heat treatment leaving behind a hollow spherical shell structure. The surface of the spheres was then modified by adding aminopropyl groups. Here we present the first experimental evidence that toluene is a suitable alternative functionalization medium for the resulting thin shells, and report the comprehensive characterization of the amino-functionalized hollow silica spheres based on scanning electron microscopy, transmission electron microscopy, N2 adsorption, FT-IR spectroscopy, Raman spectroscopy and electrokinetic potential measurement. Both the presence of the amino groups and the preservation of the hollow spherical morphology were unambiguously proven. The introduction of the amine functionality adds amphoteric character to the shell as shown by the zeta potential vs. pH function. Unlike pristine silica particles, amino-functionalized nanosphere aqueous sols can be stable at both acidic and basic conditions.

Indium nanoparticles for ultraviolet surface-enhanced Raman spectroscopy

NASA Astrophysics Data System (ADS)

Das, Rupali; Soni, R. K.

2018-05-01

Ultraviolet Surface-enhanced Raman spectroscopy (UVSERS) has emerged as an efficient molecular spectroscopy technique for ultra-sensitive and ultra-low detection of analyte concentration. The generic SERS substrates based on gold and silver nanostructures have been extensively explored for high local electric field enhancement only in visible-NIR region of the electromagnetic spectrum. The template synthesis of controlled nanoscale size metallic nanostructures supporting localized surface plasmon resonance (LSPR) in the UV region have been recently explored due to their ease of synthesis and potential applications in optoelectronic, catalysis and magnetism. Indium (In0) nanoparticles exhibit active surface plasmon resonance (SPR) in ultraviolet (UV) and deep-ultaviolet (DUV) region with optimal absorption losses. This extended accessibility makes indium a promising material for UV plasmonic, chemical sensing and more recently in UV-SERS. In this work, spherical indium nanoparticles (In NPs) were synthesized by modified polyol reduction method using NaBH4 having local surface plasmon resonance near 280 nm. The as-synthesized spherical In0 nanoparticles were then coated with thin silica shells of thickness ˜ 5nm by a modified Stober method protecting the nanoparticles from agglomeration, direct contact with the probed molecules as well as prevent oxidation of the nanoparticles. Morphological evolution of In0 nanoparticles and SiO2 coating were characterized by transmission electron microscope (TEM). An enhanced near resonant shell-isolated SERS activity from thin film of tryptophan (Tryp) molecules deposited on indium coated substrates under 325nm UV excitation was observed. Finite difference time domain (FDTD) method is employed to comprehend the experimental results and simulate the electric field contours which showed amplified electromagnetic field localized around the nanostructures. The comprehensive analysis indicates that indium is a promising alternate exogenous contrast agent for efficient Raman spectroscopy from molecules.

Exact solutions for laminated composite cylindrical shells in cylindrical bending

NASA Technical Reports Server (NTRS)

Yuan, F. G.

1992-01-01

Analytic elasticity solutions for laminated composite cylindrical shells under cylindrical bending are presented. The material of the shell is assumed to be general cylindrically anisotropic. Based on the theory of cylindrical anisotropic elasticity, coupled governing partial differential equations are developed. The general expressions for the stresses and displacements in the laminated composite cylinders are discussed. The closed form solutions based on Classical Shell Theory (CST) and Donnell's (1933) theory are also derived for comparison purposes. Three examples illustrate the effect of radius-to-thickness ratio, coupling and stacking sequence. The results show that, in general, CST yields poor stress and displacement distributions for thick-section composite shells, but converges to the exact elasticity solution as the radius-to-thickness ratio increases. It is also shown that Donnell's theory significantly underestimates the stress and displacement response.

Inertial modes and their transition to turbulence in a differentially rotating spherical gap flow

NASA Astrophysics Data System (ADS)

Hoff, Michael; Harlander, Uwe; Andrés Triana, Santiago; Egbers, Christoph

2016-04-01

We present a study of inertial modes in a spherical shell experiment. Inertial modes are Coriolis-restored linear wave modes, often arise in rapidly-rotating fluids (e.g. in the Earth's liquid outer core [1]). Recent experimental works showed that inertial modes exist in differentially rotating spherical shells. A set of particular inertial modes, characterized by (l,m,ˆω), where l, m is the polar and azimuthal wavenumber and ˆω = ω/Ωout the dimensionless frequency [2], has been found. It is known that they arise due to eruptions in the Ekman boundary layer of the outer shell. But it is an open issue why only a few modes develop and how they get enhanced. Kelley et al. 2010 [3] showed that some modes draw their energy from detached shear layers (e.g. Stewartson layers) via over-reflection. Additionally, Rieutord et al. (2012) [4] found critical layers within the shear layers below which most of the modes cannot exist. In contrast to other spherical shell experiments, we have a full optical access to the flow. Therefore, we present an experimental study of inertial modes, based on Particle-Image-Velocimetry (PIV) data, in a differentially rotating spherical gap flow where the inner sphere is subrotating or counter-rotating at Ωin with respect to the outer spherical shell at Ωout, characterized by the Rossby number Ro = (Ωin - Ωout)/Ωout. The radius ratio of η = 1/3, with rin = 40mm and rout = 120mm, is close to that of the Earth's core. Our apparatus is running at Ekman numbers (E ≈ 10-5, with E = ν/(Ωoutrout2), two orders of magnitude higher than most of the other experiments. Based on a frequency-Rossby number spectrogram, we can partly confirm previous considerations with respect to the onset of inertial modes. In contrast, the behavior of the modes in the counter-rotation regime is different. We found a triad interaction between three dominant inertial modes, where one is a slow axisymmetric Rossby mode [5]. We show that the amplitude of the most dominant mode (l,m,ˆω) = (3,2,˜ 0.71) is increasing with increasing |Ro| until a critical Rossby number Rocrit. Accompanying with this is an increase of the zonal mean flow outside the tangent cylinder, leading to enhanced angular momentum transport. At the particular Rocrit, the wave mode, and the entire flow, breaks up into smaller-scale turbulence [6], together with a strong increase of the zonal mean flow inside the tangent cylinder. We found that the critical Rossby number scales approximately with E1/5. References [1] Aldridge, K. D.; Lumb, L. I. (1987): Inertial waves identified in the Earth's fluid outer core. Nature 325 (6103), S. 421-423. DOI: 10.1038/325421a0. [2] Greenspan, H. P. (1968): The theory of rotating fluids. London: Cambridge U.P. (Cambridge monographs on mechanics and applied mathematics). [3] Kelley, D. H.; Triana, S. A.; Zimmerman, D. S.; Lathrop, D. P. (2010): Selection of inertial modes in spherical Couette flow. Phys. Rev. E 81 (2), 26311. DOI: 10.1103/PhysRevE.81.026311. [4] Rieutord, M.; Triana, S. A.; Zimmerman, D. S.; Lathrop, D. P. (2012): Excitation of inertial modes in an experimental spherical Couette flow. Phys. Rev. E 86 (2), 026304. DOI: 10.1103/PhysRevE.86.026304. [5] Hoff, M., Harlander, U., Egbers, C. (2016): Experimental survey of linear and nonlinear inertial waves and wave instabilities in a spherical shell. J. Fluid Mech., (in print) [6] Kerswell, R. R. (1999): Secondary instabilities in rapidly rotating fluids: inertial wave breakdown. Journal of Fluid Mechanics 382, S. 283-306. DOI: 10.1017/S0022112098003954.

Fabrication of Ni@Ti core-shell nanoparticles by modified gas aggregation source

NASA Astrophysics Data System (ADS)

Hanuš, J.; Vaidulych, M.; Kylián, O.; Choukourov, A.; Kousal, J.; Khalakhan, I.; Cieslar, M.; Solař, P.; Biederman, H.

2017-11-01

Ni@Ti core-shell nanoparticles were prepared by a vacuum based method using the gas aggregation source (GAS) of nanoparticles. Ni nanoparticles fabricated in the GAS were afterwards coated by a Ti shell. The Ti shell was deposited by means of magnetron sputtering. The Ni nanoparticles were decelerated in the vicinity of the magnetron to the Ar drift velocity in the second deposition chamber. X-ray photoelectron spectroscopy and energy dispersive x-ray spectroscopy analysis of the nanoparticles showed the core-shell structure. It was shown that the thickness of the shell can be easily tuned by the process parameters with a maximum achieved thickness of the Ti shell ~2.5 nm. The core-shell structure was confirmed by the STEM analysis of the particles.

Influence of Shell Thickness on the Performance of NiO-Based All-Inorganic Quantum Dot Light-Emitting Diodes.

PubMed

Wang, Ting; Zhu, Bingyan; Wang, Shuangpeng; Yuan, Qilin; Zhang, Han; Kang, Zhihui; Wang, Rong; Zhang, Hanzhuang; Ji, Wenyu

2018-05-02

The effect of shell thickness on the performance of all-inorganic quantum dot light-emitting diodes (QLEDs) is explored by employing a series of green quantum dots (QDs) (Zn x Cd 1- x Se/ZnS core/shell QDs with different ZnS shell thicknesses) as the emitters. ZnO nanoparticles and sol-gel NiO are employed as the electron and hole transport materials, respectively. Time-resolved and steady-state photoluminescence results indicate that positive charging processes might occur for the QDs deposited on NiO, which results in emission quenching of QDs and poor device performance. The thick shell outside the core in QDs not only largely suppresses the QD emission quenching but also effectively preserves the excitons in QDs from dissociation of electron-hole pairs when they are subjected to an electric field. The peak efficiency of 4.2 cd/A and maximum luminance of 4205 cd/m 2 are achieved for the device based on QDs with the thickest shells (∼4.2 nm). We anticipate that these results will spur progress toward the design and realization of efficient all-inorganic QLEDs as a platform for the QD-based full-colored displays.

The effect of embryonic development on the thickness of the eggshells of the coturnix quail

USGS Publications Warehouse

Kreitzer, J.F.

1972-01-01

The average thickness of the shells from 75 unincubated coturnix quail eggs was found to be 0.193 mm. This was 7.3 percent greater than the average thickness (0.179 mm.) of the shells from 60 fully incubated eggs from the same hens. The two sets of eggs were collected simultaneously. This thickness difference was statistically significant (t-test:p< 0.005).

Enhanced direct-drive implosions with thin high-Z ablation layers.

PubMed

Mostovych, Andrew N; Colombant, Denis G; Karasik, Max; Knauer, James P; Schmitt, Andrew J; Weaver, James L

2008-02-22

New direct-drive spherical implosion experiments with deuterium filled plastic shells have demonstrated significant and absolute (2x) improvements in neutron yield when the shells are coated with a very thin layer ( approximately 200-400 A) of high-Z material such as palladium. This improvement is interpreted as resulting from increased stability of the imploding shell. These results provide for a possible path to control laser imprint and stability in laser-fusion-energy target designs.

Radially Symmetric Motions of Nonlinearly Viscoelastic Bodies Under Live Loads

NASA Astrophysics Data System (ADS)

Stepanov, Alexey B.; Antman, Stuart S.

2017-12-01

This paper treats radially symmetric motions of nonlinearly viscoelastic circular-cylindrical and spherical shells subjected to the live loads of centrifugal force and (time-dependent) hydrostatic pressures. The governing equations are exact versions of those for 3-dimensional continuum mechanics (so shell does not connote an approximate via some shell theory). These motions are governed by quasilinear third-order parabolic-hyperbolic equations having but one independent spatial variable. The principal part of such a partial differential equation is determined by a general family of nonlinear constitutive equations. The presence of strains in two orthogonal directions requires a careful treatment of constitutive restrictions that are physically natural and support the analysis. The interaction of geometrically exact formulations, the compatible use of general constitutive equations for material response, and the presence of live loads show how these factors play crucial roles in the behavior of solutions. In particular, for different kinds of live loads there are thresholds separating materials that produce qualitatively different dynamical behavior. The analysis (using classical methods) covers infinite-time blowup for cylindrical shells subject to centrifugal forces, infinite-time blowup for cylindrical shells subject to steady and time-dependent hydrostatic pressures, finite-time blowup for spherical shells subject to steady and time-dependent hydrostatic pressures, and the preclusion of total compression. This paper concludes with a sketch (using some modern methods) of the existence of regular solutions until the time of blowup.

Casimir self-entropy of a spherical electromagnetic δ -function shell

NASA Astrophysics Data System (ADS)

Milton, Kimball A.; Kalauni, Pushpa; Parashar, Prachi; Li, Yang

2017-10-01

In this paper we continue our program of computing Casimir self-entropies of idealized electrical bodies. Here we consider an electromagnetic δ -function sphere ("semitransparent sphere") whose electric susceptibility has a transverse polarization with arbitrary strength. Dispersion is incorporated by a plasma-like model. In the strong-coupling limit, a perfectly conducting spherical shell is realized. We compute the entropy for both low and high temperatures. The transverse electric self-entropy is negative as expected, but the transverse magnetic self-entropy requires ultraviolet and infrared renormalization (subtraction), and, surprisingly, is only positive for sufficiently strong coupling. Results are robust under different regularization schemes. These rather surprising findings require further investigation.

Drastic difference between hole and electron injection through the gradient shell of CdxSeyZn1-xS1-y quantum dots.

PubMed

Abdellah, Mohamed; Poulsen, Felipe; Zhu, Qiushi; Zhu, Nan; Žídek, Karel; Chábera, Pavel; Corti, Annamaria; Hansen, Thorsten; Chi, Qijin; Canton, Sophie E; Zheng, Kaibo; Pullerits, Tõnu

2017-08-31

Ultrafast fluorescence spectroscopy was used to investigate the hole injection in Cd x Se y Zn 1-x S 1-y gradient core-shell quantum dot (CSQD) sensitized p-type NiO photocathodes. A series of CSQDs with a wide range of shell thicknesses was studied. Complementary photoelectrochemical cell measurements were carried out to confirm that the hole injection from the active core through the gradient shell to NiO takes place. The hole injection from the valence band of the QDs to NiO depends much less on the shell thickness when compared to the corresponding electron injection to n-type semiconductor (ZnO). We simulate the charge carrier tunneling through the potential barrier due to the gradient shell by numerically solving the Schrödinger equation. The details of the band alignment determining the potential barrier are obtained from X-ray spectroscopy measurements. The observed drastic differences between the hole and electron injection are consistent with a model where the hole effective mass decreases, while the gradient shell thickness increases.

Elucidation of Two Giants: Challenges to Thick-shell Synthesis in CdSe/ZnSe and ZnSe/CdS Core/Shell Quantum Dots

DOE Office of Scientific and Technical Information (OSTI.GOV)

Acharya, Krishna P.; Nguyen, Hue M.; Paulite, Melissa

2015-03-06

Core/thick-shell "giant" quantum dots (gQDs) possessing type II electronic structures exhibit suppressed blinking and diminished nonradiative Auger recombination. Here we investigate CdSe/ZnSe and ZnSe/CdS as potential new gQDs. We show theoretically and experimentally that both can exhibit partial or complete spatial separation of an excited-state electron–hole pair (i.e., type II behavior). However, we reveal that thick-shell growth is challenged by competing processes: alloying and cation exchange. We demonstrate that these can be largely avoided by choice of shelling conditions (e.g., time, temperature, and QD core identity). The resulting CdSe/ZnSe gQDs exhibit unusual single-QD properties, principally emitting from dim gray statesmore » but having high two-exciton (biexciton) emission efficiencies, whereas ZnSe/CdS gQDs show characteristic gQD blinking suppression, though only if shelling is accompanied by partial cation exchange.« less

Suppressed Blinking and Auger Recombination in Near-Infrared Type-II InP/CdS Nanocrystal Quantum Dots

PubMed Central

Dennis, Allison M.; Mangum, Benjamin D.; Piryatinski, Andrei; Park, Young-Shin; Hannah, Daniel C.; Casson, Joanna L.; Williams, Darrick J.; Schaller, Richard D.; Htoon, Han; Hollingsworth, Jennifer A.

2012-01-01

Non-blinking excitonic emission from near-infrared and type-II nanocrystal quantum dots (NQDs) is reported for the first time. To realize this unusual degree of stability at the single-dot level, novel InP/CdS core/shell NQDs were synthesized for a range of shell thicknesses (~1–11 monolayers of CdS). Ensemble spectroscopy measurements (photoluminescence peak position and radiative lifetimes) and electronic structure calculations established the transition from type-I to type-II band alignment in these heterostructured NQDs. More significantly, single-NQD studies revealed clear evidence for blinking suppression that was not strongly shell-thickness dependent, while photobleaching and biexciton lifetimes trended explicitly with extent of shelling. Specifically, very long biexciton lifetimes—up to >7 ns—were obtained for the thickest-shell structures, indicating dramatic suppression of non-radiative Auger recombination. This new system demonstrates that electronic structure and shell thickness can be employed together to effect control over key single-dot and ensemble NQD photophysical properties. PMID:23030497

Geodynamic Modeling of Planetary Ice-Oceans: Evolution of Ice-Shell Thickness in Convecting Two-Phase Systems

NASA Astrophysics Data System (ADS)

Allu Peddinti, D.; McNamara, A. K.

2016-12-01

Along with the newly unveiled icy surface of Pluto, several icy planetary bodies show indications of an active surface perhaps underlain by liquid oceans of some size. This augments the interest to explore the evolution of an ice-ocean system and its surface implications. The geologically young surface of the Jovian moon Europa lends much speculation to variations in ice-shell thickness over time. Along with the observed surface features, it suggests the possibility of episodic convection and conduction within the ice-shell as it evolved. What factors would control the growth of the ice-shell as it forms? If and how would those factors determine the thickness of the ice-shell and consequently the heat transfer? Would parameters such as tidal heating or initial temperature affect how the ice-shell grows and to what significance? We perform numerical experiments using geodynamical models of the two-phase ice-water system to study the evolution of planetary ice-oceans such as that of Europa. The models evolve self-consistently from an initial liquid ocean as it cools with time. The effects of presence, absence and magnitude of tidal heating on ice-shell thickness are studied in different models. The vigor of convection changes as the ice-shell continues to thicken. Initial modeling results track changes in the growth rate of the ice-shell as the vigor of the convection changes. The magnitude and temporal location of the rate change varies with different properties of tidal heating and values of initial temperature. A comparative study of models is presented to demonstrate how as the ice-shell is forming, its growth rate and convection are affected by processes such as tidal heating.

Thick or Thin Ice Shell on Europa? Artist Concept

NASA Image and Video Library

2007-12-13

Scientists are all but certain that Europa has an ocean underneath its icy surface, but they do not know how thick this ice might be. This artist concept illustrates two possible cut-away views through Europa ice shell.

Pteropods counter mechanical damage and dissolution through extensive shell repair.

PubMed

Peck, Victoria L; Oakes, Rosie L; Harper, Elizabeth M; Manno, Clara; Tarling, Geraint A

2018-01-17

The dissolution of the delicate shells of sea butterflies, or pteropods, has epitomised discussions regarding ecosystem vulnerability to ocean acidification over the last decade. However, a recent demonstration that the organic coating of the shell, the periostracum, is effective in inhibiting dissolution suggests that pteropod shells may not be as susceptible to ocean acidification as previously thought. Here we use micro-CT technology to show how, despite losing the entire thickness of the original shell in localised areas, specimens of polar species Limacina helicina maintain shell integrity by thickening the inner shell wall. One specimen collected within Fram Strait with a history of mechanical and dissolution damage generated four times the thickness of the original shell in repair material. The ability of pteropods to repair and maintain their shells, despite progressive loss, demonstrates a further resilience of these organisms to ocean acidification but at a likely metabolic cost.

Acetabular shell deformation as a function of shell stiffness and bone strength.

PubMed

Dold, Philipp; Pandorf, Thomas; Flohr, Markus; Preuss, Roman; Bone, Martin C; Joyce, Tom J; Holland, James; Deehan, David

2016-04-01

Press-fit acetabular shells used for hip replacement rely upon an interference fit with the bone to provide initial stability. This process may result in deformation of the shell. This study aimed to model shell deformation as a process of shell stiffness and bone strength. A cohort of 32 shells with two different wall thicknesses (3 and 4 mm) and 10 different shell sizes (44- to 62-mm outer diameter) were implanted into eight cadavers. Shell deformation was then measured in the cadavers using a previously validated ATOS Triple Scan III optical system. The shell-bone interface was then considered as a spring system according to Hooke's law and from this the force exerted on the shell by the bone was calculated using a combined stiffness consisting of the measured shell stiffness and a calculated bone stiffness. The median radial stiffness for the 3-mm wall thickness was 4192 N/mm (range, 2920-6257 N/mm), while for the 4-mm wall thickness the median was 9633 N/mm (range, 6875-14,341 N/mm). The median deformation was 48 µm (range, 3-187 µm), while the median force was 256 N (range, 26-916 N). No statistically significant correlation was found between shell stiffness and deformation. Deformation was also found to be not fully symmetric (centres 180° apart), with a median angle discrepancy of 11.5° between the two maximum positive points of deformation. Further work is still required to understand how the bone influences acetabular shell deformation. © IMechE 2016.

G7 BiSpherical Acetabular Shell PMCF Study

ClinicalTrials.gov

2017-11-22

Rheumatoid Arthritis; Osteoarthritis; Noninflammatory Degenerative Joint Disease; Avascular Necrosis; Correction of Functional Deformity; Non-Union Fracture; Femoral Neck Fractures; Trochanteric Fractures

The effects of the chemical composition and strain on the electronic properties of GaSb/InAs core-shell nanowires

DOE Office of Scientific and Technical Information (OSTI.GOV)

Ning, Feng; Wang, Dan; Tang, Li-Ming, E-mail: lmtang@hnu.edu.cn

2014-09-07

The effects of the chemical composition and strain on the electronic properties of [111] zinc-blende (ZB) and [0001] wurtzite (WZ) GaSb/InAs core-shell nanowires (NWs) with different core diameters and shell thicknesses are studied using first-principles methods. The band structures of the [111] ZB GaSb/InAs core-shell NWs underwent a noticeable type-I/II band alignment transition, associated with a direct-to-indirect band gap transition under a compressive uniaxial strain. The band structures of the [0001] WZ GaSb/InAs core-shell NWs preserved the direct band gap under either compressive or tensile uniaxial strains. In addition, the band gaps and the effective masses of the carriers couldmore » be tuned by their composition. For the core-shell NWs with a fixed GaSb-core size, the band gaps decreased linearly with an increasing InAs-shell thickness, caused by the significant downshift of the conduction bands. For the [111] ZB GaSb/InAs core-shell NWs, the calculated effective masses indicated that the transport properties could be changed from hole-dominated conduction to electron-dominated conduction by changing the InAs-shell thickness.« less

Polarization effects on spectra of spherical core/shell nanostructures: Perturbation theory against finite difference approach

NASA Astrophysics Data System (ADS)

Ibral, Asmaa; Zouitine, Asmaa; Assaid, El Mahdi; El Achouby, Hicham; Feddi, El Mustapha; Dujardin, Francis

2015-02-01

Poisson equation is solved analytically in the case of a point charge placed anywhere in a spherical core/shell nanostructure, immersed in aqueous or organic solution or embedded in semiconducting or insulating matrix. Conduction and valence band-edge alignments between core and shell are described by finite height barriers. Influence of polarization charges induced at the surfaces where two adjacent materials meet is taken into account. Original expressions of electrostatic potential created everywhere in the space by a source point charge are derived. Expressions of self-polarization potential describing the interaction of a point charge with its own image-charge are deduced. Contributions of double dielectric constant mismatch to electron and hole ground state energies as well as nanostructure effective gap are calculated via first order perturbation theory and also by finite difference approach. Dependencies of electron, hole and gap energies against core to shell radii ratio are determined in the case of ZnS/CdSe core/shell nanostructure immersed in water or in toluene. It appears that finite difference approach is more efficient than first order perturbation method and that the effect of polarization charge may in no case be neglected as its contribution can reach a significant proportion of the value of nanostructure gap.

Microporous Co@C Nanoparticles Prepared by Dealloying CoAl@C Precursors: Achieving Strong Wideband Microwave Absorption via Controlling Carbon Shell Thickness.

PubMed

Li, Da; Liao, Haoyan; Kikuchi, Hiroaki; Liu, Tong

2017-12-27

Excellent magnetic features make Co-based materials promising candidates as high-performance microwave absorbers. However, it is still a significant challenge for Co-based absorbers to possess high-intensity and broadband absorption simultaneously, owing to the lack of dielectric loss and impedance matching. Herein, microporous Co@C nanoparticles (NPs) with carbon shell thicknesses ranging from 1.8-4.9 nm have been successfully synthesized by dealloying CoAl@C precursors. All of the samples exhibit high microwave absorption performance. The microporous Co@C sample possessing a carbon shell of 1.8 nm exhibits the highest absorption intensity among these samples with a minimum reflection loss (RL) of -141.1 dB, whose absorption bandwidth for RL ≤ -10 dB is 7.3 GHz. As the thickness of the carbon shell increases, the absorption bandwidth of the NPs becomes wider. For the sample with the carbon shell thickness of 4.9 nm, the absorption bandwidth for RL ≤ -10 dB reaches a record high of 13.2 GHz. The outstanding microwave attenuation properties are attributed to the dielectric loss of the carbon shell, the magnetic loss of the Co core, and the cooperation of the core-shell structure and microporous morphology. The strong wideband microwave absorption of the carbon-coated microporous Co NPs highlights their potential applications in microwave absorbing systems.

Chemical complexity in the winds of the oxygen-rich supergiant star VY Canis Majoris

NASA Astrophysics Data System (ADS)

Ziurys, L. M.; Milam, S. N.; Apponi, A. J.; Woolf, N. J.

2007-06-01

The interstellar medium is enriched primarily by matter ejected from old, evolved stars. The outflows from these stars create spherical envelopes, which foster gas-phase chemistry. The chemical complexity in circumstellar shells was originally thought to be dominated by the elemental carbon to oxygen ratio. Observations have suggested that envelopes with more carbon than oxygen have a significantly greater abundance of molecules than their oxygen-rich analogues. Here we report observations of molecules in the oxygen-rich shell of the red supergiant star VY Canis Majoris (VY CMa). A variety of unexpected chemical compounds have been identified, including NaCl, PN, HNC and HCO+. From the spectral line profiles, the molecules can be distinguished as arising from three distinct kinematic regions: a spherical outflow, a tightly collimated, blue-shifted expansion, and a directed, red-shifted flow. Certain species (SiO, PN and NaCl) exclusively trace the spherical flow, whereas HNC and sulphur-bearing molecules (amongst others) are selectively created in the two expansions, perhaps arising from shock waves. CO, HCN, CS and HCO+ exist in all three components. Despite the oxygen-rich environment, HCN seems to be as abundant as CO. These results suggest that oxygen-rich shells may be as chemically diverse as their carbon counterparts.

Chemical complexity in the winds of the oxygen-rich supergiant star VY Canis Majoris.

PubMed

Ziurys, L M; Milam, S N; Apponi, A J; Woolf, N J

2007-06-28

The interstellar medium is enriched primarily by matter ejected from old, evolved stars. The outflows from these stars create spherical envelopes, which foster gas-phase chemistry. The chemical complexity in circumstellar shells was originally thought to be dominated by the elemental carbon to oxygen ratio. Observations have suggested that envelopes with more carbon than oxygen have a significantly greater abundance of molecules than their oxygen-rich analogues. Here we report observations of molecules in the oxygen-rich shell of the red supergiant star VY Canis Majoris (VY CMa). A variety of unexpected chemical compounds have been identified, including NaCl, PN, HNC and HCO+. From the spectral line profiles, the molecules can be distinguished as arising from three distinct kinematic regions: a spherical outflow, a tightly collimated, blue-shifted expansion, and a directed, red-shifted flow. Certain species (SiO, PN and NaCl) exclusively trace the spherical flow, whereas HNC and sulphur-bearing molecules (amongst others) are selectively created in the two expansions, perhaps arising from shock waves. CO, HCN, CS and HCO+ exist in all three components. Despite the oxygen-rich environment, HCN seems to be as abundant as CO. These results suggest that oxygen-rich shells may be as chemically diverse as their carbon counterparts.

Interior of black holes and information recovery

NASA Astrophysics Data System (ADS)

Kawai, Hikaru; Yokokura, Yuki

2016-02-01

We analyze time evolution of a spherically symmetric collapsing matter from a point of view that black holes evaporate by nature. We first consider a spherical thin shell that falls in the metric of an evaporating Schwarzschild black hole of which the radius a (t ) decreases in time. The important point is that the shell can never reach a (t ) but it approaches a (t )-a (t )d/a (t ) d t . This situation holds at any radius because the motion of a shell in a spherically symmetric system is not affected by the outside. In this way, we find that the collapsing matter evaporates without forming a horizon. Nevertheless, a Hawking-like radiation is created in the metric, and the object looks the same as a conventional black hole from the outside. We then discuss how the information of the matter is recovered. We also consider a black hole that is adiabatically grown in the heat bath and obtain the interior metric. We show that it is the self-consistent solution of Gμ ν=8 π G ⟨Tμ ν⟩ and that the four-dimensional Weyl anomaly induces the radiation and a strong angular pressure. Finally, we analyze the internal structures of the charged and the slowly rotating black holes.

Choroidal Thickness in 3001 Chinese Children Aged 6 to 19 Years Using Swept-Source OCT

PubMed Central

Xiong, Shuyu; He, Xiangui; Deng, Junjie; Lv, Minzhi; Jin, Jiali; Sun, Sifei; Yao, Chunxia; Zhu, Jianfeng; Zou, Haidong; Xu, Xun

2017-01-01

The purpose of the cross-sectional study is to describe the values and distribution of choroidal thickness and to explore its related factors, especially age, in Chinese children. A total of 3001 Chinese school children aged 6 to 19 years underwent comprehensive ophthalmic examinations, including axial length and cycloplegic refraction. Choroidal thickness was measured by swept-source optical coherence tomography (SS-OCT). There was a greater difference in the more central regions between the myopes and emmetropes. Multiple regression analysis was performed to determine the associated factors of choroidal thickness. The results demonstrated that age was independently positively related to choroidal thickness for emmetropes (β = 3.859, p < 0.001), and mild myopes with spherical equivalent greater than −2.00 D (−1.25 D < spherical equivalent ≤ −0.50 D: β = 3.476, p = 0.006; −2.00 D < spherical equivalent ≤ −1.25 D: β = 3.232, p = 0.020). However, no significant relationship between age and choroidal thickness was found in children with spherical equivalent ≤ −2.00 D, suggesting that the protective effect of physiologic choroidal growth with age against rapid axial elongation disappeared while axial elongation becomes the dominant determinant of choroidal thickness among children with myopia worse than −2.00 D. PMID:28327553

Biomechanical evidence suggests extensive eggshell thinning during incubation in the Sanagasta titanosaur dinosaurs

PubMed Central

Taborda, Jeremías R. A.; Fiorelli, Lucas E.; Grellet-Tinner, Gerald

2018-01-01

The reproduction of titanosaur dinosaurs is still a complex and debated topic. Their Late Cretaceous nesting sites are distributed worldwide and their eggs display substantial morphological variations according to the parent species. In contrast to the typical 1.3–2.0 mm thick shells common to eggs of most titanosaur species (e.g., those that nested in Auca Mahuevo, Tama, Toteşti or Boseong), the Cretaceous Sanagasta eggs of Argentina display an unusual shell thickness of up to 7.9 mm. Their oviposition was synchronous with a palaeogeothermal process, leading to the hypothesis that their extra thick eggshell was an adaptation to this particular nesting environment. Although this hypothesis has already been supported indirectly through several investigations, the mechanical implications of developing such thick shells and how this might have affected the success of hatching remains untested. Finite element analyses estimate that the breaking point of the thick-shelled Sanagasta eggs is 14–45 times higher than for other smaller and equally sized titanosaur eggs. The considerable energetic disadvantage for piping through these thick eggshells suggests that their dissolution during incubation would have been paramount for a successful hatching.

Quasi-static axisymmetric eversion hemispherical domes made of elastomers

NASA Astrophysics Data System (ADS)

Kabrits, Sergey A.; Kolpak, Eugeny P.

2016-06-01

The paper considers numerical solution for the problem of quasi-static axisymmetric eversion of a spherical shell (hemisphere) under action of external pressure. Results based on the general nonlinear theory of shells made of elastomers, proposed by K. F. Chernykh. It is used two models of shells based on the hypotheses of the Kirchhoff and Timoshenko, modified K.F. Chernykh for the case of hyperelastic rubber-like material. The article presents diagrams of equilibrium states of eversion hemispheres for both models as well as the shape of the shell at different points in the diagram.

Core-Shell-Corona Micelles with a Responsive Shell.

PubMed

Gohy, Jean-François; Willet, Nicolas; Varshney, Sunil; Zhang, Jian-Xin; Jérôme, Robert

2001-09-03

A reactor for the synthesis of gold nanoparticles is one of the uses of a poly(styrene)-block-poly(2-vinylpyridine)-block-poly(ethylene oxide) triblock copolymer (PS-b-P2VP-b-PEO) which forms core-shell-corona micelles in water. Very low polydispersity spherical micelles are observed that consist of a PS core surrounded by a pH-sensitive P2VP shell and a corona of PEO chains end-capped by a hydroxyl group. The corona can act as a site for attaching responsive or sensing molecules. © 2001 WILEY-VCH Verlag GmbH, Weinheim, Fed. Rep. of Germany.

Review of high convergence implosion experiments with single and double shell targets

DOE Office of Scientific and Technical Information (OSTI.GOV)

Delamater, N. D.; Watt, R. G.; Varnum, W. S.

2002-01-01

Experiments have been been performed in recent years at the Omega laser studying double shell capsules as an a1 teinative, 11011 cryogenic, path towards ignition at NTF. Double shell capsules designed to mitigate the Au M-band radiation asymmetries, were experimentally found to perform well in both spherical and cylindrical hohlraums, achieving near 1-D (-90 %) clean calculated yield at convergence comparable to that required for NIF ignition. Near-term plans include directly driven double shell experiments at Omega, which eliminates Au M-band radiation as a yield degradation m ec h an i s in.

Cryogenic target formation using cold gas jets

DOEpatents

Hendricks, Charles D.

1981-01-01

A method and apparatus using cold gas jets for producing a substantially uniform layer of cryogenic materials on the inner surface of hollow spherical members having one or more layers, such as inertially imploded targets. By vaporizing and quickly refreezing cryogenic materials contained within a hollow spherical member, a uniform layer of the materials is formed on an inner surface of the spherical member. Basically the method involves directing cold gas jets onto a spherical member having one or more layers or shells and containing the cryogenic material, such as a deuterium-tritium (DT) mixture, to freeze the contained material, momentarily heating the spherical member so as to vaporize the contained material, and quickly refreezing the thus vaporized material forming a uniform layer of cryogenic material on an inner surface of the spherical member.

Cryogenic target formation using cold gas jets

DOEpatents

Hendricks, Charles D. [Livermore, CA

1980-02-26

A method and apparatus using cold gas jets for producing a substantially uniform layer of cryogenic materials on the inner surface of hollow spherical members having one or more layers, such as inertially imploded targets. By vaporizing and quickly refreezing cryogenic materials contained within a hollow spherical member, a uniform layer of the materials is formed on an inner surface of the spherical member. Basically the method involves directing cold gas jets onto a spherical member having one or more layers or shells and containing the cryogenic material, such as a deuterium-tritium (DT) mixture, to freeze the contained material, momentarily heating the spherical member so as to vaporize the contained material, and quickly refreezing the thus vaporized material forming a uniform layer of cryogenic material on an inner surface of the spherical member.

Dynamo Scaling Laws for Uranus and Neptune: The Role of Convective Shell Thickness on Dipolarity

NASA Astrophysics Data System (ADS)

Stanley, Sabine; Yunsheng Tian, Bob

2017-10-01

Previous dynamo scaling law studies (Christensen and Aubert, 2006) have demonstrated that the morphology of a planet’s magnetic field is determined by the local Rossby number (Ro_l): a non-dimensional diagnostic variable that quantifies the ratio of inertial forces to Coriolis forces on the average length scale of the flow. Dynamos with Ro_l <~ 0.1 produce dipolar dominated magnetic fields whereas dynamos with Ro_l >~ 0.1 produce multipolar magnetic fields. Scaling studies have also determined the dependence of the local Rossby number on non-dimensional parameters governing the system - specifically the Ekman, Prandtl, magnetic Prandtl and flux-based Rayleigh numbers (Olson and Christensen, 2006). When these scaling laws are applied to the planets, it appears that Uranus and Neptune should have dipole-dominated fields, contrary to observations. However, those scaling laws were derived using the specific convective shell thickness of the Earth’s core. Here we investigate the role of convective shell thickness on dynamo scaling laws. We find that the local Rossby number depends exponentially on the convective shell thickness. Including this new dependence on convective shell thickness, we find that the dynamo scaling laws now predict that Uranus and Neptune reside deeply in the multipolar regime, thereby resolving the previous contradiction with observations.

Polymeric microspheres

DOEpatents

Walt, David R.; Mandal, Tarun K.; Fleming, Michael S.

2004-04-13

The invention features core-shell microsphere compositions, hollow polymeric microspheres, and methods for making the microspheres. The microspheres are characterized as having a polymeric shell with consistent shell thickness.

Addendum to ''Thin-shell wormholes supported by ordinary matter in Einstein-Gauss-Bonnet gravity''

DOE Office of Scientific and Technical Information (OSTI.GOV)

Simeone, Claudio

2011-04-15

Thin-shell wormholes are constructed starting from the exotic branch of the Wiltshire spherically symmetric solution of Einstein-Gauss-Bonnet gravity. The energy-momentum tensor of the shell is studied, and it is shown that configurations supported by matter satisfying the energy conditions exist for certain values of the parameters. Differing from the previous result associated with the normal branch of the Wiltshire solution, this is achieved for small positive values of the Gauss-Bonnet parameter and for vanishing charge.

Computational investigation of longitudinal diffusion, eddy dispersion, and trans-particle mass transfer in bulk, random packings of core-shell particles with varied shell thickness and shell diffusion coefficient.

PubMed

Daneyko, Anton; Hlushkou, Dzmitry; Baranau, Vasili; Khirevich, Siarhei; Seidel-Morgenstern, Andreas; Tallarek, Ulrich

2015-08-14

In recent years, chromatographic columns packed with core-shell particles have been widely used for efficient and fast separations at comparatively low operating pressure. However, the influence of the porous shell properties on the mass transfer kinetics in core-shell packings is still not fully understood. We report on results obtained with a modeling approach to simulate three-dimensional advective-diffusive transport in bulk random packings of monosized core-shell particles, covering a range of reduced mobile phase flow velocities from 0.5 up to 1000. The impact of the effective diffusivity of analyte molecules in the porous shell and the shell thickness on the resulting plate height was investigated. An extension of Giddings' theory of coupled eddy dispersion to account for retention of analyte molecules due to stagnant regions in porous shells with zero mobile phase flow velocity is presented. The plate height equation involving a modified eddy dispersion term excellently describes simulated data obtained for particle-packings with varied shell thickness and shell diffusion coefficient. It is confirmed that the model of trans-particle mass transfer resistance of core-shell particles by Kaczmarski and Guiochon [42] is applicable up to a constant factor. We analyze individual contributions to the plate height from different mass transfer mechanisms in dependence of the shell parameters. The simulations demonstrate that a reduction of plate height in packings of core-shell relative to fully porous particles arises mainly due to reduced trans-particle mass transfer resistance and transchannel eddy dispersion. Copyright © 2015 Elsevier B.V. All rights reserved.

Synthesis of SiO2-Coated Core-Shell ZnO Composites for Preparing High-Voltage Varistors

NASA Astrophysics Data System (ADS)

Qu, Xiao; Yao, Da-Chuan; Liu, Jin-Ran; Wang, Mao-Hua; Zhang, Han-Ping

2018-01-01

Monodispersed ZnO composite microspheres were successfully prepared by a facile ultrasound irradiation method. Then, the uniform core-shell structured composites were synthesized through the hydrolysis of tetraethyl orthosilicate on the surface of the ZnO composite microspheres. Microstructural studies of the as-obtained powders were carried out using the techniques of the x-ray powder diffraction, field emission scanning electron microscopy and transmission electron microscopy with energy dispersive x-ray spectroscopy. The results show that the pink ZnO composite powders as the core were spherical structures with the size of approximately 100 nm, and the SiO2 shell was fully coated on the surface of the core. On the basis of these results, the effect of SiO2 content on the thickness of the synthesized composites and microstructure, as well as the electrical properties of the ZnO varistors sintered in air at 1150°C for 2 h, were fully studied. In particular, the ZnO varistor prepared with the appropriate amount of the SiO2 coating (˜40 nm) leads to a superior electrical performance with the high breakdown voltage of 418 V mm-1 and an excellent nonlinear coefficient of 70.7, compared with the varistors obtained without the SiO2 coating. The high performance is attributed to the smaller and more homogeneous ZnO grains obtained via the SiO2 coating.

Association between Refractive Errors and Ocular Biometry in Iranian Adults

PubMed Central

Hashemi, Hassan; Khabazkhoob, Mehdi; Emamian, Mohammad Hassan; Shariati, Mohammad; Miraftab, Mohammad; Yekta, Abbasali; Ostadimoghaddam, Hadi; Fotouhi, Akbar

2015-01-01

Purpose: To investigate the association between ocular biometrics such as axial length (AL), anterior chamber depth (ACD), lens thickness (LT), vitreous chamber depth (VCD) and corneal power (CP) with different refractive errors. Methods: In a cross-sectional study on the 40 to 64-year-old population of Shahroud, random cluster sampling was performed. Ocular biometrics were measured using the Allegro Biograph (WaveLight AG, Erlangen, Germany) for all participants. Refractive errors were determined using cycloplegic refraction. Results: In the first model, the strongest correlations were found between spherical equivalent with axial length and corneal power. Spherical equivalent was strongly correlated with axial length in high myopic and high hyperopic cases, and with corneal power in high hyperopic cases; 69.5% of variability in spherical equivalent was attributed to changes in these variables. In the second model, the correlations between vitreous chamber depth and corneal power with spherical equivalent were stronger in myopes than hyperopes, while the correlations between lens thickness and anterior chamber depth with spherical equivalent were stronger in hyperopic cases than myopic ones. In the third model, anterior chamber depth + lens thickness correlated with spherical equivalent only in moderate and severe cases of hyperopia, and this index was not correlated with spherical equivalent in moderate to severe myopia. Conclusion: In individuals aged 40-64 years, corneal power and axial length make the greatest contribution to spherical equivalent in high hyperopia and high myopia. Anterior segment biometric components have a more important role in hyperopia than myopia. PMID:26730304

Zonal Flow Velocimetry in Spherical Couette Flow using Acoustic Modes

NASA Astrophysics Data System (ADS)

Adams, Matthew M.; Mautino, Anthony R.; Stone, Douglas R.; Triana, Santiago A.; Lekic, Vedran; Lathrop, Daniel P.

2015-11-01

We present studies of spherical Couette flows using the technique of acoustic mode Doppler velocimetry. This technique uses rotational splittings of acoustic modes to infer the azimuthal velocity profile of a rotating flow, and is of special interest in experiments where direct flow visualization is impractical. The primary experimental system consists of a 60 cm diameter outer spherical shell concentric with a 20 cm diameter sphere, with air or nitrogen gas serving as the working fluid. The geometry of the system approximates that of the Earth's core, making these studies geophysically relevant. A turbulent shear flow is established in the system by rotating the inner sphere and outer shell at different rates. Acoustic modes of the fluid volume are excited using a speaker and measured via microphones, allowingdetermination of rotational splittings. Preliminary results comparing observed splittings with those predicted by theory are presented. While the majority of these studies were performed in the 60 cm diameter device using nitrogen gas, some work has also been done looking at acoustic modes in the 3 m diameter liquid sodium spherical Couette experiment. Prospects for measuring zonal velocity profiles in a wide variety of experiments are discussed.

A comparison of the fragmentation thresholds and inertial cavitation doses of different ultrasound contrast agents

NASA Astrophysics Data System (ADS)

Chen, Wen-Shiang; Matula, Thomas J.; Brayman, Andrew A.; Crum, Lawrence A.

2003-01-01

Contrast bubble destruction is important in several new diagnostic and therapeutic applications. The pressure threshold of destruction is determined by the shell material, while the propensity for of the bubbles to undergo inertial cavitation (IC) depends both on the gas and shell properties of the ultrasound contrast agent (UCA). The ultrasonic fragmentation thresholds of three specific UCAs (Optison, Sonazoid, and biSpheres), each with different shell and gas properties, were determined under various acoustic conditions. The acoustic emissions generated by the agents, or their derivatives, characteristic of IC after fragmentation, was also compared, using cumulated broadband-noise emissions (IC ``dose''). Albumin-shelled Optison and surfactant-shelled Sonazoid had low fragmentation thresholds (mean=0.13 and 0.15 MPa at 1.1 MHz, 0.48 and 0.58 MPa at 3.5 MHz, respectively), while polymer-shelled biSpheres had a significant higher threshold (mean=0.19 and 0.23 MPa at 1.1 MHz, 0.73 and 0.96 MPa for thin- and thick-shell biSpheres at 3.5 MHz, respectively, p<0.01). At comparable initial concentrations, surfactant-shelled Sonazoid produced a much larger IC dose after shell destruction than did either biSpheres or Optison (p<0.01). Thick-shelled biSpheres had the highest fragmentation threshold and produced the lowest IC dose. More than two and five acoustic cycles, respectively, were necessary for the thin- and thick-shell biSpheres to reach a steady-state fragmentation threshold.

Keeping Enceladus Warm

NASA Astrophysics Data System (ADS)

Travis, B. J.; Schubert, G.

2012-12-01

Despite its small size, Enceladus emits considerable heat, especially at its south pole, even long after simple thermal models predict it should be frozen. A number of energy mechanisms have been proposed as responsible for this heating, such as TDH (tidal dissipative heating), and convection and shearing in the ice shell, but why energy outflow is primarily at the south pole is still debated. It is not known if TDH has operated continuously at Enceladus. Crater relaxation simulations suggest considerable heat flow has occurred over long stretches of its history. One process missing from previous models is fluid flow, both in an ocean layer and in the silicate core. The simulations described here are part of a study to estimate the impact of hydrothermal flow and to explore under what conditions, and for how long, an ocean layer could persist on Enceladus, with or without TDH. Our model geometry is 2-D spherical (radius and latitude) for most simulations, with one 3-D spherical simulation. We assume a silicate core of about 160 km radius, overlain by an H2O layer out to 250 km radius. Ice shell thickness is initially 15 km. Flow in an ocean layer is represented by a simplified Navier-Stokes model, and porous flow occurs in the core. Surface temperature distribution follows observed values. Radiogenic heating produces about 0.3 GW in the model. A simple TDH model is active in some simulations. Salts and/or NH3 may be present in the interior of Enceladus, and would strongly depress freezing; our model uses a low eutectic salt as an analog. The ice shell's thickness is not required to remain fixed, but can change dynamically, in response to local thermodynamics. Initial core temperature and permeability are unknowns. Initial core temperature is varied over several hundred oC, and permeability is varied over 1-100 millidarcies. In our simulations, typically, a flow field develops characterized by sinking flow at the equator and rising plumes at the poles. A broad thickening of ice in the equatorial region occurs, so much so that flow is gradually restricted to the polar regions, with the south pole flow stronger than at the northern pole. A feedback develops; cooler, sinking flow at the equator results in thickening of the ice there which in turn tends to isolate flow to the deeper ocean plus core region at the poles. The rate at which this pattern develops depends on the presence or absence of TDH. Except at the surface, a nearly cylindrical region from north to south through the model remains fluid. The presence of salt and/or NH3 allows liquid conditions and flow even as the ocean temperature falls well below 0 oC. At higher initial core temperatures, boiling occurs deep in the core because of the low overburden pressure. An approximately 70 km thick difference in ice thickness can develop between equator and poles. However, due to the low gravity of Enceladus, this would give rise to a buoyant pressure difference of only about 5 bars, which is less than shear strength measurements in ice. The core slowly cools, and eventually the ocean may freeze completely without TDH, but that can take on the order of several hundred million years or more. If episodes of strong TDH occurred on that time scale or shorter, a polar ocean might then persist indefinitely.

Ariel 6 measurements of ultra-heavy cosmic ray fluxes in the region 34 or = Z or = 48

NASA Technical Reports Server (NTRS)

Fowler, P. H.; Masheder, M. R. W.; Moses, R. T.; Walker, R. N. F.; Worley, A.; Gay, A. M.

1985-01-01

The Ariel VI satellite was launched by NASA on a Scout rocket on 3rd June 1979 from Wallops Island, Virginia, USA, into a near circular 625 km orbit inclined at 55 deg. It carried a spherical cosmic ray detector designed by a group from Bristol University. A spherical aluminum vessel of diameter 75 cm contains a gas scintillation mixture and a thin spherical shell of Pilot 425 plastic, and forms a single optical cavity viewed by 16 photomultipliers. Particle tracks through the detector may be characterized by their impact parameter p and by whether or not they pass through the cup of plastic scintillator placed between the sphere and the spacecraft body (referred to below as the Anti-Coincidence Detector or ACD). Individual particle charges are determined by separately measuring the gas scintillation and the Cerenkov emission from the plastic shell. This is possible because of the quite different distribution in time of these emissions.

Study on River Snail Shells Unearthed from Laoniupo Shang Dynasty Site.

PubMed

Zhang, Rui; Yue, Lianjian; Yang, Junchang

2016-03-01

The samples of river snail shell pieces, unearthed from Laoniupo Shang dynasty site, were observed and characterized by SEM, Raman and IR to obtain the information about their chemical component and crystal structure. The uneven surface of the cuticle was covered with nanoparticles, which formed rough surface of the shells. The surface of pearl layer was combined with nano-sized flakes and kept smooth on the whole. The insection of shell was composed of three layers: the cuticle (100-120 μm in thickness), the prismatic layer (-130-140 μm in thickness), and the thickest pearl layer (280-300 μm in thickness). All layers had the component of calcium carbonate with aragonite structure and they were different in nanostructures because of different biomineralization processes.

Sheet-like assemblies of spherical particles with point-symmetrical patches.

PubMed

Mani, Ethayaraja; Sanz, Eduardo; Roy, Soumyajit; Dijkstra, Marjolein; Groenewold, Jan; Kegel, Willem K

2012-04-14

We report a computational study on the spontaneous self-assembly of spherical particles into two-dimensional crystals. The experimental observation of such structures stabilized by spherical objects appeared paradoxical so far. We implement patchy interactions with the patches point-symmetrically (icosahedral and cubic) arranged on the surface of the particle. In these conditions, preference for self-assembly into sheet-like structures is observed. We explain our findings in terms of the inherent symmetry of the patches and the competition between binding energy and vibrational entropy. The simulation results explain why hollow spherical shells observed in some Keplerate-type polyoxometalates (POM) appear. Our results also provide an explanation for the experimentally observed layer-by-layer growth of apoferritin--a quasi-spherical protein.

Nano-structured silica coated mesoporous carbon micro-granules for potential application in water filtration

NASA Astrophysics Data System (ADS)

Das, Avik; Sen, D.; Mazumder, S.; Ghosh, A. K.

2017-05-01

A novel nano-composite spherical micro-granule has been synthesized using a facile technique of solvent evaporation induced assembly of nanoparticles for potential application in water filtration. The spherical micro-granule is comprised of nano-structured shell of hydrophilic silica encapsulating a hydrophobic mesoporous carbon at the core. Hierarchical structure of such core-shell micro-granules has been rigorously characterized using small-angle neutron and X-ray scattering techniques and complemented with scanning electron microscopy. The hydrophilic silica envelope around the carbon core helps in incorporation of such granules into the hydrophilic polymeric ultra-filtration membrane. The interstitial micro-pores present in the silica shell can serve as water transport channels and the mesoporus carbon core enhances the separation performance due its well adsorption characteristics. It has been found that the incorporation of such granules inside the ultra-filtration membrane indeed enhances the water permeability as well as the separation performance in a significant way.

Investigation on the effects of temperature dependency of material parameters on a thermoelastic loading problem

NASA Astrophysics Data System (ADS)

Kumar, Anil; Mukhopadhyay, Santwana

2017-08-01

The present work is concerned with the investigation of thermoelastic interactions inside a spherical shell with temperature-dependent material parameters. We employ the heat conduction model with a single delay term. The problem is studied by considering three different kinds of time-dependent temperature and stress distributions applied at the inner and outer surfaces of the shell. The problem is formulated by considering that the thermal properties vary as linear function of temperature that yield nonlinear governing equations. The problem is solved by applying Kirchhoff transformation along with integral transform technique. The numerical results of the field variables are shown in the different graphs to study the influence of temperature-dependent thermal parameters in various cases. It has been shown that the temperature-dependent effect is more prominent in case of stress distribution as compared to other fields and also the effect is significant in case of thermal shock applied at the two boundary surfaces of the spherical shell.

Structural investigation of spherical hollow excipient Mannit Q by X-ray microtomography.

PubMed

Kajihara, Ryusuke; Noguchi, Shuji; Iwao, Yasunori; Yasuda, Yuki; Segawa, Megumi; Itai, Shigeru

2015-11-10

The structure of Mannit Q particles, an excipient made by spray-drying a d-mannitol solution, and Mannit Q tablets were investigated by synchrotron X-ray microtomography. The Mannit Q particles had a spherical shape with a hollow core. The shells of the particles consisted of fine needle-shaped crystals, and columnar crystals were present in the hollows. These structural features suggested the following formation mechanism for the hollow particles:during the spray-drying process, the solvent rapidly evaporated from the droplet surface, resulting in the formation of shells made of fine needle-shaped crystals.Solvent remaining inside the shells then evaporated slowly and larger columnar crystals grew as the hollows formed. Although most of the Mannit Q particles were crushed on tableting, some of the particles retained their hollow structures, probably because the columnar crystals inside the hollows functioned as props. This demonstrated that the tablets with porous void spaces may be readily manufactured using Mannit Q. Copyright © 2015 Elsevier B.V. All rights reserved.

Eco-friendly synthesis of core-shell structured (TiO2/Li2CO3) nanomaterials for low cost dye-sensitized solar cells.

PubMed

Karuppuchamy, S; Brundha, C

2016-12-01

Core-shell structured TiO 2 /Li 2 CO 3 electrode was successfully synthesized by eco-friendly solution growth technique. TiO 2 /Li 2 CO 3 electrodes were characterized using X-ray Diffractometer (XRD), Scanning electron microscopy (SEM) and photocurrent-voltage measurements. The synthesized core-shell electrode material was sensitized with tetrabutylammonium cis-di(thiocyanato)-N,N'-bis(4-carboxylato-4'-carboxylic acid-2,2'-bipyridine)ruthenate(II) (N-719). The performance of dye-sensitized solar cells (DSCs) based on N719 dye modified TiO 2 /Li 2 CO 3 electrodes was investigated. The effect of various shell thickness on the photovoltaic performance of the core-shell structured electrode is also investigated. We found that Li 2 CO 3 shells of all thicknesses perform as inert barriers which improve open-circuit voltage (V oc ) of the DSCs. The energy conversion efficiency was greatly dependent on the thickness of Li 2 CO 3 on TiO 2 film, and the highest efficiency of 3.7% was achieved at the optimum Li 2 CO 3 shell layer. Copyright © 2015 Elsevier Inc. All rights reserved.

Coulomb excitations for a short linear chain of metallic shells

DOE Office of Scientific and Technical Information (OSTI.GOV)

Zhemchuzhna, Liubov, E-mail: lzhemchuzhna@unm.edu; Center for High Technology Materials, University of New Mexico, Albuquerque, New Mexico 87106; Gumbs, Godfrey

2015-03-15

A self-consistent-field theory is given for the electronic collective modes of a chain containing a finite number, N, of Coulomb-coupled spherical two-dimensional electron gases arranged with their centers along a straight line, for simulating electromagnetic response of a narrow-ribbon of metallic shells. The separation between nearest-neighbor shells is arbitrary and because of the quantization of the electron energy levels due to their confinement to the spherical surface, all angular momenta L of the Coulomb excitations, as well as their projections M on the quantization axis, are coupled. However, for incoming light with a given polarization, only one angular momentum quantummore » number is usually required. Therefore, the electromagnetic response of the narrow-ribbon of metallic shells is expected to be controlled externally by selecting different polarizations for incident light. We show that, when N = 3, the next-nearest-neighbor Coulomb coupling is larger than its value if they are located at opposite ends of a right-angle triangle forming the triad. Additionally, the frequencies of the plasma excitations are found to depend on the orientation of the line joining them with respect to the axis of quantization since the magnetic field generated from the induced oscillating electric dipole moment on one sphere can couple to the induced magnetic dipole moment on another. Although the transverse inter-shell electromagnetic coupling can be modeled by an effective dynamic medium, the longitudinal inter-shell Coulomb coupling, on the other hand, can still significantly modify the electromagnetic property of this effective medium between shells.« less

Analytical and experimental studies of natural vibrations modes of ring-stiffened truncated-cone shells with variable theoretical ring fixity

NASA Technical Reports Server (NTRS)

Naumann, E. C.; Catherines, D. S.; Walton, W. C., Jr.

1971-01-01

Experimental and analytical investigations of the vibratory behavior of ring-stiffened truncated-cone shells are described. Vibration tests were conducted on 60 deg conical shells having up to four ring stiffeners and for free-free and clamped-free edge constraints and 9 deg conical shells, for two thicknesses, each with two angle rings and for free-free, free-clamped, and clamped-clamped edge constraints. The analytical method is based on linear thin shell theory, employing the Rayleigh-Ritz method. Discrete rings are represented as composed of one or more segments, each of which is a short truncated-cone shell of uniform thickness. Equations of constraint are used to join a ring and shell along a circumferential line connection. Excellent agreement was obtained for comparisons of experimental and calculated frequencies.

Sound Transmission through a Cylindrical Sandwich Shell with Honeycomb Core

NASA Technical Reports Server (NTRS)

Tang, Yvette Y.; Robinson, Jay H.; Silcox, Richard J.

1996-01-01

Sound transmission through an infinite cylindrical sandwich shell is studied in the context of the transmission of airborne sound into aircraft interiors. The cylindrical shell is immersed in fluid media and excited by an oblique incident plane sound wave. The internal and external fluids are different and there is uniform airflow in the external fluid medium. An explicit expression of transmission loss is derived in terms of modal impedance of the fluids and the shell. The results show the effects of (a) the incident angles of the plane wave; (b) the flight conditions of Mach number and altitude of the aircraft; (c) the ratios between the core thickness and the total thickness of the shell; and (d) the structural loss factors on the transmission loss. Comparisons of the transmission loss are made among different shell constructions and different shell theories.

Benchmark solution of the dynamic response of a spherical shell at finite strain

DOE Office of Scientific and Technical Information (OSTI.GOV)

Versino, Daniele; Brock, Jerry S.

2016-09-28

Our paper describes the development of high fidelity solutions for the study of homogeneous (elastic and inelastic) spherical shells subject to dynamic loading and undergoing finite deformations. The goal of the activity is to provide high accuracy results that can be used as benchmark solutions for the verification of computational physics codes. Furthermore, the equilibrium equations for the geometrically non-linear problem are solved through mode expansion of the displacement field and the boundary conditions are enforced in a strong form. Time integration is performed through high-order implicit Runge–Kutta schemes. Finally, we evaluate accuracy and convergence of the proposed method bymore » means of numerical examples with finite deformations and material non-linearities and inelasticity.« less

Mirror mount

DOEpatents

Humpal, H.H.

1987-11-10

A mirror mount is provided that allows free pitch, yaw and roll motion of the mirror while keeping the location of a point on the surface of the mirror fixed in the rest frame of reference of the mount. Yaw movement is provided by two yaw cylinders that are bearing mounted to provide rotation. Pitch and roll motion is provided by a spherically annular shell that is air bearing mounted to move between a clamp and an upper pedestal bearing. The centers of curvature of the spherical surfaces of the shell lie upon the point. Pitch motion and roll motion are separately and independently imparted to mirror by a pair of pitch paddles and a pair of roll paddles that are independently and separately moved by control rods driven by motors. 5 figs.

Mirror mount

DOEpatents

Humpal, H.H.

1986-03-21

A mirror mount is provided that allows free pitch, yaw and roll motion of the mirror while keeping the location of a point on the surface of the mirror fixed in the rest frame of reference of the mount. Yaw movement is provided by two yaw cylinders that are bearing mounted to provide rotation. Pitch and roll motion is provided by a spherically annular shell that is air bearing mounted to move between a clamp and an upper pedestal bearing. The centers of curvature of the spherical surfaces of the shell lie upon the point. Pitch motion and roll motion are separately and independently imparted to mirror by a pair of pitch paddles and a pair of roll paddles that are independently and separately moved by control rods driven by motors.

Abnormal elastic modulus behavior in a crystalline-amorphous core-shell nanowire system.

PubMed

Lee, Jeong Hwan; Choi, Su Ji; Kwon, Ji Hwan; Van Lam, Do; Lee, Seung Mo; Kim, An Soon; Baik, Hion Suck; Ahn, Sang Jung; Hong, Seong Gu; Yun, Yong Ju; Kim, Young Heon

2018-06-13

We investigated the elastic modulus behavior of crystalline InAs/amorphous Al2O3 core-shell heterostructured nanowires with shell thicknesses varying between 10 and 90 nm by conducting in situ tensile tests inside a transmission electron microscope (TEM). Counterintuitively, the elastic modulus behaviors of InAs/Al2O3 core-shell nanowires differ greatly from those of bulk-scale composite materials, free from size effects. According to our results, the elastic modulus of InAs/Al2O3 core-shell nanowires increases, peaking at a shell thickness of 40 nm, and then decreases in the range of 50-90 nm. This abnormal behavior is attributed to the continuous decrease in the elastic modulus of the Al2O3 shell as the thickness increases, which is caused by changes in the atomic/electronic structure during the atomic layer deposition process and the relaxation of residual stress/strain in the shell transferred from the interfacial mismatch between the core and shell materials. A novel method for estimating the elastic modulus of the shell in a heterostructured core-shell system was suggested by considering these two effects, and the predictions from the suggested method coincided well with the experimental results. We also found that the former and latter effects account for 89% and 11% of the change in the elastic modulus of the shell. This study provides new insight by showing that the size dependency, which is caused by the inhomogeneity of the atomic/electronic structure and the residual stress/strain, must be considered to evaluate the mechanical properties of heterostructured nanowires.

Effect of core-shell structure on optical properties of Au-Cu2O nanoparticles

NASA Astrophysics Data System (ADS)

Sai, Cong Doanh; Ngac, An Bang

2018-03-01

Solid Au-Cu2O core-shell nanoparticles were synthesized using gold nanoparticles of 16.6 nm in size as the core. The core-shell structure of the synthesized particles was confirmed and characterized by TEM and HRTEM images. Due to their similar crystal structure, the (111) planes of Cu2O are nucleated and grown epitaxially on the {111} facets of Au nanoparticles with the lattice mismatch of about 4.3% resulting in a polycrystallized Cu2O shell covering the Au nanocore. Due to the quantum confinement effect, the band gap energy Eg of the synthesized Cu2O shells is blue-shifted from 2.35 to 2.70 eV as the shell thickness decreases from of 24.6±3.6 to 9.0±1.7 nm. The localized SPR (Surface Plasmon Resonance) peak of the Au nanocore undergoes a large red shift of the order of a hundred of nm due to both the high refractive index and the increase of the thickness of Cu2O shell. Theoretical models within the Drude framework significantly underestimate the experimental data and predict a wrong rate of change of the SPR peak position with respect to the shell thickness.

Stereoscopic Analysis of Silicone Breast Implant Shells Damaged by Surgical Instruments.

PubMed

Rapp, Derek A; Neaman, Keith C; Hammond, Dennis C

2015-07-01

Iatrogenic shell injury during the implantation and explantation of silicone gel breast implants may lead to eventual device failure. Identification of the patterns of injury caused by surgical instruments is important when attempting to characterize the cause of shell rupture. Understanding the true causes of device failure may help with its prevention. The purpose of this study was to microscopically characterize patterns of shell injury induced by various surgical instruments. Textured and smooth silicone gel implants were intentionally damaged with a variety of surgical instruments. Various scalpels and surgical scissors ranging in fineness were used to create full-thickness injuries in the implant shell. Optical microscopy and scanning electron microscopy were then used to image the injured area to determine patterns of injury. Full-thickness striations across the thickness of the shell could be seen with damage caused by scissors. The density of these striations correlated directly with the fineness of scissors used. No striations were seen with injuries caused by scalpels. Striations were only observed in injuries caused by scissors and suture needles. Striation density correlated with the coarseness of the cutting edge. No such striations were seen in shells damaged by a scalpel even when the angle of approach was changed. This difference can be of assistance in distinguishing between scissors versus scalpel injury of an implant shell.

Free form hemispherical shaped charge

DOEpatents

Haselman, L.C. Jr.

1996-06-04

A hemispherical shaped charge has been modified such that one side of the hemisphere is spherical and the other is aspherical allowing a wall thickness variation in the liner. A further modification is to use an elongated hemispherical shape. The liner has a thick wall at its pole and a thin wall at the equator with a continually decreasing wall thickness from the pole to the equator. The ratio of the wall thickness from the pole to the equator varies depending on liner material and HE shape. Hemispherical shaped charges have previously been limited to spherical shapes with no variations in wall thicknesses. By redesign of the basic liner thicknesses, the jet properties of coherence, stability, and mass distribution have been significantly improved. 8 figs.

Free form hemispherical shaped charge

DOEpatents

Haselman, Jr., Leonard C.

1996-01-01

A hemispherical shaped charge has been modified such that one side of the hemisphere is spherical and the other is aspherical allowing a wall thickness variation in the liner. A further modification is to use an elongated hemispherical shape. The liner has a thick wall at its pole and a thin wall at the equator with a continually decreasing wall thickness from the pole to the equator. The ratio of the wall thickness from the pole to the equator varies depending on liner material and HE shape. Hemispherical shaped charges have previously been limited to spherical shapes with no variations in wall thicknesses. By redesign of the basic liner thicknesses, the jet properties of coherence, stability, and mass distribution have been significantly improved.

Experimental validation of a coupled neutron-photon inverse radiation transport solver

NASA Astrophysics Data System (ADS)

Mattingly, John; Mitchell, Dean J.; Harding, Lee T.

2011-10-01

Sandia National Laboratories has developed an inverse radiation transport solver that applies nonlinear regression to coupled neutron-photon deterministic transport models. The inverse solver uses nonlinear regression to fit a radiation transport model to gamma spectrometry and neutron multiplicity counting measurements. The subject of this paper is the experimental validation of that solver. This paper describes a series of experiments conducted with a 4.5 kg sphere of α-phase, weapons-grade plutonium. The source was measured bare and reflected by high-density polyethylene (HDPE) spherical shells with total thicknesses between 1.27 and 15.24 cm. Neutron and photon emissions from the source were measured using three instruments: a gross neutron counter, a portable neutron multiplicity counter, and a high-resolution gamma spectrometer. These measurements were used as input to the inverse radiation transport solver to evaluate the solver's ability to correctly infer the configuration of the source from its measured radiation signatures.

Dark energy, antimatter gravity and geometry of the Universe

NASA Astrophysics Data System (ADS)

Hajdukovic, Dragan Slavkov

2010-11-01

This article is based on two hypotheses. The first one is the existence of the gravitational repulsion between particles and antiparticles. Consequently, virtual particle-antiparticle pairs in the quantum vacuum might be considered as gravitational dipoles. The second hypothesis is that the Universe has geometry of a four-dimensional hyper-spherical shell with thickness equal to the Compton wavelength of a pion, which is a simple generalization of the usual geometry of a 3-hypersphere. It is striking that these two hypotheses lead to a simple relation for the gravitational mass density of the vacuum, which is in very good agreement with the observed dark energy density. It might be a sign that QCD fields provide the largest contribution to the gravitational mass of the physical vacuum; contrary to the prediction of the Standard Model that QCD contribution is much smaller than some other contributions.

Changes in the selection differential exerted on a marine snail during the ontogeny of a predatory shore crab.

PubMed

Pakes, D; Boulding, E G

2010-08-01

Empirical estimates of selection gradients caused by predators are common, yet no one has quantified how these estimates vary with predator ontogeny. We used logistic regression to investigate how selection on gastropod shell thickness changed with predator size. Only small and medium purple shore crabs (Hemigrapsus nudus) exerted a linear selection gradient for increased shell-thickness within a single population of the intertidal snail (Littorina subrotundata). The shape of the fitness function for shell thickness was confirmed to be linear for small and medium crabs but was humped for large male crabs, suggesting no directional selection. A second experiment using two prey species to amplify shell thickness differences established that the selection differential on adult snails decreased linearly as crab size increased. We observed differences in size distribution and sex ratios among three natural shore crab populations that may cause spatial and temporal variation in predator-mediated selection on local snail populations.

Broadband absorption and enhanced photothermal conversion property of octopod-like Ag@Ag2S core@shell structures with gradually varying shell thickness.

PubMed

Jiang, Qian; Zeng, Wenxia; Zhang, Canying; Meng, Zhaoguo; Wu, Jiawei; Zhu, Qunzhi; Wu, Daxiong; Zhu, Haitao

2017-12-19

Photothermal conversion materials have promising applications in many fields and therefore they have attracted tremendous attention. However, the multi-functionalization of a single nanostructure to meet the requirements of multiple photothermal applications is still a challenge. The difficulty is that most nanostructures have specific absoprtion band and are not flexible to different demands. In the current work, we reported the synthesis and multi-band photothermal conversion of Ag@Ag 2 S core@shell structures with gradually varying shell thickness. We synthesized the core@shell structures through the sulfidation of Ag nanocubes by taking the advantage of their spatially different reactivity. The resulting core@shell structures show an octopod-like mopgorlogy with a Ag 2 S bulge sitting at each corner of the Ag nanocubes. The thickness of the Ag 2 S shell gradually increases from the central surface towards the corners of the structure. The synthesized core@shell structures show a broad band absorption spectrum from 300 to 1100 nm. Enhanced photothermal conversion effect is observed under the illuminations of 635, 808, and 1064 nm lasers. The results indicate that the octopod-like Ag@Ag 2 S core@shell structures have characteristics of multi-band photothermal conversion. The current work might provide a guidance for the design and synthesis of multifunctional photothermal conversion materials.

Calculation of the Transition Matrix for the Scattering of Acoustic Waves from a Thin Elastic Spherical Shell Using the ATILA Finite Element Code

DTIC Science & Technology

1994-03-01

products of radial Hankel functions and spherical harmonics. The chosen driving frequency was 474 Hz, corresponding to a value of ka 1, where k is the...spherical harmonics. The chosen driving frequency was 474 Hz, corresponding to a value of ka = 1, where k is the wavenumber of sound in water and a is...wife Adriana for her support, understanding, and for her help in typing this thesis. vi I. INTRODUCTION The utilization of sonar systems in

Strongly localized image states of spherical graphitic particles.

PubMed

Gumbs, Godfrey; Balassis, Antonios; Iurov, Andrii; Fekete, Paula

2014-01-01

We investigate the localization of charged particles by the image potential of spherical shells, such as fullerene buckyballs. These spherical image states exist within surface potentials formed by the competition between the attractive image potential and the repulsive centripetal force arising from the angular motion. The image potential has a power law rather than a logarithmic behavior. This leads to fundamental differences in the nature of the effective potential for the two geometries. Our calculations have shown that the captured charge is more strongly localized closest to the surface for fullerenes than for cylindrical nanotube.

Solvothermal Synthesis of a Hollow Micro-Sphere LiFePO4/C Composite with a Porous Interior Structure as a Cathode Material for Lithium Ion Batteries

PubMed Central

Liu, Yang; Zhang, Jieyu; Li, Ying; Hu, Yemin; Li, Wenxian; Zhu, Mingyuan; Hu, Pengfei; Chou, Shulei; Wang, Guoxiu

2017-01-01

To overcome the low lithium ion diffusion and slow electron transfer, a hollow micro sphere LiFePO4/C cathode material with a porous interior structure was synthesized via a solvothermal method by using ethylene glycol (EG) as the solvent medium and cetyltrimethylammonium bromide (CTAB) as the surfactant. In this strategy, the EG solvent inhibits the growth of the crystals and the CTAB surfactant boots the self-assembly of the primary nanoparticles to form hollow spheres. The resultant carbon-coat LiFePO4/C hollow micro-spheres have a ~300 nm thick shell/wall consisting of aggregated nanoparticles and a porous interior. When used as materials for lithium-ion batteries, the hollow micro spherical LiFePO4/C composite exhibits superior discharge capacity (163 mAh g−1 at 0.1 C), good high-rate discharge capacity (118 mAh g−1 at 10 C), and fine cycling stability (99.2% after 200 cycles at 0.1 C). The good electrochemical performances are attributed to a high rate of ionic/electronic conduction and the high structural stability arising from the nanosized primary particles and the micro-sized hollow spherical structure. PMID:29099814

Expanding relativistic shells and gamma-ray burst temporal structure

DOE Office of Scientific and Technical Information (OSTI.GOV)

Fenimore, E.E.; Madras, C.D.; Nayakshin, S.

1996-12-01

Many models of gamma-ray bursts (GRBs) involve a shell expanding at extreme relativistic speeds. The shell of material expands in a photon-quiet phase for a period {ital t}{sub 0} and then becomes gamma-ray active, perhaps due to inhomogeneities in the interstellar medium or the generation of shocks. Based on kinematics, we relate the envelope of the emission of the event to the characteristics of the photon-quiet and photon-active phases. We initially assume local spherical symmetry wherein, on average, the same conditions prevail over the shell`s surface within angles the order of {Gamma}{sup {minus}1}, where {Gamma} is the Lorentz factor formore » the bulk motion. The contribution of the curvature to the temporal structure is comparable to the contribution from the overall expansion. As a result, GRB time histories from a shell should have an envelope similar to {open_quotes}FRED{close_quotes} (fast rise, exponential decay) events in which the rise time is related to the duration of the photon-active phase and the fall time is related to the duration of the photon-quiet phase. This result depends only on local spherical symmetry and, since most GRBs do not have such envelopes, we introduce the {open_quotes}shell symmetry{close_quotes} problem: the observed time history envelopes of most GRBs do not agree with that expected for a relativistic expanding shell. Although FREDs have the signature of a relativistic shell, they may not be due to a single shell, as required by some cosmological models. Some FREDs have precursors in which the peaks are separated by more than the expansion time required to explain FRED shape. Such a burst is most likely explained by a central engine; that is, the separation of the multiple peaks occurs because the central site produced multiple releases of energy on timescales comparable to the duration of the event. (Abstract Truncated)« less

Design and Synthesis of Spherical Multicomponent Aggregates Composed of Core-Shell, Yolk-Shell, and Hollow Nanospheres and Their Lithium-Ion Storage Performances.

PubMed

Park, Gi Dae; Kang, Yun Chan

2018-03-01

Micrometer-sized spherical aggregates of Sn and Co components containing core-shell, yolk-shell, hollow nanospheres are synthesized by applying nanoscale Kirkendall diffusion in the large-scale spray drying process. The Sn 2 Co 3 -Co 3 SnC 0.7 -C composite microspheres uniformly dispersed with Sn 2 Co 3 -Co 3 SnC 0.7 mixed nanocrystals are formed by the first-step reduction of spray-dried precursor powders at 900 °C. The second-step oxidation process transforms the Sn 2 Co 3 -Co 3 SnC 0.7 -C composite into the porous microsphere composed of Sn-Sn 2 Co 3 @CoSnO 3 -Co 3 O 4 core-shell, Sn-Sn 2 Co 3 @CoSnO 3 -Co 3 O 4 yolk-shell, and CoSnO 3 -Co 3 O 4 hollow nanospheres at 300, 400, and 500 °C, respectively. The discharge capacity of the microspheres with Sn-Sn 2 Co 3 @CoSnO 3 -Co 3 O 4 core-shell, Sn-Sn 2 Co 3 @CoSnO 3 -Co 3 O 4 yolk-shell, and CoSnO 3 -Co 3 O 4 hollow nanospheres for the 200 th cycle at a current density of 1 A g -1 is 1265, 987, and 569 mA h g -1 , respectively. The ultrafine primary nanoparticles with a core-shell structure improve the structural stability of the porous-structured microspheres during repeated lithium insertion and desertion processes. The porous Sn-Sn 2 Co 3 @CoSnO 3 -Co 3 O 4 microspheres with core-shell primary nanoparticles show excellent cycling and rate performances as anode materials for lithium-ion batteries. © 2018 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

Cryogenic target formation using cold gas jets

DOEpatents

Hendricks, C.D.

1980-02-26

A method and apparatus using cold gas jets for producing a substantially uniform layer of cryogenic materials on the inner surface of hollow spherical members having one or more layers, such as inertially imploded targets are disclosed. By vaporizing and quickly refreezing cryogenic materials contained within a hollow spherical member, a uniform layer of the materials is formed on an inner surface of the spherical member. Basically the method involves directing cold gas jets onto a spherical member having one or more layers or shells and containing the cryogenic material, such as a deuterium-tritium (DT) mixture, to freeze the contained material, momentarily heating the spherical member so as to vaporize the contained material, and quickly refreezing the thus vaporized material forming a uniform layer of cryogenic material on an inner surface of the spherical member. 4 figs.

A Theoretical Investigation of Composite Overwrapped Pressure Vessel (COPV) Mechanics Applied to NASA Full Scale Tests

NASA Technical Reports Server (NTRS)

Greene, N.; Thesken, J. C.; Murthy, P. L. N.; Phoenix, S. L.; Palko, J.; Eldridge, J.; Sutter, J.; Saulsberry, R.; Beeson, H.

2006-01-01

A theoretical investigation of the factors controlling the stress rupture life of the National Aeronautics and Space Agency's (NASA) composite overwrapped pressure vessels (COPVs) continues. Kevlar(TradeMark) fiber overwrapped tanks are of particular concern due to their long usage and the poorly understood stress rupture process in Kevlar(TradeMark) filaments. Existing long term data show that the rupture process is a function of stress, temperature and time. However, due to the presence of a load sharing liner, the manufacturing induced residual stresses and the complex mechanical response, the state of actual fiber stress in flight hardware and test articles is not clearly known. This paper is a companion to the experimental investigation reported in [1] and develops a theoretical framework necessary to design full-scale pathfinder experiments and accurately interpret the experimentally observed deformation and failure mechanisms leading up to static burst in COPVs. The fundamental mechanical response of COPVs is described using linear elasticity and thin shell theory and discussed in comparison to existing experimental observations. These comparisons reveal discrepancies between physical data and the current analytical results and suggest that the vessel's residual stress state and the spatial stress distribution as a function of pressure may be completely different from predictions based upon existing linear elastic analyses. The 3D elasticity of transversely isotropic spherical shells demonstrates that an overly compliant transverse stiffness relative to membrane stiffness can account for some of this by shifting a thin shell problem well into the realm of thick shell response. The use of calibration procedures are demonstrated as calibrated thin shell model results and finite element results are shown to be in good agreement with the experimental results. The successes reported here have lead to continuing work with full scale testing of larger NASA COPV hardware.

A Radio-Polarisation and Rotation Measure Study of the Gum Nebula and Its Environment

NASA Astrophysics Data System (ADS)

Purcell, C. R.; Gaensler, B. M.; Sun, X. H.; Carretti, E.; Bernardi, G.; Haverkorn, M.; Kesteven, M. J.; Poppi, S.; Schnitzeler, D. H. F. M.; Staveley-Smith, L.

2015-05-01

The Gum Nebula is 36°-wide shell-like emission nebula at a distance of only ˜450 pc. It has been hypothesized to be an old supernova remnant, fossil H ii region, wind-blown bubble, or combination of multiple objects. Here we investigate the magneto-ionic properties of the nebula using data from recent surveys: radio-continuum data from the NRAO VLA and S-band Parkes All Sky Surveys, and H α data from the Southern H-Alpha Sky Survey Atlas. We model the upper part of the nebula as a spherical shell of ionized gas expanding into the ambient medium. We perform a maximum-likelihood Markov chain Monte Carlo fit to the NVSS rotation measure data, using the H α data to constrain average electron density in the shell ne. Assuming a latitudinal background gradient in rotation measure, we find {{n}e}=1.3-0.4+0.4 c{{m}-3}, angular radius {{φ }outer}=22\\buildrel{\\circ}\\over{.} 7-0.1+0.1, shell thickness dr=18.5-1.4+1.5 pc, ambient magnetic field strength {{B}0}=3.9-2.2+4.9 μ G, and warm gas filling factor f=0.3-0.1+0.3. We constrain the local, small-scale (˜260 pc) pitch-angle of the ordered Galactic magnetic field to +7{}^\\circ ≲ \\wp ≲ +44{}^\\circ , which represents a significant deviation from the median field orientation on kiloparsec scales (˜-7.°2). The moderate compression factor X=6.0-2.5+5.1 at the edge of the H α shell implies that the “old supernova remnant” origin is unlikely. Our results support a model of the nebula as a H ii region around a wind-blown bubble. Analysis of depolarization in 2.3 GHz S-PASS data is consistent with this hypothesis and our best-fitting values agree well with previous studies of interstellar bubbles.

Fabrication of Fe3O4@mSiO2 Core-Shell Composite Nanoparticles for Drug Delivery Applications

NASA Astrophysics Data System (ADS)

Uribe Madrid, Sergio I.; Pal, Umapada; Kang, Young Soo; Kim, Junghoon; Kwon, Hyungjin; Kim, Jungho

2015-05-01

We report the synthesis of Fe3O4@mSiO2 nanostructures of different meso-silica (mSiO2) shell thickness, their biocompatibility and behaviors for loading and release of a model drug ibuprofen. The composite nanostructures have superparamagnetic magnetite cores of 208 nm average size and meso-silica shells of 15 to 40 nm thickness. A modified Stöber method was used to grow the meso-silica shells over the hydrothermally grown monodispersed magnetite particles. The composite nanoparticles show very promising drug holding and releasing behaviors, which depend on the thickness of meso-silica shell. The biocompatibility of the meso-silica-coated and uncoated magnetite nanoparticles was tested through cytotoxicity assay on breast cancer (MCF-7), ovarian cancer (SKOV3), normal human lung fibroblasts MRC-5, and IMR-90 cells. The high drug holding capacity and reasonable biocompatibility of the nanostructures make them ideal agents for targeted drug delivery applications in human body.

The problems concerning the integration of very thin mirror shells

NASA Astrophysics Data System (ADS)

Basso, S.; Citterio, O.; Mazzoleni, F.; Pareschi, G.; Tagliaferri, G.; Valtolina, R.; Conconi, P.; Parodi, G.

2009-08-01

The necessity to reduce the mass and to increase the collecting area requires that the thickness of the optics becomes more and more thinner. Simbol-X was a typical example of this trend. Such thickness makes the shells floppy and therefore unable to maintain the correct shape. During the integration of the shells into the mechanical structure, only negligible deformation must be introduced. The low thickness means also that the shells must be glued on both sides to reach a good stiffness of the whole mirror module and this fact introduces a set of mounting problems. In INAF - Osservatorio Astronomico di Brera an integration process has been developed. The use of stiffening rings and of a temporary structure is the key to maintain the right shape of the shell. In this article the results of the integration of the first three prototypes of the Simbol-X optics are presented. The description of the process and the analysis of the degradation of the performances during the integration are shown in detail.

On the time-variable nature of Titan's obliquity

NASA Astrophysics Data System (ADS)

Noyelles, Benoit; Nimmo, Francis

2014-05-01

Titan presents an unexpectedly high obliquity (Stiles et al. 2008, Meriggiola & Iess 2012) while its topography and gravity suggest a non-hydrostatic ice shell (Hemingway et al. 2013). We here present a 6-dof model of the rotation of Titan simultaneously simulating the full orientation of the shell and the inner core, and considering a global subsurface ocean with a partially-compensated shell of spatially-variable thickness. Between 10 and 13% of our realistic interior models induce a resonance with the annual forcing, that dramatically raises the obliquity. The relevant model Titans are composed of a 130-140 km thick shell floating on a ~250 km thick ocean. The observed obliquity should not be considered as a mean one but as an instantaneous one, that should vary by ~7 arcmin over the duration of the Cassini mission.

Cloaks for suppression or enhancement of scattering of diffuse photon density waves

NASA Astrophysics Data System (ADS)

Renthlei, Lalruatfela; Ramakrishna, S. Anantha; Wanare, Harshawardhan

2018-07-01

Enhancement of wave-like characteristics of heavily damped diffuse photon density waves in a random medium by amplification can induce strongly localised resonances. These resonances can be used to either suppress or enhance scattering from an inhomogeneity in the random medium by cloaking the inhomogeneous region by a shell of random medium with the correct levels of absorption or amplification. A spherical core-shell structure consisting of a shell of a random amplifying medium is shown to enhance or suppress specific resonant modes. A shell with an absorbing random medium is also shown to suppress scattering which can also be used for cloaking the core region.

Gravastars in f (R ,T ) gravity

NASA Astrophysics Data System (ADS)

Das, Amit; Ghosh, Shounak; Guha, B. K.; Das, Swapan; Rahaman, Farook; Ray, Saibal

2017-06-01

We propose a unique stellar model under the f (R ,T ) gravity by using the conjecture of Mazur-Mottola [P. Mazur and E. Mottola, Report No. LA-UR-01-5067, P. Mazur and E. Mottola, Proc. Natl. Acad. Sci. USA 101, 9545 (2004), 10.1073/pnas.0402717101] which is known as gravastar and a viable alternative to the black hole as available in literature. This gravastar is described by the three different regions, viz., (I) Interior core region, (II) Intermediate thin shell, and (III) Exterior spherical region. The pressure within the interior region is equal to the constant negative matter density which provides a repulsive force over the thin spherical shell. This thin shell is assumed to be formed by a fluid of ultrarelativistic plasma and the pressure, which is directly proportional to the matter-energy density according to Zel'dovich's conjecture of stiff fluid [Y. B. Zel'dovich, Mon. Not. R. Astron. Soc. 160, 1 (1972), 10.1093/mnras/160.1.1P], does counterbalance the repulsive force exerted by the interior core region. The exterior spherical region is completely vacuum and assumed to be de Sitter spacetime which can be described by the Schwarzschild solution. Under this specification we find out a set of exact and singularity-free solution of the gravastar which presents several other physically valid features within the framework of alternative gravity.

The high surface energy of NiO {110} facets incorporated into TiO2 hollow microspheres by etching Ti plate for enhanced photocatalytic and photoelectrochemical activity

NASA Astrophysics Data System (ADS)

Li, Jian; Cui, Hongzhi; Song, Xiaojie; Wei, Na; Tian, Jian

2017-02-01

We present a rational design for the controllable synthesis of NiO/TiO2 hollow microspheres (NTHMs) with Ti plate via a one-pot template-free synthesis strategy. Specifically, to enhance the formation of hollow microspheres, part of the titanium source is provided by the Ti plate. The hollow spherical NiO/TiO2 particles possess unique microstructural characteristics, namely, a higher specific surface area (∼65.82 m2 g-1), a larger mesoporous structure (∼7.79 nm), and hierarchical nanoarchitectures connected with mesopores within the shell (monodispersed size of ∼1 μm and shell thickness of ∼80 nm). In addition, as a cocatalyst for improved catalytic activity, the incorporated NiO nanoparticles with exposed high surface energy {110} facets displayed an outstanding performance. It has been proven that this facile nanostructure possesses remarkably high photoelectrochemical and photocatalytic activities. The main mechanism for enhancement of photocatalytic activity is attributed to the construction of p-n junctions with an inner electric field between TiO2 and NiO, which can dramatically enhance the separation efficiency of the photogenerated electron-hole pairs. This strategy could be applied to fabricate mixed metal oxide hollow microspheres toward the photoelectrochemical catalysis.

Carbon-coated copper nanoparticles prepared by detonation method and their thermocatalysis on ammonium perchlorate

NASA Astrophysics Data System (ADS)

An, Chongwei; Ding, Penghui; Ye, Baoyun; Geng, Xiaoheng; Wang, Jingyu

2017-03-01

Carbon-coated copper nanoparticles (CCNPs) were prepared by initiating a high-density charge pressed with a mixture of microcrystalline wax, hexahydro-1,3,5-trinitro-1,3,5-triazine (RDX), and copper nitrate hydrate (Cu(NO3)2.3H2O) in an explosion vessel filled with nitrogen gas. The detonation products were characterized by transmission electron microcopy (TEM), high resolution transmission electron microcopy (HRTEM), energy dispersive X-ray spectroscopy (EDX), X-ray diffraction (XRD), and Raman spectroscopy. The effects of CCNPs on thermal decomposition of ammonium perchlorate (AP) were also investigated by differential scanning calorimeter (DSC). Results indicated that the detonation products were spherical, 25-40 nm in size, and had an apparent core-shell structure. In this structure, the carbon shell was 3-5 nm thick and mainly composed of graphite, C8 (a kind of carbyne), and amorphous carbon. When 5 wt.% CCNPs was mixed with 95 wt.% AP, the high-temperature decomposition peak of AP decreased by 95.97, 96.99, and 96.69 °Cat heating rates of 5, 10, and 20 °C/min, respectively. Moreover, CCNPs decreased the activation energy of AP as calculated through Kissinger's method by 25%, which indicated outstanding catalysis for the thermal decomposition of AP.

Process for manufacture of inertial confinement fusion targets and resulting product

DOEpatents

Masnari, Nino A.; Rensel, Walter B.; Robinson, Merrill G.; Solomon, David E.; Wise, Kensall D.; Wuttke, Gilbert H.

1982-01-01

An ICF target comprising a spherical pellet of fusion fuel surrounded by a concentric shell; and a process for manufacturing the same which includes the steps of forming hemispheric shells of a silicon or other substrate material, adhering the shell segments to each other with a fuel pellet contained concentrically therein, then separating the individual targets from the parent substrate. Formation of hemispheric cavities by deposition or coating of a mold substrate is also described. Coatings or membranes may also be applied to the interior of the hemispheric segments prior to joining.

Compositional analysis and structural elucidation of glycosaminoglycans in chicken eggs

PubMed Central

Liu, Zhangguo; Zhang, Fuming; Li, Lingyun; Li, Guoyun; He, Wenqing; Linhardt, Robert J.

2014-01-01

Glycosaminoglycans (GAGs) have numerous applications in the fields of pharmaceuticals, cosmetics, nutraceuticals, and foods. GAGs are also critically important in the developmental biology of all multicellular animals. GAGs were isolated from chicken egg components including yolk, thick egg white, thin egg white, membrane, calcified shell matrix supernatant, and shell matrix deposit. Disaccharide compositional analysis was performed using ultra high-performance liquid chromatography-mass spectrometry. The results of these analyses showed that all four families of GAGs were detected in all egg components. Keratan sulfate was found in egg whites (thick and thin) and shell matrix (calcified shell matrix supernatant and deposit) with high level. Chondroitin sulfates were much more plentiful in both shell matrix components and membrane. Hyaluronan was plentiful in both shell matrix components and membrane, but were only present in a trace of quantities in the yolk. Heparan sulfate was plentiful in the shell matrix deposit but was present in a trace of quantities in the egg content components (yolk, thick and thin egg whites). Most of the chondroitin and heparan sulfate disaccharides were present in the GAGs found in chicken eggs with the exception of chondroitin and heparan sulfate 2,6-disulfated disaccharides. Both CS and HS in the shell matrix deposit contained the most diverse chondroitin and heparan sulfate disaccharide compositions. Eggs might provide a potential new source of GAGs. PMID:25218438

Shell thickness-dependent microwave absorption of core-shell Fe3O4@C composites.

PubMed

Du, Yunchen; Liu, Wenwen; Qiang, Rong; Wang, Ying; Han, Xijiang; Ma, Jun; Xu, Ping

2014-08-13

Core-shell composites, Fe3O4@C, with 500 nm Fe3O4 microspheres as cores have been successfully prepared through in situ polymerization of phenolic resin on the Fe3O4 surface and subsequent high-temperature carbonization. The thickness of carbon shell, from 20 to 70 nm, can be well controlled by modulating the weight ratio of resorcinol and Fe3O4 microspheres. Carbothermic reduction has not been triggered at present conditions, thus the crystalline phase and magnetic property of Fe3O4 micropsheres can be well preserved during the carbonization process. Although carbon shells display amorphous nature, Raman spectra reveal that the presence of Fe3O4 micropsheres can promote their graphitization degree to a certain extent. Coating Fe3O4 microspheres with carbon shells will not only increase the complex permittivity but also improve characteristic impedance, leading to multiple relaxation processes in these composites, thus the microwave absorption properties of these composites are greatly enhanced. Very interestingly, a critical thickness of carbon shells leads to an unusual dielectric behavior of the core-shell structure, which endows these composites with strong reflection loss, especially in the high frequency range. By considering good chemical homogeneity and microwave absorption, we believe the as-fabricated Fe3O4@C composites can be promising candidates as highly effective microwave absorbers.

Organochlorine pesticides, polychlorinated biphenyls, and mercury in osprey eggs--1970-79--and their relationships to shell thinning and productivity

USGS Publications Warehouse

Wiemeyer, Stanley N.; Bunck, C.M.; Krynitsky, A.J.

1988-01-01

Osprey (Pandion haliaetus) eggs were collected in 14 states in 1970-79 and analyzed for organochlorine pesticides, polychlorinated biphenyls (PCBs), and mercury. Moderate shell thinning occurred in eggs from several areas. DDE was detected in all eggs, PCBs in 99%, DDD in 96%, dieldrin in 52%, and other compounds less frequently. Concentrations of DDT and its metabolites declined in eggs from Cape May County, New Jersey between 1970-72 and 1978-79. Eggs .from New Jersey in the early 1970s contained the highest concentrations of DDE. Dieldrin concentrations declined in eggs from the Potomac River, Maryland during 1971-77. Five different contaminants were significantly negatively correlated with shell thickness; DDE was most closely correlated. Ten percent shell thinning was associated with 2.0 ppm DDE, 15% with 4.2 ppm, and 20% with 8.7 ppm in eggs collected from randomly selected nests before egg loss. Shell thickness could not be accurately predicted from DDE concentrations in eggs collected after failure to hatch, presumably because the eggs with the thinnest shells had been broken and were unavailable for sampling. DDE was also significantly negatively correlated with brood size. Other contaminants did not appear to adversely affect shell thickness or reproductive success.

Small bending and stretching of sandwich-type shells

NASA Technical Reports Server (NTRS)

Reissner, Eric

1950-01-01

A theory has been developed for small bending and stretching of sandwich-type shells. This theory is an extension of the known theory of homogeneous thin elastic shells. It was found that two effects are important in the present problem, which are not normally of importance in the theory of curved shells: (1) the effect of transverse shear deformation and (2) the effect of transverse normal stress deformation. The first of these two effects has been known to be of importance in the theory of plates and beams. The second effect was found to occur in a manner which is typical for shells and has no counterpart in flat-plate theory. The general results of this report have been applied to the solution of problems concerning flat plates, circular rings, circular cylindrical shells, and spherical shells. In each case numerical examples have been given, illustrating the magnitude of the effects of transverse shear and normal stress deformation.

Tailoring sphere density for high pressure physical property measurements on liquids

NASA Astrophysics Data System (ADS)

Secco, R. A.; Tucker, R. F.; Balog, S. P.; Rutter, M. D.

2001-04-01

We present a new method of tailoring the density of a sphere for use as a probe in high pressure-temperature physical property experiments on liquids. The method consists of a composite sphere made of an inner, high density, metallic, spherical core and an exterior, low density, refractory, spherical shell or mantle. Micromechanical techniques are used to fabricate the composite sphere. We describe a relatively simple mechanical device that can grind hemispherical recesses as small as 200 μm in diameter in sapphire and as small as 500 μm in diameter in ruby hemispheres. Examples of composite spheres made with a Pt or WC core and Al2O3 shell used in metallic liquids pressurized to 16 GPa and 1900 K are shown.

Nonsymmetric dynamical thin-shell wormhole in Robinson-Trautman class

NASA Astrophysics Data System (ADS)

Svítek, O.; Tahamtan, T.

2018-02-01

The thin-shell wormhole created using the Darmois-Israel formalism applied to Robinson-Trautman family of spacetimes is presented. The stress energy tensor created on the throat is interpreted in terms of two dust streams and it is shown that asymptotically this wormhole settles to the Schwarzschild wormhole with a throat located at the position of the horizon. This behavior shows a nonlinear stability (within the Robinson-Trautman class) of this spherically symmetric wormhole. The gravitational radiation emitted by the Robinson-Trautman wormhole during the transition to spherical symmetry is indistinguishable from that of the corresponding black hole Robinson-Trautman spacetime. Subsequently, we show that the higher-dimensional generalization of Robinson-Trautman geometry offers a possibility of constructing wormholes without the need to violate the energy conditions for matter induced on the throat.

Model-Based Radiation Dose Correction for Yttrium-90 Microsphere Treatment of Liver Tumors With Central Necrosis

DOE Office of Scientific and Technical Information (OSTI.GOV)

Liu, Ching-Sheng; Department of Nuclear Medicine, Taipei Veterans General Hospital, Taipei, Taiwan; Lin, Ko-Han

Purpose: The objectives of this study were to model and calculate the absorbed fraction {phi} of energy emitted from yttrium-90 ({sup 90}Y) microsphere treatment of necrotic liver tumors. Methods and Materials: The tumor necrosis model was proposed for the calculation of {phi} over the spherical shell region. Two approaches, the semianalytic method and the probabilistic method, were adopted. In the former method, the range--energy relationship and the sampling of electron paths were applied to calculate the energy deposition within the target region, using the straight-ahead and continuous-slowing-down approximation (CSDA) method. In the latter method, the Monte Carlo PENELOPE code wasmore » used to verify results from the first method. Results: The fraction of energy, {phi}, absorbed from {sup 90}Y by 1-cm thickness of tumor shell from microsphere distribution by CSDA with complete beta spectrum was 0.832 {+-} 0.001 and 0.833 {+-} 0.001 for smaller (r{sub T} = 5 cm) and larger (r{sub T} = 10 cm) tumors (where r is the radii of the tumor [T] and necrosis [N]). The fraction absorbed depended mainly on the thickness of the tumor necrosis configuration, rather than on tumor necrosis size. The maximal absorbed fraction {phi} that occurred in tumors without central necrosis for each size of tumor was different: 0.950 {+-} 0.000, and 0.975 {+-} 0.000 for smaller (r{sub T} = 5 cm) and larger (r{sub T} = 10 cm) tumors, respectively (p < 0.0001). Conclusions: The tumor necrosis model was developed for dose calculation of {sup 90}Y microsphere treatment of hepatic tumors with central necrosis. With this model, important information is provided regarding the absorbed fraction applicable to clinical {sup 90}Y microsphere treatment.« less

Non-uniform thickness in Europa's icy shell: implications for astrobiology mission design

NASA Astrophysics Data System (ADS)

Fairén, A.; Amils, R.

The exploration of Europa's subsurface ocean is hardly constrained by the presence of an outer ice shell of unknown thickness: a somewhat thin crust would allow easier access to the ocean below. Current estimates for the thickness of Europa's icy surface range from a few km [1] to a few tens of km [2], the shell overlying a liquid water ocean up to 150 km thick [3,4,5]. The surface is believed to be young (mean age of 30-80 Myr [6]) and geologically active [7,8,9], as it is sparsely cratered. Here we report geological evidence indicating that the thickness of Europa's ice crust is actually a complex combination of thicker and thinner areas, highlighting the implications of such structure in the future exploration of the inner ocean. Detailed geologic mapping of impact craters, palimpsests and chaotic terrains distribution on Europa's surface, offers an initial approach to a comprehensive description of the thickness variation in the ice shell. Our analysis is based in: (1) Crater distribution, morphology, diameter and depth. Seminal work by Schenk [2] of transitions in crater shape/diameter suggested enhanced structural collapse of craters with diameter >27-33 km, that will consequently form multiring basins, due to weaker ice or a global ocean at depths >19-25 km. This being true, strictly can only be interpreted regionally: multiring basins indicate regions where the ice shell is thick; in those regions where the icy surface is thin, a bolide impact will breach the ice and leave neither crater nor multiring basin behind, but probably Ganymede's type palimpsests. (2) Palimpsest-type features distribution, indicating regions where the ice shell is too thin to support crater formation after big bolide impacts. In Ganymede, palimpsests are circular, low albedo and relief features formerly formed by impacts [10,11]. (3) Chaotic terrain distribution, considering features tens to hundreds of km across, that may be the evidence for very thin ice areas (from ˜ 2 km to zero shell thickness [12]) with liquid water at shallow depths [5], allowing for bolide penetration, diapirism and the extrusion of water to the surface. The heterogeneity in shell's thickness may be originated in spatial variations in tidal heating [13] and/or warm water upwellings from the silicate interior capable of melt-through the ice from below [12,14]. This thickness heterogeneity can be embedded in a general equatorward thickening trending, due to tidal dissipation and surface temperature variations [15]. A major constraint must be addressed at this point: the dynamism of ductile ice near the base of the shell may drive to decay in lateral thickness contrasts. But this effect has been examined both assuming ice as a Newtonian [16,17,18] and a non-Newtonian material [19], broadly reaching to similar conclusions: global shell thickness variations may survive for up to 100 Myr. In addition, lateral pressure gradients may not decay if they comprise only shallow depths [19]. Therefore, our results point to a dynamic non-uniform Europa's icy shell, displaying some regional and temporal heterogeneity in thickness. As thin/thick ice distribution is as time dependent as the surface ice features are (both are reshaped in periods ˜ 100 Myr), the analysis performed here offers an estimation of the current thickness distribution in the ice shell, estimation that cannot be extrapolated to ancient (e.g., >100 Myr) times. The astrobiological potential the shell and ocean below possess is highlighted by these results: a somewhere thin outer crust allows the possibility for some exogenous materials delivered by asteroids and comets to reach the inner liquid water ocean by breaching the brittle lithosphere [20], and so join to those generated in the interior of Europa via volcanic and hydrothermal activity [21]. In addition, pressure gradients driving the ductile ice at the base of the shell to flow laterally may help to redistribute such materials among the inner ice shell and/or ocean through time. Our results have a direct deal with the investigation of Europa's interior. Mission design will need to incorporate a drill system routine well suited to penetrate the ice shell tens of meters in the thinner areas, allowing to deep subsurface access and sampling. Landing and drilling targets should be selected among the zones where mapping indicates the presence of a thinner ice shell, as it may potentially suggest the existence of nutrient-rich hydrothermal plumes rising from the rocky interior and melting the ice from below, probably creating chaotic terrains [14]. Little-cratered, thin-crust areas would consequently be interpreted as key pacemakers to detect both the ice/ocean interface and the most complex environments under the ice shell. Additionally, drilling processes will be clearly easier in such zones. References: [1] Hoppa, G., et al. Science 285, 1899-1903 (1999). [2] Schenk, P.M. Nature 417, 419-421 (2002). [3] Anderson J.D. et al. Science 276, 1236-1239 (1997). [4] Anderson J.D. et al. Science 281, 2019-2022 (1998). [5] Carr, M.H., et al. Nature 391, 363-365 (1998). [6] Zahnle, K., et al. Icarus 163, 263-289 (2003). [7] Smith, B.A., et al. Science 206, 927-950 (1979). [8] Zahnle, K., et al. Icarus 136, 202-222 (1998). [9] Levison, H.F., et al. Icarus 143, 415-420 (2000). [10] Schenk, P.M. Lunar Planet. Sci. Conf. XXVII, #1137-1138 (1996). [11] Farrar, K.S. & Collins, G.C. Lunar Planet Sci. Conf. XXXIII, #1450 (2002). [12] Greenberg, R., et al. Icarus 141, 263-286 (1999). [13] Ojakangas, G.W. & Stevenson, D.J. Icarus 81, 220-241 (1989). [14] Collins, G.C. & Goodman, J.C. Europa's Icy Shell Conf., #7032 (2004). [15] Tobie, G., et al. J. Geophys. Res. 108, doi: 10.1029/2003JE002099 (2003). [16] Stevenson, D.J. Lunar Planet Sci. Conf. XXXI, #1506 (2000). [17] O'Brien, D.P., et al. Icarus 156, 152-161 (2002). [18] Buck, L., et al. Geophys. Res. Lett. 29, doi: 10.1029/2002GL016171 (2002). [19] Nimmo, F. Icarus in press (2004). [20] Pierazzo, E. and Chyba, C. F. Icarus 157, 120-127 (2002). [21] McCord, T.B. et al. Science 280, 1242-1245 (1998).

Synthesis of Various Metal/TiO2 Core/shell Nanorod Arrays

NASA Astrophysics Data System (ADS)

Zhu, Wei; Wang, Guan-zhong; Hong, Xun; Shen, Xiao-shuang

2011-02-01

We present a general approach to fabricate metal/TiO2 core/shell nanorod structures by two-step electrodeposition. Firstly, TiO2 nanotubes with uniform wall thickness are prepared in anodic aluminum oxide (AAO) membranes by electrodeposition. The wall thickness of the nanotubes could be easily controlled by modulating the deposition time, and their outer diameter and length are only limited by the channel diameter and the thickness of the AAO membranes, respectively. The nanotubes' tops prepared by this method are open, while the bottoms are connected directly with the Au film at the back of the AAO membranes. Secondly, Pd, Cu, and Fe elements are filled into the TiO2 nanotubes to form core/shell structures. The core/shell nanorods prepared by this two-step process are high density and free-standing, and their length is dependent on the deposition time.

Encapsulation of basic fibroblast growth factor by polyelectrolyte multilayer microcapsules and its controlled release for enhancing cell proliferation.

PubMed

She, Zhen; Wang, Chunxia; Li, Jun; Sukhorukov, Gleb B; Antipina, Maria N

2012-07-09

Basic fibroblast growth factor (FGF2) is an important protein for cellular activity and highly vulnerable to environmental conditions. FGF2 protected by heparin and bovine serum albumin was loaded into the microcapsules by a coprecipitation-based layer-by-layer encapsulation method. Low cytotoxic and biodegradable polyelectrolytes dextran sulfate and poly-L-arginine were used for capsule shell assembly. The shell thickness-dependent encapsulation efficiency was measured by enzyme-linked immunosorbent assay. A maximum encapsulation efficiency of 42% could be achieved by microcapsules with a shell thickness of 14 layers. The effects of microcapsule concentration and shell thickness on cytotoxicity, FGF2 release kinetics, and L929 cell proliferation were evaluated in vitro. The advantage of using microcapsules as the carrier for FGF2 controlled release for enhancing L929 cell proliferation was analyzed.

Myopic refractive shift represents dense nuclear sclerosis and thin lens in lenticular myopia.

PubMed

Cho, Yang Kyung; Huang, Wei; Nishimura, Eiichi

2013-09-01

It is not rare to meet unilateral nuclear sclerotic cataracts with myopic refractive changes (lenticular myopia) compared with the fellow eye in the ophthalmic examination of patients with decreased visual acuity. To determine the relationship between the myopic refractive changes and interocular differences of parameters, we investigated the interocular differences of ocular parameters between a lenticular myopic eye and the fellow eye. This retrospective study included 68 eyes of 34 patients, who showed unilateral lenticular myopia. We compared the dimensions of ocular component, such as anterior chamber depth, anterior chamber volume, lens thickness, vitreous chamber depth, lens position, lens density of nuclear sclerosis, anterior lens curvature and myopic refractive changes (spherical equivalent refraction) between the lenticular myopic eye and the myopic refractive change were examined. Statistically significant differences were found between the lenticular myopic eye and the fellow eye for anterior chamber depth (p = 0.015) anterior chamber volume (p = 0.031), lens thickness (p < 0.001), lens density of the nuclear sclerosis (p < 0.001) and the spherical equivalent myopic refractive changes (p < 0.001). Based on univariate analysis, the interocular difference in spherical equivalent refraction was significantly correlated with interocular differences of the density of the nuclear sclerosis (r = 0.79, p < 0.001), lens thickness (r = -0.70, p < 0.001) and vitreous chamber depth (r = 0.43, p = 0.012). Based on multiple regression analysis, the interocular difference in spherical equivalent refraction was significantly correlated with interocular differences of density of nuclear sclerosis (p < 0.001) and lens thickness (p = 0.007). The difference in myopic spherical change reflects the differences in the severity of nuclear sclerosis and lens thickness between the lenticular myopic eye and the fellow eye. © 2013 The Authors. Clinical and Experimental Optometry © 2013 Optometrists Association Australia.

Method and apparatus for generating microshells of refractory materials

NASA Technical Reports Server (NTRS)

Lee, Mark C. (Inventor); Schilling, Christopher (Inventor); Ladner, Jr., George O. (Inventor); Wang, Taylor G. (Inventor)

1987-01-01

A system is described for forming accurately spherical and centered fluid-filled shells, especially of high melting temperature material. Material which is to form the shells is placed in a solid form in a container, and the material is rapidly heated to a molten temperature to avoid recrystallization and the possible generation of unwanted microbubbles in the melt. Immediately after the molten shells are formed, they drop through a drop tower whose upper end is heated along a distance of at least one foot to provide time for dissipation of surface waves on the shells while they cool to a highly viscous, or just above melting temperature so that the bubble within the shell will not rise and become off centered. The rest of the tower is cryogenically cooled to cool the shell to a solid state.

High-pressure structure made of rings with peripheral weldments of reduced thickness

DOEpatents

Leventry, Samuel C.

1988-01-01

A high-pressure structure having a circular cylindrical metal shell made of metal rings joined together by weldments and which have peripheral areas of reduced shell thickness at the weldments which permit a reduction in the amount of weld metal deposited while still maintaining sufficient circumferential or hoop stress strength.

Tuning of shell thickness of solid lipid particles impacts the chemical stability of encapsulated ω-3 fish oil.

PubMed

Salminen, Hanna; Helgason, Thrandur; Kristinsson, Bjarki; Kristbergsson, Kristberg; Weiss, Jochen

2017-03-15

This study demonstrates that tuning the shell thickness of lipid particles can modulate their oxidative stability. We hypothesized that a thick crystallized shell around the incorporated fish oil would improve the oxidative stability due to the reduced diffusion of prooxidants and oxygen. We prepared solid lipid nanoparticles (5%w/w lipid phase, 1.5%w/w surfactant, pH 7) by using different ratios of tristearin as carrier lipid and ω-3 fish oil as incorporated liquid lipid stabilized by high- or low-melting lecithin. The physical, polymorphic and oxidative stability of the lipid particles was assessed. The high-melting lecithin was the key in inducing the formation of a solidified tristearin shell around the lipid particles by interfacial heterogeneous nucleation. Lipid particles containing a higher ratio of tristearin showed a better oxidative stability. The results revealed that a crystallized tristearin layer above 10nm was required to inhibit oxidation of the incorporated fish oil. This cut-off was shown for lipid particles containing 50-60% fish oil. This research gives important insights into understanding the relation between the thickness of the crystallized shell around the lipid particles and their chemical stability. Copyright © 2016 Elsevier Inc. All rights reserved.

Three-dimensional spherical models of convection in the earth's mantle

NASA Technical Reports Server (NTRS)

Bercovici, Dave; Schubert, Gerald; Glatzmaier, Gary A.

1989-01-01

Three-dimensional spherical models of mantle convection in the earth reveal that upwelling cylindrical plumes and downwelling planar sheets are the primary features of mantle circulation. Thus subduction zones and descending sheetlike slabs in the mantle are fundamental characteristics of thermal convection in a spherical shell and are not merely the consequences of the rigidity of the slabs, which are cooler than the surrounding mantle. Cylindrical mantle plumes that cause hot spots such as Hawaii are probably the only form of active upwelling and are therefore not just secondary convective currents separate from the large-scale mantle circulation.

Radiative lifetimes of zincblende CdSe/CdS quantum dots

DOE PAGES

Gong, Ke; Martin, James E.; Shea-Rohwer, Lauren E.; ...

2015-01-02

Recent synthetic advances have made available very monodisperse zincblende CdSe/CdS quantum dots having near-unity photoluminescence quantum yields. Because of the absence of nonradiative decay pathways, accurate values of the radiative lifetimes can be obtained from time-resolved PL measurements. Radiative lifetimes can also be obtained from the Einstein relations, using the static absorption spectra and the relative thermal populations in the angular momentum sublevels. We found that one of the inputs into these calculations is the shell thickness, and it is useful to be able to determine shell thickness from spectroscopic measurements. We use an empirically corrected effective mass model tomore » produce a “map” of exciton wavelength as a function of core size and shell thickness. These calculations use an elastic continuum model and the known lattice and elastic constants to include the effect of lattice strain on the band gap energy. The map is in agreement with the known CdSe sizing curve and with the shell thicknesses of zincblende core/shell particles obtained from TEM images. Furthermore, if selenium–sulfur diffusion is included and lattice strain is omitted from the calculation then the resulting map is appropriate for wurtzite CdSe/CdS quantum dots synthesized at high temperatures, and this map is very similar to one previously reported (J. Am. Chem. Soc. 2009, 131, 14299). Radiative lifetimes determined from time-resolved measurements are compared to values obtained from the Einstein relations, and found to be in excellent agreement. For a specific core size (2.64 nm diameter, in the present case), radiative lifetimes are found to decrease with increasing shell thickness. Thus, this is similar to the size dependence of one-component CdSe quantum dots and in contrast to the size dependence in type-II quantum dots.« less

Radiative shocks produced from spherical cryogenic implosions at the National Ignition Facility

DOE PAGES

Pak, A.; Divol, L.; Gregori, G.; ...

2013-05-20

Spherically expanding radiative shock waves have been observed from inertially confined implosion experiments at the National Ignition Facility. In these experiments, a spherical fusion target, initially 2 mm in diameter, is compressed via the pressure induced from the ablation of the outer target surface. At the peak compression of the capsule, x-ray and nuclear diagnostics indicate the formation of a central core, with a radius and ion temperature of ~20 μm and ~ 2 keV, respectively. This central core is surrounded by a cooler compressed shell of deuterium-tritium fuel that has an outer radius of ~40 μm and a densitymore » of >500 g/cm 3. Using inputs from multiple diagnostics, the peak pressure of the compressed core has been inferred to be of order 100 Gbar for the implosions discussed here. Furthermore, the shock front, initially located at the interface between the high pressure compressed fuel shell and surrounding in-falling low pressure ablator plasma, begins to propagate outwards after peak compression has been reached.« less

Interfacial effect on physical properties of composite media: Interfacial volume fraction with non-spherical hard-core-soft-shell-structured particles.

PubMed

Xu, Wenxiang; Duan, Qinglin; Ma, Huaifa; Chen, Wen; Chen, Huisu

2015-11-02

Interfaces are known to be crucial in a variety of fields and the interfacial volume fraction dramatically affects physical properties of composite media. However, it is an open problem with great significance how to determine the interfacial property in composite media with inclusions of complex geometry. By the stereological theory and the nearest-surface distribution functions, we first propose a theoretical framework to symmetrically present the interfacial volume fraction. In order to verify the interesting generalization, we simulate three-phase composite media by employing hard-core-soft-shell structures composed of hard mono-/polydisperse non-spherical particles, soft interfaces, and matrix. We numerically derive the interfacial volume fraction by a Monte Carlo integration scheme. With the theoretical and numerical results, we find that the interfacial volume fraction is strongly dependent on the so-called geometric size factor and sphericity characterizing the geometric shape in spite of anisotropic particle types. As a significant interfacial property, the present theoretical contribution can be further drawn into predicting the effective transport properties of composite materials.

Interfacial effect on physical properties of composite media: Interfacial volume fraction with non-spherical hard-core-soft-shell-structured particles

PubMed Central

Xu, Wenxiang; Duan, Qinglin; Ma, Huaifa; Chen, Wen; Chen, Huisu

2015-01-01

Interfaces are known to be crucial in a variety of fields and the interfacial volume fraction dramatically affects physical properties of composite media. However, it is an open problem with great significance how to determine the interfacial property in composite media with inclusions of complex geometry. By the stereological theory and the nearest-surface distribution functions, we first propose a theoretical framework to symmetrically present the interfacial volume fraction. In order to verify the interesting generalization, we simulate three-phase composite media by employing hard-core-soft-shell structures composed of hard mono-/polydisperse non-spherical particles, soft interfaces, and matrix. We numerically derive the interfacial volume fraction by a Monte Carlo integration scheme. With the theoretical and numerical results, we find that the interfacial volume fraction is strongly dependent on the so-called geometric size factor and sphericity characterizing the geometric shape in spite of anisotropic particle types. As a significant interfacial property, the present theoretical contribution can be further drawn into predicting the effective transport properties of composite materials. PMID:26522701

Self-consistent description of the SHFB equations for 112Sn

NASA Astrophysics Data System (ADS)

Ghafouri, M.; Sadeghi, H.; Torkiha, M.

2018-03-01

The Hartree-Fock (HF) method is an excellent approximation of the closed shell magic nuclei. Pair correlation is essential for the description of open shell nuclei and has been derived for even-even, odd-odd and even-odd nuclei. These effects are reported by Hartree-Fock with BCS (HFBCS) or Hartree-Fock-Bogolyubov (HFB). These issues have been investigated, especially in the nuclear charts, and such studies have been compared with the observed information. We compute observations such as total binding energy, charge radius, densities, separation energies, pairing gaps and potential energy surfaces for neutrons and protons, and compare them with experimental data and the result of the spherical codes. In spherical even-even neutron-rich nuclei are considered in the Skyrme-Hartree-Fock-Bogolyubov (SHFB) method with density-dependent pairing interaction. Zero-range density-dependent interactions is used in the pairing channel. We solve SHF or SHFB equations in the spatial coordinates with spherical symmetry for tin isotopes such as 112Sn. The numerical accuracy of solving equations in the coordinate space is much greater than the fundamental extensions, which yields almost precise results.

The Role of Convective Shell Thickness on Dynamo Scaling Laws for Magnetic Field Morphology: Implications for the Ice Giants and Future Earth

NASA Astrophysics Data System (ADS)

Stanley, S.; Tian, B. Y.

2016-12-01

Previous dynamo scaling law studies (Christensen and Aubert, 2006) have demonstrated that the morphology of a planet's magnetic field is determined by the local Rossby number (Rol): a non-dimensional diagnostic variable that quantifies the ratio of inertial forces to Coriolis forces on the average length scale of the flow. Dynamos with Rol < 0.1 produce dipolar dominated magnetic fields whereas dynamos with Rol > 0.1 produce multipolar magnetic fields. Scaling studies have also determined the dependence of the local Rossby number on non-dimensional parameters governing the system - specifically the Ekman, Prandtl, magnetic Prandtl and flux-based Rayleigh numbers (Olson and Christensen, 2006). However, those studies focused on the specific convective shell thickness of the Earth's core and hence could not determine the influence of convective shell thickness on the local Rossby number. Aubert et al. (2009) investigated the role of convective shell thickness on dynamo scaling laws in order to investigate the palaeo-evolution of the geodynamo. Due to the focus of that study, they varied the ratio of the inner to outer core radii (rio) from 0 to 0.35 and found Rol scales with (1+rio). Here we consider a larger range of convective shell thicknesses and find an exponential dependence of rio on the local Rossby number. Our results are consistent with Aubert et al. (2009) for their small rio values. With this new scaling dependence on convective shell thickness, we find that Uranus and Neptune reside deeply in the multipolar regime, whereas without the dependence on rio, they resided near Rol =0.1; i.e. on the boundary between dipolar and multipolar fields and close to where Earth resides in the parameter space. We also find that Earth will reside more deeply in the multipolar regime, and hence not produce a stable dipolar field once the inner core has grown such that rio = 0.4.

Compact Transducers and Arrays

DTIC Science & Technology

2005-05-01

Batra A, Priya S, Uchino K, Markley D, Newnham RE, Hofmann HF, "Energy harvesting using a piezoelectric "cymbal" transducer in dynamic environment...transducers, the flexural vibration of the metal shell causes an extensional vibration of the piezoelectric ceramic, or vice versa. Cymbal elements are...34On Axi-Symmetrical Vibrations of Shallow Spherical Shells," Quart. Appl. Math, 13 279 (1950). 19.R.S. Woollett, "Theory of the Piezoelectric Flexural

Resonant Vibrations and Vibrational Heating of Physically Nonlinear Viscoelastic Shells and Their Damping Using Piezoelectric Sensor and Actuator

NASA Astrophysics Data System (ADS)

Kirichok, I. F.

2017-09-01

Forced axisymmetric resonant vibrations and vibrational heating of viscoelastic, physically nonlinear, closed, spherical, and infinitely long cylindrical shells and ring with piezoelectric sensor and actuator are considered. The effect of physical nonlinearity of passive material on the vibration amplitude and vibrational heating temperature is studied. The possibility of active damping of vibrations by piezoelectric sensors and actuators is demonstrated.

The diamagnetic susceptibility of a donor in a semiconductor core shell quantum dot

NASA Astrophysics Data System (ADS)

Sudharshan, M. S.; Subhash, P.; Shaik, Nagoor Babu; Kalpana, P.; Jayakumar, K.; Reuben, A. Merwyn Jasper D.

2015-06-01

The effect of Aluminium concentration, shell thickness and size of the core shell Quantum Dot on the Diamagnetic Susceptibility of a donor in the Core Shell Quantum Dot is calculated in the effective mass approximation using the variational method. The results are presented and discussed.

Sound wave generation by a spherically symmetric outburst and AGN feedback in galaxy clusters II: impact of thermal conduction.

NASA Astrophysics Data System (ADS)

Tang, Xiaping; Churazov, Eugene

2018-04-01

We analyze the impact of thermal conduction on the appearance of a shock-heated gas shell which is produced when a spherically symmetric outburst of a supermassive black hole inflates bubbles of relativistic plasma at the center of a galaxy cluster. The presence of the hot and low-density shell can be used as an ancillary indicator for a high rate of energy release during the outburst, which is required to drive strong shocks into the gas. Here we show that conduction can effectively erase such shell, unless the diffusion of electrons is heavily suppressed. We conclude that a more robust proxy to the energy release rate is the ratio between the shock radius and bubble radius. We also revisited the issue of sound waves dissipation induced by thermal conduction in a scenario, where characteristic wavelength of the sound wave is set by the total energy of the outburst. For a fiducial short outburst model, the dissipation length does not exceed the cooling radius in a typical cluster, provided that the conduction is suppressed by a factor not larger than ˜100. For quasi-continuous energy injection neither the shock-heated shell nor the outgoing sound wave are important and the role of conduction is subdominant.

Superclustering in the explosion scenario. II - Prolate spheroidal shells from superconducting cosmic strings

NASA Technical Reports Server (NTRS)

Borden, David; Ostriker, Jeremiah P.; Weinberg, David H.

1989-01-01

If galaxies form on shells, then clusters of galaxies should form at the vertices where three shells intersect. Weinberg, Ostriker, and Dekel (WOD, 1989) studied this picture quantitatively and found that an intersecting spherical shell model reproduces many of the properties of the observed distribution of galaxy clusters, but that too much superclustering is produced. In this paper, the WOD analysis is repeated with prolate spheroids that could be created by superconducting cosmic strings. It is found that most of the attractive features of the WOD model are maintained in the more general case and there is slight improvement in some aspects, but that the overall problem of excessive superclustering is not really alleviated.

Fabrication of diamond shells

DOEpatents

Hamza, Alex V.; Biener, Juergen; Wild, Christoph; Woerner, Eckhard

2016-11-01

A novel method for fabricating diamond shells is introduced. The fabrication of such shells is a multi-step process, which involves diamond chemical vapor deposition on predetermined mandrels followed by polishing, microfabrication of holes, and removal of the mandrel by an etch process. The resultant shells of the present invention can be configured with a surface roughness at the nanometer level (e.g., on the order of down to about 10 nm RMS) on a mm length scale, and exhibit excellent hardness/strength, and good transparency in the both the infra-red and visible. Specifically, a novel process is disclosed herein, which allows coating of spherical substrates with optical-quality diamond films or nanocrystalline diamond films.

Fabrication of slender elastic shells by the coating of curved surfaces

NASA Astrophysics Data System (ADS)

Lee, A.; Brun, P.-T.; Marthelot, J.; Balestra, G.; Gallaire, F.; Reis, P. M.

2016-04-01

Various manufacturing techniques exist to produce double-curvature shells, including injection, rotational and blow molding, as well as dip coating. However, these industrial processes are typically geared for mass production and are not directly applicable to laboratory research settings, where adaptable, inexpensive and predictable prototyping tools are desirable. Here, we study the rapid fabrication of hemispherical elastic shells by coating a curved surface with a polymer solution that yields a nearly uniform shell, upon polymerization of the resulting thin film. We experimentally characterize how the curing of the polymer affects its drainage dynamics and eventually selects the shell thickness. The coating process is then rationalized through a theoretical analysis that predicts the final thickness, in quantitative agreement with experiments and numerical simulations of the lubrication flow field. This robust fabrication framework should be invaluable for future studies on the mechanics of thin elastic shells and their intrinsic geometric nonlinearities.

Fabrication of polyacrylate core-shell nanoparticles via spray drying method

NASA Astrophysics Data System (ADS)

Chen, Pengpeng; Cheng, Zenghui; Chu, Fuxiang; Xu, Yuzhi; Wang, Chunpeng

2016-05-01

Fine polyacrylate particles are thought to be environmental plastisols for car industry. However, these particles are mainly dried through demulsification of the latexes, which is not reproducible and hard to be scaled up. In this work, a spray drying method had been applied to the plastisols-used acrylate latex. By adjusting the core/shell ratio, spray drying process of the latex was fully studied. Scanning electronic microscopy observation of the nanoparticles before and after spray drying indicated that the core-shell structures could be well preserved and particles were well separated by spray drying if the shell was thick enough. Otherwise, the particles fused into each other and core-shell structures were destroyed. Polyacrylate plastisols were developed using diisononylphthalate as a plasticizer, and plastigels were obtained after heat treatment of the sols. Results showed that the shell thickness also had a great influence on the storage stability of the plastisols and mechanical properties of the plastigels.

Capsules made from prefabricated thin films

NASA Astrophysics Data System (ADS)

Amstad, Esther

2018-02-01

Capsules are composed of a core, typically a liquid containing active substances, and a surrounding shell. They are used to delay the degradation of active ingredients, protect them from reacting or interacting with substances contained in the surrounding shell, or to prevent premature consumption of encapsulants (1, 2). The performance of capsules is often determined by their permeability toward encapsulants and stability against rupture; these parameters can be adjusted with the composition, structure, and thickness of the shell (3, 4). Mechanically robust capsules with a minimal permeability even toward low molecular weight substances often have rather thick shells (5). On page 775 of this issue, Kumar et al. (6) report an elegant process to fabricate capsules with very thin, rigid shells that display a low permeability even toward small encapsulants.

Thermodynamic Theory of Spherically Trapped Coulomb Clusters

NASA Astrophysics Data System (ADS)

Wrighton, Jeffrey; Dufty, James; Bonitz, Michael; K"{A}Hlert, Hanno

2009-11-01

The radial density profile of a finite number of identical charged particles confined in a harmonic trap is computed over a wide ranges of temperatures (Coulomb coupling) and particle numbers. At low temperatures these systems form a Coulomb crystal with spherical shell structure which has been observed in ultracold trapped ions and in dusty plasmas. The shell structure is readily reproduced in simulations. However, analytical theories which used a mean field approachfootnotetext[1]C. Henning et al., Phys. Rev. E 74, 056403 (2006) or a local density approximationfootnotetext[2]C. Henning et al., Phys. Rev. E 76, 036404 (2007) have, so far, only been able to reproduce the average density profile. Here we present an approach to Coulomb correlations based on the hypernetted chain approximation with additional bridge diagrams. It is demonstrated that this model reproduces the correct shell structure within a few percent and provides the basis for a thermodynamic theory of Coulomb clusters in the strongly coupled fluid state.footnotetext[3]J. Wrighton, J.W. Dufty, H. K"ahlert and M. Bonitz, J. Phys. A 42, 214052 (2009) and Phys. Rev. E (2009) (to be submitted)

Conserved charges of black holes in Weyl and Einstein-Gauss-Bonnet gravities

NASA Astrophysics Data System (ADS)

Peng, Jun-Jin

2014-11-01

An off-shell generalization of the Abbott-Deser-Tekin (ADT) conserved charge was recently proposed by Kim et al. They achieved this by introducing off-shell Noether currents and potentials. In this paper, we construct the crucial off-shell Noether current by the variation of the Bianchi identity for the expression of EOM, with the help of the property of Killing vector. Our Noether current, which contains an additional term that is just one half of the Lie derivative of a surface term with respect to the Killing vector, takes a different form in comparison with the one in their work. Then we employ the generalized formulation to calculate the quasi-local conserved charges for the most general charged spherically symmetric and the dyonic rotating black holes with AdS asymptotics in four-dimensional conformal Weyl gravity, as well as the charged spherically symmetric black holes in arbitrary dimensional Einstein-Gauss-Bonnet gravity coupled to Maxwell or nonlinear electrodynamics in AdS spacetime. Our results confirm those obtained through other methods in the literature.

Design of efficient stiffened shells of revolution

NASA Technical Reports Server (NTRS)

Majumder, D. K.; Thornton, W. A.

1976-01-01

A method to produce efficient piecewise uniform stiffened shells of revolution is presented. The approach uses a first order differential equation formulation for the shell prebuckling and buckling analyses and the necessary conditions for an optimum design are derived by a variational approach. A variety of local yielding and buckling constraints and the general buckling constraint are included in the design process. The local constraints are treated by means of an interior penalty function and the general buckling load is treated by means of an exterior penalty function. This allows the general buckling constraint to be included in the design process only when it is violated. The self-adjoint nature of the prebuckling and buckling formulations is used to reduce the computational effort. Results for four conical shells and one spherical shell are given.

Spherical loudspeaker array for local active control of sound.

PubMed

Rafaely, Boaz

2009-05-01

Active control of sound has been employed to reduce noise levels around listeners' head using destructive interference from noise-canceling sound sources. Recently, spherical loudspeaker arrays have been studied as multiple-channel sound sources, capable of generating sound fields with high complexity. In this paper, the potential use of a spherical loudspeaker array for local active control of sound is investigated. A theoretical analysis of the primary and secondary sound fields around a spherical sound source reveals that the natural quiet zones for the spherical source have a shell-shape. Using numerical optimization, quiet zones with other shapes are designed, showing potential for quiet zones with extents that are significantly larger than the well-known limit of a tenth of a wavelength for monopole sources. The paper presents several simulation examples showing quiet zones in various configurations.

The heterogeneous ice shell thickness of Enceladus

NASA Astrophysics Data System (ADS)

Lucchetti, Alice; Pozzobon, Riccardo; Mazzarini, Francesco; Cremonese, Gabriele; Massironi, Matteo

2016-10-01

Saturn's moon Enceladus is the smallest Solar System body that presents an intense geologic activity on its surface. Plumes erupting from Enceladus' South Polar terrain (SPT) provide direct evidence of a reservoir of liquid below the surface. Previous analysis of gravity data determined that the ice shell above the liquid ocean must be 30-40 km thick from the South Pole up to 50° S latitude (Iess et al., 2014), however, understand the global or regional nature of the ocean beneath the ice crust is still challenging. To infer the thickness of the outer ice shell and prove the global extent of the ocean, we used the self-similar clustering method (Bonnet et al., 2001; Bour et al., 2002) to analyze the widespread fractures of the Enceladus's surface. The spatial distribution of fractures has been analyzed in terms of their self-similar clustering and a two-point correlation method was used to measure the fractal dimension of the fractures population (Mazzarini, 2004, 2010). A self-similar clustering of fractures is characterized by a correlation coefficient with a size range defined by a lower and upper cut-off, that represent a mechanical discontinuity and the thickness of the fractured icy crust, thus connected to the liquid reservoir. Hence, this method allowed us to estimate the icy shell thickness values in different regions of Enceladus from SPT up to northern regions.We mapped fractures in ESRI ArcGis environment in different regions of the satellite improving the recently published geological map (Crow-Willard and Pappalardo, 2015). On these regions we have taken into account the fractures, such as wide troughs and narrow troughs, located in well-defined geological units. Firstly, we analyzed the distribution of South Polar Region fracture patterns finding an ice shell thickness of ~ 31 km, in agreement with gravity measurements (Iess et al., 2014). Then, we applied the same approach to other four regions of the satellite inferring an increasing of the ice shell thickness from 31 to 70 km from the South Pole to northern regions. By these findings, we prove the global extent of the ocean underneath the ice crust of the satellite.

A circumferential crack in a cylindrical shell under tension.

NASA Technical Reports Server (NTRS)

Duncan-Fama, M. E.; Sanders, J. L., Jr.

1972-01-01

A closed cylindrical shell under uniform internal pressure has a slit around a portion of its circumference. Linear shallow shell theory predicts inverse square-root-type singularities in certain of the stresses at the crack tips. This paper reports the computed strength of these singularities for different values of a dimensionless parameter based on crack length, shell radius and shell thickness.

Buckling Behavior of Compression-Loaded Composite Cylindrical Shells With Reinforced Cutouts

NASA Technical Reports Server (NTRS)

Hilburger, Mark W.; Sarnes, James H., Jr.

2004-01-01

Results from a numerical study of the response of thin-walled compression-loaded quasi-isotropic laminated composite cylindrical shells with unreinforced and reinforced square cutouts are presented. The effects of cutout reinforcement orthotropy, size, and thickness on the nonlinear response of the shells are described. A nonlinear analysis procedure has been used to predict the nonlinear response of the shells. The results indicate that a local buckling response occurs in the shell near the cutout when subjected to load and is caused by a nonlinear coupling between local shell-wall deformations and in-plane destabilizing compression stresses near the cutout. In general, reinforcement around a cutout in a compression-loaded shell is shown to retard or eliminate the local buckling response near the cutout and increase the buckling load of the shell. However, some results show that certain reinforcement configurations can cause an unexpected increase in the magnitude of local deformations and stresses in the shell and cause a reduction in the buckling load. Specific cases are presented that suggest that the orthotropy, thickness, and size of a cutout reinforcement in a shell can be tailored to achieve improved buckling response characteristics.

Dynamics of Geometrically Nonlinear Elastic Nonthin Anisotropic Shells of Variable Thickness

NASA Astrophysics Data System (ADS)

Marchuk, M. V.; Tuchapskii, R. I.

2017-11-01

A theory of dynamic elastic geometrically nonlinear deformation of nonthin anisotropic shells with variable thickness is constructed. Shells are assumed asymmetric about the reference surface. Functions are expanded into Legendre series. The basic equations are written in a coordinate system aligned with the lines of curvature of the reference surface. The equations of motion and appropriate boundary conditions are obtained using the Hamilton-Ostrogradsky variational principle. The change in metric across the thickness is taken into account. The theory assumes that the refinement process is regular and allows deriving equations including products of terms of Legendre series of unknown functions of arbitrary order. The behavior of a square metallic plate acted upon by a pressure pulse distributed over its face is studied.

Size-tunable drug-delivery capsules composed of a magnetic nanoshell.

PubMed

Fuchigami, Teruaki; Kitamoto, Yoshitaka; Namiki, Yoshihisa

2012-01-01

Nano-sized FePt capsules with two types of ultrathin shell were fabricated using a template method for use in a nano-scale drug delivery system. One capsule was composed of an inorganic-organic hybrid shell of a water-soluble polymer and FePt nanoparticles, and the other capsule was composed of a network of fused FePt nanoparticles. We demonstrated that FePt nanoparticles selectively accumulated on the polymer molecules adsorbed on the template silica particles, and investigated the morphologies of the particle accumulation by changing the concentration of the polymer solution with which the template particles were treated. Capsular size was reduced from 340 to less than 90 nm by changing the size of the silica template particles, and the shell thickness was controlled by changing the amount of FePt nanoparticles adsorbed on the template particles. The hybrid shell was maintained by the connection of FePt nanoparticles and polymer molecules, and the shell thickness was 10 nm at the maximum. The FePt network shell was fabricated by hydrothermal treatment of the FePt/polymer-modified silica composite particles. The FePt network shell was produced from only the FePt alloy, and the shell thickness was 3 nm. Water-soluble anti-cancer drugs could be loaded into the hollow space of FePt network capsules, and lipid-coated FePt network capsules loaded with anti-cancer drugs showed cellular toxicity. The nano-sized capsular structure and the ultrathin shell suggest applicability as a drug carrier in magnetically guided drug delivery systems.

Size-tunable drug-delivery capsules composed of a magnetic nanoshell

PubMed Central

Fuchigami, Teruaki; Kitamoto, Yoshitaka; Namiki, Yoshihisa

2012-01-01

Nano-sized FePt capsules with two types of ultrathin shell were fabricated using a template method for use in a nano-scale drug delivery system. One capsule was composed of an inorganic-organic hybrid shell of a water-soluble polymer and FePt nanoparticles, and the other capsule was composed of a network of fused FePt nanoparticles. We demonstrated that FePt nanoparticles selectively accumulated on the polymer molecules adsorbed on the template silica particles, and investigated the morphologies of the particle accumulation by changing the concentration of the polymer solution with which the template particles were treated. Capsular size was reduced from 340 to less than 90 nm by changing the size of the silica template particles, and the shell thickness was controlled by changing the amount of FePt nanoparticles adsorbed on the template particles. The hybrid shell was maintained by the connection of FePt nanoparticles and polymer molecules, and the shell thickness was 10 nm at the maximum. The FePt network shell was fabricated by hydrothermal treatment of the FePt/polymer-modified silica composite particles. The FePt network shell was produced from only the FePt alloy, and the shell thickness was 3 nm. Water-soluble anti-cancer drugs could be loaded into the hollow space of FePt network capsules, and lipid-coated FePt network capsules loaded with anti-cancer drugs showed cellular toxicity. The nano-sized capsular structure and the ultrathin shell suggest applicability as a drug carrier in magnetically guided drug delivery systems. PMID:23507895

Formation mechanism of monodispersed spherical core-shell ceria/polymer hybrid nanoparticles

DOE Office of Scientific and Technical Information (OSTI.GOV)

Izu, Noriya, E-mail: n-izu@aist.go.jp; Uchida, Toshio; Matsubara, Ichiro

2011-08-15

Graphical abstract: The formation mechanism for core-shell nanoparticles is considered to be as follows: nucleation and particle growth occur simultaneously (left square); very slow particle growth occurs (middle square). Highlights: {yields} The size of the resultant nanoparticles was strongly and complicatedly dependent on the set temperature used during reflux heating and the PVP molecular weight. {yields} The size of the nanoparticles increased by a 2-step process as the reflux heating time increased. {yields} The IR spectral changes with increasing reflux time indicated the increase in the number of cross-linked polymers in the shell. -- Abstract: Very unique core-shell ceria (ceriummore » oxide)/polymer hybrid nanoparticles that have monodispersed spherical structures and are easily dispersed in water or alcohol without the need for a dispersant were reported recently. The formation mechanism of the unique nanoparticles, however, was not clear. In order to clarify the formation mechanism, these nanoparticles were prepared using a polyol method (reflux heating) under varied conditions of temperature, time, and concentration and molecular weight of added polymer (poly(vinylpyrrolidone)). The size of the resultant nanoparticles was strongly and complicatedly dependent on the set temperature used during reflux heating and the poly(vinylpyrrolidone) molecular weight. Furthermore, the size of the nanoparticles increased by a 2-step process as the reflux heating time increased. The IR spectral changes with increasing reflux time indicated the increase in the number of cross-linked polymers in the shell. From these results, the formation mechanism was discussed and proposed.« less

Nuclear shapes: Quest for triaxiality in 86Ge and the shape of 98Zr

NASA Astrophysics Data System (ADS)

Werner, V.; Lettmann, M.; Lizarazo, C.; Witt, W.; Cline, D.; Carpenter, M.; Doornenbal, P.; Obertelli, A.; Pietralla, N.; Savard, G.; Söderström, P.-A.; Wu, C.-Y.; Zhu, S.

2018-05-01

The region of neutron-rich nuclei above the N = 50 magic neutron shell closure encompasses a rich variety of nuclear structure, especially shapeevolutionary phenomena. This can be attributed to the complexity of sub-shell closures, their appearance and disappearance in the region, such as the N = 56 sub shell or Z = 40 for protons. Structural effects reach from a shape phase transition in the Zr isotopes, over shape coexistence between spherical, prolate, and oblate shapes, to possibly rigid triaxial deformation. Recent experiments in this region and their main physics viewpoints are summarized.

Green synthesis and characterization of size tunable silica-capped gold core-shell nanoparticles

NASA Astrophysics Data System (ADS)

Wangoo, Nishima; Shekhawat, Gajendra; Wu, Jin-Song; Bhasin, Aman K. K.; Suri, C. R.; Bhasin, K. K.; Dravid, Vinayak

2012-08-01

Silica-coated gold nanoparticles (Au@SiO2) with controlled silica-shell thickness were prepared by a modified Stober's method using 10-nm gold nanoparticles (AuNPs) as seeds. The AuNPs were silica-coated with a sol-gel reaction using tetraethylorthosilicate (TEOS) as a silica source and ammonia as a catalyst. An increase in TEOS concentration resulted in an increase in shell thickness. The NPs were characterized by transmission electron microscopy, selected area electron diffraction, energy-dispersive X-ray spectroscopy, scanning near-field ultrasound holography and scanning transmission electron microscopy. The method required no surface modification and the synthesized core shell nanoparticles can be used for various types of biological applications.

Reversible patterning of spherical shells through constrained buckling

NASA Astrophysics Data System (ADS)

Marthelot, J.; Brun, P.-T.; Jiménez, F. López; Reis, P. M.

2017-07-01

Recent advances in active soft structures envision the large deformations resulting from mechanical instabilities as routes for functional shape morphing. Numerous such examples exist for filamentary and plate systems. However, examples with double-curved shells are rarer, with progress hampered by challenges in fabrication and the complexities involved in analyzing their underlying geometrical nonlinearities. We show that on-demand patterning of hemispherical shells can be achieved through constrained buckling. Their postbuckling response is stabilized by an inner rigid mandrel. Through a combination of experiments, simulations, and scaling analyses, our investigation focuses on the nucleation and evolution of the buckling patterns into a reticulated network of sharp ridges. The geometry of the system, namely, the shell radius and the gap between the shell and the mandrel, is found to be the primary ingredient to set the surface morphology. This prominence of geometry suggests a robust, scalable, and tunable mechanism for reversible shape morphing of elastic shells.

High-value utilization of egg shell to synthesize Silver and Gold-Silver core shell nanoparticles and their application for the degradation of hazardous dyes from aqueous phase-A green approach.

PubMed

Sinha, Tanur; Ahmaruzzaman, M

2015-09-01

The common household material, egg shell of Anas platyrhynchos is utilized for the synthesis of Silver and Gold-Silver core shell nanoparticles using greener, environment friendly and economic way. The egg shell extracts were acting as a stabilizing and reducing agents. This method avoids the use of external reducing and stabilizing agents, templates and solvents. The effects of various reaction parameters, such as reaction temperature, concentration in the formation of nanoparticles have also been investigated. The compositional abundance of gelatin may be envisaged for the effective reductive as well as stabilizing potency. The mechanisms for the formation of NPs have also been presented. The synthesized Ag NPs formed were predominantly spherical in nature with an average size of particles in the range of 6-26 nm. While, Au-Ag core shell nanoparticles formed were spherical and oval shaped, within a narrow size spectrum of 9-18 nm. Both the Ag NPs Au-and Ag core shell nanoparticles showed characteristic Bragg's reflection planes of fcc structure and surface plasmon resonance at 430 nm and 365 nm, respectively. The NPs were utilized for the removal of toxic and hazardous dyes, such as Rose Bengal, Methyl Violet 6 B and Methylene Blue from aqueous phase. Approximately 98.2%, 98.4% and 97% degradations of Rose Bengal, Methyl Violet 6 B, and Methylene Blue were observed with Ag NPs, while the percentage degradation of these dyes was 97.3%, 97.6% and 96% with Au-Ag NPs, respectively. Therefore, the present study has opened up an innovative way for synthesizing Ag NPs and Au-Ag bimetallic nanostructures of different morphologies and sizes involving the utilization of egg shell extract. The high efficiency of the NPs as photocatalysts has opened a promising application for the removal of hazardous dyes from the industrial effluents. Copyright © 2015 Elsevier Inc. All rights reserved.

Asymmetric Spherical Coupled Escape Probability: Model and Results for Optically Thick Cometary Comae

NASA Astrophysics Data System (ADS)

Gersch, Alan; A'Hearn, M. F.

2012-05-01

We have adapted the Coupled Escape Probability method of radiative transfer calculations for use in asymmetrical spherical situations and applied it to modeling molecular emission spectra of potentially optically thick cometary comae. Recent space missions (e.g. Deep Impact & EPOXI) have provided spectra from comets of unprecedented spatial resolution of the regions of the coma near the nucleus, where the coma may be optically thick. Currently active missions (e.g. Rosetta) and hopefully more in the future will continue the trend and demonstrate the need for better modeling of comae with optical depth effects included. Here we present a brief description of our model and results of interest for cometary studies, especially for space based observations. Although primarily motivated by the need for comet modeling, our (asymmetric spherical) radiative transfer model could be used for studying other astrophysical phenomena as well.

Correcting spherical aberrations induced by an unknown medium through determination of its refractive index and thickness.

PubMed

Iwaniuk, Daniel; Rastogi, Pramod; Hack, Erwin

2011-09-26

In imaging and focusing applications, spherical aberration induces axial broadening of the point spread function (PSF). A transparent medium between lens and object of interest induces spherical aberration. We propose a method that first obtains both the physical thickness and the refractive index of the aberration inducing medium in situ by measuring the induced focal shifts for paraxial and large angle rays. Then, the fourth order angle dependence of the optical path difference inside the medium is used to correct the spherical aberration using a phase-only spatial light modulator. The obtained measurement accuracy of 3% is sufficient for a complete compensation as demonstrated in a model microscope with NA 0.3 with glass plate induced axial broadening of the PSF by a factor of 5. © 2011 Optical Society of America

Design of Aerosol Coating Reactors: Precursor Injection

PubMed Central

Buesser, Beat; Pratsinis, Sotiris E.

2013-01-01

Particles are coated with thin shells to facilitate their processing and incorporation into liquid or solid matrixes without altering core particle properties (coloristic, magnetic, etc.). Here, computational fluid and particle dynamics are combined to investigate the geometry of an aerosol reactor for continuous coating of freshly-made titanium dioxide core nanoparticles with nanothin silica shells by injection of hexamethyldisiloxane (HMDSO) vapor downstream of TiO2 particle formation. The focus is on the influence of HMDSO vapor jet number and direction in terms of azimuth and inclination jet angles on process temperature and coated particle characteristics (shell thickness and fraction of uncoated particles). Rapid and homogeneous mixing of core particle aerosol and coating precursor vapor facilitates synthesis of core-shell nanoparticles with uniform shell thickness and high coating efficiency (minimal uncoated core and free coating particles). PMID:23658471

The effect of oxide shell thickness on the structural, electronic, and optical properties of Si-SiO{sub 2} core-shell nano-crystals: A (time dependent)density functional theory study

DOE Office of Scientific and Technical Information (OSTI.GOV)

Nazemi, Sanaz, E-mail: s.nazemi@ut.ac.ir, E-mail: pourfath@ut.ac.ir; Soleimani, Ebrahim Asl; Pourfath, Mahdi, E-mail: s.nazemi@ut.ac.ir, E-mail: pourfath@ut.ac.ir

2016-04-14

Due to their tunable properties, silicon nano-crystals (NC) are currently being investigated. Quantum confinement can generally be employed for size-dependent band-gap tuning at dimensions smaller than the Bohr radius (∼5 nm for silicon). At the nano-meter scale, however, increased surface-to-volume ratio makes the surface effects dominant. Specifically, in Si-SiO{sub 2} core-shell semiconductor NCs the interfacial transition layer causes peculiar electronic and optical properties, because of the co-existence of intermediate oxidation states of silicon (Si{sup n+}, n = 0–4). Due to the presence of the many factors involved, a comprehensive understanding of the optical properties of these NCs has not yet been achieved. Inmore » this work, Si-SiO{sub 2} NCs with a diameter of 1.1 nm and covered by amorphous oxide shells with thicknesses between 2.5 and 4.75 Å are comprehensively studied, employing density functional theory calculations. It is shown that with increased oxide shell thickness, the low-energy part of the optical transition spectrum of the NC is red shifted and attenuated. Moreover, the absorption coefficient is increased in the high-energy part of the spectrum which corresponds to SiO{sub 2} transitions. Structural examinations indicate a larger compressive stress on the central silicon cluster with a thicker oxide shell. Examination of the local density of states reveals the migration of frontier molecular orbitals from the oxide shell into the silicon core with the increase of silica shell thickness. The optical and electrical properties are explained through the analysis of the density of states and the spatial distribution of silicon sub-oxide species.« less

Interfacial effect on the structural and optical properties of pure SnO2 and dual shells (ZnO; SiO2) coated SnO2 core-shell nanospheres for optoelectronic applications

NASA Astrophysics Data System (ADS)

Selvi, N.; Sankar, S.; Dinakaran, K.

2014-12-01

Nanocrystallites of SnO2 core and dual shells (ZnO, SiO2) coated SnO2 core-shell nanospheres were successfully synthesized by co-precipitation method. The as prepared and annealed samples were characterized by X-ray diffraction (XRD), Fourier Transform Infrared spectroscopy (FTIR), High resolution transmission electron microscopy (HRTEM) and UV-Vis analysis. XRD pattern confirms the obtained SnO2 core with tetragonal rutile crystalline structure and the shell ZnO with hexagonal structure. FTIR result shows the functional groups present in the samples. The spherical morphology and the formation of the core-shell structures have been confirmed by HRTEM measurements. The UV-Vis showed that band gap is red shifted for as-prepared and the shells coated core-shell samples. From this investigation it can be concluded that the surface modification with different metal and insulating oxides strongly influences the optical properties of the core-shell materials which enhance their potential applications towards optical devices fabrication.

The influence of shell thickness of Au@TiO2 core-shell nanoparticles on the plasmonic enhancement effect in dye-sensitized solar cells.

PubMed

Liu, Wei-Liang; Lin, Fan-Cheng; Yang, Yu-Chen; Huang, Chen-Hsien; Gwo, Shangjr; Huang, Michael H; Huang, Jer-Shing

2013-09-07

Plasmonic core-shell nanoparticles (PCSNPs) can function as nanoantennas and improve the efficiency of dye-sensitized solar cells (DSSCs). To achieve maximum enhancement, the morphology of PCSNPs needs to be optimized. Here we precisely control the morphology of Au@TiO2 PCSNPs and systematically study its influence on the plasmonic enhancement effect. The enhancement mechanism was found to vary with the thickness of the TiO2 shell. PCSNPs with a thinner shell mainly enhance the current, whereas particles with a thicker shell improve the voltage. While pronounced plasmonic enhancement was found in the near infrared regime, wavelength-independent enhancement in the visible range was observed and attributed to the plasmonic heating effect. Emission lifetime measurement confirms that N719 molecules neighboring nanoparticles with TiO2 shells exhibit a longer lifetime than those in contact with metal cores. Overall, PCSNPs with a 5 nm shell give the highest efficiency enhancement of 23%. Our work provides a new synthesis route for well-controlled Au@TiO2 core-shell nanoparticles and gains insight into the plasmonic enhancement in DSSCs.

Eosin-Y sensitized core-shell TiO2-ZnO nano-structured photoanodes for dye-sensitized solar cell applications.

PubMed

Manikandan, V S; Palai, Akshaya K; Mohanty, Smita; Nayak, Sanjay K

2018-06-01

In the current investigation, TiO 2 and TiO 2 -ZnO (core-shell) spherical nanoparticles were synthesized by simple combined hydrolysis and refluxing method. A TiO 2 core nanomaterial on the shell material of ZnO was synthesized by utilizing variable ratios of ZnO. The structural characterization of TiO 2 -ZnO core/shell nanoparticles were done by XRD analysis. The spherical structured morphology of the TiO 2 -ZnO has been confirmed through field emission scanning electron microscopy (FE-SEM) and transmission electron microscopy (TEM) studies. The UV-visible spectra of TiO 2 -ZnO nanostructures were also compared with the pristine TiO 2 to investigate the shift of wavelength. The TiO 2 -ZnO core/shell nanoparticles at the interface efficiently collect the photogenarated electrons from ZnO and also ZnO act a barrier for reduced charge recombination of electrolyte and dye-nanoparticles interface. This combination improved the light absorption which induced the charge transfer ability and dye loading capacity of core-shell nanoparticles. An enhancement in the short circuit current (J sc ) from 1.67 mA/cm 2 to 2.1 mA/cm 2 has been observed for TiO 2 -ZnObased photoanode (with platinum free counter electrode), promises an improvement in the energy conversion efficiency by 57% in comparison with that of the DSSCs based on the pristine TiO 2 . Henceforth, TiO 2 -ZnO photoelectrode in ZnO will effectively act as barrier at the interface of TiO 2 -ZnO and TiO 2 , ensuring the potential for DSSC application. Copyright © 2018 Elsevier B.V. All rights reserved.

Non-Negative Spherical Deconvolution (NNSD) for estimation of fiber Orientation Distribution Function in single-/multi-shell diffusion MRI.

PubMed

Cheng, Jian; Deriche, Rachid; Jiang, Tianzi; Shen, Dinggang; Yap, Pew-Thian

2014-11-01

Spherical Deconvolution (SD) is commonly used for estimating fiber Orientation Distribution Functions (fODFs) from diffusion-weighted signals. Existing SD methods can be classified into two categories: 1) Continuous Representation based SD (CR-SD), where typically Spherical Harmonic (SH) representation is used for convenient analytical solutions, and 2) Discrete Representation based SD (DR-SD), where the signal profile is represented by a discrete set of basis functions uniformly oriented on the unit sphere. A feasible fODF should be non-negative and should integrate to unity throughout the unit sphere S(2). However, to our knowledge, most existing SH-based SD methods enforce non-negativity only on discretized points and not the whole continuum of S(2). Maximum Entropy SD (MESD) and Cartesian Tensor Fiber Orientation Distributions (CT-FOD) are the only SD methods that ensure non-negativity throughout the unit sphere. They are however computational intensive and are susceptible to errors caused by numerical spherical integration. Existing SD methods are also known to overestimate the number of fiber directions, especially in regions with low anisotropy. DR-SD introduces additional error in peak detection owing to the angular discretization of the unit sphere. This paper proposes a SD framework, called Non-Negative SD (NNSD), to overcome all the limitations above. NNSD is significantly less susceptible to the false-positive peaks, uses SH representation for efficient analytical spherical deconvolution, and allows accurate peak detection throughout the whole unit sphere. We further show that NNSD and most existing SD methods can be extended to work on multi-shell data by introducing a three-dimensional fiber response function. We evaluated NNSD in comparison with Constrained SD (CSD), a quadratic programming variant of CSD, MESD, and an L1-norm regularized non-negative least-squares DR-SD. Experiments on synthetic and real single-/multi-shell data indicate that NNSD improves estimation performance in terms of mean difference of angles, peak detection consistency, and anisotropy contrast between isotropic and anisotropic regions. Copyright © 2014 Elsevier Inc. All rights reserved.

Gridless particle technique for the Vlasov-Poisson system in problems with high degree of symmetry

NASA Astrophysics Data System (ADS)

Boella, E.; Coppa, G.; D'Angola, A.; Peiretti Paradisi, B.

2018-03-01

In the paper, gridless particle techniques are presented in order to solve problems involving electrostatic, collisionless plasmas. The method makes use of computational particles having the shape of spherical shells or of rings, and can be used to study cases in which the plasma has spherical or axial symmetry, respectively. As a computational grid is absent, the technique is particularly suitable when the plasma occupies a rapidly changing space region.

DOE Office of Scientific and Technical Information (OSTI.GOV)

Shang Yazhuo; Hu Jun; Liu Honglai, E-mail: yazhuoshang@ecust.edu.c

Novel large-scale hollow ZnO spherical shells were synthesized by ionic liquids assisted hydrothermal oxidization of pure zinc powder without any catalyst at a relatively low temperature of 160 deg. C. X-ray diffraction (XRD), energy dispersive X-ray spectroscopy (EDX) and scanning electron microscopy (SEM) patterns show that the shells are composed of ZnO and the structure of the shells is very unique. Textured flower-like ZnO consisting of ZnO rods is grown on the outer surfaces of shells forming a triple assembly. Room-temperature photoluminescence spectra of the oxidized material show a sharp peak at 379 nm and a wider broad peak centeredmore » at 498 nm. The possible growth mechanism of the triple assembly of ZnO is discussed in detail. - Graphical abstract: A proposed growth mechanism of large scale hollow ZnO. Bubbles provide the aggregation center for ionic liquids that leads to the formation of hollow Zn particle-dotted shells, buoyancy promotes shells to go upward, the breach occurs when shells are subjected to overpressure.« less

Coulomb energy of uniformly charged spheroidal shell systems.

PubMed

Jadhao, Vikram; Yao, Zhenwei; Thomas, Creighton K; de la Cruz, Monica Olvera

2015-03-01

We provide exact expressions for the electrostatic energy of uniformly charged prolate and oblate spheroidal shells. We find that uniformly charged prolate spheroids of eccentricity greater than 0.9 have lower Coulomb energy than a sphere of the same area. For the volume-constrained case, we find that a sphere has the highest Coulomb energy among all spheroidal shells. Further, we derive the change in the Coulomb energy of a uniformly charged shell due to small, area-conserving perturbations on the spherical shape. Our perturbation calculations show that buckling-type deformations on a sphere can lower the Coulomb energy. Finally, we consider the possibility of counterion condensation on the spheroidal shell surface. We employ a Manning-Oosawa two-state model approximation to evaluate the renormalized charge and analyze the behavior of the equilibrium free energy as a function of the shell's aspect ratio for both area-constrained and volume-constrained cases. Counterion condensation is seen to favor the formation of spheroidal structures over a sphere of equal area for high values of shell volume fractions.

Amplified Photon Upconversion by Photonic Shell of Cholesteric Liquid Crystals.

PubMed

Kang, Ji-Hwan; Kim, Shin-Hyun; Fernandez-Nieves, Alberto; Reichmanis, Elsa

2017-04-26

As an effective platform to exploit triplet-triplet-annihilation-based photon upconversion (TTA-UC), microcapsules composed of a fluidic UC core and photonic shell are microfluidically prepared using a triple emulsion as the template. The photonic shell consists of cholesteric liquid crystals (CLCs) with a periodic helical structure, exhibiting a photonic band gap. Combined with planar anchoring at the boundaries, the shell serves as a resonance cavity for TTA-UC emission and enables spectral tuning of the UC under low-power-density excitation. The CLC shell can be stabilized by introducing a polymerizable mesogen in the LC host. Because of the microcapsule spherical symmetry, spontaneous emission of the delayed fluorescence is omnidirectionally amplified at the edge of the stop band. These results demonstrate the range of opportunities provided by TTA-UC systems for the future design of low-threshold photonic devices.

Explosive fragmentation of liquids in spherical geometry

NASA Astrophysics Data System (ADS)

Milne, A.; Longbottom, A.; Frost, D. L.; Loiseau, J.; Goroshin, S.; Petel, O.

2017-05-01

Rapid acceleration of a spherical shell of liquid following central detonation of a high explosive causes the liquid to form fine jets that are similar in appearance to the particle jets that are formed during explosive dispersal of a packed layer of solid particles. Of particular interest is determining the dependence of the scale of the jet-like structures on the physical parameters of the system, including the fluid properties (e.g., density, viscosity, and surface tension) and the ratio of the mass of the liquid to that of the explosive. The present paper presents computational results from a multi-material hydrocode describing the dynamics of the explosive dispersal process. The computations are used to track the overall features of the early stages of dispersal of the liquid layer, including the wave dynamics, and motion of the spall and accretion layers. The results are compared with new experimental results of spherical charges surrounded by a variety of different fluids, including water, glycerol, ethanol, and vegetable oil, which together encompass a significant range of fluid properties. The results show that the number of jet structures is not sensitive to the fluid properties, but primarily dependent on the mass ratio. Above a certain mass ratio of liquid fill-to-explosive burster ( F / B), the number of jets is approximately constant and consistent with an empirical model based on the maximum thickness of the accretion layer. For small values of F / B, the number of liquid jets is reduced, in contrast with explosive powder dispersal, where small F / B yields a larger number of particle jets. A hypothetical explanation of these features based on the nucleation of cavitation is explored numerically.

Finite Element Analysis of Geodesically Stiffened Cylindrical Composite Shells Using a Layerwise Theory

NASA Technical Reports Server (NTRS)

Gerhard, Craig Steven; Gurdal, Zafer; Kapania, Rakesh K.

1996-01-01

Layerwise finite element analyses of geodesically stiffened cylindrical shells are presented. The layerwise laminate theory of Reddy (LWTR) is developed and adapted to circular cylindrical shells. The Ritz variational method is used to develop an analytical approach for studying the buckling of simply supported geodesically stiffened shells with discrete stiffeners. This method utilizes a Lagrange multiplier technique to attach the stiffeners to the shell. The development of the layerwise shells couples a one-dimensional finite element through the thickness with a Navier solution that satisfies the boundary conditions. The buckling results from the Ritz discrete analytical method are compared with smeared buckling results and with NASA Testbed finite element results. The development of layerwise shell and beam finite elements is presented and these elements are used to perform the displacement field, stress, and first-ply failure analyses. The layerwise shell elements are used to model the shell skin and the layerwise beam elements are used to model the stiffeners. This arrangement allows the beam stiffeners to be assembled directly into the global stiffness matrix. A series of analytical studies are made to compare the response of geodesically stiffened shells as a function of loading, shell geometry, shell radii, shell laminate thickness, stiffener height, and geometric nonlinearity. Comparisons of the structural response of geodesically stiffened shells, axial and ring stiffened shells, and unstiffened shells are provided. In addition, interlaminar stress results near the stiffener intersection are presented. First-ply failure analyses for geodesically stiffened shells utilizing the Tsai-Wu failure criterion are presented for a few selected cases.

Optimization of wall thickness and lay-up for the shell-like composite structure loaded by non-uniform pressure field

NASA Astrophysics Data System (ADS)

Shevtsov, S.; Zhilyaev, I.; Oganesyan, P.; Axenov, V.

2017-01-01

The glass/carbon fiber composites are widely used in the design of various aircraft and rotorcraft components such as fairings and cowlings, which have predominantly a shell-like geometry and are made of quasi-isotropic laminates. The main requirements to such the composite parts are the specified mechanical stiffness to withstand the non-uniform air pressure at the different flight conditions and reduce a level of noise caused by the airflow-induced vibrations at the constrained weight of the part. The main objective of present study is the optimization of wall thickness and lay-up of composite shell-like cowling. The present approach assumes conversion of the CAD model of the cowling surface to finite element (FE) representation, then its wind tunnel testing simulation at the different orientation of airflow to find the most stressed mode of flight. Numerical solutions of the Reynolds averaged Navier-Stokes (RANS) equations supplemented by k-w turbulence model provide the spatial distributions of air pressure applied to the shell surface. At the formulation of optimization problem the global strain energy calculated within the optimized shell was assumed as the objective. A wall thickness of the shell had to change over its surface to minimize the objective at the constrained weight. We used a parameterization of the problem that assumes an initiation of auxiliary sphere with varied radius and coordinates of the center, which were the design variables. Curve that formed by the intersection of the shell with sphere defined boundary of area, which should be reinforced by local thickening the shell wall. To eliminate a local stress concentration this increment was defined as the smooth function defined on the shell surface. As a result of structural optimization we obtained the thickness of shell's wall distribution, which then was used to design the draping and lay-up of composite prepreg layers. The global strain energy in the optimized cowling was reduced in2.5 times at the weight growth up to 15%, whereas the eigenfrequencies at the 6 first natural vibration modes have been increased by 5-15%. The present approach and developed programming tools that demonstrated a good efficiency and stability at the acceptable computational costs can be used to optimize a wide range of shell-like structures made of quasi-isotropic laminates.

Design and synthesis of magnetic nanoparticles with gold shells for single particle optical tracking

NASA Astrophysics Data System (ADS)

Lim, Jitkang

The design, synthesis, and characterization of iron oxide core, gold shell nanoparticles are studied in this thesis. Firstly, nanoparticles with 18 +/- 1.7 nm diameter iron oxide cores with ˜5 nm thick gold shells were synthesized via a new seed-mediated electroless deposition method. The nanoparticles were superparamagnetic at room temperature and could be reversibly collected by a permanent magnet. These nanoparticles displayed a sharp localized surface plasmon resonance peak at 605 nm, as predicted by scattering theory, and their large scattering cross-section allowed them to be individually resolved in darkfield optical microscopy while undergoing Brownian motion in aqueous suspension. Later, commercially available 38 +/- 3.8 nm diameter spherical iron oxide nanoparticles (from Ocean Nanotech, Inc) were employed to make core-shell particles. These particles were decorated with cationic poly(diallyldimethylammonium chloride) (PDDA) which further promotes the attachment of small gold clusters. After gold seeding, the average hydrodynamic diameter of the core-shell particles is 172 +/- 65.9 nm. The magnetophoretic motion of these particles was guided by a piece of magnetized mu-metal. Individual particle trajectories were observed by darkfield optical microscopy. The typical magnetophoretic velocity achieved was within the range of 1--10 mum/sec. Random walk analysis performed on these particles while undergoing Brownian motion confirmed that individual particles were indeed being imaged. The particle size variation within the observed sample obtained through random walk analysis was within the size distribution obtained by dynamic light scattering. When the current to the solenoid used to magnetize the mu-metal was turned off, all the collected core-shell particles were readily redispersed by diffusion back into the surrounding environment. A Peclet number analysis was performed to probe the convective motion of nanospheres and nanorods under the influence of magnetophoresis and diffusion. Under most circumstances, magnetophoretic behavior dominates diffusion for nanorods, as the magnetic field lines tend to align the magnetic moment along the rod axis. The synthesis and dispersion of fluorophore-tagged nanorods are described. Fluorescence microscopy was employed to image the nanorod motion in a magnetic field gradient. The preliminary experimental data are consistent with the Peclet number analysis. Lastly, the colloidal stability of iron oxide core, gold shell nanoparticles in high ionic strength media was investigated. Such particles are sufficiently charged to be stable against flocculation without modification in low ionic strength media, but they require surface modification to be stably dispersed in elevated ionic strength media that are appropriate for biotechnological applications. Dynamic light scattering and ultraviolet-visible spectrophotometry were used to monitor the colloidal stability of core-shell particles in pH 7.4, 150 mM ionic strength phosphate buffered saline (PBS). While uncoated particles flocculated immediately upon being introduced into PBS, core-shell particles with adsorbed layers of bovine serum albumin or the amphiphilic triblock copolymers Pluronic F127 and Pluronic F68 resist flocculation after more than five days in PBS. Adsorbed dextran allowed flocculation that was limited to the formation of small clusters, while poly(ethylene glycol) homopolymers ranging in molecular weight from 6,000 to 100,000 were ineffective steric stabilizers. The effectiveness of adsorbed Pluronic copolymers as steric stabilizers was interpreted in terms of the measured adsorbed layer thickness and extended DLVO theory predictions of the interparticle interactions.

Characteristics of global organic matrix in normal and pimpled chicken eggshells.

PubMed

Liu, Z; Song, L; Zhang, F; He, W; Linhardt, R J

2017-10-01

The organic matrix from normal and pimpled calcified chicken eggshells were dissociated into acid-insoluble, water-insoluble, and facultative-soluble (both acid- and water-soluble) components, to understand the influence of shell matrix on eggshell qualities. A linear correlation was shown among these 3 matrix components in normal eggshells but was not observed in pimpled eggshells. In pimpled eggshells, the percentage contents of all 4 groups of matrix (the total matrix, acid-insoluble matrix, water-insoluble matrix, and facultative-soluble matrix) were significantly higher than that in normal eggshells. The amounts of both total matrix and acid-insoluble matrix in individual pimpled calcified shells were high, even though their weight was much lower than a normal eggshell. In both normal and pimpled eggshells, the calcified eggshell weight and shell thickness significantly and positively correlated with the amounts of all 4 groups of matrix in an individual calcified shell. In normal eggshells, the calcified shell thickness and shell breaking strength showed no significant correlations with the percentage contents of all 4 groups of matrix. In normal eggshells, only the shell membrane weight significantly correlated with the constituent ratios of both acid-insoluble matrix and facultative-soluble matrix in the whole matrix. In pimpled eggshells, 3 variables (calcified shell weight, shell thickness, and breaking strength) were significantly correlated with the constituent proportions of both acid-insoluble matrix and facultative-matrix. This study suggests that mechanical properties of normal eggshells may not linearly depend on the organic matrix content in the calcified eggshells and that pimpled eggshells might result by the disequilibrium enrichment of some proteins with negative effects. © 2017 Poultry Science Association Inc.

Controlling the Growth of Staphylococcus epidermidis by Layer-By-Layer Encapsulation.

PubMed

Jonas, Alain M; Glinel, Karine; Behrens, Adam; Anselmo, Aaron C; Langer, Robert S; Jaklenec, Ana

2018-05-16

Commensal skin bacteria such as Staphylococcus epidermidis are currently being considered as possible components in skin-care and skin-health products. However, considering the potentially adverse effects of commensal skin bacteria if left free to proliferate, it is crucial to develop methodologies that are capable of maintaining bacteria viability while controlling their proliferation. Here, we encapsulate S. epidermidis in shells of increasing thickness using layer-by-layer assembly, with either a pair of synthetic polyelectrolytes or a pair of oppositely charged polysaccharides. We study the viability of the cells and their delay of growth depending on the composition of the shell, its thickness, the charge of the last deposited layer, and the degree of aggregation of the bacteria which is varied using different coating procedures-among which is a new scalable process that easily leads to large amounts of nonaggregated bacteria. We demonstrate that the growth of bacteria is not controlled by the mechanical properties of the shell but by the bacteriostatic effect of the polyelectrolyte complex, which depends on the shell thickness and charge of its outmost layer, and involves the diffusion of unpaired amine sites through the shell. The lag times of growth are sufficient to prevent proliferation for daily topical applications.

Parametric Studies Of Lightweight Reflectors Supported On Linear Actuator Arrays

NASA Astrophysics Data System (ADS)

Seibert, George E.

1987-10-01

This paper presents the results of numerous design studies carried out at Perkin-Elmer in support of the design of large diameter controllable mirrors for use in laser beam control, surveillance, and astronomy programs. The results include relationships between actuator location and spacing and the associated degree of correctability attainable for a variety of faceplate configurations subjected to typical disturbance environments. Normalizations and design curves obtained from closed-form equations based on thin shallow shell theory and computer based finite-element analyses are presented for use in preliminary design estimates of actuator count, faceplate structural properties, system performance prediction and weight assessments. The results of the analyses were obtained from a very wide range of mirror configurations, including both continuous and segmented mirror geometries. Typically, the designs consisted of a thin facesheet controlled by point force actuators which in turn were mounted on a structurally efficient base panel, or "reaction structure". The faceplate materials considered were fused silica, ULE fused silica, Zerodur, aluminum and beryllium. Thin solid faceplates as well as rib-reinforced cross-sections were treated, with a wide variation in thickness and/or rib patterns. The magnitude and spatial frequency distribution of the residual or uncorrected errors were related to the input error functions for mirrors of many different diameters and focal ratios. The error functions include simple sphere-to-sphere corrections, "parabolization" of spheres, and higher spatial frequency input error maps ranging from 0.5 to 7.5 cycles per diameter. The parameter which dominates all of the results obtained to date, is a structural descriptor of thin shell behavior called the characteristic length. This parameter is a function of the shell's radius of curvature, thickness, and Poisson's ratio of the material used. The value of this constant, in itself, describes the extent to which the deflection under a point force is localized by the shell's curvature. The deflection shape is typically a near-gaussian "bump" with a zero-crossing at a local radius of approximately 3.5 characteristic lengths. The amplitude is a function of the shells elastic modulus, radius, and thickness, and is linearly proportional to the applied force. This basic shell behavior is well-treated in an excellent set of papers by Eric Reissner entitled "Stresses and Small Displacements of Shallow Spherical Shells".1'2 Building on the insight offered by these papers, we developed our design tools around two derived parameters, the ratio of the mirror's diameter to its characteristic length (D/l), and the ratio of the actuator spacing to the characteristic length (b/l). The D/1 ratio determines the "finiteness" of the shell, or its dependence on edge boundary conditions. For D/1 values greater than 10, the influence of edges is almost totally absent on interior behavior. The b/1 ratio, the basis of all our normalizations is the most universal term in the description of correctability or ratio of residual/input errors. The data presented in the paper, shows that the rms residual error divided by the peak amplitude of the input error function is related to the actuator spacing to characteristic length ratio by the following expression RMS Residual Error b 3.5 k (I) (1) Initial Error Ampl. The value of k ranges from approximately 0.001 for low spatial frequency initial errors up to 0.05 for higher error frequencies (e.g. 5 cycles/diameter). The studies also yielded insight to the forces required to produce typical corrections at both the center and edges of the mirror panels. Additionally, the data lends itself to rapid evaluation of the effects of trading faceplate weight for increased actuator count,

One-step formation of multiple emulsions in microfluidics.

PubMed

Abate, Adam R; Thiele, Julian; Weitz, David A

2011-01-21

We present a robust way to create multiple emulsions with controllable shell thicknesses that can vary over a wide range. We use a microfluidic device to create a coaxial jet of immiscible fluids; using a dripping instability, we break the jet into multiple emulsions. By controlling the thickness of each layer of the jet, we adjust the thicknesses of the shells of the multiple emulsions. The same method is also effective in creating monodisperse emulsions from fluids that cannot otherwise be controllably emulsified, such as, for example, viscoelastic fluids.

Core-shell-corona polymeric micelles as a versatile template for synthesis of inorganic hollow nanospheres.

PubMed

Sasidharan, Manickam; Nakashima, Kenichi

2014-01-21

Hollow, inorganic nanoscale capsules have many applications, from the delivery of encapsulated products for cosmetic and medicinal purposes to use as lightweight composite materials. Early methods for producing inorganic hollow nanospheres using hard templates suffered from low product yield and shell weakness upon template removal. In the past decade, researchers have turned to amphiphilic copolymers to synthesize hollow nanostructures and ordered mesoporous materials. Amphiphilic molecules self-assemble into well-defined nanostructures including spherical micelles. Micelles formed from simple, two-component AB diblock and ABA triblock copolymers, however, have been difficult to work with to construct inorganic hollow nanoparticles, because the corona of the micelle, which serves as the template for the shell, becomes unstable as it absorbs inorganic shell precursors, causing aggregates to form. Newly developed, three-component ABC triblock copolymers may solve this problem. They provide nanoassemblies with more diverse morphological and functional features than AB diblock and ABA triblock copolymers. Micelles formed from ABC triblock copolymers in selective solvents that dissolve only one or two of the blocks provide templates for these improved nanoassemblies. By manipulating individual polymer blocks, one can "encode" additional features at the molecular level. For instance, modifying the functional groups or substitution patterns of the blocks allows better morphological and size control. Insights into polymer self-assembly gained over years of work in our group have set the stage to systematically engineer inorganic spherical hollow nanoparticles using ABC triblock copolymers. In this Account, we report our recent progress in producing diverse, inorganic hollow spherical nanospheres from asymmetric triblock copolymeric micelles with core-shell-corona architecture as templates. We discuss three classes of polymeric micelles-with neutral, cationic, and anionic shell structures-that allow fabrication of a variety of hollow nanoparticles. Importantly, we synthesized all of these particles in water, avoiding use of hazardous organic solvents. We have designed the precursor of the inorganic material to be selectively sorbed into the shell domain, leaving the corona free from the inorganic precursors that would destabilize the micelle. The core, meanwhile, is the template for the formation of the hollow void. By rationally tailoring experimental parameters, we readily and selectively obtained a variety of hollow nanoparticles including silica, hybrid silicas, metal-oxides, metal-carbonates, metal-sulfates, metal-borates, and metal-phosphates. Finally, we highlight the state-of-the-art techniques we used to characterize these nanoparticles, and describe experiments that demonstrate the potential of these hollow particles in drug delivery, and as anode and cathode materials for lithium-ion batteries.

Radar attenuation in Europa's ice shell: obstacles and opportunities for constraining shell thickness and thermal structure

NASA Astrophysics Data System (ADS)

Kalousova, Klara; Schroeder, Dustin M.; Soderlund, Krista M.; Sotin, Christophe

2016-10-01

With its strikingly young surface and possibly recent endogenic activity, Europa is one of the most exciting bodies within our Solar System and a primary target for spacecraft exploration. Future missions to Europa are expected to carry ice penetrating radar instruments which are powerful tools to investigate the subsurface thermophysical structure of its ice shell.Several authors have addressed the 'penetration depth' of radar sounders at icy moons, however, the concept and calculation of a single value penetration depth is a potentially misleading simplification since it ignores the thermal and attenuation structure complexity of a realistic ice shell. Here we move beyond the concept of a single penetration depth by exploring the variation in two-way radar attenuation for a variety of potential thermal structures of Europa's ice shell as well as for a low loss and high loss temperature-dependent attenuation model. The possibility to detect brines is also investigated.Our results indicate that: (i) for all ice shell thicknesses investigated (5-30 km), a nominal satellite-borne radar sounder will penetrate between 15% and 100% of the total thickness, (ii) the maximum penetration depth strongly varies laterally with the deepest penetration possible through the cold downwellings, (iii) the direct detection of the ice/ocean interface might be possible for shells of up to 15 km if the radar signal travels through the cold downwelling, (iv) even if the ice/ocean interface is not detected, the penetration through most of the shell could constrain the deep shell structure through the loss of signal, and (v) for all plausible ice shells the two-way attenuation to the eutectic point is ≤30 dB which shows a robust potential for longitudinal investigation of the ice shell's shallow structure.Part of this work has been performed at the Jet Propulsion Laboratory, California Institute of Technology, under contract to NASA. K.K. acknowledges support by the Grant Agency of the Czech Republic through project 15-14263Y.

Enceladus' tidal dissipation revisited

NASA Astrophysics Data System (ADS)

Tobie, Gabriel; Behounkova, Marie; Choblet, Gael; Cadek, Ondrej; Soucek, Ondrej

2016-10-01

A series of chemical and physical evidence indicates that the intense activity at Enceladus' South Pole is related to a subsurface salty water reservoir underneath the tectonically active ice shell. The detection of a significant libration implies that this water reservoir is global and that the average ice shell thickness is about 20-25km (Thomas et al. 2016). The interpretation of gravity and topography data further predicts large variations in ice shell thickness, resulting in a shell potentially thinner than 5 km in the South Polar Terrain (SPT) (Cadek et al. 2016). Such an ice shell structure requires a very strong heat source in the interior, with a focusing mechanism at the SPT. Thermal diffusion through the ice shell implies that at least 25-30 GW is lost into space by passive diffusion, implying a very efficient dissipation mechanism in Enceladus' interior to maintain such an ocean/ice configuration thermally stable.In order to determine in which conditions such a large dissipation power may be generated, we model the tidal response of Enceladus including variable ice shell thickness. For the rock core, we consider a wide range of rheological parameters representative of water-saturated porous rock materials. We demonstrate that the thinning toward the South Pole leads to a strong increase in heat production in the ice shell, with a optimal thickness obtained between 1.5 and 3 km, depending on the assumed ice viscosity. Our results imply that the heat production in the ice shell within the SPT may be sufficient to counterbalance the heat loss by diffusion and to power eruption activity. However, outside the SPT, a strong dissipation in the porous core is required to counterbalance the diffusive heat loss. We show that about 20 GW can be generated in the core, for an effective viscosity of 1012 Pa.s, which is comparable to the effective viscosity estimated in water-saturated glacial tills on Earth. We will discuss the implications of this revisited tidal budget for the activity of Enceladus and the long-term evolution of its interior.

Plume Activity and Tidal Deformation on Enceladus Influenced by Faults and Variable Ice Shell Thickness

NASA Astrophysics Data System (ADS)

Běhounková, Marie; Souček, Ondřej; Hron, Jaroslav; Čadek, Ondřej

2017-09-01

We investigated the effect of variations in ice shell thickness and of the tiger stripe fractures crossing Enceladus' south polar terrain on the moon's tidal deformation by performing finite element calculations in three-dimensional geometry. The combination of thinning in the polar region and the presence of faults has a synergistic effect that leads to an increase of both the displacement and stress in the south polar terrain by an order of magnitude compared to that of the traditional model with a uniform shell thickness and without faults. Assuming a simplified conductive heat transfer and neglecting the heat sources below the ice shell, we computed the global heat budget of the ice shell. For the inelastic properties of the shell described by a Maxwell viscoelastic model, we show that unrealistically low average viscosity of the order of 10^{13} Pa s is necessary for preserving the volume of the ocean, suggesting the important role of the heat sources in the deep interior. Similarly, low viscosity is required to predict the observed delay of the plume activity, which hints at other delaying mechanisms than just the viscoelasticity of the ice shell. The presence of faults results in large spatial and temporal heterogeneity of geysering activity compared to the traditional models without faults. Our model contributes to understanding the physical mechanisms that control the fault activity, and it provides potentially useful information for future missions that will sample the plume for evidence of life.

The NIF x-ray spectrometer calibration campaign at Omega.

PubMed

Pérez, F; Kemp, G E; Regan, S P; Barrios, M A; Pino, J; Scott, H; Ayers, S; Chen, H; Emig, J; Colvin, J D; Bedzyk, M; Shoup, M J; Agliata, A; Yaakobi, B; Marshall, F J; Hamilton, R A; Jaquez, J; Farrell, M; Nikroo, A; Fournier, K B

2014-11-01

The calibration campaign of the National Ignition Facility X-ray Spectrometer (NXS) was carried out at the Omega laser facility. Spherically symmetric, laser-driven, millimeter-scale x-ray sources of K-shell and L-shell emission from various mid-Z elements were designed for the 2-18 keV energy range of the NXS. The absolute spectral brightness was measured by two calibrated spectrometers. We compare the measured performance of the target design to radiation hydrodynamics simulations.

Properties of surfactant films in water-in-CO2 microemulsions obtained by small-angle neutron scattering.

PubMed

Yan, Ci; Sagisaka, Masanobu; James, Craig; Rogers, Sarah; Alexander, Shirin; Eastoe, Julian

2014-12-01

The formation, stability and structural properties of normal liquid phase microemulsions, stabilized by hydrocarbon surfactants, comprising water and hydrocarbon oils can be interpreted in terms of the film bending rigidity (energy) model. Here, this model is tested for unusual water-in-CO2 (w/c) microemulsions, formed at high pressure with supercritical CO2 (sc-CO2) as a solvent and fluorinated surfactants as stabilizers. Hence, it is possible to explore the generality of this model for other types of microemulsions. High Pressure Small-Angle Neutron Scattering (HP-SANS) has been used to study w/c microemulsions, using contrast variation to highlight scattering from the stabilizing fluorinated surfactant films: these data show clear evidence for spherical core-shell structures for the microemulsion droplets. The results extend understanding of w/c microemulsions since previous SANS studies are based only on scattering from water core droplets. Here, detailed structural parameters for the surfactant films, such as thickness and film bending energy, have been extracted from the core-shell SANS profiles revealed by controlled contrast variation. Furthermore, at reduced CO2 densities (∼0.7gcm(-3)), elongated cylindrical droplet structures have been observed, which are uncommon for CO2 microemulsions/emulsions. The implications of the presence of cylindrical micelles and droplets for applications of CO2, and viscosity enhancements are discussed. Copyright © 2014 Elsevier Inc. All rights reserved.

Temperature tunable micellization of polystyrene-block-poly(2-vinylpyridine) at Si-ionic liquid interface.

PubMed

Lu, Haiyun; Lee, Dong Hyun; Russell, Thomas P

2010-11-16

Highly ordered and stable micelles formed from both symmetric and asymmetric block copolymers of polystyrene-block-poly(2-vinylpyridine) (PS-b-P2VP) at the Si-ionic liquid (IL) interface have been investigated by scanning force microscopy (SFM) and transmission electron microscopy (TEM). The 1-butyl-3-methylimidazolium trifluoromethanesulfonate IL, a selective and temperature-tunable solvent for the P2VP block, was used and gave rise to block copolymer micelles having different morphologies that strongly depended on the annealing temperature. The effects of film thickness, molecular weight of block copolymers, and experimental conditions, such as preannealing, rinsing, and substrate properties, on the morphologies of block copolymer micelles were also studied. In addition, spherical micelles consisting of PS core and P2VP shell could also be obtained by core-corona inversion by annealing the as-coated micellar film in the IL at high temperatures. The possible mechanism for micelle formation is discussed.

Molecularly imprinted silica-silver nanowires for tryptophan recognition

NASA Astrophysics Data System (ADS)

Díaz-Faes López, T.; Díaz-García, M. E.; Badía-Laíño, R.

2014-10-01

We report on silver nanowires (AgNWs) coated with molecularly imprinted silica (MIP SiO2) for recognition of tryptophan (Trp). The use of AgNWs as a template confers an imprinted material with adequate mechanical strength and with a capability of recognizing Trp due to its nanomorphology when compared to spherical microparticles with a similar surface-to-volume ratio. Studies on adsorption isotherms showed the MIP-SiO2-AgNWs to exhibit homogeneous affinity sites with narrow affinity distribution. This suggests that the synthesized material behaves as a 1D nanomaterial with a large area and small thickness with very similar affinity sites. Trp release from MIP-SiO2-AgNWs was demonstrated to be dominated by the diffusion rate of Trp as controlled by the specific interactions with the imprinted silica shell. Considering these results and the lack of toxicity of silica sol-gel materials, the material offers potential in the field of drug or pharmaceutical controlled delivery, but also in optoelectronic devices, electrodes and sensors.

Luminosity distance in ``Swiss cheese'' cosmology with randomized voids. II. Magnification probability distributions

NASA Astrophysics Data System (ADS)

Flanagan, Éanna É.; Kumar, Naresh; Wasserman, Ira; Vanderveld, R. Ali

2012-01-01

We study the fluctuations in luminosity distances due to gravitational lensing by large scale (≳35Mpc) structures, specifically voids and sheets. We use a simplified “Swiss cheese” model consisting of a ΛCDM Friedman-Robertson-Walker background in which a number of randomly distributed nonoverlapping spherical regions are replaced by mass-compensating comoving voids, each with a uniform density interior and a thin shell of matter on the surface. We compute the distribution of magnitude shifts using a variant of the method of Holz and Wald , which includes the effect of lensing shear. The standard deviation of this distribution is ˜0.027 magnitudes and the mean is ˜0.003 magnitudes for voids of radius 35 Mpc, sources at redshift zs=1.0, with the voids chosen so that 90% of the mass is on the shell today. The standard deviation varies from 0.005 to 0.06 magnitudes as we vary the void size, source redshift, and fraction of mass on the shells today. If the shell walls are given a finite thickness of ˜1Mpc, the standard deviation is reduced to ˜0.013 magnitudes. This standard deviation due to voids is a factor ˜3 smaller than that due to galaxy scale structures. We summarize our results in terms of a fitting formula that is accurate to ˜20%, and also build a simplified analytic model that reproduces our results to within ˜30%. Our model also allows us to explore the domain of validity of weak-lensing theory for voids. We find that for 35 Mpc voids, corrections to the dispersion due to lens-lens coupling are of order ˜4%, and corrections due to shear are ˜3%. Finally, we estimate the bias due to source-lens clustering in our model to be negligible.

Cement hydration from hours to centuries controlled by diffusion through barrier shells of C-S-H

NASA Astrophysics Data System (ADS)

Rahimi-Aghdam, Saeed; Bažant, Zdeněk P.; Abdolhosseini Qomi, M. J.

2017-02-01

Although a few good models for cement hydration exist, they have some limitations. Some do not take into account the complete range of variation of pore relative humidity and temperature, and apply over durations limited from up a few months to up to about a year. The ones that are applicable for long durations are either computationally too intensive for use in finite element programs or predict the hydration to terminate after few months. However, recent tests of autogenous shrinkage and swelling in water imply that the hydration may continue, at decaying rate, for decades, provided that a not too low relative pore humidity (above 0.7) persists for a long time, as expected for the cores of thick concrete structural members. Therefore, and because design lifetimes of over hundred years are required for large concrete structures, a new hydration model for a hundred year lifespan and beyond is developed. The new model considers that, after the first day of hydration, the remnants of anhydrous cement grains, gradually consumed by hydration, are enveloped by contiguous, gradually thickening, spherical barrier shells of calcium-silicate hydrate (C-S-H). The hydration progress is controlled by transport of water from capillary pores through the barrier shells toward the interface with anhydrous cement. The transport is driven by a difference of humidity, defined by equivalence with the difference in chemical potential of water. Although, during the period of 4-24 h, the C-S-H forms discontinuous nano-globules around the cement grain, an equivalent barrier shell control was formulated for this period, too, for ease and effectiveness of calculation. The entire model is calibrated and validated by published test data on the evolution of hydration degree for various cement types, particle size distributions, water-cement ratios and temperatures. Computationally, this model is sufficiently effective for calculating the evolution of hydration degree (or aging) at every integration point of every finite element in a large structure.

Iceberg Scour and Shell Damage in the Antarctic Bivalve Laternula elliptica

PubMed Central

Harper, Elizabeth M.; Clark, Melody S.; Hoffman, Joseph I.; Philipp, Eva E. R.; Peck, Lloyd S.; Morley, Simon A.

2012-01-01

We document differences in shell damage and shell thickness in a bivalve mollusc (Laternula elliptica) from seven sites around Antarctica with differing exposures to ice movement. These range from 60% of the sea bed impacted by ice per year (Hangar Cove, Antarctic Peninsula) to those protected by virtually permanent sea ice cover (McMurdo Sound). Patterns of shell damage consistent with blunt force trauma were observed in populations where ice scour frequently occurs; damage repair frequencies and the thickness of shells correlated positively with the frequency of iceberg scour at the different sites with the highest repair rates and thicker shells at Hangar Cove (74.2% of animals damaged) compared to the other less impacted sites (less than 10% at McMurdo Sound). Genetic analysis of population structure using Amplified Fragment Length Polymorphisms (AFLPs) revealed no genetic differences between the two sites showing the greatest difference in shell morphology and repair rates. Taken together, our results suggest that L. elliptica exhibits considerable phenotypic plasticity in response to geographic variation in physical disturbance. PMID:23029484

Control of the shell structural properties and cavity diameter of hollow magnesium fluoride particles.

PubMed

Nandiyanto, Asep Bayu Dani; Ogi, Takashi; Okuyama, Kikuo

2014-03-26

Control of the shell structural properties [i.e., thickness (8-25 nm) and morphology (dense and raspberry)] and cavity diameter (100-350 nm) of hollow particles was investigated experimentally, and the results were qualitatively explained based on the available theory. We found that the selective deposition size and formation of the shell component on the surface of a core template played important roles in controlling the structure of the resulting shell. To achieve the selective deposition size and formation of the shell component, various process parameters (i.e., reaction temperature and charge, size, and composition of the core template and shell components) were tested. Magnesium fluoride (MgF2) and polystyrene spheres were used as models for shell and core components, respectively. MgF2 was selected because, to the best of our knowledge, the current reported approaches to date were limited to synthesis of MgF2 in film and particle forms only. Therefore, understanding how to control the formation of MgF2 with various structures (both the thickness and morphology) is a prospective for advanced lens synthesis and applications.

Wideband and multi-frequency infrared cloaking of spherical objects by using the graphene-based metasurface.

PubMed

Shokati, Elnaz; Granpayeh, Nosrat; Danaeifar, Mohammad

2017-04-10

The ultrathin graphene metasurface is proposed as a mantle cloak to achieve wideband tunable scattering reduction around the spherical (three-dimensional) objects. The cloaking shell over the metallic or dielectric sphere is structured by a periodic array of graphene nanodisks that operate at infrared frequencies. By using the polarizability of the graphene nanodisks and equivalent conductivity method, the metasurface reactance is obtained. To achieve the cloaking shell for both dielectric and conducting spheres, the metasurface reactance as a function of nanodisks dimensions, graphene's Fermi energy, and permittivity of the surrounding areas can be tuned from the inductive to capacitive situation. Inhomogeneous metasurfaces including graphene nanodisks with different radii provide wideband invisibility due to extra resonances. We could significantly increase the 3-dB bandwidth more than the homogenous case by simpler realistic designs compared to the multi-layer structures. The analytical results are confirmed with full-wave numerical simulations.

Quantification of Processing Effects on Filament Wound Pressure Vessels

NASA Technical Reports Server (NTRS)

Aiello, Robert A.; Chamis, Christos C.

1999-01-01

A computational simulation procedure is described which is designed specifically for the modeling and analysis of filament wound pressure vessels. Cylindrical vessels with spherical or elliptical end caps can be generated automatically. End caps other than spherical or elliptical may be modeled by varying circular sections along the x-axis according to the C C! end cap shape. The finite element model generated is composed of plate type quadrilateral shell elements on the entire vessel surface. This computational procedure can also be sued to generate grid, connectivity and material cards (bulk data) for component parts of a larger model. These bulk data are assigned to a user designated file for finite element structural/stress analysis of composite pressure vessels. The procedure accommodates filament would pressure vessels of all types of shells-of-revolution. It has provisions to readily evaluate initial stresses due to pretension in the winding filaments and residual stresses due to cure temperature.

Quantification of Processing Effects on Filament Wound Pressure Vessels. Revision

NASA Technical Reports Server (NTRS)

Aiello, Robert A.; Chamis, Christos C.

2002-01-01

A computational simulation procedure is described which is designed specifically for the modeling and analysis of filament wound pressure vessels. Cylindrical vessels with spherical or elliptical end caps can be generated automatically. End caps other than spherical or elliptical may be modeled by varying circular sections along the x-axis according to the end cap shape. The finite element model generated is composed of plate type quadrilateral shell elements on the entire vessel surface. This computational procedure can also be used to generate grid, connectivity and material cards (bulk data) for component parts of a larger model. These bulk data are assigned to a user designated file for finite element structural/stress analysis of composite pressure vessels. The procedure accommodates filament wound pressure vessels of all types of shells-of -revolution. It has provisions to readily evaluate initial stresses due to pretension in the winding filaments and residual stresses due to cure temperature.

Mirror mount

DOEpatents

Humpal, Harold H.

1987-01-01

A mirror mount (10) is provided that allows free pitch, yaw and roll motion of the mirror (28) while keeping the location of a point (56) on the surface of the mirror (28) fixed in the rest frame of reference of the mount (10). Yaw movement is provided by two yaw cylinders (30,32) that are bearing (52) mounted to provide rotation. Pitch and roll motion is provided by a spherically annular shell (42) that is air bearing (72,74) mounted to move between a clamp (60) and an upper pedestal bearing (44). The centers of curvature of the spherical surfaces of the shell (42) lie upon the point (56). Pitch motion and roll motion are separately and independently imparted to mirror (28) by a pair of pitch paddles (34) and a pair of roll paddles (36) that are independently and separately moved by control rods (76,80) driven by motors (78,82).

Wide-range tuning of the surface plasmon resonance of silver/gold core shell and alloyed nanoparticles

NASA Astrophysics Data System (ADS)

Hubenthal, Frank; Ziegler, Torsten; Hendrich, Christian; Träger, Frank

2004-03-01

For many applications like surface enhanced Raman scattering in which the optical field enhancement associated with surface plasmon excitation is exploited, tunability of this collective resonance over a wide range is required. For this purpose we have prepared Ag/Au core shell and Ag/Au alloyed nanoparticles with different shell thicknesses and different percentages of the two metals. The nanoparticles were made by subsequent deposition of Ag and Au atoms on dielectric substrates followed by diffusion and nucleation or heat treatment. Depending on the Au shell thickness the plasmon frequency can be tuned, e.g. from 2.8 eV (442 nm) to 2.1 eV (590 nm). Annealing of the core-shell nanoparticles causes a shift of the resonance frequency to 2.6 eV. Theoretical modelling allows us to attribute this observation to the production of alloyed nanoparticles. Possible application of the Ag/Au nanoparticles will be discussed.

Fabrication, Characterization and Cytotoxicity of Spherical-Shaped Conjugated Gold-Cockle Shell Derived Calcium Carbonate Nanoparticles for Biomedical Applications

NASA Astrophysics Data System (ADS)

Kiranda, Hanan Karimah; Mahmud, Rozi; Abubakar, Danmaigoro; Zakaria, Zuki Abubakar

2018-01-01

The evolution of nanomaterial in science has brought about a growing increase in nanotechnology, biomedicine, and engineering fields. This study was aimed at fabrication and characterization of conjugated gold-cockle shell-derived calcium carbonate nanoparticles (Au-CSCaCO3NPs) for biomedical application. The synthetic technique employed used gold nanoparticle citrate reduction method and a simple precipitation method coupled with mechanical use of a Programmable roller-ball mill. The synthesized conjugated nanomaterial was characterized for its physicochemical properties using transmission electron microscope (TEM), field emission scanning electron microscope (FESEM) equipped with energy dispersive X-ray (EDX) and Fourier transform infrared spectroscopy (FTIR). However, the intricacy of cellular mechanisms can prove challenging for nanomaterial like Au-CSCaCO3NPs and thus, the need for cytotoxicity assessment. The obtained spherical-shaped nanoparticles (light-green purplish) have an average diameter size of 35 ± 16 nm, high carbon and oxygen composition. The conjugated nanomaterial, also possesses a unique spectra for aragonite polymorph and carboxylic bond significantly supporting interactions between conjugated nanoparticles. The negative surface charge and spectra absorbance highlighted their stability. The resultant spherical shaped conjugated Au-CSCaCO3NPs could be a great nanomaterial for biomedical applications.

Electromagnetic δ -function sphere

NASA Astrophysics Data System (ADS)

Parashar, Prachi; Milton, Kimball A.; Shajesh, K. V.; Brevik, Iver

2017-10-01

We develop a formalism to extend our previous work on the electromagnetic δ -function plates to a spherical surface. The electric (λe) and magnetic (λg) couplings to the surface are through δ -function potentials defining the dielectric permittivity and the diamagnetic permeability, with two anisotropic coupling tensors. The formalism incorporates dispersion. The electromagnetic Green's dyadic breaks up into transverse electric and transverse magnetic parts. We derive the Casimir interaction energy between two concentric δ -function spheres in this formalism and show that it has the correct asymptotic flat-plate limit. We systematically derive expressions for the Casimir self-energy and the total stress on a spherical shell using a δ -function potential, properly regulated by temporal and spatial point splitting, which are different from the conventional temporal point splitting. In the strong-coupling limit, we recover the usual result for the perfectly conducting spherical shell but in addition there is an integrated curvature-squared divergent contribution. For finite coupling, there are additional divergent contributions; in particular, there is a familiar logarithmic divergence occurring in the third order of the uniform asymptotic expansion that renders it impossible to extract a unique finite energy except in the case of an isorefractive sphere, which translates into λg=-λe.

Dynamos in asymptotic-giant-branch stars as the origin of magnetic fields shaping planetary nebulae.

PubMed

Blackman, E G; Frank, A; Markiel, J A; Thomas, J H; Van Horn, H M

2001-01-25

Planetary nebulae are thought to be formed when a slow wind from the progenitor giant star is overtaken by a subsequent fast wind generated as the star enters its white dwarf stage. A shock forms near the boundary between the winds, creating the relatively dense shell characteristic of a planetary nebula. A spherically symmetric wind will produce a spherically symmetric shell, yet over half of known planetary nebulae are not spherical; rather, they are elliptical or bipolar in shape. A magnetic field could launch and collimate a bipolar outflow, but the origin of such a field has hitherto been unclear, and some previous work has even suggested that a field could not be generated. Here we show that an asymptotic-giant-branch (AGB) star can indeed generate a strong magnetic field, having as its origin a dynamo at the interface between the rapidly rotating core and the more slowly rotating envelope of the star. The fields are strong enough to shape the bipolar outflows that produce the observed bipolar planetary nebulae. Magnetic braking of the stellar core during this process may also explain the puzzlingly slow rotation of most white dwarf stars.

Compact Q-balls and Q-shells in a scalar electrodynamics

DOE Office of Scientific and Technical Information (OSTI.GOV)

Arodz, H.; Lis, J.

2009-02-15

We investigate spherically symmetric nontopological solitons in electrodynamics with a scalar field self-interaction U{approx}|{psi}| taken from the complex signum-Gordon model. We find Q-balls for small absolute values of the total electric charge Q, and Q-shells when |Q| is large enough. In both cases the charge density exactly vanishes outside certain compact regions in the three-dimensional space. The dependence of the total energy E of small Q-balls on the total electric charge has the form E{approx}|Q|{sup 5/6}, while in the case of very large Q-shells, E{approx}|Q|{sup 7/6}.

Greenhouse effect: temperature of a metal sphere surrounded by a glass shell and heated by sunlight

NASA Astrophysics Data System (ADS)

Nguyen, Phuc H.; Matzner, Richard A.

2012-01-01

We study the greenhouse effect on a model satellite consisting of a tungsten sphere surrounded by a thin spherical, concentric glass shell, with a small gap between the sphere and the shell. The system sits in vacuum and is heated by sunlight incident along the z-axis. This development is a generalization of the simple treatment of the greenhouse effect given by Kittel and Kroemer (1980 Thermal Physics (San Francisco: Freeman)) and can serve as a very simple model demonstrating the much more complex Earth greenhouse effect. Solution of the model problem provides an excellent pedagogical tool at the Junior/Senior undergraduate level.

Multiwalled carbon nanotube monoliths prepared by spark plasma sintering (SPS) and their mechanical properties.

PubMed

Uo, Motohiro; Hasegawa, Tomoka; Akasaka, Tsukasa; Tanaka, Isao; Munekane, Fuminori; Omori, Mamoru; Kimura, Hisamichi; Nakatomi, Reiko; Soga, Kohei; Kogo, Yasuo; Watari, Fumio

2009-01-01

Three types of multiwalled carbon nanotube (MWCNT) monoliths without any binders were obtained by spark plasma sintering (SPS) treatment at 2000 degrees C under 80 MPa sintering pressure. Three MWCNTs with different diameters: thin (slashed circle20-30 nm, CNT Co., Ltd., Korea), thick (slashed circle100 nm, Nano Carbon Technologies Co., Ltd., Japan) and spherical thin (slashed circle20-30 nm, granulated diameter = 1-3 microm, Shimizu Corporation, Japan) were employed for SPS. SEM observation confirmed that these materials maintained the nanosized tube microstructure of raw CNT powder after SPS treatment. The densest monolith was prepared with the spherical MWCNTs. The mechanical properties of this material were estimated by the dynamic hardness test. The elastic modulus of the monolith did not depend on the difference of MWCNTs, but the hardness of spherical MWCNTs was higher than that of thick MWCNTs. The high density and hardness of the spherical MWCNTs were caused by the high packing density during the SPS process because of its spherical granulation. Thus, the spherical MWCNTs were most useful for the MWCNT monolith preparation with the SPS process and its application as a bone substitute material and a bone tissue engineering scaffold material was suggested.

Design and Analysis of Tow-Steered Composite Shells Using Fiber Placement

NASA Technical Reports Server (NTRS)

Wu, K. Chauncey

2008-01-01

In this study, a sub-scale advanced composite shell design is evaluated to determine its potential for use on a future aircraft fuselage. Two composite shells with the same nominal 8-ply [+/-45/+/-Theta](sub s) layup are evaluated, where Theta indicates a tow-steered ply. To build this shell, a fiber placement machine would be used to steer unidirectional prepreg tows as they are placed around the circumference of a 17-inch diameter right circular cylinder. The fiber orientation angle varies continuously from 10 degrees (with respect to the shell axis of revolution) at the crown, to 45 degrees on the side, and back to 10 degrees on the keel. All 24 tows are placed at each point on every fiber path in one structure designated as the shell with overlaps. The resulting pattern of tow overlaps causes the laminate thickness to vary between 8 and 16 plies. The second shell without tow overlaps uses the capability of the fiber placement machine to cut and add tows at any point along the fiber paths to fabricate a shell with a nearly uniform 8-ply laminate thickness. Issues encountered during the design and analysis of these shells are presented and discussed. Static stiffness and buckling loads of shells with tow-steered layups are compared with the performance of a baseline quasi-isotropic shell using both finite element analyses and classical strength of materials theory.

Polystyrene Core-Silica Shell Particles with Defined Nanoarchitectures as a Versatile Platform for Suspension Array Technology.

PubMed

Sarma, Dominik; Gawlitza, Kornelia; Rurack, Knut

2016-04-19

The need for rapid and high-throughput screening in analytical laboratories has led to significant growth in interest in suspension array technologies (SATs), especially with regard to cytometric assays targeting a low to medium number of analytes. Such SAT or bead-based assays rely on spherical objects that constitute the analytical platform. Usually, functionalized polymer or silica (SiO2) microbeads are used which each have distinct advantages and drawbacks. In this paper, we present a straightforward synthetic route to highly monodisperse SiO2-coated polystyrene core-shell (CS) beads for SAT with controllable architectures from smooth to raspberry- and multilayer-like shells by varying the molecular weight of poly(vinylpyrrolidone) (PVP), which was used as the stabilizer of the cores. The combination of both organic polymer core and a structurally controlled inorganic SiO2 shell in one hybrid particle holds great promises for flexible next-generation design of the spherical platform. The particles were characterized by electron microscopy (SEM, T-SEM, and TEM), thermogravimetry, flow cytometry, and nitrogen adsorption/desorption, offering comprehensive information on the composition, size, structure, and surface area. All particles show ideal cytometric detection patterns and facile handling due to the hybrid structure. The beads are endowed with straightforward modification possibilities through the defined SiO2 shells. We successfully implemented the particles in fluorometric SAT model assays, illustrating the benefits of tailored surface area which is readily available for small-molecule anchoring. Very promising assay performance was shown for DNA hybridization assays with quantification limits down to 8 fmol.

STEAM STIRRED HOMOGENEOUS NUCLEAR REACTOR

DOEpatents

Busey, H.M.

1958-06-01

A homogeneous nuclear reactor utilizing a selfcirculating liquid fuel is described. The reactor vessel is in the form of a vertically disposed tubular member having the lower end closed by the tube walls and the upper end closed by a removal fianged assembly. A spherical reaction shell is located in the lower end of the vessel and spaced from the inside walls. The reaction shell is perforated on its lower surface and is provided with a bundle of small-diameter tubes extending vertically upward from its top central portion. The reactor vessel is surrounded in the region of the reaction shell by a neutron reflector. The liquid fuel, which may be a solution of enriched uranyl sulfate in ordinary or heavy water, is mainiained at a level within the reactor vessel of approximately the top of the tubes. The heat of the reaction which is created in the critical region within the spherical reaction shell forms steam bubbles which more upwardly through the tubes. The upward movement of these bubbles results in the forcing of the liquid fuel out of the top of these tubes, from where the fuel passes downwardly in the space between the tubes and the vessel wall where it is cooled by heat exchangers. The fuel then re-enters the critical region in the reaction shell through the perforations in the bottom. The upper portion of the reactor vessel is provided with baffles to prevent the liquid fuel from splashing into this region which is also provided with a recombiner apparatus for recombining the radiolytically dissociated moderator vapor and a control means.

Full-Color Biomimetic Photonic Materials with Iridescent and Non-Iridescent Structural Colors

PubMed Central

Kawamura, Ayaka; Kohri, Michinari; Morimoto, Gen; Nannichi, Yuri; Taniguchi, Tatsuo; Kishikawa, Keiki

2016-01-01

The beautiful structural colors in bird feathers are some of the brightest colors in nature, and some of these colors are created by arrays of melanin granules that act as both structural colors and scattering absorbers. Inspired by the color of bird feathers, high-visibility structural colors have been created by altering four variables: size, blackness, refractive index, and arrangement of the nano-elements. To control these four variables, we developed a facile method for the preparation of biomimetic core-shell particles with melanin-like polydopamine (PDA) shell layers. The size of the core-shell particles was controlled by adjusting the core polystyrene (PSt) particles’ diameter and the PDA shell thicknesses. The blackness and refractive index of the colloidal particles could be adjusted by controlling the thickness of the PDA shell. The arrangement of the particles was controlled by adjusting the surface roughness of the core-shell particles. This method enabled the production of both iridescent and non-iridescent structural colors from only one component. This simple and novel process of using core-shell particles containing PDA shell layers can be used in basic research on structural colors in nature and their practical applications. PMID:27658446

The oil palm Shell gene controls oil yield and encodes a homologue of SEEDSTICK

PubMed Central

Singh, Rajinder; Leslie Low, Eng-Ti; Ooi, Leslie Cheng-Li; Ong-Abdullah, Meilina; Chin, Ting Ngoot; Nagappan, Jayanthi; Nookiah, Rajanaidu; Amiruddin, Mohd Din; Rosli, Rozana; Abdul Manaf, Mohamad Arif; Chan, Kuang-Lim; Halim, Mohd Amin; Azizi, Norazah; Lakey, Nathan; Smith, Steven W; Budiman, Muhammad A; Hogan, Michael; Bacher, Blaire; Van Brunt, Andrew; Wang, Chunyan; Ordway, Jared M; Sambanthamurthi, Ravigadevi; Martienssen, Robert A

2014-01-01

A key event in the domestication and breeding of the oil palm, Elaeis guineensis, was loss of the thick coconut-like shell surrounding the kernel. Modern E. guineensis has three fruit forms, dura (thick-shelled), pisifera (shell-less) and tenera (thin-shelled), a hybrid between dura and pisifera1–4. The pisifera palm is usually female-sterile but the tenera yields far more oil than dura, and is the basis for commercial palm oil production in all of Southeast Asia5. Here, we describe the mapping and identification of the Shell gene responsible for the different fruit forms. Using homozygosity mapping by sequencing we found two independent mutations in the DNA binding domain of a homologue of the MADS-box gene SEEDSTICK (STK) which controls ovule identity and seed development in Arabidopsis. The Shell gene is responsible for the tenera phenotype in both cultivated and wild palms from sub-Saharan Africa, and our findings provide a genetic explanation for the single gene heterosis attributed to Shell, via heterodimerization. This gene mutation explains the single most important economic trait in oil palm, and has implications for the competing interests of global edible oil production, biofuels and rainforest conservation6. PMID:23883930

Study of the effect of varying core diameter, shell thickness and strain velocity on the tensile properties of single crystals of Cu-Ag core-shell nanowire using molecular dynamics simulations

NASA Astrophysics Data System (ADS)

Sarkar, Jit; Das, D. K.

2018-01-01

Core-shell type nanostructures show exceptional properties due to their unique structure having a central solid core of one type and an outer thin shell of another type which draw immense attention among researchers. In this study, molecular dynamics simulations are carried out on single crystals of copper-silver core-shell nanowires having wire diameter ranging from 9 to 30 nm with varying core diameter, shell thickness, and strain velocity. The tensile properties like yield strength, ultimate tensile strength, and Young's modulus are studied and correlated by varying one parameter at a time and keeping the other two parameters constant. The results obtained for a fixed wire size and different strain velocities were extrapolated to calculate the tensile properties like yield strength and Young's modulus at standard strain rate of 1 mm/min. The results show ultra-high tensile properties of copper-silver core-shell nanowires, several times than that of bulk copper and silver. These copper-silver core-shell nanowires can be used as a reinforcing agent in bulk metal matrix for developing ultra-high strength nanocomposites.

Full-Color Biomimetic Photonic Materials with Iridescent and Non-Iridescent Structural Colors.

PubMed

Kawamura, Ayaka; Kohri, Michinari; Morimoto, Gen; Nannichi, Yuri; Taniguchi, Tatsuo; Kishikawa, Keiki

2016-09-23

The beautiful structural colors in bird feathers are some of the brightest colors in nature, and some of these colors are created by arrays of melanin granules that act as both structural colors and scattering absorbers. Inspired by the color of bird feathers, high-visibility structural colors have been created by altering four variables: size, blackness, refractive index, and arrangement of the nano-elements. To control these four variables, we developed a facile method for the preparation of biomimetic core-shell particles with melanin-like polydopamine (PDA) shell layers. The size of the core-shell particles was controlled by adjusting the core polystyrene (PSt) particles' diameter and the PDA shell thicknesses. The blackness and refractive index of the colloidal particles could be adjusted by controlling the thickness of the PDA shell. The arrangement of the particles was controlled by adjusting the surface roughness of the core-shell particles. This method enabled the production of both iridescent and non-iridescent structural colors from only one component. This simple and novel process of using core-shell particles containing PDA shell layers can be used in basic research on structural colors in nature and their practical applications.

Effects of convergent diffusion and charge transfer kinetics on the diffusion layer thickness of spherical micro- and nanoelectrodes.

PubMed

Molina, A; Laborda, E; González, J; Compton, R G

2013-05-21

Nuances of the linear diffusion layer approximation are examined for slow charge transfer reactions at (hemi)spherical micro- and nanoelectrodes. This approximation is widely employed in Electrochemistry to evaluate the extent of electrolyte solution perturbed by the electrode process, which is essential to the understanding of the effects arising from thin-layer diffusion, convergent diffusion, convection, coupled chemical reactions and the double layer. The concept was well established for fast charge transfer processes at macroelectrodes, but remains unclear under other conditions such that a thorough assessment of its meaning was necessary. In a previous publication [A. Molina, J. González, E. Laborda and R. G. Compton, Phys. Chem. Chem. Phys., 2013, 15, 2381-2388] we shed some light on the influence of the reversibility degree. In the present work, the meaning of the diffusion layer thickness is investigated when very small electrodes are employed and so the contribution of convergent diffusion to the mass transport is very important. An analytical expression is given to calculate the linear diffusion layer thickness at (hemi)spherical electrodes and its behaviour is studied for a wide range of conditions of reversibility (from reversible to fully-irreversible processes) and electrode size (from macro- to nano-electrodes). Rigorous analytical solutions are deduced for true concentration profiles, surface concentrations, linear diffusion layer thickness and current densities when a potential pulse is applied at (hemi)spherical electrodes. The expressions for the magnitudes mentioned above are valid for electrodes of any size (including (hemi)spherical nanoelectrodes) and for any degree of reversibility, provided that mass transport occurs exclusively via diffusion. The variation of the above with the electrode size, applied potential and charge transfer kinetics is studied.

Proton-neutron sdg boson model and spherical-deformed phase transition

NASA Astrophysics Data System (ADS)

Otsuka, Takaharu; Sugita, Michiaki

1988-12-01

The spherical-deformed phase transition in nuclei is described in terms of the proton-neutron sdg interacting boson model. The sdg hamiltonian is introduced to model the pairing+quadrupole interaction. The phase transition is reproduced in this framework as a function of the boson number in the Sm isotopes, while all parameters in the hamiltonian are kept constant at values reasonable from the shell-model point of view. The sd IBM is derived from this model through the renormalization of g-boson effects.