Optimal hydrograph separation using a recursive digital filter constrained by chemical mass balance, with application to selected Chesapeake Bay watersheds

USGS Publications Warehouse

Raffensperger, Jeff P.; Baker, Anna C.; Blomquist, Joel D.; Hopple, Jessica A.

2017-06-26

Quantitative estimates of base flow are necessary to address questions concerning the vulnerability and response of the Nation’s water supply to natural and human-induced change in environmental conditions. An objective of the U.S. Geological Survey National Water-Quality Assessment Project is to determine how hydrologic systems are affected by watershed characteristics, including land use, land cover, water use, climate, and natural characteristics (geology, soil type, and topography). An important component of any hydrologic system is base flow, generally described as the part of streamflow that is sustained between precipitation events, fed to stream channels by delayed (usually subsurface) pathways, and more specifically as the volumetric discharge of water, estimated at a measurement site or gage at the watershed scale, which represents groundwater that discharges directly or indirectly to stream reaches and is then routed to the measurement point.Hydrograph separation using a recursive digital filter was applied to 225 sites in the Chesapeake Bay watershed. The recursive digital filter was chosen for the following reasons: it is based in part on the assumption that groundwater acts as a linear reservoir, and so has a physical basis; it has only two adjustable parameters (alpha, obtained directly from recession analysis, and beta, the maximum value of the base-flow index that can be modeled by the filter), which can be determined objectively and with the same physical basis of groundwater reservoir linearity, or that can be optimized by applying a chemical-mass-balance constraint. Base-flow estimates from the recursive digital filter were compared with those from five other hydrograph-separation methods with respect to two metrics: the long-term average fraction of streamflow that is base flow, or base-flow index, and the fraction of days where streamflow is entirely base flow. There was generally good correlation between the methods, with some biased slightly high and some biased slightly low compared to the recursive digital filter. There were notable differences between the days at base flow estimated by the different methods, with the recursive digital filter having a smaller range of values. This was attributed to how the different methods determine cessation of quickflow (the part of streamflow which is not base flow).For 109 Chesapeake Bay watershed sites with available specific conductance data, the parameters of the filter were optimized using a chemical-mass-balance constraint and two different models for the time-dependence of base-flow specific conductance. Sixty-seven models were deemed acceptable and the results compared well with non-optimized results. There are a number of limitations to the optimal hydrograph-separation approach resulting from the assumptions implicit in the conceptual model, the mathematical model, and the approach taken to impose chemical mass balance (including tracer choice). These limitations may be evidenced by poor model results; conversely, poor model fit may provide an indication that two-component separation does not adequately describe the hydrologic system’s runoff response.The results of this study may be used to address a number of questions regarding the role of groundwater in understanding past changes in stream-water quality and forecasting possible future changes, such as the timing and magnitude of land-use and management practice effects on stream and groundwater quality. Ongoing and future modeling efforts may benefit from the estimates of base flow as calibration targets or as a means to filter chemical data to model base-flow loads and trends. Ultimately, base-flow estimation might provide the basis for future work aimed at improving the ability to quantify groundwater discharge, not only at the scale of a gaged watershed, but at the scale of individual reaches as well.

A new model for simulating spring discharge recession and estimating effective porosity of karst aquifers

NASA Astrophysics Data System (ADS)

Xu, Bin; Ye, Ming; Dong, Shuning; Dai, Zhenxue; Pei, Yongzhen

2018-07-01

Quantitative analysis of recession curves of karst spring hydrographs is a vital tool for understanding karst hydrology and inferring hydraulic properties of karst aquifers. This paper presents a new model for simulating karst spring recession curves. The new model has the following characteristics: (1) the model considers two separate but hydraulically connected reservoirs: matrix reservoir and conduit reservoir; (2) the model separates karst spring hydrograph recession into three stages: conduit-drainage stage, mixed-drainage stage (with both conduit drainage and matrix drainage), and matrix-drainage stage; and (3) in the mixed-drainage stage, the model uses multiple conduit layers to present different levels of conduit development. The new model outperforms the classical Mangin model and the recently developed Fiorillo model for simulating observed discharge at the Madison Blue Spring located in northern Florida. This is attributed to the latter two characteristics of the new model. Based on the new model, a method is developed for estimating effective porosity of the matrix and conduit reservoirs for the three drainage stages. The estimated porosity values are consistent with measured matrix porosity at the study site and with estimated conduit porosity reported in literature. The new model for simulating karst spring hydrograph recession is mathematically general, and can be applied to a wide range of karst spring hydrographs to understand groundwater flow in karst aquifers. The limitations of the model are discussed at the end of this paper.

A three-component hydrograph separation based on geochemical tracers in a tropical mountainous headwater catchment in northern Thailand

NASA Astrophysics Data System (ADS)

Hugenschmidt, C.; Ingwersen, J.; Sangchan, W.; Sukvanachaikul, Y.; Duffner, A.; Uhlenbrook, S.; Streck, T.

2014-02-01

Land-use change in the mountainous parts of northern Thailand is reflected by an increased application of agrochemicals, which may be lost to surface and groundwater. The close relation between flow paths and contaminant transport within hydrological systems requires recognizing and understanding the dominant hydrological processes. To date, the vast majority of studies on runoff generation have been conducted in temperate regions. Tropical regions suffer from a general lack of data, and little is known about runoff generation processes. To fill this knowledge gap, a three-component hydrograph separation based on geochemical tracers was carried out in a steep, remote and monsoon-dominated study site (7 km2) in northern Thailand. Silica and electrical conductivity (EC) were identified as useful tracers and were applied to calculate the fractions of groundwater (similar to pre-event water), shallow subsurface flow and surface runoff on stormflow. K+ was a useful indicator for surface runoff dynamics, and Ca2+ provided insights into groundwater behaviour. Nevertheless, neither measure was applicable for the quantification of runoff components. Cl- and further parameters (e.g. Na+, K+, and Mg2+) were also not helpful for flow path identification, nor were their concentrations distinguishable among the components. Groundwater contributed the largest fractions to stormflow (62-80%) throughout all events, followed by shallow subsurface flow (17-36%) and surface runoff (2-13%). Our results provide important insights into the dynamics of the runoff processes in the study area and may be used to assess the transport pattern of contaminants (i.e. agrochemicals) here.

U.S. Geological Survey groundwater toolbox, a graphical and mapping interface for analysis of hydrologic data (version 1.0): user guide for estimation of base flow, runoff, and groundwater recharge from streamflow data

USGS Publications Warehouse

Barlow, Paul M.; Cunningham, William L.; Zhai, Tong; Gray, Mark

2015-01-01

This report is a user guide for the streamflow-hydrograph analysis methods provided with version 1.0 of the U.S. Geological Survey (USGS) Groundwater Toolbox computer program. These include six hydrograph-separation methods to determine the groundwater-discharge (base-flow) and surface-runoff components of streamflow—the Base-Flow Index (BFI; Standard and Modified), HYSEP (Fixed Interval, Sliding Interval, and Local Minimum), and PART methods—and the RORA recession-curve displacement method and associated RECESS program to estimate groundwater recharge from streamflow data. The Groundwater Toolbox is a customized interface built on the nonproprietary, open source MapWindow geographic information system software. The program provides graphing, mapping, and analysis capabilities in a Microsoft Windows computing environment. In addition to the four hydrograph-analysis methods, the Groundwater Toolbox allows for the retrieval of hydrologic time-series data (streamflow, groundwater levels, and precipitation) from the USGS National Water Information System, downloading of a suite of preprocessed geographic information system coverages and meteorological data from the National Oceanic and Atmospheric Administration National Climatic Data Center, and analysis of data with several preprocessing and postprocessing utilities. With its data retrieval and analysis tools, the Groundwater Toolbox provides methods to estimate many of the components of the water budget for a hydrologic basin, including precipitation; streamflow; base flow; runoff; groundwater recharge; and total, groundwater, and near-surface evapotranspiration.

Neural network river forecasting through baseflow separation and binary-coded swarm optimization

NASA Astrophysics Data System (ADS)

Taormina, Riccardo; Chau, Kwok-Wing; Sivakumar, Bellie

2015-10-01

The inclusion of expert knowledge in data-driven streamflow modeling is expected to yield more accurate estimates of river quantities. Modular models (MMs) designed to work on different parts of the hydrograph are preferred ways to implement such approach. Previous studies have suggested that better predictions of total streamflow could be obtained via modular Artificial Neural Networks (ANNs) trained to perform an implicit baseflow separation. These MMs fit separately the baseflow and excess flow components as produced by a digital filter, and reconstruct the total flow by adding these two signals at the output. The optimization of the filter parameters and ANN architectures is carried out through global search techniques. Despite the favorable premises, the real effectiveness of such MMs has been tested only on a few case studies, and the quality of the baseflow separation they perform has never been thoroughly assessed. In this work, we compare the performance of MM against global models (GMs) for nine different gaging stations in the northern United States. Binary-coded swarm optimization is employed for the identification of filter parameters and model structure, while Extreme Learning Machines, instead of ANN, are used to drastically reduce the large computational times required to perform the experiments. The results show that there is no evidence that MM outperform global GM for predicting the total flow. In addition, the baseflow produced by the MM largely underestimates the actual baseflow component expected for most of the considered gages. This occurs because the values of the filter parameters maximizing overall accuracy do not reflect the geological characteristics of the river basins. The results indeed show that setting the filter parameters according to expert knowledge results in accurate baseflow separation but lower accuracy of total flow predictions, suggesting that these two objectives are intrinsically conflicting rather than compatible.

Base flow of streams in the outcrop area of southeastern sand aquifer, South Carolina, Georgia, Alabama, and Mississippi

USGS Publications Warehouse

Stricker, Virginia

1983-01-01

The base flow component of streamflow was separated from hydrographs for unregulated streams in the Cretaceous and Tertiary clastic outcrop area of South Carolina, Georgia, Alabama, and Mississippi. The base flow values are used in estimating recharge to the sand aquifer. Relations developed between mean annual base flow and stream discharge at the 60- and 65-percent streamflow duration point can be used to approximate mean annual base flow in lieu of hydrograph separation methods for base flows above 10 cu ft/s. Base flow recession curves were used to derive estimates of hydraulic diffusivity of the aquifer which was converted to transmissivity using estimated specific yield. These base-flow-derived transmissivities are in general agreement with transmissivities derived from well data. The shape of flow duration curves of streams is affected by the lithology of the Coastal Plain sediments. Steep flow duration curves appear to be associated with basins underlain by clay or chalk where a low percentage of the discharge is base flow while flatter curves appear to be associated with basins underlain by sand and gravel where a high percentage of the discharge is base flow. (USGS)

A comparison of high-resolution specific conductance-based end-member mixing analysis and a graphical method for baseflow separation of four streams in hydrologically challenging agricultural watersheds

USGS Publications Warehouse

Kronholm, Scott C.; Capel, Paul D.

2015-01-01

Quantifying the relative contributions of different sources of water to a stream hydrograph is important for understanding the hydrology and water quality dynamics of a given watershed. To compare the performance of two methods of hydrograph separation, a graphical program [baseflow index (BFI)] and an end-member mixing analysis that used high-resolution specific conductance measurements (SC-EMMA) were used to estimate daily and average long-term slowflow additions of water to four small, primarily agricultural streams with different dominant sources of water (natural groundwater, overland flow, subsurface drain outflow, and groundwater from irrigation). Because the result of hydrograph separation by SC-EMMA is strongly related to the choice of slowflow and fastflow end-member values, a sensitivity analysis was conducted based on the various approaches reported in the literature to inform the selection of end-members. There were substantial discrepancies among the BFI and SC-EMMA, and neither method produced reasonable results for all four streams. Streams that had a small difference in the SC of slowflow compared with fastflow or did not have a monotonic relationship between streamflow and stream SC posed a challenge to the SC-EMMA method. The utility of the graphical BFI program was limited in the stream that had only gradual changes in streamflow. The results of this comparison suggest that the two methods may be quantifying different sources of water. Even though both methods are easy to apply, they should be applied with consideration of the streamflow and/or SC characteristics of a stream, especially where anthropogenic water sources (irrigation and subsurface drainage) are present.

Assessment of surface water resources availability using catchment modeling and the results of tracer studies in the meso-scale Migina Catchment, Rwanda

NASA Astrophysics Data System (ADS)

Munyaneza, O.; Mukubwa, A.; Maskey, S.; Wenninger, J.; Uhlenbrook, S.

2013-12-01

In the last couple of years, different hydrological research projects were undertaken in the Migina catchment (243.2 km2), a tributary of the Kagera river in Southern Rwanda. These projects were aimed to understand hydrological processes of the catchment using analytical and experimental approaches and to build a pilot case whose experience can be extended to other catchments in Rwanda. In the present study, we developed a hydrological model of the catchment, which can be used to inform water resources planning and decision making. The semi-distributed hydrological model HEC-HMS (version 3.5) was used with its soil moisture accounting, unit hydrograph, liner reservoir (for base flow) and Muskingum-Cunge (river routing) methods. We used rainfall data from 12 stations and streamflow data from 5 stations, which were collected as part of this study over a period of two years (May 2009 and June 2011). The catchment was divided into five sub-catchments each represented by one of the five observed streamflow gauges. The model parameters were calibrated separately for each sub-catchment using the observed streamflow data. Calibration results obtained were found acceptable at four stations with a Nash-Sutcliffe Model Efficiency of 0.65 on daily runoff at the catchment outlet. Due to the lack of sufficient and reliable data for longer periods, a model validation (split sample test) was not undertaken. However, we used results from tracer based hydrograph separation from a previous study to compare our model results in terms of the runoff components. It was shown that the model performed well in simulating the total flow volume, peak flow and timing as well as the portion of direct runoff and base flow. We observed considerable disparities in the parameters (e.g. groundwater storage) and runoff components across the five sub-catchments, that provided insights into the different hydrological processes at sub-catchment scale. We conclude that such disparities justify the need to consider catchment subdivisions, if such parameters and components of the water cycle are to form the base for decision making in water resources planning in the Migina catchment.

Assessment of surface water resources availability using catchment modelling and the results of tracer studies in the mesoscale Migina Catchment, Rwanda

NASA Astrophysics Data System (ADS)

Munyaneza, O.; Mukubwa, A.; Maskey, S.; Uhlenbrook, S.; Wenninger, J.

2014-12-01

In the present study, we developed a catchment hydrological model which can be used to inform water resources planning and decision making for better management of the Migina Catchment (257.4 km2). The semi-distributed hydrological model HEC-HMS (Hydrologic Engineering Center - the Hydrologic Modelling System) (version 3.5) was used with its soil moisture accounting, unit hydrograph, liner reservoir (for baseflow) and Muskingum-Cunge (river routing) methods. We used rainfall data from 12 stations and streamflow data from 5 stations, which were collected as part of this study over a period of 2 years (May 2009 and June 2011). The catchment was divided into five sub-catchments. The model parameters were calibrated separately for each sub-catchment using the observed streamflow data. Calibration results obtained were found acceptable at four stations with a Nash-Sutcliffe model efficiency index (NS) of 0.65 on daily runoff at the catchment outlet. Due to the lack of sufficient and reliable data for longer periods, a model validation was not undertaken. However, we used results from tracer-based hydrograph separation from a previous study to compare our model results in terms of the runoff components. The model performed reasonably well in simulating the total flow volume, peak flow and timing as well as the portion of direct runoff and baseflow. We observed considerable disparities in the parameters (e.g. groundwater storage) and runoff components across the five sub-catchments, which provided insights into the different hydrological processes on a sub-catchment scale. We conclude that such disparities justify the need to consider catchment subdivisions if such parameters and components of the water cycle are to form the base for decision making in water resources planning in the catchment.

Using isotopes of dissolved inorganic carbon species and water to separate sources of recharge in a cave spring, northwestern Arkansas, USA Blowing Spring Cave

USGS Publications Warehouse

Knierim, Katherine J.; Pollock, Erik; Hays, Phillip D.

2013-01-01

Blowing Spring Cave in northwestern Arkansas is representative of cave systems in the karst of the Ozark Plateaus, and stable isotopes of water (δ18O and δ2H) and inorganic carbon (δ13C) were used to quantify soil-water, bedrock-matrix water, and precipitation contributions to cave-spring flow during storm events to understand controls on cave water quality. Water samples from recharge-zone soils and the cave were collected from March to May 2012 to implement a multicomponent hydrograph separation approach using δ18O and δ2H of water and dissolved inorganic carbon (δ13C–DIC). During baseflow, median δ2H and δ18O compositions were –41.6‰ and –6.2‰ for soil water and were –37.2‰ and –5.9‰ for cave water, respectively. Median DIC concentrations for soil and cave waters were 1.8 mg/L and 25.0 mg/L, respectively, and median δ13C–DIC compositions were –19.9‰ and –14.3‰, respectively. During a March storm event, 12.2 cm of precipitation fell over 82 h and discharge increased from 0.01 to 0.59 m3/s. The isotopic composition of precipitation varied throughout the storm event because of rainout, a change of 50‰ and 10‰ for δ2H and δ18O was observed, respectively. Although, at the spring, δ2H and δ18O only changed by approximately 3‰ and 1‰, respectively. The isotopic compositions of precipitation and pre-event (i.e., soil and bedrock matrix) water were isotopically similar and the two-component hydrograph separation was inaccurate, either overestimating (>100%) or underestimating (<0%) the precipitation contribution to the spring. During the storm event, spring DIC and δ13C–DIC decreased to a minimum of 8.6 mg/L and –16.2‰, respectively. If the contribution from precipitation was assumed to be zero, soil water was found to contribute between 23 to 72% of the total volume of discharge. Although the assumption of negligible contributions from precipitation is unrealistic, especially in karst systems where rapid flow through conduits occurs, the hydrograph separation using inorganic carbon highlights the importance of considering vadose-zone soil water when analyzing storm chemohydrographs.

Estimation of time-variable fast flow path chemical concentrations for application in tracer-based hydrograph separation analyses

USGS Publications Warehouse

Kronholm, Scott C.; Capel, Paul D.

2016-01-01

Mixing models are a commonly used method for hydrograph separation, but can be hindered by the subjective choice of the end-member tracer concentrations. This work tests a new variant of mixing model that uses high-frequency measures of two tracers and streamflow to separate total streamflow into water from slowflow and fastflow sources. The ratio between the concentrations of the two tracers is used to create a time-variable estimate of the concentration of each tracer in the fastflow end-member. Multiple synthetic data sets, and data from two hydrologically diverse streams, are used to test the performance and limitations of the new model (two-tracer ratio-based mixing model: TRaMM). When applied to the synthetic streams under many different scenarios, the TRaMM produces results that were reasonable approximations of the actual values of fastflow discharge (±0.1% of maximum fastflow) and fastflow tracer concentrations (±9.5% and ±16% of maximum fastflow nitrate concentration and specific conductance, respectively). With real stream data, the TRaMM produces high-frequency estimates of slowflow and fastflow discharge that align with expectations for each stream based on their respective hydrologic settings. The use of two tracers with the TRaMM provides an innovative and objective approach for estimating high-frequency fastflow concentrations and contributions of fastflow water to the stream. This provides useful information for tracking chemical movement to streams and allows for better selection and implementation of water quality management strategies.

Spatiotemporal tracer variability in glacier melt and its influence on hydrograph separation

NASA Astrophysics Data System (ADS)

Schmieder, Jan; Marke, Thomas; Strasser, Ulrich

2017-04-01

Glaciers are important seasonal water contributors in many mountainous regions. Knowledge on the timing and amount of glacier melt water is crucial for water resources management, especially in downstream regions where the water is needed (hydropower, drinking water) or where it represents a potential risk (drought, flood). This becomes even more relevant in a changing climate. Environmental tracers are a useful tool in the assessment of ice water resources, because they provide information about the sources, flow paths and traveling times of water contributing to streamflow at the catchment scale. Hydrometric and meteorological measurements combined with tracer analyses help to unravel streamflow composition and improve the understanding of hydroclimatological processes. Empirical studies on runoff composition are necessary to parameterize and validate hydrological models in a process-oriented manner, rather than comparing total measured and simulated runoff only. In the present study three approaches of hydrograph separation are compared to decide which sampling frequency is required to capture the spatiotemporal variability of glacier melt, and to draw implications for future studies of streamflow partitioning. Therefore glacier melt contributions to a proglacial stream at the sub-daily, daily, and seasonal scale were estimated using electrical conductivity and oxygen-18 as tracers. The field work was conducted during December 2015 and September 2016 in the glaciated (34%) high-elevation catchment of the Hochjochbach, a small sub-basin (17 km2) of the Oetztaler Ache river in the Austrian Alps, ranging from 2400 to 3500 m a.s.l. in elevation. Hydroclimatological data was provided by an automatic weather station and a streamflow gauging station equipped with a pressure transducer. Water samples of streamflow, glacier melt, and rain were collected throughout the winter period (December to March) and the ablation season (July to September). In the proposed contribution, the experimental setup and preliminary results are described and discussed for the three approaches (sub-daily, daily, seasonal) of three-component hydrograph separations (glacier melt, rain, and groundwater).

Genetic analysis of seasonal runoff based on automatic techniques of hydrometeorological data processing

NASA Astrophysics Data System (ADS)

Kireeva, Maria; Sazonov, Alexey; Rets, Ekaterina; Ezerova, Natalia; Frolova, Natalia; Samsonov, Timofey

2017-04-01

Detection of the rivers' feeding type is a complex and multifactor task. Such partitioning should be based, on the one hand, on the genesis of the feeding water, on the other hand, on its physical path. At the same time it should consider relationship of the feeding type with corresponding phase of the water regime. Due to the above difficulties and complexity of the approach, there are many different variants of separation of flow hydrograph for feeding types. The most common method is extraction of so called basic component which in one way or another reflects groundwater feeding of the river. In this case, the selection most often is based on the principle of local minima or graphic separation of this component. However, in this case neither origin of the water nor corresponding phase of water regime is considered. In this paper, the authors offer a method of complex automated analysis of genetic components of the river's feeding together with the separation of specific phases of the water regime. The objects of the study are medium and large rivers of European Russia having a pronounced spring flood, formed due to melt water, and summer-autumn and winter low water which is periodically interrupted by rain or thaw flooding. The method is based on genetic separation of hydrograph proposed in 1960s years by B. I. Kudelin. This technique is considered for large rivers having hydraulic connection with groundwater horizons during flood. For better detection of floods genesis the analysis involves reanalysis data on temperature and precipitation. Separation is based on the following fundamental graphic-analytical principles: • Ground feeding during the passage of flood peak tends to zero • Beginning of the flood is determined as the exceeding of critical value of low water discharge • Flood periods are determined on the basis of exceeding the critical low-water discharge; they relate to thaw in case of above-zero temperatures • During thaw and rain floods, ground feeding is determined using interpolation of values before and after the flood • Floods during the rise and fall of high water are determined using depletion curves plotting • Groundwater component of runoff is divided into dynamic and static parts. The algorithm of subdivision described was formalized in the form of a program code in Fortran, with the connection of additional modules of R-Studio. The use of two languages allows, on the one hand, to speed up the processing of a large array of daily water discharges, on the other hand, to facilitate visualization and interpretation of results. The algorithm includes the selection of 15 calibration parameters describing the characteristics of each watershed. Verification and calibration of the program was carried out for 20 rivers of European Russia. According to calculations, there is a significant increase in the groundwater flow component in the most part of watershed and an increase in the role of flooding as the phase of the water regime as a whole. This research was supported by Russian Foundation for Basic Research (contract No. 16-35-60080).

Using Chemical Tracers to Estimate Pesticide Mass Discharge in an Agricultural Watershed

NASA Astrophysics Data System (ADS)

Simmons, A. N.; Allen-King, R. M.; Van Biersel, T. P.; Keller, C. K.; Smith, J. L.

2001-12-01

The goal of this research is to use environmental tracers to quantify the contributions of subsurface and surface runoff to predict the mass discharge of non-point source agricultural pollutants to rivers at multiple scales of study. Easily measured chemical tracers, such as electrical conductivity (EC), are used to distinguish ground and surface water contributions to the river system. The study area is the Missouri Flat Creek watershed, a 14,400 ha semi-arid dryland agricultural setting located near Pullman, WA. Ground and surface water samples are collected at approximately two-week intervals from an ephemeral stream and a tile drain located in actively farmed and topographically constrained fields ( ~20 ha), and from seven stream-gaging stations. Surface water discharge is monitored continuously. Samples are routinely analyzed for two pesticides (the insecticide lindane or gamma-hexachlorocyclohexane (HCH) and the herbicide triallate, S-(2,3,3-trichloroallyl) diisopropylthiocarbamate), a nutrient (nitrate), and the tracers EC and silica. Lindane is applied as a seed coating on most spring and fall crops in the region. Observed lindane concentrations in the different hydrologic reservoirs ranged over approximately two orders of magnitude, from typically less than the detection limit ( ~0.005 μ g/L) in most soil pore water and groundwater samples to a weighted mean of 0.25 μ g/L in field (ephemeral stream) surface runoff. A two-component, ground and surface water, hydrograph separation was performed using tile drain and ephemeral stream tracer concentrations from field plots to represent groundwater and surface runoff end-members. The hydrograph separation was used to predict lindane discharge. Reasonable agreement between model and observed lindane discharge timing and trend supports the hypothesis that in-stream pesticide is derived from annual surface runoff. During the high flow winter months, the model predictions are two to five times greater than observed. The differences between the model and observed mass discharges are likely attributable to dilution (from fields to which the chemical was not applied) or attenuation by biological processes. These are the subjects of continued work.

Effects of timber harvesting on the lag time of Caspar Creek watershed

Treesearch

Karen Hardison Sendek

1985-01-01

Abstract - Hydrograph lag time was analyzed to determine changes after road construction and after selective, tractor-yarded logging in a Caspar Creek watershed, Mendocino County, California. The paired watershed technique was used. Hydrograph lag time for each storm was the time separation between the midpoint of precipitation and the time coordinate of the runoff...

A new time-space accounting scheme to predict stream water residence time and hydrograph source components at the watershed scale

Treesearch

Takahiro Sayama; Jeffrey J. McDonnell

2009-01-01

Hydrograph source components and stream water residence time are fundamental behavioral descriptors of watersheds but, as yet, are poorly represented in most rainfall-runoff models. We present a new time-space accounting scheme (T-SAS) to simulate the pre-event and event water fractions, mean residence time, and spatial source of streamflow at the watershed scale. We...

Generalised synthesis of space-time variability in flood response: Dynamics of flood event types

NASA Astrophysics Data System (ADS)

Viglione, Alberto; Battista Chirico, Giovanni; Komma, Jürgen; Woods, Ross; Borga, Marco; Blöschl, Günter

2010-05-01

A analytical framework is used to characterise five flood events of different type in the Kamp area in Austria: one long-rain event, two short-rain events, one rain-on-snow event and one snowmelt event. Specifically, the framework quantifies the contributions of the space-time variability of rainfall/snowmelt, runoff coefficient, hillslope and channel routing to the flood runoff volume and the delay and spread of the resulting hydrograph. The results indicate that the components obtained by the framework clearly reflect the individual processes which characterise the event types. For the short-rain events, temporal, spatial and movement components can all be important in runoff generation and routing, which would be expected because of their local nature in time and, particularly, in space. For the long-rain event, the temporal components tend to be more important for runoff generation, because of the more uniform spatial coverage of rainfall, while for routing the spatial distribution of the produced runoff, which is not uniform, is also important. For the rain-on-snow and snowmelt events, the spatio-temporal variability terms typically do not play much role in runoff generation and the spread of the hydrograph is mainly due to the duration of the event. As an outcome of the framework, a dimensionless response number is proposed that represents the joint effect of runoff coefficient and hydrograph peakedness and captures the absolute magnitudes of the observed flood peaks.

Quantifying space-time dynamics of flood event types

NASA Astrophysics Data System (ADS)

Viglione, Alberto; Chirico, Giovanni Battista; Komma, Jürgen; Woods, Ross; Borga, Marco; Blöschl, Günter

2010-11-01

SummaryA generalised framework of space-time variability in flood response is used to characterise five flood events of different type in the Kamp area in Austria: one long-rain event, two short-rain events, one rain-on-snow event and one snowmelt event. Specifically, the framework quantifies the contributions of the space-time variability of rainfall/snowmelt, runoff coefficient, hillslope and channel routing to the flood runoff volume and the delay and spread of the resulting hydrograph. The results indicate that the components obtained by the framework clearly reflect the individual processes which characterise the event types. For the short-rain events, temporal, spatial and movement components can all be important in runoff generation and routing, which would be expected because of their local nature in time and, particularly, in space. For the long-rain event, the temporal components tend to be more important for runoff generation, because of the more uniform spatial coverage of rainfall, while for routing the spatial distribution of the produced runoff, which is not uniform, is also important. For the rain-on-snow and snowmelt events, the spatio-temporal variability terms typically do not play much role in runoff generation and the spread of the hydrograph is mainly due to the duration of the event. As an outcome of the framework, a dimensionless response number is proposed that represents the joint effect of runoff coefficient and hydrograph peakedness and captures the absolute magnitudes of the observed flood peaks.

Evidence for the Activation of Shallow Preferential Flow Paths in a Tropical Panama Watershed Using Germanium and Silicon

NASA Astrophysics Data System (ADS)

Gardner, Christopher B.; Litt, Guy F.; Lyons, W. Berry; Ogden, Fred L.

2017-10-01

In humid tropical watersheds, the hydrologic flow paths taken by rain event waters and how they interact with groundwater and soil matrix water to form streamflow are poorly understood. Preferential flow paths (PFPs) confound storm infiltration processes, especially in the humid tropics where PFPs are common. This work applies germanium (Ge) and silicon (Si) as natural flow path tracers in conjunction with water stable isotopes and electrical conductivity to examine the rapid delivery of shallow soil water, the activation of PFPs, and event water partitioning in an experimental catchment in central Panama. We employed a three-component mixing model for hydrograph separation using the following end-member waters: (i) base flow (high [Si], low [Ge], and low Ge/Si ratio), (ii) dilute canopy throughfall (low [Si] and low [Ge]), and (iii) shallow (<15 cm) soil matrix water (low [Si], high [Ge], and high Ge/Si ratio). These three end-members bounded all observed Ge/Si streamflow ratios. During small rain events (<˜24 mm), base flow and dilute canopy throughfall components dominated stormflow. During larger precipitation events (>˜35 mm), we detected the third shallow soil water component with an elevated [Ge] and Ge/Si ratio. This component reached its maximum during the hydrograph's receding limb coincident with the maximum event fraction, and increased proportionally to the total storm rainfall exceeding ˜35 mm. Only shallow (<15 cm) soil matrix water exhibited elevated Ge concentrations and high Ge/Si ratios. This third component represents rapidly delivered soil matrix water combined with shallow lateral PFP activation through which event waters interact with soil minerals.

SEPHYDRO: An Integrated Multi-Filter Web-Based Tool for Baseflow Separation

NASA Astrophysics Data System (ADS)

Serban, D.; MacQuarrie, K. T. B.; Popa, A.

2017-12-01

Knowledge of baseflow contributions to streamflow is important for understanding watershed scale hydrology, including groundwater-surface water interactions, impact of geology and landforms on baseflow, estimation of groundwater recharge rates, etc. Baseflow (or hydrograph) separation methods can be used as supporting tools in many areas of environmental research, such as the assessment of the impact of agricultural practices, urbanization and climate change on surface water and groundwater. Over the past few decades various digital filtering and graphically-based methods have been developed in an attempt to improve the assessment of the dynamics of the various sources of streamflow (e.g. groundwater, surface runoff, subsurface flow); however, these methods are not available under an integrated platform and, individually, often require significant effort for implementation. Here we introduce SEPHYDRO, an open access, customizable web-based tool, which integrates 11 algorithms allowing for separation of streamflow hydrographs. The streamlined interface incorporates a reference guide as well as additional information that allows users to import their own data, customize the algorithms, and compare, visualise and export results. The tool includes one-, two- and three-parameter digital filters as well as graphical separation methods and has been successfully applied in Atlantic Canada, in studies dealing with nutrient loading to fresh water and coastal water ecosystems. Future developments include integration of additional separation algorithms as well as incorporation of geochemical separation methods. SEPHYDRO has been developed through a collaborative research effort between the Canadian Rivers Institute, University of New Brunswick (Fredericton, New Brunswick, Canada), Agriculture and Agri-Food Canada and Environment and Climate Change Canada and is currently available at http://canadianriversinstitute.com/tool/

Thermographic Data Analyses for Karst Watersheds

NASA Technical Reports Server (NTRS)

Campbell, C. Warren; McCaleb, Rebecca C. (Technical Monitor)

2001-01-01

Aerial thermography is an emerging technology unsurpassed for locating groundwater discharges. Thermography can be used to locate submerged discharges that are extremely difficult to find by other means. In two large projects, thermography was used to identify almost every significant spring at sites underlain by karst aquifers. This technology effectively converts Brown's Type 5 topology to types 1 or 2 (all discharges known), which has a significant impact on dye tracing. At a north Alabama site, springs located by thermography quadrupled the known groundwater discharge in and around the site. For submerged discharges, thermographic temperatures can be measured down the center of the groundwater plume that rises to the surface in the winter. Using the Cornell Mixing (CORMIX) model, flow rate for one submerged spring was estimated. Once identified, estimates of spring recharge area were desired. The size of the area of recharge was estimated by hydrograph separation of flow data from nearby, unregulated surface streams. Monthly recharge estimates were also made and used to show that in north Alabama the mean annual recharge/discharge occurs during May and December. Spring flow measurements for the same county of north Alabama were averaged to obtain mean flows. Then measurements for May only, were averaged. The two averages usually agreed to within 20 percent. This provides evidence that hydrograph separation determinations of recharge are valid.

Quantifying components of the hydrologic cycle in Virginia using chemical hydrograph separation and multiple regression analysis

USGS Publications Warehouse

Sanford, Ward E.; Nelms, David L.; Pope, Jason P.; Selnick, David L.

2012-01-01

This study by the U.S. Geological Survey, prepared in cooperation with the Virginia Department of Environmental Quality, quantifies the components of the hydrologic cycle across the Commonwealth of Virginia. Long-term, mean fluxes were calculated for precipitation, surface runoff, infiltration, total evapotranspiration (ET), riparian ET, recharge, base flow (or groundwater discharge) and net total outflow. Fluxes of these components were first estimated on a number of real-time-gaged watersheds across Virginia. Specific conductance was used to distinguish and separate surface runoff from base flow. Specific-conductance data were collected every 15 minutes at 75 real-time gages for approximately 18 months between March 2007 and August 2008. Precipitation was estimated for 1971–2000 using PRISM climate data. Precipitation and temperature from the PRISM data were used to develop a regression-based relation to estimate total ET. The proportion of watershed precipitation that becomes surface runoff was related to physiographic province and rock type in a runoff regression equation. Component flux estimates from the watersheds were transferred to flux estimates for counties and independent cities using the ET and runoff regression equations. Only 48 of the 75 watersheds yielded sufficient data, and data from these 48 were used in the final runoff regression equation. The base-flow proportion for the 48 watersheds averaged 72 percent using specific conductance, a value that was substantially higher than the 61 percent average calculated using a graphical-separation technique (the USGS program PART). Final results for the study are presented as component flux estimates for all counties and independent cities in Virginia.

Evaluating Snowmelt Runoff Processes Using Stable Isotopes in a Permafrost Hillslope

NASA Astrophysics Data System (ADS)

Carey, S. K.

2004-05-01

Conceptual understanding of runoff generation in permafrost regions have been derived primarily from hydrometric information, with isotope and hydrochemical data having only limited application in delineating sources and pathways of water. Furthermore, when stable isotope data are used to infer runoff processes, it often provides conflicting results from hydrometric measurements. In a small subarctic alpine catchment within the Wolf Creek Research Basin, Yukon, Canada, experiments were conducted during the melt period of 2002 and 2003 to trace the stable isotopic signature (d18O) of meltwater from a melting snowpack into permafrost soils and laterally to the stream to identify runoff processes and evaluate sources of error for traditional hydrograph separation studies in snowmelt-dominated permafrost basins. Isotopic variability in the snowpack was recorded at 0.1 m depth intervals during the melt period and compared with the meltwater isotopic signature at the snowpack base collected in lysimeters. Throughout the melt period in both years, there was an isotopic enrichment of meltwater as the season progressed. A downslope transect of wells and piezometers were used to evaluate the influence of infiltrating meltwater and thawing ground on the subsurface d18O signature. As melt began, meltwater infiltrated the frozen porous organic layer, leading to liquid water saturation in the unsaturated pore spaces. Water sampled during this initial melt stage show soil water d18O mirroring that of the meltwater signal. As the melt season progressed, frozen soil began to melt, mixing enriched pre-melt soil water with meltwater. This mixing increased the overall value of d18O obtained from the soil, which gradually increased as thaw progressed. At the end of snowmelt, soil water had a d18O value similar to values from the previous fall, suggesting that much of the initial snowmelt water had been flushed from the hillslope. Results from the hillslope scale are compared with two-component hydrograph separations and sources of error are discussed.

Contribution of directly connected and isolated impervious areas to urban drainage network hydrographs

NASA Astrophysics Data System (ADS)

Seo, Y.; Choi, N.-J.; Schmidt, A. R.

2013-05-01

This paper addresses the mass balance error observed in runoff hydrographs in urban watersheds by introducing assumptions regarding the contribution of infiltrated rainfall from pervious areas and isolated impervious area (IIA) to the runoff hydrograph. Rainfall infiltrating into pervious areas has been assumed not to contribute to the runoff hydrograph until Hortonian excess rainfall occurs. However, mass balance analysis in an urban watershed indicates that rainfall infiltrated to pervious areas can contribute to direct runoff hydrograph, thereby offering an explanation for the long hydrograph tail commonly observed in runoff from urban storm sewers. In this study, a hydrologic analysis based on the width function is introduced, with two types of width functions obtained from both pervious and impervious areas, respectively. The width function can be regarded as the direct interpretation of the network response. These two width functions are derived to obtain distinct response functions for directly connected impervious areas (DCIA), IIA, and pervious areas. The results show significant improvement in the estimation of runoff hydrographs and suggest the need to consider the flow contribution from pervious areas to the runoff hydrograph. It also implies that additional contribution from flow paths through joints and cracks in sewer pipes needs to be taken into account to improve the estimation of runoff hydrographs in urban catchments.

Contribution of directly connected and isolated impervious areas to urban drainage network hydrographs

NASA Astrophysics Data System (ADS)

Seo, Y.; Choi, N.-J.; Schmidt, A. R.

2013-09-01

This paper addresses the mass balance error observed in runoff hydrographs in urban watersheds by introducing assumptions regarding the contribution of infiltrated rainfall from pervious areas and isolated impervious area (IIA) to the runoff hydrograph. Rainfall infiltrating into pervious areas has been assumed not to contribute to the runoff hydrograph until Hortonian excess rainfall occurs. However, mass balance analysis in an urban watershed indicates that rainfall infiltrated to pervious areas can contribute directly to the runoff hydrograph, thereby offering an explanation for the long hydrograph tail commonly observed in runoff from urban storm sewers. In this study, a hydrologic analysis based on the width function is introduced, with two types of width functions obtained from both pervious and impervious areas, respectively. The width function can be regarded as the direct interpretation of the network response. These two width functions are derived to obtain distinct response functions for directly connected impervious areas (DCIA), IIA, and pervious areas. The results show significant improvement in the estimation of runoff hydrographs and suggest the need to consider the flow contribution from pervious areas to the runoff hydrograph. It also implies that additional contribution from flow paths through joints and cracks in sewer pipes needs to be taken into account to improve the estimation of runoff hydrographs in urban catchments.

Characterizing hydrology and the importance of ground-water discharge in natural and constructed wetlands

USGS Publications Warehouse

Hunt, Randall J.; Walker, John F.; Krabbenhoft, David P.

1999-01-01

Although considered the most important component for the establishment and persistence of wetlands, hydrology has been hard to characterize and linkages between hydrology and other environmental conditions are often poorly understood. In this work, methods for characterizing a wetland’s hydrology from hydrographs were developed, and the importance of ground water to the physical and geochemical conditions in the root zone was investigated. Detailed sampling of nearly continuous hydrographs showed that sites with greater ground-water discharge had higher water tables and more stable hydrographs. Subsampling of the continuous hydrograph failed to characterize the sites correctly, even though the wetland complex is located in a strong regional ground-water-discharge area. By comparing soil-moisture-potential measurements to the water-table hydrograph at one site, we noted that the amount of root-zone saturation was not necessarily driven by the water-table hydrograph but can be a result of other soil parameters (i.e., soil texture and associated capillary fringe). Ground-water discharge was not a significant determinant of maximum or average temperatures in the root zone. High ground-water discharge was associated with earliest date of thaw and shortest period of time that the root zone was frozen, however. Finally, the direction and magnitude of shallow ground-water flow was found to affect the migration and importance of a geochemical species. Areas of higher ground-water discharge had less downward penetration of CO2 generated in the root zone. In contrast, biotically derived CO2 was able to penetrate the deeper ground-water system in areas of ground-water recharge. Although ground-water flows are difficult to characterize, understanding these components is critical to the success of wetland restoration and creation efforts.

HYDRORECESSION: A toolbox for streamflow recession analysis

NASA Astrophysics Data System (ADS)

Arciniega, S.

2015-12-01

Streamflow recession curves are hydrological signatures allowing to study the relationship between groundwater storage and baseflow and/or low flows at the catchment scale. Recent studies have showed that streamflow recession analysis can be quite sensitive to the combination of different models, extraction techniques and parameter estimation methods. In order to better characterize streamflow recession curves, new methodologies combining multiple approaches have been recommended. The HYDRORECESSION toolbox, presented here, is a Matlab graphical user interface developed to analyse streamflow recession time series with the support of different tools allowing to parameterize linear and nonlinear storage-outflow relationships through four of the most useful recession models (Maillet, Boussinesq, Coutagne and Wittenberg). The toolbox includes four parameter-fitting techniques (linear regression, lower envelope, data binning and mean squared error) and three different methods to extract hydrograph recessions segments (Vogel, Brutsaert and Aksoy). In addition, the toolbox has a module that separates the baseflow component from the observed hydrograph using the inverse reservoir algorithm. Potential applications provided by HYDRORECESSION include model parameter analysis, hydrological regionalization and classification, baseflow index estimates, catchment-scale recharge and low-flows modelling, among others. HYDRORECESSION is freely available for non-commercial and academic purposes.

Lagtime relations for urban streams in Georgia

USGS Publications Warehouse

Inman, Ernest J.

2000-01-01

Urban flood hydrographs are needed for the design of many highway drainage structures, embankments, and entrances to detention ponds. The three components that are needed to simulate urban flood hydrographs at ungaged sites are the design flood, the dimensionless hydrograph, and lagtime. The design flood and the dimensionless hydrograph have been presented in earlier studies for urban streams in Georgia. The objective of this study was to develop equations for estimating lagtime for urban streams in Georgia. Lagtimes were computed for 329 floods at 69 urban gaging stations in 11 cities in Georgia. These data were used to compute an average lagtime for each gaging station. Multiple regression analysis was then used to define relations between lagtime and certain physical basin characteristics, of which drainage area, slope, and impervious area were found to be significant. A qualitative variable was used to account for a geographical bias in flood-frequency region 4, a small area of southwestern Georgia. Information from this report can be used to simulate a flood hydrograph using a dimensionless hydrograph, the design flood, and the lagtime obtained from regression equations for any urban site with less than a 25-square-mile drainage area in Georgia.

Spatial Connectivity and Temporal Response of Variable Source Areas (VSAs): Implications for Catchment Scale Water and Solute Mixing

NASA Astrophysics Data System (ADS)

Inamdar, S.; Mitchell, M.; McDonnell, J.; McGlynn, B.; Shanley, J.

2001-05-01

The significance of variable source areas (VSAs) in storm runoff generation and as loci for mixing of event and pre-event waters has long been recognized. Recent research suggests that VSAs may also play an important role in regulating the export of C and N solutes from catchments. We hypothesize that the spatial distribution of VSAs in the catchment and their connectedness with the stream network is a first order control on the temporal dynamics and expression of water and solutes from the catchment. We examined two contrasting scenarios of VSA distribution: (1) VSAs located lower in the catchment and well connected to the stream network, versus, (2) discrete VSAs located in the upper portions of the catchment and disconnected from the stream network. We evaluated the potential impact of these scenarios on: (a) the timing and peak of event water contributions, and (b) the timing and peak of solute signatures. We hypothesized that if VSAs are well connected to the stream network (Scenario 1), then event water contributions would be distinct and would predominate early on during the rising limb of the hydrograph of stream discharge. In contrast, if VSAs are isolated and disconnected (Scenario 2), then event water contributions would be damped and delayed and possibly continue to be observed through hydrograph recession. We believe solutes such as dissolved organic carbon (DOC), which are primarily flushed from near surface soil horizons, will follow an event water trajectory. We tested these hypotheses for a 135 ha forested headwater catchment in the Adirondack Mountains of New York. Detailed storm runoff and solute data for the catchment are available since 1994. A two-component separation model using base cations (Na, Mg, Ca, and K) was used to partition stormflow discharge into pre-event and event components. Event water contributions were small on the rising limb of the hydrograph, reached their maximum just after the discharge peak, and continued through the recession limb, hours after cessation of rainfall. DOC concentrations followed a temporal pattern very similar to the event water contributions, with a peak at or just after peak discharge. In contrast, the timing of the nitrate peak appeared to vary seasonally, indicating availability of nitrate in the soil profile as a controlling mechanism. Nitrate peaks appeared to match DOC and event water peaks for spring events, but occurred much earlier on the rising limb of the discharge hydrograph during fall events. Results from this study appear to confirm our hypothesis for scenario 2, where the disconnected nature of VSAs is displayed by the delayed expression of event water and DOC. These results also confirm our hypothesis that the spatial distribution of VSAs will have a greater impact on the temporal expression of solutes that are available in near surface soil horizons, as opposed to solutes whose availability in the near surface soil varies with seasons. These hypotheses are also being evaluated for a forested subcatchment of the Sleepers River watershed in Vermont.

Hillslope versus riparian zone runoff contributions in headwater catchments: A multi-watershed comparison

NASA Astrophysics Data System (ADS)

McGlynn, B. L.; McGlynn, B. L.; McDonnell, J. J.; Hooper, R. P.; Shanley, J. B.; Hjerdt, K. N.; Hjerdt, K. N.

2001-12-01

It is often assumed that hillslope and riparian areas constitute the two most important and identifiable landscape units contributing to catchment runoff in upland humid catchments. Nevertheless, the relative amount and timing of hillslope versus riparian contributions to stormflow are poorly understood across different watersheds. We quantified the contributions of hillslopes and riparian zones to stormflow using physical, chemical, and isotopic techniques across 3 diverse ({ ~}15 ha) headwater catchments: a highly responsive steep wet watershed (Maimai, New Zealand), a moderately steep snowmelt dominated watershed (Sleepers, River, VT), and at a highly seasonal relatively low relief watershed (Panola Mt., Georgia). We monitored catchment runoff, internal hydrological response, and isotopic and solute dynamics for discrete riparian and hillslope zones within each catchment. Monitored catchment positions, including hillslope trenches at Maimai and Panola, were used to characterize directly, the hydrologic response and source water signatures for hillslope zones and riparian zones. We also examined the spatial and temporal source components of catchment stormflow using 3-component mass balance hydrograph separation techniques. At Maimai, NZ we found that hillslope runoff comprised 47-55% of total runoff during a 70 mm event. Despite the large amount of subsurface hillslope runoff in total catchment stormflow, riparian and channel zones accounted for 28% out of 29% of the total new water measured catchment runoff. Riparian water dominated the storm hydrograph composition early in the event, although hillslope water reached the catchment outlet soon after hillslope water tables were developed. Preliminary results for Sleepers River, VT and Panola Mountain, GA indicate that the timing and relative proportion of hillslope water in catchment runoff is later and smaller than at Maimai. Our multi-catchment comparison suggests that the ratio of the riparian reservoir to the hillslope reservoir/stormflow flux partially controls the relative contributions of hillslope and riparian zones to catchment runoff and solute dynamics.

Recharge Area, Base-Flow and Quick-Flow Discharge Rates and Ages, and General Water Quality of Big Spring in Carter County, Missouri, 2000-04

USGS Publications Warehouse

Imes, Jeffrey L.; Plummer, Niel; Kleeschulte, Michael J.; Schumacher, John G.

2007-01-01

Exploration for lead deposits has occurred in a mature karst area of southeast Missouri that is highly valued for its scenic beauty and recreational opportunities. The area contains the two largest springs in Missouri (Big Spring and Greer Spring), both of which flow into federally designated scenic rivers. Concerns about potential mining effects on the area ground water and aquatic biota prompted an investigation of Big Spring. Water-level measurements made during 2000 helped define the recharge area of Big Spring, Greer Spring, Mammoth Spring, and Boze Mill Spring. The data infer two distinct potentiometric surfaces. The shallow potentiometric surface, where the depth-to-water is less than about 250 feet, tends to mimic topographic features and is strongly controlled by streams. The deep potentiometric surface, where the depth-to-water is greater than about 250 feet represents ground-water hydraulic heads within the more mature karst areas. A highly permeable zone extends about 20 mile west of Big Spring toward the upper Hurricane Creek Basin. Deeper flowing water in the Big Spring recharge area is directed toward this permeable zone. The estimated sizes of the spring recharge areas are 426 square miles for Big Spring, 352 square miles for Greer Spring, 290 square miles for Mammoth Spring, and 54 square miles for Boze Mill Spring. A discharge accumulation curve using Big Spring daily mean discharge data shows no substantial change in the discharge pattern of Big Spring during the period of record (water years 1922 through 2004). The extended periods when the spring flow deviated from the trend line can be attributed to prolonged departures from normal precipitation. The maximum possible instantaneous flow from Big Spring has not been adequately defined because of backwater effects from the Current River during high-flow conditions. Physical constraints within the spring conduit system may restrict its maximum flow. The largest discharge measured at Big Spring during the period of record (water years 1922 through 2004) was 1,170 cubic feet per second on December 7, 1982. The daily mean water temperature of Big Spring was monitored during water years 2001 through 2004 and showed little variability, ranging from 13 to 15? C (degree Celsius). Water temperatures generally vary less than 1? C throughout the year. The warmest temperatures occur during October and November and decrease until April, indicating Big Spring water temperature does show a slight seasonal variation. The use of the traditional hydrograph separation program HYSEP to determine the base flow and quick flow or runoff components at Big Spring failed to yield base-flow and quick-flow discharge curves that matched observations of spring characteristics. Big Spring discharge data were used in combination with specific conductance data to develop an improved hydrograph separation method for the spring. The estimated annual mean quick flow ranged from 15 to 48 cubic feet per second for the HYSEP analysis and ranged from 26 to 154 cubic feet per second for the discharge and specific conductance method for water years 2001 to 2004. Using the discharge and specific conductance method, the estimated base-flow component rises abruptly as the spring hydrograph rises, attains a peak value on the same day as the discharge peak, and then declines abruptly from its peak value. Several days later, base flow begins to increase again at an approximately linear trend, coinciding with the time at which the percentage of quick flow has reached a maximum after each recharge-induced discharge peak. The interval between the discharge peak and the peak in percentage quick flow ranges from 8 to 11 days for seven hydrograph peaks, consistent with quick-flow traveltime estimates by dye-trace tests from the mature karst Hurricane Creek Basin in the central part of the recharge area. Concentrations of environmental tracers chlorofluorocarbons (CFCs: CFC-11, CFC-12, CFC-113)

Hydrograph matching method for measuring model performance

NASA Astrophysics Data System (ADS)

Ewen, John

2011-09-01

SummaryDespite all the progress made over the years on developing automatic methods for analysing hydrographs and measuring the performance of rainfall-runoff models, automatic methods cannot yet match the power and flexibility of the human eye and brain. Very simple approaches are therefore being developed that mimic the way hydrologists inspect and interpret hydrographs, including the way that patterns are recognised, links are made by eye, and hydrological responses and errors are studied and remembered. In this paper, a dynamic programming algorithm originally designed for use in data mining is customised for use with hydrographs. It generates sets of "rays" that are analogous to the visual links made by the hydrologist's eye when linking features or times in one hydrograph to the corresponding features or times in another hydrograph. One outcome from this work is a new family of performance measures called "visual" performance measures. These can measure differences in amplitude and timing, including the timing errors between simulated and observed hydrographs in model calibration. To demonstrate this, two visual performance measures, one based on the Nash-Sutcliffe Efficiency and the other on the mean absolute error, are used in a total of 34 split-sample calibration-validation tests for two rainfall-runoff models applied to the Hodder catchment, northwest England. The customised algorithm, called the Hydrograph Matching Algorithm, is very simple to apply; it is given in a few lines of pseudocode.

Effect of Hydrograph Characteristics on Vertical Grain Sorting in Gravel Bed Rivers

NASA Astrophysics Data System (ADS)

Hassan, M. A.; Parker, G.; Egozi, R.

2005-12-01

This study focuses on the formation of armour layers over a range of hydrologic conditions that includes two limiting cases; a relatively flat hydrograph that represents conditions produced by continuous snowmelt and a sharply peaked hydrograph that represents conditions associated with flash floods. To achieve our objective we analyzed field evidence, conducted flume experiments and performed numerical simulations. Sediment supply appears to be a first-order control on bed surface armouring, while the shape of the hydrograph plays a secondary role. All constant hydrograph experiments developed a well-armored structured surface while short asymmetrical hydrographs did not show substantial vertical sorting. All symmetrical hydrographs show some degree of sorting, and the sorting tended to become more pronounced with longer duration. Using the numerical framework of Parker, modified Powell, et al. and Wilcock and Crowe, we were able to achieve similar results.

Consistency of patterns in concentration‐discharge plots

USGS Publications Warehouse

Chanat, Jeffrey G.; Rice, Karen C.; Hornberger, George M.

2002-01-01

Concentration‐discharge (c‐Q) plots have been used to infer how flow components such as event water, soil water, and groundwater mix to produce the observed episodic hydrochemical response of small catchments. Because c‐Q plots are based only on observed streamflow and solute concentration, their interpretation requires assumptions about the relative volume, hydrograph timing, and solute concentration of the streamflow end‐members. Evans and Davies [1998] present a taxonomy of c‐Q loops resulting from three‐component conservative mixing. Their analysis, based on a fixed template of end‐member hydrograph volume, timing, and concentration, suggests a unique relationship between c‐Q loop form and the rank order of end‐member concentrations. Many catchments exhibit variability in component contributions to storm flow in response to antecedent conditions or rainfall characteristics, but the effects of such variation on c‐Q relationships have not been studied systematically. Starting with a “baseline” condition similar to that assumed by Evans and Davies [1998], we use a simple computer model to characterize the variability in c‐Q plot patterns resulting from variation in end‐member volume, timing, and solute concentration. Variability in these three factors can result in more than one c‐Q loop shape for a given rank order of end‐member solute concentrations. The number of resulting hysteresis patterns and their relative frequency depends on the rank order of solute concentrations and on their separation in absolute value. In ambiguous cases the c‐Q loop shape is determined by the relative “prominence” of the event water versus soil water components. This “prominence” is broadly defined as a capacity to influence the total streamflow concentration and may result from a combination of end‐member volume, timing, or concentration. The modeling results indicate that plausible hydrological variability in field situations can confound the interpretation of c‐Q plots, even when fundamental end‐member mixing assumptions are satisfied.

Equations for estimating synthetic unit-hydrograph parameter values for small watersheds in Lake County, Illinois

USGS Publications Warehouse

Melching, C.S.; Marquardt, J.S.

1997-01-01

Design hydrographs computed from design storms, simple models of abstractions (interception, depression storage, and infiltration), and synthetic unit hydrographs provide vital information for stormwater, flood-plain, and water-resources management throughout the United States. Rainfall and runoff data for small watersheds in Lake County collected between 1990 and 1995 were studied to develop equations for estimation of synthetic unit-hydrograph parameters on the basis of watershed and storm characteristics. The synthetic unit-hydrograph parameters of interest were the time of concentration (TC) and watershed-storage coefficient (R) for the Clark unit-hydrograph method, the unit-graph lag (UL) for the Soil Conservation Service (now known as the Natural Resources Conservation Service) dimensionless unit hydrograph, and the hydrograph-time lag (TL) for the linear-reservoir method for unit-hydrograph estimation. Data from 66 storms with effective-precipitation depths greater than 0.4 inches on 9 small watersheds (areas between 0.06 and 37 square miles (mi2)) were utilized to develop the estimation equations, and data from 11 storms on 8 of these watersheds were utilized to verify (test) the estimation equations. The synthetic unit-hydrograph parameters were determined by calibration using the U.S. Army Corps of Engineers Flood Hydrograph Package HEC-1 (TC, R, and UL) or by manual analysis of the rainfall and run-off data (TL). The relation between synthetic unit-hydrograph parameters, and watershed and storm characteristics was determined by multiple linear regression of the logarithms of the parameters and characteristics. Separate sets of equations were developed with watershed area and main channel length as the starting parameters. Percentage of impervious cover, main channel slope, and depth of effective precipitation also were identified as important characteristics for estimation of synthetic unit-hydrograph parameters. The estimation equations utilizing area had multiple correlation coefficients of 0.873, 0.961, 0.968, and 0.963 for TC, R, UL, and TL, respectively, and the estimation equations utilizing main channel length had multiple correlation coefficients of 0.845, 0.957, 0.961, and 0.963 for TC, R, UL, and TL, respectively. Simulation of the measured hydrographs for the verification storms utilizing TC and R obtained from the estimation equations yielded good results without calibration. The peak discharge for 8 of the 11 storms was estimated within 25 percent and the time-to-peak discharge for 10 of the 11 storms was estimated within 20 percent. Thus, application of the estimation equations to determine synthetic unit-hydrograph parameters for design-storm simulation may result in reliable design hydrographs; as long as the physical characteristics of the watersheds under consideration are within the range of those for the watersheds in this study (area: 0.06-37 mi2, main channel length: 0.33-16.6 miles, main channel slope: 3.13-55.3 feet per mile, and percentage of impervious cover: 7.32-40.6 percent). The estimation equations are most reliable when applied to watersheds with areas less than 25 mi2.

Snowmelt hydrograph interpretation: Revealing watershed scale hydrologic characteristics of the Yellowstone volcanic plateau

USGS Publications Warehouse

Payton, Gardner W.; Susong, D.D.; Kip, Solomon D.; Heasler, H.

2010-01-01

Snowmelt hydrograph analysis and groundwater age dates of cool water springs on the Yellowstone volcanic plateau provide evidence of high volumes of groundwater circulation in watersheds comprised of quaternary Yellowstone volcanics. Ratios of maximum to minimum mean daily discharge and average recession indices are calculated for watersheds within and surrounding the Yellowstone volcanic plateau. A model for snowmelt recession is used to separate groundwater discharge from overland runoff, and compare groundwater systems. Hydrograph signal interpretation is corroborated with chlorofluorocarbon (CFC) and tritium concentrations in cool water springs on the Yellowstone volcanic plateau. Hydrograph parameters show a spatial pattern correlated with watershed geology. Watersheds comprised dominantly of quaternary Yellowstone volcanics are characterized by slow streamflow recession, low maximum to minimum flow ratios. Cool springs sampled within the Park contain CFC's and tritium and have apparent CFC age dates that range from about 50 years to modern. Watersheds comprised of quaternary Yellowstone volcanics have a large volume of active groundwater circulation. A large, advecting groundwater field would be the dominant mechanism for mass and energy transport in the shallow crust of the Yellowstone volcanic plateau, and thus control the Yellowstone hydrothermal system. ?? 2009 Elsevier B.V.

Isotopic tracing of the outflow during artificial rain-on-snow event

NASA Astrophysics Data System (ADS)

Juras, Roman; Pavlásek, Jirka; Vitvar, Tomáš; Šanda, Martin; Holub, Jirka; Jankovec, Jakub; Linda, Miloslav

2016-10-01

The frequency of rain-on-snow (ROS) occurrence is increasing and this natural phenomenon is beginning to play an important role in temperate climate regions. Present knowledge of outflow generation mechanisms and rainwater dynamics during ROS is still insufficient. The study introduces a combined method of artificial ROS, isotopic tracing and energy balance to partition the event rainwater and the pre-event non-rainwater in the outflow. A rainfall simulator and water enriched with deuterium were used for identifying event rainwater and pre-event non-rainwater during an ROS event. The ROS experiment was conducted in the Krkonoše Mountains in the Czech Republic. An experimental snow block consisting of ripe and isothermal snow was sprayed with deuterium enriched water. The outflow from the snowpack was continuously monitored to gain quantitative and qualitative information about outflow water. The isotopic deuterium content was further analysed from the samples by means of laser spectroscopy in order to separate the hydrograph components. The deuterium content was also analysed from the snow samples gathered before and after the experiment to identify the retention of event rainwater in the snowpack. Isotopic hydrograph separation revealed that although high rain intensity was applied, the event rainwater represented one half (52.7%) of the total outflow volume. The ripe snowpack retained about one third of the rainwater input (33.6%). Significant changes in the outflowing water quality can therefore be expected during ROS events. This experiment also shows that rainwater during ROS firstly pushes-out the non-rainwater and then contributes to the outflow. These results show that the presented technique allows us to gain sufficient information about rainwater dynamics during ROS.

An assessment of the tracer-based approach to quantifying groundwater contributions to streamflow

NASA Astrophysics Data System (ADS)

Jones, J. P.; Sudicky, E. A.; Brookfield, A. E.; Park, Y.-J.

2006-02-01

The use of conservative geochemical and isotopic tracers along with mass balance equations to determine the pre-event groundwater contributions to streamflow during a rainfall event is widely used for hydrograph separation; however, aspects related to the influence of surface and subsurface mixing processes on the estimates of the pre-event contribution remain poorly understood. Moreover, the lack of a precise definition of "pre-event" versus "event" contributions on the one hand and "old" versus "new" water components on the other hand has seemingly led to confusion within the hydrologic community about the role of Darcian-based groundwater flow during a storm event. In this work, a fully integrated surface and subsurface flow and solute transport model is used to analyze flow system dynamics during a storm event, concomitantly with advective-dispersive tracer transport, and to investigate the role of hydrodynamic mixing processes on the estimates of the pre-event component. A number of numerical experiments are presented, including an analysis of a controlled rainfall-runoff experiment, that compare the computed Darcian-based groundwater fluxes contributing to streamflow during a rainfall event with estimates of these contributions based on a tracer-based separation. It is shown that hydrodynamic mixing processes can dramatically influence estimates of the pre-event water contribution estimated by a tracer-based separation. Specifically, it is demonstrated that the actual amount of bulk flowing groundwater contributing to streamflow may be much smaller than the quantity indirectly estimated from a separation based on tracer mass balances, even if the mixing processes are weak.

Water Resources of the Basin and Range Carbonate-Rock Aquifer System, White Pine County, Nevada, and Adjacent Areas in Nevada and Utah

USGS Publications Warehouse

Welch, Alan H.; Bright, Daniel J.; Knochenmus, Lari A.

2008-01-01

INTRODUCTION This report summarizes results of a water-resources study for White Pine County, Nevada, and adjacent areas in east-central Nevada and western Utah. The Basin and Range carbonate-rock aquifer system (BARCAS) study was initiated in December 2004 through Federal legislation (Section 301(e) of the Lincoln County Conservation, Recreation, and Development Act of 2004; PL108-424) directing the Secretary of the Interior to complete a water-resources study through the U.S. Geological Survey, Desert Research Institute, and State of Utah. The study was designed as a regional water-resource assessment, with particular emphasis on summarizing the hydrogeologic framework and hydrologic processes that influence ground-water resources. The study area includes 13 hydrographic areas that cover most of White Pine County; in this report however, results for the northern and central parts of Little Smoky Valley were combined and presented as one hydrographic area. Hydrographic areas are the basic geographic units used by the State of Nevada and Utah and local agencies for water-resource planning and management, and are commonly defined on the basis of surface-water drainage areas. Hydrographic areas were further divided into subbasins that are separated by areas where bedrock is at or near the land surface. Subbasins are the subdivisions used in this study for estimating recharge, discharge, and water budget. Hydrographic areas are the subdivision used for reporting summed and tabulated subbasin estimates.

Water Resources of the Basin and Range Carbonate-Rock Aquifer System, White Pine County, Nevada, and Adjacent Areas in Nevada and Utah - Draft Report

USGS Publications Warehouse

Welch, Alan H.; Bright, Daniel J.

2007-01-01

Summary of Major Findings This report summarizes results of a water-resources study for White Pine County, Nevada, and adjacent areas in east-central Nevada and western Utah. The Basin and Range carbonate-rock aquifer system (BARCAS) study was initiated in December 2004 through Federal legislation (Section 131 of the Lincoln County Conservation, Recreation, and Development Act of 2004) directing the Secretary of the Interior to complete a water-resources study through the U.S. Geological Survey, Desert Research Institute, and State of Utah. The study was designed as a regional water-resource assessment, with particular emphasis on summarizing the hydrogeologic framework and hydrologic processes that influence ground-water resources. The study area includes 13 hydrographic areas that cover most of White Pine County; in this report however, results for the northern and central parts of Little Smoky Valley were combined and presented as one hydrographic area. Hydrographic areas are the basic geographic units used by the State of Nevada and Utah and local agencies for water-resource planning and management, and are commonly defined on the basis of surface-water drainage areas. Hydrographic areas were further divided into subbasins that are separated by areas where bedrock is at or near the land surface. Subbasins represent subdivisions used in this study for estimating recharge, discharge, and water budget. Hydrographic areas represent the subdivision used for reporting summed and tabulated subbasin estimates.

Precipitation induced stream flow: An event based chemical and isotopic study of a small stream in the Great Plains region of the USA

USGS Publications Warehouse

Machavaram, M.V.; Whittemore, Donald O.; Conrad, M.E.; Miller, N.L.

2006-01-01

A small stream in the Great Plains of USA was sampled to understand the streamflow components following intense precipitation and the influence of water storage structures in the drainage basin. Precipitation, stream, ponds, ground-water and soil moisture were sampled for determination of isotopic (D, 18O) and chemical (Cl, SO4) composition before and after two intense rain events. Following the first storm event, flow at the downstream locations was generated primarily through shallow subsurface flow and runoff whereas in the headwaters region - where a pond is located in the stream channel - shallow ground-water and pond outflow contributed to the flow. The distinct isotopic signatures of precipitation and the evaporated pond water allowed separation of the event water from the other sources that contributed to the flow. Similarly, variations in the Cl and SO4 concentrations helped identify the relative contributions of ground-water and soil moisture to the streamflow. The relationship between deuterium excess and Cl or SO4 content reveals that the early contributions from a rain event to streamflow depend upon the antecedent climatic conditions and the position along the stream channel within the watershed. The design of this study, in which data from several locations within a watershed were collected, shows that in small streams changes in relative contributions from ground water and soil moisture complicate hydrograph separation, with surface-water bodies providing additional complexity. It also demonstrates the usefulness of combined chemical and isotopic methods in hydrologic investigations, especially the utility of the deuterium excess parameter in quantifying the relative contributions of various source components to the stream flow. ?? 2006 Elsevier B.V. All rights reserved.

An initial-abstraction, constant-loss model for unit hydrograph modeling for applicable watersheds in Texas

USGS Publications Warehouse

Asquith, William H.; Roussel, Meghan C.

2007-01-01

Estimation of representative hydrographs from design storms, which are known as design hydrographs, provides for cost-effective, riskmitigated design of drainage structures such as bridges, culverts, roadways, and other infrastructure. During 2001?07, the U.S. Geological Survey (USGS), in cooperation with the Texas Department of Transportation, investigated runoff hydrographs, design storms, unit hydrographs,and watershed-loss models to enhance design hydrograph estimation in Texas. Design hydrographs ideally should mimic the general volume, peak, and shape of observed runoff hydrographs. Design hydrographs commonly are estimated in part by unit hydrographs. A unit hydrograph is defined as the runoff hydrograph that results from a unit pulse of excess rainfall uniformly distributed over the watershed at a constant rate for a specific duration. A time-distributed, watershed-loss model is required for modeling by unit hydrographs. This report develops a specific time-distributed, watershed-loss model known as an initial-abstraction, constant-loss model. For this watershed-loss model, a watershed is conceptualized to have the capacity to store or abstract an absolute depth of rainfall at and near the beginning of a storm. Depths of total rainfall less than this initial abstraction do not produce runoff. The watershed also is conceptualized to have the capacity to remove rainfall at a constant rate (loss) after the initial abstraction is satisfied. Additional rainfall inputs after the initial abstraction is satisfied contribute to runoff if the rainfall rate (intensity) is larger than the constant loss. The initial abstraction, constant-loss model thus is a two-parameter model. The initial-abstraction, constant-loss model is investigated through detailed computational and statistical analysis of observed rainfall and runoff data for 92 USGS streamflow-gaging stations (watersheds) in Texas with contributing drainage areas from 0.26 to 166 square miles. The analysis is limited to a previously described, watershed-specific, gamma distribution model of the unit hydrograph. In particular, the initial-abstraction, constant-loss model is tuned to the gamma distribution model of the unit hydrograph. A complex computational analysis of observed rainfall and runoff for the 92 watersheds was done to determine, by storm, optimal values of initial abstraction and constant loss. Optimal parameter values for a given storm were defined as those values that produced a modeled runoff hydrograph with volume equal to the observed runoff hydrograph and also minimized the residual sum of squares of the two hydrographs. Subsequently, the means of the optimal parameters were computed on a watershed-specific basis. These means for each watershed are considered the most representative, are tabulated, and are used in further statistical analyses. Statistical analyses of watershed-specific, initial abstraction and constant loss include documentation of the distribution of each parameter using the generalized lambda distribution. The analyses show that watershed development has substantial influence on initial abstraction and limited influence on constant loss. The means and medians of the 92 watershed-specific parameters are tabulated with respect to watershed development; although they have considerable uncertainty, these parameters can be used for parameter prediction for ungaged watersheds. The statistical analyses of watershed-specific, initial abstraction and constant loss also include development of predictive procedures for estimation of each parameter for ungaged watersheds. Both regression equations and regression trees for estimation of initial abstraction and constant loss are provided. The watershed characteristics included in the regression analyses are (1) main-channel length, (2) a binary factor representing watershed development, (3) a binary factor representing watersheds with an abundance of rocky and thin-soiled terrain, and (4) curve numb

Preferential flow estimates to an agricultural tile drain with implications for glyphosate transport

USGS Publications Warehouse

Stone, W.W.; Wilson, J.T.

2006-01-01

Agricultural subsurface drains, commonly referred to as tile drains, are potentially significant pathways for the movement of fertilizers and pesticides to streams and ditches in much of the Midwest. Preferential flow in the unsaturated zone provides a route for water and solutes to bypass the soil matrix and reach tile drains faster than predicted by traditional displacement theory. This paper uses chloride concentrations to estimate preferential flow contributions to a tile drain during two storms in May 2004. Chloride, a conservative anion, was selected as the tracer because of differences in chloride concentrations between the two sources of water to the tile drain, preferential and matrix flow. A strong correlation between specific conductance and chloride concentration provided a mechanism to estimate chloride concentrations in the tile drain throughout the storm hydrographs. A simple mixing analysis was used to identify the preferential flow component of the storm hydrograph. During two storms, preferential flow contributed 11 and 51% of total storm tile drain flow; the peak contributions, 40 and 81%, coincided with the peak tile drain flow. Positive relations between glyphosate [N-(phosphonomethyl)glycine] concentrations and preferential flow for the two storms suggest that preferential flow is an important transport pathway to the tile drain. ?? ASA, CSSA, SSSA.

A methodology for investigation of the seasonal evolution in proglacial hydrograph form

NASA Astrophysics Data System (ADS)

Hannah, David M.; Gurnell, Angela M.; McGregor, Glenn R.

1999-11-01

This paper advances an objective method of diurnal hydrograph classification as an aid to exploring changes in the hydrological functioning of glacierized catchments over the ablation season. The temporal sequencing of different hydrograph classes allows identification of seasonal evolution in hydrograph form and also assists delimitation of hydrologically-meaningful time periods of similar diurnal discharge response. The effectiveness of this approach is illustrated by applying it to two contrasting summer discharge records for a small cirque basin. By comparing the results with patterns of surface energy receipt and glacier ablation, the seasonally transient relative influences of: (i) surface meltwater production and (ii) meltwater routing and storage conditions within the intervening glacier drainage system in determining runoff are elucidated. The method successfully characterizes distinct seasonal-scale changes in the diurnal outflow hydrograph during the ablation-dominated 1995 melt season but is also able to reveal underlying trends and short-term fluctuations in the precipitation-dominated, poorly ablation-regulated 1996 melt season. The limitations and benefits of this hydrograph classification technique are evaluated.

Tracing hydrologic pathways using chloride at the Panola mountain research watershed, Georgia, USA

USGS Publications Warehouse

Peters, N.E.; Ratcliffe, E.B.

1998-01-01

An analysis of chloride (Cl-) concentrations and fluxes at the 41 ha Panola Mountain Research Watershed indicates that Cl- may be used effectively to differentiate 'new' and 'old' water flow through the hillslope and their respective contributions to streamwater. Rainfall and throughfall, the 'new' water inputs, are marked by low Cl- concentrations (30 ??eq L-1). Timing of soil water transport is not sufficiently rapid to suggest that soil water from this hillslope site (20 m from the stream) contributes to streamwater during individual rainstorms. The source of streamflow, therefore, must be a combination of channel interception, overland flow and soil water from nearchannel areas, and run off from a 3 ha bedrock outcrop in the headwaters Groundwater contribution to streamflow was estimated using Cl- concentrations of throughfall and groundwater as the two end members for a two-component hydrograph separation. For the study period, groundwater contributed 79% of the streamflow and from 1985 to 1995, contributed 75% of the streamflow. Rainfall was the source of 45% of the Cl- flux from the watershed in the long term; the remaining Cl- is hypothesized to be derived from dry deposition, consistent with the enrichment noted for throughfall. At peak flow during individual rainstorms, 'new' water can contribute 95% of the runoff.

A Flash Flood Study on the Small Montaneous River Catchments in Western Romania

NASA Astrophysics Data System (ADS)

Győri, Maria-Mihaela; Haidu, Ionel; Humbert, Joël

2013-04-01

The present study focuses on flash flood modeling on several mountaneous catchments situated in Western Romania by the use of two methodologies, when rainfall and catchment characteristics are known. Hence, the Soil Conservation Service (SCS) Method and the Rational Method will be employed for the generation of the 1%, 2% and 10% historical flash flood hydrographs on the basis of data spanning from 1989-2009. The SCS Method has been applied on the three gauged catchments in the study area: Petris, Troas and Monorostia making use of the existing interconnection between GIS and the rainfall-runoff models. The DEM, soil data and land use preprocessing in GIS allowed a determination of the hydrologic parameters needed for the rainfall-runoff model, with special emphasis on determining the time of concentration, Lag time and the weighted Curve Number according to Antecedent Moisture Conditions II, adapted for the Romanian territory. HEC-HMS rainfall-runoff model (Hydrologic Engineering Center- Hydrologic Modeling System) facilitates the historical 1%, 2% and 10% flash flood hydrograph generation for the three afore mentioned watersheds. The model is calibrated against measured streamflow data from the three existing gauging stations. The results show a good match between the resulted hydrographs and the observed hydrographs under the form of the Peak Weighted Error RMS values. The hydrographs generated by surface runoff on the ungauged catchments in the area is based on an automation of a workflow in GIS, built with ArcGIS Model Builder graphical interface, as a large part of the functions needed were available as ArcGIS tools. The several components of this model calculate: the runoff depth in mm, the runoff coefficient, the travel time and finally the discharge module which is an application of the rational method, allowing the discharge computation for every cell within the catchment. The result consists of discharges for each isochrones that will be subsequently interpolated in order to obtain the hydrograph of the historical flash floods. The two methodologies employed offer the hydrologist the opportunity of computing the historical hydrographs be it on a section of the river at choice, or for every affluent within the small river basins studied, the graphical data being easily accessed both in GIS and HEC-HMS. The peak discharge values of the main rivers as well as those of their tributaries are of great importance in establishing the hydrologic hazard under the form of floodplain maps that are inexistent for the studied watersheds. Key words: flash flood modeling, ungauged catchments, GIS, HEC-HMS rainfall-runoff model. Aknowledgements This work was possible with the financial support of the Sectoral Operational Programme for Human Resources Development 2007-2013, co-financed by the European Social Fund, under the project number POSDRU/107/1.5/S/76841 with the title "Modern Doctoral Studies: Internationalization and Interdisciplinarity".

Old groundwater influence on stream hydrochemistry and catchment response times in a small Sierra Nevada catchment: Sagehen Creek, California

USGS Publications Warehouse

Rademacher, Laura K.; Clark, Jordan F.; Clow, David W.; Bryant, Hudson G.

2005-01-01

The relationship between the chemical and isotopic composition of groundwater and residence times was used to understand the temporal variability in stream hydrochemistry in Sagehen basin, California. On the basis of the relationship between groundwater age and [Ca2+], the mean residence time of groundwater feeding Sagehen Creek during base flow is approximately 28 years. [Cl−]:[Ca2+] ratios in Sagehen Creek can be used to distinguish between two important processes: changes in the apparent age of groundwater discharging into the creek and dilution with snowmelt. The mean residence time of groundwater discharging into the creek is approximately 15 years during snowmelt periods. The results from this study have implications for hydrograph separation studies as groundwater is not a single, well‐mixed chemical component but rather is a variable parameter that predictably depends on groundwater residence time. Most current models of catchment hydrochemistry do not account for chemical and isotopic variability found within the groundwater reservoir. In addition, this study provides valuable insight into the long‐term hydrochemical response of a catchment to perturbations as catchment‐flushing times are related to the mean residence time of water in a basin.

Trade-off analysis of discharge-desiltation-turbidity and ANN analysis on sedimentation of a combined reservoir-reach system under multi-phase and multi-layer conjunctive releasing operation

NASA Astrophysics Data System (ADS)

Huang, Chien-Lin; Hsu, Nien-Sheng; Wei, Chih-Chiang; Yao, Chun-Hao

2017-10-01

Multi-objective reservoir operation considering the trade-off of discharge-desiltation-turbidity during typhoons and sediment concentration (SC) simulation modeling are the vital components for sustainable reservoir management. The purposes of this study were (1) to analyze the multi-layer release trade-offs between reservoir desiltation and intake turbidity of downstream purification plants and thus propose a superior conjunctive operation strategy and (2) to develop ANFIS-based (adaptive network-based fuzzy inference system) and RTRLNN-based (real-time recurrent learning neural networks) substitute SC simulation models. To this end, this study proposed a methodology to develop (1) a series of multi-phase and multi-layer sediment-flood conjunctive release modes and (2) a specialized SC numerical model for a combined reservoir-reach system. The conjunctive release modes involve (1) an optimization model where the decision variables are multi-phase reduction/scaling ratios and the timings to generate a superior total release hydrograph for flood control (Phase I: phase prior to flood arrival, Phase II/III: phase prior to/subsequent to peak flow) and (2) a combination method with physical limitations regarding separation of the singular hydrograph into multi-layer release hydrographs for sediment control. This study employed the featured signals obtained from statistical quartiles/sediment duration curve in mesh segmentation, and an iterative optimization model with a sediment unit response matrix and corresponding geophysical-based acceleration factors, for efficient parameter calibration. This research applied the developed methodology to the Shihmen Reservoir basin in Taiwan. The trade-off analytical results using Typhoons Sinlaku and Jangmi as case examples revealed that owing to gravity current and re-suspension effects, Phase I + II can de-silt safely without violating the intake's turbidity limitation before reservoir discharge reaches 2238 m3/s; however, Phase III can only de-silt after the release at spillway reaches 827 m3/s, and before reservoir discharge reaches 1924 m3/s, with corresponding maximum desiltation ratio being 0.221 and 0.323, respectively. Moreover, the model construction results demonstrated that the self-adaption/fuzzy inference of ANFIS can effectively simulate the SC hydrograph in an unsteady state for suspended load-dominated water bodies, and that the real-time recurrent deterministic routing of RTRLNN can accurately simulate that of a bedload-dominated flow regime.

Temporal variations in baseflow for the Little River Experimental Watershed in South Georgia

USDA-ARS?s Scientific Manuscript database

Hydrology is the driving force of sediment, nutrient, and pesticide movement. Separation of streamflow hydrographs into rapid surface runoff and baseflow can vastly improve our understanding of watershed processes. Data collected at the Little River Experimental Watershed (LREW) in the South Atlanti...

A Modified Penalty Parameter Approach for Optimal Estimation of UH with Simultaneous Estimation of Infiltration Parameters

NASA Astrophysics Data System (ADS)

Bhattacharjya, Rajib Kumar

2018-05-01

The unit hydrograph and the infiltration parameters of a watershed can be obtained from observed rainfall-runoff data by using inverse optimization technique. This is a two-stage optimization problem. In the first stage, the infiltration parameters are obtained and the unit hydrograph ordinates are estimated in the second stage. In order to combine this two-stage method into a single stage one, a modified penalty parameter approach is proposed for converting the constrained optimization problem to an unconstrained one. The proposed approach is designed in such a way that the model initially obtains the infiltration parameters and then searches the optimal unit hydrograph ordinates. The optimization model is solved using Genetic Algorithms. A reduction factor is used in the penalty parameter approach so that the obtained optimal infiltration parameters are not destroyed during subsequent generation of genetic algorithms, required for searching optimal unit hydrograph ordinates. The performance of the proposed methodology is evaluated by using two example problems. The evaluation shows that the model is superior, simple in concept and also has the potential for field application.

Generation of synthetic flood hydrographs by hydrological donors (SHYDONHY method)

NASA Astrophysics Data System (ADS)

Paquet, Emmanuel

2017-04-01

For the design of hydraulic infrastructures like dams, a design hydrograph is required in most of the cases. Some of its features (e.g. peak value, duration, volume) corresponding to a given return period are computed thanks to a wide range of methods: historical records, mono or multivariate statistical analysis, stochastic simulation, etc. Then various methods have been proposed to construct design hydrographs having such characteristics, ranging from traditional unit-hydrograph to statistical methods (Yue et al., 2002). A new method to build design hydrographs (or more generally synthetic hydrographs) is introduced here, named SHYDONHY, French acronym for "Synthèse d'HYdrogrammes par DONneurs HYdrologiques". It is based on an extensive database of 100 000 flood hydrographs recorded at hourly time-step on 1300 gauging stations in France and Switzerland, covering a wide range of catchment size and climatology. For each station, an average of two hydrographs per year of record has been selected by a peak-over-threshold (POT) method with independence criteria (Lang et al., 1999). This sampling ensures that only hydrographs of intense floods are gathered in the dataset. For a given catchment, where few or no hydrograph is available at the outlet, a sub-set of 10 "donor stations" is selected within the complete dataset, considering several criteria: proximity, size, mean annual values and regimes for both total runoff and POT-selected floods. This sub-set of stations (and their corresponding flood hydrographs) will allow to: • Estimate a characteristic duration of flood hydrographs (e.g. duration for which the discharge is above 50% of the peak value). • For a given duration (e.g. one day), estimate the average peak-to- volume ratio of floods. • For a given duration and peak-to-volume ratio, generation of a synthetic reference hydrograph by combining appropriate hydrographs of the sub-set. • For a given daily discharge sequence, being observed or generated for extreme flood estimation, generate a suitable synthetic hydrograph, also by combining selected hydrographs of the sub-set. The reliability of the method is assessed by performing a jackknife validation on the whole dataset of stations, in particular by reconstructing the hydrograph of the biggest flood of each station and comparing it to the actual one. Some applications are presented, e.g. the coupling of SHYDONHY with the SCHADEX method (Paquet et al., 2003) for the stochastic simulation of extreme reservoir level in dams. References: Lang, M., Ouarda, T. B. M. J., & Bobée, B. (1999). Towards operational guidelines for over-threshold modeling. Journal of hydrology, 225(3), 103-117. Paquet, E., Garavaglia, F., Garçon, R., & Gailhard, J. (2013). The SCHADEX method: A semi-continuous rainfall-runoff simulation for extreme flood estimation. Journal of Hydrology, 495, 23-37. Yue, S., Ouarda, T. B., Bobée, B., Legendre, P., & Bruneau, P. (2002). Approach for describing statistical properties of flood hydrograph. Journal of hydrologic engineering, 7(2), 147-153.

EVALUATION AND APPLICATION OF ELECTRICAL CONDUCTIVITY AS A TRACER FOR HYDROGRAPH SEPARATION STUDIES IN URBAN WATERSHEDS. (R828582)

EPA Science Inventory

The perspectives, information and conclusions conveyed in research project abstracts, progress reports, final reports, journal abstracts and journal publications convey the viewpoints of the principal investigator and may not represent the views and policies of ORD and EPA. Concl...

Reply to Discussion by Zekai Șen on "Modeling karst spring hydrograph recession based on head drop at sinkholes"

NASA Astrophysics Data System (ADS)

Field, Malcolm S.; Goldscheider, Nico; Li, Guangquan

2018-02-01

We are pleased to learn that the model presented in our paper dealing with the "modeling karst spring hydrograph recession based on head drop at sinkholes," published in the Journal of Hydrology in 2016 (Li et al., 2016), is of interest to readers of this journal. Our study presented a new non-exponential model for assessing spring hydrographs in terms of head drop at flooded sinkholes, as an extension of an earlier model proposed by Li and Field (2014). In both papers, we used two spring hydrographs measured in the St. Marks Karst Watershed in northwest Florida to test the applicability and to verify the validity of our models.

Excel Spreadsheet Tools for Analyzing Groundwater Level Records and Displaying Information in ArcMap

USGS Publications Warehouse

Tillman, Fred D.

2009-01-01

When beginning hydrologic investigations, a first action is often to gather existing sources of well information, compile this information into a single dataset, and visualize this information in a geographic information system (GIS) environment. This report presents tools (macros) developed using Visual Basic for Applications (VBA) for Microsoft Excel 2007 to assist in these tasks. One tool combines multiple datasets into a single worksheet and formats the resulting data for use by the other tools. A second tool produces summary information about the dataset, such as a list of unique site identification numbers, the number of water-level observations for each, and a table of the number of sites with a listed number of water-level observations. A third tool creates subsets of the original dataset based on user-specified options and produces a worksheet with water-level information for each well in the subset, including the average and standard deviation of water-level observations and maximum decline and rise in water levels between any two observations, among other information. This water-level information worksheet can be imported directly into ESRI ArcMap as an 'XY Data' file, and each of the fields of summary well information can be used for custom display. A separate set of VBA tools distributed in an additional Excel workbook creates hydrograph charts of each of the wells in the data subset produced by the aforementioned tools and produces portable document format (PDF) versions of the hydrograph charts. These PDF hydrographs can be hyperlinked to well locations in ArcMap or other GIS applications.

Forecasting approaches to the Mekong River

NASA Astrophysics Data System (ADS)

Plate, E. J.

2009-04-01

Hydrologists distinguish between flood forecasts, which are concerned with events of the immediate future, and flood predictions, which are concerned with events that are possible, but whose date of occurrence is not determined. Although in principle both involve the determination of runoff from rainfall, the analytical approaches differ because of different objectives. The differences between the two approaches will be discussed, starting with an analysis of the forecasting process. The Mekong River in south-east Asia is used as an example. Prediction is defined as forecast for a hypothetical event, such as the 100-year flood, which is usually sufficiently specified by its magnitude and its probability of occurrence. It forms the basis for designing flood protection structures and risk management activities. The method for determining these quantities is hydrological modeling combined with extreme value statistics, today usually applied both to rainfall events and to observed river discharges. A rainfall-runoff model converts extreme rainfall events into extreme discharges, which at certain gage points along a river are calibrated against observed discharges. The quality of the model output is assessed against the mean value by means of the Nash-Sutcliffe quality criterion. The result of this procedure is a design hydrograph (or a family of design hydrographs) which are used as inputs into a hydraulic model, which converts the hydrograph into design water levels according to the hydraulic situation of the location. The accuracy of making a prediction in this sense is not particularly high: hydrologists know that the 100-year flood is a statistical quantity which can be estimated only within comparatively wide error bounds, and the hydraulics of a river site, in particular under conditions of heavy sediment loads has many uncertainties. Safety margins, such as additional freeboards are arranged to compensate for the uncertainty of the prediction. Forecasts, on the other hand, have as objective to obtain an accurate hydrograph of the near future. The method by means of which this is done is not as important as the accuracy of the forecast. A mathematical rainfall-runoff model is not necessarily a good forecast model. It has to be very carefully designed, and in many cases statistical models are found to give better results than mathematical models. Forecasters have the advantage of knowing the course of the hydrographs up to the point in time where forecasts have to be made. Therefore, models can be calibrated on line against the hydrograph of the immediate past. To assess the quality of a forecast, the quality criterion should not be based on the mean value, as does the Nash-Sutcliffe criterion, but should be based on the best forecast given the information up to the forecast time. Without any additional information, the best forecast when only the present day value is known is to assume a no-change scenario, i.e. to assume that the present value does not change in the immediate future. For the Mekong there exists a forecasting system which is based on a rainfall-runoff model operated by the Mekong River Commission. This model is found not to be adequate for forecasting for periods longer than one or two days ahead. Improvements are sought through two approaches: a strictly deterministic rainfall-runoff model, and a strictly statistical model based on regression with upstream stations. The two approaches are com-pared, and suggestions are made how to best combine the advantages of both approaches. This requires that due consideration is given to critical hydraulic conditions of the river at and in between the gauging stations. Critical situations occur in two ways: when the river overtops, in which case the rainfall-runoff model is incomplete unless overflow losses are considered, and at the confluence with tributaries. Of particular importance is the role of the large Tonle Sap Lake, which dampens the hydrograph downstream of Phnom Penh. The effect of these components of river hydraulics on forecasting accuracy will be assessed.

Catchment-scale hydrologic implications of parcel-level stormwater management (Ohio USA)

NASA Astrophysics Data System (ADS)

Shuster, William; Rhea, Lee

2013-04-01

SummaryThe effectiveness of stormwater management strategies is a key issue affecting decision making on urban water resources management, and so proper monitoring and analysis of pilot studies must be addressed before drawing conclusions. We performed a pilot study in the suburban Shepherd Creek watershed located in Cincinnati, Ohio to evaluate the practicality of voluntary incentives for stormwater quantity reduction on privately owned suburban properties. Stream discharge and precipitation were monitored 3 years before and after implementation of the stormwater management treatments. To implement stormwater control measures, we elicited the participation of citizen landowners with two successive reverse-auctions. Auctions were held in spring 2007, and 2008, resulting in the installation of 85 rain gardens and 174 rain barrels. We demonstrated an analytic process of increasing model flexibility to determine hydrologic effectiveness of stormwater management at the sub-catchment level. A significant albeit small proportion of total variance was explained by both the effects of study period (˜69%) and treatment-vs.-control (˜7%). Precipitation-discharge relationships were synthesized in estimated unit hydrographs, which were decomposed and components tested for influence of treatments. Analysis of unit hydrograph parameters showed a weakened correlation between precipitation and discharge, and support the output from the initial model that parcel-level green infrastructure added detention capacity to treatment basins. We conclude that retrofit management of stormwater runoff quantity with green infrastructure in a small suburban catchment can be successfully initiated with novel economic incentive programs, and that these measures can impart a small, but statistically significant decrease in otherwise uncontrolled runoff volume. Given consistent monitoring data and analysis, water resource managers can use our approach as a way to estimate actual effectiveness of stormwater runoff volume management, with potential benefits for management of both separated and combined sewer systems. We also discuss lessons-learned with regard to monitoring design for catchment-scale hydrologic studies.

Use of seasonal trend decomposition to understand groundwater behaviour in the Permo-Triassic Sandstone aquifer, Eden Valley, UK

NASA Astrophysics Data System (ADS)

Lafare, Antoine E. A.; Peach, Denis W.; Hughes, Andrew G.

2016-02-01

The daily groundwater level (GWL) response in the Permo-Triassic Sandstone aquifers in the Eden Valley, England (UK), has been studied using the seasonal trend decomposition by LOESS (STL) technique. The hydrographs from 18 boreholes in the Permo-Triassic Sandstone were decomposed into three components: seasonality, general trend and remainder. The decomposition was analysed first visually, then using tools involving a variance ratio, time-series hierarchical clustering and correlation analysis. Differences and similarities in decomposition pattern were explained using the physical and hydrogeological information associated with each borehole. The Penrith Sandstone exhibits vertical and horizontal heterogeneity, whereas the more homogeneous St Bees Sandstone groundwater hydrographs characterize a well-identified seasonality; however, exceptions can be identified. A stronger trend component is obtained in the silicified parts of the northern Penrith Sandstone, while the southern Penrith, containing Brockram (breccias) Formation, shows a greater relative variability of the seasonal component. Other boreholes drilled as shallow/deep pairs show differences in responses, revealing the potential vertical heterogeneities within the Penrith Sandstone. The differences in bedrock characteristics between and within the Penrith and St Bees Sandstone formations appear to influence the GWL response. The de-seasonalized and de-trended GWL time series were then used to characterize the response, for example in terms of memory effect (autocorrelation analysis). By applying the STL method, it is possible to analyse GWL hydrographs leading to better conceptual understanding of the groundwater flow. Thus, variation in groundwater response can be used to gain insight into the aquifer physical properties and understand differences in groundwater behaviour.

Customizing WRF-Hydro for the Laurentian Great Lakes Basin

NASA Astrophysics Data System (ADS)

Gronewold, A.; Pei, L.; Gochis, D.; Mason, L.; Sampson, K. M.; Dugger, A. L.; Read, L.; McCreight, J. L.; Xiao, C.; Lofgren, B. M.; Anderson, E. J.; Chu, P. Y.

2017-12-01

To advance the state of the art in regional hydrological forecasting, and to align with operational deployment of the National Water Model, a team of scientists has been customizing WRF-Hydro (the Weather Research and Forecasting model - Hydrological modeling extension package) to the entirety (including binational land and lake surfaces) of the Laurentian Great Lakes basin. Objectives of this customization project include opererational simulation and forecasting of the Great Lakes water balance and, in the short-term, research-oriented insights into modeling one- and two-way coupled lake-atmosphere and near-shore processes. Initial steps in this project have focused on overcoming inconsistencies in land surface hydrographic datasets between the United States and Canada. Improvements in the model's current representation of lake physics and stream routing are also critical components of this effort. Here, we present an update on the status of this project, including a synthesis of offline tests with WRF-Hydro based on the newly developed Great Lakes hydrographic data, and an assessment of the model's ability to simulate seasonal and multi-decadal hydrological response across the Great Lakes.

Mapping mesoscale variability of the Azores Current using TOPEX/POSEIDON and ERS 1 altimetry, together with hydrographic and Lagrangian measurements

NASA Astrophysics Data System (ADS)

Hernandez, Fabrice; Le Traon, Pierre-Yves; Morrow, Rosemary

1995-12-01

The SEMAPHORE mesoscale air/sea experiment was conducted in the Azores-Madeira region from July to November 1993. TOPEX/POSEIDON (T/P) and ERS 1 were flying simultaneously at that time. The main purposes of this paper are to evaluate the estimation of the oceanic mesoscale circulation from the two different sets of altimetric data (T/P and ERS 1) and to compare the results with in situ measurements provided by the SEMAPHORE hydrographic surveys and surface drifters (three expendable bathytermograph conductivity-temperature-depth surveys in a 500-km2 box and a set of 47 Lagrangian surface drifters drogued at 150 m). Comparisons are carried out through the maps obtained by objective analysis from the four data sets. The mapping accuracy of T/P, ERS 1, T/P and ERS 1 combined, and in situ data is investigated, as well as the sensitivity of the mapping to the correlation functions used. There is a good qualitative agreement between altimetric maps and corresponding drifter and hydrographic maps for the three hydrographic surveys. Correlations are about 0.8, and the regression fit is about 0.6-0.7; the lower values are due to the smooth climatology used to reference the altimetric maps. The correlation for time differences is better, with regression lines not significantly different from 1, especially when ERS 1 and T/P are combined. T/P mapping is almost as good as ERS 1 mapping, which was rather unexpected since the ERS 1 space-time sampling is better suited for the mesoscale. This may reflect the fact that the signal mapped by the hydrography and drifters does not contain the high frequency/wavenumber components. T/P and ERS 1 combined provide better results, although the improvement is not as large as expected, probably for the same reason.

Stable-isotope and solute-chemistry approaches to flow characterization in a forested tropical watershed, Luquillo Mountains, Puerto Rico

USGS Publications Warehouse

Scholl, Martha A.; Shanley, James B.; Murphy, Sheila F.; Willenbring, Jane K; Occhi, Marcie; González, Grizelle

2015-01-01

The prospect of changing climate has led to uncertainty about the resilience of forested mountain watersheds in the tropics. In watersheds where frequent, high rainfall provides ample runoff, we often lack understanding of how the system will respond under conditions of decreased rainfall or drought. Factors that govern water supply, such as recharge rates and groundwater storage capacity, may be poorly quantified. This paper describes 8-year data sets of water stable isotope composition (δ2H and δ18O) of precipitation (4 sites) and a stream (1 site), and four contemporaneous stream sample sets of solute chemistry and isotopes, used to investigate watershed response to precipitation inputs in the 1780-ha Río Mameyes basin in the Luquillo Mountains of northeastern Puerto Rico. Extreme δ2H and δ18O values from low-pressure storm systems and the deuterium excess (d-excess) were useful tracers of watershed response in this tropical system. A hydrograph separation experiment performed in June 2011 yielded different but complementary information from stable isotope and solute chemistry data. The hydrograph separation results indicated that 36% of the storm rain that reached the soil surface left the watershed in a very short time as runoff. Weathering-derived solutes indicated near-stream groundwater was displaced into the stream at the beginning of the event, followed by significant dilution. The more biologically active solutes exhibited a net flushing behavior. The d-excess analysis suggested that streamflow typically has a recent rainfall component (∼25%) with transit time less than the sampling resolution of 7 days, and a more well-mixed groundwater component (∼75%). The contemporaneous stream sample sets showed an overall increase in dissolved solute concentrations with decreasing elevation that may be related to groundwater inputs, different geology, and slope position. A considerable amount of water from rain events runs off as quickflow and bypasses subsurface watershed flowpaths, and better understanding of shallow hillslope and deeper groundwater processes in the watershed will require sub-weekly data and detailed transit time modeling. A combined isotopic and solute chemistry approach can guide further studies to a more comprehensive model of the hydrology, and inform decisions for managing water supply with future changes in climate and land use.

Anisotropic properties of phase separation in two-component dipolar Bose-Einstein condensates

NASA Astrophysics Data System (ADS)

Wang, Wei; Li, Jinbin

2018-03-01

Using Crank-Nicolson method, we calculate ground state wave functions of two-component dipolar Bose-Einstein condensates (BECs) and show that, due to dipole-dipole interaction (DDI), the condensate mixture displays anisotropic phase separation. The effects of DDI, inter-component s-wave scattering, strength of trap potential and particle numbers on the density profiles are investigated. Three types of two-component profiles are present, first cigar, along z-axis and concentric torus, second pancake (or blood cell), in xy-plane, and two non-uniform ellipsoid, separated by the pancake and third two dumbbell shapes.

Temporal dynamics in dominant runoff sources and flow paths in the Andean Páramo

NASA Astrophysics Data System (ADS)

Correa, Alicia; Windhorst, David; Tetzlaff, Doerthe; Crespo, Patricio; Célleri, Rolando; Feyen, Jan; Breuer, Lutz

2017-07-01

The relative importance of catchment's water provenance and flow paths varies in space and time, complicating the conceptualization of the rainfall-runoff responses. We assessed the temporal dynamics in source areas, flow paths, and age by End Member Mixing Analysis (EMMA), hydrograph separation, and Inverse Transit Time Proxies (ITTPs) estimation within a headwater catchment in the Ecuadorian Andes. Twenty-two solutes, stable isotopes, pH, and electrical conductivity from a stream and 12 potential sources were analyzed. Four end-members were required to satisfactorily represent the hydrological system, i.e., rainfall, spring water, and water from the bottom layers of Histosols and Andosols. Water from Histosols in and near the riparian zone was the highest source contributor to runoff throughout the year (39% for the drier season, 45% for the wetter season), highlighting the importance of the water that is stored in the riparian zone. Spring water contributions to streamflow tripled during the drier season, as evidenced by geochemical signatures that are consistent with deeper flow paths rather than shallow interflow through Andosols. Rainfall exhibited low seasonal variation in this contribution. Hydrograph separation revealed that 94% and 84% is preevent water in the drier and wetter seasons, respectively. From low-flow to high-flow conditions, all the sources increased their contribution except spring water. The relative age of stream water decreased during wetter periods, when the contributing area of the riparian zone expands. The multimethod and multitracer approach enabled to closely study the interchanging importance of flow processes and water source dynamics from an interannual perspective.

Base flow (1966-2005) and streamflow gain and loss (2006) of the Brazos River, McLennan County to Fort Bend County, Texas

USGS Publications Warehouse

Turco, Michael J.; East, Jeffery W.; Milburn, Matthew S.

2007-01-01

During 2006?07, the U.S. Geological Survey (USGS), in cooperation with the Texas Water Development Board, did a study to quantify historical (water years 1966?2005) base flow and streamflow gains and losses from two streamflow-measuring surveys (March and August 2006) in the Brazos River from McLennan County to Fort Bend County, Texas. The Brazos River is hydraulically connected to the Brazos River alluvium aquifer, which in turn is hydraulically connected to several underlying aquifers, the outcrops of which occur in laterally adjacent layers generally parallel to the coast (major aquifers, Carrizo-Wilcox and Gulf Coast, and minor aquifers, Queen City, Sparta, and Yegua-Jackson). Hydrograph separation was done using the USGS computer program Hydrograph Separation and Analysis with historical streamflow from 10 USGS gaging stations, three on the Brazos River and seven on selected tributaries to the Brazos River. Streamflow data for computation of gains and losses were collected in March 2006 from 36 sites on the Brazos River and 19 sites on 19 tributaries to the Brazos River; and in August 2006 from 28 sites on the Brazos River and 16 sites on tributaries. Hydrograph separation and associated analyses indicate an appreciable increase in base flow as a percentage of streamflow in the reach of the Brazos River that crosses the outcrops of the Carrizo-Wilcox, Queen City, Sparta, and Yegua-Jackson aquifers compared to that in the adjacent upstream reach (on average from about 43 percent to about 60 percent). No increase in base flow as a percentage of streamflow in the reach of the Brazos River crossing the Gulf Coast aquifer compared to that in the adjacent upstream reach was indicated. Streamflow gains and losses computed for March 2006 for 35 reaches defined by pairs of sites on the Brazos River indicated that five reaches were verifiably gaining streamflow (computed gain exceeded potential flow measurement error) and none were verifiably losing streamflow. Four of the five gaining reaches are in the outcrop areas of the Carrizo-Wilcox and Yegua-Jackson aquifers. The results of the synoptic gain and loss surveys are consistent with the results of the base-flow analysis of historical streamflow. Appreciable increases in streamflow, apparently the result of increases in base flow, occur in the reach of the Brazos River that crosses the outcrops of the Carrizo-Wilcox, Queen City, Sparta, and Yegua-Jackson aquifers.

Final summarizing report on Grant DE-SC0001014 "Separation of Highly Complex Mixtures by Two-dimension Liquid Chromatography"

DOE Office of Scientific and Technical Information (OSTI.GOV)

Guiochon, Georges

The goal of our research was a fundamental investigation of methods available for the coupling of two separate chromatographic separations that would considerably enhance the individual separation power of each of these two separations. This gain arises from the combination of two independent retention mechanisms, one of them separating the components that coelute on the other column, making possible the separation of many more compounds in a given time. The two separation mechanisms used must be very different. This is possible because many retention mechanisms are available, using different kinds of molecular interactions, hydrophobic or hydrophilic interactions, polar interactions, hydrogenmore » bonding, complex formation, ionic interactions, steric exclusion. Two methods can be used, allowing separations to be performed in space (spreading the bands of sample components on a plate covered with stationary phase layer) or in time (eluting the sample components through a column and detecting the bands leaving the column). Both offer a wide variety of possible combinations and were studied.« less

The Landlab v1.0 OverlandFlow component: a Python tool for computing shallow-water flow across watersheds

NASA Astrophysics Data System (ADS)

Adams, Jordan M.; Gasparini, Nicole M.; Hobley, Daniel E. J.; Tucker, Gregory E.; Hutton, Eric W. H.; Nudurupati, Sai S.; Istanbulluoglu, Erkan

2017-04-01

Representation of flowing water in landscape evolution models (LEMs) is often simplified compared to hydrodynamic models, as LEMs make assumptions reducing physical complexity in favor of computational efficiency. The Landlab modeling framework can be used to bridge the divide between complex runoff models and more traditional LEMs, creating a new type of framework not commonly used in the geomorphology or hydrology communities. Landlab is a Python-language library that includes tools and process components that can be used to create models of Earth-surface dynamics over a range of temporal and spatial scales. The Landlab OverlandFlow component is based on a simplified inertial approximation of the shallow water equations, following the solution of de Almeida et al.(2012). This explicit two-dimensional hydrodynamic algorithm simulates a flood wave across a model domain, where water discharge and flow depth are calculated at all locations within a structured (raster) grid. Here, we illustrate how the OverlandFlow component contained within Landlab can be applied as a simplified event-based runoff model and how to couple the runoff model with an incision model operating on decadal timescales. Examples of flow routing on both real and synthetic landscapes are shown. Hydrographs from a single storm at multiple locations in the Spring Creek watershed, Colorado, USA, are illustrated, along with a map of shear stress applied on the land surface by flowing water. The OverlandFlow component can also be coupled with the Landlab DetachmentLtdErosion component to illustrate how the non-steady flow routing regime impacts incision across a watershed. The hydrograph and incision results are compared to simulations driven by steady-state runoff. Results from the coupled runoff and incision model indicate that runoff dynamics can impact landscape relief and channel concavity, suggesting that, on landscape evolution timescales, the OverlandFlow model may lead to differences in simulated topography in comparison with traditional methods. The exploratory test cases described within demonstrate how the OverlandFlow component can be used in both hydrologic and geomorphic applications.

Separation of the Components of a Commercial Analgesic Tablet: A Two-Week Sequence Comparing Purification by Two-Base Extraction and Column Chromatography

ERIC Educational Resources Information Center

Revell, Kevin D.

2011-01-01

A new laboratory experiment is described in which students compare two benchtop separation methods to isolate the three active components of the commercial analgesic Excedrin. In the two-week sequence, aspirin, acetaminophen, and caffeine are separated using either a two-base liquid-liquid extraction or silica column chromatography. Students then…

The Value of Hydrograph Partitioning Curves for Calibrating Hydrological Models in Glacierized Basins

NASA Astrophysics Data System (ADS)

He, Zhihua; Vorogushyn, Sergiy; Unger-Shayesteh, Katy; Gafurov, Abror; Kalashnikova, Olga; Omorova, Elvira; Merz, Bruno

2018-03-01

This study refines the method for calibrating a glacio-hydrological model based on Hydrograph Partitioning Curves (HPCs), and evaluates its value in comparison to multidata set optimization approaches which use glacier mass balance, satellite snow cover images, and discharge. The HPCs are extracted from the observed flow hydrograph using catchment precipitation and temperature gradients. They indicate the periods when the various runoff processes, such as glacier melt or snow melt, dominate the basin hydrograph. The annual cumulative curve of the difference between average daily temperature and melt threshold temperature over the basin, as well as the annual cumulative curve of average daily snowfall on the glacierized areas are used to identify the starting and end dates of snow and glacier ablation periods. Model parameters characterizing different runoff processes are calibrated on different HPCs in a stepwise and iterative way. Results show that the HPC-based method (1) delivers model-internal consistency comparably to the tri-data set calibration method; (2) improves the stability of calibrated parameter values across various calibration periods; and (3) estimates the contributions of runoff components similarly to the tri-data set calibration method. Our findings indicate the potential of the HPC-based approach as an alternative for hydrological model calibration in glacierized basins where other calibration data sets than discharge are often not available or very costly to obtain.

Onsager Vortex Formation in Two-component Bose-Einstein Condensates

NASA Astrophysics Data System (ADS)

Han, Junsik; Tsubota, Makoto

2018-06-01

We numerically study the dynamics of quantized vortices in two-dimensional two-component Bose-Einstein condensates (BECs) trapped by a box potential. For one-component BECs in a box potential, it is known that quantized vortices form Onsager vortices, which are clusters of same-sign vortices. We confirm that the vortices of the two components spatially separate from each other — even for miscible two-component BECs — suppressing the formation of Onsager vortices. This phenomenon is caused by the repulsive interaction between vortices belonging to different components, hence, suggesting a new possibility for vortex phase separation.

Estimation of synthetic flood design hydrographs using a distributed rainfall-runoff model coupled with a copula-based single storm rainfall generator

NASA Astrophysics Data System (ADS)

Candela, A.; Brigandì, G.; Aronica, G. T.

2014-07-01

In this paper a procedure to derive synthetic flood design hydrographs (SFDH) using a bivariate representation of rainfall forcing (rainfall duration and intensity) via copulas, which describes and models the correlation between two variables independently of the marginal laws involved, coupled with a distributed rainfall-runoff model, is presented. Rainfall-runoff modelling (R-R modelling) for estimating the hydrological response at the outlet of a catchment was performed by using a conceptual fully distributed procedure based on the Soil Conservation Service - Curve Number method as an excess rainfall model and on a distributed unit hydrograph with climatic dependencies for the flow routing. Travel time computation, based on the distributed unit hydrograph definition, was performed by implementing a procedure based on flow paths, determined from a digital elevation model (DEM) and roughness parameters obtained from distributed geographical information. In order to estimate the primary return period of the SFDH, which provides the probability of occurrence of a hydrograph flood, peaks and flow volumes obtained through R-R modelling were treated statistically using copulas. Finally, the shapes of hydrographs have been generated on the basis of historically significant flood events, via cluster analysis. An application of the procedure described above has been carried out and results presented for the case study of the Imera catchment in Sicily, Italy.

Influence of urban surface properties and rainfall characteristics on surface water flood outputs - insights from a physical modelling environment

NASA Astrophysics Data System (ADS)

Green, Daniel; Pattison, Ian; Yu, Dapeng

2017-04-01

Surface water (pluvial) flooding occurs when excess rainfall from intense precipitation events is unable to infiltrate into the subsurface or drain via natural or artificial drainage channels. Surface water flood events pose a major hazard to urban regions across the world, with nearly two thirds of flood damages in the UK being caused by surface water flood events. The perceived risk of surface water flooding appears to have increased in recent years due to several factors, including (i) precipitation increases associated with climatic change and variability; (ii) population growth meaning more people are occupying flood risk areas, and; (iii) land-use changes. Because urban areas are often associated with a high proportion of impermeable land-uses (e.g. tarmacked or paved surfaces and buildings) and a reduced coverage of vegetated, permeable surfaces, urban surface water flood risk during high intensity precipitation events is often exacerbated. To investigate the influence of urbanisation and terrestrial factors on surface water flood outputs, rainfall intensity, catchment slope, permeability, building density/layout scenarios were designed within a novel, 9m2 physical modelling environment. The two-tiered physical model used consists of (i) a low-cost, nozzle-type rainfall simulator component which is able to simulate consistent, uniformly distributed rainfall events of varying duration and intensity, and; (ii) a reconfigurable, modular plot surface. All experiments within the physical modelling environment were subjected to a spatiotemporally uniform 45-minute simulated rainfall event, while terrestrial factors on the physical model plot surface were altered systematically to investigate their hydrological response on modelled outflow and depth profiles. Results from the closed, controlled physical modelling experiments suggest that meteorological factors, such as the duration and intensity of simulated rainfall, and terrestrial factors, such as model slope, surface permeability and building density have a significant influence on physical model hydrological outputs. For example, changes in building density across the urban model catchment are shown to result in hydrographs having (i) a more rapid rising limb; (ii) higher peak discharges; (iii) a reduction in the total hydrograph time, and; (iv) a faster falling limb, with the dense building scenario having a 22% increase in peak discharge when compared to the no building scenario. Furthermore, the layout of buildings across the plot surface and their proximity to the outflow unit (i.e. downstream, upstream or to the side of the physical model outlet) is shown to influence outflow hydrograph response, with downstream concentrated building scenarios resulting in a delay in hydrograph onset time and a reduction in the time of the total outflow hydrograph event.

Calculating the spatio-temporal variability of bedrock exposure on seasonal hydrograph timescales as a prerequisite to modeling bedrock river evolution

NASA Astrophysics Data System (ADS)

Hurst, A. A.; Anderson, R. S.; Tucker, G. E.

2017-12-01

Erosion of bedrock river channels exerts significant control on landscape evolution because it communicates climatic and tectonic signals across a landscape by setting the lower erosional boundaries for hillslopes. Hillslope erosion delivers sediment to the channels, which then either store or transport the sediment. At times of high storage, access to the bedrock floor of the channel is limited, inhibiting bedrock erosion. This affects the timescale of channel response to imposed base-level lowering, which in turn affects hillslope erosion. Because occasional exposure of the bedrock bed is a minimum prerequisite for bedrock erosion, we seek to understand the evolution of sediment cover, or scour history, with sufficient resolution to answer when and where the bed is exposed. The scour history at a site is governed by grain size, bed and channel morphology, sediment concentration in the water, and seasonal flow conditions (hydrograph). The transient nature of bedrock exposure during high-flow events implies that short-term sediment cover dynamics are important for predicting long-term bedrock incision rates. Models of channel profile evolution, or of landscape evolution, generally ignore evolution of sediment cover on the hydrograph timescale. To develop insight into the necessary and sufficient conditions for bedrock exposure followed by reburial, we have developed a 1-D model of the evolution of alluvial cover thickness in a long channel profile in response to a seasonal hydrograph. This model tracks erosion, deposition, and the concentration of sediment in the water column separately, and generates histories of scour and fill over the course of the hydrograph. We compare the model's predictions with net-scour measurements in tributaries of the Grand Canyon and with scour-chain and accelerometer measurements in the Cedar River, Washington. By addressing alluvial scour on short timescales, we acknowledge the processes required to allow bedrock incision and landscape evolution over longer timescales.

A new approach for continuous estimation of baseflow using discrete water quality data: Method description and comparison with baseflow estimates from two existing approaches

USGS Publications Warehouse

Miller, Matthew P.; Johnson, Henry M.; Susong, David D.; Wolock, David M.

2015-01-01

Understanding how watershed characteristics and climate influence the baseflow component of stream discharge is a topic of interest to both the scientific and water management communities. Therefore, the development of baseflow estimation methods is a topic of active research. Previous studies have demonstrated that graphical hydrograph separation (GHS) and conductivity mass balance (CMB) methods can be applied to stream discharge data to estimate daily baseflow. While CMB is generally considered to be a more objective approach than GHS, its application across broad spatial scales is limited by a lack of high frequency specific conductance (SC) data. We propose a new method that uses discrete SC data, which are widely available, to estimate baseflow at a daily time step using the CMB method. The proposed approach involves the development of regression models that relate discrete SC concentrations to stream discharge and time. Regression-derived CMB baseflow estimates were more similar to baseflow estimates obtained using a CMB approach with measured high frequency SC data than were the GHS baseflow estimates at twelve snowmelt dominated streams and rivers. There was a near perfect fit between the regression-derived and measured CMB baseflow estimates at sites where the regression models were able to accurately predict daily SC concentrations. We propose that the regression-derived approach could be applied to estimate baseflow at large numbers of sites, thereby enabling future investigations of watershed and climatic characteristics that influence the baseflow component of stream discharge across large spatial scales.

SIMULATION OF FLOOD HYDROGRAPHS FOR GEORGIA STREAMS.

USGS Publications Warehouse

Inman, E.J.; Armbruster, J.T.

1986-01-01

Flood hydrographs are needed for the design of many highway drainage structures and embankments. A method for simulating these flood hydrographs at urban and rural ungauged sites in Georgia is presented. The O'Donnell method was used to compute unit hydrographs from 355 flood events from 80 stations. An average unit hydrograph and an average lag time were computed for each station. These average unit hydrographs were transformed to unit hydrographs having durations of one-fourth, one-third, one-half, and three-fourths lag time and then reduced to dimensionless terms by dividing the time by lag time and the discharge by peak discharge. Hydrographs were simulated for these 355 flood events and their widths were compared with the widths of the observed hydrographs at 50 and 75 percent of peak flow. For simulating hydrographs at sites larger than 500 mi**2, the U. S. Geological Survey computer model CONROUT can be used.

Tracing hydrologic pathways at the Panola Mountain research watershed, Georgia, USA

USGS Publications Warehouse

Peters, N.E.; Ratcliffe, E.B.

1997-01-01

An analysis of Cl- concentrations and fluxes at the Panola Mountain Research Watershed indicates that Cl- may be effectively used to differentiate 'new' and 'old' water flow through the hillslope and their respective contributions to streamwater. Rainfall and throughfall, the 'new' water inputs, are marked by low Cl- concentrations (15 ??eq 1-1). Stormwater moves rapidly to depth along preferred pathways in a deciduous forest hillslope, as evidenced by low concentrations (20 ??eq 1-1) in mobile soil water from zero-tension stainless-steel pan lysimeters. 'Old' waters, matrix soil waters and groundwater, typically have high concentrations (20 ??eq 1-1). Timing of soil water transport is not sufficiently rapid to suggest that soil water from the hillslope contributes to streamwater for an individual rainstorm. The source of streamflow, therefore, must be a combination of channel interception, runoff from near-channel areas, and runoff from a 3-ha bedrock outcrop in the headwaters. Groundwater contribution to streamflow was estimated using Cl- concentrations of throughfall and groundwater as the two end members for a two-component hydrograph separation. For the study period, groundwater contributed 79% of the runoff and from 1985 to 1995, contributed 75% of the runoff. Rainfall was the source of 45% of the Cl- flux from the watershed in the long term; the remaining Cl- is hypothesized to be derived from dry deposition, consistent with the enrichment noted for throughfall. At peak flow during individual rainstorms, 'new' water can contribute 95% of the runoff.

15 CFR 996.23 - Audit and decertification of hydrographic products.

Code of Federal Regulations, 2011 CFR

2011-01-01

... ASSURANCE AND CERTIFICATION REQUIREMENTS FOR NOAA HYDROGRAPHIC PRODUCTS AND SERVICES QUALITY ASSURANCE AND CERTIFICATION REQUIREMENTS FOR NOAA HYDROGRAPHIC PRODUCTS AND SERVICES Certification of a Hydrographic Product and Decertification. § 996.23 Audit and decertification of hydrographic products. (a) NOAA may audit...

15 CFR 996.23 - Audit and decertification of hydrographic products.

Code of Federal Regulations, 2013 CFR

2013-01-01

... ASSURANCE AND CERTIFICATION REQUIREMENTS FOR NOAA HYDROGRAPHIC PRODUCTS AND SERVICES QUALITY ASSURANCE AND CERTIFICATION REQUIREMENTS FOR NOAA HYDROGRAPHIC PRODUCTS AND SERVICES Certification of a Hydrographic Product and Decertification. § 996.23 Audit and decertification of hydrographic products. (a) NOAA may audit...

15 CFR 996.23 - Audit and decertification of hydrographic products.

Code of Federal Regulations, 2014 CFR

2014-01-01

... ASSURANCE AND CERTIFICATION REQUIREMENTS FOR NOAA HYDROGRAPHIC PRODUCTS AND SERVICES QUALITY ASSURANCE AND CERTIFICATION REQUIREMENTS FOR NOAA HYDROGRAPHIC PRODUCTS AND SERVICES Certification of a Hydrographic Product and Decertification. § 996.23 Audit and decertification of hydrographic products. (a) NOAA may audit...

15 CFR 996.23 - Audit and decertification of hydrographic products.

Code of Federal Regulations, 2012 CFR

2012-01-01

... ASSURANCE AND CERTIFICATION REQUIREMENTS FOR NOAA HYDROGRAPHIC PRODUCTS AND SERVICES QUALITY ASSURANCE AND CERTIFICATION REQUIREMENTS FOR NOAA HYDROGRAPHIC PRODUCTS AND SERVICES Certification of a Hydrographic Product and Decertification. § 996.23 Audit and decertification of hydrographic products. (a) NOAA may audit...

15 CFR 996.20 - Submission of a hydrographic product for certification.

Code of Federal Regulations, 2010 CFR

2010-01-01

... QUALITY ASSURANCE AND CERTIFICATION REQUIREMENTS FOR NOAA HYDROGRAPHIC PRODUCTS AND SERVICES QUALITY ASSURANCE AND CERTIFICATION REQUIREMENTS FOR NOAA HYDROGRAPHIC PRODUCTS AND SERVICES Certification of a Hydrographic Product and Decertification. § 996.20 Submission of a hydrographic product for certification. (a...

Temporal downscaling of decadal sediment load estimates to a daily interval for use in hindcast simulations

USGS Publications Warehouse

Ganju, N.K.; Knowles, N.; Schoellhamer, D.H.

2008-01-01

In this study we used hydrologic proxies to develop a daily sediment load time-series, which agrees with decadal sediment load estimates, when integrated. Hindcast simulations of bathymetric change in estuaries require daily sediment loads from major tributary rivers, to capture the episodic delivery of sediment during multi-day freshwater flow pulses. Two independent decadal sediment load estimates are available for the Sacramento/San Joaquin River Delta, California prior to 1959, but they must be downscaled to a daily interval for use in hindcast models. Daily flow and sediment load data to the Delta are available after 1930 and 1959, respectively, but bathymetric change simulations for San Francisco Bay prior to this require a method to generate daily sediment load estimates into the Delta. We used two historical proxies, monthly rainfall and unimpaired flow magnitudes, to generate monthly unimpaired flows to the Sacramento/San Joaquin Delta for the 1851-1929 period. This step generated the shape of the monthly hydrograph. These historical monthly flows were compared to unimpaired monthly flows from the modern era (1967-1987), and a least-squares metric selected a modern water year analogue for each historical water year. The daily hydrograph for the modern analogue was then assigned to the historical year and scaled to match the flow volume estimated by dendrochronology methods, providing the correct total flow for the year. We applied a sediment rating curve to this time-series of daily flows, to generate daily sediment loads for 1851-1958. The rating curve was calibrated with the two independent decadal sediment load estimates, over two distinct periods. This novel technique retained the timing and magnitude of freshwater flows and sediment loads, without damping variability or net sediment loads to San Francisco Bay. The time-series represents the hydraulic mining period with sustained periods of increased sediment loads, and a dramatic decrease after 1910, corresponding to a reduction in available mining debris. The analogue selection procedure also permits exploration of the morphological hydrograph concept, where a limited set of hydrographs is used to simulate the same bathymetric change as the actual set of hydrographs. The final daily sediment load time-series and morphological hydrograph concept will be applied as landward boundary conditions for hindcasting simulations of bathymetric change in San Francisco Bay.

Estimating flood hydrographs for urban basins in North Carolina

USGS Publications Warehouse

Mason, R.R.; Bales, J.D.

1996-01-01

A dimensionless hydrograph for North Carolina was developed from data collected in 29 urban and urbanizing basins in the State. The dimen- sionless hydrograph can be used with an estimate of peak flow and basin lagtime to synthesize a design flood hydrograph for urban basins in North Carolina. Peak flows can be estimated from a number of avail- able techniques; a procedure for estimating basin lagtime from main channel length, stream slope, and percentage of impervious area was developed from data collected at 50 sites and is presented in this report. The North Carolina dimensionless hydrograph provides satis- factory predictions of flood hydrographs in all regions of the State except for basins in or near Asheville where the method overestimated 11 of 12 measured hydrographs. A previously developed dimensionless hydrograph for urban basins in the Piedmont and upper Coastal Plain of South Carolina provides better flood-hydrograph predictions for the Asheville basins and has a standard error of 21 percent as compared to 41 percent for the North Carolina dimensionless hydrograph.

Man vs. Machine: An interactive poll to evaluate hydrological model performance of a manual and an automatic calibration

NASA Astrophysics Data System (ADS)

Wesemann, Johannes; Burgholzer, Reinhard; Herrnegger, Mathew; Schulz, Karsten

2017-04-01

In recent years, a lot of research in hydrological modelling has been invested to improve the automatic calibration of rainfall-runoff models. This includes for example (1) the implementation of new optimisation methods, (2) the incorporation of new and different objective criteria and signatures in the optimisation and (3) the usage of auxiliary data sets apart from runoff. Nevertheless, in many applications manual calibration is still justifiable and frequently applied. The hydrologist performing the manual calibration, with his expert knowledge, is able to judge the hydrographs simultaneously concerning details but also in a holistic view. This integrated eye-ball verification procedure available to man can be difficult to formulate in objective criteria, even when using a multi-criteria approach. Comparing the results of automatic and manual calibration is not straightforward. Automatic calibration often solely involves objective criteria such as Nash-Sutcliffe Efficiency Coefficient or the Kling-Gupta-Efficiency as a benchmark during the calibration. Consequently, a comparison based on such measures is intrinsically biased towards automatic calibration. Additionally, objective criteria do not cover all aspects of a hydrograph leaving questions concerning the quality of a simulation open. This contribution therefore seeks to examine the quality of manually and automatically calibrated hydrographs by interactively involving expert knowledge in the evaluation. Simulations have been performed for the Mur catchment in Austria with the rainfall-runoff model COSERO using two parameter sets evolved from a manual and an automatic calibration. A subset of resulting hydrographs for observation and simulation, representing the typical flow conditions and events, will be evaluated in this study. In an interactive crowdsourcing approach experts attending the session can vote for their preferred simulated hydrograph without having information on the calibration method that produced the respective hydrograph. Therefore, the result of the poll can be seen as an additional quality criterion for the comparison of the two different approaches and help in the evaluation of the automatic calibration method.

Peak flow estimation in ungauged basins by means of water level data analysis

NASA Astrophysics Data System (ADS)

Corato, G.; Moramarco, T.; Tucciarelli, T.

2009-04-01

Discharge hydrograph estimation in rivers is usually carried out by means of water level measurements and the use of a water depth - discharge relationship. The water depth - discharge curve is obtained by integrating local velocities measured in a given section at specified water depth values. To build up such curve is very expensive and very often the highest points, used for the peak flow estimation, are the result of rough extrapolation of points corresponding to much lower water depths. Recently, discharge estimation methodologies based only on the analysis of synchronous water level data recorded in two different river sections far some kilometers from each other have been developed. These methodologies are based only on the analysis of the water levels, the knowledge of the river bed elevations within the two sections, and the use of a diffusive flow routing numerical model. The bed roughness estimation, in terms of average Manning coefficient, is carried out along with the discharge hydrograph estimation. The 1D flow routing model is given by the following Saint Venant equations, simplified according to the diffusive hypothesis: ‚-+ ‚q-= 0 ‚t ‚x (1) ‚h+ (Sf - S0) = 0 ‚x (2) where q(x,t) is the discharge, h(x,t) is the water depth, Sf is the energy slope and S0 is the bed slope. The energy slope is related to the average n Manning coefficient by the Chezy relationship: -q2n2- Sf = 2ℜ4•3 (3) whereℜ is the hydraulic radius and gs the river section. The upstream boundary condition of the flow routing model is given by the measured upstream water level hydrograph. The computational domain is extended some kilometers downstream the second measurement section and the downstream boundary condition is properly approximated. This avoids the use of the downstream measured data for the solution of the system (1)-(3) and limits the model error even in the case of subcritical flow. The optimal average Manning coefficient is obtained by fitting the water level data available in the downstream measurement section with the computed ones. The optimal discharge hydrograph estimated in the upstream measurement section is given by the function q(0,t) computed in the first section (where x = 0) using the optimal Manning coefficient. Two different fitting quality criteria are compared and their practical implications are discussed; the first one is the equality of the computed and the measured time peak lag between the first and the second measurement section; the second one is the minimization of the total square error between the measured and the computed downstream water level hydrographs. The uniqueness and identifiability properties of the associated inverse problem are analyzed, and a model error analysis is carried out addressing the most relevant sources of error arising from the adopted approximations. Three case studies previously used for the validation of the proposed methodology are reviewed. The first two are water level hydrographs collected in two sections of the Arno river (Tuscany, Italy) and the Tiber river (Umbria, Italy). Water level and discharge hydrographs recorded during many storm events were available in both cases. The optimal average Manning coefficient has been estimated in both cases using the data of a single event, properly selected among all the available ones. In the third case, concerning hystorical data collected in a small tributary of the Tanagro river (Campania, Italy), three water level hydrographs were measured in three different sections of the channel. This allowed to carry on the discharge estimation using the data collected in only two of the three sections, using the data of the third one for validation. The results obtained in the three test cases highlight the advantages and the limits of the adopted analysis. The advantage is the simplicity of the hardware required for the data acquisition, that can be easily performed continuously in time, also during very bad weather conditions and using a long distance control. A first limit is the assumption of negligible inflow between the two measurement sections. Because the distance between the two sections must be large enough to measure the time lag between the two hydrographs, this limit can result in a difficult selection of the measurement sections. A second limit is the real heterogeneity of the bed roughness, that provides a shape of the water level hydrograph different from the computed one. Preliminary results of a new, multiparametric data analysis, are finally presented.

Probability distribution functions for unit hydrographs with optimization using genetic algorithm

NASA Astrophysics Data System (ADS)

Ghorbani, Mohammad Ali; Singh, Vijay P.; Sivakumar, Bellie; H. Kashani, Mahsa; Atre, Atul Arvind; Asadi, Hakimeh

2017-05-01

A unit hydrograph (UH) of a watershed may be viewed as the unit pulse response function of a linear system. In recent years, the use of probability distribution functions (pdfs) for determining a UH has received much attention. In this study, a nonlinear optimization model is developed to transmute a UH into a pdf. The potential of six popular pdfs, namely two-parameter gamma, two-parameter Gumbel, two-parameter log-normal, two-parameter normal, three-parameter Pearson distribution, and two-parameter Weibull is tested on data from the Lighvan catchment in Iran. The probability distribution parameters are determined using the nonlinear least squares optimization method in two ways: (1) optimization by programming in Mathematica; and (2) optimization by applying genetic algorithm. The results are compared with those obtained by the traditional linear least squares method. The results show comparable capability and performance of two nonlinear methods. The gamma and Pearson distributions are the most successful models in preserving the rising and recession limbs of the unit hydographs. The log-normal distribution has a high ability in predicting both the peak flow and time to peak of the unit hydrograph. The nonlinear optimization method does not outperform the linear least squares method in determining the UH (especially for excess rainfall of one pulse), but is comparable.

Techniques for simulating flood hydrographs and estimating flood volumes for ungaged basins in east and west Tennessee

USGS Publications Warehouse

Gamble, C.R.

1989-01-01

A dimensionless hydrograph developed for a variety of basin conditions in Georgia was tested for its applicability to streams in East and West Tennessee by comparing it to a similar dimensionless hydrograph developed for streams in East and West Tennessee. Hydrographs of observed discharge at 83 streams in East Tennessee and 38 in West Tennessee were used in the study. Statistical analyses were performed by comparing simulated (or computed) hydrographs, derived by application of the Georgia dimensionless hydrograph, and dimensionless hydrographs developed from Tennessee data, with the observed hydrographs at 50 and 75% of their peak-flow widths. Results of the tests indicate that the Georgia dimensionless hydrography is virtually the same as the one developed for streams in East Tennessee, but that it is different from the dimensionless hydrograph developed for streams in West Tennessee. Because of the extensive testing of the Georgia dimensionless hydrograph, it was determined to be applicable for East Tennessee, whereas the dimensionless hydrograph developed from data on streams in West Tennessee was determined to be applicable in West Tennessee. As part of the dimensionless hydrograph development, an average lagtime in hours for each study basin, and the volume in inches of flood runoff for each flood event were computed. By use of multiple-regression analysis, equations were developed that relate basin lagtime to drainage area size, basin length, and percent impervious area. Similarly, flood volumes were related to drainage area size, peak discharge, and basin lagtime. These equations, along with the appropriate dimensionless hydrograph, can be used to estimate a typical (average) flood hydrograph and volume for recurrence-intervals up to 100 years at any ungaged site draining less than 50 sq mi in East and West Tennessee. (USGS)

Simulation of flood hydrographs for Georgia streams

USGS Publications Warehouse

Inman, Ernest J.

1987-01-01

Flood hydrographs are needed for the design of many highway drainage structures and embankments. A method for simulating these flood hydrographs at ungaged sites in Georgia is presented in this report. The O'Donnell method was used to compute unit hydrographs and lagtimes for 355 floods at 80 gaging stations. An average unit hydrograph and an average lagtime were computed for each station. These average unit hydrographs were transformed to unit hydrographs having durations of one-fourth, one-third, one-half, and three-fourths lagtime, then reduced to dimensionless terms by dividing the time by lagtime and the discharge by peak discharge. Hydrographs were simulated for these 355 floods and their widths were compared with the widths of the observed hydrographs at 50 and 75 percent of peak flow. The dimensionless hydrograph based on one-half lagtime duration provided the best fit of the observed data. Multiple regression analysis was then used to define relations between lagtime and certain physical basin characteristics; of these characteristics, drainage area and slope were found to be significant for the rural-stream equations and drainage area, slope, and impervious area were found to be significant for the Atlanta urban-stream equation. A hydrograph can be simulated from the dimensionless hydrograph, the peak discharge of a specific recurrence interval, and the lagtime obtained from regression equations for any site in Georgia having a drainage area of less than 500 square miles. For simulating hydrographs at sites having basins larger than 500 square miles, the U.S. Geological Survey computer model CONROUT can be used. This model routes streamflow from an upstream channel location to a user-defined location downstream. The product of CONROUT is a simulated discharge hydrograph for the downstream site that has a peak discharge of a specific recurrence interval.

Diatoms as an indicator for tile drainage flow in a German lowland catchment.

PubMed

Wu, Naicheng; Faber, Claas; Ulrich, Uta; Fohrer, Nicola

2018-01-01

The separation of runoff components within a model simulation is of great importance for a successful implementation of management measures. Diatoms could be a promising indicator for tile drainage flow due to their diverse preferences to different aquatic habitats. In this study, we collected diatom samples of 9 sites (4 tile drainage, TD, and 5 river sites, Ri) in a German lowland catchment at a weekly or biweekly time step from March to July 2013 with the aim of testing the suitability of diatoms for tile drainage flow, which is typical for lowland catchment. Planothidium lanceolatum , Ulnaria biceps , and Navicula gregaria dominated in TD sites with relative abundances of 22.2, 21.5, and 10.9%, respectively. For Ri sites, the most abundant species was Navicula lanceolata (20.5%), followed by Ulnaria biceps (12.9%), Cyclotella meneghiniana (9.5%), and Planothidium lanceolatum (9.3%). Compared with Ri sites, TD had a lower diatom density, biomass, species richness, and percentage of Aquatic/Riparian diatoms (AqRi%). However, the proportion of Riparian diatoms (RiZo%) increased at TD. Indicator value method (IndVal) revealed that the two groups (Ri and TD) were characterized by different indicator species. Fifteen taxa, including Cocconeis placentula , Cyclotella meneghiniana , N. lanceolata , and U. biceps , were significant indicators for Ri sites. Planothidium lanceolatum , Achnanthidium minutissimum , and Navicula gregaria were significant indicators for TD sites. A pronounced variation was found in the species lists of diatom community between Ri and TD water body types associated with different indicator species. With respect to hydrograph separation, these findings highlight the suitability of diatoms as an indicator for tile drainage flow. However, spatial and temporal variations of diatoms should be considered in future surveys.

Desired future condition: Fish habitat in southwestern riparian-stream habitats

Treesearch

John N. Rinne

1996-01-01

Riparian ecosystems in the southwestern United States provide valuable habitats for many living organisms including native fishes. An analysis of habitat components important to native fishes was made based on the literature, case histories, and unpublished and observational data. Results suggest a natural, surface water hydrograph and lack of introduced species of...

Area contact networks and the spatio-temporal spread of infectious salmon anemia virus (ISAV) in Chile.

PubMed

Gustafson, L; Remmenga, M; Sandoval Del Valle, O; Ibarra, R; Antognoli, M; Gallardo, A; Rosenfeld, C; Doddis, J; Enriquez Sais, R; Bell, E; Lara Fica, M

2016-03-01

Area management, the coordination of production and biosecurity practices across neighboring farms, is an important disease control strategy in aquaculture. Area management in aquaculture escalated in prominence in response to outbreaks of infectious salmon anemia (ISA) internationally. Successes in disease control have been attributed to the separation achieved through area-level synchronized stocking, fallowing, movement restrictions, and fomite or pest control. Area management, however, is costly; often demanding extra biosecurity, lengthy or inconveniently timed fallows, and localization of equipment, personnel, and services. Yet, this higher-order organizational structure has received limited epidemiologic attention. Chile's National Fisheries and Aquaculture Service instigated area management practices in response to the 2007 emergence of ISA virus (ISAV). Longitudinal data simultaneously collected allowed retrospective evaluation of the impact of component tenets on virus control. Spatiotemporal analyses identified hydrographic linkages, shared ports, and fish transfers from areas with recent occurrence of ISAV as the strongest predictors of virus spread between areas, though specifics varied by ISAV type (here categorized as HPR0 for the non-virulent genotypes, and HPRv otherwise). Hydrographic linkages were most predictive in the period before implementation of enhanced biosecurity and fallowing regulations, suggesting that viral load can impact spread dynamics. HPR0 arose late in the study period, so few HPRv events were available by which to explore the hypothesis of HPR0 as progenitor of outbreaks. However, spatiotemporal patterns in HPRv occurrence were predictive of subsequent patterns in HPR0 detection, suggesting a parallel, or dependent, means of spread. Better data precision, breadth and consistency, common challenges for retrospective studies, could improve model fit; and, for HPR0, specification of diagnostic test accuracy would improve interpretation. Published by Elsevier B.V.

Seasonal and weekly variability of Atlantic inflow into the northern North Sea

NASA Astrophysics Data System (ADS)

Sheehan, Peter; Berx, Bee; Gallego, Alejandro; Hall, Rob; Heywood, Karen

2017-04-01

Quantifying the variability of Atlantic inflow is necessary for managing the North Sea ecosystem and for producing accurate models for forecasting, for example, oil spill trajectories. The JONSIS hydrographic section (2.23°W to 0° at 59.28°N) crosses the path of the main inflow of Atlantic water into the northwestern North Sea. 122 occupations between 1989 and 2015 are examined to determine the annual cycle of thermohaline-driven volume transport into the North Sea. Thermohaline transport is at a minimum (0.1 Sv) during winter when it is driven by a horizontal salinity gradient across a zonal bottom front; it is at a maximum (0.35 Sv) in early autumn when it is driven by a horizontal temperature gradient that develops across the same front. The amplitude of the annual cycle of temperature-driven transport (0.15 Sv) is bigger than the amplitude of the annual cycle of salinity-driven transport (0.025 Sv). The annual cycles are approximately six months out of phase. Our quantitative results are the first to be based on a long-term dataset, and we advance previous understanding by identifying a salinity-driven flow in winter. Week-to-week variability of the Atlantic inflow is examined from ten Seaglider occupations of the JONSIS section in October and November 2013. Tidal ellipses produced from glider dive-average current observations are in good agreement with ellipses produced from tide model predictions. Total transport is derived by referencing geostrophic shear to dive-average-current observations once the tidal component of the flow has been removed. Total transport through the section during the deployment (0.5-1 Sv) is bigger than the thermohaline component (0.1-0.2 Sv), suggesting non-thermohaline forcings (e.g. wind forcing) are important at that time of year. Thermohaline transport during the glider deployment is in agreement with the annual cycle derived from the long-term observations. The addition of the glider-derived barotropic current permits a more accurate estimate of the transport than is possible from long-term hydrographic monitoring, and enables the separation of barotropic and depth-varying components. These results refine our understanding of the variability of Atlantic inflow into the North Sea on key timescales, and of the contribution of frontal flow to shelf sea circulation.

Mathematical modeling of synthetic unit hydrograph case study: Citarum watershed

NASA Astrophysics Data System (ADS)

Islahuddin, Muhammad; Sukrainingtyas, Adiska L. A.; Kusuma, M. Syahril B.; Soewono, Edy

2015-09-01

Deriving unit hydrograph is very important in analyzing watershed's hydrologic response of a rainfall event. In most cases, hourly measures of stream flow data needed in deriving unit hydrograph are not always available. Hence, one needs to develop methods for deriving unit hydrograph for ungagged watershed. Methods that have evolved are based on theoretical or empirical formulas relating hydrograph peak discharge and timing to watershed characteristics. These are usually referred to Synthetic Unit Hydrograph. In this paper, a gamma probability density function and its variant are used as mathematical approximations of a unit hydrograph for Citarum Watershed. The model is adjusted with real field condition by translation and scaling. Optimal parameters are determined by using Particle Swarm Optimization method with weighted objective function. With these models, a synthetic unit hydrograph can be developed and hydrologic parameters can be well predicted.

A two-model hydrologic ensemble prediction of hydrograph: case study from the upper Nysa Klodzka river basin (SW Poland)

NASA Astrophysics Data System (ADS)

Niedzielski, Tomasz; Mizinski, Bartlomiej

2016-04-01

The HydroProg system has been elaborated in frame of the research project no. 2011/01/D/ST10/04171 of the National Science Centre of Poland and is steadily producing multimodel ensemble predictions of hydrograph in real time. Although there are six ensemble members available at present, the longest record of predictions and their statistics is available for two data-based models (uni- and multivariate autoregressive models). Thus, we consider 3-hour predictions of water levels, with lead times ranging from 15 to 180 minutes, computed every 15 minutes since August 2013 for the Nysa Klodzka basin (SW Poland) using the two approaches and their two-model ensemble. Since the launch of the HydroProg system there have been 12 high flow episodes, and the objective of this work is to present the performance of the two-model ensemble in the process of forecasting these events. For a sake of brevity, we limit our investigation to a single gauge located at the Nysa Klodzka river in the town of Klodzko, which is centrally located in the studied basin. We identified certain regular scenarios of how the models perform in predicting the high flows in Klodzko. At the initial phase of the high flow, well before the rising limb of hydrograph, the two-model ensemble is found to provide the most skilful prognoses of water levels. However, while forecasting the rising limb of hydrograph, either the two-model solution or the vector autoregressive model offers the best predictive performance. In addition, it is hypothesized that along with the development of the rising limb phase, the vector autoregression becomes the most skilful approach amongst the scrutinized ones. Our simple two-model exercise confirms that multimodel hydrologic ensemble predictions cannot be treated as universal solutions suitable for forecasting the entire high flow event, but their superior performance may hold only for certain phases of a high flow.

Assessment of the instantaneous unit hydrograph derived from the theory of topologically random networks

USGS Publications Warehouse

Karlinger, M.R.; Troutman, B.M.

1985-01-01

An instantaneous unit hydrograph (iuh) based on the theory of topologically random networks (topological iuh) is evaluated in terms of sets of basin characteristics and hydraulic parameters. Hydrographs were computed using two linear routing methods for each of two drainage basins in the southeastern United States and are the basis of comparison for the topological iuh's. Elements in the sets of basin characteristics for the topological iuh's are the number of first-order streams only, (N), or the nuber of sources together with the number of channel links in the topological diameter (N, D); the hydraulic parameters are values of the celerity and diffusivity constant. Sensitivity analyses indicate that the mean celerity of the internal links in the network is the critical hydraulic parameter for determining the shape of the topological iuh, while the diffusivity constant has minimal effect on the topological iuh. Asymptotic results (source-only) indicate the number of sources need not be large to approximate the topological iuh with the Weibull probability density function.

Uncertainty Assessment of Synthetic Design Hydrographs for Gauged and Ungauged Catchments

NASA Astrophysics Data System (ADS)

Brunner, Manuela I.; Sikorska, Anna E.; Furrer, Reinhard; Favre, Anne-Catherine

2018-03-01

Design hydrographs described by peak discharge, hydrograph volume, and hydrograph shape are essential for engineering tasks involving storage. Such design hydrographs are inherently uncertain as are classical flood estimates focusing on peak discharge only. Various sources of uncertainty contribute to the total uncertainty of synthetic design hydrographs for gauged and ungauged catchments. These comprise model uncertainties, sampling uncertainty, and uncertainty due to the choice of a regionalization method. A quantification of the uncertainties associated with flood estimates is essential for reliable decision making and allows for the identification of important uncertainty sources. We therefore propose an uncertainty assessment framework for the quantification of the uncertainty associated with synthetic design hydrographs. The framework is based on bootstrap simulations and consists of three levels of complexity. On the first level, we assess the uncertainty due to individual uncertainty sources. On the second level, we quantify the total uncertainty of design hydrographs for gauged catchments and the total uncertainty of regionalizing them to ungauged catchments but independently from the construction uncertainty. On the third level, we assess the coupled uncertainty of synthetic design hydrographs in ungauged catchments, jointly considering construction and regionalization uncertainty. We find that the most important sources of uncertainty in design hydrograph construction are the record length and the choice of the flood sampling strategy. The total uncertainty of design hydrographs in ungauged catchments depends on the catchment properties and is not negligible in our case.

Identification of Flood Reactivity Regions via the Functional Clustering of Hydrographs

NASA Astrophysics Data System (ADS)

Brunner, Manuela I.; Viviroli, Daniel; Furrer, Reinhard; Seibert, Jan; Favre, Anne-Catherine

2018-03-01

Flood hydrograph shapes contain valuable information on the flood-generation mechanisms of a catchment. To make good use of this information, we express flood hydrograph shapes as continuous functions using a functional data approach. We propose a clustering approach based on functional data for flood hydrograph shapes to identify a set of representative hydrograph shapes on a catchment scale and use these catchment-specific sets of representative hydrographs to establish regions of catchments with similar flood reactivity on a regional scale. We applied this approach to flood samples of 163 medium-size Swiss catchments. The results indicate that three representative hydrograph shapes sufficiently describe the hydrograph shape variability within a catchment and therefore can be used as a proxy for the flood behavior of a catchment. These catchment-specific sets of three hydrographs were used to group the catchments into three reactivity regions of similar flood behavior. These regions were not only characterized by similar hydrograph shapes and reactivity but also by event magnitudes and triggering event conditions. We envision these regions to be useful in regionalization studies, regional flood frequency analyses, and to allow for the construction of synthetic design hydrographs in ungauged catchments. The clustering approach based on functional data which establish these regions is very flexible and has the potential to be extended to other geographical regions or toward the use in climate impact studies.

Component flow processes at four streams in the Catskill Mountains, New York, analysed using episodic concentration/discharge relationship

USGS Publications Warehouse

Evans, C.; Davies, T.D.; Murdoch, Peter S.

1999-01-01

Plots of solute concentration against discharge have been used to relate stream hydrochemical variations to processes of flow generation, using data collected at four streams in the Catskill Mountains, New York, during the Episodic Response Project of the US Environmental Protection Agency. Results suggest that a two-component system of shallow and deep saturated subsurface flow, in which the two components respond simultaneously during hydrologic events, may be applicable to the study basins. Using a large natural sea-salt sodium input as a tracer for precipitation, it is argued that an additional distinction can be made between pre-event and event water travelling along the shallow subsurface flow path. Pre-event water is thought to be displaced by infiltrating event water, which becomes dominant on the falling limb of the hydrograph. Where, as appears to be the case for sulfate, a solute equilibrates rapidly within the soil, the pre-event-event water distinction is unimportant. However, for some solutes there are clear and consistent compositional differences between water from the two sources, evident as a hysteresis loop in concentration-discharge plots. Nitrate and acidity, in particular, appear to be elevated in event water following percolation through the organic horizon. Consequently, the most acidic, high nitrate conditions during an episode generally occur after peak discharge. A simple conceptual model of episode runoff generation is presented on the basis of these results.Plots of solute concentration against discharge have been used to relate stream hydrochemical variations to processes of flow generation, using data collected at four streams in the Catskill Mountains, New York, during the Episodic Response Project of the US Environmental Protection Agency. Results suggest that a two-component system of shallow and deep saturated subsurface flow, in which the two components respond simultaneously during hydrologic events, may be applicable to the study basins. Using a large natural sea-salt sodium input as a tracer for precipitation, it is argued that an additional distinction can be made between pre-event and event water travelling along the shallow subsurface flow path. Pre-event water is thought to be displaced by infiltrating event water, which becomes dominant on the falling limb of the hydrograph. Where, as appears to be the case for sulfate, a solute equilibrates rapidly within the soil, the pre-event - event water distinction is unimportant. However, for some solutes there are clear and consistent compositional differences between water from the two sources, evident as a hysteresis loop in concentration-discharge plots. Nitrate and acidity, in particular, appear to be elevated in event water following percolation through the organic horizon. Consequently, the most acidic, high nitrate conditions during an episode generally occur after peak discharge. A simple conceptual model of episode runoff generation is presented on the basis of these results.

Evaluating GCM land surface hydrology parameterizations by computing river discharges using a runoff routing model: Application to the Mississippi basin

NASA Technical Reports Server (NTRS)

Liston, G. E.; Sud, Y. C.; Wood, E. F.

1994-01-01

To relate general circulation model (GCM) hydrologic output to readily available river hydrographic data, a runoff routing scheme that routes gridded runoffs through regional- or continental-scale river drainage basins is developed. By following the basin overland flow paths, the routing model generates river discharge hydrographs that can be compared to observed river discharges, thus allowing an analysis of the GCM representation of monthly, seasonal, and annual water balances over large regions. The runoff routing model consists of two linear reservoirs, a surface reservoir and a groundwater reservoir, which store and transport water. The water transport mechanisms operating within these two reservoirs are differentiated by their time scales; the groundwater reservoir transports water much more slowly than the surface reservior. The groundwater reservior feeds the corresponding surface store, and the surface stores are connected via the river network. The routing model is implemented over the Global Energy and Water Cycle Experiment (GEWEX) Continental-Scale International Project Mississippi River basin on a rectangular grid of 2 deg X 2.5 deg. Two land surface hydrology parameterizations provide the gridded runoff data required to run the runoff routing scheme: the variable infiltration capacity model, and the soil moisture component of the simple biosphere model. These parameterizations are driven with 4 deg X 5 deg gridded climatological potential evapotranspiration and 1979 First Global Atmospheric Research Program (GARP) Global Experiment precipitation. These investigations have quantified the importance of physically realistic soil moisture holding capacities, evaporation parameters, and runoff mechanisms in land surface hydrology formulations.

Bivariate analysis of floods in climate impact assessments.

PubMed

Brunner, Manuela Irene; Sikorska, Anna E; Seibert, Jan

2018-03-01

Climate impact studies regarding floods usually focus on peak discharges and a bivariate assessment of peak discharges and hydrograph volumes is not commonly included. A joint consideration of peak discharges and hydrograph volumes, however, is crucial when assessing flood risks for current and future climate conditions. Here, we present a methodology to develop synthetic design hydrographs for future climate conditions that jointly consider peak discharges and hydrograph volumes. First, change factors are derived based on a regional climate model and are applied to observed precipitation and temperature time series. Second, the modified time series are fed into a calibrated hydrological model to simulate runoff time series for future conditions. Third, these time series are used to construct synthetic design hydrographs. The bivariate flood frequency analysis used in the construction of synthetic design hydrographs takes into account the dependence between peak discharges and hydrograph volumes, and represents the shape of the hydrograph. The latter is modeled using a probability density function while the dependence between the design variables peak discharge and hydrograph volume is modeled using a copula. We applied this approach to a set of eight mountainous catchments in Switzerland to construct catchment-specific and season-specific design hydrographs for a control and three scenario climates. Our work demonstrates that projected climate changes have an impact not only on peak discharges but also on hydrograph volumes and on hydrograph shapes both at an annual and at a seasonal scale. These changes are not necessarily proportional which implies that climate impact assessments on future floods should consider more flood characteristics than just flood peaks. Copyright © 2017. Published by Elsevier B.V.

Distillation process using microchannel technology

DOEpatents

Tonkovich, Anna Lee [Dublin, OH; Simmons, Wayne W [Dublin, OH; Silva, Laura J [Dublin, OH; Qiu, Dongming [Carbondale, IL; Perry, Steven T [Galloway, OH; Yuschak, Thomas [Dublin, OH; Hickey, Thomas P [Dublin, OH; Arora, Ravi [Dublin, OH; Smith, Amanda [Galloway, OH; Litt, Robert Dwayne [Westerville, OH; Neagle, Paul [Westerville, OH

2009-11-03

The disclosed invention relates to a distillation process for separating two or more components having different volatilities from a liquid mixture containing the components. The process employs microchannel technology for effecting the distillation and is particularly suitable for conducting difficult separations, such as the separation of ethane from ethylene, wherein the individual components are characterized by having volatilities that are very close to one another.

The Upper Mississippi River System—Topobathy

USGS Publications Warehouse

Stone, Jayme M.; Hanson, Jenny L.; Sattler, Stephanie R.

2017-03-23

The Upper Mississippi River System (UMRS), the navigable part of the Upper Mississippi and Illinois Rivers, is a diverse ecosystem that contains river channels, tributaries, shallow-water wetlands, backwater lakes, and flood-plain forests. Approximately 10,000 years of geologic and hydrographic history exist within the UMRS. Because it maintains crucial wildlife and fish habitats, the dynamic ecosystems of the Upper Mississippi River Basin and its tributaries are contingent on the adjacent flood plains and water-level fluctuations of the Mississippi River. Separate data for flood-plain elevation (lidar) and riverbed elevation (bathymetry) were collected on the UMRS by the U.S. Army Corps of Engineers’ (USACE) Upper Mississippi River Restoration (UMRR) Program. Using the two elevation datasets, the U.S. Geological Survey (USGS) Upper Midwest Environmental Sciences Center (UMESC) developed a systemic topobathy dataset.

A comparison of hydrographically and optically derived mixed layer depths

USGS Publications Warehouse

Zawada, D.G.; Zaneveld, J.R.V.; Boss, E.; Gardner, W.D.; Richardson, M.J.; Mishonov, A.V.

2005-01-01

Efforts to understand and model the dynamics of the upper ocean would be significantly advanced given the ability to rapidly determine mixed layer depths (MLDs) over large regions. Remote sensing technologies are an ideal choice for achieving this goal. This study addresses the feasibility of estimating MLDs from optical properties. These properties are strongly influenced by suspended particle concentrations, which generally reach a maximum at pycnoclines. The premise therefore is to use a gradient in beam attenuation at 660 nm (c660) as a proxy for the depth of a particle-scattering layer. Using a global data set collected during World Ocean Circulation Experiment cruises from 1988-1997, six algorithms were employed to compute MLDs from either density or temperature profiles. Given the absence of published optically based MLD algorithms, two new methods were developed that use c660 profiles to estimate the MLD. Intercomparison of the six hydrographically based algorithms revealed some significant disparities among the resulting MLD values. Comparisons between the hydrographical and optical approaches indicated a first-order agreement between the MLDs based on the depths of gradient maxima for density and c660. When comparing various hydrographically based algorithms, other investigators reported that inherent fluctuations of the mixed layer depth limit the accuracy of its determination to 20 m. Using this benchmark, we found a ???70% agreement between the best hydrographical-optical algorithm pairings. Copyright 2005 by the American Geophysical Union.

Mass-induced sea level variations in the Red Sea from GRACE, steric-corrected altimetry, in situ bottom pressure records, and hydrographic observations

NASA Astrophysics Data System (ADS)

Feng, W.; Lemoine, J.-M.; Zhong, M.; Hsu, H. T.

2014-08-01

An annual amplitude of ∼18 cm mass-induced sea level variations (SLV) in the Red Sea is detected from the Gravity Recovery and Climate Experiment (GRACE) satellites and steric-corrected altimetry from 2003 to 2011. The annual mass variations in the region dominate the mean SLV, and generally reach maximum in late January/early February. The annual steric component of the mean SLV is relatively small (<3 cm) and out of phase of the mass-induced SLV. In situ bottom pressure records at the eastern coast of the Red Sea validate the high mass variability observed by steric-corrected altimetry and GRACE. In addition, the horizontal water mass flux of the Red Sea estimated from GRACE and steric-corrected altimetry is validated by hydrographic observations.

Representative sets of design hydrographs for ungauged catchments: A regional approach using probabilistic region memberships

NASA Astrophysics Data System (ADS)

Brunner, Manuela Irene; Seibert, Jan; Favre, Anne-Catherine

2018-02-01

Traditional design flood estimation approaches have focused on peak discharges and have often neglected other hydrograph characteristics such as hydrograph volume and shape. Synthetic design hydrograph estimation procedures overcome this deficiency by jointly considering peak discharge, hydrograph volume, and shape. Such procedures have recently been extended to allow for the consideration of process variability within a catchment by a flood-type specific construction of design hydrographs. However, they depend on observed runoff time series and are not directly applicable in ungauged catchments where such series are not available. To obtain reliable flood estimates, there is a need for an approach that allows for the consideration of process variability in the construction of synthetic design hydrographs in ungauged catchments. In this study, we therefore propose an approach that combines a bivariate index flood approach with event-type specific synthetic design hydrograph construction. First, regions of similar flood reactivity are delineated and a classification rule that enables the assignment of ungauged catchments to one of these reactivity regions is established. Second, event-type specific synthetic design hydrographs are constructed using the pooled data divided by event type from the corresponding reactivity region in a bivariate index flood procedure. The approach was tested and validated on a dataset of 163 Swiss catchments. The results indicated that 1) random forest is a suitable classification model for the assignment of an ungauged catchment to one of the reactivity regions, 2) the combination of a bivariate index flood approach and event-type specific synthetic design hydrograph construction enables the consideration of event types in ungauged catchments, and 3) the use of probabilistic class memberships in regional synthetic design hydrograph construction helps to alleviate the problem of misclassification. Event-type specific synthetic design hydrograph sets enable the inclusion of process variability into design flood estimation and can be used as a compromise between single best estimate synthetic design hydrographs and continuous simulation studies.

Deciphering storm-event runoff behavior in a coastal plain watershed using chemical and physical hydrograph separation techniques

Treesearch

Timothy Callahan; Austin E. Morrison

2016-01-01

Interpreting storm-event runoff in coastal plain watersheds is challenging because of the space- and time-variable nature of different sources that contribute to stream flow. These flow vectors and the magnitude of water flux is dependent on the pre-storm soil moisture (as estimated from depth to water table) in the lower coastal plain (LCP) region.

Spatio-temporal dynamics of ocean conditions and forage taxa reveal regional structuring of seabird–prey relationships.

PubMed

Santora, Jarrod A; Schroeder, Isaac D; Field, John C; Wells, Brian K; Sydeman, William J

Studies of predator–prey demographic responses and the physical drivers of such relationships are rare, yet essential for predicting future changes in the structure and dynamics of marine ecosystems. Here, we hypothesize that predator–prey relationships vary spatially in association with underlying physical ocean conditions, leading to observable changes in demographic rates, such as reproduction. To test this hypothesis, we quantified spatio-temporal variability in hydrographic conditions, krill, and forage fish to model predator (seabird) demographic responses over 18 years (1990–2007). We used principal component analysis and spatial correlation maps to assess coherence among ocean conditions, krill, and forage fish, and generalized additive models to quantify interannual variability in seabird breeding success relative to prey abundance. The first principal component of four hydrographic measurements yielded an index that partitioned “warm/weak upwelling” and “cool/strong upwelling” years. Partitioning of krill and forage fish time series among shelf and oceanic regions yielded spatially explicit indicators of prey availability. Krill abundance within the oceanic region was remarkably consistent between years, whereas krill over the shelf showed marked interannual fluctuations in relation to ocean conditions. Anchovy abundance varied on the shelf, and was greater in years of strong stratification, weak upwelling and warmer temperatures. Spatio-temporal variability of juvenile forage fish co-varied strongly with each other and with krill, but was weakly correlated with hydrographic conditions. Demographic responses between seabirds and prey availability revealed spatially variable associations indicative of the dynamic nature of “predator–habitat” relationships. Quantification of spatially explicit demographic responses, and their variability through time, demonstrate the possibility of delineating specific critical areas where the implementation of protective measures could maintain functions and productivity of central place foraging predators.

Robust high-performance control for robotic manipulators

NASA Technical Reports Server (NTRS)

Seraji, Homayoun (Inventor)

1991-01-01

Model-based and performance-based control techniques are combined for an electrical robotic control system. Thus, two distinct and separate design philosophies have been merged into a single control system having a control law formulation including two distinct and separate components, each of which yields a respective signal component that is combined into a total command signal for the system. Those two separate system components include a feedforward controller and a feedback controller. The feedforward controller is model-based and contains any known part of the manipulator dynamics that can be used for on-line control to produce a nominal feedforward component of the system's control signal. The feedback controller is performance-based and consists of a simple adaptive PID controller which generates an adaptive control signal to complement the nominal feedforward signal.

Analysis of radiofrequency discharges in plasma

DOEpatents

Kumar, Devendra; McGlynn, Sean P.

1992-01-01

Separation of laser optogalvanic signals in plasma into two components: (1) an ionization rate change component, and (2) a photoacoustic mediated component. This separation of components may be performed even when the two components overlap in time, by measuring time-resolved laser optogalvanic signals in an rf discharge plasma as the rf frequency is varied near the electrical resonance peak of the plasma and associated driving/detecting circuits. A novel spectrometer may be constructed to make these measurements. Such a spectrometer would be useful in better understanding and controlling such processes as plasma etching and plasma deposition.

Radiocarbon (14C) Constraints On The Fraction Of Refractory Dissolved Organic Carbon In Primary Marine Aerosol From The Northwest Atlantic

NASA Astrophysics Data System (ADS)

Beaupre, S. R.; Kieber, D. J.; Keene, W. C.; Long, M. S.; Frossard, A. A.; Kinsey, J. D.; Duplessis, P.; Chang, R.; Maben, J. R.; Lu, X.; Zhu, Y.; Bisgrove, J.

2017-12-01

Nearly all organic carbon in seawater is dissolved (DOC), with more than 95% considered refractory based on modeled average lifetimes ( 16,000 years) and characteristically old bulk radiocarbon (14C) ages (4000 - 6000 years) that exceed the timescales of overturning circulation. Although this refractory dissolved organic carbon (RDOC) is present throughout the oceans as a major reservoir of the global carbon cycle, its sources and sinks are poorly constrained. Recently, RDOC was proposed to be removed from the oceans through adsorption onto the surfaces of rising bubble plumes produced by breaking waves, ejection into the atmosphere via bubble bursting as a component of primary marine aerosol (PMA), and subsequent oxidation in the atmosphere. To test this mechanism, we used natural abundance 14C (5730 ± 40 yr half-life) to trace the fraction of RDOC in PMA produced in a high capacity generator at two biologically-productive and two oligotrophic hydrographic stations in the Northwest Atlantic Ocean during a research cruise aboard the R/V Endeavor (Sep - Oct 2016). The 14C signatures of PMA separately generated day and night from near-surface (5 m) and deep (2500 m) seawater were compared with corresponding 14C signatures in seawater of near-surface dissolved inorganic carbon (DIC, a proxy for recently produced organic matter), bulk deep DOC (a proxy for RDOC), and near-surface bulk DOC. Results constrain the selectivity of PMA formation from RDOC in natural mixtures of recently produced and refractory DOC. The implications of these results for PMA formation and RDOC biogeochemistry will be discussed.

Baseflow and stormflow metal fluxes from two small agricultural catchments in the Coastal Plain of the Chesapeake Bay Basin, United States

USGS Publications Warehouse

Miller, C.V.; Foster, G.D.; Majedi, B.F.

2003-01-01

Annual yields (fluxes per unit area) of Al, Mn, Fe, Ni, Cd, Pb, Zn, Cu, Cr, Co, As and Se were estimated for two small non-tidal stream catchments on the Eastern Shore of the Chesapeake Bay, United States - a poorly drained dissected-upland watershed in the Nanticoke River Basin, and a well-drained feeder tributary in the lower reaches of the Chester River Basin. Both watersheds are dominated by agriculture. A hydrograph-separation technique was used to determine the baseflow and stormflow components of metal yields, thus providing important insights into the effects of hydrology and climate on the transport of metals. Concentrations of suspended-sediment were used as a less-costly proxy of metal concentrations which are generally associated with particles. Results were compared to other studies in Chesapeake Bay and to general trends in metal concentrations across the United States. The study documented a larger than background yield of Zn and Co from the upper Nanticoke River Basin and possibly enriched concentrations of As, Cd and Se from both the upper Nanticoke River and the Chesterville Branch (a tributary of the lower Chester River). The annual yield of total Zn from the Nanticoke River Basin in 1998 was 18,000 g/km2/a, and was two to three times higher than yields reported from comparable river basins in the region. Concentrations of Cd also were high in both basins when compared to crustal concentrations and to other national data, but were within reasonable agreement with other Chesapeake Bay studies. Thus, Cd may be enriched locally either in natural materials or from agriculture.

15 CFR 996.10 - Submission and selection of hydrographic products for the development of standards and compliance...

Code of Federal Regulations, 2011 CFR

2011-01-01

... ATMOSPHERIC ADMINISTRATION, DEPARTMENT OF COMMERCE QUALITY ASSURANCE AND CERTIFICATION REQUIREMENTS FOR NOAA HYDROGRAPHIC PRODUCTS AND SERVICES QUALITY ASSURANCE AND CERTIFICATION REQUIREMENTS FOR NOAA HYDROGRAPHIC...: Hydrographic Product Quality Assurance Program, Office of Coast Survey, NOAA, 1315 East West Highway, Silver...

15 CFR 996.12 - Development of standards compliance tests for a hydrographic product or class.

Code of Federal Regulations, 2011 CFR

2011-01-01

..., DEPARTMENT OF COMMERCE QUALITY ASSURANCE AND CERTIFICATION REQUIREMENTS FOR NOAA HYDROGRAPHIC PRODUCTS AND SERVICES QUALITY ASSURANCE AND CERTIFICATION REQUIREMENTS FOR NOAA HYDROGRAPHIC PRODUCTS AND SERVICES The... a hydrographic product or class. (a) NOAA shall work, to the extent practicable, through existing...

15 CFR 996.12 - Development of standards compliance tests for a hydrographic product or class.

Code of Federal Regulations, 2012 CFR

2012-01-01

..., DEPARTMENT OF COMMERCE QUALITY ASSURANCE AND CERTIFICATION REQUIREMENTS FOR NOAA HYDROGRAPHIC PRODUCTS AND SERVICES QUALITY ASSURANCE AND CERTIFICATION REQUIREMENTS FOR NOAA HYDROGRAPHIC PRODUCTS AND SERVICES The... a hydrographic product or class. (a) NOAA shall work, to the extent practicable, through existing...

15 CFR 996.10 - Submission and selection of hydrographic products for the development of standards and compliance...

Code of Federal Regulations, 2012 CFR

2012-01-01

... ATMOSPHERIC ADMINISTRATION, DEPARTMENT OF COMMERCE QUALITY ASSURANCE AND CERTIFICATION REQUIREMENTS FOR NOAA HYDROGRAPHIC PRODUCTS AND SERVICES QUALITY ASSURANCE AND CERTIFICATION REQUIREMENTS FOR NOAA HYDROGRAPHIC...: Hydrographic Product Quality Assurance Program, Office of Coast Survey, NOAA, 1315 East West Highway, Silver...

15 CFR 996.12 - Development of standards compliance tests for a hydrographic product or class.

Code of Federal Regulations, 2013 CFR

2013-01-01

..., DEPARTMENT OF COMMERCE QUALITY ASSURANCE AND CERTIFICATION REQUIREMENTS FOR NOAA HYDROGRAPHIC PRODUCTS AND SERVICES QUALITY ASSURANCE AND CERTIFICATION REQUIREMENTS FOR NOAA HYDROGRAPHIC PRODUCTS AND SERVICES The... a hydrographic product or class. (a) NOAA shall work, to the extent practicable, through existing...

15 CFR 996.10 - Submission and selection of hydrographic products for the development of standards and compliance...

Code of Federal Regulations, 2013 CFR

2013-01-01

... ATMOSPHERIC ADMINISTRATION, DEPARTMENT OF COMMERCE QUALITY ASSURANCE AND CERTIFICATION REQUIREMENTS FOR NOAA HYDROGRAPHIC PRODUCTS AND SERVICES QUALITY ASSURANCE AND CERTIFICATION REQUIREMENTS FOR NOAA HYDROGRAPHIC...: Hydrographic Product Quality Assurance Program, Office of Coast Survey, NOAA, 1315 East West Highway, Silver...

15 CFR 996.12 - Development of standards compliance tests for a hydrographic product or class.

Code of Federal Regulations, 2014 CFR

2014-01-01

..., DEPARTMENT OF COMMERCE QUALITY ASSURANCE AND CERTIFICATION REQUIREMENTS FOR NOAA HYDROGRAPHIC PRODUCTS AND SERVICES QUALITY ASSURANCE AND CERTIFICATION REQUIREMENTS FOR NOAA HYDROGRAPHIC PRODUCTS AND SERVICES The... a hydrographic product or class. (a) NOAA shall work, to the extent practicable, through existing...

15 CFR 996.10 - Submission and selection of hydrographic products for the development of standards and compliance...

Code of Federal Regulations, 2014 CFR

2014-01-01

... ATMOSPHERIC ADMINISTRATION, DEPARTMENT OF COMMERCE QUALITY ASSURANCE AND CERTIFICATION REQUIREMENTS FOR NOAA HYDROGRAPHIC PRODUCTS AND SERVICES QUALITY ASSURANCE AND CERTIFICATION REQUIREMENTS FOR NOAA HYDROGRAPHIC...: Hydrographic Product Quality Assurance Program, Office of Coast Survey, NOAA, 1315 East West Highway, Silver...

15 CFR 996.12 - Development of standards compliance tests for a hydrographic product or class.

Code of Federal Regulations, 2010 CFR

2010-01-01

..., DEPARTMENT OF COMMERCE QUALITY ASSURANCE AND CERTIFICATION REQUIREMENTS FOR NOAA HYDROGRAPHIC PRODUCTS AND SERVICES QUALITY ASSURANCE AND CERTIFICATION REQUIREMENTS FOR NOAA HYDROGRAPHIC PRODUCTS AND SERVICES The Quality Assurance Program for Hydrographic Products § 996.12 Development of standards compliance tests for...

15 CFR 996.10 - Submission and selection of hydrographic products for the development of standards and compliance...

Code of Federal Regulations, 2010 CFR

2010-01-01

... ATMOSPHERIC ADMINISTRATION, DEPARTMENT OF COMMERCE QUALITY ASSURANCE AND CERTIFICATION REQUIREMENTS FOR NOAA HYDROGRAPHIC PRODUCTS AND SERVICES QUALITY ASSURANCE AND CERTIFICATION REQUIREMENTS FOR NOAA HYDROGRAPHIC PRODUCTS AND SERVICES The Quality Assurance Program for Hydrographic Products § 996.10 Submission and...

15 CFR 996.13 - Determination of whether to offer certification for a hydrographic product or class.

Code of Federal Regulations, 2010 CFR

2010-01-01

... certification for a hydrographic product or class. 996.13 Section 996.13 Commerce and Foreign Trade Regulations..., DEPARTMENT OF COMMERCE QUALITY ASSURANCE AND CERTIFICATION REQUIREMENTS FOR NOAA HYDROGRAPHIC PRODUCTS AND SERVICES QUALITY ASSURANCE AND CERTIFICATION REQUIREMENTS FOR NOAA HYDROGRAPHIC PRODUCTS AND SERVICES The...

Identifying meaningful trends in Atlantic water temperature from sparse in situ hydrographic observations from the periphery of the Greenland Ice Sheet

NASA Astrophysics Data System (ADS)

Fenty, I. G.; Willis, J. K.; Rignot, E. J.

2016-12-01

Motivated by the need to understand the connection between the warming North Atlantic Ocean and increasing ice mass loss from the Greenland Ice Sheet, in 2015 we initiated "Oceans Melting Greenland" (OMG), a 5-year NASA sub-orbital mission. One component of OMG is a once-yearly sampling of full-depth vertical profiles of ocean temperature and salinity around Greenland's continental shelf at 250 locations. These measurements have the potential to provide an unprecedented view of ocean properties around Greenland, especially the warm, salty subsurface Atlantic Waters that have been implicated in tidewater glacier retreat, acceleration, and thinning. However, OMG'S ocean measurements are essentially large-scale synoptic snapshots of an ocean state whose characteristic scales of temporal and spatial variability around Greenland are largely unknown. In this talk we discuss how high-resolution numerical ocean modelling is being employed to quantitatively estimate the region's natural hydrographic variability for the dual purposes of (1) informing our pan-Greenland ocean sampling strategy and (2) informing our interpretation of temperature trends in the data. OMG hydrographic shelf data collected in ship-based CTDs (2015, 2016) and Airborne eXpendable CTDs (2016) will be examined in the context of this estimated ocean variability.

Two-component Gaussian core model: Strong-coupling limit, Bjerrum pairs, and gas-liquid phase transition.

PubMed

Frydel, Derek; Levin, Yan

2018-01-14

In the present work, we investigate a gas-liquid transition in a two-component Gaussian core model, where particles of the same species repel and those of different species attract. Unlike a similar transition in a one-component system with particles having attractive interactions at long separations and repulsive interactions at short separations, a transition in the two-component system is not driven solely by interactions but by a specific feature of the interactions, the correlations. This leads to extremely low critical temperature, as correlations are dominant in the strong-coupling limit. By carrying out various approximations based on standard liquid-state methods, we show that a gas-liquid transition of the two-component system poses a challenging theoretical problem.

Two-component Gaussian core model: Strong-coupling limit, Bjerrum pairs, and gas-liquid phase transition

NASA Astrophysics Data System (ADS)

Frydel, Derek; Levin, Yan

2018-01-01

In the present work, we investigate a gas-liquid transition in a two-component Gaussian core model, where particles of the same species repel and those of different species attract. Unlike a similar transition in a one-component system with particles having attractive interactions at long separations and repulsive interactions at short separations, a transition in the two-component system is not driven solely by interactions but by a specific feature of the interactions, the correlations. This leads to extremely low critical temperature, as correlations are dominant in the strong-coupling limit. By carrying out various approximations based on standard liquid-state methods, we show that a gas-liquid transition of the two-component system poses a challenging theoretical problem.

Precision laser surveying instrument using atmospheric turbulence compensation by determining the absolute displacement between two laser beam components

DOEpatents

Veligdan, James T.

1993-01-01

Atmospheric effects on sighting measurements are compensated for by adjusting any sighting measurements using a correction factor that does not depend on atmospheric state conditions such as temperature, pressure, density or turbulence. The correction factor is accurately determined using a precisely measured physical separation between two color components of a light beam (or beams) that has been generated using either a two-color laser or two lasers that project different colored beams. The physical separation is precisely measured by fixing the position of a short beam pulse and measuring the physical separation between the two fixed-in-position components of the beam. This precisely measured physical separation is then used in a relationship that includes the indexes of refraction for each of the two colors of the laser beam in the atmosphere through which the beam is projected, thereby to determine the absolute displacement of one wavelength component of the laser beam from a straight line of sight for that projected component of the beam. This absolute displacement is useful to correct optical measurements, such as those developed in surveying measurements that are made in a test area that includes the same dispersion effects of the atmosphere on the optical measurements. The means and method of the invention are suitable for use with either single-ended systems or a double-ended systems.

Circulation in the SAV, Shelf of Veracruz, Mexico

NASA Astrophysics Data System (ADS)

Zavala-Hidalgo, J.; Martinez-Lopez, B.; Fernandez-Eguiarte, A.; de Buen, R.; Rojas, J.

2007-05-01

Data from current meter, hydrographic measurements, and numerical modeling are analyzed to determine the circulation patterns in the Sistema Arrecifal Veracruzano (SAV), Veracruz, Mexico, region. Results show that the main forcing in the region is the along-coast wind stress component. Tides contribute with one order of magnitude less energy, during the fall-winter period. Two main regimes are identified: one between the coast and the 20 m isobath, with waters of large turbidity and small influence from rivers, and the other between the 20 m isobath and the external shelf, with clearer waters. Stratified water column with low temperature upwelled waters near the bottom are observed when southeasterly winds are present. Downwelling and southeastward currents are associated with northerly winds linked with northers.

Analysis of radiofrequency discharges in plasma

DOEpatents

Kumar, D.; McGlynn, S.P.

1992-08-04

Separation of laser optogalvanic signals in plasma into two components: (1) an ionization rate change component, and (2) a photoacoustic mediated component. This separation of components may be performed even when the two components overlap in time, by measuring time-resolved laser optogalvanic signals in an rf discharge plasma as the rf frequency is varied near the electrical resonance peak of the plasma and associated driving/detecting circuits. A novel spectrometer may be constructed to make these measurements. Such a spectrometer would be useful in better understanding and controlling such processes as plasma etching and plasma deposition. 15 figs.

A look inside 'black box' hydrograph separation models: A study at the hydrohill catchment

USGS Publications Warehouse

Kendall, C.; McDonnell, Jeffery J.; Gu, W.

2001-01-01

Runoff sources and dominant flowpaths are still poorly understood in most catchments; consequently, most hydrograph separations are essentially 'black box' models where only external information is used. The well-instrumented 490 m2 Hydrohill artificial grassland catchment located near Nanjing (China) was used to examine internal catchment processes. Since groundwater levels never reach the soil surface at this site, two physically distinct flowpaths can unambiguously be defined: surface and subsurface runoff. This study combines hydrometric, isotopic and geochemical approaches to investigating the relations between the chloride, silica, and oxygen isotopic compositions of subsurface waters and rainfall. During a 120 mm storm over a 24 h period in 1989, 55% of event water input infiltrated and added to soil water storage; the remainder ran off as infiltration-excess overland flow. Only about 3-5% of the pre-event water was displaced out of the catchment by in-storm rainfall. About 80% of the total flow was quickflow, and 10% of the total flow was pre-event water, mostly derived from saturated flow from deeper soils. Rain water with high ??18O values from the beginning of the storm appeared to be preferentially stored in shallow soils. Groundwater at the end of the storm shows a wide range of isotopic and chemical compositions, primarily reflecting the heterogeneous distribution of the new and mixed pore waters. High chloride and silica concentrations in quickflow runoff derived from event water indicate that these species are not suitable conservative tracers of either water sources or flowpaths in this catchment. Determining the proportion of event water alone does not constrain the possible hydrologic mechanisms sufficiently to distinguish subsurface and surface flowpaths uniquely, even in this highly controlled artificial catchment. We reconcile these findings with a perceptual model of stormflow sources and flowpaths that explicitly accounts for water, isotopic, and chemical mass balance. Copyright ?? 2001 John Wiley & Sons, Ltd.

Temporal variation of transit time of rainfall-runoff water and groundwater flow dynamics inferred by noble gasses concentration (SF6, CFCs) in a forested small catchment (Fukushima, Japan)

NASA Astrophysics Data System (ADS)

Sakakibara, Koichi; Tsujimura, Maki; Onda, Yuichi; Iwagami, Sho; Konuma, Ryohei; Sato, Yutaro

2016-04-01

Time variant transit time of water in catchments can fundamentally describe catchment function, controlling rainfall-runoff generation, groundwater flow pathway and water storage. Though rainstorm event has been recognized as active phase on catchment hydrology, accurate and precise time variance of water transit time and related water dynamics during rainstorm have not been well clarified yet. Here, in order to reveal temporal variation of mean transit time of groundwater and related hydrological processes in a forested small catchment during rainstorm event, periodic and intensive field observations (15 - 17th July 2015, rainfall of 100.8 mm in total) were conducted in Yamakiya district (Fukushima, Japan) from September 2014 to December 2015. Discharge volume, groundwater table and precipitation amount were measured in 10 minutes interval. Water samples were taken from groundwater, discharge water, soil water and precipitation for determination of stable isotopic compositions (δ18O, δ2H), inorganic solutes concentration and dissolved noble gasses concentration (CFC11, CFC12, CFC113, SF6) in water. Storm hydrograph and groundwater table clearly responded to rainfall event especially with more than 30 mm per day throughout monitoring period. According to SF6 concentration in water, the mean transit time of discharge water (perennial spring) showed 3 - 6.5 years in the no-rainfall period (steady state), but fluctuated from zero to 12.5 years in the rainstorm event with totally 100.8 mm (unsteady state). The mean transit time of discharge water dramatically altered from zero to 12.5 years from before to after the tentative hydrograph peak in the rising limb, indicating new water components were dominant before tentative hydrograph peak, whereas deep groundwater component with longer residence time contributed much to discharge after the tentative hydrograph peak. On the other hand, mean residence time of groundwater (water in 5 m well) ranged from 0.5 to 11.5 years during the rainstorm event, which followed temporal transit time variation of discharge water. Stable isotopic compositions and chloride ions as conservative tracers presented clear different signals between rainfall and discharge water, and chloride ion concentration in discharge water increased to as high as deeper groundwater (water in 20 m well) just after tentative hydrograph peak in the rising limb. Additionally, CFCs concentration especially in discharge water obviously decreased below the level of current atmospheric CFCs concentration. All of the facts suggest that the contribution of deep groundwater with longer residence time for the discharge water becomes significant at the jumping phase of runoff during intense rainfall, causing dynamic change of groundwater flow system in a catchment.

Springtime phytoplankton dynamics in Arctic Krossfjorden and Kongsfjorden (Spitsbergen) as a function of glacier proximity

NASA Astrophysics Data System (ADS)

Piquet, A. M.-T.; van de Poll, W. H.; Visser, R. J. W.; Wiencke, C.; Bolhuis, H.; Buma, A. G. J.

2014-04-01

The hydrographic properties of the Kongsfjorden-Krossfjorden system (79° N, Spitsbergen) are affected by Atlantic water incursions as well as glacier meltwater runoff. This results in strong physical gradients (temperature, salinity and irradiance) within the fjords. Here, we tested the hypothesis that glaciers affect phytoplankton dynamics as early as the productive spring bloom period. During two campaigns in 2007 (late spring) and 2008 (early spring) we studied hydrographic characteristics and phytoplankton variability along two transects in both fjords, using high-performance liquid chromatography (HPLC)-CHEMTAX pigment fingerprinting, molecular fingerprinting (denaturing gradient gel electrophoresis, or DGGE) and sequencing of 18S rRNA genes. The sheltered inner fjord locations remained colder during spring as opposed to the outer locations. Vertical light attenuation coefficients increased from early spring onwards, at all locations, but in particular at the inner locations. In late spring meltwater input caused stratification of surface waters in both fjords. The inner fjord locations were characterized by overall lower phytoplankton biomass. Furthermore HPLC-CHEMTAX data revealed that diatoms and Phaeocystis sp. were replaced by small nano- and picophytoplankton during late spring, coinciding with low nutrient availability. The innermost stations showed higher relative abundances of nano- and picophytoplankton throughout, notably of cyanophytes and cryptophytes. Molecular fingerprinting revealed a high similarity between inner fjord samples from early spring and late spring samples from all locations, while outer samples from early spring clustered separately. We conclude that glacier influence, mediated by early meltwater input, modifies phytoplankton biomass and composition already during the spring bloom period, in favor of low biomass and small cell size communities. This may affect higher trophic levels especially when regional warming further increases the period and volume of meltwater.

mizuRoute version 1: A river network routing tool for a continental domain water resources applications

USGS Publications Warehouse

Mizukami, Naoki; Clark, Martyn P.; Sampson, Kevin; Nijssen, Bart; Mao, Yixin; McMillan, Hilary; Viger, Roland; Markstrom, Steven; Hay, Lauren E.; Woods, Ross; Arnold, Jeffrey R.; Brekke, Levi D.

2016-01-01

This paper describes the first version of a stand-alone runoff routing tool, mizuRoute. The mizuRoute tool post-processes runoff outputs from any distributed hydrologic model or land surface model to produce spatially distributed streamflow at various spatial scales from headwater basins to continental-wide river systems. The tool can utilize both traditional grid-based river network and vector-based river network data. Both types of river network include river segment lines and the associated drainage basin polygons, but the vector-based river network can represent finer-scale river lines than the grid-based network. Streamflow estimates at any desired location in the river network can be easily extracted from the output of mizuRoute. The routing process is simulated as two separate steps. First, hillslope routing is performed with a gamma-distribution-based unit-hydrograph to transport runoff from a hillslope to a catchment outlet. The second step is river channel routing, which is performed with one of two routing scheme options: (1) a kinematic wave tracking (KWT) routing procedure; and (2) an impulse response function – unit-hydrograph (IRF-UH) routing procedure. The mizuRoute tool also includes scripts (python, NetCDF operators) to pre-process spatial river network data. This paper demonstrates mizuRoute's capabilities to produce spatially distributed streamflow simulations based on river networks from the United States Geological Survey (USGS) Geospatial Fabric (GF) data set in which over 54 000 river segments and their contributing areas are mapped across the contiguous United States (CONUS). A brief analysis of model parameter sensitivity is also provided. The mizuRoute tool can assist model-based water resources assessments including studies of the impacts of climate change on streamflow.

Evaluating the use of in-situ turbidity measurements to quantify fluvial sediment and phosphorus concentrations and fluxes in agricultural streams.

PubMed

Stutter, Marc; Dawson, Julian J C; Glendell, Miriam; Napier, Fiona; Potts, Jacqueline M; Sample, James; Vinten, Andrew; Watson, Helen

2017-12-31

Accurate quantification of suspended sediments (SS) and particulate phosphorus (PP) concentrations and loads is complex due to episodic delivery associated with storms and management activities often missed by infrequent sampling. Surrogate measurements such as turbidity can improve understanding of pollutant behaviour, providing calibrations can be made cost-effectively and with quantified uncertainties. Here, we compared fortnightly and storm intensive water quality sampling with semi-continuous turbidity monitoring calibrated against spot samples as three potential methods for determining SS and PP concentrations and loads in an agricultural catchment over two-years. In the second year of sampling we evaluated the transferability of turbidity calibration relationships to an adjacent catchment with similar soils and land cover. When data from nine storm events were pooled, both SS and PP concentrations (all in log space) were better related to turbidity than they were to discharge. Developing separate calibration relationship for the rising and falling limbs of the hydrograph provided further improvement. However, the ability to transfer calibrations between adjacent catchments was not evident as the relationships of both SS and PP with turbidity differed both in gradient and intercept on the rising limb of the hydrograph between the two catchments. We conclude that the reduced uncertainty in load estimation derived from the use of turbidity as a proxy for specific water quality parameters in long-term regulatory monitoring programmes, must be considered alongside the increased capital and maintenance costs of turbidity equipment, potentially noisy turbidity data and the need for site-specific prolonged storm calibration periods. Copyright © 2017 Elsevier B.V. All rights reserved.

Estimating basin lagtime and hydrograph-timing indexes used to characterize stormflows for runoff-quality analysis

USGS Publications Warehouse

Granato, Gregory E.

2012-01-01

A nationwide study to better define triangular-hydrograph statistics for use with runoff-quality and flood-flow studies was done by the U.S. Geological Survey (USGS) in cooperation with the Federal Highway Administration. Although the triangular hydrograph is a simple linear approximation, the cumulative distribution of stormflow with a triangular hydrograph is a curvilinear S-curve that closely approximates the cumulative distribution of stormflows from measured data. The temporal distribution of flow within a runoff event can be estimated using the basin lagtime, (which is the time from the centroid of rainfall excess to the centroid of the corresponding runoff hydrograph) and the hydrograph recession ratio (which is the ratio of the duration of the falling limb to the rising limb of the hydrograph). This report documents results of the study, methods used to estimate the variables, and electronic files that facilitate calculation of variables. Ten viable multiple-linear regression equations were developed to estimate basin lagtimes from readily determined drainage basin properties using data published in 37 stormflow studies. Regression equations using the basin lag factor (BLF, which is a variable calculated as the main-channel length, in miles, divided by the square root of the main-channel slope in feet per mile) and two variables describing development in the drainage basin were selected as the best candidates, because each equation explains about 70 percent of the variability in the data. The variables describing development are the USGS basin development factor (BDF, which is a function of the amount of channel modifications, storm sewers, and curb-and-gutter streets in a basin) and the total impervious area variable (IMPERV) in the basin. Two datasets were used to develop regression equations. The primary dataset included data from 493 sites that have values for the BLF, BDF, and IMPERV variables. This dataset was used to develop the best-fit regression equation using the BLF and BDF variables. The secondary dataset included data from 896 sites that have values for the BLF and IMPERV variables. This dataset was used to develop the best-fit regression equation using the BLF and IMPERV variables. Analysis of hydrograph recession ratios and basin characteristics for 41 sites indicated that recession ratios are random variables. Thus, recession ratios cannot be estimated quantitatively using multiple linear regression equations developed using the data available for these sites. The minimums of recession ratios for different streamgages are well characterized by a value of one. The most probable values and maximum values of recession ratios for different streamgages are, however, more variable than the minimums. The most probable values of recession ratios for the 41 streamgages analyzed ranged from 1.0 to 3.52 and had a median of 1.85. The maximum values ranged from 2.66 to 11.3 and had a median of 4.36.

Separation of Trend and Chaotic Components of Time Series and Estimation of Their Characteristics by Linear Splines

NASA Astrophysics Data System (ADS)

Kryanev, A. V.; Ivanov, V. V.; Romanova, A. O.; Sevastyanov, L. A.; Udumyan, D. K.

2018-03-01

This paper considers the problem of separating the trend and the chaotic component of chaotic time series in the absence of information on the characteristics of the chaotic component. Such a problem arises in nuclear physics, biomedicine, and many other applied fields. The scheme has two stages. At the first stage, smoothing linear splines with different values of smoothing parameter are used to separate the "trend component." At the second stage, the method of least squares is used to find the unknown variance σ2 of the noise component.

Quantitative characterization of solid epoxy resins using comprehensive two dimensional liquid chromatography coupled with electrospray ionization-time of flight mass spectrometry.

PubMed

Julka, Samir; Cortes, Hernan; Harfmann, Robert; Bell, Bruce; Schweizer-Theobaldt, Andreas; Pursch, Matthias; Mondello, Luigi; Maynard, Shawn; West, David

2009-06-01

A comprehensive multidimensional liquid chromatography system coupled to Electrospray Ionization-Mass Spectrometry (LCxLC-ESI-MS) was developed for detailed characterization and quantitation of solid epoxy resin components. The two orthogonal modes of separation selected were size exclusion chromatography (SEC) in the first dimension and liquid chromatography at critical conditions (LCCC) in the second dimension. Different components present in the solid epoxy resins were separated and quantitated for the first time based on the functional groups and molecular weight heterogeneity. Coupling LCxLC separations with mass spectrometry enabled the identification of components resolved in the two-dimensional space. Several different functional group families of compounds were separated and identified, including epoxy-epoxy and epoxy-alpha-glycol functional oligomers, and their individual molecular weight ranges were determined. Repeatability obtained ranged from 0.5% for the main product to 21% for oligomers at the 0.4% concentration level.

Ground-water levels in the alluvial aquifer at Louisville, Kentucky, 1982-87

USGS Publications Warehouse

Faust, R.J.; Lyverse, M.A.

1987-01-01

Water level data have been collected in the alluvial aquifer at Louisville, Kentucky by the U.S. Geological Survey since 1943. Interpretations of these data have been published in several reports by the Survey, but none have been published since 1983. Contour maps and hydrographs are presented in this report to document and to help interpret water level changes for the period 1982-87. Maps and hydrographs show that groundwater levels generally stabilized in the 1980 's after rising for many years. Two areas of groundwater withdrawals are apparent in the maps and hydrographs. Withdrawals in an industrial area in west Louisville disrupt the typical pattern of the contours to curve landward around the area of withdrawal. Resumption of pumping of groundwater for heating and cooling of some buildings in the downtown area in 1985 caused declines of about 3 to 4 ft in the downtown area. (Author 's abstract)

On river-floodplain interaction and hydrograph skewness

NASA Astrophysics Data System (ADS)

Fleischmann, Ayan S.; Paiva, Rodrigo C. D.; Collischonn, Walter; Sorribas, Mino V.; Pontes, Paulo R. M.

2016-10-01

Understanding hydrological processes occurring within a basin by looking at its outlet hydrograph can improve and foster comprehension of ungauged regions. In this context, we present an extensive examination of the roles that floodplains play on driving hydrograph shapes. Observations of many river hydrographs with large floodplain influence are carried out and indicate that a negative skewness of the hydrographs is present among many of them. Through a series of numerical experiments and analytical reasoning, we show how the relationship between flood wave celerity and discharge in such systems is responsible for determining the hydrograph shapes. The more water inundates the floodplains upstream of the observed point, the more negatively skewed is the observed hydrograph. A case study is performed in the Amazon River Basin, where major rivers with large floodplain attenuation (e.g., Purus, Madeira, and Juruá) are identified with higher negative skewness in the respective hydrographs. Finally, different wetland types could be distinguished by using this feature, e.g., wetlands maintained by endogenous processes, from wetlands governed by overbank flow (along river floodplains). A metric of hydrograph skewness was developed to quantify this effect, based on the time derivative of discharge. Together with the skewness concept, it may be used in other studies concerning the relevance of floodplain attenuation in large, ungauged rivers, where remote sensing data (e.g., satellite altimetry) can be very useful.

Performance Analysis of Low-Cost Single-Frequency GPS Receivers in Hydrographic Surveying

NASA Astrophysics Data System (ADS)

Elsobeiey, M.

2017-10-01

The International Hydrographic Organization (IHO) has issued standards that provide the minimum requirements for different types of hydrographic surveys execution to collect data to be used to compile navigational charts. Such standards are usually updated from time to time to reflect new survey techniques and practices and must be achieved to assure both surface navigation safety and marine environment protection. Hydrographic surveys can be classified to four orders namely, special order, order 1a, order 1b, and order 2. The order of hydrographic surveys to use should be determined in accordance with the importance to the safety of navigation in the surveyed area. Typically, geodetic-grade dual-frequency GPS receivers are utilized for position determination during data collection in hydrographic surveys. However, with the evolution of high-sensitivity low-cost single-frequency receivers, it is very important to evaluate the performance of such receivers. This paper investigates the performance of low-cost single-frequency GPS receivers in hydrographic surveying applications. The main objective is to examine whether low-cost single-frequency receivers fulfil the IHO standards for hydrographic surveys. It is shown that the low-cost single-frequency receivers meet the IHO horizontal accuracy for all hydrographic surveys orders at any depth. However, the single-frequency receivers meet only order 2 requirements for vertical accuracy at depth more than or equal 100 m.

Rainfall-Driven Diffusive Hydrograph and Runoff Model for Two Sub-Basins within the Arroyo Colorado in South Texas.

NASA Astrophysics Data System (ADS)

Ball, M. C.; Al-Qudah, O.; Jones, K.

2017-12-01

The Arroyo Colorado, located within the Rio Grande Valley of South Texas, has been on the list for the State of Texas's most impaired rivers since the 1990's. Few models for the watershed discharge and contaminates transport have been developed, but all require specialized understanding of modeling and input data which must either be assumed, estimated or which is difficult, time-consuming and expensive to collect. It makes sense to see if a general, simpler `catchment-scale' lumping model would be feasible to model water discharge along the Arroyo. Due to its simplicity and the hypothesized diffusive nature of the drainage in the alluvial floodplain deposits of the Arroyo watershed, the Criss and Winston model was chosen for this study. Hydrographs were characterized, clearly demonstrating that the discharge to the Arroyo is greatly affected by precipitation, and which provided clear rain events for evaluation: 62 rain events over a ten-year time span (2007 - 2017) were selected. Best fit curves using the Criss and Winston lag time were plotted, but better fitting curves were created by modifying the Criss and Winston lag time which improved the fit for the rising limb portion of the hydrograph but had no effect on the receding limb portion of the graph. This model provided some insights into the nature of water transport along the Arroyo within two separate sub-basins: El Fuste and Harlingen. The value for the apparent diffusivity constant "b", a constant which encompasses all diffusive characteristics of the watershed or sub-basins in the watershed (i.e. the lumping constant), was calculated to be 0.85 and 0.93 for El Fuste and Harlingen, respectively, indicating that each sub-basin within the watershed is somewhat unique. Due to the lumping nature of the "b" constant, no specific factor can be attributed to this difference. More research could provide additional insight. It is suggested that water diffusion takes longer in the Harlingen sub-basin (larger "b") not only because its sub-basin is larger than El Fuste's, but also because Harlingen is a larger city with more impervious surfaces and a more developed stormwater distribution system - all of which likely delay the time it takes rain to percolate into the ground.

Characterization and Fate of Dissolved Organic Matter in the Lena Delta Region, Siberia

NASA Astrophysics Data System (ADS)

Goncalves-Araujo, R.; Stedmon, C. A.; Heim, B.; Dubinenkov, I.; Kraberg, A.; Moiseev, D.; Bracher, A.

2016-02-01

Connectivity between the terrestrial and marine environment in the Artic is changing as a result of climate change, influencing both freshwater budgets and the supply of carbon to the sea. This study characterizes the optical properties of dissolved organic matter (DOM) within the Lena Delta region and evaluates the behavior of DOM across the fresh water-marine gradient. Six fluorescent components (four humic-like; one marine humic-like; one protein-like) were identified by Parallel Factor Analysis (PARAFAC) with a clear dominance of allochthonous humic-like signals. Colored DOM (CDOM) and dissolved organic carbon (DOC) were highly correlated and had their distribution coupled with hydrographical conditions. Higher DOM concentration and degree of humification were associated with the low salinity waters of the Lena River. Values decreased towards the higher salinity Laptev Sea shelf waters. Results demonstrate different responses of DOM mixing in relation to the vertical structure of the water column, as reflecting the hydrographical dynamics in the region. Two mixing curves for DOM were apparent. In surface waters above the pycnocline there was a sharper decrease in DOM concentration in relation to salinity indicating removal. In the bottom water layer the DOM decrease within salinity was less. We propose there is a removal of DOM occurring primarily at the surface layer, which is likely driven by photodegradation and flocculation.

Using Emergent and Internal Catchment Data to Elucidate the Influence of Landscape Structure and Storage State on Hydrologic Response in a Piedmont Watershed

NASA Astrophysics Data System (ADS)

Putnam, S. M.; Harman, C. J.

2017-12-01

Many studies have sought to unravel the influence of landscape structure and catchment state on the quantity and composition of water at the catchment outlet. These studies run into issues of equifinality where multiple conceptualizations of flow pathways or storage states cannot be discriminated against on the basis of the quantity and composition of water alone. Here we aim to parse out the influence of landscape structure, flow pathways, and storage on both the observed catchment hydrograph and chemograph, using hydrometric and water isotope data collected from multiple locations within Pond Branch, a 37-hectare Piedmont catchment of the eastern US. This data is used to infer the quantity and age distribution of water stored and released by individual hydrogeomorphic units, and the catchment as a whole, in order to test hypotheses relating landscape structure, flow pathways, and catchment storage to the hydrograph and chemograph. Initial hypotheses relating internal catchment properties or processes to the hydrograph or chemograph are formed at the catchment scale. Data from Pond Branch include spring and catchment discharge measurements, well water levels, and soil moisture, as well as three years of high frequency precipitation and surface water stable water isotope data. The catchment hydrograph is deconstructed using hydrograph separation and the quantity of water associated with each time-scale of response is compared to the quantity of discharge that could be produced from hillslope and riparian hydrogeomorphic units. Storage is estimated for each hydrogeomorphic unit as well as the vadose zone, in order to construct a continuous time series of total storage, broken down by landscape unit. Rank StorAge Selection (rSAS) functions are parameterized for each hydrogeomorphic unit as well as the catchment as a whole, and the relative importance of changing proportions of discharge from each unit as well as storage in controlling the variability in the catchment chemograph is explored. The results suggest that the quantity of quickflow can be accounted for by direct precipitation onto < 5.2% of the catchment area, representing a zero-order swale plus the riparian area. rSAS modeling suggests that quickflow is largely composed of pre-event, stored water, generated through a process such as groundwater ridging.

Reach-Scale Channel Adjustments to Channel Network Geometry in Mountain Bedrock Streams

NASA Astrophysics Data System (ADS)

Plitzuweit, S. J.; Springer, G. S.

2008-12-01

Channel network geometry (CNG) is a critical determinant of hydrological response and may significantly affect incision processes within the Appalachian Plateau near Richwood, West Virginia. The Williams, Cherry, and Cranberry Rivers share drainage divides and their lower reaches flow atop resistant, quartz-rich sandstones. The lower two-thirds of the Cranberry and Williams Rivers display linear profiles atop the sandstones; whereas the Cherry is concave upwards atop the sandstones. Because lithologies and geological structures are similar among the watersheds, we tested whether differences in CNGs explain the profile shapes and reach-scale channel properties. Specifically, we quantified CNG by calculating reach- specific area-distance functions using DEMs. The area-distance functions were then converted into synthetic hydrographs to model hydrological responses. The Cherry River exhibits a classic dendritic drainage pattern, producing peaked hydrographs and low interval transit times. The Cranberry River displays a trellis-like drainage pattern, which produces attenuated hydrographs and high interval transit times. The upstream reaches of the Williams River have a dendritic drainage pattern, but the lower two-thirds of the watershed transitions into an elongated basin with trellis-like CNG. Reach gradients are steeper in the lower reaches of the Williams and Cranberry Rivers where hydrographs are attenuated. In contrast, peaked hydrographs within the Cherry River are associated with lower reach gradients despite resistant sandstone channel beds. Trellis-like CNG may restrict the ability of downstream reaches within the Williams and Cranberry Rivers to achieve the critical discharge needed to cause incision during floods (all other things being equal). If so, increased reach gradients may be hydraulic adjustments that compensate for comparatively low discharges. We are now applying the synthetic hydrographs to HEC-RAS flow models generated from field channel surveys in order to analyze whether stream power and shear stress are adjusted to reflect CNG at the reach- scale. These models are compared to those with discharges calculated using drainage area and precipitation totals alone. We conclude that gradients in bedrock mountain streams may reflect basin-scale hydrology (CNG) and not simply local geological or geomorphic factors. This challenges the conclusions of others who ascribe local channel adjustments to: i) lithology and structure alone, or ii) local colluvium grain sizes.

Onsager vortex formation in two-component Bose–Einstein condensates in two-dimensional traps

NASA Astrophysics Data System (ADS)

Han, Junsik; Tsubota, Makoto

2018-03-01

We study numerically the dynamics of quantized vortices in two-dimensional one-component and two-component Bose–Einstein condensates (BECs) trapped by a harmonic and box potentials. In two-component miscible BECs, we confirmed the tendency of the formation of Onsager vortices in both traps. The vortices in one component separate spatially from those in the other component, which comes from their intercomponent-coupling. We also discuss the decay of the number of vortices.

On the Relationship Between Transfer Function-derived Response Times and Hydrograph Analysis Timing Parameters: Are there Similarities?

NASA Astrophysics Data System (ADS)

Bansah, S.; Ali, G.; Haque, M. A.; Tang, V.

2017-12-01

The proportion of precipitation that becomes streamflow is a function of internal catchment characteristics - which include geology, landscape characteristics and vegetation - and influence overall storage dynamics. The timing and quantity of water discharged by a catchment are indeed embedded in event hydrographs. Event hydrograph timing parameters, such as the response lag and time of concentration, are important descriptors of how long it takes the catchment to respond to input precipitation and how long it takes the latter to filter through the catchment. However, the extent to which hydrograph timing parameters relate to average response times derived from fitting transfer functions to annual hydrographs is unknown. In this study, we used a gamma transfer function to determine catchment average response times as well as event-specific hydrograph parameters across a network of eight nested watersheds ranging from 0.19 km2 to 74.6 km2 prairie catchments located in south central Manitoba (Canada). Various statistical analyses were then performed to correlate average response times - estimated using the parameters of the fitted gamma transfer function - to event-specific hydrograph parameters. Preliminary results show significant interannual variations in response times and hydrograph timing parameters: the former were in the order of a few hours to days, while the latter ranged from a few days to weeks. Some statistically significant relationships were detected between response times and event-specific hydrograph parameters. Future analyses will involve the comparison of statistical distributions of event-specific hydrograph parameters with that of runoff response times and baseflow transit times in order to quantity catchment storage dynamics across a range of temporal scales.

15 CFR 996.22 - Certification.

Code of Federal Regulations, 2010 CFR

2010-01-01

... AND ATMOSPHERIC ADMINISTRATION, DEPARTMENT OF COMMERCE QUALITY ASSURANCE AND CERTIFICATION REQUIREMENTS FOR NOAA HYDROGRAPHIC PRODUCTS AND SERVICES QUALITY ASSURANCE AND CERTIFICATION REQUIREMENTS FOR NOAA HYDROGRAPHIC PRODUCTS AND SERVICES Certification of a Hydrographic Product and Decertification...

Hursh CR and Brater EF (1941) separating storm-hydrographs from small drainage-areas into surface- and subsurface-flow. Transactions, American Geophysical Union 22:863-871

Treesearch

T.P. Burt; W.T. Swank

2010-01-01

The Coweeta Hydrologic Laboratory was established in 1934 (originally known as the ‘Coweeta Experimental Forest’). A symposium to celebrate its 75th anniversary in 2009 was an opportunity to acknowledge that some of the world’s most important long-term research in forest hydrology and ecology has been conducted there (Swank and Vose, 2009).

Environmental Assessment for Changes to Reveille Airspace at Nevada Test and Training Range Nellis Air Force Base, Nevada

DTIC Science & Technology

2002-03-01

basin and range characteristics associated with the Great Basin . The base elevation of the area is 5000 feet above Mean Sea Level (MSL) to 6000 MSL...REVEILLE AIRSPACE AT NEVADA TEST AND TRAINING RANGE The area is located within the Great Basin , a physiographic region with no external drainage...characterized by “ basin and range” topography, in which hydrographically isolated basins or valleys are separated by north-south trending low mountain

Hydrological Signature From River-Floodplain Interactions

NASA Astrophysics Data System (ADS)

Paiva, R. C. D.; Fleischmann, A. S.; Collischonn, W.; Sorribas, M.; Pontes, P. R.

2015-12-01

Understanding river-floodplain hydraulic processes is fundamental to promote comprehension of related water paths, biogeochemicalcyclesand ecosystems. Large river basins around the globe present enormous developed floodplains, which strongly affect flood waves and water dynamics. Since most of these river-floodplain interactions are not monitored, it is interesting to develop strategies to understand such processes through characteristic hydrological signatures, e.g. hydrographs. We studied observed hydrographs from large South American rivers and found that in several cases rivers with extensive wetlands present a particular hydrograph shape, with slower rising limb in relation to the receding one, due to storage effects and the associated decrease of wave celerity with stage. A negative asymmetry in the hydrograph is generated, which is higher when more water flows through floodplains upstream of the observed point. Finally, we studied the Amazon basin using gauged information and simulation results from the MGB-IPH regional hydrological model. Major rivers with larger wetland areas (e.g. Purus, Madeira and Juruá) were identified with higher negative asymmetry in their hydrographs. The hydrodynamic model was run in scenarios with and without floodplains, and results supported that floodplain storage affects hydrographs in creating a negative asymmetry, besides attenuating peaks, increasing hydrograph smoothness and increasing minimum flows. Finally, different wetland types could be distinguished with hydrograph shape, e.g. differing wetlands fed by local rainfall from wetlands due to overbank flow (floodplains). These metrics and concepts on hydrograph features have great potential to infer about river-floodplain processes from large rivers and wetland systems.

Tracer and hydrometric techniques to determine the contribution of glacier melt to a proglacial stream in the Ötztal Alps (Tyrol, Austria)

NASA Astrophysics Data System (ADS)

Schmieder, Jan; Marke, Thomas; Strasser, Ulrich

2016-04-01

Glaciers are important seasonal water contributors in many mountainous landscapes. For water resources management it is important to know about the timing and amount of released glacier melt water, especially in downstream regions where the water is needed (hydropower, drinking water) or where it represents a potential risk (drought, flood). Seasonal availability of melt water is strongly dependent on boundary layer atmospheric processes and becomes even more relevant in a changing climate. Environmental tracers are a useful tool in the assessment of snow and ice water resources, because they provide information about the sources, flow paths and traveling times of water contributing to streamflow at the catchment scale. Previously, high-elevation tracer studies throughout the Alps have been scarce as they require intense field work in remote areas. However, hydrometric and meteorological measurements combined with tracer analyses help to unravel streamflow composition and improve the understanding of hydroclimatological processes. On top of that, empirical studies are necessary to parameterize and validate hydrological models in more process-oriented ways, rather than comparing total measured and simulated runoff only. In the present study three approaches are applied to derive glacier melt contributions to a proglacial stream at the seasonal scale and to identify their individual advances and limitations. Tracers used for each approach are (1) electrical conductivity, (2) stable isotopes of water and (3) heavy metals. The field work was conducted during the summer of 2015 in the glaciated (35%) high-elevation catchment of the Hochjochbach, a small sub-basin (17 km²) of the Ötztaler Ache river in the Austrian Alps, ranging from 2400 to 3500 m.a.s.l. in elevation. Hydroclimatological data was provided by an automatic weather station and a gauging station equipped with a pressure transducer. Water samples from shallow groundwater, streamflow, glacier and snow melt, as well as rain were collected throughout the ablation season and analysed for electrical conductivity, stable isotopes and heavy metals. Hydrograph separation is applied with tracer signatures of potential end-members identified by principal component analysis. The proposed contribution describes the experimental setup and discusses preliminary results of the three approaches of hydrograph separation.

Robust high-performance control for robotic manipulators

NASA Technical Reports Server (NTRS)

Seraji, Homayoun (Inventor)

1989-01-01

Model-based and performance-based control techniques are combined for an electrical robotic control system. Thus, two distinct and separate design philosophies were merged into a single control system having a control law formulation including two distinct and separate components, each of which yields a respective signal componet that is combined into a total command signal for the system. Those two separate system components include a feedforward controller and feedback controller. The feedforward controller is model-based and contains any known part of the manipulator dynamics that can be used for on-line control to produce a nominal feedforward component of the system's control signal. The feedback controller is performance-based and consists of a simple adaptive PID controller which generates an adaptive control signal to complement the nomical feedforward signal.

Recession curve analysis for groundwater levels: case study in Latvia

NASA Astrophysics Data System (ADS)

Gailuma, A.; VÄ«tola, I.; Abramenko, K.; Lauva, D.; Vircavs, V.; Veinbergs, A.; Dimanta, Z.

2012-04-01

Recession curve analysis is powerful and effective analysis technique in many research areas related with hydrogeology where observations have to be made, such as water filtration and absorption of moisture, irrigation and drainage, planning of hydroelectric power production and chemical leaching (elution of chemical substances) as well as in other areas. The analysis of the surface runoff hydrograph`s recession curves, which is performed to conceive the after-effects of interaction of precipitation and surface runoff, has approved in practice. The same method for analysis of hydrograph`s recession curves can be applied for the observations of the groundwater levels. There are manually prepared hydrograph for analysis of recession curves for observation wells (MG2, BG2 and AG1) in agricultural monitoring sites in Latvia. Within this study from the available monitoring data of groundwater levels were extracted data of declining periods, splitted by month. The drop-down curves were manually (by changing the date) moved together, until to find the best match, thereby obtaining monthly drop-down curves, representing each month separately. Monthly curves were combined and manually joined, for obtaining characterizing drop-down curves of the year for each well. Within the process of decreased recession curve analysis, from the initial curve was cut out upward areas, leaving only the drops of the curve, consequently, the curve is transformed more closely to the groundwater flow, trying to take out the impact of rain or drought periods from the curve. Respectively, the drop-down curve is part of the data, collected with hydrograph, where data with the discharge dominates, without considering impact of precipitation. Using the recession curve analysis theory, ready tool "A Visual Basic Spreadsheet Macro for Recession Curve Analysis" was used for selection of data and logarithmic functions matching (K. Posavec et.al., GROUND WATER 44, no. 5: 764-767, 2006), as well as functions were developed by manual processing of data. For displaying data the mathematical model of data equalization was used, finding the corresponding or closest logarithmic function of the recession for the graph. Obtained recession curves were similar but not identical. With full knowledge of the fluctuations of ground water level, it is possible to indirectly (without taking soil samples) determine the filtration coefficient: more rapid decline in the recession curve correspond for the better filtration conditions. This research could be very useful in construction planning, road constructions, agriculture etc. Acknowledgments The authors gratefully acknowledge the funding from ESF Project "Establishment of interdisciplinary scientist group and modeling system for groundwater research" (Agreement No. 2009/0212/1DP/1.1.1.2.0/09/APIA/VIAA/060EF7)

Testing Orions Fairing Separation System

NASA Technical Reports Server (NTRS)

Martinez, Henry; Cloutier, Chris; Lemmon, Heber; Rakes, Daniel; Oldham, Joe; Schlagel, Keith

2014-01-01

Traditional fairing systems are designed to fully encapsulate and protect their payload from the harsh ascent environment including acoustic vibrations, aerodynamic forces and heating. The Orion fairing separation system performs this function and more by also sharing approximately half of the vehicle structural load during ascent. This load-share condition through launch and during jettison allows for a substantial increase in mass to orbit. A series of component-level development tests were completed to evaluate and characterize each component within Orion's unique fairing separation system. Two full-scale separation tests were performed to verify system-level functionality and provide verification data. This paper summarizes the fairing spring, Pyramidal Separation Mechanism and forward seal system component-level development tests, system-level separation tests, and lessons learned.

15 CFR 996.22 - Certification.

Code of Federal Regulations, 2014 CFR

2014-01-01

... REQUIREMENTS FOR NOAA HYDROGRAPHIC PRODUCTS AND SERVICES QUALITY ASSURANCE AND CERTIFICATION REQUIREMENTS FOR NOAA HYDROGRAPHIC PRODUCTS AND SERVICES Certification of a Hydrographic Product and Decertification... automatically be considered for certification by NOAA. NOAA shall make its certification determination, if its...

15 CFR 996.22 - Certification.

Code of Federal Regulations, 2012 CFR

2012-01-01

... REQUIREMENTS FOR NOAA HYDROGRAPHIC PRODUCTS AND SERVICES QUALITY ASSURANCE AND CERTIFICATION REQUIREMENTS FOR NOAA HYDROGRAPHIC PRODUCTS AND SERVICES Certification of a Hydrographic Product and Decertification... automatically be considered for certification by NOAA. NOAA shall make its certification determination, if its...

15 CFR 996.22 - Certification.

Code of Federal Regulations, 2013 CFR

2013-01-01

... REQUIREMENTS FOR NOAA HYDROGRAPHIC PRODUCTS AND SERVICES QUALITY ASSURANCE AND CERTIFICATION REQUIREMENTS FOR NOAA HYDROGRAPHIC PRODUCTS AND SERVICES Certification of a Hydrographic Product and Decertification... automatically be considered for certification by NOAA. NOAA shall make its certification determination, if its...

15 CFR 996.22 - Certification.

Code of Federal Regulations, 2011 CFR

2011-01-01

... REQUIREMENTS FOR NOAA HYDROGRAPHIC PRODUCTS AND SERVICES QUALITY ASSURANCE AND CERTIFICATION REQUIREMENTS FOR NOAA HYDROGRAPHIC PRODUCTS AND SERVICES Certification of a Hydrographic Product and Decertification... automatically be considered for certification by NOAA. NOAA shall make its certification determination, if its...

15 CFR 996.21 - Performance of compliance testing.

Code of Federal Regulations, 2010 CFR

2010-01-01

... (Continued) NATIONAL OCEANIC AND ATMOSPHERIC ADMINISTRATION, DEPARTMENT OF COMMERCE QUALITY ASSURANCE AND CERTIFICATION REQUIREMENTS FOR NOAA HYDROGRAPHIC PRODUCTS AND SERVICES QUALITY ASSURANCE AND CERTIFICATION REQUIREMENTS FOR NOAA HYDROGRAPHIC PRODUCTS AND SERVICES Certification of a Hydrographic Product and...

Automated Method to Develop a Clark Synthetic Unit Hydrograph within ArcGIS

DTIC Science & Technology

2015-08-01

assumption of superposition, a simulated outflow hydrograph is created. Peff represents the fraction of precipitation that contributes to immediate runoff ...the spatial features of the watershed affect the runoff of the basin and therefore the unit hydrograph at the outlet of the basin. BACKGROUND...Rainfall- runoff response within a watershed is a core consideration of hydrologists. The use of unit hydrographs as a way to analyze the rainfall- runoff

Estimating discharge and non-point source nitrate loading to streams from three end-member pathways using high-frequency water quality and streamflow data

NASA Astrophysics Data System (ADS)

Miller, M. P.; Tesoriero, A. J.; Hood, K.; Terziotti, S.; Wolock, D.

2017-12-01

The myriad hydrologic and biogeochemical processes taking place in watersheds occurring across space and time are integrated and reflected in the quantity and quality of water in streams and rivers. Collection of high-frequency water quality data with sensors in surface waters provides new opportunities to disentangle these processes and quantify sources and transport of water and solutes in the coupled groundwater-surface water system. A new approach for separating the streamflow hydrograph into three components was developed and coupled with high-frequency specific conductance and nitrate data to estimate time-variable watershed-scale nitrate loading from three end-member pathways - dilute quickflow, concentrated quickflow, and slowflow groundwater - to two streams in central Wisconsin. Time-variable nitrate loads from the three pathways were estimated for periods of up to two years in a groundwater-dominated and a quickflow-dominated stream, using only streamflow and in-stream water quality data. The dilute and concentrated quickflow end-members were distinguished using high-frequency specific conductance data. Results indicate that dilute quickflow contributed less than 5% of the nitrate load at both sites, whereas 89±5% of the nitrate load at the groundwater-dominated stream was from slowflow groundwater, and 84±13% of the nitrate load at the quickflow-dominated stream was from concentrated quickflow. Concentrated quickflow nitrate concentrations varied seasonally at both sites, with peak concentrations in the winter that were 2-3 times greater than minimum concentrations during the growing season. Application of this approach provides an opportunity to assess stream vulnerability to non-point source nitrate loading and expected stream responses to current or changing conditions and practices in watersheds.

Independent active and thermodynamic processes govern the nucleolus assembly in vivo

PubMed Central

Falahati, Hanieh; Wieschaus, Eric

2017-01-01

Membraneless organelles play a central role in the organization of protoplasm by concentrating macromolecules, which allows efficient cellular processes. Recent studies have shown that, in vitro, certain components in such organelles can assemble through phase separation. Inside the cell, however, such organelles are multicomponent, with numerous intermolecular interactions that can potentially affect the demixing properties of individual components. In addition, the organelles themselves are inherently active, and it is not clear how the active, energy-consuming processes that occur constantly within such organelles affect the phase separation behavior of the constituent macromolecules. Here, we examine the phase separation model for the formation of membraneless organelles in vivo by assessing the two features that collectively distinguish it from active assembly, namely temperature dependence and reversibility. We use a microfluidic device that allows accurate and rapid manipulation of temperature and examine the quantitative dynamics by which six different nucleolar proteins assemble into the nucleoli of Drosophila melanogaster embryos. Our results indicate that, although phase separation is the main mode of recruitment for four of the studied proteins, the assembly of the other two is irreversible and enhanced at higher temperatures, behaviors indicative of active recruitment to the nucleolus. These two subsets of components differ in their requirements for ribosomal DNA; the two actively assembling components fail to assemble in the absence of ribosomal DNA, whereas the thermodynamically driven components assemble but lose temporal and spatial precision. PMID:28115706

Ensuring Safety of Navigation: A Three-Tiered Approach

NASA Astrophysics Data System (ADS)

Johnson, S. D.; Thompson, M.; Brazier, D.

2014-12-01

The primary responsibility of the Hydrographic Department at the Naval Oceanographic Office (NAVOCEANO) is to support US Navy surface and sub-surface Safety of Navigation (SoN) requirements. These requirements are interpreted, surveys are conducted, and accurate products are compiled and archived for future exploitation. For a number of years NAVOCEANO has employed a two-tiered data-basing structure to support SoN. The first tier (Data Warehouse, or DWH) provides access to the full-resolution sonar and lidar data. DWH preserves the original data such that any scale product can be built. The second tier (Digital Bathymetric Database - Variable resolution, or DBDB-V) served as the final archive for SoN chart scale, gridded products compiled from source bathymetry. DBDB-V has been incorporated into numerous DoD tactical decision aids and serves as the foundation bathymetry for ocean modeling. With the evolution of higher density survey systems and the addition of high-resolution gridded bathymetry product requirements, a two-tiered model did not provide an efficient solution for SoN. The two-tiered approach required scientists to exploit full-resolution data in order to build any higher resolution product. A new perspective on the archival and exploitation of source data was required. This new perspective has taken the form of a third tier, the Navigation Surface Database (NSDB). NSDB is an SQLite relational database populated with International Hydrographic Organization (IHO), S-102 compliant Bathymetric Attributed Grids (BAGs). BAGs archived within NSDB are developed at the highest resolution that the collection sensor system can support and contain nodal estimates for depth, uncertainty, separation values and metadata. Gridded surface analysis efforts culminate in the generation of the source resolution BAG files and their storage within NSDB. Exploitation of these resources eliminates the time and effort needed to re-grid and re-analyze native source file formats.

An Analysis of Wind Power Development in the Town of Hull, MA_Appendix 4_Geophysical Survey Report

DOE Office of Scientific and Technical Information (OSTI.GOV)

Adams, Christopher

2013-06-30

CR Environmental, Inc. (CR) was contracted by GZA GeoEnvironmental, Inc. (GZA) to perform hydrographic and geophysical surveys of an approximately 3.35 square mile area off the eastern shore of Hull, Massachusetts. Survey components included: • Single-beam bathymetry; • 100-kHz and 500-kHz side scan sonar; • Magnetometry; and • Low to mid-frequency sub-bottom profiling.

76 FR 32957 - Hydrographic Services Review Panel

Federal Register 2010, 2011, 2012, 2013, 2014

2011-06-07

... Review Panel AGENCY: National Ocean Service, National Oceanic and Atmospheric Administration (NOAA), Department of Commerce. ACTION: Notice of membership solicitation for Hydrographic Services Review Panel...), to solicit nominations for membership on the Hydrographic Services Review Panel (HSRP). The HSRP, a...

75 FR 20809 - Hydrographic Services Review Panel

Federal Register 2010, 2011, 2012, 2013, 2014

2010-04-21

... Review Panel AGENCY: National Ocean Service, National Oceanic and Atmospheric Administration (NOAA), Department of Commerce. ACTION: Notice of Additional Membership Solicitation for Hydrographic Services Review... applications for membership on the Hydrographic Services Review Panel (the Panel), a Federal advisory committee...

75 FR 20816 - Hydrographic Services Review Panel Meeting

Federal Register 2010, 2011, 2012, 2013, 2014

2010-04-21

... DEPARTMENT OF COMMERCE National Oceanic and Atmospheric Administration Hydrographic Services... (NOAA), Department of Commerce. ACTION: Notice of open meeting. SUMMARY: The Hydrographic Services Review Panel (HSRP) is a Federal Advisory Committee established to advise the Under Secretary of Commerce...

76 FR 61091 - Hydrographic Services Review Panel Meeting

Federal Register 2010, 2011, 2012, 2013, 2014

2011-10-03

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76 FR 20323 - Hydrographic Services Review Panel Meeting

Federal Register 2010, 2011, 2012, 2013, 2014

2011-04-12

... DEPARTMENT OF COMMERCE National Oceanic and Atmospheric Administration Hydrographic Services... (NOAA), Department of Commerce. ACTION: Notice of open meeting. SUMMARY: The Hydrographic Services Review Panel (HSRP) is a Federal Advisory Committee established to advise the Under Secretary of Commerce...

Drainage area characterization for evaluating green infrastructure using the Storm Water Management Model

NASA Astrophysics Data System (ADS)

Lee, Joong Gwang; Nietch, Christopher T.; Panguluri, Srinivas

2018-05-01

Urban stormwater runoff quantity and quality are strongly dependent upon catchment properties. Models are used to simulate the runoff characteristics, but the output from a stormwater management model is dependent on how the catchment area is subdivided and represented as spatial elements. For green infrastructure modeling, we suggest a discretization method that distinguishes directly connected impervious area (DCIA) from the total impervious area (TIA). Pervious buffers, which receive runoff from upgradient impervious areas should also be identified as a separate subset of the entire pervious area (PA). This separation provides an improved model representation of the runoff process. With these criteria in mind, an approach to spatial discretization for projects using the US Environmental Protection Agency's Storm Water Management Model (SWMM) is demonstrated for the Shayler Crossing watershed (SHC), a well-monitored, residential suburban area occupying 100 ha, east of Cincinnati, Ohio. The model relies on a highly resolved spatial database of urban land cover, stormwater drainage features, and topography. To verify the spatial discretization approach, a hypothetical analysis was conducted. Six different representations of a common urbanscape that discharges runoff to a single storm inlet were evaluated with eight 24 h synthetic storms. This analysis allowed us to select a discretization scheme that balances complexity in model setup with presumed accuracy of the output with respect to the most complex discretization option considered. The balanced approach delineates directly and indirectly connected impervious areas (ICIA), buffering pervious area (BPA) receiving impervious runoff, and the other pervious area within a SWMM subcatchment. It performed well at the watershed scale with minimal calibration effort (Nash-Sutcliffe coefficient = 0.852; R2 = 0.871). The approach accommodates the distribution of runoff contributions from different spatial components and flow pathways that would impact green infrastructure performance. A developed SWMM model using the discretization approach is calibrated by adjusting parameters per land cover component, instead of per subcatchment and, therefore, can be applied to relatively large watersheds if the land cover components are relatively homogeneous and/or categorized appropriately in the GIS that supports the model parameterization. Finally, with a few model adjustments, we show how the simulated stream hydrograph can be separated into the relative contributions from different land cover types and subsurface sources, adding insight to the potential effectiveness of planned green infrastructure scenarios at the watershed scale.

Ocean data assimilation using optimal interpolation with a quasi-geostrophic model

NASA Technical Reports Server (NTRS)

Rienecker, Michele M.; Miller, Robert N.

1991-01-01

A quasi-geostrophic (QG) stream function is analyzed by optimal interpolation (OI) over a 59-day period in a 150-km-square domain off northern California. Hydrographic observations acquired over five surveys were assimilated into a QG open boundary ocean model. Assimilation experiments were conducted separately for individual surveys to investigate the sensitivity of the OI analyses to parameters defining the decorrelation scale of an assumed error covariance function. The analyses were intercompared through dynamical hindcasts between surveys. The best hindcast was obtained using the smooth analyses produced with assumed error decorrelation scales identical to those of the observed stream function. The rms difference between the hindcast stream function and the final analysis was only 23 percent of the observation standard deviation. The two sets of OI analyses were temporally smoother than the fields from statistical objective analysis and in good agreement with the only independent data available for comparison.

Determination of rainfall losses in Virginia, phase II : final report.

DOT National Transportation Integrated Search

1982-01-01

A procedure is presented by which regional unit hydrograph and loss rate parameters are estimated for the generation of design storm hydrographs for watershed in Virginia. The state is divided into seven hydrological regions, and unit hydrograph and ...

Hydrometric, Hydrochemical, and Hydrogeophysical Runoff Characterization Across Multiple Land Covers in the Agua Salud Project, Panama

NASA Astrophysics Data System (ADS)

Litt, Guy Finley

As the Panama Canal Authority faces sensitivity to water shortages, managing water resources becomes crucial for the global shipping industry's security. These studies address knowledge gaps in tropical water resources to aid hydrological model development and validation. Field-based hydrological investigations in the Agua Salud Project within the Panama Canal Watershed employed multiple tools across a variety of land covers to investigate hydrological processes. Geochemical tracers informed where storm runoff in a stream comes from and identified electrical conductivity (EC) as an economical, high sample frequency tracer during small storms. EC-based hydrograph separation coupled with hydrograph recession rate analyses identified shallow and deep groundwater storage-discharge relationships that varied by season and land cover. A series of plot-scale electrical resistivity imaging geophysical experiments coupled with rainfall simulation characterized subsurface flow pathway behavior and quantified respectively increasing infiltration rates across pasture, 10 year old secondary succession forest, teak (tectona grandis), and 30 year old secondary succession forest land covers. Additional soil water, groundwater, and geochemical studies informed conceptual model development in subsurface flow pathways and groundwater, and identified future research needs.

High-resolution ultraviolet observations of interstellar lines toward Zeta Persei observed with the balloon-borne ultraviolet stellar spectrometer

DOE Office of Scientific and Technical Information (OSTI.GOV)

Snow, T.P.; Lamers, H.J.G.L.M.; Joseph, C.L.

1987-10-01

The balloon-borne ultraviolet stellar spectrometer payload has been used to obtain high-resolution data on interstellar absorption lines toward Zeta Per. The only lines clearly present in the 2150-2450 region were several Fe II features, which show double structure. The two velocity components were sufficiently well separated that it was possible to construct separate curves of growth to derive the Fe II column densities for the individual components. These column densities and the component velocity separation were then used to compute a realistic two-component curve of growth for the line of sight to Zeta Per, which was then used to reanalyzemore » existing ultraviolet data from Copernicus. The results were generally similar to an earlier two-component analysis of the Copernicus data, with the important exception that the silicon depletion increased from near zero to about 1 dex. This makes the Zeta Per depletion pattern quite similar to those derived for other reddened lines of sight, supporting the viewpoint that the general diffuse interstellar medium has a nearly constant pattern of depletions. 31 references.« less

Interaction between Meso-scale Eddies and Sub-polar Front in the East (Japan) Sea based on ARGO, AVHRR, and Numerical Model

NASA Astrophysics Data System (ADS)

Ro, Y.; Kim, E.

2008-12-01

The East (Japan) Sea is drawing keen international attentions from broad spectrum of groups such as scientists, diplomats, and defense officers for its geopolitical situation, peculiar scientific assets recognized as miniature ocean. From physical oceanographic aspect, it is very rich with many features such as basin-wide circulation pattern, boundary currents, sub-polar front, meso-scale eddy activities and deep water formation. The circulation pattern in the East (Japan) Sea has been of major interests for its peculiar gyre, a western boundary current and its separation that resembles the currents such as Kuroshio and Gulf Stream. In relation to the gyre system in the East Sea, the formation of the East Korea Warm Current (EKWC) has brought up with many numerical experiments. Numerical experiments suggested a new idea to explain the formation of the EKWC in that the potential energy supply into the Ulleung Basin (UB) from the meso-scale eddy is a key process. This is closely linked with the baroclinic instability and the meandering of offshore component of Tsushima Warm Current. The UB has drawn attentions for its role of the formation of two major boundary currents, EKWC, North Korea Warm Current (NKCC), their interaction with the mesoscale UWE, watermass exchange between the Northern Japan Basin and UB. Numerical experiments along with hydrographic and other satellite datasets such as AVHRR, altimeter and ARGO profiles have been analyzed to understand the formation of the UWE. We found that the influence of the bottom topography and frictional forcing against lateral boundary are all closely associated with the sub-polar front. Meandering of the axis of the sub-polar front is closely linked with the separation point of the EKWC, Ulleung Warm Eddy, and other small and meso-scale eddies on the sub-polar front. These will be demonstrated with results of the numerical modeling experiments and animation movie will be presented.

15 CFR 996.21 - Performance of compliance testing.

Code of Federal Regulations, 2011 CFR

2011-01-01

... CERTIFICATION REQUIREMENTS FOR NOAA HYDROGRAPHIC PRODUCTS AND SERVICES QUALITY ASSURANCE AND CERTIFICATION REQUIREMENTS FOR NOAA HYDROGRAPHIC PRODUCTS AND SERVICES Certification of a Hydrographic Product and Decertification. § 996.21 Performance of compliance testing. (a) NOAA and the applicant shall submit the applicant...

15 CFR 996.21 - Performance of compliance testing.

Code of Federal Regulations, 2014 CFR

2014-01-01

... CERTIFICATION REQUIREMENTS FOR NOAA HYDROGRAPHIC PRODUCTS AND SERVICES QUALITY ASSURANCE AND CERTIFICATION REQUIREMENTS FOR NOAA HYDROGRAPHIC PRODUCTS AND SERVICES Certification of a Hydrographic Product and Decertification. § 996.21 Performance of compliance testing. (a) NOAA and the applicant shall submit the applicant...

15 CFR 996.21 - Performance of compliance testing.

Code of Federal Regulations, 2013 CFR

2013-01-01

... CERTIFICATION REQUIREMENTS FOR NOAA HYDROGRAPHIC PRODUCTS AND SERVICES QUALITY ASSURANCE AND CERTIFICATION REQUIREMENTS FOR NOAA HYDROGRAPHIC PRODUCTS AND SERVICES Certification of a Hydrographic Product and Decertification. § 996.21 Performance of compliance testing. (a) NOAA and the applicant shall submit the applicant...

15 CFR 996.21 - Performance of compliance testing.

Code of Federal Regulations, 2012 CFR

2012-01-01

... CERTIFICATION REQUIREMENTS FOR NOAA HYDROGRAPHIC PRODUCTS AND SERVICES QUALITY ASSURANCE AND CERTIFICATION REQUIREMENTS FOR NOAA HYDROGRAPHIC PRODUCTS AND SERVICES Certification of a Hydrographic Product and Decertification. § 996.21 Performance of compliance testing. (a) NOAA and the applicant shall submit the applicant...

How Does Variability in Aragonite Saturation Proxies Impact Our Estimates of the Intensity and Duration of Exposure to Aragonite Corrosive Conditions in a Coastal Upwelling System?

NASA Astrophysics Data System (ADS)

Abell, J. T.; Jacobsen, J.; Bjorkstedt, E.

2016-02-01

Determining aragonite saturation state (Ω) in seawater requires measurement of two parameters of the carbonate system: most commonly dissolved inorganic carbon (DIC) and total alkalinity (TA). The routine measurement of DIC and TA is not always possible on frequently repeated hydrographic lines or at moored-time series that collect hydrographic data at short time intervals. In such cases a proxy can be developed that relates the saturation state as derived from one time or infrequent DIC and TA measurements (Ωmeas) to more frequently measured parameters such as dissolved oxygen (DO) and temperature (Temp). These proxies are generally based on best-fit parameterizations that utilize references values of DO and Temp and adjust linear coefficients until the error between the proxy-derived saturation state (Ωproxy) and Ωmeas is minimized. Proxies have been used to infer Ω from moored hydrographic sensors and gliders which routinely collect DO and Temp data but do not include carbonate parameter measurements. Proxies can also calculate Ω in regional oceanographic models which do not explicitly include carbonate parameters. Here we examine the variability and accuracy of Ωproxy along a near-shore hydrographic line and a moored-time series stations at Trinidad Head, CA. The saturation state is determined using proxies from different coastal regions of the California Current Large Marine Ecosystem and from different years of sampling along the hydrographic line. We then calculate the variability and error associated with the use of different proxy coefficients, the sensitivity to reference values and the inclusion of additional variables. We demonstrate how this variability affects estimates of the intensity and duration of exposure to aragonite corrosive conditions on the near-shore shelf and in the water column.

A hybrid method for flood simulation in small catchments combining hydrodynamic and hydrological techniques

NASA Astrophysics Data System (ADS)

Bellos, Vasilis; Tsakiris, George

2016-09-01

The study presents a new hybrid method for the simulation of flood events in small catchments. It combines a physically-based two-dimensional hydrodynamic model and the hydrological unit hydrograph theory. Unit hydrographs are derived using the FLOW-R2D model which is based on the full form of two-dimensional Shallow Water Equations, solved by a modified McCormack numerical scheme. The method is tested at a small catchment in a suburb of Athens-Greece for a storm event which occurred in February 2013. The catchment is divided into three friction zones and unit hydrographs of 15 and 30 min are produced. The infiltration process is simulated by the empirical Kostiakov equation and the Green-Ampt model. The results from the implementation of the proposed hybrid method are compared with recorded data at the hydrometric station at the outlet of the catchment and the results derived from the fully hydrodynamic model FLOW-R2D. It is concluded that for the case studied, the proposed hybrid method produces results close to those of the fully hydrodynamic simulation at substantially shorter computational time. This finding, if further verified in a variety of case studies, can be useful in devising effective hybrid tools for the two-dimensional flood simulations, which are lead to accurate and considerably faster results than those achieved by the fully hydrodynamic simulations.

Water exchange and pressure transfer between conduits and matrix and their influence on hydrodynamics of two karst aquifers with sinking streams

NASA Astrophysics Data System (ADS)

Bailly-Comte, Vincent; Martin, Jonathan B.; Jourde, Hervé; Screaton, Elizabeth J.; Pistre, Séverin; Langston, Abigail

2010-05-01

SummaryKarst aquifers are heterogeneous media where conduits usually drain water from lower permeability volumes (matrix and fractures). For more than a century, various approaches have used flood recession curves, which integrate all hydrodynamic processes in a karst aquifer, to infer physical properties of the movement and storage of groundwater. These investigations typically only consider flow to the conduits and thus have lacked quantitative observations of how pressure transfer and water exchange between matrix and conduit during flooding could influence recession curves. We present analyses of simultaneous discharge and water level time series of two distinctly different karst systems, one with low porosity and permeability matrix rocks in southern France, and one with high porosity and permeability matrix rocks in north-central Florida (USA). We apply simple mathematical models of flood recession using time series representations of recharge, storage, and discharge processes in the karst aquifer. We show that karst spring hydrographs can be interpreted according to pressure transfer between two distinct components of the aquifer, conduit and matrix porosity, which induce two distinct responses at the spring. Water exchange between conduits and matrix porosity successively control the flow regime at the spring. This exchange is governed by hydraulic head differences between conduits and matrix, head gradients within conduits, and the contrast of permeability between conduits and matrix. These observations have consequences for physical interpretations of recession curves and modeling of karst spring flows, particularly for the relative magnitudes of base flow and quick flow from karst springs. Finally, these results suggest that similar analyses of recession curves can be applied to karst aquifers with distinct physical characteristics utilizing well and spring hydrograph data, but information must be known about the hydrodynamics and physical properties of the aquifer before the results can be correctly interpreted.

15 CFR 996.20 - Submission of a hydrographic product for certification.

Code of Federal Regulations, 2014 CFR

2014-01-01

... QUALITY ASSURANCE AND CERTIFICATION REQUIREMENTS FOR NOAA HYDROGRAPHIC PRODUCTS AND SERVICES QUALITY ASSURANCE AND CERTIFICATION REQUIREMENTS FOR NOAA HYDROGRAPHIC PRODUCTS AND SERVICES Certification of a...) Upon adoption by NOAA of standards and compliance tests, any non-Federal entity may submit a...

15 CFR 996.20 - Submission of a hydrographic product for certification.

Code of Federal Regulations, 2012 CFR

2012-01-01

... QUALITY ASSURANCE AND CERTIFICATION REQUIREMENTS FOR NOAA HYDROGRAPHIC PRODUCTS AND SERVICES QUALITY ASSURANCE AND CERTIFICATION REQUIREMENTS FOR NOAA HYDROGRAPHIC PRODUCTS AND SERVICES Certification of a...) Upon adoption by NOAA of standards and compliance tests, any non-Federal entity may submit a...

15 CFR 996.20 - Submission of a hydrographic product for certification.

Code of Federal Regulations, 2011 CFR

2011-01-01

... QUALITY ASSURANCE AND CERTIFICATION REQUIREMENTS FOR NOAA HYDROGRAPHIC PRODUCTS AND SERVICES QUALITY ASSURANCE AND CERTIFICATION REQUIREMENTS FOR NOAA HYDROGRAPHIC PRODUCTS AND SERVICES Certification of a...) Upon adoption by NOAA of standards and compliance tests, any non-Federal entity may submit a...

15 CFR 996.11 - Development of standards for a hydrographic product or class.

Code of Federal Regulations, 2012 CFR

2012-01-01

... COMMERCE QUALITY ASSURANCE AND CERTIFICATION REQUIREMENTS FOR NOAA HYDROGRAPHIC PRODUCTS AND SERVICES QUALITY ASSURANCE AND CERTIFICATION REQUIREMENTS FOR NOAA HYDROGRAPHIC PRODUCTS AND SERVICES The Quality... class. (a) NOAA shall work, to the extent practicable, through existing, recognized, standards bodies in...

15 CFR 996.11 - Development of standards for a hydrographic product or class.

Code of Federal Regulations, 2013 CFR

2013-01-01

... COMMERCE QUALITY ASSURANCE AND CERTIFICATION REQUIREMENTS FOR NOAA HYDROGRAPHIC PRODUCTS AND SERVICES QUALITY ASSURANCE AND CERTIFICATION REQUIREMENTS FOR NOAA HYDROGRAPHIC PRODUCTS AND SERVICES The Quality... class. (a) NOAA shall work, to the extent practicable, through existing, recognized, standards bodies in...

15 CFR 996.11 - Development of standards for a hydrographic product or class.

Code of Federal Regulations, 2011 CFR

2011-01-01

... COMMERCE QUALITY ASSURANCE AND CERTIFICATION REQUIREMENTS FOR NOAA HYDROGRAPHIC PRODUCTS AND SERVICES QUALITY ASSURANCE AND CERTIFICATION REQUIREMENTS FOR NOAA HYDROGRAPHIC PRODUCTS AND SERVICES The Quality... class. (a) NOAA shall work, to the extent practicable, through existing, recognized, standards bodies in...

15 CFR 996.20 - Submission of a hydrographic product for certification.

Code of Federal Regulations, 2013 CFR

2013-01-01

... QUALITY ASSURANCE AND CERTIFICATION REQUIREMENTS FOR NOAA HYDROGRAPHIC PRODUCTS AND SERVICES QUALITY ASSURANCE AND CERTIFICATION REQUIREMENTS FOR NOAA HYDROGRAPHIC PRODUCTS AND SERVICES Certification of a...) Upon adoption by NOAA of standards and compliance tests, any non-Federal entity may submit a...

15 CFR 996.11 - Development of standards for a hydrographic product or class.

Code of Federal Regulations, 2014 CFR

2014-01-01

... COMMERCE QUALITY ASSURANCE AND CERTIFICATION REQUIREMENTS FOR NOAA HYDROGRAPHIC PRODUCTS AND SERVICES QUALITY ASSURANCE AND CERTIFICATION REQUIREMENTS FOR NOAA HYDROGRAPHIC PRODUCTS AND SERVICES The Quality... class. (a) NOAA shall work, to the extent practicable, through existing, recognized, standards bodies in...

15 CFR 996.11 - Development of standards for a hydrographic product or class.

Code of Federal Regulations, 2010 CFR

2010-01-01

... COMMERCE QUALITY ASSURANCE AND CERTIFICATION REQUIREMENTS FOR NOAA HYDROGRAPHIC PRODUCTS AND SERVICES QUALITY ASSURANCE AND CERTIFICATION REQUIREMENTS FOR NOAA HYDROGRAPHIC PRODUCTS AND SERVICES The Quality... adopt or reject the standard as the NOAA Quality Assurance Program Standard for the particular...

Estimating flood hydrographs and volumes for Alabama streams

USGS Publications Warehouse

Olin, D.A.; Atkins, J.B.

1988-01-01

The hydraulic design of highway drainage structures involves an evaluation of the effect of the proposed highway structures on lives, property, and stream stability. Flood hydrographs and associated flood volumes are useful tools in evaluating these effects. For design purposes, the Alabama Highway Department needs information on flood hydrographs and volumes associated with flood peaks of specific recurrence intervals (design floods) at proposed or existing bridge crossings. This report will provide the engineer with a method to estimate flood hydrographs, volumes, and lagtimes for rural and urban streams in Alabama with drainage areas less than 500 sq mi. Existing computer programs and methods to estimate flood hydrographs and volumes for ungaged streams have been developed in Georgia. These computer programs and methods were applied to streams in Alabama. The report gives detailed instructions on how to estimate flood hydrographs for ungaged rural or urban streams in Alabama with drainage areas less than 500 sq mi, without significant in-channel storage or regulations. (USGS)

Flood type specific construction of synthetic design hydrographs

NASA Astrophysics Data System (ADS)

Brunner, Manuela I.; Viviroli, Daniel; Sikorska, Anna E.; Vannier, Olivier; Favre, Anne-Catherine; Seibert, Jan

2017-02-01

Accurate estimates of flood peaks, corresponding volumes, and hydrographs are required to design safe and cost-effective hydraulic structures. In this paper, we propose a statistical approach for the estimation of the design variables peak and volume by constructing synthetic design hydrographs for different flood types such as flash-floods, short-rain floods, long-rain floods, and rain-on-snow floods. Our approach relies on the fitting of probability density functions to observed flood hydrographs of a certain flood type and accounts for the dependence between peak discharge and flood volume. It makes use of the statistical information contained in the data and retains the process information of the flood type. The method was tested based on data from 39 mesoscale catchments in Switzerland and provides catchment specific and flood type specific synthetic design hydrographs for all of these catchments. We demonstrate that flood type specific synthetic design hydrographs are meaningful in flood-risk management when combined with knowledge on the seasonality and the frequency of different flood types.

"Physically-based" numerical experiment to determine the dominant hillslope processes during floods?

NASA Astrophysics Data System (ADS)

Gaume, Eric; Esclaffer, Thomas; Dangla, Patrick; Payrastre, Olivier

2016-04-01

To study the dynamics of hillslope responses during flood event, a fully coupled "physically-based" model for the combined numerical simulation of surface runoff and underground flows has been developed. A particular attention has been given to the selection of appropriate numerical schemes for the modelling of both processes and of their coupling. Surprisingly, the most difficult question to solve, from a numerical point of view, was not related to the coupling of two processes with contrasted kinetics such as surface and underground flows, but to the high gradient infiltration fronts appearing in soils, source of numerical diffusion, instabilities and sometimes divergence. The model being elaborated, it has been successfully tested against results of high quality experiments conducted on a laboratory sandy slope in the early eighties, which is still considered as a reference hillslope experimental setting (Abdul & Guilham). The model appeared able to accurately simulate the pore pressure distributions observed in this 1.5 meter deep and wide laboratory hillslope, as well as its outflow hydrograph shapes and the measured respective contributions of direct runoff and groundwater to these outflow hydrographs. Based on this great success, the same model has been used to simulate the response of a theoretical 100-meter wide and 10% sloped hillslope, with a 2 meter deep pervious soil and impervious bedrock. Three rain events have been tested: a 100 millimeter rainfall event over 10 days, over 1 day or over one hour. The simulated responses are hydrologically not realistic and especially the fast component of the response, that is generally observed in the real-world and explains flood events, is almost absent of the simulated response. Thinking a little about the whole problem, the simulation results appears totally logical according to the proposed model. The simulated response, in fact a recession hydrograph, corresponds to a piston flow of a relatively uniformly saturated hillslope leading to a constant discharge over several days. Some ingredients are clearly missing in the proposed model to reproduce hydrologically sensible responses. Heterogeneities are necessary to generate a variety of residence times and especially preferential flows must clearly be present to generate the fast component of hillslope responses. The importance of preferential flows in hillslope hydrology has been confirmed since this reported failure by several hillslope field experiments. We let also the readers draw their own conclusions about the numerous numerical models, that look very much alike the model proposed here, even if generally much more simplified, but representing the watersheds as much too homogeneous neglecting heterogeneities and preferential flows and pretending to be "physically based"…

ERP Go/NoGo condition effects are better detected with separate PCAs.

PubMed

Barry, Robert J; De Blasio, Frances M; Fogarty, Jack S; Karamacoska, Diana

2016-08-01

We explored the separation of Go and NoGo effects in the ERP components elicited in an equiprobable Go/NoGo task, using different forms of temporal Principal Components Analysis (PCA). Following exploratory simulation studies assessing the PCA impact of latency jitter and between-condition latency differences in the P3 latency range, an empirical study compared results of a Combined PCA carried out using both Go and NoGo ERPs together as input, with those from two Separate PCAs carried out on the Go and NoGo ERPs separately. The simulation studies indicated that Separate PCAs provide adequate component recovery in the presence of P3 latency jitter, and that Combined PCAs provide good separation of components only when systematic condition-related latency differences are sufficiently large (here ~110ms). In the empirical data, broadly-similar components were obtained from the Combined and Separate PCAs, supporting previous findings from Combined PCA investigations, and the consequent interpretations of the sequential processing involved. However, the Separate PCAs generated latency differences for components in the Go and NoGo processing chains that better matched the late Go/NoGo ERP peaks, and produced better-defined and larger components that fitted the stages in a hypothetical processing schema developed for this paradigm. Overall, the Separate PCAs yielded a better partitioning of the ERP variance associated with the Go and NoGo conditions, and should be considered as the first choice in future investigations if systematic component or subcomponent latency differences are present or suspected. Copyright © 2016 Elsevier B.V. All rights reserved.

Sinos River Hydrographic Basin: urban occupation, industrialization and environmental memory.

PubMed

Nunes, M F; Figueiredo, J A S; Rocha, A L C

2015-12-01

This article presents an analysis of the process of industrialization and urbanization of the Sinos Valley in Rio Grande do Sul state, Brazil, starting from the establishment of leather goods and footwear manufacturing in the region during the 19th century when tanneries and factories producing footwear and/or components for footwear began to appear, and with special attention to aspects related to the environmental impact on the Sinos river hydrographic basin. The article is based on both bibliographic and documentary research and also draws on biographical narratives of workers with links to the leather goods and footwear industry obtained using ethnographic method. It was found that contemporary environmental conflicts emerge from within a memory of work and an environmental memory in which the factories, the unplanned urbanization, and the utilization of water and other natural resources form a chain of significance. Significance that precludes any form of fragmented analysis that isolates any of these aspects from the others: the economic, socio-historic, cultural, political, or the environmental.

The Use of Hydrograph Analysis and Impulse Response Functions to Improve Understanding of Groundwater Flooding: A Case Study from the Chalk Aquifer, United Kingdom.

NASA Astrophysics Data System (ADS)

Ascott, M.; Bloomfield, J.; Macdonald, D.; Marchant, B.; McKenzie, A.

2017-12-01

The Cretaceous Chalk, the most important aquifer in the United Kingdom (UK) for public water supply, underlies many large cities in southern and eastern England including parts of London, however, it is prone to groundwater flooding. We have developed a new approach to analyse the spatio-temporal extent of groundwater flooding using statistical analysis of groundwater level hydrographs and impulse response functions (IRFs) applied to a major Chalk groundwater flooding event in the UK during winter 2013/14. Using monthly groundwater levels for 26 boreholes in the Chalk and a new standardised index for groundwater flooding, we have: estimated standardised series; grouped them using k-means cluster analysis; and, cross-correlated the cluster centroids with the Standardised Precipitation Index accumulated over time intervals between 1 and 60 months. This analysis reveals two spatially coherent groups of standardised hydrographs which respond to precipitation over different timescales. We estimate IRF models of the groundwater level response to effective precipitation for three boreholes in each group. The IRF models support the SPI analysis showing different response functions between the two groups. If we apply identical effective precipitation inputs to each of the IRF models we see differences between the hydrographs from each group. It is proposed that these differences are due to the intrinsic, hydrogeological properties of the Chalk and of overlying relatively low permeability superficial deposits. Consequently, it is concluded that the overarching controls on groundwater flood response are a complex combination of antecedent conditions, rainfall and catchment hydrogeological properties. These controls should be taken into consideration when anticipating and managing future groundwater flood events.

On the rate and causes of twentieth century sea-level rise.

PubMed

Miller, Laury; Douglas, Bruce C

2006-04-15

Both the rate and causes of twentieth century global sea-level rise (GSLR) have been controversial. Estimates from tide-gauges range from less than one, to more than two millimetre yr(-1). In contrast, values based on the processes mostly responsible for GSLR-mass increase (from mountain glaciers and the great high latitude ice masses) and volume increase (expansion due to ocean warming)-fall below this range. Either the gauge estimates are too high, or one (or both) of the component estimates is too low. Gauge estimates of GSLR have been in dispute for several decades because of vertical land movements, especially due to glacial isostatic adjustment (GIA). More recently, the possibility has been raised that coastal tide-gauges measure exaggerated rates of sea-level rise because of localized ocean warming. Presented here are two approaches to a resolution of these problems. The first is morphological, based on the limiting values of observed trends of twentieth century relative sea-level rise as a function of distance from the centres of the ice loads at last glacial maximum. This observational approach, which does not depend on a geophysical model of GIA, supports values of GSLR near 2 mm yr(-1). The second approach involves an analysis of long records of tide-gauge and hydrographic (in situ temperature and salinity) observations in the Pacific and Atlantic Oceans. It was found that sea-level trends from tide-gauges, which reflect both mass and volume change, are 2-3 times higher than rates based on hydrographic data which reveal only volume change. These results support those studies that put the twentieth century rate near 2 mm yr(-1), thereby indicating that mass increase plays a much larger role than ocean warming in twentieth century GSLR.

15 CFR 996.23 - Audit and decertification of hydrographic products.

Code of Federal Regulations, 2010 CFR

2010-01-01

... hydrographic products it has certified. NOAA may conduct audits without advance notification. However, visits... 15 Commerce and Foreign Trade 3 2010-01-01 2010-01-01 false Audit and decertification of... ASSURANCE AND CERTIFICATION REQUIREMENTS FOR NOAA HYDROGRAPHIC PRODUCTS AND SERVICES QUALITY ASSURANCE AND...

Integrated acoustic phase separator and multiphase fluid composition monitoring apparatus and method

DOEpatents

Sinha, Dipen N.

2016-01-12

An apparatus and method for down hole gas separation from the multiphase fluid flowing in a wellbore or a pipe, for determining the quantities of the individual components of the liquid and the flow rate of the liquid, and for remixing the component parts of the fluid after which the gas volume may be measured, without affecting the flow stream, are described. Acoustic radiation force is employed to separate gas from the liquid, thereby permitting measurements to be separately made for these two components; the liquid (oil/water) composition is determined from ultrasonic resonances; and the gas volume is determined from capacitance measurements. Since the fluid flows around and through the component parts of the apparatus, there is little pressure difference, and no protection is required from high pressure differentials.

Integrated acoustic phase separator and multiphase fluid composition monitoring apparatus and method

DOEpatents

Sinha, Dipen N

2014-02-04

An apparatus and method for down hole gas separation from the multiphase fluid flowing in a wellbore or a pipe, for determining the quantities of the individual components of the liquid and the flow rate of the liquid, and for remixing the component parts of the fluid after which the gas volume may be measured, without affecting the flow stream, are described. Acoustic radiation force is employed to separate gas from the liquid, thereby permitting measurements to be separately made for these two components; the liquid (oil/water) composition is determined from ultrasonic resonances; and the gas volume is determined from capacitance measurements. Since the fluid flows around and through the component parts of the apparatus, there is little pressure difference, and no protection is required from high pressure differentials.

Salinity minima, water masses and surface circulation in the Eastern Tropical Pacific off Mexico and surrounding areas

NASA Astrophysics Data System (ADS)

Portela, Esther; Beier, Emilio; Godínez, Victor; Castro, Rubén; Desmond Barton, Eric

2016-04-01

The seasonal variations of the water masses and their interactions are analyzed in the Tropical Pacific off Mexico (TPOM) and four contiguous areas of on the basis of new extensive hydrographic database. The regional water masses intervals are redefined in terms of Absolute Salinity (SA) in g kg-1 and Conservative Temperature (Θ) according to TEOS - 10. The California Current System Water (CCSW) mass is introduced as an improved description of the former California Current Water (CCW) together with the Subarctic Water (SAW) to describe better the characteristics of the components of the California Current System. Hydrographic data, Precipitation-Evaporation balance and geostrophic currents were used to investigate the origin and seasonality of two salinity minima in the area. The shallow salinity minimum of around 33.5 g kg-1 originated in the California Current System and became saltier but less dense water as it traveled to the southeast. It can be identified as a mixture of CCSW and tropical waters. The surface salinity minimum of 32 - 33 g kg-1 was seen as a sharp surface feature in the TPOM from August to November. It was produced by the arrival of tropical waters from the south in combination with the net precipitation in the area during these months. This result provides new evidence of the presence of the poleward-flowing Mexican Coastal Current and, for the first time, of its seasonal pattern of variation.

Independent component analysis separates spikes of different origin in the EEG.

PubMed

Urrestarazu, Elena; Iriarte, Jorge; Artieda, Julio; Alegre, Manuel; Valencia, Miguel; Viteri, César

2006-02-01

Independent component analysis (ICA) is a novel system that finds independent sources in recorded signals. Its usefulness in separating epileptiform activity of different origin has not been determined. The goal of this study was to demonstrate that ICA is useful for separating different spikes using samples of EEG of patients with focal epilepsy. Digital EEG samples from four patients with focal epilepsy were included. The patients had temporal (n = 2), centrotemporal (n = 1) or frontal spikes (n = 1). Twenty-six samples with two (or more) spikes from two different patients were created. The selection of the two spikes for each mixed EEG was performed randomly, trying to have all the different combinations and rejecting the mixture of two spikes from the same patient. Two different examiners studied the EEGs using ICA with JADE paradigm in Matlab platform, trying to separate and to identify the spikes. They agreed in the correct separation of the spikes in 24 of the 26 samples, classifying the spikes as frontal, temporal or centrotemporal, left or right sided. The demonstration of the possibility of detecting different artificially mixed spikes confirms that ICA may be useful in separating spikes or other elements in real EEGs.

Predictions of runoff signatures in ungauged basins: Austrian case study

NASA Astrophysics Data System (ADS)

Viglione, A.; Parajka, J.; Salinas, J.; Rogger, M.; Sivapalan, M.; Bloeschl, G.

2012-12-01

Runoff variability can be broken up into several components, each of them meaningful of a certain class of applications of societal relevance: annual runoff, seasonal runoff, flow duration curve, low flows, floods and hydrographs. We call them runoff signatures and we view them as a manifestation of catchment functioning at different time scales, as emergent properties of the complex systems that catchments are. Just as a medical doctor has many different options for studying the state and functioning of a patient, we can infer the state and functioning of a catchment observing its runoff signatures. But what can we do in the absence of runoff data? This study aims to understand how well one can predict runoff signatures in ungauged catchments. The comparison across signatures is based on one consistent data set (Austria) and one regionalisation method (Top-Kriging) in order to explore the relative performance of the predictions of each of the signatures. Results indicate that the performance, assessed by cross-validation, is best for annual and seasonal runoff, it degrades as one moves to low flows and floods and goes up again to high values for runoff hydrographs. Also, dedicated regionalisation methods, i.e. focusing on particular signatures and their characteristics, provide better predictions of the signatures than regionalisation of the entire hydrograph. These results suggest that the use of signatures in the calibration or assessment of process models can be valuable, in that this can lead to models predicting runoff correctly for the right reasons.

Counter-rotating accretion discs

NASA Astrophysics Data System (ADS)

Dyda, S.; Lovelace, R. V. E.; Ustyugova, G. V.; Romanova, M. M.; Koldoba, A. V.

2015-01-01

Counter-rotating discs can arise from the accretion of a counter-rotating gas cloud on to the surface of an existing corotating disc or from the counter-rotating gas moving radially inwards to the outer edge of an existing disc. At the interface, the two components mix to produce gas or plasma with zero net angular momentum which tends to free-fall towards the disc centre. We discuss high-resolution axisymmetric hydrodynamic simulations of viscous counter-rotating discs for the cases where the two components are vertically separated and radially separated. The viscosity is described by an isotropic α-viscosity including all terms in the viscous stress tensor. For the vertically separated components, a shear layer forms between them and the middle part of this layer free-falls to the disc centre. The accretion rates are increased by factors of ˜102-104 over that for a conventional disc rotating in one direction with the same viscosity. The vertical width of the shear layer and the accretion rate are strongly dependent on the viscosity and the mass fraction of the counter-rotating gas. In the case of radially separated components where the inner disc corotates and the outer disc rotates in the opposite direction, a gap between the two components opens and closes quasi-periodically. The accretion rates are ≳25 times larger than those for a disc rotating in one direction with the same viscosity.

Stable oxygen isotope variability in two contrasting glacier river catchments in Greenland

NASA Astrophysics Data System (ADS)

Yde, Jacob C.; Knudsen, Niels T.; Steffensen, Jørgen P.; Carrivick, Jonathan L.; Hasholt, Bent; Ingeman-Nielsen, Thomas; Kronborg, Christian; Larsen, Nicolaj K.; Mernild, Sebastian H.; Oerter, Hans; Roberts, David H.; Russell, Andrew J.

2016-03-01

Analysis of stable oxygen isotope (δ18O) characteristics is a useful tool to investigate water provenance in glacier river systems. In order to attain knowledge on the diversity of δ18O variations in Greenlandic rivers, we examined two contrasting glacierised catchments disconnected from the Greenland Ice Sheet (GrIS). At the Mittivakkat Gletscher river, a small river draining a local temperate glacier in southeast Greenland, diurnal oscillations in δ18O occurred with a 3 h time lag to the diurnal oscillations in run-off. The mean annual δ18O was -14.68 ± 0.18 ‰ during the peak flow period. A hydrograph separation analysis revealed that the ice melt component constituted 82 ± 5 % of the total run-off and dominated the observed variations during peak flow in August 2004. The snowmelt component peaked between 10:00 and 13:00 local time, reflecting the long travel time and an inefficient distributed subglacial drainage network in the upper part of the glacier. At the Kuannersuit Glacier river on the island Qeqertarsuaq in west Greenland, the δ18O characteristics were examined after the major 1995-1998 glacier surge event. The mean annual δ18O was -19.47 ± 0.55 ‰. Despite large spatial variations in the δ18O values of glacier ice on the newly formed glacier tongue, there were no diurnal oscillations in the bulk meltwater emanating from the glacier in the post-surge years. This is likely a consequence of a tortuous subglacial drainage system consisting of linked cavities, which formed during the surge event. Overall, a comparison of the δ18O compositions from glacial river water in Greenland shows distinct differences between water draining local glaciers and ice caps (between -23.0 and -13.7 ‰) and the GrIS (between -29.9 and -23.2 ‰). This study demonstrates that water isotope analyses can be used to obtain important information on water sources and the subglacial drainage system structure that is highly desired for understanding glacier hydrology.

A method for estimating peak and time of peak streamflow from excess rainfall for 10- to 640-acre watersheds in the Houston, Texas, metropolitan area

USGS Publications Warehouse

Asquith, William H.; Cleveland, Theodore G.; Roussel, Meghan C.

2011-01-01

Estimates of peak and time of peak streamflow for small watersheds (less than about 640 acres) in a suburban to urban, low-slope setting are needed for drainage design that is cost-effective and risk-mitigated. During 2007-10, the U.S. Geological Survey (USGS), in cooperation with the Harris County Flood Control District and the Texas Department of Transportation, developed a method to estimate peak and time of peak streamflow from excess rainfall for 10- to 640-acre watersheds in the Houston, Texas, metropolitan area. To develop the method, 24 watersheds in the study area with drainage areas less than about 3.5 square miles (2,240 acres) and with concomitant rainfall and runoff data were selected. The method is based on conjunctive analysis of rainfall and runoff data in the context of the unit hydrograph method and the rational method. For the unit hydrograph analysis, a gamma distribution model of unit hydrograph shape (a gamma unit hydrograph) was chosen and parameters estimated through matching of modeled peak and time of peak streamflow to observed values on a storm-by-storm basis. Watershed mean or watershed-specific values of peak and time to peak ("time to peak" is a parameter of the gamma unit hydrograph and is distinct from "time of peak") of the gamma unit hydrograph were computed. Two regression equations to estimate peak and time to peak of the gamma unit hydrograph that are based on watershed characteristics of drainage area and basin-development factor (BDF) were developed. For the rational method analysis, a lag time (time-R), volumetric runoff coefficient, and runoff coefficient were computed on a storm-by-storm basis. Watershed-specific values of these three metrics were computed. A regression equation to estimate time-R based on drainage area and BDF was developed. Overall arithmetic means of volumetric runoff coefficient (0.41 dimensionless) and runoff coefficient (0.25 dimensionless) for the 24 watersheds were used to express the rational method in terms of excess rainfall (the excess rational method). Both the unit hydrograph method and excess rational method are shown to provide similar estimates of peak and time of peak streamflow. The results from the two methods can be combined by using arithmetic means. A nomograph is provided that shows the respective relations between the arithmetic-mean peak and time of peak streamflow to drainage areas ranging from 10 to 640 acres. The nomograph also shows the respective relations for selected BDF ranging from undeveloped to fully developed conditions. The nomograph represents the peak streamflow for 1 inch of excess rainfall based on drainage area and BDF; the peak streamflow for design storms from the nomograph can be multiplied by the excess rainfall to estimate peak streamflow. Time of peak streamflow is readily obtained from the nomograph. Therefore, given excess rainfall values derived from watershed-loss models, which are beyond the scope of this report, the nomograph represents a method for estimating peak and time of peak streamflow for applicable watersheds in the Houston metropolitan area. Lastly, analysis of the relative influence of BDF on peak streamflow is provided, and the results indicate a 0:04log10 cubic feet per second change of peak streamflow per positive unit of change in BDF. This relative change can be used to adjust peak streamflow from the method or other hydrologic methods for a given BDF to other BDF values; example computations are provided.

Development of a Technique for Separating Raman Scattering Signals from Background Emission with Single-Shot Measurement Potential

NASA Technical Reports Server (NTRS)

Hartfield, Roy J., Jr.; Dobson, Chris; Eskridge, Richard; Wehrmeyer, Joseph A.

1997-01-01

A novel technique for extracting Q-branch Raman signals scattered by a diatomic species from the emission spectrum resulting from the irradiation of combustion products using a broadband excimer laser has been developed. This technique is based on the polarization characteristics of vibrational Raman scattering and can be used for both single-shot Raman extraction and time-averaged data collection. The Q-branch Raman signal has a unique set of polarization characteristics which depend on the direction of the scattering while fluorescence signals are unpolarized. For the present work, a calcite crystal is used to separate the horizonal component of a collected signal from the vertical component. The two components are then sent through a UV spectrometer and imaged onto an intensified CCD camera separately. The vertical component contains both the Raman signal and the interfering fluorescence signal. The horizontal component contains the fluorescence signal and a very weak component of the Raman signal; hence, the Raman scatter can be extracted by taking the difference between the two signals. The separation of the Raman scatter from interfering fluorescence signals is critically important to the interpretation of the Raman for cases in which a broadband ultraviolet (UV) laser is used as an excitation source in a hydrogen-oxygen flame and in all hydrocarbon flames. The present work provides a demonstration of the separation of the Raman scatter from the fluorescence background in real time.

15 CFR 996.13 - Determination of whether to offer certification for a hydrographic product or class.

Code of Federal Regulations, 2012 CFR

2012-01-01

..., DEPARTMENT OF COMMERCE QUALITY ASSURANCE AND CERTIFICATION REQUIREMENTS FOR NOAA HYDROGRAPHIC PRODUCTS AND SERVICES QUALITY ASSURANCE AND CERTIFICATION REQUIREMENTS FOR NOAA HYDROGRAPHIC PRODUCTS AND SERVICES The... at the option of NOAA. NOAA may decide at any time whether or not to offer certification for a...

15 CFR 996.13 - Determination of whether to offer certification for a hydrographic product or class.

Code of Federal Regulations, 2011 CFR

2011-01-01

..., DEPARTMENT OF COMMERCE QUALITY ASSURANCE AND CERTIFICATION REQUIREMENTS FOR NOAA HYDROGRAPHIC PRODUCTS AND SERVICES QUALITY ASSURANCE AND CERTIFICATION REQUIREMENTS FOR NOAA HYDROGRAPHIC PRODUCTS AND SERVICES The... at the option of NOAA. NOAA may decide at any time whether or not to offer certification for a...

15 CFR 996.13 - Determination of whether to offer certification for a hydrographic product or class.

Code of Federal Regulations, 2013 CFR

2013-01-01

..., DEPARTMENT OF COMMERCE QUALITY ASSURANCE AND CERTIFICATION REQUIREMENTS FOR NOAA HYDROGRAPHIC PRODUCTS AND SERVICES QUALITY ASSURANCE AND CERTIFICATION REQUIREMENTS FOR NOAA HYDROGRAPHIC PRODUCTS AND SERVICES The... at the option of NOAA. NOAA may decide at any time whether or not to offer certification for a...

15 CFR 996.13 - Determination of whether to offer certification for a hydrographic product or class.

Code of Federal Regulations, 2014 CFR

2014-01-01

..., DEPARTMENT OF COMMERCE QUALITY ASSURANCE AND CERTIFICATION REQUIREMENTS FOR NOAA HYDROGRAPHIC PRODUCTS AND SERVICES QUALITY ASSURANCE AND CERTIFICATION REQUIREMENTS FOR NOAA HYDROGRAPHIC PRODUCTS AND SERVICES The... at the option of NOAA. NOAA may decide at any time whether or not to offer certification for a...

Daily values flow comparison and estimates using program HYCOMP, version 1.0

USGS Publications Warehouse

Sanders, Curtis L.

2002-01-01

A method used by the U.S. Geological Survey for quality control in computing daily value flow records is to compare hydrographs of computed flows at a station under review to hydrographs of computed flows at a selected index station. The hydrographs are placed on top of each other (as hydrograph overlays) on a light table, compared, and missing daily flow data estimated. This method, however, is subjective and can produce inconsistent results, because hydrographers can differ when calculating acceptable limits of deviation between observed and estimated flows. Selection of appropriate index stations also is judgemental, giving no consideration to the mathematical correlation between the review station and the index station(s). To address the limitation of the hydrograph overlay method, a set of software programs, written in the SAS macrolanguage, was developed and designated Program HYDCOMP. The program automatically selects statistically comparable index stations by correlation and regression, and performs hydrographic comparisons and estimates of missing data by regressing daily mean flows at the review station against -8 to +8 lagged flows at one or two index stations and day-of-week. Another advantage that HYDCOMP has over the graphical method is that estimated flows, the criteria for determining the quality of the data, and the selection of index stations are determined statistically, and are reproducible from one user to another. HYDCOMP will load the most-correlated index stations into another file containing the ?best index stations,? but will not overwrite stations already in the file. A knowledgeable user should delete unsuitable index stations from this file based on standard error of estimate, hydrologic similarity of candidate index stations to the review station, and knowledge of the individual station characteristics. Also, the user can add index stations not selected by HYDCOMP, if desired. Once the file of best-index stations is created, a user may do hydrographic comparison and data estimates by entering the number of the review station, selecting an index station, and specifying the periods to be used for regression and plotting. For example, the user can restrict the regression to ice-free periods of the year to exclude flows estimated during iced conditions. However, the regression could still be used to estimate flow during iced conditions. HYDCOMP produces the standard error of estimate as a measure of the central scatter of the regression and R-square (coefficient of determination) for evaluating the accuracy of the regression. Output from HYDCOMP includes plots of percent residuals against (1) time within the regression and plot periods, (2) month and day of the year for evaluating seasonal bias in the regression, and (3) the magnitude of flow. For hydrographic comparisons, it plots 2-month segments of hydrographs over the selected plot period showing the observed flows, the regressed flows, the 95 percent confidence limit flows, flow measurements, and regression limits. If the observed flows at the review station remain outside the 95 percent confidence limits for a prolonged period, there may be some error in the flows at the review station or at the index station(s). In addition, daily minimum and maximum temperatures and daily rainfall are shown on the hydrographs, if available, to help indicate whether an apparent change in flow may result from rainfall or from changes in backwater from melting ice or freezing water. HYDCOMP statistically smooths estimated flows from non-missing flows at the edges of the gaps in data into regressed flows at the center of the gaps using the Kalman smoothing algorithm. Missing flows are automatically estimated by HYDCOMP, but the user also can specify that periods of erroneous, but nonmissing flows, be estimated by the program.

Investigation of Separation of the Turbulent Boundary Layer

NASA Technical Reports Server (NTRS)

Schubauer, G B; Klebanoff, P S

1951-01-01

An investigation was conducted on a turbulent boundary layer near a smooth surface with pressure gradients sufficient to cause flow separation. The reynolds number was high, but the speeds were entirely within the incompressible flow range. The investigation consisted of measurements of mean flow, three components of turbulence intensity, turbulent shearing stress, and correlations between two fluctuation components at a point and between the same component of different points. The results are given in the form of tables and graphs. The discussion deals first with separation and then with the more fundamental question of basic concepts of turbulent flow.

Multidimensional profiling of components in complex mixtures of natural products for metabolic analysis, proof of concept: application to Quillaja saponins.

PubMed

Bankefors, Johan; Nord, Lars I; Kenne, Lennart

2010-02-01

A method for separation and detection of major and minor components in complex mixtures has been developed, utilising two-dimensional high-performance liquid chromatography (2D-HPLC) combined with electrospray ionisation ion-trap multiple-stage mass spectrometry (ESI-ITMS(n)). Chromatographic conditions were matched with mass spectrometric detection to maximise the number of components that could be separated. The described procedure has proven useful to discern several hundreds of saponin components when applied to Quillaja saponaria Molina bark extracts. The discrimination of each saponin component relies on the fact that three coordinates (x, y, z) for each component can be derived from the retention time of the two chromatographic steps (x, y) and the m/z-values from the multiple-stage mass spectrometry (z(n), n=1, 2, ...). Thus an improved graphical representation was obtained by combining retention times from the two-stage separation with +MS(1) (z(1)) and the additional structural information from the second mass stage +MS(2) (z(2), z(3)) corresponding to the main fragment ions. By this approach three-dimensional plots can be made that reveal both the chromatographic and structural properties of a specific mixture which can be useful in fingerprinting of complex mixtures. 2009 Elsevier B.V. All rights reserved.

Technique for simulating peak-flow hydrographs in Maryland

USGS Publications Warehouse

Dillow, Jonathan J.A.

1998-01-01

The efficient design and management of many bridges, culverts, embankments, and flood-protection structures may require the estimation of time-of-inundation and (or) storage of floodwater relating to such structures. These estimates can be made on the basis of information derived from the peak-flow hydrograph. Average peak-flow hydrographs corresponding to a peak discharge of specific recurrence interval can be simulated for drainage basins having drainage areas less than 500 square miles in Maryland, using a direct technique of known accuracy. The technique uses dimensionless hydrographs in conjunction with estimates of basin lagtime and instantaneous peak flow. Ordinary least-squares regression analysis was used to develop an equation for estimating basin lagtime in Maryland. Drainage area, main channel slope, forest cover, and impervious area were determined to be the significant explanatory variables necessary to estimate average basin lagtime at the 95-percent confidence interval. Qualitative variables included in the equation adequately correct for geographic bias across the State. The average standard error of prediction associated with the equation is approximated as plus or minus (+/-) 37.6 percent. Volume correction factors may be applied to the basin lagtime on the basis of a comparison between actual and estimated hydrograph volumes prior to hydrograph simulation. Three dimensionless hydrographs were developed and tested using data collected during 278 significant rainfall-runoff events at 81 stream-gaging stations distributed throughout Maryland and Delaware. The data represent a range of drainage area sizes and basin conditions. The technique was verified by applying it to the simulation of 20 peak-flow events and comparing actual and simulated hydrograph widths at 50 and 75 percent of the observed peak-flow levels. The events chosen are considered extreme in that the average recurrence interval of the selected peak flows is 130 years. The average standard errors of prediction were +/- 61 and +/- 56 percent at the 50 and 75 percent of peak-flow hydrograph widths, respectively.

Data Report of Hydrographic Observations: Geomagnetic Observations at the Hatizyo Hydrographic Observatory for the Year 1994. No. 12

NASA Technical Reports Server (NTRS)

1996-01-01

The Hatizyo Hydrographic Observatory, which is one of the essential magnetic observatories in Japan, was established in 1979 and is currently operated by the Hydrographic Department, Maritime Safety Agency. This is the annual report compiled from the results of magnetic observations carried out at the observatory in 1994. As to the instruments used for magnetic observations, the digital recording variometer was replaced by a fluxgate magnetometer in 1986, and one set each of the proton and fluxgate magnetometers was additionally installed in January and October 1992, respectively.

Data Report of Hydrographic Observations: Geomagnetic Observations at the Hatizyo Hydrographic Observatory for the Year 1993. No. 11

NASA Technical Reports Server (NTRS)

1995-01-01

The Hatizyo Hydrographic Observatory, which is one of the essential magnetic observatories in Japan, was established in 1979 and is currently operated by the Hydrographic Department, Maritime Safety Agency. This is the annual report compiled from the results of magnetic observations carried out at the observatory in 1993. As to the instruments used for magnetic observations, the digital recording variometer was replaced by a fluxgate magnetometer in 1986, and one set each of the proton and fluxgate magnetometers was additionally installed in January and October 1992, respectively.

Fast comprehensive two-dimensional gas chromatography method for fatty acid methyl ester separation and quantification using dual ionic liquid columns.

PubMed

Nosheen, Asia; Mitrevski, Blagoj; Bano, Asghari; Marriott, Philip J

2013-10-18

Safflower oil is a complex mixture of C18 saturated and unsaturated fatty acids amongst other fatty acids, and achieving separation between these similar structure components using one dimensional gas chromatography (GC) may be difficult. This investigation aims to obtain improved separation of fatty acid methyl esters in safflower oil, and their quantification using comprehensive two-dimensional GC (GC×GC). Here, GC×GC separation is accomplished by the coupling of two ionic liquid (IL) column phases: the combination of SLB-IL111 with IL59 column phases was finally selected since it provided excellent separation of a FAME standard mixture, as well as fatty acids in safflower and linseed oil, compared to other tested column sets. Safflower oil FAME were well separated in a short run of 16min. FAME validation was demonstrated by method reproducibility, linearity over a range up to 500mgL(-1), and limits of detection which ranged from 1.9mgL(-1) to 5.2mgL(-1) at a split ratio of 20:1. Quantification was carried out using two dilution levels of 200-fold for major components and 20-fold for trace components. The fatty acids C15:0 and C17:0 were not reported previously in safflower oil. The SLB-IL111/IL59 column set proved to be an effective and novel configuration for separation and quantification of vegetable and animal oil fatty acids. Copyright © 2013 Elsevier B.V. All rights reserved.

Unravel Spurious Bathymetric Highs on the Western Continental Margin of India

NASA Astrophysics Data System (ADS)

Mahale, V. P.

2017-12-01

Swath mapping multibeam echosounder systems (MBES) have become a de-facto-standard component on today's research vessel (RV). Modern MBES provide high temporal and spatial resolution for mapping the seabed morphology. Improved resolution capabilities requires large hull mounted transceivers, which after installation undergoes calibration procedure during the sea acceptance test (SAT). To accurately estimate various vessel offsets and lever-arm corrections, the installer runs calibration lines over a prominent seabed feature. In the year 2014, while conducting SAT for the RV Sindhu Sadhana and calibrate the ATLAS make MBES system, a hunt was on to find suitable bathymetric highs in the region of operation. Regional hydrographic charts published by the National Hydrographic Office, in India were referred to locate such features. Two bathymetric highs were spotted on the chart that are 20 km apart and 40 km west of the shelf-edge on the Western Continental Margin of India. The charted depth on these highs are 252 m and 343 m on a relatively even but moderately sloppy seabed, representing an isolated elevations of 900 m. The geographic locations of these knolls were verified with the GEBCO's 30-arc second gridded bathymetry, before heading out for the waypoints. There were no signs of knolls at those locations, indicating erroneous georeferencing. Hence, the region was subsequently revisited in the following years until an area of 3000 sq. km was mapped. Failing to locate the bathymetric highs they are referred to as 'spurious'. Investigation was planned to unravel the rationale of existence and sustenance of these knolls in the hydrographic charts since historic time. Tweaking the MBES settings reveals existence of strong acoustic scattering layer, to which even the depth tracking gate gets locked-on and is documented. Analogically, in the past, ships transecting the region equipped with single beam echosounder tuned for shallow depth operations might have charted the scattering layer and contributed to crowdsourced bathymetry eventually. Literature study indicates deepsea scattering layer (DSL) prevalent in the study region, having diurnal variation with depths similar to those on the chart. The author thus hypothesize that DSL would have been the rationale behind the existence of spurious bathymetric highs.

Flotability and flotation separation of polymer materials modulated by wetting agents.

PubMed

Wang, Hui; Wang, Chong-qing; Fu, Jian-gang; Gu, Guo-hua

2014-02-01

The surface free energy, surface tension and contact angles were performed to investigate the properties of wetting agents. Adsorption of wetting agents changes wetting behavior of polymer resins. Flotability of polymer materials modulated by wetting agents was studied, and wetting agents change significantly flotability of polymer materials. The flotability decreases with increasing the concentration of wetting agents, and the wetting ability is lignin sulfonate (LS)>tannic acid (TA)>methylcellulose (MC)>triton X-100 (TX-100) (from strong to weak). There is significant difference in the flotability between polymer resins and plastics due to the presence of additives in the plastics. Flotation separation of two-component and multicomponent plastics was conducted based on the flotability modulated by wetting agents. The two-component mixtures can be efficiently separated using proper wetting agent through simple flotation flowsheet. The multicomponent plastic mixtures can be separated efficiently through multi-stage flotation using TA and LS as wetting agents, and the purity of separated component was above 94%, and the recovery was more than 93%. Copyright © 2013 Elsevier Ltd. All rights reserved.

Estimation of daily stream flow of southeastern coastal plain watersheds by combining estimated magnitude and sequence

Treesearch

Herbert Ssegane; Devendra M. Amatya; E.W. Tollner; Zhaohua Dai; Jami E. Nettles

2013-01-01

Commonly used methods to predict streamflow at ungauged watersheds implicitly predict streamflow magnitude and temporal sequence concurrently. An alternative approach that has not been fully explored is the conceptualization of streamflow as a composite of two separable components of magnitude and sequence, where each component is estimated separately and then combined...

Where does streamwater come from in low-relief forested watersheds? A dual-isotope approach

DOE Office of Scientific and Technical Information (OSTI.GOV)

Klaus, J.; McDonnell, J. J.; Jackson, C. R.

The time and geographic sources of streamwater in low-relief watersheds are poorly understood. This is partly due to the difficult combination of low runoff coefficients and often damped streamwater isotopic signals precluding traditional hydrograph separation and convolution integral approaches. Here we present a dual-isotope approach involving 18O and 2H of water in a low-angle forested watershed to determine streamwater source components and then build a conceptual model of streamflow generation. We focus on three headwater lowland sub-catchments draining the Savannah River Site in South Carolina, USA. Our results for a 3-year sampling period show that the slopes of the meteoricmore » water lines/evaporation water lines (MWLs/EWLs) of the catchment water sources can be used to extract information on runoff sources in ways not considered before. Our dual-isotope approach was able to identify unique hillslope, riparian and deep groundwater, and streamflow compositions. Thus, the streams showed strong evaporative enrichment compared to the local meteoric water line (δ 2H = 7.15 · δ 18O +9.28‰) with slopes of 2.52, 2.84, and 2.86. Based on the unique and unambiguous slopes of the EWLs of the different water cycle components and the isotopic time series of the individual components, we were able to show how the riparian zone controls baseflow in this system and how the riparian zone "resets" the stable isotope composition of the observed streams in our low-angle, forested watersheds. Although this approach is limited in terms of quantifying mixing percentages between different end-members, our dual-isotope approach enabled the extraction of hydrologically useful information in a region with little change in individual isotope time series.« less

Where does streamwater come from in low-relief forested watersheds? A dual-isotope approach

DOE PAGES

Klaus, J.; McDonnell, J. J.; Jackson, C. R.; ...

2015-01-08

The time and geographic sources of streamwater in low-relief watersheds are poorly understood. This is partly due to the difficult combination of low runoff coefficients and often damped streamwater isotopic signals precluding traditional hydrograph separation and convolution integral approaches. Here we present a dual-isotope approach involving 18O and 2H of water in a low-angle forested watershed to determine streamwater source components and then build a conceptual model of streamflow generation. We focus on three headwater lowland sub-catchments draining the Savannah River Site in South Carolina, USA. Our results for a 3-year sampling period show that the slopes of the meteoricmore » water lines/evaporation water lines (MWLs/EWLs) of the catchment water sources can be used to extract information on runoff sources in ways not considered before. Our dual-isotope approach was able to identify unique hillslope, riparian and deep groundwater, and streamflow compositions. Thus, the streams showed strong evaporative enrichment compared to the local meteoric water line (δ 2H = 7.15 · δ 18O +9.28‰) with slopes of 2.52, 2.84, and 2.86. Based on the unique and unambiguous slopes of the EWLs of the different water cycle components and the isotopic time series of the individual components, we were able to show how the riparian zone controls baseflow in this system and how the riparian zone "resets" the stable isotope composition of the observed streams in our low-angle, forested watersheds. Although this approach is limited in terms of quantifying mixing percentages between different end-members, our dual-isotope approach enabled the extraction of hydrologically useful information in a region with little change in individual isotope time series.« less

Microbial, physical and chemical properties of irrigation water in rice fields of Southern Brazil.

PubMed

Reche, Maria Helena L R; Machado, Vilmar; Saul, Danilo A; Macedo, Vera R M; Marcolin, Elio; Knaak, Neiva; Fiuza, Lidia M

2016-03-01

This paper presents the results of the statistical analysis of microbiological, physical and chemical parameters related to the quality of the water used in rice fields in Southern Brazil. Data were collected during three consecutive crop years, within structure of a comprehensive monitoring program. The indicators used were: potential hydrogen, electrical conductivity, turbidity, nitrogen, phosphorus, potassium, calcium, total and fecal coliforms. Principal Component and Discriminant Analysis showed consistent differences between the water irrigation and drainage, as the temporal variation demonstrated a clear reduction in the concentration of most of the variables analyzed. The pattern of this reduction is not the same in the two regions - that is, the importance of each of the different variables in the observed differentiation is modified in two locations. These results suggested that the variations in the water quality utilized for rice irrigation was influenced by certain specific aspects of each rice region in South Brazilian - such as anthropic action or soil/climate conditions in each hydrographic basin.

Integrated Hydrographical Basin Management. Study Case - Crasna River Basin

NASA Astrophysics Data System (ADS)

Visescu, Mircea; Beilicci, Erika; Beilicci, Robert

2017-10-01

Hydrographical basins are important from hydrological, economic and ecological points of view. They receive and channel the runoff from rainfall and snowmelt which, when adequate managed, can provide fresh water necessary for water supply, irrigation, food industry, animal husbandry, hydrotechnical arrangements and recreation. Hydrographical basin planning and management follows the efficient use of available water resources in order to satisfy environmental, economic and social necessities and constraints. This can be facilitated by a decision support system that links hydrological, meteorological, engineering, water quality, agriculture, environmental, and other information in an integrated framework. In the last few decades different modelling tools for resolving problems regarding water quantity and quality were developed, respectively water resources management. Watershed models have been developed to the understanding of water cycle and pollution dynamics, and used to evaluate the impacts of hydrotechnical arrangements and land use management options on water quantity, quality, mitigation measures and possible global changes. Models have been used for planning monitoring network and to develop plans for intervention in case of hydrological disasters: floods, flash floods, drought and pollution. MIKE HYDRO Basin is a multi-purpose, map-centric decision support tool for integrated hydrographical basin analysis, planning and management. MIKE HYDRO Basin is designed for analyzing water sharing issues at international, national and local hydrographical basin level. MIKE HYDRO Basin uses a simplified mathematical representation of the hydrographical basin including the configuration of river and reservoir systems, catchment hydrology and existing and potential water user schemes with their various demands including a rigorous irrigation scheme module. This paper analyzes the importance and principles of integrated hydrographical basin management and develop a case study for Crasna river basin, with the use of MIKE HYDRO Basin advanced hydroinformatic tool for integrated hydrographical basin analysis, planning and management.

Flow regime alterations under changing climate in two river basins: Implications for freshwater ecosystems

USGS Publications Warehouse

Gibson, C.A.; Meyer, J.L.; Poff, N.L.; Hay, L.E.; Georgakakos, A.

2005-01-01

We examined impacts of future climate scenarios on flow regimes and how predicted changes might affect river ecosystems. We examined two case studies: Cle Elum River, Washington, and Chattahoochee-Apalachicola River Basin, Georgia and Florida. These rivers had available downscaled global circulation model (GCM) data and allowed us to analyse the effects of future climate scenarios on rivers with (1) different hydrographs, (2) high future water demands, and (3) a river-floodplain system. We compared observed flow regimes to those predicted under future climate scenarios to describe the extent and type of changes predicted to occur. Daily stream flow under future climate scenarios was created by either statistically downscaling GCMs (Cle Elum) or creating a regression model between climatological parameters predicted from GCMs and stream flow (Chattahoochee-Apalachicola). Flow regimes were examined for changes from current conditions with respect to ecologically relevant features including the magnitude and timing of minimum and maximum flows. The Cle Elum's hydrograph under future climate scenarios showed a dramatic shift in the timing of peak flows and lower low flow of a longer duration. These changes could mean higher summer water temperatures, lower summer dissolved oxygen, and reduced survival of larval fishes. The Chattahoochee-Apalachicola basin is heavily impacted by dams and water withdrawals for human consumption; therefore, we made comparisons between pre-large dam conditions, current conditions, current conditions with future demand, and future climate scenarios with future demand to separate climate change effects and other anthropogenic impacts. Dam construction, future climate, and future demand decreased the flow variability of the river. In addition, minimum flows were lower under future climate scenarios. These changes could decrease the connectivity of the channel and the floodplain, decrease habitat availability, and potentially lower the ability of the river to assimilate wastewater treatment plant effluent. Our study illustrates the types of changes that river ecosystems might experience under future climates. Copyright ?? 2005 John Wiley & Sons, Ltd.

Simulation of extreme reservoir level distribution with the SCHADEX method (EXTRAFLO project)

NASA Astrophysics Data System (ADS)

Paquet, Emmanuel; Penot, David; Garavaglia, Federico

2013-04-01

The standard practice for the design of dam spillways structures and gates is to consider the maximum reservoir level reached for a given hydrologic scenario. This scenario has several components: peak discharge, flood volumes on different durations, discharge gradients etc. Within a probabilistic analysis framework, several scenarios can be associated with different return times, although a reference return level (e.g. 1000 years) is often prescribed by the local regulation rules or usual practice. Using continuous simulation method for extreme flood estimation is a convenient solution to provide a great variety of hydrological scenarios to feed a hydraulic model of dam operation: flood hydrographs are explicitly simulated by a rainfall-runoff model fed by a stochastic rainfall generator. The maximum reservoir level reached will be conditioned by the scale and the dynamics of the generated hydrograph, by the filling of the reservoir prior to the flood, and by the dam gates and spillway operation during the event. The simulation of a great number of floods will allow building a probabilistic distribution of maximum reservoir levels. A design value can be chosen at a definite return level. An alternative approach is proposed here, based on the SCHADEX method for extreme flood estimation, proposed by Paquet et al. (2006, 2013). SCHADEX is a so-called "semi-continuous" stochastic simulation method in that flood events are simulated on an event basis and are superimposed on a continuous simulation of the catchment saturation hazard using rainfall-runoff modelling. The SCHADEX process works at the study time-step (e.g. daily), and the peak flow distribution is deduced from the simulated daily flow distribution by a peak-to-volume ratio. A reference hydrograph relevant for extreme floods is proposed. In the standard version of the method, both the peak-to-volume and the reference hydrograph are constant. An enhancement of this method is presented, with variable peak-to-volume ratios and hydrographs applied to each simulated event. This allows accounting for different flood dynamics, depending on the season, the generating precipitation event, the soil saturation state, etc. In both cases, a hydraulic simulation of dam operation is performed, in order to compute the distribution of maximum reservoir levels. Results are detailed for an extreme return level, showing that a 1000 years return level reservoir level can be reached during flood events whose components (peaks, volumes) are not necessarily associated with such return level. The presentation will be illustrated by the example of a fictive dam on the Tech River at Reynes (South of France, 477 km²). This study has been carried out within the EXTRAFLO project, Task 8 (https://extraflo.cemagref.fr/). References: Paquet, E., Gailhard, J. and Garçon, R. (2006), Evolution of the GRADEX method: improvement by atmospheric circulation classification and hydrological modeling, La Houille Blanche, 5, 80-90. doi:10.1051/lhb:2006091. Paquet, E., Garavaglia, F., Garçon, R. and Gailhard, J. (2012), The SCHADEX method: a semi-continuous rainfall-runoff simulation for extreme food estimation, Journal of Hydrology, under revision

Laparoscopic versus open-component separation: a comparative analysis in a porcine model.

PubMed

Rosen, Michael J; Williams, Christina; Jin, Judy; McGee, Michael F; Schomisch, Steve; Marks, Jeffrey; Ponsky, Jeffrey

2007-09-01

The ideal surgical treatment for complicated ventral hernias remains elusive. Traditional component separation provides local advancement of native tissue for tension-free closure without prosthetic materials. This technique requires an extensive subcutaneous dissection with division of perforating vessels predisposing to skin-flap necrosis and complicated wound infections. A minimally invasive component separation may decrease wound complication rates; however, the adequacy of the myofascial advancement has not been studied. Five 25-kg pigs underwent bilateral laparoscopic component separation. A 10-mm incision was made lateral to the rectus abdominus muscle. The external oblique fascia was incised, and a dissecting balloon was inflated between the internal and external oblique muscles. Two additional ports were placed in the intermuscular space. The external oblique was incised from the costal margin to the inguinal ligament. The maximal abdominal wall advancement was recorded. A formal open-component separation was performed and maximal advancement 5 cm superior and 5 cm inferior to the umbilicus was recorded for comparison. Groups were compared using standard statistical analysis. The laparoscopic component separation was completed successfully in all animals, with a mean of 22 min/side. Laparoscopic component separation yielded 3.9 cm (SD 1.1) of fascial advancement above the umbilicus, whereas 4.4 cm (1.2) was obtained after open release (P = .24). Below the umbilicus, laparoscopic release achieved 5.0 cm (1.0) of advancement, whereas 5.8 cm (1.2) was gained after open release (P = .13). The minimally invasive component separation achieved an average of 86% of the myofascial advancement compared with a formal open release. The laparoscopic approach does not require extensive subcutaneous dissection and might theoretically result in a decreased incidence or decreased complexity of postoperative wound infections or skin-flap necrosis. Based on our preliminary data in this porcine model, further comparative studies of laparoscopic versus open component separation in complex ventral hernia repair is warranted to evaluate postoperative morbidity and long-term hernia recurrence rates.

Interest of A Morphological Explanation of The Unit Hydrograph Concept: Case of Urban Catchments

NASA Astrophysics Data System (ADS)

Rodriguez, F.; Cudennec, C.; Cellier, G.; Andrieu, H.

Expansion of urbanised areas has put emphasis on related water management prob- lems, such as flooding and pollution control, which requires a good knowledge of the hydrological response of urban catchments. Unfortunately, most of urban catchments are ungauged and their hydrological features must be deduced from existent data. A good description of the urban characteristics can give some advances in the field of urban hydrology : the geographical and physical knowledge of the city is made eas- ier by the emergence of urban data banks, introducing a meter-scale morphological description of the city. Linking the hydrological response of a catchment to its geo- morphology has been successfully implemented in natural settings within the concept of GIUH (Geomorphologic Instantaneous Unit Hydrograph). In the same manner, the available description of urban catchments makes it possible to deduce their hydrolog- ical behaviour throughout the Unit Hydrograph concept. We suggest to compare three complementary methods of determination of Unit Hydrographs, with increasing de- grees of description of the catchment morphology. The first method, presenting a high degree of accounting for the catchment morphology, is called MIUH (Morphologi- cal Instantaneous Unit Hydrograph; Rodriguez et al., 2000), and is derived from the analysis of urban databanks allowing an explicit description of the runoff production areas and their downstream flow channels. The second one, called H2U (Duchesne et al., 1997) and corresponding to a moderate degree, is a gamma law whose 2 pa- rameters are based on the Strahler order of the catchment and the mean hydraulic length of water paths through the drainage system. The third method, called FDTF (First Derivative Transfert Function; Duband et al., 1993) and corresponding to a low degree, is a validation method deriving Unit Hydrograph by a deconvolution itera- tive identification technique, from a sample of observed rainfall and flow data. The three methods are shortly summarised, and applied to two urban catchments of the Nantes urban center (60 and 180 ha), Western France. Their comparison is discussed and shows encouraging results. Deriving Unit Hydrographs from the morphology of ungauged catchment appears to be of high interest for hydrology, and the degree of accounting for informations about this morphology can be adapted according to the availability of geographical data on the studied catchment. Duchesne, J., C. Cudennec, and V. Corbierre, 1997. Relevance of the H2U model to 1 predict the discharge of a catchment, Water Science and Technology, 36(5), 169-175. Duband, D., C. Obled, and J. Rodriguez, 1993. Unit hydrograph revisited : an alterna- tive approach to UH and effective precipitation identification. Journal of Hydrology, 150(1): p 115-150. Rodriguez, F., H. Andrieu, J.D. Creutin, and G. Raimbault, 2000. Hydrological anal- ysis using urban data banks, paper presented at Hydroinformatics, IIHR Iowa City, USA. 2

Water-table and potentiometric-surface altitudes in the Upper Glacial, Magothy, and Lloyd aquifers of Long Island, New York, April-May 2013

USGS Publications Warehouse

Como, Michael D.; Noll, Michael L.; Finkelstein, Jason S.; Monti, Jack; Busciolano, Ronald J.

2015-01-01

Hydrographs are included on these maps for selected wells that have digital recording equipment. These hydrographs are representative of the 2013 water year to show the changes that have occurred throughout that period. The synoptic survey water level measured at the well is included on each hydrograph.

A combination strategy for extraction and isolation of multi-component natural products by systematic two-phase solvent extraction-(13)C nuclear magnetic resonance pattern recognition and following conical counter-current chromatography separation: Podophyllotoxins and flavonoids from Dysosma versipellis (Hance) as examples.

PubMed

Yang, Zhi; Wu, Youqian; Wu, Shihua

2016-01-29

Despite of substantial developments of extraction and separation techniques, isolation of natural products from natural resources is still a challenging task. In this work, an efficient strategy for extraction and isolation of multi-component natural products has been successfully developed by combination of systematic two-phase liquid-liquid extraction-(13)C NMR pattern recognition and following conical counter-current chromatography separation. A small-scale crude sample was first distributed into 9 systematic hexane-ethyl acetate-methanol-water (HEMWat) two-phase solvent systems for determination of the optimum extraction solvents and partition coefficients of the prominent components. Then, the optimized solvent systems were used in succession to enrich the hydrophilic and lipophilic components from the large-scale crude sample. At last, the enriched components samples were further purified by a new conical counter-current chromatography (CCC). Due to the use of (13)C NMR pattern recognition, the kinds and structures of major components in the solvent extracts could be predicted. Therefore, the method could collect simultaneously the partition coefficients and the structural information of components in the selected two-phase solvents. As an example, a cytotoxic extract of podophyllotoxins and flavonoids from Dysosma versipellis (Hance) was selected. After the systematic HEMWat system solvent extraction and (13)C NMR pattern recognition analyses, the crude extract of D. versipellis was first degreased by the upper phase of HEMWat system (9:1:9:1, v/v), and then distributed in the two phases of the system of HEMWat (2:8:2:8, v/v) to obtain the hydrophilic lower phase extract and lipophilic upper phase extract, respectively. These extracts were further separated by conical CCC with the HEMWat systems (1:9:1:9 and 4:6:4:6, v/v). As results, total 17 cytotoxic compounds were isolated and identified. In general, whole results suggested that the strategy was very efficient for the systematic extraction and isolation of biological active components from the complex biomaterials. Copyright © 2016 Elsevier B.V. All rights reserved.

Using diatoms, hydrochemical and stable isotope tracers to infer runoff generation processes

NASA Astrophysics Data System (ADS)

Martínez-Carreras, N.; Wetzel, C. E.; Frentress, J.; Hlúbiková, D.; Ector, L.; McDonnell, J. J.; Hoffmann, L.; Pfister, L.

2012-04-01

Imaginative techniques are needed to improve our understanding of runoff generation processes. In this context, the hydrological community calls to cut across disciplines looking for new and exciting advances in knowledge. In this study, hydrologists and ecologists have worked together to use not only hydrochemical and stable isotope tracers, but also diatoms to infer runoff generation processes. Diatoms, one of the most common and divers algal group, can be easily transported by flowing water due to their small size (~10-200 μm). They are present in most terrestrial habitats and their diversified species distributions are largely controlled by physico-geographical factors (e.g. light, temperature, pH and moisture). Thus, hydrological systems largely control diatom species community composition and distribution. This study was conducted in the schistose Weierbach catchment (0.45 km2, NW Luxembourg). Its runoff regime is characterised by seasonal variation and a delayed shallow groundwater component originating from a saprolite zone. The catchment was instrumented with piezometers, suction cups, an automatic streamwater sampler, a sequential rainfall sampler, and soil moisture and temperature sensors. Samples collected bi-weekly and during storm runoff events allowed the characterisation of the different end-members. Chemical and isotopic hydrograph separations of stream discharge were used to determine not only the geographic sources of water, but also the fractions of old and new water contributing to streamflow. Diatoms intra-storm variability was also analysed and samples of diatoms from various terrestrial and subaerial substrates (bryophytes, litter and leaves), as well as from aquatic habitats (epilithon, epipelon and drift samples) were regularly collected. Diatoms were then used to constrain assumptions and to confirm or reject the hypothesis of existing surface runoff during rainfall-runoff events and to document the intermittent character of hydrological connectivity between upland, riparian and aquatic zones. As an advantage, diatoms do not seem to be subject to some inherent limitations of the classical tracer-based hydrograph separation techniques, such as unrealistic mixing assumptions, unstable end-member solutions and temporally varying input concentrations. Results suggested a substantial contribution of soil water during winter events in the Weierbach catchment, whereas groundwater played a more significant role during summer events. Even though overland flow remained insignificant during most of the sampled events, terrestrial diatom abundance increased with precipitation in all sampled events suggesting a rapid connectivity between soil surface and stream water. We hypothesise the mobilization and flushing away of terrestrial diatoms through a subsurface network of macropores in the shallow soils.

Ground-water levels and quality data for Georgia

USGS Publications Warehouse

,

1979-01-01

This report begins a publication format that will present annually both water-level and water-quality data in Georgia. In this format the information is presented in two-page units: the left page includes text which summarizes the information for an area or subject and the right page consists of one or more illustrations. Daily mean water-level fluctuations and trends are shown in hydrographs for the previous year and fluctuations for the monthly mean water level the previous 10 years for selected observation wells. The well data best illustrate the effects of changes in recharge and discharge in the various ground-water reservoirs in the State. A short narrative explains fluctuations and trends in each hydrograph. (Woodard-USGS)

Water resources management: Hydrologic characterization through hydrograph simulation may bias streamflow statistics

NASA Astrophysics Data System (ADS)

Farmer, W. H.; Kiang, J. E.

2017-12-01

The development, deployment and maintenance of water resources management infrastructure and practices rely on hydrologic characterization, which requires an understanding of local hydrology. With regards to streamflow, this understanding is typically quantified with statistics derived from long-term streamgage records. However, a fundamental problem is how to characterize local hydrology without the luxury of streamgage records, a problem that complicates water resources management at ungaged locations and for long-term future projections. This problem has typically been addressed through the development of point estimators, such as regression equations, to estimate particular statistics. Physically-based precipitation-runoff models, which are capable of producing simulated hydrographs, offer an alternative to point estimators. The advantage of simulated hydrographs is that they can be used to compute any number of streamflow statistics from a single source (the simulated hydrograph) rather than relying on a diverse set of point estimators. However, the use of simulated hydrographs introduces a degree of model uncertainty that is propagated through to estimated streamflow statistics and may have drastic effects on management decisions. We compare the accuracy and precision of streamflow statistics (e.g. the mean annual streamflow, the annual maximum streamflow exceeded in 10% of years, and the minimum seven-day average streamflow exceeded in 90% of years, among others) derived from point estimators (e.g. regressions, kriging, machine learning) to that of statistics derived from simulated hydrographs across the continental United States. Initial results suggest that the error introduced through hydrograph simulation may substantially bias the resulting hydrologic characterization.

Springtime phytoplankton dynamics in the Arctic Krossfjorden and Kongsfjorden (Spitsbergen) as a function of glacier proximity

NASA Astrophysics Data System (ADS)

Piquet, A. M.-T.; van de Poll, W. H.; Visser, R. J. W.; Wiencke, C.; Bolhuis, H.; Buma, A. G. J.

2013-10-01

The hydrographic properties of the Kongsfjorden - Krossfjorden system (79° N, Spitsbergen) are affected by Atlantic water incursions as well as glacier meltwater runoff. This results in strong physical gradients (temperature, salinity and irradiance) within the fjords. Here, we tested the hypothesis that glaciers affect phytoplankton dynamics as early as the productive spring bloom period. During two campaigns in 2007 (late spring) and 2008 (early spring) we studied hydrographic characteristics and phytoplankton variability along 2 transects in both fjords, using HPLC-CHEMTAX pigment fingerprinting, molecular fingerprinting (DGGE) and sequencing of 18S rRNA genes. The sheltered inner fjord locations remained colder during spring as opposed to the outer locations. Vertical light attenuation coefficients increased from early spring onwards, at all locations, but in particular at the inner locations. During the end of spring, meltwater input had stratified surface waters throughout the fjords. The inner fjord locations were characterized by overall lower phytoplankton biomass. Furthermore HPLC-CHEMTAX data revealed that diatoms and Phaeocystis sp. were replaced by small nano- and picophytoplankton during late spring, coinciding with low nutrient availability. The innermost stations showed higher relative abundances of nano- and picophytoplankton throughout, notably of cyanophytes and cryptophytes. Molecular fingerprinting revealed a high similarity between inner fjord samples from early spring and late spring samples from all locations, while outer samples from early spring clustered separately. We conclude that glacier influence, mediated by early meltwater input, modifies phytoplankton biomass and composition already during the spring bloom period, in favor of low biomass and small cell size communities. This may affect higher trophic levels especially when regional warming further increases the period and volume of meltwater.

Hydrograph monitoring and analysis for sustainable karst water management in Nyadeng Spring, East Borneo

NASA Astrophysics Data System (ADS)

Widyastuti, M.; Fatchurohman, H.; Fathoni, W. A.; Hakim, A. A.; Haryono, E.

2018-04-01

Karst aquifer stores abundant water resources within its matrix, conduits, and intergranular pores. Karst aquifer plays an important role in providing water supply, especially in the areas nearby that commonly dry and lack of surface water resources. Karst spring hydrograph analysis is very fundamental step to–assess and determines the condition of the catchment area in karst terrain. Recession curve is believed to be the most stable part in single flood hydrograph that represents the aquifer characteristics. Nyadeng is one of the most significant karst springs that located in Merabu Karst Area, East Borneo. Villagers in Merabu highly depend on Nyadeng Spring for fulfilled their freshwater need. Hydrograph monitoring has been initiated for one year in Nyadeng Spring as a preliminary action for karst water management in Merabu. Water level data series obtained using automatic water level data logger and then correlated with manual discharge measurement to generate stage-discharge rating curve. The stage-discharge rating curve formula for Nyadeng Spring calculated as y = 0,0102e5,8547x with r2 value = 0.8759. From the combination of several single flood events, Master Recession Curve (MRC) was generated to determine flow regime as the main consideration for karstification degree calculation. From the MRC result, flow regimes formula determined as Qt = 3.2-0.001t + 1.2(1-0.012t)+1.6(1-0.035t) indicated that one sub-regime with laminar flow and two sub-regimes with turbulent flow existed. From the MRC formula, the degree of karstification in Nyadeng Spring classified at seventh scale (developed karstification of the aquifer) based on Malik’s karstification degree (2012). The degree of karstification in Nyadeng Spring indicates that the aquifer formed by large conduit channels, fissures, and macro fissures which are able to provide significant water sources that can be utilized for multi purposes. Therefore, it is concluded that spring hydrograph monitoring provide essential information in order to establish a careful water resources management actions.

40 CFR Appendix E to Part 63 - Monitoring Procedure for Nonthoroughly Mixed Open Biological Treatment Systems at Kraft Pulp...

Code of Federal Regulations, 2010 CFR

2010-07-01

... two separate components. The first data collection component demonstrates that the open biological... each zone of the open biological treatment unit. After the first two components of data collection are... determined using actual sampling data from the open biological treatment unit. This is done during the...

40 CFR Appendix E to Part 63 - Monitoring Procedure for Nonthoroughly Mixed Open Biological Treatment Systems at Kraft Pulp...

Code of Federal Regulations, 2011 CFR

2011-07-01

... two separate components. The first data collection component demonstrates that the open biological... each zone of the open biological treatment unit. After the first two components of data collection are... determined using actual sampling data from the open biological treatment unit. This is done during the...

A Representation of an Instantaneous Unit Hydrograph From Geomorphology

NASA Astrophysics Data System (ADS)

Gupta, Vijay K.; Waymire, Ed; Wang, C. T.

1980-10-01

The channel network and the overland flow regions in a river basin satisfy Horton's empirical geo-morphologic laws when ordered according to the Strahler ordering scheme. This setting is presently employed in a kinetic theoretic framework for obtaining an explicit mathematical representation for the instantaneous unit hydrograph (iuh) at the basin outlet. Two examples are developed which lead to explicit formulae for the iuh. These examples are formally analogous to the solutions that would result if a basin is represented in terms of linear reservoirs and channels, respectively, in series and in parallel. However, this analogy is only formal, and it does not carry through physically. All but one of the parameters appearing in the iuh formulae are obtained in terms of Horton's bifurcation ratio, stream length ratio, and stream area ratio. The one unknown parameter is obtained through specifying the basin mean lag time independently. Three basins from Illinois are selected to check the theoretical results with the observed direct surface runoff hydrographs. The theory provided excellent agreement for two basins with areas of the order of 1100 mi2 (1770 km2) but underestimates the peak flow for the smaller basin with 300-mi2 (483-km2) area. This relative lack of agreement for the smaller basin may be used to question the validity of the linearity assumption in the rainfall runoff transformation which is embedded in the above development.

Diversity and community structure of pelagic fishes to 5000 m depth in the Sargasso Sea

NASA Astrophysics Data System (ADS)

Sutton, Tracey T.; Wiebe, Peter H.; Madin, Laurence; Bucklin, Ann

2010-12-01

The diversity, abundance and distribution of pelagic fishes from 0-5000 m in the Sargasso Sea, northwestern Atlantic Ocean, were investigated, with primary focus on fishes between 1000-5000 m. A large-volume, fine-mesh (335-μm), discrete-depth sampling system was used to sample the latter strata in 1000-m intervals. Species composition and total biomass of fishes collected in these strata were compared with samples taken 0-1000 m using a smaller midwater trawl. Samples were collected in association with the Census of Marine Zooplankton at-sea DNA-sequencing effort, allowing the determination of genetic barcodes of taxa for which species descriptions do not currently exist (e.g., many male ceratioid anglerfishes). A total of 3965 fish specimens were collected, representing minimally 127 species (84 genera), from 42 families. The bristlemouth, Cyclothone braueri, dominated the catches both above (47%) and below (41%) 1000 m. The Myctophidae and Stomiidae were the most species-rich taxa, while the deep-sea anglerfish suborder Ceratioidei was the most diverse bathypelagic taxon. Thirty species of fish were sequenced and data submitted to GenBank. New Ocean Biogeographic Information System location records for the Saragasso Sea were logged for 84 fish species. Hydrographic data revealed separation of the region into three physical regimes within the top 1000 m (northern, transition, and southern), while the sub-1000 m stratum was fairly homogeneous. Though species richness, abundance, and diversity were highest in the southern Sargasso, diversity indices of whole water column (0-5000 m) samples were not significantly different between regions. Below 1000 m, the 1000-2000 m stratum held the most diverse assemblage across the entire transect, but high diversity was exhibited below 3000 m at two of four stations. Ordination discriminated 13 pelagic fish assemblages, with these related to depth far more than region. Geometric abundance class analysis revealed profound differences in relative species abundances between the meso- and bathypelagic zones with the former demonstrating a much higher percentage of common species. This finding tracks the hydrographic patterns observed: increased stability in the bathypelagic zone favors increased numbers of rare species relative to the mesopelagic zone, where hydrographic complexity favors higher numbers of common species.

The role of varying flow on channel morphology: a flume experiment

NASA Astrophysics Data System (ADS)

Hempel, L. A.; Grant, G.; Eaton, B. C.; Hassan, M. A.; Lewis, S.

2017-12-01

Numerous studies have explored how alluvial channels develop under different sediment and flow conditions, yet we still know very little about how channels adjust and respond to changing flow conditions. One reason for this oversight is the long-held idea that channels with complex flow regimes are adjusted to a single, channel-forming discharge. But growing evidence shows that channel form reflects time-dependent processes occuring over multiple flows. To better understand how stream channels adjust to a range of flows, and identify the timescales associated with those adjustments, we conducted a series of hydrograph experiments in a freely-adjustable flume that developed a self-formed, meander pattern with pool-riffle morphology. Hydrographs had different shapes, magnitudes, and durations, but the total sediment volume fed under equilibrium conditions was kept constant among experiments. We found that hydrograph shape controlled channel morphology, the rate of channel development, and degree of regularity in the pool-riffle pattern. Hydrographs with slowly rising rates of rise and fall produced channels that were equivalent in size to channels generated from constant flow experiments, and had regularly spaced pool-riffle and meander patterns, while hydrographs with fast rates of rise and fall produced undersized channels with a chaotic bed structure and pool-riffle pattern. The latter suggests that during quickly rising hydrographs, the flow rate increases faster than the channel capacity and planform pattern adjusts. We confirmed these observations by comparing the timescales associated with pool-riffle and planform curvature development, which were identified under simple, constant flow conditions, to the total duration of the hydrograph. Hydrographs with step durations equal to or longer than the channel adjustment time produced channels with a more regular pool-riffle patterns compared to channels with step durations shorter than the adjustment time. This work points to the importance of the hydrograph as a fundamental control on channel adjustment and offers the prospect of better understanding of how changes in the flow regime, either through climate, land use, or dams, translate into morphodynamic changes.

Comparison of methods for estimating ground-water recharge and base flow at a small watershed underlain by fractured bedrock in the Eastern United States

USGS Publications Warehouse

Risser, Dennis W.; Gburek, William J.; Folmar, Gordon J.

2005-01-01

This study by the U.S. Geological Survey (USGS), in cooperation with the Agricultural Research Service (ARS), U.S. Department of Agriculture, compared multiple methods for estimating ground-water recharge and base flow (as a proxy for recharge) at sites in east-central Pennsylvania underlain by fractured bedrock and representative of a humid-continental climate. This study was one of several within the USGS Ground-Water Resources Program designed to provide an improved understanding of methods for estimating recharge in the eastern United States. Recharge was estimated on a monthly and annual basis using four methods?(1) unsaturated-zone drainage collected in gravity lysimeters, (2) daily water balance, (3) water-table fluctuations in wells, and (4) equations of Rorabaugh. Base flow was estimated by streamflow-hydrograph separation using the computer programs PART and HYSEP. Estimates of recharge and base flow were compared for an 8-year period (1994-2001) coinciding with operation of the gravity lysimeters at an experimental recharge site (Masser Recharge Site) and a longer 34-year period (1968-2001), for which climate and streamflow data were available on a 2.8-square-mile watershed (WE-38 watershed). Estimates of mean-annual recharge at the Masser Recharge Site and WE-38 watershed for 1994-2001 ranged from 9.9 to 14.0 inches (24 to 33 percent of precipitation). Recharge, in inches, from the various methods was: unsaturated-zone drainage, 12.2; daily water balance, 12.3; Rorabaugh equations with PULSE, 10.2, or RORA, 14.0; and water-table fluctuations, 9.9. Mean-annual base flow from streamflow-hydrograph separation ranged from 9.0 to 11.6 inches (21-28 percent of precipitation). Base flow, in inches, from the various methods was: PART, 10.7; HYSEP Local Minimum, 9.0; HYSEP Sliding Interval, 11.5; and HYSEP Fixed Interval, 11.6. Estimating recharge from multiple methods is useful, but the inherent differences of the methods must be considered when comparing results. For example, although unsaturated-zone drainage from the gravity lysimeters provided the most direct measure of potential recharge, it does not incorporate spatial variability that is contained in watershed-wide estimates of net recharge from the Rorabaugh equations or base flow from streamflow-hydrograph separation. This study showed that water-level fluctuations, in particular, should be used with caution to estimate recharge in low-storage fractured-rock aquifers because of the variability of water-level response among wells and sensitivity of recharge to small errors in estimating specific yield. To bracket the largest range of plausible recharge, results from this study indicate that recharge derived from RORA should be compared with base flow from the Local-Minimum version of HYSEP.

Mass-induced sea level variations in the Red Sea from steric-corrected altimetry, GRACE, in-situ bottom pressure records, and hydrographic observations

NASA Astrophysics Data System (ADS)

Feng, Wei; Lemoine, Jean-Michel; Zhong, Min; Xu, Houze

2014-05-01

An annual amplitude of ~18 cm mass-induced sea level variations (SLV) in the Red Sea is detected from steric-corrected altimetry and the Gravity Recovery and Climate Experiment (GRACE) satellites from 2003 to 2011, which dominates the mean sea level in the region. Seawater mass variations here generally reach maximum in late January/early February. The steric component of SLV calculated from oceanographic temperature and salinity data is relatively small and peaks about seven months later than mass variations. The phase difference between the steric SLV and the mass-induced SLV indicates that when the Red Sea gains the mass from inflow water in winter, the steric SLV fall, and vice versa in summer. In-situ bottom pressure records in the eastern coast of the Red Sea validate the high mass variability observed by steric-corrected altimetry and GRACE. Furthermore, we compare the horizontal water mass flux in the Red Sea from steric-corrected altimetry and GRACE with that estimated from hydrographic observations.

Multiple fuel supply system for an internal combustion engine

DOEpatents

Crothers, William T.

1977-01-01

A multiple fuel supply or an internal combustion engine wherein phase separation of components is deliberately induced. The resulting separation permits the use of a single fuel tank to supply components of either or both phases to the engine. Specifically, phase separation of a gasoline/methanol blend is induced by the addition of a minor amount of water sufficient to guarantee separation into an upper gasoline phase and a lower methanol/water phase. A single fuel tank holds the two-phase liquid with separate fuel pickups and separate level indicators for each phase. Either gasoline or methanol, or both, can be supplied to the engine as required by predetermined parameters. A fuel supply system for a phase-separated multiple fuel supply contained in a single fuel tank is described.

Techniques for estimating flood hydrographs for ungaged urban watersheds

USGS Publications Warehouse

Stricker, V.A.; Sauer, V.B.

1984-01-01

The Clark Method, modified slightly was used to develop a synthetic, dimensionless hydrograph which can be used to estimate flood hydrographs for ungaged urban watersheds. Application of the technique results in a typical (average) flood hydrograph for a given peak discharge. Input necessary to apply the technique is an estimate of basin lagtime and the recurrence interval peak discharge. Equations for this purpose were obtained from a recent nationwide study on flood frequency in urban watersheds. A regression equation was developed which relates flood volumes to drainage area size, basin lagtime, and peak discharge. This equation is useful where storage of floodwater may be a part of design of flood prevention. (USGS)

Effects of urban development on stormwater runoff characteristics for the Houston, Texas, metropolitan area

USGS Publications Warehouse

Liscum, Fred

2001-01-01

A study was done to estimate the effects of urban development in the Houston, Texas, metropolitan area on nine stormwater runoff characteristics. Three of the nine characteristics define the magnitude of stormwater runoff, and the remaining six characteristics describe the shape and duration of a storm hydrograph. Multiple linear regression was used to develop equations to estimate the nine stormwater runoff characteristics from basin and rainfall characteristics. Five basin characteristics and five rainfall characteristics were tested in the regressions to determine which basin and rainfall characteristics significantly affect stormwater runoff characteristics. Basin development factor was found to be significant in equations for eight of the nine stormwater runoff characteristics. Two sets of equations were developed, one for each of two regions based on soil type, from a database containing 1,089 storm discharge hydrographs for 42 sites compiled during 1964–89.The effects of urban development on the eight stormwater runoff characteristics were quantified by varying basin development factor in the equations and recomputing the stormwater runoff characteristics. The largest observed increase in basin development factor for region 1 (north of Buffalo Bayou) during the study resulted in corresponding increases in the characteristics that define magnitude of stormwater runoff ranging from about 40 percent (for direct runoff) to 235 percent (for peak yield); and corresponding decreases in the characteristics that describe hydrograph shape and duration ranging from about 22 percent (for direct runoff duration) to about 58 percent (for basin lag). The largest observed increase in basin development factor for region 2 (south of Buffalo Bayou) during the study resulted in corresponding increases in the characteristics that define magnitude of stormwater runoff ranging from about 33 percent (for direct runoff) to about 210 percent (for both peak flow and peak yield); and corresponding decreases in the characteristics that describe hydrograph shape and duration ranging from about 38 percent (for direct runoff duration) to about 64 percent (for basin lag). 

The design and implementation of hydrographical information management system (HIMS)

NASA Astrophysics Data System (ADS)

Sui, Haigang; Hua, Li; Wang, Qi; Zhang, Anming

2005-10-01

With the development of hydrographical work and information techniques, the large variety of hydrographical information including electronic charts, documents and other materials are widely used, and the traditional management mode and techniques are unsuitable for the development of the Chinese Marine Safety Administration Bureau (CMSAB). How to manage all kinds of hydrographical information has become an important and urgent problem. A lot of advanced techniques including GIS, RS, spatial database management and VR techniques are introduced for solving these problems. Some design principles and key techniques of the HIMS including the mixed mode base on B/S, C/S and stand-alone computer mode, multi-source & multi-scale data organization and management, multi-source data integration and diverse visualization of digital chart, efficient security control strategies are illustrated in detail. Based on the above ideas and strategies, an integrated system named Hydrographical Information Management System (HIMS) was developed. And the HIMS has been applied in the Shanghai Marine Safety Administration Bureau and obtained good evaluation.

Inter-Annual and Shorter-Term Variability in Physical and Biological Characteristics Across Barrow Canyon in August - September 2005-2014

NASA Astrophysics Data System (ADS)

Ashjian, C. J.; Okkonen, S. R.; Campbell, R. G.; Alatalo, P.

2014-12-01

Late summer physical and biological conditions along a 37-km transect crossing Barrow Canyon have been described for the past ten years as part of an ongoing program, supported by multiple funding sources including the NSF AON, focusing on inter-annual variability and the formation of a bowhead whale feeding hotspot near Barrow. These repeated transects (at least two per year, separated in time by days-weeks) provide an opportunity to assess the inter-annual and shorter term (days-weeks) changes in hydrographic structure, ocean temperature, current velocity and transport, chlorophyll fluorescence, nutrients, and micro- and mesozooplankton community composition and abundance. Inter-annual variability in all properties was high and was associated with larger scale, meteorological forcing. Shorter-term variability could also be high but was strongly influenced by changes in local wind forcing. The sustained sampling at this location provided critical measures of inter-annual variability that should permit detection of longer-term trends that are associated with ongoing climate change.

A bill to amend the Hydrographic Services Improvement Act of 1998 to authorize funds to acquire hydrographic data and provide hydrographic services specific to the Arctic for safe navigation, delineating the United States extended continental shelf, and the monitoring and description of coastal changes.

THOMAS, 111th Congress

Sen. Murkowski, Lisa [R-AK

2009-07-24

Senate - 07/24/2009 Read twice and referred to the Committee on Commerce, Science, and Transportation. (All Actions) Tracker: This bill has the status IntroducedHere are the steps for Status of Legislation:

Comprehensive two-dimensional HPLC to study the interaction of multiple components in Rheum palmatum L. with HSA by coupling a silica-bonded HSA column to a silica monolithic ODS column.

PubMed

Hu, Lianghai; Li, Xin; Feng, Shun; Kong, Liang; Su, Xingye; Chen, Xueguo; Qin, Feng; Ye, Mingliang; Zou, Hanfa

2006-04-01

A mode of comprehensive 2-D LC was developed by coupling a silica-bonded HSA column to a silica monolithic ODS column. This system combined the affinity property of the HSA column and the high-speed separation ability of the monolithic ODS column. The affinity chromatography with HSA-immobilized stationary phase was applied to study the interaction of multiple components in traditional Chinese medicines (TCMs) with HSA according to their affinity to protein in the first dimension. Then the unresolved components retained on the HSA column were further separated on the silica monolithic ODS column in the second dimension. By hyphenating the 2-D separation system to diode array detector and MS detectors, the UV and molecular weight information of the separated compounds can also be obtained. The developed separation system was applied to analysis of the extract of Rheum palmatum L., a number of low-abundant components can be separated on a single peak from the HSA column after normalization of peak heights. Six compounds were preliminarily identified according to their UV and MS spectra. It showed that this system was very useful for biological fingerprinting analysis of the components in TCMs and natural products.

A framework for quantification of groundwater dynamics - redundancy and transferability of hydro(geo-)logical metrics

NASA Astrophysics Data System (ADS)

Heudorfer, Benedikt; Haaf, Ezra; Barthel, Roland; Stahl, Kerstin

2017-04-01

A new framework for quantification of groundwater dynamics has been proposed in a companion study (Haaf et al., 2017). In this framework, a number of conceptual aspects of dynamics, such as seasonality, regularity, flashiness or inter-annual forcing, are described, which are then linked to quantitative metrics. Hereby, a large number of possible metrics are readily available from literature, such as Pardé Coefficients, Colwell's Predictability Indices or Base Flow Index. In the present work, we focus on finding multicollinearity and in consequence redundancy among the metrics representing different patterns of dynamics found in groundwater hydrographs. This is done also to verify the categories of dynamics aspects suggested by Haaf et al., 2017. To determine the optimal set of metrics we need to balance the desired minimum number of metrics and the desired maximum descriptive property of the metrics. To do this, a substantial number of candidate metrics are applied to a diverse set of groundwater hydrographs from France, Germany and Austria within the northern alpine and peri-alpine region. By applying Principle Component Analysis (PCA) to the correlation matrix of the metrics, we determine a limited number of relevant metrics that describe the majority of variation in the dataset. The resulting reduced set of metrics comprise an optimized set that can be used to describe the aspects of dynamics that were identified within the groundwater dynamics framework. For some aspects of dynamics a single significant metric could be attributed. Other aspects have a more fuzzy quality that can only be described by an ensemble of metrics and are re-evaluated. The PCA is furthermore applied to groups of groundwater hydrographs containing regimes of similar behaviour in order to explore transferability when applying the metric-based characterization framework to groups of hydrographs from diverse groundwater systems. In conclusion, we identify an optimal number of metrics, which are readily available for usage in studies on groundwater dynamics, intended to help overcome analytical limitations that exist due to the complexity of groundwater dynamics. Haaf, E., Heudorfer, B., Stahl, K., Barthel, R., 2017. A framework for quantification of groundwater dynamics - concepts and hydro(geo-)logical metrics. EGU General Assembly 2017, Vienna, Austria.

Alternative polymer separation technology by centrifugal force in a melted state

DOE Office of Scientific and Technical Information (OSTI.GOV)

Dobrovszky, Károly; Ronkay, Ferenc, E-mail: ronkay@pt.bme.hu

2014-11-15

Highlights: • Waste separation should take place at high purity. • Developed a novel, alternative separation method, where the separation occurred in a melted state by centrifugal forces. • Possibility of separation two different plastics into neat fractions. • High purity fractions were established at granulates and also at prefabricated blend. • Results were verified by DSC, optical microscopy and Raman spectroscopy. - Abstract: In order to upgrade polymer waste during recycling, separation should take place at high purity. The present research was aimed to develop a novel, alternative separation opportunity, where the polymer fractions were separated by centrifugal forcemore » in melted state. The efficiency of the constructed separation equipment was verified by two immiscible plastics (polyethylene terephthalate, PET; low density polyethylene, LDPE), which have a high difference of density, and of which large quantities can also be found in the municipal solid waste. The results show that the developed equipment is suitable not only for separating dry blended mixtures of PET/LDPE into pure components again, but also for separating prefabricated polymer blends. By this process it becomes possible to recover pure polymer substances from multi-component products during the recycling process. The adequacy of results was verified by differential scanning calorimetry (DSC) measurement as well as optical microscopy and Raman spectroscopy.« less

A dimensionless approach for the runoff peak assessment: effects of the rainfall event structure

NASA Astrophysics Data System (ADS)

Gnecco, Ilaria; Palla, Anna; La Barbera, Paolo

2018-02-01

The present paper proposes a dimensionless analytical framework to investigate the impact of the rainfall event structure on the hydrograph peak. To this end a methodology to describe the rainfall event structure is proposed based on the similarity with the depth-duration-frequency (DDF) curves. The rainfall input consists of a constant hyetograph where all the possible outcomes in the sample space of the rainfall structures can be condensed. Soil abstractions are modelled using the Soil Conservation Service method and the instantaneous unit hydrograph theory is undertaken to determine the dimensionless form of the hydrograph; the two-parameter gamma distribution is selected to test the proposed methodology. The dimensionless approach is introduced in order to implement the analytical framework to any study case (i.e. natural catchment) for which the model assumptions are valid (i.e. linear causative and time-invariant system). A set of analytical expressions are derived in the case of a constant-intensity hyetograph to assess the maximum runoff peak with respect to a given rainfall event structure irrespective of the specific catchment (such as the return period associated with the reference rainfall event). Looking at the results, the curve of the maximum values of the runoff peak reveals a local minimum point corresponding to the design hyetograph derived according to the statistical DDF curve. A specific catchment application is discussed in order to point out the dimensionless procedure implications and to provide some numerical examples of the rainfall structures with respect to observed rainfall events; finally their effects on the hydrograph peak are examined.

Buffalo Metropolitan Area, New York Water Resources Management. Interim Report on Feasibility of Flood Management. Appendices.

DTIC Science & Technology

1983-07-01

storage areas were taken into account during the flood routings. AI.36 The computer program REVPULS, developed for this report, reverse Modified Puls...routed the hydrograph at Batavia through the storage upstream of the LVRR embankment. Subtracting this reverse -routed hydrograph from the combined...segments to form a more accurate reconstitution. The hydrographs upstream of Batavia were derived by reverse -routing and prorating by drainage area. Table

To amend the Hydrographic Services Improvement Act of 1998 to authorize funds to acquire hydrographic data and provide hydrographic services specific to the Arctic for safe navigation, delineating the United States extended continental shelf, and the monitoring and description of coastal changes.

THOMAS, 111th Congress

Rep. Young, Don [R-AK-At Large

2009-06-12

Senate - 07/15/2010 Received in the Senate and Read twice and referred to the Committee on Commerce, Science, and Transportation. (All Actions) Tracker: This bill has the status Passed HouseHere are the steps for Status of Legislation:

To amend the Hydrographic Services Improvement Act of 1998 to authorize funds to acquire hydrographic data and provide hydrographic services specific to the Arctic for safe navigation, delineating the United States extended continental shelf, and the monitoring and description of coastal changes.

THOMAS, 112th Congress

Rep. Young, Don [R-AK-At Large

2011-01-12

Senate - 10/31/2011 Received in the Senate and Read twice and referred to the Committee on Commerce, Science, and Transportation. (All Actions) Tracker: This bill has the status Passed HouseHere are the steps for Status of Legislation:

Temperature-Induced Phase Separation in Molecular Assembly of Nanotubes Comprising Amphiphilic Polypeptide with Poly( N-Ethyl Glycine) in Water by a Hydrophilic-Region Driven Type Mechanism.

PubMed

Hattori, Tetsuya; Itagaki, Toru; Uji, Hirotaka; Kimura, Shunsaku

2018-06-20

Two kinds of amphiphilic polypeptides having different types of hydrophilic polypeptoids, poly(sarcosine)-b-(L-Leu-Aib)6 (ML12) and poly(N-ethyl glycine)-b-(L-Leu-Aib)6 (EL12), were self-assembled via two paths to phase-separated nanotubes. One path was via sticking ML12 nanotubes with EL12 nanotubes, and the other was a preparation from a mixture of ML12 and EL12 in solution. In either case, nanotubes showed temperature-induced phase separation along the long axis, which was observed by two methods of labeling one phase with gold nanoparticles and fluorescence resonance energy transfer between the components. The phase-separation was ascribed to aggregation of poly(N-ethyl glycine) blocks over the cloud point temperature. The addition of 5% trifluoroethanol was needed for the phase separation, because the tight association of the helices in the hydrophobic region should be loosened to allow lateral diffusion of the components to be separated. The phase-separation in molecular assemblies in water based on the hydrophilic-region driven type mechanism therefore requires sophisticated balances of association forces exerting among the hydrophilic and hydrophobic regions of the amphiphilic polypeptoids.

Regional-scale, fully coupled modelling of stream aquifer interaction in a tropical catchment

NASA Astrophysics Data System (ADS)

Werner, Adrian D.; Gallagher, Mark R.; Weeks, Scott W.

2006-09-01

SummaryThe planning and management of water resources in the Pioneer Valley, north-eastern Australia requires a tool for assessing the impact of groundwater and stream abstractions on water supply reliabilities and environmental flows in Sandy Creek (the main surface water system studied). Consequently, a fully coupled stream-aquifer model has been constructed using the code MODHMS, calibrated to near-stream observations of watertable behaviour and multiple components of gauged stream flow. This model has been tested using other methods of estimation, including stream depletion analysis and radon isotope tracer sampling. The coarseness of spatial discretisation, which is required for practical reasons of computational efficiency, limits the model's capacity to simulate small-scale processes (e.g., near-stream groundwater pumping, bank storage effects), and alternative approaches are required to complement the model's range of applicability. Model predictions of groundwater influx to Sandy Creek are compared with baseflow estimates from three different hydrograph separation techniques, which were found to be unable to reflect the dynamics of Sandy Creek stream-aquifer interactions. The model was also used to infer changes in the water balance of the system caused by historical land use change. This led to constraints on the recharge distribution which can be implemented to improve model calibration performance.

Pesticide leaching by agricultural drainage in sloping, mid-textured soil conditions - the role of runoff components.

PubMed

Zajíček, Antonín; Fučík, Petr; Kaplická, Markéta; Liška, Marek; Maxová, Jana; Dobiáš, Jakub

2018-04-01

Dynamics of pesticides and their metabolites in drainage waters during baseflow periods and rainfall-runoff events (RREs) were studied from 2014 to 2016 at three small, tile-drained agricultural catchments in Bohemian-Moravian Highlands, Czech Republic. Drainage systems in this region are typically built in slopes with considerable proportion of drainage runoff originating outside the drained area itself. Continuous monitoring was performed by automated samplers, and the event hydrograph was separated using 18 O and 2 H isotopes and drainage water temperature. Results showed that drainage systems represent a significant source for pesticides leaching from agricultural land. Leaching of pesticide metabolites was mainly associated with baseflow and shallow interflow. Water from causal precipitation diluted their concentrations. The prerequisites for the leaching of parental compounds were a rainfall-runoff event occurring shortly after spraying, and the presence of event water in the runoff. When such situations happened consequently, pesticides concentrations in drainage water were high and the pesticide load reached several grams in a few hours. Presented results introduce new insights into the processes of pesticides movement in small, tile-drained catchments and emphasizes the need to incorporate drainage hydrology and flow-triggered sampling into monitoring programmes in larger catchments as well as in environment-conservation policy.

Usage of machine learning for the separation of electroweak and strong Zγ production at the LHC experiments

NASA Astrophysics Data System (ADS)

Petukhov, A. M.; Soldatov, E. Yu

2017-12-01

Separation of electroweak component from strong component of associated Zγ production on hadron colliders is a very challenging task due to identical final states of such processes. The only difference is the origin of two leading jets in these two processes. Rectangular cuts on jet kinematic variables from ATLAS/CMS 8 TeV Zγ experimental analyses were improved using machine learning techniques. New selection variables were also tested. The expected significance of separation for LHC experiments conditions at the second datataking period (Run2) and 120 fb-1 amount of data reaches more than 5σ. Future experimental observation of electroweak Zγ production can also lead to the observation physics beyond Standard Model.

Classifying hydrological events to quantify their impact on nitrate leaching across three spatial scales

NASA Astrophysics Data System (ADS)

Bauwe, Andreas; Tiemeyer, Bärbel; Kahle, Petra; Lennartz, Bernd

2015-04-01

Nitrate is one of the most important sources of pollution for surface waters in tile-drained agricultural areas. In order to develop appropriate management strategies to reduce nitrate losses, it is crucial to first understand the underlying hydrological processes. In this study, we used Principle Component Analysis (PCA) and Linear Discriminant Analysis (LDA) to analyze 212 storm events between 2004 and 2011 across three spatial scales (collector drain, ditch, and brook) to identify the controlling factors for hydrograph response characteristics and their influence on nitrate concentration patterns. Our results showed that the 212 hydrological events can be classified into six different types: summer events (28%), snow-dominated events (10%), events controlled by rainfall duration (16%), rainfall totals (8%), dry antecedent conditions (10%), and events controlled by wet antecedent conditions (14%). The relatively large number of unclassified events (15%) demonstrated the difficulty in separating event types due to mutually influencing variables. NO3-N concentrations showed a remarkably consistent pattern during the discharge events regardless of event type, with minima at the beginning, increasing concentrations at the rising limb, and maxima around peak discharge. However, the level of NO3-N concentrations varied notably among the event types. The highest average NO3-N concentrations were found for events controlled by rainfall totals (NO3-N=17.1 mg/l), events controlled by wet antecedent conditions (NO3-N=17.1 mg/l), and snowmelt (NO3-N=15.2 mg/l). Average maximum NO3-N concentrations were significantly lower during summer events (NO3-N=10.2 mg/l) and events controlled by dry antecedent conditions (NO3-N=11.7 mg/l). The results have furthermore shown that similar hydrological and biogeochemical processes determine the hydrograph and NO3-N response on storm events at various spatial scales. The management of tile-drained agricultural land to reduce NO3-N losses should focus explicitly on flow events and, more specifically, active management should preferably be conducted in the winter season for discharge events after snowmelt, after heavy rain storms and when the soil moisture conditions are wet.

Classifying hydrological events to quantify their impact on nitrate leaching across three spatial scales

NASA Astrophysics Data System (ADS)

Bauwe, Andreas; Tiemeyer, Bärbel; Kahle, Petra; Lennartz, Bernd

2015-12-01

Nitrate is one of the most important sources of pollution for surface waters in tile-drained agricultural areas. In order to develop appropriate management strategies to reduce nitrate losses, it is crucial to first understand the underlying hydrological processes. In this study, we used Principle Component Analysis (PCA) and Linear Discriminant Analysis (LDA) to analyze 212 discharge events between 2004 and 2011 across three spatial scales (68 events at the collector drain, 72 at the ditch, and 72 at the brook) to identify the controlling factors for hydrograph response characteristics and their influence on nitrate concentration patterns. Our results showed that the 212 hydrological events can be classified into six different types: summer events (28%), snow-dominated events (10%), events controlled by rainfall duration (16%), rainfall totals (8%), dry antecedent conditions (10%), and events controlled by wet antecedent conditions (14%). The relatively large number of unclassified events (15%) demonstrated the difficulty in separating event types due to mutually influencing variables. NO3-N concentrations showed a remarkably consistent pattern during the discharge events regardless of event type, with minima at the beginning, increasing concentrations at the rising limb, and maxima around peak discharge. However, the level of NO3-N concentrations varied notably among the event types. The highest average NO3-N concentrations were found for events controlled by rainfall totals (NO3-N = 17.1 mg/l), events controlled by wet antecedent conditions (NO3-N = 17.1 mg/l), and snowmelt (NO3-N = 15.2 mg/l). Average maximum NO3-N concentrations were significantly lower during summer events (NO3-N = 10.2 mg/l) and events controlled by dry antecedent conditions (NO3-N = 11.7 mg/l). The results have furthermore shown that similar hydrological and biogeochemical processes determine the hydrograph and NO3-N response on storm events at various spatial scales. The management of tile-drained agricultural land to reduce NO3-N losses should focus explicitly on flow events and, more specifically, active management should preferably be conducted in the winter season for discharge events after snowmelt, after heavy rain storms and when the soil moisture conditions are wet.

Quantifying new water fractions and water age distributions using ensemble hydrograph separation

NASA Astrophysics Data System (ADS)

Kirchner, James

2017-04-01

Catchment transit times are important controls on contaminant transport, weathering rates, and runoff chemistry. Recent theoretical studies have shown that catchment transit time distributions are nonstationary, reflecting the temporal variability in precipitation forcing, the structural heterogeneity of catchments themselves, and the nonlinearity of the mechanisms controlling storage and transport in the subsurface. The challenge of empirically estimating these nonstationary transit time distributions in real-world catchments, however, has only begun to be explored. Long, high-frequency tracer time series are now becoming available, creating new opportunities to study how rainfall becomes streamflow on timescales of minutes to days following the onset of precipitation. Here I show that the conventional formula used for hydrograph separation can be converted into an equivalent linear regression equation that quantifies the fraction of current rainfall in streamflow across ensembles of precipitation events. These ensembles can be selected to represent different discharge ranges, different precipitation intensities, or different levels of antecedent moisture, thus quantifying how the fraction of "new water" in streamflow varies with forcings such as these. I further show how this approach can be generalized to empirically determine the contributions of precipitation inputs to streamflow across a range of time lags. In this way the short-term tail of the transit time distribution can be directly quantified for an ensemble of precipitation events. Benchmark testing with a simple, nonlinear, nonstationary catchment model demonstrates that this approach quantitatively measures the short tail of the transit time distribution for a wide range of catchment response characteristics. In combination with reactive tracer time series, this approach can potentially be extended to measure short-term chemical reaction rates at the catchment scale. High-frequency tracer time series from several experimental catchments will be used to demonstrate the utility of the new approach outlined here.

Rainwater propagation through snowpack during rain-on-snow sprinkling experiments under different snow conditions

NASA Astrophysics Data System (ADS)

Juras, Roman; Würzer, Sebastian; Pavlásek, Jirka; Vitvar, Tomáš; Jonas, Tobias

2017-09-01

The mechanisms of rainwater propagation and runoff generation during rain-on-snow (ROS) events are still insufficiently known. Understanding storage and transport of liquid water in natural snowpacks is crucial, especially for forecasting of natural hazards such as floods and wet snow avalanches. In this study, propagation of rainwater through snow was investigated by sprinkling experiments with deuterium-enriched water and applying an alternative hydrograph separation technique on samples collected from the snowpack runoff. This allowed us to quantify the contribution of rainwater, snowmelt and initial liquid water released from the snowpack. Four field experiments were carried out during winter 2015 in the vicinity of Davos, Switzerland. Blocks of natural snow were isolated from the surrounding snowpack to inhibit lateral exchange of water and were exposed to artificial rainfall using deuterium-enriched water. The experiments were composed of four 30 min periods of sprinkling, separated by three 30 min breaks. The snowpack runoff was continuously gauged and sampled periodically for the deuterium signature. At the onset of each experiment antecedent liquid water was first pushed out by the sprinkling water. Hydrographs showed four pronounced peaks corresponding to the four sprinkling bursts. The contribution of rainwater to snowpack runoff consistently increased over the course of the experiment but never exceeded 86 %. An experiment conducted on a non-ripe snowpack suggested the development of preferential flow paths that allowed rainwater to efficiently propagate through the snowpack limiting the time for mass exchange processes to take effect. In contrast, experiments conducted on ripe isothermal snowpack showed a slower response behaviour and resulted in a total runoff volume which consisted of less than 50 % of the rain input.

Particle Image Velocimetry Measurements of a Two/Three-dimensional Separating/Reattaching Boundary Layer Downstream of an Axisymmetric Backward-facing Step

NASA Technical Reports Server (NTRS)

Hudy, Laura M.; Naguib, Ahmed M.; Humphreys, William M.; Bartram, Scott M.

2005-01-01

Planar Particle Image Velocimetry measurements were obtained in the separating/reattaching flow region downstream of an axisymmetric backward-facing step. Data were acquired for a two-dimensional (2D) separating boundary layer at five different Reynolds numbers based on step height (Re(sub h)), spanning 5900-33000, and for a three-dimensional (3D) separating boundary layer at Re(sub h) = 5980 and 8081. Reynolds number effects were investigated in the 2D cases using mean-velocity field, streamwise and wall-normal turbulent velocity, and Reynolds stress statistics. Results show that both the reattachment length (x(sub r)) and the secondary separation point are Reynolds number dependent. The reattachment length increased with rising Re(sub h) while the secondary recirculation region decreased in size. These and other Re(sub h) effects were interpreted in terms of changes in the separating boundary layer thickness and wall-shear stress. On the other hand, in the 3D case, it was found that the imposed cross-flow component was relatively weak in comparison to the streamwise component. As a result, the primary influences of three dimensionality only affected the near-separation region rather than the entire separation bubble.

[Separation and purification of the components in Trachelospermum jasminoides by two dimensional hydrophilic interaction liquid chromatography- reversed-phase liquid chromatography].

PubMed

Jia, Youmei; Cai, Jianfeng; Xin, Huaxia; Feng, Jiatao; Fu, Yanhui; Fu, Qing; Jin, Yu

2017-06-08

A preparative two dimensional hydrophilic interaction liquid chromatography/reversed-phase liquid chromatography (Pre-2D-HILIC/RPLC) method was established to separate and purify the components in Trachelospermum jasminoides . The pigments and strongly polar components were removed from the crude extract after the active carbon decolorization and solid phase extraction processes. A Click XIon column (250 mm×20 mm, 10 μm) was selected as stationary phase and water-acetonitrile as mobile phases in the first dimensional HILIC. Finally, 15 fractions were collected under UV-triggered mode. In the second dimensional RPLC, a C18 column (250 mm×20 mm, 5 μm) was selected and water-acetonitrile was used as mobile phases. As a result, 14 compounds with high purity were obtained, which were further identified by mass spectrometry (MS) and nuclear magnetic resonance (NMR). Finally, 11 lignan compounds and three flavonoid compounds were obtained. The method has a good orthogonality, and can improve the resolution and the peak capacity. It is significant for the separation of complex components from Trachelospermum jasminoides .

Mechanisms for chemostatic behavior in catchments: implications for CO2 consumption by mineral weathering

USGS Publications Warehouse

Clow, David W.; Mast, M. Alisa

2010-01-01

Concentrations of weathering products in streams often show relatively little variation compared to changes in discharge, both at event and annual scales. In this study, several hypothesized mechanisms for this “chemostatic behavior” were evaluated, and the potential for those mechanisms to influence relations between climate, weathering fluxes, and CO2 consumption via mineral weathering was assessed. Data from Loch Vale, an alpine catchment in the Colorado Rocky Mountains, indicates that cation exchange and seasonal precipitation and dissolution of amorphous or poorly crystalline aluminosilicates are important processes that help regulate solute concentrations in the stream; however, those processes have no direct effect on CO2 consumption in catchments. Hydrograph separation analyses indicate that old water stored in the subsurface over the winter accounts for about one-quarter of annual streamflow, and almost one-half of annual fluxes of Na and SiO2 in the stream; thus, flushing of old water by new water (snowmelt) is an important component of chemostatic behavior. Hydrologic flushing of subsurface materials further induces chemostatic behavior by reducing mineral saturation indices and increasing reactive mineral surface area, which stimulate mineral weathering rates. CO2 consumption by carbonic acid mediated mineral weathering was quantified using mass-balance calculations; results indicated that silicate mineral weathering was responsible for approximately two-thirds of annual CO2 consumption, and carbonate weathering was responsible for the remaining one-third. CO2 consumption was strongly dependent on annual precipitation and temperature; these relations were captured in a simple statistical model that accounted for 71% of the annual variation in CO2 consumption via mineral weathering in Loch Vale.

A Comprehensive Two-Dimensional Retention Time Alignment Algorithm To Enhance Chemometric Analysis of Comprehensive Two-Dimensional Separation Data

DOE Office of Scientific and Technical Information (OSTI.GOV)

Pierce, Karisa M.; Wood, Lianna F.; Wright, Bob W.

2005-12-01

A comprehensive two-dimensional (2D) retention time alignment algorithm was developed using a novel indexing scheme. The algorithm is termed comprehensive because it functions to correct the entire chromatogram in both dimensions and it preserves the separation information in both dimensions. Although the algorithm is demonstrated by correcting comprehensive two-dimensional gas chromatography (GC x GC) data, the algorithm is designed to correct shifting in all forms of 2D separations, such as LC x LC, LC x CE, CE x CE, and LC x GC. This 2D alignment algorithm was applied to three different data sets composed of replicate GC x GCmore » separations of (1) three 22-component control mixtures, (2) three gasoline samples, and (3) three diesel samples. The three data sets were collected using slightly different temperature or pressure programs to engender significant retention time shifting in the raw data and then demonstrate subsequent corrections of that shifting upon comprehensive 2D alignment of the data sets. Thirty 12-min GC x GC separations from three 22-component control mixtures were used to evaluate the 2D alignment performance (10 runs/mixture). The average standard deviation of the first column retention time improved 5-fold from 0.020 min (before alignment) to 0.004 min (after alignment). Concurrently, the average standard deviation of second column retention time improved 4-fold from 3.5 ms (before alignment) to 0.8 ms (after alignment). Alignment of the 30 control mixture chromatograms took 20 min. The quantitative integrity of the GC x GC data following 2D alignment was also investigated. The mean integrated signal was determined for all components in the three 22-component mixtures for all 30 replicates. The average percent difference in the integrated signal for each component before and after alignment was 2.6%. Singular value decomposition (SVD) was applied to the 22-component control mixture data before and after alignment to show the restoration of trilinearity to the data, since trilinearity benefits chemometric analysis. By applying comprehensive 2D retention time alignment to all three data sets (control mixtures, gasoline samples, and diesel samples), classification by principal component analysis (PCA) substantially improved, resulting in 100% accurate scores clustering.« less

15 CFR 996.4 - Liability.

Code of Federal Regulations, 2014 CFR

2014-01-01

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15 CFR 996.4 - Liability.

Code of Federal Regulations, 2013 CFR

2013-01-01

... REQUIREMENTS FOR NOAA HYDROGRAPHIC PRODUCTS AND SERVICES QUALITY ASSURANCE AND CERTIFICATION REQUIREMENTS FOR NOAA HYDROGRAPHIC PRODUCTS AND SERVICES General § 996.4 Liability. The Government of the United States...

15 CFR 996.4 - Liability.

Code of Federal Regulations, 2012 CFR

2012-01-01

... REQUIREMENTS FOR NOAA HYDROGRAPHIC PRODUCTS AND SERVICES QUALITY ASSURANCE AND CERTIFICATION REQUIREMENTS FOR NOAA HYDROGRAPHIC PRODUCTS AND SERVICES General § 996.4 Liability. The Government of the United States...

15 CFR 996.4 - Liability.

Code of Federal Regulations, 2011 CFR

2011-01-01

... REQUIREMENTS FOR NOAA HYDROGRAPHIC PRODUCTS AND SERVICES QUALITY ASSURANCE AND CERTIFICATION REQUIREMENTS FOR NOAA HYDROGRAPHIC PRODUCTS AND SERVICES General § 996.4 Liability. The Government of the United States...

Toward Separating Alpha-lactalbumin and Beta-lactoglobulin Proteins from Whey through Cation-exchange Adsorption

NASA Astrophysics Data System (ADS)

El-Sayed, Mayyada; Chase, Howard

2009-05-01

This paper describes the cation-exchange adsorption of the two major whey proteins, alpha-lactalbumin (ALA) and beta-lactoglobulin (BLG) with the purpose of establishing a process for isolating them from cow's milk whey. The single- and two-component adsorption of 1.5 mg/ml ALA and 3 mg/ml BLG to the cation-exchanger SP Sepharose FF at 20° C using 0.1 M acetate buffer of pH 3.7 was studied. Langmuir isotherm parameters were determined for the pure proteins. In two-component systems, BLG breakthrough curve exhibited an overshoot phenomenon that gave evidence for the presence of a competitive adsorption between the two proteins. Complete separation occurred and it was possible to obtain each of the two proteins in a pure form. The process was then applied to a whey concentrate mixture where incomplete separation took place. However, BLG was produced with 95% purity and a recovery of 80%, while ALA showed an 84% recovery with low purity.

Cold Regime Interannual Variability of Primary and Secondary Producer Community Composition in the Southeastern Bering Sea

PubMed Central

Stauffer, Beth A.; Miksis-Olds, Jennifer; Goes, Joaquim I.

2015-01-01

Variability of hydrographic conditions and primary and secondary productivity between cold and warm climatic regimes in the Bering Sea has been the subject of much study in recent years, while interannual variability within a single regime and across multiple trophic levels has been less well-documented. Measurements from an instrumented mooring on the southeastern shelf of the Bering Sea were analyzed for the spring-to-summer transitions within the cold regime years of 2009–2012 to investigate the interannual variability of hydrographic conditions, primary producer biomass, and acoustically-derived secondary producer and consumer abundance and community structure. Hydrographic conditions in 2012 were significantly different than in 2009, 2010, and 2011, driven largely by increased ice extent and thickness, later ice retreat, and earlier stratification of the water column. Primary producer biomass was more tightly coupled to hydrographic conditions in 2012 than in 2009 or 2011, and shallow and mid-column phytoplankton blooms tended to occur independent of one another. There was a high degree of variability in the relationships between different classes of secondary producers and hydrographic conditions, evidence of significant intra-consumer interactions, and trade-offs between different consumer size classes in each year. Phytoplankton blooms stimulated different populations of secondary producers in each year, and summer consumer populations appeared to determine dominant populations in the subsequent spring. Overall, primary producers and secondary producers were more tightly coupled to each other and to hydrographic conditions in the coldest year compared to the warmer years. The highly variable nature of the interactions between the atmospherically-driven hydrographic environment, primary and secondary producers, and within food webs underscores the need to revisit how climatic regimes within the Bering Sea are defined and predicted to function given changing climate scenarios. PMID:26110822

Cold Regime interannual variability of primary and secondary producer community composition in the southeastern Bering Sea.

PubMed

Stauffer, Beth A; Miksis-Olds, Jennifer; Goes, Joaquim I

2015-01-01

Variability of hydrographic conditions and primary and secondary productivity between cold and warm climatic regimes in the Bering Sea has been the subject of much study in recent years, while interannual variability within a single regime and across multiple trophic levels has been less well-documented. Measurements from an instrumented mooring on the southeastern shelf of the Bering Sea were analyzed for the spring-to-summer transitions within the cold regime years of 2009-2012 to investigate the interannual variability of hydrographic conditions, primary producer biomass, and acoustically-derived secondary producer and consumer abundance and community structure. Hydrographic conditions in 2012 were significantly different than in 2009, 2010, and 2011, driven largely by increased ice extent and thickness, later ice retreat, and earlier stratification of the water column. Primary producer biomass was more tightly coupled to hydrographic conditions in 2012 than in 2009 or 2011, and shallow and mid-column phytoplankton blooms tended to occur independent of one another. There was a high degree of variability in the relationships between different classes of secondary producers and hydrographic conditions, evidence of significant intra-consumer interactions, and trade-offs between different consumer size classes in each year. Phytoplankton blooms stimulated different populations of secondary producers in each year, and summer consumer populations appeared to determine dominant populations in the subsequent spring. Overall, primary producers and secondary producers were more tightly coupled to each other and to hydrographic conditions in the coldest year compared to the warmer years. The highly variable nature of the interactions between the atmospherically-driven hydrographic environment, primary and secondary producers, and within food webs underscores the need to revisit how climatic regimes within the Bering Sea are defined and predicted to function given changing climate scenarios.

OCEANOGRAPHIC SURVEY OF THE GULF OF MEXICO

DTIC Science & Technology

psychrometer readings were taken at 3 levels and wind, cloud, and other auxiliary data were taken at 6-hr intervals. A short hydrographic survey was made of...upon the loss of a hydrographic cable. The second cruise covered about 2160 mi. No hydrographic casts were made below 1200 m. Thirty-four stations were...occupied, of which 11 were in the water deeper than 1000 fathoms. Sixty-six bathy-thermographic observations were made , 2 on each deep station and the

Process for recovering organic components from liquid streams

DOEpatents

Blume, Ingo; Baker, Richard W.

1991-01-01

A separation process for recovering organic components from liquid streams. The process is a combination of pervaporation and decantation. In cases where the liquid stream contains the organic to be separated in dissolved form, the pervaporation step is used to concentrate the organic to a point above the solubility limit, so that a two-phase permeate is formed and then decanted. In cases where the liquid stream is a two-phase mixture, the decantation step is performed first, to remove the organic product phase, and the residue from the decanter is then treated by pervaporation. The condensed permeate from the pervaporation unit is sufficiently concentrated in the organic component to be fed back to the decanter. The process can be tailored to produce only two streams: an essentially pure organic product stream suitable for reuse, and a residue stream for discharge or reuse.

The use of multidate multichannel radiance data in urban feature analysis

NASA Technical Reports Server (NTRS)

Duggin, M. J.; Rowntree, R.; Emmons, M.; Hubbard, N.; Odell, A. W.

1986-01-01

Two images were obtained from thematic mappers on Landsats 4 and 5 over the Washington, DC area during November 1982 and March 1984. Selected training areas containing different types of urban land use were examined,one area consisting entirely of forest. Mean digital radiance values for each bandpass in each image were examined, and variances, standard deviations, and covariances between bandpasses were calculated. It has been found that two bandpasses caused forested areas to stand out from other land use types, especially for the November 1982 image. In order to evaluate quantitatively the possible utility of the principal components analysis in selected feature extraction, the eigenvectors were evaluated for principal axes rotations which rendered each selected land use type most separable from all other land use types. The evaluated eigenvectors were plotted as a function of land use type, whose order was decided by considering anticipated shadow component and by examining the relative loadings indicative of vegetation for each of the principal components for the different features considered. The analysis was performed for each seven-band image separately and for the two combined images. It was found that by combining the two images, more dramatic land use type separation could be obtained.

15 CFR 995.3 - Availability of other publications.

Code of Federal Regulations, 2014 CFR

2014-01-01

... CERTIFICATION REQUIREMENTS FOR NOAA HYDROGRAPHIC PRODUCTS AND SERVICES CERTIFICATION REQUIREMENTS FOR DISTRIBUTORS OF NOAA HYDROGRAPHIC PRODUCTS General § 995.3 Availability of other publications. (a) For further...

15 CFR 995.3 - Availability of other publications.

Code of Federal Regulations, 2012 CFR

2012-01-01

... CERTIFICATION REQUIREMENTS FOR NOAA HYDROGRAPHIC PRODUCTS AND SERVICES CERTIFICATION REQUIREMENTS FOR DISTRIBUTORS OF NOAA HYDROGRAPHIC PRODUCTS General § 995.3 Availability of other publications. (a) For further...

15 CFR 995.14 - Auditing.

Code of Federal Regulations, 2011 CFR

2011-01-01

... REQUIREMENTS FOR NOAA HYDROGRAPHIC PRODUCTS AND SERVICES CERTIFICATION REQUIREMENTS FOR DISTRIBUTORS OF NOAA HYDROGRAPHIC PRODUCTS Certification and Procedures § 995.14 Auditing. NOAA reserves the right to audit CED or...

15 CFR 995.14 - Auditing.

Code of Federal Regulations, 2014 CFR

2014-01-01

... REQUIREMENTS FOR NOAA HYDROGRAPHIC PRODUCTS AND SERVICES CERTIFICATION REQUIREMENTS FOR DISTRIBUTORS OF NOAA HYDROGRAPHIC PRODUCTS Certification and Procedures § 995.14 Auditing. NOAA reserves the right to audit CED or...

15 CFR 995.3 - Availability of other publications.

Code of Federal Regulations, 2013 CFR

2013-01-01

... CERTIFICATION REQUIREMENTS FOR NOAA HYDROGRAPHIC PRODUCTS AND SERVICES CERTIFICATION REQUIREMENTS FOR DISTRIBUTORS OF NOAA HYDROGRAPHIC PRODUCTS General § 995.3 Availability of other publications. (a) For further...

15 CFR 995.14 - Auditing.

Code of Federal Regulations, 2012 CFR

2012-01-01

... REQUIREMENTS FOR NOAA HYDROGRAPHIC PRODUCTS AND SERVICES CERTIFICATION REQUIREMENTS FOR DISTRIBUTORS OF NOAA HYDROGRAPHIC PRODUCTS Certification and Procedures § 995.14 Auditing. NOAA reserves the right to audit CED or...

15 CFR 995.22 - Training of data users.

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2013-01-01

... REQUIREMENTS FOR NOAA HYDROGRAPHIC PRODUCTS AND SERVICES CERTIFICATION REQUIREMENTS FOR DISTRIBUTORS OF NOAA HYDROGRAPHIC PRODUCTS Requirements for Certified Distributors and Value Added Distributors of NOAA ENC Products...

15 CFR 995.14 - Auditing.

Code of Federal Regulations, 2013 CFR

2013-01-01

... REQUIREMENTS FOR NOAA HYDROGRAPHIC PRODUCTS AND SERVICES CERTIFICATION REQUIREMENTS FOR DISTRIBUTORS OF NOAA HYDROGRAPHIC PRODUCTS Certification and Procedures § 995.14 Auditing. NOAA reserves the right to audit CED or...

15 CFR 995.22 - Training of data users.

Code of Federal Regulations, 2010 CFR

2010-01-01

... REQUIREMENTS FOR NOAA HYDROGRAPHIC PRODUCTS AND SERVICES CERTIFICATION REQUIREMENTS FOR DISTRIBUTORS OF NOAA HYDROGRAPHIC PRODUCTS Requirements for Certified Distributors and Value Added Distributors of NOAA ENC Products...

Effect of contrast leakage on the detection of abnormal brain tumor vasculature in high-grade glioma.

PubMed

LaViolette, Peter S; Daun, Mitchell K; Paulson, Eric S; Schmainda, Kathleen M

2014-02-01

Abnormal brain tumor vasculature has recently been highlighted by a dynamic susceptibility contrast (DSC) MRI processing technique. The technique uses independent component analysis (ICA) to separate arterial and venous perfusion. The overlap of the two, i.e. arterio-venous overlap or AVOL, preferentially occurs in brain tumors and predicts response to anti-angiogenic therapy. The effects of contrast agent leakage on the AVOL biomarker have yet to be established. DSC was acquired during two separate contrast boluses in ten patients undergoing clinical imaging for brain tumor diagnosis. Three components were modeled with ICA, which included the arterial and venous components. The percentage of each component as well as a third component were determined within contrast enhancing tumor and compared. AVOL within enhancing tumor was also compared between doses. The percentage of enhancing tumor classified as not arterial or venous and instead into a third component with contrast agent leakage apparent in the time-series was significantly greater for the first contrast dose compared to the second. The amount of AVOL detected within enhancing tumor was also significantly greater with the second dose compared to the first. Contrast leakage results in large signal variance classified as a separate component by the ICA algorithm. The use of a second dose mitigates the effect and allows measurement of AVOL within enhancement.

How Many Separable Sources? Model Selection In Independent Components Analysis

PubMed Central

Woods, Roger P.; Hansen, Lars Kai; Strother, Stephen

2015-01-01

Unlike mixtures consisting solely of non-Gaussian sources, mixtures including two or more Gaussian components cannot be separated using standard independent components analysis methods that are based on higher order statistics and independent observations. The mixed Independent Components Analysis/Principal Components Analysis (mixed ICA/PCA) model described here accommodates one or more Gaussian components in the independent components analysis model and uses principal components analysis to characterize contributions from this inseparable Gaussian subspace. Information theory can then be used to select from among potential model categories with differing numbers of Gaussian components. Based on simulation studies, the assumptions and approximations underlying the Akaike Information Criterion do not hold in this setting, even with a very large number of observations. Cross-validation is a suitable, though computationally intensive alternative for model selection. Application of the algorithm is illustrated using Fisher's iris data set and Howells' craniometric data set. Mixed ICA/PCA is of potential interest in any field of scientific investigation where the authenticity of blindly separated non-Gaussian sources might otherwise be questionable. Failure of the Akaike Information Criterion in model selection also has relevance in traditional independent components analysis where all sources are assumed non-Gaussian. PMID:25811988

Effect of uncertainty in Digital Surface Models on the boundary of inundated areas

NASA Astrophysics Data System (ADS)

Nalbantis, I.; Papageorgaki, I.; Sioras, P.; Ioannidis, Ch.

2012-04-01

The planning, design and operation of flood damage reduction works or non-structural measures require the construction of maps that indicate zones to be potentially inundated during floods. Referring to floods due to heavy rainfall, the common procedure for flood mapping consists of the following five computational steps: (1) Frequency analysis of extreme rainfall; (2) construction of design hyetographs for various return periods; (3) construction of the related direct runoff hydrographs; (4) routing of these hydrographs through the hydrographic network; (5) mapping of the inundated area that corresponds to the temporally maximum depth for each location in the flood plain. Steps 3 through 5 require the use of spatial information which can be easily obtained from a Digital Surface Model (DSM). The DSM contains grid-based elevations of the ground or overlying objects that influence the propagation of flood waves. In this work, the SCS-CN method is used in step 3 in combination with a synthetic Unit Hydrograph based on the SCS dimensionless Unit Hydrograph. In step 4, the full one-dimensional Saint Venant equations for non-uniform unsteady flow on fixed bed are used, which are numerically solved. The impact of uncertainty in the DSM on the inundated area boundary is investigated. For this the Monte Carlo simulation method is employed to produce a large number of erroneous DSMs through introducing errors in elevation with a standard deviation equal to σ. These DSMs are then used for delineating potentially flooded areas. The standard deviation of the distance (from the riverbed axis) of the boundary of these areas, herein denoted as σF, is used as the measure of the resulting uncertainty. The link between σ and σF is examined for a spectrum of large return periods (100 to 10000). A computer experiment was set up based on data from two drainage basins. The first basin is located in East Attica and is drained by a branch of the Erasinos Torrent named the South-East Kalyvia Torrent; it extends over an area of about 17 square kilometres. The second basin is that of the Kerynitis River in north-western Peloponnesus; it covers an area of 89 square kilometres. In each one of the two basins hydrographs at the outlet of the upper part of the basin are estimated with the aid of hydrological modelling, while, for the lower part hydraulic routing is employed. The South-East Kalyvia basin is hilly, whereas the Kerynitis Basin shows high ground slopes in its upper part and low slopes in the lower part. Graphs of σ vs. σF and maps showing the mean position μF of the boundary of flooded area along with limits of this boundary that reflect positions μF±2σF help visualize the impact of the uncertainty in DSM. To acquire a better feeling of the effect of DSM uncertainty, results are compared to those obtained from uncertain rainfall depths of the design hyetographs.

Spatial scale, means and gradients of hydrographic variables define pelagic seascapes of bluefin and bullet tuna spawning distribution.

PubMed

Alvarez-Berastegui, Diego; Ciannelli, Lorenzo; Aparicio-Gonzalez, Alberto; Reglero, Patricia; Hidalgo, Manuel; López-Jurado, Jose Luis; Tintoré, Joaquín; Alemany, Francisco

2014-01-01

Seascape ecology is an emerging discipline focused on understanding how features of the marine habitat influence the spatial distribution of marine species. However, there is still a gap in the development of concepts and techniques for its application in the marine pelagic realm, where there are no clear boundaries delimitating habitats. Here we demonstrate that pelagic seascape metrics defined as a combination of hydrographic variables and their spatial gradients calculated at an appropriate spatial scale, improve our ability to model pelagic fish distribution. We apply the analysis to study the spawning locations of two tuna species: Atlantic bluefin and bullet tuna. These two species represent a gradient in life history strategies. Bluefin tuna has a large body size and is a long-distant migrant, while bullet tuna has a small body size and lives year-round in coastal waters within the Mediterranean Sea. The results show that the models performance incorporating the proposed seascape metrics increases significantly when compared with models that do not consider these metrics. This improvement is more important for Atlantic bluefin, whose spawning ecology is dependent on the local oceanographic scenario, than it is for bullet tuna, which is less influenced by the hydrographic conditions. Our study advances our understanding of how species perceive their habitat and confirms that the spatial scale at which the seascape metrics provide information is related to the spawning ecology and life history strategy of each species.

Decadal to centennial oscillations in the upper and lower boundaries of the San Diego, California margin Oxygen Minimum Zone

NASA Astrophysics Data System (ADS)

Myhre, S. E.; Hill, T. M.; Frieder, C.; Grupe, B.

2016-02-01

Here we present two new marine sediment archives from the continental margin of San Diego, California, USA, which record decadal to centennial oscillations in the hydrographic structure of the Eastern Pacific Oxygen Minimum Zone (OMZ). The two cores, located at 528 and 1,180 m water depth, record oceanographic history across overlapping timescales. Biotic communities, including Foraminifera, Echinodermata, Brachiopoda, Mollusca and Ostrocoda, were examined in subsurface (>10 cm sediment core depth) samples. Chronologies for both cores were developed with reservoir-corrected 14C dates of mixed planktonic Foraminifera and linearly interpolated sedimentation rates. Sediment ages for the cores range from 400-1,800 years before present. Indices of foraminiferal community density, diversity and evenness are applied as biotic proxies to track the intensification of the continental margin OMZ. Biotic communities at the shallower site reveal multi-decadal to centennial timescales of OMZ intensification, whereas the deeper site exhibits decadal to multi-decadal scales of hydrographic variability. Hypoxia-associated foraminiferal genera Uvigerina and Bolivina were compositionally dominant during intervals of peak foraminiferal density. Invertebrate assemblages often co-occurred across taxa groups, and thereby provide a broad trophic context for interpreting changes in the margin seafloor. Variability in the advection of Pacific Equatorial Water may mechanistically contribute to this described hydrographic variability. This investigation reconstructs historical timescales of OMZ intensification, seafloor ecological variability, and synchrony between open-ocean processes and regional climate.

A large-scale phylogeny of Synodontis (Mochokidae, Siluriformes) reveals the influence of geological events on continental diversity during the Cenozoic.

PubMed

Pinton, Aurélie; Agnèse, Jean-François; Paugy, Didier; Otero, Olga

2013-03-01

To explain the spatial variability of fish taxa at a large scale, two alternative proposals are usually evoked. In recent years, the debate has centred on the relative roles of present and historical processes in shaping biodiversity patterns. In Africa, attempts to understand the processes that determine the large scale distribution of fishes and exploration of historical contingencies have been under-investigated given that most of the phylogenetic studies focus on the history of the Great Lakes. Here, we explore phylogeographic events in the evolutionary history of Synodontis (Mohokidae, Siluriformes) over Africa during the Cenozoic focusing on the putative role of historical processes. We discuss how known geological events together with hydrographical changes contributed to shape Synodontis biogeographical history. Synodontis was chosen on the basis of its high diversity and distribution in Africa: it consists of approximately 120 species that are widely distributed in all hydrographic basins except the Maghreb and South Africa. We propose the most comprehensive phylogeny of this catfish genus. Our results provide support for the 'hydrogeological' hypothesis, which proposes that palaeohydrological changes linked with the geological context may have been the cause of diversification of freshwater fish deep in the Tertiary. More precisely, the two main geological structures that participated to shape the hydrographical network in Africa, namely the Central African Shear zone and the East African rift system, appear as strong drivers of Synodontis diversification and evolution. Copyright © 2012 Elsevier Inc. All rights reserved.

Analysis of differential detergent fractions of an AtT-20 cellular homogenate using one- and two-dimensional capillary electrophoresis.

PubMed

Fazal, Md Abul; Palmer, Vanessa R; Dovichi, Norman J

2006-10-20

Differential detergent fractionation was used to sequentially extract cytosolic, membrane, nuclear, and cytoskeletal fractions from AtT-20 cells. Extracted components were denatured by sodium dodecyl sulfate (SDS) and then labeled with the fluorogenic reagent 3-(2-furoyl) quinoline-1-carboxaldehyde. Both capillary sieving electrophoresis (CSE) and micellar electrokinetic capillary chromatography (MECC) were used to separate labeled components by one-dimensional (1D) electrophoresis. Labeled components were also separated by two-dimensional (2D) capillary electrophoresis; CSE was employed in the first dimension and MECC in the second dimension. Roughly 150 fractions were transferred from the first to the second capillary for this comprehensive analysis in 2.5 h.

Impact of calibration errors on CMB component separation using FastICA and ILC

NASA Astrophysics Data System (ADS)

Dick, Jason; Remazeilles, Mathieu; Delabrouille, Jacques

2010-01-01

The separation of emissions from different astrophysical processes is an important step towards the understanding of observational data. This topic of component separation is of particular importance in the observation of the relic cosmic microwave background (CMB) radiation, as performed by the Wilkinson Microwave Anisotropy Probe satellite and the more recent Planck mission, launched on 2009 May 14 from Kourou and currently taking data. When performing any sort of component separation, some assumptions about the components must be used. One assumption that many techniques typically use is knowledge of the frequency scaling of one or more components. This assumption may be broken in the presence of calibration errors. Here we compare, in the context of imperfect calibration, the recovery of a clean map of emission of the CMB from observational data with two methods: FastICA (which makes no assumption of the frequency scaling of the components) and an `Internal Linear Combination' (ILC), which explicitly extracts a component with a given frequency scaling. We find that even in the presence of small calibration errors (less than 1 per cent) with a Planck-style mission, the ILC method can lead to inaccurate CMB reconstruction in the high signal-to-noise ratio regime, because of partial cancellation of the CMB emission in the recovered map. While there is no indication that the failure of the ILC will translate to other foreground cleaning or component separation techniques, we propose that all methods which assume knowledge of the frequency scaling of one or more components be careful to estimate the effects of calibration errors.

Use of fallout radionuclides ((7)Be, (210)Pb) to estimate resuspension of Escherichia coli from streambed sediments during floods in a tropical montane catchment.

PubMed

Ribolzi, Olivier; Evrard, Olivier; Huon, Sylvain; Rochelle-Newall, Emma; Henri-des-Tureaux, Thierry; Silvera, Norbert; Thammahacksac, Chanthamousone; Sengtaheuanghoung, Oloth

2016-02-01

Consumption of water polluted by faecal contaminants is responsible for 2 million deaths annually, most of which occur in developing countries without adequate sanitation. In tropical aquatic systems, streambeds can be reservoirs of persistent pathogenic bacteria and high rainfall can lead to contaminated soils entering streams and to the resuspension of sediment-bound microbes in the streambed. Here, we present a novel method using fallout radionuclides ((7)Be and (210)Pbxs) to estimate the proportions of Escherichia coli, an indicator of faecal contamination, associated with recently eroded soil particles and with the resuspension of streambed sediments. We show that using these radionuclides and hydrograph separations we are able to characterize the proportion of particles originating from highly contaminated soils and that from the resuspension of particle-attached bacteria within the streambed. We also found that although overland flow represented just over one tenth of the total flood volume, it was responsible for more than two thirds of the downstream transfer of E. coli. We propose that data obtained using this method can be used to understand the dynamics of faecal indicator bacteria (FIB) in streams thereby providing information for adapted management plans that reduce the health risks to local populations. Graphical Abstract Graphical abstract showing (1) the main water flow processes (i.e. overland flow, groundwater return flow, blue arrows) and sediment flow components (i.e. resuspension and soil erosion, black arrows) during floods in the Houay Pano catchment; (2) the general principle of the method using fallout radionuclide markers (i.e. (7)Be and (210)Pbxs) to estimate E. coli load from the two main sources (i.e. streambed resuspension vs soil surface washoff); and 3) the main results obtained during the 15 May 2012 storm event (i.e. relative percentage contribution of each process to the total streamflow, values in parentheses).

A modified approach for isolation of essential oil from fruit of Amorpha fruticosa Linn using microwave-assisted hydrodistillation concatenated liquid-liquid extraction.

PubMed

Chen, Fengli; Jia, Jia; Zhang, Qiang; Gu, Huiyan; Yang, Lei

2017-11-17

In this work, a modified technique was developed to separate essential oil from the fruit of Amorpha fruticosa using microwave-assisted hydrodistillation concatenated liquid-liquid extraction (MHD-LLE). The new apparatus consists of two series-wound separation columns for separating essential oil, one is the conventional oil-water separation column, and the other is the extraction column of components from hydrosol using an organic solvent. Therefore, the apparatus can simultaneously collect the essential oil separated on the top of hydrosol and the components extracted from hydrosol using an organic solvent. Based on the yield of essential oil in the first and second separation columns, the effects of parameters were investigated by single factor experiments and Box-Behnken design. Under the optimum conditions (2mL ethyl ether as the extraction solvent in the second separation column, 12mL/g liquid-solid ratio, 4.0min homogenate time, 35min microwave irradiation time and 540W microwave irradiation power), satisfactory yields for the essential oil in the first separation column (10.31±0.33g/kg) and second separation column (0.82±0.03g/kg) were obtained. Compared with traditional methods, the developed method gave a higher yield of essential oil in a shorter time. In addition, GC-MS analysis of the essential oil indicated significant differences of the relative contents of individual volatile components in the essential oils obtained in the two separation columns. Therefore, the MHD-LLE technique developed here is a good alternative for the isolation of essential oil from A. fruticosa fruit as well as other herbs. Copyright © 2017 Elsevier B.V. All rights reserved.

Capillary sieving electrophoresis and micellar electrokinetic capillary chromatography produce highly correlated separation of tryptic digests

PubMed Central

Dickerson, Jane A.; Dovichi, Norman J.

2011-01-01

We perform two-dimensional capillary electrophoresis on fluorescently labeled proteins and peptides. Capillary sieving electrophoresis was performed in the first dimension and micellar electrokinetic capillary chromatography was performed in the second. A cellular homogenate was labeled with the fluorogenic reagent FQ and separated using the system. This homogenate generated a pair of ridges; the first had essentially constant migration time in the CSE dimension, while the second had essentially constant migration time in the MEKC dimension. In addition a few spots were scattered through the electropherogram. The same homogenate was digested using trypsin, and then labeled and subjected to the two dimensional separation. In this case, the two ridges observed from the original two-dimensional separation disappeared, and were replaced by a set of spots that fell along the diagonal. Those spots were identified using a local-maximum algorithm and each was fit using a two-dimensional Gaussian surface by an unsupervised nonlinear least squares regression algorithm. The migration times of the tryptic digest components were highly correlated (r = 0.862). When the slowest migrating components were eliminated from the analysis, the correlation coefficient improved to r = 0.956. PMID:20564272

Device for magneto-optic signal detection with a small crystal prism.

PubMed

Saito, K; Sato, S; Shino, K; Taniguchi, T

2000-03-10

A device made of a birefringent crystal for signal detection of magneto-optic (MO) disks is presented. The light beam from a MO disk is separated into two orthogonally polarized components at the surface of a birefringent prism. After these two components are reflected by the top and the bottom surfaces of the prism inside, at the detector they become sufficiently separated from each other for discrete detection, even though the prism is small. A method for calculating the light intensities and the positions of focused beams in a birefringent prism and the results of a fundamental experiment are presented.

Improved application of independent component analysis to functional magnetic resonance imaging study via linear projection techniques.

PubMed

Long, Zhiying; Chen, Kewei; Wu, Xia; Reiman, Eric; Peng, Danling; Yao, Li

2009-02-01

Spatial Independent component analysis (sICA) has been widely used to analyze functional magnetic resonance imaging (fMRI) data. The well accepted implicit assumption is the spatially statistical independency of intrinsic sources identified by sICA, making the sICA applications difficult for data in which there exist interdependent sources and confounding factors. This interdependency can arise, for instance, from fMRI studies investigating two tasks in a single session. In this study, we introduced a linear projection approach and considered its utilization as a tool to separate task-related components from two-task fMRI data. The robustness and feasibility of the method are substantiated through simulation on computer data and fMRI real rest data. Both simulated and real two-task fMRI experiments demonstrated that sICA in combination with the projection method succeeded in separating spatially dependent components and had better detection power than pure model-based method when estimating activation induced by each task as well as both tasks.

IDENTIFICATION OF SEDIMENT SOURCE AREAS WITHIN A WATERSHED

EPA Science Inventory

Two methods, one using a travel time approach and the other based on optimization techniques, were developed to identify sediment generating areas within a watershed. Both methods rely on hydrograph and sedimentograph data collected at the mouth of the watershed. Data from severa...

Unit Hydrograph Peaking Analysis for Goose Creek Watershed in Virginia: A Case Study

DTIC Science & Technology

2017-05-01

ER D C/ CH L TR -1 7- 6 Unit Hydrograph Peaking Analysis for Goose Creek Watershed in Virginia: A Case Study Co as ta l a nd H yd ra...default. ERDC/CHL TR-17-6 May 2017 Unit Hydrograph Peaking Analysis for Goose Creek Watershed in Virginia: A Case Study Nawa Raj Pradhan and...confidence interval precipitation depths to the watershed in addition to the 50% value. This study concluded that a design event with a return period greater

Topographic and hydrographic survey data for the São Francisco River near Torrinha, Bahia, Brazil, 2014

USGS Publications Warehouse

Fosness, Ryan L.; Dietsch, Benjamin J.

2015-10-21

This report presents the surveying techniques and data-processing methods used to collect, process, and disseminate topographic and hydrographic data. All standard and non‑standard data-collection methods, techniques, and data process methods were documented. Additional discussion describes the quality-assurance and quality-control elements used in this study, along with the limitations for the Torrinha-Itacoatiara study reach data. The topographic and hydrographic geospatial data are published along with associated metadata.

Hydrographs showing groundwater levels for selected wells in the Puyallup River watershed and vicinity, Pierce and King Counties, Washington

USGS Publications Warehouse

Lane, R.C.; Julich, R.J.; Justin, G.B.

2013-01-01

Hydrographs of groundwater levels for selected wells in and adjacent to the Puyallup River watershed in Pierce and King Counties, Washington, are presented using an interactive Web-based map of the study area to illustrate changes in groundwater levels on a monthly and seasonal basis. The interactive map displays well locations that link to the hydrographs, which in turn link to the U.S. Geological Survey National Water Information System, Groundwater Site Inventory System.

Report of the Hydrographic Service Royal Australian Navy for the Year Ended 30th June 1983, Issue Number 19.

DTIC Science & Technology

1983-01-01

eastwards of MORESBY’s 1981 survey. The ship suffered considerable problems in establishing her ARGO stations on this barren and inhospitable coast...on 6 months exchange whilst an RFMF officer pined experience in Australia. A CPOSR has continued the loan service arrang-ments in support of the...training in hydrographic surveying is undertaken at the Royal Navy’s Hydrographic School in Plymouth . It is expected that an average of four officers will

Instrumentation for detailed bridge-scour measurements

USGS Publications Warehouse

Landers, Mark N.; Mueller, David S.; Trent, Roy E.; ,

1993-01-01

A portable instrumentation system is being developed to obtain channel bathymetry during floods for detailed bridge-scour measurements. Portable scour measuring systems have four components: sounding instrument, horizontal positioning instrument, deployment mechanisms, and data storage device. The sounding instrument will be a digital fathometer. Horizontal position will be measured using a range-azimuth based hydrographic survey system. The deployment mechanism designed for this system is a remote-controlled boat using a small waterplane area, twin-hull design. An on-board computer and radio will monitor the vessel instrumentation, record measured data, and telemeter data to shore.

Ground-water recharge from streamflow data, NW Florida

USGS Publications Warehouse

Vecchioli, John; Bridges, W.C.; Rumenik, Roger P.; Grubbs, J.W.

1991-01-01

Annual base flows of streams draining Okaloosa County and adjacent areas in northwest Florida were determined through hydrograph separation and correlation techniques for purposes of evaluating variations in ground-water recharge rates. Base flows were least in the northern part of the county and greatest in the southern part. Topographic and soils data were then superimposed on the distribution of base flow by subbasin to produce a map showing distribution of ground-water recharge throughout the county. The highest recharge rate occurs in the southern part of the county where relatively flat upland areas underlain by excessively drained sandy soils result in minimal storm runoff and evapotranspiration.

Simultaneous water activation and glucose metabolic rate imaging with PET

NASA Astrophysics Data System (ADS)

Verhaeghe, Jeroen; Reader, Andrew J.

2013-02-01

A novel imaging and signal separation strategy is proposed to be able to separate [18F]FDG and multiple [15O]H2O signals from a simultaneously acquired dynamic PET acquisition of the two tracers. The technique is based on the fact that the dynamics of the two tracers are very distinct. By adopting an appropriate bolus injection strategy and by defining tailored sets of basis functions that model either the FDG or water component, it is possible to separate the FDG and water signal. The basis functions are inspired from the spectral analysis description of dynamic PET studies and are defined as the convolution of estimated generating functions (GFs) with a set of decaying exponential functions. The GFs are estimated from the overall measured head curve, while the decaying exponential functions are pre-determined. In this work, the time activity curves (TACs) are modelled post-reconstruction but the model can be incorporated in a global 4D reconstruction strategy. Extensive PET simulation studies are performed considering single [18F]FDG and 6 [15O]H2O bolus injections for a total acquisition time of 75 min. The proposed method is evaluated at multiple noise levels and different parameters were estimated such as [18F]FDG uptake and blood flow estimated from the [15O]H2O component, requiring a full dynamic analysis of the two components, static images of [18F]FDG and the water components as well as [15O]H2O activation. It is shown that the resulting images and parametric values in ROIs are comparable to images obtained from separate imaging, illustrating the feasibility of simultaneous imaging of [18F]FDG and [15O]H2O components. For more information on this article, see medicalphysicsweb.org

OpenSimulator Interoperability with DRDC Simulation Tools: Compatibility Study

DTIC Science & Technology

2014-09-01

into two components: (1) backend data services consisting of user accounts, login service, assets, and inventory; and (2) the simulator server which...components are combined into a single OpenSimulator process. In grid mode, the two components are separated, placing the backend services into a ROBUST... mobile devices. Potential points of compatibility between Unity and OpenSimulator include: a Unity-based desktop computer OpenSimulator viewer; a

Is a bird in the hand worth two in the future? Intertemporal choice, attachment and theory of mind in school-aged children.

PubMed

Marchetti, Antonella; Castelli, Ilaria; Sanvito, Laura; Massaro, Davide

2014-01-01

Intertemporal choice is a decision-making dilemma related to outcomes of different entity located at different time points. Economic and psychological literature on this topic showed the phenomen of temporal discounting, i.e., the proclivity to devalue the outcome distant in time on the basis of the time delay necessary to obtain it. The goals of this research are to investigate two different components of intertemporal choice separately, namely time and outcome, in school-age children, and the possible link among such components and the security of attachment style and theory of mind. Ninety one children aged between 6 and 10 years performed two intertemporal choice tasks, first and second order false belief tasks and the Separation Anxiety Task in the Family and School versions. Results showed that the two components of intertemporal choice (waiting tolerance and sensitivity to delayed outcome) are stately interrelated; the quality of the attachment to the family caregiver affects the tolerance to waiting time and first order false belief understanding affects both the components of intertemporal choice.

Is a bird in the hand worth two in the future? Intertemporal choice, attachment and theory of mind in school-aged children

PubMed Central

Marchetti, Antonella; Castelli, Ilaria; Sanvito, Laura; Massaro, Davide

2014-01-01

Intertemporal choice is a decision-making dilemma related to outcomes of different entity located at different time points. Economic and psychological literature on this topic showed the phenomen of temporal discounting, i.e., the proclivity to devalue the outcome distant in time on the basis of the time delay necessary to obtain it. The goals of this research are to investigate two different components of intertemporal choice separately, namely time and outcome, in school-age children, and the possible link among such components and the security of attachment style and theory of mind. Ninety one children aged between 6 and 10 years performed two intertemporal choice tasks, first and second order false belief tasks and the Separation Anxiety Task in the Family and School versions. Results showed that the two components of intertemporal choice (waiting tolerance and sensitivity to delayed outcome) are stately interrelated; the quality of the attachment to the family caregiver affects the tolerance to waiting time and first order false belief understanding affects both the components of intertemporal choice. PMID:24904496

Separation of pedogenic and lithogenic components of magnetic susceptibility in the Chinese loess/palaeosol sequence as determined by the CBD procedure and a mixing analysis

NASA Astrophysics Data System (ADS)

Vidic, Nataša. J.; TenPas, Jeff D.; Verosub, Kenneth L.; Singer, Michael J.

2000-08-01

Magnetic susceptibility variations in the Chinese loess/palaeosol sequences have been used extensively for palaeoclimatic interpretations. The magnetic signal of these sequences must be divided into lithogenic and pedogenic components because the palaeoclimatic record is primarily reflected in the pedogenic component. In this paper we compare two methods for separating the pedogenic and lithogenic components of the magnetic susceptibility signal: the citrate-bicarbonate-dithionite (CBD) extraction procedure, and a mixing analysis. Both methods yield good estimates of the pedogenic component, especially for the palaeosols. The CBD procedure underestimates the lithogenic component and overestimates the pedogenic component. The magnitude of this effect is moderately high in loess layers but almost negligible in palaeosols. The mixing model overestimates the lithogenic component and underestimates the pedogenic component. Both methods can be adjusted to yield better estimates of both components. The lithogenic susceptibility, as determined by either method, suggests that palaeoclimatic interpretations based only on total susceptibility will be in error and that a single estimate of the average lithogenic susceptibility is not an accurate basis for adjusting the total susceptibility. A long-term decline in lithogenic susceptibility with depth in the section suggests more intense or prolonged periods of weathering associated with the formation of the older palaeosols. The CBD procedure provides the most comprehensive information on the magnitude of the components and magnetic mineralogy of loess and palaeosols. However, the mixing analysis provides a sensitive, rapid, and easily applied alternative to the CBD procedure. A combination of the two approaches provides the most powerful and perhaps the most accurate way of separating the magnetic susceptibility components.

Fuel and fuel blending components from biomass derived pyrolysis oil

DOEpatents

McCall, Michael J.; Brandvold, Timothy A.; Elliott, Douglas C.

2012-12-11

A process for the conversion of biomass derived pyrolysis oil to liquid fuel components is presented. The process includes the production of diesel, aviation, and naphtha boiling point range fuels or fuel blending components by two-stage deoxygenation of the pyrolysis oil and separation of the products.

The intrinsic dependence structure of peak, volume, duration, and average intensity of hyetographs and hydrographs

NASA Astrophysics Data System (ADS)

Serinaldi, Francesco; Kilsby, Chris G.

2013-06-01

The information contained in hyetographs and hydrographs is often synthesized by using key properties such as the peak or maximum value Xp, volume V, duration D, and average intensity I. These variables play a fundamental role in hydrologic engineering as they are used, for instance, to define design hyetographs and hydrographs as well as to model and simulate the rainfall and streamflow processes. Given their inherent variability and the empirical evidence of the presence of a significant degree of association, such quantities have been studied as correlated random variables suitable to be modeled by multivariate joint distribution functions. The advent of copulas in geosciences simplified the inference procedures allowing for splitting the analysis of the marginal distributions and the study of the so-called dependence structure or copula. However, the attention paid to the modeling task has overlooked a more thorough study of the true nature and origin of the relationships that link Xp,V,D, and I. In this study, we apply a set of ad hoc bootstrap algorithms to investigate these aspects by analyzing the hyetographs and hydrographs extracted from 282 daily rainfall series from central eastern Europe, three 5 min rainfall series from central Italy, 80 daily streamflow series from the continental United States, and two sets of 200 simulated universal multifractal time series. Our results show that all the pairwise dependence structures between Xp,V,D, and I exhibit some key properties that can be reproduced by simple bootstrap algorithms that rely on a standard univariate resampling without resort to multivariate techniques. Therefore, the strong similarities between the observed dependence structures and the agreement between the observed and bootstrap samples suggest the existence of a numerical generating mechanism based on the superposition of the effects of sampling data at finite time steps and the process of summing realizations of independent random variables over random durations. We also show that the pairwise dependence structures are weakly dependent on the internal patterns of the hyetographs and hydrographs, meaning that the temporal evolution of the rainfall and runoff events marginally influences the mutual relationships of Xp,V,D, and I. Finally, our findings point out that subtle and often overlooked deterministic relationships between the properties of the event hyetographs and hydrographs exist. Confusing these relationships with genuine stochastic relationships can lead to an incorrect application of multivariate distributions and copulas and to misleading results.

Hydrograph structure informed calibration in the frequency domain with time localization

NASA Astrophysics Data System (ADS)

Kumarasamy, K.; Belmont, P.

2015-12-01

Complex models with large number of parameters are commonly used to estimate sediment yields and predict changes in sediment loads as a result of changes in management or conservation practice at large watershed (>2000 km2) scales. As sediment yield is a strongly non-linear function that responds to channel (peak or mean) velocity or flow depth, it is critical to accurately represent flows. The process of calibration in such models (e.g., SWAT) generally involves the adjustment of several parameters to obtain better estimates of goodness of fit metrics such as Nash Sutcliff Efficiency (NSE). However, such indicators only provide a global view of model performance, potentially obscuring accuracy of the timing or magnitude of specific flows of interest. We describe an approach for streamflow calibration that will greatly reduce the black-box nature of calibration, when response from a parameter adjustment is not clearly known. Fourier Transform or the Short Term Fourier Transform could be used to characterize model performance in the frequency domain as well, however, the ambiguity of a Fourier transform with regards to time localization renders its implementation in a model calibration setting rather useless. Brief and sudden changes (e.g. stream flow peaks) in signals carry the most interesting information from parameter adjustments, which are completely lost in the transform without time localization. Wavelet transform captures the frequency component in the signal without compromising time and is applied to contrast changes in signal response to parameter adjustments. Here we employ the mother wavelet called the Mexican hat wavelet and apply a Continuous Wavelet Transform to understand the signal in the frequency domain. Further, with the use of the cross-wavelet spectrum we examine the relationship between the two signals (prior or post parameter adjustment) in the time-scale plane (e.g., lower scales correspond to higher frequencies). The non-stationarity of the streamflow signal does not hinder this assessment and regions of change called boundaries of influence (seasons or time when such change occurs in the hydrograph) for each parameter are delineated. In addition, we can discover the structural component of the signal (e.g., shifts or amplitude change) that has changed.

On Another Edge of Defocusing: Hyperbolicity of Asymmetric Lemon Billiards

NASA Astrophysics Data System (ADS)

Bunimovich, Leonid; Zhang, Hong-Kun; Zhang, Pengfei

2016-02-01

Defocusing mechanism provides a way to construct chaotic (hyperbolic) billiards with focusing components by separating all regular components of the boundary of a billiard table sufficiently far away from each focusing component. If all focusing components of the boundary of the billiard table are circular arcs, then the above separation requirement reduces to that all circles obtained by completion of focusing components are contained in the billiard table. In the present paper we demonstrate that a class of convex tables— asymmetric lemons, whose boundary consists of two circular arcs, generate hyperbolic billiards. This result is quite surprising because the focusing components of the asymmetric lemon table are extremely close to each other, and because these tables are perturbations of the first convex ergodic billiard constructed more than 40 years ago.

Isotopic separation of snowmelt runoff during an artificial rain-on-snow event

NASA Astrophysics Data System (ADS)

Juras, Roman; Pavlasek, Jirka; Šanda, Martin; Jankovec, Jakub; Linda, Miloslav

2013-04-01

Rain-on-snow events are common phenomenon in the climate conditions of central Europe, mainly during the spring snowmelt period. These events can cause serious floods in areas with seasonal snow. The snowpack hit by rain is able to store a fraction of rain water, but runoff caused by additional snowmelt also increases. Assessment of the rainwater ratio contributing to the outflow from the snowpack is therefore critical for discharge modelling. A rainfall simulator and water enriched by deuterium were used for the study of rainwater behaviour during an artificial rain-on-snow event. An area of 1 m2 of the snow sample, which was 1.2 m deep, consisting of ripped coarse-grained snow, was sprayed during the experiment with deuterium enriched water. The outflow from the snowpack was measured and samples of outflow water were collected. The isotopic content of deuterium was further analyzed from these samples by means of laser spectroscopy for the purpose of hydrograph separation. The concentration of deuterium in snow before and after the experiment was also investigated. The deuterium enriched water above the natural concentration of deuterium in snowpack was detected in the outflow in 7th minute from start of spraying, but the significant increase of deuterium concentration in outflow was observed in 19th minute. The isotopic hydrograph separation estimated, that deuterium enriched rainwater became the major part (> 50% volumetric) of the outflow in 28th minute. The culmination of the outflow (1.23 l min-1) as well as deuterium enriched rainwater fraction (63.5%) in it occurred in 63th minute, i.e. right after the end of spraying. In total, 72.7 l of deuterium enriched water was sprayed on the snowpack in 62 minutes. Total volume of outflow (after 12.3 hours) water was 97.4 l, which contained 48.3 l of deuterium enriched water (i.e. 49.6 %) and 49.1 l (50.4 %) of the melted snowpack. The volume of 24.4 l of deuterium enriched spray-water was stored in the snowpack. The increased total output v. input of the water volume was caused by the warmer spray-water induced snowmelt also connecting separated liquid layers in the snowpack within the process of infiltration and drainage. Key words: deuterium tracer, rainfall simulator, snowmelt

Performance comparison of three types of high-speed counter-current chromatographs for the separation of components of hydrophilic and hydrophobic color additives.

PubMed

Weisz, Adrian; Ito, Yoichiro

2011-09-09

The performance of three types of high-speed counter-current chromatography (HSCCC) instruments was assessed for their use in separating components in hydrophilic and hydrophobic dye mixtures. The HSCCC instruments compared were: (i) a J-type coil planet centrifuge (CPC) system with a conventional multilayer-coil column, (ii) a J-type CPC system with a spiral-tube assembly-coil column, and (iii) a cross-axis CPC system with a multilayer-coil column. The hydrophilic dye mixture consisted of a sample of FD&C Blue No. 2 that contained mainly two isomeric components, 5,5'- and 5,7'-disulfonated indigo, in the ratio of ∼7:1. The hydrophobic dye mixture consisted of a sample of D&C Red No. 17 (mainly Sudan III) and Sudan II in the ratio of ∼4:1. The two-phase solvent systems used for these separations were 1-butanol/1.3M HCl and hexane/acetonitrile. Each of the three instruments was used in two experiments for the hydrophilic dye mixture and two for the hydrophobic dye mixture, for a total of 12 experiments. In one set of experiments, the lower phase was used as the mobile phase, and in the second set of experiments, the upper phase was used as the mobile phase. The results suggest that: (a) use of a J-type instrument with either a multilayer-coil column or a spiral-tube assembly column, applying the lower phase as the mobile phase, is preferable for separating the hydrophilic components of FD&C Blue No. 2; and (b) use of a J-type instrument with multilayer-coil column, while applying either the upper phase or the lower phase as the mobile phase, is preferable for separating the hydrophobic dye mixture of D&C Red No. 17 and Sudan II. Published by Elsevier B.V.

Eogenetic karst hydrology: insights from the 2004 hurricanes, peninsular Florida.

PubMed

Florea, Lee J; Vacher, H L

2007-01-01

Eogenetic karst lies geographically and temporally close to the depositional environment of limestone in warm marine water at low latitude, in areas marked by midafternoon thunderstorms during a summer rainy season. Spring hydrographs from such an environment in north-central Florida are characterized by smooth, months-long, seasonal maxima. The passage of Hurricanes Frances and Jeanne in September 2004 over three field locations shows how the eogenetic karst of the Upper Floridan Aquifer responds to unequivocal recharge events. Hydrographs at wells in the High Springs area, Rainbow Springs, and at Morris, Briar, and Bat Caves all responded promptly with a similar drawn-out rise to a maximum that extended long into the winter dry season. The timing indicates that the typical hydrograph of eogenetic karst is not the short-term fluctuations of springs in epigenic, telogenetic karst, or the smoothed response to all the summer thunderstorms, but rather the protracted response of the system to rainfall that exceeds a threshold. The similarity of cave and noncave hydrographs indicates distributed autogenic recharge and a free communication between secondary porosity and permeable matrix-both of which differ from the hydrology of epigenic, telogenetic karst. At Briar Cave, drip rates lagged behind the water table rise, suggesting that recharge was delivered by fractures, which control the cave's morphology. At High Springs, hydrographs at the Santa Fe River and a submerged conduit apparently connected to it show sharp maxima after the storms, unlike the other cave hydrographs. Our interpretation is that the caves, in general, are discontinuous.

Disordered hyperuniformity in two-component nonadditive hard-disk plasmas

NASA Astrophysics Data System (ADS)

Lomba, Enrique; Weis, Jean-Jacques; Torquato, Salvatore

2017-12-01

We study the behavior of a classical two-component ionic plasma made up of nonadditive hard disks with additional logarithmic Coulomb interactions between them. Due to the Coulomb repulsion, long-wavelength total density fluctuations are suppressed and the system is globally hyperuniform. Short-range volume effects lead to phase separation or to heterocoordination for positive or negative nonadditivities, respectively. These effects compete with the hidden long-range order imposed by hyperuniformity. As a result, the critical behavior of the mixture is modified, with long-wavelength concentration fluctuations partially damped when the system is charged. It is also shown that the decrease of configurational entropy due to hyperuniformity originates from contributions beyond the two-particle level. Finally, despite global hyperuniformity, we show that in our system the spatial configuration associated with each component separately is not hyperuniform, i.e., the system is not "multihyperuniform."

A Geochemical Mass-Balance Method for Base-Flow Separation, Upper Hillsborough River Watershed, West-Central Florida, 2003-2005 and 2009

USGS Publications Warehouse

Kish, G.R.; Stringer, C.E.; Stewart, M.T.; Rains, M.C.; Torres, A.E.

2010-01-01

Geochemical mass-balance (GMB) and conductivity mass-balance (CMB) methods for hydrograph separation were used to determine the contribution of base flow to total stormflow at two sites in the upper Hillsborough River watershed in west-central Florida from 2003-2005 and at one site in 2009. The chemical and isotopic composition of streamflow and precipitation was measured during selected local and frontal low- and high-intensity storm events and compared to the geochemical and isotopic composition of groundwater. Input for the GMB method included cation, anion, and stable isotope concentrations of surface water and groundwater, whereas input for the CMB method included continuous or point-sample measurement of specific conductance. The surface water is a calcium-bicarbonate type water, which closely resembles groundwater geochemically, indicating that much of the surface water in the upper Hillsborough River basin is derived from local groundwater discharge. This discharge into the Hillsborough River at State Road 39 and at Hillsborough River State Park becomes diluted by precipitation and runoff during the wet season, but retains the calcium-bicarbonate characteristics of Upper Floridan aquifer water. Field conditions limited the application of the GMB method to low-intensity storms but the CMB method was applied to both low-intensity and high-intensity storms. The average contribution of base flow to total discharge for all storms ranged from 31 to 100 percent, whereas the contribution of base flow to total discharge during peak discharge periods ranged from less than 10 percent to 100 percent. Although calcium, magnesium, and silica were consistent markers of Upper Floridan aquifer chemistry, their use in calculating base flow by the GMB method was limited because the frequency of point data collected in this study was not sufficient to capture the complete hydrograph from pre-event base-flow to post-event base-flow concentrations. In this study, pre-event water represented somewhat diluted groundwater. Streamflow conductivity integrates the concentrations of the major ions, and the logistics of acquiring specific conductance at frequent time intervals are less complicated than data collection, sample processing, shipment, and analysis of water samples in a laboratory. The acquisition of continuous specific conductance data reduces uncertainty associated with less-frequently collected geochemical point data.

Ecosystem Consequences of Contrasting Flow Regimes in an Urban Effects Stream Mesocosm Study

EPA Science Inventory

A stream mesocosm experiment was conducted to study the ecosystem-wide effects of two replicated flow hydrograph treatments programmed in an attempt to compare a simulated predevelopment condition to the theoretical changes that new development brings, while accounting for engine...

Dual laser optical system and method for studying fluid flow

NASA Technical Reports Server (NTRS)

Owen, R. B.; Witherow, W. K. (Inventor)

1983-01-01

A dual laser optical system and method is disclosed for visualization of phenomena in transport substances which induce refractive index gradients such as fluid flow and pressure and temperature gradients in fluids and gases. Two images representing mutually perpendicular components of refractive index gradients may be viewed simultaneously on screen. Two lasers having wave lengths in the visible range but separated by about 1000 angstroms are utilized to provide beams which are collimated into a beam containing components of the different wave lengths. The collimated beam is passed through a test volume of the transparent substance. The collimated beam is then separated into components of the different wave lengths and focused onto a pair of knife edges arranged mutually perpendicular to produce and project images onto the screen.

15 CFR 996.32 - Appeals.

Code of Federal Regulations, 2010 CFR

2010-01-01

... AND ATMOSPHERIC ADMINISTRATION, DEPARTMENT OF COMMERCE QUALITY ASSURANCE AND CERTIFICATION REQUIREMENTS FOR NOAA HYDROGRAPHIC PRODUCTS AND SERVICES QUALITY ASSURANCE AND CERTIFICATION REQUIREMENTS FOR NOAA HYDROGRAPHIC PRODUCTS AND SERVICES Other Quality Assurance Program Matters § 996.32 Appeals. (a...

Fluid dynamic mechanisms and interactions within separated flows

NASA Astrophysics Data System (ADS)

Dutton, J. C.; Addy, A. L.

1990-02-01

The significant results of a joint research effort investigating the fundamental fluid dynamic mechanisms and interactions within high-speed separated flows are presented in detail. The results have obtained through analytical and numerical approaches, but with primary emphasis on experimental investigations of missile and projectile base flow-related configurations. The objectives of the research program focus on understanding the component mechanisms and interactions which establish and maintain high-speed separated flow regions. The analytical and numerical efforts have centered on unsteady plume-wall interactions in rocket launch tubes and on predictions of the effects of base bleed on transonic and supersonic base flowfields. The experimental efforts have considered the development and use of a state-of-the-art two component laser Doppler velocimeter (LDV) system for experiments with planar, two-dimensional, small-scale models in supersonic flows. The LDV experiments have yielded high quality, well documented mean and turbulence velocity data for a variety of high-speed separated flows including initial shear layer development, recompression/reattachment processes for two supersonic shear layers, oblique shock wave/turbulent boundary layer interactions in a compression corner, and two-stream, supersonic, near-wake flow behind a finite-thickness base.

Three-dimensional analysis of magnetometer array data

NASA Technical Reports Server (NTRS)

Richmond, A. D.; Baumjohann, W.

1984-01-01

A technique is developed for mapping magnetic variation fields in three dimensions using data from an array of magnetometers, based on the theory of optimal linear estimation. The technique is applied to data from the Scandinavian Magnetometer Array. Estimates of the spatial power spectra for the internal and external magnetic variations are derived, which in turn provide estimates of the spatial autocorrelation functions of the three magnetic variation components. Statistical errors involved in mapping the external and internal fields are quantified and displayed over the mapping region. Examples of field mapping and of separation into external and internal components are presented. A comparison between the three-dimensional field separation and a two-dimensional separation from a single chain of stations shows that significant differences can arise in the inferred internal component.

Report of the Hydrographic Service Royal Australian Navy for the Year ended 30th June 1985, Issue Number 21.

DTIC Science & Technology

1985-01-01

Mapping Council which will be held in October 1985. IJS. COMPTONAPTAIN RAN HYDROGRAPHER RAN Accesion For NTIS -CRAMI LDrIC TAB U,.annournced 0 J ...itifcation By .-........ . Di.. t ibution Availability Codes Dit Avail ar-.I or A-1 QUALITYSSPECTED - 2 L. 2. GENERAL The RAN Hydrographic Service, the...FLINDERS used Side Scan Sonar and her diving team to find, and determine the least depths over, the wrecks SAFARI and ERICA J lying on the sea-bed in the

Runoff prediction using rainfall data from microwave links: Tabor case study.

PubMed

Stransky, David; Fencl, Martin; Bares, Vojtech

2018-05-01

Rainfall spatio-temporal distribution is of great concern for rainfall-runoff modellers. Standard rainfall observations are, however, often scarce and/or expensive to obtain. Thus, rainfall observations from non-traditional sensors such as commercial microwave links (CMLs) represent a promising alternative. In this paper, rainfall observations from a municipal rain gauge (RG) monitoring network were complemented by CMLs and used as an input to a standard urban drainage model operated by the water utility of the Tabor agglomeration (CZ). Two rainfall datasets were used for runoff predictions: (i) the municipal RG network, i.e. the observation layout used by the water utility, and (ii) CMLs adjusted by the municipal RGs. The performance was evaluated in terms of runoff volumes and hydrograph shapes. The use of CMLs did not lead to distinctively better predictions in terms of runoff volumes; however, CMLs outperformed RGs used alone when reproducing a hydrograph's dynamics (peak discharges, Nash-Sutcliffe coefficient and hydrograph's rising limb timing). This finding is promising for number of urban drainage tasks working with dynamics of the flow. Moreover, CML data can be obtained from a telecommunication operator's data cloud at virtually no cost. That makes their use attractive for cities unable to improve their monitoring infrastructure for economic or organizational reasons.

Sources and routing of the Amazon River Flood Wave

NASA Astrophysics Data System (ADS)

Richey, Jeffrey E.; Mertes, Leal A. K.; Dunne, Thomas; Victoria, Reynaldo L.; Forsberg, Bruce R.; Tancredi, AntôNio C. N. S.; Oliveira, Eurides

1989-09-01

We describe the sources and routing of the Amazon River flood wave through a 2000-km reach of the main channel, between São Paulo de Olivença and Obidos, Brazil. The damped hydrograph of the main stem reflects the large drainage basin area, the 3-month phase lag in peak flows between the north and south draining tributaries due to seasonal differences in precipitation, and the large volume of water stored on the floodplain. We examined several aspects of the valley floor hydrology that are important for biogeochemistry. These include volumes of water storage in the channel and the floodplain and the rates of transfer between these two storage elements at various seasons and in each segment of the valley. We estimate that up to 30% of the water in the main stem is derived from water that has passed through the floodplain. To predict the discharge at any cross section within the study reach, we used the Muskingum formula to predict the hydrograph at downriver cross sections from a known hydrograph at upstream cross-sections and inputs and outputs along each reach. The model was calibrated using three years of data and was successfully tested against an additional six years of data. With this model it is possible to interpolate discharges for unsampled times and sites.

Investigating hydraulic connections and the origin of water in a mine tunnel using stable isotopes and hydrographs

USGS Publications Warehouse

Walton-Day, K.; Poeter, E.

2009-01-01

Turquoise Lake is a water-supply reservoir located north of the historic Sugarloaf Mining district near Leadville, Colorado, USA. Elevated water levels in the reservoir may increase flow of low-quality water from abandoned mine tunnels in the Sugarloaf District and degrade water quality downstream. The objective of this study was to understand the sources of water to Dinero mine drainage tunnel and evaluate whether or not there was a direct hydrologic connection between Dinero mine tunnel and Turquoise Lake from late 2002 to early 2008. This study utilized hydrograph data from nearby draining mine tunnels and the lake, and stable isotope (??18O and ??2H) data from the lake, nearby draining mine tunnels, imported water, and springs to characterize water sources in the study area. Hydrograph results indicate that flow from the Dinero mine tunnel decreased 26% (2006) and 10% (2007) when lake elevation (above mean sea level) decreased below approximately 3004 m (approximately 9855 feet). Results of isotope analysis delineated two meteoric water lines in the study area. One line characterizes surface water and water imported to the study area from the western side of the Continental Divide. The other line characterizes groundwater including draining mine tunnels, springs, and seeps. Isotope mixing calculations indicate that water from Turquoise Lake or seasonal groundwater recharge from snowmelt represents approximately 10% or less of the water in Dinero mine tunnel. However, most of the water in Dinero mine tunnel is from deep groundwater having minimal isotopic variation. The asymmetric shape of the Dinero mine tunnel hydrograph may indicate that a limited mine pool exists behind a collapse in the tunnel and attenutates seasonal recharge. Alternatively, a conceptual model is presented (and supported with MODFLOW simulations) that is consistent with current and previous data collected in the study area, and illustrates how fluctuating lake levels change the local water-table elevation which can affect discharge from the Dinero mine tunnel without physical transfer of water between the two locations.

Investigating hydraulic connections and the origin of water in a mine tunnel using stable isotopes and hydrographs

USGS Publications Warehouse

Walton-Day, Katherine; Poeter, Eileen

2009-01-01

Turquoise Lake is a water-supply reservoir located north of the historic Sugarloaf Mining district near Leadville, Colorado, USA. Elevated water levels in the reservoir may increase flow of low-quality water from abandoned mine tunnels in the Sugarloaf District and degrade water quality downstream. The objective of this study was to understand the sources of water to Dinero mine drainage tunnel and evaluate whether or not there was a direct hydrologic connection between Dinero mine tunnel and Turquoise Lake from late 2002 to early 2008. This study utilized hydrograph data from nearby draining mine tunnels and the lake, and stable isotope (δ18O and δ2H) data from the lake, nearby draining mine tunnels, imported water, and springs to characterize water sources in the study area. Hydrograph results indicate that flow from the Dinero mine tunnel decreased 26% (2006) and 10% (2007) when lake elevation (above mean sea level) decreased below approximately 3004 m (approximately 9855 feet). Results of isotope analysis delineated two meteoric water lines in the study area. One line characterizes surface water and water imported to the study area from the western side of the Continental Divide. The other line characterizes groundwater including draining mine tunnels, springs, and seeps. Isotope mixing calculations indicate that water from Turquoise Lake or seasonal groundwater recharge from snowmelt represents approximately 10% or less of the water in Dinero mine tunnel. However, most of the water in Dinero mine tunnel is from deep groundwater having minimal isotopic variation. The asymmetric shape of the Dinero mine tunnel hydrograph may indicate that a limited mine pool exists behind a collapse in the tunnel and attenutates seasonal recharge. Alternatively, a conceptual model is presented (and supported with MODFLOW simulations) that is consistent with current and previous data collected in the study area, and illustrates how fluctuating lake levels change the local water-table elevation which can affect discharge from the Dinero mine tunnel without physical transfer of water between the two locations.

Use of Multi-class Empirical Orthogonal Function for Identification of Hydrogeological Parameters and Spatiotemporal Pattern of Multiple Recharges in Groundwater Modeling

NASA Astrophysics Data System (ADS)

Huang, C. L.; Hsu, N. S.; Yeh, W. W. G.; Hsieh, I. H.

2017-12-01

This study develops an innovative calibration method for regional groundwater modeling by using multi-class empirical orthogonal functions (EOFs). The developed method is an iterative approach. Prior to carrying out the iterative procedures, the groundwater storage hydrographs associated with the observation wells are calculated. The combined multi-class EOF amplitudes and EOF expansion coefficients of the storage hydrographs are then used to compute the initial gauss of the temporal and spatial pattern of multiple recharges. The initial guess of the hydrogeological parameters are also assigned according to in-situ pumping experiment. The recharges include net rainfall recharge and boundary recharge, and the hydrogeological parameters are riverbed leakage conductivity, horizontal hydraulic conductivity, vertical hydraulic conductivity, storage coefficient, and specific yield. The first step of the iterative algorithm is to conduct the numerical model (i.e. MODFLOW) by the initial guess / adjusted values of the recharges and parameters. Second, in order to determine the best EOF combination of the error storage hydrographs for determining the correction vectors, the objective function is devised as minimizing the root mean square error (RMSE) of the simulated storage hydrographs. The error storage hydrograph are the differences between the storage hydrographs computed from observed and simulated groundwater level fluctuations. Third, adjust the values of recharges and parameters and repeat the iterative procedures until the stopping criterion is reached. The established methodology was applied to the groundwater system of Ming-Chu Basin, Taiwan. The study period is from January 1st to December 2ed in 2012. Results showed that the optimal EOF combination for the multiple recharges and hydrogeological parameters can decrease the RMSE of the simulated storage hydrographs dramatically within three calibration iterations. It represents that the iterative approach that using EOF techniques can capture the groundwater flow tendency and detects the correction vector of the simulated error sources. Hence, the established EOF-based methodology can effectively and accurately identify the multiple recharges and hydrogeological parameters.

Hydrograph Shape Controls Channel Morphology and Organization in a Sand-Gravel Flume

NASA Astrophysics Data System (ADS)

Hempel, L. A.; Grant, G.; Hassan, M. A.; Eaton, B. C.

2016-12-01

A fundamental research question in fluvial geomorphology is to understand what flows shape river channels. Historically, the prevailing view has been that channel dimensions adjust to a so-termed "dominant discharge", which is often approximated as the bankfull flow. But using a single flow to reference the geomorphic effectiveness of an entire flow regime discounts many observations showing that different flows control different channel processes. Some flows entrain fine sediment, some entrain the full size distribution of bed sediment; some destabilize or build bars, some erode the banks, and so forth. To explore the relation between the full flow regime and channel morphology, we conducted a series of flume experiments to examine how hydrographs with different shapes, durations, and magnitudes result in different degrees of channel organization, which we define in terms of the regularity, spacing and architecture of self-formed channel features, such as bed patches, geometry and spacing of bedforms, and channel planform. Our experiments were run in a 12m long adjustable-width flume that developed a self-formed meandering, pool-riffle pattern. We found that hydrograph shape does control channel organization. In particular, channels formed by hydrographs with slower rising limbs and broader peaks were more organized than those formed by flashier hydrographs. To become organized, hydrographs needed to exceed a minimum flow threshold, defined by the intensity of sediment transport; below which the channel lacked bedforms and a regular meander pattern. Above an upper flow threshold, bars became disorganized and the channel planform transitioned towards braiding. Field studies of channels with different flow regimes but located in a similar physiographic setting support our experimental findings. Taken together, this work points to the importance of the hydrograph as a fundamental control on channel morphology, and offers the prospect of better understanding how changing hydrologic regimes, either through climate, land use, or dams, translates into geomorphic changes.

Hydrographic surveys of four narrows within the Namakan reservoir system, Voyageurs National Park, Minnesota, 2011

USGS Publications Warehouse

Densmore, Brenda K.; Strauch, Kellan R.; Ziegeweid, Jeffrey R.

2013-01-01

The U.S. Geological Survey performed multibeam echosounder hydrographic surveys of four narrows in the Namakan reservoir system in August 2011, in cooperation with the International Joint Commission and Environment Canada. The data-collection effort was completed to provide updated and detailed hydrographic data to Environment Canada for inclusion in a Hydrologic Engineering Centers River Analysis System hydraulic model. The Namakan reservoir system is composed of Namakan, Kabetogama, Sand Point, Crane, and Little Vermilion Lakes. Water elevations in the Namakan reservoir system are regulated according to rule curves, or guidelines for water-level management based on the time of year, established by the International Joint Commission. Water levels are monitored by established gages on Crane Lake and the outlet of Namakan Lake at Kettle Falls, but water elevations throughout the system may deviate from these measured values by as much as 0.3 meters, according to lake managers and residents. Deviations from expected water elevations may be caused by between-lake constrictions (narrows). According to the 2000 Rule Curve Assessment Workgroup, hydrologic models of the reservoir system are needed to better understand the system and to evaluate the recent changes made to rule curves in 2000. Hydrographic surveys were performed using a RESON SeaBat™7125 multibeam echosounder system. Surveys were completed at Namakan Narrows, Harrison Narrows, King Williams Narrows, and Little Vermilion Narrows. Hydrographic survey data were processed using Caris HIPSTM and SIPSTM software that interpolated a combined uncertainty and bathymetric estimator (CUBE) surface. Quality of the survey results was evaluated in relation to standards set by the International Hydrographic Organization (IHO) for describing the uncertainty of hydrographic surveys. More than 90 percent of the surveyed areas at the four narrows have resulting bed elevations that meet the IHO “Special Order” quality. Survey datasets published in this report are formatted as text files of x-y-z coordinates and as CARIS Spatial ArchiveTM (CSARTM) files with corresponding metadata.

40 CFR 81.329 - Nevada.

Code of Federal Regulations, 2011 CFR

2011-07-01

... classified Better than national standards (Township Range): Clark County: Las Vegas Valley (212)(15-24S, 56... County refers to 27 hydrographic areas either entirely or partially located within Clark County as shown... (September 1971), excluding the two designated areas in Clark County specifically listed in the table. Nevada...

Nanoscale wicking methods and devices

NASA Technical Reports Server (NTRS)

Zhou, Jijie (Inventor); Bronikowski, Michael (Inventor); Noca, Flavio (Inventor); Sansom, Elijah B. (Inventor)

2011-01-01

A fluid transport method and fluid transport device are disclosed. Nanoscale fibers disposed in a patterned configuration allow transport of a fluid in absence of an external power source. The device may include two or more fluid transport components having different fluid transport efficiencies. The components may be separated by additional fluid transport components, to control fluid flow.

15 CFR 995.10 - Correspondence and applications.

Code of Federal Regulations, 2012 CFR

2012-01-01

... CERTIFICATION REQUIREMENTS FOR NOAA HYDROGRAPHIC PRODUCTS AND SERVICES CERTIFICATION REQUIREMENTS FOR DISTRIBUTORS OF NOAA HYDROGRAPHIC PRODUCTS Certification and Procedures § 995.10 Correspondence and applications. (a) Distributors or value-added distributors desiring certification from NOAA shall provide a...

15 CFR 995.10 - Correspondence and applications.

Code of Federal Regulations, 2014 CFR

2014-01-01

... CERTIFICATION REQUIREMENTS FOR NOAA HYDROGRAPHIC PRODUCTS AND SERVICES CERTIFICATION REQUIREMENTS FOR DISTRIBUTORS OF NOAA HYDROGRAPHIC PRODUCTS Certification and Procedures § 995.10 Correspondence and applications. (a) Distributors or value-added distributors desiring certification from NOAA shall provide a...

15 CFR 995.10 - Correspondence and applications.

Code of Federal Regulations, 2011 CFR

2011-01-01

... CERTIFICATION REQUIREMENTS FOR NOAA HYDROGRAPHIC PRODUCTS AND SERVICES CERTIFICATION REQUIREMENTS FOR DISTRIBUTORS OF NOAA HYDROGRAPHIC PRODUCTS Certification and Procedures § 995.10 Correspondence and applications. (a) Distributors or value-added distributors desiring certification from NOAA shall provide a...

15 CFR 995.10 - Correspondence and applications.

Code of Federal Regulations, 2013 CFR

2013-01-01

... CERTIFICATION REQUIREMENTS FOR NOAA HYDROGRAPHIC PRODUCTS AND SERVICES CERTIFICATION REQUIREMENTS FOR DISTRIBUTORS OF NOAA HYDROGRAPHIC PRODUCTS Certification and Procedures § 995.10 Correspondence and applications. (a) Distributors or value-added distributors desiring certification from NOAA shall provide a...

15 CFR 996.4 - Liability.

Code of Federal Regulations, 2010 CFR

2010-01-01

... AND ATMOSPHERIC ADMINISTRATION, DEPARTMENT OF COMMERCE QUALITY ASSURANCE AND CERTIFICATION REQUIREMENTS FOR NOAA HYDROGRAPHIC PRODUCTS AND SERVICES QUALITY ASSURANCE AND CERTIFICATION REQUIREMENTS FOR NOAA HYDROGRAPHIC PRODUCTS AND SERVICES General § 996.4 Liability. The Government of the United States...

15 CFR 995.10 - Correspondence and applications.

Code of Federal Regulations, 2010 CFR

2010-01-01

... CERTIFICATION REQUIREMENTS FOR NOAA HYDROGRAPHIC PRODUCTS AND SERVICES CERTIFICATION REQUIREMENTS FOR DISTRIBUTORS OF NOAA HYDROGRAPHIC PRODUCTS Certification and Procedures § 995.10 Correspondence and applications. (a) Distributors or value-added distributors desiring certification from NOAA shall provide a...

User's guide for a general purpose dam-break flood simulation model (K-634)

USGS Publications Warehouse

Land, Larry F.

1981-01-01

An existing computer program for simulating dam-break floods for forecast purposes has been modified with an emphasis on general purpose applications. The original model was formulated, developed and documented by the National Weather Service. This model is based on the complete flow equations and uses a nonlinear implicit finite-difference numerical method. The first phase of the simulation routes a flood wave through the reservoir and computes an outflow hydrograph which is the sum of the flow through the dam 's structures and the gradually developing breach. The second phase routes this outflow hydrograph through the stream which may be nonprismatic and have segments with subcritical or supercritical flow. The results are discharge and stage hydrographs at the dam as well as all of the computational nodes in the channel. From these hydrographs, peak discharge and stage profiles are tabulated. (USGS)

On applications of chimera grid schemes to store separation

NASA Technical Reports Server (NTRS)

Cougherty, F. C.; Benek, J. A.; Steger, J. L.

1985-01-01

A finite difference scheme which uses multiple overset meshes to simulate the aerodynamics of aircraft/store interaction and store separation is described. In this chimera, or multiple mesh, scheme, a complex configuration is mapped using a major grid about the main component of the configuration, and minor overset meshes are used to map each additional component such as a store. As a first step in modeling the aerodynamics of store separation, two dimensional inviscid flow calculations were carried out in which one of the minor meshes is allowed to move with respect to the major grid. Solutions of calibrated two dimensional problems indicate that allowing one mesh to move with respect to another does not adversely affect the time accuracy of an unsteady solution. Steady, inviscid three dimensional computations demonstrate the capability to simulate complex configurations, including closely packed multiple bodies.

Bathymetry and oceanic flow structure at two deep passages crossing the Lomonosov Ridge

NASA Astrophysics Data System (ADS)

Björk, Göran; Jakobsson, Martin; Assmann, Karen; Andersson, Leif G.; Nilsson, Johan; Stranne, Christian; Mayer, Larry

2018-01-01

The Lomonosov Ridge represents a major topographical feature in the Arctic Ocean which has a large effect on the water circulation and the distribution of water properties. This study presents detailed bathymetric survey data along with hydrographic data at two deep passages across the ridge: a southern passage (80-81° N), where the ridge crest meets the Siberian continental slope, and a northern passage around 84.5° N. The southern channel is characterized by smooth and flat bathymetry around 1600-1700 m with a sill depth slightly shallower than 1700 m. A hydrographic section across the channel reveals an eastward flow with Amundsen Basin properties in the southern part and a westward flow of Makarov Basin properties in the northern part. The northern passage includes an approximately 72 km long and 33 km wide trough which forms an intra-basin in the Lomonosov Ridge morphology (the Oden Trough). The eastern side of the Oden Trough is enclosed by a narrow and steep ridge rising 500-600 m above a generally 1600 m deep trough bottom. The deepest passage (the sill) is 1470 m deep and located on this ridge. Hydrographic data show irregular temperature and salinity profiles indicating that water exchange occurs as midwater intrusions bringing water properties from each side of the ridge in well-defined but irregular layers. There is also morphological evidence that some rather energetic flows may occur in the vicinity of the sill. A well expressed deepening near the sill may be the result of seabed erosion by bottom currents.

Eogenetic karst hydrology: Insights from the 2004 hurricanes, peninsular Florida

USGS Publications Warehouse

Florea, L.J.; Vacher, H. Leonard

2007-01-01

Eogenetic karst lies geographically and temporally close to the depositional environment of limestone in warm marine water at low latitude, in areas marked by midafternoon thunderstorms during a summer rainy season. Spring hydrographs from such an environment in north-central Florida are characterized by smooth, months-long, seasonal maxima. The passage of Hurricanes Frances and Jeanne in September 2004 over three field locations shows how the eogenetic karst of the Upper Floridan Aquifer responds to unequivocal recharge events. Hydrographs at wells in the High Springs area, Rainbow Springs, and at Morris, Briar, and Bat Caves all responded promptly with a similar drawn-out rise to a maximum that extended long into the winter dry season. The timing indicates that the typical hydrograph of eogenetic karst is not the short-term fluctuations of springs in epigenic, telogenetic karst, or the smoothed response to all the summer thunderstorms, but rather the protracted response of the system to rainfall that exceeds a threshold. The similarity of cave and noncave hydrographs indicates distributed autogenic recharge and a free communication between secondary porosity and permeable matrix - both of which differ from the hydrology of epigenic, telogenetic karst. At Briar Cave, drip rates lagged behind the water table rise, suggesting that recharge was delivered by fractures, which control the cave's morphology. At High Springs, hydrographs at the Santa Fe River and a submerged conduit apparently connected to it show sharp maxima after the storms, unlike the other cave hydrographs. Our interpretation is that the caves, in general, are discontinuous. ?? 2007 National Ground Water Association.

A computer program for predicting recharge with a master recession curve

USGS Publications Warehouse

Heppner, Christopher S.; Nimmo, John R.

2005-01-01

Water-table fluctuations occur in unconfined aquifers owing to ground-water recharge following precipitation and infiltration, and ground-water discharge to streams between storm events. Ground-water recharge can be estimated from well hydrograph data using the water-table fluctuation (WTF) principle, which states that recharge is equal to the product of the water-table rise and the specific yield of the subsurface porous medium. The water-table rise, however, must be expressed relative to the water level that would have occurred in the absence of recharge. This requires a means for estimating the recession pattern of the water-table at the site. For a given site there is often a characteristic relation between the water-table elevation and the water-table decline rate following a recharge event. A computer program was written which extracts the relation between decline rate and water-table elevation from well hydrograph data and uses it to construct a master recession curve (MRC). The MRC is a characteristic water-table recession hydrograph, representing the average behavior for a declining water-table at that site. The program then calculates recharge using the WTF method by comparing the measured well hydrograph with the hydrograph predicted by the MRC and multiplying the difference at each time step by the specific yield. This approach can be used to estimate recharge in a continuous fashion from long-term well records. Presented here is a description of the code including the WTF theory and instructions for running it to estimate recharge with continuous well hydrograph data.

Separation of the pace-maker and plateau components of delayed rectification in cardiac Purkinje fibres

PubMed Central

Hauswirth, O.; Noble, D.; Tsien, R. W.

1972-01-01

1. Experiments on sheep Purkinje fibres were designed to determine whether the current mechanisms responsible for delayed rectification at the pace-maker (negative to -50 mV) and plateau (positive to -50 mV) ranges of potential are kinetically separable and independent. 2. Hyperpolarizations from the plateau range were shown to produce decay of a single component of outward current within the plateau range, but two components were evident when the hyperpolarizations entered the pace-maker range. 3. The time courses of recovery of the two components were too similar at -25 mV to allow temporal resolution at this potential. Clear temporal resolution was, however, possible at potentials between -55 and -95 mV. An indirect method of resolving the two components at -25 mV was used. 4. The kinetic properties of the two components correspond to those previously described for the pace-maker potassium current, iK2, and the outward plateau current, ix1 (Noble & Tsien, 1968, 1969a). 5. The instantaneous (fully activated) current—voltage relation for iK2 was reconstructed from the analysed current records. It was found that this relation shows a negative slope conductance at all potentials positive to -75 mV and that the current tends towards zero at zero membrane potential. 6. The results are compared with those predicted by two reaction models of the iK2 and ix1 mechanisms. It is concluded that iK2 and ix1 are kinetically separable but that it is not possible with present techniques to decide whether they are controlled by the same or completely independent membrane structures. It is also shown that the instantaneous current—voltage relation calculated for iK2 does not depend on whether the controlling mechanisms are assumed to be independent or linked. PMID:4679715

77 FR 76001 - Hydrographic Services Review Panel

Federal Register 2010, 2011, 2012, 2013, 2014

2012-12-26

... Review Panel AGENCY: National Ocean Service, National Oceanic and Atmospheric Administration (NOAA), Department of Commerce. ACTION: Notice of membership solicitation for Hydrographic Services Review Panel... Review Panel (HSRP). The HSRP, a Federal advisory committee, advises the Administrator on matters related...

15 CFR 996.3 - Fees.

Code of Federal Regulations, 2012 CFR

2012-01-01

... ATMOSPHERIC ADMINISTRATION, DEPARTMENT OF COMMERCE QUALITY ASSURANCE AND CERTIFICATION REQUIREMENTS FOR NOAA HYDROGRAPHIC PRODUCTS AND SERVICES QUALITY ASSURANCE AND CERTIFICATION REQUIREMENTS FOR NOAA HYDROGRAPHIC PRODUCTS AND SERVICES General § 996.3 Fees. NOAA may charge for its Quality Assurance Program activities...

15 CFR 996.3 - Fees.

Code of Federal Regulations, 2013 CFR

2013-01-01

... ATMOSPHERIC ADMINISTRATION, DEPARTMENT OF COMMERCE QUALITY ASSURANCE AND CERTIFICATION REQUIREMENTS FOR NOAA HYDROGRAPHIC PRODUCTS AND SERVICES QUALITY ASSURANCE AND CERTIFICATION REQUIREMENTS FOR NOAA HYDROGRAPHIC PRODUCTS AND SERVICES General § 996.3 Fees. NOAA may charge for its Quality Assurance Program activities...

15 CFR 996.3 - Fees.

Code of Federal Regulations, 2014 CFR

2014-01-01

... ATMOSPHERIC ADMINISTRATION, DEPARTMENT OF COMMERCE QUALITY ASSURANCE AND CERTIFICATION REQUIREMENTS FOR NOAA HYDROGRAPHIC PRODUCTS AND SERVICES QUALITY ASSURANCE AND CERTIFICATION REQUIREMENTS FOR NOAA HYDROGRAPHIC PRODUCTS AND SERVICES General § 996.3 Fees. NOAA may charge for its Quality Assurance Program activities...

15 CFR 996.3 - Fees.

Code of Federal Regulations, 2011 CFR

2011-01-01

... ATMOSPHERIC ADMINISTRATION, DEPARTMENT OF COMMERCE QUALITY ASSURANCE AND CERTIFICATION REQUIREMENTS FOR NOAA HYDROGRAPHIC PRODUCTS AND SERVICES QUALITY ASSURANCE AND CERTIFICATION REQUIREMENTS FOR NOAA HYDROGRAPHIC PRODUCTS AND SERVICES General § 996.3 Fees. NOAA may charge for its Quality Assurance Program activities...

15 CFR 996.3 - Fees.

Code of Federal Regulations, 2010 CFR

2010-01-01

... ATMOSPHERIC ADMINISTRATION, DEPARTMENT OF COMMERCE QUALITY ASSURANCE AND CERTIFICATION REQUIREMENTS FOR NOAA HYDROGRAPHIC PRODUCTS AND SERVICES QUALITY ASSURANCE AND CERTIFICATION REQUIREMENTS FOR NOAA HYDROGRAPHIC PRODUCTS AND SERVICES General § 996.3 Fees. NOAA may charge for its Quality Assurance Program activities...

15 CFR 996.1 - Purpose and scope.

Code of Federal Regulations, 2010 CFR

2010-01-01

... AND ATMOSPHERIC ADMINISTRATION, DEPARTMENT OF COMMERCE QUALITY ASSURANCE AND CERTIFICATION REQUIREMENTS FOR NOAA HYDROGRAPHIC PRODUCTS AND SERVICES QUALITY ASSURANCE AND CERTIFICATION REQUIREMENTS FOR NOAA HYDROGRAPHIC PRODUCTS AND SERVICES General § 996.1 Purpose and scope. The National Oceanic and...

78 FR 23909 - Hydrographic Services Review Panel Meeting

Federal Register 2010, 2011, 2012, 2013, 2014

2013-04-23

... DEPARTMENT OF COMMERCE National Oceanic and Atmospheric Administration Hydrographic Services... (NOAA), Department of Commerce. ACTION: Notice of open meeting (via webinar and teleconference). SUMMARY... the Under Secretary of Commerce for Oceans and Atmosphere on matters related to the responsibilities...

Multicomponent Separation Potential. Generalization of the Dirac Theory

NASA Astrophysics Data System (ADS)

Palkin, V. A.; Gadel‧shin, V. M.; Aleksandrov, O. E.; Seleznev, V. D.

2014-05-01

Formulas for the separation potential and the separative power have been obtained in the present work by generalizing the classical theory of Dirac, with the observance of his two axioms, to the case of a multicomponent mixture without considering a concrete cascade scheme. The resulting expressions are general characteristics of a separation process, since they are applicable to any separation methods and are independentof the form of the components in the mixture. They can be used in constructing actual cascades for separation of multicomponent mixtures and in determining the indices of their effi ciency.

Seasonal cycle of the mixed-layer heat and freshwater budget in the eastern tropical Atlantic

NASA Astrophysics Data System (ADS)

Rath, Willi; Dengler, Marcus; Lüdke, Jan; Schmidtko, Sunke; Schlundt, Michael; Brandt, Peter; Partners, Preface

2016-04-01

A new seasonal mixed-layer heat flux climatology is used to explore the mechanisms driving seasonal variability of sea surface temperature and salinity in the eastern tropical Atlantic (ETA) with a focus on the eastern boundary upwelling regions. Until recently, large areas at the continental margins of the ETA were not well covered by publically available hydrographic data hampering a detailed understanding of the involved processes. In a collaborative effort between African and European partners within the EU-funded PREFACE program, a new seasonal climatology for different components of the heat and freshwater budget was compiled for the ETA using all publically available hydrographic data sets and a large trove of previously not-publically available hydrographic measurements from the territorial waters of western African countries, either from national programs or from the FAO supported EAF-Nansen program. The publically available data includes hydrographic data from global data repositories including most recent ARGO floats and glider measurements. This data set was complemented by velocity data from surface drifter and ARGO floats to allow determining horizontal heat and freshwater advection. Monthly means of air-sea heat fluxes were derived from the TropFlux climatology while precipitation rates were derived from monthly mean fields of the Global Precipitation Climatology Project. Finally, microstructure data from individual measurement campaigns allow estimating diapycnal heat and salt fluxes for certain regions during specific months. A detailed analysis of the seasonal cycle of mixed-layer heat and freshwater balance in previously poorly covered regions in the eastern tropical Atlantic upwelling is presented. In both eastern boundary upwelling region, off Senegal/Mauritania and off Angola/Namibia, average net surface heat fluxes warm the mixed layer at a rate between 50 and 80 W/m2 with maxima in the respective summer seasons. Horizontal advection contributed to cooling of the mixed layer but a residual cooling term remains in both upwelling regions. A surprising result is that this residual is largest in the Angolan upwelling region, where upwelling-favourable winds are generally weaker than off Namibia and in the north-eastern upwelling region. The contributions of windstress-derived vertical advection and diapycnal heat and freshwater fluxes are discussed. In addition, the TropFlux climatology is evaluated against radiative and turbulent ocean-atmosphere heat and freshwater fluxes derived from ship-board observations.

Examining the effects of forest thinning on runoff responses at different catchments scales in forested headwaters

NASA Astrophysics Data System (ADS)

Dung, B. X.; Gomi, T.; Onda, Y.; Kato, H.; Hiraoka, M.

2012-12-01

We conducted field observation in nested headwater catchments draining Japanese cypress (Chamaecyparis obtusa) and cedar (Cryptomeria japonica) forests at Tochigi prefectures for examining the effects of forest thinning on runoff generation at different catchment scales. 50% of the stems was removed with line thinning in catchment K2 (treatment catchment), while catchment K3 remained untreated as a control. We also monitored nested catchments within K2-1 (17.1 ha) as K2-2 (10.2 ha), K2-3 (3.7 ha) and K2-4 (5.1 ha), and within K3-1 (8.9 ha) as K3-2 (3.0 ha). Runoff from the catchments was monitored during the pre-thinning (from April, 2010 to May 2011), and the post-thinning periods (from June 2011 to July 2012). Paired-catchment and hydrograph separation analysis were used to evaluate the effects of forest thinning on runoff generation at different catchment scales. We developed the pre-thinning calibration equation for predicting post-thinning responses. Paired-catchment analysis revealed that annual catchment runoff increased 648 mm in K2-1, 414 mm in K2-2, 517 mm in K2-3 and 487 mm in K2-4 after the thinning. Both quick and delayed runoff components only increased significantly in the larger catchments of K2-1 and K2-2, while only delayed runoff components of smaller catchments (K2-3 and K2-4) increased significantly during the post-thinning period. Increases of quick runoff in large catchments could be associated with quick runoff response to soil surface compaction by line thinning and skid trail installation. Increases of delayed runoff in small catchment may be associated with increase in net precipitation and decrease in evapotranspiration. Our finding showed that changes in internal hydrological flow pathways and associated changes in runoff components due to forest harvesting differ depending on the catchment sizes.

Schema vs. primitive perceptual grouping: the relative weighting of sequential vs. spatial cues during an auditory grouping task in frogs.

PubMed

Farris, Hamilton E; Ryan, Michael J

2017-03-01

Perceptually, grouping sounds based on their sources is critical for communication. This is especially true in túngara frog breeding aggregations, where multiple males produce overlapping calls that consist of an FM 'whine' followed by harmonic bursts called 'chucks'. Phonotactic females use at least two cues to group whines and chucks: whine-chuck spatial separation and sequence. Spatial separation is a primitive cue, whereas sequence is schema-based, as chuck production is morphologically constrained to follow whines, meaning that males cannot produce the components simultaneously. When one cue is available, females perceptually group whines and chucks using relative comparisons: components with the smallest spatial separation or those closest to the natural sequence are more likely grouped. By simultaneously varying the temporal sequence and spatial separation of a single whine and two chucks, this study measured between-cue perceptual weighting during a specific grouping task. Results show that whine-chuck spatial separation is a stronger grouping cue than temporal sequence, as grouping is more likely for stimuli with smaller spatial separation and non-natural sequence than those with larger spatial separation and natural sequence. Compared to the schema-based whine-chuck sequence, we propose that spatial cues have less variance, potentially explaining their preferred use when grouping during directional behavioral responses.

Alternative polymer separation technology by centrifugal force in a melted state.

PubMed

Dobrovszky, Károly; Ronkay, Ferenc

2014-11-01

In order to upgrade polymer waste during recycling, separation should take place at high purity. The present research was aimed to develop a novel, alternative separation opportunity, where the polymer fractions were separated by centrifugal force in melted state. The efficiency of the constructed separation equipment was verified by two immiscible plastics (polyethylene terephthalate, PET; low density polyethylene, LDPE), which have a high difference of density, and of which large quantities can also be found in the municipal solid waste. The results show that the developed equipment is suitable not only for separating dry blended mixtures of PET/LDPE into pure components again, but also for separating prefabricated polymer blends. By this process it becomes possible to recover pure polymer substances from multi-component products during the recycling process. The adequacy of results was verified by differential scanning calorimetry (DSC) measurement as well as optical microscopy and Raman spectroscopy. Copyright © 2014 Elsevier Ltd. All rights reserved.

Groundwater discharge in high-mountain watersheds: A valuable resource for downstream semi-arid zones. The case of the Bérchules River in Sierra Nevada (Southern Spain).

PubMed

Jódar, Jorge; Cabrera, José Antonio; Martos-Rosillo, Sergio; Ruiz-Constán, Ana; González-Ramón, Antonio; Lambán, Luis Javier; Herrera, Christian; Custodio, Emilio

2017-09-01

Aquifers in permeable formations developed in high-mountain watersheds slow down the transfer of snowmelt to rivers, modifying rivers' flow pattern. To gain insight into the processes that control the hydrologic response of such systems the role played by groundwater in an alpine basin located at the southeastern part of the Iberian Peninsula is investigated. As data in these environments is generally scarce and its variability is high, simple lumped parameter hydrological models that consider the groundwater component and snow accumulation and melting are needed. Instead of using existing models that use many parameters, the Témez lumped hydrological model of common use in Spain and Ibero-American countries is selected and modified to consider snow to get a simplified tool to separate hydrograph components. The result is the TDD model (Témez-Degree Day) which is applied in a high mountain watershed with seasonal snow cover in Southern Spain to help in quantifying groundwater recharge and determining the groundwater contribution to the outflow. Average groundwater recharge is about 23% of the precipitation, and groundwater contribution to total outflow ranges between 70 and 97%. Direct surface runoff is 1% of precipitation. These values depend on the existence of snow. Results are consistent with those obtained with chloride atmospheric deposition mass balances by other authors. They highlight the important role of groundwater in high mountain areas, which is enhanced by seasonal snow cover. Results compare well with other areas. This effect is often neglected in water planning, but can be easily taken into account just by extending the water balance tool in use, or any other, following the procedure that has being developed. Copyright © 2017 Elsevier B.V. All rights reserved.

Dependence of the pour point of diesel fuels on the properties of the initial components

NASA Technical Reports Server (NTRS)

Ostashov, V. M.; Bobrovskiy, S. A.

1979-01-01

An analytical expression is obtained for the dependence of the pour point of diesel fuels on the pour point and weight relationship of the initial components. For determining the pour point of a multicomponent fuel mixture, it is assumed that the mixture of two components has the pour point of a separate equivalent component, then calculating the pour point of this equivalent component mixed with a third component, etc.

Ecological analysis of spatial and temporal patterns of pelagic ecosystem components potentially interacting with an OTEC (Ocean Thermal Energy Conversion) plant near Punta Tuna, Puerto Rico: physical characteristics. Final report

DOE Office of Scientific and Technical Information (OSTI.GOV)

Lopez, J.M.; Tilly, L.J.

1983-01-01

This hydrographic study characterizes the Punta Tuna area as a potential site for an OTEC power plant. Seven cruises were conducted at approximately two month intervals. Each cruise included at least 22 hydrocast stations, six done as serial stations in a small area to reveal temporal and small scale variability. The results of the analysis of these data so far indicate a bi-seasonality in the dynamics. Mesoscale eddies and meanders are a common feature of the circulation pattern on Puerto Rico's southern coast. The time series studies have shown their existence of a very energetic internal wave field with relativelymore » large amplitude waves at the diurnal and semi-diurnal tidal frequencies. The results in terms of an OTEC power plant indicate the thermal resource to be at least a 20C thermal gradient in the upper 100 m year round.« less

15 CFR 995.29 - Limitation on endorsements.

Code of Federal Regulations, 2013 CFR

2013-01-01

... REQUIREMENTS FOR NOAA HYDROGRAPHIC PRODUCTS AND SERVICES CERTIFICATION REQUIREMENTS FOR DISTRIBUTORS OF NOAA HYDROGRAPHIC PRODUCTS Requirements for Certified Distributors and Value Added Distributors of NOAA ENC Products § 995.29 Limitation on endorsements. By certifying compliance with this part, NOAA does not...

15 CFR 995.29 - Limitation on endorsements.

Code of Federal Regulations, 2014 CFR

2014-01-01

... REQUIREMENTS FOR NOAA HYDROGRAPHIC PRODUCTS AND SERVICES CERTIFICATION REQUIREMENTS FOR DISTRIBUTORS OF NOAA HYDROGRAPHIC PRODUCTS Requirements for Certified Distributors and Value Added Distributors of NOAA ENC Products § 995.29 Limitation on endorsements. By certifying compliance with this part, NOAA does not...

15 CFR 995.20 - General.

Code of Federal Regulations, 2014 CFR

2014-01-01

... REQUIREMENTS FOR NOAA HYDROGRAPHIC PRODUCTS AND SERVICES CERTIFICATION REQUIREMENTS FOR DISTRIBUTORS OF NOAA HYDROGRAPHIC PRODUCTS Requirements for Certified Distributors and Value Added Distributors of NOAA ENC Products § 995.20 General. The requirements for certification as a “Certified NOAA ENC Distributor” (CED) and...

15 CFR 995.20 - General.

Code of Federal Regulations, 2012 CFR

2012-01-01

... REQUIREMENTS FOR NOAA HYDROGRAPHIC PRODUCTS AND SERVICES CERTIFICATION REQUIREMENTS FOR DISTRIBUTORS OF NOAA HYDROGRAPHIC PRODUCTS Requirements for Certified Distributors and Value Added Distributors of NOAA ENC Products § 995.20 General. The requirements for certification as a “Certified NOAA ENC Distributor” (CED) and...

15 CFR 995.20 - General.

Code of Federal Regulations, 2013 CFR

2013-01-01

... REQUIREMENTS FOR NOAA HYDROGRAPHIC PRODUCTS AND SERVICES CERTIFICATION REQUIREMENTS FOR DISTRIBUTORS OF NOAA HYDROGRAPHIC PRODUCTS Requirements for Certified Distributors and Value Added Distributors of NOAA ENC Products § 995.20 General. The requirements for certification as a “Certified NOAA ENC Distributor” (CED) and...

15 CFR 995.29 - Limitation on endorsements.

Code of Federal Regulations, 2011 CFR

2011-01-01

... REQUIREMENTS FOR NOAA HYDROGRAPHIC PRODUCTS AND SERVICES CERTIFICATION REQUIREMENTS FOR DISTRIBUTORS OF NOAA HYDROGRAPHIC PRODUCTS Requirements for Certified Distributors and Value Added Distributors of NOAA ENC Products § 995.29 Limitation on endorsements. By certifying compliance with this part, NOAA does not...

15 CFR 995.20 - General.

Code of Federal Regulations, 2011 CFR

2011-01-01

... REQUIREMENTS FOR NOAA HYDROGRAPHIC PRODUCTS AND SERVICES CERTIFICATION REQUIREMENTS FOR DISTRIBUTORS OF NOAA HYDROGRAPHIC PRODUCTS Requirements for Certified Distributors and Value Added Distributors of NOAA ENC Products § 995.20 General. The requirements for certification as a “Certified NOAA ENC Distributor” (CED) and...

15 CFR 995.29 - Limitation on endorsements.

Code of Federal Regulations, 2012 CFR

2012-01-01

... REQUIREMENTS FOR NOAA HYDROGRAPHIC PRODUCTS AND SERVICES CERTIFICATION REQUIREMENTS FOR DISTRIBUTORS OF NOAA HYDROGRAPHIC PRODUCTS Requirements for Certified Distributors and Value Added Distributors of NOAA ENC Products § 995.29 Limitation on endorsements. By certifying compliance with this part, NOAA does not...

75 FR 59697 - Hydrographic Services Review Panel Meeting

Federal Register 2010, 2011, 2012, 2013, 2014

2010-09-28

... Health, Columbia River and Northwest Regional navigation and hydrographic surveying, climate change and... Review Panel Meeting AGENCY: National Ocean Service, National Oceanic and Atmospheric Administration... for Oceans and Atmosphere on matters related to the responsibilities and authorities set forth in...

15 CFR 996.33 - Acceptance of program by non-Federal entities.

Code of Federal Regulations, 2010 CFR

2010-01-01

... Trade (Continued) NATIONAL OCEANIC AND ATMOSPHERIC ADMINISTRATION, DEPARTMENT OF COMMERCE QUALITY ASSURANCE AND CERTIFICATION REQUIREMENTS FOR NOAA HYDROGRAPHIC PRODUCTS AND SERVICES QUALITY ASSURANCE AND CERTIFICATION REQUIREMENTS FOR NOAA HYDROGRAPHIC PRODUCTS AND SERVICES Other Quality Assurance Program Matters...

15 CFR 995.29 - Limitation on endorsements.

Code of Federal Regulations, 2010 CFR

2010-01-01

... REQUIREMENTS FOR NOAA HYDROGRAPHIC PRODUCTS AND SERVICES CERTIFICATION REQUIREMENTS FOR DISTRIBUTORS OF NOAA HYDROGRAPHIC PRODUCTS Requirements for Certified Distributors and Value Added Distributors of NOAA ENC Products § 995.29 Limitation on endorsements. By certifying compliance with this part, NOAA does not...

15 CFR 995.20 - General.

Code of Federal Regulations, 2010 CFR

2010-01-01

... REQUIREMENTS FOR NOAA HYDROGRAPHIC PRODUCTS AND SERVICES CERTIFICATION REQUIREMENTS FOR DISTRIBUTORS OF NOAA HYDROGRAPHIC PRODUCTS Requirements for Certified Distributors and Value Added Distributors of NOAA ENC Products § 995.20 General. The requirements for certification as a “Certified NOAA ENC Distributor” (CED) and...

On summer stratification and tidal mixing in the Taiwan Strait

NASA Astrophysics Data System (ADS)

Zhu, Jia; Hu, Jianyu; Liu, Zhiyu

2013-06-01

On continental shelves, a front that separates the sea into well-mixed and stratified zones is usually formed in warm seasons due to spatial variations of tidal mixing. In this paper, using eight years of in situ hydrographic observations, satellite images of sea surface temperature (SST) and chlorophyll- a (Chl- a) concentration, and results of a tidal model, we investigate summer stratification in the Taiwan Strait and its dependence on tidal mixing, upwelling, and river diluted water plumes. In most regions of the strait the dominant role of tidal mixing in determining the thermohaline structure is confirmed by the correlation between the two; there are some regions, however, where thermohaline structure varies in different ways owing to significant influences of upwelling and river diluted water plumes. The well-mixed regions are mainly distributed on the Taiwan Bank and in the offshore regions off the Dongshan Island, Nanao Island, and Pingtan Island, while the northern and central Taiwan Strait and the region south of the Taiwan Bank are stratified. The critical Simpson-Hunter parameter for the region is estimated to be 1.78.

Hydrographs Showing Groundwater Level Changes for Selected Wells in the Chambers-Clover Creek Watershed and Vicinity, Pierce County, Washington

USGS Publications Warehouse

Justin, G.B.; Julich, R.; Payne, K.L.

2009-01-01

Selected groundwater level hydrographs for the Chambers-Clover Creek watershed (CCCW) and vicinity, Washington, are presented in an interactive web-based map to illustrate changes in groundwater levels in and near the CCCW on a monthly and seasonal basis. Hydrographs are linked to points corresponding to the well location on an interactive map of the study area. Groundwater level data and well information from Federal, State, and local agencies were obtained from the U.S. Geological Survey National Water Information System (NWIS), Groundwater Site Inventory (GWSI) System.

Planetary camera observations of the double nucleus of M31

NASA Technical Reports Server (NTRS)

Lauer, Tod R.; Faber, S. M.; Groth, Edward J.; Shaya, Edward J.; Campbell, Bel; Code, Arthur; Currie, Douglas G.; Baum, William A.; Ewald, S. P.; Hester, J. J.

1993-01-01

HST Planetary Camera images obtained in the V and I band for M31 show its inner nucleus to consist of two components that are separated by 0.49 arcsec. The nuclear component with lower surface brightness closely coincides with the bulge photocenter and is argued to be at the kinematic center of the galaxy. It is surmised that, if dust absorption generates the asymmetric nuclear morphology observed, the dust grain size must either be exceptionally large, or the dust optical depth must be extremely high; the higher surface-brightness and off-center nuclear component may alternatively be a separate stellar system.

Vertical separation of the atmospheric aerosol components by using poliphon retrieval in polarized micro pulse lidar (P-MPL) measurements: case studies of specific climate-relevant aerosol types

NASA Astrophysics Data System (ADS)

Córdoba-Jabonero, Carmen; Sicard, Michaël; Ansmann, Albert; Águila, Ana del; Baars, Holger

2018-04-01

POLIPHON (POlarization-LIdar PHOtometer Networking) retrieval consists in the vertical separation of two/three particle components in aerosol mixtures, highlighting their relative contributions in terms of the optical properties and mass concentrations. This method is based on the specific particle linear depolarization ratio given for different types of aerosols, and is applied to the new polarized Micro-Pulse Lidar (P-MPL). Case studies of specific climate-relevant aerosols (dust particles, fire smoke, and pollen aerosols, including a clean case as reference) observed over Barcelona (Spain) are presented in order to evaluate firstly the potential of P-MPLs measurements in combination with POLIPHON for retrieving the vertical separation of those particle components forming aerosol mixtures and their properties.

Hybrid membrane--PSA system for separating oxygen from air

DOEpatents

Staiger, Chad L [Albuquerque, NM; Vaughn, Mark R [Albuquerque, NM; Miller, A Keith [Albuquerque, NM; Cornelius, Christopher J [Blackburg, VA

2011-01-25

A portable, non-cryogenic, oxygen generation system capable of delivering oxygen gas at purities greater than 98% and flow rates of 15 L/min or more is described. The system consists of two major components. The first component is a high efficiency membrane capable of separating argon and a portion of the nitrogen content from air, yielding an oxygen-enriched permeate flow. This is then fed to the second component, a pressure swing adsorption (PSA) unit utilizing a commercially available, but specifically formulated zeolite compound to remove the remainder of the nitrogen from the flow. The system is a unique gas separation system that can operate at ambient temperatures, for producing high purity oxygen for various applications (medical, refining, chemical production, enhanced combustion, fuel cells, etc . . . ) and represents a significant advance compared to current technologies.

[Determination of six main components in compound theophylline tablet by convolution curve method after prior separation by column partition chromatography

NASA Technical Reports Server (NTRS)

Zhang, S. Y.; Wang, G. F.; Wu, Y. T.; Baldwin, K. M. (Principal Investigator)

1993-01-01

On a partition chromatographic column in which the support is Kieselguhr and the stationary phase is sulfuric acid solution (2 mol/L), three components of compound theophylline tablet were simultaneously eluted by chloroform and three other components were simultaneously eluted by ammonia-saturated chloroform. The two mixtures were determined by computer-aided convolution curve method separately. The corresponding average recovery and relative standard deviation of the six components were as follows: 101.6, 1.46% for caffeine; 99.7, 0.10% for phenacetin; 100.9, 1.31% for phenobarbitone; 100.2, 0.81% for theophylline; 99.9, 0.81% for theobromine and 100.8, 0.48% for aminopyrine.

Thermal gravitational separation of ternary mixture n-dodecane/isobutylbenzene/tetralin components in a porous medium

NASA Astrophysics Data System (ADS)

Larabi, Mohamed Aziz; Mutschler, Dimitri; Mojtabi, Abdelkader

2016-06-01

Our present work focuses on the coupling between thermal diffusion and convection in order to improve the thermal gravitational separation of mixture components. The separation phenomenon was studied in a porous medium contained in vertical columns. We performed analytical and numerical simulations to corroborate the experimental measurements of the thermal diffusion coefficients of ternary mixture n-dodecane, isobutylbenzene, and tetralin obtained in microgravity in the international space station. Our approach corroborates the existing data published in the literature. The authors show that it is possible to quantify and to optimize the species separation for ternary mixtures. The authors checked, for ternary mixtures, the validity of the "forgotten effect hypothesis" established for binary mixtures by Furry, Jones, and Onsager. Two complete and different analytical resolution methods were used in order to describe the separation in terms of Lewis numbers, the separation ratios, the cross-diffusion coefficients, and the Rayleigh number. The analytical model is based on the parallel flow approximation. In order to validate this model, a numerical simulation was performed using the finite element method. From our new approach to vertical separation columns, new relations for mass fraction gradients and the optimal Rayleigh number for each component of the ternary mixture were obtained.

Platelet-rich plasma differs according to preparation method and human variability.

PubMed

Mazzocca, Augustus D; McCarthy, Mary Beth R; Chowaniec, David M; Cote, Mark P; Romeo, Anthony A; Bradley, James P; Arciero, Robert A; Beitzel, Knut

2012-02-15

Varying concentrations of blood components in platelet-rich plasma preparations may contribute to the variable results seen in recently published clinical studies. The purposes of this investigation were (1) to quantify the level of platelets, growth factors, red blood cells, and white blood cells in so-called one-step (clinically used commercial devices) and two-step separation systems and (2) to determine the influence of three separate blood draws on the resulting components of platelet-rich plasma. Three different platelet-rich plasma (PRP) separation methods (on blood samples from eight subjects with a mean age [and standard deviation] of 31.6 ± 10.9 years) were used: two single-spin processes (PRPLP and PRPHP) and a double-spin process (PRPDS) were evaluated for concentrations of platelets, red and white blood cells, and growth factors. Additionally, the effect of three repetitive blood draws on platelet-rich plasma components was evaluated. The content and concentrations of platelets, white blood cells, and growth factors for each method of separation differed significantly. All separation techniques resulted in a significant increase in platelet concentration compared with native blood. Platelet and white blood-cell concentrations of the PRPHP procedure were significantly higher than platelet and white blood-cell concentrations produced by the so-called single-step PRPLP and the so-called two-step PRPDS procedures, although significant differences between PRPLP and PRPDS were not observed. Comparing the results of the three blood draws with regard to the reliability of platelet number and cell counts, wide variations of intra-individual numbers were observed. Single-step procedures are capable of producing sufficient amounts of platelets for clinical usage. Within the evaluated procedures, platelet numbers and numbers of white blood cells differ significantly. The intra-individual results of platelet-rich plasma separations showed wide variations in platelet and cell numbers as well as levels of growth factors regardless of separation method.

Blind column selection protocol for two-dimensional high performance liquid chromatography.

PubMed

Burns, Niki K; Andrighetto, Luke M; Conlan, Xavier A; Purcell, Stuart D; Barnett, Neil W; Denning, Jacquie; Francis, Paul S; Stevenson, Paul G

2016-07-01

The selection of two orthogonal columns for two-dimensional high performance liquid chromatography (LC×LC) separation of natural product extracts can be a labour intensive and time consuming process and in many cases is an entirely trial-and-error approach. This paper introduces a blind optimisation method for column selection of a black box of constituent components. A data processing pipeline, created in the open source application OpenMS®, was developed to map the components within the mixture of equal mass across a library of HPLC columns; LC×LC separation space utilisation was compared by measuring the fractional surface coverage, fcoverage. It was found that for a test mixture from an opium poppy (Papaver somniferum) extract, the combination of diphenyl and C18 stationary phases provided a predicted fcoverage of 0.48 and was matched with an actual usage of 0.43. OpenMS®, in conjunction with algorithms designed in house, have allowed for a significantly quicker selection of two orthogonal columns, which have been optimised for a LC×LC separation of crude extractions of plant material. Copyright © 2016 Elsevier B.V. All rights reserved.

15 CFR 996.32 - Appeals.

Code of Federal Regulations, 2013 CFR

2013-01-01

... REQUIREMENTS FOR NOAA HYDROGRAPHIC PRODUCTS AND SERVICES QUALITY ASSURANCE AND CERTIFICATION REQUIREMENTS FOR NOAA HYDROGRAPHIC PRODUCTS AND SERVICES Other Quality Assurance Program Matters § 996.32 Appeals. (a... Coastal Zone Management, NOAA, using procedures to be established at the time of the appeal, and which...

15 CFR 995.6 - Fees.

Code of Federal Regulations, 2011 CFR

2011-01-01

... ATMOSPHERIC ADMINISTRATION, DEPARTMENT OF COMMERCE QUALITY ASSURANCE AND CERTIFICATION REQUIREMENTS FOR NOAA HYDROGRAPHIC PRODUCTS AND SERVICES CERTIFICATION REQUIREMENTS FOR DISTRIBUTORS OF NOAA HYDROGRAPHIC PRODUCTS General § 995.6 Fees. (a) The Office of Coast Survey, NOAA, may charge a fee for costs incurred to process...

15 CFR 996.32 - Appeals.

Code of Federal Regulations, 2011 CFR

2011-01-01

... REQUIREMENTS FOR NOAA HYDROGRAPHIC PRODUCTS AND SERVICES QUALITY ASSURANCE AND CERTIFICATION REQUIREMENTS FOR NOAA HYDROGRAPHIC PRODUCTS AND SERVICES Other Quality Assurance Program Matters § 996.32 Appeals. (a... Coastal Zone Management, NOAA, using procedures to be established at the time of the appeal, and which...

15 CFR 996.1 - Purpose and scope.

Code of Federal Regulations, 2014 CFR

2014-01-01

... REQUIREMENTS FOR NOAA HYDROGRAPHIC PRODUCTS AND SERVICES QUALITY ASSURANCE AND CERTIFICATION REQUIREMENTS FOR NOAA HYDROGRAPHIC PRODUCTS AND SERVICES General § 996.1 Purpose and scope. The National Oceanic and Atmospheric Administration (NOAA) was mandated to develop and implement a quality assurance program that is...

15 CFR 995.6 - Fees.

Code of Federal Regulations, 2013 CFR

2013-01-01

... ATMOSPHERIC ADMINISTRATION, DEPARTMENT OF COMMERCE QUALITY ASSURANCE AND CERTIFICATION REQUIREMENTS FOR NOAA HYDROGRAPHIC PRODUCTS AND SERVICES CERTIFICATION REQUIREMENTS FOR DISTRIBUTORS OF NOAA HYDROGRAPHIC PRODUCTS General § 995.6 Fees. (a) The Office of Coast Survey, NOAA, may charge a fee for costs incurred to process...

15 CFR 996.1 - Purpose and scope.

Code of Federal Regulations, 2011 CFR

2011-01-01

... REQUIREMENTS FOR NOAA HYDROGRAPHIC PRODUCTS AND SERVICES QUALITY ASSURANCE AND CERTIFICATION REQUIREMENTS FOR NOAA HYDROGRAPHIC PRODUCTS AND SERVICES General § 996.1 Purpose and scope. The National Oceanic and Atmospheric Administration (NOAA) was mandated to develop and implement a quality assurance program that is...

15 CFR 996.32 - Appeals.

Code of Federal Regulations, 2012 CFR

2012-01-01

... REQUIREMENTS FOR NOAA HYDROGRAPHIC PRODUCTS AND SERVICES QUALITY ASSURANCE AND CERTIFICATION REQUIREMENTS FOR NOAA HYDROGRAPHIC PRODUCTS AND SERVICES Other Quality Assurance Program Matters § 996.32 Appeals. (a... Coastal Zone Management, NOAA, using procedures to be established at the time of the appeal, and which...

15 CFR 996.1 - Purpose and scope.

Code of Federal Regulations, 2012 CFR

2012-01-01

... REQUIREMENTS FOR NOAA HYDROGRAPHIC PRODUCTS AND SERVICES QUALITY ASSURANCE AND CERTIFICATION REQUIREMENTS FOR NOAA HYDROGRAPHIC PRODUCTS AND SERVICES General § 996.1 Purpose and scope. The National Oceanic and Atmospheric Administration (NOAA) was mandated to develop and implement a quality assurance program that is...

15 CFR 995.6 - Fees.

Code of Federal Regulations, 2014 CFR

2014-01-01

... ATMOSPHERIC ADMINISTRATION, DEPARTMENT OF COMMERCE QUALITY ASSURANCE AND CERTIFICATION REQUIREMENTS FOR NOAA HYDROGRAPHIC PRODUCTS AND SERVICES CERTIFICATION REQUIREMENTS FOR DISTRIBUTORS OF NOAA HYDROGRAPHIC PRODUCTS General § 995.6 Fees. (a) The Office of Coast Survey, NOAA, may charge a fee for costs incurred to process...

15 CFR 996.1 - Purpose and scope.

Code of Federal Regulations, 2013 CFR

2013-01-01

... REQUIREMENTS FOR NOAA HYDROGRAPHIC PRODUCTS AND SERVICES QUALITY ASSURANCE AND CERTIFICATION REQUIREMENTS FOR NOAA HYDROGRAPHIC PRODUCTS AND SERVICES General § 996.1 Purpose and scope. The National Oceanic and Atmospheric Administration (NOAA) was mandated to develop and implement a quality assurance program that is...

15 CFR 995.6 - Fees.

Code of Federal Regulations, 2012 CFR

2012-01-01

... ATMOSPHERIC ADMINISTRATION, DEPARTMENT OF COMMERCE QUALITY ASSURANCE AND CERTIFICATION REQUIREMENTS FOR NOAA HYDROGRAPHIC PRODUCTS AND SERVICES CERTIFICATION REQUIREMENTS FOR DISTRIBUTORS OF NOAA HYDROGRAPHIC PRODUCTS General § 995.6 Fees. (a) The Office of Coast Survey, NOAA, may charge a fee for costs incurred to process...

15 CFR 996.32 - Appeals.

Code of Federal Regulations, 2014 CFR

2014-01-01

... REQUIREMENTS FOR NOAA HYDROGRAPHIC PRODUCTS AND SERVICES QUALITY ASSURANCE AND CERTIFICATION REQUIREMENTS FOR NOAA HYDROGRAPHIC PRODUCTS AND SERVICES Other Quality Assurance Program Matters § 996.32 Appeals. (a... Coastal Zone Management, NOAA, using procedures to be established at the time of the appeal, and which...

Methods of Hydrographic Surveying Used by Different Countries.

DTIC Science & Technology

1983-03-01

902 Greece 16. Training and Education Division Hellenic Navy General Staff GENIKO EPITELIO NAYTIKOY (GEN) Greece 17. Hellenic Naval Academy SHOLI...Maratos Hellenic Navy Hydrographic Service Athens BST 902 Greece 21. Hellenic Army Geographic Service V. GENIKO EPITELIO STRATOU Athens, Greece 22. LT

15 CFR 996.30 - Use of the NOAA emblem.

Code of Federal Regulations, 2010 CFR

2010-01-01

...) NATIONAL OCEANIC AND ATMOSPHERIC ADMINISTRATION, DEPARTMENT OF COMMERCE QUALITY ASSURANCE AND CERTIFICATION REQUIREMENTS FOR NOAA HYDROGRAPHIC PRODUCTS AND SERVICES QUALITY ASSURANCE AND CERTIFICATION REQUIREMENTS FOR NOAA HYDROGRAPHIC PRODUCTS AND SERVICES Other Quality Assurance Program Matters § 996.30 Use of the...

15 CFR 995.6 - Fees.

Code of Federal Regulations, 2010 CFR

2010-01-01

... ATMOSPHERIC ADMINISTRATION, DEPARTMENT OF COMMERCE QUALITY ASSURANCE AND CERTIFICATION REQUIREMENTS FOR NOAA HYDROGRAPHIC PRODUCTS AND SERVICES CERTIFICATION REQUIREMENTS FOR DISTRIBUTORS OF NOAA HYDROGRAPHIC PRODUCTS General § 995.6 Fees. (a) The Office of Coast Survey, NOAA, may charge a fee for costs incurred to process...

Real-space analysis of radiation-induced specific changes with independent component analysis

DOE Office of Scientific and Technical Information (OSTI.GOV)

Borek, Dominika; Bromberg, Raquel; Hattne, Johan

A method of analysis is presented that allows for the separation of specific radiation-induced changes into distinct components in real space. The method relies on independent component analysis (ICA) and can be effectively applied to electron density maps and other types of maps, provided that they can be represented as sets of numbers on a grid. Here, for glucose isomerase crystals, ICA was used in a proof-of-concept analysis to separate temperature-dependent and temperature-independent components of specific radiation-induced changes for data sets acquired from multiple crystals across multiple temperatures. ICA identified two components, with the temperature-independent component being responsible for themore » majority of specific radiation-induced changes at temperatures below 130 K. The patterns of specific temperature-independent radiation-induced changes suggest a contribution from the tunnelling of electron holes as a possible explanation. In the second case, where a group of 22 data sets was collected on a single thaumatin crystal, ICA was used in another type of analysis to separate specific radiation-induced effects happening on different exposure-level scales. Here, ICA identified two components of specific radiation-induced changes that likely result from radiation-induced chemical reactions progressing with different rates at different locations in the structure. In addition, ICA unexpectedly identified the radiation-damage state corresponding to reduced disulfide bridges rather than the zero-dose extrapolated state as the highest contrast structure. The application of ICA to the analysis of specific radiation-induced changes in real space and the data pre-processing for ICA that relies on singular value decomposition, which was used previously in data space to validate a two-component physical model of X-ray radiation-induced changes, are discussed in detail. This work lays a foundation for a better understanding of protein-specific radiation chemistries and provides a framework for analysing effects of specific radiation damage in crystallographic and cryo-EM experiments.« less

Stepwise pH-gradient elution for the preparative separation of natural anthraquinones by multiple liquid-liquid partition.

PubMed

Hynninen, P H; Räisänen, R

2001-01-01

Preparative-scale separation of substituted anthraquinones by multiple liquid-liquid partition was studied using isopropylmethyl ketone (IMK)/aqueous phosphate buffer (aq.) as the solvent system and the Hietala apparatus with 100 partition units as the partition equipment. The lower (aq.) phase was chosen as mobile, while the upper (IMK) phase remained stationary. Hence, the principle of stepwise pH-gradient elution could be utilized to separate the components in two complex mixtures of hydroxyanthraquinones and hydroxyanthraquinone carboxylic acids, isolated from the fungus Dermocybe sanguinea. In spite of the nonlinearity of the partition isotherms for these anthraquinones, implying deviations from the Nernst partition law, remarkable separations were achieved for the components in each mixture. Every anthraquinone carboxylic acid showed markedly irregular partition behavior, appearing in the effluent as two more or less resolved concentration zones. Such splitting was attributed to the formation of relatively stable sandwich-dimers, which were in a slow equilibrium with the monomers in the more nonpolar organic phase. At lower pH-values, only the polar monomers were distributed into the mobile aqueous phase and moved forward, whereas the nonpolar sandwich-dimers remained almost entirely in the stationary organic phase and lagged behind. When the pH of the mobile aqueous phase was raised high enough, the firmly linked dimers were monomerized and emerged from the apparatus as a second concentration profile. Intermolecular hydrogen bonding and pi-pi interaction between the pi-systems of two anthraquinone molecules in a parallel orientation were considered responsible for the nonlinear and markedly irregular partition behavior of the natural anthraquinones studied. The nonlinearity of the partition behavior of the hydroxyanthraquinones lacking the carboxyl group, appeared merely as excessive broadening of the experimental concentration profile, which impaired the resolution between the components only insignificantly. Thus, e.g. the main components, dermocybin and emodin, could both be obtained from Separation 1 in a purity of at least 99%.

Water's Way at Sleepers River watershed – revisiting flow generation in a post-glacial landscape, Vermont USA

USGS Publications Warehouse

Shanley, James B.; Sebestyen, Stephen D.; McDonnell, Jeffrey J.; McGlynn, Brian L.; Dunne, Thomas

2015-01-01

The Sleepers River Research Watershed (SRRW) in Vermont, USA, has been the site of active hydrologic research since 1959 and was the setting where Dunne and Black demonstrated the importance and controls of saturation-excess overland flow (SOF) on streamflow generation. Here, we review the early studies from the SRRW and show how they guided our conceptual approach to hydrologic research at the SRRW during the most recent 25 years. In so doing, we chronicle a shift in the field from early studies that relied exclusively on hydrometric measurements to today's studies that include chemical and isotopic approaches to further elucidate streamflow generation mechanisms. Highlights of this evolution in hydrologic understanding include the following: (i) confirmation of the importance of SOF to streamflow generation, and at larger scales than first imagined; (ii) stored catchment water dominates stream response, except under unusual conditions such as deep frozen ground; (iii) hydrometric, chemical and isotopic approaches to hydrograph separation yield consistent and complementary results; (iv) nitrate and sulfate isotopic compositions specific to atmospheric inputs constrain new water contributions to streamflow; and (v) convergent areas, or ‘hillslope hollows’, contribute disproportionately to event hydrographs. We conclude by summarizing some remaining challenges that lead us to a vision for the future of research at the SRRW to address fundamental questions in the catchment sciences.

Transformation of OODT CAS to Perform Larger Tasks

NASA Technical Reports Server (NTRS)

Mattmann, Chris; Freeborn, Dana; Crichton, Daniel; Hughes, John; Ramirez, Paul; Hardman, Sean; Woollard, David; Kelly, Sean

2008-01-01

A computer program denoted OODT CAS has been transformed to enable performance of larger tasks that involve greatly increased data volumes and increasingly intensive processing of data on heterogeneous, geographically dispersed computers. Prior to the transformation, OODT CAS (also alternatively denoted, simply, 'CAS') [wherein 'OODT' signifies 'Object-Oriented Data Technology' and 'CAS' signifies 'Catalog and Archive Service'] was a proven software component used to manage scientific data from spaceflight missions. In the transformation, CAS was split into two separate components representing its canonical capabilities: file management and workflow management. In addition, CAS was augmented by addition of a resource-management component. This third component enables CAS to manage heterogeneous computing by use of diverse resources, including high-performance clusters of computers, commodity computing hardware, and grid computing infrastructures. CAS is now more easily maintainable, evolvable, and reusable. These components can be used separately or, taking advantage of synergies, can be used together. Other elements of the transformation included addition of a separate Web presentation layer that supports distribution of data products via Really Simple Syndication (RSS) feeds, and provision for full Resource Description Framework (RDF) exports of metadata.

Estimation of Psychophysical Thresholds Based on Neural Network Analysis of DPOAE Input/Output Functions

NASA Astrophysics Data System (ADS)

Naghibolhosseini, Maryam; Long, Glenis

2011-11-01

The distortion product otoacoustic emission (DPOAE) input/output (I/O) function may provide a potential tool for evaluating cochlear compression. Hearing loss causes an increase in the level of the sound that is just audible for the person, which affects the cochlea compression and thus the dynamic range of hearing. Although the slope of the I/O function is highly variable when the total DPOAE is used, separating the nonlinear-generator component from the reflection component reduces this variability. We separated the two components using least squares fit (LSF) analysis of logarithmic sweeping tones, and confirmed that the separated generator component provides more consistent I/O functions than the total DPOAE. In this paper we estimated the slope of the I/O functions of the generator components at different sound levels using LSF analysis. An artificial neural network (ANN) was used to estimate psychophysical thresholds using the estimated slopes of the I/O functions. DPOAE I/O functions determined in this way may help to estimate hearing thresholds and cochlear health.

Stepwise calibration procedure for regional coupled hydrological-hydrogeological models

NASA Astrophysics Data System (ADS)

Labarthe, Baptiste; Abasq, Lena; de Fouquet, Chantal; Flipo, Nicolas

2014-05-01

Stream-aquifer interaction is a complex process depending on regional and local processes. Indeed, the groundwater component of hydrosystem and large scale heterogeneities control the regional flows towards the alluvial plains and the rivers. In second instance, the local distribution of the stream bed permeabilities controls the dynamics of stream-aquifer water fluxes within the alluvial plain, and therefore the near-river piezometric head distribution. In order to better understand the water circulation and pollutant transport in watersheds, the integration of these multi-dimensional processes in modelling platform has to be performed. Thus, the nested interfaces concept in continental hydrosystem modelling (where regional fluxes, simulated by large scale models, are imposed at local stream-aquifer interfaces) has been presented in Flipo et al (2014). This concept has been implemented in EauDyssée modelling platform for a large alluvial plain model (900km2) part of a 11000km2 multi-layer aquifer system, located in the Seine basin (France). The hydrosystem modelling platform is composed of four spatially distributed modules (Surface, Sub-surface, River and Groundwater), corresponding to four components of the terrestrial water cycle. Considering the large number of parameters to be inferred simultaneously, the calibration process of coupled models is highly computationally demanding and therefore hardly applicable to a real case study of 10000km2. In order to improve the efficiency of the calibration process, a stepwise calibration procedure is proposed. The stepwise methodology involves determining optimal parameters of all components of the coupled model, to provide a near optimum prior information for the global calibration. It starts with the surface component parameters calibration. The surface parameters are optimised based on the comparison between simulated and observed discharges (or filtered discharges) at various locations. Once the surface parameters have been determined, the groundwater component is calibrated. The calibration procedure is performed under steady state hypothesis (to minimize the procedure time length) using recharge rates given by the surface component calibration and imposed fluxes boundary conditions given by the regional model. The calibration is performed using pilot point where the prior variogram is calculated from observed transmissivities values. This procedure uses PEST (http//:www.pesthomepage.org/Home.php) as the inverse modelling tool and EauDyssée as the direct model. During the stepwise calibration process, each modules, even if they are actually dependant from each other, are run and calibrated independently, therefore contributions between each module have to be determined. For the surface module, groundwater and runoff contributions have been determined by hydrograph separation. Among the automated base-flow separation methods, the one-parameter Chapman filter (Chapman et al 1999) has been chosen. This filter is a decomposition of the actual base-flow between the previous base-flow and the discharge gradient weighted by functions of the recession coefficient. For the groundwater module, the recharge has been determined from surface and sub-surface module. References : Flipo, N., A. Mourhi, B. Labarthe, and S. Biancamaria (2014). Continental hydrosystem modelling : the concept of nested stream-aquifer interfaces. Hydrol. Earth Syst. Sci. Discuss. 11, 451-500. Chapman,TG. (1999). A comparison of algorithms for stream flow recession and base-flow separation. hydrological Processes 13, 701-714.

Electron beam control for barely separated beams

DOEpatents

Douglas, David R.; Ament, Lucas J. P.

2017-04-18

A method for achieving independent control of multiple beams in close proximity to one another, such as in a multi-pass accelerator where coaxial beams are at different energies, but moving on a common axis, and need to be split into spatially separated beams for efficient recirculation transport. The method for independent control includes placing a magnet arrangement in the path of the barely separated beams with the magnet arrangement including at least two multipole magnets spaced closely together and having a multipole distribution including at least one odd multipole and one even multipole. The magnetic fields are then tuned to cancel out for a first of the barely separated beams to allow independent control of the second beam with common magnets. The magnetic fields may be tuned to cancel out either the dipole component or tuned to cancel out the quadrupole component in order to independently control the separate beams.

Multiple dual mode counter-current chromatography with variable duration of alternating phase elution steps.

PubMed

Kostanyan, Artak E; Erastov, Andrey A; Shishilov, Oleg N

2014-06-20

The multiple dual mode (MDM) counter-current chromatography separation processes consist of a succession of two isocratic counter-current steps and are characterized by the shuttle (forward and back) transport of the sample in chromatographic columns. In this paper, the improved MDM method based on variable duration of alternating phase elution steps has been developed and validated. The MDM separation processes with variable duration of phase elution steps are analyzed. Basing on the cell model, analytical solutions are developed for impulse and non-impulse sample loading at the beginning of the column. Using the analytical solutions, a calculation program is presented to facilitate the simulation of MDM with variable duration of phase elution steps, which can be used to select optimal process conditions for the separation of a given feed mixture. Two options of the MDM separation are analyzed: 1 - with one-step solute elution: the separation is conducted so, that the sample is transferred forward and back with upper and lower phases inside the column until the desired separation of the components is reached, and then each individual component elutes entirely within one step; 2 - with multi-step solute elution, when the fractions of individual components are collected in over several steps. It is demonstrated that proper selection of the duration of individual cycles (phase flow times) can greatly increase the separation efficiency of CCC columns. Experiments were carried out using model mixtures of compounds from the GUESSmix with solvent systems hexane/ethyl acetate/methanol/water. The experimental results are compared to the predictions of the theory. A good agreement between theory and experiment has been demonstrated. Copyright © 2014 Elsevier B.V. All rights reserved.

Restoration of recto-verso colour documents using correlated component analysis

NASA Astrophysics Data System (ADS)

Tonazzini, Anna; Bedini, Luigi

2013-12-01

In this article, we consider the problem of removing see-through interferences from pairs of recto-verso documents acquired either in grayscale or RGB modality. The see-through effect is a typical degradation of historical and archival documents or manuscripts, and is caused by transparency or seeping of ink from the reverse side of the page. We formulate the problem as one of separating two individual texts, overlapped in the recto and verso maps of the colour channels through a linear convolutional mixing operator, where the mixing coefficients are unknown, while the blur kernels are assumed known a priori or estimated off-line. We exploit statistical techniques of blind source separation to estimate both the unknown model parameters and the ideal, uncorrupted images of the two document sides. We show that recently proposed correlated component analysis techniques overcome the already satisfactory performance of independent component analysis techniques and colour decorrelation, when the two texts are even sensibly correlated.

Programmable selectivity for GC with series-coupled columns using pulsed heating of the second column.

PubMed

Whiting, Joshua; Sacks, Richard

2003-05-15

A series-coupled ensemble of a nonpolar dimethyl polysiloxane column and a polar trifluoropropylmethyl polysiloxane column with independent at-column heating is used to obtain pulsed heating of the second column. For mixture component bands that are separated by the first column but coelute from the column ensemble, a temperature pulse is initiated after the first of the two components has crossed the column junction point and is in the second column, while the other component is still in the first column. This accelerates the band for the first component. If the second column cools sufficiently prior to the second component band crossing the junction, the second band experiences less acceleration, and increased separation is observed for the corresponding peaks in the ensemble chromatogram. High-speed at-column heating is obtained by wrapping the fused-silica capillary column with resistance heater wire and sensor wire. Rapid heating for a temperature pulse is obtained with a short-duration linear heating ramp of 1000 degrees C/min. During a pulse, the second-column temperature increases by 20-100 degrees C in a few seconds. Using a cold gas environment, cooling to a quiescent temperature of 30 degrees C can be obtained in approximately 25 s. The effects of temperature pulse initiation time and amplitude on ensemble peak separation and resolution are described. A series of appropriately timed temperature pulses is used to separate three coeluting pairs of components in a 13-component mixture.

15 CFR 996.31 - Termination of the Quality Assurance Program.

Code of Federal Regulations, 2011 CFR

2011-01-01

... ASSURANCE AND CERTIFICATION REQUIREMENTS FOR NOAA HYDROGRAPHIC PRODUCTS AND SERVICES QUALITY ASSURANCE AND CERTIFICATION REQUIREMENTS FOR NOAA HYDROGRAPHIC PRODUCTS AND SERVICES Other Quality Assurance Program Matters § 996.31 Termination of the Quality Assurance Program. (a) NOAA reserves the right to terminate the...

15 CFR 996.31 - Termination of the Quality Assurance Program.

Code of Federal Regulations, 2013 CFR

2013-01-01

... ASSURANCE AND CERTIFICATION REQUIREMENTS FOR NOAA HYDROGRAPHIC PRODUCTS AND SERVICES QUALITY ASSURANCE AND CERTIFICATION REQUIREMENTS FOR NOAA HYDROGRAPHIC PRODUCTS AND SERVICES Other Quality Assurance Program Matters § 996.31 Termination of the Quality Assurance Program. (a) NOAA reserves the right to terminate the...

15 CFR 996.31 - Termination of the Quality Assurance Program.

Code of Federal Regulations, 2014 CFR

2014-01-01

... ASSURANCE AND CERTIFICATION REQUIREMENTS FOR NOAA HYDROGRAPHIC PRODUCTS AND SERVICES QUALITY ASSURANCE AND CERTIFICATION REQUIREMENTS FOR NOAA HYDROGRAPHIC PRODUCTS AND SERVICES Other Quality Assurance Program Matters § 996.31 Termination of the Quality Assurance Program. (a) NOAA reserves the right to terminate the...

15 CFR 996.31 - Termination of the Quality Assurance Program.

Code of Federal Regulations, 2012 CFR

2012-01-01

... ASSURANCE AND CERTIFICATION REQUIREMENTS FOR NOAA HYDROGRAPHIC PRODUCTS AND SERVICES QUALITY ASSURANCE AND CERTIFICATION REQUIREMENTS FOR NOAA HYDROGRAPHIC PRODUCTS AND SERVICES Other Quality Assurance Program Matters § 996.31 Termination of the Quality Assurance Program. (a) NOAA reserves the right to terminate the...

76 FR 4091 - Proposed Information Collection; Comment Request; Certification Requirements for NOAA's...

Federal Register 2010, 2011, 2012, 2013, 2014

2011-01-24

... Collection; Comment Request; Certification Requirements for NOAA's Hydrographic Product Quality Assurance... hydrographic products are proposed for certification; by which standards and compliance tests are developed, adopted, and applied for those products; and by which certification is awarded or denied. These procedures...

Kinematic and stellar population properties of the counter-rotating components in the S0 galaxy NGC 1366

NASA Astrophysics Data System (ADS)

Morelli, L.; Pizzella, A.; Coccato, L.; Corsini, E. M.; Dalla Bontà, E.; Buson, L. M.; Ivanov, V. D.; Pagotto, I.; Pompei, E.; Rocco, M.

2017-04-01

Context. Many disk galaxies host two extended stellar components that rotate in opposite directions. The analysis of the stellar populations of the counter-rotating components provides constraints on the environmental and internal processes that drive their formation. Aims: The S0 NGC 1366 in the Fornax cluster is known to host a stellar component that is kinematically decoupled from the main body of the galaxy. Here we successfully separated the two counter-rotating stellar components to independently measure the kinematics and properties of their stellar populations. Methods: We performed a spectroscopic decomposition of the spectrum obtained along the galaxy major axis and separated the relative contribution of the two counter-rotating stellar components and of the ionized-gas component. We measured the line-strength indices of the two counter-rotating stellar components and modeled each of them with single stellar population models that account for the α/Fe overabundance. Results: We found that the counter-rotating stellar component is younger, has nearly the same metallicity, and is less α/Fe enhanced than the corotating component. Unlike most of the counter-rotating galaxies, the ionized gas detected in NGC 1366 is neither associated with the counter-rotating stellar component nor with the main galaxy body. On the contrary, it has a disordered distribution and a disturbed kinematics with multiple velocity components observed along the minor axis of the galaxy. Conclusions: The different properties of the counter-rotating stellar components and the kinematic peculiarities of the ionized gas suggest that NGC 1366 is at an intermediate stage of the acquisition process, building the counter-rotating components with some gas clouds still falling onto the galaxy. Based on observations made with ESO Telescopes at the La Silla-Paranal Observatory under programmes 075.B-0794 and 077.B-0767.

The Geomorphically Effective Hydrograph: An Emerging Concept For Interpreting Channel Morphology And Evolution

NASA Astrophysics Data System (ADS)

Grant, G.; Hempel, L. A.; Marwan, H.; Eaton, B. C.; Lewis, S.

2017-12-01

Predicting how alluvial channels adjust to changes in their flow and sediment regimes is one of the Holy Grails of geomorphology. Consider Lane's balance - one of the most widely recognized conceptual models in geomorphology - which graphically shows how a change in any one of the driving variables of slope, grain size, sediment transport rate, or discharge can be accommodated by changes in the other variables. Much of the history of process geomorphology addresses how channels respond to these controlling factors. Yet the emphasis has been disproportionately focused on the effects and consequences of changing sediment transport rates or grain size. Much less attention has been paid to how changing discharge itself, particularly over short, event-based timescales influences the channel. Discharge has typically been treated as a single value - often the bankfull discharge - with little attention paid to how the unsteady nature of flow during floods may influence the morphology of the channel. More attention has been paid recently to the effect of hydrograph shape on channel characteristics, notably the texture of the channel bed. There is little theory and scant data, however, that highlights how the hydrograph affects the channel. We have begun to address this problem through models and targeted experiments. Our goal is to explore the idea of the geomorphically effective hydrograph: the concept that hydrographs with different forms, durations, and sequences play a major, controlling role in shaping the form and organization of alluvial channels. We report on results from both field studies and flume experiments that lend support to this hypothesis. We compare channel forms in channels with radically different flow regimes. The distinctive rectangular shape, constant slope, and absence of alluvial bars in spring-fed channels are in sharp contrast to the more asymmetric channels with regular pool/riffle patterns observed in systems where discharge varies over orders of magnitude. Flume studies reveal how channel organization, defined as the tendency to form regularly-spaced pools, riffles, and bars, is related to the flashiness of the hydrograph. Drawing on these and other studies, we develop a conceptual model that accounts for hydrograph shape as an overarching control on channel development and evolution.

Effect of reservoir storage on peak flow

USGS Publications Warehouse

Mitchell, William D.

1962-01-01

For observation of small-basin flood peaks, numerous crest-stage gages now are operated at culverts in roadway embankments. To the extent that they obstruct the natural flood plains of the streams, these embankments serve to create detention reservoirs, and thus to reduce the magnitude of observed peak flows. Hence, it is desirable to obtain a factor, I/O, by which the observed outflow peaks may be adjusted to corresponding inflow peaks. The problem is made more difficult by the fact that, at most of these observation sites, only peak stages and discharges are observed, and complete hydrographs are not available. It is postulated that the inflow hydrographs may be described in terms of Q, the instantaneous discharge; A, the size of drainage area; Pe, the amount of rainfall excess; H, the time from beginning of rainfall excess; D, the duration of rainfall excess; and T and k, characteristic times for the drainage area, and indicative of the time lag between rainfall and runoff. These factors are combined into the dimensionless ratios (QT/APe), (H/T), (k/T), and (D/T), leading to families of inflow hydrographs in which the first ratio is the ordinate, the second is the abscissa, and the third and fourth are distinguishing parameters. Sixteen dimensionless inflow hydrographs have been routed through reservoir storage to obtain 139 corresponding outflow hydrographs. In most of the routings it has been assumed that the storage-outflow relation is linear; that is, that storage is some constant, K, times the outflow. The existence of nonlinear storage is recognized, and exploratory nonlinear routings are described, but analyses and conclusions are confined to the problems of linear storage. Comparisons between inflow hydrographs and outflow hydrographs indicate that, at least for linear storage, I/O=f(k/T, D/T, K/T) in which I and O are, respectively, the magnitudes of the inflow and the outflow peaks, and T, k, D, and K are as defined above. Diagrams are presented to show the functional relation indicated by the foregoing equation.

Hydrographic biases in global coupled climate models and their relation to the meridional overturning circulation

NASA Astrophysics Data System (ADS)

Plancherel, Yves

2015-01-01

Comparison of the volumetric θ/S distribution of models participating in the Climate Model Intercomparison Project 3 (CMIP3) indicates that these models differ widely in their ability to represent the thermohaline properties of water masses. Relationships between features of the quasi-equilibrium hydrographic mean state of these models and aspects of their overturning circulations are investigated. This is achieved quantitatively with the help of seven diagnostic hydrographic stations. These few stations were specifically selected to provide a minimalist schematic of the global water mass system. Relationships between hydrographic conditions in the North Atlantic measured with a subset of these stations suggest that hydrographic properties in the subpolar North Atlantic are set by the circulation field of each model, pointing towards deficiencies in the models ability to resolve the Gulf Stream-North Atlantic Current system as a major limitation. Since diapycnal mixing and viscosity parameterizations differ across CMIP3 models and exert a strong control on the overturning, it is likely that these architectural differences ultimately explain the main across-model differences in overturning circulation, temperature and salinity in the North Atlantic. The analysis of properties across the quasi-equilibrium states of the CMIP3 models agrees with previously reported relationships between meridional steric height gradients or horizontal density contrasts at depth and the strength of the deep water cell. Robust relationships are also found in the Southern Ocean linking measures of vertical stratification with the strength of the abyssal circulations across the CMIP3 models. Consistent correlations between aspects of the quasi-equilibrium hydrography in the Southern Ocean and the sensitivity of the abyssal cell to increasing radiative forcing by 2100 were found. Using these relations in conjunction with modern hydrographic observations to interpolate the fate of the abyssal cell suggests that the Southern abyssal cell may decrease by roughly 20 % by the end of the century. Similar systematic relationships between the quasi-equilibrium hydrographic states of the models and the sensitivity of their Atlantic deep water cell could not be found.

Multi-Wavelength, Multi-Beam, and Polarization-Sensitive Laser Transmitter for Surface Mapping

NASA Technical Reports Server (NTRS)

Yu, Anthony W.; Ramos-Izquierdo, Luis; Harding, David; Huss, Tim

2011-01-01

A multi-beam, multi-color, polarized laser transmitter has been developed for mapping applications. It uses commercial off-the-shelf components for a lowcost approach for a ruggedized laser suitable for field deployment. The laser transmitter design is capable of delivering dual wavelengths, multiple beams on each wavelength with equal (or variable) intensities per beam, and a welldefined state of polarization. This laser transmitter has been flown on several airborne campaigns for the Slope Imaging Multi-Polarization Photon Counting Lidar (SIMPL) instrument, and at the time of this reporting is at a technology readiness level of between 5 and 6. The laser is a 1,064-nm microchip high-repetition-rate laser emitting energy of about 8 microjoules per pulse. The beam was frequency-doubled to 532 nm using a KTP (KTiOPO4) nonlinear crystal [other nonlinear crystals such as LBO (LiB3O5) or periodically poled lithium niobiate can be used as well, depending on the conversion efficiency requirements], and the conversion efficiency was approximately 30 percent. The KTP was under temperature control using a thermoelectric cooler and a feedback monitoring thermistor. The dual-wavelength beams were then spectrally separated and each color went through its own optical path, which consisted of a beam-shaping lens, quarterwave plate (QWP), and a birefringent crystal (in this case, a calcite crystal, but others such as vanadate can be used). The QWP and calcite crystal set was used to convert the laser beams from a linearly polarized state to circularly polarized light, which when injected into a calcite crystal, will spatially separate the circularly polarized light into the two linear polarized components. The spatial separation of the two linearly polarized components is determined by the length of the crystal. A second set of QWP and calcite then further separated the two beams into four. Additional sets of QWP and calcite can be used to further split the beams into multiple orders of two. The spatially separated beams had alternating linearly polarization states; a half-wave plate (HWP) array was then made to rotate the alternating states of A multi-beam, multi-color, polarized laser transmitter has been developed for mapping applications. It uses commercial off-the-shelf components for a lowcost approach for a ruggedized laser suitable for field deployment. The laser transmitter design is capable of delivering dual wavelengths, multiple beams on each wavelength with equal (or variable) intensities per beam, and a welldefined state of polarization. This laser transmitter has been flown on several airborne campaigns for the Slope Imaging Multi-Polarization Photon Counting Lidar (SIMPL) instrument, and at the time of this reporting is at a technology readiness level of between 5 and 6. The laser is a 1,064-nm microchip high-repetition-rate laser emitting energy of about 8 microjoules per pulse. The beam was frequency-doubled to 532 nm using a KTP (KTiOPO4) nonlinear crystal [other nonlinear crystals such as LBO (LiB3O5) or periodically poled lithium niobiate can be used as well, depending on the conversion efficiency requirements], and the conversion efficiency was approximately 30 percent. The KTP was under temperature control using a thermoelectric cooler and a feedback monitoring thermistor. The dual-wavelength beams were then spectrally separated and each color went through its own optical path, which consisted of a beam-shaping lens, quarterwave plate (QWP), and a birefringent crystal (in this case, a calcite crystal, but others such as vanadate can be used). The QWP and calcite crystal set was used to convert the laser beams from a linearly polarized state to circularly polarized light, which when injected into a calcite crystal, will spatially separate the circularly polarized light into the two linear polarized components. The spatial separation of the two linearly polarized components is determined by the length of the crystal. A cond set of QWP and calcite then further separated the two beams into four. Additional sets of QWP and calcite can be used to further split the beams into multiple orders of two. The spatially separated beams had alternating linearly polarization states; a half-wave plate (HWP) array was then made to rotate the alternating states of

The decoupling of the glass transitions in the two-component p-spin spherical model

NASA Astrophysics Data System (ADS)

Ikeda, Harukuni; Ikeda, Atsushi

2016-07-01

Binary mixtures of large and small particles with a disparate size ratio exhibit a rich phenomenology at their glass transition points. In order to gain insights on such systems, we introduce and study a two-component version of the p-spin spherical spin glass model. We employ the replica method to calculate the free energy and the phase diagram. We show that when the strengths of the interactions of each component are not widely separated, the model has only one glass phase characterized by the conventional one-step replica symmetry breaking. However when the strengths of the interactions are well separated, the model has three glass phases depending on the temperature and component ratio. One is the ‘single’ glass phase in which only the spins of one component are frozen while the spins of the other component remain mobile. This phase is characterized by the one-step replica symmetry breaking. The second is the ‘double’ glass phase obtained by cooling the single glass phase further, in which the spins of the remaining mobile component are also frozen. This phase is characterized by the two-step replica symmetry breaking. The third is also the ‘double’ glass phase, which, however, is formed by the simultaneous freezing of the spins of both components at the same temperatures and is characterized by the one-step replica symmetry breaking. We discuss the implications of these results for the glass transitions of binary mixtures.

Changes in storm hydrographs after roadbuilding and selective logging on a coastal watershed in northern California

Treesearch

Kenneth A. Wright

1985-01-01

Abstract - The effects of road building and selective tractor harvesting on storm peak flows and storm volumes were assessed for a small (424 hectare) coastal watershed in Northern California. Two watersheds, the North and South Fork of Caspar Creek were calibrated from 1962 to 1967 while no treatments took place. Roads were then built on the South Fork, and the two...

Comparing the extent and permanence of headwater streams from two field surveys to values from hydrographic databases and maps

EPA Science Inventory

ABSTRACT: Recent US Supreme Court cases have questioned the jurisdictional scope of the Clean Water Act. Headwater streams are central to this issue because many headwater streams do not have year-round flow, and also because little is known about their contributions to navigable...

A ground-water-quality monitoring program for Nevada

USGS Publications Warehouse

Nowlin, Jon O.

1986-01-01

A program was designed for the systematic monitoring of ground-water quality in Nevada. Basic hydrologic and water-quality principles are discussed in the formulation of a rational approach to developing a statewide monitoring program. A review of ground-water monitoring efforts in Nevada through 1977 indicates that few requirements for an effective statewide program are being met. A suggested program has been developed that consists of five major elements: (1) A Background-Quality Network to assess the existing water quality in Nevada aquifers, (2) a Contamination Source Inventory of known or potential threats to ground-water quality, (3) Surveillance Networks to monitor ground-water quality in selected hydrographic areas, (4) Intensive Surveys of individual instances of known or potential ground-water contamination, and (5) Ground-Water Data File to manage data generated by the other monitoring elements. Two indices have been developed to help assign rational priorities for monitoring ground water in the 255 hydrographic areas of Nevada: (1) A Hydrographic-Area Priority Index for surveillance monitoring, and (2) A Development-Potential Index for background monitoring of areas with little or no current development. Requirements for efficient management of data from ground-water monitoring are discussed and the three major systems containing Nevada ground-water data are reviewed. More than 11,000 chemical analyses of ground water have been acquired from existing systems and incorporated into a prototype data base.

Hydrographic charting from Landsat satellite - A comparison with aircraft imagery

NASA Technical Reports Server (NTRS)

Middleton, E. M.; Barker, J. L.

1976-01-01

The relative capabilities of two remote-sensing systems in measuring depth and, consequently, bottom contours in sandy-bottomed and sediment-laden coastal waters were determined quantitatively. The Multispectral Scanner (MSS), orbited on the Landsat-2 satellite, and the Ocean Color Scanner (OCS), flown on U-2 aircraft, were used for this evaluation. Analysis of imagery taken simultaneously indicates a potential for hydrographic charting of marine coastal and shallow shelf areas, even when water turbidity is a factor. Several of the eight optical channels examined on the OCS were found to be sensitive to depth or depth-related information. The greatest sensitivity was in OCS-4 (0.544 plus or minus 0.012 micron) from which contours corresponding to depths up to 12 m were determined. The sharpness of these contours and their spatial stability through time suggests that upwelling radiance is a measure of bottom reflectance and not of water turbidity. The two visible channels on Landsat's MSS were less sensitive in the discrimination of contours, with depths up to 8 m in the high-gain mode (3 X) determined in MSS-4 (0.5 to 0.6 micron).

Hydrographic charting from LANDSAT Satellite: A comparison with aircraft imagery

NASA Technical Reports Server (NTRS)

Middleton, E. M.; Barker, J. L.

1976-01-01

The relative capabilities of two remote-sensing systems in measuring depth and, consequently, bottom contours in sandy-bottomed and sediment-laden coastal waters were determined quantitatively. The multispectral scanner (MSS), orbited on the LANDSAT-2 Satellite, and the ocean color scanner (OCS), flown on U-2 aircraft, were used. Analysis of imagery taken simultaneously indicates a potential for hydrographic charting of marine coastal and shallow shelf areas, even when water turbidity is a factor. Several of the eight optical channels examined on the OCS were found to be sensitive to depth or depth-related information. The greatest sensitivity was in OCS-4(0.544 + or - 0.012 microns) from which contours corresponding to depths up to 12m were determined. The sharpness of these contours and their spatial stability through time suggests that upwelling radiance is a measure of bottom reflectance and not of water turbidity. The two visible channels on LANDSAT's MSS were less sensitive in the discrimination of contours, with depths up to 8m in the high-gain mode (3x) determined in MSS-4(0.5 to 0.6 microns).

15 CFR 996.33 - Acceptance of program by non-Federal entities.

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2014-01-01

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2013-01-01

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15 CFR 996.33 - Acceptance of program by non-Federal entities.

Code of Federal Regulations, 2013 CFR

2013-01-01

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15 CFR 995.21 - Registry of data users.

Code of Federal Regulations, 2012 CFR

2012-01-01

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Code of Federal Regulations, 2014 CFR

2014-01-01

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Code of Federal Regulations, 2012 CFR

2012-01-01

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15 CFR 996.33 - Acceptance of program by non-Federal entities.

Code of Federal Regulations, 2012 CFR

2012-01-01

... ASSURANCE AND CERTIFICATION REQUIREMENTS FOR NOAA HYDROGRAPHIC PRODUCTS AND SERVICES QUALITY ASSURANCE AND CERTIFICATION REQUIREMENTS FOR NOAA HYDROGRAPHIC PRODUCTS AND SERVICES Other Quality Assurance Program Matters... information submitted to NOAA under this Program shall be deemed to be in the public domain, and no...

15 CFR 996.33 - Acceptance of program by non-Federal entities.

Code of Federal Regulations, 2011 CFR

2011-01-01

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15 CFR 995.21 - Registry of data users.

Code of Federal Regulations, 2014 CFR

2014-01-01

... REQUIREMENTS FOR NOAA HYDROGRAPHIC PRODUCTS AND SERVICES CERTIFICATION REQUIREMENTS FOR DISTRIBUTORS OF NOAA HYDROGRAPHIC PRODUCTS Requirements for Certified Distributors and Value Added Distributors of NOAA ENC Products § 995.21 Registry of data users. (a) CED or CEVAD shall maintain a registry of customers receiving NOAA...

15 CFR 995.21 - Registry of data users.

Code of Federal Regulations, 2013 CFR

2013-01-01

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Hydrologic data; North Canadian River from Lake Overholser to Lake Eufaula, central Oklahoma

USGS Publications Warehouse

Havens, J.S.

1984-01-01

The data contained in this report were gathered during the period 1982 to 1984 for use in constructing a digital model of the North Canadian River from Lake Overholser, in the western part of Oklahoma City, to Lake Eufaula, in eastern Oklahoma. Locations of test holes and sampling sites are show in figure 1. Information on well depths and water levels in table 1 was gathered in the summer of 1982. Some information in the table was reported by well owners. Field water-quality data for water temperatures, specific conductance, and pH were measured at the time the wells were inventoried in 1982 and appear in table 2. Forty-nine test holes were augered to provide more comprehensive lithologic and water-level data along the North Canadian River. Lithologic logs of these test holes appear in table 3. Thirty-eight of the test holes were completed as observations wells by placing perforated plastic casing in the holes. Water levels were measured in these observations wells from the time of completion in mid-1982 through mid-1984. Hydrographs of the observation wells are shown in figures 2 through 15. The data are presented graphically for clarity. Hydrographs of water-level fluctuations in two wells equipped with continuous water-level recorders and hydrographs of stage fluctuations on the North Canadian River at nearby gaging stations are shown in figures 16 and 17. Two sets of low-flow measurements for the North Canadian River showing gains and losses in flow between measuring sites in the reach from Lake Overholser to Lake Eufaula are given in table 4. Measurements of flow on tributary streams are also given in this table. Analyses of water-quality samples collected at the time of the low-flow measurements are given in table 5.

A technique for estimating time of concentration and storage coefficient values for Illinois streams

USGS Publications Warehouse

Graf, Julia B.; Garklavs, George; Oberg, Kevin A.

1982-01-01

Values of the unit hydrograph parameters time of concentration (TC) and storage coefficient (R) can be estimated for streams in Illinois by a two-step technique developed from data for 98 gaged basins in the State. The sum of TC and R is related to stream length (L) and main channel slope (S) by the relation (TC + R)e = 35.2L0.39S-0.78. The variable R/(TC + R) is not significantly correlated with drainage area, slope, or length, but does exhibit a regional trend. Regional values of R/(TC + R) are used with the computed values of (TC + R)e to solve for estimated values of time of concentration (TCe) and storage coefficient (Re). The use of the variable R/(TC + R) is thought to account for variations in unit hydrograph parameters caused by physiographic variables such as basin topography, flood-plain development, and basin storage characteristics. (USGS)

Dynamics of the outgoing turbulent boundary layer in a Mach 5 unswept compression ramp interaction

NASA Technical Reports Server (NTRS)

Gramann, Richard A.; Dolling, David S.

1990-01-01

Wall pressure fluctuations have been measured under the unsteady separation shock and on the ramp face in an unswept Mach 5 compression ramp interaction. The freestream Reynolds number was 51.0 x 10 to the 6th/m, and the incoming turbulent boundary layer developed on the tunnel floor under approximately adiabatic wall temperature conditions. Standard data-acquisition methods, as well as real-time and posttest conditional sampling techniques were used. The results show that the mean and rms pressure levels are strong functions of separation shock position. At all stations on the ramp, from the corner to where the pressure reaches the theoretical inviscid value, the pressure signals have two dominant components: a low frequency component characteristic of the global unsteadiness, which correlates with the separation shock motion, and a higher frequency component associated with turbulence. The former is the major contributor to the overall signal variance.

Virtual experiments: a new approach for improving process conceptualization in hillslope hydrology

NASA Astrophysics Data System (ADS)

Weiler, Markus; McDonnell, Jeff

2004-01-01

We present an approach for process conceptualization in hillslope hydrology. We develop and implement a series of virtual experiments, whereby the interaction between water flow pathways, source and mixing at the hillslope scale is examined within a virtual experiment framework. We define these virtual experiments as 'numerical experiments with a model driven by collective field intelligence'. The virtual experiments explore the first-order controls in hillslope hydrology, where the experimentalist and modeler work together to cooperatively develop and analyze the results. Our hillslope model for the virtual experiments (HillVi) in this paper is based on conceptualizing the water balance within the saturated and unsaturated zone in relation to soil physical properties in a spatially explicit manner at the hillslope scale. We argue that a virtual experiment model needs to be able to capture all major controls on subsurface flow processes that the experimentalist might deem important, while at the same time being simple with few 'tunable parameters'. This combination makes the approach, and the dialog between experimentalist and modeler, a useful hypothesis testing tool. HillVi simulates mass flux for different initial conditions under the same flow conditions. We analyze our results in terms of an artificial line source and isotopic hydrograph separation of water and subsurface flow. Our results for this first set of virtual experiments showed how drainable porosity and soil depth variability exert a first order control on flow and transport at the hillslope scale. We found that high drainable porosity soils resulted in a restricted water table rise, resulting in more pronounced channeling of lateral subsurface flow along the soil-bedrock interface. This in turn resulted in a more anastomosing network of tracer movement across the slope. The virtual isotope hydrograph separation showed higher proportions of event water with increasing drainable porosity. When combined with previous experimental findings and conceptualizations, virtual experiments can be an effective way to isolate certain controls and examine their influence over a range of rainfall and antecedent wetness conditions.

Rainwater propagation through snow during artificial rain-on-snow events

NASA Astrophysics Data System (ADS)

Juras, Roman; Würzer, Sebastian; Pavlasek, Jiri; Jonas, Tobias

2016-04-01

The mechanism of rainwater propagation and runoff generation during rain-on-snow (ROS) is still insufficiently known. Understanding rainwater behaviour within the natural snowpack is crucial especially for forecasting of natural hazards like floods and wet snow avalanches. In this study, rainwater percolation through snow was investigated by sprinkling the naturally stable isotope deuterium on snow and conduct hydrograph separation on samples collected from the snowpack runoff. This allowed quantifying the contribution of rainwater and snowmelt in the water released from the snowpack. Four field experiments were carried out during the winter 2015 in the vicinity of Davos, Switzerland. A 1 by 1 m block of natural snow cover was isolated from the surrounding snowpack to enable a closed water balance. This experimental snow sample was exposed to artificial rainfall with 41 mm of deuterium enriched water. The sprinkling was run in four 30 minutes intervals separated by three 30 minutes non-sprinkling intervals. The runoff from the snow cube was monitored quantitatively by a snow lysimeter and output water was continuously sampled for the deuterium concentration. Further, snowpack properties were analysed before and after the sprinkling, including vertical profiles of snow density, liquid water content (LWC) and deuterium concentration. One experiment conducted on cold snowpack showed that rainwater propagated much faster as compared to three experiments conducted on ripe isothermal snowpack. Our data revealed that sprinkled rainwater initially pushed out pre-event LWC or mixed with meltwater created within the snowpack. Hydrographs from every single experiment showed four pronounced peaks, with the first peak always consisted of less rainwater than the following ones. The partial contribution of rainwater to the total runoff consistently increased over the course of the experiment, but never exceeded 63 %. Moreover, the development of preferential paths after the first sprinkling period caused a quicker runoff response in subsequent periods.

Study on the contribution of cryosphere to runoff in the cold alpine basin: A case study of Hulugou River Basin in the Qilian Mountains

NASA Astrophysics Data System (ADS)

Zongxing, Li; Qi, Feng; Wei, Liu; Tingting, Wang; Aifang, Cheng; Yan, Gao; Xiaoyan, Guo; Yanhui, Pan; Jianguo, Li; Rui, Guo; Bing, Jia

2014-11-01

Global warming would inevitably lead to the increased glacier-snow meltwater and mountainous discharge. Taking an example the Hulugou River Basin in the Qilian Mountains, this study confirmed the contribution of cryosphere to runoff by means of the isotope hydrograph separation. The hydro-geochemistry and the isotope geochemistry suggested that both the meltwater and rainwater infiltrated into the subsurface and fed into the river runoff of the Hulugou River Basin in the form of springs. The isotopic composition of river water and underground water was close to the Local Meteoric Water Line, and the δ18O and δD ranged among precipitation, glacier-snow meltwater and frozen soil meltwater. The results indicated that 68% of the recharge of the Hulugou River water was the precipitation, thereinto, glacier-snow meltwater and frozen soil meltwater contributing 11% and 21%, respectively. For tributary-1, precipitation accounted for 77% of the total stream runoff, with frozen soil meltwater accounting for 17%, and glacier-snow meltwater only supplied 6%. During the sampling period, the contribution of surface runoff from precipitation was 44% to tributary-2, and glacier-snow meltwater had contributed 42%; only 14% from frozen soil meltwater. For tributary-3, precipitation accounted for 63% of the total runoff, and other 37% originated from the frozen soil meltwater. According to the latest observational data, the glacier-snow meltwater has accounted for 11.36% of the total runoff in the stream outlet, in which the calculation has been verified by hydrograph separation. It is obvious that the contribution of cryosphere has accounted for 1/3 of the outlet runoff in the Hulugou River Basin, which has been an important part of river sources. This study demonstrated that the alpine regions of western China, especially those basins with glaciers, snow and frozen soil, have played a crucial role in regional water resource provision under global warming.

The Development and Validation of a New Land Surface Model for Regional and Global Climate Modeling

NASA Astrophysics Data System (ADS)

Lynch-Stieglitz, Marc

1995-11-01

A new land-surface scheme intended for use in mesoscale and global climate models has been developed and validated. The ground scheme consists of 6 soil layers. Diffusion and a modified tipping bucket model govern heat and water flow respectively. A 3 layer snow model has been incorporated into a modified BEST vegetation scheme. TOPMODEL equations and Digital Elevation Model data are used to generate baseflow which supports lowland saturated zones. Soil moisture heterogeneity represented by saturated lowlands subsequently impacts watershed evapotranspiration, the partitioning of surface fluxes, and the development of the storm hydrograph. Five years of meteorological and hydrological data from the Sleepers river watershed located in the eastern highlands of Vermont where winter snow cover is significant were then used to drive and validate the new scheme. Site validation data were sufficient to evaluate model performance with regard to various aspects of the watershed water balance, including snowpack growth/ablation, the spring snowmelt hydrograph, storm hydrographs, and the seasonal development of watershed evapotranspiration and soil moisture. By including topographic effects, not only are the main spring hydrographs and individual storm hydrographs adequately resolved, but the mechanisms generating runoff are consistent with current views of hydrologic processes. The seasonal movement of the mean water table depth and the saturated area of the watershed are consistent with site data and the overall model hydroclimatology, including the surface fluxes, seems reasonable.

Pathways and hydrography in the Mesoamerican Barrier Reef System Part 2: Water masses and thermohaline structure

NASA Astrophysics Data System (ADS)

Carrillo, L.; Johns, E. M.; Smith, R. H.; Lamkin, J. T.; Largier, J. L.

2016-06-01

Hydrographic data from two oceanographic cruises conducted during March 2006 and January/February 2007 are used to investigate the thermohaline structure related to the observed circulation along the Mesoamerican Barrier Reef System (MBRS). From our observations we identify three water masses in the MBRS: the Caribbean Surface Water (CSW), North Atlantic Subtropical Underwater (SUW), and Tropical Atlantic Central Water (TACW). Little vertical structure in temperature is observed in the upper 100 m of the water column, but important differences are observed in the salinity distribution both horizontally and with depth. Freshwater inputs to the system from the mainland can be traced in the surface layer, with two possible sources: one from surface rivers located along the southern portion of the MBRS, and the other originating from an underground river system located along the northern portion of the MBRS. The thermohaline structure in the MBRS reflects the dynamics of the observed circulation. Uplifted isopycnals along most of the central and northern coastline of the MBRS reflect the effects of the strong geostrophic circulation flowing northward, i.e. the Yucatan Current. To the south along the MBRS, much weaker velocities are observed, with the Honduras Gyre dominating the flow in this region as presented during January/February 2007. These two regions are separated by onshore and divergent alongshore flow associated with the impingement of the Cayman Current on the shore and the MBRS.

One hundred years of hydrographic measurements in the Baltic Sea

NASA Astrophysics Data System (ADS)

Fonselius, Stig; Valderrama, Jorge

2003-06-01

The first measurements of salinity of the deep water in the open Baltic Sea were made in the last decades of the 1800s. At a Scandinavian science meeting in Copenhagen in 1892, Professor Otto Pettersson from Sweden suggested that regular measurements of hydrographic parameters should be carried out at some important deep stations in the Baltic Sea. His suggestion was adopted and since that time we have rather complete hydrographical data from the Bornholm Deep, the Gotland Deep, and the Landsort Deep and from some stations in the Gulf of Bothnia. The measurements were interrupted in the Baltic Proper during the two World Wars. At the beginning only salinity, temperature and dissolved oxygen were measured and one or two expeditions were carried out annually, mostly in summer. In the 1920s also alkalinity and pH were occasionally measured and total carbonate was calculated. A few nutrient measurements were also carried out. After World War II we find results from four or more expeditions every year and intercalibration of methods was arranged. Results of temperature, salinity and dissolved oxygen measurements from the Bornholm Deep, the Gotland Deep, the Landsort Deep and salinity measurements from three stations in the Gulf of Bothnia, covering the whole 20th century are presented and discussed. The salinity distribution and the variations between oxygen and hydrogen sulphide periods in the deep water of the Gotland Deep and the Landsort Deep are demonstrated. Series of phosphate and nitrate distribution in the Gotland Deep are shown from the 1950s to the present and the effects of the stagnant conditions are briefly discussed. Two large inflows of highly saline water, the first during the First World War and the second in 1951, are demonstrated. The 20th century minimum salinity of the bottom water in the Baltic Proper in 1992 is discussed.

Hydrographic Variability off the Coast of Oman

NASA Astrophysics Data System (ADS)

Belabbassi, L.; Dimarco, S. F.; Jochens, A. E.; Al Gheilani, H.; Wang, Z.

2010-12-01

Data from hydrographic transects made in 2001 and 2002 and between 2007 and 2009 were obtained from the Oman Ministry of Fisheries Wealth. Property-depth plots of temperature, salinity, and dissolved oxygen were produced for all transects and in all months for which data were available. These were analyzed for temporal and spatial variability. For all transects, there exist large variability on various timescales, with strong spatial variability. Two common features that are seen in the hydrographic data sets are the Persian Gulf Water (PGW) and a layer of continuous low oxygen concentrations in the lower part of the water column. Plots of salinity produced for transects located in the northern part of the Gulf of Oman show a one-unit increase in salinity of the water at the bottom of deepest station during the months of August and September as compared to the other months. Similarly, cross-shelf contour plots of temperature shows an increase in water temperature near the bottom station during the months of August and September. These indicate the presence of the PGW outflow in the northern part of the Gulf of Oman. For dissolved oxygen distributions, hydrographic transects that did not extend far offshore show monthly differences in the presence of water with low oxygen concentrations. For transects that do extend far offshore and also show a layer of low oxygen water throughout the year, there is generally a monthly difference on whether this water is found close to the surface or deeper in the water column. The variability seen in the data could only be explained by comparing these data to data collected from the real time cable ocean observing system installed by Lighthouse R &D Enterprise in the Oman Sea and the Arabian Sea in 2005. The analysis of these data reveal that the variability observed is related to processes such as ocean conditions, monsoonal cycle, and extreme weather events.

15 CFR 996.30 - Use of the NOAA emblem.

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2011-01-01

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15 CFR 995.28 - Use of NOAA emblem.

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2011-01-01

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15 CFR 995.26 - Conversion of NOAA ENC ® files to other formats.

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15 CFR 996.30 - Use of the NOAA emblem.

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2012-01-01

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15 CFR 995.26 - Conversion of NOAA ENC ® files to other formats.

Code of Federal Regulations, 2014 CFR

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Hydrographic Service Royal Australian Navy

DTIC Science & Technology

1993-01-01

relocation of the Hydrographic Office to Wollongong, NSW; "* A marked decline in chart production caused by workforce changes as a result of the impending...amalgamate the plans of Clinton Coal Loader Wharf and Auckland Point to Barney Point in one plan at scale 1:10 000. The chart now provides continuous

77 FR 36998 - Notice of Availability of a Draft Programmatic Environmental Assessment for Office of Coast...

Federal Register 2010, 2011, 2012, 2013, 2014

2012-06-20

... Draft Programmatic Environmental Assessment for Office of Coast Survey Hydrographic Survey Projects... Programmatic Environmental Assessment; Request for comments. SUMMARY: NOAA's Office of Coast Survey (OCS) seeks comment on a draft programmatic environmental assessment (PEA) of the hydrographic surveys and related...

15 CFR 995.26 - Conversion of NOAA ENC ® files to other formats.

Code of Federal Regulations, 2010 CFR

2010-01-01

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15 CFR 995.28 - Use of NOAA emblem.

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2010-01-01

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CHARACTERIZING STORM HYDROGRAPH RISE AND FALL DYNAMICS AND THEIR RELATIONSHIP WITH STREAM STAGE DATA

EPA Science Inventory

Stormflow transients (i.e., hydrograph rise and fall dynamics) have been shown to impact stream biota through impacts on habitat quality and availability. However, little is known about how climate variability and temporal resolution of transient data may color the putative relat...

Maximum Likelihood and Minimum Distance Applied to Univariate Mixture Distributions.

ERIC Educational Resources Information Center

Wang, Yuh-Yin Wu; Schafer, William D.

This Monte-Carlo study compared modified Newton (NW), expectation-maximization algorithm (EM), and minimum Cramer-von Mises distance (MD), used to estimate parameters of univariate mixtures of two components. Data sets were fixed at size 160 and manipulated by mean separation, variance ratio, component proportion, and non-normality. Results…

Two Aspects of the Therapeutic Alliance: Differential Relations with Depressive Symptom Change

ERIC Educational Resources Information Center

Webb, Christian A.; Derubeis, Robert J.; Amsterdam, Jay D.; Shelton, Richard C.; Hollon, Steven D.; Dimidjian, Sona

2011-01-01

Objective: The therapeutic alliance has been linked to symptom change in numerous investigations. Although the alliance is commonly conceptualized as a multidimensional construct, few studies have examined its components separately. The current study explored which components of the alliance are most highly associated with depressive symptom…

Engine component instrumentation development facility at NASA Lewis Research Center

NASA Technical Reports Server (NTRS)

Bruckner, Robert J.; Buggele, Alvin E.; Lepicovsky, Jan

1992-01-01

The Engine Components Instrumentation Development Facility at NASA Lewis is a unique aeronautics facility dedicated to the development of innovative instrumentation for turbine engine component testing. Containing two separate wind tunnels, the facility is capable of simulating many flow conditions found in most turbine engine components. This facility's broad range of capabilities as well as its versatility provide an excellent location for the development of novel testing techniques. These capabilities thus allow a more efficient use of larger and more complex engine component test facilities.

Properties and Performance Attributes of Novel Co-Extruded Polyolefin Battery Separator Materials. Part 1; Mechanical Properties

NASA Technical Reports Server (NTRS)

Baldwin, Richard S.; Guzik, Monica; Skierski, Michael

2011-01-01

As NASA prepares for its next era of manned spaceflight missions, advanced energy storage technologies are being developed and evaluated to address future mission needs and technical requirements and to provide new mission-enabling technologies. Cell-level components for advanced lithium-ion batteries possessing higher energy, more reliable performance and enhanced, inherent safety characteristics are actively under development within the NASA infrastructure. A key component for safe and reliable cell performance is the cell separator, which separates the two energetic electrodes and functions to prevent the occurrence of an internal short-circuit while enabling ionic transport. Recently, a new generation of co-extruded separator films has been developed by ExxonMobil Chemical and introduced into their battery separator product portfolio. Several grades of this new separator material have been evaluated with respect to dynamic mechanical properties and safety-related performance attributes. This paper presents the results of these evaluations in comparison to a current state-ofthe-practice separator material. The results are discussed with respect to potential opportunities to enhance the inherent safety characteristics and reliability of future, advanced lithium-ion cell chemistries.

Ionic liquid/water mixtures: from hostility to conciliation.

PubMed

Kohno, Yuki; Ohno, Hiroyuki

2012-07-21

Water was originally inimical to ionic liquids (ILs) especially in the analysis of their detailed properties. Various data on the properties of ILs indicate that there are two ways to design functions of ionic liquids. The first is to change the structure of component ions, to provide "task-specific ILs". The second is to mix ILs with other components, such as other ILs, organic solvents or water. Mixing makes it easy to control the properties of the solution. In this strategy, water is now a very important partner. Below, we summarise our recent results on the properties of IL/water mixtures. Stable phase separation is an effective method in some separation processes. Conversely, a dynamic phase change between a homogeneous mixture and separation of phases is important in many fields. Analysis of the relation between phase behaviour and the hydration state of the component ions indicates that the pattern of phase separation is governed by the hydrophilicity of the ions. Sufficiently hydrophilic ions yielded ILs that are miscible with water, and hydrophobic ions gave stable phase separation with water. ILs composed of hydrophobic but hydrated ions undergo a dynamic phase change between a homogeneous mixture and separate phases according to temperature. ILs having more than seven water molecules per ion pair undergo this phase transition. These dynamic phase changes are considered, with some examples, and application is made to the separation of water-soluble proteins.

Runoff Analysis Considering Orographical Features Using Dual Polarization Radar Rainfall

NASA Astrophysics Data System (ADS)

Noh, Hui-seong; Shin, Hyun-seok; Kang, Na-rae; Lee, Choong-Ke; Kim, Hung-soo

2013-04-01

Recently, the necessity for rainfall estimation and forecasting using the radar is being highlighted, due to the frequent occurrence of torrential rainfall resulting from abnormal changes of weather. Radar rainfall data represents temporal and spatial distributions properly and replace the existing rain gauge networks. It is also frequently applied in many hydrologic field researches. However, the radar rainfall data has an accuracy limitation since it estimates rainfall, by monitoring clouds and precipitation particles formed around the surface of the earth(1.5-3km above the surface) or the atmosphere. In a condition like Korea where nearly 70% of the land is covered by mountainous areas, there are lots of restrictions to use rainfall radar, because of the occurrence of beam blocking areas by topography. This study is aiming at analyzing runoff and examining the applicability of (R(Z), R(ZDR) and R(KDP)) provided by the Han River Flood Control Office(HRFCO) based on the basin elevation of Nakdong river watershed. For this purpose, the amount of radar rainfall of each rainfall event was estimated according to three sub-basins of Nakdong river watershed with the average basin elevation above 400m which are Namgang dam, Andong dam and Hapcheon dam and also another three sub-basins with the average basin elevation below 150m which are Waegwan, Changryeong and Goryeong. After runoff analysis using a distribution model, Vflo model, the results were reviewed and compared with the observed runoff. This study estimated the rainfall by using the radar-rainfall transform formulas, (R(Z), R(Z,ZDR) and R(Z,ZDR,KDP) for four stormwater events and compared the results with the point rainfall of the rain gauge. As the result, it was overestimated or underestimated, depending on rainfall events. Also, calculation indicates that the values from R(Z,ZDR) and R(Z,ZDR,KDP) relatively showed the most similar results. Moreover the runoff analysis using the estimated radar rainfall is performed. Then hydrologic component of the runoff hydrographs, peak flows and total runoffs from the estimated rainfall and the observed rainfall are compared. The results show that hydrologic components have high fluctuations depending on storm rainfall event. Thus, it is necessary to choose appropriate radar rainfall data derived from the above radar rainfall transform formulas to analyze the runoff of radar rainfall. The simulated hydrograph by radar in the three basins of agricultural areas is more similar to the observed hydrograph than the other three basins of mountainous areas. Especially the peak flow and shape of hydrograph of the agricultural areas is much closer to the observed ones than that of mountainous areas. This result comes from the difference of radar rainfall depending on the basin elevation. Therefore we need the examination of radar rainfall transform formulas following rainfall event and runoff analysis based on basin elevation for the improvement of radar rainfall application. Acknowledgment This study was financially supported by the Construction Technology Innovation Program(08-Tech-Inovation-F01) through the Research Center of Flood Defence Technology for Next Generation in Korea Institute of Construction & Transportation Technology Evaluation and Planning(KICTEP) of Ministry of Land, Transport and Maritime Affairs(MLTM)

QSAR modeling of flotation collectors using principal components extracted from topological indices.

PubMed

Natarajan, R; Nirdosh, Inderjit; Basak, Subhash C; Mills, Denise R

2002-01-01

Several topological indices were calculated for substituted-cupferrons that were tested as collectors for the froth flotation of uranium. The principal component analysis (PCA) was used for data reduction. Seven principal components (PC) were found to account for 98.6% of the variance among the computed indices. The principal components thus extracted were used in stepwise regression analyses to construct regression models for the prediction of separation efficiencies (Es) of the collectors. A two-parameter model with a correlation coefficient of 0.889 and a three-parameter model with a correlation coefficient of 0.913 were formed. PCs were found to be better than partition coefficient to form regression equations, and inclusion of an electronic parameter such as Hammett sigma or quantum mechanically derived electronic charges on the chelating atoms did not improve the correlation coefficient significantly. The method was extended to model the separation efficiencies of mercaptobenzothiazoles (MBT) and aminothiophenols (ATP) used in the flotation of lead and zinc ores, respectively. Five principal components were found to explain 99% of the data variability in each series. A three-parameter equation with correlation coefficient of 0.985 and a two-parameter equation with correlation coefficient of 0.926 were obtained for MBT and ATP, respectively. The amenability of separation efficiencies of chelating collectors to QSAR modeling using PCs based on topological indices might lead to the selection of collectors for synthesis and testing from a virtual database.

Application of blind source separation to real-time dissolution dynamic nuclear polarization.

PubMed

Hilty, Christian; Ragavan, Mukundan

2015-01-20

The use of a blind source separation (BSS) algorithm is demonstrated for the analysis of time series of nuclear magnetic resonance (NMR) spectra. This type of data is obtained commonly from experiments, where analytes are hyperpolarized using dissolution dynamic nuclear polarization (D-DNP), both in in vivo and in vitro contexts. High signal gains in D-DNP enable rapid measurement of data sets characterizing the time evolution of chemical or metabolic processes. BSS is based on an algorithm that can be applied to separate the different components contributing to the NMR signal and determine the time dependence of the signals from these components. This algorithm requires minimal prior knowledge of the data, notably, no reference spectra need to be provided, and can therefore be applied rapidly. In a time-resolved measurement of the enzymatic conversion of hyperpolarized oxaloacetate to malate, the two signal components are separated into computed source spectra that closely resemble the spectra of the individual compounds. An improvement in the signal-to-noise ratio of the computed source spectra is found compared to the original spectra, presumably resulting from the presence of each signal more than once in the time series. The reconstruction of the original spectra yields the time evolution of the contributions from the two sources, which also corresponds closely to the time evolution of integrated signal intensities from the original spectra. BSS may therefore be an approach for the efficient identification of components and estimation of kinetics in D-DNP experiments, which can be applied at a high level of automation.

Assimilation of Altimeter Data into a Quasigeostrophic Model of the Gulf Stream System. Part 1; Dynamical Considerations

NASA Technical Reports Server (NTRS)

Capotondi, Antonietta; Malanotte-Rizzoli, Paola; Holland, William R.

1995-01-01

The dynamical consequences of constraining a numerical model with sea surface height data have been investigated. The model used for this study is a quasigeostrophic model of the Gulf Stream region. The data that have been assimilated are maps of sea surface height obtained as the superposition of sea surface height variability deduced from the Geosat altimeter measurements and a mean field constructed from historical hydrographic data. The method used for assimilating the data is the nudging technique. Nudging has been implemented in such a way as to achieve a high degree of convergence of the surface model fields toward the observations. The assimilation of the surface data is thus equivalent to the prescription of a surface pressure boundary condition. The authors analyzed the mechanisms of the model adjustment and the characteristics of the resultant equilibrium state when the surface data are assimilated. Since the surface data are the superposition of a mean component and an eddy component, in order to understand the relative role of these two components in determining the characteristics of the final equilibrium state, two different experiments have been considered: in the first experiment only the climatological mean field is assimilated, while in the second experiment the total surface streamfunction field (mean plus eddies) has been used. It is shown that the model behavior in the presence of the surface data constraint can be conveniently described in terms of baroclinic Fofonoff modes. The prescribed mean component of the surface data acts as a 'surface topography' in this problem. Its presence determines a distortion of the geostrophic contours in the subsurface layers, thus constraining the mean circulation in those layers. The intensity of the mean flow is determined by the inflow/outflow conditions at the open boundaries, as well as by eddy forcing and dissipation.

Dual differential interferometer for measurements of broadband surface acoustic waves

NASA Technical Reports Server (NTRS)

Turner, T. M.; Claus, R. O.

1981-01-01

A simple duel interferometer which uses two pairs of orthogonally polarized optical beams to measure both the amplitude and direction of propagation of broadband ultrasonic surface waves is described. Each pair of focused laser probe beams is used in a separate wideband differential interferometer to independently detect the component of surface wave motion along one direction on the surface. By combining the two output signals corresponding to both components, the two dimensional surface profile and its variation as a function of time is determined.

A model of the general ocean circulation determined from a joint solution for the Earth's gravity field

NASA Technical Reports Server (NTRS)

Nerem, R. S.; Tapley, B. D.; Shum, C. K.; Yuan, D. N.

1989-01-01

If the geoid and the satellite position are known accurately, satellite altimetry can be used to determine the geostrophic velocity of the surface ocean currents. The purpose of this investigation is to simultaneously estimate the sea surface topography, zeta, the model for the gravity field, and the satellite orbit. Satellite tracking data from fourteen satellites were used; along with Seasat and Geosat altimeter data as well as surface gravity data for the solution. The estimated model of zeta compares well at long wavelengths with the hydrographic model of zeta. Covariance studies show that the geoid is separable from zeta up to degree 9, at which point geoid error becomes comparable to the signal of zeta.

15 CFR 995.3 - Availability of other publications.

Code of Federal Regulations, 2010 CFR

2010-01-01

... Hydrographic Data, edition 2.0, dated October 2003, describes the validation checks to be used on ENC data... the 1974 SOLAS Convention. IEC Publication 61174, dated August 1998, can be purchased from the IEC Web site: http://www.iec.ch. (2) IHO Special Publication S57—The IHO Transfer Standard for Hydrographic...

15 CFR 995.3 - Availability of other publications.

Code of Federal Regulations, 2011 CFR

2011-01-01

... Hydrographic Data, edition 2.0, dated October 2003, describes the validation checks to be used on ENC data... the 1974 SOLAS Convention. IEC Publication 61174, dated August 1998, can be purchased from the IEC Web site: http://www.iec.ch. (2) IHO Special Publication S57—The IHO Transfer Standard for Hydrographic...

THE INFLUENCE OF CATCHMENT LAND USE ON HYDROGRAPH DYNAMICS AND IMPLICATIONS FOR STREAM BIOLOGICAL ASSEMBLAGES

EPA Science Inventory

Catchment land use impacts the rise and fall dynamic of hydrographs, and may also help explain variation in biological assemblages known to be sensitive to flow regime. We collected continuous stream depth records for the 2002 water year (5 min. intervals) from eight streams dra...

Hydrographic Basins Analysis Using Digital Terrain Modelling

NASA Astrophysics Data System (ADS)

Mihaela, Pişleagă; -Minda Codruţa, Bădăluţă; Gabriel, Eleş; Daniela, Popescu

2017-10-01

The paper, emphasis the link between digital terrain modelling and studies of hydrographic basins, concerning the hydrological processes analysis. Given the evolution of computing techniques but also of the software digital terrain modelling made its presence felt increasingly, and established itself as a basic concept in many areas, due to many advantages. At present, most digital terrain modelling is derived from three alternative sources such as ground surveys, photogrammetric data capture or from digitized cartographic sources. A wide range of features may be extracted from digital terrain models, such as surface, specific points and landmarks, linear features but also areal futures like drainage basins, hills or hydrological basins. The paper highlights how the use appropriate software for the preparation of a digital terrain model, a model which is subsequently used to study hydrographic basins according to various geomorphological parameters. As a final goal, it shows the link between digital terrain modelling and hydrographic basins study that can be used to optimize the correlation between digital model terrain and hydrological processes in order to obtain results as close to the real field processes.

Two-dimensional capillary electrophoresis: capillary isoelectric focusing and capillary zone electrophoresis with laser-induced fluorescence detection

PubMed Central

Dickerson, Jane A.; Ramsay, Lauren M.; Dada, Oluwatosin O.; Cermak, Nathan

2011-01-01

Capillary isoelectric focusing and capillary zone electrophoresis are coupled with laser-induced fluorescence detection to create an ultrasensitive two-dimensional separation method for proteins. In this method, two capillaries are joined through a buffer filled interface. Separate power supplies control the potential at the injection end of the first capillary and at the interface; the detector is held at ground potential. Proteins are labeled with the fluorogenic reagent Chromeo P503, which preserves the isoelectric point of the labeled protein. The labeled proteins were mixed with ampholytes and injected into the first dimension capillary. A focusing step was performed with the injection end of the capillary at high pH and the interface at low pH. To mobilize components, the interface was filled with a high pH buffer, which was compatible with the second dimension separation. A fraction was transferred to the second dimension capillary for separation. The process of fraction transfer and second dimension separation was repeated two dozen times. The separation produced a spot capacity of 125. PMID:20603830

Seasonal varability of the Canary Current

NASA Astrophysics Data System (ADS)

Vélez-Belchí, P.; Hernandez-Guerra, A.; Pérez-Hernández, M. D.

2016-02-01

The Atlantic meridional overturning circulation (AMOC) is recognized as an important component of the climate system, contributing to the relatively mild climate of northwest Europe. Due to its importance, the strength of the AMOC is continually monitored along 26ºN with several moorings, east of the Bahamas, in the Middle Atlantic Ridge and south of the Canary islands, known as the RAPID array. The measurements of the RAPID array show a 6 Sv seasonal cycle for the AMOC, and recent studies have pointed out the dynamics of the eastern Atlantic as the main driver for this seasonal cycle, specifically, rossby waves excited south of the Canary Islands.Due to the important role of the eastern Atlantic, in this study we describe the seasonal cycle of the Canary Current (CC) and the Canary Upwelling Current (CUC), using hydrographic data from two cruises carried out in a box around the Canary Islands, the region where the eastern component of the RAPID array is placed. CTD, VMADCP and LADCP data were combined with inverse modeling in order to determine absolute geostrophic transports in the Canary Islands region in fall and spring. During spring, the overall transport of Canary Current and the CUC was southward. In the Lanzarote Passage (LP), between the Canary Islands and Africa, the CUC transported 0.6±0.20 Sv southward, while the Canary Current transported 1.0±0.40 Sv in the oceanic waters of the Canary Islands Archipelago. During fall, the CUC transported 2.8±0.4Sv northward, while the CC transported 2.9±0.60 Sv southward in the oceanic waters of the Canary Islands Archipelago. The seasonal cycle observed has and amplitude of 3.4Sv for the CUC and 1.9Sv for the CC. Data from a mooring in the LP and the hydrographic data was used to calibrate geostrophic transport estimated using altimetry data. The amplitude of the seasonal cycle of the geostrophic transport obtained using the calibrated altimetry data (Figure 1) was quite similar to the seasonal cycle of the Eastern Atlantic contribution to the AMOC, as measured by the RAPID array. To understand the relationship between the seasonal cycle found in the CC and CUC, and the amplitude of the seasonal cycle of the AMOC transport associated with Rossby waves, a sensitivity study of the Rossby wave model is included.

Seasonal cycle of the Canary Current.

NASA Astrophysics Data System (ADS)

Vélez-Belchí, P.; Hernandez-Guerra, A.; Pérez-Hernández, M. D.

2015-12-01

The Atlantic meridional overturning circulation (AMOC) is recognized as an important component of the climate system, contributing to the relatively mild climate of northwest Europe. Due to its importance, the strength of the AMOC is continually monitored along 26ºN with several moorings east of the Bahamas, in the Middle Atlantic Ridge and south of the Canary islands, known as the RAPID array. The measurements of the RAPID array show a 6 Sv seasonal cycle for the AMOC, and recent studies have pointed out the dynamics of the eastern Atlantic as the main driver for this seasonal cycle, specifically, rossby waves excited south of the Canary Islands. Due to the important role of the eastern Atlantic, in this study we describe the seasonal cycle of the Canary Current (CC) and the Canary Upwelling Current (CUC) using hydrographic data from two cruises carried out in a box around the Canary Islands, the region where the eastern component of the RAPID array is placed. CTD, VMADCP and LADCP data were combined with inverse modeling in order to determine absolute geostrophic transports in the Canary Islands region in fall and spring. During spring, the overall transport of Canary Current and the CUC was southward. In the Lanzarote Passage (LP), between the Canary Islands and Africa, the CUC transported 0.6±0.20 Sv southward, while the Canary Current transported 1.0±0.40 Sv in the oceanic waters of the Canary Islands Archipelago. During fall, the CUC transported 2.8±0.4Sv northward, while the CC transported 2.9±0.60 Sv southward in the oceanic waters of the Canary Islands Archipelago. The seasonal cycle observed has an amplitude of 3.4Sv for the CUC and 1.9Sv for the CC. Data from a mooring in the LP and the hydrographic data was used to calibrate geostrophic transport estimated using altimetry data. The amplitude of the seasonal cycle of the geostrophic transport obtained using the calibrated altimetry data (Figure 1) was quite similar to the seasonal cycle of the Eastern Atlantic contribution to the AMOC, as measured by the RAPID array. To understand the relationship between the seasonal cycle found in the CC and CUC, and the amplitude of the seasonal cycle of the AMOC transport associated with Rossby waves, a sensitivity study of the Rossby wave model is included.

The 'robust' capture-recapture design allows components of recruitment to be estimated

USGS Publications Warehouse

Pollock, K.H.; Kendall, W.L.; Nichols, J.D.; Lebreton, J.-D.; North, P.M.

1993-01-01

The 'robust' capture-recapture design (Pollock 1982) allows analyses which combine features of closed population model analyses (Otis et aI., 1978, White et aI., 1982) and open population model analyses (Pollock et aI., 1990). Estimators obtained under these analyses are more robust to unequal catch ability than traditional Jolly-Seber estimators (Pollock, 1982; Pollock et al., 1990; Kendall, 1992). The robust design also allows estimation of parameters for population size, survival rate and recruitment numbers for all periods of the study unlike under Jolly-Seber type models. The major advantage of this design that we emphasize in this short review paper is that it allows separate estimation of immigration and in situ recruitment numbers for a two or more age class model (Nichols and Pollock, 1990). This is contrasted with the age-dependent Jolly-Seber model (Pollock, 1981; Stokes, 1984; Pollock et L, 1990) which provides separate estimates for immigration and in situ recruitment for all but the first two age classes where there is at least a three age class model. The ability to achieve this separation of recruitment components can be very important to population modelers and wildlife managers as many species can only be separated into two easily identified age classes in the field.

A Simple Experiment in the Separation of a Solid-Phase Mixture and Infrared Spectroscopy for Introductory Chemistry

ERIC Educational Resources Information Center

Szalay, Paul S.

2008-01-01

This experiment was developed as a means of incorporating instrumental analyses into an introductory chemistry laboratory. A two-component solid mixture of caffeine and ibuprofen is separated through a series of solution extractions and precipitation and their relative amounts measured. These compounds were chosen because the combination of…