Sample records for transfer properties indication

  1. Information transfer network of global market indices

    NASA Astrophysics Data System (ADS)

    Kim, Yup; Kim, Jinho; Yook, Soon-Hyung

    2015-07-01

    We study the topological properties of the information transfer networks (ITN) of the global financial market indices for six different periods. ITN is a directed weighted network, in which the direction and weight are determined by the transfer entropy between market indices. By applying the threshold method, it is found that ITN undergoes a crossover from the complete graph to a small-world (SW) network. SW regime of ITN for a global crisis is found to be much more enhanced than that for ordinary periods. Furthermore, when ITN is in SW regime, the average clustering coefficient is found to be synchronized with average volatility of markets. We also compare the results with the topological properties of correlation networks.

  2. An Analysis of NASA Technology Transfer. Degree awarded by Pennsylvania State Univ.

    NASA Technical Reports Server (NTRS)

    Bush, Lance B.

    1996-01-01

    A review of previous technology transfer metrics, recommendations, and measurements is presented within the paper. A quantitative and qualitative analysis of NASA's technology transfer efforts is performed. As a relative indicator, NASA's intellectual property performance is benchmarked against a database of over 100 universities. Successful technology transfer (commercial sales, production savings, etc.) cases were tracked backwards through their history to identify the key critical elements that lead to success. Results of this research indicate that although NASA's performance is not measured well by quantitative values (intellectual property stream data), it has a net positive impact on the private sector economy. Policy recommendations are made regarding technology transfer within the context of the documented technology transfer policies since the framing of the Constitution. In the second thrust of this study, researchers at NASA Langley Research Center were surveyed to determine their awareness of, attitude toward, and perception about technology transfer. Results indicate that although researchers believe technology transfer to be a mission of the Agency, they should not be held accountable or responsible for its performance. In addition, the researchers are not well educated about the mechanisms to perform, or policies regarding, technology transfer.

  3. Electron transfer and conformational change in complexes of trimethylamine dehydrogenase and electron transferring flavoprotein.

    PubMed

    Jones, Matthew; Talfournier, Francois; Bobrov, Anton; Grossmann, J Günter; Vekshin, Nikolai; Sutcliffe, Michael J; Scrutton, Nigel S

    2002-03-08

    The trimethylamine dehydrogenase-electron transferring flavoprotein (TMADH.ETF) electron transfer complex has been studied by fluorescence and absorption spectroscopies. These studies indicate that a series of conformational changes occur during the assembly of the TMADH.ETF electron transfer complex and that the kinetics of assembly observed with mutant TMADH (Y442F/L/G) or ETF (alpha R237A) complexes are much slower than are the corresponding rates of electron transfer in these complexes. This suggests that electron transfer does not occur in the thermodynamically most favorable state (which takes too long to form), but that one or more metastable states (which are formed more rapidly) are competent in transferring electrons from TMADH to ETF. Additionally, fluorescence spectroscopy studies of the TMADH.ETF complex indicate that ETF undergoes a stable conformational change (termed structural imprinting) when it interacts transiently with TMADH to form a second, distinct, structural form. The mutant complexes compromise imprinting of ETF, indicating a dependence on the native interactions present in the wild-type complex. The imprinted form of semiquinone ETF exhibits an enhanced rate of electron transfer to the artificial electron acceptor, ferricenium. Overall molecular conformations as probed by small-angle x-ray scattering studies are indistinguishable for imprinted and non-imprinted ETF, suggesting that changes in structure likely involve confined reorganizations within the vicinity of the FAD. Our results indicate a series of conformational events occur during the assembly of the TMADH.ETF electron transfer complex, and that the properties of electron transfer proteins can be affected lastingly by transient interaction with their physiological redox partners. This may have significant implications for our understanding of biological electron transfer reactions in vivo, because ETF encounters TMADH at all times in the cell. Our studies suggest that caution needs to be exercised in extrapolating the properties of in vitro interprotein electron transfer reactions to those occurring in vivo.

  4. The role of heat transfer in strip casting

    NASA Astrophysics Data System (ADS)

    Misra, Paretosh

    The last few years have witnessed rapid developments in the area of strip casting of steel. It involves smaller capital and operating cost, lower greenhouse gas emissions, and an opportunity to create newer products due to a faster solidification rate that leads to a different solidification structure. Thus, ample reasons for interest in the technology exist. At the same time, it needs to be determined if the properties of a strip cast product can match those of a conventional product and if it is possible to produce steel strip at high production rates. The first objective of this work was to characterize the quality, structure, and properties of strip cast material of different chemistries and cast at different machines, to identify the critical operating conditions that would result in the best properties. Determination of the possible range of properties was also aimed, given that the structure of the material is different from the traditional material. The second objective was to investigate ways to increase the rate of heat transfer in strip casting, as that will also enhance the productivity of a strip caster. It was also envisaged to see what effect a high rate of heat transfer will have on the properties of the strip cast material. Results from the strip cast material characterization that was carried out to achieve the first objective indicated that an effective control of heat transfer is very important to get the best properties. Samples that showed best properties had a uniform solidification structure consisting of columnar grains running from the edge of a strip to the centerline, indicating a good control of heat transfer, and their dendrite spacings pointed towards a relatively faster rate of cooling between the rolls. These findings indicated that heat transfer is a core issue in strip casting. The mechanism of increase in the rate of heat transfer in strip casting due to the presence of liquid oxide films at the metal-mold interface was examined. It was discovered that these films originate from the metal itself. A high degree of interdendritic supersaturation can lead to the formation of low melting point oxide phases by the deoxidizing agents in the steel. As the temperature lowers further the film may get ejected out of the metal due to the non-wetting of the metal by the oxide phase. If enough oxide film can be generated then this can result in an almost two-fold increase in the rate of heat transfer during initial solidification---the first 20 milliseconds. The results indicate that if a proper control of these films is ensured then it provides an attractive alternative to increasing the roll diameter as a mechanism of increasing the rate of production of a strip caster. This mechanism will work even with smaller diameter rolls, in fact, perhaps better in that case due to a smaller interface area over which uniformity of heat transfer has to be ensured, thus leveraging its full advantages. If successfully implemented at a plant, this technique can help the strip casting machines to increase their productivity and emerge as a competitive technology to produce steel strip.

  5. 7 CFR 1962.34 - Transfer of chattel security and EO property and assumption of debts.

    Code of Federal Regulations, 2010 CFR

    2010-01-01

    ... Food Security Act of 1985 (Pub. L. 99-198) after December 23, 1985, if a loan is being transferred and... closing. If the applicant does not indicate a choice, the loan will be closed at the rate in effect at the...

  6. Spectroscopic properties and energy transfer of Tm(3+)/Ho(3+)-codoped TeO(2)-WO(3)-ZnO glasses for 1.47mum amplifier.

    PubMed

    Chen, Ganxin; Zhang, Qinyuan; Cheng, Yun; Zhao, Chun; Qian, Qi; Yang, Zhongmin; Jiang, Zhonghong

    2009-05-01

    We report on spectroscopic properties and energy transfer of Tm(3+)/Ho(3+)-codoped tungsten tellurite glasses for 1.47microm amplifier. Fluorescence spectra and the analysis of energy transfer indicate that Ho(3+) is an excellent codopant for 1.47microm emission. Comparing with other tellurite glasses, the radiative lifetime of the (3)H(4) level of Tm(3+) in tungsten tellurite glass is slightly lower, but the spontaneous emission probability, stimulated emission cross-section and the figure of merit for bandwidth are obviously larger. Although the pump efficiency of tungsten tellurite amplifier is approximately 50% less than that of fluoride glass, the figure of merit for bandwidth is approximately three times larger in tungsten tellurite glass than in fluoride glass. The results indicate that Tm(3+)/Ho(3+)-codoped tungsten tellurite glass is attractive for broadband amplifier.

  7. Effect of solvent hydrogen bonding on the photophysical properties of intramolecular charge transfer probe trans-ethyl p-(dimethylamino) cinamate and its derivative

    NASA Astrophysics Data System (ADS)

    Singh, T. Sanjoy; Moyon, N. S.; Mitra, Sivaprasad

    2009-08-01

    Intramolecular charge transfer (ICT) behavior of trans-ethyl p-(dimethylamino) cinamate (EDAC) and 4-(dimethylamino) cinnamic acid (DMACA) were studied by steady state absorption and emission, picosecond time-resolved fluorescence experiments in various pure and mixed solvent systems. The large fluorescence spectral shift in more polar solvents indicates an efficient charge transfer from the donor site to the acceptor moiety in the excited state compared to the ground state. The energy for 0,0 transition ( ν0,0) for EDAC shows very good linear correlation with static solvent dielectric property; however, fluorescence emission maximum, stokes shift and fluorescence quantum yield show significant deviation from linearity in polar protic solvents, indicating a large contribution of solvent hydrogen bonding on the excited state relaxation mechanism. A quantitative estimation of contribution from different solvatochromic parameters was made using linear free energy relationship based on Kamlet-Taft equation.

  8. Scalable transfer of vertical graphene nanosheets for flexible supercapacitor applications

    NASA Astrophysics Data System (ADS)

    Sahoo, Gopinath; Ghosh, Subrata; Polaki, S. R.; Mathews, Tom; Kamruddin, M.

    2017-10-01

    Vertical graphene nanosheets (VGN) are the material of choice for application in next-generation electronic devices. The growing demand for VGN-based flexible devices for the electronics industry brings in restriction on VGN growth temperature. The difficulty associated with the direct growth of VGN on flexible substrates can be overcome by adopting an effective strategy of transferring the well-grown VGN onto arbitrary flexible substrates through a soft chemistry route. In the present study, we report an inexpensive and scalable technique for the polymer-free transfer of VGN onto arbitrary substrates without disrupting its morphology, structure, and properties. After transfer, the morphology, chemical structure, and electrical properties are analyzed by scanning electron microscopy, Raman spectroscopy, x-ray photoelectron spectroscopy, and four-probe resistive methods, respectively. The wetting properties are studied from the water contact angle measurements. The observed results indicate the retention of morphology, surface chemistry, structure, and electronic properties. Furthermore, the storage capacity of the transferred VGN-based binder-free and current collector-free flexible symmetric supercapacitor device is studied. A very low sheet resistance of 670 Ω/□ and excellent supercapacitance of 158 μF cm-2 with 86% retention after 10 000 cycles show the prospect of the damage-free VGN transfer approach for the fabrication of flexible nanoelectronic devices.

  9. Enhanced 3  μm luminescence properties based on effective energy transfer Yb3+ : 2F5/2→Dy3+ : 6H5/2 in fluoaluminate glass modified by TeO2.

    PubMed

    Qi, Fangwei; Huang, Feifei; Wang, Tao; Tian, Ying; Lei, Ruoshan; Ye, Renguang; Zhang, Junjie; Zhang, Long; Xu, Shiqing

    2017-11-01

    Enhanced 3 μm luminescence of Dy 3+ based on the effective process of Yb 3+ :F 5/2 2→Dy 3+ :H 5/2 6 with a higher energy transfer coefficient of 7.36×10 -39   cm 6 /s in fluoaluminate glass modified by TeO 2 was obtained. The energy transfer efficiency from Yb 3+ to Dy 3+ in Dy 3+ /Yb 3+ codoped glass was as high as 80%, indicating the effective energy transfer of Yb 3+ . The higher temperature of the glass transition (T g ) and larger characteristic temperatures (ΔT,K gl ) revealed better thermal properties of the prepared glasses compared with the traditional fluoaluminate glasses, which is of great benefit to fiber drawing. The lower hydroxyl content (15.7 ppm) indicated better fluorescence properties of the glass. It was noted that the longer lifetime of 572 μs and higher emission cross section of 5.22×10 -21   cm 2 along with the bandwidth of 245 nm around 3 μm proved potential applications in mid-IR laser materials of the present glass.

  10. Charge transfer properties of pentacene adsorbed on silver: DFT study

    NASA Astrophysics Data System (ADS)

    N, Rekha T.; Rajkumar, Beulah J. M.

    2015-06-01

    Charge transfer properties of pentacene adsorbed on silver is investigated using DFT methods. Optimized geometry of pentacene after adsorption on silver indicates distortion in hexagonal structure of the ring close to the silver cluster and deviations in co-planarity of carbon atoms due to the variations in bond angles and dihedral angles. Theoretically simulated absorption spectrum has a symmetric surface plasmon resonance peak around 486nm corresponding to the transfer of charge from HOMO-2 to LUMO. Theoretical SERS confirms the process of adsorption, tilted orientation of pentacene on silver surface and the charge transfers reported. Localization of electron density arising from redistribution of electrostatic potential together with a reduced bandgap of pentacene after adsorption on silver suggests its utility in the design of electro active organic semiconducting devices.

  11. Corrosion and Heat Transfer Characteristics of Water Dispersed with Carboxylate Additives and Multi Walled Carbon Nano Tubes

    NASA Astrophysics Data System (ADS)

    Moorthy, Chellapilla V. K. N. S. N.; Srinivas, Vadapalli

    2016-10-01

    This paper summarizes a recent work on anti-corrosive properties and enhanced heat transfer properties of carboxylated water based nanofluids. Water mixed with sebacic acid as carboxylate additive found to be resistant to corrosion and suitable for automotive environment. The carboxylated water is dispersed with very low mass concentration of carbon nano tubes at 0.025, 0.05 and 0.1 %. The stability of nanofluids in terms of zeta potential is found to be good with carboxylated water compared to normal water. The heat transfer performance of nanofluids is carried out on an air cooled heat exchanger similar to an automotive radiator with incoming air velocities across radiator at 5, 10 and 15 m/s. The flow Reynolds number of water is in the range of 2500-6000 indicating developing flow regime. The corrosion resistance of nanofluids is found to be good indicating its suitability to automotive environment. There is a slight increase in viscosity and marginal decrease in the specific heat of nanofluids with addition of carboxylate as well as CNTs. Significant improvement is observed in the thermal conductivity of nanofluids dispersed with CNTs. During heat transfer experimentation, the inside heat transfer coefficient and overall heat transfer coefficient has also improved markedly. It is also found that the velocity of air and flow rate of coolant plays an important role in enhancement of the heat transfer coefficient and overall heat transfer coefficient.

  12. The Case Against Charge Transfer Interactions in Dissolved Organic Matter Photophysics.

    PubMed

    McKay, Garrett; Korak, Julie A; Erickson, Paul R; Latch, Douglas E; McNeill, Kristopher; Rosario-Ortiz, Fernando L

    2018-01-16

    The optical properties of dissolved organic matter influence chemical and biological processes in all aquatic ecosystems. Dissolved organic matter optical properties have been attributed to a charge-transfer model in which donor-acceptor complexes play a primary role. This model was evaluated by measuring the absorbance and fluorescence response of organic matter isolates to changes in solvent temperature, viscosity, and polarity, which affect the position and intensity of spectra for known donor-acceptor complexes of organic molecules. Absorbance and fluorescence spectral shape were largely unaffected by these changes, indicating that the distribution of absorbing and emitting species was unchanged. Overall, these results call into question the wide applicability of the charge-transfer model for explaining organic matter optical properties and suggest that future research should explore other models for dissolved organic matter photophysics.

  13. Effect of sample thickness on the extracted near-infrared bulk optical properties of Bacillus subtilis in liquid culture.

    PubMed

    Dzhongova, Elitsa; Harwood, Colin R; Thennadil, Suresh N

    2011-11-01

    In order to determine the bulk optical properties of a Bacillus subtilis culture during growth phase we investigated the effect of sample thickness on measurements taken with different measurement configurations, namely total diffuse reflectance and total diffuse transmittance. The bulk optical properties were extracted by inverting the measurements using the radiative transfer theory. While the relationship between reflectance and biomass changes with sample thickness and the intensity (absorbance) levels vary significantly for both reflectance and transmittance measurements, the extracted optical properties show consistent behavior in terms of both the relationship with biomass and magnitude. This observation indicates the potential of bulk optical properties for building models that could be more easily transferable compared to those built using raw measurements.

  14. Ultrafast Interlayer Electron Transfer in Incommensurate Transition Metal Dichalcogenide Homobilayers.

    PubMed

    Li, Yuanyuan; Cui, Qiannan; Ceballos, Frank; Lane, Samuel D; Qi, Zeming; Zhao, Hui

    2017-11-08

    Two-dimensional materials, such as graphene, transition metal dichalcogenides, and phosphorene, can be used to construct van der Waals multilayer structures. This approach has shown potentials to produce new materials that combine novel properties of the participating individual layers. One key requirement for effectively harnessing emergent properties of these materials is electronic connection of the involved atomic layers through efficient interlayer charge or energy transfer. Recently, ultrafast charge transfer on a time scale shorter than 100 fs has been observed in several van der Waals bilayer heterostructures formed by two different materials. However, information on the transfer between two atomic layers of the same type is rare. Because these homobilayers are essential elements in constructing multilayer structures with desired optoelectronic properties, efficient interlayer transfer is highly desired. Here we show that electron transfer between two monolayers of MoSe 2 occurs on a picosecond time scale. Even faster transfer was observed in homobilayers of WS 2 and WSe 2 . The samples were fabricated by manually stacking two exfoliated monolayer flakes. By adding a graphene layer as a fast carrier recombination channel for one of the two monolayers, the transfer of the photoexcited carriers from the populated to the drained monolayers was time-resolved by femtosecond transient absorption measurements. The observed efficient interlayer carrier transfer indicates that such homobilayers can be used in van der Waals multilayers to enhance their optical absorption without significantly compromising the interlayer transport performance. Our results also provide valuable information for understanding interlayer charge transfer in heterostructures.

  15. Infants transfer nonobvious properties from pictures to real-world objects.

    PubMed

    Keates, Jeany; Graham, Susan A; Ganea, Patricia A

    2014-09-01

    The current research examined infants' ability to generalize information about the nonobvious properties of objects depicted in picture books to their real-world referents. Infants aged 13, 15, and 18 months (N=135) were shown a series of pictures depicting an adult acting on a novel object to elicit a nonobvious property of that object. Infants were subsequently tested on their extension of the nonobvious property to the real-world object depicted in the book and their generalization of this property to a different color exemplar of the depicted object. Results indicated that, regardless of age, infants expected the real-world objects to have the nonobvious property, as indicated by their attempts to elicit this property with these objects. These findings indicate that early in their second year of life, infants are beginning to make inductive inferences about nonobvious object properties based on information provided in pictures. Copyright © 2014 Elsevier Inc. All rights reserved.

  16. Study of ring influence and electronic response to proton transfer reactions. Reaction electronic flux analysis.

    PubMed

    Herrera, Barbara

    2011-05-01

    In this article, a theoretical study of 1-5 proton transfers is presented. Two model systems which represent 1-5 proton transfer, 3-hidroxy-2-propenimine and salicyldenaniline have been studied as shown in Fig. 1. For this purpose, a DFT/B3LYP/6-311+G**, reaction force and reaction electronic flux analysis is made. The obtained results indicate that both proton transfers exhibit energetic and electronic differences emphasizing the role of the neighbor ring and the impact of conjugation on electronic properties.

  17. Element-specific behaviour and sediment properties modulate transfer and bioaccumulation of trace elements in a highly-contaminated area (Augusta Bay, Central Mediterranean Sea).

    PubMed

    Signa, Geraldina; Mazzola, Antonio; Di Leonardo, Rossella; Vizzini, Salvatrice

    2017-11-01

    High sediment contamination in the coastal area of Priolo Bay, adjacent to the highly-polluted Augusta Harbour, poses serious risks for the benthic communities inhabiting the area. Nevertheless, the transfer of trace elements and consequent bioaccumulation in the biota is an overlooked issue. This study aimed to assess the transfer and bioaccumulation patterns of As, Cd, Ni and Hg to the dominant macroalgae and benthic invertebrates of Priolo Bay. Results revealed different patterns among trace elements (TEs), not driven by sediment contamination but rather by element-specific behaviour coupled with sediment physicochemical properties. Specifically, As accumulated in macroalgae but not in invertebrates, indicating bioavailability of dissolved As only, and a lack of effective trophic transfer. Ni was confined to surface sediment and transfer to biota was not highlighted. Cd and Hg showed the highest concentrations in invertebrates and bioaccumulated especially in filter feeders and carnivores, revealing the importance of suspended particulate and diet as transfer pathways. Total organic carbon (TOC), fine-grained sediments and redox potential were the most important sediment features in shaping the sediment contamination spatial patterns as well as those of TE transfer and bioaccumulation. In particular, As and Cd transfer to macroalgae, and especially Hg bioaccumulation in benthic invertebrates was controlled by sediment properties, resulting in limited transfer and accumulation in the most contaminated stations. Copyright © 2017 Elsevier Ltd. All rights reserved.

  18. The Case Against Charge Transfer Interactions in Dissolved Organic Matter Optical Properties

    NASA Astrophysics Data System (ADS)

    McKay, G.; Korak, J.; Erickson, P. R.; Latch, D. E.; McNeill, K.; Rosario-Ortiz, F.

    2017-12-01

    The optical properties of dissolved organic matter influence chemical and biological processes in all aquatic ecosystems. Organic matter optical properties have been used by scientists and engineers for decades for remote sensing, in situ monitoring, and characterizing laboratory samples to track dissolved organic carbon concentration and character. However, there is still a lack of understanding of the origin of organic matter optical properties, which could conflict with other empirical fluorescence interpretation methods (e.g. PARAFAC). Organic matter optical properties have been attributed to a charge-transfer model in which donor-acceptor complexes play a primary role. This model was evaluated by measuring the absorbance and fluorescence response of organic matter isolates to perturbations in solvent temperature, viscosity, and polarity, which affect the position and intensity of spectra for known donor-acceptor complexes of organic molecules. Absorbance and fluorescence spectral shape were unaffected by these perturbations, indicating that the distribution of absorbing and emitting species was unchanged. These results call into question the wide applicability of the charge-transfer model for explaining organic matter optical properties and suggest that future research should explore other models for organic matter photophysics.

  19. Structural Health Monitoring of a Composite Panel Based on PZT Sensors and a Transfer Impedance Framework.

    PubMed

    Dziendzikowski, Michal; Niedbala, Patryk; Kurnyta, Artur; Kowalczyk, Kamil; Dragan, Krzysztof

    2018-05-11

    One of the ideas for development of Structural Health Monitoring (SHM) systems is based on excitation of elastic waves by a network of PZT piezoelectric transducers integrated with the structure. In the paper, a variant of the so-called Transfer Impedance (TI) approach to SHM is followed. Signal characteristics, called the Damage Indices (DIs), were proposed for data presentation and analysis. The idea underlying the definition of DIs was to maintain most of the information carried by the voltage induced on PZT sensors by elastic waves. In particular, the DIs proposed in the paper should be sensitive to all types of damage which can influence the amplitude or the phase of the voltage induced on the sensor. Properties of the proposed DIs were investigated experimentally using a GFRP composite panel equipped with PZT networks attached to its surface and embedded into its internal structure. Repeatability and stability of DI indications under controlled conditions were verified in tests. Also, some performance indicators for surface-attached and structure-embedded sensors were obtained. The DIs' behavior was dependent mostly on the presence of a simulated damage in the structure. Anisotropy of mechanical properties of the specimen, geometrical properties of PZT network as well as, to some extent, the technology of sensor integration with the structure were irrelevant for damage indication. This property enables the method to be used for damage detection and classification.

  20. Learning multisensory representations for auditory-visual transfer of sequence category knowledge: a probabilistic language of thought approach.

    PubMed

    Yildirim, Ilker; Jacobs, Robert A

    2015-06-01

    If a person is trained to recognize or categorize objects or events using one sensory modality, the person can often recognize or categorize those same (or similar) objects and events via a novel modality. This phenomenon is an instance of cross-modal transfer of knowledge. Here, we study the Multisensory Hypothesis which states that people extract the intrinsic, modality-independent properties of objects and events, and represent these properties in multisensory representations. These representations underlie cross-modal transfer of knowledge. We conducted an experiment evaluating whether people transfer sequence category knowledge across auditory and visual domains. Our experimental data clearly indicate that we do. We also developed a computational model accounting for our experimental results. Consistent with the probabilistic language of thought approach to cognitive modeling, our model formalizes multisensory representations as symbolic "computer programs" and uses Bayesian inference to learn these representations. Because the model demonstrates how the acquisition and use of amodal, multisensory representations can underlie cross-modal transfer of knowledge, and because the model accounts for subjects' experimental performances, our work lends credence to the Multisensory Hypothesis. Overall, our work suggests that people automatically extract and represent objects' and events' intrinsic properties, and use these properties to process and understand the same (and similar) objects and events when they are perceived through novel sensory modalities.

  1. Experimental investigation of forced convective heat transfer performance in nanofluids of Al2O3/water and CuO/water in a serpentine shaped micro channel heat sink

    NASA Astrophysics Data System (ADS)

    Sivakumar, A.; Alagumurthi, N.; Senthilvelan, T.

    2016-07-01

    The microchannels are device used to remove high heat fluxes from smaller area. In this experimental research work the heat transfer performance of nanofluids of Al2O3/water and CuO/water were compared. The important character of such fluids is the enhanced thermal conductivity, in comparison with base fluid without considerable alteration in physical and chemical properties. The effect of forced convective heat transfer coefficient was calculated using serpentine shaped microchannel heat exchanger. Furthermore we calculated the forced convective heat transfer coefficient of the nanofluids using theoretical correlations in order to compare the results with the experimental data. The heat transfer coefficient for different particle concentration and temperature were analysed using forced convection heat transfer using nanofluids. The findings indicate considerable enhancement in convective heat transfer coefficient of the nanofluids as compared to the basefluid. The results also shows that CuO/water nanofluid has increased heat transfer coefficient compared with Al2O3/water and base fluids. Moreover the experimental results indicate there is increased forced convective heat transfer coefficient with the increase in nano particle concentration.

  2. Formation of W(3)A(1) electron-transferring flavoprotein (ETF) hydroquinone in the trimethylamine dehydrogenase x ETF protein complex.

    PubMed

    Jang, M H; Scrutton, N S; Hille, R

    2000-04-28

    The electron-transferring flavoprotein (ETF) from Methylophilus methylotrophus (sp. W(3)A(1)) exhibits unusual oxidation-reduction properties and can only be reduced to the level of the semiquinone under most circumstances (including turnover with its physiological reductant, trimethylamine dehydrogenase (TMADH), or reaction with strong reducing reagents such as sodium dithionite). In the present study, we demonstrate that ETF can be reduced fully to its hydroquinone form both enzymatically and chemically when it is in complex with TMADH. Quantitative titration of the TMADH x ETF protein complex with sodium dithionite shows that a total of five electrons are taken up by the system, indicating that full reduction of ETF occurs within the complex. The results indicate that the oxidation-reduction properties of ETF are perturbed upon binding to TMADH, a conclusion further supported by the observation of a spectral change upon formation of the TMADH x ETF complex that is due to a change in the environment of the FAD of ETF. The results are discussed in the context of ETF undergoing a conformational change during formation of the TMADH x ETF electron transfer complex, which modulates the spectral and oxidation-reduction properties of ETF such that full reduction of the protein can take place.

  3. Theoretical investigation of the charge-transfer properties in different meso-linked zinc porphyrins for highly efficient dye-sensitized solar cells.

    PubMed

    Namuangruk, Supawadee; Sirithip, Kanokkorn; Rattanatwan, Rattanawelee; Keawin, Tinnagon; Kungwan, Nawee; Sudyodsuk, Taweesak; Promarak, Vinich; Surakhot, Yaowarat; Jungsuttiwong, Siriporn

    2014-06-28

    The charge transfer effect of different meso-substituted linkages on porphyrin analogue 1 (A1, B1 and C1) was theoretically investigated using density functional theory (DFT) and time-dependent DFT (TDDFT) calculations. The calculated geometry parameters and natural bond orbital analysis reveal that the twisted conformation between porphyrin macrocycle and meso-substituted linkages leads to blocking of the conjugation of the conjugated backbone, and the frontier molecular orbital plot shows that the intramolecular charge transfer of A1, B1 and C1 hardly takes place. In an attempt to improve the photoinduced intramolecular charge transfer ability of the meso-linked zinc porphyrin sensitizer, a strong electron-withdrawing group (CN) was introduced into the anchoring group of analogue 1 forming analogue 2 (A2, B2 and C2). The density difference plot of A2, B2 and C2 shows that the charge transfer properties dramatically improved. The electron injection process has been performed using TDDFT; the direct charge-transfer transition in the A2-(TiO2)38 interacting system takes place; our results strongly indicated that introducing electron-withdrawing groups into the acceptor part of porphyrin dyes can fine-tune the effective conjugation length of the π-spacer and improve intramolecular charge transfer properties, consequently inducing the electron injection process from the anchoring group of the porphyrin dye to the (TiO2)38 surface which may improve the conversion efficiency of the DSSCs. Our calculated results can provide valuable information and a promising outlook for computation-aided sensitizer design with anticipated good properties in further experimental synthesis.

  4. Exploring the Electrical Conductivity of Cytochrome P450 by Nano-Electrode and Conductive Atomic Force Microscopy

    NASA Astrophysics Data System (ADS)

    Li, Debin; Gu, Jianhua; Chye, Yewhee; Lederman, David; Kabulski, Jarod; Gannett, Peter; Tracy, Timothy

    2006-03-01

    There is a growing interest in measuring the conductivity of electron-transfer proteins. The cytochrome P450 (CP450) enzymes represent an important class of heme-containing enzymes. Immobilizing CP450 enzymes on a surface can be used for studying a single enzyme with respect to electron transfer. The spin state of the heme iron can change upon binding of a substrate. In our experiment, CP450 (diameter ˜ 5 nm) has been bonded to a metal surface. Nano-electrodes (gap < 10 nm) were fabricated by defining a bridge via e-beam lithography and then breaking the junction by electromigration at low temperatures. We have examined the electronic properties of CP450 by itself and after binding CP450 with flurbiprofen. The room temperature I-V conductivity is reminiscent to cyclic voltammetry measurements, indicating the presence of strong ionic transfer. At lower temperatures (100 K) the I-V characteristics indicate electronic transport dominated by tunneling processes. The conductive AFM is an additional method used to examine the enzyme's electronic properties. The results from two methods will be discussed..

  5. Vacuum drying of apples (cv. Golden Delicious): drying characteristics, thermodynamic properties, and mass transfer parameters

    NASA Astrophysics Data System (ADS)

    Nadi, Fatemeh; Tzempelikos, Dimitrios

    2018-01-01

    In this work, apples of cv. Golden Delicious were cut into slices that were 5 and 7 mm thick and then vacuum dried at 50, 60 and 70 °C and pressure of 0.02 bar. The thin layer model drying kinetics was studied, and mass transfer properties, specifically effective moisture diffusivity and convective mass transfer coefficient, were evaluated using the Fick's equation of diffusion. Also, thermodynamic parameters of the process, i.e. enthalpy (ΔH), entropy (ΔS) and Gibbs free energy (ΔG), were determined. Colour properties were evaluated as one of the important indicators of food quality and marketability. Determination of mass transfer parameters and thermodynamic properties of vacuum dried apple slices has not been discussed much in the literature. In conclusion, the Nadi's model fitted best the observed data that represent the drying process. Thermodynamic properties were determined based on the dependence of the drying constant of the Henderson and Pabis model on temperature, and it was concluded that the variation in drying kinetics depends on the energy contribution of the surrounding environment. The enthalpy and entropy diminished, while the Gibbs free energy increased with the increase of the temperature of drying; therefore, it was possible to verify that variation in the diffusion process in the apple during drying depends on energetic contributions of the environment. The obtained results showed that diffusivity increased for 69%, while the mass transfer coefficient increase was even higher, 75%, at the variation of temperature of 20 °C. The increase in the dimensionless Biot number was 20%.

  6. Vacuum drying of apples (cv. Golden Delicious): drying characteristics, thermodynamic properties, and mass transfer parameters

    NASA Astrophysics Data System (ADS)

    Nadi, Fatemeh; Tzempelikos, Dimitrios

    2018-07-01

    In this work, apples of cv. Golden Delicious were cut into slices that were 5 and 7 mm thick and then vacuum dried at 50, 60 and 70 °C and pressure of 0.02 bar. The thin layer model drying kinetics was studied, and mass transfer properties, specifically effective moisture diffusivity and convective mass transfer coefficient, were evaluated using the Fick's equation of diffusion. Also, thermodynamic parameters of the process, i.e. enthalpy ( ΔH), entropy ( ΔS) and Gibbs free energy ( ΔG), were determined. Colour properties were evaluated as one of the important indicators of food quality and marketability. Determination of mass transfer parameters and thermodynamic properties of vacuum dried apple slices has not been discussed much in the literature. In conclusion, the Nadi's model fitted best the observed data that represent the drying process. Thermodynamic properties were determined based on the dependence of the drying constant of the Henderson and Pabis model on temperature, and it was concluded that the variation in drying kinetics depends on the energy contribution of the surrounding environment. The enthalpy and entropy diminished, while the Gibbs free energy increased with the increase of the temperature of drying; therefore, it was possible to verify that variation in the diffusion process in the apple during drying depends on energetic contributions of the environment. The obtained results showed that diffusivity increased for 69%, while the mass transfer coefficient increase was even higher, 75%, at the variation of temperature of 20 °C. The increase in the dimensionless Biot number was 20%.

  7. Three-dimensional aspects of radiative transfer in remote sensing of precipitation: Application to the 1986 COHMEX storm

    NASA Technical Reports Server (NTRS)

    Haferman, J. L.; Krajewski, W. F.; Smith, T. F.

    1994-01-01

    Several multifrequency techniques for passive microwave estimation of precipitation based on the absorption and scattering properties of hydrometers have been proposed in the literature. In the present study, plane-parallel limitations are overcome by using a model based on the discrete-ordinates method to solve the radiative transfer equation in three-dimensional rectangular domains. This effectively accounts for the complexity and variety of radiation problems encountered in the atmosphere. This investigation presents result for plane-parallel and three-dimensional radiative transfer for a precipitating system, discusses differences between these results, and suggests possible explanations for these differences. Microphysical properties were obtained from the Colorado State University Regional Atmospehric Modeling System and represent a hailstorm observed during the 1986 Cooperative Huntsville Meteorological Experiment. These properties are used as input to a three-dimensional radiative transfer model in order to simulate satellite observation of the storm. The model output consists of upwelling brightness temperatures at several of the frequencies on the Special Sensor Microwave/Imager. The radiative transfer model accounts for scattering and emission of atmospheric gases and hydrometers in liquid and ice phases. Brightness temperatures obtained from the three-dimensional model of this investigation indicate that horizontal inhomogeneities give rise to brightness temperature fields that can be quite different from fields obtained using plane-parallel radiative transfer theory. These differences are examined for various resolutions of the satellite sensor field of view. In adddition, the issue of boundary conditions for three-dimensional atmospheric radiative transfer is addressed.

  8. Utilizing in situ Directional Hyperpectral Measurements to Validate Bio-Indicator Simulations for a Corn Crop Canaopy

    USDA-ARS?s Scientific Manuscript database

    Two radiative transfer canopy models, SAIL and the Markov-Chain Canopy Reflectance Model (MRCM), were coupled with in situ leaf optical properties to simulate canopy-level spectral band ratio vegetation indices with the focus on the Photochemical Reflectance Index (PRI) in a cornfield. In situ hyper...

  9. Preparation of polystyrene brush film by radical chain-transfer polymerization and micromechanical properties

    NASA Astrophysics Data System (ADS)

    Zhao, Jing; Chen, Miao; An, Yanqing; Liu, Jianxi; Yan, Fengyuan

    2008-12-01

    A radical chain-transfer polymerization technique has been applied to graft-polymerize brushes of polystyrene (PSt) on single-crystal silicon substrates. 3-Mercapto-propyltrimethoxysilane (MPTMS), as a chain-transfer agent for grafting, was immobilized on the silicon surface by a self-assembling process. The structure and morphology of the graft-functionalized silicon surfaces were characterized by the means of contact-angle measurement, ellipsometric thickness measurement, Fourier transformation infrared (FTIR) spectroscopy, and atomic force microscopy (AFM). The nanotribological and micromechanical properties of the as-prepared polymer brush films were investigated by frictional force microscopy (FFM), force-volume analysis and scratch test. The results indicate that the friction properties of the grafted polymer films can be improved significantly by the treatment of toluene, and the chemically bonded polystyrene film exhibits superior scratch resistance behavior compared with the spin-coated polystyrene film. The resultant polystyrene brush film is expected to develop as a potential lubrication coating for microelectromechanical systems (MEMS).

  10. Non-switching to switching transferring mechanism investigation for Ag/SiO x /p-Si structure with SiO x deposited by HWCVD

    NASA Astrophysics Data System (ADS)

    Liu, Yanhong; Wang, Ruoying; Li, Zhongyue; Wang, Song; Huang, Yang; Peng, Wei

    2018-04-01

    We proposed and fabricated an Ag/SiO x /p-Si sandwich structure, in which amorphous SiO x films were deposited through hot wire chemical vapor deposition (HWCVD) using tetraethylorthosilicate (TEOS) as Si and O precursor. Experimental results indicate that the I–V properties of this structure transfer from non-switching to switching operation as the SiO x deposition temperature increased. The device with SiO x deposited at high deposition temperature exhibits typical bipolar switching properties, which can be potentially used in resistive switching random accessible memory (RRAM). The transferring mechanism from non-switching to switching can be ascribed to the change of structural and electronic properties of SiO x active layer deposited at different temperatures, as evidenced by analyzing FTIR spectrum and fitting its I–V characteristics curves. This work demonstrates a safe and practicable low-temperature device-grade SiO x film deposition technology by conducting HWCVD from TEOS.

  11. Transfer and Transition in the SLA of Aspect: A Bidirectional Study of Learners of English and Japanese

    ERIC Educational Resources Information Center

    Gabriele, Alison

    2009-01-01

    Previous studies have shown that it is particularly difficult for second language (L2) learners to overcome the effects of transfer when they need to unlearn specific aspects of the native language in the absence of explicit input that indicates which properties of the first language (L1) are ruled out by the L2 grammar (Inagaki, 2001;…

  12. Probing Bioluminescence Resonance Energy Transfer in Quantum Rod-Luciferase Nanoconjugates.

    PubMed

    Alam, Rabeka; Karam, Liliana M; Doane, Tennyson L; Coopersmith, Kaitlin; Fontaine, Danielle M; Branchini, Bruce R; Maye, Mathew M

    2016-02-23

    We describe the necessary design criteria to create highly efficient energy transfer conjugates containing luciferase enzymes derived from Photinus pyralis (Ppy) and semiconductor quantum rods (QRs) with rod-in-rod (r/r) microstructure. By fine-tuning the synthetic conditions, CdSe/CdS r/r-QRs were prepared with two different emission colors and three different aspect ratios (l/w) each. These were hybridized with blue, green, and red emitting Ppy, leading to a number of new BRET nanoconjugates. Measurements of the emission BRET ratio (BR) indicate that the resulting energy transfer is highly dependent on QR energy accepting properties, which include absorption, quantum yield, and optical anisotropy, as well as its morphological and topological properties, such as aspect ratio and defect concentration. The highest BR was found using r/r-QRs with lower l/w that were conjugated with red Ppy, which may be activating one of the anisotropic CdSe core energy levels. The role QR surface defects play on Ppy binding, and energy transfer was studied by growth of gold nanoparticles at the defects, which indicated that each QR set has different sites. The Ppy binding at those sites is suggested by the observed BRET red-shift as a function of Ppy-to-QR loading (L), where the lowest L results in highest efficiency and furthest shift.

  13. Structural Health Monitoring of a Composite Panel Based on PZT Sensors and a Transfer Impedance Framework

    PubMed Central

    Dziendzikowski, Michal; Niedbala, Patryk; Kurnyta, Artur; Kowalczyk, Kamil; Dragan, Krzysztof

    2018-01-01

    One of the ideas for development of Structural Health Monitoring (SHM) systems is based on excitation of elastic waves by a network of PZT piezoelectric transducers integrated with the structure. In the paper, a variant of the so-called Transfer Impedance (TI) approach to SHM is followed. Signal characteristics, called the Damage Indices (DIs), were proposed for data presentation and analysis. The idea underlying the definition of DIs was to maintain most of the information carried by the voltage induced on PZT sensors by elastic waves. In particular, the DIs proposed in the paper should be sensitive to all types of damage which can influence the amplitude or the phase of the voltage induced on the sensor. Properties of the proposed DIs were investigated experimentally using a GFRP composite panel equipped with PZT networks attached to its surface and embedded into its internal structure. Repeatability and stability of DI indications under controlled conditions were verified in tests. Also, some performance indicators for surface-attached and structure-embedded sensors were obtained. The DIs’ behavior was dependent mostly on the presence of a simulated damage in the structure. Anisotropy of mechanical properties of the specimen, geometrical properties of PZT network as well as, to some extent, the technology of sensor integration with the structure were irrelevant for damage indication. This property enables the method to be used for damage detection and classification. PMID:29751664

  14. Efficient modulation of optical and electrical properties of X-shaped thermally activated delayed fluorescence emitters by substitution.

    PubMed

    Fan, Jianzhong; Wang, Xin; Lin, Lili; Wang, Chuankui

    2016-08-01

    A series of X-shaped thermally activated delayed fluorescence (TADF) emitters are systematically studied by first-principles calculations. Effects of the cyano group adding to the acceptor unit and the hydroxyl group adding to the donor part on the optical and electrical properties are analyzed. It is found that both kinds of groups can efficiently increase the emission wavelength to realize full-color emission. Although they play different roles in modulating the energy level of frontier orbitals, the S-T energy gap, the reorganization energy and transfer integral for different molecules, they can efficiently increase the charge transfer rate and reduce the difference of electron transfer rate and hole transfer rate. These results indicate that these designed strategies are efficient to achieve balanced charge transfer rates and modulate emission colors. By analyzing the energy matching between the TADF emitters and three kinds of hosts, the emission spectra of the 3,5-bis(N-carbazolyl)benzene (mcp) and the absorption spectra of most TADF emitters have a large overlap, which provides helpful information in application of these TADF molecules.

  15. Effect of counterface material type and its topography on the tribological properties of polyimide composites

    NASA Technical Reports Server (NTRS)

    Fusaro, R. L.

    1985-01-01

    Graphite fiber reinforced polyimide composite pins were slid against seven different counterfaces to determine the effect of material type on the tribological properties of polymer composites. In addition, the effect of sliding a new pin on a pre-established transfer film was investigated. The results indicated that almost a five order of magnitude difference in composite wear rate can occur just by varying the counterface material. An attempt to make all surfaces as smooth as possible was made, but due to differences in material composition this was not possible and a range of surface roughnesses were obtained. The results indicate that the smoother the surface, the lower the composite wear rate; but that small protrusions (not discernible with arithmetic surface roughness measurements) can markedly increase wear rates. A pre-established transfer film improved both run in and steady state wear rates.

  16. Measurements of Heat-Transfer and Friction Coefficients for Helium Flowing in a Tube at Surface Temperatures up to 5900 Deg R

    NASA Technical Reports Server (NTRS)

    Taylor, Maynard F.; Kirchgessner, Thomas A.

    1959-01-01

    Measurements of average heat transfer and friction coefficients and local heat transfer coefficients were made with helium flowing through electrically heated smooth tubes with length-diameter ratios of 60 and 92 for the following range of conditions: Average surface temperature from 1457 to 4533 R, Reynolds numbe r from 3230 to 60,000, heat flux up to 583,200 Btu per hr per ft2 of heat transfer area, and exit Mach numbe r up to 1.0. The results indicate that, in the turbulent range of Reynolds number, good correlation of the local heat transfer coefficients is obtained when the physical properties and density of helium are evaluated at the surface temperature. The average heat transfer coefficients are best correlated on the basis that the coefficient varies with [1 + (L/D))(sup -0,7)] and that the physical properties and density are evaluated at the surface temperature. The average friction coefficients for the tests with no heat addition are in complete agreement with the Karman-Nikuradse line. The average friction coefficients for heat addition are in poor agreement with the accepted line.

  17. Millimeter wave radiative transfer studies for precipitation measurements

    NASA Technical Reports Server (NTRS)

    Vivekanandan, J.; Evans, Frank

    1989-01-01

    Scattering calculations using the discrete dipole approximation and vector radiative transfer calculations were performed to model multiparameter radar return and passive microwave emission for a simple model of a winter storm. The issue of dendrite riming was addressed by computing scattering properties of thin ice disks with varying bulk density. It was shown that C-band multiparameter radar contains information about particle density and the number concentration of the ice particles. The radiative transfer modeling indicated that polarized multifrequency passive microwave emission may be used to infer some properties of ice hydrometers. Detailed radar modeling and vector radiative transfer modeling is in progress to enhance the understanding of simultaneous radar and radiometer measurements, as in the case of the proposed TRMM field program. A one-dimensional cloud model will be used to simulate the storm structure in detail and study the microphysics, such as size and density. Multifrequency polarized radiometer measurements from the SSMI satellite instrument will be analyzed in relation to dual-frequency and dual-polarization radar measurements.

  18. A glutamate is the essential proton transfer gate during the catalytic cycle of the [NiFe] hydrogenase.

    PubMed

    Dementin, Sébastien; Burlat, Bénédicte; De Lacey, Antonio L; Pardo, Alejandro; Adryanczyk-Perrier, Géraldine; Guigliarelli, Bruno; Fernandez, Victor M; Rousset, Marc

    2004-03-12

    Kinetic, EPR, and Fourier transform infrared spectroscopic analysis of Desulfovibrio fructosovorans [NiFe] hydrogenase mutants targeted to Glu-25 indicated that this amino acid participates in proton transfer between the active site and the protein surface during the catalytic cycle. Replacement of that glutamic residue by a glutamine did not modify the spectroscopic properties of the enzyme but cancelled the catalytic activity except the para-H(2)/ortho-H(2) conversion. This mutation impaired the fast proton transfer from the active site that allows high turnover numbers for the oxidation of hydrogen. Replacement of the glutamic residue by the shorter aspartic acid slowed down this proton transfer, causing a significant decrease of H(2) oxidation and hydrogen isotope exchange activities, but did not change the para-H(2)/ortho-H(2) conversion activity. The spectroscopic properties of this mutant were totally different, especially in the reduced state in which a non-photosensitive nickel EPR spectrum was obtained.

  19. Fluorescence properties and energy transfer study of Er3+/Nd3+ doped fluorophosphate glass pumped at 800 and 980 nm for mid-infrared laser applications

    NASA Astrophysics Data System (ADS)

    Tian, Ying; Xu, Rongrong; Hu, Lili; Zhang, Junjie

    2012-04-01

    The fluorescence properties of 2.7 μm emission as well as near infrared emissions in Er3+/Nd3+ doped fluorophosphate glasses are investigated under 800 and 980 nm excitation. The fluorescence dynamics and energy transfer processes between Er and Nd ions in different pumping schemes are reported. Three Judd-Ofelt intensity parameters, energy transfer microparameters, and efficiency have been determined using the Judd-Ofelt and Förster-Dexter theories. The calculated energy transfer efficiency of the Er3+:4I13/2 level to the Nd3+:4I15/2 level is as high as 83.91%. The results indicate that Nd3+ may be an efficient sensitizer for Er3+ to obtain mid-infrared emission and the more suitable pumping scheme of 2.7 μm laser applications for Er3+/Nd3+ doped fluorophosphate glass is 980 nm excitation.

  20. Applications of the similarity relations in radiative transfer to remote sensing implementation and flux simulation

    NASA Astrophysics Data System (ADS)

    Yang, P.; Ding, J.; Tang, G.; King, M. D.; Platnick, S. E.; Meyer, K.; Mlawer, E. J.

    2017-12-01

    Van de Hulst (1974) showed several quasi-invariant quantities in radiative transfer concerning multiple scattering. Recently, we illustrated that the aforesaid quasi-invariant quantities are useful in remote sensing of ice cloud properties from spaceborne radiometric observations (Ding et al. 2017). Specifically, the overall performance of an ice cloud optical property model can be estimated without carrying out detailed retrieval implementation. In this presentation, we will review the radiative transfer similarity relations and some recent results including the study by Ding et al. (2017). Furthermore, we will illustrate an application of the similarity relations to improvement of broadband radiative flux computation. For example, the Rapid Radiative Transfer Model (RRTM, Mlawer et al, 1999) does not consider multiple scattering in the longwave spectral regime (RRTMG-LW) ("G" indicates a version suitable for GCM applications). We show that the similarity relations can be used to effectively improve the accuracy of RRTMG-LW without increasing computational effort.

  1. 41 CFR 102-37.80 - What happens to surplus property that isn't transferred for donation?

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... property that isn't transferred for donation? 102-37.80 Section 102-37.80 Public Contracts and Property... PROPERTY 37-DONATION OF SURPLUS PERSONAL PROPERTY General Provisions Donation Overview § 102-37.80 What happens to surplus property that isn't transferred for donation? Surplus property not transferred for...

  2. 41 CFR 102-37.80 - What happens to surplus property that isn't transferred for donation?

    Code of Federal Regulations, 2013 CFR

    2013-07-01

    ... property that isn't transferred for donation? 102-37.80 Section 102-37.80 Public Contracts and Property... PROPERTY 37-DONATION OF SURPLUS PERSONAL PROPERTY General Provisions Donation Overview § 102-37.80 What happens to surplus property that isn't transferred for donation? Surplus property not transferred for...

  3. 41 CFR 102-37.80 - What happens to surplus property that isn't transferred for donation?

    Code of Federal Regulations, 2012 CFR

    2012-01-01

    ... property that isn't transferred for donation? 102-37.80 Section 102-37.80 Public Contracts and Property... PROPERTY 37-DONATION OF SURPLUS PERSONAL PROPERTY General Provisions Donation Overview § 102-37.80 What happens to surplus property that isn't transferred for donation? Surplus property not transferred for...

  4. 41 CFR 102-37.80 - What happens to surplus property that isn't transferred for donation?

    Code of Federal Regulations, 2014 CFR

    2014-01-01

    ... property that isn't transferred for donation? 102-37.80 Section 102-37.80 Public Contracts and Property... PROPERTY 37-DONATION OF SURPLUS PERSONAL PROPERTY General Provisions Donation Overview § 102-37.80 What happens to surplus property that isn't transferred for donation? Surplus property not transferred for...

  5. 41 CFR 102-37.80 - What happens to surplus property that isn't transferred for donation?

    Code of Federal Regulations, 2011 CFR

    2011-01-01

    ... property that isn't transferred for donation? 102-37.80 Section 102-37.80 Public Contracts and Property... PROPERTY 37-DONATION OF SURPLUS PERSONAL PROPERTY General Provisions Donation Overview § 102-37.80 What happens to surplus property that isn't transferred for donation? Surplus property not transferred for...

  6. 15 CFR 744.22 - Restrictions on exports, reexports and transfers to persons whose property and interests in...

    Code of Federal Regulations, 2014 CFR

    2014-01-01

    ... transfers to persons whose property and interests in property are blocked pursuant to Executive Orders 13310... transfers to persons whose property and interests in property are blocked pursuant to Executive Orders 13310..., reexports, and transfers to persons whose property and interests in property are blocked pursuant to...

  7. 15 CFR 744.22 - Restrictions on exports, reexports and transfers to persons whose property and interests in...

    Code of Federal Regulations, 2012 CFR

    2012-01-01

    ... transfers to persons whose property and interests in property are blocked pursuant to Executive Orders 13310... transfers to persons whose property and interests in property are blocked pursuant to Executive Orders 13310..., reexports, and transfers to persons whose property and interests in property are blocked pursuant to...

  8. 15 CFR 744.22 - Restrictions on exports, reexports and transfers to persons whose property and interests in...

    Code of Federal Regulations, 2013 CFR

    2013-01-01

    ... transfers to persons whose property and interests in property are blocked pursuant to Executive Orders 13310... transfers to persons whose property and interests in property are blocked pursuant to Executive Orders 13310..., reexports, and transfers to persons whose property and interests in property are blocked pursuant to...

  9. 15 CFR 744.22 - Restrictions on exports, reexports and transfers to persons whose property and interests in...

    Code of Federal Regulations, 2011 CFR

    2011-01-01

    ... transfers to persons whose property and interests in property are blocked pursuant to Executive Orders 13310... transfers to persons whose property and interests in property are blocked pursuant to Executive Orders 13310..., reexports, and transfers to persons whose property and interests in property are blocked pursuant to...

  10. 15 CFR 744.22 - Restrictions on exports, reexports and transfers to persons whose property and interests in...

    Code of Federal Regulations, 2010 CFR

    2010-01-01

    ... transfers to persons whose property and interests in property are blocked pursuant to Executive Orders 13310... transfers to persons whose property and interests in property are blocked pursuant to Executive Orders 13310..., reexports, and transfers to persons whose property and interests in property are blocked pursuant to...

  11. 43 CFR 41.120 - Transfers of property.

    Code of Federal Regulations, 2011 CFR

    2011-10-01

    ... Transfers of property. If a recipient sells or otherwise transfers property financed in whole or in part... the Federal share of the fair market value of the property is not upon such sale or transfer properly...

  12. 6 CFR 17.120 - Transfers of property.

    Code of Federal Regulations, 2012 CFR

    2012-01-01

    ....120 Transfers of property. If a recipient sells or otherwise transfers property financed in whole or... activity, and the Federal share of the fair market value of the property is not upon such sale or transfer...

  13. 6 CFR 17.120 - Transfers of property.

    Code of Federal Regulations, 2013 CFR

    2013-01-01

    ....120 Transfers of property. If a recipient sells or otherwise transfers property financed in whole or... activity, and the Federal share of the fair market value of the property is not upon such sale or transfer...

  14. 45 CFR 86.5 - Transfers of property.

    Code of Federal Regulations, 2011 CFR

    2011-10-01

    ... Transfers of property. If a recipient sells or otherwise transfers property financed in whole or in part... the Federal share of the fair market value of the property is not upon such sale or transfer properly...

  15. 43 CFR 41.120 - Transfers of property.

    Code of Federal Regulations, 2012 CFR

    2012-10-01

    ... Transfers of property. If a recipient sells or otherwise transfers property financed in whole or in part... the Federal share of the fair market value of the property is not upon such sale or transfer properly...

  16. 6 CFR 17.120 - Transfers of property.

    Code of Federal Regulations, 2011 CFR

    2011-01-01

    ....120 Transfers of property. If a recipient sells or otherwise transfers property financed in whole or... activity, and the Federal share of the fair market value of the property is not upon such sale or transfer...

  17. 40 CFR 5.120 - Transfers of property.

    Code of Federal Regulations, 2012 CFR

    2012-07-01

    ....120 Transfers of property. If a recipient sells or otherwise transfers property financed in whole or... activity, and the Federal share of the fair market value of the property is not upon such sale or transfer...

  18. 45 CFR 86.5 - Transfers of property.

    Code of Federal Regulations, 2014 CFR

    2014-10-01

    ... Transfers of property. If a recipient sells or otherwise transfers property financed in whole or in part... the Federal share of the fair market value of the property is not upon such sale or transfer properly...

  19. 14 CFR 1253.120 - Transfers of property.

    Code of Federal Regulations, 2011 CFR

    2011-01-01

    ....120 Transfers of property. If a recipient sells or otherwise transfers property financed in whole or... activity, and the Federal share of the fair market value of the property is not upon such sale or transfer...

  20. 43 CFR 41.120 - Transfers of property.

    Code of Federal Regulations, 2014 CFR

    2014-10-01

    ... Transfers of property. If a recipient sells or otherwise transfers property financed in whole or in part... the Federal share of the fair market value of the property is not upon such sale or transfer properly...

  1. 43 CFR 41.120 - Transfers of property.

    Code of Federal Regulations, 2013 CFR

    2013-10-01

    ... Transfers of property. If a recipient sells or otherwise transfers property financed in whole or in part... the Federal share of the fair market value of the property is not upon such sale or transfer properly...

  2. 40 CFR 5.120 - Transfers of property.

    Code of Federal Regulations, 2014 CFR

    2014-07-01

    ....120 Transfers of property. If a recipient sells or otherwise transfers property financed in whole or... activity, and the Federal share of the fair market value of the property is not upon such sale or transfer...

  3. 45 CFR 86.5 - Transfers of property.

    Code of Federal Regulations, 2013 CFR

    2013-10-01

    ... Transfers of property. If a recipient sells or otherwise transfers property financed in whole or in part... the Federal share of the fair market value of the property is not upon such sale or transfer properly...

  4. 6 CFR 17.120 - Transfers of property.

    Code of Federal Regulations, 2014 CFR

    2014-01-01

    ....120 Transfers of property. If a recipient sells or otherwise transfers property financed in whole or... activity, and the Federal share of the fair market value of the property is not upon such sale or transfer...

  5. 40 CFR 5.120 - Transfers of property.

    Code of Federal Regulations, 2011 CFR

    2011-07-01

    ....120 Transfers of property. If a recipient sells or otherwise transfers property financed in whole or... activity, and the Federal share of the fair market value of the property is not upon such sale or transfer...

  6. 15 CFR 8a.120 - Transfers of property.

    Code of Federal Regulations, 2013 CFR

    2013-01-01

    ....120 Transfers of property. If a recipient sells or otherwise transfers property financed in whole or... activity, and the Federal share of the fair market value of the property is not upon such sale or transfer...

  7. 31 CFR 28.120 - Transfers of property.

    Code of Federal Regulations, 2012 CFR

    2012-07-01

    ... § 28.120 Transfers of property. If a recipient sells or otherwise transfers property financed in whole... activity, and the Federal share of the fair market value of the property is not upon such sale or transfer...

  8. 31 CFR 28.120 - Transfers of property.

    Code of Federal Regulations, 2011 CFR

    2011-07-01

    ... § 28.120 Transfers of property. If a recipient sells or otherwise transfers property financed in whole... activity, and the Federal share of the fair market value of the property is not upon such sale or transfer...

  9. 14 CFR 1253.120 - Transfers of property.

    Code of Federal Regulations, 2012 CFR

    2012-01-01

    ... § 1253.120 Transfers of property. If a recipient sells or otherwise transfers property financed in whole... activity, and the Federal share of the fair market value of the property is not upon such sale or transfer...

  10. 31 CFR 28.120 - Transfers of property.

    Code of Federal Regulations, 2014 CFR

    2014-07-01

    ... § 28.120 Transfers of property. If a recipient sells or otherwise transfers property financed in whole... activity, and the Federal share of the fair market value of the property is not upon such sale or transfer...

  11. 15 CFR 8a.120 - Transfers of property.

    Code of Federal Regulations, 2011 CFR

    2011-01-01

    ....120 Transfers of property. If a recipient sells or otherwise transfers property financed in whole or... activity, and the Federal share of the fair market value of the property is not upon such sale or transfer...

  12. 15 CFR 8a.120 - Transfers of property.

    Code of Federal Regulations, 2014 CFR

    2014-01-01

    ....120 Transfers of property. If a recipient sells or otherwise transfers property financed in whole or... activity, and the Federal share of the fair market value of the property is not upon such sale or transfer...

  13. 15 CFR 8a.120 - Transfers of property.

    Code of Federal Regulations, 2012 CFR

    2012-01-01

    ....120 Transfers of property. If a recipient sells or otherwise transfers property financed in whole or... activity, and the Federal share of the fair market value of the property is not upon such sale or transfer...

  14. 14 CFR 1253.120 - Transfers of property.

    Code of Federal Regulations, 2013 CFR

    2013-01-01

    ... § 1253.120 Transfers of property. If a recipient sells or otherwise transfers property financed in whole... activity, and the Federal share of the fair market value of the property is not upon such sale or transfer...

  15. Mechanical properties of water-assembled graphene oxide Langmuir monolayers: Guiding controlled transfer

    DOE PAGES

    Harrison, Katharine L.; Biedermann, Laura B.; Zavadil, Kevin R.

    2015-08-24

    Liquid-phase transfer of graphene oxide (GO) and reduced graphene oxide (RGO) monolayers is investigated from the perspective of the mechanical properties of these films. Monolayers are assembled in a Langmuir–Blodgett trough, and oscillatory barrier measurements are used to characterize the resulting compressive and shear moduli as a function of surface pressure. GO monolayers are shown to develop a significant shear modulus (10–25 mN/m) at relevant surface pressures while RGO monolayers do not. The existence of a shear modulus indicates that GO is acting as a two-dimensional solid driven by strong interaction between the individual GO sheets. The absence of suchmore » behavior in RGO is attributed to the decrease in oxygen moieties on the sheet basal plane, permitting RGO sheets to slide across one another with minimum energy dissipation. Knowledge of this two-dimensional solid behavior is exploited to successfully transfer large-area, continuous GO films to hydrophobic Au substrates. The key to successful transfer is the use of shallow-angle dipping designed to minimize tensile stress present during the insertion or extraction of the substrate. A shallow dip angle on hydrophobic Au does not impart a beneficial effect for RGO monolayers, as these monolayers do not behave as two-dimensional solids and do not remain coherent during the transfer process. As a result, we hypothesize that this observed correlation between monolayer mechanical properties and continuous film transfer success is more universally applicable across substrate hydrophobicities and could be exploited to control the transfer of films composed of two-dimensional materials.« less

  16. 26 CFR 1.615-7 - Effect of transfer of mineral property.

    Code of Federal Regulations, 2013 CFR

    2013-04-01

    ... 26 Internal Revenue 7 2013-04-01 2013-04-01 false Effect of transfer of mineral property. 1.615-7... TAX (CONTINUED) INCOME TAXES (CONTINUED) Natural Resources § 1.615-7 Effect of transfer of mineral property. (a) Transfer before election by transferor. (1) If mineral property is transferred in a...

  17. Anion-cation charge-transfer properties and spectral studies of [M(phen)3][Cd4(SPh)10] (M = Ru, Fe, and Ni).

    PubMed

    Jiang, Jian-Bing; Bian, Guo-Qing; Zhang, Ya-Ping; Luo, Wen; Zhu, Qin-Yu; Dai, Jie

    2011-10-07

    Three anion-cation compounds 1-3 with formula [M(phen)(3)][Cd(4)(SPh)(10)]·Sol (M = Ru(2+), Fe(2+), and Ni(2+), Sol = MeCN and H(2)O) have been synthesized and characterized by single-crystal analysis. Both the cations and anion are well-known ions, but the properties of the co-assembled compounds are interesting. Molecular structures and charge-transfer between the cations and anions in crystal and even in solution are discussed. These compounds are isomorphous and short inter-ion interactions are found in these crystals, such as π···π stacking and C-H···π contacts. Both spectroscopic and theoretical calculated results indicate that there is anion-cation charge-transfer (ACCT) between the Ru-phen complex dye and the Cd-SPh cluster, which plays an important role in their photophysical properties. The intensity of the fluorescent emission of the [Ru(phen)(3)](2+) is enhanced when the cation interacts with the [Cd(4)(SPh)(10)](2-) anion. The mechanism for the enhancement of photoluminescence has been proposed.

  18. Spectroscopic and molecular docking studies on the charge transfer complex of bovine serum albumin with quinone in aqueous medium and its influence on the ligand binding property of the protein.

    PubMed

    Satheshkumar, Angupillai; Elango, Kuppanagounder P

    2014-09-15

    The spectral techniques such as UV-Vis, (1)H NMR and fluorescence and electrochemical experiments have been employed to investigate the interaction between 2-methoxy-3,5,6-trichloro-1,4-benzoquinone (MQ; a water soluble quinone) and bovine serum albumin (BSA) in aqueous medium. The fluorescence of BSA was quenched by MQ via formation of a 1:1 BSA-MQ charge transfer adduct with a formation constant of 3.3×10(8) L mol(-1). Based on the Forster's theory the binding distance between them is calculated as 2.65 nm indicating high probability of binding. For the first time, influence of quinone on the binding property of various types of ligands such as aspirin, ascorbic acid, nicotinimide and sodium stearate has also been investigated. The results indicated that the strong and spontaneous binding existing between BSA and MQ, decreased the intensity of binding of these ligands with BSA. Since Tryptophan (Trp) is the basic residue present in BSA, a comparison between binding property of Trp-MQ adduct with that of BSA-MQ with these ligands has also been attempted. 1H NMR titration study indicated that the Trp forms a charge transfer complex with MQ, which reduces the interaction of Trp with the ligands. Molecular docking study supported the fact that the quinone interacts with the Trp212 unit of the BSA and the free energy change of binding (ΔG) for the BSA-MQ complex was found to be -46 kJ mol(-1), which is comparable to our experimental free energy of binding (-49 kJ mol(-1)) obtained from fluorescence study. Copyright © 2014 Elsevier B.V. All rights reserved.

  19. Spectroscopic and molecular docking studies on the charge transfer complex of bovine serum albumin with quinone in aqueous medium and its influence on the ligand binding property of the protein

    NASA Astrophysics Data System (ADS)

    Satheshkumar, Angupillai; Elango, Kuppanagounder P.

    2014-09-01

    The spectral techniques such as UV-Vis, 1H NMR and fluorescence and electrochemical experiments have been employed to investigate the interaction between 2-methoxy-3,5,6-trichloro-1,4-benzoquinone (MQ; a water soluble quinone) and bovine serum albumin (BSA) in aqueous medium. The fluorescence of BSA was quenched by MQ via formation of a 1:1 BSA-MQ charge transfer adduct with a formation constant of 3.3 × 108 L mol-1. Based on the Forster’s theory the binding distance between them is calculated as 2.65 nm indicating high probability of binding. For the first time, influence of quinone on the binding property of various types of ligands such as aspirin, ascorbic acid, nicotinimide and sodium stearate has also been investigated. The results indicated that the strong and spontaneous binding existing between BSA and MQ, decreased the intensity of binding of these ligands with BSA. Since Tryptophan (Trp) is the basic residue present in BSA, a comparison between binding property of Trp-MQ adduct with that of BSA-MQ with these ligands has also been attempted. 1H NMR titration study indicated that the Trp forms a charge transfer complex with MQ, which reduces the interaction of Trp with the ligands. Molecular docking study supported the fact that the quinone interacts with the Trp212 unit of the BSA and the free energy change of binding (ΔG) for the BSA-MQ complex was found to be -46 kJ mol-1, which is comparable to our experimental free energy of binding (-49 kJ mol-1) obtained from fluorescence study.

  20. Angular momentum transfer in low velocity oblique impacts - Implications for asteroids

    NASA Technical Reports Server (NTRS)

    Yanagisawa, Masahisa; Eluszkiewicz, Janusz; Ahrens, Thomas J.

    1991-01-01

    An experimental study has been conducted for the low-velocity oblique impact efficiency of angular momentum transfer, which is defined as that fraction of incident angular momentum that is transferred to the rotation of a target. The results obtained suggest that more energetic impacts are able to transfer angular momentum more efficiently. In the cases of ricochetted projectiles, the fraction of angular momentum carried off by the ejecta was noted to be less than 30 percent. It is suggested that, if asteroid spin rates are due to mutual noncatastrophic collisions and the taxonomic classes are indicative of bulk properties, the differences between corresponding spin rates will be smaller than expected from a consideration of relative strength and density alone.

  1. Structure and Electronic Spectra of Purine-Methyl Viologen Charge Transfer Complexes

    PubMed Central

    Jalilov, Almaz S.; Patwardhan, Sameer; Singh, Arunoday; Simeon, Tomekia; Sarjeant, Amy A.; Schatz, George C.; Lewis, Frederick D.

    2014-01-01

    The structure and properties of the electron donor-acceptor complexes formed between methyl viologen (MV) and purine nucleosides and nucleotides in water and the solid state have been investigated using a combination of experimental and theoretical methods. Solution studies were performed using UV-vis and 1H NMR spectroscopy. Theoretical calculations were performed within the framework of density functional theory (DFT). Energy decomposition analysis indicates that dispersion and induction (charge-transfer) interactions dominate the total binding energy, whereas electrostatic interactions are largely repulsive. The appearance of charge transfer bands in the absorption spectra of the complexes are well described by time-dependent (TD) DFT and are further explained in terms of the redox properties of purine monomers and solvation effects. Crystal structures are reported for complexes of methyl viologen with the purines 2′-deoxyguanosine 3′-monophosphate GMP (DAD′DAD′ type) and 7-deazaguanosine zG (DAD′ADAD′ type). Comparison of the structures determined in the solid state and by theoretical methods in solution provides valuable insights into the nature of charge-transfer interactions involving purine bases as electron donors. PMID:24294996

  2. 26 CFR 1.1015-4 - Transfers in part a gift and in part a sale.

    Code of Federal Regulations, 2014 CFR

    2014-04-01

    ... property, or (ii) The transferor's adjusted basis for the property at the time of the transfer, and (2) The... greater than the fair market value of the property at the time of such transfer. For determination of gain... examples: Example 1. If A transfers property to his son for $30,000, and such property at the time of the...

  3. 41 CFR 101-4.120 - Transfers of property.

    Code of Federal Regulations, 2011 CFR

    2011-07-01

    ... of property. If a recipient sells or otherwise transfers property financed in whole or in part with... Federal share of the fair market value of the property is not upon such sale or transfer properly...

  4. 41 CFR 101-4.120 - Transfers of property.

    Code of Federal Regulations, 2012 CFR

    2012-07-01

    ... of property. If a recipient sells or otherwise transfers property financed in whole or in part with... Federal share of the fair market value of the property is not upon such sale or transfer properly...

  5. 41 CFR 101-4.120 - Transfers of property.

    Code of Federal Regulations, 2013 CFR

    2013-07-01

    ... of property. If a recipient sells or otherwise transfers property financed in whole or in part with... Federal share of the fair market value of the property is not upon such sale or transfer properly...

  6. 28 CFR 54.120 - Transfers of property.

    Code of Federal Regulations, 2014 CFR

    2014-07-01

    ... property. If a recipient sells or otherwise transfers property financed in whole or in part with Federal... of the fair market value of the property is not upon such sale or transfer properly accounted for to...

  7. 41 CFR 101-4.120 - Transfers of property.

    Code of Federal Regulations, 2014 CFR

    2014-07-01

    ... of property. If a recipient sells or otherwise transfers property financed in whole or in part with... Federal share of the fair market value of the property is not upon such sale or transfer properly...

  8. 28 CFR 54.120 - Transfers of property.

    Code of Federal Regulations, 2012 CFR

    2012-07-01

    ... property. If a recipient sells or otherwise transfers property financed in whole or in part with Federal... of the fair market value of the property is not upon such sale or transfer properly accounted for to...

  9. 28 CFR 54.120 - Transfers of property.

    Code of Federal Regulations, 2011 CFR

    2011-07-01

    ... property. If a recipient sells or otherwise transfers property financed in whole or in part with Federal... of the fair market value of the property is not upon such sale or transfer properly accounted for to...

  10. Radiative transfer modeling applied to sea water constituent determination. [Gulf of Mexico

    NASA Technical Reports Server (NTRS)

    Faller, K. H.

    1979-01-01

    Optical radiation from the sea is influenced by pigments dissolved in the water and contained in discrete organisms suspended in the sea, and by pigmented and unpigmented inorganic and organic particles. The problem of extracting the information concerning these pigments and particulates from the optical properties of the sea is addressed and the properties which determine characteristics of the radiation that a remote sensor will detect and measure are considered. The results of the application of the volume scattering function model to the data collected in the Gulf of Mexico and its environs indicate that the size distribution of the concentrations of particles found in the sea can be predicted from measurements of the volume scattering function. Furthermore, with the volume scattering function model and knowledge of the absorption spectra of dissolved pigments, the radiative transfer model can compute a distribution of particle sizes and indices of refraction and concentration of dissolved pigments that give an upwelling light spectrum that closely matches measurements of that spectrum at sea.

  11. 41 CFR 102-75.85 - Can disposal agencies transfer excess real property to agencies for programs that appear to be...

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... Property Management Regulations System (Continued) FEDERAL MANAGEMENT REGULATION REAL PROPERTY 75-REAL PROPERTY DISPOSAL Utilization of Excess Real Property Guidelines § 102-75.85 Can disposal agencies transfer... transfer excess real property to agencies for programs that appear to be scheduled for substantial...

  12. 31 CFR 560.422 - Termination and acquisition of an interest in blocked property.

    Code of Federal Regulations, 2013 CFR

    2013-07-01

    ... the transfer of property (including any property interest) away from the Government of Iran, an... property interest) is transferred or attempted to be transferred to the Government of Iran, an Iranian... § 560.211, such property shall be deemed to be property in which the Government of Iran, an Iranian...

  13. 31 CFR 560.422 - Termination and acquisition of an interest in blocked property.

    Code of Federal Regulations, 2014 CFR

    2014-07-01

    ... the transfer of property (including any property interest) away from the Government of Iran, an... property interest) is transferred or attempted to be transferred to the Government of Iran, an Iranian... § 560.211, such property shall be deemed to be property in which the Government of Iran, an Iranian...

  14. Experimental and theoretical analysis of nanofluids based on high temperature-heat transfer fluid with enhanced thermal properties

    NASA Astrophysics Data System (ADS)

    Navas, Javier; Sánchez-Coronilla, Antonio; Martín, Elisa I.; Gómez-Villarejo, Roberto; Teruel, Miriam; Gallardo, Juan Jesús; Aguilar, Teresa; Alcántara, Rodrigo; Fernández-Lorenzo, Concha; Martín-Calleja, Joaquín

    2017-04-01

    In this work, nanofluids were prepared using commercial Cu nanoparticles and a commercial high temperature-heat transfer Fluid (eutectic mixture of diphenyl oxide and biphenyl) as the base fluid, which is used in concentrating solar power (CSP) plants. Different properties such as density, viscosity, heat capacity and thermal conductivity were characterized. Nanofluids showed enhanced heat transfer efficiency. In detail, the incorporation of Cu nanoparticles led to an increase of the heat capacity up to 14%. Also, thermal conductivity was increased up to 13%. Finally, the performance of the nanofluids prepared increased up to 11% according to the Dittus-Boelter correlation. On the other hand, equilibrium molecular dynamics simulation was used to model the experimental nanofluid system studied. Thermodynamic properties such as heat capacity and thermal conductivity were calculated and the results were compared with experimental data. The analysis of the radial function distributions (RDFs) and the inspection of the spatial distribution functions (SDFs) indicate the important role that plays the metal-oxygen interaction in the system. Dynamic properties such as the diffusion coefficients of base fluid and nanofluid were computed according to Einstein relation by computing the mean square displacement (MSD). Supplementary online material is available in electronic form at http://www.epjap.org

  15. Research on Intellectual Property Conflicts Identification in Knowledge Transferring among EC Enterprises

    NASA Astrophysics Data System (ADS)

    Su, Shibin

    As the lacks of existing research about intellectual property conflicts management of EC enterprise, the paper analysis the intellectual property conflicts in knowledge transferring among EC enterprises by intellectual property types, then, the paper makes research on intellectual property conflicts identification in knowledge transferring among EC enterprises, and gives relative assumption, meanwhile, the paper makes quantities identification of intellectual property conflicts in knowledge transferring among EC enterprises by evidential theory, finally, the paper gives the further research orientations.

  16. 41 CFR 102-41.165 - May we require reimbursement for the costs incurred in the transfer of unclaimed personal property?

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... reimbursement for the costs incurred in the transfer of unclaimed personal property? 102-41.165 Section 102-41... for the costs incurred in the transfer of unclaimed personal property? Yes, you may require reimbursement from the recipient agency of any direct costs you incur in the transfer of the unclaimed property...

  17. 10 CFR 770.8 - May DOE transfer real property at defense nuclear facilities for economic development at less...

    Code of Federal Regulations, 2014 CFR

    2014-01-01

    ... 10 Energy 4 2014-01-01 2014-01-01 false May DOE transfer real property at defense nuclear... ENERGY TRANSFER OF REAL PROPERTY AT DEFENSE NUCLEAR FACILITIES FOR ECONOMIC DEVELOPMENT § 770.8 May DOE transfer real property at defense nuclear facilities for economic development at less than fair market...

  18. 10 CFR 770.8 - May DOE transfer real property at defense nuclear facilities for economic development at less...

    Code of Federal Regulations, 2013 CFR

    2013-01-01

    ... 10 Energy 4 2013-01-01 2013-01-01 false May DOE transfer real property at defense nuclear... ENERGY TRANSFER OF REAL PROPERTY AT DEFENSE NUCLEAR FACILITIES FOR ECONOMIC DEVELOPMENT § 770.8 May DOE transfer real property at defense nuclear facilities for economic development at less than fair market...

  19. Theoretical study on the photocatalytic properties of graphene oxide with single Au atom adsorption

    NASA Astrophysics Data System (ADS)

    Ju, Lin; Dai, Ying; Wei, Wei; Li, Mengmeng; Jin, Cui; Huang, Baibiao

    2018-03-01

    The photocatalytic properties of graphene oxide (GO) with single Au atom adsorption are studied via the first-principles calculations based on the density functional theory. The present study addresses the origin of enhancement in photocatalytic efficiency of GO derived from single Au atom depositing. Compared with the clean one, the work function of the single Au atom adsorbed GO is lowered due to the charge transfer from Au to GO, indicating enhanced surface activity. The Au atom plays as an electron trapping center and a mediating role in charge transfer from photon excited GO to target species. The photogenerated electron-hole pairs can be separated effectively. For the GO configuration with atomic Au dispersion, there are some states introduced in the band gap, which are predominantly composed of Au 6s states. Through the in-gap state, the photo-generated electron transfer from the valence band of clean GO to the conductive band more easily. In addition, the reduction of the gap in the system is also presented in the current work, which indicates that the single Au atom adsorption improves light absorption for the GO based photocatalyst. These theoretical results are valuable for the future applications of GO materials as photocatalyst for water splitting.

  20. 40 CFR 5.120 - Transfers of property.

    Code of Federal Regulations, 2013 CFR

    2013-07-01

    ... OF SEX IN EDUCATION PROGRAMS OR ACTIVITIES RECEIVING FEDERAL FINANCIAL ASSISTANCE Introduction § 5.120 Transfers of property. If a recipient sells or otherwise transfers property financed in whole or...

  1. 31 CFR 28.120 - Transfers of property.

    Code of Federal Regulations, 2013 CFR

    2013-07-01

    ... BASIS OF SEX IN EDUCATION PROGRAMS OR ACTIVITIES RECEIVING FEDERAL FINANCIAL ASSISTANCE Introduction § 28.120 Transfers of property. If a recipient sells or otherwise transfers property financed in whole...

  2. 45 CFR 86.5 - Transfers of property.

    Code of Federal Regulations, 2012 CFR

    2012-10-01

    ... SEX IN EDUCATION PROGRAMS OR ACTIVITIES RECEIVING FEDERAL FINANCIAL ASSISTANCE Introduction § 86.5 Transfers of property. If a recipient sells or otherwise transfers property financed in whole or in part...

  3. Optical properties of humic substances and CDOM: relation to structure.

    PubMed

    Boyle, Erin S; Guerriero, Nicolas; Thiallet, Anthony; Del Vecchio, Rossana; Blough, Neil V

    2009-04-01

    The spectral dependencies of absorption and fluorescence emission (emission maxima (lamdamax), quantum yields (phi), and mean lifetimes (taum)) were acquired for a commercial lignin, Suwannee River humic (SRHA) and fulvic (SRFA) acids, and a series solid phase extracts (C18) from the Middle Atlantic Bight (MAB extracts). These parameters were compared with the relative average size and total lignin phenol content (TLP). TLP was strongly correlated with absorption at 280 and 355 nm for the MAB extracts, SRHA, and SRFA. The spectral dependence of lamdamax, phi), and taum was very similar for all samples, suggesting a common photophysical and thus structural basis. A strong decrease of phi and taum with increasing average size indicates that intramolecular interactions must be important. When combined with previous work, the results lead us to conclude that the optical properties commonly associated with terrestrial humic substances and chromophoric dissolved organic matter arise primarily from an ensemble of partially oxidized lignins derived from vascular plant sources. Theyfurther provide additional support for an electronic interaction model in which intramolecular energy transfer, excited-state electron transfer, as well as charge transfer likely play important roles in producing the observed optical and photochemical properties of these materials.

  4. Energy transfer characteristics of silicate glass doped with Er3+, Tm3+, and Ho3+ for ˜2 μm emission

    NASA Astrophysics Data System (ADS)

    Li, Ming; Liu, Xueqiang; Guo, Yanyan; Hu, Lili; Zhang, Junjie

    2013-12-01

    A Er3+/Tm3+/Ho3+ tri-doped silicate glass with good thermal stability is prepared by melt-quenching method. Efficient ˜2 μm emission is observed under 808 nm laser excitation. It is found that the 2.0 μm emission of Ho3+ can be enhanced under the excitation at 808 nm by incorporating Er3+ and Tm3+. Based on the measurement of absorption spectra, the Judd-Ofelt intensity parameters, radiation emission probability, and branching ratio are calculated to evaluate the spectroscopic properties simultaneously. The maximum value of emission cross section of Ho3+ is 3.54 × 10-21 cm2 at 2008 nm. Additionally, the phonon assistance and the micro-parameters in the energy transfer process are quantitatively analyzed by using Dexter model. The energy transfer coefficient from Tm3+ to Ho3+ can reach as high as 21.44 × 10-40 cm6/s, respectively. The emission property together with good thermal property indicates that Er3+/Tm3+/Ho3+ tri-doped silicate glass is a potential kind of laser glass for efficient 2 μm laser.

  5. Two-phase nanofluid-based thermal management systems for LED cooling

    NASA Astrophysics Data System (ADS)

    Kiseev, V.; Aminev, D.; Sazhin, O.

    2017-04-01

    This research focuses on two-phase thermal control systems, namely loop thermosyphons (LTS) filled with nanofluids, and their use as LED cooling devices. The behavior of the fluid in the thermosyphons and the mechanisms explaining the possible impact of nanoparticles on thermal properties of the working fluid as well as the processes in the LTS are addressed. Nanoparticle distribution in the nanofluid, methods of preparation of nanofluids and nanofluid degradation processes (aging) are studied. The results are obtained from a set of experiments on thermosyphon characteristics depending on the thermophysical properties of the working fluid, filling volume, geometry and materials of radiators. The impact of nanofluids on heat-transfer process occurring inside thermosyphon is also studied. Results indicate strong influence of nanoparticles on the thermal properties of the thermosyphons, with up to 20% increase of the heat transfer coefficient. Additionally, a method of calculating the hydrodynamic limit of the LTS is proposed, which allows for estimation of the maximum heat flux that can be transferred by means of the LTS. Possible ways for further improvement of the model are proposed. The nanofluids are shown to be effective means of enhancing two-phase systems of thermal management.

  6. Efficient natural-convective heat transfer properties of carbon nanotube sheets and their roles on the thermal dissipation.

    PubMed

    Jiang, Shaohui; Liu, Changhong; Fan, Shoushan

    2014-03-12

    In this work, we report our studies related to the natural-convective heat transfer properties of carbon nanotube (CNT) sheets. We theoretically derived the formulas and experimentally measured the natural-convective heat transfer coefficients (H) via electrical heating method. The H values of the CNT sheets containing different layers (1, 2, 3, and 1000) were measured. We found that the single-layer CNT sheet had a unique ability on heat dissipation because of its great H. The H value of the single-layer CNT sheet was 69 W/(m(2) K) which was about twice of aluminum foil in the same environment. As the layers increased, the H values dropped quickly to the same with that of aluminum foil. We also discussed its roles on thermal dissipation, and the results indicated that the convection was a significant way of dissipation when the CNT sheets were applied on macroscales. These results may give us a new guideline to design devices based on the CNT sheets.

  7. Absorption degree analysis on biogas separation with ionic liquid systems.

    PubMed

    Zhang, Xin; Zhang, Suojiang; Bao, Di; Huang, Ying; Zhang, Xiangping

    2015-01-01

    For biogas upgrading, present work mainly focuses on either thermodynamics or mass transfer properties. A systematical study on these two aspects is important for developing a new biogas separation process. In this work, a new criterion "absorption degree", which combines both thermodynamics and mass transfer properties, was proposed for the first time to comprehensively evaluate the absorption performance. Henry's law constants of CO2 and CH4 in ionic liquids-polyethylene glycol dimethyl ethers mixtures were investigated. The liquid-side mass transfer coefficients (kL) were determined. The results indicate that IL-NHD mixtures exhibit not only a high CO2/CH4 selectivity, but also a fast kL for CO2 absorption. The [bmim][NO3]+NHD mixtures present a high absorption degree value for CO2 but a low value for CH4. For presenting a highest relative absorption degree value, the 50wt% [bmim][NO3]+50wt% NHD mixture is recommended for biogas upgrading. Copyright © 2014 Elsevier Ltd. All rights reserved.

  8. 45 CFR 618.120 - Transfers of property.

    Code of Federal Regulations, 2014 CFR

    2014-10-01

    ... NONDISCRIMINATION ON THE BASIS OF SEX IN EDUCATION PROGRAMS OR ACTIVITIES RECEIVING FEDERAL FINANCIAL ASSISTANCE Introduction § 618.120 Transfers of property. If a recipient sells or otherwise transfers property financed in...

  9. 13 CFR 113.120 - Transfers of property.

    Code of Federal Regulations, 2012 CFR

    2012-01-01

    ... Nondiscrimination on the Basis of Sex in Education Programs or Activities Receiving Federal Financial Assistance Introduction § 113.120 Transfers of property. If a recipient sells or otherwise transfers property financed in...

  10. 34 CFR 106.5 - Transfers of property.

    Code of Federal Regulations, 2012 CFR

    2012-07-01

    ... NONDISCRIMINATION ON THE BASIS OF SEX IN EDUCATION PROGRAMS OR ACTIVITIES RECEIVING FEDERAL FINANCIAL ASSISTANCE Introduction § 106.5 Transfers of property. If a recipient sells or otherwise transfers property financed in...

  11. The feasibility of coherent energy transfer in microtubules.

    PubMed

    Craddock, Travis John Adrian; Friesen, Douglas; Mane, Jonathan; Hameroff, Stuart; Tuszynski, Jack A

    2014-11-06

    It was once purported that biological systems were far too 'warm and wet' to support quantum phenomena mainly owing to thermal effects disrupting quantum coherence. However, recent experimental results and theoretical analyses have shown that thermal energy may assist, rather than disrupt, quantum coherent transport, especially in the 'dry' hydrophobic interiors of biomolecules. Specifically, evidence has been accumulating for the necessary involvement of quantum coherent energy transfer between uniquely arranged chromophores in light harvesting photosynthetic complexes. The 'tubulin' subunit proteins, which comprise microtubules, also possess a distinct architecture of chromophores, namely aromatic amino acids, including tryptophan. The geometry and dipolar properties of these aromatics are similar to those found in photosynthetic units indicating that tubulin may support coherent energy transfer. Tubulin aggregated into microtubule geometric lattices may support such energy transfer, which could be important for biological signalling and communication essential to living processes. Here, we perform a computational investigation of energy transfer between chromophoric amino acids in tubulin via dipole excitations coupled to the surrounding thermal environment. We present the spatial structure and energetic properties of the tryptophan residues in the microtubule constituent protein tubulin. Plausibility arguments for the conditions favouring a quantum mechanism of signal propagation along a microtubule are provided. Overall, we find that coherent energy transfer in tubulin and microtubules is biologically feasible. © 2014 The Author(s) Published by the Royal Society. All rights reserved.

  12. 41 CFR 102-75.85 - Can disposal agencies transfer excess real property to agencies for programs that appear to be...

    Code of Federal Regulations, 2011 CFR

    2011-01-01

    ... further Federal utilization or disposal as surplus property at an agreed upon time when the transfer is... PROPERTY DISPOSAL Utilization of Excess Real Property Guidelines § 102-75.85 Can disposal agencies transfer...

  13. 29 CFR 36.120 - Transfers of property.

    Code of Federal Regulations, 2014 CFR

    2014-07-01

    ... otherwise transfers property financed in whole or in part with Federal financial assistance to a transferee... property is not upon such sale or transfer properly accounted for to the Federal Government, both the...

  14. 44 CFR 19.120 - Transfers of property.

    Code of Federal Regulations, 2014 CFR

    2014-10-01

    ... otherwise transfers property financed in whole or in part with Federal financial assistance to a transferee... property is not upon such sale or transfer properly accounted for to the Federal Government, both the...

  15. 36 CFR § 1211.120 - Transfers of property.

    Code of Federal Regulations, 2013 CFR

    2013-07-01

    ... otherwise transfers property financed in whole or in part with Federal financial assistance to a transferee... property is not upon such sale or transfer properly accounted for to the Federal Government, both the...

  16. 44 CFR 19.120 - Transfers of property.

    Code of Federal Regulations, 2012 CFR

    2012-10-01

    ... otherwise transfers property financed in whole or in part with Federal financial assistance to a transferee... property is not upon such sale or transfer properly accounted for to the Federal Government, both the...

  17. 10 CFR 1042.120 - Transfers of property.

    Code of Federal Regulations, 2013 CFR

    2013-01-01

    ... recipient sells or otherwise transfers property financed in whole or in part with Federal financial... market value of the property is not upon such sale or transfer properly accounted for to the Federal...

  18. 44 CFR 19.120 - Transfers of property.

    Code of Federal Regulations, 2011 CFR

    2011-10-01

    ... otherwise transfers property financed in whole or in part with Federal financial assistance to a transferee... property is not upon such sale or transfer properly accounted for to the Federal Government, both the...

  19. 44 CFR 19.120 - Transfers of property.

    Code of Federal Regulations, 2013 CFR

    2013-10-01

    ... otherwise transfers property financed in whole or in part with Federal financial assistance to a transferee... property is not upon such sale or transfer properly accounted for to the Federal Government, both the...

  20. 10 CFR 1042.120 - Transfers of property.

    Code of Federal Regulations, 2014 CFR

    2014-01-01

    ... recipient sells or otherwise transfers property financed in whole or in part with Federal financial... market value of the property is not upon such sale or transfer properly accounted for to the Federal...

  1. 41 CFR 102-75.620 - What happens if property that was transferred to meet a self-help housing or housing assistance...

    Code of Federal Regulations, 2011 CFR

    2011-01-01

    ... that was transferred to meet a self-help housing or housing assistance use requirement is found to be... PROPERTY 75-REAL PROPERTY DISPOSAL Surplus Real Property Disposal Property for Providing Self-Help Housing Or Housing Assistance § 102-75.620 What happens if property that was transferred to meet a self-help...

  2. Microstructure and properties of single crystal BaTiO3 thin films synthesized by ion implantation-induced layer transfer

    NASA Astrophysics Data System (ADS)

    Park, Young-Bae; Ruglovsky, Jennifer L.; Atwater, Harry A.

    2004-07-01

    Single crystal BaTiO3 thin films have been transferred onto Pt-coated and Si3N4-coated substrates by the ion implantation-induced layer transfer method using H + and He+ ion coimplantation and subsequent annealing. The transferred BaTiO3 films are single crystalline with root mean square roughness of 17nm. Polarized optical and piezoresponse force microscopy (PFM) indicate that the BaTiO3 film domain structure closely resembles that of bulk tetragonal BaTiO3 and atomic force microscopy shows a 90° a -c domain structure with a tetragonal angle of 0.5°-0.6°. Micro-Raman spectroscopy indicates that the local mode intensity is degraded in implanted BaTiO3 but recovers during anneals above the Curie temperature. The piezoelectric coefficient, d33, is estimated from PFM to be 80-100pm/V and the coercive electric field (Ec) is 12-20kV/cm, comparable to those in single crystal BaTiO3.

  3. Comparison of discrete ordinate and Monte Carlo simulations of polarized radiative transfer in two coupled slabs with different refractive indices.

    PubMed

    Cohen, D; Stamnes, S; Tanikawa, T; Sommersten, E R; Stamnes, J J; Lotsberg, J K; Stamnes, K

    2013-04-22

    A comparison is presented of two different methods for polarized radiative transfer in coupled media consisting of two adjacent slabs with different refractive indices, each slab being a stratified medium with no change in optical properties except in the direction of stratification. One of the methods is based on solving the integro-differential radiative transfer equation for the two coupled slabs using the discrete ordinate approximation. The other method is based on probabilistic and statistical concepts and simulates the propagation of polarized light using the Monte Carlo approach. The emphasis is on non-Rayleigh scattering for particles in the Mie regime. Comparisons with benchmark results available for a slab with constant refractive index show that both methods reproduce these benchmark results when the refractive index is set to be the same in the two slabs. Computed results for test cases with coupling (different refractive indices in the two slabs) show that the two methods produce essentially identical results for identical input in terms of absorption and scattering coefficients and scattering phase matrices.

  4. 22 CFR 229.120 - Transfers of property.

    Code of Federal Regulations, 2012 CFR

    2012-04-01

    .... If a recipient sells or otherwise transfers property financed in whole or in part with Federal... of the fair market value of the property is not upon such sale or transfer properly accounted for to...

  5. 22 CFR 146.120 - Transfers of property.

    Code of Federal Regulations, 2012 CFR

    2012-04-01

    .... If a recipient sells or otherwise transfers property financed in whole or in part with Federal... of the fair market value of the property is not upon such sale or transfer properly accounted for to...

  6. 22 CFR 229.120 - Transfers of property.

    Code of Federal Regulations, 2014 CFR

    2014-04-01

    .... If a recipient sells or otherwise transfers property financed in whole or in part with Federal... of the fair market value of the property is not upon such sale or transfer properly accounted for to...

  7. 49 CFR 25.120 - Transfers of property.

    Code of Federal Regulations, 2012 CFR

    2012-10-01

    .... If a recipient sells or otherwise transfers property financed in whole or in part with Federal... of the fair market value of the property is not upon such sale or transfer properly accounted for to...

  8. 49 CFR 25.120 - Transfers of property.

    Code of Federal Regulations, 2011 CFR

    2011-10-01

    .... If a recipient sells or otherwise transfers property financed in whole or in part with Federal... of the fair market value of the property is not upon such sale or transfer properly accounted for to...

  9. 22 CFR 229.120 - Transfers of property.

    Code of Federal Regulations, 2013 CFR

    2013-04-01

    .... If a recipient sells or otherwise transfers property financed in whole or in part with Federal... of the fair market value of the property is not upon such sale or transfer properly accounted for to...

  10. 22 CFR 146.120 - Transfers of property.

    Code of Federal Regulations, 2013 CFR

    2013-04-01

    .... If a recipient sells or otherwise transfers property financed in whole or in part with Federal... of the fair market value of the property is not upon such sale or transfer properly accounted for to...

  11. 22 CFR 146.120 - Transfers of property.

    Code of Federal Regulations, 2011 CFR

    2011-04-01

    .... If a recipient sells or otherwise transfers property financed in whole or in part with Federal... of the fair market value of the property is not upon such sale or transfer properly accounted for to...

  12. 22 CFR 229.120 - Transfers of property.

    Code of Federal Regulations, 2011 CFR

    2011-04-01

    .... If a recipient sells or otherwise transfers property financed in whole or in part with Federal... of the fair market value of the property is not upon such sale or transfer properly accounted for to...

  13. 49 CFR 25.120 - Transfers of property.

    Code of Federal Regulations, 2014 CFR

    2014-10-01

    .... If a recipient sells or otherwise transfers property financed in whole or in part with Federal... of the fair market value of the property is not upon such sale or transfer properly accounted for to...

  14. 22 CFR 146.120 - Transfers of property.

    Code of Federal Regulations, 2014 CFR

    2014-04-01

    .... If a recipient sells or otherwise transfers property financed in whole or in part with Federal... of the fair market value of the property is not upon such sale or transfer properly accounted for to...

  15. 49 CFR 25.120 - Transfers of property.

    Code of Federal Regulations, 2013 CFR

    2013-10-01

    .... If a recipient sells or otherwise transfers property financed in whole or in part with Federal... of the fair market value of the property is not upon such sale or transfer properly accounted for to...

  16. 28 CFR 54.120 - Transfers of property.

    Code of Federal Regulations, 2013 CFR

    2013-07-01

    ... 28 Judicial Administration 2 2013-07-01 2013-07-01 false Transfers of property. 54.120 Section 54.120 Judicial Administration DEPARTMENT OF JUSTICE (CONTINUED) NONDISCRIMINATION ON THE BASIS OF SEX IN... property. If a recipient sells or otherwise transfers property financed in whole or in part with Federal...

  17. 26 CFR 1.707-6 - Disguised sales of property by partnership to partner; general rules.

    Code of Federal Regulations, 2013 CFR

    2013-04-01

    ... transferred property to the partner; by (B) The excess of the fair market value of the property at the time it... property X to A. At the time of the transfer, property X has a fair market value of $1,000,000. One year... similar to those provided in § 1.707-3 apply in determining whether a transfer of property by a...

  18. 26 CFR 1.707-6 - Disguised sales of property by partnership to partner; general rules.

    Code of Federal Regulations, 2012 CFR

    2012-04-01

    ... transferred property to the partner; by (B) The excess of the fair market value of the property at the time it... property X to A. At the time of the transfer, property X has a fair market value of $1,000,000. One year... similar to those provided in § 1.707-3 apply in determining whether a transfer of property by a...

  19. 41 CFR 102-75.610 - Who is responsible for enforcing compliance with the terms and conditions of the transfer of the...

    Code of Federal Regulations, 2011 CFR

    2011-01-01

    ... enforcing compliance with the terms and conditions of the transfer of the property for self-help housing or... PROPERTY DISPOSAL Surplus Real Property Disposal Property for Providing Self-Help Housing Or Housing... transfer of the property for self-help housing or housing assistance use? HUD is responsible for enforcing...

  20. 41 CFR 102-37.65 - What happens to surplus property that has been approved for transfer when the prospective...

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... property that has been approved for transfer when the prospective transferee decides it cannot use the property and declines to pick it up? 102-37.65 Section 102-37.65 Public Contracts and Property Management... happens to surplus property that has been approved for transfer when the prospective transferee decides it...

  1. White long-lasting phosphorescence generation in a CaAl2Si2O8 : Eu2+, Mn2+, Dy3+ system through persistent energy transfer

    NASA Astrophysics Data System (ADS)

    Zhang, Jinsu; Chen, Baojiu; Sun, Jiashi; Li, Xiangping; Cheng, Lihong; Zhong, Haiyang

    2012-08-01

    Based on the persistent energy transfer principle, Mn2+ was introduced into a CaAl2Si2O8 : Eu2+/Dy3+ phosphor to achieve white long-lasting emissions. Eu2+, Mn2+ and Dy3+ tri-doped CaAl2Si2O8 phosphors with various Mn2+ concentrations were prepared via a solid-state reaction, and the crystal structure of the phosphors was identified by the x-ray diffraction technique. The luminescent properties of the Eu2+, Mn2+ and Dy3+ tri-doped CaAl2Si2O8 phosphors were studied. The energy transfer behaviour from Eu2+ to Mn2+ was analysed within the framework of Dexter theory. The physical mechanism of energy transfer was assigned to the electric dipole-quadrupole interaction. It was also demonstrated that the colour coordinates of the phosphors can be tuned from the blue region to the white region in the colour space. Furthermore, the afterglow decay and thermoluminescence curves were measured, indicating excellent phosphorescence properties of the current phosphors.

  2. Drying of Durum Wheat Pasta and Enriched Pasta: A Review of Modeling Approaches.

    PubMed

    Mercier, Samuel; Mondor, Martin; Moresoli, Christine; Villeneuve, Sébastien; Marcos, Bernard

    2016-05-18

    Models on drying of durum wheat pasta and enriched pasta were reviewed to identify avenues for improvement according to consumer needs, product formulation and processing conditions. This review first summarized the fundamental phenomena of pasta drying, mass transfer, heat transfer, momentum, chemical changes, shrinkage and crack formation. The basic equations of the current models were then presented, along with methods for the estimation of pasta transport and thermodynamic properties. The experimental validation of these models was also presented and highlighted the need for further model validation for drying at high temperatures (>-100°C) and for more accurate estimation of the pasta diffusion and mass transfer coefficients. This review indicates the need for the development of mechanistic models to improve our understanding of the mass and heat transfer mechanisms involved in pasta drying, and to consider the local changes in pasta transport properties and relaxation time for more accurate description of the moisture transport near glass transition conditions. The ability of current models to describe dried pasta quality according to the consumers expectations or to predict the impact of incorporating ingredients high in nutritional value on the drying of these enriched pasta was also discussed.

  3. Numerical evaluation of laminar heat transfer enhancement in nanofluid flow in coiled square tubes

    PubMed Central

    2011-01-01

    Convective heat transfer can be enhanced by changing flow geometry and/or by enhancing thermal conductivity of the fluid. This study proposes simultaneous passive heat transfer enhancement by combining the geometry effect utilizing nanofluids inflow in coils. The two nanofluid suspensions examined in this study are: water-Al2O3 and water-CuO. The flow behavior and heat transfer performance of these nanofluid suspensions in various configurations of coiled square tubes, e.g., conical spiral, in-plane spiral, and helical spiral, are investigated and compared with those for water flowing in a straight tube. Laminar flow of a Newtonian nanofluid in coils made of square cross section tubes is simulated using computational fluid dynamics (CFD)approach, where the nanofluid properties are treated as functions of particle volumetric concentration and temperature. The results indicate that addition of small amounts of nanoparticles up to 1% improves significantly the heat transfer performance; however, further addition tends to deteriorate heat transfer performance. PMID:21711901

  4. Spectroscopic properties and energy transfer parameters of Er3+-doped fluorozirconate and oxyfluoroaluminate glasses.

    PubMed

    Huang, Feifei; Liu, Xueqiang; Hu, Lili; Chen, Danping

    2014-05-23

    Er3+-doped fluorozirconate (ZrF4-BaF2-YF3-AlF3) and oxyfluoroaluminate glasses are successfully prepared here. These glasses exhibit significant superiority compared with traditional fluorozirconate glass (ZrF4-BaF2-LaF3-AlF3-NaF) because of their higher temperature of glass transition and better resistance to water corrosion. Judd-Ofelt (J-O) intensity parameters are evaluated and used to compute the radiative properties based on the VIS-NIR absorption spectra. Broad emission bands located at 1535 and 2708 nm are observed, and large calculated emission sections are obtained. The intensity of 2708 nm emission closely relates to the phonon energy of host glass. A lower phonon energy leads to a more intensive 2708 nm emission. The energy transfer processes of Er3+ ions are discussed and lifetime of Er3+:4I13/2 is measured. It is the first time to observe that a longer lifetime of the 4I13/2 level leads to a less intensive 1535 nm emission, because the lifetime is long enough to generate excited state absorption (ESA) and energy transfer (ET) processes. These results indicate that the novel glasses possess better chemical and thermal properties as well as excellent optical properties compared with ZBLAN glass. These Er3+-doped ZBYA and oxyfluoroaluminate glasses have potential applications as laser materials.

  5. 31 CFR 570.403 - Termination and acquisition of an interest in blocked property.

    Code of Federal Regulations, 2012 CFR

    2012-07-01

    ... transfer of property (including any property interest) away from the Government of Libya or a person, such... transferred or attempted to be transferred to the Government of Libya or any other person whose property and... which the Government of Libya or that person has an interest and therefore blocked. ...

  6. 31 CFR 570.403 - Termination and acquisition of an interest in blocked property.

    Code of Federal Regulations, 2011 CFR

    2011-07-01

    ... transfer of property (including any property interest) away from the Government of Libya or a person, such... transferred or attempted to be transferred to the Government of Libya or any other person whose property and... which the Government of Libya or that person has an interest and therefore blocked. ...

  7. 31 CFR 570.403 - Termination and acquisition of an interest in blocked property.

    Code of Federal Regulations, 2014 CFR

    2014-07-01

    ... transfer of property (including any property interest) away from the Government of Libya or a person, such... transferred or attempted to be transferred to the Government of Libya or any other person whose property and... which the Government of Libya or that person has an interest and therefore blocked. ...

  8. 31 CFR 570.403 - Termination and acquisition of an interest in blocked property.

    Code of Federal Regulations, 2013 CFR

    2013-07-01

    ... transfer of property (including any property interest) away from the Government of Libya or a person, such... transferred or attempted to be transferred to the Government of Libya or any other person whose property and... which the Government of Libya or that person has an interest and therefore blocked. ...

  9. 26 CFR 1.707-6 - Disguised sales of property by partnership to partner; general rules.

    Code of Federal Regulations, 2010 CFR

    2010-04-01

    ... transferred property to the partner; by (B) The excess of the fair market value of the property at the time it... property X to A. At the time of the transfer, property X has a fair market value of $1,000,000. One year... provided in § 1.707-3 apply in determining whether a transfer of property by a partnership to a partner and...

  10. Microstructure Evolution and Mechanical Behavior of 2219 Aluminum Alloys Additively Fabricated by the Cold Metal Transfer Process

    PubMed Central

    Fang, Xuewei; Li, Hui; Li, Chaolong; Lu, Bingheng

    2018-01-01

    In this research, four different welding arc modes including conventional cold metal transfer (CMT), CMT-Pulse (CMT-P), CMT-Advanced (CMT-ADV), and CMT pulse advanced (CMT-PADV) were used to deposit 2219-Al wire. The effects of different arc modes on porosity, pore size distribution, microstructure evolution, and mechanical properties were thoroughly investigated. The statistical analysis of the porosity and its size distribution indicated that the CMT-PADV process gave the smallest pore area percentage and pore aspect ratio, and had almost no larger pores. The results from optical microscopy, scanning electron microscopy, and fractographic morphology proved that uniform and fine equiaxed grains, evenly distributed Al2Cu second phase particles were formed during the CMT-PADV process. Furthermore, the X-ray diffraction test ascertained that the CMT-PADV sample had the smallest lattice parameter and the highest solute Cu content. Besides, the tensile strength could reach 283 MPa, the data scattering was the smallest, and the strength scattering of the sample in the horizontal direction was the shortest. In addition, the strength properties were nearly isotropic, with only 5 MPa difference in the vertical and horizontal directions. The above mentioned results indicated that the mechanical properties of 2219 aluminum alloy was improved using the CMT-PADV arc mode. PMID:29772708

  11. Microstructure Evolution and Mechanical Behavior of 2219 Aluminum Alloys Additively Fabricated by the Cold Metal Transfer Process.

    PubMed

    Fang, Xuewei; Zhang, Lijuan; Li, Hui; Li, Chaolong; Huang, Ke; Lu, Bingheng

    2018-05-16

    In this research, four different welding arc modes including conventional cold metal transfer (CMT), CMT-Pulse (CMT-P), CMT-Advanced (CMT-ADV), and CMT pulse advanced (CMT-PADV) were used to deposit 2219-Al wire. The effects of different arc modes on porosity, pore size distribution, microstructure evolution, and mechanical properties were thoroughly investigated. The statistical analysis of the porosity and its size distribution indicated that the CMT-PADV process gave the smallest pore area percentage and pore aspect ratio, and had almost no larger pores. The results from optical microscopy, scanning electron microscopy, and fractographic morphology proved that uniform and fine equiaxed grains, evenly distributed Al₂Cu second phase particles were formed during the CMT-PADV process. Furthermore, the X-ray diffraction test ascertained that the CMT-PADV sample had the smallest lattice parameter and the highest solute Cu content. Besides, the tensile strength could reach 283 MPa, the data scattering was the smallest, and the strength scattering of the sample in the horizontal direction was the shortest. In addition, the strength properties were nearly isotropic, with only 5 MPa difference in the vertical and horizontal directions. The above mentioned results indicated that the mechanical properties of 2219 aluminum alloy was improved using the CMT-PADV arc mode.

  12. Size dependence of energetic properties in nanowire-based energetic materials

    NASA Astrophysics Data System (ADS)

    Menon, L.; Aurongzeb, D.; Patibandla, S.; Bhargava Ram, K.; Richter, C.; Sacco, A.

    2006-08-01

    We prepared nanowire-array-based thin film energetic nanocomposites based on Al -Fe2O3. The ignition properties as a function of wire dimensions and interwire spacing have been investigated. We show significant variations in ignition behavior, which we relate to the kinetic and heat transfer dynamics of the various configurations studied. Our results indicate the possibility for nanoscale control of reaction parameters such as flame temperature and burn rate in such composites for optimized configurations (optimum wire size, interwire spacing, film thickness, etc.).

  13. Idiocy and the Law in Colonial New England.

    ERIC Educational Resources Information Center

    Wickham, Parnel

    2001-01-01

    A review of laws and records of the courts of colonial New England indicates early laws of Massachusetts extended certain rights to idiots: they authorized the transfer of property, exonerated idiots who committed capital crimes, and extended relief to impoverished idiots. The relationship between colonial laws and present legislation is examined.…

  14. Improved ferroelectric and photoluminescence properties in Pr3+ substituted Na0.5Bi0.5TiO3 synthesized using hydrothermal route

    NASA Astrophysics Data System (ADS)

    Goutham, Cilaveni; Kandula, Kumara Raja; Raavi, Sai Santhosh Kumar; Asthana, Saket

    2018-04-01

    Nanocrystalline Pr3+ substituted NBT was synthesized using hydrothermal technique. Pr3+ modifies the ferroelectric NBT optically active and enhances the electrical properties with small structural changes. Aiming to the development of the bottom up optoelectronic devices this optimized nanoscale Na0.5Bi0.5-xPrxTiO3(x = 0.005) compound is synthesized hydrothermally. X-ray diffraction pattern shows that the system is stabilized in the Rhombohedral (space groupR3c) phase indicating the local strain inhomogeneity. PE loop shows that there is a decrement in the Ec value compared with compounds synthesized using conventional methods. The strong red emission assigned to prominent transition of the Pr3+ ions at 610nm was observed along with weak blue-green emission, indicating the potential use of the system. Energy transfer from host system to Pr3+ ions is responsible for red emission while blue green emission is due to quenching of 3P0 induced by intervalence charge transfer state.

  15. Decree No. 896, Law on transferring rural state property suitable for agriculture and livestock to the beneficiaries of agrarian reform, 18 February 1988.

    PubMed

    1988-01-01

    This Law creates a Special Technical Commission in El Salvador to collect information, investigate, and make decisions on the transfer of property belonging to the State. State property includes property belonging to the State at the national, regional, and local levels as well as land belonging to official autonomous institutions and public law corporations. Such property is eligible for transfer if it is not indispensable for state activities and if it is suitable for agriculture. Under the Law, all government bodies, official autonomous institutions, and public law corporations have the duty to report to the Commission the status of their property. After the Executive determines which properties are to be transferred, the property will be paid for through agrarian reform bonds. The property will be transferred to farmers with no land or with insufficient land and to farming cooperatives. Preference will be given to farmers without land and to those who have been exploiting the land subject to transfer. Persons acquiring land will pay for it through mortgages in favor of state agrarian reform agencies. full text

  16. 26 CFR 1.1041-1T - Treatment of transfer of property between spouses or incident to divorce (temporary).

    Code of Federal Regulations, 2010 CFR

    2010-04-01

    ... whether the transfer is of property separately owned by the transferor or is a division (equal or unequal... includes a modification or amendment to such decree or instrument. Any transfer not pursuant to a divorce... the transferred property equal to the transferee's cost (the fair market value). This carryover basis...

  17. 10 CFR 770.6 - May interested persons and entities request that real property at defense nuclear facilities be...

    Code of Federal Regulations, 2010 CFR

    2010-01-01

    ... property at defense nuclear facilities be transferred for economic development? 770.6 Section 770.6 Energy DEPARTMENT OF ENERGY TRANSFER OF REAL PROPERTY AT DEFENSE NUCLEAR FACILITIES FOR ECONOMIC DEVELOPMENT § 770.6... transferred for economic development? Any person or entity may request that specific real property be made...

  18. 48 CFR 245.103-71 - Transferring Government property accountability.

    Code of Federal Regulations, 2014 CFR

    2014-10-01

    ... 48 Federal Acquisition Regulations System 3 2014-10-01 2014-10-01 false Transferring Government... ACQUISITION REGULATIONS SYSTEM, DEPARTMENT OF DEFENSE CONTRACT MANAGEMENT GOVERNMENT PROPERTY General 245.103-71 Transferring Government property accountability. Follow the procedures at PGI 245.103-71 for...

  19. Differentiated effect of ageing on the enzymes of Krebs' cycle, electron transfer complexes and glutamate metabolism of non-synaptic and intra-synaptic mitochondria from cerebral cortex.

    PubMed

    Villa, R F; Gorini, A; Hoyer, S

    2006-11-01

    The effect of ageing on the activity of enzymes linked to Krebs' cycle, electron transfer chain and glutamate metabolism was studied in three different types of mitochondria of cerebral cortex of 1-year old and 2-year old male Wistar rats. We assessed the maximum rate (V(max)) of the mitochondrial enzyme activities in non-synaptic perikaryal mitochondria, and in two populations of intra-synaptic mitochondria. The results indicated that: (i) in normal, steady-state cerebral cortex the values of the catalytic activities of the enzymes markedly differed in the various populations of mitochondria; (ii) in intra-synaptic mitochondria, ageing affected the catalytic properties of the enzymes linked to Krebs' cycle, electron transfer chain and glutamate metabolism; (iii) these changes were more evident in intra-synaptic "heavy" than "light" mitochondria. These results indicate a different age-related vulnerability of subpopulations of mitochondria in vivo located into synapses than non-synaptic ones.

  20. Assessing transfer property and reliability of urban bus network based on complex network theory

    NASA Astrophysics Data System (ADS)

    Zhang, Hui; Zhuge, Cheng-Xiang; Zhao, Xiang; Song, Wen-Bo

    Transfer reliability has an important impact on the urban bus network. The proportion of zero and one transfer time is a key indicator to measure the connectivity of bus networks. However, it is hard to calculate the transfer time between nodes because of the complicated network structure. In this paper, the topological structures of urban bus network in Jinan are constructed by space L and space P. A method to calculate transfer times between stations has been proposed by reachable matrix under space P. The result shows that it is efficient to calculate the transfer time between nodes in large networks. In order to test the transfer reliability, a node failure process has been built according to degree, clustering coefficient and betweenness centrality under space L and space P. The results show that the deliberate attack by betweenness centrality under space P is more effective compared with other five attack modes. This research could provide a power tool to find hub stations in bus networks and give a help for traffic manager to guarantee the normal operation of urban bus systems.

  1. Excited-state redox properties of ruthenium(II) phthalocyanine from electron-transfer quenching

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Prasad, D.R.; Ferraudi, G.

    1982-09-30

    Electron-transfer reactions between the lowest-lying triplet state, /sup 3/..pi pi../sup */, of ruthenium (phthalocyanine)(pyridine)/sub 2/ and various nitroaromatic compounds have been studied by laser and conventional flash photolysis. Quenching rate constants determined for the oxidation of the excited state have been treated according to the Marcus-Hush theory. A self-exchange rate constant K approx. 10/sup 7/ M/sup -1/ x/sup -1/ was determined for the self-exchange reaction between the /sup 3/..pi pi../sup */ and radical cation, Ru(ph)(py)/sub 2//sup +/. Such a value indicates that the major component to the Franck-Condon reorganizational energy is the outer-sphere contribution. The photochemical properties of the phthalocyaninesmore » are discussed in terms of the redox potentials estimate for various excited states.« less

  2. DOE Office of Scientific and Technical Information (OSTI.GOV)

    N, Rekha T.; Rajkumar, Beulah J. M., E-mail: beulah-rajkumar@yahoo.co.in

    Charge transfer properties of pentacene adsorbed on silver is investigated using DFT methods. Optimized geometry of pentacene after adsorption on silver indicates distortion in hexagonal structure of the ring close to the silver cluster and deviations in co-planarity of carbon atoms due to the variations in bond angles and dihedral angles. Theoretically simulated absorption spectrum has a symmetric surface plasmon resonance peak around 486nm corresponding to the transfer of charge from HOMO-2 to LUMO. Theoretical SERS confirms the process of adsorption, tilted orientation of pentacene on silver surface and the charge transfers reported. Localization of electron density arising from redistributionmore » of electrostatic potential together with a reduced bandgap of pentacene after adsorption on silver suggests its utility in the design of electro active organic semiconducting devices.« less

  3. Further Insights on the Chemical Structure of Humic Substances (HS) and Chromophoric Dissolved Organic Matter (CDOM) in Relation to their Optical/Chemical Properties

    NASA Astrophysics Data System (ADS)

    Del Vecchio, R.; Schendorf, T. M.; Koech, K.; Blough, N. V.

    2016-02-01

    HS have been studied extensively over the last decades, yet the structural basis of their optical properties is still highly debated. Aromatic ketones, aldehydes and quinones along with carboxylic groups and phenolic moieties are significant constituents of HS, however their contribution to the optical properties has only recently been investigated. Chemical manipulation of selected functional groups thus represents an extremely promising approach to highlight the contribution of such groups to the HS (and CDOM) optical properties. Chemical reduction (and re-oxidation) along with pH titrations are employed herein to assess the relative contribution of aromatic ketones/aldehydes/quinones and carboxylic groups/phenolic moieties, respectively to the optical properties of HS (and CDOM). Results indicate that (a) the contribution of quinones to HS absorption and fluorescence is minor (or nil), while that of aromatic ketones (and aldehydes) is significant; (b) phenolic groups contribute more than carboxylic acids to the HS optical properties; (c) the effects of borohydride reduction and pH on the long-wavelength absorption and fluorescence is consistent with charge-transfer interactions between carbonyl and phenolic groups (as well as aromatic carboxylic acids, but to a smaller extent). Results will be presented within the context of our proposed charge-transfer model.

  4. Factors Affecting Transfer of Pyrethroid Residues from Herbal Teas to Infusion and Influence of Physicochemical Properties of Pesticides

    PubMed Central

    Xiao, Jin-Jing; Li, Yang; Fang, Qing-Kui; Shi, Yan-Hong; Liao, Min; Wu, Xiang-Wei; Hua, Ri-Mao

    2017-01-01

    The transfer of pesticide residues from herbal teas to their infusion is a subject of particular interest. In this study, a multi-residue analytical method for the determination of pyrethroids (fenpropathrin, beta-cypermethrin, lambda-cyhalothrin, and fenvalerate) in honeysuckle, chrysanthemum, wolfberry, and licorice and their infusion samples was validated. The transfer of pyrethroid residues from tea to infusion was investigated at different water temperatures, tea/water ratios, and infusion intervals/times. The results show that low amounts (0–6.70%) of pyrethroids were transferred under the different tea brewing conditions examined, indicating that the infusion process reduced the pyrethroid content in the extracted liquid by over 90%. Similar results were obtained for the different tea varieties, and pesticides with high water solubility and low octanol–water partition coefficients (log Kow) exhibited high transfer rates. Moreover, the estimated values of the exposure risk to the pyrethroids were in the range of 0.0022–0.33, indicating that the daily intake of the four pyrethroid residues from herbal tea can be regarded as safe. The present results can support the identification of suitable tea brewing conditions for significantly reducing the pesticide residue levels in the infusion. PMID:28973970

  5. Adsorption of formaldehyde on graphene and graphyne

    NASA Astrophysics Data System (ADS)

    Majidi, R.; Karami, A. R.

    2014-05-01

    The adsorption of formaldehyde on graphene and graphyne was investigated to search high sensitivity sensors for detection of formaldehyde. We have used density functional theory to study the effect of formaldehyde on the electronic properties of graphene and graphyne. It is found that formaldehyde is physisorbed on the graphene and graphyne with small binding energy, large binding distance, and small charge transfer. The calculations also indicate that formaldehyde adsorption modifies the electronic properties of semimetallic graphene, α-graphyne, and β-graphyne and semiconducting γ-graphyne. The graphene and graphyne show semiconducting property in the presence of formaldehyde. The effect of formaldehyde on the electronic properties of graphene and graphyne suggests the potential application of these carbon nanomaterials for formaldehyde detection.

  6. 78 FR 23487 - Certain Outbound Property Transfers by Domestic Corporations; Certain Stock Distributions by...

    Federal Register 2010, 2011, 2012, 2013, 2014

    2013-04-19

    ... Outbound Property Transfers by Domestic Corporations; Certain Stock Distributions by Domestic Corporations... temporary regulations apply to transfers of certain property by a domestic corporation to a foreign corporation in certain nonrecognition exchanges, or to distributions of stock of certain foreign corporations...

  7. 12 CFR 591.2 - Definitions.

    Code of Federal Regulations, 2011 CFR

    2011-01-01

    ... includes transfers of real property subject to a real property loan by assumptions, installment land sales... other like transfers.“Completed credit application” has the same meaning as completed application for... security instrument upon a sale of transfer of all or any part of the real property securing the loan...

  8. 12 CFR 591.2 - Definitions.

    Code of Federal Regulations, 2010 CFR

    2010-01-01

    ... includes transfers of real property subject to a real property loan by assumptions, installment land sales... other like transfers.“Completed credit application” has the same meaning as completed application for... security instrument upon a sale of transfer of all or any part of the real property securing the loan...

  9. 41 CFR 102-73.295 - What property transfer expenses must Federal agencies cover when acquiring real property?

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... 41 Public Contracts and Property Management 3 2010-07-01 2010-07-01 false What property transfer... Contracts and Property Management Federal Property Management Regulations System (Continued) FEDERAL MANAGEMENT REGULATION REAL PROPERTY 73-REAL ESTATE ACQUISITION Acquisition by Purchase or Condemnation...

  10. Photoluminescence properties and energy transfer in Ce(3+) /Dy(3+) co-doped Sr(3) MgSi(2) O(8) phosphors for potential application in ultraviolet white light-emitting diodes.

    PubMed

    Yu, Hong; Zi, Wenwen; Lan, Shi; Gan, Shucai; Zou, Haifeng; Xu, Xuechun; Hong, Guangyan

    2013-01-01

    Sr(3) MgSi(2) O(8) :Ce(3+) , Dy(3+) phosphors were prepared by a solid-state reaction technique and the photoluminescence properties were investigated. The emission spectra show not only a band due to Ce(3+) ions (403 nm) but also as a band due to Dy(3+) ions (480, 575 nm) (UV light excitation). The photoluminescence properties reveal that effective energy transfer occurs in Ce(3+) /Dy(3+) co-doped Sr(3) MgSi(2) O(8)phosphors, and the co-doping of Ce(3+) could enhance the emission intensity of Dy(3+) to a certain extent by transferring its energy to Dy(3+) . The Ce(3+) /Dy(3+) energy transfer was investigated by emission/excitation spectra, and photoluminescence decay behaviors. In Sr2.94 MgSi2 O8 :0.01Ce(3+) , 0.05Dy(3+) phosphors, the fluorescence lifetime of Dy(3+) (from 3.35 to 27.59 ns) is increased whereas that of Ce(3+) is greatly decreased (from 43.59 to 13.55 ns), and this provides indirect evidence of the Ce(3+) to Dy(3+) energy transfer. The varied emitted color of Sr(3) MgSi(2) O(8):Ce(3+) , Dy(3+) phosphors from blue to white were achieved by altering the concentration ratio of Ce(3+) and Dy(3+) . These results indicate Sr(3) MgSi(2) O(8):Ce(3+) , Dy(3+) may be as a candidate phosphor for white light-emitting diodes. Copyright © 2012 John Wiley & Sons, Ltd.

  11. Defining the origins of electron transfer at screen-printed graphene-like and graphite electrodes: MoO2 nanowire fabrication on edge plane sites reveals electrochemical insights.

    PubMed

    Rowley-Neale, Samuel J; Brownson, Dale A C; Banks, Craig E

    2016-08-18

    Molybdenum (di)oxide (MoO2) nanowires are fabricated onto graphene-like and graphite screen-printed electrodes (SPEs) for the first time, revealing crucial insights into the electrochemical properties of carbon/graphitic based materials. Distinctive patterns observed in the electrochemical process of nanowire decoration show that electron transfer occurs predominantly on edge plane sites when utilising SPEs fabricated/comprised of graphitic materials. Nanowire fabrication along the edge plane sites (and on edge plane like-sites/defects) of graphene/graphite is confirmed with Cyclic Voltammetry, Scanning Electron Microscopy (SEM) and Raman Spectroscopy. Comparison of the heterogeneous electron transfer (HET) rate constants (k°) at unmodified and nanowire coated SPEs show a reduction in the electrochemical reactivity of SPEs when the edge plane sites are effectively blocked/coated with MoO2. Throughout the process, the basal plane sites of the graphene/graphite electrodes remain relatively uncovered; except when the available edge plane sites have been utilised, in which case MoO2 deposition grows from the edge sites covering the entire surface of the electrode. This work clearly illustrates the distinct electron transfer properties of edge and basal plane sites on graphitic materials, indicating favourable electrochemical reactivity at the edge planes in contrast to limited reactivity at the basal plane sites. In addition to providing fundamental insights into the electron transfer properties of graphite and graphene-like SPEs, the reported simple, scalable, and cost effective formation of unique and intriguing MoO2 nanowires realised herein is of significant interest for use in both academic and commercial applications.

  12. Theoretical and experimental study of electron-deficient core substitution effect of diketopyrrolopyrrole derivatives on optoelectrical and charge transport properties

    NASA Astrophysics Data System (ADS)

    Ding, Guodong; Mahmood, Asif; Tang, Ailing; Chen, Fan; Zhou, Erjun

    2018-01-01

    Three new diketopyrrolopyrrole based compounds with Acceptor-Donor-Acceptor-Donor-Acceptor (A-D-A-D-A) skeletons were designed and synthesized through varying the electron-deficient core from diphenylquinoxaline (DP-Qx), thieno[3,4-c]pyrrole-4,6-dione (DP-TPD) to 2-dodecyl-6,7-diphenyl-2H-[1,2,3]triazole[4,5-g]quinoxaline (DP-TQx). We have calculated and studied the effect of central acceptor units on electronic, optical and non-optical properties. As well as, we have predicted the charge transport properties. Results indicate that change of central acceptor unit remarkably affects the molecular electronic, optical and non-optical properties. And the molecular band gap and UV/vis adsorption spectra are significantly changed. It should be noted that Compound 3 with 2-dodecyl-6,7-diphenyl-2H-[1,2,3]triazole[4,5-g]quinoxaline as core show superior non-optical properties as compare to other compounds. Our study here indicate that inserting the strong electron-deficient moieties improves intramolecular charge transfer (ICT) and charge transport properties dramatically.

  13. Synthesis, Luminescence Properties and Energy Transfer of CaZrO3:Sm3+, Bi3+ Phosphor

    NASA Astrophysics Data System (ADS)

    Cao, Renping; Han, Peng; Luo, Wenjie; Fu, Ting; Luo, Zhiyang; Liu, Pan; Chen, Zhiquan; Yu, Xiaoguang

    2016-07-01

    Novel CaZrO3:Sm3+, Bi3+ phosphor is synthesized by a solid-state reaction method in air and the crystal structures and luminescence properties are investigated. The emission spectrum with excitation 308 nm contains emission of Sm3+ and Bi3+ ions at the same time; however, it only has an emission of Sm3+ ion with excitation 408 nm. Emission intensity of CaZrO3:Sm3+ phosphor can be enhanced about four times owing to energy transfer from the Bi3+ ion to the Sm3+ ion and with the fluxing agent role of Bi3+ ion when Bi3+ ion is co-doped. The possible luminous mechanism is analyzed by energy level diagrams of Bi3+ and Sm3+ ions and the energy transfer process in CaZrO3:Sm3+, Bi3+ phosphor. The experimental results indicate that, hopefully, CaZrO3:Sm3+, Bi3+ phosphor can be used as a reddish orange phosphor candidate for white light-emitting diodes based on near an ultraviolet (~408 nm) chip.

  14. 12 CFR 1228.1 - Definitions.

    Code of Federal Regulations, 2013 CFR

    2013-01-01

    ... continuing basis each time a property is transferred (except for transfers specifically excepted) for a period of time or indefinitely. A private transfer fee does not include fees, charges, payments, or other... SECURITY INTERESTS IN, MORTGAGES ON PROPERTIES ENCUMBERED BY CERTAIN PRIVATE TRANSFER FEE COVENANTS AND...

  15. 10 CFR 1042.120 - Transfers of property.

    Code of Federal Regulations, 2012 CFR

    2012-01-01

    ... 10 Energy 4 2012-01-01 2012-01-01 false Transfers of property. 1042.120 Section 1042.120 Energy DEPARTMENT OF ENERGY (GENERAL PROVISIONS) NONDISCRIMINATION ON THE BASIS OF SEX IN EDUCATION PROGRAMS OR... recipient sells or otherwise transfers property financed in whole or in part with Federal financial...

  16. 29 CFR 36.120 - Transfers of property.

    Code of Federal Regulations, 2013 CFR

    2013-07-01

    ... 29 Labor 1 2013-07-01 2013-07-01 false Transfers of property. 36.120 Section 36.120 Labor Office of the Secretary of Labor NONDISCRIMINATION ON THE BASIS OF SEX IN EDUCATION PROGRAMS OR ACTIVITIES RECEIVING FEDERAL FINANCIAL ASSISTANCE Introduction § 36.120 Transfers of property. If a recipient sells or...

  17. 29 CFR 36.120 - Transfers of property.

    Code of Federal Regulations, 2011 CFR

    2011-07-01

    ... 29 Labor 1 2011-07-01 2011-07-01 false Transfers of property. 36.120 Section 36.120 Labor Office of the Secretary of Labor NONDISCRIMINATION ON THE BASIS OF SEX IN EDUCATION PROGRAMS OR ACTIVITIES RECEIVING FEDERAL FINANCIAL ASSISTANCE Introduction § 36.120 Transfers of property. If a recipient sells or...

  18. 29 CFR 36.120 - Transfers of property.

    Code of Federal Regulations, 2012 CFR

    2012-07-01

    ... 29 Labor 1 2012-07-01 2012-07-01 false Transfers of property. 36.120 Section 36.120 Labor Office of the Secretary of Labor NONDISCRIMINATION ON THE BASIS OF SEX IN EDUCATION PROGRAMS OR ACTIVITIES RECEIVING FEDERAL FINANCIAL ASSISTANCE Introduction § 36.120 Transfers of property. If a recipient sells or...

  19. 10 CFR 1042.120 - Transfers of property.

    Code of Federal Regulations, 2011 CFR

    2011-01-01

    ... 10 Energy 4 2011-01-01 2011-01-01 false Transfers of property. 1042.120 Section 1042.120 Energy DEPARTMENT OF ENERGY (GENERAL PROVISIONS) NONDISCRIMINATION ON THE BASIS OF SEX IN EDUCATION PROGRAMS OR... recipient sells or otherwise transfers property financed in whole or in part with Federal financial...

  20. ∼2 μm fluorescence radiative dynamics and energy transfer between Er{sup 3+} and Tm{sup 3+} ions in silicate glass

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Li, Ming; Liu, Xueqiang; Graduate School of Chinese Academy of Sciences, Beijing 100039

    2014-03-01

    Graphical abstract: - Highlights: • A Er{sup 3+}/Tm{sup 3+} co-doped silicate glass with good thermal stability (k{sub gl} = 0.402 for STE glass) is prepared. • Efficient ∼2 μm emission is observed under 808 nm and 980 nm laser excitation. • The glass structure and spectroscopic properties are confirmed by optical absorption, IR transmission, Raman and fluorescence studies. • The content of OH groups deceases efficiently after fluorine ions are introduced. • The energy transfer coefficient from Er{sup 3+} to Tm{sup 3+} in STFE glass is 13.39 × 10{sup −40} cm{sup 6}/s. - Abstract: A Er{sup 3+}/Tm{sup 3+} co-doped silicatemore » glass with good thermal stability is prepared by melt-quenching method. An efficient emission of ∼2 μm is observed under different selective laser excitations. The optical absorption and transmission spectra, Raman spectra, and emission spectra are tested to characterize ∼2 μm emission properties of Er{sup 3+}/Tm{sup 3+} co-doped silicate glasses and a reasonable energy transfer mechanism of ∼2 μm emission between Er{sup 3+} and Tm{sup 3+} ions is proposed. Based on the optical absorption spectra, the Judd–Ofelt parameters and radiative properties were calculated. Intense ∼2 μm emission is obtained from Er{sup 3+}/Tm{sup 3+} co-doped silicate glasses due to the efficient energy transfer from Er{sup 3+} to Tm{sup 3+} ions. The energy transfer coefficient from Er{sup 3+} to Tm{sup 3+} ions can reach as high as 13.39 × 10{sup −40} cm{sup 6}/s. In addition, the population of the OH groups is decreased and the ∼2 μm emission is effectively enhanced with fluoride introduction. The emission property, together with good thermal property, indicates that Er{sup 3+}/Tm{sup 3+} co-doped silicate glass is a potential kind of laser glass for efficient ∼2 μm laser.« less

  1. 12 CFR Appendix A to Subpart B of... - Risk-Based Capital Stress Test

    Code of Federal Regulations, 2013 CFR

    2013-01-01

    ... Loan Number Ending Scheduled Balance Group Pre/Post Act Property State Product Type Origination Date... t-test 2 of the differences in the means for the group of defaulted loans and active loans indicated... of pre-1996 loan volume being transferred to post-1996 loan volume. The interest rate risk and credit...

  2. 12 CFR Appendix A to Subpart B of... - Risk-Based Capital Stress Test

    Code of Federal Regulations, 2012 CFR

    2012-01-01

    ... Loan Number Ending Scheduled Balance Group Pre/Post Act Property State Product Type Origination Date... t-test 2 of the differences in the means for the group of defaulted loans and active loans indicated... of pre-1996 loan volume being transferred to post-1996 loan volume. The interest rate risk and credit...

  3. 12 CFR Appendix A to Subpart B of... - Risk-Based Capital Stress Test

    Code of Federal Regulations, 2014 CFR

    2014-01-01

    ... Loan Number Ending Scheduled Balance Group Pre/Post Act Property State Product Type Origination Date... t-test 2 of the differences in the means for the group of defaulted loans and active loans indicated... of pre-1996 loan volume being transferred to post-1996 loan volume. The interest rate risk and credit...

  4. Clouds in the atmospheres of extrasolar planets. IV. On the scattering greenhouse effect of CO2 ice particles: Numerical radiative transfer studies

    NASA Astrophysics Data System (ADS)

    Kitzmann, D.; Patzer, A. B. C.; Rauer, H.

    2013-09-01

    Context. Owing to their wavelength-dependent absorption and scattering properties, clouds have a strong impact on the climate of planetary atmospheres. The potential greenhouse effect of CO2 ice clouds in the atmospheres of terrestrial extrasolar planets is of particular interest because it might influence the position and thus the extension of the outer boundary of the classic habitable zone around main sequence stars. Such a greenhouse effect, however, is a complicated function of the CO2 ice particles' optical properties. Aims: We study the radiative effects of CO2 ice particles obtained by different numerical treatments to solve the radiative transfer equation. To determine the effectiveness of the scattering greenhouse effect caused by CO2 ice clouds, the radiative transfer calculations are performed over the relevant wide range of particle sizes and optical depths, employing different numerical methods. Methods: We used Mie theory to calculate the optical properties of particle polydispersion. The radiative transfer calculations were done with a high-order discrete ordinate method (DISORT). Two-stream radiative transfer methods were used for comparison with previous studies. Results: The comparison between the results of a high-order discrete ordinate method and simpler two-stream approaches reveals large deviations in terms of a potential scattering efficiency of the greenhouse effect. The two-stream methods overestimate the transmitted and reflected radiation, thereby yielding a higher scattering greenhouse effect. For the particular case of a cool M-type dwarf, the CO2 ice particles show no strong effective scattering greenhouse effect by using the high-order discrete ordinate method, whereas a positive net greenhouse effect was found for the two-stream radiative transfer schemes. As a result, previous studies of the effects of CO2 ice clouds using two-stream approximations overrated the atmospheric warming caused by the scattering greenhouse effect. Consequently, the scattering greenhouse effect of CO2 ice particles seems to be less effective than previously estimated. In general, higher order radiative transfer methods are needed to describe the effects of CO2 ice clouds accurately as indicated by our numerical radiative transfer studies.

  5. Spectroscopic analysis and efficient diode-pumped 2.0 μm emission in Ho3+/Tm3+ codoped fluoride glass

    NASA Astrophysics Data System (ADS)

    Tian, Ying; Jing, Xufeng; Xu, Shiqing

    2013-11-01

    Intense 2.0 μm emission has been obtained in Ho3+/Tm3+ codoped ZBLAY glass pumped by common laser diode. Three intensity parameters and radiative properties have been determined from the absorption spectrum based on the Judd-Ofelt theory. The 2 μm emission characteristics and the energy transfer mechanism upon excitation of a conventional 800 nm laser diode are investigated. Efficient Tm3+ to Ho3+ energy transfer processes have been observed in present glass and investigated using steady-state and time-resolved optical spectroscopy measurement. The energy transfer microscopic parameter has been calculated with the Inokuti-Hirayama and Förster-Dexter models. High quantum efficiency of 2 μm emission (80.35%) and large energy transfer coefficient from Tm3+ to Ho3+ indicates this Ho3+/Tm3+ codoped ZBLAY glass is a promising material for 2.0 μm laser.

  6. Oscillation characteristics of zero-field spin transfer oscillators with field-like torque

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Guo, Yuan-Yuan; Xue, Hai-Bin, E-mail: xuehaibin@tyut.edu.cn; Department of Physics and Optoelectronics, Taiyuan University of Technology, Taiyuan 030024

    2015-05-15

    We theoretically investigate the influence of the field-like spin torque term on the oscillation characteristics of spin transfer oscillators, which are based on MgO magnetic tunnel junctions (MTJs) consisting of a perpendicular magnetized free layer and an in-plane magnetized pinned layer. It is demonstrated that the field-like torque has a strong impact on the steady-state precession current region and the oscillation frequency. In particular, the steady-state precession can occur at zero applied magnetic field when the ratio between the field-like torque and the spin transfer torque takes up a negative value. In addition, the dependence of the oscillation properties onmore » the junction sizes has also been analyzed. The results indicate that this compact structure of spin transfer oscillator without the applied magnetic field is practicable under certain conditions, and it may be a promising configuration for the new generation of on-chip oscillators.« less

  7. Parametric dependence of ocean wave-radar modulation transfer functions

    NASA Technical Reports Server (NTRS)

    Plant, W. J.; Keller, W. C.; Cross, A.

    1983-01-01

    Microwave techniques at X and L band were used to determine the dependence of ocean-wave radar modulation transfer functions (MTFs) on various environmental and radar parameters during the Marine Remote Sensing experiment of 1979 (MARSEN 79). These MIF are presented, as are coherence functions between the AM and FM parts of the backscattered microwave signal. It is shown that they both depend on several of these parameters. Besides confirming many of the properties of transfer functions reported by previous authors, indications are found that MTFs decrease with increasing angle between wave propagation and antenna-look directions but are essentially independent of small changes in air-sea temperature difference. However, coherence functions are much smaller when the antennas are pointed perpendicular to long waves. It is found that X band transfer functions measured with horizontally polarized microwave radiation have larger magnitudes than those obtained by using vertical polarization.

  8. Anomalous heat transfer modes of nanofluids: a review based on statistical analysis

    NASA Astrophysics Data System (ADS)

    Sergis, Antonis; Hardalupas, Yannis

    2011-05-01

    This paper contains the results of a concise statistical review analysis of a large amount of publications regarding the anomalous heat transfer modes of nanofluids. The application of nanofluids as coolants is a novel practise with no established physical foundations explaining the observed anomalous heat transfer. As a consequence, traditional methods of performing a literature review may not be adequate in presenting objectively the results representing the bulk of the available literature. The current literature review analysis aims to resolve the problems faced by researchers in the past by employing an unbiased statistical analysis to present and reveal the current trends and general belief of the scientific community regarding the anomalous heat transfer modes of nanofluids. The thermal performance analysis indicated that statistically there exists a variable enhancement for conduction, convection/mixed heat transfer, pool boiling heat transfer and critical heat flux modes. The most popular proposed mechanisms in the literature to explain heat transfer in nanofluids are revealed, as well as possible trends between nanofluid properties and thermal performance. The review also suggests future experimentation to provide more conclusive answers to the control mechanisms and influential parameters of heat transfer in nanofluids.

  9. Anomalous heat transfer modes of nanofluids: a review based on statistical analysis.

    PubMed

    Sergis, Antonis; Hardalupas, Yannis

    2011-05-19

    This paper contains the results of a concise statistical review analysis of a large amount of publications regarding the anomalous heat transfer modes of nanofluids. The application of nanofluids as coolants is a novel practise with no established physical foundations explaining the observed anomalous heat transfer. As a consequence, traditional methods of performing a literature review may not be adequate in presenting objectively the results representing the bulk of the available literature. The current literature review analysis aims to resolve the problems faced by researchers in the past by employing an unbiased statistical analysis to present and reveal the current trends and general belief of the scientific community regarding the anomalous heat transfer modes of nanofluids. The thermal performance analysis indicated that statistically there exists a variable enhancement for conduction, convection/mixed heat transfer, pool boiling heat transfer and critical heat flux modes. The most popular proposed mechanisms in the literature to explain heat transfer in nanofluids are revealed, as well as possible trends between nanofluid properties and thermal performance. The review also suggests future experimentation to provide more conclusive answers to the control mechanisms and influential parameters of heat transfer in nanofluids.

  10. Anomalous heat transfer modes of nanofluids: a review based on statistical analysis

    PubMed Central

    2011-01-01

    This paper contains the results of a concise statistical review analysis of a large amount of publications regarding the anomalous heat transfer modes of nanofluids. The application of nanofluids as coolants is a novel practise with no established physical foundations explaining the observed anomalous heat transfer. As a consequence, traditional methods of performing a literature review may not be adequate in presenting objectively the results representing the bulk of the available literature. The current literature review analysis aims to resolve the problems faced by researchers in the past by employing an unbiased statistical analysis to present and reveal the current trends and general belief of the scientific community regarding the anomalous heat transfer modes of nanofluids. The thermal performance analysis indicated that statistically there exists a variable enhancement for conduction, convection/mixed heat transfer, pool boiling heat transfer and critical heat flux modes. The most popular proposed mechanisms in the literature to explain heat transfer in nanofluids are revealed, as well as possible trends between nanofluid properties and thermal performance. The review also suggests future experimentation to provide more conclusive answers to the control mechanisms and influential parameters of heat transfer in nanofluids. PMID:21711932

  11. 12 CFR 1228.1 - Definitions.

    Code of Federal Regulations, 2014 CFR

    2014-01-01

    ... of title to real estate, and payable on a continuing basis each time a property is transferred (except for transfers specifically excepted) for a period of time or indefinitely. A private transfer fee... SECURITY INTERESTS IN, MORTGAGES ON PROPERTIES ENCUMBERED BY CERTAIN PRIVATE TRANSFER FEE COVENANTS AND...

  12. Properties and heat transfer coefficients of four molten-salt high temperature heat transfer fluid candidates for concentrating solar power plants

    NASA Astrophysics Data System (ADS)

    Liu, T. L.; Liu, W. R.; Xu, X. H.

    2017-11-01

    Heat transfer fluid is one critical component for transferring and storing heat energy in concentrating solar power systems. Molten-salt mixtures can be used as high temperature heat transfer fluids because of their thermophysical properties. This paper studied the thermophysical properties of Li2CO3-Na2CO3-K2CO3 eutectic salt and three eutectic chloride salts NaCl-KCl-ZnCl2 with different compositions in the range of 450-600°C and 250-800°C, respectively. Properties including specific heat capacity, thermal conductivity, density and viscosity were determined based on imperial correlations and compared at different operating temperatures. The heat transfer coefficients of using different eutectic salts as heat transfer fluids were also calculated and compared in their operating temperature range. It is concluded that all the four eutectic salts can satisfy the requirements of a high-temperature heat transfer fluid.

  13. Accreting Black Hole Binaries in Globular Clusters

    NASA Astrophysics Data System (ADS)

    Kremer, Kyle; Chatterjee, Sourav; Rodriguez, Carl L.; Rasio, Frederic A.

    2018-01-01

    We explore the formation of mass-transferring binary systems containing black holes (BHs) within globular clusters (GC). We show that it is possible to form mass-transferring BH binaries with main sequence, giant, and white dwarf companions with a variety of orbital parameters in GCs spanning a large range in present-day properties. All mass-transferring BH binaries found in our models at late times are dynamically created. The BHs in these systems experienced a median of ∼30 dynamical encounters within the cluster before and after acquiring the donor. Furthermore, we show that the presence of mass-transferring BH systems has little correlation with the total number of BHs within the cluster at any time. This is because the net rate of formation of BH–non-BH binaries in a cluster is largely independent of the total number of retained BHs. Our results suggest that the detection of a mass-transferring BH binary in a GC does not necessarily indicate that the host cluster contains a large BH population.

  14. Directly measuring of thermal pulse transfer in one-dimensional highly aligned carbon nanotubes

    PubMed Central

    Zhang, Guang; Liu, Changhong; Fan, Shoushan

    2013-01-01

    Using a simple and precise instrument system, we directly measured the thermo-physical properties of one-dimensional highly aligned carbon nanotubes (CNTs). A kind of CNT-based macroscopic materials named super aligned carbon nanotube (SACNT) buckypapers was measured in our experiment. We defined a new one-dimensional parameter, the “thermal transfer speed” to characterize the thermal damping mechanisms in the SACNT buckypapers. Our results indicated that the SACNT buckypapers with different densities have obviously different thermal transfer speeds. Furthermore, we found that the thermal transfer speed of high-density SACNT buckypapers may have an obvious damping factor along the CNTs aligned direction. The anisotropic thermal diffusivities of SACNT buckypapers could be calculated by the thermal transfer speeds. The thermal diffusivities obviously increase as the buckypaper-density increases. For parallel SACNT buckypapers, the thermal diffusivity could be as high as 562.2 ± 55.4 mm2/s. The thermal conductivities of these SACNT buckypapers were also calculated by the equation k = Cpαρ. PMID:23989589

  15. Directly measuring of thermal pulse transfer in one-dimensional highly aligned carbon nanotubes.

    PubMed

    Zhang, Guang; Liu, Changhong; Fan, Shoushan

    2013-01-01

    Using a simple and precise instrument system, we directly measured the thermo-physical properties of one-dimensional highly aligned carbon nanotubes (CNTs). A kind of CNT-based macroscopic materials named super aligned carbon nanotube (SACNT) buckypapers was measured in our experiment. We defined a new one-dimensional parameter, the "thermal transfer speed" to characterize the thermal damping mechanisms in the SACNT buckypapers. Our results indicated that the SACNT buckypapers with different densities have obviously different thermal transfer speeds. Furthermore, we found that the thermal transfer speed of high-density SACNT buckypapers may have an obvious damping factor along the CNTs aligned direction. The anisotropic thermal diffusivities of SACNT buckypapers could be calculated by the thermal transfer speeds. The thermal diffusivities obviously increase as the buckypaper-density increases. For parallel SACNT buckypapers, the thermal diffusivity could be as high as 562.2 ± 55.4 mm(2)/s. The thermal conductivities of these SACNT buckypapers were also calculated by the equation k = Cpαρ.

  16. Impact of distal mutations on the network of coupled motions correlated to hydride transfer in dihydrofolate reductase.

    PubMed

    Wong, Kim F; Selzer, Tzvia; Benkovic, Stephen J; Hammes-Schiffer, Sharon

    2005-05-10

    A comprehensive analysis of the network of coupled motions correlated to hydride transfer in dihydrofolate reductase is presented. Hybrid quantum/classical molecular dynamics simulations are combined with a rank correlation analysis method to extract thermally averaged properties that vary along the collective reaction coordinate according to a prescribed target model. Coupled motions correlated to hydride transfer are identified throughout the enzyme. Calculations for wild-type dihydrofolate reductase and a triple mutant, along with the associated single and double mutants, indicate that each enzyme system samples a unique distribution of coupled motions correlated to hydride transfer. These coupled motions provide an explanation for the experimentally measured nonadditivity effects in the hydride transfer rates for these mutants. This analysis illustrates that mutations distal to the active site can introduce nonlocal structural perturbations and significantly impact the catalytic rate by altering the conformational motions of the entire enzyme and the probability of sampling conformations conducive to the catalyzed reaction.

  17. 41 CFR 102-41.155 - Is unclaimed personal property available for transfer to another Federal agency?

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... 41 Public Contracts and Property Management 3 2010-07-01 2010-07-01 false Is unclaimed personal... and Property Management Federal Property Management Regulations System (Continued) FEDERAL MANAGEMENT... transferred property then loses its identity as unclaimed property and becomes property of the Government, and...

  18. QTAIM electron density study of natural chalcones

    NASA Astrophysics Data System (ADS)

    González Moa, María J.; Mandado, Marcos; Cordeiro, M. Natália D. S.; Mosquera, Ricardo A.

    2007-09-01

    QTAIM atomic and bond properties, ionization potential, and O-H bond dissociation energies calculated at the B3LYP/6-311++G(2d,2p) level indicate the natural chalcones bear a significant radical scavenging activity. However, their ionization potentials indicate they decrease the electron-transfer rate between antioxidant and oxygen that yields the pro-oxidative cations less than other natural antioxidants. Rings A and B display slight and similar positive charges, whereas ring B is involved in exocycle delocalization at a larger extension.

  19. Spectroscopic properties and energy transfer parameters of Er3+- doped fluorozirconate and oxyfluoroaluminate glasses

    PubMed Central

    Huang, Feifei; Liu, Xueqiang; Hu, Lili; Chen, Danping

    2014-01-01

    Er3+- doped fluorozirconate (ZrF4-BaF2-YF3-AlF3) and oxyfluoroaluminate glasses are successfully prepared here. These glasses exhibit significant superiority compared with traditional fluorozirconate glass (ZrF4-BaF2-LaF3-AlF3-NaF) because of their higher temperature of glass transition and better resistance to water corrosion. Judd-Ofelt (J-O) intensity parameters are evaluated and used to compute the radiative properties based on the VIS-NIR absorption spectra. Broad emission bands located at 1535 and 2708 nm are observed, and large calculated emission sections are obtained. The intensity of 2708 nm emission closely relates to the phonon energy of host glass. A lower phonon energy leads to a more intensive 2708 nm emission. The energy transfer processes of Er3+ ions are discussed and lifetime of Er3+: 4I13/2 is measured. It is the first time to observe that a longer lifetime of the 4I13/2 level leads to a less intensive 1535 nm emission, because the lifetime is long enough to generate excited state absorption (ESA) and energy transfer (ET) processes. These results indicate that the novel glasses possess better chemical and thermal properties as well as excellent optical properties compared with ZBLAN glass. These Er3+- doped ZBYA and oxyfluoroaluminate glasses have potential applications as laser materials. PMID:24852112

  20. 26 CFR 20.2013-4 - Valuation of property transferred.

    Code of Federal Regulations, 2010 CFR

    2010-04-01

    ... 26 Internal Revenue 14 2010-04-01 2010-04-01 false Valuation of property transferred. 20.2013-4 Section 20.2013-4 Internal Revenue INTERNAL REVENUE SERVICE, DEPARTMENT OF THE TREASURY (CONTINUED) ESTATE....2013-4 Valuation of property transferred. (a) For purposes of section 2013 and §§ 20.2013-1 to 20.2013...

  1. 26 CFR 20.2013-4 - Valuation of property transferred.

    Code of Federal Regulations, 2011 CFR

    2011-04-01

    ... 26 Internal Revenue 14 2011-04-01 2010-04-01 true Valuation of property transferred. 20.2013-4 Section 20.2013-4 Internal Revenue INTERNAL REVENUE SERVICE, DEPARTMENT OF THE TREASURY (CONTINUED) ESTATE....2013-4 Valuation of property transferred. (a) For purposes of section 2013 and §§ 20.2013-1 to 20.2013...

  2. 26 CFR 20.2013-3 - “Second limitation”.

    Code of Federal Regulations, 2014 CFR

    2014-04-01

    ... computed by subtracting from the present decedent's gross estate the value of the property transferred (see... transferred property (see § 20.2013-4)) bears to H (the value of the present decedent's gross estate reduced... limitation”. (a) The amount of the Federal estate tax attributable to the transferred property in the present...

  3. 32 CFR 196.120 - Transfers of property.

    Code of Federal Regulations, 2013 CFR

    2013-07-01

    ... transfers property financed in whole or in part with Federal financial assistance to a transferee that... is not upon such sale or transfer properly accounted for to the Federal Government, both the...

  4. 32 CFR 196.120 - Transfers of property.

    Code of Federal Regulations, 2011 CFR

    2011-07-01

    ... transfers property financed in whole or in part with Federal financial assistance to a transferee that... is not upon such sale or transfer properly accounted for to the Federal Government, both the...

  5. 32 CFR 196.120 - Transfers of property.

    Code of Federal Regulations, 2014 CFR

    2014-07-01

    ... transfers property financed in whole or in part with Federal financial assistance to a transferee that... is not upon such sale or transfer properly accounted for to the Federal Government, both the...

  6. 10 CFR 5.120 - Transfers of property.

    Code of Federal Regulations, 2013 CFR

    2013-01-01

    ... transfers property financed in whole or in part with Federal financial assistance to a transferee that... is not upon such sale or transfer properly accounted for to the Federal Government, both the...

  7. 36 CFR 1211.120 - Transfers of property.

    Code of Federal Regulations, 2011 CFR

    2011-07-01

    ... transfers property financed in whole or in part with Federal financial assistance to a transferee that... is not upon such sale or transfer properly accounted for to the Federal Government, both the...

  8. 10 CFR 5.120 - Transfers of property.

    Code of Federal Regulations, 2012 CFR

    2012-01-01

    ... transfers property financed in whole or in part with Federal financial assistance to a transferee that... is not upon such sale or transfer properly accounted for to the Federal Government, both the...

  9. 36 CFR 1211.120 - Transfers of property.

    Code of Federal Regulations, 2012 CFR

    2012-07-01

    ... transfers property financed in whole or in part with Federal financial assistance to a transferee that... is not upon such sale or transfer properly accounted for to the Federal Government, both the...

  10. 32 CFR 196.120 - Transfers of property.

    Code of Federal Regulations, 2012 CFR

    2012-07-01

    ... transfers property financed in whole or in part with Federal financial assistance to a transferee that... is not upon such sale or transfer properly accounted for to the Federal Government, both the...

  11. 45 CFR 2555.120 - Transfers of property.

    Code of Federal Regulations, 2011 CFR

    2011-10-01

    ... transfers property financed in whole or in part with Federal financial assistance to a transferee that... is not upon such sale or transfer properly accounted for to the Federal Government, both the...

  12. 10 CFR 5.120 - Transfers of property.

    Code of Federal Regulations, 2011 CFR

    2011-01-01

    ... transfers property financed in whole or in part with Federal financial assistance to a transferee that... is not upon such sale or transfer properly accounted for to the Federal Government, both the...

  13. 45 CFR 2555.120 - Transfers of property.

    Code of Federal Regulations, 2014 CFR

    2014-10-01

    ... transfers property financed in whole or in part with Federal financial assistance to a transferee that... is not upon such sale or transfer properly accounted for to the Federal Government, both the...

  14. 36 CFR 1211.120 - Transfers of property.

    Code of Federal Regulations, 2014 CFR

    2014-07-01

    ... transfers property financed in whole or in part with Federal financial assistance to a transferee that... is not upon such sale or transfer properly accounted for to the Federal Government, both the...

  15. 10 CFR 5.120 - Transfers of property.

    Code of Federal Regulations, 2014 CFR

    2014-01-01

    ... transfers property financed in whole or in part with Federal financial assistance to a transferee that... is not upon such sale or transfer properly accounted for to the Federal Government, both the...

  16. 45 CFR 2555.120 - Transfers of property.

    Code of Federal Regulations, 2012 CFR

    2012-10-01

    ... transfers property financed in whole or in part with Federal financial assistance to a transferee that... is not upon such sale or transfer properly accounted for to the Federal Government, both the...

  17. 45 CFR 2555.120 - Transfers of property.

    Code of Federal Regulations, 2013 CFR

    2013-10-01

    ... transfers property financed in whole or in part with Federal financial assistance to a transferee that... is not upon such sale or transfer properly accounted for to the Federal Government, both the...

  18. 31 CFR 560.543 - Sale of certain real property in Iran and transfer of related funds to the United States.

    Code of Federal Regulations, 2013 CFR

    2013-07-01

    ... 31 Money and Finance:Treasury 3 2013-07-01 2013-07-01 false Sale of certain real property in Iran... Statements of Licensing Policy § 560.543 Sale of certain real property in Iran and transfer of related funds... necessary and ordinarily incident to the sale of real property in Iran and to transfer the proceeds to the...

  19. 31 CFR 560.543 - Sale of certain real property in Iran and transfer of related funds to the United States.

    Code of Federal Regulations, 2014 CFR

    2014-07-01

    ... 31 Money and Finance:Treasury 3 2014-07-01 2014-07-01 false Sale of certain real property in Iran... Statements of Licensing Policy § 560.543 Sale of certain real property in Iran and transfer of related funds... necessary and ordinarily incident to the sale of real property in Iran and to transfer the proceeds to the...

  20. A facile, bio-based, novel approach for synthesis of covalently functionalized graphene nanoplatelet nano-coolants toward improved thermo-physical and heat transfer properties.

    PubMed

    Sadri, Rad; Hosseini, Maryam; Kazi, S N; Bagheri, Samira; Abdelrazek, Ali H; Ahmadi, Goodarz; Zubir, Nashrul; Ahmad, Roslina; Abidin, N I Z

    2018-01-01

    In this study, we synthesized covalently functionalized graphene nanoplatelet (GNP) aqueous suspensions that are highly stable and environmentally friendly for use as coolants in heat transfer systems. We evaluated the heat transfer and hydrodynamic properties of these nano-coolants flowing through a horizontal stainless steel tube subjected to a uniform heat flux at its outer surface. The GNPs functionalized with clove buds using the one-pot technique. We characterized the clove-treated GNPs (CGNPs) using X-ray photoelectron spectroscopy (XPS) and transmission electron microscopy (TEM). We then dispersed the CGNPs in distilled water at three particle concentrations (0.025, 0.075 and 0.1wt%) in order to prepare the CGNP-water nanofluids (nano-coolants). We used ultraviolet-visible (UV-vis) spectroscopy to examine the stability and solubility of the CGNPs in the distilled water. There is significant enhancement in thermo-physical properties of CGNPs nanofluids relative those for distilled water. We validated our experimental set-up by comparing the friction factor and Nusselt number for distilled water obtained from experiments with those determined from empirical correlations, indeed, our experimental set-up is reliable and produces results with reasonable accuracy. We conducted heat transfer experiments for the CGNP-water nano-coolants flowing through the horizontal heated tube in fully developed turbulent condition. Our results are indeed promising since there is a significant enhancement in the Nusselt number and convective heat transfer coefficient for the CGNP-water nanofluids, with only a negligible increase in the friction factor and pumping power. More importantly, we found that there is a significant increase in the performance index, which is a positive indicator that our nanofluids have potential to substitute conventional coolants in heat transfer systems because of their overall thermal performance and energy savings benefits. Copyright © 2017 Elsevier Inc. All rights reserved.

  1. Novel Red-Emitting Ba₃Y(BO₃)₃:Bi3+, Eu3+ Phosphors for N-UV White Light-Emitting Diodes.

    PubMed

    Maggay, Irish Valerie B; Liu, Wei-Ren

    2018-01-01

    Ba3Y(BO3)3:Eu3+, Bi3+ were successfully prepared via a solid-state reaction. The crystallinity, photoluminescence properties, energy transfer and thermal quenching properties were studied. Subjecting Ba3Y(BO3)3:Bi3+ samples to different excitation wavelengths (340-370 nm), obtained blue and green emission ascribed to Bi3+(II) and Bi3+(I) sites, respectively. The influence of these two sites were systematically investigated. Bi3+ efficiently transferred its absorbed energy to neighboring Eu3+ sites by enhancing its luminescence intensity. Moreover, Bi3+ greatly enhanced the excitation spectra of Eu3+ in the N-UV region by 2.26 times which indicates that Ba3Y(BO3)3:Eu3+, Bi3+ can be used as a phosphor for w-LEDs using N-UV LED chips.

  2. Decoupled Ion Transport in a Protein-Based Solid Ion Conductor.

    PubMed

    Fu, Xuewei; Jewel, Yead; Wang, Yu; Liu, Jin; Zhong, Wei-Hong

    2016-11-03

    Simultaneous achievement of good electrochemical and mechanical properties is crucial for practical applications of solid ion conductors. Conventional polymer conductors suffer from low conductivity, low transference number, and deteriorated mechanical properties with the enhancement of conductivity, resulting from the coupling between ion transport and polymer movement. Here we present a successful fabrication and fundamental understanding of a high performance soy protein-based solid conductor. The conductor shows ionic conductivity of ∼10 -5 S/cm, transference number of 0.94, and modulus of 1 GPa at room temperature, and still remains flexible and easily processable. Molecular simulations indicate that this is due to appropriate manipulation of the protein structures for effective exploitation of protein functional groups. A decoupled transport mechanism, which is able to explain all results, is proposed. The new insights can be utilized to provide guidelines for design, optimization, and fabrication of high performance biosolid conductors.

  3. 24 CFR 572.115 - Transfer of homeownership interests.

    Code of Federal Regulations, 2010 CFR

    2010-04-01

    ... 24 Housing and Urban Development 3 2010-04-01 2010-04-01 false Transfer of homeownership interests... interests. (a) Deadline for transfer. (1) All units in eligible properties (including in rem properties.... The transfer must involve either: (i) Acquisition by an eligible family of an ownership interest in a...

  4. 41 CFR 102-75.80 - What are an Executive agency's responsibilities before requesting a transfer of excess real...

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... agency's responsibilities before requesting a transfer of excess real property? 102-75.80 Section 102-75.80 Public Contracts and Property Management Federal Property Management Regulations System (Continued) FEDERAL MANAGEMENT REGULATION REAL PROPERTY 75-REAL PROPERTY DISPOSAL Utilization of Excess Real Property...

  5. IMPLICATIONS FOR THE FORMATION OF BLUE STRAGGLER STARS FROM HST ULTRAVIOLET OBSERVATIONS OF NGC 188

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Gosnell, Natalie M.; Mathieu, Robert D.; Geller, Aaron M.

    We present results of a Hubble Space Telescope (HST) far-ultraviolet (FUV) survey searching for white dwarf (WD) companions to blue straggler stars (BSSs) in open cluster NGC 188. The majority of NGC 188 BSSs (15 of 21) are single-lined binaries with properties suggestive of mass-transfer formation via Roche lobe overflow, specifically through an asymptotic giant branch star transferring mass to a main sequence secondary, yielding a BSS binary with a WD companion. In NGC 188, a BSS formed by this mechanism within the past 400 Myr will have a WD companion that is hot and luminous enough to be directlymore » detected as a FUV photometric excess with HST. Comparing expected BSS FUV emission to observed photometry reveals four BSSs with WD companions above 12,000 K (younger than 250 Myr) and three WD companions with temperatures between 11,000 and 12,000 K. These BSS+WD binaries all formed through recent mass transfer. The location of the young BSSs in an optical color–magnitude diagram (CMD) indicates that distance from the zero-age main sequence does not necessarily correlate with BSS age. There is no clear CMD separation between mass transfer-formed BSSs and those likely formed through other mechanisms, such as collisions. The seven detected WD companions place a lower limit on the mass-transfer formation frequency of 33%. We consider other possible formation mechanisms by comparing properties of the BSS population to theoretical predictions. We conclude that 14 BSS binaries likely formed from mass transfer, resulting in an inferred mass-transfer formation frequency of approximately 67%.« less

  6. 41 CFR 102-36.135 - How much time do we have to pick up excess personal property that has been approved for transfer?

    Code of Federal Regulations, 2012 CFR

    2012-01-01

    ... Excess Personal Property For Our Agency Processing Transfers § 102-36.135 How much time do we have to... 41 Public Contracts and Property Management 3 2012-01-01 2012-01-01 false How much time do we have to pick up excess personal property that has been approved for transfer? 102-36.135 Section 102-36...

  7. 41 CFR 102-36.135 - How much time do we have to pick up excess personal property that has been approved for transfer?

    Code of Federal Regulations, 2011 CFR

    2011-01-01

    ... Excess Personal Property For Our Agency Processing Transfers § 102-36.135 How much time do we have to... 41 Public Contracts and Property Management 3 2011-01-01 2011-01-01 false How much time do we have to pick up excess personal property that has been approved for transfer? 102-36.135 Section 102-36...

  8. 41 CFR 102-36.135 - How much time do we have to pick up excess personal property that has been approved for transfer?

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... Excess Personal Property For Our Agency Processing Transfers § 102-36.135 How much time do we have to... 41 Public Contracts and Property Management 3 2010-07-01 2010-07-01 false How much time do we have to pick up excess personal property that has been approved for transfer? 102-36.135 Section 102-36...

  9. 41 CFR 102-36.135 - How much time do we have to pick up excess personal property that has been approved for transfer?

    Code of Federal Regulations, 2014 CFR

    2014-01-01

    ... Excess Personal Property For Our Agency Processing Transfers § 102-36.135 How much time do we have to... 41 Public Contracts and Property Management 3 2014-01-01 2014-01-01 false How much time do we have to pick up excess personal property that has been approved for transfer? 102-36.135 Section 102-36...

  10. 41 CFR 102-36.135 - How much time do we have to pick up excess personal property that has been approved for transfer?

    Code of Federal Regulations, 2013 CFR

    2013-07-01

    ... Excess Personal Property For Our Agency Processing Transfers § 102-36.135 How much time do we have to... 41 Public Contracts and Property Management 3 2013-07-01 2013-07-01 false How much time do we have to pick up excess personal property that has been approved for transfer? 102-36.135 Section 102-36...

  11. Hydrogen film/conductive cooling

    NASA Technical Reports Server (NTRS)

    Ewen, R. L.

    1972-01-01

    Small scale nozzle tests using heated nitrogen were run to obtain effectiveness and wall heat transfer data with hydrogen film cooling. Effectiveness data are compared with an entrainment model developed from planar, unaccelerated flow data. Results indicate significant effects due to flow turning and acceleration. With injection velocity effects accounted for explicitly, heat transfer correlation coefficients were found to be the same with and without film cooling when properties are evaluated at an appropriate reference temperature for the local gas composition defined by the coolant effectiveness. A design study for an O2/H2 application with 300 psia (207 N/sq cm) chamber pressure and 1500 lbs (6670 N) thrust indicates an adiabatic wall design requires 4 to 5 percent of the total flow as hydrogen film cooling. Internal regenerative cooling designs were found to offer no reduction in coolant requirements.

  12. The effect of creative labor on property-ownership transfer by preschool children and adults.

    PubMed

    Kanngiesser, Patricia; Gjersoe, Nathalia; Hood, Bruce M

    2010-09-01

    Recognizing property ownership is of critical importance in social interactions, but little is known about how and when this attribute emerges. We investigated whether preschool children and adults believe that ownership of one person's property is transferred to a second person following the second person's investment of creative labor in that property. In our study, an experimenter and a participant borrowed modeling-clay objects from each other to mold into new objects. Participants were more likely to transfer ownership to the second individual after he or she invested creative labor in the object than after any other manipulations (holding the object, making small changes to it). This effect was significantly stronger in preschool children than in adults. Duration of manipulation had no effect on property-ownership transfer. Changes in the object's identity acted only as a secondary cue for children. We conclude that ownership is transferred after an investment of creative labor and that determining property ownership may be an intuitive process that emerges in early childhood.

  13. Dust around the Cool Component of D-Type Symbiotic Binaries

    NASA Astrophysics Data System (ADS)

    Jurkic, Tomislav; Kotnik-Karuza, Dubravka

    2018-04-01

    D type symbiotic binaries are an excellent astrophysical laboratory for investigation of the dust properties and dust formation under the influence of theMira stellar wind and nova activity and of the mass loss and mass transfer between components in such a widely separated system. We present a study of the properties of circumstellar dust in symbiotic Miras by use of long-term near-IR photometry and colour indices. The published JHKL magnitudes of o Ceti, RX Pup, KM Vel, V366 Car, V835 Cen, RR Tel, HM Sge and R Aqr have been collected, analyzed and corrected for short-term variations caused by Mira pulsations. Assuming spherical temperature distribution of the dust in the close neighbourhood of the Mira, the DUSTY code was used to solve the radiative transfer in order to determine the dust temperature and its properties in each particular case. Common dust properties of the symbiotic Miras have been found, suggesting similar conditions in the condensation region of the studied symbiotic Miras. Silicate dust with the inner dust shell radius determined by the dust condensation and with the dust temperature of 900-1200 K can fully explain the observed colour indices. R Aqr is an exception and showed lower dust temperature of 650 K. Obscuration events visible in light curves can be explained by variable dust optical depth with minimal variations of other dust properties. More active symbioticMiras that underwent recent nova outbursts showed higher dust optical depths and larger maximum grain sizes of the order of μm, which means that the post-nova activity could stimulate the dust formation and the grain growth. Optically thicker dust shells and higher dust condensation temperatures have been found in symbiotic Miras compared to their single counterparts, suggesting different conditions for dust production.

  14. 26 CFR 1.684-2 - Transfers.

    Code of Federal Regulations, 2011 CFR

    2011-04-01

    ... 1, 2007, at a time when the fair market value of the property is 1100X, I transfers the property to... market value of 500X and an adjusted basis of 100X to FT. At the time of the transfer, FT has no U.S... time of the transfer by DT to FT. Example 2. Transfer by a foreign trust. On January 1, 2001, A...

  15. 26 CFR 1.684-2 - Transfers.

    Code of Federal Regulations, 2013 CFR

    2013-04-01

    ... 1, 2007, at a time when the fair market value of the property is 1100X, I transfers the property to... market value of 500X and an adjusted basis of 100X to FT. At the time of the transfer, FT has no U.S... time of the transfer by DT to FT. Example 2. Transfer by a foreign trust. On January 1, 2001, A...

  16. 26 CFR 1.684-2 - Transfers.

    Code of Federal Regulations, 2012 CFR

    2012-04-01

    ... 1, 2007, at a time when the fair market value of the property is 1100X, I transfers the property to... market value of 500X and an adjusted basis of 100X to FT. At the time of the transfer, FT has no U.S... time of the transfer by DT to FT. Example 2. Transfer by a foreign trust. On January 1, 2001, A...

  17. 36 CFR 1211.120 - Transfers of property.

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... 36 Parks, Forests, and Public Property 3 2010-07-01 2010-07-01 false Transfers of property. 1211.120 Section 1211.120 Parks, Forests, and Public Property NATIONAL ARCHIVES AND RECORDS ADMINISTRATION... operates any education program or activity, and the Federal share of the fair market value of the property...

  18. Computational modeling of GTA (gas tungsten arc) welding with emphasis on surface tension effects

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Zacharia, T.; David, S.A.

    1990-01-01

    A computational study of the convective heat transfer in the weld pool during gas tungsten arch (GTA) welding of Type 304 stainless steel is presented. The solution of the transport equations is based on a control volume approach which utilized directly, the integral form of the governing equations. The computational model considers buoyancy and electromagnetic and surface tension forces in the solution of convective heat transfer in the weld pool. In addition, the model treats the weld pool surface as a deformable free surface. The computational model includes weld metal vaporization and temperature dependent thermophysical properties. The results indicate thatmore » consideration of weld pool vaporization effects and temperature dependent thermophysical properties significantly influence the weld model predictions. Theoretical predictions of the weld pool surface temperature distributions and the cross-sectional weld pool size and shape wee compared with corresponding experimental measurements. Comparison of the theoretically predicted and the experimentally obtained surface temperature profiles indicated agreement with {plus minus} 8%. The predicted weld cross-section profiles were found to agree very well with actual weld cross-sections for the best theoretical models. 26 refs., 8 figs.« less

  19. Novel Zn(II) complexes of 1,3-diphenyl-4-(arylazo)pyrazol-5-one derivatives: Synthesis, spectroscopic properties, DFT calculations and first order nonlinear optical properties

    NASA Astrophysics Data System (ADS)

    Abdel-Latif, Samir A.; Mohamed, Adel A.

    2018-03-01

    Eight novel Zn(II) complexes with substituted 1,3-diphenyl-4-(arylazo)pyrazol-5-one (L1-L4) derivatives have been synthesized and elucidated using various physicochemical techniques. Quantum mechanical calculations of energies, geometries were done by DFT using B3LYP/GEN functional combined with 6.311G (d,p) and LAN2DZ basis sets. The analyses of HOMO and LUMO have been used to explain the charge transfer within the ligands and complexes. The calculated small energy gap between HOMO and LUMO energies shows that the charge transfer occurs within Zn(II) complexes. Geometrical parameters, molecular electrostatic potential maps (MEP) and total electron densities analyses of the ligands and their Zn complexes have been carried out. Molecular stability, hyperconjugative interactions, intramolecular charge transfer (ICT) and bond strength has been investigated by the applying of natural bond orbital (NBO) analysis. Total static dipole moment (μ), the mean polarizability (<α>), the anisotropy of the polarizability (Δα), the mean first-order hyperpolarizability (<β>) have been also performed. The obtained values show that Zn(II) complexes is brilliant candidate to NLO materials. The analyses of the 1:1 complexes indicate that the Zn(II) ion is five-coordinated with water molecules at axial position in case of L1, L2 and L4 whereas, six-coordinated with L3 and non-electrolytic behaviour of complexes indicates the absence of counter ion.

  20. 48 CFR 45.106 - Transferring accountability.

    Code of Federal Regulations, 2010 CFR

    2010-10-01

    ... 48 Federal Acquisition Regulations System 1 2010-10-01 2010-10-01 false Transferring accountability. 45.106 Section 45.106 Federal Acquisition Regulations System FEDERAL ACQUISITION REGULATION CONTRACT MANAGEMENT GOVERNMENT PROPERTY General 45.106 Transferring accountability. Government property...

  1. Transfer rates of 19 typical pesticides and the relationship with their physicochemical property.

    PubMed

    Chen, Hongping; Pan, Meiling; Pan, Rong; Zhang, Minglu; Liu, Xin; Lu, Chengyin

    2015-01-21

    Determining the transfer rate of pesticides during tea brewing is important to identify the potential exposure risks from pesticide residues in tea. In this study, the transfer rates of 19 typical pesticides from tea to brewing were investigated using gas chromatography tandem mass and ultraperformance liquid chromatography tandem mass. The leaching rates of five pesticides (isocarbophos, triazophos, fenvalerate, buprofezin, and pyridaben) during tea brewing were first reported. The pesticides exhibited different transfer rates; however, this result was not related to residual concentrations and tea types. Pesticides with low octanol-water partition coefficients (Logkow) and high water solubility demonstrated high transfer rates. The transfer rates of pesticides with water solubility > 29 mg L(-1) (or <15 mg L(-1)) were >25% (or <10%), and those of pesticides with LogKow < 1.52 (or >2.48) were >65% (or <35%). This result indicates that water solubility at approximately 20 mg L(-1) and LogKow at approximately 2.0 could be the demarcation lines of transfer rate. The results of this study can be used as a guide in the application of pesticides to tea trees and establishment of maximum residue limits of pesticides in tea to reduce pesticide exposure in humans.

  2. 41 CFR 102-75.610 - Who is responsible for enforcing compliance with the terms and conditions of the transfer of the...

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... enforcing compliance with the terms and conditions of the transfer of the property for self-help housing or... Property Management Regulations System (Continued) FEDERAL MANAGEMENT REGULATION REAL PROPERTY 75-REAL PROPERTY DISPOSAL Surplus Real Property Disposal Property for Providing Self-Help Housing Or Housing...

  3. Multistate empirical valence bond study of temperature and confinement effects on proton transfer in water inside hydrophobic nanochannels.

    PubMed

    Tahat, Amani; Martí, Jordi

    2016-07-01

    Microscopic characteristics of an aqueous excess proton in a wide range of thermodynamic states, from low density amorphous ices (down to 100 K) to high temperature liquids under the critical point (up to 600 K), placed inside hydrophobic graphene slabs at the nanometric scale (with interplate distances between 3.1 and 0.7 nm wide) have been analyzed by means of molecular dynamics simulations. Water-proton and carbon-proton forces were modeled with a multistate empirical valence bond method. Densities between 0.07 and 0.02 Å(-3) have been considered. As a general trend, we observed a competition between effects of confinement and temperature on structure and dynamical properties of the lone proton. Confinement has strong influence on the local structure of the proton, whereas the main effect of temperature on proton properties is observed on its dynamics, with significant variation of proton transfer rates, proton diffusion coefficients, and characteristic frequencies of vibrational motions. Proton transfer is an activated process with energy barriers between 1 and 10 kJ/mol for both proton transfer and diffusion, depending of the temperature range considered and also on the interplate distance. Arrhenius-like behavior of the transfer rates and of proton diffusion are clearly observed for states above 100 K. Spectral densities of proton species indicated that in all states Zundel-like and Eigen-like complexes survive at some extent. © 2016 Wiley Periodicals, Inc. © 2016 Wiley Periodicals, Inc.

  4. 26 CFR 1.684-2 - Transfers.

    Code of Federal Regulations, 2010 CFR

    2010-04-01

    ... decides to transfer additional property with a fair market value of 1000X and an adjusted basis of 600X to... fair market value of 1000X and an adjusted basis of 300X to I, a foreign person. On January 1, 2007, at a time when the fair market value of the property is 1100X, I transfers the property to FT. A is...

  5. 41 CFR 102-75.235 - May disposal agencies transfer excess property to the Senate, the House of Representatives, and...

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... transfer excess property to the Senate, the House of Representatives, and the Architect of the Capitol? 102... the Senate, the House of Representatives, and the Architect of the Capitol? Yes, disposal agencies may transfer excess property to the Senate, the House of Representatives, and the Architect of the Capitol and...

  6. 10 CFR 770.8 - May DOE transfer real property at defense nuclear facilities for economic development at less...

    Code of Federal Regulations, 2012 CFR

    2012-01-01

    ... 10 Energy 4 2012-01-01 2012-01-01 false May DOE transfer real property at defense nuclear facilities for economic development at less than fair market value? 770.8 Section 770.8 Energy DEPARTMENT OF ENERGY TRANSFER OF REAL PROPERTY AT DEFENSE NUCLEAR FACILITIES FOR ECONOMIC DEVELOPMENT § 770.8 May DOE...

  7. 41 CFR 102-75.235 - May disposal agencies transfer excess property to the Senate, the House of Representatives, and...

    Code of Federal Regulations, 2011 CFR

    2011-01-01

    ... transfer excess property to the Senate, the House of Representatives, and the Architect of the Capitol? 102... the Senate, the House of Representatives, and the Architect of the Capitol? Yes, disposal agencies may transfer excess property to the Senate, the House of Representatives, and the Architect of the Capitol and...

  8. 10 CFR 770.8 - May DOE transfer real property at defense nuclear facilities for economic development at less...

    Code of Federal Regulations, 2010 CFR

    2010-01-01

    ... facilities for economic development at less than fair market value? 770.8 Section 770.8 Energy DEPARTMENT OF ENERGY TRANSFER OF REAL PROPERTY AT DEFENSE NUCLEAR FACILITIES FOR ECONOMIC DEVELOPMENT § 770.8 May DOE transfer real property at defense nuclear facilities for economic development at less than fair market...

  9. 10 CFR 770.7 - What procedures are to be used to transfer real property at defense nuclear facilities for...

    Code of Federal Regulations, 2011 CFR

    2011-01-01

    ... 10 Energy 4 2011-01-01 2011-01-01 false What procedures are to be used to transfer real property at defense nuclear facilities for economic development? 770.7 Section 770.7 Energy DEPARTMENT OF ENERGY TRANSFER OF REAL PROPERTY AT DEFENSE NUCLEAR FACILITIES FOR ECONOMIC DEVELOPMENT § 770.7 What...

  10. 10 CFR 770.8 - May DOE transfer real property at defense nuclear facilities for economic development at less...

    Code of Federal Regulations, 2011 CFR

    2011-01-01

    ... 10 Energy 4 2011-01-01 2011-01-01 false May DOE transfer real property at defense nuclear facilities for economic development at less than fair market value? 770.8 Section 770.8 Energy DEPARTMENT OF ENERGY TRANSFER OF REAL PROPERTY AT DEFENSE NUCLEAR FACILITIES FOR ECONOMIC DEVELOPMENT § 770.8 May DOE...

  11. Development of property-transfer models for estimating the hydraulic properties of deep sediments at the Idaho National Engineering and Environmental Laboratory, Idaho

    USGS Publications Warehouse

    Winfield, Kari A.

    2005-01-01

    Because characterizing the unsaturated hydraulic properties of sediments over large areas or depths is costly and time consuming, development of models that predict these properties from more easily measured bulk-physical properties is desirable. At the Idaho National Engineering and Environmental Laboratory, the unsaturated zone is composed of thick basalt flow sequences interbedded with thinner sedimentary layers. Determining the unsaturated hydraulic properties of sedimentary layers is one step in understanding water flow and solute transport processes through this complex unsaturated system. Multiple linear regression was used to construct simple property-transfer models for estimating the water-retention curve and saturated hydraulic conductivity of deep sediments at the Idaho National Engineering and Environmental Laboratory. The regression models were developed from 109 core sample subsets with laboratory measurements of hydraulic and bulk-physical properties. The core samples were collected at depths of 9 to 175 meters at two facilities within the southwestern portion of the Idaho National Engineering and Environmental Laboratory-the Radioactive Waste Management Complex, and the Vadose Zone Research Park southwest of the Idaho Nuclear Technology and Engineering Center. Four regression models were developed using bulk-physical property measurements (bulk density, particle density, and particle size) as the potential explanatory variables. Three representations of the particle-size distribution were compared: (1) textural-class percentages (gravel, sand, silt, and clay), (2) geometric statistics (mean and standard deviation), and (3) graphical statistics (median and uniformity coefficient). The four response variables, estimated from linear combinations of the bulk-physical properties, included saturated hydraulic conductivity and three parameters that define the water-retention curve. For each core sample,values of each water-retention parameter were estimated from the appropriate regression equation and used to calculate an estimated water-retention curve. The degree to which the estimated curve approximated the measured curve was quantified using a goodness-of-fit indicator, the root-mean-square error. Comparison of the root-mean-square-error distributions for each alternative particle-size model showed that the estimated water-retention curves were insensitive to the way the particle-size distribution was represented. Bulk density, the median particle diameter, and the uniformity coefficient were chosen as input parameters for the final models. The property-transfer models developed in this study allow easy determination of hydraulic properties without need for their direct measurement. Additionally, the models provide the basis for development of theoretical models that rely on physical relationships between the pore-size distribution and the bulk-physical properties of the media. With this adaptation, the property-transfer models should have greater application throughout the Idaho National Engineering and Environmental Laboratory and other geographic locations.

  12. Redox control of ferrocene-based complexes with systematically extended π-conjugated connectors: switchable and tailorable second order nonlinear optics.

    PubMed

    Wang, Wen-Yong; Ma, Na-Na; Sun, Shi-Ling; Qiu, Yong-Qing

    2014-03-14

    The studies of geometrical structures, thermal stabilities, redox properties, nonlinear responses and optoelectronic properties have been carried out on a series of novel ferrocenyl (Fc) chromophores with the view of assessing their switchable and tailorable second order nonlinear optics (NLO). The use of a constant Fc donor and a 4,4'-bipyridinium acceptor and varied conjugated bridges makes it possible to systematically determine the contribution of organic connectors to chromophore nonlinear optical activities. The structures reveal that both the reduction reactions and organic connectors have a significant influence on 4,4'-bipyridinium. The potential energy surface maps along with plots of reduced density gradient mirror the thermal stabilities of the Fc-based chromophores. The first and second reductions take place preferentially at the 4,4'-bipyridinium moieties. Significantly, the reduction processes result in the molecular switches with large NLO contrast varying from zero or very small to a large value. Moreover, time-dependent density functional theory results indicate that the absorption peaks are mainly attributed to Fc to 4,4'-bipyridinium charge transfer and the mixture of intramolecular charge transfer within the two respective 4,4'-bipyridinium moieties coupled with interlayer charge transfer between the two 4,4'-bipyridinium moieties. This provides us with comprehensive information on the effect of organic connectors on the NLO properties.

  13. Low tritium partial pressure permeation system for mass transport measurement in lead lithium eutectic

    DOE PAGES

    Pawelko, R. J.; Shimada, M.; Katayama, K.; ...

    2015-11-28

    This paper describes a new experimental system designed to investigate tritium mass transfer properties in materials important to fusion technology. Experimental activities were carried out at the Safety and Tritium Applied Research (STAR) facility located at the Idaho National Laboratory (INL). The tritium permeation measurement system was developed as part of the Japan/US TITAN collaboration to investigate tritium mass transfer properties in liquid lead lithium eutectic (LLE) alloy. The experimental system is configured to measure tritium mass transfer properties at low tritium partial pressures. Initial tritium permeation scoping tests were conducted on a 1 mm thick α-Fe plate to determinemore » operating parameters and to validate the experimental technique. A second series of permeation tests was then conducted with the α-Fe plate covered with an approximately 8.5 mm layer of liquid lead lithium eutectic alloy (α-Fe/LLE). We present preliminary tritium permeation data for α-Fe and α-Fe/LLE at temperatures between 400 and 600°C and at tritium partial pressures between 1.7E-3 and 2.5 Pa in helium. Preliminary results for the α-Fe plate and α-Fe/LLE indicate that the data spans a transition region between the diffusion-limited regime and the surface-limited regime. In conclusion, additional data is required to determine the existence and range of a surface-limited regime.« less

  14. Interactive effects in transfer-appropriate processing for event-based prospective memory: the roles of effort, ongoing task, and PM cue properties.

    PubMed

    Abney, Drew H; McBride, Dawn M; Petrella, Samantha N

    2013-10-01

    Past studies (e.g., Marsh, Hicks, & Cook Journal of Experimental Psychology: Learning, Memory, and Cognition 31:68-75, 2005; Meiser & Schult European Journal of Cognitive Psychology 20:290-311, 2008) have shown that transfer-appropriate processing (TAP) effects in event-based prospective memory (PM) depend on the effort directed toward the ongoing task. In the present study, we addressed mixed findings from these studies and examined monitoring in TAP and transfer-inappropriate processing (TIP) conditions. In two experiments, a semantic or orthographic ongoing task was paired with a PM cue that either was matched in processing (TAP) or did not match in processing (TIP). Within each condition, effort was varied across trials. The results indicated that PM accuracy was higher in TAP than in TIP conditions, regardless of effort condition, supporting the findings reported by Meiser and Schult. Ex-Gaussian functions were fit to the mean reaction times (cf. Brewer Journal of Psychology 219:117-124, 2011) in order to examine monitoring across conditions. The analysis of distributional skew (τ parameter) showed sensitivity to ongoing task instructions and properties of the PM cues. These results support Meiser and Schult's suggestion that TIP conditions require more attentional processing, and they also afford novel discussion on the interactive effects of ongoing task condition, PM cue properties, and manipulations of effort.

  15. 43 CFR 4110.2-3 - Transfer of grazing preference.

    Code of Federal Regulations, 2012 CFR

    2012-10-01

    ... property and the grazing preference, in animal unit months, attached to that base property. (c) If a... the transfer. (e) If an unqualified transferee acquires rights in base property through operation of...

  16. 43 CFR 4110.2-3 - Transfer of grazing preference.

    Code of Federal Regulations, 2013 CFR

    2013-10-01

    ... property and the grazing preference, in animal unit months, attached to that base property. (c) If a... the transfer. (e) If an unqualified transferee acquires rights in base property through operation of...

  17. 41 CFR 302-3.205 - If my transfer is involuntary (due to i.e., reduction in force, cessation, or transfer of work...

    Code of Federal Regulations, 2011 CFR

    2011-07-01

    ... 41 Public Contracts and Property Management 4 2011-07-01 2011-07-01 false If my transfer is... interest of the Government? 302-3.205 Section 302-3.205 Public Contracts and Property Management Federal... TYPE Types of Transfers Reduction in Force Relocation § 302-3.205 If my transfer is involuntary (due to...

  18. 41 CFR 302-3.205 - If my transfer is involuntary (due to i.e., reduction in force, cessation, or transfer of work...

    Code of Federal Regulations, 2013 CFR

    2013-07-01

    ... 41 Public Contracts and Property Management 4 2013-07-01 2012-07-01 true If my transfer is... interest of the Government? 302-3.205 Section 302-3.205 Public Contracts and Property Management Federal... TYPE Types of Transfers Reduction in Force Relocation § 302-3.205 If my transfer is involuntary (due to...

  19. 41 CFR 302-3.205 - If my transfer is involuntary (due to i.e., reduction in force, cessation, or transfer of work...

    Code of Federal Regulations, 2014 CFR

    2014-07-01

    ... 41 Public Contracts and Property Management 4 2014-07-01 2014-07-01 false If my transfer is... interest of the Government? 302-3.205 Section 302-3.205 Public Contracts and Property Management Federal... TYPE Types of Transfers Reduction in Force Relocation § 302-3.205 If my transfer is involuntary (due to...

  20. 41 CFR 302-3.205 - If my transfer is involuntary (due to i.e., reduction in force, cessation, or transfer of work...

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... 41 Public Contracts and Property Management 4 2010-07-01 2010-07-01 false If my transfer is... interest of the Government? 302-3.205 Section 302-3.205 Public Contracts and Property Management Federal... TYPE Types of Transfers Reduction in Force Relocation § 302-3.205 If my transfer is involuntary (due to...

  1. 41 CFR 302-3.205 - If my transfer is involuntary (due to i.e., reduction in force, cessation, or transfer of work...

    Code of Federal Regulations, 2012 CFR

    2012-07-01

    ... 41 Public Contracts and Property Management 4 2012-07-01 2012-07-01 false If my transfer is... interest of the Government? 302-3.205 Section 302-3.205 Public Contracts and Property Management Federal... TYPE Types of Transfers Reduction in Force Relocation § 302-3.205 If my transfer is involuntary (due to...

  2. 26 CFR 26.2663-2 - Application of chapter 13 to transfers by nonresidents not citizens of the United States.

    Code of Federal Regulations, 2012 CFR

    2012-04-01

    ... SERVICE, DEPARTMENT OF THE TREASURY (CONTINUED) ESTATE AND GIFT TAXES GENERATION-SKIPPING TRANSFER TAX... generation-skipping trust. Of the property transferred to the trust, property having a value of $200 is... exemption to the trust on a timely filed United States Gift (and Generation-Skipping Transfer) Tax Return...

  3. 26 CFR 26.2663-2 - Application of chapter 13 to transfers by nonresidents not citizens of the United States.

    Code of Federal Regulations, 2013 CFR

    2013-04-01

    ... SERVICE, DEPARTMENT OF THE TREASURY (CONTINUED) ESTATE AND GIFT TAXES GENERATION-SKIPPING TRANSFER TAX... generation-skipping trust. Of the property transferred to the trust, property having a value of $200 is... exemption to the trust on a timely filed United States Gift (and Generation-Skipping Transfer) Tax Return...

  4. 26 CFR 26.2663-2 - Application of chapter 13 to transfers by nonresidents not citizens of the United States.

    Code of Federal Regulations, 2014 CFR

    2014-04-01

    ... SERVICE, DEPARTMENT OF THE TREASURY (CONTINUED) ESTATE AND GIFT TAXES GENERATION-SKIPPING TRANSFER TAX... generation-skipping trust. Of the property transferred to the trust, property having a value of $200 is... exemption to the trust on a timely filed United States Gift (and Generation-Skipping Transfer) Tax Return...

  5. 26 CFR 26.2663-2 - Application of chapter 13 to transfers by nonresidents not citizens of the United States.

    Code of Federal Regulations, 2011 CFR

    2011-04-01

    ... SERVICE, DEPARTMENT OF THE TREASURY (CONTINUED) ESTATE AND GIFT TAXES GENERATION-SKIPPING TRANSFER TAX... generation-skipping trust. Of the property transferred to the trust, property having a value of $200 is... exemption to the trust on a timely filed United States Gift (and Generation-Skipping Transfer) Tax Return...

  6. 41 CFR 302-3.101 - As a transferred employee what relocation allowances must my agency pay or reimburse to me?

    Code of Federal Regulations, 2013 CFR

    2013-07-01

    ... 41 Public Contracts and Property Management 4 2013-07-01 2012-07-01 true As a transferred employee... Contracts and Property Management Federal Travel Regulation System RELOCATION ALLOWANCES RELOCATION ALLOWANCES 3-RELOCATION ALLOWANCE BY SPECIFIC TYPE Transferred Employees § 302-3.101 As a transferred...

  7. 36 CFR 1233.16 - How does an agency transfer records to the National Personnel Records Center (NPRC)?

    Code of Federal Regulations, 2011 CFR

    2011-07-01

    ... employee medical folder (EMF) to the NPRC at the same time. (2) Transfer EMFs and OPFs in separate folders... 36 Parks, Forests, and Public Property 3 2011-07-01 2011-07-01 false How does an agency transfer... Public Property NATIONAL ARCHIVES AND RECORDS ADMINISTRATION RECORDS MANAGEMENT TRANSFER, USE, AND...

  8. 41 CFR 102-75.740 - Does the State agency have any responsibilities in helping to accomplish the transfer of the...

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... 41 Public Contracts and Property Management 3 2010-07-01 2010-07-01 false Does the State agency have any responsibilities in helping to accomplish the transfer of the property? 102-75.740 Section 102... helping to accomplish the transfer of the property? Yes, the State agency is required to bear the costs of...

  9. 41 CFR 102-75.740 - Does the State agency have any responsibilities in helping to accomplish the transfer of the...

    Code of Federal Regulations, 2011 CFR

    2011-01-01

    ... 41 Public Contracts and Property Management 3 2011-01-01 2011-01-01 false Does the State agency have any responsibilities in helping to accomplish the transfer of the property? 102-75.740 Section 102... helping to accomplish the transfer of the property? Yes, the State agency is required to bear the costs of...

  10. 26 CFR 1.1015-2 - Transfer of property in trust after December 31, 1920.

    Code of Federal Regulations, 2010 CFR

    2010-04-01

    ... 26 Internal Revenue 11 2010-04-01 2010-04-01 true Transfer of property in trust after December 31, 1920. 1.1015-2 Section 1.1015-2 Internal Revenue INTERNAL REVENUE SERVICE, DEPARTMENT OF THE TREASURY (CONTINUED) INCOME TAX (CONTINUED) INCOME TAXES Basis Rules of General Application § 1.1015-2 Transfer of property in trust after December 31, 192...

  11. 41 CFR 109-26.501-53 - Acquisitions by transfer.

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... 41 Public Contracts and Property Management 3 2010-07-01 2010-07-01 false Acquisitions by transfer. 109-26.501-53 Section 109-26.501-53 Public Contracts and Property Management Federal Property Management Regulations System (Continued) DEPARTMENT OF ENERGY PROPERTY MANAGEMENT REGULATIONS SUPPLY AND...

  12. Novel models on fluid's variable thermo-physical properties for extensive study on convection heat and mass transfer

    NASA Astrophysics Data System (ADS)

    Shang, De-Yi; Zhong, Liang-Cai

    2017-01-01

    Our novel models for fluid's variable physical properties are improved and reported systematically in this work for enhancement of theoretical and practical value on study of convection heat and mass transfer. It consists of three models, namely (1) temperature parameter model, (2) polynomial model, and (3) weighted-sum model, respectively for treatment of temperature-dependent physical properties of gases, temperature-dependent physical properties of liquids, and concentration- and temperature-dependent physical properties of vapour-gas mixture. Two related components are proposed, and involved in each model for fluid's variable physical properties. They are basic physic property equations and theoretical similarity equations on physical property factors. The former, as the foundation of the latter, is based on the typical experimental data and physical analysis. The latter is built up by similarity analysis and mathematical derivation based on the former basic physical properties equations. These models are available for smooth simulation and treatment of fluid's variable physical properties for assurance of theoretical and practical value of study on convection of heat and mass transfer. Especially, so far, there has been lack of available study on heat and mass transfer of film condensation convection of vapour-gas mixture, and the wrong heat transfer results existed in widespread studies on the related research topics, due to ignorance of proper consideration of the concentration- and temperature-dependent physical properties of vapour-gas mixture. For resolving such difficult issues, the present novel physical property models have their special advantages.

  13. Mass Transfer Cooling Near The Stagnation Point

    NASA Technical Reports Server (NTRS)

    Roberts, Leonard

    1959-01-01

    A simplified analysis is made of mass transfer cooling, that is, injection of a foreign gas, near the stagnation point for two-dimensional and axisymmetric bodies. The reduction in heat transfer is given in terms of the properties of the coolant gas and it is shown that the heat transfer may be reduced considerably by the introduction of a gas having appropriate thermal and diffusive properties. The mechanism by which heat transfer is reduced is discussed.

  14. Disk brake design for cooling improvement using Computational Fluid Dynamics (CFD)

    NASA Astrophysics Data System (ADS)

    Munisamy, Kannan M.; Shafik, Ramel

    2013-06-01

    The car disk brake design is improved with two different blade designs compared to the baseline blade design. The two designs were simulated in Computational fluid dynamics (CFD) to obtain heat transfer properties such as Nusselt number and Heat transfer coefficient. The heat transfer property is compared against the baseline design. The improved shape has the highest heat transfer performance. The curved design is inferior to baseline design in heat transfer performance.

  15. Analysis on energy transfer process of Ho3+ doped fluoroaluminate glass sensitized by Yb3+ for mid-infrared 2.85 μm emission

    NASA Astrophysics Data System (ADS)

    Zhou, Beier; Wei, Tao; Cai, Muzhi; Tian, Ying; Zhou, Jiajia; Deng, Degang; Xu, Shiqing; Zhang, Junjie

    2014-12-01

    This work reports the mid-infrared emission properties around 2.85 μm in a Yb3+/Ho3+ codoped fluoroaluminate glass. This fluoroaluminate glass shows a good thermal stability and high transmittance around 3 μm. The mid-infrared emission characteristics and energy transfer mechanism upon the excitation of the conventional 980 nm laser diode have been investigated. The prepared glass possesses higher spontaneous transition probability (31.77 s-1) along with the larger calculated emission cross section (1.91×10-20 cm2) corresponding to the laser transition of Ho3+:5I6→5I7. Besides, the upconversion, 1.2 μm and 2 μm fluorescence spectra were measured to understand mid-infrared emission behavior together with decay curves of Ho3+:5I6 level. Moreover, energy transfer microparameters between Yb3+ and Ho3+ were calculated and discussed based on Dexter's model. Hence, the advantageous spectroscopic characteristics of Yb3+/Ho3+ codoped fluoroaluminate glass as well as the good thermal property indicate that this kind of glass is an attractive host for developing mid-infrared solid state laser.

  16. Measuring Economic Freedom: Better Without Size of Government.

    PubMed

    Ott, Jan

    2018-01-01

    The Heritage Foundation and the Fraser Institute measure economic freedom in nations using indices with ten and five indicators respectively. Eight of the Heritage indicators and four of the Fraser-indicators are about specific types of institutional quality, like rule of law, the protection of property, and the provision of sound money. More of these is considered to denote more economic freedom. Both indices also involve indicators of 'big government', or levels of government activities. More of that is seen to denote less economic freedom. Yet, levels of government spending, consumption, and transfers and subsidies appear to correlate positively with the other indicators related to institutional quality, while this correlation is close to zero for the level of taxation as a percentage of GDP. Using government spending, consumption transfers and subsidies as positive indicators is no alternative, because these levels stand for very different government activities, liberal or less liberal. This means that levels of government activities can better be left out as negative or positive indicators. Thus shortened variants of the indices create a better convergent validity in the measurement of economic freedom, and create higher correlations between economic freedom and alternative types of freedom, and between economic freedom and happiness. The higher correlations indicate a better predictive validity, since they are predictable in view of the findings of previous research and theoretical considerations about the relations between types of freedom, and between freedom and happiness.

  17. State of the Art of Current Practices for Transit Transfers.

    DOT National Transportation Integrated Search

    1981-07-01

    The major objectives of the study are to: (1) describe and summarize the transfer policies currently in use on U.S. transit properties; (2) identify reasons why properties use or do not use particular transfer policies; (3) determine the consequences...

  18. Information Transfer Capacity of Articulators in American Sign Language.

    PubMed

    Malaia, Evie; Borneman, Joshua D; Wilbur, Ronnie B

    2018-03-01

    The ability to convey information is a fundamental property of communicative signals. For sign languages, which are overtly produced with multiple, completely visible articulators, the question arises as to how the various channels co-ordinate and interact with each other. We analyze motion capture data of American Sign Language (ASL) narratives, and show that the capacity of information throughput, mathematically defined, is highest on the dominant hand (DH). We further demonstrate that information transfer capacity is also significant for the non-dominant hand (NDH), and the head channel too, as compared to control channels (ankles). We discuss both redundancy and independence in articulator motion in sign language, and argue that the NDH and the head articulators contribute to the overall information transfer capacity, indicating that they are neither completely redundant to, nor completely independent of, the DH.

  19. New methodology for the heat flow prediction for different construction materials

    NASA Astrophysics Data System (ADS)

    Benachour, Elhadj; Draoui, Belkacem; Imine, Bachir; Asnoune, Khadidja; Boumediene, Allaoua; Mebarki, Brahim

    2018-06-01

    Among the ways of energy transfer by conduction is that of molecular interaction, in which the greater motion of a molecule at a higher energy level (temperature) imparts energy to adjacent molecules at lower energy levels. This type of transfer is present, to some degree, in all systems in which a temperature gradient exists and in which molecules of a solid, liquid, or gas are present. So, in heat transfer, the thermal conductivity of a substance is an intensive property that indicates its ability to conduct heat In particular in the building sector. The thermal flux is often measured with a mathematical analysis but for the same material, on the other hand the estimate will be disruptive and sometimes very difficult when the material changes. In this paper, a single equation for predicting heat flux of different materials is given.

  20. FILM-30: A Heat Transfer Properties Code for Water Coolant

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    MARSHALL, THERON D.

    2001-02-01

    A FORTRAN computer code has been written to calculate the heat transfer properties at the wetted perimeter of a coolant channel when provided the bulk water conditions. This computer code is titled FILM-30 and the code calculates its heat transfer properties by using the following correlations: (1) Sieder-Tate: forced convection, (2) Bergles-Rohsenow: onset to nucleate boiling, (3) Bergles-Rohsenow: partially developed nucleate boiling, (4) Araki: fully developed nucleate boiling, (5) Tong-75: critical heat flux (CHF), and (6) Marshall-98: transition boiling. FILM-30 produces output files that provide the heat flux and heat transfer coefficient at the wetted perimeter as a function ofmore » temperature. To validate FILM-30, the calculated heat transfer properties were used in finite element analyses to predict internal temperatures for a water-cooled copper mockup under one-sided heating from a rastered electron beam. These predicted temperatures were compared with the measured temperatures from the author's 1994 and 1998 heat transfer experiments. There was excellent agreement between the predicted and experimentally measured temperatures, which confirmed the accuracy of FILM-30 within the experimental range of the tests. FILM-30 can accurately predict the CHF and transition boiling regimes, which is an important advantage over current heat transfer codes. Consequently, FILM-30 is ideal for predicting heat transfer properties for applications that feature high heat fluxes produced by one-sided heating.« less

  1. 41 CFR 109-48.101-6 - Transfer to other Federal agencies.

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... 41 Public Contracts and Property Management 3 2010-07-01 2010-07-01 false Transfer to other Federal agencies. 109-48.101-6 Section 109-48.101-6 Public Contracts and Property Management Federal Property Management Regulations System (Continued) DEPARTMENT OF ENERGY PROPERTY MANAGEMENT REGULATIONS...

  2. 41 CFR 109-48.101-6 - Transfer to other Federal agencies.

    Code of Federal Regulations, 2011 CFR

    2011-01-01

    ... 41 Public Contracts and Property Management 3 2011-01-01 2011-01-01 false Transfer to other Federal agencies. 109-48.101-6 Section 109-48.101-6 Public Contracts and Property Management Federal Property Management Regulations System (Continued) DEPARTMENT OF ENERGY PROPERTY MANAGEMENT REGULATIONS...

  3. 41 CFR 101-27.303-1 - Cancellation or transfer.

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... 41 Public Contracts and Property Management 2 2010-07-01 2010-07-01 true Cancellation or transfer. 101-27.303-1 Section 101-27.303-1 Public Contracts and Property Management Federal Property Management Regulations System FEDERAL PROPERTY MANAGEMENT REGULATIONS SUPPLY AND PROCUREMENT 27-INVENTORY MANAGEMENT 27.3...

  4. 76 FR 28188 - Office of Procurement and Property Management; Guidelines for the Transfer of Excess Computers or...

    Federal Register 2010, 2011, 2012, 2013, 2014

    2011-05-16

    ... general, to provide the public the option of submitting information or transacting business electronically... Office of Procurement and Property Management; Guidelines for the Transfer of Excess Computers or Other... Property Management, USDA. ACTION: Proposed rule. SUMMARY: The Office of Procurement and Property...

  5. Scientific charge-coupled devices

    NASA Technical Reports Server (NTRS)

    Janesick, James R.; Elliott, Tom; Collins, Stewart; Blouke, Morley M.; Freeman, Jack

    1987-01-01

    The charge-coupled device dominates an ever-increasing variety of scientific imaging and spectroscopy applications. Recent experience indicates, however, that the full potential of CCD performance lies well beyond that realized in devices currently available.Test data suggest that major improvements are feasible in spectral response, charge collection, charge transfer, and readout noise. These properties, their measurement in existing CCDs, and their potential for future improvement are discussed in this paper.

  6. Energy transfer and kinetics in mechanochemistry.

    PubMed

    Chen, Zhiliang; Lu, Shengyong; Mao, Qiongjing; Buekens, Alfons; Wang, Yuting; Yan, Jianhua

    2017-11-01

    Mechanochemistry (MC) exerts extraordinary degradation and decomposition effects on many chlorinated, brominated, and even fluorinated persistent organic pollutants (POPs). However, its application is still limited by inadequate study of its reaction kinetic aspects. In the present work, the ball motion and energy transfer in planetary ball mill are investigated in some detail. Almost all milling parameters are summarised in a single factor-total effective impact energy. Furthermore, the MC kinetic between calcium oxide/Al and hexachlorobenzene is well established and modelled. The results indicate that total effective impact energy and reagent ratio are the two factors sufficient for describing the MC degradation degree of POPs. The reaction rate constant only depends on the chemical properties of reactants, so it could be used as an important index to appraise the quality of MC additives. This model successfully predicts the reaction rate for different operating conditions, indicating that it could be suitably applied for conducting MC reactions in other reactors.

  7. A critical examination of the validity of simplified models for radiant heat transfer analysis.

    NASA Technical Reports Server (NTRS)

    Toor, J. S.; Viskanta, R.

    1972-01-01

    Examination of the directional effects of the simplified models by comparing the experimental data with the predictions based on simple and more detailed models for the radiation characteristics of surfaces. Analytical results indicate that the constant property diffuse and specular models do not yield the upper and lower bounds on local radiant heat flux. In general, the constant property specular analysis yields higher values of irradiation than the constant property diffuse analysis. A diffuse surface in the enclosure appears to destroy the effect of specularity of the other surfaces. Semigray and gray analyses predict the irradiation reasonably well provided that the directional properties and the specularity of the surfaces are taken into account. The uniform and nonuniform radiosity diffuse models are in satisfactory agreement with each other.

  8. Energy transfer mechanism and optoelectronic properties of (PFO/TiO2)/Fluorol 7GA nanocomposite thin films

    NASA Astrophysics Data System (ADS)

    Al-Asbahi, Bandar Ali

    2017-10-01

    Energy transfer between poly (9,9'-di-n-octylfluorenyl-2,7-diyl) (PFO) as a donor in presence of TiO2 nanoparticles (NPs) and Fluorol 7GA as an acceptor with different weight ratios has been investigated by steady-state emission measurements. Based on the absorption and fluorescence measurements, the energy transfer properties, such as quenching rate constant (kSV), energy transfer rate constant (kET), quantum yield (ϕDA), and lifetime (τDA), of the donor in the presence of the acceptor, energy transfer probability (PDA), energy transfer efficiency (η), energy transfer time (τET), and critical distance of the energy transfer (Ro) were calculated. Förster-type energy transfer between the excited donor and ground-state acceptor molecules was the dominant mechanism responsible for the energy transfer as evidenced by large values of kSV, kET, and Ro. Moreover, these composite materials were employed as an emissive layer in organic light-emitting diodes (OLEDs). Additionally, the optoelectronic properties of OLEDs were investigated in terms of current density-voltage characteristics and electroluminescence spectra.

  9. Excitation Energy Transfer by Coherent and Incoherent Mechanisms in the Peridinin-Chlorophyll a Protein.

    PubMed

    Ghosh, Soumen; Bishop, Michael M; Roscioli, Jerome D; LaFountain, Amy M; Frank, Harry A; Beck, Warren F

    2017-01-19

    Excitation energy transfer from peridinin to chlorophyll (Chl) a is unusually efficient in the peridinin-chlorophyll a protein (PCP) from dinoflagellates. This enhanced performance is derived from the long intrinsic lifetime of 4.4 ps for the S 2 (1 1 B u + ) state of peridinin in PCP, which arises from the electron-withdrawing properties of its carbonyl substituent. Results from heterodyne transient grating spectroscopy indicate that S 2 serves as the donor for two channels of energy transfer: a 30 fs process involving quantum coherence and delocalized peridinin-Chl states and an incoherent, 2.5 ps process initiated by dynamic exciton localization, which accompanies the formation of a conformationally distorted intermediate in 45 fs. The lifetime of the S 2 state is lengthened in PCP by its intramolecular charge-transfer character, which increases the system-bath coupling and slows the torsional motions that promote nonradiative decay to the S 1 (2 1 A g - ) state.

  10. Monte Carlo Study on Carbon-Gradient-Doped Silica Aerogel Insulation.

    PubMed

    Zhao, Y; Tang, G H

    2015-04-01

    Silica aerogel is almost transparent for wavelengths below 8 µm where significant energy is transferred by thermal radiation. The radiative heat transfer can be restricted at high temperature if doped with carbon powder in silica aerogel. However, different particle sizes of carbon powder doping have different spectral extinction coefficients and the doped carbon powder will increase the solid conduction of silica aerogel. This paper presents a theoretical method for determining the optimal carbon doping in silica aerogel to minimize the energy transfer. Firstly we determine the optimal particle size by combining the spectral extinction coefficient with blackbody radiation and then evaluate the optimal doping amount between heat conduction and radiation. Secondly we develop the Monte Carlo numerical method to study radiative properties of carbon-gradient-doped silica aerogel to decrease the radiative heat transfer further. The results indicate that the carbon powder is able to block infrared radiation and thus improve the thermal insulating performance of silica aerogel effectively.

  11. Modeling of the Inter-phase Mass Transfer during Cosolvent-Enhanced NAPL Remediation

    NASA Astrophysics Data System (ADS)

    Agaoglu, B.; Scheytt, T. J.; Copty, N. K.

    2012-12-01

    This study investigates the factors influencing inter-phase mass transfer during cosolvent-enhanced NAPL remediation and the ability of the REV (Representative Elementary Volume) modeling approach to simulate these processes. The NAPLs considered in this study consist of pure toluene, pure benzene and known mixtures of these two compounds, while ethanol-water mixtures were selected as the remedial flushing solutions. Batch tests were performed to identify both the equilibrium and non-equilibrium properties of the multiphase system. A series of column flushing experiments involving different NAPLs were conducted for different ethanol contents in the flushing solution and for different operational parameters. Experimental results were compared to numerical simulations obtained with the UTCHEM multiphase flow simulator (Delshad et al., 1996). Results indicate that the velocity of the flushing solution is a major parameter influencing the inter-phase mass transport processes at the pore scale. Depending on the NAPL composition and porous medium properties, the remedial solution may follow preferential flow paths and be subject to reduced contact with the NAPL. This leads to a steep decrease in the apparent mass transfer coefficient. Correlations of the apparent time-dependent mass transfer coefficient as a function of flushing velocity are developed for various porous media. Experimental results also show that the NAPL mass transfer coefficient into the cosolvent solution increases when the NAPL phase becomes mobile. This is attributed to the increase in pore scale contact area between NAPL and the remedial solution when NAPL mobilization occurs. These results suggest the need to define a temporal and spatially variable mass transfer coefficient of the NAPL into the cosolvent solution to reflect the occurrence of subscale preferential flow paths and the transient bypassing of the NAPL mass. The implications of these findings on field scale NAPL remediation with cosolvents are discussed.

  12. Virulence properties of multidrug resistant ocular isolates of Acinetobacter baumannii.

    PubMed

    Talreja, Deepa; Muraleedharan, Chithra; Gunathilaka, Gayathri; Zhang, Yifan; Kaye, Keith S; Walia, Satish K; Kumar, Ashok

    2014-07-01

    Acinetobacter (A.) baumannii is an opportunistic pathogen and has been reported as a causative agent of ocular infections. The aim of this study is to identify virulence properties (biofilm formation, adhesion, invasion and cytotoxicity) and antibiotic resistance among A. baumannii isolates recovered from the eye. The Microscan Walk-Away®, an automated bacterial identification and susceptibility testing system was used to determine antibiotic resistance. Clonal relatedness was assessed by Pulsed-field gel electrophoresis (PFGE) and plasmid profile analysis. Conjugation experiments were carried out to determine the transfer of antibiotic resistance genes and PCR was used to confirm gene transfer. Virulence properties of the isolates were determined by biofilm formation using crystal violet and immunofluorescence staining, adherence and internalization using cultured corneal epithelial cells, and cytotoxicity by TUNEL-staining and LDH release assays. All ocular isolates (n = 12) exhibited multidrug resistant (MDR) phenotype and one of the isolate (AB12) was resistant to 18 antibiotics (β-lactam, aminoglycosides, tetracycline, chloramphenicol and quinolones). The plasmid profile analysis showed the presence of multiple plasmids in each isolate and a total of 10 different profiles were observed. However, PFGE analysis was more discriminatory which revealed 12 distinct genotypes. Antibiotic resistance (tetracycline and quinolone) was transferable from the isolate AB12 to a recipient Escherichia coli J53. Ten isolates were strong biofilm producers and the remaining two (AB5 and AB7) were moderate producers. All isolates demonstrated adherence and invasive properties towards HCECs. A similar trend was observed in their ability to cause cell death and toxicity. Our results indicate that ocular isolates of A. baumannii are biofilm producers and adherent and invasive to corneal epithelium, a first step in the pathogenesis of ocular infection. In addition, they demonstrated plasmid-mediated transfer of MDR traits making them a reservoir of resistance genes at ocular surface.

  13. Oxygen ion transference number of doped lanthanum gallate

    NASA Astrophysics Data System (ADS)

    Wang, Shizhong; Wu, Lingli; Gao, Jie; He, Qiong; Liu, Meilin

    The transference numbers for oxygen ion (t O) in several LaGaO 3-based materials are determined from oxygen concentration cells using the materials as the electrolyte, including La 0.8Sr 0.2Ga 0.8Mg 0.2O 3- δ (LSGM8282), La 0.8Sr 0.2Ga 0.8Mg 0.15Co 0.05O 3- δ (LSGMC5) and La 0.8Sr 0.2Ga 0.8Mg 0.115Co 0.085O 3- δ (LSGMC8.5). Analysis indicates that the accuracy in determination of oxygen ion transference number depends on the electrode polarization resistances of the concentration cell as well as the transport properties of the materials studied. For example, the ratio of open cell voltage to Nernst potential is a good approximation to the ionic transference number for LSGM8282. However, this approximation is no longer adequate for LSGMC5 and LSGMC8.5; the effect of electrode polarization resistances must be taken into consideration in estimation of the ionic transference numbers. In particular, the ionic transference number for LSGMC5 is as high as 0.99, suggesting that it is a promising electrolyte material for low-temperature solid-state electrochemical applications.

  14. NASA Intellectual Property Negotiation Practices and their Relationship to Quantitative Measures of Technology Transfer

    NASA Technical Reports Server (NTRS)

    Bush, Lance B.

    1997-01-01

    In the current political climate NASA must be able to show reliable measures demonstrating successful technology transfer. The currently available quantitative data of intellectual property technology transfer efforts portray a less than successful performance. In this paper, the use of only quantitative values for measurement of technology transfer is shown to undervalue the effort. In addition, NASA's current policy in negotiating intellectual property rights results in undervalued royalty rates. NASA has maintained that it's position of providing public good precludes it from negotiating fair market value for its technology and instead has negotiated for reasonable cost in order to recover processing fees. This measurement issue is examined and recommendations made which include a new policy regarding the intellectual property rights negotiation, and two measures to supplement the intellectual property measures.

  15. 41 CFR 101-4.120 - Transfers of property.

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... EDUCATION PROGRAMS OR ACTIVITIES RECEIVING FEDERAL FINANCIAL ASSISTANCE Introduction § 101-4.120 Transfers... Federal financial assistance to a transferee that operates any education program or activity, and the Federal share of the fair market value of the property is not upon such sale or transfer properly...

  16. Theoretical Studies on Two-Photon Fluorescent Hg2+ Probes Based on the Coumarin-Rhodamine System.

    PubMed

    Zhang, Yujin; Leng, Jiancai

    2017-07-20

    The development of fluorescent sensors for Hg 2+ has attracted much attention due to the well-known adverse effects of mercury on biological health. In the present work, the optical properties of two newly-synthesized Hg 2+ chemosensors based on the coumarin-rhodamine system (named Pro1 and Pro2) were systematically investigated using time-dependent density functional theory. It is shown that Pro1 and Pro2 are effective ratiometric fluorescent Hg 2+ probes, which recognize Hg 2+ by Förster resonance energy transfer and through bond energy transfer mechanisms, respectively. To further understand the mechanisms of the two probes, we have developed an approach to predict the energy transfer rate between the donor and acceptor. Using this approach, it can be inferred that Pro1 has a six times higher energy transfer rate than Pro2. Thus the influence of spacer group between the donor and acceptor on the sensing performance of the probe is demonstrated. Specifically, two-photon absorption properties of these two probes are calculated. We have found that both probes show significant two-photon responses in the near-infrared light region. However, only the maximum two-photon absorption cross section of Pro1 is greatly enhanced with the presence of Hg 2+ , indicating that Pro1 can act as a potential two-photon excited fluorescent probe for Hg 2+ . The theoretical investigations would be helpful to build a relationship between the structure and the optical properties of the probes, providing information on the design of efficient two-photon fluorescent sensors that can be used for biological imaging of Hg 2+ in vivo.

  17. Color-tunable photoluminescence and energy transfer properties of single-phase Ba{sub 10}(PO{sub 4}){sub 6}O:Eu{sup 2+}, Mn{sup 2+} phosphors

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Guo, Qingfeng; Liao, Libing, E-mail: clayl@cugb.edu.cn; Mei, Lefu, E-mail: mlf@cugb.edu.cn

    2015-12-15

    Single-phase Ba{sub 10−x−y}(PO{sub 4}){sub 6}O:xEu{sup 2+},yMn{sup 2+} samples with apatite structure have been synthesized via a solid-state reaction method. The phase structure, luminescence properties, lifetime, PL thermal stability, as well as fluorescence decay curves of the samples were investigated. Effective energy transfer occurs from Eu{sup 2+} to Mn{sup 2+} in Ba{sub 10}(PO{sub 4}){sub 6}O and a possible mechanism of the energy-transfer from Eu{sup 2+} to Mn{sup 2+} is proposed. The critical distances R{sub c} was calculated by concentration quenching and turned out to be about 0.817 nm (x{sub c}=0.21). The CIE and thermally stable luminescence behaviors of Ba{sub 9.94}(PO{sub 4}){submore » 6}O:0.06Eu{sup 2+} phosphor were also studied in detail. All the results indicate that Ba{sub 10−x−y}(PO{sub 4}){sub 6}O:xEu{sup 2+}, yMn{sup 2+} phosphors have potential applications as near UV-convertible phosphors for white light-emitting diodes. - Graphical abstract: Crystal structure and luminescence property of Ba{sub 10−x−y}(PO{sub 4}){sub 6}O:xEu{sup 2+},yMn{sup 2+} have been discussed. - Highlights: • Ba{sub 10−x−y}(PO{sub 4}){sub 6}O:xEu{sup 2+},yMn{sup 2+} was firstly reported. • Ba{sub 9.94}(PO{sub 4}){sub 6}O:0.06Eu{sup 2+} exhibits high thermal quenching resistance. • The energy transfer between Eu{sup 2+} and Mn{sup 2+} was investigated.« less

  18. 26 CFR 16.3-1 - Returns as to the creation of or transfers to certain foreign trusts.

    Code of Federal Regulations, 2011 CFR

    2011-04-01

    ... United States person who, on or after October 16, 1962, either creates a foreign trust or transfers money... in subparagraph (5) of this paragraph), who transfers money or property to or for the benefit of a foreign trust. It does not refer to a person who transfers money or property to a foreign trust pursuant...

  19. 26 CFR 16.3-1 - Returns as to the creation of or transfers to certain foreign trusts.

    Code of Federal Regulations, 2012 CFR

    2012-04-01

    ... United States person who, on or after October 16, 1962, either creates a foreign trust or transfers money... in subparagraph (5) of this paragraph), who transfers money or property to or for the benefit of a foreign trust. It does not refer to a person who transfers money or property to a foreign trust pursuant...

  20. 26 CFR 16.3-1 - Returns as to the creation of or transfers to certain foreign trusts.

    Code of Federal Regulations, 2014 CFR

    2014-04-01

    ... United States person who, on or after October 16, 1962, either creates a foreign trust or transfers money... in subparagraph (5) of this paragraph), who transfers money or property to or for the benefit of a foreign trust. It does not refer to a person who transfers money or property to a foreign trust pursuant...

  1. 26 CFR 16.3-1 - Returns as to the creation of or transfers to certain foreign trusts.

    Code of Federal Regulations, 2013 CFR

    2013-04-01

    ... United States person who, on or after October 16, 1962, either creates a foreign trust or transfers money... in subparagraph (5) of this paragraph), who transfers money or property to or for the benefit of a foreign trust. It does not refer to a person who transfers money or property to a foreign trust pursuant...

  2. 26 CFR 16.3-1 - Returns as to the creation of or transfers to certain foreign trusts.

    Code of Federal Regulations, 2010 CFR

    2010-04-01

    ... United States person who, on or after October 16, 1962, either creates a foreign trust or transfers money... in subparagraph (5) of this paragraph), who transfers money or property to or for the benefit of a foreign trust. It does not refer to a person who transfers money or property to a foreign trust pursuant...

  3. 26 CFR 1.367(a)-2 - Exception for transfers of property for use in the active conduct of a trade or business.

    Code of Federal Regulations, 2014 CFR

    2014-04-01

    ... 26 Internal Revenue 4 2014-04-01 2014-04-01 false Exception for transfers of property for use in the active conduct of a trade or business. 1.367(a)-2 Section 1.367(a)-2 Internal Revenue INTERNAL...) Effects on Corporation § 1.367(a)-2 Exception for transfers of property for use in the active conduct of a...

  4. The role of the University Licensing Office in transferring intellectual property to industry

    NASA Technical Reports Server (NTRS)

    Preston, John T.

    1992-01-01

    Universities in the US have a significant impact on business through the transfer of technology. This transfer of technology takes various forms, including faculty communications, faculty consulting activities, and the direct transfer of technology through the licensing of patents, copyrights, and other intellectual property to industry. The topics discussed include the following: background of the MIT Technology Licensing Office (TLO), goals of the MIT TLO, MIT's technology transfer philosophy, and important factors for success in new company formation.

  5. 41 CFR 302-3.100 - What is a transferred employee?

    Code of Federal Regulations, 2013 CFR

    2013-07-01

    ... 41 Public Contracts and Property Management 4 2013-07-01 2012-07-01 true What is a transferred employee? 302-3.100 Section 302-3.100 Public Contracts and Property Management Federal Travel Regulation System RELOCATION ALLOWANCES RELOCATION ALLOWANCES 3-RELOCATION ALLOWANCE BY SPECIFIC TYPE Transferred...

  6. 41 CFR 302-3.100 - What is a transferred employee?

    Code of Federal Regulations, 2011 CFR

    2011-07-01

    ... 41 Public Contracts and Property Management 4 2011-07-01 2011-07-01 false What is a transferred employee? 302-3.100 Section 302-3.100 Public Contracts and Property Management Federal Travel Regulation System RELOCATION ALLOWANCES RELOCATION ALLOWANCES 3-RELOCATION ALLOWANCE BY SPECIFIC TYPE Transferred...

  7. 41 CFR 302-3.100 - What is a transferred employee?

    Code of Federal Regulations, 2012 CFR

    2012-07-01

    ... 41 Public Contracts and Property Management 4 2012-07-01 2012-07-01 false What is a transferred employee? 302-3.100 Section 302-3.100 Public Contracts and Property Management Federal Travel Regulation System RELOCATION ALLOWANCES RELOCATION ALLOWANCES 3-RELOCATION ALLOWANCE BY SPECIFIC TYPE Transferred...

  8. 41 CFR 302-3.100 - What is a transferred employee?

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... 41 Public Contracts and Property Management 4 2010-07-01 2010-07-01 false What is a transferred employee? 302-3.100 Section 302-3.100 Public Contracts and Property Management Federal Travel Regulation System RELOCATION ALLOWANCES RELOCATION ALLOWANCES 3-RELOCATION ALLOWANCE BY SPECIFIC TYPE Transferred...

  9. 41 CFR 302-3.100 - What is a transferred employee?

    Code of Federal Regulations, 2014 CFR

    2014-07-01

    ... 41 Public Contracts and Property Management 4 2014-07-01 2014-07-01 false What is a transferred employee? 302-3.100 Section 302-3.100 Public Contracts and Property Management Federal Travel Regulation System RELOCATION ALLOWANCES RELOCATION ALLOWANCES 3-RELOCATION ALLOWANCE BY SPECIFIC TYPE Transferred...

  10. 28 CFR 54.120 - Transfers of property.

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... EDUCATION PROGRAMS OR ACTIVITIES RECEIVING FEDERAL FINANCIAL ASSISTANCE Introduction § 54.120 Transfers of... financial assistance to a transferee that operates any education program or activity, and the Federal share of the fair market value of the property is not upon such sale or transfer properly accounted for to...

  11. 26 CFR 1.482-0 - Outline of regulations under section 482.

    Code of Federal Regulations, 2011 CFR

    2011-04-01

    ... transfer pricing rules for other transactions. (1) Services transactions that include other types of.... (iii) Subleases. (d) Transfer of property. (e) [Reserved] For further guidance, see § 1.482-0T, the... in connection with a transfer of tangible property. (a) In general. (b) Comparable uncontrolled price...

  12. 32 CFR 174.4 - Policy.

    Code of Federal Regulations, 2014 CFR

    2014-07-01

    ... property. Federal law provides the Department with an array of legal authorities, including public benefit... government, conservation conveyances, and public sales, by which to transfer property on closed or realigned... transfer property in a timely manner and provide a foundation for solid economic redevelopment. (e) Speak...

  13. 32 CFR 174.4 - Policy.

    Code of Federal Regulations, 2013 CFR

    2013-07-01

    ... property. Federal law provides the Department with an array of legal authorities, including public benefit... government, conservation conveyances, and public sales, by which to transfer property on closed or realigned... transfer property in a timely manner and provide a foundation for solid economic redevelopment. (e) Speak...

  14. 32 CFR 174.4 - Policy.

    Code of Federal Regulations, 2012 CFR

    2012-07-01

    ... property. Federal law provides the Department with an array of legal authorities, including public benefit... government, conservation conveyances, and public sales, by which to transfer property on closed or realigned... transfer property in a timely manner and provide a foundation for solid economic redevelopment. (e) Speak...

  15. 32 CFR 174.4 - Policy.

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... property. Federal law provides the Department with an array of legal authorities, including public benefit... government, conservation conveyances, and public sales, by which to transfer property on closed or realigned... transfer property in a timely manner and provide a foundation for solid economic redevelopment. (e) Speak...

  16. 32 CFR 174.4 - Policy.

    Code of Federal Regulations, 2011 CFR

    2011-07-01

    ... property. Federal law provides the Department with an array of legal authorities, including public benefit... government, conservation conveyances, and public sales, by which to transfer property on closed or realigned... transfer property in a timely manner and provide a foundation for solid economic redevelopment. (e) Speak...

  17. Friction and wear of iron-base binary alloys in sliding contact with silicon carbide in vacuum

    NASA Technical Reports Server (NTRS)

    Miyoshi, K.; Buckley, D. H.

    1980-01-01

    Multipass sliding friction experiments were conducted with various iron base binary alloys in contact with a single crystal silicon carbide surface in vacuum. Results indicate that the atomic size and concentration of alloy elements play important roles in controlling the transfer and friction properties of iron base binary alloys. Alloys having high solute concentration produce more transfer than do alloys having low solute concentration. The coefficient of friction during multipass sliding generally increases with an increase in the concentration of alloying element. The change of friction with succeeding passes after the initial pass also increases as the solute to iron, atomic radius ratio increases or decreases from unity.

  18. Experimental Investigation of the Thermophysical Properties of TiO2/Propylene Glycol-Water Nanofluids for Heat-Transfer Applications

    NASA Astrophysics Data System (ADS)

    Leena, M.; Srinivasan, S.

    2018-05-01

    Nanofluids have been prepared by dispersing TiO2 nanoparticles in 70:30% (by weight) water-propylene glycol mixture. The thermal conductivity and viscosity were found experimentally at various temperatures with the volume concentrations 0.1-0.8%. The results indicate that the thermal conductivity of the nanofluids increases with the volume concentration and temperature. Similarly, the viscosity of the nanofluids increases with the volume concentration but decreases with increase in the temperature. Correlations have been proposed for estimating the thermal conductivity and viscosity of the nanofluids. The potential heat transfer benefits of their use in laminar and turbulent flow conditions has been explained.

  19. 26 CFR 1.684-1 - Recognition of gain on transfers to certain foreign trusts and estates.

    Code of Federal Regulations, 2010 CFR

    2010-04-01

    ... recognize gain at the time of the transfer equal to the excess of the fair market value of the property... portion of FT. Under paragraph (a)(1) of this section, A recognizes gain at the time of the transfer equal... of 1000X, and property R, with a fair market value of 2000X, to FT. At the time of the transfer, A's...

  20. Complex formation between chlorophyll a and cytochrome c: surface properties at the air-water interface. Absorbance, fluorescence and fluorescence-lifetime in Langmuir-Blodgett films.

    PubMed

    Lamarche, F; Picard, G; Téchy, F; Aghion, J; Leblanc, R M

    1991-04-23

    The binding of cytochrome c to an insoluble monolayer of chlorophyll a was studied. Surface pressure (II), surface potential (delta V) and [14C]cytochrome c surface-concentration (gamma) isotherms were measured versus molecular area (sigma) in mixed films. Compared to the successive-addition method, this procedure allows the formation of homogeneous mixed films. The cytochrome c is incorporated into a chlorophyll a monolayer, compressed at a surface pressure of 20 mN.m-1. On expansion, the quantity of protein incorporated into the monolayer gradually increases. Subsequent compression-expansion cycles result in similar isotherms, distinct from that measured during the first expansion. All surface properties measured, but more specifically the surface radioactivity of [14C]cytochrome c, indicate the irreversibility of protein incorporation into the chlorophyll a monolayer. In fact, surface properties of the binary film are completely different from the properties of either of the pure components. As a result, calculated values of surface potentials for mixed films using the additivity law deviate from experimentally measured potentials. The absorption and fluorescence spectra of mixed films transferred onto a solid substrate by the Langmuir-Blodgett technique, indicate a dilution effect of chlorophyll a by cytochrome c. However, the dilution effect cannot be detected by the fluorescence lifetimes of pure chlorophyll a and mixed chlorophyll a-cytochrome c films, both shorter than 0.2 ns. This provides support for the existence of an energy-transfer mechanism between chlorophyll a monomer and chlorophyll a aggregates which could serve as an energy trap. The role of the protein could be related to that of the matrix.

  1. Cellulose microfibrils grafted with PBA via surface-initiated atom transfer radical polymerization for biocomposite reinforcement.

    PubMed

    Li, Shuzhao; Xiao, Miaomiao; Zheng, Anna; Xiao, Huining

    2011-09-12

    Immobilizing poly(butyl acrylate) (PBA) on cellulose microfibrils (CMFs) by atom transfer radical polymerization (ATRP) of butyl acrylate (BA) on the surface of 2-bromoisobutyryl-functionalized CMF generated highly hydrophobic microfibrils (CMF-PBA) with a hard core and a soft-shell structure. TGA and static water contact angle results suggested that the surfaces of the modified CMF samples were not completely covered by PBA chains until the molecular weight of grafts became sufficiently long. The GPC results indicated that the grafts with low molecular weight showed controlled/"living" characteristics of the surface-initiated ATRP; however, there existed more side reactions with the increase in molecular weights. Biocomposites consisting of polypropylene (PP) and CMF-PBA samples exhibited significantly improved compatibility, interface adhesion, and mechanical properties with the increase in PBA graft length. The findings confirmed that the longer grafts facilitated the better entanglement of PBA grafts with PP macromolecules and thus further improved the mechanical properties.

  2. Design of UV-absorbing PVDF membrane via surface-initiated AGET ATRP

    NASA Astrophysics Data System (ADS)

    Dong, Li; Liu, Xiangdong; Xiong, Zhengrong; Sheng, Dekun; Zhou, Yan; Lin, Changhong; Yang, Yuming

    2018-03-01

    Herein, PVDF membranes with excellent UV-absorbing property were first synthesized through grafting the polymerizable low-molecular-weight organic UV-absorber 2-hydroxy-4-(3-methacryloxy-2-hydroxylpropoxy) benzophenone (BPMA) onto α-bromoester-functionalized PVDF membranes via the surface-initiated activator generated by electron transfer atom transfer radical polymerization (SI-AGET ATRP). The surface initiators were immobilized by the reaction between 2-bromoisobutyryl bromide (BIBB) and the hydroxylated PVDF membranes. PVDF-g-PBPMA membranes with different grafting densities were obtained by tuning the polymerization time and the modified membranes were characterized by 1H-NMR, FT-IR, XPS, SEM, UV-vis Spectrophotometer, TGA and DSC. The experimental results indicated that PBPMA chains were successfully introduced onto PVDF membranes. Most importantly, the PVDF-g-PBPMA membranes exhibited outstanding UV-shielding property. UV-vis transmittance spectra showed that most UV light below 360 nm could be absorbed by PVDF-g-PBPMA membranes and the whole UV light region (200-400 nm) can be blocked with the reaction time increased.

  3. Ultrasonication effect on thermophysical properties of Al2O3 nanofluids

    NASA Astrophysics Data System (ADS)

    Shah, Janki; Ranjan, Mukesh; Gupta, Sanjeev K.; Sonvane, Yogesh

    2018-04-01

    In this work, we studied the thermal conductivity and viscosity of alumina nanofluids for their excellent thermophysical properties. Here we considered the bath sonication time effects on thermal conductivity, viscosity and zeta potential of alumina nanofluid with different concentration (0.2, 0.3, 0.4, 0.5 Vol.%). We observed that the thermal conductivity of the nanofluids increased nonlinearly with an increased sonication time/energy as well as viscosity decreased. An enhancement of the thermal conductivity and viscosity at higher particle concentration is also observed. The results indicate that thermal properties of Al2O3 nanofluid enhances as the sonication time increases and prove Al2O3 nanofluid is one of the best thermostable heat transfer fluids compared to conventional cooling fluids.

  4. Improving surface-enhanced Raman scattering properties of TiO(2) nanoparticles by metal Co doping.

    PubMed

    Yang, Libin; Qin, Xiaoyu; Gong, Mengdi; Jiang, Xin; Yang, Ming; Li, Xiuling; Li, Guangzhi

    2014-04-05

    In this paper, pure and different amount Co ions doped TiO2 nanoparticles were synthesized by a sol-hydrothermal method and were served as SERS-active substrate. The effect of metal Co doping on SERS properties of TiO2 nanoparticles was mostly investigated. The results indicate that abundant metal doping energy levels can be formed in the energy gap of TiO2 by an appropriate amount Co ions doping, which can promote the charge transfer from TiO2 to molecule, and subsequently enhance SERS signal of adsorbed molecule on TiO2 substrate, and improve remarkably SERS properties of TiO2 nanoparticles. Copyright © 2013 Elsevier B.V. All rights reserved.

  5. JAGUAR Procedures for Detonation Behavior of Silicon Containing Explosives

    NASA Astrophysics Data System (ADS)

    Stiel, Leonard; Baker, Ernest; Capellos, Christos; Poulos, William; Pincay, Jack

    2007-06-01

    Improved relationships for the thermodynamic properties of solid and liquid silicon and silicon oxide for use with JAGUAR thermo-chemical equation of state routines were developed in this study. Analyses of experimental melting temperature curves for silicon and silicon oxide indicated complex phase behavior and that improved coefficients were required for solid and liquid thermodynamic properties. Advanced optimization routines were utilized in conjunction with the experimental melting point data to establish volumetric coefficients for these substances. The new property libraries resulted in agreement with available experimental values, including Hugoniot data at elevated pressures. Detonation properties were calculated with JAGUAR using the revised property libraries for silicon containing explosives. Constants of the JWLB equation of state were established for varying extent of silicon reaction. Supporting thermal heat transfer analyses were conducted for varying silicon particle sizes to establish characteristic times for melting and silicon reaction.

  6. 41 CFR 102-37.220 - Are there special types of surplus property that require written justification when submitting a...

    Code of Federal Regulations, 2012 CFR

    2012-01-01

    ... 41 Public Contracts and Property Management 3 2012-01-01 2012-01-01 false Are there special types of surplus property that require written justification when submitting a transfer request? 102-37.220... types of surplus property that require written justification when submitting a transfer request? Yes, a...

  7. 41 CFR 102-37.220 - Are there special types of surplus property that require written justification when submitting a...

    Code of Federal Regulations, 2014 CFR

    2014-01-01

    ... 41 Public Contracts and Property Management 3 2014-01-01 2014-01-01 false Are there special types of surplus property that require written justification when submitting a transfer request? 102-37.220... types of surplus property that require written justification when submitting a transfer request? Yes, a...

  8. 41 CFR 102-37.220 - Are there special types of surplus property that require written justification when submitting a...

    Code of Federal Regulations, 2011 CFR

    2011-01-01

    ... 41 Public Contracts and Property Management 3 2011-01-01 2011-01-01 false Are there special types of surplus property that require written justification when submitting a transfer request? 102-37.220... types of surplus property that require written justification when submitting a transfer request? Yes, a...

  9. 41 CFR 102-37.220 - Are there special types of surplus property that require written justification when submitting a...

    Code of Federal Regulations, 2013 CFR

    2013-07-01

    ... 41 Public Contracts and Property Management 3 2013-07-01 2013-07-01 false Are there special types of surplus property that require written justification when submitting a transfer request? 102-37.220... types of surplus property that require written justification when submitting a transfer request? Yes, a...

  10. 41 CFR 102-37.220 - Are there special types of surplus property that require written justification when submitting a...

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... 41 Public Contracts and Property Management 3 2010-07-01 2010-07-01 false Are there special types of surplus property that require written justification when submitting a transfer request? 102-37.220... types of surplus property that require written justification when submitting a transfer request? Yes, a...

  11. 10 CFR 770.6 - May interested persons and entities request that real property at defense nuclear facilities be...

    Code of Federal Regulations, 2013 CFR

    2013-01-01

    ... property at defense nuclear facilities be transferred for economic development? 770.6 Section 770.6 Energy DEPARTMENT OF ENERGY TRANSFER OF REAL PROPERTY AT DEFENSE NUCLEAR FACILITIES FOR ECONOMIC DEVELOPMENT § 770.6 May interested persons and entities request that real property at defense nuclear facilities be...

  12. 10 CFR 770.6 - May interested persons and entities request that real property at defense nuclear facilities be...

    Code of Federal Regulations, 2014 CFR

    2014-01-01

    ... property at defense nuclear facilities be transferred for economic development? 770.6 Section 770.6 Energy DEPARTMENT OF ENERGY TRANSFER OF REAL PROPERTY AT DEFENSE NUCLEAR FACILITIES FOR ECONOMIC DEVELOPMENT § 770.6 May interested persons and entities request that real property at defense nuclear facilities be...

  13. High-frequency dielectric study of proustite crystals Ag3AsS3

    NASA Astrophysics Data System (ADS)

    Bordovsky, V. A.; Gunia, N. Yu; Castro, R. A.

    2014-12-01

    The dielectric properties of the crystals proustite in the frequency of 106-109 Hz and a temperature range of 173 to 473 K were studied. The dispersion of the dielectric parameters indicates the existence of non-Debye relaxation mechanism correlates with structural changes in the phase transition region. The charge transfer is temperature activated with an activation energy of 2.40 ± 0.01 eV.

  14. 10 CFR 4.21 - General requirements.

    Code of Federal Regulations, 2010 CFR

    2010-01-01

    ... purpose involving the provision of similar services or benefits. In the case of personal property the... instrument effecting or recording the transfer shall contain a covenant running with the land assuring... benefits. Where no transfer of property is involved, but property is improved with Federal financial...

  15. 45 CFR 84.5 - Assurances required.

    Code of Federal Regulations, 2010 CFR

    2010-10-01

    ... benefits. (2) In the case of Federal financial assistance extended to provide personal property, the... effecting or recording this transfer shall contain a covenant running with the land to assure... benefits. (2) Where no transfer of property is involved but property is purchased or improved with Federal...

  16. 22 CFR 217.5 - Assurances required.

    Code of Federal Regulations, 2010 CFR

    2010-04-01

    ... benefits. (2) In the case of Federal financial assistance extended to provide personal property, the... or recording this transfer shall contain a covenant running with the land to assure nondiscrimination... services or benefits. (2) Where no transfer of property is involved but property is purchased or improved...

  17. 76 FR 44655 - Transfer of Federally Assisted Land or Facility

    Federal Register 2010, 2011, 2012, 2013, 2014

    2011-07-26

    ... square feet (the ``Property''). NICTD wishes to transfer ownership of the Property to Amtrak for Amtrak's... square feet (the ``Property''). The Northern Indiana Commuter Transportation District (NICTD) requests... approximately 5900 square feet in South Bend, Indiana, to the National Railroad Passenger Corporation (Amtrak...

  18. Bipyridinium array-type porous polymer displaying hydrogen storage, charge-transfer-type guest inclusion, and tunable magnetic properties.

    PubMed

    Yao, Qing-Xia; Pan, Long; Jin, Xu-Hui; Li, Jing; Ju, Zhan-Feng; Zhang, Jie

    2009-11-09

    A multifunctional pillared-layer porous coordination polymer, {[Mn(2)(Bpybc)(ox)(2)]8 H(2)O}(n), has been constructed based on a flexible viologen derivative, 1,1'-bis(4-carboxybenzyl)-4,4'-bipyridinium dichloride (H(2)BpybcCl(2)), and an oxalate (ox) coligand. Single-crystal X-ray analysis reveals that the compound possesses multichannels with dimensions of about 6.1x6.6 A along the [110] and [-110] directions and 4.2x7.6 A along [100], and a void space of about 41.4 %. Hydrogen adsorption measurements at 77 K and 1 atm indicate that the compound exhibits a hydrogen uptake of 0.71 wt %. Owing to the incorporation of bipyridinium acceptor units, the compound can selectively accommodate aromatic donors into its nanosized pores based on charge-transfer interactions in an elastic way, and afford a specific color to different guests. Furthermore, the effect of perturbation exerted by the guest molecules on its magnetic properties has been investigated. The results indicate that the donor inclusion has little effect on its antiferromagnetic behavior, whereas dehydration of the compound decreases the strength of the magnetic exchange couplings and results in a change of the antiferromagnetic transition temperature from 14.7 to 9.8 K.

  19. Nanofiber adsorbents for high productivity downstream processing.

    PubMed

    Hardick, Oliver; Dods, Stewart; Stevens, Bob; Bracewell, Daniel G

    2013-04-01

    Electrospun polymeric nanofiber adsorbents offer an alternative ligand support surface for bioseparations. Their non-woven fiber structure with diameters in the sub-micron range creates a remarkably high surface area. To improve the purification productivity of biological molecules by chromatography, cellulose nanofiber adsorbents were fabricated and assembled into a cartridge and filter holder format with a volume of 0.15 mL, a bed height of 0.3 mm and diameter of 25 mm. The present study investigated the performance of diethylaminoethyl (DEAE) derivatized regenerated cellulose nanofiber adsorbents based on criteria including mass transfer and flow properties, binding capacity, and fouling effects. Our results show that nanofibers offer higher flow and mass transfer properties. The non-optimized DEAE-nanofiber adsorbents indicate a binding capacity of 10% that of packed bed systems with BSA as a single component system. However, they operate reproducibly at flowrates of a hundred times that of packed beds, resulting in a potential productivity increase of 10-fold. Lifetime studies showed that this novel adsorbent material operated reproducibly with complex feed material (centrifuged and 0.45 µm filtered yeast homogenate) and harsh cleaning-in-place conditions over multiple cycles. DEAE nanofibers showed superior operating performance in permeability and fouling over conventional adsorbents indicating their potential for bioseparation applications. Copyright © 2012 Wiley Periodicals, Inc.

  20. Tunable photoluminescence and magnetic properties of Dy(3+) and Eu(3+) doped GdVO4 multifunctional phosphors.

    PubMed

    Liu, Yanxia; Liu, Guixia; Dong, Xiangting; Wang, Jinxian; Yu, Wensheng

    2015-10-28

    A series of Dy(3+) or/and Eu(3+) doped GdVO4 phosphors were successfully prepared by a simple hydrothermal method and characterized by X-ray diffraction (XRD), field emission scanning electron microscopy (FE-SEM), energy-dispersive X-ray spectrometry (EDS), photoluminescence (PL) spectroscopy and vibrating sample magnetometry (VSM). The results indicate that the as-prepared samples are pure tetragonal phase GdVO4, taking on nanoparticles with an average size of 45 nm. Under ultraviolet (UV) light excitation, the individual Dy(3+) or Eu(3+) ion activated GdVO4 phosphors exhibit excellent emission properties in their respective regions. The mechanism of energy transfer from the VO4(3-) group and the charge transfer band (CTB) to Dy(3+) and Eu(3+) ions is proposed. Color-tunable emissions in GdVO4:Dy(3+),Eu(3+) phosphors are realized through adopting different excitation wavelengths or adjusting the appropriate concentration of Dy(3+) and Eu(3+) when excited by a single excitation wavelength. In addition, the as-prepared samples show paramagnetic properties at room temperature. This kind of multifunctional color-tunable phosphor has great potential applications in the fields of photoelectronic devices and biomedical sciences.

  1. Calendering effects on the physical and electrochemical properties of Li[Ni1/3Mn1/3Co1/3]O2 cathode

    NASA Astrophysics Data System (ADS)

    Zheng, Honghe; Tan, Li; Liu, Gao; Song, Xiangyun; Battaglia, Vincent S.

    2012-06-01

    Li[Ni1/3Mn1/3Co1/3]O2 cathode laminate containing 8% PVDF and 7% acetylene black is fabricated and calendered to different porosities. Calendering effects on the physical and electrochemical properties of the Li[Ni1/3Mn1/3Co1/3]O2 cathode are investigated. It is found that mechanical properties of the composite laminate strongly depend on the electrode porosity whereas the electronic conductivity is not significantly affected by calendering. Electrochemical performances including the specific capacity, the first coulombic efficiency, cycling performance and rate capability for the cathode at different porosities are compared. An optimized porosity of around 30-40% is identified. Electrochemical impedance spectroscopy (EIS) studies illustrate that calendering improves the electronic conductivity between active particles at relatively high porosities, but increases charge transfer resistance at electrode/electrolyte interface at relatively low porosities. An increase of activation energy of Li interfacial transfer for the electrode at 0% porosity indicates a relatively high barrier of activation at the electrode/electrolyte interface, which accounts for the poor rate capability of the electrode at extremely low porosity.

  2. Electrochemistry and electrochemiluminescence from a redox-active metal-organic framework.

    PubMed

    Xu, Yang; Yin, Xue-Bo; He, Xi-Wen; Zhang, Yu-Kui

    2015-06-15

    The marriage of metal-organic frameworks (MOFs) and electrochemiluminescence (ECL) can combine their merits together. Designing ECL-active MOF with a high electron transfer capacity and high stability is critical for ECL emission. Here we reported the ECL from a redox-active MOF prepared from {Ru[4,4'-(HO2C)2-bpy]2bpy}(2+) and Zn(2+); a property of MOFs has not been reported previously. The MOF structure is independent of its charge and is therefore stable electrochemically. The redox-activity and well-ordered porous structure of the MOF were confirmed by its electrochemical properties and ECL emission. The high ECL emission indicated the ease of electron transfer between the MOF and co-reactants. Furthermore, the MOF exhibited permselectivity, charge selectivity, and catalytic selectivity along with a stable and concentration-dependent ECL emission toward co-reactants. ECL mechanism was proposed based on the results. The detection and recovery of cocaine in the serum sample was used to validate the feasibility of MOF- based ECL system. The information obtained in this study provides a better understanding of the redox properties of MOFs and their potential electrochemical applications. Copyright © 2014 Elsevier B.V. All rights reserved.

  3. 36 CFR 9.6 - Transfers of interest.

    Code of Federal Regulations, 2012 CFR

    2012-07-01

    ... 36 Parks, Forests, and Public Property 1 2012-07-01 2012-07-01 false Transfers of interest. 9.6 Section 9.6 Parks, Forests, and Public Property NATIONAL PARK SERVICE, DEPARTMENT OF THE INTERIOR MINERALS MANAGEMENT Mining and Mining Claims § 9.6 Transfers of interest. (a) Whenever a claimant who has recorded his...

  4. 36 CFR 9.6 - Transfers of interest.

    Code of Federal Regulations, 2011 CFR

    2011-07-01

    ... 36 Parks, Forests, and Public Property 1 2011-07-01 2011-07-01 false Transfers of interest. 9.6 Section 9.6 Parks, Forests, and Public Property NATIONAL PARK SERVICE, DEPARTMENT OF THE INTERIOR MINERALS MANAGEMENT Mining and Mining Claims § 9.6 Transfers of interest. (a) Whenever a claimant who has recorded his...

  5. 36 CFR 9.6 - Transfers of interest.

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... 36 Parks, Forests, and Public Property 1 2010-07-01 2010-07-01 false Transfers of interest. 9.6 Section 9.6 Parks, Forests, and Public Property NATIONAL PARK SERVICE, DEPARTMENT OF THE INTERIOR MINERALS MANAGEMENT Mining and Mining Claims § 9.6 Transfers of interest. (a) Whenever a claimant who has recorded his...

  6. 36 CFR 9.6 - Transfers of interest.

    Code of Federal Regulations, 2013 CFR

    2013-07-01

    ... 36 Parks, Forests, and Public Property 1 2013-07-01 2013-07-01 false Transfers of interest. 9.6 Section 9.6 Parks, Forests, and Public Property NATIONAL PARK SERVICE, DEPARTMENT OF THE INTERIOR MINERALS MANAGEMENT Mining and Mining Claims § 9.6 Transfers of interest. (a) Whenever a claimant who has recorded his...

  7. 36 CFR 9.6 - Transfers of interest.

    Code of Federal Regulations, 2014 CFR

    2014-07-01

    ... 36 Parks, Forests, and Public Property 1 2014-07-01 2014-07-01 false Transfers of interest. 9.6 Section 9.6 Parks, Forests, and Public Property NATIONAL PARK SERVICE, DEPARTMENT OF THE INTERIOR MINERALS MANAGEMENT Mining and Mining Claims § 9.6 Transfers of interest. (a) Whenever a claimant who has recorded his...

  8. Two dimensional finite element heat transfer models for softwood

    Treesearch

    Hongmei Gu; John F. Hunt

    2004-01-01

    The anisotropy of wood creates a complex problem for solving heat and mass transfer problems that require analyses be based on fundamental material properties of the wood structure. Most heat transfer models use average thermal properties across either the radial or tangential directions and have not differentiated the effects of cellular alignment, earlywood/latewood...

  9. [Valorization of biological resources in tumour libraries].

    PubMed

    Keelaghan, Thérèse

    2006-01-01

    The transfer and commercialization of biological materials, whether in the form of tumour samples, tissue samples or chemicals, and of the data base pertaining to such material have become a subject of considerable importance for both the private and public sectors involved in medical research. In order to fully appreciate and apprehend the process for the protection and the valuation of the transferred material, intellectual property law must be taken into account. As a result, a distinction is made between the tangible and intangible elements of the biological material and of the attached data base, thus providing the transferring entity the possibility to claim property rights to future intellectual property arising from the research regarding the transferred material. The transfer of biological material and attached data base without such contractual provisions can lead to the loss of this potential value as well as of physical and legal control over the material transferred by the providing entity. The intentions and the assumptions of the parties must be negotiated and written into terms of contract, at the risk of losing future value due to unexpressed assumptions concerning intangible property rights.

  10. 75 FR 18826 - Notice of Inventions Available for License

    Federal Register 2010, 2011, 2012, 2013, 2014

    2010-04-13

    ..., Office of the Assistant General Counsel for Technology Transfer and Intellectual Property, U.S..., 2010. Paul A. Gottlieb, Assistant General Counsel for Technology, Transfer and Intellectual Property...

  11. Climate Responses to Changes in Land-surface Properties due to Wildfires

    NASA Astrophysics Data System (ADS)

    Liu, Y.; Hao, X.; Qu, J. J.

    2015-12-01

    Wildfires can feedback the atmosphere by impacting atmospheric radiation transfer and cloud microphysics through emitting smoke particles and the land-air heat and water fluxes through modifying land-surface properties. While the impacts through smoke particles have been extensively investigated recently, very few studies have been conducted to examine the impacts through land-surface property change. This study is to fill this gap by examining the climate responses to the changes in land-surface properties induced by several large wildfires in the United States. Satellite remote sensing tools including MODIS and Landsat are used to quantitatively evaluate the land-surface changes characterized by reduced vegetation coverage and increased albedo over long post-fire periods. Variations in air and soil temperature and moisture of the burned areas are also monitored. Climate modeling is conducted to simulate climate responses and understand the related physical processes and interactions. The preliminary results indicate noticeable changes in water and heat transfers from the ground to the atmosphere through several mechanisms. Larger albedo reduces solar radiation absorbed on the ground, leading to less energy for latent and sensible heat fluxes. With smaller vegetation coverage, water transfer from the soil to the atmosphere through transpiration is reduced. Meanwhile, the Bowen ratio becomes larger after burning and therefore more solar energy absorbed on the ground is converted into sensible heat instead of being used as latent energy for water phase change. In addition, reduced vegetation coverage reduces roughness and increases wind speed, which modify dynamic resistances to water and heat movements. As a result of the changes in the land-air heat and water fluxes, clouds and precipitation as well as other atmospheric processes are affected by wildfires.

  12. Using a quasi-heat-pulse method to determine heat and moisture transfer properties for porous orthotropic wood products or cellular solid materials

    Treesearch

    M. A. Dietenberger

    2006-01-01

    Understanding heat and moisture transfer in a wood specimen as used in the K-tester has led to an unconventional numerical solution arid intriguing protocol to deriving the transfer properties. Laplace transform solutions of Luikov’s differential equations are derived for one-dimensional heat and moisture transfer in porous hygroscopic orthotropic materials and for a...

  13. The optical properties of transferred graphene and the dielectrics grown on it obtained by ellipsometry

    NASA Astrophysics Data System (ADS)

    Kasikov, Aarne; Kahro, Tauno; Matisen, Leonard; Kodu, Margus; Tarre, Aivar; Seemen, Helina; Alles, Harry

    2018-04-01

    Graphene layers grown by chemical vapour deposition (CVD) method and transferred from Cu-foils to the oxidized Si-substrates were investigated by spectroscopic ellipsometry (SE), Raman and X-Ray Photoelectron Spectroscopy (XPS) methods. The optical properties of transferred CVD graphene layers do not always correspond to the ones of the exfoliated graphene due to the contamination from the chemicals used in the transfer process. However, the real thickness and the mean properties of the transferred CVD graphene layers can be found using ellipsometry if a real thickness of the SiO2 layer is taken into account. The pulsed laser deposition (PLD) and atomic layer deposition (ALD) methods were used to grow dielectric layers on the transferred graphene and the obtained structures were characterized using optical methods. The approach demonstrated in this work could be useful for the characterization of various materials grown on graphene.

  14. Crustal Properties Across the Mid-Continent Rift via Transfer Function Analysis

    NASA Astrophysics Data System (ADS)

    Frederiksen, A. W.; Tyomkin, Y.; Campbell, R.; van der Lee, S.; Zhang, H.

    2015-12-01

    The Mid-Continent Rift (MCR), a failed Proterozoic rift structure in central North America, is a dominant feature of North American gravity maps. The rift underwent a combination of extension, magmatism, and later compression, and it is difficult to predict how these events affected the overall crustal thickness and bulk composition in the vicinity of the rift axis, though the associated gravity high indicates that large-volume mafic magmatism took place. The Superior Province Rifting Earthscope Experiment (SPREE) project instrumented the MCR with Flexible Array broadband seismographs from 2011 through 2013 in Minnesota and Wisconsin, along two lines crossing the rift axis as well as a line following the axis. We examine teleseismic P-coda data from SPREE and nearby Transportable Array instruments using a new technique: transfer-function analysis. In this approach, possible models of crustal structure are used to generate a predicted transfer function relating the radial and vertical components of the P coda at a particular site. The transfer function then allows generation of a misfit (between the true radial component and a synthetic radial component predicted from the vertical trace) without the need to perform receiver-function deconvolution, thus avoiding the deconvolution problems encountered with receiver functions in sedimentary basins. We use the transfer-function approach to perform a grid search over three crustal properties: crustal thickness, crustal P/S velocity ratio, and the thickness of an overlying sedimentary basin. Results for our SPREE/TA data set indicate that the crust is significantly thickened along the rift axis, with maximum thicknesses approaching 50 km; the crust is thinner (ca. 40 km) outside of the rift zone. The crustal thickness structure is particularly complex beneath southeastern Minnesota, where very strong Moho topography is present, as well as up to 2 km of sediment; further north, the Moho is smoother and the basin is not present. P/S ratio varies along the rift axis, suggesting a higher mafic component (higher ratio) in southern Minnesota. The complexity we see along the MCR is consistent with the results obtained by Zhang et al. (this conference) using receiver function analysis.

  15. 41 CFR 102-34.305 - What forms do we use to transfer ownership when selling a motor vehicle?

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... 41 Public Contracts and Property Management 3 2010-07-01 2010-07-01 false What forms do we use to transfer ownership when selling a motor vehicle? 102-34.305 Section 102-34.305 Public Contracts and Property Management Federal Property Management Regulations System (Continued) FEDERAL MANAGEMENT REGULATION PERSONAL PROPERTY 34-MOTOR VEHICLE...

  16. Covenant Deferral Request for the Proposed Transfer of Land Parcel ED-8 at the East Tennessee Technology Park, Oak Ridge, Tennessee - Final - May 2009

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    SAIC

    2009-05-01

    The United States Department of Energy (DOE) is proposing to transfer a land parcel (hereinafter referred to as 'the Property') designated as Land Parcel ED-8 at the East Tennessee Technology Park (ETTP) in Oak Ridge, Tennessee, by deed, and is submitting this Covenant Deferral Request (CDR) pursuant to Section 120(h)(3)(C) of the Comprehensive Environmental Response, Compensation, and Liability Act (CERCLA), as amended, and applicable U. S. Environmental Protection Agency (EPA) guidance. The Oak Ridge Reservation (ORR), which includes ETTP, was placed on the National Priorities List (NPL) in November 1989. Environmental investigation and cleanup activities are continuing at ETTP inmore » accordance with CERCLA, the National Contingency Plan (NCP), and the Federal Facility Agreement (FFA). The FFA was entered into by the DOE-Oak Ridge Office (ORO), EPA Region 4, and the Tennessee Department of Environment and Conservation (TDEC) in 1991. The FFA establishes the schedule and milestones for environmental remediation of the ORR. The proposed property transfer is a key component of the Oak Ridge Performance Management Plan (ORPMP) for accelerated cleanup of the ORR. DOE, using its authority under Section 161(g) of the Atomic Energy Act of 1954 (AEA), proposes to transfer the Property to Heritage Center, LLC, a subsidiary of the Community Reuse Organization of East Tennessee (CROET), hereafter referred to as 'Heritage Center.' CROET is a 501(c)(3) not-for-profit corporation established to foster the diversification of the regional economy by re-utilizing DOE property for private-sector investment and job creation. The Property is located in the southern portion of ETTP and consists of approximately 84 acres proposed as the potential site for new facilities to be used for office space, industrial activities, or other commercial uses. The parcel contains both grassy fields located outside the ETTP 'main plant' area and infrastructure located inside the 'main plant' area. No buildings are included in the proposed ED-8 transfer. The buildings in ED-8 have already been transferred (Buildings K-1007, K-1580, K-1330, and K-1000). These buildings are not included in the transfer footprint of Land Parcel ED-8. A number of temporary structures, such as trailers and tents (non-real property), are located within the footprint. These temporary structures are not included in the transfer. DOE would continue to be responsible for any contamination resulting from DOE activities that is present on the property at the time of transfer but found after the date of transfer. The deed transferring the Property contains various restrictions and prohibitions on the use of the Property that are subject to enforcement pursuant to State Law Tennessee Code Annotated (T.C.A.) 68-212-225 and state real property law. These restrictions and prohibitions are designed to ensure protection of human health and the environment.« less

  17. 10 CFR 5.120 - Transfers of property.

    Code of Federal Regulations, 2010 CFR

    2010-01-01

    ... operates any education program or activity, and the Federal share of the fair market value of the property... 10 Energy 1 2010-01-01 2010-01-01 false Transfers of property. 5.120 Section 5.120 Energy NUCLEAR REGULATORY COMMISSION NONDISCRIMINATION ON THE BASIS OF SEX IN EDUCATION PROGRAMS OR ACTIVITIES RECEIVING...

  18. 18 CFR 1317.120 - Transfers of property.

    Code of Federal Regulations, 2010 CFR

    2010-04-01

    ... 18 Conservation of Power and Water Resources 2 2010-04-01 2010-04-01 false Transfers of property. 1317.120 Section 1317.120 Conservation of Power and Water Resources TENNESSEE VALLEY AUTHORITY... or activity, and the Federal share of the fair market value of the property is not upon such sale or...

  19. 45 CFR 12.9 - General disposal terms and conditions.

    Code of Federal Regulations, 2014 CFR

    2014-10-01

    ... UTILIZATION OF SURPLUS REAL PROPERTY FOR PUBLIC HEALTH PURPOSES § 12.9 General disposal terms and conditions. (a) Surplus real property transfers under this part will be limited to public health purposes... hereof. (b) A transfer of surplus real property for public health purposes is subject to the disapproval...

  20. 45 CFR 12.9 - General disposal terms and conditions.

    Code of Federal Regulations, 2013 CFR

    2013-10-01

    ... UTILIZATION OF SURPLUS REAL PROPERTY FOR PUBLIC HEALTH PURPOSES § 12.9 General disposal terms and conditions. (a) Surplus real property transfers under this part will be limited to public health purposes... hereof. (b) A transfer of surplus real property for public health purposes is subject to the disapproval...

  1. 45 CFR 12.9 - General disposal terms and conditions.

    Code of Federal Regulations, 2012 CFR

    2012-10-01

    ... UTILIZATION OF SURPLUS REAL PROPERTY FOR PUBLIC HEALTH PURPOSES § 12.9 General disposal terms and conditions. (a) Surplus real property transfers under this part will be limited to public health purposes... hereof. (b) A transfer of surplus real property for public health purposes is subject to the disapproval...

  2. Boundary layer development as a function of chamber pressure in the NASA Lewis 1030:1 area ratio rocket nozzle

    NASA Technical Reports Server (NTRS)

    Smith, Tamara A.

    1988-01-01

    Through the use of theoretical predictions of fluid properties and experimental heat transfer and thrust measurements, the zones of laminar, transitional, and turbulent boundary layer flow were defined for the NASA Lewis 1039:1 area ratio rocket nozzle. Tests were performed on the nozzle at chamber pressures from 350 to 100 psia. For these conditions, the throat diameter Reynolds numbers varied from 300,000 to 1 million. The propellants used were gaseous hydrogen and gaseous oxygen. Thrust measurements and nozzle outer wall temperature measurements were taken during the 3-sec test runs. Comparison of experimental heat transfer and thrust data with the corresponding predictions from the Two-Dimensional Kinetics (TDK) nozzle analysis program indicated laminar flow in the nozzle at a throat diameter Reynolds number of 320,000 or chamber pressure of 360 psia. Comparison of experimental and predicted heat transfer data indicated transitional flow up to and including a chamber pressure of 1000 psia. Predicted values of the axisymmetric acceleration parameter within the convergent and divergent nozzle were consistent with the above results. Based upon an extrapolation of the heat transfer data and predicted distributions of the axisymmetric acceleration parameter, transitional flow was predicted up to a throat diameter Reynolds number of 220,000 or 2600-psia chamber pressure. Above 2600-psia chamber pressure, fully developed turbulent flow was predicted.

  3. Boundary layer development as a function of chamber pressure in the NASA Lewis 1030:1 area ratio rocket nozzle

    NASA Technical Reports Server (NTRS)

    Smith, Tamara A.

    1988-01-01

    Through the use of theoretical predictions of fluid properties and experimental heat transfer and thrust measurements, the zones of laminar, transitional, and turbulent boundary layer flow were defined for the NASA Lewis 1030:1 area ratio rocket nozzle. Tests were performed on the nozzle at chamber pressures from 350 to 100 psia. For these conditions, the throat diameter Reynolds numbers varied from 300,000 to 1 million. The propellants used were gaseous hydrogen and gaseous oxygen. Thrust measurements and nozzle outer wall temperature measurements were taken during the 3-sec test runs. Comparison of experimental heat transfer and thrust data with the corresponding predictions from the Two-Dimensional Kinetics (TDK) nozzle analysis program indicated laminar flow in the nozzle at a throat diameter Reynolds number of 320,000 or chamber pressure of 360 psia. Comparison of experimental and predicted heat transfer data indicated transitional flow up to and including a chamber pressure of 1000 psia. Predicted values of the axisymmetric acceleration parameter within the convergent and divergent nozzle were consistent with the above results. Based upon an extrapolation of the heat transfer data and predicted distributions of the axisymmetric acceleration parameter, transitional flow was predicted up to a throat diameter Reynolds number of 220,000 or 2600-psia chamber pressure. Above 2600-psia chamber pressure, fully developed turbulent flow was predicted.

  4. 26 CFR 1.367(d)-1T - Transfers of intangible property to foreign corporations (temporary).

    Code of Federal Regulations, 2010 CFR

    2010-04-01

    ... the parties to the transaction shall not necessarily be controlling for this purpose. (6) Anti-abuse rule. If a U.S. person— (i) Transfers intangible property to a domestic corporation with a principal... transfers the stock of that domestic corporation to a related foreign corporation, then solely for purposes...

  5. 7 CFR 1806.4 - Examining and general servicing of insurance.

    Code of Federal Regulations, 2014 CFR

    2014-01-01

    ... protect the interests of the Government. (2) Transfer of property. (i) When a borrower or transferee requests the consent of FmHA or its successor agency under Public Law 103-354 to a transfer of the security property which already has been made, or when the County Supervisor learns that any such transfer has been...

  6. 7 CFR 1806.4 - Examining and general servicing of insurance.

    Code of Federal Regulations, 2013 CFR

    2013-01-01

    ... protect the interests of the Government. (2) Transfer of property. (i) When a borrower or transferee requests the consent of FmHA or its successor agency under Public Law 103-354 to a transfer of the security property which already has been made, or when the County Supervisor learns that any such transfer has been...

  7. 7 CFR 1806.4 - Examining and general servicing of insurance.

    Code of Federal Regulations, 2012 CFR

    2012-01-01

    ... protect the interests of the Government. (2) Transfer of property. (i) When a borrower or transferee requests the consent of FmHA or its successor agency under Public Law 103-354 to a transfer of the security property which already has been made, or when the County Supervisor learns that any such transfer has been...

  8. 41 CFR 302-3.101 - As a transferred employee what relocation allowances must my agency pay or reimburse to me?

    Code of Federal Regulations, 2014 CFR

    2014-07-01

    ... 41 Public Contracts and Property Management 4 2014-07-01 2014-07-01 false As a transferred... Public Contracts and Property Management Federal Travel Regulation System RELOCATION ALLOWANCES RELOCATION ALLOWANCES 3-RELOCATION ALLOWANCE BY SPECIFIC TYPE Transferred Employees § 302-3.101 As a...

  9. 41 CFR 302-3.101 - As a transferred employee what relocation allowances must my agency pay or reimburse to me?

    Code of Federal Regulations, 2012 CFR

    2012-07-01

    ... 41 Public Contracts and Property Management 4 2012-07-01 2012-07-01 false As a transferred... Public Contracts and Property Management Federal Travel Regulation System RELOCATION ALLOWANCES RELOCATION ALLOWANCES 3-RELOCATION ALLOWANCE BY SPECIFIC TYPE Transferred Employees § 302-3.101 As a...

  10. 7 CFR 1948.90 - Land transfers.

    Code of Federal Regulations, 2010 CFR

    2010-01-01

    ... § 1948.90 Land transfers. (a) Transfers of real property acquired by FmHA or its successor agency under Public Law 103-354. (1) A request for FmHA or its successor agency under Public Law 103-354 acquisition... property and to reimburse FmHA or its successor agency under Public Law 103-354 for the fair market value...

  11. Two-dimensional finite element heat transfer model of softwood. Part I, Effective thermal conductivity

    Treesearch

    John F. Hunt; Hongmei Gu

    2006-01-01

    The anisotropy of wood complicates solution of heat and mass transfer problems that require analyses be based on fundamental material properties of the wood structure. Most heat transfer models use average thermal properties across either the radial or tangential direction and do not differentiate the effects of cellular alignment, earlywood/latewood differences, or...

  12. Environmental Effects on Hysteresis of Transfer Characteristics in Molybdenum Disulfide Field-Effect Transistors

    NASA Astrophysics Data System (ADS)

    Shimazu, Yoshihiro; Tashiro, Mitsuki; Sonobe, Satoshi; Takahashi, Masaki

    2016-07-01

    Molybdenum disulfide (MoS2) has recently received much attention for nanoscale electronic and photonic applications. To explore the intrinsic properties and enhance the performance of MoS2-based field-effect transistors, thorough understanding of extrinsic effects such as environmental gas and contact resistance of the electrodes is required. Here, we report the effects of environmental gases on the transport properties of back-gated multilayered MoS2 field-effect transistors. Comparisons between different gases (oxygen, nitrogen, and air and nitrogen with varying relative humidities) revealed that water molecules acting as charge-trapping centers are the main cause of hysteresis in the transfer characteristics. While the hysteresis persisted even after pumping out the environmental gas for longer than 10 h at room temperature, it disappeared when the device was cooled to 240 K, suggesting a considerable increase in the time constant of the charge trapping/detrapping at these modestly low temperatures. The suppression of the hysteresis or instability in the easily attainable temperature range without surface passivation is highly advantageous for the device application of this system. The humidity dependence of the threshold voltages in the transfer curves indicates that the water molecules dominantly act as hole-trapping centers. A strong dependence of the on-state current on oxygen pressure was also observed.

  13. Triplet state dissolved organic matter in aquatic photochemistry: reaction mechanisms, substrate scope, and photophysical properties.

    PubMed

    McNeill, Kristopher; Canonica, Silvio

    2016-11-09

    Excited triplet states of chromophoric dissolved organic matter ( 3 CDOM*) play a major role among the reactive intermediates produced upon absorption of sunlight by surface waters. After more than two decades of research on the aquatic photochemistry of 3 CDOM*, the need for improving the knowledge about the photophysical and photochemical properties of these elusive reactive species remains considerable. This critical review examines the efforts to date to characterize 3 CDOM*. Information on 3 CDOM* relies mainly on the use of probe compounds because of the difficulties associated with directly observing 3 CDOM* using transient spectroscopic methods. Singlet molecular oxygen ( 1 O 2 ), which is a product of the reaction between 3 CDOM* and dissolved oxygen, is probably the simplest indicator that can be used to estimate steady-state concentrations of 3 CDOM*. There are two major modes of reaction of 3 CDOM* with substrates, namely triplet energy transfer or oxidation (via electron transfer, proton-coupled electron transfer or related mechanisms). Organic molecules, including several environmental contaminants, that are susceptible to degradation by these two different reaction modes are reviewed. It is proposed that through the use of appropriate sets of probe compounds and model photosensitizers an improved estimation of the distribution of triplet energies and one-electron reduction potentials of 3 CDOM* can be achieved.

  14. Optical properties of nucleobase thin films as studied by attenuated total reflection and surface-enhanced Raman spectroscopy

    NASA Astrophysics Data System (ADS)

    Kim, MinSuk; Ham, Won Kyu; Kim, Wonyoung; Hwangbo, Chang Kwon; Choi, Eun Ha; Lee, Geon Joon

    2018-04-01

    Optical properties of nucleobase thin films were studied by attenuated total reflection (ATR) and surface-enhanced Raman spectroscopy (SERS). Adenine and guanine films were deposited on fused silica and silver at room temperature by thermal evaporation, and the normal dispersion of refractive indices of transparent adenine and guanine films in the visible and near-infrared regions were analyzed. The measured ATR spectra of adenine (guanine) films and numerical simulations by optical transfer matrix formalism demonstrate that the shift of surface plasmon resonance (SPR) wavelength is approximately linearly proportional to the adenine (guanine) film thickness, indicating that SPR can be used for quantitative measurements of biomaterials. The Raman spectra indicated that the adenine (guanine) films can be deposited by thermal evaporation. The adenine (guanine) films on silver exhibited Raman intensity enhancement as compared to those on glass, which was attributed to the SPR effect of silver platform and might play a role as a hot plate for SERS detection of biomaterials.

  15. Nonautonomous linear system of the terrestrial carbon cycle

    NASA Astrophysics Data System (ADS)

    Luo, Y.

    2012-12-01

    Carbon cycle has been studied by uses of observation through various networks, field and laboratory experiments, and simulation models. Much less has been done on theoretical thinking and analysis to understand fundament properties of carbon cycle and then guide observatory, experimental, and modeling research. This presentation is to explore what would be the theoretical properties of terrestrial carbon cycle and how those properties can be used to make observatory, experimental, and modeling research more effective. Thousands of published data sets from litter decomposition and soil incubation studies almost all indicate that decay processes of litter and soil organic carbon can be well described by first order differential equations with one or more pools. Carbon pool dynamics in plants and soil after disturbances (e.g., wildfire, clear-cut of forests, and plows of soil for cropping) and during natural recovery or ecosystem restoration also exhibit characteristics of first-order linear systems. Thus, numerous lines of empirical evidence indicate that the terrestrial carbon cycle can be adequately described as a nonautonomous linear system. The linearity reflects the nature of the carbon cycle that carbon, once fixed by photosynthesis, is linearly transferred among pools within an ecosystem. The linear carbon transfer, however, is modified by nonlinear functions of external forcing variables. In addition, photosynthetic carbon influx is also nonlinearly influenced by external variables. This nonautonomous linear system can be mathematically expressed by a first-order linear ordinary matrix equation. We have recently used this theoretical property of terrestrial carbon cycle to develop a semi-analytic solution of spinup. The new methods have been applied to five global land models, including NCAR's CLM and CABLE models and can computationally accelerate spinup by two orders of magnitude. We also use this theoretical property to develop an analytic framework to decompose modeled carbon cycle into a few traceable components so as to facilitate model intercompsirosn, benchmark analysis, and data assimilation of global land models.

  16. 24 CFR 3.120 - Transfers of property.

    Code of Federal Regulations, 2011 CFR

    2011-04-01

    ... property financed in whole or in part with Federal financial assistance to a transferee that operates any... such sale or transfer properly accounted for to the Federal Government, both the transferor and the...

  17. 24 CFR 3.120 - Transfers of property.

    Code of Federal Regulations, 2013 CFR

    2013-04-01

    ... property financed in whole or in part with Federal financial assistance to a transferee that operates any... such sale or transfer properly accounted for to the Federal Government, both the transferor and the...

  18. 24 CFR 3.120 - Transfers of property.

    Code of Federal Regulations, 2014 CFR

    2014-04-01

    ... property financed in whole or in part with Federal financial assistance to a transferee that operates any... such sale or transfer properly accounted for to the Federal Government, both the transferor and the...

  19. 24 CFR 3.120 - Transfers of property.

    Code of Federal Regulations, 2012 CFR

    2012-04-01

    ... property financed in whole or in part with Federal financial assistance to a transferee that operates any... such sale or transfer properly accounted for to the Federal Government, both the transferor and the...

  20. Heat transfer in freeboard region of fluidized beds

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Biyikli, S.; Tuzla, K.; Chen, J.C.

    1983-10-01

    This research involved the study of heat transfer and fluid mechanic characteristics around a horizontal tube in the freeboard region of fluidized beds. Heat transfer coefficients were experimetnally measured for different bed temperatures, particle sizes, gas flow rates, and tube elevations in the freeboard region of air fluidized beds at atmospheric pressure. Local heat transfer coefficients were found to vary significantly with angular position around the tube. Average heat transfer coefficients were found to decrease with increasing freeboard tube elevation and approach the values for gas convection plus radiation for any given gas velocity. For a fixed tube elevation, heatmore » transfer coefficients generally increased with increasing gas velocity and with high particle entrainment they can approach the magnitudes found for immersed tubes. Heat transfer coefficients were also found to increase with increasing bed temperature. It was concluded that this increase is partly due to increase of radiative heat transfer and partly due to change of thermal properties of the fluidizing gas and particles. To investigate the fluid mechanic behavior of gas and particles around a freeboard tube, transient particle tube contacts were measured with a special capacitance probe in room temperature experiments. The results indicated that the tube surface experiences alternating dense and lean phase contacts. Quantitative information for local characteristics was obtained from the capacitance signals and used to develop a phenomenological model for prediction of the heat transfer coefficients around freeboard tubes. The packet renewal theory was modified to account for the dense phase heat transfer and a new model was suggested for the lean phase heat transfer. Finally, an empirical freeboard heat transfer correlation was developed from functional analysis of the freeboard heat transfer data using nondimensional groups representing gas velocity and tube elevation.« less

  1. Hole transfer from CdSe nanoparticles to TQ1 polymer in hybrid solar cell device

    NASA Astrophysics Data System (ADS)

    Sohail, Muhammad; Shah, Zawar Hussain; Saeed, Shomaila; Bibi, Nasreen; Shahbaz, Sadia; Ahmed, Safeer; Shabbir, Saima; Siddiq, Muhammad; Iqbal, Azhar

    2018-05-01

    In view of realizing the economic viability, we fabricate a solar cell device containing low band gap and easily processable polymer 5-yl-8-(thiophene-2,5-diyl)-2,3-bis(3-(octyloxy)phenyl) quinoxaline (TQ1) and CdSe nanoparticles (NPs) and investigate its charge transport properties. When the TQ1 is combined with the CdSe NPs a strong photoluminescence quenching and shortening of photoluminescence lifetime of the TQ1 is observed indicating exciton transfer from TQ1 to the CdSe NPs. The time-resolved photoluminescence further reveals that the exciton transfer from the polymer to CdSe NPs is very efficient (68%) and it occurs in <1 ns. The exciton transfer from TQ1 to the NPs and electron-hole pair separation followed by hole transfer from the NPs to the TQ1 at the interface indeed increases the lifetime of the charge carriers. This in turn increases the efficiency of the solar cell as compared to polymer only device. These observations suggest the importance of other II-VI semiconductor NPs to achieve higher efficiency for photovoltaic devices containing TQ1 polymer.

  2. Origin of Self-preservation Effect for Hydrate Decomposition: Coupling of Mass and Heat Transfer Resistances

    PubMed Central

    Bai, Dongsheng; Zhang, Diwei; Zhang, Xianren; Chen, Guangjin

    2015-01-01

    Gas hydrates could show an unexpected high stability at conditions out of thermodynamic equilibrium, which is called the self-preservation effect. The mechanism of the effect for methane hydrates is here investigated via molecular dynamics simulations, in which an NVT/E method is introduced to represent different levels of heat transfer resistance. Our simulations suggest a coupling between the mass transfer resistance and heat transfer resistance as the driving mechanism for self-preservation effect. We found that the hydrate is initially melted from the interface, and then a solid-like water layer with temperature-dependent structures is formed next to the hydrate interface that exhibits fractal feature, followed by an increase of mass transfer resistance for the diffusion of methane from hydrate region. Furthermore, our results indicate that heat transfer resistance is a more fundamental factor, since it facilitates the formation of the solid-like layer and hence inhibits the further dissociation of the hydrates. The self-preservation effect is found to be enhanced with the increase of pressure and particularly the decrease of temperature. Kinetic equations based on heat balance calculations is also developed to describe the self-preservation effect, which reproduces our simulation results well and provides an association between microscopic and macroscopic properties. PMID:26423519

  3. Origin of Self-preservation Effect for Hydrate Decomposition: Coupling of Mass and Heat Transfer Resistances.

    PubMed

    Bai, Dongsheng; Zhang, Diwei; Zhang, Xianren; Chen, Guangjin

    2015-10-01

    Gas hydrates could show an unexpected high stability at conditions out of thermodynamic equilibrium, which is called the self-preservation effect. The mechanism of the effect for methane hydrates is here investigated via molecular dynamics simulations, in which an NVT/E method is introduced to represent different levels of heat transfer resistance. Our simulations suggest a coupling between the mass transfer resistance and heat transfer resistance as the driving mechanism for self-preservation effect. We found that the hydrate is initially melted from the interface, and then a solid-like water layer with temperature-dependent structures is formed next to the hydrate interface that exhibits fractal feature, followed by an increase of mass transfer resistance for the diffusion of methane from hydrate region. Furthermore, our results indicate that heat transfer resistance is a more fundamental factor, since it facilitates the formation of the solid-like layer and hence inhibits the further dissociation of the hydrates. The self-preservation effect is found to be enhanced with the increase of pressure and particularly the decrease of temperature. Kinetic equations based on heat balance calculations is also developed to describe the self-preservation effect, which reproduces our simulation results well and provides an association between microscopic and macroscopic properties.

  4. Graphene Derivative in Magnetically Recoverable Catalyst Determines Catalytic Properties in Transfer Hydrogenation of Nitroarenes to Anilines with 2-Propanol.

    PubMed

    Das, Vijay Kumar; Mazhar, Sumaira; Gregor, Lennon; Stein, Barry D; Morgan, David Gene; Maciulis, Nicholas A; Pink, Maren; Losovyj, Yaroslav; Bronstein, Lyudmila M

    2018-06-14

    Here, we report transfer hydrogenation of nitroarenes to aminoarenes using 2-propanol as a hydrogen source and Ag-containing magnetically recoverable catalysts based on partially reduced graphene oxide (pRGO) sheets. X-ray diffraction and X-ray photoelectron spectroscopy data demonstrated that, during the one-pot catalyst synthesis, formation of magnetite nanoparticles (NPs) is accompanied by the reduction of graphene oxide (GO) to pRGO. The formation of Ag 0 NPs on top of magnetite nanoparticles does not change the pRGO structure. At the same time, the catalyst structure is further modified during the transfer hydrogenation, leading to a noticeable increase of sp 2 carbons. These carbons are responsible for the adsorption of substrate and intermediates, facilitating a hydrogen transfer from Ag NPs and creating synergy between the components of the catalyst. The nitroarenes with electron withdrawing and electron donating substituents allow for excellent yields of aniline derivatives with high regio and chemoselectivity, indicating that the reaction is not disfavored by these functionalities. The versatility of the catalyst synthetic protocol was demonstrated by a synthesis of an Ru-containing graphene derivative based catalyst, also allowing for efficient transfer hydrogenation. Easy magnetic separation and stable catalyst performance in the transfer hydrogenation make this catalyst promising for future applications.

  5. Hydrological regionalisation based on available hydrological information for runoff prediction at catchment scale

    NASA Astrophysics Data System (ADS)

    Li, Qiaoling; Li, Zhijia; Zhu, Yuelong; Deng, Yuanqian; Zhang, Ke; Yao, Cheng

    2018-06-01

    Regionalisation provides a way of transferring hydrological information from gauged to ungauged catchments. The past few decades has seen several kinds of regionalisation approaches for catchment classification and runoff predictions. The underlying assumption is that catchments having similar catchment properties are hydrological similar. This requires the appropriate selection of catchment properties, particularly the inclusion of observed hydrological information, to explain the similarity of hydrological behaviour. We selected observable catchments properties and flow duration curves to reflect the hydrological behaviour, and to regionalize rainfall-runoff response for runoff prediction. As a case study, we investigated 15 catchments located in the Yangtze and Yellow River under multiple hydro-climatic conditions. A clustering scheme was developed to separate the catchments into 4 homogeneous regions by employing catchment properties including hydro-climatic attributes, topographic attributes and land cover etc. We utilized daily flow duration curves as the indicator of hydrological response and interpreted hydrological similarity by root mean square errors. The combined analysis of similarity in catchment properties and hydrological response suggested that catchments in the same homogenous region were hydrological similar. A further validation was conducted by establishing a rainfall-runoff coaxial correlation diagram for each catchment. A common coaxial correlation diagram was generated for each homogenous region. The performances of most coaxial correlation diagrams met the national standard. The coaxial correlation diagram can be transferred within the homogeneous region for runoff prediction in ungauged catchments at an hourly time scale.

  6. 41 CFR 102-36.475 - What is the authority for transfers under “Computers for Learning”?

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... 41 Public Contracts and Property Management 3 2010-07-01 2010-07-01 false What is the authority... Property Management Federal Property Management Regulations System (Continued) FEDERAL MANAGEMENT... Technology Innovation Act of 1980, as amended (15 U.S.C. 3710(i)), authorizes federal agencies to transfer...

  7. 41 CFR 102-35.15 - What are the goals of GSA's personal property regulations?

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... to agencies where the transfer will avoid a new Federal procurement. A transfer to an agency where... donation of surplus personal property to State and local public agencies and other eligible non-Federal... personal property sold under the exchange/sale authority; and (e) Reduce management and inventory costs by...

  8. 26 CFR 25.2518-1 - Qualified disclaimers of property; in general.

    Code of Federal Regulations, 2011 CFR

    2011-04-01

    ... property. For rules relating to the determination of when a transfer creating an interest occurs, see § 25... retains the right to receive the income for life. Upon the death of W, which occurs after December 31, 1976, the trust property is distributable to W's surviving issue, per stirpes. The transfer creating...

  9. Image transfer properties by photonic crystal slab with negative refractive index

    NASA Astrophysics Data System (ADS)

    Chen, Hongbo; Chen, Xiaoshuang; Zhou, Renlong; Lu, Wei

    2008-04-01

    We have studied the properties of image transferred by photonic crystal (PhC) slab with negative refractive index n=-1 and confirmed the negative refractive phonomenon, but not found the saturated image properties as expected. It is found that real images will not be formed when the source distance larger than the thickness of PhC, and the transferred images are virtual images. Furthermore, comparing the quality of images transferred by a PhC slab and a cascaded stack of photonic crystal slab (CSPS), we found that the transferred images are distorted in both situations. The image resolution is good along the direction parallel to the slab interface, but bad along the direction normal to the slab interface. Simulation results show that the image formed by a CSPS is no better than a PhC slab.

  10. Charge transfer interactions and nonlinear optical properties of push pull chromophore benzaldehyde phenylhydrazone: A vibrational approach

    NASA Astrophysics Data System (ADS)

    Ravikumar, C.; Joe, I. Hubert; Jayakumar, V. S.

    2008-07-01

    FT Raman and IR spectra of the crystallized nonlinear optic (NLO) molecule, benzaldehyde phenylhydrazone (BPH) have been recorded and analyzed. The equilibrium geometry, bonding features and harmonic vibrational frequencies of BPH have been investigated with the help of B3LYP density functional theory (DFT) method. The assignments of the vibrational spectra have been carried out with the help of normal coordinate analysis (NCA) following the scaled quantum mechanical force field methodology (SQMFF). From the optimized geometry, the decrease in C-N bond length indicates the electron delocalization over the region of the molecule. The vibrational analysis confirm the charge transfer interaction between the phenyl rings through ≻Cdbnd N-N≺ skeleton.

  11. Machine learning for quantum dynamics: deep learning of excitation energy transfer properties

    DOE PAGES

    Häse, Florian; Kreisbeck, Christoph; Aspuru-Guzik, Alán

    2017-01-01

    Understanding the relationship between the structure of light-harvesting systems and their excitation energy transfer properties is of fundamental importance in many applications including the development of next generation photovoltaics.

  12. 41 CFR 302-3.203 - If I am transferring in the interest of the Government and my employed immediate family member(s...

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... 41 Public Contracts and Property Management 4 2010-07-01 2010-07-01 false If I am transferring in... Contracts and Property Management Federal Travel Regulation System RELOCATION ALLOWANCES RELOCATION ALLOWANCES 3-RELOCATION ALLOWANCE BY SPECIFIC TYPE Types of Transfers Relocation of Two Or More Employed...

  13. 41 CFR 302-3.203 - If I am transferring in the interest of the Government and my employed immediate family member(s...

    Code of Federal Regulations, 2013 CFR

    2013-07-01

    ... 41 Public Contracts and Property Management 4 2013-07-01 2012-07-01 true If I am transferring in... Contracts and Property Management Federal Travel Regulation System RELOCATION ALLOWANCES RELOCATION ALLOWANCES 3-RELOCATION ALLOWANCE BY SPECIFIC TYPE Types of Transfers Relocation of Two Or More Employed...

  14. 41 CFR 302-3.203 - If I am transferring in the interest of the Government and my employed immediate family member(s...

    Code of Federal Regulations, 2014 CFR

    2014-07-01

    ... 41 Public Contracts and Property Management 4 2014-07-01 2014-07-01 false If I am transferring in... Contracts and Property Management Federal Travel Regulation System RELOCATION ALLOWANCES RELOCATION ALLOWANCES 3-RELOCATION ALLOWANCE BY SPECIFIC TYPE Types of Transfers Relocation of Two Or More Employed...

  15. 41 CFR 302-3.203 - If I am transferring in the interest of the Government and my employed immediate family member(s...

    Code of Federal Regulations, 2011 CFR

    2011-07-01

    ... 41 Public Contracts and Property Management 4 2011-07-01 2011-07-01 false If I am transferring in... Contracts and Property Management Federal Travel Regulation System RELOCATION ALLOWANCES RELOCATION ALLOWANCES 3-RELOCATION ALLOWANCE BY SPECIFIC TYPE Types of Transfers Relocation of Two Or More Employed...

  16. 41 CFR 302-3.203 - If I am transferring in the interest of the Government and my employed immediate family member(s...

    Code of Federal Regulations, 2012 CFR

    2012-07-01

    ... 41 Public Contracts and Property Management 4 2012-07-01 2012-07-01 false If I am transferring in... Contracts and Property Management Federal Travel Regulation System RELOCATION ALLOWANCES RELOCATION ALLOWANCES 3-RELOCATION ALLOWANCE BY SPECIFIC TYPE Types of Transfers Relocation of Two Or More Employed...

  17. 26 CFR 1.367(d)-1T - Transfers of intangible property to foreign corporations (temporary).

    Code of Federal Regulations, 2014 CFR

    2014-04-01

    ... limited election to treat certain transfers of intangible property as sales at fair market value (in lieu... accordance with the provisions of section 482 and regulations thereunder. See § 1.482-2(d). The amount of the... United States in an amount equal to the difference between the fair market value of the transferred...

  18. 26 CFR 1.367(d)-1T - Transfers of intangible property to foreign corporations (temporary).

    Code of Federal Regulations, 2012 CFR

    2012-04-01

    ... limited election to treat certain transfers of intangible property as sales at fair market value (in lieu... accordance with the provisions of section 482 and regulations thereunder. See § 1.482-2(d). The amount of the... United States in an amount equal to the difference between the fair market value of the transferred...

  19. 26 CFR 1.367(d)-1T - Transfers of intangible property to foreign corporations (temporary).

    Code of Federal Regulations, 2013 CFR

    2013-04-01

    ... limited election to treat certain transfers of intangible property as sales at fair market value (in lieu... accordance with the provisions of section 482 and regulations thereunder. See § 1.482-2(d). The amount of the... United States in an amount equal to the difference between the fair market value of the transferred...

  20. EPA Guidance on the Transfer of Federal Property by Deed Before All Necessary Remedial Action Has Been Taken Pursuant to CERCLA Section 120(h)(3) -- (Early Transfer Authority Guidance)

    EPA Pesticide Factsheets

    This guidance addresses the transfer of real property listed on the National Priorities List (NPL) held by a federal agency where the release or disposal of hazardous substances has occurred, but where all necessary remedial action has not yet been taken.

  1. Nonparametric Transfer Function Models

    PubMed Central

    Liu, Jun M.; Chen, Rong; Yao, Qiwei

    2009-01-01

    In this paper a class of nonparametric transfer function models is proposed to model nonlinear relationships between ‘input’ and ‘output’ time series. The transfer function is smooth with unknown functional forms, and the noise is assumed to be a stationary autoregressive-moving average (ARMA) process. The nonparametric transfer function is estimated jointly with the ARMA parameters. By modeling the correlation in the noise, the transfer function can be estimated more efficiently. The parsimonious ARMA structure improves the estimation efficiency in finite samples. The asymptotic properties of the estimators are investigated. The finite-sample properties are illustrated through simulations and one empirical example. PMID:20628584

  2. Simultaneous observation of up/down conversion photoluminescence and colossal permittivity properties in (Er+Nb) co-doped TiO2 materials

    NASA Astrophysics Data System (ADS)

    Tse, Mei-Yan; Tsang, Ming-Kiu; Wong, Yuen-Ting; Chan, Yi-Lok; Hao, Jianhua

    2016-07-01

    We have investigated the optical and dielectric properties of rutile TiO2 doped with Nb and Er, i.e., (Er0.5Nb0.5)xTi1-xO2. The up/downconversion photoluminescence was observed in the visible and near-infrared region from the materials under 980 nm laser diode excitation. The upconversion emissions are attributed to the energy transfer between Er ions in the excited states. Moreover, the dielectric measurements indicate that the fabricated materials simultaneously present colossal permittivity properties with relatively low dielectric loss. Our work demonstrates the coexistence of both interesting luminescence and attractive dielectric characteristics in (Er+Nb) co-doped TiO2, showing the potential for multifunctional applications.

  3. Structures and Properties of Polymers Important to Their Wear Behavior

    NASA Technical Reports Server (NTRS)

    Tanaka, K.

    1984-01-01

    The wear and transfer of various semicrystalline polymers sliding against smooth steel or glass surfaces were examined. The effects of structures, and properties of polymers on their wear behavior are discussed. It is found that the high wear characteristics of PTFE is due to the easy destruction of the banded structure of PTFE. The size of spherulites and the molecular profile are closely related to the magnitude of wear rates of typical semicrystalline polymers. The effects of these factors on the wear rate on the basis of the destruction or melting of spherulites at the frictional surface are discussed. Although the fatigue theory of wear indicates that some mechanical properties are important to wear behavior, it is shown that the theory does not always explain the experimental result obtained on a smooth surface.

  4. Cell-printing and transfer technology applications for bone defects in mice.

    PubMed

    Tsugawa, Junichi; Komaki, Motohiro; Yoshida, Tomoko; Nakahama, Ken-ichi; Amagasa, Teruo; Morita, Ikuo

    2011-10-01

    Bone regeneration therapy based on the delivery of osteogenic factors and/or cells has received a lot of attention in recent years since the discovery of pluripotent stem cells. We reported previously that the implantation of capillary networks engineered ex vivo by the use of cell-printing technology could improve blood perfusion. Here, we developed a new substrate prepared by coating glass with polyethylene glycol (PEG) to create a non-adhesive surface and subsequent photo-lithography to finely tune the adhesive property for efficient cell transfer. We examined the cell-transfer efficiency onto amniotic membrane and bone regenerative efficiency in murine calvarial bone defect. Cell transfer of KUSA-A1 cells (murine osteoblasts) to amniotic membrane was performed for 1 h using the substrates. Cell transfer using the substrate facilitated cell engraftment onto the amniotic membrane compared to that by direct cell inoculation. KUSA-A1 cells transferred onto the amniotic membrane were applied to critical-sized calvarial bone defects in mice. Micro-computed tomography (micro-CT) analysis showed rapid and effective bone formation by the cell-equipped amniotic membrane. These results indicate that the cell-printing and transfer technology used to create the cell-equipped amniotic membrane was beneficial for the cell delivery system. Our findings support the development of a biologically stable and effective bone regeneration therapy. Copyright © 2011 John Wiley & Sons, Ltd.

  5. Fourier analysis of conductive heat transfer for glazed roofing materials

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Roslan, Nurhana Lyana; Bahaman, Nurfaradila; Almanan, Raja Noorliyana Raja

    For low-rise buildings, roof is the most exposed surface to solar radiation. The main mode of heat transfer from outdoor via the roof is conduction. The rate of heat transfer and the thermal impact is dependent on the thermophysical properties of roofing materials. Thus, it is important to analyze the heat distribution for the various types of roofing materials. The objectives of this paper are to obtain the Fourier series for the conductive heat transfer for two types of glazed roofing materials, namely polycarbonate and polyfilled, and also to determine the relationship between the ambient temperature and the conductive heatmore » transfer for these materials. Ambient and surface temperature data were collected from an empirical field investigation in the campus of Universiti Teknologi MARA Shah Alam. The roofing materials were installed on free-standing structures in natural ventilation. Since the temperature data are generally periodic, Fourier series and numerical harmonic analysis are applied. Based on the 24-point harmonic analysis, the eleventh order harmonics is found to generate an adequate Fourier series expansion for both glazed roofing materials. In addition, there exists a linear relationship between the ambient temperature and the conductive heat transfer for both glazed roofing materials. Based on the gradient of the graphs, lower heat transfer is indicated through polyfilled. Thus polyfilled would have a lower thermal impact compared to polycarbonate.« less

  6. Palm oil based nanofluids for enhancing heat transfer and rheological properties

    NASA Astrophysics Data System (ADS)

    Hussein, A. M.; Lingenthiran; Kadirgamma, K.; Noor, M. M.; Aik, L. K.

    2018-04-01

    Colloidal suspensions of nanomaterials size not more than 100 nm in basefluid are defined as nanofluids. The thermal and rheological properties study of oil based nanofluid is conducted to develop stable transformers palm oil based nanofluid. This paper describes the analysis techniques to determine the enhancement of thermal properties of nanofluids. Titanium dioxide (TiO2) has dispersed in the palm oil to prepare nanofluids with volume concentration (0.01-0.09) percentage. Both thermal conductivity and viscosity of nanofluid have measured by using the hot wire method and viscometer equipment respectively. Results indicate that the stable nanofluids improve the thermal properties as compared to palm oil. Results showed that the friction factor decreases as the Reynolds number increases and increases as the volume concentration increases. Additionally, the Nusselt number increases as the Reynolds number and volume concentration of the nanofluid increases.

  7. Assessment and validation of the community radiative transfer model for ice cloud conditions

    NASA Astrophysics Data System (ADS)

    Yi, Bingqi; Yang, Ping; Weng, Fuzhong; Liu, Quanhua

    2014-11-01

    The performance of the Community Radiative Transfer Model (CRTM) under ice cloud conditions is evaluated and improved with the implementation of MODIS collection 6 ice cloud optical property model based on the use of severely roughened solid column aggregates and a modified Gamma particle size distribution. New ice cloud bulk scattering properties (namely, the extinction efficiency, single-scattering albedo, asymmetry factor, and scattering phase function) suitable for application to the CRTM are calculated by using the most up-to-date ice particle optical property library. CRTM-based simulations illustrate reasonable accuracy in comparison with the counterparts derived from a combination of the Discrete Ordinate Radiative Transfer (DISORT) model and the Line-by-line Radiative Transfer Model (LBLRTM). Furthermore, simulations of the top of the atmosphere brightness temperature with CRTM for the Crosstrack Infrared Sounder (CrIS) are carried out to further evaluate the updated CRTM ice cloud optical property look-up table.

  8. Characterization of Fluid Transfer Properties in a Transpressive Fault System: Chaîne des Matheux Fold-and-Thrust Belt and Enriquillo-Plantain Garden Fault Zone - Haiti

    NASA Astrophysics Data System (ADS)

    Wessels, R.; Ellouz-Zimmermann, N.; Rosenberg, C.; Hamon, Y.; Battani, A.; Bellahsen, N.; Deschamps, R.; Leroy, S. D.; Momplaisir, R.

    2016-12-01

    The NW - SE trending Chaîne des Matheux (CdM) comprises the onshore frontal thrust sheet of the SW-verging Haitian fold-and-thrust belt (HFTB). The HFTB's active deformation front is covered by sediments of the Cul-de-Sac plain and is bounded on the south by the E - W trending left-lateral Enriquillo-Plantain Garden fault zone (EPGFZ). Seismicity down to the junction between the two systems has been recorded during the 12 January 2010 Mw 7.0 Léogâne earthquake. Stratigraphic, structural and kinematic field data on a transect from the CdM to the EPGFZ indicate (N)NE - (S)SW oriented shortening, which is partitioned over 1) (N)NE-dipping oblique thrusts rooted in Cretaceous basement, 2) decollement levels in both latest Cretaceous and Paleogene limestones, and 3) by strike-slip and positive flower structures along the EPGFZ. We investigated the geometry and kinematics of both fault and fracture systems, which was coupled with sampling and analysis of fluid-derived mineralizations to constrain the timing and geological evolution. C & O isotope and whole-rock analyses have been performed to characterize the geochemistry of the source of these fluids. Raman spectroscopy and fluid-inclusion analyses has been applied to selected samples to comprehend the local burial history. Fluid and gas seepages along fault planes are qualitative indicators for transfer properties between different fault segments and their connectivity with deeper crustal or mantle reservoirs. Relative timing of structures in the CdM coupled with cathodoluminescence (CL) microscopy reveals three deformation phases, characterized by associated calcite veins that precipitated from oxidizing meteoric fluids. The deeply rooted frontal CdM thrust lacks mineralization, but fluids expelled from along-strike natural springs registered He and Ne isotope ratios suggesting a strong mantle-derived component. CL microscopy results on calcite veins from the EPGFZ's fault core imply fluid circulation in an episodically `open' system under a reducing environment. He and Ne isotope ratios from fluids derived along the EPGFZ suggest a significant, but less pronounced, mantle-derived component compared to the frontal thrust of the CdM. The above results indicate a change in fluid transfer properties over time for this transpressive system.

  9. Computational study of heat transfer in gas fluidization

    NASA Astrophysics Data System (ADS)

    Hou, Q. F.; Zhou, Z. Y.; Yu, A. B.

    2013-06-01

    Heat transfer in gas fluidization is investigated at a particle scale by means of a combined discrete element method and computational fluid dynamicsapproach. To develop understanding of heat transfer at various conditions, the effects of a few important material properties such as particle size, the Hamaker constant and particle thermal conductivity are examined through controlled numerical experiments. It is found that the convective heat transfer is dominant, and radiative heat transfer becomes important when the temperature is high. Conductive heat transfer also plays a role depending on the flow regimes and material properties. The heat transfer between a fluidized bed and an immersed surface is enhanced by the increase of particle thermal conductivity while it is little affected by Young's modulus. The findings should be useful for better understanding and predicting the heat transfer in gas fluidization.

  10. 31 CFR 585.202 - Effect of transfers violating the provisions of this part.

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... authorization hereunder and involves any property or interest in property blocked pursuant to § 585.201 is null... hereunder. (d) Transfers of property which otherwise would be null and void or unenforceable by virtue of the provisions of this section shall not be deemed to be null and void or unenforceable as to any...

  11. Decree No. 2001, 28 September 1988.

    PubMed

    1988-01-01

    This Decree regulates the establishment of indigenous reservations in Colombia. Under the Decree, an indigenous reservation is a legal institution constituted by the transfer to an indigenous community of title to the property where the community is situated or where it will be located. The property may be cultivated or uncultivated. The Decree sets forth the requirements for qualifying for the transfer of such land. Before the land is transferred, the Colombian Institute for Agricultural Reform is to monitor and review the proposed reservation. It is to undertake a socioeconomic and legal study of the indigenous community and to ascertain the community's origins, institutions, customs, and property claims. It is also to address the property claims of third parties. full text

  12. 41 CFR 102-75.545 - What happens if property that was transferred to meet an educational or public health requirement...

    Code of Federal Regulations, 2014 CFR

    2014-01-01

    ... that was transferred to meet an educational or public health requirement is revested in the United... Educational and Public Health Purposes § 102-75.545 What happens if property that was transferred to meet an educational or public health requirement is revested in the United States for noncompliance with the terms of...

  13. 41 CFR 102-75.545 - What happens if property that was transferred to meet an educational or public health requirement...

    Code of Federal Regulations, 2012 CFR

    2012-01-01

    ... that was transferred to meet an educational or public health requirement is revested in the United... Educational and Public Health Purposes § 102-75.545 What happens if property that was transferred to meet an educational or public health requirement is revested in the United States for noncompliance with the terms of...

  14. 41 CFR 102-75.545 - What happens if property that was transferred to meet an educational or public health requirement...

    Code of Federal Regulations, 2013 CFR

    2013-07-01

    ... that was transferred to meet an educational or public health requirement is revested in the United... Educational and Public Health Purposes § 102-75.545 What happens if property that was transferred to meet an educational or public health requirement is revested in the United States for noncompliance with the terms of...

  15. 26 CFR 1.642(c)-6 - Valuation of a remainder interest in property transferred to a pooled income fund.

    Code of Federal Regulations, 2010 CFR

    2010-04-01

    ... transferred to a pooled income fund. 1.642(c)-6 Section 1.642(c)-6 Internal Revenue INTERNAL REVENUE SERVICE, DEPARTMENT OF THE TREASURY (CONTINUED) INCOME TAX (CONTINUED) INCOME TAXES Estates, Trusts, and Beneficiaries § 1.642(c)-6 Valuation of a remainder interest in property transferred to a pooled income fund. (a) In...

  16. 26 CFR 1.642(c)-6 - Valuation of a remainder interest in property transferred to a pooled income fund.

    Code of Federal Regulations, 2011 CFR

    2011-04-01

    ... transferred to a pooled income fund. 1.642(c)-6 Section 1.642(c)-6 Internal Revenue INTERNAL REVENUE SERVICE, DEPARTMENT OF THE TREASURY (CONTINUED) INCOME TAX (CONTINUED) INCOME TAXES (CONTINUED) Estates, Trusts, and Beneficiaries § 1.642(c)-6 Valuation of a remainder interest in property transferred to a pooled income fund. (a...

  17. Two-dimensional finite element heat transfer model of softwood. Part III, Effect of moisture content on thermal conductivity

    Treesearch

    Hongmei Gu; John F. Hunt

    2007-01-01

    The anisotropy of wood creates a complex problem for solving heat and mass transfer problems that require analyses be based on fundamental material properties of the wood structure. Most heat transfer models for softwood use average thermal properties across either the radial or tangential direction and do not differentiate the effects of cellular alignment or...

  18. 26 CFR 1.1041-1T - Treatment of transfer of property between spouses or incident to divorce (temporary).

    Code of Federal Regulations, 2011 CFR

    2011-04-01

    ... spouses or incident to divorce (temporary). 1.1041-1T Section 1.1041-1T Internal Revenue INTERNAL REVENUE... Nontaxable Exchanges § 1.1041-1T Treatment of transfer of property between spouses or incident to divorce... benefit of) a spouse or, if the transfer is incident to a divorce, a former spouse. The following...

  19. 26 CFR 1.1041-1T - Treatment of transfer of property between spouses or incident to divorce (temporary).

    Code of Federal Regulations, 2013 CFR

    2013-04-01

    ... spouses or incident to divorce (temporary). 1.1041-1T Section 1.1041-1T Internal Revenue INTERNAL REVENUE... Nontaxable Exchanges § 1.1041-1T Treatment of transfer of property between spouses or incident to divorce... benefit of) a spouse or, if the transfer is incident to a divorce, a former spouse. The following...

  20. 26 CFR 1.1041-1T - Treatment of transfer of property between spouses or incident to divorce (temporary).

    Code of Federal Regulations, 2014 CFR

    2014-04-01

    ... spouses or incident to divorce (temporary). 1.1041-1T Section 1.1041-1T Internal Revenue INTERNAL REVENUE... Nontaxable Exchanges § 1.1041-1T Treatment of transfer of property between spouses or incident to divorce... benefit of) a spouse or, if the transfer is incident to a divorce, a former spouse. The following...

  1. 26 CFR 1.1041-1T - Treatment of transfer of property between spouses or incident to divorce (temporary).

    Code of Federal Regulations, 2012 CFR

    2012-04-01

    ... spouses or incident to divorce (temporary). 1.1041-1T Section 1.1041-1T Internal Revenue INTERNAL REVENUE... Nontaxable Exchanges § 1.1041-1T Treatment of transfer of property between spouses or incident to divorce... benefit of) a spouse or, if the transfer is incident to a divorce, a former spouse. The following...

  2. 41 CFR 102-75.545 - What happens if property that was transferred to meet an educational or public health requirement...

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... that was transferred to meet an educational or public health requirement is revested in the United... Educational and Public Health Purposes § 102-75.545 What happens if property that was transferred to meet an educational or public health requirement is revested in the United States for noncompliance with the terms of...

  3. 41 CFR 102-75.545 - What happens if property that was transferred to meet an educational or public health requirement...

    Code of Federal Regulations, 2011 CFR

    2011-01-01

    ... that was transferred to meet an educational or public health requirement is revested in the United... Educational and Public Health Purposes § 102-75.545 What happens if property that was transferred to meet an educational or public health requirement is revested in the United States for noncompliance with the terms of...

  4. Sensory methods and electronic nose as innovative tools for the evaluation of the aroma transfer properties of food plastic bags.

    PubMed

    Torri, Luisa; Piochi, Maria

    2016-07-01

    Despite the key role of the sensory quality for food acceptance, the aroma transfer properties of food packaging materials have not yet been studied using sensory approaches. This research investigated the suitability of sensory and electronic nose methods to evaluate the aroma transfer properties of plastic materials that come in contact with food. Four (W, X, Y, and Z) commercial freezer bags (polyethylene) for domestic uses were compared. The degree of the aroma transfer through the materials was estimated as the sensory contamination of an odor absorber food (bread) by an odor releaser food (onion), separated by the bags and stored under frozen conditions. Bread samples were analyzed by means of an electronic nose, and 42 assessors used three different sensory methods (triangle, scoring, and partial sorted Napping tests). From the triangle test, none of the plastic bags acted as a complete aroma barrier, showing a sensory contamination of bread stored in all four materials. Partial sorting Napping results clearly described the sensory contamination of bread as "onion flavor", due to the aroma transfer from the odor releaser food to the odor absorber food through the plastic bag. Scoring tests showed significant (p<0.0001) differences of aroma transfer properties among the plastic bags, revealing the highest aroma permeation for W (3.1±0.1), the lowest aroma transfer for X and Y (2.0±0.1), and intermediate aroma transfer properties for Z (2.6±0.1). Electronic nose data were in good agreement with the sensory responses, and a high correlation with the scoring data was observed (R 2 =0.988). The presented approaches had suitable results to provide meaningful information on the aroma transfer properties of freezer plastic bags, and could advantageously be applied in the future for analyzing other finished food containers (e.g. plastic trays, boxes, etc.) or packaging materials of a different nature (multilayer plastic films, biodegradable materials, composites, etc.). Copyright © 2016 Elsevier Ltd. All rights reserved.

  5. Synthesis, photophysical and electrochemical properties of a blue emitter with binaphthalene and carbazole units.

    PubMed

    Guo, Lixia; Wang, Xiaoju; Feng, Liheng

    2018-08-05

    A blue emitter, 3,3'-(2,2'-dimethoxy-[1,1'-binaphthalene]-6,6'-diyl)bis(9-benzyl-9H-carbazole), was synthesized by Suzuki coupling reaction. The photophysical properties of the emitter in solution were firstly investigated by UV-Vis absorption and fluorescence emission techniques. The results indicate that the emitter has excellent optical and electron transfer properties. The maximum absorption and emission peaks of the emitter are 302 nm and 406 nm with 67.4% fluorescence quantum yield in chloroform, respectively. Thermal stability study reveals that the emitter has a good thermal stability (Td > 330 °C, Tg > 160 °C). Electrochemical Redox properties of the emitters were measured by cyclic voltammetry, and the energy gaps of highest occupied molecular orbital and the lowest unoccupied molecular orbital levels are in good agreement with the results of theoretical calculation. Furthermore, the multilayer electrochemcial device with the emitter was fabricated and its properties were explored. The wavelength of electroluminescence for the device with this emitter locates at 428 nm. These results indicate the emitter as a deep blue-emitting material has promising application in organic light-emitting diode devices. Copyright © 2018 Elsevier B.V. All rights reserved.

  6. [Conceptual foundations of creation of branch database of technology and intellectual property rights owned by scientific institutions, organizations, higher medical educational institutions and enterprises of healthcare sphere of Ukraine].

    PubMed

    Horban', A Ie

    2013-09-01

    The question of implementation of the state policy in the field of technology transfer in the medical branch to implement the law of Ukraine of 02.10.2012 No 5407-VI "On Amendments to the law of Ukraine" "On state regulation of activity in the field of technology transfers", namely to ensure the formation of branch database on technology and intellectual property rights owned by scientific institutions, organizations, higher medical education institutions and enterprises of healthcare sphere of Ukraine and established by budget are considered. Analysis of international and domestic experience in the processing of information about intellectual property rights and systems implementation support transfer of new technologies are made. The main conceptual principles of creation of this branch database of technology transfer and branch technology transfer network are defined.

  7. Numerical investigation of porous materials composites reinforced with natural fibers

    NASA Astrophysics Data System (ADS)

    Chikhi, M.; Metidji, N.; Mokhtari, F.; Merzouk, N. k.

    2018-05-01

    The present article tends to predict the effective thermal properties of porous biocomposites materials. The composites matrix consists on porous materials namely gypsum and the reinforcement is a natural fiber as date palm fibers. The numerical study is done using Comsol software resolving the heat transfer equation. The results are fitted with theoretical model and experimental results. The results of this study indicate that the porosity has an effect on the Effective thermal conductivity biocompoites.

  8. Luminescent properties of Eu{sup 2+}-doped BaGdF{sub 5} glass ceramics a potential blue phosphor for ultra-violet light-emitting diode

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Zhang, Weihuan; Zhang, Yuepin, E-mail: zhangyuepin@nbu.edu.cn; Ouyang, Shaoye

    2015-01-14

    Eu{sup 2+} doped transparent oxyfluoride glass ceramics containing BaGdF{sub 5} nanocrystals were successfully fabricated by melt-quenching technique under a reductive atmosphere. The structure of the glass and glass ceramics were investigated by differential scanning calorimetry, X-ray diffraction (XRD), and transmission electron microscopy (TEM). The luminescent properties were investigated by transmission, excitation, and emission spectra. The decay time of the Gd{sup 3+} ions at 312 nm excited with 275 nm were also investigated. The results of XRD and TEM indicated the existence of BaGdF5 nanocrystals in the transparent glass ceramics. The excitation spectra of Eu{sup 2+} doped glass ceramics showed an excellent overlapmore » with the main emission region of an ultraviolet light-emitting diode (UV-LED). Compared with the as-made glass, the emission of glass ceramics is much stronger by a factor of increasing energy transfer efficiency from Gd{sup 3+} to Eu{sup 2+} ions, the energy transfer efficiency from Gd{sup 3+} to Eu{sup 2+} ions was discussed. In addition, the chromaticity coordinates of glass and glass ceramics specimens were also discussed, which indicated that the Eu{sup 2+} doped BaGdF{sub 5} glass ceramics may be used as a potential blue-emitting phosphor for UV-LED.« less

  9. Film Boiling Heat Transfer Properties of Liquid Hydrogen in Natural Convection

    NASA Astrophysics Data System (ADS)

    Horie, Y.; Shirai, Y.; Shiotsu, M.; Matsuzawa, T.; Yoneda, K.; Shigeta, H.; Tatsumoto, H.; Hata, K.; Naruo, Y.; Kobayashi, H.; Inatani, Y.

    Film boiling heat transfer properties of LH2 for various pressures and subcooling conditions were measured by applying electric current to give an exponential heat input to a PtCo wire with a diameter of 1.2 mm submerged in LH2. The heated wire was set to be horizontal to the ground. The heat transfer coefficient in the film boiling region was higher for higher pressure and higher subcooling. The experimental results are compared with the equation of pool film boiling heat transfer. It is confirmed that the pool film boiling heat transfer coefficients in LH2 can be expressed by this equation.

  10. Estimated effects on water quality of Lake Houston from interbasin transfer of water from the Trinity River, Texas

    USGS Publications Warehouse

    Liscum, Fred; East, Jeffery W.

    2000-01-01

    The City of Houston is considering the transfer of water from the Trinity River to Lake Houston (on the San Jacinto River) to alleviate concerns about adequate water supplies for future water demands. The U.S. Geological Survey, in cooperation with the City of Houston, conducted a study to estimate the effects on the water quality of Lake Houston from the transfer of Trinity River water. A water-quality model, CE–QUAL–W2, was used to simulate six water-quality properties and constituents for scenarios of interbasin transfer of Trinity River water. Three scenarios involved the transferred Trinity River water augmenting streamflow in the East Fork of Lake Houston, and three scenarios involved the transferred water replacing streamflow from the West Fork of the San Jacinto River.The estimated effects on Lake Houston were determined by comparing volume-weighted daily mean water temperature, phosphorus, ammonia nitrogen, nitrite plus nitrate nitrogen, algal biomass, and dissolved oxygen simulated for each of the transfer scenarios to simulations for a base dataset. The effects of the interbasin transfer on Lake Houston do not appear to be detrimental to water temperature, ammonia nitrogen, or dissolved oxygen. Phosphorus and nitrite plus nitrate nitrogen showed fairly large changes when Trinity River water was transferred to replace West Fork San Jacinto River streamflow. Algal biomass showed large decreases when Trinity River water was transferred to augment East Fork Lake Houston streamflow and large increases when Trinity River water was transferred to replace West Fork San Jacinto River streamflow. Regardless of the scenario simulated, the model indicated that light was the limiting factor for algal biomass growth.

  11. Coupling radiative heat transfer in participating media with other heat transfer modes

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Tencer, John; Howell, John R.

    The common methods for finding the local radiative flux divergence in participating media through solution of the radiative transfer equation are outlined. The pros and cons of each method are discussed in terms of their speed, ability to handle spectral properties and scattering phenomena, as well as their accuracy in different ranges of media transport properties. The suitability of each method for inclusion in the energy equation to efficiently solve multi-mode thermal transfer problems is discussed. Lastly, remaining topics needing research are outlined.

  12. Coupling radiative heat transfer in participating media with other heat transfer modes

    DOE PAGES

    Tencer, John; Howell, John R.

    2015-09-28

    The common methods for finding the local radiative flux divergence in participating media through solution of the radiative transfer equation are outlined. The pros and cons of each method are discussed in terms of their speed, ability to handle spectral properties and scattering phenomena, as well as their accuracy in different ranges of media transport properties. The suitability of each method for inclusion in the energy equation to efficiently solve multi-mode thermal transfer problems is discussed. Lastly, remaining topics needing research are outlined.

  13. Understanding the Effect of Gas Dynamics in Plasma Gun Performance for Simulating Fusion Wall Response to Disruption Events

    NASA Astrophysics Data System (ADS)

    Riedel, Will; Underwood, Thomas; Righetti, Fabio; Cappelli, Mark

    2017-10-01

    In this work, the suitability of a pulsed coaxial plasma accelerator to simulate the interaction of edge-localized modes with plasma first wall materials is investigated. Experimental measurements derived from a suite of diagnostics are presented that focus on both the properties of the plasma flow and the manner in which such jets couple with material interfaces. Specific emphasis is placed on quantifying the variation in these properties using tungsten tokens exposed to the plasma plume as the gun volume is progressively filled with more neutral gas. These results are mapped to the operational dynamics of the gun via a time-resolved Schlieren cinematic visualization of the density gradient within the flow. Resulting videos indicate the existence of two distinct modes with vastly different characteristic timescales, spatial evolution, and plasma properties. Time resolved quantification of the associated plasma heat flux for both modes, including a range spanning 150 MW m-2 - 10 GW m-2, is presented using both a fast thermocouple gauge and an IR camera. Both diagnostics in conjunction with a heat transfer model provide an accurate description of the energy transfer dynamics and operational characteristics of plasma guns. This work is supported by the U.S. Department of Energy Stewardship Science Academic Program.

  14. Edible moisture barriers: how to assess of their potential and limits in food products shelf-life extension?

    PubMed

    Bourlieu, C; Guillard, V; Vallès-Pamiès, B; Guilbert, S; Gontard, N

    2009-05-01

    Control of moisture transfer inside composite food products or between food and its environment remains today a major challenge in food preservation. A wide rage of film-forming compounds is now available and facilitates tailoring moisture barriers with optimized functional properties. Despite these huge potentials, a realistic assessment of the film or coating efficacy is still critical. Due to nonlinear water sorption isotherms, water-dependent diffusivities, and variations of physical state, modelling transport phenomena through edible barriers is complex. Water vapor permeability can hardly be considered as an inherent property of films and only gives a relative indication of the barrier efficacy. The formal or mechanistic models reported in literature that describe the influence of testing conditions on the barrier properties of edible films are reviewed and discussed. Most of these models have been validated on a narrow range of conditions. Conversely, few original predictive models based on Fick's Second Law have been developed to assess shelf-life extension of food products including barriers. These models, assuming complex and realistic hypothesis, have been validated in various model foods. The development of nondestructive methods of moisture content measurement should speed up model validation and allow a better comprehension of moisture transfer through edible films.

  15. Hydrogen Bonding Stabilized Self-Assembly of Inorganic Nanoparticles: Mechanism and Collective Properties.

    PubMed

    Yue, Mingli; Li, Yanchun; Hou, Ying; Cao, Wenxin; Zhu, Jiaqi; Han, Jiecai; Lu, Zhongyuan; Yang, Ming

    2015-06-23

    Developing a simple and efficient method to organize nanoscale building blocks into ordered superstructures, understanding the mechanism for self-assembly and revealing the essential collective properties are crucial steps toward the practical use of nanostructures in nanotechnology-based applications. In this study, we showed that the high-yield formation of ZnO nanoparticle chains with micrometer length can be readily achieved by the variation of solvents from methanol to water. Spectroscopic studies confirmed the solvent effect on the surface properties of ZnO nanoparticles, which were found to be critical for the formation of anisotropic assemblies. Quantum mechanical calculations and all atom molecular dynamic simulations indicated the contribution of hydrogen bonding for stabilizing the structure in water. Dissipative particle dynamics further revealed the importance of solvent-nanoparticle interactions for promoting one-dimensional self-assembly. The branching of chains was found upon aging, resulting in the size increase of the ensembles and network formation. Steady-state and time-resolved luminescent spectroscopes, which probed the variation of defect-related emission, revealed stronger Forster resonance energy transfer (FRET) between nanoparticles when the chain networks were formed. The high efficiency of FRET quenching can be ascribed to the presence of multiple energy transfer channels, as well as the short internanoparticle distances and the dipole alignment.

  16. An integrated fiber-optic probe combined with support vector regression for fast estimation of optical properties of turbid media.

    PubMed

    Zhou, Yang; Fu, Xiaping; Ying, Yibin; Fang, Zhenhuan

    2015-06-23

    A fiber-optic probe system was developed to estimate the optical properties of turbid media based on spatially resolved diffuse reflectance. Because of the limitations in numerical calculation of radiative transfer equation (RTE), diffusion approximation (DA) and Monte Carlo simulations (MC), support vector regression (SVR) was introduced to model the relationship between diffuse reflectance values and optical properties. The SVR models of four collection fibers were trained by phantoms in calibration set with a wide range of optical properties which represented products of different applications, then the optical properties of phantoms in prediction set were predicted after an optimal searching on SVR models. The results indicated that the SVR model was capable of describing the relationship with little deviation in forward validation. The correlation coefficient (R) of reduced scattering coefficient μ'(s) and absorption coefficient μ(a) in the prediction set were 0.9907 and 0.9980, respectively. The root mean square errors of prediction (RMSEP) of μ'(s) and μ(a) in inverse validation were 0.411 cm(-1) and 0.338 cm(-1), respectively. The results indicated that the integrated fiber-optic probe system combined with SVR model were suitable for fast and accurate estimation of optical properties of turbid media based on spatially resolved diffuse reflectance. Copyright © 2015 Elsevier B.V. All rights reserved.

  17. Numerical Study on the Thermal Stress and its Formation Mechanism of a Thermoelectric Device

    NASA Astrophysics Data System (ADS)

    Pan, Tao; Gong, Tingrui; Yang, Wei; Wu, Yongjia

    2018-06-01

    The strong thermo-mechanical stress is one of the most critical failure mechanisms that affect the durability of thermoelectric devices. In this study, numerical simulations on the formation mechanism of the maximum thermal stress inside the thermoelectric device have been performed by using finite element method. The influences of the material properties and the thermal radiation on the thermal stress have been examined. The results indicate that the maximum thermal stress was located at the contact position between the two materials and occurred due to differential thermal expansions and displacement constraints of the materials. The difference in the calculated thermal stress value between the constant and the variable material properties was between 3% and 4%. At a heat flux of 1 W·cm-2 and an emissivity of 0.5, the influence of the radiation heat transfer on the thermal stress was only about 5%; however, when the heat flux was 20 W·cm-2 and the emissivity was 0.7, the influence of the radiation heat transfer was more than 30%.

  18. A detailed study of intermolecular interactions, electronic and vibrational properties of the metal complex bis(uracilato)diammine copper(ii) dihydrate

    NASA Astrophysics Data System (ADS)

    Gramajo Feijoo, M.; Fernández-Liencres, M. P.; Gil, D. M.; Gómez, M. I.; Ben Altabef, A.; Navarro, A.; Tuttolomondo, M. E.

    2018-03-01

    Density Functional Theory (DFT) calculations were performed with the aim of investigating the vibrational, electronic and structural properties of [Cu(uracilato-N1)2 (NH3)2]ṡ2H2O complex. The IR and Raman spectra were recorded leading to a complete analysis of the normal modes of vibration of the metal complex. A careful study of the intermolecular interactions observed in solid state was performed by using the Hirshfeld surface analysis and their associated 2D fingerprint plots. The results indicated that the crystal packing is stabilized by Nsbnd H⋯O hydrogen bonds and π-stacking interactions. In addition, Csbnd H···π interactions were also observed. Time-dependent density functional theory (TD-DFT) calculations revealed that all the low-lying electronic states correspond to a mixture of intraligand charge transfer (ILCT) and ligand-to-metal charge transfer (LMCT) transitions. Finally, Natural Bond Orbital (NBO) and Atoms in Molecules (AIM) analysis were performed to shed light on the intermolecular interactions in the coordination sphere.

  19. Effects of the charge-transfer reorganization energy on the open-circuit voltage in small-molecular bilayer organic photovoltaic devices: comparison of the influence of deposition rates of the donor.

    PubMed

    Lee, Chih-Chien; Su, Wei-Cheng; Chang, Wen-Chang

    2016-05-14

    The theoretical maximum of open-circuit voltage (VOC) of organic photovoltaic (OPV) devices has yet to be determined, and its origin remains debated. Here, we demonstrate that VOC of small-molecule OPV devices can be improved by controlling the deposition rate of a donor without changing the interfacial energy gap at the donor/acceptor interface. The measurement of external quantum efficiency and electroluminescence spectra facilitates the observation of the existence of charge transfer (CT) states. A simplified approach by reusing the reciprocity relationship for obtaining the properties of the CT states is proposed without introducing complex techniques. We compare experimental and fitting results and propose that reorganization energy is the primary factor in determining VOC instead of either the CT energy or electronic coupling term in bilayer OPV devices. Atomic force microscopy images indicate a weak molecular aggregation when a higher deposition rate is used. The results of temperature-dependent measurements suggest the importance of molecular stacking for the CT properties.

  20. Influence of Gd3+ concentration on luminescence properties of Eu3+ ions in sol-gel materials

    NASA Astrophysics Data System (ADS)

    Szpikowska-Sroka, Barbara; Pawlik, Natalia; Pisarski, Wojciech A.

    2016-12-01

    The sol-gel powders doubly-doped with Gd3+/Eu3+ ions with different concentration of Gd3+ have been successfully obtained. The spectroscopic characterization of prepared samples was conducted based on excitation and emission spectra as well as luminescence decay analysis. Upon direct excitation of Eu3+ active ions, the characteristic 5D0 → 7F1 (orange) and 5D0 → 7F2 (red) emission bands were observed. The energy transfer from Gd3+ to Eu3+ ions was registered upon λexc = 273 nm excitation. An efficient conversion of ultraviolet radiation (UV) into visible luminescence was successfully observed. The energy transfer process from Gd3+ to Eu3+ led to longer luminescence decay from the 5D0 state in comparison to that obtained under direct excitation of Eu3+ ions (λexc = 393 nm). Generally, obtained results clearly indicated the beneficial influence of increasing concentration of Gd3+ ions on luminescence properties of Eu3+ in studied silica sol-gel phosphors.

  1. Dispersion properties of plasma cladded annular optical fiber

    NASA Astrophysics Data System (ADS)

    KianiMajd, M.; Hasanbeigi, A.; Mehdian, H.; Hajisharifi, K.

    2018-05-01

    One of the considerable problems in a conventional image transferring fiber optic system is the two-fold coupling of propagating hybrid modes. In this paper, using a simple and practical analytical approach based on exact modal vectorial analysis together with Maxwell's equations, we show that applying plasma as a cladding medium of an annular optical fiber can remove this defect of conventional fiber optic automatically without any external instrument as the polarization beam splitter. Moreover, the analysis indicates that the presence of plasma in the proposed optical fiber could extend the possibilities for controlling the propagation property. The proposed structure presents itself as a promising route to advanced optical processing and opens new avenues in applied optics and photonics.

  2. High pressure and temperature induced structural and elastic properties of lutetium chalcogenides

    NASA Astrophysics Data System (ADS)

    Shriya, S.; Kinge, R.; Khenata, R.; Varshney, Dinesh

    2018-04-01

    The high-pressure structural phase transition and pressure as well temperature induced elastic properties of rock salt to CsCl structures in semiconducting LuX (X = S, Se, and Te) chalcogenides compound have been performed using effective interionic interaction potential with emphasis on charge transfer interactions and covalent contribution. Estimated values of phase transition pressure and the volume discontinuity in pressure-volume phase diagram indicate the structural phase transition from ZnS to NaCl structure. From the investigations of elastic constants the pressure (temperature) dependent volume collapse/expansion, melting temperature TM, Hardness (HV), and young modulus (E) the LuX lattice infers mechanical stiffening, and thermal softening.

  3. Effect of Various Material Properties on the Adhesive Stage of Fretting

    NASA Technical Reports Server (NTRS)

    Buckley, D. H.

    1974-01-01

    Various properties of metals and alloys were studied with respect to their effect on the initial stage of the fretting process, namely adhesion. Crystallographic orientation, crystal structure, interfacial binding energies of dissimiliar metal, segregation of alloy constituents and the nature and structure of surface films were found to influence adhesion. High atomic density, low surface energy grain orientations exhibited lower adhesion than other orientations. Knowledge of interfacial surface binding energies assists in predicting adhesive transfer and wear. Selective surface segregation of alloy constituents accomplishes both a reduction in adhesion and improved surface oxidation characteristics. Equivalent surface coverages of various adsorbed species indicate that some are markedly more effective in inhibiting adhesion than others.

  4. MODELING FUNCTIONALLY GRADED INTERPHASE REGIONS IN CARBON NANOTUBE REINFORCED COMPOSITES

    NASA Technical Reports Server (NTRS)

    Seidel, G. D.; Lagoudas, D. C.; Frankland, S. J. V.; Gates, T. S.

    2006-01-01

    A combination of micromechanics methods and molecular dynamics simulations are used to obtain the effective properties of the carbon nanotube reinforced composites with functionally graded interphase regions. The multilayer composite cylinders method accounts for the effects of non-perfect load transfer in carbon nanotube reinforced polymer matrix composites using a piecewise functionally graded interphase. The functional form of the properties in the interphase region, as well as the interphase thickness, is derived from molecular dynamics simulations of carbon nanotubes in a polymer matrix. Results indicate that the functional form of the interphase can have a significant effect on all the effective elastic constants except for the effective axial modulus for which no noticeable effects are evident.

  5. Proceedings of radiological health symposium

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Doi, K.; Holje, G.; Loo, L.N.

    Resolution (or sharpness) of radiographic screen-film systems influences the physical image quality of radiographs, and thereby the diagnositc accuracy and patient exposure. We use the modulation transfer function (MTF) to quantify the resolution property of screen-film systems. In our laboratory, the slit method and the digital Fourier transformation are used for measurements of the MTFs of screen-film systems. Recent measurements indicate that the MTFs of Detail, Par Speed, and Hi-Plus screens with XRP film are significantly lower than the MTFs of the same screens with Blue Brand film. This result underscores the need to evaluate the resolution property of screen-filmmore » systems with close attention to the x-ray film used.« less

  6. Transport properties of electrons in fractal magnetic-barrier structures

    NASA Astrophysics Data System (ADS)

    Sun, Lifeng; Fang, Chao; Guo, Yong

    2010-09-01

    Quantum transport properties in fractal magnetically modulated structures are studied by the transfer-matrix method. It is found that the transmission spectra depend sensitively not only on the incident energy and the direction of the wave vector but also on the stage of the fractal structures. Resonance splitting, enhancement, and position shift of the resonance peaks under different magnetic modulation are observed at four different fractal stages, and the relationship between the conductance in the fractal structure and magnetic modulation is also revealed. The results indicate the spectra of the transmission can be considered as fingerprints for the fractal structures, which show the subtle correspondence between magnetic structures and transport behaviors.

  7. 41 CFR 102-75.540 - Who is responsible for enforcing compliance with the terms and conditions of the transfer for...

    Code of Federal Regulations, 2014 CFR

    2014-01-01

    ... 41 Public Contracts and Property Management 3 2014-01-01 2014-01-01 false Who is responsible for enforcing compliance with the terms and conditions of the transfer for educational or public health purposes... Real Property Disposal Property for Educational and Public Health Purposes § 102-75.540 Who is...

  8. 41 CFR 102-75.540 - Who is responsible for enforcing compliance with the terms and conditions of the transfer for...

    Code of Federal Regulations, 2012 CFR

    2012-01-01

    ... 41 Public Contracts and Property Management 3 2012-01-01 2012-01-01 false Who is responsible for enforcing compliance with the terms and conditions of the transfer for educational or public health purposes... Real Property Disposal Property for Educational and Public Health Purposes § 102-75.540 Who is...

  9. 41 CFR 102-75.540 - Who is responsible for enforcing compliance with the terms and conditions of the transfer for...

    Code of Federal Regulations, 2013 CFR

    2013-07-01

    ... 41 Public Contracts and Property Management 3 2013-07-01 2013-07-01 false Who is responsible for enforcing compliance with the terms and conditions of the transfer for educational or public health purposes... Real Property Disposal Property for Educational and Public Health Purposes § 102-75.540 Who is...

  10. 26 CFR 1.367(d)-1T - Transfers of intangible property to foreign corporations (temporary).

    Code of Federal Regulations, 2011 CFR

    2011-04-01

    ... property as sales at fair market value (in lieu of applying the general useful life-contingent payment rule... of section 482 and regulations thereunder. See § 1.482-2(d). The amount of the deemed payment thus... amount equal to the difference between the fair market value of the transferred intangible property on...

  11. 31 CFR 588.202 - Effect of transfers violating the provisions of this part.

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... any property or interest in property blocked pursuant to § 588.201(a), is null and void and shall not... part. (d) Transfers of property that otherwise would be null and void or unenforceable by virtue of the provisions of this section shall not be deemed to be null and void or unenforceable as to any person with...

  12. 31 CFR 543.202 - Effect of transfers violating the provisions of this part.

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... any property or interest in property blocked pursuant to § 543.201(a), is null and void and shall not..., instruction, or license issued pursuant to this part. (d) Transfers of property that otherwise would be null and void or unenforceable by virtue of the provisions of this section shall not be deemed to be null...

  13. 31 CFR 541.202 - Effect of transfers violating the provisions of this part.

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... any property or interest in property blocked pursuant to § 541.201(a), is null and void and shall not... part. (d) Transfers of property that otherwise would be null and void or unenforceable by virtue of the provisions of this section shall not be deemed to be null and void or unenforceable as to any person with...

  14. Where Have All the Volumes Gone? A Contribution to the Discussion of "Captured Cultural Property" and "Trophy Commissions."

    ERIC Educational Resources Information Center

    Kolasa, Ingo

    1996-01-01

    During and after World War II, "trophy commissions" organized the systematic removal of German library holdings and art to Soviet libraries, archives, and museums. Discusses the organized transfer of cultural property, motives for transfer, German property in Russia today, and suggests that Germans and Russians should aid each other in…

  15. 10 CFR 770.5 - How does DOE notify persons and entities that defense nuclear facility real property is available...

    Code of Federal Regulations, 2012 CFR

    2012-01-01

    ... 10 Energy 4 2012-01-01 2012-01-01 false How does DOE notify persons and entities that defense nuclear facility real property is available for transfer for economic development? 770.5 Section 770.5 Energy DEPARTMENT OF ENERGY TRANSFER OF REAL PROPERTY AT DEFENSE NUCLEAR FACILITIES FOR ECONOMIC...

  16. 10 CFR 770.6 - May interested persons and entities request that real property at defense nuclear facilities be...

    Code of Federal Regulations, 2012 CFR

    2012-01-01

    ... 10 Energy 4 2012-01-01 2012-01-01 false May interested persons and entities request that real property at defense nuclear facilities be transferred for economic development? 770.6 Section 770.6 Energy DEPARTMENT OF ENERGY TRANSFER OF REAL PROPERTY AT DEFENSE NUCLEAR FACILITIES FOR ECONOMIC DEVELOPMENT § 770.6...

  17. 10 CFR 770.5 - How does DOE notify persons and entities that defense nuclear facility real property is available...

    Code of Federal Regulations, 2011 CFR

    2011-01-01

    ... 10 Energy 4 2011-01-01 2011-01-01 false How does DOE notify persons and entities that defense nuclear facility real property is available for transfer for economic development? 770.5 Section 770.5 Energy DEPARTMENT OF ENERGY TRANSFER OF REAL PROPERTY AT DEFENSE NUCLEAR FACILITIES FOR ECONOMIC...

  18. 10 CFR 770.6 - May interested persons and entities request that real property at defense nuclear facilities be...

    Code of Federal Regulations, 2011 CFR

    2011-01-01

    ... 10 Energy 4 2011-01-01 2011-01-01 false May interested persons and entities request that real property at defense nuclear facilities be transferred for economic development? 770.6 Section 770.6 Energy DEPARTMENT OF ENERGY TRANSFER OF REAL PROPERTY AT DEFENSE NUCLEAR FACILITIES FOR ECONOMIC DEVELOPMENT § 770.6...

  19. 41 CFR 102-75.540 - Who is responsible for enforcing compliance with the terms and conditions of the transfer for...

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... 41 Public Contracts and Property Management 3 2010-07-01 2010-07-01 false Who is responsible for enforcing compliance with the terms and conditions of the transfer for educational or public health purposes... Real Property Disposal Property for Educational and Public Health Purposes § 102-75.540 Who is...

  20. 41 CFR 102-75.540 - Who is responsible for enforcing compliance with the terms and conditions of the transfer for...

    Code of Federal Regulations, 2011 CFR

    2011-01-01

    ... 41 Public Contracts and Property Management 3 2011-01-01 2011-01-01 false Who is responsible for enforcing compliance with the terms and conditions of the transfer for educational or public health purposes... Real Property Disposal Property for Educational and Public Health Purposes § 102-75.540 Who is...

  1. Opto-electronic conversion logic behaviour through dynamic modulation of electron/energy transfer states at the TiO2-carbon quantum dot interface.

    PubMed

    Wang, Fang; Zhang, Yonglai; Liu, Yang; Wang, Xuefeng; Shen, Mingrong; Lee, Shuit-Tong; Kang, Zhenhui

    2013-03-07

    Here we show a bias-mediated electron/energy transfer process at the CQDs-TiO(2) interface for the dynamic modulation of opto-electronic properties. Different energy and electron transfer states have been observed in the CQDs-TNTs system due to the up-conversion photoluminescence and the electron donation/acceptance properties of the CQDs decorated on TNTs.

  2. Development of the lateral ventricular choroid plexus in a marsupial, Monodelphis domestica

    PubMed Central

    2010-01-01

    Background Choroid plexus epithelial cells are the site of blood/cerebrospinal fluid (CSF) barrier and regulate molecular transfer between the two compartments. Their mitotic activity in the adult is low. During development, the pattern of growth and timing of acquisition of functional properties of plexus epithelium are not known. Methods Numbers and size of choroid plexus epithelial cells and their nuclei were counted and measured in the lateral ventricular plexus from the first day of its appearance until adulthood. Newborn Monodelphis pups were injected with 5-bromo-2-deoxyuridine (BrdU) at postnatal day 3 (P3), P4 and P5. Additional animals were injected at P63, P64 and P65. BrdU-immunopositive nuclei were counted and their position mapped in the plexus structure at different ages after injections. Double-labelling immunocytochemistry with antibodies to plasma protein identified post-mitotic cells involved in protein transfer. Results Numbers of choroid plexus epithelial cells increased 10-fold between the time of birth and adulthood. In newborn pups each consecutive injection of BrdU labelled 20-40 of epithelial cells counted. After 3 injections, numbers of BrdU positive cells remained constant for at least 2 months. BrdU injections at an older age (P63, P64, P65) resulted in a smaller number of labelled plexus cells. Numbers of plexus cells immunopositive for both BrdU and plasma protein increased with age indicating that protein transferring properties are acquired post mitotically. Labelled nuclei were only detected on the dorsal arm of the plexus as it grows from the neuroependyma, moving along the structure in a 'conveyor belt' like fashion. Conclusions The present study established that lateral ventricular choroid plexus epithelial cells are born on the dorsal side of the structure only. Cells born in the first few days after choroid plexus differentiation from the neuroependyma remain present even two months later. Protein-transferring properties are acquired post-mitotically and relatively early in plexus development. PMID:20920364

  3. Development of the lateral ventricular choroid plexus in a marsupial, Monodelphis domestica.

    PubMed

    Liddelow, Shane A; Dziegielewska, Katarzyna M; Vandeberg, John L; Saunders, Norman R

    2010-10-05

    Choroid plexus epithelial cells are the site of blood/cerebrospinal fluid (CSF) barrier and regulate molecular transfer between the two compartments. Their mitotic activity in the adult is low. During development, the pattern of growth and timing of acquisition of functional properties of plexus epithelium are not known. Numbers and size of choroid plexus epithelial cells and their nuclei were counted and measured in the lateral ventricular plexus from the first day of its appearance until adulthood. Newborn Monodelphis pups were injected with 5-bromo-2-deoxyuridine (BrdU) at postnatal day 3 (P3), P4 and P5. Additional animals were injected at P63, P64 and P65. BrdU-immunopositive nuclei were counted and their position mapped in the plexus structure at different ages after injections. Double-labelling immunocytochemistry with antibodies to plasma protein identified post-mitotic cells involved in protein transfer. Numbers of choroid plexus epithelial cells increased 10-fold between the time of birth and adulthood. In newborn pups each consecutive injection of BrdU labelled 20-40 of epithelial cells counted. After 3 injections, numbers of BrdU positive cells remained constant for at least 2 months. BrdU injections at an older age (P63, P64, P65) resulted in a smaller number of labelled plexus cells. Numbers of plexus cells immunopositive for both BrdU and plasma protein increased with age indicating that protein transferring properties are acquired post mitotically. Labelled nuclei were only detected on the dorsal arm of the plexus as it grows from the neuroependyma, moving along the structure in a 'conveyor belt' like fashion. The present study established that lateral ventricular choroid plexus epithelial cells are born on the dorsal side of the structure only. Cells born in the first few days after choroid plexus differentiation from the neuroependyma remain present even two months later. Protein-transferring properties are acquired post-mitotically and relatively early in plexus development.

  4. Pilot Emergency Tutoring System for F-4 Aircraft Fuel System Malfunction Using Means-Ends Analysis

    DTIC Science & Technology

    1990-06-01

    pulled , and wing transfer pressure is normal. What operator do you choose? For example: type look_at INDICATOR for looked_at(INDICATOR) type set...cb internal wing transfer is pulled , and wing transfer pressure is normal. What operator do you choose? For example: type look_at INDICATOR for...at, external transfer is off, internal wing transfer is stop trans, refuel probe is extended, cb internal wing transfer is pulled ,and wing

  5. Exciton-to-Dopant Energy Transfer in Mn-Doped Cesium Lead Halide Perovskite Nanocrystals.

    PubMed

    Parobek, David; Roman, Benjamin J; Dong, Yitong; Jin, Ho; Lee, Elbert; Sheldon, Matthew; Son, Dong Hee

    2016-12-14

    We report the one-pot synthesis of colloidal Mn-doped cesium lead halide (CsPbX 3 ) perovskite nanocrystals and efficient intraparticle energy transfer between the exciton and dopant ions resulting in intense sensitized Mn luminescence. Mn-doped CsPbCl 3 and CsPb(Cl/Br) 3 nanocrystals maintained the same lattice structure and crystallinity as their undoped counterparts with nearly identical lattice parameters at ∼0.2% doping concentrations and no signature of phase separation. The strong sensitized luminescence from d-d transition of Mn 2+ ions upon band-edge excitation of the CsPbX 3 host is indicative of sufficiently strong exchange coupling between the charge carriers of the host and dopant d electrons mediating the energy transfer, essential for obtaining unique properties of magnetically doped quantum dots. Highly homogeneous spectral characteristics of Mn luminescence from an ensemble of Mn-doped CsPbX 3 nanocrystals and well-defined electron paramagnetic resonance spectra of Mn 2+ in host CsPbX 3 nanocrystal lattices suggest relatively uniform doping sites, likely from substitutional doping at Pb 2+ . These observations indicate that CsPbX 3 nanocrystals, possessing many superior optical and electronic characteristics, can be utilized as a new platform for magnetically doped quantum dots expanding the range of optical, electronic, and magnetic functionality.

  6. A SIFT study of the reactions of H2ONO+ ions with several types of organic molecules

    NASA Astrophysics Data System (ADS)

    Smith, David; Wang, Tianshu; Spanel, Patrik

    2003-11-01

    A selected ion flow tube (SIFT) study has been carried out of the reactions of hydrated nitrosonium ions, NO+H2O, which theory has equated to protonated nitrous acid ions, H2ONO+. One objective of this study was to investigate if this ion exhibits the properties of both a cluster ion and a protonated acid in their reactions with a variety of organic molecules. The chosen reactant molecules comprise two each of the following types--amines, terpenes, aromatic hydrocarbons, esters, carboxylic acids, ketones, aldehydes and alcohols. The reactant H2ONO+ (NO+H2O) ions are formed in a discharge ion source and injected into helium carrier gas where they are partially vibrationally excited and partially dissociated to NO+ ions. Hence, the reactions of the H2ONO+ ions had to be studies simultaneously with NO+ ions, the reactions of the latter ions readily being studied by selectively injecting NO+ ions into the carrier gas. The results of this study indicate that the H2ONO+ ions undergo a wide variety of reaction processes that depend on the properties of the reactant molecules such as their ionisation energies and proton affinities. These processes include charge transfer with compounds, M, that have low ionisation energies (producing M+), proton transfer with compounds possessing large proton affinities (MH+), hydride ion transfer (M---H+), alkyl radical (M---R+), alkoxide radical transfer (M---OR+), ion-molecule association (NO+H2OM) and ligand switching (NO+M), producing the ions given in parentheses.

  7. Ab initio molecular dynamics simulations of AlN responding to low energy particle radiation

    NASA Astrophysics Data System (ADS)

    Xi, Jianqi; Liu, Bin; Zhang, Yanwen; Weber, William J.

    2018-01-01

    Ab initio molecular dynamics simulations of low energy recoil events in wurtzite AlN have been performed to determine threshold displacement energies, defect production and evolution mechanisms, role of partial charge transfer during the process, and the influence of irradiation-induced defects on the properties of AlN. The results show that the threshold displacement energies, Ed, along the direction parallel to the basal planes are smaller than those perpendicular to the basal planes. The minimum Ed values are determined to be 19 eV and 55 eV for N and Al atom, respectively, which occur along the [ 1 ¯ 1 ¯ 20 ] direction. In general, the threshold displacement energies for N are smaller than those for Al atom, indicating the N defects would be dominant under irradiation. The defect production mechanisms have been analyzed. It is found that charge transfer and redistribution for both the primary knock-on atom and the subsequent recoil atoms play a significant role in defect production and evolution. Similar to the trend in oxide materials, there is a nearly linear relationship between Ed and the total amount of charge transfer at the potential energy peak in AlN, which provides guidance on the development of charge-transfer interatomic potentials for classic molecular dynamics simulations. Finally, the response behavior of AlN to low energy irradiation is qualitatively investigated. The existence of irradiation-induced defects significantly modifies the electronic structure, and thus affects the magnetic, electronic and optical properties of AlN. These findings further enrich the understanding of defects in the wide bandgap semiconductor of AlN.

  8. Ag colloids and arrays for plasmonic non-radiative energy transfer from quantum dots to a quantum well

    NASA Astrophysics Data System (ADS)

    Murphy, Graham P.; Gough, John J.; Higgins, Luke J.; Karanikolas, Vasilios D.; Wilson, Keith M.; Garcia Coindreau, Jorge A.; Zubialevich, Vitaly Z.; Parbrook, Peter J.; Bradley, A. Louise

    2017-03-01

    Non-radiative energy transfer (NRET) can be an efficient process of benefit to many applications including photovoltaics, sensors, light emitting diodes and photodetectors. Combining the remarkable optical properties of quantum dots (QDs) with the electrical properties of quantum wells (QWs) allows for the formation of hybrid devices which can utilize NRET as a means of transferring absorbed optical energy from the QDs to the QW. Here we report on plasmon-enhanced NRET from semiconductor nanocrystal QDs to a QW. Ag nanoparticles in the form of colloids and ordered arrays are used to demonstrate plasmon-mediated NRET from QDs to QWs with varying top barrier thicknesses. Plasmon-mediated energy transfer (ET) efficiencies of up to ˜25% are observed with the Ag colloids. The distance dependence of the plasmon-mediated ET is found to follow the same d -4 dependence as the direct QD to QW ET. There is also evidence for an increase in the characteristic distance of the interaction, thus indicating that it follows a Förster-like model with the Ag nanoparticle-QD acting as an enhanced donor dipole. Ordered Ag nanoparticle arrays display plasmon-mediated ET efficiencies up to ˜21%. To explore the tunability of the array system, two arrays with different geometries are presented. It is demonstrated that changing the geometry of the array allows a transition from overall quenching of the acceptor QW emission to enhancement, as well as control of the competition between the QD donor quenching and ET rates.

  9. Right-Sized Reuse - Use a Systematic Process, and Design for a Specialized, Yet Flexible Result - 13558

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Cusick, Lesley T.; Schiesswohl, Steven R.

    2013-07-01

    The process of transferring real property from the U.S. Department of Energy (DOE) is always the same - except when it's not. The most frequently asked questions in the process are: how can this take so long and be so complex, and why is it different every time? The process of transferring real property from the Department of Energy is always the same - except when it's not. Repeat as needed. The authority for DOE to transfer property is found in the Atomic Energy Act of 1954 (AEA). Specifically, the transfer of real property for mission-related purposes is done pursuantmore » to the AEA Section 161(g). Another rule that can provide certain unique benefits to the transferee is found in 10 Code of Federal Regulations (CFR) Part 770, Transfer of Real Property at Defense Nuclear Facilities for Economic Development; it can be followed for economic development purposes at defense nuclear facilities. All federal real property transfers include at minimum a National Environmental Policy Act (NEPA) review and a Comprehensive Environmental Response, Compensation, and Liability Act (CERCLA) chap. 120(h) environmental due diligence evaluation. The end-point objective is to be able to demonstrate that a transfer is protective of human health and the environment - typically attained via a risk evaluation. That's it...mostly. None of these requirements are new; their processes are well-known. So, why is it different every time there is a transfer and what can be done to move things along? Time and the perception of open-ended schedules kill projects. Economic development projects that are proposed by Community Reuse Organizations (CROs) and others or by parties who need private capital are especially time-sensitive. It is not reasonable to expect business interests or investors to wait two years while the property transfer process is carried out. Lenders are also risk-sensitive and not solely business-risk sensitive. After all, these are federal properties where contamination is a factor. What are some of the things you can do to address those time and risk issues? Issues of time and complexity arise from several variables. Short-sighted vision and lack of project definition lead to wasted effort and lengthy delays. Some variability on the input side of the process can be controlled in a way that will save you time and actually work to your advantage. Steps can be taken to systematize the transfer process on the agency's part and on the requester/grantee's part. Having the right mix of dedicated people from the beginning, planning with flexibility, coordinating with the clean-up program at your site, knowing the interests and issues of your stakeholders, and working with the CRO/economic development authorities - all of these measures and others can and will help you. The key is not simply knowing the steps and making a punch-list, but understanding the steps and how to work with and use them. These concepts can be applied to create a vision of success for those engaged in real property transfer. (authors)« less

  10. Modeling of biomass to hydrogen via the supercritical water pyrolysis process

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Divilio, R.J.

    1998-08-01

    A heat transfer model has been developed to predict the temperature profile inside the University of Hawaii`s Supercritical Water Reactor. A series of heat transfer tests were conducted on the University of Hawaii`s apparatus to calibrate the model. Results of the model simulations are shown for several of the heat transfer tests. Tests with corn starch and wood pastes indicated that there are substantial differences between the thermal properties of the paste compared to pure water, particularly near the pseudo critical temperature. The assumption of constant thermal diffusivity in the temperature range of 250 to 450 C gave a reasonablemore » prediction of the reactor temperatures when paste is being fed. A literature review is presented for pyrolysis of biomass in water at elevated temperatures up to the supercritical range. Based on this review, a global reaction mechanism is proposed. Equilibrium calculations were performed on the test results from the University of Hawaii`s Supercritical Water Reactor when corn starch and corn starch and wood pastes were being fed. The calculations indicate that the data from the reactor falls both below and above the equilibrium hydrogen concentrations depending on test conditions. The data also indicates that faster heating rates may be beneficial to the hydrogen yield. Equilibrium calculations were also performed to examine the impact of wood concentration on the gas mixtures produced. This calculation showed that increasing wood concentrations favors the formation of methane at the expense of hydrogen.« less

  11. Numerical analysis on pressure drop and heat transfer performance of mesh regenerators used in cryocoolers

    NASA Astrophysics Data System (ADS)

    Tao, Y. B.; Liu, Y. W.; Gao, F.; Chen, X. Y.; He, Y. L.

    2009-09-01

    An anisotropic porous media model for mesh regenerator used in pulse tube refrigerator (PTR) is established. Formulas for permeability and Forchheimer coefficient are derived which include the effects of regenerator configuration and geometric parameters, oscillating flow, operating frequency, cryogenic temperature. Then, the fluid flow and heat transfer performances of mesh regenerator are numerically investigated under different mesh geometric parameters and material properties. The results indicate that the cooling power of the PTR increases with the increases of specific heat capacity and density of the regenerator mesh material, and decreases with the increases of penetration depth and thermal conductivity ratio ( a). The cooling power at a = 0.1 is 0.5-2.0 W higher than that at a = 1. Optimizing the filling scale of different mesh configurations (such as 75% #200 twill and 25% #250 twill) and adopting multi segments regenerator with stainless steel meshes at the cold end can enhance the regenerator's efficiency and achieve better heat transfer performance.

  12. An investigation of the processes controlling ozone in the upper stratosphere

    NASA Technical Reports Server (NTRS)

    Patten, Kenneth O., Jr.; Connell, Peter S.; Kinnison, Douglas E.; Wuebbles, Donald J.; Waters, Joe; Froidevaux, Lucien; Slanger, Tom G.

    1994-01-01

    Photolysis of vibrationally excited oxygen produced by ultraviolet photolysis of ozone in the upper stratosphere is incorporated into the Lawrence Livermore National Laboratory 2-D zonally averaged chemical-radiative-transport model of the troposphere and stratosphere. The importance of this potential contributor of odd oxygen to the concentration of ozone is evaluated based upon recent information on vibrational distributions of excited oxygen and upon preliminary studies of energy transfer from the excited oxygen. When the energy transfer rate constants of previous work are assumed, increases in model ozone concentrations of up to 40 percent in the upper stratosphere are found, and the ozone concentrations of the model agree with measurements, including data from the Upper Atmosphere Research Satellite. However, the increase is about 0.4 percent when the larger energy transfer rate constants suggested by more recent experimental work are applied in the model. This indicates the importance of obtaining detailed information on vibrationally excited oxygen properties to evaluation of this process for stratospheric modelling.

  13. The Effect of Cooling Passage Aspect Ratio on Curvature Heat Transfer Enhancement

    NASA Technical Reports Server (NTRS)

    Meyer, Michael L.

    1997-01-01

    A series of electrically heated tube experiments was performed to investigate the effect of high aspect ratio on curvature heat transfer enhancement in uniformly heated rectangular cooling passages. Three hardware geometries were tested: a baseline straight aspect ratio 10 tube, an aspect ratio 1 (square) tube with a 45 deg. curve, and an aspect ratio 10 tube with a 45 deg. curve. Gaseous nitrogen with the following properties was used as the coolant: ambient inlet temperature, pressures to 8.3 MPa, wall-to-bulk temperature ratios less than two, and Reynolds numbers based on hydraulic diameter ranging from 250,000 to 1,600,000. The measured curvature enhancement factors were compared to values predicted by three previously published models which had been developed for low aspect ratio tubes. The models were shown to be valid for the high aspect ratio tube as well the low aspect ratio tube, indicating that aspect ratio had little impact on the curvature heat transfer enhancement in these tests.

  14. Noncovalent binding of xanthene and phthalocyanine dyes with graphene sheets: the effect of the molecular structure revealed by a photophysical study.

    PubMed

    Zhang, Xian-Fu; Liu, Su-Ping; Shao, Xiao-Na

    2013-09-01

    The fluorescence and absorption properties of several xanthene and phthalocyanine dyes were measured in the presence and absence of chemically derived graphene (CDG) sheets. The interaction of pyronine Y (PYY) with graphene sheets was compared with that of rhodamine 6G (R6G) to reveal the effect of the molecular structure. Although the presence of the perpendicular benzene moiety in a R6G or phthalocyanine molecule does cause the difficulty for forming dye-CDG complex and make CDG less efficient in quenching the fluorescence intensity and shortening the fluorescence lifetime, it does not affect the band position of charge transfer absorption, suggesting that no molecular shape change occurred in a dye molecule caused by the interaction with CDG sheets. The spectroscopic and thermodynamic data indicated that the dye-CDG binding is of charge transfer nature, while the dynamic fluorescence quenching is due to photoinduced energy and electron transfer. Copyright © 2013 Elsevier B.V. All rights reserved.

  15. Inter-layer and intra-layer heat transfer in bilayer/monolayer graphene van der Waals heterostructure: Is there a Kapitza resistance analogous?

    NASA Astrophysics Data System (ADS)

    Rajabpour, Ali; Fan, Zheyong; Vaez Allaei, S. Mehdi

    2018-06-01

    Van der Waals heterostructures have exhibited interesting physical properties. In this paper, heat transfer in hybrid coplanar bilayer/monolayer (BL-ML) graphene, as a model layered van der Waals heterostructure, was studied using non-equilibrium molecular dynamics (MD) simulations. The temperature profile and inter- and intra-layer heat fluxes of the BL-ML graphene indicated that, there is no fully developed thermal equilibrium between layers and the drop in the average temperature profile at the step-like BL-ML interface is not attributable to the effect of Kapitza resistance. By increasing the length of the system up to 1 μm in the studied MD simulations, the thermally non-equilibrium region was reduced to a small area near the step-like interface. All MD results were compared to a continuum model and a good match was observed between the two approaches. Our results provide a useful understanding of heat transfer in nano- and micro-scale layered materials and van der Waals heterostructures.

  16. Hamiltonian indices and rational spectral densities

    NASA Technical Reports Server (NTRS)

    Byrnes, C. I.; Duncan, T. E.

    1980-01-01

    Several (global) topological properties of various spaces of linear systems, particularly symmetric, lossless, and Hamiltonian systems, and multivariable spectral densities of fixed McMillan degree are announced. The study is motivated by a result asserting that on a connected but not simply connected manifold, it is not possible to find a vector field having a sink as its only critical point. In the scalar case, this is illustrated by showing that only on the space of McMillan degree = /Cauchy index/ = n, scalar transfer functions can one define a globally convergent vector field. This result holds both in discrete-time and for the nonautonomous case. With these motivations in mind, theorems of Bochner and Fogarty are used in showing that spaces of transfer functions defined by symmetry conditions are, in fact, smooth algebraic manifolds.

  17. DOE Office of Scientific and Technical Information (OSTI.GOV)

    Sharma, Amrish, E-mail: amrish99@gmail.com; Kaur, Sandeep, E-mail: sipusukhn@gmail.com; Mudahar, Isha, E-mail: isha@pbi.ac.in

    We have investigated the structural and electronic properties of carbon nanotube with small fullerene halves C{sub n} (n ≤ 40) which are covalently bonded to the side wall of an armchair single wall carbon nanotube (SWCNT) using first principle method based on density functional theory. The fullerene size results in weak bonding between fullerene halves and carbon nanotube (CNT). Further, it was found that the C-C bond distance that attaches the fullerene half and CNT is of the order of 1.60 Å. The calculated binding energies indicate the stability of the complexes formed. The HOMO-LUMO gaps and electron density ofmore » state plots points towards the metallicity of the complex formed. Our calculations on charge transfer reveal that very small amount of charge is transferred from CNT to fullerene halves.« less

  18. Buckminsterfullerene hybridized zinc oxide tetrapods: defects and charge transfer induced optical and electrical response.

    PubMed

    Smazna, Daria; Rodrigues, Joana; Shree, Sindu; Postica, Vasile; Neubüser, Gero; Martins, A F; Ben Sedrine, N; Jena, Naresh K; Siebert, Leonard; Schütt, Fabian; Lupan, Oleg; Ahuja, Rajeev; Correia, M R; Monteiro, Teresa; Kienle, Lorenz; Yang, Ya; Adelung, Rainer; Mishra, Yogendra Kumar

    2018-05-21

    Buckminster fullerene (C60) based hybrid metal oxide materials are receiving considerable attention because of their excellent fundamental and applied aspects, like semiconducting, electron transfer, luminescent behaviors, etc. and this work briefly discusses the successful fabrication of C60 decorated ZnO tetrapod materials and their detailed structure-property relationships including device sensing applications. The electron microscopy investigations indicate that a quite dense surface coverage of ZnO tetrapods with C60 clusters is achieved. The spectroscopy studies confirmed the identification of the C60 vibrational modes and the C60 induced changes in the absorption and luminescence properties of the ZnO tetrapods. An increased C60 concentration on ZnO results in steeper ZnO bandgap absorption followed by well-defined free exciton and 3.31 eV line emissions. As expected, higher amounts of C60 increase the intensity of C60-related visible absorption bands. Pumping the samples with photons with an energy corresponding to these absorption band maxima leads to additional emission from ZnO showing an effective charge transfer phenomenon from C60 to the ZnO host. The density of states model obtained from DFT studies for pure and C60 coated ZnO surfaces confirms the experimental observations. The fabricated C60-ZnO hybrid tetrapod based micro- and nanodevices showed interesting ethanol gas sensing characteristics.

  19. 26 CFR 1.1055-2 - Determination of amount realized on the transfer of the right to hold real property subject to...

    Code of Federal Regulations, 2010 CFR

    2010-04-01

    ... of the right to hold real property subject to liabilities under a redeemable ground rent. 1.1055-2... of the right to hold real property subject to liabilities under a redeemable ground rent. In determining the amount realized from a transfer, occurring on or after April 11, 1963, of the right to hold...

  20. 34 CFR 12.14 - What are the sanctions for noncompliance with a term or condition of a transfer or lease of...

    Code of Federal Regulations, 2012 CFR

    2012-07-01

    ... leased surplus Federal real property not due to— (A) Reasonable wear and tear; (B) Acts of God; or (C... condition of a transfer or lease of surplus Federal real property? 12.14 Section 12.14 Education Office of the Secretary, Department of Education DISPOSAL AND UTILIZATION OF SURPLUS FEDERAL REAL PROPERTY FOR...

  1. 34 CFR 12.14 - What are the sanctions for noncompliance with a term or condition of a transfer or lease of...

    Code of Federal Regulations, 2013 CFR

    2013-07-01

    ... leased surplus Federal real property not due to— (A) Reasonable wear and tear; (B) Acts of God; or (C... condition of a transfer or lease of surplus Federal real property? 12.14 Section 12.14 Education Office of the Secretary, Department of Education DISPOSAL AND UTILIZATION OF SURPLUS FEDERAL REAL PROPERTY FOR...

  2. 34 CFR 12.14 - What are the sanctions for noncompliance with a term or condition of a transfer or lease of...

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... leased surplus Federal real property not due to— (A) Reasonable wear and tear; (B) Acts of God; or (C... condition of a transfer or lease of surplus Federal real property? 12.14 Section 12.14 Education Office of the Secretary, Department of Education DISPOSAL AND UTILIZATION OF SURPLUS FEDERAL REAL PROPERTY FOR...

  3. 34 CFR 12.14 - What are the sanctions for noncompliance with a term or condition of a transfer or lease of...

    Code of Federal Regulations, 2011 CFR

    2011-07-01

    ... leased surplus Federal real property not due to— (A) Reasonable wear and tear; (B) Acts of God; or (C... condition of a transfer or lease of surplus Federal real property? 12.14 Section 12.14 Education Office of the Secretary, Department of Education DISPOSAL AND UTILIZATION OF SURPLUS FEDERAL REAL PROPERTY FOR...

  4. 34 CFR 12.14 - What are the sanctions for noncompliance with a term or condition of a transfer or lease of...

    Code of Federal Regulations, 2014 CFR

    2014-07-01

    ... leased surplus Federal real property not due to— (A) Reasonable wear and tear; (B) Acts of God; or (C... condition of a transfer or lease of surplus Federal real property? 12.14 Section 12.14 Education Office of the Secretary, Department of Education DISPOSAL AND UTILIZATION OF SURPLUS FEDERAL REAL PROPERTY FOR...

  5. 41 CFR 102-36.365 - May we transfer or donate canines that have been used in the performance of law enforcement duties?

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... 41 Public Contracts and Property Management 3 2010-07-01 2010-07-01 false May we transfer or donate canines that have been used in the performance of law enforcement duties? 102-36.365 Section 102-36.365 Public Contracts and Property Management Federal Property Management Regulations System (Continued) FEDERAL MANAGEMENT REGULATION PERSONAL...

  6. Reactions of electron-transfer flavoprotein and electron-transfer flavoprotein: ubiquinone oxidoreductase.

    PubMed Central

    Ramsay, R R; Steenkamp, D J; Husain, M

    1987-01-01

    Electron-transfer flavoprotein:ubiquinone oxidoreductase (ETF-Q oxidoreductase) catalyses the re-oxidation of reduced electron-transfer flavoprotein (ETF) with ubiquinone-1 (Q-1) as the electron acceptor. A kinetic assay for the enzyme was devised in which glutaryl-CoA in the presence of glutaryl-CoA dehydrogenase was used to reduce ETFox. and the reduction of Q-1 was monitored at 275 nm. The partial reactions involved in the overall assay system were examined. Glutaryl-CoA dehydrogenase catalyses the rapid reduction of ETFox. to the anionic semiquinone (ETF.-), but reduces ETF.- to the fully reduced form (ETFhq) at a rate that is about 6-fold lower. ETF.-, but not ETFhq, is directly re-oxidized by Q-1 at a rate that, depending on the steady-state concentration of ETF.-, may contribute significantly to the overall reaction. ETF-Q oxidoreductase catalyses rapid disproportionation of ETF.- with an equilibrium constant of about 1.0 at pH 7.8. In the presence of Q-1 it also catalyses the re-oxidation of ETFhq at a rate that is faster than that of the overall reaction. Rapid-scan experiments indicated the formation of ETF.-, but its fractional concentration in the early stages of the re-oxidation of ETFhq is low. The data indicate that the re-oxidation of ETFhq proceeds at a rate that is adequate to account for the overall rate of electron transfer from glutaryl-CoA to Q-1. An unusual property of ETF-Q oxidoreductase seems to be that it not only catalyses the re-oxidation of the reduced forms of ETF but also facilitates the complete reduction of ETFox. to ETFhq by disproportionation of the radical. PMID:3593226

  7. Electron transfer function versus oxygen delivery: a comparative study for several hexacoordinated globins across the animal kingdom.

    PubMed

    Kiger, Laurent; Tilleman, Lesley; Geuens, Eva; Hoogewijs, David; Lechauve, Christophe; Moens, Luc; Dewilde, Sylvia; Marden, Michael C

    2011-01-01

    Caenorhabditis elegans globin GLB-26 (expressed from gene T22C1.2) has been studied in comparison with human neuroglobin (Ngb) and cytoglobin (Cygb) for its electron transfer properties. GLB-26 exhibits no reversible binding for O(2) and a relatively low CO affinity compared to myoglobin-like globins. These differences arise from its mechanism of gaseous ligand binding since the heme iron of GLB-26 is strongly hexacoordinated in the absence of external ligands; the replacement of this internal ligand, probably the E7 distal histidine, is required before binding of CO or O(2) as for Ngb and Cygb. Interestingly the ferrous bis-histidyl GLB-26 and Ngb, another strongly hexacoordinated globin, can transfer an electron to cytochrome c (Cyt-c) at a high bimolecular rate, comparable to those of inter-protein electron transfer in mitochondria. In addition, GLB-26 displays an unexpectedly rapid oxidation of the ferrous His-Fe-His complex without O(2) actually binding to the iron atom, since the heme is oxidized by O(2) faster than the time for distal histidine dissociation. These efficient mechanisms for electron transfer could indicate a family of hexacoordinated globin which are functionally different from that of pentacoordinated globins.

  8. Numerical Investigation of Radiative Heat Transfer in Laser Induced Air Plasmas

    NASA Technical Reports Server (NTRS)

    Liu, J.; Chen, Y. S.; Wang, T. S.; Turner, James E. (Technical Monitor)

    2001-01-01

    Radiative heat transfer is one of the most important phenomena in the laser induced plasmas. This study is intended to develop accurate and efficient methods for predicting laser radiation absorption and plasma radiative heat transfer, and investigate the plasma radiation effects in laser propelled vehicles. To model laser radiation absorption, a ray tracing method along with the Beer's law is adopted. To solve the radiative transfer equation in the air plasmas, the discrete transfer method (DTM) is selected and explained. The air plasma radiative properties are predicted by the LORAN code. To validate the present nonequilibrium radiation model, several benchmark problems are examined and the present results are found to match the available solutions. To investigate the effects of plasma radiation in laser propelled vehicles, the present radiation code is coupled into a plasma aerodynamics code and a selected problem is considered. Comparisons of results at different cases show that plasma radiation plays a role of cooling plasma and it lowers the plasma temperature by about 10%. This change in temperature also results in a reduction of the coupling coefficient by about 10-20%. The present study indicates that plasma radiation modeling is very important for accurate modeling of aerodynamics in a laser propelled vehicle.

  9. How Does the Surface of Al-ITQ-HB 2D-MOF Condition the Intermolecular Interactions of an Adsorbed Organic Molecule?

    PubMed

    Caballero-Mancebo, Elena; Moreno, José María; Corma, Avelino; Díaz, Urbano; Cohen, Boiko; Douhal, Abderrazzak

    2018-05-30

    In this work, we unravel how the two-dimensional Al-ITQ-4-heptylbenzoic acid (HB) metal-organic framework (MOF) changes the interactions of Nile red (NR) adsorbed on its surface. Time-resolved emission experiments indicate the occurrence of energy transfer between adsorbed NR molecules, in abnormally long time constant of 2-2.5 ns, which gets shorter (∼0.25 ns) when the concentration of the surface-adsorbed NR increases. We identify the emission from local excited state of aggregates and charge transfer and energy transfer between adsorbed molecules. Femtosecond emission studies reveal an ultrafast process (∼425 fs) in the NR@Al-ITQ-HB composites, assigned to an intramolecular charge transfer in NR molecules. A comparison of the observed photobehavior with that of NR/SiO 2 and NR/Al 2 O 3 composites suggests that the occurrence of energy transfer in the NR@MOF complexes is a result of specific and nonspecific interactions, reflecting the different surface properties of Al-ITQ-HB that are of relevance to the reported high catalytic activity. Our results provide new knowledge for further researches on other composites with the aim to improve understanding of photocatalytic and photonic processes within MOFs.

  10. Theoretical Investigation of Charge Transfer in Metal Organic Frameworks for Electrochemical Device Applications

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Patwardhan, Sameer; Schatz, George C.

    For electrochemical device applications metal organic frameworks (MOFs) must exhibit suitable conduction properties. To this end, we have performed computational studies of intermolecular charge transfer in MOFs consisting of hexa-ZrIV nodes and tetratopic carboxylate linkers. This includes an examination of the electronic structure of linkers that are derived from tetraphenyl benzene 1, tetraphenyl pyrene 2, and tetraphenyl porphyrin 3 molecules. These results are used to determine charge transfer propensities in MOFs, within the framework of Marcus theory, including an analysis of the key parameters (charge transfer integral t, reorganization energy λ, and free energy change ΔG0) and evaluation of figuresmore » of merit for charge transfer based on the chemical structures of the linkers. This qualitative analysis indicates that delocalization of the HOMO/LUMO on terminal substituents increases t and decreases λ, while weaker binding to counterions decreases ΔG0, leading to better charge transfer propensity. Subsequently, we study hole transfer in the linker 2 containing MOFs, NU-901 and NU-1000, in detail and describe mechanisms (hopping and superexchange) that may be operative under different electrochemical conditions. Comparisons with experiment are provided where available. On the basis of the redox and catalytic activity of nodes and linkers, we propose three possible schemes for constructing electrochemical devices for catalysis. We believe that the results of this study will lay the foundation for future experimental work on this topic.« less

  11. Saccharomyces cerevisiae Shuttle vectors.

    PubMed

    Gnügge, Robert; Rudolf, Fabian

    2017-05-01

    Yeast shuttle vectors are indispensable tools in yeast research. They enable cloning of defined DNA sequences in Escherichia coli and their direct transfer into Saccharomyces cerevisiae cells. There are three types of commonly used yeast shuttle vectors: centromeric plasmids, episomal plasmids and integrating plasmids. In this review, we discuss the different plasmid systems and their characteristic features. We focus on their segregational stability and copy number and indicate how to modify these properties. Copyright © 2017 John Wiley & Sons, Ltd. Copyright © 2017 John Wiley & Sons, Ltd.

  12. Internal energy transfer phenomenon and light-emission properties of γ-LiAlO2 phosphor doped with Mn2+

    NASA Astrophysics Data System (ADS)

    Wang, Bai-Bin; Chang, Chi-Fen; Yang, Wein-Duo

    2013-07-01

    γ-LiAlO2:Mn2+ phosphor was synthesized using the cellulose-citric acid sol-gel method, and its light emission and energy transfer properties were investigated. Excitation and emission spectrum analysis revealed a decrease in intensity of the spectrum as the amount of Mn2+ doping increased. Blasse's equation determined the maximum distance for energy transfer between Mn2+ ions as 4.3142 nm. Dexter's theory verifies that the mechanism of energy transfer between Mn2+ ions conforms to an electric dipole and electric quadrupole interaction.

  13. Overpressure generation by load transfer following shale framework weakening due to smectite diagenesis

    USGS Publications Warehouse

    Lahann, R.W.; Swarbrick, R.E.

    2011-01-01

    Basin model studies which have addressed the importance of smectite conversion to illite as a source of overpressure in the Gulf of Mexico have principally relied on a single-shale compaction model and treated the smectite reaction as only a fluid-source term. Recent fluid pressure interpretation and shale petrology studies indicate that conversion of bound water to mobile water, dissolution of load-bearing grains, and increased preferred orientation change the compaction properties of the shale. This results in substantial changes in effective stress and fluid pressure. The resulting fluid pressure can be 1500-3000psi higher than pressures interpreted from models based on shallow compaction trends. Shale diagenesis changes the mineralogy, volume, and orientation of the load-bearing grains in the shale as well as the volume of bound water. This process creates a weaker (more compactable) grain framework. When these changes occur without fluid export from the shale, some of the stress is transferred from the grains onto the fluid. Observed relationships between shale density and calculated effective stress in Gulf of Mexico shelf wells confirm these changes in shale properties with depth. Further, the density-effective stress changes cannot be explained by fluid-expansion or fluid-source processes or by prediagenesis compaction, but are consistent with a dynamic diagenetic modification of the shale mineralogy, texture, and compaction properties during burial. These findings support the incorporation of diagenetic modification of compaction properties as part of the fluid pressure interpretation process. ?? 2011 Blackwell Publishing Ltd.

  14. Non-Covalent Functionalisation of C30 Fullerene by Pyrrole-n-Carboxylic Acid (n=2, 3): Density Functional Theory Studies

    NASA Astrophysics Data System (ADS)

    Harismah, Kun; Mirzaei, Mahmoud; Ghasemi, Nahid; Nejati, Mohammad

    2017-12-01

    For functionalisation of a representative C30 fullerene nanostructure by pyrrole-n-carboxylic acid (PnCA; n=2, 3) their stabilities and properties were investigated based on density functional theory calculations. Parallel calculations were also done for C60 fullerene as evidence for comparing the results. Non-covalent interactions are considered to make the functionalised structures. In contrast with the spherical shape of C60, the shape of C30 fullerene is elliptical; therefore, the functionalisation processes were done for both axial and equatorial elliptical positions (AC30 and EC30). The results indicated that both the positions of C30 have almost equivalent chances to be functionalised by PnCA; but functionalisation by P2CA is slightly more favourable than P3CA, either for C60. The illustrated molecular orbitals' distributions indicated that the direction of charge transfer could be considered from PnCA counterparts to fullerene counterparts. The molecular properties indicated more reactivity for C30 than for C60 fullerene. Finally, the atomic scale quadrupole coupling constants indicated different roles for N and O atoms of PnCA in the functionalised models.

  15. Engineering and Probing Topological Properties of Dirac Semimetal Films by Asymmetric Charge Transfer.

    PubMed

    Villanova, John W; Barnes, Edwin; Park, Kyungwha

    2017-02-08

    Dirac semimetals (DSMs) have topologically robust three-dimensional Dirac (doubled Weyl) nodes with Fermi-arc states. In heterostructures involving DSMs, charge transfer occurs at the interfaces, which can be used to probe and control their bulk and surface topological properties through surface-bulk connectivity. Here we demonstrate that despite a band gap in DSM films, asymmetric charge transfer at the surface enables one to accurately identify locations of the Dirac-node projections from gapless band crossings and to examine and engineer properties of the topological Fermi-arc surface states connecting the projections, by simulating adatom-adsorbed DSM films using a first-principles method with an effective model. The positions of the Dirac-node projections are insensitive to charge transfer amount or slab thickness except for extremely thin films. By varying the amount of charge transfer, unique spin textures near the projections and a separation between the Fermi-arc states change, which can be observed by gating without adatoms.

  16. 32 CFR 174.9 - Economic development conveyances.

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... 32 National Defense 1 2010-07-01 2010-07-01 false Economic development conveyances. 174.9 Section... Economic development conveyances. (a) The Secretary concerned may transfer real property and personal property to the LRA for purposes of job generation on the installation. Such a transfer is an Economic...

  17. 43 CFR 41.120 - Transfers of property.

    Code of Federal Regulations, 2010 CFR

    2010-10-01

    ... SEX IN EDUCATION PROGRAMS OR ACTIVITIES RECEIVING FEDERAL FINANCIAL ASSISTANCE Introduction § 41.120... with Federal financial assistance to a transferee that operates any education program or activity, and the Federal share of the fair market value of the property is not upon such sale or transfer properly...

  18. 45 CFR 86.5 - Transfers of property.

    Code of Federal Regulations, 2010 CFR

    2010-10-01

    ... SEX IN EDUCATION PROGRAMS OR ACTIVITIES RECEIVING FEDERAL FINANCIAL ASSISTANCE Introduction § 86.5... with Federal financial assistance to a transferee which operates any education program or activity, and the Federal share of the fair market value of the property is not upon such sale or transfer properly...

  19. 32 CFR 174.9 - Economic development conveyances.

    Code of Federal Regulations, 2011 CFR

    2011-07-01

    ... 32 National Defense 1 2011-07-01 2011-07-01 false Economic development conveyances. 174.9 Section... Economic development conveyances. (a) The Secretary concerned may transfer real property and personal property to the LRA for purposes of job generation on the installation. Such a transfer is an Economic...

  20. Vectorial photoinduced energy transfer between boron-dipyrromethene (Bodipy) chromophores across a fluorene bridge.

    PubMed

    Puntoriero, Fausto; Nastasi, Francesco; Campagna, Sebastiano; Bura, Thomas; Ziessel, Raymond

    2010-08-02

    A series of novel multichromophoric, luminescent compounds has been prepared, and their absorption spectra, luminescence properties (both at 77 K in rigid matrix and at 298 K in fluid solution), and photoinduced intercomponent energy-transfer processes have been studied. The series contains two new multichromophoric systems 1 and 2, each one containing two different boron-dipyrromethene (Bodipy) subunits and one bridging fluorene species, and two fluorene-Bodipy bichromophoric species, 6 and 7. Three monochromophoric compounds, 3, 4, and 5, used as precursors in the synthetic process, were also fully characterized. The absorption spectra of the multichromophoric compounds are roughly the summation of the absorption spectra of their individual components, thus demonstrating the supramolecular nature of the assemblies. Luminescence studies show that quantitative energy transfer occurs in 6 and 7 from the fluorene chromophore to the Bodipy dyes. Luminescence studies, complemented by transient-absorption spectroscopy studies, also indicate that efficient inter-Bodipy energy transfer across the rigid fluorene spacer takes place in 1 and 2, with rate constants, evaluated by several experimental methods, between 2.0 and 7.0 x 10(9) s(-1). Such an inter-Bodipy energy transfer appears to be governed by the Förster mechanism. By taking advantage of the presence of various protonable sites in the substituents of the lower-energy Bodipy subunit of 1 and 2, the effect of protonation on the energy-transfer rates has also been investigated. The results suggest that control of energy-transfer rate and efficiency of inter-Bodipy energy transfer in this type of systems can be achieved by an external, reversible input.

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