[Effects of thinning on Calligonum arborescens growth and soil water-salt distribution in Tarim Desert Highway shelterbelt, Xinjiang of Northwest China].

PubMed

Zhang, Jian-Guo; Li, Ying-Gang; Xu, Xin-Wen; Lei, Jia-Qiang; Li, Sheng-Yu

2012-09-01

In order to understand the effects of thinning on the growth of Calligonum arborescens and the soil water-salt distribution in Tarim Desert Highway shelterbelt, a thinning experiment was conducted on an aged and declined C. arborescens woodland in a demonstration section of the shelterbelt, with the growth of C. arborescens and the soil water-salt distribution monitored. Thinning had no effects on the phenophase of C. arborescens, but after thinning, the growth of the current year plant height, crown width, ground diameter, and new branch length of reserved trees was larger than that of the control, and the increment was in the order of planting space 2 mx 1 m > 1 m x 1 m > the control, with significant differences among the treatments. The assimilation branch surface area in treatments 2 mx 1 m and 1 m x 1 m were 5.97 m2 and 5.22 m2 per plant, respectively, being significantly larger than the control (3.1 m2 per plant). The soil moisture content in 0-160 cm layer was significantly higher in treatments 2 m x 1 m and 1 mx 1 m than in the control, and increased obviously with thinning intensity. The soil salt content was in the order of control > planting space 1 m x 1 m > 2 m x 1 m, and the differences among the treatments were significant. It was suggested that the best reserved plant density after thinning was planting space 2 m x 1 m.

Novel diffusive gradients in thin films technique to assess labile sulfate in soil.

PubMed

Hanousek, Ondrej; Mason, Sean; Santner, Jakob; Chowdhury, Md Mobaroqul Ahsan; Berger, Torsten W; Prohaska, Thomas

2016-09-01

A novel diffusive gradients in thin films (DGT) technique for sampling labile soil sulfate was developed, based on a strong basic anion exchange resin (Amberlite IRA-400) for sulfate immobilization on the binding gel. For reducing the sulfate background on the resin gels, photopolymerization was applied instead of ammonium persulfate-induced polymerization. Agarose cross-linked polyacrylamide (APA) hydrogels were used as diffusive layer. The sulfate diffusion coefficient in APA gel was determined as 9.83 × 10(-6) ± 0.35 × 10(-6) cm(2) s(-1) at 25 °C. The accumulated sulfate was eluted in 1 mol L(-1) HNO3 with a recovery of 90.9 ± 1.6 %. The developed method was tested against two standard extraction methods for soil sulfate measurement. The obtained low correlation coefficients indicate that DGT and conventional soil test methods assess differential soil sulfate pools, rendering DGT a potentially important tool for measuring labile soil sulfate.

Effects of Nitrogen Fertilization and Thinning Treatments on Subsurface Soil Carbon and Nitrogen

NASA Astrophysics Data System (ADS)

Gross, C. D.; James, J. N.; Harrison, R. B.

2016-12-01

Increases in intensively managed forest plantations have caused concern for the long-term productivity and sustainability of these stands, as decreased organic matter retention and shorter rotations can substantially impact soil nutrition both in the short- and long-term. This study aims to provide data for regional responses of soil carbon (C) and nitrogen (N) by depth to fertilization and thinning treatments. Soil was sampled at an intensively managed Douglas-fir (Pseudotsuga menziesii (Mirb.) Franco) plantation in northwestern Oregon, USA. Nine 0.2-ha plots were sampled with at least three pits per plot. Management regimes included no treatment (control), fertilization (F+), minimal thinning (mT), repeated thinning (rT), and combination treatments (mTF+ and rTF+). Fertilized plots received a total of 1120 kg N ha-1 as urea over 16 years. Bulk density and chemical analysis samples were taken in the middle of succeeding soil layers at depths of 0.1, 0.2, 0.5, 1.0, and 1.5 m. Forest floor samples were collected from a randomly placed quadrat. Preliminary results show an increase in total soil C and N of 113 and 106%, respectively, on the mTF+ plot compared to a control plot. The subsoil, defined here as below 0.2 m, contained over 50% of both soil C and N on the mTF+ plot and experienced greater C and N increases than the surface soil following treatment. This study demonstrates that forest management practices over a relatively short time span (<30 years) can significantly alter subsoil, which comprises a substantial portion of biologically available C and N in terrestrial ecosystems. Subsoil processes are critical to our understanding of changes in soil quality and our ability to accurately assess changes in soil C and N reservoirs.

Restoring marsh elevation in a rapidly subsiding salt marsh by thin-layer deposition of dredged material

USGS Publications Warehouse

Ford, M.A.; Cahoon, D.R.; Lynch, J.C.

1999-01-01

Thin-layer deposition of dredged material on coastal marsh by means of high-pressure spray dredging (Jet-Spray??2) technology has been proposed as a mechanism to minimize wetland impacts associated with traditional bucket dredging technologies and to restore soil elevations in deteriorated marshes of the Mississippi River delta. The impact of spray dredging on vegetated marsh and adjacent shallow-water habitat (formerly vegetated marsh that deteriorated to open water) was evaluated in a 0.5-ha Spartina alterniflora-dominated salt marsh in coastal Louisiana. The thickness of dredged sediment deposits was determined from artificial soil marker horizons and soil elevation change was determined from sedimentation-erosion tables (SET) established prior to spraying in both sprayed and reference marshes. The vertical accretion and elevation change measurements were made simultaneously to allow for calculation of shallow (~5 m depth) subsidence (accretion minus elevation change). Measurements made immediately following spraying in July 1996 revealed that stems of S. alterniflora were knocked down by the force of the spray and covered with 23 mm of dredged material. Stems of S. alterniflora soon recovered, and by July 1997 the percent cover of S. alterniflora had increased three-fold over pre-project conditions. Thus, the layer of dredged material was thin enough to allow for survival of the S. alterniflora plants, with no subsequent colonization by plant species typical of higher marsh zones. By February 1998, 62 mm of vertical accretion accumulated at this site, and little indication of disturbance was noted. Although not statistically significant, soil elevation change was greater than accretion on average at both the spray and reference marshes, suggesting that subsurface expansion caused by increased root biomass production and/or pore water storage influence elevation in this marsh region. In the adjacent shallow water pond, 129 mm of sediment was deposited in July 1996 as a result of spraying, and despite initial shallow subsidence and continual erosion through February 1998, water bottom elevation was raised sufficiently to allow S. alterniflora to invade via rhizome growth from the adjacent marsh. Hence, thin-layer deposition of dredged material at this site was effective at restoring and maintaining marsh elevation after 1.5 years. However, if the open water sediment deposits are not soon completely stabilized via further vegetative colonization, erosion may eventually lower elevations to the level where emergent vegetation cannot persist.

Experimental Investigation of Soil and Atmospheric Conditions on the Momentum, Mass, and Thermal Boundary Layers Above the Land Atmosphere Interface

NASA Astrophysics Data System (ADS)

Trautz, A.; Smits, K. M.; Illangasekare, T. H.; Schulte, P.

2014-12-01

The purpose of this study is to investigate the impacts of soil conditions (i.e. soil type, saturation) and atmospheric forcings (i.e. velocity, temperature, relative humidity) on the momentum, mass, and temperature boundary layers. The atmospheric conditions tested represent those typically found in semi-arid and arid climates and the soil conditions simulate the three stages of evaporation. The data generated will help identify the importance of different soil conditions and atmospheric forcings with respect to land-atmospheric interactions which will have direct implications on future numerical studies investigating the effects of turbulent air flow on evaporation. The experimental datasets generated for this study were performed using a unique climate controlled closed-circuit wind tunnel/porous media facility located at the Center for Experimental Study of Subsurface Environmental Processes (CESEP) at the Colorado School of Mines. The test apparatus consisting of a 7.3 m long porous media tank and wind tunnel, were outfitted with a sensor network to carefully measure wind velocity, air and soil temperature, relative humidity, soil moisture, and soil air pressure. Boundary layer measurements were made between the heights of 2 and 500 mm above the soil tank under constant conditions (i.e. wind velocity, temperature, relative humidity). The soil conditions (e.g. soil type, soil moisture) were varied between datasets to analyze their impact on the boundary layers. Experimental results show that the momentum boundary layer is very sensitive to the applied atmospheric conditions and soil conditions to a much less extent. Increases in velocity above porous media leads to momentum boundary layer thinning and closely reflect classical flat plate theory. The mass and thermal boundary layers are directly dependent on both atmospheric and soil conditions. Air pressure within the soil is independent of atmospheric temperature and relative humidity - wind velocity and soil moisture effects were observed. This data provides important insight into future work of accurately modeling the exchange processes associated with evaporation under various turbulent atmospheric conditions.

Kinetics of Zn sorption-desorption using a thin disk flow method

DOE Office of Scientific and Technical Information (OSTI.GOV)

Hinz, C.; Selim, H.M.

1999-02-01

In this study the authors investigated the kinetics of Zn sorption and desorption using a short column or thin disk method. The method is based on continuous flow through a thin soil layer where the effluent was collected using a fraction collector. Two soils were used: a Windsor soil and Mahan soil. Breakthrough results (BTCs) for different flow velocities indicated that Zn sorption is instantaneous and equilibrium retention is dominant when a pulse of Zn with a concentration of 2.62 [times] 10[sup [minus]5] M is applied. However, based on flow interruption, time-dependent Zn sorption-desorption processes were most pronounced when themore » applied Zn pulse concentration was two orders of magnitude lower. This confirms earlier findings of concentration-dependent kinetics from batch experiments on Windsor soil. The removal of organic matter and iron oxide, based on peroxide and peroxide/dithionite-treatments, resulted in doubling and quadrupling Zn retention, respectively, compared with the untreated Windsor soil. Differences between the untreated, peroxide-, and peroxide/dithionite-treated Windsor soils were most pronounced at low input Zn concentrations, suggesting that more specific sites became available as a result of the different treatments. At high input Zn concentrations, increases of specific sites may not be significant. For the treated soil, stronger sorption and desorption kinetic behavior was exhibited compared with the untreated soil. Diffusion into soil minerals or surface-controlled reactions may cause such behavior.« less

GPR monitoring for non-uniform infiltration through a high permeable gravel layer in the test sand box

NASA Astrophysics Data System (ADS)

Kuroda, Seiichiro; Ishii, Nobuyuki; Morii, Toshihiro

2017-04-01

Recently capillary barriers have been known as a method to protect subsurface regions against infiltration from soil surface. It has essentially non-uniform structure of permeability or soil physical property. To identify the function of the capillary barrier, the site-characterization technique for non-uniform soil moisture distribution and infiltration process is needed. We built a sand box in which a thin high-permeable gravel layer was embedded and conducted a infiltration test, including non-uniform flow of soil water induced by capillary barrier effects. We monitored this process by various types of GPR measurements, including time-lapsed soundings with multi-frequency antenna and transmission measurements like one using cross-borehole radar. Finally we will discuss the applicability of GPR for monitoring the phenomena around the capillary barrier of soil. This work has partially supported by JSPS Grant-in-aid Scientific Research program, No.16H02580.

Spatiotemporal dynamics of phosphorus release, oxygen consumption and greenhouse gas emissions after localised soil amendment with organic fertilisers.

PubMed

Christel, Wibke; Zhu, Kun; Hoefer, Christoph; Kreuzeder, Andreas; Santner, Jakob; Bruun, Sander; Magid, Jakob; Jensen, Lars Stoumann

2016-06-01

Organic fertilisation inevitably leads to heterogeneous distribution of organic matter and nutrients in soil, i.e. due to uneven surface spreading or inhomogeneous incorporation. The resulting localised hotspots of nutrient application will induce various biotic and abiotic nutrient turnover processes and fixation in the residue sphere, giving rise to distinct differences in nutrient availability, soil oxygen content and greenhouse gas (GHG) production. In this study we investigated the spatiotemporal dynamics of the reaction of manure solids and manure solids char with soil, focusing on their phosphorus (P) availability, as current emphasis on improving societal P efficiency through recycling waste or bio-based fertilisers necessitates a sound understanding of their behaviour. Soil layers amended at a constant P application rate with either pig manure solids or char made from pig manure solids were incubated for three weeks between layers of non-amended, P-depleted soil. Spatial and temporal changes in and around the amendment layers were simultaneously investigated in this study using a sandwich sensor consisting of a planar oxygen optode and multi-element diffusive gradients in thin films (DGT) gels, combined with GHG emission measurements. After three weeks of incubation, the soil containing a layer amended with manure solids had a lower overall O2 content and had emitted significantly more CO2 than the non-amended control or the char-amended soil. The P availability from manure solids was initially higher than that from the char, but decreased over time, whereas from the char-amended layer P availability increased in the same period. In both treatments, increases in P availability were confined to the amended soil layer and did not greatly affect P availability in the directly adjacent soil layers during the three-week incubation. These results highlight the importance of placing organic P fertilisers close to where the plant roots will grow in order to facilitate optimal fertiliser use efficiency. Copyright © 2016 The Authors. Published by Elsevier B.V. All rights reserved.

Thin soil layer of green roof systems studied by X-Ray CT

NASA Astrophysics Data System (ADS)

Šácha, Jan; Jelínková, Vladimíra; Dohnal, Michal

2016-04-01

The popular non-invasive visualization technique of X-ray computed tomography (CT) has been used for 3D examination of thin soil layer of vegetated roof systems. The two categories of anthropogenic soils, usually used for green roof systems, were scanned during the first months after green roof system construction. First was represented by stripped topsoil with admixed crushed bricks and was well graded in terms of particle size distribution. The other category represented a commercial lightweight technogenic substrate. The undisturbed soil samples of total volume of 62.8 ccm were studied be means of X-ray Computed Tomography using X-ray Inspection System GE Phoenix Nanomex 180T with resulting spatial resolution about 57 μm in all directions. For both soil categories visible macroporosity, connectivity (described by the Euler characteristic), dimensionless connectivity and critical cross section of pore network were determined. Moreover, the temporal structural changes of studied soils were discussed together with heat and water regime of the green roof system. The analysis of CT images of anthropogenic soils was problematic due to the different X-ray attenuation of individual constituents. The correct determination of the threshold image intensity differentiating the soil constituents from the air phase had substantial importance for soil pore network analyses. However, X-ray CT derived macroporosity profiles reveal significant temporal changes notably in the soil comprised the stripped topsoil with admixed crushed bricks. The results implies that the technogenic substrate is structurally more stable over time compared to the stripped topsoil. The research was realized as a part of the University Centre for Energy Efficient Buildings supported by the EU and with financial support from the Czech Science Foundation under project number 14-10455P.

Enhanced photodegradation of phenolic compounds by adding TiO2 to soil in a rotary reactor.

PubMed

Wang, Jing-xian; Chen, Shuo; Quan, Xie; Zhao, Hui-min; Zhao, Ya-zhi

2006-01-01

Photodegradation of pentachlorophenol (PCP) and p-nitrophenol (PNP) in soil was carried out in a designed rotary reactor, which can provide the soil particles with continually uniform irradiation, and on a series of thin soil layers. TiO2, as a kind of environmental friendly photocatalyst, was introduced to the soil to enhance the processes. Compared with that on the soil layers, photodegradation of PCP at initial concentration of 60 mg/kg was improved dramatically in the rotary reactor no matter whether TiO2 was added, with an increase of 3.0 times in the apparent first-order rate constants. The addition of 1 wt% TiO2 furthered the improvement by 1.4 times. Without addition of TiO2, PNP (initial concentration of 60 mg/kg) photodegradation rate in the rotary reactor was similar to that on the soil layers. When 1 wt% additional TiO2 was added, PNP photodegradation was enhanced obviously, and the enhancement in the rotary reactor was 2 times of that on the soil layers, which may be attributed to the higher frequency of the contact between PNP on soil particles and the photocatalyst. The effect of soil pH and initial concentrations of the target compounds on the photodegradation in the rotary reactor was investigated. The order of the degradation rate at different soil pH was relative to the aggregation of soil particles during mixing in the rotary reactor. Photodegradation of PCP and PNP at different initial concentrations showed that addition of TiO2 to enhance the photodegradation was more suitable for contaminated soil with higher concentration of PCP, while was effective for contaminated soil at each PNP concentration tested in our study.

Natural soil mediated photo Fenton-like processes in treatment of pharmaceuticals: Batch and continuous approach.

PubMed

Changotra, Rahil; Rajput, Himadri; Dhir, Amit

2017-12-01

This paper manifests the potential viability of soil as a cost-free catalyst in photo-Fenton-like processes for treating pharmaceuticals at large scale. Naturally available soil without any cost intensive modification was utilized as a catalyst to degrade pharmaceuticals, specifically ornidazole (ORZ) and ofloxacin (OFX). Soil was characterized and found enriched with various iron oxides like hematite, magnetite, goethite, pyrite and wustite, which contributes toward enhanced dissolution of Fe 3+ than Fe 2+ in the aqueous solution resulting in augmented rate of photo-Fenton reaction. The leached iron concentration in solution was detected during the course of experiments. The degradation of ORZ and OFX was assessed in solar induced batch experiments using H 2 O 2 as oxidant and 95% ORZ and 92% OFX removal was achieved. Elevated efficiencies were achieved due to Fe 2+ /Fe 3+ cycling, producing more hydroxyl radical leading to the existence of homogeneous and heterogeneous reactions simultaneously. The removal efficiency of solar photo-Fenton like process was also compared to photo-Fenton process with different irradiation sources (UV-A and UV-B) and were statistically analysed. Continuous-scale studies were conducted employing soil either in the form of soil beads or as a thin layer spread on the surface of baffled reactor. Soil beads were found to have satisfactory reusability and stability. 84 and 79% degradation of ORZ and OFX was achieved using soil as thin layer while with soil beads 71 and 68% degradation, respectively. HPLC and TOC study confirmed the efficient removal of both the compounds. Toxicity assessment demonstrates the inexistence of toxic intermediates during the reaction. Copyright © 2017 Elsevier Ltd. All rights reserved.

Tdap (tetanus, diphtheria, pertussis) Vaccine and Pregnancy

MedlinePlus

... bacteria that cause tetanus can be found in soil and animal waste. Tetanus gets into a person’s body through an open cut. Diphtheria is a bacterial infection that often starts with a fever and sore throat. A thin layer (called a membrane) can form over the back ...

Soil moisture content estimation using ground-penetrating radar reflection data

NASA Astrophysics Data System (ADS)

Lunt, I. A.; Hubbard, S. S.; Rubin, Y.

2005-06-01

Ground-penetrating radar (GPR) reflection travel time data were used to estimate changes in soil water content under a range of soil saturation conditions throughout the growing season at a California winery. Data were collected during three data acquisition campaigns over an 80 by 180 m area using 100 MHz surface GPR antennas. GPR reflections were associated with a thin, low permeability clay layer located 0.8-1.3 m below the ground surface that was identified from borehole information and mapped across the study area. Field infiltration tests and neutron probe logs suggest that the thin clay layer inhibited vertical water flow, and was coincident with high volumetric water content (VWC) values. The GPR reflection two-way travel time and the depth of the reflector at the borehole locations were used to calculate an average dielectric constant for soils above the reflector. A site-specific relationship between the dielectric constant and VWC was then used to estimate the depth-averaged VWC of the soils above the reflector. Compared to average VWC measurements from calibrated neutron probe logs over the same depth interval, the average VWC estimates obtained from GPR reflections had an RMS error of 0.018 m 3 m -3. These results suggested that the two-way travel time to a GPR reflection associated with a geological surface could be used under natural conditions to obtain estimates of average water content when borehole control is available and the reflection strength is sufficient. The GPR reflection method therefore, has potential for monitoring soil water content over large areas and under variable hydrological conditions.

Forest thinning and soil respiration in a ponderosa pine plantation in the Sierra Nevada.

PubMed

Tang, Jianwu; Qi, Ye; Xu, Ming; Misson, Laurent; Goldstein, Allen H

2005-01-01

Soil respiration is controlled by soil temperature, soil water, fine roots, microbial activity, and soil physical and chemical properties. Forest thinning changes soil temperature, soil water content, and root density and activity, and thus changes soil respiration. We measured soil respiration monthly and soil temperature and volumetric soil water continuously in a young ponderosa pine (Pinus ponderosa Dougl. ex P. Laws. & C. Laws.) plantation in the Sierra Nevada Mountains in California from June 1998 to May 2000 (before a thinning that removed 30% of the biomass), and from May to December 2001 (after thinning). Thinning increased the spatial homogeneity of soil temperature and respiration. We conducted a multivariate analysis with two independent variables of soil temperature and water and a categorical variable representing the thinning event to simulate soil respiration and assess the effect of thinning. Thinning did not change the sensitivity of soil respiration to temperature or to water, but decreased total soil respiration by 13% at a given temperature and water content. This decrease in soil respiration was likely associated with the decrease in root density after thinning. With a model driven by continuous soil temperature and water time series, we estimated that total soil respiration was 948, 949 and 831 g C m(-2) year(-1) in the years 1999, 2000 and 2001, respectively. Although thinning reduced soil respiration at a given temperature and water content, because of natural climate variability and the thinning effect on soil temperature and water, actual cumulative soil respiration showed no clear trend following thinning. We conclude that the effect of forest thinning on soil respiration is the combined result of a decrease in root respiration, an increase in soil organic matter, and changes in soil temperature and water due to both thinning and interannual climate variability.

Prospect of life on cold planets with low atmospheric pressures

NASA Astrophysics Data System (ADS)

Pavlov, A. A.; Vdovina, M.

2009-12-01

Stable liquid water on the surface of a planet has been viewed as the major requirement for a habitable planet. Such approach would exclude planets with low atmospheric pressures and cold mean surface temperatures (like present Mars) as potential candidates for extraterrestrial life search. Here we explore a possibility of the liquid water formation in the extremely shallow (1-3 cm) subsurface layer under low atmospheric pressures (0.1-10 mbar) and low average surface temperatures (~-30 C). During brief periods of simulated daylight warming the shallow subsurface ice sublimates, the water vapor can diffuse through the porous surface layer of soil temporarily producing supersaturated conditions in the soil, which lead to the formation of liquid films. We show that non-extremophile terrestrial microorganisms (Vibrio sp.) can grow and reproduce under such conditions. The necessary conditions for metabolism and reproduction are the sublimation of ground ice through a thin layer of soil and short episodes of warm temperatures at the planetary surface.

Ground tests of the Dynamic Albedo of Neutron instrument operation in the passive mode with a Martian soil model

NASA Astrophysics Data System (ADS)

Shvetsov, V. N.; Dubasov, P. V.; Golovin, D. V.; Kozyrev, A. S.; Krylov, A. R.; Krylov, V. A.; Litvak, M. L.; Malakhov, A. V.; Mitrofanov, I. G.; Mokrousov, M. I.; Sanin, A. B.; Timoshenko, G. N.; Vostrukhin, A. A.; Zontikov, A. O.

2017-07-01

The results of the Dynamic Albedo of Neutrons (DAN) instrument ground tests in the passive mode of operation are presented in comparison with the numerical calculations. These test series were conducted to support the current surface measurements of DAN onboard the MSL Curiosity rover. The instrument sensitivity to detect thin subsurface layers of water ice buried at different depths in the analog of Martian soil has been evaluated during these tests. The experiments have been done with a radioisotope Pu-Be neutron source (analog of the MMRTG neutron source onboard the Curiosity rover) and the Martian soil model assembled from silicon-rich window glass pane. Water ice layers were simulated with polyethylene sheets. All experiments have been performed at the test facility built at the Joint Institute for Nuclear Research (Dubna, Russia).

Soil Production, Landscape Evolution and Vegetation Dynamics in the Blue Mountains, Australia.

NASA Astrophysics Data System (ADS)

Wilkinson, M. T.; Humphreys, G. S.; Chappell, J.; Fifield, K.; Smith, B. L.; Hesse, P.

2004-12-01

Soil production is thought to relate to overlying soil depth by an inverse exponential function, as empirically derived using terrestrial in situ cosmogenic nuclides (TCN) at several study areas. This contrasts with a long held assumption that soil production is maximised under a thin soil cover, dm (Gilbert, 1877). Many sites in the Blue Mountains, Australia, display prima facie morphologic evidence for a `humped' soil production function. A sharp soil depth change occurs between proximal and distal spur extremities that accord with a change from forest to treeless heath, and shallow discontinuous soils are found on spur noses. Either of these features may indicate unstable conditions at depths less than dm implicit in a humped soil production function. We attempt to constrain the soil production function at our site using the TCN Be-10 from sandstone bedrock and saprolite, and morphometric analysis at Marrangaroo Creek. Although the soil depth change from forest to heath may be related to regional curvature not soil production, the peak in soil production under shallow mantles may explain alternating bands of soil and outcrop on spur noses. Soil production rates are mildly influenced by overlying soil thickness, suggesting that although thin layers of iron cemented sandstone only comprise a small percentage of the catchment bedrock, its resistance to weathering sets the pace of surface lowering. Furthermore, we present evidence that Marrangaroo Creek is a result of post-Miocene incision, similar to adjacent catchments in the region.

Adsorbed water and thin liquid films on Mars

NASA Astrophysics Data System (ADS)

Boxe, C. S.; Hand, K. P.; Nealson, K. H.; Yung, Y. L.; Yen, A. S.; Saiz-Lopez, A.

2012-07-01

At present, bulk liquid water on the surface and near-subsurface of Mars does not exist due to the scarcity of condensed- and gas-phase water, pressure and temperature constraints. Given that the nuclei of soil and ice, that is, the soil solid and ice lattice, respectively, are coated with adsorbed and/or thin liquid films of water well below 273 K and the availability of water limits biological activity, we quantify lower and upper limits for the thickness of such adsorbed/water films on the surface of the Martian regolith and for subsurface ice. These limits were calculated based on experimental and theoretical data for pure water ice and water ice containing impurities, where water ice containing impurities exhibit thin liquid film enhancements, ranging from 3 to 90. Close to the cold limit of water stability (i.e. 273 K), thin liquid film thicknesses at the surface of the Martian regolith is 0.06 nm (pure water ice) and ranges from 0.2 to 5 nm (water ice with impurities). An adsorbed water layer of 0.06 nm implies a dessicated surface as the thickness of one monolayer of water is 0.3 nm but represents 0.001-0.02% of the Martian atmospheric water vapour inventory. Taking into account the specific surface area (SSA) of surface-soil (i.e. top 1 mm of regolith and 0.06 nm adsorbed water layer), shows Martian surface-soil may contain interfacial water that represents 6-66% of the upper- and lower-limit atmospheric water vapour inventory and almost four times and 33%, the lower- and upper-limit Martian atmospheric water vapour inventory. Similarly, taking the SSA of Martian soil, the top 1 mm or regolith at 5 nm thin liquid water thickness, yields 1.10×1013 and 6.50×1013 litres of waters, respectively, 55-325 times larger than Mars' atmospheric water vapour inventory. Film thicknesses of 0.2 and 5 nm represent 2.3×104-1.5×106 litres of water, which is 6.0×10-7-4.0×10-4%, respectively, of a 10 pr μm water vapour column, and 3.0×10-6-4.0×10-4% and 6.0×10-6-8.0×10-4%, respectively, of the Martian atmospheric water vapour inventory. Thin liquid film thicknesses on/in subsurface ice were investigated via two scenarios: (i) under the idealistic case where it is assumed that the diurnal thermal wave is equal to the temperature of ice tens of centimetres below the surface, allowing for such ice to experience temperatures close to 273 K and (ii) under the, likely, realistic scenario where the diurnal thermal wave allows for the maximum subsurface ice temperature of 235 K at 1 m depth between 30°N and 30°S. Scenario 1 yields thin liquid film thicknesses ranging from 11 to 90 nm; these amounts represent 4×106-3.0×107 litres of water. For pure water ice, Scenario 2 reveals that the thickness of thin liquid films contained on/within Martian subsurface is less than 1.2 nm, several molecular layers thick. Conversely, via the effect of impurities at 235 K allows for a thin liquid film thickness on/within subsurface ice of 0.5 nm, corresponding to 6.0×104 litres of water. The existence of thin films on Mars is supported by data from the Mars Exploration Rovers (MERs) Spirit and Opportunity's Alpha Proton X-ray Spectrometer instrumentation, which have detected increased levels of bromine beneath the immediate surface, suggestive of the mobilization of soluble salts by thin films of liquid water towards local cold traps. These findings show that biological activity on the Martian surface and subsurface is not limited by nanometre dimensions of available water.

Denitrification potential in relation to lithology in five headwater riparian zones.

PubMed

Hill, Alan R; Vidon, Philippe G F; Langat, Jackson

2004-01-01

The influence of riparian zone lithology on nitrate dynamics is poorly understood. We investigated vertical variations in potential denitrification activity in relation to the lithology and stratigraphy of five headwater riparian zones on glacial till and outwash landscapes in southern Ontario, Canada. Conductive coarse sand and gravel layers occurred in four of the five riparian areas. These layers were thin and did not extend to the field-riparian perimeter in some riparian zones, which limited their role as conduits for ground water flow. We found widespread organic-rich layers at depths ranging from 40 to 300 cm that resulted from natural floodplain processes and the burial of surface soils by rapid valley-bottom sedimentation after European settlement. The organic matter content of these layers varied considerably from 2 to 5% (relic channel deposit) to 5 to 21% (buried soils) and 30 to 62% (buried peat). Denitrification potential (DNP) was measured by the acetylene block method in sediment slurries amended with nitrate. The highest DNP rates were usually found in the top 0- to 15-cm surface soil layer in all riparian zones. However, a steep decline in DNP with depth was often absent and high DNP activity occurred in the deep organic-rich layers. Water table variations in 2000-2002 indicated that ground water only interacted frequently with riparian surface soils between late March and May, whereas subsurface organic layers that sustain considerable DNP were below the water table for most of the year. These results suggest that riparian zones with organic deposits at depth may effectively remove nitrate from ground water even when the water table does not interact with organic-rich surface soil horizons.

Thin-layer chromatography coupled with high performance liquid chromatography for determining tetrabromobisphenol A/S and their derivatives in soils.

PubMed

Liu, Aifeng; Shen, Zhaoshuang; Tian, Yong; Shi, Rongguang; Liu, Yi; Zhao, Zongshan; Xian, Mo

2017-12-01

As brominated flame retardants (BFRs), tetrabromobisphenol A/S (TBBPA/S) and their derivatives have raised wide concerns owing to their widely usage, distributions and adverse effects on human health, thus monitoring these BFRs was urgently needed. In this study, a rapid and cost-effective method based on thin-layer chromatography (TLC) sample pre-treatment coupled with high performance liquid chromatography-diode array detector (HPLC-DAD) (UV=214nm) was developed for determining TBBPA/S and their derivatives in soils, including TBBPA, TBBPA bis(allyl ether) (TBBPA-BAE), TBBPA bis(2,3-dibromopropyl ether) (TBBPA-BDBPE), TBBPS bis(allyl ether) (TBBPS-BAE) and TBBPS bis(2,3-dibromopropyl ether) (TBBPS-BDBPE). The method detection limits (MDLs) and the method quantification limits (MQLs) for these BFRs ranged from 0.023 to 0.087μgg -1 dw and 0.076-0.29μgg -1 dw, respectively. The recoveries were 41-108% and both RSD of repeatability and intermediate precision were less than 11%. The developed method presented good performance for analyzing natural soil samples collected from BFRs industrial park, suggesting its great application potential for monitoring environmental TBBPA/S and their derivatives. Copyright © 2017 Elsevier B.V. All rights reserved.

Soil Moisture Content Estimation using GPR Reflection Travel Time

NASA Astrophysics Data System (ADS)

Lunt, I. A.; Hubbard, S. S.; Rubin, Y.

2003-12-01

Ground-penetrating radar (GPR) reflection travel time data were used to estimate changes in soil water content under a range of soil saturation conditions throughout the growing season at a California winery. Data were collected during four data acquisition campaigns over an 80 by 180 m area using 100 MHz surface GPR antennae. GPR reflections were associated with a thin, low permeability clay layer located between 0.8 to 1.3 m below the ground surface that was calibrated with borehole information and mapped across the study area. Field infiltration tests and neutron probe logs suggest that the thin clay layer inhibited vertical water flow, and was coincident with high volumetric water content (VWC) values. The GPR reflection two-way travel time and the depth of the reflector at borehole locations were used to calculate an average dielectric constant for soils above the reflector. A site-specific relationship between the dielectric constant and VWC was then used to estimate the depth-averaged VWC of the soils above the reflector. Compared to average VWC measurements from calibrated neutron probe logs over the same depth interval, the average VWC estimates obtained from GPR reflections had an RMS error of 2 percent. We also investigated the estimation of VWC using reflections associated with an advancing water front, and found that estimates of average VWC to the water front could be obtained with similar accuracy. These results suggested that the two-way travel time to a GPR reflection associated with a geological surface or wetting front can be used under natural conditions to obtain estimates of average water content when borehole control is available. The GPR reflection method therefore has potential for monitoring soil water content over large areas and under variable hydrological conditions.

The global distribution and dynamics of surface soil moisture

NASA Astrophysics Data System (ADS)

McColl, Kaighin A.; Alemohammad, Seyed Hamed; Akbar, Ruzbeh; Konings, Alexandra G.; Yueh, Simon; Entekhabi, Dara

2017-01-01

Surface soil moisture has a direct impact on food security, human health and ecosystem function. It also plays a key role in the climate system, and the development and persistence of extreme weather events such as droughts, floods and heatwaves. However, sparse and uneven observations have made it difficult to quantify the global distribution and dynamics of surface soil moisture. Here we introduce a metric of soil moisture memory and use a full year of global observations from NASA's Soil Moisture Active Passive mission to show that surface soil moisture--a storage believed to make up less than 0.001% of the global freshwater budget by volume, and equivalent to an, on average, 8-mm thin layer of water covering all land surfaces--plays a significant role in the water cycle. Specifically, we find that surface soil moisture retains a median 14% of precipitation falling on land after three days. Furthermore, the retained fraction of the surface soil moisture storage after three days is highest over arid regions, and in regions where drainage to groundwater storage is lowest. We conclude that lower groundwater storage in these regions is due not only to lower precipitation, but also to the complex partitioning of the water cycle by the surface soil moisture storage layer at the land surface.

Fruit and seed heteromorphism in the cold desert annual ephemeral Diptychocarpus strictus (Brassicaceae) and possible adaptive significance.

PubMed

Lu, Juanjuan; Tan, Dunyan; Baskin, Jerry M; Baskin, Carol C

2010-06-01

Diptychocarpus strictus is an annual ephemeral in the cold desert of northwest China that produces heteromorphic fruits and seeds. The primary aims of this study were to characterize the morphology and anatomy of fruits and seeds of this species and compare the role of fruit and seed heteromorphism in dispersal and germination. Shape, size, mass and dispersal of siliques and seeds and the thickness of the mucilage layer on seeds were measured, and the anatomy of siliques and seeds, the role of seed mucilage in water absorption/dehydration, germination and adherence of seeds to soil particles, the role of pericarp of lower siliques in seed dormancy and seed after-ripening and germination phenology were studied using standard procedures. Plants produce dehiscent upper siliques with a thin pericarp containing seeds with large wings and a thick mucilage layer and indehiscent lower siliques with a thick pericarp containing nearly wingless seeds with a thin mucilage layer. The dispersal ability of seeds from the upper siliques was much greater than that of intact lower siliques. Mucilage increased the amount of water absorbed by seeds and decreased the rate of dehydration. Seeds with a thick mucilage layer adhered to soil particles much better than those with a thin mucilage layer or those from which mucilage had been removed. Fresh seeds were physiologically dormant and after-ripened during summer. Non-dormant seeds germinated to high percentages in light and in darkness. Germination of seeds from upper siliques is delayed until spring primarily by drought in summer and autumn, whereas the thick, indehiscent pericarp prevents germination for >1 year of seeds retained in lower siliques. The life cycle of D. strictus is morphologically and physiologically adapted to the cold desert environment in time and space via a combination of characters associated with fruit and seed heteromorphism.

Scanning Electron Microscope Studies of Interactions between Agaricus bisporus (Lang) Sing Hyphae and Bacteria in Casing Soil

PubMed Central

Masaphy, Segula; Levanon, D.; Tchelet, R.; Henis, Y.

1987-01-01

Relationships between the hyphae of Agaricus bisporus (Lang) Sing and bacteria from the mushroom bed casing layer were examined with a scanning electron microscope. Hyphae growing in the casing layer differed morphologically from compost-grown hyphae. Whereas the compost contained thin single hyphae surrounded by calcium oxalate crystals, the casing layer contained mainly wide hyphae or mycelial strands without crystals. The bacterial population in the hyphal environment consisted of several types, some attached to the hyphae with filamentlike structures. This attachment may be important in stimulation of pinhead initiation. Images PMID:16347340

An Experimental Study of the Effects of Litter and Duff Consumption and Ash Formation on Post-Fire Runoff.

NASA Astrophysics Data System (ADS)

Woods, S. W.; Balfour, V.

2007-12-01

Consumption of the litter and duff layers in forest wildfires can lead to substantial increases in the frequency and magnitude of overland flow. These increases result from the loss of storage in the organic surface layer, reduced surface roughness, and from sealing of the exposed mineral soil surface. The presence of an ash layer may accentuate surface sealing by providing an additional source of fine material, or it may reduce runoff by storing rainfall and by protecting the soil surface from raindrop impacts. We used simulated rainfall experiments to assess the effects of litter and duff consumption and the presence of ash layers of varying thickness on post fire runoff at two forested sites in western Montana, one with sandy loam soils formed out of granodiorite and the other with gravelly silt loam soils formed out of argillite. At each site we measured the runoff from simulated rainfall in replicated 0.5 m2 plots before and after application of the following treatments: 1) burning with a fuel load of 90 Mg ha-1, 2) manual removal of the litter and duff layers, 3) addition of 0.5, 2.5 and 5 cm of ash to plots from which the litter and duff had previously been removed, and 4) addition of the same depths of ash to burned plots at the sandy loam site. In the burned plots the surface litter and duff layers were completely consumed and a <1cm layer of black and gray ash and char was formed, indicating a moderate severity burn. The mean soil temperature in the upper 1 cm of the mineral soil was 70° C, and there was no detectable increase in water repellency. The mean final infiltration capacity of the burned sandy loam plots was 35 mm hr-1 compared to a pre-fire mean of 87 mm hr-1, while in the gravelly silt loam plots the pre- and post burn infiltration capacities (27 and 31 mm hr- 1) were not significantly different. Manual removal of the litter and duff layers reduced the mean final infiltration capacity in the sandy loam plots from 64 mm hr-1 to 40 mm hr-1 and in the gravelly silt loam plots from 23 mm hr-1 to 16 mm hr-1. We attribute decreases in infiltration due to the burning and duff removal treatments primarily to surface sealing. In the sandy loam plots, burning may have had a greater effect on infiltration than duff removal because the thin ash layer in the burned plots provided an additional source of fine material. In the gravelly silt loam plots, macropores located around rock fragments helped to minimize sealing effects. The addition of 0.5 cm of ash to the burned granitic plots resulted in a 20 mm hr-1 decrease in the final infiltration rate, and this was also probably due to surface sealing. However, the overall effect of ash addition was to increase the cumulative infiltration in proportion to the ash thickness and to maintain a higher average infiltration rate, indicating that while thin (<1 cm) ash layers may promote sealing, thicker ash layers help to reduce the runoff rate by providing additional storage for rainfall and by protecting the soil surface from raindrop impacts.

Effects of fire on the thermal stability of permafrost in lowland and upland black spruce forests of interior Alaska in a changing climate

USGS Publications Warehouse

Jafarov, Elchin E.; Romanovsky, Vladimir E.; Genet, Helene; McGuire, Anthony David; Marchenko, Sergey S.

2013-01-01

Fire is an important factor controlling the composition and thickness of the organic layer in the black spruce forest ecosystems of interior Alaska. Fire that burns the organic layer can trigger dramatic changes in the underlying permafrost, leading to accelerated ground thawing within a relatively short time. In this study, we addressed the following questions. (1) Which factors determine post-fire ground temperature dynamics in lowland and upland black spruce forests? (2) What levels of burn severity will cause irreversible permafrost degradation in these ecosystems? We evaluated these questions in a transient modeling–sensitivity analysis framework to assess the sensitivity of permafrost to climate, burn severity, soil organic layer thickness, and soil moisture content in lowland (with thick organic layers, ~80 cm) and upland (with thin organic layers, ~30 cm) black spruce ecosystems. The results indicate that climate warming accompanied by fire disturbance could significantly accelerate permafrost degradation. In upland black spruce forest, permafrost could completely degrade in an 18 m soil column within 120 years of a severe fire in an unchanging climate. In contrast, in a lowland black spruce forest, permafrost is more resilient to disturbance and can persist under a combination of moderate burn severity and climate warming.

Aliphatic and aromatic plant biopolymer dynamics in soil particles isolated from sequential density fractionation

NASA Astrophysics Data System (ADS)

Caldwell, B.; Filley, T.; Sollins, P.; Lajtha, K.; Swanston, C.; Kleber, M.; Kramer, M.

2007-12-01

A recent multi-layer-based soil organic matter-mineral interaction mechanistic model to describe the nature of soil organic matter-mineral surface mechanism for soil organic matter stabilization predicts that proteinaceous and aliphatic materials establish the core of strong binding-interactions upon which other organic matter is layered. A key methodology providing data underpinning this hypothesis is sequential density fractionation where soil is partitioned into particles of increasing density with the assumption that a partial control on organic matter distribution through density series is the thickness of its layering. Four soils of varying mineralogy and texture were investigated for their biopolymer, isotopic, and mineralogical properties. Light fractions (<1.8 g/cm3), although dominanted by organic detritus, did not always contain the highest concentration of lignin and substituted fatty acids from cutin and suberin while heavier fractions, 1.8-2.6 g/cm3, exhibited a progressive decrease in concentration in plant derived biopolymers with density. Extractable lignin phenols exhibited a progressive oxidation state with density. The concentration of biopolymers roughly mirrored the C:N ratio of soil particles which dropped consistently with increasing particle density. Although, in all soils, both lignin phenols and SFA concentration generally decreased with increasing density the ratio SFA/lignin varied with density and depending upon the soil. All soils, except the oxisol, exhibited an increase in SFA with respect to lignin suggesting a selective stabilization of those material with respect to lignin. In the oxisol, which showed little variation in its hematite dominated mineralogy across density, SFA/lignin remained constant, potentially indicating a greater capacity to stabilize lignin in that system. Interestingly, the lignin oxidation state increased with density in the oxisol. Given the variation in soil character, the consistency in these trends it suggests a general phenomenon of progressive decay in plant derived material with thinness of mineral coating but an overall relative increase in aliphatic character-all consistent with the multi-layer model.

Long-term experiments to better understand soil-human interactions

NASA Astrophysics Data System (ADS)

Bormann, B. T.; Homann, P. S.

2011-12-01

Interactions between soils and people may be transforming global conditions, but the interactions are poorly understood. Changes in soils have proven difficult to quantify, especially in complex ecosystems manifesting large spatiotemporal variability. Long-term ecosystem experiments that evaluate soil change and demonstrate alternative choices are important to understanding changes, discovering new controls and drivers, and influencing decisions. Inspired by agriculture studies, like Rothamsted, the US Forest Service established in 1990 a network of operational-scale experiments across the Pacific Northwest to evaluate long-term effects of different forest management and disturbance regimes. With a strong experimental design, these experiments are now helping to better understand the long-term effects of managing tree harvesting (clearcutting and thinning), woody debris, and tree and understory species composition, and-serendipitously-the effects of fire. Initial results from the Southern Oregon experimental site indicate surprisingly rapid soil changes in some regimes but not others. We've also learned that rapid change presents challenges to repeat sampling. We present our sample-archive and comparable-layer approaches that seek to accommodate changes in surface elevation, aggregation and disaggregation, and mineral-soil exports. Thinning mature forest stands (80-100 yrs old) did not significantly change soil C in 11-yrs. A small upper-layer C increase was observed after thinning, but it was similar to the control. Significant increases in upper-layer soil N were observed with most treatments, but all increases were similar to the control. Leaving woody debris had little effect. The most remarkable change occurred when mature stands were clearcut and Douglas-firs were planted and tended. Associated with rapid growth of Douglas-fir, an average of 8 Mg C ha-1 was lost from weathered soil 4-18 cm deep. This contrasts with clearcuts where early-seral hardwoods and knobcone pines were established, that trended positively with 2 Mg C ha-1. Soil changes resulting from wild and prescribed fire were substantial. About 50% of the soil C (3-21 Mg ha-1) and 36% of soil N (41-650 kg ha-1) were lost from the upper profile (0-6.2 cm) compared to pre-fire conditions. Intense wildfire that killed most forest trees had about double the losses of C and N than forests burned at lower temperature with fewer trees killed. Average wildfire C losses were more than twice prescribed-fire losses. A long-term perspective is needed to compare episodic influences on soils, like harvesting and wildfire, to day-in, day-out effects of different species mixtures. Especially important is the effect of shrubs, that can rapidly achieve full leaf area but that lack the woody stem structure to store captured C as well as conifers. In theory, therefore, extending shrub cover will increase soil C. The annual profile soil C loss in Douglas-fir (-0.8 Mg ha-1yr-1), if continued beyond 11 yrs, would be similar to the effects of a fire-return interval of less than a third of the historical interval of about 100 years. National and regional soil-C monitoring would benefit from being grounded in existing experimental studies to help integrate large-scale changes with an unfolding understanding of processes in ways useful to decisionmakers.

New Conceptual Model for Soil Treatment Units: Formation of Multiple Hydraulic Zones during Unsaturated Wastewater Infiltration.

PubMed

Geza, Mengistu; Lowe, Kathryn S; Huntzinger, Deborah N; McCray, John E

2013-07-01

Onsite wastewater treatment systems are commonly used in the United States to reclaim domestic wastewater. A distinct biomat forms at the infiltrative surface, causing resistance to flow and decreasing soil moisture below the biomat. To simulate these conditions, previous modeling studies have used a two-layer approach: a thin biomat layer (1-5 cm thick) and the native soil layer below the biomat. However, the effect of wastewater application extends below the biomat layer. We used numerical modeling supported by experimental data to justify a new conceptual model that includes an intermediate zone (IZ) below the biomat. The conceptual model was set up using Hydrus 2D and calibrated against soil moisture and water flux measurements. The estimated hydraulic conductivity value for the IZ was between biomat and the native soil. The IZ has important implications for wastewater treatment. When the IZ was not considered, a loading rate of 5 cm d resulted in an 8.5-cm ponding. With the IZ, the same loading rate resulted in a 9.5-cm ponding. Without the IZ, up to 3.1 cm d of wastewater could be applied without ponding; with the IZ, only up to 2.8 cm d could be applied without ponding. The IZ also plays a significant role in soil moisture distribution. Without the IZ, near-saturation conditions were observed only within the biomat, whereas near-saturation conditions extended below the biomat with the IZ. Accurate prediction of ponding is important to prevent surfacing of wastewater. The degree of water and air saturation influences pollutant treatment efficiency through residence time, volatility, and biochemical reactions. Copyright © by the American Society of Agronomy, Crop Science Society of America, and Soil Science Society of America, Inc.

Use of Amynthas gracilis (Oligochaeta, Megascolecidae) and Bougainvillea litter for rehabilitation of overexploited soils, in Campeche, Yucatan Peninsula, Mexico.

NASA Astrophysics Data System (ADS)

Huerta, Esperanza; Alonso Gongora, Erick

2014-05-01

Yucatan peninsula is one of the recent emerged lands in Mexico; where more of the soils have low organic matter content, and/or the organic horizon is thin (2-5cm). The industry of material extraction for construction purposes is well developed in Yucatan Peninsula, due to the fact of the calcareous material that can be obtained by the maternal rock. Therefore, the material extraction promotes the desertification of the areas, and soil erosion. Bougainvillea sp is a tropical and subtropical woody, evergreen, shrubby vine (Kobayashi et al. 2007), it has a wide range of distribution and it roots are superficial, what allows the plant to inhabit soils with a thin layer of soil organic matter. Earthworms as ecosystem engineers (Jones et al. 1994) can modify their environment, forming borrows and incorporation organic matter into the soil. The aim of this study was to rehabilitate soils without organic matter horizon by the use of earthworms and Bougainvillea litter. The study was developed at mesocosmos level in the laboratory of soils at El Colegio de la Frontera Sur, Unidad Campeche, Mexico. Individual of anecic earthworms were collected and reproduced previously, anecic worms can better incorporate organic matter in to the soil than epigeics or endogeics worms, in Mexican tropical terrestrial ecosystems, anecic worms are almost absent or scarce. In this study we used the exotic earthworm Amynthas gracilis (native in Taiwan),that used to inhabit banana plantations with low technology in southeast Mexico, as exotic has a wide range of tolerance to different amounts of soil organic matter and pH. Four treatments with 4 replicas were established: a) calcareous soil without organic matter horizon+earthworms+litter, b) calcareous soil with organic matter horizon+ earthworms+litter, c) calcareous soil without organic matter horizon+litter, d) calcareous soil with organic matter horizon+litter. After 60 days of study, we observed how earthworms developed successfully in treatments with and without organic matter horizon. Higher amount of litter was incorporated into the soil in those treatments with earthworms. Soil invertebrates populated those treatments with organic matter and earthworms. This study shows that Bougainvillea sp and A. gracilis can be a good combination for rehabilitation of soils without organic matter layer in tropics. Further studies are required in order to observe same results at the field level.

Management Impacts on Carbon Dynamics in a Sierra Nevada Mixed Conifer Forest

PubMed Central

Dore, Sabina; Fry, Danny L.; Collins, Brandon M.; Vargas, Rodrigo; York, Robert A.; Stephens, Scott L.

2016-01-01

Forest ecosystems can act as sinks of carbon and thus mitigate anthropogenic carbon emissions. When forests are actively managed, treatments can alter forests carbon dynamics, reducing their sink strength and switching them from sinks to sources of carbon. These effects are generally characterized by fast temporal dynamics. Hence this study monitored for over a decade the impacts of management practices commonly used to reduce fire hazards on the carbon dynamics of mixed-conifer forests in the Sierra Nevada, California, USA. Soil CO2 efflux, carbon pools (i.e. soil carbon, litter, fine roots, tree biomass), and radial tree growth were compared among un-manipulated controls, prescribed fire, thinning, thinning followed by fire, and two clear-cut harvested sites. Soil CO2 efflux was reduced by both fire and harvesting (ca. 15%). Soil carbon content (upper 15 cm) was not significantly changed by harvest or fire treatments. Fine root biomass was reduced by clear-cut harvest (60–70%) but not by fire, and the litter layer was reduced 80% by clear-cut harvest and 40% by fire. Thinning effects on tree growth and biomass were concentrated in the first year after treatments, whereas fire effects persisted over the seven-year post-treatment period. Over this period, tree radial growth was increased (25%) by thinning and reduced (12%) by fire. After seven years, tree biomass returned to pre-treatment levels in both fire and thinning treatments; however, biomass and productivity decreased 30%-40% compared to controls when thinning was combined with fire. The clear-cut treatment had the strongest impact, reducing ecosystem carbon stocks and delaying the capacity for carbon uptake. We conclude that post-treatment carbon dynamics and ecosystem recovery time varied with intensity and type of treatments. Consequently, management practices can be selected to minimize ecosystem carbon losses while increasing future carbon uptake, resilience to high severity fire, and climate related stresses. PMID:26918460

N cycling and the composition of terpenes and tannins in boreal forest soils: Effects of logging residues

NASA Astrophysics Data System (ADS)

Smolander, Aino; Kitunen, Veikko; Kukkola, Mikko; Tamminen, Pekka

2014-05-01

There is increasing evidence available that certain terpenes and tannins may mediate substantial changes in nitrogen cycling processes in boreal forest soils. Terpenes and tannins are two important groups of plant secondary metabolites: Terpenes are hydrocarbons having different number of isoprene-derived units and tannins are complex polyphenolic compounds able to interact with proteins. Logging residues, consisting of fresh tree tops and branches with needles contain large amounts of terpenes and tannins. Currently there is increasing demand for forest biomass for bioenergy production. Therefore, harvesting of logging residues has become more common from both clear-cutting and thinning stands, instead of conventional stem-only harvest where logging residues are retained on the site. Our aim was to determine how logging residues affect soil N cycling processes in Scots pine and Norway spruce thinning stands in long-term, and how these processes are related to the composition of terpenes and tannins in the soil. Samples were taken from the humus layer of pine and spruce experiments which had been thinned 4-to-19 years before; in the thinning different amounts of logging residues had been distributed on the plots. Logging residues had only little effect on soil microbial biomass N or C. However, in several sites logging residues increased the rate of net N mineralization and the ratios net N mineralization/ C mineralization and net N mineralization/microbial biomass N, and these positive effects were very long-lasting. Logging residues also changed the composition of different terpenes and condensed tannins in soil. In general, with regard to the processes and ratios indicating N availability, stem-only harvest seems to be more favorable than whole-tree harvest. The results from long-term field experiments will be discussed in relation to the effects of different terpenes and tannins, observed in short-term laboratory experiments, on N cycling processes.

Using Combustion Synthesis to Reinforce Berms and Other Regolith Structures

NASA Technical Reports Server (NTRS)

Rodriquez, Gary

2013-01-01

The Moonraker Excavator and other tools under development for use on the Moon, Mars, and asteroids will be employed to construct a number of civil engineering projects and to mine the soil. Mounds of loose soil will be subject to the local transport mechanisms plus artificial mechanisms such as blast effects from landers and erosion from surface vehicles. Some of these structures will require some permanence, with a minimum of maintenance and upkeep. Combustion Synthesis (CS) is a family of processes and techniques whereby chemistry is used to transform materials, often creating flame in a hard vacuum. CS can be used to stabilize civil engineering works such as berms, habitat shielding, ramps, pads, roadways, and the like. The method is to unroll thin sheets of CS fabric between layers of regolith and then fire the fabric, creating a continuous sheet of crusty material to be interposed among layers of loose regolith. The combination of low-energy processes, ISRU (in situ resource utilization) excavator, and CS fabrics, seems compelling as a general method for establishing structures of some permanence and utility, especially in the role of robotic missions as precursors to manned exploration and settlement. In robotic precursory missions, excavator/ mobility ensembles mine the Lunar surface, erect constructions of soil, and dispense sheets of CS fabrics that are covered with layers of soil, fired, and then again covered with layers of soil, iterating until the desired dimensions and forms are achieved. At the base of each berm, for example, is a shallow trench lined with CS fabric, fired and filled, mounded, and then covered and fired, iteratively to provide a footing against lateral shear. A larger trench is host to a habitat module, backfilled, covered with fabric, covered with soil, and fired. Covering the applied CS fabric with layers of soil before firing allows the resulting matrix to incorporate soil both above and below the fabric ply into the fused layer, developing a very irregular surface which, like sandpaper, can provide an anchor for loose soil. CS fabrics employ a coarse fiberglass weave that persists as reinforcement for the fired material. The fiberglass softens at a temperature that exceeds the combustion temperature by factors of two to three, and withstands the installation process. This type of structure should be more resistant to rocket blast effects from Lunar landers.

Fire severity is more sensitive to low fuel moisture content on Calluna heathlands than on peat bogs.

PubMed

Grau-Andrés, Roger; Davies, G Matt; Gray, Alan; Scott, E Marian; Waldron, Susan

2018-03-01

Moorland habitats dominated by the dwarf shrub Calluna vulgaris provide important ecosystem services. Drought is projected to intensify throughout their range, potentially leading to increased fire severity as moisture is a key control on severity. We studied the effect of low fuel moisture content (FMC) on fire severity by using 2×2m rain-out shelters prior to completing 19 experimental fires in two sites in Scotland (UK): a dry heath with thin organic soils and a raised bog with deep, saturated peat, both dominated by Calluna vulgaris. Reduced FMC of the moss and litter (M/L) layer at both sites, and the soil moisture of the dry heath, increased fire-induced consumption of the M/L layer and soil heating at both sites. Increase in fire severity was greater at the dry heath than at the raised bog, e.g. average maximum temperatures at the soil surface increased from 31°C to 189°C at the dry heath, but only from 10°C to 15°C at the raised bog. Substantial M/L layer consumption was observed when its FMC was below 150%. This led to larger seasonal and daily soil temperature fluctuation, particularly at the dry heath during warm months. The results suggest that low FMC following predicted changes in climate are likely to increase wildfire severity and that the impact on vegetation composition and carbon stores may be greater at heathlands than at peatlands. Managed burning aiming to minimise fire severity (e.g. ignition of the M/L layer and exposure to lethal temperatures of ericoid seeds) should be carried out when the FMC of the M/L layer is above 150% and the FMC of the soil is above 200-300%. Copyright © 2017 Elsevier B.V. All rights reserved.

Cleanup procedure for water, soil, animal and plant extracts for the use of electron-capture detector in the gas chromatographic analysis of organophosphorus insecticide residues.

PubMed

Kadoum, A M

1968-07-01

A simple, aqueous acetonitrile partition cleanup method for analyses of some common organophosphorus insecticide residues is described. The procedure described is for cleanup and quantitative recovery of parathion, methyl parathion, diazinon, malathion and thimet from different extracts. Those insecticides in the purified extracts of ground water, grain, soil, plant and animal tissues can be detected quantitatively by gas chromatography with an electron capture-detector at 0.01 ppm. Cleanup is satisfactory for paper and thin-layer chromatography for further identification of individual insecticides in the extracts.

Paired comparison of water, energy and carbon exchanges over two young maritime pine stands (Pinus pinaster Ait.): effects of thinning and weeding in the early stage of tree growth.

PubMed

Moreaux, Virginie; Lamaud, Eric; Bosc, Alexandre; Bonnefond, Jean-Marc; Medlyn, Belinda E; Loustau, Denis

2011-09-01

The effects of management practices on energy, water and carbon exchanges were investigated in a young pine plantation in south-west France. In 2009-10, carbon dioxide (CO(2)), H(2)O and heat fluxes were monitored using the eddy covariance and sap flow techniques in a control plot (C) with a developed gorse layer, and an adjacent plot that was mechanically weeded and thinned (W). Despite large differences in the total leaf area index and canopy structure, the annual net radiation absorbed was only 4% lower in plot W. We showed that higher albedo in this plot was offset by lower emitted long-wave radiation. Annual evapotranspiration (ET) from plot W was 15% lower, due to lower rainfall interception and transpiration by the tree canopy, partly counterbalanced by the larger evaporation from both soil and regrowing weedy vegetation. The drainage belowground from plot W was larger by 113 mm annually. The seasonal variability of ET was driven by the dynamics of the soil and weed layers, which was more severely affected by drought in plot C. Conversely, the temporal changes in pine transpiration and stem diameter growth were synchronous between sites despite higher soil water content in the weeded plot. At the annual scale, both plots were carbon sinks, but thinning and weeding reduced the carbon uptake by 73%: annual carbon uptake was 243 and 65 g C m(-2) on plots C and W, respectively. Summer drought dramatically impacted the net ecosystem exchange: plot C became a carbon source as the gross primary production (GPP) severely decreased. However, plot W remained a carbon sink during drought, as a result of decreases in both GPP and ecosystem respiration (R(E)). In winter, both plots were carbon sources, plots C and W emitting 67.5 and 32.4 g C m(-2), respectively. Overall, this study highlighted the significant contribution of the gorse layer to mass and energy exchange in young pine plantations.

3D soil structure characterization of Biological Soil Crusts from Alpine Tarfala Valley

NASA Astrophysics Data System (ADS)

Mele, Giacomo; Gargiulo, Laura; Zucconi, Laura; D'Acqui, Luigi; Ventura, Stefano

2017-04-01

Cyanobacteria filaments, microfungal hyphae, lichen rhizinae and anchoring rhizoids of bryophytes all together contribute to induce formation of structure in the thin soil layer beneath the Biological Soil Crusts (BSCs). Quantitative assessment of the soil structure beneath the BSCs is primarily hindered by the fragile nature of the crusts. Therefore, the role of BSCs in affecting such soil physical property has been rarely addressed using direct measurements. In this work we applied non-destructive X-ray microtomography imaging on five different samples of BSCs collected in the Alpine Tarfala Valley (northern Sweden), which have already been characterized in terms of fungal biodiversity in a previous work. We obtained images of the 3D spatial organization of the soil underneath the BSCs and characterized its structure by applying procedures of image analysis allowing to determine pore size distribution, pore connectivity and aggregate size distribution. Results has then been correlated with the different fungal assemblages of the samples.

Directional optical transmission through a sand layer: a preliminary laboratory experiment

NASA Astrophysics Data System (ADS)

Tian, Jia; Philpot, William D.

2017-10-01

Given the importance of penetration of light in the soil for seed germination, soil warming, and the photolytic degradation of pesticides, directional transmission of thin sand samples are studied in this paper under both dry and saturated conditions. The detector views upward through a glass-bottom sample holder, filled to 3 or 4 mm with a coarse, translucent, quartz sand sample. Transmission through the samples was measured as the illumination zenith angle moved from 0 to 70° in 5° intervals. In the most cases, transmission decreased monotonically, but slowly with increasing illumination angle at all wavelengths. A peak in transmission only appeared at 0° illumination for the low bulk density, dry sample at 3 mm depth. The 0° peak disappeared when the sample was wetted, when the bulk density increased, or when the depth of the sample increased, which indicates that the radiation transmitting through a sand layer can be diffused thoroughly with a millimeters-thin sand layer. For the saturated samples, water influences light transmission in contrasting ways in shorter and longer wavelength. Transmission increased in the VNIR when saturated relative to dry, while transmission decreased sharply after 1300 nm, with spectral absorption features characteristic of water absorption. In VNIR region, water absorption is low and the low relative index of refraction enhanced transmission through sand sample. In contrast, water absorption became dominant at longer wavelengths region leading to the strongly reduced transmission.

Soil moisture, dielectric permittivity and emissivity of soil: effective depth of emission measured by the L-band radiometer ELBARA

NASA Astrophysics Data System (ADS)

Usowicz, Boguslaw; Lukowski, Mateusz; Marczewski, Wojciech; Usowicz, Jerzy; Lipiec, Jerzy; Rojek, Edyta; Slominska, Ewa; Slominski, Jan

2014-05-01

Due to the large variation of soil moisture in space and in time, obtaining soil water balance with an aid of data acquired from the surface is still a challenge. Microwave remote sensing is widely used to determine the water content in soil. It is based on the fact that the dielectric constant of the soil is strongly dependent on its water content. This method provides the data in both local and global scales. Very important issue that is still not solved, is the soil depth at which radiometer "sees" the incoming radiation and how this "depth of view" depends on water content and physical properties of soil. The microwave emission comes from its entire profile, but much of this energy is absorbed by the upper layers of soil. As a result, the contribution of each layer to radiation visible for radiometer decreases with depth. The thickness of the surface layer, which significantly contributes to the energy measured by the radiometer is defined as the "penetration depth". In order to improve the physical base of the methodology of soil moisture measurements using microwave remote sensing and to determine the effective emission depth seen by the radiometer, a new algorithm was developed. This algorithm determines the reflectance coefficient from Fresnel equations, and, what is new, the complex dielectric constant of the soil, calculated from the Usowicz's statistical-physical model (S-PM) of dielectric permittivity and conductivity of soil. The model is expressed in terms of electrical resistance and capacity. The unit volume of soil in the model consists of solid, water and air, and is treated as a system made up of spheres, filling volume by overlapping layers. It was assumed that connections between layers and spheres in the layer are represented by serial and parallel connections of "resistors" and "capacitors". The emissivity of the soil surface is calculated from the ratio between the brightness temperature measured by the ELBARA radiometer (GAMMA Remote Sensing AG) and the physical temperature of the soil surface measured by infrared sensor. As the input data for S-PM: volumes of soil components, mineralogical composition, organic matter content, specific surface area and bulk density of the soil were used. Water contents in the model are iteratively changed, until emissivities calculated from the S-PM reach the best agreement with emissivities measured by the radiometer. Final water content will correspond to the soil moisture measured by the radiometer. Then, the examined soil profile will be virtually divided into thin slices where moisture, temperature and thermal properties will be measured and simultaneously modelled via S-PM. In the next step, the slices will be "added" starting from top (soil surface), until the effective soil moisture will be equal to the soil moisture measured by ELBARA. The thickness of obtained stack will be equal to desired "penetration depth". Moreover, it will be verified further by measuring the moisture content using thermal inertia. The work was partially funded by the Government of Poland through an ESA Contract under the PECS ELBARA_PD project No. 4000107897/13/NL/KML.

Earth Observations taken by Expedition 38 Crewmember

NASA Image and Video Library

2014-02-14

ISS038-E-047388 (14 Feb. 2014) --- As the International Space Station passed over the deserts of central Iran, including Kavir, one of the Expedition 38 crew members used a digital camera equipped with a 200mm lens to record this image featuring an unusual pattern of numerous parallel lines and sweeping curves. The lack of soil and vegetation allows the geological structure of the rocks to appear quite clearly. According to geologists, the patterns result from the gentle folding of numerous, thin, light and dark layers of rock. Later erosion by wind and water, say the scientists, cut a flat surface across the folds, not only exposing hundreds of layers but also showing the shapes of the folds. The dark water of a lake (image center) occupies a depression in a more easily eroded, S-shaped layer of rock. The irregular light-toned patch just left of the lake is a sand sheet thin enough to allow the underlying rock layers to be detected. A small river snakes across the bottom of the image. In this desert landscape there are no fields or roads to give a sense of scale. In fact, the image width represents a distance of 65 kilometers.

The wettability of selected organic soils in Poland

NASA Astrophysics Data System (ADS)

Całka, A.; Hajnos, M.

2009-04-01

The wettability was measured in the laboratory by means of two methods: Water Drop Penetration Time (WDPT) test and Thin Column Wicking (TCW) method. WDPT is fast and simple method and was used to investigate potential water repellency of analyzed samples. TCW is an indirect method and was used to determine contact angles and surface free energy components. The measurement was performed in horizontal teflon chambers for thin-layer chromatography, adapted for tubes 10 cm long. The experiment was carried out on muck soils (samples were taken from two levels of soil profile: 0-20 cm and 20-40 cm) and peat soils. There were two types of peats: low-moor peats and high moor peats. Samples of low-moor peats were taken from level 25-75 cm (alder peat) and 75-125cm (sedge peat) and 25-75 cm (peloid peat). Samples of high moor peats from level 25-175 cm (sphagnum peat) and 175-225 cm (sphagnum peat with Eriophorum). There was found no variability in persistence of potential water repellency but there were differences in values of contact angles of individual soil samples. Both muck and peat samples are extremely water repellent soils. Water droplets persisted on the surface of soils for more than 24 hours. Contact angles and surface free energy components for all samples were differentiated. Ranges of water contact angles for organic soils are from 27,54o to 96,50o. The highest values of contact angles were for sphagnum peats, and the lowest for muck soil from 20-40 cm level. It means, that there are differences in wettability between these samples. Muck soil is the best wettable and sphagnum peats is the worst wettable soil. If the content of organic compounds in the soil exceeds 40% (like in peats), the tested material displays only dispersion-type interactions. Therefore for peat soils, the technique of thin column wicking could only be used to determine the dispersive component γiLW. For muck soils it was also determined electron-acceptor (Lewis acid) γ+ and electron-donor (Lewis base) γ- surface free energy components. The authors gratefully acknowledge the Ministry of Science and Higher Education for financial support of this work (grant No. N N310 149335).

System for analysis of explosives

DOEpatents

Haas, Jeffrey S [San Ramon, CA

2010-06-29

A system for analysis of explosives. Samples are spotted on a thin layer chromatography plate. Multi-component explosives standards are spotted on the thin layer chromatography plate. The thin layer chromatography plate is dipped in a solvent mixture and chromatography is allowed to proceed. The thin layer chromatography plate is dipped in reagent 1. The thin layer chromatography plate is heated. The thin layer chromatography plate is dipped in reagent 2.

Soil moisture decline due to afforestation across the Loess Plateau, China

NASA Astrophysics Data System (ADS)

Jia, Xiaoxu; Shao, Ming'an; Zhu, Yuanjun; Luo, Yi

2017-03-01

The Loess Plateau of China is a region with one of the most severe cases of soil erosion in the world. Since the 1950s, there has been afforestation measure to control soil erosion and improve ecosystem services on the plateau. However, the introduction of exotic tree species (e.g., R. pseudoacacia, P. tabulaeformis and C. korshinskii) and high-density planting has had a negative effect on soil moisture content (SMC) in the region. Any decrease in SMC could worsen soil water shortage in both the top and deep soil layers, further endangering the sustainability of the fragile ecosystem. This study analyzed the variations in SMC following the conversion of croplands into forests in the Loess Plateau. SMC data within the 5-m soil profile were collected at 50 sites in the plateau region via field survey, long-term in-situ observations and documented literature. The study showed that for the 50 sites, the depth-averaged SMC was much lower under forest than under cropland. Based on in-situ measurements of SMC in agricultural plots and C. korshinskii plots in 2004-2014, SMC in the 0-4 m soil profile in both plots declined significantly (p < 0.01) during the growing season. The rate of decline in SMC in various soil layers under C. korshinskii plots (-0.008 to -0.016 cm3 cm-3 yr-1) was much higher than those under agricultural plots (-0.004 to -0.005 cm3 cm-3 yr-1). This suggested that planting C. korshinskii intensified soil moisture decline in China's Loess Plateau. In the first 20-25 yr of growth, the depth-averaged SMC gradually decreased with stand age in R. pseudoacacia plantation, but SMC somehow recovered with increasing tree age over the 25-year period. Irrespectively, artificial forests consumed more deep soil moisture than cultivated crops in the study area, inducing soil desiccation and dry soil layer formation. Thus future afforestation should consider those species that use less water and require less thinning for sustainable soil conservation without compromising future water resources demands in the Loess Plateau.

Changes in Soil Carbon and Moisture over the Six Year after Thinning of a Natural Oak Forest

NASA Astrophysics Data System (ADS)

Kim, S.; Han, S. H.; Li, G.; Chang, H.; Kim, H. J.; Son, Y.

2017-12-01

The objective of this study was to assess the effects of thinning on soil carbon (C) in a natural oak forest in central Korea. The study forest received three different thinning treatments consisting of un-thinned control (UTC) and two thinning intensities (15% and 30% basal area reductions) in March in 2010. Precipitation near the study forest maintained the normal level from 2010 to 2013 (average 1,400 mm year-1), but abnormally decreased from 2014 to 2016 (average 800 mm year-1). To measure total soil C stock and soil moisture conditions, soils were collected from 0-10, 10-20, and 20-30 cm depths in June, 2010, 2013, and 2016, respectively. Soil microbial biomass C and C-cycling enzymes (β-glucosidase, cellobiohydrolase, β-xylosidase, phenol oxidase, and peroxidase) at 0-10 cm depth were determined in June, 2016. Total soil C stock at 0-30 cm depth increased throughout the study period, whereas soil moisture decreased at all depths from 2013 to 2016. Both thinning treatments had higher total soil C stock at 0-30 cm depth and moisture at 10-20 and 20-30 cm depths than the UTC in 2013 and 2016, whereas the treatments showed no effects in 2010. Microbial biomass C at 0-10 cm depth in 2016 also increased because of the thinning treatments, which was positively correlated to total soil C stock. However, any effects of thinning on C-cycling enzymes were not significant. Our results indicate that thinning could contribute to relieving the impacts of decreasing precipitation by enhancing the storage of soil moisture. Furthermore, the change in total soil C stock under thinning might result from the stimulation of microbial potential for retaining organic C as a form of biomass. This study was supported by the Ministry of Environment (2014001810002) and the National Institute of Forest Science of Korea (FM0101-2009-01).

Soils of Low-Mountain Landscapes of North Karelia

NASA Astrophysics Data System (ADS)

Medvedeva, M. V.; Akhmetova, G. V.; Fedorets, N. G.; Yakovlev, A. S.; Raevskii, B. V.; Travin, V. V.

2018-02-01

Soils of low-mountain landscapes in the northwest of Karelia have been studied. The soil cover of the studied area is mainly represented by Al-Fe-humus soils (Podzols); thin soils (Leptosols) are widespread. Characteristic morphological features of all the studied soils are relatively shallow profiles, high stone content, and underlying by hard bedrock with fine earth material in crevices between large boulders. The studied soils have the high carbon and low nitrogen content, which points to unfavorable conditions of organic matter transformation. The content of most macro- and microelements is not high, which is typical for soils of the region; the content of copper and zinc exceeds the regional background two-three times. Regularities of the vertical zonality in the properties of soils of mountain ecosystems manifest themselves in decreasing thickness of the soil profile at higher altitude above sea level in parallel to decreasing thickness of the layer of loose rocks, while the stone content increases. In soils of the forest-tundra zone, the organomineral horizon with the high organic matter content is formed immediately under the forest litter. The litter horizon is the soils of this zone is characterized by increased concentrations of calcium, magnesium, phosphorus, and zinc.

21 CFR 862.2270 - Thin-layer chromatography system for clinical use.

Code of Federal Regulations, 2010 CFR

2010-04-01

... 21 Food and Drugs 8 2010-04-01 2010-04-01 false Thin-layer chromatography system for clinical use... Instruments § 862.2270 Thin-layer chromatography system for clinical use. (a) Identification. A thin-layer... a mixture. The mixture of compounds is absorbed onto a stationary phase or thin layer of inert...

Predicting surface vibration from underground railways through inhomogeneous soil

NASA Astrophysics Data System (ADS)

Jones, Simon; Hunt, Hugh

2012-04-01

Noise and vibration from underground railways is a major source of disturbance to inhabitants near subways. To help designers meet noise and vibration limits, numerical models are used to understand vibration propagation from these underground railways. However, the models commonly assume the ground is homogeneous and neglect to include local variability in the soil properties. Such simplifying assumptions add a level of uncertainty to the predictions which is not well understood. The goal of the current paper is to quantify the effect of soil inhomogeneity on surface vibration. The thin-layer method (TLM) is suggested as an efficient and accurate means of simulating vibration from underground railways in arbitrarily layered half-spaces. Stochastic variability of the soil's elastic modulus is introduced using a K-L expansion; the modulus is assumed to have a log-normal distribution and a modified exponential covariance kernel. The effect of horizontal soil variability is investigated by comparing the stochastic results for soils varied only in the vertical direction to soils with 2D variability. Results suggest that local soil inhomogeneity can significantly affect surface velocity predictions; 90 percent confidence intervals showing 8 dB averages and peak values up to 12 dB are computed. This is a significant source of uncertainty and should be considered when using predictions from models assuming homogeneous soil properties. Furthermore, the effect of horizontal variability of the elastic modulus on the confidence interval appears to be negligible. This suggests that only vertical variation needs to be taken into account when modelling ground vibration from underground railways.

Method of transferring a thin crystalline semiconductor layer

DOEpatents

Nastasi, Michael A [Sante Fe, NM; Shao, Lin [Los Alamos, NM; Theodore, N David [Mesa, AZ

2006-12-26

A method for transferring a thin semiconductor layer from one substrate to another substrate involves depositing a thin epitaxial monocrystalline semiconductor layer on a substrate having surface contaminants. An interface that includes the contaminants is formed in between the deposited layer and the substrate. Hydrogen atoms are introduced into the structure and allowed to diffuse to the interface. Afterward, the thin semiconductor layer is bonded to a second substrate and the thin layer is separated away at the interface, which results in transferring the thin epitaxial semiconductor layer from one substrate to the other substrate.

Volcanic soils and landslides: a case study of the island of Ischia (southern Italy) and its relationship with other Campania events

NASA Astrophysics Data System (ADS)

Vingiani, S.; Mele, G.; De Mascellis, R.; Terribile, F.; Basile, A.

2015-06-01

An integrated investigation was carried out on the volcanic soils involved in the landslide phenomena that occurred in 2006 at Mt. Vezzi on the island of Ischia (southern Italy). Chemical (soil pH, organic carbon content, exchangeable cations and cation exchange capacity, electrical conductivity, Na adsorption ratio and Al, Fe and Si forms), physical (particle and pore size distribution, pore structure), hydrological (soil water retention, saturated and unsaturated hydraulic conductivity), mineralogical and micromorphological analyses were carried out for three soil profiles selected in two of the main head scarps. The studied soils showed a substantial abrupt discontinuity in all the studied properties at the interface with a buried fine ash layer (namely, the 2C horizon), that was only marginally involved in the sliding surface of the landslide phenomena. When compared to the overlying horizons, 2C showed (i) fine grey ash that is almost pumice free, with the silt content increasing by 20 %; (ii) ks values 1 order of magnitude lower; (iii) a pore distribution concentrated into small (15-30 μm modal class) pores characterised by a very low percolation threshold (approximately 15-25 μm); (iv) the presence of expandable clay minerals; and (v) increasing Na content in the exchange complex. Most of these properties indicated that 2C was a lower permeability horizon compared to the overlying ones. Nevertheless, it was possible to assume this interface to be an impeding layer to vertical water fluxes only by the identification of a thin (6.5 mm) finely stratified ash layer, on top of 2C, and of the hydromorphic features (e.g. Fe / Mn concretions) within and on top of the layer. Although Mt. Vezzi's soil environment has many properties in common with those of other Campania debris-mudflows (e.g. high gradient, north-facing slope, similar forestry, and volcanic origin of the parent material), the results of this study suggest a more complex relationship between soil properties and landslides and emphasise the role of vertical discontinuities as noteworthy predisposing factors.

Taxonomic and environmental soil diversity of marine terraces of Gronfjord (West Spitsbergen island)

NASA Astrophysics Data System (ADS)

Alekseev, Ivan; Abakumov, Evgeny

2017-04-01

Soil surveys in polar region are faced to problems of soil diagnostics, evolution, geography and pedogenesis with the aim to assess the actual state and future dynamics of soil cover under changing environmental conditions. This investigation is devoted to specification of taxonomic and environmental soil diversity of marine terraces of Gronfjord (Svalbard archipelago, West Spitsbergen Island). It was established 3 key plots (Grendasselva, Aldegonda rivers and marine terrace in surroundings of Barentsburg aerodrome). Soil diagnostics was carried out according to Russian soil classification system and WRB. Grendasselva river valley is characterized by numerous patterned ground elements combined with lichen-moss and moss-lichen patches with sporadic inclusions of higher plants (mostly Lusula pilosa). Soil cover is represented by Typic Cryosols on elevated sites and Histic Gleysols, Turbic Gleysols and Histosols on well-drained boggy sites. Aldegonda river valley characterizes by predominance of entic soils (soil with non-pronounced profile differentiation) on moraine material (mostly Cryic Leptosols). Vegetation is presented by sporadic plant communities comprised by Lusula pilosa and thin lichen-moss ground layer (developed only in well-moistened micro depression). Marine terrace in surroundings of Barentsburg aerodrome is covered by moss-lichen tundra with sporadic inclusions of Lusula pilosa. On the top of the terrace compressed barren circles are quite abundant. Soil catena has been established within this key plot. Soil types are represented by Typic Cryosols in watershed parts of catena, Gleysols and Histic Gleysols in accumulation positions. The active layer depths have been distinguished using vertical electrical sounding. They ranged from 80-90 cm at Grendasselva and Aldegonda river key plot to 140-150 cm at marine terrace in surroundings of Barentsburg aerodrome. Regional differences in this indicator may be explained not only by local differences in thermal regime of soil and permafrost layers, but also by different ways of anthropogenic forcing on studied key plots. Spatial differentiation of soil types within the studied area is caused mainly by relief conditions (since it determines moisture conditions and gleyzation rates especially) and parent materials. Cryogenic mass transfer, cryoturbations and degree of their manifestation in studied soils depend on active layer thickness and also varies significantly. This study was conducted in cooperation with Arctic and Antarctic Research Institute (Saint Petersburg, Russia) and supported by Russian Foundation for basic research, grant 16-34-60010, Russian presidents' grant for Young Doctors of Science № MD-3615.2015.4.

Effect of soil-rock system on speleothems weathering in Bailong Cave, Yunnan Province, China*

PubMed Central

Wang, Jing; Song, Lin-hua

2005-01-01

Bailong Cave with its well-developed Middle Triassic calcareous dolomite’s system was opened as a show cave for visitors in 1988. The speleothem scenery has been strongly weathered as white powder on the outer layers. Study of the cave winds, permeability of soil-rock system and the chemical compositions of the dripping water indicated: (1) The cave dimension structure distinctively affects the cave winds, which were stronger at narrow places. (2) Based on the different soil grain size distribution, clay was the highest in composition in the soil. The response sense of dripping water to the rainwater percolation was slow. The density of joints and other openings in dolomite make the dolomite as mesh seepage body forming piles of thin and high columns and stalactites. (3) Study of 9 dripping water samples by HYDROWIN computer program showed that the major mineral in the water was dolomite. PMID:15682505

Effect of soil-rock system on speleothems weathering in Bailong Cave, Yunnan Province, China.

PubMed

Wang, Jing; Song, Lin-Hua

2005-03-01

Bailong Cave with its well-developed Middle Triassic calcareous dolomite's system was opened as a show cave for visitors in 1988. The speleothem scenery has been strongly weathered as white powder on the outer layers. Study of the cave winds, permeability of soil-rock system and the chemical compositions of the dripping water indicated: (1) The cave dimension structure distinctively affects the cave winds, which were stronger at narrow places. (2) Based on the different soil grain size distribution, clay was the highest in composition in the soil. The response sense of dripping water to the rainwater percolation was slow. The density of joints and other openings in dolomite make the dolomite as mesh seepage body forming piles of thin and high columns and stalactites. (3) Study of 9 dripping water samples by HYDROWIN computer program showed that the major mineral in the water was dolomite.

The stability of ground ice in the equatorial region of Mars

NASA Technical Reports Server (NTRS)

Clifford, S. M.; Hillel, D.

1983-01-01

The lifetime of an unreplenished layer of ground ice lying within 30 deg of the Martian equator was examined within the context of the existing data base on Martian regolith and climate. Data on the partial pressure of H2O in the Martian atmosphere and the range of mean annual temperatures indicated the ground ice would be restricted to latitudes poleward of 40 deg. However, the ground ice near the poles may be a relic from early Martian geologic times held in place by a thin layer of regolith. Consideration of twelve model pore size distributions, similar to silt- and clay-type earth soils, was combined with a parallel pore model of gaseous diffusion to calculate the flux of H2O molecules escaping from the subsurface ground ice layer. Martian equatorial ground ice was found to be influenced by the soil structure, the magnitude of the geothermal gradient, the climatic desorption of CO2 from the regolith. It is concluded that equatorial ground ice is present on Mars only if a process of replenishment is active.

Triboelectric generator

DOEpatents

Wang, Zhong L; Fan, Fengru; Lin, Long; Zhu, Guang; Pan, Caofeng; Zhou, Yusheng

2015-11-03

A generator includes a thin first contact charging layer and a thin second contact charging layer. The thin first contact charging layer includes a first material that has a first rating on a triboelectric series. The thin first contact charging layer has a first side with a first conductive electrode applied thereto and an opposite second side. The thin second contact charging layer includes a second material that has a second rating on a triboelectric series that is more negative than the first rating. The thin first contact charging layer has a first side with a first conductive electrode applied thereto and an opposite second side. The thin second contact charging layer is disposed adjacent to the first contact charging layer so that the second side of the second contact charging layer is in contact with the second side of the first contact charging layer.

Topographic imprint on chemical weathering in deeply weathered soil-mantled landscapes (southern Brazil)

NASA Astrophysics Data System (ADS)

Vanacker, Veerle; Schoonejans, Jerome; Ameijeiras-Marino, Yolanda; Opfergelt, Sophie; Minella, Jean

2017-04-01

The regolith mantle is defined as the thin layer of unconsolidated material overlaying bedrock that contributes to shape the Earth's surface. The development of the regolith mantle in a landscape is the result of in-situ weathering, atmospheric input and downhill transport of weathering products. Bedrock weathering - the physical and chemical transformations of rock to soil - contributes to the vertical development of the regolith layer through downward propagation of the weathering front. Lateral transport of soil particles, aggregates and solutes by diffusive and concentrated particle and solute fluxes result in lateral redistribution of weathering products over the hillslope. In this study, we aim to expand the empirical basis on long-term soil evolution at the landscape scale through a detailed study of soil weathering in subtropical soils. Spatial variability in chemical mass fluxes and weathering intensity were studied along two toposequences with similar climate, lithology and vegetation but different slope morphology. This allowed us to isolate the topographic imprint on chemical weathering and soil development. The toposequences have convexo-concave slope morphology, and eight regolith profiles were analysed involving the flat upslope, steep midslope and flat toeslope part. Our data show a clear topographic imprint on soil development. Along hillslope, the chemical weathering intensity of the regolith profiles increases with distance from the crest. In contrast to the upslope positions, the soils in the basal concavities develop on in-situ and transported regolith. While the chemical weathering extent on the slope convexities (the upslope profiles) is similar for the steep and gentle toposequence, there is a clear difference in the rate of increase of the chemical weathering extent with distance from the crest. The increase of chemical weathering extent along hillslope is highest for the steep toposequence, suggesting that topography enhances soil particle, aggregate and solute fluxes.

Nutrient status of the lowbush blueberry, Lac-Saint-Jean area, Quebec, Canada. [Vaccinium angustifolium

DOE Office of Scientific and Technical Information (OSTI.GOV)

Bouchard, A.R.; Gagnon, M.J.

1987-01-01

The lowbush blueberry (Vaccinium angustifolium Ait.) is an important commercial crop of the Lac-Saint-Jean area (Quebec, Canada). The major blueberry fields are located on sandy soils relatively poor in available mineral nutrients. The nutrients originate from a thin organic layer found on the top of these sandy soils. The leaf mineral contents (N, P, K, Mg, Ca, Mn, Fe, Cu, Zn and B) were measured in five blueberry fields during 1984 and 1985. Soil pH and soil available P, K, and Mg were also assessed. The results show that the leaf mineral contents are generally adequate. However, K and Znmore » might be occasionally deficient when compared to the actual established standards. The available Mg in soil was significantly correlated with the leaf Mg concentration. The data also suggest that the influence of the pH following the burn pruning seems to influence the nutrition of this species.« less

Wildfire mitigation strategies affect soil enzyme activity and soil organic carbon in loblolly pine (Pinus taeda) forests

Treesearch

R.E.J. Boerner; T.A. Waldrop; V.B. Shelburne

2006-01-01

We quantified the effects of three wildfire hazard reduction treatments (prescribed fire, thinning from below, and the combination of fire and thinning), and passive management (control) on mineral soil organic C, and enzyme activity in loblolly pine (Pinus taeda L.) forests on the Piedmont of South Carolina. Soil organic C was reduced by thinning,...

DOE Office of Scientific and Technical Information (OSTI.GOV)

Kebede, Mulu A.; Bish, David L.; Losovyj, Yaroslav

Nitrous acid (HONO) accumulates in the nocturnal boundary layer where it is an important source of daytime hydroxyl radicals. Although there is clear evidence for the involvement of heterogeneous reactions of NO2 on surfaces as a source of HONO, mechanisms remain poorly understood. We used coated-wall flow tube measurements of NO2 reactivity on environmentally relevant surfaces [Fe (hydr)oxides, clay minerals, and soil from Arizona and the Saharan Desert] and detailed mineralogical characterization of substrates to show that reduction of NO2 by Fe-bearing minerals in soil can be a more important source of HONO than the putative NO2 hydrolysis mechanism. Themore » magnitude of NO2-to-HONO conversion depends on the amount of Fe2+ present in substrates and soil surface acidity. Studies examining the dependence of HONO flux on substrate pH revealed that HONO is formed at soil pH < 5 from the reaction between NO2 and Fe2+(aq) present in thin films of water coating the surface, whereas in the range of pH 5–8 HONO stems from reaction of NO2 with structural iron or surface complexed Fe2+ followed by protonation of nitrite via surface Fe-OH2+ groups. Reduction of NO2 on ubiquitous Fe-bearing minerals in soil may explain HONO accumulation in the nocturnal boundary layer and the enhanced [HONO]/[NO2] ratios observed during dust storms in urban areas.« less

The Role of Iron-Bearing Minerals in NO2 to HONO Conversion on Soil Surfaces.

PubMed

Kebede, Mulu A; Bish, David L; Losovyj, Yaroslav; Engelhard, Mark H; Raff, Jonathan D

2016-08-16

Nitrous acid (HONO) accumulates in the nocturnal boundary layer where it is an important source of daytime hydroxyl radicals. Although there is clear evidence for the involvement of heterogeneous reactions of NO2 on surfaces as a source of HONO, mechanisms remain poorly understood. We used coated-wall flow tube measurements of NO2 reactivity on environmentally relevant surfaces (Fe (hydr)oxides, clay minerals, and soil from Arizona and the Saharan Desert) and detailed mineralogical characterization of substrates to show that reduction of NO2 by Fe-bearing minerals in soil can be a more important source of HONO than the putative NO2 hydrolysis mechanism. The magnitude of NO2-to-HONO conversion depends on the amount of Fe(2+) present in substrates and soil surface acidity. Studies examining the dependence of HONO flux on substrate pH revealed that HONO is formed at soil pH < 5 from the reaction between NO2 and Fe(2+)(aq) present in thin films of water coating the surface, whereas in the range of pH 5-8 HONO stems from reaction of NO2 with structural iron or surface complexed Fe(2+) followed by protonation of nitrite via surface Fe-OH2(+) groups. Reduction of NO2 on ubiquitous Fe-bearing minerals in soil may explain HONO accumulation in the nocturnal boundary layer and the enhanced [HONO]/[NO2] ratios observed during dust storms in urban areas.

Low stress polysilicon film and method for producing same

NASA Technical Reports Server (NTRS)

Heuer, Arthur H. (Inventor); Kahn, Harold (Inventor); Yang, Jie (Inventor)

2001-01-01

Multi-layer assemblies of polysilicon thin films having predetermined stress characteristics and techniques for forming such assemblies are disclosed. In particular, a multi-layer assembly of polysilicon thin film may be produced that has a stress level of zero, or substantially so. The multi-layer assemblies comprise at least one constituent thin film having a tensile stress and at least one constituent thin film having a compressive stress. The thin films forming the multi-layer assemblies may be disposed immediately adjacent to one another without the use of intermediate layers between the thin films.

Low stress polysilicon film and method for producing same

NASA Technical Reports Server (NTRS)

Heuer, Arthur H. (Inventor); Kahn, Harold (Inventor); Yang, Jie (Inventor)

2002-01-01

Multi-layer assemblies of polysilicon thin films having predetermined stress characteristics and techniques for forming such assemblies are disclosed. In particular, a multi-layer assembly of polysilicon thin film may be produced that has a stress level of zero, or substantially so. The multi-layer assemblies comprise at least one constituent thin film having a tensile stress and at least one constituent thin film having a compressive stress. The thin films forming the multi-layer assemblies may be disposed immediately adjacent to one another without the use of intermediate layers between the thin films.

[Dynamics of Quercus variabilis seed rain and soil seed bank in different habitats on the north slope of Qinling Mountains].

PubMed

Wu, Min; Zhang, Wen-Hui; Zhou, Jian-Yun; Ma, Chuang; Ma, Li-Wei

2011-11-01

In order to explore the dynamics of Quercus variabilis seed rain and soil seed bank in different habitats on the north slope of Qinling Mountains, three kinds of micro-habitats (understory, forest gap, and forest edge) were selected, with the seed rain quantity and quality of Q. variabilis, seed amount and viability in soil seed bank, as well as the seedling development of Q. variabilis studied. The seed rain of Q. variabilis started from mid August, reached the peak in mid September-early October, and ended at the beginning of November, and there existed differences in the dissemination process, occurrence time, and composition of the seed rain among the three micro-habitats. The seed rain had the maximum intensity (39.55 +/- 5.56 seeds x m(-2)) in understory, the seeds had the earliest landing time, the longest lasting duration, and the highest viability in forest gap, and the mature seeds had the largest proportion in forest edge, accounting for 58.7% of the total. From the ending time of seed rain to next August, the total reserve of soil seed bank was the largest in understory and the smallest in forest edge. In the three habitats, the amount of mature and immature seeds, that of seeds eaten by animals, and the seed viability in soil seed bank all decreased with time. In contrast, the number of moldy seeds increased. The seeds were mainly concentrated in litter layer, a few of them were in 0-2 cm soil layer, and few were in 2-5 cm soil layer. The density of the seedlings varied with habitats, being the largest in forest gap, followed by in forest edge, and the least in understory, which suggested that forest gap was more suitable for the seed germination and seedling growth of Q. variabilis, and thus, appropriate thinning should be taken to increase forest gap to provide favorable conditions for the natural regeneration of Q. variabilis forest.

Boreal Forest Permafrost Sensitivity Ecotypes to changes in Snow Depth and Soil Moisture

NASA Astrophysics Data System (ADS)

Dabbs, A.; Romanovsky, V. E.; Kholodov, A. L.

2017-12-01

Changes in the global climate, pronounced especially in polar regions due to their accelerated warming, are expected by many global climate models to have large impacts on the moisture budget throughout the world. Permafrost extent and the soil temperature regime are both strongly dependent on soil moisture and snow depth because of their immense effects on the thermal properties of the soil column and surface energy balance respectively. To assess how the ground thermal regime at various ecotypes may react to a change in the moisture budget, we performed a sensitivity analysis using the Geophysical Institute Permafrost Laboratory model, which simulates subsurface temperature dynamics by solving a one-dimensional nonlinear heat equation with phase change. We used snow depth and air temperature data from the Fairbanks International Airport meteorological station as forcing for this sensitivity analysis. We looked at five different ecotypes within the boreal forest region of Alaska: mixed, deciduous and black forests, willow shrubs and tundra. As a result of this analysis, we found that ecotypes with higher soil moisture contents, such as willow shrubs, are most sensitive to changes in snow depth due to the larger amount of latent heat trapped underneath the snow during the freeze up of active layer. In addition, soil within these ecotypes has higher thermal conductivity due to high saturation degree allowing for deeper seasonal freezing. Also, we found that permafrost temperatures were most sensitive to changes in soil moisture in ecotypes that were not completely saturated such as boreal forest. These ecotypes lacked complete saturation because of thick organic layers that have very high porosities or partially drained mineral soils. Contrarily, tundra had very little response to changes in soil moisture due to its thin organic layer and almost completely saturated soil column. This difference arises due to the disparity between the frozen and unfrozen thermal conductivities of the soil. In highly saturated soils, the frozen thermal conductivity of the soil can be more than double that of the unfrozen thermal conductivity while in dryer soils that ratio reduces down to less than 1.5. This difference allows the seasonal freezing to penetrate quicker and deeper causing even more latent heat to be released and trapped.

Patch testing with thin-layer chromatograms of chamomile tea in patients allergic to sesquiterpene lactones.

PubMed

Lundh, Kerstin; Gruvberger, Birgitta; Möller, Halvor; Persson, Lena; Hindsén, Monica; Zimerson, Erik; Svensson, Ake; Bruze, Magnus

2007-10-01

Patients with contact allergy to sesquiterpene lactones (SLs) are usually hypersensitive to Asteraceae plant products such as herbal teas. The objective of this study was to show sensitizers in chamomile tea by patch testing with thin-layer chromatograms. Tea made from German chamomile was separated by thin-layer chromatography. Strips of the thin-layer chromatograms were used for patch testing SL-positive patients. 15 (43%) of 35 patients tested positively to 1 or more spots on the thin-layer chromatogram, with many individual reaction patterns. Patch testing with thin-layer chromatograms of German chamomile tea showed the presence of several allergens.

A passive air sampler for characterizing the vertical concentration profile of gaseous phase polycyclic aromatic hydrocarbons in near soil surface air.

PubMed

Zhang, Yuzhong; Deng, Shuxing; Liu, Yanan; Shen, Guofeng; Li, Xiqing; Cao, Jun; Wang, Xilong; Reid, Brian; Tao, Shu

2011-03-01

Air-soil exchange is an important process governing the fate of polycyclic aromatic hydrocarbons (PAHs). A novel passive air sampler was designed and tested for measuring the vertical concentration profile of 4 low molecular weight PAHs in gaseous phase (PAH(LMW4)) in near soil surface air. Air at various heights from 5 to 520 mm above the ground was sampled by polyurethane foam disks held in down-faced cartridges. The samplers were tested at three sites: A: an extremely contaminated site, B: a site near A, and C: a background site on a university campus. Vertical concentration gradients were revealed for PAH(LMW4) within a thin layer close to soil surface at the three sites. PAH concentrations either decreased (Site A) or increased (Sites B and C) with height, suggesting either deposition to or evaporation from soils. The sampler is a useful tool for investigating air-soil exchange of gaseous phase semi-volatile organic chemicals. Copyright © 2010 Elsevier Ltd. All rights reserved.

Amorphous silicon Schottky barrier solar cells incorporating a thin insulating layer and a thin doped layer

DOEpatents

Carlson, David E.

1980-01-01

Amorphous silicon Schottky barrier solar cells which incorporate a thin insulating layer and a thin doped layer adjacent to the junction forming metal layer exhibit increased open circuit voltages compared to standard rectifying junction metal devices, i.e., Schottky barrier devices, and rectifying junction metal insulating silicon devices, i.e., MIS devices.

Method for collecting spores from a mold

DOEpatents

Au, Frederick H. F.; Beckert, Werner F.

1977-01-01

A technique and apparatus used therewith for determining the uptake of plutonium and other contaminants by soil microorganisms which, in turn, gives a measure of the plutonium and/or other contaminants available to the biosphere at that particular time. A measured quantity of uncontaminated spores of a selected mold is added to a moistened sample of the soil to be tested. The mixture is allowed to sit a predetermined number of days under specified temperature conditions. An agar layer is then applied to the top of the sample. After three or more days, when spores of the mold growing in the sample have formed, the spores are collected by a miniature vacuum collection apparatus operated under preselected vacuum conditions, which collect only the spores with essentially no contamination by mycelial fragments or culture medium. After collection, the fungal spores are dried and analyzed for the plutonium and/or other contaminants. The apparatus is also suitable for collection of pollen, small insects, dust and other small particles, material from thin-layer chromatography plates, etc.

System for sampling and monitoring microscopic organisms and substances

DOEpatents

Au, Frederick H. F.; Beckert, Werner F.

1976-01-01

A technique and apparatus used therewith for determining the uptake of plutonium and other contaminants by soil microorganisms which, in turn, gives a measure of the plutonium and/or other contaminants available to the biosphere at that particular time. A measured quantity of uncontaminated spores of a selected mold is added to a moistened sample of the soil to be tested. The mixture is allowed to sit a predetermined number of days under specified temperature conditions. An agar layer is then applied to the top of the sample. After three or more days, when spores of the mold growing in the sample have formed, the spores are collected by a miniature vacuum collection apparatus operated under preselected vacuum conditions, which collect only the spores with essentially no contamination by mycelial fragments or culture medium. After collection, the fungal spores are dried and analyzed for the plutonium and/or other contaminants. The apparatus is also suitable for collection of pollen, small insects, dust and other small particles, material from thin-layer chromatography plates, etc.

Anti-reflection coatings applied by acid leaching process

NASA Technical Reports Server (NTRS)

Pastirik, E.

1980-01-01

The Magicote C process developed by S.M. Thompsen was evaluated for use in applying an antireflective coating to the cover plates of solar panels. The process uses a fluosilicic acid solution supersaturated with silica at elevated temperature to selectively attack the surface of soda-lime glass cover plates and alter the physical and chemical composition of a thin layer of glass. The altered glass layer constitutes an antireflective coating. The process produces coatings of excellent optical quality which possess outstanding resistance to soiling and staining. The coatings produced are not resistant to mechanical abrasion and are attacked to some extent by glass cleansers. Control of the filming process was found to be difficult.

Linear modeling of the soil-water partition coefficient normalized to organic carbon content by reversed-phase thin-layer chromatography.

PubMed

Andrić, Filip; Šegan, Sandra; Dramićanin, Aleksandra; Majstorović, Helena; Milojković-Opsenica, Dušanka

2016-08-05

Soil-water partition coefficient normalized to the organic carbon content (KOC) is one of the crucial properties influencing the fate of organic compounds in the environment. Chromatographic methods are well established alternative for direct sorption techniques used for KOC determination. The present work proposes reversed-phase thin-layer chromatography (RP-TLC) as a simpler, yet equally accurate method as officially recommended HPLC technique. Several TLC systems were studied including octadecyl-(RP18) and cyano-(CN) modified silica layers in combination with methanol-water and acetonitrile-water mixtures as mobile phases. In total 50 compounds of different molecular shape, size, and various ability to establish specific interactions were selected (phenols, beznodiazepines, triazine herbicides, and polyaromatic hydrocarbons). Calibration set of 29 compounds with known logKOC values determined by sorption experiments was used to build simple univariate calibrations, Principal Component Regression (PCR) and Partial Least Squares (PLS) models between logKOC and TLC retention parameters. Models exhibit good statistical performance, indicating that CN-layers contribute better to logKOC modeling than RP18-silica. The most promising TLC methods, officially recommended HPLC method, and four in silico estimation approaches have been compared by non-parametric Sum of Ranking Differences approach (SRD). The best estimations of logKOC values were achieved by simple univariate calibration of TLC retention data involving CN-silica layers and moderate content of methanol (40-50%v/v). They were ranked far well compared to the officially recommended HPLC method which was ranked in the middle. The worst estimates have been obtained from in silico computations based on octanol-water partition coefficient. Linear Solvation Energy Relationship study revealed that increased polarity of CN-layers over RP18 in combination with methanol-water mixtures is the key to better modeling of logKOC through significant diminishing of dipolar and proton accepting influence of the mobile phase as well as enhancing molar refractivity in excess of the chromatographic systems. Copyright © 2016 Elsevier B.V. All rights reserved.

Long-term effect of silvicultural thinnings on soil carbon and nitrogen pools

Treesearch

Martin Jurgensen; Rachel Tarpey; Jim Pickens; Randy Kolka; Brian Palik

2012-01-01

The effects of long-term silvicultural thinning on soil C and N content are not well known. We evaluated the impact of periodic thinnings on soil C and N pools in a 134-yr-old red pine (Pinus resinosa Ait.) forest in Minnesota, and a 104 yr-old northern hardwood forest in Wisconsin. The red pine stands had five thinning regimes (13.8, 18.4, 22.7, 27....

Effects of channel thickness on oxide thin film transistor with double-stacked channel layer

NASA Astrophysics Data System (ADS)

Lee, Kimoon; Kim, Yong-Hoon; Yoon, Sung-Min; Kim, Jiwan; Oh, Min Suk

2017-11-01

To improve the field effect mobility and control the threshold voltage ( V th ) of oxide thin film transistors (TFTs), we fabricated the oxide TFTs with double-stacked channel layers which consist of thick Zn-Sn-O (ZTO) and very thin In-Zn-O (IZO) layers. We investigated the effects of the thickness of thin conductive layer and the conductivity of thick layer on oxide TFTs with doublestacked channel layer. When we changed the thickness of thin conductive IZO channel layer, the resistivity values were changed. This resistivity of thin channel layer affected on the saturation field effect mobility and the off current of TFTs. In case of the thick ZTO channel layer which was deposited by sputtering in Ar: O2 = 10: 1, the device showed better performances than that which was deposited in Ar: O2 = 1: 1. Our TFTs showed high mobility ( μ FE ) of 40.7 cm2/Vs and V th of 4.3 V. We assumed that high mobility and the controlled V th were caused by thin conductive IZO layer and thick stable ZTO layer. Therefore, this double-stacked channel structure can be very promising way to improve the electrical characteristics of various oxide thin film transistors.

Depositing bulk or micro-scale electrodes

DOEpatents

Shah, Kedar G.; Pannu, Satinderpall S.; Tolosa, Vanessa; Tooker, Angela C.; Sheth, Heeral J.; Felix, Sarah H.; Delima, Terri L.

2016-11-01

Thicker electrodes are provided on microelectronic device using thermo-compression bonding. A thin-film electrical conducting layer forms electrical conduits and bulk depositing provides an electrode layer on the thin-film electrical conducting layer. An insulating polymer layer encapsulates the electrically thin-film electrical conducting layer and the electrode layer. Some of the insulating layer is removed to expose the electrode layer.

Method for bonding thin film thermocouples to ceramics

DOEpatents

Kreider, Kenneth G.

1993-01-01

A method is provided for adhering a thin film metal thermocouple to a ceramic substrate used in an environment up to 700 degrees Centigrade, such as at a cylinder of an internal combustion engine. The method includes the steps of: depositing a thin layer of a reactive metal on a clean ceramic substrate; and depositing thin layers of platinum and a platinum-10% rhodium alloy forming the respective legs of the thermocouple on the reactive metal layer. The reactive metal layer serves as a bond coat between the thin noble metal thermocouple layers and the ceramic substrate. The thin layers of noble metal are in the range of 1-4 micrometers thick. Preferably, the ceramic substrate is selected from the group consisting of alumina and partially stabilized zirconia. Preferably, the thin layer of reactive metal is in the range of 0.015-0.030 micrometers (15-30 nanometers) thick. The preferred reactive metal is chromium. Other reactive metals may be titanium or zirconium. The thin layer of reactive metal may be deposited by sputtering in ultra high purity argon in a vacuum of approximately 2 milliTorr (0.3 Pascals).

Multi-layer assemblies with predetermined stress profile and method for producing same

NASA Technical Reports Server (NTRS)

Heuer, Arthur H. (Inventor); Kahn, Harold (Inventor); Yang, Jie (Inventor); Phillips, Stephen M. (Inventor)

2003-01-01

Multi-layer assemblies of polysilicon thin films having predetermined stress characteristics and techniques for forming such assemblies are disclosed. In particular, a multi-layer assembly of polysilicon thin films may be produced that has a stress level of zero, or substantially so. The multi-layer assemblies comprise at least one constituent thin film having a tensile stress and at least one constituent thin film having a compressive stress. The thin films forming the multi-layer assemblies may be disposed immediately adjacent to one another without the use of intermediate layers between the thin films. Multi-layer assemblies exhibiting selectively determinable overall bending moments are also disclosed. Selective production of overall bending moments in microstructures enables manufacture of such structures with a wide array of geometrical configurations.

Optical Properties of Hybrid Inorganic/Organic Thin Film Encapsulation Layers for Flexible Top-Emission Organic Light-Emitting Diodes.

PubMed

An, Jae Seok; Jang, Ha Jun; Park, Cheol Young; Youn, Hongseok; Lee, Jong Ho; Heo, Gi-Seok; Choi, Bum Ho; Lee, Choong Hun

2015-10-01

Inorganic/organic hybrid thin film encapsulation layers consist of a thin Al2O3 layer together with polymer material. We have investigated optical properties of thin film encapsulation layers for top-emission flexible organic light-emitting diodes. The transmittance of hybrid thin film encapsulation layers and the electroluminescent spectrum of organic light-emitting diodes that were passivated by hybrid organic/inorganic thin film encapsulation layers were also examined as a function of the thickness of inorganic Al203 and monomer layers. The number of interference peaks, their intensity, and their positions in the visible range can be controlled by varying the thickness of inorganic Al2O3 layer. On the other hand, changing the thickness of monomer layer had a negligible effect on the optical properties. We also verified that there is a trade-off between transparency in the visible range and the permeation of water vapor in hybrid thin film encapsulation layers. As the number of dyads decreased, optical transparency improved while the water vapor permeation barrier was degraded. Our study suggests that, in top-emission organic light-emitting diodes, the thickness of each thin film encapsulation layer, in particular that of the inorganic layer, and the number of dyads should be controlled for highly efficient top-emission flexible organic light-emitting diodes.

Composite polymeric film and method for its use in installing a very-thin polymeric film in a device

DOEpatents

Duchane, D.V.; Barthell, B.L.

1982-04-26

A composite polymeric film and a method for its use in forming and installing a very thin (< 10 ..mu..m) polymeric film are disclosed. The composite film consists of a thin film layer and a backing layer. The backing layer is soluble in a solvent in which the thin film layer is not soluble. In accordance with the method, the composite film is installed in a device in the same position in which it is sought to finally emplace the thin film. The backing layer is then selectiely dissolved in the solvent to leave the insoluble thin film layer as an unbacked film. The method permits a very thin film to e successfully installed in devices where the fragility of the film would preclude handling and installation by conventional methods.

Composite polymeric film and method for its use in installing a very thin polymeric film in a device

DOEpatents

Duchane, David V.; Barthell, Barry L.

1984-01-01

A composite polymeric film and a method for its use in forming and installing a very thin (<10 .mu.m) polymeric film are disclosed. The composite film consists of a thin film layer and a backing layer. The backing layer is soluble in a solvent in which the thin film layer is not soluble. In accordance with the method, the composite film is installed in a device in the same position in which it is sought to finally emplace the thin film. The backing layer is then selectively dissolved in the solvent to leave the insoluble thin film layer as an unbacked film. The method permits a very thin film to be successfully installed in devices where the fragility of the film would preclude handling and installation by conventional methods.

Spatial arrangement of organic compounds on a model mineral surface: implications for soil organic matter stabilization.

PubMed

Petridis, Loukas; Ambaye, Haile; Jagadamma, Sindhu; Kilbey, S Michael; Lokitz, Bradley S; Lauter, Valeria; Mayes, Melanie A

2014-01-01

The complexity of the mineral-organic carbon interface may influence the extent of stabilization of organic carbon compounds in soils, which is important for global climate futures. The nanoscale structure of a model interface was examined here by depositing films of organic carbon compounds of contrasting chemical character, hydrophilic glucose and amphiphilic stearic acid, onto a soil mineral analogue (Al2O3). Neutron reflectometry, a technique which provides depth-sensitive insight into the organization of the thin films, indicates that glucose molecules reside in a layer between Al2O3 and stearic acid, a result that was verified by water contact angle measurements. Molecular dynamics simulations reveal the thermodynamic driving force behind glucose partitioning on the mineral interface: The entropic penalty of confining the less mobile glucose on the mineral surface is lower than for stearic acid. The fundamental information obtained here helps rationalize how complex arrangements of organic carbon on soil mineral surfaces may arise.

Out-of-plane (SH) soil-structure interaction: a shear wall with rigid and flexible ring foundation

NASA Astrophysics Data System (ADS)

Le, Thang; Lee, Vincent W.; Luo, Hao

2016-02-01

Soil-structure interaction (SSI) of a building and shear wall above a foundation in an elastic half-space has long been an important research subject for earthquake engineers and strong-motion seismologists. Numerous papers have been published since the early 1970s; however, very few of these papers have analytic closed-form solutions available. The soil-structure interaction problem is one of the most classic problems connecting the two disciplines of earthquake engineering and civil engineering. The interaction effect represents the mechanism of energy transfer and dissipation among the elements of the dynamic system, namely the soil subgrade, foundation, and superstructure. This interaction effect is important across many structure, foundation, and subgrade types but is most pronounced when a rigid superstructure is founded on a relatively soft lower foundation and subgrade. This effect may only be ignored when the subgrade is much harder than a flexible superstructure: for instance a flexible moment frame superstructure founded on a thin compacted soil layer on top of very stiff bedrock below. This paper will study the interaction effect of the subgrade and the superstructure. The analytical solution of the interaction of a shear wall, flexible-rigid foundation, and an elastic half-space is derived for incident SH waves with various angles of incidence. It found that the flexible ring (soft layer) cannot be used as an isolation mechanism to decouple a superstructure from its substructure resting on a shaking half-space.

History and anatomy of subsurface ice on Mars

NASA Astrophysics Data System (ADS)

Schorghofer, Norbert; Forget, Francois

2012-08-01

Ice buried beneath a thin layer of soil has been revealed by neutron spectroscopy and explored by the Phoenix Mars Lander. It has also been exposed by recent impacts. This subsurface ice is thought to lose and gain volume in response to orbital variations (Milankovitch cycles). We use a powerful numerical model to follow the growth and retreat of near-surface ice as a result of regolith-atmosphere exchange continuously over millions of years. If a thick layer of almost pure ice has been deposited recently, it has not yet reached equilibrium with the atmospheric water vapor and may still remain as far equatorward as 43°N, where ice has been revealed by recent impacts. A potentially observable consequence is present-day humidity output from the still retreating ice. We also demonstrate that in a sublimation environment, subsurface pore ice can accumulate in two ways. The first mode, widely known, is the progressive filling of pores by ice over a range of depths. The second mode occurs on top of an already impermeable ice layer; subsequent ice accumulates in the form of pasted on horizontal layers such that beneath the ice table, the pores are completely full with ice. Most or all of the pore ice on Mars today may be of the second type. At the Phoenix landing site, where such a layer is also expected to exist above an underlying ice sheet, it may be extremely thin, due to exceptionally small variations in ice stability over time.

Multi-layered, chemically bonded lithium-ion and lithium/air batteries

DOEpatents

Narula, Chaitanya Kumar; Nanda, Jagjit; Bischoff, Brian L; Bhave, Ramesh R

2014-05-13

Disclosed are multilayer, porous, thin-layered lithium-ion batteries that include an inorganic separator as a thin layer that is chemically bonded to surfaces of positive and negative electrode layers. Thus, in such disclosed lithium-ion batteries, the electrodes and separator are made to form non-discrete (i.e., integral) thin layers. Also disclosed are methods of fabricating integrally connected, thin, multilayer lithium batteries including lithium-ion and lithium/air batteries.

Ecosystem restoration treatments affect soil physical and chemical properties in Appalachian mixed oak forests

Treesearch

Ralph E.J. Boerner; Jennifer a. Brinkman; Daniel A. Yaussy

2007-01-01

This study presents an analysis of the effect of ecosystem restoration treatments on soil properties in the oak forests of southern Ohio. The treatments were (1) prescribed fire, (2) mechanical thinning, (3) fire and thinning, and (4) passive management (control). Fire and thinning resulted in increased mineral soil exposure, with the effect decreasing by the fourth...

Fabrication of low-temperature solid oxide fuel cells with a nanothin protective layer by atomic layer deposition

PubMed Central

2013-01-01

Anode aluminum oxide-supported thin-film fuel cells having a sub-500-nm-thick bilayered electrolyte comprising a gadolinium-doped ceria (GDC) layer and an yttria-stabilized zirconia (YSZ) layer were fabricated and electrochemically characterized in order to investigate the effect of the YSZ protective layer. The highly dense and thin YSZ layer acted as a blockage against electron and oxygen permeation between the anode and GDC electrolyte. Dense GDC and YSZ thin films were fabricated using radio frequency sputtering and atomic layer deposition techniques, respectively. The resulting bilayered thin-film fuel cell generated a significantly higher open circuit voltage of approximately 1.07 V compared with a thin-film fuel cell with a single-layered GDC electrolyte (approximately 0.3 V). PMID:23342963

Visualizing Rhizosphere Soil Structure Around Living Roots

NASA Astrophysics Data System (ADS)

Menon, M.; Berli, M.; Ghezzehei, T. A.; Nico, P.; Young, M. H.; Tyler, S. W.

2008-12-01

The rhizosphere, a thin layer of soil (0 to 2 mm) surrounding a living root, is an important interface between bulk soil and plant root and plays a critical role in root water and nutrient uptake. In this study, we used X-ray Computerized Microtomography (microCT) to visualize soil structure around living roots non-destructively and with high spatial resolution. Four different plant species (Helianthus annuus, Lupinus hartwegii, Vigna radiata and Phaseolus lunatus), grown in four different porous materials (glass beads, medium and coarse sand, loam aggregates), were scanned with 10 ìm spatial resolution, using the microtomography beamline 8.3.2 at the Advanced Light Source, Lawrence Berkeley National Laboratory, Berkeley, CA. Sample cross section images clearly show contacts between roots and soil particles, connecting water films, air-water interfaces as well as some cellular features of the plants taproots. We found with a simulation experiment, inflating a cylindrical micro-balloon in a pack of air-dry loam aggregates, that soil fracturing rather than compaction might occur around a taproot growing in dry soil. Form these preliminary experiments, we concluded that microCT has potential as a tool for a more process-based understanding of the role of rhizosphere soil structure on soil fertility, plant growth and the water balance at the earth-atmosphere interface.

The long-term effects of silvicultural thinning and partial cutting on soil compaction in red pine (Pinus resinosa Ait.) and northern hardwood stands in the northern Great Lakes Region of the United States

Treesearch

Rachel A. Tarpey; Martin F. Jurgensen; Brian J. Palik; Randy K. Kolka

2008-01-01

Periodic silvicultural thinnings (23.0, 27.6, 32.1 m2 ha-1 residual basal area) in a red pine stand growing on a sandy soil in north-central Minnesota over a 57-yr period increased soil compaction as the intensity of the thinning treatment increased. Of the three different methods used to measure soil compaction (bulk...

Thinning but not understory removal increased heterotrophic respiration and total soil respiration in Pinus massoniana stands.

PubMed

Lei, Lei; Xiao, Wenfa; Zeng, Lixiong; Zhu, Jianhua; Huang, Zhilin; Cheng, Ruimei; Gao, Shangkun; Li, Mai-He

2018-04-15

Quantifying soil respiration (R s ) and its components [autotrophic respiration (R a ) and heterotrophic respiration (R h )] in relation to forest management is vital to accurately evaluate forest carbon balance. Thus, R s , R a , and R h were continuously monitored from November 2013 to November 2016 in Pinus massoniana forests subjected to four different management practices in China. We hypothesized that understory removal and thinning decrease R a and R h and thus R s , and these decreases will change with time following UR and thinning. Mean values of R s , R a , and R h in light thinned plots (LT=15% of tree basal area thinned) and heavily thinned plots (HT=70% of tree basal area thinned) were significantly higher than in control (CK) and understory removal plots (UR). The annual R h /R s ratio ranged from 58% to 70% across all treatments, and this ratio was significantly higher in HT and LT than in UR and CK. Only HT significantly increased soil temperature. Soil temperature could better explain R h (R 2 =0.69-0.96) than R a (R 2 =0.51-0.86). HT and LT increased Q 10 for both R a and R h , except for R h in UR. Soil moisture content (W; %) was significantly higher in HT than in other treatments, but W had limited effects on soil respiration in that rain-rich subtropical China. This result suggests that global warming alone, or in combination with clear-cutting or canopy tree thinning will markedly increase soil heterotrophic respiration and thus the total soil CO 2 emission. To get firewood for local people and to reduce soil CO 2 emissions under global warming, canopy trees are needed to be protected and understory shrubs may be allowed to be used in the subtropical China. Copyright © 2017 Elsevier B.V. All rights reserved.

Thin film electronic devices with conductive and transparent gas and moisture permeation barriers

DOEpatents

Simpson, Lin Jay

2015-07-28

Thin film electronic devices (or stacks integrated with a substrate) that include a permeation barrier formed of a thin layer of metal that provides a light transmitting and electrically conductive layer, wherein the electrical conductive layer is formed on a surface of the substrate or device layer such as a transparent conducting material layer with pin holes or defects caused by manufacturing and the thin layer of metal is deposited on the conductive layer and formed from a self-healing metal that forms self-terminating oxides. A permeation plug or block is formed in or adjacent to the thin film of metal at or proximate to the pin holes to block further permeation of contaminants through the pin holes.

Transient Liquid Water as a Mechanism for Induration of Soil Crusts on Mars

NASA Technical Reports Server (NTRS)

Landis, G. A.; Blaney, D.; Cabrol, N.; Clark, B. C.; Farmer, J.; Grotzinger, J.; Greeley, R.; McLennan, S. M.; Richter, L.; Yen, A.

2004-01-01

The Viking and the Mars Exploration Rover missions observed that the surface of Mars is encrusted by a thinly cemented layer tagged as "duricrust". A hypothesis to explain the formation of duricrust on Mars should address not only the potential mechanisms by which these materials become cemented, but also the textural and compositional components of cemented Martian soils. Elemental analyzes at five sites on Mars show that these soils have sulfur content of up to 4%, and chlorine content of up to 1%. This is consistent with the presence of sulfates and halides as mineral cements. . For comparison, the rock "Adirondack" at the MER site, after the exterior layer was removed, had nearly five times lower sulfur and chlorine content , and the Martian meteorites have ten times lower sulfur and chlorine content, showing that the soil is highly enriched in the saltforming elements compared with rock.Here we propose two alternative models to account for the origin of these crusts, each requiring the action of transient liquid water films to mediate adhesion and cementation of grains. Two alternative versions of the transient water hypothesis are offered, a top down hypothesis that emphasizes the surface deposition of frost, melting and downward migration of liquid water and a bottom up alternative that proposes the presence of interstitial ice/brine, with the upward capillary migration of liquid water.

Large area polysilicon films with predetermined stress characteristics and method for producing same

NASA Technical Reports Server (NTRS)

Heuer, Arthur H. (Inventor); Kahn, Harold (Inventor); Yang, Jie (Inventor); Phillips, Stephen M. (Inventor)

2002-01-01

Multi-layer assemblies of polysilicon thin films having predetermined stress characteristics and techniques for forming such assemblies are disclosed. In particular, a multi-layer assembly of polysilicon thin films may be produced that has a stress level of zero, or substantially so. The multi-layer assemblies comprise at least one constituent thin film having a tensile stress and at least one constituent thin film having a compressive stress. The thin films forming the multi-layer assemblies may be disposed immediately adjacent to one another without the use of intermediate layers between the thin films. Multi-layer assemblies exhibiting selectively determinable overall bending moments are also disclosed. Selective production of overall bending moments in microstructures enables manufacture of such structures with a wide array of geometrical configurations.

Spatial Distribution of Acid Neutralizing Processes in Steep Headwater Catchments in Tanakami Mountains, Central Japan

NASA Astrophysics Data System (ADS)

Asano, Y.; Uchida, T.; Ohte, N.; Tani, M.

2001-05-01

The areas characterized by steep slope, thin soils, and unreactive bedrock types are often considered as acid-sensitive. The purpose of this study is to investigate the spatial distribution of acid neutralizing processes in steep headwater catchment in the humid temperate region, and to discuss the long-term change in acid neutralizing processes associated with the forest growth and soil development. The observations were conducted at two adjacent unchannelled steep catchment, Fudoji (0.10ha) and Rachidani (0.18ha). Two catchments share similar climatic condition and the same bedrock geology (granite). The mean hollow gradient is 37degrees in Fudoji and 34degrees in Rachidani. Fudoji is forested with mean soil depth of 77cm, while Rachidani is non-vegetated with mean soil depth of about 10cm. In both catchments, hydrometric and isotopic measurements illustrated the substantial downward water flux into the bedrock in upslope area and emerging of this water from bedrock to soil layer within 2m from the perennial spring points. The mean pH of soil water and groundwater were dispersed over a wide range of 4.00 to 5.84 in Fudoji and 5.29 to 6.28 in Rachidani, while stream pHs converged very closely to neutral value in two catchments. In both catchments, major H+ sources distributed at the near-surface soil layer and the intensity of internal H+ production was greater in forested Fudoji than non-vegetated Rachidani, attributed to the biological cycles in forest ecosystems. Calculation of budget for base cations (Na+, K+, Ca2+ and Mg2+) presented that 72 to 84 percent (Fudoji) and 34percent (Rachidani) of the net base cation production in each catchment was derived from the bedrock, indicating that a considerable amount of the H+ was consumed within the bedrock. Moreover, the H+ consumption rate per unit volume of soil in Fudoji was almost one order of magnitude smaller than that of Rachidani. These results suggested that the dominant H+ sink in catchments shifted from soil layer to the bedrock along with the forest growth and with soil formation, associated with the increase of the H+ production and the decrease of the buffering potential of soils. It can be pointed out that bedrock flow paths play an important role in the acid neutralizing processes.

Comparison Between Navier-Stokes and Thin-Layer Computations for Separated Supersonic Flow

NASA Technical Reports Server (NTRS)

Degani, David; Steger, Joseph L.

1983-01-01

In the numerical simulation of high Reynolds-number flow, one can frequently supply only enough grid points to resolve the viscous terms in a thin layer. As a consequence, a body-or stream-aligned coordinate system is frequently used and viscous terms in this direction are discarded. It is argued that these terms cannot be resolved and computational efficiency is gained by their neglect. Dropping the streamwise viscous terms in this manner has been termed the thin-layer approximation. The thin-layer concept is an old one, and similar viscous terms are dropped, for example, in parabolized Navier-Stokes schemes. However, such schemes also make additional assumptions so that the equations can be marched in space, and such a restriction is not usually imposed on a thin-layer model. The thin-layer approximation can be justified in much the same way as the boundary-layer approximation; it requires, therefore, a body-or stream-aligned coordinate and a high Reynolds number. Unlike the boundary-layer approximation, the same equations are used throughout, so there is no matching problem. Furthermore, the normal momentum equation is not simplified and the convection terms are not one-sided differenced for marching. Consequently, the thin-layer equations are numerically well behaved at separation and require no special treatment there. Nevertheless, the thin-layer approximation receives criticism. It has been suggested that the approximation is invalid at separation and, more recently, that it is inadequate for unsteady transonic flow. Although previous comparisons between the thin-layer and Navier-Stokes equations have been made, these comparisons have not been adequately documented.

Multilayer composites and manufacture of same

DOEpatents

Holesinger, Terry G.; Jia, Quanxi

2006-02-07

The present invention is directed towards a process of depositing multilayer thin films, disk-shaped targets for deposition of multilayer thin films by a pulsed laser or pulsed electron beam deposition process, where the disk-shaped targets include at least two segments with differing compositions, and a multilayer thin film structure having alternating layers of a first composition and a second composition, a pair of the alternating layers defining a bi-layer wherein the thin film structure includes at least 20 bi-layers per micron of thin film such that an individual bi-layer has a thickness of less than about 100 nanometers.

Measured Two-Dimensional Ice-Wedge Polygon Thermal and Active Layer Dynamics

NASA Astrophysics Data System (ADS)

Cable, W.; Romanovsky, V. E.; Busey, R.

2016-12-01

Ice-wedge polygons are perhaps the most dominant permafrost related features in the arctic landscape. The microtopography of these features, that includes rims, troughs, and high and low polygon centers, alters the local hydrology. During winter, wind redistribution of snow leads to an increased snowpack depth in the low areas, while the slightly higher areas often have very thin snow cover, leading to differences across the landscape in vegetation communities and soil moisture between higher and lower areas. To investigate the effect of microtopographic caused variation in surface conditions on the ground thermal regime, we established temperature transects, composed of five vertical array thermistor probes (VATP), across four different development stages of ice-wedge polygons near Barrow, Alaska. Each VATP had 16 thermistors from the surface to a depth of 1.5 m, for a total of 80 temperature measurements per polygon. We found snow cover, timing and depth, and active layer soil moisture to be major controlling factors in the observed thermal regimes. In troughs and in the centers of low-centered polygons, the combined effect of typically saturated soils and increased snow accumulation resulted in the highest mean annual ground temperatures (MAGT) and latest freezeback dates. While the centers of high-centered polygons, with thinner snow cover and a dryer active layer, had the lowest MAGT, earliest freezeback dates, and shallowest active layer. Refreezing of the active layer initiated at nearly the same time for all locations and polygons however, we found large differences in the proportion of downward versus upward freezing and the length of time required to complete the refreezing process between polygon types and locations. Using our four polygon stages as a space for time substitution, we conclude that ice-wedge degradation resulting in surface subsidence and trough deepening can lead to overall drying of the active layer and increased skewedness of snow distribution. Which in turn leads to shallower active layers, earlier freezeback dates, and lower MAGT. We also find that the large variation in active layer dynamics (active layer depth, downward vs upward freezing, and freezeback date) are important considerations to understanding and scaling biological processes occurring in these landscapes.

Three mars years: Viking lander 1 imaging observations

USGS Publications Warehouse

Arvidson, R. E.; Guinness, E.A.; Moore, H.J.; Tillman, J.; Wall, S.D.

1983-01-01

The Mutch Memorial Station (Viking Lander 1) on Mars acquired imaging and meteorological data over a period of 2245 martian days (3:3 martian years). This article discusses the deposition and erosion of thin deposits (ten to hundreds of micrometers) of bright red dust associated with global dust storms, and the removal of centimeter amounts of material in selected areas during a dust storm late in the third winter. Atmospheric pressure data acquired during the period of intense erosion imply that baroclinic disturbances and strong diurnal solar tidal heating combined to produce strong winds. Erosion occurred principally in areas where soil cohesion was reduced by earlier surface sampler activities. Except for redistribution of thin layers of materials, the surface appears to be remarkably stable, perhaps because of cohesion of the undisturbed surface material.

Three Mars years: viking lander 1 imaging observations.

PubMed

Arvidson, R E; Guinness, E A; Moore, H J; Tillman, J; Wall, S D

1983-11-04

The Mutch Memorial Station (Viking Lander 1) on Mars acquired imaging and meteorological data over a period of 2245 martian days (3:3 martian years). This article discusses the deposition and erosion of thin deposits (ten to hundreds of micrometers) of bright red dust associated with global dust storms, and the removal of centimeter amounts of material in selected areas during a dust storm late in the third winter. Atmospheric pressure data acquired during the period of intense erosion imply that baroclinic disturbances and strong diurnal solar tidal heating combined to produce strong winds. Erosion occurred principally in areas where soil cohesion was reduced by earlier surface sampler activities. Except for redistribution of thin layers of materials, the surface appears to be remarkably stable, perhaps because of cohesion of the undisturbed surface material.

Three Mars years - Viking Lander 1 imaging observations

NASA Technical Reports Server (NTRS)

Arvidson, R. E.; Guinness, E. A.; Moore, H. J.; Tillman, J.; Wall, S. D.

1983-01-01

The Mutch Memorial Station (Viking Lander 1) on Mars acquired imaging and meteorological data over a period of 2245 martian days (3.3 martian years). This article discusses the deposition and erosion of thin deposits (ten to hundreds of micrometers) of bright red dust associated with global dust storms, and the removal of centimeter amounts of material in selected areas during a dust storm late in the third winter. Atmospheric pressure data acquired during the period of intense erosion imply that baroclinic disturbances and strong diurnal solar tidal heating combined to produce strong winds. Erosion occurred principally in areas where soil cohesion was reduced by earlier surface sampler activities. Except for redistribution of thin layers of materials, the surface appears to be remarkably stable, perhaps because of cohension of the undisturbed surface material.

Soil formation on hard rock with and without cover of Pleistocene periglacial slope deposits in humid-temperate climate of Europe

NASA Astrophysics Data System (ADS)

Sauer, Daniela; Schülli-Maurer, Isabelle

2014-05-01

Until the 1960s pedologists in Germany assumed that soils on hard rock in the mountainous regions of Germany developed directly from the underlying hard rock. Then, especially Schilling and Wiefel (1962) in eastern Germany and Semmel (1964, 1968) in western Germany developed, independently from each other, the concept of Pleistocene periglacial slope deposits (PPSD). However, it took several decades until this concept became largely accepted and was also introduced in textbooks and in the German soil and substrate taxonomy. This paper compares soil development on hard rock covered by PPSD in the eastern Rhenish Massif (Germany) to soil development that took place indeed directly on hard rock, in southern Norway, where glaciers removed all loose, weathered material from the rock during the last glacial period. Eight soil profiles developed in PPSD on quartzite and 12 soil profiles developed in PPSD on diabase are compared to four profiles in the Oslofjord region developed from hard rock. Soils were described in the field and analysed with regard to particle size analysis, pH in water, total element composition, Fed, Feo, CEC and base saturation. 1) Podzol developed from medium-grained granite This soil has an age of ca. 10,000 years. An 18 cm thick organic surface layer has accumulated on top of the mineral soil consisting of an E (14 cm) and BCs (14 cm) horizon. Vegetation at the site consists mainly of pine, birch, fir, and blueberry, heather and mosses. 2) Podzol developed from coarse-grained granite This soil has an age of above 11,000 years. The organic surface layer has a thickness of 7 cm; the mineral soil comprises an E (7 cm) and Bs (7 cm) horizon. Vegetation consists mainly of pine, fir, birch, and blueberry, heather, ferns and mosses. 3) Cambic Leptosol developed from Latite This soil has an age of ca. 10,000 years. The thickness of the organic surface layer is 5 cm; the mineral soil comprises an Ah (4 cm) and AB (20 cm) horizon. Vegetation consists mainly of beech, birch, fir, pine, and sorb, blueberry and hair-grass (Deschampsia flexuosa). 4) Cambisol developed from Monzonite This soil has an age of ca. 9,500 years. The thickness of the organic surface layer is 6 cm; the mineral soil comprises an Ah (9 cm), Bw (17 cm) and BC (9 cm) horizon. Vegetation consists mainly of fir, oak, beech, and sorb, blueberry, ferns, grasses and mosses. Geochemical data suggest that the soil has not entirely developed from Monzonite but that the Ah and Bw horizon are mainly composed of a thin layer of beach sediments. The comparison demonstrates the importance of physical weathering under periglacial conditions and formation of PPSD for Holocene soil development on hard rock in central Europe. References: Schilling, W., Wiefel, H. (1962): Jungpleistozäne Periglazialbildungen und ihre regionale Differenzierung in einigen Teilen Thüringens und des Harzes. Geologie, Jg. 11, Heft 4: 393 - 504. Semmel, A. (1964): Junge Schuttdecken in Hessischen Mittelgebirgen. Notitzbl. Hess. L.-Amt Bodenforsch. 92: 275 - 285. Semmel, A. (1968): Studien über den Verlauf jungpleistozäner Formung in Hessen. Frankfurter Geogr. Hefte 45.

NASA Tech Briefs, April 2008

NASA Technical Reports Server (NTRS)

2008-01-01

Topics covered include: Gas Sensors Based on Coated and Doped Carbon Nanotubes; Tactile Robotic Topographical Mapping Without Force or Contact Sensors; Thin-Film Magnetic-Field-Response Fluid-Level Sensor for Non-Viscous Fluids; Progress in Development of Improved Ion-Channel Biosensors; Simulating Operation of a Complex Sensor Network; Using Transponders on the Moon to Increase Accuracy of GPS; Controller for Driving a Piezoelectric Actuator at Resonance; Coaxial Electric Heaters; Dual-Input AND Gate From Single-Channel Thin-Film FET; High-Density, High-Bandwidth, Multilevel Holographic Memory; Fabrication of Gate-Electrode Integrated Carbon-Nanotube Bundle Field Emitters; Hydroxide-Assisted Bonding of Ultra-Low-Expansion Glass; Photochemically Synthesized Polyimides; Optimized Carbonate and Ester-Based Li-Ion Electrolytes; Compact 6-DOF Stage for Optical Adjustments; Ultrasonic/Sonic Impacting Penetrators; Miniature, Lightweight, One-Time-Opening Valve; Supplier Management System; Improved CLARAty Functional-Layer/Decision-Layer Interface; JAVA Stereo Display Toolkit; Remote-Sensing Time Series Analysis, a Vegetation Monitoring Tool; PyPele Rewritten To Use MPI; Data Assimilation Cycling for Weather Analysis; Hydrocyclone/Filter for Concentrating Biomarkers from Soil; Activating STAT3 Alpha for Promoting Healing of Neurons; and Probing a Spray Using Frequency-Analyzed Light Scattering.

Ordered organic-organic multilayer growth

DOEpatents

Forrest, Stephen R.; Lunt, Richard R.

2016-04-05

An ordered multilayer crystalline organic thin film structure is formed by depositing at least two layers of thin film crystalline organic materials successively wherein the at least two thin film layers are selected to have their surface energies within .+-.50% of each other, and preferably within .+-.15% of each other, whereby every thin film layer within the multilayer crystalline organic thin film structure exhibit a quasi-epitaxial relationship with the adjacent crystalline organic thin film.

Ordered organic-organic multilayer growth

DOEpatents

Forrest, Stephen R; Lunt, Richard R

2015-01-13

An ordered multilayer crystalline organic thin film structure is formed by depositing at least two layers of thin film crystalline organic materials successively wherein the at least two thin film layers are selected to have their surface energies within .+-.50% of each other, and preferably within .+-.15% of each other, whereby every thin film layer within the multilayer crystalline organic thin film structure exhibit a quasi-epitaxial relationship with the adjacent crystalline organic thin film.

Nano-crystalline thin and nano-particulate thick TiO{sub 2} layer: Cost effective sequential deposition and study on dye sensitized solar cell characteristics

DOE Office of Scientific and Technical Information (OSTI.GOV)

Das, P.; Sengupta, D.; CSIR-Central Mechanical Engineering Research Institute, Academy of Scientific and Innovative Research

Highlights: • Thin TiO{sub 2} layer is deposited on conducting substrate using sol–gel based dip coating. • TiO{sub 2} nano-particles are synthesized using hydrothermal route. • Thick TiO{sub 2} particulate layer is deposited on prepared thin layer. • Dye sensitized solar cells are made using thin and thick layer based photo-anode. • Introduction of thin layer in particulate photo-anode improves the cell efficiency. - Abstract: A compact thin TiO{sub 2} passivation layer is introduced between the mesoporous TiO{sub 2} nano-particulate layer and the conducting glass substrate to prepare photo-anode for dye-sensitized solar cell (DSSC). In order to understand the effectmore » of passivation layer, other two DSSCs are also developed separately using TiO{sub 2} nano-particulate and compact thin film based photo-anodes. Nano-particles are prepared using hydrothermal synthesis route and the compact passivation layer is prepared by simply dip coating the precursor sol prepared through wet chemical route. The TiO{sub 2} compact layer and the nano-particles are characterised in terms of their micro-structural features and phase formation behavior. It is found that introduction of a compact TiO{sub 2} layer in between the mesoporous TiO{sub 2} nano-particulate layer and the conducting substrate improves the solar to electric conversion efficiency of the fabricated cell. The dense thin passivation layer is supposed to enhance the photo-excited electron transfer and prevent the recombination of photo-excited electrons.« less

Efficient infiltration of water in the subsurface by using point-wells: A field study

NASA Astrophysics Data System (ADS)

Lopik, J. V.; Schotting, R.; Raoof, A.

2017-12-01

The ability to infiltrate large volumes of water in the subsurface would have great value for battling flooding in urban regions. Moreover, efficient water infiltration is key to optimize underground aquifer storage and recovery (ASR), aquifer thermal energy storage (ATES), as well as construction dewatering systems. Usually, variable infiltration rates of large water quantities could have a huge hydrogeological impact in the upper part of (phreatic) aquifer systems. In urban regions, minimizing excessive groundwater table fluctuations are necessary. A newly developed method, Fast, High Volume Infiltration (FHVI), by Dutch dewatering companies can be used to enable fast injection into the shallow subsurface. Conventional infiltration methods are using injection wells that screen large parts of the aquifer depth, whereas FHVI uses a specific infiltration point (1-m well screen) in the aquifer. These infiltration points are generally thin, high permeable layers in the aquifer of approximately 0.5-2 meter thick, and are embedded by less permeable layers. Currently, much higher infiltration pressures in shallow aquifers can be achieved with FHVI (up to 1 bar) compared to conventional infiltration methods ( 0.2 bar). Despite the high infiltration pressures and high discharge rate near the FHVI-filter, the stresses on shallow groundwater levels are significantly reduced with FHVI. In order to investigate the mechanisms that enable FHVI, a field experiment is conducted in a sandy aquifer to obtain insight in the 3-D hydraulic pressure distribution and flow patterns around a FHVI-filter during infiltration. A detailed characterization of the soil profile is obtained by using soil samples and cone pressure tests with a specific hydraulic profiling tool to track the vertical variation in aquifer permeability. A tracer test with bromide and heat is conducted to investigate preferential flow paths. The experimental data show that tracking small heterogeneities in aquifers and analysing the permeability difference ratio between the aimed infiltration layer and the surrounding layers in the aquifer are key to optimize the configuration of the FHVI-well. The results show that the use of point wells in thin, high permeable layers could drastically improve the efficiency of the infiltration system.

An Electrochemical Experiment Using an Optically Transparent Thin Layer Electrode

ERIC Educational Resources Information Center

DeAngelis, Thomas P.; Heineman, William R.

1976-01-01

Describes a unified experiment in which an optically transparent thin layer electrode is used to illustrate the techniques of thin layer electrochemistry, cyclic voltammetry, controlled potential coulometry, and spectroelectrochemistry. (MLH)

Rectenna that converts infrared radiation to electrical energy

DOEpatents

Davids, Paul; Peters, David W.

2016-09-06

Technologies pertaining to converting infrared (IR) radiation to DC energy are described herein. In a general embodiment, a rectenna comprises a conductive layer. A thin insulator layer is formed on the conductive layer, and a nanoantenna is formed on the thin insulator layer. The thin insulator layer acts as a tunnel junction of a tunnel diode.

Phytotoxicity of water-soluble substances from alfalfa and barley soil extracts on four crop species.

PubMed

Read, J J; Jensen, E H

1989-02-01

Problems associated with continuously planting alfalfa (Medicago saliva L.) or seeding to thicken depleted alfalfa stands may be due to autotoxicity, an intraspecific form of allelopathy. A bioassay approach was utilized to characterize the specificity and chemical nature of phytotoxins in extracts of alfalfa soils as compared to fallow soil or soil where a cereal was the previous crop. In germination chamber experiments, water-soluble substances present in methanol extracts of soil cropped to alfalfa or barley (Hordeum vulgare L.) decreased seedling root length of alfalfa L-720, winter wheat (Triticum aestivum L. Nugaines) and radish (Raphanus sativa L. Crimson Giant). Five days after germination, seedling dry weights of alfalfa and radish in alfalfa soil extracts were lower compared to wheat or red clover (Trifolium pralense L. Kenland). Growth of red clover was not significantly reduced by soil extracts from cropped soil. Extracts of crop residue screened from soil cropped to alfalfa or barley significantly reduced seedling root length; extracts of alfalfa residue caused a greater inhibition of seedling dry weight than extracts of barely residue. A phytotoxic, unidentified substance present in extracts of crop residue screened from alfalfa soil, which inhibited seedling root length of alfalfa, was isolated by thin-layer chromatography (TLC). Residues from a soil cropped continuously to alfalfa for 10 years had the greatest phytotoxic activity.

Effects of thinning, residue mastication, and prescribed fire on soil and nutrient budgets in a Sierra Nevada mixed-conifer forest

USDA-ARS?s Scientific Manuscript database

The effects of thinning followed by residue mastication (THIN), prescribed fire (BURN), and thinning plus residue mastication plus burning (T+B) on nutrient budgets and resin-based (plant root simulator [PRS] probe) measurements of soil nutrient availability in a mixed-conifer forest were measured. ...

Effects of thinning, residue mastication, and prescribed fire on soil and nutrient budgets in a Sierra Nevada mixed conifer forest

USDA-ARS?s Scientific Manuscript database

The effects of thinning followed by residue mastication (THIN), prescribed fire (BURN), and thinning plus residue mastication plus burning (T+B) on nutrient budgets and resin-based (plant root simulator [PRS] probe) measurements of soil nutrient availability in a mixed-conifer forest were measured. ...

Cadmium-free junction fabrication process for CuInSe.sub.2 thin film solar cells

DOEpatents

Ramanathan, Kannan V.; Contreras, Miguel A.; Bhattacharya, Raghu N.; Keane, James; Noufi, Rommel

1999-01-01

The present invention provides an economical, simple, dry and controllable semiconductor layer junction forming process to make cadmium free high efficiency photovoltaic cells having a first layer comprised primarily of copper indium diselenide having a thin doped copper indium diselenide n-type region, generated by thermal diffusion with a group II(b) element such as zinc, and a halide, such as chlorine, and a second layer comprised of a conventional zinc oxide bilayer. A photovoltaic device according the present invention includes a first thin film layer of semiconductor material formed primarily from copper indium diselenide. Doping of the copper indium diselenide with zinc chloride is accomplished using either a zinc chloride solution or a solid zinc chloride material. Thermal diffusion of zinc chloride into the copper indium diselenide upper region creates the thin n-type copper indium diselenide surface. A second thin film layer of semiconductor material comprising zinc oxide is then applied in two layers. The first layer comprises a thin layer of high resistivity zinc oxide. The second relatively thick layer of zinc oxide is doped to exhibit low resistivity.

Soil water content spatial pattern estimated by thermal inertia from air-borne sensors

NASA Astrophysics Data System (ADS)

Coppola, Antonio; Basile, Angelo; Esposito, Marco; Menenti, Massimo; Buonanno, Maurizio

2010-05-01

Remote sensing of soil water content from air- or space-borne platforms offer the possibility to provide large spatial coverage and temporal continuity. The water content can be actually monitored in a thin soil layer, usually up to a depth of 0.05m below the soil surface. To the contrary, difficulties arise in the estimation of the water content storage along the soil profile and its spatial (horizontal) distribution, which are closely connected to soil hydraulic properties and their spatial distribution. A promising approach for estimating soil water contents profiles is the integration of remote sensing of surface water content and hydrological modeling. A major goal of the scientific group is to develop a practical and robust procedure for estimating water contents throughout the soil profile from surface water content. As a first step, in this work, we will show some preliminary results from aircraft images analysis and their validation by field campaigns data. The data extracted from the airborne sensors provided the opportunity of retrieving land surface temperatures with a very high spatial resolution. The surface water content pattern, as deduced by the thermal inertia estimations, was compared to the surface water contents maps measured in situ by time domain reflectometry-based probes.

[Effect of long-term fertilization on microbial community functional diversity in black soil].

PubMed

Liu, Jing-xin; Chi, Feng-qin; Xu, Xiu-hong; Kuang, En-jun; Zhang, Jiu-ming; Su, Qing-rui; Zhou, Bao-ku

2015-10-01

In order to study the effects of long-term different fertilization on microbial community functional diversity in arable black. soil, we examined microbial metabolic activities in two soil la- yers (0-20 cm, 20-40 cm) under four treatments (CK, NPK, M, MNPK) from a 35-year continuous fertilization field at the Ministry of Agriculture Key Field Observation Station of Harbin Black Soil Ecology Environment using Biolog-ECO method. The results showed that: in the 0-20 cm soil layer, combined application of organic and inorganic fertilizer(MNPK) increased the rate of soil microbial carbon source utilization and community metabolism richness, diversity and dominance; In the 20-40 cm layer, these indices of the MNPK treatment was lower than that of the NPK treat- ment; while NPK treatment decreased soil microbial community metabolism evenness in both layers. Six groups of carbon sources used by soil microbes of all the treatments were different between the two soil layers, and the difference was significant among all treatments in each soil layer (P < 0.05) , while the variations among treatments were different in the two soil layers. Canonical correspondence analysis (CCA) showed that soil microbial community metabolic function of all the treatments was different between the two soil layers, and there was difference among all treatments in each soil layer, while the influences of soil nutrients on soil microbial community metabolic function of all treatments were similar in each soil layer. It was concluded that long-term different fertilization affected soil microbial community functional diversity in both tillage soil layer and down soil layers, and chemical fertilization alone had a larger influence on the microbial community functional diversity in the 20-40 cm layer.

The threshold strength of laminar ceramics utilizing molar volume changes and porosity

NASA Astrophysics Data System (ADS)

Pontin, Michael Gene

It has been shown that uniformly spaced thin compressive layers within a ceramic body can arrest the propagation of an otherwise catastrophic crack, producing a threshold strength: a strength below which the probability of failure is zero. Previous work has shown that the threshold strength increases with both the magnitude of the compressive stress and the fracture toughness of the thin layer material, and finite element analysis predicts that the threshold strength can be further increased when the elastic modulus of the compressive layer is much smaller than the thicker layer. The current work describes several new approaches to increase the threshold strength of a laminar ceramic system. The initial method utilized a molar volume expansion within the thin layers, produced by the tetragonal-to-monoclinic phase transformation of unstabilized zirconia during cooling, in order to produce large compressive stresses within the thin layers. High threshold strengths were measured for this system, but they remained relatively constant as the zirconia content was increased. It was determined that microcracking produced during the transformation reduced the magnitude of the compressive stresses, but may also have served to reduce the modulus of the thin compressive layer, providing an additional strengthening mechanism. The second approach studied the addition of porosity to reduce the elastic modulus of the thin compressive layers. A new processing method was created and analyzed, in which thick layers of the laminate were fabricated by tape-casting, and then dip-coated into a slurry, containing rice starch, to create thin porous compressive layers upon densification. The effects of porosity on the residual compressive stress, elastic modulus, and fracture toughness of the thin layers were measured and calculated, and it was found that the elastic modulus mismatch between the thin and thick layers produced a large strengthening effect for volume fractions of porosity below a critical level. Specimens with greater volume fractions of porosity exhibited complete crack arrest, typically followed by non-catastrophic failure, as cracks initiating in adjacent thick layers coalesced by cracking or delamination along the thin porous layers.

Characterization of Cu buffer layers for growth of L10-FeNi thin films

NASA Astrophysics Data System (ADS)

Mizuguchi, M.; Sekiya, S.; Takanashi, K.

2010-05-01

A Cu(001) layer was fabricated on a Au(001) layer to investigate the use of Cu as a buffer layer for growing L10-FeNi thin films. The epitaxial growth of a Cu buffer layer was observed using reflection high-energy electron diffraction. The flatness of the layer improved drastically with an increase in the substrate temperature although the layer was an alloy (AuCu3). An FeNi thin film was epitaxially grown on the AuCu3 buffer layer by alternate monatomic layer deposition and the formation of an L10-FeNi ordered alloy was expected. The AuCu3 buffer layer is thus a promising candidate material for the growth of L10-FeNi thin films.

Can thinning slash cause a nitrogen deficiency in pumice soils of central Oregon?

Treesearch

P.H. Cochran

1968-01-01

Decomposition of thinning slash deposited on the soil surface should have no direct adverse effect on the soil nitrogen available to higher plants in the pumice soil region. Decomposition of roots of cut trees would immobilize nitrogen in the soil immediately adjacent to the root during the decomposition period, which appears to be short for the smaller roots. However...

Influence of thinning Loblolly Pine (Pinus taeda L.) on hydraulic properties of an organic soil

Treesearch

Johnny M. Grace; R. W. Skaggs; D. Keith Cassel

2006-01-01

The impact of forest operations on soil properties has been a concern in forest management over the past 30 years. The objective of this study was to evaluate the impact of forest thinning operations on soil hydraulic properties of a shallow organic (Belhaven series) soil in the Tidewater region of North Carolina. Soil physical properties were evaluated in a nested...

Impact of a moderate/high-severity prescribed eucalypt forest fire on soil phosphorous stocks and partitioning.

PubMed

Santín, Cristina; Otero, Xose L; Doerr, Stefan H; Chafer, Chris J

2018-04-15

This study examines the direct impact of a moderate/high-severity prescribed fire on phosphorous (P) stocks and partitioning in oligotrophic soils of a dry eucalypt forest within Sydney's water supply catchments, Australia. We also quantify and characterize the P present in the ash produced in this fire, and explore its relationships with the maximum temperatures recorded in the litter layer during the burn. In these oligotrophic soils, P concentrations were already relatively low before the fire (<130mgkg -1 , mainly in organic forms). The fire consumed the entire litter layer and the thin Oa soil horizon, creating 6.3±3.1tha -1 of ash, and resulted into direct net P losses of ~7kgha -1 . The P lost was mostly organic and there was a moderate net gain of inorganic and non-reactive P forms. Importantly, only a small proportion of the post-fire P was bioavailable (equivalent to ~3% of the total P lost during fire). Higher total P concentrations in ash corresponded with higher maximum temperatures (>650°C) recorded in the burning litter layer, but effects of fire temperature on ash P partitioning were not significant. Fire not only transformed P chemically, but also physically. Our results show that, immediately after fire, up to 2kgha -1 of P was present in the ash layer and, therefore, highly erodible and susceptible to be transported off-site by wind- and water erosion. Even if most of this P was, initially, of low bioavailability, its transfer to depositional environments with different geochemical conditions (e.g. anoxic sediments in water reservoirs) can alter its geochemical forms and availability. Further investigation of potential P transformations off-site is therefore essential, particularly given that SE-Australian water supply catchments are subject to recurrent perturbation by prescribed fire and wildfires. The latter have already resulted in major algal blooms in water supply reservoirs. Copyright © 2017 Elsevier B.V. All rights reserved.

Quantifying Water Infiltration through the Preferential Passages in the Forest Soil

NASA Astrophysics Data System (ADS)

Qu, Liqin; Chen, Ping; Gan, Ping; Lei, Tingwu

2017-04-01

Infiltration of water into soil commonly involves infiltration through the matrix body and preferential passages. Quantifying the contribution of preferential flow is important to evaluate the effects of land use and land cover changes on hillslope hydrology and watershed sedimentation. A new procedure was applied in this study to estimate the water infiltration into the soil through the soil body and macrospores. Field experiments were conducted in a forest field on the Loess Plateau at Tianshui Soil and Water Conservation Experimental Station, Gansu Province, China. The experiment implements a double-ring infiltrometer and involves two measuring phases. Firstly, a thin layer sieved soil collected on site was sprinkled on the nylon cloth to shelter the macrospores and to ensure that water infiltrates the soil through the matrix only. The infiltration process was measured, computed, and recorded. Secondly, immediately after the first phase, the nylon cloth and layered soil above the soil surface was removed from the double ring infiltrometer carefully, and the infiltration process was measured for 30 mins in which water infiltration through both soil body impacted by the preferential passages in the soil body. There were three treatments according to the measured infiltration periods in the first phase of 30, 60, 90 mins, respectively, and two replicates for each treatment were conducted. The measured soil infiltration curves in the first phase explained the transient process of soil matrix infiltration well. The measured date were fitted by Kostiako models fitted measured data well with all coefficients of determination greater than 0.9. The constant infiltration rates from the second phase were at least 2 times larger than the estimates from the first phase. In other words, the results indicated that more than 60% of water infiltration was through the preferential passages in the forest soil. The result also shows that durations in the first phase affect the trends of the infiltration curve in the second phase. The result from this study is helpful to understand the mechanism of hydrological response to different land covers.

Ceramic Composite Thin Films

NASA Technical Reports Server (NTRS)

Dikin, Dmitriy A. (Inventor); Nguyen, SonBinh T. (Inventor); Ruoff, Rodney S. (Inventor); Stankovich, Sasha (Inventor)

2013-01-01

A ceramic composite thin film or layer includes individual graphene oxide and/or electrically conductive graphene sheets dispersed in a ceramic (e.g. silica) matrix. The thin film or layer can be electrically conductive film or layer depending the amount of graphene sheets present. The composite films or layers are transparent, chemically inert and compatible with both glass and hydrophilic SiOx/silicon substrates. The composite film or layer can be produced by making a suspension of graphene oxide sheet fragments, introducing a silica-precursor or silica to the suspension to form a sol, depositing the sol on a substrate as thin film or layer, at least partially reducing the graphene oxide sheets to conductive graphene sheets, and thermally consolidating the thin film or layer to form a silica matrix in which the graphene oxide and/or graphene sheets are dispersed.

The Foote House (10-AA-96), An Historic Archaeological Complex in the Boise River Canyon, Idaho.

DTIC Science & Technology

1982-01-01

into four or perhaps five basic rooms, three of which opened into one another (Paul 1972:293). The main front entrance faced west, and consisted of low...sediments were dry screened through 1/4 in. hardward mesh. Four areas in or adjacent to the Foote House were tested to provide structural and (if possible...down into the soil matrix through the first excavation level, to 10 cm depth. At this level, in the northwest quadrant of the unit, a thin layer of

Rock Hole Habitats of a Feral Population of Aedes aegypti on the Island of Anguilla, West Indies

DTIC Science & Technology

1983-03-01

htAHCH, 1983 MOSQUITO NEWS $9 tions of medical importance. Annu. Rev. Entomol. 13:427-450. Fish, D. and S. R. Carpenter. 1982. Leaf litter and...Aedes mgspi larvae (ruler length is 0.31 m). it1 bare rock holes or those containing leaf litter arid/or soil. Larval densities are usually higher in...shade cover. At one end there is a la! er of leaf litter, the remainder has ;I thin mud layer over its rock bottom. During this time, the hole filled

Major and Trace Element Variations in Impact Crater Clay from Chicxulub, Lonar, and Mistastin, Implications for the Martian Soil

NASA Technical Reports Server (NTRS)

Newsom, H. E.; Nelson, M. J.; Shearer, C. K.; Rietmeijer, F. J. M.; Gakin, R.; Lee, K.

2004-01-01

The catastrophic Chicxulub event should have generated a large hydrothermal system with volatile element mobilization, producing interesting alteration materials and clays. The Yaxcopoil-1 (YAX) drill hole is located in the annular trough, about 70 km southwest of the crater center, in an area where the impactite layers are relatively thin (approx. 100 m thick). We have analyzed samples from the YAX drill core and from other impact craters including Mistastin and Lonar to determine the nature of alteration and trace element mobilization.

Thin-layer voltammetry of soluble species on screen-printed electrodes: proof of concept.

PubMed

Botasini, S; Martí, A C; Méndez, E

2016-10-17

Thin-layer diffusion conditions were accomplished on screen-printed electrodes by placing a controlled-weight onto the cast solution and allowing for its natural spreading. The restricted diffusive conditions were assessed by cyclic voltammetry at low voltage scan rates and electrochemical impedance spectroscopy. The relationship between the weight exerted over the drop and the thin-layer thickness achieved was determined, in such a way that the simple experimental set-up designed for this work could be developed into a commercial device with variable control of the thin-layer conditions. The experimental results obtained resemble those reported for the voltammetric features of electroactive soluble species employing electrodes modified with carbon nanotubes or graphene layers, suggesting that the attainment of the benefits reported for these nanomaterials could be done simply by forcing the solution to spread over the screen-printed electrodic system to form a thin layer solution. The advantages of thin-layer voltammetry in the kinetic characterization of quasi-reversible and irreversible processes are highlighted.

[Soil organic carbon mineralization of Black Locust forest in the deep soil layer of the hilly region of the Loess Plateau, China].

PubMed

Ma, Xin-Xin; Xu, Ming-Xiang; Yang, Kai

2012-11-01

The deep soil layer (below 100 cm) stores considerable soil organic carbon (SOC). We can reveal its stability and provide the basis for certification of the deep soil carbon sinks by studying the SOC mineralization in the deep soil layer. With the shallow soil layer (0-100 cm) as control, the SOC mineralization under the condition (temperature 15 degrees C, the soil water content 8%) of Black Locust forest in the deep soil layer (100-400 cm) of the hilly region of the Loess Plateau was studied. The results showed that: (1) There was a downward trend in the total SOC mineralization with the increase of soil depth. The total SOC mineralization in the sub-deep soil (100-200 cm) and deep soil (200-400 cm) were equivalent to approximately 88.1% and 67.8% of that in the shallow layer (0-100 cm). (2) Throughout the carbon mineralization process, the same as the shallow soil, the sub-deep and deep soil can be divided into 3 stages. In the rapid decomposition phase, the ratio of the mineralization or organic carbon to the total mineralization in the sub-deep and deep layer (0-10 d) was approximately 50% of that in the shallow layer (0-17 d). In the slow decomposition phase, the ratio of organic carbon mineralization to total mineralization in the sub-deep, deep layer (11-45 d) was 150% of that in the shallow layer (18-45 d). There was no significant difference in this ratio among these three layers (46-62 d) in the relatively stable stage. (3) There was no significant difference (P > 0.05) in the mineralization rate of SOC among the shallow, sub-deep, deep layers. The stability of SOC in the deep soil layer (100-400 cm) was similar to that in the shallow soil layer and the SOC in the deep soil layer was also involved in the global carbon cycle. The change of SOC in the deep soil layer should be taken into account when estimating the effects of soil carbon sequestration in the Hilly Region of the Loess Plateau, China.

A model for thin layer formation by delayed particle settling at sharp density gradients

NASA Astrophysics Data System (ADS)

Prairie, Jennifer C.; White, Brian L.

2017-02-01

Thin layers - regions where plankton or particles accumulate vertically on scales of a few meters or less - are common in coastal waters, and have important implications for both trophic dynamics and carbon cycling. These features can form by a variety of biological and physical mechanisms, including localized growth, shear-thinning, and directed swimming. An additional mechanism may result in the formation of thin layers of marine aggregates, which have been shown to decrease their settling velocity when passing through sharp density gradients, a behavior termed delayed settling. Here, we apply a simple vertical advection-diffusion model to predict the properties of aggregate thin layers formed by this process. We assume a constant vertical flux of particles from the surface, which is parameterized by observations from laboratory experiments with marine aggregates. The formation, maintenance, and shape of the layers are described in relation to non-dimensional numbers that depend on environmental conditions and particle settling properties. In particular, model results demonstrate layer intensity and sharpness both increase with higher Péclet number (Pe), that is, under conditions with weaker mixing relative to layer formation. Similarly, more intense and sharper layers are found when the delayed settling behavior of aggregates is characterized by a lower velocity minimum. The model also predicts layers that are vertically asymmetric and highly "peaky" when compared with a Gaussian distribution, features often seen in thin layers in natural environments. Lastly, by comparing model predictions with observations of thin layers in the field, we are able to gain some insight into the applicability of delayed settling as a thin layer formation mechanism in different environmental conditions.

Hydrologic and water quality effects of thinning Loblolly Pine

Treesearch

Johnny M. Grace; R. W. Skaggs; G. M. Chescheir

2006-01-01

Forest operations such as harvesting, thinning, and site preparation can affect the hydrologic behavior of watersheds on poorly drained soils. The influence of these operations conducted on organic soil sites can be more pronounced than on mineral soil sites due to the differences in bulk density and soil moisture relationships that exist between mineral and organic...

Thin Film Transistors On Plastic Substrates

DOEpatents

Carey, Paul G.; Smith, Patrick M.; Sigmon, Thomas W.; Aceves, Randy C.

2004-01-20

A process for formation of thin film transistors (TFTs) on plastic substrates replaces standard thin film transistor fabrication techniques, and uses sufficiently lower processing temperatures so that inexpensive plastic substrates may be used in place of standard glass, quartz, and silicon wafer-based substrates. The silicon based thin film transistor produced by the process includes a low temperature substrate incapable of withstanding sustained processing temperatures greater than about 250.degree. C., an insulating layer on the substrate, a layer of silicon on the insulating layer having sections of doped silicon, undoped silicon, and poly-silicon, a gate dielectric layer on the layer of silicon, a layer of gate metal on the dielectric layer, a layer of oxide on sections of the layer of silicon and the layer of gate metal, and metal contacts on sections of the layer of silicon and layer of gate metal defining source, gate, and drain contacts, and interconnects.

Characterization for capillary barriers effects in a sand box test using time-lapsed GPR measurements

NASA Astrophysics Data System (ADS)

Kuroda, S.; Ishii, N.; Morii, T.

2017-12-01

Capillary barriers have been known as the method to protect subsurface regions against infiltration from soil surface. It is caused by essentially heterogeneous structure in permeability or soil physical property and produce non-uniform infiltration process then, in order to estimate the actual situation of the capillary barrier effect, the site-characterization with imaging technique like geophysical prospecting is effective. In this study, we examine the applicability of GPR to characterization for capillary barriers. We built a sand box with 90x340x90cm in which a thin high-permeable gravel layer was embedded as a capillary barrier. We conducted an infiltration test in the sand box using porous tube array for irrigation. It is expected to lead to non-uniform flow of soil water induced by capillary barrier effects. We monitored this process by various types of GPR measurements, including time-lapsed common offset profiling (COP) with multi- frequency antenna and transmission measurements like cross-borehole radar. At first, we conducted GPR common-offset survey. It could show the depth of capillary barrier in sand box. After that we conducted the infiltration test and GPR monitoring for infiltration process. GPR profiles can detect the wetting front and estimate water content change in the soil layer above the capillary barrier. From spatial change in these results we can estimate the effect of capillary barrier and the zone where the break through occur or not. Based on these results, we will discuss the applicability of GPR for monitoring the phenomena around the capillary barrier of soil. At first, we conducted GPR common-offset survey. It could show the depth of capillary barrier in sand box. After that we conducted the infiltration test and GPR monitoring for infiltration process. GPR profiles can detect the wetting front and estimate water content change in the soil layer above the capillary barrier. From spatial change in these results we can estimate the effect of capillary barrier and the zone where the break through occur. Based on these results, we will discuss the applicability of GPR for monitoring the phenomena around the capillary barrier of soil.

Room temperature rubbing for few-layer two-dimensional thin flakes directly on flexible polymer substrates

PubMed Central

Yu, Yan; Jiang, Shenglin; Zhou, Wenli; Miao, Xiangshui; Zeng, Yike; Zhang, Guangzu; Liu, Sisi

2013-01-01

The functional layers of few-layer two-dimensional (2-D) thin flakes on flexible polymers for stretchable applications have attracted much interest. However, most fabrication methods are “indirect” processes that require transfer steps. Moreover, previously reported “transfer-free” methods are only suitable for graphene and not for other few-layer 2-D thin flakes. Here, a friction based room temperature rubbing method is proposed for fabricating different types of few-layer 2-D thin flakes (graphene, hexagonal boron nitride (h-BN), molybdenum disulphide (MoS2), and tungsten disulphide (WS2)) on flexible polymer substrates. Commercial 2-D raw materials (graphite, h-BN, MoS2, and WS2) that contain thousands of atom layers were used. After several minutes, different types of few-layer 2-D thin flakes were fabricated directly on the flexible polymer substrates by rubbing procedures at room temperature and without any transfer step. These few-layer 2-D thin flakes strongly adhere to the flexible polymer substrates. This strong adhesion is beneficial for future applications. PMID:24045289

Hydrogeological and geophysical investigations to evaluate groundwater influences on GHG emissions at the national research site Skogaryd

NASA Astrophysics Data System (ADS)

Banzhaf, Stefan; Klemedtsson, Leif; Sturkell, Erik; Nyström, Elin; Barthel, Roland

2015-04-01

The overall objective of the presented study is to explore the impact of groundwater fluctuations on greenhouse gas (GHG) emissions from peatlands and in particular from drained organic soils. The hypothesis is that drained organic soils react sensitively to changing water content, i.e. that frequent changes of groundwater level enhance the emissions of GHG from these soils and thus contribute significantly to global warming. The area under investigation is based at the Skogaryd Research Catchment (within Swedish Infrastructure for Ecosystem Sciences, SITES) in western Sweden (Meyer, et al., 2013), which was recently assigned the status of a national research site by the Swedish research council (www.vr.se). Skogaryd is a unique place in Sweden for doing research on organic soils as the area was simultaneously afforested in the 1960s and the drained fertile soils have a different land-use history. The ditching for drainage purposes throughout the entire area has had and still has a huge influence on groundwater level, which in turn is assumed to trigger GHG emissions from the organic soils at Skogaryd. To address the influence of groundwater dynamics on GHG emissions in this system, a characterisation of the subsurface using electrical resistivity and Ground Penetrating Radar (GPR) measurements was carried out. These geophysical measurements were combined with drilling along them to allow for ground truthing. An average peat thickness of around 3 m was estimated for the field site. Below the peat follows a fine sand layer, which reaches a maximum thickness of around 1.0 m right at the valley borders and thins out significantly towards the middle of the valley. Below the fine sand layer follows a layer of marine clay, which extends down to the bedrock at depths between 12 and 15 m below ground surface. The results show that the peat layer in Skogaryd forms an isolated hydraulic system without interaction with deeper or regional groundwater systems. The continuously extending clay layer hinders water moving downward or upward crossing the border of peat and clay. The peat layer is a fast reacting hydraulic system that shows immediate reaction to precipitation or drought and is independent from regional groundwater levels. The study of groundwater controls on the GHG from the drained organic soils at Skogaryd can thus focus on the fast reacting peat layer. Future investigations will show if this conclusion can be generalized for similar situations in Sweden. Geophysical measurements have proved to be a valuable method for estimating the peat thickness over a large area. Meyer A, Tarvainen L, Nousratpour A, Björk RG, Ernfors M, Grelle A, Kasimir Klemedtsson Å, Lindroth A, Räntfors M, Rütting T, Wallin G, Weslien P, Klemedtsson L (2013) A fertile peatland forest does not constitute a major greenhouse gas sink. Biogeosciences 10: 7739-7758 DOI 10.5194/bg-10-7739-2013

Tree thinning as an option to increase herbaceous yield of an encroached semi-arid savanna in South Africa

PubMed Central

Smit, Gert N

2005-01-01

Background The investigation was conducted in a savanna area covered by what was considered an undesirably dense stand of Colophospermum mopane trees, mainly because such a dense stand of trees often results in the suppression of herbaceous plants. The objectives of this study were to determine the influence of intensity of tree thinning on the dry matter yield of herbaceous plants (notably grasses) and to investigate differences in herbaceous species composition between defined subhabitats (under tree canopies, between tree canopies and where trees have been removed). Seven plots (65 × 180 m) were subjected to different intensities of tree thinning, ranging from a totally cleared plot (0 %) to plots thinned to the equivalent of 10 %, 20%, 35 %, 50% and 75 % of the leaf biomass of a control plot (100 %) with a tree density of 2711 plants ha-1. The establishment of herbaceous plants (grasses and forbs) in response to reduced competition from the woody plants was measured during three full growing seasons following the thinning treatments. Results The grass component reacted positively to the tree thinning in terms of total dry matter (DM) yield, but forbs were negatively influenced. Rainfall interacted with tree density and the differences between grass DM yields in thinned plots during years of below average rainfall were substantially higher than those of the control. At high tree densities, yields differed little between seasons of varying rainfall. The relation between grass DM yield and tree biomass was curvilinear, best described by the exponential regression equation. Subhabitat differentiation by C. mopane trees did provide some qualitative benefits, with certain desirable grass species showing a preference for the subhabitat under tree canopies. Conclusion While it can be concluded from this study that high tree densities suppress herbaceous production, the decision to clear/thin the C. mopane trees should include additional considerations. Thinning of C. mopane with the exclusive objective of increasing productivity of the grass layer would thus invariably involve a compromise situation where some trees should be left for the sake of the qualitative benefits on the herbaceous layer, soil enrichment, provision of browse and stability of the ecosystem. PMID:15921528

Polymer thin film as coating layer to prevent corrosion of metal/metal oxide film

NASA Astrophysics Data System (ADS)

Sarkar, Suman; Kundu, Sarathi

2018-04-01

Thin film of polymer is used as coating layer and the corrosion of metal/metal oxide layer is studied with the variation of the thickness of the coating layer. The thin layer of polystyrene is fabricated using spin coating method on copper oxide (CuO) film which is deposited on glass substrate using DC magnetron sputtering technique. Thickness of the polystyrene and the CuO layers are determined using X-ray reflectivity (XRR) technique. CuO thin films coated with the polystyrene layer are exposed to acetic acid (2.5 v/v% aqueous CH3COOH solution) environments and are subsequently analyzed using UV-Vis spectroscopy and atomic force microscopy (AFM). Surface morphology of the film before and after interaction with the acidic environment is determined using AFM. Results obtained from the XRR and UV-Vis spectroscopy confirm that the thin film of polystyrene acts as an anticorrosion coating layer and the strength of the coating depends upon the polymer layer thickness at a constant acid concentration.

Nonenzymatic detection of glucose using BaCuO2 thin layer

NASA Astrophysics Data System (ADS)

Ito, Takeshi; Asada, Tsuyoshi; Asai, Naoto; Shimizu, Tomohiro; Shingubara, Shoso

2017-01-01

A BaCuO2 thin layer was deposited on a glassy carbon electrode and used for the direct oxidation of glucose. The crystalline, electrochemical, and physicochemical properties that depend on the deposition temperature and deposition time were studied. X-ray diffraction (XRD) analysis showed that the thin layer was amorphous even at 400 °C. The current density of the glucose oxidation using the thin layer deposited at 200 °C was higher than those at other deposition temperatures. Under this condition, the current density increased with the glucose concentration and deposition time. These results indicate that a BaCuO2 thin layer has potential for measuring the blood glucose level without enzymes.

Management effects on carbon fluxes in boreal forests (Invited)

NASA Astrophysics Data System (ADS)

Lindroth, A.; Mölder, M.; Lagergren, F.; Vestin, P.; Hellström, M.; Sundqvist, E.; Norunda Bgs Team

2010-12-01

Disturbance by management or natural causes such as wind throw or fire are believed to be one of the main factors that are controlling the carbon balance of vegetation. In Northern Europe a large fraction of the forest area is managed with clear cutting and thinning as the main silvicultural methods. The effect of clear-cutting on carbon dioxide exchanges were studied in different chrono-sequences located in Sweden, Finland, UK and France, respectively. The combined results from these studies showed that a simple model could be developed describing relative net ecosystem exchange as a function of relative rotation length (age). A stand with a rotation length of 100 years, typical for Swedish conditions, looses substantial amounts of carbon during the first 12-15 years and the time it takes to reach cumulative balance after clear-cut, is 25-30 years. The mean net ecosystem exchange over the whole rotation length equals 50% of the maximum uptake. An interesting question is if it is possible to harvest without the substantial carbon losses that take place after clear-cutting. Selective harvest by thinning could potentially be such a method. We therefore studied the effect of thinning on soil and ecosystem carbon fluxes in a mixed pine and spruce forest in Central Sweden, the Norunda forest, located in the semi-boreal zone at 60.08°N, 17.48 °E. The CO2 fluxes from the forest were measured by eddy covariance method and soil effluxes were measured by automatic chambers. Maximum canopy height of the ca. 100 years-old forest was 28 m. The stand was composed of ca 72% pine, 28% before the thinning while the composition after the thinning became 82% pine and 18% spruce. The thinning was made in November/December 2008 in a half- circle from the tower with a radius of 200 m. The LAI decreased from 4.5 to 2.8 after the thinning operation. Immediately after the thinning, we found significantly higher soil effluxes, probably due to increased decomposition of dead roots. The stand level flux measurements showed no effect on total ecosystem respiration, probably because of reduced autotrophic respiration from canopy layer. Initially the GPP was slightly reduced as compared to the non-thinned sector but already after 6-7 months, no effect of the thinning on GPP could be detected. We attributed this fast recovery to increased resource availability (nutrients and light) to the remaining trees and possibly also to the ground vegetation. The results indicate that selective harvest such as thinning has a potential to increase the mean net ecosystem exchange over the rotation length mainly because of avoiding the emissions that occur after a heavy disturbance such as that caused by clear-cutting. An important question in this context is how successful the re-growth after thinning will be but that is out of scope of this presentation.

Methods for making thin layers of crystalline materials

DOEpatents

Lagally, Max G; Paskiewicz, Deborah M; Tanto, Boy

2013-07-23

Methods for making growth templates for the epitaxial growth of compound semiconductors and other materials are provided. The growth templates are thin layers of single-crystalline materials that are themselves grown epitaxially on a substrate that includes a thin layer of sacrificial material. The thin layer of sacrificial material, which creates a coherent strain in the single-crystalline material as it is grown thereon, includes one or more suspended sections and one or more supported sections.

A prelanding assessment of the ice table depth and ground ice characteristics in Martian permafrost at the Phoenix landing site

USGS Publications Warehouse

Mellon, M.T.; Boynton, W.V.; Feldman, W.C.; Arvidson, R. E.; Titus, Joshua T.N.; Bandfield, L.; Putzig, N.E.; Sizemore, H.G.

2009-01-01

We review multiple estimates of the ice table depth at potential Phoenix landing sites and consider the possible state and distribution of subsurface ice. A two-layer model of ice-rich material overlain by ice-free material is consistent with both the observational and theoretical lines of evidence. Results indicate ground ice to be shallow and ubiquitous, 2-6 cm below the surface. Undulations in the ice table depth are expected because of the thermodynamic effects of rocks, slopes, and soil variations on the scale of the Phoenix Lander and within the digging area, which can be advantageous for analysis of both dry surficial soils and buried ice-rich materials. The ground ice at the ice table to be sampled by the Phoenix Lander is expected to be geologically young because of recent climate oscillations. However, estimates of the ratio of soil to ice in the ice-rich subsurface layer suggest that that the ice content exceeds the available pore space, which is difficult to reconcile with existing ground ice stability and dynamics models. These high concentrations of ice may be the result of either the burial of surface snow during times of higher obliquity, initially high-porosity soils, or the migration of water along thin films. Measurement of the D/H ratio within the ice at the ice table and of the soil-to-ice ratio, as well as imaging ice-soil textures, will help determine if the ice is indeed young and if the models of the effects of climate change on the ground ice are reasonable. Copyright 2008 by the American Geophysical Union.

3D printed e-tongue

NASA Astrophysics Data System (ADS)

Gaál, Gabriel; da Silva, Tatiana A.; Gaál, Vladimir; Hensel, Rafael C.; Amaral, Lucas R.; Rodrigues, Varlei; Riul, Antonio

2018-05-01

Nowadays, one of the biggest issues addressed to electronic sensor fabrication is the build-up of efficient electrodes as an alternative way to the expensive, complex and multistage processes required by traditional techniques. Printed electronics arises as an interesting alternative to fulfill this task due to the simplicity and speed to stamp electrodes on various surfaces. Within this context, the Fused Deposition Modeling 3D printing is an emerging, cost-effective and alternative technology to fabricate complex structures that potentiates several fields with more creative ideas and new materials for a rapid prototyping of devices. We show here the fabrication of interdigitated electrodes using a standard home-made CoreXY 3D printer using transparent and graphene-based PLA filaments. Macro 3D printed electrodes were easily assembled within 6 minutes with outstanding reproducibility. The electrodes were also functionalized with different nanostructured thin films via dip-coating Layer-by-Layer technique to develop a 3D printed e-tongue setup. As a proof of concept, the printed e-tongue was applied to soil analysis. A control soil sample was enriched with several macro-nutrients to the plants (N, P, K, S, Mg and Ca) and the discrimination was done by electrical impedance spectroscopy of water solution of the soil samples. The data was analyzed by Principal Component Analysis and the 3D printed sensor distinguished clearly all enriched samples despite the complexity of the soil chemical composition. The 3D printed e-tongue successfully used in soil analysis encourages further investments in developing new sensory tools for precision agriculture and other fields exploiting the simplicity and flexibility offered by the 3D printing techniques.

Snow Water Equivalent Retrieval By Markov Chain Monte Carlo Based on Memls and Hut Snow Emission Model

NASA Astrophysics Data System (ADS)

Pan, J.; Durand, M. T.; Vanderjagt, B. J.

2014-12-01

The Markov chain Monte Carlo (MCMC) method had been proved to be successful in snow water equivalent retrieval based on synthetic point-scale passive microwave brightness temperature (TB) observations. This method needs only general prior information about distribution of snow parameters, and could estimate layered snow properties, including the thickness, temperature, density and snow grain size (or exponential correlation length) of each layer. In this study, the multi-layer HUT (Helsinki University of Technology) model and the MEMLS (Microwave Emission Model of Layered Snowpacks) will be used as observation models to assimilate the observed TB into snow parameter prediction. Previous studies had shown that the multi-layer HUT model tends to underestimate TB at 37 GHz for deep snow, while the MEMLS does not show sensitivity of model bias to snow depth. Therefore, results using HUT model and MEMLS will be compared to see how the observation model will influence the retrieval of snow parameters. The radiometric measurements at 10.65, 18.7, 36.5 and 90 GHz at Sodankyla, Finland will be used as MCMC input, and the statistics of all snow property measurement will be used to calculate the prior information. 43 dry snowpits with complete measurements of all snow parameters will be used for validation. The entire dataset are from NorSREx (Nordic Snow Radar Experiment) experiments carried out by Juha Lemmetyinen, Anna Kontu and Jouni Pulliainen in FMI in 2009-2011 winters, and continued two more winters from 2011 to Spring of 2013. Besides the snow thickness and snow density that are directly related to snow water equivalent, other parameters will be compared with observations, too. For thin snow, the previous studies showed that influence of underlying soil is considerable, especially when the soil is half frozen with part of unfrozen liquid water and part of ice. Therefore, this study will also try to employ a simple frozen soil permittivity model to improve the performance of retrieval. The behavior of the Markov chain in soil parameters will be studied.

Impact of thinning on soil properties and biomass in Apalachicola National Forest, Florida

Treesearch

Kelechi James Nwaokorie; Odemari Stephen Mbuya; Johnny Grace

2016-01-01

The effect of a silvicultural operation, row thinning at two intensities (single row, SR, and double row, DR, thinning), on soil properties and biomass were investigated in selected 28 year-old slash pine (Pinus elliotti) plantations in the Apalachicola National Forest. Stands were thinned in May 2011 and burn regimes were executed during dormant...

Improvement in temperature dependence and dielectric tunability properties of PbZr0.52Ti0.48O3 thin films using Ba(Mg1/3Ta2/3)O3 buffer layer

NASA Astrophysics Data System (ADS)

Wu, Zhi; Zhou, Jing; Chen, Wen; Shen, Jie; Yang, Huimin; Zhang, Shisai; Liu, Yueli

2016-12-01

In this paper, Pb(Zr0.52Ti0.48)O3 (PZT) thin films were prepared via sol-gel method. The effects of Ba(Mg1/3Ta2/3)O3 (BMT) buffer layer on the temperature dependence and dielectric tunability properties of PZT thin films were studied. As the thickness of BMT buffer layer increases, the tan δ and tunability of PZT thin films decrease while tunability still maintains above 10%. This result shows that BMT buffer layer can improve the dielectric tunability properties of PZT thin films. Furthermore, the temperature coefficient of the dielectric constant decreases from 2333.4 to 906.9 ppm/°C with the thickness of BMT buffer layer increasing in the range from 25 to 205 °C, indicating that BMT buffer layer can improve the temperature stability of PZT thin films. Therefore, BMT buffer layer plays a critical role in improving temperature dependence and dielectric tunability properties of PbZr0.52Ti0.48O3 thin films.

Breakthrough to Non-Vacuum Deposition of Single-Crystal, Ultra-Thin, Homogeneous Nanoparticle Layers: A Better Alternative to Chemical Bath Deposition and Atomic Layer Deposition

PubMed Central

Liao, Yu-Kuang; Liu, Yung-Tsung; Hsieh, Dan-Hua; Shen, Tien-Lin; Hsieh, Ming-Yang; Tzou, An-Jye; Chen, Shih-Chen; Tsai, Yu-Lin; Lin, Wei-Sheng; Chan, Sheng-Wen; Shen, Yen-Ping; Cheng, Shun-Jen; Chen, Chyong-Hua; Wu, Kaung-Hsiung; Chen, Hao-Ming; Kuo, Shou-Yi; Charlton, Martin D. B.; Hsieh, Tung-Po; Kuo, Hao-Chung

2017-01-01

Most thin-film techniques require a multiple vacuum process, and cannot produce high-coverage continuous thin films with the thickness of a few nanometers on rough surfaces. We present a new ”paradigm shift” non-vacuum process to deposit high-quality, ultra-thin, single-crystal layers of coalesced sulfide nanoparticles (NPs) with controllable thickness down to a few nanometers, based on thermal decomposition. This provides high-coverage, homogeneous thickness, and large-area deposition over a rough surface, with little material loss or liquid chemical waste, and deposition rates of 10 nm/min. This technique can potentially replace conventional thin-film deposition methods, such as atomic layer deposition (ALD) and chemical bath deposition (CBD) as used by the Cu(In,Ga)Se2 (CIGS) thin-film solar cell industry for decades. We demonstrate 32% improvement of CIGS thin-film solar cell efficiency in comparison to reference devices prepared by conventional CBD deposition method by depositing the ZnS NPs buffer layer using the new process. The new ZnS NPs layer allows reduction of an intrinsic ZnO layer, which can lead to severe shunt leakage in case of a CBD buffer layer. This leads to a 65% relative efficiency increase. PMID:28383488

Layer-by-Layer Assembly of a pH-Responsive and Electrochromic Thin Film

ERIC Educational Resources Information Center

Schmidt, Daniel J.; Pridgen, Eric M.; Hammond, Paula T.; Love, J. Christopher

2010-01-01

This article summarizes an experiment on thin-film fabrication with layer-by-layer assembly that is appropriate for undergraduate laboratory courses. The purpose of this experiment is to teach students about self-assembly in the context of thin films and to expose students to the concepts of functional polymeric coatings. Students dip coat…

[Changes of soil physical properties during the conversion of cropland to agroforestry system].

PubMed

Wang, Lai; Gao, Peng Xiang; Liu, Bin; Zhong, Chong Gao; Hou, Lin; Zhang, Shuo Xin

2017-01-01

To provide theoretical basis for modeling and managing agroforestry systems, the influence of conversion of cropland to agroforestry system on soil physical properties was investigated via a walnut (Juglans regia)-wheat (Triticum aestivum) intercropping system, a wide spreading local agroforestry model in northern Weihe River of loess area, with the walnut and wheat monoculture systems as the control. The results showed that the improvement of the intercropping system on soil physical properties mainly appeared in the 0-40 cm soil layer. The intercropping system could prevent soil bulk density rising in the surface soil (0-20 cm), and the plow pan in the 20-40 cm soil layer could be significantly alleviated. The intercropping system had conti-nuous improvement on soil field capacity in each soil layer with the planting age increase, and the soil field capacity was higher than that of each monoculture system in each soil layer (except 20-40 cm soil layer) since the 5th year after planting. The intercropping system had continuous improvement on soil porosity in each soil layer, but mainly in the 0-20 and 20-40 cm soil layer, and the ratio of capillary porosity was also improved. The soil bulk density, field capacity and soil porosity obtained continuous improvement during the conversion of cropland to agroforestry system, and the improvement on soil physical properties was stronger in shallow soil layer than in deep soil.

Arsenic microdistribution and speciation in toenail clippings of children living in a historic gold mining area

DOE Office of Scientific and Technical Information (OSTI.GOV)

Pearce, Dora C.; Dowling, Kim; Gerson, Andrea R.

2010-05-04

Arsenic is naturally associated with gold mineralization and elevated in some soils and mine waste around historical gold mining activity in Victoria, Australia. To explore uptake, arsenic concentrations in children's toenail clippings and household soils were measured, and the microdistribution and speciation of arsenic in situ in toenail clipping thin sections investigated using synchrotron-based X-ray microprobe techniques. The ability to differentiate exogenous arsenic was explored by investigating surface contamination on cleaned clippings using depth profiling, and direct diffusion of arsenic into incubated clippings. Total arsenic concentrations ranged from 0.15 to 2.1 {micro}g/g (n = 29) in clipping samples and frommore » 3.3 to 130 {micro}g/g (n = 22) in household soils, with significant correlation between transformed arsenic concentrations (Pearson's r = 0.42, P = 0.023) when household soil was treated as independent. In clipping thin sections (n = 2), X-ray fluorescence (XRF) mapping showed discrete layering of arsenic consistent with nail structure, and irregular arsenic incorporation along the nail growth axis. Arsenic concentrations were heterogeneous at 10 x 10 {micro}m microprobe spot locations investigated (< 0.1 to 13.3 {micro}g/g). X-ray absorption near-edge structure (XANES) spectra suggested the presence of two distinct arsenic species: a lower oxidation state species, possibly with mixed sulphur and methyl coordination (denoted As{sub (-S, -ch3)}{sup {approx}III}); and a higher oxidation state species (denoted As{sub (-O)}{sup {approx}V}). Depth profiling suggested that surface contamination was unlikely (n = 4), and XRF and XANES analyses of thin sections of clippings incubated in dry or wet mine waste, or untreated, suggested direct diffusion of arsenic occurred under moist conditions. These findings suggest that arsenic in soil contributes to some systemic absorption associated with periodic exposures among children resident in areas of historic gold mining activity in Victoria, Australia. Future studies are required to ascertain if adverse health effects are associated with current levels of arsenic uptake.« less

Gyrotactic trapping: A numerical study

NASA Astrophysics Data System (ADS)

Ghorai, S.

2016-04-01

Gyrotactic trapping is a mechanism proposed by Durham et al. ["Disruption of vertical motility by shear triggers formation of thin Phytoplankton layers," Science 323, 1067-1070 (2009)] to explain the formation of thin phytoplankton layer just below the ocean surface. This mechanism is examined numerically using a rational model based on the generalized Taylor dispersion theory. The crucial role of sedimentation speed in the thin layer formation is demonstrated. The effects of variation in different parameters on the thin layer formation are also investigated.

[High performance thin-layer chromatography in specific blood diagnosis (author's transl)].

PubMed

Bernardelli, B; Masotti, G

1976-01-01

Furthering their research into the differentiation of various haemoglobins (both human and animal) with the use of thin layer chromatographic methods, the Authors have applied Kaiser's high performance thin layer chromatography (HPTLC) to the specific diagnosis of blood. Although the method was superior to ascending one-dimensional thin layer chromatography for its sensitivity, Rf reproducibility and much briefer migration times, it did not turn out to be suitable for application to the specific requirements of forensic haematology.

Thin-film metal coated insulation barrier in a Josephson tunnel junction. [Patent application

DOEpatents

Hawkins, G.A.; Clarke, J.

1975-10-31

A highly stable, durable, and reproducible Josephson tunnel junction consists of a thin-film electrode of a hard superconductor, a thin oxide insulation layer over the electrode constituting a Josephson tunnel junction barrier, a thin-film layer of stabilizing metal over the barrier, and a second thin-film hard superconductive electrode over the stabilizing film. The thin stabilizing metal film is made only thick enough to limit penetration of the electrode material through the insulation layer so as to prevent a superconductive short.

Fabrication of Crack-Free Barium Titanate Thin Film with High Dielectric Constant Using Sub-Micrometric Scale Layer-by-Layer E-Jet Deposition.

PubMed

Liang, Junsheng; Li, Pengfei; Wang, Dazhi; Fang, Xu; Ding, Jiahong; Wu, Junxiong; Tang, Chang

2016-01-19

Dense and crack-free barium titanate (BaTiO₃, BTO) thin films with a thickness of less than 4 μm were prepared by using sub-micrometric scale, layer-by-layer electrohydrodynamic jet (E-jet) deposition of the suspension ink which is composed of BTO nanopowder and BTO sol. Impacts of the jet height and line-to-line pitch of the deposition on the micro-structure of BTO thin films were investigated. Results show that crack-free BTO thin films can be prepared with 4 mm jet height and 300 μm line-to-line pitch in this work. Dielectric constant of the prepared BTO thin film was recorded as high as 2940 at 1 kHz at room temperature. Meanwhile, low dissipation factor of the BTO thin film of about 8.6% at 1 kHz was also obtained. The layer-by-layer E-jet deposition technique developed in this work has been proved to be a cost-effective, flexible and easy to control approach for the preparation of high-quality solid thin film.

Performance enhancement in Sb doped Cu(InGa)Se2 thin film solar cell by e-beam evaporation

NASA Astrophysics Data System (ADS)

Chen, Jieyi; Shen, Honglie; Zhai, Zihao; Li, Yufang; Yi, Yunge

2018-03-01

To investigate the effects of Sb doping on the structural and electrical properties of Cu(InGa)Se2 (CIGS) thin films and solar cells, CIGS thin films, prepared by e-beam evaporation on soda-lime glass, were doped with lower and upper Sb layers in the precursor stacks respectively. Change of structure and introduction of stress were observed in the CIGS thin films with upper Sb layer in stack through XRD and Raman measurement. Both crystalline quality and compactness of CIGS thin films were improved by the doping of upper Sb layer in stack and the CIGS thin film showed an optimal structural property with 20 nm Sb layer. Movement of Fermi level of the surface of CIGS thin film after doping of upper Sb layer in stack and electrons transfer between Cu/Cu+ redox couple and CIGS thin films, which provided probability for the substitution of Sb for Cu sites at the surface of CIGS thin films, were proposed to explain the migration of Cu from the surface to the bulk of CIGS thin films. The larger barrier at the CIGS/CdS interface after doping of upper Sb layer in stack made contribution to the increase of VOC of CIGS solar cells. The efficiency of CIGS solar cell was improved from 3.3% to 7.2% after doping with 20 nm upper Sb. Compared to the CIGS solar cell with lower Sb layer in stack, in which an additional Cu2-xSe phase was found, the CIGS solar cell with upper Sb layer in stack possessed a higher efficiency.

Evaluation of double-layer density modulated Si thin films as Li-ion battery anodes

NASA Astrophysics Data System (ADS)

Taha Demirkan, Muhammed; Yurukcu, Mesut; Dursun, Burcu; Demir-Cakan, Rezan; Karabacak, Tansel

2017-10-01

Double-layer density modulated silicon thin films which contain alternating low and high density Si film layers were fabricated by magnetron sputtering. Two different samples consisting of alternating layers of high-density/low-density and low-density/high-density Si thin film layers were investigated as anode electrodes in Li-ion batteries. Si thin film in which the terminating layer at the top is low density Si layer-quoted as low-density/high-density film (LD/HD)- exhibits better performance than Si thin film that has high density layer at the top, -quoted as high-density/low-density (HD/LD). A highly stabilized cycling performance with the specific charge capacities of 2000 mAh g-1 at the 150th cycle at C/2 current density, and 1200 mAh g-1 at the 240th cycle at 10 C current density were observed for the LD/HD Si anode in the presence of fluoroethylene carbonate (FEC) electrolyte additive.

Photovoltaic devices comprising cadmium stannate transparent conducting films and method for making

DOEpatents

Wu, Xuanzhi; Coutts, Timothy J.; Sheldon, Peter; Rose, Douglas H.

1999-01-01

A photovoltaic device having a substrate, a layer of Cd.sub.2 SnO.sub.4 disposed on said substrate as a front contact, a thin film comprising two or more layers of semiconductor materials disposed on said layer of Cd.sub.2 SnO.sub.4, and an electrically conductive film disposed on said thin film of semiconductor materials to form a rear electrical contact to said thin film. The device is formed by RF sputter coating a Cd.sub.2 SnO.sub.4 layer onto a substrate, depositing a thin film of semiconductor materials onto the layer of Cd.sub.2 SnO.sub.4, and depositing an electrically conductive film onto the thin film of semiconductor materials.

CPT-based probabilistic and deterministic assessment of in situ seismic soil liquefaction potential

USGS Publications Warehouse

Moss, R.E.S.; Seed, R.B.; Kayen, R.E.; Stewart, J.P.; Der Kiureghian, A.; Cetin, K.O.

2006-01-01

This paper presents a complete methodology for both probabilistic and deterministic assessment of seismic soil liquefaction triggering potential based on the cone penetration test (CPT). A comprehensive worldwide set of CPT-based liquefaction field case histories were compiled and back analyzed, and the data then used to develop probabilistic triggering correlations. Issues investigated in this study include improved normalization of CPT resistance measurements for the influence of effective overburden stress, and adjustment to CPT tip resistance for the potential influence of "thin" liquefiable layers. The effects of soil type and soil character (i.e., "fines" adjustment) for the new correlations are based on a combination of CPT tip and sleeve resistance. To quantify probability for performancebased engineering applications, Bayesian "regression" methods were used, and the uncertainties of all variables comprising both the seismic demand and the liquefaction resistance were estimated and included in the analysis. The resulting correlations were developed using a Bayesian framework and are presented in both probabilistic and deterministic formats. The results are compared to previous probabilistic and deterministic correlations. ?? 2006 ASCE.

Evaluation of potential site for mineral processing plant

NASA Astrophysics Data System (ADS)

Izwan Ishak, Muhamad Noor; Sipaun, Susan Maria; Mustapha, Ismail; Fahmi Engku Chik, Engku Mohd; Abdullah, Nurliyana; Affandi Mahmood, Airwan

2018-01-01

Nuclear moisture-density gauge is a type of instrument for measuring density and moisture of the material in a relatively thin zone beneath a surface of the material by using low activity of neutron and gamma radiation source. Density and moisture content data of the compacted layers are needed to determine the degree of compaction of soils, aggregate, concrete, asphalt or other materials used in civil engineering works. A gamma radiation source is mounted inside gauge housing with the source rod vertically extended to various depth positions. Direct transmission gamma radiation technique is used to obtain the count reading for the number of photons emitted before it is converted into density reading by microprocessor. This paper presents the inspection technique and results for the measurement of soil moisture and density carried out at potential site for mineral processing plant, Malaysian Nuclear Agency. Primarily, the experiment was conducted to ensure the compaction of ground is suitable for the plant construction. From the calculation, the percentages of soil wet density compaction (%WD Compact) are within acceptable limits with respect to the standard compacted wet soil density measured in the laboratory.

Amplitude various angles (AVA) phenomena in thin layer reservoir: Case study of various reservoirs

DOE Office of Scientific and Technical Information (OSTI.GOV)

Nurhandoko, Bagus Endar B., E-mail: bagusnur@bdg.centrin.net.id, E-mail: bagusnur@rock-fluid.com; Rock Fluid Imaging Lab., Bandung; Susilowati, E-mail: bagusnur@bdg.centrin.net.id, E-mail: bagusnur@rock-fluid.com

2015-04-16

Amplitude various offset is widely used in petroleum exploration as well as in petroleum development field. Generally, phenomenon of amplitude in various angles assumes reservoir’s layer is quite thick. It also means that the wave is assumed as a very high frequency. But, in natural condition, the seismic wave is band limited and has quite low frequency. Therefore, topic about amplitude various angles in thin layer reservoir as well as low frequency assumption is important to be considered. Thin layer reservoir means the thickness of reservoir is about or less than quarter of wavelength. In this paper, I studied aboutmore » the reflection phenomena in elastic wave which considering interference from thin layer reservoir and transmission wave. I applied Zoeppritz equation for modeling reflected wave of top reservoir, reflected wave of bottom reservoir, and also transmission elastic wave of reservoir. Results show that the phenomena of AVA in thin layer reservoir are frequency dependent. Thin layer reservoir causes interference between reflected wave of top reservoir and reflected wave of bottom reservoir. These phenomena are frequently neglected, however, in real practices. Even though, the impact of inattention in interference phenomena caused by thin layer in AVA may cause inaccurate reservoir characterization. The relation between classes of AVA reservoir and reservoir’s character are different when effect of ones in thin reservoir and ones in thick reservoir are compared. In this paper, I present some AVA phenomena including its cross plot in various thin reservoir types based on some rock physics data of Indonesia.« less

Prescribed burning and mechanical thinning effects on belowground conditions and soil respiration in a mixed-conifer forest, California

Treesearch

Soung-Ryoul Ryu; Amy Concilio; Jiquan Chen; Malcolm North; Siyan Ma

2009-01-01

Soil respiration (RS) is a major carbon pathway from terrestrial ecosystems to the atmosphere and is sensitive to environmental changes. Although commonly used mechanical thinning and prescribed burning can significantly alter the soil environment, the effect of these practices on RS...

Water-retaining barrier and method of construction

DOEpatents

Adams, Melvin R.; Field, Jim G.

1996-01-01

An agricultural barrier providing a medium for supporting plant life in an arid or semi-arid land region having a ground surface, the barrier being disposed on native soil of the region, the barrier including: a first layer composed of pieces of basalt, the first layer being porous and being in contact with the native soil; a porous second layer of at least one material selected from at least one of sand and gravel, the second layer being less porous than, and overlying, the first layer; and a porous third layer containing soil which favors plant growth, the third layer being less porous than, and overlying, the second layer and having an exposed upper surface, wherein the porosities of the second and third layers differ from one another by an amount which impedes transport of soil from the first layer into the second layer. Soil for the third layer may be provided by washing salinated or contaminated soil with water and using the washed soil for the third layer.

Water-retaining barrier and method of construction

DOEpatents

Adams, M.R.; Field, J.G.

1996-02-20

An agricultural barrier is disclosed which provides a medium for supporting plant life in an arid or semi-arid land region having a ground surface. The barrier is disposed on native soil of the region. The barrier includes a first porous layer composed of pieces of basalt, and is in contact with the native soil. There is a less porous second layer of at least one material selected from at least one of sand and gravel. The second layer overlies the first layer. A third layer, less porous than the second layer, contains soil which favors plant growth. The third layer overlies the second layer and has an exposed upper surface. The porosities of the second and third layers differ from one another by an amount which impedes transport of soil from the first layer into the second layer. Soil for the third layer may be provided by washing salinated or contaminated soil with water and using the washed soil for the third layer. 2 figs.

[Screening and optimization of cholesterol conversion strain].

PubMed

Fan, Dan; Xiong, Bingjian; Pang, Cuiping; Zhu, Xiangdong

2014-10-04

Bacterial strain SE-1 capable of transforming cholesterol was isolated from soil and characterized. The transformation products were identified. Fermentation conditions were optimized for conversion. Cholesterol was used as sole carbon source to isolate strain SE-1. Morphology, physiological and biochemical characteristics of strain SE-1 were studied. 16S rRNA gene was sequenced and subjected to phylogenetic analysis. Fermentation supernatants were extracted with chloroform, the transformation products were analyzed by silica gel thin layer chromatography and Sephadex LH20. Their structures were identified by 1H-NMR and 13C-NMR. Fermentation medium including carbon and nitrogen, methods of adding substrates and fermentation conditions for Strain SE-1 were optimized. Strain SE-1 was a Gram-negative bacterium, exhibiting the highest homologs to Burkholderia cepacia based on the physiological analysis. The sequence analysis of 16S rRNA gene of SE-1 strain and comparison with related Burkholderia show that SE-1 strain was very close to B. cepacia (Genbank No. U96927). The similarity was 99%. The result of silica gel thin layer chromatography shows that strain SE-1 transformed cholesterol to two products, 7beta-hydroxycholesterol and the minor product was 7-oxocholesterol. The optimum culture conditions were: molasses 5%, (NH4 )2SO4 0.3%, 4% of inoculation, pH 7.5 and 36 degrees C. Under the optimum culture condition, the conversion rate reached 34.4% when concentration of cholesterol-Tween 80 was 1 g/L. Cholesterol 7beta-hydroxylation conversion rate under optimal conditions was improved by 20.8%. Strain SE-1 isolated from soil is capable of converting cholesterol at lab-scale.

Impact of ecosystem management on microbial community level physiological profiles of postmining forest rehabilitation.

PubMed

Cookson, W R; O'Donnell, A J; Grant, C D; Grierson, P F; Murphy, D V

2008-02-01

We investigated the impacts of forest thinning, prescribed fire, and contour ripping on community level physiological profiles (CLPP) of the soil microbial population in postmining forest rehabilitation. We hypothesized that these management practices would affect CLPP via an influence on the quality and quantity of soil organic matter. The study site was an area of Jarrah (Eucalyptus marginata Donn ex Sm.) forest rehabilitation that had been mined for bauxite 12 years previously. Three replicate plots (20 x 20 m) were established in nontreated forest and in forest thinned from 3,000-8,000 stems ha(-1) to 600-800 stems ha(-1) in April (autumn) of 2003, followed either by a prescribed fire in September (spring) of 2003 or left nonburned. Soil samples were collected in August 2004 from two soil depths (0-5 cm and 5-10 cm) and from within mounds and furrows caused by postmining contour ripping. CLPP were not affected by prescribed fire, although the soil pH and organic carbon (C), total C and total nitrogen (N) contents were greater in burned compared with nonburned plots, and the coarse and fine litter mass lower. However, CLPP were affected by forest thinning, as were fine litter mass, soil C/N ratio, and soil pH, which were all higher in thinned than nonthinned plots. Furrow soil had greater coarse and fine litter mass, and inorganic phosphorous (P), organic P, organic C, total C, total N, ammonium, microbial biomass C contents, but lower soil pH and soil C/N ratio than mound soil. Soil pH, inorganic P, organic P, organic C, total C and N, ammonium, and microbial biomass C contents also decreased with depth, whereas soil C/N ratio increased. Differences in CLPP were largely (94%) associated with the relative utilization of gluconic, malic (greater in nonthinned than thinned soil and mound than furrow soil), L-tartaric, succinic, and uric acids (greater in thinned than nonthinned, mound than furrow, and 5-10 cm than 0-5 cm soil). The relative utilization of amino acids also tended to increase with increasing soil total C and organic C contents but decreased with increasing nitrate content, whereas the opposite was true for carboxylic acids. Only 45% of the variance in CLPP was explained using a multivariate multiple regression model, but soil C and N pools and litter mass were significant predictors of CLPP. Differences in soil textural components between treatments were also correlated with CLPP; likely causes of these differences are discussed. Our results suggest that 1 year after treatment, CLPP from this mined forest ecosystem are resilient to a spring prescribed fire but not forest thinning. We conclude that differences in CLPP are likely to result from complex interactions among soil properties that mediate substrate availability, microbial nutrient demand, and microbial community composition.

Uncooled thin film pyroelectric IR detector with aerogel thermal isolation

DOEpatents

Ruffner, Judith A.; Bullington, Jeff A.; Clem, Paul G.; Warren, William L.; Brinker, C. Jeffrey; Tuttle, Bruce A.; Schwartz, Robert W.

1999-01-01

A monolithic infrared detector structure which allows integration of pyroelectric thin films atop low thermal conductivity aerogel thin films. The structure comprises, from bottom to top, a substrate, an aerogel insulating layer, a lower electrode, a pyroelectric layer, and an upper electrode layer capped by a blacking layer. The aerogel can offer thermal conductivity less than that of air, while providing a much stronger monolithic alternative to cantilevered or suspended air-gap structures for pyroelectric thin film pixel arrays. Pb(Zr.sub.0.4 Ti.sub.0.6)O.sub.3 thin films deposited on these structures displayed viable pyroelectric properties, while processed at 550.degree. C.

Microstructure and thermochromic properties of VOX-WOX-VOX ceramic thin films

NASA Astrophysics Data System (ADS)

Khamseh, S.; Araghi, H.; Ghahari, M.; Faghihi Sani, M. A.

2016-03-01

W-doped VO2 films have been synthesized via oxygen annealing of V-W-V (vanadium-tungsten-vanadium) multilayered films. The effects of middle layer's thickness of V-W-V multilayered film on structure and properties of VOX-WOX-VOX ceramic thin films were investigated. The as-deposited V-W-V multilayered film showed amorphous-like structure when mixed structure of VO2 (M) and VO2 (B) was formed in VOX-WOX-VOX ceramic thin films. Tungsten content of VOX-WOX-VOX ceramic thin films increased with increasing middle layer's thickness. With increasing middle layer's thickness, room temperature square resistance ( R sq) of VOX-WOX-VOX ceramic thin films increased from 65 to 86 kΩ/sq. The VOX-WOX-VOX ceramic thin film with the thinnest middle layer showed significant SMT (semiconductor-metal transition) when SMT became negligible on increasing middle layer's thickness.

Maintaining soil productivity during forest or biomass-to-energy thinning harvests in the western United States

Treesearch

Deborah S. Page-Dumroese; Martin Jurgensen; Thomas Terry

2010-01-01

Forest biomass thinnings, to promote forest health or for energy production, can potentially impact the soil resource by altering soil physical, chemical, and/or biological properties. The extent and degree of impacts within a harvest unit or across a watershed will subsequently determine if site or soil productivity is affected. Although the impacts of stand removal...

Soil microbiological properties and enzymatic activities of long-term post-fire recovery in dry and semiarid Aleppo pine (Pinus halepensis M.) forest stands

NASA Astrophysics Data System (ADS)

Hedo, J.; Lucas-Borja, M. E.; Wic, C.; Andrés Abellán, M.; de Las Heras, J.

2014-10-01

Wildfires affecting forest ecosystems and post-fire silvicultural treatments may cause considerable changes in soil properties. The capacity of different microbial groups to recolonize soil after disturbances is crucial for proper soil functioning. The aim of this work was to investigate some microbial soil properties and enzyme activities in semiarid and dry Aleppo pine (Pinus halepensis M.) forest stands. Different plots affected by a wildfire event 17 years ago without or with post-fire silvicultural treatments five years after the fire event were selected. A mature Aleppo pine stand unaffected by wildfire and not thinned was used as a control. Physicochemical soil properties (soil texture, pH, carbonates, organic matter, electrical conductivity, total N and P), soil enzymes (urease, phosphatase, β-glucosidase and dehydrogenase activities), soil respiration and soil microbial biomass carbon were analysed in the selected forests areas and plots. The main finding was that long time after this fire event produces no differences in the microbiological soil properties and enzyme activities of soil after comparing burned and thinned, burned and not thinned, and mature plots. Thus, the long-term consequences and post-fire silvicultural management in the form of thinning have a significant effect on the site recovery after fire. Moreover, significant site variation was generally seen in soil enzyme activities and microbiological parameters. We conclude that total vegetation restoration normalises microbial parameters, and that wildfire and post-fire silvicultural treatments are not significant factors of soil properties after 17 years.

How Trees Interact with Their Hydrologic Environment: a Stable Isotope Study

NASA Astrophysics Data System (ADS)

Gierke, C.; Newton, T.

2012-12-01

The Sacramento Mountains of southeast New Mexico serve as the primary recharge area to adjacent regional aquifers, including the Roswell Artesian Basin, the Tularosa Basin and the Salt Basin. Under pressures of population growth and climate change, land and water managers are interested in identifying land management and forest restoration methods that may increase local and regional groundwater recharge in the high mountains. The Sacramento Mountain Watershed Study is designed to assess the effects of tree thinning in mountain watersheds as an effective method of increasing groundwater recharge. The project employs a soil water balance to quantify the partitioning of local precipitation before and after tree thinning. This study was designed to determine the role that trees play in the hydrologic cycle by using the stable isotopes of oxygen and hydrogen to identify tree water sources. The study is being conducted in a 1st order watershed with no perennial outflow stream where vegetation is dominated by Douglas Fir (Pseudotsuga Menziesii). Ridges are capped with San Andres Limestone while lower slopes and the valley bottom are underlain by the Yeso Formation which is composed of sandstones, mudstones and interbedded carbonate layers. The area has thin soils covering shallow fractured bedrock or epikarst features. Some of the fractures within the epikarst zone provide direct conduits to the larger groundwater system while others are isolated rendering the reservoir inactive. From March 2011 to February 2012, we collected soil and twig samples from which water was extracted by cryogenic vacuum distillation. Soil water was also sampled with passive capillary samplers (PCAPS). The isotopic composition of bulk soil water appears to be controlled by evaporation of snowmelt stored within the soil matrix. The isotopic composition of soil water sampled by wick samplers reflects mixing of non-evaporated rainfall with evaporated bulk soil water. As the monsoon season progressed and cumulative rainfall increased, the isotopic composition of mobile soil water evolved towards that of local precipitation. The isotopic composition of twig water samples resembled that of bulk soil water from March and July 2011. In August, September and into November, twig water isotope values appeared to have both bulk soil water and mobile soil water contributions. The conceptual model that we have developed to explain this phenomenon relies on different infiltration mechanisms for snowmelt and monsoon precipitation which determine where water is stored. Snowmelt infiltrates soil and is stored in shallow soils where trees can easily access it. Short duration, high intensity monsoon rains in the late summer exceed infiltration capacity, exploit preferential flow paths and quickly flush through profiles to recharge groundwater and shallow epikarst reservoirs in the underlying bedrock. As epikarst storage increases, a secondary root system is able to begin exploiting the newly available source in the epikarst feature. The contribution of this secondary source manifests in tree water as an integrated mixture of bulk soil water and mobile soil water. Continued use into November of these two water sources by certain trees while others returned to bulk soil water usage suggests spatial variation in epikarst storage and drainage.

System and Method for Fabricating Super Conducting Circuitry on Both Sides of an Ultra-Thin Layer

NASA Technical Reports Server (NTRS)

Brown, Ari D. (Inventor); Mikula, Vilem (Inventor)

2017-01-01

A method of fabricating circuitry in a wafer includes depositing a superconducting metal on a silicon on insulator wafer having a handle wafer, coating the wafer with a sacrificial layer and bonding the wafer to a thermally oxide silicon wafer with a first epoxy. The method includes flipping the wafer, thinning the flipped wafer by removing a handle wafer, etching a buried oxide layer, depositing a superconducting layer, bonding the wafer to a thermally oxidized silicon wafer having a handle wafer using an epoxy, flipping the wafer again, thinning the flipped wafer, etching a buried oxide layer from the wafer and etching the sacrificial layer from the wafer. The result is a wafer having superconductive circuitry on both sides of an ultra-thin silicon layer.

Photoluminescence-based quality control for thin film absorber layers of photovoltaic devices

DOEpatents

Repins, Ingrid L.; Kuciauskas, Darius

2015-07-07

A time-resolved photoluminescence-based system providing quality control during manufacture of thin film absorber layers for photovoltaic devices. The system includes a laser generating excitation beams and an optical fiber with an end used both for directing each excitation beam onto a thin film absorber layer and for collecting photoluminescence from the absorber layer. The system includes a processor determining a quality control parameter such as minority carrier lifetime of the thin film absorber layer based on the collected photoluminescence. In some implementations, the laser is a low power, pulsed diode laser having photon energy at least great enough to excite electron hole pairs in the thin film absorber layer. The scattered light may be filterable from the collected photoluminescence, and the system may include a dichroic beam splitter and a filter that transmit the photoluminescence and remove scattered laser light prior to delivery to a photodetector and a digital oscilloscope.

Device and method for luminescence enhancement by resonant energy transfer from an absorptive thin film

DOE Office of Scientific and Technical Information (OSTI.GOV)

Akselrod, Gleb M.; Bawendi, Moungi G.; Bulovic, Vladimir

Disclosed are a device and a method for the design and fabrication of the device for enhancing the brightness of luminescent molecules, nanostructures, and thin films. The device includes a mirror, a dielectric medium or spacer, an absorptive layer, and a luminescent layer. The absorptive layer is a continuous thin film of a strongly absorbing organic or inorganic material. The luminescent layer may be a continuous luminescent thin film or an arrangement of isolated luminescent species, e.g., organic or metal-organic dye molecules, semiconductor quantum dots, or other semiconductor nanostructures, supported on top of the absorptive layer.

Advanced germanium layer transfer for ultra thin body on insulator structure

NASA Astrophysics Data System (ADS)

Maeda, Tatsuro; Chang, Wen-Hsin; Irisawa, Toshifumi; Ishii, Hiroyuki; Hattori, Hiroyuki; Poborchii, Vladimir; Kurashima, Yuuichi; Takagi, Hideki; Uchida, Noriyuki

2016-12-01

We present the HEtero-Layer Lift-Off (HELLO) technique to obtain ultra thin body (UTB) Ge on insulator (GeOI) substrates. The transferred ultra thin Ge layers are characterized by the Raman spectroscopy measurements down to the thickness of ˜1 nm, observing a strong Raman intensity enhancement for high quality GeOI structure in ultra thin regime due to quantum size effect. This advanced Ge layer transfer technique enabled us to demonstrate UTB-GeOI nMOSFETs with the body thickness of only 4 nm.

Y1Ba2Cu3O(6+delta) growth on thin Y-enhanced SiO2 buffer layers on silicon

NASA Technical Reports Server (NTRS)

Robin, T.; Mesarwi, A.; Wu, N. J.; Fan, W. C.; Espoir, L.; Ignatiev, A.; Sega, R.

1991-01-01

SiO2 buffer layers as thin as 2 nm have been developed for use in the growth of Y1Ba2Cu3O(6+delta) thin films on silicon substrates. The SiO2 layers are formed through Y enhancement of silicon oxidation, and are highly stoichiometric. Y1Ba2Cu3O(6+delta) film growth on silicon with thin buffer layers has shown c orientation and Tc0 = 78 K.

Some Remarks on Practical Aspects of Laboratory Testing of Deep Soil Mixing Composites Achieved in Organic Soils

NASA Astrophysics Data System (ADS)

Kanty, Piotr; Rybak, Jarosław; Stefaniuk, Damian

2017-10-01

This paper presents the results of laboratory testing of organic soil-cement samples are presented in the paper. The research program continues previously reported the authors’ experiences with cement-fly ash-soil sample testing. Over 100 of compression and a dozen of tension tests have been carried out altogether. Several samples were waiting for failure test for over one year after they were formed. Several factors, like: the large amount of the tested samples, a long observation time, carrying out the tests in complex cycles of loading and the possibility of registering the loads and deformation in the axial and lateral direction - have made it possible to take into consideration numerous interdependencies, three of which have been presented in this work: the increments of compression strength, the stiffness of soil-cement in relation to strength and the tensile strength. Compressive strength, elastic modulus and tensile resistance of cubic samples were examined. Samples were mixed and stored in the laboratory conditions. Further numerical analysis in the Finite Element Method numerical code Z_Soil, were performed on the basis of laboratory test results. Computations prove that cement-based stabilization of organic soil brings serious risks (in terms of material capacity and stiffness) and Deep Soil Mixing technology should not be recommended for achieving it. The numerical analysis presented in the study below includes only one type of organic and sandy soil and several possible geometric combinations. Despite that, it clearly points to the fact that designing the DSM columns in the organic soil may be linked with a considerable risk and the settlement may reach too high values. During in situ mixing, the organic material surrounded by sand layers surely mixes with one another in certain areas. However, it has not been examined and it is difficult to assume such mixing already at the designing stage. In case of designing the DSM columns which goes through a thin layer of organic soil it is recommended to carry out each time the core drilling which checks the degree of material mixing and their strength.

Photovoltaic devices comprising cadmium stannate transparent conducting films and method for making

DOEpatents

Wu, X.; Coutts, T.J.; Sheldon, P.; Rose, D.H.

1999-07-13

A photovoltaic device is disclosed having a substrate, a layer of Cd[sub 2]SnO[sub 4] disposed on said substrate as a front contact, a thin film comprising two or more layers of semiconductor materials disposed on said layer of Cd[sub 2]SnO[sub 4], and an electrically conductive film disposed on said thin film of semiconductor materials to form a rear electrical contact to said thin film. The device is formed by RF sputter coating a Cd[sub 2]SnO[sub 4] layer onto a substrate, depositing a thin film of semiconductor materials onto the layer of Cd[sub 2]SnO[sub 4], and depositing an electrically conductive film onto the thin film of semiconductor materials. 10 figs.

Layered Organization in the Coastal Ocean: 4-D Assessment of Thin Layer Structure, Dynamics and Impacts

DTIC Science & Technology

2009-09-30

maintenance and dissipation of layers; (2) to understand the spatial coherence and spatial properties of thin layers in the coastal ocean (especially in...ORCAS profilers at K1 South and K2 had a Nortek ADV (Acoustic Doppler Velocity meter) for simultaneously measuring centimeter- scale currents and...year will be used to (1) detect the presence, intensity, thickness, temporal persistence, and spatial coherence of thin optical and acoustical layers

A tri-layer thin film containing graphene oxide to protect zinc substrates from wear

NASA Astrophysics Data System (ADS)

Wang, Ying; Gu, Zhengpeng; Yuan, Ningyi; Chu, Fuqiang; Cheng, Guanggui; Ding, Jianning

2018-06-01

Due to its excellent properties, Zn alloy is widely used in daily life. However, the poor wear-resisting properties of Zn alloys limits their application. In this paper, a tri-layer thin film consisting of 3-aminopropyltriethoxysilane (APS), graphene oxide (GO) and perfluoropolyethers (PFPE) were successfully prepared on the surface of Zn alloy to improve the wear-resisting properties. The as-prepared tri-layer thin films were characterized by atomic force microscopy, Raman spectroscopy, x-ray photoelectron spectroscopy and contact angle measurement. In addition, the tribological properties of the as-prepared tri-layer thin films were studied on a ball-on-plate tribometer and the morphologies of worn surfaces were observed using 3D noncontact interferometric microscope. Compared with the control samples, the tri-layer thin films showed excellent friction-reducing and wear-resisting properties, which was attributed to the synergistic effect of the GO as the load-carrying layer and the PFPE as the lubricating layer.

Fabrication of Crack-Free Barium Titanate Thin Film with High Dielectric Constant Using Sub-Micrometric Scale Layer-by-Layer E-Jet Deposition

PubMed Central

Liang, Junsheng; Li, Pengfei; Wang, Dazhi; Fang, Xu; Ding, Jiahong; Wu, Junxiong; Tang, Chang

2016-01-01

Dense and crack-free barium titanate (BaTiO3, BTO) thin films with a thickness of less than 4 μm were prepared by using sub-micrometric scale, layer-by-layer electrohydrodynamic jet (E-jet) deposition of the suspension ink which is composed of BTO nanopowder and BTO sol. Impacts of the jet height and line-to-line pitch of the deposition on the micro-structure of BTO thin films were investigated. Results show that crack-free BTO thin films can be prepared with 4 mm jet height and 300 μm line-to-line pitch in this work. Dielectric constant of the prepared BTO thin film was recorded as high as 2940 at 1 kHz at room temperature. Meanwhile, low dissipation factor of the BTO thin film of about 8.6% at 1 kHz was also obtained. The layer-by-layer E-jet deposition technique developed in this work has been proved to be a cost-effective, flexible and easy to control approach for the preparation of high-quality solid thin film. PMID:28787860

MultiLayer solid electrolyte for lithium thin film batteries

DOEpatents

Lee, Se -Hee; Tracy, C. Edwin; Pitts, John Roland; Liu, Ping

2015-07-28

A lithium metal thin-film battery composite structure is provided that includes a combination of a thin, stable, solid electrolyte layer [18] such as Lipon, designed in use to be in contact with a lithium metal anode layer; and a rapid-deposit solid electrolyte layer [16] such as LiAlF.sub.4 in contact with the thin, stable, solid electrolyte layer [18]. Batteries made up of or containing these structures are more efficient to produce than other lithium metal batteries that use only a single solid electrolyte. They are also more resistant to stress and strain than batteries made using layers of only the stable, solid electrolyte materials. Furthermore, lithium anode batteries as disclosed herein are useful as rechargeable batteries.

Prescribed fire experiences on crop residue removal for biomass exploitations. Application to the maritime pine forests in the Mediterranean Basin.

PubMed

Molina, Juan Ramón; García, Juan Pedro; Fernández, Juan José; Rodríguez Y Silva, Francisco

2018-01-15

Socioeconomic changes, climate change, rural migration and fire exclusion have led to a high woody biomass accumulation increasing potential wildfire severity. Mechanical thinning and prescribed burning practices are commonly used to prevent large fires. The purpose of this study was to assess burning treatment effectiveness following mechanical thinning from biomass harvesting. Prescribed burning to reduce residue removal could help mitigate fire behavior, mainly in strategic management or critical focal points. Field samplings were conducted before and immediately after burnings on different environmental scenarios where fuel load was classified by categories. Prescribed fires reduced available fuel in all fuel categories, mainly in surface litter layer. Total fuel load reduction ranged from 59.07% to 86.18%. In this sense, fuel reduction effects were more pronounced when burns were conducted fewer than 10% on surface litter moisture. The difference in fuel consumption among scenarios was higher for most all woody fuel components and decomposition litter layer than for surface litter layer. Managers can use this information to design technical prescription to achieve the targets while decomposed litter retention maintaining the soil properties and biodiversity. Understanding the most effective "burn window" should help better plan prescribed burning, both in term of fire behavior and fuel consumption, without altering ecosystem properties. Copyright © 2017 Elsevier B.V. All rights reserved.

Bioleaching remediation of heavy metal-contaminated soils using Burkholderia sp. Z-90.

PubMed

Yang, Zhihui; Zhang, Zhi; Chai, Liyuan; Wang, Yong; Liu, Yi; Xiao, Ruiyang

2016-01-15

Bioleaching is an environment-friendly and economical technology to remove heavy metals from contaminated soils. In this study, a biosurfactant-producing strain with capacity of alkaline production was isolated from cafeteria sewer sludge and its capability for removing Zn, Pb, Mn, Cd, Cu, and As was investigated. Phylogenetic analysis using 16S rDNA gene sequences confirmed that the strain belonged to Burkholderia sp. and named as Z-90. The biosurfactant was glycolipid confirmed by thin layer chromatography and Fourier-transform infrared spectroscopy. Z-90 broth was then used for bioleaching remediation of heavy metal-contaminated soils. The removal efficiency was 44.0% for Zn, 32.5% for Pb, 52.2% for Mn, 37.7% for Cd, 24.1% for Cu and 31.6% for As, respectively. Mn, Zn and Cd were more easily removed from soil than Cu, Pb and As, which was attributed to the presence of high acid-soluble fraction of Mn, Zn and Cd and high residual fraction of Cu, Pb and As. The heavy metal removal in soils was contributed to the adhesion of heavy metal-contaminated soil minerals with strain Z-90 and the formation of a metal complex with biosurfactant. Copyright © 2015 Elsevier B.V. All rights reserved.

Buried soils in a perched dunefield as indicators of late holecene lake-level change in the Lake Superior basin

USGS Publications Warehouse

Anderton, John B.; Loope, Walter L.

1995-01-01

A stratigraphic analysis of buried soils within the Grand Sable Dunes, a dune field perched 90 m above the southern shore of Lake Superior, reveals a history of eolian activity apparently linked with lake-level fluctuations over the last 5500 yr. A relative rise in the water plane of the Nipissing Great Lakes initially destabilized the lakeward bluff face of the Grand Sable plateau between 5400 and 4600 14C yr B.P. This led to the burial of the Sable Creek soil by eolian sediments derived from the bluff face. Subsequent episodes of eolian activity appear to be tied to similar destabilizing events; high lake levels may have initiated at least four and perhaps eleven episodes of dune building as expressed by soil burials within the dunes. Intervening low lake levels probably correlate with soil profile development, which varies from the well-developed Sable Creek Spodosol catena to thin organic layers containing in-place stumps and tree trunks. Paleoecological reconstructions available for the area do not imply enough climatic change to account for the episodic dune activity. Burial of soils by fine-fraction sediments links dune-building episodes with destabilization of the lower lake-facing bluff, which is rich in fines.

The Mars oxidant experiment (MOx) for Mars '96

NASA Technical Reports Server (NTRS)

McKay, C. P.; Grunthaner, F. J.; Lane, A. L.; Herring, M.; Bartman, R. K.; Ksendzov, A.; Manning, C. M.; Lamb, J. L.; Williams, R. M.; Ricco, A. J.;

Green roof soil system affected by soil structural changes: A project initiation

NASA Astrophysics Data System (ADS)

Jelínková, Vladimíra; Dohnal, Michal; Šácha, Jan; Šebestová, Jana; Sněhota, Michal

2014-05-01

Anthropogenic soil systems and structures such as green roofs, permeable or grassed pavements comprise appreciable part of the urban watersheds and are considered to be beneficial regarding to numerous aspects (e.g. carbon dioxide cycle, microclimate, reducing solar absorbance and storm water). Expected performance of these systems is significantly affected by water and heat regimes that are primarily defined by technology and materials used for system construction, local climate condition, amount of precipitation, the orientation and type of the vegetation cover. The benefits and potencies of anthropogenic soil systems could be considerably threatened in case when exposed to structural changes of thin top soil layer in time. Extensive green roof together with experimental green roof segment was established and advanced automated monitoring system of micrometeorological variables was set-up at the experimental site of University Centre for Energy Efficient Buildings as an interdisciplinary research facility of the Czech Technical University in Prague. The key objectives of the project are (i) to characterize hydraulic and thermal properties of soil substrate studied, (ii) to establish seasonal dynamics of water and heat in selected soil systems from continuous monitoring of relevant variables, (iii) to detect structural changes with the use of X-ray Computed Tomography, (iv) to identify with the help of numerical modeling and acquired datasets how water and heat dynamics in anthropogenic soil systems are affected by soil structural changes. Achievements of the objectives will advance understanding of the anthropogenic soil systems behavior in conurbations with the temperate climate.

Developments of the Physical and Electrical Properties of NiCr and NiCrSi Single-Layer and Bi-Layer Nano-Scale Thin-Film Resistors.

PubMed

Cheng, Huan-Yi; Chen, Ying-Chung; Li, Chi-Lun; Li, Pei-Jou; Houng, Mau-Phon; Yang, Cheng-Fu

2016-02-25

In this study, commercial-grade NiCr (80 wt % Ni, 20 wt % Cr) and NiCrSi (55 wt % Ni, 40 wt % Cr, 5 wt % Si) were used as targets and the sputtering method was used to deposit NiCr and NiCrSi thin films on Al₂O₃ and Si substrates at room temperature under different deposition time. X-ray diffraction patterns showed that the NiCr and NiCrSi thin films were amorphous phase, and the field-effect scanning electronic microscope observations showed that only nano-crystalline grains were revealed on the surfaces of the NiCr and NiCrSi thin films. The log (resistivity) values of the NiCr and NiCrSi thin-film resistors decreased approximately linearly as their thicknesses increased. We found that the value of temperature coefficient of resistance (TCR value) of the NiCr thin-film resistors was positive and that of the NiCrSi thin-film resistors was negative. To investigate these thin-film resistors with a low TCR value, we designed a novel bi-layer structure to fabricate the thin-film resistors via two different stacking methods. The bi-layer structures were created by depositing NiCr for 10 min as the upper (or lower) layer and depositing NiCrSi for 10, 30, or 60 min as the lower (or upper) layer. We aim to show that the stacking method had no apparent effect on the resistivity of the NiCr-NiCrSi bi-layer thin-film resistors but had large effect on the TCR value.

Developments of the Physical and Electrical Properties of NiCr and NiCrSi Single-Layer and Bi-Layer Nano-Scale Thin-Film Resistors

PubMed Central

Cheng, Huan-Yi; Chen, Ying-Chung; Li, Chi-Lun; Li, Pei-Jou; Houng, Mau-Phon; Yang, Cheng-Fu

2016-01-01

In this study, commercial-grade NiCr (80 wt % Ni, 20 wt % Cr) and NiCrSi (55 wt % Ni, 40 wt % Cr, 5 wt % Si) were used as targets and the sputtering method was used to deposit NiCr and NiCrSi thin films on Al2O3 and Si substrates at room temperature under different deposition time. X-ray diffraction patterns showed that the NiCr and NiCrSi thin films were amorphous phase, and the field-effect scanning electronic microscope observations showed that only nano-crystalline grains were revealed on the surfaces of the NiCr and NiCrSi thin films. The log (resistivity) values of the NiCr and NiCrSi thin-film resistors decreased approximately linearly as their thicknesses increased. We found that the value of temperature coefficient of resistance (TCR value) of the NiCr thin-film resistors was positive and that of the NiCrSi thin-film resistors was negative. To investigate these thin-film resistors with a low TCR value, we designed a novel bi-layer structure to fabricate the thin-film resistors via two different stacking methods. The bi-layer structures were created by depositing NiCr for 10 min as the upper (or lower) layer and depositing NiCrSi for 10, 30, or 60 min as the lower (or upper) layer. We aim to show that the stacking method had no apparent effect on the resistivity of the NiCr-NiCrSi bi-layer thin-film resistors but had large effect on the TCR value. PMID:28344296

30 CFR 715.16 - Topsoil handling.

Code of Federal Regulations, 2010 CFR

2010-07-01

... as the surface soil layers. Where the A horizon is less than 6 inches, a 6-inch layer that includes... replaced as the surface soil layer. (3) Where necessary to obtain soil productivity consistent with... amounts and analyses as determined by soil tests shall be applied to the surface soil layer so that it...

30 CFR 715.16 - Topsoil handling.

Code of Federal Regulations, 2011 CFR

2011-07-01

... as the surface soil layers. Where the A horizon is less than 6 inches, a 6-inch layer that includes... replaced as the surface soil layer. (3) Where necessary to obtain soil productivity consistent with... amounts and analyses as determined by soil tests shall be applied to the surface soil layer so that it...

30 CFR 715.16 - Topsoil handling.

Code of Federal Regulations, 2014 CFR

2014-07-01

... as the surface soil layers. Where the A horizon is less than 6 inches, a 6-inch layer that includes... replaced as the surface soil layer. (3) Where necessary to obtain soil productivity consistent with... amounts and analyses as determined by soil tests shall be applied to the surface soil layer so that it...

30 CFR 715.16 - Topsoil handling.

Code of Federal Regulations, 2012 CFR

2012-07-01

... as the surface soil layers. Where the A horizon is less than 6 inches, a 6-inch layer that includes... replaced as the surface soil layer. (3) Where necessary to obtain soil productivity consistent with... amounts and analyses as determined by soil tests shall be applied to the surface soil layer so that it...

30 CFR 715.16 - Topsoil handling.

Code of Federal Regulations, 2013 CFR

2013-07-01

... as the surface soil layers. Where the A horizon is less than 6 inches, a 6-inch layer that includes... replaced as the surface soil layer. (3) Where necessary to obtain soil productivity consistent with... amounts and analyses as determined by soil tests shall be applied to the surface soil layer so that it...

Monitoring the layer-by-layer self-assembly of graphene and graphene oxide by spectroscopic ellipsometry.

PubMed

Zhou, Kai-Ge; Chang, Meng-Jie; Wang, Hang-Xing; Xie, Yu-Long; Zhang, Hao-Li

2012-01-01

Thin films of graphene oxide, graphene and copper (II) phthalocyanine dye have been successfully fabricated by electrostatic layer-by-layer (LbL) assembly approach. We present the first variable angle spectroscopic ellipsometry (VASE) investigation on these graphene-dye hybrid thin films. The thickness evaluation suggested that our LbL assembly process produces highly uniform and reproducible thin films. We demonstrate that the refractive indices of the graphene-dye thin films undergo dramatic variation in the range close to the absorption of the dyes. This investigation provides new insight to the optical properties of graphene containing thin films and shall help to establish an appropriate optical model for graphene-based hybrid materials.

Influences of Indium Tin Oxide Layer on the Properties of RF Magnetron-Sputtered (BaSr)TiO3 Thin Films on Indium Tin Oxide-Coated Glass Substrate

NASA Astrophysics Data System (ADS)

Kim, Tae Song; Oh, Myung Hwan; Kim, Chong Hee

1993-06-01

Nearly stoichiometric ((Ba+Sr)/Ti=1.08-1.09) and optically transparent (BaSr)TiO3 thin films were deposited on an indium tin oxide (ITO)-coated glass substrate by means of rf magnetron sputtering for their application to the insulating layer of an electroluminescent flat panel display. The influence of the ITO layer on the properties of (BaSr)TiO3 thin films deposited on the ITO-coated substrate was investigated. The ITO layer did not affect the crystallographic orientation of (BaSr)TiO3 thin film, but enhanced the grain growth. Another effect of the ITO layer on (BaSr)TiO3 thin films was the interdiffusion phenomenon, which was studied by means of secondary ion mass spectrometry (SIMS). As the substrate temperature increased, interdiffusion intensified at the interface not only between the grown film and ITO layer but also between the ITO layer and base glass substrate. The refractive index (nf) of (BaSr)TiO3 thin film deposited on a bare glass substrate was 2.138-2.286, as a function of substrate temperature.

Aflatoxin decomposition in various soils

DOE Office of Scientific and Technical Information (OSTI.GOV)

Angle, J.S.

The persistence of aflatoxin in the soil environment could potentially result in a number of adverse environmental consequences. To determine the persistence of aflatoxin in soil, /sup 14/C-labeled aflatoxin B1, was added to silt loam, sandy loam, and silty clay loam soils and the subsequent release of /sup 14/CO/sub 2/ was determined. After 120 days of incubation, 8.1% of the original aflatoxin added to the silt loam soil was released as CO/sub 2/. Aflatoxin decomposition in the sandy loam soil proceeded more quickly than the other two soils for the first 20 days of incubation. After this time, the decompositionmore » rate declined and by the end of the study, 4.9% of the aflatoxin was released as CO/sub 2/. Aflatoxin decomposition proceeded most slowly in the silty clay loam soil. Only 1.4% of aflatoxin added to the soil was released as CO/sub 2/ after 120 days incubation. To determine whether aflatoxin was bound to the silty clay loam soil, aflatoxin B1 was added to this soil and incubated for 20 days. The soil was periodically extracted and the aflatoxin species present were determined using thin layer chromatographic (TLC) procedures. After one day of incubation, the degradation products, aflatoxins B2 and G2, were observed. It was also found that much of the aflatoxin extracted from the soil was not mobile with the TLC solvent system used. This indicated that a conjugate may have formed and thus may be responsible for the lack of aflatoxin decomposition.« less

Corrosion-resistant multilayer structures with improved reflectivity

DOEpatents

Soufli, Regina; Fernandez-Perea, Monica; Robinson, Jeff C.

2013-04-09

In one general embodiment, a thin film structure includes a substrate; a first corrosion barrier layer above the substrate; a reflective layer above the first corrosion barrier layer, wherein the reflective layer comprises at least one repeating set of sub-layers, wherein one of the sub-layers of each set of sub-layers being of a corrodible material; and a second corrosion barrier layer above the reflective layer. In another general embodiment, a system includes an optical element having a thin film structure as recited above; and an image capture or spectrometer device. In a further general embodiment, a laser according to one embodiment includes a light source and the thin film structure as recited above.

Internal hypersonic flow. [in thin shock layer

NASA Technical Reports Server (NTRS)

Lin, T. C.; Rubin, S. G.

1974-01-01

An approach for studying hypersonic internal flow with the aid of a thin-shock-layer approximation is discussed, giving attention to a comparison of thin-shock-layer results with the data obtained on the basis of the imposition theory or a finite-difference integration of the Euler equations. Relations in the case of strong interaction are considered together with questions of pressure distribution and aspects of the boundary-layer solution.

Methods for producing thin film charge selective transport layers

DOE Office of Scientific and Technical Information (OSTI.GOV)

Hammond, Scott Ryan; Olson, Dana C.; van Hest, Marinus Franciscus Antonius Maria

Methods for producing thin film charge selective transport layers are provided. In one embodiment, a method for forming a thin film charge selective transport layer comprises: providing a precursor solution comprising a metal containing reactive precursor material dissolved into a complexing solvent; depositing the precursor solution onto a surface of a substrate to form a film; and forming a charge selective transport layer on the substrate by annealing the film.

Al-/Ga-Doped ZnO Window Layers for Highly Efficient Cu₂ZnSn(S,Se)₄ Thin Film Solar Cells.

PubMed

Seo, Se Won; Seo, Jung Woo; Kim, Donghwan; Cheon, Ki-Beom; Lee, Doh-Kwon; Kim, Jin Young

2018-09-01

The successful use of Al-/Ga-doped ZnO (AGZO) thin films as a transparent conducting oxide (TCO) layer of a Cu2ZnSn(S,Se)4 (CZTSSe) thin film solar cell is demonstrated. The AGZO thin films were prepared by radio frequency (RF) sputtering. The structural, crystallographic, electrical, and optical properties of the AGZO thin films were systematically investigated. The photovoltaic properties of CZTSSe thin film solar cells incorporating the AGZO-based TCO layer were also reported. It has been found that the RF power and substrate temperature of the AGZO thin film are important factors determining the electrical, optical, and structural properties. The optimization process involving the RF power and the substrate temperature leads to good electrical and optical transmittance of the AGZO thin films. Finally, the CZTSSe solar cell with the AGZO TCO layer demonstrated a high conversion efficiency of 9.68%, which is higher than that of the conventional AZO counterpart by 12%.

Soil Compaction Assessment Using Spectral Analysis of Surface Waves (SASW)

NASA Astrophysics Data System (ADS)

Afiq Roslan, Muhammad; Madun, Aziman; Hazreek Zainalabidin, Mohd; Dan@Azlan, Mohd Firdaus Md; Khaidir Abu Talib, Mohd; Nur Hidayat Zahari, Muhammad; Ambak, Kamaruddin; Ashraf Mohamad Ismail, Mohd

2018-04-01

Compaction is a process of soil densification in earthworks via by pressing the soil particles with air being expelled from the soil mass, thereby increasing its unit weight. Thus, it is important to evaluate the quality of soil compaction as prescribed in the technical requirement. SASW method is widely used for estimating material properties in layered structures based on the dispersion characteristics of Rayleigh Waves. The small scale at dimension area of 1.0 m width x 1.0 m length x 0.9 m depth was excavated and back filled with laterite soil. The soil was compacted for every layer at 0.3 m thickness. Each layer of soil compaction was conducted compaction test using core cutter methods and SASW test to determine the density and shear wave velocity. The phase velocity for layer 1 was between 112 m/s and 114 m/s, layer 2 was between 67 m/s and 74 m/s and layer 3 was between 74 m/s and 97 m/s. The result shows that the compacted soil layers are not fulfilled the quality of compacted soil layers where supposedly the expected shear wave velocity for the compacted layers should be higher than 180 m/s which is classified as stiff soil.

Growth and optical property characterization of textured barium titanate thin films for photonic applications

NASA Astrophysics Data System (ADS)

Dicken, Matthew J.; Diest, Kenneth; Park, Young-Bae; Atwater, Harry A.

2007-03-01

We have investigated the growth of barium titanate thin films on bulk crystalline and amorphous substrates utilizing biaxially oriented template layers. Ion beam-assisted deposition was used to grow thin, biaxially textured, magnesium oxide template layers on amorphous and silicon substrates. Growth of highly oriented barium titanate films on these template layers was achieved by molecular beam epitaxy using a layer-by-layer growth process. Barium titanate thin films were grown in molecular oxygen and in the presence of oxygen radicals produced by a 300 W radio frequency plasma. We used X-ray and in situ reflection high-energy electron diffraction (RHEED) to analyze the structural properties and show the predominantly c-oriented grains in the films. Variable angle spectroscopic ellipsometry was used to analyze and compare the optical properties of the thin films grown with and without oxygen plasma. We have shown that optical quality barium titanate thin films, which show bulk crystal-like properties, can be grown on any substrate through the use of biaxially oriented magnesium oxide template layers.

Ring Resonator for Detection of Melting Brine Under Shallow Subsurface of Mars

NASA Technical Reports Server (NTRS)

Ponchak, George E.; Jordan, Jennifer L.; Scardelletti, Maximillian C.

2016-01-01

Laboratory experimental evidence using Raman spectroscopy has shown that liquid brine may form below the shallow subsurface of Mars. A simpler experimental method to verify the presence of liquid brine or liquid water below Mars surface is needed. In this paper, a ring resonator is used to detect the phase change between frozen water and liquid water below a sandy soil that simulates the Mars surface. Experimental data shows that the ring resonator can detect the melting of thin layers of frozen brine or water up to 15 mm below the surface.

Shark as viewed by Sojourner Rover

NASA Technical Reports Server (NTRS)

1998-01-01

This close-up image of Shark, in the Bookshelf at the back of the Rock Garden, was taken by Sojourner Rover on Sol 75. Also in the image are Half Dome (right) and Desert Princess (lower right). At the bottom left, a thin 'crusty' soil layer has been disturbed by the rover wheels.

Mars Pathfinder is the second in NASA's Discovery program of low-cost spacecraft with highly focused science goals. The Jet Propulsion Laboratory, Pasadena, CA, developed and manages the Mars Pathfinder mission for NASA's Office of Space Science, Washington, D.C. JPL is a division of the California Institute of Technology (Caltech).

[Spatial variation of soil phosphorus in flooded area of the Yellow River based on GIS and geo-statistical methods: A case study in Zhoukou City, Henan, China.

PubMed

Jia, Zhen Yu; Zhang, Jun Hua; Ding, Sheng Yan; Feng, Shu; Xiong, Xiao Bo; Liang, Guo Fu

2016-04-22

Soil phosphorus is an important indicator to measure the soil fertility, because the content of soil phosphorus has an important effect on physical and chemical properties of soil, plant growth, and microbial activity in soil. In this study, the soil samples collecting and indoor analysis were conducted in Zhoukou City located in the flooded area of the Yellow River. By using GIS combined with geo-statistics, we tried to analyze the spatial variability and content distribution of soil total phosphorus (TP) and soil available phosphorus (AP) in the study area. Results showed that TP and AP of both soil layers (0-20 cm and 20-40 cm) were rich, and the contents of TP and AP in surface layer (0-20 cm) were higher than in the second layer (20-40 cm). TP and AP of both soil layers exhibited variation at medium level, and AP had varied much higher than TP. TP of both layers showed medium degree of anisotropy which could be well modeled by the Gaussian model. TP in the surface layer showed strong spatial correlation, but that of the second layer had medium spatial correlation. AP of both layers had a weaker scope in anisotropy which could be simulated by linear model, and both soil layers showed weaker spatial correlations. TP of both soil layers showed a slowly rising change from southwest to northeast of the study area, while it gradually declined from northwest to southeast. AP in soil surface layer exhibited an increase tendency firstly and then decrease from southwest to the northeast, while it decreased firstly and then increased from southeast to the northwest. AP in the second soil layer had an opposite change in the southwest to the northeast, while it showed continuously increasing tendency from northwest to the southeast. The contents of TP and AP in the surface layer presented high grades and the second layer of TP belonged to medium grade, but the second layer of AP was in a lower grade. The artificial factors such as land use type, cropping system, irrigation and fertilization were the main factors influencing the distribution and spatial variation of soil phosphorus in this area.

Effect of different coating layer on the topography and optical properties of ZnO nanostructured

NASA Astrophysics Data System (ADS)

Mohamed, R.; Mamat, M. H.; Malek, M. F.; Ismail, A. S.; Yusoff, M. M.; Asiah, M. N.; Khusaimi, Z.; Rusop, M.

2018-05-01

Magnesium (Mg) and aluminum (Al) co-doped zinc oxide (MAZO) thin films were synthesized on glass substrate by sol-gel spin coating method. MAZO thin films were prepared at different coating layers range from 1 to 9. Atomic Force Microscopy (AFM) was used to investigate the topography of the thin films. According to the AFM results, Root Means Square (RMS) of MAZO thin films was increased from 0.747 to 6.545 nm, with increase of number coating layer from 1 to 9, respectively. The results shown the variation on structural and topography properties of MAZO seed film when it's deposited at different coating layers on glass substrate. The optical properties was analyzed using UV-Vis spectroscopy. The obtained results show that the transmittance spectra was increased as thin films coating layer increases.

Thin layer model for nonlinear evolution of the Rayleigh-Taylor instability

NASA Astrophysics Data System (ADS)

Zhao, K. G.; Wang, L. F.; Xue, C.; Ye, W. H.; Wu, J. F.; Ding, Y. K.; Zhang, W. Y.

2018-03-01

On the basis of the thin layer approximation [Ott, Phys. Rev. Lett. 29, 1429 (1972)], a revised thin layer model for incompressible Rayleigh-Taylor instability has been developed to describe the deformation and nonlinear evolution of the perturbed interface. The differential equations for motion are obtained by analyzing the forces (the gravity and pressure difference) of fluid elements (i.e., Newton's second law). The positions of the perturbed interface are obtained from the numerical solution of the motion equations. For the case of vacuum on both sides of the layer, the positions of the upper and lower interfaces obtained from the revised thin layer approximation agree with that from the weakly nonlinear (WN) model of a finite-thickness fluid layer [Wang et al., Phys. Plasmas 21, 122710 (2014)]. For the case considering the fluids on both sides of the layer, the bubble-spike amplitude from the revised thin layer model agrees with that from the WN model [Wang et al., Phys. Plasmas 17, 052305 (2010)] and the expanded Layzer's theory [Goncharov, Phys. Rev. Lett. 88, 134502 (2002)] in the early nonlinear growth regime. Note that the revised thin layer model can be applied to investigate the perturbation growth at arbitrary Atwood numbers. In addition, the large deformation (the large perturbed amplitude and the arbitrary perturbed distributions) in the initial stage can also be described by the present model.

Two-dimensional models for the optical response of thin films

NASA Astrophysics Data System (ADS)

Li, Yilei; Heinz, Tony F.

2018-04-01

In this work, we present a systematic study of 2D optical models for the response of thin layers of material under excitation by normally incident light. The treatment, within the framework of classical optics, analyzes a thin film supported by a semi-infinite substrate, with both the thin layer and the substrate assumed to exhibit local, isotropic linear response. Starting from the conventional three-dimensional (3D) slab model of the system, we derive a two-dimensional (2D) sheet model for the thin film in which the optical response is described by a sheet optical conductivity. We develop criteria for the applicability of this 2D sheet model for a layer with an optical thickness far smaller than the wavelength of the light. We examine in detail atomically thin semi-metallic and semiconductor van-der-Waals layers and ultrathin metal films as representative examples. Excellent agreement of the 2D sheet model with the 3D slab model is demonstrated over a broad spectral range from the radio frequency limit to the near ultraviolet. A linearized version of system response for the 2D model is also presented for the case where the influence of the optically thin layer is sufficiently weak. Analytical expressions for the applicability and accuracy of the different optical models are derived, and the appropriateness of the linearized treatment for the materials is considered. We discuss the advantages, as well as limitations, of these models for the purpose of deducing the optical response function of the thin layer from experiment. We generalize the theory to take into account in-plane anisotropy, layered thin film structures, and more general substrates. Implications of the 2D model for the transmission of light by the thin film and for the implementation of half- and totally absorbing layers are discussed.

Solid-state 13C nuclear magnetic resonance spectroscopic characterization of soil organic matter fractions in a forest ecosystem subjected to prescribed burning and thinning

USDA-ARS?s Scientific Manuscript database

Prescribed burning and thinning are gaining popularity as low-cost forest protection measures. Such field management practices could alter the chemical properties of soil organic matter (SOM), especially humic substances. In this work, we collected surface soil samples from the Bankhead National For...

Soil Suitability for Forest Trees in the Thin Loess Area

Treesearch

W. M. Broadfoot; J. S. McKnight

1961-01-01

The Thin Loess soil belt lies east and adjacent to the Deep Loess area. Soils in the area's uplands developed in wind- blown silty deposits less than 4 feet thick. The terraces and bottoms are derived principally from sediments of the nearby loess hills, and mixed alluvium from loess and Coastal Plain sands and clays.

Soil variability and landscape history of the last 800.000 years revealed by the horsification of the landscape in North-Brabant, The Netherlands

NASA Astrophysics Data System (ADS)

Kluiving, Sjoerd; Kok, Marielle; van Suijlekom, Jan-Jaap; Kasse, Kees

2015-04-01

In the province of North-Brabant in the southern Netherlands a diverse geological substrate is present variable in chronology, sediment properties, and soil profiles. The human influence on soil quality and topography has a history of millennia while new developments related to the horsification of the landscape in this region allow an insight in the soil patterns with associated landscape evolution. The objective in this project is to show that records of soils and landscape in this area are able to demonstrate the evolutional history and disseminate the pedological and geological knowledge to a wider audience in demonstrating that soil records and associated landscape evolution reveal a regional identity that can be very useful to apply in landscape architectural projects, such as in the horsification of the landscape. Soil records show landscape evolution has progressed in three distinct phases: 1) The oldest deposits in the region are formed by river sediments that reflect a fluvial environment that was present 800.000 years ago in the Lower-Pleistocene. Old courses of the rivers Rhine and Meuse deposited gravelly white sands and clay layers that have a distinct effect on hydrological properties. 2) Eolian sands dating from the Late Glacial, deposited 12.000-14.000 years before present were deposited by western wind directions, obvious from large scale linear and parabolic dune ridges. These sandy deposits have endured soil acidification and podzolisation resulting in classic Umbric Podzol profiles testifying of a prolonged period of landscape evolution. 3) Tree removal in the Holocene by man created unprotected open sand plains that were eroded and deposited by wind processes in small scale ridges with steep slopes up till approximately 500 years ago. These drift sands have a widespread occurrence and can be recognized in thin micro-podzol profiles in association with a distinct morphology of steep sloped dunes. Multiple soil horizons reflect different time periods elapsed and specific 'open landscape' environments, as these thin podzolic horizons testify. Future research will involve cartographic mapping by soil coring, as well as OSL dating, next to an ecological field reconnaissance. In this poster we will show how the soil in this region beholds an entire landscape history, and how that information can be combined with nature development in landscape architectural plans.

Initial formation of calcite crystals in the thin prismatic layer with the periostracum of Pinctada fucata.

PubMed

Suzuki, Michio; Nakayama, Seiji; Nagasawa, Hiromichi; Kogure, Toshihiro

2013-02-01

Although the formation mechanism of calcite crystals in the prismatic layer has been studied well in many previous works, the initial state of calcite formation has not been observed in detail using electron microscopes. In this study, we report that the soft prismatic layer with transparent color (the thin prismatic layer) in the tip of the fresh shell of Pinctada fucata was picked up to observe the early calcification phase. A scanning electron microscope (SEM) image showed that the growth tip of the thin prismatic layer was covered by the periostracum, which was also where the initial formation of calcite crystals began. A cross-section containing the thin calcite crystals in the thin prismatic layer with the periostracum was made using a focused ion beam (FIB) system. In a transmission electron microscope (TEM) observation, the thin calcite crystal (thickness is about 1μm) on the periostracum was found to be a single crystal with the c-axis oriented perpendicular to the shell surface. On the other hand, many aggregated small particles consisting of bassanite crystals were observed in the periostracum suggesting the possibility that not only organic sulfate but also inorganic sulfates exist in the prismatic layer. These discoveries in the early calcification phase of the thin prismatic layer may help to clarify the mechanism of regulating the nucleation and orientation of the calcite crystal in the shell. Copyright © 2012 Elsevier Ltd. All rights reserved.

Buffer layers for high-Tc thin films on sapphire

NASA Technical Reports Server (NTRS)

Wu, X. D.; Foltyn, S. R.; Muenchausen, R. E.; Cooke, D. W.; Pique, A.; Kalokitis, D.; Pendrick, V.; Belohoubek, E.

1992-01-01

Buffer layers of various oxides including CeO2 and yttrium-stabilized zirconia (YSZ) have been deposited on R-plane sapphire. The orientation and crystallinity of the layers were optimized to promote epitaxial growth of YBa2Cu3O(7-delta) (YBCO) thin films. An ion beam channeling minimum yield of about 3 percent was obtained in the CeO2 layer on sapphire, indicating excellent crystallinity of the buffer layer. Among the buffer materials used, CeO2 was found to be the best one for YBCO thin films on R-plane sapphire. High Tc and Jc were obtained in YBCO thin films on sapphire with buffer layers. Surface resistances of the YBCO films were about 4 mOmega at 77 K and 25 GHz.

Soils of the Eastern mountainsides of the southern Sikhote-Alin (on the example of Lazovsky nature reserve, Russia)

NASA Astrophysics Data System (ADS)

Tregubova, Valentina; Semal, Victoria; Nesterova, Olga; Yaroslavtsev, Alexis

2017-04-01

The most common soils of the southern Far East are Brownzems under Russian classification (Cambisols), which are the zonal ones, emerging on the steep slopes and tops of hills, on high river terraces under broad-leaved and cedar-broad-leaved forests. Those soils formed due to two processes: organic matter metamorphism and clayization by siallite, leading to the formation of clay-metamorphic horizon Bw. The main morphological features of Cambisols are not deep soil profile (50 - 70 cm), weak horizons differentiation, with lots of cobble. Chemically those soils are low saturated, even in the humus horizon. Distribution of total absorbed bases is mostly accumulative, which is related to the distribution of humus in these soils, and the predominant type of clay fraction distribution of. The only exception are Humic Cambisols and Humic Cambisols Calcic which were formed on redeposited products of limestone rock weathering. Fine-grained deposits are mainly loams with a low content of silt. Silt distribution has an accumulative character with a gradual decrease in the content of silt down from the top of the profile. Layer of fresh leaf fall is very common for the Humic Cambisols surfaces, and under it there is the litter of plant residues with different degrees of decomposition. Accumulative humus horizon is dark gray with brownish tint, thin, from 10 to 15 cm in depth, loose, crumbly, highly penetrated by roots, with a strong granular structure, with aggregates tightly attached to the root hairs, sandy loam or sandy clay loam. The middle horizon is brown, yellowish-brown, divided into sub-horizons, with different color intensity, density, soil texture and amount of cobble. Dystric Cambisols are acidic or strongly acidic with low saturation of soil absorbing complex. Due to amount and distribution of organic matter these soils can be divided into two groups. The first group is soils with accumulative humus distribution: with a low depth humus-accumulative horizon (11 - 12 cm) and high content of organic matter (23 - 26 %); humus in the upper horizons mainly consists of humic acids, while in lower horizons it is with higher ratio of fulvic acids. The second group is soils with a gradual humus distribution along the profile and with a smaller amount of organic matter in the upper horizon (9 - 13 %) and with no differentiation in humus composition. Folic Cambisols are formed on the watershed surfaces, on the steep slopes under pine and oak trees. Under thin litter horizon these soils have organic-accumulative horizon of well decomposed organic matter, but in contrast with Dystric Cambisols it doesn't have strong granular structure. At the bottom the organic horizon is humic-impregnated or has clear streaks of humus. Humic Cambisols are formed in the lower parts of slopes, on steep slopes and high river terraces under pine and deciduous forests. All this soils have humified litter horizon, which is up to 7 cm in depth, weak differentiation of the soil profile, deep humus-accumulative horizon (18 - 31 cm) with dark gray, almost black color, with strong granular structure and loam or clay loam texture. Soil acidity is determined by the lithogenic basis. Base saturation is quite high (77 - 90%) in mineral horizons and is up to 70 % in organic and accumulative ones. There is a high amount of humus on the entire profile (5 - 16 %), which consists of humic acids in the upper half of the profile and of fulvates at the bottom. Humic Cambisols Gleyic are located in the lower parts of gentle slopes under mixed forest. Due to higher moisture at the lower parts of slopes this soils have signs of weak gley process in dense subsoil horizons in the form of small light grey spots. Humic Leptosols are weakly developed soils formed on rocky hills, boulders, rocky outcrops, under thick moss layer, under which is a layer of weathered gravel rock. Humic Cambisols (Calcic) are formed on the surface sediments of limestone. They have a deep soil profile, up to 40 cm and it's humus-accumulative horizon is dark gray or black, gradually passing into soil-forming rock. Bw horizon, typical for Cambisols, is weak.

Soil enzyme activities in Pinus tabuliformis (Carriere) plantations in northern China

Treesearch

Weiwei Wang; Deborah Page-Dumroese; Ruiheng Lv; Chen Xiao; Guolei Li; Yong Liu

2016-01-01

Changes in forest stand structure may alter the activity of invertase, urease, catalase and phenol oxidase after thinning Pinus tabuliformis (Carriére) plantations in Yanqing County of Beijing, China. We examined changes in these soil enzymes as influenced by time since thinning (24, 32, and 40 years since thinning) for 3 seasons (spring, summer and autumn)...

Layered ultra-thin coherent structures used as electrical resistors having low-temperature coefficient of resistivity

DOEpatents

Werner, T.R.; Falco, C.M.; Schuller, I.K.

1982-08-31

A thin film resistor having a controlled temperature coefficient of resistance (TCR) ranging from negative to positive degrees kelvin and having relatively high resistivity. The resistor is a multilayer superlattice crystal containing a plurality of alternating, ultra-thin layers of two different metals. TCR is varied by controlling the thickness of the individual layers. The resistor can be readily prepared by methods compatible with thin film circuitry manufacturing techniques.

[Effects of water storage in deeper soil layers on the root growth, root distribution and economic yield of cotton in arid area with drip irrigation under mulch].

PubMed

Luo, Hong-Hai; Zhang, Hong-Zhi; Zhang, Ya-Li; Zhang, Wang-Feng

2012-02-01

Taking cotton cultivar Xinluzao 13 as test material, a soil column culture expenment was conducted to study the effects of water storage in deeper (> 60 cm) soil layer on the root growth and its relations with the aboveground growth of the cultivar in arid area with drip irrigation under mulch. Two levels of water storage in 60-120 cm soil layer were installed, i. e., well-watered and no watering, and for each, the moisture content in 0-40 cm soil layer during growth period was controlled at two levels, i.e., 70% and 55% of field capacity. It was observed that the total root mass density of the cultivar and its root length density and root activity in 40-120 cm soil layer had significant positive correlations with the aboveground dry mass. When the moisture content in 0-40 cm soil layer during growth season was controlled at 70% of field capacity, the total root mass density under well-watered and no watering had less difference, but the root length density and root activity in 40-120 cm soil layer under well-watered condition increased, which enhanced the water consumption in deeper soil layer, increased the aboveground dry mass, and finally, led to an increased economic yield and higher water use efficiency. When the moisture content in 0-40 cm soil layer during growth season was controlled at 55% of field capacity and the deeper soil layer was well-watered, the root/shoot ratio and root length density in 40-120 cm soil layer and the root activity in 80-120 cm soil layer were higher, the water consumption in deeper soil layer increased, but it was still failed to adequately compensate for the negative effects of water deficit during growth season on the impaired growth of roots and aboveground parts, leading to a significant decrease in the economic yield, as compared with that at 70% of field capacity. Overall, sufficient water storage in deeper soil layer and a sustained soil moisture level of 65% -75% of field capacity during growth period could promote the downward growth of cotton roots, which was essential for achieving water-saving and high-yielding cultivation of cotton with drip irrigation under mulch.

Effect of ZnO buffer layer on phase transition properties of vanadium dioxide thin films

NASA Astrophysics Data System (ADS)

Zhu, Huiqun; Li, Lekang; Li, Chunbo

2016-03-01

VO2 thin films were prepared on ZnO buffer layers by DC magnetron sputtering at room temperature using vanadium target and post annealing at 400 °C. The ZnO buffer layers with different thickness deposited on glass substrates by magnetron sputtering have a high visible and near infrared optical transmittance. The electrical resistivity and the phase transition properties of the VO2/ZnO composite thin films in terms of temperature were investigated. The results showed that the resistivity variation of VO2 thin film with ZnO buffer layer deposited for 35 min was 16 KΩ-cm. The VO2/ZnO composite thin films exhibit a reversible semiconductor-metal phase transition at 48 °C.

Thin-Layer Fuel Cell for Teaching and Classroom Demonstrations

ERIC Educational Resources Information Center

Shirkhanzadeh, M.

2009-01-01

A thin-layer fuel cell is described that is simple and easy to set up and is particularly useful for teaching and classroom demonstrations. The cell is both an electrolyzer and a fuel cell and operates using a thin layer of electrolyte with a thickness of approximately 127 micrometers and a volume of approximately 40 microliters. As an…

Optical characterizations of silver nanoprisms embedded in polymer thin film layers

NASA Astrophysics Data System (ADS)

Carlberg, Miriam; Pourcin, Florent; Margeat, Olivier; Le Rouzo, Judikael; Berginc, Gerard; Sauvage, Rose-Marie; Ackermann, Jorg; Escoubas, Ludovic

2017-10-01

The precise control of light-matter interaction has a wide range of applications and is currently driven by the use of nanoparticles (NPs) by the recent advances in nanotechnology. Taking advantage of the material, size, shape, and surrounding media dependence of the optical properties of plasmonic NPs, thin film layers with tunable optical properties are achieved. The NPs are synthesized by wet chemistry and embedded in a polyvinylpyrrolidone (PVP) polymer thin film layer. Spectrophotometer and spectroscopic ellipsometry measurements are coupled to finite-difference time domain numerical modeling to optically characterize the heterogeneous thin film layers. Silver nanoprisms of 10 to 50 nm edge size exhibit high absorption through the visible wavelength range. A simple optical model composed of a Cauchy law and a Lorentz law, accounting for the optical properties of the nonabsorbing polymer and the absorbing property of the nanoprisms, fits the spectroscopic ellipsometry measurements. Knowing the complex optical indices of heterogeneous thin film layers let us design layers of any optical properties.

[Dynamics of soil physical properties and biological soil crust during the vegetation restoration process of abandoned croplands in the Ordos Plateau, China].

PubMed

Cai, Wen Tao; Li, He Yi; Lai, Li Ming; Zhang, Xiao Long; Guan, Tian Yu; Zhou, Ji Hua; Jiang, Lian He; Zheng, Yuan Run

2017-03-18

A series of typical abandoned croplands in the regions of Ruanliang and Yingliang in the Ordos Plateau, China, were selected, and dynamics of the surface litter, biological soil crust and soil bulk density, soil texture, and soil moisture in different soil layers were investigated. The results showed that in the abandoned cropland in Ruanliang, the clay particle content and surface litter of the surface soil layer (0-10 cm) increased during the restoration process, while that of soil bulk density substantially decreased and soil water content slightly increased in the surface soil. In the medium soil layer (10-30 cm), the clay particle content increased and the soil water content slightly decreased. In the deep soil layer (30-50 cm), there was a relatively large variation in the physical properties. In the abandoned cropland in Yingliang, the coverage of litter and the coverage and thickness of the biological soil crust increased during the abandonment process. The surface soil bulk density, soil clay particle content and soil water content remained constant in 0-10 cm soil layer, while the physical properties varied substantially in 10-40 cm soil layer. The shallow distribution of the soil water content caused by the accumulation of the litter and clay particles on the soil surface might be the key reason of the replacement of the semi-shrub Artemisia ordosica community with a perennial grass community over the last 20 years of the abandoned cropland in Ruanliang. The relatively high soil water content in the shallow layer and the development of the biological soil crust might explain why the abandoned cropland in Yingliang was not invaded by the semi-shrub A. ordosica during the restoration process.

Extracting elastic properties of an atomically thin interfacial layer by time-domain analysis of femtosecond acoustics

NASA Astrophysics Data System (ADS)

Chen, H.-Y.; Huang, Y.-R.; Shih, H.-Y.; Chen, M.-J.; Sheu, J.-K.; Sun, C.-K.

2017-11-01

Modern devices adopting denser designs and complex 3D structures have created much more interfaces than before, where atomically thin interfacial layers could form. However, fundamental information such as the elastic property of the interfacial layers is hard to measure. The elastic property of the interfacial layer is of great importance in both thermal management and nano-engineering of modern devices. Appropriate techniques to probe the elastic properties of interfacial layers as thin as only several atoms are thus critically needed. In this work, we demonstrated the feasibility of utilizing the time-resolved femtosecond acoustics technique to extract the elastic properties and mass density of a 1.85-nm-thick interfacial layer, with the aid of transmission electron microscopy. We believe that this femtosecond acoustics approach will provide a strategy to measure the absolute elastic properties of atomically thin interfacial layers.

Layer chromatography-bioassays directed screening and identification of antibacterial compounds from Scotch thistle.

PubMed

Móricz, Ágnes M; Krüzselyi, Dániel; Alberti, Ágnes; Darcsi, András; Horváth, Györgyi; Csontos, Péter; Béni, Szabolcs; Ott, Péter G

2017-11-17

The antibacterial profiling of Onopordum acanthium L. leaf extract and subsequent targeted identification of active compounds is demonstrated. Thin-layer chromatography (TLC) and off-line overpressured layer chromatography (OPLC) coupled with direct bioautography were utilized for investigation of the extract against eight bacterial strains including two plant and three human pathogens and a soil, a marine and a probiotic human gut bacteria. Antibacterial fractions obtaining infusion-transfusion OPLC were transferred to HPLC-MS/MS analysis that resulted in the characterization of three active compounds and two of them were identified as, linoleic and linolenic acid. OPLC method was adopted to preparative-scale flash chromatography for the isolation of the third active compound, which was identified after a further semi-preparative HPLC purification as the germacranolide sesquiterpene lactone onopordopicrin. Pure onopordopicrin exhibited antibacterial activity that was specified as minimal inhibitory concentration in the liquid phase as well. Copyright © 2017 Elsevier B.V. All rights reserved.

Time domain reflectometry measurements of solute transport across a soil layer boundary

DOE Office of Scientific and Technical Information (OSTI.GOV)

Nissen, H.H.; Moldrup, P.; Kachanoski, R.G.

2000-02-01

The mechanisms governing solute transport through layered soil are not fully understood. Solute transport at, above, and beyond the interface between two soil layers during quasi-steady-state soil water movement was investigated using time domain reflectometry (TDR). A 0.26-m sandy loam layer was packed on top of a 1.35-m fine sand layer in a soil column. Soil water content ({theta}) and bulk soil electrical conductivity (EC{sub b}) were measured by 50 horizontal and 2 vertical TDR probes. A new TDR calibration method that gives a detailed relationship between apparent relative dielectric permittivity (K{sub s}) and {theta} was applied. Two replicate solutemore » transport experiments were conducted adding a conservative tracer (CCl) to the surface as a short pulse. The convective lognormal transfer function model (CLT) was fitted to the TDR-measured time integral-normalized resident concentration breakthrough curves (BTCs). The BTCs and the average solute-transport velocities showed preferential flow occurred across the layer boundary. A nonlinear decrease in TDR-measured {theta} in the upper soil toward the soil layer boundary suggests the existence of a 0.10-m zone where water is confined towards fingered flow, creating lateral variations in the area-averaged water flux above the layer boundary. A comparison of the time integral-normalized flux concentration measured by vertical and horizontal TDR probes at the layer boundary also indicates a nonuniform solute transport. The solute dispersivity remained constant in the upper soil layer, but increased nonlinearly (and further down, linearly) with depth in the lower layer, implying convective-dispersive solute transport in the upper soil, a transition zone just below the boundary, and stochastic-convective solute transport in the remaining part of the lower soil.« less

Determination of the Mass Absorption Coefficient in Two-Layer Ti/V and V/Ti Thin Film Systems by the X-Ray Fluorescence Method

NASA Astrophysics Data System (ADS)

Mashin, N. I.; Chernyaeva, E. A.; Tumanova, A. N.; Gafarova, L. M.

2016-03-01

A new XRF procedure for the determination of the mass absorption coefficient in thin film Ti/V and V/Ti two-layer systems has been proposed. The procedure uses easy-to-make thin-film layers of sputtered titanium and vanadium on a polymer film substrate. Correction coefficients have been calculated that take into account attenuation of primary radiation of the X-ray tube, as well as attenuation of the spectral line of the bottom layer element in the top layer.

Effects of forest conversion on soil microbial communities depend on soil layer on the eastern Tibetan Plateau of China.

PubMed

He, Ruoyang; Yang, Kaijun; Li, Zhijie; Schädler, Martin; Yang, Wanqin; Wu, Fuzhong; Tan, Bo; Zhang, Li; Xu, Zhenfeng

2017-01-01

Forest land-use changes have long been suggested to profoundly affect soil microbial communities. However, how forest type conversion influences soil microbial properties remains unclear in Tibetan boreal forests. The aim of this study was to explore variations of soil microbial profiles in the surface organic layer and subsurface mineral soil among three contrasting forests (natural coniferous forest, NF; secondary birch forest, SF and spruce plantation, PT). Soil microbial biomass, activity and community structure of the two layers were investigated by chloroform fumigation, substrate respiration and phospholipid fatty acid analysis (PLFA), respectively. In the organic layer, both NF and SF exhibited higher soil nutrient levels (carbon, nitrogen and phosphorus), microbial biomass carbon and nitrogen, microbial respiration, PLFA contents as compared to PT. However, the measured parameters in the mineral soils often did not differ following forest type conversion. Irrespective of forest types, the microbial indexes generally were greater in the organic layer than in the mineral soil. PLFAs biomarkers were significantly correlated with soil substrate pools. Taken together, forest land-use change remarkably altered microbial community in the organic layer but often did not affect them in the mineral soil. The microbial responses to forest land-use change depend on soil layer, with organic horizons being more sensitive to forest conversion.

Long term consequences of a controlled slash burn and slash mastication to soil moisture and CO2 at a southern Colorado site

Treesearch

W. J. Massman; J. M. Frank; A. E. Jimenez Esquilin; M. E. Stromberger; W. D. Shepperd

2006-01-01

Thinning of forest stands is frequently used to reduce the risk of catastrophic fire. But thinning requires that the refuse (or slash) be removed from the site, which can be done either by burning it or by mastication and dispersal. Either method has long term consequences to the soil and to soil moisture and soil CO2 levels. For example, after the initial drying of...

High Performance and Highly Reliable ZnO Thin Film Transistor Fabricated by Atomic Layer Deposition for Next Generation Displays

DTIC Science & Technology

2011-08-19

zinc oxide ( ZnO ) thin film as an active channel layer in TFT has become of great interest owing to their specific...630-0192 Japan Phone: +81-743-72-6060 Fax: +81-743-72-6069 E-mail: uraoka@ms.naist.jp Keywords: zinc oxide , thin film transistors , atomic layer...deposition Symposium topic: Transparent Semiconductors Oxides [Abstract] In this study, we fabricated TFTs using ZnO thin film as the

Soil responses to management, increased precipitation, and added nitrogen in ponderosa pine forests.

PubMed

Hungate, Bruce A; Hart, Stephen C; Selmants, Paul C; Boyle, Sarah I; Gehring, Catherine A

2007-07-01

Forest management, climatic change, and atmospheric N deposition can affect soil biogeochemistry, but their combined effects are not well understood. We examined the effects of water and N amendments and forest thinning and burning on soil N pools and fluxes in ponderosa pine forests near Flagstaff, Arizona (USA). Using a 15N-depleted fertilizer, we also documented the distribution of added N into soil N pools. Because thinning and burning can increase soil water content and N availability, we hypothesized that these changes would alleviate water and N limitation of soil processes, causing smaller responses to added N and water in the restored stand. We found little support for this hypothesis. Responses of fine root biomass, potential net N mineralization, and the soil microbial N to water and N amendments were mostly unaffected by stand management. Most of the soil processes we examined were limited by N and water, and the increased N and soil water availability caused by forest restoration was insufficient to alleviate these limitations. For example, N addition caused a larger increase in potential net nitrification in the restored stand, and at a given level of soil N availability, N addition had a larger effect on soil microbial N in the restored stand. Possibly, forest restoration increased the availability of some other limiting resource, amplifying responses to added N and water. Tracer N recoveries in roots and in the forest floor were lower in the restored stand. Natural abundance delta15N of labile soil N pools were higher in the restored stand, consistent with a more open N cycle. We conclude that thinning and burning open up the N cycle, at least in the short-term, and that these changes are amplified by enhanced precipitation and N additions. Our results suggest that thinning and burning in ponderosa pine forests will not increase their resistance to changes in soil N dynamics resulting from increased atmospheric N deposition or increased precipitation due to climatic change. Restoration plans should consider the potential impact on long-term forest productivity of greater N losses from a more open N cycle, especially during the period immediately after thinning and burning.

Soil microbiological properties and enzymatic activities of long-term post-fire recovery in dry and semiarid Aleppo pine (Pinus halepensis M.) forest stands

NASA Astrophysics Data System (ADS)

Hedo, J.; Lucas-Borja, M. E.; Wic, C.; Andrés-Abellán, M.; de Las Heras, J.

2015-02-01

Wildfires affecting forest ecosystems and post-fire silvicultural treatments may cause considerable changes in soil properties. The capacity of different microbial groups to recolonise soil after disturbances is crucial for proper soil functioning. The aim of this work was to investigate some microbial soil properties and enzyme activities in semiarid and dry Aleppo pine (Pinus halepensis M.) forest stands. Different plots affected by a wildfire event 17 years ago without or with post-fire silvicultural treatments 5 years after the fire event were selected. A mature Aleppo pine stand, unaffected by wildfire and not thinned was used as a control. Physicochemical soil properties (soil texture, pH, carbonates, organic matter, electrical conductivity, total N and P), soil enzymes (urease, phosphatase, β-glucosidase and dehydrogenase activities), soil respiration and soil microbial biomass carbon were analysed in the selected forests areas and plots. The main finding was that long time after this fire event produces no differences in the microbiological soil properties and enzyme activities of soil after comparing burned and thinned, burned and not thinned, and mature plots. Moreover, significant site variation was generally seen in soil enzyme activities and microbiological parameters. We conclude that total vegetation recovery normalises post-fire soil microbial parameters, and that wildfire and post-fire silvicultural treatments are not significant factors affecting soil properties after 17 years.

Drivers of tall shrub proliferation adjacent to the Dempster Highway, Northwest Territories, Canada

NASA Astrophysics Data System (ADS)

Cameron, Emily A.; Lantz, Trevor C.

2016-04-01

Arctic ecosystems are undergoing rapid changes as a result of climate warming and more frequent disturbances. Disturbances can have particularly large effects on high-latitude ecosystems when ecosystem structure and function is controlled by strong feedbacks between soil conditions, vegetation, and ground thermal regime. In this study we investigated the impact of road construction and maintenance on vegetation structure and biomass along the Dempster Highway where it crosses the Peel Plateau in the Northwest Territories. To explore drivers of tall shrub proliferation and to quantify shrub proliferation in this region of continuous permafrost, greyscale air photos (1975) and Quickbird satellite imagery (2008) were used to map landcover change within two 0.6 km2 belts next to the road and two 0.6 km2 belts 500 m away from the road. Maps showing areas where: 1) tall shrubs expanded, and 2) dwarf shrub tundra resisted invasion were then used to select field sites where a suite of biophysical variables were measured. Rapid tall shrub proliferation and greater biomass adjacent to the road indicate that disturbance can facilitate vegetation change in tundra environments. Our field data also suggests that increased shrub proliferation adjacent to the road was caused by greater soil moisture. Tall shrub proliferation adjacent to the road occurred at lower elevation sites characterized by wetter soils with thicker organic layers. Areas that resisted tall shrub encroachment were located at higher elevations and had drier soils with thin organic layers. Our observations also support previous work illustrating that tall shrub expansion next to the highway promotes strong positive feedbacks to ongoing shrub growth and proliferation.

Thermal removal of pyrene contamination from soil: basic studies and environmental health implications.

PubMed Central

Saito, H H; Bucalá, V; Howard, J B; Peters, W A

1998-01-01

Effects of temperature (400-1000 degrees C) and rate of heating to 550 degrees C (100, 1000, 5000 degrees C/sec) on reduction of pyrene contamination in a Superfund-related soil and on yields of volatile products (tars, CO, CO2, methane, acetylene, ethylene) have been measured. Fifty (+/- 3)-milligram thin layers (less than or equal to 150 micron) of 63- to 125-micron soil particles, neat (i.e., without exogenous chemicals), or pretreated with 4.75 wt% of pyrene, were heated for about 1 to 6 sec, under 3 psig (pounds per in.(2) gauge) of helium in a 12-liter sealed chamber. Pyrene removal, defined as the difference in weight loss of neat versus contaminated soil, was virtually immune to heating rate but increased strongly with increasing temperature, approaching 100% at about 530 degrees C. However, for pyrenepolluted soil, excess soil weight loss and modified CO yields were observed above about 500 degrees C for a 1000 degrees C/sec heating rate. These observations suggest that soil chemical reactions with pyrene or pyrene decomposition products augment soil volatilization. Consequently at elevated temperatures, the difference in weight loss protocol may overestimate polycyclic aromatic hydrocarbon (PAH) removal from soil. Increasing heating rate caused yields of CO, CO(2), and acetylene from pyrene-polluted soil to pass through maxima. Heating neat or contaminated soil resulted in at least two gaseous products of particular environmental interest:acetylene, a precursor to PAH in thermal synthesis, and CO, a toxin to human hemoglobin. Images Figure 1 Figure 2 PMID:9703498

Domain matched epitaxial growth of (111) Ba{sub 0.5}Sr{sub 0.5}TiO{sub 3} thin films on (0001) Al{sub 2}O{sub 3} with ZnO buffer layer

DOE Office of Scientific and Technical Information (OSTI.GOV)

Krishnaprasad, P. S., E-mail: pskrishnaprasu@gmail.com, E-mail: mkj@cusat.ac.in; Jayaraj, M. K., E-mail: pskrishnaprasu@gmail.com, E-mail: mkj@cusat.ac.in; Antony, Aldrin

2015-03-28

Epitaxial (111) Ba{sub 0.5}Sr{sub 0.5}TiO{sub 3} (BST) thin films have been grown by pulsed laser deposition on (0001) Al{sub 2}O{sub 3} substrate with ZnO as buffer layer. The x-ray ω-2θ, Φ-scan and reciprocal space mapping indicate epitaxial nature of BST thin films. The domain matched epitaxial growth of BST thin films over ZnO buffer layer was confirmed using Fourier filtered high resolution transmission electron microscope images of the film-buffer interface. The incorporation of ZnO buffer layer effectively suppressed the lattice mismatch and promoted domain matched epitaxial growth of BST thin films. Coplanar inter digital capacitors fabricated on epitaxial (111) BSTmore » thin films show significantly improved tunable performance over polycrystalline thin films.« less

Experimental Study of Acid Treatment Toward Characterization of Structural, Optical, and Morphological Properties of TiO2-SnO2 Composite Thin Film

NASA Astrophysics Data System (ADS)

Fajar, M. N.; Hidayat, R.; Triwikantoro; Endarko

2018-04-01

The TiO2-SnO2 thin film with single and double-layer structure has successfully synthesized on FTO (Fluorine-doped Tin Oxide) substrate using the screen printing technique. The structural, optical, and morphological properties of the film were investigated by XRD, UV-Vis, and SEM, respectively. The results showed that the single and double-layer structure of TiO2-SnO2 thin film has mixed phase with a strong formation of casseritte phase. The acid treatment effect on TiO2-SnO2 thin film decreases the peak intensity of anatase phase formation and thin film’s absorbance values. The morphological study is also revealed that the single layer TiO2-SnO2 thin film had a more porous nature and decreased particle size distribution after acid treatment, while the double-layer TiO2-SnO2 thin film Eroded due to acid treatment.

Nanopore thin film enabled optical platform for drug loading and release.

PubMed

Song, Chao; Che, Xiangchen; Que, Long

2017-08-07

In this paper, a drug loading and release device fabricated using nanopore thin film and layer-by-layer (LbL) nanoassembly is reported. The nanopore thin film is a layer of anodic aluminum oxide (AAO), consisting of honeycomb-shape nanopores. Using the LbL nanoassembly process, the drug, using gentamicin sulfate (GS) as the model, can be loaded into the nanopores and the stacked layers on the nanopore thin film surface. The drug release from the device is achieved by immersing it into flowing DI water. Both the loading and release processes can be monitored optically. The effect of the nanopore size/volume on drug loading and release has also been evaluated. Further, the neuron cells have been cultured and can grow normally on the nanopore thin film, verifying its bio-compatibility. The successful fabrication of nanopore thin film device on silicon membrane render it as a potential implantable controlled drug release device.

Soil gas radon concentrations measurements in terms of great soil groups.

PubMed

Içhedef, Mutlu; Saç, Müslim Murat; Camgöz, Berkay; Bolca, Mustafa; Harmanşah, Çoşkun

2013-12-01

In this study, soil gas radon concentrations were investigated according to locations, horizontal soil layers and great soil groups around Tuzla Fault, Seferihisar-İzmir. Great soil groups are a category that described the horizontal soil layers under soil classification system and distributions of radon concentration in the great soil groups are firstly determined by the present study. According to the obtained results, it has been showed that the radon concentrations in the Koluvial soil group are higher than the other soil groups in the region. Also significant differences on location in same great soil group were determined. The radon concentrations in the Koluvial soil groups were measured with respect to soil layers structures (A, B, C1, and C2). It has been observed that the values increase with depth of soil (C2>C1>B>A). The main reason may be due to the meteorological factors that have limited effect on radon escape from deep layers. Although fault lines pass thought the study area radon concentrations were varied location to location, layer to layer and great group to great group. The study shows that a detailed location description should be performed before soil radon measurements for earthquake predictions. Copyright © 2013 Elsevier Ltd. All rights reserved.

Dominant Douglas-fir respond to fertilizing and thinning in southwest Oregon

Treesearch

Richard E. Miller; Richard L. Williamson

1974-01-01

In 30-year-old, Site IV Douglas-fir in southwest Oregon, fertilizing increased average 4-year basal area growth of dominant trees by 57 and 28 percent on clay loam and sandy loam soils, respectively. Fertilizing with thinning increased growth by 94 and 132 percent over untreated growth. Thinning on clay loam soil increased growth by 53 percent. Treatment did not affect...

Surface passivation investigation on ultra-thin atomic layer deposited aluminum oxide layers for their potential application to form tunnel layer passivated contacts

NASA Astrophysics Data System (ADS)

Xin, Zheng; Ling, Zhi Peng; Nandakumar, Naomi; Kaur, Gurleen; Ke, Cangming; Liao, Baochen; Aberle, Armin G.; Stangl, Rolf

2017-08-01

The surface passivation performance of atomic layer deposited ultra-thin aluminium oxide layers with different thickness in the tunnel layer regime, i.e., ranging from one atomic cycle (∼0.13 nm) to 11 atomic cycles (∼1.5 nm) on n-type silicon wafers is studied. The effect of thickness and thermal activation on passivation performance is investigated with corona-voltage metrology to measure the interface defect density D it(E) and the total interface charge Q tot. Furthermore, the bonding configuration variation of the AlO x films under various post-deposition thermal activation conditions is analyzed by Fourier transform infrared spectroscopy. Additionally, poly(3,4-ethylenedioxythiophene) poly(styrene sulfonate) is used as capping layer on ultra-thin AlO x tunneling layers to further reduce the surface recombination current density to values as low as 42 fA/cm2. This work is a useful reference for using ultra-thin ALD AlO x layers as tunnel layers in order to form hole selective passivated contacts for silicon solar cells.

Fabrication and properties of ZnO/GaN heterostructure nanocolumnar thin film on Si (111) substrate

PubMed Central

2013-01-01

Zinc oxide thin films have been obtained on bare and GaN buffer layer decorated Si (111) substrates by pulsed laser deposition (PLD), respectively. GaN buffer layer was achieved by a two-step method. The structure, surface morphology, composition, and optical properties of these thin films were investigated by X-ray diffraction, field emission scanning electron microscopy, infrared absorption spectra, and photoluminiscence (PL) spectra, respectively. Scanning electron microscopy images indicate that the flower-like grains were presented on the surface of ZnO thin films grown on GaN/Si (111) substrate, while the ZnO thin films grown on Si (111) substrate show the morphology of inclination column. PL spectrum reveals that the ultraviolet emission efficiency of ZnO thin film on GaN buffer layer is high, and the defect emission of ZnO thin film derived from Zni and Vo is low. The results demonstrate that the existence of GaN buffer layer can greatly improve the ZnO thin film on the Si (111) substrate by PLD techniques. PMID:23448090

Fabrication and properties of ZnO/GaN heterostructure nanocolumnar thin film on Si (111) substrate.

PubMed

Wei, Xianqi; Zhao, Ranran; Shao, Minghui; Xu, Xijin; Huang, Jinzhao

2013-02-28

Zinc oxide thin films have been obtained on bare and GaN buffer layer decorated Si (111) substrates by pulsed laser deposition (PLD), respectively. GaN buffer layer was achieved by a two-step method. The structure, surface morphology, composition, and optical properties of these thin films were investigated by X-ray diffraction, field emission scanning electron microscopy, infrared absorption spectra, and photoluminiscence (PL) spectra, respectively. Scanning electron microscopy images indicate that the flower-like grains were presented on the surface of ZnO thin films grown on GaN/Si (111) substrate, while the ZnO thin films grown on Si (111) substrate show the morphology of inclination column. PL spectrum reveals that the ultraviolet emission efficiency of ZnO thin film on GaN buffer layer is high, and the defect emission of ZnO thin film derived from Zni and Vo is low. The results demonstrate that the existence of GaN buffer layer can greatly improve the ZnO thin film on the Si (111) substrate by PLD techniques.

Conductive layer for biaxially oriented semiconductor film growth

DOEpatents

Findikoglu, Alp T.; Matias, Vladimir

2007-10-30

A conductive layer for biaxially oriented semiconductor film growth and a thin film semiconductor structure such as, for example, a photodetector, a photovoltaic cell, or a light emitting diode (LED) that includes a crystallographically oriented semiconducting film disposed on the conductive layer. The thin film semiconductor structure includes: a substrate; a first electrode deposited on the substrate; and a semiconducting layer epitaxially deposited on the first electrode. The first electrode includes a template layer deposited on the substrate and a buffer layer epitaxially deposited on the template layer. The template layer includes a first metal nitride that is electrically conductive and has a rock salt crystal structure, and the buffer layer includes a second metal nitride that is electrically conductive. The semiconducting layer is epitaxially deposited on the buffer layer. A method of making such a thin film semiconductor structure is also described.

Unexpected structural and magnetic depth dependence of YIG thin films

NASA Astrophysics Data System (ADS)

Cooper, J. F. K.; Kinane, C. J.; Langridge, S.; Ali, M.; Hickey, B. J.; Niizeki, T.; Uchida, K.; Saitoh, E.; Ambaye, H.; Glavic, A.

2017-09-01

We report measurements on yttrium iron garnet (YIG) thin films grown on both gadolinium gallium garnet (GGG) and yttrium aluminum garnet (YAG) substrates, with and without thin Pt top layers. We provide three principal results: the observation of an interfacial region at the Pt/YIG interface, we place a limit on the induced magnetism of the Pt layer, and confirm the existence of an interfacial layer at the GGG/YIG interface. Polarized neutron reflectometry (PNR) was used to give depth dependence of both the structure and magnetism of these structures. We find that a thin film of YIG on GGG is best described by three distinct layers: an interfacial layer near the GGG, around 5 nm thick and nonmagnetic, a magnetic "bulk" phase, and a nonmagnetic and compositionally distinct thin layer near the surface. We theorize that the bottom layer, which is independent of the film thickness, is caused by Gd diffusion. The top layer is likely to be extremely important in inverse spin Hall effect measurements, and is most likely Y2O3 or very similar. Magnetic sensitivity in the PNR to any induced moment in the Pt is increased by the existence of the Y2O3 layer; any moment is found to be less than 0.02 μB/atom .

Methods for fabricating thin film III-V compound solar cell

DOEpatents

Pan, Noren; Hillier, Glen; Vu, Duy Phach; Tatavarti, Rao; Youtsey, Christopher; McCallum, David; Martin, Genevieve

2011-08-09

The present invention utilizes epitaxial lift-off in which a sacrificial layer is included in the epitaxial growth between the substrate and a thin film III-V compound solar cell. To provide support for the thin film III-V compound solar cell in absence of the substrate, a backing layer is applied to a surface of the thin film III-V compound solar cell before it is separated from the substrate. To separate the thin film III-V compound solar cell from the substrate, the sacrificial layer is removed as part of the epitaxial lift-off. Once the substrate is separated from the thin film III-V compound solar cell, the substrate may then be reused in the formation of another thin film III-V compound solar cell.

Schottky barrier solar cell

NASA Technical Reports Server (NTRS)

Stirn, R. J.; Yeh, Y. C. M. (Inventor)

1981-01-01

A method of fabricating a Schottky barrier solar cell is described. The cell consists of a thin substrate of low cost material with at least the top surface of the substrate being electrically conductive. A thin layer of heavily doped n-type polycrystalling germanium is deposited on the substrate after a passivation layer is deposited to prevent migration of impurities into the polycrystalline germanium. The polycrystalline germanium is recrystallized to increase the crystal sizes to serve as a base layer on which a thin layer of gallium arsenide is vapor-epitaxilly grown followed by a thermally-grown oxide layer. A metal layer is deposited on the oxide layer and a grid electrode is deposited to be in electrical contact with the top surface of the metal layer.

Laser readable thermoluminescent radiation dosimeters and methods for producing thereof

DOEpatents

Braunlich, Peter F.; Tetzlaff, Wolfgang

1989-01-01

Thin layer thermoluminescent radiation dosimeters for use in laser readable dosimetry systems, and methods of fabricating such thin layer dosimeters. The thin layer thermoluminescent radiation dosimeters include a thin substrate made from glass or other inorganic materials capable of withstanding high temperatures and high heating rates. A thin layer of a thermoluminescent phoshphor material is heat bonded to the substrate using an inorganic binder such as glass. The dosimeters can be mounted in frames and cases for ease in handling. Methods of the invention include mixing a suitable phosphor composition and binder, both being in particulate or granular form. The mixture is then deposited onto a substrate such as by using mask printing techniques. The dosimeters are thereafter heated to fuse and bond the binder and phosphor to the substrate.

Antisoiling technology: Theories of surface soiling and performance of antisoiling surface coatings

NASA Technical Reports Server (NTRS)

Cuddihy, E. F.; Willis, P. B.

1984-01-01

Physical examination of surfaces undergoing natural outdoor soiling suggests that soil matter accumulates in up to three distinct layers. The first layer involves strong chemical attachment or strong chemisorption of soil matter on the primary surface. The second layer is physical, consisting of a highly organized arrangement of soil creating a gradation in surface energy from a high associated with the energetic first layer to the lowest possible state on the outer surfce of the second layer. The lowest possible energy state is dictated by the physical nature of the regional atmospheric soiling materials. These first two layers are resistant to removal by rain. The third layer constitutes a settling of loose soil matter, accumulating in dry periods and being removed during rainy periods. Theories and evidence suggest that surfaces that should be naturally resistant to the formation of the first two-resistant layers should be hard, smooth, hydrophobic, free of first-period elements, and have the lowest possible surface energy. These characteristics, evolving as requirements for low-soiling surfaces, suggest that surfaces or surface coatings should be of fluorocarbon chemistry. Evidence for the three-soil-layer concept, and data on the positive performance of candidate fluorocarbon coatings on glass and transparent plastic films after 28 months of outdoor exposure, are presented.

BOREAS Soils Data over the SSA in Raster Format and AEAC Projection

NASA Technical Reports Server (NTRS)

Knapp, David; Rostad, Harold; Hall, Forrest G. (Editor)

2000-01-01

This data set consists of GIS layers that describe the soils of the BOREAS SSA. The original data were submitted as vector layers that were gridded by BOREAS staff to a 30-meter pixel size in the AEAC projection. These data layers include the soil code (which relates to the soil name), modifier (which also relates to the soil name), and extent (indicating the extent that this soil exists within the polygon). There are three sets of these layers representing the primary, secondary, and tertiary soil characteristics. Thus, there is a total of nine layers in this data set along with supporting files. The data are stored in binary, image format files.

[Characteristics of soil moisture in artificial impermeable layers].

PubMed

Suo, Gai-Di; Xie, Yong-Sheng; Tian, Fei; Chuai, Jun-Feng; Jing, Min-Xiao

2014-09-01

For the problem of low water and fertilizer use efficiency caused by nitrate nitrogen lea- ching into deep soil layer and soil desiccation in dryland apple orchard, characteristics of soil moisture were investigated by means of hand tamping in order to find a new approach in improving the water and fertilizer use efficiency in the apple orchard. Two artificial impermeable layers of red clay and dark loessial soil were built in soil, with a thickness of 3 or 5 cm. Results showed that artificial impermeable layers with the two different thicknesses were effective in reducing or blocking water infiltration into soil and had higher seepage controlling efficiency. Seepage controlling efficiency for the red clay impermeable layer was better than that for the dark loessial soil impermeable layer. Among all the treatments, the red clay impermeable layer of 5 cm thickness had the highest bulk density, the lowest initial infiltration rate (0.033 mm · min(-1)) and stable infiltration rate (0.018 mm · min(-1)) among all treatments. After dry-wet alternation in summer and freezing-thawing cycle in winter, its physiochemical properties changed little. Increase in years did not affect stable infiltration rate of soil water. The red clay impermeable layer of 5 cm thickness could effectively increase soil moisture content in upper soil layer which was conducive to raise the water and nutrient use efficiency. The approach could be applied to the apple production of dryland orchard.

The Opportunity Rover's Athena science investigation at Meridiani Planum, Mars

NASA Technical Reports Server (NTRS)

Squyres, S. W.; Arvidson, R. E.; Bell, J. F., III; Bruckner, J.; Cabrol, N. A.; Calvin, W.; Carr, M. H.; Christensen, P. R.; Clark, B. C.; Crumpler, L.;

The opportunity Rover's athena science investigation at Meridiani Planum, Mars

USGS Publications Warehouse

Squyres, S. W.; Arvidson, R. E.; Bell, J.F.; Brückner, J.; Cabrol, N.A.; Calvin, W.; Carr, M.H.; Christensen, P.R.; Clark, B. C.; Crumpler, L.; Des Marais, D.J.; D'Uston, C.; Economou, T.; Farmer, J.; Farrand, W.; Folkner, W.; Golombek, M.; Gorevan, S.; Grant, J. A.; Greeley, R.; Grotzinger, J.; Haskin, L.; Herkenhoff, K. E.; Hviid, S.; Johnson, J.; Klingelhofer, G.; Knoll, A.H.; Landis, G.; Lemmon, M.; Li, R.; Madsen, M.B.; Malin, M.C.; McLennan, S.M.; McSween, H.Y.; Ming, D. W.; Moersch, J.; Morris, R.V.; Parker, T.; Rice, J. W.; Richter, L.; Rieder, R.; Sims, M.; Smith, M.; Smith, P.; Soderblom, L.A.; Sullivan, R.; Wanke, H.; Wdowiak, T.; Wolff, M.; Yen, A.

2004-01-01

The Mars Exploration Rover Opportunity has investigated the landing site in Eagle crater and the nearby plains within Meridiani Planum. The soils consist of fine-grained basaltic sand and a surface lag of hematite-rich spherules, spherule fragments, and other granules. Wind ripples are common. Underlying the thin soil layer, and exposed within small impact craters and troughs, are flat-lying sedimentary rocks. These rocks are finely laminated, are rich in sulfur, and contain abundant sulfate salts. Small-scale cross-lamination in some locations provides evidence for deposition in flowing liquid water. We interpret the rocks to be a mixture of chemical and siliciclastic sediments formed by episodic inundation by shallow surface water, followed by evaporation, exposure, and desiccation. Hematite-rich spherules are embedded in the rock and eroding from them. We interpret these spherules to be concretions formed by postdepositional diagenesis, again involving liquid water.

Layered Organization in the Coastal Ocean: 4-D Assessment of Thin Layer Structure, Dynamics and Impacts

DTIC Science & Technology

2007-09-30

For example, the differences seen between the waters off of the US Pacific Northwest and the California Bight are almost certainly a reflection of the...the Pacific Northwest were favorable for thin layer development during that study. This is even more evident in those cases where thin layers...approach during the 2005 and 2006 LOCO process study combined time series data from an array of our Ocean Response Coastal Analysis System ( ORCAS ) (Donaghay

Soil Respiration Controls Ionic Nutrient Concentration In Percolating Water In Rice Fields

NASA Astrophysics Data System (ADS)

Kimura, M.

2004-12-01

Soil water in the plow layer in rice fields contains various kinds of cations and anions, and they are lost from the plow layer by water percolation. Some portions of CO2 produced by respirations of rice roots and soil microorganisms are also leached by water percolation to the subsoil layer as HCO3-. As the electrical neutrality of inorganic substances in percolating water is maintained when they are assumed to be in the form of simple cations and anions, soil respiration accelerates the leaching of ionic nutrients from the plow layer by water percolation. The proportion of inorganic carbon (Σ CO2) originated from photosynthates in the total Σ CO2 in soil solution in the plow layer was from 28 to 36 % in the rice straw amended soil and from 16 to 31 % in the soil without rice straw amendment in a soil pot experiment with rice plant after the maximum tillering stage. Most of Σ CO2 in percolating water from the plow layer accumulates in the subsoil layer. Periodical measurement of Σ CO2 in percolating water at 13 and 40 cm soil depths indicated that 10 % of total soil organic C in the plow layer was leached down from the plow layer (13 cm), and that about 90 % of it was retained in the subsoil layer to the depth of 40 cm. Water soluble organic materials are also leached from the plow layer by water percolation, and the leaching is accelerated by soil reduction. Soil reduction decreased the content of organic materials that were bound with ferric iron in soil (extractable by 0.1M Na4P2O7 + NaBH4) and increased the content of organic materials that were extractable by the neutral chelating solution (0.1M Na4P2O7). In addition, water percolation transformed the latter organic materials to those that were extractable by water and a neutral salt. Considerable portions of organic materials in percolating water are adsorbed in the subsoil layer, and then partially decomposed and polymerized to specific soil organic materials in the subsoil. Organic materials that were leached from the plow layer by percolating water amounted to 170 kgC ha-1 in a Japanese rice field, among which 120 kgC of organic materials were adsorbed in the subsoil layer between 13 and 40 cm depth.

Ice Lens Formation, Frost Heave, Thin Films, and the Importance of the Polar H2O Reservoir at High Obliquity

NASA Technical Reports Server (NTRS)

Zent, A. P.; Sizemore, H. G.; Rempel, A. W.

2011-01-01

Several lines of evidence indicate that the volume of shallow ground ice in the martian high latitudes exceeds the pore volume of the host regolith. Boynton et al. found an optimal fit to the Mars Odyssey Gamma Ray Spectrometer (GRS) data at the Phoenix landing site by modeling a buried layer of 50-75% ice by mass (up to 90% ice by volume). Thermal and optical observations of recent impact craters in the northern hemisphere have revealed nearly pure ice. Ice deposits containing only 1-2% soil by volume were excavaged by Phoenix. One hypothesis for the origin of this excess ice is that it developed in situ by a mechanism analogous to the formation of terrestrial ice lenses and needle ice. Problematically, terrestrial soil-ice segregation is driven by freeze/thaw cycling and the movement of bulk water, neither of which are expected to have occurred in the geologically recent past on Mars. If however ice lens formation is possible at temperatures less than 273 K, there are possible implications for the habitability of Mars permafrost, since the same thin films of unfrozen water that lead to ice segregation are used by terrestrial psychrophiles to metaboluze and grow down to temperatures of at least 258 K.

Influence of an experimental herbicide on soil nitrogen-fixing bacteria and other microorganisms

DOE Office of Scientific and Technical Information (OSTI.GOV)

Nelson, L.M. Jr.; Hedrick, H.G.

Influence of an experimental herbicide on two isolates of soil nitrogen-fixing bacteria Rhizobium japonicum 3I1b110 and Azotobacter vinelandii ATCC 12837, was determined using a bioresponse assay, thin-layer chromatographic analysis, and changes in viable cells on the herbicide as the sole source of organic carbon. Seven bacterial and nine fungus isolates were also found by a soil enrichment technique to show utilization of the herbicide. A. vinelandii showed stimulation of growth in the first 4 days of exposure on the herbicide at 1,000 ppM. The herbicide then became toxic or was metabolized into toxic by-products. R. japonicum showed utilization of themore » herbicide by changes in growth rate as influenced by the inoculum concentration, the thoroughness of inoculum washing, and the concentration of herbicide. Using TLC assay techniques, the herbicide was found to be depleted in laboratory experiments by R. japonicum following 10 days of growth, without detectable nonmetabolic by-products. These findings suggested that the addition of the experimental herbicide to soils planted with bean crops could possibly influence the metabolic activity of R. japonicum as a symbiotic nitrogen-fixing bacterium. 5 figures, 1 table.« less

Short-term effects of experimental burning and thinning on soil respiration in an old-growth, mixed-conifer forest

Treesearch

Siyan Ma; Jiquan Chen; Malcolm North; Heather E. Erickson; Mary Bresee; James Le Moine

2004-01-01

To understand the roles of forest management practices in meeting the goals of forest sustainability and CO2 sequestration, we evaluated the effects of burning and thinning treatments on soil respiration and soil environments in an old-growth, mixed-conifer forest in California’s southern Sierra Nevada. Six experimental treatments with two levels...

Solvent-dependent transformation of aflatoxin B1 in soil.

PubMed

Starr, James M; Rushing, Blake R; Selim, Mustafa I

2017-08-01

To date, all studies of aflatoxin B 1 (AFB 1 ) transformation in soil or in purified mineral systems have identified aflatoxins B 2 (AFB 2 ) and G 2 (AFG 2 ) as the primary transformation products. However, identification in these studies was made using thin layer chromatography which has relatively low resolution, and these studies did not identify a viable mechanism by which such transformations would occur. Further, the use of methanol as the solvent delivery vehicle in these studies may have contributed to formation of artifactual transformation products. In this study, we investigated the role of the solvent vehicle in the transformation of AFB 1 in soil. To do this, we spiked soils with AFB 1 dissolved in water (93:7, water/methanol) or methanol and used HPLC-UV and HPLC-MS to identify the transformation products. Contrasting previous published reports, we did not detect AFB 2 or AFG 2 . In an aqueous-soil environment, we identified aflatoxin B 2a (AFB 2a ) as the single major transformation product. We propose that AFB 2a is formed from hydrolysis of AFB 1 with the soil acting as an acid catalyst. Alternatively, when methanol was used, we identified methoxy aflatoxin species likely formed via acid-catalyzed addition of methanol to AFB 1 . These results suggest that where soil moisture is adequate, AFB 1 is hydrolyzed to AFB 2a and that reactive organic solvents should be avoided when replicating natural conditions to study the fate of AFB 1 in soil.

Intensification of freeze-thaw cycles in the soil on post-fire alpine slopes of Mount Shirouma-dake, northern Japanese Alps central Japan

NASA Astrophysics Data System (ADS)

Sasaki, A.; Suzuki, K.

2016-12-01

This is the continuous study to clarify the geo-environmental changes on the post-fire alpine slopes of Mount Shirouma-dake in the Northern Japanese Alps. The fire occurred at May 9, 2009 on the alpine slopes of Mount Shirouma-dake, and the fire spread to the Pinus pumila communities and grasslands. Although the grass had a little damage by the fire, the P. pumila received nearly impact of the fire. In the P. pumila communities where the leaf burnt, forest floor is exposed and become easy to be affected by atmospheric condition such as rain, wind, snow, and etc. First, we observed condition of the micro-landforms on post-fire slopes repeatedly for seventh years after the fire. As the results of the observation, it is clear that remarkable changes of these micro-landforms have not occurred but some litters on the forest-floor in the fired P. pumila communities are flushed out to surroundings. The litter layer on the forest-floor in the fired P. pumila communities were 3-4 cm thick in August of 2011, but it became 0.5 cm thick in September of 2014. The P. pumila communities established on the slopes consists of angular and sub-angular gravel with openwork texture, which are covered by thin soil layer. On July of 2016, the litter layer almost entirely flushed out and surface of soil layer is exposed to atmosphere. In addition, we observe the ground temperature and soil moisture, under the fired P. pumila communities and the no fired P. pumila communities since October 2009, to find influence of the fire. The ground temperature sensors were installed into at 1 cm, 10 cm, and 40 cm depth. The soil moisture sensors were installed into at 1 cm and 10 cm depth. The 1 cm depth of the soil on the post-fire slopes, several times of diurnal freeze-thaw cycles occurred on October and November since 2011, but it had not occurred in 2009 and 2010. In particular, more than 20 times of diurnal freeze-thaw cycles occurred on freezing period of 2014. The diurnal freeze-thaw cycles continue to be increasing until thawing period of 2016. The period of seasonal frost at 10 cm and 40 cm depth on the post-fire slopes are extended for two weeks. Snowmelt water is especially thought to be act on re-freezing of post-fire slopes on thawing period. These thermal condition changes are triggered by decrease in the thickness of the litter layer on the fired P. pumila communities.

Effects of forest conversion on soil microbial communities depend on soil layer on the eastern Tibetan Plateau of China

PubMed Central

He, Ruoyang; Yang, Kaijun; Li, Zhijie; Schädler, Martin; Yang, Wanqin; Wu, Fuzhong; Tan, Bo; Zhang, Li

2017-01-01

Forest land-use changes have long been suggested to profoundly affect soil microbial communities. However, how forest type conversion influences soil microbial properties remains unclear in Tibetan boreal forests. The aim of this study was to explore variations of soil microbial profiles in the surface organic layer and subsurface mineral soil among three contrasting forests (natural coniferous forest, NF; secondary birch forest, SF and spruce plantation, PT). Soil microbial biomass, activity and community structure of the two layers were investigated by chloroform fumigation, substrate respiration and phospholipid fatty acid analysis (PLFA), respectively. In the organic layer, both NF and SF exhibited higher soil nutrient levels (carbon, nitrogen and phosphorus), microbial biomass carbon and nitrogen, microbial respiration, PLFA contents as compared to PT. However, the measured parameters in the mineral soils often did not differ following forest type conversion. Irrespective of forest types, the microbial indexes generally were greater in the organic layer than in the mineral soil. PLFAs biomarkers were significantly correlated with soil substrate pools. Taken together, forest land-use change remarkably altered microbial community in the organic layer but often did not affect them in the mineral soil. The microbial responses to forest land-use change depend on soil layer, with organic horizons being more sensitive to forest conversion. PMID:28982191

High average power scaleable thin-disk laser

DOEpatents

Beach, Raymond J.; Honea, Eric C.; Bibeau, Camille; Payne, Stephen A.; Powell, Howard; Krupke, William F.; Sutton, Steven B.

2002-01-01

Using a thin disk laser gain element with an undoped cap layer enables the scaling of lasers to extremely high average output power values. Ordinarily, the power scaling of such thin disk lasers is limited by the deleterious effects of amplified spontaneous emission. By using an undoped cap layer diffusion bonded to the thin disk, the onset of amplified spontaneous emission does not occur as readily as if no cap layer is used, and much larger transverse thin disks can be effectively used as laser gain elements. This invention can be used as a high average power laser for material processing applications as well as for weapon and air defense applications.

The enhancement mechanism of thin plasma layer on antenna radiation

DOE Office of Scientific and Technical Information (OSTI.GOV)

Wang, Chunsheng, E-mail: wangcs@hit.edu.cn; Jiang, Binhao; Li, Xueai

A model of plasma-antenna is carried out to study the radiation enhancement mechanism of antenna covered by thin plasma layer. The results show when the radiation intensity achieves maximum, a region of equal electric field is formed due to the reflection of electric field at the interface of plasma and air. The plasma layer acted as an extension of the antenna. Furthermore, the shape of plasma layer is changed to verify the effect of plasma boundary on antenna radiation. The study shows the effect of thin plasma layer on electromagnetic field and provides a type of plasma antenna.

Changes in quantity and spectroscopic properties of water-extractable organic matter during soil aquifer treatment.

PubMed

Xue, S; Zhao, Q L; Wei, L L; Ma, X P; Tie, M

2013-01-01

The aim of this study was to identify qualitative and quantitative changes in the character of water-extractable organic matter (WEOM) in soils as a consequence of soil aquifer treatment (SAT). Soil samples were obtained from a soil-column system with a 2-year operation, and divided into seven layers from top to bottom: CS1 (0-12.5 cm), CS2 (12.5-25 cm), CS3 (25-50 cm), CS4 (50-75 cm), CS5 (75-100 cm), CS6 (100-125 cm) and CS7 (125-150 cm). A sample of the original soil used to pack the columns was also analysed to determine the effects of SAT. Following 2 years of SAT operation, both soil organic carbon and water-extractable organic carbon were shown to accumulate in the top soil layer (0-12.5 cm), and to decrease in soil layers deeper than 12.5 cm. The WEOM in the top soil layer was characterized by low aromaticity index (AI), low emission humification index (HIX) and low fluorescence efficiency index (F(eff)). On the other hand, the WEOM in soil layers deeper than 12.5 cm had increased values of HIX and F(eff), as well as decreased AI values relative to the original soil before SAT. In all soil layers, the percentage of hydrophobic and transphilic fractions decreased, while that of the hydrophilic fraction increased, as a result of SAT. The production of the amide-2 functional groups was observed in the top soil layer. SAT operation also led to the enrichment of hydrocarbon and amide-1 functional groups, as well as the depletion of oxygen-containing functional groups in soil layers deeper than 12.5 cm.

Improving Fire Resistance of Cotton Fabric through Layer-by-Layer Assembled Graphene Multilayer Nanocoating

NASA Astrophysics Data System (ADS)

Jang, Wonjun; Chung, Il Jun; Kim, Junwoo; Seo, Seongmin; Park, Yong Tae; Choi, Kyungwho

2018-05-01

In this study, thin films containing poly(vinyl alcohol) (PVA) and graphene nanoplatelets (GNPs), stabilized with poly(4-styrene-sulfonic acid) (PSS), were assembled by a simple and cost-effective layer-by-layer (LbL) technique in order to introduce the anti-flammability to cotton. These antiflammable layers were characterized by using UV-vis spectrometry and quartz crystal microbalance as a function of the number of bilayers deposited. Scanning electron microscopy was used to visualize the morphology of the thin film coatings on the cotton fabric. The graphene-polymer thin films introduced anti-flammable properties through thermally stable carbonaceous layers at a high temperature. The thermal stability and flame retardant property of graphene-coated cotton was demonstrated by thermogravimetric analysis, cone calorimetry, and vertical flame test. The results indicate that LbL-assembled graphene-polymer thin films can be applied largely in the field of flame retardant.

Reduction of stand density as a management tool to mitigate the effect of drought

NASA Astrophysics Data System (ADS)

Giuggiola, A.; Rigling, A.; Dobbertin, M.

2012-04-01

An increasing frequency and severity of drought combined with increased competition due to reduced forest management practices are putting many Scots pine forest (Pinus sylvestris) under increased drought pressure. Declining pines are already been observed in many drought exposed regions as in southern Europe or in the dry inner Alpine valleys. Thus, forest management practices oriented at reducing competition for water should increase pines tolerance to climate change and thus enhancing their long-term mitigation potential. In this study, we are testing the beneficial effect of thinning and understory removal as possible management practices. As a first study object we selected a trial with 3 thinning intensities (basal area reduction of 15%, 46% and 70%) and one control (unmanaged forest). The second experiment consisted in removing the understory layer in a radius of 5 meter from 6 mature pine trees. Water-related indicators, such as soil water content, sapflow, point dendrometer and ring width measurements over the growing season were then compared with control trees. Both objects belongs to the pine forests from the dry Rhone valley. Our results indicates that over the 10 years following the thinning performed in 1965 (when the stand was 45 years old) doubled and quadrupled the basal area increment in the medium and heavy treatments compared to the control. The annual mortality rates for the period 1978-1990 ranged between 2.9% for the control and 0.8% for the heavy thinned stand. An increasing mortality rates during the period 1991-2009 (up to 3.3%), with consequent decline in basal area and carbon sequestration, has been observed in relation to high remaining stand density. The removal of understory performed in April 2010 increased soil water content at 30 cm and 65 cm depth reducing trees drought stress. The transpiration and the predawn leaf water potential of overstory trees were higher in the trees with removal of the understory vegetation. The same trees also showed delayed stomata closure during drought periods. This advantage eventually resulted in a significant increase in tree growth, which was observed in the second year after removal. This combining approach highlight the positive effect of competition removal of growth and vitality of Scots pine trees. Our results suggest that in dry forests of the inner-Alps or the Mediterranean region, a strong reduction of basal area (15-25 m2/ha) is suitable to preserve enough water availability to maintain and healthy state. If thinning lead to a major increase of the understory layer, understory removal would prolong the initial positive effect of thinning. Thinning and understory removal enhance tree vitality and increase tree resistance against drought, insects and pathogens. These results simultaneously suggests that pine decline is not driven only by the increase of temperature, but is also a consequence of a change of forest use, specifically for the Valais, to a reduction of goat grazing pressure and wood harvesting.

[Effects of altitudes on soil microbial biomass and enzyme activity in alpine-gorge regions.

PubMed

Cao, Rui; Wu, Fu Zhong; Yang, Wan Qin; Xu, Zhen Feng; Tani, Bo; Wang, Bin; Li, Jun; Chang, Chen Hui

2016-04-22

In order to understand the variations of soil microbial biomass and soil enzyme activities with the change of altitude, a field incubation was conducted in dry valley, ecotone between dry valley and mountain forest, subalpine coniferous forest, alpine forest and alpine meadow from 1563 m to 3994 m of altitude in the alpine-gorge region of western Sichuan. The microbial biomass carbon and nitrogen, and the activities of invertase, urease and acid phosphorus were measured in both soil organic layer and mineral soil layer. Both the soil microbial biomass and soil enzyme activities showed the similar tendency in soil organic layer. They increased from 2158 m to 3028 m, then decreased to the lowest value at 3593 m, and thereafter increased until 3994 m in the alpine-gorge region. In contrast, the soil microbial biomass and soil enzyme activities in mineral soil layer showed the trends as, the subalpine forest at 3028 m > alpine meadow at 3994 m > montane forest ecotone at 2158 m > alpine forest at 3593 m > dry valley at 1563 m. Regardless of altitudes, soil microbial biomass and soil enzyme activities were significantly higher in soil organic layer than in mineral soil layer. The soil microbial biomass was significantly positively correlated with the activities of the measured soil enzymes. Moreover, both the soil microbial biomass and soil enzyme activities were significantly positively correlated with soil water content, organic carbon, and total nitrogen. The activity of soil invertase was significantly positively correlated with soil phosphorus content, and the soil acid phosphatase was so with soil phosphorus content and soil temperature. In brief, changes in vegetation and other environmental factors resulting from altitude change might have strong effects on soil biochemical properties in the alpine-gorge region.

Anthropogenic sediments and soils of tells of the Balkans and Anatolia: Composition, genesis, and relationships with the history of landscape and human occupation

NASA Astrophysics Data System (ADS)

Sedov, S. N.; Aleksandrovskii, A. L.; Benz, M.; Balabina, V. I.; Mishina, T. N.; Shishkov, V. A.; Şahin, F.; Özkaya, V.

2017-04-01

Soils and sediments composing Tell Körtik Tepe (Epipaleolithic, Turkey) and Tell Yunatsite (Chalcolithic (Eneolithic), Bulgaria) have been studied with the aim to gain a better insight into their microfabrics, determine the composition of anthropogenic artifacts, and, on this basis, to analyze similarities and distinctions between these objects and the modern soils of urban areas. The methods of micromorphology, scanning electron microscopy with an energy dispersive X-ray microanalyzer, X-ray fluorometry, and other techniques to determine the chemical and physical properties of the soils and sediments have been applied. Two paleosols have been identified in Tell Yunatsite with a total thickness of 9 m: the paleosol buried under the tell and the paleosol in its middle part. Sediments of Tell Körtik Tepe have a total thickness of up to 5 m; their accumulation began at the end of Pleistocene over the surface of buried paleosol. The cultural layer of the tells consists of construction debris mainly represented by a mixture of clay and sand and of domestic wastes with the high content of phosphorus. The major source of phosphorus is calcium phosphate (apatite) of bone tissues. The abundance of various anthropogenic materials in the sediments is clearly seen in thin sections. Even in the paleosols developed within the cultural layer (the mid-profile paleosol in Tell Yunatsite), the amount of microinclusions of bone fragments, charcoal, and burnt clay (ceramics) is very high. Micromorphological data indicate that up to 50% of the layered material filling an Epipaleolithic construction in Tell Körtik Tepe consists of the anthropogenic inclusions: bone fragments, charcoal, etc. The features of pedogenic transformation are present in the sediments. Such sediments can be classified as synlithogenic soils similar to the modern Urbic Technosols. It is shown that the formation of paleosols and sediments of Tell Körtik Tepe took place under extreme environmental conditions—arid climate of the latest Pleistocene climate cooling phase (the Younger Dryas, Tell Körtik Tepe)—and intensive anthropogenic loads (tells Körtik Tepe and Yunatsite).

Programmable Electrochemical Rectifier Based on a Thin-Layer Cell.

PubMed

Park, Seungjin; Park, Jun Hui; Hwang, Seongpil; Kwak, Juhyoun

2017-06-21

A programmable electrochemical rectifier based on thin-layer electrochemistry is described here. Both the rectification ratio and the response time of the device are programmable by controlling the gap distance of the thin-layer electrochemical cell, which is easily controlled using commercially available beads. One of the electrodes was modified using a ferrocene-terminated self-assembled monolayer to offer unidirectional charge transfers via soluble redox species. The thin-layer configuration provided enhanced mass transport, which was determined by the gap thickness. The device with the smallest gap thickness (∼4 μm) showed an unprecedented, high rectification ratio (up to 160) with a fast response time in a two-terminal configuration using conventional electronics.

The effects of layering in ferroelectric Si-doped HfO{sub 2} thin films

DOE Office of Scientific and Technical Information (OSTI.GOV)

Lomenzo, Patrick D.; Nishida, Toshikazu, E-mail: nishida@ufl.edu; Takmeel, Qanit

2014-08-18

Atomic layer deposited Si-doped HfO{sub 2} thin films approximately 10 nm thick are deposited with various Si-dopant concentrations and distributions. The ferroelectric behavior of the HfO{sub 2} thin films are shown to be dependent on both the Si mol. % and the distribution of Si-dopants. Metal-ferroelectric-insulator-semiconductor capacitors are shown to exhibit a tunable remanent polarization through the adjustment of the Si-dopant distribution at a constant Si concentration. Inhomogeneous layering of Si-dopants within the thin films effectively lowers the remanent polarization. A pinched hysteresis loop is observed for higher Si-dopant concentrations and found to be dependent on the Si layering distribution.

Can shallow-layer measurements at a single location be used to predict deep soil water storage at the slope scale?

NASA Astrophysics Data System (ADS)

Gao, Lei; Lv, Yujuan; Wang, Dongdong; Tahir, Muhammad; Peng, Xinhua

2015-12-01

Knowing the amount of soil water storage (SWS) in agricultural soil profiles is important for understanding physical, chemical, and biological soil processes. However, measuring the SWS in deep soil layers is more expensive and time consuming than in shallower layers. Whether deep SWS can be predicted from shallow-layer measurements through temporal stability analysis (TSA) remains unclear. To address this issue, the soil water content was measured at depths of 0-1.6 m (0.2-m depth intervals) at 79 locations along an agricultural slope on 28 occasions between July 2013 and October 2014. SWSs values were then calculated for the 0-0.4, 0.4-0.8, 0.8-1.2, 1.2-1.6, and 0-1.6 m soil layers. The SWS exhibited strong temporal stability, with mean Spearman's ranking coefficients (rs) of 0.83, 0.92, 0.83, and 0.79 in the 0-0.4, 0.4-0.8, 0.8-1.2, and 1.2-1.6 m soil layers, respectively. As expected, the most temporally stable location (MTSL1) accurately predicted the average SWS of the corresponding soil layer, and the values of absolute bias relative to mean (ARB) were lower than 3% for all of the investigated soil layers. Using TSA, deep-layer SWS information could be predicted using a single-location measurement in the 0-0.4 m soil layer. The mean ARB values between the observed and predicted mean SWS values were 2.9%, 4.3%, 3.9%, and 2.7% in the 0.4-0.8, 0.8-1.2, 1.2-1.6, and 0-1.6 m soil layers, respectively. The prediction accuracy of the spatial distribution generally decreased with increasing depth, with linear determination coefficients (R2) of 0.93, 0.79, 0.72, and 0.84 for the four soil layers, respectively. The proposed method could further expand the application of the temporal stability technique in the estimation of SWS.

NMR of thin layers using a meanderline surface coil

DOEpatents

Cowgill, Donald F.

2001-01-01

A miniature meanderline sensor coil which extends the capabilities of nuclear magnetic resonance (NMR) to provide analysis of thin planar samples and surface layer geometries. The sensor coil allows standard NMR techniques to be used to examine thin planar (or curved) layers, extending NMRs utility to many problems of modern interest. This technique can be used to examine contact layers, non-destructively depth profile into films, or image multiple layers in a 3-dimensional sense. It lends itself to high resolution NMR techniques of magic angle spinning and thus can be used to examine the bonding and electronic structure in layered materials or to observe the chemistry associated with aging coatings. Coupling this sensor coil technology with an arrangement of small magnets will produce a penetrator probe for remote in-situ chemical analysis of groundwater or contaminant sediments. Alternatively, the sensor coil can be further miniaturized to provide sub-micron depth resolution within thin films or to orthoscopically examine living tissue. This thin-layer NMR technique using a stationary meanderline coil in a series-resonant circuit has been demonstrated and it has been determined that the flat meanderline geometry has about he same detection sensitivity as a solenoidal coil, but is specifically tailored to examine planar material layers, while avoiding signals from the bulk.

Effect of processing parameters on microstructure of MoS{sub 2} ultra-thin films synthesized by chemical vapor deposition method

DOE Office of Scientific and Technical Information (OSTI.GOV)

Song, Yang; You, Suping; Sun, Kewei

2015-06-15

MoS{sub 2} ultra-thin layers are synthesized using a chemical vapor deposition method based on the sulfurization of molybdenum trioxide (MoO{sub 3}). The ultra-thin layers are characterized by X-ray diffraction (XRD), photoluminescence (PL) spectroscopy and atomic force microscope (AFM). Based on our experimental results, all the processing parameters, such as the tilt angle of substrate, applied voltage, heating time and the weight of source materials have effect on the microstructures of the layers. In this paper, the effects of such processing parameters on the crystal structures and morphologies of the as-grown layers are studied. It is found that the film obtainedmore » with the tilt angle of 0.06° is more uniform. A larger applied voltage is preferred to the growth of MoS{sub 2} thin films at a certain heating time. In order to obtain the ultra-thin layers of MoS{sub 2}, the weight of 0.003 g of source materials is preferred. Under our optimal experimental conditions, the surface of the film is smooth and composed of many uniformly distributed and aggregated particles, and the ultra-thin MoS{sub 2} atomic layers (1∼10 layers) covers an area of more than 2 mm×2 mm.« less

[Effects of snow pack on soil nitrogen transformation enzyme activities in a subalpine Abies faxioniana forest of western Sichuan, China].

PubMed

Xiong, Li; Xu, Zhen-Feng; Wu, Fu-Zhong; Yang, Wan-Qin; Yin, Rui; Li, Zhi-Ping; Gou, Xiao-Lin; Tang, Shi-Shan

2014-05-01

This study characterized the dynamics of the activities of urease, nitrate reductase and nitrite reductase in both soil organic layer and mineral soil layer under three depths of snow pack (deep snowpack, moderate snowpack and shallow snowpack) over the three critical periods (snow formed period, snow stable period, and snow melt period) in the subalpine Abies faxoniana forest of western Sichuan in the winter of 2012 and 2013. Throughout the winter, soil temperature under deep snowpack increased by 46.2% and 26.2%, respectively in comparison with moderate snowpack and shallow snowpack. In general, the three nitrogen-related soil enzyme activities under shallow snowpack were 0.8 to 3.9 times of those under deep snowpack during the winter. In the beginning and thawing periods of seasonal snow pack, shallow snowpack significantly increased the activities of urease, nitrate and nitrite reductase enzyme in both soil organic layer and mineral soil layer. Although the activities of the studied enzymes in soil organic layer and mineral soil layer were observed to be higher than those under deep- and moderate snowpacks in deep winter, no significant difference was found under the three snow packs. Meanwhile, the effects of snowpack on the activities of the measured enzymes were related with season, soil layer and enzyme type. Significant variations of the activities of nitrogen-related enzymes were found in three critical periods over the winter, and the three measured soil enzymes were significantly higher in organic layer than in mineral layer. In addition, the activities of the three measured soil enzymes were closely related with temperature and moisture in soils. In conclusion, the decrease of snow pack induced by winter warming might increase the activities of soil enzymes related with nitrogen transformation and further stimulate the process of wintertime nitrogen transformation in soils of the subalpine forest.

The properties of plasma-enhanced atomic layer deposition (ALD) ZnO thin films and comparison with thermal ALD

NASA Astrophysics Data System (ADS)

Kim, Doyoung; Kang, Hyemin; Kim, Jae-Min; Kim, Hyungjun

2011-02-01

Zinc oxide (ZnO) thin films were prepared by plasma-enhanced atomic layer deposition (PE-ALD) using oxygen plasma as a reactant and the properties were compared with those of thermal atomic layer deposition (TH-ALD) ZnO thin films. While hexagonal wurzite phase with preferential (0 0 2) orientation was obtained for both cases, significant differences were observed in various aspects of film properties including resistivity values between these two techniques. Photoluminescence (PL) measurements have shown that high resistivity of PE-ALD ZnO thin films is due to the oxygen interstitials at low growth temperature of 200 °C, whose amount decreases with increasing growth temperature. Thin film transistors (TFT) using TH- and PE-ALD ZnO as an active layer were also fabricated and the device properties were evaluated comparatively.

Laser readable thermoluminescent radiation dosimeters and methods for producing thereof

DOEpatents

Braunlich, P.F.; Tetzlaff, W.

1989-04-25

Thin layer thermoluminescent radiation dosimeters for use in laser readable dosimetry systems, and methods of fabricating such thin layer dosimeters are disclosed. The thin layer thermoluminescent radiation dosimeters include a thin substrate made from glass or other inorganic materials capable of withstanding high temperatures and high heating rates. A thin layer of a thermoluminescent phosphor material is heat bonded to the substrate using an inorganic binder such as glass. The dosimeters can be mounted in frames and cases for ease in handling. Methods of the invention include mixing a suitable phosphor composition and binder, both being in particulate or granular form. The mixture is then deposited onto a substrate such as by using mask printing techniques. The dosimeters are thereafter heated to fuse and bond the binder and phosphor to the substrate. 34 figs.

Fermi level de-pinning of aluminium contacts to n-type germanium using thin atomic layer deposited layers

DOE Office of Scientific and Technical Information (OSTI.GOV)

Gajula, D. R., E-mail: dgajula01@qub.ac.uk; Baine, P.; Armstrong, B. M.

Fermi-level pinning of aluminium on n-type germanium (n-Ge) was reduced by insertion of a thin interfacial dielectric by atomic layer deposition. The barrier height for aluminium contacts on n-Ge was reduced from 0.7 eV to a value of 0.28 eV for a thin Al{sub 2}O{sub 3} interfacial layer (∼2.8 nm). For diodes with an Al{sub 2}O{sub 3} interfacial layer, the contact resistance started to increase for layer thicknesses above 2.8 nm. For diodes with a HfO{sub 2} interfacial layer, the barrier height was also reduced but the contact resistance increased dramatically for layer thicknesses above 1.5 nm.

Self-assembled three-dimensional and compressible interdigitated thin-film supercapacitors and batteries

PubMed Central

Nyström, Gustav; Marais, Andrew; Karabulut, Erdem; Wågberg, Lars; Cui, Yi; Hamedi, Mahiar M.

2015-01-01

Traditional thin-film energy-storage devices consist of stacked layers of active films on two-dimensional substrates and do not exploit the third dimension. Fully three-dimensional thin-film devices would allow energy storage in bulk materials with arbitrary form factors and with mechanical properties unique to bulk materials such as compressibility. Here we show three-dimensional energy-storage devices based on layer-by-layer self-assembly of interdigitated thin films on the surface of an open-cell aerogel substrate. We demonstrate a reversibly compressible three-dimensional supercapacitor with carbon nanotube electrodes and a three-dimensional hybrid battery with a copper hexacyanoferrate ion intercalating cathode and a carbon nanotube anode. The three-dimensional supercapacitor shows stable operation over 400 cycles with a capacitance of 25 F g−1 and is fully functional even at compressions up to 75%. Our results demonstrate that layer-by-layer self-assembly inside aerogels is a rapid, precise and scalable route for building high-surface-area 3D thin-film devices. PMID:26021485

Thin film electronic devices with conductive and transparent gas and moisture permeation barriers

DOEpatents

Simpson, Lin Jay

2013-12-17

A thin film stack (100, 200) is provided for use in electronic devices such as photovoltaic devices. The stack (100, 200) may be integrated with a substrate (110) such as a light transmitting/transmissive layer. A electrical conductor layer (120, 220) is formed on a surface of the substrate (110) or device layer such as a transparent conducting (TC) material layer (120,220) with pin holes or defects (224) caused by manufacturing. The stack (100) includes a thin film (130, 230) of metal that acts as a barrier for environmental contaminants (226, 228). The metal thin film (130,230) is deposited on the conductor layer (120, 220) and formed from a self-healing metal such as a metal that forms self-terminating oxides. A permeation plug or block (236) is formed in or adjacent to the thin film (130, 230) of metal at or proximate to the pin holes (224) to block further permeation of contaminants through the pin holes (224).

Space Weathering of Olivine in Lunar Soils: A Comparison to Itokawa Regolith Samples

NASA Technical Reports Server (NTRS)

Keller, L. P.; Berger, E. L.

2014-01-01

Regolith particles from airless bodies preserve a record of the space weathering processes that occurred during their surface exposure history. These processes have major implications for interpreting remote-sensing data from airless bodies. Solar wind irradiation effects occur in the rims of exposed grains, and impact processes result in the accumulation of vapordeposited elements and other surface-adhering materials. The grains returned from the surface of Itokawa by the Hayabusa mission allow the space weathering "style" of a chondritic, asteroidal "soil" to be compared to the lunar case. Here, we present new studies of space-weathered olivine grains from lunar soils, and compare these results to olivine grains from Itokawa. Samples and Methods: We analyzed microtome thin sections of olivine grains from the 20-45 micron fractions of three lunar soils: 71061, 71501 and 10084 (immature, submature and mature, respectively). Imaging and analytical data were obtained using a JEOL 2500SE 200kV field-emission scanning-transmission electron microscope equipped with a thin-window energy-dispersive x-ray spectrometer. Similar analyses were obtained from three Hayabusa olivine grains. Results and Discussion: We observed lunar grains showing a range of solar flare track densities (from <10(exp 9) to approx.10(exp 12)/sq cm). The lunar olivines all show disordered, highly strained, nanocrystalline rims up to 150-nm thick. The disordered rim thickness is positively correlated with solar flare track density. All of the disordered rims are overlain by a Si-rich amorphous layer, ranging up to 50-nm thick, enriched in elements that are not derived from the host olivine (e.g., Ca, Al, and Ti). The outmost layer represents impact-generated vapor deposits typically observed on other lunar soil grains. The Hayabusa olivine grains show track densities <10(exp 10)/sq cm and display disordered rims 50- to 100-nm thick. The track densities are intermediate to those observed in olivines in immature and submature lunar soils and indicate surface exposures of approx. 10(exp 5) years. The outermost few nanometers of the disordered rims on Hayabusa olivines are more Si-rich and Mg- and Fe-depleted relative to the cores of the grains and likely represent a minor accumulation of impact-generated vapors or sputter deposits. Nanophase Fe metal particles are less abundant in the Hayabusa rims compared to the rims on lunar grains. Conclusions: The Hayabusa and lunar olivine grain rims have widths and microstructures consistent with formation from atomic displacement damage from solar wind ions. The space weathering features in the Hayabusa grains are similar to those observed in olivines from immature to submature lunar soils. A major difference, however, is that the Hayabusa grains appear to lack the hypervelocity impact products (melt spherules, thick vapor deposits, and abundant nanophase Fe metal particles) that are common in lunar soil grains with a similar exposure history.

Fabrication of read-only type triple-layered disc

NASA Astrophysics Data System (ADS)

Yang, Huei Wen; Jeng, Tzuan Ren; Yen, Wen Hsin; Chan, Rong Po; Shin, Kuo Ding; Huang, Der Ray

2003-06-01

The approach to increase optical recording density has become very popular research subject in these years. One direct and effective method is to increase the recording layer stack number. That is to say, to add one more recording layer can get one more recording capacity. In this paper, we will propose a new method for manufacturing read only type multi-layered disc. The process is described in the following. This first recorded data layer (called L0) still follows the traditional DVD disc manufacturing process. We obtain the polycarbonate substrate by replicating from Ni stamper. Then polycarbonate substrate is sputtered thin silicon film for semi-reflection layer. As for second layer (L1) and even more layer (Ln-1) producing, one special kind of duplication (called SKD) method is proposed. The duplication (or replication) source of second or nth recorded data is not only limited from Ni stamper. Even polycarbonate or PMMA substrate has recording data are also acceptable sources. At next step, the duplication source is deposited by thin gold film. Then we apply spin coating to bond the first layer (L0) substrate and second layer (L1) duplication source by choosing suitable UV curing glue. After being emitted by UV lamp for several seconds, we can easily separate the duplication source of second layer (L1) from (L0) substrate. Then we find the thin second data layer (L1) is replicated and stacks upon the first layer. On the same way, we sputter thin AgTi layer on the thin second data layer for another semi- reflective layer. By following the above manufacture step, we can produce more layers. In our experimental, we prepare triple layered read-only type disc. The total capacity is almost 12GB for one side of disc, and 24GB for two side of disc. The read-out intensity of laser from each data layer is expected to be similar. Thus we have designed particular reflectance and transmittance for each data layer by controlling the thickness of thin silicon film. We can verify our design by checking the focusing error signal in S-curve search of optical pickup head. The signal quality for each layer can be found from the signal eye pattern and jitter. For compatibility with present drive system, the requirement of the readout signal from each layer should be same as DVD or CD specification

Monsoon dependent ecosystems: Implications of the vertical distribution of soil moisture on land surface-atmosphere interactions

NASA Astrophysics Data System (ADS)

Sanchez-Mejia, Zulia M.

Uncertainty of predicted change in precipitation frequency and intensity motivates the scientific community to better understand, quantify, and model the possible outcome of dryland ecosystems. In pulse dependent ecosystems (i.e. monsoon driven) soil moisture is tightly linked to atmospheric processes. Here, I analyze three overarching questions; Q1) How does soil moisture presence or absence in a shallow or deep layer influence the surface energy budget and planetary boundary layer characteristics?, Q2) What is the role of vegetation on ecosystem albedo in the presence or absence of deep soil moisture?, Q3) Can we develop empirical relationships between soil moisture and the planetary boundary layer height to help evaluate the role of future precipitation changes in land surface atmosphere interactions? . To address these questions I use a conceptual framework based on the presence or absence of soil moisture in a shallow or deep layer. I define these layers by using root profiles and establish soil moisture thresholds for each layer using four years of observations from the Santa Rita Creosote Ameriflux site. Soil moisture drydown curves were used to establish the shallow layer threshold in the shallow layer, while NEE (Net Ecosystem Exchange of carbon dioxide) was used to define the deep soil moisture threshold. Four cases were generated using these thresholds: Case 1, dry shallow layer and dry deep layer; Case 2, wet shallow layer and dry deep layer; Case 3, wet shallow layer and wet deep layer, and Case 4 dry shallow and wet deep layer. Using this framework, I related data from the Ameriflux site SRC (Santa Rita Creosote) from 2008 to 2012 and from atmospheric soundings from the nearby Tucson Airport; conducted field campaigns during 2011 and 2012 to measure albedo from individual bare and canopy patches that were then evaluated in a grid to estimate the influence of deep moisture on albedo via vegetation cover change; and evaluated the potential of using a two-layer bucket model and empirical relationships to evaluate the link between deep soil moisture and the planetary boundary layer height under changing precipitation regime. My results indicate that (1) the presence or absence of water in two layers plays a role in surface energy dynamics, (2) soil moisture presence in the deep layer is linked with decreased ecosystem albedo and planetary boundary layer height, (3) deep moisture sustains vegetation greenness and decreases albedo, and (4) empirical relationships are useful in modeling planetary boundary layer height from dryland ecosystems. Based on these results we argue that deep soil moisture plays an important role in land surface-atmosphere interactions.

Insight into the epitaxial encapsulation of Pd catalysts in an oriented metalloporphyrin network thin film for tandem catalysis.

PubMed

Vohra, M Ismail; Li, De-Jing; Gu, Zhi-Gang; Zhang, Jian

2017-06-14

A palladium catalyst (Pd-Cs) encapsulated metalloporphyrin network PIZA-1 thin film with bifunctional properties has been developed through a modified epitaxial layer-by-layer encapsulation approach. Combining the oxidation activity of Pd-Cs and the acetalization activity of the Lewis acidic sites in the PIZA-1 thin film, this bifunctional catalyst of the Pd-Cs@PIZA-1 thin film exhibits a good catalytic activity in a one-pot tandem oxidation-acetalization reaction. Furthermore, the surface components can be controlled by ending the top layer with different precursors in the thin film preparation procedures. The catalytic performances of these thin films with different surface composites were studied under the same conditions, which showed different reaction conversions. The result revealed that the surface component can influence the catalytic performance of the thin films. This epitaxial encapsulation offers a good understanding of the tandem catalysis for thin film materials and provides useful guidance to develop new thin film materials with catalytic properties.

Vertical distribution of bacterial community is associated with the degree of soil organic matter decomposition in the active layer of moist acidic tundra.

PubMed

Kim, Hye Min; Lee, Min Jin; Jung, Ji Young; Hwang, Chung Yeon; Kim, Mincheol; Ro, Hee-Myong; Chun, Jongsik; Lee, Yoo Kyung

2016-11-01

The increasing temperature in Arctic tundra deepens the active layer, which is the upper layer of permafrost soil that experiences repeated thawing and freezing. The increasing of soil temperature and the deepening of active layer seem to affect soil microbial communities. Therefore, information on soil microbial communities at various soil depths is essential to understand their potential responses to climate change in the active layer soil. We investigated the community structure of soil bacteria in the active layer from moist acidic tundra in Council, Alaska. We also interpreted their relationship with some relevant soil physicochemical characteristics along soil depth with a fine scale (5 cm depth interval). The bacterial community structure was found to change along soil depth. The relative abundances of Acidobacteria, Gammaproteobacteria, Planctomycetes, and candidate phylum WPS-2 rapidly decreased with soil depth, while those of Bacteroidetes, Chloroflexi, Gemmatimonadetes, and candidate AD3 rapidly increased. A structural shift was also found in the soil bacterial communities around 20 cm depth, where two organic (upper Oi and lower Oa) horizons are subdivided. The quality and the decomposition degree of organic matter might have influenced the bacterial community structure. Besides the organic matter quality, the vertical distribution of bacterial communities was also found to be related to soil pH and total phosphorus content. This study showed the vertical change of bacterial community in the active layer with a fine scale resolution and the possible influence of the quality of soil organic matter on shaping bacterial community structure.

Use of a thin-layer technique in thyroid fine needle aspiration.

PubMed

Malle, Despoina; Valeri, Rosalia-Maria; Pazaitou-Panajiotou, Kalliopi; Kiziridou, Anastasia; Vainas, Iraklis; Destouni, Charicleia

2006-01-01

To investigate the efficacy of the ThinPrep Processor (Cytyc Corporation, Boxborough, Massachusetts, U.S.A) in fine needle aspiration (FNA) of thyroid gland lesions. This study included 459 thyroid FNA specimens obtained from patients who came to our endocrinology department with various thyroid disorders over 3 years. The cytologic material was prepared using both the conventional and ThinPrep method in the first 2 years (285 cases), while in the last one only the ThinPrep method was used (1 74 cases). The smears were stained using a modified Papanicolaou procedure and May-Grünwald-Giemsa stain. Immunocytochemistry was performed on thin-layer slides using specific monoclonal antibodies when needed. Thin-layer and direct smear diagnoses were compared with the final cytologic or histologic diagnoses, when available. Our cases included 279 adenomatoid nodules, 15 cases of Hashimoto thyroiditis, 45 follicular neoplasms, 14 Hürthle cell tumors, 58 papillary carcinomas and 1 5 anaplastic carcinomas. Thin-layer preparations showed a trend toward a lower proportion of inadequate specimens and a lower false negative rate. Cytomorphologic features showed some differences between the 2 methods. Colloid was less frequently observed on ThinPrep slides, while nuclear detail and micronucleoli were more easily detected with this technique. Moreover, ThinPrep appeared to be the appropriate method for the use of ancillary techniques in suspicious cases. Thin-layer cytology improves the diagnostic accuracy of thyroid FNA and offers the possibility of performing new techniques, such as immunocytochemistry, on the same sample in order to detect malignancy as well as the type and origin of thyroid gland neoplasms.

Photovoltaic sub-cell interconnects

DOE Office of Scientific and Technical Information (OSTI.GOV)

van Hest, Marinus Franciscus Antonius Maria; Swinger Platt, Heather Anne

2017-05-09

Photovoltaic sub-cell interconnect systems and methods are provided. In one embodiment, a photovoltaic device comprises a thin film stack of layers deposited upon a substrate, wherein the thin film stack layers are subdivided into a plurality of sub-cells interconnected in series by a plurality of electrical interconnection structures; and wherein the plurality of electrical interconnection structures each comprise no more than two scribes that penetrate into the thin film stack layers.

Effect of atmospheric-pressure plasma treatment on the adhesion properties of a thin adhesive layer in a selective transfer process

NASA Astrophysics Data System (ADS)

Yoon, Min-Ah; Kim, Chan; Hur, Min; Kang, Woo Seok; Kim, Jaegu; Kim, Jae-Hyun; Lee, Hak-Joo; Kim, Kwang-Seop

2018-01-01

The adhesion between a stamp and thin film devices is crucial for their transfer on a flexible substrate. In this paper, a thin adhesive silicone layer on the stamp was treated by atmospheric pressure plasma to locally control the adhesion strength for the selective transfer. The adhesion strength of the silicone layer was significantly reduced after the plasma treatment, while its surface energy was increased. To understand the inconsistency between the adhesion strength and surface energy changes, the surface properties of the silicone layer were characterized using nanoindentation and X-ray photoelectron spectroscopy. These techniques revealed that a thin, hard, silica-like layer had formed on the surface from plasma-enhanced oxidation. This layer played an important role in decreasing the contact area and increasing the interfacial slippage, resulting in decreased adhesion. As a practical application, the transfer process was demonstrated on GaN LEDs that had been previously delaminated by a laser lift-off (LLO) process. Although the LEDs were not transferred onto the treated adhesive layer due to the reduced adhesion, the untreated adhesive layer could readily pick up the LEDs. It is expected that this simple method of controlling the adhesion of a stamp with a thin adhesive layer would enable a continuous, selective and large-scale roll-to-roll selective transfer process and thereby advance the development of flexible, stretchable and wearable electronics.

Pleistocene ice-rich yedoma in Interior Alaska

NASA Astrophysics Data System (ADS)

Kanevskiy, M. Z.; Shur, Y.; Jorgenson, T. T.; Sturm, M.; Bjella, K.; Bray, M.; Harden, J. W.; Dillon, M.; Fortier, D.; O'Donnell, J.

2011-12-01

Yedoma, or the ice-rich syngenetic permafrost with large ice wedges, widely occurs in parts of Alaska that were unglaciated during the last glaciation including Interior Alaska, Foothills of Brooks Range and Seward Peninsula. A thick layer of syngenetic permafrost was formed by simultaneous accumulation of silt and upward permafrost aggradation. Until recently, yedoma has been studied mainly in Russia. In Interior Alaska, we have studied yedoma at several field sites (Erickson Creek area, Boot Lake area, and several sites around Fairbanks, including well-known CRREL Permafrost tunnel). All these locations are characterized by thick sequences of ice-rich silt with large ice wedges up to 30 m deep. Our study in the CRREL Permafrost tunnel and surrounding area revealed a yedoma section up to 18 m thick, whose formation began about 40,000 yr BP. The volume of wedge-ice (about 10-15%) is not very big in comparison with other yedoma sites (typically more than 30%), but soils between ice wedges are extremely ice-rich - an average value of gravimetric moisture content of undisturbed yedoma silt with micro-cryostructures is about 130%. Numerous bodies of thermokarst-cave ice were detected in the tunnel. Geotechnical investigations along the Dalton Highway near Livengood (Erickson Creek area) provided opportunities for studies of yedoma cores from deep boreholes. The radiocarbon age of sediments varies from 20,000 to 45,000 yr BP. Most of soils in the area are extremely ice-rich. Thickness of ice-rich silt varies from 10 m to more than 26 m, and volume of wedge-ice reaches 35-45%. Soil between ice wedges has mainly micro-cryostructures and average gravimetric moisture content from 80% to 100%. Our studies have shown that the top part of yedoma in many locations was affected by deep thawing during the Holocene, which resulted in formation of the layer of thawed and refrozen soils up to 6 m thick on top of yedoma deposits. Thawing of the upper permafrost could be related to climate changes during Holocene or to wildfires, or both. The ice-poor layer of thawed and refrozen sediments (gravimetric moisture content usually does not exceed 40%) was encountered in many boreholes below the thin ice-rich intermediate layer (gravimetric moisture content usually exceeds 100%). These two layers separate ice wedges from the active layer and protect them from further thawing. Such structure of the upper permafrost at different yedoma sites of Interior Alaska can explain a relatively rare occurrence of surface features related to yedoma degradation such as thermokarst mounds and erosional gullies developed along ice wedges.

Study on the growth mechanism and optical properties of sputtered lead selenide thin films

NASA Astrophysics Data System (ADS)

Sun, Xigui; Gao, Kewei; Pang, Xiaolu; Yang, Huisheng; Volinsky, Alex A.

2015-11-01

Lead selenide thin films with different microstructure were deposited on Si (1 0 0) substrates using magnetron sputtering at 50 °C, 150 °C and 250 °C, respectively. The crystal structure of the sputtered PbSe thin films varies from amorphous crystalline to columnar grain, and then to double-layer (nano-crystalline layer and columnar grain layer) structure as the deposition temperature increases, which is due to the dominating growth mode of the thin films changes from Frank-van der Merwe (or layer-by-layer) growth mode at 50 °C to Volmer-Weber (or 3D island) growth mode at 150 °C, and then to Stranski-Krastanow (or 3D island-on-wetting-layer) growth mode at 250 °C. The growth mechanism of the sputtered PbSe thin films is mainly dominated by the surface and strain energy contributions. Moreover, the strain energy contribution is more prominent when the deposition temperature is less than 180 °C, while, the surface energy contribution is more prominent when the deposition temperature is higher than 180 °C. The absorption spectra of the sputtered PbSe thin films are in 3.1-5 μm range. Besides, the sputtered PbSe thin film prepared at 250 °C has two different optical band gaps due to its unique double-layer structure. According to the theoretical calculation results, the variation of the band gap with the deposition temperature is determined by the shift of the valence band maximum with the lattice constant.

Synthesis and characterization of Zn(O,OH)S and AgInS2 layers to be used in thin film solar cells

NASA Astrophysics Data System (ADS)

Vallejo, W.; Arredondo, C. A.; Gordillo, G.

2010-11-01

In this paper AgInS2 and Zn(O,OH)S thin films were synthesized and characterized. AgInS2 layers were grown by co-evaporation from metal precursors in a two-step process, and, Zn(O,OH)S thin films were deposited from chemical bath containing thiourea, zinc acetate, sodium citrate and ammonia. X-ray diffraction measurements indicated that AgInS2 thin films grown with chalcopyrite structure, and the as-grown Zn(O,OH)S thin films were polycrystalline. It was also found that the AgInS2 films presented p-type conductivity, a high absorption coefficient (greater than 104 cm-1) and energy band-gap Eg of about 1.95 eV, Zn(O,OH),S thin films presented Eg of about 3.89 eV. Morphological analysis showed that under this synthesis conditions Zn(O,OH),S thin films coated uniformly the absorber layer. Additionally, the Zn(O,OH)S kinetic growth on AgInS2 layer was studied also. Finally, the results suggest that these layers possibly could be used in one-junction solar cells and/or as top cell in a tandem solar cell.

Deformation behavior of coherently strained InAs/GaAs(111)A heteroepitaxial systems: Theoretical calculations and experimental measurements

NASA Astrophysics Data System (ADS)

Zepeda-Ruiz, Luis A.; Pelzel, Rodney I.; Nosho, Brett Z.; Weinberg, W. Henry; Maroudas, Dimitrios

2001-09-01

A comprehensive, quantitative analysis is presented of the deformation behavior of coherently strained InAs/GaAs(111)A heteroepitaxial systems. The analysis combines a hierarchical theoretical approach with experimental measurements. Continuum linear elasticity theory is linked with atomic-scale calculations of structural relaxation for detailed theoretical studies of deformation in systems consisting of InAs thin films on thin GaAs(111)A substrates that are mechanically unconstrained at their bases. Molecular-beam epitaxy is used to grow very thin InAs films on both thick and thin GaAs buffer layers on epi-ready GaAs(111)A substrates. The deformation state of these samples is characterized by x-ray diffraction (XRD). The interplanar distances of thin GaAs buffer layers along the [220] and [111] crystallographic directions obtained from the corresponding XRD spectra indicate clearly that thin buffer layers deform parallel to the InAs/GaAs(111)A interfacial plane, thus aiding in the accommodation of the strain induced by lattice mismatch. The experimental measurements are in excellent agreement with the calculated lattice interplanar distances and the corresponding strain fields in the thin mechanically unconstrained substrates considered in the theoretical analysis. Therefore, this work contributes direct evidence in support of our earlier proposal that thin buffer layers in layer-by-layer semiconductor heteroepitaxy exhibit mechanical behavior similar to that of compliant substrates [see, e.g., B. Z. Nosho, L. A. Zepeda-Ruiz, R. I. Pelzel, W. H. Weinberg, and D. Maroudas, Appl. Phys. Lett. 75, 829 (1999)].

Self-assembly of dodecaphenyl POSS thin films

NASA Astrophysics Data System (ADS)

Handke, Bartosz; Klita, Łukasz; Niemiec, Wiktor

2017-12-01

The self-assembly abilities of Dodecaphenyl Polyhedral Oligomeric Silsesquioxane thin films on Si(1 0 0) surfaces were studied. Due to their thermal properties - relatively low sublimation temperature and preservation of molecular structure - cage type silsesquioxanes are ideal material for the preparation of a thin films by Physical Vapor Deposition. The Ultra-High Vacuum environment and the deposition precision of the PVD method enable the study of early stages of thin film growth and its molecular organization. X-ray Reflectivity and Atomic Force Microscopy measurements allow to pursuit size-effects in the structure of thin films with thickness ranges from less than a single molecular layer up to several tens of layers. Thermal treatment of the thin films triggered phase change: from a poorly ordered polycrystalline film into a well-ordered multilayer structure. Self-assembly of the layers is the effect of the π-stacking of phenyl rings, which force molecules to arrange in a superlattice, forming stacks of alternating organic-inorganic layers.

Effect of Al doping on performance of ZnO thin film transistors

NASA Astrophysics Data System (ADS)

Dong, Junchen; Han, Dedong; Li, Huijin; Yu, Wen; Zhang, Shendong; Zhang, Xing; Wang, Yi

2018-03-01

In this work, we investigate the Aluminum-doped Zinc Oxide (AZO) thin films and their feasibility as the active layer for thin film transistors (TFTs). A comparison on performance is made between the AZO TFTs and ZnO TFTs. The electrical properties such as saturation mobility, subthreshold swing, and on-to-off current ratio are improved when AZO is utilized as the active layer. Oxygen component of the thin film materials indicates that Al is the suppressor for oxygen defect in active layer, which improves the subthreshold swing. Moreover, based on band structure analyzation, we observe that the carrier concentration of AZO is higher than ZnO, leading to the enhancement of saturation mobility. The microstructure of the thin films convey that the AZO films exhibit much smaller grain boundaries than ZnO films, which results in the lower off-state current and higher on-to-off current ratio of AZO TFTs. The AZO thin films show huge potential to be the active layer of TFTs.

Thin film photovoltaic device with multilayer substrate

DOEpatents

Catalano, Anthony W.; Bhushan, Manjul

1984-01-01

A thin film photovoltaic device which utilizes at least one compound semiconductor layer chosen from Groups IIB and VA of the Periodic Table is formed on a multilayer substrate The substrate includes a lowermost support layer on which all of the other layers of the device are formed. Additionally, an uppermost carbide or silicon layer is adjacent to the semiconductor layer. Below the carbide or silicon layer is a metal layer of high conductivity and expansion coefficient equal to or slightly greater than that of the semiconductor layer.

Geohydrology of the glacial-outwash aquifer in the Baldwinsville area, Seneca River, Onondaga County, New York

USGS Publications Warehouse

Pagano, Timothy S.; Terry, David B.; Ingram, Arlynn W.

1986-01-01

Seven sheets of map data comprise this geohydrologic report. Sheet 1, surficial geology, illustrates the distribution of: open water areas; artificial fill; made land; urban land; alluvial silt and sand; alluvial sand and gravel; peat, marl, muck and clay; lake silt and/or clay; delta sand and gravel; beach sand and gravel; outwash sand and gravel; ice contact sand and ground; thick till cover bedrock; and thin till over bedrock over the Baldwinsville Area. Sheet 2, geologic sections, shows the layering of the aforementioned components below the surface layer. Sheet 3 illustrates the water infiltration of soil zone. Sheet 4 depicts the aquifer thickness. Sheet 5 illustrates the potentiometric surface, and Sheet 6 the well yield. Finally, Sheet 7 shows the land use in the region, specifically: industrial and extractive; commercial and services; transportation; farmland; forestland; residential; open public land; and water and wetlands. (Lantz-PTT)

Analysis of the Control Factors of Groundwater Petroleum Hydrocarbons Contamination in a City’s West Part

NASA Astrophysics Data System (ADS)

Sun, L. H.; Ma, Z. M.; Liu, Z. W.

2018-05-01

Based on study of the hydrogeological condition and the characteristics of petroleum hydrocarbons pollution in karst groundwater, an oil refinery located in western part of a certain city is chosen as the study site to have an analysis on the control factors of groundwater petroleum hydrocarbons contamination. The study result shows that the control factors of groundwater petroleum hydrocarbons contamination are hydrogeological condition and biodegradation. The soil layer of Quaternary is very thin, the limestone is exposed in the surface, which makes the petroleum hydrocarbons easy to permeate into the water bearing layer. Karst-fractured zone in aquifer determines the migration way of petroleum hydrocarbons to be convection, but the magmatic rock in northern part has certain blocking effect on the migration of petroleum hydrocarbons. Biodegradation makes both the contamination plume area of petroleum hydrocarbons and the content of petroleum hydrocarbons decreased.

Controlled placement and orientation of nanostructures

DOEpatents

Zettl, Alex K; Yuzvinsky, Thomas D; Fennimore, Adam M

2014-04-08

A method for controlled deposition and orientation of molecular sized nanoelectromechanical systems (NEMS) on substrates is disclosed. The method comprised: forming a thin layer of polymer coating on a substrate; exposing a selected portion of the thin layer of polymer to alter a selected portion of the thin layer of polymer; forming a suspension of nanostructures in a solvent, wherein the solvent suspends the nanostructures and activates the nanostructures in the solvent for deposition; and flowing a suspension of nanostructures across the layer of polymer in a flow direction; thereby: depositing a nanostructure in the suspension of nanostructures only to the selected portion of the thin layer of polymer coating on the substrate to form a deposited nanostructure oriented in the flow direction. By selectively employing portions of the method above, complex NEMS may be built of simpler NEMSs components.

In situ measurement of solution concentrations and fluxes of sulfonamides and trimethoprim antibiotics in soils using o-DGT.

PubMed

Chen, Chang-Er; Chen, Wei; Ying, Guang-Guo; Jones, Kevin C; Zhang, Hao

2015-01-01

Techniques, such as Diffusive Gradients in Thin-films (DGT), which either minimally disturb the soil or perturb it in a controlled way are most likely to provide information relevant to toxicity. Herein, we report the first use of DGT for organics (o-DGT) in soil systems to gain insight into the mobility and lability of four antibiotics-sulfamethoxazole (SMX), sulfamethazine (SMZ), and sulfadimethoxine (SDM), trimethoprim (TMP) in soil. In experiments where the same known amount of antibiotics were spiked into the soil, which was then further modified with NaOH, NaCl or dissolved organic matter, directly measured soil solution concentrations (Csoln) of these antibiotics were in the order: SMX>SMZ≈SDM>TMP. The R values (ratio of concentrations measured by o-DGT and directly in solution) were 0.56, 0.41, 0.40 and 0.28, respectively, indicating that the removal of these antibiotics from the solution can be to some extent resupplied by release from the solid phase. The nonlinearity of the relationship between o-DGT fluxes and the reciprocal of diffusive layer thickness (Δg) also suggested that soil solution concentrations were only partially sustained by the solid phase. The potential fluxes of these antibiotics in this soil were 5.4, 3.6, 2.4, and 1.2 pg/cm(2)/s for SMX, SMZ, SDM, and TMP, respectively. o-DGT is a promising tool for understanding the fate and behaviour of polar organic chemicals in soil, and it potentially provides an in situ approach for assessing their bioavailability. Copyright © 2014 Elsevier B.V. All rights reserved.

Predicting Soil Strength in Terms of Cone Index and California Bearing Ratio for Trafficability

DTIC Science & Technology

2016-03-01

conditions, however, soil strength will be a key factor. The Wet- Slippery conditions are considered when the top layer has reached a point of...the soil . Modeling moisture content of a soil in a layered system can be conducted using a finite difference water budget model illustrated in...Figure 2 (Sellers et al. 1986). Figure 2 shows how flow Q through the soil layer ij is modeled. In general, saturation of layer Qi due to rainfall is

Effect of inserting a hole injection layer in organic light-emitting diodes: A numerical approach

NASA Astrophysics Data System (ADS)

Lee, Hyeongi; Hwang, Youngwook; Won, Taeyoung

2015-01-01

For investigating the effect of inserting a hole injection layer (HIL), we carried out a computational study concerning organic light-emitting diodes (OLEDs) that had a thin CuPc layer as the hole injection layer. We used S-TAD (2, 2', 7, 7'-tetrakis-(N, Ndiphenylamino)-9, 9-spirobifluoren) for the hole transfer layer, S-DPVBi (4, 4'-bis (2, 2'-diphenylvinyl)-1, 1'-spirobiphenyl) for the emission layer and Alq3 (Tris (8-hyroxyquinolinato) aluminium) for the electron transfer layer. This tri-layer device was compared with four-layer devices. To this tri-layer device, we added a thin CuPc layer, which had a 5.3 eV highest occupied molecular orbital (HOMO) level and a 3.8 eV lowest unoccupied molecular orbital (LUMO) level, as a hole injection layer, and we chose this device for Device A. Also, we varied the LUMO level or the HOMO level of the thin CuPc layer. These two devices were identified as Device C and Device D, respectively. In this paper, we simulated the carrier injection, transport and recombination in these four devices. Thereby, we showed the effect of the HIL, and we demonstrated that the characteristics of these devices were improved by adding a thin layer of CuPc between the anode and the HTL.

Depth profile of 236U/238U in soil samples in La Palma, Canary Islands

PubMed Central

Srncik, M.; Steier, P.; Wallner, G.

2011-01-01

The vertical distribution of the 236U/238U isotopic ratio was investigated in soil samples from three different locations on La Palma (one of the seven Canary Islands, Spain). Additionally the 240Pu/239Pu atomic ratio, as it is a well establish tool for the source identification, was determined. The radiochemical procedure consisted of a U separation step by extraction chromatography using UTEVA® Resin (Eichrom Technologies, Inc.). Afterwards Pu was separated from Th and Np by anion exchange using Dowex 1x2 (Dow Chemical Co.). Furthermore a new chemical procedure with tandem columns to separate Pu and U from the matrix was tested. For the determination of the uranium and plutonium isotopes by alpha spectrometry thin sources were prepared by microprecipitation techniques. Additionally these fractions separated from the soil samples were measured by Accelerator Mass Spectrometry (AMS) to get information on the isotopic ratios 236U/238U, 240Pu/239Pu and 236U/239Pu, respectively. The 236U concentrations [atoms/g] in each surface layer (∼2 cm) were surprisingly high compared to deeper layers where values around two orders of magnitude smaller were found. Since the isotopic ratio 240Pu/239Pu indicated a global fallout signature we assume the same origin as the probable source for 236U. Our measured 236U/239Pu value of around 0.2 is within the expected range for this contamination source. PMID:21481502

Fabrication of ATO/Graphene Multi-layered Transparent Conducting Thin Films

NASA Astrophysics Data System (ADS)

Li, Na; Chen, Fei; Shen, Qiang; Wang, Chuanbin; Zhang, Lianmeng

2013-03-01

A novel transparent conducting oxide based on the ATO/graphene multi-layered thin films has been developed to satisfy the application of transparent conductive electrode in solar cells. The ATO thin films are prepared by pulsed laser deposition method with high quality, namely the sheet resistance of 49.5 Ω/sq and average transmittance of 81.9 %. The prepared graphene sheet is well reduced and shows atomically thin, spotty distributed appearance on the top of the ATO thin films. The XRD and optical micrographs are used to confirm the successfully preparation of the ATO/graphene multi-layered thin films. The Hall measurements and UV-Vis spectrophotometer are conducted to evaluate the sheet resistance and optical transmittance of the innovative structure. It is found that graphene can improve the electrical properties of the ATO thin films with little influence on the optical transmittance.

Degradation and adsorption of tralkoxydim in Chinese soils and water-sediment environments.

PubMed

Wu, Wen Zhu; Shan, Zheng Jun; Kong, De Yang; He, Jian

2017-06-01

Tralkoxydim is a cyclohexanedione herbicide primarily used for gramineous weed control in China. In this paper, we present results of a tralkoxydim laboratory environmental fate study characterizing its degradation, adsorption, and mobility behavior in three different soils and two water-sediment systems (river and lake) in China. Degradation half-life of tralkoxydim in soil under aerobic conditions was 5.1, 7.7, and 7.9 days in Jiangxi red soil, Taihu paddy soil, and Northeast China black soil, respectively. Under anaerobic and flooding conditions, half-life values were 6.2, 15.1, and 19.8 days for the same three soils, respectively. Soil pH was the major factor effecting tralkoxydim degradation. In the aerobic water-sediment experiments, tralkoxydim degraded faster in the river system (total system half-life 43.3 days) than the lake system (total system half-life 99.0 days). Correspondingly, its anaerobic degradation half-life values were 46.2 and 53.3 days for the river and lake systems, respectively. Tralkoxydim adsorption in the three soils was found to follow the empirical Freundlich isotherm. The adsorption coefficient (K d ) was 8.60, 1.00, and 1.57 for Jiangxi red soil, Taihu paddy soil, and Northeast China black soil, respectively. Soil pH was the major factor effecting tralkoxydim adsorption. Adsorption free energy change was less than 40 kJ mol -1 in all three soils, indicating a physical mechanism in the process. Thin-layer chromatography (TLC) tests showed that relative to the solvent transport to 11.5 cm, the travel distance of tralkoxydim was 8-10 cm in the three soils, corresponding Rf values at 0.05, 0.35, and 0.75 for Jiangxi red soil, Taihu paddy soil, and Northeast China black soil, respectively. Results of this work suggest that under alkaline conditions, tralkoxydim adsorption becomes smaller; thus, assessments on its mobility and potential groundwater impact should focus on these soil types.

Oriented conductive oxide electrodes on SiO2/Si and glass

DOEpatents

Jia, Quanxi; Arendt, Paul N.

2001-01-01

A thin film structure is provided including a silicon substrate with a layer of silicon dioxide on a surface thereof, and a layer of cubic oxide material deposited upon the layer of silicon dioxide by ion-beam-assisted-deposition, said layer of cubic oxide material characterized as biaxially oriented. Preferably, the cubic oxide material is yttria-stabilized zirconia. Additional thin layers of biaxially oriented ruthenium oxide or lanthanum strontium cobalt oxide are deposited upon the layer of yttria-stabilized zirconia. An intermediate layer of cerium oxide is employed between the yttria-stabilized zirconia layer and the lanthanum strontium cobalt oxide layer. Also, a layer of barium strontium titanium oxide can be upon the layer of biaxially oriented ruthenium oxide or lanthanum strontium cobalt oxide. Also, a method of forming such thin film structures, including a low temperature deposition of a layer of a biaxially oriented cubic oxide material upon the silicon dioxide surface of a silicon dioxide/silicon substrate is provided.

Damped response of shells by a constrained viscoelastic layer

NASA Technical Reports Server (NTRS)

El-Raheb, M.; Wagner, P.

1986-01-01

Vibration absorbers are introduced into an asymmetric configuration of thin cylinders and tori enclosing an acoustic medium. The absorbers consist of thin axial strips bonded to the cylinder with a thin viscoelastic layer. The constrained layer dissipates the energy of relative motions between strip and cylinder. The absorber is most effective on response modes with two or more circumferential waves. The use of transfer matrices is extended to the coupled cylinder-absorber system.

Photocurrent generation in SnO2 thin film by surface charged chemisorption O ions

NASA Astrophysics Data System (ADS)

Lee, Po-Ming; Liao, Ching-Han; Lin, Chia-Hua; Liu, Cheng-Yi

2018-06-01

We report a photocurrent generation mechanism in the SnO2 thin film surface layer by the charged chemisorption O ions on the SnO2 thin film surface induced by O2-annealing. A critical build-in electric field in the SnO2 surface layer resulted from the charged O ions on SnO2 surface prolongs the lifetime and reduces the recombination probability of the photo-excited electron-hole pairs by UV-laser irradiation (266 nm) in the SnO2 surface layer, which is the key for the photocurrent generation in the SnO2 thin film surface layer. The critical lifetime of prolonged photo-excited electron-hole pair is calculated to be 8.3 ms.

Multi-oxide active layer deposition using Applied Materials Pivot array coater for high-mobility metal oxide TFT

NASA Astrophysics Data System (ADS)

Park, Hyun Chan; Scheer, Evelyn; Witting, Karin; Hanika, Markus; Bender, Marcus; Hsu, Hao Chien; Yim, Dong Kil

2015-11-01

By controlling a thin indium tin oxide (ITO), indium zinc oxide interface layer between gate insulator and indium gallium zinc oxide (IGZO), the thin-film transistor (TFT) performance can reach higher mobility as conventional IGZO as well as superior stability. For large-area display application, Applied Materials static PVD array coater (Applied Materials GmbH & Co. KG, Alzenau, Germany) using rotary targets has been developed to enable uniform thin layer deposition in display industry. Unique magnet motion parameter optimization in Pivot sputtering coater is shown to provide very uniform thin ITO layer to reach TFT performance with high mobility, not only on small scale, but also on Gen8.5 (2500 × 2200 mm glass size) production system.

Augmentation of freeze-thaw cycles in the alpine soil triggered by the fire on the alpine slopes, Mount Shirouma-dake, northern Japanese Alps

NASA Astrophysics Data System (ADS)

Sasaki, A.; Suzuki, K.

2015-12-01

This is the continuous study to clarify the geo-environmental changes on the post-fire alpine slopes of Mount Shirouma-dake in the northern Japanese Alps. The fire occurred at May 9, 2009 on the alpine slopes of Mount Shirouma-dake, and the fire spread to the Pinus pumila communities and grasslands. Although the grass had a little damage by the fire, the P. pumila received nearly impact of the fire. In the P. pumila communities where the leaf burnt, forest floor is exposed and become easy to be affected by atmospheric condition such as rain, wind, snow, and etc. First, we illustrated a map of micro-landforms, based on geomorphological fieldworks. We observed these micro-landforms repeatedly for fifth years after the fire. As the results of the observation, it is clear that remarkable changes of these micro-landforms have not occurred but some litters on the forest-floor in the P. pumila communities are flushed out to surroundings. The litter layer on the forest-floor in the P. pumila communities were 3-4 cm thick in August of 2011, but it became 0.5 cm thick in September of 2014. The P. pumila communities established on the slopes consists of angular and sub-angular gravel with openwork texture, which are covered by thin soil layer. Therefore, it is necessary to pay attention to soil erosion following the outflow of the litter. In addition, we observe the ground temperature and soil moisture, under the fired P. pumila communities and the no fired P. pumila communities after the fire, to find influence of the fire. The ground temperature sensors were installed into at 1 cm, 10 cm, and 40 cm depth. The soil moisture sensors were installed into at 1 cm and 10 cm depth. The 1 cm depth of the soil on the post-fire slopes, diurnal freeze-thaw cycles occurred in October and November of 2011, 2012, 2013, and 2014 but it had not occurred in 2009 and 2010. In addition, the period of seasonal frost at 10 cm and 40 cm depth on the post-fire slopes are extended for two weeks. These thermal condition changes are triggered by decrease in the thickness of the litter layer on the fired P. pumila communities.

Highly stable thin film transistors using multilayer channel structure

NASA Astrophysics Data System (ADS)

Nayak, Pradipta K.; Wang, Zhenwei; Anjum, D. H.; Hedhili, M. N.; Alshareef, H. N.

2015-03-01

We report highly stable gate-bias stress performance of thin film transistors (TFTs) using zinc oxide (ZnO)/hafnium oxide (HfO2) multilayer structure as the channel layer. Positive and negative gate-bias stress stability of the TFTs was measured at room temperature and at 60 °C. A tremendous improvement in gate-bias stress stability was obtained in case of the TFT with multiple layers of ZnO embedded between HfO2 layers compared to the TFT with a single layer of ZnO as the semiconductor. The ultra-thin HfO2 layers act as passivation layers, which prevent the adsorption of oxygen and water molecules in the ZnO layer and hence significantly improve the gate-bias stress stability of ZnO TFTs.

Method of manufacturing a shapeable short-resistant capacitor

DOEpatents

Taylor, Ralph S.; Myers, John D.; Baney, William J.

2013-04-02

A method that employs a novel combination of conventional fabrication techniques provides a ceramic short-resistant capacitor that is bendable and/or shapeable to provide a multiple layer capacitor that is extremely compact and amenable to desirable geometries. The method allows thinner and more flexible ceramic capacitors to be made. The method includes forming a first thin metal layer on a substrate; depositing a thin, ceramic dielectric layer over the metal layer; depositing a second thin metal layer over the dielectric layer to form a capacitor exhibiting a benign failure mode; and separating the capacitor from the substrate. The method may also include bending the resulting capacitor into a serpentine arrangement with gaps between the layers that allow venting of evaporated electrode material in the event of a benign failure.

Water Redistribution, Temperature Change and CO2 Diffusion of Reconstruction Soil Profiles Filled with Gangue in Coal Mining Areas

NASA Astrophysics Data System (ADS)

Wang, S.; Zhan, H.; Chen, X.; Hu, Y.

2017-12-01

There were a great many projects of reconstruction soil profile filled with gangue to restore ecological environment and land resources in coal mining areas. A simulation experimental system in laboratory was designed for studying water transport and gas-heat diffusion of the reconstruction soil as to help the process of engineering and soil-ripening technology application. The system could be used for constantly measuring soil content, temperature and soil CO2 concentration by laid sensors and detectors in different depth of soil column. The results showed that soil water infiltration process was slowed down and the water-holding capacity of the upper soil was increased because of good water resistance from coal gangue layer. However, the water content of coal gangue layer, 10% approximately, was significantly lower than that of topsoil for the poor water-holding capacity of gangue. The temperature of coal gangue layer was also greater than that of soil layer and became easily sustainable temperature gradient under the condition with heating in reconstruction soil due to the higher thermal diffusivity from gangue, especially being plenty of temperature difference between gangue and soil layers. The effects of heated from below on topsoil was small, which it was mainly influenced from indoor temperature in the short run. In addition, the temperature changing curve of topsoil is similar with the temperature of laboratory and its biggest fluctuation range was for 2.89°. The effects of aerating CO2 from column bottom on CO2 concentration of topsoil soil was also very small, because gas transport from coal gangue layers to soil ones would easily be cut off as so to gas accumulated below the soil layer. The coal gangue could have a negative impact on microbial living environment to adjacent topsoil layers and declined microorganism activities. The effects of coal gangue on topsoil layer were brought down when the cove soil thickness was at 60 cm. And the influences gradually would be weakened with the thickness increasing.

Soil moisture dynamics and dominant controls at different spatial scales over semiarid and semi-humid areas

NASA Astrophysics Data System (ADS)

Suo, Lizhu; Huang, Mingbin; Zhang, Yongkun; Duan, Liangxia; Shan, Yan

2018-07-01

Soil moisture dynamics plays an active role in ecological and hydrological processes, and it depends on a large number of environmental factors, such as topographic attributes, soil properties, land use types, and precipitation. However, studies must still clarify the relative significance of these environmental factors at different soil depths and at different spatial scales. This study aimed: (1) to characterize temporal and spatial variations in soil moisture content (SMC) at four soil layers (0-40, 40-100, 100-200, and 200-500 cm) and three spatial scales (plot, hillslope, and region); and (2) to determine their dominant controls in diverse soil layers at different spatial scales over semiarid and semi-humid areas of the Loess Plateau, China. Given the high co-dependence of environmental factors, partial least squares regression (PLSR) was used to detect relative significance among 15 selected environmental factors that affect SMC. Temporal variation in SMC decreased with increasing soil depth, and vertical changes in the 0-500 cm soil profile were divided into a fast-changing layer (0-40 cm), an active layer (40-100 cm), a sub-active layer (100-200 cm), and a relatively stable layer (200-500 cm). PLSR models simulated SMC accurately in diverse soil layers at different scales; almost all values for variation in response (R2) and goodness of prediction (Q2) were >0.5 and >0.0975, respectively. Upper and lower layer SMCs were the two most important factors that influenced diverse soil layers at three scales, and these SMC variables exhibited the highest importance in projection (VIP) values. The 7-day antecedent precipitation and 7-day antecedent potential evapotranspiration contributed significantly to SMC only at the 0-40 cm soil layer. VIP of soil properties, especially sand and silt content, which influenced SMC strongly, increased significantly after increasing the measured scale. Mean annual precipitation and potential evapotranspiration also influenced SMC at the regional scale significantly. Overall, this study indicated that dominant controls of SMC varied among three spatial scales on the Loess Plateau, and VIP was a function of spatial scale and soil depth.

Method and apparatus for fabricating a thin-film solar cell utilizing a hot wire chemical vapor deposition technique

DOEpatents

Wang, Qi; Iwaniczko, Eugene

2006-10-17

A thin-film solar cell is provided. The thin-film solar cell comprises an a-SiGe:H (1.6 eV) n-i-p solar cell having a deposition rate of at least ten (10) .ANG./second for the a-SiGe:H intrinsic layer by hot wire chemical vapor deposition. A method for fabricating a thin film solar cell is also provided. The method comprises depositing a n-i-p layer at a deposition rate of at least ten (10) .ANG./second for the a-SiGe:H intrinsic layer.

[Effects of intensive management on soil C and N pools and soil enzyme activities in Moso bamboo plantations.

PubMed

Yang, Meng; Li, Yong Fu; Li, Yong Chun; Xiao, Yong Heng; Yue, Tian; Jiang, Pei Kun; Zhou, Guo Mo; Liu, Juan

2016-11-18

In order to elucidate the effects of intensive management on soil carbon pool, nitrogen pool, enzyme activities in Moso bamboo (Phyllostachys pubescens) plantations, we collected soil samples from the soil surface (0-20 cm) and subsurface (20-40 cm) layers in the adjacent Moso bamboo plantations with extensive and intensive managements in Sankou Township, Lin'an City, Zhejiang Province. We determined different forms of C, N and soil invertase, urease, catalase and acid phosphatase activities. The results showed that long-term intensive management of Moso bamboo plantations significantly decreased the content and storage of soil organic carbon (SOC), with the SOC storage in the soil surface and subsurface layers decreased by 13.2% and 18.0%, respectively. After 15 years' intensive management of Masoo bamboo plantations, the contents of soil water soluble carbon (WSOC), hot water soluble carbon (HWSOC), microbial carbon (MBC) and readily oxidizable carbon (ROC) were significantly decreased in the soil surface and subsurface layers. The soil N storage in the soil surface and subsurface layers in intensively managed Moso bamboo plantations increased by 50.8% and 36.6%, respectively. Intensive management significantly increased the contents of nitrate-N (NO 3 - -N) and ammonium-N (NH 4 + -N), but decreased the contents of water-soluble nitrogen (WSON) and microbial biomass nitrogen (MBN). After 15 years' intensive management of Masoo bamboo plantations, the soil invertase, urease, catalase and acid phosphatase activities in the soil surface layer were significantly decreased, the soil acid phosphatase activity in the soil subsurface layer were significantly decreased, and other enzyme activities in the soil subsurface layer did not change. In conclusion, long-term intensive management led to a significant decline of soil organic carbon storage, soil labile carbon and microbial activity in Moso bamboo plantations. Therefore, we should consider the use of organic fertilizer in the intensive mana-gement process for the sustainable management of Moso bamboo plantations in the future.

Leaving moss and litter layers undisturbed reduces the short-term environmental consequences of heathland managed burns.

PubMed

Grau-Andrés, Roger; Davies, G Matt; Waldron, Susan; Scott, E Marian; Gray, Alan

2017-12-15

Variation in the structure of ground fuels, i.e. the moss and litter (M/L) layer, may be an important control on fire severity in heather moorlands and thus influence vegetation regeneration and soil carbon dynamics. We completed experimental fires in a Calluna vulgaris-dominated heathland to study the role of the M/L layer in determining (i) fire-induced temperature pulses into the soil and (ii) post-fire soil thermal dynamics. Manually removing the M/L layer before burning increased fire-induced soil heating, both at the soil surface and 2 cm below. Burnt plots where the M/L layer was removed simulated the fuel structure after high severity fires where ground fuels are consumed but the soil does not ignite. Where the M/L layer was manually removed, either before or after the fire, post-fire soil thermal dynamics showed larger diurnal and seasonal variation, as well as similar patterns to those observed after wildfires, compared to burnt plots where the M/L layer was not manipulated. We used soil temperatures to explore potential changes in post-fire soil respiration. Simulated high fire severity (where the M/L layer was manually removed) increased estimates of soil respiration in warm months. With projected fire regimes shifting towards higher severity fires, our results can help land managers develop strategies to balance ecosystem services in Calluna-dominated habitats. Copyright © 2017 The Authors. Published by Elsevier Ltd.. All rights reserved.

Ultra-high current density thin-film Si diode

DOEpatents

Wang; Qi

2008-04-22

A combination of a thin-film .mu.c-Si and a-Si:H containing diode structure characterized by an ultra-high current density that exceeds 1000 A/cm.sup.2, comprising: a substrate; a bottom metal layer disposed on the substrate; an n-layer of .mu.c-Si deposited the bottom metal layer; an i-layer of .mu.c-Si deposited on the n-layer; a buffer layer of a-Si:H deposited on the i-layer, a p-layer of .mu.c-Si deposited on the buffer layer; and a top metal layer deposited on the p-layer.

Electron transport in ultra-thin films and ballistic electron emission microscopy

NASA Astrophysics Data System (ADS)

Claveau, Y.; Di Matteo, S.; de Andres, P. L.; Flores, F.

2017-03-01

We have developed a calculation scheme for the elastic electron current in ultra-thin epitaxial heterostructures. Our model uses a Keldysh’s non-equilibrium Green’s function formalism and a layer-by-layer construction of the epitaxial film. Such an approach is appropriate to describe the current in a ballistic electron emission microscope (BEEM) where the metal base layer is ultra-thin and generalizes a previous one based on a decimation technique appropriated for thick slabs. This formalism allows a full quantum mechanical description of the transmission across the epitaxial heterostructure interface, including multiple scattering via the Dyson equation, which is deemed a crucial ingredient to describe interfaces of ultra-thin layers properly in the future. We introduce a theoretical formulation needed for ultra-thin layers and we compare with results obtained for thick Au(1 1 1) metal layers. An interesting effect takes place for a width of about ten layers: a BEEM current can propagate via the center of the reciprocal space (\\overlineΓ ) along the Au(1 1 1) direction. We associate this current to a coherent interference finite-width effect that cannot be found using a decimation technique. Finally, we have tested the validity of the handy semiclassical formalism to describe the BEEM current.

Method to measure soil matrix infiltration in forest soil

NASA Astrophysics Data System (ADS)

Zhang, Jing; Lei, Tingwu; Qu, Liqin; Chen, Ping; Gao, Xiaofeng; Chen, Chao; Yuan, Lili; Zhang, Manliang; Su, Guangxu

2017-09-01

Infiltration of water into forest soil commonly involves infiltration through the matrix body and preferential passages. Determining the matrix infiltration process is important in partitioning water infiltrating into the soil through the soil body and macropores to evaluate the effects of soil and water conservation practices on hillslope hydrology and watershed sedimentation. A new method that employs a double-ring infiltrometer was applied in this study to determine the matrix infiltration process in forest soil. Field experiments were conducted in a forest field on the Loess Plateau at Tianshui Soil and Water Conservation Experimental Station. Nylon cloth was placed on the soil surface in the inner ring and between the inner and outer rings of infiltrometers. A thin layer of fine sands were placed onto the nylon cloth to shelter the macropores and ensure that water infiltrates the soil through the matrix only. Brilliant Blue tracers were applied to examine the exclusion of preferential flow occurrences in the measured soil body. The infiltration process was measured, computed, and recorded through procedures similar to those of conventional methods. Horizontal and vertical soil profiles were excavated to check the success of the experiment and ensure that preferential flow did not occur in the measured soil column and that infiltration was only through the soil matrix. The infiltration processes of the replicates of five plots were roughly the same, thereby indicating the feasibility of the methodology to measure soil matrix infiltration. The measured infiltration curves effectively explained the transient process of soil matrix infiltration. Philip and Kostiakov models fitted the measured data well, and all the coefficients of determination were greater than 0.9. The wetted soil bodies through excavations did not present evidence of preferential flow. Therefore, the proposed method can determine the infiltration process through the forest soil matrix. This method can also be applied to explore matrix infiltration in other land-use types.

Aquifer configuration and geostructural links control the groundwater quality in thin-bedded carbonate-siliciclastic alternations of the Hainich CZE, central Germany

NASA Astrophysics Data System (ADS)

Kohlhepp, Bernd; Lehmann, Robert; Seeber, Paul; Küsel, Kirsten; Trumbore, Susan E.; Totsche, Kai U.

2017-12-01

The quality of near-surface groundwater reservoirs is controlled, but also threatened, by manifold surface-subsurface interactions. Vulnerability studies typically evaluate the variable interplay of surface factors (land management, infiltration patterns) and subsurface factors (hydrostratigraphy, flow properties) in a thorough way, but disregard the resulting groundwater quality. Conversely, hydrogeochemical case studies that address the chemical evolution of groundwater often lack a comprehensive analysis of the structural buildup. In this study, we aim to reconstruct the actual spatial groundwater quality pattern from a synoptic analysis of the hydrostratigraphy, lithostratigraphy, pedology and land use in the Hainich Critical Zone Exploratory (Hainich CZE). This CZE represents a widely distributed yet scarcely described setting of thin-bedded mixed carbonate-siliciclastic strata in hillslope terrains. At the eastern Hainich low-mountain hillslope, bedrock is mainly formed by alternated marine sedimentary rocks of the Upper Muschelkalk (Middle Triassic) that partly host productive groundwater resources. Spatial patterns of the groundwater quality of a 5.4 km long well transect are derived by principal component analysis and hierarchical cluster analysis. Aquifer stratigraphy and geostructural links were deduced from lithological drill core analysis, mineralogical analysis, geophysical borehole logs and mapping data. Maps of preferential recharge zones and recharge potential were deduced from digital (soil) mapping, soil survey data and field measurements of soil hydraulic conductivities (Ks). By attributing spatially variable surface and subsurface conditions, we were able to reconstruct groundwater quality clusters that reflect the type of land management in their preferential recharge areas, aquifer hydraulic conditions and cross-formational exchange via caprock sinkholes or ascending flow. Generally, the aquifer configuration (spatial arrangement of strata, valley incision/outcrops) and related geostructural links (enhanced recharge areas, karst phenomena) control the role of surface factors (input quality and locations) vs. subsurface factors (water-rock interaction, cross-formational flow) for groundwater quality in the multi-layered aquifer system. Our investigation reveals general properties of alternating sequences in hillslope terrains that are prone to forming multi-layered aquifer systems. This synoptic analysis is fundamental and indispensable for a mechanistic understanding of ecological functioning, sustainable resource management and protection.

Lidar observation of transition of cirrus clouds over a tropical station Gadanki (13.45° N, 79.18° E): case studies

NASA Astrophysics Data System (ADS)

Srinivasan, M. A.; Rao, C. Dhananjaya; Krishnaiah, M.

2016-05-01

The present study describes Mie lidar observations of the cirrus cloud passage showing transition between double thin layers into single thick and single thick layer into double thin layers of cirrus over Gadanki region. During Case1: 17 January 2007, Case4: 12 June 2007, Case5: 14 July 2007 and Case6: 24 July 2007 the transition is found to from two thin cirrus layers into single geometrically thick layer. Case2: 14 May 2007 and Case3: 15 May 2007, the transition is found to from single geometrically thick layer into two thin cirrus layers. Linear Depolarization Ratio (LDR) and Back Scatter Ration (BSR) are found to show similar variation with strong peaks during transition; both LDR and Cloud Optical Depth (COD) is found to show similar variation except during transition with strong peaks in COD which is not clearly found from LDR for the all cases. There is a significant weakening of zonal and meridional winds during Case1 which might be due to the transition from multiple to single thick cirrus indicating potential capability of thick cirrus in modulating the wind fields. There exists strong upward wind dominance contributed to significant ascent in cloud-base altitude thereby causing transition of multiple thin layers into single thick cirrus.

Patterning layer-by-layer self-assembled multilayer by lithography and its applications to thin film devices

NASA Astrophysics Data System (ADS)

Hua, Feng

Nanoparticles are exciting materials because they exhibit unique electronic, catalytic, and optical properties. As a novel and promising nanobuilding block, it attracts considerable research efforts in its integration into a wide variety of thin film devices. Nanoparticles were adsorbed onto the substrate with layer-by-layer self-assembly which becomes of great interest due to its suitability in colloid particle assembly. Without extremely high temperatures and sophisticated equipment, molecularly organized films in an exactly pre-designed order can grow on almost all the substrates in nature. Two approaches generating spatially separated patterns comprised of nanoparticles are demonstrated, as well as two approaches patterning more than one type of nonoparticle on a silicon wafer. The structure of the thin film patterned by these approaches are analyzed and considered suitable to the thin film device. Finally, the combination of lithography and layer-by-layer (lbl) self-assembly is utilized to realize the microelectronic device with functional nonoparticles. The lbl self-assembly is the way to coat the nonoparticles and the lighography to pattern them. Based on the coating and patterning technique, a MOS-capacitor, a MOS field-effect-transistor and magnetic thin film cantilever are fabricated.

Thin and thick layers of resin-based sealer cement bonded to root dentine compared: Adhesive behaviour.

PubMed

Pane, Epita S; Palamara, Joseph E A; Messer, Harold H

2015-12-01

This study aims to evaluate tensile and shear bond strengths of one epoxy (AH) and two methacrylate resin-based sealers (EZ and RS) in thin and thick layers bonded to root dentine. An alignment device was prepared for accurate positioning of 20 root dentine cylinders in a predefined gap of 0.1 or 1 mm. Sealer was placed in the interface. Bond strength tests were conducted. Mode of failures and representative surfaces were evaluated. Data were analysed using anova and post-hoc tests, with P < 0.05. The thick layer of sealer produced higher bond strength, except for the shear bond strength of EZ. Significant differences between thin and thick layers were found only in tensile bond strengths of AH and RS. Mixed type of failure was constantly found with all sealers. Bond strengths of thick layers of resin-based sealers to root dentine tended to be higher than with thin layers. © 2015 Australian Society of Endodontology.

Method of Fabricating Schottky Barrier solar cell

NASA Technical Reports Server (NTRS)

Stirn, R. J.; Yeh, Y. C. M. (Inventor)

1982-01-01

On a thin substrate of low cost material with at least the top surface of the substrate being electrically conductive is deposited a thin layer of heavily doped n-type polycrystalline germanium, with crystalline sizes in the submicron range. A passivation layer may be deposited on the substrate to prevent migration of impurities into the polycrystalline germanium. The polycrystalline germanium is recrystallized to increase the crystal sizes in the germanium layer to not less than 5 micros to serve as a base layer on which a thin layer of gallium arsenide is vapor epitaxially grown to a selected thickness. A thermally-grown oxide layer of a thickness of several tens of angstroms is formed on the gallium arsenide layer. A metal layer, of not more about 100 angstroms thick, is deposited on the oxide layer, and a grid electrode is deposited to be in electrical contact with the top surface of the metal layer. An antireflection coating may be deposited on the exposed top surface of the metal layer.

Characterization of aluminum selenide bi-layer thin film

NASA Astrophysics Data System (ADS)

Boolchandani, Sarita; Soni, Gyanesh; Srivastava, Subodh; Vijay, Y. K.

2018-05-01

The Aluminum Selenide (AlSe) bi-layer thin films were grown on glass substrate using thermal evaporation method under high vacuum condition. The morphological characterization was done using SEM. Electrical measurement with temperature variation shows that thin films exhibit the semiconductor nature. The optical properties of prepared thin films have also been characterized by UV-VIS spectroscopy measurements. The band gap of composite thin films has been calculated by Tauc's relation at different temperature ranging 35°C-100°C.

Agriculture Canada Central Saskatchewan Vector Soils Data

NASA Technical Reports Server (NTRS)

Knapp, David; Hall, Forrest G. (Editor); Rostad, Harold

2000-01-01

This data set consists of GIS layers that describe the soils of the BOREAS SSA. These original data layers were submitted as vector data in ARC/INFO EXPORT format. These data also include the soil name and soil layer files, which provide additional information about the soils. There are three sets of attributes that include information on the primary, secondary, and tertiary soil type within each polygon. Thus, there is a total of nine main attributes in this data set.

Piezoresistivity of mechanically drawn single-walled carbon nanotube (SWCNT) thin films-: mechanism and optimizing principle

NASA Astrophysics Data System (ADS)

Obitayo, Waris

The individual carbon nanotube (CNT) based strain sensors have been found to have excellent piezoresistive properties with a reported gauge factor (GF) of up to 3000. This GF on the other hand, has been shown to be structurally dependent on the nanotubes. In contrast, to individual CNT based strain sensors, the ensemble CNT based strain sensors have very low GFs e.g. for a single walled carbon nanotube (SWCNT) thin film strain sensor, GF is ~1. As a result, studies which are mostly numerical/analytical have revealed the dependence of piezoresistivity on key parameters like concentration, orientation, length and diameter, aspect ratio, energy barrier height and Poisson ratio of polymer matrix. The fundamental understanding of the piezoresistive mechanism in an ensemble CNT based strain sensor still remains unclear, largely due to discrepancies in the outcomes of these numerical studies. Besides, there have been little or no experimental confirmation of these studies. The goal of my PhD is to study the mechanism and the optimizing principle of a SWCNT thin film strain sensor and provide experimental validation of the numerical/analytical investigations. The dependence of the piezoresistivity on key parameters like orientation, network density, bundle diameter (effective tunneling area), and length is studied, and how one can effectively optimize the piezoresistive behavior of a SWCNT thin film strain sensors. To reach this goal, my first research accomplishment involves the study of orientation of SWCNTs and its effect on the piezoresistivity of mechanically drawn SWCNT thin film based piezoresistive sensors. Using polarized Raman spectroscopy analysis and coupled electrical-mechanical test, a quantitative relationship between the strain sensitivity and SWCNT alignment order parameter was established. As compared to randomly oriented SWCNT thin films, the one with draw ratio of 3.2 exhibited ~6x increase on the GF. My second accomplishment involves studying the influence of the network density on the piezoresistivity of mechanically drawn SWCNT thin films. Mechanically drawn SWCNT thin films with different layer (or thickness) e.g. 1-layer, 3-layer, 10-layer and 20-layer SWCNT thin films were prepared to understand the variation of SWCNT network density as well as the alignment of SWCNTs on the strain sensitivity. The less entangled SWCNT bundles observed in the sparse network density (1- layer and 3-layer SWCNT thin films) allows for easy alignment and the best gauge factors. As compared to the randomly oriented SWCNT thin films, the one with draw ratio of 3.2 exhibited ~8x increase on the GF for the 1-layer SWCNT thin films while the 20-layer SWCNT thin films exhibited ~3x increase in the GF. My third accomplishment examines the effect of SWCNT bundles with different diameters on the piezoresistive behavior of mechanically drawn SWCNT thin films. SWCNT thin film network of sparse morphology (1-layer) with different bundle sizes were prepared by varying the sonication duration e.g. S0.5hr, S4hr, S10hr and S20hr and using spraying coating. The GF increased by a factor of ~10 when the randomly oriented SWCNT thin film was stretched to a draw ratio of 3.2 for the S0.5hr SWCNT thin films and by a factor of ~2 for the S20hr SWCNT thin films. Three main mechanisms were attributed to this behavior e.g. effect of concentration of exfoliated nanotubes, bundle reduction due to mechanical stretching, and influence of bundle length on the alignment of SWCNTs. Furthermore, information about the average length and length distribution is very essential when investigating the influence of individual nanotube length on the strain sensitivity. With that in mind, we would use our previously developed preparative ultracentrifuge method (PUM), and our newly developed gel electrophoresis and simultaneous Raman and photoluminescence spectroscopy (GEP-SRSPL) to characterize the average length and length distribution of individual SWCNTs respectively.

Effect of integrating straw into agricultural soils on soil infiltration and evaporation.

PubMed

Cao, Jiansheng; Liu, Changming; Zhang, Wanjun; Guo, Yunlong

2012-01-01

Soil water movement is a critical consideration for crop yield in straw-integrated fields. This study used an indoor soil column experiment to determine soil infiltration and evaporation characteristics in three forms of direct straw-integrated soils (straw mulching, straw mixing and straw inter-layering). Straw mulching is covering the land surface with straw. Straw mixing is mixing straw with the top 10 cm surface soil. Then straw inter-layering is placing straw at the 20 cm soil depth. There are generally good correlations among the mulch integration methods at p < 0.05, and with average errors/biases <10%. Straw mixing exhibited the best effect in terms of soil infiltration, followed by straw mulching. Due to over-burden weight-compaction effect, straw inter-layering somehow retarded soil infiltration. In terms of soil water evaporation, straw mulching exhibited the best effect. This was followed by straw mixing and then straw inter-layering. Straw inter-layering could have a long-lasting positive effect on soil evaporation as it limited the evaporative consumption of deep soil water. The responses of the direct straw integration modes to soil infiltration and evaporation could lay the basis for developing efficient water-conservation strategies. This is especially useful for water-scarce agricultural regions such as the arid/semi-arid regions of China.

Process for forming epitaxial perovskite thin film layers using halide precursors

DOEpatents

Clem, Paul G.; Rodriguez, Mark A.; Voigt, James A.; Ashley, Carol S.

2001-01-01

A process for forming an epitaxial perovskite-phase thin film on a substrate. This thin film can act as a buffer layer between a Ni substrate and a YBa.sub.2 Cu.sub.3 O.sub.7-x superconductor layer. The process utilizes alkali or alkaline metal acetates dissolved in halogenated organic acid along with titanium isopropoxide to dip or spin-coat the substrate which is then heated to about 700.degree. C. in an inert gas atmosphere to form the epitaxial film on the substrate. The YBCO superconductor can then be deposited on the layer formed by this invention.

Photo-EMF sensitivity of porous silicon thin layer-crystalline silicon heterojunction to ammonia adsorption.

PubMed

Vashpanov, Yuriy; Jung, Jae Il; Kwack, Kae Dal

2011-01-01

A new method of using photo-electromotive force in detecting gas and controlling sensitivity is proposed. Photo-electromotive force on the heterojunction between porous silicon thin layer and crystalline silicon wafer depends on the concentration of ammonia in the measurement chamber. A porous silicon thin layer was formed by electrochemical etching on p-type silicon wafer. A gas and light transparent electrical contact was manufactured to this porous layer. Photo-EMF sensitivity corresponding to ammonia concentration in the range from 10 ppm to 1,000 ppm can be maximized by controlling the intensity of illumination light.

19.5%-Efficient CuIn1-xGaxSe2 Photovoltaic Cells Using A Cd-Zn-S Buffer Layer

DOE Office of Scientific and Technical Information (OSTI.GOV)

Bhattacharya. R. N.

2008-01-01

CuIn1-xGaxSe2 (CIGS) solar cell junctions prepared by chemical-bath-deposited (CBD) Zn1-xCdxS (CdZnS), ZnS, and CdS buffer layers are discussed. A 19.52%-efficient, CIGS-based, thin-film photovoltaic device has been fabricated using a single-layer CBD CdZnS buffer layer. The mechanism that creates extensive hydroxide and oxide impurities in CBD-ZnS and CBD-CdZnS thin films (compared to CBD-CdS thin film) is presented.

Management of light absorption in extraordinary optical transmission based ultra-thin-film tandem solar cells

DOE Office of Scientific and Technical Information (OSTI.GOV)

Mashooq, Kishwar; Talukder, Muhammad Anisuzzaman, E-mail: anis@eee.buet.ac.bd

2016-05-21

Although ultra-thin-film solar cells can be attractive in reducing the cost, they suffer from low absorption as the thickness of the active layer is usually much smaller than the wavelength of incident light. Different nano-photonic techniques, including plasmonic structures, are being explored to increase the light absorption in ultra-thin-film solar cells. More than one layer of active materials with different energy bandgaps can be used in tandem to increase the light absorption as well. However, due to different amount of light absorption in different active layers, photo-generated currents in different active layers will not be the same. The current mismatchmore » between the tandem layers makes them ineffective in increasing the efficiency. In this work, we investigate the light absorption properties of tandem solar cells with two ultra-thin active layers working as two subcells and a metal layer with periodically perforated holes in-between the two subcells. While the metal layer helps to overcome the current mismatch, the periodic holes increase the absorption of incident light by helping extraordinary optical transmission of the incident light from the top to the bottom subcell, and by coupling the incident light to plasmonic and photonic modes within ultra-thin active layers. We extensively study the effects of the geometry of holes in the intermediate metal layer on the light absorption properties of tandem solar cells with ultra-thin active layers. We also study how different metals in the intermediate layer affect the light absorption; how the geometry of holes in the intermediate layer affects the absorption when the active layer materials are changed; and how the intermediate metal layer affects the collection of photo-generated electron-hole pairs at the terminals. We find that in a solar cell with 6,6-phenyl C61-butyric acid methyl ester top subcell and copper indium gallium selenide bottom subcell, if the periodic holes in the metal layer are square or polygon, total absorption remains approximately the same. However, the total absorption suffers significantly if the holes are triangle. The transmission spectra of incident light into the bottom subcell, and hence the absorption, change significantly for square and circle holes if the active materials change to cadmium selenide (CdSe) and cadmium telluride (CdTe) in the top and bottom subcells, respectively. Although the intermediate metal layer may induce electron-hole pair recombination due to surface defects, the short-circuit current density of an ultra-thin plasmonic solar cell with an intermediate metal layer with two-dimensional hole array is >9% of that of a structure without the intermediate metal layer.« less

Study on the Hydrogenated ZnO-Based Thin Film Transistors. Part 1

DTIC Science & Technology

2011-04-30

IGZO film on the performance of thin film transistors 5 Chapter 2. Hydrogenation of a- IGZO channel layer in the thin film transistors 12...effect of substrate temperature during the deposition of a- IGZO film on the performance of thin film transistors Introduction The effect of substrate...temperature during depositing IGZO channel layer on the performance of amorphous indium-gallium-zinc oxide (a- IGZO

Thin-Film Power Transformers

NASA Technical Reports Server (NTRS)

Katti, Romney R.

1995-01-01

Transformer core made of thin layers of insulating material interspersed with thin layers of ferromagnetic material. Flux-linking conductors made of thinner nonferromagnetic-conductor/insulator multilayers wrapped around core. Transformers have geometric features finer than those of transformers made in customary way by machining and mechanical pressing. In addition, some thin-film materials exhibit magnetic-flux-carrying capabilities superior to those of customary bulk transformer materials. Suitable for low-cost, high-yield mass production.

Substrate spacing and thin-film yield in chemical bath deposition of semiconductor thin films

NASA Astrophysics Data System (ADS)

Arias-Carbajal Reádigos, A.; García, V. M.; Gomezdaza, O.; Campos, J.; Nair, M. T. S.; Nair, P. K.

2000-11-01

Thin-film yield in the chemical bath deposition technique is studied as a function of separation between substrates in batch production. Based on a mathematical model, it is proposed and experimentally verified in the case of CdS thin films that the film thickness reaches an asymptotic maximum with increase in substrate separation. It is shown that at a separation less than 1 mm between substrates the yield, i.e. percentage in moles of a soluble cadmium salt deposited as a thin film of CdS, can exceed 50%. This behaviour is explained on the basis of the existence of a critical layer of solution near the substrate, within which the relevant ionic species have a higher probability of interacting with the thin-film layer than of contributing to precipitate formation. The critical layer depends on the solution composition and the temperature of the bath as well as the duration of deposition. An effective value for the critical layer thickness has been defined as half the substrate separation at which 90% of the maximum film thickness for the particular bath composition, bath temperature and duration of deposition is obtained. In the case of CdS thin films studied as an example, the critical layer is found to extend from 0.5 to 2.5 mm from the substrate surface, depending on the deposition conditions.

Vertical electric sounding of selected Arctic and Antarctic soils: advances in express field investigation of the Cryosols

NASA Astrophysics Data System (ADS)

Abakumov, Evgeny

2016-04-01

Physical properties of the soils of the cold environments are underestimated. Soil and permafrost border and active layer thickness are the key classification indicators for the polar soils. That is why electrophysical research has been conducted with aim to determine the soil-permafrost layer heterogeneity and the depth of the uppermost permafrost layer on examples of selected plots in Antarctic region and Russian Arctic. The electric resistivity (ER) was measured directly in the soil profiles using the vertical electrical sounding (VERS) method, which provides data on the changes in the electrical resistivity throughout the profile from the soil surface without digging pits or drilling. This method allows dividing the soil layer vertically into genetic layers, which are different on main key properties and characteristics Different soil layers have different ER values, that is why the sharp changes in ER values in soil profile can be interpreted as results of transition of one horizon to another. In our study, the resistivity measurements were performed using four-electrode (AB + MN) arrays of the AMNB configuration with use of the Schlumberger geometry. A Landmapper ERM-03 instrument (Landviser, USA) was used for the VES measurements in this study. Electrodes were situated on the soil surface, distance between M and N was fixes, while distance from A to B were changed during the sounding. Vertical Electrical Resistivity Soundings (VERS) using Schlumberger array were carried out at stations, situated on the different plots of terrestrial ecosystems of Arctic and Antarctic. The resistance readings at every VERS point were automatically displayed on the digital readout screen and then written down on the field note book. The soils had been 'sounded' thoroughly and found to vary between 5 cm and 3-5 m in A-B distances. It was shown that use of VES methodology in soil survey is quite useful for identification of the permafrost depth without digging of soil pit. This method allow identify soil heterogeneity, because the ER values are strongly affected by soil properties and intensively changes on the border of different geochemical regimes, i.e. on the border of active layer and permafrost. VES data obtained show that the upper border of the permafrost layer coincides with that border, which were identified in field on the base of soil profile morphology. The VERS method also can used for identification of Gleyic, Histic and Podzolic layers. It has been also shown that permafrost layer is less homogenous in upper part of permafrost, than in lower one. It is caused by number of cracks, channels and other paths of dissolved organic matter and iron containing compounds migration. VES methodology is useful for preliminary soil survey in the regions with permafrost affected soil cover. It is also can be applied for detalization of soil-permafrost layer stratification in field soil pits.

Effects of morphological control on the characteristics of vertical-type OTFTs using Alq3.

PubMed

Kim, Young Do; Park, Jong Wook; Kang, In Nam; Oh, Se Young

2008-09-01

We have fabricated vertical-type organic thin-film transistors (OTFTs) using tris-(8-hydroxyquinoline) aluminum (Alq(3)) as an n-type active material. Vertical-type OTFT using Alq(3) has a layered structure of Al(source electrode)/Alq(3)(active layer)/Al(gate electrode)/Alq(3)(active layer)/ITO glass(drain electrode). Alq(3) thin films containing various surface morphologies could be obtained by the control of evaporation rate and substrate temperature. The effects of the morphological control of Alq(3) thin layer on the grain size and the flatness of film surface were investigated. The characteristics of vertical-type OTFT significantly influenced the growth condition of Alq(3) layer.

Disruption of vertical motility by shear triggers formation of thin phytoplankton layers.

PubMed

Durham, William M; Kessler, John O; Stocker, Roman

2009-02-20

Thin layers of phytoplankton are important hotspots of ecological activity that are found in the coastal ocean, meters beneath the surface, and contain cell concentrations up to two orders of magnitude above ambient concentrations. Current interpretations of their formation favor abiotic processes, yet many phytoplankton species found in these layers are motile. We demonstrated that layers formed when the vertical migration of phytoplankton was disrupted by hydrodynamic shear. This mechanism, which we call gyrotactic trapping, can be responsible for the thin layers of phytoplankton commonly observed in the ocean. These results reveal that the coupling between active microorganism motility and ambient fluid motion can shape the macroscopic features of the marine ecological landscape.

Enhanced electrical properties of dual-layer channel ZnO thin film transistors prepared by atomic layer deposition

NASA Astrophysics Data System (ADS)

Li, Huijin; Han, Dedong; Dong, Junchen; Yu, Wen; Liang, Yi; Luo, Zhen; Zhang, Shengdong; Zhang, Xing; Wang, Yi

2018-05-01

The thin film transistors (TFTs) with a dual-layer channel structure combing ZnO thin layer grown at 200 °C and ZnO film grown at 120 °C by atomic layer deposition are fabricated. The dual-layer channel TFT exhibits a low leakage current of 2.8 × 10-13 A, Ion/Ioff ratio of 3.4 × 109, saturation mobility μsat of 12 cm2 V-1 s-1, subthreshold swing (SS) of 0.25 V/decade. The SS value decreases to 0.18 V/decade after the annealing treatment in O2 due to the reduction of the trap states at the channel/dielectric interface and in the bulk channel layer. The enhanced performance obtained from the dual-layer channel TFTs is due to the ability of maintaining high mobility and suppressing the increase in the off-current at the same time.

Fabrication and characterization of {110}-oriented Pb(Zr,Ti)O3 thin films on Pt/SiO2/Si substrates using PdO//Pd buffer layer

NASA Astrophysics Data System (ADS)

Oshima, Naoya; Uchiyama, Kiyoshi; Ehara, Yoshitaka; Oikawa, Takahiro; Ichinose, Daichi; Tanaka, Hiroki; Sato, Tomoya; Uchida, Hiroshi; Funakubo, Hiroshi

2017-10-01

A strongly {110}-oriented perovskite-type thin film of tetragonal Pb(Zr0.4Ti0.6)O3 (PZT) was successfully obtained on a (100)Si substrate using a {101}PdO//{111}Pd thin film as a buffer layer. The {101}PdO//{111}Pd thin film buffer layer was obtained by oxidizing {111}Pd after depositing {111}Pd on a {111}Pt/TiO x /SiO2/{100}Si substrate. Using this buffer layer, a {110} c -oriented SrRuO3 (SRO) thin film was deposited by sputtering as a bottom electrode of PZT thin films. Subsequently, the {110}-oriented PZT thin film can be deposited on a (110) c SRO thin film by metal-organic chemical deposition (MOCVD) and its properties can be compared with those of PZT thin films with other orientations of {100} and {111}. Among the {100}, {110}, {111}-oriented PZT films, the {100}-oriented one showed the largest remnant polarization, which is in good agreement with those of the PZTs epitaxially grown in the 〈100〉, 〈110〉, and 〈111〉 directions. The other properties, i.e., piezoelectricity and dielectric constants, also showed similar anisotropic tendencies, which is in good agreement with the data reported in the epitaxially grown PZTs.

The influence of wildfire severity on soil char composition and nitrogen dynamics

NASA Astrophysics Data System (ADS)

Rhoades, Charles; Fegel, Timothy; Chow, Alex; Tsai, Kuo-Pei; Norman, John, III; Kelly, Eugene

2017-04-01

Forest fires cause lasting ecological changes and alter the biogeochemical processes that control stream water quality. Decreased plant nutrient uptake is the mechanism often held responsible for lasting post-fire shifts in nutrient supply and demand, though other upland and in-stream factors also likely contribute to elevated stream nutrient losses. Soil heating, for example, creates pyrogenic carbon (C) and char layers that influence C and nitrogen (N) cycling. Char layer composition and persistence vary across burned landscapes and are influenced first by fire behavior through the temperature and duration of combustion and then by post-fire erosion. To evaluate the link between soil char and stream C and N export we studied areas burned by the 2002 Hayman Fire, the largest wildfire in Colorado, USA history. We compared soil C and N pools and processes across ecotones that included 1) unburned forests, 2) areas with moderate and 3) high wildfire severity. We analyzed 1-2 cm thick charred organic layers that remain visible 15 years after the fire, underlying mineral soils, and soluble leachate from both layers. Unburned soils released more dissolved organic C and N (DOC and DON) from organic and mineral soil layers than burned soils. The composition of DOC leachate characterized by UV-fluorescence, emission-excitation matrices (EEMs) and Fluorescence Regional Integration (FRI) found similarity between burned and unburned soils, underscoring a common organic matter source. Humic and fulvic acid-like fractions, contained in regions V and III of the FRI model, comprised the majority of the fluorescing DOM in both unburned and char layers. Similarity between two EEMs indices (Fluorescence and Freshness), further denote that unburned soils and char layers originate from the same source and are consistent with visual evidence char layers contain significant amounts of unaltered OM. However, the EEMs humification index (HIX) and compositional analysis with pyrolysis GCMS both indicate that C contained or leached from severely-burned char layers has higher aromaticity and thus chemical stability compared to C in unburned soils. Mineral soil (0-5 cm depth) beneath char layers in high severity portions of the Hayman Fire had significantly more soil N and C and lower pH. Potential net mineralization - an index of the supply of plant-available nitrogen - differed between the severely-burned areas and both unburned and moderately-burn areas. Negative net mineralization in unburned and moderately burned soils indicates immobilization or retention of inorganic N by soil microbes. In contrast, soils burned at high severity produced inorganic N sources available to plants, leaching and gas losses. Water soluble nitrate comprised a larger proportion of inorganic N leached from the char layer of high severity burns. Mineral soil in those areas had both higher water soluble nitrate and total inorganic N in leachate. Char layers that have persisted for fifteen years influence soil N turnover within the Hayman Fire affected area and may contribute to elevated N losses in streams burned at high severity. The chemical stability of soil char layers perpetuates their importance for C sequestration and N dynamics in burned landscapes.

Modeling of Multiphase Flow through Thin Porous Layers: Application to a Polymer Electrolyte Fuel Cell (PEFC)

NASA Astrophysics Data System (ADS)

Qin, C.; Hassanizadeh, S.

2013-12-01

Multiphase flow and species transport though thin porous layers are encountered in a number of industrial applications, such as fuel cells, filters, and hygiene products. Based on some macroscale models like the Darcy's law, to date, the modeling of flow and transport through such thin layers has been mostly performed in 3D discretized domains with many computational cells. But, there are a number of problems with this approach. First, a proper representative elementary volume (REV) is not defined. Second, one needs to discretize a thin porous medium into computational cells whose size may be comparable to the pore sizes. This suggests that the traditional models are not applicable to such thin domains. Third, the interfacial conditions between neighboring layers are usually not well defined. Last, 3D modeling of a number of interacting thin porous layers often requires heavy computational efforts. So, to eliminate the drawbacks mentioned above, we propose a new approach to modeling multilayers of thin porous media as 2D interacting continua (see Fig. 1). Macroscale 2D governing equations are formulated in terms of thickness-averaged material properties. Also, the exchange of thermodynamic properties between neighboring layers is described by thickness-averaged quantities. In Comparison to previous macroscale models, our model has the distinctive advantages of: (1) it is rigorous thermodynamics-based model; (2) it is formulated in terms of thickness-averaged material properties which are easily measureable; and (3) it reduces 3D modeling to 2D leading to a very significant reduction of computation efforts. As an application, we employ the new approach in the study of liquid water flooding in the cathode of a polymer electrolyte fuel cell (PEFC). To highlight the advantages of the present model, we compare the results of water distribution with those obtained from the traditional 3D Darcy-based modeling. Finally, it is worth noting that, for specific case studies, a number of material properties in the model need to be determined experimentally, such as mass and heat exchange coefficients between neighboring layers. Fig. 1: Schematic representation of three thin porous layers, which may exchange mass, momentum, and energy. Also, a typical averaging domain (REV) is shown. Note that the layer thickness and thus the REV height can be spatially variable. Also, in reality, the layers are tightly stacked and there is no gap between them.

Effect of thin oxide layers incorporated in spin valve structures

NASA Astrophysics Data System (ADS)

Gillies, M. F.; Kuiper, A. E. T.; Leibbrandt, G. W. R.

2001-06-01

The enhancement of the magnetoresistance effect, induced by incorporating nano-oxide layers (NOLs) in a bottom-type spin valve, was studied for various preparation conditions. The effect of a NOL in the Co90Fe10 pinned layer was found to depend critically on the oxygen pressure applied to form the thin oxide film. Pressures over 10-3 Torr O2 yield oxides thicker than about 0.7 nm, which apparently deteriorate the biasing field which exists over the oxide. The magnetoresistance values can further be raised by forming a specular reflecting oxide on top of the sense layer. Promising results were obtained with an Al2O3 capping layer formed in a solid-state oxidation reaction that occurs spontaneously when a thin Al layer is deposited on the oxidized surface of the Co90Fe10 sense layer.

Water softening process

DOEpatents

Sheppard, John D.; Thomas, David G.

1976-01-01

This invention involves an improved process for softening hard water which comprises selectively precipitaing CaCO.sub.3 to form a thin layer thereof, increasing the pH of said water to precipitate magnesium as magnesium hydroxide and then filtering the resultant slurry through said layer. The CaCO.sub.3 layer serves as a thin permeable layer which has particularly useful application in cross-flow filtration applications.

Matching characteristics of different buffer layers with VO2 thin films

NASA Astrophysics Data System (ADS)

Yang, Kai; Zhang, Dongping; Liu, Yi; Guan, Tianrui; Qin, Xiaonan; Zhong, Aihua; Cai, Xingmin; Fan, Ping; Lv, Weizhong

2016-10-01

VO2 thin films were fabricated by reactive DC magnetron sputtering on different buffer layers of MgF2, Al2O3 and TiO2, respectively. The crystallinity and orientation relationship, thickness of VO2 thin films, atoms vibrational modes, optical and electrical property, surface morphology of films were characterized by X-ray diffraction, Raman scattering microscopy, step profiler, spectrophotometer, four-probe technique, and scanning electron microscopy, respectively. XRD results investigated that the films have preferential crystalline planes VO2 (011). The crystallinity of VO2 films grown on TiO2 buffer layers are superior to VO2 directly deposited on soda-lime glass. The Raman bands of the VO2 films correspond to an Ag symmetry mode of VO2 (M). The sample prepared on 100nm TiO2 buffer layer appears nanorods structure, and exhibits remarkable solar energy modulation ability as high as 5.82% in full spectrum and 23% in near infrared spectrum. Cross-sectional SEM image of the thin films samples indicate that MgF2 buffer layer has clear interface with VO2 layer. But there are serious interdiffusion phenomenons between Al2O3, TiO2 buffer layer with VO2 layer.

[Effects of ex situ rice straw incorporation on organic matter content and main physical properties of hilly red soil].

PubMed

Zhu, Han-hua; Huang, Dao-you; Liu, Shou-long; Zhu, Qi-hong

2007-11-01

Two typical land-use types, i.e., newly cultivated slope land and mellow upland, were selected to investigate the effects of ex situ rice straw incorporation on the organic matter content, field water-holding capacity, bulk density, and porosity of hilly red soil, and to approach the correlations between these parameters. The results showed that ex situ incorporation of rice straw increased soil organic matter content, ameliorated soil physical properties, and improved soil water storage. Comparing with non-fertilization and applying chemical fertilizers, ex situ incorporation of rice straw increased the contents of organic matter (5.8%-28.9%) and > 0.25 mm water-stable aggregates in 0-20 cm soil layer, and increased the field water-holding capacity (6.8%-16.2%) and porosity (4.8%-7.7%) significantly (P < 0.05) while decreased the bulk density (4.5%-7.5%) in 10-15 cm soil layer. The organic matter content in 0-20 cm soil layer was significantly correlated to the bulk density, porosity, and field water-holding capacity in 10-15 cm soil layer (P < 0.01), and the field water-holding capacity in 0-20 cm and 10-15 cm soil layers was significantly correlated to the bulk density and porosity in these two layers (P < 0.05).

Isolation of Three Components from Spearmint Oil: An Exercise in Column and Thin-Layer Chromatography

ERIC Educational Resources Information Center

Davies, Don R.; Johnson, Todd M.

2007-01-01

A simple experiment for undergraduate organic chemistry students to separate a colorless mixture using column chromatography and then monitor the outcome of the separation using thin-layer chromatography (TLC) and infrared spectroscopy(IR) is described. The experiment teaches students the principle and techniques of column and thin-layer…

High performance thin film transistor with ZnO channel layer deposited by DC magnetron sputtering.

PubMed

Moon, Yeon-Keon; Moon, Dae-Yong; Lee, Sang-Ho; Jeong, Chang-Oh; Park, Jong-Wan

2008-09-01

Research in large area electronics, especially for low-temperature plastic substrates, focuses commonly on limitations of the semiconductor in thin film transistors (TFTs), in particular its low mobility. ZnO is an emerging example of a semiconductor material for TFTs that can have high mobility, while a-Si and organic semiconductors have low mobility (<1 cm2/Vs). ZnO-based TFTs have achieved high mobility, along with low-voltage operation low off-state current, and low gate leakage current. In general, ZnO thin films for the channel layer of TFTs are deposited with RF magnetron sputtering methods. On the other hand, we studied ZnO thin films deposited with DC magnetron sputtering for the channel layer of TFTs. After analyzing the basic physical and chemical properties of ZnO thin films, we fabricated a TFT-unit cell using ZnO thin films for the channel layer. The field effect mobility (micro(sat)) of 1.8 cm2/Vs and threshold voltage (Vth) of -0.7 V were obtained.

Magnetoelastic sensor for characterizing properties of thin-film/coatings

NASA Technical Reports Server (NTRS)

Bachas, Leonidas G. (Inventor); Barrett, Gary (Inventor); Grimes, Craig A. (Inventor); Kouzoudis, Dimitris (Inventor); Schmidt, Stefan (Inventor)

2004-01-01

An apparatus for determining elasticity characteristics of a thin-film layer. The apparatus comprises a sensor element having a base magnetostrictive element at least one surface of which is at least partially coated with the thin-film layer. The thin-film layer may be of a variety of materials (having a synthetic and/or bio-component) in a state or form capable of being deposited, manually or otherwise, on the base element surface, such as by way of eye-dropper, melting, dripping, brushing, sputtering, spraying, etching, evaporation, dip-coating, laminating, etc. Among suitable thin-film layers for the sensor element of the invention are fluent bio-substances, thin-film deposits used in manufacturing processes, polymeric coatings, paint, an adhesive, and so on. A receiver, preferably remotely located, is used to measure a plurality of values for magneto-elastic emission intensity of the sensor element in either characterization: (a) the measure of the plurality of values is used to identify a magneto-elastic resonant frequency value for the sensor element; and (b) the measure of the plurality of successive values is done at a preselected magneto-elastic frequency.

Scavenging of oxygen from SrTiO3 by metals and its implications for oxide thin film deposition

NASA Astrophysics Data System (ADS)

Posadas, Agham; Kormondy, Kristy; Guo, Wei; Ponath, Patrick; Kremer, Jacqueline; Hadamek, Tobias; Demkov, Alexander

SrTiO3 is a widely used substrate for the growth of other functional oxide thin films. However, SrTiO3 loses oxygen very easily during oxide thin film deposition even under relatively high oxygen pressures. In some cases, there will be an interfacial layer of oxygen-deficient SrTiO3 formed at the interface with the deposited oxide film, depending on the metals present in the film. By depositing a variety of metals layer by layer and measuring the evolution of the core level spectra of both the deposited metal and SrTiO3 using x-ray photoelectron spectroscopy, we show that there are three distinct types of behavior that occur for thin metal films on SrTiO3. We discuss the implications of these types of behavior for the growth of complex oxide thin films on SrTiO3, and which oxide thin films are expected to produce an interfacial oxygen-deficient layer depending on their elemental constituents.

Soil organic carbon and nitrogen accumulation on coal mine spoils reclaimed with maritime pine (Pinus pinaster Aiton) in Agacli-Istanbul.

PubMed

Sever, Hakan; Makineci, Ender

2009-08-01

Mining operations on open coal mines in Agacli-Istanbul have resulted in the destruction of vast amounts of land. To rehabilitate these degraded lands, plantations on this area began in 1988. Twelve tree species were planted, however, the most planted tree species was maritime pine (Pinus pinaster Aiton). This study performed on 14 sample plots randomly selected in maritime pine plantations on coal mine soil/spoils in 2005. Soil samples were taken from eight different soil layers (0-1, 1-3, 3-5, 5-10, 10-20, 20-30, 30-40 and 40-50 cm) into the soil profile. On soil samples; fine soil fraction (<2 mm), soil acidity (pH), organic carbon (C(org)) and total nitrogen (N(t)) contents were investigated, and results were compared statistically among soil layers. As a result, 17 years after plantations, total forest floor accumulation determined as 17,973.20 kg ha(-1). Total nitrogen and organic matter amounts of forest floor were 113.90 and 14,640.92 kg ha(-1) respectively. Among soil layers, the highest levels of organic carbon (1.77%) and total nitrogen (0.096%) and the lowest pH value (pH 5.38) were found in 0-1 cm soil layer, and the variation differs significantly among soil layers. Both organic carbon and total nitrogen content decreased, pH values increased from 0-1 to 5-10 cm layer. In conclusion, according to results obtained maritime pine plantations on coal mine spoils; slow accumulation and decomposition of forest floor undergo simultaneously. Depending on these changes organic carbon and total nitrogen contents increased in upper layer of soil/spoil.

Extraordinary Corrosion Protection from Polymer-Clay Nanobrick Wall Thin Films.

PubMed

Schindelholz, Eric J; Spoerke, Erik D; Nguyen, Hai-Duy; Grunlan, Jaime C; Qin, Shuang; Bufford, Daniel C

2018-06-20

Metals across all industries demand anticorrosion surface treatments and drive a continual need for high-performing and low-cost coatings. Here we demonstrate polymer-clay nanocomposite thin films as a new class of transparent conformal barrier coatings for protection in corrosive atmospheres. Films assembled via layer-by-layer deposition, as thin as 90 nm, are shown to reduce copper corrosion rates by >1000× in an aggressive H 2 S atmosphere. These multilayer nanobrick wall coatings hold promise as high-performing anticorrosion treatment alternatives to costlier, more toxic, and less scalable thin films, such as graphene, hexavalent chromium, or atomic-layer-deposited metal oxides.

New approach to analyzing soil-building systems

USGS Publications Warehouse

Safak, E.

1998-01-01

A new method of analyzing seismic response of soil-building systems is introduced. The method is based on the discrete-time formulation of wave propagation in layered media for vertically propagating plane shear waves. Buildings are modeled as an extension of the layered soil media by assuming that each story in the building is another layer. The seismic response is expressed in terms of wave travel times between the layers, and the wave reflection and transmission coefficients at layer interfaces. The calculation of the response is reduced to a pair of simple finite-difference equations for each layer, which are solved recursively starting from the bedrock. Compared with commonly used vibration formulation, the wave propagation formulation provides several advantages, including the ability to incorporate soil layers, simplicity of the calculations, improved accuracy in modeling the mass and damping, and better tools for system identification and damage detection.A new method of analyzing seismic response of soil-building systems is introduced. The method is based on the discrete-time formulation of wave propagation in layered media for vertically propagating plane shear waves. Buildings are modeled as an extension of the layered soil media by assuming that each story in the building is another layer. The seismic response is expressed in terms of wave travel times between the layers, and the wave reflection and transmission coefficients at layer interfaces. The calculation of the response is reduced to a pair of simple finite-difference equations for each layer, which are solved recursively starting from the bedrock. Compared with commonly used vibration formulation, the wave propagation formulation provides several advantages, including the ability to incorporate soil layers, simplicity of the calculations, improved accuracy in modeling the mass and damping, and better tools for system identification and damage detection.

Effects of V2O5/Au bi-layer electrodes on the top contact Pentacene-based organic thin film transistors

NASA Astrophysics Data System (ADS)

Borthakur, Tribeni; Sarma, Ranjit

2017-05-01

Top-contact Pentacene-based organic thin film transistors (OTFTs) with a thin layer of Vanadium Pent-oxide between Pentacene and Au layer are fabricated. Here we have found that the devices with V2O5/Au bi-layer source-drain electrode exhibit better field-effect mobility, high on-off ratio, low threshold voltage and low sub-threshold slope than the devices with Au only. The field-effect mobility, current on-off ratio, threshold voltage and sub-threshold slope of V2O5/Au bi-layer OTFT estimated from the device with 15 nm thick V2O5 layer is .77 cm2 v-1 s-1, 7.5×105, -2.9 V and .36 V/decade respectively.

Vertical III-nitride thin-film power diode

DOE Office of Scientific and Technical Information (OSTI.GOV)

Wierer, Jr., Jonathan; Fischer, Arthur J.; Allerman, Andrew A.

2017-03-14

A vertical III-nitride thin-film power diode can hold off high voltages (kV's) when operated under reverse bias. The III-nitride device layers can be grown on a wider bandgap template layer and growth substrate, which can be removed by laser lift-off of the epitaxial device layers grown thereon.

Carbon-Nanotube Conductive Layers for Thin-Film Solar Cells

NASA Technical Reports Server (NTRS)

Landis, Geoffrey A.

2005-01-01

Thin, transparent layers comprising mats of carbon nanotubes have been proposed for providing lateral (that is, inplane) electrical conductivities for collecting electric currents from the front surfaces of the emitter layers of thin-film solar photovoltaic cells. Traditionally, thin, semitransparent films of other electrically conductive materials (usually, indium tin oxide, zinc oxide, or cadmium sulfide) have been used for this purpose. As in the cases of the traditional semitransparent conductive films, the currents collected by the nanotube layers would, in turn, be further collected by front metal contact stripes. Depending on details of a specific solar-cell design, the layer of carbon nanotubes would be deposited in addition to, or instead of, a semitransparent layer of one of these traditional conductive materials (see figure). The proposal is expected to afford the following advantages: The electrical conductivity of the carbon- nanotube layer would exceed that of the corresponding semitransparent layer of traditional electrically conductive material. The greater electrical conductivity of the carbon-nanotube layer would make it possible to retain adequate lateral electrical conductivity while reducing the thickness of, or eliminating entirely, the traditional semitransparent conductive layer. As a consequence of thinning or elimination of the traditional semitransparent conductive layer, less light would be absorbed, so that more of the incident light would be available for photovoltaic conversion. The greater electrical conductivity of the carbon-nanotube layer would make it possible to increase the distance between front metal contact stripes, in addition to (or instead of) thinning or eliminating the layer of traditional semitransparent conductive material. Consequently, the fraction of solar-cell area shadowed by front metal contact stripes would be reduced again, making more of the incident light available for photovoltaic conversion. The electrical conductivities of individual carbon nanotubes can be so high that the mat of carbon nanotubes could be made sparse enough to be adequately transparent while affording adequate lateral electrical conductivity of the mat as a whole. The thickness of the nanotube layer would be chosen so that the layer would contribute significant lateral electrical conductivity, yet would be as nearly transparent as possible to incident light. A typical thickness for satisfying these competing requirements is expected to lie between 50 and 100 nm. The optimum thickness must be calculated by comparing the lateral electrical conductivity, the distance between front metal stripes, and the amount of light lost by absorption in the nanotube layer.

Molecular investigations into a globally important carbon pool: Permafrost-protected carbon in Alaskan soils

USGS Publications Warehouse

Waldrop, M.P.; Wickland, K.P.; White, Rickie; Berhe, A.A.; Harden, J.W.; Romanovsky, V.E.

2010-01-01

The fate of carbon (C) contained within permafrost in boreal forest environments is an important consideration for the current and future carbon cycle as soils warm in northern latitudes. Currently, little is known about the microbiology or chemistry of permafrost soils that may affect its decomposition once soils thaw. We tested the hypothesis that low microbial abundances and activities in permafrost soils limit decomposition rates compared with active layer soils. We examined active layer and permafrost soils near Fairbanks, AK, the Yukon River, and the Arctic Circle. Soils were incubated in the lab under aerobic and anaerobic conditions. Gas fluxes at -5 and 5 ??C were measured to calculate temperature response quotients (Q10). The Q10 was lower in permafrost soils (average 2.7) compared with active layer soils (average 7.5). Soil nutrients, leachable dissolved organic C (DOC) quality and quantity, and nuclear magnetic resonance spectroscopy of the soils revealed that the organic matter within permafrost soils is as labile, or even more so, than surface soils. Microbial abundances (fungi, bacteria, and subgroups: methanogens and Basidiomycetes) and exoenzyme activities involved in decomposition were lower in permafrost soils compared with active layer soils, which, together with the chemical data, supports the reduced Q10 values. CH4 fluxes were correlated with methanogen abundance and the highest CH4 production came from active layer soils. These results suggest that permafrost soils have high inherent decomposability, but low microbial abundances and activities reduce the temperature sensitivity of C fluxes. Despite these inherent limitations, however, respiration per unit soil C was higher in permafrost soils compared with active layer soils, suggesting that decomposition and heterotrophic respiration may contribute to a positive feedback to warming of this eco region. Published 2010. This article is a US Government work and is in the public domain in the USA.

Electromagnetic shielding effectiveness of a thin silver layer deposited onto PET film via atmospheric pressure plasma reduction

NASA Astrophysics Data System (ADS)

Oh, Hyo-Jun; Dao, Van-Duong; Choi, Ho-Suk

2018-03-01

This study presents the first use of a plasma reduction reaction under atmospheric pressure to fabricate a thin silver layer on polyethylene terephthalate (PET) film without the use of toxic chemicals, high voltages, or an expensive vacuum apparatus. The developed film is applied to electromagnetic interference (EMI) shielding. After repeatedly depositing a silver layer through a plasma reduction reaction on PET, we can successfully fabricate a uniformly deposited thin silver layer. It was found that both the particle size and film thickness of thin silver layers fabricated at different AgNO3 concentrations increase with an increase in the concentration of AgNO3. However, the roughness of the thin silver layer decreases when increasing the concentration of AgNO3 from 100 to 500 mM, and the roughness increases with a further increase in the concentration of AgNO3. The EMI shielding effectiveness (SE) of the film is measured in the frequency range of 0.045 to 1 GHz. As a result of optimizing the electrical conductivity by measuring sheet resistance of the thin silver layer, the film fabricated from 500 mM AgNO3 exhibits the highest EMI SE among all fabricated films. The maximum values of the EMI SE are 60.490 dB at 0.1 GHz and 54.721 dB at 1.0 GHz with minimum sheet resistance of 0.244 Ω/□. Given that the proposed strategy is simple and effective, it is promising for fabricating various low-cost metal films with high EMI SE.

Field sampling of loose erodible material: A new method to consider the full particle-size range

NASA Astrophysics Data System (ADS)

Klose, Martina; Gill, Thomas E.

2017-04-01

The aerodynamic entrainment of sand and dust is determined by the atmospheric forces exerted onto the soil surface and by the soil-surface condition. If aerodynamic forces are strong enough to generate sand and dust lifting, the entrained sediment amount still critically depends on the supply of loose particles readily available for lifting. This loose erodible material (LEM) is sometimes defined as the thin layer of loose particles on top of a crusted surface. Here, we more generally define LEM as loose particles or particle aggregates available for entrainment, which may or may not overlay a soil crust. Field sampling of LEM is difficult and only few attempts have been made. Motivated by saltation as the most efficient process to generate dust emission, methods have focused on capturing LEM in the sand-size range or on determining the potential of a soil surface to be eroded by aerodynamic forces and particle impacts. Here, our focus is to capture the full particle-size distribution of LEM in situ, including the dust and sand-size range, to investigate the potential and likelihood of dust emission mechanisms (aerodynamic entrainment, saltation bombardment, aggregate disintegration) to occur. A new vacuum method is introduced and its capability to sample LEM without significant alteration of the LEM particle-size distribution is investigated.

Landscape and hydrologic changes in the permafrost regions of the Western Canadian Arctic

NASA Astrophysics Data System (ADS)

Marsh, P.

2012-12-01

The Western Canadian Arctic, in the vicinity of the Mackenzie River Delta, is characterized by long cold winters, short summers, low precipitation, thin organic soils, and ice-rich continuous permafrost. Over the last few decades, this region has undergone dramatic changes in climate, with warming air temperature and decreasing winter and summer precipitation. This has resulted in various landscape changes, including the warming of the upper layers of the permafrost, deepening of the active layer, drainage of permafrost affected lakes, an ongoing change from tundra to shrub tundra, and earlier spring breakup of streams, rivers and lakes. However, interactions between climate, hydrology, snow, and vegetation greatly affect both the spatial and temporal changes to the permafrost and hydrology of this region. Knowledge of these changes is important to the understanding of methane dynamics in this permafrost landscape, and for predicting future changes. Two examples of observed landscape change will be discussed. First, ground based observations and analysis of air photo images has demonstrated that shrub expansion is not uniform across the landscape, but instead is characterized by shrub patches of varying size. This patchiness is likely related to existing variations in soil temperature and moisture, active layer depth, snowcover, and tundra fires. As shrub patches further develop, they impact soil temperature and active layer depth. For example, small patches of shrubs typically have snow depths that are deeper than surrounding tundra areas due to the accumulation of blowing snow, and as a result have much warmer soil temperatures and deeper active layers. In contrast to these small shrub patches, large shrub patches have snow depths only slightly larger than found in the surrounding tundra and therefore only slightly warmer winter soil temperatures. However, shading of the surface during the summer may result in cooler summer soil temperatures. The overall effect of large shrub patches may be either deeper or shallower active layer depths than the surrounding tundra areas, depending on the leaf area index, the degree of shrub bending during the winter, and snow accumulation. Second, in contrast to many areas in Alaska and Siberia where increased rates of lake drainage have been reported, the rate of lake drainage in the Western Canadian Arctic has been decreasing over the past 50 years. The primary factors causing lake drainage in this region are high lake levels and winter cracking of ice wedges in the area immediately around the lake. Hydrologic modelling has suggested that summer lake levels have not changed significantly over the last 50 years, and therefore are not responsible for the decrease in drainage. However, the role of factors such as snow dams at lake outlets that result in high spring water levels, or the offsetting factors of warmer, but less snowy winters on ice wedge cracking are not well understood. As a result, further research is required to better understand how these lakes will respond to future changes in climate. Given the potential changes to methane dynamics in areas of changing permafrost, there is an urgent need to better understand ongoing, and future, changes in the landscape of these permafrost regions.

Comparison of reproduce signal and noise of conventional and keepered CoCrTa/Cr thin film media

NASA Astrophysics Data System (ADS)

Sin, Kyusik; Ding, Juren; Glijer, Pawel; Sivertsen, John M.; Judy, Jack H.; Zhu, Jian-Gang

1994-05-01

We studied keepered high coercivity CoCrTa/Cr thin film media with a Cr isolation layer between the CoCrTa storage and an overcoating of an isotropic NiFe soft magnetic layer. The influence of the thickness of the NiFe and Cr layers, and the effects of head bias current on the signal output and noise, were studied using a thin film head. The reproduced signal increased by 7.3 dB, but the signal-to-noise ratio decreased by 4 dB at a linear density of 2100 fr/mm (53.3 kfr/in.) with a 1000 Å thick NiFe keeper layer. The medium noise increased with increasing NiFe thickness and the signal output decreased with decreasing Cr thickness. A low output signal obtained with very thin Cr may be due to magnetic interactions between the keeper layer and magnetic media layer. It is observed that signal distortion and timing asymmetry of the output signals depend on the thickness of the keeper layer and the head bias current. The signal distortion increased and the timing asymmetry decreased as the head bias current was increased. These results may be associated with different permeability of the keeper under the poles of the thin film head due to the superposition of head bias and bit fields.

Multiple-layered effective medium approximation approach to modeling environmental effects on alumina passivated highly porous silicon nanostructured thin films measured by in-situ Mueller matrix ellipsometry

NASA Astrophysics Data System (ADS)

Mock, Alyssa; Carlson, Timothy; VanDerslice, Jeremy; Mohrmann, Joel; Woollam, John A.; Schubert, Eva; Schubert, Mathias

2017-11-01

Optical changes in alumina passivated highly porous silicon slanted columnar thin films during controlled exposure to toluene vapor are reported. Electron-beam evaporation glancing angle deposition and subsequent atomic layer deposition are utilized to deposit alumina passivated nanostructured porous silicon thin films. In-situ Mueller matrix generalized spectroscopic ellipsometry in an environmental cell is then used to determine changes in optical properties of the nanostructured thin films by inspection of individual Mueller matrix elements, each of which exhibit sensitivity to adsorption. The use of a multiple-layered effective medium approximation model allows for accurate description of the inhomogeneous nature of toluene adsorption onto alumina passivated highly porous silicon slanted columnar thin films.

Effect of Selectively Etched Ferroelectric Thin-Film Layer on the Performance of a Tunable Bandpass Filter

NASA Technical Reports Server (NTRS)

Subramanyam, Guru; Vignesparamoorthy, Sivaruban; Mueller, Carl; VanKeuls, Fred; Warner, Joseph; Miranda, Felix A.

2001-01-01

The main purpose of this work is to study the effect of a selectively etched ferroelectric thin film layer on the performance of an electrically tunable filter. An X-band tunable filter was designed, fabricated and tested on a selectively etched Barium Strontium Titanate (BSTO) ferroelectric thin film layer. Tunable filters with varying lengths of BSTO thin-film in the input and output coupling gaps were modeled, as well as experimentally tested. Experimental results showed that filters with coupling gaps partially filled with BSTO maintained frequency tunability and improved the insertion loss by approx. 2dB. To the best of our knowledge, these results represent the first experimental demonstration of the advantages of selective etching in the performance of thin film ferroelectric-based tunable microwave components.

Surface layer formation of LiCoO2 thin film electrodes in non-aqueous electrolyte containing lithium bis(oxalate)borate

NASA Astrophysics Data System (ADS)

Matsui, Masaki; Dokko, Kaoru; Akita, Yasuhiro; Munakata, Hirokazu; Kanamura, Kiyoshi

2012-07-01

Surface layer formation processes on a LiCoO2 thin film electrode in a non-aqueous electrolyte containing lithium bis(oxalate)borate (LiBOB) were investigated using in situ FTIR spectroscopy and X-ray photoelectron spectroscopy (XPS). The in situ FTIR spectra of the electrolyte solution containing LiBOB showed that the adsorption of BOB anions on the electrode surface occurred during the charge process of the LiCoO2 thin film electrode above 4.0 V. XPS analysis for the LiCoO2 thin film electrode charged in an electrolyte containing LiBOB suggested that the adsorbed BOB anions on the electrode surface prevent the continuous decomposition of hexafluorophosphate (PF6) anions resulting in the formation of a very thin surface layer containing organic species, while the LiCoO2 charged in a LiPF6 solution had a relatively thick surface layer containing organic species and inorganic species.

Nanofiber based triple layer hydro-philic/-phobic membrane - a solution for pore wetting in membrane distillation

PubMed Central

Prince, J. A.; Rana, D.; Matsuura, T.; Ayyanar, N.; Shanmugasundaram, T. S.; Singh, G.

2014-01-01

The innovative design and synthesis of nanofiber based hydro-philic/phobic membranes with a thin hydro-phobic nanofiber layer on the top and a thin hydrophilic nanofiber layer on the bottom of the conventional casted micro-porous layer which opens up a solution for membrane pore wetting and improves the pure water flux in membrane distillation. PMID:25377488

[Change characteristics of soil moisture and nutrients in rain-fed winter wheat field under different fertilization modes in Southern Shanxi of China during summer fallow period].

PubMed

Li, Ting-Liang; Xie, Ying-He; Hong, Jian-Ping; Feng, Qian; Sun, Cheng-Hong; Wang, Zhi-Wei

2013-06-01

In 2009-2011, a field experiment was conducted in a rain-fed winter wheat field in Southern Shanxi of China to study the effects of different fertilization modes on the change characteristics of soil moisture and nitrate-N contents in 0-200 cm layer and of soil available phosphorus (Oslen-P) and potassium contents in 0-40 cm layer during summer fallow period (from June to September). Three fertilization modes were installed, i. e., conventional fertilization (CF), recommended fertilization (RF), and ridge film furrow planting (RFFP) combined with straw mulch. The results showed that the rainfall in summer fallow period could complement the consumed water in 0-200 cm soil layer in dryland wheat field throughout the growth season, and more than 94% of the water storage was in 0-140 cm soil layer, with the fallow efficiency ranged from 6% to 27%. The rainfall in summer fallow period caused the soil nitrate-N moving downward. 357-400 mm rainfall could make the soil nitrate-N leaching down to 100 cm soil layer, with the peak in 20-40 cm soil layer. Straw mulching or plastic film with straw mulch in summer fallow period could effectively increase the Oslen-P and available K contents in 0-40 cm soil layer, and the accumulative increment in three summer fallow periods was 16-45% and 36-49%, respectively. Among the three modes, the binary coverage mode of RFFP plus furrow straw mulching had the best effect in maintaining soil water and fertility. The accumulative water storage and mineral N in 0-200 cm soil layer in three summer fallow periods were up to 215 mm and 90 kg x hm(-2), and the accumulative Oslen-P and available K contents in plough layer were increased by 2.7 mg x kg(-1) and 83 mg x kg(-1), respectively, being significantly higher than those in treatments CF and RF. There were no significant differences in the change characteristics in the soil moisture and nutrients between treatments CF and RF.

Burning Graphene Layer-by-Layer

PubMed Central

Ermakov, Victor A.; Alaferdov, Andrei V.; Vaz, Alfredo R.; Perim, Eric; Autreto, Pedro A. S.; Paupitz, Ricardo; Galvao, Douglas S.; Moshkalev, Stanislav A.

2015-01-01

Graphene, in single layer or multi-layer forms, holds great promise for future electronics and high-temperature applications. Resistance to oxidation, an important property for high-temperature applications, has not yet been extensively investigated. Controlled thinning of multi-layer graphene (MLG), e.g., by plasma or laser processing is another challenge, since the existing methods produce non-uniform thinning or introduce undesirable defects in the basal plane. We report here that heating to extremely high temperatures (exceeding 2000 K) and controllable layer-by-layer burning (thinning) can be achieved by low-power laser processing of suspended high-quality MLG in air in “cold-wall” reactor configuration. In contrast, localized laser heating of supported samples results in non-uniform graphene burning at much higher rates. Fully atomistic molecular dynamics simulations were also performed to reveal details of oxidation mechanisms leading to uniform layer-by-layer graphene gasification. The extraordinary resistance of MLG to oxidation paves the way to novel high-temperature applications as continuum light source or scaffolding material. PMID:26100466

Polymer mediated layer-by-layer assembly of different shaped gold nanoparticles.

PubMed

Budy, Stephen M; Hamilton, Desmond J; Cai, Yuheng; Knowles, Michelle K; Reed, Scott M

2017-02-01

Gold nanoparticles (GNPs) have a wide range of properties with potential applications in electronics, optics, catalysis, and sensing. In order to demonstrate that dense, stable, and portable samples could be created for these applications, multiple layers of GNPs were assembled via drop casting on glass substrates by layer-by-layer (LBL) techniques. Two cationic polyelectrolytes, poly(diallyldimethylammonium chloride) and polyethyleneimine, one anionic polyelectrolyte, poly(sodium 4-styrene sulfonate), and one neutral polymer, polyvinylpyrrolidone, were combined with four different shapes of GNPs (spherical, rod, triangular prismatic, and octahedral) to prepare thin films. A subset of these polymer nanoparticle combinations were assembled into thin films. Synthesized GNPs were characterized via dynamic light scattering, UV-vis spectroscopy, and transmission electron microscopy and the LBL thin films were characterized using UV-vis spectroscopy and atomic force microscopy. Sensing applications of the nanoparticles in solution and thin films were tested by monitoring the localized surface plasmon resonance of the GNPs. LBL thin films were prepared ranging from 25 to 100 layers with optical densities at plasmon from 0.5 to 3.0. Sensitivity in solutions ranged from 14 to 1002nm/refractive index units (RIU) and films ranged from 18.8 to 135.1nm/RIU suggesting reduced access to the GNPs within the films. Copyright © 2016 Elsevier Inc. All rights reserved.

Stepwise crystallization and the layered distribution in crystallization kinetics of ultra-thin poly(ethylene terephthalate) film

NASA Astrophysics Data System (ADS)

Zuo, Biao; Xu, Jianquan; Sun, Shuzheng; Liu, Yue; Yang, Juping; Zhang, Li; Wang, Xinping

2016-06-01

Crystallization is an important property of polymeric materials. In conventional viewpoint, the transformation of disordered chains into crystals is usually a spatially homogeneous process (i.e., it occurs simultaneously throughout the sample), that is, the crystallization rate at each local position within the sample is almost the same. Here, we show that crystallization of ultra-thin poly(ethylene terephthalate) (PET) films can occur in the heterogeneous way, exhibiting a stepwise crystallization process. We found that the layered distribution of glass transition dynamics of thin film modifies the corresponding crystallization behavior, giving rise to the layered distribution of the crystallization kinetics of PET films, with an 11-nm-thick surface layer having faster crystallization rate and the underlying layer showing bulk-like behavior. The layered distribution in crystallization kinetics results in a particular stepwise crystallization behavior during heating the sample, with the two cold-crystallization temperatures separated by up to 20 K. Meanwhile, interfacial interaction is crucial for the occurrence of the heterogeneous crystallization, as the thin film crystallizes simultaneously if the interfacial interaction is relatively strong. We anticipate that this mechanism of stepwise crystallization of thin polymeric films will allow new insight into the chain organization in confined environments and permit independent manipulation of localized properties of nanomaterials.

Stepwise crystallization and the layered distribution in crystallization kinetics of ultra-thin poly(ethylene terephthalate) film

DOE Office of Scientific and Technical Information (OSTI.GOV)

Zuo, Biao, E-mail: chemizuo@zstu.edu.cn, E-mail: wxinping@yahoo.com; Xu, Jianquan; Sun, Shuzheng

2016-06-21

Crystallization is an important property of polymeric materials. In conventional viewpoint, the transformation of disordered chains into crystals is usually a spatially homogeneous process (i.e., it occurs simultaneously throughout the sample), that is, the crystallization rate at each local position within the sample is almost the same. Here, we show that crystallization of ultra-thin poly(ethylene terephthalate) (PET) films can occur in the heterogeneous way, exhibiting a stepwise crystallization process. We found that the layered distribution of glass transition dynamics of thin film modifies the corresponding crystallization behavior, giving rise to the layered distribution of the crystallization kinetics of PET films,more » with an 11-nm-thick surface layer having faster crystallization rate and the underlying layer showing bulk-like behavior. The layered distribution in crystallization kinetics results in a particular stepwise crystallization behavior during heating the sample, with the two cold-crystallization temperatures separated by up to 20 K. Meanwhile, interfacial interaction is crucial for the occurrence of the heterogeneous crystallization, as the thin film crystallizes simultaneously if the interfacial interaction is relatively strong. We anticipate that this mechanism of stepwise crystallization of thin polymeric films will allow new insight into the chain organization in confined environments and permit independent manipulation of localized properties of nanomaterials.« less

Approximate transient and long time limit solutions for the band broadening induced by the thin sidewall-layer in liquid chromatography columns.

PubMed

Broeckhoven, Ken; Desmet, Gert

2007-11-16

Using a combination of both analytical and numerical techniques, approximate analytical expressions have been established for the transient and long time limit band broadening, originating from the presence of a thin disturbed sidewall layer in liquid chromatography columns, including packed, monolithic as well as microfabricated columns. The established expressions can be used to compare the importance of a thin disturbed sidewall layer with that of other radial heterogeneity effects (such as transcolumn packing density variations due to the relief of packing stresses). The expressions are independent of the actual velocity profile inside the layer as long as the disturbed sidewall layer occupies less than 2.5% of the column width.

Enhancement of absorption and color contrast in ultra-thin highly absorbing optical coatings

NASA Astrophysics Data System (ADS)

Kats, Mikhail A.; Byrnes, Steven J.; Blanchard, Romain; Kolle, Mathias; Genevet, Patrice; Aizenberg, Joanna; Capasso, Federico

2013-09-01

Recently a new class of optical interference coatings was introduced which comprises ultra-thin, highly absorbing dielectric layers on metal substrates. We show that these lossy coatings can be augmented by an additional transparent subwavelength layer. We fabricated a sample comprising a gold substrate, an ultra-thin film of germanium with a thickness gradient, and several alumina films. The experimental reflectivity spectra showed that the additional alumina layer increases the color range that can be obtained, in agreement with calculations. More generally, this transparent layer can be used to enhance optical absorption, protect against erosion, or as a transparent electrode for optoelectronic devices.

Tree thinning treatments alter soil properties, arbuscular mycorrhizal fungi and understory plant communities

Treesearch

Suzanne M. Neal

2007-01-01

Forest management practices designed to reduce fire risk, particularly thinning followed by burning slash piles, can cause below ground disturbance that creates favorable conditions for exotic plant species. Newer fuel-reduction methods, such as mechanical mastication are being examined as potential alternatives to the burning of slash piles. We compared soil...

Harvesting costs and environmental impacts associated with skyline yarding shelterwood harvests and thinning in Appalachian hardwoods

Treesearch

J. E. Baumgras; C. B. LeDoux; J. R. Sherar

1993-01-01

To evaluate the potential for moderating the visual impact and soil disturbance associated with timber harvesting on steep-slope hardwood sites, thinning and shelterwood harvests were conducted with a skyline yarding system. Operations were monitored to document harvesting production, residual stand damage, soil disturbance, and visual quality. Yarding costs for...

Soil Compaction Absent in Plantation Thinning

Treesearch

Tony King; Sharon Haines

1979-01-01

We examine the effects on soil bulk density by using a TH-105 Thinner Harvester and two forwarders in a mechanically thinned slash pine (Pinus elliottii Engelm.) plantation. Points in the machine tracks were sampled before and after harvesting at depths of 5 and 10 cm (2 and 4 in) for moisture and bulk density. Both the standard gravimetric method...

An Assessment of Soil Disturbance from Five Harvesting Intensities

Treesearch

John Klepac; Stephen E. Reutebuch; Robert B. Rummer

1999-01-01

Surface soil disturbance was compared among a commercial thinning, group selection, patch cut, 2-age, and clearcut. The thinning, group selection and patch cut units had significantly higher percentages of undisturbed area. The 2-age unit had a significantly higher percentage of area disturbed with litter in place. The clearcut unit had a significantly higher...

Effects of thinning intensities on transpiration and productivity of 50-year-old Pinus koraeinsis stands

NASA Astrophysics Data System (ADS)

Park, Juhan; Kim, Taekyu; Moon, Minkyu; Cho, Sungsik; Ryu, Daun; Kim, Hyun Seok

2015-04-01

This study investigated the effects of thinning intensities on stand transpiration and productivity of 50-year-old Korean pine forests for two years. Forest thinning, which removes some fraction of trees from stand, is widely conducted for reducing competition between remaining trees, improving tree productivity, reducing the risk of natural fire, and thus maintaining healthy forest. Forest thinning alters the microclimatic conditions such as radiation distribution within canopy, vapor pressure deficit, and amount of available soil water. These changes influence on the tree water use, and related productivity. Thinning was conducted on March, 2012 with two intensities (Control, Light-thinning (20%), and Heavy-thinning (40% of tree density)). Transpiration was estimated from sap flux density, which was measured with Granier-type thermal dissipation sensors. Tree diameter growth was measured with dendrometer, and converted to tree productivity using allometric equations developed specifically in our study sites. The climatic conditions showed little differences between two years. During the first growing season after thinning, stand transpiration was ca. 20% and 42% lower on light-thinning and heavy-thinning stand, respectively, even though sap flux density were higher in thinned stand. The difference in stand transpiration among treatments showed seasonal trends, so it was larger on summer when soil moisture was abundant due to monsoon, but was diminished on spring and autumn when soil moisture was limited. Tree-level productivity increased ca. 8% and 21% on light-thinning and heavy thinning stand, respectively. However, stand net primary production was ca. 20% lower on light-thinning stand, and ca. 31% on heavy-thinning stand. As a result, water use efficiency increased only in heavy-thinning stand. During the second growing season after thinning, stand transpiration was ca. 19% lower on light-thinning stand, and ca. 37% lower on heavy-thinning stand. The reduction of stand transpiration difference in heavy-thinning stand was caused mainly by increase in sap flux density. Trees in thinned stand showed higher productivity, but the magnitude was ca. 4% on light-thinning stand, and ca. 27% on heavy-thinning stand. Stand net primary production was ca. 23% lower on light-thinning stand, and ca. 28% on heavy-thinning stand. As a result, heavy-thinning stand showed highest water use efficiency. These results indicate that there are differences in biological reactions with thinning intensities.

High Performance 50 nm InAlAs/In0.75GaAs Metamorphic High Electron Mobility Transistors with Si3N4 Passivation on Thin InGaAs Layer

NASA Astrophysics Data System (ADS)

Yeon, Seongjin; Seo, Kwangseok

2008-04-01

We fabricated 50 nm InAlAs/InGaAs metamorphic high electron mobility transistors (HEMTs) with a very thin barrier. Through the reduction of the gate-channel distance (dGC) in the epitaxial structure, a channel aspect ratio (ARC) of over three was achieved when Lg was 50 nm. We inserted a thin InGaAs layer as a protective layer, and tested various gate structures to reduce surface problems induced by barrier shrinkage and to optimize the device characteristics. Through the optimization of the gate structure with the thin InGaAs layer, the fabricated 50 nm metamorphic HEMT exhibited high DC and RF characteristics, Gm of 1.5 S/mm, and fT of 490 GHz.

Frontally eluted components procedure with thin layer chromatography as a mode of sample preparation for high performance liquid chromatography quantitation of acetaminophen in biological matrix.

PubMed

Klimek-Turek, A; Sikora, M; Rybicki, M; Dzido, T H

2016-03-04

A new concept of using thin-layer chromatography to sample preparation for the quantitative determination of solute/s followed by instrumental techniques is presented Thin-layer chromatography (TLC) is used to completely separate acetaminophen and its internal standard from other components (matrix) and to form a single spot/zone containing them at the solvent front position (after the final stage of the thin-layer chromatogram development). The location of the analytes and internal standard in the solvent front zone allows their easy extraction followed by quantitation by HPLC. The exctraction procedure of the solute/s and internal standard can proceed from whole solute frontal zone or its part without lowering in accuracy of quantitative analysis. Copyright © 2016 Elsevier B.V. All rights reserved.

Thin layer drying of cassava starch using continuous vibrated fluidized bed dryer

NASA Astrophysics Data System (ADS)

Suherman, Trisnaningtyas, Rona

2015-12-01

This paper present the experimental work and thin layer modelling of cassava starch drying in continuous vibrated fluidized bed dryer. The experimental data was used to validate nine thin layer models of drying curve. Cassava starch with 0.21 initial moisture content was dried in different air drying temperature (50°C, 55°C, 60°C, 65°C, 70°C), different weir height in bed (0 and 1 cm), and different solid feed flow (10 and 30 gr.minute-1). The result showed air dryer temperature has a significant effect on drying curve, while the weir height and solid flow rate are slightly. Based on value of R2, χ2, and RMSE, Page Model is the most accurate simulation for thin layer drying model of cassava starch.

Fabrication of nanocrystal ink based superstrate-type CuInS₂ thin film solar cells.

PubMed

Cho, Jin Woo; Park, Se Jin; Kim, Woong; Min, Byoung Koun

2012-07-05

A CuInS₂ (CIS) nanocrystal ink was applied to thin film solar cell devices with superstrate-type configuration. Monodispersed CIS nanocrystals were synthesized by a colloidal synthetic route and re-dispersed in toluene to form an ink. A spray method was used to coat CIS films onto conducting glass substrates. Prior to CIS film deposition, TiO₂ and CdS thin films were also prepared as a blocking layer and a buffer layer, respectively. We found that both a TiO₂ blocking layer and a CdS buffer layer are necessary to generate photoresponses in superstrate-type devices. The best power conversion efficiency (∼1.45%) was achieved by the CIS superstrate-type thin film solar cell device with 200 and 100 nm thick TiO₂ and CdS films, respectively.

Synthesis and Characterization of Hydrophobic Silica Thin Layer Derived from Methyltrimethoxysilane (MTMS)

NASA Astrophysics Data System (ADS)

Darmawan, Adi; Utari, Riyadini; Eka Saputra, Riza; Suhartana; Astuti, Yayuk

2018-01-01

This study investigated the synthesis and characterization of MTMS hydrophobic silica prepared by sol-gel method. In principle, silica xerogels and silica thin layer were obtained by reacting MTMS in ethanol solvent in some pH variations. The MTMS solution was used to modify the surface of the ceramic plate by dipcoating method to further be calcined at two different temperatures of 350°C and 500°C. The silica xerogels were analysed by FTIR, TGA-DSC and GSA to determine functional group characteristics, thermal properties and pore morphology respectively. Meanwhile, the silica thin layers were analysed their hydrophobic properties using water contact angle measurement and surface roughness determination using SEM. The results showed that the higher the pH used in the MTMS solution, the higher the resulting contact angle. The highest contact angle was obtained at pH 8.12 which reached 94.7° and 79.5° for silica thin layer calcined at 350°C and 500°C, respectively. The TGA results indicated that the methyl group survived up to 400°C and disappeared at 500°C which had implications on silica thin layer hydrophobic nature. GSA result exhibited that the silica xerogel had a close structure with a very low pore volume. While the SEM-EDX results displayed that the silica thin layer prepared at acidic pH had smoother surface morphology and became rough when prepared at an alkaline pH.

Distinct temperature sensitivity of soil carbon decomposition in forest organic layer and mineral soil

PubMed Central

Xu, Wenhua; Li, Wei; Jiang, Ping; Wang, Hui; Bai, Edith

2014-01-01

The roles of substrate availability and quality in determining temperature sensitivity (Q10) of soil carbon (C) decomposition are still unclear, which limits our ability to predict how soil C storage and cycling would respond to climate change. Here we determined Q10 in surface organic layer and subsurface mineral soil along an elevation gradient in a temperate forest ecosystem. Q10 was calculated by comparing the times required to respire a given amount of soil C at 15 and 25°C in a 350-day incubation. Results indicated that Q10 of the organic layer was 0.22–0.71 (absolute difference) higher than Q10 of the mineral soil. Q10 in both the organic layer (2.5–3.4) and the mineral soil (2.1–2.8) increased with decreasing substrate quality during the incubation. This enhancement of Q10 over incubation time in both layers suggested that Q10 of more labile C was lower than that of more recalcitrant C, consistent with the Arrhenius kinetics. No clear trend of Q10 was found along the elevation gradient. Because the soil organic C pool of the organic layer in temperate forests is large, its higher temperature sensitivity highlights its importance in C cycling under global warming. PMID:25270905

Enhanced biogeochemical cycling and subsequent reduction of hydraulic conductivity associated with soil-layer interfaces in the vadose zone

PubMed Central

Hansen, David J.; McGuire, Jennifer T.; Mohanty, Binayak P.

2013-01-01

Biogeochemical dynamics in the vadose zone are poorly understood due to the transient nature of chemical and hydrologic conditions, but are nonetheless critical to understanding chemical fate and transport. This study explored the effects of a soil layer on linked geochemical, hydrological, and microbiological processes. Three laboratory soil columns were constructed: a homogenized medium-grained sand, a homogenized organic-rich loam, and a sand-over-loam layered column. Upward and downward infiltration of water was evaluated during experiments to simulate rising water table and rainfall events respectively. In-situ collocated probes measured soil water content, matric potential, and Eh while water samples collected from the same locations were analyzed for Br−, Cl−, NO3−, SO42−, NH4+, Fe2+, and total sulfide. Compared to homogenous columns, the presence of a soil layer altered the biogeochemistry and water flow of the system considerably. Enhanced biogeochemical cycling was observed in the layered column over the texturally homogeneous soil columns. Enumerations of iron and sulfate reducing bacteria showed 1-2 orders of magnitude greater community numbers in the layered column. Mineral and soil aggregate composites were most abundant near the soil-layer interface; the presence of which, likely contributed to an observed order-of-magnitude decrease in hydraulic conductivity. These findings show that quantifying coupled hydrologic-biogeochemical processes occurring at small-scale soil interfaces is critical to accurately describing and predicting chemical changes at the larger system scale. Findings also provide justification for considering soil layering in contaminant fate and transport models because of its potential to increase biodegradation and/or slow the rate of transport of contaminants. PMID:22031578

Total Synthesis of Ionic Liquid Systems for Dissolution of Lunar Simulant

NASA Technical Reports Server (NTRS)

Sharpe, Robert J.; Karr, Laurel J.; Paley, Mark S.

2010-01-01

For purposes of Space Resource Utilization, work in the total synthesis of a new ionic liquid system for the extraction of oxygen and metals from lunar soil is studied and described. Reactions were carried out according to procedures found in the chemical literature, analyzed via Thin-Layer Chromatography and 1H Nuclear Magnetic Resonance Spectroscopy and purified via vacuum distillation and rotary evaporation. Upon final analysis via 1H NMR, it was found that while the intermediates of the synthesis had been achieved, unexpected side products were also present. The mechanisms and constraints of the synthesis are described as well as the final results of the project and recommendations for continued study

Composite lamination method

NASA Technical Reports Server (NTRS)

Dickerson, G. E. (Inventor)

1977-01-01

A process was developed for preparing relatively thick composite laminate structure wherein thin layers of prepreg tapes are assembled, these thin layers are cut into strips that are partially cured, and stacked into the desired thickness with uncured prepreg disposed between each layer of strips. The formed laminate is finally cured and thereafter machined to the desired final dimensions.

Bioremediation of pesticide wastes in soil using two plant species, Kochia Scoparia and Brassica Napus

DOE Office of Scientific and Technical Information (OSTI.GOV)

Kruger, E.L.; Anderson, T.A.; Coats, J.R.

1995-12-31

Radiotracer studies were conducted to determine the fate of atrazine and metolachlor, applied as a mixture, in soils taken from pesticide-contaminated sites. Samples taken from nonvegetated areas and from the rhizosphere of Kochia scoparia were treated with {sup 14}C-atrazine and unlabeled metolachlor (50 {mu}g/g each) and incubated for 30, 60 or 135 d. A mass balance of the {sup 14}C applied revealed significant differences between the two soil types in soil bound residues, {sup 14}CO{sub 2}, and the extractable organic fraction (p<0.05). After 135-d incubation, 28% of the applied {sup 14}C was mineralized in Kochia rhizosphere soil, compared to 4%more » in soil taken from a nonvegetated area. A greater amount of {sup 14}C was extractable from the nonvegetated soil compared to the rhizosphere soil (64% and 22%, respectively). The half-life of atrazine based on extractable {sup 14}C-atrazine was 193 d in nonvegetated soil and 50 d in Kochia rhizosphere soil. Additional subsamples of nonvegetated soils treated with a mixture of {sup 14}C-atrazine and metolachlor were allowed to age for 135 d, and then were either planted with Brassica napus, Kochia scoparia, or left unvegetated. Incubations were carried out in enclosed chambers under controlled conditions. After 30 additional days, a subset of samples was extracted and analyzed using thin-layer chromatography, soil and plant combustion, and liquid scintillation spectroscopy. The percent of applied {sup 14}C-atrazine remaining as atrazine in soil which was nonvegetated, or planted with Brassica napus or Kochia scoparia was 9.3, 6.5, and 4.2%, respectively. Combustion of plants revealed that 11% of the applied radioactivity was taken up in Kochia scoparia, while less than 1% was taken up in Brassica napus plants. The potential for vegetation to aid in bioremediating pesticide wastes in soil is promising.« less

A Step toward High-Energy Silicon-Based Thin Film Lithium Ion Batteries.

PubMed

Reyes Jiménez, Antonia; Klöpsch, Richard; Wagner, Ralf; Rodehorst, Uta C; Kolek, Martin; Nölle, Roman; Winter, Martin; Placke, Tobias

2017-05-23

The next generation of lithium ion batteries (LIBs) with increased energy density for large-scale applications, such as electric mobility, and also for small electronic devices, such as microbatteries and on-chip batteries, requires advanced electrode active materials with enhanced specific and volumetric capacities. In this regard, silicon as anode material has attracted much attention due to its high specific capacity. However, the enormous volume changes during lithiation/delithiation are still a main obstacle avoiding the broad commercial use of Si-based electrodes. In this work, Si-based thin film electrodes, prepared by magnetron sputtering, are studied. Herein, we present a sophisticated surface design and electrode structure modification by amorphous carbon layers to increase the mechanical integrity and, thus, the electrochemical performance. Therefore, the influence of amorphous C thin film layers, either deposited on top (C/Si) or incorporated between the amorphous Si thin film layers (Si/C/Si), was characterized according to their physical and electrochemical properties. The thin film electrodes were thoroughly studied by means of electrochemical impedance spectroscopy, Raman spectroscopy, X-ray photoelectron spectroscopy, and atomic force microscopy. We can show that the silicon thin film electrodes with an amorphous C layer showed a remarkably improved electrochemical performance in terms of capacity retention and Coulombic efficiency. The C layer is able to mitigate the mechanical stress during lithiation of the Si thin film by buffering the volume changes and to reduce the loss of active lithium during solid electrolyte interphase formation and cycling.

Design and construction control guidance for chemically stabilized pavement base layers.

DOT National Transportation Integrated Search

2013-12-01

A laboratory and field study was conducted related to chemically stabilized pavement layers, which is also : referred to as soil-cement. Soil-cement practices within MDOT related to Class 9C soils used for base layers : were evaluated in this report....

Testing conceptual and physically based soil hydrology schemes against observations for the Amazon Basin

NASA Astrophysics Data System (ADS)

Guimberteau, M.; Ducharne, A.; Ciais, P.; Boisier, J. P.; Peng, S.; De Weirdt, M.; Verbeeck, H.

2014-06-01

This study analyzes the performance of the two soil hydrology schemes of the land surface model ORCHIDEE in estimating Amazonian hydrology and phenology for five major sub-basins (Xingu, Tapajós, Madeira, Solimões and Negro), during the 29-year period 1980-2008. A simple 2-layer scheme with a bucket topped by an evaporative layer is compared to an 11-layer diffusion scheme. The soil schemes are coupled with a river routing module and a process model of plant physiology, phenology and carbon dynamics. The simulated water budget and vegetation functioning components are compared with several data sets at sub-basin scale. The use of the 11-layer soil diffusion scheme does not significantly change the Amazonian water budget simulation when compared to the 2-layer soil scheme (+3.1 and -3.0% in evapotranspiration and river discharge, respectively). However, the higher water-holding capacity of the soil and the physically based representation of runoff and drainage in the 11-layer soil diffusion scheme result in more dynamic soil water storage variation and improved simulation of the total terrestrial water storage when compared to GRACE satellite estimates. The greater soil water storage within the 11-layer scheme also results in increased dry-season evapotranspiration (+0.5 mm d-1, +17%) and improves river discharge simulation in the southeastern sub-basins such as the Xingu. Evapotranspiration over this sub-basin is sustained during the whole dry season with the 11-layer soil diffusion scheme, whereas the 2-layer scheme limits it after only 2 dry months. Lower plant drought stress simulated by the 11-layer soil diffusion scheme leads to better simulation of the seasonal cycle of photosynthesis (GPP) when compared to a GPP data-driven model based on eddy covariance and satellite greenness measurements. A dry-season length between 4 and 7 months over the entire Amazon Basin is found to be critical in distinguishing differences in hydrological feedbacks between the soil and the vegetation cover simulated by the two soil schemes. On average, the multilayer soil diffusion scheme provides little improvement in simulated hydrology over the wet tropical Amazonian sub-basins, but a more significant improvement is found over the drier sub-basins. The use of a multilayer soil diffusion scheme might become critical for assessments of future hydrological changes, especially in southern regions of the Amazon Basin where longer dry seasons and more severe droughts are expected in the next century.

Effects of different wetting layers on the growth of smooth ultra-thin silver thin films

NASA Astrophysics Data System (ADS)

Ni, Chuan; Shah, Piyush; Sarangan, Andrew M.

2014-09-01

Ultrathin silver films (thickness below 10 nm) are of great interest as optical coatings on windows and plasmonic devices. However, producing these films has been a continuing challenge because of their tendency to form clusters or islands rather than smooth contiguous thin films. In this work we have studied the effect of Cu, Ge and ZnS as wetting layers (1.0 nm) to achieve ultrasmooth thin silver films. The silver films (5 nm) were grown by RF sputter deposition on silicon and glass substrates using a few monolayers of the different wetting materials. SEM imaging was used to characterize the surface properties such as island formation and roughness. Also the optical properties were measured to identify the optical impact of the different wetting layers. Finally, a multi-layer silver based structure is designed and fabricated, and its performance is evaluated. The comparison between the samples with different wetting layers show that the designs with wetting layers which have similar optical properties to silver produce the best overall performance. In the absence of a wetting layer, the measured optical spectra show a significant departure from the model predictions, which we attribute primarily to the formation of clusters.

Durable high strength cement concrete topping for asphalt roads

NASA Astrophysics Data System (ADS)

Vyrozhemskyi, Valerii; Krayushkina, Kateryna; Bidnenko, Nataliia

2017-09-01

Work on improving riding qualities of pavements by means of placing a thin cement layer with high roughness and strength properties on the existing asphalt pavement were conducted in Ukraine for the first time. Such pavement is called HPCM (High Performance Cementitious Material). This is a high-strength thin cement-layer pavement of 8-9 mm thickness reinforced with metal or polymer fiber of less than 5 mm length. Increased grip properties are caused by placement of stone material of 3-5 mm fraction on the concrete surface. As a result of the research, the preparation and placement technology of high-strength cement thin-layer pavement reinforced with fiber was developed to improve friction properties of existing asphalt pavements which ensures their roughness and durability. It must be emphasized that HPCM is a fundamentally new type of thin-layer pavement in which a rigid layer of 10 mm thickness is placed on a non-rigid base thereby improving riding qualities of asphalt pavement at any season of a year.

[Soil basal respiration and enzyme activities in the root-layer soil of tea bushes in a red soil].

PubMed

Yu, Shen; He, Zhenli; Zhang, Rongguang; Chen, Guochao; Huang, Changyong

2003-02-01

Soil basal respiration potential, metabolic quotient (qCO2), and activities of urease, invertase and acid phosphomonoesterase were investigated in the root-layer of 10-, 40-, and 90-yr-old tea bushes grown on the same type of red soil. The soil daily basal respiration potential ranged from 36.23 to 58.52 mg.kg-1.d-1, and the potentials in the root-layer of 40- or 90-yr-old were greater than that of 10-yr old tea bushes. The daily qCO2, ranging from 0.30 to 0.68, was in the reverse trend. The activities of test three enzymes changed differently with tea bushes' age. Urease activity in the root-layer of all age tea bushes ranged from 41.48 to 47.72 mg.kg-1.h-1 and slightly decreased with tea bushes' age. Invertase activity was 189.29-363.40 mg.kg-1.h-1 and decreased with tea bushes' age, but its activity in the root-layer of 10-year old tea bushes was significantly greater than that in the root-layer soil of 40- or 90-year old tea bushes. Acid phosphomonoesterase activity (444.22-828.32 mg.kg-1.h-1) increased significantly with tea bushes' age. Soil basal respiration potential, qCO2 and activities of 3 soil enzymes were closely related to soil pH, soil organic carbon, total nitrogen and C/N ratio, total soluble phenol, and microbial biomass carbon, respectively.

Pedogenesis and paleoenvironmental records in the tephra-paleosol sequences of Central Mexico: micromorphometric indicators.

NASA Astrophysics Data System (ADS)

Diaz, Jaime; Solleiro, Elizabeth; Sedov, Sergey

2014-05-01

tepetates (hardened volcanic soils) in Mexico have been studied from an agronomic and mechanisms viewpoint, however due to their different origins have not been established mechanisms that link them to environmental studies. This paper uses morphometric tools to determine the origin of the Tepetates in Mexico, using them as indicators of environmental changes and periods of instability of the landscape. The Glacis de Buenavista is located mainly in the northwestern portion of the state of Morelos, between the parallels 18° 20'and 19° 08' north latitude and meridians 98° 37' and 99° 30' west, forming a piedmont relief caused by erosion-sedimentation phases of volcanic materials from the Sierra de Zempoala mainly, and that is a big fan of Pleistocene age. Covers an area of 202.7 km 2. The maximum altitude is in the north, 2600 m, and minimun in the south to the 970 m, with an average slope of 6 . The Glacis de Buenavista has soils cover which consists of Luvisols, Vertisols, and layers of Tepetates, Phaeozems and Luvisols, in particular, represent soils polycyclic polygenetic high degree of development that have been formed in the Holocene. The next question is what mechanisms control the presence of a floor or other unit that occurs in the area? Since the lateral boundaries between soil types are abrupt, which speaks of discontinuities in the processes that have given rise. The morphometric study was carried out in thins sections of the blocks of Tepetates undisturbed. The blocks were vacuum impregnated with polyester resin. The thins sections were scanned with an Epson scanner 7100 with high resolution 9600 dpi and 24 bit color depth and analyzed using Image Pro Plus 5.1 program. The stratigraphic control was performed by 14C dating of organic matter. The pedofeatures measured were roundness of soil fragments, matrix percentage, percentage of papules and porosity. Was also carried out a microscopic control using a microscope BX51 Olimpus pedofeatures observing the following: matrix, fabric, coating clay (cutan), nodules of iron, rock fragments, fragments of roots, charcoal, organic matter, papules (fragment coating of clay). The Tepetates contain primarily, within its matrix rounded fragments of Luvisol soil type, which also include charcoal evidence of wildfire that was in situ. When soils become devoid of vegetation, were susceptible to water erosion which caused lahar deposits were emplaced later and formed the current Tepetates. The morphometric studies show a clear mix of materials and low porosity in Tepetates, besides giving a numerical value to the round of the materials that were incorporated into the matrix, thus giving more strength to the theory that the origin of these, this area is characterized by mass movements and their subsequent hidroconsolidacion late Pleistocene early Holocene. The Tepetates ages show that the instability of the environment is presented in the Pleistocene-Holocene boundary where the period of greatest formation of different layers of Tepetates, after this are more stable periods which are developed soil cover type luvisol,

Spatial distribution of hydroxylamine and its role in aerobic N2O formation in a Norway spruce forest soil

NASA Astrophysics Data System (ADS)

Liu, S.; Weymann, D.; Gottselig, N.; Wiekenkamp, I.; Vereecken, H.; Brueggemann, N.

2014-12-01

Hydroxylamine (HA) as a crucial intermediate in the microbial oxidation of ammonium to nitrite (nitrification) is a potential precursor of abiotic N2O formation in the soil. However, the determination of HA concentration in natural soil samples has not been reported until now. Here, we determined the HA concentrations in organic (Oh) and mineral (Ah) layers of 135 soil samples collected from a spruce forest (Wüstebach, Eifel National Park, Germany) using a novel approach, based on the fast extraction of HA from the soil at a pH of 1.7, the oxidation of HA to N2O with Fe3+, and the analysis of produced N2O using gas chromatography (GC). Meanwhile, N2O emission rates were determined by means of aerobic laboratory incubations of 3-g soil in 22-mL vials. Subsequently, the spatial distribution of soil HA concentrations and N2O emission rates in the Oh and Ah layers of the whole sampling area were analyzed using a geostatistical approach. The correlations among soil HA, N2O emission rate, pH, soil C, N, Fe, Mn and soil water content (SWC) were further explored. The HA concentrations ranged from 0.3-44.6 μg N kg-1 dry soil and 0.02-16.2 μg N kg-1 dry soil in the Oh and the Ah layer, respectively. The spatial distribution of HA was similar in both layers, with substantial spatial variability dependent on soil type, tree density and distance to a stream. For example, HA concentration was greater at locations with a thick litter layer or at locations close to the stream. The average N2O emission rate in the Oh layer was 0.38 μg N kg-1 dry soil h-1, 10-fold larger than in the Ah layer. Interestingly, N2O emission rate exhibited high correlation with soil HA content in the Oh (R2 = 0.65, p < 0.01) and Ah (R2 = 0.45, p < 0.05) layer. The results demonstrated that HA is a crucial component for aerobic N2O formation and emission in spruce forest soils. Moreover, HA concentration was negatively correlated with pH and positively correlated with SWC in the Oh layer, while positively correlated with C and N as well as NO3- content in the Ah layer. Mn content was the most important factor for HA recovery at the specific extraction conditions. Further studies should focus on the effects of soil organic matter, Mn content, and pH on the production of N2O from HA under aerobic conditions.

[Nitrogen mineralization rate in different soil layers and its influence factors under plastic film mulched in Danjiangkou Reservoir area, China].

PubMed

Yu, Xing Xiu; Xui, Miao Miao; Zhao, Jin Hui; Zhang, Jia Peng; Wang, Wei; Guo, Ya Li; Xiao, Juan Hua

2018-04-01

The objective of this study was to investigate the rate of nitrogen mineralization in various soil layers (0-10, 10-20, and 20-30 cm) and its influencing factors under plastic film mulching ridge-furrow in a corn field of Wulongchi small watershed, Danjiangkou Reservoir Area. Results showed that the rate of soil ammonification decreased with soil depth during the entire maize growth period. The rate of nitrification in seedling, jointing, and heading stages decreased in the following order: 10-20 cm > 0-10 cm > 20-30 cm, while it increased with soil depth in maturation stage. The rate of soil nitrogen mineralization decreased with the increases in soil depth in the seedling, jointing and heading stages, whereas an opposite pattern was observed in maturation stage. Compared with non-filming, film mulching promoted the soil ammonification process in 0-10 cm and the soil nitrification and nitrogen mineralization processes in jointing, heading, and maturation stages in both 0-10 and 10-20 cm. However, the rates of soil nitrification and nitrogen mineralization under film mulching were much lower than those under non-filming in seedling stage. The stepwise regression analysis indicated that the main factors influencing soil nitrogen mineralization rate varied with soil depth. Soil moisture and total N content were the dominant controller for variation of soil nitrogen mineralization in 0-10 cm layer. Soil temperature, moisture, and total N content were dominant controller for that in 10-20 cm layer. Soil temperature drove the variation of soil nitrogen mineralization in 20-30 cm layer.

Biosurfactant production by halotolerant Rhodococcus fascians from Casey Station, Wilkes Land, Antarctica.

PubMed

Gesheva, Victoria; Stackebrandt, Erko; Vasileva-Tonkova, Evgenia

2010-08-01

Isolate A-3 from Antarctic soil in Casey Station, Wilkes Land, was characterized for growth on hydrocarbons. Use of glucose or kerosene as a sole carbon source in the culture medium favoured biosynthesis of surfactant which, by thin-layer chromatography, indicated the formation of a rhamnose-containing glycolipid. This compound lowered the surface tension at the air/water interface to 27 mN/m as well as inhibited the growth of B. subtilis ATCC 6633 and exhibited hemolytic activity. A highly hydrophobic surface of the cells suggests that uptake occurs via a direct cell-hydrocarbon substrate contact. Strain A-3 is Gram-positive, halotolerant, catalase positive, urease negative and has rod-coccus shape. Its cell walls contained meso-diaminopimelic acid. Phylogenetic analysis based on comparative analysis of 16S rRNA gene sequences revealed that strain A-3 is closely related to Rhodococcus fascians with which it shares 100% sequence similarity. This is the first report on rhamnose-containing biosurfactant production by Rhodococcus fascians isolated from Antarctic soil.

Metabolites of the phenylurea herbicides chlorotoluron, diuron, isoproturon and linuron produced by the soil fungus Mortierella sp.

PubMed

Badawi, Nora; Rønhede, Stig; Olsson, Stefan; Kragelund, Birthe B; Johnsen, Anders H; Jacobsen, Ole Stig; Aamand, Jens

2009-10-01

Phenylurea herbicides are used worldwide, and often pollute surface- and groundwater in concentrations exceeding the limit value for drinking water (0.1 microg l(-1)). Bacteria degrade phenylurea herbicides by successive N-dealkylation to substituted aniline products. Little is known about the corresponding fungal pathways, however. We here report degradation of chlorotoluron, diuron, isoproturon and linuron by the soil fungus Mortierella sp. Gr4. Degradation was fastest with linuron and resulted in successively dealkylated metabolites and 3,4-dichloroaniline. A major new metabolite was detected that has not yet been fully identified. Thin layer chromatography and nuclear magnetic resonance spectroscopy indicate that it is a non-aromatic diol. Degradation of isoproturon, chlorotoluron and diuron involved successive N-demethylation and, in the case of isoproturon and chlorotoluron, additional hydroxylation. A new hydroxylated isoproturon metabolite was detected. The study thus shows that the fungal pathways differ from the bacterial pathways and yield new metabolites of possible environmental concern.

Metabolic activity of permafrost bacteria below the freezing point

NASA Technical Reports Server (NTRS)

Rivkina, E. M.; Friedmann, E. I.; McKay, C. P.; Gilichinsky, D. A.

2000-01-01

Metabolic activity was measured in the laboratory at temperatures between 5 and -20 degrees C on the basis of incorporation of (14)C-labeled acetate into lipids by samples of a natural population of bacteria from Siberian permafrost (permanently frozen soil). Incorporation followed a sigmoidal pattern similar to growth curves. At all temperatures, the log phase was followed, within 200 to 350 days, by a stationary phase, which was monitored until the 550th day of activity. The minimum doubling times ranged from 1 day (5 degrees C) to 20 days (-10 degrees C) to ca. 160 days (-20 degrees C). The curves reached the stationary phase at different levels, depending on the incubation temperature. We suggest that the stationary phase, which is generally considered to be reached when the availability of nutrients becomes limiting, was brought on under our conditions by the formation of diffusion barriers in the thin layers of unfrozen water known to be present in permafrost soils, the thickness of which depends on temperature.

Should precipitation influence dust emission in global dust models?

NASA Astrophysics Data System (ADS)

Okin, Gregory

2016-04-01

Soil moisture modulates the threshold shear stress required to initiate aeolian transport and dust emission. Most of the theoretical and laboratory work that has confirmed the impact of soil moisture has appropriately acknowledged that it is the soil moisture of a surface layer a few grain diameters thick that truly controls threshold shear velocity. Global and regional models of dust emission include the effect of soil moisture on transport threshold, but most ignore the fact that only the moisture of the very topmost "active layer" matters. The soil moisture in the active layer can differ greatly from that integrated through the top 2, 5, 10, or 100 cm (surface layers used by various global models) because the top 2 mm of heavy texture soils dries within ~1/2 day while sandy soils dry within less than 2 hours. Thus, in drylands where dust emission occurs, it is likely that this top layer is drier than the underlying soil in the days and weeks after rain. This paper explores, globally, the time between rain events in relation to the time for the active layer to dry and the timing of high wind events. This analysis is carried out using the same coarse reanalyses used in global dust models and is intended to inform the soil moisture controls in these models. The results of this analysis indicate that the timing between events is, in almost all dust-producing areas, significantly longer than the drying time of the active layer, even when considering soil texture differences. Further, the analysis shows that the probability of a high wind event during the period after a rain where the surface is wet is small. Therefore, in coarse global models, there is little reason to include rain-derived soil moisture in the modeling scheme.

Uptake of Light Elements in Thin Metallic Films

NASA Astrophysics Data System (ADS)

Markwitz, Andreas; Waldschmidt, Mathias

Ion beam analysis was used to investigate the influence of substrate temperature on the inclusion of impurities during the deposition process of thin metallic single and double layers. Thin layers of gold and aluminium were deposited at different temperatures onto thin copper layers evaporated on silicon wafer substrates. The uptake of oxygen in the layers was measured using the highly sensitive non-resonant reaction 16O(d,p)170O at 920 keV. Nuclear reaction analysis was also used to probe for carbon and nitrogen with a limit of detection better than 20 ppm. Hydrogen depth profiles were measured using elastic recoil detection on the nanometer scale. Rutherford backscattering spectroscopy was used to determine the depth profiles of the metallic layers and to study diffusion processes. The combined ion beam analyses revealed an uptake of oxygen in the layers depending on the different metallic cap layers and the deposition temperature. Lowest oxygen values were measured for the Au/Cu layers, whereas the highest amount of oxygen was measured in Al/Cu layers deposited at 300°C. It was also found that with single copper layers produced at various temperatures, oxygen contamination occurred during the evaporation process and not afterwards, for example, as a consequence of the storage of the films under normal conditions for several days. Hydrogen, carbon, and nitrogen were found as impurities in the single and double layered metallic films, a finding that is in agreement with the measured oxidation behaviour of the metallic films.

Method of forming ultra thin film devices by vacuum arc vapor deposition

NASA Technical Reports Server (NTRS)

Schramm, Harry F. (Inventor)

2005-01-01

A method for providing an ultra thin electrical circuit integral with a portion of a surface of an object, including using a focal Vacuum Arc Vapor Deposition device having a chamber, a nozzle and a nozzle seal, depressing the nozzle seal against the portion of the object surface to create an airtight compartment in the chamber and depositing one or more ultra thin film layer(s) only on the portion of the surface of the object, the layers being of distinct patterns such that they form the circuit.

Non-destructive evaluation of nano-sized structure of thin film devices by using small angle neutron scattering.

PubMed

Shin, E J; Seong, B S; Choi, Y; Lee, J K

2011-01-01

Nano-sized multi-layers copper-doped SrZrO3, platinum (Pt) and silicon oxide (SiO2) on silicon substrates were prepared by dense plasma focus (DPF) device with the high purity copper anode tip and analyzed by using small angle neutron scattering (SANS) to establish a reliable method for the non-destructive evaluation of the under-layer structure. Thin film was well formed at the time-to-dip of 5 microsec with stable plasma of DPF. Several smooth intensity peaks were periodically observed when neutron beam penetrates the thin film with multi-layers perpendicularly. The platinum layer is dominant to intensity peaks, where the copper-doped SrZnO3 layer next to the platinum layer causes peak broadening. The silicon oxide layer has less effect on the SANS spectra due to its relative thick thickness. The SANS spectra shows thicknesses of platinum and copper-doped SrZnO3 layers as 53 and 25 nm, respectively, which are well agreement with microstructure observation.

[Soil moisture variation under different water and fertilization managements in apple orchard of Weibei dryland, China].

PubMed

Zhao, Zhi Yuan; Zheng, Wei; Liu, Jie; Ma, Peng Yi; Li, Zi Yan; Zhai, Bing Nian; Wang, Zhao Hui

2018-04-01

To evaluate the variations of soil moisture under different water and fertilizer treatments in apple orchard in the Weibei dryland, a field experiment was carried out in 2013-2016 at Tianjiawa Village, Baishui County, Shaanxi Province. There were three treatments, i.e., farmers traditional model (only addition of NPK chemical fertilizer, FM), extension model (swine manure and NPK chemical fertilizer combined with black plastic film in tree row space, EM), and optimized model (swine manure and NPK chemical fertilizer combined with black plastic film in tree row space and planting rape in the inter-row of apple trees, OM). The results showed that OM treatment significantly increased soil water storage capacity in 0-200 cm soil layer. Water content of 0-100 cm soil layer was increased by 5.6% and 15.3% in the dry season compared with FM and EM treatment, respectively. Moreover, the soil water relative deficit index of OM was lower than that of EM in 200-300 cm soil layer. The rainfall infiltration in the dry year could reach 300 cm depth under OM. Meanwhile, OM stabilized soil water content and efficiently alleviated the desiccation in deep soil layer. Compared with FM and EM, the 4-year average yield of OM was increased by 36.6% and 22.5%, respectively. In summary, OM could increase water use efficiency through increasing the contents of available soil water and improving the soil water condition in shallow and deep layers, which help alleviate the soil deficit in deep layer and increase yield.

Layer-by-layer deposition of nanostructured CsPbBr3 perovskite thin films

NASA Astrophysics Data System (ADS)

Reshetnikova, A. A.; Matyushkin, L. B.; Andronov, A. A.; Sokolov, V. S.; Aleksandrova, O. A.; Moshnikov, V. A.

2017-11-01

Layer-by-layer deposition of nanostructured perovskites cesium lead halide thin films is described. The method of deposition is based on alternate immersion of the substrate in the precursor solutions or colloidal solution of nanocrystals and methyl acetate/lead nitrate solution using the device for deposition of films by SILAR and dip-coating techniques. An example of obtaining a photosensitive structure based on nanostructures of ZnO nanowires and layers of CsBbBr3 nanocrystals is also shown.

Silicon superlattices. 2: Si-Ge heterostructures and MOS systems

NASA Technical Reports Server (NTRS)

Moriarty, J. A.

1983-01-01

Five main areas were examined: (1) the valence-and conduction-band-edge electronic structure of the thin layer ( 11 A) silicon-superlattice systems; (2) extension of thin-layer calculations to layers of thickness 11 A, where most potential experimental interest lies; (3) the electronic structure of thicker-layer (11 to 110 A) silicon superlattices; (4) preliminary calculations of impurity-scattering-limited electron mobility in the thicker-layer superlattices; and (5) production of the fine metal lines that would be required to produce on MOS superlattice.

Epitaxial thinning process

NASA Technical Reports Server (NTRS)

Siegel, C. M. (Inventor)

1984-01-01

A method is described for thinning an epitaxial layer of a wafer that is to be used in producing diodes having a specified breakdown voltage and which also facilitates the thinning process. Current is passed through the epitaxial layer, by connecting a current source between the substrate of the wafer and an electrolyte in which the wafer is immersed. When the wafer is initially immersed, the voltage across the wafer initially drops and then rises at a steep rate. When light is applied to the wafer the voltage drops, and when the light is interrupted the voltage rises again. These changes in voltage, each indicate the breakdown voltage of a Schottky diode that could be prepared from the wafer at that time. The epitaxial layer is thinned by continuing to apply current through the wafer while it is immersed and light is applied, to form an oxide film and when the oxide film is thick the wafer can then be cleaned of oxide and the testing and thinning continued. Uninterrupted thinning can be achieved by first forming an oxide film, and then using an electrolyte that dissolves the oxide about as fast as it is being formed, to limit the thickness of the oxide layer.

Vertical variation of a black soil's properties in response to freeze-thaw cycles and its links to shift of microbial community structure.

PubMed

Han, Ziming; Deng, Mingwen; Yuan, Anqi; Wang, Jiahui; Li, Hao; Ma, Jincai

2018-06-01

Soil freeze-thaw cycles (FTCs) change soil physical, chemical, and biological properties, however information regarding their vertical variations in response to FTCs is limited. In this work, black soil (silty loam) packed soil columns were exposed to 8 FTCs, and soil properties were determined for each of vertical layer of soil columns. The results revealed that after FTCs treatment, moisture and electrical conductivity (EC) salinity tended to increase in upper soil layers. Increments of ammonium nitrogen (NH 4 + -N) and nitrate nitrogen (NO 3 - -N) in top layers (0-10cm) were greater than those in other layers, and increments of water soluble organic carbon (WSOC) and decrease of microbial biomass carbon (MBC) in middle layers (10-20cm) were greater than those in both ends. Overall, microbial community structure was mainly influenced by soil physical properties (moisture and EC) and chemical properties (pH and WSOC). For bacterial (archaeal) and fungal communities, soil physical properties, chemical properties and their interaction explained 79.73% and 82.66% of total variation, respectively. Our results provided insights into the vertical variation of soil properties caused by FTCs, and such variation had a major impact on the change of structure and composition of soil bacterial and fungal communities. Copyright © 2017 Elsevier B.V. All rights reserved.

Variations in bacterial and fungal communities through soil depth profiles in a Betula albosinensis forest.

PubMed

Du, Can; Geng, Zengchao; Wang, Qiang; Zhang, Tongtong; He, Wenxiang; Hou, Lin; Wang, Yueling

2017-09-01

Microbial communities in subsurface soil are specialized for their environment, which is distinct from that of the surface communities. However, little is known about the microbial communities (bacteria and fungi) that exist in the deeper soil horizons. Vertical changes in microbial alpha-diversity (Chao1 and Shannon indices) and community composition were investigated at four soil depths (0-10, 10-20, 20-40, and 40-60 cm) in a natural secondary forest of Betula albosinensis by high-throughput sequencing of the 16S and internal transcribed spacer rDNA regions. The numbers of operational taxonomic units (OTUs), and the Chao1 and Shannon indices decreased in the deeper soil layers. Each soil layer contained both mutual and specific OTUs. In the 40-60 cm soil layer, 175 and 235 specific bacterial and fungal OTUs were identified, respectively. Acidobacteria was the most dominant bacterial group in all four soil layers, but reached its maximum at 40-60 cm (62.88%). In particular, the 40-60 cm soil layer typically showed the highest abundance of the fungal genus Inocybe (47.46%). The Chao1 and Shannon indices were significantly correlated with the soil organic carbon content. Redundancy analysis indicated that the bacterial communities were closely correlated with soil organic carbon content (P = 0.001). Collectively, these results indicate that soil nutrients alter the microbial diversity and relative abundance and affect the microbial composition.

Antimalarial activity of Bidens pilosa L. (Asteraceae) ethanol extracts from wild plants collected in various localities or plants cultivated in humus soil.

PubMed

Andrade-Neto, Valter F; Brandão, Maria G L; Oliveira, Francielda Q; Casali, Vicente W D; Njaine, Brian; Zalis, Mariano G; Oliveira, Luciana A; Krettli, Antoniana U

2004-08-01

Bidens pilosa (Asteraceae), a medicinal plant used worldwide, has antimalarial activity as shown in previous work. This study tested ethanol extracts from wild plants collected in three different regions of Brazil and from plants cultivated in various soil conditions. The extracts were active in mice infected with P. berghei: doses of < or =500 mg/kg administered by oral route reduced malaria parasitaemia and mouse mortality; higher doses were found to be less effective. Tested in vitro against three P. falciparum isolates, two chloroquine resistant and one mefloquine resistant, the plants cultivated under standard conditions, and in humus enriched soil, were active; but the wild plants were the most active. Analysis using thin layer chromatography demonstrated the presence of flavonoids (compounds considered responsible for the antimalarial activity) in all plants tested, even though at different profiles. Because B. pilosa is proven to be active against P. falciparum drug-resistant parasites in vitro, and in rodent malaria in vivo, it is a good candidate for pre-clinical tests as a phytotherapeutic agent or for chemical isolation of the active compounds with the aim of finding new antimalarial drugs. Copyright (c) 2004 John Wiley & Sons, Ltd.

Talc based exopolysaccharides formulation enhancing growth and production of Hellianthus annuus under saline conditions.

PubMed

Tewari, S; Arora, K

2014-12-24

Stress tolerating strain of Pseudomonas aeruginosa PF07 possessing plant growth promoting activity was screened for the production of exopolysaccharides (EPS). EPS production was monitored in the cell free culture supernatant (CFCS) and extracted EPS was further purified by thin layer chromatography. EPS producing cells were taken to design talc based formulation and its efficacy was checked on oilseed crop sunflower (Hellianthus annuus), under in vivo saline conditions (soil irrigated with 125 mM of saline water). Application of bioformulation significantly enhanced the yield and growth attributes of the plant in comparison to control (untreated seeds) under stress and non—stress conditions. Germination rate, plant length, dry weight and seed weight increased remarkably. The above findings suggest the application and benefits of utilizing EPS formulation in boosting early seedling emergence, enhancing plant growth parameters, increasing seed weight and mitigating stress in saline affected regions. Such bioformulation may enhance RAS/RT (Root Adhering Soil to Root Tissue ratio), texture of the soil, increase porosity, improve uptake of nutrients, and hence may be considered as commercially important formulation for renovation of stressed sites and enhancing plant growth.

Electrochemical planarization

DOEpatents

Bernhardt, A.F.; Contolini, R.J.

1993-10-26

In a process for fabricating planarized thin film metal interconnects for integrated circuit structures, a planarized metal layer is etched back to the underlying dielectric layer by electropolishing, ion milling or other procedure. Electropolishing reduces processing time from hours to minutes and allows batch processing of multiple wafers. The etched back planarized thin film interconnect is flush with the dielectric layer. 12 figures.

Relating results from earthworm toxicity tests to agricultural soil

USGS Publications Warehouse

Beyer, W.N.; Greig-Smith, P.W.

1992-01-01

The artificial soil tests of the European Economic Community and of the Organization for Economic Cooperation produce data relating earthworm mortality to pesticide concentrations in soil under laboratory conditions. To apply these results to agricultural soils it is necessary to relate these concentrations to amounts of pesticide applied per area. This paper reviews the relevant published literature and suggests a simple relation for regulatory use. Hazards to earthworms from pesticides are suggested to be greatest soon after application, when the pesticides may be concentrated in a soil layer a few millimeters thick. For estimating exposure of earthworms, however, a thicker soil layer should be considered, to account for their movement through soil. During favorable weather conditions, earthworms belonging to species appropriate to the artificial soil test have been reported to confine their activity to a layer about 5 cm. If a 5-cm layer is accepted as relevant for regulatory purposes, then an application of 1 kg/ha would be equivalent to 1-67 ppm (dry) in the artificial soil test.

Specific Features of Profile Distribution and Crystallochemistry of Phyllosilicates in Soils of the Cisbaikal Forest-Steppe

NASA Astrophysics Data System (ADS)

Chizhikova, N. P.; Gamzikov, G. P.; Chechetko, E. S.

2018-01-01

The mineralogical composition of agrogray, dark gray, and agro-dark gray soils (Luvic Greyzemic Retic Phaeozems); agro-dark gray residual-calcareous soils (Calcaric Cambic Phaeozems); clay-illuvial agrochernozems (Luvic Chernic Phaeozems); and agrochernozems with migrational-mycelial carbonates (Haplic Chernozems) developed in the forest-steppe of Central Siberia within the Irkutsk Depression has been studied. The clay (<1 μm) fraction separated from these soils consists of mixed-layer minerals with alternating layers of hydromica, smectite, vermiculite, and chlorite; the proportions between them change within the soil profiles. The clay fraction also contains hydromicas, kaolinite, chlorite, and some admixture of the fine-dispersed quartz. Each type of the soils is characterized by its own distribution pattern of clay material with specific alternation of layers in the mixed-layer formations. Mixed-layer minerals of the chlorite-vermiculite type predominate in the upper horizons of texture-differentiated soils. Down the soil profile, the content of mixed-layer mica-smectitic minerals increases. In the clay fraction of arable dark gray-humus soils with residual carbonates, the distribution of the clay fraction and major mineral phases in the soil profile is relatively even. An increased content of well-crystallized kaolinite is typical of these soils. The parent material of agrochernozems has a layered character: the upper horizons are generally depleted of clay, and the middle-profile and lower horizons are characterized by the considerable kaolinite content. In general, the clay material of soils of the Tulun-Irkutsk forest-steppe differs considerably from the clay material of foreststeppe soils developed from loesslike and mantle loams in the European part of Russia. In particular, this difference is seen in the proportions between major mineral phases and between biotitic and muscovitic components, as well as in the degree of crystallinity and behavior of kaolinite and chlorite.

Use of screenings to produce HMA mixtures

DOT National Transportation Integrated Search

2002-10-01

Thin-lift hot mix asphalt (HMA) layers are utilized in almost every maintenance and rehabilitation application. These mix types require smaller maximum particle sizes than most conventional HMA surface layers. Although the primary functions of thin-l...

[Ascending one-dimensional thin layer chromatography in specific blood diagnosis (author's transl)].

PubMed

Bernardelli, B; Masotti, G

1976-01-01

A brief review of the literature on chromatography in forensic haematology is followed by a report of the results obtained by using ascending one-dimensional thin layer chromatography in specific blood diagnosis.

Flat-lying semiconductor-insulator interfacial layer in DNTT thin films.

PubMed

Jung, Min-Cherl; Leyden, Matthew R; Nikiforov, Gueorgui O; Lee, Michael V; Lee, Han-Koo; Shin, Tae Joo; Takimiya, Kazuo; Qi, Yabing

2015-01-28

The molecular order of organic semiconductors at the gate dielectric is the most critical factor determining carrier mobility in thin film transistors since the conducting channel forms at the dielectric interface. Despite its fundamental importance, this semiconductor-insulator interface is not well understood, primarily because it is buried within the device. We fabricated dinaphtho[2,3-b:2',3'-f]thieno[3,2-b]thiophene (DNTT) thin film transistors by thermal evaporation in vacuum onto substrates held at different temperatures and systematically correlated the extracted charge mobility to the crystal grain size and crystal orientation. As a result, we identify a molecular layer of flat-lying DNTT molecules at the semiconductor-insulator interface. It is likely that such a layer might form in other material systems as well, and could be one of the factors reducing charge transport. Controlling this interfacial flat-lying layer may raise the ultimate possible device performance for thin film devices.

Bias of shear wave elasticity measurements in thin layer samples and a simple correction strategy.

PubMed

Mo, Jianqiang; Xu, Hao; Qiang, Bo; Giambini, Hugo; Kinnick, Randall; An, Kai-Nan; Chen, Shigao; Luo, Zongping

2016-01-01

Shear wave elastography (SWE) is an emerging technique for measuring biological tissue stiffness. However, the application of SWE in thin layer tissues is limited by bias due to the influence of geometry on measured shear wave speed. In this study, we investigated the bias of Young's modulus measured by SWE in thin layer gelatin-agar phantoms, and compared the result with finite element method and Lamb wave model simulation. The result indicated that the Young's modulus measured by SWE decreased continuously when the sample thickness decreased, and this effect was more significant for smaller thickness. We proposed a new empirical formula which can conveniently correct the bias without the need of using complicated mathematical modeling. In summary, we confirmed the nonlinear relation between thickness and Young's modulus measured by SWE in thin layer samples, and offered a simple and practical correction strategy which is convenient for clinicians to use.

AES study on the chemical composition of ferroelectric BaTiO3 thin films RF sputter-deposited on silicon

NASA Technical Reports Server (NTRS)

Dharmadhikari, V. S.; Grannemann, W. W.

1983-01-01

AES depth profiling data are presented for thin films of BaTiO3 deposited on silicon by RF sputtering. By profiling the sputtered BaTiO3/silicon structures, it was possible to study the chemical composition and the interface characteristics of thin films deposited on silicon at different substrate temperatures. All the films showed that external surface layers were present, up to a few tens of angstroms thick, the chemical composition of which differed from that of the main layer. The main layer had stable composition, whereas the intermediate film-substrate interface consisted of reduced TiO(2-x) oxides. The thickness of this intermediate layer was a function of substrate temperature. All the films showed an excess of barium at the interface. These results are important in the context of ferroelectric phenomena observed in BaTiO3 thin films.

Impact of bimetal electrodes on dielectric properties of TiO2 and Al-doped TiO2 films.

PubMed

Kim, Seong Keun; Han, Sora; Jeon, Woojin; Yoon, Jung Ho; Han, Jeong Hwan; Lee, Woongkyu; Hwang, Cheol Seong

2012-09-26

Rutile structured Al-doped TiO(2) (ATO) and TiO(2) films were grown on bimetal electrodes (thin Ru/thick TiN, Pt, and Ir) for high-performance capacitors. The work function of the top Ru layer decreased on TiN and increased on Pt and Ir when it was thinner than ~2 nm, suggesting that the lower metal within the electrodes influences the work function of the very thin Ru layer. The use of the lower electrode with a high work function for bottom electrode eventually improves the leakage current properties of the capacitor at a very thin Ru top layer (≤2 nm) because of the increased Schottky barrier height at the interface between the dielectric and the bottom electrode. The thin Ru layer was necessary to achieve the rutile structured ATO and TiO(2) dielectric films.

Fuel cell with interdigitated porous flow-field

DOEpatents

Wilson, Mahlon S.

1997-01-01

A polymer electrolyte membrane (PEM) fuel cell is formed with an improved system for distributing gaseous reactants to the membrane surface. A PEM fuel cell has an ionic transport membrane with opposed catalytic surfaces formed thereon and separates gaseous reactants that undergo reactions at the catalytic surfaces of the membrane. The fuel cell may also include a thin gas diffusion layer having first and second sides with a first side contacting at least one of the catalytic surfaces. A macroporous flow-field with interdigitated inlet and outlet reactant channels contacts the second side of the thin gas diffusion layer for distributing one of the gaseous reactants over the thin gas diffusion layer for transport to an adjacent one of the catalytic surfaces of the membrane. The porous flow field may be formed from a hydrophilic material and provides uniform support across the backside of the electrode assembly to facilitate the use of thin backing layers.

Fuel cell with interdigitated porous flow-field

DOEpatents

Wilson, M.S.

1997-06-24

A polymer electrolyte membrane (PEM) fuel cell is formed with an improved system for distributing gaseous reactants to the membrane surface. A PEM fuel cell has an ionic transport membrane with opposed catalytic surfaces formed thereon and separates gaseous reactants that undergo reactions at the catalytic surfaces of the membrane. The fuel cell may also include a thin gas diffusion layer having first and second sides with a first side contacting at least one of the catalytic surfaces. A macroporous flow-field with interdigitated inlet and outlet reactant channels contacts the second side of the thin gas diffusion layer for distributing one of the gaseous reactants over the thin gas diffusion layer for transport to an adjacent one of the catalytic surfaces of the membrane. The porous flow field may be formed from a hydrophilic material and provides uniform support across the backside of the electrode assembly to facilitate the use of thin backing layers. 9 figs.

Electrical contacts to thin layers of Bi2Sr2CaCu2O8+δ

NASA Astrophysics Data System (ADS)

Suzuki, Shota; Taniguchi, Hiroki; Kawakami, Tsukasa; Cosset-Cheneau, Maxen; Arakawa, Tomonori; Miyasaka, Shigeki; Tajima, Setsuko; Niimi, Yasuhiro; Kobayashi, Kensuke

2018-05-01

Thin layers of Bi2Sr2CaCu2O8+δ (Bi2212) were fabricated using the mechanical exfoliation technique. Good electrical contacts to the thin Bi2212 films with low contact resistance were realized by depositing Ag and Au electrodes onto the Bi2212 films and annealing them with an oxygen flow at 350 °C for 30 min. We observed cross-section images of the Bi2212 thin film device using a transmission electron microscope to characterize the diffusion of Ag and Au atoms into the Bi2212 thin film.

Organic layer serves as a hotspot of microbial activity and abundance in Arctic tundra soils.

PubMed

Lee, Seung-Hoon; Jang, Inyoung; Chae, Namyi; Choi, Taejin; Kang, Hojeong

2013-02-01

Tundra ecosystem is of importance for its high accumulation of organic carbon and vulnerability to future climate change. Microorganisms play a key role in carbon dynamics of the tundra ecosystem by mineralizing organic carbon. We assessed both ecosystem process rates and community structure of Bacteria, Archaea, and Fungi in different soil layers (surface organic layer and subsurface mineral soil) in an Arctic soil ecosystem located at Spitsbergen, Svalbard during the summer of 2008 by using biochemical and molecular analyses, such as enzymatic assay, terminal restriction fragment length polymorphism (T-RFLP), quantitative polymerase chain reaction (qPCR), and pyrosequencing. Activity of hydrolytic enzymes showed difference according to soil type. For all three microbial communities, the average gene copy number did not significantly differ between soil types. However, archaeal diversities appeared to differ according to soil type, whereas bacterial and fungal diversity indices did not show any variation. Correlation analysis between biogeochemical and microbial parameters exhibited a discriminating pattern according to microbial or soil types. Analysis of the microbial community structure showed that bacterial and archaeal communities have different profiles with unique phylotypes in terms of soil types. Water content and hydrolytic enzymes were found to be related with the structure of bacterial and archaeal communities, whereas soil organic matter (SOM) and total organic carbon (TOC) were related with bacterial communities. The overall results of this study indicate that microbial enzyme activity were generally higher in the organic layer than in mineral soils and that bacterial and archaeal communities differed between the organic layer and mineral soils in the Arctic region. Compared to mineral soil, peat-covered organic layer may represent a hotspot for secondary productivity and nutrient cycling in this ecosystem.

Precise Control of the Number of Layers of Graphene by Picosecond Laser Thinning.

PubMed

Lin, Zhe; Ye, Xiaohui; Han, Jinpeng; Chen, Qiao; Fan, Peixun; Zhang, Hongjun; Xie, Dan; Zhu, Hongwei; Zhong, Minlin

2015-06-26

The properties of graphene can vary as a function of the number of layers (NOL). Controlling the NOL in large area graphene is still challenging. In this work, we demonstrate a picosecond (ps) laser thinning removal of graphene layers from multi-layered graphene to obtain desired NOL when appropriate pulse threshold energy is adopted. The thinning process is conducted in atmosphere without any coating and it is applicable for graphene films on arbitrary substrates. This method provides many advantages such as one-step process, non-contact operation, substrate and environment-friendly, and patternable, which will enable its potential applications in the manufacturing of graphene-based electronic devices.

Precise Control of the Number of Layers of Graphene by Picosecond Laser Thinning

NASA Astrophysics Data System (ADS)

Lin, Zhe; Ye, Xiaohui; Han, Jinpeng; Chen, Qiao; Fan, Peixun; Zhang, Hongjun; Xie, Dan; Zhu, Hongwei; Zhong, Minlin

2015-06-01

The properties of graphene can vary as a function of the number of layers (NOL). Controlling the NOL in large area graphene is still challenging. In this work, we demonstrate a picosecond (ps) laser thinning removal of graphene layers from multi-layered graphene to obtain desired NOL when appropriate pulse threshold energy is adopted. The thinning process is conducted in atmosphere without any coating and it is applicable for graphene films on arbitrary substrates. This method provides many advantages such as one-step process, non-contact operation, substrate and environment-friendly, and patternable, which will enable its potential applications in the manufacturing of graphene-based electronic devices.

Thin-film limit formalism applied to surface defect absorption.

PubMed

Holovský, Jakub; Ballif, Christophe

2014-12-15

The thin-film limit is derived by a nonconventional approach and equations for transmittance, reflectance and absorptance are presented in highly versatile and accurate form. In the thin-film limit the optical properties do not depend on the absorption coefficient, thickness and refractive index individually, but only on their product. We show that this formalism is applicable to the problem of ultrathin defective layer e.g. on a top of a layer of amorphous silicon. We develop a new method of direct evaluation of the surface defective layer and the bulk defects. Applying this method to amorphous silicon on glass, we show that the surface defective layer differs from bulk amorphous silicon in terms of light soaking.

Experimental system to displace radioisotopes from upper to deeper soil layers: chemical research

PubMed Central

Cazzola, Pietro; Cena, Agostino; Ghignone, Stefano; Abete, Maria C; Andruetto, Sergio

2004-01-01

Background Radioisotopes are introduced into the environment following nuclear power plant accidents or nuclear weapons tests. The immobility of these radioactive elements in uppermost soil layers represents a problem for human health, since they can easily be incorporated in the food chain. Preventing their assimilation by plants may be a first step towards the total recovery of contaminated areas. Methods The possibility of displacing radionuclides from the most superficial soil layers and their subsequent stabilisation at lower levels were investigated in laboratory trials. An experimental system reproducing the environmental conditions of contaminated areas was designed in plastic columns. A radiopolluted soil sample was treated with solutions containing ions normally used in fertilisation (NO3-, NH4+, PO4--- and K+). Results Contaminated soils treated with an acid solution of ions NO3-, PO4--- and K+, undergo a reduction of radioactivity up to 35%, after a series of washes which simulate one year's rainfall. The capacity of the deepest soil layers to immobilize the radionuclides percolated from the superficial layers was also confirmed. Conclusion The migration of radionuclides towards deeper soil layers, following chemical treatments, and their subsequent stabilization reduces bioavailability in the uppermost soil horizon, preventing at the same time their transfer into the water-bearing stratum. PMID:15132749

[Effects of mulching management on biomass of Phyllostachys praecox and soil fertility].

PubMed

Zhai, Wan Lu; Yang, Chuan Bao; Zhang, Xiao Ping; Gao, Gui Bin; Zhong, Zhe Ke

2018-04-01

We analyzed the dynamics of stand growth and soil nutrient availability during the degradation processes of Phyllostachys praecox plantation, taking the advantage of bamboo forest stands with different mulching ages (0, 3, 6, 9 and 12 a). The results showed the aboveground and belowground biomass of bamboo forest reached the maximum value when they were covered by three years, which was significantly increased by 14.6% and 146.6% compared with the control. The soil nutrient content was affected by the mulching age and soil layer. Soil nutrients gradually accumulated in upper layer. Soil organic carbon and total nitrogen content were increased with the increases of coverage years. The soil total phosphorus content at different soil layers showed a trend of decreasing first and then increasing. It was the lowest level in the surface layer (0-20 cm) and the bottom (40-60 cm) in 6 years, and the subsurface (20-40 cm) soil reached the lowest level in three years. The total potassium content kept increasing in 0-20 cm soil layer, but decreased during the first three years of mulching and then increased in 20-60 cm soil layer. The comprehensive index of soil fertility quality was greatly improved after nine years mulching, with fertility of subsurface soil being better than that of surface and bottom soils. There was no relationship between the soil fertility index and biomass of different organs in bamboo in the different mulching ages. In the subsurface, however, nitrogen content was negatively related to leaf biomass and potassium was negatively correlated with the biomass of leaves and whip roots. Our results indicated that excessive accumulation of soil nutrients seriously inhibited the propagation and biomass accumulation of P. praecox after long-term mulching management and a large amount of fertilizer, which further aggravated the degradation of bamboo plantation.

Fabrication of Organic Thin Film Transistors Using Layer-By-Layer Assembly (Preprint)

DTIC Science & Technology

2007-03-01

thin-film transistors ( TFTs ) have received considerable attention as a low- cost, light-weight, flexible alternative to traditional amorphous silicon...Previous studies have investigated the use of a number of materials for both the active layer and the gate dielectric in various TFT architectures. These...performance. Conjugated small molecules, such as pentacene, or polymers, such as poly(3- hexylthiophene), are commonly used as the active layer in organic TFT

Use of separate ZnTe interface layers to form ohmic contacts to p-CdTe films

DOEpatents

Gessert, T.A.

1999-06-01

A method of is disclosed improving electrical contact to a thin film of a p-type tellurium-containing II-VI semiconductor comprising: depositing a first undoped layer of ZnTe on a thin film of p-type tellurium containing II-VI semiconductor with material properties selected to limit the formation of potential barriers at the interface between the p-CdTe and the undoped layer, to a thickness sufficient to control diffusion of the metallic-doped ZnTe into the p-type tellurium-containing II-VI semiconductor, but thin enough to minimize affects of series resistance; depositing a second heavy doped p-type ZnTe layer to the first layer using an appropriate dopant; and depositing an appropriate metal onto the outer-most surface of the doped ZnTe layer for connecting an external electrical conductor to an ohmic contact. 11 figs.

High-performance a-IGZO thin-film transistor with conductive indium-tin-oxide buried layer

NASA Astrophysics Data System (ADS)

Ahn, Min-Ju; Cho, Won-Ju

2017-10-01

In this study, we fabricated top-contact top-gate (TCTG) structure of amorphous indium-gallium-zinc oxide (a-IGZO) thin-film transistors (TFTs) with a thin buried conductive indium-tin oxide (ITO) layer. The electrical performance of a-IGZO TFTs was improved by inserting an ITO buried layer under the IGZO channel. Also, the effect of the buried layer's length on the electrical characteristics of a-IGZO TFTs was investigated. The electrical performance of the transistors improved with increasing the buried layer's length: a large on/off current ratio of 1.1×107, a high field-effect mobility of 35.6 cm2/Vs, a small subthreshold slope of 116.1 mV/dec, and a low interface trap density of 4.2×1011 cm-2eV-1 were obtained. The buried layer a-IGZO TFTs exhibited enhanced transistor performance and excellent stability against the gate bias stress.

Thin Carbon Layers on Nanostructured Silicon-Properties and Applications

NASA Astrophysics Data System (ADS)

Angelescu, Anca; Kleps, Irina; Miu, Mihaela; Simion, Monica; Bragaru, Adina; Petrescu, Stefana; Paduraru, Crina; Raducanu, Aurelia

Thin carbon layers such as silicon carbide (SiC) and diamond like carbon (DLC) layers on silicon, or on nanostructured silicon substrats were obtained by different methods. This paper is a review of our results in the areas of carbon layer microfabrication technologies and their properties related to different microsystem apllications. So, silicon membranes using a-SiC or DLC layers as etching mask, as well as silicon carbide membranes using a combined porous silicon — DLC structure were fabricated for sensor applications. A detailed evaluation of the field emission (FE) properties of these films was done to demonstrate their capability to be used in field emission devices. Carbon thin layers on nanostructured silicon samples were also investigated with respect to the living cell adhesion on these structures. The experiments indicate that the cell attachment on the surface of carbon coatings can be controlled by deposition parameters during the technological process.

Use of separate ZnTe interface layers to form OHMIC contacts to p-CdTe films

DOEpatents

Gessert, Timothy A.

1999-01-01

A method of improving electrical contact to a thin film of a p-type tellurium-containing II-VI semiconductor comprising: depositing a first undoped layer of ZnTe on a thin film of p-type tellurium containing II-VI semiconductor with material properties selected to limit the formation of potential barriers at the interface between the p-CdTe and the undoped layer, to a thickness sufficient to control diffusion of the metallic-doped ZnTe into the p-type tellurim-containing II-VI semiconductor, but thin enough to minimize affects of series resistance; depositing a second heavy doped p-type ZnTe layer to the first layer using an appropriate dopant; and depositing an appropriate metal onto the outer-most surface of the doped ZnTe layer for connecting an external electrical conductor to an ohmic contact.

Thin-film solar cell fabricated on a flexible metallic substrate

DOEpatents

Tuttle, John R.; Noufi, Rommel; Hasoon, Falah S.

2006-05-30

A thin-film solar cell (10) is provided. The thin-film solar cell (10) comprises a flexible metallic substrate (12) having a first surface and a second surface. A back metal contact layer (16) is deposited on the first surface of the flexible metallic substrate (12). A semiconductor absorber layer (14) is deposited on the back metal contact. A photoactive film deposited on the semiconductor absorber layer (14) forms a heterojunction structure and a grid contact (24) deposited on the heterjunction structure. The flexible metal substrate (12) can be constructed of either aluminium or stainless steel. Furthermore, a method of constructing a solar cell is provided. The method comprises providing an aluminum substrate (12), depositing a semiconductor absorber layer (14) on the aluminum substrate (12), and insulating the aluminum substrate (12) from the semiconductor absorber layer (14) to inhibit reaction between the aluminum substrate (12) and the semiconductor absorber layer (14).

Thin-Film Solar Cell Fabricated on a Flexible Metallic Substrate

DOEpatents

Tuttle, J. R.; Noufi, R.; Hasoon, F. S.

2006-05-30

A thin-film solar cell (10) is provided. The thin-film solar cell (10) comprises a flexible metallic substrate (12) having a first surface and a second surface. A back metal contact layer (16) is deposited on the first surface of the flexible metallic substrate (12). A semiconductor absorber layer (14) is deposited on the back metal contact. A photoactive film deposited on the semiconductor absorber layer (14) forms a heterojunction structure and a grid contact (24) deposited on the heterjunction structure. The flexible metal substrate (12) can be constructed of either aluminium or stainless steel. Furthermore, a method of constructing a solar cell is provided. The method comprises providing an aluminum substrate (12), depositing a semiconductor absorber layer (14) on the aluminum substrate (12), and insulating the aluminum substrate (12) from the semiconductor absorber layer (14) to inhibit reaction between the aluminum substrate (12) and the semiconductor absorber layer (14).

Morphology and genesis of carbonate soils on the Kyle Canyon fan, Nevada, U.S.A.

USGS Publications Warehouse

Reheis, M.C.; Sowers, J.M.; Taylor, E.M.; McFadden, L.D.; Harden, J.W.

1992-01-01

The physical and chemical properties of soils formed in an arid climate on calcareous alluvium of the Kyle Canyon alluvial fan, southern Nevada, were studied in order to infer the rates and relative importance of various soil-forming processes. These studies included field and microscopic observations and analyses of thin sections, major oxides, extractable iron, and clay minerals. The results are interpreted to reflect five major pedogenic processes: (1) The calcic horizons and calcretes of Kyle Canyon soils form by precipitation of CaCO3, derived from eolian dust and alluvium, as clast coats, matrix cement, and massive layers. (2) The A and uppermost B horizons are essentially dust-derived, for they contain large amounts of detrital material not present in the alluvial parent material, and their major-oxide content is similar to that of modern dust. (3) Clay particles are translocated from A into B horizons. (4) Iron-bearing minerals in the near-surface B horizons are slowly oxidized. (5) Carbonate and aluminosilicate grains are both displaced and replaced by pedogenic CaCO3; the silica released by replacement of aluminosilicates may be locally precipitated as amorphous or opaline silica and (or) incorporated into newly formed palygorskite and sepiolite. Rates of soil development at Kyle Canyon are approximate due to uncertainties in age estimates. Some soil field properties change at rates that are similar to rates for soils formed in rhyolitic parent material near Mercury, Nevada. The rate of accumulation of CaCO3 (3-5 g m-2 yr-1) at Kyle Canyon is an order of magnitude faster than that near Mercury, but is comparable to rates calculated for soils in southern New Mexico and Utah. ?? 1992.

Direct charge carrier injection into Ga2O3 thin films using an In2O3 cathode buffer layer: their optical, electrical and surface state properties

NASA Astrophysics Data System (ADS)

Cui, W.; Zhao, X. L.; An, Y. H.; Guo, D. Y.; Qing, X. Y.; Wu, Z. P.; Li, P. G.; Li, L. H.; Cui, C.; Tang, W. H.

2017-04-01

Conductive Ga2O3 thin films with an In2O3 buffer layer have been prepared on c-plane sapphire substrates using a laser molecular beam epitaxy technique. The effects of the In2O3 buffer layer on the structure and optical, electrical and surface state properties of the Ga2O3 films have been studied. The change in conductivity of the thin films is attributed to different thicknesses of the In2O3 buffer layer, which determine the concentration of charge carriers injected into the upper Ga2O3 layer from the interface of the bilayer thin films. In addition, the increase in flat band voltage shift and capacitance values as the In2O3 buffer layer thickens are attributed to the increase in surface state density, which also contributes to the rapid shrinkage of the optical band gap of the Ga2O3. With transparency to visible light, high n-type conduction and the ability to tune the optical band gap and surface state density, we propose that Ga2O3/In2O3 bilayer thin film is an ideal n-type semiconductor for fabrication of transparent power devices, solar cell electrodes and gas sensors.

Synthesis of bimetallic nanostructures by nanosecond laser ablation of multicomponent thin films in water

NASA Astrophysics Data System (ADS)

Nikov, R. G.; Nedyalkov, N. N.; Atanasov, P. A.; Karashanova, D. B.

2018-03-01

The paper presents results on nanosecond laser ablation of thin films immersed in a liquid. The thin films were prepared by consecutive deposition of layers of different metals by thermal evaporation (first layer) and classical on-axis pulsed laser deposition (second layer); Ni/Au, Ag/Au and Ni/Ag thin films were thus deposited on glass substrates. The as-prepared films were then placed at the bottom of a glass vessel filled with double distilled water and irradiated by nanosecond laser pulses delivered by a Nd:YAG laser system at λ = 355 nm. This resulted in the formation of colloids of the thin films’ material. We also compared the processes of ablation of a bulk target and a thin film in the liquid by irradiating a Au target and a Au thin film by the same laser wavelength and fluence (λ = 355 nm, F = 5 J/cm2). The optical properties of the colloids were evaluated by optical transmittance measurements in the UV– VIS spectral range. Transmission electron microscopy was employed to estimate the particles’ size distribution.

Improvement in interfacial characteristics of low-voltage carbon nanotube thin-film transistors with solution-processed boron nitride thin films

NASA Astrophysics Data System (ADS)

Jeon, Jun-Young; Ha, Tae-Jun

2017-08-01

In this article, we demonstrate the potential of solution-processed boron nitride (BN) thin films for high performance single-walled carbon nanotube thin-film transistors (SWCNT-TFTs) with low-voltage operation. The use of BN thin films between solution-processed high-k dielectric layers improved the interfacial characteristics of metal-insulator-metal devices, thereby reducing the current density by three orders of magnitude. We also investigated the origin of improved device performance in SWCNT-TFTs by employing solution-processed BN thin films as an encapsulation layer. The BN encapsulation layer improves the electrical characteristics of SWCNT-TFTs, which includes the device key metrics of linear field-effect mobility, sub-threshold swing, and threshold voltage as well as the long-term stability against the aging effect in air. Such improvements can be achieved by reduced interaction of interfacial localized states with charge carriers. We believe that this work can open up a promising route to demonstrate the potential of solution-processed BN thin films on nanoelectronics.

Organic Field Effect Transistor Using Amorphous Fluoropolymer as Gate Insulating Film

NASA Astrophysics Data System (ADS)

Kitajima, Yosuke; Kojima, Kenzo; Mizutani, Teruyoshi; Ochiai, Shizuyasu

Organic field effect transistors are fabricated by the active layer of Regioregular poly (3-hexylthiophene-2,5-diy)(P3HT) thin film. CYTOP thin film made from Amorphous Fluoropolymer and fabricated by spin-coating is adopted to a gate dielectric layer on Polyethylenenaphthalate (PEN) thin film that is the substrate of an organic field effect transistor. The surface morphology and molecular orientation of P3HT thin films is observed by atomic force microscope (AFM) and X-Ray diffractometer (XRD). Grains are observed on the CYTOP thin film via an AFM image and the P3HT molecule is oriented perpendicularly on the CYTOP thin film. Based on the performance of the organic field effect transistor, the carrier mobility is 0.092 cm2/Vs, the ON/OFF ratio is 7, and the threshold voltage is -12 V. The ON/OFF ratio is relatively low and to improve On/Off ratio, the CYTOP/Polyimide double gate insulating layer is adopted to OFET.

Thin film absorber for a solar collector

DOEpatents

Wilhelm, William G.

1985-01-01

This invention pertains to energy absorbers for solar collectors, and more particularly to high performance thin film absorbers. The solar collectors comprising the absorber of this invention overcome several problems seen in current systems, such as excessive hardware, high cost and unreliability. In the preferred form, the apparatus features a substantially rigid planar frame with a thin film window bonded to one planar side of the frame. An absorber in accordance with the present invention is comprised of two thin film layers that are sealed perimetrically. In a preferred embodiment, thin film layers are formed from a metal/plastic laminate. The layers define a fluid-tight planar envelope of large surface area to volume through which a heat transfer fluid flows. The absorber is bonded to the other planar side of the frame. The thin film construction of the absorber assures substantially full envelope wetting and thus good efficiency. The window and absorber films stress the frame adding to the overall strength of the collector.

Organic photovoltaic cells utilizing ultrathin sensitizing layer

DOEpatents

Rand, Barry P [Princeton, NJ; Forrest, Stephen R [Princeton, NJ

2011-05-24

A photosensitive device includes a series of organic photoactive layers disposed between two electrodes. Each layer in the series is in direct contact with a next layer in the series. The series is arranged to form at least one donor-acceptor heterojunction, and includes a first organic photoactive layer comprising a first host material serving as a donor, a thin second organic photoactive layer comprising a second host material disposed between the first and a third organic photoactive layer, and the third organic photoactive layer comprising a third host material serving as an acceptor. The first, second, and third host materials are different. The thin second layer serves as an acceptor relative to the first layer or as a donor relative to the third layer.

In-depth evolution of chemical states and sub-10-nm-resolution crystal orientation mapping of nanograins in Ti(5 nm)/Au(20 nm)/Cr(3 nm) tri-layer thin films

NASA Astrophysics Data System (ADS)

Zhu, Xiaoli; Todeschini, Matteo; Bastos da Silva Fanta, Alice; Liu, Lintao; Jensen, Flemming; Hübner, Jörg; Jansen, Henri; Han, Anpan; Shi, Peixiong; Ming, Anjie; Xie, Changqing

2018-09-01

The applications of Au thin films and their adhesion layers often suffer from a lack of sufficient information about the chemical states of adhesion layers and about the high-lateral-resolution crystallographic morphology of Au nanograins. Here, we demonstrate the in-depth evolution of the chemical states of adhesive layers at the interfaces and the crystal orientation mapping of gold nanograins with a lateral resolution of less than 10 nm in a Ti/Au/Cr tri-layer thin film system. Using transmission electron microscopy, the variation in the interdiffusion at Cr/Au and Ti/Au interfaces was confirmed. From X-ray photoelectron spectroscopy (XPS) depth profiling, the chemical states of Cr, Au and Ti were characterized layer by layer, suggesting the insufficient oxidation of the adhesive layers. At the interfaces the Au 4f peaks shift to higher binding energies and this behavior can be described by a proposed model based on electron reorganization and substrate-induced final-state neutralization in small Au clusters supported by the partially oxidized Ti layer. Utilizing transmission Kikuchi diffraction (TKD) in a scanning electron microscope, the crystal orientation of Au nanograins between two adhesion layers was non-destructively characterized with sub-10 nm spatial resolution. The results provide nanoscale insights into the Ti/Au/Cr thin film system and contribute to our understanding of its behavior in nano-optic and nano-electronic devices.

Removal of nitrogen by a layered soil infiltration system during intermittent storm events.

PubMed

Cho, Kang Woo; Song, Kyung Guen; Cho, Jin Woo; Kim, Tae Gyun; Ahn, Kyu Hong

2009-07-01

The fates of various nitrogen species were investigated in a layered biological infiltration system under an intermittently wetting regime. The layered system consisted of a mulch layer, coarse soil layer (CSL), and fine soil layer (FSL). The effects of soil texture were assessed focusing on the infiltration rate and the removal of inorganic nitrogen species. The infiltration rate drastically decreased when the uniformity coefficient was larger than four. The ammonium in the synthetic runoff was shown to be removed via adsorption during the stormwater dosing and nitrification during subsequent dry days. Stable ammonium adsorption was observed when the silt and clay content of CSL was greater than 3%. This study revealed that the nitrate leaching was caused by nitrification during dry days. Various patterns of nitrate flushing were observed depending on the soil configuration. The washout of nitrate was more severe as the silt/clay content of the CSL was greater. However, proper layering of soil proved to enhance the nitrate removal. Consequently, a strictly sandy CSL over FSL with a silt and clay content of 10% was the best configuration for the removal of ammonium and nitrate.

Direct leaf wetness measurements and its numerical analysis using a multi-layer atmosphere-soil-vegetation model at a grassland site in pre-alpine region in Germany

NASA Astrophysics Data System (ADS)

Katata, Genki; Held, Andreas; Mauder, Matthias

2014-05-01

The wetness of plant leaf surfaces (leaf wetness) is important in meteorological, agricultural, and environmental studies including plant disease management and the deposition process of atmospheric trace gases and particles. Although many models have been developed to predict leaf wetness, wetness data directly measured at the leaf surface for model validations are still limited. In the present study, the leaf wetness was monitored using seven electrical sensors directly clipped to living leaf surfaces of thin and broad-leaved grasses. The measurements were carried out at the pre-alpine grassland site in TERestrial ENvironmental Observatories (TERENO) networks in Germany from September 20 to November 8, 2013. Numerical simulations of a multi-layer atmosphere-SOiL-VEGetation model (SOLVEG) developed by the authors were carried out for analyzing the data. For numerical simulations, the additional routine meteorological data of wind speed, air temperature and humidity, radiation, rainfall, long-wave radiative surface temperature, surface fluxes, ceilometer backscatter, and canopy or snow depth were used. The model reproduced well the observed leaf wetness, net radiation, momentum and heat, water vapor, and CO2 fluxes, surface temperature, and soil temperature and moisture. In rain-free days, a typical diurnal cycle as a decrease and increase during the day- and night-time, respectively, was observed in leaf wetness data. The high wetness level was always monitored under rain, fog, and snowcover conditions. Leaf wetness was also often high in the early morning due to thawing of leaf surface water frozen during a cold night. In general, leaf wetness was well correlated with relative humidity (RH) in condensation process, while it rather depended on wind speed in evaporation process. The comparisons in RH-wetness relations between leaf characteristics showed that broad-leaved grasses tended to be wetter than thin grasses.

[Soil moisture dynamics of artificial Caragana microphylla shrubs at different topographical sites in Horqin sandy land].

PubMed

Huang, Gang; Zhao, Xue-yong; Huang, Ying-xin; Su, Yan-gui

2009-03-01

Based on the investigation data of vegetation and soil moisture regime of Caragana microphylla shrubs widely distributed in Horqin sandy land, the spatiotemporal variations of soil moisture regime and soil water storage of artificial sand-fixing C. microphylla shrubs at different topographical sites in the sandy land were studied, and the evapotranspiration was measured by water balance method. The results showed that the soil moisture content of the shrubs was the highest in the lowland of dunes, followed by in the middle, and in the crest of the dunes, and increased with increasing depth. No water stress occurred during the growth season of the shrubs. Soil moisture content of the shrubs was highly related to precipitation event, and the relationship of soil moisture content with precipitation was higher in deep soil layer (50-180 cm) than in shallow soil layer (0-50 cm). The variation coefficient of soil moisture content was also higher in deep layer than in shallow layer. Soil water storage was increasing in the whole growth season of the shrubs, which meant that the accumulation of soil water occurred in this area. The evapotranspiriation of the shrubs occupied above 64% of the precipitation.

Eucalyptus obliqua seedling growth in organic vs. mineral soil horizons

PubMed Central

Barry, Karen M.; Janos, David P.; Nichols, Scott; Bowman, David M. J. S.

2015-01-01

Eucalyptus obliqua, the most widespread timber tree in Tasmania, is a pioneer after fire which can eliminate the organic layer of forest soil, exposing the underlying mineral soil. We compared seedling growth, mycorrhiza formation, and mineral nutrient limitation in organic layer vs. mineral soil. We grew E. obliqua seedlings separately in pots of organic layer and mineral soil in a glasshouse. Additional treatments of organic soil only, involved fully crossed methyl-bromide fumigation and fertilization. Fertilization comprised chelated iron for 121 days after transplant (DAT) followed by soluble phosphorus. At 357 DAT, whole plant dry weight was three times greater in ambient organic than in mineral soil. In organic soil, fumigation halved ectomycorrhiza abundance and reduced seedling growth at 149 DAT, but by 357 DAT when negative effects of fumigation on seedling growth had disappeared, neither fumigation nor fertilization affected mycorrhiza abundance. Iron fertilization diminished seedling growth, but subsequent phosphorus fertilization improved it. E. obliqua seedlings grow much better in organic layer soil than in mineral soil, although phosphorus remains limiting. The prevalent forestry practice of burning to mineral soil after timber harvest exposes a poor growth medium likely only partially compensated by fire-induced mineral soil alterations. PMID:25750650

Development of the α-IGZO/Ag/α-IGZO Triple-Layer Structure Films for the Application of Transparent Electrode.

PubMed

Chen, Kun-Neng; Yang, Cheng-Fu; Wu, Chia-Ching; Chen, Yu-Hsin

2017-02-24

We investigated the structural, optical, and electrical properties of amorphous IGZO/silver/amorphous IGZO (α-IGZO/Ag/α-IGZO) triple-layer structures that were deposited at room temperature on Eagle XG glass and flexible polyethylene terephthalate substrates through the sputtering method. Thin Ag layers with different thicknesses were inserted between two IGZO layers to form a triple-layer structure. Ag was used because of its lower absorption and resistivity. Field emission scanning electron microscopy measurements of the triple-layer structures revealed that the thicknesses of the Ag layers ranged from 13 to 41 nm. The thickness of the Ag layer had a large effect on the electrical and optical properties of the electrodes. The optimum thickness of the Ag metal thin film could be evaluated according to the optical transmittance, electrical conductivity, and figure of merit of the electrode. This study demonstrates that the α-IGZO/Ag/α-IGZO triple-layer transparent electrode can be fabricated with low sheet resistance (4.2 Ω/□) and high optical transmittance (88.1%) at room temperature without postannealing processing on the deposited thin films.

DOE Office of Scientific and Technical Information (OSTI.GOV)

Tesfaye, Meron; MacDonald, Andrew N.; Dudenas, Peter J.

Local gas transport limitation attributed to the ionomer thin-film in the catalyst layer is a major deterrent to widespread commercialization of polymer-electrolyte fuel cells. So far functionality and limitations of these thin-films have been assumed identical in the anode and cathode. In this study, Nafion ionomer thin-films on platinum(Pt) support were exposed to H 2 and air as model schemes, mimicking anode and cathode catalyst layers. Findings indicate decreased swelling, increased densification of ionomer matrix, and increased humidity-induced aging rates in reducing environment, compared to oxidizing and inert environments. Observed phenomenon could be related to underlying Pt-gas interaction dictating Pt-ionomermore » behavior. Presented results could have significant implications about the disparate behavior of ionomer thin-film in anode and cathode catalyst layers.« less

Spectroscopic Ellipsometry Studies of Ag and ZnO Thin Films and Their Interfaces for Thin Film Photovoltaics

NASA Astrophysics Data System (ADS)

Sainju, Deepak

Many modern optical and electronic devices, including photovoltaic devices, consist of multilayered thin film structures. Spectroscopic ellipsometry (SE) is a critically important characterization technique for such multilayers. SE can be applied to measure key parameters related to the structural, optical, and electrical properties of the components of multilayers with high accuracy and precision. One of the key advantages of this non-destructive technique is its capability of monitoring the growth dynamics of thin films in-situ and in real time with monolayer level precision. In this dissertation, the techniques of SE have been applied to study the component layer materials and structures used as back-reflectors and as the transparent contact layers in thin film photovoltaic technologies, including hydrogenated silicon (Si:H), copper indium-gallium diselenide (CIGS), and cadmium telluride (CdTe). The component layer materials, including silver and both intrinsic and doped zinc oxide, are fabricated on crystalline silicon and glass substrates using magnetron sputtering techniques. These thin films are measured in-situ and in real time as well as ex-situ by spectroscopic ellipsometry in order to extract parameters related to the structural properties, such as bulk layer thickness and surface roughness layer thickness and their time evolution, the latter information specific to real time measurements. The index of refraction and extinction coefficient or complex dielectric function of a single unknown layer can also be obtained from the measurement versus photon energy. Applying analytical expressions for these optical properties versus photon energy, parameters that describe electronic transport, such as electrical resistivity and electron scattering time, can be extracted. The SE technique is also performed as the sample is heated in order to derive the effects of annealing on the optical properties and derived electrical transport parameters, as well as the intrinsic temperature dependence of these properties and parameters. One of the major achievements of this dissertation research is the characterization of the thickness and optical properties of the interface layer formed between the silver and zinc oxide layers in a back-reflector structure used in thin film photovoltaics. An understanding of the impact of these thin film material properties on solar cell device performance has been complemented by applying reflectance and transmittance spectroscopy as well as simulations of cell performance.

Cu2ZnSnSe4 Thin Film Solar Cell with Depth Gradient Composition Prepared by Selenization of Sputtered Novel Precursors.

PubMed

Lai, Fang-I; Yang, Jui-Fu; Chen, Wei-Chun; Kuo, Shou-Yi

2017-11-22

In this study, we proposed a new method for the synthesis of the target material used in a two stage process for preparation of a high quality CZTSe thin film. The target material consisting of a mixture of Cu x Se and Zn x Sn 1-x alloy was synthesized, providing a quality CZTSe precursor layer for highly efficient CZTSe thin film solar cells. The CZTSe thin film can be obtained by annealing the precursor layers through a 30 min selenization process under a selenium atmosphere at 550 °C. The CZTSe thin films prepared by using the new precursor thin film were investigated and characterized using X-ray diffraction, Raman scattering, and photoluminescence spectroscopy. It was found that diffusion of Sn occurred and formed the CTSe phase and Cu x Se phase in the resultant CZTSe thin film. By selective area electron diffraction transmission electron microscopy images, the crystallinity of the CZTSe thin film was verified to be single crystal. By secondary ion mass spectroscopy measurements, it was confirmed that a double-gradient band gap profile across the CZTSe absorber layer was successfully achieved. The CZTSe solar cell with the CZTSe absorber layer consisting of the precursor stack exhibited a high efficiency of 5.46%, high short circuit current (J SC ) of 37.47 mA/cm 2 , open circuit voltage (V OC ) of 0.31 V, and fill factor (F.F.) of 47%, at a device area of 0.28 cm 2 . No crossover of the light and dark current-voltage (I-V) curves of the CZTSe solar cell was observed, and also, no red kink was observed under red light illumination, indicating a low defect concentration in the CZTSe absorber layer. Shunt leakage current with a characteristic metal/CZTSe/metal leakage current model was observed by temperature-dependent I-V curves, which led to the discovery of metal incursion through the CdS buffer layer on the CZTSe absorber layer. This leakage current, also known as space charge-limited current, grew larger as the measurement temperature increased and completely overwhelmed the diode current at a measurement temperature of 200 °C. This is due to interlayer diffusion of metal that increases the shunt leakage current and decreases the efficiency of the CZTSe thin film solar cells.

Characterization of crystallographic properties of thin films using X-ray diffraction

NASA Astrophysics Data System (ADS)

Zoo, Yeongseok

2007-12-01

Silver (Ag) has been recognized as one of promising candidates in Ultra-Large Scale Integrated (ULSI) applications in that it has the lowest bulk electrical resistivity of all pure metals and higher electromigration resistance than other interconnect materials. However, low thermal stability on Silicon Dioxide (Si02) at high temperatures (e.g., agglomeration) is considered a drawback for the Ag metallization scheme. Moreover, if a thin film is attached on a substrate, its properties may differ significantly from that of the bulk, since the properties of thin films can be significantly affected by the substrate. In this study, the Coefficient of Thermal Expansion (CTE) and texture evolution of Ag thin films on different substrates were characterized using various analytical techniques. The experimental results showed that the CTE of the Ag thin film was significantly affected by underlying substrate and the surface roughness of substrate. To investigate the alloying effect for Ag meatallization, small amounts of Copper (Cu) were added and characterized using theta-2theta X-ray Diffraction (XRD) scan and pole figure analysis. These XRD techniques are useful for investigating the primary texture of a metal film, (111) in this study, which (111) is the notation of a specific plane in the orthogonal coordinate system. They revealed that the (111) textures of Ag and Ag(Cu) thin films were enhanced with increasing temperature. Comparison of texture profiles between Ag and Ag(Cu) thin films showed that Cu additions enhanced (111) texture in Ag thin films. Accordingly, the texture enhancement in Ag thin films by Cu addition was discussed. Strained Silicon-On-Insulator (SSOI) is being considered as a potential substrate for Complementary Metal-Oxide-Semiconductor (CMOS) technology since the induced strain results in a significant improvement in device performance. High resolution X-ray diffraction (XRD) techniques were used to characterize the perpendicular and parallel strains in SSOI layers. XRD diffraction profiles generated from the crystalline SSOI layer provided a direct measurement of the layer's strain components. In addition, it has demonstrated that the rotational misalignment between the layer and the substrate can be incorporated within the biaxial strain equations for epitaxial layers. Based on these results, the strain behavior of the SSOI layer and the relation between strained Si and SiO2 layers are discussed for annealed samples.

Assessing the dynamics of the upper soil layer relative to soil management practices

USDA-ARS?s Scientific Manuscript database

The upper layer of the soil is the critical interface between the soil and the atmosphere and is the most dynamic in response to management practices. One of the soil properties is the stability of the aggregates because this property controls infiltration of water and exchange of gases. An aggregat...

Optimization of rotational speed for growing BaFe12O19 thin films using spin coating

NASA Astrophysics Data System (ADS)

Budiawanti, S.; Soegijono, B.; Mudzakir, I.; Suharno, Fadillah, L.

2017-07-01

Barium ferrite (BaFe12O19, BaM) thin films were fabricated by the spin coating of precursors obtained by using a sol-gel method. The effects of the rotational speed on the spin-coating process for growing a BaM thin film were investigated in this study. Coated films were heat-deposited at different rotational speeds ranging from 2000 to 4000 rpm, while the number of layers was set to nine. Further, the effect of the number of layers on the growth of BaM thin films was discussed. For this purpose, we take the layers number 1 to 12 and take the constant rotational speed of 3000 rpm. All the film were characterized using X-Ray diffraction, Scanning Electron microscope, and Energy-dispersive X-Ray spectroscopy and Vibrating Sample Magnetometer. It was found that by increasing the rotational speed the amount of material deposited on the Si substrate decreased. The measured grain size of the BaM thin film was nearly similar for three three different rotational speeds. However, the grain size was found to increase the number of layers.

GaN ultraviolet p-i-n photodetectors with enhanced deep ultraviolet quantum efficiency

NASA Astrophysics Data System (ADS)

Wang, Guosheng; Xie, Feng; Wang, Jun; Guo, Jin

2017-10-01

GaN ultraviolet (UV) p-i-n photodetectors (PDs) with a thin p-AlGaN/GaN contact layer are designed and fabricated. The PD exhibits a low dark current density of˜7 nA/cm2 under -5 V, and a zero-bias peak responsivity of ˜0.16 A/W at 360 nm, which corresponds to a maximum quantum efficiency of 55%. It is found that, in the wavelength range between 250 and 365 nm, the PD with thin p-AlGaN/GaN contact layer exhibits enhanced quantum efficiency especially in a deep-UV wavelength range, than that of the control PD with conventional thin p-GaN contact layer. The improved quantum efficiency of the PD with thin p-AlGaN/GaN contact layer in the deep-UV wavelength range is mainly attributed to minority carrier reflecting properties of thin p-AlGaN/GaN heterojunction which could reduce the surface recombination loss of photon-generated carriers and improve light current collection efficiency.

Elaboration and Characterization of TiO2 and Study of the Influence of The Number of Thin Films on the Methylene Blue Adsorption Rate

NASA Astrophysics Data System (ADS)

Madoui, Karima; Medjahed, Aicha; Hamici, Melia; Djamila, Abdi; Boudissa, Mokhtar

2018-05-01

Thin films of titanium oxide (TiO2) deposited on glass substrates were fabricated by using the sol-gel route. The realization of these thin layers was made using the dip-coating technique with a solution of titanium isopropoxyde as a precursor. The samples prepared with different numbers of deposited layers were annealed at 400 ° C for 2 hours. The main purposes of this work were investigations of both the effect of the number of thin TiO2 layers on the crystal structure of the anatase form first and, their ability to adsorb the solution of methylene blue in order to make colored filters from a photocatalytic process. The deposited titanium-oxide layers were characterized by using various techniques: namely, X-ray diffraction (XRD), Raman spectroscopy, atomic force microscopy (AFM) and UV-Visible spectrometry. The result obtained by using the XRD technique showed the appearance of an anatase phase, as was confirmed by using Raman spectroscopy. The AFM surface analysis allowed the surface topography to be characterized and the surface roughness to be measured, which increased with increasing number of layers. The UV-Visible spectra showed that the TiO2 films had a good transmittance varying from 65% to 95% according to the number of layers. The gap energy varied as a function of the number of deposited layers. The as deposited TiO2 layers were tested as a photocatalyst towards the adsorption of methylene blue dye. The results obtained during this study showed that the adsorption capacity varied according to the number of deposited thin layers and the exposing duration to ultraviolet (UV) light. The maximum absorption rate of the dye was obtained for the two-layer sample. Seventy-two hours of irradiation allowed the adsorption intensity of the dye to be maximized for two-layer films.

Observations of a two-layer soil moisture influence on surface energy dynamics and planetary boundary layer characteristics in a semiarid shrubland

NASA Astrophysics Data System (ADS)

Sanchez-Mejia, Zulia Mayari; Papuga, Shirley A.

2014-01-01

We present an observational analysis examining soil moisture control on surface energy dynamics and planetary boundary layer characteristics. Understanding soil moisture control on land-atmosphere interactions will become increasingly important as climate change continues to alter water availability. In this study, we analyzed 4 years of data from the Santa Rita Creosote Ameriflux site. We categorized our data independently in two ways: (1) wet or dry seasons and (2) one of the four cases within a two-layer soil moisture framework for the root zone based on the presence or absence of moisture in shallow (0-20 cm) and deep (20-60 cm) soil layers. Using these categorizations, we quantified the soil moisture control on surface energy dynamics and planetary boundary layer characteristics using both average responses and linear regression. Our results highlight the importance of deep soil moisture in land-atmosphere interactions. The presence of deep soil moisture decreased albedo by about 10%, and significant differences were observed in evaporative fraction even in the absence of shallow moisture. The planetary boundary layer height (PBLh) was largest when the whole soil profile was dry, decreasing by about 1 km when the whole profile was wet. Even when shallow moisture was absent but deep moisture was present the PBLh was significantly lower than when the entire profile was dry. The importance of deep moisture is likely site-specific and modulated through vegetation. Therefore, understanding these relationships also provides important insights into feedbacks between vegetation and the hydrologic cycle and their consequent influence on the climate system.

Ultraviolet emission enhancement in ZnO thin films modified by nanocrystalline TiO2

NASA Astrophysics Data System (ADS)

Zheng, Gaige; Lu, Xi; Qian, Liming; Xian, Fenglin

2017-05-01

In this study, nanocrystalline TiO2 modified ZnO thin films were prepared by electron beam evaporation. The structural, morphological and optical properties of the samples were analyzed by X-ray diffraction (XRD), scanning electron microscopy (SEM), high-resolution transmission electron microscopy (HRTEM), UV-visible spectroscopy, fluorescence spectroscopy, respectively. The composition of the films was examined by energy dispersive X-ray spectroscopy (EDX). The photoluminescent spectrum shows that the pure ZnO thin film exhibits an ultraviolet (UV) emission peak and a strong green emission band. Surface analysis indicates that the ZnO thin film contains many oxygen vacancy defects on the surface. After the ZnO thin film is modified by the nanocrystalline TiO2 layer, the UV emission of ZnO is largely enhanced and the green emission is greatly suppressed, which suggests that the surface defects such as oxygen vacancies are passivated by the TiO2 capping layer. As for the UV emission enhancement of the ZnO thin film, the optimized thickness of the TiO2 capping layer is ∼16 nm. When the thickness is larger than 16 nm, the UV emission of the ZnO thin film will decrease because the TiO2 capping layer absorbs most of the excitation energy. The UV emission enhancement in the nanocrystalline TiO2 modified ZnO thin film can be attributed to surface passivation and flat band effect.

Use of flue gas desulfurization gypsum for leaching Cd and Pb in reclaimed tidal flat soil.

PubMed

Yang, Ping; Li, Xian; Tong, Ze-Jun; Li, Qu-Sheng; He, Bao-Yan; Wang, Li-Li; Guo, Shi-Hong; Xu, Zhi-Min

2016-04-01

A soil column leaching experiment was conducted to eliminate heavy metals from reclaimed tidal flat soil. Flue gas desulfurization (FGD) gypsum was used for leaching. The highest removal rates of Cd and Pb in the upper soil layers (0-30 cm) were 52.7 and 30.5 %, respectively. Most of the exchangeable and carbonate-bound Cd and Pb were removed. The optimum FGD gypsum application rate was 7.05 kg·m(-2), and the optimum leaching water amount for the application was 217.74 L·m(-2). The application of FGD gypsum (two times) and the extension of the leaching interval time to 20 days increased the heavy metal removal rate in the upper soil layers. The heavy metals desorbed from the upper soil layers were re-adsorbed and fixed in the 30-70 cm soil layers.

Effect of native oxide layers on copper thin-film tensile properties: A reactive molecular dynamics study

DOE Office of Scientific and Technical Information (OSTI.GOV)

Skarlinski, Michael D., E-mail: michael.skarlinski@rochester.edu; Quesnel, David J.; Department of Mechanical Engineering, University of Rochester, Rochester, New York 14627

2015-12-21

Metal-oxide layers are likely to be present on metallic nano-structures due to either environmental exposure during use, or high temperature processing techniques such as annealing. It is well known that nano-structured metals have vastly different mechanical properties from bulk metals; however, difficulties in modeling the transition between metallic and ionic bonding have prevented the computational investigation of the effects of oxide surface layers. Newly developed charge-optimized many body [Liang et al., Mater. Sci. Eng., R 74, 255 (2013)] potentials are used to perform fully reactive molecular dynamics simulations which elucidate the effects that metal-oxide layers have on the mechanical propertiesmore » of a copper thin-film. Simulated tensile tests are performed on thin-films while using different strain-rates, temperatures, and oxide thicknesses to evaluate changes in yield stress, modulus, and failure mechanisms. Findings indicate that copper-thin film mechanical properties are strongly affected by native oxide layers. The formed oxide layers have an amorphous structure with lower Cu-O bond-densities than bulk CuO, and a mixture of Cu{sub 2}O and CuO charge character. It is found that oxidation will cause modifications to the strain response of the elastic modulii, producing a stiffened modulii at low temperatures (<75 K) and low strain values (<5%), and a softened modulii at higher temperatures. While under strain, structural reorganization within the oxide layers facilitates brittle yielding through nucleation of defects across the oxide/metal interface. The oxide-free copper thin-film yielding mechanism is found to be a tensile-axis reorientation and grain creation. The oxide layers change the observed yielding mechanism, allowing for the inner copper thin-film to sustain an FCC-to-BCC transition during yielding. The mechanical properties are fit to a thermodynamic model based on classical nucleation theory. The fit implies that the oxidation of the films reduces the activation volume for yielding.« less

Hydrothermal variations in soils resulting from the freezing and thawing processes in the active layer of an alpine grassland in the Qilian Mountains, northeastern Tibetan Plateau

NASA Astrophysics Data System (ADS)

Wang, Qingfeng; Yang, Qianqian; Guo, Hong; Xiao, Xiongxin; Jin, Huijun; Li, Lili; Zhang, Tingjun; Wu, Qingbai

2018-06-01

Soil hydrothermal dynamics, resulting from the freezing and thawing processes in the active layer and their influencing factors, were studied in the upper Heihe River Basin (UHRB) in the Qilian Mountains, northeastern Tibetan Plateau. Soil temperature and water content measurements were taken in the active layer of the UHRB in alpine grassland from 2013 to 2014. The results showed that the thaw rate of the active layer was significantly smaller in alpine paludal meadows than the thaw rate in alpine meadows and alpine steppes. This was mainly related to the hydrothermal properties of soils in the active layer, such as moisture content, thermal conductivity, and specific heat. During the thawing process, the active layer soil water content was higher and fluctuated less in alpine paludal meadows. Conversely, the soil water content was lower and fluctuated more significantly in alpine meadows and alpine steppes. These findings could be explained by the prevalence of peat soils, with a low bulk density, and high clay and organic matter content. By contrast, the soil particles in the active layer of alpine meadows and alpine steppes were significantly coarser, with higher bulk density and lower organic matter content. During the freezing process, gravel content and soil texture had a great impact on the unfrozen water content in the frozen soils. However, the factors influencing the soil water retention in frozen soils are complex, and further study is needed. These results provide theoretical support for the evaluation of the hydrological characteristics of the alpine permafrost zone in the Qilian Mountains. Furthermore, the effect of frozen ground on hydrological changes due to climate change in the Heihe River Basin can be simulated and predicted, providing a scientific basis for the ecological conservation of the Qilian Mountains National Park.

[Responses of soil organic carbon and its labile fractions to nitrogen and phosphorus additions in Cunninghamia lanceolata plantations in subtropical China.

PubMed

Zhang, Xiu Lan; Wang, Fang Chao; Fang, Xiang Min; He, Ping; Zhang, Yu Fei; Chen, Fu Sheng; Wang, Hui Min

2017-02-01

A series of nitrogen (N) and phosphorus (P) addition experiments using treatments of N 0 (0 kg N·hm -2 ·a -1 ), N 1 (50 kg N·hm -2 ·a -1 ), N 2 (100 kg N·hm -2 ·a -1 ), P (50 kg P·hm -2 ·a -1 ), N 1 P and N 2 P were conducted at Cunninghamia lanceolata plantations in subtropical China. The responses of soil organic carbon (SOC), particulate organic carbon (POC) and water-soluble organic carbon (WSOC) to the nutrient addition treatments after 3 years were determined. The results showed that N and P additions had no significant effects on SOC concentration in 0-20 cm soil layer, while P addition significantly decreased soil POC content in 0-5 cm soil layer by 26.1%. The responses of WSOC to N and P addition were mainly found in 0-5 cm soil layer, and low level N and P addition significantly increased the WSOC content in 0-5 cm soil layer. Nitrogen addition had no significant effect on POC/SOC, while the POC/SOC significantly decreased by 15.9% in response to P addition in 0-5 cm soil layer. In 5-10 cm and 10-20 cm soil layers, POC/SOC was not significantly altered in N and P addition treatments. Therefore, the forest soil C stability was mainly controlled by P content in subtropical areas. P addition was liable to cause the decomposition of surface soil active organic C and increased the soil C stability in the short term treatment.

Spatially and momentum resolved energy electron loss spectra from an ultra-thin PrNiO{sub 3} layer

DOE Office of Scientific and Technical Information (OSTI.GOV)

Kinyanjui, M. K., E-mail: michael.kinyanjui@uni-ulm.de; Kaiser, U.; Benner, G.

2015-05-18

We present an experimental approach which allows for the acquisition of spectra from ultra-thin films at high spatial, momentum, and energy resolutions. Spatially and momentum (q) resolved electron energy loss spectra have been obtained from a 12 nm ultra-thin PrNiO{sub 3} layer using a nano-beam electron diffraction based approach which enabled the acquisition of momentum resolved spectra from individual, differently oriented nano-domains and at different positions of the PrNiO{sub 3} thin layer. The spatial and wavelength dependence of the spectral excitations are obtained and characterized after the analysis of the experimental spectra using calculated dielectric and energy loss functions. The presentedmore » approach makes a contribution towards obtaining momentum-resolved spectra from nanostructures, thin film, heterostructures, surfaces, and interfaces.« less

[Effect of tillage system on soil animal, microorganism and enzyme activity in paddy field].

PubMed

Gao, Ming; Zhou, Baotong; Wei, Chaofu; Xie, Deti; Zhang, Lei

2004-07-01

A long-term experiment showed that under ridge-no-tillage, the amount of soil animal in 0 - 20 cm layer was 14700 ind. x m(-2), while under no-tillage and fallow in winter, paddy-upland rotation, and conventional tillage, it was 10450, 7950 and 6275 ind. x m(-2), respectively. Soil microbial biomass and microbial biomass N were more in spring and autumn, and less in summer. Soil enzyme activity was higher in surface soil layer and lower in bottom soil layer. The amount of soil animal, microbial biomass and microbial biomass N and soil enzyme activity was in order of ridge-no-tillage > paddy-upland rotation > no-tillage and fallow in winter > conventional tillage. The results also indicated that ridge-no-tillage was advantageous to improve soil ecological environment and soil fertility in paddy field.

Materials science and integration bases for fabrication of (BaxSr1-x)TiO3 thin film capacitors with layered Cu-based electrodes

NASA Astrophysics Data System (ADS)

Fan, W.; Kabius, B.; Hiller, J. M.; Saha, S.; Carlisle, J. A.; Auciello, O.; Chang, R. P. H.; Ramesh, R.

2003-11-01

The synthesis and fundamental material properties of layered TiAl/Cu/Ta electrodes were investigated to achieve the integration of Cu electrodes with high-dielectric constant (κ) oxide thin films for application to the fabrication of high-frequency devices. The Ta layer is an excellent diffusion barrier to inhibit deleterious Cu diffusion into the Si substrate, while the TiAl layer provides an excellent barrier against oxygen diffusion into the Cu layer to inhibit Cu oxidation during the growth of the high-κ layer in an oxygen atmosphere. Polycrystalline (BaxSr1-x)TiO3 (BST) thin films were grown on the Cu-based bottom electrode by rf magnetron sputtering at temperatures in the range 400-600 °C in oxygen, to investigate the performance of BST/Cu-based capacitors. Characterization of the Cu-based layered structure using surface analytical methods showed that two amorphous oxide layers were formed on both sides of the TiAl barrier, such that the oxide layer on the free surface of the TiAl layer correlates with TiAlOx, while the oxide layer at the TiAl/Cu interface is an Al2O3-rich layer. This double amorphous barrier layer structure effectively prevents oxygen penetration towards the underlying Cu and Ta layers. The TiAlOx interfacial layer, which has a relatively low dielectric constant compared with BST, reduced the total capacitance of the BST thin film capacitors. In addition, the layered electrode-oxide interface roughening observed during the growth of BST films at high temperature, due to copper grain growth, resulted in large dielectric loss on the fabricated BST capacitors. These problems were solved by growing the BST layer at 450 °C followed by a rapid thermal annealing at 700 °C. This process significantly reduced the thickness of the TiAlOx layer and interface roughness resulting in BST capacitors exhibiting properties suitable for the fabrication of high-performance high-frequency devices. In summary, relatively high dielectric constant (280), low dielectric loss (0.007), and low leakage current (<2×10-8 A/cm2 at 100 kV/cm) were achieved for BST thin film capacitors with Cu-based electrodes.

Impact of phenanthrene on the properties of biogeochemical interfaces in soil: A two-layer column study

NASA Astrophysics Data System (ADS)

Reichel, Katharina; Totsche, Kai Uwe

2013-04-01

Biogeochemical interfaces in soils (Totsche et al. 2010) are the "hot spots" of microbial activity and the processing of organic compounds in soils. The production and relocation of mobile organic matter (MOM) and biocolloids like microorganisms are key processes for the formation and depth propagation of biogeochemical interfaces in soils (BGI). Phenanthrene (PHE) has been shown to affect microbial communities in soils (Ding et al. 2012) and may induce shifts in MOM quantity and quality (amount, type and properties of MOM). We hypothesize that the properties of BGI in soil change significantly due to the presence of PHE. The objectives of this study are (i) to evaluate the effect of PHE on soil microbial communities and on MOM quantity and quality under flow conditions with single- and two-layer column experiments and (ii) to assess the role of these processes for the physicochemical, mechanical and sorptive properties of BGI in soils. The soil columns were operated under water-unsaturated conditions. The top layer (source layer, SL, 2 cm) is made of sieved soil material (Luvisol, Scheyern, Germany) spiked with PHE (0.2 mg/g). The bottom layer (reception layer, RL, 10 cm) comprised the same soil without PHE. PHE-free columns were conducted in parallel as reference. Release and transport of MOM in mature soil of a single-layer column experiment was found to depend on the transport regime. The release of larger sized MOM (>0.45 µm) was restricted to an increased residence time during flow interruptions. Steady flow conditions favor the release of smaller MOM (<0.45 µm). Compared to the reference, in the two-layer column experiments higher OC concentrations were detected in the effluent from PHE spiked columns after enhanced flow interruptions (26d, 52d). That indicated the PHE influenced production or mobilization of MOM. Parallel factor analysis of fluorescence excitation and emission matrices revealed the presence of a constant DOM background and two new unknown components in the effluent, probably PHE metabolites. The emergence of new components emphasizes the role of metabolization processes in the release of MOM. The identification of key microbial actors and communities are currently in progress. Totsche, K.U. et al. (2010): Biogeochemical interfaces in soil: The interdisciplinary challenge for soil science. J. Plant Nutr. Soil Sci., 173(1), 88-99 Ding, G.-C., Heuer, H. & Smalla, K. (2012): Dynamics of bacterial communities in two unpolluted soils after spiking with phenanthrene: soil type specific and common responders. Front Microbio 10.3389/fmicb.2012.00290.

Using atomistic simulations to model cadmium telluride thin film growth

NASA Astrophysics Data System (ADS)

Yu, Miao; Kenny, Steven D.

2016-03-01

Cadmium telluride (CdTe) is an excellent material for low-cost, high efficiency thin film solar cells. It is important to conduct research on how defects are formed during the growth process, since defects lower the efficiency of solar cells. In this work we use computer simulation to predict the growth of a sputter deposited CdTe thin film. On-the-fly kinetic Monte Carlo technique is used to simulate the CdTe thin film growth on the (1 1 1) surfaces. The results show that on the (1 1 1) surfaces the growth mechanisms on surfaces which are terminated by Cd or Te are quite different, regardless of the deposition energy (0.1∼ 10 eV). On the Te-terminated (1 1 1) surface the deposited clusters first form a single mixed species layer, then the Te atoms in the mixed layer moved up to form a new layer. Whilst on the Cd-terminated (1 1 1) surface the new Cd and Te layers are formed at the same time. Such differences are probably caused by stronger bonding between ad-atoms and surface atoms on the Te layer than on the Cd layer.

Marangoni-Benard Convection in a Evaporating Liquid Thin Layer

NASA Technical Reports Server (NTRS)

Chai, An-Ti; Zhang, Nengli

1996-01-01

Marangoni-Benard convection in evaporating liquid thin layers has been investigated through flow visualization and temperature profile measurement. Twelve liquids, namely ethyl alcohol, methanol, chloroform, acetone, cyclohexane, benzine, methylene chloride, carbon tetrachloride, ethyl acetate, n-pentane, silicone oil (0.65 cSt.), and freon-113, were tested and convection patterns in thin layers of these samples were observed. Comparison among these tested samples shows that some liquids are sensitive to surface contamination from aluminum powder but some are not. The latter is excellent to be used for the investigation of surface-tension driven convection through visualization using the tracer. Two sample liquids, alcohol and freon-113 were particularly selected for systematic study. It was found that the wavelength of Benard cells would not change with thickness of the layer when it evaporates at room temperature. Special attention was focused on cases in which a liquid layer was cooled from below, and some interesting results were obtained. Convection patterns were recorded during the evaporation process and the patterns at certain time frame were compared. Benard cells were observed in thin layers with a nonlinear temperature profile and even with a zero or positive temperature gradient. Wavelength of the cells was found to increase as the evaporation progressed.

Solid oxide fuel cell having monolithic core

DOEpatents

Ackerman, John P.; Young, John E.

1984-01-01

A solid oxide fuel cell for electrochemically combining fuel and oxidant for generating galvanic output, wherein the cell core has an array of electrolyte and interconnect walls that are substantially devoid of any composite inert materials for support. Instead, the core is monolithic, where each electrolyte wall consists of thin layers of cathode and anode materials sandwiching a thin layer of electrolyte material therebetween, and each interconnect wall consists of thin layers of the cathode and anode materials sandwiching a thin layer of interconnect material therebetween. The electrolyte walls are arranged and backfolded between adjacent interconnect walls operable to define a plurality of core passageways alternately arranged where the inside faces thereof have only the anode material or only the cathode material exposed. Means direct the fuel to the anode-exposed core passageways and means direct the oxidant to the cathode-exposed core passageway; and means also direct the galvanic output to an exterior circuit. Each layer of the electrolyte and interconnect materials is of the order of 0.002-0.01 cm thick; and each layer of the cathode and anode materials is of the order of 0.002-0.05 cm thick.

Exciton-dominated dielectric function of atomically thin MoS 2 films

DOE PAGES

Yu, Yiling; Yu, Yifei; Cai, Yongqing; ...

2015-11-24

We systematically measure the dielectric function of atomically thin MoS 2 films with different layer numbers and demonstrate that excitonic effects play a dominant role in the dielectric function when the films are less than 5–7 layers thick. The dielectric function shows an anomalous dependence on the layer number. It decreases with the layer number increasing when the films are less than 5–7 layers thick but turns to increase with the layer number for thicker films. We show that this is because the excitonic effect is very strong in the thin MoS 2 films and its contribution to the dielectricmore » function may dominate over the contribution of the band structure. We also extract the value of layer-dependent exciton binding energy and Bohr radius in the films by fitting the experimental results with an intuitive model. The dominance of excitonic effects is in stark contrast with what reported at conventional materials whose dielectric functions are usually dictated by band structures. Lastly, the knowledge of the dielectric function may enable capabilities to engineer the light-matter interactions of atomically thin MoS 2 films for the development of novel photonic devices, such as metamaterials, waveguides, light absorbers, and light emitters.« less

High efficiency copper indium gallium diselenide (CIGS) thin film solar cells

NASA Astrophysics Data System (ADS)

Rajanikant, Ray Jayminkumar

The generation of electrical current from the solar radiation is known as the photovoltaic effect. Solar cell, also known as photovoltaic (PV) cell, is a device that works on the principle of photovoltaic effect, and is widely used for the generation of electricity. Thin film polycrystalline solar cells based on copper indium gallium diselenide (CIGS) are admirable candidates for clean energy production with competitive prices in the near future. CIGS based polycrystalline thin film solar cells with efficiencies of 20.3 % and excellent temperature stability have already been reported at the laboratory level. The present study discusses about the fabrication of CIGS solar cell. Before the fabrication part of CIGS solar cell, a numerical simulation is carried out using One-Dimensional Analysis of Microelectronic and Photonic Structures (AMPS-ID) for understanding the physics of a solar cell device, so that an optimal structure is analyzed. In the fabrication part of CIGS solar cell, Molybdenum (Mo) thin film, which acts as a 'low' resistance metallic back contact, is deposited by RF magnetron sputtering on organically cleaned soda lime glass substrate. The major advantages for using Mo are high temperature, (greater than 600 °C), stability and inertness to CIGS layer (i.e., no diffusion of CIGS into Mo). Mo thin film is deposited at room temperature (RT) by varying the RF power and the working pressure. The Mo thin films deposited with 100 W RF power and 1 mTorr working pressure show a reflectivity of above average 50 % and the low sheet resistance of about 1 O/□. The p-type CIGS layer is deposited on Mo. Before making thin films of CIGS, a powder of CIGS material is synthesized using melt-quenching method. Thin films of CIGS are prepared by a single-stage flash evaporation process on glass substrates, initially, for optimization of deposition parameters and than on Mo coated glass substrates for device fabrication. CIGS thin film is deposited at 250 °C at a pressure of 10-5 mbar. The thickness of the film was kept 1 mum for the solar cell device preparation. Rapid Thermal Annealing (RTA) is carried out of CIGS thin film at 500 °C for 2 minutes in the argon atmosphere. Annealing process mainly improves the grain growth of the CIGS and, hence the surface roughness, which is essential for a multilayered semiconductor structure. Thin layer of n-type highly resistive cadmium sulphide (CdS), generally known as a "buffer" layer, is deposited on CIGS layer by thermal and flash evaporation method at the substrate temperature of 100 °C. The CdS thin film plays a crucial role in the formation of the p-n junction and thus the solar cell device performance. The effect of CdS film substrate temperature ranging from 50 °C to 200 °C is observed. At the 100 °C substrate temperature, CdS thin film shows the near to 85 % of transmission in the visible region and resistivity of the order of greater then 20 x 109 Ocm, which are the essential characteristics of buffer layer. The bi-layer structure of ZnO, containing 70 nm i-ZnO and 500 nm aluminum (Al) doped ZnO, act as a transparent front-contact for CIGS thin film solar cell. These layers were deposited using RF magnetron sputtering. i-ZnO thin film acts as an insulating layer, which prevents the recombination of the photo-generated carries and also minimizes the lattice miss match defects between CdS and Al-ZnO. The resistivity of iZnO and Al-ZnO is of the order of 1012 Ocm and 10-4 Ocm, respectively. Al-ZnO thin films act as transparent conducting top electrode having transparency of about 85 % in the visible region. On Al-ZnO layer the finger-type grid pattern of silver (Ag), 200 nm thick, is deposited for the collection of photo-generated carriers. The thin film based multilayered structure Mo / CIGS / CdS / i-ZnO / Al-ZnO / Ag grid of CIGS solar cell is grown one by one on a single glass substrate. As-prepared CIGS solar cell device shows a minute photovoltaic effect. For the further improvement of the cell we have varied the thickness of the buffer layer i.e. CdS. In addition, the deposition of CdS is carried out using flash evaporation method to improve the CIGS/CdS junction. Heat soak pulses of about 200 °C are also applied for 20 sec for the further upgrading the junction. To protect the CIGS/CdS junction from the high-energy sputtered particles of ZnO, a fine mesh of stainless steel is placed just before the sample holder to enhance the performance of the solar cell. The influence of the thickness of iZnO and CdS has been checked. The maximum V oe and Jsc of about 138 mV and 1.3 mA/cm2 , respectively, are achieved using flash evaporated CIGS layer and flash evaporated CdS thin film. Further improvement of current performance can be done either by adopting some other fabrication method to obtain a denser CIGS absorber layer or replacing the CdS layer with some other efficient buffer layer.

Effect of thinning and soil treatments on Pinus ponderosa plantations: 15-year results

Treesearch

Jianwei Zhang; Jeff Webster; David H. Young; Gary O. Fiddler

2016-01-01

Thinning with removal of whole trees in a plantation or natural forest stand raises two main concerns – soil compaction from the ground-based machinery and nutrient depletion particularly with whole tree harvest as is often practiced for attendant fuels reduction. To address these concerns, two sets of experimental treatments were imposed in young ponderosa pine...

Seeding versus natural regeneration: A comparison of vegetation change following thinning and burning in ponderosa pine

Treesearch

Judith D. Springer; Amy E. M. Waltz; Peter Z. Fule; Margaret M. Moore; W. Wallace Covington

2001-01-01

The decision whether to seed with native species following restoration treatments should be based on existing vegetation, species present in or absent from the soil seed bank, past management history, microclimate conditions and soils. We installed three permanent monitoring plots in two areas (total 18.6 ha) at Mt. Trumbull, AZ. Trees were thinned and the sites burned...

Speciation and Lability of Ag-, AgCl- and Ag2S-Nanoparticles in Soil Determined by X-ray Absorption Spectroscopy and Diffusive Gradients in Thin Films

EPA Science Inventory

Long-term speciation and lability of silver (Ag-), silver chloride (AgCl-) and silver sulfide nanoparticles (Ag₂S-NPs) in soil were studied by X-ray absorption spectroscopy (XAS), and newly developed "nano" Diffusive Gradients in Thin Films (DGT) devices. These nano-D...

Soil Moisture Controls the Thermal Habitat of Active Layer Soils in the McMurdo Dry Valleys, Antarctica

NASA Astrophysics Data System (ADS)

Wlostowski, A. N.; Gooseff, M. N.; Adams, B. J.

2018-01-01

Antarctic soil ecosystems are strongly controlled by abiotic habitat variables. Regional climate change in the McMurdo Dry Valleys is expected to cause warming over the next century, leading to an increase in frequency of freeze-thaw cycling in the soil habitat. Previous studies show that physiological stress associated with freeze-thaw cycling adversely affects invertebrate populations by decreasing abundance and positively selecting for larger body sizes. However, it remains unclear whether or not climate warming will indeed enhance the frequency of annual freeze-thaw cycling and associated physiological stresses. This research quantifies the frequency, rate, and spatial heterogeneity of active layer freezing to better understand how regional climate change may affect active layer soil thermodynamics, and, in turn, affect soil macroinvertebrate communities. Shallow active layer temperature, specific conductance, and soil moisture were observed along natural wetness gradients. Field observations show that the frequency and rate of freeze events are nonlinearly related to freezable soil moisture (θf). Over a 2 year period, soils at θf < 0.080 m3/m3 experienced between 15 and 35 freeze events and froze rapidly compared to soils with θf > 0.080 m3/m3, which experienced between 2 and 6 freeze events and froze more gradually. A numerical soil thermodynamic model is able to simulate observed freezing rates across a range of θf, reinforcing a well-known causal relationship between soil moisture and active layer freezing dynamics. Findings show that slight increases in soil moisture can potentially offset the effect of climate warming on exacerbating soil freeze-thaw cycling.

Method of forming contacts for a back-contact solar cell

DOEpatents

Manning, Jane

2013-07-23

Methods of forming contacts for back-contact solar cells are described. In one embodiment, a method includes forming a thin dielectric layer on a substrate, forming a polysilicon layer on the thin dielectric layer, forming and patterning a solid-state p-type dopant source on the polysilicon layer, forming an n-type dopant source layer over exposed regions of the polysilicon layer and over a plurality of regions of the solid-state p-type dopant source, and heating the substrate to provide a plurality of n-type doped polysilicon regions among a plurality of p-type doped polysilicon regions.

Mercury accumulation in the surface layers of mountain soils: a case study from the Karkonosze Mountains, Poland.

PubMed

Szopka, Katarzyna; Karczewska, Anna; Kabała, Cezary

2011-06-01

The study was aimed to examine total concentrations and pools of Hg in surface layers of soils in the Karkonosze Mountains, dependent on soil properties and site locality. Soil samples were collected from a litter layer and the layers 0-10 cm and 10-20 cm, at 68 sites belonging to the net of a monitoring system, in two separate areas, and in three altitudinal zones: below 900 m, 900-1100 m, and over 1100 m. Air-borne pollution was the major source of mercury in soils. Hg has accumulated mainly in the litter (where its concentrations were the highest), and in the layer 0-10 cm. Hg concentrations in all samples were in the range 0.04-0.97 mg kg(-1), with mean values 0.38, 0.28, and 0.14 mg kg(-1) for litter and the layers 0-10 cm and 10-20 cm, respectively. The highest Hg concentrations in the litter layer were found in the intermediate altitudinal zone, whereas Hg concentrations in the layer 0-10 cm increased with increasing altitude. Soil quality standard for protected areas (0.50 mg kg(-1)) was exceeded in a few sites. The pools of Hg accumulated in soils were in the range: 0.8-84.8 mg m(-2), with a mean value of 16.5 mg m(-2), and they correlated strongly with the pools of stored organic matter. Copyright © 2011 Elsevier Ltd. All rights reserved.

Characteristics of water infiltration in layered water repellent soils

USDA-ARS?s Scientific Manuscript database

Hydrophobic soil can influence soil water infiltration, but information regarding the impacts of different levels of hydrophobicity within a layered soil profile is limited. An infiltration study was conducted to determine the effects of different levels of hydrophobicity and the position of the hyd...

Observations of metal concentrations in E-region sporadic thin layers using incoherent-scatter radar

NASA Astrophysics Data System (ADS)

Suzuki, Nobuhiro

This thesis has used incoherent-scatter radar data from the facility at Sondrestrom, Greenland to determine the ion mass values inside thin sporadic-E layers in the lower ionosphere. Metallic positively-charged ions of meteoric origin are deposited in the earth's upper atmosphere over a height range of about 85-120 km. Electric fields and neutral-gas (eg N2, O, O2) winds at high latitudes may produce convergent ion dynamics that results in the re-distribution of the background altitude distribution of the ions to form thin (1-3 km) high-density layers that are detectable with radar. A large database of experimental radar observations has been processed to determine ion mass values inside these thin ion layers. The range resolution of the radar was 600 meters that permitted mass determinations at several altitude steps within the layers. Near the lower edge of the layers the ion mass values were in the range 20-25 amu while at the top portion of the layers the mass values were generally in the range 30-40 amu. The numerical values are consistent with in-situ mass spectrometer data obtained by other researchers that suggest these layers are mainly composed of a mixture or Mg +, Si+, and Fe + ions. The small tendency for heavier ions to reside at the top portion of the layers is consistent with theory. The results have also found new evidence for the existence of complex-shaped multiple layers; the examples studied suggest similar ion mass values in different layers that in some cases are separated in altitude by several km.

The effects of GaN nanocolumn arrays and thin SixNy buffer layers on the morphology of GaN layers grown by plasma-assisted molecular beam epitaxy on Si(111) substrates

NASA Astrophysics Data System (ADS)

Shubina, K. Yu; Pirogov, E. V.; Mizerov, A. M.; Nikitina, E. V.; Bouravleuv, A. D.

2018-03-01

The effects of GaN nanocolumn arrays and a thin SixNy layer, used as buffer layers, on the morphology of GaN epitaxial layers are investigated. Two types of samples with different buffer layers were synthesized by PA-MBE. The morphology of the samples was characterized by SEM. The crystalline quality of the samples was assessed by XRD. The possibility of synthesis of continuous crystalline GaN layers on Si(111) substrates without the addition of other materials such as aluminum nitride was demonstrated.

Thin layer asphaltic concrete density measuring using nuclear gages.

DOT National Transportation Integrated Search

1989-03-01

A Troxler 4640 thin layer nuclear gage was evaluated under field conditions to determine if it would provide improved accuracy of density measurements on asphalt overlays of 1-3/4 and 2 inches in thickness. Statistical analysis shows slightly improve...

High-performance thin layer chromatography to assess pharmaceutical product quality.

PubMed

Kaale, Eliangiringa; Manyanga, Vicky; Makori, Narsis; Jenkins, David; Michael Hope, Samuel; Layloff, Thomas

2014-06-01

To assess the sustainability, robustness and economic advantages of high-performance thin layer chromatography (HPTLC) for quality control of pharmaceutical products. We compared three laboratories where three lots of cotrimoxazole tablets were assessed using different techniques for quantifying the active ingredient. The average assay relative standard deviation for the three lots was 1.2 with a range of 0.65-2.0. High-performance thin layer chromatography assessments are yielding valid results suitable for assessing product quality. The local pharmaceutical manufacturer had evolved the capacity to produce very high quality products. © 2014 John Wiley & Sons Ltd.

[Thin layer agar represents a cost-effective alternative for the rapid diagnosis of multi-drug resistant tuberculosis].

PubMed

Hernández-Sarmiento, José M; Martínez-Negrete, Milton A; Castrillón-Velilla, Diana M; Mejía-Espinosa, Sergio A; Mejía-Mesa, Gloria I; Zapata-Fernández, Elsa M; Rojas-Jiménez, Sara; Marín-Castro, Andrés E; Robledo-Restrepo, Jaime A

2014-01-01

Using cost-benefit analysis for comparing the thin-layer agar culture method to the standard multiple proportion method used in diagnosing multidrug-resistant tuberculosis (MDR TB). A cost-benefit evaluation of two diagnostic tests was made at the Corporación para Investigaciones Biológicas (CIB) in Medellín, Colombia. 100 patients were evaluated; 10.8% rifampicin resistance and 14.3% isoniazid resistance were found. A computer-based decision tree model was used for cost-effectiveness analysis (Treeage Pro); the thin-layer agar culture method was most cost-effective, having 100% sensitivity, specificity and predictive values for detecting rifampicin and isoniazid resistance. The multiple proportion method value was calculated as being US$ 71 having an average 49 day report time compared to US$ 18 and 14 days for the thin-layer agar culture method. New technologies have been developed for diagnosing tuberculosis which are apparently faster and more effective; their operating characteristics must be evaluated as must their effectiveness in terms of cost-benefit. The present study established that using thin-layer agar culture was cheaper, equally effective and could provide results more quickly than the traditional method. This implies that a patient could receive MDR TB treatment more quickly.

Enhanced stability of thin film transistors with double-stacked amorphous IWO/IWO:N channel layer

NASA Astrophysics Data System (ADS)

Lin, Dong; Pi, Shubin; Yang, Jianwen; Tiwari, Nidhi; Ren, Jinhua; Zhang, Qun; Liu, Po-Tsun; Shieh, Han-Ping

2018-06-01

In this work, bottom-gate top-contact thin film transistors with double-stacked amorphous IWO/IWO:N channel layer were fabricated. Herein, amorphous IWO and N-doped IWO were deposited as front and back channel layers, respectively, by radio-frequency magnetron sputtering. The electrical characteristics of the bi-layer-channel thin film transistors (TFTs) were examined and compared with those of single-layer-channel (i.e., amorphous IWO or IWO:N) TFTs. It was demonstrated to exhibit a high mobility of 27.2 cm2 V‑1 s‑1 and an on/off current ratio of 107. Compared to the single peers, bi-layer a-IWO/IWO:N TFTs showed smaller hysteresis and higher stability under negative bias stress and negative bias temperature stress. The enhanced performance could be attributed to its unique double-stacked channel configuration, which successfully combined the merits of the TFTs with IWO and IWO:N channels. The underlying IWO thin film provided percolation paths for electron transport, meanwhile, the top IWO:N layer reduced the bulk trap densities. In addition, the IWO channel/gate insulator interface had reduced defects, and IWO:N back channel surface was insensitive to the ambient atmosphere. Overall, the proposed bi-layer a-IWO/IWO:N TFTs show potential for practical applications due to its possibly long-term serviceability.

The Implement of a Multi-layer Frozen Soil Scheme into SSiB3 and its Evaluation over Cold Regions

NASA Astrophysics Data System (ADS)

Li, Q.

2016-12-01

The SSiB3 is a biophysics-based model of land-atmosphere interactions and is designed for global and regional studies. It has three soil layers, three snow layers, as well as one vegetation layer. Soil moisture of the three soil layers, interception water store for the canopy, subsurface soil temperature, ground temperature, canopy temperature and snow water equivalent are all predicted based on the water and energy balance at canopy, soil and snow. SSiB3 substantially enhances the model's capability for cold season studies and produces reasonable results compared with observations. However, frozen soil processes are ignored in the SSiB3 and may have effects on the interannual variability of soil temperature and deep soil memory. A multi-layer comprehensive frozen soil scheme (FSM), which is developed for climate study has been implemented into the SSiB3 to describe soil heat transfer and water flow affected by frozen processed in soil. In the coupled SSiB3-FSM, both liquid water and ice content have been taken into account in the frozen soil hydrologic and thermal property parameterization. The maximum soil layer depth could reach 10 meters thick depending on land conditions. To better evaluate the models' performance, the coupled offline SSiB3-FSM and SSiB3 have been driven from 1948 to 1958 by the Princeton global meteorological data set, respectively. For the 10yrs run, the coupled SSiB3-FSM almost captures the features over different regions, especially cold regions. In order to analysis and compare the differences of SSIB3-FSM and SSIB3 in detail, monthly mean surface temperature for different regions are compared with CAMS data. The statistical results of surface skin temperature show that high latitude regions, Africa, Eastern Australia, and North American monsoon regions have been greatly improved in SSIB3-FSM. For the global statistics, the RMSE of the surface temperature simulated by SSiB3-FSM can be improved about 0.6K compared to SSiB3. In this study, the improvements in the coupled SSiB3-FSM have also been analyzed.

Stability of organic carbon in deep soil layers controlled by fresh carbon supply.

PubMed

Fontaine, Sébastien; Barot, Sébastien; Barré, Pierre; Bdioui, Nadia; Mary, Bruno; Rumpel, Cornelia

2007-11-08

The world's soils store more carbon than is present in biomass and in the atmosphere. Little is known, however, about the factors controlling the stability of soil organic carbon stocks and the response of the soil carbon pool to climate change remains uncertain. We investigated the stability of carbon in deep soil layers in one soil profile by combining physical and chemical characterization of organic carbon, soil incubations and radiocarbon dating. Here we show that the supply of fresh plant-derived carbon to the subsoil (0.6-0.8 m depth) stimulated the microbial mineralization of 2,567 +/- 226-year-old carbon. Our results support the previously suggested idea that in the absence of fresh organic carbon, an essential source of energy for soil microbes, the stability of organic carbon in deep soil layers is maintained. We propose that a lack of supply of fresh carbon may prevent the decomposition of the organic carbon pool in deep soil layers in response to future changes in temperature. Any change in land use and agricultural practice that increases the distribution of fresh carbon along the soil profile could however stimulate the loss of ancient buried carbon.

Development of buffer layer structure for epitaxial growth of (100)/(001)Pb(Zr,Ti)O3-based thin film on (111)Si wafer

NASA Astrophysics Data System (ADS)

Hayasaka, Takeshi; Yoshida, Shinya; Tanaka, Shuji

2017-07-01

This paper reports on the development of a novel buffer layer structure, (100)SrRuO3/(100)LaNiO3/(111)Pt/(111)CeO2, for the epitaxial growth of a (100)/(001)-oriented Pb(Zr,Ti)O3 (PZT)-based thin film on a (111)Si wafer. (111)Pt and (111)CeO2 were epitaxially grown on (111)Si straightforwardly. Then, the crystal orientation was forcibly changed from (111) to (100) at the LaNiO3 layer owing to its strong (100)-self-orientation property, which enabled the cube-on-cube epitaxial growth of the subsequent (100)SrRuO3 layer and preferentially (100)/(001)-oriented PZT-based thin film. The PZT-based epitaxial thin films were comprehensively characterized in terms of the crystallinity, in-plane epitaxial relationships, piezoelectricity, and so forth. This buffer layer structure for the epitaxial growth of PZT can be applied to piezoelectric micro-electro-mechanical systems (MEMS) vibrating ring gyroscopes.

Direct numerical simulation of turbulent Rayleigh-Bénard convection in a vertical thin disk

NASA Astrophysics Data System (ADS)

Xu, Wei; Wang, Yin; He, Xiao-Zhou; Yik, Hiu-Fai; Wang, Xiao-Ping; Schumacher, Jorg; Tong, Penger

2017-11-01

We report a direct numerical simulation (DNS) of turbulent Rayleigh-Bénard convection in a thin vertical disk with a high-order spectral element method code NEK5000. An unstructured mesh is used to adapt the turbulent flow in the thin disk and to ensure that the mesh sizes satisfy the refined Groetzbach criterion and a new criterion for thin boundary layers proposed by Shishkina et al. The DNS results for the mean and variance temperature profiles in the thermal boundary layer region are found to be in good agreement with the predictions of the new boundary layer models proposed by Shishkina et al. and Wang et al.. Furthermore, we numerically calculate the five budget terms in the boundary layer equation, which are difficult to measure in experiment. The DNS results agree well with the theoretical predictions by Wang et al. Our numerical work thus provides a strong support for the development of a common framework for understanding the effect of boundary layer fluctuations. This work was supported in part by Hong Kong Research Grants Council.

High density nonmagnetic cobalt in thin films

NASA Astrophysics Data System (ADS)

Banu, Nasrin; Singh, Surendra; Basu, Saibal; Roy, Anupam; Movva, Hema C. P.; Lauter, V.; Satpati, B.; Dev, B. N.

2018-05-01

Recently high density (HD) nonmagnetic cobalt has been discovered in a nanoscale cobalt thin film, grown on Si(111) single crystal. This form of cobalt is not only nonmagnetic but also superconducting. These promising results have encouraged further investigations of the growth of the nonmagnetic (NM) phase of cobalt. In the original investigation, the cobalt film had a natural cobalt oxide at the top. We have investigated whether the growth of HD NM cobalt layers in the thin film depends on (i) a capping layer on the cobalt film, (ii) the thickness of the cobalt film and (iii) the nature of the substrate on which the cobalt film is grown. The results of such investigations indicate that for cobalt films capped with a thin gold layer, and for various film thicknesses, HD NM cobalt layers are formed. However, instead of a Si substrate, when the cobalt films are grown on oxide substrates, such as silicon oxide or cobalt oxide, HD NM cobalt layers are not formed. The difference is attributed to the nature—crystalline or amorphous—of the substrate.

Impact of ultra-thin Al2O3-y layers on TiO2-x ReRAM switching characteristics

NASA Astrophysics Data System (ADS)

Trapatseli, Maria; Cortese, Simone; Serb, Alexander; Khiat, Ali; Prodromakis, Themistoklis

2017-05-01

Transition metal-oxide resistive random access memory devices have demonstrated excellent performance in switching speed, versatility of switching and low-power operation. However, this technology still faces challenges like poor cycling endurance, degradation due to high electroforming (EF) switching voltages and low yields. Approaches such as engineering of the active layer by doping or addition of thin oxide buffer layers have been often adopted to tackle these problems. Here, we have followed a strategy that combines the two; we have used ultra-thin Al2O3-y buffer layers incorporated between TiO2-x thin films taking into account both 3+/4+ oxidation states of Al/Ti cations. Our devices were tested by DC and pulsed voltage sweeping and in both cases demonstrated improved switching voltages. We believe that the Al2O3-y layers act as reservoirs of oxygen vacancies which are injected during EF, facilitate a filamentary switching mechanism and provide enhanced filament stability, as shown by the cycling endurance measurements.