Using dynamic mode decomposition for real-time background/foreground separation in video

DOE Office of Scientific and Technical Information (OSTI.GOV)

Kutz, Jose Nathan; Grosek, Jacob; Brunton, Steven

The technique of dynamic mode decomposition (DMD) is disclosed herein for the purpose of robustly separating video frames into background (low-rank) and foreground (sparse) components in real-time. Foreground/background separation is achieved at the computational cost of just one singular value decomposition (SVD) and one linear equation solve, thus producing results orders of magnitude faster than robust principal component analysis (RPCA). Additional techniques, including techniques for analyzing the video for multi-resolution time-scale components, and techniques for reusing computations to allow processing of streaming video in real time, are also described herein.

Dynamic correlations at different time-scales with empirical mode decomposition

NASA Astrophysics Data System (ADS)

Nava, Noemi; Di Matteo, T.; Aste, Tomaso

2018-07-01

We introduce a simple approach which combines Empirical Mode Decomposition (EMD) and Pearson's cross-correlations over rolling windows to quantify dynamic dependency at different time scales. The EMD is a tool to separate time series into implicit components which oscillate at different time-scales. We apply this decomposition to intraday time series of the following three financial indices: the S&P 500 (USA), the IPC (Mexico) and the VIX (volatility index USA), obtaining time-varying multidimensional cross-correlations at different time-scales. The correlations computed over a rolling window are compared across the three indices, across the components at different time-scales and across different time lags. We uncover a rich heterogeneity of interactions, which depends on the time-scale and has important lead-lag relations that could have practical use for portfolio management, risk estimation and investment decisions.

Design and testing of a pilot scale magnetic separator for the treatment of textile dyeing wastewater.

PubMed

Salinas, Tobías; Durruty, Ignacio; Arciniegas, Lorena; Pasquevich, Gustavo; Lanfranconi, Matías; Orsi, Isabela; Alvarez, Vera; Bonanni, Sebastian

2018-07-15

Iron nanoparticles can be incorporated on the structure of natural clays to obtain magnetic clays, an adsorbent that be easily removed from a wastewater by magnetic means. Magnetic clays have high adsorption capacities of different contaminants such as heavy metals, fungicides, aromatic compounds and colorants and show rapid adsorption kinetics, but crucial data for achieving its full or pilot scale application is still lacking. In this work, magnetic bentonites with different amounts of magnetite (iron fractions on the clay of 0.55, 0.6 and 0.6) were used to remove color from a real textile wastewater. On a first stage the optimal conditions for the adsorption of the dye, including pH, temperature and clay dosage were determined. Also design parameters for the separation process such as residence time, distance from magnet to magnetic clay and magnet strength were obtained. Finally a pilot scale magnetic drum separator was constructed and tested. A removal of 60% of the dye from a wastewater that contained more than 250 ppm of azo dye was achieved with only 10 min of residence time inside the separator. Copyright © 2018 Elsevier Ltd. All rights reserved.

Measurement instruments to assess posture, gait, and balance in Parkinson's disease: Critique and recommendations.

PubMed

Bloem, Bastiaan R; Marinus, Johan; Almeida, Quincy; Dibble, Lee; Nieuwboer, Alice; Post, Bart; Ruzicka, Evzen; Goetz, Christopher; Stebbins, Glenn; Martinez-Martin, Pablo; Schrag, Anette

2016-09-01

Disorders of posture, gait, and balance in Parkinson's disease (PD) are common and debilitating. This MDS-commissioned task force assessed clinimetric properties of existing rating scales, questionnaires, and timed tests that assess these features in PD. A literature review was conducted. Identified instruments were evaluated systematically and classified as "recommended," "suggested," or "listed." Inclusion of rating scales was restricted to those that could be used readily in clinical research and practice. One rating scale was classified as "recommended" (UPDRS-derived Postural Instability and Gait Difficulty score) and 2 as "suggested" (Tinetti Balance Scale, Rating Scale for Gait Evaluation). Three scales requiring equipment (Berg Balance Scale, Mini-BESTest, Dynamic Gait Index) also fulfilled criteria for "recommended" and 2 for "suggested" (FOG score, Gait and Balance Scale). Four questionnaires were "recommended" (Freezing of Gait Questionnaire, Activities-specific Balance Confidence Scale, Falls Efficacy Scale, Survey of Activities, and Fear of Falling in the Elderly-Modified). Four tests were classified as "recommended" (6-minute and 10-m walk tests, Timed Up-and-Go, Functional Reach). We identified several questionnaires that adequately assess freezing of gait and balance confidence in PD and a number of useful clinical tests. However, most clinical rating scales for gait, balance, and posture perform suboptimally or have been evaluated insufficiently. No instrument comprehensively and separately evaluates all relevant PD-specific gait characteristics with good clinimetric properties, and none provides separate balance and gait scores with adequate content validity for PD. We therefore recommend the development of such a PD-specific, easily administered, comprehensive gait and balance scale that separately assesses all relevant constructs. © 2016 International Parkinson and Movement Disorder Society. © 2016 International Parkinson and Movement Disorder Society.

Enantioselective Analytical- and Preparative-Scale Separation of Hexabromocyclododecane Stereoisomers Using Packed Column Supercritical Fluid Chromatography.

PubMed

Riddell, Nicole; Mullin, Lauren Gayle; van Bavel, Bert; Ericson Jogsten, Ingrid; McAlees, Alan; Brazeau, Allison; Synnott, Scott; Lough, Alan; McCrindle, Robert; Chittim, Brock

2016-11-10

Hexabromocyclododecane (HBCDD) is an additive brominated flame retardant which has been listed in Annex A of the Stockholm Convention for elimination of production and use. It has been reported to persist in the environment and has the potential for enantiomer-specific degradation, accumulation, or both, making enantioselective analyses increasingly important. The six main stereoisomers of technical HBCDD (i.e., the (+) and (-) enantiomers of α-, β-, and γ-HBCDD) were separated and isolated for the first time using enantioselective packed column supercritical fluid chromatography (pSFC) separation methods on a preparative scale. Characterization was completed using published chiral liquid chromatography (LC) methods and elution profiles, as well as X-ray crystallography, and the isolated fractions were definitively identified. Additionally, the resolution of the enantiomers, along with two minor components of the technical product (δ- and ε-HBCDD), was investigated on an analytical scale using both LC and pSFC separation techniques, and changes in elution order were highlighted. Baseline separation of all HBCDD enantiomers was achieved by pSFC on an analytical scale using a cellulose-based column. The described method emphasizes the potential associated with pSFC as a green method of isolating and analyzing environmental contaminants of concern.

Comparison of turbulent separation over a smooth surface and mako shark skin on a NACA 4412 hydrofoil

NASA Astrophysics Data System (ADS)

Smith, Drew; Lang, Amy; Wahidi, Redha

2011-11-01

Shark skin is being investigated as a means of passive flow separation control due to the flexibility and preferential flow direction of the scales covering the skin. In this study, the effect of the scales is observed in a tripped turbulent boundary layer by comparing the flow over a NACA 4412 hydrofoil with a smooth surface to that over the same hydrofoil with samples of mako shark skin affixed to its upper surface. These samples were taken from the flank area of the shark because the scales at that location have been shown to have the greatest angle of erection, and thus the best potential for separation control. All flow data in this study was obtained using Time-Resolved Digital Particle Image Velocimetry and recorded at multiple angles of attack (between 8 and 16 degrees) and two Reynolds numbers. The flow was primarily analyzed by means of the backflow coefficient (a value based on the percentage of time that flow in a region over the hydrofoil is reversed) and the time history of instantaneous flow velocity values at specific points in the boundary layer over the hydrofoil models. Research performed under NSF grant 0932352.

Through the Eye of the Needle: The Separator and its Environs

NASA Astrophysics Data System (ADS)

Scudder, J. D.; Mozer, F. S.; Maynard, N. C.; Russell, C. T.

2001-05-01

The observed properties of the electromagnetic field and the plasma at and around a magnetic separator observed on May 29, 1996 with the ISTP GGS Polar satellite will be discussed. The electron pressure ridge will be illustrated astride the current layer, and the ion flow will be shown to impinge on the separator with MA ~= 0.1 and leave along the pressure ridge with MA ~= 1.1 33 traversals of rotational shear layers have been documented in this interval using the electron form of the Walen test. The electron fluid velocity is shown to have strong parallel Mach number enhancements along the separatrices, with peak parallel Alfven mach numbers of 4.5 that are probably limited by plasma time resolution (4.3s). These are similar in location to those in two fluid, hybrid, and particle - particle simulations of collisionless reconnection. The direct detection of the parallel electric field in the vicinity of the separator is shown in all cases to be limited by the so called Vasyliunas limit, $ E∥ <= O(1)√ {{{kTe}/{2m_ic2}}}| B|, that corresponds to the scale length of the pressure gradient being limited by the scale \\rho_s = \\beta_e^{1\\over2}{c\\over {\\omegapi}} seen to be important in the multi-species analysis of collisionless reconnection. In turn, the electron gas is shown at times not to drift at the E \\times B drift speed, but have substantial drifts perpendicular to B of a sense implied by the pressure divergences that cause the parallel electric field. Two techniques have been introduced to demonstrate the spectacular enhancement of the departures from cylindrical symmetry exhibited by the electrons as the separator null field region is traversed. Using totally separate arguments, the thermal electrons are shown to be clearly unmagnetized within the {c\\over{\\omegape}}$ scales about the separator, with the thermal gyroradius 10-30 times the scale length of B in this vicinity. At the moment level this demagnetization shows up as the loss of gyrotropy, or increase of ``agyrotropy''. In these regimes the thermal electrons can move onto different field lines and affect a loss of identity of field lines. Said differently, this agyrotropy requires the retention of the full tensorial electron pressure tensor to convey its effects in the multi-fluid treatments. Superposed epoch pictures of the spatial environment of the separator will be illustrated in different diagnostic "wavelengths" such as magnetic intensity, electron pressure, beta and gyroradius of electrons relative to scale lengths of B. In this way we provide the first in situ empirical definition of a site of collisionless magnetic reconnection and verify the demagnetization of electrons outlined by Vasyliunas 25 years ago as the likely mechanism for violation of the frozen flux theorem.

Experiments on an unsteady, three-dimensional separation

NASA Technical Reports Server (NTRS)

Henk, R. W.; Reynolds, W. C.; Reed, H. L.

1992-01-01

Unsteady, three-dimensional flow separation occurs in a variety of technical situations including turbomachinery and low-speed aircraft. An experimental program at Stanford in unsteady, three-dimensional, pressure-driven laminar separation has investigated the structure and time-scaling of these flows; of particular interest is the development, washout, and control of flow separation. Results reveal that a two-dimensional, laminar boundary layer passes through several stages on its way to a quasi-steady three-dimensional separation. The quasi-steady state of the separation embodies a complex, unsteady, vortical structure.

Micro-Macro Coupling in Plasma Self-Organization Processes during Island Coalescence

DOE Office of Scientific and Technical Information (OSTI.GOV)

Wan Weigang; Lapenta, Giovanni; Centrum voor Plasma-Astrofysica, Departement Wiskunde, Katholieke Universiteit Leuven, Celestijnenlaan 200B, 3001 Leuven

The collisionless island coalescence process is studied with particle-in-cell simulations, as an internal-driven magnetic self-organization scenario. The macroscopic relaxation time, corresponding to the total time required for the coalescence to complete, is found to depend crucially on the scale of the system. For small-scale systems, where the macroscopic scales and the dissipation scales are more tightly coupled, the relaxation time is independent of the strength of the internal driving force: the small-scale processes of magnetic reconnection adjust to the amount of the initial magnetic flux to be reconnected, indicating that at the microscopic scales reconnection is enslaved by the macroscopicmore » drive. However, for large-scale systems, where the micro-macro scale separation is larger, the relaxation time becomes dependent on the driving force.« less

A hybrid multiscale Monte Carlo algorithm (HyMSMC) to cope with disparity in time scales and species populations in intracellular networks.

PubMed

Samant, Asawari; Ogunnaike, Babatunde A; Vlachos, Dionisios G

2007-05-24

The fundamental role that intrinsic stochasticity plays in cellular functions has been shown via numerous computational and experimental studies. In the face of such evidence, it is important that intracellular networks are simulated with stochastic algorithms that can capture molecular fluctuations. However, separation of time scales and disparity in species population, two common features of intracellular networks, make stochastic simulation of such networks computationally prohibitive. While recent work has addressed each of these challenges separately, a generic algorithm that can simultaneously tackle disparity in time scales and population scales in stochastic systems is currently lacking. In this paper, we propose the hybrid, multiscale Monte Carlo (HyMSMC) method that fills in this void. The proposed HyMSMC method blends stochastic singular perturbation concepts, to deal with potential stiffness, with a hybrid of exact and coarse-grained stochastic algorithms, to cope with separation in population sizes. In addition, we introduce the computational singular perturbation (CSP) method as a means of systematically partitioning fast and slow networks and computing relaxation times for convergence. We also propose a new criteria of convergence of fast networks to stochastic low-dimensional manifolds, which further accelerates the algorithm. We use several prototype and biological examples, including a gene expression model displaying bistability, to demonstrate the efficiency, accuracy and applicability of the HyMSMC method. Bistable models serve as stringent tests for the success of multiscale MC methods and illustrate limitations of some literature methods.

Controllability of multiplex, multi-time-scale networks

NASA Astrophysics Data System (ADS)

Pósfai, Márton; Gao, Jianxi; Cornelius, Sean P.; Barabási, Albert-László; D'Souza, Raissa M.

2016-09-01

The paradigm of layered networks is used to describe many real-world systems, from biological networks to social organizations and transportation systems. While recently there has been much progress in understanding the general properties of multilayer networks, our understanding of how to control such systems remains limited. One fundamental aspect that makes this endeavor challenging is that each layer can operate at a different time scale; thus, we cannot directly apply standard ideas from structural control theory of individual networks. Here we address the problem of controlling multilayer and multi-time-scale networks focusing on two-layer multiplex networks with one-to-one interlayer coupling. We investigate the practically relevant case when the control signal is applied to the nodes of one layer. We develop a theory based on disjoint path covers to determine the minimum number of inputs (Ni) necessary for full control. We show that if both layers operate on the same time scale, then the network structure of both layers equally affect controllability. In the presence of time-scale separation, controllability is enhanced if the controller interacts with the faster layer: Ni decreases as the time-scale difference increases up to a critical time-scale difference, above which Ni remains constant and is completely determined by the faster layer. We show that the critical time-scale difference is large if layer I is easy and layer II is hard to control in isolation. In contrast, control becomes increasingly difficult if the controller interacts with the layer operating on the slower time scale and increasing time-scale separation leads to increased Ni, again up to a critical value, above which Ni still depends on the structure of both layers. This critical value is largely determined by the longest path in the faster layer that does not involve cycles. By identifying the underlying mechanisms that connect time-scale difference and controllability for a simplified model, we provide crucial insight into disentangling how our ability to control real interacting complex systems is affected by a variety of sources of complexity.

Transport and Lagrangian Statistics in Rotating Stratified Turbulence

NASA Astrophysics Data System (ADS)

Rosenberg, D. L.

2015-12-01

Transport plays a crucial role in geophysical flows, both in theatmosphere and in the ocean. Transport in such flows is ultimatelycontrolled by small-scale turbulence, although the large scales arein geostrophic balance between pressure gradient, gravity and Coriolisforces. As a result of the seemingly random nature of the flow, singleparticles are dispersed by the flow and on time scales significantlylonger than the eddy turn-over time, they undergo a diffusive motionwhose diffusion coefficient is the integral of the velocity correlationfunction. On intermediate time scales, in homogeneous, isotropic turbuilence(HIT) the separation between particle pairs has been argued to grow withtime according to the Richardson law: <(Δ x)2(t)> ~ t3, with aproportionality constant that depends on the initial particleseparation. The description of the phenomena associated withthe dispersion of single particles, or of particle pairs, ultimatelyrests on relatively simple statistical properties of the flowvelocity transporting the particles, in particular on its temporalcorrelation function. In this work, we investigate particle dispersionin the anisotropic case of rotating stratified turbulence examining whetherthe dependence on initial particle separation differs from HIT,particularly in the presence of an inverse cascade.

Anomalous volatility scaling in high frequency financial data

NASA Astrophysics Data System (ADS)

Nava, Noemi; Di Matteo, T.; Aste, Tomaso

2016-04-01

Volatility of intra-day stock market indices computed at various time horizons exhibits a scaling behaviour that differs from what would be expected from fractional Brownian motion (fBm). We investigate this anomalous scaling by using empirical mode decomposition (EMD), a method which separates time series into a set of cyclical components at different time-scales. By applying the EMD to fBm, we retrieve a scaling law that relates the variance of the components to a power law of the oscillating period. In contrast, when analysing 22 different stock market indices, we observe deviations from the fBm and Brownian motion scaling behaviour. We discuss and quantify these deviations, associating them to the characteristics of financial markets, with larger deviations corresponding to less developed markets.

Scaling and design of landslide and debris-flow experiments

USGS Publications Warehouse

Iverson, Richard M.

2015-01-01

Scaling plays a crucial role in designing experiments aimed at understanding the behavior of landslides, debris flows, and other geomorphic phenomena involving grain-fluid mixtures. Scaling can be addressed by using dimensional analysis or – more rigorously – by normalizing differential equations that describe the evolving dynamics of the system. Both of these approaches show that, relative to full-scale natural events, miniaturized landslides and debris flows exhibit disproportionately large effects of viscous shear resistance and cohesion as well as disproportionately small effects of excess pore-fluid pressure that is generated by debris dilation or contraction. This behavioral divergence grows in proportion to H3, where H is the thickness of a moving mass. Therefore, to maximize geomorphological relevance, experiments with wet landslides and debris flows must be conducted at the largest feasible scales. Another important consideration is that, unlike stream flows, landslides and debris flows accelerate from statically balanced initial states. Thus, no characteristic macroscopic velocity exists to guide experiment scaling and design. On the other hand, macroscopic gravity-driven motion of landslides and debris flows evolves over a characteristic time scale (L/g)1/2, where g is the magnitude of gravitational acceleration and L is the characteristic length of the moving mass. Grain-scale stress generation within the mass occurs on a shorter time scale, H/(gL)1/2, which is inversely proportional to the depth-averaged material shear rate. A separation of these two time scales exists if the criterion H/L < < 1 is satisfied, as is commonly the case. This time scale separation indicates that steady-state experiments can be used to study some details of landslide and debris-flow behavior but cannot be used to study macroscopic landslide or debris-flow dynamics.

Cycles, scaling and crossover phenomenon in length of the day (LOD) time series

NASA Astrophysics Data System (ADS)

Telesca, Luciano

2007-06-01

The dynamics of the temporal fluctuations of the length of the day (LOD) time series from January 1, 1962 to November 2, 2006 were investigated. The power spectrum of the whole time series has revealed annual, semi-annual, decadal and daily oscillatory behaviors, correlated with oceanic-atmospheric processes and interactions. The scaling behavior was analyzed by using the detrended fluctuation analysis (DFA), which has revealed two different scaling regimes, separated by a crossover timescale at approximately 23 days. Flicker-noise process can describe the dynamics of the LOD time regime involving intermediate and long timescales, while Brownian dynamics characterizes the LOD time series for small timescales.

Long-Baseline Comparisons of the Brazilian National Time Scale to UTC (NIST) Using Near Real-Time and Postprocessed Solutions

DTIC Science & Technology

2007-11-01

long baseline of ~8600 km. The comparisons were made with measurement systems developed for the Sistema Interamericano de Metrologia (SIM) comparison...measurements are compared and summarized. I. INTRODUCTION The Sistema Interamericano de Metrologia (SIM) is a regional metrology organization...Brazil. The two time scales are separated by a long baseline of ~8600 km. The comparisons were made with measurement systems developed for the Sistema

Implications of cellular models of dopamine neurons for disease

PubMed Central

Evans, Rebekah C.; Oster, Andrew M.; Pissadaki, Eleftheria K.; Drion, Guillaume; Kuznetsov, Alexey S.; Gutkin, Boris S.

2016-01-01

This review addresses the present state of single-cell models of the firing pattern of midbrain dopamine neurons and the insights that can be gained from these models into the underlying mechanisms for diseases such as Parkinson's, addiction, and schizophrenia. We will explain the analytical technique of separation of time scales and show how it can produce insights into mechanisms using simplified single-compartment models. We also use morphologically realistic multicompartmental models to address spatially heterogeneous aspects of neural signaling and neural metabolism. Separation of time scale analyses are applied to pacemaking, bursting, and depolarization block in dopamine neurons. Differences in subpopulations with respect to metabolic load are addressed using multicompartmental models. PMID:27582295

A new precipitation-based method of baseflow separation and event identification for small watersheds (<50 km2)

NASA Astrophysics Data System (ADS)

Koskelo, Antti I.; Fisher, Thomas R.; Utz, Ryan M.; Jordan, Thomas E.

2012-07-01

SummaryBaseflow separation methods are often impractical, require expensive materials and time-consuming methods, and/or are not designed for individual events in small watersheds. To provide a simple baseflow separation method for small watersheds, we describe a new precipitation-based technique known as the Sliding Average with Rain Record (SARR). The SARR uses rainfall data to justify each separation of the hydrograph. SARR has several advantages such as: it shows better consistency with the precipitation and discharge records, it is easier and more practical to implement, and it includes a method of event identification based on precipitation and quickflow response. SARR was derived from the United Kingdom Institute of Hydrology (UKIH) method with several key modifications to adapt it for small watersheds (<50 km2). We tested SARR on watersheds in the Choptank Basin on the Delmarva Peninsula (US Mid-Atlantic region) and compared the results with the UKIH method at the annual scale and the hydrochemical method at the individual event scale. Annually, SARR calculated a baseflow index that was ˜10% higher than the UKIH method due to the finer time step of SARR (1 d) compared to UKIH (5 d). At the watershed scale, hydric soils were an important driver of the annual baseflow index likely due to increased groundwater retention in hydric areas. At the event scale, SARR calculated less baseflow than the hydrochemical method, again because of the differences in time step (hourly for hydrochemical) and different definitions of baseflow. Both SARR and hydrochemical baseflow increased with event size, suggesting that baseflow contributions are more important during larger storms. To make SARR easy to implement, we have written a MatLab program to automate the calculations which requires only daily rainfall and daily flow data as inputs.

Comparison of swallowing outcomes of laryngotracheal separation versus total laryngectomy in a validated ovine model of profound oropharyngeal dysphagia.

PubMed

Venkatesan, N N; Johnson, C M; Siddiqui, M T; Cates, D J; Kuhn, M A; Postma, G N; Belafsky, P C

2017-04-01

To validate the ovine model of profound oropharyngeal dysphagia and compare swallowing outcomes of laryngotracheal separation with those of total laryngectomy. Under real-time fluoroscopy, swallowing trials were conducted using the head and neck of two Dorper cross ewes and one human cadaver, secured in lateral fluoroscopic orientation. Barium trials were administered at baseline, pre- and post-laryngohyoid suspension, following laryngotracheal separation, and following laryngectomy in the ovine model. Mean pre-intervention Penetration Aspiration Scale and National Institutes of Health Swallow Safety Scale scores were 8 ± 0 and 6 ± 0 respectively in sheep and human cadavers, with 100 per cent intra- and inter-species reproducibility. These scores improved to 1 ± 0 and 2 ± 0 post-laryngohyoid suspension (p < 0.01). Aerodigestive tract residue was 18.6 ± 2.4 ml at baseline, 15.4 ± 3.8 ml after laryngotracheal separation and 3.0 ± 0.7 ml after total laryngectomy (p < 0.001). The ovine model displayed perfect intra- and inter- species reliability for the Penetration Aspiration Scale and Swallow Safety Scale. Less aerodigestive tract residue after narrow-field laryngectomy suggests that swallowing outcomes after total laryngectomy are superior to those after laryngotracheal separation.

Linear regulator design for stochastic systems by a multiple time scales method

NASA Technical Reports Server (NTRS)

Teneketzis, D.; Sandell, N. R., Jr.

1976-01-01

A hierarchically-structured, suboptimal controller for a linear stochastic system composed of fast and slow subsystems is considered. The controller is optimal in the limit as the separation of time scales of the subsystems becomes infinite. The methodology is illustrated by design of a controller to suppress the phugoid and short period modes of the longitudinal dynamics of the F-8 aircraft.

Optimal Control Modification Adaptive Law for Time-Scale Separated Systems

NASA Technical Reports Server (NTRS)

Nguyen, Nhan T.

2010-01-01

Recently a new optimal control modification has been introduced that can achieve robust adaptation with a large adaptive gain without incurring high-frequency oscillations as with the standard model-reference adaptive control. This modification is based on an optimal control formulation to minimize the L2 norm of the tracking error. The optimal control modification adaptive law results in a stable adaptation in the presence of a large adaptive gain. This study examines the optimal control modification adaptive law in the context of a system with a time scale separation resulting from a fast plant with a slow actuator. A singular perturbation analysis is performed to derive a modification to the adaptive law by transforming the original system into a reduced-order system in slow time. A model matching conditions in the transformed time coordinate results in an increase in the actuator command that effectively compensate for the slow actuator dynamics. Simulations demonstrate effectiveness of the method.

Optimal Control Modification for Time-Scale Separated Systems

NASA Technical Reports Server (NTRS)

Nguyen, Nhan T.

2012-01-01

Recently a new optimal control modification has been introduced that can achieve robust adaptation with a large adaptive gain without incurring high-frequency oscillations as with the standard model-reference adaptive control. This modification is based on an optimal control formulation to minimize the L2 norm of the tracking error. The optimal control modification adaptive law results in a stable adaptation in the presence of a large adaptive gain. This study examines the optimal control modification adaptive law in the context of a system with a time scale separation resulting from a fast plant with a slow actuator. A singular perturbation analysis is performed to derive a modification to the adaptive law by transforming the original system into a reduced-order system in slow time. A model matching conditions in the transformed time coordinate results in an increase in the actuator command that effectively compensate for the slow actuator dynamics. Simulations demonstrate effectiveness of the method.

Nanoparticle separation with a miniaturized asymmetrical flow field-flow fractionation cartridge

PubMed Central

Müller, David; Cattaneo, Stefano; Meier, Florian; Welz, Roland; de Mello, Andrew J.

2015-01-01

Asymmetrical Flow Field-Flow Fractionation (AF4) is a separation technique applicable to particles over a wide size range. Despite the many advantages of AF4, its adoption in routine particle analysis is somewhat limited by the large footprint of currently available separation cartridges, extended analysis times and significant solvent consumption. To address these issues, we describe the fabrication and characterization of miniaturized AF4 cartridges. Key features of the down-scaled platform include simplified cartridge and reagent handling, reduced analysis costs and higher throughput capacities. The separation performance of the miniaturized cartridge is assessed using certified gold and silver nanoparticle standards. Analysis of gold nanoparticle populations indicates shorter analysis times and increased sensitivity compared to conventional AF4 separation schemes. Moreover, nanoparticulate titanium dioxide populations exhibiting broad size distributions are analyzed in a rapid and efficient manner. Finally, the repeatability and reproducibility of the miniaturized platform are investigated with respect to analysis time and separation efficiency. PMID:26258119

Nanoparticle separation with a miniaturized asymmetrical flow field-flow fractionation cartridge

NASA Astrophysics Data System (ADS)

Müller, David; Cattaneo, Stefano; Meier, Florian; Welz, Roland; deMello, Andrew

2015-07-01

Asymmetrical Flow Field-Flow Fractionation (AF4) is a separation technique applicable to particles over a wide size range. Despite the many advantages of AF4, its adoption in routine particle analysis is somewhat limited by the large footprint of currently available separation cartridges, extended analysis times and significant solvent consumption. To address these issues, we describe the fabrication and characterization of miniaturized AF4 cartridges. Key features of the scale-down platform include simplified cartridge and reagent handling, reduced analysis costs and higher throughput capacities. The separation performance of the miniaturized cartridge is assessed using certified gold and silver nanoparticle standards. Analysis of gold nanoparticle populations indicates shorter analysis times and increased sensitivity compared to conventional AF4 separation schemes. Moreover, nanoparticulate titanium dioxide populations exhibiting broad size distributions are analyzed in a rapid and efficient manner. Finally, the repeatability and reproducibility of the miniaturized platform are investigated with respect to analysis time and separation efficiency.

Separation and imaging diffractions by a sparsity-promoting model and subspace trust-region algorithm

NASA Astrophysics Data System (ADS)

Yu, Caixia; Zhao, Jingtao; Wang, Yanfei; Wang, Chengxiang; Geng, Weifeng

2017-03-01

The small-scale geologic inhomogeneities or discontinuities, such as tiny faults, cavities or fractures, generally have spatial scales comparable to or even smaller than the seismic wavelength. Therefore, the seismic responses of these objects are coded in diffractions and an attempt to high-resolution imaging can be made if we can appropriately image them. As the amplitudes of reflections can be several orders of magnitude larger than those of diffractions, one of the key problems of diffraction imaging is to suppress reflections and at the same time to preserve diffractions. A sparsity-promoting method for separating diffractions in the common-offset domain is proposed that uses the Kirchhoff integral formula to enforce the sparsity of diffractions and the linear Radon transform to formulate reflections. A subspace trust-region algorithm that can provide globally convergent solutions is employed for solving this large-scale computation problem. The method not only allows for separation of diffractions in the case of interfering events but also ensures a high fidelity of the separated diffractions. Numerical experiment and field application demonstrate the good performance of the proposed method in imaging the small-scale geological features related to the migration channel and storage spaces of carbonate reservoirs.

Entanglement renormalization, quantum error correction, and bulk causality

NASA Astrophysics Data System (ADS)

Kim, Isaac H.; Kastoryano, Michael J.

2017-04-01

Entanglement renormalization can be viewed as an encoding circuit for a family of approximate quantum error correcting codes. The logical information becomes progres-sively more well-protected against erasure errors at larger length scales. In particular, an approximate variant of holographic quantum error correcting code emerges at low energy for critical systems. This implies that two operators that are largely separated in scales behave as if they are spatially separated operators, in the sense that they obey a Lieb-Robinson type locality bound under a time evolution generated by a local Hamiltonian.

Scaling behavior of nonisothermal phase separation.

PubMed

Rüllmann, Max; Alig, Ingo

2004-04-22

The phase separation process in a critical mixture of polydimethylsiloxane and polyethylmethylsiloxane (PDMS/PEMS, a system with an upper critical solution temperature) was investigated by time-resolved light scattering during continuous quenches from the one-phase into the two-phase region. Continuous quenches were realized by cooling ramps with different cooling rates kappa. Phase separation kinetics is studied by means of the temporal evolution of the scattering vector qm and the intensity Im at the scattering peak. The curves qm(t) for different cooling rates can be shifted onto a single mastercurve. The curves Im(t) show similar behavior. As shift factors, a characteristic length Lc and a characteristic time tc are introduced. Both characteristic quantities depend on the cooling rate through power laws: Lc approximately kappa(-delta) and tc approximately kappa(-rho). Scaling behavior in isothermal critical demixing is well known. There the temporal evolutions of qm and Im for different quench depths DeltaT can be scaled with the correlation length xi and the interdiffusion coefficient D, both depending on DeltaT through critical power laws. We show in this paper that the cooling rate scaling in nonisothermal demixing is a consequence of the quench depth scaling in the isothermal case. The exponents delta and rho are related to the critical exponents nu and nu* of xi and D, respectively. The structure growth during nonisothermal demixing can be described with a semiempirical model based on the hydrodynamic coarsening mechanism well known in the isothermal case. In very late stages of nonisothermal phase separation a secondary scattering maximum appears. This is due to secondary demixing. We explain the onset of secondary demixing by a competition between interdiffusion and coarsening. (c) 2004 American Institute of Physics

Sample-independent approach to normalize two-dimensional data for orthogonality evaluation using whole separation space scaling.

PubMed

Jáčová, Jaroslava; Gardlo, Alžběta; Friedecký, David; Adam, Tomáš; Dimandja, Jean-Marie D

2017-08-18

Orthogonality is a key parameter that is used to evaluate the separation power of chromatography-based two-dimensional systems. It is necessary to scale the separation data before the assessment of the orthogonality. Current scaling approaches are sample-dependent, and the extent of the retention space that is converted into a normalized retention space is set according to the retention times of the first and last analytes contained in a unique sample to elute. The presence or absence of a highly retained analyte in a sample can thus significantly influence the amount of information (in terms of the total amount of separation space) contained in the normalized retention space considered for the calculation of the orthogonality. We propose a Whole Separation Space Scaling (WOSEL) approach that accounts for the whole separation space delineated by the analytical method, and not the sample. This approach enables an orthogonality-based evaluation of the efficiency of the analytical system that is independent of the sample selected. The WOSEL method was compared to two currently used orthogonality approaches through the evaluation of in silico-generated chromatograms and real separations of human biofluids and petroleum samples. WOSEL exhibits sample-to-sample stability values of 3.8% on real samples, compared to 7.0% and 10.1% for the two other methods, respectively. Using real analyses, we also demonstrate that some previously developed approaches can provide misleading conclusions on the overall orthogonality of a two-dimensional chromatographic system. Copyright © 2017 Elsevier B.V. All rights reserved.

Understanding the free energy barrier and multiple timescale dynamics of charge separation in organic photovoltaic cells.

PubMed

Yan, Yaming; Song, Linze; Shi, Qiang

2018-02-28

By employing several lattice model systems, we investigate the free energy barrier and real-time dynamics of charge separation in organic photovoltaic (OPV) cells. It is found that the combined effects of the external electric field, entropy, and charge delocalization reduce the free energy barrier significantly. The dynamic disorder reduces charge carrier delocalization and results in the increased charge separation barrier, while the effect of static disorder is more complicated. Simulation of the real-time dynamics indicates that the free charge generation process involves multiple time scales, including an ultrafast component within hundreds of femtoseconds, an intermediate component related to the relaxation of the hot charge transfer (CT) state, and a slow component on the time scale of tens of picoseconds from the thermally equilibrated CT state. Effects of hot exciton dissociation as well as its dependence on the energy offset between the Frenkel exciton and the CT state are also analyzed. The current results indicate that only a small energy offset between the band gap and the lowest energy CT state is needed to achieve efficient free charge generation in OPV devices, which agrees with recent experimental findings.

Understanding the free energy barrier and multiple timescale dynamics of charge separation in organic photovoltaic cells

NASA Astrophysics Data System (ADS)

Yan, Yaming; Song, Linze; Shi, Qiang

2018-02-01

By employing several lattice model systems, we investigate the free energy barrier and real-time dynamics of charge separation in organic photovoltaic (OPV) cells. It is found that the combined effects of the external electric field, entropy, and charge delocalization reduce the free energy barrier significantly. The dynamic disorder reduces charge carrier delocalization and results in the increased charge separation barrier, while the effect of static disorder is more complicated. Simulation of the real-time dynamics indicates that the free charge generation process involves multiple time scales, including an ultrafast component within hundreds of femtoseconds, an intermediate component related to the relaxation of the hot charge transfer (CT) state, and a slow component on the time scale of tens of picoseconds from the thermally equilibrated CT state. Effects of hot exciton dissociation as well as its dependence on the energy offset between the Frenkel exciton and the CT state are also analyzed. The current results indicate that only a small energy offset between the band gap and the lowest energy CT state is needed to achieve efficient free charge generation in OPV devices, which agrees with recent experimental findings.

Perceived Health Outcomes of Recreation Scale (PHORS): Reliability, Validity and Invariance

ERIC Educational Resources Information Center

Gómez, Edwin; Hill, Eddie; Zhu, Xihe; Freidt, Barbara

2016-01-01

This study examined the psychometric properties of the Perceived Health Outcomes of Recreation Scale (PHORS). Data for PHORS were collected from three different trail sites (Appalachian Trail, Pacific Crest Trail, and First Landing State Park) during three separate time periods, allowing for cross-validation and invariance testing. Exploratory…

Participation in International Large-Scale Assessments from a US Perspective

ERIC Educational Resources Information Center

Plisko, Valena White

2013-01-01

International large-scale assessments (ILSAs) play a distinct role in the United States' decentralized federal education system. Separate from national and state assessments, they offer an external, objective measure for the United States to assess student performance comparatively with other countries and over time. The US engagement in ILSAs…

Fluid particles only separate exponentially in the dissipation range of turbulence after extremely long times

NASA Astrophysics Data System (ADS)

Dhariwal, Rohit; Bragg, Andrew D.

2018-03-01

In this paper, we consider how the statistical moments of the separation between two fluid particles grow with time when their separation lies in the dissipation range of turbulence. In this range, the fluid velocity field varies smoothly and the relative velocity of two fluid particles depends linearly upon their separation. While this may suggest that the rate at which fluid particles separate is exponential in time, this is not guaranteed because the strain rate governing their separation is a strongly fluctuating quantity in turbulence. Indeed, Afik and Steinberg [Nat. Commun. 8, 468 (2017), 10.1038/s41467-017-00389-8] argue that there is no convincing evidence that the moments of the separation between fluid particles grow exponentially with time in the dissipation range of turbulence. Motivated by this, we use direct numerical simulations (DNS) to compute the moments of particle separation over very long periods of time in a statistically stationary, isotropic turbulent flow to see if we ever observe evidence for exponential separation. Our results show that if the initial separation between the particles is infinitesimal, the moments of the particle separation first grow as power laws in time, but we then observe convincing evidence that at sufficiently long times the moments do grow exponentially. However, this exponential growth is only observed after extremely long times ≳200 τη , where τη is the Kolmogorov time scale. This is due to fluctuations in the strain rate about its mean value measured along the particle trajectories, the effect of which on the moments of the particle separation persists for very long times. We also consider the backward-in-time (BIT) moments of the article separation, and observe that they too grow exponentially in the long-time regime. However, a dramatic consequence of the exponential separation is that at long times the difference between the rate of the particle separation forward in time (FIT) and BIT grows exponentially in time, leading to incredibly strong irreversibility in the dispersion. This is in striking contrast to the irreversibility of their relative dispersion in the inertial range, where the difference between FIT and BIT is constant in time according to Richardson's phenomenology.

Variability of interconnected wind plants: correlation length and its dependence on variability time scale

DOE PAGES

St. Martin, Clara M.; Lundquist, Julie K.; Handschy, Mark A.

2015-04-02

The variability in wind-generated electricity complicates the integration of this electricity into the electrical grid. This challenge steepens as the percentage of renewably-generated electricity on the grid grows, but variability can be reduced by exploiting geographic diversity: correlations between wind farms decrease as the separation between wind farms increases. However, how far is far enough to reduce variability? Grid management requires balancing production on various timescales, and so consideration of correlations reflective of those timescales can guide the appropriate spatial scales of geographic diversity grid integration. To answer 'how far is far enough,' we investigate the universal behavior of geographic diversity by exploring wind-speed correlations using three extensive datasets spanning continents, durations and time resolution. First, one year of five-minute wind power generation data from 29 wind farms span 1270 km across Southeastern Australia (Australian Energy Market Operator). Second, 45 years of hourly 10 m wind-speeds from 117 stations span 5000 km across Canada (National Climate Data Archive of Environment Canada). Finally, four years of five-minute wind-speeds from 14 meteorological towers span 350 km of the Northwestern US (Bonneville Power Administration). After removing diurnal cycles and seasonal trends from all datasets, we investigate dependence of correlation length on time scale by digitally high-pass filtering the data on 0.25–2000 h timescales and calculating correlations between sites for each high-pass filter cut-off. Correlations fall to zero with increasing station separation distance, but the characteristic correlation length varies with the high-pass filter applied: the higher the cut-off frequency, the smaller the station separation required to achieve de-correlation. Remarkable similarities between these three datasets reveal behavior that, if universal, could be particularly useful for grid management. For high-pass filter time constants shorter than about τ = 38 h, all datasets exhibit a correlation lengthmore » $$\\xi $$ that falls at least as fast as $${{\\tau }^{-1}}$$ . Since the inter-site separation needed for statistical independence falls for shorter time scales, higher-rate fluctuations can be effectively smoothed by aggregating wind plants over areas smaller than otherwise estimated.« less

Variability of interconnected wind plants: correlation length and its dependence on variability time scale

NASA Astrophysics Data System (ADS)

St. Martin, Clara M.; Lundquist, Julie K.; Handschy, Mark A.

2015-04-01

The variability in wind-generated electricity complicates the integration of this electricity into the electrical grid. This challenge steepens as the percentage of renewably-generated electricity on the grid grows, but variability can be reduced by exploiting geographic diversity: correlations between wind farms decrease as the separation between wind farms increases. But how far is far enough to reduce variability? Grid management requires balancing production on various timescales, and so consideration of correlations reflective of those timescales can guide the appropriate spatial scales of geographic diversity grid integration. To answer ‘how far is far enough,’ we investigate the universal behavior of geographic diversity by exploring wind-speed correlations using three extensive datasets spanning continents, durations and time resolution. First, one year of five-minute wind power generation data from 29 wind farms span 1270 km across Southeastern Australia (Australian Energy Market Operator). Second, 45 years of hourly 10 m wind-speeds from 117 stations span 5000 km across Canada (National Climate Data Archive of Environment Canada). Finally, four years of five-minute wind-speeds from 14 meteorological towers span 350 km of the Northwestern US (Bonneville Power Administration). After removing diurnal cycles and seasonal trends from all datasets, we investigate dependence of correlation length on time scale by digitally high-pass filtering the data on 0.25-2000 h timescales and calculating correlations between sites for each high-pass filter cut-off. Correlations fall to zero with increasing station separation distance, but the characteristic correlation length varies with the high-pass filter applied: the higher the cut-off frequency, the smaller the station separation required to achieve de-correlation. Remarkable similarities between these three datasets reveal behavior that, if universal, could be particularly useful for grid management. For high-pass filter time constants shorter than about τ = 38 h, all datasets exhibit a correlation length ξ that falls at least as fast as {{τ }-1} . Since the inter-site separation needed for statistical independence falls for shorter time scales, higher-rate fluctuations can be effectively smoothed by aggregating wind plants over areas smaller than otherwise estimated.

Ultrafast charge separation dynamics in opaque, operational dye-sensitized solar cells revealed by femtosecond diffuse reflectance spectroscopy

PubMed Central

Ghadiri, Elham; Zakeeruddin, Shaik M.; Hagfeldt, Anders; Grätzel, Michael; Moser, Jacques-E.

2016-01-01

Efficient dye-sensitized solar cells are based on highly diffusive mesoscopic layers that render these devices opaque and unsuitable for ultrafast transient absorption spectroscopy measurements in transmission mode. We developed a novel sub-200 femtosecond time-resolved diffuse reflectance spectroscopy scheme combined with potentiostatic control to study various solar cells in fully operational condition. We studied performance optimized devices based on liquid redox electrolytes and opaque TiO2 films, as well as other morphologies, such as TiO2 fibers and nanotubes. Charge injection from the Z907 dye in all TiO2 morphologies was observed to take place in the sub-200 fs time scale. The kinetics of electron-hole back recombination has features in the picosecond to nanosecond time scale. This observation is significantly different from what was reported in the literature where the electron-hole back recombination for transparent films of small particles is generally accepted to occur on a longer time scale of microseconds. The kinetics of the ultrafast electron injection remained unchanged for voltages between +500 mV and –690 mV, where the injection yield eventually drops steeply. The primary charge separation in Y123 organic dye based devices was clearly slower occurring in two picoseconds and no kinetic component on the shorter femtosecond time scale was recorded. PMID:27095505

Incorporation of memory effects in coarse-grained modeling via the Mori-Zwanzig formalism

DOE Office of Scientific and Technical Information (OSTI.GOV)

Li, Zhen; Bian, Xin; Karniadakis, George Em, E-mail: george-karniadakis@brown.edu

2015-12-28

The Mori-Zwanzig formalism for coarse-graining a complex dynamical system typically introduces memory effects. The Markovian assumption of delta-correlated fluctuating forces is often employed to simplify the formulation of coarse-grained (CG) models and numerical implementations. However, when the time scales of a system are not clearly separated, the memory effects become strong and the Markovian assumption becomes inaccurate. To this end, we incorporate memory effects into CG modeling by preserving non-Markovian interactions between CG variables, and the memory kernel is evaluated directly from microscopic dynamics. For a specific example, molecular dynamics (MD) simulations of star polymer melts are performed while themore » corresponding CG system is defined by grouping many bonded atoms into single clusters. Then, the effective interactions between CG clusters as well as the memory kernel are obtained from the MD simulations. The constructed CG force field with a memory kernel leads to a non-Markovian dissipative particle dynamics (NM-DPD). Quantitative comparisons between the CG models with Markovian and non-Markovian approximations indicate that including the memory effects using NM-DPD yields similar results as the Markovian-based DPD if the system has clear time scale separation. However, for systems with small separation of time scales, NM-DPD can reproduce correct short-time properties that are related to how the system responds to high-frequency disturbances, which cannot be captured by the Markovian-based DPD model.« less

Disentangling Global Warming, Multidecadal Variability, and El Niño in Pacific Temperatures

NASA Astrophysics Data System (ADS)

Wills, Robert C.; Schneider, Tapio; Wallace, John M.; Battisti, David S.; Hartmann, Dennis L.

2018-03-01

A key challenge in climate science is to separate observed temperature changes into components due to internal variability and responses to external forcing. Extended integrations of forced and unforced climate models are often used for this purpose. Here we demonstrate a novel method to separate modes of internal variability from global warming based on differences in time scale and spatial pattern, without relying on climate models. We identify uncorrelated components of Pacific sea surface temperature variability due to global warming, the Pacific Decadal Oscillation (PDO), and the El Niño-Southern Oscillation (ENSO). Our results give statistical representations of PDO and ENSO that are consistent with their being separate processes, operating on different time scales, but are otherwise consistent with canonical definitions. We isolate the multidecadal variability of the PDO and find that it is confined to midlatitudes; tropical sea surface temperatures and their teleconnections mix in higher-frequency variability. This implies that midlatitude PDO anomalies are more persistent than previously thought.

Photoluminescence decay dynamics in γ-Ga2O3 nanocrystals: The role of exclusion distance at short time scales

NASA Astrophysics Data System (ADS)

Fernandes, Brian; Hegde, Manu; Stanish, Paul C.; Mišković, Zoran L.; Radovanovic, Pavle V.

2017-09-01

We developed a comprehensive theoretical model describing the photoluminescence decay dynamics at short and long time scales based on the donor-acceptor defect interactions in γ-Ga2O3 nanocrystals, and quantitatively determined the importance of exclusion distance and spatial distribution of defects. We allowed for donors and acceptors to be adjacent to each other or separated by different exclusion distances. The optimal exclusion distance was found to be comparable to the donor Bohr radius and have a strong effect on the photoluminescence decay curve at short times. The importance of the exclusion distance at short time scales was confirmed by Monte Carlo simulations.

A new time scale based k-epsilon model for near wall turbulence

NASA Technical Reports Server (NTRS)

Yang, Z.; Shih, T. H.

1992-01-01

A k-epsilon model is proposed for wall bonded turbulent flows. In this model, the eddy viscosity is characterized by a turbulent velocity scale and a turbulent time scale. The time scale is bounded from below by the Kolmogorov time scale. The dissipation equation is reformulated using this time scale and no singularity exists at the wall. The damping function used in the eddy viscosity is chosen to be a function of R(sub y) = (k(sup 1/2)y)/v instead of y(+). Hence, the model could be used for flows with separation. The model constants used are the same as in the high Reynolds number standard k-epsilon model. Thus, the proposed model will be also suitable for flows far from the wall. Turbulent channel flows at different Reynolds numbers and turbulent boundary layer flows with and without pressure gradient are calculated. Results show that the model predictions are in good agreement with direct numerical simulation and experimental data.

New time scale based k-epsilon model for near-wall turbulence

NASA Technical Reports Server (NTRS)

Yang, Z.; Shih, T. H.

1993-01-01

A k-epsilon model is proposed for wall bonded turbulent flows. In this model, the eddy viscosity is characterized by a turbulent velocity scale and a turbulent time scale. The time scale is bounded from below by the Kolmogorov time scale. The dissipation equation is reformulated using this time scale and no singularity exists at the wall. The damping function used in the eddy viscosity is chosen to be a function of R(sub y) = (k(sup 1/2)y)/v instead of y(+). Hence, the model could be used for flows with separation. The model constants used are the same as in the high Reynolds number standard k-epsilon model. Thus, the proposed model will be also suitable for flows far from the wall. Turbulent channel flows at different Reynolds numbers and turbulent boundary layer flows with and without pressure gradient are calculated. Results show that the model predictions are in good agreement with direct numerical simulation and experimental data.

Contrasting scaling properties of interglacial and glacial climates

PubMed Central

Shao, Zhi-Gang; Ditlevsen, Peter D.

2016-01-01

Understanding natural climate variability is essential for assessments of climate change. This is reflected in the scaling properties of climate records. The scaling exponents of the interglacial and the glacial climates are fundamentally different. The Holocene record is monofractal, with a scaling exponent H∼0.7. On the contrary, the glacial record is multifractal, with a significantly higher scaling exponent H∼1.2, indicating a longer persistence time and stronger nonlinearities in the glacial climate. The glacial climate is dominated by the strong multi-millennial Dansgaard–Oeschger (DO) events influencing the long-time correlation. However, by separately analysing the last glacial maximum lacking DO events, here we find the same scaling for that period as for the full glacial period. The unbroken scaling thus indicates that the DO events are part of the natural variability and not externally triggered. At glacial time scales, there is a scale break to a trivial scaling, contrasting the DO events from the similarly saw-tooth-shaped glacial cycles. PMID:26980084

Design and Processing of Electret Structures

DTIC Science & Technology

2009-10-31

and width as a function of time. ( d ) Estimated current density j of dissolving copper disk as a function of time. (e) Total current I of dissolving...effect leading to a higher corrosion rate in the galvanic microreactor . Because of the small scale of our galvanic system, the dissolving copper disk is...estimated by focusing with a calibrated microscope stage.   Figure 5: Particle separation and electrolyte convection. Scale bars in ( A , D ) are 100 µm

Detection of crossover time scales in multifractal detrended fluctuation analysis

NASA Astrophysics Data System (ADS)

Ge, Erjia; Leung, Yee

2013-04-01

Fractal is employed in this paper as a scale-based method for the identification of the scaling behavior of time series. Many spatial and temporal processes exhibiting complex multi(mono)-scaling behaviors are fractals. One of the important concepts in fractals is crossover time scale(s) that separates distinct regimes having different fractal scaling behaviors. A common method is multifractal detrended fluctuation analysis (MF-DFA). The detection of crossover time scale(s) is, however, relatively subjective since it has been made without rigorous statistical procedures and has generally been determined by eye balling or subjective observation. Crossover time scales such determined may be spurious and problematic. It may not reflect the genuine underlying scaling behavior of a time series. The purpose of this paper is to propose a statistical procedure to model complex fractal scaling behaviors and reliably identify the crossover time scales under MF-DFA. The scaling-identification regression model, grounded on a solid statistical foundation, is first proposed to describe multi-scaling behaviors of fractals. Through the regression analysis and statistical inference, we can (1) identify the crossover time scales that cannot be detected by eye-balling observation, (2) determine the number and locations of the genuine crossover time scales, (3) give confidence intervals for the crossover time scales, and (4) establish the statistically significant regression model depicting the underlying scaling behavior of a time series. To substantive our argument, the regression model is applied to analyze the multi-scaling behaviors of avian-influenza outbreaks, water consumption, daily mean temperature, and rainfall of Hong Kong. Through the proposed model, we can have a deeper understanding of fractals in general and a statistical approach to identify multi-scaling behavior under MF-DFA in particular.

Full-Scale Numerical Modeling of Turbulent Processes in the Earth's Ionosphere

DOE Office of Scientific and Technical Information (OSTI.GOV)

Eliasson, B.; Stenflo, L.; Department of Physics, Linkoeping University, SE-581 83 Linkoeping

2008-10-15

We present a full-scale simulation study of ionospheric turbulence by means of a generalized Zakharov model based on the separation of variables into high-frequency and slow time scales. The model includes realistic length scales of the ionospheric profile and of the electromagnetic and electrostatic fields, and uses ionospheric plasma parameters relevant for high-latitude radio facilities such as Eiscat and HAARP. A nested grid numerical method has been developed to resolve the different length-scales, while avoiding severe restrictions on the time step. The simulation demonstrates the parametric decay of the ordinary mode into Langmuir and ion-acoustic waves, followed by a Langmuirmore » wave collapse and short-scale caviton formation, as observed in ionospheric heating experiments.« less

Partitioning evapotranspiration using long-term carbon dioxide and water vapor fluxes: New approach to ET partitioning

USDA-ARS?s Scientific Manuscript database

The separate components of evapotranspiration (ET) provide critical information about the pathways and time scales over which water is returned to the atmosphere, but ecosystem-scale measurements of transpiration (T) and evaporation (E) remain elusive. We propose a novel determination of average E a...

Ares I Stage Separation System Design Certification Testing

NASA Technical Reports Server (NTRS)

Mayers, Stephen L.; Beard, Bernard B.; Smith, R. Kenneth; Patterson, Alan

2009-01-01

NASA is committed to the development of a new crew launch vehicle, the Ares I, that can support human missions to low Earth orbit (LEO) and the moon with unprecedented safety and reliability. NASA's Constellation program comprises the Ares I and Ares V launch vehicles, the Orion crew vehicle, and the Altair lunar lander. Based on historical precedent, stage separation is one of the most significant technical and systems engineering challenges that must be addressed in order to achieve this commitment. This paper surveys historical separation system tests that have been completed in order to ensure staging of other launch vehicles. Key separation system design trades evaluated for Ares I include single vs. dual separation plane options, retro-rockets vs. pneumatic gas actuators, small solid motor quantity/placement/timing, and continuous vs. clamshell interstage configuration options. Both subscale and full-scale tests are required to address the prediction of complex dynamic loading scenarios present during staging events. Test objectives such as separation system functionality, and pyroshock and debris field measurements for the full-scale tests are described. Discussion about the test article, support infrastructure and instrumentation are provided.

Titius-Bode laws in the solar system. 2: Build your own law from disk models

NASA Astrophysics Data System (ADS)

Dubrulle, B.; Graner, F.

1994-02-01

Simply respecting both scale and rotational invariance, it is easy to construct an endless collection of theoretical models predicting a Titius-Bode law, irrespective to their physical content. Due to the numerous ways to get the law and its intrinsic arbitrariness, it is not a useful constraint on theories of solar system formation. To illustrate the simple elegance of scale-invariant methods, we explicitly cook up one of the simplest examples, an infinitely thin cold gaseous disk rotating around a central object. In that academic case, the Titius-Bode law holds during the linear stage of the gravitational instability. The time scale of the instability is of the order of a self-gravitating time scale, (G rhod)-1/2, where rhod is the disk density. This model links the separation between different density maxima with the ratio MD/MC of the masses of the disk and the central object; for instance, MD/MC of the order of 0.18 roughly leads to the observed separation between the planets. We discuss the boundary conditions and the limit of the Wentzel-Kramer-Brillouin (WKB) approximation.

Flow-induced separation in wall turbulence.

PubMed

Nguyen, Quoc; Srinivasan, Chiranth; Papavassiliou, Dimitrios V

2015-03-01

One of the defining characteristics of turbulence is its ability to promote mixing. We present here a case where the opposite happens-simulation results indicate that particles can separate near the wall of a turbulent channel flow, when they have sufficiently different Schmidt numbers without use of any other means. The physical mechanism of the separation is understood when the interplay between convection and diffusion, as expressed by their characteristic time scales, is considered, leading to the determination of the necessary conditions for a successful separation between particles. Practical applications of these results can be found when very small particles need to be separated or removed from a fluid.

Schinus terebinthifolius scale-up countercurrent chromatography (Part I): High performance countercurrent chromatography fractionation of triterpene acids with off-line detection using atmospheric pressure chemical ionization mass spectrometry.

PubMed

Vieira, Mariana Neves; Costa, Fernanda das Neves; Leitão, Gilda Guimarães; Garrard, Ian; Hewitson, Peter; Ignatova, Svetlana; Winterhalter, Peter; Jerz, Gerold

2015-04-10

'Countercurrent chromatography' (CCC) is an ideal technique for the recovery, purification and isolation of bioactive natural products, due to the liquid nature of the stationary phase, process predictability and the possibility of scale-up from analytical to preparative scale. In this work, a method developed for the fractionation of Schinus terebinthifolius Raddi berries dichloromethane extract was thoroughly optimized to achieve maximal throughput with minimal solvent and time consumption per gram of processed crude extract, using analytical, semi-preparative and preparative 'high performance countercurrent chromatography' (HPCCC) instruments. The method using the biphasic solvent system composed of n-heptane-ethyl acetate-methanol-water (6:1:6:1, v/v/v/v) was volumetrically scaled up to increase sample throughput up to 120 times, while maintaining separation efficiency and time. As a fast and specific detection alternative, the fractions collected from the CCC-separations were injected to an 'atmospheric pressure chemical ionization mass-spectrometer' (APCI-MS/MS) and reconstituted molecular weight MS-chromatograms of the APCI-ionizable compounds from S. terebinthifolius were obtained. This procedure led to the direct isolation of tirucallane type triterpenes such as masticadienonic and 3β-masticadienolic acids. Also oleanonic and moronic acids have been identified for the first time in the species. In summary, this approach can be used for other CCC scale-up processes, enabling MS-target-guided isolation procedures. Copyright © 2015 Elsevier B.V. All rights reserved.

Laminar separation control effects of shortfin mako shark skin

NASA Astrophysics Data System (ADS)

Bradshaw, Michael Thomas

Shark skin is investigated as a means of laminar flow separation control due to its preferential flow direction as well as the potential for scales to erect and obstruct low-momentum backflow resulting from an adverse pressure gradient acting on the boundary layer. In this study, the effect of the scales on flow reversal is observed in laminar flow conditions. This is achieved by comparing the flow over a pectoral fin from a shortfin mako shark to that over the same fin that is painted to neutralize the effect of the scales on the flow. The effect of the scales on flow reversal is also observed by comparing the flow over a smooth PVC cylinder to that over the same cylinder with samples of mako shark skin affixed to the entire circumference of the cylinder. These samples were taken from the flank region of the shark because the scales at this location have been shown to have the greatest angle of erection compared to the scales on the rest of the shark's body. Scales at this location have an average crown length of 220 microm with a maximum bristling angle of proximately 50 degrees. Because these scales have the highest bristling angle, they have the best potential for separation control. All data was taken using time-resolved Digital Particle Image Velocimetry. The flow over the pectoral fin was analyzed at multiple angles of attack. It was found that the shark skin had the effect of decreasing the size of the separated region over both the pectoral fin and the cylinder as well as decreasing the magnitudes of the reversing flow found in these regions. For all Reynolds numbers tested, drag reduction over 28% was found when applying the sharkskin to the cylinder.

Low-Frequency Flow Oscillations on Stalled Wings Exhibiting Cellular Separation Topology

NASA Astrophysics Data System (ADS)

Disotell, Kevin James

One of the most pervasive threats to aircraft controllability is wing stall, a condition associated with loss of lift due to separation of air flow from the wing surface at high angles of attack. A recognized need for improved upset recovery training in extended-envelope flight simulators is a physical understanding of the post-stall aerodynamic environment, particularly key flow phenomena which influence the vehicle trajectory. Large-scale flow structures known as stall cells, which scale with the wing chord and are spatially-periodic along the span, have been previously observed on post-stall airfoils with trailing-edge separation present. Despite extensive documentation of stall cells in the literature, the physical mechanisms behind their formation and evolution have proven to be elusive. The undertaken study has sought to characterize the inherently turbulent separated flow existing above the wing surface with cell formation present. In particular, the question of how the unsteady separated flow may interact with the wing to produce time-averaged cellular surface patterns is considered. Time-resolved, two-component particle image velocimetry measurements were acquired at the plane of symmetry of a single stall cell formed on an extruded NACA 0015 airfoil model at chord Reynolds number of 560,000 to obtain insight into the time-dependent flow structure. The evolution of flow unsteadiness was analyzed over a static angle-of-attack range covering the narrow post-stall regime in which stall cells have been observed. Spectral analysis of velocity fields acquired near the stall angle confirmed a low-frequency flow oscillation previously detected in pointwise surface measurements by Yon and Katz (1998), corresponding to a Strouhal number of 0.042 based on frontal projected chord height. Probability density functions of the streamwise velocity component were used to estimate the convective speed of this mode at approximately half the free-stream velocity, in agreement with Yon and Katz. Large-amplitude streamwise Reynolds stresses in the separated shear layer were found to be manifested by the low-frequency oscillation through inspection of the spectral energy distribution. Using the method of Proper Orthogonal Decomposition to construct reduced-order models of the acquired time sequences, the low-frequency unsteadiness appeared to be linked to an interaction between the separated and trailing-edge shear layers, in contrast to a bubble-bursting mechanism which has been observed for different stall behaviors. As the static angle of attack was increased further, the separated flow structure was seen to transition to a faster eddy motion expected for bluff-body wakes. A novel scaling study was conducted to evaluate the potential role of low-frequency unsteadiness in producing the spanwise wavelengths associated with cell formation, which was found to be in favorable agreement with scaling trends in the literature. Finally, instantaneous pressure-sensitive paint measurements were demonstrated on a DU 97-W-300 wind turbine airfoil at chord Reynolds number of 225,000 with leading-edge trip applied, in which the development of spiral node structures associated with cell formation were captured in the trailing-edge separation. The contributed work suggests that further study into the influence of large-scale unsteadiness on the three-dimensional organization of stall cells is merited.

Polymer Dispersed Liquid Crystal Displays

NASA Astrophysics Data System (ADS)

Doane, J. William

The following sections are included: * INTRODUCTION AND HISTORICAL DEVELOPMENT * PDLC MATERIALS PREPARATION * Polymerization induced phase separation (PIPS) * Thermally induced phase separation (TIPS) * Solvent induced phase separation (SIPS) * Encapsulation (NCAP) * RESPONSE VOLTAGE * Dielectric and resistive effects * Radial configuration * Bipolar configuration * Other director configurations * RESPONSE TIME * DISPLAY CONTRAST * Light scattering and index matching * Incorporation of dyes * Contrast measurements * PDLC DISPLAY DEVICES AND INNOVATIONS * Reflective direct view displays * Large-scale, flexible displays * Switchable windows * Projection displays * High definition spatial light modulator * Haze-free PDLC shutters: wide angle view displays * ENVIRONMENTAL STABILITY * ACKNOWLEDGEMENTS * REFERENCES

An Eulerian time filtering technique to study large-scale transient flow phenomena

NASA Astrophysics Data System (ADS)

Vanierschot, Maarten; Persoons, Tim; van den Bulck, Eric

2009-10-01

Unsteady fluctuating velocity fields can contain large-scale periodic motions with frequencies well separated from those of turbulence. Examples are the wake behind a cylinder or the processing vortex core in a swirling jet. These turbulent flow fields contain large-scale, low-frequency oscillations, which are obscured by turbulence, making it impossible to identify them. In this paper, we present an Eulerian time filtering (ETF) technique to extract the large-scale motions from unsteady statistical non-stationary velocity fields or flow fields with multiple phenomena that have sufficiently separated spectral content. The ETF method is based on non-causal time filtering of the velocity records in each point of the flow field. It is shown that the ETF technique gives good results, similar to the ones obtained by the phase-averaging method. In this paper, not only the influence of the temporal filter is checked, but also parameters such as the cut-off frequency and sampling frequency of the data are investigated. The technique is validated on a selected set of time-resolved stereoscopic particle image velocimetry measurements such as the initial region of an annular jet and the transition between flow patterns in an annular jet. The major advantage of the ETF method in the extraction of large scales is that it is computationally less expensive and it requires less measurement time compared to other extraction methods. Therefore, the technique is suitable in the startup phase of an experiment or in a measurement campaign where several experiments are needed such as parametric studies.

Background-Source Cosmic-Photon Elevation Scaling and Cosmic-Neutron/Photon Date Scaling in MCNP6

DOE PAGES

Tutt, James Robert; Anderson, Casey Alan; McKinney, Gregg Walter

2017-10-26

Here, cosmic neutron and photon fluxes are known to scale exponentially with elevation. Consequently, cosmic neutron elevation scaling was implemented for use with the background-source option shortly after its introduction into MCNP6, whereby the neutron flux weight factor was adjusted by the elevation scaling factor when the user-specified elevation differed from the selected background.dat grid-point elevation. At the same time, an elevation scaling factor was suggested for the cosmic photon flux, however, cosmic photon elevation scaling is complicated by the fact that the photon background consists of two components: cosmic and terrestrial. Previous versions of the background.dat file did notmore » provide any way to separate these components. With Rel. 4 of this file in 2015, two new columns were added that provide the energy grid and differential cosmic photon flux separately from the total photon flux. Here we show that the cosmic photon flux component can now be scaled independently and combined with the terrestrial component to form the total photon flux at a user-specified elevation in MCNP6.« less

Background-Source Cosmic-Photon Elevation Scaling and Cosmic-Neutron/Photon Date Scaling in MCNP6

DOE Office of Scientific and Technical Information (OSTI.GOV)

Tutt, James Robert; Anderson, Casey Alan; McKinney, Gregg Walter

Here, cosmic neutron and photon fluxes are known to scale exponentially with elevation. Consequently, cosmic neutron elevation scaling was implemented for use with the background-source option shortly after its introduction into MCNP6, whereby the neutron flux weight factor was adjusted by the elevation scaling factor when the user-specified elevation differed from the selected background.dat grid-point elevation. At the same time, an elevation scaling factor was suggested for the cosmic photon flux, however, cosmic photon elevation scaling is complicated by the fact that the photon background consists of two components: cosmic and terrestrial. Previous versions of the background.dat file did notmore » provide any way to separate these components. With Rel. 4 of this file in 2015, two new columns were added that provide the energy grid and differential cosmic photon flux separately from the total photon flux. Here we show that the cosmic photon flux component can now be scaled independently and combined with the terrestrial component to form the total photon flux at a user-specified elevation in MCNP6.« less

Chromatographic hydrogen isotope separation

DOEpatents

Aldridge, Frederick T.

1981-01-01

Intermetallic compounds with the CaCu.sub.5 type of crystal structure, particularly LaNiCo.sub.4 and CaNi.sub.5, exhibit high separation factors and fast equilibrium times and therefore are useful for packing a chromatographic hydrogen isotope separation colum. The addition of an inert metal to dilute the hydride improves performance of the column. A large scale mutli-stage chromatographic separation process run as a secondary process off a hydrogen feedstream from an industrial plant which uses large volumes of hydrogen can produce large quantities of heavy water at an effective cost for use in heavy water reactors.

Chromatographic hydrogen isotope separation

DOEpatents

Aldridge, F.T.

Intermetallic compounds with the CaCu/sub 5/ type of crystal structure, particularly LaNiCo/sub 4/ and CaNi/sub 5/, exhibit high separation factors and fast equilibrium times and therefore are useful for packing a chromatographic hydrogen isotope separation column. The addition of an inert metal to dilute the hydride improves performance of the column. A large scale multi-stage chromatographic separation process run as a secondary process off a hydrogen feedstream from an industrial plant which uses large volumes of hydrogen cn produce large quantities of heavy water at an effective cost for use in heavy water reactors.

Superadiabatic driving of a three-level quantum system

NASA Astrophysics Data System (ADS)

Theisen, M.; Petiziol, F.; Carretta, S.; Santini, P.; Wimberger, S.

2017-07-01

We study superadiabatic quantum control of a three-level quantum system whose energy spectrum exhibits multiple avoided crossings. In particular, we investigate the possibility of treating the full control task in terms of independent two-level Landau-Zener problems. We first show that the time profiles of the elements of the full control Hamiltonian are characterized by peaks centered around the crossing times. These peaks decay algebraically for large times. In principle, such a power-law scaling invalidates the hypothesis of perfect separability. Nonetheless, we address the problem from a pragmatic point of view by studying the fidelity obtained through separate control as a function of the intercrossing separation. This procedure may be a good approach to achieve approximate adiabatic driving of a specific instantaneous eigenstate in realistic implementations.

Coarsening mechanism of phase separation caused by a double temperature quench in an off-symmetric binary mixture.

PubMed

Sigehuzi, Tomoo; Tanaka, Hajime

2004-11-01

We study phase-separation behavior of an off-symmetric fluid mixture induced by a "double temperature quench." We first quench a system into the unstable region. After a large phase-separated structure is formed, we again quench the system more deeply and follow the pattern-evolution process. The second quench makes the domains formed by the first quench unstable and leads to double phase separation; that is, small droplets are formed inside the large domains created by the first quench. The complex coarsening behavior of this hierarchic structure having two characteristic length scales is studied in detail by using the digital image analysis. We find three distinct time regimes in the time evolution of the structure factor of the system. In the first regime, small droplets coarsen with time inside large domains. There a large domain containing small droplets in it can be regarded as an isolated system. Later, however, the coarsening of small droplets stops when they start to interact via diffusion with the large domain containing them. Finally, small droplets disappear due to the Lifshitz-Slyozov mechanism. Thus the observed behavior can be explained by the crossover of the nature of a large domain from the isolated to the open system; this is a direct consequence of the existence of the two characteristic length scales.

Simultaneous separation by reversed-phase high-performance liquid chromatography and mass spectral identification of anthocyanins and flavonols in Shiraz grape skin.

PubMed

Downey, Mark O; Rochfort, Simone

2008-08-01

A limitation of large-scale viticultural trials is the time and cost of comprehensive compositional analysis of the fruit by high-performance liquid chromatography (HPLC). In addition, separate methods have generally been required to identify and quantify different classes of metabolites. To address these shortcomings a reversed-phase HPLC method was developed to simultaneously separate the anthocyanins and flavonols present in grape skins. The method employs a methanol and water gradient acidified with 10% formic acid with a run-time of 48 min including re-equilibration. Identity of anthocyanins and flavonols in Shiraz (Vitis vinifera L.) skin was confirmed by mass spectral analysis.

Two-particle diffusion and locality assumption

NASA Astrophysics Data System (ADS)

Nicolleau, F.; Yu, G.

2004-07-01

A three-dimensional kinematic simulation (KS) model is used to study one- and two-particle diffusion in turbulent flows. The energy spectrum E(k) takes a power law form E(k)˜k-p. The value of this power p is varied from 1.2 to 3, so that its effects on the diffusion of one and two particles can be studied. The two-particle diffusion behaves differently depending on whether the two-particle separation is larger or smaller than the smallest scale of turbulence (Kolmogorov length scale η). When the two-particle mean square separation <Δ2(t)> is smaller than η2 it experiences a time exponential growth <Δ2(t)>=Δ02eγ(t/tη) but for a very short time. For longer times, when η2<<Δ2(t)>. In this inertial range we observe that d/dt<Δ2(t)>={a ln(<Δ(t)2>1/2/η)+b}u'L(η/L)(p+1)/2(<Δ(t)2>1/2/η)(p+1)/2 for p⩽3. For Δ0/η≫1 a=0, but a≠0 for Δ0/η⩽1 and as a consequence the pair diffusion cannot have lost its dependence on the initial separation during the exponential growth, i.e., γ is a function of Δ0/η. Our modified Richardson law is compared with two other proposed modifications to Richardson's power law, namely the virtual time [G. K. Batchelor, Proc. Cambridge Philos. Soc. 48, 345 (1952)] and the correction factor [F. Nicolleau and J. C. Vassilicos, Phys. Rev. Lett. 90, 245003 (2003)]. Further investigations on two-particle diffusion when p=3 give an excellent agreement with the experimental results in P. Morel and M. Larchevêque, J. Atmos. Sci. 31 (1974) for atmospheric turbulent flows. Finally, using two different combined power law energy spectra in KS, the isotropic small scales are found to have no significant role when their largest scale lT is less than 10 times the Kolmogorov length scale η.

Multiscaling for systems with a broad continuum of characteristic lengths and times: Structural transitions in nanocomposites.

PubMed

Pankavich, S; Ortoleva, P

2010-06-01

The multiscale approach to N-body systems is generalized to address the broad continuum of long time and length scales associated with collective behaviors. A technique is developed based on the concept of an uncountable set of time variables and of order parameters (OPs) specifying major features of the system. We adopt this perspective as a natural extension of the commonly used discrete set of time scales and OPs which is practical when only a few, widely separated scales exist. The existence of a gap in the spectrum of time scales for such a system (under quasiequilibrium conditions) is used to introduce a continuous scaling and perform a multiscale analysis of the Liouville equation. A functional-differential Smoluchowski equation is derived for the stochastic dynamics of the continuum of Fourier component OPs. A continuum of spatially nonlocal Langevin equations for the OPs is also derived. The theory is demonstrated via the analysis of structural transitions in a composite material, as occurs for viral capsids and molecular circuits.

Two time scale output feedback regulation for ill-conditioned systems

NASA Technical Reports Server (NTRS)

Calise, A. J.; Moerder, D. D.

1986-01-01

Issues pertaining to the well-posedness of a two time scale approach to the output feedback regulator design problem are examined. An approximate quadratic performance index which reflects a two time scale decomposition of the system dynamics is developed. It is shown that, under mild assumptions, minimization of this cost leads to feedback gains providing a second-order approximation of optimal full system performance. A simplified approach to two time scale feedback design is also developed, in which gains are separately calculated to stabilize the slow and fast subsystem models. By exploiting the notion of combined control and observation spillover suppression, conditions are derived assuring that these gains will stabilize the full-order system. A sequential numerical algorithm is described which obtains output feedback gains minimizing a broad class of performance indices, including the standard LQ case. It is shown that the algorithm converges to a local minimum under nonrestrictive assumptions. This procedure is adapted to and demonstrated for the two time scale design formulations.

Electrical cream separator coupled with vacuum filtration for the purification of eimerian oocysts and trichostronglyid eggs

NASA Astrophysics Data System (ADS)

El-Ashram, Saeed; Suo, Xun

2017-02-01

Several methods have been proposed for separation of eimerian oocysts and trichostronglyid eggs from extraneous debris; however, these methods have been considered to be still inconvenient in terms of time and wide-ranging applications. We describe herein an alternative way using the combination of electrical cream separator and vacuum filtration for harvesting and purifying eimerian oocysts and haemonchine eggs on large-scale applications with approximately 81% and 92% recovery rates for oocysts and nematode eggs obtained from avian and ovine faeces, correspondingly. The sporulation percentages as a measure of viability in the harvested oocysts and eggs from dry faecal materials are nearly 68% and 74%, respectively, and 12 liters of faecal suspension can be processed in approximately 7.5 min. The mode of separation in terms of costs (i.e. simple laboratory equipments and comparably cheap reagents) and benefits renders the reported procedure an appropriate pursuit to harvest and purify parasite oocysts and eggs on a large scale in the shortest duration from diverse volumes of environmental samples compared to the modified traditional sucrose gradient, which can be employed on a small scale.

Electrical cream separator coupled with vacuum filtration for the purification of eimerian oocysts and trichostronglyid eggs

PubMed Central

El-Ashram, Saeed; Suo, Xun

2017-01-01

Several methods have been proposed for separation of eimerian oocysts and trichostronglyid eggs from extraneous debris; however, these methods have been considered to be still inconvenient in terms of time and wide-ranging applications. We describe herein an alternative way using the combination of electrical cream separator and vacuum filtration for harvesting and purifying eimerian oocysts and haemonchine eggs on large-scale applications with approximately 81% and 92% recovery rates for oocysts and nematode eggs obtained from avian and ovine faeces, correspondingly. The sporulation percentages as a measure of viability in the harvested oocysts and eggs from dry faecal materials are nearly 68% and 74%, respectively, and 12 liters of faecal suspension can be processed in approximately 7.5 min. The mode of separation in terms of costs (i.e. simple laboratory equipments and comparably cheap reagents) and benefits renders the reported procedure an appropriate pursuit to harvest and purify parasite oocysts and eggs on a large scale in the shortest duration from diverse volumes of environmental samples compared to the modified traditional sucrose gradient, which can be employed on a small scale. PMID:28233853

[A new scale for measuring return-to-work motivation of mentally ill employees].

PubMed

Poersch, M

2007-03-01

A new scale "motivation for return to work" has been constructed to measure depressive patients' motivation to start working again in a stepwise process. The scale showed in 46 patients of a first case management (CM) sample with depressive employees a good correlation with the final social status of the CM. Only the motivated patients were successful returning to work and could be, separated clearly from the most demotivated one. Second, the scale correlated with the duration of sick leave and third showed an inverse correlation with the complete time of CM, suggesting that a successful stepwise return to work requires time. These first results need further examination.

The CE way of thinking: "all is relative!".

PubMed

Schmitt-Kopplin, Philippe; Fekete, Agnes

2008-01-01

Over the last two decades, the development of capillary electrophoresis (CE) instruments has lead to systems with programmable samplers, separation columns, separation buffers, and detection devices comparable visually in many aspects to the setup of classical chromatography. Two characteristics make CE essentially different from chromatography and are the basis of the CE way of thinking: first is the injection type and the liquid flow within the capillary. When the injection is made hydrodynamically (such as in most of the applications found in the literature), the injected volumes are directly dependent on the type and size of the separation capillary. The second characteristic is that in CE, buffer velocity is not pressure-driven, as in liquid chromatography, but is electrokinetically governed by the quality of the capillary surface (separation buffer dependent surface charge) inducing an electroosmotic flow (EOF). The EOF undergoes small variations and is not necessarily identical from one separation or day to the other. The direct consequence is that the migration time of the analytes apparently nonreproducible, although the velocity of the ions is the same. The effective mobility (field strength normalized velocity) of the ions is a possible parameterization from acquired time-scale to effective mobility-scale electropherograms leading to a reproducible visualization and better quantification with a direct relation to structural characters of the analytes (i.e., charge and size; see Chapter 23).

Statistical mechanical approach to secondary processes and structural relaxation in glasses and glass formers: a leading model to describe the onset of Johari-Goldstein processes and their relationship with fully cooperative processes.

PubMed

Crisanti, A; Leuzzi, L; Paoluzzi, M

2011-09-01

The interrelation of dynamic processes active on separated time-scales in glasses and viscous liquids is investigated using a model displaying two time-scale bifurcations both between fast and secondary relaxation and between secondary and structural relaxation. The study of the dynamics allows for predictions on the system relaxation above the temperature of dynamic arrest in the mean-field approximation, that are compared with the outcomes of the equations of motion directly derived within the Mode Coupling Theory (MCT) for under-cooled viscous liquids. By varying the external thermodynamic parameters, a wide range of phenomenology can be represented, from a very clear separation of structural and secondary peak in the susceptibility loss to excess wing structures.

Contrasting scaling properties of interglacial and glacial climates

NASA Astrophysics Data System (ADS)

Ditlevsen, Peter; Shao, Zhi-Gang

2017-04-01

Understanding natural climate variability is essential for assessments of climate change. This is reflected in the scaling properties of climate records. The scaling exponents of the interglacial and the glacial climates are fundamentally different. The Holocene record is monofractal, with a scaling exponent H˜0.7. On the contrary, the glacial record is multifractal, with a significantly higher scaling exponent H˜1.2, indicating a longer persistence time and stronger nonlinearities in the glacial climate. The glacial climate is dominated by the strong multi-millennial Dansgaard-Oeschger (DO) events influencing the long-time correlation. However, by separately analysing the last glacial maximum lacking DO events, here we find the same scaling for that period as for the full glacial period. The unbroken scaling thus indicates that the DO events are part of the natural variability and not externally triggered. At glacial time scales, there is a scale break to a trivial scaling, contrasting the DO events from the similarly saw-tooth-shaped glacial cycles. Ref: Zhi-Gang Shao and Peter Ditlevsen, Nature Comm. 7, 10951, 2016

Effect of helicity on the correlation time of large scales in turbulent flows

NASA Astrophysics Data System (ADS)

Cameron, Alexandre; Alexakis, Alexandros; Brachet, Marc-Étienne

2017-11-01

Solutions of the forced Navier-Stokes equation have been conjectured to thermalize at scales larger than the forcing scale, similar to an absolute equilibrium obtained for the spectrally truncated Euler equation. Using direct numeric simulations of Taylor-Green flows and general-periodic helical flows, we present results on the probability density function, energy spectrum, autocorrelation function, and correlation time that compare the two systems. In the case of highly helical flows, we derive an analytic expression describing the correlation time for the absolute equilibrium of helical flows that is different from the E-1 /2k-1 scaling law of weakly helical flows. This model predicts a new helicity-based scaling law for the correlation time as τ (k ) ˜H-1 /2k-1 /2 . This scaling law is verified in simulations of the truncated Euler equation. In simulations of the Navier-Stokes equations the large-scale modes of forced Taylor-Green symmetric flows (with zero total helicity and large separation of scales) follow the same properties as absolute equilibrium including a τ (k ) ˜E-1 /2k-1 scaling for the correlation time. General-periodic helical flows also show similarities between the two systems; however, the largest scales of the forced flows deviate from the absolute equilibrium solutions.

Complex Processes from Dynamical Architectures with Time-Scale Hierarchy

PubMed Central

Perdikis, Dionysios; Huys, Raoul; Jirsa, Viktor

2011-01-01

The idea that complex motor, perceptual, and cognitive behaviors are composed of smaller units, which are somehow brought into a meaningful relation, permeates the biological and life sciences. However, no principled framework defining the constituent elementary processes has been developed to this date. Consequently, functional configurations (or architectures) relating elementary processes and external influences are mostly piecemeal formulations suitable to particular instances only. Here, we develop a general dynamical framework for distinct functional architectures characterized by the time-scale separation of their constituents and evaluate their efficiency. Thereto, we build on the (phase) flow of a system, which prescribes the temporal evolution of its state variables. The phase flow topology allows for the unambiguous classification of qualitatively distinct processes, which we consider to represent the functional units or modes within the dynamical architecture. Using the example of a composite movement we illustrate how different architectures can be characterized by their degree of time scale separation between the internal elements of the architecture (i.e. the functional modes) and external interventions. We reveal a tradeoff of the interactions between internal and external influences, which offers a theoretical justification for the efficient composition of complex processes out of non-trivial elementary processes or functional modes. PMID:21347363

A separate phase drag model and a surrogate approximation for simulation of the steam assisted gravity drainage (SAGD) process

DOE Office of Scientific and Technical Information (OSTI.GOV)

Padrino-Inciarte, Juan Carlos; Ma, Xia; VanderHeyden, W. Brian

General ensemble phase averaged equations for multiphase flows have been specialized for the simulation of the steam assisted gravity drainage (SAGD) process. In the average momentum equation, fluid-solid and fluid-fluid viscous interactions are represented by separate force terms. This equation has a form similar to that of Darcy’s law for multiphase flow but augmented by the fluid-fluid viscous forces. Models for these fluid-fluid interactions are suggested and implemented into the numerical code CartaBlanca. Numerical results indicate that the model captures the main features of the multiphase flow in the SAGD process, but the detailed features, such as plumes are missed.more » We find that viscous coupling among the fluid phases is important. Advection time scales for the different fluids differ by several orders of magnitude because of vast viscosity differences. Numerically resolving all of these time scales is time consuming. To address this problem, we introduce a steam surrogate approximation to increase the steam advection time scale, while keeping the mass and energy fluxes well approximated. This approximation leads to about a 40-fold speed-up in execution speed of the numerical calculations at the cost of a few percent error in the relevant quantities.« less

A separate phase drag model and a surrogate approximation for simulation of the steam assisted gravity drainage (SAGD) process

DOE PAGES

Padrino-Inciarte, Juan Carlos; Ma, Xia; VanderHeyden, W. Brian; ...

2016-01-01

General ensemble phase averaged equations for multiphase flows have been specialized for the simulation of the steam assisted gravity drainage (SAGD) process. In the average momentum equation, fluid-solid and fluid-fluid viscous interactions are represented by separate force terms. This equation has a form similar to that of Darcy’s law for multiphase flow but augmented by the fluid-fluid viscous forces. Models for these fluid-fluid interactions are suggested and implemented into the numerical code CartaBlanca. Numerical results indicate that the model captures the main features of the multiphase flow in the SAGD process, but the detailed features, such as plumes are missed.more » We find that viscous coupling among the fluid phases is important. Advection time scales for the different fluids differ by several orders of magnitude because of vast viscosity differences. Numerically resolving all of these time scales is time consuming. To address this problem, we introduce a steam surrogate approximation to increase the steam advection time scale, while keeping the mass and energy fluxes well approximated. This approximation leads to about a 40-fold speed-up in execution speed of the numerical calculations at the cost of a few percent error in the relevant quantities.« less

Study of the Unsteady Flow Features on a Stalled Wing

NASA Technical Reports Server (NTRS)

Yon, Steven A.; Katz, Joseph

1997-01-01

The occurrence of large scale structures in the post stall flow over a rectangular wing at high angles of attack was investigated in a small-scale subsonic wind tunnel. Mean and time dependent measurements within the separated flow field suggest the existence of two distinct angle of attack regimes beyond wing stall. The shallow stall regime occurs over a narrow range of incidence angles (2-3 deg.) immediately following the inception of leading edge separation. In this regime, the principal mean flow structures, termed stall cells, are manifested as a distinct spanwise periodicity in the chordwise extent of the separated region on the model surface with possible lateral mobility not previously reported. Within the stall cells and on the wing surface, large amplitude pressure fluctuations occur with a frequency much lower than anticipated for bluff body shedding, and with minimum effect in the far wake. In the deep stall regime, stall cells are not observed and the separated region near the model is relatively free of large amplitude pressure disturbances.

High-rate wastewater treatment combining a moving bed biofilm reactor and enhanced particle separation.

PubMed

Helness, H; Melin, E; Ulgenes, Y; Järvinen, P; Rasmussen, V; Odegaard, H

2005-01-01

Many cities around the world are looking for compact wastewater treatment alternatives since space for treatment plants is becoming scarce. In this paper development of a new compact, high-rate treatment concept with results from experiments in lab-scale and pilot-scale are presented. The idea behind the treatment concept is that coagulation/floc separation may be used to separate suspended and colloidal matter (resulting in > 70% organic matter removal in normal wastewater) while a high-rate biofilm process (based on Moving Bed biofilm reactors) may be used for removing low molecular weight, easily biodegradable, soluble organic matter. By using flotation for floc/biomass separation, the total residence time for a plant according to this concept will normally be < 1 hour. A cationic polymer combined with iron is used as coagulant at low dosages (i.e. 1-2 mg polymer/l, 5-10 mg Fe/l) resulting in low sludge production (compared to conventional chemical treatment) and sufficient P-removal.

Flow Control via a Single Spanwise Wire on the Surface of a Stationary Cylinder

NASA Astrophysics Data System (ADS)

Ekmekci, Alis; Rockwell, Donald

2007-11-01

The flow structure arising from a single spanwise wire attached along the surface of a circular stationary cylinder is investigated experimentally via a cinema technique of digital particle image velocimetry (DPIV). Consideration is given to wires that have smaller and larger scales than the thickness of the unperturbed boundary layer that develops around the cylinder prior to flow separation. The wires have diameters that are 1% and 3% of the cylinder diameter. Over a certain range of angular positions with respect to the approach flow, both small- and large-scale wires show important global effects on the entire near-wake. Two critical angles are identified on the basis of the near-wake structure. These critical angles are associated with extension and contraction of the near-wake, relative to the wake in absence of the effect of a surface disturbance. The critical angle of the wire that yields near-wake extension is associated with bistable oscillations of the separating shear layer, at irregular time intervals, much longer that the time scale associated with classical Karman vortex shedding. Moreover, for the large scale wire, in specific cases, either attenuation or enhancement of the Karman mode of vortex formation is observed.

Ultrafast Self-Assembly of Sub-10 nm Block Copolymer Nanostructures by Solvent-Free High-Temperature Laser Annealing.

PubMed

Jiang, Jing; Jacobs, Alan G; Wenning, Brandon; Liedel, Clemens; Thompson, Michael O; Ober, Christopher K

2017-09-20

Laser spike annealing was applied to PS-b-PDMS diblock copolymers to induce short-time (millisecond time scale), high-temperature (300 to 700 °C) microphase segregation and directed self-assembly of sub-10 nm features. Conditions were identified that enabled uniform microphase separation in the time frame of tens of milliseconds. Microphase ordering improved with increased temperature and annealing time, whereas phase separation contrast was lost for very short annealing times at high temperature. PMMA brush underlayers aided ordering under otherwise identical laser annealing conditions. Good long-range order for sub-10 nm cylinder morphology was achieved using graphoepitaxy coupled with a 20 ms dwell laser spike anneal above 440 °C.

Influence of the time scale on the construction of financial networks.

PubMed

Emmert-Streib, Frank; Dehmer, Matthias

2010-09-30

In this paper we investigate the definition and formation of financial networks. Specifically, we study the influence of the time scale on their construction. For our analysis we use correlation-based networks obtained from the daily closing prices of stock market data. More precisely, we use the stocks that currently comprise the Dow Jones Industrial Average (DJIA) and estimate financial networks where nodes correspond to stocks and edges correspond to none vanishing correlation coefficients. That means only if a correlation coefficient is statistically significant different from zero, we include an edge in the network. This construction procedure results in unweighted, undirected networks. By separating the time series of stock prices in non-overlapping intervals, we obtain one network per interval. The length of these intervals corresponds to the time scale of the data, whose influence on the construction of the networks will be studied in this paper. Numerical analysis of four different measures in dependence on the time scale for the construction of networks allows us to gain insights about the intrinsic time scale of the stock market with respect to a meaningful graph-theoretical analysis.

Separate versus Concurrent Calibration Methods in Vertical Scaling.

ERIC Educational Resources Information Center

Karkee, Thakur; Lewis, Daniel M.; Hoskens, Machteld; Yao, Lihua; Haug, Carolyn

Two methods to establish a common scale across grades within a content area using a common item design (separate and concurrent) have previously been studied under simulated conditions. Separate estimation is accomplished through separate calibration and grade-by-grade chained linking. Concurrent calibration established the vertical scale in a…

Satellite orbit and data sampling requirements

NASA Technical Reports Server (NTRS)

Rossow, William

1993-01-01

Climate forcings and feedbacks vary over a wide range of time and space scales. The operation of non-linear feedbacks can couple variations at widely separated time and space scales and cause climatological phenomena to be intermittent. Consequently, monitoring of global, decadal changes in climate requires global observations that cover the whole range of space-time scales and are continuous over several decades. The sampling of smaller space-time scales must have sufficient statistical accuracy to measure the small changes in the forcings and feedbacks anticipated in the next few decades, while continuity of measurements is crucial for unambiguous interpretation of climate change. Shorter records of monthly and regional (500-1000 km) measurements with similar accuracies can also provide valuable information about climate processes, when 'natural experiments' such as large volcanic eruptions or El Ninos occur. In this section existing satellite datasets and climate model simulations are used to test the satellite orbits and sampling required to achieve accurate measurements of changes in forcings and feedbacks at monthly frequency and 1000 km (regional) scale.

System identification through nonstationary data using Time-Frequency Blind Source Separation

NASA Astrophysics Data System (ADS)

Guo, Yanlin; Kareem, Ahsan

2016-06-01

Classical output-only system identification (SI) methods are based on the assumption of stationarity of the system response. However, measured response of buildings and bridges is usually non-stationary due to strong winds (e.g. typhoon, and thunder storm etc.), earthquakes and time-varying vehicle motions. Accordingly, the response data may have time-varying frequency contents and/or overlapping of modal frequencies due to non-stationary colored excitation. This renders traditional methods problematic for modal separation and identification. To address these challenges, a new SI technique based on Time-Frequency Blind Source Separation (TFBSS) is proposed. By selectively utilizing "effective" information in local regions of the time-frequency plane, where only one mode contributes to energy, the proposed technique can successfully identify mode shapes and recover modal responses from the non-stationary response where the traditional SI methods often encounter difficulties. This technique can also handle response with closely spaced modes which is a well-known challenge for the identification of large-scale structures. Based on the separated modal responses, frequency and damping can be easily identified using SI methods based on a single degree of freedom (SDOF) system. In addition to the exclusive advantage of handling non-stationary data and closely spaced modes, the proposed technique also benefits from the absence of the end effects and low sensitivity to noise in modal separation. The efficacy of the proposed technique is demonstrated using several simulation based studies, and compared to the popular Second-Order Blind Identification (SOBI) scheme. It is also noted that even some non-stationary response data can be analyzed by the stationary method SOBI. This paper also delineates non-stationary cases where SOBI and the proposed scheme perform comparably and highlights cases where the proposed approach is more advantageous. Finally, the performance of the proposed method is evaluated using a full-scale non-stationary response of a tall building during an earthquake and found it to perform satisfactorily.

Radar-based Quantitative Precipitation Forecasting using Spatial-scale Decomposition Method for Urban Flood Management

NASA Astrophysics Data System (ADS)

Yoon, S.; Lee, B.; Nakakita, E.; Lee, G.

2016-12-01

Recent climate changes and abnormal weather phenomena have resulted in increased occurrences of localized torrential rainfall. Urban areas in Korea have suffered from localized heavy rainfall, including the notable Seoul flood disaster in 2010 and 2011. The urban hydrological environment has changed in relation to precipitation, such as reduced concentration time, a decreased storage rate, and increased peak discharge. These changes have altered and accelerated the severity of damage to urban areas. In order to prevent such urban flash flood damages, we have to secure the lead time for evacuation through the improvement of radar-based quantitative precipitation forecasting (QPF). The purpose of this research is to improve the QPF products using spatial-scale decomposition method for considering the life time of storm and to assess the accuracy between traditional QPF method and proposed method in terms of urban flood management. The layout of this research is as below. First, this research applies the image filtering to separate the spatial-scale of rainfall field. Second, the separated small and large-scale rainfall fields are extrapolated by each different forecasting method. Third, forecasted rainfall fields are combined at each lead time. Finally, results of this method are evaluated and compared with the results of uniform advection model for urban flood modeling. It is expected that urban flood information using improved QPF will help to reduce casualties and property damage caused by urban flooding through this research.

Exploration of the benefits of an activity-specific test of temperament.

PubMed

Trofimova, Irina N

2009-10-01

The Structure of Temperament Questionnaire (STQ) was proposed by Rusalov in 1989 and subsequently tested in five languages. The questionnaire assesses four temperamental traits (Ergonicity, Plasticity, Tempo, and Emotionality) in three separate areas of activity: physical, verbal-social, and intellectual. The scales are all activity-specific. In 775 Canadian subjects, two temperament tests were compared, both developed on the basis of Pavlovian studies of the nervous system: the activity-specific approach (STQ) and the nonspecific Pavlovian Temperamental Survey (PTS). More significant sex differences were found on activity-specific scales of the STQ than on the nonspecific PTS scales. The pattern of correlations between the STQ scales and the time taken on an experimental task requiring a prolonged and intense word-assessment activity showed stronger correlations with the specific scales of the STQ measuring the dynamic aspects of social-verbal activity, and not with the PTS Strength of Excitation scale, which is based on a "general arousal" concept. The results supported the separation of temperament traits related to three different types of activities and opposed to "general arousal" theories of temperament.

Time scales for molecule formation by ion-molecule reactions

NASA Technical Reports Server (NTRS)

Langer, W. D.; Glassgold, A. E.

1976-01-01

Analytical solutions are obtained for nonlinear differential equations governing the time-dependence of molecular abundances in interstellar clouds. Three gas-phase reaction schemes are considered separately for the regions where each dominates. The particular case of CO, and closely related members of the Oh and CH families of molecules, is studied for given values of temperature, density, and the radiation field. Nonlinear effects and couplings with particular ions are found to be important. The time scales for CO formation range from 100,000 to a few million years, depending on the chemistry and regime. The time required for essentially complete conversion of C(+) to CO in the region where the H3(+) chemistry dominates is several million years. Because this time is longer than or comparable to dynamical time scales for dense interstellar clouds, steady-state abundances may not be observed in such clouds.

Semi-implicit time integration of atmospheric flows with characteristic-based flux partitioning

DOE Office of Scientific and Technical Information (OSTI.GOV)

Ghosh, Debojyoti; Constantinescu, Emil M.

2016-06-23

Here, this paper presents a characteristic-based flux partitioning for the semi-implicit time integration of atmospheric flows. Nonhydrostatic models require the solution of the compressible Euler equations. The acoustic time scale is significantly faster than the advective scale, yet it is typically not relevant to atmospheric and weather phenomena. The acoustic and advective components of the hyperbolic flux are separated in the characteristic space. High-order, conservative additive Runge-Kutta methods are applied to the partitioned equations so that the acoustic component is integrated in time implicitly with an unconditionally stable method, while the advective component is integrated explicitly. The time step ofmore » the overall algorithm is thus determined by the advective scale. Benchmark flow problems are used to demonstrate the accuracy, stability, and convergence of the proposed algorithm. The computational cost of the partitioned semi-implicit approach is compared with that of explicit time integration.« less

Levels of Satisfaction with Leisure Time in Foreign Students

ERIC Educational Resources Information Center

Akdeniz, Hakan; Simsek, Sinem Didem; Kavi, Onur; Uzuner, Muhammet Eyup; Sekban, Gulsah

2018-01-01

The aim of this study was to investigate levels of satisfaction with leisure time in foreign students of Kocaeli University. In the collection of the data, the Leisure Satisfaction Scale (LSS) and demographic status questionnaire were used; 257 male and 103 female students participated. In the LSS scores for the separate domains, participants…

Background-Source Cosmic-Photon Elevation Scaling and Cosmic-Neutron/Photon Date Scaling in MCNP6

NASA Astrophysics Data System (ADS)

Tutt, J.; Anderson, C.; McKinney, G.

Cosmic neutron and photon fluxes are known to scale exponentially with elevation. Consequently, cosmic neutron elevation scaling was implemented for use with the background-source option shortly after its introduction into MCNP6, whereby the neutron flux weight factor was adjusted by the elevation scaling factor when the user-specified elevation differed from the selected background.dat grid-point elevation. At the same time, an elevation scaling factor was suggested for the cosmic photon flux, however, cosmic photon elevation scaling is complicated by the fact that the photon background consists of two components: cosmic and terrestrial. Previous versions of the background.dat file did not provide any way to separate these components. With Rel. 4 of this file in 2015, two new columns were added that provide the energy grid and differential cosmic photon flux separately from the total photon flux. Here we show that the cosmic photon flux component can now be scaled independently and combined with the terrestrial component to form the total photon flux at a user-specified elevation in MCNP6. Cosmic background fluxes also scale with the solar cycle due to solar modulation. This modulation has been shown to be nearly sinusoidal over time, with an inverse effect - increased modulation leads to a decrease in cosmic fluxes. This effect was initially included with the cosmic source option in MCNP6 and has now been extended for use with the background source option when: (1) the date is specified in the background.dat file, and (2) when the user specifies a date on the source definition card. A description of the cosmic-neutron/photon date scaling feature will be presented along with scaling results for past and future date extrapolations.

Separation of components from a scale mixture of Gaussian white noises

NASA Astrophysics Data System (ADS)

Vamoş, Călin; Crăciun, Maria

2010-05-01

The time evolution of a physical quantity associated with a thermodynamic system whose equilibrium fluctuations are modulated in amplitude by a slowly varying phenomenon can be modeled as the product of a Gaussian white noise {Zt} and a stochastic process with strictly positive values {Vt} referred to as volatility. The probability density function (pdf) of the process Xt=VtZt is a scale mixture of Gaussian white noises expressed as a time average of Gaussian distributions weighted by the pdf of the volatility. The separation of the two components of {Xt} can be achieved by imposing the condition that the absolute values of the estimated white noise be uncorrelated. We apply this method to the time series of the returns of the daily S&P500 index, which has also been analyzed by means of the superstatistics method that imposes the condition that the estimated white noise be Gaussian. The advantage of our method is that this financial time series is processed without partitioning or removal of the extreme events and the estimated white noise becomes almost Gaussian only as result of the uncorrelation condition.

Scale Issues in Air Quality Modeling

EPA Science Inventory

This presentation reviews past model evaluation studies investigating the impact of horizontal grid spacing on model performance. It also presents several examples of using a spectral decomposition technique to separate the forcings from processes operating on different time scal...

Effect of Stagger on the Vibroacoustic Loads from Clustered Rockets

NASA Technical Reports Server (NTRS)

Rojo, Raymundo; Tinney, Charles E.; Ruf, Joseph H.

2016-01-01

The effect of stagger startup on the vibro-acoustic loads that form during the end- effects-regime of clustered rockets is studied using both full-scale (hot-gas) and laboratory scale (cold gas) data. Both configurations comprise three nozzles with thrust optimized parabolic contours that undergo free shock separated flow and restricted shock separated flow as well as an end-effects regime prior to flowing full. Acoustic pressure waveforms recorded at the base of the nozzle clusters are analyzed using various statistical metrics as well as time-frequency analysis. The findings reveal a significant reduction in end- effects-regime loads when engine ignition is staggered. However, regardless of stagger, both the skewness and kurtosis of the acoustic pressure time derivative elevate to the same levels during the end-effects-regime event thereby demonstrating the intermittence and impulsiveness of the acoustic waveforms that form during engine startup.

Fokker-Planck electron diffusion caused by an obliquely propagating electromagnetic wave packet of narrow bandwidth

NASA Technical Reports Server (NTRS)

Hizanidis, Kyriakos

1989-01-01

The relativistic motion of electrons in an intense electromagnetic wave packet propagating obliquely to a uniform magnetic field is analytically studied on the basis of the Fokker-Planck-Kolmogorov (FPK) approach. The wavepacket consists of circularly polarized electron-cyclotron waves. The dynamical system in question is shown to be reducible to one with three degrees of freedom. Within the framework of the Hamiltonian analysis the nonlinear diffusion tensor is derived, and it is shown that this tensor can be separated into zeroth-, first-, and second-order parts with respect to the relative bandwidth. The zeroth-order part describes diffusive acceleration along lines of constant unperturbed Hamiltonian. The second-order part, which corresponds to the longest time scale, describes diffusion across those lines. A possible transport theory is outlined on the basis of this separation of the time scales.

Modeling Climate Responses to Spectral Solar Forcing on Centennial and Decadal Time Scales

NASA Technical Reports Server (NTRS)

Wen, G.; Cahalan, R.; Rind, D.; Jonas, J.; Pilewskie, P.; Harder, J.

2012-01-01

We report a series of experiments to explore clima responses to two types of solar spectral forcing on decadal and centennial time scales - one based on prior reconstructions, and another implied by recent observations from the SORCE (Solar Radiation and Climate Experiment) SIM (Spectral 1rradiance Monitor). We apply these forcings to the Goddard Institute for Space Studies (GISS) Global/Middle Atmosphere Model (GCMAM). that couples atmosphere with ocean, and has a model top near the mesopause, allowing us to examine the full response to the two solar forcing scenarios. We show different climate responses to the two solar forCing scenarios on decadal time scales and also trends on centennial time scales. Differences between solar maximum and solar minimum conditions are highlighted, including impacts of the time lagged reSponse of the lower atmosphere and ocean. This contrasts with studies that assume separate equilibrium conditions at solar maximum and minimum. We discuss model feedback mechanisms involved in the solar forced climate variations.

On the estimation of the current density in space plasmas: Multi- versus single-point techniques

NASA Astrophysics Data System (ADS)

Perri, Silvia; Valentini, Francesco; Sorriso-Valvo, Luca; Reda, Antonio; Malara, Francesco

2017-06-01

Thanks to multi-spacecraft mission, it has recently been possible to directly estimate the current density in space plasmas, by using magnetic field time series from four satellites flying in a quasi perfect tetrahedron configuration. The technique developed, commonly called ;curlometer; permits a good estimation of the current density when the magnetic field time series vary linearly in space. This approximation is generally valid for small spacecraft separation. The recent space missions Cluster and Magnetospheric Multiscale (MMS) have provided high resolution measurements with inter-spacecraft separation up to 100 km and 10 km, respectively. The former scale corresponds to the proton gyroradius/ion skin depth in ;typical; solar wind conditions, while the latter to sub-proton scale. However, some works have highlighted an underestimation of the current density via the curlometer technique with respect to the current computed directly from the velocity distribution functions, measured at sub-proton scales resolution with MMS. In this paper we explore the limit of the curlometer technique studying synthetic data sets associated to a cluster of four artificial satellites allowed to fly in a static turbulent field, spanning a wide range of relative separation. This study tries to address the relative importance of measuring plasma moments at very high resolution from a single spacecraft with respect to the multi-spacecraft missions in the current density evaluation.

Change of Multifractal Thermal Characteristics in the Western Philippine Sea Upper Layer During Internal Wave-Soliton Propagation

DTIC Science & Technology

2007-01-01

where H is the scaling exponent , or called the Hurst exponent . In 1941, Kolmogorov suggested that the velocity increment in high-Reynolds number...turbulent flows should scale with the mean (time-averaged) energy dissipation and the separation length scale. The Hurst exponent H is equal to 1/3. For...the internal solitons change the power exponent of the power spectra drastically especially in the low wave number domain; break down the power law

Molecular dynamics at low time resolution.

PubMed

Faccioli, P

2010-10-28

The internal dynamics of macromolecular systems is characterized by widely separated time scales, ranging from fraction of picoseconds to nanoseconds. In ordinary molecular dynamics simulations, the elementary time step Δt used to integrate the equation of motion needs to be chosen much smaller of the shortest time scale in order not to cut-off physical effects. We show that in systems obeying the overdamped Langevin equation, it is possible to systematically correct for such discretization errors. This is done by analytically averaging out the fast molecular dynamics which occurs at time scales smaller than Δt, using a renormalization group based technique. Such a procedure gives raise to a time-dependent calculable correction to the diffusion coefficient. The resulting effective Langevin equation describes by construction the same long-time dynamics, but has a lower time resolution power, hence it can be integrated using larger time steps Δt. We illustrate and validate this method by studying the diffusion of a point-particle in a one-dimensional toy model and the denaturation of a protein.

Estimation of surface heat and moisture fluxes over a prairie grassland. II - Two-dimensional time filtering and site variability

NASA Technical Reports Server (NTRS)

Crosson, William L.; Smith, Eric A.

1992-01-01

The behavior of in situ measurements of surface fluxes obtained during FIFE 1987 is examined by using correlative and spectral techniques in order to assess the significance of fluctuations on various time scales, from subdiurnal up to synoptic, intraseasonal, and annual scales. The objectives of this analysis are: (1) to determine which temporal scales have a significant impact on areal averaged fluxes and (2) to design a procedure for filtering an extended flux time series that preserves the basic diurnal features and longer time scales while removing high frequency noise that cannot be attributed to site-induced variation. These objectives are accomplished through the use of a two-dimensional cross-time Fourier transform, which serves to separate processes inherently related to diurnal and subdiurnal variability from those which impact flux variations on the longer time scales. A filtering procedure is desirable before the measurements are utilized as input with an experimental biosphere model, to insure that model based intercomparisons at multiple sites are uncontaminated by input variance not related to true site behavior. Analysis of the spectral decomposition indicates that subdiurnal time scales having periods shorter than 6 hours have little site-to-site consistency and therefore little impact on areal integrated fluxes.

Synaptic Scaling Enables Dynamically Distinct Short- and Long-Term Memory Formation

PubMed Central

Tetzlaff, Christian; Kolodziejski, Christoph; Timme, Marc; Tsodyks, Misha; Wörgötter, Florentin

2013-01-01

Memory storage in the brain relies on mechanisms acting on time scales from minutes, for long-term synaptic potentiation, to days, for memory consolidation. During such processes, neural circuits distinguish synapses relevant for forming a long-term storage, which are consolidated, from synapses of short-term storage, which fade. How time scale integration and synaptic differentiation is simultaneously achieved remains unclear. Here we show that synaptic scaling – a slow process usually associated with the maintenance of activity homeostasis – combined with synaptic plasticity may simultaneously achieve both, thereby providing a natural separation of short- from long-term storage. The interaction between plasticity and scaling provides also an explanation for an established paradox where memory consolidation critically depends on the exact order of learning and recall. These results indicate that scaling may be fundamental for stabilizing memories, providing a dynamic link between early and late memory formation processes. PMID:24204240

Synaptic scaling enables dynamically distinct short- and long-term memory formation.

PubMed

Tetzlaff, Christian; Kolodziejski, Christoph; Timme, Marc; Tsodyks, Misha; Wörgötter, Florentin

2013-10-01

Memory storage in the brain relies on mechanisms acting on time scales from minutes, for long-term synaptic potentiation, to days, for memory consolidation. During such processes, neural circuits distinguish synapses relevant for forming a long-term storage, which are consolidated, from synapses of short-term storage, which fade. How time scale integration and synaptic differentiation is simultaneously achieved remains unclear. Here we show that synaptic scaling - a slow process usually associated with the maintenance of activity homeostasis - combined with synaptic plasticity may simultaneously achieve both, thereby providing a natural separation of short- from long-term storage. The interaction between plasticity and scaling provides also an explanation for an established paradox where memory consolidation critically depends on the exact order of learning and recall. These results indicate that scaling may be fundamental for stabilizing memories, providing a dynamic link between early and late memory formation processes.

Pattern, growth, and aging in aggregation kinetics of a Vicsek-like active matter model

NASA Astrophysics Data System (ADS)

Das, Subir K.

2017-01-01

Via molecular dynamics simulations, we study kinetics in a Vicsek-like phase-separating active matter model. Quantitative results, for isotropic bicontinuous pattern, are presented on the structure, growth, and aging. These are obtained via the two-point equal-time density-density correlation function, the average domain length, and the two-time density autocorrelation function. Both the correlation functions exhibit basic scaling properties, implying self-similarity in the pattern dynamics, for which the average domain size exhibits a power-law growth in time. The equal-time correlation has a short distance behavior that provides reasonable agreement between the corresponding structure factor tail and the Porod law. The autocorrelation decay is a power-law in the average domain size. Apart from these basic similarities, the overall quantitative behavior of the above-mentioned observables is found to be vastly different from those of the corresponding passive limit of the model which also undergoes phase separation. The functional forms of these have been quantified. An exceptionally rapid growth in the active system occurs due to fast coherent motion of the particles, mean-squared-displacements of which exhibit multiple scaling regimes, including a long time ballistic one.

Rapid and Convenient Separation of Chitooligosaccharides by Ion-Exchange Chromatography

NASA Astrophysics Data System (ADS)

Wu, Yuxiao; Lu, Wei-Peng; Wang, Jianing; Gao, Yunhua; Guo, Yanchuan

2017-12-01

Pervious methods for separation of highly purified chitooligosaccharides was time-consuming and labor-intensive, which limited the large-scale production. This study developed a convenient ion-exchange chromatography using the ÄKTA™ avant 150 chromatographic system. Five fractions were automatically collected under detecting the absorption at 210 nm. The fractions were analyzed by high-performance liquid chromatography. It proved that they primarily comprised chitobiose, chitotriose, chitotetraose, chitopentaose, and chitohexaose, respectively, with chromatographic purities over 90%. The separation process was rapid, convenient and could be monitored on-line, which would be benefit for the mass production of chitooligosaccharides.

Frequency Preference Response to Oscillatory Inputs in Two-dimensional Neural Models: A Geometric Approach to Subthreshold Amplitude and Phase Resonance.

PubMed

Rotstein, Horacio G

2014-01-01

We investigate the dynamic mechanisms of generation of subthreshold and phase resonance in two-dimensional linear and linearized biophysical (conductance-based) models, and we extend our analysis to account for the effect of simple, but not necessarily weak, types of nonlinearities. Subthreshold resonance refers to the ability of neurons to exhibit a peak in their voltage amplitude response to oscillatory input currents at a preferred non-zero (resonant) frequency. Phase-resonance refers to the ability of neurons to exhibit a zero-phase (or zero-phase-shift) response to oscillatory input currents at a non-zero (phase-resonant) frequency. We adapt the classical phase-plane analysis approach to account for the dynamic effects of oscillatory inputs and develop a tool, the envelope-plane diagrams, that captures the role that conductances and time scales play in amplifying the voltage response at the resonant frequency band as compared to smaller and larger frequencies. We use envelope-plane diagrams in our analysis. We explain why the resonance phenomena do not necessarily arise from the presence of imaginary eigenvalues at rest, but rather they emerge from the interplay of the intrinsic and input time scales. We further explain why an increase in the time-scale separation causes an amplification of the voltage response in addition to shifting the resonant and phase-resonant frequencies. This is of fundamental importance for neural models since neurons typically exhibit a strong separation of time scales. We extend this approach to explain the effects of nonlinearities on both resonance and phase-resonance. We demonstrate that nonlinearities in the voltage equation cause amplifications of the voltage response and shifts in the resonant and phase-resonant frequencies that are not predicted by the corresponding linearized model. The differences between the nonlinear response and the linear prediction increase with increasing levels of the time scale separation between the voltage and the gating variable, and they almost disappear when both equations evolve at comparable rates. In contrast, voltage responses are almost insensitive to nonlinearities located in the gating variable equation. The method we develop provides a framework for the investigation of the preferred frequency responses in three-dimensional and nonlinear neuronal models as well as simple models of coupled neurons.

Application of a chromatography model with linear gradient elution experimental data to the rapid scale-up in ion-exchange process chromatography of proteins.

PubMed

Ishihara, Takashi; Kadoya, Toshihiko; Yamamoto, Shuichi

2007-08-24

We applied the model described in our previous paper to the rapid scale-up in the ion exchange chromatography of proteins, in which linear flow velocity, column length and gradient slope were changed. We carried out linear gradient elution experiments, and obtained data for the peak salt concentration and peak width. From these data, the plate height (HETP) was calculated as a function of the mobile phase velocity and iso-resolution curve (the separation time and elution volume relationship for the same resolution) was calculated. The scale-up chromatography conditions were determined by the iso-resolution curve. The scale-up of the linear gradient elution from 5 to 100mL and 2.5L column sizes was performed both by the separation of beta-lactoglobulin A and beta-lactoglobulin B with anion-exchange chromatography and by the purification of a recombinant protein with cation-exchange chromatography. Resolution, recovery and purity were examined in order to verify the proposed method.

Impact vaporization: Late time phenomena from experiments

NASA Technical Reports Server (NTRS)

Schultz, P. H.; Gault, D. E.

1987-01-01

While simple airflow produced by the outward movement of the ejecta curtain can be scaled to large dimensions, the interaction between an impact-vaporized component and the ejecta curtain is more complicated. The goal of these experiments was to examine such interaction in a real system involving crater growth, ejection of material, two phased mixtures of gas and dust, and strong pressure gradients. The results will be complemented by theoretical studies at laboratory scales in order to separate the various parameters for planetary scale processes. These experiments prompt, however, the following conclusions that may have relevance at broader scales. First, under near vacuum or low atmospheric pressures, an expanding vapor cloud scours the surrounding surface in advance of arriving ejecta. Second, the effect of early-time vaporization is relatively unimportant at late-times. Third, the overpressure created within the crater cavity by significant vaporization results in increased cratering efficiency and larger aspect ratios.

Hydrological landscape analysis based on digital elevation data

NASA Astrophysics Data System (ADS)

Seibert, J.; McGlynn, B.; Grabs, T.; Jensco, K.

2008-12-01

Topography is a major factor controlling both hydrological and soil processes at the landscape scale. While this is well-accepted qualitatively, quantifying relationships between topography and spatial variations of hydrologically relevant variables at the landscape scale still remains a challenging research topic. In this presentation, we describe hydrological landscape analysis HLA) as a way to derive relevant topographic indicies to describe the spatial variations of hydrological variables at the landscape scale. We demonstrate our HLA approach with four high-resolution digital elevation models (DEMs) from Sweden, Switzerland and Montana (USA). To investigate scale effects HLA metrics, we compared DEMs of different resolutions. These LiDAR-derived DEMs of 3m, 10m, and 30m, resolution represent catchments of ~ 5 km2 ranging from low to high relief. A central feature of HLA is the flowpath-based analysis of topography and the separation of hillslopes, riparian areas, and the stream network. We included the following metrics: riparian area delineation, riparian buffer potential, separation of stream inflows into right and left bank components, travel time proxies based on flowpath distances and gradients to the channel, and as a hydrologic similarity to the hypsometric curve we suggest the distribution of elevations above the stream network (computed based on the location where a certain flow pathway enters the stream). Several of these indices depended clearly on DEM resolution, whereas this effect was minor for others. While the hypsometric curves all were S-shaped the 'hillslope-hypsometric curves' had the shape of a power function with exponents less than 1. In a similar way we separated flow pathway lengths and gradients between hillslopes and streams and compared a topographic travel time proxy, which was based on the integration of gradients along the flow pathways. Besides the comparison of HLA-metrics for different catchments and DEM resolutions we present examples from experimental catchments to illustrate how these metrics can be used to describe catchment scale hydrological processes and provide context for plot scale observations.

Validity of the Malaise Inventory in general population samples.

PubMed

Rodgers, B; Pickles, A; Power, C; Collishaw, S; Maughan, B

1999-06-01

The Malaise Inventory is a commonly used self-completion scale for assessing psychiatric morbidity. There is some evidence that it may represent two separate psychological and somatic subscales rather than a single underlying factor of distress. This paper provides further information on the factor structure of the Inventory and on the reliability and validity of the total scale and two sub-scales. Two general population samples completed the full Inventory: over 11,000 subjects from the National Child Development Study at ages 23 and 33, and 544 mothers of adolescents included in the Isle of Wight epidemiological surveys. The internal consistency of the full 24-item scale and the 15-item psychological subscale were found to be acceptable, but the eight-item somatic sub-scale was less reliable. Factor analysis of all 24 items identified a first main general factor and a second more purely psychological factor. Receiver operating characteristic (ROC) analysis indicated that the validity of the scale held for men and women separately and for different socio-economic groups, by reference to external criteria covering current or recent psychiatric morbidity and service use, and that the psychological sub-scale had no greater validity than the full scale. This study did not support the separate scoring of a somatic sub-scale of the Malaise Inventory. Use of the 15-item psychological sub-scale can be justified on the grounds of reduced time and cost for completion, with little loss of reliability or validity, but this approach would not significantly enhance the properties of the Inventory by comparison with the full 24-item scale. Inclusion of somatic items may be more problematic when the full scale is used to compare particular sub-populations with different propensities for physical morbidity, such as different age groups, and in these circumstances it would be a sensible precaution to utilise the 15-item psychological sub-scale.

Atomic Force Microscope Mediated Chromatography

NASA Technical Reports Server (NTRS)

Anderson, Mark S.

2013-01-01

The atomic force microscope (AFM) is used to inject a sample, provide shear-driven liquid flow over a functionalized substrate, and detect separated components. This is demonstrated using lipophilic dyes and normal phase chromatography. A significant reduction in both size and separation time scales is achieved with a 25-micron-length column scale, and one-second separation times. The approach has general applications to trace chemical and microfluidic analysis. The AFM is now a common tool for ultra-microscopy and nanotechnology. It has also been demonstrated to provide a number of microfluidic functions necessary for miniaturized chromatography. These include injection of sub-femtoliter samples, fluidic switching, and sheardriven pumping. The AFM probe tip can be used to selectively remove surface layers for subsequent microchemical analysis using infrared and tip-enhanced Raman spectroscopy. With its ability to image individual atoms, the AFM is a remarkably sensitive detector that can be used to detect separated components. These diverse functional components of microfluidic manipulation have been combined in this work to demonstrate AFM mediated chromatography. AFM mediated chromatography uses channel-less, shear-driven pumping. This is demonstrated with a thin, aluminum oxide substrate and a non-polar solvent system to separate a mixture of lipophilic dyes. In conventional chromatographic terms, this is analogous to thin-layer chromatography using normal phase alumina substrate with sheardriven pumping provided by the AFM tip-cantilever mechanism. The AFM detection of separated components is accomplished by exploiting the variation in the localized friction of the separated components. The AFM tip-cantilever provides the mechanism for producing shear-induced flows and rapid pumping. Shear-driven chromatography (SDC) is a relatively new concept that overcomes the speed and miniaturization limitations of conventional liquid chromatography. SDC is based on a sliding plate system, consisting of two flat surfaces, one of which has a recessed channel. A fluid flow is produced by axially sliding one plate past another, where the fluid has mechanical shear forces imposed at each point along the channel length. The shear-induced flow rates are very reproducible, and do not have pressure or voltage gradient limitations. SDC opens up a new range of enhanced separation kinetics by permitting the sample confinement with submicron dimensions. Small, highly confined liquid is advantageous for chromatographic separation because the separation rate is known to scale according to the square of the confined sample diameter. In addition, because shear-driven flows are not limited by fluid velocity, shear-driven liquid chromatography may provide up to 100,000 plate efficiency.

A Two-Time Scale Decentralized Model Predictive Controller Based on Input and Output Model

PubMed Central

Niu, Jian; Zhao, Jun; Xu, Zuhua; Qian, Jixin

2009-01-01

A decentralized model predictive controller applicable for some systems which exhibit different dynamic characteristics in different channels was presented in this paper. These systems can be regarded as combinations of a fast model and a slow model, the response speeds of which are in two-time scale. Because most practical models used for control are obtained in the form of transfer function matrix by plant tests, a singular perturbation method was firstly used to separate the original transfer function matrix into two models in two-time scale. Then a decentralized model predictive controller was designed based on the two models derived from the original system. And the stability of the control method was proved. Simulations showed that the method was effective. PMID:19834542

SIGN SINGULARITY AND FLARES IN SOLAR ACTIVE REGION NOAA 11158

DOE Office of Scientific and Technical Information (OSTI.GOV)

Sorriso-Valvo, L.; De Vita, G.; Kazachenko, M. D.

Solar Active Region NOAA 11158 has hosted a number of strong flares, including one X2.2 event. The complexity of current density and current helicity are studied through cancellation analysis of their sign-singular measure, which features power-law scaling. Spectral analysis is also performed, revealing the presence of two separate scaling ranges with different spectral index. The time evolution of parameters is discussed. Sudden changes of the cancellation exponents at the time of large flares and the presence of correlation with Extreme-Ultra-Violet and X-ray flux suggest that eruption of large flares can be linked to the small-scale properties of the current structures.

Wedge measures parallax separations...on large-scale 70-mm

Treesearch

Steven L. Wert; Richard J. Myhre

1967-01-01

A new parallax wedge (range: 1.5 to 2 inches) has been designed for use with large-scaled 70-mm. aerial photographs. The narrow separation of the wedge allows the user to measure small parallax separations that are characteristic of large-scale photographs.

Influence of the Time Scale on the Construction of Financial Networks

PubMed Central

Emmert-Streib, Frank; Dehmer, Matthias

2010-01-01

Background In this paper we investigate the definition and formation of financial networks. Specifically, we study the influence of the time scale on their construction. Methodology/Principal Findings For our analysis we use correlation-based networks obtained from the daily closing prices of stock market data. More precisely, we use the stocks that currently comprise the Dow Jones Industrial Average (DJIA) and estimate financial networks where nodes correspond to stocks and edges correspond to none vanishing correlation coefficients. That means only if a correlation coefficient is statistically significant different from zero, we include an edge in the network. This construction procedure results in unweighted, undirected networks. By separating the time series of stock prices in non-overlapping intervals, we obtain one network per interval. The length of these intervals corresponds to the time scale of the data, whose influence on the construction of the networks will be studied in this paper. Conclusions/Significance Numerical analysis of four different measures in dependence on the time scale for the construction of networks allows us to gain insights about the intrinsic time scale of the stock market with respect to a meaningful graph-theoretical analysis. PMID:20949124

REAL TIME CONTROL OF SEWERS: US EPA MANUAL

EPA Science Inventory

The problem of sewage spills and local flooding has traditionally been addressed by large scale capital improvement programs that focus on construction alternatives such as sewer separation or construction of storage facilities. The cost of such projects is often high, especiall...

Cooling of solar flares plasmas. 1: Theoretical considerations

NASA Technical Reports Server (NTRS)

Cargill, Peter J.; Mariska, John T.; Antiochos, Spiro K.

1995-01-01

Theoretical models of the cooling of flare plasma are reexamined. By assuming that the cooling occurs in two separate phase where conduction and radiation, respectively, dominate, a simple analytic formula for the cooling time of a flare plasma is derived. Unlike earlier order-of-magnitude scalings, this result accounts for the effect of the evolution of the loop plasma parameters on the cooling time. When the conductive cooling leads to an 'evaporation' of chromospheric material, the cooling time scales L(exp 5/6)/p(exp 1/6), where the coronal phase (defined as the time maximum temperature). When the conductive cooling is static, the cooling time scales as L(exp 3/4)n(exp 1/4). In deriving these results, use was made of an important scaling law (T proportional to n(exp 2)) during the radiative cooling phase that was forst noted in one-dimensional hydrodynamic numerical simulations (Serio et al. 1991; Jakimiec et al. 1992). Our own simulations show that this result is restricted to approximately the radiative loss function of Rosner, Tucker, & Vaiana (1978). for different radiative loss functions, other scaling result, with T and n scaling almost linearly when the radiative loss falls off as T(exp -2). It is shown that these scaling laws are part of a class of analytic solutions developed by Antiocos (1980).

Universal time-dependent dispersion properties for diffusion in a one-dimensional critically tilted potential

NASA Astrophysics Data System (ADS)

Guérin, T.; Dean, D. S.

2017-01-01

We consider the time-dependent dispersion properties of overdamped tracer particles diffusing in a one-dimensional periodic potential under the influence of an additional constant tilting force F . The system is studied in the region where the force is close to the critical value Fc at which the barriers separating neighboring potential wells disappear. We show that, when F crosses the critical value, the shape of the mean-square displacement (MSD) curves is strongly modified. We identify a diffusive regime at intermediate-time scales with an effective diffusion coefficient which is much larger than the late-time diffusion coefficient for F >Fc , whereas for F

Method of producing nano-scaled inorganic platelets

DOEpatents

Zhamu, Aruna; Jang, Bor Z.

2012-11-13

The present invention provides a method of exfoliating a layered material (e.g., transition metal dichalcogenide) to produce nano-scaled platelets having a thickness smaller than 100 nm, typically smaller than 10 nm. The method comprises (a) dispersing particles of a non-graphite laminar compound in a liquid medium containing therein a surfactant or dispersing agent to obtain a stable suspension or slurry; and (b) exposing the suspension or slurry to ultrasonic waves at an energy level for a sufficient length of time to produce separated nano-scaled platelets. The nano-scaled platelets are candidate reinforcement fillers for polymer nanocomposites.

Singular Perturbations and Time Scales in Modeling and Control of Dynamic Systems,

DTIC Science & Technology

1980-11-01

Madanic, "Closed-Loop Stackelberg Stategies for Singularly Perturbed Linear Quadratic Problem," IEEE Transactions on Automtic Control, Vol. AC-25, No...of the state variables. On the other hand the com- (15 damped high steqenc oscillalor mode cannsome o \\s/ del are not separable. In this ’ mixed ’ case...are found to be mixed and hence is not electromechanical Interactions and the single ma- suitable for direct state separation into a slow chine

Lagrangian velocity and acceleration correlations of large inertial particles in a closed turbulent flow

DOE Office of Scientific and Technical Information (OSTI.GOV)

Machicoane, Nathanaël; Volk, Romain

We investigate the response of large inertial particle to turbulent fluctuations in an inhomogeneous and anisotropic flow. We conduct a Lagrangian study using particles both heavier and lighter than the surrounding fluid, and whose diameters are comparable to the flow integral scale. Both velocity and acceleration correlation functions are analyzed to compute the Lagrangian integral time and the acceleration time scale of such particles. The knowledge of how size and density affect these time scales is crucial in understanding particle dynamics and may permit stochastic process modelization using two-time models (for instance, Sawford’s). As particles are tracked over long timesmore » in the quasi-totality of a closed flow, the mean flow influences their behaviour and also biases the velocity time statistics, in particular the velocity correlation functions. By using a method that allows for the computation of turbulent velocity trajectories, we can obtain unbiased Lagrangian integral time. This is particularly useful in accessing the scale separation for such particles and to comparing it to the case of fluid particles in a similar configuration.« less

Efficient and Extensible Quasi-Explicit Modular Nonlinear Multiscale Battery Model: GH-MSMD

DOE Office of Scientific and Technical Information (OSTI.GOV)

Kim, Gi-Heon; Smith, Kandler; Lawrence-Simon, Jake

Complex physics and long computation time hinder the adoption of computer aided engineering models in the design of large-format battery cells and systems. A modular, efficient battery simulation model -- the multiscale multidomain (MSMD) model -- was previously introduced to aid the scale-up of Li-ion material and electrode designs to complete cell and pack designs, capturing electrochemical interplay with 3-D electronic current pathways and thermal response. Here, this paper enhances the computational efficiency of the MSMD model using a separation of time-scales principle to decompose model field variables. The decomposition provides a quasi-explicit linkage between the multiple length-scale domains andmore » thus reduces time-consuming nested iteration when solving model equations across multiple domains. In addition to particle-, electrode- and cell-length scales treated in the previous work, the present formulation extends to bus bar- and multi-cell module-length scales. We provide example simulations for several variants of GH electrode-domain models.« less

Efficient and Extensible Quasi-Explicit Modular Nonlinear Multiscale Battery Model: GH-MSMD

DOE PAGES

Kim, Gi-Heon; Smith, Kandler; Lawrence-Simon, Jake; ...

2017-03-24

Complex physics and long computation time hinder the adoption of computer aided engineering models in the design of large-format battery cells and systems. A modular, efficient battery simulation model -- the multiscale multidomain (MSMD) model -- was previously introduced to aid the scale-up of Li-ion material and electrode designs to complete cell and pack designs, capturing electrochemical interplay with 3-D electronic current pathways and thermal response. Here, this paper enhances the computational efficiency of the MSMD model using a separation of time-scales principle to decompose model field variables. The decomposition provides a quasi-explicit linkage between the multiple length-scale domains andmore » thus reduces time-consuming nested iteration when solving model equations across multiple domains. In addition to particle-, electrode- and cell-length scales treated in the previous work, the present formulation extends to bus bar- and multi-cell module-length scales. We provide example simulations for several variants of GH electrode-domain models.« less

On the wake flow of asymmetrically beveled trailing edges

NASA Astrophysics Data System (ADS)

Guan, Yaoyi; Pröbsting, Stefan; Stephens, David; Gupta, Abhineet; Morris, Scott C.

2016-05-01

Trailing edge and wake flows are of interest for a wide range of applications. Small changes in the design of asymmetrically beveled or semi-rounded trailing edges can result in significant difference in flow features which are relevant for the aerodynamic performance, flow-induced structural vibration and aerodynamically generated sound. The present study describes in detail the flow field characteristics around a family of asymmetrically beveled trailing edges with an enclosed trailing-edge angle of 25° and variable radius of curvature R. The flow fields over the beveled trailing edges are described using data obtained by particle image velocimetry (PIV) experiments. The flow topology for different trailing edges was found to be strongly dependent on the radius of curvature R, with flow separation occurring further downstream as R increases. This variation in the location of flow separation influences the aerodynamic force coefficients, which were evaluated from the PIV data using a control volume approach. Two-point correlations of the in-plane velocity components are considered to assess the structure in the flow field. The analysis shows large-scale coherent motions in the far wake, which are associated with vortex shedding. The wake thickness parameter yf is confirmed as an appropriate length scale to characterize this large-scale roll-up motion in the wake. The development in the very near wake was found to be critically dependent on R. In addition, high-speed PIV measurements provide insight into the spectral characteristics of the turbulent fluctuations. Based on the time-resolved flow field data, the frequency range associated with the shedding of coherent vortex pairs in the wake is identified. By means of time-correlation of the velocity components, turbulent structures are found to convect from the attached or separated shear layers without distinct separation point into the wake.

Simulations of eddy kinetic energy transport in barotropic turbulence

NASA Astrophysics Data System (ADS)

Grooms, Ian

2017-11-01

Eddy energy transport in rotating two-dimensional turbulence is investigated using numerical simulation. Stochastic forcing is used to generate an inhomogeneous field of turbulence and the time-mean energy profile is diagnosed. An advective-diffusive model for the transport is fit to the simulation data by requiring the model to accurately predict the observed time-mean energy distribution. Isotropic harmonic diffusion of energy is found to be an accurate model in the case of uniform, solid-body background rotation (the f plane), with a diffusivity that scales reasonably well with a mixing-length law κ ∝V ℓ , where V and ℓ are characteristic eddy velocity and length scales. Passive tracer dynamics are added and it is found that the energy diffusivity is 75 % of the tracer diffusivity. The addition of a differential background rotation with constant vorticity gradient β leads to significant changes to the energy transport. The eddies generate and interact with a mean flow that advects the eddy energy. Mean advection plus anisotropic diffusion (with reduced diffusivity in the direction of the background vorticity gradient) is moderately accurate for flows with scale separation between the eddies and mean flow, but anisotropic diffusion becomes a much less accurate model of the transport when scale separation breaks down. Finally, it is observed that the time-mean eddy energy does not look like the actual eddy energy distribution at any instant of time. In the future, stochastic models of the eddy energy transport may prove more useful than models of the mean transport for predicting realistic eddy energy distributions.

The ultrasonically assisted metals recovery treatment of printed circuit board waste sludge by leaching separation.

PubMed

Xie, Fengchun; Li, Haiying; Ma, Yang; Li, Chuncheng; Cai, Tingting; Huang, Zhiyuan; Yuan, Gaoqing

2009-10-15

This paper provides a practical technique that realized industrial scale copper and iron separation from printed circuit board (PCB) waste sludge by ultrasonically assisted acid leaching in a low cost, low energy consumption and zero discharge of wastes manner. The separation efficiencies of copper and iron from acid leaching with assistance of ultrasound were compared with the one without assistance of ultrasound and the effects of the leaching procedure, pH value, and ultrasonic strength have been investigated in the paper. With the appropriate leaching procedure, a final pH of 3.0, an ultrasonic generator power of 160 W (in 1l tank), leaching time of 60 min, leaching efficiencies of copper and iron had reached 97.83% and 1.23%, respectively. Therefore the separation of copper and iron in PCB waste sludge was virtually achieved. The lab results had been successfully applied to the industrial scaled applications in a heavy metal recovery plant in city of Huizhou, China for more than two years. It has great potentials to be used in even the broad metal recovery practices.

Relative Time-scale for Channeling Events Within Chaotic Terrains, Margaritifer Sinus, Mars

NASA Technical Reports Server (NTRS)

Janke, D.

1985-01-01

A relative time scale for ordering channel and chaos forming events was constructed for areas within the Margaritifer Sinus region of Mars. Transection and superposition relationships of channels, chaotic terrain, and the surfaces surrounding them were used to create the relative time scale; crater density studies were not used. Channels and chaos in contact with one another were treated as systems. These systems were in turn treated both separately (in order to understand internal relationships) and as members of the suite of Martian erosional forms (in order to produce a combined, master time scale). Channeling events associated with chaotic terrain development occurred over an extended geomorphic period. The channels can be divided into three convenient groups: those that pre-date intercrater plains development post-plains, pre-chasma systems; and those associated with the development of the Vallis Marineris chasmata. No correlations with cyclic climatic changes, major geologic events in other regions on Mars, or triggering phenomena (for example, specific impact events) were found.

Inspection of the dynamic properties of laminar separation bubbles: free-stream turbulence intensity effects for different Reynolds numbers

NASA Astrophysics Data System (ADS)

Simoni, Daniele; Lengani, Davide; Ubaldi, Marina; Zunino, Pietro; Dellacasagrande, Matteo

2017-06-01

The effects of free-stream turbulence intensity (FSTI) on the transition process of a pressure-induced laminar separation bubble have been studied for different Reynolds numbers (Re) by means of time-resolved (TR) PIV. Measurements have been performed along a flat plate installed within a double-contoured test section, designed to produce an adverse pressure gradient typical of ultra-high-lift turbine blade profiles. A test matrix spanning 3 FSTI levels and 3 Reynolds numbers has been considered allowing estimation of cross effects of these parameters on the instability mechanisms driving the separated flow transition process. Boundary layer integral parameters, spatial growth rate and saturation level of velocity fluctuations are discussed for the different cases in order to characterize the base flow response as well as the time-mean properties of the Kelvin-Helmholtz instability. The inspection of the instantaneous velocity vector maps highlights the dynamics of the large-scale structures shed near the bubble maximum displacement, as well as the low-frequency motion of the fore part of the separated shear layer. Proper Orthogonal Decomposition (POD) has been implemented to reduce the large amount of data for each condition allowing a rapid evaluation of the group velocity, spatial wavelength and dominant frequency of the vortex shedding process. The dimensionless shedding wave number parameter makes evident that the modification of the shear layer thickness at separation due to Reynolds number variation mainly drives the length scale of the rollup vortices, while higher FSTI levels force the onset of the shedding phenomenon to occur upstream due to the higher velocity fluctuations penetrating into the separating boundary layer.

Evidence of a forward energy cascade and Kolmogorov self-similarity in submesoscale ocean surface drifter observations

NASA Astrophysics Data System (ADS)

Poje, Andrew C.; Ã-zgökmen, Tamay M.; Bogucki, Darek J.; Kirwan, A. D.

2017-02-01

Using two-point velocity and position data from the near-simultaneous release of O(100) GPS-tracked surface drifters in the northern Gulf of Mexico, we examine the applicability of classical turbulent scaling laws to upper ocean velocity fields. The dataset allows direct estimates of both velocity structure functions and the temporal evolution of the distribution of particle pair separations. On 100 m-10 km spatial scales, and time scales of order 1-10 days, all metrics of the observed surface fluctuations are consistent with standard Kolmogorov turbulence theory in an energy cascade inertial-range regime. The sign of the third-order structure function is negative and proportional to the separation distance for scales ≲10 km where local, fluctuating Rossby numbers are found to be larger than 0.1. The scale-independent energy dissipation rate, or downscale spectral flux, estimated from Kolmogorov's 4/5th law in this regime closely matches nearby microscale dissipation measurements in the near-surface. In contrast, similar statistics derived from a like-sized set of synthetic drifters advected by purely geostrophic altimetric AVISO data agree well with Kolmogorov-Kraichnan scaling for 2D turbulence in the forward enstrophy cascade range.

Separation of spatial-temporal patterns ('climatic modes') by combined analysis of really measured and generated numerically vector time series

NASA Astrophysics Data System (ADS)

Feigin, A. M.; Mukhin, D.; Volodin, E. M.; Gavrilov, A.; Loskutov, E. M.

2013-12-01

The new method of decomposition of the Earth's climate system into well separated spatial-temporal patterns ('climatic modes') is discussed. The method is based on: (i) generalization of the MSSA (Multichannel Singular Spectral Analysis) [1] for expanding vector (space-distributed) time series in basis of spatial-temporal empirical orthogonal functions (STEOF), which makes allowance delayed correlations of the processes recorded in spatially separated points; (ii) expanding both real SST data, and longer by several times SST data generated numerically, in STEOF basis; (iii) use of the numerically produced STEOF basis for exclusion of 'too slow' (and thus not represented correctly) processes from real data. The application of the method allows by means of vector time series generated numerically by the INM RAS Coupled Climate Model [2] to separate from real SST anomalies data [3] two climatic modes possessing by noticeably different time scales: 3-5 and 9-11 years. Relations of separated modes to ENSO and PDO are investigated. Possible applications of spatial-temporal climatic patterns concept to prognosis of climate system evolution is discussed. 1. Ghil, M., R. M. Allen, M. D. Dettinger, K. Ide, D. Kondrashov, et al. (2002) "Advanced spectral methods for climatic time series", Rev. Geophys. 40(1), 3.1-3.41. 2. http://83.149.207.89/GCM_DATA_PLOTTING/GCM_INM_DATA_XY_en.htm 3. http://iridl.ldeo.columbia.edu/SOURCES/.KAPLAN/.EXTENDED/.v2/.ssta/

Separation of Time Scales in a Quantum Newton’s Cradle

DOE PAGES

van den Berg, R.; Wouters, B.; Eliëns, S.; ...

2016-06-01

For strongly repulsive bosons in one dimension, we provide detailed modeling of the Bragg pulse used in quantum Newton's cradle-like settings or in Bragg spectroscopy experiments. By employing the Fermi-Bose mapping for a nite harmonically trapped gas and the Quench Action approach for a thermodynamic system on a ring, we reconstruct the exact post-pulse many-body time evolution of Lieb-Liniger gases in the Tonks-Girardeau limit, together with their changing local density pro le and momentum distribution. Our results display a clear separation of timescales between rapid and trap-insensitive relaxation immediately after the pulse, followed by slow in-trap periodic behaviour.

Differences in mother-to-infant bonding according to type of C-section: Elective versus unplanned.

PubMed

Forti-Buratti, María Azul; Palanca-Maresca, Inmaculada; Fajardo-Simón, Lourdes; Olza-Fernández, Ibone; Bravo-Ortiz, María Fe; Marín-Gabriel, Miguel Ángel

2017-12-01

Aim To compare the mother-to-infant bond of mothers who gave birth by elective C-section versus urgent C-section in the first 48-72h of life and 10-12weeks after delivery. This is a cohort prospective study of women giving birth by C-section. 48-72h after delivery, sociodemographic variables were collected, Mother-to-Infant Bonding Scale and newborn's response to separation test were performed. 10-12weeks after delivery Mother-to-Infant Bonding Scale and questions about baby's feeding were completed. A total of 116 dyads were recruited, 58 in each group. No significant differences between the two C-sections in bonding, newborn response to separation or type of feeding were observed at any time points. However, those dyads presenting with an abnormal bond at time 1 had more frequently an abnormal bond at time 2 (50% versus 8.1%, p=0.000). No differences in mother-to-infant bond were found according to type of C-section. Copyright © 2017 Elsevier B.V. All rights reserved.

Characteristic variations of sea surface temperature with multiple time scales in the North Pacific

DOE Office of Scientific and Technical Information (OSTI.GOV)

Tanimoto, Youichi; Hanawa, Kimio; Toba, Yoshiaki

1993-06-01

It is unclear whether the recent increases in global temperatures are really due to the increase of greenhouse gases or are a manifestation of natural variability. Temporal evolution and spectral structure of sea surface temperature (SST) anomalies in the North Pacific over the last 37 years are investigated on the three characteristic time scales: shorter than 24 months (HF), 24-60 months (ES), and longer than 60 months (DC). The leading empirical-orthogonal function (EOF) for the DC time scale is characterized by a zonally elongated monopole centered at around 40[degrees]N, 180[degrees]. The leading EOF for the HF time scale is somewhatmore » similar to that for the DC time scale, although there are two centers of action with the same polarity at the mid and western Pacific. The leading EOF for the ES time scale, however, exhibits a different pattern whose center of action at the mid Pacific is located farther southeastward. In the time evolution of the SST anomalies associated with the leading EOF of the DC time scale, several anomaly periods can be identified that last five years or longer. The transition from a persistent period to another with the opposite polarity is generally very brief, except for the one that lasts throughout the late 1960s. The EOF analysis was repeated separately on these persistent anomaly periods and the long transition period. The spatial structure of the leading EOF of the SST variability with the ES time scale is found to be sensitive to the polarity of the decadal anomaly. These results are suggestive of the possible influence of the decadal SST variability upon the spatial structure of the variability with shorter time scales. 31 refs., 8 figs.« less

A High Resolution Scale-of-four

DOE R&D Accomplishments Database

Fitch, V.

1949-08-25

A high resolution scale-of-four has been developed to be used in conjunction with the nuclear particle detection devices in applications where the counting rate is unusually high. Specifically, it is intended to precede the commercially available medium resolution scaling circuits and so decrease the resolving time of the counting system. The circuit will function reliably on continuously recurring pulses separated by less than 0.1 microseconds. It will resolve two pulses (occurring at a moderate repetition rate) which are spaced at 0.04 microseconds. A five-volt input signal is sufficient to actuate the device.

Cheetah Reunion - The Challenge of Finding Your Friends Again.

PubMed

Hubel, Tatjana Y; Shotton, Justine; Wilshin, Simon D; Horgan, Jane; Klein, Rebecca; McKenna, Rick; Wilson, Alan M

2016-01-01

Animals navigate their environment using a variety of senses and strategies. This multiplicity enables them to respond to different navigational requirements resulting from habitat, scale and purpose. One of the challenges social animals face is how to reunite after periods of separation. We explore a variety of possible mechanisms used to reunite the members of a cheetah coalition dispersed within a large area after prolonged separation. Using GPS data from three cheetahs reuniting after weeks of separation, we determined that 1) the likelihood of purely coincidental reunion is miniscule 2) the reunion occurred in an area not normally frequented 3) with very little time spent in the region in advance of the reunion. We therefore propose that timely encounter of scent markings where paths cross is the most likely mechanism used to aid the reunion.

Cheetah Reunion – The Challenge of Finding Your Friends Again

PubMed Central

Shotton, Justine; Wilshin, Simon D.; Horgan, Jane; Klein, Rebecca; McKenna, Rick; Wilson, Alan M.

2016-01-01

Animals navigate their environment using a variety of senses and strategies. This multiplicity enables them to respond to different navigational requirements resulting from habitat, scale and purpose. One of the challenges social animals face is how to reunite after periods of separation. We explore a variety of possible mechanisms used to reunite the members of a cheetah coalition dispersed within a large area after prolonged separation. Using GPS data from three cheetahs reuniting after weeks of separation, we determined that 1) the likelihood of purely coincidental reunion is miniscule 2) the reunion occurred in an area not normally frequented 3) with very little time spent in the region in advance of the reunion. We therefore propose that timely encounter of scent markings where paths cross is the most likely mechanism used to aid the reunion. PMID:27926915

Tannase-mediated biotransformation assisted separation and purification of theaflavin and epigallocatechin by high speed counter current chromatography and preparative high performance liquid chromatography: A comparative study.

PubMed

Xia, Guobin; Lin, Chunfang; Liu, Songbai

2016-09-01

A large scale isolation and purification of theaflavin (TF) and epigallocatechin (EGC) has been successfully developed by tannase-mediated biotransformation combining high-speed countercurrent chromatography. After tannase hydrolysis of a commercially available theaflavins extract (TE), the content of TF and EGC in tannase-mediated biotransformation product (TBP) achieved approximately 3 times enrichment. SEM studies revealed smooth tannase biotransformation and the possibility of recovery of the tannase. A single 1.5 hours' HSCCC separation for TF and EGC employing a two-phase solvent system could simultaneously produce 180.8 mg of 97.3% purity TF and 87.5 mg of 97.3% purity EGC. However, a preparative HPLC separation of maximum injection volume containing 120 mg TBP prepared 11.2 mg TF of 94.9% purity and 7.7 mg EGC of 89.9% purity. HSCCC separation demonstrated significant advantages over Prep HPLC in terms of sample loading size, separation time, environmental friendly solvent systems, and the production. © 2016 Wiley Periodicals, Inc.

A Structured Grid Based Solution-Adaptive Technique for Complex Separated Flows

NASA Technical Reports Server (NTRS)

Thornburg, Hugh; Soni, Bharat K.; Kishore, Boyalakuntla; Yu, Robert

1996-01-01

The objective of this work was to enhance the predictive capability of widely used computational fluid dynamic (CFD) codes through the use of solution adaptive gridding. Most problems of engineering interest involve multi-block grids and widely disparate length scales. Hence, it is desirable that the adaptive grid feature detection algorithm be developed to recognize flow structures of different type as well as differing intensity, and adequately address scaling and normalization across blocks. In order to study the accuracy and efficiency improvements due to the grid adaptation, it is necessary to quantify grid size and distribution requirements as well as computational times of non-adapted solutions. Flow fields about launch vehicles of practical interest often involve supersonic freestream conditions at angle of attack exhibiting large scale separate vortical flow, vortex-vortex and vortex-surface interactions, separated shear layers and multiple shocks of different intensity. In this work, a weight function and an associated mesh redistribution procedure is presented which detects and resolves these features without user intervention. Particular emphasis has been placed upon accurate resolution of expansion regions and boundary layers. Flow past a wedge at Mach=2.0 is used to illustrate the enhanced detection capabilities of this newly developed weight function.

Removal of Iron Oxide Scale from Feed-water in Thermal Power Plant by Using Magnetic Separation

NASA Astrophysics Data System (ADS)

Nakanishi, Motohiro; Shibatani, Saori; Mishima, Fumihito; Akiyama, Yoko; Nishijima, Shigehiro

2017-09-01

One of the factors of deterioration in thermal power generation efficiency is adhesion of the scale to inner wall in feed-water system. Though thermal power plants have employed All Volatile Treatment (AVT) or Oxygen Treatment (OT) to prevent scale formation, these treatments cannot prevent it completely. In order to remove iron oxide scale, we proposed magnetic separation system using solenoidal superconducting magnet. Magnetic separation efficiency is influenced by component and morphology of scale which changes their property depending on the type of water treatment and temperature. In this study, we estimated component and morphology of iron oxide scale at each equipment in the feed-water system by analyzing simulated scale generated in the pressure vessel at 320 K to 550 K. Based on the results, we considered installation sites of the magnetic separation system.

SEPARATING DIFFERENT SCALES OF MOTION IN TIME SERIES OF METEOROLOGICAL VARIABLES. (R825260)

EPA Science Inventory

The perspectives, information and conclusions conveyed in research project abstracts, progress reports, final reports, journal abstracts and journal publications convey the viewpoints of the principal investigator and may not represent the views and policies of ORD and EPA. Concl...

Control of Systems With Slow Actuators Using Time Scale Separation

NASA Technical Reports Server (NTRS)

Stepanyan, Vehram; Nguyen, Nhan

2009-01-01

This paper addresses the problem of controlling a nonlinear plant with a slow actuator using singular perturbation method. For the known plant-actuator cascaded system the proposed scheme achieves tracking of a given reference model with considerably less control demand than would otherwise result when using conventional design techniques. This is the consequence of excluding the small parameter from the actuator dynamics via time scale separation. The resulting tracking error is within the order of this small parameter. For the unknown system the adaptive counterpart is developed based on the prediction model, which is driven towards the reference model by the control design. It is proven that the prediction model tracks the reference model with an error proportional to the small parameter, while the prediction error converges to zero. The resulting closed-loop system with all prediction models and adaptive laws remains stable. The benefits of the approach are demonstrated in simulation studies and compared to conventional control approaches.

Development of processes for the production of solar grade silicon from halides and alkali metals, phase 1 and phase 2

NASA Technical Reports Server (NTRS)

Dickson, C. R.; Gould, R. K.; Felder, W.

1981-01-01

High temperature reactions of silicon halides with alkali metals for the production of solar grade silicon are described. Product separation and collection processes were evaluated, measure heat release parameters for scaling purposes and effects of reactants and/or products on materials of reactor construction were determined, and preliminary engineering and economic analysis of a scaled up process were made. The feasibility of the basic process to make and collect silicon was demonstrated. The jet impaction/separation process was demonstrated to be a purification process. The rate at which gas phase species from silicon particle precursors, the time required for silane decomposition to produce particles, and the competing rate of growth of silicon seed particles injected into a decomposing silane environment were determined. The extent of silane decomposition as a function of residence time, temperature, and pressure was measured by infrared absorption spectroscopy. A simplistic model is presented to explain the growth of silicon in a decomposing silane enviroment.

Universal time-dependent dispersion properties for diffusion in a one-dimensional critically tilted potential.

PubMed

Guérin, T; Dean, D S

2017-01-01

We consider the time-dependent dispersion properties of overdamped tracer particles diffusing in a one-dimensional periodic potential under the influence of an additional constant tilting force F. The system is studied in the region where the force is close to the critical value F_{c} at which the barriers separating neighboring potential wells disappear. We show that, when F crosses the critical value, the shape of the mean-square displacement (MSD) curves is strongly modified. We identify a diffusive regime at intermediate-time scales with an effective diffusion coefficient which is much larger than the late-time diffusion coefficient for F>F_{c}, whereas for F

Low speed streak formation in a separating turbulent boundary layer

NASA Astrophysics Data System (ADS)

Santos, Leonardo; Lang, Amy; Wahidi, Redha; Bonacci, Andrew

2017-11-01

Separation control mechanisms present on the skin of the shortfin mako shark may permit higher swimming speeds. The morphology of the scales varies over the entire body, with maximum scale flexibility found on the flank region with an adverse pressure gradient(APG). It is hypothesized that reversing flow close the skin bristles the scales inhibiting further flow reversal and controlling flow separation. Experiments are conducted in water tunnel facility and the flow field of a separating turbulent boundary layer(TBL) is measured using DPIV and Insight V3V. Flow separation is induced by a rotating cylinder which generates a controlled APG over a flat plate (Re = 510000 and 620000). Specifically, the low speed streak(LSS) formation is documented and matches predicted sizing based on viscous length scale calculations. It is surmised that shark scale width corresponds to this LSS sizing for real swimming TBL conditions. However, flow separation control has been demonstrated over real skin specimens under much lower speed conditions which indicates the mechanism is fairly Re independent if multiple scales are bristled as the width of the LSS increases. The formation of reversing flow within the streaks is studied specifically to better understand the process by which this flow initiates scale bristling on shortfin mako skin as a passive, flow actuated separation control mechanism. The authors would like to greatefully acknowledge the Army Research Office for funding this project.

Direct Observations of a Dynamically Driven Phase Transition with in situ X-Ray Diffraction in a Simple Ionic Crystal

NASA Astrophysics Data System (ADS)

Kalita, Patricia; Specht, Paul; Root, Seth; Sinclair, Nicholas; Schuman, Adam; White, Melanie; Cornelius, Andrew L.; Smith, Jesse; Sinogeikin, Stanislav

2017-12-01

We report real-time observations of a phase transition in the ionic solid CaF2 , a model A B2 structure in high-pressure physics. Synchrotron x-ray diffraction coupled with dynamic loading to 27.7 GPa, and separately with static compression, follows, in situ, the fluorite to cotunnite structural phase transition, both on nanosecond and on minute time scales. Using Rietveld refinement techniques, we examine the kinetics and hysteresis of the transition. Our results give insight into the kinetic time scale of the fluorite-cotunnite phase transition under shock compression, which is relevant to a number of isomorphic compounds.

Direct Observations of a Dynamically Driven Phase Transition with in situ X-Ray Diffraction in a Simple Ionic Crystal

DOE PAGES

Kalita, Patricia E.; Specht, Paul Elliot; Root, Seth; ...

2017-12-21

Here, we report real-time observations of a phase transition in the ionic solid CaF 2, a model AB 2 structure in high-pressure physics. Synchrotron x-ray diffraction coupled with dynamic loading to 27.7 GPa, and separately with static compression, follows, in situ, the fluorite to cotunnite structural phase transition, both on nanosecond and on minute time scales. Using Rietveld refinement techniques, we examine the kinetics and hysteresis of the transition. Our results give insight into the kinetic time scale of the fluorite-cotunnite phase transition under shock compression, which is relevant to a number of isomorphic compounds.

Observations of Omicron 1 Cygni (STFA 50AD)

NASA Astrophysics Data System (ADS)

Bidler, Jeff; Hagee, Joshua; McGuire, Paul; McGuire, Rosa; Montes, Leslie; Richardson, Nicole; Rodriguez, Arturo; Brewer, Mark

2016-10-01

In over 215 years, the star STFA 50AD located in the Cygnus constellation has only been analyzed about 35 times. A group of eight individuals from five affiliations participated in the third annual Apple Valley Double Star Workshop to measure the separations and position angles of a double star. During this workshop, data from several astronomical identifiers was used to compare the data collected. The main apparatus used was an 8-inch telescope. An astrometric eyepiece and a stopwatch were used. The scale constant 9.9 arc seconds per division mark, separations 340.9 arc seconds, and position angles 324.1 degrees were determined by the telescope-eyepiece combination. The plate scale 1.01 arc seconds per pixel, separation 337.1 arc seconds, and position angle 321.3 degrees were determined by using the Digitized Sky Survey and Astrometrica. The results obtained were compared to previous observations listed in the Washington Double Star Catalog. After rigorous calculations and teamwork, it was concluded that the 2008 results were determined to be an outlier.

Charge Separation and Exciton Dynamics at Polymer/ZnO Interface from First-Principles Simulations.

PubMed

Wu, Guangfen; Li, Zi; Zhang, Xu; Lu, Gang

2014-08-07

Charge separation and exciton dynamics play a crucial role in determining the performance of excitonic photovoltaics. Using time-dependent density functional theory with a range-separated exchange-correlation functional as well as nonadiabatic ab initio molecular dynamics, we have studied the formation and dynamics of charge-transfer (CT) excitons at polymer/ZnO interface. The interfacial atomic structure, exciton density of states and conversions between exciton species are examined from first-principles. The exciton dynamics exhibits both adiabatic and nonadiabatic characters. While the adiabatic transitions are facilitated by C═C vibrations along the polymer (P3HT) backbone, the nonadiabatic transitions are realized by exciton hopping between the excited states. We find that the localized ZnO surface states lead to localized low-energy CT states and poor charge separation. In contrast, the surface states of crystalline C60 are indistinguishable from the bulk states, resulting in delocalized CT states and efficient charge separation in polymer/fullerene (P3HT/PCBM) heterojunctions. The hot CT states are found to cool down in an ultrafast time scale and may not play a major role in charge separation of P3HT/ZnO. Finally we suggest that the dimensions of nanostructured acceptors can be tuned to obtain both efficient charge separation and high open circuit voltages.

On hydrostatic flows in isentropic coordinates

NASA Astrophysics Data System (ADS)

Bokhove, Onno

2000-01-01

The hydrostatic primitive equations of motion which have been used in large-scale weather prediction and climate modelling over the last few decades are analysed with variational methods in an isentropic Eulerian framework. The use of material isentropic coordinates for the Eulerian hydrostatic equations is known to have distinct conceptual advantages since fluid motion is, under inviscid and statically stable circumstances, confined to take place on quasi-horizontal isentropic surfaces. First, an Eulerian isentropic Hamilton's principle, expressed in terms of fluid parcel variables, is therefore derived by transformation of a Lagrangian Hamilton's principle to an Eulerian one. This Eulerian principle explicitly describes the boundary dynamics of the time-dependent domain in terms of advection of boundary isentropes sB; these are the values the isentropes have at their intersection with the (lower) boundary. A partial Legendre transform for only the interior variables yields an Eulerian ‘action’ principle. Secondly, Noether's theorem is used to derive energy and potential vorticity conservation from the Eulerian Hamilton's principle. Thirdly, these conservation laws are used to derive a wave-activity invariant which is second-order in terms of small-amplitude disturbances relative to a resting or moving basic state. Linear stability criteria are derived but only for resting basic states. In mid-latitudes a time- scale separation between gravity and vortical modes occurs. Finally, this time-scale separation suggests that conservative geostrophic and ageostrophic approximations can be made to the Eulerian action principle for hydrostatic flows. Approximations to Eulerian variational principles may be more advantageous than approximations to Lagrangian ones because non-dimensionalization and scaling tend to be based on Eulerian estimates of the characteristic scales involved. These approximations to the stratified hydrostatic formulation extend previous approximations to the shallow- water equations. An explicit variational derivation is given of an isentropic version of Hoskins & Bretherton's model for atmospheric fronts.

Downscaling ocean conditions: Experiments with a quasi-geostrophic model

NASA Astrophysics Data System (ADS)

Katavouta, A.; Thompson, K. R.

2013-12-01

The predictability of small-scale ocean variability, given the time history of the associated large-scales, is investigated using a quasi-geostrophic model of two wind-driven gyres separated by an unstable, mid-ocean jet. Motivated by the recent theoretical study of Henshaw et al. (2003), we propose a straightforward method for assimilating information on the large-scale in order to recover the small-scale details of the quasi-geostrophic circulation. The similarity of this method to the spectral nudging of limited area atmospheric models is discussed. Results from the spectral nudging of the quasi-geostrophic model, and an independent multivariate regression-based approach, show that important features of the ocean circulation, including the position of the meandering mid-ocean jet and the associated pinch-off eddies, can be recovered from the time history of a small number of large-scale modes. We next propose a hybrid approach for assimilating both the large-scales and additional observed time series from a limited number of locations that alone are too sparse to recover the small scales using traditional assimilation techniques. The hybrid approach improved significantly the recovery of the small-scales. The results highlight the importance of the coupling between length scales in downscaling applications, and the value of assimilating limited point observations after the large-scales have been set correctly. The application of the hybrid and spectral nudging to practical ocean forecasting, and projecting changes in ocean conditions on climate time scales, is discussed briefly.

Least-rattling feedback from strong time-scale separation

NASA Astrophysics Data System (ADS)

Chvykov, Pavel; England, Jeremy

2018-03-01

In most interacting many-body systems associated with some "emergent phenomena," we can identify subgroups of degrees of freedom that relax on dramatically different time scales. Time-scale separation of this kind is particularly helpful in nonequilibrium systems where only the fast variables are subjected to external driving; in such a case, it may be shown through elimination of fast variables that the slow coordinates effectively experience a thermal bath of spatially varying temperature. In this paper, we investigate how such a temperature landscape arises according to how the slow variables affect the character of the driven quasisteady state reached by the fast variables. Brownian motion in the presence of spatial temperature gradients is known to lead to the accumulation of probability density in low-temperature regions. Here, we focus on the implications of attraction to low effective temperature for the long-term evolution of slow variables. After quantitatively deriving the temperature landscape for a general class of overdamped systems using a path-integral technique, we then illustrate in a simple dynamical system how the attraction to low effective temperature has a fine-tuning effect on the slow variable, selecting configurations that bring about exceptionally low force fluctuation in the fast-variable steady state. We furthermore demonstrate that a particularly strong effect of this kind can take place when the slow variable is tuned to bring about orderly, integrable motion in the fast dynamics that avoids thermalizing energy absorbed from the drive. We thus point to a potentially general feedback mechanism in multi-time-scale active systems, that leads to the exploration of slow variable space, as if in search of fine tuning for a "least-rattling" response in the fast coordinates.

Inertial particle manipulation in microscale oscillatory flows

NASA Astrophysics Data System (ADS)

Agarwal, Siddhansh; Rallabandi, Bhargav; Raju, David; Hilgenfeldt, Sascha

2017-11-01

Recent work has shown that inertial effects in oscillating flows can be exploited for simultaneous transport and differential displacement of microparticles, enabling size sorting of such particles on extraordinarily short time scales. Generalizing previous theory efforts, we here derive a two-dimensional time-averaged version of the Maxey-Riley equation that includes the effect of an oscillating interface to model particle dynamics in such flows. Separating the steady transport time scale from the oscillatory time scale results in a simple and computationally efficient reduced model that preserves all slow-time features of the full unsteady Maxey-Riley simulations, including inertial particle displacement. Comparison is made not only to full simulations, but also to experiments using oscillating bubbles as the driving interfaces. In this case, the theory predicts either an attraction to or a repulsion from the bubble interface due to inertial effects, so that versatile particle manipulation is possible using differences in particle size, particle/fluid density contrast and streaming strength. We also demonstrate that these predictions are in agreement with experiments.

Low-temperature method of producing nano-scaled graphene platelets and their nanocomposites

DOEpatents

Zhamu, Aruna [Centerville, OH; Shi, Jinjun [Columbus, OH; Guo, Jiusheng [Centerville, OH; Jang, Bor Z [Centerville, OH

2012-03-13

A method of exfoliating a layered material to produce separated nano-scaled platelets having a thickness smaller than 100 nm. The method comprises: (a) providing a graphite intercalation compound comprising a layered graphite containing expandable species residing in an interlayer space of the layered graphite; (b) exposing the graphite intercalation compound to an exfoliation temperature lower than 650.degree. C. for a duration of time sufficient to at least partially exfoliate the layered graphite without incurring a significant level of oxidation; and (c) subjecting the at least partially exfoliated graphite to a mechanical shearing treatment to produce separated platelets. The method can further include a step of dispersing the platelets in a polymer or monomer solution or suspension as a precursor step to nanocomposite fabrication.

Strategy for large-scale isolation of enantiomers in drug discovery.

PubMed

Leek, Hanna; Thunberg, Linda; Jonson, Anna C; Öhlén, Kristina; Klarqvist, Magnus

2017-01-01

A strategy for large-scale chiral resolution is illustrated by the isolation of pure enantiomer from a 5kg batch. Results from supercritical fluid chromatography will be presented and compared with normal phase liquid chromatography. Solubility of the compound in the supercritical mobile phase was shown to be the limiting factor. To circumvent this, extraction injection was used but shown not to be efficient for this compound. Finally, a method for chiral resolution by crystallization was developed and applied to give diastereomeric salt with an enantiomeric excess of 99% at a 91% yield. Direct access to a diverse separation tool box will be shown to be essential for solving separation problems in the most cost and time efficient way. Copyright © 2016 Elsevier Ltd. All rights reserved.

Parallel multispot smFRET analysis using an 8-pixel SPAD array

NASA Astrophysics Data System (ADS)

Ingargiola, A.; Colyer, R. A.; Kim, D.; Panzeri, F.; Lin, R.; Gulinatti, A.; Rech, I.; Ghioni, M.; Weiss, S.; Michalet, X.

2012-02-01

Single-molecule Förster resonance energy transfer (smFRET) is a powerful tool for extracting distance information between two fluorophores (a donor and acceptor dye) on a nanometer scale. This method is commonly used to monitor binding interactions or intra- and intermolecular conformations in biomolecules freely diffusing through a focal volume or immobilized on a surface. The diffusing geometry has the advantage to not interfere with the molecules and to give access to fast time scales. However, separating photon bursts from individual molecules requires low sample concentrations. This results in long acquisition time (several minutes to an hour) to obtain sufficient statistics. It also prevents studying dynamic phenomena happening on time scales larger than the burst duration and smaller than the acquisition time. Parallelization of acquisition overcomes this limit by increasing the acquisition rate using the same low concentrations required for individual molecule burst identification. In this work we present a new two-color smFRET approach using multispot excitation and detection. The donor excitation pattern is composed of 4 spots arranged in a linear pattern. The fluorescent emission of donor and acceptor dyes is then collected and refocused on two separate areas of a custom 8-pixel SPAD array. We report smFRET measurements performed on various DNA samples synthesized with various distances between the donor and acceptor fluorophores. We demonstrate that our approach provides identical FRET efficiency values to a conventional single-spot acquisition approach, but with a reduced acquisition time. Our work thus opens the way to high-throughput smFRET analysis on freely diffusing molecules.

Reynolds number dependence of relative dispersion statistics in isotropic turbulence

NASA Astrophysics Data System (ADS)

Sawford, Brian L.; Yeung, P. K.; Hackl, Jason F.

2008-06-01

Direct numerical simulation results for a range of relative dispersion statistics over Taylor-scale Reynolds numbers up to 650 are presented in an attempt to observe and quantify inertial subrange scaling and, in particular, Richardson's t3 law. The analysis includes the mean-square separation and a range of important but less-studied differential statistics for which the motion is defined relative to that at time t =0. It seeks to unambiguously identify and quantify the Richardson scaling by demonstrating convergence with both the Reynolds number and initial separation. According to these criteria, the standard compensated plots for these statistics in inertial subrange scaling show clear evidence of a Richardson range but with an imprecise estimate for the Richardson constant. A modified version of the cube-root plots introduced by Ott and Mann [J. Fluid Mech. 422, 207 (2000)] confirms such convergence. It has been used to yield more precise estimates for Richardson's constant g which decrease with Taylor-scale Reynolds numbers over the range of 140-650. Extrapolation to the large Reynolds number limit gives an asymptotic value for Richardson's constant in the range g =0.55-0.57, depending on the functional form used to make the extrapolation.

DOE Office of Scientific and Technical Information (OSTI.GOV)

Naughton, M.J.; Bourke, W.; Browning, G.L.

The convergence of spectral model numerical solutions of the global shallow-water equations is examined as a function of the time step and the spectral truncation. The contributions to the errors due to the spatial and temporal discretizations are separately identified and compared. Numerical convergence experiments are performed with the inviscid equations from smooth (Rossby-Haurwitz wave) and observed (R45 atmospheric analysis) initial conditions, and also with the diffusive shallow-water equations. Results are compared with the forced inviscid shallow-water equations case studied by Browning et al. Reduction of the time discretization error by the removal of fast waves from the solution usingmore » initialization is shown. The effects of forcing and diffusion on the convergence are discussed. Time truncation errors are found to dominate when a feature is large scale and well resolved; spatial truncation errors dominate for small-scale features and also for large scale after the small scales have affected them. Possible implications of these results for global atmospheric modeling are discussed. 31 refs., 14 figs., 4 tabs.« less

Ultrafast Electron Transfer across a Nanocapsular Wall: Coumarins as Donors, Viologen as Acceptor, and Octa Acid Capsule as the Mediator.

PubMed

Chuang, Chi-Hung; Porel, Mintu; Choudhury, Rajib; Burda, Clemens; Ramamurthy, V

2018-01-11

Results of our study on ultrafast electron transfer (eT) dynamics from coumarins (coumarin-1, coumarin-480, and coumarin-153) incarcerated within octa acid (OA) capsules as electron donors to methyl viologen dissolved in water as acceptor are presented. Upon photoexcitation, coumarin inside the OA capsule transfers an electron to the acceptor electrostatically attached to the capsule leading to a long-lived radical-ion pair separated by the OA capsular wall. This charge-separated state returns to the neutral ground state via back electron transfer on the nanosecond time scale. This system allows for ultrafast electron transfer processes through a molecular wall from the apolar capsular interior to the highly polar (aqueous) environment on the femtosecond time scale. Employing femtosecond transient absorption spectroscopy, distinct rates of both forward (1-25 ps) and backward eT (700-1200 ps) processes were measured. Further understanding of the energetics is provided using Rehm-Weller analysis for the investigated photoinduced eT reactions. The results provide the rates of the eT across a molecular wall, akin to an isotropic solution, depending on the standard free energy of the reaction. The insights from this work could be utilized in the future design of efficient electron transfer processes across interfaces separating apolar and polar environments.

Two-Time Scale Virtual Sensor Design for Vibration Observation of a Translational Flexible-Link Manipulator Based on Singular Perturbation and Differential Games

PubMed Central

Ju, Jinyong; Li, Wei; Wang, Yuqiao; Fan, Mengbao; Yang, Xuefeng

2016-01-01

Effective feedback control requires all state variable information of the system. However, in the translational flexible-link manipulator (TFM) system, it is unrealistic to measure the vibration signals and their time derivative of any points of the TFM by infinite sensors. With the rigid-flexible coupling between the global motion of the rigid base and the elastic vibration of the flexible-link manipulator considered, a two-time scale virtual sensor, which includes the speed observer and the vibration observer, is designed to achieve the estimation for the vibration signals and their time derivative of the TFM, as well as the speed observer and the vibration observer are separately designed for the slow and fast subsystems, which are decomposed from the dynamic model of the TFM by the singular perturbation. Additionally, based on the linear-quadratic differential games, the observer gains of the two-time scale virtual sensor are optimized, which aims to minimize the estimation error while keeping the observer stable. Finally, the numerical calculation and experiment verify the efficiency of the designed two-time scale virtual sensor. PMID:27801840

Advances in high frequency ultrasound separation of particulates from biomass.

PubMed

Juliano, Pablo; Augustin, Mary Ann; Xu, Xin-Qing; Mawson, Raymond; Knoerzer, Kai

2017-03-01

In recent years the use of high frequency ultrasound standing waves (megasonics) for droplet or cell separation from biomass has emerged beyond the microfluidics scale into the litre to industrial scale applications. The principle for this separation technology relies on the differential positioning of individual droplets or particles across an ultrasonic standing wave field within the reactor and subsequent biomass material predisposition for separation via rapid droplet agglomeration or coalescence into larger entities. Large scale transducers have been characterised with sonochemiluminescence and hydrophones to enable better reactor designs. High frequency enhanced separation technology has been demonstrated at industrial scale for oil recovery in the palm oil industry and at litre scale to assist olive oil, coconut oil and milk fat separation. Other applications include algal cell dewatering and milk fat globule fractionation. Frequency selection depends on the material properties and structure in the biomass mixture. Higher frequencies (1 and 2MHz) have proven preferable for better separation of materials with smaller sized droplets such as milk fat globules. For palm oil and olive oil, separation has been demonstrated within the 400-600kHz region, which has high radical production, without detectable impact on product quality. Crown Copyright © 2016. Published by Elsevier B.V. All rights reserved.

Progress in fast, accurate multi-scale climate simulations

DOE PAGES

Collins, W. D.; Johansen, H.; Evans, K. J.; ...

2015-06-01

We present a survey of physical and computational techniques that have the potential to contribute to the next generation of high-fidelity, multi-scale climate simulations. Examples of the climate science problems that can be investigated with more depth with these computational improvements include the capture of remote forcings of localized hydrological extreme events, an accurate representation of cloud features over a range of spatial and temporal scales, and parallel, large ensembles of simulations to more effectively explore model sensitivities and uncertainties. Numerical techniques, such as adaptive mesh refinement, implicit time integration, and separate treatment of fast physical time scales are enablingmore » improved accuracy and fidelity in simulation of dynamics and allowing more complete representations of climate features at the global scale. At the same time, partnerships with computer science teams have focused on taking advantage of evolving computer architectures such as many-core processors and GPUs. As a result, approaches which were previously considered prohibitively costly have become both more efficient and scalable. In combination, progress in these three critical areas is poised to transform climate modeling in the coming decades.« less

Analysis of high-incidence separated flow past airfoils

NASA Technical Reports Server (NTRS)

Chia, K. N.; Osswald, G. A.; Chia, U.

1989-01-01

An unsteady Navier-Stokes (NS) analysis is developed and used to carefully examine high-incidence aerodynamic separated flows past airfoils. Clustered conformal C-grids are employed for the 12 percent thick symmetric Joukowski airfoil as well as for the NACA 0012 airfoil with a sharp trailing edge. The clustering is controlled by appropriate one-dimensional stretching transformations. An attempt is made to resolve many of the dominant scales of an unsteady flow with massive separation, while maintaining the transformation metrics to be smooth and continuous in the entire flow field. A fully implicit time-marching alternating-direction implicit-block Gaussian elimination (ADI-BGE) method is employed, in which no use is made of any explicit artificial dissipation. Detailed results are obtained for massively separated, unsteady flow past symmetric Joukowski and NACA 0012 airfoils.

RaInCube: a proposed constellation of precipitation profiling Radars In Cubesat

NASA Astrophysics Data System (ADS)

Peral, E.; Tanelli, S.; Haddad, Z. S.; Stephens, G. L.; Im, E.

2014-12-01

Precipitation radars in Low-Earth-Orbit provide vertically resolved profiles of rain and snow on a global scale. With the recent advances in miniaturized radar and CubeSat/SmallSat technologies, it would now be feasible to launch multiple copies of the same radar instrument in desirable formations to allow measurements of short time scale evolution of atmospheric processes. One such concept is the novel radar architecture compatible with the 6U CubeSat class that is being developed at JPL by exploiting simplification and miniaturization of the radar subsystems. The RaInCube architecture would significantly reduce the number of components, power consumption and mass with respect to existing spaceborne radars. The baseline RaInCube instrument configuration would be a fixed nadir-pointing profiler at Ka-band with a minimum detectable reflectivity better than +10 dBZ at 250m range resolution and 5 km horizontal resolution. The low cost nature of the RaInCube platform would enable deployment of a constellation of identical copies of the same instrument in various relative positions in LEO to address specific observational gaps left open by the current missions that require high-resolution vertical profiling capability. A constellation of only four RaInCubes would populate the precipitation statistics in a distributed fashion across the globe and across the times of day, and therefore, would enable substantially better sampling of the diurnal cycle statistics. One could extend this scheme by adding more RaInCubes in each of the orbital planes, and phase them once in orbit so that they would be separated by an arbitrary amount of time among them. Wide separations (say 20-30 min) would further extend the sampling of the diurnal cycle to sub-hourly scales. Narrower time separations between RaInCubes would allow studying the evolution of convective systems at the convective time scale in each region of interest and would reveal the dominant modes of evolution of each corresponding climatological regime. A constellation of RaInCubes would also be a natural complement to other resources aiming at monitoring the evolution of weather systems, for example the Geostationary IR/VIS imagers, the NEXRAD network, and the GPM constellation.

Decomposition of the complex system into nonlinear spatio-temporal modes: algorithm and application to climate data mining

NASA Astrophysics Data System (ADS)

Feigin, Alexander; Gavrilov, Andrey; Loskutov, Evgeny; Mukhin, Dmitry

2015-04-01

Proper decomposition of the complex system into well separated "modes" is a way to reveal and understand the mechanisms governing the system behaviour as well as discover essential feedbacks and nonlinearities. The decomposition is also natural procedure that provides to construct adequate and concurrently simplest models of both corresponding sub-systems, and of the system in whole. In recent works two new methods of decomposition of the Earth's climate system into well separated modes were discussed. The first method [1-3] is based on the MSSA (Multichannel Singular Spectral Analysis) [4] for linear expanding vector (space-distributed) time series and makes allowance delayed correlations of the processes recorded in spatially separated points. The second one [5-7] allows to construct nonlinear dynamic modes, but neglects delay of correlations. It was demonstrated [1-3] that first method provides effective separation of different time scales, but prevent from correct reduction of data dimension: slope of variance spectrum of spatio-temporal empirical orthogonal functions that are "structural material" for linear spatio-temporal modes, is too flat. The second method overcomes this problem: variance spectrum of nonlinear modes falls essentially sharply [5-7]. However neglecting time-lag correlations brings error of mode selection that is uncontrolled and increases with growth of mode time scale. In the report we combine these two methods in such a way that the developed algorithm allows constructing nonlinear spatio-temporal modes. The algorithm is applied for decomposition of (i) multi hundreds years globally distributed data generated by the INM RAS Coupled Climate Model [8], and (ii) 156 years time series of SST anomalies distributed over the globe [9]. We compare efficiency of different methods of decomposition and discuss the abilities of nonlinear spatio-temporal modes for construction of adequate and concurrently simplest ("optimal") models of climate systems. 1. Feigin A.M., Mukhin D., Gavrilov A., Volodin E.M., and Loskutov E.M. (2013) "Separation of spatial-temporal patterns ("climatic modes") by combined analysis of really measured and generated numerically vector time series", AGU 2013 Fall Meeting, Abstract NG33A-1574. 2. Alexander Feigin, Dmitry Mukhin, Andrey Gavrilov, Evgeny Volodin, and Evgeny Loskutov (2014) "Approach to analysis of multiscale space-distributed time series: separation of spatio-temporal modes with essentially different time scales", Geophysical Research Abstracts, Vol. 16, EGU2014-6877. 3. Dmitry Mukhin, Dmitri Kondrashov, Evgeny Loskutov, Andrey Gavrilov, Alexander Feigin, and Michael Ghil (2014) "Predicting critical transitions in ENSO models, Part II: Spatially dependent models", Journal of Climate (accepted, doi: 10.1175/JCLI-D-14-00240.1). 4. Ghil, M., R. M. Allen, M. D. Dettinger, K. Ide, D. Kondrashov, et al. (2002) "Advanced spectral methods for climatic time series", Rev. Geophys. 40(1), 3.1-3.41. 5. Dmitry Mukhin, Andrey Gavrilov, Evgeny M Loskutov and Alexander M Feigin (2014) "Nonlinear Decomposition of Climate Data: a New Method for Reconstruction of Dynamical Modes", AGU 2014 Fall Meeting, Abstract NG43A-3752. 6. Andrey Gavrilov, Dmitry Mukhin, Evgeny Loskutov, and Alexander Feigin (2015) "Empirical decomposition of climate data into nonlinear dynamic modes", Geophysical Research Abstracts, Vol. 17, EGU2015-627. 7. Dmitry Mukhin, Andrey Gavrilov, Evgeny Loskutov, Alexander Feigin, and Juergen Kurths (2015) "Reconstruction of principal dynamical modes from climatic variability: nonlinear approach", Geophysical Research Abstracts, Vol. 17, EGU2015-5729. 8. http://83.149.207.89/GCM_DATA_PLOTTING/GCM_INM_DATA_XY_en.htm. 9. http://iridl.ldeo.columbia.edu/SOURCES/.KAPLAN/.EXTENDED/.v2/.ssta/.

Generation of skeletal mechanism by means of projected entropy participation indices

NASA Astrophysics Data System (ADS)

Paolucci, Samuel; Valorani, Mauro; Ciottoli, Pietro Paolo; Galassi, Riccardo Malpica

2017-11-01

When the dynamics of reactive systems develop very-slow and very-fast time scales separated by a range of active time scales, with gaps in the fast/active and slow/active time scales, then it is possible to achieve multi-scale adaptive model reduction along-with the integration of the ODEs using the G-Scheme. The scheme assumes that the dynamics is decomposed into active, slow, fast, and invariant subspaces. We derive expressions that establish a direct link between time scales and entropy production by using estimates provided by the G-Scheme. To calculate the contribution to entropy production, we resort to a standard model of a constant pressure, adiabatic, batch reactor, where the mixture temperature of the reactants is initially set above the auto-ignition temperature. Numerical experiments show that the contribution to entropy production of the fast subspace is of the same magnitude as the error threshold chosen for the identification of the decomposition of the tangent space, and the contribution of the slow subspace is generally much smaller than that of the active subspace. The information on entropy production associated with reactions within each subspace is used to define an entropy participation index that is subsequently utilized for model reduction.

Skin Cancer, Irradiation, and Sunspots: The Solar Cycle Effect

PubMed Central

Zurbenko, Igor

2014-01-01

Skin cancer is diagnosed in more than 2 million individuals annually in the United States. It is strongly associated with ultraviolet exposure, with melanoma risk doubling after five or more sunburns. Solar activity, characterized by features such as irradiance and sunspots, undergoes an 11-year solar cycle. This fingerprint frequency accounts for relatively small variation on Earth when compared to other uncorrelated time scales such as daily and seasonal cycles. Kolmogorov-Zurbenko filters, applied to the solar cycle and skin cancer data, separate the components of different time scales to detect weaker long term signals and investigate the relationships between long term trends. Analyses of crosscorrelations reveal epidemiologically consistent latencies between variables which can then be used for regression analysis to calculate a coefficient of influence. This method reveals that strong numerical associations, with correlations >0.5, exist between these small but distinct long term trends in the solar cycle and skin cancer. This improves modeling skin cancer trends on long time scales despite the stronger variation in other time scales and the destructive presence of noise. PMID:25126567

Thresholds of catastrophe in the Earth system

PubMed Central

Rothman, Daniel H.

2017-01-01

The history of the Earth system is a story of change. Some changes are gradual and benign, but others, especially those associated with catastrophic mass extinction, are relatively abrupt and destructive. What sets one group apart from the other? Here, I hypothesize that perturbations of Earth’s carbon cycle lead to mass extinction if they exceed either a critical rate at long time scales or a critical size at short time scales. By analyzing 31 carbon isotopic events during the past 542 million years, I identify the critical rate with a limit imposed by mass conservation. Identification of the crossover time scale separating fast from slow events then yields the critical size. The modern critical size for the marine carbon cycle is roughly similar to the mass of carbon that human activities will likely have added to the oceans by the year 2100. PMID:28948221

Order reduction for a model of marine bacteriophage evolution

NASA Astrophysics Data System (ADS)

Pagliarini, Silvia; Korobeinikov, Andrei

2017-02-01

A typical mechanistic model of viral evolution necessary includes several time scales which can differ by orders of magnitude. Such a diversity of time scales makes analysis of these models difficult. Reducing the order of a model is highly desirable when handling such a model. A typical approach applied to such slow-fast (or singularly perturbed) systems is the time scales separation technique. Constructing the so-called quasi-steady-state approximation is the usual first step in applying the technique. While this technique is commonly applied, in some cases its straightforward application can lead to unsatisfactory results. In this paper we construct the quasi-steady-state approximation for a model of evolution of marine bacteriophages based on the Beretta-Kuang model. We show that for this particular model the quasi-steady-state approximation is able to produce only qualitative but not quantitative fit.

Transition Manifolds of Complex Metastable Systems: Theory and Data-Driven Computation of Effective Dynamics.

PubMed

Bittracher, Andreas; Koltai, Péter; Klus, Stefan; Banisch, Ralf; Dellnitz, Michael; Schütte, Christof

2018-01-01

We consider complex dynamical systems showing metastable behavior, but no local separation of fast and slow time scales. The article raises the question of whether such systems exhibit a low-dimensional manifold supporting its effective dynamics. For answering this question, we aim at finding nonlinear coordinates, called reaction coordinates, such that the projection of the dynamics onto these coordinates preserves the dominant time scales of the dynamics. We show that, based on a specific reducibility property, the existence of good low-dimensional reaction coordinates preserving the dominant time scales is guaranteed. Based on this theoretical framework, we develop and test a novel numerical approach for computing good reaction coordinates. The proposed algorithmic approach is fully local and thus not prone to the curse of dimension with respect to the state space of the dynamics. Hence, it is a promising method for data-based model reduction of complex dynamical systems such as molecular dynamics.

Transition Manifolds of Complex Metastable Systems

NASA Astrophysics Data System (ADS)

Bittracher, Andreas; Koltai, Péter; Klus, Stefan; Banisch, Ralf; Dellnitz, Michael; Schütte, Christof

2018-04-01

We consider complex dynamical systems showing metastable behavior, but no local separation of fast and slow time scales. The article raises the question of whether such systems exhibit a low-dimensional manifold supporting its effective dynamics. For answering this question, we aim at finding nonlinear coordinates, called reaction coordinates, such that the projection of the dynamics onto these coordinates preserves the dominant time scales of the dynamics. We show that, based on a specific reducibility property, the existence of good low-dimensional reaction coordinates preserving the dominant time scales is guaranteed. Based on this theoretical framework, we develop and test a novel numerical approach for computing good reaction coordinates. The proposed algorithmic approach is fully local and thus not prone to the curse of dimension with respect to the state space of the dynamics. Hence, it is a promising method for data-based model reduction of complex dynamical systems such as molecular dynamics.

On the effects of surrogacy of energy dissipation in determining the intermittency exponent in fully developed turbulence

NASA Astrophysics Data System (ADS)

Cleve, J.; Greiner, M.; Sreenivasan, K. R.

2003-03-01

The two-point correlation function of the energy dissipation, obtained from a one-point time record of an atmospheric boundary layer, reveals a rigorous power law scaling with intermittency exponent μ approx 0.20 over almost the entire inertial range of scales. However, for the related integral moment, the power law scaling is restricted to the upper part of the inertial range only. This observation is explained in terms of the operational surrogacy of the construction of energy dissipation, which influences the behaviour of the correlation function for small separation distances.

Linking the influence and dependence of people on biodiversity across scales.

PubMed

Isbell, Forest; Gonzalez, Andrew; Loreau, Michel; Cowles, Jane; Díaz, Sandra; Hector, Andy; Mace, Georgina M; Wardle, David A; O'Connor, Mary I; Duffy, J Emmett; Turnbull, Lindsay A; Thompson, Patrick L; Larigauderie, Anne

2017-05-31

Biodiversity enhances many of nature's benefits to people, including the regulation of climate and the production of wood in forests, livestock forage in grasslands and fish in aquatic ecosystems. Yet people are now driving the sixth mass extinction event in Earth's history. Human dependence and influence on biodiversity have mainly been studied separately and at contrasting scales of space and time, but new multiscale knowledge is beginning to link these relationships. Biodiversity loss substantially diminishes several ecosystem services by altering ecosystem functioning and stability, especially at the large temporal and spatial scales that are most relevant for policy and conservation.

Reversing flow causes passive shark scale actuation in a separating turbulent boundary layer

NASA Astrophysics Data System (ADS)

Lang, Amy; Gemmell, Bradford; Motta, Phil; Habegger, Laura; Du Clos, Kevin; Devey, Sean; Stanley, Caleb; Santos, Leo

2017-11-01

Control of flow separation by shortfin mako skin in experiments has been demonstrated, but the mechanism is still poorly understood yet must be to some extent Re independent. The hypothesized mechanisms inherent in the shark skin for controlling flow separation are: (1) the scales, which are capable of being bristled only by reversing flow, inhibit flow reversal events from further development into larger-scale separation and (2) the cavities formed when scales bristle induces mixing of high momentum flow towards the wall thus energizing the flow close to the surface. Two studies were carried out to measure passive scale actuation caused by reversing flow. A small flow channel induced an unsteady, wake flow over the scales prompting reversing flow events and scale actuation. To resolve the flow and scale movements simultaneously we used specialized optics at high magnification (1 mm field of view) at 50,000 fps. In another study, 3D printed models of shark scales, or microflaps (bristling capability up to 50 degrees), were set into a flat plate. Using a tripped, turbulent boundary layer grown over the long flat plate and a localized adverse pressure gradient, a separation bubble was generated within which the microflaps were placed. Passive flow actuation of both shark scales and microflaps by reversing flow was observed. Funding from Army Research Office and NSF REU site Grant.

Catalyzed CO.sub.2-transport membrane on high surface area inorganic support

DOEpatents

Liu, Wei

2014-05-06

Disclosed are membranes and methods for making the same, which membranes provide improved permeability, stability, and cost-effective manufacturability, for separating CO.sub.2 from gas streams such as flue gas streams. High CO.sub.2 permeation flux is achieved by immobilizing an ultra-thin, optionally catalyzed fluid layer onto a meso-porous modification layer on a thin, porous inorganic substrate such as a porous metallic substrate. The CO.sub.2-selective liquid fluid blocks non-selective pores, and allows for selective absorption of CO.sub.2 from gas mixtures such as flue gas mixtures and subsequent transport to the permeation side of the membrane. Carbon dioxide permeance levels are in the order of 1.0.times.10.sup.-6 mol/(m.sup.2sPa) or better. Methods for making such membranes allow commercial scale membrane manufacturing at highly cost-effective rates when compared to conventional commercial-scale CO.sub.2 separation processes and equipment for the same and such membranes are operable on an industrial use scale.

Real-time powder diffraction studies of energy materials under non-equilibrium conditions

DOE Office of Scientific and Technical Information (OSTI.GOV)

Peterson, Vanessa K.; Auckett, Josie E.; Pang, Wei-Kong

Energy materials form the central part of energy devices. An essential part of their function is the ability to reversibly host charge or energy carriers, and analysis of their phase composition and structure in real time under non-equilibrium conditions is mandatory for a full understanding of their atomic-scale functional mechanism. Real-time powder diffraction is increasingly being applied for this purpose, forming a critical step in the strategic chemical engineering of materials with improved behaviour. This topical review gives examples of real-time analysis using powder diffraction of rechargeable battery electrodes and porous sorbent materials used for the separation and storage ofmore » energy-relevant gases to demonstrate advances in the insights which can be gained into their atomic-scale function.« less

Real-time powder diffraction studies of energy materials under non-equilibrium conditions

PubMed Central

Peterson, Vanessa K.; Auckett, Josie E.; Pang, Wei-Kong

2017-01-01

Energy materials form the central part of energy devices. An essential part of their function is the ability to reversibly host charge or energy carriers, and analysis of their phase composition and structure in real time under non-equilibrium conditions is mandatory for a full understanding of their atomic-scale functional mechanism. Real-time powder diffraction is increasingly being applied for this purpose, forming a critical step in the strategic chemical engineering of materials with improved behaviour. This topical review gives examples of real-time analysis using powder diffraction of rechargeable battery electrodes and porous sorbent materials used for the separation and storage of energy-relevant gases to demonstrate advances in the insights which can be gained into their atomic-scale function. PMID:28989711

Multiresolution forecasting for futures trading using wavelet decompositions.

PubMed

Zhang, B L; Coggins, R; Jabri, M A; Dersch, D; Flower, B

2001-01-01

We investigate the effectiveness of a financial time-series forecasting strategy which exploits the multiresolution property of the wavelet transform. A financial series is decomposed into an over complete, shift invariant scale-related representation. In transform space, each individual wavelet series is modeled by a separate multilayer perceptron (MLP). We apply the Bayesian method of automatic relevance determination to choose short past windows (short-term history) for the inputs to the MLPs at lower scales and long past windows (long-term history) at higher scales. To form the overall forecast, the individual forecasts are then recombined by the linear reconstruction property of the inverse transform with the chosen autocorrelation shell representation, or by another perceptron which learns the weight of each scale in the prediction of the original time series. The forecast results are then passed to a money management system to generate trades.

Development of pseudo-linear gradient elution for high-throughput resin selectivity screening in RoboColumn® Format.

PubMed

Kiesewetter, André; Menstell, Peter; Peeck, Lars H; Stein, Andreas

2016-11-01

Rapid development of chromatographic processes relies on effective high-throughput screening (HTS) methods. This article describes the development of pseudo-linear gradient elution for resin selectivity screening using RoboColumns ® . It gives guidelines for the implementation of this HTS method on a Tecan Freedom EVO ® robotic platform, addressing fundamental aspects of scale down and liquid handling. The creation of a flexible script for buffer preparation and column operation plus efficient data processing provided the basis for this work. Based on the concept of discretization, linear gradient elution was transformed into multistep gradients. The impact of column size, flow rate, multistep gradient design, and fractionation scheme on separation efficiency was systematically investigated, using a ternary model protein mixture. We identified key parameters and defined optimal settings for effective column performance. For proof of concept, we examined the selectivity of several cation exchange resins using various buffer conditions. The final protocol enabled a clear differentiation of resin selectivity on miniature chromatography column (MCC) scale. Distinct differences in separation behavior of individual resins and the influence of buffer conditions could be demonstrated. Results obtained with the robotic platform were representative and consistent with data generated on a conventional chromatography system. A study on antibody monomer/high molecular weight separation comparing MCC and lab scale under higher loading conditions provided evidence of the applicability of the miniaturized approach to practically relevant feedstocks with challenging separation tasks as well as of the predictive quality for larger scale. A comparison of varying degrees of robotic method complexity with corresponding effort (analysis time and labware consumption) and output quality highlights tradeoffs to select a method appropriate for a given separation challenge or analytical constraints. © 2016 American Institute of Chemical Engineers Biotechnol. Prog., 32:1503-1519, 2016. © 2016 American Institute of Chemical Engineers.

Probing Cold Dark Matter Substructure with Wide Binaries in Dwarf Spheroidal Galaxies

NASA Astrophysics Data System (ADS)

Chaname, Julio

2013-10-01

The mass function of dark matter {DM} halos is a central piece in the current framework of hierarchical structure formation. Although a wealth of information is available on the properties of DM halos with M>1e8 solar masses {Msun}, lower-mass halos remain virtually inaccessible. In particular, we do not know whether there is substructure on scales below dwarf spheroidal {dSph} galaxies, nor whether the DM power spectrum cuts off at some low-mass value. Here we propose an experiment that, using resolved binary systems as gravitational test particles, will probe these unexplored regimes for the first time. We will measure the stellar 2-point correlation function in 370 square arcmin of the Ursa Minor dSph down to separations of 40 mas, corresponding to 3000 AU. If there is no DM substructure on small scales, we will detect a 6-sigma excess due to "wide" binaries at the smallest separations. On the other hand, if DM substructure exists on scales of 1e4 Msun at even 10% of the level predicted by standard theory, then these binaries will have been destroyed and there will be no excess at small separations. Because the wide-binary separation function is identical in the Milky Way disk and halo {despite being radically different dynamical environments}, it is almost certain that dSphs were originally endowed with the same wide-binary distribution. Moreover, the interpretation of the resulting data is free from ambiguities, as there are no known mechanisms for destroying these binaries within dSph environments, other than DM subhalos. Thus this is, to the best of our knowledge, the only current experiment that could detect or rule out DM clustering on M=1e4 Msun scales.

Reversing flow development in a separating turbulent boundary layer

NASA Astrophysics Data System (ADS)

Santos, Leonardo; Lang, Amy; Wahidi, Redha; Bonacci, Andrew

2016-11-01

Fast swimming sharks have micro-structures on their skin consisting of bristling scales. These scales are hypothesized to bristle in response to backflow generated from the separated turbulent boundary layer (TBL) in regions of adverse pressure gradient (APG) on the shark body. Vortices are trapped in the cavities between the scales, which induce momentum exchange between the higher momentum fluid in the outer flow and that in the separated region. This momentum exchange causes reattachment of the separated TBL, causing the scales to return to the unbristled location, and the cycle continues. The rows of scales have widths that are comparable to the spanwise length scale of the intermittent backflow patches that appear in the region of incipient detachment of TBLs. In this experimental investigation, correlations between the shark scale's width and the spanwise size of the low backflow streaks are examined, as well as details of the incipient detachment region. The experiments are conducted in a water tunnel facility and the flow field is measured using PIV. Turbulent boundary layers are subjected to an APG via a rotating cylinder. Separated TBLs are investigated on a flat plate. The authors would like to greatfully acknowledge the Army Research Office for funding this project.

DOE Office of Scientific and Technical Information (OSTI.GOV)

Despotopulos, John D.; Kmak, Kelly N.; Gharibyan, Narek

Eichrom’s Pb resin, a crown-ether-based extraction chromatography resin, was characterized for separation of the flerovium (Fl) homologs, Pb and Sn. Batch uptake of Pb(II) and Sn(IV) radionuclides was determined from an HNO 3 matrix. Pb(II) was strongly retained on the resin at all HNO 3 concentrations, while Sn(IV) showed no uptake. Extraction kinetics for Pb(II) were examined and show suitable uptake on the second time scale. Here, separation methods for the isolation of individual homologs, Pb(II) and Sn(IV), have been established using 2 mL pre-packed vacuum flow Pb resin columns.

Mesoscale Models of Fluid Dynamics

NASA Astrophysics Data System (ADS)

Boghosian, Bruce M.; Hadjiconstantinou, Nicolas G.

During the last half century, enormous progress has been made in the field of computational materials modeling, to the extent that in many cases computational approaches are used in a predictive fashion. Despite this progress, modeling of general hydrodynamic behavior remains a challenging task. One of the main challenges stems from the fact that hydrodynamics manifests itself over a very wide range of length and time scales. On one end of the spectrum, one finds the fluid's "internal" scale characteristic of its molecular structure (in the absence of quantum effects, which we omit in this chapter). On the other end, the "outer" scale is set by the characteristic sizes of the problem's domain. The resulting scale separation or lack thereof as well as the existence of intermediate scales are key to determining the optimal approach. Successful treatments require a judicious choice of the level of description which is a delicate balancing act between the conflicting requirements of fidelity and manageable computational cost: a coarse description typically requires models for underlying processes occuring at smaller length and time scales; on the other hand, a fine-scale model will incur a significantly larger computational cost.

Method of producing exfoliated graphite, flexible graphite, and nano-scaled graphene platelets

DOEpatents

Zhamu, Aruna; Shi, Jinjun; Guo, Jiusheng; Jang, Bor Z.

2010-11-02

The present invention provides a method of exfoliating a layered material (e.g., graphite and graphite oxide) to produce nano-scaled platelets having a thickness smaller than 100 nm, typically smaller than 10 nm. The method comprises (a) dispersing particles of graphite, graphite oxide, or a non-graphite laminar compound in a liquid medium containing therein a surfactant or dispersing agent to obtain a stable suspension or slurry; and (b) exposing the suspension or slurry to ultrasonic waves at an energy level for a sufficient length of time to produce separated nano-scaled platelets. The nano-scaled platelets are candidate reinforcement fillers for polymer nanocomposites. Nano-scaled graphene platelets are much lower-cost alternatives to carbon nano-tubes or carbon nano-fibers.

Electrodynamical Model of Quasi-Efficient Financial Markets

NASA Astrophysics Data System (ADS)

Ilinski, Kirill N.; Stepanenko, Alexander S.

The modelling of financial markets presents a problem which is both theoretically challenging and practically important. The theoretical aspects concern the issue of market efficiency which may even have political implications [1], whilst the practical side of the problem has clear relevance to portfolio management [2] and derivative pricing [3]. Up till now all market models contain "smart money" traders and "noise" traders whose joint activity constitutes the market [4, 5]. On a short time scale this traditional separation does not seem to be realistic, and is hardly acceptable since all high-frequency market participants are professional traders and cannot be separated into "smart" and "noisy." In this paper we present a "microscopic" model with homogenuous quasi-rational behaviour of traders, aiming to describe short time market behaviour. To construct the model we use an analogy between "screening" in quantum electrodynamics and an equilibration process in a market with temporal mispricing [6, 7]. As a result, we obtain the time-dependent distribution function of the returns which is in quantitative agreement with real market data and obeys the anomalous scaling relations recently reported for both high-frequency exchange rates [8], S&P500 [9] and other stock market indices [10, 11].

Scale-Free Fluctuations in Behavioral Performance: Delineating Changes in Spontaneous Behavior of Humans with Induced Sleep Deficiency

PubMed Central

Beldzik, Ewa; Chialvo, Dante R.; Domagalik, Aleksandra; Fafrowicz, Magdalena; Gudowska-Nowak, Ewa; Marek, Tadeusz; Nowak, Maciej A.; Oginska, Halszka; Szwed, Jerzy

2014-01-01

The timing and dynamics of many diverse behaviors of mammals, e.g., patterns of animal foraging or human communication in social networks exhibit complex self-similar properties reproducible over multiple time scales. In this paper, we analyze spontaneous locomotor activity of healthy individuals recorded in two different conditions: during a week of regular sleep and a week of chronic partial sleep deprivation. After separating activity from rest with a pre-defined activity threshold, we have detected distinct statistical features of duration times of these two states. The cumulative distributions of activity periods follow a stretched exponential shape, and remain similar for both control and sleep deprived individuals. In contrast, rest periods, which follow power-law statistics over two orders of magnitude, have significantly distinct distributions for these two groups and the difference emerges already after the first night of shortened sleep. We have found steeper distributions for sleep deprived individuals, which indicates fewer long rest periods and more turbulent behavior. This separation of power-law exponents is the main result of our investigations, and might constitute an objective measure demonstrating the severity of sleep deprivation and the effects of sleep disorders. PMID:25222128

Lagrangian Statistics and Intermittency in Gulf of Mexico.

PubMed

Lin, Liru; Zhuang, Wei; Huang, Yongxiang

2017-12-12

Due to the nonlinear interaction between different flow patterns, for instance, ocean current, meso-scale eddies, waves, etc, the movement of ocean is extremely complex, where a multiscale statistics is then relevant. In this work, a high time-resolution velocity with a time step 15 minutes obtained by the Lagrangian drifter deployed in the Gulf of Mexico (GoM) from July 2012 to October 2012 is considered. The measured Lagrangian velocity correlation function shows a strong daily cycle due to the diurnal tidal cycle. The estimated Fourier power spectrum E(f) implies a dual-power-law behavior which is separated by the daily cycle. The corresponding scaling exponents are close to -1.75 and -2.75 respectively for the time scale larger (resp. 0.1 ≤ f ≤ 0.4 day -1 ) and smaller (resp. 2 ≤ f ≤ 8 day -1 ) than 1 day. A Hilbert-based approach is then applied to this data set to identify the possible multifractal property of the cascade process. The results show an intermittent dynamics for the time scale larger than 1 day, while a less intermittent dynamics for the time scale smaller than 1 day. It is speculated that the energy is partially injected via the diurnal tidal movement and then transferred to larger and small scales through a complex cascade process, which needs more studies in the near future.

The big brown bat's perceptual dimension of target range

NASA Astrophysics Data System (ADS)

Simmons, James A.

2005-09-01

Big brown bats determine the distance to targets from echo delay, but information actually is entered onto the bat's psychological delay scale from two sources. The first is the target-ranging system itself, from the time that elapses between single-spike neural responses evoked by the broadcast and similar responses evoked by echoes at different delays. These responses register the FM sweeps of broadcasts or echoes, and the associated system of neural delay lines and coincidence detectors cross correlates the spectrograms along the time axis. The second source is the echo spectrum, which relates to shape expressed as range profile. The target-ranging system extracts this by fanning out to encompass parallel representations of many possible notch frequencies and notch widths in echoes. Bats perceive delay separations of 5-30 μs and have a resolution limit of about 2 μs, but interference amplifies small delay separations by transposing them into large changes in notch frequency, so only perception of intervals smaller than 5 μs is surprising. Experiments with phase-shifted echoes show that the psychological time scale can represent two different delays originating entirely in the time domain when they are at least as close together as 10 μs. [Work supported by NIH and ONR.

Divided-evolution-based pulse scheme for quantifying exchange processes in proteins: powerful complement to relaxation dispersion experiments.

PubMed

Bouvignies, Guillaume; Hansen, D Flemming; Vallurupalli, Pramodh; Kay, Lewis E

2011-02-16

A method for quantifying millisecond time scale exchange in proteins is presented based on scaling the rate of chemical exchange using a 2D (15)N, (1)H(N) experiment in which (15)N dwell times are separated by short spin-echo pulse trains. Unlike the popular Carr-Purcell-Meiboom-Gill (CPMG) experiment where the effects of a radio frequency field on measured transverse relaxation rates are quantified, the new approach measures peak positions in spectra that shift as the effective exchange time regime is varied. The utility of the method is established through an analysis of data recorded on an exchanging protein-ligand system for which the exchange parameters have been accurately determined using alternative approaches. Computations establish that a combined analysis of CPMG and peak shift profiles extends the time scale that can be studied to include exchanging systems with highly skewed populations and exchange rates as slow as 20 s(-1).

Influence of particle size and shell thickness of core-shell packing materials on optimum experimental conditions in preparative chromatography.

PubMed

Horváth, Krisztián; Felinger, Attila

2015-08-14

The applicability of core-shell phases in preparative separations was studied by a modeling approach. The preparative separations were optimized for two compounds having bi-Langmuir isotherms. The differential mass balance equation of chromatography was solved by the Rouchon algorithm. The results show that as the size of the core increases, larger particles can be used in separations, resulting in higher applicable flow rates, shorter cycle times. Due to the decreasing volume of porous layer, the loadability of the column dropped significantly. As a result, the productivity and economy of the separation decreases. It is shown that if it is possible to optimize the size of stationary phase particles for the given separation task, the use of core-shell phases are not beneficial. The use of core-shell phases proved to be advantageous when the goal is to build preparative column for general purposes (e.g. for purification of different products) in small scale separations. Copyright © 2015 Elsevier B.V. All rights reserved.

Measurement of flow separation in a human vocal folds model

NASA Astrophysics Data System (ADS)

Šidlof, Petr; Doaré, Olivier; Cadot, Olivier; Chaigne, Antoine

2011-07-01

The paper provides experimental data on flow separation from a model of the human vocal folds. Data were measured on a four times scaled physical model, where one vocal fold was fixed and the other oscillated due to fluid-structure interaction. The vocal folds were fabricated from silicone rubber and placed on elastic support in the wall of a transparent wind tunnel. A PIV system was used to visualize the flow fields immediately downstream of the glottis and to measure the velocity fields. From the visualizations, the position of the flow separation point was evaluated using a semiautomatic procedure and plotted for different airflow velocities. The separation point position was quantified relative to the orifice width separately for the left and right vocal folds to account for flow asymmetry. The results indicate that the flow separation point remains close to the narrowest cross-section during most of the vocal fold vibration cycle, but moves significantly further downstream shortly prior to and after glottal closure.

The DSM‐5 Dimensional Anxiety Scales in a Dutch non‐clinical sample: psychometric properties including the adult separation anxiety disorder scale

PubMed Central

Bögels, Susan M.

2016-01-01

Abstract With DSM‐5, the American Psychiatric Association encourages complementing categorical diagnoses with dimensional severity ratings. We therefore examined the psychometric properties of the DSM‐5 Dimensional Anxiety Scales, a set of brief dimensional scales that are consistent in content and structure and assess DSM‐5‐based core features of anxiety disorders. Participants (285 males, 255 females) completed the DSM‐5 Dimensional Anxiety Scales for social anxiety disorder, generalized anxiety disorder, specific phobia, agoraphobia, and panic disorder that were included in previous studies on the scales, and also for separation anxiety disorder, which is included in the DSM‐5 chapter on anxiety disorders. Moreover, they completed the Screen for Child Anxiety Related Emotional Disorders Adult version (SCARED‐A). The DSM‐5 Dimensional Anxiety Scales demonstrated high internal consistency, and the scales correlated significantly and substantially with corresponding SCARED‐A subscales, supporting convergent validity. Separation anxiety appeared present among adults, supporting the DSM‐5 recognition of separation anxiety as an anxiety disorder across the life span. To conclude, the DSM‐5 Dimensional Anxiety Scales are a valuable tool to screen for specific adult anxiety disorders, including separation anxiety. Research in more diverse and clinical samples with anxiety disorders is needed. © 2016 The Authors International Journal of Methods in Psychiatric Research Published by John Wiley & Sons Ltd. PMID:27378317

Fast Human Detection for Intelligent Monitoring Using Surveillance Visible Sensors

PubMed Central

Ko, Byoung Chul; Jeong, Mira; Nam, JaeYeal

2014-01-01

Human detection using visible surveillance sensors is an important and challenging work for intruder detection and safety management. The biggest barrier of real-time human detection is the computational time required for dense image scaling and scanning windows extracted from an entire image. This paper proposes fast human detection by selecting optimal levels of image scale using each level's adaptive region-of-interest (ROI). To estimate the image-scaling level, we generate a Hough windows map (HWM) and select a few optimal image scales based on the strength of the HWM and the divide-and-conquer algorithm. Furthermore, adaptive ROIs are arranged per image scale to provide a different search area. We employ a cascade random forests classifier to separate candidate windows into human and nonhuman classes. The proposed algorithm has been successfully applied to real-world surveillance video sequences, and its detection accuracy and computational speed show a better performance than those of other related methods. PMID:25393782

Geomagnetic field and length-of-day fluctuations at decadal and subdecadal time scales. A plea for looking beyond the atmosphere for partners in Earth's rotation

NASA Astrophysics Data System (ADS)

Demetrescu, C.; Dobrica, V.; Stefan, C.

2017-12-01

A rich scientific literature is linking length-of-day (LOD) fluctuations to geomagnetic field and flow oscillations in the fluid outer core. We demostrate that the temporal evolution of the geomagnetic field shows the existence of several oscillations at decadal, inter-decadal, and sub-centennial time scales that superimpose on a so-called inter-centennial constituent. We show that while the subcentennial oscillations of the geomagnetic field, produced by torsional oscillations in the core, could be linked to oscillations of LOD at a similar time scale, the oscillations at decadal and sub-decadal time scales, of external origin, can be found in LOD too. We discuss these issues from the perspective of long time-span main field models (gufm1 - Jackson et al., 2000; COV-OBS - Gillet et al., 2013) that are used to retrieve time series of geomagnetic elements in a 2.5x2.5° network. The decadal and sub-decadal constituents of the time series of annual values in LOD and geomagnetic field were separated in the cyclic component of a Hodrick-Prescott filtering applied to data, and shown to highly correlate to variations of external sources such as the magnetospheric ring current.

Trend assessment: applications for hydrology and climate research

NASA Astrophysics Data System (ADS)

Kallache, M.; Rust, H. W.; Kropp, J.

2005-02-01

The assessment of trends in climatology and hydrology still is a matter of debate. Capturing typical properties of time series, like trends, is highly relevant for the discussion of potential impacts of global warming or flood occurrences. It provides indicators for the separation of anthropogenic signals and natural forcing factors by distinguishing between deterministic trends and stochastic variability. In this contribution river run-off data from gauges in Southern Germany are analysed regarding their trend behaviour by combining a deterministic trend component and a stochastic model part in a semi-parametric approach. In this way the trade-off between trend and autocorrelation structure can be considered explicitly. A test for a significant trend is introduced via three steps: First, a stochastic fractional ARIMA model, which is able to reproduce short-term as well as long-term correlations, is fitted to the empirical data. In a second step, wavelet analysis is used to separate the variability of small and large time-scales assuming that the trend component is part of the latter. Finally, a comparison of the overall variability to that restricted to small scales results in a test for a trend. The extraction of the large-scale behaviour by wavelet analysis provides a clue concerning the shape of the trend.

Vacuum energy density fluctuations in Minkowski and Casimir states via smeared quantum fields and point separation

NASA Astrophysics Data System (ADS)

Phillips, Nicholas G.; Hu, B. L.

2000-10-01

We present calculations of the variance of fluctuations and of the mean of the energy momentum tensor of a massless scalar field for the Minkowski and Casimir vacua as a function of an intrinsic scale defined by a smeared field or by point separation. We point out that, contrary to prior claims, the ratio of variance to mean-squared being of the order unity is not necessarily a good criterion for measuring the invalidity of semiclassical gravity. For the Casimir topology we obtain expressions for the variance to mean-squared ratio as a function of the intrinsic scale (defined by a smeared field) compared to the extrinsic scale (defined by the separation of the plates, or the periodicity of space). Our results make it possible to identify the spatial extent where negative energy density prevails which could be useful for studying quantum field effects in worm holes and baby universes, and for examining the design feasibility of real-life ``time machines.'' For the Minkowski vacuum we find that the ratio of the variance to the mean-squared, calculated from the coincidence limit, is identical to the value of the Casimir case at the same limit for spatial point separation while identical to the value of a hot flat space result with a temporal point separation. We analyze the origin of divergences in the fluctuations of the energy density and discuss choices in formulating a procedure for their removal, thus raising new questions about the uniqueness and even the very meaning of regularization of the energy momentum tensor for quantum fields in curved or even flat spacetimes when spacetime is viewed as having an extended structure.

Dancing to CHANGA: a self-consistent prediction for close SMBH pair formation time-scales following galaxy mergers

NASA Astrophysics Data System (ADS)

Tremmel, M.; Governato, F.; Volonteri, M.; Quinn, T. R.; Pontzen, A.

2018-04-01

We present the first self-consistent prediction for the distribution of formation time-scales for close supermassive black hole (SMBH) pairs following galaxy mergers. Using ROMULUS25, the first large-scale cosmological simulation to accurately track the orbital evolution of SMBHs within their host galaxies down to sub-kpc scales, we predict an average formation rate density of close SMBH pairs of 0.013 cMpc-3 Gyr-1. We find that it is relatively rare for galaxy mergers to result in the formation of close SMBH pairs with sub-kpc separation and those that do form are often the result of Gyr of orbital evolution following the galaxy merger. The likelihood and time-scale to form a close SMBH pair depends strongly on the mass ratio of the merging galaxies, as well as the presence of dense stellar cores. Low stellar mass ratio mergers with galaxies that lack a dense stellar core are more likely to become tidally disrupted and deposit their SMBH at large radii without any stellar core to aid in their orbital decay, resulting in a population of long-lived `wandering' SMBHs. Conversely, SMBHs in galaxies that remain embedded within a stellar core form close pairs in much shorter time-scales on average. This time-scale is a crucial, though often ignored or very simplified, ingredient to models predicting SMBH mergers rates and the connection between SMBH and star formation activity.

Casimir force in the Gödel space-time and its possible induced cosmological inhomogeneity

NASA Astrophysics Data System (ADS)

Khodabakhshi, Sh.; Shojai, A.

2017-07-01

The Casimir force between two parallel plates in the Gödel universe is computed for a scalar field at finite temperature. It is observed that when the plates' separation is comparable with the scale given by the rotation of the space-time, the force becomes repulsive and then approaches zero. Since it has been shown previously that the universe may experience a Gödel phase for a small period of time, the induced inhomogeneities from the Casimir force are also studied.

Preparative supercritical fluid chromatography: A powerful tool for chiral separations.

PubMed

Speybrouck, David; Lipka, Emmanuelle

2016-10-07

In 2012, the 4 biggest pharmaceutical blockbusters were pure enantiomers and separating racemic mixtures is now frequently a key step in the development of a new drug. For a long time, preparative liquid chromatography was the technique of choice for the separation of chiral compounds either during the drug discovery process to get up to a hundred grams of a pure enantiomer or during the clinical trial phases needing kilograms of material. However the advent of supercritical Fluid Chromatography (SFC) in the 1990s has changed things. Indeed, the use of carbon dioxide as the mobile phase in SFC offers many advantages including high flow rate, short equilibration time as well as low solvent consumption. Despite some initial teething troubles, SFC is becoming the primary method for preparative chiral chromatography. This article will cover recent developments in preparative SFC for the separation of enantiomers, reviewing several aspects such as instrumentation, chiral stationary phases, mobile phases or purely preparative considerations including overloading, productivity or large scale chromatography. Copyright © 2016 Elsevier B.V. All rights reserved.

Data series embedding and scale invariant statistics.

PubMed

Michieli, I; Medved, B; Ristov, S

2010-06-01

Data sequences acquired from bio-systems such as human gait data, heart rate interbeat data, or DNA sequences exhibit complex dynamics that is frequently described by a long-memory or power-law decay of autocorrelation function. One way of characterizing that dynamics is through scale invariant statistics or "fractal-like" behavior. For quantifying scale invariant parameters of physiological signals several methods have been proposed. Among them the most common are detrended fluctuation analysis, sample mean variance analyses, power spectral density analysis, R/S analysis, and recently in the realm of the multifractal approach, wavelet analysis. In this paper it is demonstrated that embedding the time series data in the high-dimensional pseudo-phase space reveals scale invariant statistics in the simple fashion. The procedure is applied on different stride interval data sets from human gait measurements time series (Physio-Bank data library). Results show that introduced mapping adequately separates long-memory from random behavior. Smaller gait data sets were analyzed and scale-free trends for limited scale intervals were successfully detected. The method was verified on artificially produced time series with known scaling behavior and with the varying content of noise. The possibility for the method to falsely detect long-range dependence in the artificially generated short range dependence series was investigated. (c) 2009 Elsevier B.V. All rights reserved.

Utilizing the dynamic stark shift as a probe for dielectric relaxation in photosynthetic reaction centers during charge separation.

PubMed

Guo, Zhi; Lin, Su; Woodbury, Neal W

2013-09-26

In photosynthetic reaction centers, the electric field generated by light-induced charge separation produces electrochromic shifts in the transitions of reaction center pigments. The extent of this Stark shift indirectly reflects the effective field strength at a particular cofactor in the complex. The dynamics of the effective field strength near the two monomeric bacteriochlorophylls (BA and BB) in purple photosynthetic bacterial reaction centers has been explored near physiological temperature by monitoring the time-dependent Stark shift during charge separation (dynamic Stark shift). This dynamic Stark shift was determined through analysis of femtosecond time-resolved absorbance change spectra recorded in wild type reaction centers and in four mutants at position M210. In both wild type and the mutants, the kinetics of the dynamic Stark shift differ from those of electron transfer, though not in the same way. In wild type, the initial electron transfer and the increase in the effective field strength near the active-side monomer bacteriochlorophyll (BA) occur in synchrony, but the two signals diverge on the time scale of electron transfer to the quinone. In contrast, when tyrosine is replaced by aspartic acid at M210, the kinetics of the BA Stark shift and the initial electron transfer differ, but transfer to the quinone coincides with the decay of the Stark shift. This is interpreted in terms of differences in the dynamics of the local dielectric environment between the mutants and the wild type. In wild type, comparison of the Stark shifts associated with BA and BB on the two quasi-symmetric halves of the reaction center structure confirm that the effective dielectric constants near these cofactors are quite different when the reaction center is in the state P(+)QA(-), as previously determined by Steffen et al. at 1.5 K (Steffen, M. A.; et al. Science 1994, 264, 810-816). However, it is not possible to determine from static, low-temperature measurments if the difference in the effective dielectric constant between the two sides of the reaction center is manifest on the time scale of initial electron transfer. By comparing directly the Stark shift dynamics of the ground-state spectra of the two monomer bacteriochlorophylls, it is evident that there is, in fact, a large dielectric difference between protein environments of the two quasi-symmetric electron-transfer branches on the time scale of initial electron transfer and that the effective dielectric constant in the region continues to evolve on a time scale of hundreds of picoseconds.

Introducing causality violation for improved DPOAE component unmixing

NASA Astrophysics Data System (ADS)

Moleti, Arturo; Sisto, Renata; Shera, Christopher A.

2018-05-01

The DPOAE response consists of the linear superposition of two components, a nonlinear distortion component generated in the overlap region, and a reflection component generated by roughness in the DP resonant region. Due to approximate scaling symmetry, the DPOAE distortion component has approximately constant phase. As the reflection component may be considered as a SFOAE generated by the forward DP traveling wave, it has rapidly rotating phase, relative to that of its source, which is also equal to the phase of the DPOAE distortion component. This different phase behavior permits effective separation of the DPOAE components (unmixing), using time-domain or time-frequency domain filtering. Departures from scaling symmetry imply fluctuations around zero delay of the distortion component, which may seriously jeopardize the accuracy of these filtering techniques. The differential phase-gradient delay of the reflection component obeys causality requirements, i.e., the delay is positive only, and the fine-structure oscillations of amplitude and phase are correlated to each other, as happens for TEOAEs and SFOAEs relative to their stimulus phase. Performing the inverse Fourier (or wavelet) transform of a modified DPOAE complex spectrum, in which a constant phase function is substituted for the measured one, the time (or time-frequency) distribution shows a peak at (exactly) zero delay and long-latency specular symmetric components, with a modified (positive and negative) delay, which is that relative to that of the distortion component in the original response. Component separation, applied to this symmetrized distribution, becomes insensitive to systematic errors associated with violation of the scaling symmetry in specific frequency ranges.

A review of induction and attachment times of wetting thin films between air bubbles and particles and its relevance in the separation of particles by flotation.

PubMed

Albijanic, Boris; Ozdemir, Orhan; Nguyen, Anh V; Bradshaw, Dee

2010-08-11

Bubble-particle attachment in water is critical to the separation of particles by flotation which is widely used in the recovery of valuable minerals, the deinking of wastepaper, the water treatment and the oil recovery from tar sands. It involves the thinning and rupture of wetting thin films, and the expansion and relaxation of the gas-liquid-solid contact lines. The time scale of the first two processes is referred to as the induction time, whereas the time scale of the attachment involving all the processes is called the attachment time. This paper reviews the experimental studies into the induction and attachment times between minerals and air bubbles, and between oil droplets and air bubbles. It also focuses on the experimental investigations and mathematical modelling of elementary processes of the wetting film thinning and rupture, and the three-phase contact line expansion relevant to flotation. It was confirmed that the time parameters, obtained by various authors, are sensitive enough to show changes in both flotation surface chemistry and physical properties of solid surfaces of pure minerals. These findings should be extended to other systems. It is proposed that measurements of the bubble-particle attachment can be used to interpret changes in flotation behaviour or, in conjunction with other factors, such as particle size and gas dispersion, to predict flotation performance. Copyright 2010 Elsevier B.V. All rights reserved.

Origin of Reversible Photoinduced Phase Separation in Hybrid Perovskites

NASA Astrophysics Data System (ADS)

Bischak, Connor G.; Hetherington, Craig L.; Wu, Hao; Aloni, Shaul; Ogletree, D. Frank; Limmer, David T.; Ginsberg, Naomi S.

2017-02-01

Nonequilibrium processes occurring in functional materials can significantly impact device efficiencies and are often difficult to characterize due to the broad range of length and time scales involved. In particular, mixed halide hybrid perovskites are promising for optoelectronics, yet the halides reversibly phase separate when photo-excited, significantly altering device performance. By combining nanoscale imaging and multiscale modeling, we elucidate the mechanism underlying this phenomenon, demonstrating that local strain induced by photo-generated polarons promotes halide phase separation and leads to nucleation of light-stabilized iodide-rich clusters. This effect relies on the unique electromechanical properties of hybrid materials, characteristic of neither their organic nor inorganic constituents alone. Exploiting photo-induced phase separation and other nonequilibrium phenomena in hybrid materials, generally, could enable new opportunities for expanding the functional applications in sensing, photoswitching, optical memory, and energy storage.

Large-scale dialysis of sample lipids

USGS Publications Warehouse

Meadows, Jill; Tillitt, Donald E.; Huckins, James; Schroeder, D.

1993-01-01

The use of a semipermeable membrane device (SPMD) for dialysis in an organic solvent phase is an efficient alternative approach to separation of contaminants from large amounts of lipid (up to 50 grams or more) prior to organic chemical analysis. Passive separation of contaminants can be accomplished with a minimum of equipment and a comparatively small volume of solvent. This study examines the effects of factors such as dialytic solvent, lipid type, dialytic solvent:lipid volume ratio, dialysis time, and temperature on the performance of polyethylene SPMDs during lipid-contaminant separations. The experimental conditions for maximal recoveries of organochlorine pesticides and polychlorinated biphenyls with minimal lipid carryover are determined for the examined variables. When the dialytic procedure is optimized, very satisfactory and highly reproducible analyte recoveries can be obtained in a few days while separating > 90% of the lipid material in a single operation.

Ultra-Long Time Dynamics of Contaminant Plume Mixing Induced by Transient Forcing Factors in Geologic Formations

NASA Astrophysics Data System (ADS)

Rajabi, F.; Battiato, I.

2016-12-01

Long term predictions of the impact of anthropogenic stressors on the environment is essential to reduce the risks associated with processes such as CO2 sequestration and nuclear waste storage in the subsurface. On the other hand, transient forcing factors (e.g. time-varying injection or pumping rate) with evolving heterogeneity of time scales spanning from days to years can influence transport phenomena at the pore scale. A comprehensive spatio-temporal prediction of reactive transport in porous media under time-dependent forcing factors for thousands of years requires the formulation of continuum scale models for time-averages. Yet, as every macroscopic model, time-averaged models can loose predictivity and accuracy when certain conditions are violated. This is true whenever lack of temporal and spatial scale separation occurs and it makes the continuum scale equation a poor assumption for the processes at the pore scale. In this work, we consider mass transport of a dissolved species undergoing a heterogeneous reaction and subject to time-varying boundary conditions in a periodic porous medium. By means of homogenization method and asymptotic expansion technique, we derive a macro-time continuum-scale equation as well as expressions for its effective properties. Our analysis demonstrates that the dynamics at the macro-scale is strongly influenced by the interplay between signal frequency at the boundary and transport processes at the pore level. In addition, we provide the conditions under which the space-time averaged equations accurately describe pore-scale processes. To validate our theoretical predictions, we consider a thin fracture with reacting walls and transient boundary conditions at the inlet. Our analysis shows a good agreement between numerical simulations and theoretical predictions. Furthermore, our numerical experiments show that mixing patterns of the contaminant plumes at the pore level strongly depend on the signal frequency.

Biointerface dynamics--Multi scale modeling considerations.

PubMed

Pajic-Lijakovic, Ivana; Levic, Steva; Nedovic, Viktor; Bugarski, Branko

2015-08-01

Irreversible nature of matrix structural changes around the immobilized cell aggregates caused by cell expansion is considered within the Ca-alginate microbeads. It is related to various effects: (1) cell-bulk surface effects (cell-polymer mechanical interactions) and cell surface-polymer surface effects (cell-polymer electrostatic interactions) at the bio-interface, (2) polymer-bulk volume effects (polymer-polymer mechanical and electrostatic interactions) within the perturbed boundary layers around the cell aggregates, (3) cumulative surface and volume effects within the parts of the microbead, and (4) macroscopic effects within the microbead as a whole based on multi scale modeling approaches. All modeling levels are discussed at two time scales i.e. long time scale (cell growth time) and short time scale (cell rearrangement time). Matrix structural changes results in the resistance stress generation which have the feedback impact on: (1) single and collective cell migrations, (2) cell deformation and orientation, (3) decrease of cell-to-cell separation distances, and (4) cell growth. Herein, an attempt is made to discuss and connect various multi scale modeling approaches on a range of time and space scales which have been proposed in the literature in order to shed further light to this complex course-consequence phenomenon which induces the anomalous nature of energy dissipation during the structural changes of cell aggregates and matrix quantified by the damping coefficients (the orders of the fractional derivatives). Deeper insight into the matrix partial disintegration within the boundary layers is useful for understanding and minimizing the polymer matrix resistance stress generation within the interface and on that base optimizing cell growth. Copyright © 2015 Elsevier B.V. All rights reserved.

Several vapor phase chemical treatments for dimensional stabilization of wood

Treesearch

H.M. Barnes; E.T. Choong; R.C. Mcllhenny

1969-01-01

A bench-scale system for the impregnation of wood with volatile compounds was constructed for the purpose of testing the system concept and evaluating various polymeric bulking materials as dimensional stabilizing agents. Provisions were incorporated for recycling the treating material, introduction of two separate materials alternately or simultaneously, timed-cycle...

Spectral variation during one quasi-periodic oscillation cycle in the black hole candidate H1743-322

NASA Astrophysics Data System (ADS)

Sarathi Pal, Partha; Debnath, Dipak; Chakrabarti, Sandip Kumar

2016-07-01

From the nature of energy dependence of the power density spectra, it is believed that the oscillation of the Compton cloud may be related to low frequency quasi-periodic oscillations (LFQPOs). In the context of two component advective flow (TCAF) solution, the centrifugal pressure supported boundary layer of a transonic flow acts as the Compton cloud. This region undergoes resonance oscillation when cooling time scale roughly agrees with infall time scale as matter crosses this region. By carefully separating photons emitted at different phases of a complete oscillation, we establish beyond reasonable doubt that such an oscillation is the cause of LFQPOs. We show that the degree of Comptonization and therefore the spectral properties of the flow oscillate systematically with the phase of LFQPOs. We analysis the properties of a 0.2Hz LFQPO exhibited by a black hole candidate H 1743-322 using the 3-80 keV data from NuSTAR satellite. This object was chosen because of availability of high quality data for a relatively low frequency oscillation, rendering easy phase-wise of separation of the light curve data.

A linear framework for time-scale separation in nonlinear biochemical systems.

PubMed

Gunawardena, Jeremy

2012-01-01

Cellular physiology is implemented by formidably complex biochemical systems with highly nonlinear dynamics, presenting a challenge for both experiment and theory. Time-scale separation has been one of the few theoretical methods for distilling general principles from such complexity. It has provided essential insights in areas such as enzyme kinetics, allosteric enzymes, G-protein coupled receptors, ion channels, gene regulation and post-translational modification. In each case, internal molecular complexity has been eliminated, leading to rational algebraic expressions among the remaining components. This has yielded familiar formulas such as those of Michaelis-Menten in enzyme kinetics, Monod-Wyman-Changeux in allostery and Ackers-Johnson-Shea in gene regulation. Here we show that these calculations are all instances of a single graph-theoretic framework. Despite the biochemical nonlinearity to which it is applied, this framework is entirely linear, yet requires no approximation. We show that elimination of internal complexity is feasible when the relevant graph is strongly connected. The framework provides a new methodology with the potential to subdue combinatorial explosion at the molecular level.

Boosting Bayesian parameter inference of nonlinear stochastic differential equation models by Hamiltonian scale separation.

PubMed

Albert, Carlo; Ulzega, Simone; Stoop, Ruedi

2016-04-01

Parameter inference is a fundamental problem in data-driven modeling. Given observed data that is believed to be a realization of some parameterized model, the aim is to find parameter values that are able to explain the observed data. In many situations, the dominant sources of uncertainty must be included into the model for making reliable predictions. This naturally leads to stochastic models. Stochastic models render parameter inference much harder, as the aim then is to find a distribution of likely parameter values. In Bayesian statistics, which is a consistent framework for data-driven learning, this so-called posterior distribution can be used to make probabilistic predictions. We propose a novel, exact, and very efficient approach for generating posterior parameter distributions for stochastic differential equation models calibrated to measured time series. The algorithm is inspired by reinterpreting the posterior distribution as a statistical mechanics partition function of an object akin to a polymer, where the measurements are mapped on heavier beads compared to those of the simulated data. To arrive at distribution samples, we employ a Hamiltonian Monte Carlo approach combined with a multiple time-scale integration. A separation of time scales naturally arises if either the number of measurement points or the number of simulation points becomes large. Furthermore, at least for one-dimensional problems, we can decouple the harmonic modes between measurement points and solve the fastest part of their dynamics analytically. Our approach is applicable to a wide range of inference problems and is highly parallelizable.

Scale-dependent temporal variations in stream water geochemistry.

PubMed

Nagorski, Sonia A; Moore, Iohnnie N; McKinnon, Temple E; Smith, David B

2003-03-01

A year-long study of four western Montana streams (two impacted by mining and two "pristine") evaluated surface water geochemical dynamics on various time scales (monthly, daily, and bi-hourly). Monthly changes were dominated by snowmelt and precipitation dynamics. On the daily scale, post-rain surges in some solute and particulate concentrations were similar to those of early spring runoff flushing characteristics on the monthly scale. On the bi-hourly scale, we observed diel (diurnal-nocturnal) cycling for pH, dissolved oxygen, water temperature, dissolved inorganic carbon, total suspended sediment, and some total recoverable metals at some or all sites. A comparison of the cumulative geochemical variability within each of the temporal groups reveals that for many water quality parameters there were large overlaps of concentration ranges among groups. We found that short-term (daily and bi-hourly) variations of some geochemical parameters covered large proportions of the variations found on a much longer term (monthly) time scale. These results show the importance of nesting short-term studies within long-term geochemical study designs to separate signals of environmental change from natural variability.

Scale-dependent temporal variations in stream water geochemistry

USGS Publications Warehouse

Nagorski, S.A.; Moore, J.N.; McKinnon, Temple E.; Smith, D.B.

2003-01-01

A year-long study of four western Montana streams (two impacted by mining and two "pristine") evaluated surface water geochemical dynamics on various time scales (monthly, daily, and bi-hourly). Monthly changes were dominated by snowmelt and precipitation dynamics. On the daily scale, post-rain surges in some solute and particulate concentrations were similar to those of early spring runoff flushing characteristics on the monthly scale. On the bi-hourly scale, we observed diel (diurnal-nocturnal) cycling for pH, dissolved oxygen, water temperature, dissolved inorganic carbon, total suspended sediment, and some total recoverable metals at some or all sites. A comparison of the cumulative geochemical variability within each of the temporal groups reveals that for many water quality parameters there were large overlaps of concentration ranges among groups. We found that short-term (daily and bi-hourly) variations of some geochemical parameters covered large proportions of the variations found on a much longer term (monthly) time scale. These results show the importance of nesting short-term studies within long-term geochemical study designs to separate signals of environmental change from natural variability.

Stochastic modeling of experimental chaotic time series.

PubMed

Stemler, Thomas; Werner, Johannes P; Benner, Hartmut; Just, Wolfram

2007-01-26

Methods developed recently to obtain stochastic models of low-dimensional chaotic systems are tested in electronic circuit experiments. We demonstrate that reliable drift and diffusion coefficients can be obtained even when no excessive time scale separation occurs. Crisis induced intermittent motion can be described in terms of a stochastic model showing tunneling which is dominated by state space dependent diffusion. Analytical solutions of the corresponding Fokker-Planck equation are in excellent agreement with experimental data.

On the Measurement of Ecological Novelty: Scale-Eating Pupfish Are Separated by 168 my from Other Scale-Eating Fishes

PubMed Central

Martin, Christopher H.; Wainwright, Peter C.

2013-01-01

The colonization of new adaptive zones is widely recognized as one of the hallmarks of adaptive radiation. However, the adoption of novel resources during this process is rarely distinguished from phenotypic change because morphology is a common proxy for ecology. How can we quantify ecological novelty independent of phenotype? Our study is split into two parts: we first document a remarkable example of ecological novelty, scale-eating (lepidophagy), within a rapidly-evolving adaptive radiation of Cyprinodon pupfishes on San Salvador Island, Bahamas. This specialized predatory niche is known in several other fish groups, but is not found elsewhere among the 1,500 species of atherinomorphs. Second, we quantify this ecological novelty by measuring the time-calibrated phylogenetic distance in years to the most closely-related species with convergent ecology. We find that scale-eating pupfish are separated by 168 million years of evolution from the nearest scale-eating fish. We apply this approach to a variety of examples and highlight the frequent decoupling of ecological novelty from phenotypic divergence. We observe that novel ecology is not always tightly correlated with rates of phenotypic or species diversification, particularly within recent adaptive radiations, necessitating the use of additional measures of ecological novelty independent of phenotype. PMID:23976994

Multi-time resolution analysis of speech: evidence from psychophysics

PubMed Central

Chait, Maria; Greenberg, Steven; Arai, Takayuki; Simon, Jonathan Z.; Poeppel, David

2015-01-01

How speech signals are analyzed and represented remains a foundational challenge both for cognitive science and neuroscience. A growing body of research, employing various behavioral and neurobiological experimental techniques, now points to the perceptual relevance of both phoneme-sized (10–40 Hz modulation frequency) and syllable-sized (2–10 Hz modulation frequency) units in speech processing. However, it is not clear how information associated with such different time scales interacts in a manner relevant for speech perception. We report behavioral experiments on speech intelligibility employing a stimulus that allows us to investigate how distinct temporal modulations in speech are treated separately and whether they are combined. We created sentences in which the slow (~4 Hz; Slow) and rapid (~33 Hz; Shigh) modulations—corresponding to ~250 and ~30 ms, the average duration of syllables and certain phonetic properties, respectively—were selectively extracted. Although Slow and Shigh have low intelligibility when presented separately, dichotic presentation of Shigh with Slow results in supra-additive performance, suggesting a synergistic relationship between low- and high-modulation frequencies. A second experiment desynchronized presentation of the Slow and Shigh signals. Desynchronizing signals relative to one another had no impact on intelligibility when delays were less than ~45 ms. Longer delays resulted in a steep intelligibility decline, providing further evidence of integration or binding of information within restricted temporal windows. Our data suggest that human speech perception uses multi-time resolution processing. Signals are concurrently analyzed on at least two separate time scales, the intermediate representations of these analyses are integrated, and the resulting bound percept has significant consequences for speech intelligibility—a view compatible with recent insights from neuroscience implicating multi-timescale auditory processing. PMID:26136650

Speed of Improvement in Symptoms of Depression With Desvenlafaxine 50 mg and 100 mg Compared With Placebo in Patients With Major Depressive Disorder.

PubMed

Katzman, Martin A; Nierenberg, Andrew A; Wajsbrot, Dalia B; Meier, Ellen; Prieto, Rita; Pappadopulos, Elizabeth; Mackell, Joan; Boucher, Matthieu

2017-10-01

This post hoc analysis examined the time point at which clinically significant improvement in major depressive disorder (MDD) symptoms occurs with desvenlafaxine versus placebo. Data were pooled from 9 short-term, double-blind, placebo-controlled studies in adults with MDD randomly assigned to desvenlafaxine 50 mg/d, 100 mg/d, or placebo. A mixed-effects model for repeated-measures analysis of change from baseline score was used to determine the time point at which desvenlafaxine treatment groups separated from placebo on the 17-item Hamilton Rating Scale for Depression and psychosocial outcomes. The association between early improvement and week 8 outcomes was examined using logistic regression analyses. Time to remission for patients with early improvement versus without early improvement was assessed using Kaplan-Meier techniques. Comparisons between groups were performed with log-rank tests. In the intent-to-treat population (N = 4279 patients: desvenlafaxine 50 mg/d, n = 1714; desvenlafaxine 100 mg/d, n = 870; placebo, n = 1695), a statistically significant improvement on the 17-item Hamilton Rating Scale for Depression was observed with desvenlafaxine 50 mg/d at week 1 (P = 0.0129) and with desvenlafaxine 100 mg/d at week 2 (P = 0.0002) versus placebo. Early improvement was a significant predictor of later remission. Treatment assignment, baseline depression scale scores, and race were significantly associated with probability of early improvement. On several measures of depressive symptoms and function, desvenlafaxine 50 mg/d and 100 mg/d separated from placebo as early as week 1 and no later than week 4 in patients with MDD. These findings suggest that clinicians may be able to use depression rating scale scores early in treatment as a guide to inform treatment optimization.

Linking the influence and dependence of people on biodiversity across scales

PubMed Central

Isbell, Forest; Gonzalez, Andrew; Loreau, Michel; Cowles, Jane; Díaz, Sandra; Hector, Andy; Mace, Georgina M.; Wardle, David A.; O’Connor, Mary I.; Duffy, J. Emmett; Turnbull, Lindsay A.; Thompson, Patrick L.; Larigauderie, Anne

2017-01-01

Biodiversity enhances many of nature’s benefits to people, including the regulation of climate and the production of wood in forests, livestock forage in grasslands and fish in aquatic ecosystems. Yet people are now driving the sixth mass extinction event in Earth’s history. Human dependence and influence on biodiversity have mainly been studied separately and at contrasting scales of space and time, but new multiscale knowledge is beginning to link these relationships. Biodiversity loss substantially diminishes several ecosystem services by altering ecosystem functioning and stability, especially at the large temporal and spatial scales that are most relevant for policy and conservation. PMID:28569811

The DSM-5 Dimensional Anxiety Scales in a Dutch non-clinical sample: psychometric properties including the adult separation anxiety disorder scale.

PubMed

Möller, Eline L; Bögels, Susan M

2016-09-01

With DSM-5, the American Psychiatric Association encourages complementing categorical diagnoses with dimensional severity ratings. We therefore examined the psychometric properties of the DSM-5 Dimensional Anxiety Scales, a set of brief dimensional scales that are consistent in content and structure and assess DSM-5-based core features of anxiety disorders. Participants (285 males, 255 females) completed the DSM-5 Dimensional Anxiety Scales for social anxiety disorder, generalized anxiety disorder, specific phobia, agoraphobia, and panic disorder that were included in previous studies on the scales, and also for separation anxiety disorder, which is included in the DSM-5 chapter on anxiety disorders. Moreover, they completed the Screen for Child Anxiety Related Emotional Disorders Adult version (SCARED-A). The DSM-5 Dimensional Anxiety Scales demonstrated high internal consistency, and the scales correlated significantly and substantially with corresponding SCARED-A subscales, supporting convergent validity. Separation anxiety appeared present among adults, supporting the DSM-5 recognition of separation anxiety as an anxiety disorder across the life span. To conclude, the DSM-5 Dimensional Anxiety Scales are a valuable tool to screen for specific adult anxiety disorders, including separation anxiety. Research in more diverse and clinical samples with anxiety disorders is needed. © 2016 The Authors International Journal of Methods in Psychiatric Research Published by John Wiley & Sons Ltd. © 2016 The Authors International Journal of Methods in Psychiatric Research Published by John Wiley & Sons Ltd.

Simultaneous determination of radionuclides separable into natural decay series by use of time-interval analysis.

PubMed

Hashimoto, Tetsuo; Sanada, Yukihisa; Uezu, Yasuhiro

2004-05-01

A delayed coincidence method, time-interval analysis (TIA), has been applied to successive alpha- alpha decay events on the millisecond time-scale. Such decay events are part of the (220)Rn-->(216)Po ( T(1/2) 145 ms) (Th-series) and (219)Rn-->(215)Po ( T(1/2) 1.78 ms) (Ac-series). By using TIA in addition to measurement of (226)Ra (U-series) from alpha-spectrometry by liquid scintillation counting (LSC), two natural decay series could be identified and separated. The TIA detection efficiency was improved by using the pulse-shape discrimination technique (PSD) to reject beta-pulses, by solvent extraction of Ra combined with simple chemical separation, and by purging the scintillation solution with dry N(2) gas. The U- and Th-series together with the Ac-series were determined, respectively, from alpha spectra and TIA carried out immediately after Ra-extraction. Using the (221)Fr-->(217)At ( T(1/2) 32.3 ms) decay process as a tracer, overall yields were estimated from application of TIA to the (225)Ra (Np-decay series) at the time of maximum growth. The present method has proven useful for simultaneous determination of three radioactive decay series in environmental samples.

Hierarchical coarse-graining model for photosystem II including electron and excitation-energy transfer processes.

PubMed

Matsuoka, Takeshi; Tanaka, Shigenori; Ebina, Kuniyoshi

2014-03-01

We propose a hierarchical reduction scheme to cope with coupled rate equations that describe the dynamics of multi-time-scale photosynthetic reactions. To numerically solve nonlinear dynamical equations containing a wide temporal range of rate constants, we first study a prototypical three-variable model. Using a separation of the time scale of rate constants combined with identified slow variables as (quasi-)conserved quantities in the fast process, we achieve a coarse-graining of the dynamical equations reduced to those at a slower time scale. By iteratively employing this reduction method, the coarse-graining of broadly multi-scale dynamical equations can be performed in a hierarchical manner. We then apply this scheme to the reaction dynamics analysis of a simplified model for an illuminated photosystem II, which involves many processes of electron and excitation-energy transfers with a wide range of rate constants. We thus confirm a good agreement between the coarse-grained and fully (finely) integrated results for the population dynamics. Copyright © 2014 Elsevier Ireland Ltd. All rights reserved.

DOE Office of Scientific and Technical Information (OSTI.GOV)

Collins, William D; Johansen, Hans; Evans, Katherine J

We present a survey of physical and computational techniques that have the potential to con- tribute to the next generation of high-fidelity, multi-scale climate simulations. Examples of the climate science problems that can be investigated with more depth include the capture of remote forcings of localized hydrological extreme events, an accurate representation of cloud features over a range of spatial and temporal scales, and parallel, large ensembles of simulations to more effectively explore model sensitivities and uncertainties. Numerical techniques, such as adaptive mesh refinement, implicit time integration, and separate treatment of fast physical time scales are enabling improved accuracy andmore » fidelity in simulation of dynamics and allow more complete representations of climate features at the global scale. At the same time, part- nerships with computer science teams have focused on taking advantage of evolving computer architectures, such as many-core processors and GPUs, so that these approaches which were previously considered prohibitively costly have become both more efficient and scalable. In combination, progress in these three critical areas is poised to transform climate modeling in the coming decades.« less

Paleobiology, community ecology, and scales of ecological pattern.

PubMed

Jablonski, D; Sepkoski, J J

1996-07-01

The fossil record provides a wealth of data on the role of regional processes and historical events in shaping biological communities over a variety of time scales. The Quaternary record with its evidence of repeated climatic change shows that both terrestrial and marine species shifted independently rather than as cohesive assemblages over scales of thousands of years. Larger scale patterns also show a strong individualistic component to taxon dynamics; assemblage stability, when it occurs, is difficult to separate from shared responses to low rates of environmental change. Nevertheless, the fossil record does suggest that some biotic interactions influence large-scale ecological and evolutionary patterns, albeit in more diffuse and protracted fashions than those generally studied by community ecologists. These include: (1) the resistance by incumbents to the establishment of new or invading taxa, with episodes of explosive diversification often appearing contingent on the removal of incumbents at extinction events; (2) steady states of within-habitat and global diversity at longer time scales (10(7)-l0(8) yr), despite enormous turnover of taxa; and (3) morphological and biogeographic responses to increased intensities of predation and substratum disturbance over similarly long time scales. The behavior of species and communities over the array of temporal and spatial scales in the fossil record takes on additional significance for framing conservation strategies, and for understanding recovery of species, lineages, and communities from environmental changes.

Paleobiology, community ecology, and scales of ecological pattern

NASA Technical Reports Server (NTRS)

Jablonski, D.; Sepkoski, J. J. Jr; Sepkoski JJ, J. r. (Principal Investigator)

1996-01-01

The fossil record provides a wealth of data on the role of regional processes and historical events in shaping biological communities over a variety of time scales. The Quaternary record with its evidence of repeated climatic change shows that both terrestrial and marine species shifted independently rather than as cohesive assemblages over scales of thousands of years. Larger scale patterns also show a strong individualistic component to taxon dynamics; assemblage stability, when it occurs, is difficult to separate from shared responses to low rates of environmental change. Nevertheless, the fossil record does suggest that some biotic interactions influence large-scale ecological and evolutionary patterns, albeit in more diffuse and protracted fashions than those generally studied by community ecologists. These include: (1) the resistance by incumbents to the establishment of new or invading taxa, with episodes of explosive diversification often appearing contingent on the removal of incumbents at extinction events; (2) steady states of within-habitat and global diversity at longer time scales (10(7)-l0(8) yr), despite enormous turnover of taxa; and (3) morphological and biogeographic responses to increased intensities of predation and substratum disturbance over similarly long time scales. The behavior of species and communities over the array of temporal and spatial scales in the fossil record takes on additional significance for framing conservation strategies, and for understanding recovery of species, lineages, and communities from environmental changes.

Space Technology 5 Multipoint Observations of Temporal and Spatial Variability of Field-Aligned Currents

NASA Technical Reports Server (NTRS)

Le, G.; Wang, Y.; Slavin, J. A.; Strangeway, R. L.

2009-01-01

Space Technology 5 (ST5) is a constellation mission consisting of three microsatellites. It provides the first multipoint magnetic field measurements in low Earth orbit, which enables us to separate spatial and temporal variations. In this paper, we present a study of the temporal variability of field-aligned currents using the ST5 data. We examine the field-aligned current observations during and after a geomagnetic storm and compare the magnetic field profiles at the three spacecraft. The multipoint data demonstrate that mesoscale current structures, commonly embedded within large-scale current sheets, are very dynamic with highly variable current density and/or polarity in approx.10 min time scales. On the other hand, the data also show that the time scales for the currents to be relatively stable are approx.1 min for mesoscale currents and approx.10 min for large-scale currents. These temporal features are very likely associated with dynamic variations of their charge carriers (mainly electrons) as they respond to the variations of the parallel electric field in auroral acceleration region. The characteristic time scales for the temporal variability of mesoscale field-aligned currents are found to be consistent with those of auroral parallel electric field.

Extraordinary phase separation and segregation in vent fluids from the southern East Pacific Rise

USGS Publications Warehouse

Von Damm, Karen L.; Lilley, M.D.; Shanks, Wayne C.; Brockington, M.; Bray, A.M.; O'Grady, K. M.; Olson, E.; Graham, A.; Proskurowski, G.

2003-01-01

The discovery of Brandon vent on the southern East Pacific Rise is providing new insights into the controls on midocean ridge hydrothermal vent fluid chemistry. The physical conditions at the time ofsampling (287 bar and 405??C) place the Brandon fluids very close to the critical point of seawater (298 bar and 407??C). This permits in situ study of the effects of near criticalphenomena, which are interpreted to be the primary cause of enhanced transition metal transport in these fluids. Of the five orifices on Brandon sampled, three were venting fluids with less than seawater chlorinity, and two were venting fluids with greater than seawater chlorinity. The liquid phase orifices contain 1.6-1.9 times the chloride content of the vapors. Most other elements, excluding the gases, have this same ratio demonstrating the conservative nature of phase separation and the lack of subsequent water-rock interaction. The vapor and liquid phases vent at the same time from orifices within meters of each other on the Brandon structure. Variations in fluid compositions occur on a time scale of minutes. Our interpretation is that phase separation and segregation must be occurring 'real time' within the sulfide structure itself. Fluids from Brandon therefore provide an unique opportunity to understand in situ phase separation without the overprinting of continued water-rock interaction with the oceanic crust, as well as critical phenomena. ?? 2002 Elsevier Science B.V. All rights reserved.

Phase Transitions and Scaling in Systems Far from Equilibrium

NASA Astrophysics Data System (ADS)

Täuber, Uwe C.

2017-03-01

Scaling ideas and renormalization group approaches proved crucial for a deep understanding and classification of critical phenomena in thermal equilibrium. Over the past decades, these powerful conceptual and mathematical tools were extended to continuous phase transitions separating distinct nonequilibrium stationary states in driven classical and quantum systems. In concordance with detailed numerical simulations and laboratory experiments, several prominent dynamical universality classes have emerged that govern large-scale, long-time scaling properties both near and far from thermal equilibrium. These pertain to genuine specific critical points as well as entire parameter space regions for steady states that display generic scale invariance. The exploration of nonstationary relaxation properties and associated physical aging scaling constitutes a complementary potent means to characterize cooperative dynamics in complex out-of-equilibrium systems. This review describes dynamic scaling features through paradigmatic examples that include near-equilibrium critical dynamics, driven lattice gases and growing interfaces, correlation-dominated reaction-diffusion systems, and basic epidemic models.

SHI induced nano track polymer filters and characterization

NASA Astrophysics Data System (ADS)

Vijay, Y. K.

2009-07-01

Swift heavy ion irradiation produces damage in polymers in the form of latent tracks. Latent tracks can be enlarged by etching it in a suitable etchant and thus nuclear track etch membrane can be formed for gas permeation / purification in particular for hydrogen where the molecular size is very small. By applying suitable and controlled etching conditions well defined tracks can be formed for specific applications of the membranes. After etching gas permeation method is used for characterizing the tracks. In the present work polycarbonate (PC) of various thickness were irradiated with energetic ion beam at Inter University Accelerator Centre (IUAC), New Delhi. Nuclear tracks were modified by etching the PC in 6N NaOH at 60 (±1) °C from both sides for different times to produce track etch membranes. At critical etch time the etched pits from both the sides meet a rapid increase in gas permeation was observed. Permeability of hydrogen and carbon dioxide has been measured in samples etched for different times. The latent tracks produced by SHI irradiation in the track etch membranes show enhancement of free volume of the polymer. Nano filters are separation devices for the mixture of gases, different ions in the solution and isotopes and isobars separations. The polymer thin films with controlled porosity finding it self as best choice. However, the permeability and selectivity of these polymer based membrane filters are very important at the nano scale separation. The Swift Heavy Ion (SHI) induced nuclear track etched polymeric films with controlled etching have been attempted and characterized as nano scale filters.

Computations of Internal and External Axisymmetric Nozzle Aerodynamics at Transonic Speeds

NASA Technical Reports Server (NTRS)

Dalbello, Teryn; Georgiadis, Nicholas; Yoder, Dennis; Keith, Theo

2003-01-01

Computational Fluid Dynamics (CFD) analyses of axisymmetric circular-arc boattail nozzles have been completed in support of NASA's Next Generation Launch Technology Program to investigate the effects of high-speed nozzle geometries on the nozzle internal flow and the surrounding boattail regions. These computations span the very difficult transonic flight regime, with shock-induced separations and strong adverse pressure gradients. External afterbody and internal nozzle pressure distributions computed with the Wind code are compared with experimental data. A range of turbulence models were examined in Wind, including an Explicit Algebraic Stress model (EASM). Computations on two nozzle geometries have been completed at freestream Mach numbers ranging from 0.6 to 0.9, driven by nozzle pressure ratios (NPR) ranging from 2.9 to 5. Results obtained on converging-only geometry indicate reasonable agreement to experimental data, with the EASM and Shear Stress Transport (SST) turbulence models providing the best agreement. Calculations completed on a converging-diverging geometry involving large-scale internal flow separation did not converge to a true steady-state solution when run with variable timestepping (steady-state). Calculations obtained using constant timestepping (time-accurate) indicate less variations in flow properties compared with steady-state solutions. This failure to converge to a steady-state solution was found to be the result of difficulties in using variable time-stepping with large-scale separations present in the flow. Nevertheless, time-averaged boattail surface pressure coefficient and internal nozzle pressures show fairly good agreement with experimental data. The SST turbulence model demonstrates the best over-all agreement with experimental data.

Airphoto assessment of changes in aquatic vegetation

NASA Technical Reports Server (NTRS)

Markham, B. L.; Philipson, W. R.; Russel, A. E.

1977-01-01

Large scale, multiyear, color and color infrared aerial photographs were used to evaluate changes in aquatic vegetation that have accompanied a reduction in phosphorus inputs to a phosphorus-limited, eutrophic lake in New York State. The study showed that the distribution of emergent, floating and submersed vegetation could be determined with little or no concurrent ground data; that various emergent and floating types could be separated and, with limited field checks, identified; and that different submersed types are generally not separable. Major vegetative types are characterized by spectral and nonspectral features, and a classification is developed for compiling time-sequential vegetation maps.

Using Wavelet Bases to Separate Scales in Quantum Field Theory

NASA Astrophysics Data System (ADS)

Michlin, Tracie L.

This thesis investigates the use of Daubechies wavelets to separate scales in local quantum field theory. Field theories have an infinite number of degrees of freedom on all distance scales. Quantum field theories are believed to describe the physics of subatomic particles. These theories have no known mathematically convergent approximation methods. Daubechies wavelet bases can be used separate degrees of freedom on different distance scales. Volume and resolution truncations lead to mathematically well-defined truncated theories that can be treated using established methods. This work demonstrates that flow equation methods can be used to block diagonalize truncated field theoretic Hamiltonians by scale. This eliminates the fine scale degrees of freedom. This may lead to approximation methods and provide an understanding of how to formulate well-defined fine resolution limits.

A real-time multi-scale 2D Gaussian filter based on FPGA

NASA Astrophysics Data System (ADS)

Luo, Haibo; Gai, Xingqin; Chang, Zheng; Hui, Bin

2014-11-01

Multi-scale 2-D Gaussian filter has been widely used in feature extraction (e.g. SIFT, edge etc.), image segmentation, image enhancement, image noise removing, multi-scale shape description etc. However, their computational complexity remains an issue for real-time image processing systems. Aimed at this problem, we propose a framework of multi-scale 2-D Gaussian filter based on FPGA in this paper. Firstly, a full-hardware architecture based on parallel pipeline was designed to achieve high throughput rate. Secondly, in order to save some multiplier, the 2-D convolution is separated into two 1-D convolutions. Thirdly, a dedicate first in first out memory named as CAFIFO (Column Addressing FIFO) was designed to avoid the error propagating induced by spark on clock. Finally, a shared memory framework was designed to reduce memory costs. As a demonstration, we realized a 3 scales 2-D Gaussian filter on a single ALTERA Cyclone III FPGA chip. Experimental results show that, the proposed framework can computing a Multi-scales 2-D Gaussian filtering within one pixel clock period, is further suitable for real-time image processing. Moreover, the main principle can be popularized to the other operators based on convolution, such as Gabor filter, Sobel operator and so on.

Magnetophoresis of iron oxide nanoparticles at low field gradient: the role of shape anisotropy.

PubMed

Lim, Jitkang; Yeap, Swee Pin; Leow, Chee Hoe; Toh, Pey Yi; Low, Siew Chun

2014-05-01

Magnetophoresis of iron oxide magnetic nanoparticle (IOMNP) under low magnetic field gradient (<100 T/m) is significantly enhanced by particle shape anisotropy. This unique feature of magnetophoresis is influenced by the particle concentration and applied magnetic field gradient. By comparing the nanosphere and nanorod magnetophoresis at different concentration, we revealed the ability for these two species of particles to achieve the same separation rate by adjusting the field gradient. Under cooperative magnetophoresis, the nanorods would first go through self- and magnetic field induced aggregation followed by the alignment of the particle clusters formed with magnetic field. Time scale associated to these two processes is investigated to understand the kinetic behavior of nanorod separation under low field gradient. Surface functionalization of nanoparticles can be employed as an effective strategy to vary the temporal evolution of these two aggregation processes which subsequently influence the magnetophoretic separation time and rate. Copyright © 2014 Elsevier Inc. All rights reserved.

3D ion-scale dynamics of BBFs and their associated emissions in Earth's magnetotail using 3D hybrid simulations and MMS multi-spacecraft observations

NASA Astrophysics Data System (ADS)

Breuillard, H.; Aunai, N.; Le Contel, O.; Catapano, F.; Alexandrova, A.; Retino, A.; Cozzani, G.; Gershman, D. J.; Giles, B. L.; Khotyaintsev, Y. V.; Lindqvist, P. A.; Ergun, R.; Strangeway, R. J.; Russell, C. T.; Magnes, W.; Plaschke, F.; Nakamura, R.; Fuselier, S. A.; Turner, D. L.; Schwartz, S. J.; Torbert, R. B.; Burch, J.

2017-12-01

Transient and localized jets of hot plasma, also known as Bursty Bulk Flows (BBFs), play a crucial role in Earth's magnetotail dynamics because the energy input from the solar wind is partly dissipated in their vicinity, notably in their embedded dipolarization front (DF). This dissipation is in the form of strong low-frequency waves that can heat and accelerate energetic particles up to the high-latitude plasma sheet. The ion-scale dynamics of BBFs have been revealed by the Cluster and THEMIS multi-spacecraft missions. However, the dynamics of BBF propagation in the magnetotail are still under debate due to instrumental limitations and spacecraft separation distances, as well as simulation limitations. The NASA/MMS fleet, which features unprecedented high time resolution instruments and four spacecraft separated by kinetic-scale distances, has also shown recently that the DF normal dynamics and its associated emissions are below the ion gyroradius scale in this region. Large variations in the dawn-dusk direction were also observed. However, most of large-scale simulations are using the MHD approach and are assumed 2D in the XZ plane. Thus, in this study we take advantage of both multi-spacecraft observations by MMS and large-scale 3D hybrid simulations to investigate the 3D dynamics of BBFs and their associated emissions at ion-scale in Earth's magnetotail, and their impact on particle heating and acceleration.

Combining Quick-Turnaround and Batch Workloads at Scale

NASA Technical Reports Server (NTRS)

Matthews, Gregory A.

2012-01-01

NAS uses PBS Professional to schedule and manage the workload on Pleiades, an 11,000+ node 1B cluster. At this scale the user experience for quick-turnaround jobs can degrade, which led NAS initially to set up two separate PBS servers, each dedicated to a particular workload. Recently we have employed PBS hooks and scheduler modifications to merge these workloads together under one PBS server, delivering sub-1-minute start times for the quick-turnaround workload, and enabling dynamic management of the resources set aside for that workload.

The design of disengaging mechanism of radix pseudostellariae and soil

NASA Astrophysics Data System (ADS)

Xiao, Shungen; Song, Mengmeng; Chen, Chanwei

2017-12-01

With the continuous development of the scale of the cultivation of the radix pseudostellariae, the traditional separation mode cannot adapt to the mass production of the crown prince, and the existing manual separation mode is of great labor intensity and low degree of mechanization. Therefore, it is necessary to design a disengaging mechanism of radix pseudostellariae and soil on the basis of the design principle of modern agricultural machinery. According to the physical characteristics and growing environment of radix pseudostellariae, a drum-type separating component is presented, and the drum screen separating mechanism and vibration mechanism of the disengaging mechanism are designed. In this paper, the movement rule and time of the mixture of radix pseudostellariae and soil are determined in the drum screen. Rotation speed of the drum screen is calculated, and the operation rules of the eccentric wheel in the vibration mechanism are summarized.

Hierarchically structured photonic crystals for integrated chemical separation and colorimetric detection.

PubMed

Fu, Qianqian; Zhu, Biting; Ge, Jianping

2017-02-16

A SiO 2 colloidal photonic crystal film with a hierarchical porous structure is fabricated to demonstrate an integrated separation and colorimetric detection of chemical species for the first time. This new photonic crystal based thin layer chromatography process requires no dyeing, developing and UV irradiation compared to the traditional TLC. The assembling of mesoporous SiO 2 particles via a supersaturation-induced-precipitation process forms uniform and hierarchical photonic crystals with micron-scale cracks and mesopores, which accelerate the diffusion of developers and intensify the adsorption/desorption between the analytes and silica for efficient separation. Meanwhile, the chemical substances infiltrated to the voids of photonic crystals cause an increase of the refractive index and a large contrast of structural colors towards the unloaded part, so that the sample spots can be directly recognized with the naked eye before and after separation.

Acoustic streaming: an arbitrary Lagrangian-Eulerian perspective.

PubMed

Nama, Nitesh; Huang, Tony Jun; Costanzo, Francesco

2017-08-25

We analyse acoustic streaming flows using an arbitrary Lagrangian Eulerian (ALE) perspective. The formulation stems from an explicit separation of time scales resulting in two subproblems: a first-order problem, formulated in terms of the fluid displacement at the fast scale, and a second-order problem, formulated in terms of the Lagrangian flow velocity at the slow time scale. Following a rigorous time-averaging procedure, the second-order problem is shown to be intrinsically steady, and with exact boundary conditions at the oscillating walls. Also, as the second-order problem is solved directly for the Lagrangian velocity, the formulation does not need to employ the notion of Stokes drift, or any associated post-processing, thus facilitating a direct comparison with experiments. Because the first-order problem is formulated in terms of the displacement field, our formulation is directly applicable to more complex fluid-structure interaction problems in microacoustofluidic devices. After the formulation's exposition, we present numerical results that illustrate the advantages of the formulation with respect to current approaches.

Acoustic streaming: an arbitrary Lagrangian–Eulerian perspective

PubMed Central

Nama, Nitesh; Huang, Tony Jun; Costanzo, Francesco

2017-01-01

We analyse acoustic streaming flows using an arbitrary Lagrangian Eulerian (ALE) perspective. The formulation stems from an explicit separation of time scales resulting in two subproblems: a first-order problem, formulated in terms of the fluid displacement at the fast scale, and a second-order problem, formulated in terms of the Lagrangian flow velocity at the slow time scale. Following a rigorous time-averaging procedure, the second-order problem is shown to be intrinsically steady, and with exact boundary conditions at the oscillating walls. Also, as the second-order problem is solved directly for the Lagrangian velocity, the formulation does not need to employ the notion of Stokes drift, or any associated post-processing, thus facilitating a direct comparison with experiments. Because the first-order problem is formulated in terms of the displacement field, our formulation is directly applicable to more complex fluid–structure interaction problems in microacoustofluidic devices. After the formulation’s exposition, we present numerical results that illustrate the advantages of the formulation with respect to current approaches. PMID:29051631

Particle separation by phase modulated surface acoustic waves.

PubMed

Simon, Gergely; Andrade, Marco A B; Reboud, Julien; Marques-Hueso, Jose; Desmulliez, Marc P Y; Cooper, Jonathan M; Riehle, Mathis O; Bernassau, Anne L

2017-09-01

High efficiency isolation of cells or particles from a heterogeneous mixture is a critical processing step in lab-on-a-chip devices. Acoustic techniques offer contactless and label-free manipulation, preserve viability of biological cells, and provide versatility as the applied electrical signal can be adapted to various scenarios. Conventional acoustic separation methods use time-of-flight and achieve separation up to distances of quarter wavelength with limited separation power due to slow gradients in the force. The method proposed here allows separation by half of the wavelength and can be extended by repeating the modulation pattern and can ensure maximum force acting on the particles. In this work, we propose an optimised phase modulation scheme for particle separation in a surface acoustic wave microfluidic device. An expression for the acoustic radiation force arising from the interaction between acoustic waves in the fluid was derived. We demonstrated, for the first time, that the expression of the acoustic radiation force differs in surface acoustic wave and bulk devices, due to the presence of a geometric scaling factor. Two phase modulation schemes are investigated theoretically and experimentally. Theoretical findings were experimentally validated for different mixtures of polystyrene particles confirming that the method offers high selectivity. A Monte-Carlo simulation enabled us to assess performance in real situations, including the effects of particle size variation and non-uniform acoustic field on sorting efficiency and purity, validating the ability to separate particles with high purity and high resolution.

Geometrical Patterning of Super-Hydrophobic Biosensing Transistors Enables Space and Time Resolved Analysis of Biological Mixtures.

PubMed

Gentile, Francesco; Ferrara, Lorenzo; Villani, Marco; Bettelli, Manuele; Iannotta, Salvatore; Zappettini, Andrea; Cesarelli, Mario; Di Fabrizio, Enzo; Coppedè, Nicola

2016-01-12

PSS is a conductive polymer that can be integrated into last generation Organic Electrochemical Transistor (OECT) devices for biological inspection, identification and analysis. While a variety of reports in literature demonstrated the chemical and biological sensitivity of these devices, still their ability in resolving complex mixtures remains controversial. Similar OECT devices display good time dynamics behavior but lack spatial resolution. In this work, we integrated PSS with patterns of super-hydrophobic pillars in which a finite number of those pillars is independently controlled for site-selective measurement of a solution. We obtained a multifunctional, hierarchical OECT device that bridges the micro- to the nano-scales for specific, combined time and space resolved analysis of the sample. Due to super-hydrophobic surface properties, the biological species in the drop are driven by convection, diffusion, and the externally applied electric field: the balance/unbalance between these forces will cause the molecules to be transported differently within its volume depending on particle size thus realizing a size-selective separation. Within this framework, the separation and identification of two different molecules, namely Cetyl Trimethyl Ammonium Bromid (CTAB) and adrenaline, in a biological mixture have been demonstrated, showing that geometrical control at the micro-nano scale impart unprecedented selectivity to the devices.

Geometrical Patterning of Super-Hydrophobic Biosensing Transistors Enables Space and Time Resolved Analysis of Biological Mixtures

PubMed Central

Gentile, Francesco; Ferrara, Lorenzo; Villani, Marco; Bettelli, Manuele; Iannotta, Salvatore; Zappettini, Andrea; Cesarelli, Mario; Di Fabrizio, Enzo; Coppedè, Nicola

2016-01-01

PEDOT:PSS is a conductive polymer that can be integrated into last generation Organic Electrochemical Transistor (OECT) devices for biological inspection, identification and analysis. While a variety of reports in literature demonstrated the chemical and biological sensitivity of these devices, still their ability in resolving complex mixtures remains controversial. Similar OECT devices display good time dynamics behavior but lack spatial resolution. In this work, we integrated PEDOT:PSS with patterns of super-hydrophobic pillars in which a finite number of those pillars is independently controlled for site-selective measurement of a solution. We obtained a multifunctional, hierarchical OECT device that bridges the micro- to the nano-scales for specific, combined time and space resolved analysis of the sample. Due to super-hydrophobic surface properties, the biological species in the drop are driven by convection, diffusion, and the externally applied electric field: the balance/unbalance between these forces will cause the molecules to be transported differently within its volume depending on particle size thus realizing a size-selective separation. Within this framework, the separation and identification of two different molecules, namely Cetyl Trimethyl Ammonium Bromid (CTAB) and adrenaline, in a biological mixture have been demonstrated, showing that geometrical control at the micro-nano scale impart unprecedented selectivity to the devices. PMID:26753611

Diffusion in an expanding medium: Fokker-Planck equation, Green's function, and first-passage properties

NASA Astrophysics Data System (ADS)

Yuste, S. B.; Abad, E.; Escudero, C.

2016-09-01

We present a classical, mesoscopic derivation of the Fokker-Planck equation for diffusion in an expanding medium. To this end, we take a conveniently generalized Chapman-Kolmogorov equation as the starting point. We obtain an analytical expression for the Green's function (propagator) and investigate both analytically and numerically how this function and the associated moments behave. We also study first-passage properties in expanding hyperspherical geometries. We show that in all cases the behavior is determined to a great extent by the so-called Brownian conformal time τ (t ) , which we define via the relation τ ˙=1 /a2 , where a (t ) is the expansion scale factor. If the medium expansion is driven by a power law [a (t ) ∝tγ with γ >0 ] , then we find interesting crossover effects in the mixing effectiveness of the diffusion process when the characteristic exponent γ is varied. Crossover effects are also found at the level of the survival probability and of the moments of the first passage-time distribution with two different regimes separated by the critical value γ =1 /2 . The case of an exponential scale factor is analyzed separately both for expanding and contracting media. In the latter situation, a stationary probability distribution arises in the long-time limit.

Geometrical Patterning of Super-Hydrophobic Biosensing Transistors Enables Space and Time Resolved Analysis of Biological Mixtures

NASA Astrophysics Data System (ADS)

Gentile, Francesco; Ferrara, Lorenzo; Villani, Marco; Bettelli, Manuele; Iannotta, Salvatore; Zappettini, Andrea; Cesarelli, Mario; di Fabrizio, Enzo; Coppedè, Nicola

2016-01-01

PEDOT:PSS is a conductive polymer that can be integrated into last generation Organic Electrochemical Transistor (OECT) devices for biological inspection, identification and analysis. While a variety of reports in literature demonstrated the chemical and biological sensitivity of these devices, still their ability in resolving complex mixtures remains controversial. Similar OECT devices display good time dynamics behavior but lack spatial resolution. In this work, we integrated PEDOT:PSS with patterns of super-hydrophobic pillars in which a finite number of those pillars is independently controlled for site-selective measurement of a solution. We obtained a multifunctional, hierarchical OECT device that bridges the micro- to the nano-scales for specific, combined time and space resolved analysis of the sample. Due to super-hydrophobic surface properties, the biological species in the drop are driven by convection, diffusion, and the externally applied electric field: the balance/unbalance between these forces will cause the molecules to be transported differently within its volume depending on particle size thus realizing a size-selective separation. Within this framework, the separation and identification of two different molecules, namely Cetyl Trimethyl Ammonium Bromid (CTAB) and adrenaline, in a biological mixture have been demonstrated, showing that geometrical control at the micro-nano scale impart unprecedented selectivity to the devices.

Thermalization and light cones in a model with weak integrability breaking

DOE PAGES

Bertini, Bruno; Essler, Fabian H. L.; Groha, Stefan; ...

2016-12-09

Here, we employ equation-of-motion techniques to study the nonequilibrium dynamics in a lattice model of weakly interacting spinless fermions. Our model provides a simple setting for analyzing the effects of weak integrability-breaking perturbations on the time evolution after a quantum quench. We establish the accuracy of the method by comparing results at short and intermediate times to time-dependent density matrix renormalization group computations. For sufficiently weak integrability-breaking interactions we always observe prethermalization plateaus, where local observables relax to nonthermal values at intermediate time scales. At later times a crossover towards thermal behavior sets in. We determine the associated time scale,more » which depends on the initial state, the band structure of the noninteracting theory, and the strength of the integrability-breaking perturbation. Our method allows us to analyze in some detail the spreading of correlations and in particular the structure of the associated light cones in our model. We find that the interior and exterior of the light cone are separated by an intermediate region, the temporal width of which appears to scale with a universal power law t 1/3.« less

Environment-induced decoherence II. Effect of decoherence on Bell's inequality for an EPR pair

NASA Astrophysics Data System (ADS)

Venugopalan, A.; Kumar, Deepak; Ghosh, R.

1995-02-01

According to Bell's theorem, the degree of correlation between spatially separated measurements on a quantum system is limited by certain inequalities if one assumes the condition of locality. Quantum mechanics predicts that this limit can be exceeded, making it nonlocal. We analyse the effect of an environment modelled by a fluctuating magnetic field on the quantum correlations in an EPR singlet as seen in the Bell inequality. We show that in an EPR setup, the system goes from the usual ‘violation’ of Bell's inequality to a ‘non-violation’ for times larger than a characteristic time scale which is related to the parameters of the fluctuating field. We also look at these inequalities as a function of the spatial separation between the EPR pair.

Dynamic stall reattachment revisited

NASA Astrophysics Data System (ADS)

Mulleners, Karen

2017-11-01

Dynamic stall on pitching airfoils is an important practical problem that affects for example rotary wing aircraft and wind turbines. It also comprises a number of interesting fundamental fluid dynamical phenomena such as unsteady flow separation, vortex formation and shedding, unsteady flow reattachment, and dynamic hysteresis. Following up on past efforts focussing on the separation development, we now revisited the flow reattachment or stall recovery process. Experimental time-resolved velocity field and surface pressure data for a two-dimensional sinusoidally pitching airfoil with various reduced frequencies was analysed using different Eulerian, Lagrangian, and modal decomposition methods. This complementary analysis resulted in the identification of the chain of events that play a role in the flow reattachment process, a detailed description of that role, and characterisation of the individual events by the governing time-scales and flow features.

Intrinsic vs. spurious long-range memory in high-frequency records of environmental radioactivity. Critical re-assessment and application to indoor 222Rn concentrations from Coimbra, Portugal

NASA Astrophysics Data System (ADS)

Donner, R. V.; Potirakis, S. M.; Barbosa, S. M.; Matos, J. A. O.; Pereira, A. J. S. C.; Neves, L. J. P. F.

2015-05-01

The presence or absence of long-range correlations in the environmental radioactivity fluctuations has recently attracted considerable interest. Among a multiplicity of practically relevant applications, identifying and disentangling the environmental factors controlling the variable concentrations of the radioactive noble gas radon is important for estimating its effect on human health and the efficiency of possible measures for reducing the corresponding exposition. In this work, we present a critical re-assessment of a multiplicity of complementary methods that have been previously applied for evaluating the presence of long-range correlations and fractal scaling in environmental radon variations with a particular focus on the specific properties of the underlying time series. As an illustrative case study, we subsequently re-analyze two high-frequency records of indoor radon concentrations from Coimbra, Portugal, each of which spans several weeks of continuous measurements at a high temporal resolution of five minutes.Our results reveal that at the study site, radon concentrations exhibit complex multi-scale dynamics with qualitatively different properties at different time-scales: (i) essentially white noise in the high-frequency part (up to time-scales of about one hour), (ii) spurious indications of a non-stationary, apparently long-range correlated process (at time scales between some hours and one day) arising from marked periodic components, and (iii) low-frequency variability indicating a true long-range dependent process. In the presence of such multi-scale variability, common estimators of long-range memory in time series are prone to fail if applied to the raw data without previous separation of time-scales with qualitatively different dynamics.

The stability and change of etiological influences on depression, anxiety symptoms and their co-occurrence across adolescence and young adulthood.

PubMed

Waszczuk, M A; Zavos, H M S; Gregory, A M; Eley, T C

2016-01-01

Depression and anxiety persist within and across diagnostic boundaries. The manner in which common v. disorder-specific genetic and environmental influences operate across development to maintain internalizing disorders and their co-morbidity is unclear. This paper investigates the stability and change of etiological influences on depression, panic, generalized, separation and social anxiety symptoms, and their co-occurrence, across adolescence and young adulthood. A total of 2619 twins/siblings prospectively reported symptoms of depression and anxiety at mean ages 15, 17 and 20 years. Each symptom scale showed a similar pattern of moderate continuity across development, largely underpinned by genetic stability. New genetic influences contributing to change in the developmental course of the symptoms emerged at each time point. All symptom scales correlated moderately with one another over time. Genetic influences, both stable and time-specific, overlapped considerably between the scales. Non-shared environmental influences were largely time- and symptom-specific, but some contributed moderately to the stability of depression and anxiety symptom scales. These stable, longitudinal environmental influences were highly correlated between the symptoms. The results highlight both stable and dynamic etiology of depression and anxiety symptom scales. They provide preliminary evidence that stable as well as newly emerging genes contribute to the co-morbidity between depression and anxiety across adolescence and young adulthood. Conversely, environmental influences are largely time-specific and contribute to change in symptoms over time. The results inform molecular genetics research and transdiagnostic treatment and prevention approaches.

Large-Scale Atmospheric Teleconnection Patterns Associated with the Interannual Variability of Heatwaves in East Asia and Its Decadal Changes

NASA Astrophysics Data System (ADS)

Choi, N.; Lee, M. I.; Lim, Y. K.; Kim, K. M.

2017-12-01

Heatwave is an extreme hot weather event which accompanies fatal damage to human health. The heatwave has a strong relationship with the large-scale atmospheric teleconnection patterns. In this study, we examine the spatial pattern of heatwave in East Asia by using the EOF analysis and the relationship between heatwave frequency and large-scale atmospheric teleconnection patterns. We also separate the time scale of heatwave frequency as the time scale longer than a decade and the interannual time scale. The long-term variation of heatwave frequency in East Asia shows a linkage with the sea surface temperature (SST) variability over the North Atlantic with a decadal time scale (a.k.a. the Atlantic Multidecadal Oscillation; AMO). On the other hands, the interannual variation of heatwave frequency is linked with the two dominant spatial patterns associated with the large-scale teleconnection patterns mimicking the Scandinavian teleconnection (SCAND-like) pattern and the circumglobal teleconnection (CGT-like) pattern, respectively. It is highlighted that the interannual variation of heatwave frequency in East Asia shows a remarkable change after mid-1990s. While the heatwave frequency was mainly associated with the CGT-like pattern before mid-1990s, the SCAND-like pattern becomes the most dominant one after mid-1990s, making the CGT-like pattern as the second. This study implies that the large-scale atmospheric teleconnection patterns play a key role in developing heatwave events in East Asia. This study further discusses possible mechanisms for the decadal change in the linkage between heatwave frequency and the large-scale teleconnection patterns in East Asia such as early melting of snow cover and/or weakening of East Asian jet stream due to global warming.

Origin of Reversible Photoinduced Phase Separation in Hybrid Perovskites.

PubMed

Bischak, Connor G; Hetherington, Craig L; Wu, Hao; Aloni, Shaul; Ogletree, D Frank; Limmer, David T; Ginsberg, Naomi S

2017-02-08

The distinct physical properties of hybrid organic-inorganic materials can lead to unexpected nonequilibrium phenomena that are difficult to characterize due to the broad range of length and time scales involved. For instance, mixed halide hybrid perovskites are promising materials for optoelectronics, yet bulk measurements suggest the halides reversibly phase separate upon photoexcitation. By combining nanoscale imaging and multiscale modeling, we find that the nature of halide demixing in these materials is distinct from macroscopic phase separation. We propose that the localized strain induced by a single photoexcited charge interacting with the soft, ionic lattice is sufficient to promote halide phase separation and nucleate a light-stabilized, low-bandgap, ∼8 nm iodide-rich cluster. The limited extent of this polaron is essential to promote demixing because by contrast bulk strain would simply be relaxed. Photoinduced phase separation is therefore a consequence of the unique electromechanical properties of this hybrid class of materials. Exploiting photoinduced phase separation and other nonequilibrium phenomena in hybrid materials more generally could expand applications in sensing, switching, memory, and energy storage.

STOCHASTIC OPTICS: A SCATTERING MITIGATION FRAMEWORK FOR RADIO INTERFEROMETRIC IMAGING

DOE Office of Scientific and Technical Information (OSTI.GOV)

Johnson, Michael D., E-mail: mjohnson@cfa.harvard.edu

2016-12-10

Just as turbulence in the Earth’s atmosphere can severely limit the angular resolution of optical telescopes, turbulence in the ionized interstellar medium fundamentally limits the resolution of radio telescopes. We present a scattering mitigation framework for radio imaging with very long baseline interferometry (VLBI) that partially overcomes this limitation. Our framework, “stochastic optics,” derives from a simplification of strong interstellar scattering to separate small-scale (“diffractive”) effects from large-scale (“refractive”) effects, thereby separating deterministic and random contributions to the scattering. Stochastic optics extends traditional synthesis imaging by simultaneously reconstructing an unscattered image and its refractive perturbations. Its advantages over direct imagingmore » come from utilizing the many deterministic properties of the scattering—such as the time-averaged “blurring,” polarization independence, and the deterministic evolution in frequency and time—while still accounting for the stochastic image distortions on large scales. These distortions are identified in the image reconstructions through regularization by their time-averaged power spectrum. Using synthetic data, we show that this framework effectively removes the blurring from diffractive scattering while reducing the spurious image features from refractive scattering. Stochastic optics can provide significant improvements over existing scattering mitigation strategies and is especially promising for imaging the Galactic Center supermassive black hole, Sagittarius A*, with the Global mm-VLBI Array and with the Event Horizon Telescope.« less

Spin-diffusions and diffusive molecular dynamics

NASA Astrophysics Data System (ADS)

Farmer, Brittan; Luskin, Mitchell; Plecháč, Petr; Simpson, Gideon

2017-12-01

Metastable configurations in condensed matter typically fluctuate about local energy minima at the femtosecond time scale before transitioning between local minima after nanoseconds or microseconds. This vast scale separation limits the applicability of classical molecular dynamics (MD) methods and has spurned the development of a host of approximate algorithms. One recently proposed method is diffusive MD which aims at integrating a system of ordinary differential equations describing the likelihood of occupancy by one of two species, in the case of a binary alloy, while quasistatically evolving the locations of the atoms. While diffusive MD has shown itself to be efficient and provide agreement with observations, it is fundamentally a model, with unclear connections to classical MD. In this work, we formulate a spin-diffusion stochastic process and show how it can be connected to diffusive MD. The spin-diffusion model couples a classical overdamped Langevin equation to a kinetic Monte Carlo model for exchange amongst the species of a binary alloy. Under suitable assumptions and approximations, spin-diffusion can be shown to lead to diffusive MD type models. The key assumptions and approximations include a well-defined time scale separation, a choice of spin-exchange rates, a low temperature approximation, and a mean field type approximation. We derive several models from different assumptions and show their relationship to diffusive MD. Differences and similarities amongst the models are explored in a simple test problem.

Scale separation for multi-scale modeling of free-surface and two-phase flows with the conservative sharp interface method

DOE Office of Scientific and Technical Information (OSTI.GOV)

Han, L.H., E-mail: Luhui.Han@tum.de; Hu, X.Y., E-mail: Xiangyu.Hu@tum.de; Adams, N.A., E-mail: Nikolaus.Adams@tum.de

In this paper we present a scale separation approach for multi-scale modeling of free-surface and two-phase flows with complex interface evolution. By performing a stimulus-response operation on the level-set function representing the interface, separation of resolvable and non-resolvable interface scales is achieved efficiently. Uniform positive and negative shifts of the level-set function are used to determine non-resolvable interface structures. Non-resolved interface structures are separated from the resolved ones and can be treated by a mixing model or a Lagrangian-particle model in order to preserve mass. Resolved interface structures are treated by the conservative sharp-interface model. Since the proposed scale separationmore » approach does not rely on topological information, unlike in previous work, it can be implemented in a straightforward fashion into a given level set based interface model. A number of two- and three-dimensional numerical tests demonstrate that the proposed method is able to cope with complex interface variations accurately and significantly increases robustness against underresolved interface structures.« less

The Dynamics of Controlled Flow Separation within a Diverter Duct Diffuser

NASA Astrophysics Data System (ADS)

Peterson, C. J.; Vukasinovic, B.; Glezer, A.

2016-11-01

The evolution and receptivity to fluidic actuation of the flow separation within a rectangular, constant-width, diffuser that is branched off of a primary channel is investigated experimentally at speeds up to M = 0.4. The coupling between the diffuser's adverse pressure gradient and the internal separation that constricts nearly half of the flow passage through the duct is controlled using a spanwise array of fluidic actuators on the surface upstream of the diffuser's inlet plane. The dynamics of the separating surface vorticity layer in the absence and presence of actuation are investigated using high-speed particle image velocimetry combined with surface pressure measurements and total pressure distributions at the primary channel's exit plane. It is shown that the actuation significantly alters the incipient dynamics of the separating vorticity layer as the characteristic cross stream scales of the boundary layer upstream of separation and of the ensuing vorticity concentrations within the separated flow increase progressively with actuation level. It is argued that the dissipative (high frequency) actuation alters the balance between large- and small-scale motions near separation by intensifying the large-scale motions and limiting the small-scale dynamics. Controlling separation within the diffuser duct also has a profound effect on the global flow. In the presence of actuation, the mass flow rate in the primary duct increases 10% while the fraction of the diverted mass flow rate in the diffuser increases by more than 45% at 0.7% actuation mass fraction. Supported by the Boeing Company.

Decoupling processes and scales of shoreline morphodynamics

USGS Publications Warehouse

Hapke, Cheryl J.; Plant, Nathaniel G.; Henderson, Rachel E.; Schwab, William C.; Nelson, Timothy R.

2016-01-01

Behavior of coastal systems on time scales ranging from single storm events to years and decades is controlled by both small-scale sediment transport processes and large-scale geologic, oceanographic, and morphologic processes. Improved understanding of coastal behavior at multiple time scales is required for refining models that predict potential erosion hazards and for coastal management planning and decision-making. Here we investigate the primary controls on shoreline response along a geologically-variable barrier island on time scales resolving extreme storms and decadal variations over a period of nearly one century. An empirical orthogonal function analysis is applied to a time series of shoreline positions at Fire Island, NY to identify patterns of shoreline variance along the length of the island. We establish that there are separable patterns of shoreline behavior that represent response to oceanographic forcing as well as patterns that are not explained by this forcing. The dominant shoreline behavior occurs over large length scales in the form of alternating episodes of shoreline retreat and advance, presumably in response to storms cycles. Two secondary responses include long-term response that is correlated to known geologic variations of the island and the other reflects geomorphic patterns with medium length scale. Our study also includes the response to Hurricane Sandy and a period of post-storm recovery. It was expected that the impacts from Hurricane Sandy would disrupt long-term trends and spatial patterns. We found that the response to Sandy at Fire Island is not notable or distinguishable from several other large storms of the prior decade.

Microphase separation of comb copolymers with two different lengths of side chains

NASA Astrophysics Data System (ADS)

Aliev, M. A.; Kuzminyh, N. Yu.

2009-10-01

The phase behavior of the monodisperse AB comb copolymer melt contained the macromolecules of special architecture is discussed. Each macromolecule is assumed to be composed of two comb blocks which differ in numbers of side chains and numbers of monomer units in these chains. It is shown (by analysis of the structure factor of the melt) that microphase separation at two different length scales in the melt is possible. The large and small length scales correspond to separation between comb blocks and separation between monomer units in repeating fragments of blocks, respectively. The classification diagrams indicated which length scale is favored for a given parameters of chemical structure of macromolecules are constructed.

On the Spatio-Temporal Variability of Field-Aligned Currents Observed with the Swarm Satellite Constellation: Implications for the Energetics of Magnetosphere-Ionosphere Coupling

NASA Astrophysics Data System (ADS)

Pakhotin, I.; Mann, I. R.; Forsyth, C.; Rae, J.; Burchill, J. K.; Knudsen, D. J.; Murphy, K. R.; Gjerloev, J. W.; Ozeke, L.; Balasis, G.; Daglis, I. A.

2016-12-01

With the advent of the Swarm mission with its multi-satellite capacity, it became possible for the first time to make systematic close separation multi-satellite measurements of the magnetic fields associated with field-aligned currents (FACs) at a 50 Hz cadence using fluxgate magnetometers. Initial studies have revealed an even greater level of detail and complexity and spatio-temporal non-stationarity than previously understood. On inter-satellite separation scales of 10 seconds along-track and <120 km cross-track, the peak-to-peak magnitudes of the small scale and poorly correlated inter-spacecraft magnetic field fluctuations can reach tens to hundreds of nanoteslas. These magnitudes are directly comparable to those associated with larger scale magnetic perturbations such as the global scale Region 1 and 2 FAC systems characterised by Iijima and Potemra 40 years ago. We evaluate the impact of these smaller scale magnetic perturbations relative to the larger scale FAC systems statistically as a function of the total number of FAC crossings observed, and as a function of geomagnetic indices, spatial location, and season. Further case studies incorporating Swarm electric field measurements enable estimates of the Poynting flux associated with the small scale and non-stationary magnetic fields. We interpret the small scale structures as Alfvenic, suggesting that Alfven waves play a much larger and more energetically significant role in magnetosphere-ionosphere coupling than previously thought. We further examine what causes such high variability among low-Earth orbit FAC systems to be observed under some conditions but not in others.

Evaluation of flow hydrodynamics in a pilot-scale dissolved air flotation tank: a comparison between CFD and experimental measurements.

PubMed

Lakghomi, B; Lawryshyn, Y; Hofmann, R

2015-01-01

Computational fluid dynamics (CFD) models of dissolved air flotation (DAF) have shown formation of stratified flow (back and forth horizontal flow layers at the top of the separation zone) and its impact on improved DAF efficiency. However, there has been a lack of experimental validation of CFD predictions, especially in the presence of solid particles. In this work, for the first time, both two-phase (air-water) and three-phase (air-water-solid particles) CFD models were evaluated at pilot scale using measurements of residence time distribution, bubble layer position and bubble-particle contact efficiency. The pilot-scale results confirmed the accuracy of the CFD model for both two-phase and three-phase flows, but showed that the accuracy of the three-phase CFD model would partly depend on the estimation of bubble-particle attachment efficiency.

The Triggering of Large-Scale Waves by CME Initiation

NASA Astrophysics Data System (ADS)

Forbes, Terry

Studies of the large-scale waves generated at the onset of a coronal mass ejection (CME) can provide important information about the processes in the corona that trigger and drive CMEs. The size of the region where the waves originate can indicate the location of the magnetic forces that drive the CME outward, and the rate at which compressive waves steepen into shocks can provide a measure of how the driving forces develop in time. However, in practice it is difficult to separate the effects of wave formation from wave propagation. The problem is particularly acute for the corona because of the multiplicity of wave modes (e.g. slow versus fast MHD waves) and the highly nonuniform structure of the solar atmosphere. At the present time large-scale numerical simulations provide the best hope for deconvolving wave propagation and formation effects from one another.

Fe3O4@MOF core-shell magnetic microspheres as excellent catalysts for the Claisen-Schmidt condensation reaction

NASA Astrophysics Data System (ADS)

Ke, Fei; Qiu, Ling-Guang; Zhu, Junfa

2014-01-01

Separation and recycling of catalysts after catalytic reactions are critically required to reduce the cost of catalysts as well as to avoid the generation of waste in industrial applications. In this work, we present a facile fabrication and characterization of a novel type of MOF-based porous catalyst, namely, Fe3O4@MIL-100(Fe) core-shell magnetic microspheres. It has been shown that these catalysts not only exhibit high catalytic activities for the Claisen-Schmidt condensation reactions under environmentally friendly conditions, but remarkably, they can be easily separated and recycled without significant loss of catalytic efficiency after being used for many times. Therefore, compared to other reported catalysts used in the Claisen-Schmidt condensation reactions, these catalysts are green, cheap and more suitable for large scale industrial applications.Separation and recycling of catalysts after catalytic reactions are critically required to reduce the cost of catalysts as well as to avoid the generation of waste in industrial applications. In this work, we present a facile fabrication and characterization of a novel type of MOF-based porous catalyst, namely, Fe3O4@MIL-100(Fe) core-shell magnetic microspheres. It has been shown that these catalysts not only exhibit high catalytic activities for the Claisen-Schmidt condensation reactions under environmentally friendly conditions, but remarkably, they can be easily separated and recycled without significant loss of catalytic efficiency after being used for many times. Therefore, compared to other reported catalysts used in the Claisen-Schmidt condensation reactions, these catalysts are green, cheap and more suitable for large scale industrial applications. Electronic supplementary information (ESI) available: SEM and TEM images, and GC-MS spectra for chalcones. See DOI: 10.1039/c3nr05051c

Ultrafast photoinduced charge separation in metal-semiconductor nanohybrids.

PubMed

Mongin, Denis; Shaviv, Ehud; Maioli, Paolo; Crut, Aurélien; Banin, Uri; Del Fatti, Natalia; Vallée, Fabrice

2012-08-28

Hybrid nano-objects formed by two or more disparate materials are among the most promising and versatile nanosystems. A key parameter in their properties is interaction between their components. In this context we have investigated ultrafast charge separation in semiconductor-metal nanohybrids using a model system of gold-tipped CdS nanorods in a matchstick architecture. Experiments are performed using an optical time-resolved pump-probe technique, exciting either the semiconductor or the metal component of the particles, and probing the light-induced change of their optical response. Electron-hole pairs photoexcited in the semiconductor part of the nanohybrids are shown to undergo rapid charge separation with the electron transferred to the metal part on a sub-20 fs time scale. This ultrafast gold charging leads to a transient red-shift and broadening of the metal surface plasmon resonance, in agreement with results for free clusters but in contrast to observation for static charging of gold nanoparticles in liquid environments. Quantitative comparison with a theoretical model is in excellent agreement with the experimental results, confirming photoexcitation of one electron-hole pair per nanohybrid followed by ultrafast charge separation. The results also point to the utilization of such metal-semiconductor nanohybrids in light-harvesting applications and in photocatalysis.

Understanding the influence of solvent field and fluctuations on the stability of photo-induced charge-separated state in molecular triad

NASA Astrophysics Data System (ADS)

Balamurugan, D.; Aquino, Adelia; Lischka, Hans; Dios, Francis; Flores, Lionel; Cheung, Margaret

2013-03-01

Molecular triad composed of fullerene, porphyrin, and carotene is an artificial analogue of natural photosynthetic system and is considered for applications in solar energy conversion because of its ability to produce long-lived photo-induced charge separated state. The goal of the present multiscale simulation is to understand how the stability of photo-induced charge-separated state in molecular triad is influenced by a polar organic solvent, namely tetrahydrofuran (THF). The multiscale approach is based on combined quantum, classical molecular dynamics, and statistical physics calculations. The quantum chemical calculations were performed on the triad using the second order algebraic diagrammatic perturbation and time-dependent density functional theory. Molecular dynamics simulations were performed on triad in a box of THF solvent with the replica exchange method. The two methods on different length and time scales are bridged through an important sampling technique. We have analyzed the free energy landscape, structural fluctuations, and the long- range electrostatic interactions between triad and solvent molecules. The results suggest that the polarity and re-organization of the solvent is critical in stabilization of charge-separated state in triad. Supported by DOE (DE-FG02-10ER16175)

Floating-point scaling technique for sources separation automatic gain control

NASA Astrophysics Data System (ADS)

Fermas, A.; Belouchrani, A.; Ait-Mohamed, O.

2012-07-01

Based on the floating-point representation and taking advantage of scaling factor indetermination in blind source separation (BSS) processing, we propose a scaling technique applied to the separation matrix, to avoid the saturation or the weakness in the recovered source signals. This technique performs an automatic gain control in an on-line BSS environment. We demonstrate the effectiveness of this technique by using the implementation of a division-free BSS algorithm with two inputs, two outputs. The proposed technique is computationally cheaper and efficient for a hardware implementation compared to the Euclidean normalisation.

Multiscale modeling and general theory of non-equilibrium plasma-assisted ignition and combustion

NASA Astrophysics Data System (ADS)

Yang, Suo; Nagaraja, Sharath; Sun, Wenting; Yang, Vigor

2017-11-01

A self-consistent framework for modeling and simulations of plasma-assisted ignition and combustion is established. In this framework, a ‘frozen electric field’ modeling approach is applied to take advantage of the quasi-periodic behaviors of the electrical characteristics to avoid the re-calculation of electric field for each pulse. The correlated dynamic adaptive chemistry (CO-DAC) method is employed to accelerate the calculation of large and stiff chemical mechanisms. The time-step is dynamically updated during the simulation through a three-stage multi-time scale modeling strategy, which utilizes the large separation of time scales in nanosecond pulsed plasma discharges. A general theory of plasma-assisted ignition and combustion is then proposed. Nanosecond pulsed plasma discharges for ignition and combustion can be divided into four stages. Stage I is the discharge pulse, with time scales of O (1-10 ns). In this stage, input energy is coupled into electron impact excitation and dissociation reactions to generate charged/excited species and radicals. Stage II is the afterglow during the gap between two adjacent pulses, with time scales of O (1 0 0 ns). In this stage, quenching of excited species dissociates O2 and fuel molecules, and provides fast gas heating. Stage III is the remaining gap between pulses, with time scales of O (1-100 µs). The radicals generated during Stages I and II significantly enhance exothermic reactions in this stage. The cumulative effects of multiple pulses is seen in Stage IV, with time scales of O (1-1000 ms), which include preheated gas temperatures and a large pool of radicals and fuel fragments to trigger ignition. For flames, plasma could significantly enhance the radical generation and gas heating in the pre-heat zone, thereby enhancing the flame establishment.

Scaling theory in a model of corrosion and passivation.

PubMed

Aarão Reis, F D A; Stafiej, Janusz; Badiali, J-P

2006-09-07

We study a model for corrosion and passivation of a metallic surface after small damage of its protective layer using scaling arguments and simulation. We focus on the transition between an initial regime of slow corrosion rate (pit nucleation) to a regime of rapid corrosion (propagation of the pit), which takes place at the so-called incubation time. The model is defined in a lattice in which the states of the sites represent the possible states of the metal (bulk, reactive, and passive) and the solution (neutral, acidic, or basic). Simple probabilistic rules describe passivation of the metal surface, dissolution of the passive layer, which is enhanced in acidic media, and spatially separated electrochemical reactions, which may create pH inhomogeneities in the solution. On the basis of a suitable matching of characteristic times of creation and annihilation of pH inhomogeneities in the solution, our scaling theory estimates the average radius of the dissolved region at the incubation time as a function of the model parameters. Among the main consequences, that radius decreases with the rate of spatially separated reactions and the rate of dissolution in acidic media, and it increases with the diffusion coefficient of H(+) and OH(-) ions in solution. The average incubation time can be written as the sum of a series of characteristic times for the slow dissolution in neutral media, until significant pH inhomogeneities are observed in the dissolved cavity. Despite having a more complex dependence on the model parameters, it is shown that the average incubation time linearly increases with the rate of dissolution in neutral media, under the reasonable assumption that this is the slowest rate of the process. Our theoretical predictions are expected to apply in realistic ranges of values of the model parameters. They are confirmed by numerical simulation in two-dimensional lattices, and the expected extension of the theory to three dimensions is discussed.

Optimal approaches for balancing invasive species eradication and endangered species management.

PubMed

Lampert, Adam; Hastings, Alan; Grosholz, Edwin D; Jardine, Sunny L; Sanchirico, James N

2014-05-30

Resolving conflicting ecosystem management goals-such as maintaining fisheries while conserving marine species or harvesting timber while preserving habitat-is a widely recognized challenge. Even more challenging may be conflicts between two conservation goals that are typically considered complementary. Here, we model a case where eradication of an invasive plant, hybrid Spartina, threatens the recovery of an endangered bird that uses Spartina for nesting. Achieving both goals requires restoration of native Spartina. We show that the optimal management entails less intensive treatment over longer time scales to fit with the time scale of natural processes. In contrast, both eradication and restoration, when considered separately, would optimally proceed as fast as possible. Thus, managers should simultaneously consider multiple, potentially conflicting goals, which may require flexibility in the timing of expenditures. Copyright © 2014, American Association for the Advancement of Science.

Large-scale anisotropy in stably stratified rotating flows

DOE PAGES

Marino, R.; Mininni, P. D.; Rosenberg, D. L.; ...

2014-08-28

We present results from direct numerical simulations of the Boussinesq equations in the presence of rotation and/or stratification, both in the vertical direction. The runs are forced isotropically and randomly at small scales and have spatial resolutions of up tomore » $1024^3$ grid points and Reynolds numbers of $$\\approx 1000$$. We first show that solutions with negative energy flux and inverse cascades develop in rotating turbulence, whether or not stratification is present. However, the purely stratified case is characterized instead by an early-time, highly anisotropic transfer to large scales with almost zero net isotropic energy flux. This is consistent with previous studies that observed the development of vertically sheared horizontal winds, although only at substantially later times. However, and unlike previous works, when sufficient scale separation is allowed between the forcing scale and the domain size, the total energy displays a perpendicular (horizontal) spectrum with power law behavior compatible with $$\\sim k_\\perp^{-5/3}$$, including in the absence of rotation. In this latter purely stratified case, such a spectrum is the result of a direct cascade of the energy contained in the large-scale horizontal wind, as is evidenced by a strong positive flux of energy in the parallel direction at all scales including the largest resolved scales.« less

Acetaminophen Versus Liquefied Ibuprofen for Control of Pain During Separation in Orthodontic Patients: A Randomized Triple Blinded Clinical Trial.

PubMed

Hosseinzadeh Nik, Tahereh; Shahsavari, Negin; Ghadirian, Hannaneh; Ostad, Seyed Nasser

2016-07-01

The aim of this randomized clinical study was to investigate the effectiveness of acetaminophen 650 mg or liquefied ibuprofen 400 mg in pain control of orthodontic patients during separation with an elastic separator. A total of 101 patients with specific inclusion criteria were divided randomly into three groups (acetaminophen, liquefied ibuprofen, and placebo). They were instructed to take their drugs one hour before separator placement and every six hours afterward (five doses in total). They recorded their discomfort on visual analog scales immediately after separator placement, 2 hours later, 6 hours later, at bedtime, and 24 hours after separator placement. Repeated measure analysis of variance (ANOVA) was used to compare the mean pain scores between the three groups. Data were collected from 89 patients. The pain increased with time in all groups. Pain scores were statistically lower in the analgesic groups compared with the placebo group (P.value<0.001), but no statistically significant difference was found in mean pain scores between the two drug groups (acetaminophen and liquefied ibuprofen) (P.value=1). Acetaminophen and liquefied ibuprofen have similar potential in pain reduction during separation.

The Development of a Post Separation/Post Divorce Problems and Stress Scale.

ERIC Educational Resources Information Center

Raschke, Helen J.

Factors associated with the speed and level of difficulty with which individuals adjust to separation and divorce were investigated. A scale was developed to analyze these factors, and included items dealing with the subdimensions of stress and the perception of the persons involved. Factor analysis of the scale items as well as additional tests…

Multi-scale variability and long-range memory in indoor Radon concentrations from Coimbra, Portugal

NASA Astrophysics Data System (ADS)

Donner, Reik V.; Potirakis, Stelios; Barbosa, Susana

2014-05-01

The presence or absence of long-range correlations in the variations of indoor Radon concentrations has recently attracted considerable interest. As a radioactive gas naturally emitted from the ground in certain geological settings, understanding environmental factors controlling Radon concentrations and their dynamics is important for estimating its effect on human health and the efficiency of possible measures for reducing the corresponding exposition. In this work, we re-analyze two high-resolution records of indoor Radon concentrations from Coimbra, Portugal, each of which spans several months of continuous measurements. In order to evaluate the presence of long-range correlations and fractal scaling, we utilize a multiplicity of complementary methods, including power spectral analysis, ARFIMA modeling, classical and multi-fractal detrended fluctuation analysis, and two different estimators of the signals' fractal dimensions. Power spectra and fluctuation functions reveal some complex behavior with qualitatively different properties on different time-scales: white noise in the high-frequency part, indications of some long-range correlated process dominating time scales of several hours to days, and pronounced low-frequency variability associated with tidal and/or meteorological forcing. In order to further decompose these different scales of variability, we apply two different approaches. On the one hand, applying multi-resolution analysis based on the discrete wavelet transform allows separately studying contributions on different time scales and characterize their specific correlation and scaling properties. On the other hand, singular system analysis (SSA) provides a reconstruction of the essential modes of variability. Specifically, by considering only the first leading SSA modes, we achieve an efficient de-noising of our environmental signals, highlighting the low-frequency variations together with some distinct scaling on sub-daily time-scales resembling the properties of a long-range correlated process.

Frequency adjustment and synchrony in networks of delayed pulse-coupled oscillators

NASA Astrophysics Data System (ADS)

Nishimura, Joel

2015-01-01

We introduce a system of pulse-coupled oscillators that can change both their phases and frequencies and prove that when there is a separation of time scales between phase and frequency adjustment the system converges to exact synchrony on strongly connected graphs with time delays. The analysis involves decomposing the network into a forest of tree-like structures that capture causality. These results provide a robust method of sensor net synchronization as well as demonstrate a new avenue of possible pulse-coupled oscillator research.

Thermalization after an interaction quench in the Hubbard model.

PubMed

Eckstein, Martin; Kollar, Marcus; Werner, Philipp

2009-07-31

We use nonequilibrium dynamical mean-field theory to study the time evolution of the fermionic Hubbard model after an interaction quench. Both in the weak-coupling and in the strong-coupling regime the system is trapped in quasistationary states on intermediate time scales. These two regimes are separated by a sharp crossover at U(c)dyn=0.8 in units of the bandwidth, where fast thermalization occurs. Our results indicate a dynamical phase transition which should be observable in experiments on trapped fermionic atoms.

Impulsive effects of phase-locked pulse pairs on nuclear motion in the electronic ground state

NASA Astrophysics Data System (ADS)

Cina, J. A.; Smith, T. J.

1993-06-01

The nonlinear effects of ultrashort phase-locked electronically resonant pulse pairs on the ground state nuclear motion are investigated theoretically. The pulse-pair propagator, momentum impulse, and displacement are determined in the weak field limit for pulse pairs separated by a time delay short on a nuclear time scale. Possible application to large amplitude vibrational excitation of the 104 cm-1 mode of α-perylene is considered and comparisons are made to other Raman excitation methods.

Effects of a scalar scaling field on quantum mechanics

DOE PAGES

Benioff, Paul

2016-04-18

This paper describes the effects of a complex scalar scaling field on quantum mechanics. The field origin is an extension of the gauge freedom for basis choice in gauge theories to the underlying scalar field. The extension is based on the idea that the value of a number at one space time point does not determine the value at another point. This, combined with the description of mathematical systems as structures of different types, results in the presence of separate number fields and vector spaces as structures, at different space time locations. Complex number structures and vector spaces at eachmore » location are scaled by a complex space time dependent scaling factor. The effect of this scaling factor on several physical and geometric quantities has been described in other work. Here the emphasis is on quantum mechanics of one and two particles, their states and properties. Multiparticle states are also briefly described. The effect shows as a complex, nonunitary, scalar field connection on a fiber bundle description of nonrelativistic quantum mechanics. Here, the lack of physical evidence for the presence of this field so far means that the coupling constant of this field to fermions is very small. It also means that the gradient of the field must be very small in a local region of cosmological space and time. Outside this region, there are no restrictions on the field gradient.« less

The Effect of Micro-ramps on Supersonic Flow over a Forward-Facing Step

NASA Astrophysics Data System (ADS)

Zhang, Qing-Hu; Yi, Shi-He; Zhu, Yang-Zhu; Chen, Zhi; Wu, Yu

2013-04-01

The effect of micro-ramp control on fully developed turbulent flow over a forward-facing step (FFS) is investigated in a supersonic low-noise wind tunnel at Mach number 3 using nano-tracer planar laser scattering (NPLS) and supersonic particle image velocimetry (PIV) techniques. High spatiotemporal resolution images and the average velocity profiles of supersonic flow over the FFS with and without the control of the micro-ramps are captured. The fine structures of both cases, including the coherent structures of fully developed boundary layer and the large-scale hairpin-like vortices originated from the micro-ramps as well as the interaction of shock waves with the large-scale structures, are revealed and compared. Based on the time-correlation images, the temporal and spatial evolutionary characteristics of the coherent structures are investigated. It is beneficial to understand the dynamic mechanisms of the separated flow and the control mechanisms of the micro-ramps. The size of the separation region is determined by the NPLS and PIV. The results indicate that the control of the micro-ramps is capable of delaying the separation and diminishing the extent of recirculation zone.

Spatial and temporal variability of chorus and hiss

NASA Astrophysics Data System (ADS)

Santolik, O.; Hospodarsky, G. B.; Kurth, W. S.; Kletzing, C.

2017-12-01

Whistler-mode electromagnetic waves, especially natural emissions of chorus and hiss, have been shown to influence the dynamics of the Van Allen radiation belts via quasi-linear or nonlinear wave particle interactions, transferring energy between different electron populations. Average intensities of chorus and hiss emissions have been found to increase with increasing levels of geomagnetic activity but their stochastic variations in individual spacecraft measurements are usually larger these large-scale temporal effects. To separate temporal and spatial variations of wave characteristics, measurements need to be simultaneously carried out in different locations by identical and/or well calibrated instrumentation. We use two-point survey measurements of the Waves instruments of the Electric and Magnetic Field Instrument Suite and Integrated Science (EMFISIS) onboard two Van Allen Probes to asses spatial and temporal variability of chorus and hiss. We take advantage of a systematic analysis of this large data set which has been collected during 2012-2017 over a range of separation vectors of the two spacecraft. We specifically address the question whether similar variations occur at different places at the same time. Our results indicate that power variations are dominated by separations in MLT at scales larger than 0.5h.

Intrapair differences in personality and cognitive ability among young monozygotic twins distinguished by chorion type.

PubMed

Sokol, D K; Moore, C A; Rose, R J; Williams, C J; Reed, T; Christian, J C

1995-09-01

We evaluated placentation effects on behavioral resemblance of 44 pairs of monozygotic (MZ) twin children. Tested at ages 4-6, the twins' zygosity and placental type had been determined at their delivery. The sample included 23 monochorionic (MC) and 21 dichorionic (DC) MZ twin pairs: DC-MZ twins result from separation of blastomeres within 72 h of ovulation; MC-MZ twins arise from later duplication of the inner cell mass. Twins were individually administered the McCarthy Scales of Cognitive Ability, while their mothers separately rated each cotwin on an individualized 280-item form of the Personality Inventory for Children (PIC). Absolute differences between MC-MZ cotwins were smaller than those between DC-MZ cotwins for all 20 PIC scales, significantly so for 3 of 4 factor scales, 8 of 12 clinical scales, and 2 of 4 validity/screening scales from the PIC; in contrast, no consistent differences in intrapair resemblance of mono- and dichorionic MZ twins were found for the McCarthy Scales. The chorion differences found in the PIC data cannot be due to genetic differences, because all pairs are monozygotes; nor are they associated with differences in parity, gestational age, birth weight, maternal education, palmar dermatoglyphic asymmetry, or maternal knowledge of chorion type. We interpret our findings as suggestive evidence that variation in timing of embryological division, with effects on MZ twins' placental vasculature, has significant consequences for some dimensions of their behavioral development, as well.

A new scheme for velocity analysis and imaging of diffractions

NASA Astrophysics Data System (ADS)

Lin, Peng; Peng, Suping; Zhao, Jingtao; Cui, Xiaoqin; Du, Wenfeng

2018-06-01

Seismic diffractions are the responses of small-scale inhomogeneities or discontinuous geological features, which play a vital role in the exploitation and development of oil and gas reservoirs. However, diffractions are generally ignored and considered as interference noise in conventional data processing. In this paper, a new scheme for velocity analysis and imaging of seismic diffractions is proposed. Two steps compose of this scheme in our application. First, the plane-wave destruction method is used to separate diffractions from specular reflections in the prestack domain. Second, in order to accurately estimate migration velocity of the diffractions, the time-domain dip-angle gathers are derived from a Kirchhoff-based angle prestack time migration using separated diffractions. Diffraction events appear flat in the dip-angle gathers when imaged above the diffraction point with selected accurate migration velocity for diffractions. The selected migration velocity helps to produce the desired prestack imaging of diffractions. Synthetic and field examples are applied to test the validity of the new scheme. The diffraction imaging results indicate that the proposed scheme for velocity analysis and imaging of diffractions can provide more detailed information about small-scale geologic features for seismic interpretation.

Degradation modeling of high temperature proton exchange membrane fuel cells using dual time scale simulation

NASA Astrophysics Data System (ADS)

Pohl, E.; Maximini, M.; Bauschulte, A.; vom Schloß, J.; Hermanns, R. T. E.

2015-02-01

HT-PEM fuel cells suffer from performance losses due to degradation effects. Therefore, the durability of HT-PEM is currently an important factor of research and development. In this paper a novel approach is presented for an integrated short term and long term simulation of HT-PEM accelerated lifetime testing. The physical phenomena of short term and long term effects are commonly modeled separately due to the different time scales. However, in accelerated lifetime testing, long term degradation effects have a crucial impact on the short term dynamics. Our approach addresses this problem by applying a novel method for dual time scale simulation. A transient system simulation is performed for an open voltage cycle test on a HT-PEM fuel cell for a physical time of 35 days. The analysis describes the system dynamics by numerical electrochemical impedance spectroscopy. Furthermore, a performance assessment is performed in order to demonstrate the efficiency of the approach. The presented approach reduces the simulation time by approximately 73% compared to conventional simulation approach without losing too much accuracy. The approach promises a comprehensive perspective considering short term dynamic behavior and long term degradation effects.

Stretchable Lithium-Ion Batteries Enabled by Device-Scaled Wavy Structure and Elastic-Sticky Separator

DOE Office of Scientific and Technical Information (OSTI.GOV)

Liu, Wei; Chen, Jun; Chen, Zheng

Fast developments and substantial achievements have been shaping the field of wearable electronic devices, resulting in the persistent requirement for stretchable lithium-ion batteries (LIBs). Despite recent progress in stretchable electrodes, stretching full batteries, including electrodes, separator, and sealing material, remains a great challenge. Here, a simple design concept for stretchable LIBs via a wavy structure at the full battery device scale is reported. All components including the package are capable of being reversibly stretched by folding the entire pouch cell into a wavy shape with polydimethylsiloxane filled in each valley region. In addition, the stretchable, sticky, and porous polyurethane/poly(vinylidene fluoride)more » membrane is adopted as a separator for the first time, which can maintain intimate contact between electrodes and separator to continuously secure ion pathway under dynamic state. Commercial cathode, anode, and package can be utilized in this rationally designed wavy battery to enable stretchability. The results indicate good electrochemical performances and long-term stability at repeatable release–stretch cycles. A high areal capacity of 3.6 mA h cm -2 and energy density of up to 172 W h L -1 can be achieved for the wavy battery. The promising results of the cost-effective wavy battery with high stretchability shed light on the development of stretchable energy storages.« less

Stretchable Lithium-Ion Batteries Enabled by Device-Scaled Wavy Structure and Elastic-Sticky Separator

DOE PAGES

Liu, Wei; Chen, Jun; Chen, Zheng; ...

2017-07-17

Fast developments and substantial achievements have been shaping the field of wearable electronic devices, resulting in the persistent requirement for stretchable lithium-ion batteries (LIBs). Despite recent progress in stretchable electrodes, stretching full batteries, including electrodes, separator, and sealing material, remains a great challenge. Here, a simple design concept for stretchable LIBs via a wavy structure at the full battery device scale is reported. All components including the package are capable of being reversibly stretched by folding the entire pouch cell into a wavy shape with polydimethylsiloxane filled in each valley region. In addition, the stretchable, sticky, and porous polyurethane/poly(vinylidene fluoride)more » membrane is adopted as a separator for the first time, which can maintain intimate contact between electrodes and separator to continuously secure ion pathway under dynamic state. Commercial cathode, anode, and package can be utilized in this rationally designed wavy battery to enable stretchability. The results indicate good electrochemical performances and long-term stability at repeatable release–stretch cycles. A high areal capacity of 3.6 mA h cm -2 and energy density of up to 172 W h L -1 can be achieved for the wavy battery. The promising results of the cost-effective wavy battery with high stretchability shed light on the development of stretchable energy storages.« less

Intrinsic vs. spurious long-range memory in high-frequency records of environmental radioactivity - Critical re-assessment and application to indoor 222Rn concentrations from Coimbra, Portugal

NASA Astrophysics Data System (ADS)

Donner, Reik V.; Potirakis, Stelios M.; Barbosa, Susana M.; Matos, Jose A. O.

2015-04-01

The presence or absence of long-range correlations in environmental radioactivity fluctuations has recently attracted considerable interest. Among a multiplicity of practically relevant applications, identifying and disentangling the environmental factors controlling the variable concentrations of the radioactive noble gas Radon is important for estimating its effect on human health and the efficiency of possible measures for reducing the corresponding exposition. In this work, we present a critical re-assessment of a multiplicity of complementary methods that have been previously applied for evaluating the presence of long-range correlations and fractal scaling in environmental Radon variations with a particular focus on the specific properties of the underlying time series. As an illustrative case study, we subsequently re-analyze two high-frequency records of indoor Radon concentrations from Coimbra, Portugal, each of which spans several months of continuous measurements at a high temporal resolution of five minutes. Our results reveal that at the study site, Radon concentrations exhibit complex multi-scale dynamics with qualitatively different properties at different time-scales: (i) essentially white noise in the high-frequency part (up to time-scales of about one hour), (ii) spurious indications of a non-stationary, apparently long-range correlated process (at time scales between hours and one day) arising from marked periodic components probably related to tidal frequencies, and (iii) low-frequency variability indicating a true long-range dependent process, which might be dominated by a response to meteorological drivers. In the presence of such multi-scale variability, common estimators of long-range memory in time series are necessarily prone to fail if applied to the raw data without previous separation of time-scales with qualitatively different dynamics. We emphasize that similar properties can be found in other types of geophysical time series (for example, tide gauge records), calling for a careful application of time series analysis tools when studying such data.

Characteristic Length Scales in Fracture Networks: Hydraulic Connectivity through Periodic Hydraulic Tests

NASA Astrophysics Data System (ADS)

Becker, M.; Bour, O.; Le Borgne, T.; Longuevergne, L.; Lavenant, N.; Cole, M. C.; Guiheneuf, N.

2017-12-01

Determining hydraulic and transport connectivity in fractured bedrock has long been an important objective in contaminant hydrogeology, petroleum engineering, and geothermal operations. A persistent obstacle to making this determination is that the characteristic length scale is nearly impossible to determine in sparsely fractured networks. Both flow and transport occur through an unknown structure of interconnected fracture and/or fracture zones making the actual length that water or solutes travel undetermined. This poses difficulties for flow and transport models. For, example, hydraulic equations require a separation distance between pumping and observation well to determine hydraulic parameters. When wells pairs are close, the structure of the network can influence the interpretation of well separation and the flow dimension of the tested system. This issue is explored using hydraulic tests conducted in a shallow fractured crystalline rock. Periodic (oscillatory) slug tests were performed at the Ploemeur fractured rock test site located in Brittany, France. Hydraulic connectivity was examined between three zones in one well and four zones in another, located 6 m apart in map view. The wells are sufficiently close, however, that the tangential distance between the tested zones ranges between 6 and 30 m. Using standard periodic formulations of radial flow, estimates of storativity scale inversely with the square of the separation distance and hydraulic diffusivity directly with the square of the separation distance. Uncertainty in the connection paths between the two wells leads to an order of magnitude uncertainty in estimates of storativity and hydraulic diffusivity, although estimates of transmissivity are unaffected. The assumed flow dimension results in alternative estimates of hydraulic parameters. In general, one is faced with the prospect of assuming the hydraulic parameter and inverting the separation distance, or vice versa. Similar uncertainties exist, for instance, when trying to invert transport parameters from tracer mean residence time. This field test illustrates that when dealing with fracture networks, there is a need for analytic methods of complexity that lie between simple radial solutions and discrete fracture network models.

Aspects regarding at 13C isotope separation column control using Petri nets system

NASA Astrophysics Data System (ADS)

Boca, M. L.; Ciortea, M. E.

2015-11-01

This paper is intended to show that Petri nets can be also applicable in the chemical industry. It used linear programming, modeling underlying Petri nets, especially discrete event systems for isotopic separation, the purpose of considering and control events in real-time through graphical representations. In this paper it is simulate the control of 13C Isotope Separation column using Petri nets. The major problem with 13C comes from the difficulty of obtaining it and raising its natural fraction. Carbon isotopes can be obtained using many methods, one of them being the cryogenic distillation of carbon monoxide. Some few aspects regarding operating conditions and the construction of such cryogenic plants are known today, and even less information are available as far as the separation process modeling and control are concerned. In fact, the efficient control of the carbon monoxide distillation process represents a necessity for large-scale 13C production. Referring to a classic distillation process, some models for carbon isotope separation have been proposed, some based on mass, component and energy balance equations, some on the nonlinear wave theory or the Cohen equations. For modeling the system it was used Petri nets because in this case it is deal with discrete event systems. In use of the non-timed and with auxiliary times Petri model, the transport stream was divided into sections and these sections will be analyzed successively. Because of the complexity of the system and the large amount of calculations required it was not possible to analyze the system as a unitary whole. A first attempt to model the system as a unitary whole led to the blocking of the model during simulation, because of the large processing times.

Characterization of the homologs of flerovium with crown ether based extraction chromatography resins: studies in nitric acid

DOE PAGES

Despotopulos, John D.; Kmak, Kelly N.; Gharibyan, Narek; ...

2016-09-17

Eichrom’s Pb resin, a crown-ether-based extraction chromatography resin, was characterized for separation of the flerovium (Fl) homologs, Pb and Sn. Batch uptake of Pb(II) and Sn(IV) radionuclides was determined from an HNO 3 matrix. Pb(II) was strongly retained on the resin at all HNO 3 concentrations, while Sn(IV) showed no uptake. Extraction kinetics for Pb(II) were examined and show suitable uptake on the second time scale. Here, separation methods for the isolation of individual homologs, Pb(II) and Sn(IV), have been established using 2 mL pre-packed vacuum flow Pb resin columns.

The temporal spectrum of adult mosquito population fluctuations: conceptual and modeling implications.

PubMed

Jian, Yun; Silvestri, Sonia; Brown, Jeff; Hickman, Rick; Marani, Marco

2014-01-01

An improved understanding of mosquito population dynamics under natural environmental forcing requires adequate field observations spanning the full range of temporal scales over which mosquito abundance fluctuates in natural conditions. Here we analyze a 9-year daily time series of uninterrupted observations of adult mosquito abundance for multiple mosquito species in North Carolina to identify characteristic scales of temporal variability, the processes generating them, and the representativeness of observations at different sampling resolutions. We focus in particular on Aedes vexans and Culiseta melanura and, using a combination of spectral analysis and modeling, we find significant population fluctuations with characteristic periodicity between 2 days and several years. Population dynamical modelling suggests that the observed fast fluctuations scales (2 days-weeks) are importantly affected by a varying mosquito activity in response to rapid changes in meteorological conditions, a process neglected in most representations of mosquito population dynamics. We further suggest that the range of time scales over which adult mosquito population variability takes place can be divided into three main parts. At small time scales (indicatively 2 days-1 month) observed population fluctuations are mainly driven by behavioral responses to rapid changes in weather conditions. At intermediate scales (1 to several month) environmentally-forced fluctuations in generation times, mortality rates, and density dependence determine the population characteristic response times. At longer scales (annual to multi-annual) mosquito populations follow seasonal and inter-annual environmental changes. We conclude that observations of adult mosquito populations should be based on a sub-weekly sampling frequency and that predictive models of mosquito abundance must include behavioral dynamics to separate the effects of a varying mosquito activity from actual changes in the abundance of the underlying population.

Method for identifying subsurface fluid migration and drainage pathways in and among oil and gas reservoirs using 3-D and 4-D seismic imaging

DOEpatents

Anderson, R.N.; Boulanger, A.; Bagdonas, E.P.; Xu, L.; He, W.

1996-12-17

The invention utilizes 3-D and 4-D seismic surveys as a means of deriving information useful in petroleum exploration and reservoir management. The methods use both single seismic surveys (3-D) and multiple seismic surveys separated in time (4-D) of a region of interest to determine large scale migration pathways within sedimentary basins, and fine scale drainage structure and oil-water-gas regions within individual petroleum producing reservoirs. Such structure is identified using pattern recognition tools which define the regions of interest. The 4-D seismic data sets may be used for data completion for large scale structure where time intervals between surveys do not allow for dynamic evolution. The 4-D seismic data sets also may be used to find variations over time of small scale structure within individual reservoirs which may be used to identify petroleum drainage pathways, oil-water-gas regions and, hence, attractive drilling targets. After spatial orientation, and amplitude and frequency matching of the multiple seismic data sets, High Amplitude Event (HAE) regions consistent with the presence of petroleum are identified using seismic attribute analysis. High Amplitude Regions are grown and interconnected to establish plumbing networks on the large scale and reservoir structure on the small scale. Small scale variations over time between seismic surveys within individual reservoirs are identified and used to identify drainage patterns and bypassed petroleum to be recovered. The location of such drainage patterns and bypassed petroleum may be used to site wells. 22 figs.

Method for identifying subsurface fluid migration and drainage pathways in and among oil and gas reservoirs using 3-D and 4-D seismic imaging

DOEpatents

Anderson, Roger N.; Boulanger, Albert; Bagdonas, Edward P.; Xu, Liqing; He, Wei

1996-01-01

The invention utilizes 3-D and 4-D seismic surveys as a means of deriving information useful in petroleum exploration and reservoir management. The methods use both single seismic surveys (3-D) and multiple seismic surveys separated in time (4-D) of a region of interest to determine large scale migration pathways within sedimentary basins, and fine scale drainage structure and oil-water-gas regions within individual petroleum producing reservoirs. Such structure is identified using pattern recognition tools which define the regions of interest. The 4-D seismic data sets may be used for data completion for large scale structure where time intervals between surveys do not allow for dynamic evolution. The 4-D seismic data sets also may be used to find variations over time of small scale structure within individual reservoirs which may be used to identify petroleum drainage pathways, oil-water-gas regions and, hence, attractive drilling targets. After spatial orientation, and amplitude and frequency matching of the multiple seismic data sets, High Amplitude Event (HAE) regions consistent with the presence of petroleum are identified using seismic attribute analysis. High Amplitude Regions are grown and interconnected to establish plumbing networks on the large scale and reservoir structure on the small scale. Small scale variations over time between seismic surveys within individual reservoirs are identified and used to identify drainage patterns and bypassed petroleum to be recovered. The location of such drainage patterns and bypassed petroleum may be used to site wells.

The rate of separation of magnetic lines of force in a random magnetic field.

NASA Technical Reports Server (NTRS)

Jokipii, J. R.

1973-01-01

The mixing of magnetic lines of force, as represented by their rate of separation, as a function of distance along the magnetic field, is considered with emphasis on neighboring lines of force. This effect is particularly important in understanding the transport of charged particles perpendicular to the average magnetic field. The calculation is carried out in the approximation that the separation changes by an amount small compared with the correlation scale normal to the field, in a distance along the field of a few correlation scales. It is found that the rate of separation is very sensitive to the precise form of the power spectrum. Application to the interplanetary and interstellar magnetic fields is discussed, and it is shown that in some cases field lines, much closer together than the correlation scale, separate at a rate which is effectively as rapid as if they were many correlation lengths apart.

Fiber-based monolithic columns for liquid chromatography.

PubMed

Ladisch, Michael; Zhang, Leyu

2016-10-01

Fiber-based monoliths for use in liquid chromatographic separations are defined by columns packed with aligned fibers, woven matrices, or contiguous fiber structures capable of achieving rapid separations of proteins, macromolecules, and low molecular weight components. A common denominator and motivating driver for this approach, first initiated 25 years ago, was reducing the cost of bioseparations in a manner that also reduced residence time of retained components while achieving a high ratio of mass to momentum transfer. This type of medium, when packed into a liquid chromatography column, minimized the fraction of stagnant liquid and resulted in a constant plate height for non-adsorbing species. The uncoupling of dispersion from eluent flow rate enabled the surface chemistry of the stationary phase to be considered separately from fluid transport phenomena and pointed to new ways to apply chemistry for the engineering of rapid bioseparations. This paper addresses developments and current research on fiber-based monoliths and explains how the various forms of this type of chromatographic stationary phase have potential to provide new tools for analytical and preparative scale separations. The different stationary phases are discussed, and a model that captures the observed constant plate height as a function of mobile phase velocity is reviewed. Methods that enable hydrodynamically stable fiber columns to be packed and operated over a range of mobile phase flow rates, together with the development of new fiber chemistries, are shown to provide columns that extend the versatility of liquid chromatography using monoliths, particularly at the preparative scale. Graphical Abstract Schematic representation of a sample mixture being separated by a rolled-stationary phase column, resulting separated peaks shown in the chromatogram.

Flow Separation Control on A Full-Scale Vertical Tail Model Using Sweeping Jet Actuators

NASA Technical Reports Server (NTRS)

Andino, Marlyn Y.; Lin, John C.; Washburn, Anthony E.; Whalen, Edward A.; Graff, Emilio C.; Wygnanski, Israel J.

2015-01-01

This paper describes test results of a joint NASA/Boeing research effort to advance Active Flow Control (AFC) technology to enhance aerodynamic efficiency. A full-scale Boeing 757 vertical tail model equipped with sweeping jets AFC was tested at the National Full-Scale Aerodynamics Complex 40- by 80-Foot Wind Tunnel at NASA Ames Research Center. The flow separation control optimization was performed at 100 knots, a maximum rudder deflection of 30deg, and sideslip angles of 0deg and -7.5deg. Greater than 20% increments in side force were achieved at the two sideslip angles with a 31-actuator AFC configuration. Flow physics and flow separation control associated with the AFC are presented in detail. AFC caused significant increases in suction pressure on the actuator side and associated side force enhancement. The momentum coefficient (C sub mu) is shown to be a useful parameter to use for scaling-up sweeping jet AFC from sub-scale tests to full-scale applications. Reducing the number of actuators at a constant total C(sub mu) of approximately 0.5% and tripling the actuator spacing did not significantly affect the flow separation control effectiveness.

Memory and betweenness preference in temporal networks induced from time series

NASA Astrophysics Data System (ADS)

Weng, Tongfeng; Zhang, Jie; Small, Michael; Zheng, Rui; Hui, Pan

2017-02-01

We construct temporal networks from time series via unfolding the temporal information into an additional topological dimension of the networks. Thus, we are able to introduce memory entropy analysis to unravel the memory effect within the considered signal. We find distinct patterns in the entropy growth rate of the aggregate network at different memory scales for time series with different dynamics ranging from white noise, 1/f noise, autoregressive process, periodic to chaotic dynamics. Interestingly, for a chaotic time series, an exponential scaling emerges in the memory entropy analysis. We demonstrate that the memory exponent can successfully characterize bifurcation phenomenon, and differentiate the human cardiac system in healthy and pathological states. Moreover, we show that the betweenness preference analysis of these temporal networks can further characterize dynamical systems and separate distinct electrocardiogram recordings. Our work explores the memory effect and betweenness preference in temporal networks constructed from time series data, providing a new perspective to understand the underlying dynamical systems.

Analysis of Massively Separated Flows of Aircraft Using Detached Eddy Simulation

NASA Astrophysics Data System (ADS)

Morton, Scott

2002-08-01

An important class of turbulent flows of aerodynamic interest are those characterized by massive separation, e.g., the flow around an aircraft at high angle of attack. Numerical simulation is an important tool for analysis, though traditional models used in the solution of the Reynolds-averaged Navier-Stokes (RANS) equations appear unable to accurately account for the time-dependent and three-dimensional motions governing flows with massive separation. Large-eddy simulation (LES) is able to resolve these unsteady three-dimensional motions, yet is cost prohibitive for high Reynolds number wall-bounded flows due to the need to resolve the small scale motions in the boundary layer. Spalart et. al. proposed a hybrid technique, Detached-Eddy Simulation (DES), which takes advantage of the often adequate performance of RANS turbulence models in the "thin," typically attached regions of the flow. In the separated regions of the flow the technique becomes a Large Eddy Simulation, directly resolving the time-dependent and unsteady features that dominate regions of massive separation. The current work applies DES to a 70 degree sweep delta wing at 27 degrees angle of attack, a geometrically simple yet challenging flowfield that exhibits the unsteady three-dimensional massively separated phenomena of vortex breakdown. After detailed examination of this basic flowfield, the method is demonstrated on three full aircraft of interest characterized by massive separation, the F-16 at 45 degrees angle of attack, the F-15 at 65 degree angle of attack (with comparison to flight test), and the C-130 in a parachute drop condition at near stall speed with cargo doors open.

Stress-dependent grain size evolution of nanocrystalline Ni-W and its impact on friction behavior

DOE PAGES

Argibay, N.; Furnish, T. A.; Boyce, B. L.; ...

2016-06-07

The friction behavior of ultra-nanocrystalline Ni-W coatings was investigated. A critical stress threshold was identified below which friction remained low, and above which a time-dependent evolution toward higher friction behavior occurred. Founded on established plasticity models we propose a correlation between surface grain size and applied stress that can be used to predict the critical stress separating the two friction regimes. Lastly, this interpretation of plasticity models suggests that macro-scale low and high friction regimes are respectively associated with the nano-scale mechanisms of grain boundary and dislocation-mediated plasticity.

Refining and validating the Social Interaction Anxiety Scale and the Social Phobia Scale.

PubMed

Carleton, R Nicholas; Collimore, Kelsey C; Asmundson, Gordon J G; McCabe, Randi E; Rowa, Karen; Antony, Martin M

2009-01-01

The Social Interaction Anxiety Scale and Social Phobia Scale are companion measures for assessing symptoms of social anxiety and social phobia. The scales have good reliability and validity across several samples, however, exploratory and confirmatory factor analyses have yielded solutions comprising substantially different item content and factor structures. These discrepancies are likely the result of analyzing items from each scale separately or simultaneously. The current investigation sets out to assess items from those scales, both simultaneously and separately, using exploratory and confirmatory factor analyses in an effort to resolve the factor structure. Participants consisted of a clinical sample (n 5353; 54% women) and an undergraduate sample (n 5317; 75% women) who completed the Social Interaction Anxiety Scale and Social Phobia Scale, along with additional fear-related measures to assess convergent and discriminant validity. A three-factor solution with a reduced set of items was found to be most stable, irrespective of whether the items from each scale are assessed together or separately. Items from the Social Interaction Anxiety Scale represented one factor, whereas items from the Social Phobia Scale represented two other factors. Initial support for scale and factor validity, along with implications and recommendations for future research, is provided. (c) 2009 Wiley-Liss, Inc.

Adaptive multiresolution modeling of groundwater flow in heterogeneous porous media

NASA Astrophysics Data System (ADS)

Malenica, Luka; Gotovac, Hrvoje; Srzic, Veljko; Andric, Ivo

2016-04-01

Proposed methodology was originally developed by our scientific team in Split who designed multiresolution approach for analyzing flow and transport processes in highly heterogeneous porous media. The main properties of the adaptive Fup multi-resolution approach are: 1) computational capabilities of Fup basis functions with compact support capable to resolve all spatial and temporal scales, 2) multi-resolution presentation of heterogeneity as well as all other input and output variables, 3) accurate, adaptive and efficient strategy and 4) semi-analytical properties which increase our understanding of usually complex flow and transport processes in porous media. The main computational idea behind this approach is to separately find the minimum number of basis functions and resolution levels necessary to describe each flow and transport variable with the desired accuracy on a particular adaptive grid. Therefore, each variable is separately analyzed, and the adaptive and multi-scale nature of the methodology enables not only computational efficiency and accuracy, but it also describes subsurface processes closely related to their understood physical interpretation. The methodology inherently supports a mesh-free procedure, avoiding the classical numerical integration, and yields continuous velocity and flux fields, which is vitally important for flow and transport simulations. In this paper, we will show recent improvements within the proposed methodology. Since "state of the art" multiresolution approach usually uses method of lines and only spatial adaptive procedure, temporal approximation was rarely considered as a multiscale. Therefore, novel adaptive implicit Fup integration scheme is developed, resolving all time scales within each global time step. It means that algorithm uses smaller time steps only in lines where solution changes are intensive. Application of Fup basis functions enables continuous time approximation, simple interpolation calculations across different temporal lines and local time stepping control. Critical aspect of time integration accuracy is construction of spatial stencil due to accurate calculation of spatial derivatives. Since common approach applied for wavelets and splines uses a finite difference operator, we developed here collocation one including solution values and differential operator. In this way, new improved algorithm is adaptive in space and time enabling accurate solution for groundwater flow problems, especially in highly heterogeneous porous media with large lnK variances and different correlation length scales. In addition, differences between collocation and finite volume approaches are discussed. Finally, results show application of methodology to the groundwater flow problems in highly heterogeneous confined and unconfined aquifers.

Mitigating nonlinearity in full waveform inversion using scaled-Sobolev pre-conditioning

NASA Astrophysics Data System (ADS)

Zuberi, M. AH; Pratt, R. G.

2018-04-01

The Born approximation successfully linearizes seismic full waveform inversion if the background velocity is sufficiently accurate. When the background velocity is not known it can be estimated by using model scale separation methods. A frequently used technique is to separate the spatial scales of the model according to the scattering angles present in the data, by using either first- or second-order terms in the Born series. For example, the well-known `banana-donut' and the `rabbit ear' shaped kernels are, respectively, the first- and second-order Born terms in which at least one of the scattering events is associated with a large angle. Whichever term of the Born series is used, all such methods suffer from errors in the starting velocity model because all terms in the Born series assume that the background Green's function is known. An alternative approach to Born-based scale separation is to work in the model domain, for example, by Gaussian smoothing of the update vectors, or some other approach for separation by model wavenumbers. However such model domain methods are usually based on a strict separation in which only the low-wavenumber updates are retained. This implies that the scattered information in the data is not taken into account. This can lead to the inversion being trapped in a false (local) minimum when sharp features are updated incorrectly. In this study we propose a scaled-Sobolev pre-conditioning (SSP) of the updates to achieve a constrained scale separation in the model domain. The SSP is obtained by introducing a scaled Sobolev inner product (SSIP) into the measure of the gradient of the objective function with respect to the model parameters. This modified measure seeks reductions in the L2 norm of the spatial derivatives of the gradient without changing the objective function. The SSP does not rely on the Born prediction of scale based on scattering angles, and requires negligible extra computational cost per iteration. Synthetic examples from the Marmousi model show that the constrained scale separation using SSP is able to keep the background updates in the zone of attraction of the global minimum, in spite of using a poor starting model in which conventional methods fail.

The 1,800-year oceanic tidal cycle: A possible cause of rapid climate change

PubMed Central

Keeling, Charles D.; Whorf, Timothy P.

2000-01-01

Variations in solar irradiance are widely believed to explain climatic change on 20,000- to 100,000-year time-scales in accordance with the Milankovitch theory of the ice ages, but there is no conclusive evidence that variable irradiance can be the cause of abrupt fluctuations in climate on time-scales as short as 1,000 years. We propose that such abrupt millennial changes, seen in ice and sedimentary core records, were produced in part by well characterized, almost periodic variations in the strength of the global oceanic tide-raising forces caused by resonances in the periodic motions of the earth and moon. A well defined 1,800-year tidal cycle is associated with gradually shifting lunar declination from one episode of maximum tidal forcing on the centennial time-scale to the next. An amplitude modulation of this cycle occurs with an average period of about 5,000 years, associated with gradually shifting separation-intervals between perihelion and syzygy at maxima of the 1,800-year cycle. We propose that strong tidal forcing causes cooling at the sea surface by increasing vertical mixing in the oceans. On the millennial time-scale, this tidal hypothesis is supported by findings, from sedimentary records of ice-rafting debris, that ocean waters cooled close to the times predicted for strong tidal forcing. PMID:10725399

A longitudinal evaluation of the Center for Epidemiologic Studies-Depression scale (CES-D) in a Rheumatoid Arthritis Population using Rasch Analysis

PubMed Central

Covic, Tanya; Pallant, Julie F; Conaghan, Philip G; Tennant, Alan

2007-01-01

Background The aim of this study was to test the internal validity of the total Center for Epidemiologic Studies-Depression (CES-D) scale using Rasch analysis in a rheumatoid arthritis (RA) population. Methods CES-D was administered to 157 patients with RA over three time points within a 12 month period. Rasch analysis was applied using RUMM2020 software to assess the overall fit of the model, the response scale used, individual item fit, differential item functioning (DIF) and person separation. Results Pooled data across three time points was shown to fit the Rasch model with removal of seven items from the original 20-item CES-D scale. It was necessary to rescore the response format from four to three categories in order to improve the scale's fit. Two items demonstrated some DIF for age and gender but were retained within the 13-item CES-D scale. A new cut point for depression score of 9 was found to correspond to the original cut point score of 16 in the full CES-D scale. Conclusion This Rasch analysis of the CES-D in a longstanding RA cohort resulted in the construction of a modified 13-item scale with good internal validity. Further validation of the modified scale is recommended particularly in relation to the new cut point for depression. PMID:17629902

A simple transferable adaptive potential to study phase separation in large-scale xMgO-(1-x)SiO2 binary glasses.

PubMed

Bidault, Xavier; Chaussedent, Stéphane; Blanc, Wilfried

2015-10-21

A simple transferable adaptive model is developed and it allows for the first time to simulate by molecular dynamics the separation of large phases in the MgO-SiO2 binary system, as experimentally observed and as predicted by the phase diagram, meaning that separated phases have various compositions. This is a real improvement over fixed-charge models, which are often limited to an interpretation involving the formation of pure clusters, or involving the modified random network model. Our adaptive model, efficient to reproduce known crystalline and glassy structures, allows us to track the formation of large amorphous Mg-rich Si-poor nanoparticles in an Mg-poor Si-rich matrix from a 0.1MgO-0.9SiO2 melt.

Quantum superposition at the half-metre scale.

PubMed

Kovachy, T; Asenbaum, P; Overstreet, C; Donnelly, C A; Dickerson, S M; Sugarbaker, A; Hogan, J M; Kasevich, M A

2015-12-24

The quantum superposition principle allows massive particles to be delocalized over distant positions. Though quantum mechanics has proved adept at describing the microscopic world, quantum superposition runs counter to intuitive conceptions of reality and locality when extended to the macroscopic scale, as exemplified by the thought experiment of Schrödinger's cat. Matter-wave interferometers, which split and recombine wave packets in order to observe interference, provide a way to probe the superposition principle on macroscopic scales and explore the transition to classical physics. In such experiments, large wave-packet separation is impeded by the need for long interaction times and large momentum beam splitters, which cause susceptibility to dephasing and decoherence. Here we use light-pulse atom interferometry to realize quantum interference with wave packets separated by up to 54 centimetres on a timescale of 1 second. These results push quantum superposition into a new macroscopic regime, demonstrating that quantum superposition remains possible at the distances and timescales of everyday life. The sub-nanokelvin temperatures of the atoms and a compensation of transverse optical forces enable a large separation while maintaining an interference contrast of 28 per cent. In addition to testing the superposition principle in a new regime, large quantum superposition states are vital to exploring gravity with atom interferometers in greater detail. We anticipate that these states could be used to increase sensitivity in tests of the equivalence principle, measure the gravitational Aharonov-Bohm effect, and eventually detect gravitational waves and phase shifts associated with general relativity.

Parallel computation of fluid-structural interactions using high resolution upwind schemes

NASA Astrophysics Data System (ADS)

Hu, Zongjun

An efficient and accurate solver is developed to simulate the non-linear fluid-structural interactions in turbomachinery flutter flows. A new low diffusion E-CUSP scheme, Zha CUSP scheme, is developed to improve the efficiency and accuracy of the inviscid flux computation. The 3D unsteady Navier-Stokes equations with the Baldwin-Lomax turbulence model are solved using the finite volume method with the dual-time stepping scheme. The linearized equations are solved with Gauss-Seidel line iterations. The parallel computation is implemented using MPI protocol. The solver is validated with 2D cases for its turbulence modeling, parallel computation and unsteady calculation. The Zha CUSP scheme is validated with 2D cases, including a supersonic flat plate boundary layer, a transonic converging-diverging nozzle and a transonic inlet diffuser. The Zha CUSP2 scheme is tested with 3D cases, including a circular-to-rectangular nozzle, a subsonic compressor cascade and a transonic channel. The Zha CUSP schemes are proved to be accurate, robust and efficient in these tests. The steady and unsteady separation flows in a 3D stationary cascade under high incidence and three inlet Mach numbers are calculated to study the steady state separation flow patterns and their unsteady oscillation characteristics. The leading edge vortex shedding is the mechanism behind the unsteady characteristics of the high incidence separated flows. The separation flow characteristics is affected by the inlet Mach number. The blade aeroelasticity of a linear cascade with forced oscillating blades is studied using parallel computation. A simplified two-passage cascade with periodic boundary condition is first calculated under a medium frequency and a low incidence. The full scale cascade with 9 blades and two end walls is then studied more extensively under three oscillation frequencies and two incidence angles. The end wall influence and the blade stability are studied and compared under different frequencies and incidence angles. The Zha CUSP schemes are the first time to be applied in moving grid systems and 2D and 3D calculations. The implicit Gauss-Seidel iteration with dual time stepping is the first time to be used for moving grid systems. The NASA flutter cascade is the first time to be calculated in full scale.

Material Recycling and Waste Minimization by Freeze Crystallization. Phase 1

DTIC Science & Technology

1995-05-01

or centrifuge for recovery. DESIGN PARAMETERS - Crystallizer Gives direct scale-up information. - Eutectic Salt Separation Gives direct scale-up...because of sfer rates and crystal kinetics, differences in crystallizer construction. - Eutectic Salt Separation No ability in this system. - Wash Columns

The effects of display variables and secondary loading on the dual axis critical task performance

NASA Technical Reports Server (NTRS)

Swisher, G. M.; Nataraj, S.

1973-01-01

The effects of scanning displays for separated instruments, separated versus combined displays, and the effects of secondary loading are investigated. An operator rating scale for handling qualities is established analogous to the Cooper Harper Scale.

Document image binarization using "multi-scale" predefined filters

NASA Astrophysics Data System (ADS)

Saabni, Raid M.

2018-04-01

Reading text or searching for key words within a historical document is a very challenging task. one of the first steps of the complete task is binarization, where we separate foreground such as text, figures and drawings from the background. Successful results of this important step in many cases can determine next steps to success or failure, therefore it is very vital to the success of the complete task of reading and analyzing the content of a document image. Generally, historical documents images are of poor quality due to their storage condition and degradation over time, which mostly cause to varying contrasts, stains, dirt and seeping ink from reverse side. In this paper, we use banks of anisotropic predefined filters in different scales and orientations to develop a binarization method for degraded documents and manuscripts. Using the fact, that handwritten strokes may follow different scales and orientations, we use predefined sets of filter banks having various scales, weights, and orientations to seek a compact set of filters and weights in order to generate diffrent layers of foregrounds and background. Results of convolving these fiters on the gray level image locally, weighted and accumulated to enhance the original image. Based on the different layers, seeds of components in the gray level image and a learning process, we present an improved binarization algorithm to separate the background from layers of foreground. Different layers of foreground which may be caused by seeping ink, degradation or other factors are also separated from the real foreground in a second phase. Promising experimental results were obtained on the DIBCO2011 , DIBCO2013 and H-DIBCO2016 data sets and a collection of images taken from real historical documents.

Terrestrial Testing of the CapiBRIC, a Microgravity Optimized Brine Processor

NASA Technical Reports Server (NTRS)

Sargusingh, Miriam J.; Callahan, Michael R.; Weislogel, Mark M.

2016-01-01

Utilizing geometry based static phase separation exhibited in the radial vaned capillary drying tray, a system was conceived to recover water from brine. This technology has been named the Capillary BRIC; abbreviated CapiBRIC. The CapiBRIC utilizes a capillary drying tray within a drying chamber. Water is recovered from clean water vapor evaporating from the free surface leaving waste brine solids behind. A novel approach of optimizing the containment geometry to support passive capillary flow and static phase separation provides the opportunity for a low power system that is not as susceptible to fouling as membranes or other technologies employing physical barriers across the free brine surface to achieve phase separation in microgravity. Having been optimized for operation in microgravity, full-scale testing of the CapiBRIC as designed cannot be performed on the ground as the force of gravity would dominate over the capillary forces. However, subscale units relevant to full-scale design were used to characterize fill rates, containment stability, and interaction with a variable volume reservoir in the PSU Dryden Drop Tower (DDT) facility. PSU also using tested units scaled such that capillary forces dominated in a 1-g environment to characterize evaporation from a free-surface in 1-g upward, sideways and downward orientations. In order to augment the subscale testing performed by PSU, a full scale 1-g analogue of the CapiBRIC drying unit was initiated to help validate performance predictions regarding expected water recovery ratio, estimated processing time, and interface definitions for inlets, outlets, and internal processes, including vent gas composition. This paper describes the design, development and test of the terrestrial CapiBRIC prototypes.

Design of a TW-SLIM Module for Dual Polarity Confinement, Transport, and Reactions

DOE Office of Scientific and Technical Information (OSTI.GOV)

Garimella, Sandilya V. B.; Webb, Ian K.; Prabhakaran, Aneesh

2017-05-30

Here we describe instrumental approaches for performing dual polarity ion confinement, transport, ion mobility separations and reactions in Structures for Lossless Ion Manipulations (SLIM). Previous means of ion confinement in SLIM based upon rf- generated pseudopotentials and dc fields for lateral confinement cannot trap ions of opposite polarity simultaneously. Here we explore alternative approaches to provide lateral confinement of both ion polarities. Traveling wave ion mobility (IM) separations experienced by both polarities in such SLIM cause ions of both polarities migrate in the same directions and exhibit similar separations. The ion motion (and relative motion of the two polarities) undermore » both surfing and IM separation conditions are discussed. Strategies to separate the two populations to minimize reactive losses during transport are presented. A theoretical treatment of the time scales over which two populations (injected into a dc field-free region of the dual polarity SLIM device) interact is considered, and SLIM designs for allowing ion/ion interactions and other manipulations with dual polarities at 4 torr are presented.« less

Accessible methods for the dynamic time-scale decomposition of biochemical systems.

PubMed

Surovtsova, Irina; Simus, Natalia; Lorenz, Thomas; König, Artjom; Sahle, Sven; Kummer, Ursula

2009-11-01

The growing complexity of biochemical models asks for means to rationally dissect the networks into meaningful and rather independent subnetworks. Such foregoing should ensure an understanding of the system without any heuristics employed. Important for the success of such an approach is its accessibility and the clarity of the presentation of the results. In order to achieve this goal, we developed a method which is a modification of the classical approach of time-scale separation. This modified method as well as the more classical approach have been implemented for time-dependent application within the widely used software COPASI. The implementation includes different possibilities for the representation of the results including 3D-visualization. The methods are included in COPASI which is free for academic use and available at www.copasi.org. irina.surovtsova@bioquant.uni-heidelberg.de Supplementary data are available at Bioinformatics online.

Mass spectrometric-based stable isotopic 2-aminobenzoic acid glycan mapping for rapid glycan screening of biotherapeutics.

PubMed

Prien, Justin M; Prater, Bradley D; Qin, Qiang; Cockrill, Steven L

2010-02-15

Fast, sensitive, robust methods for "high-level" glycan screening are necessary during various stages of a biotherapeutic product's lifecycle, including clone selection, process changes, and quality control for lot release testing. Traditional glycan screening involves chromatographic or electrophoretic separation-based methods, and, although reproducible, these methods can be time-consuming. Even ultrahigh-performance chromatographic and microfluidic integrated LC/MS systems, which work on the tens of minute time scale, become lengthy when hundreds of samples are to be analyzed. Comparatively, a direct infusion mass spectrometry (MS)-based glycan screening method acquires data on a millisecond time scale, exhibits exquisite sensitivity and reproducibility, and is amenable to automated peak annotation. In addition, characterization of glycan species via sequential mass spectrometry can be performed simultaneously. Here, we demonstrate a quantitative high-throughput MS-based mapping approach using stable isotope 2-aminobenzoic acid (2-AA) for rapid "high-level" glycan screening.

Temporal separation and self-rating of alertness as indicators of driver fatigue in commercial motor vehicle operators.

PubMed

Belz, Steven M; Robinson, Gary S; Casali, John G

2004-01-01

This on-road field investigation employed, for the first time, a completely automated trigger-based data collection system capable of evaluating driver performance in an extended-duration real-world commercial motor vehicle environment. The study examined the use of self-assessment of fatigue (Karolinska Sleepiness Scale) and temporal separation (minimum time to collision, minimum headway, and mean headway) as indicators of driver fatigue. Without exception, the correlation analyses for both the self-rating of alertness and temporal separation yielded models low in associative ability; neither metric was found to be a valid indicator of driver fatigue. In addition, based upon the data collected for this research, preliminary evidence suggests that driver fatigue onset within a real-world driving environment does not appear to follow the standard progression of events associated with the onset of fatigue within a simulated driving environment. Application of this research includes the development of an on-board driver performance/fatigue monitoring system that could potentially assist drivers in identifying the onset of fatigue.

Dynamics of phase separation of binary fluids

NASA Technical Reports Server (NTRS)

Ma, Wen-Jong; Maritan, Amos; Banavar, Jayanth R.; Koplik, Joel

1992-01-01

The results of molecular-dynamics studies of surface-tension-dominated spinodal decomposition of initially well-mixed binary fluids in the absence and presence of gravity are presented. The growth exponent for the domain size and the decay exponent of the potential energy of interaction between the two species with time are found to be 0.6 +/- 0.1, inconsistent with scaling arguments based on dimensional analysis.

Rational and Efficient Preparative Isolation of Natural Products by MPLC-UV-ELSD based on HPLC to MPLC Gradient Transfer.

PubMed

Challal, Soura; Queiroz, Emerson Ferreira; Debrus, Benjamin; Kloeti, Werner; Guillarme, Davy; Gupta, Mahabir Prashad; Wolfender, Jean-Luc

2015-11-01

In natural product research, the isolation of biomarkers or bioactive compounds from complex natural extracts represents an essential step for de novo identification and bioactivity assessment. When pure natural products have to be obtained in milligram quantities, the chromatographic steps are generally labourious and time-consuming. In this respect, an efficient method has been developed for the reversed-phase gradient transfer from high-performance liquid chromatography to medium-performance liquid chromatography for the isolation of pure natural products at the level of tens of milligrams from complex crude natural extracts. The proposed method provides a rational way to predict retention behaviour and resolution at the analytical scale prior to medium-performance liquid chromatography, and guarantees similar performances at both analytical and preparative scales. The optimisation of the high-performance liquid chromatography separation and system characterisation allows for the prediction of the gradient at the medium-performance liquid chromatography scale by using identical stationary phase chemistries. The samples were introduced in medium-performance liquid chromatography using a pressure-resistant aluminium dry load cell especially designed for this study to allow high sample loading while maintaining a maximum achievable flow rate for the separation. The method has been validated with a mixture of eight natural product standards. Ultraviolet and evaporative light scattering detections were used in parallel for a comprehensive monitoring. In addition, post-chromatographic mass spectrometry detection was provided by high-throughput ultrahigh-performance liquid chromatography time-of-flight mass spectrometry analyses of all fractions. The processing of all liquid chromatography-mass spectrometry data in the form of an medium-performance liquid chromatography x ultra high-performance liquid chromatography time-of-flight mass spectrometry matrix enabled an efficient localisation of the compounds of interest in the generated fractions. The methodology was successfully applied for the separation of three different plant extracts that contain many diverse secondary metabolites. The advantages and limitations of this approach and the theoretical chromatographic background that rules such as liquid chromatography gradient transfer are presented from a practical viewpoint. Georg Thieme Verlag KG Stuttgart · New York.

Population connectivity of deep-sea corals: Chapter 12

USGS Publications Warehouse

Morrison, Cheryl L.; Baco, Amy; Nizinski, Martha S.; Coykendall, D. Katharine; Demopoulos, Amanda W. J.; Cho, Walter; Shank, Tim

2015-01-01

Identifying the scale of dispersal among habitats has been a challenge in marine ecology for decades (Grantham et al., 2003; Kinlan & Gaines, 2003; Hixon, 2011). Unlike terrestrial habitats in which barriers to dispersal may be obvious (e.g. mountain ranges, rivers), few absolute barriers to dispersal are recognizable in the sea. Additionally, most marine species have complex life cycles in which juveniles are more mobile than adults. As such, the dynamics of populations may involve processes in distant habitats that are coupled by a transport mechanism. Studies of population connectivity try to quantify the transport, or dispersal of individuals, among geographically separated populations. For benthic marine species, such as corals and demersal fishes, colonization of new populations occurs primarily by dispersal of larvae (Figure 1; Shank, 2010). Successful dispersal and recruitment, followed by maturation and reproduction of these new migrants ensures individuals contribute to the gene pool (Hedgecock, 2007). Thus, successful dispersal links and cohesively maintains spatially separated sub-populations. At shorter time scales (10-100s years), connectivity regulates community structure by influencing the genetic composition, diversity and demographic stability of the population, whereas at longer time scales (1000s years), geographic distributions are affected (McClain and Hardy, 2010). Alternatively, populations may become extinct or speciation may occur if connectivity ceases (Cowen et al., 2007). Therefore, the genetic exchange of individuals between populations is fundamental to the short-term resilience and long-term maintenance of the species. However, for the vast majority of marine species, population connectivity remains poorly understood.

Examining the uniqueness of frequency and intensity symptom ratings in posttraumatic stress disorder assessment.

PubMed

Elhai, Jon D; Lindsay, Brenda M; Gray, Matt J; Grubaugh, Anouk L; North, Terry C; Frueh, B Christopher

2006-12-01

Data from two studies are presented, investigating the relative effectiveness of posttraumatic stress disorder (PTSD) symptom frequency and intensity rating dimensions, in assessing overall PTSD severity and diagnosis. We assessed frequency and intensity ratings using 1) the Modified PTSD Symptom Scale with 298 trauma-exposed college students, and 2) the Clinician-Administered PTSD Scale with 130 combat-exposed military veterans. Results demonstrated little empirical justification for separating frequency and intensity ratings when measuring PTSD. Large overlaps in variance were evidenced between the dimensions (suggesting construct redundancy), with little meaningful contribution to diagnosing PTSD using one dimension over the other. Implications for future PTSD clinical and research assessment are discussed, including the potential to decrease administration time for these commonly used PTSD measures, given their time-consuming nature.

Time-resolved spectroscopy using a chopper wheel as a fast shutter

DOE Office of Scientific and Technical Information (OSTI.GOV)

Wang, Shicong; Wendt, Amy E.; Boffard, John B.

Widely available, small form-factor, fiber-coupled spectrometers typically have a minimum exposure time measured in milliseconds, and thus cannot be used directly for time-resolved measurements at the microsecond level. Spectroscopy at these faster time scales is typically done with an intensified charge coupled device (CCD) system where the image intensifier acts as a “fast” electronic shutter for the slower CCD array. In this paper, we describe simple modifications to a commercially available chopper wheel system to allow it to be used as a “fast” mechanical shutter for gating a fiber-coupled spectrometer to achieve microsecond-scale time-resolved optical measurements of a periodically pulsedmore » light source. With the chopper wheel synchronized to the pulsing of the light source, the time resolution can be set to a small fraction of the pulse period by using a chopper wheel with narrow slots separated by wide spokes. Different methods of synchronizing the chopper wheel and pulsing of the light sources are explored. The capability of the chopper wheel system is illustrated with time-resolved measurements of pulsed plasmas.« less

Adaptation and learning: characteristic time scales of performance dynamics.

PubMed

Newell, Karl M; Mayer-Kress, Gottfried; Hong, S Lee; Liu, Yeou-Teh

2009-12-01

A multiple time scales landscape model is presented that reveals structures of performance dynamics that were not resolved in the traditional power law analysis of motor learning. It shows the co-existence of separate processes during and between practice sessions that evolve in two independent dimensions characterized by time scales that differ by about an order of magnitude. Performance along the slow persistent dimension of learning improves often as much and sometimes more during rest (memory consolidation and/or insight generation processes) than during a practice session itself. In contrast, the process characterized by the fast, transient dimension of adaptation reverses direction between practice sessions, thereby significantly degrading performance at the beginning of the next practice session (warm-up decrement). The theoretical model fits qualitatively and quantitatively the data from Snoddy's [Snoddy, G. S. (1926). Learning and stability. Journal of Applied Psychology, 10, 1-36] classic learning study of mirror tracing and other averaged and individual data sets, and provides a new account of the processes of change in adaptation and learning. 2009 Elsevier B.V. All rights reserved.

The Physics of Boiling at Burnout

NASA Technical Reports Server (NTRS)

Theofanous, T. G.; Tu, J. P.; Dinh, T. N.; Salmassi, T.; Dinh, A. T.; Gasljevic, K.

2000-01-01

The basic elements of a new experimental approach for the investigation of burnout in pool boiling are presented. The approach consists of the combined use of ultrathin (nano-scale) heaters and high speed infrared imaging of the heater temperature pattern as a whole, in conjunction with highly detailed control and characterization of heater morphology at the nano and micron scales. It is shown that the burnout phenomenon can be resolved in both space and time. Ultrathin heaters capable of dissipating power levels, at steady-state, of over 1 MW/square m are demonstrated. A separation of scales is identified and it is used to transfer the focus of attention from the complexity of the two-phase mixing layer in the vicinity of the heater to a micron-scaled microlayer and nucleation and associated film-disruption processes within it.

A Synergistic Combination of Advanced Separation and Chemical Scale Inhibitor Technologies for Efficient Use of Imparied Water As Cooling Water in Coal-based Power Plants

DOE Office of Scientific and Technical Information (OSTI.GOV)

Jasbir Gill

2010-08-30

Nalco Company is partnering with Argonne National Laboratory (ANL) in this project to jointly develop advanced scale control technologies that will provide cost-effective solutions for coal-based power plants to operate recirculating cooling water systems at high cycles using impaired waters. The overall approach is to use combinations of novel membrane separations and scale inhibitor technologies that will work synergistically, with membrane separations reducing the scaling potential of the cooling water and scale inhibitors extending the safe operating range of the cooling water system. The project started on March 31, 2006 and ended in August 30, 2010. The project was amore » multiyear, multi-phase project with laboratory research and development as well as a small pilot-scale field demonstration. In Phase 1 (Technical Targets and Proof of Concept), the objectives were to establish quantitative technical targets and develop calcite and silica scale inhibitor chemistries for high stress conditions. Additional Phase I work included bench-scale testing to determine the feasibility of two membrane separation technologies (electrodialysis ED and electrode-ionization EDI) for scale minimization. In Phase 2 (Technology Development and Integration), the objectives were to develop additional novel scale inhibitor chemistries, develop selected separation processes, and optimize the integration of the technology components at the laboratory scale. Phase 3 (Technology Validation) validated the integrated system's performance with a pilot-scale demonstration. During Phase 1, Initial evaluations of impaired water characteristics focused on produced waters and reclaimed municipal wastewater effluents. Literature and new data were collected and evaluated. Characteristics of produced waters vary significantly from one site to another, whereas reclaimed municipal wastewater effluents have relatively more uniform characteristics. Assessment to date confirmed that calcite and silica/silicate are two common potential cycle-limiting minerals for using impaired waters. For produced waters, barium sulfate and calcium sulfate are two additional potential cycle-limiting minerals. For reclaimed municipal wastewater effluents, calcium phosphate scaling can be an issue, especially in the co-presence of high silica. Computational assessment, using a vast amount of Nalco's field data from coal fired power plants, showed that the limited use and reuse of impaired waters is due to the formation of deposit caused by the presence of iron, high hardness, high silica and high alkalinity in the water. Appropriate and cost-effective inhibitors were identified and developed - LL99B0 for calcite and gypsum inhibition and TX-15060 for silica inhibition. Nalco's existing dispersants HSP-1 and HSP-2 has excellent efficacy for dispersing Fe and Mn. ED and EDI were bench-scale tested by the CRADA partner Argonne National Laboratory for hardness, alkalinity and silica removal from synthetic make-up water and then cycled cooling water. Both systems showed low power consumption and 98-99% salt removal, however, the EDI system required 25-30% less power for silica removal. For Phase 2, the EDI system's performance was optimized and the length of time between clean-in-place (CIP) increased by varying the wafer composition and membrane configuration. The enhanced EDI system could remove 88% of the hardness and 99% of the alkalinity with a processing flux of 19.2 gal/hr/m{sup 2} and a power consumption of 0.54 kWh/100 gal water. Bench tests to screen alternative silica/silicate scale inhibitor chemistries have begun. The silica/silicate control approaches using chemical inhibitors include inhibition of silicic acid polymerization and dispersion of silica/silicate crystals. Tests were conducted with an initial silica concentration of 290-300 mg/L as SiO{sub 2} at pH 7 and room temperature. A proprietary new chemistry was found to be promising, compared with a current commercial product commonly used for silica/silicate control. Additional pilot cooling tower testing confirmed the bench study. We also developed a molecule to inhibit calcium carbonate precipitation and calcium sulfate precipitation at high supersaturations. During Phase 3, a long-term test of the EDI system and scale inhibitors was done at Nalco's cooling tower water testing facility, producing 850 gallons of high purity water (90+% salt removal) at a rate of 220 L/day. The EDI system's performance was stable when the salt concentration in the concentrate compartment (i.e. the EDI waste stream) was controlled and a CIP was done after every 48 hours of operation time. A combination of EDI and scale inhibitors completely eliminated blowdown discharge from the Pilot cooling Tower. The only water-consumption came from evaporation, CIP and EDI concentrate. Silica Inhibitor was evaluated in the field at a western coal fired power plant.« less

Pathways for diffusion in the potential energy landscape of the network glass former SiO2

NASA Astrophysics Data System (ADS)

Niblett, S. P.; Biedermann, M.; Wales, D. J.; de Souza, V. K.

2017-10-01

We study the dynamical behaviour of a computer model for viscous silica, the archetypal strong glass former, and compare its diffusion mechanism with earlier studies of a fragile binary Lennard-Jones liquid. Three different methods of analysis are employed. First, the temperature and time scale dependence of the diffusion constant is analysed. Negative correlation of particle displacements influences transport properties in silica as well as in fragile liquids. We suggest that the difference between Arrhenius and super-Arrhenius diffusive behaviour results from competition between the correlation time scale and the caging time scale. Second, we analyse the dynamics using a geometrical definition of cage-breaking transitions that was proposed previously for fragile glass formers. We find that this definition accurately captures the bond rearrangement mechanisms that control transport in open network liquids, and reproduces the diffusion constants accurately at low temperatures. As the same method is applicable to both strong and fragile glass formers, we can compare correlation time scales in these two types of systems. We compare the time spent in chains of correlated cage breaks with the characteristic caging time and find that correlations in the fragile binary Lennard-Jones system persist for an order of magnitude longer than those in the strong silica system. We investigate the origin of the correlation behaviour by sampling the potential energy landscape for silica and comparing it with the binary Lennard-Jones model. We find no qualitative difference between the landscapes, but several metrics suggest that the landscape of the fragile liquid is rougher and more frustrated. Metabasins in silica are smaller than those in binary Lennard-Jones and contain fewer high-barrier processes. This difference probably leads to the observed separation of correlation and caging time scales.

Negative Emissions Technology

NASA Astrophysics Data System (ADS)

Day, Danny

2006-04-01

Although `negative emissions' of carbon dioxide need not, in principle, involve use of biological processes to draw carbon out of the atmosphere, such `agricultural' sequestration' is the only known way to remove carbon from the atmosphere on time scales comparable to the time scale for anthropogenic increases in carbon emissions. In order to maintain the `negative emissions' the biomass must be used in such a way that the resulting carbon dioxide is separated and permanently sequestered. Two options for sequestration are in the topsoil and via geologic carbon sequestration. The former has multiple benefits, but the latter also is needed. Thus, although geologic carbon sequestration is viewed skeptically by some environmentalists as simply a way to keep using fossil fuels---it may be a key part of reversing accelerating climate forcing if rapid climate change is beginning to occur. I will first review the general approach of agricultural sequestration combined with use of resulting biofuels in a way that permits carbon separation and then geologic sequestration as a negative emissions technology. Then I discuss the process that is the focus of my company---the EPRIDA cycle. If deployed at a sufficiently large scale, it could reverse the increase in CO2 concentrations. I also estimate of benefits --carbon and other---of large scale deployment of negative emissions technologies. For example, using the EPRIDA cycle by planting and soil sequestering carbon in an area abut In 3X the size of Texas would remove the amount of carbon that is being accumulated worldwide each year. In addition to the atmospheric carbon removal, the EPRIDA approach also counters the depletion of carbon in the soil---increasing topsoil and its fertility; reduces the excess nitrogen in the water by eliminating the need for ammonium nitrate fertilizer and reduces fossil fuel reliance by providing biofuel and avoiding natural gas based fertilizer production.

Size-selective sorting in bubble streaming flows: Particle migration on fast time scales

NASA Astrophysics Data System (ADS)

Thameem, Raqeeb; Rallabandi, Bhargav; Hilgenfeldt, Sascha

2015-11-01

Steady streaming from ultrasonically driven microbubbles is an increasingly popular technique in microfluidics because such devices are easily manufactured and generate powerful and highly controllable flows. Combining streaming and Poiseuille transport flows allows for passive size-sensitive sorting at particle sizes and selectivities much smaller than the bubble radius. The crucial particle deflection and separation takes place over very small times (milliseconds) and length scales (20-30 microns) and can be rationalized using a simplified geometric mechanism. A quantitative theoretical description is achieved through the application of recent results on three-dimensional streaming flow field contributions. To develop a more fundamental understanding of the particle dynamics, we use high-speed photography of trajectories in polydisperse particle suspensions, recording the particle motion on the time scale of the bubble oscillation. Our data reveal the dependence of particle displacement on driving phase, particle size, oscillatory flow speed, and streaming speed. With this information, the effective repulsive force exerted by the bubble on the particle can be quantified, showing for the first time how fast, selective particle migration is effected in a streaming flow. We acknowledge support by the National Science Foundation under grant number CBET-1236141.

An experimental study of large-scale vortices over a blunt-faced flat plate in pulsating flow

NASA Astrophysics Data System (ADS)

Hwang, K. S.; Sung, H. J.; Hyun, J. M.

Laboratory measurements are made of flow over a blunt flat plate of finite thickness, which is placed in a pulsating free stream, U=Uo(1+Aocos 2πfpt). Low turbulence-intensity wind tunnel experiments are conducted in the ranges of Stp<=1.23 and Ao<=0.118 at ReH=560. Pulsation is generated by means of a woofer speaker. Variations of the time-mean reattachment length xR as functions of Stp and Ao are scrutinized by using the forward-time fraction and surface pressure distributions (Cp). The shedding frequency of large-scale vortices due to pulsation is measured. Flow visualizations depict the behavior of large-scale vortices. The results for non-pulsating flows (Ao=0) are consistent with the published data. In the lower range of Ao, as Stp increases, xR attains a minimum value at a particular pulsation frequency. For large Ao, the results show complicated behaviors of xR. For Stp>=0.80, changes in xR are insignificant as Ao increases. The shedding frequency of large-scale vortices is locked-in to the pulsation frequency. A vortex-pairing process takes place between two neighboring large-scale vortices in the separated shear layer.

Intense Current Structures Observed at Electron Kinetic Scales in the Near-Earth Magnetotail During Dipolarization and Substorm Current Wedge Formation

NASA Astrophysics Data System (ADS)

Grigorenko, E. E.; Dubyagin, S.; Malykhin, A. Yu.; Khotyaintsev, Yu V.; Kronberg, E. A.; Lavraud, B.; Ganushkina, N. Yu

2018-01-01

We use data from the 2013-2014 Cluster Inner Magnetosphere Campaign, with its uniquely small spacecraft separations (less than or equal to electron inertia length, λe), to study multiscale magnetic structures in 14 substorm-related prolonged dipolarizations in the near-Earth magnetotail. Three time scales of dipolarization are identified: (i) a prolonged growth of the BZ component with duration ≤20 min; (ii) BZ pulses with durations ≤1 min during the BZ growth; and (iii) strong magnetic field gradients with durations ≤2 s during the dipolarization growth. The values of these gradients observed at electron scales are several dozen times larger than the corresponding values of magnetic gradients simultaneously detected at ion scales. These nonlinear features in magnetic field gradients denote the formation of intense and localized (approximately a few λe) current structures during the dipolarization and substorm current wedge formation. These observations highlight the importance of electron scale processes in the formation of a 3-D substorm current system.

On measuring time metaphors.

PubMed

Sobol-Kwapinska, Malgorzata; Oles, Piotr K

2007-02-01

Referring to the 2005 article by Wittmann and Lehnhoff, the problem of using time metaphors for measuring awareness of time is posed. Starting from clarification of meaning, the Metaphors Slowness scale which was not homogeneous, an alternative interpretation of the result was proposed, given that metaphors refer to two separate aspects of time speed, an ongoing passage of time, and ex post reflection on passage of time that has already passed. The former refers to the judgment of an ongoing passage of time, and the latter to the judgment of passage of past time from a particular point in the past till now. Time perception is multifaceted and perhaps ambiguous. This particular aspect of time perception is covered by a notion of a "dialectical time", when opposite aspects of time are combined, e.g., pleasant and unpleasant ones.

Nurses' short-term prediction of violence in acute psychiatric intensive care.

PubMed

Björkdahl, A; Olsson, D; Palmstierna, T

2006-03-01

To evaluate the short-term predictive capacity of the Brøset Violence Checklist (BVC) when used by nurses in a psychiatric intensive care unit. Seventy-three patients were assessed according to the BVC three times daily. Violent incidents were recorded with the Staff Observation Aggression Scale, revised version. An extended Cox proportional hazards model with multiple events and time-dependent covariates was estimated to evaluate how the highest BVC sum of the last 24 h and its separate items affect the risk for severe violence within the next 24 h. With a BVC sum of one or more, hazard for severe violence was six times higher than if the sum was zero. Four of the six separate items significantly increased the risk for severe violence with hazard ratios between 3.0 and 6.3. Risk for in-patient violence in a short-term perspective can to a high degree be predicted by nurses using the BVC.

[Object Separation from Medical X-Ray Images Based on ICA].

PubMed

Li, Yan; Yu, Chun-yu; Miao, Ya-jian; Fei, Bin; Zhuang, Feng-yun

2015-03-01

X-ray medical image can examine diseased tissue of patients and has important reference value for medical diagnosis. With the problems that traditional X-ray images have noise, poor level sense and blocked aliasing organs, this paper proposes a method for the introduction of multi-spectrum X-ray imaging and independent component analysis (ICA) algorithm to separate the target object. Firstly image de-noising preprocessing ensures the accuracy of target extraction based on independent component analysis and sparse code shrinkage. Then according to the main proportion of organ in the images, aliasing thickness matrix of each pixel was isolated. Finally independent component analysis obtains convergence matrix to reconstruct the target object with blind separation theory. In the ICA algorithm, it found that when the number is more than 40, the target objects separate successfully with the aid of subjective evaluation standard. And when the amplitudes of the scale are in the [25, 45] interval, the target images have high contrast and less distortion. The three-dimensional figure of Peak signal to noise ratio (PSNR) shows that the different convergence times and amplitudes have a greater influence on image quality. The contrast and edge information of experimental images achieve better effects with the convergence times 85 and amplitudes 35 in the ICA algorithm.

Cloud Inhomogeneity from MODIS

NASA Technical Reports Server (NTRS)

Oreopoulos, Lazaros; Cahalan, Robert F.

2004-01-01

Two full months (July 2003 and January 2004) of MODIS Atmosphere Level-3 data from the Terra and Aqua satellites are analyzed in order to characterize the horizontal variability of cloud optical thickness and water path at global scales. Various options to derive cloud variability parameters are discussed. The climatology of cloud inhomogeneity is built by first calculating daily parameter values at spatial scales of l degree x 1 degree, and then at zonal and global scales, followed by averaging over monthly time scales. Geographical, diurnal, and seasonal changes of inhomogeneity parameters are examined separately for the two cloud phases, and separately over land and ocean. We find that cloud inhomogeneity is weaker in summer than in winter, weaker over land than ocean for liquid clouds, weaker for local morning than local afternoon, about the same for liquid and ice clouds on a global scale, but with wider probability distribution functions (PDFs) and larger latitudinal variations for ice, and relatively insensitive to whether water path or optical thickness products are used. Typical mean values at hemispheric and global scales of the inhomogeneity parameter nu (roughly the mean over the standard deviation of water path or optical thickness), range from approximately 2.5 to 3, while for the inhomogeneity parameter chi (the ratio of the logarithmic to linear mean) from approximately 0.7 to 0.8. Values of chi for zonal averages can occasionally fall below 0.6 and for individual gridpoints below 0.5. Our results demonstrate that MODIS is capable of revealing significant fluctuations in cloud horizontal inhomogenity and stress the need to model their global radiative effect in future studies.

Global diffusion of cosmic rays in random magnetic fields

NASA Astrophysics Data System (ADS)

Snodin, A. P.; Shukurov, A.; Sarson, G. R.; Bushby, P. J.; Rodrigues, L. F. S.

2016-04-01

The propagation of charged particles, including cosmic rays, in a partially ordered magnetic field is characterized by a diffusion tensor whose components depend on the particle's Larmor radius RL and the degree of order in the magnetic field. Most studies of the particle diffusion presuppose a scale separation between the mean and random magnetic fields (e.g. there being a pronounced minimum in the magnetic power spectrum at intermediate scales). Scale separation is often a good approximation in laboratory plasmas, but not in most astrophysical environments such as the interstellar medium (ISM). Modern simulations of the ISM have numerical resolution of the order of 1 pc, so the Larmor radius of the cosmic rays that dominate in energy density is at least 106 times smaller than the resolved scales. Large-scale simulations of cosmic ray propagation in the ISM thus rely on oversimplified forms of the diffusion tensor. We take the first steps towards a more realistic description of cosmic ray diffusion for such simulations, obtaining direct estimates of the diffusion tensor from test particle simulations in random magnetic fields (with the Larmor radius scale being fully resolved), for a range of particle energies corresponding to 10-2 ≲ RL/lc ≲ 103, where lc is the magnetic correlation length. We obtain explicit expressions for the cosmic ray diffusion tensor for RL/lc ≪ 1, that might be used in a sub-grid model of cosmic ray diffusion. The diffusion coefficients obtained are closely connected with existing transport theories that include the random walk of magnetic lines.

The island coalescence problem: Scaling of reconnection in extended fluid models including higher-order moments

DOE PAGES

Ng, Jonathan; Huang, Yi -Min; Hakim, Ammar; ...

2015-11-05

As modeling of collisionless magnetic reconnection in most space plasmas with realistic parameters is beyond the capability of today's simulations, due to the separation between global and kinetic length scales, it is important to establish scaling relations in model problems so as to extrapolate to realistic scales. Furthermore, large scale particle-in-cell simulations of island coalescence have shown that the time averaged reconnection rate decreases with system size, while fluid systems at such large scales in the Hall regime have not been studied. Here, we perform the complementary resistive magnetohydrodynamic (MHD), Hall MHD, and two fluid simulations using a ten-moment modelmore » with the same geometry. In contrast to the standard Harris sheet reconnection problem, Hall MHD is insufficient to capture the physics of the reconnection region. Additionally, motivated by the results of a recent set of hybrid simulations which show the importance of ion kinetics in this geometry, we evaluate the efficacy of the ten-moment model in reproducing such results.« less

Time-cumulated visible and infrared radiance histograms used as descriptors of surface and cloud variations

NASA Technical Reports Server (NTRS)

Seze, Genevieve; Rossow, William B.

1991-01-01

The spatial and temporal stability of the distributions of satellite-measured visible and infrared radiances, caused by variations in clouds and surfaces, are investigated using bidimensional and monodimensional histograms and time-composite images. Similar analysis of the histograms of the original and time-composite images provides separation of the contributions of the space and time variations to the total variations. The variability of both the surfaces and clouds is found to be larger at scales much larger than the minimum resolved by satellite imagery. This study shows that the shapes of these histograms are distinctive characteristics of the different climate regimes and that particular attributes of these histograms can be related to several general, though not universal, properties of clouds and surface variations at regional and synoptic scales. There are also significant exceptions to these relationships in particular climate regimes. The characteristics of these radiance histograms provide a stable well defined descriptor of the cloud and surface properties.

Unsteady flow characteristics in the near-wake of a two-dimensional obstacle

NASA Technical Reports Server (NTRS)

Dyment, A.; Gryson, P.

1984-01-01

The influence of the characteristics of the boundary layer separation on the formation of vortices and alternate paths in the wake of a bidimensional obstacle at high Reynolds numbers was studied by ultra fast visualization system. It is shown that there are alternate paths for laminar and turbulent flows, with similar flow characteristics. It is found that emission of vortices does not change substantially when the flow passes from laminar to turbulent. A film with a time scale change of 10,000 times illustrates some of the discussed phenomena.

Aftershocks of microearthquakes as probes of the mechanics of rupture

NASA Astrophysics Data System (ADS)

Rubin, Allan M.

2002-07-01

Using a waveform cross-correlation technique, Rubin and Gillard [2000] obtained precise relative locations for 4300 0.5 < M < 3.5 earthquakes occurring along 50 km of the San Andreas fault. This study adds to that another 5000 earthquakes distributed along 10 km of the San Andreas fault and 20 km of the Calaveras fault. Errors in relative location are typically tens of meters for earthquakes separated by hundreds of meters and, after correcting for time-dependent station delays, meters for earthquakes separated by tens of meters. Along both faults, the minimum separation between consecutive earthquakes scales with magnitude in a manner consistent with a magnitude-independent stress drop. By treating each earthquake on the San Andreas as if it were a main shock, scaling the distances to all subsequent earthquakes by main shock size, and stacking the results, a ``composite'' aftershock sequence is produced that has many of the characteristics predicted by rate-and-state friction models. Projected onto the fault surface, these aftershocks outline a quasi-elliptical, roughly 4-MPa stress drop main shock elongate in the slip-parallel direction by ~40%. At the ends of the major axes of this ellipse over twice as many aftershocks occur to the NW than to the SE, an asymmetry attributed to the contrast in material properties across the fault. Unlike the San Andreas, the Calaveras fault exhibits little P wave velocity contrast and no discernible aftershock asymmetry; however, the earliest part of the aftershock sequence on the Calaveras might be truncated by the ~30-s ``blind'' time of the network following a triggering event.

Development of a High-Throughput Magnetic Separation Device for Malaria-infected Erythrocytes

PubMed Central

Martin, A. Blue; Wu, Wei-Tao; Kameneva, Marina V.; Antaki, James F.

2017-01-01

This study describes a non-dilutive high-gradient magnetic separation (HGMS) device intended to continuously remove malaria-infected red blood cells (iRBCs) from the circulation. A mesoscale prototype device with disposable photo-etched ferromagnetic grid and reusable permanent magnet was designed with a computationally-optimized magnetic force. The prototype device was evaluated in-vitro using a non-pathogenic analog for malaria-infected blood, comprised of 24% healthy RBCs, 6% human methemoglobin RBCs (metRBCs), and 70% phosphate buffer solution (PBS). The device provided a 27.0 ± 2.2% reduction of metRBCs in a single pass at a flow rate of 77 μL min−1. This represents a clearance rate over 380 times greater throughput than microfluidic devices reported previously. These positive results encourage development of a clinical scale system that would economize time and donor blood for treating severe malaria. PMID:28924724

Relaxation dynamics and transformation kinetics of deeply supercooled water: Temperature, pressure, doping, and proton/deuteron isotope effects.

PubMed

Lemke, Sonja; Handle, Philip H; Plaga, Lucie J; Stern, Josef N; Seidl, Markus; Fuentes-Landete, Violeta; Amann-Winkel, Katrin; Köster, Karsten W; Gainaru, Catalin; Loerting, Thomas; Böhmer, Roland

2017-07-21

Above its glass transition, the equilibrated high-density amorphous ice (HDA) transforms to the low-density pendant (LDA). The temperature dependence of the transformation is monitored at ambient pressure using dielectric spectroscopy and at elevated pressures using dilatometry. It is found that near the glass transition temperature of deuterated samples, the transformation kinetics is 300 times slower than the structural relaxation, while for protonated samples, the time scale separation is at least 30 000 and insensitive to doping. The kinetics of the HDA to LDA transformation lacks a proton/deuteron isotope effect, revealing that this process is dominated by the restructuring of the oxygen network. The x-ray diffraction experiments performed on samples at intermediate transition stages reflect a linear combination of the LDA and HDA patterns implying a macroscopic phase separation, instead of a local intermixing of the two amorphous states.

Development of a High-Throughput Magnetic Separation Device for Malaria-Infected Erythrocytes.

PubMed

Blue Martin, A; Wu, Wei-Tao; Kameneva, Marina V; Antaki, James F

2017-12-01

This study describes a non-dilutive high-gradient magnetic separation (HGMS) device intended to continuously remove malaria-infected red blood cells (iRBCs) from the circulation. A mesoscale prototype device with disposable photo-etched ferromagnetic grid and reusable permanent magnet was designed with a computationally-optimized magnetic force. The prototype device was evaluated in vitro using a non-pathogenic analog for malaria-infected blood, comprised of 24% healthy RBCs, 6% human methemoglobin RBCs (metRBCs), and 70% phosphate buffer solution (PBS). The device provided a 27.0 ± 2.2% reduction of metRBCs in a single pass at a flow rate of 77 μL min -1 . This represents a clearance rate over 380 times greater throughput than microfluidic devices reported previously. These positive results encourage development of a clinical scale system that would economize time and donor blood for treating severe malaria.

Relaxation dynamics and transformation kinetics of deeply supercooled water: Temperature, pressure, doping, and proton/deuteron isotope effects

NASA Astrophysics Data System (ADS)

Lemke, Sonja; Handle, Philip H.; Plaga, Lucie J.; Stern, Josef N.; Seidl, Markus; Fuentes-Landete, Violeta; Amann-Winkel, Katrin; Köster, Karsten W.; Gainaru, Catalin; Loerting, Thomas; Böhmer, Roland

2017-07-01

Above its glass transition, the equilibrated high-density amorphous ice (HDA) transforms to the low-density pendant (LDA). The temperature dependence of the transformation is monitored at ambient pressure using dielectric spectroscopy and at elevated pressures using dilatometry. It is found that near the glass transition temperature of deuterated samples, the transformation kinetics is 300 times slower than the structural relaxation, while for protonated samples, the time scale separation is at least 30 000 and insensitive to doping. The kinetics of the HDA to LDA transformation lacks a proton/deuteron isotope effect, revealing that this process is dominated by the restructuring of the oxygen network. The x-ray diffraction experiments performed on samples at intermediate transition stages reflect a linear combination of the LDA and HDA patterns implying a macroscopic phase separation, instead of a local intermixing of the two amorphous states.

Boussinesq approximation of the Cahn-Hilliard-Navier-Stokes equations.

PubMed

Vorobev, Anatoliy

2010-11-01

We use the Cahn-Hilliard approach to model the slow dissolution dynamics of binary mixtures. An important peculiarity of the Cahn-Hilliard-Navier-Stokes equations is the necessity to use the full continuity equation even for a binary mixture of two incompressible liquids due to dependence of mixture density on concentration. The quasicompressibility of the governing equations brings a short time-scale (quasiacoustic) process that may not affect the slow dynamics but may significantly complicate the numerical treatment. Using the multiple-scale method we separate the physical processes occurring on different time scales and, ultimately, derive the equations with the filtered-out quasiacoustics. The derived equations represent the Boussinesq approximation of the Cahn-Hilliard-Navier-Stokes equations. This approximation can be further employed as a universal theoretical model for an analysis of slow thermodynamic and hydrodynamic evolution of the multiphase systems with strongly evolving and diffusing interfacial boundaries, i.e., for the processes involving dissolution/nucleation, evaporation/condensation, solidification/melting, polymerization, etc.

Central composite design with the help of multivariate curve resolution in loadability optimization of RP-HPLC to scale-up a binary mixture.

PubMed

Taheri, Mohammadreza; Moazeni-Pourasil, Roudabeh Sadat; Sheikh-Olia-Lavasani, Majid; Karami, Ahmad; Ghassempour, Alireza

2016-03-01

Chromatographic method development for preparative targets is a time-consuming and subjective process. This can be particularly problematic because of the use of valuable samples for isolation and the large consumption of solvents in preparative scale. These processes could be improved by using statistical computations to save time, solvent and experimental efforts. Thus, contributed by ESI-MS, after applying DryLab software to gain an overview of the most effective parameters in separation of synthesized celecoxib and its co-eluted compounds, design of experiment software that relies on multivariate modeling as a chemometric approach was used to predict the optimized touching-band overloading conditions by objective functions according to the relationship between selectivity and stationary phase properties. The loadability of the method was investigated on the analytical and semi-preparative scales, and the performance of this chemometric approach was approved by peak shapes beside recovery and purity of products. © 2016 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

Hospital Social Workers and Indirect Trauma Exposure: An Exploratory Study of Contributing Factors

ERIC Educational Resources Information Center

Badger, Karen; Royse, David; Craig, Carlton

2008-01-01

This article explores the predictive ability of empathy (measured by the Interpersonal Reactivity Index), emotional separation (measured by the Maintenance of Emotional Separation Scale), occupational stress (measured by the Work-Related Strain Inventory), and social support (measured by the Multidimensional Scale of Perceived Social Support) on…

Linking Item Parameters to a Base Scale

ERIC Educational Resources Information Center

Kang, Taehoon; Petersen, Nancy S.

2012-01-01

This paper compares three methods of item calibration--concurrent calibration, separate calibration with linking, and fixed item parameter calibration--that are frequently used for linking item parameters to a base scale. Concurrent and separate calibrations were implemented using BILOG-MG. The Stocking and Lord in "Appl Psychol Measure"…

Flowfield measurements in a separated and reattached flat plate turbulent boundary layer

NASA Technical Reports Server (NTRS)

Patrick, William P.

1987-01-01

The separation and reattachment of a large-scale, two-dimensional turbulent boundary layer at low subsonic speed on a flat plate has been studied experimentally. The separation bubble was 55 cm long and had a maximum bubble thickness, measured to the height of the mean dividing streamline, of 17 cm, which was twice the thickness of the inlet boundary layer. A combination of laser velocimetry, hot-wire anemometry, pneumatic probing techniques, and flow visualization were used as diagnostics. Principal findings were that an outer inviscid rotational flow was defined which essentially convected over the blockage associated with the inner, viscously dominated bubble recirculation region. A strong backflow region in which the flow moved upstream 100 percent of the time was measured near the test surface over the central 35 percent of the bubble. A laminar backflow boundary layer having pseudo-turbulent characteristics including a log-linear velocity profile was generated under the highly turbulent backflow. Velocity profile shapes in the reversed flow region matched a previously developed universal backflow profile at the upstream edge of the separation region but not in the steady backflow region downstream. A smoke flow visualization movie and hot-film measurements revealed low frequency nonperiodic flapping at reattachment. However, forward flow fraction data at reattachment and mean velocity profiles in the redeveloping boundary layer downstream of reattachment correlated with backward-facing step data when the axial dimension was scaled by the distance from the maximum bubble thickness to reattachment.

Transport on intermediate time scales in flows with cat's eye patterns

NASA Astrophysics Data System (ADS)

Pöschke, Patrick; Sokolov, Igor M.; Zaks, Michael A.; Nepomnyashchy, Alexander A.

2017-12-01

We consider the advection-diffusion transport of tracers in a one-parameter family of plane periodic flows where the patterns of streamlines feature regions of confined circulation in the shape of "cat's eyes," separated by meandering jets with ballistic motion inside them. By varying the parameter, we proceed from the regular two-dimensional lattice of eddies without jets to the sinusoidally modulated shear flow without eddies. When a weak thermal noise is added, i.e., at large Péclet numbers, several intermediate time scales arise, with qualitatively and quantitatively different transport properties: depending on the parameter of the flow, the initial position of a tracer, and the aging time, motion of the tracers ranges from subdiffusive to superballistic. We report on results of extensive numerical simulations of the mean-squared displacement for different initial conditions in ordinary and aged situations. These results are compared with a theory based on a Lévy walk that describes the intermediate-time ballistic regime and gives a reasonable description of the behavior for a certain class of initial conditions. The interplay of the walk process with internal circulation dynamics in the trapped state results at intermediate time scales in nonmonotonic characteristics of aging not captured by the Lévy walk model.

A neuromorphic implementation of multiple spike-timing synaptic plasticity rules for large-scale neural networks

PubMed Central

Wang, Runchun M.; Hamilton, Tara J.; Tapson, Jonathan C.; van Schaik, André

2015-01-01

We present a neuromorphic implementation of multiple synaptic plasticity learning rules, which include both Spike Timing Dependent Plasticity (STDP) and Spike Timing Dependent Delay Plasticity (STDDP). We present a fully digital implementation as well as a mixed-signal implementation, both of which use a novel dynamic-assignment time-multiplexing approach and support up to 226 (64M) synaptic plasticity elements. Rather than implementing dedicated synapses for particular types of synaptic plasticity, we implemented a more generic synaptic plasticity adaptor array that is separate from the neurons in the neural network. Each adaptor performs synaptic plasticity according to the arrival times of the pre- and post-synaptic spikes assigned to it, and sends out a weighted or delayed pre-synaptic spike to the post-synaptic neuron in the neural network. This strategy provides great flexibility for building complex large-scale neural networks, as a neural network can be configured for multiple synaptic plasticity rules without changing its structure. We validate the proposed neuromorphic implementations with measurement results and illustrate that the circuits are capable of performing both STDP and STDDP. We argue that it is practical to scale the work presented here up to 236 (64G) synaptic adaptors on a current high-end FPGA platform. PMID:26041985

Donders is dead: cortical traveling waves and the limits of mental chronometry in cognitive neuroscience.

PubMed

Alexander, David M; Trengove, Chris; van Leeuwen, Cees

2015-11-01

An assumption nearly all researchers in cognitive neuroscience tacitly adhere to is that of space-time separability. Historically, it forms the basis of Donders' difference method, and to date, it underwrites all difference imaging and trial-averaging of cortical activity, including the customary techniques for analyzing fMRI and EEG/MEG data. We describe the assumption and how it licenses common methods in cognitive neuroscience; in particular, we show how it plays out in signal differencing and averaging, and how it misleads us into seeing the brain as a set of static activity sources. In fact, rather than being static, the domains of cortical activity change from moment to moment: Recent research has suggested the importance of traveling waves of activation in the cortex. Traveling waves have been described at a range of different spatial scales in the cortex; they explain a large proportion of the variance in phase measurements of EEG, MEG and ECoG, and are important for understanding cortical function. Critically, traveling waves are not space-time separable. Their prominence suggests that the correct frame of reference for analyzing cortical activity is the dynamical trajectory of the system, rather than the time and space coordinates of measurements. We illustrate what the failure of space-time separability implies for cortical activation, and what consequences this should have for cognitive neuroscience.

Design parameters for the separation of fat from natural whole milk in an ultrasonic litre-scale vessel.

PubMed

Leong, Thomas; Johansson, Linda; Juliano, Pablo; Mawson, Raymond; McArthur, Sally; Manasseh, Richard

2014-07-01

The separation of milk fat from natural whole milk has been achieved by applying ultrasonic standing waves (1 MHz and/or 2 MHz) in a litre-scale (5L capacity) batch system. Various design parameters were tested such as power input level, process time, specific energy, transducer-reflector distance and the use of single and dual transducer set-ups. It was found that the efficacy of the treatment depended on the specific energy density input into the system. In this case, a plateau in fat concentration of ∼20% w/v was achieved in the creamed top layer after applying a minimum specific energy of 200 kJ/kg. In addition, the fat separation was enhanced by reducing the transducer reflector distance in the vessel, operating two transducers in a parallel set-up, or by increasing the duration of insonation, resulting in skimmed milk with a fat concentration as low as 1.7% (w/v) using raw milk after 20 min insonation. Dual mode operation with both transducers in parallel as close as 30 mm apart resulted in the fastest creaming and skimming in this study at ∼1.6 g fat/min. Copyright © 2014 Elsevier B.V. All rights reserved.

A novel bio-safe phase separation process for preparing open-pore biodegradable polycaprolactone microparticles.

PubMed

Salerno, Aurelio; Domingo, Concepción

2014-09-01

Open-pore biodegradable microparticles are object of considerable interest for biomedical applications, particularly as cell and drug delivery carriers in tissue engineering and health care treatments. Furthermore, the engineering of microparticles with well definite size distribution and pore architecture by bio-safe fabrication routes is crucial to avoid the use of toxic compounds potentially harmful to cells and biological tissues. To achieve this important issue, in the present study a straightforward and bio-safe approach for fabricating porous biodegradable microparticles with controlled morphological and structural features down to the nanometer scale is developed. In particular, ethyl lactate is used as a non-toxic solvent for polycaprolactone particles fabrication via a thermal induced phase separation technique. The used approach allows achieving open-pore particles with mean particle size in the 150-250 μm range and a 3.5-7.9 m(2)/g specific surface area. Finally, the combination of thermal induced phase separation and porogen leaching techniques is employed for the first time to obtain multi-scaled porous microparticles with large external and internal pore sizes and potential improved characteristics for cell culture and tissue engineering. Samples were characterized to assess their thermal properties, morphology and crystalline structure features and textural properties. Copyright © 2014 Elsevier B.V. All rights reserved.

DOE Office of Scientific and Technical Information (OSTI.GOV)

Benioff, Paul

This paper describes the effects of a complex scalar scaling field on quantum mechanics. The field origin is an extension of the gauge freedom for basis choice in gauge theories to the underlying scalar field. The extension is based on the idea that the value of a number at one space time point does not determine the value at another point. This, combined with the description of mathematical systems as structures of different types, results in the presence of separate number fields and vector spaces as structures, at different space time locations. Complex number structures and vector spaces at eachmore » location are scaled by a complex space time dependent scaling factor. The effect of this scaling factor on several physical and geometric quantities has been described in other work. Here the emphasis is on quantum mechanics of one and two particles, their states and properties. Multiparticle states are also briefly described. The effect shows as a complex, nonunitary, scalar field connection on a fiber bundle description of nonrelativistic quantum mechanics. Here, the lack of physical evidence for the presence of this field so far means that the coupling constant of this field to fermions is very small. It also means that the gradient of the field must be very small in a local region of cosmological space and time. Outside this region, there are no restrictions on the field gradient.« less

Scaling analysis of bilateral hand tremor movements in essential tremor patients.

PubMed

Blesic, S; Maric, J; Dragasevic, N; Milanovic, S; Kostic, V; Ljubisavljevic, Milos

2011-08-01

Recent evidence suggests that the dynamic-scaling behavior of the time-series of signals extracted from separate peaks of tremor spectra may reveal existence of multiple independent sources of tremor. Here, we have studied dynamic characteristics of the time-series of hand tremor movements in essential tremor (ET) patients using the detrended fluctuation analysis method. Hand accelerometry was recorded with (500 g) and without weight loading under postural conditions in 25 ET patients and 20 normal subjects. The time-series comprising peak-to-peak (PtP) intervals were extracted from regions around the first three main frequency components of power spectra (PwS) of the recorded tremors. The data were compared between the load and no-load condition on dominant (related to tremor severity) and non-dominant tremor side and with the normal (physiological) oscillations in healthy subjects. Our analysis shows that, in ET, the dynamic characteristics of the main frequency component of recorded tremors exhibit scaling behavior. Furthermore, they show that the two main components of ET tremor frequency spectra, otherwise indistinguishable without load, become significantly different after inertial loading and that they differ between the tremor sides (related to tremor severity). These results show that scaling, a time-domain analysis, helps revealing tremor features previously not revealed by frequency-domain analysis and suggest that distinct oscillatory central circuits may generate the tremor in ET patients.

Tracking the coherent generation of polaron pairs in conjugated polymers

NASA Astrophysics Data System (ADS)

de Sio, Antonietta; Troiani, Filippo; Maiuri, Margherita; Réhault, Julien; Sommer, Ephraim; Lim, James; Huelga, Susana F.; Plenio, Martin B.; Rozzi, Carlo Andrea; Cerullo, Giulio; Molinari, Elisa; Lienau, Christoph

2016-12-01

The optical excitation of organic semiconductors not only generates charge-neutral electron-hole pairs (excitons), but also charge-separated polaron pairs with high yield. The microscopic mechanisms underlying this charge separation have been debated for many years. Here we use ultrafast two-dimensional electronic spectroscopy to study the dynamics of polaron pair formation in a prototypical polymer thin film on a sub-20-fs time scale. We observe multi-period peak oscillations persisting for up to about 1 ps as distinct signatures of vibronic quantum coherence at room temperature. The measured two-dimensional spectra show pronounced peak splittings revealing that the elementary optical excitations of this polymer are hybridized exciton-polaron-pairs, strongly coupled to a dominant underdamped vibrational mode. Coherent vibronic coupling induces ultrafast polaron pair formation, accelerates the charge separation dynamics and makes it insensitive to disorder. These findings open up new perspectives for tailoring light-to-current conversion in organic materials.

Measurement of dielectric constant of organic solvents by indigenously developed dielectric probe

NASA Astrophysics Data System (ADS)

Keshari, Ajay Kumar; Rao, J. Prabhakar; Rao, C. V. S. Brahmmananda; Ramakrishnan, R.; Ramanarayanan, R. R.

2018-04-01

The extraction, separation and purification of actinides (uranium and plutonium) from various matrices are an important step in nuclear fuel cycle. One of the separation process adopted in an industrial scale is the liquid-liquid extraction or solvent extraction. Liquid-liquid extraction uses a specific ligand/extractant in conjunction with suitable diluent. Solvent extraction or liquid-liquid extraction, involves the partitioning of the solute between two immiscible phases. In most cases, one of the phases is aqueous, and the other one is an organic solvent. The solvent used in solvent extraction should be selective for the metal of interest, it should have optimum distribution ratio, and the loaded metal from the organic phase should be easily stripped under suitable experimental conditions. Some of the important physical properties which are important for the solvent are density, viscosity, phase separation time, interfacial surface tension and the polarity of the extractant.

On-line comprehensive two-dimensional normal-phase liquid chromatography×reversed-phase liquid chromatography for preparative isolation of toad venom.

PubMed

Li, Jia-Fu; Fang, Hua; Yan, Xia; Chang, Fang-Rong; Wu, Zhen; Wu, Yun-Long; Qiu, Ying-Kun

2016-07-22

An on-line comprehensive preparative two-dimensional normal-phase liquid chromatography×reversed-phase liquid chromatography (2D NPLC×RPLC) system was constructed with a newly developed vacuum evaporation assisted adsorption (VEAA) interface, allowing fast removal of NPLC solvent in the vacuum condition and successfully solving the solvent incompatibility problem between NPLC and RPLC. The system achieved on-line solvent exchange within the two dimensions and its performance was illustrated by gram-scale isolation of crude extract from the venom of Bufo bufo gargarizans. Within separation time of ∼20h, 19 compounds were obtained with high purity in a single run. With the VEAA interface, the 2D system exhibited apparent advantages in separation efficiency and automation compared with conventional methods, indicating its promising application in the routine separation process for complicated natural products. Copyright © 2016 Elsevier B.V. All rights reserved.

High resolution separations of charge variants and disulfide isomers of monoclonal antibodies and antibody drug conjugates using ultra-high voltage capillary electrophoresis with high electric field strength.

PubMed

Henley, W Hampton; He, Yan; Mellors, J Scott; Batz, Nicholas G; Ramsey, J Michael; Jorgenson, James W

2017-11-10

Ultra-high voltage capillary electrophoresis with high electric field strength has been applied to the separation of the charge variants, drug conjugates, and disulfide isomers of monoclonal antibodies. Samples composed of many closely related species are difficult to resolve and quantify using traditional analytical instrumentation. High performance instrumentation can often save considerable time and effort otherwise spent on extensive method development. Ideally, the resolution obtained for a given CE buffer system scales with the square root of the applied voltage. Currently available commercial CE instrumentation is limited to an applied voltage of approximately 30kV and a maximum electric field strength of 1kV/cm due to design limitations. The instrumentation described here is capable of safely applying potentials of at least 120kV with electric field strengths over 2000V/cm, potentially doubling the resolution of the best conventional CE buffer/capillary systems while decreasing analysis time in some applications. Separations of these complex mixtures using this new instrumentation demonstrate the potential of ultra-high voltage CE to identify the presence of previously unresolved components and to reduce analysis time for complex mixtures of antibody variants and drug conjugates. Copyright © 2017 Elsevier B.V. All rights reserved.

Ultra-fast relaxation, decoherence, and localization of photoexcited states in π-conjugated polymers

NASA Astrophysics Data System (ADS)

Mannouch, Jonathan R.; Barford, William; Al-Assam, Sarah

2018-01-01

The exciton relaxation dynamics of photoexcited electronic states in poly(p-phenylenevinylene) are theoretically investigated within a coarse-grained model, in which both the exciton and nuclear degrees of freedom are treated quantum mechanically. The Frenkel-Holstein Hamiltonian is used to describe the strong exciton-phonon coupling present in the system, while external damping of the internal nuclear degrees of freedom is accounted for by a Lindblad master equation. Numerically, the dynamics are computed using the time evolving block decimation and quantum jump trajectory techniques. The values of the model parameters physically relevant to polymer systems naturally lead to a separation of time scales, with the ultra-fast dynamics corresponding to energy transfer from the exciton to the internal phonon modes (i.e., the C-C bond oscillations), while the longer time dynamics correspond to damping of these phonon modes by the external dissipation. Associated with these time scales, we investigate the following processes that are indicative of the system relaxing onto the emissive chromophores of the polymer: (1) Exciton-polaron formation occurs on an ultra-fast time scale, with the associated exciton-phonon correlations present within half a vibrational time period of the C-C bond oscillations. (2) Exciton decoherence is driven by the decay in the vibrational overlaps associated with exciton-polaron formation, occurring on the same time scale. (3) Exciton density localization is driven by the external dissipation, arising from "wavefunction collapse" occurring as a result of the system-environment interactions. Finally, we show how fluorescence anisotropy measurements can be used to investigate the exciton decoherence process during the relaxation dynamics.

Archaeological Investigation at El Dorado Lake, Butler County, Kansas. Phase III.

DTIC Science & Technology

1982-01-01

time during which deep disturbance predominated is estimated to be roughly equal to the number of years surface and shallow techniques have been... during excavation, but sampled. Measurements are therefore estimated from scale drawings of feature plans. However, the drawing of Feature 3 consists... roasting features with the limestones and/or deposited as refuse during separate disposal episodes. Fauna and Flora A total of 862 bones and bone

Fundamental Mechanisms, Predictive Modeling, and Novel Aerospace Applications of Plasma Assisted Combustion. Overview of OSU Research Plan

DTIC Science & Technology

2009-11-04

air, low-temperature plasma chemistry kinetic model Nonequilibrium Thermodynamics Laboratories The Ohio State University • Air plasma model...problems require separate analysis: • Nsec pulse plasma / sheath models cannot incorporate detailed reactive plasma chemistry : too many species ( 100...and reactions ( 1 000)~ ~ , • Detailed plasma chemistry models (quasi-neutral) cannot incorporate repetitive, nsec time scale sheath dynamics and plasma

Phosphate recovery from wastewater using engineered superparamagnetic particles modified with layered double hydroxide ion exchangers.

PubMed

Drenkova-Tuhtan, Asya; Mandel, Karl; Paulus, Anja; Meyer, Carsten; Hutter, Frank; Gellermann, Carsten; Sextl, Gerhard; Franzreb, Matthias; Steinmetz, Heidrun

2013-10-01

An innovative nanocomposite material is proposed for phosphate recovery from wastewater using magnetic assistance. Superparamagnetic microparticles modified with layered double hydroxide (LDH) ion exchangers of various compositions act as phosphate adsorbers. Magnetic separation and chemical regeneration of the particles allows their reuse, leading to the successful recovery of phosphate. Based upon the preliminary screening of different LDH ion exchanger modifications for phosphate selectivity and uptake capacity, MgFe-Zr LDH coated magnetic particles were chosen for further characterization and application. The adsorption kinetics of phosphate from municipal wastewater was studied in dependence with particle concentration, contact time and pH. Adsorption isotherms were then determined for the selected particle system. Recovery of phosphate and regeneration of the particles was examined via testing a variety of desorption solutions. Reusability of the particles was demonstrated for 15 adsorption/desorption cycles. Adsorption in the range of 75-97% was achieved in each cycle after 1 h contact time. Phosphate recovery and enrichment was possible through repetitive application of the desorption solution. Finally, a pilot scale experiment was carried out by treating 125 L of wastewater with the particles in five subsequent 25 L batches. Solid-liquid separation on this scale was carried out with a high-gradient magnetic filter (HGMF). Copyright © 2013 Elsevier Ltd. All rights reserved.

On scattered waves and lipid domains: detecting membrane rafts with X-rays and neutrons

DOE PAGES

Marquardt, Drew; Heberle, Frederick A.; Nickels, Jonathan D.; ...

2015-09-21

In order to understand the biological role of lipids in cell membranes, it is necessary to determine the mesoscopic structure of well-defined model membrane systems. Neutron and X-ray scattering are non-invasive, probe-free techniques that have been used extensively in such systems to probe length scales ranging from angstroms to microns, and dynamics occurring over picosecond to millisecond time scales. Finally, recent developments in the area of phase separated lipid systems mimicking membrane rafts will be presented, and the underlying concepts of the different scattering techniques used to study them will be discussed in detail.

A simple and fast representation space for classifying complex time series

NASA Astrophysics Data System (ADS)

Zunino, Luciano; Olivares, Felipe; Bariviera, Aurelio F.; Rosso, Osvaldo A.

2017-03-01

In the context of time series analysis considerable effort has been directed towards the implementation of efficient discriminating statistical quantifiers. Very recently, a simple and fast representation space has been introduced, namely the number of turning points versus the Abbe value. It is able to separate time series from stationary and non-stationary processes with long-range dependences. In this work we show that this bidimensional approach is useful for distinguishing complex time series: different sets of financial and physiological data are efficiently discriminated. Additionally, a multiscale generalization that takes into account the multiple time scales often involved in complex systems has been also proposed. This multiscale analysis is essential to reach a higher discriminative power between physiological time series in health and disease.

Bench Scale Thin Film Composite Hollow Fiber Membranes for Post-Combustion Carbon Dioxide Capture

DOE Office of Scientific and Technical Information (OSTI.GOV)

Glaser, Paul; Bhandari, Dhaval; Narang, Kristi

2015-04-01

GE Global Research, Idaho National Laboratory (INL), Georgia Institute of Technology (Georgia Tech), and Western Research Institute (WRI) proposed to develop high performance thin film polymer composite hollow fiber membranes and advanced processes for economical post-combustion carbon dioxide (CO 2) capture from pulverized coal flue gas at temperatures typical of existing flue gas cleanup processes. The project sought to develop and then optimize new gas separations membrane systems at the bench scale, including tuning the properties of a novel polyphosphazene polymer in a coating solution and fabricating highly engineered porous hollow fiber supports. The project also sought to define themore » processes needed to coat the fiber support to manufacture composite hollow fiber membranes with high performance, ultra-thin separation layers. Physical, chemical, and mechanical stability of the materials (individual and composite) towards coal flue gas components was considered via exposure and performance tests. Preliminary design, technoeconomic, and economic feasibility analyses were conducted to evaluate the overall performance and impact of the process on the cost of electricity (COE) for a coal-fired plant including capture technologies. At the onset of the project, Membranes based on coupling a novel selective material polyphosphazene with an engineered hollow fiber support was found to have the potential to capture greater than 90% of the CO 2 in flue gas with less than 35% increase in COE, which would achieve the DOE-targeted performance criteria. While lab-scale results for the polyphosphazene materials were very promising, and the material was incorporated into hollow-fiber modules, difficulties were encountered relating to the performance of these membrane systems over time. Performance, as measured by both flux of and selectivity for CO 2 over other flue gas constituents was found to deteriorate over time, suggesting a system that was more dynamic than initially hypothesized. These phenomena are believed to be associated with the physical and mechanical properties of the separation material, rather than chemical degradation by flue gas or one of its constituents. Strategies to improve the composite systems via alternate chemistries and processing techniques were only partially successful in creating a more robust system, but the research provided critical insight into the barriers to engineering sophisticated composite systems for gas separation. Promising concepts, including a re-engineering of the separation material with interpenetrating polymer networks were identified which may prove useful to future efforts in this field.« less

Toward a comprehensive landscape vegetation monitoring framework

NASA Astrophysics Data System (ADS)

Kennedy, Robert; Hughes, Joseph; Neeti, Neeti; Larrue, Tara; Gregory, Matthew; Roberts, Heather; Ohmann, Janet; Kane, Van; Kane, Jonathan; Hooper, Sam; Nelson, Peder; Cohen, Warren; Yang, Zhiqiang

2016-04-01

Blossoming Earth observation resources provide great opportunity to better understand land vegetation dynamics, but also require new techniques and frameworks to exploit their potential. Here, I describe several parallel projects that leverage time-series Landsat imagery to describe vegetation dynamics at regional and continental scales. At the core of these projects are the LandTrendr algorithms, which distill time-series earth observation data into periods of consistent long or short-duration dynamics. In one approach, we built an integrated, empirical framework to blend these algorithmically-processed time-series data with field data and lidar data to ascribe yearly change in forest biomass across the US states of Washington, Oregon, and California. In a separate project, we expanded from forest-only monitoring to full landscape land cover monitoring over the same regional scale, including both categorical class labels and continuous-field estimates. In these and other projects, we apply machine-learning approaches to ascribe all changes in vegetation to driving processes such as harvest, fire, urbanization, etc., allowing full description of both disturbance and recovery processes and drivers. Finally, we are moving toward extension of these same techniques to continental and eventually global scales using Google Earth Engine. Taken together, these approaches provide one framework for describing and understanding processes of change in vegetation communities at broad scales.

Resonance-modulated wavelength scaling of high-order-harmonic generation from H2+

NASA Astrophysics Data System (ADS)

Wang, Baoning; He, Lixin; Wang, Feng; Yuan, Hua; Zhu, Xiaosong; Lan, Pengfei; Lu, Peixiang

2018-01-01

Wavelength scaling of high-order harmonic generation (HHG) in a non-Born-Oppenheimer treatment of H2+ is investigated by numerical simulations of the time-dependent Schrödinger equation. The results show that the decrease in the wavelength-dependent HHG yield is reduced compared to that in the fixed-nucleus approximation. This slower wavelength scaling is related to the charge-resonance-enhanced ionization effect, which considerably increases the ionization rate at longer driving laser wavelengths due to the relatively larger nuclear separation. In addition, we find an oscillation structure in the wavelength scaling of HHG from H2+. Upon decreasing the laser intensity or increasing the nuclear mass, the oscillation structure will shift towards a longer wavelength of the laser pulse. These results permit the generation of an efficient harmonic spectrum in the midinfrared regime by manipulating the nuclear dynamics of molecules.

Trends in scale and shape of survival curves.

PubMed

Weon, Byung Mook; Je, Jung Ho

2012-01-01

The ageing of the population is an issue in wealthy countries worldwide because of increasing costs for health care and welfare. Survival curves taken from demographic life tables may help shed light on the hypotheses that humans are living longer and that human populations are growing older. We describe a methodology that enables us to obtain separate measurements of scale and shape variances in survival curves. Specifically, 'living longer' is associated with the scale variance of survival curves, whereas 'growing older' is associated with the shape variance. We show how the scale and shape of survival curves have changed over time during recent decades, based on period and cohort female life tables for selected wealthy countries. Our methodology will be useful for performing better tracking of ageing statistics and it is possible that this methodology can help identify the causes of current trends in human ageing.

Automating multistep flow synthesis: approach and challenges in integrating chemistry, machines and logic

PubMed Central

Shukla, Chinmay A

2017-01-01

The implementation of automation in the multistep flow synthesis is essential for transforming laboratory-scale chemistry into a reliable industrial process. In this review, we briefly introduce the role of automation based on its application in synthesis viz. auto sampling and inline monitoring, optimization and process control. Subsequently, we have critically reviewed a few multistep flow synthesis and suggested a possible control strategy to be implemented so that it helps to reliably transfer the laboratory-scale synthesis strategy to a pilot scale at its optimum conditions. Due to the vast literature in multistep synthesis, we have classified the literature and have identified the case studies based on few criteria viz. type of reaction, heating methods, processes involving in-line separation units, telescopic synthesis, processes involving in-line quenching and process with the smallest time scale of operation. This classification will cover the broader range in the multistep synthesis literature. PMID:28684977

Attosecond-resolution Hong-Ou-Mandel interferometry.

PubMed

Lyons, Ashley; Knee, George C; Bolduc, Eliot; Roger, Thomas; Leach, Jonathan; Gauger, Erik M; Faccio, Daniele

2018-05-01

When two indistinguishable photons are each incident on separate input ports of a beamsplitter, they "bunch" deterministically, exiting via the same port as a direct consequence of their bosonic nature. This two-photon interference effect has long-held the potential for application in precision measurement of time delays, such as those induced by transparent specimens with unknown thickness profiles. However, the technique has never achieved resolutions significantly better than the few-femtosecond (micrometer) scale other than in a common-path geometry that severely limits applications. We develop the precision of Hong-Ou-Mandel interferometry toward the ultimate limits dictated by statistical estimation theory, achieving few-attosecond (or nanometer path length) scale resolutions in a dual-arm geometry, thus providing access to length scales pertinent to cell biology and monoatomic layer two-dimensional materials.

First record of Pulvinaria urbicola Cockerell (Hemiptera: Coccidae) from India, with a key to the Indian species of Pulvinaria Targioni Tozzetti.

PubMed

Joshi, Sunil

2017-02-23

The notoriously destructive and invasive soft scale, Pulvinaria urbicola Cockerell (Hemiptera: Coccidae), is recorded for the first time from India. This scale, with variable morphological appearance and similarities with other known scales of the same genus established in India, is redescribed to facilitate its identification and separation from other similar species. Information on its host range, natural enemies and distribution is provided. Management options in the event of an outbreak are discussed briefly. A key to the species of Pulvinaria Targioni Tozzetti in India is also provided. This new arrival warrants special attention in India as it is a potentially damaging plant pest and has a broad host range across many plant families.

Results of an experimental investigation to determine separation characteristics for the Orbiter/747 using a 0.0125-scale model (48-0 AX1318I-1 747) in the Ames Research Center 14-foot wind tunnel (CA23B)

NASA Technical Reports Server (NTRS)

Esparza, V.

1976-01-01

Aerodynamic separation data obtained from a wind tunnel test of an 0.0125-scale SSV Orbiter model of a VC70-000002 Configuration and a 0.0125-scale 747 model was presented. Separation data was obtained at a Mach number of 0.6 and three incidence angles of 4, 6, and 8 degrees. The orbiter angle of attack was varied from 0 to 14 degrees. Longitudinal, lateral and normal separation increments were obtained for fixed 747 angles of attack of 0, 2, and 4 degrees while varying the orbiter angle of attack. Control surface settings on the 747 carrier included rudder deflections of 0 and 10 degrees and horizontal stabilizer deflections of -1 and +5 degrees.

Plasmon mass scale and quantum fluctuations of classical fields on a real time lattice

NASA Astrophysics Data System (ADS)

Kurkela, Aleksi; Lappi, Tuomas; Peuron, Jarkko

2018-03-01

Classical real-time lattice simulations play an important role in understanding non-equilibrium phenomena in gauge theories and are used in particular to model the prethermal evolution of heavy-ion collisions. Above the Debye scale the classical Yang-Mills (CYM) theory can be matched smoothly to kinetic theory. First we study the limits of the quasiparticle picture of the CYM fields by determining the plasmon mass of the system using 3 different methods. Then we argue that one needs a numerical calculation of a system of classical gauge fields and small linearized fluctuations, which correspond to quantum fluctuations, in a way that keeps the separation between the two manifest. We demonstrate and test an implementation of an algorithm with the linearized fluctuation showing that the linearization indeed works and that the Gauss's law is conserved.

Separation Anxiety in Parents of Adolescents: Theoretical Significance and Scale Development.

ERIC Educational Resources Information Center

Hock, Ellen; Eberly, Mary; Bartle-Haring, Suzanne; Ellwanger, Pamela; Widaman, Keith F.

2001-01-01

Developed and validated Parents of Adolescents Separation Anxiety Scale with parents of sixth, eighth, tenth, and twelfth graders, and college freshmen and seniors. Factor analyses supported two subscales: Anxiety about Adolescent Distancing (AAD) and Comfort with Secure Base Role (CSBR); both showed distinctive change patterns with child age.…

Linking Item Parameters to a Base Scale. ACT Research Report Series, 2009-2

ERIC Educational Resources Information Center

Kang, Taehoon; Petersen, Nancy S.

2009-01-01

This paper compares three methods of item calibration--concurrent calibration, separate calibration with linking, and fixed item parameter calibration--that are frequently used for linking item parameters to a base scale. Concurrent and separate calibrations were implemented using BILOG-MG. The Stocking and Lord (1983) characteristic curve method…

Achieving high permeability and enhanced selectivity for Angstrom-scale separations using artificial water channel membranes.

PubMed

Shen, Yue-Xiao; Song, Woochul C; Barden, D Ryan; Ren, Tingwei; Lang, Chao; Feroz, Hasin; Henderson, Codey B; Saboe, Patrick O; Tsai, Daniel; Yan, Hengjing; Butler, Peter J; Bazan, Guillermo C; Phillip, William A; Hickey, Robert J; Cremer, Paul S; Vashisth, Harish; Kumar, Manish

2018-06-12

Synthetic polymer membranes, critical to diverse energy-efficient separations, are subject to permeability-selectivity trade-offs that decrease their overall efficacy. These trade-offs are due to structural variations (e.g., broad pore size distributions) in both nonporous membranes used for Angstrom-scale separations and porous membranes used for nano to micron-scale separations. Biological membranes utilize well-defined Angstrom-scale pores to provide exceptional transport properties and can be used as inspiration to overcome this trade-off. Here, we present a comprehensive demonstration of such a bioinspired approach based on pillar[5]arene artificial water channels, resulting in artificial water channel-based block copolymer membranes. These membranes have a sharp selectivity profile with a molecular weight cutoff of ~ 500 Da, a size range challenging to achieve with current membranes, while achieving a large improvement in permeability (~65 L m -2  h -1  bar -1  compared with 4-7 L m -2  h -1  bar -1 ) over similarly rated commercial membranes.

Characteristic Time Scales of Characteristic Magmatic Processes and Systems

NASA Astrophysics Data System (ADS)

Marsh, B. D.

2004-05-01

Every specific magmatic process, regardless of spatial scale, has an associated characteristic time scale. Time scales associated with crystals alone are rates of growth, dissolution, settling, aggregation, annealing, and nucleation, among others. At the other extreme are the time scales associated with the dynamics of the entire magmatic system. These can be separated into two groups: those associated with system genetics (e.g., the production and transport of magma, establishment of the magmatic system) and those due to physical characteristics of the established system (e.g., wall rock failure, solidification front propagation and instability, porous flow). The detailed geometry of a specific magmatic system is particularly important to appreciate; although generic systems are useful, care must be taken to make model systems as absolutely realistic as possible. Fuzzy models produce fuzzy science. Knowledge of specific time scales is not necessarily useful or meaningful unless the hierarchical context of the time scales for a realistic magmatic system is appreciated. The age of a specific phenocryst or ensemble of phenocrysts, as determined from isotopic or CSD studies, is not meaningful unless something can be ascertained of the provenance of the crystals. For example, crystal size multiplied by growth rate gives a meaningful crystal age only if it is from a part of the system that has experienced semi-monotonic cooling prior to chilling; crystals entrained from a long-standing cumulate bed that were mechanically sorted in ascending magma may not reveal this history. Ragged old crystals rolling about in the system for untold numbers of flushing times record specious process times, telling more about the noise in the system than the life of typical, first generation crystallization processes. The most helpful process-related time scales are those that are known well and that bound or define the temporal style of the system. Perhaps the most valuable of these times comes from the observed durations and rates of volcanism. There can be little doubt that the temporal styles of volcanism are the same as those of magmatism in general. Volcano repose times, periodicity, eruptive fluxes, acoustic emission structures, lava volumes, longevity, etc. must also be characteristic of pluton-dominated systems. We must therefore give up some classical concepts (e.g., instantaneous injection of crystal-free magma as an initial condition) for any plutonic/chambered system and move towards an integrated concept of magmatism. Among the host of process-related time scales, probably the three most fundamental of any magmatic system are (1) the time scale associated with crystal nucleation (J) and growth (G) (tx}=C{1(G3 J)-{1}/4; Zieg & Marsh, J. Pet. 02') along with the associated scales for mean crystal size (L) and population (N), (2) the time scale associated with conductive cooling controlled by a local length scale (d) (tc}=C{2 d2/K; K is thermal diffusivity), and (3) the time scale associated with intra-crystal diffusion (td}=C{3 L2/D; D is chemical diffusivity). It is the subtle, clever, and insightful application of time scales, dovetailed with realistic system geometry and attention paid to the analogous time scales of volcanism, that promises to reveal the true dynamic integration of magmatic systems.

Subgroups of advanced cancer patients clustered by their symptom profiles: quality-of-life outcomes.

PubMed

Husain, Amna; Myers, Jeff; Selby, Debbie; Thomson, Barbara; Chow, Edward

2011-11-01

Symptom cluster analysis is a new frontier of research in symptom management. This study clustered patients by their symptom profiles to identify subgroups that may be at higher risk for poor quality of life (QOL) and that may, therefore, benefit most from targeted interventions. Longitudinal study of metastatic cancer patients using the Edmonton Symptom Assessment Scale (ESAS). We generated two-, three-, and four-cluster subgroups and examined the relationship of cluster membership with patient outcomes. To address the problem of missing longitudinal data, we developed a novel outcome variable (QualTime) that measures both QOL and time in study. Two hundred and twenty-one patients with a mean Palliative Performance Scale (PPS) of 59.1 were enrolled. The three-cluster model was chosen for further analysis. The low-burden subgroup had all low severity symptom scores. The intermediate subgroup separates from the low-burden group on the "debility" profile of fatigue, drowsiness, appetite, and well-being. The high-burden group separates from the intermediate-burden group on pain, depression, and anxiety. At baseline, PPS (p=0.0003) and cluster membership (p<0.0001) contributed significantly to global QOL. In univariate analysis, cluster membership was related to the longitudinal outcome, QualTime. In a multivariate model, the relationship of PPS to QualTime was still significant (p=0.0002), but subgroup membership was no longer significant (p=0.1009). PPS is a stronger predictor of the longitudinal variable than cluster subgroups; however, cluster subgroups provide a target for clinical interventions that may improve QOL.

Scale-dependency of the global mean surface temperature trend and its implication for the recent hiatus of global warming.

PubMed

Lin, Yong; Franzke, Christian L E

2015-08-11

Studies of the global mean surface temperature trend are typically conducted at a single (usually annual or decadal) time scale. The used scale does not necessarily correspond to the intrinsic scales of the natural temperature variability. This scale mismatch complicates the separation of externally forced temperature trends from natural temperature fluctuations. The hiatus of global warming since 1999 has been claimed to show that human activities play only a minor role in global warming. Most likely this claim is wrong due to the inadequate consideration of the scale-dependency in the global surface temperature (GST) evolution. Here we show that the variability and trend of the global mean surface temperature anomalies (GSTA) from January 1850 to December 2013, which incorporate both land and sea surface data, is scale-dependent and that the recent hiatus of global warming is mainly related to natural long-term oscillations. These results provide a possible explanation of the recent hiatus of global warming and suggest that the hiatus is only temporary.

EEG Oscillations Are Modulated in Different Behavior-Related Networks during Rhythmic Finger Movements.

PubMed

Seeber, Martin; Scherer, Reinhold; Müller-Putz, Gernot R

2016-11-16

Sequencing and timing of body movements are essential to perform motoric tasks. In this study, we investigate the temporal relation between cortical oscillations and human motor behavior (i.e., rhythmic finger movements). High-density EEG recordings were used for source imaging based on individual anatomy. We separated sustained and movement phase-related EEG source amplitudes based on the actual finger movements recorded by a data glove. Sustained amplitude modulations in the contralateral hand area show decrease for α (10-12 Hz) and β (18-24 Hz), but increase for high γ (60-80 Hz) frequencies during the entire movement period. Additionally, we found movement phase-related amplitudes, which resembled the flexion and extension sequence of the fingers. Especially for faster movement cadences, movement phase-related amplitudes included high β (24-30 Hz) frequencies in prefrontal areas. Interestingly, the spectral profiles and source patterns of movement phase-related amplitudes differed from sustained activities, suggesting that they represent different frequency-specific large-scale networks. First, networks were signified by the sustained element, which statically modulate their synchrony levels during continuous movements. These networks may upregulate neuronal excitability in brain regions specific to the limb, in this study the right hand area. Second, movement phase-related networks, which modulate their synchrony in relation to the movement sequence. We suggest that these frequency-specific networks are associated with distinct functions, including top-down control, sensorimotor prediction, and integration. The separation of different large-scale networks, we applied in this work, improves the interpretation of EEG sources in relation to human motor behavior. EEG recordings provide high temporal resolution suitable to relate cortical oscillations to actual movements. Investigating EEG sources during rhythmic finger movements, we distinguish sustained from movement phase-related amplitude modulations. We separate these two EEG source elements motivated by our previous findings in gait. Here, we found two types of large-scale networks, representing the right fingers in distinction from the time sequence of the movements. These findings suggest that EEG source amplitudes reconstructed in a cortical patch are the superposition of these simultaneously present network activities. Separating these frequency-specific networks is relevant for studying function and possible dysfunction of the cortical sensorimotor system in humans as well as to provide more advanced features for brain-computer interfaces. Copyright © 2016 the authors 0270-6474/16/3611671-11$15.00/0.

A study of the effectiveness and energy efficiency of ultrasonic emulsification.

PubMed

Li, Wu; Leong, Thomas S H; Ashokkumar, Muthupandian; Martin, Gregory J O

2017-12-20

Three essential experimental parameters in the ultrasonic emulsification process, namely sonication time, acoustic amplitude and processing volume, were individually investigated, theoretically and experimentally, and correlated to the emulsion droplet sizes produced. The results showed that with a decrease in droplet size, two kinetic regions can be separately correlated prior to reaching a steady state droplet size: a fast size reduction region and a steady state transition region. In the fast size reduction region, the power input and sonication time could be correlated to the volume-mean diameter by a power-law relationship, with separate power-law indices of -1.4 and -1.1, respectively. A proportional relationship was found between droplet size and processing volume. The effectiveness and energy efficiency of droplet size reduction was compared between ultrasound and high-pressure homogenisation (HPH) based on both the effective power delivered to the emulsion and the total electric power consumed. Sonication could produce emulsions across a broad range of sizes, while high-pressure homogenisation was able to produce emulsions at the smaller end of the range. For ultrasonication, the energy efficiency was higher at increased power inputs due to more effective droplet breakage at high ultrasound intensities. For HPH the consumed energy efficiency was improved by operating at higher pressures for fewer passes. At the laboratory scale, the ultrasound system required less electrical power than HPH to produce an emulsion of comparable droplet size. The energy efficiency of HPH is greatly improved at large scale, which may also be true for larger scale ultrasonic reactors.

Design and Demonstration of Bolt Retractor Separation System for X-38 Deorbit Propulsion Stage

NASA Technical Reports Server (NTRS)

Ahmed, Raf; Johnston, A. S.; Garrison, J. C.; Gaines, J. L.; Waggoner, J. D.

2003-01-01

A separation system was designed for the X-38 experimental crew return vehicle program to allow the Deorbit Propulsion Stage (DPS) to separate from the X-38 lifting body during reentry operations. The configuration chosen was a spring-loaded plunger, known as the Bolt Retractor Subsystem (BRS), that retracts each of the six DPS-to-lifting body attachment bolts across the interface plane after being triggered by a separation nut mechanism. The system was designed to function on the ground in an atmospheric environment as well as in space. The BRS provides the same functionality as that of a completely pyrotechnic shear separation system that would normally be considered ideal for this application, but at a much lower cost. This system also could potentially be applied to future space station crew return vehicles. The design goal of 40 ms retraction time was successfully met in a series of demonstrations performed at the NASA Marshall Space Flight Center s Pyrotechnic Shock Facility (PSF) and Flight Robotics Laboratory (FRL). It must be emphasized that a full-scale test series was not performed on the BRS due to program schedule and cost constraints.

Spatially modulated structural colour in bird feathers.

PubMed

Parnell, Andrew J; Washington, Adam L; Mykhaylyk, Oleksandr O; Hill, Christopher J; Bianco, Antonino; Burg, Stephanie L; Dennison, Andrew J C; Snape, Mary; Cadby, Ashley J; Smith, Andrew; Prevost, Sylvain; Whittaker, David M; Jones, Richard A L; Fairclough, J Patrick A; Parker, Andrew R

2015-12-21

Eurasian Jay (Garrulus glandarius) feathers display periodic variations in the reflected colour from white through light blue, dark blue and black. We find the structures responsible for the colour are continuous in their size and spatially controlled by the degree of spinodal phase separation in the corresponding region of the feather barb. Blue structures have a well-defined broadband ultra-violet (UV) to blue wavelength distribution; the corresponding nanostructure has characteristic spinodal morphology with a lengthscale of order 150 nm. White regions have a larger 200 nm nanostructure, consistent with a spinodal process that has coarsened further, yielding broader wavelength white reflectance. Our analysis shows that nanostructure in single bird feather barbs can be varied continuously by controlling the time the keratin network is allowed to phase separate before mobility in the system is arrested. Dynamic scaling analysis of the single barb scattering data implies that the phase separation arrest mechanism is rapid and also distinct from the spinodal phase separation mechanism i.e. it is not gelation or intermolecular re-association. Any growing lengthscale using this spinodal phase separation approach must first traverse the UV and blue wavelength regions, growing the structure by coarsening, resulting in a broad distribution of domain sizes.

Spatially modulated structural colour in bird feathers

PubMed Central

Parnell, Andrew J.; Washington, Adam L.; Mykhaylyk, Oleksandr O.; Hill, Christopher J.; Bianco, Antonino; Burg, Stephanie L.; Dennison, Andrew J. C.; Snape, Mary; Cadby, Ashley J.; Smith, Andrew; Prevost, Sylvain; Whittaker, David M.; Jones, Richard A. L.; Fairclough, J. Patrick. A.; Parker, Andrew R.

2015-01-01

Eurasian Jay (Garrulus glandarius) feathers display periodic variations in the reflected colour from white through light blue, dark blue and black. We find the structures responsible for the colour are continuous in their size and spatially controlled by the degree of spinodal phase separation in the corresponding region of the feather barb. Blue structures have a well-defined broadband ultra-violet (UV) to blue wavelength distribution; the corresponding nanostructure has characteristic spinodal morphology with a lengthscale of order 150 nm. White regions have a larger 200 nm nanostructure, consistent with a spinodal process that has coarsened further, yielding broader wavelength white reflectance. Our analysis shows that nanostructure in single bird feather barbs can be varied continuously by controlling the time the keratin network is allowed to phase separate before mobility in the system is arrested. Dynamic scaling analysis of the single barb scattering data implies that the phase separation arrest mechanism is rapid and also distinct from the spinodal phase separation mechanism i.e. it is not gelation or intermolecular re-association. Any growing lengthscale using this spinodal phase separation approach must first traverse the UV and blue wavelength regions, growing the structure by coarsening, resulting in a broad distribution of domain sizes. PMID:26686280

The decay of triple systems

NASA Astrophysics Data System (ADS)

Martynova, A. I.; Orlov, V. V.

2014-10-01

Numerical simulations have been carried out in the general three-body problem with equal masses with zero initial velocities, to investigate the distribution of the decay times T based on a representative sample of initial conditions. The distribution has a power-law character on long time scales, f( T) ∝ T - α , with α = 1.74. Over small times T < 30 T cr ( T cr is the mean crossing time for a component of the triple system), a series of local maxima separated by about 1.0 T cr is observed in the decay-time distribution. These local peaks correspond to zones of decay after one or a few triple encounters. Figures showing the arrangement of these zones in the domain of the initial conditions are presented.

Reynolds number trend of hierarchies and scale interactions in turbulent boundary layers.

PubMed

Baars, W J; Hutchins, N; Marusic, I

2017-03-13

Small-scale velocity fluctuations in turbulent boundary layers are often coupled with the larger-scale motions. Studying the nature and extent of this scale interaction allows for a statistically representative description of the small scales over a time scale of the larger, coherent scales. In this study, we consider temporal data from hot-wire anemometry at Reynolds numbers ranging from Re τ ≈2800 to 22 800, in order to reveal how the scale interaction varies with Reynolds number. Large-scale conditional views of the representative amplitude and frequency of the small-scale turbulence, relative to the large-scale features, complement the existing consensus on large-scale modulation of the small-scale dynamics in the near-wall region. Modulation is a type of scale interaction, where the amplitude of the small-scale fluctuations is continuously proportional to the near-wall footprint of the large-scale velocity fluctuations. Aside from this amplitude modulation phenomenon, we reveal the influence of the large-scale motions on the characteristic frequency of the small scales, known as frequency modulation. From the wall-normal trends in the conditional averages of the small-scale properties, it is revealed how the near-wall modulation transitions to an intermittent-type scale arrangement in the log-region. On average, the amplitude of the small-scale velocity fluctuations only deviates from its mean value in a confined temporal domain, the duration of which is fixed in terms of the local Taylor time scale. These concentrated temporal regions are centred on the internal shear layers of the large-scale uniform momentum zones, which exhibit regions of positive and negative streamwise velocity fluctuations. With an increasing scale separation at high Reynolds numbers, this interaction pattern encompasses the features found in studies on internal shear layers and concentrated vorticity fluctuations in high-Reynolds-number wall turbulence.This article is part of the themed issue 'Toward the development of high-fidelity models of wall turbulence at large Reynolds number'. © 2017 The Author(s).

Temperature and velocity structure functions in the upper troposhere and lower stratosphere from aircraft measurements (Invited)

NASA Astrophysics Data System (ADS)

Wroblewski, D. E.; Werne, J.; Cote, O.; Hacker, J.; Dobosy, R.

2010-12-01

High-resolution turbulence measurements of temperature and three components of velocity were acquired from the GROB 520T EGRETT high altitude research aircraft equipped with three NOAA/FRD built BAT probes. The research campaign spanned eight years with the goal of characterizing clear air turbulence (CAT) and optical turbulence (OpT) in the upper troposphere and lower stratosphere (UTLS), focusing on scales from 1 meter to 1 km, a range that encompasses three-dimensional phenomena critical to CAT and OpT, but for which a dearth of experimental data exists. This talk will cover structure function analysis from 129 separate level flight segments representing 41 hours of flight time and 12,600 km of flight distance. The scaling behavior for sub 100- meter scales will be discussed, with an emphasis on Kelvin-Helmholtz (KH) shear layer development as a phenomenological model for this scale range. Comparisons with micro-scale, direct numerical simulations of KH billows will be presented.

Spontaneous symmetry breaking, conformal anomaly and incompressible fluid turbulence

NASA Astrophysics Data System (ADS)

Oz, Yaron

2017-11-01

We propose an effective conformal field theory (CFT) description of steady state incompressible fluid turbulence at the inertial range of scales in any number of spatial dimensions. We derive a KPZ-type equation for the anomalous scaling of the longitudinal velocity structure functions and relate the intermittency parameter to the boundary Euler (A-type) conformal anomaly coefficient. The proposed theory consists of a mean field CFT that exhibits Kolmogorov linear scaling (K41 theory) coupled to a dilaton. The dilaton is a Nambu-Goldstone gapless mode that arises from a spontaneous breaking due to the energy flux of the separate scale and time symmetries of the inviscid Navier-Stokes equations to a K41 scaling with a dynamical exponent z=2/3 . The dilaton acts as a random measure that dresses the K41 theory and introduces intermittency. We discuss the two, three and large number of space dimensions cases and how entanglement entropy can be used to characterize the intermittency strength.

The statistical overlap theory of chromatography using power law (fractal) statistics.

PubMed

Schure, Mark R; Davis, Joe M

2011-12-30

The chromatographic dimensionality was recently proposed as a measure of retention time spacing based on a power law (fractal) distribution. Using this model, a statistical overlap theory (SOT) for chromatographic peaks is developed that estimates the number of peak maxima as a function of the chromatographic dimension, saturation and scale. Power law models exhibit a threshold region whereby below a critical saturation value no loss of peak maxima due to peak fusion occurs as saturation increases. At moderate saturation, behavior is similar to the random (Poisson) peak model. At still higher saturation, the power law model shows loss of peaks nearly independent of the scale and dimension of the model. The physicochemical meaning of the power law scale parameter is discussed and shown to be equal to the Boltzmann-weighted free energy of transfer over the scale limits. The scale is discussed. Small scale range (small β) is shown to generate more uniform chromatograms. Large scale range chromatograms (large β) are shown to give occasional large excursions of retention times; this is a property of power laws where "wild" behavior is noted to occasionally occur. Both cases are shown to be useful depending on the chromatographic saturation. A scale-invariant model of the SOT shows very simple relationships between the fraction of peak maxima and the saturation, peak width and number of theoretical plates. These equations provide much insight into separations which follow power law statistics. Copyright © 2011 Elsevier B.V. All rights reserved.

Scale disparity and spectral transfer in anisotropic numerical turbulence

NASA Technical Reports Server (NTRS)

Zhou, YE; Yeung, P. K.; Brasseur, James G.

1994-01-01

To study the effect of cancellations within long-range interactions on local isotropy at the small scales, we calculate explicitly the degree of cancellation in distant interactions in the simulations of Yeung & Brasseur and Yeung, Brasseur & Wang using the single scale disparity parameter 's' developed by Zhou. In the simulations, initially isotropic simulated turbulence was subjected to coherent anisotropic forcing at the large scales and the smallest scales were found to become anisotropic as a consequence of direct large-small scale couplings. We find that the marginally distant interactions in the simulation do not cancel out under summation and that the development of small-scale anisotropy is indeed a direct consequence of the distant triadic group, as argued by Yeung, et. al. A reduction of anisotropy at later times occurs as a result of the isotropizing influences of more local energy-cascading triadic interactions. Nevertheless, the local-to-nonlocal triadic group persists as an isotropizing influence at later times. We find that, whereas long-range interactions, in general, contribute little to net energy transfer into or out of a high wavenumber shell k, the anisotropic transfer of component energy within the shell increases with increasing scale separations. These results are consistent with results by Zhou, and Brasseur & Wei, and suggest that the anisotropizing influences of long range interactions should persist to higher Reynolds numbers. The residual effect of the forced distant group in this low-Reynolds number simulation is found to be forward cascading, on average.

Towards integrating tracer studies in conceptual rainfall-runoff models: recent insights from a sub-arctic catchment in the Cairngorm Mountains, Scotland

NASA Astrophysics Data System (ADS)

Soulsby, Chris; Dunn, Sarah M.

2003-02-01

Hydrochemical tracers (alkalinity and silica) were used in an end-member mixing analysis (EMMA) of runoff sources in the 10 km2 Allt a' Mharcaidh catchment. A three-component mixing model was used to separate the hydrograph and estimate, to a first approximation, the range of likely contributions of overland flow, shallow subsurface storm flow, and groundwater to the annual hydrograph. A conceptual, catchment-scale rainfall-runoff model (DIY) was also used to separate the annual hydrograph in an equivalent set of flow paths. The two approaches produced independent representations of catchment hydrology that exhibited reasonable agreement. This showed the dominance of overland flow in generating storm runoff and the important role of groundwater inputs throughout the hydrological year. Moreover, DIY was successfully adapted to simulate stream chemistry (alkalinity) at daily time steps. Sensitivity analysis showed that whilst a distinct groundwater source at the catchment scale could be identified, there was considerable uncertainty in differentiating between overland flow and subsurface storm flow in both the EMMA and DIY applications. Nevertheless, the study indicated that the complementary use of tracer analysis in EMMA can increase the confidence in conceptual model structure. However, conclusions are restricted to the specific spatial and temporal scales examined.

Ultrasonic Cole-Cole diagram for solutions and application to alpha-chymotrypsin.

PubMed

Cerf, R; Salehi, S T; Rogez, D

1989-04-01

Deconvolution of ultrasonic data into single relaxations is rarely feasible when only the absorption or the velocity of the waves is measured. Here we use both series of data to construct a Cole-Cole diagram for a solution. When applied to alpha-chymotrypsin, this method shows two relaxations that are well separated on the time scale, a result that will help simplify analyses of the ultrasonic data for this enzyme.

Ultrasonic Cole-Cole diagram for solutions and application to alpha-chymotrypsin.

PubMed Central

Cerf, R; Salehi, S T; Rogez, D

1989-01-01

Deconvolution of ultrasonic data into single relaxations is rarely feasible when only the absorption or the velocity of the waves is measured. Here we use both series of data to construct a Cole-Cole diagram for a solution. When applied to alpha-chymotrypsin, this method shows two relaxations that are well separated on the time scale, a result that will help simplify analyses of the ultrasonic data for this enzyme. PMID:2720063

Approximate Quantum Dynamics using Ab Initio Classical Separable Potentials: Spectroscopic Applications.

PubMed

Hirshberg, Barak; Sagiv, Lior; Gerber, R Benny

2017-03-14

Algorithms for quantum molecular dynamics simulations that directly use ab initio methods have many potential applications. In this article, the ab initio classical separable potentials (AICSP) method is proposed as the basis for approximate algorithms of this type. The AICSP method assumes separability of the total time-dependent wave function of the nuclei and employs mean-field potentials that govern the dynamics of each degree of freedom. In the proposed approach, the mean-field potentials are determined by classical ab initio molecular dynamics simulations. The nuclear wave function can thus be propagated in time using the effective potentials generated "on the fly". As a test of the method for realistic systems, calculations of the stationary anharmonic frequencies of hydrogen stretching modes were carried out for several polyatomic systems, including three amino acids and the guanine-cytosine pair of nucleobases. Good agreement with experiments was found. The method scales very favorably with the number of vibrational modes and should be applicable for very large molecules, e.g., peptides. The method should also be applicable for properties such as vibrational line widths and line shapes. Work in these directions is underway.

Short-term functional health and well-being after marital separation: does initiator status make a difference?

PubMed

Hewitt, Belinda; Turrell, Gavin

2011-06-01

The authors investigated the health consequences of marital separation and whether the partners who initiated the separation had better health than those who did not. The data came from the Households, Income and Labour Dynamics in Australia (HILDA) panel study (2001-2007), comprising an analytic sample of 1,786 men and 2,068 women who were in their first marriages in 2001. For participants who separated, the authors distinguished between self-initiated, partner-initiated, and jointly initiated separations. Using linear random-intercept models, they examined scores on the 8 physical and mental health dimensions of Short Form 36, with scale scores ranging from 0 to 100. The results indicated that in general, men who separated had a decline in health, although this was more pronounced for mental dimensions than for physical dimensions. Among separated men, those whose partner initiated the separation had poorer mental health than those for whom the separation was self-initiated or jointly initiated (-4.61). Women's physical health improved with separation, but their mental health declined. For separated women, those whose partner initiated the separation had lower scores on the general health (-5.39), role-emotional (-11.08), and mental health (-7.18) scales than women who self-initiated separation. The health consequences of separation were less severe for self- or jointly initiated separations, suggesting that not all marital dissolutions are equally bad for health.

Subgrid-scale parameterization and low-frequency variability: a response theory approach

NASA Astrophysics Data System (ADS)

Demaeyer, Jonathan; Vannitsem, Stéphane

2016-04-01

Weather and climate models are limited in the possible range of resolved spatial and temporal scales. However, due to the huge space- and time-scale ranges involved in the Earth System dynamics, the effects of many sub-grid processes should be parameterized. These parameterizations have an impact on the forecasts or projections. It could also affect the low-frequency variability present in the system (such as the one associated to ENSO or NAO). An important question is therefore to know what is the impact of stochastic parameterizations on the Low-Frequency Variability generated by the system and its model representation. In this context, we consider a stochastic subgrid-scale parameterization based on the Ruelle's response theory and proposed in Wouters and Lucarini (2012). We test this approach in the context of a low-order coupled ocean-atmosphere model, detailed in Vannitsem et al. (2015), for which a part of the atmospheric modes is considered as unresolved. A natural separation of the phase-space into a slow invariant set and its fast complement allows for an analytical derivation of the different terms involved in the parameterization, namely the average, the fluctuation and the long memory terms. Its application to the low-order system reveals that a considerable correction of the low-frequency variability along the invariant subset can be obtained. This new approach of scale separation opens new avenues of subgrid-scale parameterizations in multiscale systems used for climate forecasts. References: Vannitsem S, Demaeyer J, De Cruz L, Ghil M. 2015. Low-frequency variability and heat transport in a low-order nonlinear coupled ocean-atmosphere model. Physica D: Nonlinear Phenomena 309: 71-85. Wouters J, Lucarini V. 2012. Disentangling multi-level systems: averaging, correlations and memory. Journal of Statistical Mechanics: Theory and Experiment 2012(03): P03 003.

Clustering on very small scales from a large sample of confirmed quasar pairs: does quasar clustering track from Mpc to kpc scales?

NASA Astrophysics Data System (ADS)

Eftekharzadeh, S.; Myers, A. D.; Hennawi, J. F.; Djorgovski, S. G.; Richards, G. T.; Mahabal, A. A.; Graham, M. J.

2017-06-01

We present the most precise estimate to date of the clustering of quasars on very small scales, based on a sample of 47 binary quasars with magnitudes of g < 20.85 and proper transverse separations of ˜25 h-1 kpc. Our sample of binary quasars, which is about six times larger than any previous spectroscopically confirmed sample on these scales, is targeted using a kernel density estimation (KDE) technique applied to Sloan Digital Sky Survey (SDSS) imaging over most of the SDSS area. Our sample is 'complete' in that all of the KDE target pairs with 17.0 ≲ R ≲ 36.2 h-1 kpc in our area of interest have been spectroscopically confirmed from a combination of previous surveys and our own long-slit observational campaign. We catalogue 230 candidate quasar pairs with angular separations of <8 arcsec, from which our binary quasars were identified. We determine the projected correlation function of quasars (\\bar{W}_p) in four bins of proper transverse scale over the range 17.0 ≲ R ≲ 36.2 h-1 kpc. The implied small-scale quasar clustering amplitude from the projected correlation function, integrated across our entire redshift range, is A = 24.1 ± 3.6 at ˜26.6 h-1 kpc. Our sample is the first spectroscopically confirmed sample of quasar pairs that is sufficiently large to study how quasar clustering evolves with redshift at ˜25 h-1 kpc. We find that empirical descriptions of how quasar clustering evolves with redshift at ˜25 h-1 Mpc also adequately describe the evolution of quasar clustering at ˜25 h-1 kpc.

Brain Dynamics of Aging: Multiscale Variability of EEG Signals at Rest and during an Auditory Oddball Task1,2,3

PubMed Central

Perdikis, Dionysios; Müller, Viktor; Blanc, Jean-Luc; Huys, Raoul; Temprado, Jean-Jacques

2015-01-01

Abstract The present work focused on the study of fluctuations of cortical activity across time scales in young and older healthy adults. The main objective was to offer a comprehensive characterization of the changes of brain (cortical) signal variability during aging, and to make the link with known underlying structural, neurophysiological, and functional modifications, as well as aging theories. We analyzed electroencephalogram (EEG) data of young and elderly adults, which were collected at resting state and during an auditory oddball task. We used a wide battery of metrics that typically are separately applied in the literature, and we compared them with more specific ones that address their limits. Our procedure aimed to overcome some of the methodological limitations of earlier studies and verify whether previous findings can be reproduced and extended to different experimental conditions. In both rest and task conditions, our results mainly revealed that EEG signals presented systematic age-related changes that were time-scale-dependent with regard to the structure of fluctuations (complexity) but not with regard to their magnitude. Namely, compared with young adults, the cortical fluctuations of the elderly were more complex at shorter time scales, but less complex at longer scales, although always showing a lower variance. Additionally, the elderly showed signs of spatial, as well as between, experimental conditions dedifferentiation. By integrating these so far isolated findings across time scales, metrics, and conditions, the present study offers an overview of age-related changes in the fluctuation electrocortical activity while making the link with underlying brain dynamics. PMID:26464983

Superior lithium adsorption and required magnetic separation behavior of iron-doped lithium ion-sieves

DOE Office of Scientific and Technical Information (OSTI.GOV)

Wang, Shulei; Zheng, Shili; Wang, Zheming

The recent research on adsorption-based lithium recovery from lithium-containing solutions has been centred on adsorption capacity and separation of lithium ion-sieves powder from solutions. Herein, an effective iron-doped lithium titanium oxide (Fe-doped Li 2TiO 3) was synthesized by Fe-doping via solid state reactions followed by acid treatment to form iron-doped lithium ion-sieves (Fe/Ti-x(H)). The resulting solid powder displays both superior adsorption capacity of lithium and high separation efficiency of the adsorbent from the solutions. SEM imaging and BET surface area measurement results showed that at Fe doping levels x ≤ 0.15, Fe-doping led to grain shrinkage as compared to Limore » 2TiO 3 and at the same time the BET surface area increased. The Fe/Ti-0.15(H) exhibited saturated magnetization values of 13.76 emu g -1, allowing effective separation of the material from solid suspensions through the use of a magnet. Consecutive magnetic separation results suggested that the Fe/Ti-0.15(H) powders could be applied at large-scale and continuously removed from LiOH solutions with separation efficiency of 96% or better. Lithium adsorption studies indicated that the equilibrium adsorption capacity of Fe/Ti-0.15(H) in LiOH solutions (1.8 g L -1 Li, pH 12) reached 53.3 mg g -1 within 24 h, which was higher than that of pristine Li 2TiO 3 (50.5 mg g-1) without Fe doping. Competitive adsorption and regeneration results indicated that the Fe/Ti-0.15(H) possessed a high selectivity for Li with facile regeneration. Therefore, it could be expected that the iron-doped lithium ion-sieves have practical applicability potential for large scale lithium extraction and recovery from lithium-bearing solutions.« less

Superior lithium adsorption and required magnetic separation behavior of iron-doped lithium ion-sieves

DOE Office of Scientific and Technical Information (OSTI.GOV)

Wang, Shulei; Zheng, Shili; Wang, Zheming

The recent research on adsorption-based lithium recovery from lithium-containing solutions has been centred on adsorption capacity and separation of lithium ion-sieves powder from solutions. Herein, an effective iron-doped lithium titanium oxide (Fe-doped Li2TiO3) was synthesized by Fe-doping via solid state reactions followed by acid treatment to form iron-doped lithium ion-sieves (Fe/Ti-x(H)). The resulting solid powder displays both superior adsorption capacity of lithium and high separation efficiency of the adsorbent from the solutions. SEM imaging and BET surface area measurement results showed that at Fe doping levels x0.15, Fe-doping led to grain shrinkage as compared to Li2TiO3 and at the samemore » time the BET surface area increased. The Fe/Ti-0.15(H) exhibited saturated magnetization values of 13.76 emu g-1, allowing effective separation of the material from solid suspensions through the use of a magnet. Consecutive magnetic separation results suggested that the Fe/Ti-0.15(H) powders could be applied at large-scale and continuously removed from LiOH solutions with separation efficiency of 96% or better. Lithium adsorption studies indicated that the equilibrium adsorption capacity of Fe/Ti-0.15(H) in LiOH 2 solutions (1.8 g L-1 Li, pH 12) reached 53.3 mg g-1 within 24 h, which was higher than that of pristine Li2TiO3 (50.5 mg g-1) without Fe doping. Competitive adsorption and regeneration results indicated that the Fe/Ti-0.15(H) possessed a high selectivity for Li with facile regeneration. Therefore, it could be expected that the iron-doped lithium ion-sieves have practical applicability potential for large scale lithium extraction and recovery from lithium-bearing solutions.« less

The effect of a lidocaine/prilocaine topical anesthetic on pain and discomfort associated with orthodontic elastomeric separator placement.

PubMed

Al-Melh, M Abu; Andersson, L

2017-12-01

The initial placement of orthodontic elastomeric separators can be uncomfortable and painful. Therefore, it is important to relieve this disturbing sensation to create a discomfort or pain-free orthodontic visit. The purpose of this study was to investigate the effect of a lidocaine/prilocaine topical anesthetic on pain and discomfort associated with the placement of orthodontic elastomeric separators. Fifty subjects aging between 20-35 years were included in this study. In the maxillary arch, a lidocaine/prilocaine topical anesthetic was placed around the ginigval margins of the premolar and molar on side. On the other side, a placebo agent was placed around the ginigval margins of the premolar and molar. After two minutes, an elastomeric separator was placed between the premolar and molar on both sides. The subjects were then asked to report their findings on a Verbal Scale and a Visual Analogue Scale every second minute for a period of 10 min. The subjects were also given a questionnaire to evaluate the overall impression on the topical anesthetic use. The overall mean discomfort/pain score was found to be significantly lower (p < 0.001) with the topical anesthetic than with the placebo. Repeated measures ANOVA with a Greenhouse-Geisser correction determined that mean pain scores were statistically significantly low with the 10-min time duration (F (1.54,42.2)  = 40.7, p = 0.001), with an estimated grand mean (8.37, 95% CI 6.75-9.98). The questionnaire responses revealed that 87% of the subjects reported an overall satisfaction and agreement with the topical anesthetic than with the placebo or no difference (13%) after the initial separator placement. The discomfort and pain resulting from the initial placement of orthodontic elastomeric separators can be significantly reduced with the lidocaine/prilocaine topical anesthetic.

Superior lithium adsorption and required magnetic separation behavior of iron-doped lithium ion-sieves

DOE PAGES

Wang, Shulei; Zheng, Shili; Wang, Zheming; ...

2018-09-09

The recent research on adsorption-based lithium recovery from lithium-containing solutions has been centred on adsorption capacity and separation of lithium ion-sieves powder from solutions. Herein, an effective iron-doped lithium titanium oxide (Fe-doped Li 2TiO 3) was synthesized by Fe-doping via solid state reactions followed by acid treatment to form iron-doped lithium ion-sieves (Fe/Ti-x(H)). The resulting solid powder displays both superior adsorption capacity of lithium and high separation efficiency of the adsorbent from the solutions. SEM imaging and BET surface area measurement results showed that at Fe doping levels x ≤ 0.15, Fe-doping led to grain shrinkage as compared to Limore » 2TiO 3 and at the same time the BET surface area increased. The Fe/Ti-0.15(H) exhibited saturated magnetization values of 13.76 emu g -1, allowing effective separation of the material from solid suspensions through the use of a magnet. Consecutive magnetic separation results suggested that the Fe/Ti-0.15(H) powders could be applied at large-scale and continuously removed from LiOH solutions with separation efficiency of 96% or better. Lithium adsorption studies indicated that the equilibrium adsorption capacity of Fe/Ti-0.15(H) in LiOH solutions (1.8 g L -1 Li, pH 12) reached 53.3 mg g -1 within 24 h, which was higher than that of pristine Li 2TiO 3 (50.5 mg g-1) without Fe doping. Competitive adsorption and regeneration results indicated that the Fe/Ti-0.15(H) possessed a high selectivity for Li with facile regeneration. Therefore, it could be expected that the iron-doped lithium ion-sieves have practical applicability potential for large scale lithium extraction and recovery from lithium-bearing solutions.« less

Development of the Faith Activities in the Home Scale (FAITHS)

ERIC Educational Resources Information Center

Lambert, Nathaniel M.; Dollahite, David C.

2010-01-01

This article reports the development of the Faith Activities In The Home Scale (FAITHS). The initial FAITHS measure was improved on and expanded by using qualitative data of two separate samples and then empirically tested on three separate samples. Study 1 comprised two samples totaling 57 highly religious families from New England and California…

Supramolecular separation mechanism of pentafluorophenyl column using ibuprofen and omeprazole as markers: LC-MS and simulation study.

PubMed

Hussain, Afzal; AlAjmi, Mohamed F; Ali, Imran

2018-06-01

The pentafluorophenyl (PFP) column is emerging as a new advancement in separation science to analyze a wide range of analytes and, thus, its separation mechanism at supramolecular level is significant. We developed a mechanism for the separation of ibuprofen and omeprazole using different combinations (ranging from 50:50 to 60:40) of water-acetonitrile containing 0.1% formic acid as the mobile phase. The column used was Waters Acquity UPLC HSS PFP (75 × 2.1 mm, 1.8 μm). The reverse order of elution was observed in different combinations of the mobile phases. The docking study indicated hydrogen bonding between ibuprofen and PFP stationary phase (binding energy was -11.30 kJ/mol). Separation at PFP stationary phase is controlled by hydrogen bonding along with π-π interactions. This stationary phase may be used to analyze both aromatic and aliphatic analytes. The developed mechanism will be useful to separate various analytes by considering the possible interactions, leading to saving of energy, time and money. In addition, this work will be highly useful in preparative chromatography where separation is the major problem at a large scale. Moreover, the developed LC-MS-QTOF method may be used to analyze ibuprofen and omeprazole in an unknown sample owing to the low value of detection limits. Copyright © 2018 John Wiley & Sons, Ltd.

Scale Dependence of Statistics of Spatially Averaged Rain Rate Seen in TOGA COARE Comparison with Predictions from a Stochastic Model

NASA Technical Reports Server (NTRS)

Kundu, Prasun K.; Bell, T. L.; Lau, William K. M. (Technical Monitor)

2002-01-01

A characteristic feature of rainfall statistics is that they in general depend on the space and time scales over which rain data are averaged. As a part of an earlier effort to determine the sampling error of satellite rain averages, a space-time model of rainfall statistics was developed to describe the statistics of gridded rain observed in GATE. The model allows one to compute the second moment statistics of space- and time-averaged rain rate which can be fitted to satellite or rain gauge data to determine the four model parameters appearing in the precipitation spectrum - an overall strength parameter, a characteristic length separating the long and short wavelength regimes and a characteristic relaxation time for decay of the autocorrelation of the instantaneous local rain rate and a certain 'fractal' power law exponent. For area-averaged instantaneous rain rate, this exponent governs the power law dependence of these statistics on the averaging length scale $L$ predicted by the model in the limit of small $L$. In particular, the variance of rain rate averaged over an $L \\times L$ area exhibits a power law singularity as $L \\rightarrow 0$. In the present work the model is used to investigate how the statistics of area-averaged rain rate over the tropical Western Pacific measured with ship borne radar during TOGA COARE (Tropical Ocean Global Atmosphere Coupled Ocean Atmospheric Response Experiment) and gridded on a 2 km grid depends on the size of the spatial averaging scale. Good agreement is found between the data and predictions from the model over a wide range of averaging length scales.

Tiny Molybdenites Tell Diffusion Tales

NASA Astrophysics Data System (ADS)

Stein, H. J.; Hannah, J. L.

2014-12-01

Diffusion invokes micron-scale exchange during crystal growth and dissolution in magma chambers on short time-scales. Fundamental to interpreting such data are assumptions on magma-fluid dynamics at all scales. Nevertheless, elemental diffusion profiles are used to estimate time scales for magma storage, eruption, and recharge. An underutilized timepiece to evaluate diffusion and 3D mobility of magmatic fluids is high-precision Re-Os dating of molybdenite. With spatially unique molybdenite samples from a young ore system (e.g., 1 Ma) and a double Os spike, analytical errors of 1-3 ka unambiguously separate events in time. Re-Os ages show that hydrous shallow magma chambers locally recharge and expel Cu-Mo-Au-silica as superimposed stockwork vein networks at time scales less than a few thousand years [1]. Re-Os ages provide diffusion rates controlled by a dynamic crystal mush, accumulation and expulsion of metalliferous fluid, and magma reorganization after explosive crystallization events. Importantly, this approach has broad application far from ore deposits. Here, we use Re-Os dating of molybdenite to assess time scales for generating and diffusing metals through the deep crust. To maximize opportunity for chemical diffusion, we use a continental-scale Sveconorwegian mylonite zone for the study area. A geologically constrained suite of molybdenite samples was acquired from quarry exposures. Molybdenite, previously unreported, is extremely scarce. Tiny but telling molybdenites include samples from like occurrences to assure geologic accuracy in Re-Os ages. Ages range from mid-Mesoproterozoic to mid-Neoproterozoic, and correspond to early metamorphic dehydration of a regionally widespread biotite-rich gneiss, localized melting of gneiss to form cm-m-scale K-feldspar ± quartz pods, development of vapor-rich, vuggy mm stringers that serve as volatile collection surfaces in felsic leucosomes, and low-angle (relative to foliation) cross-cutting cm-scale quartz veins. Re-Os ages and detailed geologic observation document a 200 m.y. history of metal liberation and diffusion through oxidation. [1] Stein, H.J. (2014) Dating and Tracing the History of Ore Formation, in Holland, H.D. & Turekian, K.K. (eds) Treatise on Geochemistry, 2nd Ed. 13: 87-118, Oxford: Elsevier.

Hybrid magnet devices for molecule manipulation and small scale high gradient-field applications

DOEpatents

Humphries, David E [El Cerrito, CA; Hong, Seok-Cheol [Seoul, KR; Cozzarelli, legal representative, Linda A.; Pollard, Martin J [El Cerrito, CA; Cozzarelli, Nicholas R [Berkeley, CA

2009-01-06

The present disclosure provides a high performance hybrid magnetic structure made from a combination of permanent magnets and ferromagnetic pole materials which are assembled in a predetermined array. The hybrid magnetic structure provides means for separation and other biotechnology applications involving holding, manipulation, or separation of magnetizable molecular structures and targets. Also disclosed are hybrid magnetic tweezers able to exert approximately 1 nN of force to 4.5 .mu.m magnetic bead. The maximum force was experimentally measured to be .about.900 pN which is in good agreement with theoretical estimations and other measurements. In addition, a new analysis scheme that permits fast real-time position measurement in typical geometry of magnetic tweezers has been developed and described in detail.

New Approaches to Parameterizing Convection

NASA Technical Reports Server (NTRS)

Randall, David A.; Lappen, Cara-Lyn

1999-01-01

Many general circulation models (GCMs) currently use separate schemes for planetary boundary layer (PBL) processes, shallow and deep cumulus (Cu) convection, and stratiform clouds. The conventional distinctions. among these processes are somewhat arbitrary. For example, in the stratocumulus-to-cumulus transition region, stratocumulus clouds break up into a combination of shallow cumulus and broken stratocumulus. Shallow cumulus clouds may be considered to reside completely within the PBL, or they may be regarded as starting in the PBL but terminating above it. Deeper cumulus clouds often originate within the PBL with also can originate aloft. To the extent that our models separately parameterize physical processes which interact strongly on small space and time scales, the currently fashionable practice of modularization may be doing more harm than good.

Evolving together: the biology of symbiosis, part 2

PubMed Central

2000-01-01

Symbiotic trade-offs dominate the world of biology and medicine in colonist-host relationships and between separate, mutually dependent organisms of different species. Infectious and parasitic diseases can be better understood by exploring the dynamic continuum between pathogenicity and mutualism, between antagonism and cooperation—the sliding scale along which microorganisms can move in a moment's notice with a single nucleotide substitution. Organisms practicing piracy or pastoralism may be close genetic relatives. Mergers occur not only between cells but also between genomes; viruses co-opt host genes and in turn insert themselves into host genomes. Separate organisms, from ants to fungi to plants, establish symbiotic ties with each other that bind over deep time, generating much of the diversity we see in nature. PMID:16389348

Microscopic modeling of gas-surface scattering: II. Application to argon atom adsorption on a platinum (111) surface

NASA Astrophysics Data System (ADS)

Filinov, A.; Bonitz, M.; Loffhagen, D.

2018-06-01

A new combination of first principle molecular dynamics (MD) simulations with a rate equation model presented in the preceding paper (paper I) is applied to analyze in detail the scattering of argon atoms from a platinum (111) surface. The combined model is based on a classification of all atom trajectories according to their energies into trapped, quasi-trapped and scattering states. The number of particles in each of the three classes obeys coupled rate equations. The coefficients in the rate equations are the transition probabilities between these states which are obtained from MD simulations. While these rates are generally time-dependent, after a characteristic time scale t E of several tens of picoseconds they become stationary allowing for a rather simple analysis. Here, we investigate this time scale by analyzing in detail the temporal evolution of the energy distribution functions of the adsorbate atoms. We separately study the energy loss distribution function of the atoms and the distribution function of in-plane and perpendicular energy components. Further, we compute the sticking probability of argon atoms as a function of incident energy, angle and lattice temperature. Our model is important for plasma-surface modeling as it allows to extend accurate simulations to longer time scales.

Effects of reward context on feedback processing as indexed by time-frequency analysis.

PubMed

Watts, Adreanna T M; Bernat, Edward M

2018-05-11

The role of reward context has been investigated as an important factor in feedback processing. Previous work has demonstrated that the amplitude of the feedback negativity (FN) depends on the value of the outcome relative to the range of possible outcomes in a given context, not the objective value of the outcome. However, some research has shown that the FN does not scale with loss magnitude in loss-only contexts, suggesting that some contexts do not show a pattern of context dependence. Methodologically, time-frequency decomposition techniques have proven useful for isolating time-domain ERP activity as separable processes indexed in delta (< 3 Hz) and theta (3-7 Hz). Thus, the current study assessed the role of context in a modified gambling feedback task using time-frequency analysis to better isolate the underlying processes. Results revealed that theta was more context dependent and reflected a binary evaluation of bad versus good outcomes in the gain and even contexts. Delta was more context independent: good outcomes scaled linearly with reward magnitude and good-bad differences scaled with context valence. Our findings reveal that theta and delta are differentially sensitive to context and that context valence may play a critical role in determining how the brain processes feedback. © 2018 Society for Psychophysiological Research.

Real-Time Atmospheric Phase Fluctuation Correction Using a Phased Array of Widely Separated Antennas: X-Band Results and Ka-Band Progress

NASA Astrophysics Data System (ADS)

Geldzahler, B.; Birr, R.; Brown, R.; Grant, K.; Hoblitzell, R.; Miller, M.; Woods, G.; Argueta, A.; Ciminera, M.; Cornish, T.; D'Addario, L.; Davarian, F.; Kocz, J.; Lee, D.; Morabito, D.; Tsao, P.; Jakeman-Flores, H.; Ott, M.; Soloff, J.; Denn, G.; Church, K.; Deffenbaugh, P.

2016-09-01

NASA is pursuing a demonstration of coherent uplink arraying at 7.145-7.190 GHz (X-band) and 30-31 GHz (Kaband) using three 12m diameter COTS antennas separated by 60m at the Kennedy Space Center in Florida. In addition, we have used up to three 34m antennas separated by 250m at the Goldstone Deep Space Communication Complex in California at X-band 7.1 GHz incorporating real-time correction for tropospheric phase fluctuations. Such a demonstration can enable NASA to design and establish a high power, high resolution, 24/7 availability radar system for (a) tracking and characterizing observations of Near Earth Objects (NEOs), (b) tracking, characterizing and determining the statistics of small-scale (≤10cm) orbital debris, (c) incorporating the capability into its space communication and navigation tracking stations for emergency spacecraft commanding in the Ka band era which NASA is entering, and (d) fielding capabilities of interest to other US government agencies. We present herein the results of our phased array uplink combining at near 7.17 and 8.3 GHz using widely separated antennas demonstrations at both locales, the results of a study to upgrade from a communication to a radar system, and our vision for going forward in implementing a high performance, low lifecycle cost multi-element radar array.

Psychometric properties of the Spanish version of the Controlling Coach Behaviors Scale in the sport context.

PubMed

Castillo, Isabel; Tomás, Inés; Ntoumanis, Nikos; Bartholomew, Kimberley; Duda, Joan L; Balaguer, Isabel

2014-01-01

The purpose of this research was to translate into Spanish and examine the psychometric properties of the Spanish version of the Controlling Coach Behaviors Scale (CCBS) in male soccer players. The CCBS is a questionnaire designed to assess athletes' perceptions of sports coaches' controlling interpersonal style from the perspective of the self-determination theory. Study 1 tested the factorial structure of the translated scale using confirmatory factor analysis (CFA) and provided evidence of discriminant validity. Studies 2 and 3 examined the invariance across time and across competitive level via multi-sample CFA. Reliability analyses were also conducted. The CFA results revealed that a four-factor model was acceptable, indicating that a controlling interpersonal style is a multidimensional construct represented by four separate and related controlling coaching strategies. Further, results supported the invariance of the CCBS factor structure across time and competitive level and provided support for the internal consistency of the scale. Overall, the CCBS demonstrated adequate internal consistency, as well as good factorial validity. The Spanish version of the CCBS represents a valid and reliable adaptation of the instrument, which can be confidently used to measure soccer players' perceptions of their coaches' controlling interpersonal style.

Separations in the STATS report

DOE Office of Scientific and Technical Information (OSTI.GOV)

Choppin, G.R.

1996-12-31

The Separations Technology and Transmutation Systems (STATS) Committee formed a Subcommittee on Separations. This subcommittee was charged with evaluating the separations proposed for the several reactor and accelerator transmutation systems. It was also asked to review the processing options for the safe management of high-level waste generated by the defense programs, in particular, the special problems involved in dealing with the waste at the U.S. Department of Energy (DOE) facility in Hanford, Washington. Based on the evaluations from the Subcommittee on Separations, the STATS Committee concluded that for the reactor transmutation programs, aqueous separations involving a combination of PUREX andmore » TRUEX solvent extraction processes could be used. However, additional research and development (R&D) would be required before full plant-scale use of the TRUEX technology could be employed. Alternate separations technology for the reactor transmutation program involves pyroprocessing. This process would require a significant amount of R&D before its full-scale application can be evaluated.« less

Features of separating turbulent boundary layers

NASA Technical Reports Server (NTRS)

Nagabushana, K. A.; Agarwal, Naval K.; Simpson, Roger L.

1988-01-01

In the present study of two strong adverse pressure gradient flows, mean flow and turbulence characteristics are measured, together with frequency spectra, using hot-wire and laser anemometry. In these separating flows, reattachment occurs over a shorter distance than separation. It is noted that the outer flow variables form a unique set of scaling parameters for streamwise power spectra in adverse pressure gradient flows. The inner flow scaling of Perry et al. (1985) for streamwise spectra does not hold in the backflow region unless the value of the downstream-upstream intermittency in the flow is unity.

Nonlinear zero-sum differential game analysis by singular perturbation methods

NASA Technical Reports Server (NTRS)

Sinar, J.; Farber, N.

1982-01-01

A class of nonlinear, zero-sum differential games, exhibiting time-scale separation properties, can be analyzed by singular-perturbation techniques. The merits of such an analysis, leading to an approximate game solution, as well as the 'well-posedness' of the formulation, are discussed. This approach is shown to be attractive for investigating pursuit-evasion problems; the original multidimensional differential game is decomposed to a 'simple pursuit' (free-stream) game and two independent (boundary-layer) optimal-control problems. Using multiple time-scale boundary-layer models results in a pair of uniformly valid zero-order composite feedback strategies. The dependence of suboptimal strategies on relative geometry and own-state measurements is demonstrated by a three dimensional, constant-speed example. For game analysis with realistic vehicle dynamics, the technique of forced singular perturbations and a variable modeling approach is proposed. Accuracy of the analysis is evaluated by comparison with the numerical solution of a time-optimal, variable-speed 'game of two cars' in the horizontal plane.

A design for integration.

PubMed

Fenna, D

1977-09-01

For nearly two decades, the development of computerized information systems has struggled for acceptable compromises between the unattainable "total system" and the unacceptable separate applications. Integration of related applications is essential if the computer is to be exploited fully, yet relative simplicity is necessary for systems to be implemented in a reasonable time-scale. This paper discusses a system being progressively developed from minimal beginnings but which, from the outset, had a highly flexible and fully integrated system basis. The system is for batch processing, but can accommodate on-line data input; it is similar in its approach to many transaction-processing real-time systems.

Pushing x-ray photon correlation spectroscopy beyond the continuous frame rate limit

DOE PAGES

Dufresne, Eric M.; Narayanan, Suresh; Sandy, Alec R.; ...

2016-01-06

We demonstrate delayed-frame X-ray Photon Correlation Spectroscopy with 120 microsecond time resolution, limited only by sample scattering rates, with a prototype Pixel-array detector capable of taking two image frames separated by 153 ns or less. Although the overall frame rate is currently limited to about 4 frame pairs per second, we easily measured millisecond correlation functions. In conclusion, this technology, coupled to the use of brighter synchrotrons such as Petra III or the NSLS-II should enable X-ray Photon Correlation Spectroscopy on microsecond time scales on a wider variety of materials.

Assessing the validity of station location assumptions made in the calculation of the geomagnetic disturbance index, Dst

USGS Publications Warehouse

Gannon, Jennifer

2012-01-01

In this paper, the effects of the assumptions made in the calculation of the Dst index with regard to longitude sampling, hemisphere bias, and latitude correction are explored. The insights gained from this study will allow operational users to better understand the local implications of the Dst index and will lead to future index formulations that are more physically motivated. We recompute the index using 12 longitudinally spaced low-latitude stations, including the traditional 4 (in Honolulu, Kakioka, San Juan, and Hermanus), and compare it to the standard United States Geological Survey definitive Dst. We look at the hemisphere balance by comparing stations at equal geomagnetic latitudes in the Northern and Southern hemispheres. We further separate the 12-station time series into two hemispheric indices and find that there are measurable differences in the traditional Dst formulation due to the undersampling of the Southern Hemisphere in comparison with the Northern Hemisphere. To analyze the effect of latitude correction, we plot latitudinal variation in a disturbance observed during the year 2005 using two separate longitudinal observatory chains. We separate these by activity level and find that while the traditional cosine form fits the latitudinal distributions well for low levels of activity, at higher levels of disturbance the cosine form does not fit the observed variation. This suggests that the traditional latitude scaling is insufficient during active times. The effect of the Northern Hemisphere bias and the inadequate latitude scaling is such that the standard correction underestimates the true disturbance by 10–30 nT for storms of main phase magnitude deviation greater than 150 nT in the traditional Dst index.

Spike avalanches in vivo suggest a driven, slightly subcritical brain state

PubMed Central

Priesemann, Viola; Wibral, Michael; Valderrama, Mario; Pröpper, Robert; Le Van Quyen, Michel; Geisel, Theo; Triesch, Jochen; Nikolić, Danko; Munk, Matthias H. J.

2014-01-01

In self-organized critical (SOC) systems avalanche size distributions follow power-laws. Power-laws have also been observed for neural activity, and so it has been proposed that SOC underlies brain organization as well. Surprisingly, for spiking activity in vivo, evidence for SOC is still lacking. Therefore, we analyzed highly parallel spike recordings from awake rats and monkeys, anesthetized cats, and also local field potentials from humans. We compared these to spiking activity from two established critical models: the Bak-Tang-Wiesenfeld model, and a stochastic branching model. We found fundamental differences between the neural and the model activity. These differences could be overcome for both models through a combination of three modifications: (1) subsampling, (2) increasing the input to the model (this way eliminating the separation of time scales, which is fundamental to SOC and its avalanche definition), and (3) making the model slightly sub-critical. The match between the neural activity and the modified models held not only for the classical avalanche size distributions and estimated branching parameters, but also for two novel measures (mean avalanche size, and frequency of single spikes), and for the dependence of all these measures on the temporal bin size. Our results suggest that neural activity in vivo shows a mélange of avalanches, and not temporally separated ones, and that their global activity propagation can be approximated by the principle that one spike on average triggers a little less than one spike in the next step. This implies that neural activity does not reflect a SOC state but a slightly sub-critical regime without a separation of time scales. Potential advantages of this regime may be faster information processing, and a safety margin from super-criticality, which has been linked to epilepsy. PMID:25009473

Galaxy clustering and the origin of large-scale flows

NASA Technical Reports Server (NTRS)

Juszkiewicz, R.; Yahil, A.

1989-01-01

Peebles's 'cosmic virial theorem' is extended from its original range of validity at small separations, where hydrostatic equilibrium holds, to large separations, in which linear gravitational stability theory applies. The rms pairwise velocity difference at separation r is shown to depend on the spatial galaxy correlation function xi(x) only for x less than r. Gravitational instability theory can therefore be tested by comparing the two up to the maximum separation for which both can reliably be determined, and there is no dependence on the poorly known large-scale density and velocity fields. With the expected improvement in the data over the next few years, however, this method should yield a reliable determination of omega.

Perceived Parental Styles and Adult Separation Anxiety.

PubMed

Başbuğ, Sezin; Cesur, Gizem; Durak Batıgün, Ayşegül

2017-01-01

The Mediating Role of Interpersonal Cognitive Distortions OBJECTIVE: This study primarily aimed to determine whether perceived parental styles and interpersonal cognitive distortions are predictors of adult separation anxiety. Further, this study aimed to examine the mediating role of interpersonal cognitive distortions in the relationship between perceived over-permissive/boundless parental styles and adult separation anxiety in university students. This study included 444 university students (281 female (63,3%) and 163 male (36,7%) with a mean age of sample 21,02 years (SS = 1,70). The Demographic Information Form, Young Parenting Inventory, Interpersonal Cognitive Distortions Scale, and Adult Separation Anxiety Questionnaire were used. The regression analyses revealed that the age of the participants and their percieved controlling/shaping father parenting style negatively predicted adult separation anxiety, while percieved over-permissive/boundless mother parenting style, exploitative/abusive and overprotective/anxious father parenting styles and the subscales of the interpersonal cognitive distortions scale positively predicted adult separation anxiety. As hypothesized, data from this study reveal that subscales of the interpersonal cognitive distortions scale play a full mediating role in the relationship between over-permissive/boundless parenting styles and adult separation anxiety. Results indicate that the perceived over-permissive/boundless parenting style positively predicts adult separation anxiety symptoms by distorting interpersonal cognitions. Furthermore, the over-permissive parenting style and lack of boundaries and/or discipline lead to similar adverse effects as do authoritarian and normative parenting. To our knowledge, there are very few studies investigating adult separation anxiety symptoms in Turkey. Therefore, our current study provides practical information to mental health professionals regarding adult separation anxiety symptoms, which are likely to be accompanied by other psychological symptoms.

Open microfluidic gel electrophoresis: Rapid and low cost separation and analysis of DNA at the nanoliter scale.

PubMed

Gutzweiler, Ludwig; Gleichmann, Tobias; Tanguy, Laurent; Koltay, Peter; Zengerle, Roland; Riegger, Lutz

2017-07-01

Gel electrophoresis is one of the most applied and standardized tools for separation and analysis of macromolecules and their fragments in academic research and in industry. In this work we present a novel approach for conducting on-demand electrophoretic separations of DNA molecules in open microfluidic (OM) systems on planar polymer substrates. The approach combines advantages of slab gel, capillary- and chip-based methods offering low consumable costs (<0.1$) circumventing cost-intensive microfluidic chip fabrication, short process times (5 min per analysis) and high sensitivity (4 ng/μL dsDNA) combined with reasonable resolution (17 bases). The open microfluidic separation system comprises two opposing reservoirs of 2-4 μL in volume, a semi-contact written gel line acting as separation channel interconnecting the reservoirs and sample injected into the line via non-contact droplet dispensing and thus enabling the precise control of the injection plug and sample concentration. Evaporation is prevented by covering aqueous structures with PCR-grade mineral oil while maintaining surface temperature at 15°C. The liquid gel line exhibits a semi-circular cross section of adaptable width (∼200-600 μm) and height (∼30-80 μm) as well as a typical length of 15-55 mm. Layout of such liquid structures is adaptable on-demand not requiring time consuming and repetitive fabrication steps. The approach was successfully demonstrated by the separation of a standard label-free DNA ladder (100-1000 bp) at 100 V/cm via in-line staining and laser induced fluorescent end-point detection using an automated prototype. © 2017 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

Suspended Microchannel Resonators for Ultralow Volume Universal Detection

PubMed Central

Son, Sungmin; Grover, William H.; Burg, Thomas P.; Manalis, Scott R.

2008-01-01

Universal detectors that maintain high sensitivity as the detection volume is reduced to the subnanoliter scale can enhance the utility of miniaturized total analysis systems (μ-TAS). Here the unique scaling properties of the suspended microchannel resonator (SMR) are exploited to show universal detection in a 10 pL analysis volume with a density detection limit of ∼1 μg/cm3 (10 Hz bandwidth) and a dynamic range of 6 decades. Analytes with low UV extinction coefficients such as polyethylene glycol (PEG) 8 kDa, glucose, and glycine are measured with molar detection limits of 0.66, 13.5, and 31.6 μM, respectively. To demonstrate the potential for real-time monitoring, gel filtration chromatography was used to separate different molecular weights of PEG as the SMR acquired a chromatogram by measuring the eluate density. This work suggests that the SMR could offer a simple and sensitive universal detector for various separation systems from liquid chromatography to capillary electrophoresis. Moreover, since the SMR is itself a microfluidic channel, it can be directly integrated into μ-TAS without compromising overall performance. PMID:18489125

Drag reduction and thrust generation by tangential surface motion in flow past a cylinder

NASA Astrophysics Data System (ADS)

Mao, Xuerui; Pearson, Emily

2018-03-01

Sensitivity of drag to tangential surface motion is calculated in flow past a circular cylinder in both two- and three-dimensional conditions at Reynolds number Re ≤ 1000 . The magnitude of the sensitivity maximises in the region slightly upstream of the separation points where the contour lines of spanwise vorticity are normal to the cylinder surface. A control to reduce drag can be obtained by (negatively) scaling the sensitivity. The high correlation of sensitivities of controlled and uncontrolled flow indicates that the scaled sensitivity is a good approximation of the nonlinear optimal control. It is validated through direct numerical simulations that the linear range of the steady control is much higher than the unsteady control, which synchronises the vortex shedding and induces lock-in effects. The steady control injects angular momentum into the separating boundary layer, stabilises the flow and increases the base pressure significantly. At Re=100 , when the maximum tangential motion reaches 50% of the free-stream velocity, the vortex shedding, boundary-layer separation and recirculation bubbles are eliminated and 32% of the drag is reduced. When the maximum tangential motion reaches 2.5 times of the free-stream velocity, thrust is generated and the power savings ratio, defined as the ratio of the reduced drag power to the control input power, reaches 19.6. The mechanism of drag reduction is attributed to the change of the radial gradient of spanwise vorticity (partial r \\hat{ζ } ) and the subsequent accelerated pressure recovery from the uncontrolled separation points to the rear stagnation point.

Transient eddy formation around headlands

USGS Publications Warehouse

Signell, Richard P.; Geyer, W. Rockwell

1991-01-01

Eddies with length scales of 1-10 km are commonly observed in coastal waters and play an important role in the dispersion of water-borne materials. The generation and evolution of these eddies by oscillatory tidal flow around coastal headlands is investigated with analytical and numerical models. Using shallow water depth-averaged vorticity dynamics, eddies are shown to form when flow separation occurs near the tip of the headland, causing intense vorticity generated along the headland to be injected into the interior. An analytic boundary layer model demonstrates that flow separation occurs when the pressure gradient along the boundary switches from favoring (accelerating) to adverse (decelerating), and its occurrence depends principally on three parameters: the aspect ratio [b/a], where b and a are characteristic width and length scales of the headland; [H/CDa], where H is the water depth, CD is the depth-averaged drag coefficient; and [Uo/aa], where Uo and a are the magnitude and frequency of the far-field tidal flow. Simulations with a depth-averaged numerical model show a wide range of responses to changes in these parameters, including cases where no separation occurs, cases where only one eddy exists at a given time, and cases where bottom friction is weak enough that eddies produced during successive tidal cycles coexist, interacting strongly with each other. These simulations also demonstrate that in unsteady flow, a strong start-up vortex forms after the flow separates, leading to a much more intense patch of vorticity and stronger recirculation than found in steady flow. 

The influence of the absence of fathers and the timing of separation on anxiety and self-esteem of adolescents: a cross-sectional survey.

PubMed

Luo, J; Wang, L-G; Gao, W-B

2012-09-01

Many rural children in China have been experiencing life without fathers since the 1990s, when their fathers left the rural areas for the urban areas to find a job that would allow them to continue to support their family. However, to date, knowledge and understanding of the effects of the absence of fathers and timing of separation on the mental health of adolescents are limited. A total of 2233 students, ranging in age from 11 to 23 years, from five provinces of China, including 1024 adolescents who experienced the absence of their fathers, were recruited for this study. The data were collected using State-Trait Anxiety Inventory and Rosenberg Self-Esteem Scale, which were self-report questionnaires. Findings from a structured questionnaire showed that the subjects who experienced life without fathers have increased state-anxiety (t=-5.80, P < 0.001) and lower self-esteem (t= 39.54, P < 0.001) when compared with other subjects, and the above results could be influenced by gender and grade. A limited effect of the timing of separation was found on the mental health of students whose fathers were absent. A significant timing group effect existed for state-anxiety scores [F(3,992) = 2.26, P= 0.05], and post test also revealed that the self-esteem of female scores in the 0-2 timing group was higher than other timing group's [F(3,992) = 4.58, P= 0.004]. The influence of the absence of fathers on the anxiety and self-esteem of adolescents seems to be more serious than our expectation, and the influence will be different according to the timing of father absence. © 2011 Blackwell Publishing Ltd.

Detecting Patchy Reionization in the Cosmic Microwave Background.

PubMed

Smith, Kendrick M; Ferraro, Simone

2017-07-14

Upcoming cosmic microwave background (CMB) experiments will measure temperature fluctuations on small angular scales with unprecedented precision. Small-scale CMB fluctuations are a mixture of late-time effects: gravitational lensing, Doppler shifting of CMB photons by moving electrons [the kinematic Sunyaev-Zel'dovich (KSZ) effect], and residual foregrounds. We propose a new statistic which separates the KSZ signal from the others, and also allows the KSZ signal to be decomposed in redshift bins. The decomposition extends to high redshift and does not require external data sets such as galaxy surveys. In particular, the high-redshift signal from patchy reionization can be cleanly isolated, enabling future CMB experiments to make high-significance and qualitatively new measurements of the reionization era.

Flow Structure along the 1303 UCAV

NASA Astrophysics Data System (ADS)

Kosoglu, Mehmet A.; Rockwell, Donald

2007-11-01

The 1303 Unmanned Combat Air Vehicle is representative of a variety of UCAVs with blended wing-body configurations. Flow structure along a scale model of this configuration was investigated using dye visualization and particle image velocimetry for variations of Reynolds number and angle-of-attack. Both of these parameters substantially influence onset and structure of the leading-edge vortex (LEV) and a separation bubble/stall region along the tip. The onset of formation of the LEV initially occurs at a location well downstream of the apex and moves upstream for increasing values of either Reynolds number or angle-of-attack. In cases where a separation bubble or stall region exists, quantitative information on its structure was obtained via PIV imaging on a plane nearly parallel to the surface of the wing. By acquiring images on planes at successively larger elevations from the surface, it was possible to gain insight into the space-time features of the three-dimensional and highly time-dependent structure of the bubble or stall region. Time-averaged images indicate that maximum velocity defect decreases in magnitude and moves downstream with increasing elevation from the surface.

Collective odor source estimation and search in time-variant airflow environments using mobile robots.

PubMed

Meng, Qing-Hao; Yang, Wei-Xing; Wang, Yang; Zeng, Ming

2011-01-01

This paper addresses the collective odor source localization (OSL) problem in a time-varying airflow environment using mobile robots. A novel OSL methodology which combines odor-source probability estimation and multiple robots' search is proposed. The estimation phase consists of two steps: firstly, the separate probability-distribution map of odor source is estimated via Bayesian rules and fuzzy inference based on a single robot's detection events; secondly, the separate maps estimated by different robots at different times are fused into a combined map by way of distance based superposition. The multi-robot search behaviors are coordinated via a particle swarm optimization algorithm, where the estimated odor-source probability distribution is used to express the fitness functions. In the process of OSL, the estimation phase provides the prior knowledge for the searching while the searching verifies the estimation results, and both phases are implemented iteratively. The results of simulations for large-scale advection-diffusion plume environments and experiments using real robots in an indoor airflow environment validate the feasibility and robustness of the proposed OSL method.

Collective Odor Source Estimation and Search in Time-Variant Airflow Environments Using Mobile Robots

PubMed Central

Meng, Qing-Hao; Yang, Wei-Xing; Wang, Yang; Zeng, Ming

2011-01-01

This paper addresses the collective odor source localization (OSL) problem in a time-varying airflow environment using mobile robots. A novel OSL methodology which combines odor-source probability estimation and multiple robots’ search is proposed. The estimation phase consists of two steps: firstly, the separate probability-distribution map of odor source is estimated via Bayesian rules and fuzzy inference based on a single robot’s detection events; secondly, the separate maps estimated by different robots at different times are fused into a combined map by way of distance based superposition. The multi-robot search behaviors are coordinated via a particle swarm optimization algorithm, where the estimated odor-source probability distribution is used to express the fitness functions. In the process of OSL, the estimation phase provides the prior knowledge for the searching while the searching verifies the estimation results, and both phases are implemented iteratively. The results of simulations for large-scale advection–diffusion plume environments and experiments using real robots in an indoor airflow environment validate the feasibility and robustness of the proposed OSL method. PMID:22346650

Transit timing variations for planets co-orbiting in the horseshoe regime

DOE Office of Scientific and Technical Information (OSTI.GOV)

Vokrouhlický, David; Nesvorný, David, E-mail: vokrouhl@cesnet.cz, E-mail: davidn@boulder.swri.edu

2014-08-10

Although not yet detected, pairs of exoplanets in 1:1 mean motion resonance probably exist. Low eccentricity, near-planar orbits, which in the comoving frame follow horseshoe trajectories, are one of the possible stable configurations. Here we study transit timing variations (TTVs) produced by mutual gravitational interaction of planets in this orbital architecture, with the goal to develop methods that can be used to recognize this case in observational data. In particular, we use a semi-analytic model to derive parametric constraints that should facilitate data analysis. We show that characteristic traits of the TTVs can directly constrain the (1) ratio of planetarymore » masses and (2) their total mass (divided by that of the central star) as a function of the minimum angular separation as seen from the star. In an ideal case, when transits of both planets are observed and well characterized, the minimum angular separation can also be inferred from the data. As a result, parameters derived from the observed transit timing series alone can directly provide both planetary masses scaled to the central star mass.« less

Computational Study of Axisymmetric Off-Design Nozzle Flows

NASA Technical Reports Server (NTRS)

DalBello, Teryn; Georgiadis, Nicholas; Yoder, Dennis; Keith, Theo

2003-01-01

Computational Fluid Dynamics (CFD) analyses of axisymmetric circular-arc boattail nozzles operating off-design at transonic Mach numbers have been completed. These computations span the very difficult transonic flight regime with shock-induced separations and strong adverse pressure gradients. External afterbody and internal nozzle pressure distributions computed with the Wind code are compared with experimental data. A range of turbulence models were examined, including the Explicit Algebraic Stress model. Computations have been completed at freestream Mach numbers of 0.9 and 1.2, and nozzle pressure ratios (NPR) of 4 and 6. Calculations completed with variable time-stepping (steady-state) did not converge to a true steady-state solution. Calculations obtained using constant timestepping (timeaccurate) indicate less variations in flow properties compared with steady-state solutions. This failure to converge to a steady-state solution was the result of using variable time-stepping with large-scale separations present in the flow. Nevertheless, time-averaged boattail surface pressure coefficient and internal nozzle pressures show reasonable agreement with experimental data. The SST turbulence model demonstrates the best overall agreement with experimental data.

Inverse and Direct Energy Cascades in Three-Dimensional Magnetohydrodynamic Turbulence at Low Magnetic Reynolds Number

NASA Astrophysics Data System (ADS)

Baker, Nathaniel T.; Pothérat, Alban; Davoust, Laurent; Debray, François

2018-06-01

This experimental study analyzes the relationship between the dimensionality of turbulence and the upscale or downscale nature of its energy transfers. We do so by forcing low-R m magnetohydrodynamic turbulence in a confined channel, while precisely controlling its dimensionality by means of an externally applied magnetic field. We first identify a specific length scale l^⊥ c that separates smaller 3D structures from larger quasi-2D ones. We then show that an inverse energy cascade of horizontal kinetic energy along horizontal scales is always observable at large scales, and that it extends well into the region of 3D structures. At the same time, a direct energy cascade confined to the smallest and strongly 3D scales is observed. These dynamics therefore appear not to be simply determined by the dimensionality of individual scales, nor by the forcing scale, unlike in other studies. In fact, our findings suggest that the relationship between kinematics and dynamics is not universal and may strongly depend on the forcing and dissipating mechanisms at play.

A living mesoscopic cellular automaton made of skin scales.

PubMed

Manukyan, Liana; Montandon, Sophie A; Fofonjka, Anamarija; Smirnov, Stanislav; Milinkovitch, Michel C

2017-04-12

In vertebrates, skin colour patterns emerge from nonlinear dynamical microscopic systems of cell interactions. Here we show that in ocellated lizards a quasi-hexagonal lattice of skin scales, rather than individual chromatophore cells, establishes a green and black labyrinthine pattern of skin colour. We analysed time series of lizard scale colour dynamics over four years of their development and demonstrate that this pattern is produced by a cellular automaton (a grid of elements whose states are iterated according to a set of rules based on the states of neighbouring elements) that dynamically computes the colour states of individual mesoscopic skin scales to produce the corresponding macroscopic colour pattern. Using numerical simulations and mathematical derivation, we identify how a discrete von Neumann cellular automaton emerges from a continuous Turing reaction-diffusion system. Skin thickness variation generated by three-dimensional morphogenesis of skin scales causes the underlying reaction-diffusion dynamics to separate into microscopic and mesoscopic spatial scales, the latter generating a cellular automaton. Our study indicates that cellular automata are not merely abstract computational systems, but can directly correspond to processes generated by biological evolution.

A living mesoscopic cellular automaton made of skin scales

NASA Astrophysics Data System (ADS)

Manukyan, Liana; Montandon, Sophie A.; Fofonjka, Anamarija; Smirnov, Stanislav; Milinkovitch, Michel C.

2017-04-01

In vertebrates, skin colour patterns emerge from nonlinear dynamical microscopic systems of cell interactions. Here we show that in ocellated lizards a quasi-hexagonal lattice of skin scales, rather than individual chromatophore cells, establishes a green and black labyrinthine pattern of skin colour. We analysed time series of lizard scale colour dynamics over four years of their development and demonstrate that this pattern is produced by a cellular automaton (a grid of elements whose states are iterated according to a set of rules based on the states of neighbouring elements) that dynamically computes the colour states of individual mesoscopic skin scales to produce the corresponding macroscopic colour pattern. Using numerical simulations and mathematical derivation, we identify how a discrete von Neumann cellular automaton emerges from a continuous Turing reaction-diffusion system. Skin thickness variation generated by three-dimensional morphogenesis of skin scales causes the underlying reaction-diffusion dynamics to separate into microscopic and mesoscopic spatial scales, the latter generating a cellular automaton. Our study indicates that cellular automata are not merely abstract computational systems, but can directly correspond to processes generated by biological evolution.

Large-scale production of diesel-like biofuels - process design as an inherent part of microorganism development.

PubMed

Cuellar, Maria C; Heijnen, Joseph J; van der Wielen, Luuk A M

2013-06-01

Industrial biotechnology is playing an important role in the transition to a bio-based economy. Currently, however, industrial implementation is still modest, despite the advances made in microorganism development. Given that the fuels and commodity chemicals sectors are characterized by tight economic margins, we propose to address overall process design and efficiency at the start of bioprocess development. While current microorganism development is targeted at product formation and product yield, addressing process design at the start of bioprocess development means that microorganism selection can also be extended to other critical targets for process technology and process scale implementation, such as enhancing cell separation or increasing cell robustness at operating conditions that favor the overall process. In this paper we follow this approach for the microbial production of diesel-like biofuels. We review current microbial routes with both oleaginous and engineered microorganisms. For the routes leading to extracellular production, we identify the process conditions for large scale operation. The process conditions identified are finally translated to microorganism development targets. We show that microorganism development should be directed at anaerobic production, increasing robustness at extreme process conditions and tailoring cell surface properties. All the same time, novel process configurations integrating fermentation and product recovery, cell reuse and low-cost technologies for product separation are mandatory. This review provides a state-of-the-art summary of the latest challenges in large-scale production of diesel-like biofuels. Copyright © 2013 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

The new climate data record of total and spectral solar irradiance: Current progress and future steps

NASA Astrophysics Data System (ADS)

Coddington, Odele; Lean, Judith; Rottman, Gary; Pilewskie, Peter; Snow, Martin; Lindholm, Doug

2016-04-01

We present a climate data record of Total Solar Irradiance (TSI) and Solar Spectral Irradiance (SSI), with associated time and wavelength dependent uncertainties, from 1610 to the present. The data record was developed jointly by the Laboratory for Atmospheric and Space Physics (LASP) at the University of Colorado Boulder and the Naval Research Laboratory (NRL) as part of the National Oceanographic and Atmospheric Administration's (NOAA) National Centers for Environmental Information (NCEI) Climate Data Record (CDR) Program, where the data record, source code, and supporting documentation are archived. TSI and SSI are constructed from models that determine the changes from quiet Sun conditions arising from bright faculae and dark sunspots on the solar disk using linear regression of proxies of solar magnetic activity with observations from the SOlar Radiation and Climate Experiment (SORCE) Total Irradiance Monitor (TIM), Spectral Irradiance Monitor (SIM), and SOlar Stellar Irradiance Comparison Experiment (SOLSTICE). We show that TSI can be separately modeled to within TIM's measurement accuracy from solar rotational to solar cycle time scales and we assume that SSI measurements are reliable on solar rotational time scales. We discuss the model formulation, uncertainty estimates, and operational implementation and present comparisons of the modeled TSI and SSI with the measurement record and with other solar irradiance models. We also discuss ongoing work to assess the sensitivity of the modeled irradiances to model assumptions, namely, the scaling of solar variability from rotational-to-cycle time scales and the representation of the sunspot darkening index.

Short-term dynamics of the high-latitude auroral distribution

DOE Office of Scientific and Technical Information (OSTI.GOV)

Murphree, J.S.; Elphinstone, R.D.; Cogger, L.L.

During two consecutive orbits of the Viking satellite on March 24, 1986, UV observations of the northern hemisphere auroral distribution revealed rapid growth and decay of large-scale polar arcs. Evolution of these features occurred from the nightside auroral distribution (to which they are optically connected) toward the dayside. The connection on the dayside was short-lived ({approx} 2 min) and the arc retreated at similar speeds to its development ({approx} 5 km/s). Time scales for growth (at least to the level of the sensitivity of the instrument) can also be less than 1 min. Examples of arc occurrences during a half-hourmore » time period show that arcs can extend from the nightside to the dayside and disappear and another extended arc can appear at a widely separated position. These types of dynamic polar features appear consistent with the dynamic energization and precipitation of boundary layer electrons at high latitudes.« less

Towards the computation of time-periodic inertial range dynamics

NASA Astrophysics Data System (ADS)

van Veen, L.; Vela-Martín, A.; Kawahara, G.

2018-04-01

We explore the possibility of computing simple invariant solutions, like travelling waves or periodic orbits, in Large Eddy Simulation (LES) on a periodic domain with constant external forcing. The absence of material boundaries and the simple forcing mechanism make this system a comparatively simple target for the study of turbulent dynamics through invariant solutions. We show, that in spite of the application of eddy viscosity the computations are still rather challenging and must be performed on GPU cards rather than conventional coupled CPUs. We investigate the onset of turbulence in this system by means of bifurcation analysis, and present a long-period, large-amplitude unstable periodic orbit that is filtered from a turbulent time series. Although this orbit is computed on a coarse grid, with only a small separation between the integral scale and the LES filter length, the periodic dynamics seem to capture a regeneration process of the large-scale vortices.

On the structure of contact binaries. I - The contact discontinuity

NASA Technical Reports Server (NTRS)

Shu, F. H.; Lubow, S. H.; Anderson, L.

1976-01-01

The problem of the interior structure of contact binaries is reviewed, and a simple resolution of the difficulties which plague the theory is suggested. It is proposed that contact binaries contain a contact discontinuity between the lower surface of the common envelope and the Roche lobe of the cooler star. This discontinuity is maintained against thermal diffusion by fluid flow, and the transition layer is thin to the extent that the dynamical time scale is short in comparison with the thermal time scale. The idealization that the transition layer has infinitesimal thickness allows a simple formulation of the structure equations which are closed by appropriate jump conditions across the discontinuity. The further imposition of the standard boundary conditions suffices to define a unique model for the system once the chemical composition, the masses of the two stars, and the orbital separation are specified.

Differential absorption lidar observation on small-time-scale features of water vapor in the atmospheric boundary layer

NASA Astrophysics Data System (ADS)

Kong, Wei; Li, Jiatang; Liu, Hao; Chen, Tao; Hong, Guanglie; Shu, Rong

2017-11-01

Observation on small-time-scale features of water vapor density is essential for turbulence, convection and many other fast atmospheric processes study. For the high signal-to-noise signal of elastic signal acquired by differential absorption lidar, it has great potential for all-day water vapor turbulence observation. This paper presents a set of differential absorption lidar at 935nm developed by Shanghai Institute of Technical Physics of the Chinese Academy of Science for water vapor turbulence observation. A case at the midday is presented to demonstrate the daytime observation ability of this system. "Autocovariance method" is used to separate the contribution of water vapor fluctuation from random error. The results show that the relative error is less than 10% at temporal and spatial resolution of 10 seconds and 60 meters in the ABL. This indicate that the system has excellent performance for daytime water vapor turbulence observation.

Critical Thresholds in Earth-System Dynamics

NASA Astrophysics Data System (ADS)

Rothman, D.

2017-12-01

The history of the Earth system is a story of change. Some changesare gradual and benign, but others, especially those associated withcatastrophic mass extinction, are relatively abrupt and destructive.What sets one group apart from the other? Here I hypothesize thatperturbations of Earth's carbon cycle lead to mass extinction if theyexceed either a critical rate at long time scales or a critical sizeat short time scales. By analyzing 31 carbon-isotopic events duringthe last 542 million years, I identify the critical rate with a limitimposed by mass conservation. Further analysis identifies thecrossover timescale separating fast from slow events with thetimescale of the ocean's homeostatic response to a change in pH. Theproduct of the critical rate and the crossover timescale then yieldsthe critical size. The modern critical size for the marine carboncycle is roughly similar to the mass of carbon that human activitieswill likely have added to the oceans by the year 2100.

Hybrid model for simulation of plasma jet injection in tokamak

NASA Astrophysics Data System (ADS)

Galkin, Sergei A.; Bogatu, I. N.

2016-10-01

Hybrid kinetic model of plasma treats the ions as kinetic particles and the electrons as charge neutralizing massless fluid. The model is essentially applicable when most of the energy is concentrated in the ions rather than in the electrons, i.e. it is well suited for the high-density hyper-velocity C60 plasma jet. The hybrid model separates the slower ion time scale from the faster electron time scale, which becomes disregardable. That is why hybrid codes consistently outperform the traditional PIC codes in computational efficiency, still resolving kinetic ions effects. We discuss 2D hybrid model and code with exact energy conservation numerical algorithm and present some results of its application to simulation of C60 plasma jet penetration through tokamak-like magnetic barrier. We also examine the 3D model/code extension and its possible applications to tokamak and ionospheric plasmas. The work is supported in part by US DOE DE-SC0015776 Grant.

Dynamical evolution of domain walls in an expanding universe

NASA Technical Reports Server (NTRS)

Press, William H.; Ryden, Barbara S.; Spergel, David N.

1989-01-01

Whenever the potential of a scalar field has two or more separated, degenerate minima, domain walls form as the universe cools. The evolution of the resulting network of domain walls is calculated for the case of two potential minima in two and three dimensions, including wall annihilation, crossing, and reconnection effects. The nature of the evolution is found to be largely independent of the rate at which the universe expands. Wall annihilation and reconnection occur almost as fast as causality allows, so that the horizon volume is 'swept clean' and contains, at any time, only about one, fairly smooth, wall. Quantitative statistics are given. The total area of wall per volume decreases as the first power of time. The relative slowness of the decrease and the smoothness of the wall on the horizon scale make it impossible for walls to both generate large-scale structure and be consistent with quadrupole microwave background anisotropy limits.

Thermoset molecular composites

DOEpatents

Benicewicz, Brian C.; Douglas, Elliot P.; Hjelm, Jr., Rex P.

1996-01-01

A polymeric composition including a liquid crystalline polymer and a thermosettable liquid crystalline monomer matrix, said polymeric composition characterized by a phase separation on the scale of less than about 500 Angstroms and a polymeric composition including a liquid crystalline polymer and a liquid crystalline thermoset matrix, said polymeric composition characterized by a phase separation on the scale of less than about 500 Angstroms are disclosed.

Flow Separation

DTIC Science & Technology

1975-11-01

PLENUM CHAMBER 4 DIFFUSER 2 FIXEn NOZZLE BLOCK 5 MODEL i MOVABLE NOZZLE BLOCK 6 SUPPORT Fig. 3. Trl-Color Filter ...boun- dary layer ( Model 2) to examine scaling effects. Special attention was paid to the phenomenon of flow separation in three dimensions...consequence. Special attention should be paid to the difference in scale of an average boundary layer thickness between Model 1 and 2. Because

Gross separation approaching a blunt trailing edge as the turbulence intensity increases.

PubMed

Scheichl, B

2014-07-28

A novel rational description of incompressible two-dimensional time-mean turbulent boundary layer (BL) flow separating from a bluff body at an arbitrarily large globally formed Reynolds number, Re, is devised. Partly in contrast to and partly complementing previous approaches, it predicts a pronounced delay of massive separation as the turbulence intensity level increases. This is bounded from above by a weakly decaying Re-dependent gauge function (hence, the BL approximation stays intact locally), and thus the finite intensity level characterizing fully developed turbulence. However, it by far exceeds the moderate level found in a preceding study which copes with the associated moderate delay of separation. Thus, the present analysis bridges this self-consistent and another forerunner theory, proposing extremely retarded separation by anticipating a fully attached external potential flow. Specifically, it is shown upon formulation of a respective distinguished limit at which rate the separation point and the attached-flow trailing edge collapse as [Formula: see text] and how on a short streamwise scale the typical small velocity deficit in the core region of the incident BL evolves to a large one. Hence, at its base, the separating velocity profile varies generically with the one-third power of the wall distance, and the classical triple-deck problem describing local viscous-inviscid interaction crucial for moderately retarded separation is superseded by a Rayleigh problem, governing separation of that core layer. Its targeted solution proves vital for understanding the separation process more close to the wall. Most importantly, the analysis does not resort to any specific turbulence closure. A first comparison with the available experimentally found positions of separation for the canonical flow past a circular cylinder is encouraging. © 2014 The Author(s) Published by the Royal Society. All rights reserved.

Binary Oscillatory Crossflow Electrophoresis

NASA Technical Reports Server (NTRS)

Molloy, Richard F.; Gallagher, Christopher T.; Leighton, David T., Jr.

1997-01-01

Electrophoresis has long been recognized as an effective analytic technique for the separation of proteins and other charged species, however attempts at scaling up to accommodate commercial volumes have met with limited success. In this report we describe a novel electrophoretic separation technique - Binary Oscillatory Crossflow Electrophoresis (BOCE). Numerical simulations indicate that the technique has the potential for preparative scale throughputs with high resolution, while simultaneously avoiding many problems common to conventional electrophoresis. The technique utilizes the interaction of an oscillatory electric field and a transverse oscillatory shear flow to create an active binary filter for the separation of charged protein species. An oscillatory electric field is applied across the narrow gap of a rectangular channel inducing a periodic motion of charged protein species. The amplitude of this motion depends on the dimensionless electrophoretic mobility, alpha = E(sub o)mu/(omega)d, where E(sub o) is the amplitude of the electric field oscillations, mu is the dimensional mobility, omega is the angular frequency of oscillation and d is the channel gap width. An oscillatory shear flow is induced along the length of the channel resulting in the separation of species with different mobilities. We present a model that predicts the oscillatory behavior of charged species and allows estimation of both the magnitude of the induced convective velocity and the effective diffusivity as a function of a in infinitely long channels. Numerical results indicate that in addition to the mobility dependence, the steady state behavior of solute species may be strongly affected by oscillating fluid into and out of the active electric field region at the ends of the cell. The effect is most pronounced using time dependent shear flows of the same frequency (cos((omega)t)) flow mode) as the electric field oscillations. Under such conditions, experiments indicate that solute is drawn into the cell from reservoirs at both ends of the cell leading to a large mass build up. As a consequence, any initially induced mass flux will vanish after short times. This effect was not captured by the infinite channel model and hence numerical and experimental results deviated significantly. The revised model including finite cell lengths and reservoir volumes allowed quantitative predictions of the time history of the concentration profile throughout the system. This latter model accurately describes the fluxes observed for both oscillatory flow modes in experiments using single protein species. Based on the results obtained from research funded under NASA grant NAG-8-1080.S, we conclude that binary separations are not possible using purely oscillatory flow modes because of end effects associated with the cos((omega)t) mode. Our research shows, however, that a combination of cos(2(omega)t) and steady flow should lead to efficient separation free of end effects. This possibility is currently under investigation.

Simulation of Sweep-Jet Flow Control, Single Jet and Full Vertical Tail

NASA Technical Reports Server (NTRS)

Childs, Robert E.; Stremel, Paul M.; Garcia, Joseph A.; Heineck, James T.; Kushner, Laura K.; Storms, Bruce L.

2016-01-01

This work is a simulation technology demonstrator, of sweep jet flow control used to suppress boundary layer separation and increase the maximum achievable load coefficients. A sweep jet is a discrete Coanda jet that oscillates in the plane parallel to an aerodynamic surface. It injects mass and momentum in the approximate streamwise direction. It also generates turbulent eddies at the oscillation frequency, which are typically large relative to the scales of boundary layer turbulence, and which augment mixing across the boundary layer to attack flow separation. Simulations of a fluidic oscillator, the sweep jet emerging from a nozzle downstream of the oscillator, and an array of sweep jets which suppresses boundary layer separation are performed. Simulation results are compared to data from a dedicated validation experiment of a single oscillator and its sweep jet, and from a wind tunnel test of a full-scale Boeing 757 vertical tail augmented with an array of sweep jets. A critical step in the work is the development of realistic time-dependent sweep jet inflow boundary conditions, derived from the results of the single-oscillator simulations, which create the sweep jets in the full-tail simulations. Simulations were performed using the computational fluid dynamics (CFD) solver Overow, with high-order spatial discretization and a range of turbulence modeling. Good results were obtained for all flows simulated, when suitable turbulence modeling was used.

M13 bacteriophage-activated superparamagnetic beads for affinity separation.

PubMed

Muzard, Julien; Platt, Mark; Lee, Gil U

2012-08-06

The growth of the biopharmaceutical industry has created a demand for new technologies for the purification of genetically engineered proteins.The efficiency of large-scale, high-gradient magnetic fishing could be improved if magnetic particles offering higher binding capacity and magnetization were available. This article describes several strategies for synthesizing microbeads that are composed of a M13 bacteriophage layer assembled on a superparamagnetic core. Chemical cross-linking of the pVIII proteins to a carboxyl-functionalized bead produces highly responsive superparamagnetic particles (SPM) with a side-on oriented, adherent virus monolayer. Also, the genetic manipulation of the pIII proteins with a His(6) peptide sequence allows reversible assembly of the bacteriophage on a nitrilotriacetic-acid-functionalized core in an end-on configuration. These phage-magnetic particles are successfully used to separate antibodies from high-protein concentration solutions in a single step with a >90% purity. The dense magnetic core of these particles makes them five times more responsive to magnetic fields than commercial materials composed of polymer-(iron oxide) composites and a monolayer of phage could produce a 1000 fold higher antibody binding capacity. These new bionanomaterials appear to be well-suited to large-scale high-gradient magnetic fishing separation and promise to be cost effective as a result of the self-assembling and self-replicating properties of genetically engineered M13 bacteriophage. Copyright © 2012 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

Origin of two time-scale regimes in potentiometric titration of metal oxides. A replica kinetic Monte Carlo study.

PubMed

Zarzycki, Piotr; Rosso, Kevin M

2009-06-16

Replica kinetic Monte Carlo simulations were used to study the characteristic time scales of potentiometric titration of the metal oxides and (oxy)hydroxides. The effect of surface heterogeneity and surface transformation on the titration kinetics were also examined. Two characteristic relaxation times are often observed experimentally, with the trailing slower part attributed to surface nonuniformity, porosity, polymerization, amorphization, and other dynamic surface processes induced by unbalanced surface charge. However, our simulations show that these two characteristic relaxation times are intrinsic to the proton-binding reaction for energetically homogeneous surfaces, and therefore surface heterogeneity or transformation does not necessarily need to be invoked. However, all such second-order surface processes are found to intensify the separation and distinction of the two kinetic regimes. The effect of surface energetic-topographic nonuniformity, as well dynamic surface transformation, interface roughening/smoothing were described in a statistical fashion. Furthermore, our simulations show that a shift in the point-of-zero charge is expected from increased titration speed, and the pH-dependence of the titration measurement error is in excellent agreement with experimental studies.

Accurate acceleration of kinetic Monte Carlo simulations through the modification of rate constants.

PubMed

Chatterjee, Abhijit; Voter, Arthur F

2010-05-21

We present a novel computational algorithm called the accelerated superbasin kinetic Monte Carlo (AS-KMC) method that enables a more efficient study of rare-event dynamics than the standard KMC method while maintaining control over the error. In AS-KMC, the rate constants for processes that are observed many times are lowered during the course of a simulation. As a result, rare processes are observed more frequently than in KMC and the time progresses faster. We first derive error estimates for AS-KMC when the rate constants are modified. These error estimates are next employed to develop a procedure for lowering process rates with control over the maximum error. Finally, numerical calculations are performed to demonstrate that the AS-KMC method captures the correct dynamics, while providing significant CPU savings over KMC in most cases. We show that the AS-KMC method can be employed with any KMC model, even when no time scale separation is present (although in such cases no computational speed-up is observed), without requiring the knowledge of various time scales present in the system.

Exploring the dynamics of phase separation in colloid-polymer mixtures with long range attraction.

PubMed

Sabin, Juan; Bailey, Arthur E; Frisken, Barbara J

2016-06-28

We have studied the kinetics of phase separation and gel formation in a low-dispersity colloid - non-adsorbing polymer system with long range attraction using small-angle light scattering. This system exhibits two-phase and three-phase coexistence of gas, liquid and crystal phases when the strength of attraction is between 2 and 4kBT and gel phases when the strength of attraction is increased. For those samples that undergo macroscopic phase separation, whether to gas-crystal, gas-liquid or gas-liquid-crystal coexistence, we observe dynamic scaling of the structure factor and growth of a characteristic length scale that behaves as expected for phase separation in fluids. In samples that gel, the power law associated with the growth of the dominant length scale is not equal to 1/3, but appears to depend mainly on the strength of attraction, decreasing from 1/3 for samples near the coexistence region to 1/27 at 8kBT, over a wide range of colloid and polymer concentrations.

Measuring meaning and peace with the FACIT-spiritual well-being scale: distinction without a difference?

PubMed

Peterman, Amy H; Reeve, Charlie L; Winford, Eboni C; Cotton, Sian; Salsman, John M; McQuellon, Richard; Tsevat, Joel; Campbell, Cassie

2014-03-01

The Functional Assessment of Chronic Illness Therapy-Spiritual Well-Being Scale (FACIT-Sp; Peterman, Fitchett, Brady, Hernandez, & Cella, 2002) has become a widely used measure of spirituality; however, there remain questions about its specific factor structure and the validity of scores from its separate scales. Specifically, it remains unclear whether the Meaning and Peace scales denote distinct factors. The present study addresses previous limitations by examining the extent to which the Meaning and Peace scales relate differentially to a variety of physical and mental health variables across 4 sets of data from adults with a number of chronic health conditions. Although a model with separate but correlated factors fit the data better, discriminant validity analyses indicated limited differences in the pattern of associations each scale showed with a wide array of commonly used health and quality-of-life measures. In total, the results suggest that people may distinguish between the concepts of Meaning and Peace, but the observed relations with health outcomes are primarily due to variance shared between the 2 factors. Additional research is needed to better understand the separate and joint role of Meaning and Peace in the quality of life of people with chronic illness. 2014 APA

Measuring Meaning and Peace With the FACIT–Spiritual Well-Being Scale: Distinction Without a Difference?

PubMed Central

Peterman, Amy H.; Reeve, Charlie L.; Winford, Eboni C.; Salsman, John M.; Tsevat, Joel; Cotton, Sian; McQuellon, Richard; Campbell, Cassie

2014-01-01

The Functional Assessment of Chronic Illness Therapy–Spiritual Well-Being Scale (FACIT–Sp; Peterman, Fitchett, Brady, Hernandez, & Cella, 2002) has become a widely used measure of spirituality; however, there remain questions about its specific factor structure and the validity of scores from its separate scales. Specifically, it remains unclear whether the Meaning and Peace scales denote distinct factors. The present study addresses previous limitations by examining the extent to which the Meaning and Peace scales relate differentially to a variety of physical and mental health variables across 4 sets of data from adults with a number of chronic health conditions. Although a model with separate but correlated factors fit the data better, discriminant validity analyses indicated limited differences in the pattern of associations each scale showed with a wide array of commonly used health and quality-of-life measures. In total, the results suggest that people may distinguish between the concepts of Meaning and Peace, but the observed relations with health outcomes are primarily due to variance shared between the 2 factors. Additional research is needed to better understand the separate and joint role of Meaning and Peace in the quality of life of people with chronic illness. PMID:24188147

Neural Representation of Scale Illusion: Magnetoencephalographic Study on the Auditory Illusion Induced by Distinctive Tone Sequences in the Two Ears

PubMed Central

Kuriki, Shinya; Yokosawa, Koichi; Takahashi, Makoto

2013-01-01

The auditory illusory perception “scale illusion” occurs when a tone of ascending scale is presented in one ear, a tone of descending scale is presented simultaneously in the other ear, and vice versa. Most listeners hear illusory percepts of smooth pitch contours of the higher half of the scale in the right ear and the lower half in the left ear. Little is known about neural processes underlying the scale illusion. In this magnetoencephalographic study, we recorded steady-state responses to amplitude-modulated short tones having illusion-inducing pitch sequences, where the sound level of the modulated tones was manipulated to decrease monotonically with increase in pitch. The steady-state responses were decomposed into right- and left-sound components by means of separate modulation frequencies. It was found that the time course of the magnitude of response components of illusion-perceiving listeners was significantly correlated with smooth pitch contour of illusory percepts and that the time course of response components of stimulus-perceiving listeners was significantly correlated with discontinuous pitch contour of stimulus percepts in addition to the contour of illusory percepts. The results suggest that the percept of illusory pitch sequence was represented in the neural activity in or near the primary auditory cortex, i.e., the site of generation of auditory steady-state response, and that perception of scale illusion is maintained by automatic low-level processing. PMID:24086676

Multiscale analysis of structure development in expanded starch snacks

NASA Astrophysics Data System (ADS)

van der Sman, R. G. M.; Broeze, J.

2014-11-01

In this paper we perform a multiscale analysis of the food structuring process of the expansion of starchy snack foods like keropok, which obtains a solid foam structure. In particular, we want to investigate the validity of the hypothesis of Kokini and coworkers, that expansion is optimal at the moisture content, where the glass transition and the boiling line intersect. In our analysis we make use of several tools, (1) time scale analysis from the field of physical transport phenomena, (2) the scale separation map (SSM) developed within a multiscale simulation framework of complex automata, (3) the supplemented state diagram (SSD), depicting phase transition and glass transition lines, and (4) a multiscale simulation model for the bubble expansion. Results of the time scale analysis are plotted in the SSD, and give insight into the dominant physical processes involved in expansion. Furthermore, the results of the time scale analysis are used to construct the SSM, which has aided us in the construction of the multiscale simulation model. Simulation results are plotted in the SSD. This clearly shows that the hypothesis of Kokini is qualitatively true, but has to be refined. Our results show that bubble expansion is optimal for moisture content, where the boiling line for gas pressure of 4 bars intersects the isoviscosity line of the critical viscosity 106 Pa.s, which runs parallel to the glass transition line.

Highly efficient and ultra-small volume separation by pressure-driven liquid chromatography in extended nanochannels.

PubMed

Ishibashi, Ryo; Mawatari, Kazuma; Kitamori, Takehiko

2012-04-23

The rapidly developing interest in nanofluidic analysis, which is used to examine liquids ranging in amounts from the attoliter to the femtoliter scale, correlates with the recent interest in decreased sample amounts, such as in the field of single-cell analysis. For general nanofluidic analysis, the fact that a pressure-driven flow does not limit the choice of solvents (aqueous or organic) is important. This study shows the first pressure-driven liquid chromatography technique that enables separation of atto- to femtoliter sample volumes, with a high separation efficiency within a few seconds. The apparent diffusion coefficient measurement of the unretentive sample suggests that there is no increase in the viscosity of toluene in the extended nanospace, unlike in aqueous solvents. Evaluation of the normal phase separation, therefore, should involve only the examination of the effect of the small size of the extended nanospace. Compared to a conventionally packed high-performance liquid chromatography column, the separation here results in a faster separation (4 s) by 2 orders of magnitude, a smaller injection volume (10(0) fL) by 9 orders, and a higher separation efficiency (440,000 plates/m) by 1 order. Moreover, the separation behavior agrees with the theory showing that this high efficiency was due to the small and controlled size of the separation channel, where the diffusion through the channel depth direction is fast enough to be neglected. Our chip-based platform should allow direct and real-time analysis or screening of ultralow volume of sample. Copyright © 2012 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

Psychometric properties of the Social Interaction Anxiety Scale and separation criterion between Spanish youths with and without subtypes of social anxiety.

PubMed

Zubeidat, Ihab; Salinas, José María; Sierra, Juan Carlos; Fernández-Parra, Antonio

2007-01-01

In this study, we analyzed the reliability and validity of the Social Interaction Anxiety Scale (SIAS) and propose a separation criterion between youths with specific and generalized social anxiety and youths without social anxiety. A sample of 1012 Spanish youths attending school completed the SIAS, the Liebowitz Social Anxiety Scale, the Social Avoidance and Distress Scale, the Fear of Negative Evaluation Scale, the Youth Self-Report for Ages 11-18 and the Minnesota Multiphasic Personality Inventory-Adolescent. The factor analysis suggests the existence of three factors in the SIAS, the first two of which explain most of the variance of the construct assessed. Internal consistency is adequate in the first two factors. The SIAS features an adequate theoretical validity with the scores of different variables related to social interaction. Analysis of the criterion scores yields three groups pertaining to three clearly differentiated clusters. In the third cluster, two of social anxiety groups - specific and generalized - have been identified by means of a quantitative separation criterion.

Studies of Transitional Flow, Unsteady Separation Phenomena and Particle Induced Augmentation Heating on Ablated Nose Tips.

DTIC Science & Technology

1975-10-01

63 29 Variation of Profile Shape with Time for Axisyinmetric Camphor Models 63 30 The Development of Ablated Nose Shapes Over Which Flow...ablation tests using camphor models and inferred from downrange observation of full scale flight missions. Regions of gross instability on nose...been verified in wind tunnel tests of camphor models where shapes similar to those shown on Figure 29 can be developed under transitional conditions

A Theory For The Variability of The Baroclinic Quasi-geostrophic Winnd Driven Circulation.

NASA Astrophysics Data System (ADS)

Ben Jelloul, M.; Huck, T.

We propose a theory of the wind driven circulation based on the large scale (i.e. small Burger number) quasi-geostrophic assumptions retained in the Rhines and Young (1982) classical study of the steady baroclinic flow. We therefore use multiple time scale and asymptotic expansions to separate steady and the time dependent component of the flow. The barotropic flow is given by the Sverdrup balance. At first order in Burger number, the baroclinic flow can be decom- posed in two parts. A steady contribution ensures no flow in the deep layer which is at rest in absence of dissipative processes. Since the baroclinic instability is inhibited at large scale a spectrum of neutral modes also arises. These are of three type, classical Rossby basin modes deformed through advection by the barotropic flow, recirculating modes localized in the recirculation gyre and blocked modes corresponding to closed potential vorticity contours. At next order in Burger number, amplitude equations for baroclinic modes are derived. If dissipative processes are included at this order, the system adjusts towards Rhines and Young solution with a homogenized potential vorticity pool.

Combined aerodynamic and structural dynamic problem emulating routines (CASPER): Theory and implementation

NASA Technical Reports Server (NTRS)

Jones, William H.

1985-01-01

The Combined Aerodynamic and Structural Dynamic Problem Emulating Routines (CASPER) is a collection of data-base modification computer routines that can be used to simulate Navier-Stokes flow through realistic, time-varying internal flow fields. The Navier-Stokes equation used involves calculations in all three dimensions and retains all viscous terms. The only term neglected in the current implementation is gravitation. The solution approach is of an interative, time-marching nature. Calculations are based on Lagrangian aerodynamic elements (aeroelements). It is assumed that the relationships between a particular aeroelement and its five nearest neighbor aeroelements are sufficient to make a valid simulation of Navier-Stokes flow on a small scale and that the collection of all small-scale simulations makes a valid simulation of a large-scale flow. In keeping with these assumptions, it must be noted that CASPER produces an imitation or simulation of Navier-Stokes flow rather than a strict numerical solution of the Navier-Stokes equation. CASPER is written to operate under the Parallel, Asynchronous Executive (PAX), which is described in a separate report.

Effective long wavelength scalar dynamics in de Sitter

DOE Office of Scientific and Technical Information (OSTI.GOV)

Moss, Ian; Rigopoulos, Gerasimos, E-mail: ian.moss@newcastle.ac.uk, E-mail: gerasimos.rigopoulos@ncl.ac.uk

We discuss the effective infrared theory governing a light scalar's long wavelength dynamics in de Sitter spacetime. We show how the separation of scales around the physical curvature radius k / a ∼ H can be performed consistently with a window function and how short wavelengths can be integrated out in the Schwinger-Keldysh path integral formalism. At leading order, and for time scales Δ t >> H {sup −1}, this results in the well-known Starobinsky stochastic evolution. However, our approach allows for the computation of quantum UV corrections, generating an effective potential on which the stochastic dynamics takes place. Themore » long wavelength stochastic dynamical equations are now second order in time, incorporating temporal scales Δ t ∼ H {sup −1} and resulting in a Kramers equation for the probability distribution—more precisely the Wigner function—in contrast to the more usual Fokker-Planck equation. This feature allows us to non-perturbatively evaluate, within the stochastic formalism, not only expectation values of field correlators, but also the stress-energy tensor of φ.« less

Dyadic Short Forms of the Wechsler Adult Intelligence Scale-IV.

PubMed

Denney, David A; Ringe, Wendy K; Lacritz, Laura H

2015-08-01

Full Wechsler Adult Intelligence Scale-Fourth Edition (WAIS-IV) administration can be time-consuming and may not be necessary when intelligence quotient estimates will suffice. Estimated Full Scale Intelligence Quotient (FSIQ) and General Ability Index (GAI) scores were derived from nine dyadic short forms using individual regression equations based on data from a clinical sample (n = 113) that was then cross validated in a separate clinical sample (n = 50). Derived scores accounted for 70%-83% of the variance in FSIQ and 77%-88% of the variance in GAI. Predicted FSIQs were strongly associated with actual FSIQ (rs = .73-.88), as were predicted and actual GAIs (rs = .80-.93). Each of the nine dyadic short forms of the WAIS-IV was a good predictor of FSIQ and GAI in the validation sample. These data support the validity of WAIS-IV short forms when time is limited or lengthier batteries cannot be tolerated by patients. © The Author 2015. Published by Oxford University Press. All rights reserved. For permissions, please e-mail: journals.permissions@oup.com.

Temperature dependence of fast carbonyl backbone dynamics in chicken villin headpiece subdomain

PubMed Central

Vugmeyster, Liliya; Ostrovsky, Dmitry

2012-01-01

Temperature-dependence of protein dynamics can provide information on details of the free energy landscape by probing the characteristics of the potential responsible for the fluctuations. We have investigated the temperature-dependence of picosecond to nanosecond backbone dynamics at carbonyl carbon sites in chicken villin headpiece subdomain protein using a combination of three NMR relaxation rates: 13C′ longitudinal rate, and two cross-correlated rates involving dipolar and chemical shift anisotropy (CSA) relaxation mechanisms, 13C′/13C′−13Cα CSA/dipolar and 13C′/13C′−15N CSA/dipolar. Order parameters have been extracted using the Lipari-Szabo model-free approach assuming a separation of the time scales of internal and molecular motions in the 2–16°C temperature range. There is a gradual deviation from this assumption from lower to higher temperatures, such that above 16°C the separation of the time scales is inconsistent with the experimental data and, thus, the Lipari-Szabo formalism can not be applied. While there are variations among the residues, on the average the order parameters indicate a markedly steeper temperature dependence at backbone carbonyl carbons compared to that probed at amide nitrogens in an earlier study. This strongly advocates for probing sites other than amide nitrogen for accurate characterization of the potential and other thermodynamics characteristics of protein backbone. PMID:21416162

Integrodifferential formulations of the continuous-time random walk for solute transport subject to bimolecular A +B →0 reactions: From micro- to mesoscopic

NASA Astrophysics Data System (ADS)

Hansen, Scott K.; Berkowitz, Brian

2015-03-01

We develop continuous-time random walk (CTRW) equations governing the transport of two species that annihilate when in proximity to one another. In comparison with catalytic or spontaneous transformation reactions that have been previously considered in concert with CTRW, both species have spatially variant concentrations that require consideration. We develop two distinct formulations. The first treats transport and reaction microscopically, potentially capturing behavior at sharp fronts, but at the cost of being strongly nonlinear. The second, mesoscopic, formulation relies on a separation-of-scales technique we develop to separate microscopic-scale reaction and upscaled transport. This simplifies the governing equations and allows treatment of more general reaction dynamics, but requires stronger smoothness assumptions of the solution. The mesoscopic formulation is easily tractable using an existing solution from the literature (we also provide an alternative derivation), and the generalized master equation (GME) for particles undergoing A +B →0 reactions is presented. We show that this GME simplifies, under appropriate circumstances, to both the GME for the unreactive CTRW and to the advection-dispersion-reaction equation. An additional major contribution of this work is on the numerical side: to corroborate our development, we develop an indirect particle-tracking-partial-integro-differential-equation (PIDE) hybrid verification technique which could be applicable widely in reactive anomalous transport. Numerical simulations support the mesoscopic analysis.

From Fibrils to Toughness: Multi-Scale Mechanics of Fibrillating Interfaces in Stretchable Electronics

PubMed Central

van der Sluis, Olaf; Vossen, Bart; Geers, Marc

2018-01-01

Metal-elastomer interfacial systems, often encountered in stretchable electronics, demonstrate remarkably high interface fracture toughness values. Evidently, a large gap exists between the rather small adhesion energy levels at the microscopic scale (‘intrinsic adhesion’) and the large measured macroscopic work-of-separation. This energy gap is closed here by unravelling the underlying dissipative mechanisms through a systematic numerical/experimental multi-scale approach. This self-containing contribution collects and reviews previously published results and addresses the remaining open questions by providing new and independent results obtained from an alternative experimental set-up. In particular, the experimental studies on Cu-PDMS (Poly(dimethylsiloxane)) samples conclusively reveal the essential role of fibrillation mechanisms at the micro-meter scale during the metal-elastomer delamination process. The micro-scale numerical analyses on single and multiple fibrils show that the dynamic release of the stored elastic energy by multiple fibril fracture, including the interaction with the adjacent deforming bulk PDMS and its highly nonlinear behaviour, provide a mechanistic understanding of the high work-of-separation. An experimentally validated quantitative relation between the macroscopic work-of-separation and peel front height is established from the simulation results. Finally, it is shown that a micro-mechanically motivated shape of the traction-separation law in cohesive zone models is essential to describe the delamination process in fibrillating metal-elastomer systems in a physically meaningful way. PMID:29393908

Scale-up protein separation on stainless steel wide bore toroidal columns in the type-J counter-current chromatography.

PubMed

Guan, Yue Hugh; Hewitson, Peter; van den Heuvel, Remco N A M; Zhao, Yan; Siebers, Rick P G; Zhuang, Ying-Ping; Sutherland, Ian

2015-12-11

Manufacturing high-value added biotech biopharmaceutical products (e.g. therapeutic proteins) requires quick-to-develop, GMP-compliant, easy-to-scale and cost effective preparatory chromatography technologies. In this work, we describe the construction and testing of a set of 5-mm inner diameter stainless steel toroidal columns for use on commercially available preparatory scale synchronous J-type counter-current chromatography (CCC) machinery. We used a 20.2m long column with an aqueous two-phase system containing 14% (w/w) PEG1000 and 14% (w/w) potassium phosphate at pH 7, and tested a sample loading of 5% column volume and a mobile phase flow rate of 20ml/min. We then satisfactorily demonstrated the potential for a weekly protein separation and preparation throughput of ca. 11g based on a normal weekly routine for separating a pair of model proteins by making five stacked injections on a single portion of stationary phase with no stripping. Compared to our previous 1.6mm bore PTFE toroidal column, the present columns enlarged the nominal column processing throughput by nearly 10. For an ideal model protein injection modality, we observed a scaling up factor of at least 21. The 2 scales of protein separation and purification steps were realized on the same commercial CCC device. Copyright © 2015 Elsevier B.V. All rights reserved.

Adiabatic approximation with exponential accuracy for many-body systems and quantum computation

NASA Astrophysics Data System (ADS)

Lidar, Daniel A.; Rezakhani, Ali T.; Hamma, Alioscia

2009-10-01

We derive a version of the adiabatic theorem that is especially suited for applications in adiabatic quantum computation, where it is reasonable to assume that the adiabatic interpolation between the initial and final Hamiltonians is controllable. Assuming that the Hamiltonian is analytic in a finite strip around the real-time axis, that some number of its time derivatives vanish at the initial and final times, and that the target adiabatic eigenstate is nondegenerate and separated by a gap from the rest of the spectrum, we show that one can obtain an error between the final adiabatic eigenstate and the actual time-evolved state which is exponentially small in the evolution time, where this time itself scales as the square of the norm of the time derivative of the Hamiltonian divided by the cube of the minimal gap.

Amplitude Scaling of Active Separation Control

NASA Technical Reports Server (NTRS)

Stalnov, Oksana; Seifert, Avraham

2010-01-01

Three existing and two new excitation magnitude scaling options for active separation control at Reynolds numbers below one Million. The physical background for the scaling options was discussed and their relevance was evaluated using two different sets of experimental data. For F+ approx. 1, 2D excitation: a) The traditional VR and C(mu) - do not scale the data. b) Only the Re*C(mu) is valid. This conclusion is also limited for positive lift increment.. For F+ > 10, 3D excitation, the Re corrected C(mu), the St corrected velocity ratio and the vorticity flux coefficient, all scale the amplitudes equally well. Therefore, the Reynolds weighted C(mu) is the preferred choice, relevant to both excitation modes. Incidence also considered, using Ue from local Cp.

European Invasion of North American Pinus strobus at Large and Fine Scales: High Genetic Diversity and Fine-Scale Genetic Clustering over Time in the Adventive Range

PubMed Central

Mandák, Bohumil; Hadincová, Věroslava; Mahelka, Václav; Wildová, Radka

2013-01-01

Background North American Pinus strobus is a highly invasive tree species in Central Europe. Using ten polymorphic microsatellite loci we compared various aspects of the large-scale genetic diversity of individuals from 30 sites in the native distribution range with those from 30 sites in the European adventive distribution range. To investigate the ascertained pattern of genetic diversity of this intercontinental comparison further, we surveyed fine-scale genetic diversity patterns and changes over time within four highly invasive populations in the adventive range. Results Our data show that at the large scale the genetic diversity found within the relatively small adventive range in Central Europe, surprisingly, equals the diversity found within the sampled area in the native range, which is about thirty times larger. Bayesian assignment grouped individuals into two genetic clusters separating North American native populations from the European, non-native populations, without any strong genetic structure shown over either range. In the case of the fine scale, our comparison of genetic diversity parameters among the localities and age classes yielded no evidence of genetic diversity increase over time. We found that SGS differed across age classes within the populations under study. Old trees in general completely lacked any SGS, which increased over time and reached its maximum in the sapling stage. Conclusions Based on (1) the absence of difference in genetic diversity between the native and adventive ranges, together with the lack of structure in the native range, and (2) the lack of any evidence of any temporal increase in genetic diversity at four highly invasive populations in the adventive range, we conclude that population amalgamation probably first happened in the native range, prior to introduction. In such case, there would have been no need for multiple introductions from previously isolated populations, but only several introductions from genetically diverse populations. PMID:23874648

Scaling laws and dynamics of bubble coalescence

NASA Astrophysics Data System (ADS)

Anthony, Christopher R.; Kamat, Pritish M.; Thete, Sumeet S.; Munro, James P.; Lister, John R.; Harris, Michael T.; Basaran, Osman A.

2017-08-01

The coalescence of bubbles and drops plays a central role in nature and industry. During coalescence, two bubbles or drops touch and merge into one as the neck connecting them grows from microscopic to macroscopic scales. The hydrodynamic singularity that arises when two bubbles or drops have just touched and the flows that ensue have been studied thoroughly when two drops coalesce in a dynamically passive outer fluid. In this paper, the coalescence of two identical and initially spherical bubbles, which are idealized as voids that are surrounded by an incompressible Newtonian liquid, is analyzed by numerical simulation. This problem has recently been studied (a) experimentally using high-speed imaging and (b) by asymptotic analysis in which the dynamics is analyzed by determining the growth of a hole in the thin liquid sheet separating the two bubbles. In the latter, advantage is taken of the fact that the flow in the thin sheet of nonconstant thickness is governed by a set of one-dimensional, radial extensional flow equations. While these studies agree on the power law scaling of the variation of the minimum neck radius with time, they disagree with respect to the numerical value of the prefactors in the scaling laws. In order to reconcile these differences and also provide insights into the dynamics that are difficult to probe by either of the aforementioned approaches, simulations are used to access both earlier times than has been possible in the experiments and also later times when asymptotic analysis is no longer applicable. Early times and extremely small length scales are attained in the new simulations through the use of a truncated domain approach. Furthermore, it is shown by direct numerical simulations in which the flow within the bubbles is also determined along with the flow exterior to them that idealizing the bubbles as passive voids has virtually no effect on the scaling laws relating minimum neck radius and time.

Making long-term memories in minutes: a spaced learning pattern from memory research in education

PubMed Central

Kelley, Paul; Whatson, Terry

2013-01-01

Memory systems select from environmental stimuli those to encode permanently. Repeated stimuli separated by timed spaces without stimuli can initiate Long-Term Potentiation (LTP) and long-term memory (LTM) encoding. These processes occur in time scales of minutes, and have been demonstrated in many species. This study reports on using a specific timed pattern of three repeated stimuli separated by 10 min spaces drawn from both behavioral and laboratory studies of LTP and LTM encoding. A technique was developed based on this pattern to test whether encoding complex information into LTM in students was possible using the pattern within a very short time scale. In an educational context, stimuli were periods of highly compressed instruction, and spaces were created through 10 min distractor activities. Spaced Learning in this form was used as the only means of instruction for a national curriculum Biology course, and led to very rapid LTM encoding as measured by the high-stakes test for the course. Remarkably, learning at a greatly increased speed and in a pattern that included deliberate distraction produced significantly higher scores than random answers (p < 0.00001) and scores were not significantly different for experimental groups (one hour spaced learning) and control groups (four months teaching). Thus learning per hour of instruction, as measured by the test, was significantly higher for the spaced learning groups (p < 0.00001). In a third condition, spaced learning was used to replace the end of course review for one of two examinations. Results showed significantly higher outcomes for the course using spaced learning (p < 0.0005). The implications of these findings and further areas for research are briefly considered. PMID:24093012

Using Symptom and Interference Questionnaires to Identify Recovery Among Children With Anxiety Disorders

PubMed Central

2016-01-01

Questionnaires are widely used in routine clinical practice to assess treatment outcomes for children with anxiety disorders. This study was conducted to determine whether 2 widely used child and parent report questionnaires of child anxiety symptoms and interference (Spence Child Anxiety Scale [SCAS-C/P] and Child Anxiety Impact Scale [CAIS-C/P]) accurately identify recovery from common child anxiety disorder diagnoses as measured by a ‘gold-standard’ diagnostic interview. Three hundred thirty-seven children (7–12 years, 51% female) and their parents completed the ADIS-IV-C/P diagnostic interview and questionnaire measures (SCAS-C/P and CAIS-C/P) before (Time 1) and after (Time 2) treatment or wait-list. Time 2 parent reported interference (CAIS-P) was found to be a good predictor of absence of any diagnoses (area under the curve [AUC] = .81). In terms of specific diagnoses, Time 2 SCAS-C/P separation anxiety subscale (SCAS-C/P-SA) identified recovery from separation anxiety disorder well (SCAS-C-SA, AUC = .80; SCAS-P-SA, AUC = .82) as did the CAIS-P (AUC = .79). The CAIS-P also successfully identified recovery from social phobia (AUC = .78) and generalized anxiety disorder (AUC = .76). These AUC values were supported by moderate to good sensitivity (.70–.78) and specificity (.70–.73) at the best identified cut-off scores. None of the measures successfully identified recovery from specific phobia. The results suggest that questionnaire measures, particularly the CAIS-P, can be used to identify whether children have recovered from common anxiety disorders, with the exception of specific phobias. Cut-off scores have been identified that can guide the use of routine outcome measures in clinical practice. PMID:27845527

Using symptom and interference questionnaires to identify recovery among children with anxiety disorders.

PubMed

Evans, Rachel; Thirlwall, Kerstin; Cooper, Peter; Creswell, Cathy

2017-07-01

Questionnaires are widely used in routine clinical practice to assess treatment outcomes for children with anxiety disorders. This study was conducted to determine whether 2 widely used child and parent report questionnaires of child anxiety symptoms and interference (Spence Child Anxiety Scale [SCAS-C/P] and Child Anxiety Impact Scale [CAIS-C/P]) accurately identify recovery from common child anxiety disorder diagnoses as measured by a 'gold-standard' diagnostic interview. Three hundred thirty-seven children (7-12 years, 51% female) and their parents completed the ADIS-IV-C/P diagnostic interview and questionnaire measures (SCAS-C/P and CAIS-C/P) before (Time 1) and after (Time 2) treatment or wait-list. Time 2 parent reported interference (CAIS-P) was found to be a good predictor of absence of any diagnoses (area under the curve [AUC] = .81). In terms of specific diagnoses, Time 2 SCAS-C/P separation anxiety subscale (SCAS-C/P-SA) identified recovery from separation anxiety disorder well (SCAS-C-SA, AUC = .80; SCAS-P-SA, AUC = .82) as did the CAIS-P (AUC = .79). The CAIS-P also successfully identified recovery from social phobia (AUC = .78) and generalized anxiety disorder (AUC = .76). These AUC values were supported by moderate to good sensitivity (.70-.78) and specificity (.70-.73) at the best identified cut-off scores. None of the measures successfully identified recovery from specific phobia. The results suggest that questionnaire measures, particularly the CAIS-P, can be used to identify whether children have recovered from common anxiety disorders, with the exception of specific phobias. Cut-off scores have been identified that can guide the use of routine outcome measures in clinical practice. (PsycINFO Database Record (c) 2017 APA, all rights reserved).

Computing aerodynamic sound using advanced statistical turbulence theories

NASA Technical Reports Server (NTRS)

Hecht, A. M.; Teske, M. E.; Bilanin, A. J.

1981-01-01

It is noted that the calculation of turbulence-generated aerodynamic sound requires knowledge of the spatial and temporal variation of Q sub ij (xi sub k, tau), the two-point, two-time turbulent velocity correlations. A technique is presented to obtain an approximate form of these correlations based on closure of the Reynolds stress equations by modeling of higher order terms. The governing equations for Q sub ij are first developed for a general flow. The case of homogeneous, stationary turbulence in a unidirectional constant shear mean flow is then assumed. The required closure form for Q sub ij is selected which is capable of qualitatively reproducing experimentally observed behavior. This form contains separation time dependent scale factors as parameters and depends explicitly on spatial separation. The approximate forms of Q sub ij are used in the differential equations and integral moments are taken over the spatial domain. The velocity correlations are used in the Lighthill theory of aerodynamic sound by assuming normal joint probability.

Evidence for the interaction of large scale magnetic structures in solar flares

NASA Technical Reports Server (NTRS)

Mandrini, C. H.; Demoulin, P.; Henoux, J. C.; Machado, M. E.

1991-01-01

By modeling the observed vertical magnetic field of an active region AR 2372 by the potential field of an ensemble of magnetic dipoles, the likely location of the separatrices, surfaces that separates cells of different field line connectivities, and of the separator which is the intersection of the separatrices, is derived. Four of the five off-band H-alpha kernels of a flare that occurred less than 20 minutes before obtaining the magnetogram are shown to have taken place near or at the separatrices. These H-alpha kernels are connected by field lines that pass near the separator. This indicates that the flare may have resulted from the interaction in the separator region of large scale magnetic structures.

Zoning and exsolution in cumulate alkali feldspars from the eruption (12.9 Ka) of Laacher see volcano (Western Germany) as an indicator of time-scales and dynamics of carbonate-silicate unmixing

NASA Astrophysics Data System (ADS)

Sourav Rout, Smruti; Wörner, Gerhard

2017-04-01

Time-scales extracted from the detailed analysis of chemically zoned minerals provide insights into crystal ages, magma storage and compositional evolution, including mixing and unmixing events. This allows having a better understanding of pre-eruptive history of large and potentially dangerous magma chambers. We present a comprehensive study of chemical diffusion across zoning and exsolution patterns of alkali feldspars in carbonatite-bearing cognate syenites from the 6.3 km3 (D.R.E) phonolitic Laacher See Tephra (LST) eruption 12.9 ka ago. The Laacher See volcano is located in the Quaternary East Eifel volcanic field of the Paleozoic Rhenish Massif in Western Germany and has produced a compositionally variable sequence in a single eruption from a magma chamber that was zoned from mafic phonolite at the base to highly evolved, actively degassing phonolite magma at the top. Diffusion chronometry is applied to major and trace element compositions obtained on alkali feldspars from carbonate-bearing syenitic cumulates. Methods used were laser ablation inductively coupled plasma mass spectrometry (LA ICP-MS) in combination with energy-dispersive and wavelength-dispersive electron microprobe analyses (EDS & WDS-EMPA). The grey scale values extracted from multiple accumulations of back-scattered electron images represent the K/Na ratio owing to the extremely low concentrations of Ba and Sr (<30 ppm). The numerical grey scale profiles and the quantitative compositional profiles are anatomized using three different fitting models in MATLAB®, Mathematica® and Origin® to estimate related time-scales with minimized error for a temperature range of 750 deg C to 800 deg C (on the basis of existing experimental data on phase transition and phase separation). A distinctive uphill diffusive analysis is used specifically for the phase separation in the case of exsolution features (comprising of albite- and orthoclase-rich phases) in sanidines. The error values are aggregates of propagated error through calculations and the uncertainty in temperature values. Trace element compositional data of distinct feldspar compositions that are assumed to have grown before and after silicate-carbonate unmixing are used to estimate partition coefficients between carbonate and silicate melt. The resulting values correlate well with available experimental data from the literature. We will present a genetic model based on the compositional data on feldspar zonation for the process and timing of silicate-carbonate unmixing prior to eruption of the host phonolite magma.

Hybrid LES RANS technique based on a one-equation near-wall model

NASA Astrophysics Data System (ADS)

Breuer, M.; Jaffrézic, B.; Arora, K.

2008-05-01

In order to reduce the high computational effort of wall-resolved large-eddy simulations (LES), the present paper suggests a hybrid LES RANS approach which splits up the simulation into a near-wall RANS part and an outer LES part. Generally, RANS is adequate for attached boundary layers requiring reasonable CPU-time and memory, where LES can also be applied but demands extremely large resources. Contrarily, RANS often fails in flows with massive separation or large-scale vortical structures. Here, LES is without a doubt the best choice. The basic concept of hybrid methods is to combine the advantages of both approaches yielding a prediction method, which, on the one hand, assures reliable results for complex turbulent flows, including large-scale flow phenomena and massive separation, but, on the other hand, consumes much fewer resources than LES, especially for high Reynolds number flows encountered in technical applications. In the present study, a non-zonal hybrid technique is considered (according to the signification retained by the authors concerning the terms zonal and non-zonal), which leads to an approach where the suitable simulation technique is chosen more or less automatically. For this purpose the hybrid approach proposed relies on a unique modeling concept. In the LES mode a subgrid-scale model based on a one-equation model for the subgrid-scale turbulent kinetic energy is applied, where the length scale is defined by the filter width. For the viscosity-affected near-wall RANS mode the one-equation model proposed by Rodi et al. (J Fluids Eng 115:196 205, 1993) is used, which is based on the wall-normal velocity fluctuations as the velocity scale and algebraic relations for the length scales. Although the idea of combined LES RANS methods is not new, a variety of open questions still has to be answered. This includes, in particular, the demand for appropriate coupling techniques between LES and RANS, adaptive control mechanisms, and proper subgrid-scale and RANS models. Here, in addition to the study on the behavior of the suggested hybrid LES RANS approach, special emphasis is put on the investigation of suitable interface criteria and the adjustment of the RANS model. To investigate these issues, two different test cases are considered. Besides the standard plane channel flow test case, the flow over a periodic arrangement of hills is studied in detail. This test case includes a pressure-induced flow separation and subsequent reattachment. In comparison with a wall-resolved LES prediction encouraging results are achieved.

Size exclusion chromatography for semipreparative scale separation of Au38(SR)24 and Au40(SR)24 and larger clusters.

PubMed

Knoppe, Stefan; Boudon, Julien; Dolamic, Igor; Dass, Amala; Bürgi, Thomas

2011-07-01

Size exclusion chromatography (SEC) on a semipreparative scale (10 mg and more) was used to size-select ultrasmall gold nanoclusters (<2 nm) from polydisperse mixtures. In particular, the ubiquitous byproducts of the etching process toward Au(38)(SR)(24) (SR, thiolate) clusters were separated and gained in high monodispersity (based on mass spectrometry). The isolated fractions were characterized by UV-vis spectroscopy, MALDI mass spectrometry, HPLC, and electron microscopy. Most notably, the separation of Au(38)(SR)(24) and Au(40)(SR)(24) clusters is demonstrated.

A Hamiltonian replica exchange method for building protein-protein interfaces applied to a leucine zipper

NASA Astrophysics Data System (ADS)

Cukier, Robert I.

2011-01-01

Leucine zippers consist of alpha helical monomers dimerized (or oligomerized) into alpha superhelical structures known as coiled coils. Forming the correct interface of a dimer from its monomers requires an exploration of configuration space focused on the side chains of one monomer that must interdigitate with sites on the other monomer. The aim of this work is to generate good interfaces in short simulations starting from separated monomers. Methods are developed to accomplish this goal based on an extension of a previously introduced [Su and Cukier, J. Phys. Chem. B 113, 9595, (2009)] Hamiltonian temperature replica exchange method (HTREM), which scales the Hamiltonian in both potential and kinetic energies that was used for the simulation of dimer melting curves. The new method, HTREM_MS (MS designates mean square), focused on interface formation, adds restraints to the Hamiltonians for all but the physical system, which is characterized by the normal molecular dynamics force field at the desired temperature. The restraints in the nonphysical systems serve to prevent the monomers from separating too far, and have the dual aims of enhancing the sampling of close in configurations and breaking unwanted correlations in the restrained systems. The method is applied to a 31-residue truncation of the 33-residue leucine zipper (GCN4-p1) of the yeast transcriptional activator GCN4. The monomers are initially separated by a distance that is beyond their capture length. HTREM simulations show that the monomers oscillate between dimerlike and monomerlike configurations, but do not form a stable interface. HTREM_MS simulations result in the dimer interface being faithfully reconstructed on a 2 ns time scale. A small number of systems (one physical and two restrained with modified potentials and higher effective temperatures) are sufficient. An in silico mutant that should not dimerize because it lacks charged residues that provide electrostatic stabilization of the dimer does not with HTREM_MS, giving confidence in the method. The interface formation time scale is sufficiently short that using HTREM_MS as a screening tool to validate leucine zipper design methods may be feasible.

Kinetic Modeling of Slow Energy Release in Non-Ideal Carbon Rich Explosives

DOE Office of Scientific and Technical Information (OSTI.GOV)

Vitello, P; Fried, L; Glaesemann, K

2006-06-20

We present here the first self-consistent kinetic based model for long time-scale energy release in detonation waves in the non-ideal explosive LX-17. Non-ideal, insensitive carbon rich explosives, such as those based on TATB, are believed to have significant late-time slow release in energy. One proposed source of this energy is diffusion-limited growth of carbon clusters. In this paper we consider the late-time energy release problem in detonation waves using the thermochemical code CHEETAH linked to a multidimensional ALE hydrodynamics model. The linked CHEETAH-ALE model dimensional treats slowly reacting chemical species using kinetic rate laws, with chemical equilibrium assumed for speciesmore » coupled via fast time-scale reactions. In the model presented here we include separate rate equations for the transformation of the un-reacted explosive to product gases and for the growth of a small particulate form of condensed graphite to a large particulate form. The small particulate graphite is assumed to be in chemical equilibrium with the gaseous species allowing for coupling between the instantaneous thermodynamic state and the production of graphite clusters. For the explosive burn rate a pressure dependent rate law was used. Low pressure freezing of the gas species mass fractions was also included to account for regions where the kinetic coupling rates become longer than the hydrodynamic time-scales. The model rate parameters were calibrated using cylinder and rate-stick experimental data. Excellent long time agreement and size effect results were achieved.« less

Neural spike-timing patterns vary with sound shape and periodicity in three auditory cortical fields

PubMed Central

Lee, Christopher M.; Osman, Ahmad F.; Volgushev, Maxim; Escabí, Monty A.

2016-01-01

Mammals perceive a wide range of temporal cues in natural sounds, and the auditory cortex is essential for their detection and discrimination. The rat primary (A1), ventral (VAF), and caudal suprarhinal (cSRAF) auditory cortical fields have separate thalamocortical pathways that may support unique temporal cue sensitivities. To explore this, we record responses of single neurons in the three fields to variations in envelope shape and modulation frequency of periodic noise sequences. Spike rate, relative synchrony, and first-spike latency metrics have previously been used to quantify neural sensitivities to temporal sound cues; however, such metrics do not measure absolute spike timing of sustained responses to sound shape. To address this, in this study we quantify two forms of spike-timing precision, jitter, and reliability. In all three fields, we find that jitter decreases logarithmically with increase in the basis spline (B-spline) cutoff frequency used to shape the sound envelope. In contrast, reliability decreases logarithmically with increase in sound envelope modulation frequency. In A1, jitter and reliability vary independently, whereas in ventral cortical fields, jitter and reliability covary. Jitter time scales increase (A1 < VAF < cSRAF) and modulation frequency upper cutoffs decrease (A1 > VAF > cSRAF) with ventral progression from A1. These results suggest a transition from independent encoding of shape and periodicity sound cues on short time scales in A1 to a joint encoding of these same cues on longer time scales in ventral nonprimary cortices. PMID:26843599

Coupled thermal-fluid-mechanics analysis of twin roll casting of A7075 aluminum alloy

NASA Astrophysics Data System (ADS)

Lee, Yun-Soo; Kim, Hyoung-Wook; Cho, Jae-Hyung; Chun, Se-Hwan

2017-09-01

Better understanding of temperature distribution and roll separation force during twin roll casting of aluminum alloys is critical to successfully fabricate good quality of aluminum strips. Therefore, the simulation techniques are widely applied to understand the twin roll casting process in a comprehensive way and to reduce the experimental time and cost of trial and error. However, most of the conventional approaches are considered thermally coupled flow, or thermally coupled mechanical behaviors. In this study, a fully coupled thermal-fluid-mechanical analysis of twin roll casting of A7075 aluminum strips was carried out using the finite element method. Temperature profile, liquid fraction and metal flow of aluminum strips with different thickness were predicted. Roll separation force and roll temperatures were experimentally obtained from a pilot-scale twin roll caster, and those results were compared with model predictions. Coupling the fluid of the liquid melt to the thermal and mechanical modeling reasonably predicted roll temperature distribution and roll separation force during twin roll casting.

Discrete-vortex simulation of pulsating flow on a turbulent leading-edge separation bubble

NASA Technical Reports Server (NTRS)

Sung, Hyung Jin; Rhim, Jae Wook; Kiya, Masaru

1992-01-01

Studies are made of the turbulent separation bubble in a two-dimensional semi-infinite blunt plate aligned to a uniform free stream with a pulsating component. The discrete-vortex method is applied to simulate this flow situation because this approach is effective for representing the unsteady motions of the turbulent shear layer and the effect of viscosity near the solid surface. The numerical simulation provides reasonable predictions when compared with the experimental results. A particular frequency with a minimum reattachment is related to the drag reduction. The most effective frequency is dependent on the amplified shedding frequency. The turbulent flow structure is scrutinized. This includes the time-mean and fluctuations of the velocity and the surface pressure, together with correlations between the fluctuating components. A comparison between the pulsating flow and the non-pulsating flow at the particular frequency of the minimum reattachment length of the separation bubble suggests that the large-scale vortical structure is associated with the shedding frequency and the flow instabilities.

Separated Carbon Nanotube Macroelectronics for Active Matrix Organic Light-Emitting Diode Displays

NASA Astrophysics Data System (ADS)

Fu, Yue; Zhang, Jialu; Wang, Chuan; Chen, Pochiang; Zhou, Chongwu

2012-02-01

Active matrix organic light-emitting diode (AMOLED) display holds great potential for the next generation visual technologies due to its high light efficiency, flexibility, lightweight, and low-temperature processing. However, suitable thin-film transistors (TFTs) are required to realize the advantages of AMOLED. Pre-separated, semiconducting enriched carbon nanotubes are excellent candidates for this purpose because of their excellent mobility, high percentage of semiconducting nanotubes, and room-temperature processing compatibility. Here we report, for the first time, the demonstration of AMOLED displays driven by separated nanotube thin-film transistors (SN-TFTs) including key technology components such as large-scale high-yield fabrication of devices with superior performance, carbon nanotube film density optimization, bilayer gate dielectric for improved substrate adhesion to the deposited nanotube film, and the demonstration of monolithically integrated AMOLED display elements with 500 pixels driven by 1000 SN-TFTs. Our approach can serve as the critical foundation for future nanotube-based thin-film display electronics.

The long-range correlation and evolution law of centennial-scale temperatures in Northeast China.

PubMed

Zheng, Xiaohui; Lian, Yi; Wang, Qiguang

2018-01-01

This paper applies the detrended fluctuation analysis (DFA) method to investigate the long-range correlation of monthly mean temperatures from three typical measurement stations at Harbin, Changchun, and Shenyang in Northeast China from 1909 to 2014. The results reveal the memory characteristics of the climate system in this region. By comparing the temperatures from different time periods and investigating the variations of its scaling exponents at the three stations during these different time periods, we found that the monthly mean temperature has long-range correlation, which indicates that the temperature in Northeast China has long-term memory and good predictability. The monthly time series of temperatures over the past 106 years also shows good long-range correlation characteristics. These characteristics are also obviously observed in the annual mean temperature time series. Finally, we separated the centennial-length temperature time series into two time periods. These results reveal that the long-range correlations at the Harbin station over these two time periods have large variations, whereas no obvious variations are observed at the other two stations. This indicates that warming affects the regional climate system's predictability differently at different time periods. The research results can provide a quantitative reference point for regional climate predictability assessment and future climate model evaluation.

Characterization of intermittency and statistical properties of high-resolution rainfall observations across a topographic transect in Northwest Mexico

NASA Astrophysics Data System (ADS)

Mascaro, G.; Vivoni, E. R.; Gochis, D. J.; Watts, C. J.; Rodriguez, J. C.

2013-12-01

In northwest Mexico, the statistical properties of rainfall at high temporal resolution (up to 1 min) have been poorly characterized, mainly due to a lack of observations. Under a combined effort of US and Mexican institutions initiated during the North American Monsoon-Soil Moisture Experiment in 2004 (NAME-SMEX04), a network of 8 tipping-bucket rain gauges were installed across a topographic transect in the Sierra Los Locos basin of Sonora, Mexico. The transect spans a distance of ~14 km and an elevation difference of 748 m, thus including valley, mid-elevation and ridge sites where rainfall generation mechanisms in the summer and winter seasons are potentially affected by orography. In this study, we used the data collected during the period of 2007-2010 to characterize the rainfall statistical properties in a wide range of time scales (1 min to ~45 days) and analyzed how these properties change as a function of elevation, the gauge separation distance, and the summer and winter seasons. We found that the total summer (winter) rainfall decreases (increases) with elevation, and that rainfall has a clear diurnal cycle in the summertime, with a peak around 9 pm at all gauges. The correlation structure across the transect indicates that: (i) when times series are aggregated at a resolution greater than 3 hours, the correlation distance is greater than the maximum separation distance (~14 km), while it dramatically decreases for lower time resolutions (e.g., it is ~1.5 km when the resolution is 10 min). Consistent with other semiarid regions, spectral and scale invariance analyses show the presence of different scaling regimes, which are associated to single convective events and larger stratiform systems, with different intermittency properties dependent on the rainfall season. Results of this work are useful for the interpretation of storm generation mechanisms and hydrologic response in the region, as well as for the calibration of high-resolution, stochastic rainfall models used in climate, hydrology, and engineering applications.

Experimental Study of Unsteady Separation in a Laminar Boundary Layer

NASA Astrophysics Data System (ADS)

Bonacci, Andrew; Lang, Amy; Wahidi, Redha; Santos, Leo

2016-11-01

Separation, caused by an adverse pressure gradient, can be a major problem to aircraft. Reversing flow occurs in separated regions and an investigation of how this backflow forms is of interest due to the fact that this could be used as a means of initiating flow control. Specifically, backflow can bristle shark scales which may be linked to a passive, flow actuated separation control mechanism. An experiment was conducted in a water tunnel to replicate separation, with a focus on the reversing flow development near the wall within a laminar boundary layer. Using a rotating cylinder, an adverse pressure gradient was induced creating a separated region over a flat plate. In this experiment the boundary layer grows to sizes great enough that the scale of the flow is increased, making it more measurable to DPIV. In the future, this research can be utilized to better understand flow control mechanisms such as those enabled by shark skin. Funding from Army Research Office and NSF REU site Grant EEC 1358991 is greatly appreciated.