Lidar observation of transition of cirrus clouds over a tropical station Gadanki (13.45° N, 79.18° E): case studies

NASA Astrophysics Data System (ADS)

Srinivasan, M. A.; Rao, C. Dhananjaya; Krishnaiah, M.

2016-05-01

The present study describes Mie lidar observations of the cirrus cloud passage showing transition between double thin layers into single thick and single thick layer into double thin layers of cirrus over Gadanki region. During Case1: 17 January 2007, Case4: 12 June 2007, Case5: 14 July 2007 and Case6: 24 July 2007 the transition is found to from two thin cirrus layers into single geometrically thick layer. Case2: 14 May 2007 and Case3: 15 May 2007, the transition is found to from single geometrically thick layer into two thin cirrus layers. Linear Depolarization Ratio (LDR) and Back Scatter Ration (BSR) are found to show similar variation with strong peaks during transition; both LDR and Cloud Optical Depth (COD) is found to show similar variation except during transition with strong peaks in COD which is not clearly found from LDR for the all cases. There is a significant weakening of zonal and meridional winds during Case1 which might be due to the transition from multiple to single thick cirrus indicating potential capability of thick cirrus in modulating the wind fields. There exists strong upward wind dominance contributed to significant ascent in cloud-base altitude thereby causing transition of multiple thin layers into single thick cirrus.

Effect of Protuberance Shape and Orientation on Space Shuttle Orbiter Boundary-Layer Transition

NASA Technical Reports Server (NTRS)

King, RUdolph A.; Berry, Scott A.; Kegerise, Michael A.

2008-01-01

This document describes an experimental study conducted to examine the effects of protuberances on hypersonic boundary-layer transition. The experiment was conducted in the Langley 20-Inch Mach 6 Tunnel on a series of 0.9%-scale Shuttle Orbiter models. The data were acquired to complement the existing ground-based boundary-layer transition database that was used to develop Version 1.0 of the boundary-layer transition RTF (return-to-flight) tool. The existing ground-based data were all acquired on 0.75%-scale Orbiter models using diamond-shaped ( pizza-box ) trips. The larger model scale facilitated in manufacturing higher fidelity protuberances. The end use of this experimental database will be to develop a technical basis (in the form of a boundary-layer transition correlation) to assess representative protrusion shapes, e.g., gap fillers and protrusions resulting from possible tile repair concepts. The primary objective of this study is to investigate the effects of protuberance-trip location and geometry on Shuttle Orbiter boundary-layer transition. Secondary goals are to assess the effects of gap-filler orientation and other protrusion shapes on boundary-layer transition. Global heat-transfer images using phosphor thermography of the Orbiter windward surface and the corresponding streamwise and spanwise heating distributions were used to infer the state of the boundary layer, i.e., laminar, transitional, or turbulent.

Effects of different binders on microstructure and phase composition of hydroxyapatite Nd-YAG laser clad coatings

NASA Astrophysics Data System (ADS)

Chien, C. S.; Hong, T. F.; Han, T. J.; Kuo, T. Y.; Liao, T. Y.

2011-01-01

The laser clad coating technique can help to produce metallurgical bonding with high bonding strength between the coating layer and the substrate, which has been gradually applied for hydroxyapatite (HA) coating on metallic substrates. In this study, HA powder is mixed with two different binders, namely water glass (WG) and polyvinyl alcohol (PVA), respectively, and is then clad on Ti-6Al-4V substrates using an Nd:YAG laser system under various processing conditions. The microstructure, chemical composition and hardness of the coating layer and transition layer of the various samples are then systematically explored. The experimental results show that the coating layers of the various samples all contain both cellular dendrites and rod-like piled structures, while the transition layers contain only cellular dendrites. For all samples, the coating layer consists mostly of CaTiO 3, Ca 2P 2O 7, CaO and HA phases, whereas the transition layer contains primarily CaTiO 3, Ca 2P 2O 7, Ti 3P, Ti and HA phases. In addition, the transition layer of the WG samples also contains SiO 2 and Si 2Ti phases. In all of the specimens, the transition layer has a higher average hardness than the substrate or coating layer. Moreover, the transition layer in the WG sample is harder than that in the PVA sample.

Bypass transition in boundary layers including curvature and favorable pressure gradient effects

NASA Technical Reports Server (NTRS)

Volino, R. J.; Simon, T. W.

1991-01-01

Recent studies of 2-D boundary layers undergoing bypass transition were reviewed. Bypass transition is characterized by the sudden appearance of turbulent spots in boundary layer without first the regular, observable growth of disturbances predicted by linear stability theory. There are no standard criteria or parameters for defining bypass transition, but it is known to be the mode of transition when the flow is disturbed by perturbations of sufficient amplitude.

Mechanics of Boundary Layer Transition. Part 5: Boundary Layer Stability theory in incompressible and compressible flow

NASA Technical Reports Server (NTRS)

Mack, L. M.

1967-01-01

The fundamentals of stability theory, its chief results, and the physical mechanisms at work are presented. The stability theory of the laminar boundary determines whether a small disturbance introduced into the boundary layer will amplify or damp. If the disturbance damps, the boundary layer remains laminar. If the disturbance amplifies, and by a sufficient amount, then transition to turbulence eventually takes place. The stability theory establishes those states of the boundary layer which are most likely to lead to transition, identifys those frequencies which are the most dangerous, and indicates how the external parameters can best be changed to avoid transition.

Experiments on Hypersonic Roughness Induced Transition by Means of Infrared Thermography

NASA Astrophysics Data System (ADS)

Schrijer, F. F. J.; Scarano, F.; van Oudheusden, B. W.; Bannink, W. J.

2005-02-01

Roughness induced boundary layer transition is experimentally investigated in the hypersonic flow regime at M = 9. The primary interest is the possible effect of stepwise geometry imperfections (2D isolated roughness) on (boundary layer) transition which may be caused on the EXPERT vehicle by the difference in thermal expansion due to the different materials used in the vehicle-nose construction. Also 3D isolated and 3D distributed roughness configurations were studied. Quantitative Infra-Red Thermography (QIRT) is used as primary diagnostic technique to measure the surface convective heat transfer and to detect boundary layer laminar-to-turbulent transition. The investigation shows that for a given height of the roughness element, the boundary layer is least sensitive to a step-like disturbance, whereas distributed 3D roughness was found to be effective in triggering transition. The experimental results have been compared to existing hypersonic transition correlations (PANT and Shuttle). Finally a transition criterion is evaluated which is based on the critical roughness height Reynolds number. Usage of this criterion enables a straightforward extrapolation to flight. Key words: hypersonic flow, boundary layer transition.

Comparison of Theoretical and Experimental Heat-Transfer Characteristics of Bodies of Revolution at Supersonic Speeds

NASA Technical Reports Server (NTRS)

Scherrer, Richard

1951-01-01

An investigation of the three important factors that determine convective heat-transfer characteristics at supersonic speeds, location boundary-layer transition, recovery factor, and heat-transfer parameter has been performed at Mach numbers from 1.49 to 1.18. The bodies of revolution that were tested had, in most cases, laminar boundary layers, and the test results have been compared with available theory. Boundary-layer transition was found to be affected by heat transfer. Adding heat to a laminar boundary layer caused transition to move forward on the test body, while removing heat caused transition to move rearward. These experimental results and the implications of boundary-layer-stability theory are in qualitative agreement.

Self-sustained Flow-acoustic Interactions in Airfoil Transitional Boundary Layers

DTIC Science & Technology

2015-07-09

AFRL-AFOSR-VA-TR-2015-0235 Self-sustained flow-acoustic interactions in airfoil transitional boundary layers Vladimir Golubev EMBRY-RIDDLE...From - To)      01-04-2012 to 31-03-2015 4.  TITLE AND SUBTITLE Self-sustained flow-acoustic interactions in airfoil transitional boundary layers 5a...complementary experimental and numerical studies of flow-acoustic resonant interactions in transitional airfoils and their impact on airfoil surface

Determination of Boundary-Layer Transition on Three Symmetrical Airfoils in the NACA Full-Scale Wind Tunnel

NASA Technical Reports Server (NTRS)

Silverstein, Abe; Becker, John V

1938-01-01

For the purpose of studying the transition from laminar to turbulent flow, boundary-layer measurements were made in the NACA full-scale wind tunnel on three symmetrical airfoils of NACA 0009, 0012, and 0018 sections. The effects of variations in lift coefficient, Reynolds number, and airfoil thickness on transition were investigated. Air speed in the boundary layer was measured by total-head tubes and by hot wires; a comparison of transition as indicated by the two techniques was obtained. The results indicate no unique value of Reynolds number for the transition, whether the Reynolds number is based upon the distance along the chord or upon the thickness of the boundary layer at the transition point. In general, the transition is not abrupt and occurs in a region that varies in length as a function of the test conditions.

Tunable Bragg filters with a phase transition material defect layer

DOE PAGES

Wang, Xi; Gong, Zilun; Dong, Kaichen; ...

2016-01-01

We propose an all-solid-state tunable Bragg filter with a phase transition material as the defect layer. Bragg filters based on a vanadium dioxide defect layer sandwiched between silicon dioxide/titanium dioxide Bragg gratings are experimentally demonstrated. Temperature dependent reflection spectroscopy shows the dynamic tunability and hysteresis properties of the Bragg filter. Temperature dependent Raman spectroscopy reveals the connection between the tunability and the phase transition of the vanadium dioxide defect layer. This work paves a new avenue in tunable Bragg filter designs and promises more applications by combining phase transition materials and optical cavities.

Tunable Bragg filters with a phase transition material defect layer

DOE Office of Scientific and Technical Information (OSTI.GOV)

Wang, Xi; Gong, Zilun; Dong, Kaichen

We propose an all-solid-state tunable Bragg filter with a phase transition material as the defect layer. Bragg filters based on a vanadium dioxide defect layer sandwiched between silicon dioxide/titanium dioxide Bragg gratings are experimentally demonstrated. Temperature dependent reflection spectroscopy shows the dynamic tunability and hysteresis properties of the Bragg filter. Temperature dependent Raman spectroscopy reveals the connection between the tunability and the phase transition of the vanadium dioxide defect layer. This work paves a new avenue in tunable Bragg filter designs and promises more applications by combining phase transition materials and optical cavities.

An experimental investigation of wall boundary layer transition Reynolds numbers in an expansion tube

NASA Technical Reports Server (NTRS)

Weilmuenster, K. J.

1974-01-01

Experimental measurements of boundary-layer transition in an expansion-tube test-gas flow are presented along with radial distributions of pitot pressure. An integral method for calculating constant Reynolds number lines for an expansion-tube flow is introduced. Comparison of experimental data and constant Reynolds number calculations has shown that for given conditions, wall boundary-layer transition occurs at a constant Reynolds number in an expansion-tube flow. Operating conditions in the expansion tube were chosen so that the effects of test-gas nonequilibrium on boundary-layer transition could be studied.

Boundary-field-driven control of discontinuous phase transitions on hyperbolic lattices

NASA Astrophysics Data System (ADS)

Lee, Yoju; Verstraete, Frank; Gendiar, Andrej

2016-08-01

The multistate Potts models on two-dimensional hyperbolic lattices are studied with respect to various boundary effects. The free energy is numerically calculated using the corner transfer matrix renormalization group method. We analyze phase transitions of the Potts models in the thermodynamic limit with respect to contracted boundary layers. A false phase transition is present even if a couple of the boundary layers are contracted. Its significance weakens, as the number of the contracted boundary layers increases, until the correct phase transition (deep inside the bulk) prevails over the false one. For this purpose, we derive a thermodynamic quantity, the so-called bulk excess free energy, which depends on the contracted boundary layers and memorizes additional boundary effects. In particular, the magnetic field is imposed on the outermost boundary layer. While the boundary magnetic field does not affect the second-order phase transition in the bulk if suppressing all the boundary effects on the hyperbolic lattices, the first-order (discontinuous) phase transition is significantly sensitive to the boundary magnetic field. Contrary to the phase transition on the Euclidean lattices, the discontinuous phase transition on the hyperbolic lattices can be continuously controlled (within a certain temperature coexistence region) by varying the boundary magnetic field.

Competitions between Rayleigh-Taylor instability and Kelvin-Helmholtz instability with continuous density and velocity profiles

DOE Office of Scientific and Technical Information (OSTI.GOV)

Ye, W. H.; He, X. T.; CAPT, Peking University, Beijing 100871

2011-02-15

In this research, competitions between Rayleigh-Taylor instability (RTI) and Kelvin-Helmholtz instability (KHI) in two-dimensional incompressible fluids within a linear growth regime are investigated analytically. Normalized linear growth rate formulas for both the RTI, suitable for arbitrary density ratio with continuous density profile, and the KHI, suitable for arbitrary density ratio with continuous density and velocity profiles, are obtained. The linear growth rates of pure RTI ({gamma}{sub RT}), pure KHI ({gamma}{sub KH}), and combined RTI and KHI ({gamma}{sub total}) are investigated, respectively. In the pure RTI, it is found that the effect of the finite thickness of the density transition layermore » (L{sub {rho}}) reduces the linear growth of the RTI (stabilizes the RTI). In the pure KHI, it is found that conversely, the effect of the finite thickness of the density transition layer increases the linear growth of the KHI (destabilizes the KHI). It is found that the effect of the finite thickness of the density transition layer decreases the ''effective'' or ''local'' Atwood number (A) for both the RTI and the KHI. However, based on the properties of {gamma}{sub RT}{proportional_to}{radical}(A) and {gamma}{sub KH}{proportional_to}{radical}(1-A{sup 2}), the effect of the finite thickness of the density transition layer therefore has a completely opposite role on the RTI and the KHI noted above. In addition, it is found that the effect of the finite thickness of the velocity shear layer (L{sub u}) stabilizes the KHI, and for the most cases, the combined effects of the finite thickness of the density transition layer and the velocity shear layer (L{sub {rho}=}L{sub u}) also stabilize the KHI. Regarding the combined RTI and KHI, it is found that there is a competition between the RTI and the KHI because of the completely opposite effect of the finite thickness of the density transition layer on these two kinds of instability. It is found that the competitions between the RTI and the KHI depend, respectively, on the Froude number, the density ratio of the light fluid to the heavy one, and the finite thicknesses of the density transition layer and the velocity shear layer. Furthermore, for the fixed Froude number, the linear growth rate ratio of the RTI to the KHI decreases with both the density ratio and the finite thickness of the density transition layer, but increases with the finite thickness of the velocity shear layer and the combined finite thicknesses of the density transition layer and the velocity shear layer (L{sub {rho}=}L{sub u}). In summary, our analytical results show that the effect of the finite thickness of the density transition layer stabilizes the RTI and the overall combined effects of the finite thickness of the density transition layer and the velocity shear layer (L{sub {rho}=}L{sub u}) also stabilize the KHI. Thus, it should be included in applications where the transition layer effect plays an important role, such as the formation of large-scale structures (jets) in high energy density physics and astrophysics and turbulent mixing.« less

Tuning SPT-3G Transition-Edge-Sensor Electrical Properties with a Four-Layer Ti-Au-Ti-Au Thin-Film Stack

NASA Astrophysics Data System (ADS)

Carter, F. W.; Ade, P. A. R.; Ahmed, Z.; Anderson, A. J.; Austermann, J. E.; Avva, J. S.; Thakur, R. Basu; Bender, A. N.; Benson, B. A.; Carlstrom, J. E.; Cecil, T.; Chang, C. L.; Cliche, J. F.; Cukierman, A.; Denison, E. V.; de Haan, T.; Ding, J.; Divan, R.; Dobbs, M. A.; Dutcher, D.; Everett, W.; Foster, A.; Gannon, R. N.; Gilbert, A.; Groh, J. C.; Halverson, N. W.; Harke-Hosemann, A. H.; Harrington, N. L.; Henning, J. W.; Hilton, G. C.; Holzapfel, W. L.; Huang, N.; Irwin, K. D.; Jeong, O. B.; Jonas, M.; Khaire, T.; Kofman, A. M.; Korman, M.; Kubik, D.; Kuhlmann, S.; Kuo, C. L.; Kutepova, V.; Lee, A. T.; Lowitz, A. E.; Meyer, S. S.; Michalik, D.; Miller, C. S.; Montgomery, J.; Nadolski, A.; Natoli, T.; Nguyen, H.; Noble, G. I.; Novosad, V.; Padin, S.; Pan, Z.; Pearson, J.; Posada, C. M.; Rahlin, A.; Ruhl, J. E.; Saunders, L. J.; Sayre, J. T.; Shirley, I.; Shirokoff, E.; Smecher, G.; Sobrin, J. A.; Stan, L.; Stark, A. A.; Story, K. T.; Suzuki, A.; Tang, Q. Y.; Thompson, K. L.; Tucker, C.; Vale, L. R.; Vanderlinde, K.; Vieira, J. D.; Wang, G.; Whitehorn, N.; Yefremenko, V.; Yoon, K. W.; Young, M. R.

2018-04-01

We have developed superconducting Ti transition-edge sensors with Au protection layers on the top and bottom for the South Pole Telescope's third-generation receiver (a cosmic microwave background polarimeter, due to be upgraded this austral summer of 2017/2018). The base Au layer (deposited on a thin Ti glue layer) isolates the Ti from any substrate effects; the top Au layer protects the Ti from oxidation during processing and subsequent use of the sensors. We control the transition temperature and normal resistance of the sensors by varying the sensor width and the relative thicknesses of the Ti and Au layers. The transition temperature is roughly six times more sensitive to the thickness of the base Au layer than to that of the top Au layer. The normal resistance is inversely proportional to sensor width for any given film configuration. For widths greater than five micrometers, the critical temperature is independent of width.

A nonperturbing boundary-layer transition detection

NASA Astrophysics Data System (ADS)

Ohare, J. E.

1985-01-01

A laser interferometer technique is being applied to the characterization of boundary-layer conditions on models in supersonic and hypersonic wind tunnels in the von Karman Facility at Arnold Engineering Development Center (AEDC). The Boundary-Layer Transition Detector (BLTD), based on lateral interferometry, is applicable for determining the turbulence frequency spectrum of boundary layers in compressible flow. The turbulence, in terms of air density fluctuations, is detected by monitoring interferometric fringe phase shifts (in real time) formed by one beam which passes through the boundary layer and a reference beam which is outside the boundary layer. This technique is nonintrusive to the flow field unlike other commonly used methods such as pitot tube probing and hot-wire anemometry. Model boundary-layer data are presented at Mach 8 and compared with data recorded using other methods during boundary-layer transition from laminar to turbulent flow. Spectra from the BLTD reveal the presence of a high-frequency peak during transition, which is characteristic of spectra obtained with hot wires. The BLTD is described along with operational requirements and limitations.

A Nonperturbing Boundary-Layer Transition Detector

NASA Astrophysics Data System (ADS)

O'Hare, J. E.

1986-01-01

A laser interferometer technique is being applied to the characterization of boundary-layer conditions on models in supersonic and hypersonic wind tunnels in the von Kaman Facility at Arnold Engineering Development Center (AEDC). The Boundary-Layer Transition Detector (BLTD), based on lateral interferometry, is applicable for determining the turbulence frequency spectrum of boundary layers in compressible flow. The turbulence, in terms of air density fluctuations, is detected by monitoring interferometric fringe phase shifts (in real time) formed by one beam which passes through the boundary layer and a reference beam which is outside the boundary layer. This technique is nonintrusive to the flow field unlike other commonly used methods such as pitot tube probing and hot-wire anemometry. Model boundary-layer data are presented at Mach 8 and compared with data recorded using other methods during boundary-layer transition from laminar to turbulent flow. Spectra from the BLTD reveal the presence of a high-frequency peak during transition, which is characteristic of spectra obtained with hot wires. The BLTD is described along with operational requirements and limitations.

Boundary-layer transition on a plate subjected to simultaneous spanwise and chordwise pressure gradients

NASA Technical Reports Server (NTRS)

Boldman, D. R.; Brinich, P. F.

1974-01-01

The boundary-layer transition on a short plate was studied by means of the china-clay visual technique. The plate model was mounted in a wind tunnel so that it was subjected to small simultaneous spanwise and chordwise pressure gradients. Results of the experimental study, which was performed at three subsonic velocities, indicated that the transition pattern was appreciably curved in the spanwise direction but quite smooth and well behaved. Reasonable comparisons between predictions of transition and experiment were obtained from two finite-difference two-dimensional boundary-layer calculation methods which incorporated transition models based on the concept of a transition intermittency factor.

Shuttle Return To Flight Experimental Results: Cavity Effects on Boundary Layer Transition

NASA Technical Reports Server (NTRS)

Liechty, Derek S.; Horvath, Thomas J.; Berry, Scott A.

2006-01-01

The effect of an isolated rectangular cavity on hypersonic boundary layer transition of the windward surface of the Shuttle Orbiter has been experimentally examined in the Langley Aerothermodynamics Laboratory in support of an agency-wide effort to prepare the Shuttle Orbiter for return to flight. This experimental study was initiated to provide a cavity effects database for developing hypersonic transition criteria to support on-orbit decisions to repair a damaged thermal protection system. Boundary layer transition results were obtained using 0.0075-scale Orbiter models with simulated tile damage (rectangular cavities) of varying length, width, and depth. The database contained within this report will be used to formulate cavity-induced transition correlations using predicted boundary layer edge parameters.

Laminar-turbulent transition tripped by step on transonic compressor profile

NASA Astrophysics Data System (ADS)

Flaszynski, Pawel; Doerffer, Piotr; Szwaba, Ryszard; Piotrowicz, Michal; Kaczynski, Piotr

2018-02-01

The shock wave boundary layer interaction on the suction side of transonic compressor blade is one of the main objectives of TFAST project (Transition Location Effect on Shock Wave Boundary Layer Interaction). The experimental and numerical results for the flow structure investigations are shown for the flow conditions as the existing ones on the suction side of the compressor profile. The two cases are investigated: without and with boundary layer tripping device. In the first case, boundary layer is laminar up to the shock wave, while in the second case the boundary layer is tripped by the step. Numerical results carried out by means of Fine/Turbo Numeca with Explicit Algebraic Reynolds Stress Model including transition modeling are compared with schlieren, Temperature Sensitive Paint and wake measurements. Boundary layer transition location is detected by Temperature Sensitive Paint.

Shuttle Return To Flight Experimental Results: Protuberance Effects on Boundary Layer Transition

NASA Technical Reports Server (NTRS)

Liechty, Derek S.; Berry, Scott A.; Horvath, Thomas J.

2006-01-01

The effect of isolated roughness elements on the windward boundary layer of the Shuttle Orbiter has been experimentally examined in the Langley Aerothermodynamic Laboratory in support of an agency-wide effort to prepare the Shuttle Orbiter for return to flight. This experimental effort was initiated to provide a roughness effects database for developing transition criteria to support on-orbit decisions to repair damage to the thermal protection system. Boundary layer transition results were obtained using trips of varying heights and locations along the centerline and attachment lines of 0.0075-scale models. Global heat transfer images using phosphor thermography of the Orbiter windward surface and the corresponding heating distributions were used to infer the state of the boundary layer (laminar, transitional, or turbulent). The database contained within this report will be used to formulate protuberance-induced transition correlations using predicted boundary layer edge parameters.

A preliminary investigation of boundary-layer transition along a flat plate with adverse pressure gradient

NASA Technical Reports Server (NTRS)

Von Doenhoff, Albert E

1938-01-01

Boundary-layer surveys were made throughout the transition region along a smooth flat plate placed in an airstream of practically zero turbulence and with an adverse pressure gradient. The boundary-layer Reynolds number at the laminar separation point was varied from 1,800 to 2,600. The test data, when considered in the light of certain theoretical deductions, indicated that transition probably began with separation of the laminar boundary layer. The extent of the transition region, defined as the distance from a calculated laminar separation point to the position of the first fully developed turbulent boundary-layer profile, could be expressed as a constant Reynolds number run of approximately 70,000. Some speculations are presented concerning the application of the foregoing concepts, after certain assumptions have been made, to the problem of the connection between transition on the upper surface of an airfoil at high angles of attack and the maximum lift.

DNSs of Multicomponent Gaseous and Drop-Laden Mixing Layers Achieving Transition to Turbulence

NASA Technical Reports Server (NTRS)

Bellan, Josette; Selle, Laurent

2007-01-01

A paper describes direct numerical simulations (DNSs) of three-dimensional mixing-layer flows undergoing transition to turbulence; the mixing layers may or may not be laden with evaporating liquid drops.

Dynamical Generation of the Transition Zone in the Earth's Mantle

NASA Astrophysics Data System (ADS)

Hansen, U.; Stemmer, K.

2005-12-01

The internal structure of the Earth is made up by a series of layers, though it is unclear how many layers exist and if there are layers invisible to remote sensing techniques. The transition zone is likely to be a boundary layer separating the convective systems in the lower and upper mantle. It seems likely that currently there is some mass exchange across this boundary, rather than the two systems beeing strictly separated.a Double-diffusive convection(d.d.c) is a vital mechanism which can generate layered structure and may thus be an important mmical machinery behind the formation of the transition zone. Double-diffusive convection determines the dynamics of systems whose density is influenced by at least two components with different molecular diffusivities.In the mantle, composition and temperature play the role of those two components. By means of numerical experiments we demonstrate that under mantle relevant conditions d.d.c typically leads to the formation of a transition zone. The calculations encompass two- and three dimensional Cartesian geometries as well as fully 3D spherical domains. We have further included strongly temperature dependent viscosity and find that this leads to even more pronounced layering. In most cases a layered flow pattern emerges, where two layers with a transition zone in between resembles a quasistationary state. Thus, the transition zone can be the result of a self organization process of the convective flow in the mantle. The presence of a phase transition further helps to stabilize the boundary against overturning, even on a time scale on the order of the age of the Earth.

A brief review of some mechanisms causing boundary layer transition at high speeds

NASA Technical Reports Server (NTRS)

Tauber, M. E.

1990-01-01

In high speed flight, the state of the boundary layer can strongly influence the design of vehicles through its effect on skin friction drag and aerodynamic heating. The major mechanisms causing boundary layer transition on high speed vehicles are briefly reviewed and some empirical relations from the unclassified literature are given for the transition Reynolds numbers.

Effect of Surface Waviness on Transition in Three-Dimensional Boundary-Layer Flow

NASA Technical Reports Server (NTRS)

Masad, Jamal A.

1996-01-01

The effect of a surface wave on transition in three-dimensional boundary-layer flow over an infinite swept wing was studied. The mean flow computed using interacting boundary-layer theory, and transition was predicted using linear stability theory coupled with the empirical eN method. It was found that decreasing the wave height, sweep angle, or freestream unit Reynolds number, and increasing the freestream Mach number or suction level all stabilized the flow and moved transition onset to downstream locations.

Correlation of nosetip boundary-layer transition data measured in ballistics-range experiments

DOE Office of Scientific and Technical Information (OSTI.GOV)

Reda, D.C.

1979-11-01

Preablated nosetips of various carbonaceous materials were tested in a ballistics range. Surface-temperature contours, measured with image-converter cameras, were used to define boundary-layer transition-fron contours. Measurements of surface roughness, surface temperature, average transition-calculations of nosetip flowfields, and with calculations of laminar boundary-layer development in these flowfields, to transform all data into various dimensionless parameters. These parameters were defined by previous attempts to correlate existing wind-tunnel data for transition on rough/blunt bodies.

Flight Experiment Verification of Shuttle Boundary Layer Transition Prediction Tool

NASA Technical Reports Server (NTRS)

Berry, Scott A.; Berger, Karen T.; Horvath, Thomas J.; Wood, William A.

2016-01-01

Boundary layer transition at hypersonic conditions is critical to the design of future high-speed aircraft and spacecraft. Accurate methods to predict transition would directly impact the aerothermodynamic environments used to size a hypersonic vehicle's thermal protection system. A transition prediction tool, based on wind tunnel derived discrete roughness correlations, was developed and implemented for the Space Shuttle return-to-flight program. This tool was also used to design a boundary layer transition flight experiment in order to assess correlation uncertainties, particularly with regard to high Mach-number transition and tunnel-to-flight scaling. A review is provided of the results obtained from the flight experiment in order to evaluate the transition prediction tool implemented for the Shuttle program.

Flight-measured laminar boundary-layer transition phenomena including stability theory analysis

NASA Technical Reports Server (NTRS)

Obara, C. J.; Holmes, B. J.

1985-01-01

Flight experiments were conducted on a single-engine turboprop aircraft fitted with a 92-in-chord, 3-ft-span natural laminar flow glove at glove section lift coefficients from 0.15 to 1.10. The boundary-layer transition measurement methods used included sublimating chemicals and surface hot-film sensors. Transition occurred downstream of the minimum pressure point. Hot-film sensors provided a well-defined indication of laminar, laminar-separation, transitional, and turbulent boundary layers. Theoretical calculations of the boundary-layer parameters provided close agreement between the predicted laminar-separation point and the measured transition location. Tollmien-Schlichting (T-S) wave growth n-factors between 15 and 17 were calculated at the predicted point of laminar separation. These results suggest that for many practical airplane cruise conditions, laminar separation (as opposed to T-S instability) is the major cause of transition in predominantly two-dimensional flows.

Atomically thin transition metal layers: Atomic layer stabilization and metal-semiconductor transition

NASA Astrophysics Data System (ADS)

Hwang, Jeongwoon; Oh, Young Jun; Kim, Jiyoung; Sung, Myung Mo; Cho, Kyeongjae

2018-04-01

We have performed first-principle calculations to explore the possibility of synthesizing atomically thin transition metal (TM) layers. Buckled structures as well as planar structures of elemental 2D TM layers result in significantly higher formation energies compared with sp-bonded elemental 2D materials with similar structures, such as silicene and phosphorene. It is shown that the TM layers can be stabilized by surface passivation with HS, C6H5S2, or O, and O passivation is most effective. The surface oxygen passivation can improve stability leading to thermodynamically stable TM monolayers except Au, which is the most non-reactive metal element. Such stabilized TM monolayers also show an electronic structure transition from metallic state of free-standing TM layer to semiconducting O-passivated Mo and W monolayers with band gaps of 0.20-1.38 eV.

Shuttle orbiter boundary layer transition at flight and wind tunnel conditions

NASA Technical Reports Server (NTRS)

Goodrich, W. D.; Derry, S. M.; Bertin, J. J.

1983-01-01

Hypersonic boundary layer transition data obtained on the windward centerline of the Shuttle orbiter during entry for the first five flights are presented and analyzed. Because the orbiter surface is composed of a large number of thermal protection tiles, the transition data include the effects of distributed roughness arising from tile misalignment and gaps. These data are used as a benchmark for assessing and improving the accuracy of boundary layer transition predictions based on correlations of wind tunnel data taken on both aerodynamically rough and smooth orbiter surfaces. By comparing these two data bases, the relative importance of tunnel free stream noise and surface roughness on orbiter boundary layer transition correlation parameters can be assessed. This assessment indicates that accurate predications of transition times can be made for the orbiter at hypersonic flight conditions by using roughness dominated wind tunnel data. Specifically, times of transition onset and completion is accurately predicted using a correlation based on critical and effective values of a roughness Reynolds number previously derived from wind tunnel data.

Heat transfer and fluid mechanics measurements in transitional boundary layer flows

NASA Technical Reports Server (NTRS)

Wang, T.; Simon, T. W.; Buddhavarapu, J.

1985-01-01

Experimental results are presented to document hydrodynamic and thermal development of flat-plate boundary layers undergoing natural transition. Local heat transfer coefficients, skin friction coefficients and profiles of velocity, temperature and Reynolds normal and shear stresses are presented. A case with no transition and transitional cases with 0.68% and 2.0% free-stream disturbance intensities were investigated. The locations of transition are consistent with earlier data. A late-laminar state with significant levels of turbulence is documented. In late-transitional and early-turbulent flows, turbulent Prandtl number and conduction layer thickness values exceed, and the Reynolds analogy factor is less than, values previously measured in fully turbulent flows.

A nonperturbing boundary-layer transition detector

NASA Astrophysics Data System (ADS)

Ohare, J. E.

1985-11-01

A laser interferometer technique is being applied to the characterization of boundary-layer conditions on models in supersonic and hypersonic wind tunnels. The boundary-layer transition detector (BLTD), based on lateral interferometry, is applicable for determining the turbulence frequency spectrum of boundary layers in compressible flow. The turbulence, in terms of air density fluctuations, is detected by monitoring interferometric fringe phase shifts (in real time) formed by one beam which passes through the boundary layer and a reference beam which is outside the boundary layer. This technique is nonintrusive to the flow field unlike other commonly used methods such as pitot tube probing and hot-wire anemometry. Data which depict boundary-layer transition from laminar to turbulent flow are presented to provide comparisons of the BLTD with other measurement methods. Spectra from the BLTD reveals the presence of a high-frequency peak during transition which is characteristic of spectra obtained with hot wires. The BLTD is described along with operational requirements and limitations.

Numerical investigation of hypersonic flat-plate boundary layer transition mechanism induced by different roughness shapes

NASA Astrophysics Data System (ADS)

Zhou, Yunlong; Zhao, Yunfei; Xu, Dan; Chai, Zhenxia; Liu, Wei

2016-10-01

The roughness-induced laminar-turbulent boundary layer transition is significant for high-speed aerospace applications. The transition mechanism is closely related to the roughness shape. In this paper, high-order numerical method is used to investigate the effect of roughness shape on the flat-plate laminar-to-turbulent boundary layer transition. Computations are performed in both the supersonic and hypersonic regimes (free-stream Mach number from 3.37 up to 6.63) for the square, cylinder, diamond and hemisphere roughness elements. It is observed that the square and diamond roughness elements are more effective in inducing transition compared with the cylinder and hemisphere ones. The square roughness element has the longest separated region in which strong unsteadiness exists and the absolute instability is formed, thus resulting in the earliest transition. The diamond roughness element has a maximum width of the separated region leading to the widest turbulent wake region far downstream. Furthermore, transition location moves backward as the Mach number increases, which indicates that the compressibility significantly suppresses the roughness-induced boundary layer transition.

Hypersonic Boundary Layer Transition Measurements Using NO2 approaches NO Photo-dissociation Tagging Velocimetry

NASA Technical Reports Server (NTRS)

Bathel, Brett F.; Johansen, Craig T.; Danehy, Paul M.; Inman, Jennifer A.; Jones, Stephen B.; Goyne, Christopher P.

2011-01-01

Measurements of instantaneous and mean streamwise velocity profiles in a hypersonic laminar boundary layer as well as a boundary layer undergoing laminar-to-turbulent transition were obtained over a 10-degree half-angle wedge model. A molecular tagging velocimetry technique consisting of a NO2 approaches?NO photo-dissociation reaction and two subsequent excitations of NO was used. The measurement of the transitional boundary layer velocity profiles was made downstream of a 1-mm tall, 4-mm diameter cylindrical trip along several lines lying within a streamwise measurement plane normal to the model surface and offset 6-mm from the model centerline. For laminar and transitional boundary layer measurements, the magnitudes of streamwise velocity fluctuations are compared. In the transitional boundary layer the fluctuations were, in general, 2-4 times larger than those in the laminar boundary layer. Of particular interest were fluctuations corresponding to a height of approximately 50% of the laminar boundary layer thickness having a magnitude of nearly 30% of the mean measured velocity. For comparison, the measured fluctuations in the laminar boundary layer were approximately 5% of the mean measured velocity at the same location. For the highest 10% signal-to-noise ratio data, average single-shot uncertainties using a 1 ?Es and 50 ?Es interframe delay were 115 m/s and 3 m/s, respectively. By averaging single-shot measurements of the transitional boundary layer, uncertainties in mean velocity as low as 39 m/s were obtained in the wind tunnel. The wall-normal and streamwise spatial resolutions were 0.14-mm (2 pixel) and 0.82-mm (11 pixels), respectively. These measurements were performed in the 31-inch Mach 10 Air Wind Tunnel at the NASA Langley Research Center.

Direct simulation of flat-plate boundary layer with mild free-stream turbulence

NASA Astrophysics Data System (ADS)

Wu, Xiaohua; Moin, Parviz

2014-11-01

Spatially evolving direct numerical simulation of the flat-plate boundary layer has been performed. The momentum thickness Reynolds number develops from 80 to 3000 with a free-stream turbulence intensity decaying from 3 percent to 0.8 percent. Predicted skin-friction is in agreement with the Blasius solution prior to breakdown, follows the well-known T3A bypass transition data during transition, and agrees with the Erm and Joubert Melbourne wind-tunnel data after the completion of transition. We introduce the concept of bypass transition in the narrow sense. Streaks, although present, do not appear to be dynamically important during the present bypass transition as they occur downstream of infant turbulent spots. For the turbulent boundary layer, viscous scaling collapses the rate of dissipation profiles in the logarithmic region at different Reynolds numbers. The ratio of Taylor microscale and the Kolmogorov length scale is nearly constant over a large portion of the outer layer. The ratio of large-eddy characteristic length and the boundary layer thickness scales very well with Reynolds number. The turbulent boundary layer is also statistically analyzed using frequency spectra, conditional-sampling, and two-point correlations. Near momentum thickness Reynolds number of 2900, three layers of coherent vortices are observed: the upper and lower layers are distinct hairpin forests of large and small sizes respectively; the middle layer consists of mostly fragmented hairpin elements.

Ab Initio Study of Interfacial Structure Transformation of Amorphous Carbon Catalyzed by Ti, Cr, and W Transition Layers.

PubMed

Li, Xiaowei; Li, Lei; Zhang, Dong; Wang, Aiying

2017-11-29

Amorphous carbon (a-C) films composited with transition layers exhibit the desirable improvement of adhesion strength between films and substrate, but the further understanding on the interfacial structure transformation of a-C structure induced by transition layers is still lacked. In this paper, using ab initio calculations, we comparatively studied the interfacial structure between Ti, Cr, or W transition layers and a-C film from the atomic scale, and demonstrated that the addition of Ti, Cr, or W catalyzed the graphitic transformation of a-C structure at different levels, which provided the theoretical guidance for designing a multilayer nanocomposite film for renewed application.

A stable lithium-rich surface structure for lithium-rich layered cathode materials

PubMed Central

Kim, Sangryun; Cho, Woosuk; Zhang, Xiaobin; Oshima, Yoshifumi; Choi, Jang Wook

2016-01-01

Lithium ion batteries are encountering ever-growing demand for further increases in energy density. Li-rich layered oxides are considered a feasible solution to meet this demand because their specific capacities often surpass 200 mAh g−1 due to the additional lithium occupation in the transition metal layers. However, this lithium arrangement, in turn, triggers cation mixing with the transition metals, causing phase transitions during cycling and loss of reversible capacity. Here we report a Li-rich layered surface bearing a consistent framework with the host, in which nickel is regularly arranged between the transition metal layers. This surface structure mitigates unwanted phase transitions, improving the cycling stability. This surface modification enables a reversible capacity of 218.3 mAh g−1 at 1C (250 mA g−1) with improved cycle retention (94.1% after 100 cycles). The present surface design can be applied to various battery electrodes that suffer from structural degradations propagating from the surface. PMID:27886178

Superconductive coupling in tailored [(SnSe)1+δ ] m (NbSe2)1 multilayers

NASA Astrophysics Data System (ADS)

Trahms, Martina; Grosse, Corinna; Alemayehu, Matti B.; Hite, Omar K.; Chiatti, Olivio; Mogilatenko, Anna; Johnson, David C.; Fischer, Saskia F.

2018-06-01

Ferecrystals are a new artificially layered material system, in which the individual layers are stacked with monolayer precision and are turbostratically disordered. Here, the superconducting coupling of the NbSe2 layers in [(SnSe)1+δ ] m [NbSe2]1 ferecrystals with m between 1 and 6 are investigated. The variation of m effectively increases the distance between the superconducting NbSe2 monolayers. We find a systematic decrease of the transition temperature with an increasing number of SnSe layers per repeat unit. For m = 9 a superconducting transition can no longer be observed at temperatures above 250 mK. In order to investigate the superconducting coupling between individual NbSe2 layers, the cross-plane Ginzburg–Landau coherence lengths were determined. Electric transport measurements of the superconducting transition were performed in the presence of a magnetic field, oriented parallel and perpendicular to the layers, at temperatures closely below the transition temperature. A decoupling with increasing distance of the NbSe2 layers is observed. However, ferecrystals with NbSe2 layers separated by up to six layers of SnSe are still considered as three-dimensional superconductors.

Overview of Boundary Layer Transition Research in Support of Orbiter Return To Flight

NASA Technical Reports Server (NTRS)

Berry, Scott A.; Horvath, Thomas J.; Greene, Francis A.; Kinder, Gerald R.; Wang, K. C.

2006-01-01

A predictive tool for estimating the onset of boundary layer transition resulting from damage to and/or repair of the thermal protection system was developed in support of Shuttle Return to Flight. The boundary layer transition tool is part of a suite of tools that analyze the aerothermodynamic environment to the local thermal protection system to allow informed disposition of damage for making recommendations to fly as is or to repair. Using mission specific trajectory information and details of each damage site or repair, the expected time (and thus Mach number) at transition onset is predicted to help define the aerothermodynamic environment to use in the subsequent thermal and stress analysis of the local thermal protection system and structure. The boundary layer transition criteria utilized for the tool was developed from ground-based measurements to account for the effect of both protuberances and cavities and has been calibrated against select flight data. Computed local boundary layer edge conditions were used to correlate the results, specifically the momentum thickness Reynolds number over the edge Mach number and the boundary layer thickness. For the initial Return to Flight mission, STS-114, empirical curve coefficients of 27, 100, and 900 were selected to predict transition onset for protuberances based on height, and cavities based on depth and length, respectively.

Stripline/Microstrip Transition in Multilayer Circuit Board

NASA Technical Reports Server (NTRS)

Epp, Larry; Khan, Abdur

2005-01-01

A stripline-to-microstrip transition has been incorporated into a multilayer circuit board that supports a distributed solid-state microwave power amplifier, for the purpose of coupling the microwave signal from a buried-layer stripline to a top-layer microstrip. The design of the transition could be adapted to multilayer circuit boards in such products as cellular telephones (for connecting between circuit-board signal lines and antennas), transmitters for Earth/satellite communication systems, and computer mother boards (if processor speeds increase into the range of tens of gigahertz). The transition is designed to satisfy the following requirements in addition to the basic coupling requirement described above: (1) The transition must traverse multiple layers, including intermediate layers that contain DC circuitry. (2) The transition must work at a frequency of 32 GHz with low loss and low reflection. (3) The power delivered by the transition to top-layer microstrip must be split equally in opposite directions along the microstrip. Referring to the figure, this amounts to a requirement that when power is supplied to input port 1, equal amounts of power flow through output ports 2 and 3. (4) The signal-line via that is necessarily a part of such a transition must not be what is known in the art as a blind via; that is, it must span the entire thickness of the circuit board.

Competition of simple and complex adoption on interdependent networks

NASA Astrophysics Data System (ADS)

Czaplicka, Agnieszka; Toral, Raul; San Miguel, Maxi

2016-12-01

We consider the competition of two mechanisms for adoption processes: a so-called complex threshold dynamics and a simple susceptible-infected-susceptible (SIS) model. Separately, these mechanisms lead, respectively, to first-order and continuous transitions between nonadoption and adoption phases. We consider two interconnected layers. While all nodes on the first layer follow the complex adoption process, all nodes on the second layer follow the simple adoption process. Coupling between the two adoption processes occurs as a result of the inclusion of some additional interconnections between layers. We find that the transition points and also the nature of the transitions are modified in the coupled dynamics. In the complex adoption layer, the critical threshold required for extension of adoption increases with interlayer connectivity whereas in the case of an isolated single network it would decrease with average connectivity. In addition, the transition can become continuous depending on the detailed interlayer and intralayer connectivities. In the SIS layer, any interlayer connectivity leads to the extension of the adopter phase. Besides, a new transition appears as a sudden drop of the fraction of adopters in the SIS layer. The main numerical findings are described by a mean-field type analytical approach appropriately developed for the threshold-SIS coupled system.

Boundary-layer development and transition due to free-stream exothermic reactions in shock-induced flows

NASA Technical Reports Server (NTRS)

Hall, J. L.

1974-01-01

A study of the effect of free-stream thermal-energy release from shock-induced exothermic reactions on boundary-layer development and transition is presented. The flow model is that of a boundary layer developing behind a moving shock wave in two-dimensional unsteady flow over a shock-tube wall. Matched sets of combustible hydrogen-oxygen-nitrogen mixtures and inert hydrogen-nitrogen mixtures were used to obtain transition data over a range of transition Reynolds numbers from 1,100,000 to 21,300,000. The heat-energy is shown to significantly stabilize the boundary layer without changing its development character. A method for application of this data to flat-plate steady flows is included.

Rough-to-smooth transition of an equilibrium neutral constant stress layer. [atmospheric flow over rough terrain

NASA Technical Reports Server (NTRS)

Logan, E., Jr.; Fichtl, G. H.

1975-01-01

A model is proposed for low-level atmospheric flows over terrains of changing roughness length, such as those found at the windward end of landing strips adjoining rough terrain. The proposed model is used to develop a prediction technique for calculating transition wind and shear-stress profiles in the region following surface roughness discontinuity. The model for the transition region comprises two layers: a logarithmic layer and a buffer layer. The flow is assumed to be steady, two-dimensional, and incompressible, with neutral hydrostatic stability. A diagram is presented for a typical wind profile in the transition region, obtained from the logarithmic and velocity defect profiles using shear stress calculated by relevant equations.

Control of boundary layer transition location and plate vibration in the presence of an external acoustic field

NASA Technical Reports Server (NTRS)

Maestrello, L.; Grosveld, F. W.

1991-01-01

The experiment is aimed at controlling the boundary layer transition location and the plate vibration when excited by a flow and an upstream sound source. Sound has been found to affect the flow at the leading edge and the response of a flexible plate in a boundary layer. Because the sound induces early transition, the panel vibration is acoustically coupled to the turbulent boundary layer by the upstream radiation. Localized surface heating at the leading edge delays the transition location downstream of the flexible plate. The response of the plate excited by a turbulent boundary layer (without sound) shows that the plate is forced to vibrate at different frequencies and with different amplitudes as the flow velocity changes indicating that the plate is driven by the convective waves of the boundary layer. The acoustic disturbances induced by the upstream sound dominate the response of the plate when the boundary layer is either turbulent or laminar. Active vibration control was used to reduce the sound induced displacement amplitude of the plate.

Study of the Effect of Free-Stream Turbulence upon Disturbances in the Pre-Transitional Laminar Boundary Layer. Part I. Laminar Boundary Layer Distortion by Surface Roughness; Effect upon Stability. Part II.

DTIC Science & Technology

1982-04-01

Boundary Layer Near a Plate." NACA Rept. 562, 1936. 5) A. A. Hall and G. S. Hislop , "Experiments on the Transition of the Laminar Boundary Layer on a...Cylinder." Proc. 5th Inter. Congr. Appl. Math, 1938. 7) G. S. Hislop , "The Transition of a Laminar Boundary Layer in a Wind Tunnel." Ph.D. Thesis...Small Vertical Cylinder Attached to a Flat Plate", h Fa- Elul"s, Vol. 23, Part 1, pp. 221-223, Jan. 1980 . 9. A. Von Doenhoff and E. A. Horton, "A Low

Simulation of dispersion in layered coastal aquifer systems

USGS Publications Warehouse

Reilly, T.E.

1990-01-01

A density-dependent solute-transport formulation is used to examine ground-water flow in layered coastal aquifers. The numerical experiments indicate that although the transition zone may be thought of as an impermeable 'sharp' interface with freshwater flow parallel to the transition zone in homogeneous aquifers, this is not the case for layered systems. Freshwater can discharge through the transition zone in the confining units. Further, for the best simulation of layered coastal aquifer systems, either a flow-direction-dependent dispersion formulation is required, or the dispersivities must change spatially to reflect the tight thin confining unit. ?? 1990.

Forward-facing steps induced transition in a subsonic boundary layer

NASA Astrophysics Data System (ADS)

Zh, Hui; Fu, Song

2017-10-01

A forward-facing step (FFS) immersed in a subsonic boundary layer is studied through a high-order flux reconstruction (FR) method to highlight the flow transition induced by the step. The step height is a third of the local boundary-layer thickness. The Reynolds number based on the step height is 720. Inlet disturbances are introduced giving rise to streamwise vortices upstream of the step. It is observed that these small-scale streamwise structures interact with the step and hairpin vortices are quickly developed after the step leading to flow transition in the boundary layer.

Correlations for Boundary-Layer Transition on Mars Science Laboratory Entry Vehicle Due to Heat-Shield Cavities

NASA Technical Reports Server (NTRS)

Hollis, Brian R.; Liechty, Derek S.

2008-01-01

The influence of cavities (for attachment bolts) on the heat-shield of the proposed Mars Science Laboratory entry vehicle has been investigated experimentally and computationally in order to develop a criterion for assessing whether the boundary layer becomes turbulent downstream of the cavity. Wind tunnel tests were conducted on the 70-deg sphere-cone vehicle geometry with various cavity sizes and locations in order to assess their influence on convective heating and boundary layer transition. Heat-transfer coefficients and boundary-layer states (laminar, transitional, or turbulent) were determined using global phosphor thermography.

Boundary Layer Transition During the Orion Exploration Flight Test 1 (EFT-1)

NASA Technical Reports Server (NTRS)

Kirk, Lindsay C.

2016-01-01

Boundary layer transition was observed in the thermocouple data on the windside backshell of the Orion reentry capsule. Sensors along the windside centerline, as well as off-centerline, indicated transition late in the flight at approximately Mach 4 conditions. Transition progressed as expected, beginning at the sensors closest to the forward bay cover (FBC) and moving towards the heatshield. Sensors placed in off-centerline locations did not follow streamlines, so the progression of transition observed in these sensors is less intuitive. Future analysis will include comparisons to pre-flight predictions and expected transitional behavior will be investigated. Sensors located within the centerline and off-centerline launch abort system (LAS) attach well cavities on the FBC also showed indications of boundary layer transition. The transition within the centerline cavity was observed in the temperature traces prior to transition onset on the sensors upstream of the cavity. Transition behavior within the off centerline LAS attach well cavity will also be investigated. Heatshield thermocouples were placed within Avcoat plugs to attempt to capture transitional behavior as well as better understand the aerothermal environments. Thermocouples were placed in stacks of two or five vertically within the plugs, but the temperature data obtained at the sensors closest to the surface did not immediately indicate transitional behavior. Efforts to use the in depth thermocouple temperatures to reconstruct the surface heat flux are ongoing and any results showing the onset of boundary layer transition obtained from those reconstructions will also be included in this paper. Transition on additional features of interest, including compression pad ramps, will be included if it becomes available.

Structural and electronic properties of the transition layer at the SiO{sub 2}/4H-SiC interface

DOE Office of Scientific and Technical Information (OSTI.GOV)

Li, Wenbo; Wang, Dejun, E-mail: dwang121@dlut.edu.cn; Zhao, Jijun

Using first-principles methods, we generate an amorphous SiO{sub 2}/4H-SiC interface with a transition layer. Based this interface model, we investigate the structural and electronic properties of the interfacial transition layer. The calculated Si 2p core-level shifts for this interface are comparable to the experimental data, indicating that various SiC{sub x}O{sub y} species should be present in this interface transition layer. The analysis of the electronic structures reveals that the tetrahedral SiC{sub x}O{sub y} structures cannot introduce any of the defect states at the interface. Interestingly, our transition layer also includes a C-C=C trimer and SiO{sub 5} configurations, which lead tomore » the generation of interface states. The accurate positions of Kohn-Sham energy levels associated with these defects are further calculated within the hybrid functional scheme. The Kohn-Sham energy levels of the carbon trimer and SiO{sub 5} configurations are located near the conduction and valence band of bulk 4H-SiC, respectively. The result indicates that the carbon trimer occurred in the transition layer may be a possible origin of near interface traps. These findings provide novel insight into the structural and electronic properties of the realistic SiO{sub 2}/SiC interface.« less

A review and analysis of boundary layer transition data for turbine application

NASA Technical Reports Server (NTRS)

Gaugler, R. E.

1985-01-01

A number of data sets from the open literature that include heat transfer data in apparently transitional boundary layers, with particular application to the turbine environment, were reviewed and analyzed to extract transition information. The data were analyzed by using a version of the STAN5 two-dimensional boundary layer code. The transition starting and ending points were determined by adjusting parameters in STAN5 until the calculations matched the data. The results are presented as a table of the deduced transition location and length as functions of the test parameters. The data sets reviewed cover a wide range of flow conditions, from low-speed, flat-plate tests to full-scale turbine airfoils operating at simulated turbine engine conditions. The results indicate that free-stream turbulence and pressure gradient have strong, and opposite, effects on the location of the start of transition and on the length of the transition zone.

Transition in Turbines

NASA Technical Reports Server (NTRS)

1985-01-01

The concept of a large disturbance bypass mechanism for the initiation of transition is reviewed and studied. This mechanism, or some manifestation thereof, is suspected to be at work in the boundary layers present in a turbine flow passage. Discussion is presented on four relevant subtopics: (1) the effect of upstream disturbances and wakes on transition; (2) transition prediction models, code development, and verification; (3) transition and turbulence measurement techniques; and (4) the hydrodynamic condition of low Reynolds number boundary layers.

Minnowbrook I: 1993 Workshop on End-Stage Boundary Layer Transition

NASA Technical Reports Server (NTRS)

LaGraff, John E. (Editor)

2007-01-01

This volume contains materials presented at the Minnowbrook I-1993 Workshop on End-Stage Boundary Layer Transition, held at the Syracuse University Minnowbrook Conference Center, New York, from August 15 to 18, 1993. This volume was previously published as a Syracuse University report edited by John E. LaGraff. The workshop organizers were John E. LaGraff (Syracuse University), Terry V. Jones (Oxford University), and J. Paul Gostelow (University of Technology, Sydney). The workshop focused on physical understanding of the late stages of transition from laminar to turbulent flows, with the specific goal of contributing to improving engineering design of turbomachinery and wing airfoils. The workshop participants included academic researchers from the United States and abroad, and representatives from the gas-turbine industry and U.S. government laboratories. To improve interaction and discussions among the participants, no formal papers were required. The physical mechanisms discussed were related to natural and bypass transition, wake-induced transition, effects of freestream turbulence, turbulent spots, hairpin vortices, nonlinear instabilities and breakdown, instability wave interactions, intermittency, turbulence, numerical simulation and modeling of transition, heat transfer in boundary-layer transition, transition in separated flows, laminarization, transition in turbomachinery compressors and turbines, hypersonic boundary-layer transition, and other related topics. This volume contains abstracts and copies of the viewgraphs presented, organized according to the workshop sessions. The workshop summary and the plenary discussion transcript clearly outline future research needs.

Bypass transition and spot nucleation in boundary layers

NASA Astrophysics Data System (ADS)

Kreilos, Tobias; Khapko, Taras; Schlatter, Philipp; Duguet, Yohann; Henningson, Dan S.; Eckhardt, Bruno

2016-08-01

The spatiotemporal aspects of the transition to turbulence are considered in the case of a boundary-layer flow developing above a flat plate exposed to free-stream turbulence. Combining results on the receptivity to free-stream turbulence with the nonlinear concept of a transition threshold, a physically motivated model suggests a spatial distribution of spot nucleation events. To describe the evolution of turbulent spots a probabilistic cellular automaton is introduced, with all parameters directly obtained from numerical simulations of the boundary layer. The nucleation rates are then combined with the cellular automaton model, yielding excellent quantitative agreement with the statistical characteristics for different free-stream turbulence levels. We thus show how the recent theoretical progress on transitional wall-bounded flows can be extended to the much wider class of spatially developing boundary-layer flows.

Boundary-Layer Bypass Transition Over Large-Scale Bodies

DTIC Science & Technology

2016-12-16

shape of the streamwise velocity profile compared to the flat- plate boundary layer. The research showed that the streamwise wavenumber plays a key role...many works on the suppression of the transitional boundary layer. Most of the results in the literature are for the flat- plate boundary layer but the...behaviour of the velocity and pressure changes with the curvature. This work aims to extend the results of the flat- plate boundary layer to a Rankine

Roles of Engineering Correlations in Hypersonic Entry Boundary Layer Transition Prediction

NASA Technical Reports Server (NTRS)

Campbell, Charles H.; King, Rudolph A.; Kergerise, Michael A.; Berry, Scott A.; Horvath, Thomas J.

2010-01-01

Efforts to design and operate hypersonic entry vehicles are constrained by many considerations that involve all aspects of an entry vehicle system. One of the more significant physical phenomenon that affect entry trajectory and thermal protection system design is the occurrence of boundary layer transition from a laminar to turbulent state. During the Space Shuttle Return To Flight activity following the loss of Columbia and her crew of seven, NASA's entry aerothermodynamics community implemented an engineering correlation based framework for the prediction of boundary layer transition on the Orbiter. The methodology for this implementation relies upon the framework of correlation techniques that have been in use for several decades. What makes the Orbiter boundary layer transition correlation implementation unique is that a statistically significant data set was acquired in multiple ground test facilities, flight data exists to assist in establishing a better correlation and the framework was founded upon state of the art chemical nonequilibrium Navier Stokes flow field simulations. The basic tenets that guided the formulation and implementation of the Orbiter Return To Flight boundary layer transition prediction capability will be reviewed as a recommended format for future empirical correlation efforts. The validity of this approach has since been demonstrated by very favorable comparison of recent entry flight testing performed with the Orbiter Discovery, which will be graphically summarized. These flight data can provide a means to validate discrete protuberance engineering correlation approaches as well as high fidelity prediction methods to higher confidence. The results of these Orbiter engineering and flight test activities only serve to reinforce the essential role that engineering correlations currently exercise in the design and operation of entry vehicles. The framework of information-related to the Orbiter empirical boundary layer transition prediction capability will be utilized to establish a fresh perspective on this role, to illustrate how quantitative statistical evaluations of empirical correlations can and should be used to assess accuracy and to discuss what the authors' perceive as a recent heightened interest in the application of high fidelity numerical modeling of boundary layer transition. Concrete results will also be developed related to empirical boundary layer transition onset correlations. This will include assessment of the discrete protuberance boundary layer transition onset data assembled for the Orbiter configuration during post-Columbia Return To Flight. Assessment of these data will conclude that momentum thickness Reynolds number based correlations have superior coefficients and uncertainty in comparison to roughness height based Reynolds numbers, aka Re(sub k) or Re(sub kk). In addition, linear regression results from roughness height Reynolds number based correlations will be evaluated, leading to a hypothesis that non-continuum effects play a role in the processes associated with incipient boundary layer transition on discrete protuberances.

Magnetic and electrical control of engineered materials

DOEpatents

Schuller, Ivan K.; de La Venta Granda, Jose; Wang, Siming; Ramirez, Gabriel; Erekhinskiy, Mikhail; Sharoni, Amos

2016-08-16

Methods, systems, and devices are disclosed for controlling the magnetic and electrical properties of materials. In one aspect, a multi-layer structure includes a first layer comprising a ferromagnetic or ferrimagnetic material, and a second layer positioned within the multi-layer structure such that a first surface of the first layer is in direct physical contact with a second surface of the second layer. The second layer includes a material that undergoes structural phase transitions and metal-insulator transitions upon experiencing a change in temperature. One or both of the first and second layers are structured to allow a structural phase change associated with the second layer cause a change magnetic properties of the first layer.

Statistical crossover characterization of the heterotic localized-extended transition.

PubMed

Ugajin, Ryuichi

2003-07-01

We investigated the spectral statistics of a quantum particle in a superlattice consisting of a disordered layer and a clean layer, possibly accompanied by random magnetic fields. Because a disordered layer has localized states and a clean layer has extended states, our quantum system shows a heterotic phase of an Anderson insulator and a normal metal. As the ratio of the volume of these two layers changes, the spectral statistics change from Poissonian to one of the Gaussian ensembles which characterize quantum chaos. A crossover distribution specified by two parameters is introduced to distinguish the transition from an integrable system to a quantum chaotic system during the heterotic phase from an Anderson transition in which the degree of random potentials is homogenous.

Minnowbrook II 1997 Workshop on Boundary Layer Transition in Turbomachines

NASA Technical Reports Server (NTRS)

LaGraff John E. (Editor); Ashpis, David E. (Editor)

1998-01-01

The volume contains materials presented at the Minnowbrook II - 1997 Workshop on Boundary Layer Transition in Turbomachines, held at Syracuse University Minnowbrook Conference Center, New York, on September 7-10, 1997. The workshop followed the informal format at the 1993 Minnowbrook I workshop, focusing on improving the understanding of late stage (final breakdown) boundary layer transition, with the engineering application of improving design codes for turbomachinery in mind. Among the physical mechanisms discussed were hydrodynamic instabilities, laminar to turbulent transition, bypass transition, turbulent spots, wake interaction with boundary layers, calmed regions, and separation, all in the context of flow in turbomachinery, particularly in compressors and high and low pressure turbines. Results from experiments, DNS, computation, modeling and theoretical analysis were presented. Abstracts and copies of viewgraphs, a specifically commissioned summation paper prepared after the workshop, and a transcript of the extensive working group reports and discussions are included in this volume. They provide recommendations for future research and clearly highlight the need for continued vigorous research in the technologically important area of transition in turbomachines.

Review of Orbiter Flight Boundary Layer Transition Data

NASA Technical Reports Server (NTRS)

Mcginley, Catherine B.; Berry, Scott A.; Kinder, Gerald R.; Barnell, maria; Wang, Kuo C.; Kirk, Benjamin S.

2006-01-01

In support of the Shuttle Return to Flight program, a tool was developed to predict when boundary layer transition would occur on the lower surface of the orbiter during reentry due to the presence of protuberances and cavities in the thermal protection system. This predictive tool was developed based on extensive wind tunnel tests conducted after the loss of the Space Shuttle Columbia. Recognizing that wind tunnels cannot simulate the exact conditions an orbiter encounters as it re-enters the atmosphere, a preliminary attempt was made to use the documented flight related damage and the orbiter transition times, as deduced from flight instrumentation, to calibrate the predictive tool. After flight STS-114, the Boundary Layer Transition Team decided that a more in-depth analysis of the historical flight data was needed to better determine the root causes of the occasional early transition times of some of the past shuttle flights. In this paper we discuss our methodology for the analysis, the various sources of shuttle damage information, the analysis of the flight thermocouple data, and how the results compare to the Boundary Layer Transition prediction tool designed for Return to Flight.

Orbiter Boundary Layer Transition Prediction Tool Enhancements

NASA Technical Reports Server (NTRS)

Berry, Scott A.; King, Rudolph A.; Kegerise, Michael A.; Wood, William A.; McGinley, Catherine B.; Berger, Karen T.; Anderson, Brian P.

2010-01-01

Updates to an analytic tool developed for Shuttle support to predict the onset of boundary layer transition resulting from thermal protection system damage or repair are presented. The boundary layer transition tool is part of a suite of tools that analyze the local aerothermodynamic environment to enable informed disposition of damage for making recommendations to fly as is or to repair. Using mission specific trajectory information and details of each d agmea site or repair, the expected time (and thus Mach number) of transition onset is predicted to help define proper environments for use in subsequent thermal and stress analysis of the thermal protection system and structure. The boundary layer transition criteria utilized within the tool were updated based on new local boundary layer properties obtained from high fidelity computational solutions. Also, new ground-based measurements were obtained to allow for a wider parametric variation with both protuberances and cavities and then the resulting correlations were calibrated against updated flight data. The end result is to provide correlations that allow increased confidence with the resulting transition predictions. Recently, a new approach was adopted to remove conservatism in terms of sustained turbulence along the wing leading edge. Finally, some of the newer flight data are also discussed in terms of how these results reflect back on the updated correlations.

Boundary Layer Transition in the Leading Edge Region of a Swept Cylinder in High Speed Flow

NASA Technical Reports Server (NTRS)

Coleman, Colin P.

1998-01-01

Experiments were conducted on a 76 degree swept cylinder to establish the behavior of the attachment line transition process in a low-disturbance level, Mach number 1.6 flow. For a near adiabatic wall condition, the attachment-line boundary layer remained laminar up to the highest attainable Reynolds number. The attachment-line boundary layer transition under the influence of trip wires depended on wind tunnel disturbance level, and a transition onset condition for this flow is established. Internal heating raised the surface temperature of the attachment line to induce boundary layer instabilities. This was demonstrated experimentally for the first time and the frequencies of the most amplified disturbances were determined over a range of temperature settings. Results were in excellent agreement to those predicted by a linear stability code, and provide the first experimental verification of theory. Transition onset along the heated attachment line at an R-bar of 800 under quiet tunnel conditions was found to correlate with an N factor of 13.2. Increased tunnel disturbance levels caused the transition onset to occur at lower cylinder surface temperatures and was found to correlate with an approximate N factor of 1 1.9, so demonstrating that the attachment-line boundary layer is receptive to increases in the tunnel disturbance level.

Simulations of laminar boundary-layer flow encountering large-scale surface indentions

NASA Astrophysics Data System (ADS)

Beratlis, N.; Balaras, E.; Squires, K.; Vizard, A.

2016-03-01

The transition from laminar to turbulent flow over dimples and grooves has been investigated through a series of direct numerical simulations. Emphasis has been given to the mechanism of transition and the momentum transport in the post-dimple boundary layer. It has been found that the dimple geometry plays an important role in the evolution of the turbulent boundary layer downstream. The mechanism of transition in all cases is that of the reorientation of the spanwise vorticity into streamwise oriented structures resembling hairpin vortices commonly encountered in wall bounded turbulent flows. Although qualitatively the transition mechanism amongst the three different cases is similar, important quantitative differences exist. It was shown that two-dimensional geometries like a groove are more stable than three-dimensional geometries like a dimple. In addition, it was found that the cavity geometry controls the initial thickness of the boundary layer and practically results in a shift of the virtual origin of the turbulent boundary layer. Important differences in the momentum transport downstream of the dimples exist but in all cases the boundary layer grows in a self-similar manner.

Calibration of a γ- Re θ transition model and its application in low-speed flows

NASA Astrophysics Data System (ADS)

Wang, YunTao; Zhang, YuLun; Meng, DeHong; Wang, GunXue; Li, Song

2014-12-01

The prediction of laminar-turbulent transition in boundary layer is very important for obtaining accurate aerodynamic characteristics with computational fluid dynamic (CFD) tools, because laminar-turbulent transition is directly related to complex flow phenomena in boundary layer and separated flow in space. Unfortunately, the transition effect isn't included in today's major CFD tools because of non-local calculations in transition modeling. In this paper, Menter's γ- Re θ transition model is calibrated and incorporated into a Reynolds-Averaged Navier-Stokes (RANS) code — Trisonic Platform (TRIP) developed in China Aerodynamic Research and Development Center (CARDC). Based on the experimental data of flat plate from the literature, the empirical correlations involved in the transition model are modified and calibrated numerically. Numerical simulation for low-speed flow of Trapezoidal Wing (Trap Wing) is performed and compared with the corresponding experimental data. It is indicated that the γ- Re θ transition model can accurately predict the location of separation-induced transition and natural transition in the flow region with moderate pressure gradient. The transition model effectively imporves the simulation accuracy of the boundary layer and aerodynamic characteristics.

Control of electronic properties of 2D carbides (MXenes) by manipulating their transition metal layers

DOE PAGES

Anasori, Babak; Shi, Chenyang; Moon, Eun Ju; ...

2016-02-24

In this paper, a transition from metallic to semiconducting-like behavior has been demonstrated in two-dimensional (2D) transition metal carbides by replacing titanium with molybdenum in the outer transition metal (M) layers of M 3C 2 and M 4C 3 MXenes. The MXene structure consists of n + 1 layers of near-close packed M layers with C or N occupying the octahedral site between them in an [MX] nM arrangement. Recently, two new families of ordered 2D double transition metal carbides MXenes were discovered, M' 2M"C 2 and M' 2M" 2C 3 – where M' and M" are two different earlymore » transition metals, such as Mo, Cr, Ta, Nb, V, and Ti. The M' atoms only occupy the outer layers and the M" atoms fill the middle layers. In other words, M' atomic layers sandwich the middle M"–C layers. Using X-ray atomic pair distribution function (PDF) analysis on Mo 2TiC 2 and Mo 2Ti 2C 3 MXenes, we present the first quantitative analysis of structures of these novel materials and experimentally confirm that Mo atoms are in the outer layers of the [MC] nM structures. The electronic properties of these Mo-containing MXenes are compared with their Ti 3C 2 counterparts, and are found to be no longer metallic-like conductors; instead the resistance increases mildly with decreasing temperatures. Density functional theory (DFT) calculations suggest that OH terminated Mo–Ti MXenes are semiconductors with narrow band gaps. Measurements of the temperature dependencies of conductivities and magnetoresistances have confirmed that Mo 2TiC 2T x exhibits semiconductor-like transport behavior, while Ti 3C 2T x is a metal. Finally, this finding opens new avenues for the control of the electronic and optical applications of MXenes and for exploring new applications, in which semiconducting properties are required.« less

USArray Receiver Function Imaging of Multiple-Layer Crustal Structure of the Contiguous United States

NASA Astrophysics Data System (ADS)

Ma, X.; Lowry, A. R.; Ravat, D.

2014-12-01

Thickness andseismic velocity of crustal layers are useful for understanding the history and evolution of continental lithosphere. Lowry and Pérez-Gussinyé (2011) observed that low bulk crustal seismic velocity ratio, Vp/Vs, strongly correlates with high geothermal gradient and active deformation, indicating quartz (to which Vp/Vs is most sensitive) plays a role in these processes. The lower crust (where ductile flow occurs which might explain the relationship) is commonly thought to be quartz-poor. However, layering of the crust may represent changes in either lithology or the phase of quartz. Laboratory strain-stress experiments on quartz indicate that near the a- to b-quartz phase transition, both Vp and Vp/Vs initially drop dramatically but then increase relative to the a-quartz regime because Young's modulus initially decreases by 30% before increasing by a net ~20%. Shear modulus varies only ~3% across the transition. Crustal structure is commonly represented by an upper, mid- and lower layer (e.g., Crust1.0) and conceptualized as primarily reflecting a change to more mafic lithology at greater depth, but estimates of Moho temperature indicate a quartz phase transition should be present in much of the western and central U.S. We have imaged multiple layering of the contiguous U.S. by applying a new cross-correlation and stacking method to USArray receiver functions. Synthetic models of a multiple layer crust indicate 'splitting' of converted-phase arrivals would be expected if a quartz phase transition were responsible. Preliminary imaging using cross-correlation of observed receiver functions with multiple layer synthetics demonstrates a marked improvement in correlation coefficients relative to a single-layer crust. In this presentation we will examine observational evidence for possible a- to b- phase transition layering (indicating quartz at depth) and compare with depths predicted for the quartz phase transition based on Pn-derived Moho temperatures and estimates of magnetic Curie depths.

Crystal structure and magnetism of layered perovskites compound EuBaCuFeO5

NASA Astrophysics Data System (ADS)

Lal, Surender; Mukherjee, K.; Yadav, C. S.

2018-04-01

Layered perovskite compounds have interesting multiferroic properties.YBaCuFeO5 is one of the layered perovskite compounds which have magnetic and dielectric transition above 200 K. The multiferroic properties can be tuned with the replacement of Y with some other rare earth ions. In this manuscript, structural and magnetic properties of layered perovskite compound EuBaCuFeO5 have been investigated. This compound crystallizes in the tetragonal structure with P4mm space group and is iso-structural with YBaCuFeO5. The magnetic transition has been found to shift to 120 K as compared to YBaCuFeO5 which has the transition at 200 K. This shift in the magnetic transition has been ascribed to the decrease in the chemical pressure that relaxes the magnetic moments.

Ferroelectric control of metal-insulator transition

NASA Astrophysics Data System (ADS)

He, Xu; Jin, Kui-juan; Ge, Chen; Ma, Zhong-shui; Yang, Guo-zhen

2016-03-01

We propose a method of controlling the metal-insulator transition of one perovskite material at its interface with another ferroelectric material based on first principle calculations. The operating principle is that the rotation of oxygen octahedra tuned by the ferroelectric polarization can modulate the superexchange interaction in this perovskite. We designed a tri-color superlattice of (BiFeO3)N/LaNiO3/LaTiO3, in which the BiFeO3 layers are ferroelectric, the LaNiO3 layer is the layer of which the electronic structure is to be tuned, and LaTiO3 layer is inserted to enhance the inversion asymmetry. By reversing the ferroelectric polarization in this structure, there is a metal-insulator transition of the LaNiO3 layer because of the changes of crystal field splitting of the Ni eg orbitals and the bandwidth of the Ni in-plane eg orbital. It is highly expected that a metal-transition can be realized by designing the structures at the interfaces for more materials.

Measurements in Transitional Boundary Layers Under High Free-Stream Turbulence and Strong Acceleration Conditions

NASA Technical Reports Server (NTRS)

Volino, Ralph J.; Simon, Terrence W.

1995-01-01

Measurements from transitional, heated boundary layers along a concave-curved test wall are presented and discussed. A boundary layer subject to low free-stream turbulence intensity (FSTI), which contains stationary streamwise (Gortler) vortices, is documented. The low FSTI measurements are followed by measurements in boundary layers subject to high (initially 8%) free-stream turbulence intensity and moderate to strong streamwise acceleration. Conditions were chosen to simulate those present on the downstream half of the pressure side of a gas turbine airfoil. Mean flow characteristics as well as turbulence statistics, including the turbulent shear stress, turbulent heat flux, and turbulent Prandtl number, are documented. A technique called "octant analysis" is introduced and applied to several cases from the literature as well as to data from the present study. Spectral analysis was applied to describe the effects of turbulence scales of different sizes during transition. To the authors'knowledge, this is the first detailed documentation of boundary layer transition under such high free-stream turbulence conditions.

Pressure induced metallization with absence of structural transition in layered molybdenum diselenide

PubMed Central

Zhao, Zhao; Zhang, Haijun; Yuan, Hongtao; Wang, Shibing; Lin, Yu; Zeng, Qiaoshi; Xu, Gang; Liu, Zhenxian; Solanki, G. K.; Patel, K. D.; Cui, Yi; Hwang, Harold Y.; Mao, Wendy L.

2015-01-01

Layered transition-metal dichalcogenides have emerged as exciting material systems with atomically thin geometries and unique electronic properties. Pressure is a powerful tool for continuously tuning their crystal and electronic structures away from the pristine states. Here, we systematically investigated the pressurized behavior of MoSe2 up to ∼60 GPa using multiple experimental techniques and ab-initio calculations. MoSe2 evolves from an anisotropic two-dimensional layered network to a three-dimensional structure without a structural transition, which is a complete contrast to MoS2. The role of the chalcogenide anions in stabilizing different layered patterns is underscored by our layer sliding calculations. MoSe2 possesses highly tunable transport properties under pressure, determined by the gradual narrowing of its band-gap followed by metallization. The continuous tuning of its electronic structure and band-gap in the range of visible light to infrared suggest possible energy-variable optoelectronics applications in pressurized transition-metal dichalcogenides. PMID:26088416

Pressure induced metallization with absence of structural transition in layered molybdenum diselenide

DOE PAGES

Zhao, Zhao; Zhang, Haijun; Yuan, Hongtao; ...

2015-06-19

Layered transition-metal dichalcogenides have emerged as exciting material systems with atomically thin geometries and unique electronic properties. Pressure is a powerful tool for continuously tuning their crystal and electronic structures away from the pristine states. Here, we systematically investigated the pressurized behavior of MoSe 2 up to ~60 GPa using multiple experimental techniques and ab-initio calculations. MoSe 2 evolves from an anisotropic two-dimensional layered network to a three-dimensional structure without a structural transition, which is a complete contrast to MoS 2. The role of the chalcogenide anions in stabilizing different layered patterns is underscored by our layer sliding calculations. MoSemore » 2 possesses highly tunable transport properties under pressure, determined by the gradual narrowing of its band-gap followed by metallization. The continuous tuning of its electronic structure and band-gap in the range of visible light to infrared suggest possible energy-variable optoelectronics applications in pressurized transition-metal dichalcogenides.« less

On the Effects of Surface Roughness on Boundary Layer Transition

NASA Technical Reports Server (NTRS)

Choudhari, Meelan M.; Li, Fei; Chang, Chau-Lyan; Edwards, Jack

2009-01-01

Surface roughness can influence laminar-turbulent transition in many different ways. This paper outlines selected analyses performed at the NASA Langley Research Center, ranging in speed from subsonic to hypersonic Mach numbers and highlighting the beneficial as well as adverse roles of the surface roughness in technological applications. The first theme pertains to boundary-layer tripping on the forebody of a hypersonic airbreathing configuration via a spanwise periodic array of trip elements, with the goal of understanding the physical mechanisms underlying roughness-induced transition in a high-speed boundary layer. The effect of an isolated, finite amplitude roughness element on a supersonic boundary layer is considered next. The other set of flow configurations examined herein corresponds to roughness based laminar flow control in subsonic and supersonic swept wing boundary layers. A common theme to all of the above configurations is the need to apply higher fidelity, physics based techniques to develop reliable predictions of roughness effects on laminar-turbulent transition.

Correlation-based Transition Modeling for External Aerodynamic Flows

NASA Astrophysics Data System (ADS)

Medida, Shivaji

Conventional turbulence models calibrated for fully turbulent boundary layers often over-predict drag and heat transfer on aerodynamic surfaces with partially laminar boundary layers. A robust correlation-based model is developed for use in Reynolds-Averaged Navier-Stokes simulations to predict laminar-to-turbulent transition onset of boundary layers on external aerodynamic surfaces. The new model is derived from an existing transition model for the two-equation k-omega Shear Stress Transport (SST) turbulence model, and is coupled with the one-equation Spalart-Allmaras (SA) turbulence model. The transition model solves two transport equations for intermittency and transition momentum thickness Reynolds number. Experimental correlations and local mean flow quantities are used in the model to account for effects of freestream turbulence level and pressure gradients on transition onset location. Transition onset is triggered by activating intermittency production using a vorticity Reynolds number criterion. In the new model, production and destruction terms of the intermittency equation are modified to improve consistency in the fully turbulent boundary layer post-transition onset, as well as ensure insensitivity to freestream eddy viscosity value specified in the SA model. In the original model, intermittency was used to control production and destruction of turbulent kinetic energy. Whereas, in the new model, only the production of eddy viscosity in SA model is controlled, and the destruction term is not altered. Unlike the original model, the new model does not use an additional correction to intermittency for separation-induced transition. Accuracy of drag predictions are improved significantly with the use of the transition model for several two-dimensional single- and multi-element airfoil cases over a wide range of Reynolds numbers. The new model is able to predict the formation of stable and long laminar separation bubbles on low-Reynolds number airfoils that is not captured with conventional turbulence models. The validated transition model is successfully applied to rotating blade configurations in axial flow conditions to study the effects of transitional boundary layers on rotor thrust and torque. In helicopter rotors, inclusion of transition effects increased thrust prediction by 2% and decreased torque by as much as 8% at lower collective angles, due to reduced airfoil profile drag. In wind turbine rotors, transition model predicted a 7%--70% increase in generated shaft torque at lower wind speeds, due to lower viscous drag. This has important implications for CFD analysis of small wind turbines operating at low values of rated power. Transition onset locations along upper and lower surfaces of rotor blades are analyzed in detail. A new crossflow transition onset criterion is developed to account for crossflow instability effects in three-dimensional boundary layers. Preliminary results for swept wing and rotating blade flows demonstrate the need to account for crossflow transition in three-dimensional simulations of wings, rotating blades, and airframes. Inclusion of crossflow effects resulted in accelerated transition in the presence of favorable pressure gradients and yawed flow. Finally, a new correction to the wall damping function in the Spalart-Allmaras turbulence model is proposed to improve sensitivity of the model to strong adverse pressure gradients (APG). The correction reduces turbulence production in the boundary layer when the ratio of magnitudes of local turbulent stress to the wall shear stress exceeds a threshold value, therefore enabling earlier separation of boundary layer. Improved prediction of static and dynamic stall on two-dimensional airfoils is demonstrated with the APG correction.

Modeling of near wall turbulence and modeling of bypass transition

NASA Technical Reports Server (NTRS)

Yang, Z.

1992-01-01

The objectives for this project are as follows: (1) Modeling of the near wall turbulence: We aim to develop a second order closure for the near wall turbulence. As a first step of this project, we try to develop a kappa-epsilon model for near wall turbulence. We require the resulting model to be able to handle both near wall turbulence and turbulent flows away from the wall, computationally robust, and applicable for complex flow situations, flow with separation, for example, and (2) Modeling of the bypass transition: We aim to develop a bypass transition model which contains the effect of intermittency. Thus, the model can be used for both the transitional boundary layers and the turbulent boundary layers. We require the resulting model to give a good prediction of momentum and heat transfer within the transitional boundary and a good prediction of the effect of freestream turbulence on transitional boundary layers.

Transitional-turbulent spots and turbulent-turbulent spots in boundary layers

NASA Astrophysics Data System (ADS)

Wu, Xiaohua; Moin, Parviz; Wallace, James M.; Skarda, Jinhie; Lozano-Durán, Adrián; Hickey, Jean-Pierre

2017-07-01

Two observations drawn from a thoroughly validated direct numerical simulation of the canonical spatially developing, zero-pressure gradient, smooth, flat-plate boundary layer are presented here. The first is that, for bypass transition in the narrow sense defined herein, we found that the transitional-turbulent spot inception mechanism is analogous to the secondary instability of boundary-layer natural transition, namely a spanwise vortex filament becomes a ΛΛ vortex and then, a hairpin packet. Long streak meandering does occur but usually when a streak is infected by a nearby existing transitional-turbulent spot. Streak waviness and breakdown are, therefore, not the mechanisms for the inception of transitional-turbulent spots found here. Rather, they only facilitate the growth and spreading of existing transitional-turbulent spots. The second observation is the discovery, in the inner layer of the developed turbulent boundary layer, of what we call turbulent-turbulent spots. These turbulent-turbulent spots are dense concentrations of small-scale vortices with high swirling strength originating from hairpin packets. Although structurally quite similar to the transitional-turbulent spots, these turbulent-turbulent spots are generated locally in the fully turbulent environment, and they are persistent with a systematic variation of detection threshold level. They exert indentation, segmentation, and termination on the viscous sublayer streaks, and they coincide with local concentrations of high levels of Reynolds shear stress, enstrophy, and temperature fluctuations. The sublayer streaks seem to be passive and are often simply the rims of the indentation pockets arising from the turbulent-turbulent spots.

Mars Science Laboratory Heatshield Aerothermodynamics: Design and Reconstruction

NASA Technical Reports Server (NTRS)

Edquist, Karl T.; Hollis, Brian R.; Johnston, Christopher O.; Bose, Deepak; White, Todd R.; Mahzari, Milad

2013-01-01

The Mars Science Laboratory heatshield was designed to withstand a fully turbulent heat pulse based on test results and computational analysis on a pre-flight design trajectory. Instrumentation on the flight heatshield measured in-depth temperatures in the thermal protection system. The data indicate that boundary layer transition occurred at 5 of 7 thermocouple locations prior to peak heating. Data oscillations at 3 pressure measurement locations may also indicate transition. This paper presents the heatshield temperature and pressure data, possible explanations for the timing of boundary layer transition, and a qualitative comparison of reconstructed and computational heating on the as-flown trajectory. Boundary layer Reynolds numbers that are typically used to predict transition are compared to observed transition at various heatshield locations. A uniform smooth-wall transition Reynolds number does not explain the timing of boundary layer transition observed during flight. A roughness-based Reynolds number supports the possibility of transition due to discrete or distributed roughness elements on the heatshield. However, the distributed roughness height would have needed to be larger than the pre-flight assumption. The instrumentation confirmed the predicted location of maximum turbulent heat flux near the leeside shoulder. The reconstructed heat flux at that location is bounded by smooth-wall turbulent calculations on the reconstructed trajectory, indicating that augmentation due to surface roughness probably did not occur. Turbulent heating on the downstream side of the heatshield nose exceeded smooth-wall computations, indicating that roughness may have augmented heating. The stagnation region also experienced heating that exceeded computational levels, but shock layer radiation does not fully explain the differences.

Fabric transition with dislocation creep of a carbonate fault zone in the brittle regime

NASA Astrophysics Data System (ADS)

Kim, Sungshil; Ree, Jin-Han; Han, Raehee; Kim, Nahyeon; Jung, Haemyeong

2018-01-01

Fabric transition by a switch in the dominant slip system of minerals in the plastic regime can be induced by changes in temperature, strain rate, or water content. We propose here this fabric transition by frictional heating in seismogenic fault zones in the brittle regime. The Garam Thrust in the Taebaeksan Basin of South Korea has a hanging wall of Cambrian dolostone juxtaposed against a footwall of Ordovician limestone and records a minimum displacement of 120 m. In a 10 cm thick plastically deformed layer adjacent to the principal slip layer of the fault zone, the lattice preferred orientation of calcite grains suggests that the dominant slip system changes, approaching the principal slip layer, from r 〈02-21〉 and e-twinning, through r 〈02-21〉 and basal 〈a〉, to basal 〈a〉. This fabric transition requires a high temperature-gradient of 40 °C/cm, which we infer to result from frictional heating of the seismic fault zone. We suggest that fabric transition within a thin plastically deformed layer adjacent to the principal slip layer of a fault zone indicates an unusually steep temperature gradient and provides strong evidence of seismic slip.

High-Order Finite-Difference Schemes for Numerical Simulation of Hypersonic Boundary-Layer Transition

NASA Astrophysics Data System (ADS)

Zhong, Xiaolin

1998-08-01

Direct numerical simulation (DNS) has become a powerful tool in studying fundamental phenomena of laminar-turbulent transition of high-speed boundary layers. Previous DNS studies of supersonic and hypersonic boundary layer transition have been limited to perfect-gas flow over flat-plate boundary layers without shock waves. For hypersonic boundary layers over realistic blunt bodies, DNS studies of transition need to consider the effects of bow shocks, entropy layers, surface curvature, and finite-rate chemistry. It is necessary that numerical methods for such studies are robust and high-order accurate both in resolving wide ranges of flow time and length scales and in resolving the interaction between the bow shocks and flow disturbance waves. This paper presents a new high-order shock-fitting finite-difference method for the DNS of the stability and transition of hypersonic boundary layers over blunt bodies with strong bow shocks and with (or without) thermo-chemical nonequilibrium. The proposed method includes a set of new upwind high-order finite-difference schemes which are stable and are less dissipative than a straightforward upwind scheme using an upwind-bias grid stencil, a high-order shock-fitting formulation, and third-order semi-implicit Runge-Kutta schemes for temporal discretization of stiff reacting flow equations. The accuracy and stability of the new schemes are validated by numerical experiments of the linear wave equation and nonlinear Navier-Stokes equations. The algorithm is then applied to the DNS of the receptivity of hypersonic boundary layers over a parabolic leading edge to freestream acoustic disturbances.

Control of valence and conduction band energies in layered transition metal phosphates via surface functionalization

DOE Office of Scientific and Technical Information (OSTI.GOV)

Lentz, Levi C.; Kolb, Brian; Kolpak, Alexie M.

Layered transition metal phosphates and phosphites (TMPs) are a class of 2D materials bound togetherviavan der Waals interactions. Through simple functionalization, band energies can be systematically controlled.

Linear stability theory and three-dimensional boundary layer transition

NASA Technical Reports Server (NTRS)

Spall, Robert E.; Malik, Mujeeb R.

1992-01-01

The viewgraphs and discussion of linear stability theory and three dimensional boundary layer transition are provided. The ability to predict, using analytical tools, the location of boundary layer transition over aircraft-type configurations is of great importance to designers interested in laminar flow control (LFC). The e(sup N) method has proven to be fairly effective in predicting, in a consistent manner, the location of the onset of transition for simple geometries in low disturbance environments. This method provides a correlation between the most amplified single normal mode and the experimental location of the onset of transition. Studies indicate that values of N between 8 and 10 correlate well with the onset of transition. For most previous calculations, the mean flows were restricted to two-dimensional or axisymmetric cases, or have employed simple three-dimensional mean flows (e.g., rotating disk, infinite swept wing, or tapered swept wing with straight isobars). Unfortunately, for flows over general wing configurations, and for nearly all flows over fuselage-type bodies at incidence, the analysis of fully three-dimensional flow fields is required. Results obtained for the linear stability of fully three-dimensional boundary layers formed over both wing and fuselage-type geometries, and for both high and low speed flows are discussed. When possible, transition estimates form the e(sup N) method are compared to experimentally determined locations. The stability calculations are made using a modified version of the linear stability code COSAL. Mean flows were computed using both Navier Stokes and boundary-layer codes.

Instability waves and transition in adverse-pressure-gradient boundary layers

NASA Astrophysics Data System (ADS)

Bose, Rikhi; Zaki, Tamer A.; Durbin, Paul A.

2018-05-01

Transition to turbulence in incompressible adverse-pressure-gradient (APG) boundary layers is investigated by direct numerical simulations. Purely two-dimensional instability waves develop on the inflectional base velocity profile. When the boundary layer is perturbed by isotropic turbulence from the free stream, streamwise elongated streaks form and may interact with the instability waves. Subsequent mechanisms that trigger transition depend on the intensity of the free-stream disturbances. All evidence from the present simulations suggest that the growth rate of instability waves is sufficiently high to couple with the streaks. Under very low levels of free-stream turbulence (˜0.1 % ), transition onset is highly sensitive to the inlet disturbance spectrum and is accelerated if the spectrum contains frequency-wave-number combinations that are commensurate with the instability waves. Transition onset and completion in this regime is characterized by formation and breakdown of Λ vortices, but they are more sporadic than in natural transition. Beneath free-stream turbulence with higher intensity (1-2 % ), bypass transition mechanisms are dominant, but instability waves are still the most dominant disturbances in wall-normal and spanwise perturbation spectra. Most of the breakdowns were by disturbances with critical layers close to the wall, corresponding to inner modes. On the other hand, the propensity of an outer mode to occur increases with the free-stream turbulence level. Higher intensity free-stream disturbances induce strong streaks that favorably distort the boundary layer and suppress the growth of instability waves. But the upward displacement of high amplitude streaks brings them to the outer edge of the boundary layer and exposes them to ambient turbulence. Consequently, high-amplitude streaks exhibit an outer-mode secondary instability.

Modelling the transitional boundary layer

NASA Technical Reports Server (NTRS)

Narasimha, R.

1990-01-01

Recent developments in the modelling of the transition zone in the boundary layer are reviewed (the zone being defined as extending from the station where intermittency begins to depart from zero to that where it is nearly unity). The value of using a new non-dimensional spot formation rate parameter, and the importance of allowing for so-called subtransitions within the transition zone, are both stressed. Models do reasonably well in constant pressure 2-dimensional flows, but in the presence of strong pressure gradients further improvements are needed. The linear combination approach works surprisingly well in most cases, but would not be so successful in situations where a purely laminar boundary layer would separate but a transitional one would not. Intermittency-weighted eddy viscosity methods do not predict peak surface parameters well without the introduction of an overshooting transition function whose connection with the spot theory of transition is obscure. Suggestions are made for further work that now appears necessary for developing improved models of the transition zone.

Experimental Investigation of Separated and Transitional Boundary Layers Under Low-Pressure Turbine Airfoil Conditions

NASA Technical Reports Server (NTRS)

Hultgren, Lennart S.; Volino, Ralph J.

2002-01-01

Modern low-pressure turbine airfoils are subject to increasingly stronger pressure gradients as designers impose higher loading in an effort to improve efficiency and to reduce part count. The adverse pressure gradients on the suction side of these airfoils can lead to boundary-layer separation, particularly under cruise conditions. Separation bubbles, notably those which fail to reattach, can result in a significant degradation of engine efficiency. Accurate prediction of separation and reattachment is hence crucial to improved turbine design. This requires an improved understanding of the transition flow physics. Transition may begin before or after separation, depending on the Reynolds number and other flow conditions, has a strong influence on subsequent reattachment, and may even eliminate separation. Further complicating the problem are the high free-stream turbulence levels in a real engine environment, the strong pressure gradients along the airfoils, the curvature of the airfoils, and the unsteadiness associated with wake passing from upstream stages. Because of the complicated flow situation, transition in these devices can take many paths that can coexist, vary in importance, and possibly also interact, at different locations and instances in time. The present work was carried out in an attempt to systematically sort out some of these issues. Detailed velocity measurements were made along a flat plate subject to the same nominal dimensionless pressure gradient as the suction side of a modern low-pressure turbine airfoil ('Pak-B'). The Reynolds number based on wetted plate length and nominal exit velocity, Re, was varied from 50;000 to 300; 000, covering cruise to takeoff conditions. Low, 0.2%, and high, 7%, inlet free-stream turbulence intensities were set using passive grids. These turbulence levels correspond to about 0.2% and 2.5% turbulence intensity in the test section when normalized with the exit velocity. The Reynolds number and free-stream turbulence level do not have a significant effect on the location of boundary-layer separation unless they are high enough to induce transition upstream of separation. The location and extent of the transition zone, in contrast, depend strongly on Re and TI. The beginning of reattachment closely follows the onset of transition. Under low free-stream turbulence conditions the boundary layer is laminar at separation and then begins to exhibit fluctuations in a finite frequency band in the shear layer over the separation bubble. These fluctuations are due to instability waves. The fluctuations grow in magnitude, higher harmonics are generated, and finally lead to a breakdown to turbulence. Transition begins in the shear layer, but quickly spreads to the near wall region and causes the boundary layer to reattach. The transition is rapid and the resulting turbulence contains a full range of high and low frequencies. Under high free-stream turbulence conditions, slowly growing low-frequency fluctuations are induced in the pretransitional boundary layer by the free-stream. The separation bubbles are considerably thinner than in the low TI cases, resulting in thinner boundary layers at the end of the test wall. At Re=50,000 and 100,000, the pre-transitional boundary layer separates at about the same location as in the low TI cases. Transition occurs through a bypass mode, begins upstream of the corresponding low-TI location, and proceeds in a manner similar to that of an attached boundary layer. Under high TI at Re=200,000 and 300,000, transition begins before separation. The boundary layer may separate, but if it does the separation bubble is very short and does not significantly affect the downstream development of the boundary layer. A comparison is made to previous work in a simulated cascade.

Fluid transition layer between rigid solute and liquid solvent: is there depletion or enrichment?

PubMed

Djikaev, Yuri S; Ruckenstein, Eli

2016-03-21

The fluid layer between solute and liquid solvent is studied by combining the density functional theory with the probabilistic hydrogen bond model. This combination allows one to obtain the equilibrium distribution of fluid molecules, taking into account the hydrogen bond contribution to the external potential whereto they are subjected near the solute. One can find the effective width of the fluid solvent-solute transition layer and fluid average density in that layer, and determine their dependence on temperature, solvent-solute affinity, vicinal hydrogen bond (hb) energy alteration ratio, and solute radius. Numerical calculations are performed for the solvation of a plate and spherical solutes of four different radii in two model solvents (associated liquid and non-associated one) in the temperature range from 293 K to 333 K for various solvent-solute affinities and hydrogen bond energy alteration ratios. The predictions of our model for the effective width and average density of the transition layer are consistent with experiments and simulations. The small-to-large crossover lengthscale for hydrophobic hydration is expected to be about 3-5 nm. Remarkably, characterizing the transition layer with the average density, one can observe that for small hydrophobes, the transition layer becomes enriched with rather than depleted of fluid when the solvent-solute affinity and hb-energy alteration ratio become large enough. The boundary values of solvent-solute affinity and hb-energy alteration ratio, needed for the "depletion-to-enrichment" crossover (in the smoothed density sense), are predicted to decrease with increasing temperature.

Early Warning Signals for Regime Transition in the Stable Boundary Layer: A Model Study

NASA Astrophysics Data System (ADS)

van Hooijdonk, I. G. S.; Moene, A. F.; Scheffer, M.; Clercx, H. J. H.; van de Wiel, B. J. H.

2017-02-01

The evening transition is investigated in an idealized model for the nocturnal boundary layer. From earlier studies it is known that the nocturnal boundary layer may manifest itself in two distinct regimes, depending on the ambient synoptic conditions: strong-wind or overcast conditions typically lead to weakly stable, turbulent nights; clear-sky and weak-wind conditions, on the other hand, lead to very stable, weakly turbulent conditions. Previously, the dynamical behaviour near the transition between these regimes was investigated in an idealized setting, relying on Monin-Obukhov (MO) similarity to describe turbulent transport. Here, we investigate a similar set-up, using direct numerical simulation; in contrast to MO-based models, this type of simulation does not need to rely on turbulence closure assumptions. We show that previous predictions are verified, but now independent of turbulence parametrizations. Also, it appears that a regime shift to the very stable state is signaled in advance by specific changes in the dynamics of the turbulent boundary layer. Here, we show how these changes may be used to infer a quantitative estimate of the transition point from the weakly stable boundary layer to the very stable boundary layer. In addition, it is shown that the idealized, nocturnal boundary-layer system shares important similarities with generic non-linear dynamical systems that exhibit critical transitions. Therefore, the presence of other, generic early warning signals is tested as well. Indeed, indications are found that such signals are present in stably stratified turbulent flows.

Functionally gradient material for membrane reactors to convert methane gas into value-added products

DOEpatents

Balachandran, U.; Dusek, J.T.; Kleefisch, M.S.; Kobylinski, T.P.

1996-11-12

A functionally gradient material for a membrane reactor for converting methane gas into value-added-products includes an outer tube of perovskite, which contacts air; an inner tube which contacts methane gas, of zirconium oxide, and a bonding layer between the perovskite and zirconium oxide layers. The bonding layer has one or more layers of a mixture of perovskite and zirconium oxide, with the layers transitioning from an excess of perovskite to an excess of zirconium oxide. The transition layers match thermal expansion coefficients and other physical properties between the two different materials. 7 figs.

Functionally gradient material for membrane reactors to convert methane gas into value-added products

DOEpatents

Balachandran, Uthamalingam; Dusek, Joseph T.; Kleefisch, Mark S.; Kobylinski, Thadeus P.

1996-01-01

A functionally gradient material for a membrane reactor for converting methane gas into value-added-products includes an outer tube of perovskite, which contacts air; an inner tube which contacts methane gas, of zirconium oxide, and a bonding layer between the perovskite and zirconium oxide layers. The bonding layer has one or more layers of a mixture of perovskite and zirconium oxide, with the layers transitioning from an excess of perovskite to an excess of zirconium oxide. The transition layers match thermal expansion coefficients and other physical properties between the two different materials.

Free-stream disturbance, continuous Eigenfunctions, boundary-layer instability and transition

NASA Technical Reports Server (NTRS)

Grosch, C. E.

1980-01-01

A rational foundation is presented for the application of the linear shear flows to transition prediction, and an explicit method is given for carrying out the necessary calculations. The expansions used are shown to be complete. Sample calculations show that a typical boundary layer is very sensitive to vorticity disturbances in the inner boundary layer, near the critical layer. Vorticity disturbances three or four boundary layer thicknesses above the boundary are nearly uncoupled from the boundary layer in that the amplitudes of the discrete Tollmien-Schlicting waves are an extremely small fraction of the amplitude of the disturbance.

Coherently coupled ZnO and VO2 interface studied by photoluminescence and electrical transport across a phase transition

NASA Astrophysics Data System (ADS)

Srivastava, Amar; Herng, T. S.; Saha, Surajit; Nina, Bao; Annadi, A.; Naomi, N.; Liu, Z. Q.; Dhar, S.; Ariando; Ding, J.; Venkatesan, T.

2012-06-01

We have investigated the photoluminescence and electrical properties of a coherently coupled interface consisting of a ZnO layer grown on top of an oriented VO2 layer on sapphire across the phase transition of VO2. The band edge and defect luminescence of the ZnO overlayer exhibit hysteresis in opposite directions induced by the phase transition of VO2. Concomitantly the phase transition of VO2 was seen to induce defects in the ZnO layer. Such coherently coupled interfaces could be of use in characterizing the stability of a variety of interfaces in situ and also for novel device application.

Characteristics of Boundary Layer Transition in a Multi-Stage Low-Pressure Turbine

NASA Technical Reports Server (NTRS)

Wisler, Dave; Halstead, David E.; Okiishi, Ted

2007-01-01

An experimental investigation of boundary layer transition in a multi-stage turbine has been completed using surface-mounted hot-film sensors. Tests were carried out using the two-stage Low Speed Research Turbine of the Aerodynamics Research Laboratory of GE Aircraft Engines. Blading in this facility models current, state-of-the-art low pressure turbine configurations. The instrumentation technique involved arrays of densely-packed hot-film sensors on the surfaces of second stage rotor and nozzle blades. The arrays were located at mid-span on both the suction and pressure surfaces. Boundary layer measurements were acquired over a complete range of relevant Reynolds numbers. Data acquisition capabilities provided means for detailed data interrogation in both time and frequency domains. Data indicate that significant regions of laminar and transitional boundary layer flow exist on the rotor and nozzle suction surfaces. Evidence of relaminarization both near the leading edge of the suction surface and along much of the pressure surface was observed. Measurements also reveal the nature of the turbulent bursts occuring within and between the wake segments convecting through the blade row. The complex character of boundary layer transition resulting from flow unsteadiness due to nozzle/nozzle, rotor/nozzle, and nozzle/rotor wake interactions are elucidated using these data. These measurements underscore the need to provide turbomachinery designers with models of boundary layer transition to facilitate accurate prediction of aerodynamic loss and heat transfer.

Version 2 of the Protuberance Correlations for the Shuttle-Orbiter Boundary Layer Transition Tool

NASA Technical Reports Server (NTRS)

King, Rudolph A.; Kegerise, Michael A.; Berry, Scott A.

2009-01-01

Orbiter-specific transition data, acquired in four ground-based facilities (LaRC 20-Inch Mach 6 Air Tunnel, LaRC 31-Inch Mach 10 Air Tunnel, LaRC 20-Inch Mach 6 CF4 Tunnel, and CUBRC LENS-I Shock Tunnel) with three wind tunnel model scales (0.75, 0.90, and 1.8%) and from Orbiter historical flight data, have been analyzed to improve a pre-existing engineering tool for reentry transition prediction on the windward side of the Orbiter. Boundary layer transition (BLT) engineering correlations for transition induced by isolated protuberances are presented using a laminar Navier-Stokes (N-S) database to provide the relevant boundary-layer properties. It is demonstrated that the earlier version of the BLT correlation that had been developed using parameters derived from an engineering boundary-layer code has improved data collapse when developed with the N-S database. Of the new correlations examined, the proposed correlation 5, based on boundary-layer edge and wall properties, was found to provide the best overall correlation metrics when the entire database is employed. The second independent correlation (proposed correlation 7) selected is based on properties within the boundary layer at the protuberance height. The Aeroheating Panel selected a process to derive the recommended coefficients for Version 2 of the BLT Tool. The assumptions and limitations of the recommended protuberance BLT Tool V.2 are presented.

Advanced boundary layer transition measurement methods for flight applications

NASA Technical Reports Server (NTRS)

Holmes, B. J.; Croom, C. C.; Gail, P. D.; Manuel, G. S.; Carraway, D. L.

1986-01-01

In modern laminar flow flight research, it is important to understand the specific cause(s) of laminar to turbulent boundary-layer transition. Such information is crucial to the exploration of the limits of practical application of laminar flow for drag reduction on aircraft. The transition modes of interest in current flight investigations include the viscous Tollmien-Schlichting instability, the inflectional instability at laminar separation, and the crossflow inflectional instability, as well as others. This paper presents the results to date of research on advanced devices and methods used for the study of laminar boundary-layer transition phenomena in the flight environment. Recent advancements in the development of arrayed hot-film devices and of a new flow visualization method are discussed. Arrayed hot-film devices have been designed to detect the presence of laminar separation, and of crossflow vorticity. The advanced flow visualization method utilizes color changes in liquid-crystal coatings to detect boundary-layer transition at high altitude flight conditions. Flight and wind tunnel data are presented to illustrate the design and operation of these advanced methods. These new research tools provide information on disturbance growth and transition mode which is essential to furthering our understanding of practical design limits for applications of laminar flow technology.

Results of correlations for transition location on a clean-up glove installed on an F-14 aircraft and design studies for a laminar glove for the X-29 aircraft accounting for spanwise pressure gradient

NASA Technical Reports Server (NTRS)

Goradia, S. H.; Bobbitt, P. J.; Morgan, H. L.; Ferris, J. C.; Harvey, William D.

1989-01-01

Results of correlative and design studies for transition location, laminar and turbulent boundary-layer parameters, and wake drag for forward swept and aft swept wings are presented. These studies were performed with the use of an improved integral-type boundary-layer and transition-prediction methods. Theoretical predictions were compared with flight measurements at subsonic and transonic flow conditions for the variable aft swept wing F-14 aircraft for which experimental pressure distributions, transition locations, and turbulent boundary-layer velocity profiles were measured. Flight data were available at three spanwise stations for several values of sweep, freestream unit Reynolds number, Mach numbers, and lift coefficients. Theory/experiment correlations indicate excellent agreement for both transition location and turbulent boundary-layer parameters. The results of parametric studies performed during the design of a laminar glove for the forward swept wing X-29 aircraft are also presented. These studies include the effects of a spanwise pressure gradient on transition location and wake drag for several values of freestream Reynolds numbers at a freestream Mach number of 0.9.

Boundary layer turbulence in transitional and developed states

NASA Astrophysics Data System (ADS)

Park, George Ilhwan; Wallace, James M.; Wu, Xiaohua; Moin, Parviz

2012-03-01

Using the recent direct numerical simulations by Wu and Moin ["Transitional and turbulent boundary layer with heat transfer," Phys. Fluids 22, 85 (2010)] of a flat-plate boundary layer with a passively heated wall, statistical properties of the turbulence in transition at Reθ ≈ 300, from individual turbulent spots, and at Reθ ≈ 500, where the spots merge (distributions of the mean velocity, Reynolds stresses, kinetic energy production, and dissipation rates, enstrophy and its components) have been compared to these statistical properties for the developed boundary layer turbulence at Reθ = 1840. When the distributions in the transitional regions are conditionally averaged so as to exclude locations and times when the flow is not turbulent, they closely resemble the distributions in the developed turbulent state at the higher Reynolds number, especially in the buffer layer. Skin friction coefficients, determined in this conditional manner at the two Reynolds numbers in the transitional flow are, of course, much larger than when their values are obtained by including both turbulent and non-turbulent information there, and the conditional averaged values are consistent with the 1/7th power law approximation. An octant analysis based on the combinations of signs of the velocity and temperature fluctuations, u, v, and θ shows that the momentum and heat fluxes are predominantly of the mean gradient type in both the transitional and developed regions. The fluxes appear to be closely associated with vortices that transport momentum and heat toward and away from the wall in both regions of the flow. The results suggest that there may be little fundamental difference between the nonlinear processes involved in the formation of turbulent spots that appear in transition and those that sustain the turbulence when it is developed. They also support the view that the transport processes and the vortical structures that drive them in developed and transitional boundary layer turbulence are, in many dynamically important respects, similar.

Correlation of nosetip boundary-layer transition data measured in ballistics-range experiments

DOE Office of Scientific and Technical Information (OSTI.GOV)

Reda, D.C.

1980-01-01

Preablated nosetips of various carbonaceous materials were tested in a ballistics range. Surface-temperature contours, measured with image-converter cameras, were used to define boundary-layer transition-front contours. Measurements of surface roughness, surface temperature, average transition-front location, and freestream environment were combined with calculations of nosetip flowfields, and with calculations of laminar boundary-layer development in these flowfields, to transform all data into various dimensionless parameters. These parameters were defined by previous attempts to correlate existing wind-tunnel data for transition on rough/blunt bodies. Of the available correlating techniques, only one, based on the concept of a constant (critical) roughness Reynolds number for transition, wasmore » found to successfully describe both the wind-tunnel and ballistics-range data, thereby validating the extrapolation of this concept to actual reentry-vehicle materials and environments.« less

Boundary-Layer Edge Conditions and Transition Reynolds Number Data for a Flight Test at Mach 20 (Reentry F)

NASA Technical Reports Server (NTRS)

Johnson, Charles B.; Stainback, P. Calvin; Wicker, Kathleen C.; Boney, Lillian R.

1972-01-01

A flight experiment, designated Reentry F, was conducted to measure heat-transfer rates for laminar, transitional, and turbulent boundary layers on a 5 deg half-angle cone 3.962 m (13 ft) long with a preflight nose radius of 2.54 mm (0.10 in.). Data were obtained over an altitude range from 36.58 to 18.29 km (120 000 to 60 000 ft) at a flight velocity of about 6.096 km/sec (20 000 ft/sec). The nominal values of the free-stream total enthalpy, sharp-cone Mach number, and the wall-to-total enthalpy ratio were 18 MJ/kg (8000 Btu/lb), 15, and 0.03, respectively. Calculated boundary-layer edge conditions that account for effects of the entropy layer and corresponding local transition Reynolds numbers are reported in the present paper. Fully developed turbulent flow occurred with essentially constant boundary-layer edge conditions near the sharp-cone values. Transition data were obtained with local edge Mach numbers ranging from about 5.55 to 15. Transition Reynolds numbers, based on local condition, were as high as 6.6 x 10(exp 7) with an edge Mach number of about 14.4 at an altitude of 24.38 km (80 000 ft). The transition could be correlated with previous flight data taken over a Mach number range from 3 to 12 in terms of parameters including the effects of local unit Reynolds number, boundary-layer wall-to-edge enthalpy ratio, and local Mach number.

Mg concentration profile and its control in the low temperature grown Mg-doped GaN epilayer

NASA Astrophysics Data System (ADS)

Liu, S. T.; Yang, J.; Zhao, D. G.; Jiang, D. S.; Liang, F.; Chen, P.; Zhu, J. J.; Liu, Z. S.; Liu, W.; Xing, Y.; Zhang, L. Q.; Wang, W. J.; Li, M.; Zhang, Y. T.; Du, G. T.

2018-01-01

In this work, the Cp2Mg flux and growth pressure influence to Mg doping concentration and depth profiles is studied. From the SIMS measurement we found that a transition layer exists at the bottom region of the layer in which the Mg doping concentration changes gradually. The thickness of transition layer decreases with the increases of Mg doping concentration. Through analysis, we found that this is caused by Ga memory effect which the Ga atoms stay residual in MOCVD system will react with Mg source, leading a transition layer formation and improve the growth rate. And the Ga memory effect can be well suppressed by increasing Mg doping concentration and growth pressure and thus get a steep Mg doping at the bottom region of p type layer.

Orbiter Entry Aeroheating Working Group Viscous CFD Boundary Layer Transition Trailblazer Solutions

NASA Technical Reports Server (NTRS)

Wood, William A.; Erickson, David W.; Greene, Francis A.

2007-01-01

Boundary layer transition correlations for the Shuttle Orbiter have been previously developed utilizing a two-layer boundary layer prediction technique. The particular two-layer technique that was used is limited to Mach numbers less than 20. To allow assessments at Mach numbers greater than 20, it is proposed to use viscous CFD to the predict boundary layer properties. This report addresses if the existing Orbiter entry aeroheating viscous CFD solutions, which were originally intended to be used for heat transfer rate predictions, adequately resolve boundary layer edge properties and if the existing two-layer results could be leveraged to reduce the number of needed CFD solutions. The boundary layer edge parameters from viscous CFD solutions are extracted along the wind side centerline of the Space Shuttle Orbiter at reentry conditions, and are compared with results from the two-layer boundary layer prediction technique. The differences between the viscous CFD and two-layer prediction techniques vary between Mach 6 and 18 flight conditions and Mach 6 wind tunnel conditions, and there is not a straightforward scaling between the viscous CFD and two-layer values. Therefore: it is not possible to leverage the existing two-layer Orbiter flight boundary layer data set as a substitute for a viscous CFD data set; but viscous CFD solutions at the current grid resolution are sufficient to produce a boundary layer data set suitable for applying edge-based boundary layer transition correlations.

Hypersonic Boundary-Layer Transition for X-33 Phase 2 Vehicle

NASA Technical Reports Server (NTRS)

Thompson, Richard A.; Hamilton, Harris H., II; Berry, Scott A.; Horvath, Thomas J.; Nowak, Robert J.

1998-01-01

A status review of the experimental and computational work performed to support the X-33 program in the area of hypersonic boundary-layer transition is presented. Global transition fronts are visualized using thermographic phosphor measurements. Results are used to derive transition correlations for "smooth body" and discrete roughness data and a computational tool is developed to predict transition onset for X-33 using these results. The X-33 thermal protection system appears to be conservatively designed for transition effects based on these studies. Additional study is needed to address concerns related to surface waviness. A discussion of future test plans is included.

Techniques used in the F-14 variable-sweep transition flight experiment

NASA Technical Reports Server (NTRS)

Anderson, Bianca Trujillo; Meyer, Robert R., Jr.; Chiles, Harry R.

1988-01-01

This paper discusses and evaluates the test measurement techniques used to determine the laminar-to-turbulent boundary layer transition location in the F-14 variable-sweep transition flight experiment (VSTFE). The main objective of the VSTFE was to determine the effects of wing sweep on the laminar-to-turbulent transition location at conditions representative of transport aircraft. Four methods were used to determine the transition location: (1) a hot-film anemometer system; (2) two boundary-layer rakes; (3) surface pitot tubes; and (4) liquid crystals for flow visualization. Of the four methods, the hot-film anemometer system was the most reliable indicator of transition.

The effect of bioadhesive on the interfacial compatibility and pervaporation performance of composite membranes by MD and GCMC simulation.

PubMed

Wang, Baohe; Nie, Yan; Ma, Jing

2018-03-01

Combing molecular dynamics (MD) and Grand Canonical Monte Carlo (GCMC) simulation, the effect of bioadhesive transition layer on the interfacial compatibility of the pervaporation composite membranes, and the pervaporation performance toward penetrant molecules were investigated. In our previous experimental study, the structural stability and permeability selectivity of the composite membranes were considerably enhanced by the introduction of bioadhesive carbopol (CP). In the present study, the interfacial compatibility and the interfacial energies between the chitosan (CS) separation layer, CP transition layer and the support layer were investigated, respectively. The mobility of polymer chains, free volume in bulk and interface regions were evaluated by the mean-square displacement (MSD) and free volume voids (FFV) analysis. The diffusion and sorption behavior of water/ethanol molecules in bulk and interface regions were characterized. The simulation results of membrane structure have good consistency, indicating that the introduction of CP transition layer improved the interfacial compatibility and interaction between the separation layer and the support layer. Comparing the bulk region of the separation layer, the mobility and free volume of the polymer chain in the interface region decreased and thus reduced the swelling of CS active layer, revealing the increased diffusion selectivity toward the permeated water and ethanol molecules. The strong hydrogen bonds interaction between the COOH of the CP transition layer and water molecules increased the adsorption of water molecules in the interface region. The simulation results were quite consistent with the experimental results. Copyright © 2018 Elsevier Inc. All rights reserved.

A Classification of Subaqueous Density Flows Based on Transformations From Proximal to Distal Regions

NASA Astrophysics Data System (ADS)

Hermidas, Navid; Eggenhuisen, Joris; Luthi, Stefan; Silva Jacinto, Ricardo; Toth, Ferenc; Pohl, Florian

2017-04-01

Transformations of a subaqueous density flow from proximal to distal regions are investigated. A classification of these transformations based on the state of the free shear and boundary layers and existence of a plug layer during transition from a debris flow to a turbidity current is presented. A connection between the emplaced deposit by the flow and the relevant flow type is drawn through the results obtained from a series of laboratory flume experiments. These were performed using 9%, 15%, and 21% sediment mixture concentrations composed of sand, silt, clay, and tap water, on varying bed slopes of 6°, 8°, and 9.5°, and with discharge rates of 10[m3/h] and 15[m3/h]. Stress-controlled rheometry experiments were performed on the mixtures to obtain apparent viscosity data. A classification was developed based on the imposed flow conditions, where a cohesive flow may fall within one of five distinct flow types: 1) a cohesive plug flow (PF) with a laminar free shear and boundary layers, 2) a top transitional plug flow (TTPF) containing a turbulent free shear layer, a plug layer, and a laminar boundary layer, 3) a complete transitional plug flow (CTPF) consisting of a turbulent free shear and boundary layers and a plug, 4) a transitional turbidity current (TTC) with a turbulent free shear layer and a laminar boundary layer, and, 5) a completely turbulent turbidity current (TC). During the experiments, flow type PF resulted in en masse deposition of a thick uniform ungraded muddy sand mixture, which was emplaced once the yield stress overcame the gravitational forces within the tail region of the flow. Flow type TTPF resulted in deposition of a thin ungraded basal clean sand layer during the run. This layer was covered by a muddy sand deposit from the tail. Flow type TTC did not deposit any sediment during the run. A uniform muddy sand mixture was emplaced by the tail of the flow. Flow type TC resulted in deposition of poorly sorted massive bottom sand layer. This layer was overlain by either a muddy sand mixture or a sand and silt planar lamination. Flow type CTPF was not observed during the experiments. Furthermore, it was observed that flows which are in transition from a TTC to a TTPF result in a thin bottom clean sand layer covered by a banded transitional interval. This was overlain by a muddy sand layer and a very thin clean sand layer, resulting from traction by dilute turbulent wake. In all cases a mud cap was emplaced on top of the deposit after the runs were terminated.

High-Speed Boundary-Layer Transition Induced by an Isolated Roughness Element

NASA Technical Reports Server (NTRS)

Kegerise, Michael A.; Owens, Lewis R.; King, Rudolph A.

2010-01-01

Progress on an experimental effort to quantify the instability mechanisms associated with roughness-induced transition in a high-speed boundary layer is reported in this paper. To simulate the low-disturbance environment encountered during high-altitude flight, the experimental study was performed in the NASA-Langley Mach 3.5 Supersonic Low-Disturbance Tunnel. A flat plate trip sizing study was performed first to identify the roughness height required to force transition. That study, which included transition onset measurements under both quiet and noisy freestream conditions, confirmed the sensitivity of roughness-induced transition to freestream disturbance levels. Surveys of the laminar boundary layer on a 7deg half-angle sharp-tipped cone were performed via hot-wire anemometry and pitot-pressure measurements. The measured mean mass-flux and Mach-number profiles agreed very well with computed mean-flow profiles. Finally, surveys of the boundary layer developing downstream of an isolated roughness element on the cone were performed. The measurements revealed an instability in the far wake of the roughness element that grows exponentially and has peak frequencies in the 150 to 250 kHz range.

Nonlinear Transient Growth and Boundary Layer Transition

NASA Technical Reports Server (NTRS)

Paredes, Pedro; Choudhari, Meelan M.; Li, Fei

2016-01-01

Parabolized stability equations (PSE) are used in a variational approach to study the optimal, non-modal disturbance growth in a Mach 3 at plate boundary layer and a Mach 6 circular cone boundary layer. As noted in previous works, the optimal initial disturbances correspond to steady counter-rotating streamwise vortices, which subsequently lead to the formation of streamwise-elongated structures, i.e., streaks, via a lift-up effect. The nonlinear evolution of the linearly optimal stationary perturbations is computed using the nonlinear plane-marching PSE for stationary perturbations. A fully implicit marching technique is used to facilitate the computation of nonlinear streaks with large amplitudes. To assess the effect of the finite-amplitude streaks on transition, the linear form of plane- marching PSE is used to investigate the instability of the boundary layer flow modified by spanwise periodic streaks. The onset of bypass transition is estimated by using an N- factor criterion based on the amplification of the streak instabilities. Results show that, for both flow configurations of interest, streaks of sufficiently large amplitude can lead to significantly earlier onset of transition than that in an unperturbed boundary layer without any streaks.

Bimetallic strip for low temperature use. [4-300/sup 0/K

DOEpatents

Bussiee, J.F.; Welch, D.O.; Suenaga, M.

A class of mechanically pre-stressed structures is provided suitably bi-layer strips, consisting of a layer of group 5 transition metals in intimate contact with a layer of an intermetallic compound of transition metals with certain group 3A, 4A or 5A metals or metalloids such as Ga, In, Si, Ge, Sn, As or Sb. The changes of Young's modulus of these bi-layered combinations at temperatures in the region of somewhat above absolute zero provides a useful means of sensing temperature changes. Such bi-metallic strips may be used as control strips in thermostats, or in direct dial reading instruments. The structures are made by preparing a sandwich of a group 5B transition metal strip between the substantially thicker strips of an alloy between copper and a predetermined group 3A, 4A or 5A metal or metalloid, holding the three layers are heated, cooled the copper alloys and is removed. Removing one of the two formed interlayer alloys between the transition metal and the metal previously alloyed with copper remain.

Bimetallic strip for low temperature use

DOEpatents

Bussiere, Jean F.; Welch, David O.; Suenaga, Masaki

1981-01-01

There is provided a class of mechanically pre-stressed structures, suitably bi-layer strips comprising a layer of group 5 transition metals in intimate contact with a layer of an intermetallic compound of said transition metals with certain group 3A, 4A or 5A metals or metalloids suitably gallium, indium, silicon, germanium, tin, arsenic or antimony. The changes of Young's modulus of these bi-layered combinations at temperatures in the region of but somewhat above absolute zero provides a useful means of sensing temperature changes. Such bi-metallic strips may be used as control strips in thermostats, in direct dial reading instruments, or the like. The structures are made by preparing a sandwich of a group 5B transition metal strip between the substantially thicker strips of an alloy between copper and a predetermined group 3A, 4A or 5A metal or metalloid, holding the three layers of the sandwich in intimate contact heating the same, cooling the same and removing the copper alloy and then removing one of the two thus formed interlayer alloys between said transition metal and the metal previously alloyed with copper.

On the Unsteadiness of a Transitional Shock Wave-Boundary Layer Interaction Using Fast-Response Pressure-Sensitive Paint

NASA Astrophysics Data System (ADS)

Lash, E. Lara; Schmisseur, John

2017-11-01

Pressure-sensitive paint has been used to evaluate the unsteady dynamics of transitional and turbulent shock wave-boundary layer interactions generated by a vertical cylinder on a flat plate in a Mach 2 freestream. The resulting shock structure consists of an inviscid bow shock that bifurcates into a separation shock and trailing shock. The primary features of interest are the separation shock and an upstream influence shock that is intermittently present in transitional boundary layer interactions, but not observed in turbulent interactions. The power spectral densities, frequency peaks, and normalized wall pressures are analyzed as the incoming boundary layer state changes from transitional to fully turbulent, comparing both centerline and outboard regions of the interaction. The present study compares the scales and frequencies of the dynamics of the separation shock structure in different boundary layer regimes. Synchronized high-speed Schlieren imaging provides quantitative statistical analyses as well as qualitative comparisons to the fast-response pressure sensitive paint measurements. Materials based on research supported by the U.S. Office of Naval Research under Award Number N00014-15-1-2269.

Laminar microvascular transit time distribution in the mouse somatosensory cortex revealed by Dynamic Contrast Optical Coherence Tomography

PubMed Central

Merkle, Conrad W.; Srinivasan, Vivek J.

2015-01-01

The transit time distribution of blood through the cerebral microvasculature both constrains oxygen delivery and governs the kinetics of neuroimaging signals such as blood-oxygen-level-dependent functional Magnetic Resonance Imaging (BOLD fMRI). However, in spite of its importance, capillary transit time distribution has been challenging to quantify comprehensively and efficiently at the microscopic level. Here, we introduce a method, called Dynamic Contrast Optical Coherence Tomography (DyC-OCT), based on dynamic cross-sectional OCT imaging of an intravascular tracer as it passes through the field-of-view. Quantitative transit time metrics are derived from temporal analysis of the dynamic scattering signal, closely related to tracer concentration. Since DyC-OCT does not require calibration of the optical focus, quantitative accuracy is achieved even deep in highly scattering brain tissue where the focal spot degrades. After direct validation of DyC-OCT against dilution curves measured using a fluorescent plasma label in surface pial vessels, we used DyC-OCT to investigate the transit time distribution in microvasculature across the entire depth of the mouse somatosensory cortex. Laminar trends were identified, with earlier transit times and less heterogeneity in the middle cortical layers. The early transit times in the middle cortical layers may explain, at least in part, the early BOLD fMRI onset times observed in these layers. The layer-dependencies in heterogeneity may help explain how a single vascular supply manages to deliver oxygen to individual cortical layers with diverse metabolic needs. PMID:26477654

Laminar microvascular transit time distribution in the mouse somatosensory cortex revealed by Dynamic Contrast Optical Coherence Tomography.

PubMed

Merkle, Conrad W; Srinivasan, Vivek J

2016-01-15

The transit time distribution of blood through the cerebral microvasculature both constrains oxygen delivery and governs the kinetics of neuroimaging signals such as blood-oxygen-level-dependent functional Magnetic Resonance Imaging (BOLD fMRI). However, in spite of its importance, capillary transit time distribution has been challenging to quantify comprehensively and efficiently at the microscopic level. Here, we introduce a method, called Dynamic Contrast Optical Coherence Tomography (DyC-OCT), based on dynamic cross-sectional OCT imaging of an intravascular tracer as it passes through the field-of-view. Quantitative transit time metrics are derived from temporal analysis of the dynamic scattering signal, closely related to tracer concentration. Since DyC-OCT does not require calibration of the optical focus, quantitative accuracy is achieved even deep in highly scattering brain tissue where the focal spot degrades. After direct validation of DyC-OCT against dilution curves measured using a fluorescent plasma label in surface pial vessels, we used DyC-OCT to investigate the transit time distribution in microvasculature across the entire depth of the mouse somatosensory cortex. Laminar trends were identified, with earlier transit times and less heterogeneity in the middle cortical layers. The early transit times in the middle cortical layers may explain, at least in part, the early BOLD fMRI onset times observed in these layers. The layer-dependencies in heterogeneity may help explain how a single vascular supply manages to deliver oxygen to individual cortical layers with diverse metabolic needs. Copyright © 2015 Elsevier Inc. All rights reserved.

Effect of ZnO buffer layer on phase transition properties of vanadium dioxide thin films

NASA Astrophysics Data System (ADS)

Zhu, Huiqun; Li, Lekang; Li, Chunbo

2016-03-01

VO2 thin films were prepared on ZnO buffer layers by DC magnetron sputtering at room temperature using vanadium target and post annealing at 400 °C. The ZnO buffer layers with different thickness deposited on glass substrates by magnetron sputtering have a high visible and near infrared optical transmittance. The electrical resistivity and the phase transition properties of the VO2/ZnO composite thin films in terms of temperature were investigated. The results showed that the resistivity variation of VO2 thin film with ZnO buffer layer deposited for 35 min was 16 KΩ-cm. The VO2/ZnO composite thin films exhibit a reversible semiconductor-metal phase transition at 48 °C.

Natural laminar flow and airplane stability and control

NASA Technical Reports Server (NTRS)

Vandam, Cornelis P.

1986-01-01

Location and mode of transition from laminar to turbulent boundary layer flow have a dominant effect on the aerodynamic characteristics of an airfoil section. The influences of these parameters on the sectional lift and drag characteristics of three airfoils are examined. Both analytical and experimental results demonstrate that when the boundary layer transitions near the leading edge as a result of surface roughness, extensive trailing-edge separation of the turbulent boundary layer may occur. If the airfoil has a relatively sharp leading-edge, leading-edge stall due to laminar separation can occur after the leading-edge suction peak is formed. These two-dimensional results are used to examine the effects of boundary layer transition behavior on airplane longitudinal and lateral-directional stability and control.

Delay of Transition Using Forced Damping

NASA Technical Reports Server (NTRS)

Exton, Reginald J.

2014-01-01

Several experiments which have reported a delay of transition are analyzed in terms of the frequencies of the induced disturbances generated by different flow control elements. Two of the experiments employed passive stabilizers in the boundary layer, one leading-edge bluntness, and one employed an active spark discharge in the boundary layer. It is found that the frequencies generated by the various elements lie in the damping region of the associated stability curve. It is concluded that the creation of strong disturbances in the damping region stabilizes the boundary-layer and delays the transition from laminar to turbulent flow.

Comparison of turbulence in a transitional boundary layer to turbulence in a developed boundary layer*

NASA Astrophysics Data System (ADS)

Park, G. I.; Wallace, J.; Wu, X.; Moin, P.

2010-11-01

Using a recent DNS of a flat-plate boundary layer, statistics of turbulence in transition at Reθ= 500 where spots merge (distributions of the mean velocity, rms velocity and vorticity fluctuations, Reynolds shear stress, kinetic energy production and dissipation rates and enstrophy) have been compared to these statistics for the developed boundary layer turbulence at Reθ= 1850. When the distributions in the transitional region, determined in narrow planes 0.03 Reθ wide, exclude regions and times when the flow is not turbulent, they closely resemble those in the developed turbulent state at the higher Reynolds number, especially in the buffer and sublayers. The skin friction coefficient, determined in this conditional manner in the transitional flow is, of course, much larger than that obtained by including both turbulent and non-turbulent information there, and is consistent with a value obtained by extrapolating from the developed turbulent region. We are attempting to perform this data analysis even further upstream in the transitioning flow at Reθ= 300 where the turbulent spots are individuated. These results add further evidence to support the view that the structure of a developed turbulent boundary layer is little different from its structure in its embryonic form in turbulent spots. *CTR 2010 Summer Program research.

In-Flight Boundary-Layer Transition of a Large Flat Plate at Supersonic Speeds

NASA Technical Reports Server (NTRS)

Banks, D. W.; Frederick, M. A.; Tracy, R. R.; Matisheck, J. R.; Vanecek, N. D.

2012-01-01

A flight experiment was conducted to investigate the pressure distribution, local-flow conditions, and boundary-layer transition characteristics on a large flat plate in flight at supersonic speeds up to Mach 2.00. The tests used a NASA testbed aircraft with a bottom centerline mounted test fixture. The primary objective of the test was to characterize the local flow field in preparation for future tests of a high Reynolds number natural laminar flow test article. A second objective was to determine the boundary-layer transition characteristics on the flat plate and the effectiveness of using a simplified surface coating. Boundary-layer transition was captured in both analog and digital formats using an onboard infrared imaging system. Surface pressures were measured on the surface of the flat plate. Flow field measurements near the leading edge of the test fixture revealed the local flow characteristics including downwash, sidewash, and local Mach number. Results also indicated that the simplified surface coating did not provide sufficient insulation from the metallic structure, which likely had a substantial effect on boundary-layer transition compared with that of an adiabatic surface. Cold wall conditions were predominant during the acceleration to maximum Mach number, and warm wall conditions were evident during the subsequent deceleration.

Ultrasonic guided wave propagation across waveguide transitions: energy transfer and mode conversion.

PubMed

Puthillath, Padmakumar; Galan, Jose M; Ren, Baiyang; Lissenden, Cliff J; Rose, Joseph L

2013-05-01

Ultrasonic guided wave inspection of structures containing adhesively bonded joints requires an understanding of the interaction of guided waves with geometric and material discontinuities or transitions in the waveguide. Such interactions result in mode conversion with energy being partitioned among the reflected and transmitted modes. The step transition between an aluminum layer and an aluminum-adhesive-aluminum multi-layer waveguide is analyzed as a model structure. Dispersion analysis enables assessment of (i) synchronism through dispersion curve overlap and (ii) wavestructure correlation. Mode-pairs in the multi-layer waveguide are defined relative to a prescribed mode in a single layer as being synchronized and having nearly perfect wavestructure matching. Only a limited number of mode-pairs exist, and each has a unique frequency range. A hybrid model based on semi-analytical finite elements and the normal mode expansion is implemented to assess mode conversion at a step transition in a waveguide. The model results indicate that synchronism and wavestructure matching is associated with energy transfer through the step transition, and that the energy of an incident wave mode in a single layer is transmitted almost entirely to the associated mode-pair, where one exists. This analysis guides the selection of incident modes that convert into transmitted modes and improve adhesive joint inspection with ultrasonic guided waves.

Shuttle Damage/Repair from the Perspective of Hypersonic Boundary Layer Transition - Experimental Results

NASA Technical Reports Server (NTRS)

Horvath, Thomas J.; Berry, Scott A.; Merski, N. Ronald; Berger, Karen T.; Buck, Gregory M.; Liechty, Derek S.; Schneider, Steven P.

2006-01-01

An overview is provided of the experimental wind tunnel program conducted at the NASA Langley Research Center Aerothermodynamics Laboratory in support of an agency-wide effort to prepare the Shuttle Orbiter for Return-to-Flight. The effect of an isolated protuberance and an isolated rectangular cavity on hypersonic boundary layer transition onset on the windward surface of the Shuttle Orbiter has been experimentally characterized. These experimental studies were initiated to provide a protuberance and cavity effects database for developing hypersonic transition criteria to support on-orbit disposition of thermal protection system damage or repair. In addition, a synergistic experimental investigation was undertaken to assess the impact of an isolated mass-flow entrainment source (simulating pyrolysis/outgassing from a proposed tile repair material) on boundary layer transition. A brief review of the relevant literature regarding hypersonic boundary layer transition induced from cavities and localized mass addition from ablation is presented. Boundary layer transition results were obtained using 0.0075-scale Orbiter models with simulated tile damage (rectangular cavities) of varying length, width, and depth and simulated tile damage or repair (protuberances) of varying height. Cavity and mass addition effects were assessed at a fixed location (x/L = 0.3) along the model centerline in a region of near zero pressure gradient. Cavity length-to-depth ratio was systematically varied from 2.5 to 17.7 and length-to-width ratio of 1 to 8.5. Cavity depth-to-local boundary layer thickness ranged from 0.5 to 4.8. Protuberances were located at several sites along the centerline and port/starboard attachment lines along the chine and wing leading edge. Protuberance height-to-boundary layer thickness was varied from approximately 0.2 to 1.1. Global heat transfer images and heating distributions of the Orbiter windward surface using phosphor thermography were used to infer the state of the boundary layer (laminar, transitional, or turbulent). Test parametrics include angles-of-attack of 30 deg and 40 deg, sideslip angle of 0 deg, freestream Reynolds numbers from 0.02x106 to 7.3x106 per foot, edge-to-wall temperature ratio from 0.4 to 0.8, and normal shock density ratios of approximately 5.3, 6.0, and 12 in Mach 6 air, Mach 10 air, and Mach 6 CF4, respectively. Testing to simulate the effects of ablation from a proposed tile repair concept indicated that transition was not a concern. The experimental protuberance and cavity databases highlighted in this report were used to formulate boundary layer transition correlations that were an integral part of an analytical process to disposition observed Orbiter TPS damage during STS- 114.

Simulating boundary layer transition with low-Reynolds-number k-epsilon turbulence models. I - An evaluation of prediction characteristics. II - An approach to improving the predictions

NASA Technical Reports Server (NTRS)

Schmidt, R. C.; Patankar, S. V.

1991-01-01

The capability of two k-epsilon low-Reynolds number (LRN) turbulence models, those of Jones and Launder (1972) and Lam and Bremhorst (1981), to predict transition in external boundary-layer flows subject to free-stream turbulence is analyzed. Both models correctly predict the basic qualitative aspects of boundary-layer transition with free stream turbulence, but for calculations started at low values of certain defined Reynolds numbers, the transition is generally predicted at unrealistically early locations. Also, the methods predict transition lengths significantly shorter than those found experimentally. An approach to overcoming these deficiencies without abandoning the basic LRN k-epsilon framework is developed. This approach limits the production term in the turbulent kinetic energy equation and is based on a simple stability criterion. It is correlated to the free-stream turbulence value. The modification is shown to improve the qualitative and quantitative characteristics of the transition predictions.

Coherent structures in bypass transition induced by a cylinder wake

NASA Astrophysics Data System (ADS)

Pan, Chong; Wang, Jin Jun; Zhang, Pan Feng; Feng, Li Hao

Flat-plate boundary layer transition induced by the wake vortex of a two-dimensional circular cylinder is experimentally investigated. Combined visualization and velocity measurements show a different transition route from the Klebanoff mode in free-stream turbulence-induced transition. This transition scenario is mainly characterized as: (i) generation of secondary transverse vortical structures near the flat plate surface in response to the von Kn vortex street of the cylinder; (ii) formation of hairpin vortices due to the secondary instability of secondary vortical structures; (iii) growth of hairpins which is accelerated by wake-vortex induction; (iv) formation of hairpin packets and the associated streaky structures. Detailed investigation shows that during transition the evolution dynamics and self-sustaining mechanisms of hairpins, hairpin packets and streaks are consistent with those in a turbulent boundary layer. The wake vortex mainly plays the role of generating and destabilizing secondary transverse vortices. After that, the internal mechanisms become dominant and lead to the setting up of a self-sustained turbulent boundary layer.

Numerical simulation of transitional flow on a wind turbine airfoil with RANS-based transition model

NASA Astrophysics Data System (ADS)

Zhang, Ye; Sun, Zhengzhong; van Zuijlen, Alexander; van Bussel, Gerard

2017-09-01

This paper presents a numerical investigation of transitional flow on the wind turbine airfoil DU91-W2-250 with chord-based Reynolds number Rec = 1.0 × 106. The Reynolds-averaged Navier-Stokes based transition model using laminar kinetic energy concept, namely the k - kL - ω model, is employed to resolve the boundary layer transition. Some ambiguities for this model are discussed and it is further implemented into OpenFOAM-2.1.1. The k - kL - ω model is first validated through the chosen wind turbine airfoil at the angle of attack (AoA) of 6.24° against wind tunnel measurement, where lift and drag coefficients, surface pressure distribution and transition location are compared. In order to reveal the transitional flow on the airfoil, the mean boundary layer profiles in three zones, namely the laminar, transitional and fully turbulent regimes, are investigated. Observation of flow at the transition location identifies the laminar separation bubble. The AoA effect on boundary layer transition over wind turbine airfoil is also studied. Increasing the AoA from -3° to 10°, the laminar separation bubble moves upstream and reduces in size, which is in close agreement with wind tunnel measurement.

Boundary layer transition detection on the X-15 vertical fin using surface-pressure-fluctuation measurements

NASA Technical Reports Server (NTRS)

Lewis, T. L.; Banner, R. D.

1971-01-01

A flush-mounted microphone on the vertical fin of an X-15 airplane was used to investigate boundary layer transition phenomenon during flights to peak altitudes of approximately 70,000 meters. The flight results were compared with those from wind tunnel studies, skin temperature measurements, and empirical prediction data. The Reynolds numbers determined for the end of transition were consistent with those obtained from wind tunnel studies. Maximum surface-pressure-fluctuation coefficients in the transition region were about an order of magnitude greater than those for fully developed turbulent flow. This was also consistent with wind tunnel data. It was also noted that the power-spectral-density estimates of the surface-pressure fluctuations were characterized by a shift in power from high frequencies to low frequencies as the boundary layer changed from turbulent to laminar flow. Large changes in power at the lowest frequencies appeared to mark the beginning of transition.

Onset of two-dimensional superconductivity in space charge doped few-layer molybdenum disulfide

NASA Astrophysics Data System (ADS)

Biscaras, Johan; Chen, Zhesheng; Paradisi, Andrea; Shukla, Abhay

2015-11-01

Atomically thin films of layered materials such as molybdenum disulfide (MoS2) are of growing interest for the study of phase transitions in two-dimensions through electrostatic doping. Electrostatic doping techniques giving access to high carrier densities are needed to achieve such phase transitions. Here we develop a method of electrostatic doping which allows us to reach a maximum n-doping density of 4 × 1014 cm-2 in few-layer MoS2 on glass substrates. With increasing carrier density we first induce an insulator to metal transition and subsequently an incomplete metal to superconductor transition in MoS2 with critical temperature ~10 K. Contrary to earlier reports, after the onset of superconductivity, the superconducting transition temperature does not depend on the carrier density. Our doping method and the results we obtain in MoS2 for samples as thin as bilayers indicates the potential of this approach.

In-flight transition measurement on a 10 deg cone at Mach numbers from 0.5 to 2.0

NASA Technical Reports Server (NTRS)

Fisher, D. F.; Dougherty, N. S., Jr.

1982-01-01

Boundary layer transition measurements were made in flight on a 10 deg transition cone tested previously in 23 wind tunnels. The cone was mounted on the nose of an F-15 aircraft and flown at Mach numbers room 0.5 to 2.0 and altitudes from 1500 meters (5000 feet) to 15,000 meters (50,000 feet), overlapping the Mach number/Reynolds number envelope of the wind tunnel tests. Transition was detected using a traversing pitot probe in contact with the surface. Data were obtained near zero cone incidence and adiabatic wall temperature. Transition Reynolds number was found to be a function of Mach number and of the ratio of wall temperature to adiabatic all temperature. Microphones mounted flush with the cone surface measured free-stream disturbances imposed on the laminar boundary layer and identified Tollmien-Schlichting waves as the probable cause of transition. Transition Reynolds number also correlated with the disturbance levels as measured by the cone surface microphones under a laminar boundary layer as well as the free-stream impact.

Boundary-Layer Transition on a Slender Cone in Hypervelocity Flow with Real Gas Effects

NASA Astrophysics Data System (ADS)

Jewell, Joseph Stephen

The laminar to turbulent transition process in boundary layer flows in thermochemical nonequilibrium at high enthalpy is measured and characterized. Experiments are performed in the T5 Hypervelocity Reflected Shock Tunnel at Caltech, using a 1 m length 5-degree half angle axisymmetric cone instrumented with 80 fast-response annular thermocouples, complemented by boundary layer stability computations using the STABL software suite. A new mixing tank is added to the shock tube fill apparatus for premixed freestream gas experiments, and a new cleaning procedure results in more consistent transition measurements. Transition location is nondimensionalized using a scaling with the boundary layer thickness, which is correlated with the acoustic properties of the boundary layer, and compared with parabolized stability equation (PSE) analysis. In these nondimensionalized terms, transition delay with increasing CO2 concentration is observed: tests in 100% and 50% CO2, by mass, transition up to 25% and 15% later, respectively, than air experiments. These results are consistent with previous work indicating that CO2 molecules at elevated temperatures absorb acoustic instabilities in the MHz range, which is the expected frequency of the Mack second-mode instability at these conditions, and also consistent with predictions from PSE analysis. A strong unit Reynolds number effect is observed, which is believed to arise from tunnel noise. NTr for air from 5.4 to 13.2 is computed, substantially higher than previously reported for noisy facilities. Time- and spatially-resolved heat transfer traces are used to track the propagation of turbulent spots, and convection rates at 90%, 76%, and 63% of the boundary layer edge velocity, respectively, are observed for the leading edge, centroid, and trailing edge of the spots. A model constructed with these spot propagation parameters is used to infer spot generation rates from measured transition onset to completion distance. Finally, a novel method to control transition location with boundary layer gas injection is investigated. An appropriate porous-metal injector section for the cone is designed and fabricated, and the efficacy of injected CO2 for delaying transition is gauged at various mass flow rates, and compared with both no injection and chemically inert argon injection cases. While CO2 injection seems to delay transition, and argon injection seems to promote it, the experimental results are inconclusive and matching computations do not predict a reduction in N factor from any CO2 injection condition computed.

Atmospheric boundary layer evening transitions over West Texas

USDA-ARS?s Scientific Manuscript database

A systemic analysis of the atmospheric boundary layer behavior during some evening transitions over West Texas was done using the data from an extensive array of instruments which included small and large aperture scintillometers, net radiometers, and meteorological stations. The analysis also comp...

Evidence for a π-junction in Nb/F/Nb' trilayers from superfluid density measurements

NASA Astrophysics Data System (ADS)

Lemberger, Thomas; Hinton, Michael; Steers, Stanley; Peters, Bryan; Yang, Fengyuan

Two-coil measurements of the sheet superfluid density of Nb/NiV/Nb' trilayers reveal the transition temperatures and volume superfluid densities of both Nb layers, as functions of the thickness, dF, of the intervening ferromagnetic (F) Ni0.96V0.04 layer. The upper transition occurs when the thicker Nb layer goes superconducting and superfluid first appears. Fitting the high-temperature superfluid density to an appropriate functional form reveals the presence of a lower ``transition'' where additional superfluid appears. This event is really a crossover, but the difference is irrelevant here. There is a surprising minimum in superfluid densities of both Nb layers at dF ~ 30 Å, followed by a slow rise. This behavior suggests that a π phase difference between the Nb layers develops at dF ~ 30 Å and continues to larger F thickness. Supported in part by NSF Grant DMR-0805227.

Boundary Layer Transition Results From STS-114

NASA Technical Reports Server (NTRS)

Berry, Scott A.; Horvath, Thomas J.; Cassady, Amy M.; Kirk, Benjamin S.; Wang, K. C.; Hyatt, Andrew J.

2006-01-01

The tool for predicting the onset of boundary layer transition from damage to and/or repair of the thermal protection system developed in support of Shuttle Return to Flight is compared to the STS-114 flight results. The Boundary Layer Transition (BLT) Tool is part of a suite of tools that analyze the aerothermodynamic environment of the local thermal protection system to allow informed disposition of damage for making recommendations to fly as is or to repair. Using mission specific trajectory information and details of each damage site or repair, the expected time of transition onset is predicted to help determine the proper aerothermodynamic environment to use in the subsequent thermal and stress analysis of the local structure. The boundary layer transition criteria utilized for the tool was developed from ground-based measurements to account for the effect of both protuberances and cavities and has been calibrated against flight data. Computed local boundary layer edge conditions provided the means to correlate the experimental results and then to extrapolate to flight. During STS-114, the BLT Tool was utilized and was part of the decision making process to perform an extravehicular activity to remove the large gap fillers. The role of the BLT Tool during this mission, along with the supporting information that was acquired for the on-orbit analysis, is reviewed. Once the large gap fillers were removed, all remaining damage sites were cleared for reentry as is. Post-flight analysis of the transition onset time revealed excellent agreement with BLT Tool predictions.

Boundary Layer Transition on X-43A

NASA Technical Reports Server (NTRS)

Berry, Scott; Daryabeigi, Kamran; Wurster, Kathryn; Bittner, Robert

2008-01-01

The successful Mach 7 and 10 flights of the first fully integrated scramjet propulsion systems by the Hyper-X (X-43A) program have provided the means with which to verify the original design methodologies and assumptions. As part of Hyper-X s propulsion-airframe integration, the forebody was designed to include a spanwise array of vortex generators to promote boundary layer transition ahead of the engine. Turbulence at the inlet is thought to provide the most reliable engine design and allows direct scaling of flight results to groundbased data. Pre-flight estimations of boundary layer transition, for both Mach 7 and 10 flight conditions, suggested that forebody boundary layer trips were required to ensure fully turbulent conditions upstream of the inlet. This paper presents the results of an analysis of the thermocouple measurements used to infer the dynamics of the transition process during the trajectories for both flights, on both the lower surface (to assess trip performance) and the upper surface (to assess natural transition). The approach used in the analysis of the thermocouple data is outlined, along with a discussion of the calculated local flow properties that correspond to the transition events as identified in the flight data. The present analysis has confirmed that the boundary layer trips performed as expected for both flights, providing turbulent flow ahead of the inlet during critical portions of the trajectory, while the upper surface was laminar as predicted by the pre-flight analysis.

Effect of strain on electronic and thermoelectric properties of few layers to bulk MoS₂.

PubMed

Bhattacharyya, Swastibrata; Pandey, Tribhuwan; Singh, Abhishek K

2014-11-21

The sensitive dependence of the electronic and thermoelectric properties of MoS₂ on applied strain opens up a variety of applications in the emerging area of straintronics. Using first-principles-based density functional theory calculations, we show that the band gap of a few layers of MoS₂ can be tuned by applying normal compressive (NC) strain, biaxial compressive (BC) strain, and biaxial tensile (BT) strain. A reversible semiconductor-to-metal transition (S-M transition) is observed under all three types of strain. In the case of NC strain, the threshold strain at which the S-M transition occurs increases when the number of layers increase and becomes maximum for the bulk. On the other hand, the threshold strain for the S-M transition in both BC and BT strains decreases when the number of layers increase. The difference in the mechanisms for the S-M transition is explained for different types of applied strain. Furthermore, the effect of both strain type and the number of layers on the transport properties are also studied using Botzmann transport theory. We optimize the transport properties as a function of the number of layers and the applied strain. 3L- and 2L-MoS₂ emerge as the most efficient thermoelectric materials under NC and BT strain, respectively. The calculated thermopower is large and comparable to some of the best thermoelectric materials. A comparison among the feasibility of these three types of strain is also discussed.

High-resolution depth profile of the InGaP-on-GaAs heterointerface by FE-AES and its relationship to device properties

NASA Astrophysics Data System (ADS)

Ichikawa, O.; Fukuhara, N.; Hata, M.; Nakano, T.; Sugiyama, M.; Shimogaki, Y.; Nakano, Y.

2007-01-01

At InGaP-on-GaAs heterointerface, transition layer is formed during metalorganic vapor phase epitaxy (MOVPE) growth that can affect device properties. Many studies of this transition layer have been done but the characterization methods used are not direct measures of the atomic structure at the heterointerface. In this study, we investigated the abruptness and thickness of the InGaP-on-GaAs transition layers by field-emission Auger electron spectroscopy, by which a depth profile with a resolution of abruptness of 30 Å or below can be obtained. The group V switching position relative to that of In goes deeper into the GaAs with increasing PH 3 supply, suggesting an initial, quick replacement of As atoms with P atoms followed by a slow P diffusion into the bulk GaAs. Changes of abruptness of the As or P profiles at the heterointerface with varying PH 3 supply on the GaAs surface are not observed. Furthermore, we evaluated the effect of the GaAsP-like transition layers on the turn-on voltage of an InGaP emitter HBT. A linear relationship is shown between the shift of the group V switching position and the HBT turn-on voltage, which is consistent with the assumption that current flow decreases at the transition layer. Calculated difference of conduction band energy between InGaP and the transition layer is 0.15 eV for the sample with ordered InGaP and 0.04 eV for disordered InGaP, is consistent with the difference of the band gap energies between ordered and disordered InGaP. Calculated P compositions are 0.52 and 0.35, respectively.

In-Flight Boundary-Layer Transition on a Large Flat Plate at Supersonic Speeds

NASA Technical Reports Server (NTRS)

Banks, Daniel W.; Fredericks, Michael Alan; Tracy, Richard R.; Matisheck, Jason R.; Vanecek, Neal D.

2012-01-01

A flight experiment was conducted to investigate the pressure distribution, local flow conditions, and boundary-layer transition characteristics on a large flat plate in flight at supersonic speeds up to Mach 2.0. The primary objective of the test was to characterize the local flow field in preparation for future tests of a high Reynolds number natural laminar flow test article. The tests used a F-15B testbed aircraft with a bottom centerline mounted test fixture. A second objective was to determine the boundary-layer transition characteristics on the flat plate and the effectiveness of using a simplified surface coating for future laminar flow flight tests employing infrared thermography. Boundary-layer transition was captured using an onboard infrared imaging system. The infrared imagery was captured in both analog and digital formats. Surface pressures were measured with electronically scanned pressure modules connected to 60 surface-mounted pressure orifices. The local flow field was measured with five 5-hole conical probes mounted near the leading edge of the test fixture. Flow field measurements revealed the local flow characteristics including downwash, sidewash, and local Mach number. Results also indicated that the simplified surface coating did not provide sufficient insulation from the metallic structure, which likely had a substantial effect on boundary-layer transition compared with that of an adiabatic surface. Cold wall conditions were predominant during the acceleration to maximum Mach number, and warm wall conditions were evident during the subsequent deceleration. The infrared imaging system was able to capture shock wave impingement on the surface of the flat plate in addition to indicating laminar-to-turbulent boundary-layer transition.

Measured Boundary Layer Transition and Rotor Hover Performance at Model Scale

NASA Technical Reports Server (NTRS)

Overmeyer, Austin D.; Martin, Preston B.

2017-01-01

An experiment involving a Mach-scaled, 11:08 f t: diameter rotor was performed in hover during the summer of 2016 at NASA Langley Research Center. The experiment investigated the hover performance as a function of the laminar to turbulent transition state of the boundary layer, including both natural and fixed transition cases. The boundary layer transition locations were measured on both the upper and lower aerodynamic surfaces simultaneously. The measurements were enabled by recent advances in infrared sensor sensitivity and stability. The infrared thermography measurement technique was enhanced by a paintable blade surface heater, as well as a new high-sensitivity long wave infrared camera. The measured transition locations showed extensive amounts, x=c>0:90, of laminar flow on the lower surface at moderate to high thrust (CT=s > 0:068) for the full blade radius. The upper surface showed large amounts, x=c > 0:50, of laminar flow at the blade tip for low thrust (CT=s < 0:045). The objective of this paper is to provide an experimental data set for comparisons to newly developed and implemented rotor boundary layer transition models in CFD and rotor design tools. The data is expected to be used as part of the AIAA Rotorcraft SimulationWorking Group

Diffractive Hyperbola of a Skin Layer

NASA Astrophysics Data System (ADS)

Yakubov, V. P.; Vaiman, E. V.; Shipilov, S. È.; Prasath, A. K.

2018-03-01

Based on an analysis of physics of the phase transition from the quasistatic state field to the running wave field of elementary electric and magnetic dipoles located in absorbing media, it is concluded that the skin layer is formed at the boundary of this phase transition. The possibility is considered of obtaining the diffractive hyperbola of the skin layer and its subsequent application for sensing of objects in strongly absorbing media.

The influence of flow parameters on the transition to turbulence in supersonic boundary layer on swept wing

NASA Astrophysics Data System (ADS)

Semionov, N. V.; Yermolaev, Yu. G.; Kosinov, A. D.; Dryasov, A. D.; Semenov, A. N.; Yatskikh, A. A.

2016-10-01

The paper is devoted to an experimental study of laminar-turbulent transition in a three-dimensional supersonic boundary layer. The experiments were conducted at the low nose supersonic wind tunnel T-325 of ITAM at Mach numbers M=2 - 4. Model is a symmetrical wing with a 45° sweep angle, a 3 percent-thick circular-arc airfoil. The influence of flow parameters, such as the Mach number, unit Reynolds number, angle of attack, level of perturbations on the transitions to turbulence are on the consideration. Transition Reynolds numbers are obtained. Analysis of all obtained data allow to determine reliable value of Retr of swept wing supersonic boundary layer, that especially important at consideration of experiments fulfilled at different flow conditions in different wind tunnels.

Entropically Driven Layering Near a Substrate: A Fluids DFT Study

NASA Astrophysics Data System (ADS)

McGarrity, Erin; Frischknecht, Amalie; Mackay, Michael

2008-03-01

We employ a fluids density functional theory to study the phase behavior of athermal polymer/nanoparticle blends near a hard substrate. These blends exhibit two types of first order, entropically driven layering transitions. In the first type of transition, the nanoparticles order to form a layer which is a fixed distance from the surface. The structure and location of this layer depends on nanoparticle radius. In the second type of transition, which occurs at melt-like densities, the nanoparticles and polymers form laminar structures which resemble colloidal crystals. We examine the effects of packing density, chain length and nanoparticle radius on the system and show that the transitions are first order. In addition we show that the crystalline phase is nucleated by the presence of the surface. Sandia is a multiprogram laboratory operated by Sandia Corporation, a Lockheed Martin Company, for the United States Department of Energy's National Nuclear Security Administration under contract DE-AC04-94AL85000.

Experimental investigations on characteristics of boundary layer and control of transition on an airfoil by AC-DBD

NASA Astrophysics Data System (ADS)

Geng, Xi; Shi, Zhiwei; Cheng, Keming; Dong, Hao; Zhao, Qun; Chen, Sinuo

2018-03-01

Plasma-based flow control is one of the most promising techniques for aerodynamic problems, such as delaying the boundary layer transition. The boundary layer’s characteristics induced by AC-DBD plasma actuators and applied by the actuators to delay the boundary layer transition on airfoil at Ma = 0.3 were experimentally investigated. The PIV measurement was used to study the boundary layer’s characteristics induced by the plasma actuators. The measurement plane, which was parallel to the surface of the actuators and 1 mm above the surface, was involved in the test, including the perpendicular plane. The instantaneous results showed that the induced flow field consisted of many small size unsteady vortices which were eliminated by the time average. The subsequent oil-film interferometry skin friction measurement was conducted on a NASA SC(2)-0712 airfoil at Ma = 0.3. The coefficient of skin friction demonstrates that the plasma actuators successfully delay the boundary layer transition and the efficiency is better at higher driven voltage.

Boundary Layer Transition Correlations and Aeroheating Predictions for Mars Smart Lander

NASA Technical Reports Server (NTRS)

Hollis, Brian R.; Liechty, Derek S.

2002-01-01

Laminar and turbulent perfect-gas air, Navier-Stokes computations have been performed for a proposed Mars Smart Lander entry vehicle at Mach 6 over a free stream Reynolds number range of 6.9 x 10(exp 6)/m to 2.4 x 10(exp 7)/m (2.1 x 10(exp 6)/ft to 7.3 x 10(exp 6)/ft) for angles-of-attack of 0-deg, 11-deg, 16-deg, and 20-deg, and comparisons were made to wind tunnel heating data obtained a t the same conditions. Boundary layer edge properties were extracted from the solutions and used to correlate experimental data on the effects of heat-shield penetrations (bolt-holes where the entry vehicle would be attached to the propulsion module during transit to Mars) on boundary-layer transition. A non-equilibrium Martian-atmosphere computation was performed for the peak heating point on the entry trajectory in order to determine if the penetrations would produce boundary-layer transition by using this correlation.

Boundary Layer Transition Correlations and Aeroheating Predictions for Mars Smart Lander

NASA Technical Reports Server (NTRS)

Hollis, Brian R.; Liechty, Derek S.

2002-01-01

Laminar and turbulent perfect-gas air, Navier-Stokes computations have been performed for a proposed Mars Smart Lander entry vehicle at Mach 6 over a free stream Reynolds number range of 6.9 x 10(exp 6/m to 2.4 x 10(exp 7)m(2.1 x 10(exp 6)/ft to 7.3 x 10(exp 6)ft) for angles-of-attack of 0-deg, 11-deg, 16-deg, and 20-deg, and comparisons were made to wind tunnel heating data obtained at the same conditions. Boundary layer edge properties were extracted from the solutions and used to correlate experimental data on the effects of heat-shield penetrations (bolt-holes where the entry vehicle would be attached to the propulsion module during transit to Mars) on boundary-layer transition. A non-equilibrium Martian-atmosphere computation was performed for the peak heating point on the entry trajectory in order to determine if the penetrations would produce boundary-layer transition by using this correlation.

An Experimental Investigation of Wall-Cooling Effects on Hypersonic Boundary-Layer Stability in a Quiet Wind Tunnel

NASA Technical Reports Server (NTRS)

Blanchard, Alan E.; Selby, Gregory V.

1996-01-01

One of the primary reasons for developing quiet tunnels is for the investigation of high-speed boundary-layer stability and transition phenomena without the transition-promoting effects of acoustic radiation from tunnel walls. In this experiment, a flared-cone model under adiabatic- and cooled-wall conditions was placed in a calibrated, 'quiet' Mach 6 flow and the stability of the boundary layer was investigated using a prototype constant-voltage anemometer. The results were compared with linear-stability theory predictions and good agreement was found in the prediction of second-mode frequencies and growth. In addition, the same 'N=10' criterion used to predict boundary-layer transition in subsonic, transonic, and supersonic flows was found to be applicable for the hypersonic flow regime as well. Under cooled-wall conditions, a unique set of continuous spectra data was acquired that documents the linear, nonlinear, and breakdown regions associated with the transition of hypersonic flow under low-noise conditions.

Assessing Uncertainties in Boundary Layer Transition Predictions for HIFiRE-1 at Non-zero Angles of Attack

NASA Technical Reports Server (NTRS)

Marek, Lindsay C.

2011-01-01

Boundary layer stability was analyzed for the HIFiRE-1 flight vehicle geometry for ground tests conducted at the CUBRC LENS I hypersonic shock test facility and the Langley Research Center (LaRC) 20- inch Mach 6 Tunnel. Boundary layer stability results were compared to transition onset location obtained from discrete heat transfer measurements from thin film gauges during the CUBRC test and spatially continuous heat transfer measurements from thermal phosphor paint data during the LaRC test. The focus of this analysis was on conditions at non-zero angles of attack as stability analysis has already been performed at zero degrees angle of attack. Also, the transition onset data obtained during flight testing was at nonzero angles of attack, so this analysis could be expanded in the future to include the results of the flight test data. Stability analysis was performed using the 2D parabolized stability software suite STABL (Stability and Transition Analysis for Hypersonic Boundary Layers) developed at the University of Minnesota and the mean flow solutions were computed using the DPLR finite volume Navier-Stokes computational fluid dynamics (CFD) solver. A center line slice of the 3D mean flow solution was used for the stability analysis to incorporate the angle of attack effects while still taking advantage of the 2D STABL software suite. The N-factors at transition onset and the value of Re(sub theta)/M(sub e), commonly used to predict boundary layer transition onset, were compared for all conditions analyzed. Ground test data was analyzed at Mach 7.2 and Mach 6.0 and angles of attack of 1deg, 3deg and 5deg. At these conditions, the flow was found to be second mode dominant for the HIFiRE-1 slender cone geometry. On the leeward side of the vehicle, a strong trend of transition onset location with angle of attack was observed as the boundary layer on the leeward side of the vehicle developed inflection points at streamwise positions on the vehicle that correlated to angle of attack. Inflection points are a strong instability mechanism that lead to rapid breakdown and transition to turbulence. The transition onset location on the windward side of the vehicle displayed no trend with angle of attack or freestream Reynolds number and transition was observed farther down the vehicle than observed on the leeward side of the vehicle. In analysis of both windward and leeward sides of the vehicle, use of the N factor methodology to develop trends to predict boundary layer transition onset showed improvements over the Re(sub theta)/M(sub e) empirical correlation methodology. Stronger correlations and less scatter in the data were observed when using the N factor method for these cases.

Layered transition metal carboxylates: efficient reusable heterogeneous catalyst for epoxidation of olefins.

PubMed

Sen, Rupam; Bhunia, Susmita; Mal, Dasarath; Koner, Subratanath; Miyashita, Yoshitaro; Okamoto, Ken-Ichi

2009-12-01

Layered metal carboxylates [M(malonato)(H(2)O)(2)](n) (M = Ni(II) and Mn(II)) that have a claylike structure have been synthesized hydrothermally and characterized. The interlayer separation in these layered carboxylates is comparable to that of the intercalation distance of the naturally occurring clay materials or layered double hydroxides (LDHs). In this study, we have demonstrated that, instead of intercalating the metal complex into layers of the clay or LDH, layered transition metal carboxylates, [M(malonato)(H(2)O)(2)](n), as such can be used as a recyclable heterogeneous catalyst in olefin epoxidation reaction. Metal carboxylates [M(malonato)(H(2)O)(2)](n) exhibit excellent catalytic performance in olefin epoxidation reaction.

Experimental study of 2-layer regenerators using Mn-Fe-Si-P materials

NASA Astrophysics Data System (ADS)

Christiaanse, T. V.; Trevizoli, P. V.; Misra, Sumohan; Carroll, Colman; van Asten, David; Zhang, Lian; Teyber, R.; Govindappa, P.; Niknia, I.; Rowe, A.

2018-03-01

This work describes an experimental study of a two layer active magnetic regenerator with varying transition temperature spacing. The transition temperature of the materials is based on the specific heat peak of the materials. A transition temperature based on the average of the heating and cooling curves at zero Tesla field value is used to refer to the materials throughout this paper. This study uses five Mn-Fe-Si-P materials with transition temperatures of 294.6 K, 292.3 K, 290.7 K, 282.5 K and 281.4 K. Six different regenerators are tested. A reference configuration is tested using the 294.6 K material a hot side layer and with a second passive layer of lead spheres as cold side layer. Followed by four configurations that use the same 294.6 K material as hot side layer, but where each configuration uses a different cold side material. For the second active layer the materials are used in sequence; 292.3 K, 290.7 K, 282.5 K and 281.4K. Lastly, a sixth configuration uses the 292.3 K and 282.5 K materials. For each configuration, the temperature span is measured for rejection temperatures from 40 °C to 9 °C and at 0 W and 2 W applied load. Experimental results for temperature span and exergetic cooling power are compared based on the differences from the reference configuration. Materials are analysed based on material performance metrics such as peak adiabatic temperature change, peak entropy change and RCP(s) values. For the cases considered, a closer transition temperature spacing generally gives a greater temperature span and exergetic cooling power than further spaced materials, even when the combined materials have comparatively lower performance metrics. When two materials with higher RCP(s) values with large transition temperature spacing are compared to materials with lower RCP(s) values but, closer transition temperature spacing a higher exergetic cooling power and temperature span is found for the latter.

Bypass transition in compressible boundary layers

NASA Technical Reports Server (NTRS)

Vandervegt, J. J.

1992-01-01

Transition to turbulence in aerospace applications usually occurs in a strongly disturbed environment. For instance, the effects of free-stream turbulence, roughness and obstacles in the boundary layer strongly influence transition. Proper understanding of the mechanisms leading to transition is crucial in the design of aircraft wings and gas turbine blades, because lift, drag and heat transfer strongly depend on the state of the boundary layer, laminar or turbulent. Unfortunately, most of the transition research, both theoretical and experimental, has focused on natural transition. Many practical flows, however, defy any theoretical analysis and are extremely difficult to measure. Morkovin introduced in his review paper the concept of bypass transition as those forms of transition which bypass the known mechanisms of linear and non-linear transition theories and are currently not understood by experiments. In an effort to better understand the mechanisms leading to transition in a disturbed environment, experiments are conducted studying simpler cases, viz. the effects of free stream turbulence on transition on a flat plate. It turns out that these experiments are very difficult to conduct, because generation of free stream turbulence with sufficiently high fluctuation levels and reasonable homogeneity is non trivial. For a discussion see Morkovin. Serious problems also appear due to the fact that at high Reynolds numbers the boundary layers are very thin, especially in the nose region of the plate where the transition occurs, which makes the use of very small probes necessary. The effects of free-stream turbulence on transition are the subject of this research and are especially important in a gas turbine environment, where turbulence intensities are measured between 5 and 20 percent, Wang et al. Due to the fact that the Reynolds number for turbine blades is considerably lower than for aircraft wings, generally a larger portion of the blade will be in a laminar transitional state. The effects of large free stream turbulence in compressible boundary layers at Mach numbers are examined both in the subsonic and transonic regime using direct numerical simulations. The flow is computed over a flat plate and curved surface. while many applications operate in the transonic regime. Due the nature of their numerical scheme, a non-conservation formulation of the Navier-Stokes equations, it is a non-trivial extension to compute flow fields in the transonic regime. This project aims at better understanding the effects of large free-stream turbulence in compressible boundary layers at mach number both in the subsonic and transonic regime using direct numerical simulations. The present project aims at computing the flow over a flat plate and curved surface. This research will provide data which can be used to clarify mechanisms leading to transition in an environment with high free stream turbulence. This information is useful for the development of turbulence models, which are of great importance for CFD applications, and are currently unreliable for more complex flows, such as transitional flows.

Fluid Mechanics and Heat Transfer in Transitional Boundary Layers

NASA Technical Reports Server (NTRS)

Wang, Ting

2007-01-01

Experiments have been performed to investigate the effects of elevated free-stream turbulence and streamwise acceleration on flow and thermal structures in transitional boundary layers. The free-stream turbulence ranges from 0.5 to 6.4% and the streamwise acceleration ranges from K = 0 to 0.8 x 10(exp -6). The onset of transition, transition length and the turbulent spot formation rate are determined. The statistical results and conditionally sampled results of th streamwise and cross-stream velocity fluctuations, temperature fluctuations, Reynolds stress and Reynolds heat fluxes are presented.

Electrochromic device containing metal oxide nanoparticles and ultraviolet blocking material

DOE Office of Scientific and Technical Information (OSTI.GOV)

Garcia, Guillermo; Koo, Bonil; Gregoratto, Ivano

An electrochromic device includes a nanostructured transition metal oxide bronze layer that includes one or more transition metal oxide and one or more dopant. The electrochromic device also includes nanoparticles containing one or more transparent conducting oxide (TCO), a solid state electrolyte, a counter electrode, and at least one protective layer to prevent degradation of the one or more nanostructured transition metal oxide bronze. The nanostructured transition metal oxide bronze selectively modulates transmittance of near-infrared (NIR) and visible radiation as a function of an applied voltage to the device.

Influence of a heated leading edge on boundary layer growth, stability, and transition

DOE Office of Scientific and Technical Information (OSTI.GOV)

Landrum, D.B.; Macha, J.M.

1987-06-01

This paper presents the results of a combined theoretical and experimental study of the influence of a heated leading edge on the growth, stability, and transition of a two-dimensional boundary layer. The findings are directly applicable to aircraft wings and nacelles that use surface heating for anti-icing protection. The potential effects of the non-adiabatic condition are particularly important for laminar-flow sections where even small perturbations can result in significantly degraded aerodynamic performance. The results of the study give new insight to the fundamental coupling between streamwise pressure gradient and surface heat flux in laminar and transitional boundary layers. 13 references.

Influence of a heated leading edge on boundary layer growth, stability, and transition

DOE Office of Scientific and Technical Information (OSTI.GOV)

Landrum, D.B.; Macha, J.M.

1987-01-01

This paper presents the results of a combined theoretical and experimental study of the influence of a heated leading edge on the growth, stability, and transition of a two-dimensional boundary layer. The findings are directly applicable to aircraft wings and nacelles that use surface heating for anti-icing protection. The potential effects of the non-adiabatic condition are particularly important for laminar-flow sections where even small perturbations can result in significantly degraded aerodynamic performance. The results of the study give new insight to the fundamental coupling between streamwise pressure gradient and surface heat flux in laminar and transitional boundary layers.

Magnetic layering transitions in a polyamidoamine (PAMAM) dendrimer nano-structure: Monte Carlo study

NASA Astrophysics Data System (ADS)

Ziti, S.; Aouini, S.; Labrim, H.; Bahmad, L.

2017-02-01

We study the magnetic layering transitions in a polyamidoamine (PAMAM) dendrimer nano-structure, under the effect of an external magnetic field. We examine the magnetic properties, of this model of the spin S=1 Ising ferromagnetic in real nanostructure used in several scientific domains. For T=0, we give and discuss the ground state phase diagrams. At non null temperatures, we applied the Monte Carlo simulations giving important results summarized in the form of the phase diagrams. We also analyzed the effect of varying the external magnetic field, and found the layering transitions in the polyamidoamine (PAMAM) dendrimer nano-structure.

Observations of the Morning Development of the Urban Boundary Layer Over London, UK, Taken During the ACTUAL Project

NASA Astrophysics Data System (ADS)

Halios, Christos H.; Barlow, Janet F.

2018-03-01

The study of the boundary layer can be most difficult when it is in transition and forced by a complex surface, such as an urban area. Here, a novel combination of ground-based remote sensing and in situ instrumentation in central London, UK, is deployed, aiming to capture the full evolution of the urban boundary layer (UBL) from night-time until the fully-developed convective phase. In contrast with the night-time stable boundary layer observed over rural areas, the night-time UBL is weakly convective. Therefore, a new approach for the detection of the morning-transition and rapid-growth phases is introduced, based on the sharp, quasi-linear increase of the mixing height. The urban morning-transition phase varied in duration between 0.5 and 4 h and the growth rate of the mixing layer during the rapid-growth phase had a strong positive relationship with the convective velocity scale, and a weaker, negative relationship with wind speed. Wind shear was found to be higher during the night-time and morning-transition phases than the rapid-growth phase and the shear production of turbulent kinetic energy near the mixing-layer top was around six times larger than surface shear production in summer, and around 1.5 times larger in winter. In summer under low winds, low-level jets dominated the UBL, and shear production was greater than buoyant production during the night-time and the morning-transition phase near the mixing-layer top. Within the rapid-growth phase, buoyant production dominated at the surface, but shear production dominated in the upper half of the UBL. These results imply that regional flows such as low-level jets play an important role alongside surface forcing in determining UBL structure and growth.

Coherently Coupled ZnO and VO2 Interface studied by Photoluminescence and electrical transport across a phase transition

NASA Astrophysics Data System (ADS)

Srivastava, Amar; Saha, S.; Annadi, A.; Zhao, Y. L.; Gopinadhan, K.; Wang, X.; Naomi, N.; Liu, Z. Q.; Dhar, S.; Herng, T. S.; Nina, Bao; Ariando, -; Ding, Jun; Venkatesan, T.

2012-02-01

In this work we report a study of a coherently coupled interface consisting of a ZnO layer grown on top of an oriented VO2 layer on sapphire by photoluminescence and electrical transport measurements across the VO2 metal insulator phase transition (MIT). The photoluminescence of the ZnO layer showed a broad hysteresis induced by the phase transition of VO2 while the width of the electrical hysteresis was narrow and unaffected by the over layer. The enhanced width of the PL hysteresis was due to the formation of defects during the MIT as evidenced by a broad hysteresis in the opposite direction to that of the band edge PL in the defect luminescense. Unlike VO2 the defects in ZnO did not fully recover across the phase transition. From the defect luminescence data, oxygen interstitials were found to be the predominant defects in ZnO mediated by the strain from the VO2 phase transition. Such coherently coupled interfaces could be of use in characterizing the stability of a variety of interfaces and also for novel device application.

On the Relationship between Transitional and Fully Turbulent Shear Flow.

DTIC Science & Technology

1982-05-01

the spot a single large coherent eddy on which mall scale turbulence is superimposed or is it an assembly of eddies, both large and mall ...laminar boundary layer. These finds provided the first link between stability theory and the actual spreading of turbu- lence. We expected the...findings of the transitional spot and its re- lation to the transition process in boundary layers flow were drawn togeth- er into an organized theory

Initial Conceptualization and Application of the Alaska Thermokarst Model

NASA Astrophysics Data System (ADS)

Bolton, W. R.; Lara, M. J.; Genet, H.; Romanovsky, V. E.; McGuire, A. D.

2015-12-01

Thermokarst topography forms whenever ice-rich permafrost thaws and the ground subsides due to the volume loss when ground ice transitions to water. The Alaska Thermokarst Model (ATM) is a large-scale, state-and-transition model designed to simulate transitions between landscape units affected by thermokarst disturbance. The ATM uses a frame-based methodology to track transitions and proportion of cohorts within a 1-km2 grid cell. In the arctic tundra environment, the ATM tracks thermokarst-related transitions among wetland tundra, graminoid tundra, shrub tundra, and thermokarst lakes. In the boreal forest environment, the ATM tracks transitions among forested permafrost plateau, thermokarst lakes, collapse scar fens and bogs. The transition from one cohort to another due to thermokarst processes can take place if thaw reaches ice-rich ground layers either due to pulse disturbance (i.e. large precipitation event or fires), or due to gradual active layer deepening that eventually results in penetration of the protective layer. The protective layer buffers the ice-rich soils from the land surface and is critical to determine how susceptible an area is to thermokarst degradation. The rate of terrain transition in our model is determined by a set of rules that are based upon the ice-content of the soil, the drainage efficiency (or the ability of the landscape to store or transport water), the cumulative probability of thermokarst initiation, distance from rivers, lake dynamics (increasing, decreasing, or stable), and other factors. Tundra types are allowed to transition from one type to another (for example, wetland tundra to graminoid tundra) under favorable climatic conditions. In this study, we present our conceptualization and initial simulation results from in the arctic (the Barrow Peninsula) and boreal (the Tanana Flats) regions of Alaska.

Reflective article having a sacrificial cathodic layer

DOE Office of Scientific and Technical Information (OSTI.GOV)

Kabagambe, Benjamin; Buchanan, Michael J.; Scott, Matthew S.

The present invention relates to reflective articles, such as solar mirrors, that include a sacrificial cathodic layer. The reflective article, more particularly includes a substrate, such as glass, having a multi-layered coating thereon that includes a lead-free sacrificial cathodic layer. The sacrificial cathodic layer includes at least one transition metal, such as a particulate transition metal, which can be in the form of flakes (e.g., zinc flakes). The sacrificial cathodic layer can include an inorganic matrix formed from one or more organo-titanates. Alternatively, the sacrificial cathodic layer can include an organic polymer matrix (e.g., a crosslinked organic polymer matrix formedmore » from an organic polymer and an aminoplast crosslinking agent). The reflective article also includes an outer organic polymer coating, that can be electrodeposited over the sacrificial cathodic layer.« less

Highly improved passivation of c-Si surfaces using a gradient i a-Si:H layer

NASA Astrophysics Data System (ADS)

Lee, Soonil; Ahn, Jaehyun; Mathew, Leo; Rao, Rajesh; Zhang, Zhongjian; Kim, Jae Hyun; Banerjee, Sanjay K.; Yu, Edward T.

2018-04-01

Surface passivation using intrinsic a-Si:H (i a-Si:H) films plays a key role in high efficiency c-Si heterojunction solar cells. In this study, we demonstrate improved passivation quality using i a-Si:H films with a gradient-layered structure consisting of interfacial, transition, and capping layers deposited on c-Si surfaces. The H2 dilution ratio (R) during deposition was optimized individually for the interfacial and capping layers, which were separated by a transition layer for which R changed gradually between its values for the interfacial and capping layers. This approach yielded a significant reduction in surface carrier recombination, resulting in improvement of the minority carrier lifetime from 1480 μs for mono-layered i a-Si:H passivation to 2550 μs for the gradient-layered passivation approach.

Detection of boundary-layer transitions in wind tunnels

NASA Technical Reports Server (NTRS)

Wood, W. R.; Somers, D. M.

1978-01-01

Accelerometer replaces stethoscope in technique for detection of laminar-to-turbulent boundary-layer transitions on wind-tunnel models. Technique allows measurements above or below atmospheric pressure because human operator is not required within tunnel. Data may be taken from accelerometer, and pressure transducer simultaneously, and delivered to systems for analysis.

Boundary-layer transition on cones at angle of attack in a Mach-6 Quiet Tunnel

NASA Astrophysics Data System (ADS)

Swanson, Erick O.

It is desirable for the boundary layer on a re-entry vehicle (RV) to be laminar during as much of its flight as possible, since a turbulent boundary layer causes several problems, such as high heat flux to the vehicle and larger drag forces. Nosetip roughness can cause the boundary layer to transition downstream on the cone. Surface roughness and nosetip bluntness may cause windside-forward transition on maneuvering RVs. The crossflow instability may also influence transition on yawed RVs. The mechanisms through which these phenomena induce transition are poorly understood. Several experiments have been conducted to study these phenomena. The temperature-sensitive-paint (TSP) and oil-flow techniques were used to observe transition and crossflow vortices on cones at angle of attack in the Purdue Boeing/AFOSR Mach-6 Quiet Tunnel. The high-Reynolds number capability of the tunnel was developed to facilitate these experiments. Improvements were made in the use of the temperature-sensitive-paint technique in the Purdue Mach-6 Quiet Tunnel. The measured heat transfer to cones with sharp and spherically-blunt nosetips at 0° angle-of-attack was within 60% of the values from Navier-Stokes computations. Transition was observed on sharp and spherically-blunt cones at 6° angle-of-attack in noisy flow. Crossflow vortices were observed with both TSP and oil flow under noisy conditions in the turbulent boundary layer on a sharp cone. The vortex angles were about 50% of the surface-streamline angles observed using oil dots. TSP was also used to observe crossflow vortices in quiet flow. The vortices were similar to those seen in noisy flow. An array of roughness elements at x = 2 inches (axially) with a spacing of 9° on a yawed sharp cone in noisy flow influenced transition that was apparently induced by the crossflow instability. No influence of the roughness array was observed in quiet flow.

Design optimization of natural laminar flow bodies in compressible flow

NASA Technical Reports Server (NTRS)

Dodbele, Simha S.

1992-01-01

An optimization method has been developed to design axisymmetric body shapes such as fuselages, nacelles, and external fuel tanks with increased transition Reynolds numbers in subsonic compressible flow. The new design method involves a constraint minimization procedure coupled with analysis of the inviscid and viscous flow regions and linear stability analysis of the compressible boundary-layer. In order to reduce the computer time, Granville's transition criterion is used to predict boundary-layer transition and to calculate the gradients of the objective function, and linear stability theory coupled with the e(exp n)-method is used to calculate the objective function at the end of each design iteration. Use of a method to design an axisymmetric body with extensive natural laminar flow is illustrated through the design of a tiptank of a business jet. For the original tiptank, boundary layer transition is predicted to occur at a transition Reynolds number of 6.04 x 10(exp 6). For the designed body shape, a transition Reynolds number of 7.22 x 10(exp 6) is predicted using compressible linear stability theory coupled with the e(exp n)-method.

Characterization of structural response to hypersonic boundary-layer transition

DOE PAGES

Riley, Zachary B.; Deshmukh, Rohit; Miller, Brent A.; ...

2016-05-24

The inherent relationship between boundary-layer stability, aerodynamic heating, and surface conditions makes the potential for interaction between the structural response and boundary-layer transition an important and challenging area of study in high-speed flows. This paper phenomenologically explores this interaction using a fundamental two-dimensional aerothermoelastic model under the assumption of an aluminum panel with simple supports. Specifically, an existing model is extended to examine the impact of transition onset location, transition length, and transitional overshoot in heat flux and fluctuating pressure on the structural response of surface panels. Transitional flow conditions are found to yield significantly increased thermal gradients, and theymore » can result in higher maximum panel temperatures compared to turbulent flow. Results indicate that overshoot in heat flux and fluctuating pressure reduces the flutter onset time and increases the strain energy accumulated in the panel. Furthermore, overshoot occurring near the midchord can yield average temperatures and peak displacements exceeding those experienced by the panel subject to turbulent flow. Lastly, these results suggest that fully turbulent flow does not always conservatively predict the thermo-structural response of surface panels.« less

Butt Welding of 2205/X65 Bimetallic Sheet and Study on the Inhomogeneity of the Properties of the Welded Joint

NASA Astrophysics Data System (ADS)

Gou, Ning-Nian; Zhang, Jian-Xun; Wang, Jian-Long; Bi, Zong-Yue

2017-04-01

The explosively welded 2205 duplex stainless steel/X65 pipe steel bimetallic sheets were butt jointed by multilayer and multi-pass welding (gas tungsten arc welding for the flyer and gas metal arc welding for the transition and parent layers of the bimetallic sheets). The microstructure and mechanical properties of the welded joint were investigated. The results showed that in the thickness direction, microstructure and mechanical properties of the welded joint exhibited obvious inhomogeneity. The microstructures of parent filler layers consisted of acicular ferrite, widmanstatten ferrite, and a small amount of blocky ferrite. The microstructure of the transition layer and flyer layer consisted of both austenite and ferrite structures; however, the transition layer of weld had a higher volume fraction of austenite. The results of the microhardness test showed that in both weld metal (WM) and heat-affected zone (HAZ) of the parent filler layers, the average hardness decreased with the increasing (from parent filler layer 1 to parent filler layer 3) welding heat input. The results of hardness test also indicated that the hardness of the WM and the HAZ for the flyer and transition layers was equivalent. The tensile test combined with Digital Specklegram Processing Technology demonstrated that the fracturing of the welded joint started at the HAZ of the flyer, and then the fracture grew toward the base metal of the parent flyer near the parent HAZ. The stratified impact test at -5 °C showed that the WM and HAZ of the flyer exhibited lower impact toughness, and the fracture mode was ductile and brittle mixed fracture.

Bulk Kosterlitz-Thouless Type Molecular Superconductor β″-(BEDT-TTF)2[(H2O)(NH4)2Cr(C2O4)3]·18-crown-6.

PubMed

Martin, Lee; Lopez, Jordan R; Akutsu, Hiroki; Nakazawa, Yasuhiro; Imajo, Shusaku

2017-11-20

A new molecular superconductor, β″-(BEDT-TTF) 2 [(H 2 O)(NH 4 ) 2 Cr(C 2 O 4 ) 3 ]·18-crown-6, has been synthesized from the organic donor molecule BEDT-TTF with the anion Cr(C 2 O 4 ) 3 3- . The crystal structure consists of conducting organic layers of BEDT-TTF molecules which adopt the β″ packing motif (layer A), layers of NH 4 + and Λ-Cr(C 2 O 4 ) 3 3- (layer B), layers of (H 2 O)(NH 4 )18-crown-6 (layer C), and layers of NH 4 + and Δ-Cr(C 2 O 4 ) 3 3- (layer D) which produce a superstructure with a repeating pattern of ABCDABCDA. As a result of this packing arrangement, this is the 2D superconductor with the widest gap between conducting layers where only a single donor packing motif is present (β″). Superconducting critical temperatures at ambient pressure observed by electrical transport and magnetic measurements are 4.0-4.9 and 2.5 K, respectively. The strong 2D nature of this system, the broad transition to T zero at 1.8K, and the transition of α of V ∝ I α from 1 to 3 on I-V curves strongly suggest that the superconducting transition is very close to a Kosterlitz-Thouless transition. The magnetic field dependence of the superconducting critical temperature parallel to the conducting plane gives an upper critical field μ 0 H c2∥ > 8 T, which is over the calculated Pauli-Clogston limit for this material.

Gas diffusion in and out of super-hydrophobic surface in transitional and turbulent boundary layers

NASA Astrophysics Data System (ADS)

Ling, Hangjian; Fu, Matthew; Hultmark, Marcus; Katz, Joseph

2017-11-01

The rate of gas diffusion in and out of a super-hydrophobic surface (SHS) located in boundary layers is investigated at varying Reynolds numbers and ambient pressures. The hierarchical SHS consists of nano-textured, 100 μm wide spanwise grooves. The boundary layers over the SHS under the Cassie-Baxter and Wenzel states as well as a smooth wall at same conditions are characterized by particle image velocimetry. The Reynolds number based on momentum thickness of the smooth wall, ReΘ0, ranges from 518 to 2088, covering transitional and turbulent boundary layer regimes. The mass diffusion rate is estimated by using microscopy to measure the time-evolution of plastron shape and volume. The data is used for calculating the Sherwood number based on smooth wall momentum thickness, ShΘ0. As expected, the diffusion rate increases linearly with the under- or super-saturation level, i.e., ShΘ0 is independent of ambient pressure. For the turbulent boundary layers, the data collapses onto ShΘ0 = 0.47ReΘ00.77 . For the transitional boundary layer, ShΘ0 is lower than the turbulent power law. When ShΘ0 is plotted against the friction Reynolds number (Reτ0) , both the transitional and turbulent boundary layer data collapse onto a single power law, ShΘ0 = 0.34Reτ00.913 . Results scaled based on Wenzel state momentum thickness show very similar trends. Sponsored by ONR.

DOE Office of Scientific and Technical Information (OSTI.GOV)

Anasori, Babak; Shi, Chenyang; Moon, Eun Ju

In this paper, a transition from metallic to semiconducting-like behavior has been demonstrated in two-dimensional (2D) transition metal carbides by replacing titanium with molybdenum in the outer transition metal (M) layers of M 3C 2 and M 4C 3 MXenes. The MXene structure consists of n + 1 layers of near-close packed M layers with C or N occupying the octahedral site between them in an [MX] nM arrangement. Recently, two new families of ordered 2D double transition metal carbides MXenes were discovered, M' 2M"C 2 and M' 2M" 2C 3 – where M' and M" are two different earlymore » transition metals, such as Mo, Cr, Ta, Nb, V, and Ti. The M' atoms only occupy the outer layers and the M" atoms fill the middle layers. In other words, M' atomic layers sandwich the middle M"–C layers. Using X-ray atomic pair distribution function (PDF) analysis on Mo 2TiC 2 and Mo 2Ti 2C 3 MXenes, we present the first quantitative analysis of structures of these novel materials and experimentally confirm that Mo atoms are in the outer layers of the [MC] nM structures. The electronic properties of these Mo-containing MXenes are compared with their Ti 3C 2 counterparts, and are found to be no longer metallic-like conductors; instead the resistance increases mildly with decreasing temperatures. Density functional theory (DFT) calculations suggest that OH terminated Mo–Ti MXenes are semiconductors with narrow band gaps. Measurements of the temperature dependencies of conductivities and magnetoresistances have confirmed that Mo 2TiC 2T x exhibits semiconductor-like transport behavior, while Ti 3C 2T x is a metal. Finally, this finding opens new avenues for the control of the electronic and optical applications of MXenes and for exploring new applications, in which semiconducting properties are required.« less

Observations of the Early Evening Boundary-Layer Transition Using a Small Unmanned Aerial System

NASA Astrophysics Data System (ADS)

Bonin, Timothy; Chilson, Phillip; Zielke, Brett; Fedorovich, Evgeni

2013-01-01

The evolution of the lower portion of the planetary boundary layer is investigated using the Small Multifunction Research and Teaching Sonde (SMARTSonde), an unmanned aerial vehicle developed at the University of Oklahoma. The study focuses on the lowest 200 m of the atmosphere, where the most noticeable thermodynamic changes occur during the day. Between October 2010 and February 2011, a series of flights was conducted during the evening hours on several days to examine the vertical structure of the lower boundary layer. Data from a nearby Oklahoma Mesonet tower was used to supplement the vertical profiles of temperature, humidity, and pressure, which were collected approximately every 30 min, starting 2 h before sunset and continuing until dusk. From the profiles, sensible and latent heat fluxes were estimated. These fluxes were used to diagnose the portion of the boundary layer that was most affected by the early evening transition. During the transition period, a shallow cool and moist layer near the ground was formed, and as the evening progressed the cooling affected an increasingly shallower layer just above the surface.

Hypersonic Boundary Layer Stability over a Flared Cone in a Quiet Tunnel

NASA Technical Reports Server (NTRS)

Lachowicz, Jason T.; Chokani, Ndaona; Wilkinson, Stephen P.

1996-01-01

Hypersonic boundary layer measurements were conducted over a flared cone in a quiet wind tunnel. The flared cone was tested at a freestream unit Reynolds number of 2.82x106/ft in a Mach 6 flow. This Reynolds number provided laminar-to-transitional flow over the model in a low-disturbance environment. Point measurements with a single hot wire using a novel constant voltage anemometry system were used to measure the boundary layer disturbances. Surface temperature and schlieren measurements were also conducted to characterize the laminar-to-transitional state of the boundary layer and to identify instability modes. Results suggest that the second mode disturbances were the most unstable and scaled with the boundary layer thickness. The integrated growth rates of the second mode compared well with linear stability theory in the linear stability regime. The second mode is responsible for transition onset despite the existence of a second mode sub-harmonic. The sub-harmonic wavelength also scales with the boundary layer thickness. Furthermore, the existence of higher harmonics of the fundamental suggests that non-linear disturbances are not associated with high free stream disturbance levels.

Performance limits of tunnel transistors based on mono-layer transition-metal dichalcogenides

DOE Office of Scientific and Technical Information (OSTI.GOV)

Jiang, Xiang-Wei, E-mail: xwjiang@semi.ac.cn; Li, Shu-Shen; Synergetic Innovation Center of Quantum Information and Quantum Physics, University of Science and Technology of China, Hefei, Anhui 230026

2014-05-12

Performance limits of tunnel field-effect transistors based on mono-layer transition metal dichalcogenides are investigated through numerical quantum mechanical simulations. The atomic mono-layer nature of the devices results in a much smaller natural length λ, leading to much larger electric field inside the tunneling diodes. As a result, the inter-band tunneling currents are found to be very high as long as ultra-thin high-k gate dielectric is possible. The highest on-state driving current is found to be close to 600 μA/μm at V{sub g} = V{sub d} = 0.5 V when 2 nm thin HfO{sub 2} layer is used for gate dielectric, outperforming most of the conventional semiconductor tunnelmore » transistors. In the five simulated transition-metal dichalcogenides, mono-layer WSe{sub 2} based tunnel field-effect transistor shows the best potential. Deep analysis reveals that there is plenty room to further enhance the device performance by either geometry, alloy, or strain engineering on these mono-layer materials.« less

New-class of Semiconducting 2D materials: Tin Dichalcogenides (SnX2)

NASA Astrophysics Data System (ADS)

Ataca, Can; Wu, Kedi; Saritas, Kayahan; Tongay, Sefaattin; Grossman, Jeffrey C.

2015-03-01

Recent studies have focused on a new generation of atomically thin films of semiconducting materials. A broad family of two-dimensional (2D) semiconducting transition metal dichalcogenides (MX2) have been fabricated and investigated in monolayer, bilayer and few layer form. In this work, we investigated the electronic, optical and elastic properties of single and few layer and bulk SnX2 (X = S, Se) both theoretically and experimentally. Using density functional theory (DFT) we carried out stability analysis through phonon and electronic, optical and elastic structure calculations. Single-few layer SnX2s are mechanically exfoliated and Raman and photoluminescence (PL) measurements are taken. UV-Vis absorption spectrum together with PL measurements and DFT calculations yield an indirect gap of ~ 2.5 eV for SnS2 structures (bulk). Tunability of the energy band gap and indirect-direct gap transitions are investigated by controlling the number of layers and applied stress. Lowering the number of layers decreases the indirect gap (0.1-0.3 eV), but indirect-direct gap transition occurs when layer-layer distance is reduced. Due to flexibility in engineering the electronic and optical properties, SnX2 compounds are promising materials for future optoelectronic nanoscale applications.

Transition Delay in Hypersonic Boundary Layers via Optimal Perturbations

NASA Technical Reports Server (NTRS)

Paredes, Pedro; Choudhari, Meelan M.; Li, Fei

2016-01-01

The effect of nonlinear optimal streaks on disturbance growth in a Mach 6 axisymmetric flow over a 7deg half-angle cone is investigated in an e ort to expand the range of available techniques for transition control. Plane-marching parabolized stability equations are used to characterize the boundary layer instability in the presence of azimuthally periodic streaks. The streaks are observed to stabilize nominally planar Mack mode instabilities, although oblique Mack mode disturbances are destabilized. Experimentally measured transition onset in the absence of any streaks correlates with an amplification factor of N = 6 for the planar Mack modes. For high enough streak amplitudes, the transition threshold of N = 6 is not reached by the Mack mode instabilities within the length of the cone, but subharmonic first mode instabilities, which are destabilized by the presence of the streaks, reach N = 6 near the end of the cone. These results suggest a passive flow control strategy of using micro vortex generators to induce streaks that would delay transition in hypersonic boundary layers.

Onset of two-dimensional superconductivity in space charge doped few-layer molybdenum disulfide

PubMed Central

Biscaras, Johan; Chen, Zhesheng; Paradisi, Andrea; Shukla, Abhay

2015-01-01

Atomically thin films of layered materials such as molybdenum disulfide (MoS2) are of growing interest for the study of phase transitions in two-dimensions through electrostatic doping. Electrostatic doping techniques giving access to high carrier densities are needed to achieve such phase transitions. Here we develop a method of electrostatic doping which allows us to reach a maximum n-doping density of 4 × 1014 cm−2 in few-layer MoS2 on glass substrates. With increasing carrier density we first induce an insulator to metal transition and subsequently an incomplete metal to superconductor transition in MoS2 with critical temperature ≈10 K. Contrary to earlier reports, after the onset of superconductivity, the superconducting transition temperature does not depend on the carrier density. Our doping method and the results we obtain in MoS2 for samples as thin as bilayers indicates the potential of this approach. PMID:26525386

Application of renormalization group theory to the large-eddy simulation of transitional boundary layers

NASA Technical Reports Server (NTRS)

Piomelli, Ugo; Zang, Thomas A.; Speziale, Charles G.; Lund, Thomas S.

1990-01-01

An eddy viscosity model based on the renormalization group theory of Yakhot and Orszag (1986) is applied to the large-eddy simulation of transition in a flat-plate boundary layer. The simulation predicts with satisfactory accuracy the mean velocity and Reynolds stress profiles, as well as the development of the important scales of motion. The evolution of the structures characteristic of the nonlinear stages of transition is also predicted reasonably well.

Boundary layer transition: A review of theory, experiment and related phenomena

NASA Technical Reports Server (NTRS)

Kistler, E. L.

1971-01-01

The overall problem of boundary layer flow transition is reviewed. Evidence indicates a need for new, basic physical hypotheses in classical fluid mechanics math models based on the Navier-Stokes equations. The Navier-Stokes equations are challenged as inadequate for the investigation of fluid transition, since they are based on several assumptions which should be expected to alter significantly the stability characteristics of the resulting math model. Strong prima facie evidence is presented to this effect.

Mechanical heating in the transition region

NASA Technical Reports Server (NTRS)

Withbroe, G.

1981-01-01

Attention is focused on the energy balance in the transition region and the role that mechanical heating plays in determining the temperature density structure of this region in a stellar atmosphere. Because of its role as the interface layer through which mass and energy flow between the chromospheres and corona, direct deposition of mechanical energy is a relatively unimportant factor in the overall energy balance in the transition region, except in the uppermost layers where the temperature approaches coronal values.

Multilayered thermal insulation formed of zirconia bonded layers of zirconia fibers and metal oxide fibers and method for making same

DOEpatents

Wrenn, Jr., George E.; Holcombe, Jr., Cressie E.

1988-01-01

A multilayered thermal insulating composite is formed of a first layer of zirconia-bonded zirconia fibers for utilization near the hot phase or surface of a furnace or the like. A second layer of zirconia-bonded metal oxide fibers is attached to the zirconia fiber layer by a transition layer formed of intermingled zirconia fibers and metal oxide fibers. The thermal insulation is fabricated by vacuum molding with the layers being sequentially applied from aqueous solutions containing the fibers to a configured mandrel. A portion of the solution containing the fibers forming the first layer is intermixed with the solution containing the fibers of the second layer for forming the layer of mixed fibers. The two layers of fibers joined together by the transition layer are saturated with a solution of zirconium oxynitrate which provides a zirconia matrix for the composite when the fibers are sintered together at their nexi.

Multilayered thermal insulation formed of zirconia bonded layers of zirconia fibers and metal oxide fibers and method for making same

DOEpatents

Wrenn, G.E. Jr.; Holcombe, C.E. Jr.

1988-09-13

A multilayered thermal insulating composite is formed of a first layer of zirconia-bonded zirconia fibers for utilization near the hot phase or surface of a furnace or the like. A second layer of zirconia-bonded metal oxide fibers is attached to the zirconia fiber layer by a transition layer formed of intermingled zirconia fibers and metal oxide fibers. The thermal insulation is fabricated by vacuum molding with the layers being sequentially applied from aqueous solutions containing the fibers to a configured mandrel. A portion of the solution containing the fibers forming the first layer is intermixed with the solution containing the fibers of the second layer for forming the layer of mixed fibers. The two layers of fibers joined together by the transition layer are saturated with a solution of zirconium oxynitrate which provides a zirconia matrix for the composite when the fibers are sintered together at their nexi.

Electric field-triggered metal-insulator transition resistive switching of bilayered multiphasic VOx

NASA Astrophysics Data System (ADS)

Won, Seokjae; Lee, Sang Yeon; Hwang, Jungyeon; Park, Jucheol; Seo, Hyungtak

2018-01-01

Electric field-triggered Mott transition of VO2 for next-generation memory devices with sharp and fast resistance-switching response is considered to be ideal but the formation of single-phase VO2 by common deposition techniques is very challenging. Here, VOx films with a VO2-dominant phase for a Mott transition-based metal-insulator transition (MIT) switching device were successfully fabricated by the combined process of RF magnetron sputtering of V metal and subsequent O2 annealing to form. By performing various material characterizations, including scanning transmission electron microscopy-electron energy loss spectroscopy, the film is determined to have a bilayer structure consisting of a VO2-rich bottom layer acting as the Mott transition switching layer and a V2O5/V2O3 mixed top layer acting as a control layer that suppresses any stray leakage current and improves cyclic performance. This bilayer structure enables excellent electric field-triggered Mott transition-based resistive switching of Pt-VOx-Pt metal-insulator-metal devices with a set/reset current ratio reaching 200, set/reset voltage of less than 2.5 V, and very stable DC cyclic switching upto 120 cycles with a great set/reset current and voltage distribution less than 5% of standard deviation at room temperature, which are specifications applicable for neuromorphic or memory device applications. [Figure not available: see fulltext.

Statistical mechanics study on wetting behaviors of Ne on Mg surface

NASA Astrophysics Data System (ADS)

Zhou, S.; Zhang, M.

2017-04-01

Wetting behavior of Ne adsorbed on a Mg surface, first investigated by means of a grand canonical Monte Carlo method in a previous publication (M. J. Bojan, G. Stan, S. Curtarolo, W. A. Steele, and M. W. Cole, Phys. Rev. E, 1999, 59, 864), is again studied by means of classical density functional theory. The Ne-Ne interaction is taken to be of the Lennard-Jones form, while the Ne-surface interaction is derived from an electronic density functional theory. The wetting phase diagram is calculated, and the isotherm shapes, energy and structural properties of the adsorbed films are examined. The present calculations indicate that the system exhibits first-order pre-wetting transition at temperatures above a wetting temperature of Tw≈24 K, and below a critical pre-wetting temperature of Tpwc≈25.09 K. The present findings include (i) in the pre-wetting temperature region, the pre-wetting transition is mixed with many layering transitions; after pre-wetting, the film thickness discontinuously increases (due to frequent occurrences of the layering transitions) and eventually diverges as the chemical potential approaches and eventually equals the saturation value. (ii) Occurrence of the layering transition remains above Tpwc, and the increase of the film thickness with the chemical potential is discontinuous. (iii) Below the wetting temperature, the layering transitions frequently occur and tend to gather together more closely as the saturation is approached.

Minnowbrook III: 2000 Workshop on Boundary Layer Transition and Unsteady Aspects of Turbomachinery Flows

NASA Technical Reports Server (NTRS)

LaGraff, John E. (Editor); Ashpis, David E. (Editor)

2002-01-01

This volume and its accompanying CD-ROM contain materials presented at the Minnowbrook III-2000 Workshop on Boundary Layer Transition and Unsteady Aspects of Turbomachinery Flows held at the Syracuse University Minnowbrook Conference Center, Blue Mountain Lake, New York, August 20-23, 2000. Workshop organizers were John E. LaGraff (Syracuse University), Terry V Jones (Oxford University), and J. Paul Gostelow (University of Leicester). The workshop followed the theme, venue, and informal format of two earlier workshops: Minnowbrook I (1993) and Minnowbrook II (1997). The workshop was focused on physical understanding the late stage (final breakdown) boundary layer transition, separation, and effects of unsteady wakes with the specific goal of contributing to engineering application of improving design codes for turbomachinery. The workshop participants included academic researchers from the USA and abroad, and representatives from the gas-turbine industry and government laboratories. The physical mechanisms discussed included turbulence disturbance environment in turbomachinery, flow instabilities, bypass and natural transition, turbulent spots and calmed regions, wake interactions with attached and separated boundary layers, turbulence and transition modeling and CFD, and DNS. This volume contains abstracts and copies of the viewgraphs presented, organized according to the workshop sessions. The viewgraphs are included on the CD-ROM only. The workshop summary and the plenary-discussion transcripts clearly highlight the need for continued vigorous research in the technologically important area of transition, separated and unsteady flows in turbomachines.

Boundary-Layer Receptivity and Integrated Transition Prediction

NASA Technical Reports Server (NTRS)

Chang, Chau-Lyan; Choudhari, Meelan

2005-01-01

The adjoint parabold stability equations (PSE) formulation is used to calculate the boundary layer receptivity to localized surface roughness and suction for compressible boundary layers. Receptivity efficiency functions predicted by the adjoint PSE approach agree well with results based on other nonparallel methods including linearized Navier-Stokes equations for both Tollmien-Schlichting waves and crossflow instability in swept wing boundary layers. The receptivity efficiency function can be regarded as the Green's function to the disturbance amplitude evolution in a nonparallel (growing) boundary layer. Given the Fourier transformed geometry factor distribution along the chordwise direction, the linear disturbance amplitude evolution for a finite size, distributed nonuniformity can be computed by evaluating the integral effects of both disturbance generation and linear amplification. The synergistic approach via the linear adjoint PSE for receptivity and nonlinear PSE for disturbance evolution downstream of the leading edge forms the basis for an integrated transition prediction tool. Eventually, such physics-based, high fidelity prediction methods could simulate the transition process from the disturbance generation through the nonlinear breakdown in a holistic manner.

Two dimensional disorder in black phosphorus and layered monochalcogenides

NASA Astrophysics Data System (ADS)

Barraza-Lopez, Salvador; Mehboudi, Mehrshad; Kumar, Pradeep; Harriss, Edmund O.; Churchill, Hugh O. H.; Dorio, Alex M.; Zhu, Wenjuan; van der Zande, Arend; Pacheco Sanjuan, Alejandro A.

The degeneracies of the structural ground state of materials with a layered orthorhombic structure such as black phosphorus and layered monochalcogenides GeS, GeSe, SnS, and SnSe, lead to an order/disorder transition in two dimensions at finite temperature. This transition has consequences on applications based on these materials requiring a crystalline two-dimensional structure. Details including a Potts model that explains the two-dimensional transition, among other results, will be given in this talk. References: M. Mehboudi, A.M. Dorio, W. Zhu, A. van der Zande, H.O.H. Churchill, A.A. Pacheco Sanjuan, E.O.H. Harris, P. Kumar, and S. Barraza-Lopez. arXiv:1510.09153.

Role of interfacial transition layers in VO2/Al2O3 heterostructures

DOE Office of Scientific and Technical Information (OSTI.GOV)

Zhou, Honghui; Chisholm, Matthew F; Yang, Tsung-Han

2011-01-01

Epitaxial VO2 films grown by pulsed laser deposition (PLD) on c-cut sapphire substrates ((0001) Al2O3) were studied by aberration-corrected scanning transmission electron microscopy (STEM). A number of film/substrate orientation relationships were found and are discussed in the context of the semiconductor-metal transition (SMT) characteristics. A structurally and electronically modified buffer layer was revealed on the interface and was attributed to the interface free-energy minimization process of accommodating the symmetry mismatch between the substrate and the film. This interfacial transition layer is expected to affect the SMT behavior when the interfacial region is a significant fraction of the VO2 film thickness.

Characteristics of Mach 10 transitional and turbulent boundary layers

NASA Technical Reports Server (NTRS)

Watson, R. D.

1978-01-01

Measurements of the mean flow properties of transitional and turbulent boundary layers in helium on 4 deg and 5 deg wedges were made for flows with edge Mach numbers from 9.5 to 11.3, ratios of wall temperature to total temperature of 0.4 to 0.95, and maximum length Reynolds numbers of one hundred million. The data include pitot and total temperature surveys and measurements of heat transfer and surface shear. In addition, with the assumption of local similarity, turbulence quantities such as the mixing length were derived from the mean flow profiles. Low Reynolds number and precursor transition effects were significant factors at these test conditions and were included in finite difference boundary layer predictions.

A review and analysis of boundary layer transition data for turbine application

NASA Technical Reports Server (NTRS)

Gaugler, R. E.

1984-01-01

A symposium on transition in turbines was held at the NASA Lewis Research Center. One recommendation of the working groups was the collection of existing transition data to provide standard cases against which models could be tested. A number of data sets from the open literature that include heat transfer data in apparently transitional boundary layers, with particular application to the turbine environment, were reviewed and analyzed to extract transition information from the heat transfer data. The data sets reviewed cover a wide range of flow conditions, from low speed, flat plate tests to full scale turbine airfoils operating at simulated turbine engine conditions. The results indicate that free stream turbulence and pressure gradient have strong, and opposite, effects on the location of the start of transition and on the length of the transition zone.

A review and analysis of boundary layer transition data for turbine application

NASA Technical Reports Server (NTRS)

Gaugler, R. E.

1985-01-01

A symposium on transition in turbines was held at the NASA Lewis Research Center. One recommendation of the working groups was the collection of existing transition data to provide standard cases against which models could be tested. A number of data sets from the open literature that include heat transfer data in apparently transitional boundary layers, with particular application to the turbine environment, were reviewed and analyzed to extract transition information from the heat transfer data. The data sets reviewed cover a wide range of flow conditions, from low speed, flat plate tests to full scale turbine airfoils operating at simulated turbine engine conditions. The results indicate that free stream turbulence and pressure gradient have strong, and opposite, effects on the location of the start of transition and on the length of the transition zone.

Experimental studies on the stability and transition of 3-dimensional boundary layers

NASA Technical Reports Server (NTRS)

Nitschke-Kowsky, P.

1987-01-01

Three-dimensional unstable boundary layers were investigated as to their characteristic instabilities, leading to turbulence. Standing cross-flow instabilities and traveling waves preceding the transition were visualized with the hydrogen bubble technique in the boundary layer above the wall of a swept cylinder. With the sublimation method and hot film technique, a model consisting of a swept flat plate with a pressure-inducing displacement body in the 1 m wind tunnel was studied. Standing waves and traveling waves in a broad frequency are observed. The boundary layer of this model is close to the assumptions of the theory.

Electrodeposition of biaxially textured layers on a substrate

DOEpatents

Bhattacharya, Raghu N; Phok, Sovannary; Spagnol, Priscila; Chaudhuri, Tapas

2013-11-19

Methods of producing one or more biaxially textured layer on a substrate, and articles produced by the methods, are disclosed. An exemplary method may comprise electrodepositing on the substrate a precursor material selected from the group consisting of rare earths, transition metals, actinide, lanthanides, and oxides thereof. An exemplary article (150) may comprise a biaxially textured base material (130), and at least one biaxially textured layer (110) selected from the group consisting of rare earths, transition metals, actinides, lanthanides, and oxides thereof. The at least one biaxially textured layer (110) is formed by electrodeposition on the biaxially textured base material (130).

Layer Anti-Ferromagnetism on Bilayer Honeycomb Lattice

PubMed Central

Tao, Hong-Shuai; Chen, Yao-Hua; Lin, Heng-Fu; Liu, Hai-Di; Liu, Wu-Ming

2014-01-01

Bilayer honeycomb lattice, with inter-layer tunneling energy, has a parabolic dispersion relation, and the inter-layer hopping can cause the charge imbalance between two sublattices. Here, we investigate the metal-insulator and magnetic phase transitions on the strongly correlated bilayer honeycomb lattice by cellular dynamical mean-field theory combined with continuous time quantum Monte Carlo method. The procedures of magnetic spontaneous symmetry breaking on dimer and non-dimer sites are different, causing a novel phase transition between normal anti-ferromagnet and layer anti-ferromagnet. The whole phase diagrams about the magnetism, temperature, interaction and inter-layer hopping are obtained. Finally, we propose an experimental protocol to observe these phenomena in future optical lattice experiments. PMID:24947369

Surface roughening transition and critical layer thickness in strained-layer heteroepitaxy of EuTe on PbTe (111)

NASA Astrophysics Data System (ADS)

Springholz, G.; Frank, N.; Bauer, G.

1994-05-01

Heteroepitaxial growth of 2% lattice-mismatched EuTe on PbTe (111) by molecular beam epitaxy is investigated in the two-dimensional layer-by-layer growth regime combining in situ reflection high-energy electron diffraction and scanning tunneling microscopy (STM). At the critical layer thickness a distinct surface roughening is observed. The quantitative analysis of STM images yields an increase of the root mean square roughness by a factor of 4 at this roughening transition. Strong evidence is presented that for the used growth conditions this roughening is not caused by strain induced coherent islanding but by misfit dislocations at the onset of strain relaxation.

Research in Natural Laminar Flow and Laminar-Flow Control, part 2

NASA Technical Reports Server (NTRS)

Hefner, Jerry N. (Compiler); Sabo, Frances E. (Compiler)

1987-01-01

Part 2 of the Symposium proceedings includes papers addressing various topics in basic wind tunnel research/techniques and computational transitional research. Specific topics include: advanced measurement techniques; laminar flow control; Tollmien-Schlichting wave characteristics; boundary layer transition; flow visualization; wind tunnel tests; flight tests; boundary layer equations; swept wings; and skin friction.

Tuning transitions in rotating Rayleigh-Bénard convection

NASA Astrophysics Data System (ADS)

Joshi, Pranav; Kunnen, Rudie; Clercx, Herman

2015-11-01

Turbulent rotating Rayleigh-Bénard convection, depending on the system parameters, exhibits multiple flow states and transitions between them. The present experimental study aims to control the transitions between the flow regimes, and hence the system heat transfer characteristics, by introducing particles in the flow. We inject near-neutrally buoyant silver coated hollow ceramic spheres (~100 micron diameter) and measure the system response, i.e. the Nusselt number, at different particle concentrations and rotation rates. Both for rotating and non-rotating cases, most of the particles settle on the top and bottom plates in a few hours following injection. This rapid settling may be a result of ``trapping'' of particles in the laminar boundary layers at the horizontal walls. These particle layers on the heat-transfer surfaces reduce their effective conductivity, and consequently, lower the heat transfer rate. We calculate the effective system parameters by estimating, and accounting for, the temperature drop across the particle layers. Preliminary analysis suggests that the thermal resistance of the particle layers may affect the flow structure and delay the transition to the ``geostrophic'' regime. Financial support from Foundation for Fundamental Research on Matter.

A Low-Speed Experimental Investigation of the Effect of a Sandpaper Type of Roughness on Boundary-Layer Transition

NASA Technical Reports Server (NTRS)

Von Doenhoff, Albert E; Horton, Elmer A

1958-01-01

An investigation was made in the Langley low-turbulence pressure tunnel to determine the effect of size and location of a sandpaper type of roughness on the Reynolds number for transition. Transition was observed by means of a hot-wire anemometer located at various chordwise stations for each position of the roughness. These observations indicated that when the roughness is sufficiently submerged in the boundary layer to provide a substantially linear variation of boundary-layer velocity with distance from the surface up to the top of the roughness, turbulent "spots" begin to appear immediately behind the roughness when the Reynolds number based on the velocity at the top of the roughness height exceeds a value of approximately 600. At Reynolds numbers even slightly below the critical value (value for transition), the sandpaper type of roughness introduced no measurable disturbances into the laminar layer downstream of the roughness. The extent of the roughness area does not appear to have an important effect on the critical value of the roughness Reynolds number.

Even–odd layer-dependent magnetotransport of high-mobility Q-valley electrons in transition metal disulfides

PubMed Central

Wu, Zefei; Xu, Shuigang; Lu, Huanhuan; Khamoshi, Armin; Liu, Gui-Bin; Han, Tianyi; Wu, Yingying; Lin, Jiangxiazi; Long, Gen; He, Yuheng; Cai, Yuan; Yao, Yugui; Zhang, Fan; Wang, Ning

2016-01-01

In few-layer transition metal dichalcogenides (TMDCs), the conduction bands along the ΓK directions shift downward energetically in the presence of interlayer interactions, forming six Q valleys related by threefold rotational symmetry and time reversal symmetry. In even layers, the extra inversion symmetry requires all states to be Kramers degenerate; whereas in odd layers, the intrinsic inversion asymmetry dictates the Q valleys to be spin-valley coupled. Here we report the transport characterization of prominent Shubnikov-de Hass (SdH) oscillations and the observation of the onset of quantum Hall plateaus for the Q-valley electrons in few-layer TMDCs. Universally in the SdH oscillations, we observe a valley Zeeman effect in all odd-layer TMDC devices and a spin Zeeman effect in all even-layer TMDC devices, which provide a crucial information for understanding the unique properties of multi-valley band structures of few-layer TMDCs. PMID:27651106

Transition Induced by Fence Geometrics on Shuttle Orbiter at Mach 10

NASA Technical Reports Server (NTRS)

Everhart, Joel L.

2010-01-01

Fence-induced transition data simulating a raised gap filler have been acquired on the wing lower surface of a Shuttle Orbiter model in the Langley 31-Inch Mach 10 Tunnel to compare with the Shuttle Boundary Layer Transition Flight and HYTHIRM Experiments, and to provide additional correlation data for the Boundary Layer Transition Tool. In a qualitative assessment, the data exhibit the expected response to all parameter variations; however, it is unclear whether fully effective tripping at the fence was ever realized at any test condition with the present model hardware. A preliminary, qualitative comparison of the ground-based transition measurements with those obtained from the STS-128 HYTHIRM imagery at Mach 15 reveal similar transition-wake response characteristics in terms of the spreading and the path along the vehicle surface.

Transition within a Hypervelocity Boundary Layer on a 5-degree Half-Angle Cone in Freestream Air/CO2 Mixtures

DTIC Science & Technology

2013-01-01

Pasadena, CA, 91125 Nomenclature A = amplitude of oscillation f = frequency hres = reservoir enthalpy Me = boundary layer edge Mach number Pres...showed an increase in the reference Reynolds number Re* at the point of transition as reservoir enthalpy hres increased. Germain and Adam also observed...that flows of CO2 transitioned at higher values of Re* than flows of air for the same hres and Pres. Johnson et al. (1998) studied this effect with a

Detection and Characterization of Boundary-Layer Transition in Flight at Supersonic Conditions Using Infrared Thermography

NASA Technical Reports Server (NTRS)

Banks, Daniel W.

2008-01-01

Infrared thermography is a powerful tool for investigating fluid mechanics on flight vehicles. (Can be used to visualize and characterize transition, shock impingement, separation etc.). Updated onboard F-15 based system was used to visualize supersonic boundary layer transition test article. (Tollmien-Schlichting and cross-flow dominant flow fields). Digital Recording improves image quality and analysis capability. (Allows accurate quantitative (temperature) measurements, Greater enhancement through image processing allows analysis of smaller scale phenomena).

Ground state transitions in vertically coupled N-layer single electron quantum dots

NASA Astrophysics Data System (ADS)

Xie, Wenfang; Wang, Anmei

2003-12-01

A method is proposed to exactly diagonalize the Hamiltonian of a N-layer quantum dot containing a single electron in each dot in arbitrary magnetic fields. For N=4, the energy spectra of the dot are calculated as a function of the applied magnetic field. We find discontinuous ground-state energy transitions induced by an external magnetic field in the case of strong coupling. However, in the case of weak coupling, such a transition does not occur and the angular momentum remains zero.

Sound radiation due to boundary layer transition

NASA Technical Reports Server (NTRS)

Wang, Meng

1993-01-01

This report describes progress made to date towards calculations of noise produced by the laminar-turbulence transition process in a low Mach number boundary layer formed on a rigid wall. The primary objectives of the study are to elucidate the physical mechanisms by which acoustic waves are generated, to clarify the roles of the fluctuating Reynolds stress and the viscous stress in the presence of a solid surface, and to determine the relative efficiency as a noise source of the various transition stages. In particular, we will examine the acoustic characteristics and directivity associated with three-dimensional instability waves, the detached high-shear layer, and turbulent spots following a laminar breakdown. Additionally, attention will be paid to the unsteady surface pressures during the transition, which provide a source of flow noise as well as a forcing function for wall vibration in both aeronautical and marine applications.

Casimir energy for two and three superconducting coupled cavities: Numerical calculations

NASA Astrophysics Data System (ADS)

Rosa, L.; Avino, S.; Calloni, E.; Caprara, S.; De Laurentis, M.; De Rosa, R.; Esposito, Giampiero; Grilli, M.; Majorana, E.; Pepe, G. P.; Petrarca, S.; Puppo, P.; Rapagnani, P.; Ricci, F.; Rovelli, C.; Ruggi, P.; Saini, N. L.; Stornaiolo, C.; Tafuri, F.

2017-11-01

In this paper we study the behavior of the Casimir energy of a "multi-cavity" across the transition from the metallic to the superconducting phase of the constituting plates. Our analysis is carried out in the framework of the ARCHIMEDES experiment, aiming at measuring the interaction of the electromagnetic vacuum energy with a gravitational field. For this purpose it is foreseen to modulate the Casimir energy of a layered structure composing a multy-cavity coupled system by inducing a transition from the metallic to the superconducting phase. This implies a thorough study of the behavior of the cavity, in which normal metallic layers are alternated with superconducting layers, across the transition. Our study finds that, because of the coupling between the cavities, mainly mediated by the transverse magnetic modes of the radiation field, the variation of energy across the transition can be very large.

Experimental study of boundary layer transition with elevated freestream turbulence on a heated flat plate

NASA Technical Reports Server (NTRS)

Sohn, Ki-Hyeon; Reshotko, Eli

1991-01-01

A detailed investigation to document momentum and thermal development of boundary layers undergoing natural transition on a heated flat plate was performed. Experimental results of both overall and conditionally sampled characteristics of laminar, transitional, and low Reynolds number turbulent boundary layers are presented. Measurements were acquired in a low-speed, closed-loop wind tunnel with a freestream velocity of 100 ft/s and zero pressure gradient over a range of freestream turbulence intensities (TI) from 0.4 to 6 percent. The distributions of skin friction, heat transfer rate and Reynolds shear stress were all consistent with previously published data. Reynolds analogy factors for R(sub theta) is less than 2300 were found to be well predicted by laminar and turbulent correlations which accounted for an unheated starting length. The measured laminar value of Reynolds analogy factor was as much as 53 percent higher than the Pr(sup -2/3). A small dependence of turbulent results on TI was observed. Conditional sampling performed in the transitional boundary layer indicated the existence of a near-wall drop in intermittency, pronounced at certain low intermittencies, which is consistent with the cross-sectional shape of turbulent spots observed by others. Non-turbulent intervals were observed to possess large magnitudes of near-wall unsteadiness and turbulent intervals had peak values as much as 50 percent higher than were measured at fully turbulent stations. Non-turbulent and turbulent profiles in transitional boundary layers cannot be simply treated as Blasius and fully turbulent profiles, respectively. The boundary layer spectra indicate predicted selective amplification of T-S waves for TI is approximately 0.4 percent. However, for TI is approximately 0.8 and 1.1 percent, T-S waves are localized very near the wall and do not play a dominant role in transition process.

Countering the Segregation of Transition-Metal Ions in LiMn1/3 Co1/3 Ni1/3 O2 Cathode for Ultralong Life and High-Energy Li-Ion Batteries.

PubMed

Luo, Dong; Fang, Shaohua; Tamiya, Yu; Yang, Li; Hirano, Shin-Ichi

2016-08-01

High-voltage layered lithium transition-metal oxides are very promising cathodes for high-energy Li-ion batteries. However, these materials often suffer from a fast degradation of cycling stability due to structural evolutions. It seriously impedes the large-scale application of layered lithium transition-metal oxides. In this work, an ultralong life LiMn1/3 Co1/3 Ni1/3 O2 microspherical cathode is prepared by constructing an Mn-rich surface. Its capacity retention ratio at 700 mA g(-1) is as large as 92.9% after 600 cycles. The energy dispersive X-ray maps of electrodes after numerous cycles demonstrate that the ultralong life of the as-prepared cathode is attributed to the mitigation of TM-ions segregation. Additionally, it is discovered that layered lithium transition-metal oxide cathodes with an Mn-rich surface can mitigate the segregation of TM ions and the corrosion of active materials. This study provides a new strategy to counter the segregation of TM ions in layered lithium transition-metal oxides and will help to the design and development of high-energy cathodes with ultralong life. © 2016 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

Phase constitution in the interfacial region of laser penetration brazed magnesium–steel joints

DOE Office of Scientific and Technical Information (OSTI.GOV)

Miao, Yugang; Han, Duanfeng, E-mail: handuanfeng@gmail.com; Xu, Xiangfang

2014-07-01

The phase constitution in the interfacial region of laser penetration brazed magnesium–steel joints was investigated using electron microscopy. From the distribution of elements, the transition zone was mainly composed of elements Mg and Fe along with some Al and O. Furthermore, the transition layer consisted mainly of intermetallic compounds and metal oxides. The compounds were identified as Al-rich phases, such as Mg{sub 17}Al{sub 12}, Mg{sub 2}Al{sub 3}, FeAl and Fe{sub 4}Al{sub 13}. More noteworthy was that the thickness of the transition layer was determined by Fe–Al compounds. The presence of FeAl and Fe{sub 4}Al{sub 13} was a result of themore » complex processes that were associated with the interfacial reaction of solid steel and liquid Mg–Al alloy. - Highlights: • A technology of laser penetration brazed Mg alloy and steel has been developed. • The interface of Mg/Fe dissimilar joints was investigated using electron microscopy. • The transition layer consisted of intermetallic compounds and metal oxides. • Moreover, the thickness of transition layer was determined by Fe/Al compounds. • The presence of FeAl and Fe{sub 4}Al{sub 13} was associated with the interfacial reaction.« less

Discrete Roughness Effects on Shuttle Orbiter at Mach 6

NASA Technical Reports Server (NTRS)

Berry, Scott A.; Hamilton, H. Harris, II

2002-01-01

Discrete roughness boundary layer transition results on a Shuttle Orbiter model in the NASA Langley Research Center 20-Inch Mach 6 Air Tunnel have been reanalyzed with new boundary layer calculations to provide consistency for comparison to other published results. The experimental results were previously obtained utilizing the phosphor thermography system to monitor the status of the boundary layer via global heat transfer images of the Orbiter windward surface. The size and location of discrete roughness elements were systematically varied along the centerline of the 0.0075-scale model at an angle of attack of 40 deg and the boundary layer response recorded. Various correlative approaches were attempted, with the roughness transition correlations based on edge properties providing the most reliable results. When a consistent computational method is used to compute edge conditions, transition datasets for different configurations at several angles of attack have been shown to collapse to a well-behaved correlation.

Local Deplanation Of Double Reinforced Beam Cross Section Under Bending

NASA Astrophysics Data System (ADS)

Baltov, Anguel; Yanakieva, Ana

2015-12-01

Bending of beams, double reinforced by means of thin composite layers, is considered in the study. Approximate numerical solution is proposed, considering transitional boundary areas, where smooth quadratic transition of the elasticity modulus and deformations take place. Deplanation of the cross section is also accounted for in the areas. Their thickness is found equalizing the total stiffness of the cross section and the layer stiffness. Deplanation of the cross section of the transitional area is determined via the longitudinal deformation in the reinforcing layer, accounting for the equilibrium between the internal and the external moment, generated by the longitudinal stresses in the cross section. A numerical example is given as an illustration demonstrating model's plausibility. The model allows the design and the calculation of recycled concrete beams double reinforced by means of thin layers. The approach is in agreement with modern design of nearly zero energy buildings (NZEB).

Shock wave boundary layer interaction on suction side of compressor profile in single passage test section

NASA Astrophysics Data System (ADS)

Flaszynski, Pawel; Doerffer, Piotr; Szwaba, Ryszard; Kaczynski, Piotr; Piotrowicz, Michal

2015-11-01

The shock wave boundary layer interaction on the suction side of transonic compressor blade is one of the main objectives of TFAST project (Transition Location Effect on Shock Wave Boundary Layer Interaction). In order to investigate the flow structure on the suction side of a profile, a design of a generic test section in linear transonic wind tunnel was proposed. The experimental and numerical results for the flow structure investigations are shown for the flow conditions as the existing ones on the suction side of the compressor profile. Near the sidewalls the suction slots are applied for the corner flow structure control. It allows to control the Axial Velocity Density Ratio (AVDR), important parameter for compressor cascade investigations. Numerical results for Explicit Algebraic Reynolds Stress Model with transition modeling are compared with oil flow visualization, schlieren and Pressure Sensitive Paint. Boundary layer transition location is detected by Temperature Sensitive Paint.

Recent insights into instability and transition to turbulence in open-flow systems

NASA Technical Reports Server (NTRS)

Morkovin, Mark V.

1988-01-01

Roads to turbulence in open-flow shear layers are interpreted as sequences of often competing instabilities. These correspond to primary and higher order restructurings of vorticity distributions which culminate in convected spatial disorder (with some spatial coherence on the scale of the shear layer) traditionally called turbulence. Attempts are made to interpret these phenomena in terms of concepts of convective and global instabilities on one hand, and of chaos and strange attractors on the other. The first is fruitful, and together with a review of mechanisms of receptivity provides a unifying approach to understanding and estimating transition to turbulence. In contrast, current evidence indicates that concepts of chaos are unlikely to help in predicting transition in open-flow systems. Furthermore, a distinction should apparently be made between temporal chaos and the convected spatial disorder of turbulence past Reynolds numbers where boundary layers and separated shear layers are formed.

Laser transit anemometer measurements on a slender cone in the Langley unitary plan wind tunnel

NASA Technical Reports Server (NTRS)

Humphreys, William M., Jr.; Hunter, William W., Jr.; Covell, Peter F.; Nichols, Cecil E., Jr.

1990-01-01

A laser transit anemometer (LTA) system was used to probe the boundary layer on a slender (5 degree half angle) cone model in the Langley unitary plan wind tunnel. The anemometer system utilized a pair of laser beams with a diameter of 40 micrometers spaced 1230 micrometers apart to measure the transit times of ensembles of seeding particles using a cross-correlation technique. From these measurements, boundary layer profiles around the model were constructed and compared with CFD calculations. The measured boundary layer profiles representing the boundary layer velocity normalized to the edge velocity as a function of height above the model surface were collected with the model at zero angle of attack for four different flow conditions, and were collected in a vertical plane that bisected the model's longitudinal center line at a location 635 mm from the tip of the forebody cone. The results indicate an excellent ability of the LTA system to make velocity measurements deep into the boundary layer. However, because of disturbances in the flow field caused by onboard seeding, premature transition occurred implying that upstream seeding is mandatory if model flow field integrity is to be maintained. A description and results of the flow field surveys are presented.

Transitional boundary layer in low-Prandtl-number convection at high Rayleigh number

NASA Astrophysics Data System (ADS)

Schumacher, Joerg; Bandaru, Vinodh; Pandey, Ambrish; Scheel, Janet

2016-11-01

The boundary layer structure of the velocity and temperature fields in turbulent Rayleigh-Bénard flows in closed cylindrical cells of unit aspect ratio is revisited from a transitional and turbulent viscous boundary layer perspective. When the Rayleigh number is large enough the boundary layer dynamics at the bottom and top plates can be separated into an impact region of downwelling plumes, an ejection region of upwelling plumes and an interior region (away from side walls) that is dominated by a shear flow of varying orientation. This interior plate region is compared here to classical wall-bounded shear flows. The working fluid is liquid mercury or liquid gallium at a Prandtl number of Pr = 0 . 021 for a range of Rayleigh numbers of 3 ×105 <= Ra <= 4 ×108 . The momentum transfer response to these system parameters generates a fluid flow in the closed cell with a macroscopic flow Reynolds number that takes values in the range of 1 . 8 ×103 <= Re <= 4 . 6 ×104 . It is shown that particularly the viscous boundary layers for the largest Ra are highly transitional and obey some properties that are directly comparable to transitional channel flows at friction Reynolds numbers below 100. This work is supported by the Deutsche Forschungsgemeinschaft.

Characterization of the Embryogenic Tissue of the Norway Spruce Including a Transition Layer between the Tissue and the Culture Medium by Magnetic Resonance Imaging

NASA Astrophysics Data System (ADS)

Kořínek, R.; Mikulka, J.; Hřib, J.; Hudec, J.; Havel, L.; Bartušek, K.

2017-02-01

The paper describes the visualization of the cells (ESEs) and mucilage (ECMSN) in an embryogenic tissue via magnetic resonance imaging (MRI) relaxometry measurement combined with the subsequent multi-parametric segmentation. The computed relaxometry maps T1 and T2 show a thin layer (transition layer) between the culture medium and the embryogenic tissue. The ESEs, mucilage, and transition layer differ in their relaxation times T1 and T2; thus, these times can be used to characterize the individual parts within the embryogenic tissue. The observed mean values of the relaxation times T1 and T2 of the ESEs, mucilage, and transition layer are as follows: 1469 ± 324 and 53 ± 10 ms, 1784 ± 124 and 74 ± 8 ms, 929 ± 164 and 32 ± 4.7 ms, respectively. The multi-parametric segmentation exploiting the T1 and T2 relaxation times as a classifier shows the distribution of the ESEs and mucilage within the embryogenic tissue. The discussed T1 and T2 indicators can be utilized to characterize both the growth-related changes in an embryogenic tissue and the effect of biotic/abiotic stresses, thus potentially becoming a distinctive indicator of the state of any examined embryogenic tissue.

Response of the solar atmosphere to a simple flare burst: UV emission from the flare transition layer.

NASA Astrophysics Data System (ADS)

Shmeleva, O. P.

The flare transition layer exists as a relatively steady formation even during impulsive heating. It is maintained by a heat flow from the high-temperature plasma, where the major part of the electron beam energy is absorbed. The lifetime of this plasma is much greater than the impulsive heating time. Intensities of resonance UV lines are calculated using both the model of impulsive nonthermal heating by energetic electrons and the model of continuous thermal heating. The calculated line intensity is almost constant during a long time. The line Doppler shifts predicted by the former model match observations. This suggests that the model represents sufficiently well the actual dynamics of the flare plasma. The flare transition layer is a thin formation, its thickness being Δξ = 1021m-2. It is therefore described adequately within the p = const approximation though the picture of hydrodynamic response of the solar atmosphere to the impulsive heating by energy flows is rather complicated and nonsteady, of course. The intensities of the C IV λλ154.8, 155.1 nm and O VI λλ103.2, 103.8 nm lines are calculated within the scope of the model of continuous thermal heating, in which the conductive heating of the flare transition layer is balanced by radiative cooling. The line intensities are proportional to the pressure in the layer, which permits the pressure to be found from the observed line intensities. The analysis reveals that both heating models adequately represent the actual structure and dynamics of plasma in a flare. In the flare transition layer, the classical heat conduction always does work.

Insights into the crustal structure of the transition between Nares Strait and Baffin Bay

NASA Astrophysics Data System (ADS)

Altenbernd, Tabea; Jokat, Wilfried; Heyde, Ingo; Damm, Volkmar

2016-11-01

The crustal structure and continental margin between southern Nares Strait and northern Baffin Bay were studied based on seismic refraction and gravity data acquired in 2010. We present the resulting P wave velocity, density and geological models of the crustal structure of a profile, which extends from the Greenlandic margin of the Nares Strait into the deep basin of central northern Baffin Bay. For the first time, the crustal structure of the continent-ocean transition of the very northern part of Baffin Bay could be imaged. We divide the profile into three parts: continental, thin oceanic, and transitional crust. On top of the three-layered continental crust, a low-velocity zone characterizes the lowermost layer of the three-layered Thule Supergroup underneath Steensby Basin. The 4.3-6.3 km thick oceanic crust in the southern part of the profile can be divided into a northern and southern section, more or less separated by a fracture zone. The oceanic crust adjacent to the continent-ocean transition is composed of 3 layers and characterized by oceanic layer 3 velocities of 6.7-7.3 km/s. Toward the south only two oceanic crustal layers are necessary to model the travel time curves. Here, the lower oceanic crust has lower seismic velocities (6.4-6.8 km/s) than in the north. Rather low velocities of 7.7 km/s characterize the upper mantle underneath the oceanic crust, which we interpret as an indication for the presence of upper mantle serpentinization. In the continent-ocean transition zone, the velocities are lower than in the adjacent continental and oceanic crustal units. There are no signs for massive magmatism or the existence of a transform margin in our study area.

Phase transitions in orthopyroxene (En 90) to 49GPa from single-crystal X-ray diffraction

DOE PAGES

Finkelstein, Gregory J.; Dera, Przemyslaw K.; Duffy, Thomas S.

2014-10-29

Synchrotron-based high-pressure single-crystal X-ray diffraction experiments were conducted on ~Mg 0.9Fe 0.1SiO 3 (En 90) orthopyroxene crystals at room temperature to a maximum pressure of 48.5 GPa. The sample was compressed in a diamond anvil cell with a neon pressure medium and a gold pressure calibrant. In addition to the previously described orthopyroxene to β-opx transition (designated HPCEN2 in previous studies), we observe two further phase transitions at 29.9 GPa and 40.3 GPa. However, we do not observe the γ-opx phase recently described in an Fe-rich orthopyroxene composition. The structures of both of the new phases were solved in spacemore » group Pca21. While their Mg-O layers remain pyroxene-like, their Si-O layers transform in a stepwise fashion to akimotoite-like sheets, with sites in 4-, 5-, or 6-fold coordination, depending on the specific structure and layer. Due to the increased Si-O coordination number, we designate the new structures α- and β-post-orthopyroxene (α-popx and β-popx). α-popx has one Si-O layer that is entirely tetrahedral, and one layer that contains both tetrahedra and 5-coordinated Si in distorted square pyramids. β-popx retains the mixed 4- and 5-coordinated Si layer found in α-popx, while the other Si layer adopts fully octahedral coordination. The α- and β-popx structures show a progressive transformation towards the arrangement of Si layers found in akimotoite, a potentially important phase in the earth’s transition zone. Metastable transformations in pyroxenes are of interest for understanding possible metastability in geological environments such as subducting slabs and meteorite impacts« less

Layered transition metal dichalcogenide electrochemistry: journey across the periodic table.

PubMed

Chia, Xinyi; Pumera, Martin

2018-06-08

Studies on layered transition metal dichalcogenides (TMDs), in particular for Group VIB TMDs like MoS2 and WS2, have long reached a crescendo in the realms of electrochemical applications initiated by their remarkable catalytic and electronic properties. One area that garnered considerable attention is the fervent pursuit of layered TMDs as electrocatalysts for hydrogen evolution reaction (HER), driven by global efforts towards reducing carbon footprint and attaining hydrogen economy. This Tutorial Review captures the essence of electrochemistry of different classes of layered TMDs and metal chalcogenides across the period table and showcases their tuneable electrochemical and HER catalytic attributes that are governed by the elemental composition, structure and anisotropy. Of interest to the assiduously studied Group VIB TMDs, we describe the role of elemental constituents and material purity in aspects of surface composition and structure, on their electrochemistry. Across families of layered TMDs in the periodic table, we highlight the apparent trends in their electrochemical and electrocatalytic properties through diligent comparison. Inevitably, these trends vary according to the type of chalcogen or transition metal that constitutes the eventual TMD. Beyond layered TMDs, we discuss the electrochemistry and recent progress in HER electrocatalysis of other layered metal chalcogenides that are overshadowed by the success of Group VIB TMDs. At the pinnacle of the emergent applications of layered TMDs, it is prudent to demystify the intrinsic electrochemical behaviour that originates from the participation of the elemental constitution of transition metal or chalcogen. Moreover, knowledge of the catalytic and electronic properties of the various TMD families and emerging trends across the period or down the group is of paramount importance when introducing or refining their prospective uses. The annotations in this Tutorial Review are envisioned to promote discourse into the catalytic and electrochemical trends of TMDs that is currently absent.

Phase transitions in orthopyroxene (En 90) to 49GPa from single-crystal X-ray diffraction

DOE Office of Scientific and Technical Information (OSTI.GOV)

Finkelstein, Gregory J.; Dera, Przemyslaw K.; Duffy, Thomas S.

Synchrotron-based high-pressure single-crystal X-ray diffraction experiments were conducted on ~Mg 0.9Fe 0.1SiO 3 (En 90) orthopyroxene crystals at room temperature to a maximum pressure of 48.5 GPa. The sample was compressed in a diamond anvil cell with a neon pressure medium and a gold pressure calibrant. In addition to the previously described orthopyroxene to β-opx transition (designated HPCEN2 in previous studies), we observe two further phase transitions at 29.9 GPa and 40.3 GPa. However, we do not observe the γ-opx phase recently described in an Fe-rich orthopyroxene composition. The structures of both of the new phases were solved in spacemore » group Pca21. While their Mg-O layers remain pyroxene-like, their Si-O layers transform in a stepwise fashion to akimotoite-like sheets, with sites in 4-, 5-, or 6-fold coordination, depending on the specific structure and layer. Due to the increased Si-O coordination number, we designate the new structures α- and β-post-orthopyroxene (α-popx and β-popx). α-popx has one Si-O layer that is entirely tetrahedral, and one layer that contains both tetrahedra and 5-coordinated Si in distorted square pyramids. β-popx retains the mixed 4- and 5-coordinated Si layer found in α-popx, while the other Si layer adopts fully octahedral coordination. The α- and β-popx structures show a progressive transformation towards the arrangement of Si layers found in akimotoite, a potentially important phase in the earth’s transition zone. Metastable transformations in pyroxenes are of interest for understanding possible metastability in geological environments such as subducting slabs and meteorite impacts« less

Photovoltaic cell

DOEpatents

Gordon, Roy G.; Kurtz, Sarah

1984-11-27

In a photovoltaic cell structure containing a visibly transparent, electrically conductive first layer of metal oxide, and a light-absorbing semiconductive photovoltaic second layer, the improvement comprising a thin layer of transition metal nitride, carbide or boride interposed between said first and second layers.

Tradeoffs in Chemical and Thermal Variations in the Post-perovskite Phase Transition: Mixed Phase Regions in the Deep Lower Mantle?

NASA Astrophysics Data System (ADS)

Giles, G. F.; Spera, F. J.; Yuen, D. A.

2005-12-01

The recent discovery of a phase-transition in Mg-rich perovskite (Pv) to a post-perovskite (pPv) phase at lower mantle depths and its relationship to D", lower mantle heterogeneity and iron content prompted an investigation of the relative importance of lower mantle (LM) compositional and temperature fluctuations in creating topographic undulations on mixed phase regions. Above the transition, Mg-rich Pv makes up ~70 percent by mass of the LM. Using results from experimental phase equilibria, first-principles computations and thermodynamic relations for Fe2+-Mg mixing in silicates, a preliminary thermodynamic model for the perovskite to post-perovskite phase transition in the divariant system MgSiO3-FeSiO3 is developed. Complexities associated with components Fe2O3 and Al2O3 and other phases (Ca-Pv, magnesiowustite) are neglected. The model predicts phase transition pressures are sensitive to the FeSiO3 content of perovskite (~-1.5 GPa per one mole percent FeSiO3). This leads to considerable topography along the top boundary of the mixed phase region. The Clapeyron slope for the Pv to pPv transition at XFeSiO3=0.1 is +11 MPa/K about 20% higher than for pure Mg-Pv. Increasing bulk concentration of iron elevates the mixed (two-phase) layer above the core-mantle boundary (CMB); increasing temperature acts to push the mixed layer deeper into the LM into the D" thermal boundary layer resting upon the (CMB). For various LM geotherms and CMB temperatures, a single mixed layer of thickness ~300 km lies within the bottom 40% of the lower mantle. For low iron contents (XFeSiO3 ~5 mole percent or less), two perched layers are found. This is the divariant analog to the univariant double-crosser. The hotter the mantle, the deeper the mixed phase layer; the more iron-rich the LM, the higher the mixed phase layer. In a hotter Hadean Earth with interior temperatures everywhere 200-500 K warmer pPv is not stable unless the LM bulk composition is Fe-enriched compared to the present upper mantle.

Experimental Study of Transitional Flow Behavior in a Simulated Low Pressure Turbine

NASA Technical Reports Server (NTRS)

Sohn, Ki Hyeon; DeWitt, Kenneth J.

1998-01-01

A detailed investigation of the flow physics occurring on the suction side of a simulated Low Pressure Turbine (LPT) blade was performed. A contoured upper wall was designed to simulate the pressure distribution of an actual LPT airfoil onto a flat lower plate. The experiments were carried out for the Reynolds numbers of 35,000, 70,000, 100,000 and 250,000 with four levels of freestream turbulence ranging from 1% to 4%. For the three lower Reynolds numbers, the boundary layer on the flat plate was separated and formed a bubble. The size of laminar separation bubble was measured to be inversely proportional to the freestream turbulence levels and Reynolds numbers. However, no separation was observed for the Re = 250,000 case. The transition on a separated flow was found to proceed through the formation of turbulent spots in the free shear layer as evidenced in the intermittency profiles for Re = 35,000, 70,000 and 100,000. Spectral data show no evidence of Kelvin-Helmholtz or Tollmien-Schlichting instability waves in the free shear layer over a separation bubble (bypass transition). However, the flow visualization revealed the large vortex structures just outside of the bubble and their development to turbulent flow for Re = 50,000, which is similar to that in the free shear layer (separated-flow transition). Therefore, it is fair to say that the bypass and separated-flow transition modes coexist in the transitional flows over the separation bubble for certain conditions. Transition onset and end locations and length determined from intermittency profiles decrease as Reynolds number and freestream turbulence levels increase.

Experimental Study of Transitional Flow Behavior in a Simulated Low Pressure Turbine

NASA Technical Reports Server (NTRS)

Sohn, Ki Hyeon; DeWitt, Kenneth J.

2007-01-01

A detailed investigation of the flow physics occurring on the suction side of a simulated Low Pressure Turbine (LPT) blade was performed. A contoured upper wall was designed to simulate the pressure distribution of an actual LPT airfoil onto a flat lower plate. The experiments were carried out for the Reynolds numbers of 35,000, 70,000, 100,000, and 250,000 with four levels of freestream turbulence ranging from 1 to 4 percent. For the three lower Reynolds numbers, the boundary layer on the flat plate was separated and formed a bubble. The size of laminar separation bubble was measured to be inversely proportional to the freestream turbulence levels and Reynolds numbers. However, no separation was observed for the Re = 250,000 case. The transition on a separated flow was found to proceed through the formation of turbulent spots in the free shear layer as evidenced in the intermittency profiles for Re = 35,000, 70,000, and 100,000. Spectral data show no evidence of Kelvin-Helmholtz of Tollmien-Schlichting instability waves in the free shear layer over a separation bubble (bypass transition). However, the flow visualization revealed the large vortex structures just outside of the bubble and their development to turbulent flow for Re = 50,000, which is similar to that in the free shear layer (separated-flow transition). Therefore, it is fair to say that the bypass and separated-flow transition modes coexist in the transition flows over the separation bubble of certain conditions. Transition onset and end locations and length determined from intermittency profiles decreased as Reynolds number and freestream turbulence levels increase.

Nonlinear dynamics of mushy layers induced by external stochastic fluctuations.

PubMed

Alexandrov, Dmitri V; Bashkirtseva, Irina A; Ryashko, Lev B

2018-02-28

The time-dependent process of directional crystallization in the presence of a mushy layer is considered with allowance for arbitrary fluctuations in the atmospheric temperature and friction velocity. A nonlinear set of mushy layer equations and boundary conditions is solved analytically when the heat and mass fluxes at the boundary between the mushy layer and liquid phase are induced by turbulent motion in the liquid and, as a result, have the corresponding convective form. Namely, the 'solid phase-mushy layer' and 'mushy layer-liquid phase' phase transition boundaries as well as the solid fraction, temperature and concentration (salinity) distributions are found. If the atmospheric temperature and friction velocity are constant, the analytical solution takes a parametric form. In the more common case when they represent arbitrary functions of time, the analytical solution is given by means of the standard Cauchy problem. The deterministic and stochastic behaviour of the phase transition process is analysed on the basis of the obtained analytical solutions. In the case of stochastic fluctuations in the atmospheric temperature and friction velocity, the phase transition interfaces (mushy layer boundaries) move faster than in the deterministic case. A cumulative effect of these noise contributions is revealed as well. In other words, when the atmospheric temperature and friction velocity fluctuate simultaneously due to the influence of different external processes and phenomena, the phase transition boundaries move even faster. This article is part of the theme issue 'From atomistic interfaces to dendritic patterns'.This article is part of the theme issue 'From atomistic interfaces to dendritic patterns'. © 2018 The Author(s).

Study of boundary-layer transition using transonic cone Preston tube data

NASA Technical Reports Server (NTRS)

Reed, T. D.; Abu-Mostafa, A.

1982-01-01

Laminar layer Preston tube data on a sharp nose, ten degree cone obtained in the Ames 11 ft TWT and in flight tests are analyzed. During analyses of the laminar-boundary layer data, errors were discovered in both the wind tunnel and the flight data. A correction procedure for errors in the flight data is recommended which forces the flight data to exhibit some of the orderly characteristics of the wind tunnel data. From corrected wind tunnel data, a correlation is developed between Preston tube pressures and the corresponding values of theoretical laminar skin friction. Because of the uncertainty in correcting the flight data, a correlation for the unmodified data is developed, and, in addition, three other correlations are developed based on different correction procedures. Each of these correlations are used in conjunction with the wind tunnel correlation to define effective freestream unit Reynolds numbers for the 11 ft TWT over a Mach number range of 0.30 to 0.95. The maximum effective Reynolds numbers are approximately 6.5% higher than the normal values. These maximum values occur between freestream Mach numbers of 0.60 and 0.80. Smaller values are found outside this Mach number range. These results indicate wind tunnel noise affects the average laminar skin friction much less than it affects boundary layer transition. Data on the onset, extent, and end of boundary layer transition are summarized. Application of a procedure for studying the relative effects of varying nose radius on a ten degree cone at supercritical speeds indicates that increasing nose radius promotes boundary layer transition and separation of laminar boundary layers.

Stability theory applications to laminar-flow control

NASA Technical Reports Server (NTRS)

Malik, Mujeeb R.

1987-01-01

In order to design Laminar Flow Control (LFC) configurations, reliable methods are needed for boundary-layer transition predictions. Among the available methods, there are correlations based upon R sub e, shape factors, Goertler number and crossflow Reynolds number. The most advanced transition prediction method is based upon linear stability theory in the form of the e sup N method which has proven to be successful in predicting transition in two- and three-dimensional boundary layers. When transition occurs in a low disturbance environment, the e sup N method provides a viable design tool for transition prediction and LFC in both 2-D and 3-D subsonic/supersonic flows. This is true for transition dominated by either TS, crossflow, or Goertler instability. If Goertler/TS or crossflow/TS interaction is present, the e sup N will fail to predict transition. However, there is no evidence of such interaction at low amplitudes of Goertler and crossflow vortices.

Analysis of flight test transition and turbulent heating data. Part 1: Boundary layer transition results

NASA Technical Reports Server (NTRS)

Martellucci, A.; Maguire, B. L.; Neff, R. S.

1972-01-01

The objective of the study was to provide a detailed post flight evaluation of ballistic vehicle flight test boundary layer transition data. A total of fifty-five vehicles were selected for analysis. These vehicles were chosen from a data sampling of roughly two hundred flights and the criteria for vehicle selection is delineated herein. The results of the analysis indicate that frustum transition of re-entry vehicles appears to be nose tip dominated. Frustum related parameters and materials apparently have a second order effect on transition. This implies that local viscous parameters on the frustum should not correlate flight test transition data, and in fact they do not. Specific parameters relative to the nose tip have been identified as the apparent dominant factors that characterize the transition phenomena and a correlation of flight test data is presented.

Particle signatures of magnetic topology at the magnetopause: AMPTE/CCE observations

NASA Technical Reports Server (NTRS)

Fuselier, S. A.; Anderson, B. J.; Onsager, T. G.

1995-01-01

Electron distributions at energies above 50 eV have been found to be a sensitive indicator of magnetic topology for magnetopause crossings of the AMPTE/CCE spacecraft. Progressing from the magnetosheath to the magnetosphere two abrupt transitions occur. First, the magnetosheath electron population directed either parallel or antiparallel to the magnetic field is replaced by a streaming, heated magnetosheath electron population. The other half of the distribution is unchanged. The region with unidirectional, heated magnetosheath electrons is identified as the magnetosheath boundary layer (MSBL). Second, the unheated magnetosheath electron population is replaced by a heated population nearly identical to the population encountered in the MSBL, resulting in a symmetric counterstreaming distribution. The region populated by the bidirectional heated magnetosheath electrons is identified as the low-latitude boundary layer (LLBL). The MSBL and LLBL identified by the electron transitions are the same as the regions identified using ion composition measurements. The magnetosheath-MSBL transition reflects a change in magnetic topology from a solar wind field line to one that threads the magnetopause, and the existence of a magnetosheath-MSBL transition implies that the magnetopause is open. When the current layer is easily identified, the MSBL-LLBL transition coincides with the magnetopause current layer, indicating that the magnetosheath electrons are heated in the current layer. Both magnetosheath-MSBL and MSBL-LLBL transitions are observed for low as well as high magnetic shears. Moreover, the transitions are particularly clear for low shear implying that magnetic topology boundaries are sharp even when abrupt changes in the field and other plasma parameters are absent. Furthermore, for low magnetic shear, solar wind ions with low parallel drift speeds make up the majority of the LLBL population indicating that the magnetosheath plasma has convected directly across the magnetosheath plasma has converted directly across the magnetopause. These observations are consistent with quasi-steady, high-latitude reconnection and indicate that the signatures of this reconnection geometry are commonly present in the subpolar region.

Superconducting Metallic Glass Transition-Edge-Sensors

NASA Technical Reports Server (NTRS)

Hays, Charles C. (Inventor)

2013-01-01

A superconducting metallic glass transition-edge sensor (MGTES) and a method for fabricating the MGTES are provided. A single-layer superconducting amorphous metal alloy is deposited on a substrate. The single-layer superconducting amorphous metal alloy is an absorber for the MGTES and is electrically connected to a circuit configured for readout and biasing to sense electromagnetic radiation.

Predicting Boundary-Layer Transition on Space-Shuttle Re-Entry

NASA Technical Reports Server (NTRS)

Berry, Scott; Horvath, Tom; Merski, Ron; Liechty, Derek; Greene, Frank; Bibb, Karen; Buck, Greg; Hamilton, Harris; Weilmuenster, Jim; Campbell, Chuck;

Direct Numerical Simulation of a Plane Transitional Wall Jet

NASA Astrophysics Data System (ADS)

Ramesh, O.; Varghese, Joel

2017-11-01

A transitional plane wall jet is studied using direct numerical simulation. The presence of an inflectional point leads to the outer layer rolling up into vortices that interacts with the inner region resulting in a double array of counter rotating vortices before breakdown into turbulence. Past studies have focused on forced wall jet which results in shorter transition region and prominent vortical structures. In the present work, natural transition will be discussed by analysing the coherent structures and scaled frequency spectra. Clear hairpin like structures leaning downstream in the inner region(as in a boundary layer) and leaning upstream in the outerstream (as in a jet) are evident.

Boundary-layer transition on a flared cone in a Mach 6 quiet wind tunnel

NASA Astrophysics Data System (ADS)

Hofferth, Jerrod; Saric, William

2010-11-01

The Mach 6 Quiet Tunnel at Texas A&M is a low-disturbance blowdown facility suitable for boundary-layer stability and transition research. Following its reactivation in 2009, initial testing confirmed the presence of low-disturbance (< 0.1% Pt^'/Pt) freestream flow at select locations on the centerline of the nozzle for settling chamber pressures up to 10 atm, and a fully-traversed freestream flow-quality assessment is currently underway. As a third performance benchmark to complement these direct measurements, the present work measures the transition location on the NASA Langley 93-10 flared-cone model. This model has a 0.5m length, beginning as a 5^o half-angle circular cone. At the X=254mm station, a flare of surface radius 2.35m begins which is intended to induce transition within the quiet test core. Boundary-layer transition is detected on the thin-walled model by an observed surface temperature rise using an array of 51 embedded thermocouples. Transition data are presented for a sharp (2.5 μm) nose-tip radius case for comparison with the Lachowicz & Chokani (1996 data). Data for larger-radius nose-tips are also presented.

Resolution requirements for numerical simulations of transition

NASA Technical Reports Server (NTRS)

Zang, Thomas A.; Krist, Steven E.; Hussaini, M. Yousuff

1989-01-01

The resolution requirements for direct numerical simulations of transition to turbulence are investigated. A reliable resolution criterion is determined from the results of several detailed simulations of channel and boundary-layer transition.

Natural laminar flow flight experiments on a swept wing business jet-boundary layer stability analyses

NASA Technical Reports Server (NTRS)

Rozendaal, R. A.

1986-01-01

The linear boundary layer stability analyses and their correlation with data of 18 cases from a natural laminar flow (NLF) flight test program using a Cessna Citation 3 business jet are described. The transition point varied from 5% to 35% chord for these conditions, and both upper and lower wing surfaces were included. Altitude varied from 10,000 to 43,000 ft and Mach number from 0.3 to 0.8. Four cases were at nonzero sideslip. Although there was much scatter in the results, the analyses of boundary layer stability at the 18 conditions led to the conclusion that crossflow instability was the primary cause of transition. However, the sideslip cases did show some interaction of crossflow and Tollmien-Schlichting disturbances. The lower surface showed much lower Tollmien-Schlichting amplification at transition than the upper surface, but similar crossflow amplifications. No relationship between Mach number and disturbance amplification at transition could be found. The quality of these results is open to question from questionable wing surface quality, inadequate density of transition sensors on the wing upper surface, and an unresolved pressure shift in the wing pressure data. The results of this study show the need for careful preparation for transition experiments. Preparation should include flow analyses of the test surface, boundary layer disturbance amplification analyses, and assurance of adequate surface quality in the test area. The placement of necessary instruments and usefulness of the resulting data could largely be determined during the pretest phase.

Effects of Periodic Unsteady Wake Flow and Pressure Gradient on Boundary Layer Transition Along the Concave Surface of a Curved Plate. Part 3

NASA Technical Reports Server (NTRS)

Schobeiri, M. T.; Radke, R. E.

1996-01-01

Boundary layer transition and development on a turbomachinery blade is subjected to highly periodic unsteady turbulent flow, pressure gradient in longitudinal as well as lateral direction, and surface curvature. To study the effects of periodic unsteady wakes on the concave surface of a turbine blade, a curved plate was utilized. On the concave surface of this plate, detailed experimental investigations were carried out under zero and negative pressure gradient. The measurements were performed in an unsteady flow research facility using a rotating cascade of rods positioned upstream of the curved plate. Boundary layer measurements using a hot-wire probe were analyzed by the ensemble-averaging technique. The results presented in the temporal-spatial domain display the transition and further development of the boundary layer, specifically the ensemble-averaged velocity and turbulence intensity. As the results show, the turbulent patches generated by the wakes have different leading and trailing edge velocities and merge with the boundary layer resulting in a strong deformation and generation of a high turbulence intensity core. After the turbulent patch has totally penetrated into the boundary layer, pronounced becalmed regions were formed behind the turbulent patch and were extended far beyond the point they would occur in the corresponding undisturbed steady boundary layer.

PLIF Visualization of Active Control of Hypersonic Boundary Layers Using Blowing

NASA Technical Reports Server (NTRS)

Bathel, Brett F.; Danehy, Paul M.; Inman, Jennifer A.; Alderfer, David W.; Berry, Scott A.

2008-01-01

Planar laser-induced fluorescence (PLIF) imaging was used to visualize the boundary layer flow on a 1/3-scale Hyper-X forebody model. The boundary layer was perturbed by blowing out of orifices normal to the model surface. Two blowing orifice configurations were used: a spanwise row of 17-holes spaced at 1/8 inch, with diameters of 0.020 inches and a single-hole orifice with a diameter of 0.010 inches. The purpose of the study was to visualize and identify laminar and turbulent structures in the boundary layer and to make comparisons with previous phosphor thermography measurements of surface heating. Jet penetration and its influence on the boundary layer development was also examined as was the effect of a compression corner on downstream boundary layer transition. Based upon the acquired PLIF images, it was determined that global surface heating measurements obtained using the phosphor thermography technique provide an incomplete indicator of transitional and turbulent behavior of the corresponding boundary layer flow. Additionally, the PLIF images show a significant contribution towards transition from instabilities originating from the underexpanded jets. For this experiment, a nitric oxide/nitrogen mixture was seeded through the orifices, with nitric oxide (NO) serving as the fluorescing gas. The experiment was performed in the 31-inch Mach 10 Air Tunnel at NASA Langley Research Center.

Summary of past experience in natural laminar flow and experimental program for resilient leading edge

NASA Technical Reports Server (NTRS)

Carmichael, B. H.

1979-01-01

The potential of natural laminar flow for significant drag reduction and improved efficiency for aircraft is assessed. Past experience with natural laminar flow as reported in published and unpublished data and personal observations of various researchers is summarized. Aspects discussed include surface contour, waviness, and smoothness requirements; noise and vibration effects on boundary layer transition, boundary layer stability criteria; flight experience with natural laminar flow and suction stabilized boundary layers; and propeller slipstream, rain, frost, ice and insect contamination effects on boundary layer transition. The resilient leading edge appears to be a very promising method to prevent leading edge insect contamination.

Viscous drag reduction in boundary layers

NASA Technical Reports Server (NTRS)

Bushnell, Dennis M. (Editor); Hefner, Jerry N. (Editor)

1990-01-01

The present volume discusses the development status of stability theory for laminar flow control design, applied aspects of laminar-flow technology, transition delays using compliant walls, the application of CFD to skin friction drag-reduction, active-wave control of boundary-layer transitions, and such passive turbulent-drag reduction methods as outer-layer manipulators and complex-curvature concepts. Also treated are such active turbulent drag-reduction technique applications as those pertinent to MHD flow drag reduction, as well as drag reduction in liquid boundary layers by gas injection, drag reduction by means of polymers and surfactants, drag reduction by particle addition, viscous drag reduction via surface mass injection, and interactive wall-turbulence control.

Tomographic PIV investigation of roughness-induced transition in a hypersonic boundary layer

NASA Astrophysics Data System (ADS)

Avallone, F.; Ye, Q.; Schrijer, F. F. J.; Scarano, F.; Cardone, G.

2014-11-01

The disturbance generated by roughness elements in a hypersonic laminar boundary layer is investigated, with attention to its three-dimensional properties. The transition of the boundary layer is inspected with tomographic particle image velocimetry that is applied for the first time at Mach 7.5 inside a short duration hypersonic wind tunnel. A low aspect ratio cylindrical roughness element is installed on a flat plate, and experiments are conducted downstream of the element describing the mean velocity field and the turbulent fluctuations. Details of the experimental procedure needed to realize these measurements are discussed, along with the fluid dynamic behaviour of the perturbed hypersonic boundary layer.

Hypersonic Boundary Layer Stability Experiments in a Quiet Wind Tunnel with Bluntness Effects

NASA Technical Reports Server (NTRS)

Lachowicz, Jason T.; Chokani, Ndaona

1996-01-01

Hypersonic boundary layer measurements over a flared cone were conducted in a Mach 6 quiet wind tunnel at a freestream unit Reynolds number of 2.82 million/ft. This Reynolds number provided laminar-to-transitional flow over the cone model in a low-disturbance environment. Four interchangeable nose-tips, including a sharp-tip, were tested. Point measurements with a single hot-wire using a novel constant voltage anemometer were used to measure the boundary layer disturbances. Surface temperature and schlieren measurements were also conducted to characterize the transitional state of the boundary layer and to identify instability modes. Results suggest that second mode disturbances were the most unstable and scaled with the boundary layer thickness. The second mode integrated growth rates compared well with linear stability theory in the linear stability regime. The second mode is responsible for transition onset despite the existence of a second mode subharmonic. The subharmonic disturbance wavelength also scales with the boundary layer thickness. Furthermore, the existence of higher harmonics of the fundamental suggests that nonlinear disturbances are not associated with 'high' free stream disturbance levels. Nose-tip radii greater than 2.7% of the base radius completely stabilized the second mode.

Numerical modeling of the transitional boundary layer over a flat plate

NASA Astrophysics Data System (ADS)

Ivanov, Dimitry; Chorny, Andrei

2015-11-01

Our example is connected with fundamental research on understanding how an initially laminar boundary layer becomes turbulent. We have chosen the flow over a flat plate as a prototype for boundary-layer flows around bodies. Special attention was paid to the near-wall region in order to capture all levels of the boundary layer. In this study, the numerical software package OpenFOAM has been used in order to solve the flow field. The results were used in a comparative study with data obtained from Large Eddy Simulation (LES). The composite SGS-wall model is presently incorporated into a computer code suitable for the LES of developing flat-plate boundary layers. Presently this model is extended to the LES of the zero-pressure gradient, flat-plate turbulent boundary layer. In current study the time discretization is based on a second order Crank-Nicolson/Adams-Bashforth method. LES solver using Smagorinsky and the one-equation LES turbulence models. The transition models significantly improve the prediction of the onset location compared to the fully turbulent models.LES methods appear to be the most promising new tool for the design and analysis of flow devices including transition regions of the turbulent flow.

Boundary-layer transition and displacement thickness effects on zero-lift drag of a series of power-law bodies at Mach 6

NASA Technical Reports Server (NTRS)

Ashby, G. C., Jr.; Harris, J. E.

1974-01-01

Wave and skin-friction drag have been numerically calculated for a series of power-law bodies at a Mach number of 6 and Reynolds numbers, based on body length, from 1.5 million to 9.5 million. Pressure distributions were computed on the nose by the inverse method and on the body by the method of characteristics. These pressure distributions and the measured locations of boundary-layer transition were used in a nonsimilar-boundary-layer program to determine viscous effects. A coupled iterative approach between the boundary-layer and pressure-distribution programs was used to account for boundary-layer displacement-thickness effects. The calculated-drag coefficients compared well with previously obtained experimental data.

Study of boundary-layer transition using transonic-cone preston tube data

NASA Technical Reports Server (NTRS)

Reed, T. D.; Moretti, P. M.

1980-01-01

The laminar boundary layer on a 10 degree cone in a transonic wind tunnel was studied. The inviscid flow and boundary layer development were simulated by computer programs. The effects of pitch and yaw angles on the boundary layer were examined. Preston-tube data, taken on the boundary-layer-transition cone in the NASA Ames 11 ft transonic wind tunnel, were used to develope a correlation which relates the measurements to theoretical values of laminar skin friction. The recommended correlation is based on a compressible form of the classical law-of-the-wall. The computer codes successfully simulates the laminar boundary layer for near-zero pitch and yaw angles. However, in cases of significant pitch and/or yaw angles, the flow is three dimensional and the boundary layer computer code used here cannot provide a satisfactory model. The skin-friction correlation is thought to be valid for body geometries other than cones.

Predictions of Separated and Transitional Boundary Layers Under Low-Pressure Turbine Airfoil Conditions Using an Intermittency Transport Equation

NASA Technical Reports Server (NTRS)

Suzen, Y. Bora; Huang, P. G.; Hultgren, Lennart S.; Ashpis, David E.

2001-01-01

A new transport equation for the intermittency factor was proposed to predict separated and transitional boundary layers under low-pressure turbine airfoil conditions. The intermittent behavior of the transitional flows is taken into account and incorporated into computations by modifying the eddy viscosity, mu(sub t), with the intermittency factor, gamma. Turbulent quantities are predicted by using Menter's two-equation turbulence model (SST). The intermittency factor is obtained from a transport equation model, which not only can reproduce the experimentally observed streamwise variation of the intermittency in the transition zone, but also can provide a realistic cross-stream variation of the intermittency profile. In this paper, the intermittency model is used to predict a recent separated and transitional boundary layer experiment under low pressure turbine airfoil conditions. The experiment provides detailed measurements of velocity, turbulent kinetic energy and intermittency profiles for a number of Reynolds numbers and freestream turbulent intensity conditions and is suitable for validation purposes. Detailed comparisons of computational results with experimental data are presented and good agreements between the experiments and predictions are obtained.

Predictions of Separated and Transitional Boundary Layers Under Low-Pressure Turbine Airfoil Conditions Using an Intermittency Transport Equation

NASA Technical Reports Server (NTRS)

Suzen, Y. B.; Huang, P. G.; Hultgren, Lennart S.; Ashpis, David E.

2003-01-01

A new transport equation for the intermittency factor was proposed to predict separated and transitional boundary layers under low-pressure turbine airfoil conditions. The intermittent behavior of the transitional flows is taken into account and incorporated into computations by modifying the eddy viscosity, t , with the intermittency factor, y. Turbulent quantities are predicted by using Menter s two-equation turbulence model (SST). The intermittency factor is obtained from a transport equation model, which not only can reproduce the experimentally observed streamwise variation of the intermittency in the transition zone, but also can provide a realistic cross-stream variation of the intermittency profile. In this paper, the intermittency model is used to predict a recent separated and transitional boundary layer experiment under low pressure turbine airfoil conditions. The experiment provides detailed measurements of velocity, turbulent kinetic energy and intermittency profiles for a number of Reynolds numbers and freestream turbulent intensity conditions and is suitable for validation purposes. Detailed comparisons of computational results with experimental data are presented and good agreements between the experiments and predictions are obtained.

High-Speed Boundary-Layer Transition: Study of Stationary Crossflow Using Spectral Analysis

NASA Astrophysics Data System (ADS)

McGuire, Patrick Joseph

Crossflow instability is primary cause of boundary-layer transition on swept wings used in high-speed applications. Delaying the downstream location of transition would drastically reduce the viscous drag over the wing surface, and subsequently improves the overall aircraft efficiency. By studying the development of instability growth rates and how they interact with the surroundings, researchers can control the crossflow transition location. Experiments on the 35° swept-wing model were performed in the NASA Langley 20-Inch Supersonic Wind Tunnel with Mach 2.0 flow conditions and 20 μm tall discrete roughness elements (DRE) with varying spacing placed along the leading edge. Fluorene was used as the sublimating chemical in the surface flow visualization technique to observe the transition front and stationary crossflow vortex patterns in the laminar flow region. Spatial spectral decomposition was completed on high-resolution images of sublimating chemical runs using a newly developed image processing technique. Streamwise evolution of the vortex track wavelengths within the laminar boundary-layer region was observed. The spectral information was averaged to produce dominant modes present throughout the laminar region.

Boundary-layer instability & transition on a flared cone in a Mach 6 quiet wind tunnel

NASA Astrophysics Data System (ADS)

Hofferth, Jerrod; Saric, William

2011-11-01

Measurements of boundary-layer transition location and instability growth on a sharp-tipped 5°-half-angle flared cone were conducted in a low-disturbance Mach 6 wind tunnel at a freestream unit Reynolds number of 10 × 106/m. Under quiet flow at these conditions, the boundary layer becomes transitional near the base of the cone, where significant second-mode instability growth is evident. Transition location is determined using an array of embedded thermocouples, and instability development is observed in mean and fluctuating mass flux data using hotwire anemometry. The present work seeks to reproduce and build upon previous experiments which used the same test article and similar diagnostics in the facility's former installation at NASA Langley. Together with comprehensive measurements of the freestream disturbance environment, these baseline cone data characterize the facility's performance relative to that in its previous installation. In addition, the current campaign establishes experimental readiness for future research, which will study the effects of periodic surface roughness and controlled-input disturbances. AFOSR/NASA National Center for Hypersonic Research in Laminar-Turbulent Transition; Grant FA9550-09-1-0341.

Analysis of Crossflow Transition Flight Experiment aboard the Pegasus Launch Vehicle

NASA Technical Reports Server (NTRS)

Malik, Mujeeb R.; Li, Fei; Choudhan, Meelan

2007-01-01

The Pegasus wing-glove flight experiment was designed to provide crossflow transition data at high Mach numbers, specifically to help validate stability based predictions for transition onset in a flight environment. This paper provides an analysis of the flight experiment, with emphasis on computational results for crossflow disturbances and the correlation of disturbance growth factors with in-flight transition locations via the e(sup N) method. Implications of the flight data for attachment line stability are also examined. Analysis of the thermocouple data reveals that transition (from turbulent to laminar flow) was first detected during the ascending flight of the rocket when the free stream Mach number exceeded about 4. Therefore, computations have been performed for flight Mach numbers of 4.13, 4.35, 4.56 and 4.99. Due to continually decreasing unit Reynolds number at higher altitudes, the entire wing-glove boundary layer became laminar at the highest flight Mach number computed above. In contrast, the boundary layer flow over the inboard tile region remained transitional up to and somewhat beyond the time of laminarization over the instrumented glove region. Linear stability predictions confirmed that the tile boundary layer is indeed more unstable to crossflow disturbances than the much colder stainless steel glove boundary layer. The transition locations based on thermocouple data from both the glove and the tile regions are found to correlate with stationary-crossflow N-factors within the range of 7 to 12.4 and with traveling mode N-factors between 7.6 and 14.1. Data from the thermocouples and hot film sensors indicates that transition from turbulent to laminar flow (i.e., laminarization) at a fixed point over the glove is generally completed within a flight time interval of 3 seconds. However, the times at which transition begins and ends as inferred from the hot film sensors are found to differ by about 2 seconds from the corresponding estimates based on the thermocouple data.

Thermal phase transition behavior of lipid layers on a single human corneocyte cell.

PubMed

Imai, Tomohiro; Nakazawa, Hiromitsu; Kato, Satoru

2013-09-01

We have improved the selected area electron diffraction method to analyze the dynamic structural change in a single corneocyte cell non-invasively stripped off from human skin surface. The improved method made it possible to obtain reliable diffraction images to trace the structural change in the intercellular lipid layers on a single corneocyte cell during heating from 24°C to 100°C. Comparison of the results with those of synchrotron X-ray diffraction experiments on human stratum corneum sheets revealed that the intercellular lipid layers on a corneocyte cell exhibit essentially the same thermal phase transitions as those in a stratum corneum sheet. These results suggest that the structural features of the lipid layers are well preserved after the mechanical stripping of the corneocyte cell. Moreover, electron diffraction analyses of the thermal phase transition behaviors of the corneocyte cells that had the lipid layers with different distributions of orthorhombic and hexagonal domains at 24°C suggested that small orthorhombic domains interconnected with surrounding hexagonal domains transforms in a continuous manner into new hexagonal domains. Copyright © 2013 Elsevier Ireland Ltd. All rights reserved.

Development of Modal Analysis for the Study of Global Modes in High Speed Boundary Layer Flows

NASA Astrophysics Data System (ADS)

Brock, Joseph Michael

Boundary layer transition for compressible flows remains a challenging and unsolved problem. In the context of high-speed compressible flow, transitional and turbulent boundary-layers produce significantly higher surface heating caused by an increase in skin-friction. The higher heating associated with transitional and turbulent boundary layers drives thermal protection systems (TPS) and mission trajectory bounds. Proper understanding of the mechanisms that drive transition is crucial to the successful design and operation of the next generation spacecraft. Currently, prediction of boundary-layer transition is based on experimental efforts and computational stability analysis. Computational analysis, anchored by experimental correlations, offers an avenue to assess/predict stability at a reduced cost. Classical methods of Linearized Stability Theory (LST) and Parabolized Stability Equations (PSE) have proven to be very useful for simple geometries/base flows. Under certain conditions the assumptions that are inherent to classical methods become invalid and the use of LST/PSE is inaccurate. In these situations, a global approach must be considered. A TriGlobal stability analysis code, Global Mode Analysis in US3D (GMAUS3D), has been developed and implemented into the unstructured solver US3D. A discussion of the methodology and implementation will be presented. Two flow configurations are presented in an effort to validate/verify the approach. First, stability analysis for a subsonic cylinder wake is performed and results compared to literature. Second, a supersonic blunt cone is considered to directly compare LST/PSE analysis and results generated by GMAUS3D.

Single-Column Model Simulations of Subtropical Marine Boundary-Layer Cloud Transitions Under Weakening Inversions

NASA Astrophysics Data System (ADS)

Neggers, R. A. J.; Ackerman, A. S.; Angevine, W. M.; Bazile, E.; Beau, I.; Blossey, P. N.; Boutle, I. A.; de Bruijn, C.; Cheng, A.; van der Dussen, J.; Fletcher, J.; Dal Gesso, S.; Jam, A.; Kawai, H.; Cheedela, S. K.; Larson, V. E.; Lefebvre, M.-P.; Lock, A. P.; Meyer, N. R.; de Roode, S. R.; de Rooy, W.; Sandu, I.; Xiao, H.; Xu, K.-M.

2017-10-01

Results are presented of the GASS/EUCLIPSE single-column model intercomparison study on the subtropical marine low-level cloud transition. A central goal is to establish the performance of state-of-the-art boundary-layer schemes for weather and climate models for this cloud regime, using large-eddy simulations of the same scenes as a reference. A novelty is that the comparison covers four different cases instead of one, in order to broaden the covered parameter space. Three cases are situated in the North-Eastern Pacific, while one reflects conditions in the North-Eastern Atlantic. A set of variables is considered that reflects key aspects of the transition process, making use of simple metrics to establish the model performance. Using this method, some longstanding problems in low-level cloud representation are identified. Considerable spread exists among models concerning the cloud amount, its vertical structure, and the associated impact on radiative transfer. The sign and amplitude of these biases differ somewhat per case, depending on how far the transition has progressed. After cloud breakup the ensemble median exhibits the well-known "too few too bright" problem. The boundary-layer deepening rate and its state of decoupling are both underestimated, while the representation of the thin capping cloud layer appears complicated by a lack of vertical resolution. Encouragingly, some models are successful in representing the full set of variables, in particular, the vertical structure and diurnal cycle of the cloud layer in transition. An intriguing result is that the median of the model ensemble performs best, inspiring a new approach in subgrid parameterization.

Hairpin vortices in turbulent boundary layers

NASA Astrophysics Data System (ADS)

Eitel-Amor, G.; Örlü, R.; Schlatter, P.; Flores, O.

2015-02-01

The present work presents a number of parallel and spatially developing simulations of boundary layers to address the question of whether hairpin vortices are a dominant feature of near-wall turbulence, and which role they play during transition. In the first part, the parent-offspring regeneration mechanism is investigated in parallel (temporal) simulations of a single hairpin vortex introduced in a mean shear flow corresponding to either turbulent channels or boundary layers (Reτ ≲ 590). The effect of a turbulent background superimposed on the mean flow is considered by using an eddy viscosity computed from resolved simulations. Tracking the vortical structure downstream, it is found that secondary hairpins are only created shortly after initialization, with all rotational structures decaying for later times. For hairpins in a clean (laminar) environment, the decay is relatively slow, while hairpins in weak turbulent environments (10% of νt) dissipate after a couple of eddy turnover times. In the second part, the role of hairpin vortices in laminar-turbulent transition is studied using simulations of spatial boundary layers tripped by hairpin vortices. These vortices are generated by means of specific volumetric forces representing an ejection event, creating a synthetic turbulent boundary layer initially dominated by hairpin-like vortices. These hairpins are advected towards the wake region of the boundary layer, while a sinusoidal instability of the streaks near the wall results in rapid development of a turbulent boundary layer. For Reθ > 400, the boundary layer is fully developed, with no evidence of hairpin vortices reaching into the wall region. The results from both the parallel and spatial simulations strongly suggest that the regeneration process is rather short-lived and may not sustain once a turbulent background is developed. From the transitional flow simulations, it is conjectured that the forest of hairpins reported in former direct numerical simulation studies is reminiscent of the transitional boundary layer and may not be connected to some aspects of the dynamics of the fully developed wall-bounded turbulence.

Results of thermal modeling of Smart Energy Coating with phase-transition material for independent electricity generation

NASA Astrophysics Data System (ADS)

Pospelova, I. Y.; Pospelova, M. Y.; Bondarenko, A. S.; Kornilov, D. A.

2018-05-01

The modeling for Smart Energy Coating is presented. The coating is able to produce electricity on the surface of pipelines and structural elements. Along with electric output, Smart Energy Coating ensures the stable temperature conditions of work for structures, pipelines and regulating elements. The energy production scheme is based on the Peltier principle and the insulating layer with a phase transition. Thermally conductive inclusions of the inside layer with a phase transition material ensure the stable operation of the Peltier element.

High Infrared Blocking Cellulose Film Based on Amorphous to Anatase Transition of TiO2 via Atomic Layer Deposition.

PubMed

Li, Wenbin; Li, Linfeng; Wu, Xi; Li, Junyu; Jiang, Lang; Yang, Hongjun; Ke, Guizhen; Cao, Genyang; Deng, Bo; Xu, Weilin

2018-06-27

A high IR-blocking cellulose film was designed based on an amorphous to anatase transition of TiO 2 using atomic layer deposition (ALD). This transition was realized at 250 °C, at which the cellulose is thermal stable. Optimized ALD condition of 250 °C and 1200 cycles give us an excellent heat insulator, which could significantly reduce the enclosed space temperature from 59.2 to 51.9 °C after exposure to IR lamp for 5 min.

Analysis of Windward Side Hypersonic Boundary Layer Transition on Blunted Cones at Angle of Attack

DTIC Science & Technology

2017-01-09

AIAA-95-2294 , 1995. 6Wadhams, T. P., MacLean, M. G., Holden, M. S., and Mundy, E., “ Pre -Flight Ground Testing of the Full-Scale FRESH FX-1 at...correlated with PSE/LST N-Factors. 15. SUBJECT TERMS boundary layer transition, hypersonic, ground test 16. SECURITY CLASSIFICATION OF: 17. LIMITATION...movement of the windward transition front on a sharp and 6% blunt cones, but upstream movement for a 21% blunt cone at M = 11 and 13. Tests of the HIFiRE

Effect of stress nonhomogeneity on the shear melting of a thin boundary lubrication layer.

PubMed

Lyashenko, Iakov A; Filippov, Alexander E; Popov, Mikhail; Popov, Valentin L

2016-11-01

We consider the dynamical properties of boundary lubrication in contact between two atomically smooth solid surfaces separated by an ultrathin layer of lubricant. In contrast to previous works on this topic, we explicitly consider the heterogeneity of tangential stresses, which arises in a contact of elastic bodies that are moved tangentially relative to each other. To describe phase transitions between structural states of the lubricant we use an approach based on the field theory of phase transitions. It is assumed that the lubricant layer, when stressed, can undergo a shear-melting transition of first or second order. While solutions for the homogeneous system can be easily obtained analytically, the kinetics of the phase transitions in the spatially heterogeneous system can only be studied numerically. In our numerical experiments melting of the lubricant layer starts from the outer boundary of contact and propagates to its center. The melting wave is followed by a wave of solidification. This process repeats itself periodically, following the stick-slip pattern that is characteristic of such systems. Depending on the thermodynamic and kinetic parameters of the model, different modes of sliding with almost complete or only partial intermediate solidification are possible.

Electronic transitions and band offsets in C60:SubPc and C60:MgPc on MoO3 studied by modulated surface photovoltage spectroscopy

NASA Astrophysics Data System (ADS)

Fengler, S.; Dittrich, Th.; Rusu, M.

2015-07-01

Electronic transitions at interfaces between MoO3 layers and organic layers of C60, SubPc, MgPc, and nano-composite layers of SubPc:C60 and MgPc:C60 have been studied by modulated surface photovoltage (SPV) spectroscopy. For all systems, time dependent and modulated SPV signals pointed to dissociation of excitons at the MoO3/organic layer interfaces with a separation of holes towards MoO3. The highest occupied molecular orbital (HOMO)-lowest unoccupied molecular orbital (LUMO) gaps (EHL) of C60, SubPc, and MgPc and the effective EHL of SubPc:C60 and MgPc:C60 were measured. The offsets between the LUMO (ΔEL) or HOMO (ΔEH) bands were obtained with high precision and amounted to 0.33 or 0.73 eV for SubPc:C60, respectively, and to -0.33 or 0.67 eV for MgPc:C60, respectively. Exponential tails below EHL and most pronounced sub-bandgap transitions were characterized and ascribed to disorder and transitions from HOMO bands to unoccupied defect states.

Experimental Investigation of Transition to Turbulence as Affected By Passing Wakes

NASA Technical Reports Server (NTRS)

Kaszeta, Richard W.; Ashpis, David E.; Simon, Terrence W.

2001-01-01

This paper presents experimental results from a study of the effects of periodically passing wakes upon laminar-to-turbulent transition and separation in a low-pressure turbine passage. The test section geometry is designed to simulate unsteady wakes in turbine engines for studying their effects on boundary layers and separated flow regions over the suction surface by using a single suction surface and a single pressure surface to simulate a single turbine blade passage. Single-wire, thermal anemometry techniques are used to measure time-resolved and phase averaged, wall-normal profiles of velocity, turbulence intensity and intermittency at multiple streamwise locations over the turbine airfoil suction surface. These data are compared to steady-state wake-free data collected in the same geometry to identify the effects of wakes upon laminar-to-turbulent transition. Results are presented for flows with a Reynolds number based on suction surface length and stage exit velocity of 50,000 and an approach flow turbulence intensity of 2.5%. While both existing design and experimental data are primarily concerned with higher Reynolds number flows (Re greater than 100,000), recent advances in gas turbine engines, and the accompanying increase in laminar and transitional flow effects, have made low-Re research increasingly important. From the presented data, the effects of passing wakes on transition and separation in the boundary layer, due to both increased turbulence levels and varying streamwise pressure gradients are presented. The results show how the wakes affect transition. The wakes affect the flow by virtue of their difference in turbulence levels and scales from those of the free-stream and by virtue of their ensemble- averaged velocity deficits, relative to the free-stream velocity, and the concomitant changes in angle of attack and temporal pressure gradients. The relationships between the velocity oscillations in the freestream and the unsteady velocity profile shapes in the near-wall flow are described. In this discussion is support for the theory that bypass transition is a response of the near-wall viscous layer to pressure fluctuations imposed upon it from the free-stream flow. Recent transition models are based on that premise. The data also show a significant lag between when the wake is present over the surface and when transition begins.cous layer to pressure fluctuations imposed upon it from the free-stream flow. Recent transition models are based on that premise. The data also show a significant lag between when the wake is present over the surface and when transition begins.cous layer to pressure fluctuations imposed upon it from the free-stream flow. Recent transition models are based on that premise. The data also show a significant lag between when the wake is present over the surface and when transition begins.

The LENS Facilities and Experimental Studies to Evaluate the Modeling of Boundary Layer Transition, Shock/Boundary Layer Interaction, Real Gas, Radiation and Plasma Phenomena in Contemporary CFD Codes

DTIC Science & Technology

2010-04-01

Layer Interaction, Real Gas, Radiation and Plasma Phenomena in Contemporary CFD Codes Michael S. Holden, PhD CUBRC , Inc. 4455 Genesee Street Buffalo...NUMBER 5f. WORK UNIT NUMBER 7. PERFORMING ORGANIZATION NAME(S) AND ADDRESS(ES) CUBRC , Inc. 4455 Genesee Street Buffalo, NY 14225, USA 8. PERFORMING...HyFly Navy EMRG Reentry-F Slide 2 X-43 HIFiRE-2 Figure 17: Transition in Hypervelocity Flows: CUBRC Focus – Fully Duplicated Ground Test

Design and performance of the University of Michigan 6.6-inch hypersonic wind tunnel

NASA Technical Reports Server (NTRS)

Amick, J. L.

1975-01-01

The tunnel described has several design features intended to maintain laminar flow in the boundary layer of its nozzle. Measurements show that transition to turbulence in the nozzle wall boundary layer begins at the throat and is sensitive to surface roughness, heat transfer rate, and longitudinal radius of curvature. The observed dependence of transition on heat transfer rate is the reverse of that predicted by stability theory for infinitesimal disturbances. Tests include boundary layer surveys of a contoured nozzle and a conical nozzle with four interchangeable throats.

Numerical simulation of the control of the three-dimensional transition process in boundary layers

NASA Technical Reports Server (NTRS)

Kral, L. D.; Fasel, H. F.

1990-01-01

Surface heating techniques to control the three-dimensional laminar-turbulent transition process are numerically investigated for a water boundary layer. The Navier-Stokes and energy equations are solved using a fully implicit finite difference/spectral method. The spatially evolving boundary layer is simulated. Results of both passive and active methods of control are shown for small amplitude two-dimensional and three-dimensional disturbance waves. Control is also applied to the early stages of the secondary instability process using passive or active control techniques.

Determination of Optimal Heat-Storage Thickness of Layer for “Smart Wall” by Methods of Nonlinear Heat Conduction Equations for Phase-transition Materials

NASA Astrophysics Data System (ADS)

Pospelova, I.

2017-11-01

The article suggests an original way of keeping heat load and its compensation for a microclimate system by proposing the “Smart Wall”. The construction consists of specially combined composite materials including phase-transition materials. The method for determination of the layer thickness is proposed for a certain accumulation time. Varying the thickness and composition of the layer it is possible to achieve a low amount of the thermal conductivity coefficient and to obtain various functional characteristics of fences.

Photoreflectance study of the near-band-edge transitions of chemical vapor deposition-grown mono- and few-layer MoS{sub 2} films

DOE Office of Scientific and Technical Information (OSTI.GOV)

Lin, Kuang-I, E-mail: kilin@mail.ncku.edu.tw; Chen, Yen-Jen; Wang, Bo-Yan

2016-03-21

Room-temperature photoreflectance (PR) and reflectance (R) spectroscopy are utilized to investigate the near-band-edge transitions of molybdenum disulfide (MoS{sub 2}) thin films grown on sapphire substrates by a hot-wall chemical vapor deposition system. The layer thickness and optical properties of the MoS{sub 2} thin films are confirmed by Raman spectroscopy, atomic force microscope, and photoluminescence (PL) analysis. The B exciton shows relatively weak PL intensity in comparing with the A exciton even for monolayer MoS{sub 2} films. In the R spectrum of few‐layer MoS{sub 2}, it is not possible to clearly observe exciton related features. The PR spectra have two sharp,more » derivative-like features on a featureless background. Throughout the PR lineshape fitting, the transition energies are designated as the A and B excitons at the K-point of the Brillouin zone, but at room temperature there seems to be no distinguishable feature corresponding to an H‐point transition for the mono- and few-layer MoS{sub 2} films unlike in bulk. These transition energies are slightly larger than those obtained by PL, which is attributed to the Stokes shifts related to doping level. The obtained values of valence-band spin-orbit splitting are in good agreement with those from other experimental methods. By comparing the PR lineshapes, the dominant modulation mechanism is attributed to variations of the exciton transition energies due to change in the built-in electric field. On the strength of this study, PR spectroscopy is demonstrated as a powerful technique for characterizing the near-band-edge transitions of MoS{sub 2} from monolayer to bulk.« less

Tuning interfacial exchange interactions via electronic reconstruction in transition-metal oxide heterostructures

DOE PAGES

Li, Binzhi; Chopdekar, Rajesh V.; N'Diaye, Alpha T.; ...

2016-10-10

The impact of interfacial electronic reconstruction on the magnetic characteristics of La0.7Sr0.3CoO3 (LSCO)/La0.7Sr0.3MnO3 (LSMO) superlattices was investigated as a function of layer thickness using a combination of soft x-ray magnetic spectroscopy and bulk magnetometry. We found that the magnetic properties of the LSCO layers are impacted by two competing electronic interactions occurring at the LSCO/substrate and LSMO/LSCO interfaces. For thin LSCO layers (< 5 nm), the heterostructures exist in a highly coupled state where the chemically distinct layers behave as a single magnetic compound with magnetically active Co2+ ions. As the LSCO thickness increases, a high coercivity LSCO layer developsmore » which biases a low coercivity layer, which is composed not only of the LSMO layer, but also an interfacial LSCO layer. These results suggest a new route to tune the magnetic properties of transition metal oxide heterostructures through careful control of the interface structure.« less

Observations of the Early Morning Boundary-Layer Transition with Small Remotely-Piloted Aircraft

NASA Astrophysics Data System (ADS)

Wildmann, Norman; Rau, Gerrit Anke; Bange, Jens

2015-12-01

A remotely-piloted aircraft (RPA), equipped with a high resolution thermodynamic sensor package, was used to investigate physical processes during the morning transition of the atmospheric boundary layer over land. Experiments were conducted at a test site in heterogeneous terrain in south-west Germany on 5 days from June to September 2013 in an evolving shallow convective boundary layer, which then developed into a well-mixed layer later in the day. A combination of vertical profiling and constant-altitude profiling (CAP) at 100 m height above ground level was chosen as the measuring strategy throughout the experiment. The combination of flight strategies allows the application of mixed-layer scaling using the boundary-layer height z_i, convective velocity scale w_* and convective temperature scale θ _*. The hypothesis that mixed-layer theory is valid during the whole transition was not confirmed for all parameters. A good agreement is found for temperature variances, especially in the upper half of the boundary layer, and the normalized heat-flux profile. The results were compared to a previous study with the helicopter-borne turbulence probe Helipod, and it was found that similar data quality can be achieved with the RPA. On all days, the CAP flight level was within the entrainment zone for a short time, and the horizontal variability of temperature and water vapour along the flight path is presented as an example of the inhomogeneity of layer interfaces in the boundary layer. The study serves as a case study of the possibilities and limitations with state-of-the-art RPA technology in micrometeorology.

Different phases of a system of hard rods on three dimensional cubic lattice

NASA Astrophysics Data System (ADS)

Vigneshwar, N.; Dhar, Deepak; Rajesh, R.

2017-11-01

We study the different phases of a system of monodispersed hard rods of length k on a cubic lattice, using an efficient cluster algorithm able to simulate densities close to the fully-packed limit. For k≤slant 4 , the system is disordered at all densities. For k=5, 6 , we find a single density-driven transition, from a disordered phase to high density layered-disordered phase, in which the density of rods of one orientation is strongly suppressed, breaking the system into weakly coupled layers. Within a layer, the system is disordered. For k ≥slant 7 , three density-driven transitions are observed numerically: isotropic to nematic to layered-nematic to layered-disordered. In the layered-nematic phase, the system breaks up into layers, with nematic order in each layer, but very weak correlation between the ordering directions of different layers. We argue that the layered-nematic phase is a finite-size effect, and in the thermodynamic limit, the nematic phase will have higher entropy per site. We expect the systems of rods in four and higher dimensions will have a qualitatively similar phase diagram.

Dynamics of the transition zone in coastal zone color scanner-sensed ocean color in the North Pacific during oceanographic spring

NASA Technical Reports Server (NTRS)

Glover, David M.; Wroblewski, J. S.; Mcclain, Charles R.

1994-01-01

A transition zone in phytoplankton concentration running across the North Pacific basin at 30 deg to 40 deg north latitude corresponds to a basin-wide front in surface chlorophyll observed in a composite of coastal zone color scanner (CZCS) images for May, June, and July 1979-1986. This transition zone with low chlorophyll to the south and higher chlorophyll to the north can be simulated by a simple model of the concentration of phytoplankton, zooplankton, and dissolved nutrient (nitrate) in the surface mixed layer of the ocean applied to the North Pacific basin for the climatological conditions during oceanographic springtime (May, June, and July). The model is initialized with a 1 deg x 1 deg gridded estimate of wintertime (February, March, and April) mixed layer nitrate concentrations calculated from an extensive nutrient database and a similarly gridded mixed layer depth data set. Comparison of model predictions with CZCS data provides a means of evaluating the dynamics of the transition zone. We conclude that in the North Pacific, away from major boundary currents and coastal upwelling zones, wintertime vertical mixing determines the total nutrient available to the plankton ecosystem in the spring. The transition zone seen in basin-scale CZCS images is a reflection of the geographic variation in the wintertime mixed layer depth and the nitracline, leading to a latitudinal gradient in phytoplankton chlorophyll.

A robust H∞ control-based hierarchical mode transition control system for plug-in hybrid electric vehicle

NASA Astrophysics Data System (ADS)

Yang, Chao; Jiao, Xiaohong; Li, Liang; Zhang, Yuanbo; Chen, Zheng

2018-01-01

To realize a fast and smooth operating mode transition process from electric driving mode to engine-on driving mode, this paper presents a novel robust hierarchical mode transition control method for a plug-in hybrid electric bus (PHEB) with pre-transmission parallel hybrid powertrain. Firstly, the mode transition process is divided into five stages to clearly describe the powertrain dynamics. Based on the dynamics models of powertrain and clutch actuating mechanism, a hierarchical control structure including two robust H∞ controllers in both upper layer and lower layer is proposed. In upper layer, the demand clutch torque can be calculated by a robust H∞controller considering the clutch engaging time and the vehicle jerk. While in lower layer a robust tracking controller with L2-gain is designed to perform the accurate position tracking control, especially when the parameters uncertainties and external disturbance occur in the clutch actuating mechanism. Simulation and hardware-in-the-loop (HIL) test are carried out in a traditional driving condition of PHEB. Results show that the proposed hierarchical control approach can obtain the good control performance: mode transition time is greatly reduced with the acceptable jerk. Meanwhile, the designed control system shows the obvious robustness with the uncertain parameters and disturbance. Therefore, the proposed approach may offer a theoretical reference for the actual vehicle controller.

Critical Transitions in Thin Layer Turbulence

NASA Astrophysics Data System (ADS)

Benavides, Santiago; Alexakis, Alexandros

2017-11-01

We investigate a model of thin layer turbulence that follows the evolution of the two-dimensional motions u2 D (x , y) along the horizontal directions (x , y) coupled to a single Fourier mode along the vertical direction (z) of the form uq (x , y , z) = [vx (x , y) sin (qz) ,vy (x , y) sin (qz) ,vz (x , y) cos (qz) ] , reducing thus the system to two coupled, two-dimensional equations. Its reduced dimensionality allows a thorough investigation of the transition from a forward to an inverse cascade of energy as the thickness of the layer H = π / q is varied.Starting from a thick layer and reducing its thickness it is shown that two critical heights are met (i) one for which the forward unidirectional cascade (similar to three-dimensional turbulence) transitions to a bidirectional cascade transferring energy to both small and large scales and (ii) one for which the bidirectional cascade transitions to a unidirectional inverse cascade when the layer becomes very thin (similar to two-dimensional turbulence). The two critical heights are shown to have different properties close to criticality that we are able to analyze with numerical simulations for a wide range of Reynolds numbers and aspect ratios. This work was Granted access to the HPC resources of MesoPSL financed by the Region Ile de France and the project Equip@Meso (reference ANR-10-EQPX-29-01).

Impact of rheological layering on rift asymmetry

NASA Astrophysics Data System (ADS)

Jaquet, Yoann; Schmalholz, Stefan M.; Duretz, Thibault

2015-04-01

Although numerous models of rift formation have been proposed, what triggers asymmetry of rifted margins remains unclear. Parametrized material softening is often employed to induce asymmetric fault patterns in numerical models. Here, we use thermo-mechanical finite element models that allow softening via thermal weakening. We investigate the importance of lithosphere rheology and mechanical layering on rift morphology. The numerical code is based on the MILAMIN solver and uses the Triangle mesh generator. Our model configuration consists of a visco-elasto-platic layered lithosphere comprising either (1) only one brittle-ductile transition (in the mantle) or (2) three brittle-ductile transitions (one in the upper crust, one in the lower crust and one in the mantle). We perform then two sets of simulations characterized by low and high extensional strain rates (5*10-15 s-1, 2*10-14 s-1). The results show that the extension of a lithosphere comprising only one brittle-ductile transition produces a symmetric 'neck' type rift. The upper and lower crusts are thinned until the lithospheric mantle is exhumed to the seafloor. A lithosphere containing three brittle-ductile transitions favors strain localization. Shear zones at different horizontal locations and generated in the brittle levels of the lithosphere get connected by the weak ductile layers. The results suggest that rheological layering of the lithosphere can be a reason for the generation of asymmetric rifting and subsequent rift morphology.

DOE Office of Scientific and Technical Information (OSTI.GOV)

Bühler, Stefan; Obrist, Dominik; Kleiser, Leonhard

We investigate numerically the effects of nozzle-exit flow conditions on the jet-flow development and the near-field sound at a diameter-based Reynolds number of Re{sub D} = 18 100 and Mach number Ma = 0.9. Our computational setup features the inclusion of a cylindrical nozzle which allows to establish a physical nozzle-exit flow and therefore well-defined initial jet-flow conditions. Within the nozzle, the flow is modeled by a potential flow core and a laminar, transitional, or developing turbulent boundary layer. The goal is to document and to compare the effects of the different jet inflows on the jet flow development and themore » sound radiation. For laminar and transitional boundary layers, transition to turbulence in the jet shear layer is governed by the development of Kelvin-Helmholtz instabilities. With the turbulent nozzle boundary layer, the jet flow development is characterized by a rapid changeover to a turbulent free shear layer within about one nozzle diameter. Sound pressure levels are strongly enhanced for laminar and transitional exit conditions compared to the turbulent case. However, a frequency and frequency-wavenumber analysis of the near-field pressure indicates that the dominant sound radiation characteristics remain largely unaffected. By applying a recently developed scaling procedure, we obtain a close match of the scaled near-field sound spectra for all nozzle-exit turbulence levels and also a reasonable agreement with experimental far-field data.« less

Optimal resource diffusion for suppressing disease spreading in multiplex networks

NASA Astrophysics Data System (ADS)

Chen, Xiaolong; Wang, Wei; Cai, Shimin; Stanley, H. Eugene; Braunstein, Lidia A.

2018-05-01

Resource diffusion is a ubiquitous phenomenon, but how it impacts epidemic spreading has received little study. We propose a model that couples epidemic spreading and resource diffusion in multiplex networks. The spread of disease in a physical contact layer and the recovery of the infected nodes are both strongly dependent upon resources supplied by their counterparts in the social layer. The generation and diffusion of resources in the social layer are in turn strongly dependent upon the state of the nodes in the physical contact layer. Resources diffuse preferentially or randomly in this model. To quantify the degree of preferential diffusion, a bias parameter that controls the resource diffusion is proposed. We conduct extensive simulations and find that the preferential resource diffusion can change phase transition type of the fraction of infected nodes. When the degree of interlayer correlation is below a critical value, increasing the bias parameter changes the phase transition from double continuous to single continuous. When the degree of interlayer correlation is above a critical value, the phase transition changes from multiple continuous to first discontinuous and then to hybrid. We find hysteresis loops in the phase transition. We also find that there is an optimal resource strategy at each fixed degree of interlayer correlation under which the threshold reaches a maximum and the disease can be maximally suppressed. In addition, the optimal controlling parameter increases as the degree of inter-layer correlation increases.

An infrared spectroscopic study of the structural phase transition in the perovskite-type layer compound [ n-C 16H 33NH 3] 2CoCl 4

NASA Astrophysics Data System (ADS)

Ning, Guo; Guangfu, Zeng; Shiquan, Xi

1992-12-01

The solid-solid phase transitions in the perovskite-type layer compound [ n-C 16H 33NH 3] 2CoCl 4 have been studied by infrared spectroscopy. A new phase transition at 340 K was found by comparison with differential scanning calorimetry results. A temperature dependence study of the infrared spectra provides evidence of the occurrence of structural phase transitions related to the dynamics of the alkylammonium ions and hydrogen bonds. The main transition at 374 K corresponds to the conformational order-disorder change in the chain, which probably couples with reorientational motions of the NH 3 polar heads. GTG or GTG' defects appear in the high temperature disordered phase.

Discrete Roughness Transition for Hypersonic Flight Vehicles

NASA Technical Reports Server (NTRS)

Berry, Scott A.; Horvath, Thomas J.

2007-01-01

The importance of discrete roughness and the correlations developed to predict the onset of boundary layer transition on hypersonic flight vehicles are discussed. The paper is organized by hypersonic vehicle applications characterized in a general sense by the boundary layer: slender with hypersonic conditions at the edge of the boundary layer, moderately blunt with supersonic, and blunt with subsonic. This paper is intended to be a review of recent discrete roughness transition work completed at NASA Langley Research Center in support of agency flight test programs. First, a review is provided of discrete roughness wind tunnel data and the resulting correlations that were developed. Then, results obtained from flight vehicles, in particular the recently flown Hyper-X and Shuttle missions, are discussed and compared to the ground-based correlations.

Superconductivity in REO0.5F0.5BiS2 with high-entropy-alloy-type blocking layers

NASA Astrophysics Data System (ADS)

Sogabe, Ryota; Goto, Yosuke; Mizuguchi, Yoshikazu

2018-05-01

We synthesized new REO0.5F0.5BiS2 (RE: rare earth) superconductors with high-entropy-alloy-type (HEA-type) REO blocking layers. The lattice constant a systematically changed in the HEA-type samples with the RE concentration and the RE ionic radius. A sharp superconducting transition was observed in the resistivity measurements for all the HEA-type samples, and the transition temperature of the HEA-type samples was higher than that of typical REO0.5F0.5BiS2. The sharp superconducting transition and the enhanced superconducting properties of the HEA-type samples may indicate the effectiveness of the HEA states of the REO blocking layers in the REO0.5F0.5BiS2 system.

Photo-modulation of the spin Hall conductivity of mono-layer transition metal dichalcogenides

DOE Office of Scientific and Technical Information (OSTI.GOV)

Sengupta, Parijat; Bellotti, Enrico

2016-05-23

We report on a possible optical tuning of the spin Hall conductivity in mono-layer transition metal dichalcogenides. Light beams of frequencies much higher than the energy scale of the system (the off-resonant condition) do not excite electrons but rearrange the band structure. The rearrangement is quantitatively established using the Floquet formalism. For such a system of mono-layer transition metal dichalcogenides, the spin Hall conductivity (calculated with the Kubo expression in presence of disorder) exhibits a drop at higher frequencies and lower intensities. Finally, we compare the spin Hall conductivity of the higher spin-orbit coupled WSe{sub 2} to MoS{sub 2}; themore » spin Hall conductivity of WSe{sub 2} was found to be larger.« less

Variable Sweep Transition Flight Experiment (VSTFE): Unified Stability System (USS). Description and Users' Manual

NASA Technical Reports Server (NTRS)

Rozendaal, Rodger A.; Behbehani, Roxanna

1990-01-01

NASA initiated the Variable Sweep Transition Flight Experiment (VSTFE) to establish a boundary layer transition database for laminar flow wing design. For this experiment, full-span upper surface gloves were fitted to a variable sweep F-14 aircraft. The development of an improved laminar boundary layer stability analysis system called the Unified Stability System (USS) is documented and results of its use on the VSTFE flight data are shown. The USS consists of eight computer codes. The theoretical background of the system is described, as is the input, output, and usage hints. The USS is capable of analyzing boundary layer stability over a wide range of disturbance frequencies and orientations, making it possible to use different philosophies in calculating the growth of disturbances on sweptwings.

Energy efficient engine, low-pressure turbine boundary layer program

NASA Technical Reports Server (NTRS)

Gardner, W. B.

1981-01-01

A study was conducted to investigate development of boundary layers under the influence of velocity distributions simulating the suction side of two state-of-the-art turbine airfoils: a forward loaded airfoil (squared-off design) and an aft loaded airfoil (aft-loaded design). These velocity distributions were simulated in a boundary layer wind tunnel. Detailed measurements of boundary layer mean velocity and turbulence intensity profiles were obtained for an inlet turbulence level of 2.4 percent and an exit Reynolds number of 800,000. Flush-mounted hot film probes identified the boundary layer transition regimes in the adverse pressure gradient regions for both velocity distributions. Wall intermittency data showed good agreement with the correlations of Dhawan and Narasimha for the intermittency factor distribution in transitional flow regimes.

Direct visualization of a two-dimensional topological insulator in the single-layer 1 T'-WT e2

NASA Astrophysics Data System (ADS)

Jia, Zhen-Yu; Song, Ye-Heng; Li, Xiang-Bing; Ran, Kejing; Lu, Pengchao; Zheng, Hui-Jun; Zhu, Xin-Yang; Shi, Zhi-Qiang; Sun, Jian; Wen, Jinsheng; Xing, Dingyu; Li, Shao-Chun

2017-07-01

We have grown nearly freestanding single-layer 1 T'-WT e2 on graphitized 6 H -SiC(0001) by using molecular beam epitaxy (MBE), and characterized its electronic structure with scanning tunneling microscopy/spectroscopy (STM/STS). The existence of topological edge states at the periphery of single-layer WT e2 islands was confirmed. Surprisingly, a bulk band gap at the Fermi level and insulating behaviors were also found in single-layer WT e2 at low temperature, which are likely associated with an incommensurate charge order transition. The realization of two-dimensional topological insulators (2D TIs) in single-layer transition-metal dichalcogenide provides a promising platform for further exploration of the 2D TIs' physics and related applications.

Computational Investigation of Supersonic Boundary Layer Transition Over Canonical Fuselage Nose Configurations

NASA Technical Reports Server (NTRS)

Choudhari, Meelan M.; Tokugawa, Naoko; Li, Fei; Chang, Chau-Lyan; White, Jeffery A.; Ishikawa, Hiroaki; Ueda, Yoshine; Atobe, Takashi; Fujii, Keisuke

2012-01-01

Boundary layer transition over axisymmetric bodies at non-zero angle of attack in supersonic flow is numerically investigated as part of joint research between the National Aeronautics and Space Administration (NASA) and Japan Aerospace Exploration Agency (JAXA). Transition over four axisymmetric bodies (namely, Sears-Haack body, semi-Sears-Haack body, 5-degree straight cone and flared cone) with different axial pressure gradients has been studied at Mach 2 in order to understand the effect of axial pressure gradient on instability amplification along the leeward symmetry plane and in the region of nonzero crossflow away from it. Comparisons are made with measured transition data in Mach 2 facilities as well as with predicted and measured transition characteristics for a 5-degree straight cone in a Mach 3.5 low disturbance tunnel. Limitations of using linear stability correlations for predicting transition over axisymmetric bodies at angle of attack are pointed out.

Numerical simulation of strong wake/boundary layer interaction

NASA Astrophysics Data System (ADS)

Ovchinnikov, Victor; Piomelli, Ugo; Choudhari, Meelan M.

2003-11-01

DNS and LES of the strong interaction between an unsteady cylinder wake and a flat-plate boundary layer are carried out. Of the two Reynolds numbers examined, in the lower Reynolds number case (Re=385 based on cylinder diameter) the boundary layer is buffeted by the vortices shed off the cylinder, but the Reynolds number is too low to trigger transition to turbulence. In contrast, in the higher Reyolds number case (Re=1155) we observe the inception of a self-sustained turbulence-generation mechanism triggered by the Karman vortex street behind the cylinder. In previously performed simulations the computational box was not long enough to extend into the turbulent region; therefore, we have lengthened the streamwise domain using a second computational box in order to capture the transition point. In addition to examining turbulence statistics, we look at the Reynolds stress budgets up to and through the transitional regime to obtain further insights into the physics of bypass transition via wake contamination.

Control of 3-D Modes in a Boundary Layer Undergoing Subharmonic Transition.

NASA Astrophysics Data System (ADS)

Corke, T. C.; Peto, J.; Speer, A.; Paroozan, P.; Sciammarella, C.

1997-11-01

The effect of alternating standing patterns of wall displacements in the transition region of a Falkner-Skan boundary layer with an adverse pressure gradient is investigated. Transition is controlled by introducing disturbances to excite a pair of oblique modes along with a plane TS mode. The oblique modes are at the TS subharmonic frequency in order to promote subharmonic resonance. Measurements consist of a spanwise rake of hot-wire sensors placed near the wall below the critical layer, and a 2-D (15 x 15) array of optical pressure sensors. The space-time data series are processed using 2-D Fourier analysis to determine the spanwise wave number content of the flow. Of particular interest is the streamwise vortex mode which results from a difference interaction of the subharmonic oblique modes. We examine the effect of different patterns and amplitudes of upstream wall displacements on the development of the travelling and stationary modes in this case leading to transition. Supported by ARO Grant No. DAAH04-93-G-0212

Strain effect in epitaxial VO2 thin films grown on sapphire substrates using SnO2 buffer layers

NASA Astrophysics Data System (ADS)

Kim, Heungsoo; Bingham, Nicholas S.; Charipar, Nicholas A.; Piqué, Alberto

2017-10-01

Epitaxial VO2/SnO2 thin film heterostructures were deposited on m-cut sapphire substrates via pulsed laser deposition. By adjusting SnO2 (150 nm) growth conditions, we are able to control the interfacial strain between the VO2 film and SnO2 buffer layer such that the semiconductor-to-metal transition temperature (TC) of VO2 films can be tuned without diminishing the magnitude of the transition. It is shown that in-plane tensile strain and out-of-plane compressive strain of the VO2 film leads to a decrease of Tc. Interestingly, VO2 films on SnO2 buffer layers exhibit a structural phase transition from tetragonal-like VO2 to tetragonal-VO2 during the semiconductor-to-metal transition. These results suggest that the strain generated by SnO2 buffer provides an effective way for tuning the TC of VO2 films.

Anisotropic dielectric phase transition triggered by pendulum-like motion coupled with proton transfer in a layered hybrid crystalline material (4-nitroanilinium+) (18-crown-6) (H2PO4-) (H3PO4)2

NASA Astrophysics Data System (ADS)

Liu, Yang; Zhu, Chun-li; Qin, Liu-lei; Zheng, Xiao-yuan; Liu, Zun-qi

2018-07-01

The organic-inorganic hybrid phase-transition material, (4-nitroanilinium+) (18-crown-6) (H2PO4-) (H3PO4)2 (1), was successfully synthesized. The organic (4-nitroanilinium) (18-crown-6)+ supramolecular cation layer and inorganic phosphate anion layer were arranged alternately. Differential scanning calorimetry (DSC), temperature-dependent dielectric measurements, and variable-temperature single-crystal X-ray diffraction analysis confirmed the reversible isostructural phase transition of 1 with the same space group Pbca at 225 K, wherein the synergistic effect between the pendulum-like motion of organic cations and the proton transfer in the Osbnd H⋯O hydrogen bonding of inorganic anions was mainly responsible for the phase-transition behavior of 1. The most striking dielectric property was the remarkable anisotropy along various crystallographic axes. A potential-energy calculation further supported the possibility of dynamic motion of cations in the crystal.

Chloride ions induce order-disorder transition at water-oxide interfaces

NASA Astrophysics Data System (ADS)

Deshmukh, Sanket; Kamath, Ganesh; Ramanathan, Shriram; Sankaranarayanan, Subramanian K. R. S.

2013-12-01

Water can form quasi-two-dimensional ordered layers near a solid interface. The solvation dynamics and ionic transport phenomena through this ordered water structure is of direct relevance to a variety of problems in interface science. Molecular dynamics simulations are used to study the impact of local fluctuation of the chloride ion density in the vicinity of an oxide surface on the structure and dynamics of water layers. We demonstrate that local increase in chloride ions beyond a threshold concentration near the water-MgO (100) interface introduces an order-disorder transition of this two-dimensional layered network into bulklike water, leading to increased diffusional characteristics and reduced hydrogen bonding lifetimes. We find that the extent of this order-disorder transition can be tuned by modifying the defect chemistry and nature of the underlying substrate. The kinetic fluidity resulting from order-disorder transition at high chloride ion concentration has significance for a broad range of phenomena, ranging from freezing point depression of brine to onset of aqueous corrosion.

Two-photon absorption in layered transition metal dichalcogenides

NASA Astrophysics Data System (ADS)

Dong, Ningning; Zhang, Saifeng; Li, Yuanxin; Wang, Jun

2018-02-01

Two-dimensional (2D) layered transition metal dichalcogenides (TMDCs) exhibit unique nonlinear optical (NLO) features and have becoming intriguing and promising candidate materials for photonic and optoelectronic devices with high performance and unique functions. Owing to layered geometry and the thickness-dependent bandgap, we studied the ultrafast NLO properties of a range of TMDCs. TMDCs with high-quality layered nanosheets were prepared through chemical vapor deposition (CVD) technique and vapor-phase growth method. Saturable absorption, two photon absorption (TPA) and two photon pumped frequency up-converted luminescence were observed from these 2D nanostructures. The exciting results open up the door to 2D photonic devices, such as passive mode-lockers, Q-switchers, optical limiters, light emitters, etc.

Gortler vortices and transition in wall boundary layers of two Mach 5 nozzles

NASA Technical Reports Server (NTRS)

Beckwith, I. E.; Holley, B. B.

1981-01-01

The onset of transition in the wall boundary layers of two axisymmetric Mach 5 wind-tunnel nozzles has been measured under conditions of extremely low incident disturbance levels. The range of test unit Reynolds numbers, based on conditions at the nozzle exit, was from 6 x 10 to the 6th power m to 2.5 x 10 to the 7th power m. When the nozzle walls were maintained in a polished and clean condition, transition moved gradually upstream as the test Reynolds number was increased. When transition occurred in the supersonic concave wall region, the values of the local Gortler parameter at transition varied from about 5 to 6, whereas the momentum thickness Reynolds number varied from about 750 to 1050. Oil flow patterns obtained near the exit of the nozzles indicated that Gortler vortices were always present when the wall boundary layers were laminar. Calculations for the growth of Gortler vortices based on new results from linear theory for supersonic flat-plate profiles gave amplification ratios to transition from e to the 4th power to e to the 15th power. Possible reasons for this wide range in amplification ratios are discussed, but no definite conclusions are yet possible regarding the values of n in a simple e to the nth power type theory for the assumed linear amplification of Gortler vortices to transition in supersonic nozzles.

X-ray radiation generated by a beam of relativistic electrons in composite structure

NASA Astrophysics Data System (ADS)

Blazhevich, S. V.; Noskov, A. V.

2018-04-01

The dynamic theory of coherent X-ray radiation generated by a beam of relativistic electrons in the three-layer structure consisting of an amorphous layer, a vacuum (air) layer and a single crystal has been developed. The phenomenon description is based on two main radiation mechanisms, namely, parametric X-ray radiation (PXR) and diffracted transition radiation (DTR). The possibility to increase the spectral-angular density of DTR under the condition of constructive interference of the transition radiation waves from different boundaries of such a structure has been demonstrated. It is shown that little changes in the layers thicknesses should not cause a considerable change in the interference picture, for example, the transition of constructive interference into destructive one. It means that in the considered process the conditions of constructive interference are enough stable to use them for increasing the intensity of X-ray source that can be created based on the interaction of relativistic electrons with such a structure.

Transition from Selective Withdrawal to Light Layer Entrainment in an Oil-Water System

NASA Astrophysics Data System (ADS)

Hartenberger, Joel; O'Hern, Timothy; Webb, Stephen; James, Darryl

2010-11-01

Selective withdrawal refers to the selective removal of fluid of one density without entraining an adjacent fluid layer of a different density. Most prior literature has examined removal of the lower density fluid and the transition to entraining the higher density fluid. In the present experiments, a higher density liquid is removed through a tube that extends just below its interface with a lower density fluid. The critical depth for a given flow rate at which the liquid-liquid interface transitions to entrain the lighter fluid was measured. Experiments were performed for a range of different light layer silicone oils and heavy layer water or brine, covering a range of density and viscosity ratios. Applications include density-stratified reservoirs and brine removal from oil storage caverns. Sandia is a multiprogram laboratory operated by Sandia Corporation, a Lockheed Martin Company, for the United States Department of Energy's National Nuclear Security Administration under contract DE-AC04-94AL85000.

Multi-layer Lanczos iteration approach to calculations of vibrational energies and dipole transition intensities for polyatomic molecules

DOE PAGES

Yu, Hua-Gen

2015-01-28

We report a rigorous full dimensional quantum dynamics algorithm, the multi-layer Lanczos method, for computing vibrational energies and dipole transition intensities of polyatomic molecules without any dynamics approximation. The multi-layer Lanczos method is developed by using a few advanced techniques including the guided spectral transform Lanczos method, multi-layer Lanczos iteration approach, recursive residue generation method, and dipole-wavefunction contraction. The quantum molecular Hamiltonian at the total angular momentum J = 0 is represented in a set of orthogonal polyspherical coordinates so that the large amplitude motions of vibrations are naturally described. In particular, the algorithm is general and problem-independent. An applicationmore » is illustrated by calculating the infrared vibrational dipole transition spectrum of CH₄ based on the ab initio T8 potential energy surface of Schwenke and Partridge and the low-order truncated ab initio dipole moment surfaces of Yurchenko and co-workers. A comparison with experiments is made. The algorithm is also applicable for Raman polarizability active spectra.« less

Optical and Excitonic Properties of Atomically Thin Transition-Metal Dichalcogenides

NASA Astrophysics Data System (ADS)

Berkelbach, Timothy C.; Reichman, David R.

2018-03-01

Starting with the isolation of a single sheet of graphene, the study of layered materials has been one of the most active areas of condensed matter physics, chemistry, and materials science. Single-layer transition-metal dichalcogenides are direct-gap semiconducting analogs of graphene that exhibit novel electronic and optical properties. These features provide exciting opportunities for the discovery of both new fundamental physical phenomena as well as innovative device platforms. Here, we review the progress associated with the creation and use of a simple microscopic framework for describing the optical and excitonic behavior of few-layer transition-metal dichalcogenides, which is based on symmetry, band structure, and the effective interactions between charge carriers in these materials. This approach provides an often quantitative account of experiments that probe the physics associated with strong electron–hole interactions in these quasi two-dimensional systems and has been successfully employed by many groups to both describe and predict emergent excitonic behavior in these layered semiconducting systems.

Infrared Imaging of Boundary Layer Transition Flight Experiments

NASA Technical Reports Server (NTRS)

Berry, Scott A.; Horvath, Thomas J., Jr.; Schwartz, Richard; Ross, Martin; Anderson, Brian; Campbell, Charles H.

2008-01-01

The Hypersonic Thermodynamic Infrared Measurement (HYTHIRM) project is presently focused on near term support to the Shuttle program through the development of an infrared imaging capability of sufficient spatial and temporal resolution to augment existing on-board Orbiter instrumentation. Significant progress has been made with the identification and inventory of relevant existing optical imaging assets and the development, maturation, and validation of simulation and modeling tools for assessment and mission planning purposes, which were intended to lead to the best strategies and assets for successful acquisition of quantitative global surface temperature data on the Shuttle during entry. However, there are longer-term goals of providing global infrared imaging support to other flight projects as well. A status of HYTHIRM from the perspective of how two NASA-sponsored boundary layer transition flight experiments could benefit by infrared measurements is provided. Those two flight projects are the Hypersonic Boundary layer Transition (HyBoLT) flight experiment and the Shuttle Boundary Layer Transition Flight Experiment (BLT FE), which are both intended for reducing uncertainties associated with the extrapolation of wind tunnel derived transition correlations for flight application. Thus, the criticality of obtaining high quality flight data along with the impact it would provide to the Shuttle program damage assessment process are discussed. Two recent wind tunnel efforts that were intended as risk mitigation in terms of quantifying the transition process and resulting turbulent wedge locations are briefly reviewed. Progress is being made towards finalizing an imaging strategy in support of the Shuttle BLT FE, however there are no plans currently to image HyBoLT.

Organization of the Tropical Convective Cloud Population by Humidity and the Critical Transition to Heavy Precipitation

NASA Astrophysics Data System (ADS)

Igel, M.

2015-12-01

The tropical atmosphere exhibits an abrupt statistical switch between non-raining and heavily raining states as column moisture increases across a wide range of length scales. Deep convection occurs at values of column humidity above the transition point and induces drying of moist columns. With a 1km resolution, large domain cloud resolving model run in RCE, what will be made clear here for the first time is how the entire tropical convective cloud population is affected by and feeds back to the pickup in heavy precipitation. Shallow convection can act to dry the low levels through weak precipitation or vertical redistribution of moisture, or to moisten toward a transition to deep convection. It is shown that not only can deep convection dehydrate the entire column, it can also dry just the lower layer through intense rain. In the latter case, deep stratiform cloud then forms to dry the upper layer through rain with anomalously high rates for its value of column humidity until both the total column moisture falls below the critical transition point and the upper levels are cloud free. Thus, all major tropical cloud types are shown to respond strongly to the same critical phase-transition point. This mutual response represents a potentially strong organizational mechanism for convection, and the frequency of and logical rules determining physical evolutions between these convective regimes will be discussed. The precise value of the point in total column moisture at which the transition to heavy precipitation occurs is shown to result from two independent thresholds in lower-layer and upper-layer integrated humidity.

Atomic Layer Deposition Alumina-Passivated Silicon Nanowires: Probing the Transition from Electrochemical Double-Layer Capacitor to Electrolytic Capacitor.

PubMed

Gaboriau, Dorian; Boniface, Maxime; Valero, Anthony; Aldakov, Dmitry; Brousse, Thierry; Gentile, Pascal; Sadki, Said

2017-04-19

Silicon nanowires were coated by a 1-5 nm thin alumina layer by atomic layer deposition (ALD) in order to replace poorly reproducible and unstable native silicon oxide by a highly conformal passivating alumina layer. The surface coating enabled probing the behavior of symmetric devices using such electrodes in the EMI-TFSI electrolyte, allowing us to attain a large cell voltage up to 6 V in ionic liquid, together with very high cyclability with less than 4% capacitance fade after 10 6 charge/discharge cycles. These results yielded fruitful insights into the transition between an electrochemical double-layer capacitor behavior and an electrolytic capacitor behavior. Ultimately, thin ALD dielectric coatings can be used to obtain hybrid devices exhibiting large cell voltage and excellent cycle life of dielectric capacitors, while retaining energy and power densities close to the ones displayed by supercapacitors.

Infrared fingerprints of few-layer black phosphorus.

PubMed

Zhang, Guowei; Huang, Shenyang; Chaves, Andrey; Song, Chaoyu; Özçelik, V Ongun; Low, Tony; Yan, Hugen

2017-01-06

Black phosphorus is an infrared layered material. Its bandgap complements other widely studied two-dimensional materials: zero-gap graphene and visible/near-infrared gap transition metal dichalcogenides. Although highly desirable, a comprehensive infrared characterization is still lacking. Here we report a systematic infrared study of mechanically exfoliated few-layer black phosphorus, with thickness ranging from 2 to 15 layers and photon energy spanning from 0.25 to 1.36 eV. Each few-layer black phosphorus exhibits a thickness-dependent unique infrared spectrum with a series of absorption resonances, which reveals the underlying electronic structure evolution and serves as its infrared fingerprints. Surprisingly, unexpected absorption features, which are associated with the forbidden optical transitions, have been observed. Furthermore, we unambiguously demonstrate that controllable uniaxial strain can be used as a convenient and effective approach to tune the electronic structure of few-layer black phosphorus. Our study paves the way for black phosphorus applications in infrared photonics and optoelectronics.

Spin polarized and density modulated phases in symmetric electron-electron and electron-hole bilayers.

PubMed

Kumar, Krishan; Moudgil, R K

2012-10-17

We have studied symmetric electron-electron and electron-hole bilayers to explore the stable homogeneous spin phase and the feasibility of inhomogeneous charge-/spin-density ground states. The former is resolved by comparing the ground-state energies in states of different spin polarizations, while the latter is resolved by searching for a divergence in the wavevector-dependent static charge/spin susceptibility. For this endeavour, we have used the dielectric approach within the self-consistent mean-field theory of Singwi et al. We find that the inter-layer interactions tend to change an abrupt spin-polarization transition of an isolated layer into a nearly gradual one, even though the partially spin-polarized phases are not clearly stable within the accuracy of our calculation. The transition density is seen to decrease with a reduction in layer spacing, implying a suppression of spin polarization by inter-layer interactions. Indeed, the suppression shows up distinctly in the spin susceptibility computed from the spin-polarization dependence of the ground-state energy. However, below a critical layer spacing, the unpolarized liquid becomes unstable against a charge-density-wave (CDW) ground state at a density preceding full spin polarization, with the transition density for the CDW state increasing on further reduction in the layer spacing. Due to attractive e-h correlations, the CDW state is found to be more pronounced in the e-h bilayer. On the other hand, the static spin susceptibility diverges only in the long-wavelength limit, which simply represents a transition to the homogeneous spin-polarized phase.

H I-to-H2 Transition Layers in the Star-forming Region W43

NASA Astrophysics Data System (ADS)

Bialy, Shmuel; Bihr, Simon; Beuther, Henrik; Henning, Thomas; Sternberg, Amiel

2017-02-01

The process of atomic-to-molecular (H I-to-H2) gas conversion is fundamental for molecular-cloud formation and star formation. 21 cm observations of the star-forming region W43 revealed extremely high H I column densities, of 120-180 {M}⊙ {{pc}}-2, a factor of 10-20 larger than predicted by H I-to-H2 transition theories. We analyze the observed H I with a theoretical model of the H I-to-H2 transition, and show that the discrepancy between theory and observation cannot be explained by the intense radiation in W43, nor be explained by variations of the assumed volume density or H2 formation rate coefficient. We show that the large observed H I columns are naturally explained by several (9-22) H I-to-H2 transition layers, superimposed along the sightlines of W43. We discuss other possible interpretations such as a non-steady-state scenario and inefficient dust absorption. The case of W43 suggests that H I thresholds reported in extragalactic observations are probably not associated with a single H I-to-H2 transition, but are rather a result of several transition layers (clouds) along the sightlines, beam-diluted with diffuse intercloud gas.

Geometric confinement effects on the metal-insulator transition temperature and stress relaxation in VO2 thin films grown on silicon

NASA Astrophysics Data System (ADS)

Viswanath, Changhyun Ko, B.; Yang, Zheng; Ramanathan, Shriram

2011-03-01

VO2 undergoes a sharp metal-insulator transition at ˜67 °C with several orders of change in conductivity and optical transmittance. Understanding and control of the properties of vanadium oxide layers grown on technologically relevant substrates such as Si (100) single crystals is therefore of great interest. In this work, we show tunability of metal-insulator transition temperature as well as recoverable stress in VO2 thin films grown on Si substrate by introducing nanoscale atomic layer deposited HfO2 interfacial layers with no degradation in the resistance ratio. For a confined VO2 film, the metal-insulator transition temperature is suppressed by ˜16 °C and the recoverable stress is 150 MPa, compared to 400 MPa for a bare film. These observations are further correlated with in situ variable temperature measurement of stress changes occurring during the phase transition. Structural and microstructural studies on the various samples have been carried out by x ray diffraction and cross-sectional transmission electron microscopy. The strategy of tuning the metal-insulator transition characteristics by nanoscale interfacial dielectrics is of broader relevance in design of programmable materials and integration into solid state devices for electronics.

Boundary-Layer Transition on the N.A.C.A. 0012 and 23012 Airfoils in the 8-Foot High-Speed Wind Tunnel, Special Report

NASA Technical Reports Server (NTRS)

Becker, John V.

1940-01-01

Determinations of boundary-layer transition on the NACA 0012 and 2301 airfoils were made in the 8-foot high-speed wind tunnel over a range of Reynolds Numbers from 1,600,000 to 16,800,000. The results are of particular significance as compared with flight tests and tests in wind tunnels of appreciable turbulence because of the extremely low turbulence in the high-speed tunnel. A comparison of the results obtained on NACA 0012 airfoils of 2-foot and 5-foot chord at the same Reynolds Number permitted an evaluation of the effect of compressibility on transition. The local skin friction along the surface of the NACA 0012 airfoil was measured at a Reynolds Number of 10,000,000. For all the lift coefficient at which tests were made, transition occurred in the region of estimated laminar separation at the low Reynolds Numbers and approach the point of minimum static pressure as a forward limit at the high Reynolds Numbers. The effect of compressibility on transition was slight. None of the usual parameters describing the local conditions in the boundary layer near the transition point served as an index for locating the transition point. As a consequence of the lower turbulence in the 8-foot high-speed tunnel, the transition points occurred consistently farther back along the chord than those measured in the NACA full-scale tunnel. An empirical relation for estimating the location of the transition point for conventional airfoils on the basis of static-pressure distribution and Reynolds Number is presented.

Highly siderophile elements and Os isotope signatures in the K-Pg transition of the Chicxulub peak-ring rocks

NASA Astrophysics Data System (ADS)

Sato, H.; Ishikawa, A.; Ferrière, L.; Morgan, J. V.; Gulick, S. P. S.

2017-12-01

The Chicxulub impact structure, located in the northern Yucatan Peninsula, Mexico, formed 66 My ago, was drilled by IODP-ICDP 364 expedition in April-May, 2016. A continuous core was successfully recovered from the peak ring from depth between 505.7 and 1334.7 mbsf. In order to determine the distribution and abundance of the projectile component in the Chicxulub peak-ring rocks, we determined highly siderophile elements (HSE: Os, Ir, Ru, Pt, Pd, and Re) concentrations and Os isotope ratio (187Os/188Os) in five samples of Unit 1G from a 75 cm-thick transitional layer between the impactites and early Paleogene rocks (616.59-617.34 mbsf interval). HSE concentrations and 187Os/188Os ratios show systematic variations across the transitional layer. The upper part (616.59-616.63 mbsf) is characterized by about one order of magnitude higher Os, Ir, and Ru contents compared to the average continental crust abundances, but much lower than for the typical Ir-enriched Cretaceous-Paleogene boundary sites (e.g., Gubbio and Caravaca). Relatively flat CI chondrite-normalized HSE patterns are observed in the upper part of the layer. Meanwhile, the HSE concentrations in the lower part of the transitional layer (617.315-617.34 mbsf) are almost equivalent to those of upper continental crust showing pronounced step CI chondrite-normalized HSE patterns (low Ir, and high Pt and Pd). 187Os/188Os and Re/Os ratios in the transitional layer gradually decrease from 0.33 to 0.25 and 35.45 to 1.14, respectively, from bottom to top. These results suggest that the projectile component, with chondritic composition, is enriched in the uppermost part of the transitional layer just below carbonate rocks that are early Paleogene in age, but could be distributed over a thicker interval than for the typical Ir-enriched sites. Further detailed studies of HSE and Os isotope compositions through the stratigraphic sequence will reveal the distribution and dilution effect of the projectile component.

What Is Happening at Spectral Type F5 in Hyades F Stars?

NASA Technical Reports Server (NTRS)

Boehm-Vitense, Erika; Robinson, Richard; Carpenter, Kenneth; Mena-Werth, Jose

2002-01-01

Aiming at a better understanding of the mechanisms heating the chromospheres, transition regions, and coronae of cool stars, we study ultraviolet, low-resolution Hubble Space Telescope/Space Telescope Imaging Spectrograph spectra of Hyades main-sequence F stars. We study the B-V dependence(s) of the chromospheric and transition layer emission line fluxes and their dependences on rotational velocities. We find that the transition layer emission line fluxes and also those of strong chromospheric lines decrease steeply between B-V = 0.42 and 0.45, i.e., at spectral type F5, for which the rotational velocities also decrease steeply. The magnitude of the line-flux decrease increases for lines of ions with increasing degree of ionization. This shows that the line-flux decrease is not due to a change in the surface filling factor but rather due to a change of the relative importance of different heating mechanisms. For early F stars with B-V < 0.42 we find for the transition layer emission lines increasing fluxes for increasing v sin i, indicating magnetohydrodynamic heating. The v sin i dependence is strongest for the high-ionization lines. On the other hand, the low chromospheric lines show no dependence on v sin i, indicating acoustic shock heating for these layers. This also contributes to the heating of the transition layers. The Mg II and Ca II lines show decreasing fluxes for increasing v sin i, as long as v sin i is less than approx. 40 km/s. The coronal X-ray emission also decreases for increasing v sin i, except for v sin i larger than approx. 100 km/s. We have at present no explanation for this behavior. For late F stars the chromospheric lines show v sin i dependences similar to those observed for early F stars, again indicating acoustic heating for these layers. We were unable to determine the v sin i dependence of the transition layer lines because of too few single star targets. The decrease of emission line fluxes at the spectral type F5, with steeply decreasing v sin i, indicates, however, a decreasing contribution of magnetohydrodynamic heating for the late F stars. The X-ray emission for the late F stars increases for increasing v sin i, indicating magnetohydrodynamic heating for the coronae of the late F stars, different from the early F stars.

Atomic-layer soft plasma etching of MoS2

PubMed Central

Xiao, Shaoqing; Xiao, Peng; Zhang, Xuecheng; Yan, Dawei; Gu, Xiaofeng; Qin, Fang; Ni, Zhenhua; Han, Zhao Jun; Ostrikov, Kostya (Ken)

2016-01-01

Transition from multi-layer to monolayer and sub-monolayer thickness leads to the many exotic properties and distinctive applications of two-dimensional (2D) MoS2. This transition requires atomic-layer-precision thinning of bulk MoS2 without damaging the remaining layers, which presently remains elusive. Here we report a soft, selective and high-throughput atomic-layer-precision etching of MoS2 in SF6 + N2 plasmas with low-energy (<0.4 eV) electrons and minimized ion-bombardment-related damage. Equal numbers of MoS2 layers are removed uniformly across domains with vastly different initial thickness, without affecting the underlying SiO2 substrate and the remaining MoS2 layers. The etching rates can be tuned to achieve complete MoS2 removal and any desired number of MoS2 layers including monolayer. Layer-dependent vibrational and photoluminescence spectra of the etched MoS2 are also demonstrated. This soft plasma etching technique is versatile, scalable, compatible with the semiconductor manufacturing processes, and may be applicable for a broader range of 2D materials and intended device applications. PMID:26813335

Mechanisms affecting the transition from shallow to deep convection over land: Inferences from observations collected at the ARM Southern Great Plains site

NASA Astrophysics Data System (ADS)

Zhang, Y.; Klein, S. A.

2009-12-01

11 years of summertime observations at the Atmospheric Radiation Measurement (ARM) Climate Research Facility Southern Great Plains (SGP) site are used to investigate mechanisms controlling the transition from shallow to deep convection over land. A more humid environment above the boundary layer favors the occurrence of late-afternoon heavy precipitation events. The higher moisture content is brought by wind from south. Greater boundary layer inhomogeneity in moist static energy (MSE) is correlated to larger rain rates at the initial stage of precipitation. MSE inhomogeneity is attributed to both moisture and temperature fields, and is correlated with westerly winds. In an examination of afternoon rain statistics, higher relative humidity above the boundary layer is correlated to an earlier onset and longer duration of precipitation, while greater boundary layer inhomogeneity and atmospheric instability are positively correlated to the total rain amount and the maximum rain rate. On balance, these observations favor theories for the transition that involve a moist free troposphere and boundary layer heterogeneity in preference to those that involve convective available potential energy or convective inhibition. Thus the evidence presented here supports the current emphasis in the modeling community on the entraining nature of convection and the role of boundary layer cold pools in triggering new convection.

DOE Office of Scientific and Technical Information (OSTI.GOV)

Song, Kok Wee; Koshelev, Alexei E.

Electronic nematicity plays an important role in iron-based superconductors. These materials have a layered structure and the theoretical description of their magnetic and nematic transitions has been well established in the two-dimensional approximation, i.e., when the layers can be treated independently. However, the interaction between iron layers mediated by electron tunneling may cause nontrivial three-dimensional behavior. Starting from the simplest model for orbital nematic in a single layer, we investigate the influence of interlayer tunneling on the bulk nematic order and a possible preemptive state where this order is only formed near the surface. In addition, we found that themore » interlayer tunneling suppresses the bulk nematicity, which makes favorable the formation of a surface nematic order above the bulk transition temperature. The purely electronic tunneling Hamiltonian, however, favors a nematic order parameter that alternates from layer to layer. The uniform bulk state typically observed experimentally may be stabilized by the coupling with the elastic lattice deformation. Depending on the strength of this coupling, we found three regimes: (i) surface nematic and alternating bulk order, (ii) surface nematic and uniform bulk order, and (iii) uniform bulk order without the intermediate surface phase. Lastly, the intermediate surface-nematic state may resolve the current controversy about the existence of a weak nematic transition in the compound BaFe 2As 2-xP x .« less

Surface nematic order in iron pnictides

NASA Astrophysics Data System (ADS)

Song, Kok Wee; Koshelev, Alexei E.

2016-09-01

Electronic nematicity plays an important role in iron-based superconductors. These materials have a layered structure and the theoretical description of their magnetic and nematic transitions has been well established in the two-dimensional approximation, i.e., when the layers can be treated independently. However, the interaction between iron layers mediated by electron tunneling may cause nontrivial three-dimensional behavior. Starting from the simplest model for orbital nematic in a single layer, we investigate the influence of interlayer tunneling on the bulk nematic order and a possible preemptive state where this order is only formed near the surface. We found that the interlayer tunneling suppresses the bulk nematicity, which makes favorable the formation of a surface nematic order above the bulk transition temperature. The purely electronic tunneling Hamiltonian, however, favors a nematic order parameter that alternates from layer to layer. The uniform bulk state typically observed experimentally may be stabilized by the coupling with the elastic lattice deformation. Depending on the strength of this coupling, we found three regimes: (i) surface nematic and alternating bulk order, (ii) surface nematic and uniform bulk order, and (iii) uniform bulk order without the intermediate surface phase. The intermediate surface-nematic state may resolve the current controversy about the existence of a weak nematic transition in the compound BaFe2As2 -xPx .

Disruption of the air-sea interface and formation of two-phase transitional layer in hurricane conditions

NASA Astrophysics Data System (ADS)

Soloviev, A.; Matt, S.; Fujimura, A.

2012-04-01

The change of the air-sea interaction regime in hurricane conditions is linked to the mechanism of direct disruption of the air-sea interface by pressure fluctuations working against surface tension forces (Soloviev and Lukas, 2010). The direct disruption of the air-sea interface due to the Kelvin-Helmholtz (KH) instability and formation of a two-phase transitional layer have been simulated with a computational fluid dynamics model. The volume of fluid multiphase model included surface tension at the water-air interface. The model was initialized with either a flat interface or short wavelets. Wind stress was applied at the upper boundary of the air layer, ranging from zero stress to hurricane force stress in different experiments. Under hurricane force wind, the numerical model demonstrated disruption of the air-water interface and the formation of spume and the two-phase transition layer. In the presence of a transition layer, the air-water interface is no longer explicitly identifiable. As a consequence, the analysis of dimensions suggests a linear dependence for velocity and logarithm of density on depth (which is consistent with the regime of marginal stability in the transition layer). The numerical simulations confirmed the presence of linear segments in the corresponding profiles within the transition layer. This permitted a parameterization of the equivalent drag coefficient due to the presence of the two-phase transition layer at the air-sea interface. This two-phase layer parameterization represented the lower limit imposed on the drag coefficient under hurricane conditions. The numerical simulations helped to reduce the uncertainty in the critical Richardson number applicable to the air-sea interface and in the values of two dimensionless constants; this reduced the uncertainty in the parameterization of the lower limit on the drag coefficient. The available laboratory data (Donelan et al., 2004) are bounded by the two-phase layer parameterization from below and the wave resistance parameterization from above. The available field data (Powell et al., 2003; Black et al., 2007) fall between these two parameterizations, for wind speeds of up to 50 m/s. A few points from the dropsonde data from Powell et al. (2003), obtained at very high wind speeds, are below the theoretical lower limit on the drag coefficient. We also conducted a numerical experiment with imposed short wavelets. Streamwise coherent structures were observed on the water surface, which were especially prominent on the top of wave crests. These intermittent streamwise structures on the top of wavelets, with periodicity in the transverse direction, presumably were a result of the Tollmien-Schlichting (TS) instability. Similar processes take place at the atomization of liquid fuels in cryogenic and diesel engines (Yecko et al., 2002). According to McNaughton and Brunet (2002), the nonlinear stage of the TS instability results in streamwise streaks followed by fluid ejections. This mechanism can contribute to the generation of spume in the form of streaks. Foam streaks are an observable feature on photographic images of the ocean surface under hurricane conditions. The mechanism of the TS instability can also contribute to dispersion of oil spills and other pollutants in hurricane conditions.

Single-Column Model Simulations of Subtropical Marine Boundary-Layer Cloud Transitions Under Weakening Inversions: SCM SIMULATIONS OF CLOUD TRANSITIONS

DOE Office of Scientific and Technical Information (OSTI.GOV)

Neggers, R. A. J.; Ackerman, A. S.; Angevine, W. M.

Results are presented of the GASS/EUCLIPSE single-column model inter-comparison study on the subtropical marine low-level cloud transition. A central goal is to establish the performance of state-of-the-art boundary-layer schemes for weather and climate mod- els for this cloud regime, using large-eddy simulations of the same scenes as a reference. A novelty is that the comparison covers four different cases instead of one, in order to broaden the covered parameter space. Three cases are situated in the North-Eastern Pa- cific, while one reflects conditions in the North-Eastern Atlantic. A set of variables is considered that reflects key aspects of the transitionmore » process, making use of simple met- rics to establish the model performance. Using this method some longstanding problems in low level cloud representation are identified. Considerable spread exists among models concerning the cloud amount, its vertical structure and the associated impact on radia- tive transfer. The sign and amplitude of these biases differ somewhat per case, depending on how far the transition has progressed. After cloud breakup the ensemble median ex- hibits the well-known “too few too bright” problem. The boundary layer deepening rate and its state of decoupling are both underestimated, while the representation of the thin capping cloud layer appears complicated by a lack of vertical resolution. Encouragingly, some models are successful in representing the full set of variables, in particular the verti- cal structure and diurnal cycle of the cloud layer in transition. An intriguing result is that the median of the model ensemble performs best, inspiring a new approach in subgrid pa- rameterization.« less

Layer-Dependent Ultrafast Carrier and Coherent Phonon Dynamics in Black Phosphorus.

PubMed

Miao, Xianchong; Zhang, Guowei; Wang, Fanjie; Yan, Hugen; Ji, Minbiao

2018-05-09

Black phosphorus is a layered semiconducting material, demonstrating strong layer-dependent optical and electronic properties. Probing the photophysical properties on ultrafast time scales is of central importance in understanding many-body interactions and nonequilibrium quasiparticle dynamics. Here, we applied temporally, spectrally, and spatially resolved pump-probe microscopy to study the transient optical responses of mechanically exfoliated few-layer black phosphorus, with layer numbers ranging from 2 to 9. We have observed layer-dependent resonant transient absorption spectra with both photobleaching and red-shifted photoinduced absorption features, which could be attributed to band gap renormalization of higher subband transitions. Surprisingly, coherent phonon oscillations with unprecedented intensities were observed when the probe photons were in resonance with the optical transitions, which correspond to the low-frequency layer-breathing mode. Our results reveal strong Coulomb interactions and electron-phonon couplings in photoexcited black phosphorus, providing important insights into the ultrafast optical, nanomechanical, and optoelectronic properties of this novel two-dimensional material.

First-principles simulations of Graphene/Transition-metal-Dichalcogenides/Graphene Field-Effect Transistor

NASA Astrophysics Data System (ADS)

Li, Xiangguo; Wang, Yun-Peng; Zhang, X.-G.; Cheng, Hai-Ping

A prototype field-effect transistor (FET) with fascinating properties can be made by assembling graphene and two-dimensional insulating crystals into three-dimensional stacks with atomic layer precision. Transition metal dichalcogenides (TMDCs) such as WS2, MoS2 are good candidates for the atomically thin barrier between two layers of graphene in the vertical FET due to their sizable bandgaps. We investigate the electronic properties of the Graphene/TMDCs/Graphene sandwich structure using first-principles method. We find that the effective tunnel barrier height of the TMDC layers in contact with the graphene electrodes has a layer dependence and can be modulated by a gate voltage. Consequently a very high ON/OFF ratio can be achieved with appropriate number of TMDC layers and a suitable range of the gate voltage. The spin-orbit coupling in TMDC layers is also layer dependent but unaffected by the gate voltage. These properties can be important in future nanoelectronic device designs. DOE/BES-DE-FG02-02ER45995; NERSC.

Blunt body near wake flow field at Mach 6

NASA Technical Reports Server (NTRS)

Horvath, Thomas J.; McGinley, Catherine B.; Hannemann, Klaus

1996-01-01

Tests were conducted in a Mach 6 flow to examine the reattachment process of an axisymmetric free shear layer associated with the near wake of a 70 deg. half angle, spherically blunted cone with a cylindrical after body. Model angle of incidence was fixed at 0 deg. and free-stream Reynolds numbers based on body diameter ranged from 0.5 x 10(exp 6) to 4 x 10(exp 6). The sensitivity of wake shear layer transition on reattachment heating was investigated. The present perfect gas study was designed to compliment results obtained previously in facilities capable of producing real gas effects. The instrumented blunted cone model was designed primarily for testing in high enthalpy hypervelocity shock tunnels in both this country and abroad but was amenable for testing in conventional hypersonic blowdown wind tunnels as well. Surface heating rates were inferred from temperature - time histories from coaxial surface thermocouples on the model forebody and thin film resistance gages along the model base and cylindrical after body. General flow feature (bow shock, wake shear layer, and recompression shock) locations were visually identified by schlieren photography. Mean shear layer position and growth were determined from intrusive pitot pressure surveys. In addition, wake surveys with a constant temperature hot-wire anemometer were utilized to qualitatively characterize the state of the shear layer prior to reattachment. Experimental results were compared to laminar perfect gas predictions provided by a 3-D Navier Stokes code (NSHYP). Shear layer impingement on the instrumented cylindrical after body resulted in a localized heating maximum that was 21 to 29 percent of the forebody stagnation point heating. Peak heating resulting from the reattaching shear layer was found to be a factor of 2 higher than laminar predictions, which suggested a transitional shear layer. Schlieren flow visualization and fluctuating voltage time histories and spectra from the hot wire surveys across the shear layer substantiate this observation. The sensitivity of surface heating to forebody roughness was characterized for a reattaching shear layer. For example, at R(sub infinity), d = 4 x 10(exp 6), when the shear layer was transitional, the magnitude of peak heating from shear layer impingement was reduced by approximately 24 percent when transition grit was applied to the forebody. The spatial location of the local peak, however, remained unchanged.

A discussion of cone and flat-plate Reynolds numbers for equal ratios of the laminar shear to the shear caused by small velocity fluctuations in a laminar boundary layer

NASA Technical Reports Server (NTRS)

Tetervin, Neal

1957-01-01

By use of the linear theory of boundary-layer stability and Schlichting's formula for the maximum amplification of a disturbance, an approximate relation is derived between the Reynolds number on a cone and the Reynolds number on a flat plate for equal closeness to transition. The indication is that the ratio of the cone Reynolds number for transition, based on the distance to the cone apex, to the plate Reynolds number for transition, based on the distance to the leading edge, is not in general equal to 3, as has been suggested by other investigators, but varies from 3 when transition occurs at the minimum critical Reynolds number to unity when transition occurs at a large multiple of the critical Reynolds number.

Superconductivity in two-dimensional NbSe2 field effect transistors

NASA Astrophysics Data System (ADS)

El-Bana, Mohammed S.; Wolverson, Daniel; Russo, Saverio; Balakrishnan, Geetha; Mck Paul, Don; Bending, Simon J.

2013-12-01

We describe investigations of superconductivity in few molecular layer NbSe2 field effect transistors. While devices fabricated from NbSe2 flakes less than eight molecular layers thick did not conduct, thicker flakes were superconducting with an onset Tc that was only slightly depressed from the bulk value for 2H-NbSe2 (7.2 K). The resistance typically showed a small, sharp high temperature transition followed by one or more broader transitions which usually ended in a wide tail to zero resistance at low temperatures. We speculate that these multiple resistive transitions are related to disorder in the layer stacking. The behavior of several flakes has been characterized as a function of temperature, applied field and back-gate voltage. We find that the conductance in the normal state and transition temperature depend weakly on the gate voltage, with both conductivity and Tc decreasing as the electron concentration is increased. The application of a perpendicular magnetic field allows the evolution of different resistive transitions to be tracked and values of the zero temperature upper critical field, Hc2(0), and coherence length, ξ(0), to be independently estimated. Our results are analyzed in terms of available theories for these phenomena.

Phase Transition of Single-Layer Molybdenum Disulfide Nanosheets under Mechanical Loading Based on Molecular Dynamics Simulations.

PubMed

Pang, Haosheng; Li, Minglin; Gao, Chenghui; Huang, Haili; Zhuo, Weirong; Hu, Jianyue; Wan, Yaling; Luo, Jing; Wang, Weidong

2018-03-27

The single-layer molybdenum disulfide (SLMoS2) nanosheets have been experimentally discovered to exist in two different polymorphs, which exhibit different electrical properties, metallic or semiconducting. Herein, molecular dynamics (MD) simulations of nanoindentation and uniaxial compression were conducted to investigate the phase transition of SLMoS2 nanosheets. Typical load-deflection curves, stress-strain curves, and local atomic structures were obtained. The loading force decreases sharply and then increases again at a critical deflection under the nanoindentation, which is inferred to the phase transition. In addition to the layer thickness, some related bond lengths and bond angles were also found to suddenly change as the phase transition occurs. A bell-like hollow, so-called residual deformation, was found to form, mainly due to the lattice distortion around the waist of the bell. The effect of indenter size on the residual hollow was also analyzed. Under the uniaxial compression along the armchair direction, a different phase transition, a uniformly quadrilateral structure, was observed when the strain is greater than 27.7%. The quadrilateral structure was found to be stable and exhibit metallic conductivity in view of the first-principle calculation.

Network traffic behaviour near phase transition point

NASA Astrophysics Data System (ADS)

Lawniczak, A. T.; Tang, X.

2006-03-01

We explore packet traffic dynamics in a data network model near phase transition point from free flow to congestion. The model of data network is an abstraction of the Network Layer of the OSI (Open Systems Interconnect) Reference Model of packet switching networks. The Network Layer is responsible for routing packets across the network from their sources to their destinations and for control of congestion in data networks. Using the model we investigate spatio-temporal packets traffic dynamics near the phase transition point for various network connection topologies, and static and adaptive routing algorithms. We present selected simulation results and analyze them.

COSAL: A black-box compressible stability analysis code for transition prediction in three-dimensional boundary layers

NASA Technical Reports Server (NTRS)

Malik, M. R.

1982-01-01

A fast computer code COSAL for transition prediction in three dimensional boundary layers using compressible stability analysis is described. The compressible stability eigenvalue problem is solved using a finite difference method, and the code is a black box in the sense that no guess of the eigenvalue is required from the user. Several optimization procedures were incorporated into COSAL to calculate integrated growth rates (N factor) for transition correlation for swept and tapered laminar flow control wings using the well known e to the Nth power method. A user's guide to the program is provided.

Synergistic interactions promote behavior spreading and alter phase transitions on multiplex networks

NASA Astrophysics Data System (ADS)

Liu, Quan-Hui; Wang, Wei; Cai, Shi-Min; Tang, Ming; Lai, Ying-Cheng

2018-02-01

Synergistic interactions are ubiquitous in the real world. Recent studies have revealed that, for a single-layer network, synergy can enhance spreading and even induce an explosive contagion. There is at the present a growing interest in behavior spreading dynamics on multiplex networks. What is the role of synergistic interactions in behavior spreading in such networked systems? To address this question, we articulate a synergistic behavior spreading model on a double layer network, where the key manifestation of the synergistic interactions is that the adoption of one behavior by a node in one layer enhances its probability of adopting the behavior in the other layer. A general result is that synergistic interactions can greatly enhance the spreading of the behaviors in both layers. A remarkable phenomenon is that the interactions can alter the nature of the phase transition associated with behavior adoption or spreading dynamics. In particular, depending on the transmission rate of one behavior in a network layer, synergistic interactions can lead to a discontinuous (first-order) or a continuous (second-order) transition in the adoption scope of the other behavior with respect to its transmission rate. A surprising two-stage spreading process can arise: due to synergy, nodes having adopted one behavior in one layer adopt the other behavior in the other layer and then prompt the remaining nodes in this layer to quickly adopt the behavior. Analytically, we develop an edge-based compartmental theory and perform a bifurcation analysis to fully understand, in the weak synergistic interaction regime where the dynamical correlation between the network layers is negligible, the role of the interactions in promoting the social behavioral spreading dynamics in the whole system.

Carrier lifetime in exfoliated few-layer graphene determined from intersubband optical transitions.

PubMed

Limmer, Thomas; Feldmann, Jochen; Da Como, Enrico

2013-05-24

We report a femtosecond transient spectroscopy study in the near to middle infrared range, 0.8-0.35 eV photon energy, on graphene and few layer graphene single flakes. The spectra show an evolving structure of photoinduced absorption bands superimposed on the bleaching caused by Pauli blocking of the interband optically coupled states. Supported by tight-binding model calculations, we assign the photoinduced absorption features to intersubband transitions as the number of layers is increased. Interestingly, the intersubband photoinduced resonances show a longer dynamics than the interband bleaching, because of their independence from the absolute energy of the carriers with respect to the Dirac point. The dynamic of these intersubband transitions reflects the lifetime of the hot carriers and provides an elegant method to access it in this important class of semimetals.

Carrier Lifetime in Exfoliated Few-Layer Graphene Determined from Intersubband Optical Transitions

NASA Astrophysics Data System (ADS)

Limmer, Thomas; Feldmann, Jochen; Da Como, Enrico

2013-05-01

We report a femtosecond transient spectroscopy study in the near to middle infrared range, 0.8-0.35 eV photon energy, on graphene and few layer graphene single flakes. The spectra show an evolving structure of photoinduced absorption bands superimposed on the bleaching caused by Pauli blocking of the interband optically coupled states. Supported by tight-binding model calculations, we assign the photoinduced absorption features to intersubband transitions as the number of layers is increased. Interestingly, the intersubband photoinduced resonances show a longer dynamics than the interband bleaching, because of their independence from the absolute energy of the carriers with respect to the Dirac point. The dynamic of these intersubband transitions reflects the lifetime of the hot carriers and provides an elegant method to access it in this important class of semimetals.

Low temperature detection of phase transitions and relaxation processes in strontium titanate by means of cathodoluminescence

NASA Astrophysics Data System (ADS)

Yang, B.; Townsend, P. D.; Fromknecht, R.

2004-11-01

Cathodoluminescence is an effective tool for investigating phase changes and relaxation processes in insulators and data are presented for strontium titanate. The results demonstrate considerable sensitivity to the origin of the samples as the detailed spectra and intensity changes with temperature are strongly dependent on the growth conditions, trace impurities and radiation induced defects. It is of particular note that in the defective surface layer the normal second-order phase transition cited near 105 K transforms into a sharply defined first-order transition because of the relaxation of the near surface layer in doped crystals. Detection of the other main relaxation stages is also straightforward via intensity and spectral changes. Secondary effects of phase changes incorporated within the surface layers are clearly evident, particularly for the 197 K sublimation of CO2 nanoparticle inclusions.

Combustion theory for liquids with a free surface. 3: Special problems

NASA Technical Reports Server (NTRS)

Milkov, S. N.; Sukhov, G. S.; Yarin, L. P.

1986-01-01

Two special problems concerning the combustion of liquids with a free surface, i.e., flame quenching during the mixing of a burning liquid inside a container and liquid burnout from a porous layer, are analyzed using a quasi-one-dimensional model. The critical parameters corresponding to the quenching of a burning fluid with a free surface are determined. Determinations are also made of the limiting pressure gradients corresponding to the transition from the combustion mode where the liquid evaporates from the surface of a porous layer to the mode where the phase transition surface lies inside the porous layer.

Studying the Afternoon Transition of the Planetary Boundary Layer

NASA Astrophysics Data System (ADS)

Lothon, Marie; Lenschow, Donald H.

2010-07-01

The planetary boundary layer is the part of the atmosphere that interacts directly with the Earth's surface on a time scale of a few hours or less. In daytime, solar heating of the surface can generate buoyant turbulent eddies that efficiently mix the air through a depth of more than a kilometer. This convective boundary layer (CBL) is a conduit for trace gases such as water vapor and carbon dioxide that are emitted or absorbed by the surface (and surface vegetation) to be transported into or out of the layer nearest the surface. The CBL has been extensively observed and relatively successfully modeled. But the early morning transition—when the CBL emerges from the nocturnal boundary layer—and the late afternoon transition—when the CBL decays to an intermittently turbulent “residual layer” overlying a shallower, stably stratified boundary layer—are difficult to observe and model due to turbulence intermittency and anisotropy, horizontal heterogeneity, and rapid time changes. Even the definition of the boundary layer during these transitional periods is fuzzy; there is no consensus on what criteria to use and no simple scaling laws, as there are for the CBL, that apply during these transitions.

Ordering transitions of weakly anisotropic hard rods in narrow slitlike pores.

PubMed

Aliabadi, Roohollah; Gurin, Péter; Velasco, Enrique; Varga, Szabolcs

2018-01-01

The effect of strong confinement on the positional and orientational ordering is examined in a system of hard rectangular rods with length L and diameter D (L>D) using the Parsons-Lee modification of the second virial density-functional theory. The rods are nonmesogenic (L/D<3) and confined between two parallel hard walls, where the width of the pore (H) is chosen in such a way that both planar (particle's long axis parallel to the walls) and homeotropic (particle's long axis perpendicular to the walls) orderings are possible and a maximum of two layers is allowed to form in the pore. In the extreme confinement limit of H≤2D, where only one-layer structures appear, we observe a structural transition from a planar to a homeotropic fluid layer with increasing density, which becomes sharper as L→H. In wider pores (2D

Transitional and turbulent flat-plate boundary layers with heat transfer

NASA Astrophysics Data System (ADS)

Wu, Xiaohua; Moin, Parviz

2010-11-01

We report on our direct numerical simulation of two incompressible, nominally zero-pressure-gradient flat-plate boundary layers from momentum thickness Reynolds number 80 to 1950. Heat transfer between the constant-temperature solid surface and the free-stream is also simulated with molecular Prandtl number=1. Throughout the entire flat-plate, the ratio of Stanton number and skin-friction St/Cfdeviates from the exact Reynolds analogy value of 0.5 by less than 1.5%. Turbulent Prandtl number t peaks at the wall. Preponderance of hairpin vortices is observed in both the transitional and turbulent regions of the boundary layers. In particular, the internal structure of merged turbulent spots is hairpin forest; the internal structure of infant turbulent spots is hairpin packet. Numerous hairpin vortices are readily detected in both the near-wall and outer regions of the boundary layers up to momentum thickness Reynolds number 1950. This suggests that the hairpin vortices in the turbulent region are not simply the aged hairpin forests convected from the upstream transitional region. Temperature iso-surfaces in the companion thermal boundary layers are found to be a useful tracer in identifying hairpin vortex structures.

The stability boundary of group-III transition metal diboride ScB 2 (0 0 0 1) surfaces

NASA Astrophysics Data System (ADS)

Zhao, Hui; Qin, Na

2012-01-01

Experimental observations and theoretical investigations exhibit that a group-IV(V) transition metal diboride (0 0 0 1) surface is terminated with a 1 × 1 TM(B) layer. As to a group-III transition metal diboride, we have investigated the stability boundary of ScB2 (0 0 0 1) surfaces using first principles total energy plane-wave pseudopotential method based on density functional theory. The Mulliken charge population analysis shows that Sc atoms in the second layer cannot provide B atoms in the first layer with sufficient electrons to form a complete graphene-like boron layer. We also found that the charge transfer between the first and the second layer for the B-terminated surface is more than that for Sc-terminated surface. It elucidates the reason that the outermost interlayer spacing contract more strongly in the B-terminated surface than in the Sc-terminated surface. The surface energies of both terminated ScB2 (0 0 0 1) surfaces as a function of the chemical potential of B are also calculated to check the relative stability of the two surface structures.

Enthalpy effects on hypervelocity boundary layers

NASA Astrophysics Data System (ADS)

Adam, Philippe H.

Shots with air and carbon dioxide were carried out in the T5 shock tunnel at GALCIT to study enthalpy effects on hypervelocity boundary layers. The model tested was a 1-meter long, 5-deg half-angle cone. It was instrumented with 51 chromel-constantan coaxial thermocouples and the surface heat transfer rate was computed to deduce the state of the boundary layer. Transitional boundary layers obtained confirm the stabilizing effect of enthalpy. As the reservoir enthalpy is increased, the transition Reynolds number evaluated at the reference conditions increases. This stabilizing effect is more rapid in gases with lower dissociation energy and it seems to level off when no further dissociation can be achieved. Normalizing the reservoir enthalpy with the edge enthalpy appears to collapse the data for all gases onto a single curve. A similar collapse is obtained when normalizing both the transition location and the reservoir enthalpy with the maximum temperature conditions obtained with BLIMPK, a nonequilibrium boundary layer code. The observation that reference conditions are more appropriate to normalize high enthalpy transition data was taken a step further by comparing the tunnel data with results from a reentry experiment. When the edge conditions are used, the tunnel and flight data are around an order of magnitude apart. This is commonly attributed to high disturbance levels in tunnels that cause the boundary layer to transition early. However, when the reference conditions are used instead, the tunnel and flight data come within striking distance of one another although the trends with enthalpy are reversed. This difference could be due to the cone bending and nose blunting. Experimental laminar heat transfer levels were compared to numerical results obtained with BLIMPK. Results for air indicate that the reactions are probably in nonequilibrium and that the wall is catalytic. The catalycity is seen to yield higher surface heat transfer rates than the noncatalytic and frozen chemistry models. The results for carbon dioxide, however, are inconclusive. This is, perhaps, because of inadequate modeling of the reactions. Experimentally, an anomalous yet repeatable, rise in the laminar heat transfer level can be seen at medium enthalpies in carbon dioxide boundary layers.

Electronics and optoelectronics of two-dimensional transition metal dichalcogenides.

PubMed

Wang, Qing Hua; Kalantar-Zadeh, Kourosh; Kis, Andras; Coleman, Jonathan N; Strano, Michael S

2012-11-01

The remarkable properties of graphene have renewed interest in inorganic, two-dimensional materials with unique electronic and optical attributes. Transition metal dichalcogenides (TMDCs) are layered materials with strong in-plane bonding and weak out-of-plane interactions enabling exfoliation into two-dimensional layers of single unit cell thickness. Although TMDCs have been studied for decades, recent advances in nanoscale materials characterization and device fabrication have opened up new opportunities for two-dimensional layers of thin TMDCs in nanoelectronics and optoelectronics. TMDCs such as MoS(2), MoSe(2), WS(2) and WSe(2) have sizable bandgaps that change from indirect to direct in single layers, allowing applications such as transistors, photodetectors and electroluminescent devices. We review the historical development of TMDCs, methods for preparing atomically thin layers, their electronic and optical properties, and prospects for future advances in electronics and optoelectronics.

Two-dimensional inorganic analogues of graphene: transition metal dichalcogenides.

PubMed

Jana, Manoj K; Rao, C N R

2016-09-13

The discovery of graphene marks a major event in the physics and chemistry of materials. The amazing properties of this two-dimensional (2D) material have prompted research on other 2D layered materials, of which layered transition metal dichalcogenides (TMDCs) are important members. Single-layer and few-layer TMDCs have been synthesized and characterized. They possess a wide range of properties many of which have not been known hitherto. A typical example of such materials is MoS2 In this article, we briefly present various aspects of layered analogues of graphene as exemplified by TMDCs. The discussion includes not only synthesis and characterization, but also various properties and phenomena exhibited by the TMDCs.This article is part of the themed issue 'Fullerenes: past, present and future, celebrating the 30th anniversary of Buckminster Fullerene'. © 2016 The Author(s).

Two-dimensional inorganic analogues of graphene: transition metal dichalcogenides

PubMed Central

Jana, Manoj K.; Rao, C. N. R.

2016-01-01

The discovery of graphene marks a major event in the physics and chemistry of materials. The amazing properties of this two-dimensional (2D) material have prompted research on other 2D layered materials, of which layered transition metal dichalcogenides (TMDCs) are important members. Single-layer and few-layer TMDCs have been synthesized and characterized. They possess a wide range of properties many of which have not been known hitherto. A typical example of such materials is MoS2. In this article, we briefly present various aspects of layered analogues of graphene as exemplified by TMDCs. The discussion includes not only synthesis and characterization, but also various properties and phenomena exhibited by the TMDCs. This article is part of the themed issue ‘Fullerenes: past, present and future, celebrating the 30th anniversary of Buckminster Fullerene’. PMID:27501969

Laminar-Boundary-Layer Oscillations and Transition on a Flat Plate

NASA Technical Reports Server (NTRS)

Schubauer, G B; Skramstad, H K

1948-01-01

This is an account of an investigation in which oscillations were discovered in the laminar boundary layer along a flat plate. These oscillations were found during the course of an experiment in which transition from laminar to turbulent flow was being studied on the plate as the turbulence in the wind stream was being reduced to unusually low values by means of damping screens. The first part of the paper deals with experimental methods and apparatus, measurements of turbulence and sound, and studies of transition. A description is then given of the manner in which oscillations were discovered and how they were found to be related to transition, and then how controlled oscillations were produced and studied in detail.

Method of boronizing transition metal surfaces

DOEpatents

Koyama, Koichiro; Shimotake, Hiroshi

1983-01-01

A method is presented for preparing a boride layer on a transition metal substrate for use in corrosive environments or as a harden surface in machine applications. This method is particularly useful in treating current collectors for use within a high temperature and corrosive electrochemical cell environment. A melt of a alkali metal boride tetrafluoride salt including such as KF to lower its melting point is prepared including a dissolved boron containing material, for instance NiB, MnB.sub.2, or CrB.sub.2. A transition metal to be coated is immersed in the melt at a temperature of no more than 700.degree. C. and a surface boride layer of that transition metal is formed within a period of about 24 hours on the substrate surface.

Calculation of the absolute free energy of a smectic-A phase

NASA Astrophysics Data System (ADS)

Huang, Chien-Cheng; Ramachandran, Sanoop; Ryckaert, Jean-Paul

2014-12-01

In this paper, we provide a scheme to compute the absolute free energy of a smectic-A phase via the "indirect method." The state of interest is connected through a three-step reversible path to a reference state. This state consists of a low-density layer of rods coupled to two external fields maintaining these rods close to the layer's plane and oriented preferably normal to the layer. The low-density free energy of the reference state can be computed on the basis of the relevant second virial coefficients between two rods coupled to the two external fields. We apply this technique to the Gay-Berne potential for calamitics with a parameter set leading to stable isotropic (I), nematic (N), smectic-A (SmA), and crystal (Cr) phases. We locate the I-SmA phase transition at low pressure and the sequence of phase transitions I-N-SmA along higher-pressure isobars and we establish the location of the I-N-SmA triple point. Close to this triple point, we show that the N-SmA transition is clearly first order. Our results are compared to the coexistence lines of the approximate phase diagram elucidated by de Miguel et al. [J. Chem. Phys. 121, 11183 (2004), 10.1063/1.1810472] established through the direct observation of the sequence of phase transitions occurring along isobars under heating or cooling sequences of runs. Finally, we discuss the potential of our technique in studying similar transitions observed on layered phases under confinement.

Molecular Characterization of Squamous Cell Carcinomas From Recessive Dystrophic Epidermolysis Bullosa

DTIC Science & Technology

2006-09-01

junctions found primarily in epithelial tissues but also in certain non-epithelial tissues including the meninges, dendritic reticular cells of lymph node...epidermal thickening, a phenotype becoming more prominent in adult animals. To further examine the transition between the stratum granulosum and stratum...granular cell layers of wild-type and transgenic skin. In control epidermis, an abrupt transition was observed from the granular layer to the stratum

Numerical Simulation of Hypersonic Boundary Layer Receptivity, Transient Growth and Transition With Surface Roughness

DTIC Science & Technology

2009-12-31

of receptivity of the Mach 5.92 flow over a flat plate to two- dimensional wall perturbations with surface roughness: 1) amplitude...contain a significantly large intervalθ compared with the normal grid spacing h∆ , which may lead to a deterioration of accuracy of the method... of hypersonic boundary layer receptivity, transient growth and transition with surface roughness. The main approach is to use

Transition Helmholtz free energy, entropy, and heat capacity of free-standing smectic films in water: A mean-field treatment

DOE Office of Scientific and Technical Information (OSTI.GOV)

Śliwa, Izabela, E-mail: izasliwa@ifmpan.poznan.pl; Zakharov, A. V., E-mail: alexandre.zakharov@yahoo.ca

Using the extended McMillan's mean field approach with anisotropic forces a study of both the structural and thermodynamic properties of free-standing smectic film (FSSF) in water on heating to the isotropic temperature is carried out numerically. By solving the self-consistent nonlinear equations for the order parameters, we obtained that the smectic-A-isotropic (AI) transition occurs through the series of layer-thinning transitions causing the films to thin in the stepwise manner as the temperature is increased above the bulk smectic-A-isotropic temperature T{sub AI}(bulk). With enhanced pair interactions in the bounding layers, the smectic-isotropic transition corresponds to smectic melting of the central layers.more » The effects of surface “enhanced” pair interactions in the bounding layers and of film thickness on the orientational and translational order parameters, the Helmholtz free energy and entropy, as well as the temperature dependence of the heat capacity of FSSFs, have also been investigated. Reasonable agreement between the theoretically predicted and the experimentally obtained – by means of optical microscopy and ellipsometry techniques – data of the temperature when the thin decylcyanobiphenyl smectic film immersing in water ruptures has been obtained.« less

Ultrathin and Atomically Flat Transition-Metal Oxide: Promising Building Blocks for Metal-Insulator Electronics.

PubMed

Cui, Qingsong; Sakhdari, Maryam; Chamlagain, Bhim; Chuang, Hsun-Jen; Liu, Yi; Cheng, Mark Ming-Cheng; Zhou, Zhixian; Chen, Pai-Yen

2016-12-21

We present a new and viable template-assisted thermal synthesis method for preparing amorphous ultrathin transition-metal oxides (TMOs) such as TiO 2 and Ta 2 O 5 , which are converted from crystalline two-dimensional (2D) transition-metal dichalcogenides (TMDs) down to a few atomic layers. X-ray photoelectron spectroscopy (XPS), atomic force microscopy (AFM), and scanning transmission electron microscopy (STEM) were used to characterize the chemical composition and bonding, surface morphology, and atomic structure of these ultrathin amorphous materials to validate the effectiveness of our synthesis approach. Furthermore, we have fabricated metal-insulator-metal (MIM) diodes using the TiO 2 and Ta 2 O 5 as ultrathin insulating layers with low potential barrier heights. Our MIM diodes show a clear transition from direct tunneling to Fowler-Nordheim tunneling, which was not observed in previously reported MIM diodes with TiO 2 or Ta 2 O 5 as the insulating layer. We attribute the improved performance of our MIM diodes to the excellent flatness and low pinhole/defect densities in our TMO insulting layers converted from 2D TMDs, which enable the low-threshold and controllable electron tunneling transport. We envision that it is possible to use the ultrathin TMOs converted from 2D TMDs as the insulating layer of a wide variety of metal-insulator and field-effect electronic devices for various applications ranging from microwave mixing, parametric conversion, infrared photodetection, emissive energy harvesting, to ultrafast electronic switching.

Nonuniform concentration - A mechanism for drag reduction.

NASA Technical Reports Server (NTRS)

Rivard, W. C.; Kulinski, E. S.

1972-01-01

A large reduction in drag coefficient has been observed in certain external flows of aqueous solutions with high molecular weight polymer additives. A change in the near wake configuration is phenomenologically responsible for the drag reduction, but the underlying mechanism is presently unknown. An analogy to known phenomena in particulate suspensions is drawn which suggests nonuniform concentration of the polymer additive as an explanation. An analysis of the boundary layer on a sphere with varying viscosity was made to investigate the effect. The results indicate early transition to turbulence for concentration variations whose length scale is small compared with the momentum boundary layer thickness. Stabilization and delayed transition are indicated for thicker concentration layers. Observations are suggested for the thin concentration layers.

Charge-density study on layered oxyarsenides (LaO)MAs (M = Mn, Fe, Ni, Zn)

NASA Astrophysics Data System (ADS)

Takase, Kouichi; Hiramoto, Shozo; Fukushima, Tetsuya; Sato, Kazunori; Moriyoshi, Chikako; Kuroiwa, Yoshihiro

2017-12-01

Using synchrotron X-ray powder diffraction, we investigate the charge-density distributions of the layered oxypnictides (LaO)MnAs, (LaO)FeAs, (LaO)NiAs, and (LaO)ZnAs, which are an antiferromagnetic semiconductor, a parent material of an iron-based superconductor, a low-temperature superconductor, and a non-magnetic semiconductor, respectively. For the metallic samples, clear charge densities are observed in both the transition-metal pnictide layers and the rare-earth-oxide layers. However, in the semiconducting samples, there is no finite charge density between the transition-metal element and As. These differences in charge density reflect differences in physical properties. First-principles calculations using density functional theory reproduce the experimental results reasonably well.

Hypersonic Boundary Layer Instability Over a Corner

NASA Technical Reports Server (NTRS)

Balakumar, Ponnampalam; Zhao, Hong-Wu; McClinton, Charles (Technical Monitor)

2001-01-01

A boundary-layer transition study over a compression corner was conducted under a hypersonic flow condition. Due to the discontinuities in boundary layer flow, the full Navier-Stokes equations were solved to simulate the development of disturbance in the boundary layer. A linear stability analysis and PSE method were used to get the initial disturbance for parallel and non-parallel flow respectively. A 2-D code was developed to solve the full Navier-stokes by using WENO(weighted essentially non-oscillating) scheme. The given numerical results show the evolution of the linear disturbance for the most amplified disturbance in supersonic and hypersonic flow over a compression ramp. The nonlinear computations also determined the minimal amplitudes necessary to cause transition at a designed location.

Electrophoretic formation of semiconductor layers with adjustable band gap

NASA Astrophysics Data System (ADS)

Shindrov, Alexander; Yuvchenko, Sergey; Vikulova, Maria; Tretyachenko, Elena; Zimnyakov, Dmitry; Gorokhovsky, Alexander

2017-11-01

The ceramic layers of the potassium polytitanates modified by transition metal salts were electrophoretically deposited onto the surface of glassy substrate coated with indium-tin oxide. The deposition allows obtaining a dense ceramic layer formed by composite agglomerates consisting of nanoscale particles with average size of 130-190 nm. The optical absorption spectra of the coatings modified in the mixtures of aqueous solutions of different transition metal salts were investigated. It was recognized that a bandgap value of these composites can be adjusted in a range from 1.4 to 2.3 eV depending the chemical composition of layered double hydroxide obtained during modification. This might be very promising for optoelectronic applications of such coatings due to an explicit control of optical properties.

Measure Guideline: Transitioning from Three-Coat Stucco to One-Coat Stucco with EPS

DOE Office of Scientific and Technical Information (OSTI.GOV)

Brozyna, K.; Davis, G.; Rapport, A.

2012-04-01

This Measure Guideline has been developed to help builders transition from using a traditional three-coat stucco wall-cladding system to a one-coat stucco wall-cladding system with expanded polystyrene (EPS) insulated sheathing. The three-coat system uses a base layer, a fill layer, and a finish layer. The one-coat system maintains the look of a traditional stucco system but uses only a base layer and a finish coat over EPS insulation that achieves higher levels of energy efficiency. Potential risks associated with the installation of a one-coat stucco system are addressed in terms of design, installation, and warranty concerns such as cracking andmore » delamination, along with mitigation strategies to reduce these risks.« less

X-ray Study of the Electric Double Layer at the n-Hexane/Nanocolloidal Silica Interface

DOE Office of Scientific and Technical Information (OSTI.GOV)

Tikhonov,A.

The spatial structure of the transition region between an insulator and an electrolyte solution was studied with x-ray scattering. The electron-density profile across the n-hexane/silica sol interface (solutions with 5, 7, and 12 nm colloidal particles) agrees with the theory of the electrical double layer and shows separation of positive and negative charges. The interface consists of three layers, i.e., a compact layer of Na{sup +}, a loose monolayer of nanocolloidal particles as part of a thick diffuse layer, and a low-density layer sandwiched between them. Its structure is described by a model in which the potential gradient at themore » interface reflects the difference in the potentials of 'image forces' between the cationic Na{sup +} and anionic nanoparticles and the specific adsorption of surface charge. The density of water in the large electric field ({approx}10{sup 9}-10{sup 10} V/m) of the transition region and the layering of silica in the diffuse layer is discussed.« less

Diagenesis, weathering and paleoenvironmental conditions from postglacial diamictite/cap carbonate transition layers of the Otavi Group (NW-Namibia)

NASA Astrophysics Data System (ADS)

Gyollai, I.; Popp, F.; Mader, D.; Koeberl, Ch.

2012-04-01

Introduction The so-called "Snowball Earth hypothesis" states that the "Sturtian" (710 Ma) and "Marinoan" glaciations (635 Ma) were of global extent and may have lasted for several million years. Our samples were collected from conspicuous transition layers on top of the glaciogenic Chuos (Sturtian) (10 samples) and Ghaub (Marinoan) formations (63 samples) of the Neoproterozoic Otavi Group in NW-Namibia. The goal of this study is to obtain information concerning the provenance and geochemical composition of postglacial diamictite/cap carbonate transition layers and to estimate the paleoenvironmental conditions with respect to glacio-marine sea water composition and attendant sediment accumulation in mineralogical-geochemical aspects. Methods The mineralogical composition of our samples was studied using the petrographic microscope, X-ray powder diffraction, cathodoluminescence microscopy, and micro-Raman spectrometry. Instrumental neutron activation and X-ray fluorescence analyses, as well as analytical electron microscopy, were used for the geochemical study. Results Detrital components derived from crystalline and/or dolomite platform source areas are enclosed within a diagenetically recrystallized matrix of carbonate and quartz minerals. Clay samples from both, Marinoan and some Sturtian postglacial layers are characterized by high Ni/Co, Cr/V, and low Th/Sc, La/Sc, V/Ni and Cr/Ni ratios compared to PAAS (Postarchean Australian shale, [1]), which could indicate mafic-ultramafic source material[1]. According to SEM-EDX measurements, only hematite, quartz, and feldspar make up the detrital composition, thus the Cr-Ni enrichment does not seem to be associated with any specific mineral phases. Specific results for the Sturtian postglacial transition layers: An U/Th ratio >0.75, and Mo-enrichment in the topmost iron-rich Sturtian diamictites (Chuos Fm.) and their superposed postglacial boundary layers (Rasthof Fm) indicates reducing conditions in the sea water [2,3 ]. The detritus of the basal cap carbonates is rich in kaolinite and montmorillonite and has low K/Cs values, indicating a high weathering rate. Specific results for the Marinoan postglacial transition layers: The Marinoan diamictites (Ghaub Fm.) and their superposed postglacial transition layers (basal Maieberg Fm) are characterized in a few cases by very high Th/Co, Th/Sc and LREE/HREE ratios, which indicate some influence of a felsic source area. The detrital/recrystallized components of these iron-poor diamictites are rich in pyrite and quartz and display a REE enrichment compared to PAAS, which indicates a hydrothermal component during their accumulation [3]. Conlusions 1) Sturtian layers: possibly different source areas supplied the sedimentary basins 2) Marinoan layers : sediments were influenced by hydrothermal fluids and diagenetic alteration 3) Reducing conditions existed in the marine environment during both of the "Snowball Earth" glaciation periods each followed by oxidative conditions reflected in the geochemical composition of related postglacial cap carbonates. Acknowledgement Our work is funded by the Austrian Academy of Sciences (IGCP 512) (to CK).

Design And Ground Testing For The Expert PL4/PL5 'Natural And Roughness Induced Transition'

NASA Astrophysics Data System (ADS)

Masutti, Davie; Chazot, Olivier; Donelli, Raffaele; de Rosa, Donato

2011-05-01

Unpredicted boundary layer transition can impact dramatically the stability of the vehicle, its aerodynamic coefficients and reduce the efficiency of the thermal protection system. In this frame, ESA started the EXPERT (European eXPErimental Reentry Testbed) program to pro- vide and perform in-flight experiments in order to obtain aerothermodynamic data for the validation of numerical models and of ground-to-flight extrapolation methodologies. Considering the boundary layer transition investigation, the EXPERT vehicle is equipped with two specific payloads, PL4 and PL5, concerning respectively the study of the natural and roughness induced transition. The paper is a survey on the design process of these two in-flight experiments and it covers the major analyses and findings encountered during the development of the payloads. A large amount of transition criteria have been investigated and used to estimate either the dangerousness of the height of the distributed roughness, arising due to nose erosion, or the effectiveness of height of the isolated roughness element forcing the boundary layer transition. Supporting the PL4 design, linear stability computations and CFD analyses have been performed by CIRA on the EXPERT flight vehicle to determine the amplification factor of the boundary layer instabilities at different point of the re-entry trajectory. Ground test experiments regarding the PL5 are carried on in the Mach 6 VKI H3 Hypersonic Wind Tunnel with a Reynolds numbers ranging from 18E6/m to 26E6/m. Infrared measurements (Stanton number) and flow visualization are used on a 1/16 scaled model of the EXPERT vehicle and a flat plate to validate the Potter and Whitfield criterion as a suitable methodology for ground-to-flight extrapolation and the payload design.

Infrared Images of Boundary Layer Transition on the D8 Transport Configuration in the LaRC 14- by 22-Foot Subsonic Tunnel

NASA Technical Reports Server (NTRS)

Mason, Michelle L.; Gatlin, Gregory M.

2015-01-01

Grit, trip tape, or trip dots are routinely applied on the leading-edge regions of the fuselage, wings, tails or nacelles of wind tunnel models to trip the flow from laminar to turbulent. The thickness of the model's boundary layer is calculated for nominal conditions in the wind tunnel test to determine the effective size of the trip dots, but the flow over the model may not transition as intended for runs with different flow conditions. Temperature gradients measured with an infrared camera can be used to detect laminar to turbulent boundary layer transition on a wind tunnel model. This non-intrusive technique was used in the NASA Langley 14- by 22-Foot Subsonic Tunnel to visualize the behavior of the flow over a D8 transport configuration model. As the flow through the wind tunnel either increased to or decreased from the run conditions, a sufficient temperature difference existed between the air and the model to visualize the transition location (due to different heat transfer rates through the laminar and the turbulent boundary layers) for several runs in this test. Transition phenomena were visible without active temperature control in the atmospheric wind tunnel, whether the air was cooler than the model or vice-versa. However, when the temperature of the model relative to the air was purposely changed, the ability to detect transition in the infrared images was enhanced. Flow characteristics such as a wing root horseshoe vortex or the presence of fore-body vortical flows also were observed in the infrared images. The images of flow features obtained for this study demonstrate the usefulness of current infrared technology in subsonic wind tunnel tests.

Direct Numerical Simulation of Transition in a Swept-Wing Boundary Layer

NASA Technical Reports Server (NTRS)

Duan, Lian; Choudhari, Meelan M.; Li, Fei

2013-01-01

Direct numerical simulation (DNS) is performed to examine laminar to turbulent transition due to high-frequency secondary instability of stationary crossflow vortices in a subsonic swept-wing boundary layer for a realistic natural-laminar-flow airfoil configuration. The secondary instability is introduced via inflow forcing derived from a two-dimensional, partial-differential-equation based eigenvalue computation; and the mode selected for forcing corresponds to the most amplified secondary instability mode which, in this case, derives a majority of its growth from energy production mechanisms associated with the wall-normal shear of the stationary basic state. Both the growth of the secondary instability wave and the resulting onset of laminar-turbulent transition are captured within the DNS computations. The growth of the secondary instability wave in the DNS solution compares well with linear secondary instability theory when the amplitude is small; the linear growth is followed by a region of reduced growth resulting from nonlinear effects before an explosive onset of laminar breakdown to turbulence. The peak fluctuations are concentrated near the boundary layer edge during the initial stage of transition, but rapidly propagates towards the surface during the process of laminar breakdown. Both time-averaged statistics and flow visualization based on the DNS reveal a sawtooth transition pattern that is analogous to previously documented surface flow visualizations of transition due to stationary crossflow instability. The memory of the stationary crossflow vortex is found to persist through the transition zone and well beyond the location of the maximum skin friction.

Multi-layer planting as a strategy of greening the transitional space in high-rise buildings: A review

NASA Astrophysics Data System (ADS)

Prihatmanti, Rani; Taib, Nooriati

2018-03-01

The issues regarding the rapid development in the urban have resulted in the increasing number of infrastructure built, including the high-rise buildings to accommodate the urban dwellers. Lack of greeneries due to the land limitation in the urban area has increased the surface radiation as well as the air temperature that leads to the Urban Heat Island (UHI) phenomena. Where urban land is limited, growing plants vertically could be a solution. Plants, which are widely known as one of the sustainability elements in the built environment could be integrated in building as a part of urban faming by growing edible plant species. This is also to address the food security issue in the urban as well as high-density cities. Since space is limited, the function of transitional space could be optimized for the green space. This paper explores the strategy of greening transitional space in the high-rise setting. To give a maximum impact in a limited space, multi-layer planting concept could be introduced. This concept is believed that multiple layers of plants could modify the microclimate, as well as the radiation to the building, compare to single layer plant. In addition to that, the method selected also determines the efficacy of the vertical greeneries. However, there are many other limitations related to the multi-layer planting method if installed in a transitional space that needs to be further studied. Despite its limitations, the application of vertical greeneries with multi-layer planting concept could be a promising solution for greening the limited space as well as improving the thermal comfort in the high-rise building.

Immunocytochemical and autoradiographic studies on the process of keratinization in avian epidermis suggests absence of keratohyalin.

PubMed

Alibardi, Lorenzo

2004-02-01

The process of keratinization in apteric avian epidermis and in scutate scales of some avian species has been studied by autoradiography for histidine and immunohistochemistry for keratins and other epidermal proteins. Acidic or basic alpha-keratins are present in basal, spinosus, and transitional layers, but are not seen in the corneous layer. Keratinization-specific alpha-keratins (AE2-positive) are observed in the corneous layer of apteric epidermis but not in that of scutate scales, which contain mainly beta-keratin. Alpha-keratin bundles accumulate along the plasma membrane of transitional cells of apteric epidermis. In contrast to the situation in scutate scales, in the transitional layer and in the lowermost part of the corneous layer of apteric epidermis, filaggrin-like, loricrin-like, and transglutaminase immunoreactivities are present. The lack of isopeptide bond immunoreactivity suggests that undetectable isopeptide bonds are present in avian keratinocytes. Using immunogold ultrastructural immunocytochemistry a low but localized loricrin-like and, less, filaggrin-like labeling is seen over round-oval granules or vesicles among keratin bundles of upper spinosus and transitional keratinocytes of apteric epidermis. Filaggrin-and loricrin-labeling are absent in alpha-keratin bundles localized along the plasma membrane and in the corneous layer, formerly considered keratohyalin. Using ultrastructural autoradiography for tritiated histidine, occasional trace grains are seen among these alpha-keratin bundles. A different mechanism of redistribution of matrix and corneous cell envelope proteins probably operates in avian keratinocytes as compared to that of mammals. Keratin bundles are compacted around the lipid-core of apteric epidermis keratinocytes, which do not form complex chemico/mechanical-resistant corneous cell envelopes as in mammalian keratinocytes. These observations suggest that low amounts of matrix proteins are present among keratin bundles of avian keratinocytes and that keratohyalin granules are absent. Copyright 2003 Wiley-Liss, Inc.

Epithelial-mesenchymal transition in colonies of rhesus monkey embryonic stem cells: a model for processes involved in gastrulation.

PubMed

Behr, Rüdiger; Heneweer, Carola; Viebahn, Christoph; Denker, Hans-Werner; Thie, Michael

2005-01-01

Rhesus monkey embryonic stem (rhES) cells were grown on mouse embryonic fibroblast (MEF) feeder layers for up to 10 days to form multilayered colonies. Within this period, stem cell colonies differentiated transiently into complex structures with a disc-like morphology. These complex colonies were characterized by morphology, immunohistochemistry, and marker mRNA expression to identify processes of epithelialization as well as epithelial-mesenchymal transition (EMT) and pattern formation. Typically, differentiated colonies were comprised of an upper and a lower ES cell layer, the former growing on top of the layer of MEF cells whereas the lower ES cell layer spread out underneath the MEF cells. Interestingly, in the central part of the colonies, a roundish pit developed. Here the feeder layer disappeared, and upper layer cells seemed to ingress and migrate through the pit downward to form the lower layer while undergoing a transition from the epithelial to the mesenchymal phenotype, which was indicated by the loss of the marker proteins E-cadherin and ZO-1 in the lower layer. In support of this, we found a concomitant 10-fold upregulation of the gene Snail2, which is a key regulator of the EMT process. Conversion of epiblast to mesoderm was also indicated by the regulated expression of the mesoderm marker Brachyury. An EMT is a characteristic process of vertebrate gastrulation. Thus, these rhES cell colonies may be an interesting model for studies on some basic processes involved in early primate embryogenesis and may open new ways to study the regulation of EMT in vitro.

Tephrostratigraphy of Grotta del Cavallo, Southern Italy: Insights on the chronology of Middle to Upper Palaeolithic transition in the Mediterranean

NASA Astrophysics Data System (ADS)

Zanchetta, Giovanni; Giaccio, Biagio; Bini, Monica; Sarti, Lucia

2018-02-01

The Grotta del Cavallo contains one of the most important stratification of Mousterian, Uluzzian and Final Epigravettian tecnocomplexes; its chronology is of paramount importance for understanding the timing of the transition between Middle and Upper Palaeolithic in the Mediterranean region as well as the demise of the Neanderthal and the dispersal of the first anatomically modern humans through Europe. Within the stratigraphy of the cave three different volcanic ash layers occur (layer G, Fa and C-II). They are located in the middle section of the Mousterian (layer G), in between the Mousterian and Uluzzian layers (layer Fa) and on top of the Uluzzian horizons (layer C-II). The three tephra layers were chemically fingerprinted and correlated to well-known and precisely dated widespread Late Pleistocene tephra markers. Specifically, layer G, Fa and C-II were correlated to the X-6 (108.7 ± 0.9 ka), Y-6 (45.5 ± 1.0 ka) and Campanian Ignimbrite (39.85 ± 0.14 ka), respectively. These findings provide robust chronological points allowing to conclude that: (i) the Mousterian occupation of the cave took place after the fall of the sea level following the MIS 5e high-stand; (ii) the Mousterian-Uluzzian boundary can be dated to 45.5 ± 1.0 ka and climatostratigraphically firmly placed at the transition between the Greenland Interstadial 12 (GI12)-Greenland Stadial 12 (GS12); (iii) the Uluzzian lasted for at least five millennial spanning the GS12-GI9 period and ended at beginning of the Heinrich Event 4.

Phase transitions and kinetic properties of gold nanoparticles confined between two-layer graphene nanosheets

NASA Astrophysics Data System (ADS)

Wang, Gang; Wu, Nanhua; Chen, Jionghua; Wang, Jinjian; Shao, Jingling; Zhu, Xiaolei; Lu, Xiaohua; Guo, Lucun

2016-11-01

The thermodynamic and kinetic behaviors of gold nanoparticles confined between two-layer graphene nanosheets (two-layer-GNSs) are examined and investigated during heating and cooling processes via molecular dynamics (MD) simulation technique. An EAM potential is applied to represent the gold-gold interactions while a Lennard-Jones (L-J) potential is used to describe the gold-GNS interactions. The MD melting temperature of 1345 K for bulk gold is close to the experimental value (1337 K), confirming that the EAM potential used to describe gold-gold interactions is reliable. On the other hand, the melting temperatures of gold clusters supported on graphite bilayer are corrected to the corresponding experimental values by adjusting the εAu-C value. Therefore, the subsequent results from current work are reliable. The gold nanoparticles confined within two-layer GNSs exhibit face center cubic structures, which is similar to those of free gold clusters and bulk gold. The melting points, heats of fusion, and heat capacities of the confined gold nanoparticles are predicted based on the plots of total energies against temperature. The density distribution perpendicular to GNS suggests that the freezing of confined gold nanoparticles starts from outermost layers. The confined gold clusters exhibit layering phenomenon even in liquid state. The transition of order-disorder in each layer is an essential characteristic in structure for the freezing phase transition of the confined gold clusters. Additionally, some vital kinetic data are obtained in terms of classical nucleation theory.

Transition Prediction in Hypersonic Boundary Layers Using Receptivity and Freestream Spectra

NASA Technical Reports Server (NTRS)

Balakumar, P.; Chou, Amanda

2016-01-01

Boundary-layer transition in hypersonic flows over a straight cone can be predicted using measured freestream spectra, receptivity, and threshold values for the wall pressure fluctuations at the transition onset points. Simulations are performed for hypersonic boundary-layer flows over a 7-degree half-angle straight cone with varying bluntness at a freestream Mach number of 10. The steady and the unsteady flow fields are obtained by solving the two-dimensional Navier-Stokes equations in axisymmetric coordinates using a 5th-order accurate weighted essentially non-oscillatory (WENO) scheme for space discretization and using a third-order total-variation-diminishing (TVD) Runge-Kutta scheme for time integration. The calculated N-factors at the transition onset location increase gradually with increasing unit Reynolds numbers for flow over a sharp cone and remain almost the same for flow over a blunt cone. The receptivity coefficient increases slightly with increasing unit Reynolds numbers. They are on the order of 4 for a sharp cone and are on the order of 1 for a blunt cone. The location of transition onset predicted from the simulation including the freestream spectrum, receptivity, and the linear and the weakly nonlinear evolutions yields a solution close to the measured onset location for the sharp cone. The simulations over-predict transition onset by about twenty percent for the blunt cone.

Effects of Wing Sweep on Boundary-layer Transition for a Smooth F-14A Wing at Mach Numbers from 0.700 to 0.825

NASA Technical Reports Server (NTRS)

Anderson, Bianca Trujillo; Meyer, Robert R., Jr.

1990-01-01

The results are discussed of the variable sweep transition flight experiment (VSTFE). The VSTFE was a natural laminar flow experiment flown on the swing wing F-14A aircraft. The main objective of the VSTFE was to determine the effects of wing sweep on boundary layer transition at conditions representative of transport aircraft. The experiment included the flight testing of two laminar flow wing gloves. Glove 1 was a cleanup of the existing F-14A wing. Glove 2, not discussed herein, was designed to provide favorable pressure distributions for natural laminar flow at Mach number (M) 0.700. The transition locations presented for glove 1 were determined primarily by using hot film sensors. Boundary layer rake data was provided as a supplement. Transition data were obtained for leading edge wing sweeps of 15, 20, 25, 30, and 35 degs, with Mach numbers ranging from 0.700 to 0.825, and altitudes ranging from 10,000 to 35,000 ft. Results show that a substantial amount of laminar flow was maintained at all the wing sweeps evaluated. The maximum transition Reynolds number of 13.7 x 10(exp 6) was obtained for the condition of 15 deg of sweep, M = 0.800, and an altitude of 20,000 ft.

Relaxation dynamics of magnetization transitions in synthetic antiferromagnet with perpendicular anisotropy

NASA Astrophysics Data System (ADS)

Talantsev, A.; Lu, Y.; Fache, T.; Lavanant, M.; Hamadeh, A.; Aristov, A.; Koplak, O.; Morgunov, R.; Mangin, S.

2018-04-01

Two synthetic antiferromagnet bilayer systems with strong perpendicular anisotropy CoFeB/Ta/CoFeB and Pt/Co/Ir/Co/Pt have been grown using sputtering techniques. For both systems two types of magnetization transitions have been studied. The first one concerns transitions from a state where magnetizations of the two magnetic layers are parallel (P state) to a state where magnetizations of the two layers are aligned antiparallel (AP state). The second one concerns transitions between the two possible antiparallel alignments (AP+  to AP-). For both systems and both transitions after-effect measurements can be understood in the frame of nucleation—propagation model. Time derivative analysis of magnetic relaxation curves and mapping of the first order reversal curves at different temperature allowed us to demonstrate the presence of different pinning centers, which number can be controlled by magnetic field and temperature.

Prediction and Analysis of the Nonsteady Transition and Separation Processes on an Oscillating Wind Turbine Airfoil using the \\gamma-Re_\\theta Transition Model.

DOE Office of Scientific and Technical Information (OSTI.GOV)

Nandi, Taraj; Brasseur, James; Vijayakumar, Ganesh

2016-01-04

This study is aimed at gaining insight into the nonsteady transitional boundary layer dynamics of wind turbine blades and the predictive capabilities of URANS based transition and turbulence models for similar physics through the analysis of a controlled flow with similar nonsteady parameters.

Near-optimal energy transitions for energy-state trajectories of hypersonic aircraft

NASA Technical Reports Server (NTRS)

Ardema, M. D.; Bowles, J. V.; Terjesen, E. J.; Whittaker, T.

1992-01-01

A problem of the instantaneous energy transition that occurs in energy-state approximation is considered. The transitions are modeled as a sequence of two load-factor bounded paths (either climb-dive or dive-climb). The boundary-layer equations associated with the energy-state dynamic model are analyzed to determine the precise location of the transition.

Observations of the Evolution of Turbulent Dissipation within the Ocean Surface Boundary Layer: an OSMOSIS study

NASA Astrophysics Data System (ADS)

Lucas, N. S.; Allen, J.; Belcher, S. E.; Boyd, T.; Brannigan, L.; Inall, M.; Palmer, M.; Polton, J.; Rippeth, T. P.

2016-02-01

This study presents a new 9.5 day dataset showing the evolution of the Ocean Surface Boundary Layer (OSBL) and dissipation of turbulence kinetic energy (TKE), carried out as part of OSMOSIS[i], at a location in the North East Atlantic Ocean in September 2012. The TKE dissipation measurements were made using three methods; (i) repeated profiling between 100m and the surface by an Ocean Microstructure glider, (ii) three series of profiles made using a loosely tethered velocity microstructure glider and (iii) a moored pulse-pulse coherent high frequency ADCP. Supporting measurements show the evolution of the water column structure, including surface wave measurements from a TRIAXYS wave buoy. This data shows two distinct regimes; the first, spanning 4 days with relatively low winds, displays a distinct diurnal cycle with the deepening of the active mixing layer during the night which shoaled during the day. The second spanned a significant storm, (with maximum winds speeds reaching 20 m s-1 and significant wave heights reaching 6 m), during which, rather than a deepening of the mixed layer as predicted by classical theory, the primary effect was a broadening of the transition layer, similar to that found by Dohan and Davies (2011). During the storm, significant dissipation was observed throughout the surface mixed layer and into the transition layer, driving fluxes of heat downwards through the base of the surface mixed layer. [i] Ocean Surface Mixing and Submesoscale Interaction Study Dohan, K. & Davis, R.E., 2011. Mixing in the Transition Layer during Two Storm Events. Journal of Physical Oceanography. 41 (1). pp. 42-66.

Observations of transitional tidal boundary layers and their impact on sediment transport in the Great Bay, NH

NASA Astrophysics Data System (ADS)

Koetje, K. M.; Foster, D. L.; Lippmann, T. C.

2017-12-01

Observations of the vertical structure of tidal flows obtained in 2016 and 2017 in the Great Bay Estuary, NH show evidence of transitional tidal boundary layers at deployment locations on shallow mudflats. High-resolution bottom boundary layer currents, hydrography, turbidity, and bed characteristics were observed with an acoustic Doppler current profiler (ADCP), an acoustic Doppler velocimeter (ADV), conductivity-depth-temperature (CTD) sensors, optical backscatter sensors, multibeam bathymetric surveys, and sediment grab samples and cores. Over the 2.5 m tidal range and at water depths ranging from 0.3 m to 1.5 m at mean lower low water, peak flows ranged from 10 cm/s to 30 cm/s and were primarily driven by the tides. A downward-looking ADCP captured the velocity profile over the lowest 1 m of the water column. Results consistently show a dual-log layer system, with evidence of a lower layer within 15 cm of the bed, another layer above approximately 30 cm from the bed, and a transitional region where the flow field rotates between that the two layers that can be as much as 180 degrees out of phase. CTD casts collected over a complete tidal cycle suggest that the weak thermohaline stratification is not responsible for development of the two layers. On the other hand, acoustic and optical backscatter measurements show spatial and temporal variability in suspended sediments that are dependant on tidal phase. Current work includes an examination of the relationship between sediment concentrations in the water column and velocity profile characteristics, along with an effort to quantify the impact of rotation and dual-log layers on bed stress.

Shear-Induced Isostructural Phase Transition and Metallization of Layered Tungsten Disulfide under Nonhydrostatic Compression

DOE PAGES

Duwal, Sakun; Yoo, Choong-Shik

2016-02-16

Pressure-induced structural and electronic transformations of tungsten disulfide (WS 2) have been studied to 60 GPa, in both hydrostatic and non-hydrostatic conditions, using four-probe electrical resistance measurements, micro-Raman spectroscopy and synchrotron x-ray diffraction. Our results show the evidence for an isostructural phase transition from hexagonal 2H c phase to hexagonal 2H a phase, which accompanies the metallization at ~37 GPa. This isostructural transition occurs displacively over a large pressure range between 15 and 45 GPa and is driven by the presence of strong shear stress developed in the layer structure of WS 2 under non-hydrostatic compression. Interestingly, this transition ismore » absent in hydrostatic conditions using He pressure medium, underscoring its strong dependence on the state of stress. We also attribute the absence to the incorporation of He atoms between the layers, mitigating the development of shear stress. We also conjecture a possibility of magnetic ordering in WS 2 that may occur at low temperature near the metallization.« less

The effect of small angle of attack on the laminar-turbulent transition in boundary layer on swept wing at Mach number M=2

NASA Astrophysics Data System (ADS)

Semionov, N. V.; Yermolaev, Yu. G.; Kosinov, A. D.; Semenov, A. N.; Smorodsky, B. V.; Yatskikh, A. A.

2017-10-01

The paper is devoted to an experimental and theoretical study of effect of small angle of attack on disturbances evolution and laminar-turbulent transition in a supersonic boundary layer on swept wing at Mach number M=2. The experiments are conducted at the low nose supersonic wind tunnel T-325 of ITAM. Model is a symmetrical wing with a 45° sweep angle, a 3 percent-thick circular-arc airfoil. The transition location is determined using a hot-wire anemometer. Confirmed monotonous growth of the transition Reynolds numbers with increasing of angle of attack from -2° to 2.5°. The experimental data on the influence of the angle of attack on the disturbances evolution in the supersonic boundary layer on the swept wing model are obtained. Calculations on the effect of small angles of attack on the development of perturbations are made in the framework of the linear theory of stability. A good qualitative correspondence of theoretical and experimental data are obtained.

Electric-Field Control of Oxygen Vacancies and Magnetic Phase Transition in a Cobaltite/Manganite Bilayer

NASA Astrophysics Data System (ADS)

Cui, B.; Song, C.; Li, F.; Zhong, X. Y.; Wang, Z. C.; Werner, P.; Gu, Y. D.; Wu, H. Q.; Saleem, M. S.; Parkin, S. S. P.; Pan, F.

2017-10-01

Manipulation of oxygen vacancies (VO ) in single oxide layers by varying the electric field can result in significant modulation of the ground state. However, in many oxide multilayers with strong application potentials, e.g., ferroelectric tunnel junctions and solid-oxide fuel cells, understanding VO behavior in various layers under an applied electric field remains a challenge, owing to complex VO transport between different layers. By sweeping the external voltage, a reversible manipulation of VO and a corresponding fixed magnetic phase transition sequence in cobaltite/manganite (SrCoO3 -x/La0.45Sr0.55MnO3 -y ) heterostructures are reported. The magnetic phase transition sequence confirms that the priority of electric-field-induced VO formation or annihilation in the complex bilayer system is mainly determined by the VO formation energies and Gibbs free-energy differences, which is supported by theoretical analysis. We not only realize a reversible manipulation of the magnetic phase transition in an oxide bilayer but also provide insight into the electric-field control of VO engineering in heterostructures.

Boundary Layer Transition Experiments in Support of the Hypersonics Program

NASA Technical Reports Server (NTRS)

Berry, Scott A.; Chen, Fang-Jenq; Wilder, Michael C.; Reda, Daniel C.

2007-01-01

Two experimental boundary layer transition studies in support of fundamental hypersonics research are reviewed. The two studies are the HyBoLT flight experiment and a new ballistic range effort. Details are provided of the objectives and approach associated with each experimental program. The establishment of experimental databases from ground and flight are to provide better understanding of high-speed flows and data to validate and guide the development of simulation tools.

Generalized self-consistent method for predicting the effective elastic properties of composites with random hybrid structures

NASA Astrophysics Data System (ADS)

Pan'kov, A. A.

1997-05-01

The feasibility of using a generalized self-consistent method for predicting the effective elastic properties of composites with random hybrid structures has been examined. Using this method, the problem is reduced to solution of simpler special averaged problems for composites with single inclusions and corresponding transition layers in the medium examined. The dimensions of the transition layers are defined by correlation radii of the composite random structure of the composite, while the heterogeneous elastic properties of the transition layers take account of the probabilities for variation of the size and configuration of the inclusions using averaged special indicator functions. Results are given for a numerical calculation of the averaged indicator functions and analysis of the effect of the micropores in the matrix-fiber interface region on the effective elastic properties of unidirectional fiberglass—epoxy using the generalized self-consistent method and compared with experimental data and reported solutions.

Boundary Layer Transition Flight Experiment Overview and In-Situ Measurements

NASA Technical Reports Server (NTRS)

Berger, Karen T.; Anderson, Brian P.; Campbell, Charles H.; Garske, Michael T.; Saucedo, Luis A.; Kinder, Gerald R.

2010-01-01

In support of the Boundary Layer Transition Flight Experiment (BLT FE) Project, a manufactured protuberance tile was installed on the port wing of Space Shuttle Orbiter Discovery for the flights of STS-119, STS-128 and STS-131. Additional instrumentation was installed in order to obtain more spatially resolved measurements downstream of the protuberance. This paper provides an overview of the BLT FE Project. Significant efforts were made to place the protuberance at an appropriate location on the Orbiter and to design the protuberance to withstand the expected environments. A high-level overview of the in-situ flight data is presented, along with a summary of the comparisons between pre- and post-flight analysis predictions and flight data. Comparisons show that predictions for boundary layer transition onset time closely match the flight data, while predicted temperatures were significantly higher than observed flight temperatures.

A quiet flow Ludwieg tube for study of transition in compressible boundary layers: Design and feasibility

NASA Technical Reports Server (NTRS)

Schneider, Steven P.

1991-01-01

Laminar-turbulent transition in high speed boundary layers is a complicated problem which is still poorly understood, partly because of experimental ambiguities caused by operating in noisy wind tunnels. The NASA Langley experience with quiet tunnel design has been used to design a quiet flow tunnel which can be constructed less expensively. Fabrication techniques have been investigated, and inviscid, boundary layer, and stability computer codes have been adapted for use in the nozzle design. Construction of such a facility seems feasible, at a reasonable cost. Two facilities have been proposed: a large one, with a quiet flow region large enough to study the end of transition, and a smaller and less expensive one, capable of studying low Reynolds number issues such as receptivity. Funding for either facility remains to be obtained, although key facility elements have been obtained and are being integrated into the existing Purdue supersonic facilities.

First-order wetting transition at a liquid-vapor interface

NASA Technical Reports Server (NTRS)

Schmidt, J. W.; Moldover, M. R.

1983-01-01

Evidence from reflectance and contact angle measurements is presented that three-phase mixtures of i-C3H7OH-C7F14 exhibit a first-order wetting phase transition at the liquid-vapor interface at 38 C. Equilibration phenomena support this interpretation. Ellipsometry was used to measure the apparent thickness of the intruding layer in the three-phase mixture. At temperatures slightly above the wetting temperature T(w), the intruding layer's thickness is several hundred angstroms and its variation with temperature is extremely weak. Below T(w), three-phase contact can occur between the vapor and both the upper and lower liquid phases; one of the angles which characterizes this contact has a very simple temperature dependence. The thickness of the intruding layer, monitored as the solutions approached equilibrium, is found to depend quite weakly on the height spanned by the upper liquid phase in the vicinity of a first-order wetting transition.

Possibilities for drag reduction by boundary layer control

NASA Technical Reports Server (NTRS)

Naiman, I.

1946-01-01

The mechanics of laminar boundary layer transition are reviewed. Drag possibilities for boundary layer control are analyzed using assumed conditions of transition Reynolds number, inlet loss, number of slots, blower efficiency, and duct losses. Although the results of such analysis are highly favorable, those obtained by experimental investigations yield conflicting results, showing only small gains, and sometimes losses. Reduction of this data indicates that there is a lower limit to the quantity of air which must be removed at the slot in order to stabilize the laminar flow. The removal of insufficient air permits transition to occur while the removal of excessive amounts of air results in high power costs, with a net drag increases. With the estimated value of flow coefficient and duct losses equal to half the dynamic pressure, drag reductions of 50% may be obtained; with twice this flow coefficient, the drag saving is reduced to 25%.

Crystal and Magnetic Structures in Layered, Transition Metal Dihalides and Trihalides

DOE PAGES

McGuire, Michael A.

2017-04-27

Materials composed of two dimensional layers bonded to one another through weak van der Waals interactions often exhibit strongly anisotropic behaviors and can be cleaved into very thin specimens and sometimes into monolayer crystals. Interest in such materials is driven by the study of low dimensional physics and the design of functional heterostructures. Binary compounds with the compositions MX 2 and MX 3 where M is a metal cation and X is a halogen anion often form such structures. Magnetism can be incorporated by choosing a transition metal with a partially filled d-shell for M, enabling ferroic responses for enhancedmore » functionality. Here we give a brief overview of binary transition metal dihalides and trihalides, summarizing their crystallographic properties and long-range-ordered magnetic structures, focusing on those materials with layered crystal structures and partially filled d-shells required for combining low dimensionality and cleavability with magnetism.« less

Carbon and nitrogen abundances determined from transition layer lines

NASA Technical Reports Server (NTRS)

Boehm-Vitense, Erika; Mena-Werth, Jose

1992-01-01

The possibility of determining relative carbon, nitrogen, and silicon abundances from the emission-line fluxes in the lower transition layers between stellar chromospheres and coronae is explored. Observations for main-sequence and luminosity class IV stars with presumably solar element abundances show that for the lower transition layers Em = BT sup -gamma. For a given carbon abundance the constants gamma and B in this relation can be determined from the C II and C IV emission-line fluxes. From the N V and S IV lines, the abundances of these elements relative to carbon can be determined from their surface emission-line fluxes. Ratios of N/C abundances determined in this way for some giants and supergiants agree within the limits of errors with those determined from molecular bands. For giants, an increase in the ratio of N/C at B-V of about 0.8 is found, as expected theoretically.

Percolation in real interdependent networks

NASA Astrophysics Data System (ADS)

Radicchi, Filippo

2015-07-01

The function of a real network depends not only on the reliability of its own components, but is affected also by the simultaneous operation of other real networks coupled with it. Whereas theoretical methods of direct applicability to real isolated networks exist, the frameworks developed so far in percolation theory for interdependent network layers are of little help in practical contexts, as they are suited only for special models in the limit of infinite size. Here, we introduce a set of heuristic equations that takes as inputs the adjacency matrices of the layers to draw the entire phase diagram for the interconnected network. We demonstrate that percolation transitions in interdependent networks can be understood by decomposing these systems into uncoupled graphs: the intersection among the layers, and the remainders of the layers. When the intersection dominates the remainders, an interconnected network undergoes a smooth percolation transition. Conversely, if the intersection is dominated by the contribution of the remainders, the transition becomes abrupt even in small networks. We provide examples of real systems that have developed interdependent networks sharing cores of `high quality’ edges to prevent catastrophic failures.

Characterization of a highly efficient chevron-shaped anti-contamination device

NASA Astrophysics Data System (ADS)

Fiore, M.; Vermeersch, O.; Forte, M.; Casalis, G.; François, C.

2016-04-01

This paper is devoted to the characterization of an optimized chevron-shaped anti-contamination device (ACD). This device can prevent efficiently the propagation of turbulence from the fuselage along the attachment line (hypothetical streamline that spreads the flow going to suction side and the one going to pressure side) of swept wings and enables the development of a new laminar boundary layer downstream. More specifically, the aim is to prevent boundary-layer transition along the attachment line by a contamination process. This process is characterized by the typical Reynolds number overline{R} and the associated Poll's criterion. Thus, ACD efficiency will be expressed in terms of overline{R} values. Some experiments performed on a new numerically optimized ACD have shown its ability to prevent leading-edge contamination up to overline{R} values close to the natural transition process of the laminar boundary layer along the attachment line. The corresponding stability analysis of the laminar boundary layer is made using the Görtler-Hämmerlin stability approach. The study is completed with the different transition processes that can occur downstream the attachment line, around the airfoil, especially with crossflow analysis.

Electrochemically-induced reversible transition from the tunneled to layered polymorphs of manganese dioxide

NASA Astrophysics Data System (ADS)

Lee, Boeun; Yoon, Chong Seung; Lee, Hae Ri; Chung, Kyung Yoon; Cho, Byung Won; Oh, Si Hyoung

2014-08-01

Zn-ion batteries are emerging energy storage systems eligible for large-scale applications, such as electric vehicles. These batteries consist of totally environmentally-benign electrode materials and potentially manufactured very economically. Although Zn/α-MnO2 systems produce high energy densities of 225 Wh kg-1, larger than those of conventional Mg-ion batteries, they show significant capacity fading during long-term cycling and suffer from poor performance at high current rates. To solve these problems, the concrete reaction mechanism between α-MnO2 and zinc ions that occur on the cathode must be elucidated. Here, we report the intercalation mechanism of zinc ions into α-MnO2 during discharge, which involves a reversible phase transition of MnO2 from tunneled to layered polymorphs by electrochemical reactions. This transition is initiated by the dissolution of manganese from α-MnO2 during discharge process to form layered Zn-birnessite. The original tunneled structure is recovered by the incorporation of manganese ions back into the layers of Zn-birnessite during charge process.

Acid attack on hydrated cement — Effect of mineral acids on the degradation process

DOE Office of Scientific and Technical Information (OSTI.GOV)

Gutberlet, T.; Hilbig, H.; Beddoe, R.E., E-mail: robin.beddoe@tum.de

During acid attack on concrete structural components, a degraded layer develops whose properties as a protective barrier are decisive for durability. {sup 29}Si NMR spectroscopy and {sup 27}Al NMR spectroscopy were used with XRD to investigate the degraded layer on hardened cement paste exposed to HCl and H{sub 2}SO{sub 4}. The layer comprises an amorphous silica gel with framework silicates, geminate and single silanol groups in which Si is substituted by Al. Amorphous Al(OH){sub 3} and Fe(OH){sub 3} are present. The gel forms by polycondensation and cross-linking of C-A-S-H chains at AlO{sub 4} bridging tetrahedra. In the transition zone betweenmore » the degraded layer and the undamaged material, portlandite dissolves and Ca is removed from the C-A-S-H phases maintaining their polymer structure at first. With HCl, monosulphate in the transition zone is converted into Friedel's salt and ettringite. With H{sub 2}SO{sub 4}, gypsum precipitates near the degradation front reducing the thickness of the transition zone and the rate of degradation.« less

Synthesis-microstructure-performance relationship of layered transition metal oxides as cathode for rechargeable sodium batteries prepared by high-temperature calcination.

PubMed

Xie, Man; Luo, Rui; Lu, Jun; Chen, Renjie; Wu, Feng; Wang, Xiaoming; Zhan, Chun; Wu, Huiming; Albishri, Hassan M; Al-Bogami, Abdullah S; El-Hady, Deia Abd; Amine, Khalil

2014-10-08

Research on sodium batteries has made a comeback because of concern regarding the limited resources and cost of lithium for Li-ion batteries. From the standpoint of electrochemistry and economics, Mn- or Fe-based layered transition metal oxides should be the most suitable cathode candidates for affordable sodium batteries. Herein, this paper reports a novel cathode material, layered Na1+x(Fey/2Niy/2Mn1-y)1-xO2 (x = 0.1-0.5), synthesized through a facile coprecipitation process combined with subsequent calcination. For such cathode material calcined at 800 °C for 20 h, the Na/Na1+x(Fey/2Niy/2Mn1-y)1-xO2 (x = 0.4) electrode exhibited a good capacity of 99.1 mAh g(-1) (cycled at 1.5-4.0 V) and capacity retention over 87% after 50 cycles. Optimization of this material would make layered transition metal oxides a strong candidate for the Na-ion battery cathode.

Surface nematic order in iron pnictides

DOE PAGES

Song, Kok Wee; Koshelev, Alexei E.

2016-09-09

Electronic nematicity plays an important role in iron-based superconductors. These materials have a layered structure and the theoretical description of their magnetic and nematic transitions has been well established in the two-dimensional approximation, i.e., when the layers can be treated independently. However, the interaction between iron layers mediated by electron tunneling may cause nontrivial three-dimensional behavior. Starting from the simplest model for orbital nematic in a single layer, we investigate the influence of interlayer tunneling on the bulk nematic order and a possible preemptive state where this order is only formed near the surface. In addition, we found that themore » interlayer tunneling suppresses the bulk nematicity, which makes favorable the formation of a surface nematic order above the bulk transition temperature. The purely electronic tunneling Hamiltonian, however, favors a nematic order parameter that alternates from layer to layer. The uniform bulk state typically observed experimentally may be stabilized by the coupling with the elastic lattice deformation. Depending on the strength of this coupling, we found three regimes: (i) surface nematic and alternating bulk order, (ii) surface nematic and uniform bulk order, and (iii) uniform bulk order without the intermediate surface phase. Lastly, the intermediate surface-nematic state may resolve the current controversy about the existence of a weak nematic transition in the compound BaFe 2As 2-xP x .« less

Supersonic/Hypersonic Correlations for In-Cavity Transition and Heating Augmentation

NASA Technical Reports Server (NTRS)

Everhart, Joel L.

2011-01-01

Laminar-entry cavity heating data with a non-laminar boundary layer exit flow have been retrieved from the database developed at Mach 6 and 10 in air on large flat plate models for the Space Shuttle Return-To-Flight Program. Building on previously published fully laminar and fully turbulent analysis methods, new descriptive correlations of the in-cavity floor-averaged heating and endwall maximum heating have been developed for transitional-to-turbulent exit flow. These new local-cavity correlations provide the expected flow and geometry conditions for transition onset; they provide the incremental heating augmentation induced by transitional flow; and, they provide the transitional-to-turbulent exit cavity length. Furthermore, they provide an upper application limit for the previously developed fully-laminar heating correlations. An example is provided that demonstrates simplicity of application. Heating augmentation factors of 12 and 3 above the fully laminar values are shown to exist on the cavity floor and endwall, respectively, if the flow exits in fully tripped-to-turbulent boundary layer state. Cavity floor heating data in geometries installed on the windward surface of 0.075-scale Shuttle wind tunnel models have also been retrieved from the boundary layer transition database developed for the Return-To-Flight Program. These data were independently acquired at Mach 6 and Mach 10 in air, and at Mach 6 in CF4. The correlation parameters for the floor-averaged heating have been developed and they offer an exceptionally positive comparison to previously developed laminar-cavity heating correlations. Non-laminar increments have been extracted from the Shuttle data and they fall on the newly developed transitional in-cavity correlations, and they are bounded by the 95% correlation prediction limits. Because the ratio of specific heats changes along the re-entry trajectory, turning angle into a cavity and boundary layer flow properties may be affected, raising concerns regarding the application validity of the heating augmentation predictions.

VO{sub 2} (A): Reinvestigation of crystal structure, phase transition and crystal growth mechanisms

DOE Office of Scientific and Technical Information (OSTI.GOV)

Rao Popuri, Srinivasa; University of Bordeaux, ICMCB, UPR 9048, F-33608 Pessac; National Institute for Research and Development in Electrochemistry and Condensed Matter, Timisoara, Plautius Andronescu Str. No. 1, 300224 Timisoara

2014-05-01

Well crystallized VO{sub 2} (A) microrods were grown via a single step hydrothermal reaction in the presence of V{sub 2}O{sub 5} and oxalic acid. With the advantage of high crystalline samples, we propose P4/ncc as an appropriate space group at room temperature. From morphological studies, we found that the oriented attachment and layer by layer growth mechanisms are responsible for the formation of VO{sub 2} (A) micro rods. The structural and electronic transitions in VO{sub 2} (A) are strongly first order in nature, and a marked difference between the structural transition temperatures and electronic transitions temperature was evidenced. The reversiblemore » intra- (LTP-A to HTP-A) and irreversible inter- (HTP-A to VO{sub 2} (M1)) structural phase transformations were studied by in-situ powder X-ray diffraction. Attempts to increase the size of the VO{sub 2} (A) microrods are presented and the possible formation steps for the flower-like morphologies of VO{sub 2} (M1) are described. - Graphical abstract: Using a single step and template free hydrothermal synthesis, well crystallized VO{sub 2} (A) microrods were prepared and the P4/ncc space group was assigned to the room temperature crystal structure. Reversible and irreversible phase transitions among different VO{sub 2} polymorphs were identified and their progressive nature was highlighted. Attempts to increase the microrods size, involving layer by layer formation mechanisms, are presented. - Highlights: • Highly crystallized VO{sub 2} (A) microrods were grown via a single step hydrothermal process. • The P4/ncc space group was determined for VO{sub 2} (A) at room temperature. • The electronic structure and progressive nature of the structural phase transition were investigated. • A weak coupling between structural and electronic phase transitions was identified. • Different crystallite morphologies were discussed in relation with growth mechanisms.« less

The atmospheric boundary layer evening transitions: an observational and numerical study from two different datasets

NASA Astrophysics Data System (ADS)

Sastre, Mariano; Yagüe, Carlos; Román-Cascón, Carlos; Maqueda, Gregorio; Ander Arrillaga, Jon

2015-04-01

In this work we study the temporal evolution of the Atmospheric Boundary Layer (ABL) along the transition period from a diurnal typical convection to a nocturnal more frequently stable situation. This period is known as late afternoon or evening transition, depending on the specific definitions employed by different authors [1]. In order to obtain a proper characterization, we try to learn whether or not the behaviour of these transitional boundary layers is strongly dependent on local conditions. To do so, two sets of evening transitions are studied from data collected at two different experimental sites. These locations correspond to research facilities named CIBA (Spain) and CRA (France), which are the places where atmospheric field campaigns have been conducted during the last years, such as CIBA2008 and BLLAST 2011, respectively. In order to get comparable situations, we focus especially on transitions with weak synoptic forcing, and consider daily astronomical sunset as a reference time. A statistical analysis on main parameters related to the transition is carried out for both locations, and the average behaviour is shown as well as extreme values according to the timing. A similar pattern in the qualitative evolution of many variables is found. Nevertheless, several relevant differences in the progress of key variables are obtained too. Moisture, both from the soil and the air, is thought to have great relevance in explaining many of the differences found between the two sites. Some case studies are explored, focusing on the role played by the atmospheric turbulence. Complementary, numerical experiments are also performed using the Weather Research and Forecast (WRF) mesoscale model, in order to test the role of humidity, by artificially varying it in some of the simulations. [1] Lothon, M. and coauthors (2014): The BLLAST field experiment: Boundary-Layer Late Afternoon and Sunset Turbulence. Atmos. Chem. Phys., 14, 10931-10960.

A three-dimensional simulation of transition and early turbulence in a time-developing mixing layer

NASA Technical Reports Server (NTRS)

Cain, A. B.; Reynolds, W. C.; Ferziger, J. H.

1981-01-01

The physics of the transition and early turbulence regimes in the time developing mixing layer was investigated. The sensitivity of the mixing layer to the disturbance field of the initial condition is considered. The growth of the momentum thickness, the mean velocity profile, the turbulence kinetic energy, the Reynolds stresses, the anisotropy tensor, and particle track pictures of computations are all examined in an effort to better understand the physics of these regimes. The amplitude, spectrum shape, and random phases of the initial disturbance field were varied. A scheme of generating discrete orthogonal function expansions on some nonuniform grids was developed. All cases address the early or near field of the mixing layer. The most significant result shows that the secondary instability of the mixing layer is produced by spanwise variations in the straining field of the primary vortex structures.

Rough-to-smooth transition of an equilibrium neutral constant stress layer

NASA Technical Reports Server (NTRS)

Logan, E., Jr.; Fichtl, G. H.

1975-01-01

Purpose of research on rough-to-smooth transition of an equilibrium neutral constant stress layer is to develop a model for low-level atmospheric flow over terrains of abruptly changing roughness, such as those occurring near the windward end of a landing strip, and to use the model to derive functions which define the extent of the region affected by the roughness change and allow adequate prediction of wind and shear stress profiles at all points within the region. A model consisting of two bounding logarithmic layers and an intermediate velocity defect layer is assumed, and dimensionless velocity and stress distribution functions which meet all boundary and matching conditions are hypothesized. The functions are used in an asymptotic form of the equation of motion to derive a relation which governs the growth of the internal boundary layer. The growth relation is used to predict variation of surface shear stress.

Enhanced magnetocaloric effect material

DOEpatents

Lewis, Laura J. H.

2006-07-18

A magnetocaloric effect heterostructure having a core layer of a magnetostructural material with a giant magnetocaloric effect having a magnetic transition temperature equal to or greater than 150 K, and a constricting material layer coated on at least one surface of the magnetocaloric material core layer. The constricting material layer may enhance the magnetocaloric effect by restriction of volume changes of the core layer during application of a magnetic field to the heterostructure. A magnetocaloric effect heterostructure powder comprising a plurality of core particles of a magnetostructural material with a giant magnetocaloric effect having a magnetic transition temperature equal to or greater than 150 K, wherein each of the core particles is encapsulated within a coating of a constricting material is also disclosed. A method for enhancing the magnetocaloric effect within a giant magnetocaloric material including the step of coating a surface of the magnetocaloric material with a constricting material is disclosed.

Turbulent Combustion Study of Scramjet Problem

DTIC Science & Technology

2015-08-01

boundary layer model for 2D simulations of a supersonic flat plate boundary layer . The inflow O2 has an average density of...flow above the flat plate has a transition from a laminar boundary layer to a turbulent boundary layer at a position downstream from the inlet. The...δ. Chapman [13] estimated the number of cells need to resolve the outer layer is proportional to Re0.4 for flat plat boundary layer and

Helioseismic Constraints on the Gradient of Angular Velocity at the Base of the Solar Convection Zone

NASA Technical Reports Server (NTRS)

Kosovichev, A. G.

1996-01-01

The layer of transition from the nearly rigid rotation of the radiative interior to the latitudinal differential rotation of the convection zone plays a significant role in the internal dynamics of the Sun. Using rotational splitting coefficients of the p-mode frequencies, obtained during 1986-1990 at the Big Bear Solar Observatory, we have found that the thickness of the transitional layer is 0.09 +/- 0.04 solar radii (63 +/- 28 Mm), and that most of the transition occurs beneath the adiabatically stratified part of the convection zone, as suggested by the dynamo theories of the 22 yr solar activity cycle.

Transition Studies on a Swept-Wing Model

NASA Technical Reports Server (NTRS)

Saric, William S.

1996-01-01

The present investigation contributes to the understanding of boundary-layer stability and transition by providing detailed measurements of carefully-produced stationary crossflow vortices. It is clear that a successful prediction of transition in swept-wing flows must include an understanding of the detailed physics involved. Receptivity and nonlinear effects must not be ignored. Linear stability theory correctly predicts the expected wavelengths and mode shapes for stationary crossflow, but fails to predict the growth rates, even for low amplitudes. As new computational and analytical methods are developed to deal with three-dimensional boundary layers, the data provided by this experiment will serve as a useful benchmark for comparison.

Determination of the energy structure of recombination centers in heavily doped AlxGa1-xN:Si epitaxial layers with x > 0.5

NASA Astrophysics Data System (ADS)

Osinnykh, I. V.; Malin, T. V.; Zhuravlev, K. S.

2018-03-01

The photoluminescence properties of the intensive defect-related emission in heavily doped Al x Ga l-x N:Si layers with x > 0.5 have been investigated by photoluminescence (PL) spectroscopy. The PL band in AlN was attributed to donor-acceptor (DA) transitions. At the lowest Al content, the impurity band merges with the conduction band and DA transitions are replaced by electron-acceptor transitions involving the same acceptor. The energy structure of recombination centers was obtained using the model of configuration coordinates for Al0.67Ga0.33N.

Evidence of a Transition Layer between the Free Surface and the Bulk.

PubMed

Ogieglo, Wojciech; Tempelman, Kristianne; Napolitano, Simone; Benes, Nieck E

2018-03-15

The free surface, a very thin layer at the interface between polymer and air, is considered the main source of the perturbations in the properties of ultrathin polymer films, i.e., nanoconfinement effects. The structural relaxation of such a layer is decoupled from the molecular dynamics of the bulk. The free surface is, in fact, able to stay liquid even below the temperature where the polymer resides in the glassy state. Importantly, this surface layer is expected to have a very sharp interface with the underlying bulk. Here, by analyzing the penetration of n-hexane into polystyrene films, we report on the existence of a transition region, not observed by previous investigations, extending for 12 nm below the free surface. The presence of such a layer permits reconciling the behavior of interfacial layers with current models and has profound implications on the performance of ultrathin membranes. We show that the expected increase in the flux of the permeating species is actually overruled by nanoconfinement.

Infrared fingerprints of few-layer black phosphorus

PubMed Central

Zhang, Guowei; Huang, Shenyang; Chaves, Andrey; Song, Chaoyu; Özçelik, V. Ongun; Low, Tony; Yan, Hugen

2017-01-01

Black phosphorus is an infrared layered material. Its bandgap complements other widely studied two-dimensional materials: zero-gap graphene and visible/near-infrared gap transition metal dichalcogenides. Although highly desirable, a comprehensive infrared characterization is still lacking. Here we report a systematic infrared study of mechanically exfoliated few-layer black phosphorus, with thickness ranging from 2 to 15 layers and photon energy spanning from 0.25 to 1.36 eV. Each few-layer black phosphorus exhibits a thickness-dependent unique infrared spectrum with a series of absorption resonances, which reveals the underlying electronic structure evolution and serves as its infrared fingerprints. Surprisingly, unexpected absorption features, which are associated with the forbidden optical transitions, have been observed. Furthermore, we unambiguously demonstrate that controllable uniaxial strain can be used as a convenient and effective approach to tune the electronic structure of few-layer black phosphorus. Our study paves the way for black phosphorus applications in infrared photonics and optoelectronics. PMID:28059084

Method for transition prediction in high-speed boundary layers, phase 2

NASA Astrophysics Data System (ADS)

Herbert, T.; Stuckert, G. K.; Lin, N.

1993-09-01

The parabolized stability equations (PSE) are a new and more reliable approach to analyzing the stability of streamwise varying flows such as boundary layers. This approach has been previously validated for idealized incompressible flows. Here, the PSE are formulated for highly compressible flows in general curvilinear coordinates to permit the analysis of high-speed boundary-layer flows over fairly general bodies. Vigorous numerical studies are carried out to study convergence and accuracy of the linear-stability code LSH and the linear/nonlinear PSE code PSH. Physical interfaces are set up to analyze the M = 8 boundary layer over a blunt cone calculated by using a thin-layer Navier Stokes (TNLS) code and the flow over a sharp cone at angle of attack calculated using the AFWAL parabolized Navier-Stokes (PNS) code. While stability and transition studies at high speeds are far from routine, the method developed here is the best tool available to research the physical processes in high-speed boundary layers.

Skin Friction and Transition Location Measurement on Supersonic Transport Models

NASA Technical Reports Server (NTRS)

Kennelly, Robert A., Jr.; Goodsell, Aga M.; Olsen, Lawrence E. (Technical Monitor)

2000-01-01

Flow visualization techniques were used to obtain both qualitative and quantitative skin friction and transition location data in wind tunnel tests performed on two supersonic transport models at Mach 2.40. Oil-film interferometry was useful for verifying boundary layer transition, but careful monitoring of model surface temperatures and systematic examination of the effects of tunnel start-up and shutdown transients will be required to achieve high levels of accuracy for skin friction measurements. A more common technique, use of a subliming solid to reveal transition location, was employed to correct drag measurements to a standard condition of all-turbulent flow on the wing. These corrected data were then analyzed to determine the additional correction required to account for the effect of the boundary layer trip devices.

Method of boronizing transition metal surfaces

DOEpatents

Koyama, Koichiro; Shimotake, Hiroshi.

1983-08-16

A method is presented for preparing a boride layer on a transition metal substrate for use in corrosive environments or as a harden surface in machine applications. This method is particularly useful in treating current collectors for use within a high temperature and corrosive electrochemical cell environment. A melt of a alkali metal boride tetrafluoride salt including such as KF to lower its melting point is prepared including a dissolved boron containing material, for instance NiB, MnB[sub 2], or CrB[sub 2]. A transition metal to be coated is immersed in the melt at a temperature of no more than 700 C and a surface boride layer of that transition metal is formed within a period of about 24 hours on the substrate surface. 4 figs.

Flight and wind-tunnel correlation of boundary-layer transition on the AEDC transition cone

NASA Technical Reports Server (NTRS)

Fisher, D. L.; Dougherty, N. S., Jr.

1982-01-01

Transition and fluctuating surface pressure data were acquired on a 10 deg included angle cone, using the same instrumentation and technique over a wide range of Mach and Reynolds numbers in 23 wind tunnels and in flight. Transition was detected with a traversing pitot-pressure probe in contact with the surface. The surface pressure fluctuations were measured with microphones set flush in the cone surface. Good correlation of end of transition Reynolds number RE(T) was obtained between data from the lower disturbance wind tunnels and flight up to a boundary layer edge Mach number, M(e) = 1.2. Above M(e) = 1.2, however, this correlation deteriorates, with the flight Re(T) being 25 to 30% higher than the wind tunnel Re(T) at M(e) = 1.6. The end of transition Reynolds number correlated within + or - 20% with the surface pressure fluctuations, according to the equation used. Broad peaks in the power spectral density distributions indicated that Tollmien-Schlichting waves were the probable cause of transition in flight and in some of the wind tunnels.

Molecular Origins of Thermal Transitions in Polyelectrolyte Assemblies

NASA Astrophysics Data System (ADS)

Yildirim, Erol; Zhang, Yanpu; Antila, Hanne S.; Lutkenhaus, Jodie L.; Sammalkorpi, Maria; Aalto Team; Texas A&M Team

2015-03-01

Polyelectrolyte (PE) multilayers and complexes formed from oppositely charged polymers can exhibit extraordinary superhydrophobicity, mechanical strength and responsiveness resulting in applications ranging functional membranes, optics, sensors and drug delivery. Depending on the assembly conditions, PE assemblies may undergo a thermal transition from glassy to soft behavior under heating. Our earlier work using thermal analysis measurements shows a distinct thermal transition for PE layer-by-layer (LbL) systems assembled with added salt but no analogous transition in films assembled without added salt or dry systems. These findings raise interesting questions on the nature of the thermal transition; here, we explore its molecular origins through characterization of the PE aggregates by temperature-controlled all-atom molecular dynamics simulations. We show via molecular simulations the thermal transition results from the existence of an LCST (lower critical solution temperature) in the PE systems: the diffusion behavior, hydrogen bond formation, and bridging capacity of water molecules plasticizing the complex changes at the transition temperature. We quantify the behavior, map its chemistry specificity through comparison of strongly and weakly charged PE complexes, and connect the findings to our interrelated QCM-D experiments.

Numerical solution of the hypersonic viscous-shock-layer equations for laminar, transitional, and turbulent flows of a perfect gas over blunt axially symmetric bodies

NASA Technical Reports Server (NTRS)

Anderson, E. C.; Moss, J. N.

1975-01-01

The viscous shock layer equations applicable to hypersonic laminar, transitional, and turbulent flows of a perfect gas over two-dimensional plane or axially symmetric blunt bodies are presented. The equations are solved by means of an implicit finite difference scheme, and the results are compared with a turbulent boundary layer analysis. The agreement between the two solution procedures is satisfactory for the region of flow where streamline swallowing effects are negligible. For the downstream regions, where streamline swallowing effects are present, the expected differences in the two solution procedures are evident.

Seismic constraints on the nature of lower crustal reflectors beneath the extending Southern Transition Zone of the Colorado Plateau, Arizona

USGS Publications Warehouse

Parsons, Thomas E.; Howie, John M.; Thompson, George A.

1992-01-01

We determine the reflection polarity and exploit variations in P and S wave reflectivity and P wave amplitude versus offset (AVO) to constrain the origin of lower crustal reflectivity observed on new three-component seismic data recorded across the structural transition of the Colorado Plateau. The near vertical incidence reflection data were collected by Stanford University in 1989 as part of the U.S. Geological Survey Pacific to Arizona Crustal Experiment that traversed the Arizona Transition Zone of the Colorado Plateau. The results of independent waveform modeling methods are consistent with much of the lower crustal reflectivity resulting from thin, high-impedance layers. The reflection polarity of the cleanest lower crustal events is positive, which implies that these reflections result from high-velocity contrasts, and the waveform character indicates that the reflectors are probably layers less than or approximately equal to 200 m thick. The lower crustal events are generally less reflective to incident S waves than to P waves, which agrees with the predicted behavior of high-velocity mafic layering. Analysis of the P wave AVO character of lower crustal reflections demonstrates that the events maintain a constant amplitude with offset, which is most consistent with a mafic-layering model. One exception is a high-amplitude (10 dB above background) event near the base of lower crustal reflectivity which abruptly decreases in amplitude at increasing offsets. The event has a pronounced S wave response, which along with its negative AVO trend is a possible indication of the presence of fluids in the lower crust. The Arizona Transition Zone is an active but weakly extended province, which causes us to discard models of lower crustal layering resulting from shearing because of the high degree of strain required to create such layers. Instead, we favor horizontal basaltic intrusions as the primary origin of high-impedance reflectors based on (1) The fact that most xenoliths in eruptive basalts of the Transition Zone are of mafic igneous composition, (2) indications that a pulse of magmatic activity crossed the Transition Zone in the late Tertiary period, and (3) the high regional heat flow observed in the Transition Zone. The apparent presence of fluids near the base of the reflective zone may indicate a partially molten intrusion. We present a mechanism by which magma can be trapped and be induced to intrude horizontally at rheologic contrasts in extending crust.

A new method for laminar boundary layer transition visualization in flight: Color changes in liquid crystal coatings

NASA Technical Reports Server (NTRS)

Holmes, B. J.; Gall, P. D.; Croom, C. C.; Manuel, G. S.; Kelliher, W. C.

1986-01-01

The visualization of laminar to turbulent boundary layer transition plays an important role in flight and wind-tunnel aerodynamic testing of aircraft wing and body surfaces. Visualization can help provide a more complete understanding of both transition location as well as transition modes; without visualization, the transition process can be very difficult to understand. In the past, the most valuable transition visualization methods for flight applications included sublimating chemicals and oil flows. Each method has advantages and limitations. In particular, sublimating chemicals are impractical to use in subsonic applications much above 20,000 feet because of the greatly reduced rates of sublimation at lower temperatures (less than -4 degrees Farenheit). Both oil flow and sublimating chemicals have the disadvantage of providing only one good data point per flight. Thus, for many important flight conditions, transition visualization has not been readily available. This paper discusses a new method for visualizing transition in flight by the use of liquid crystals. The new method overcomes the limitations of past techniques, and provides transition visualization capability throughout almost the entire altitude and speed ranges of virtually all subsonic aircraft flight envelopes. The method also has wide applicability for supersonic transition visualization in flight and for general use in wind tunnel research over wide subsonic and supersonic speed ranges.

Altitude transitions in energy climbs

NASA Technical Reports Server (NTRS)

Weston, A. R.; Cliff, E. M.; Kelley, H. J.

1982-01-01

The aircraft energy-climb trajectory for configurations with a sharp transonic drag rise is well known to possess two branches in the altitude/Mach-number plane. Transition in altitude between the two branches occurs instantaneously, a 'corner' in the minimum-time solution obtained with the energy-state model. If the initial and final values of altitude do not lie on the energy-climb trajectory, then additional jumps (crude approximations to dives and zooms) are required at the initial and terminal points. With a singular-perturbation approach, a 'boundary-layer' correction is obtained for each altitude jump, the transonic jump being a so-called 'internal' boundary layer, different in character from the initial and terminal layers. The determination of this internal boundary layer is examined and some computational results for an example presented.

Excitation of hybridized Dirac plasmon polaritons and transition radiation in multi-layer graphene traversed by a fast charged particle

NASA Astrophysics Data System (ADS)

Akbari, Kamran; Mišković, Zoran L.; Segui, Silvina; Gervasoni, Juana L.; Arista, Néstor R.

2018-06-01

We analyze the energy loss channels for a fast charged particle traversing a multi-layer graphene (MLG) structure with N layers under normal incidence. Focusing on a terahertz (THz) range of frequencies, and assuming equally doped graphene layers with a large enough separation d between them to neglect interlayer electron hopping, we use the Drude model for two-dimensional conductivity of each layer to describe hybridization of graphene’s Dirac plasmon polaritons (DPPs). Performing a layer decomposition of ohmic energy losses, which include excitation of hybridized DPPs (HDPPs), we have found for N = 3 that the middle HDPP eigenfrequency is not excited in the middle layer due to symmetry constraint, whereas the excitation of the lowest HDPP eigenfrequency produces a Fano resonance in the graphene layer that is first traversed by the charged particle. While the angular distribution of transition radiation emitted in the far field region also shows asymmetry with respect to the traversal order by the incident charged particle at supra-THz frequencies, the integrated radiative energy loss is surprisingly independent of both d and N for N ≤ 5, which is explained by a dominant role of the outer graphene layers in transition radiation. We have further found that the integrated ohmic energy loss in optically thin MLG scales as ∝1/N at sub-THz frequencies, which is explained by exposing the role of dissipative processes in graphene at low frequencies. Finally, prominent peaks are observed at supra-THz frequencies in the integrated ohmic energy loss for MLG structures that are not optically thin. The magnitude of those peaks is found to scale with N for N ≥ 2, while their shape and position replicate the peak in a double-layer graphene (N = 2), which is explained by arguing that plasmon hybridization in such MLG structures is dominated by electromagnetic interaction between the nearest-neighbor graphene layers.

Excitation of hybridized Dirac plasmon polaritons and transition radiation in multi-layer graphene traversed by a fast charged particle.

PubMed

Akbari, Kamran; Mišković, Zoran L; Segui, Silvina; Gervasoni, Juana L; Arista, Néstor R

2018-06-01

We analyze the energy loss channels for a fast charged particle traversing a multi-layer graphene (MLG) structure with N layers under normal incidence. Focusing on a terahertz (THz) range of frequencies, and assuming equally doped graphene layers with a large enough separation d between them to neglect interlayer electron hopping, we use the Drude model for two-dimensional conductivity of each layer to describe hybridization of graphene's Dirac plasmon polaritons (DPPs). Performing a layer decomposition of ohmic energy losses, which include excitation of hybridized DPPs (HDPPs), we have found for N = 3 that the middle HDPP eigenfrequency is not excited in the middle layer due to symmetry constraint, whereas the excitation of the lowest HDPP eigenfrequency produces a Fano resonance in the graphene layer that is first traversed by the charged particle. While the angular distribution of transition radiation emitted in the far field region also shows asymmetry with respect to the traversal order by the incident charged particle at supra-THz frequencies, the integrated radiative energy loss is surprisingly independent of both d and N for N ≤ 5, which is explained by a dominant role of the outer graphene layers in transition radiation. We have further found that the integrated ohmic energy loss in optically thin MLG scales as ∝1/N at sub-THz frequencies, which is explained by exposing the role of dissipative processes in graphene at low frequencies. Finally, prominent peaks are observed at supra-THz frequencies in the integrated ohmic energy loss for MLG structures that are not optically thin. The magnitude of those peaks is found to scale with N for N ≥ 2, while their shape and position replicate the peak in a double-layer graphene (N = 2), which is explained by arguing that plasmon hybridization in such MLG structures is dominated by electromagnetic interaction between the nearest-neighbor graphene layers.

The energy input mechanism into the lower transition regions between stellar chromospheres and coronae

NASA Technical Reports Server (NTRS)

Boehm-Vitense, Erika

1988-01-01

The ratio of the emission line fluxes for the C II and C IV lines in the lower transition regions (T = 30,000 to 100,000 K) between stellar chromospheres and transition layers is shown to depend mainly on the temperature gradient in the line emitting regions which can therefore be determined from this line ratio. From the observed constant (within the limits of observational error) ratio of the emission line fluxes of the C II (1335 A) and C IV (1550 A) lines it is concluded that the temperature gradients in the lower transition layers are similar for the large majority of stars independently of T sub eff, L, and degree of activity. This means that the temperature dependence of the damping length for the mechanical flux must be the same for all these stars. Since for different kinds of mechanical fluxes the dependence of the damping length on gas pressure and temperature is quite different, it is concluded that the same heating mechanism must be responsible for the heating of all the lower transition layers of these stars, regardless of their chromospheric activity. Only the amount of mechanical flux changes. The T Tauri stars are exceptions: their emission lines are probably mainly due to circumstellar material.

An O3-type Oxide with Low Sodium Content as the Phase-Transition-Free Anode for Sodium-Ion Batteries.

PubMed

Zhao, Chenglong; Avdeev, Maxim; Chen, Liquan; Hu, Yong-Sheng

2018-06-11

Layered transition metal oxides Na x MO 2 (M=transition metal) with P2 or O3 structure have attracted attention in sodium-ion batteries (NIBs). A universal law is found to distinguish structural competition between P2 and O3 types based on the ratio of interlayer distances of the alkali metal layer d (O-Na-O) and transition-metal layer d (O-M-O) . The ratio of about 1.62 can be used as an indicator. O3-type Na 0.66 Mg 0.34 Ti 0.66 O 2 oxide is prepared as a stable anode for NIBs, in which the low Na-content (ca. 0.66) usually undergoes a P2-type structure with respect to Na x MO 2 . This material delivers an available capacity of about 98 mAh g -1 within a voltage range of 0.4-2.0 V and exhibits a better cycling stability (ca. 94.2 % of capacity retention after 128 cycles). In situ X-ray diffraction reveals a single-phase reaction in the discharge-charge process, which is different from the common phase transitions reported in O3-type electrodes, ensuring long-term cycling stability. © 2018 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.

Crystal structure across the β to α phase transition in thermoelectric Cu 2–xSe

DOE Office of Scientific and Technical Information (OSTI.GOV)

Eikeland, Espen; Blichfeld, Anders B.; Borup, Kasper A.

Here, the crystal structure uniquely imparts the specific properties of a material, and thus provides the starting point for any quantitative understanding of thermoelectric properties. Cu 2–xSe is an intensely studied high performing, non-toxic and cheap thermoelectric material, and here for the first time, the average structure of β-Cu 2–xSe is reported based on analysis of multi-temperature single-crystal X-ray diffraction data. It consists of Se–Cu layers with additional copper between every alternate layer. The structural changes during the peculiar zT enhancing phase transition mainly consist of changes in the inter-layer distance coupled with subtle Cu migration. Just prior to themore » transition the structure exhibits strong negative thermal expansion due to the reordering of Cu atoms, when approached from low temperatures. The phase transition is fully reversible and group–subgroup symmetry relations are derived that relate the low-temperature β-phase to the high-temperature α-phase. Weak superstructure reflections are observed and a possible Cu ordering is proposed. The structural rearrangement may have a significant impact on the band structure and the Cu rearrangement may also be linked to an entropy increase. Both factors potentially contribute to the extraordinary zT enhancement across the phase transition.« less

Crystal structure across the β to α phase transition in thermoelectric Cu 2–xSe

DOE PAGES

Eikeland, Espen; Blichfeld, Anders B.; Borup, Kasper A.; ...

2017-06-13

Here, the crystal structure uniquely imparts the specific properties of a material, and thus provides the starting point for any quantitative understanding of thermoelectric properties. Cu 2–xSe is an intensely studied high performing, non-toxic and cheap thermoelectric material, and here for the first time, the average structure of β-Cu 2–xSe is reported based on analysis of multi-temperature single-crystal X-ray diffraction data. It consists of Se–Cu layers with additional copper between every alternate layer. The structural changes during the peculiar zT enhancing phase transition mainly consist of changes in the inter-layer distance coupled with subtle Cu migration. Just prior to themore » transition the structure exhibits strong negative thermal expansion due to the reordering of Cu atoms, when approached from low temperatures. The phase transition is fully reversible and group–subgroup symmetry relations are derived that relate the low-temperature β-phase to the high-temperature α-phase. Weak superstructure reflections are observed and a possible Cu ordering is proposed. The structural rearrangement may have a significant impact on the band structure and the Cu rearrangement may also be linked to an entropy increase. Both factors potentially contribute to the extraordinary zT enhancement across the phase transition.« less

Roles of Engineering Correlations in Hypersonic Entry Boundary Layer Transition Prediction

NASA Technical Reports Server (NTRS)

Campbell, Charles H.; Anderson, Brian P.; King, Rudolph A.; Kegerise, Michael A.; Berry, Scott A.; Horvath, Thomas J.

2010-01-01

Efforts to design and operate hypersonic entry vehicles are constrained by many considerations that involve all aspects of an entry vehicle system. One of the more significant physical phenomenon that affect entry trajectory and thermal protection system design is the occurrence of boundary layer transition from a laminar to turbulent state. During the Space Shuttle Return To Flight activity following the loss of Columbia and her crew of seven, NASA's entry aerothermodynamics community implemented an engineering correlation based framework for the prediction of boundary layer transition on the Orbiter. The methodology for this implementation relies upon similar correlation techniques that have been is use for several decades. What makes the Orbiter boundary layer transition correlation implementation unique is that a statistically significant data set was acquired in multiple ground test facilities, flight data exists to assist in establishing a better correlation and the framework was founded upon state of the art chemical nonequilibrium Navier Stokes flow field simulations. Recent entry flight testing performed with the Orbiter Discovery now provides a means to validate this engineering correlation approach to higher confidence. These results only serve to reinforce the essential role that engineering correlations currently exercise in the design and operation of entry vehicles. The framework of information related to the Orbiter empirical boundary layer transition prediction capability will be utilized to establish a fresh perspective on this role, and to discuss the characteristics which are desirable in a next generation advancement. The details of the paper will review the experimental facilities and techniques that were utilized to perform the implementation of the Orbiter RTF BLT Vsn 2 prediction capability. Statistically significant results for multiple engineering correlations from a ground testing campaign will be reviewed in order to describe why only certain correlations were selected for complete implementation to support the Shuttle Program. Historical Orbiter flight data on early boundary layer transition due to protruding gap fillers will be described in relation to the selected empirical correlations. In addition, Orbiter entry flight testing results from the BLT Flight Experiment will be discussed in relation to these correlations. Applicability of such correlations to the entry design problem will be reviewed, and finally a perspective on the desirable characteristics for a next generation capability based on high fidelity physical models will be provided.

Computational Study of Hypersonic Boundary Layer Stability on Cones

NASA Astrophysics Data System (ADS)

Gronvall, Joel Edwin

Due to the complex nature of boundary layer laminar-turbulent transition in hypersonic flows and the resultant effect on the design of re-entry vehicles, there remains considerable interest in developing a deeper understanding of the underlying physics. To that end, the use of experimental observations and computational analysis in a complementary manner will provide the greatest insights. It is the intent of this work to provide such an analysis for two ongoing experimental investigations. The first focuses on the hypersonic boundary layer transition experiments for a slender cone that are being conducted at JAXA's free-piston shock tunnel HIEST facility. Of particular interest are the measurements of disturbance frequencies associated with transition at high enthalpies. The computational analysis provided for these cases included two-dimensional CFD mean flow solutions for use in boundary layer stability analyses. The disturbances in the boundary layer were calculated using the linear parabolized stability equations. Estimates for transition locations, comparisons of measured disturbance frequencies and computed frequencies, and a determination of the type of disturbances present were made. It was found that for the cases where the disturbances were measured at locations where the flow was still laminar but nearly transitional, that the highly amplified disturbances showed reasonable agreement with the computations. Additionally, an investigation of the effects of finite-rate chemistry and vibrational excitation on flows over cones was conducted for a set of theoretical operational conditions at the HIEST facility. The second study focuses on transition in three-dimensional hypersonic boundary layers, and for this the cone at angle of attack experiments being conducted at the Boeing/AFOSR Mach-6 quiet tunnel at Purdue University were examined. Specifically, the effect of surface roughness on the development of the stationary crossflow instability are investigated in this work. One standard mean flow solution and two direct numerical simulations of a slender cone at an angle of attack were computed. The direct numerical simulations included a digitally-filtered, randomly distributed surface roughness and were performed using a high-order, low-dissipation numerical scheme on appropriately resolved grids. Comparisons with experimental observations showed excellent qualitative agreement. Comparisons with similar previous computational work were also made and showed agreement in the wavenumber range of the most unstable crossflow modes.

DOE Office of Scientific and Technical Information (OSTI.GOV)

Jellison, G. E.; Aytug, T.; Lupini, A. R.

Nanostructured glass films, which are fabricated using spinodally phase-separated low-alkali glasses, have several interesting and useful characteristics, including being robust, non-wetting and antireflective. Spectroscopic ellipsometry measurements have been performed on one such film and its optical properties were analyzed using a 5-layer structural model of the near-surface region. Since the glass and the film are transparent over the spectral region of the measurement, the Sellmeier model is used to parameterize the dispersion in the refractive index. To simulate the variation of the optical properties of the film over the spot size of the ellipsometer (~ 3 × 5 mm), themore » Sellmeier amplitude is convoluted using a Gaussian distribution. The transition layers between the ambient and the film and between the film and the substrate are modeled as graded layers, where the refractive index varies as a function of depth. These layers are modeled using a two-component Bruggeman effective medium approximation where the two components are the layer above and the layer below. Lastly, the fraction is continuous through the transition layer and is modelled using the incomplete beta function.« less

Layering PLGA-based electrospun membranes and cell sheets for engineering cartilage-bone transition.

PubMed

Mouthuy, P-A; El-Sherbini, Y; Cui, Z; Ye, H

2016-04-01

It is now widely acknowledged that implants that have been designed with an effort towards reconstructing the transition between tissues might improve their functionality and integration in vivo. This paper contributes to the development of improved treatment for articular cartilage repair by exploring the potential of the combination of electrospinning technology and cell sheet engineering to create cartilage tissue. Poly(lactic-co-glycolic acid) (PLGA) was used to create the electrospun membranes. The focus being on the cartilage-bone transition, collagen type I and hydroxyapatite (HA) were also added to the scaffolds to increase the histological biocompatibility. Human mesenchymal stem cells (hMSCs) were cultured in thermoresponsive dishes to allow non-enzymatic removal of an intact cell layer after reaching confluence. The tissue constructs were created by layering electrospun membranes with sheets of hMSCs and were cultured under chondrogenic conditions for up to 21 days. High viability was found to be maintained in the multilayered construct. Under chondrogenic conditions, reverse-transcription-polymerase chain reaction (RT-PCR) and immunohistochemistry have shown high expression levels of collagen type X, a form of collagen typically found in the calcified zone of articular cartilage, suggesting an induction of chondrocyte hypertrophy in the PLGA-based scaffolds. To conclude, this paper suggests that layering electrospun scaffolds and cell sheets is an efficient approach for the engineering of tissue transitions, and in particular the cartilage-bone transition. The use of PLGA-based scaffold might be particularly useful for the bone-cartilage reconstruction, since the differentiated tissue constructs seem to show characteristics of calcified cartilage. Copyright © 2013 John Wiley & Sons, Ltd.

Laminar-Turbulent Transition Behind Discrete Roughness Elements in a High-Speed Boundary Layer

NASA Technical Reports Server (NTRS)

Choudhari, Meelan M.; Li, Fei; Wu, Minwei; Chang, Chau-Lyan; Edwards, Jack R., Jr.; Kegerise, Michael; King, Rudolph

2010-01-01

Computations are performed to study the flow past an isolated roughness element in a Mach 3.5, laminar, flat plate boundary layer. To determine the effects of the roughness element on the location of laminar-turbulent transition inside the boundary layer, the instability characteristics of the stationary wake behind the roughness element are investigated over a range of roughness heights. The wake flow adjacent to the spanwise plane of symmetry is characterized by a narrow region of increased boundary layer thickness. Beyond the near wake region, the centerline streak is surrounded by a pair of high-speed streaks with reduced boundary layer thickness and a secondary, outer pair of lower-speed streaks. Similar to the spanwise periodic pattern of streaks behind an array of regularly spaced roughness elements, the above wake structure persists over large distances and can sustain strong enough convective instabilities to cause an earlier onset of transition when the roughness height is sufficiently large. Time accurate computations are performed to clarify additional issues such as the role of the nearfield of the roughness element during the generation of streak instabilities, as well as to reveal selected details of their nonlinear evolution. Effects of roughness element shape on the streak amplitudes and the interactions between multiple roughness elements aligned along the flow direction are also investigated.

Hydrogen jet combustion in a scramjet combustor with the rearwall-expansion cavity

NASA Astrophysics Data System (ADS)

Zhang, Yan-Xiang; Wang, Zhen-Guo; Sun, Ming-Bo; Yang, Yi-Xin; Wang, Hong-Bo

2018-03-01

This study is carried out to experimentally investigate the combustion characteristics of the hydrogen jet flame stabilized by the rearwall-expansion cavity in a model scramjet combustor. The flame distributions are characterized by the OH* spontaneous emission images, and the dynamic features of the flames are studied through the high speed framing of the flame luminosity. The combustion modes are further analyzed based on the visual flame structure and wall pressure distributions. Under the present conditions, the combustion based on the rearwall-expansion cavity appears in two distinguished modes - the typical cavity shear-layer stabilized combustion mode and the lifted-shear-layer stabilized combustion mode. In contrast with the shear-layer stabilized mode, the latter holds stronger flame. The transition from shear-layer stabilized combustion mode to lifted-shear-layer stabilized mode usually occurs when the equivalence ratio is high enough. While the increases of the offset ratio and upstream injection distance both lead to weaker jet-cavity interactions, cause longer ignition delay, and thus delay the mode transition. The results reveal that the rearwall-expansion cavity with an appropriate offset ratio should be helpful in delaying mode transition and preventing thermal choke, and meanwhile just brings minor negative impact on the combustion stability and efficiency.

The Influence of Hydrofoil Oscillation on Boundary Layer Transition and Cavitation Noise.

DTIC Science & Technology

1981-04-01

p., and V. are fluid density, reference free-stream AVERAGED static pressure and reference free-stream velocity, respec- ORSPL3. Lair tively. S3.1...of cavitation on a propeller in both uni- ly, the location of boundary layer transition with the foil in form and nonuniform flow. He concluded that...the presence of oscillation must be determined either theoretically or ex- sheet and bubble cavitation in nonuniform flow can be perimentally. Thirdly

Transitional Boundary Layers Under the Influence of High Free Stream Turbulence, Intensive Wall Cooling and High Pressure Gradients in Hot Gas Circulation. Ph.D. Thesis - Technische Hochschule, Karlsruhe, 1985

NASA Technical Reports Server (NTRS)

Rued, Klaus

1987-01-01

The requirements for fundamental experimental studies of the influence of free stream turbulence, pressure gradients and wall cooling are discussed. Under turbine-like free stream conditions, comprehensive tests of transitional boundary layers with laminar, reversing and turbulent flow increments were performed to decouple the effects of the parameters and to determine the effects during mutual interaction.

Chromospheric Lyman-Alpha SpectroPolarimeter (CLASP)

NASA Technical Reports Server (NTRS)

Kano, Ryohei; Bando, Takamasa; Narukage, Noriyuki; Ishikawa, Ryoko; Kubo, Masahito; Katsukawa, Yukio; Ishikawa, Shin-­nosuke; Hara, Hirohisa; Suematsu, Yoshinori; Giono, Gabriel;

Conceptualization and Simulation of the Alaskan Arctic Tundra Landscape Evolution Using the Alaska Thermokarst Model

NASA Astrophysics Data System (ADS)

Bolton, W. R.; Lara, M. J.; Genet, H.; Romanovsky, V. E.; McGuire, A. D.

2016-12-01

The Arctic, including Alaska, is currently undergoing a change in climate, with observed increases in both mean surface temperature and precipitation. The combination of these increases in precipitation and temperature has resulted in a permafrost condition that is susceptible to thermokarst. Changes in the landscape due to thermokarst takes place whenever ice-rich permafrost thaws and the land surface subsides due to the volume loss when ground-ice transitions to water. The important processes associated with thermokarst include surface ponding, changes in topography, vegetation distribution, soil moisture conditions, drainage patterns, and related erosion. The Alaska Thermokarst Model (ATM) is a large-scale, state-and-transition model designed to simulate transitions between landscape units affected by thermokarst disturbance. The ATM using a frame-based methodology to track cohorts transitions and their respective proportions within each model grid cell. In the arctic tundra environment, the ATM tracks thermokarst related transitions among wetland tundra, graminoid tundra,shrub tundra and lakes. The transition from one cohort to another due to thermokarst processes can take place if thaw reaches ice-rich ground layers either due to pulse disturbance or due to gradual active layer deepening that eventually results in penetration of the protective layer. The protective layer buffers the ice-rich soils from the land surface and is critical to determine how susceptible an area is to thermokarst degradation. The initial landcover distribution is based upon analysis of compiled remote sensing data sets at 30-m resolution. Remote sensing analysis and field measurements from previous and ongoing studies are used to determine the ice-content of the soil, the drainage efficiency (or the ability of the landscape to store or transport water), the cumulative probability of thermokarst initiation, distance from rivers, lake dynamics (increasing, decreasing, or stable), and other factors which help determine landscape transition rates. Tundra types are allowed to transition from one type to another (for example, wetland tundra to graminoid tundra) under favorable climatic conditions. In this study, we present our conceptualization and initial simulation results from in the arctic regions of Alaska.

Chemical solution seed layer for rabits tapes

DOEpatents

Goyal, Amit; Paranthaman, Mariappan; Wee, Sung-Hun

2014-06-10

A method for making a superconducting article includes the steps of providing a biaxially textured substrate. A seed layer is then deposited. The seed layer includes a double perovskite of the formula A.sub.2B'B''O.sub.6, where A is rare earth or alkaline earth metal and B' and B'' are different rare earth or transition metal cations. A superconductor layer is grown epitaxially such that the superconductor layer is supported by the seed layer.

Control of secondary instability of the crossflow and Görtler-like vortices (Success and problems)

NASA Astrophysics Data System (ADS)

Kozlov, Viktor V.; Grek, Genrich R.

The secondary instability on a group of crossflow vortices developing in a swept wing boundary layer is described. It is shown that, for travelling waves, there is a region of linear development, and the growth rate of disturbances appreciably depends on the separation between the vortices. Methods of controlling the secondary instability of the vortices by a controlled wave and local suction are proposed and substantiated. The stability of a flat plate boundary layer modulated by G&ou ml;rtler-like stationary vortices is described. Vortices were generated inside the boundary layer by means of roughness elements arranged in a regular array along the spanwise (z) direction. Transition is not caused directly by these structures, but by the growth of small amplitude travelling waves riding on top of the steady vortices. This situation is analogous to the transition process in Görtler and cross-flows. The waves were found to amplify up to a stage where higher harmonics are gener ated, leading to turbulent breakdown and disintegration of the spanwise boundary layer structure. For strong modulations, the observed instability is quite powerful, and can be excited "naturally" by small uncontrollable background disturbances. Controlled oscillations were then introduced by means of a vibrating ribbon, allowing a detailed investigation of the wave characteristics. The instability seems to be associated with the spanwise gradients of the mean flow, , and at all z-positions, the maximum wave amplitude was found at a wall-normal position where the mean velocity is equal to the phase velocity of the wave, U(y)=c, i.e., at the local critical layer. Unstable waves were observed at frequency well above those for which Tollmien-Schlichting (TS) waves amplify in the Blasius boundary layer. Excitation at lower frequencies and milder basic flow modulation showed that TS-type waves may a lso develop. Study of the transition control in that flow by means of riblets shows that the effect of the riblets is to suppress longitudinal vortex structures in a boundary layer. The boundary layer becomes stable with respect to high-frequency travelling waves, which cause the transition in the absence of the riblets.

Combined use of EPR and 23Na MAS NMR spectroscopy for assessing the properties of the mixed cobalt-nickel-manganese layers of P3-NayCo1-2xNixMnxO2.

PubMed

Kalapsazova, M; Ivanova, S; Kukeva, R; Simova, S; Wegner, S; Zhecheva, E; Stoyanova, R

2017-10-11

Knowledge on the formation of mixed transition metal layers on lithium and sodium transition metal oxides, Li/Na(Co,Ni,Mn,)O 2 , determines the ability to control their electrochemical properties as electrode materials in alkaline ion batteries. Taking this into account, herein we combine the EPR and 23 Na MAS NMR spectroscopic techniques to gain insights into the structural peculiarities of the mixed cobalt-nickel-manganese layers of Na y Co 1-2x Ni x Mn x O 2 with a three-layer stacking (P3-type) structure. Two types of compositions are examined where diamagnetic Co 3+ and paramagnetic Ni 3+ and Mn 4+ are stabilized: Na 2/3 Co 1/3 Ni 1/3 Mn 1/3 O 2 and Na 1/2 Ni 1/2 Mn 1/2 O 2 . EPR spectroscopy operating in the X- and Q-band region is applied with an aim to improve the spectra resolution and, on the other hand, to provide straightforward information on the coordination of the transition metal ions inside the layers. The analysis of EPR spectra is based on the reference for the Mn 4+ and Ni 2+ ions occurring simultaneously in oxides with two layer stacking, P2-Na 2/3 Ni 1/3 Mn 2/3 O 2 . Complementary to EPR, 23 Na MAS NMR spectroscopy at high spinning rates is undertaken to assess the local structure of the Na nucleus in the layered P3-Na y Co 1-2x Ni x Mn x O 2 oxides. All results are discussed taking into account the EPR and NMR data for the well-known lithium analogues O3-LiCo 1/3 Ni 1/3 Mn 1/3 O 2 and O3-LiNi 1/2 Mn 1/2 O 2 . Finally, the structure peculiarities of the transition metal layers extracted from the EPR and NMR methods are demonstrated by electrochemical intercalation of Li + ions into P3-Na y Co 1-2x Ni x Mn x O 2 .

Mechanism and microstructures in Ga2O3 pseudomartensitic solid phase transition.

PubMed

Zhu, Sheng-Cai; Guan, Shu-Hui; Liu, Zhi-Pan

2016-07-21

Solid-to-solid phase transition, although widely exploited in making new materials, challenges persistently our current theory for predicting its complex kinetics and rich microstructures in transition. The Ga2O3α-β phase transformation represents such a common but complex reaction with marked change in cation coordination and crystal density, which was known to yield either amorphous or crystalline products under different synthetic conditions. Here we, via recently developed stochastic surface walking (SSW) method, resolve for the first time the atomistic mechanism of Ga2O3α-β phase transformation, the pathway of which turns out to be the first reaction pathway ever determined for a new type of diffusionless solid phase transition, namely, pseudomartensitic phase transition. We demonstrate that the sensitivity of product crystallinity is caused by its multi-step, multi-type reaction pathway, which bypasses seven intermediate phases and involves all types of elementary solid phase transition steps, i.e. the shearing of O layers (martensitic type), the local diffusion of Ga atoms (reconstructive type) and the significant lattice dilation (dilation type). While the migration of Ga atoms across the close-packed O layers is the rate-determining step and yields "amorphous-like" high energy intermediates, the shearing of O layers contributes to the formation of coherent biphase junctions and the presence of a crystallographic orientation relation, (001)α//(201[combining macron])β + [120]α//[13[combining macron]2]β. Our experiment using high-resolution transmission electron microscopy further confirms the theoretical predictions on the atomic structure of biphase junction and the formation of (201[combining macron])β twin, and also discovers the late occurrence of lattice expansion in the nascent β phase that grows out from the parent α phase. By distinguishing pseudomartensitic transition from other types of mechanisms, we propose general rules to predict the product crystallinity of solid phase transition. The new knowledge on the kinetics of pseudomartensitic transition complements the theory of diffusionless solid phase transition.

Evaluation of Graphene/WO3 and Graphene/CeO x Structures as Electrodes for Supercapacitor Applications

NASA Astrophysics Data System (ADS)

Chaitoglou, Stefanos; Amade, Roger; Bertran, Enric

2017-12-01

The combination of graphene with transition metal oxides can result in very promising hybrid materials for use in energy storage applications thanks to its intriguing properties, i.e., highly tunable surface area, outstanding electrical conductivity, good chemical stability, and excellent mechanical behavior. In the present work, we evaluate the performance of graphene/metal oxide (WO3 and CeO x ) layered structures as potential electrodes in supercapacitor applications. Graphene layers were grown by chemical vapor deposition (CVD) on copper substrates. Single and layer-by-layer graphene stacks were fabricated combining graphene transfer techniques and metal oxides grown by magnetron sputtering. The electrochemical properties of the samples were analyzed and the results suggest an improvement in the performance of the device with the increase in the number of graphene layers. Furthermore, deposition of transition metal oxides within the stack of graphene layers further improves the areal capacitance of the device up to 4.55 mF/cm2, for the case of a three-layer stack. Such high values are interpreted as a result of the copper oxide grown between the copper substrate and the graphene layer. The electrodes present good stability for the first 850 cycles before degradation.

Rapid Near-inertial Internal Wave Group Propagation Through the Transition Layer from Float and Glider Observations in the Bay of Bengal

NASA Astrophysics Data System (ADS)

Johnston, S.; Rudnick, D. L.; Sherman, J. T.

2016-02-01

Two Spray gliders and 1 SOLO-II float were deployed in 2013 and 2014 as components of ONR's Air-Sea Interactions in the Northern Indian Ocean (ASIRI) experiment. Shallow (10-50 m) salinity-controlled mixed layers in the Bay of Bengal isolate the rest of the deeper isothermal layer and ocean interior from winds. The transition layer is a deeper stratification maximum (20-100 m), which separates the upper ocean from the interior. Downward near-inertial internal wave (NIW) groups are observed here in potential density fluctuations and can rapidly (a few inertial periods) transfer energy out of the mixed layer into the stratified interior. (Inertial periods are T = 2*pi/f = 2 - 3 days from 9 - 17°N, where f is the Coriolis frequency.) When isopycnals shoal at fronts, the transition layer is brought closer to the mixed layer allowing for faster downward group speed due to the higher stratification. With about 10 inertial wind events in the NCEP reanalysis over the observation period of about 21 weeks, we find 3 NIW groups with clear downward energy (upward phase) propagation into the interior. The groups reach 200 m within 2-3 T and have vertical wavelengths of about 200 m. This implies horizontal wavelengths of about 200 km if the waves have a frequency of 1.1f. This horizontal wavelength and propagation time scale appear consistent with surface wind forcing correlation scales from 3-day highpassed wind products and decay estimates from surface drifters and theory (Park et al., 2009). Our results extend this previous work by making subsurface observations and measuring further equatorward. The mesoscale appears to mediate: (a) the conversion from mixed layer inertial oscillations into propagating NIW and (b) NIW propagation into the interior.

High-Flow Asymmetric Reverse-Osmosis Membranes

NASA Technical Reports Server (NTRS)

Katz, M. C.; Wydeven, T. J.

1984-01-01

Water-soluble polymer membrane insolubilized by transition-metal salt. Thin layer of lower permeability material joined with thicker layer of highpermeability material. Two layers chemically identical or chemically distinct. They differ in density, compactness or other respects. Used to purify or desalinate seawater, brackish water, or industrial or domestic wastewater.

Fluorescence Visualization of Hypersonic Flow Past Triangular and Rectangular Boundary-layer Trips

NASA Technical Reports Server (NTRS)

Danehy, Paul M.; Garcia, A. P.; Borg, Stephen E.; Dyakonov, Artem A.; Berry, Scott A.; Inman, Jennifer A.; Alderfer, David W.

2007-01-01

Planar laser-induced fluorescence (PLIF) flow visualization has been used to investigate the hypersonic flow of air over surface protrusions that are sized to force laminar-to-turbulent boundary layer transition. These trips were selected to simulate protruding Space Shuttle Orbiter heat shield gap-filler material. Experiments were performed in the NASA Langley Research Center 31-Inch Mach 10 Air Wind Tunnel, which is an electrically-heated, blowdown facility. Two-mm high by 8-mm wide triangular and rectangular trips were attached to a flat plate and were oriented at an angle of 45 degrees with respect to the oncoming flow. Upstream of these trips, nitric oxide (NO) was seeded into the boundary layer. PLIF visualization of this NO allowed observation of both laminar and turbulent boundary layer flow downstream of the trips for varying flow conditions as the flat plate angle of attack was varied. By varying the angle of attack, the Mach number above the boundary layer was varied between 4.2 and 9.8, according to analytical oblique-shock calculations. Computational Fluid Dynamics (CFD) simulations of the flowfield with a laminar boundary layer were also performed to better understand the flow environment. The PLIF images of the tripped boundary layer flow were compared to a case with no trip for which the flow remained laminar over the entire angle-of-attack range studied. Qualitative agreement is found between the present observed transition measurements and a previous experimental roughness-induced transition database determined by other means, which is used by the shuttle return-to-flight program.

Effect of NO annealing on charge traps in oxide insulator and transition layer for 4H-SiC metal-oxide-semiconductor devices

NASA Astrophysics Data System (ADS)

Jia, Yifan; Lv, Hongliang; Niu, Yingxi; Li, Ling; Song, Qingwen; Tang, Xiaoyan; Li, Chengzhan; Zhao, Yanli; Xiao, Li; Wang, Liangyong; Tang, Guangming; Zhang, Yimen; Zhang, Yuming

2016-09-01

The effect of nitric oxide (NO) annealing on charge traps in the oxide insulator and transition layer in n-type 4H-SiC metal-oxide-semiconductor (MOS) devices has been investigated using the time-dependent bias stress (TDBS), capacitance-voltage (C-V), and secondary ion mass spectroscopy (SIMS). It is revealed that two main categories of charge traps, near interface oxide traps (Nniot) and oxide traps (Not), have different responses to the TDBS and C-V characteristics in NO-annealed and Ar-annealed samples. The Nniot are mainly responsible for the hysteresis occurring in the bidirectional C-V characteristics, which are very close to the semiconductor interface and can readily exchange charges with the inner semiconductor. However, Not is mainly responsible for the TDBS induced C-V shifts. Electrons tunneling into the Not are hardly released quickly when suffering TDBS, resulting in the problem of the threshold voltage stability. Compared with the Ar-annealed sample, Nniot can be significantly suppressed by the NO annealing, but there is little improvement of Not. SIMS results demonstrate that the Nniot are distributed within the transition layer, which correlated with the existence of the excess silicon. During the NO annealing process, the excess Si atoms incorporate into nitrogen in the transition layer, allowing better relaxation of the interface strain and effectively reducing the width of the transition layer and the density of Nniot. Project supported by the National Natural Science Foundation of China (Grant Nos. 61404098 and 61274079), the Doctoral Fund of Ministry of Education of China (Grant No. 20130203120017), the National Key Basic Research Program of China (Grant No. 2015CB759600), the National Grid Science & Technology Project, China (Grant No. SGRI-WD-71-14-018), and the Key Specific Project in the National Science & Technology Program, China (Grant Nos. 2013ZX02305002-002 and 2015CB759600).

Experimental analysis of the boundary layer transition with zero and positive pressure gradient

NASA Technical Reports Server (NTRS)

Arnal, D.; Jullen, J. C.; Michel, R.

1980-01-01

The influence of a positive pressure gradient on the boundary layer transition is studied. The mean velocity and turbulence profiles of four cases are examined. As the intensity of the pressure gradient is increased, the Reynolds number of the transition onset and the length of the transition region are reduced. The Tollmein-Schlichting waves disturb the laminar regime; the amplification of these waves is in good agreement with the stability theory. The three dimensional deformation of the waves leads finally to the appearance of turbulence. In the case of zero pressure gradient, the properties of the turbulent spots are studied by conditional sampling of the hot-wire signal; in the case of positive pressure gradient, the turbulence appears in a progressive manner and the turbulent spots are much more difficult to characterize.

Direct numerical simulation of transitional and turbulent flow over a heated flat plate using finite-difference schemes

NASA Technical Reports Server (NTRS)

Madavan, Nateri K.

1995-01-01

This report deals with the direct numerical simulation of transitional and turbulent flow at low Mach numbers using high-order-accurate finite-difference techniques. A computation of transition to turbulence of the spatially-evolving boundary layer on a heated flat plate in the presence of relatively high freestream turbulence was performed. The geometry and flow conditions were chosen to match earlier experiments. The development of the momentum and thermal boundary layers was documented. Velocity and temperature profiles, as well as distributions of skin friction, surface heat transfer rate, Reynolds shear stress, and turbulent heat flux, were shown to compare well with experiment. The results indicate that the essential features of the transition process have been captured. The numerical method used here can be applied to complex geometries in a straightforward manner.

Electronic band structure of 4d and 5d transition metal trichalcogenides

NASA Astrophysics Data System (ADS)

Sugita, Yusuke; Miyake, Takashi; Motome, Yukitoshi

2018-05-01

Transition metal trichalcogenides (TMTs), a family of van der Waals materials, have gained increasing interests from the discovery of magnetism in few-layer forms. Although TMTs with 3d transition metal elements have been studied extensively, much less is explored for the 4d and 5d cases, where the interesting interplay between electron correlations and the relativistic spin-orbit coupling is expected. Using ab initio calculations, we here investigate the electronic property of TMTs with 4d and 5d transition metal elements. We show that the band structures exhibit multiple node-like features near the Fermi level. These are the remnant of multiple Dirac cones that were recently discovered in the monolayer cases. Our results indicate that the peculiar two-dimensional multiple Dirac cones are concealed even in the layered bulk systems.

Investigation of magnetic transitions through ultrasonic measurements in double-layered CMR manganite La1.2Sr1.8Mn2O7

NASA Astrophysics Data System (ADS)

Reddy, Y. S.; Vishnuvardhan Reddy, C.

2014-03-01

A polycrystalline, double-layered, colossal magnetoresistive manganite La1.2Sr1.8Mn2O7 is synthesized by sol-gel process and its magnetic and ultrasonic properties were investigated in the temperature range 80-300 K. The sample has Curie temperature at 124 K, where the sample exhibits a transition from paramagnetic insulator to ferromagnetic metallic state. The longitudinal sound velocity measurements show a significant hardening of sound velocity below TC, which may be attributed to the coupling between ferromagnetic spins and longitudinal acoustic phonons. The magnetization and ultrasonic studies reveal the presence of secondary transition at ≈ 260 K in this sample. The present sound velocity measurement results confirm the reliability of ultrasonic investigations as an independent tool to probe magnetic transitions in manganites.

Controlling forebody asymmetries in flight: Experience with boundary layer transition strips

NASA Technical Reports Server (NTRS)

Fisher, David F.; Cobleigh, Brent R.

1994-01-01

The NASA Dryden Flight Research Center has an ongoing program to investigate aircraft flight characteristics at high angles of attack. As part of this investigation, longitudinal boundary layer transition strips were installed on the F-18 HARV forebody, a preproduction F/A-18 radome with a nose-slice tendency, and the X-31 aircraft forebody and noseboom to reduce asymmetric yawing moments at high angles of attack. The transition strips were effective on the F-18 HARV at angles of attack above 60 deg. On the preproduction F/A-18 radome at an angle of attack near 50 deg the strips were not effective. When the transition strips were installed on the X-31 noseboom, a favorable effect was observed on the yawing moment dynamics but the magnitude of the yawing moment was not decreased.

Thickness driven spin reorientation transition of epitaxial LaCrO3 films

NASA Astrophysics Data System (ADS)

Park, Junho; Kim, Dong-Hwan; Lee, Doopyo; Ko, Kyung-Tae; Hyun Song, Jong; Kim, Jae-Young; Koo, Tae-Yeong; Lee, Seung Ran; Park, Jae-Hoon

2018-03-01

We grew fully strained epitaxial LaCrO3 (LCO) films on SrTiO3(001) under layer-by-layer control up to the film thickness of t = 130 nm using a pulsed laser deposition method. The spin axis of the antiferromagnetic LCO film was systematically examined as a function of t by using Cr L2,3-edge x-ray magnetic linear dichroism (XMLD). The XMLD results manifest a spin reorientation transition (SRT) across a transition thickness of tT ˜ 60 nm. This SRT is well explained in terms of two competing magnetic anisotropy energies of the surface/interface (KS) and the LCO film itself (KV).

An Application of CFD to Guide Forced Boundary-Layer Transition for Low-Speed Tests of a Hybrid Wing-Body Configuration

NASA Technical Reports Server (NTRS)

Luckring, James M.; Deere, Karen A.; Childs, Robert E.; Stremel, Paul M.; Long, Kurtis R.

2016-01-01

A hybrid transition trip-dot sizing and placement test technique was developed in support of recent experimental research on a hybrid wing-body configuration under study for the NASA Environmentally Responsible Aviation project. The approach combines traditional methods with Computational Fluid Dynamics. The application had three-dimensional boundary layers that were simulated with either fully turbulent or transitional flow models using established Reynolds-Averaged Navier-Stokes methods. Trip strip effectiveness was verified experimentally using infrared thermography during a low-speed wind tunnel test. Although the work was performed on one specific configuration, the process was based on fundamental flow physics and could be applicable to other configurations.

Transition Control with Dielectric Barrier Discharge Plasmas

DTIC Science & Technology

2010-10-01

AFRL-AFOSR-UK-TR-2011-0007 Transition Control with Dielectric Barrier Discharge Plasmas Cameron Tropea Technische...Discharge Plasmas 5a. CONTRACT NUMBER FA8655-08-1-3032 5b. GRANT NUMBER Grant 08-3032 5c. PROGRAM ELEMENT NUMBER 61102F 6. AUTHOR(S...is to control natural boundary-layer transition through the use of plasma actuators. Transition delay or even suppression has its merits not only in

Transition from single to multiple double layers. [of plasma

NASA Technical Reports Server (NTRS)

Chan, C.; Hershkowitz, N.

1982-01-01

Laboratory results are presented to define parameters which allow the boundary conditions to control the characteristics of double layers of plasma. It is shown that multiple double layers arise when the ratio of Debye length to system length decreases, a result which is in line with boundary layer theory. The significance of inclusion of the system length is noted to render BGK treatments of double layers, wherein the length is neglected, invalid.

Transitional and turbulent boundary layer with heat transfer

NASA Astrophysics Data System (ADS)

Wu, Xiaohua; Moin, Parviz

2010-08-01

We report on our direct numerical simulation of an incompressible, nominally zero-pressure-gradient flat-plate boundary layer from momentum thickness Reynolds number 80-1950. Heat transfer between the constant-temperature solid surface and the free-stream is also simulated with molecular Prandtl number Pr=1. Skin-friction coefficient and other boundary layer parameters follow the Blasius solutions prior to the onset of turbulent spots. Throughout the entire flat-plate, the ratio of Stanton number and skin-friction St/Cf deviates from the exact Reynolds analogy value of 0.5 by less than 1.5%. Mean velocity and Reynolds stresses agree with experimental data over an extended turbulent region downstream of transition. Normalized rms wall-pressure fluctuation increases gradually with the streamwise growth of the turbulent boundary layer. Wall shear stress fluctuation, τw,rms'+, on the other hand, remains constant at approximately 0.44 over the range, 800

On the design of airfoils in which the transition of the boundary layer is delayed

NASA Technical Reports Server (NTRS)

Tani, Itiro

1952-01-01

A method is presented for designing suitable thickness distributions and mean camber lines for airfoils permitting extensive chordwise laminar flow. Wind tunnel and flight tests confirming the existence of laminar flow; possible maintenance of laminar flow by area suction; and the effects of wind tunnel turbulence and surface roughness on the promotion of premature boundary layer transition are discussed. In addition, estimates of profile drag and scale effect on maximum lift of the derived airfoils are made.

Numerical Simulation of Transition in Hypersonic Boundary Layers

DTIC Science & Technology

2011-02-01

sile domes. AGARD Report CP 493. Advisory Group for Aerospace Research and Development. 273 Horvath, T. 2002 Boundary layer transition on slender...reference skin-friction coefficient cp , cv Specific heats at constant pressure and volume, respectively cph Phase speed in propagation direction e...y)) 73 and two-dimensional (W = 0): u = U (y) + u′ , (4.9a) v = v′ , (4.9b) w = w′ , (4.9c) p = 1 + p′ , (4.9d) T = T (y) + T ′ , (4.9e) ρ = 1 T (y

Anomalous Insulator-Metal Transition in Boron Nitride-Graphene Hybrid Atomic Layers

DTIC Science & Technology

2012-08-13

REPORT Anomalous insulator-metal transition in boron nitride-graphene hybrid atomic layers 14 . ABSTRACT 16. SECURITY CLASSIFICATION OF: The study of...from the DFT calculation. The calculated transmission through a N terminated zigzag edged h-BN nanodomain embedded in graphene is shown in Fig. 14 , with...Energy ε − ε F (eV) 0 0.5 1 1.5 2 Tr an sm is si on FIG. 14 . (Color online) Transmission through a N terminated zigzag edged h-BN nanodomain embedded in

Room temperature broadband terahertz gains in graphene heterostructures based on inter-layer radiative transitions

DOE Office of Scientific and Technical Information (OSTI.GOV)

Tang, Linlong; Chongqing institute of green and intelligent technology, Chinese Academy of Sciences, Chongqing, 401122; Du, Jinglei, E-mail: dujl@scu.edu.cn

We exploit inter-layer radiative transitions to provide gains to amplify terahertz waves in graphene heterostructures. This is achieved by properly doping graphene sheets and aligning their energy bands so that the processes of stimulated emissions can overwhelm absorptions. We derive an expression for the gain estimation and show the gain is insensitive to temperature variation. Moreover, the gain is broadband and can be strong enough to compensate the free carrier loss, indicating graphene based room temperature terahertz lasers are feasible.

Transient Boundary Layer Disturbance Growth and Bypass Transition Due to Realistic Roughness and Continued Study of Transition Over Riblets

DTIC Science & Technology

2011-03-19

producing negative streamwise vorticity). It is not clear, however, why these ωx pancakes take on this alternating layer form. Figuring out how new...streamwise vorticity. The stream ribbons are colored by the vorticity component along the direction of the ribbon. The upshot of such an image is...different colors . The right image of figure 21 is created from analyzing several photographs of each single collar vortex. Due to limitations in the dye

Observation of a pretransitional effect near a virtual smectic-A--smectic-C* transition.

PubMed

Shibahara, S; Takanishi, Y; Yamamoto, J; Ogasawara, T; Ishikawa, K; Yokoyama, H; Takezoe, H

2001-06-01

Unusual softening of the layer compression modulus B has been observed near the phase boundary where the smectic-C* phase vanishes in a naphtalene-based liquid crystal mixture. From the systematic study of x-ray and layer compression measurements, this unusual effect is attributed to the pretransitional softening near a virtual smectic-A-smectic-C* phase transition in the smectic-A phase, which no longer appears on the thermoequilibrium phase diagram. This phenomenon is similar but not equivalent to supercritical behavior.

Large D-2 theory of superconducting fluctuations in a magnetic field and its application to iron pnictides.

PubMed

Murray, James M; Tesanović, Zlatko

2010-07-16

A Ginzburg-Landau approach to fluctuations of a layered superconductor in a magnetic field is used to show that the interlayer coupling can be incorporated within an interacting self-consistent theory of a single layer, in the limit of a large number of neighboring layers. The theory exhibits two phase transitions-a vortex liquid-to-solid transition is followed by a Bose-Einstein condensation into the Abrikosov lattice-illustrating the essential role of interlayer coupling. By using this theory, explicit expressions for magnetization, specific heat, and fluctuation conductivity are derived. We compare our results with recent experimental data on the iron-pnictide superconductors.

Boundary layer stability on a yawed spinning body of revolution and its effect on the magnus force and moment

NASA Technical Reports Server (NTRS)

Jacobson, I. D.; Morton, J. B.

1972-01-01

The parameters are established which are important to the stability of a boundary layer flow over a yawed spinning cylinder in a uniform stream. It is shown that transition occurs asymmetrically in general and this asymmetry can be important for the prediction of aerodynamic forces and moments (e.g., the Magnus effect). Instability of the steady-state boundary layer flow is determined using small disturbance theory. Although the approach is strictly valid only for the calculation of the conditions for stability in the small, experimental data indicate that in many problems, it provides a good estimate for the transition to turbulence.

Numerical investigations of shock wave interaction with laminar boundary layer on compressor profile

NASA Astrophysics Data System (ADS)

Piotrowicz, M.; Flaszyński, P.

2016-10-01

The investigation of shockwave boundary layer interaction on suction side of transonic compressor blade is one of main objectives of TFAST project (Transition Location Effect on Shock Wave Boundary Layer Interaction). In order to look more closely into the flow structure on suction side of a profile, a design of generic test section in linear transonic wind tunnel was proposed. The experimental and numerical results of flow structure on a suction side of the compressor profile investigations are presented. The numerical simulations are carried out for EARSM (Explicit Algebraic Reynolds Stress Model) turbulence model with transition model. The result are compared with oil flow visualisation, schlieren pictures, Pressure Sensitive Paint (PSP) and static pressure.

DOE Office of Scientific and Technical Information (OSTI.GOV)

Mattox, Tracy M.; Koo, Bonil; Garcia, Guillermo

An electrochromic device includes a nanostructured transition metal oxide bronze layer that includes one or more transition metal oxide and one or more dopant, a solid state electrolyte, and a counter electrode. The nanostructured transition metal oxide bronze selectively modulates transmittance of near-infrared (NIR) spectrum and visible spectrum radiation as a function of an applied voltage to the device.

Technologies for deposition of transition metal oxide thin films: application as functional layers in “Smart windows” and photocatalytic systems

NASA Astrophysics Data System (ADS)

Gesheva, K.; Ivanova, T.; Bodurov, G.; Szilágyi, I. M.; Justh, N.; Kéri, O.; Boyadjiev, S.; Nagy, D.; Aleksandrova, M.

2016-02-01

“Smart windows” are envisaged for future low-energy, high-efficient architectural buildings, as well as for the car industry. By switching from coloured to fully bleached state, these windows regulate the energy of solar flux entering the interior. Functional layers in these devices are the transition metals oxides. The materials (transitional metal oxides) used in smart windows can be also applied as photoelectrodes in water splitting photocells for hydrogen production or as photocatalytic materials for self-cleaning surfaces, waste water treatment and pollution removal. Solar energy utilization is recently in the main scope of numerous world research laboratories and energy organizations, working on protection against conventional fuel exhaustion. The paper presents results from research on transition metal oxide thin films, fabricated by different methods - atomic layer deposition, atmospheric pressure chemical vapour deposition, physical vapour deposition, and wet chemical methods, suitable for flowthrough production process. The lower price of the chemical deposition processes is especially important when the method is related to large-scale glazing applications. Conclusions are derived about which processes are recently considered as most prospective, related to electrochromic materials and devices manufacturing.

Multigrid methods for flow transition in three-dimensional boundary layers with surface roughness

NASA Technical Reports Server (NTRS)

Liu, Chaoqun; Liu, Zhining; Mccormick, Steve

1993-01-01

The efficient multilevel adaptive method has been successfully applied to perform direct numerical simulations (DNS) of flow transition in 3-D channels and 3-D boundary layers with 2-D and 3-D isolated and distributed roughness in a curvilinear coordinate system. A fourth-order finite difference technique on stretched and staggered grids, a fully-implicit time marching scheme, a semi-coarsening multigrid method associated with line distributive relaxation scheme, and an improved outflow boundary-condition treatment, which needs only a very short buffer domain to damp all order-one wave reflections, are developed. These approaches make the multigrid DNS code very accurate and efficient. This allows us not only to be able to do spatial DNS for the 3-D channel and flat plate at low computational costs, but also to do spatial DNS for transition in the 3-D boundary layer with 3-D single and multiple roughness elements, which would have extremely high computational costs with conventional methods. Numerical results show good agreement with the linear stability theory, the secondary instability theory, and a number of laboratory experiments. The contribution of isolated and distributed roughness to transition is analyzed.

Detecting the chaotic nature in a transitional boundary layer using symbolic information-theory quantifiers.

PubMed

Zhang, Wen; Liu, Peiqing; Guo, Hao; Wang, Jinjun

2017-11-01

The permutation entropy and the statistical complexity are employed to study the boundary-layer transition induced by the surface roughness. The velocity signals measured in the transition process are analyzed with these symbolic quantifiers, as well as the complexity-entropy causality plane, and the chaotic nature of the instability fluctuations is identified. The frequency of the dominant fluctuations has been found according to the time scales corresponding to the extreme values of the symbolic quantifiers. The laminar-turbulent transition process is accompanied by the evolution in the degree of organization of the complex eddy motions, which is also characterized with the growing smaller and flatter circles in the complexity-entropy causality plane. With the help of the permutation entropy and the statistical complexity, the differences between the chaotic fluctuations detected in the experiments and the classical Tollmien-Schlichting wave are shown and discussed. It is also found that the chaotic features of the instability fluctuations can be approximated with a number of regular sine waves superimposed on the fluctuations of the undisturbed laminar boundary layer. This result is related to the physical mechanism in the generation of the instability fluctuations, which is the noise-induced chaos.

Detecting the chaotic nature in a transitional boundary layer using symbolic information-theory quantifiers

NASA Astrophysics Data System (ADS)

Zhang, Wen; Liu, Peiqing; Guo, Hao; Wang, Jinjun

2017-11-01

The permutation entropy and the statistical complexity are employed to study the boundary-layer transition induced by the surface roughness. The velocity signals measured in the transition process are analyzed with these symbolic quantifiers, as well as the complexity-entropy causality plane, and the chaotic nature of the instability fluctuations is identified. The frequency of the dominant fluctuations has been found according to the time scales corresponding to the extreme values of the symbolic quantifiers. The laminar-turbulent transition process is accompanied by the evolution in the degree of organization of the complex eddy motions, which is also characterized with the growing smaller and flatter circles in the complexity-entropy causality plane. With the help of the permutation entropy and the statistical complexity, the differences between the chaotic fluctuations detected in the experiments and the classical Tollmien-Schlichting wave are shown and discussed. It is also found that the chaotic features of the instability fluctuations can be approximated with a number of regular sine waves superimposed on the fluctuations of the undisturbed laminar boundary layer. This result is related to the physical mechanism in the generation of the instability fluctuations, which is the noise-induced chaos.

FIRE aircraft observations of horizontal and vertical transport in marine stratocumulus

NASA Technical Reports Server (NTRS)

Paluch, Ilga R.; Lenschow, Donald H.

1990-01-01

A major goal of research on marine stratocumulus is to try to understand the processes that generate and dissipate them. One approach to studying this problem is to investigate the boundary layer structure in the vicinity of a transition from a cloudy to a cloud-free region to document the differences in structure on each side of the transition. Since stratiform clouds have a major impact on the radiation divergence in the boundary layer, the transition from a cloudy to a clear boundary layer is a region of large horizontal inhomogeneity in air temperature and turbulence intensity. This leads to a considerable difference in horizontal and vertical transports between the cloudy and cloud-free regions. Measurements are used from the NCAR Electra aircraft during flights 5 (7 July 1987) and 10 (18 July 1987) of FIRE for this purpose. Flight 5 coincided with a LANDSAT overflight, and was designed to investigate the transition across a well-defined N-S cloud boundary, since the LANDSAT image can document the cloud cover in considerable detail. Turbulence legs were flown about 60 km on both sides of the cloud boundary. Flight 10 was flown at night in an area of scattered small cumuli and broken cloud patches.

Perturbation Effects on a Supercritical C7H16/N2 Mixing Layer

NASA Technical Reports Server (NTRS)

Okongo'o, Nora; Bellan, Josette

2008-01-01

A computational-simulation study has been presented of effects of perturbation wavelengths and initial Reynolds numbers on the transition to turbulence of a heptane/nitrogen mixing layer at supercritical pressure. The governing equations for the simulations were the same as those of related prior studies reported in NASA Tech Briefs. Two-dimensional (2D) simulations were performed with initially im posed span wise perturbations whereas three-dimensional (3D) simulations had both streamwise and spanwise initial perturbations. The 2D simulations were undertaken to ascertain whether perturbations having the shortest unstable wavelength obtained from a linear stability analysis for inviscid flow are unstable in viscous nonlinear flows. The goal of the 3D simulations was to ascertain whether perturbing the mixing layer at different wavelengths affects the transition to turbulence. It was found that transitions to turbulence can be obtained at different perturbation wavelengths, provided that they are longer than the shortest unstable wavelength as determined by 2D linear stability analysis for the inviscid case and that the initial Reynolds number is proportionally increased as the wavelength is decreased. The transitional states thus obtained display different dynamic and mixture characteristics, departing strongly from the behaviors of perfect gases and ideal mixtures.

Optimal Disturbances in Boundary Layers Subject to Streamwise Pressure Gradient

NASA Technical Reports Server (NTRS)

Tumin, Anatoli; Ashpis, David E.

2003-01-01

Laminar-turbulent transition in shear flows is still an enigma in the area of fluid mechanics. The conventional explanation of the phenomenon is based on the instability of the shear flow with respect to infinitesimal disturbances. The conventional hydrodynamic stability theory deals with the analysis of normal modes that might be unstable. The latter circumstance is accompanied by an exponential growth of the disturbances that might lead to laminar-turbulent transition. Nevertheless, in many cases, the transition scenario bypasses the exponential growth stage associated with the normal modes. This type of transition is called bypass transition. An understanding of the phenomenon has eluded us to this day. One possibility is that bypass transition is associated with so-called algebraic (non-modal) growth of disturbances in shear flows. In the present work, an analysis of the optimal disturbances/streamwise vortices associated with the transient growth mechanism is performed for boundary layers in the presence of a streamwise pressure gradient. The theory will provide the optimal spacing of the control elements in the spanwise direction and their placement in the streamwise direction.

Two-Equation Low-Reynolds-Number Turbulence Modeling of Transitional Boundary Layer Flows Characteristic of Gas Turbine Blades. Ph.D. Thesis. Final Contractor Report

NASA Technical Reports Server (NTRS)

Schmidt, Rodney C.; Patankar, Suhas V.

1988-01-01

The use of low Reynolds number (LRN) forms of the k-epsilon turbulence model in predicting transitional boundary layer flow characteristic of gas turbine blades is developed. The research presented consists of: (1) an evaluation of two existing models; (2) the development of a modification to current LRN models; and (3) the extensive testing of the proposed model against experimental data. The prediction characteristics and capabilities of the Jones-Launder (1972) and Lam-Bremhorst (1981) LRN k-epsilon models are evaluated with respect to the prediction of transition on flat plates. Next, the mechanism by which the models simulate transition is considered and the need for additional constraints is discussed. Finally, the transition predictions of a new model are compared with a wide range of different experiments, including transitional flows with free-stream turbulence under conditions of flat plate constant velocity, flat plate constant acceleration, flat plate but strongly variable acceleration, and flow around turbine blade test cascades. In general, calculational procedure yields good agreement with most of the experiments.

Tunable inversion symmetry in heterostructures of layered oxides

NASA Astrophysics Data System (ADS)

Rondinelli, James

Traditional approaches to create and control functional electronic materials have focused on new phases in previously unknown bulk minerals. More recently, interlayer physics has spawned interest in known materials in unexplored atomic scale geometries, especially in complex transition metal oxides (TMO), where heterostructures can be created on demand. In this talk, I show that although epitaxial strain routinely induces (enhances) electric polarizations, biaxial strain can also induce an unanticipated polar-to-nonpolar (P-NP) structural transition in (001) thin films of naturally layered An + 1Bn O3n+1 (n = 1 - ∞) oxides. Density functional theory calculations and a complete phenomenological model for Ca3Ti2O7 are used to show that the origin of the P-NP transition originates from the interplay of trilinear-related lattice mode interactions active in the layered oxides, and those interactions are directly strain tunable. Moreover these layered oxides exhibit a quasi-two dimensional phonon mode-an acoustic branch with quadratic dispersion, enabling unusual membrane effects such as tunable negative thermal expansion. I conclude by emphasizing that broken inversion symmetric structures offer a plentiful playground for realizing new functionalities in thin films, including new multiferroics from polar metals.

Towards Understanding the Mechanism of Receptivity and Bypass Dynamics in Laminar Boundary Layers

NASA Technical Reports Server (NTRS)

Lasseigne, D. G.; Criminale, W. O.; Joslin, R. D.; Jackson, T. L.

1999-01-01

Three problems concerning laminar-turbulent transition are addressed by solving a series of initial value problems. The first problem is the calculation of resonance within the continuous spectrum of the Blasius boundary layer. The second is calculation of the growth of Tollmien-Schlichting waves that are a direct result of disturbances that only lie outside of the boundary layer. And, the third problem is the calculation of non-parallel effects. Together, these problems represent a unified approach to the study of freestream disturbance effects that could lead to transition. Solutions to the temporal, initial-value problem with an inhomogeneous forcing term imposed upon the flow is sought. By solving a series of problems, it is shown that: A transient disturbance lying completely outside of the boundary layer can lead to the growth of an unstable Tollmien-Schlichting wave. A resonance with the continuous spectrum leads to strong amplification that may provide a mechanism for bypass transition once nonlinear effects are considered. A disturbance with a very weak unstable Tollmien-Schlichting wave can lead to a much stronger Tollmien-Schlichting wave downstream, if the original disturbance has a significant portion of its energy in the continuum modes.

Large-scale delamination of multi-layers transition metal carbides and carbonitrides “MXenes”

DOE PAGES

Naguib, Michael; Unocic, Raymond R.; Armstrong, Beth L.; ...

2015-04-17

Herein we report on a general approach to delaminate multi-layered MXenes using an organic base to induce swelling that in turn weakens the bonds between the MX layers. Simple agitation or mild sonication of the swollen MXene in water resulted in the large-scale delamination of the MXene layers. The delamination method is demonstrated for vanadium carbide, and titanium carbonitrides MXenes.

Chemical control of orbital polarization in artificially structured transition-metal oxides: La2NiXO6 (X=B,Al,Ga,In) from first principles

NASA Astrophysics Data System (ADS)

Han, M. J.; Marianetti, C. A.; Millis, A. J.

2010-10-01

The application of modern layer-by-layer growth techniques to transition-metal oxide materials raises the possibility of creating new classes of materials with rationally designed correlated electron properties. An important step toward this goal is the demonstration that electronic structure can be controlled by atomic composition. In compounds with partially occupied transition-metal d shells, one important aspect of the electronic structure is the relative occupancy of different d orbitals. Previous work has established that strain and quantum confinement can be used to influence orbital occupancy. In this paper we demonstrate a different modality for orbital control in transition-metal oxide heterostructures, using density-functional band calculations supplemented by a tight-binding analysis to show that the choice of nontransition-metal counterion X in transition-metal oxide heterostructures composed of alternating LaNiO3 and LaXO3 units strongly affects orbital occupancy, changing the magnitude and in some cases the sign of the orbital polarization.

Some Insights on Roughness Induced Transition and Control from DNS and Experiments

NASA Astrophysics Data System (ADS)

Suryanarayanan, Saikishan; Ibitayo, Ifeoluwa; Goldstein, David; Brown, Garry

2016-11-01

We study the receptivity and subsequent evolution of an initially laminar flat boundary layer on a flat plate to single and multiple discrete roughness elements (DRE) using a combination of immersed boundary DNS and water channel flow visualization experiments. We examine the transition caused by a single DRE and demonstrate the possibility of suppressing it by an appropriately designed second DRE in both DNS and experiments. The different phases of transition are identified and the roles of Reynolds numbers based on roughness height and boundary layer thickness are investigated. The underlying mechanisms in the observed transition and its control are understood by examining detailed vorticity flux balances. Connections are also made to recent developments in transient growth and streak instability. A unified picture is sought from a parametric study of different DRE dimensions and orientations. The potential applicability of the observations and understanding derived from this study to controlling transition caused by design and environmental roughness over aircraft wings is discussed. Supported by AFOSR # FA9550-15-1-0345.

Direct Numerical Simulation of Transition Due to Traveling Crossflow Vortices

NASA Technical Reports Server (NTRS)

Li, Fei; Choudhari, Meelan M.; Duan, Lian

2016-01-01

Previous simulations of laminar breakdown mechanisms associated with stationary crossflow instability over a realistic swept-wing configuration are extended to investigate the alternate scenario of transition due to secondary instability of traveling crossflow modes. Earlier analyses based on secondary instability theory and parabolized stability equations have shown that this alternate scenario is viable when the initial amplitude of the most amplified mode of the traveling crossflow instability is greater than approximately 0.03 times the initial amplitude of the most amplified stationary mode. The linear growth predictions based on the secondary instability theory and parabolized stability equations agree well with the direct numerical simulation. Nonlinear effects are initially stabilizing but subsequently lead to a rapid growth followed by the onset of transition when the amplitude of the secondary disturbance exceeds a threshold value. Similar to the breakdown of stationary vortices, the transition zone is rather short and the boundary layer becomes completely turbulent across a distance of less than 15 times the boundary layer thickness at the completion of transition.

Control of the metal-insulator transition in vanadium dioxide by modifying orbital occupancy

NASA Astrophysics Data System (ADS)

Aetukuri, Nagaphani B.; Gray, Alexander X.; Drouard, Marc; Cossale, Matteo; Gao, Li; Reid, Alexander H.; Kukreja, Roopali; Ohldag, Hendrik; Jenkins, Catherine A.; Arenholz, Elke; Roche, Kevin P.; Dürr, Hermann A.; Samant, Mahesh G.; Parkin, Stuart S. P.

2013-10-01

External control of the conductivity of correlated oxides is one of the most promising schemes for realizing energy-efficient electronic devices. Vanadium dioxide (VO2), an archetypal correlated oxide compound, undergoes a temperature-driven metal-insulator transition near room temperature with a concomitant change in crystal symmetry. Here, we show that the metal-insulator transition temperature of thin VO2(001) films can be changed continuously from ~285 to ~345K by varying the thickness of the RuO2 buffer layer (resulting in different epitaxial strains). Using strain-, polarization- and temperature-dependent X-ray absorption spectroscopy, in combination with X-ray diffraction and electronic transport measurements, we demonstrate that the transition temperature and the structural distortion across the transition depend on the orbital occupancy in the metallic state. Our findings open up the possibility of controlling the conductivity in atomically thin VO2 layers by manipulating the orbital occupancy by, for example, heterostructural engineering.

Oscillatory mode transition for supersonic open cavity flows

NASA Astrophysics Data System (ADS)

Kumar, Mayank; Vaidyanathan, Aravind

2018-02-01

The transition in the primary oscillatory mode in an open cavity has been experimentally investigated and the associated characteristics in a Mach 1.71 flow has been analyzed. The length-to-depth (L/D) ratios of the rectangular cavities are varied from 1.67 to 3.33. Unsteady pressure measurement and flow visualization are employed to understand the transitional flow physics. Flow visualization revealed the change in oscillation pattern from longitudinal mode to transverse mode and is also characterized by the presence of two bow shocks at the trailing edge instead of one. The transition is found to occur between L/D 1.67 and 2, marked by a change in the feedback mechanism, resulting in a shift from the vortex circulation driven transverse feedback mode to the oscillating shear layer driven longitudinal feedback mode. Cavities oscillating in the transition mode exhibit multiple tones of comparable strength. Correlation analysis indicated the shift in the feedback mechanism. Wavelet analysis revealed the temporal behaviour of tones during transition. Tone switching is observed in deeper cavities and is attributed to the occurrence of two bow shocks as evident from the temporo-spectral characteristics of transition that affects the shear layer modal shape.

Closure models for transitional blunt-body flows

NASA Astrophysics Data System (ADS)

Nance, Robert Paul

1998-12-01

A mean-flow modeling approach is proposed for the prediction of high-speed blunt-body wake flows undergoing transition to turbulence. This method couples the k- /zeta (Enstrophy) compressible turbulence model with a procedure for characterizing non-turbulent fluctuations upstream of transition. Two different instability mechanisms are examined in this study. In the first model, transition is brought about by streamwise disturbance modes, whereas the second mechanism considers instabilities in the free shear layer associated with the wake flow. An important feature of this combined approach is the ability to specify or predict the location of transition onset. Solutions obtained using the new approach are presented for a variety of perfect-gas hypersonic flows over blunt- cone configurations. These results are shown to provide better agreement with experimental heating data than earlier laminar predictions by other researchers. In addition, it is demonstrated that the free-shear-layer instability mechanism is superior to the streamwise mechanism in terms of comparisons with heating measurements. The favorable comparisons are a strong indication that transition to turbulence is indeed present in the flowfields considered. They also show that the present method is a useful predictive tool for transitional blunt-body wake flows.

Boundary Layer Control for Hypersonic Airbreathing Vehicles

NASA Technical Reports Server (NTRS)

Berry, Scott A.; Nowak, Robert J.; Horvath, Thomas J.

2004-01-01

Active and passive methods for tripping hypersonic boundary layers have been examined in NASA Langley Research Center wind tunnels using a Hyper-X model. This investigation assessed several concepts for forcing transition, including passive discrete roughness elements and active mass addition (or blowing), in the 20-Inch Mach 6 Air and the 31-Inch Mach 10 Air Tunnels. Heat transfer distributions obtained via phosphor thermography, shock system details, and surface streamline patterns were measured on a 0.333-scale model of the Hyper-X forebody. The comparisons between the active and passive methods for boundary layer control were conducted at test conditions that nearly match the Hyper-X nominal Mach 7 flight test-point of an angle-of-attack of 2-deg and length Reynolds number of 5.6 million. For passive roughness, the primary parametric variation was a range of trip heights within the calculated boundary layer thickness for several trip concepts. The passive roughness study resulted in a swept ramp configuration, scaled to be roughly 0.6 of the calculated boundary layer thickness, being selected for the Mach 7 flight vehicle. For the active blowing study, the manifold pressure was systematically varied (while monitoring the mass flow) for each configuration to determine the jet penetration height, with schlieren, and transition movement, with the phosphor system, for comparison to the passive results. All the blowing concepts tested, which included various rows of sonic orifices (holes), two- and three-dimensional slots, and random porosity, provided transition onset near the trip location with manifold stagnation pressures on the order of 40 times the model surface static pressure, which is adequate to ensure sonic jets. The present results indicate that the jet penetration height for blowing was roughly half the height required with passive roughness elements for an equivalent amount of transition movement.

Towards Natural Transition in Compressible Boundary Layers

DTIC Science & Technology

2016-06-29

Behaviour of a natural laminar flow aerofoil in flight through atmospheric turbulence. Journal of Fluid Mechanics, 767:394–429, 003 2015. [70] O...DISTRIBUTION STATEMENT A. Approved for public release; distribution is unlimited See report Wave packet, compressible boundary layer, subsonic flow ...Base flow generation . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 26 3.1.1 Boundary layer profiles

Mapping of Low-Frequency Raman Modes in CVD-Grown Transition Metal Dichalcogenides: Layer Number, Stacking Orientation and Resonant Effects

PubMed Central

O’Brien, Maria; McEvoy, Niall; Hanlon, Damien; Hallam, Toby; Coleman, Jonathan N.; Duesberg, Georg S.

2016-01-01

Layered inorganic materials, such as the transition metal dichalcogenides (TMDs), have attracted much attention due to their exceptional electronic and optical properties. Reliable synthesis and characterization of these materials must be developed if these properties are to be exploited. Herein, we present low-frequency Raman analysis of MoS2, MoSe2, WSe2 and WS2 grown by chemical vapour deposition (CVD). Raman spectra are acquired over large areas allowing changes in the position and intensity of the shear and layer-breathing modes to be visualized in maps. This allows detailed characterization of mono- and few-layered TMDs which is complementary to well-established (high-frequency) Raman and photoluminescence spectroscopy. This study presents a major stepping stone in fundamental understanding of layered materials as mapping the low-frequency modes allows the quality, symmetry, stacking configuration and layer number of 2D materials to be probed over large areas. In addition, we report on anomalous resonance effects in the low-frequency region of the WS2 Raman spectrum. PMID:26766208

Emergence of charge density waves and a pseudogap in single-layer TiTe 2

DOE PAGES

Chen, P.; Pai, Woei Wu; Chan, Y. -H.; ...

2017-09-11

Two-dimensional materials constitute a promising platform for developing nanoscale devices and systems. Their physical properties can be very different from those of the corresponding three-dimensional materials because of extreme quantum confinement and dimensional reduction. Here in this paper we report a study of TiTe 2 from the single-layer to the bulk limit. Using angle-resolved photoemission spectroscopy and scanning tunneling microscopy and spectroscopy, we observed the emergence of a (2 × 2) charge density wave order in single-layer TiTe 2 with a transition temperature of 92 ± 3 K. Also observed was a pseudogap of about 28 meV at the Fermimore » level at 4.2 K. Surprisingly, no charge density wave transitions were observed in two-layer and multi-layer TiTe 2 , despite the quasi-two-dimensional nature of the material in the bulk. The unique charge density wave phenomenon in the single layer raises intriguing questions that challenge the prevailing thinking about the mechanisms of charge density wave formation.« less

Laser transit anemometer and Pitot probe comparative measurements in a sharp cone boundary layer at Mach 4

NASA Technical Reports Server (NTRS)

Hunter, W. W., Jr.; Ocheltree, S. L.; Russ, C. E., Jr.

1991-01-01

Laser transit anemometer (LTA) measurements of a 7 degree sharp cone boundary layer were conducted in the Air Force/AEDC Supersonic Tunnel A Mach 4 flow field. These measurements are compared with Pitot probe measurements and tricone theory provided by AEDC staff. Measurements were made both in laminar and turbulent boundary layers of the model. Comparison of LTA measurements with theory showed agreement to better than 1 percent for the laminar boundary layer cases. This level of agreement was obtained after small position corrections, 0.01 to 0.6 mm, were applied to the experimental data sets. Pitot probe data when compared with theory also showed small positioning errors. The Pitot data value was also limited due to probe interference with the flow near the model. The LTA turbulent boundary layer data indicated a power law dependence of 6.3 to 6.9. The LTA data was analyzed in the time (Tau) domain in which it was obtained and in the velocity domain. No significant differences were noted between Tau and velocity domain results except in one turbulent boundary layer case.

Helicity in supercritical temporal mixing layers

NASA Technical Reports Server (NTRS)

Bellan, J.; Okong'o, N.

2003-01-01

Databases of transitional states obtained from Direct Numerical Simulations (DNS) of temporal, supercritical mixing layers for two species systems, 02/H2 and C7Hle/N2, are analyzed to elucidate species-specific turbulence aspects.

Cellular automaton for migration in ecosystem: Application of traffic model to a predator-prey system

NASA Astrophysics Data System (ADS)

Nagatani, Takashi; Tainaka, Kei-ichi

2018-01-01

In most cases, physicists have studied the migration of biospecies by the use of random walk. In the present article, we apply cellular automaton of traffic model. For simplicity, we deal with an ecosystem contains a prey and predator, and use one-dimensional lattice with two layers. Preys stay on the first layer, but predators uni-directionally move on the second layer. The spatial and temporal evolution is numerically explored. It is shown that the migration has the important effect on populations of both prey and predator. Without migration, the phase transition between a prey-phase and coexisting-phase occurs. In contrast, the phase transition disappears by migration. This is because predator can survive due to migration. We find another phase transition for spatial distribution: in one phase, prey and predator form a stripe pattern of condensation and rarefaction, while in the other phase, they uniformly distribute. The self-organized stripe may be similar to the migration patterns in real ecosystems.

Phase transitions and critical properties in the antiferromagnetic Ising model on a layered triangular lattice with allowance for intralayer next-nearest-neighbor interactions

DOE Office of Scientific and Technical Information (OSTI.GOV)

Badiev, M. K., E-mail: m-zagir@mail.ru; Murtazaev, A. K.; Ramazanov, M. K.

2016-10-15

The phase transitions (PTs) and critical properties of the antiferromagnetic Ising model on a layered (stacked) triangular lattice have been studied by the Monte Carlo method using a replica algorithm with allowance for the next-nearest-neighbor interactions. The character of PTs is analyzed using the histogram technique and the method of Binder cumulants. It is established that the transition from the disordered to paramagnetic phase in the adopted model is a second-order PT. Static critical exponents of the heat capacity (α), susceptibility (γ), order parameter (β), and correlation radius (ν) and the Fischer exponent η are calculated using the finite-size scalingmore » theory. It is shown that (i) the antiferromagnetic Ising model on a layered triangular lattice belongs to the XY universality class of critical behavior and (ii) allowance for the intralayer interactions of next-nearest neighbors in the adopted model leads to a change in the universality class of critical behavior.« less

Dimensional Effects on the Charge Density Waves in Ultrathin Films of TiSe 2

DOE PAGES

Chen, P.; Chan, Y. -H.; Wong, M. -H.; ...

2016-09-20

Charge density wave (CDW) formation in solids is a critical phenomenon involving the collective reorganization of the electrons and atoms in the system into a wave structure, and it is expected to be sensitive to the geometric constraint of the system at the nanoscale. Here, we study the CDW transition in TiSe 2, a quasi-two-dimensional layered material, to determine the effects of quantum confinement and changing dimensions in films ranging from a single layer to multilayers. Of key interest is the characteristic length scale for the transformation from a two-dimensional case to the three-dimensional limit. Angle-resolved photoemission (ARPES) measurements ofmore » films with thicknesses up to six layers reveal substantial variations in the energy structure of discrete quantum well states; however, the temperature-dependent band-gap renormalization converges at just three layers. The results indicate a layer-dependent mixture of two transition temperatures and a very-short-range CDW interaction within a three-dimensional framework.« less

Beyond the single-file fluid limit using transfer matrix method: Exact results for confined parallel hard squares

DOE Office of Scientific and Technical Information (OSTI.GOV)

Gurin, Péter; Varga, Szabolcs

2015-06-14

We extend the transfer matrix method of one-dimensional hard core fluids placed between confining walls for that case where the particles can pass each other and at most two layers can form. We derive an eigenvalue equation for a quasi-one-dimensional system of hard squares confined between two parallel walls, where the pore width is between σ and 3σ (σ is the side length of the square). The exact equation of state and the nearest neighbor distribution functions show three different structures: a fluid phase with one layer, a fluid phase with two layers, and a solid-like structure where the fluidmore » layers are strongly correlated. The structural transition between differently ordered fluids develops continuously with increasing density, i.e., no thermodynamic phase transition occurs. The high density structure of the system consists of clusters with two layers which are broken with particles staying in the middle of the pore.« less

DOE Office of Scientific and Technical Information (OSTI.GOV)

Chen, P.; Pai, Woei Wu; Chan, Y. -H.

Two-dimensional materials constitute a promising platform for developing nanoscale devices and systems. Their physical properties can be very different from those of the corresponding three-dimensional materials because of extreme quantum confinement and dimensional reduction. Here in this paper we report a study of TiTe 2 from the single-layer to the bulk limit. Using angle-resolved photoemission spectroscopy and scanning tunneling microscopy and spectroscopy, we observed the emergence of a (2 × 2) charge density wave order in single-layer TiTe 2 with a transition temperature of 92 ± 3 K. Also observed was a pseudogap of about 28 meV at the Fermimore » level at 4.2 K. Surprisingly, no charge density wave transitions were observed in two-layer and multi-layer TiTe 2 , despite the quasi-two-dimensional nature of the material in the bulk. The unique charge density wave phenomenon in the single layer raises intriguing questions that challenge the prevailing thinking about the mechanisms of charge density wave formation.« less

Charge density wave transition in single-layer titanium diselenide

DOE PAGES

Chen, P.; Chan, Y. -H.; Fang, X. -Y.; ...

2015-11-16

A single molecular layer of titanium diselenide (TiSe 2) is a promising material for advanced electronics beyond graphene--a strong focus of current research. Such molecular layers are at the quantum limit of device miniaturization and can show enhanced electronic effects not realizable in thick films. We show that single-layer TiSe 2 exhibits a charge density wave (CDW) transition at critical temperature T C=232±5 K, which is higher than the bulk T C=200±5 K. Angle-resolved photoemission spectroscopy measurements reveal a small absolute bandgap at room temperature, which grows wider with decreasing temperature T below T C in conjunction with the emergencemore » of (2 × 2) ordering. The results are rationalized in terms of first-principles calculations, symmetry breaking and phonon entropy effects. The behavior of the Bardeen-Cooper-Schrieffer (BCS) gap implies a mean-field CDW order in the single layer and an anisotropic CDW order in the bulk.« less

Meteorological and intelligence evidence of long-distance transit of chemical weapons fallout from bombing early in the 1991 Persian Gulf War.

PubMed

Tuite, James J; Haley, Robert W

2013-01-01

Coalition bombings on the night of 18-19 January 1991, early in the Gulf War, targeted the Iraqi chemical weapons infrastructure. On 19 January 1991, nerve agent alarms sounded within Coalition positions hundreds of kilometers to the south, and the trace presence of sarin vapor was identified by multiple technologies. Considering only surface dispersion of plumes from explosions, officials concluded that the absence of casualties around bombed sites precluded long-distance transit of debris to US troop positions to explain the alarms and detections. Consequently, they were discounted as false positives, and low-level nerve agent exposure early in the air war was disregarded in epidemiologic investigations of chronic illnesses. Newly assembled evidence indicates that plumes from those nighttime bombings of Iraqi chemical facilities would have traversed the stable nocturnal boundary layer and penetrated the residual layer where they would be susceptible to rapid transit by supergeostrophic winds. This explanation is supported by plume height predictions, available weather charts, weather satellite images showing transit of a hot air mass, effects of solar mixing of atmospheric layers, and observations of a stationary weather front and thermal inversion in the region. Current evidence supports long-distance transit. Epidemiologic studies of chronic postwar illness should be reassessed using veterans' reports of hearing nerve agent alarms as the measure of exposure. Copyright © 2012 S. Karger AG, Basel.

Effects of Cavities and Protuberances on Transition over Hypersonic Vehicles

NASA Technical Reports Server (NTRS)

Chang, Chau-Lyan; Choudhari, Meelan M.; Li, Fei; Venkatachari, Balaji

2011-01-01

Surface protuberances and cavities on a hypersonic vehicle are known to cause several aerodynamic or aerothermodynamic issues. Most important of all, premature transition due to these surface irregularities can lead to a significant rise in surface heating. To help understand laminar-turbulent transition induced by protuberances or cavities on a Crew Exploration Vehicle (CEV) surface, high-fidelity numerical simulations are carried out for both types of trips on a CEV wind tunnel model. Due to the large bluntness, these surface irregularities reside in an accelerating subsonic boundary layer. For the Mach 6 wind tunnel conditions with a roughness Reynolds number Re(sub kk) of 800, it was found that a protuberance with a height to boundary layer thickness ratio of 0.73 leads to strong wake instability and spontaneous vortex shedding, while a cavity with identical geometry only causes a rather weak flow unsteadiness. The same cavity with a larger Reynolds number also leads to similar spontaneous vortex shedding and wake instability. The wake development and the formation of hairpin vortices for both protuberance and cavity were found to be qualitatively similar to that observed for an isolated hemisphere submerged in a subsonic, low speed flat-plate boundary layer. However, the shed vortices and their accompanying instability waves were found to be slightly stabilized downstream by the accelerating boundary layer along the CEV surface. Despite this stabilizing influence, it was found that the wake instability spreads substantially in both wall-normal and azimuthal directions as the flow is evolving towards a transitional state. Similarities and differences between the wake instability behind a protuberance and a cavity are investigated. Computations for the Mach 6 boundary layer over a slender cylindrical roughness element with a height to the boundary layer thickness of about 1.1 also shows spontaneous vortex shedding and strong wake instability. Comparisons of detailed flow structures associated with protuberances at subsonic and supersonic edge Mach numbers indicate distinctively different instability mechanisms.

Measurements in a Transitioning Cone Boundary Layer at Freestream Mach 3.5

NASA Technical Reports Server (NTRS)

King, Rudolph A.; Chou, Amanda; Balakumar, Ponnampalam; Owens, Lewis R.; Kegerise, Michael A.

2016-01-01

An experimental study was conducted in the Supersonic Low-Disturbance Tunnel to investigate naturally-occurring instabilities in a supersonic boundary layer on a 7 deg half- angle cone. All tests were conducted with a nominal freestream Mach number of M(sub infinity) = 3:5, total temperature of T(sub 0) = 299:8 K, and unit Reynolds numbers of Re(sub infinity) x 10(exp -6) = 9:89, 13.85, 21.77, and 25.73 m(exp -1). Instability measurements were acquired under noisy- ow and quiet- ow conditions. Measurements were made to document the freestream and the boundary-layer edge environment, to document the cone baseline flow, and to establish the stability characteristics of the transitioning flow. Pitot pressure and hot-wire boundary- layer measurements were obtained using a model-integrated traverse system. All hot- wire results were single-point measurements and were acquired with a sensor calibrated to mass ux. For the noisy-flow conditions, excellent agreement for the growth rates and mode shapes was achieved between the measured results and linear stability theory (LST). The corresponding N factor at transition from LST is N 3:9. The stability measurements for the quiet-flow conditions were limited to the aft end of the cone. The most unstable first-mode instabilities as predicted by LST were successfully measured, but this unstable first mode was not the dominant instability measured in the boundary layer. Instead, the dominant instabilities were found to be the less-amplified, low-frequency disturbances predicted by linear stability theory, and these instabilities grew according to linear theory. These low-frequency unstable disturbances were initiated by freestream acoustic disturbances through a receptivity process that is believed to occur near the branch I locations of the cone. Under quiet-flow conditions, the boundary layer remained laminar up to the last measurement station for the largest Re1, implying a transition N factor of N greater than 8:5.

The tropical precipitation pickup threshold and clouds in a radiative convective equilibrium model: 2. Two-layer moisture

NASA Astrophysics Data System (ADS)

Igel, Matthew R.

2017-06-01

This paper complements Part 1 in which cloud processes of aggregated convection are examined in a large-domain radiative convective equilibrium simulation in order to uncover those responsible for a consistently observed, abrupt increase in mean precipitation at a column relative humidity value of approximately 77%. In Part 2, the focus is on how the transition is affected independently by total moisture above and below the base of the melting layer. When mean precipitation rates are examined as simultaneous functions of these two moisture layers, four distinct behaviors are observed. These four behaviors suggest unique, yet familiar, physical regimes in which (i) little rain is produced by infrequent clouds, (ii) shallow convection produces increasing warm rain with increasing low-level moisture, (iii) deep convection produces progressively heavier rain above the transition point with increasing total moisture, and (iv) deep stratiform cloud produces increasingly intense precipitation from melting for increasing upper level moisture. The independent thresholds separating regimes in upper and lower layer humidity are shown to result in the value of total column humidity at which a transition between clear air and deep convection, and therefore a pickup in precipitation, is possible. All four regimes force atmospheric columns toward the pickup value at 77% column humidity, but each does so through a unique set of physical processes. Layer moisture and microphysical budgets are analyzed and contrasted with column budgets.

Probing the interaction of noble gases with pristine and nitrogen-doped graphene through Raman spectroscopy

NASA Astrophysics Data System (ADS)

Cunha, Renato; Perea-López, Néstor; Elías, Ana Laura; Fujisawa, Kazunori; Carozo, Victor; Feng, Simin; Lv, Ruitao; dos Santos, Maria Cristina; Terrones, Mauricio; Araujo, Paulo T.

2018-05-01

The interactions of adsorbates with graphene have received increasing attention due to its importance in the development of applications involving graphene-based coatings. Here, we present a study of the adsorption of noble gases on pristine and nitrogen-doped graphene. Single-layer graphene samples were synthesized by chemical vapor deposition (CVD) and transferred to transmission electron microscopy (TEM) grids. Several noble gases were allowed to adsorb on the suspended graphene substrate at very low temperatures. Raman spectra show distinct frequency blue shifts in both the 2D and G bands, which are induced by gas adsorption onto high quality single layer graphene (1LG). These shifts, which we associate with compressive biaxial strain in the graphene layers induced by the noble gases, are negligible for nitrogen-doped graphene. Additionally, a thermal depinning transition, which is related to the desorption of a noble gas layer from the graphene surface at low temperatures (ranging from 20 to 35 K), was also observed at different transition temperatures for different noble gases. These transition temperatures were found to be 25 K for argon and 35 K for xenon. Moreover, we were able to obtain values for the compressive biaxial strain in graphene induced by the adsorbed layer of noble gases, using Raman spectroscopy. Ab initio calculations confirmed the correlation between the noble gas-induced strain and the changes in the Raman features observed.

High-pressure X-ray diffraction, Raman, and computational studies of MgCl2 up to 1 Mbar: Extensive pressure stability of the β-MgCl2 layered structure.

PubMed

Stavrou, Elissaios; Yao, Yansun; Zaug, Joseph M; Bastea, Sorin; Kalkan, Bora; Konôpková, Zuzana; Kunz, Martin

2016-08-12

Magnesium chloride (MgCl2) with the rhombohedral layered CdCl2-type structure (α-MgCl2) has been studied experimentally using synchrotron angle-dispersive powder x-ray diffraction and Raman spectroscopy using a diamond-anvil cell up to 100 GPa at room temperature and theoretically using first-principles density functional calculations. The results reveal a pressure-induced second-order structural phase transition to a hexagonal layered CdI2-type structure (β-MgCl2) at 0.7 GPa: the stacking sequence of the Cl anions are altered resulting in a reduction of the c-axis length. Theoretical calculations confirm this phase transition sequence and the calculated transition pressure is in excellent agreement with the experiment. Lattice dynamics calculations also reproduce the experimental Raman spectra measured for the ambient and high-pressure phase. According to our experimental results MgCl2 remains in a 2D layered phase up to 100 GPa and further, the 6-fold coordination of Mg cations is retained. Theoretical calculations of relative enthalpy suggest that this extensive pressure stability is due to a low enthalpy of the layered structure ruling out kinetic barrier effects. This observation is unusual, as it contradicts with the general structural behavior of highly compressed AB2 compounds.

High-pressure X-ray diffraction, Raman, and computational studies of MgCl 2 up to 1 Mbar: Extensive pressure stability of the β-MgCl 2 layered structure

DOE PAGES

Stavrou, Elissaios; Yao, Yansun; Zaug, Joseph M.; ...

2016-08-12

We studied magnesium chloride (MgCl 2) with the rhombohedral layered CdCl 2-type structure (α-MgCl 2), experimentally, using synchrotron angle-dispersive powder x-ray diffraction and Raman spectroscopy using a diamond-anvil cell up to 100 GPa at room temperature and theoretically using first-principles density functional calculations. Our results reveal a pressure-induced second-order structural phase transition to a hexagonal layered CdI 2-type structure (β-MgCl 2) at 0.7 GPa: the stacking sequence of the Cl anions are altered resulting in a reduction of the c-axis length. Theoretical calculations confirm this phase transition sequence and the calculated transition pressure is in excellent agreement with the experiment.more » Lattice dynamics calculations also reproduce the experimental Raman spectra measured for the ambient and high-pressure phase. According to our experimental results MgCl 2 remains in a 2D layered phase up to 100 GPa and further, the 6-fold coordination of Mg cations is retained. Theoretical calculations of relative enthalpy suggest that this extensive pressure stability is due to a low enthalpy of the layered structure ruling out kinetic barrier effects. Our observation is unusual, as it contradicts with the general structural behavior of highly compressed AB 2 compounds.« less

Optical properties of a nanostructured glass-based film using spectroscopic ellipsometry

DOE PAGES

Jellison, G. E.; Aytug, T.; Lupini, A. R.; ...

2015-12-22

Nanostructured glass films, which are fabricated using spinodally phase-separated low-alkali glasses, have several interesting and useful characteristics, including being robust, non-wetting and antireflective. Spectroscopic ellipsometry measurements have been performed on one such film and its optical properties were analyzed using a 5-layer structural model of the near-surface region. Since the glass and the film are transparent over the spectral region of the measurement, the Sellmeier model is used to parameterize the dispersion in the refractive index. To simulate the variation of the optical properties of the film over the spot size of the ellipsometer (~ 3 × 5 mm), themore » Sellmeier amplitude is convoluted using a Gaussian distribution. The transition layers between the ambient and the film and between the film and the substrate are modeled as graded layers, where the refractive index varies as a function of depth. These layers are modeled using a two-component Bruggeman effective medium approximation where the two components are the layer above and the layer below. Lastly, the fraction is continuous through the transition layer and is modelled using the incomplete beta function.« less

Plume Splitting in a Two-layer Stratified Ambient Fluid

NASA Astrophysics Data System (ADS)

Ma, Yongxing; Flynn, Morris; Sutherland, Bruce

2017-11-01

A line-source plume descending into a two-layer stratified ambient fluid in a finite sized tank is studied experimentally. Although the total volume of ambient fluid is fixed, lower- and upper-layer fluids are respectively removed and added at a constant rate mimicking marine outfall through diffusers and natural and hybrid ventilated buildings. The influence of the plume on the ambient depends on the value of λ, defined as the ratio of the plume buoyancy to the buoyancy loss of the plume as it crosses the ambient interface. Similar to classical filling-box experiments, the plume can always reach the bottom of the tank if λ > 1 . By contrast, if λ < 1 , an intermediate layer eventually forms as a result of plume splitting. Eventually all of the plume fluid spreads within the intermediate layer. The starting time, tv, and the ending time, tt, of the transition process measured from experiments correlate with the value of λ. A three-layer ambient fluid is observed after transition, and the mean value of the measured densities of the intermediate layer fluid is well predicted using plume theory. Acknowledgments: Funding for this study was provided by NSERC.

Direct simulation of high-speed mixing layers

NASA Technical Reports Server (NTRS)

Mukunda, H. S.; Sekar, B.; Carpenter, M. H.; Drummond, J. Philip; Kumar, Ajay

1992-01-01

A computational study of a nonreacting high-speed mixing layer is performed. A higher order algorithm with sufficient grid points is used to resolve all relevant scales. In all cases, a temporal free-stream disturbance is introduced. The resulting flow is time-sampled to generate a statistical cross section of the flow properties. The studies are conducted at two convective Mach numbers, three free-stream turbulence intensities, three Reynolds numbers, and two types of initial profiles-hyperbolic tangent (tanh) and boundary layer. The boundary-layer profile leads to more realistic predictions of the transition processes. The predicted transition Reynolds number of 0.18 x 10(exp 6) compares well with experimental data. Normalized vortex spacings for the boundary-layer case are about 3.5 and compare favorably with the 1.5 to 2.5 found in experimental measurements. The tanh profile produces spacings of about 10. The growth rate of the layer is shown to be moderately affected by the initial disturbance field, but comparison with experimental data shows moderate agreement. For the boundary-layer case, it is shown that noise at the Strouhal number of 0.007 is selectively amplified and shows little Reynolds number dependence.

Influence of Freestream and Forced Disturbances on the Shear Layers of a Square Prism

NASA Astrophysics Data System (ADS)

Lander, Daniel Chapman

Flow around the square prism, an archetypal bluff body, has applications in all areas of fluid mechanics: vibration, mixing, combustion and noise production to name a few. It also has distinct importance to wind loading on architectural and industrial structures such as tall buildings, bridges, and towers. The von-Karman (VK) vortex street is a major reason for its significance: a flow phenomenon which has received intense scrutiny from scientific and engineering communities for more than 100 years! However, the characteristics of the shear layers separating from the sharp edges, essential to the vortex shedding, have received comparatively little attention. This is surprising considering the Kelvin-Helmholtz (KH) instability of shear layers produce the first signatures of turbulence in the wake. Furthermore, the shear layers are conduits for the passage of vorticity between the boundary layer and the turbulent wake. Many details of their structure and role in the shedding process remain unexplored. This dissertation aims to address this deficiency. Specifically, this project considered the influence of three variables on the characteristics of the transition-to-turbulence in the square prism shear layers. These are: (1) Reynolds number; (2) freestream disturbances and (3) forced disturbances. In each case, the dynamics of the shear layer-wake interaction were considered. Particle image velocimetry and constant temperature anemometry measurements were used to document the shear layer during inception and evolution as it passes into the wake. With increasing Reynolds number, ReD = UinfinityD/nu, in the range 16,700-148,000, the transition-to-turbulence in the initially laminar shear layer moves toward separation. A coordinate system local to the time-averaged shear layer axis was used such that the tangent and normal velocities, turbulent stresses and gradient quantities could be obtained for the curved shear layer. Characteristic frequencies, lengths and transition points of the KH instability were documented and shown to exhibit features distinct from the plane mixing layer. The evolution of the integrated turbulent kinetic energy was documented and a linear region of growth was associated with the amplification of the KH instability. A scaling relationship of the Kelvin-Helmholtz to von-Karman frequencies was established for the square prism shear layer. ƒKH/ƒ VK was shown to be a power-law function of Re D, with differing characteristics to the much more studied circular cylinder. Increasing ReD up to ˜ 70,000 bolsters the Reynolds stresses in the shear layers as they enter the wake, shortening the wake formation length, LF. The shear layer diffusion length, LD was quantified and the Gerrard-Product, LF x LD, was introduced to account for constant St D in the presence of the reduced LF as function of ReD. A freestream disturbance condition with intensity □ u¯¯ 2¯ / U infinity = 0.065 and longitudinal integral length scale, Lxu = 0.33 was considered for the case of ReD = 50,000. Disturbances were introduced by means of small circular cylinder placed upstream of the stagnation streamline. The disturbance moved the time-averaged position of the shear layer towards the body but did not substantially alter the growth rate of its width. The "normal" transition-to-turbulence pathway, via laminar vortex formation and subsequent pairing of vortices in the initial stages of the shear layer was shown to be highly sensitive to external disturbances. The disturbance interrupted the typical transition pathway and was associated with a Bypass-transition mechanism, which subsequently increased the likelihood of intermittent shear layer reattachment on the downstream surface of the body. Triple decomposition was used to study the random and coherent components of the VK structures in the wake. Data indicated a narrowing and lengthening of the wake, which was accompanied by a rise in base pressure and a reduction in time-averaged drag. The unsteady coherent vorticity field revealed a streamwise elongation of the VK vortex structures, which complemented the time-averaged wake lengthening. It appears that the influence of freestream disturbances, in particular, by their stochastic nature, is to suppress the formation of the coherent structures in the shear layer. Forced disturbances imposed on the shear layers at the leading edges of the square prism were considered at ReD=16,700 for excitation frequencies ƒe = ƒ KH, ƒVK and 0. The response of the shear layer to forcing at steady and ƒVK frequencies had little impact on the time-averaged position or growth.

Understanding the Intrinsic Electrochemistry of Ni-Rich Layered Cathodes

NASA Astrophysics Data System (ADS)

Sallis, Shawn

The demand for energy is continually increasing overtime and the key to meeting future demand in a sustainable way is with energy storage. Li-ion batteries employing layered transition metal oxide cathodes are one of the most technologically important energy storage technologies. However, current Li-ion batteries are unable to access their full theoretical capacity and suffer from performance limiting degradation over time partially originating from the cathode and partially from the interface with the electrolyte. Understanding the fundamental limitations of layered transition metal oxide cathodes requires a complete understanding of the surface and bulk of the materials in their most delithiated state. In this thesis, we employ LiNi0.8Co0.15Al 0.05O2 (NCA) as a model system for Ni-rich layered oxide cathodes. Unlike its parent compound, LiCoO2, NCA is capable of high states of delithiation with minimal structural transitions. Furthermore, commercially available NCA has little to no transition metals in the Li layer. X-ray spectroscopies are an ideal tool for studying cathodes at high states of delithiation due their elemental selectivity, range of probing depths, and sensitivity to both chemical and electronic state information. The oxidation state of the transition metals at the surface can be probed via X-ray photoelectron spectroscopy (XPS) while both bulk and surface oxidation states as well as changes in metal oxygen bonding can be probed using X-ray absorption spectroscopy (XAS). Using X-ray spectroscopy in tandem with electrochemical, transport and microscopy measurements of the same materials, the impedance growth with increasing delithiation was correlated with the formation of a disordered NiO phase on the surface of NCA which was precipitated by the release of oxygen. Furthermore, the surface degradation was strongly impacted by the type of Li salt used in the electrolyte, with the standard commercial salt LiPF6 suffering from exothermic decomposition at high voltages and temperatures. Substituting LiPF6with LiBF4 suppressed NCA surface degradation and the dissolution of the transition metals into the electrolyte which is responsible for the impedance growth. Even in the most extreme conditions (4.75V vs Li +/Li0 at 60 °C for > 100 hrs) the degradation (i.e. metal reduction) was restricted to the first 10-30 nm and no evidence of oxygen loss was observed in the bulk. However, the transition metal ions were found to cease oxidizing above 4.25 V vs Li+/Li0 despite it being possible to extract 20% more lithium. Using a newly developed high efficiency resonant inelastic x-ray scattering (RIXS) spectrometer to probe the O K-edge of NCA electrodes at various conditions, it was concluded that oxygen participates in the charge compensation at the highest states of delithiation instead of the transition metals. These results are intrinsic to the physical and electronic structure of NCA and appear general to the other layered transition metal oxides currently under consideration for use as cathodes in Li-ion batteries.

Global Infrared Observations of Roughness Induced Transition on the Space Shuttle Orbiter

NASA Technical Reports Server (NTRS)

Horvath, Thomas J.; Zalameda, Joseph N.; Wood, William A.; Berry, Scott A.; Schwartz, Richard J.; Dantowitz, Ronald F.; Spisz, Thomas S.; Taylor, Jeff C.

2012-01-01

High resolution infrared observations made from a mobile ground based optical system captured the laminar-to-turbulent boundary layer transition process as it occurred during Space Shuttle Endeavour's return to earth following its final mission in 2011. The STS-134 imagery was part of a larger effort to demonstrate an emerging and reliable non-intrusive global thermal measurement capability and to complement a series of boundary layer transition flight experiments that were flown on the Shuttle. The STS-134 observations are believed to be the first time that the development and movement of a hypersonic boundary layer transition front has been witnessed in flight over the entire vehicle surface and in particular, at unprecedented spatial resolution. Additionally, benchmark surface temperature maps of the Orbiter lower surface collected over multiple flights and spanning a Mach range of 18 to 6 are now available and represent an opportunity for collaborative comparison with computational techniques focused on hypersonic transition and turbulence modeling. The synergy of the global temperature maps with the companion in-situ thermocouple measurements serve as an example of the effective leveraging of resources to achieve a common goal of advancing our understanding of the complex nature of high Mach number transition. It is shown that quantitative imaging can open the door to a multitude of national and international opportunities for partnership associated with flight-testing and subsequent validation of numerical simulation techniques. The quantitative imaging applications highlighted in this paper offer unique and complementary flight measurement alternatives and suggest collaborative instrumentation opportunities to advance the state of the art in transition prediction and maximize the return on investment in terms of developmental flight tests for future vehicle designs.

A complex-lamellar description of boundary layer transition

NASA Astrophysics Data System (ADS)

Kolla, Maureen Louise

Flow transition is important, in both practical and phenomenological terms. However, there is currently no method for identifying the spatial locations associated with transition, such as the start and end of intermittency. The concept of flow stability and experimental correlations have been used, however, flow stability only identifies the location where disturbances begin to grow in the laminar flow and experimental correlations can only give approximations as measuring the start and end of intermittency is difficult. Therefore, the focus of this work is to construct a method to identify the start and end of intermittency, for a natural boundary layer transition and a separated flow transition. We obtain these locations by deriving a complex-lamellar description of the velocity field that exists between a fully laminar and fully turbulent boundary condition. Mathematically, this complex-lamellar decomposition, which is constructed from the classical Darwin-Lighthill-Hawthorne drift function and the transport of enstrophy, describes the flow that exists between the fully laminar Pohlhausen equations and Prandtl's fully turbulent one seventh power law. We approximate the difference in enstrophy density between the boundary conditions using a power series. The slope of the power series is scaled by using the shape of the universal intermittency distribution within the intermittency region. We solve the complex-lamellar decomposition of the velocity field along with the slope of the difference in enstrophy density function to determine the location of the laminar and turbulent boundary conditions. Then from the difference in enstrophy density function we calculate the start and end of intermittency. We perform this calculation on a natural boundary layer transition over a flat plate for zero pressure gradient flow and for separated shear flow over a separation bubble. We compare these results to existing experimental results and verify the accuracy of our transition model.

Seismics-electrics Joint Interpretation in a gypsiferous context.

NASA Astrophysics Data System (ADS)

Marzan, Ignacio; Marti, David; Lobo, Agustin; Alvarez-Marron, Joaquina; Carbonell, Ramon

2016-04-01

The main objective of this study is to improve the geophysical characterization resulting from a shallow 3D high resolution travel-time tomography survey (500x500m). This survey was acquired in Villar de Cañas (Cuenca, Spain) in late 2013 and early 2014. Lithology down to 150 m depth in this site is characterized by endorheic sediments, mainly siltstone and gypsum. After processing the tomography data, the velocity model showed a good correlation with geology models and borehole data except for the siltstone-gypsum transition. The model involves two lithological limits: the "transition layer - massive gypsum layer" (well resolved by a relatively high velocity contrast) and the "siltstone layer - transition layer" (constrained only in the central part of the model by a relatively low velocity contrast). As electrical resistivity is able to characterize shale-gypsum transitions, we complemented the seismic data with results from a collection of 2D ERT surveys, for which we build a new 3D grid with 2 parameters by node: velocity and resistivity. In order to derive a geological interpretation, we apply a statistical classification method (Linear Discriminant Analysis) to the new bi-parametric grid, using reference classes from well logs. This process results on a final 3D lithological model with less ambiguity and thus with a better definition of the two limits under discussion. Our study shows that the integration of seismic and electric methods significantly improves geological characterization in a gypsiferous context.

Design of Co/Pd multilayer system with antiferromagnetic-to-ferromagnetic phase transition

NASA Astrophysics Data System (ADS)

Thiele, Jan-Ulrich

2009-03-01

Among the known magnetic material systems there are only very few examples of materials that undergo a temperature dependent antiferromagnetic-to-ferromagnetic phase transition, and of these only the chemically ordered alloy FeRh exhibits this transition near room temperature [1, 2]. Here we present a perpendicular anisotropy multilayer structure that mimics FeRh. The basic idea is to use two stacks of Co/Pd multilayers with large perpendicular magnetic anisotropy and high Curie temperature, TC, separated by a layer providing antiferromagnetic coupling, and a CoNi/Pd multilayer with perpendicular anisotropy with a lower TC, interlayer, in the range of the desired AF-FM transition temperature, TAF-FM. At room temperature this system behaves as two antiferromagnetically coupled layers with a low perpendicular remanent magnetic moment. As the temperature is raised to approach TC, interlayer the magnetization of the interlayer is gradually reduced to zero, and consequently its coupling strength is reduced. Eventually, the effective coupling between the two high-KU, high-TC layers becomes dominated by their dipolar fields, resulting in a parallel alignment of their moments and a net remanent magnetic moment equal to the sum of the moments of the two high-TC layers [2]. [4pt] [1] J. S. Kouvel and C. C. Hartelius, J. Appl. Phys. 33 (1962) p1343 [0pt] [2] J.-U. Thiele, E. E. Fullerton, S. Maat, Appl. Phys. Lett. 82 (2003) p2859 [0pt] [3] J.-U. Thiele. T. Hauet. O. Hellwig, Appl. Phys. Lett. 92 (2008) 242502.

Preliminary Note on a Correlation of a Boundary-Layer Transition Results on Highly Cooled Blunt Bodies

NASA Technical Reports Server (NTRS)

Wisniewski, Richard J.

1957-01-01

Transition data on highly cooled blunt bodies are correlated in terms of the ratio of wall to local-stream enthalpy, Reynolds number based on displacement thickness, and location of transition. The proposed correlation, although not sensitive enough to predict the exact location of transition does predict the enthalpy ratio below which very early transition on blunt bodies is expected. The correlation is not altered by moderate amounts of surface roughness; however, the location of transition may well be affected by roughness.

Phase transition detection by surface photo charge effect in liquid crystals

NASA Astrophysics Data System (ADS)

Ivanov, O.; Petrov, M.; Naradikian, H.; Perez-Diaz, J. L.

2018-05-01

The surface photo charge effect (SPCE) was applied for the first time at structure and phase transitions study of hydrogen bonded in dimer liquid crystals (HBDLCs). Due to the high sensitivity of this method, besides first-order phase transitions, characteristic for the p,n-octyloxibenzoic acids (8OBA), an order transition was definitely detected within the nematic range. We state that the SPCE, arising at the solid-HBDLCs interface due to the double electrical layer, is invariably concomitant with solid surface-liquid interfaces, and indicates that the changes of the characteristics of this layer, under incident optical irradiation, induce surface charge rearrangement and alternating potential difference. A mechanism of induction of the SPCE at the interface of solid surface-anisotropic liquids is proposed. We also indicate that this mechanism can be adapted for solid surface-isotropic liquid interface, including colloids (milk) and fog (aerosols)-condensed medium.

Landau-de Gennes theory of surface-enhanced ordering in smectic films.

PubMed

Shalaginov, A N; Sullivan, D E

2001-03-01

A Landau theory for surface-enhanced ordering in smectic-A free-standing films is described, based on a generalization of de Gennes' model for a "presmectic" fluid confined between two walls. According to the theory, smectic ordering in free-standing films heated above the bulk smectic melting temperature is due to an intrinsic surface contribution rather than an external field. The theory yields a persistent finite-size effect, in that the film melting temperatures do not tend to the bulk transition temperature in the limit of infinite film thickness. It also predicts that a continuous transition from (N+1)- to N-layer films is impossible without an external field. The theory closely fits existing experimental data on layer-thinning transitions in compounds which exhibit a bulk smectic-A to nematic phase transition. Possible origins of the intrinsic surface contribution are discussed.